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Sample records for absorption coefficient values

  1. Effects of combined scattering and absorption coefficients on laser speckle contrast imaging values

    NASA Astrophysics Data System (ADS)

    Khaksari, Kosar; Kirkpatrick, Sean J.

    2015-03-01

    Laser Speckle contrast imaging (LSCI) is a non-invasive or minimally invasive method for visualizing blood flow and perfusion in biological tissues. In LSCI the motion of scattering particles results in a reduction in global and regional speckle contrast. A variety of parameters can affect the calculated contrast values in LSCI techniques, including the optical properties of the fluid and surrounding tissue. In typical LSCI where the motion of blood is of interests, optical properties are influenced by hematocrit levels. In this work we considered the combined effects of both the scattering and absorption coefficients on LSCI measurements on a flow phantom. Fluid phantoms consisting of various concentrations of neutrally buoyant ~10 micron microspheres and India ink mixed with DI water were formulated to mimic the optical properties of whole blood with various levels of hematocrit. In these flow studies, it was found that an increase in μa and/or μs led to a decrease in contrast values when all other experimental parameters were held constant. The observed reduction in contrast due to optical property changes could easily be confused with a contrast reduction due to increased flow velocity. These results suggest that optical properties need to be considered when using LSCI to make flow estimates.

  2. Optical absorption coefficients of pure water

    NASA Astrophysics Data System (ADS)

    Lu, Zheng; Zhao, Xianzhen; Fry, Edward S.

    2002-10-01

    The integrating cavity absorption meter(ICAM), which is independent of scattering effect, is used to measure the absolute values of small optical absorption coefficients of liquid. A modified ICAM is being used to measure the absorption of water in the wavelength range 300 to 700 nm. The ultrapure water produced by a two-stages water purification system reaches Type I quality. This is equal to or better than ASTM,CAP and NCCLS water quality standards. To avoid the fact that dissolved oxygen absorbs ultraviolet light due to the photochemical effect, the water sample is delivered through a nitrogen sealed system which will prevent the sample from contacting with oxygen. A compassion of our absorption spectrum with other existing data is given.

  3. Absorption Coefficient of Alkaline Earth Halides.

    DTIC Science & Technology

    1980-04-01

    levels . As a natural consequence, the magnitude of the absorption coefficient is the key parameter in selecting laser window materials. Over the past...of as can be achieved through improved crystal growing techniques and surface polishing. 2.5. Urbach’s Rule A central question for the development of...high absorption levels , inaccuracies progressively increasing with decreasing absorption level , a natural consequence of decreasing in instrumental

  4. [Experimental determination of the absorption coefficients of biological tissues].

    PubMed

    Kovtun, A V; Kondrat'ev, V S; Terekhov, D V

    1980-01-01

    Procedure is presented for studying the coefficient of biological tissue absorption of radiation with the wavelength lambda = 1.06 mkm. The absorption coefficient is determined by the temperature values of biological tissue experimentally measured with thermopairs. The coherent radiation current falls on the surface of biological tissue. A mathematical model is formulated for biological tissue heating with radiation. Solution of Furier equation obtained by means of Green function is given. Using the relationship found, the energy absorbed by the biological tissue was calculated and the absorption coefficient of radiation with lambda - 1.06 mkm was determined. The results were analysed and the error of the obtained values of absorption coefficients of biological tissues under study were determined.

  5. Absorption coefficient instrument for turbid natural waters.

    PubMed

    Friedman, E; Poole, L; Cherdak, A; Houghton, W

    1980-05-15

    An instrument has been developed that directly measures the multispectral absorption coefficient of turbid natural water. The design incorporates methods for compensation of variation in the internal light source intensity, correction of the spectrally dependent nature of the optical elements, and correction for variation in background light level. When used in conjunction with a spectrally matched total attenuation instrument, the spectrally dependent scattering coefficient can also be derived. Systematic errors associated with multiple scattering have been estimated using Monte Carlo techniques.

  6. Effect of applied mechanical stress on absorption coefficient of compounds

    SciTech Connect

    Gupta, Manoj Kumar; Singh, Gurinderjeet; Dhaliwal, A. S.; Kahlon, K. S.

    2015-08-28

    The absorption coefficient of given materials is the parameter required for the basic information. The measurement of absorption coefficient of compounds Al{sub 2}O{sub 3}, CaCO{sub 3}, ZnO{sub 2}, SmO{sub 2} and PbO has been taken at different incident photon energies 26, 59.54, 112, 1173, 1332keV. The studies involve the measurements of absorption coefficient of the self supporting samples prepared under different mechanical stress. This mechanical stress is render in terms of pressure up to 0-6 ton by using hydraulic press. Measurements shows that absorption coefficient of a material is directly proportional to applied mechanical stress on it up to some extent then become independent. Experimentally measured results are in fairly good agreement with in theoretical values obtained from WinXCOM.

  7. Absorption coefficient instrument for turbid natural waters

    NASA Astrophysics Data System (ADS)

    Friedman, E.; Cherdak, A.; Poole, L.; Houghton, W.

    1980-05-01

    The paper presents an instrument that directly measures multispectral absorption coefficient of turbid natural water. Attention is given to the design, which is shown to incorporate methods for the compensation of variation in the internal light source intensity, correction of the spectrally dependent nature of the optical elements, and correction for variation in the background light level. In addition, when used in conjunction with a spectrally matched total attenuation instrument, the spectrally dependent scattering coefficient can also be derived. Finally, it is reported that systematic errors associated with multiple scattering have been estimated using Monte Carlo techniques.

  8. Absorption coefficient instrument for turbid natural waters

    NASA Technical Reports Server (NTRS)

    Friedman, E.; Cherdak, A.; Poole, L.; Houghton, W.

    1980-01-01

    The paper presents an instrument that directly measures multispectral absorption coefficient of turbid natural water. Attention is given to the design, which is shown to incorporate methods for the compensation of variation in the internal light source intensity, correction of the spectrally dependent nature of the optical elements, and correction for variation in the background light level. In addition, when used in conjunction with a spectrally matched total attenuation instrument, the spectrally dependent scattering coefficient can also be derived. Finally, it is reported that systematic errors associated with multiple scattering have been estimated using Monte Carlo techniques.

  9. Aerosol Angstrom Absorption Coefficient Comparisons during MILAGRO.

    NASA Astrophysics Data System (ADS)

    Marley, N. A.; Marchany-Rivera, A.; Kelley, K. L.; Mangu, A.; Gaffney, J. S.

    2007-12-01

    aerosol Angstrom absorption exponents by linear regression over the entire UV-visible spectral range. These results are compared to results obtained from the absorbance measurements obtained in the field. The differences in calculated Angstrom absorption exponents between the field and laboratory measurements are attributed partly to the differences in time resolution of the sample collection resulting in heavier particle pileup on the filter surface of the 12-hour samples. Some differences in calculated results can also be attributed to the presence of narrow band absorbers below 400 nm that do not fall in the wavelengths covered by the 7 wavelengths of the aethalometer. 1. Marley, N.A., J.S. Gaffney, J.C. Baird, C.A. Blazer, P.J. Drayton, and J.E. Frederick, "The determination of scattering and absorption coefficients of size-fractionated aerosols for radiative transfer calculations." Aerosol Sci. Technol., 34, 535-549, (2001). This work was conducted as part of the Department of Energy's Atmospheric Science Program as part of the Megacity Aerosol Experiment - Mexico City during MILAGRO. This research was supported by the Office of Science (BER), U.S. Department of Energy Grant No. DE-FG02-07ER64329. We also wish to thank Mexican Scientists and students for their assistance from the Instituto Mexicano de Petroleo (IMP) and CENICA.

  10. Dynamic absorption coefficients of CAR and non-CAR resists at EUV

    NASA Astrophysics Data System (ADS)

    Fallica, Roberto; Stowers, Jason K.; Grenville, Andrew; Frommhold, Andreas; Robinson, Alex P. G.; Ekinci, Yasin

    2016-03-01

    The dynamic absorption coefficients of several CAR and non-CAR EUV photoresists are measured experimentally using a specifically developed setup in transmission mode at the XIL beamline of the Swiss Light Source. The absorption coefficient α and the Dill parameters ABC were measured with unprecedented accuracy. In general the α of resists match very closely with the theoretical value calculated from elemental densities and absorption coefficients, whereas exceptions are observed. In addition, through the direct measurements of the absorption coefficients and dose-to-clear values, we introduce a new figure of merit called Chemical Sensitivity to account for all the post-absorption chemical reaction ongoing in the resist, which is also predicts a quantitative clearing volume, and respectively clearing radius, due to the photon absorption in the resist. These parameters may help in deeper insight into the underlying mechanisms of EUV concept of clearing volume and clearing radius are then defined and quantitatively calculated.

  11. Determination of optical absorption coefficient with focusing photoacoustic imaging.

    PubMed

    Li, Zhifang; Li, Hui; Zeng, Zhiping; Xie, Wenming; Chen, Wei R

    2012-06-01

    Absorption coefficient of biological tissue is an important factor for photothermal therapy and photoacoustic imaging. However, its determination remains a challenge. In this paper, we propose a method using focusing photoacoustic imaging technique to quantify the target optical absorption coefficient. It utilizes the ratio of the amplitude of the peak signal from the top boundary of the target to that from the bottom boundary based on wavelet transform. This method is self-calibrating. Factors, such as absolute optical fluence, ultrasound parameters, and Grüneisen parameter, can be canceled by dividing the amplitudes of the two peaks. To demonstrate this method, we quantified the optical absorption coefficient of a target with various concentrations of an absorbing dye. This method is particularly useful to provide accurate absorption coefficient for predicting the outcomes of photothermal interaction for cancer treatment with absorption enhancement.

  12. FTIR-spectrometer-determined absorption coefficients of seven hydrazine fuel gases - Implications for laser remote sensing

    NASA Technical Reports Server (NTRS)

    Molina, L. T.; Grant, W. B.

    1984-01-01

    The absorption spectra of three hydrazines and four of their air-oxidation products were measured in the 9-12-micron spectral region with a Fourier transform infrared (FTIR) spectrometer with a 0.05-kayser resolution to determine absorption coefficients at CO2 and tunable diode laser wavelengths. The measurements agreed well with published CO2 laser determinations for many of the absorption coefficients, except where the published values are thought to be in error. The coefficients were then used to estimate the sensitivity for remote detection of these gases using CO2 and tunable diode lasers in long-path differential absorption measurements.

  13. Measurements of the absorption coefficient of stratospheric aerosols

    NASA Technical Reports Server (NTRS)

    Ogren, J. A.; Ahlquist, N. C.; Clarke, A. D.; Charlson, R. J.

    1981-01-01

    The absorption coefficients of stratospheric aerosols are measured using a variation on the integrating plate method. The technique is based on the decrease in the transparency of a substrate when an absorbing aerosol is deposited on it. A Lambert scatterer is placed behind the substrate to integrate forward scattered light and minimize the effect of scattering on the measurement. The low pressure in the stratosphere is used for the direct impaction of particles onto a narrow strip of opal glass. The eight samples collected had a median value of 4 x 10 to the -9th m with an uncertainty of + or - 5 x 10 to the -9th m. If this absorption is due to graphitic carbon, then its concentration is estimated at about 0.4 ng/cu m, or about 0.25% of the total aerosol mass concentration. Estimates of the aerosol scattering coefficients based on satellite extinction inversions result in an aerosol single-scattering albedo in the range of 0.96-1.0.

  14. Continuum Absorption Coefficient of Atoms and Ions

    NASA Technical Reports Server (NTRS)

    Armaly, B. F.

    1979-01-01

    The rate of heat transfer to the heat shield of a Jupiter probe has been estimated to be one order of magnitude higher than any previously experienced in an outer space exploration program. More than one-third of this heat load is due to an emission of continuum radiation from atoms and ions. The existing computer code for calculating the continuum contribution to the total load utilizes a modified version of Biberman's approximate method. The continuum radiation absorption cross sections of a C - H - O - N ablation system were examined in detail. The present computer code was evaluated and updated by being compared with available exact and approximate calculations and correlations of experimental data. A detailed calculation procedure, which can be applied to other atomic species, is presented. The approximate correlations can be made to agree with the available exact and experimental data.

  15. Photon absorption potential coefficient as a tool for materials engineering

    NASA Astrophysics Data System (ADS)

    Akande, Raphael Oluwole; Oyewande, Emmanuel Oluwole

    2016-09-01

    Different atoms achieve ionizations at different energies. Therefore, atoms are characterized by different responses to photon absorption in this study. That means there exists a coefficient for their potential for photon absorption from a photon source. In this study, we consider the manner in which molecular constituents (atoms) absorb photon from a photon source. We observe that there seems to be a common pattern of variation in the absorption of photon among the electrons in all atoms on the periodic table. We assume that the electrons closest to the nucleus (En) and the electrons closest to the outside of the atom (Eo) do not have as much potential for photon absorption as the electrons at the middle of the atom (Em). The explanation we give to this effect is that the En electrons are embedded within the nuclear influence, and similarly, Eo electrons are embedded within the influence of energies outside the atom that there exists a low potential for photon absorption for them. Unlike En and Eo, Em electrons are conditioned, such that there is a quest for balance between being influenced either by the nuclear force or forces external to the atom. Therefore, there exists a higher potential for photon absorption for Em electrons than for En and Eo electrons. The results of our derivations and analysis always produce a bell-shaped curve, instead of an increasing curve as in the ionization energies, for all elements in the periodic table. We obtained a huge data of PAPC for each of the several materials considered. The point at which two or more PAPC values cross one another is termed to be a region of conflicting order of ionization, where all the atoms absorb equal portion of the photon source at the same time. At this point, a greater fraction of the photon source is pumped into the material which could lead to an explosive response from the material. In fact, an unimaginable and unreported phenomenon (in physics) could occur, when two or more PAPCs cross, and

  16. Absorption and Scattering Coefficients: A Biophysical-Chemistry Experiment Using Reflectance Spectroscopy

    ERIC Educational Resources Information Center

    Cordon, Gabriela B.; Lagorio, M. Gabriela

    2007-01-01

    A biophysical-chemistry experiment, based on the reflectance spectroscopy for calculating the absorption and scattering coefficients of leaves is described. The results show that different plants species exhibit different values for both the coefficients because of their different pigment composition.

  17. Prediction of absorption coefficients by pulsed laser induced photoacoustic measurements.

    PubMed

    Priya, Mallika; Satish Rao, B S; Ray, Satadru; Mahato, K K

    2014-06-05

    In the current study, a pulsed laser induced photoacoustic spectroscopy setup was designed and developed, aiming its application in clinical diagnostics. The setup was optimized with carbon black samples in water and with various tryptophan concentrations at 281nm excitations. The sensitivity of the setup was estimated by determining minimum detectable concentration of tryptophan in water at the same excitation, and was found to be 0.035mM. The photoacoustic experiments were also performed with various tryptophan concentrations at 281nm excitation for predicting optical absorption coefficients in them and for comparing the outcomes with the spectrophotometrically-determined absorption coefficients for the same samples. Absorption coefficients for a few serum samples, obtained from some healthy female volunteers, were also determined through photoacoustic and spectrophotometric measurements at the same excitations, which showed good agreement between them, indicating its clinical implications.

  18. NUMERICAL CALCULATION OF MAGNETOBREMSSTRAHLUNG EMISSION AND ABSORPTION COEFFICIENTS

    SciTech Connect

    Leung, Po Kin; Gammie, Charles F.; Noble, Scott C. E-mail: gammie@illinois.edu

    2011-08-10

    Magnetobremsstrahlung (MBS) emission and absorption play a role in many astronomical systems. We describe a general numerical scheme for evaluating MBS emission and absorption coefficients for both polarized and unpolarized light in a plasma with a general distribution function. Along the way we provide an accurate scheme for evaluating Bessel functions of high order. We use our scheme to evaluate the accuracy of earlier fitting formulae and approximations. We also provide an accurate fitting formula for mildly relativistic (kT/(m{sub e}c{sup 2}) {approx}> 0.5) thermal electron emission (and therefore absorption). Our scheme is too slow, at present, for direct use in radiative transfer calculations but will be useful for anyone seeking to fit emission or absorption coefficients in a particular regime.

  19. Methane Absorption Coefficients for the Jovian Planets and Titan

    NASA Astrophysics Data System (ADS)

    Karkoschka, Erich; Tomasko, M. G.

    2009-09-01

    We combined 11 data sets of methane transmission measurements within 0.4-5.5 micrometer wavelength in order to better understand the variation of methane absorption with temperature and pressure for conditions in the atmospheres of the Jovian planets and Titan. Eight data sets are based on published laboratory measurements. Another two data sets come from two spectrometers onboard the Huygens probe that measured methane absorption inside Titan's atmosphere (Tomasko et al. 2008, PSS 56, 624). We present the data with a refined analysis. The last data set consists of Hubble Space Telescope images of Jupiter taken in 2005 and 2007 as Ganymede started to be occulted by Jupiter. Using Ganymede as a light source, we probed Jupiter's stratosphere with large methane pathlengths. Below 1000 nm wavelength, we find methane absorption coefficients generally similar to those by Karkoschka (1998, Icarus 133, 134). We added descriptions of temperature and pressure dependence, which are typically small in this wavelength range. Data in this wavelength range are consistent with each other, except between 882 and 902 nm wavelength where laboratory data predict larger absorptions in the Jovian atmospheres than observed. We present possible explanations. Above 1000 nm, our analysis of the Huygens data confirms methane absorption coefficients by Irwin et al. (2006, Icarus 181, 309) at their laboratory temperatures. Huygens data are consistent with Irwin's model of the pressure dependence of methane absorption. However, when large extrapolations were needed, such as from laboratory data above 200 K to Titan's temperatures near 80 K, Irwin's model of temperature dependence predicts absorption coefficients up to 100 times lower than measured by Huygens. We combined Irwin's and Huygens' data to obtain more reliable methane absorption coefficients for the temperatures in the atmospheres of the Jovian planets and Titan. This research was supported by NASA grants NAG5-12014 and NNX08AE74G.

  20. Vapor-Phase Infrared Absorptivity Coefficient of HN1

    DTIC Science & Technology

    2013-08-01

    infrared spectrometer GC gas chromatography HD sulfur mustard HeNe helium–neon (laser) HgCdTe mercury–cadmium–telluride detector HN1, HN2, HN3...coefficient of the compound. 15. SUBJECT TERMS Vapor phase Saturator cell Infrared (IR) HN1 Vapor pressure Nitrogen mustard Vesicant...9 1 VAPOR-PHASE INFRARED ABSORPTIVITY COEFFICIENT OF HN1 1. INTRODUCTION The nitrogen mustards (HN1, HN2, and HN3) are similar to

  1. Absorption coefficient measurements of particle-laden filters using laser heating: Validation with nigrosin

    NASA Astrophysics Data System (ADS)

    Presser, Cary

    2012-05-01

    A laser-heating technique, referred as the laser-driven thermal reactor, was used in conjunction with laser transmissivity measurements to determine the absorption coefficient of particle-laden substrates (e.g., quartz-fiber filters). The novelty of this approach is that it analyzes a wide variety of specific samples (not just filtered samples) and overcomes measurement issues (e.g., absorption enhancement) associated with other filter-based particle absorption techniques. The absorption coefficient was determined for nigrosin-laden, quartz-fiber filters and the effect of the filter on the absorption measurements was estimated when compared to the isolated nigrosin results. The isolated nigrosin absorption coefficient compared favorably with Lorenz-Mie calculations for an idealized polydispersion of spherical particles (based on a measured nigronsin/de-ionized water suspension size distribution) dispersed throughout a volume equivalent to that of the nigrosin-laden filter. To validate the approach, the absorption coefficient of a nigrosin/de-ionized water suspension was in good agreement with results obtained from an ultraviolet/visible spectrometer. In addition, the estimated imaginary part of the refractive index from the Lorenz-Mie calculations compared well with literature values and was used to estimate the absorption coefficient of optically opaque packed nigrosin.

  2. Ozone absorption coefficients' role in Dobson instrument ozone measurement accuracy

    NASA Astrophysics Data System (ADS)

    Basher, R. E.

    1982-11-01

    The differences of 10% or more between the laboratory measurements of UV absorption coefficients by different investigators indicate accuracies that are quite inadequate for current needs in the measurement of atmospheric ozone. The standard band-integrated set of coefficients now used with the Dobson instrument are mutually consistent to about 2%, but their absolute accuracy is still in question. The accurate calculation of band-integrated coefficients must take account of their dependence on source spectral irradiance, atmospheric spectral transmittance, mean ozone temperature, and instrument spectral transmittance. A careful examination shows that Komhyr's (1980) case for an error of about +5% in the standard Dobson AD ozone estimation is subject to large uncertainties and certain lacks of independence. The obvious solution to this accuracy problem lies in better laboratory measurements of ozone absorption.

  3. Impact of inhomogeneous optical scattering coefficient distribution on recovery of optical absorption coefficient maps using tomographic photoacoustic data.

    PubMed

    Li, Xiaoqi; Jiang, Huabei

    2013-02-21

    We present a study through extensive simulation that considers the impact of inhomogeneous optical scattering coefficient distribution on recovery of optical absorption coefficient maps using tomographic photoacoustic data collected from media mimicking breast tissue. We found that while the impact of scattering heterogeneities/targets is modest on photoacoustic recovery of optical absorption coefficients, the impact of scattering contrast caused by adipose tissue, a layer of normal tissue along the boundary of the breast, is dramatic on reconstruction of optical absorption coefficients using photoacoustic data-up to 25.8% relative error in recovering the absorption coefficient is estimated in such cases. To overcome this problem, we propose a new method to enhance photoacoustic recovery of the optical absorption coefficient in heterogeneous media by considering inhomogeneous scattering coefficient distribution provided by diffuse optical tomography (DOT). Results from extensive simulations show that photoacoustic recovery of absorption coefficient maps can be improved considerably with a priori scattering information from DOT.

  4. Minority carrier diffusion lengths and absorption coefficients in silicon sheet material

    NASA Technical Reports Server (NTRS)

    Dumas, K. A.; Swimm, R. T.

    1980-01-01

    Most of the methods which have been developed for the measurement of the minority carrier diffusion length of silicon wafers require that the material have either a Schottky or an ohmic contact. The surface photovoltage (SPV) technique is an exception. The SPV technique could, therefore, become a valuable diagnostic tool in connection with current efforts to develop low-cost processes for the production of solar cells. The technique depends on a knowledge of the optical absorption coefficient. The considered investigation is concerned with a reevaluation of the absorption coefficient as a function of silicon processing. A comparison of absorption coefficient values showed these values to be relatively consistent from sample to sample, and independent of the sample growth method.

  5. Determination of molar absorption coefficients of organic compounds adsorbed in porous media.

    PubMed

    Ciani, Andrea; Goss, Kai-Uwe; Schwarzenbach, René P

    2005-12-01

    The kinetics of direct photochemical transformations of organic compounds in light absorbing and scattering media has been sparsely investigated. This is mostly due to the experimental difficulties to assess the major parameters: light intensity in porous media, the reaction quantum yield and the molar absorption coefficient of the adsorbed compound, epsilon(i) (lambda). Here, we propose a method for the determination of the molar absorption coefficient of compounds adsorbed to air-dry surfaces using the Kubelka-Munk model for the description of radiative transfer. To illustrate the method, the molar absorption coefficients of three compounds, i.e. 4-nitroanisole (PNA), the herbicide trifluralin and the flame retardant decabromodiphenyl ether (DecaBDE), were determined on air-dry kaolinite. The measured diffuse reflectance spectra were evaluated with the Kubelka-Munk model and with previously determined Kubelka-Munk absorption and scattering coefficients (k and s), for kaolinite. For all compounds the maximum absorption band was found to be red shifted and the corresponding epsilon(i) (lambda) values were significantly greater than those determined in solvents. Together with the absorption and scattering coefficient of the medium, the measured epsilon(i) (lambda) can be used to determine the quantum yield of the photochemical reaction in this medium from experimentally determined reaction kinetics.

  6. Field testing of sound absorption coefficients in a classroom

    NASA Astrophysics Data System (ADS)

    Pettyjohn, Steve

    2005-09-01

    Formal procedures for determining the sound absorption coefficients of materials installed in the field do not exist. However, the U.S. Air Force requested such tests to prove that the sound-absorbing material used in classrooms at Beale AFB in Marysville, CA, met the specified NRC of 0.80. They permitted the use of two layers of 0.5-in. fiberboard or 1-in.-thick fiberglass panels to meet the specified NRC rating. Post-construction tests showed reverberation times longer than expected. Unrealistic sound-absorption coefficients for room finish materials had to be used with the Sabine equation to achieve agreement between the measured and predicted reverberation time. By employing the Fitzroy equation and generally published absorption coefficients for ceiling tile, carpet, and fiberboard, the model provided excellent agreement with the measured reverberation times. The NRC of the fiberboard was computed to be 0.35, agreeing with published data. Since this did not meet project specifications, the Fitzroy model was used to learn the type and quantity of material needed to meet design goals. Follow-up tests showed good agreement between the predicted and measured reverberation times with material added, and project specifications were met. Results are also compared with the requirements of ANSI 12.60.

  7. Implications of New Methane Absorption Coefficients on Uranus Vertical Structure Derived from Near-IR Spectra

    NASA Astrophysics Data System (ADS)

    Fry, Patrick M.; Sromovsky, L. A.

    2009-09-01

    Using new methane absorption coefficients from Karkoschka and Tomasko (2009, submitted to Icarus, "Methane Absorption Coefficients for the Jovian Planets from Laboratory, Huygens, and HST Data"), we fit Uranus near-IR spectra previously analyzed in Sromovsky et al. (2006, Icarus 182, 577-593, Fink and Larson, 1979 J- and H-band), Sromovsky and Fry (2008, Icarus 193, 252-266, 2006 NIRC2 J- and H-band, 2006 SpeX) using Irwin et al. (2006, Icarus 181, 309-319) methane absorption coefficients. Because the new absorption coefficients usually result in higher opacities at the low temperatures seen in Uranus' upper troposphere, our previously derived cloud altitudes are expected to generally rise to higher altitudes. For example, using Lindal et al. (1987, JGR 92, 14987-15001) model D temperature and methane abundance profiles, we are better able to fit the J-band 43-deg. south bright band with the new coefficients (chi-square=205, vs. 315 for Irwin), with the pressure of the upper tropospheric cloud decreasing to 1.6 bars (from 2.4 bars using Irwin coefficients). Improvements in fitting H-band spectra from the same latitude are not as readily obtained. Derived upper tropospheric cloud pressures are very similar using the two absorption datasets (1.6-1.7 bars), but the character of the fits differs. New Karkoschka and Tomasko coefficients better fit some details in the 1.5-1.58 micron region, but Irwin fits the broad absorption band wing at 1.61-1.62 microns better, and the fit chi-square values are similar (K&T: 243, Irwin: 220). Results for a higher methane concentration (Lindal et al. model F) were similar. Whether the new coefficients will simply raise derived altitudes across the planet or will result in fundamental changes in structure is as yet unclear. This work was suported by NASA planetary astronomy and planetary atmospheres programs.

  8. Measurements of Soot Mass Absorption Coefficients from 300 to 660 nm

    NASA Astrophysics Data System (ADS)

    Renbaum-Wolff, Lindsay; Fisher, Al; Helgestad, Taylor; Lambe, Andrew; Sedlacek, Arthur; Smith, Geoffrey; Cappa, Christopher; Davidovits, Paul; Onasch, Timothy; Freedman, Andrew

    2016-04-01

    Soot, a product of incomplete combustion, plays an important role in the earth's climate system through the absorption and scattering of solar radiation. In particular, the assumed mass absorption coefficient (MAC) of soot and its variation with wavelength presents a significant uncertainty in the calculation of radiative forcing in global climate change models. As part of the fourth Boston College/Aerodyne soot properties measurement campaign, we have measured the mass absorption coefficient of soot produced by an inverted methane diffusion flame over a spectral range of 300-660 nm using a variety of optical absorption techniques. Extinction and absorption were measured using a dual cavity ringdown photoacoustic spectrometer (CRD-PAS, UC Davis) at 405 nm and 532 nm. Scattering and extinction were measured using a CAPS PMssa single scattering albedo monitor (Aerodyne) at 630 nm; the absorption coefficient was determined by subtraction. In addition, the absorption coefficients in 8 wavelength bands from 300 to 660 nm were measured using a new broadband photoacoustic absorption monitor (UGA). Soot particle mass was quantified using a centrifugal particle mass analyzer (CPMA, Cambustion), mobility size with a scanning mobility particle sizer (SMPS, TSI) and soot concentration with a CPC (Brechtel). The contribution of doubly charged particles to the sample mass was determined using a Single Particle Soot Photometer (DMT). Over a mass range of 1-8 fg, corresponding to differential mobility diameters of ~150 nm to 550 nm, the value of the soot MAC proved to be independent of mass for all wavelengths. The wavelength dependence of the MAC was best fit to a power law with an Absorption Ångstrom Coefficient slightly greater than 1.

  9. Determination of the Absorption Coefficient and Cloudiness Multiplicity Attenuation During the Gamma-Radiation Passage

    NASA Astrophysics Data System (ADS)

    Orlova, K. N.; Borovikov, I. F.; Gaidamak, M. A.

    2016-08-01

    The paper presents background value equivalent dose of gamma-radiation investigation in different weather: clear cloudy and overcast. The change of the dose rate of gamma radiation, depending on the weather and the ability cloudiness to shield gamma rays is shown. A new method for eliminating the consequences of accidents at nuclear power plants or plants using radioactive elements is proposed. A calculation method of cloudiness coefficient absorption and cloudiness gamma-radiation multiplicity attenuation is developed. The gamma- radiation multiplicity attenuation and the absorption coefficient of gamma radiation were calculated.

  10. Dynamic absorption coefficients of chemically amplified resists and nonchemically amplified resists at extreme ultraviolet

    NASA Astrophysics Data System (ADS)

    Fallica, Roberto; Stowers, Jason K.; Grenville, Andrew; Frommhold, Andreas; Robinson, Alex P. G.; Ekinci, Yasin

    2016-07-01

    The dynamic absorption coefficients of several chemically amplified resists (CAR) and non-CAR extreme ultraviolet (EUV) photoresists are measured experimentally using a specifically developed setup in transmission mode at the x-ray interference lithography beamline of the Swiss Light Source. The absorption coefficient α and the Dill parameters ABC were measured with unprecedented accuracy. In general, the α of resists match very closely with the theoretical value calculated from elemental densities and absorption coefficients, whereas exceptions are observed. In addition, through the direct measurements of the absorption coefficients and dose-to-clear values, we introduce a new figure of merit called chemical sensitivity to account for all the postabsorption chemical reaction ongoing in the resist, which also predicts a quantitative clearing volume and clearing radius, due to the photon absorption in the resist. These parameters may help provide deeper insight into the underlying mechanisms of the EUV concepts of clearing volume and clearing radius, which are then defined and quantitatively calculated.

  11. Evaluation of ammonia absorption coefficients by photoacoustic spectroscopy for detection of ammonia levels in human breath

    NASA Astrophysics Data System (ADS)

    Dumitras, D. C.; Dutu, D. C.; Matei, C.; Cernat, R.; Banita, S.; Patachia, M.; Bratu, A. M.; Petrus, M.; Popa, C.

    2011-04-01

    Photoacoustic spectroscopy represents a powerful technique for measuring extremely low absorptions independent of the path length and offers a degree of parameter control that cannot be attained by other methods. We report precise measurements of the ammonia absorption coefficients at the CO2 laser wavelengths by using a photoacoustic (PA) cell in an extracavity configuration and we compare our results with other values reported in the literature. Ammonia presents a clear fingerprint spectrum and high absorption strengths in the CO2 wavelengths region. Because more than 250 molecular gases of environmental concern for atmospheric, industrial, medical, military, and scientific spheres exhibit strong absorption bands in the region 9.2-10.8 μm, we have chosen a frequency tunable CO2 laser. In the present work, ammonia absorption coefficients were measured at both branches of the CO2 laser lines by using a calibrated mixture of 10 ppm NH3 in N2. We found the maximum absorption in the 9 μm region, at 9R(30) line of the CO2 laser. One of the applications based on the ammonia absorption coefficients is used to measure the ammonia levels in exhaled human breath. This can be used to determine the exact time necessary at every session for an optimal degree of dialysis at patients with end-stage renal disease.

  12. Optimization of the acoustic absorption coefficients of certain functional absorbents

    NASA Technical Reports Server (NTRS)

    Pocsa, V.; Biborosch, L.; Veres, A.; Halpert, E.; Lorian, R.; Botos, T.

    1974-01-01

    The sound absorption coefficients of some functional absorbents (mineral wool plates) are determined by the reverberation chamber method. The influence of the angle of inclination of the sound absorbing material with respect to the surface to be treated is analyzed as well as the influence of the covering index, defined as the ratio of the designed area of a plate and the area of the treated surface belonging to another plate. As compared with the conventional method of applying sound-absorbing plates, the analyzed structures have a higher technological and economical efficiency. The optimum structure corresponds to an angle of inclination of 15 deg and a covering index of 0.8.

  13. A method for monitoring nuclear absorption coefficients of aviation fuels

    NASA Technical Reports Server (NTRS)

    Sprinkle, Danny R.; Shen, Chih-Ping

    1989-01-01

    A technique for monitoring variability in the nuclear absorption characteristics of aviation fuels has been developed. It is based on a highly collimated low energy gamma radiation source and a sodium iodide counter. The source and the counter assembly are separated by a geometrically well-defined test fuel cell. A computer program for determining the mass attenuation coefficient of the test fuel sample, based on the data acquired for a preset counting period, has been developed and tested on several types of aviation fuel.

  14. Measurement of Acoustic Attenuation and Absorption Coefficients using Thermometry

    NASA Astrophysics Data System (ADS)

    Morris, Hugh; Rivens, Ian; Shaw, Adam; ter Haar, Gail

    2007-05-01

    Accurate knowledge of both the attenuation and the absorption coefficient of tissue are required when planning an optimal high intensity focused ultrasound treatment. A novel technique for simple measurement of this parameters has been developed in which a thin-film thermocouple (TFT) is placed between two layers of tissue of different thicknesses. The sample can be rotated about an axis through the junction of the TFT so that it can be insonated from either side leaving the tissue adjacent to the junction unchanged, but changing the overlying thickness. The attenuation and absorption coefficients can be calculated from the heating curves measured in the two orientations. Experiments have been carried out in both tissue mimicking material (TMM) and in ex vivo liver tissue. Weakly focused transducers, resonant at 1.05 MHz, 2.4 MHz and 3.55 MHz were used at free-field spatial peak intensities of 9-14 W/cm2. The temperature rise was measured as a function of time using a TFT. These thermocouples are not subject to the viscous heating artefact that is common to other thermocouple devices and so are advantageous for this purpose. Alignment was achieved with a 3D automated gantry system, which was controlled with specialised software. Timing and data acquisition were also controlled with this software. All experiments were carried out in degassed water. Results for TMM and degassed excised bovine liver are presented.

  15. Mass specific optical absorption coefficients of mineral dust components measured by a multi wavelength photoacoustic spectrometer

    NASA Astrophysics Data System (ADS)

    Utry, N.; Ajtai, T.; Pintér, M.; Tombácz, E.; Illés, E.; Bozóki, Z.; Szabó, G.

    2014-09-01

    Mass specific optical absorption coefficients of various mineral dust components including silicate clays (illite, kaolin and bentonite), oxides (quartz, hematite and rutile), and carbonate (limestone) were determined at wavelengths of 1064, 532, 355 and 266 nm. These values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA) instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. These results are expected to have considerable importance in global radiative forcing calculations. They can also serve as reference for validating calculated wavelength dependent imaginary parts (κ) of complex refractive indices which up to now have been typically deduced from bulk phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk phase measurements.

  16. Studies on mass energy-absorption coefficients and effective atomic energy-absorption cross sections for carbohydrates

    NASA Astrophysics Data System (ADS)

    Ladhaf, Bibifatima M.; Pawar, Pravina P.

    2015-04-01

    We measured here the mass attenuation coefficients (μ/ρ) of carbohydrates, Esculine (C15H16O9), Sucrose (C12H22O11), Sorbitol (C6H14O6), D-Galactose (C6H12O6), Inositol (C6H12O6), D-Xylose (C5H10O5) covering the energy range from 122 keV up to 1330 keV photon energies by using gamma ray transmission method in a narrow beam good geometry set-up. The gamma-rays were detected using NaI(Tl) scintillation detection system with a resolution of 8.2% at 662 keV. The attenuation coefficient data were then used to obtain the total attenuation cross-section (σtot), molar extinction coefficients (ε), mass-energy absorption coefficients (μen/ρ) and effective (average) atomic energy-absorption cross section (σa,en) of the compounds. These values are found to be in good agreement with the theoretical values calculated based on XCOM data.

  17. Temperature and pressure dependence of dichloro-difluoromethane (CF2C12) absorption coefficients for CO2 waveguide laser radiation

    NASA Technical Reports Server (NTRS)

    Harward, C. N.

    1977-01-01

    Measurements were performed to determine the pressure and temperature dependence of CFM-12 absorption coefficients for CO2 waveguide laser radiation. The absorption coefficients of CFM-12 for CO2 waveguide laser radiation were found to have no spectral structure within small spectral bandwidths around the CO2 waveguide laser lines in the CO2 spectral band for pressures above 20 torr. All of the absorption coefficients for the CO2 laser lines studied are independent of pressure above 100 torr, except for the P(36) laser CO2 spectral band. The absorption coefficients associated with the P(42) line in the same band showed the greatest change with temperature, and it also has the largest value of all the lines studied.

  18. Water vapor absorption coefficients in the 8-13-micron spectral region - A critical review

    NASA Technical Reports Server (NTRS)

    Grant, William B.

    1990-01-01

    Measurements of water vapor absorption coefficients in the thermal IR atmospheric window (8-13 microns) during the past 20 years obtained by a variety of techniques are reviewed for consistency and compared with computed values based on the AFGL spectral data tapes. The methods of data collection considered were atmospheric long path absorption with a CO2 laser or a broadband source and filters, a White cell and a CO2 laser or a broadband source and a spectrometer, and a spectrophone with a CO2 laser. Advantages and disadvantages of each measurement approach are given as a guide to further research. Continuum absorption has apparently been measured accurately to about the 5-10 percent level in five of the measurements reported.

  19. Dependence of dose coefficients for inhaled 239Pu on absorption parameters.

    PubMed

    Suzuki, K; Sekimoto, H; Ishigure, N

    2001-01-01

    With regard to dissolution of particles in the respiratory tract after inhalation, the International Commission on Radiological Protection (ICRP) has classified all radionuclides into only three types according to the chemical form of compounds, and default values of absorption parameters are proposed for each type. However, it is just a simplification to estimate doses for practical use, and there is a possibility of unfitness in such an assortment. A code has been developed to reproduce the ICRP's dose coefficients for 239Pu, which is one of the most important elements for occupational exposure. By using this code, the respective absorption parameters were modified, and the effect owing to these changes evaluated. It was shown consequently that changes of absorption parameters do not greatly influence the effective doses of 239Pu for workers.

  20. Two-photon absorption and Kerr coefficients of silicon for 850-2200 nm

    NASA Astrophysics Data System (ADS)

    Bristow, Alan D.; Rotenberg, Nir; van Driel, Henry M.

    2007-05-01

    The degenerate two-photon absorption coefficient β and Kerr nonlinearity n2 are measured for bulk Si at 300K using 200fs pulses with carrier wavelength of 850<λ<2200nm for which indirect gap transitions occur. With a broad peak near the indirect gap and maximum value of 2±0.5cm/GW, the dispersion of β compares favorably with theoretical calculations of Garcia and Kalyanaraman [J. Phys. B 39, 2737 (2006)]. Within our wavelength range, n2 varies by a factor of 4 with a peak value of 1.2×10-13cm2/W at λ =1800nm.

  1. Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings at Elevated Temperatures

    NASA Technical Reports Server (NTRS)

    Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.

    2009-01-01

    The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."

  2. Measurements of the absorption and scattering coefficients of aerosol particles in suburb of Nanjing (China)

    NASA Astrophysics Data System (ADS)

    Yin, Yan; Chen, Yu; Wang, Weiwei; Yan, Jiade; Qian, Ling; Tong, Yaoqing; Lin, Zhenyi

    2008-08-01

    The absorption and scattering coefficients of atmospheric aerosols were continuously measured with a Photoacoustic Soot Spectrometer (PASS, DMT Inc. USA) at a suburb site of Nanjing, one of the regions experiencing rapid industrialization in China. The measurements were carried out during autumn and winter 2007. A preliminary analysis of the data shows that, the scattering coefficient, Bscat, is two to ten times larger than the absorption coefficient, Babs, implying that the aerosols formed/emitted in this area are more scattering than previous assumed, and can be more important in cooling the Earth-atmosphere system. The results also indicate that the absolute values of both parameters are very much dependent on the meteorological conditions, such as wind speed and direction, fog, rain, etc. as well as the time of the day. Higher values often appear at nighttimes when wind is weak, especially when a temperature inverse layer is present near the surface. Higher values of Bscat and Babs were also observed under hazy and foggy weather conditions or when wind is blown from east, where a large industrial zone is located. Simultaneous measurements of the number concentrations, chemical compositions, and size distributions of aerosol particles are used to explain the characteristics of the changes in Bscat and Babs.

  3. Inference of the microwave absorption coefficient from stray radiation measurements in Wendelstein 7-X

    NASA Astrophysics Data System (ADS)

    Moseev, D.; Laqua, H. P.; Marsen, S.; Marushchenko, N.; Stange, T.; Braune, H.; Gellert, F.; Hirsch, M.; Hoefel, U.; Knauer, J.; Oosterbeek, J. W.; Turkin, Y.; The Wendelstein 7-X Team

    2017-03-01

    The efficiency of electron cyclotron heating is determined by the microwave absorption of the plasma. Good microwave absorption is also crucial for the machine safety. In this paper we present a method of evaluating the microwave absorption coefficient from stray radiation measurements. The discussed method is computationally simple and can be applied potentially in real time. Evolution of the second harmonic extraordinary mode (X2) microwave absorption coefficient in Wendelstein 7-X during the start-up phase is presented, as well as an estimate of the absorption coefficient for the second harmonic ordinary mode (O2) wave.

  4. Linear absorption coefficient of beryllium in the 50-300-A wavelength range. [bandpass filter materials for ultraviolet astronomy instrumentation

    NASA Technical Reports Server (NTRS)

    Barstow, M. A.; Lewis, M.; Petre, R.

    1983-01-01

    Transmittances of thin-film filters fabricated for an extreme-UV astronomy sounding-rocket experiment yield values for the linear absorption coefficient of beryllium in the 50-300-A wavelength range, in which previous measurements are sparse. The inferred values are consistent with the lowest data previously published and may have important consequences for extreme-UV astronomers.

  5. A new method to retrieve spectral absorption coefficient of highly-scattering and weakly-absorbing materials

    NASA Astrophysics Data System (ADS)

    Dombrovsky, Leonid A.

    2016-03-01

    A significant uncertainty in the absorption coefficient of highly scattering dispersed materials is typical in the spectral ranges of very weak absorption. The traditional way to identify the main absorption and scattering characteristics of semi-transparent materials is based on spectral measurements of normal-hemispherical reflectance and transmittance for the material sample. Unfortunately this way cannot be used in the case of in vivo measurements of optical properties of biological tissues. A method suggested in the present paper is based on thermal response to the periodic radiative heating of the open surface of a semi-transparent material. It is shown that the period of a variation of the surface temperature is sensitive to the value of an average absorption coefficient in the surface layer. As a result, the monochromatic external irradiation combined with the surface temperature measurements can be used to retrieve the spectral values of absorption coefficient. Possible application of this method to porous semi-transparent ceramics is considered. An example problem is also solved to illustrate the applicability of this method to human skin. The approach suggested enables one to estimate an average absorption coefficient of human skin of a patient just before the thermal processing.

  6. Study of the absorption coefficient in layers of a semiconductor laser heterostructure

    SciTech Connect

    Veselov, D A; Pikhtin, N A; Lyutetskiy, A V; Nikolaev, D N; Slipchenko, S O; Sokolova, Z N; Shamakhov, V V; Shashkin, I S; Voronkova, N V; Tarasov, I S

    2015-07-31

    A method of studying the absorption coefficient in layers of semiconductor lasers is proposed. Using lasers based on MOVPE-grown separate-confinement heterostructures with a broadened waveguide, the absorption coefficient is investigated under pulsed current pumping. It is found that when the pump current flows through the laser in question, an additional internal optical absorption arises in the heterostructure layers. It is shown that an increase in the pump current density up to 20 kA cm{sup -2} leads to an increase in absorption up to 2.5 cm{sup -1}. The feasibility of studying free-carrier absorption in the active region is demonstrated. (lasers)

  7. Measurement of the absorption coefficient using the sound-intensity technique

    NASA Technical Reports Server (NTRS)

    Atwal, M.; Bernhard, R.

    1984-01-01

    The possibility of using the sound intensity technique to measure the absorption coefficient of a material is investigated. This technique measures the absorption coefficient by measuring the intensity incident on the sample and the net intensity reflected by the sample. Results obtained by this technique are compared with the standard techniques of measuring the change in the reverberation time and the standing wave ratio in a tube, thereby, calculating the random incident and the normal incident adsorption coefficient.

  8. Quantifying the effect of finite spectral bandwidth on extinction coefficient of species in laser absorption spectroscopy

    NASA Astrophysics Data System (ADS)

    Singh, Manjeet; Singh, Jaswant; Singh, Baljit; Ghanshyam, C.

    2016-11-01

    The aim of this study is to quantify the finite spectral bandwidth effect on laser absorption spectroscopy for a wide-band laser source. Experimental analysis reveals that the extinction coefficient of an analyte is affected by the bandwidth of the spectral source, which may result in the erroneous conclusions. An approximate mathematical model has been developed for optical intensities having Gaussian line shape, which includes the impact of source's spectral bandwidth in the equation for spectroscopic absorption. This is done by introducing a suitable first order and second order bandwidth approximation in the Beer-Lambert law equation for finite bandwidth case. The derived expressions were validated using spectroscopic analysis with higher SBW on a test sample, Rhodamine B. The concentrations calculated using proposed approximation, were in significant agreement with the true values when compared with those calculated with conventional approach.

  9. Sound absorption coefficient in situ: an alternative for estimating soil loss factors.

    PubMed

    Freire, Rosane; Meletti de Abreu, Marco Henrique; Okada, Rafael Yuri; Soares, Paulo Fernando; GranhenTavares, Célia Regina

    2015-01-01

    The relationship between the sound absorption coefficient and factors of the Universal Soil Loss Equation (USLE) was determined in a section of the Maringá Stream basin, Paraná State, by using erosion plots. In the field, four erosion plots were built on a reduced scale, with dimensions of 2.0×12.5m. With respect to plot coverage, one was kept with bare soil and the others contained forage grass (Brachiaria), corn and wheat crops, respectively. Planting was performed without any type of conservation practice in an area with a 9% slope. A sedimentation tank was placed at the end of each plot to collect the material transported. For the acoustic system, pink noise was used in the measurement of the proposed monitoring, for collecting information on incident and reflected sound pressure levels. In general, obtained values of soil loss confirmed that 94.3% of material exported to the basin water came from the bare soil plot, 2.8% from the corn plot, 1.8% from the wheat plot, and 1.1% from the forage grass plot. With respect to the acoustic monitoring, results indicated that at 16kHz erosion plot coverage type had a significant influence on the sound absorption coefficient. High correlation coefficients were found in estimations of the A and C factors of the USLE, confirming that the acoustic technique is feasible for the determination of soil loss directly in the field.

  10. The coefficient of bond thermal expansion measured by extended x-ray absorption fine structure.

    PubMed

    Fornasini, P; Grisenti, R

    2014-10-28

    The bond thermal expansion is in principle different from the lattice expansion and can be measured by correlation sensitive probes such as extended x-ray absorption fine structure (EXAFS) and diffuse scattering. The temperature dependence of the coefficient α(bond)(T) of bond thermal expansion has been obtained from EXAFS for CdTe and for Cu. A coefficient α(tens)(T) of negative expansion due to tension effects has been calculated from the comparison of bond and lattice expansions. Negative lattice expansion is present in temperature intervals where α(bond) prevails over α(tens); this real-space approach is complementary but not equivalent to the Grüneisen theory. The relevance of taking into account the asymmetry of the nearest-neighbours distribution of distances in order to get reliable bond expansion values and the physical meaning of the third cumulant are thoroughly discussed.

  11. Absorption Coefficient Imaging by Near-Field Scanning Optical Microscopy in Bacteria

    NASA Astrophysics Data System (ADS)

    de Paula, Ana M.; Chaves, Claudilene R.; Silva, Haroldo B.; Weber, Gerald

    2003-06-01

    We present a method for obtaining a position-dependent absorption coefficient from near-field scanning optical transmission microscopy. We show that the optical transmission intensity can be combined with the topography, resulting into an absorption coefficient that simplifies the analysis of different materials within a sample. The method is tested with the dye rhodamine 6G, and we show some analysis in biological samples such as bacteria Klebsiella pneumoniae and Pseudomonas aeruginosa . The calculated absorption coefficient images show important details of the bacteria, in particular for P. aeruginosa , in which membrane vesicles are clearly seen.

  12. Absorption coefficients for water vapor at 193 nm from 300 to 1073 K

    NASA Technical Reports Server (NTRS)

    Kessler, W. J.; Carleton, K. L.; Marinelli, W. J.

    1993-01-01

    Measurements of the water absorption coefficient at 193 nm from 300 to 1073 K are reported. The measurements were made using broadband VUV radiation and a monochromator-based detection system. The water vapor was generated by a saturator and metered into a flowing, 99 cm absorption cell via a water vapor mass flow meter. The 193 nm absorption coefficient measurements are compared to room temperature and high temperature shock tube measurements with good agreement. The absorption can be parameterized by a nu3 vibrational mode reaction coordinate and the thermal population of the nu3 mode.

  13. Measuring absorption coefficient of scattering liquids using a tube inside an integrating sphere.

    PubMed

    Villanueva, Yolanda; Veenstra, Colin; Steenbergen, Wiendelt

    2016-04-10

    A method for measuring the absorption coefficient μa of absorbing and scattering liquid samples is presented. The sample is injected into a small transparent tube mounted through an integrating sphere. Two models for determining the absorption coefficient using the relative optical output signal are described and validated using aqueous ink absorbers of 0.5 vol.% (0.3  mm-1a<1.55  mm-1) and 1.0 vol.% (1.0  mm-1a<4.0  mm-1) concentrations with 1 vol.% (μs'≈1.4  mm-1) and 10 vol.% (μs'≈14  mm-1) Intralipid dilutions. The low concentrations give μa and μs values, which are comparable with those of biological tissues. One model assumes a uniform light distribution within the sample, which is valid for low absorption. Another model considers light attenuation that obeys Lambert-Beer's law, which may be used for relatively high absorption. Measurements with low and high scattering samples are done for the wavelength range of 400-900 nm. Measured spectra of purely absorbing samples are within 15% agreement with measurements using standard transmission spectrophotometry. For 0.5 vol.% ink absorbers and at wavelengths below 700 nm, measured μa values are higher for samples with low scattering and lower for those with high scattering. At wavelengths above 700 nm, measured μa values do not vary significantly with amount of scattering. For 1.0 vol.% ink absorbers, measured spectra do not change with low scattering. These results indicate that the method can be used for measuring absorption spectra of scattering liquid samples with optical properties similar to biological absorbers, particularly at wavelengths above 700 nm, which is difficult to accomplish with standard transmission spectrophotometry.

  14. Visible and Near Infrared Absorption Coefficients of Kaolinite and Related Clays.

    DTIC Science & Technology

    propagation of light. This work is intended to provide a quantitative estimate of the absorption coefficient of kaolinite clays by application of a method based on the Kubelka - Munk theory of diffuse reflectance.

  15. A method for determination mass absorption coefficient of gamma rays by Compton scattering.

    PubMed

    El Abd, A

    2014-12-01

    A method was proposed for determination mass absorption coefficient of gamma rays for compounds, alloys and mixtures. It is based on simulating interaction processes of gamma rays with target elements having atomic numbers from Z=1 to Z=92 using the MCSHAPE software. Intensities of Compton scattered gamma rays at saturation thicknesses and at a scattering angle of 90° were calculated for incident gamma rays of different energies. The obtained results showed that the intensity of Compton scattered gamma rays at saturations and mass absorption coefficients can be described by mathematical formulas. These were used to determine mass absorption coefficients for compound, alloys and mixtures with the knowledge of their Compton scattered intensities. The method was tested by calculating mass absorption coefficients for some compounds, alloys and mixtures. There is a good agreement between obtained results and calculated ones using WinXom software. The advantages and limitations of the method were discussed.

  16. Satellite retrieval of the absorption coefficient of phytoplankton phycoerythrin pigment: theory and feasibility status.

    PubMed

    Hoge, F E; Wright, C W; Lyon, P E; Swift, R N; Yungel, J K

    1999-12-20

    Oceanic radiance model inversion methods are used to develop a comprehensive algorithm for retrieval of the absorption coefficients of phycourobilin (PUB) pigment, type I phycoerythrobilin (PEB) pigment rich in PUB, and type II PEB deficient in PUB pigment (together with the usual "big three" inherent optical properties: the total backscattering coefficient and the absorption coefficients of chromophoric dissolved organic matter (CDOM)-detritus and phytoplankton). This fully modeled inversion algorithm is then simplified to yield a hybrid modeled-unmodeled inversion algorithm in which the phycoerythrin (PE) absorption coefficient is retrieved as unmodeled 488-nm absorption (which exceeds the modeled phytoplankton and the CDOM-detritus absorption coefficients). Each algorithm was applied to water-leaving radiances, but only hybrid modeled-unmodeled inversions yielded viable retrievals of the PE absorption coefficient. Validation of the PE absorption coefficient retrieval was achieved by relative comparison with airborne laser-induced PEB fluorescence. The modeled-unmodeled retrieval of four inherent optical properties by direct matrix inversion is rapid and well conditioned, but the accuracy is strongly limited by the accuracy of the three principal inherent optical property models across all four spectral bands. Several research areas are identified to enhance the radiance-model-based retrievals: (a) improved PEB and PUB absorption coefficient models, (b) PE spectral shifts induced by PUB chromophore substitution at chromophore binding sites, (c) specific absorption-sensitive phytoplankton absorption modeling, (d) total constituent backscattering modeling, (e) unmodeled carotinoid and phycocyanin absorption that are not now accounted for in the chlorophyll-dominated phytoplankton absorption coefficient model, and (f) iterative inversion techniques to solve for six constituents with only five radiances. Although considerable progress has been made toward the

  17. Effect of absorption parameters on calculation of the dose coefficient: example of classification of industrial uranium compounds.

    PubMed

    Chazel, V; Houpert, P; Paquet, F; Ansoborlo, E

    2001-01-01

    In the Human Respiratory Tract Model (HRTM) described in ICRP Publication 66, time-dependent dissolution is described by three parameters: the fraction dissolved rapidly, fr, and the rapid and slow dissolution rates sr and ss. The effect of these parameters on the dose coefficient has been studied. A theoretical analysis was carried out to determine the sensitivity of the dose coefficient to variations in the values of these absorption parameters. Experimental values of the absorption parameters and the doses per unit intake (DPUI) were obtained from in vitro dissolution tests, or from in vivo experiments with rats, for five industrial uranium compounds UO2, U3O8, UO4, UF4 and a mixture of uranium oxides. These compounds were classified in terms of absorption types (F, M or S) according to ICRP. The overall result was that the factor which has the greatest influence on the dose coefficient was the slow dissolution rate ss. This was verified experimentally, with a variation of 20% to 55% for the DPUI according to the absorption type of the compound. In contrast, the rapid dissolution rate sr had little effect on the dose coefficient, excepted for Type F compounds.

  18. Influence of plasma parameters on the absorption coefficient of alpha particles to lower hybrid waves in tokamaks

    SciTech Connect

    Wang, J.; Zhang, X. Yu, L.; Zhao, X.

    2014-12-15

    In tokamaks, fusion generated α particles may absorb lower hybrid (LH) wave energy, thus reducing the LH current drive efficiency. The absorption coefficient γ{sub α} of LH waves due to α particles changing with some typical parameters is calculated in this paper. Results show that γ{sub α} increases with the parallel refraction index n{sub ‖}, while decreases with the frequency of LH waves ω over a wide range. Higher background plasma temperature and toroidal magnetic field will increase the absorption. The absorption coefficient γ{sub α} increases with n{sub e} when n{sub e} ≤ 8 × 10{sup 19} m{sup −3}, while decreases with n{sub e} when n{sub e} becomes larger, and there is a peak value of γ{sub α} when n{sub e} ≈ 8 × 10{sup 19} m{sup −1} for the ITER-like scenario. The influence of spectral broadening in parametric decay instabilities on the absorption coefficient is evaluated. The value of γ{sub α} with n{sub ‖} being 2.5 is almost two times larger than that with n{sub ‖} being 2.0 and is even lager in the case of 2.9, which will obviously increase the absorption of the LH power by alpha particles.

  19. Experiment to Determine the Absorption Coefficient of Gamma Rays as a Function of Energy.

    ERIC Educational Resources Information Center

    Ouseph, P. J.; And Others

    1982-01-01

    Simpler than x-ray diffractometer experiments, the experiment described illustrates certain concepts regarding the interaction of electromagnetic rays with matter such as the exponential decrease in the intensity with absorber thickness, variation of the coefficient of absorption with energy, and the effect of the K-absorption edge on the…

  20. Determination of absorption coefficients in AlInP lattice matched to GaAs

    NASA Astrophysics Data System (ADS)

    Cheong, J. S.; Ng, J. S.; Krysa, A. B.; Ong, J. S. L.; David, J. P. R.

    2015-10-01

    The absorption properties of Al0.52In0.48P have been investigated near the fundamental absorption edge by measuring the photocurrent as a function of wavelength in a series of PIN and NIP diodes. Modelling of the photocurrent in these structures enables the absorption coefficients to be determined accurately over a wide dynamic range, which allows the direct and indirect band-gap to be determined.

  1. Tunable diode laser measurements of HO2NO2 absorption coefficients near 12.5 microns

    NASA Technical Reports Server (NTRS)

    May, R. D.; Molina, L. T.; Webster, C. R.

    1988-01-01

    A tunable diode laser spectrometer has been used to measure absorption coefficients of peroxynitric acid (HO2NO2) near the 803/cm Q branch. HO2NO2 concentrations in a low-pressure flowing gas mixture were determined from chemical titration procedures and UV absorption spectroscopy. The diode laser measured absorption coefficients, at a spectral resolution of better than 0.001/cm, are about 10 percent larger than previous Fourier transform infrared measurements made at a spectral resolution of 0.06/cm.

  2. Remote-Sensing Technique for Determination of the Volume Absorption Coefficient of Turbid Water

    NASA Astrophysics Data System (ADS)

    Sydor, Michael; Arnone, Robert A.; Gould, Richard W., Jr.; Terrie, Gregory E.; Ladner, Sherwin D.; Wood, Christoper G.

    1998-07-01

    We use remote-sensing reflectance from particulate R rs to determine the volume absorption coefficient a of turbid water in the 400 700-nm spectral region. The calculated and measured values of a ( ) show good agreement for 0 . 5 a 10 (m 1 ). To determine R rs from a particulate, we needed to make corrections for remote-sensing reflectance owing to surface roughness S rs . We determined the average spectral distribution of S rs from the difference in total remote-sensing reflectance measured with and without polarization. The spectral shape of S rs showed an excellent fit to theoretical formulas for glare based on Rayleigh and aerosol scattering from the atmosphere.

  3. The Optical Absorption Coefficient of Maize Grains Investigated by Photoacoustic Spectroscopy

    NASA Astrophysics Data System (ADS)

    Rodríguez-Páez, C. L.; Carballo-Carballo, A.; Rico-Molina, R.; Hernández-Aguilar, C.; Domínguez-Pacheco, A.; Cruz-Orea, A.; Moreno-Martínez, E.

    2017-01-01

    In the maize and tortilla industry, it is important to characterize the color of maize ( Zea mays L.) grain, as it is one of the attributes that directly affect the quality of the tortillas consumed by the population. For this reason, the availability of alternative techniques for assessing and improving the quality of grain is valued. Photoacoustic spectroscopy has proven to be a useful tool for characterizing maize grain. So, the objective of the present study was to determine the optical absorption coefficient β of the maize grain used to make tortillas from two regions of Mexico: (a) Valles Altos, 2012-2013 production cycle and (b) Guasave, Sinaloa, 2013-2014 production cycle. Traditional reflectance measurements, physical characteristics of the grain and nutrient content were also calculated. The experimental results show different characteristics for maize grains.

  4. [Extracting THz absorption coefficient spectrum based on accurate determination of sample thickness].

    PubMed

    Li, Zhi; Zhang, Zhao-hui; Zhao, Xiao-yan; Su, Hai-xia; Yan, Fang

    2012-04-01

    Extracting absorption spectrum in THz band is one of the important aspects in THz applications. Sample's absorption coefficient has a complex nonlinear relationship with its thickness. However, as it is not convenient to measure the thickness directly, absorption spectrum is usually determined incorrectly. Based on the method proposed by Duvillaret which was used to precisely determine the thickness of LiNbO3, the approach to measuring the absorption coefficient spectra of glutamine and histidine in frequency range from 0.3 to 2.6 THz(1 THz = 10(12) Hz) was improved in this paper. In order to validate the correctness of this absorption spectrum, we designed a series of experiments to compare the linearity of absorption coefficient belonging to one kind amino acid in different concentrations. The results indicate that as agreed by Lambert-Beer's Law, absorption coefficient spectrum of amino acid from the improved algorithm performs better linearity with its concentration than that from the common algorithm, which can be the basis of quantitative analysis in further researches.

  5. IR Absorption Coefficients for the Quantification of Water in Hydrous Ringwoodite

    NASA Astrophysics Data System (ADS)

    Thomas, S.; Jacobsen, S. D.; Bina, C. R.; Smyth, J. R.; Frost, D. J.

    2009-12-01

    Raman spectroscopy, combined with the ‘Comparator technique’ has been developed to determine water contents ranging from a few wt ppm to wt% in glasses and nominally anhydrous minerals including garnets, olivine, and SiO2 polymorphs (Thomas et al. 2009). The routine is one promising example of quantification tools to determine mineral specific molar absorption coefficients (ɛ) for IR spectroscopy. Mineral specific absorption coefficients are required because general IR calibrations do not necessarily apply to minerals with water incorporated as hydroxyl point defects. Here we utilize the ‘Comparator technique’ to provide ɛ-values for a set of synthetic Fe-free and Fe-bearing (Fo90) ringwoodites, as well as for γ-Mg2GeO4. Ringwoodite is considered one of the major phases of the Earth’s lower transition zone (520-660 km depth) and the knowledge of its absolute water storage capacity is essential for modeling the Earth’s deep water cycle. Samples were synthesized at variable P-T conditions in a multi-anvil press and cover a range of OH contents. Single-crystals were characterized using X-ray diffraction and IR spectroscopy. Mineral specific IR absorption coefficients were calculated from independently determined water contents from Raman spectroscopy. Unpolarized IR spectra of Mg-ringwoodite show broad absorption features in the OH region with band maxima at ~2350, 2538, 3127, 3172, 3598 and 3688 cm-1. In the spectra of Fe-bearing ringwoodite and γ-Mg2GeO4 the maxima of the main OH band are shifted to 3172 cm-1 and 3207 cm-1, respectively. For Mg-ringwoodite with the mean wavenumber (area-weighted average of the peak position) of 3109 cm-1 an ɛ-value of 170000 ± 51000 L cm-2 / molH2O was determined. For a Fo90 sample with the mean wavenumber of 3132 cm-1 the value was calculated to be 123000 ± 37000 L cm-2 / molH2O. The latter two values are in good agreement with the data from the linear calibration of ~159000 L cm-2 / molH2O and ~153000 L cm-2

  6. Nonlinear absorption coefficient of pulsed laser deposited MgZnO thin film

    SciTech Connect

    Agrawal, Arpana Dar, Tanveer A.; Solanki, Ravi; Sen, Pratima; Phase, D. M.

    2015-06-24

    We report the imaginary part of 3{sup rd} order nonlinear susceptibility and the nonlinear absorption coefficient of Mg doped ZnO thin film using standard Z-scan technique. The origin of nonlinear absorption is attributed to the two photon absorption followed by the free carrier absorption because of the presence of oxygen vacancy defects. We have also confirmed the experimental results with the theoretical results obtained by considering the steady state response of a two level atom with the monochromatic field models.

  7. Assessing Absorption Coefficient of Hemoglobin in the Breast Phantom Using Near-Infrared Spectroscopy

    PubMed Central

    Mehnati, Parinaz; Jafari Tirtash, Maede; Zakerhamidi, Mohammad Sadegh; Mehnati, Parisa

    2016-01-01

    Background Blood concentrations and oxygen saturation levels are important biomarkers for breast cancer diagnosis. Objectives In this study, the absorption coefficient of hemoglobin (Hb) was used to distinguish between normal and abnormal breast tissue. Materials and Methods A near-infrared source (637 nm) was transmitted from major and minor vessels of a breast phantom containing 2×, 4× concentrations of oxy- and deoxy-Hb. The absorption coefficients were determined from spectrometer (SM) and powermeter (PM) data. Results The absorption coefficients were 0.075 ± 0.026 cm-1 for oxygenated Hb (normal) in major vessels and 0.141 ± 0.023 cm-1 at 4× concentration (abnormal) with SM, whereas the breast absorption coefficients were 0.099 ± 0.017 cm-1 for oxygenated Hb (normal) in minor vessels and 0.171 ± 0.005 cm-1 at 4× concentrations with SM. A comparison of the data obtained using a SM and a PM was not significant statistically. Conclusion The study of the absorption coefficient data of different concentrations of Hb in normal and abnormal breasts via the diffusion of near-infrared light is a valuable method and has the potential to aid in early detection of breast abnormalities with SM and PM in major and minor vessels. PMID:27895869

  8. Influence of the scattering and absorption coefficients on homogeneous room simulations that use a diffusion equation model.

    PubMed

    Navarro, Juan M; Escolano, José; Cobos, Maximo; López, José J

    2013-03-01

    The diffusion equation model was used for room acoustic simulations to predict the sound pressure level and the reverberation time. The technical literature states that the diffusion equation method accurately models the late portion of the room impulse response if the energy is sufficiently scattered. This work provides conclusions on the validity of the diffusion equation model for rooms with homogeneous dimensions in relation to the scattering coefficients of the boundaries. A systematic evaluation was conducted out to determine the ranges of the absorption and scattering coefficient values that result in low noticeable differences between the predictions from a geometrical acoustic model and those from the diffusion equation model.

  9. Study of the absorption coefficient of alpha particles to lower hybrid waves in tokamak

    SciTech Connect

    Wang, Jianbing Zhang, Xianmei Yu, Limin Zhao, Xiang

    2014-02-12

    Part of the energy of the Lower Hybrid (LH) waves may be absorbed by the α particles via the so-called perpendicular landau damping mechanism, which depends on various parameters of fusion reactors and the LH waves. In this article, we calculate the absorption coefficient γ{sub α} of LH waves due to α particles. Results show that, the γ{sub α} increases with the parallel refraction index n{sub ∥} while deceases with increasing the frequency of LH waves ω{sub LH} over a wide range. Higher background plasma temperature and toroidal magnetic field will increase the absorption, and there is a peak value of γ{sub α} when n{sub e}≈8×10{sup 19}m{sup −3} for ITER-like scenario. The thermal corrections to the cold plasma dispersion relation will change the damping rate to a certain extent under some specific conditions. We have also evaluated the fraction of LH power absorbed by the alpha particles, η ≈ 0.47% and 4.1% for an LH frequency of 5 GHz and 3.7 GHz respectively for ITER-like scenario. This work gives the effective reference for the choice of parameters of future fusion reactors.

  10. A numerical study of a method for measuring the effective in situ sound absorption coefficient.

    PubMed

    Kuipers, Erwin R; Wijnant, Ysbrand H; de Boer, André

    2012-09-01

    The accuracy of a method [Wijnant et al., Proc. of ISMA 31, Leuven, Belgium (2010), Vol. 31] for measurement of the effective area-averaged in situ sound absorption coefficient is investigated. Based on a local plane wave assumption, this method can be applied to sound fields for which a model is not available. Investigations were carried out by means of finite element simulations for a typical case. The results show that the method is a promising method for determining the effective area-averaged in situ sound absorption coefficient in complex sound fields.

  11. Measurement of optical absorption coefficient of bio-tissue at 532nm wavelength

    NASA Astrophysics Data System (ADS)

    Huang, Chuyun; Li, Zhengjia; Yao, Yucheng; He, Yanyan

    2007-05-01

    Laser technology has succeeded in medical application. High power 532nm laser has applied in prostate ablation and other clinic application. To understand optical property of bio-tissue at 532nm wavelength, a method of monitoring surface temperature was used to measure absorption coefficient of gall-stone, porcine liver and canine prostate. The absorption coefficient of gall-stone is about 62cm -1 at 532nm wavelength, and those of porcine liver and canine prostate are about 13cm -1 and 5.4cm -1, respectively. These results help to understand the optical property of bio-tissue and offer theoretic reference for optical dosimetry in clinic application.

  12. In vivo light fluence correction for determination of tissue absorption coefficient using Multispectral Optoacoustic Tomography

    NASA Astrophysics Data System (ADS)

    Brochu, Frederic M.; Joseph, James; Tomaszewski, Michal R.; Bohndiek, Sarah E.

    2016-03-01

    Optoacoustic Tomography is a fast developing imaging modality, combining the high resolution and penetration depth of ultrasound detection with the high contrast available from optical absorption in tissue. The spectral profile of near infrared excitation light used in optoacoustic tomography instruments is modified by absorption and scattering as it propagates deep into biological tissue. The resulting images therefore provide only qualitative insight into the distribution of tissue chromophores. Knowledge of the spectral profile of excitation light across the mouse is needed for accurate determination of the absorption coefficient in vivo. Under the conditions of constant Grueneisen parameter and accurate knowledge of the light fluence, a linear relationship should exist between the initial optoacoustic pressure amplitude and the tissue absorption coefficient. Using data from a commercial optoacoustic tomography system, we implemented an iterative optimization based on the σ-Eddington approximation to the Radiative Transfer Equation to derive a light fluence map within a given object. We segmented the images based on the positions of phantom inclusions, or mouse organs, and used known scattering coefficients for initialization. Performing the fluence correction in simple phantoms allowed the expected linear relationship between recorded and independently measured absorption coefficients to be retrieved and spectral coloring to be compensated. For in vivo data, the correction resulted in an enhancement of signal intensities in deep tissues. This improved our ability to visualize organs at depth (> 5mm). Future work will aim to perform the optimization without data normalization and explore the need for methodology that enables routine implementation for in vivo imaging.

  13. Normative Apparent Diffusion Coefficient Values in the Developing Fetal Brain

    PubMed Central

    Schneider, M.M.; Berman, J.I.; Baumer, F.M.; Glass, H.C.; Jeng, S.; Jeremy, R.J.; Esch, M.; Biran, V.; Barkovich, A.J.; Studholme, C.; Xu, D.; Glenn, O.A.

    2013-01-01

    BACKGROUND AND PURPOSE Previous studies of diffusion-weighted imaging (DWI) in fetuses are limited. Because of the need for normative data for comparison with young fetuses and preterm neonates with suspected brain abnormalities, we studied apparent diffusion coefficient (ADC) values in a population of singleton, nonsedated, healthy fetuses. MATERIALS AND METHODS DWI was performed in 28 singleton nonsedated fetuses with normal or questionably abnormal results on sonography and normal fetal MR imaging results; 10 fetuses also had a second fetal MR imaging, which included DWI. ADC values in the periatrial white matter (WM), frontal WM, thalamus, basal ganglia, cerebellum, and pons were plotted against gestational age and analyzed with linear regression. We compared mean ADC in different regions using the Tukey Honestly Significant Difference test. We also compared rates of decline in ADC with increasing gestational age across different areas by using the t test with multiple comparisons correction. Neurodevelopmental outcome was assessed. RESULTS Median gestational age was 24.28 weeks (range, 21–33.43 weeks). Results of all fetal MR imaging examinations were normal, including 1 fetus with a normal variant of a cavum velum interpositum. ADC values were highest in the frontal and periatrial WM and lowest in the thalamus and pons. ADC declined with increasing gestational age in periatrial WM (P = .0003), thalamus (P < .0001), basal ganglia (P = .0035), cerebellum (P < .0001), and pons (P = .024). Frontal WM ADC did not significantly change with gestational age. ADC declined fastest in the cerebellum, followed by the thalamus. CONCLUSIONS Regional differences in nonsedated fetal ADC values and their evolution with gestational age likely reflect differences in brain maturation and are similar to published data in premature neonates. PMID:19556350

  14. Determination of Absorption and Scattering Coefficients for Nonhomogeneous Media: II. Experiment.

    DTIC Science & Technology

    prepared from a glass of known absorption coefficient variation. The new model produces an accuracy inprovement up to a factor of 2.5 over the Kubelka ... Munk theory. Off-axis scattering measurements were made with improved instrumentation between 0.33 and 2.7 micrometers. The model was then applied to

  15. Calibration of an integrating sphere for determining the absorption coefficient of scattering suspensions.

    PubMed

    Nelson, N B; Prézelin, B B

    1993-11-20

    Measuring the absolute absorption of suspensions of absorbing particles with unknown scattering characteristics is not possible in conventional spectrophotometers or in integrating spheres that have the sample located outside the sphere. A method for the calibration and use of an integrating sphere with a centrally located sample to measure absolute absorption coefficients of scattering suspensions is presented. Under the tested conditions the integrating sphere used in this study was insensitive to changes in the scattering coefficient of the sample but had a nonlinear response to increasing absorption of the sample, which could be corrected with an empirically derived function. This response was analyzed by using a Monte Carlo simulation, and results indicated that amplification of the absorption signal was primarily due to photons reflected from the sphere surface and the baffle reentering the cuvette. The calibration procedure described here may be generally applicable to spheres of different configurati n. An example of the use of the sphere for determining the absorption and scattering coefficients of marine phytoplankton samples is presented.

  16. [Development of a photoacoustic spectroscopy system for the measurement of absorption coefficient of atmospheric aerosols].

    PubMed

    Liu, Qiang; Niu, Ming-Sheng; Wang, Gui-Shi; Cao, Zhen-Song; Liu, Kun; Chen, Wei-Dong; Gao, Xiao-Ming

    2013-07-01

    In the present paper, the authors focus on the effect of the resonance frequency shift due to the changes in temperature and humidity on the PA signal, present several methods to control the noise derived form gas flow and vibration from the sampling pump. Based on the efforts mentioned above, a detection limit of 1.4 x 10(-8) W x cm(-1) x Hz(-1/2) was achieved for the measurement of atmospheric aerosols absorption coefficient. During the experiments, the PA cell was calibrated with the absorption of standard NO2 gas at 532 nm and the atmospheric aerosols were measured continuously. The measurement results show that the PAS is suitable for the real-time measurement of the absorption coefficient of atmospheric aerosols in their natural suspended state.

  17. Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime.

    PubMed

    Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Wang, Lihong V

    2012-06-01

    Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of <3%. We also quantified the total hemoglobin concentration and hemoglobin oxygen saturation in a live mouse. Compared with the conventional amplitude method, the acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed.

  18. Additions and corrections to the absorption coefficients of CO2 ice - Applications to the Martian south polar cap

    NASA Technical Reports Server (NTRS)

    Calvin, Wendy M.

    1990-01-01

    Reflectance spectra of carbon dioxide frosts were calculated using the optical constants provided by Warren (1986) for the wavelength region 2-6 microns. In comparing these calculated spectra to spectra of frosts observed in the laboratory and on the surface of Mars, problems in the optical constants presented by Warren (1986) became apparent. Absorption coefficients for CO2 ice have been derived using laboratory reflectance measurements and the Hapke (1981) model for calculating diffuse reflectance. This provides approximate values in regions where no data were previously available and indicates where corrections to the compilation by Warren (1986) are required. Using these coefficients to calculate the reflectance of CO2 ice at varying grain sizes indicates that a typical Mariner polar cap spectrum is dominated by absorptions due to CO2 frost or ice at grain sizes that are quite large, probably of the order of millimeters to centimeters. There are indications of contamination of water frost or dust, but confirmation will require more precise absorption coefficients for solid CO2 than can be obtained from the method used here.

  19. Specific absorption coefficient and phytoplankton biomass in the southern region of the California Current

    NASA Astrophysics Data System (ADS)

    Millán-Núñez, Eduardo; Sieracki, Michael E.; Millán-Núñez, Roberto; Lara-Lara, José Rubén; Gaxiola-Castro, Gilberto; Trees, Charles C.

    2004-03-01

    In recent years, experts of optical hydrology have shown great interest in the variability of the specific absorption coefficient of light by phytoplankton (aph*). This parameter is important and necessary for comparing in situ bio-optical and satellite optical measurements. Such comparisons are needed for detecting primary productivity at a mesoscale level. At present, however, the parameters used in algorithms for predicting productivity are global averages. To avoid this bias, we measured the spatial-temporal variability of aph* as part of the Jan-01 Investigaciones Mexicanas de la Corriente de California cruise along the southern California Current. We observed median values of 0.041 m2 (mg chlorophyll a (Chl a))-1 at 440 nm and 0.015 at 674 nm, with significant differences between inshore and offshore stations. In general, the stations located in the area of Bahía Vizcaíno, with oceanographic conditions favorable for the growth of phytoplankton, showed lower values of the aph* . The nano-microphytoplankton (>5 μm) community comprised of 26 diatom genera with mean abundance values of the 19.5×103 cells l-1. Nitzschia closterium, a pennate diatom, was almost uniform throughout the study region. Flow cytometry measurements indicated that the picoplankton (<5 μm) community consisted of two prokaryotes, Prochlorococcus (mean 3.6×106 cells l-1) and Synechococcus (mean 10.4×106 cells l-1), and a mixture of picoeukaryotes (mean 6.5×106 cells l-1). Analyses of Chl and carotenoid pigments determined by high-performance liquid chromatographic confirmed the presence of the divinyl Chl a characteristic of Prochlorococcus. The nano-micro- and picoplankton were 82% and 18% of total phytoplankton biomass (μg C l-1), respectively. In general, we concluded that the phytoplankton community structure and biomass on this cruise showed conditions similar to oligotrophic systems.

  20. Noise-driven optical absorption coefficients of impurity doped quantum dots

    NASA Astrophysics Data System (ADS)

    Ganguly, Jayanta; Saha, Surajit; Pal, Suvajit; Ghosh, Manas

    2016-01-01

    We make an extensive investigation of linear, third-order nonlinear, and total optical absorption coefficients (ACs) of impurity doped quantum dots (QDs) in presence and absence of noise. The noise invoked in the present study is a Gaussian white noise. The quantum dot is doped with repulsive Gaussian impurity. Noise has been introduced to the system additively and multiplicatively. A perpendicular magnetic field acts as a source of confinement and a static external electric field has been applied. The AC profiles have been studied as a function of incident photon energy when several important parameters such as optical intensity, electric field strength, magnetic field strength, confinement energy, dopant location, relaxation time, Al concentration, dopant potential, and noise strength take on different values. In addition, the role of mode of application of noise (additive/multiplicative) on the AC profiles has also been analyzed meticulously. The AC profiles often consist of a number of interesting observations such as one photon resonance enhancement, shift of AC peak position, variation of AC peak intensity, and bleaching of AC peak. However, presence of noise alters the features of AC profiles and leads to some interesting manifestations. Multiplicative noise brings about more complexity in the AC profiles than its additive counterpart. The observations indeed illuminate several useful aspects in the study of linear and nonlinear optical properties of doped QD systems, specially in presence of noise. The findings are expected to be quite relevant from a technological perspective.

  1. Light fluence correction for quantitative determination of tissue absorption coefficient using multi-spectral optoacoustic tomography

    NASA Astrophysics Data System (ADS)

    Brochu, Frederic M.; Joseph, James; Tomaszewski, Michal; Bohndiek, Sarah E.

    2015-07-01

    MultiSpectral Optoacoustic Tomography (MSOT) is a fast developing imaging modality, combining the high resolution and penetration depth of ultrasound with the excellent contrast from optical imaging of tissue. Absorption and scattering of the near infrared excitation light modulates the spectral profile of light as it propagates deep into biological tissue, meaning the images obtained provide only qualitative insight into the distribution of tissue chromophores. The goal of this work is to accurately recover the spectral profile of excitation light by modelling light fluence in the data reconstruction, to enable quantitative imaging. We worked with a commercial small animal MSOT scanner and developed our light fluence correction for its' cylindrical geometry. Optoacoustic image reconstruction pinpoints the sources of acoustic waves detected by the transducers and returns the initial pressure amplitude at these points. This pressure is the product of the dimensionless Grüneisen parameter, the absorption coefficient and the light fluence. Under the condition of constant Grüneisen parameter and well modelled light fluence, there is a linear relationship between the initial pressure amplitude measured in the optoacoustic image and the absorption coefficient. We were able to reproduce this linear relationship in different physical regions of an agarose gel phantom containing targets of known optical absorption coefficient, demonstrating that our light fluence model was working. We also demonstrate promising results of light fluence correction effects on in vivo data.

  2. Diffuse reflectance spectroscopy as a tool to measure the absorption coefficient in skin: system calibration.

    PubMed

    Karsten, A E; Singh, A; Karsten, P A; Braun, M W H

    2013-02-01

    An individualised laser skin treatment may enhance the treatment and reduces risks and side-effects. The optical properties (absorption and scattering coefficients) are important parameters in the propagation of laser light in skin tissue. The differences in the melanin content of different skin phototypes influence the absorption of the light. The absorption coefficient at the treatment wavelength for an individual can be determined by diffuse reflectance spectroscopy, using a probe containing seven fibres. Six of the fibres deliver the light to the measurement site and the central fibre collects the diffused reflected light. This is an in vivo technique, offering benefits for near-real-time results. Such a probe, with an effective wavelength band from 450 to 800 nm, was used to calibrate skin-simulating phantoms consisting of intralipid and ink. The calibration constants were used to calculate the absorption coefficients from the diffuse reflectance measurements of three volunteers (skin phototypes, II, IV and V) for sun-exposed and non-exposed areas on the arm.

  3. Absorption Coefficients of Particulate Matter off the Southwest Coast of Europe: A Contribution to Validation of the MERIS Sensor

    NASA Astrophysics Data System (ADS)

    Goela, P.; Icely, J.; Cristina, S.; Newton, A.

    2010-12-01

    Variability of particulate absorption coefficients was studied off the south-west coast of Portugal, as part of a validation exercise for the Medium Resolution Image Spectrometer Sensor. Regular sampling campaigns occurred at three stations on a transect from inshore to offshore to compare fluctuations in these coefficients at the local scale. Transmittance-reflectance method with sodium hypochlorite bleaching was used to determine absorption coefficients for phytoplankton and non-algal particles. Photosynthetic pigment concentrations were determined by High Performance Liquid Chromatography. Results show that the absorption of light by particulate matter is almost totally dependent on the phytoplankton, with no significant contribution from non-algal particles, both in coastal and oceanic waters. Specific phytoplankton coefficients show significant fluctuations between seasons and stations, ranging from 0.012 to 0.038 at 678 nm. Particulate absorption is dominant over dissolved absorption. The variations in the coefficients of absorption are analysed as a function of species assemblages.

  4. Parameterization of the Mie Extinction and Absorption Coefficients for Water Clouds.

    NASA Astrophysics Data System (ADS)

    Mitchell, David L.

    2000-05-01

    It was found that the anomalous diffraction approximation (ADA) could be made to approximate Mie theory for absorption and extinction in water clouds by parameterizing the missing physics: 1) internal reflection/refraction, 2) photon tunneling, and 3) edge diffraction. Tunneling here refers to processes by which tangential or grazing photons beyond the physical cross section of a spherical particle may be absorbed. Contributions of the above processes to extinction and/or absorption were approximated in terms of particle size, index of refraction, and wavelength. It was found that tunneling can explain most of the difference between ADA and Mie theory for water clouds in the thermal IR.The modified ADA yielded analytical expressions for the absorption and extinction efficiencies, Qabs and Qext, which were integrated over a gamma size distribution to yield expressions for the absorption and extinction coefficients, abs and ext. These coefficients were expressed in terms of the three gamma distribution parameters, which were related to measured properties of the size distribution: liquid water content, mean, and mass-median diameter. Errors relative to Mie theory for abs and ext were generally 10% for the effective radius range in water clouds of 5-30 m, for any wavelength in the solar or terrestrial spectrum. For broadband emissivities and absorptivities regarding terrestrial and solar radiation, the errors were less than 1.2% and 4%, respectively. The modified ADA dramatically reduces computation times relative to Mie theory while yielding reasonably accurate results.

  5. Thin-film absorption coefficients by attenuated-total-reflection spectroscopy.

    PubMed

    Holm, R T; Palik, E D

    1978-02-01

    The application of attenuated-total-reflection spectroscopy to the measurement of the absorption coefficient of thin films is presented. For low absorption the sensitivity of ATR is discussed in terms of the concept of an effective thickness. Both the case in which the refractive index of the film is higher and the case in which it is lower than that of the ATR trapezoid are considered. Experimental ATR data for antireflection-coating materials for laser windows is analyzed and compared with calorimetric data.

  6. Measurement and calculation of the sound absorption coefficient of pine wood charcoal

    NASA Astrophysics Data System (ADS)

    Suh, Jae Gap; Baik, Kyung min; Kim, Yong Tae; Jung, Sung Soo

    2013-10-01

    Although charcoal has been widely utilized for physical therapy and as a deodorant, water purifier, etc. due to its porous features, research on its role as a sound-absorbing material is rarely found. Thus, the sound absorption coefficients of pine wood charcoal were measured using an impedance tube and were compared with the theoretical predictions in the frequency range of 500˜ 5000 Hz. The theory developed in the current study only considers the lowest possible mode propagating along the air channels of the charcoal and shows good agreements with the measurements. As the frequency is increased, the sound absorption coefficients of pine wood charcoals also increase, but are lower than those of other commonly-used sound-absorbing materials.

  7. Simultaneous retrieval of temperature-dependent absorption coefficient and conductivity of participating media

    PubMed Central

    Ren, Yatao; Qi, Hong; Zhao, Fangzhou; Ruan, Liming; Tan, Heping

    2016-01-01

    A secondary optimization technique was proposed to estimate the temperature-dependent thermal conductivity and absorption coefficient. In the proposed method, the stochastic particle swarm optimization was applied to solve the inverse problem. The coupled radiation and conduction problem was solved in a 1D absorbing, emitting, but non-scattering slab exposed to a pulse laser. It is found that in the coupled radiation and conduction problem, the temperature response is highly sensitive to conductivity but slightly sensitive to the optical properties. On the contrary, the radiative intensity is highly sensitive to optical properties but slightly sensitive to thermal conductivity. Therefore, the optical and thermal signals should both be considered in the inverse problem to estimate the temperature-dependent properties of the transparent media. On this basis, the temperature-dependent thermal conductivity and absorption coefficient were both estimated accurately by measuring the time-dependent temperature, and radiative response at the boundary of the slab. PMID:26912418

  8. Infrared absorption-coefficient data on SF6 applicable to atmospheric remote sensing

    NASA Technical Reports Server (NTRS)

    Varanasi, P.; Gopalan, A.; Brannon, J. F., Jr.

    1992-01-01

    Spectral absorption coefficients, k(nu)/cm per atm, of SF6 have been measured in the central Q-branches of the nu(3)-fundamental at 947/cm at various temperature-pressure combinations representing tangent heights in solar-occultation experiments or layers in the atmosphere. The data obtained with the Doppler-limited spectral resolution (about 0.0001/cm) of a tunable-diode laser spectrometer are useful in the atmospheric remote sensing of this trace gas.

  9. Methane absorption coefficients for the jovian planets from laboratory, Huygens, and HST data

    NASA Astrophysics Data System (ADS)

    Karkoschka, Erich; Tomasko, Martin G.

    2010-02-01

    We use 11 data sets of methane transmission measurements within 0.4-5.5 μm wavelength to model the methane transmission for temperature and pressure conditions in the jovian planets. Eight data sets are based on published laboratory measurements. Another two data sets come from two spectrometers onboard the Huygens probe that measured methane absorption inside Titan's atmosphere ( Tomasko et al., 2008b, PSS 56, 624), and we provide a refined analysis. The last data set is a set of new Jupiter images by the Hubble Space Telescope to measure atmospheric transmission with Ganymede as the light source. Below 1000 nm wavelength, our resulting methane absorption coefficients are generally close to those by Karkoschka (1998, Icarus 133, 134), but we add descriptions of temperature and pressure dependence. One remaining inconsistency occurs between 882 and 902 nm wavelength where laboratory data predict larger absorptions in the jovian atmospheres than observed. We present possible explanations. Above 1000 nm, our analysis of the Huygens data confirms methane absorption coefficients by Irwin et al. (2006, Icarus 181, 309) at their laboratory temperatures. Huygens data also confirm Irwin's model of extrapolation to Titan's lower pressures. However, their model of extrapolation to Titan's lower temperatures predicts absorption coefficients up to 100 times lower than measured by Huygens. For each of ˜3700 wavelengths, we present a temperature dependence that is consistent with all laboratory data and the Huygens data. Since the Huygens data probe similar temperatures as many observations of Saturn, Uranus, Neptune, and Titan, our methane model will allow more reliable radiative transfer models for their atmospheres.

  10. The influence of surface preparation on the absorption coefficient of laser radiation

    NASA Astrophysics Data System (ADS)

    Kurp, Piotr; Mucha, Zygmunt; Mulczyk, Krystian; Gradoń, Ryszard; Trela, Paweł

    2016-12-01

    The absorption coefficient of the surface of a workpiece is of importance in laser treatment, particularly in the treatment where the temperature of an element must be strictly controlled. Laser surface treatment (such as hardening, metallic glazing) and laser forming can be primarily included in this type of technology. In another case, surface temperature must be precisely controlled, especially if structural changes are to be avoided. There are a number of ways to increase the absorption coefficient of the surface of an element. Since the laser forming is the research subject of the authors of the presented paper, it was necessary to determine the absorption coefficient for the different surfaces preparation of workpieces. Raw surface, oxidized surface, sandblasted surface, black enamel covered surface and waterglass covered surface were examined, respectively. The experiment was performed using a CO2 laser with a head for a surface treatment which generates a rectangular beam of dimensions 2x20 mm, and the samples were made of X5CrNi18-10 stainless steel.

  11. Use of radial symmetry for the calculation of cylindrical absorption coefficients and optimal capillary loadings

    DOE PAGES

    Khalifah, Peter

    2015-02-01

    The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles θD of 0°more » to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.« less

  12. Two-photon interband absorption coefficients in tungstate and molybdate crystals

    NASA Astrophysics Data System (ADS)

    Lukanin, V. I.; Karasik, A. Ya.

    2015-02-01

    Two-photon absorption (TPA) coefficients were measured in tungstate and molybdate crystals - BaWO4, KGW, CaMoO4, BaMoO4, CaWO4, PbWO4 and ZnWO4 upon different orientations of excitation polarization with respect to the crystallographic axes. Trains of 25 ps pulses with variable radiation intensities of third (349 nm) harmonics of passively mode-locked 1047 nm Nd:YLF laser were used for interband two-photon excitation of the crystals. It was suggested that in the case, when 349 nm radiation pumping energy exceeds the bandgap width (hν>Eg), the nonlinear excitation process can be considered as two-step absorption. The interband two-photon absorption in all the studied crystals induces the following one-photon absorption from the exited states, which affects the nonlinear process dynamics and leads to a hysteresis in the dependence of the transmission on the excitation intensity. This fact was taken into account under analysis of the experimental dependences of the reciprocal transmission on the excitation intensity. Laser excitation in the transparency region of the crystals caused stimulated Raman scattering (SRS) not for all the crystals studied. The measured nonlinear coefficients allowed us to explain the suppression of SRS in crystals as a result of competition between the SRS and TPA.

  13. Use of radial symmetry for the calculation of cylindrical absorption coefficients and optimal capillary loadings

    SciTech Connect

    Khalifah, Peter

    2015-02-01

    The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles θD of 0° to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.

  14. Field calibration of multi-scattering correction factor for aethalometer aerosol absorption coefficient during CAPMEX Campaign, 2008

    NASA Astrophysics Data System (ADS)

    Kim, J. H.; Kim, S. W.; Yoon, S. C.; Park, R.; Ogren, J. A.

    2014-12-01

    Filter-based instrument, such as aethalometer, is being widely used to measure equivalent black carbon(EBC) mass concentration and aerosol absorption coefficient(AAC). However, many other previous studies have poited that AAC and its aerosol absorption angstrom exponent(AAE) are strongly affected by the multi-scattering correction factor(C) when we retrieve AAC from aethalometer EBC mass concentration measurement(Weingartner et al., 2003; Arnott et al., 2005; Schmid et al., 2006; Coen et al., 2010). We determined the C value using the method given in Weingartner et al. (2003) by comparing 7-wavelngth aethalometer (AE-31, Magee sci.) to 3-wavelength Photo-Acoustic Soot Spectrometer (PASS-3, DMT) at Gosan climate observatory, Korea(GCO) during Cheju ABC plume-asian monsoon experiment(CAPMEX) campaign(August and September, 2008). In this study, C was estimated to be 4.04 ± 1.68 at 532 nm and AAC retrieved with this value was decreased as approximately 100% as than that retrieved with soot case value from Weingartner et al (2003). We compared the AAC determined from aethalomter measurements to that from collocated Continuous Light Absorption Photometer (CLAP) measurements from January 2012 to December 2013 at GCO and found good agreement in both AAC and AAE. This result suggests the determination of site-specific C is crucially needed when we calculate AAC from aethalometer measurements.

  15. Backscatter factors and mass energy-absorption coefficient ratios for diagnostic radiology dosimetry.

    PubMed

    Benmakhlouf, Hamza; Bouchard, Hugo; Fransson, Annette; Andreo, Pedro

    2011-11-21

    Backscatter factors, B, and mass energy-absorption coefficient ratios, (μ(en)/ρ)(w, air), for the determination of the surface dose in diagnostic radiology were calculated using Monte Carlo simulations. The main purpose was to extend the range of available data to qualities used in modern x-ray techniques, particularly for interventional radiology. A comprehensive database for mono-energetic photons between 4 and 150 keV and different field sizes was created for a 15 cm thick water phantom. Backscattered spectra were calculated with the PENELOPE Monte Carlo system, scoring track-length fluence differential in energy with negligible statistical uncertainty; using the Monte Carlo computed spectra, B factors and (μ(en)/ρ)(w, air) were then calculated numerically for each energy. Weighted averaging procedures were subsequently used to convolve incident clinical spectra with mono-energetic data. The method was benchmarked against full Monte Carlo calculations of incident clinical spectra obtaining differences within 0.3-0.6%. The technique used enables the calculation of B and (μ(en)/ρ)(w, air) for any incident spectrum without further time-consuming Monte Carlo simulations. The adequacy of the extended dosimetry data to a broader range of clinical qualities than those currently available, while keeping consistency with existing data, was confirmed through detailed comparisons. Mono-energetic and spectra-averaged values were compared with published data, including those in ICRU Report 74 and IAEA TRS-457, finding average differences of 0.6%. Results are provided in comprehensive tables appropriated for clinical use. Additional qualities can easily be calculated using a designed GUI interface in conjunction with software to generate incident photon spectra.

  16. A method to obtain the absorption coefficient spectrum of single grain coal in the aliphatic C-H stretching region using infrared transflection microspectroscopy.

    PubMed

    Tonoue, Ryota; Katsura, Makoto; Hamamoto, Mai; Bessho, Hiroki; Nakashima, Satoru

    2014-01-01

    A method was developed to obtain the absorption coefficient spectrum of a grain of coal (as small as 10(-7)) in the region of aliphatic and aromatic C-H stretching bands (2700-3200 cm(-1)) using infrared transflection microspectroscopy. In this method, the complex refractive index n - ik was determined using an optimization algorithm with the Kramers-Kronig transform so that the calculated transflection spectrum from the Fresnel equation corresponded to the measured one. The obtained absorption coefficients were compared with the bulk values determined from the potassium bromide (KBr) pellet measurement method.

  17. Parameterization of the Mie extinction and absorption coefficients for water clouds

    SciTech Connect

    Mitchell, D.L.

    2000-05-01

    It was found that the anomalous diffraction approximation (ADA) could be made to approximate Mie theory for absorption and extinction in water clouds by parameterizing the missing physics: (1) internal reflection/refraction, (2) photon tunneling, and (3) edge diffraction. Tunneling here refers to processes by which tangential or grazing photons beyond the physical cross section of a spherical particle may be absorbed. Contributions of the above processes to extinction and/or absorption were approximated in terms of particle size, index of refraction, and wavelength. It was found that tunneling can explain most of the difference between ADA and Mie theory for water clouds in the thermal IR. The modified ADA yielded analytical expressions for the absorption and extinction efficiencies, Q{sub abs} and Q{sub ext}, which were integrated over a gamma size distribution to yield expressions for the absorption and extinction coefficients, {beta}{sub abs} and {beta}{sub ext}. These coefficients were expressed in terms of the three gamma distribution parameters, which were related to measured properties of the size distribution: liquid water content, mean, and mass-median diameter. Errors relative to Mie theory for {beta}{sub abs} and {beta}{sub ext} were generally {le}10% for the effective radius range in water clouds of 5--30 {micro}m, for any wavelength in the solar or terrestrial spectrum. For broadband emissivities and absorptivities regarding terrestrial and solar radiation, the errors were less than 1.2% and 4%, respectively. The modified ADA dramatically reduces computation times relative to Mie theory while yielding reasonably accurate results.

  18. Microwave Resonator Measurements of Atmospheric Absorption Coefficients: A Preliminary Design Study

    NASA Technical Reports Server (NTRS)

    Walter, Steven J.; Spilker, Thomas R.

    1995-01-01

    A preliminary design study examined the feasibility of using microwave resonator measurements to improve the accuracy of atmospheric absorption coefficients and refractivity between 18 and 35 GHz. Increased accuracies would improve the capability of water vapor radiometers to correct for radio signal delays caused by Earth's atmosphere. Calibration of delays incurred by radio signals traversing the atmosphere has applications to both deep space tracking and planetary radio science experiments. Currently, the Cassini gravity wave search requires 0.8-1.0% absorption coefficient accuracy. This study examined current atmospheric absorption models and estimated that current model accuracy ranges from 5% to 7%. The refractivity of water vapor is known to 1% accuracy, while the refractivity of many dry gases (oxygen, nitrogen, etc.) are known to better than 0.1%. Improvements to the current generation of models will require that both the functional form and absolute absorption of the water vapor spectrum be calibrated and validated. Several laboratory techniques for measuring atmospheric absorption and refractivity were investigated, including absorption cells, single and multimode rectangular cavity resonators, and Fabry-Perot resonators. Semi-confocal Fabry-Perot resonators were shown to provide the most cost-effective and accurate method of measuring atmospheric gas refractivity. The need for accurate environmental measurement and control was also addressed. A preliminary design for the environmental control and measurement system was developed to aid in identifying significant design issues. The analysis indicated that overall measurement accuracy will be limited by measurement errors and imprecise control of the gas sample's thermodynamic state, thermal expansion and vibration- induced deformation of the resonator structure, and electronic measurement error. The central problem is to identify systematic errors because random errors can be reduced by averaging

  19. Methamphetamine absorption by skin lipids: accumulated mass, partition coefficients, and the influence of fatty acids.

    PubMed

    Parker, K; Morrison, G

    2016-08-01

    Occupants of former methamphetamine laboratories, often residences, may experience increased exposure through the accumulation of the methamphetamine in the organic films that coat skin and indoor surfaces. The objectives of this study were to determine equilibrium partition coefficients of vapor-phase methamphetamine with artificial sebum (AS-1), artificial sebum without fatty acids (AS-2), and real skin surface films, herein called skin oils. Sebum and skin oil-coated filters were exposed to vapor-phase methamphetamine at concentrations ranging from 8 to 159 ppb, and samples were analyzed for exposure time periods from 2 h to 60 days. For a low vapor-phase methamphetamine concentration range of ~8-22 ppb, the equilibrium partition coefficient for AS-1 was 1500 ± 195 μg/g/ppb. For a high concentration range of 98-112 ppb, the partition coefficient was lower, 459 ± 80 μg/g/ppb, suggesting saturation of the available absorption capacity. The low partition coefficient for AS-2 (33 ± 6 μg/g/ppb) suggests that the fatty acids in AS-1 and skin oil are responsible for much high partition coefficients. We predict that the methamphetamine concentration in skin lipids coating indoor surfaces can exceed recommended surface remediation standards even for air concentrations well below 1 ppb.

  20. Diffusion Coefficients of Water and Leachables in Methacrylate-based Crosslinked Polymers using Absorption Experiments

    PubMed Central

    Parthasarathy, Ranganathan; Misra, Anil; Park, Jonggu; Ye, Qiang; Spencer, Paulette

    2012-01-01

    The diffusion of water into dentin adhesive polymers and leaching of unpolymerized monomer from the adhesive are linked to their mechanical softening and hydrolytic degradation. Therefore, diffusion coefficient data are critical for the mechanical design of these polymeric adhesives. In this study, diffusion coefficients of water and leachables were obtained for sixteen methacrylate-based crosslinked polymers using absorption experiments. The experimental mass change data was interpreted using numerical solution of the two-dimensional diffusion equations. The calculated diffusion coefficients varied from 1.05 × 10−8 cm2/sec (co-monomer TMTMA) to 3.15 × 10−8 cm2/sec (co-monomer T4EGDMA). Correlation of the diffusion coefficients with crosslink density and hydrophilicity showed an inverse trend (R2 = 0.41). The correlation of diffusion coefficient with crosslink density and hydrophilicity are closer for molecules differing by simple repeat units (R2 = 0.95). These differences in the trends reveal mechanisms of interaction of the diffusing water with the polymer structure. PMID:22430592

  1. Value of Apparent Diffusion Coefficient Values in Differentiating Malignant and Benign Breast Lesions

    PubMed Central

    Bozkurt Bostan, Tuğba; Koç, Gonca; Sezgin, Gülten; Altay, Canan; Fazıl Gelal, M.; Oyar, Orhan

    2016-01-01

    Background: Magnetic resonance imaging (MRI) has become a diagnostic and problem solving method for the breast examinations in addition to conventional breast examination methods. Diffusion-weighted imaging (DWI) adds valuable information to conventional MRI. Aims: Our aim was to show the impact of apparent diffusion coefficient (ADC) values acquired with DWI to differentiate benign and malignant breast lesions. Study Design: Diagnostic accuracy study. Methods: Forty-six women with 58 breast masses (35 malignant, 23 benign) were examined on a 1.5 T clinical MRI scanner. The morphologic characteristics of the lesions on conventional MRI sequences and contrast uptake pattern were assessed. ADC values of both lesions and normal breast parenchyma were measured. The ADC values obtained were statistically compared with the histopathologic results using Paired Samples t-Test. Results: Multiple lesions were detected in 12 (26%) of the patients, while only one lesion was detected in 34 (74%). Overall, 35 lesions out of 58 were histopathologically proven to be malignant. In the dynamic contrast-enhanced series, 5 of the malignant lesions were type 1, while 8 benign lesions revealed either type 2 or 3 time signal intensity curves (85% sensitivity, 56% spesifity). Mean ADC values were significantly different in malignant vs. benign lesions. (1.04±0.29×10−3 cm2/sec vs. 1.61±0.50×10−3 cm2/sec for the malignant and benign lesions, respectively, p=0.03). A cut-off value of 1.30×10−3 mm2/sec for ADC detected with receiver operating characteristic analysis yielded 89.1% sensitivity and 100% specificity for the differentiation between benign and malignant lesions. Conclusion: ADC values improve the diagnostic accuracy of solid breast lesions when evaluated with the conventional MRI sequences. Therefore, DWI should be incorporated to routine breast MRI protocol. PMID:27308073

  2. Effect of sealants of the sound absorption coefficients of acoustical friable insulating materials

    NASA Astrophysics Data System (ADS)

    Wayman, J. L.; Lory, M. K.

    1984-10-01

    Acoustical friable insulating materials (AFIM), which often in the past contained asbestos, have been used for sound control since the mid 1930's. Because of their widespread use and the ease of fiber dissemination, friable asbestos materials are considered to be the major source of asbestos fiber contamination in the indoor environment. Encapsulation of asbestos materials with a commercial sealant product is one of several methods used to control potential asbestos exposure in rooms. A sealant product that preserves most of the acoustical properties of the material is preferred in this usage. AFIM sample materials were treated with 6 types of sealants and the effects on normally incident absorption coefficients from 100 to 2500 Hz were measured using a fixed, dual-microphone technique. Penetrating type sealants were found to have a less detrimental effect on sound absorption than those of a bridging type.

  3. The effective air absorption coefficient for predicting reverberation time in full octave bands.

    PubMed

    Wenmaekers, R H C; Hak, C C J M; Hornikx, M C J

    2014-12-01

    A substantial amount of research has been devoted to producing a calculation model for air absorption for pure tones. However, most statistical and geometrical room acoustic prediction models calculate the reverberation time in full octave bands in accordance with ISO 3382-1 (International Organization for Standardization, 2009). So far, the available methods that allow calculation of air absorption in octave bands have not been investigated for room acoustic applications. In this paper, the effect of air absorption on octave band reverberation time calculations is investigated based on calculations. It is found that the approximation method, as described in the standard ANSI S1.26 (American National Standards Institute, 1995), fails to estimate accurate decay curves for full octave bands. In this paper, a method is used to calculate the energy decay curve in rooms based on a summation of pure tones within the band. From this decay curve, which is found to be slightly concave upwards, T20 and T30 can be determined. For different conditions, an effective intensity attenuation coefficient mB ;eff for the full octave bands has been calculated. This mB ;eff can be used for reverberation time calculations, if results are to be compared with T20 or T30 measurements. Also, guidelines are given for the air absorption correction of decay curves, measured in a scale model.

  4. Water in the Earth's Mantle: Mineral-specific IR Absorption Coefficients and Radiative Thermal Conductivities

    NASA Astrophysics Data System (ADS)

    Thomas, S. M.

    2015-12-01

    Minor and trace element chemistry, phase relations, rheology, thermal structure and the role of volatiles and their abundance in the deep Earth mantle are still far from fully explored, but fundamental to understanding the processes involved in Earth formation and evolution. Theory and high pressure experiments imply a significant water storage capacity of nominally anhydrous minerals, such as majoritic garnet, olivine, wadsleyite and ringwoodite, composing the Earth's upper mantle and transition zone to a depth of 660 km. Studying the effect of water incorporation on chemical and physical mineral properties is of importance, because the presence of trace amounts of water, incorporated as OH through charge-coupled chemical substitutions into such nominally anhydrous high-pressure silicates, notably influences phase relations, melting behavior, conductivity, elasticity, viscosity and rheology. Knowledge of absolute water contents in nominally anhydrous minerals is essential for modeling the Earth's interior water cycle. One of the most common and sensitive tools for water quantification is IR spectroscopy for which mineral-specific absorption coefficients are required. Such calibration constants can be derived from hydrogen concentrations determined by independent techniques, such as secondary ion mass spectrometry, Raman spectroscopy or proton-proton(pp)-scattering. Here, analytical advances and mineral-specific IR absorption coefficients for the quantification of H2O in major phases of the Earth's mantle will be discussed. Furthermore, new data from optical absorption measurements in resistively heated diamond-anvil cells at high pressures and temperatures up to 1000 K will be presented. Experiments were performed on synthetic single-crystals of olivine, ringwoodite, majoritic garnet, and Al-bearing phase D with varying iron, aluminum and OH contents to calculate radiative thermal conductivities and study their contribution to heat transfer in the Earth's interior

  5. Variation of Phytoplankton Absorption Coefficients in the Northern South China Sea during Spring and Autumn

    DTIC Science & Technology

    2007-05-21

    samples were collected with 1.7 L Niskin bottles mounted on a rosette equipped with a SBE19 CTD which provides temperature and salinity data. Samples were...21 November is 2002) on board R/V Yanping I1. Figure 1 shows the stations for CTD surveys and ab- sorption sampling . The 2001 cruise involved one...were sampled in both cruise legs for absorption coefficients (the second sampling is annotated as Sta. 6’ and Sta. 2’, respectively). 1559 Our sample

  6. Vapor-Phase Absorptivity Coefficient of Ethyl N,N-Dimethylphosphoramidocyanidate

    DTIC Science & Technology

    2010-01-01

    diluted in solvent by gas chromotography -mass spectrometry (GC-MS) indicated 3.4% triethyl phosphate (TEPO), as well ə% each of 0-ethyl-N,N-dimethyl...absorptivity coefficient of the chemical warfare agent ethyl N,N-dimethyl- phosphoramidocyanidate ( GA ) in the mid-infrared (4000-550 cm"’) at a...spectral resolution of 0.125 cm"’. The GA used in the feedstock was purified by fractional distillation and analyzed by nuclear magnetic resonance and

  7. Determination of the scattering coefficient of biological tissue considering the wavelength and absorption dependence of the anisotropy factor

    NASA Astrophysics Data System (ADS)

    Fukutomi, Daichi; Ishii, Katsunori; Awazu, Kunio

    2016-04-01

    The anisotropy factor g, one of the optical properties of biological tissues, has a strong influence on the calculation of the scattering coefficient μ s in inverse Monte Carlo (iMC) simulations. It has been reported that g has the wavelength and absorption dependence; however, few attempts have been made to calculate μ s using g values by taking the wavelength and absorption dependence into account. In this study, the angular distributions of scattered light for biological tissue phantoms containing hemoglobin as a light absorber were measured by a goniometric optical setup at strongly (405 nm) and weakly (664 nm) absorbing wavelengths to obtain g. Subsequently, the optical properties were calculated with the measured values of g by integrating sphere measurements and an iMC simulation, and compared with the results obtained with a conventional g value of 0.9. The μ s values with measured g were overestimated at the strongly absorbing wavelength, but underestimated at the weakly absorbing wavelength if 0.9 was used in the iMC simulation.

  8. Light absorption coefficient measurement of SOA using a UV-Visible spectrometer connected with an integrating sphere

    NASA Astrophysics Data System (ADS)

    Zhong, Min; Jang, Myoseon

    2011-08-01

    A method for measuring an aerosol light absorption coefficient ( B a) has been developed using a conventional UV-visible spectrometer equipped with an integrating sphere covering a wide range of wavelengths (280-800 nm). The feasibility of the proposed method was evaluated in both the transmittance mode (TUV-IS) and the reflective mode (RUV-IS) using the reference aerosol known for the cross-sectional area. The aerosol was collected on a conventional filter and measured for B a values. The resulting RUV-IS method was applied to measure light absorption of secondary organic aerosol (SOA). SOA was produced through photooxidation of different precursor hydrocarbons such as toluene, d-limonene and α-pinene in the presence of NO x (60-70 ppb) and inorganic seed aerosol using a 2-m 3 indoor Teflon film chamber. Of the three precursor hydrocarbons, the B a value of toluene SOA (0.574 m 2 g -1 at 350 nm) was the highest compared with B a values for α-pinene SOA (0.029 m 2 g -1) and d-limonene SOA (0.038 m 2 g -1). When d-limonene SOA or toluene SOA was internally mixed with neutral [(NH 4) 2SO 4] or acidic inorganic seed (NH 4HSO 4:H 2SO 4 = 1:1 by mole), the SOA showed 2-3 times greater B a values at 350 nm than the SOA with no seed. Aerosol aging with a light source for this study reduced B a values of SOA (e.g., on average 10% for toluene SOA and 30% for d-limonene SOA within 4 h). Overall, weak absorption appeared for chamber-generated SOA over wavelengths ranging from 280 to 550 nm, which fall into the sunlight spectrum.

  9. Mean absorption coefficients of He/Ar/N2/(C1-x-y , Ni x , Co y ) thermal plasmas for CNT synthesis

    NASA Astrophysics Data System (ADS)

    Salem, D.; Hannachi, R.; Cressault, Y.; Teulet, Ph; Béji, L.

    2017-01-01

    In this paper, we present the mean absorption coefficients (MACs) calculated for plasma mixtures of argon-helium-nitrogen-carbon-nickel-cobalt at 60 kPa and in a temperature range from 1 kK to 20 kK. These coefficients have been computed under the assumption of a local thermodynamic equilibrium (LTE), isothermal plasma, including atomic and molecular continuum, molecular bands and lines radiation splitted into nine spectral intervals. The results show that the continuum absorption coefficients strongly depend on photodissociation and photoionization processes of the molecular species N2, CN and C2, with a significant effect on photodetachment processes of C- in a frequency interval lower than 1  ×  1015 Hz and for low temperature (<6 kK). While at high temperature, the main contribution in continuum absorption coefficient comes from radiative recombination processes except in the infrared region (<0.5  ×  1015 Hz) where the inverse bremsstrahlung represents the most important component in continuum processes for all temperature values. On the other hand, the calculation of MAC shows that the role of molecular continuum, molecular bands and line absorption of the neutral catalysis species Ni/Co are only important in a small range of temperature and in a few spectral bands located in visible and infrared regions, while at high temperature and in UV and visible regions, the foremost contributions to MAC come from atomic continuum and line absorption.

  10. A comparison study of linear reconstruction techniques for diffuse optical tomographic imaging of absorption coefficient

    NASA Astrophysics Data System (ADS)

    Gaudette, Richard J.; Brooks, Dana H.; Di Marzio, Charles A.; Kilmer, Misha E.; Miller, Eric L.; Gaudette, Thomas; Boas, David A.

    2000-04-01

    We compare, through simulations, the performance of four linear algorithms for diffuse optical tomographic reconstruction of the three-dimensional distribution of absorption coefficient within a highly scattering medium using the diffuse photon density wave approximation. The simulation geometry consisted of a coplanar array of sources and detectors at the boundary of a half-space medium. The forward solution matrix is both underdetermined, because we estimate many more absorption coefficient voxels than we have measurements, and ill-conditioned, due to the ill-posedness of the inverse problem. We compare two algebraic techniques, ART and SIRT, and two subspace techniques, the truncated SVD and CG algorithms. We compare three-dimensional reconstructions with two-dimensional reconstructions which assume all inhomogeneities are confined to a known horizontal slab, and we consider two `object-based' error metrics in addition to mean square reconstruction error. We include a comparison using simulated data generated using a different FDFD method with the same inversion algorithms to indicate how our conclusions are affected in a somewhat more realistic scenario. Our results show that the subspace techniques are superior to the algebraic techniques in localization of inhomogeneities and estimation of their amplitude, that two-dimensional reconstructions are sensitive to underestimation of the object depth, and that an error measure based on a location parameter can be a useful complement to mean squared error.

  11. Spectral absorption coefficients of argon and silicon and spectral reflectivity of aluminum

    NASA Technical Reports Server (NTRS)

    Krascella, N. L.

    1972-01-01

    A theoretical investigation was conducted to estimate the spectral properties of argon as a function of pressure, temperature, and wave number. The spectral characteristics of the argon buffer gas exert a strong influence on radiative energy transfer in the in-reactor test configuration of the nuclear light bulb engine. An existing computer program was modified and used to calculate the spectral absorption coefficients of argon at total pressures of 50, 100, 250, 500, 750 and 1000 atm in the temperature interval between 1000 and 30,000 K. At each pressure and temperature, spectral properties were calculated for forty-seven wave numbers in the interval between 1000 and 1,000,000 cm/1. Estimates of the spectral absorption coefficients of silicon were made as part of an evaluation of silicon vapor as a possible buffer-gas seeding agent for the reference nuclear light bulb engine. Existing cross-section data were used to calculate the spectral characteristics of silicon at twenty-four temperatures in the interval between 2000 and 10,000 K.

  12. Modeling the cumulative distribution of absorption coefficients of gases using the generalized k-moment method

    NASA Astrophysics Data System (ADS)

    André, Frédéric; Solovjov, Vladimir; Vaillon, Rodolphe; Lemonnier, Denis

    2013-07-01

    The generalized k-moment method is formulated in terms of Cutteridge-Devyatov polynomials (CDP). In this novel approach, the moments involved are spectral averages of integer powers of the logarithm of the absorption coefficient. The technique to obtain k-distributions from those generalized moments is detailed both theoretically and from a practical point of view. Its outputs are afterward assessed against reference data in several test cases of increasing complexity. Indeed, the first ones involve single lines in the Lorentz, Doppler and Voigt regimes. The most sophisticated situations investigated in this work concern applications of the method to high resolution LBL data for pure CO2 at temperatures between 300K and 2300K and at atmospheric pressure. In any case, the CDP solution to the generalized k-moment problem is found to provide very accurate results. The present technique outperforms our previous approach to k-moment modeling of the cumulative distribution of absorption coefficients of gases that were based on first, second, first inverse and logarithmic moments, in all the situations investigated. Equations required to apply the model are provided in the paper, both over narrow bands and the full spectrum.

  13. Density, ultrasound velocity, acoustic impedance, reflection and absorption coefficient determination of liquids via multiple reflection method.

    PubMed

    Hoche, S; Hussein, M A; Becker, T

    2015-03-01

    The accuracy of density, reflection coefficient, and acoustic impedance determination via multiple reflection method was validated experimentally. The ternary system water-maltose-ethanol was used to execute a systematic, temperature dependent study over a wide range of densities and viscosities aiming an application as inline sensor in beverage industries. The validation results of the presented method and setup show root mean square errors of: 1.201E-3 g cm(-3) (±0.12%) density, 0.515E-3 (0.15%) reflection coefficient and 1.851E+3 kg s(-1) m(-2) (0.12%) specific acoustic impedance. The results of the diffraction corrected absorption showed an average standard deviation of only 0.12%. It was found that the absorption change shows a good correlation to concentration variations and may be useful for laboratory analysis of sufficiently pure liquids. The main part of the observed errors can be explained by the observed noise, temperature variation and the low signal resolution of 50 MHz. In particular, the poor signal-to-noise ratio of the second reflector echo was found to be a main accuracy limitation. Concerning the investigation of liquids the unstable properties of the reference material PMMA, due to hygroscopicity, were identified to be an additional, unpredictable source of uncertainty. While dimensional changes can be considered by adequate methodology, the impact of the time and temperature dependent water absorption on relevant reference properties like the buffer's sound velocity and density could not be considered and may explain part of the observed deviations.

  14. Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals.

    PubMed

    De Roo, Jonathan; Ibáñez, Maria; Geiregat, Pieter; Nedelcu, Georgian; Walravens, Willem; Maes, Jorick; Martins, Jose C; Van Driessche, Isabel; Kovalenko, Maksym V; Hens, Zeger

    2016-02-23

    Lead halide perovskite materials have attracted significant attention in the context of photovoltaics and other optoelectronic applications, and recently, research efforts have been directed to nanostructured lead halide perovskites. Collodial nanocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit bright photoluminescence, with emission tunable over the entire visible spectral region. However, previous studies on CsPbX3 NCs did not address key aspects of their chemistry and photophysics such as surface chemistry and quantitative light absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface chemistry. In addition, the intrinsic absorption coefficient was determined experimentally by combining elemental analysis with accurate optical absorption measurements. (1)H solution nuclear magnetic resonance spectroscopy was used to characterize sample purity, elucidate the surface chemistry, and evaluate the influence of purification methods on the surface composition. We find that ligand binding to the NC surface is highly dynamic, and therefore, ligands are easily lost during the isolation and purification procedures. However, when a small amount of both oleic acid and oleylamine is added, the NCs can be purified, maintaining optical, colloidal, and material integrity. In addition, we find that a high amine content in the ligand shell increases the quantum yield due to the improved binding of the carboxylic acid.

  15. The Optical Absorption Coefficient of Bean Seeds Investigated Using Photoacoustic Spectroscopy

    NASA Astrophysics Data System (ADS)

    Sanchez-Hernandez, G.; Hernandez-Aguilar, C.; Dominguez-Pacheco, A.; Cruz-Orea, A.; Perez-Reyes, M. C. J.; Martinez, E. Moreno

    2015-06-01

    A knowledge about seed optical parameters is of great relevance in seed technology practice. Such parameters provide information about its absorption and reflectance, which could be useful for biostimulation processes, by light sources, in early stages of seed germination. In the present research photoacoustic spectroscopy (PAS) and the Rosencwaig and Gersho model were used to determine the optical absorption coefficient () of five varieties of bean seeds ( Phaseolus vulgaris L.), of different productive cycles; the seeds were biostimulated by laser treatment to evaluate the effects of biostimulation pre-sowing. It was found that the bean varieties V1, V2, V4, and V5 were optically opaque in the visible spectrum; in the case of the V3 variety, this sample was optically transparent from 680 nm. The varieties of the studied bean seeds showed significant statistical differences in sizes and also in their optical absorption spectra. The biostimulation effects showed that the seed samples with a higher optical penetration length had a positive biostimulation, in the percentage of germination, obtaining an enhancement of 47 % compared to the control sample. The utility of PAS for the optical characterization of seeds has been demonstrated in this study of the laser biostimulation process of this kind of samples.

  16. Determination of scattering coefficient considering wavelength and absorption dependence of anisotropy factor measured by polarized beam for biological tissues

    NASA Astrophysics Data System (ADS)

    Fukutomi, D.; Ishii, K.; Awazu, K.

    2015-12-01

    Anisotropy factor g, one of the optical properties of biological tissues, is the most important parameter to accurately determine scattering coefficient μs in the inverse Monte Carlo (iMC) simulation. It has been reported that g has wavelength and absorption dependence, however, there are few attempts in order to calculate μs of biological tissue considering the wavelength and absorption dependence of g. In this study, the scattering angular distributions of biological tissue phantoms were measured in order to determine g by using goniometric measurements with three polarization conditions at strongly and weakly absorbing wavelengths of hemoglobin. Then, optical properties, especially, μs were measured by integrating sphere measurements and iMC simulation in order to confirm the influence of measured g on optical properties in comparison of with general value of g (0.9) for soft biological tissue. Consequently, it was found that μs was overestimated at strongly absorbing wavelength, however, μs was underestimated at weakly absorbing wavelength if the g was not considered its wavelength and absorption dependence.

  17. Tomographic imaging of absolute optical absorption coefficient in turbid media using combined photoacoustic and diffusing light measurements.

    PubMed

    Yin, Lu; Wang, Qiang; Zhang, Qizhi; Jiang, Huabei

    2007-09-01

    We present a new method that can provide high resolution images of absolute optical absorption coefficient in heterogeneous turbid media. In this method, acoustic measurements in conventional photoacoustic tomography are combined with diffusing light measurements to separate the product of absorption coefficient and optical fluence or photon density. We validate this method using a series of tissuelike phantom experiments. The experimental results show that targets as small as 0.5 mm in diameter with optical absorption contrasts as low as 1.5 relative to a 50 mm diameter scattering background medium can be clearly detected.

  18. Experimental investigation of X-ray spectral absorption coefficients in heated Al and Ge on the Iskra-5 laser facility

    SciTech Connect

    Bondarenko, S V; Garanin, Sergey G; Zhidkov, N V; Pinegin, A V; Suslov, N A

    2012-01-31

    We set forth the data of experimental investigation of X-ray spectral absorption coefficients in the 1.1 - 1.6 keV photon energy range for Al and Ge specimens bulk heated by soft X-ray radiation. Two experimental techniques are described: with the use of one facility channel and the heating of specimens by the X-ray radiation from a plane burnthrough target, as well as with the use of four channels and the heating by the radiation from two cylindrical targets with internal input of laser radiation. The X-ray radiation absorption coefficients were studied by way of transmission absorption spectroscopy using backlighting X-ray radiation from a point source. The results of investigation of X-ray spectral absorption coefficients on the 1s - 2p transitions in Al atoms and the 2p - 3d transitions in Ge atoms are presented.

  19. Magnetic resonance imaging of acoustic streaming: absorption coefficient and acoustic field shape estimation.

    PubMed

    Madelin, Guillaume; Grucker, Daniel; Franconi, Jean-Michel; Thiaudiere, Eric

    2006-07-01

    In this study, magnetic resonance imaging (MRI) is used to visualize acoustic streaming in liquids. A single-shot spin echo sequence (HASTE) with a saturation band perpendicular to the acoustic beam permits the acquisition of an instantaneous image of the flow due to the application of ultrasound. An average acoustic streaming velocity can be estimated from the MR images, from which the ultrasonic absorption coefficient and the bulk viscosity of different glycerol-water mixtures can be deduced. In the same way, this MRI method could be used to assess the acoustic field and time-average power of ultrasonic transducers in water (or other liquids with known physical properties), after calibration of a geometrical parameter that is dependent on the experimental setup.

  20. Measurement of acoustic absorption coefficient with phase-conjugate ultrasonic waves

    NASA Astrophysics Data System (ADS)

    Smagin, N. V.; Krutyansky, L. M.; Brysev, A. P.; Bunkin, F. V.

    2011-07-01

    Experimental results on measurements of the acoustic absorption coefficient in test objects that were obtained with two methods, i.e., a standard insert-substitution method and a modification thereof using phase-conjugate waves, are given. Samples of gelatin and biological tissue in vitro (porcine muscle fibers) were used as test objects. Gelatin objects were manufactured that were both homogeneous and with inhomogeneities in the form of a rough surface or inclusions (air bubbles) distributed over the volume. A rough surface leads mainly to phase distortions of a probe beam, while bubble inclusions cause additional field scattering. For all homogeneous samples, both compared methods produce identical results. In the case of inhomogeneous samples including biological tissues, absorption measurement by a standard method may lead to significant errors. It is demonstrated that the use of properties of phase-conjugate waves provides an opportunity to eliminate almost completely the measurement error connected with phase distortions and reduce the error in the case of a medium with scatterers.

  1. Two-dimensional poroelastic acoustical foam shape design for absorption coefficient maximization by topology optimization method.

    PubMed

    Lee, Joong Seok; Kim, Yoon Young; Kim, Jung Soo; Kang, Yeon June

    2008-04-01

    Optimal shape design of a two-dimensional poroelastic acoustical foam is formulated as a topology optimization problem. For a poroelastic acoustical system consisting of an air region and a poroelastic foam region, two different physical regions are continuously changed in an iterative design process. To automatically account for the moving interfaces between two regions, we propose a new unified model to analyze the whole poroelastic acoustical foam system with one set of governing equations; Biot's equations are modified with a material property interpolation from a topology optimization method. With the unified analysis model, we carry out two-dimensional optimal shape design of a poroelastic acoustical foam by a gradient-based topology optimization setting. The specific objective is the maximization of the absorption coefficient in low and middle ranges of frequencies with different amounts of a poroelastic material. The performances of the obtained shapes are compared with those of well-known wedge shapes, and the improvement of absorption is physically interpreted.

  2. Approximating the near-edge mass absorption coefficients for Ni using an ultra-thin bimetal foil

    DOE PAGES

    Alkire, Randall W.

    2016-11-01

    In an effort to improve the characteristics of a fluorescing metal-foil-based beam position monitor, a new bimetal ultra-thin (0.98/0.67 µm) Ti–Ni foil was introduced to replace an existing single-element ultra-thin 0.5 µm thick Cr foil. During characterization it was determined that absorption measurements on the bimetal foil could be used to fit the Ni mass absorption coefficients accurately in the vicinity of the NiKedge. Comparison with experimental results from the literature demonstrated that the fitting procedure produced coefficients with uncertainties of the order of ±1%. Once determined, these fit coefficients allowed the thickness of an independently mounted 8 µm thickmore » Ni foil to be computed from absorption measurements instead of relying on a tool-based measurement of the foil thickness. Using the 8 µm thick foil, a continuous map of Ni mass absorption coefficients was produced at 1 eV resolution throughout the near-edge region. Lastly, this high-resolution map marks a significant improvement over the existing NIST XCOM or FFAST database mass absorption coefficients, which have estimated errors of 10–20% for the near-edge region.« less

  3. Approximating the near-edge mass absorption coefficients for Ni using an ultra-thin bimetal foil

    SciTech Connect

    Alkire, Randall W.

    2016-11-01

    In an effort to improve the characteristics of a fluorescing metal-foil-based beam position monitor, a new bimetal ultra-thin (0.98/0.67 µm) Ti–Ni foil was introduced to replace an existing single-element ultra-thin 0.5 µm thick Cr foil. During characterization it was determined that absorption measurements on the bimetal foil could be used to fit the Ni mass absorption coefficients accurately in the vicinity of the NiKedge. Comparison with experimental results from the literature demonstrated that the fitting procedure produced coefficients with uncertainties of the order of ±1%. Once determined, these fit coefficients allowed the thickness of an independently mounted 8 µm thick Ni foil to be computed from absorption measurements instead of relying on a tool-based measurement of the foil thickness. Using the 8 µm thick foil, a continuous map of Ni mass absorption coefficients was produced at 1 eV resolution throughout the near-edge region. Lastly, this high-resolution map marks a significant improvement over the existing NIST XCOM or FFAST database mass absorption coefficients, which have estimated errors of 10–20% for the near-edge region.

  4. Geopotential coefficient determination and the gravimetric boundary value problem: A new approach

    NASA Technical Reports Server (NTRS)

    Sjoeberg, Lars E.

    1989-01-01

    New integral formulas to determine geopotential coefficients from terrestrial gravity and satellite altimetry data are given. The formulas are based on the integration of data over the non-spherical surface of the Earth. The effect of the topography to low degrees and orders of coefficients is estimated numerically. Formulas for the solution of the gravimetric boundary value problem are derived.

  5. Analytical modeling of photon absorption coefficient in mono and bilayer circular graphene quantum dots for light absorber applications

    NASA Astrophysics Data System (ADS)

    Tamandani, Shahryar; Darvish, Ghafar

    2017-02-01

    We present an analytical method to calculate photon absorption coefficient in mono and bilayer circular graphene quantum dots (CGQDs). We use kobo equation to extract new closed relation as the main goal. First, we calculate real and imaginary part of optical conductance separately. Then, joint density of states is obtained using a new relation that was extracted for the energy levels of mono and bilayer circular grapheme quantum dots. In this work we use closed equations to calculate energy levels in CGQDs. Next we obtain a new closed formula to calculate the photon absorption coefficient. The results show that the absorption coefficient is related to the size of CGQDs and number of layers. The photon absorption coefficient becomes lower with larger size of CGQDs. It is seen that the results of our method is compatible with the results of practical works. We also compare photon absorption in biased and unbiased bilayer CGQDs and investigate the effect of external magnetic field on photon absorption. rights reserved

  6. Spatially resolved absolute diffuse reflectance measurements for noninvasive determination of the optical scattering and absorption coefficients of biological tissue

    NASA Astrophysics Data System (ADS)

    Kienle, Alwin; Lilge, Lothar; Patterson, Michael S.; Hibst, Raimund; Steiner, Rudolf; Wilson, Brian C.

    1996-05-01

    The absorption and transport scattering coefficients of biological tissues determine the radial dependence of the diffuse reflectance that is due to a point source. A system is described for making remote measurements of spatially resolved absolute diffuse reflectance and hence noninvasive, noncontact estimates of the tissue optical properties. The system incorporated a laser source and a CCD camera. Deflection of the incident beam into the camera allowed characterization of the source for absolute reflectance measurements. It is shown that an often used solution of the diffusion equation cannot be applied for these measurements. Instead, a neural network, trained on the results of Monte Carlo simulations, was used to estimate the absorption and scattering coefficients from the reflectance data. Tests on tissue-simulating phantoms with transport scattering coefficients between 0.5 and 2.0 mm-1 and absorption coefficients between 0.002 and 0.1 mm -1 showed the rms errors of this technique to be 2.6% for the transport scattering coefficient and 14% for the absorption coefficients. The optical properties of bovine muscle, adipose, and liver tissue, as well as chicken muscle (breast), were also measured ex vivo at 633 and 751 nm. For muscle tissue it was found that the Monte Carlo simulation did not agree with experimental measurements of reflectance at distances less than 2 mm from the incident beam. Carlo, neural network.

  7. Absorption Coefficient, Molecular Composition, and Photodegradation of Different Types of Brown Carbon Aerosols

    NASA Astrophysics Data System (ADS)

    Lee, H. J.; Aiona, P. K.; Nizkorodov, S.; Laskin, J.; Laskin, A.

    2014-12-01

    Atmospheric aerosols that absorb solar radiation have a direct effect on climate. Brown carbon (BrC) represents the type of carbonaceous aerosols characterized by large absorption coefficients in the near-UV range of the spectrum. BrC can be either directly emitted into the atmosphere from combustion sources, or be formed in the atmosphere through multi-phase reactions, such as aging of secondary organic aerosols (SOA) mediated by ammonium sulfate (AS). Under the conditions of exposure to solar radiation, both primary and secondary BrC can potentially change their molecular composition and optical properties as a result of photodegradation of chromophoric compounds. This presentation will discuss the molecular level composition, the absorption and fluorescence spectra, and the mechanism of photodegradation among several representative types of BrC. The primary BrC samples include aerosol produced by smoldering wood combustion. The secondary BrC samples include AS aged products of chamber-generated SOA, products of reaction between methylglyoxal and AS, and SOA produced by the hogh-NOx photooxdiation of aromatic compounds, such as naphthalene. This presentation will also include preliminary data on the absorption and fluorescence spectra of photo-degraded bioaerosols. In all cases, absorption spectra of extracted bulk samples are measured during irradiation by a known flux of UV or visible light. The molecular level composition of the fresh and photobleached samples are characterized by high-resolution electrospray ionization mass spectrometry (HR-ESI-MS). Photobleaching of BrC is found to occur over a range of atmospherically relevant time scales. In many cases, the molecular level composition of photobleached BrC exhibits only subtle changes suggesting that the optical and fluorescence properties of BrC are controlled by a few compounds present in low quantities. The observed fluorescence from non-biological BrC indicates potential issues in using fluorescence

  8. Reduction of the bulk absorption coefficient in silicon optics for high-energy lasers through defect engineering.

    PubMed

    Goodman, W A; Goorsky, M S

    1995-06-20

    We engineered a factor-of-4 reduction in the bulk absorption coefficient over the 2.6-to-3.0-µm bandwidth in single-crystal Czochralski silicon optics for high-energy infrared lasers with high-temperature annealing treatments. Defect engineering adapted from the integrated circuit industry has been used to reduce the absorption coefficient across the 1.5-to-5-µm bandwidth for substrates up to 5 cm thick. A high-temperature oxygen-dispersion anneal dissolves precipitates and thermal donors that are present in the as-grown material. The process has been verified experimentally with Fourier transform infrared spectroscopy, infrared laser calorimetry, and Hall measurements. Reduction of the absorption coefficient results in less substrate heating and thermal distortion of the optical surface. The process is appropriate for other silicon infrared optics applications such as thermal-imaging systems, infrared windows, and spectrophotometers.

  9. Absorption coefficients for the 6190-A CH4 band between 290 and 100 K with application to Uranus' atmosphere

    NASA Technical Reports Server (NTRS)

    Smith, Wm. Hayden; Conner, Charles P.; Baines, Kevin H.

    1990-01-01

    A novel laser intracavity photoacoustic spectroscopy method allowing high sample control accuracy due to the small sample volume required has been used to obtain absorption coefficients for the CH4 6190 A band as a function of temperature, from 290 to 100 K. The peak absorption coefficient is found to increase from 0.6 to 1.0/cm, and to be accompanied by significant band shape changes. When used to further constrain the Baines and Bergstrahl (1986) standard model of the Uranus atmosphere, the low-temperature data yield an excellent fit to the bandshape near the 6190 A band's minimum.

  10. Absorption coefficients for the 6190-A CH sub 4 band between 290 and 100 K with application to Uranus' atmosphere

    SciTech Connect

    Smith, WM.H.; Conner, C.P.; Baines, K.H. JPL, Pasadena, CA )

    1990-05-01

    A novel laser intracavity photoacoustic spectroscopy method allowing high sample control accuracy due to the small sample volume required has been used to obtain absorption coefficients for the CH{sub 4} 6190 A band as a function of temperature, from 290 to 100 K. The peak absorption coefficient is found to increase from 0.6 to 1.0/cm, and to be accompanied by significant band shape changes. When used to further constrain the Baines and Bergstrahl (1986) standard model of the Uranus atmosphere, the low-temperature data yield an excellent fit to the bandshape near the 6190 A band's minimum. 18 refs.

  11. Optoelectronic properties of Mg{sub 2}Si semiconducting layers with high absorption coefficients

    SciTech Connect

    Kato, Takashi; Sago, Yuichiro; Fujiwara, Hiroyuki

    2011-09-15

    In an attempt to develop a low-cost material for solar cell devices, polycrystalline magnesium silicide (poly-Mg{sub 2}Si) semiconducting layers have been prepared by applying rf magnetron sputtering using a Mg{sub 2}Si target. The optimum substrate temperature for the poly-Mg{sub 2}Si growth was found to be T{sub s} = 200 deg. C; the film deposition at higher temperatures leads to desorption of Mg atoms from the growing surface, while the amorphous phase formation occurs at room temperature. The poly-Mg{sub 2}Si layer deposited at T{sub s} = 200 deg. C shows the (111) preferential orientation with a uniform grain size of {approx}50 nm. The dielectric function of the poly-Mg{sub 2}Si layer has been determined accurately by spectroscopic ellipsometry. From the analysis, quite high absorption coefficients and an indirect gap of 0.77 eV in the poly-Mg{sub 2}Si layer have been confirmed. The above poly-Mg{sub 2}Si layer shows clear photoconductivity and can be applied as a narrow-gap bottom layer in multi-junction solar cell devices.

  12. Effects of nanosilver on sound absorption coefficients in solid wood species.

    PubMed

    Taghiyari, Hamid Reza; Esmailpour, Ayoub; Zolfaghari, Habib

    2016-06-01

    Sound absorption coefficients (ACs) were determined in five solid woods (poplar, beech, walnut, mulberry, and fir) in the longitudinal and tangential directions at four different frequencies of 800, 1000, 2000, and 4000 Hz. The length of the longitudinal and tangential specimens was 50-mm and 10-mm, respectively. Separate sets of specimens were impregnated with either nanosilver suspension or water. The size range of nanoparticles was 30-80 nm. Results showed that sound ACs were lower in longitudinal specimens because sound waves could penetrate the open ends of vessels more easily, being trapped and damped there. Impregnation with both nanosilver suspension and water resulted in a significant decrease in the sound ACs. The decrease in the ACs was due to the collapsing and accumulation of perforation plates and cell parts, blocking the way through which waves could pass through the vessels. This caused higher damping due to a phenomenon called vibration decay. Correlation between gas permeability versus sound AC is significantly dependant on the porous structure of individual specimens.

  13. Do lab-derived distribution coefficient values of pesticides match distribution coefficient values determined from column and field-scale experiments? A critical analysis of relevant literature.

    PubMed

    Vereecken, H; Vanderborght, J; Kasteel, R; Spiteller, M; Schäffer, A; Close, M

    2011-01-01

    In this study, we analyzed sorption parameters for pesticides that were derived from batch and column or batch and field experiments. The batch experiments analyzed in this study were run with the same pesticide and soil as in the column and field experiments. We analyzed the relationship between the pore water velocity of the column and field experiments, solute residence times, and sorption parameters, such as the organic carbon normalized distribution coefficient ( ) and the mass exchange coefficient in kinetic models, as well as the predictability of sorption parameters from basic soil properties. The batch/column analysis included 38 studies with a total of 139 observations. The batch/field analysis included five studies, resulting in a dataset of 24 observations. For the batch/column data, power law relationships between pore water velocity, residence time, and sorption constants were derived. The unexplained variability in these equations was reduced, taking into account the saturation status and the packing status (disturbed-undisturbed) of the soil sample. A new regression equation was derived that allows estimating the values derived from column experiments using organic matter and bulk density with an value of 0.56. Regression analysis of the batch/column data showed that the relationship between batch- and column-derived values depends on the saturation status and packing of the soil column. Analysis of the batch/field data showed that as the batch-derived value becomes larger, field-derived values tend to be lower than the corresponding batch-derived values, and vice versa. The present dataset also showed that the variability in the ratio of batch- to column-derived value increases with increasing pore water velocity, with a maximum value approaching 3.5.

  14. Mass-specific optical absorption coefficients and imaginary part of the complex refractive indices of mineral dust components measured by a multi-wavelength photoacoustic spectrometer

    NASA Astrophysics Data System (ADS)

    Utry, N.; Ajtai, T.; Pintér, M.; Tombácz, E.; Illés, E.; Bozóki, Z.; Szabó, G.

    2015-01-01

    Mass-specific optical absorption coefficients (MACs) and the imaginary part (κ) of the refractive indices of various mineral dust components including silicate clays (illite, kaolin and bentonite), oxides (quartz, hematite and rutile), and carbonate (limestone) were determined at the wavelengths of 1064, 532, 355 and 266 nm. The MAC values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA) instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. Values of κ were calculated from the measured and particle-loss-corrected data by using a Mie-theory-based retrieval algorithm. The determined values could be used for comparisons with calculated wavelength-dependent κ values typically deduced from bulk-phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk-phase measurements.

  15. ABSORBANCE, ABSORPTION COEFFICIENT, AND APPARENT QUANTUM YIELD: A COMMENT ON AMBIGUITY IN THE USE OF THESE OPTICAL CONCEPTS

    EPA Science Inventory

    Several important optical terms such as "absorbance" and "absorption coefficient" are frequently used ambiguously in the current peer-reviewed literature. Since they are important terms that are required to derive other quantities such as the "apparent quantum yield" of photoprod...

  16. Effects of suspended sediment concentration on the absorption and scattering coefficients

    NASA Astrophysics Data System (ADS)

    Terrie, Gregory E.; Ladner, Sherwin; Gould, Richard A., Jr.

    1997-02-01

    The scattering coefficient (b) for the nearshore waters off the coast of North Carolina near Camp Lejeune is strongly influenced by suspended sediment concentration and total particulate cross-sectional area (xg). In-situ measurements of a and b were made using a WET Labs AC9 meter. Estimates of suspended sediment concentration and total particulate cross-sectional area were determined from laser particle size analyses of surface water samples. The SeaWiFS bio-optical algorithm was modified for Case II waters and used to estimate a and bb from remote sensing reflectance (Rrs). After conversion from backscattering (bb) to total scattering (b), modeled a and b values from the modified SeaWiFS algorithm were compared to the measured values. The differences between the measured and estimated values appear to be directly related to increases in suspended sediment concentration and xg. Correlations of about 0.90 were obtained for b vs xg and bb vs xg.

  17. Threshold network of a financial market using the P-value of correlation coefficients

    NASA Astrophysics Data System (ADS)

    Ha, Gyeong-Gyun; Lee, Jae Woo; Nobi, Ashadun

    2015-06-01

    Threshold methods in financial networks are important tools for obtaining important information about the financial state of a market. Previously, absolute thresholds of correlation coefficients have been used; however, they have no relation to the length of time. We assign a threshold value depending on the size of the time window by using the P-value concept of statistics. We construct a threshold network (TN) at the same threshold value for two different time window sizes in the Korean Composite Stock Price Index (KOSPI). We measure network properties, such as the edge density, clustering coefficient, assortativity coefficient, and modularity. We determine that a significant difference exists between the network properties of the two time windows at the same threshold, especially during crises. This implies that the market information depends on the length of the time window when constructing the TN. We apply the same technique to Standard and Poor's 500 (S&P500) and observe similar results.

  18. Measurement of the mass energy-absorption coefficient of air for x-rays in the range from 3 to 60 keV.

    PubMed

    Buhr, H; Büermann, L; Gerlach, M; Krumrey, M; Rabus, H

    2012-12-21

    For the first time the absolute photon mass energy-absorption coefficient of air in the energy range of 10 to 60 keV has been measured with relative standard uncertainties below 1%, considerably smaller than those of up to 2% assumed for calculated data. For monochromatized synchrotron radiation from the electron storage ring BESSY II both the radiant power and the fraction of power deposited in dry air were measured using a cryogenic electrical substitution radiometer and a free air ionization chamber, respectively. The measured absorption coefficients were compared with state-of-the art calculations and showed an average deviation of 2% from calculations by Seltzer. However, they agree within 1% with data calculated earlier by Hubbell. In the course of this work, an improvement of the data analysis of a previous experimental determination of the mass energy-absorption coefficient of air in the range of 3 to 10 keV was found to be possible and corrected values of this preceding study are given.

  19. Molar Absorptivity Measurements in Absorbing Solvents: Impact on Solvent Absorptivity Values.

    PubMed

    Bohman, Ariel; Arnold, Mark A

    2016-10-18

    Molar absorptivity is a fundamental molecular property that quantifies absorption strength as a function of wavelength. Absolute measurements of molar absorptivity demand accounting for all mechanisms of light attenuation, including reflective losses at interfaces associated with the sample. Ideally, such measurements are performed in nonabsorbing solvents and reflective losses can be determined in a straightforward manner from Fresnel equations or effectively accounted for by path length difference methods. At near-infrared wavelengths, however, many solvents, including water, are absorbing which complicates the quantification of reflective losses. Here, generalized equations are developed for calculating absolute molar absorptivities of neat liquids wherein the dependency of reflective loss on absorption properties of the liquid are considered explicitly. The resulting equations are used to characterize sensitivity of absolute molar absorptivity measurements for solvents to the absorption strength of the solvent as well as the path length of the measurement. Methods are derived from these equations to properly account for reflective losses in general and the effectiveness of these methods is demonstrated for absolute molar absorptivity measurements for water over the combination region (5000-4000 cm(-1)) of the near-infrared spectrum. Results indicate that ignoring solvent absorption effects can incorporate wide ranging systematic errors depending upon experimental conditions. As an example, systematic errors range from 0 to 10% for common conditions used in the measurement of absolute molar absorptivity of water over the combination region of the near-infrared spectrum.

  20. Determination of molar absorptivity coefficients for major type-B trichothecenes and certification of calibrators for deoxynivalenol and nivalenol.

    PubMed

    Krska, Rudolf; Schubert-Ullrich, Patricia; Josephs, Ralf D; Emteborg, Håkan; Buttinger, Gerhard; Pettersson, Hans; van Egmond, Hans P; Schothorst, Ronald C; Macdonald, Susan; Chan, Danny

    2007-07-01

    This paper presents results from the European Commission-funded project Doncalibrant, the objective of which was to produce calibrators with certified mass fractions of the Fusarium toxins deoxynivalenol (DON), 3-acetyldeoxynivalenol (3-Ac-DON), 15-acetyldeoxynivalenol (15-Ac-DON), and nivalenol (NIV), in acetonitrile. The calibrators, available in ampoules, were sufficiently homogeneous, with between-bottle variations (s (bb)) of less than 2%. Long-term stability studies performed at four different temperatures between -18 and 40 degrees C revealed no significant negative trends (at a confidence level of 95%). Molar absorptivity coefficients (in L mol(-1) cm(-1)) were determined for all four toxins (DON: 6805 +/- 126, NIV: 6955 +/- 205, 3-Ac-DON: 6983 +/- 141, 15-Ac-DON: 6935 +/- 142) on the basis of a mini-interlaboratory exercise. The overall uncertainty of the calibrators' target values for DON and NIV were evaluated on the basis of gravimetric preparation data and include uncertainty contributions from possible heterogeneity, storage, and transport. The Doncalibrant project resulted in the production of calibrators for DON (IRMM-315) and NIV (IRMM-316) in acetonitrile with certified mass fractions of 25.1 +/- 1.2 microg g(-1) and 24.0 +/- 1.1 microg g(-1), respectively. Both CRMs became commercially available from the Institute for Reference Materials and Measurements (IRMM, Geel, Belgium) at the beginning of 2007.

  1. A reduced-scale railway noise barrier's insertion loss and absorption coefficients: comparison of field measurements and predictions

    NASA Astrophysics Data System (ADS)

    Busch, T. A.; Nugent, R. E.

    2003-10-01

    In situ testing determined the insertion loss ( IL) and absorption coefficients of a candidate absorptive noise barrier (soundwall) to abate railway noise for residents of Anaheim, CA. A 4000 m barrier is proposed south of the tracks, but residential areas to the north have expressed concerns that barrier reflections will increase their noise exposure. To address these concerns, a 3.66 m high by 14.6 m long demonstration barrier was built in the parking lot of Edison Field, Anaheim, as part of a public open house, thereby allowing for acoustical measurements. Insertion loss ( IL) was measured in third-octave bands assuming 1/2-scale construction. The IL for three, scaled railway noise sub-sources (rail/wheel interface, locomotive, and train horn) was measured at six, scaled distances. The highest total, A-weighted IL, after corrections for finite-barrier and point-source speaker effects was 22 dB(A) for rail/wheel noise, 18 dB(A) for locomotive noise, and 20 dB(A) for train horn noise. These results can be compared favourably to IL predictions made using algorithms from the US Federal Rail Administration (FRA) noise assessment guidelines. For the actual barrier installation, shielded residential receivers located south of the project are expected to see their future noise exposures reduced from an unmitigated 78 CNEL to 65 CNEL. Absorption coefficients were measured using time delay spectrometry. At lower frequencies, measured absorption coefficients were notably less than the reverberation room results advertised in the manufacturer's literature, but generally conformed with impedance tube results. At higher frequencies the correspondence between measured absorption coefficients and reverberation room results was much improved. For the actual barrier installation, unshielded residential receivers to the north are expected to experience noise exposure increases of less than 1 dB(A). This factor of increase is consistent with a finding of no impact when assessed

  2. Determination of true optical absorption and scattering coefficient of wooden cell wall substance by time-of-flight near infrared spectroscopy.

    PubMed

    Kitamura, Ryunosuke; Inagaki, Tetsuya; Tsuchikawa, Satoru

    2016-02-22

    The true absorption coefficient (μa) and reduced scattering coefficient (μ´s) of the cell wall substance in Douglas fir were determined using time-of-flight near infrared spectroscopy. Samples were saturated with hexane, toluene or quinolone to minimize the multiple reflections of light on the boundary between pore-cell wall substance in wood. μ´s exhibited its minimum value when the wood was saturated with toluene because the refractive index of toluene is close to that of the wood cell wall substance. The optical parameters of the wood cell wall substance calculated were μa = 0.030 mm(-1) and μ´s= 18.4 mm(-1). Monte Carlo simulations using these values were in good agreement with the measured time-resolved transmittance profiles.

  3. Impact of measurement uncertainties on determination of chlorophyll-specific absorption coefficient for marine phytoplankton

    NASA Astrophysics Data System (ADS)

    McKee, David; Röttgers, Rüdiger; Neukermans, Griet; Calzado, Violeta Sanjuan; Trees, Charles; Ampolo-Rella, Marina; Neil, Claire; Cunningham, Alex

    2014-12-01

    Understanding variability in the chlorophyll-specific absorption of marine phytoplankton, aph*Chl (λ), is essential for primary production modelling, calculation of underwater light field characteristics, and development of algorithms for remote sensing of chlorophyll concentrations. Previous field and laboratory studies have demonstrated significant apparent variability in aph*Chl (λ) for natural samples and algal cultures. However, the potential impact of measurement uncertainties on derived values of aph*Chl (λ) has received insufficient study. This study presents an analysis of measurement uncertainties for a data set collected in the Ligurian Sea in Spring and assesses the impact on estimates of aph*Chl (λ). It is found that a large proportion of apparent variability in this set of aph*Chl (λ) can be attributed to measurement errors. Application of the same analysis to the global NOMAD data set suggests that a significant fraction of variability in aph*Chl (λ) may also be due to measurement errors. The copyright line for this article was changed on 16 JAN 2015 after original online publication.

  4. [Experimental determination of radiation scattering and absorption coefficients in a homogeneous layer of highly-dispersive biological medium].

    PubMed

    Danilov, A A; Masloboev, Iu P; Selishchev, S V; Tereshchenko, S A

    2006-01-01

    A method for experimental determination of optical characteristics of a highly-dispersive medium (radiation scattering and absorption coefficients) is described. The method is based on two mathematical models of ultrashort laser pulse propagation through a highly-dispersive medium (HDM), an axial model and a diffusion model. Milk dissolved in water was used as HDM. Dependences of optical characteristics of HDM on the concentration of milk in water are obtained. The limits of applicability of the axial and diffusion models to media with different scattering and absorption characteristics are determined.

  5. The absorption coefficient of the liquid N2 2.15-micron band and application to Triton

    NASA Technical Reports Server (NTRS)

    Grundy, William M.; Fink, Uwe

    1991-01-01

    The present measurements of the temperature dependence exhibited by the liquid N2 2.15-micron 2-0 collision-induced band's absorption coefficient and integrated absorption show the latter to be smaller than that of the N2 gas, and to decrease with decreasing temperature. Extrapolating this behavior to Triton's nominal surface temperature yields a new estimate of the N2-ice grain size on the Triton south polar cap; a mean N2 grain size of 0.7-3.0 cm is consistent with grain growth rate calculation results.

  6. Characterizing the Chlorophyll-a Specific Absorption Coefficient of Phytoplankton Measured in the Gulf of Maine in Varying Oceanic Provinces

    NASA Astrophysics Data System (ADS)

    Dowell, M.

    2006-12-01

    Chlorophyll-a specific absorption (aph*) is a parameter used in bio-optical and primary production models and its coefficients are usually assumed to be constant. However, it has been documented in previous studies that these coefficients vary significantly due to pigmentation and "the package effect" which are a function of the taxonomic composition and the physiological state of the algal population. As part of the Coastal Ocean Observing Center (COOC) at the University of New Hampshire, HPLC pigments and phytoplankton absorption measurements were taken from water samples collected within the Gulf of Maine from 2004-2006. These data were then partitioned spatially, temporally, seasonally, and by other classification criteria. Spectral aph* means were generated for all partitions within each classification method. The results were used to parameterize province-specific bio-optical models for a regional algorithm. The separation of aph* means into different classes captured the effects of taxonomy and the package effect by reducing aph* variability.

  7. Absorption coefficients of CFC-11 and CFC-12 needed for atmospheric remote sensing and global warming studies

    NASA Technical Reports Server (NTRS)

    Varanasi, Prasad

    1992-01-01

    Spectral absorption coefficients k(v) in the atmospheric window are reported for CFC-11 and CFC-12. Data obtained with a grating spectrometer are compared with NCAR cross sections and measurements of k(v) made with a tunable diode laser spectrometer at various temperature-pressure combinations representing tangent heights or layers in the atmosphere are presented. The results are suitable for atmospheric remote sensing and global warming studies.

  8. Measurement of the x-ray mass energy-absorption coefficient of air using 3 keV to 10 keV synchrotron radiation.

    PubMed

    Büermann, L; Grosswendt, B; Kramer, H-M; Selbach, H-J; Gerlach, M; Hoffmann, M; Krumrey, M

    2006-10-21

    For the first time absolute photon mass energy-absorption coefficients of air in the energy range 3 keV to 10 keV have been measured with relative standard uncertainties less than 1%, significantly smaller than those of up to 5% assumed hitherto for calculated data. Monochromatized synchrotron radiation was used to measure both the total radiant energy by means of silicon photodiodes calibrated against a cryogenic radiometer and the fraction of radiant energy that is deposited in dry air by means of a free air ionization chamber. The measured ionization charge was converted into energy absorbed in air by calculated effective W values of photons as a function of their energy based on new measurements of the W values in dry air for electron kinetic energies between 1 keV and 7 keV, also presented in this work. The measured absorption coefficients were compared with state-of-the art calculations and found to agree within 0.7% with data calculated earlier by Hubbell at energies above 4 keV but were found to differ by values up to 2.1% at 10 keV from more recent calculations of Seltzer.

  9. The absorption of trapped particles by the inner satellites of Jupiter and the radial diffusion coefficient of particle transport

    NASA Technical Reports Server (NTRS)

    Mogro-Campero, A.; Fillius, W.

    1976-01-01

    The process of trapped particle absorption by the inner Jovian satellites is considered in detail taking into account both the particle and satellite motions in a magnetic dipole field which is displaced from the center of the planet and tilted with respect to the planetary rotation axis. An expression is derived for computing the sweeping time at a given satellite, defined as the time required for the satellite to sweep up a given fraction of the trapped particles within its sweeping region. By making use of the sweeping time and the radial diffusion equation of particle transport approximate expressions for the diffusion coefficient are derived. Measurements obtained by Pioneer 10 are then used to obtain estimates of the diffusion coefficient at the orbits of Io and Europa. We find that the diffusion coefficient is a function of energy and magnetic latitude for electrons in the energy range 0.7-14 MeV.

  10. Characterization of cysts using differential correlation coefficient values from two dimensional breast elastography: preliminary study.

    PubMed

    Booi, Rebecca C; Carson, Paul L; O'Donnell, Matthew; Roubidoux, Marilyn A; Hall, Anne L; Rubin, Jonathan M

    2008-01-01

    Although simple cysts are easily identified using sonography, description and management of nonsimple cysts remains uncertain. This study evaluated whether the correlation coefficient differences between breast tissue and lesions, obtained from 2D breast elastography, could potentially distinguish nonsimple cysts from cancers and fibroadenomas. We hypothesized that correlation coefficients in cysts would be dramatically lower than surrounding tissue because noise, imaging artifacts, and particulate matter move randomly and decorrelate quickly under compression, compared with solid tissue. For this preliminary study, 18 breast lesions (7 nonsimple cysts, 4 cancers, and 7 fibroadenomas) underwent imaging with 2D elastography at 7.5 MHz through a TPX (a polymethyl pentene copolymer) 2.5 mm mammographic paddle. Breasts were compressed similar to mammographic positioning and then further compressed for elastography by 1 to 7%. Images were correlated using 2D phase-sensitive speckle tracking algorithms and displacement estimates were accumulated. Correlation coefficient means and standard deviations were measured in the lesion and adjacent tissue, and the differential correlation coefficient (DCC) was introduced as the difference between these values normalized to the correlation coefficient of adjacent tissue. Mean DCC values in nonsimple cysts were 24.2 +/- 11.6%, 5.7 +/- 6.3% for fibroadenomas, and 3.8 +/- 2.9 % for cancers (p < 0.05). Some of the cysts appeared smaller in DCC images than gray-scale images. These encouraging results demonstrate that characterization of nonsimple breast cysts may be improved by using DCC values from 2D elastography, which could potentially change management options of these cysts from intervention to imaging follow-up. A dedicated clinical trial to fully assess the efficacy of this technique is recommended.

  11. CO2 laser photoacoustic measurements of ethanol absorption coefficients within infrared region of 9.2-10.8 μm

    NASA Astrophysics Data System (ADS)

    Ivascu, I. R.; Matei, C. E.; Patachia, M.; Bratu, A. M.; Dumitras, D. C.

    2016-06-01

    Absorption coefficients of the ethanol vapors at atmospheric pressure and room temperature were measured by photoacoustic technique using a cw, line-tunable, frequency-stabilized CO2 laser as radiation source. The spectrum of the employed CO2 laser includes 54 lines with wavelengths in the infrared region of 9.2-10.8 μm and power levels up to 4.7 W. Measurements revealed a predominant absorption for ethanol within 9.4 μm band of the CO2 laser spectrum, where the highest values of the absorption coefficients were recorded: 3.68 cm- 1 atm- 1 at 9R(20) line and 3.65 cm- 1 atm- 1 at 9R(22) line. The estimated detection range covers six orders of magnitude, from a minimum of 30 ppbV to a maximum of 4% concentration of ethanol in nitrogen, which proves the suitability of the photoacoustic technique for accurate measurements of the ethanol concentration in various applications.

  12. CO2 laser photoacoustic measurements of ethanol absorption coefficients within infrared region of 9.2-10.8 μm.

    PubMed

    Ivascu, I R; Matei, C E; Patachia, M; Bratu, A M; Dumitras, D C

    2016-06-15

    Absorption coefficients of the ethanol vapors at atmospheric pressure and room temperature were measured by photoacoustic technique using a cw, line-tunable, frequency-stabilized CO2 laser as radiation source. The spectrum of the employed CO2 laser includes 54 lines with wavelengths in the infrared region of 9.2-10.8μm and power levels up to 4.7W. Measurements revealed a predominant absorption for ethanol within 9.4μm band of the CO2 laser spectrum, where the highest values of the absorption coefficients were recorded: 3.68cm(-1)atm(-1) at 9R(20) line and 3.65cm(-1)atm(-1) at 9R(22) line. The estimated detection range covers six orders of magnitude, from a minimum of 30ppbV to a maximum of 4% concentration of ethanol in nitrogen, which proves the suitability of the photoacoustic technique for accurate measurements of the ethanol concentration in various applications.

  13. A Multi-Band Analytical Algorithm for Deriving Absorption and Backscattering Coefficients from Remote-Sensing Reflectance of Optically Deep Waters

    NASA Technical Reports Server (NTRS)

    Lee, Zhong-Ping; Carder, Kendall L.

    2001-01-01

    A multi-band analytical (MBA) algorithm is developed to retrieve absorption and backscattering coefficients for optically deep waters, which can be applied to data from past and current satellite sensors, as well as data from hyperspectral sensors. This MBA algorithm applies a remote-sensing reflectance model derived from the Radiative Transfer Equation, and values of absorption and backscattering coefficients are analytically calculated from values of remote-sensing reflectance. There are only limited empirical relationships involved in the algorithm, which implies that this MBA algorithm could be applied to a wide dynamic range of waters. Applying the algorithm to a simulated non-"Case 1" data set, which has no relation to the development of the algorithm, the percentage error for the total absorption coefficient at 440 nm a (sub 440) is approximately 12% for a range of 0.012 - 2.1 per meter (approximately 6% for a (sub 440) less than approximately 0.3 per meter), while a traditional band-ratio approach returns a percentage error of approximately 30%. Applying it to a field data set ranging from 0.025 to 2.0 per meter, the result for a (sub 440) is very close to that using a full spectrum optimization technique (9.6% difference). Compared to the optimization approach, the MBA algorithm cuts the computation time dramatically with only a small sacrifice in accuracy, making it suitable for processing large data sets such as satellite images. Significant improvements over empirical algorithms have also been achieved in retrieving the optical properties of optically deep waters.

  14. Experimental determination of heat transfer coefficient in the slip regime and its anomalously low value

    NASA Astrophysics Data System (ADS)

    Demsis, Anwar; Verma, Bhaskar; Prabhu, S. V.; Agrawal, Amit

    2009-07-01

    In this paper, the measurement of the heat transfer coefficient in rarefied gases is presented; these are among the first heat transfer measurements in the slip flow regime. The experimental setup is validated by comparing friction factor in the slip regime and heat transfer coefficient in the continuum regime. Experimental results suggest that the Nusselt number is a function of Reynolds and Knudsen numbers in the slip flow regime. The measured values for Nusselt numbers are smaller than that predicted by theoretical or simulation results, and can become a few orders of magnitude smaller than the theoretical values in the continuum regime. The results are repeatable and expected to be useful for further experimentation and modeling of flow in the slip and transition regimes.

  15. Functional Linear Model with Zero-value Coefficient Function at Sub-regions.

    PubMed

    Zhou, Jianhui; Wang, Nae-Yuh; Wang, Naisyin

    2013-01-01

    We propose a shrinkage method to estimate the coefficient function in a functional linear regression model when the value of the coefficient function is zero within certain sub-regions. Besides identifying the null region in which the coefficient function is zero, we also aim to perform estimation and inferences for the nonparametrically estimated coefficient function without over-shrinking the values. Our proposal consists of two stages. In stage one, the Dantzig selector is employed to provide initial location of the null region. In stage two, we propose a group SCAD approach to refine the estimated location of the null region and to provide the estimation and inference procedures for the coefficient function. Our considerations have certain advantages in this functional setup. One goal is to reduce the number of parameters employed in the model. With a one-stage procedure, it is needed to use a large number of knots in order to precisely identify the zero-coefficient region; however, the variation and estimation difficulties increase with the number of parameters. Owing to the additional refinement stage, we avoid this necessity and our estimator achieves superior numerical performance in practice. We show that our estimator enjoys the Oracle property; it identifies the null region with probability tending to 1, and it achieves the same asymptotic normality for the estimated coefficient function on the non-null region as the functional linear model estimator when the non-null region is known. Numerically, our refined estimator overcomes the shortcomings of the initial Dantzig estimator which tends to under-estimate the absolute scale of non-zero coefficients. The performance of the proposed method is illustrated in simulation studies. We apply the method in an analysis of data collected by the Johns Hopkins Precursors Study, where the primary interests are in estimating the strength of association between body mass index in midlife and the quality of life in

  16. Absorption coefficient modeling of microcrystalline silicon thin film using Maxwell-Garnett effective medium theory.

    PubMed

    Chen, Sheng-Hui; Wang, Hsuan-Wen; Chang, Ting-Wei

    2012-03-12

    Considering the Mott-Davis density of state model and Rayleigh scattering effect, we present an approach to model the absorption profile of microcrystalline silicon thin films in this paper. Maxwell-Garnett effective medium theory was applied to analyze the absorption curves. To validate the model, several experimental profiles have been established and compared with those results from the model. With the assistance of the genetic algorithm, our results show that the absorption curves from the model are in good agreement with the experiments. Our findings also indicate that, as the crystal volume fraction increases, not only do the defects in amorphous silicon reduce, but the bulk scattering effect is gradually enhanced as well.

  17. Simultaneous Maximum-Likelihood Reconstruction of Absorption Coefficient, Refractive Index and Dark-Field Scattering Coefficient in X-Ray Talbot-Lau Tomography

    PubMed Central

    Ritter, André; Anton, Gisela; Weber, Thomas

    2016-01-01

    A maximum-likelihood reconstruction technique for X-ray Talbot-Lau tomography is presented. This technique allows the iterative simultaneous reconstruction of discrete distributions of absorption coefficient, refractive index and a dark-field scattering coefficient. This technique avoids prior phase retrieval in the tomographic projection images and thus in principle allows reconstruction from tomographic data with less than three phase steps per projection. A numerical phantom is defined which is used to evaluate convergence of the technique with regard to photon statistics and with regard to the number of projection angles and phase steps used. It is shown that the use of a random phase sampling pattern allows the reconstruction even for the extreme case of only one single phase step per projection. The technique is successfully applied to measured tomographic data of a mouse. In future, this reconstruction technique might also be used to implement enhanced imaging models for X-ray Talbot-Lau tomography. These enhancements might be suited to correct for example beam hardening and dispersion artifacts and improve overall image quality of X-ray Talbot-Lau tomography. PMID:27695126

  18. Effect of electron collisions on transport coefficients induced by the inverse bremsstrahlung absorption in plasmas

    SciTech Connect

    Bendib, A.; Tahraoui, A.; Bendib, K.; Mohammed El Hadj, K.; Hueller, S.

    2005-03-01

    The transport coefficients of fully ionized plasmas under the influence of a high-frequency electric field are derived solving numerically the electron Fokker-Planck equation using a perturbation method, parametrized as a function of the electron mean-free-path {lambda}{sub ei} compared to the spatial scales L. The isotropic and anisotropic contributions of the inverse bremsstrahlung heating are considered. Electron-electron collision terms are kept in the analysis, which allows us to consider with sufficient accuracy to describe plasmas with arbitrary atomic number Z. Practical numerical fits of the transport coefficients are proposed as functions of Z and the collisionality parameter {lambda}{sub ei}/L.

  19. Uranyl ion: A convenient standard for transient molar absorption coefficient measurements

    SciTech Connect

    Bakac, A.; Burrows, H.D.

    1997-12-01

    Transient absorption spectra of an aqueous solution of uranyl sulfate have been measured in the ultraviolet and visible spectra. The excited uranyl ion may be a convenient standard for actinometry and photoacoustic calorimetry. (AIP) {copyright} {ital 1997} {ital Society for Applied Spectroscopy}

  20. Intersubband transition in lattice-matched BGaN/AlN quantum well structures with high absorption coefficients.

    PubMed

    Park, Seoung-Hwan; Ahn, Doyeol; Park, Chan-Yong

    2017-02-20

    Intersubband absorption properties of lattice-matched BGaN/AlN quantum well (QW) structures grown on AlN substrate are theoretically investigated using an effective mass theory considering the nonparabolicity of the conduction band. These results are compared with those of GaN/AlN QW structures. The intersubband absorption coefficient of the BGaN/AlN QW structure is shown to be enhanced significantly, compared to that of the conventional GaN/AlN QW structure. This can be explained by the fact that the BGaN/AlN QW structure exhibits larger intersuband dipole moment and quasi-Fermi-level separation than the GaN/AlN QW structure, due to the increase in the carrier confinement by a larger internal field. We expect that the BGaN/AlN QW structure with a high absorption coefficient can be used for telecommunication applications at 1.55 µm under the lattice-matched condition, instead of the conventional GaN/AlN QW structure with the large strain.

  1. Spatial variability of absorption coefficients over a biogeochemical gradient in a large and optically complex shallow lake

    NASA Astrophysics Data System (ADS)

    Riddick, Caitlin A. L.; Hunter, Peter D.; Tyler, Andrew N.; Martinez-Vicente, Victor; Horváth, Hajnalka; Kovács, Attila W.; Vörös, Lajos; Preston, Tom; Présing, Mátyás.

    2015-10-01

    In order to improve robustness of remote sensing algorithms for lakes, it is vital to understand the variability of inherent optical properties (IOPs) and their mass-specific representations (SIOPs). In this study, absorption coefficients for particulate and dissolved constituents were measured at 38 stations distributed over a biogeochemical gradient in Lake Balaton, Hungary. There was a large range of phytoplankton absorption (aph(λ)) over blue and red wavelengths (aph(440) = 0.11-4.39 m-1, aph(675) = 0.048-2.52 m-1), while there was less variability in chlorophyll-specific phytoplankton absorption (a*ph(λ)) in the lake (a*ph(440) = 0.022 ± 0.0046 m2 mg-1, a*ph(675) = 0.010 ± 0.0020 m2 mg-1) and adjoining wetland system, Kis-Balaton (a*ph(440) = 0.017 ± 0.0015 m2 mg-1, a*ph(675) = 0.0088 ± 0.0017 m2 mg-1). However, in the UV, a*ph(350) significantly increased with increasing distance from the main inflow (Zala River). This was likely due to variable production of photoprotective pigments (e.g., MAAs) in response to the decreasing gradient of colored dissolved organic matter (CDOM). The slope of CDOM absorption (SCDOM) also increased from west to east due to larger terrestrial CDOM input in the western basins. Absorption by nonalgal particles (aNAP(λ)) was highly influenced by inorganic particulates, as a result of the largely mineral sediments in Balaton. The relative contributions to the absorption budget varied more widely than oceans with a greater contribution from NAP (up to 30%), and wind speed affected the proportion attributed to NAP, phytoplankton, or CDOM. Ultimately, these data provide knowledge of the heterogeneity of (S)IOPs in Lake Balaton, suggesting the full range of variability must be considered for future improvement of analytical algorithms for constituent retrieval in inland waters.

  2. Spatial variations in the chlorophyll-specific absorption coefficients of phytoplankton and photosynthetically active pigments in the equatorial Pacific

    NASA Astrophysics Data System (ADS)

    Allali, Karima; Bricaud, Annick; Claustre, Hervé

    1997-01-01

    Chlorophyll-specific absorption coefficients of particles, a*p(λ), and of phytoplankton, a*ph(λ), were determined using the glass-fiber filter technique along 150°W in the equatorial Pacific (13°S-1°N). A site-specific algorithm for correcting the path length amplification effect was derived from field measurements. Then a decomposition technique using the high-performance liquid chromatography pigment information and taking into account the package effect was used to partition a*ph into the contributions of photosynthetic pigments (a*ps) and nonphotosynthetic pigments (a*nps). Both a*ph and a*nps values were observed to decrease from the oligotrophic waters of the subequatorial area (13°-1°S) to the mesotrophic waters of the equatorial area (1°S-1°N) and from the surface to deep waters. The a*ph variations were primarily, but not exclusively, caused by changes in the concentrations of nonphotosynthetic pigments. The level of pigment packaging was also variable both horizontally and vertically, as a result of changes in populations and photoacclimation. In comparison with a*ph, a*ps exhibited a reduced range of variation with depth and along the latitudinal gradient. The variations in a*ps originating from the package effect were partly compensated by variations in the concentrations of photosynthetic pigments. We extended this analysis to include data collected in other areas with different trophic states. The a*ps values varied over a factor of 4 at 440 nm, instead of 8 for a*ph, for chlorophyll a concentrations covering 2 orders of magnitude (0.02-2 mg m-3). In agreement with a previous study performed off California with a different method [Sosik and Mitchell, 1995], we conclude that a*ps is less dependent on environmental parameters than a*ph. In addition, our results provide evidence that the variability in a*ps cannot be neglected. The use of a*ps instead of a*ph in light-photosynthesis models (in conjunction with a quantum yield for carbon fixation

  3. The Optical Absorption Coefficient of Barley Seeds Investigated by Photoacoustic Spectroscopy and Their Effects by Laser Biostimulation

    NASA Astrophysics Data System (ADS)

    Pérez Reyes, Ma. C.; Hernandez-Aguilar, C.; Dominguez-Pacheco, A.; Cruz-Orea, A.; Moreno Martínez, E.

    2015-09-01

    Laser light as a biostimulator has been applied in agriculture, and some scientific reports evidence its usefulness. A knowledge about seed optical parameters is of great relevance in the biostimulation process, because information can be provided about the light absorption of seeds. Thus, the objective of the present study was to determine the optical absorption coefficient (β ) of barley ( Hordeum vulgare L.) seeds by means of photoacoustic spectroscopy; these seeds were studied in two conditions: seeds in their natural color and seeds dyed with methylene blue. The seeds were biostimulated by a laser beam (650 nm wavelength) to evaluate the effects of pre-sowing biostimulation in natural mycobiota associated with different laser irradiation times (0 s, 60 s, 120 s, 240 s, and 480 s). The results of this research demonstrated changes in the optical parameters (absorption and penetration) that occur in the seeds by changing the natural condition to a dyed condition. The dyed seeds, by the methylene blue photosensitizer, become optically opaque, producing greater optical absorption at 650 nm which causes an increase in the effect of laser stimulation. The experimental results showed that the biggest mycobiota reduction (52 %) corresponded to dyed seeds irradiated with a laser for 120 s.

  4. Specific absorption and backscatter coefficient signatures in southeastern Atlantic coastal waters

    NASA Astrophysics Data System (ADS)

    Bostater, Charles R., Jr.

    1998-12-01

    Measurements of natural water samples in the field and laboratory of hyperspectral signatures of total absorption and reflectance were obtained using long pathlength absorption systems (50 cm pathlength). Water was sampled in Indian River Lagoon, Banana River and Port Canaveral, Florida. Stations were also occupied in near coastal waters out to the edge of the Gulf Stream in the vicinity of Kennedy Space Center, Florida and estuarine waters along Port Royal Sound and along the Beaufort River tidal area in South Carolina. The measurements were utilized to calculate natural water specific absorption, total backscatter and specific backscatter optical signatures. The resulting optical cross section signatures suggest different models are needed for the different water types and that the common linear model may only appropriate for coastal and oceanic water types. Mean particle size estimates based on the optical cross section, suggest as expected, that particle size of oceanic particles are smaller than more turbid water types. The data discussed and presented are necessary for remote sensing applications of sensors as well as for development and inversion of remote sensing algorithms.

  5. Parameter identifiability and Extended Multiple Studies Analysis of a compartmental model for human vitamin A kinetics: fixing fractional transfer coefficients for the initial steps in the absorptive process.

    PubMed

    Park, Hyunjin; Green, Michael H

    2014-03-28

    In the existing compartmental models of human vitamin A metabolism, parameters related to the absorption of the isotopic oral dose have not been well identified. We hypothesised that fixing some poorly identified parameters related to vitamin A absorption would improve parameter identifiability and add statistical certainty to such models. In the present study, data for serum vitamin A kinetics in nine subjects given [2H8]retinyl acetate orally and a model with absorption fixed at 75 % were used to test this hypothesis. In addition to absorption efficiency, we fixed two other fractional transfer coefficients: one representing the initial processing of the ingested dose and the other representing the direct secretion of retinol bound to retinol-binding protein (RBP) from enterocytes into the plasma. The Windows version of Simulation, Analysis and Modeling software (WinSAAM) was used to fit serum tracer data v. time for each subject. Then, a population model was generated by WinSAAM's Extended Multiple Studies Analysis. All the parameters had fractional standard deviations < 0·5, and none of the pairs of parameters had a correlation coefficient >0·8 (accepted criteria for well-identified parameters). Similar to the values predicted by the original model, total traced mass for retinol was 1160 (sd 468) μmol, and the time for retinol to appear in the plasma bound to RBP was 31·3 (sd 4·4) h. In conclusion, we suggest that this approach holds promise for advancing compartmental modelling of vitamin A kinetics in humans when the dose must be administered orally.

  6. [Gas Concentration Measurement Based on the Integral Value of Absorptance Spectrum].

    PubMed

    Liu, Hui-jun; Tao, Shao-hua; Yang, Bing-chu; Deng, Hong-gui

    2015-12-01

    The absorptance spectrum of a gas is the basis for the qualitative and quantitative analysis of the gas by the law of the Lambert-Beer. The integral value of the absorptance spectrum is an important parameter to describe the characteristics of the gas absorption. Based on the measured absorptance spectrum of a gas, we collected the required data from the database of HIT-RAN, and chose one of the spectral lines and calculated the integral value of the absorptance spectrum in the frequency domain, and then substituted the integral value into Lambert-Beer's law to obtain the concentration of the detected gas. By calculating the integral value of the absorptance spectrum we can avoid the more complicated calculation of the spectral line function and a series of standard gases for calibration, so the gas concentration measurement will be simpler and faster. We studied the changing trends of the integral values of the absorptance spectrums versus temperature. Since temperature variation would cause the corresponding variation in pressure, we studied the changing trends of the integral values of the absorptance spectrums versus both the pressure not changed with temperature and changed with the temperature variation. Based on the two cases, we found that the integral values of the absorptance spectrums both would firstly increase, then decrease, and finally stabilize with temperature increasing, but the ranges of specific changing trend were different in the two cases. In the experiments, we found that the relative errors of the integrated values of the absorptance spectrum were much higher than 1% and still increased with temperature when we only considered the change of temperature and completely ignored the pressure affected by the temperature variation, and the relative errors of the integrated values of the absorptance spectrum were almost constant at about only 1% when we considered that the pressure were affected by the temperature variation. As the integral value

  7. Using high-resolution laboratory and ground-based solar spectra to assess CH4 absorption coefficient calculations

    NASA Astrophysics Data System (ADS)

    Mendonca, J.; Strong, K.; Sung, K.; Devi, V. M.; Toon, G. C.; Wunch, D.; Franklin, J. E.

    2017-03-01

    A quadratic-speed-dependent Voigt line shape (qSDV) with line mixing (qSDV+LM), together with spectroscopic line parameters from Devi et al. [1,2] for the 2v3 band of CH4, was used to retrieve total columns of CH4 from atmospheric solar absorption spectra. The qSDV line shape (Tran et al., 2013) [3] with line mixing (Lévy et al., 1992) [4] was implemented into the forward model of GFIT (the retrieval algorithm that is at the heart of the GGG software (Wunch et al., 2015) [5]) to calculate CH4 absorption coefficients. High-resolution laboratory spectra of CH4 were used to assess absorption coefficients calculated using a Voigt line shape and spectroscopic parameters from the atm line list (Toon, 2014) [6]. The same laboratory spectra were used to test absorption coefficients calculated using the qSDV+LM line shape with spectroscopic line parameters from Devi et al. [1,2] for the 2v3 band of CH4 and a Voigt line shape for lines that don't belong to the 2v3 band. The spectral line list for lines that don't belong to the 2v3 band is an amalgamation of multiple spectral line lists. We found that for the P, Q, and R branches of the 2v3 band, the qSDV+LM simulated the laboratory spectra better than the Voigt line shape. The qSDV+LM was also used in the spectral fitting of high-resolution solar absorption spectra from four ground-based remote sensing sites and compared to spectra fitted with a Voigt line shape. The average root mean square (RMS) residual for 131,124 solar absorption spectra fitted with absorption coefficients calculated using the qSDV+LM for the 2v3 band of CH4 and the new spectral line list for lines for lines that don't belong to the 2v3 band, was reduced in the P, Q, and R branches by 5%, 13%, and 3%, respectively when compared with spectra fitted using a Voigt line shape and the atm line list. We found that the average total column of CH4 retrieved from these 131,124 spectra, with the qSDV+LM was 1.1±0.3% higher than the retrievals performed using a

  8. Effect of quantum dot size and size distribution on the intersublevel transitions and absorption coefficients of III-V semiconductor quantum dot

    SciTech Connect

    Kabi, Sanjib; Perera, A. G. Unil

    2015-03-28

    The intersublevel absorption peak energy and absorption coefficient of non-uniform quantum dot (QD) ensembles are calculated analytically. The effect of size variations and size distribution of QDs on their energy states is analyzed. The dots are considered as a quantum box with finite potential at the barriers and the size distribution described by a Gaussian function. The influence of the aspect ratio (base to height ratio) of the QDs on the optical transitions is studied. Our model predicts the dot size (height and base) accurately to determine the absorption peaks and corresponding absorption coefficient. We also compute the absorption coefficient of the QD with different size distributions to verify the results calculated using this model with the reported experimental and other theoretical results.

  9. Effects of magnetic field and the built-in internal fields on the absorption coefficients in a strained wurtzite GaN/AlGaN quantum dot

    NASA Astrophysics Data System (ADS)

    Minimala, N. S.; Peter, A. John

    2013-02-01

    Effects of magnetic field strength and the built-in electric fields on the exciton binding energy and the non-linear optical property such as absorption coefficients in a GaN/AlGaN wide band gap heterostructure are investigated. The internal fields due to spontaneous and piezo-electric polarizations are included in the Hamiltonian. Our results show that the optical absorption coefficients strongly depend on the internal fields and the applied magnetic field.

  10. Changing of optical absorption and scattering coefficients in nonlinear-optical crystal lithium triborate before and after interaction with UV-radiation

    NASA Astrophysics Data System (ADS)

    Demkin, Artem S.; Nikitin, Dmitriy G.; Ryabushkin, Oleg A.

    2016-04-01

    In current work optical properties of LiB3O5 (LBO) crystal with ultraviolet (UV) (λ= 266 nm) induced volume macroscopic defect (track) are investigated using novel piezoelectric resonance laser calorimetry technique. Pulsed laser radiation of 10 W average power at 532 nm wavelength, is consecutively focused into spatial regions with and without optical defect. For these cases exponential fitting of crystal temperature kinetics measured during its irradiation gives different optical absorption coefficients α1 = 8.1 • 10-4 cm-1 (region with defect) and α =3.9ṡ10-4 cm-1 (non-defected region). Optical scattering coefficient is determined as the difference between optical absorption coefficients measured for opaque and transparent lateral facets of the crystal respectively. Measurements reveal that scattering coefficient of LBO in the region with defect is three times higher than the optical absorption coefficient.

  11. Extension of the Inverse Adding-Doubling Method to the Measurement of Wavelength-Dependent Absorption and Scattering Coefficients of Biological Samples

    SciTech Connect

    Baba, Justin S; Allegood, Marcus S

    2008-01-01

    Light interaction with biological tissue can be described using three parameters: the scattering and absorption coefficients (us and ua), as well as the anisotropy (g) which describes the directional dependence of the scattered photons. Accurately determining these optical properties for different tissue types at specific wavelengths, and simultaneously, would be beneficial for a variety of different biomedical applications. The goal of this project was to take a user-defined g-value and determine the remaining two parameters for a specified wavelength range for an integrating sphere with a collimated white light input source system. A fully automated computer program and process was developed to collect data for all wavelengths in a timely and accurate manner. LabVIEW was used to write programs to automate: raw intensity data collection from a spectrometer equipped integrating sphere, conversion of the data into a format for analysis via Scott Prahl's Inverse Adding-Doubling (IAD) C code execution, and computation of the optical properties based on the output from the IAD code. To allow data to be passed efficiently between LabVIEW and C code program modules, the two were combined into a single program (OPT 3.1). OPT 3.1 was tested using tissue mimicking phantoms and determination of the absorption and scattering coefficients showed excellent agreement with theory for wavelengths were the user inputted single g-value was sufficiently precise. Future improvements entail providing for multi-wavelength g-value entry to extend the accuracy of results to encompass the complete system multispectral range. Ultimately, the data collection process and algorithms developed through this effort will be used to study actual biological tissues for the purpose of deriving and refining models for light-tissue interactions.

  12. Photoinduced transparency of effective three-photon absorption coefficient for femtosecond laser pulses in Ge16As29Se55 thin films

    NASA Astrophysics Data System (ADS)

    Barik, A. R.; Adarsh, K. V.; Naik, Ramakanta; Sandeep, C. S. Suchand; Philip, Reji; Zhao, Donghui; Jain, Himanshu

    2011-05-01

    We report a dramatic change in effective three-photon absorption coefficient of amorphous Ge16As29Se55 thin films, when its optical band gap decreases by 10 meV with 532 nm light illumination. This large change provides valuable information on the higher excited states, which are otherwise inaccessible via normal optical absorption. The results also indicate that photodarkening in chalcogenide glasses can serve as an effective tool to tune the multiphoton absorption in a rather simple way.

  13. Intrinsic absolute bioavailability prediction in rats based on in situ absorption rate constants and/or in vitro partition coefficients: 6-fluoroquinolones.

    PubMed

    Sánchez-Castaño, G; Ruíz-García, A; Bañón, N; Bermejo, M; Merino, V; Freixas, J; Garriguesx, T M; Plá-Delfina, J M

    2000-11-01

    A preliminary study attempting to predict the intrinsic absolute bioavailability of a group of antibacterial 6-fluoroquinolones-including true and imperfect homologues as well as heterologues-was carried out. The intrinsic absolute bioavailability of the test compounds, F, was assessed on permanently cannulated conscious rats by comparing the trapezoidal normalized areas under the plasma concentration-time curves obtained by intravenous and oral routes (n = 8-12). The high-performance liquid chromatography analytical methods used for plasma samples are described. Prediction of the absolute bioavailability of the compounds was based on their intrinsic rat gut in situ absorption rate constant, k(a). The working equation was: where T represents the mean absorbing time. A T value of 0.93 (+/-0.06) h provides the best correlation between predicted and experimentally obtained bioavailabilities (F' and F, respectively) when k(a) values are used (slope a = 1.10; intercept b = -0.05; r = 0.991). The k(a) values can also be expressed in function of the in vitro partition coefficients, P, between n-octanol and a phosphate buffer. In this case, theoretical k(a) values can be determined with the parameters of a standard k(a)/P correlation previously established for a group of model compounds. When P values are taken instead of k(a) values, reliable bioavailability predictions can also be made. These and other relevant features of the method are discussed.

  14. Water absorption lines, 931-961 nm - Selected intensities, N2-collision-broadening coefficients, self-broadening coefficients, and pressure shifts in air

    NASA Technical Reports Server (NTRS)

    Giver, L. P.; Gentry, B.; Schwemmer, G.; Wilkerson, T. D.

    1982-01-01

    Intensities were measured for 97 lines of H2O vapor between 932 and 961 nm. The lines were selected for their potential usefulness for remote laser measurements of H2O vapor in the earth's atmosphere. The spectra were obtained with several different H2O vapor abundances and N2 broadening gas pressures; the spectral resolution was 0.046/cm FWHM. Measured H2O line intensities range from 7 x 10 to the -25th to 7 x 10 to the -22nd/cm per (molecules/sq cm). H2O self-broadening coefficients were measured for 13 of these strongest lines; the mean value was 0.5/cm per atm. N2-collision-broadening coefficients were measured for 73 lines, and the average was 0.11 cm per atm HWHM. Pressure shifts in air were determined for a sample of six lines between 948 and 950 nm; these lines shift to lower frequency by an amount comparable to 0.1 of the collision-broadened widths measured in air or N2. The measured intensities of many lines of 300-000 band are much larger than expected from prior computations, in some cases by over an order of magnitude. Coriolis interactions with the stronger 201-000 band appear to be the primary cause of the enhancement of these line intensities.

  15. Optimizing Thermal-Optical Analysis for Atmospheric Black Carbon (BC): Determining the Beer-Lambert Mass Without a Fixed Mass Absorption Coefficient for BC

    NASA Astrophysics Data System (ADS)

    Conny, J. M.; Norris, G.

    2007-12-01

    In thermal-optical transmission analysis (TOT), laser light passing through a particle-laden filter is monitored while carbonaceous material is removed in several heating steps and measured by flame ionization detection. In a helium atmosphere, the laser signal is attenuated by the pyrolysis of organic carbon (OC). Later, while carbon is removed in an oxidizing atmosphere, the laser signal returns to its value prior to pyrolysis (split point), whereupon the amount of carbon equivalent to the native BC is measured. Since pyrolyzed OC may actually evolve beyond the split point, the specific absorption cross sections of pyrolyzed OC and native BC must be equivalent. Moreover, OC pyrolysis must be sufficient so that unpyrolyzed OC is not measured as BC beyond the split point. Using response surfaces models of the apparent specific absorption cross sections for pyrolyzed OC and what the instrument measures as native BC, we determined the thermal conditions for establishing the equivalence of the apparent cross sections while insuring sufficient pyrolysis of OC. In this way, we have optimized TOT for BC mass based on the Beer-Lambert Law but without the need for an absolute mass absorption coefficient (or an absolute attenuation coefficient) for BC. Optimal thermal conditions for the equivalence of the cross sections were indicated by the intersection of the response surfaces. Concurrently, optimal conditions for sufficient pyrolysis of OC were indicated by a plateau in the response surface for the BC cross section. Modeling was based on extensive analyses of PM2.5 samples collected from Atlanta, Los Angeles, and Seattle. Although this work was reviewed by EPA and approved for publication, it may not necessarily reflect official Agency policy.

  16. Value of apparent diffusion coefficient measurement for discrimination of focal benign and malignant hepatic masses.

    PubMed

    Kilickesmez, O; Bayramoglu, S; Inci, E; Cimilli, T

    2009-02-01

    The purpose of our study was to investigate the value of diffusion-weighted magnetic resonance imaging (DW-MRI) to discriminate benign and malignant focal lesions of the liver using parallel imaging technique. A total of 77 patients and 65 healthy controls were enrolled in the study. DW-MRI was performed with b-factors of 0, 500 and 1000 s/mm(2), and the apparent diffusion coefficients (ADC) values of the normal liver and the lesions were calculated. The mean ADC value of the focal liver lesions were as follows: simple cysts (3.16 +/- 0.18 x 10(-3) mm(2)/s), hydatid cysts (2.58 +/- 0.53 x 10(-3) mm(2)/s), hemangiomas (1.97 +/- 0.49 x 10(-3) mm(2)/s), metastases (1.14 +/- 0.41 x 10(-3) mm(2)/s) and hepatocellular carcinomas (HCC) (1.15 +/- 0.36 x 10(-3) mm(2)/s). The mean ADC values of all the disease groups were statistically significant when compared with the mean ADC value of the normal liver (1.56 +/- 0.14 x 10(-3) mm(2)/s), (P < 0.01). There were also statistically significant differences among the ADC values of hemangiomas and HCC metastases (P < 0.01), and simple and hydatid cysts (P < 0.008). However, there was no statistically significant difference between HCC and metastases. The present study showed that ADC measurement has the potential to differentiate benign and malignant focal hepatic lesions. We propose to add DW sequence in the MR protocol for the detection and quantitative discrimination of hepatic pathologies.

  17. A time-resolved single-pass technique for measuring optical absorption coefficients of window materials under 100 GPa shock pressures.

    PubMed

    Li, Jun; Zhou, Xianming; Li, Jiabo

    2008-12-01

    An experimental method was developed to perform time-resolved, single-pass optical absorption measurements and to determine absorption coefficients of window materials under strong shock compression up to approximately 200 GPa. Experimental details are described of (i) a configuration to generate an in situ dynamic, bright, optical source and (ii) a sample assembly with a lithium fluoride plate to essentially eliminate heat transfer from the hot radiator into the specimen and to maintain a constant optical source within the duration of the experiment. Examples of measurements of optical absorption coefficients of several initially transparent single crystal materials at high shock pressures are presented.

  18. Measurement of the solar heat gain coefficient and U value of windows with insect screens

    SciTech Connect

    Brunger, A.; Dubrous, F.M.; Harrison, S.

    1999-07-01

    Energy ratings are currently being used in a number of countries to assist in the selection of windows and doors based on energy performance. Developed for simple comparison purposes, these rating numbers do not take into account window removable attachments such as insect screens that are, nevertheless, widely used. Research was carried out to assess the effect of insect screens on the heat gains and losses of windows. The work reported in this paper deals with the effect of one screen type on the performance of a base-case, double-glazed window. Using an indoor solar simulator facility, measurements of the window solar heat gain coefficient (SHGC) and U value were made for different screen attachment configurations and climatic conditions. Results with the sample window tested indicate that insect screens placed on the outdoor side can reduce its SHGC by 46% with only a 7% reduction in its U value (0.19 W/m{sup 2}{center_dot}C), and that insect screens placed on the indoor side can reduce its SHGC by 15% while reducing its U value by 14% (0.38 W/m{sup 2}{center_dot}C).

  19. Effect of the concentration of magnetic grains on the linear-optical-absorption coefficient of ferrofluid-doped lyotropic mesophases: deviation from the Beer-Lambert law.

    PubMed

    Cuppo, F L S; Gómez, S L; Figueiredo Neto, A M

    2004-04-01

    In this paper is reported a systematic experimental study of the linear-optical-absorption coefficient of ferrofluid-doped isotropic lyotropic mixtures as a function of the magnetic-grains concentration. The linear optical absorption of ferrolyomesophases increases in a nonlinear manner with the concentration of magnetic grains, deviating from the usual Beer-Lambert law. This behavior is associated to the presence of correlated micelles in the mixture which favors the formation of small-scale aggregates of magnetic grains (dimers), which have a higher absorption coefficient with respect to that of isolated grains. We propose that the indirect heating of the micelles via the ferrofluid grains (hyperthermia) could account for this nonlinear increase of the linear-optical-absorption coefficient as a function of the grains concentration.

  20. Data Qualification Report For DTN: MO0012RIB00065.002, Parameter Values For Transfer Coefficients

    SciTech Connect

    C.H. Tung

    2001-01-09

    A data-qualification evaluation was conducted on Reference Information Base (RIB) data set MOO0 12RIB00065.002, ''Parameter Values for Transfer Coefficients''. The corroborating data method was used to evaluate the data. This method was selected because it closely matches the literature-review method followed to select parameter values. Five criteria were considered when the corroborating method was used: adequacy of the corroborative literature, sufficiency of value-selection criteria, implementation of the selection criteria, documentation of the process, and whether the analysis was conducted in accordance with applicable quality assurance (QA) procedures. Three criteria were used when a literature review was not conducted: appropriate logic used to select parameters, documentation of the process, and whether the analysis was conducted in accordance with applicable QA procedures. The RIB data item, the associated Analysis and Model Report (AMR), the corroborative literature, and the results of an audit revision O/ICN 0 of the AMR were examined. All calculations and the selection process for all values were repeated and confirmed. The qualification team concluded: (1) A sufficient quantity of corroborative literature was reviewed and no additional literature was identified that should have been considered. (2) The selection criteria were sufficient and resulted in valid parameter values. (3) The process was well defined, adequately documented in the AMR, and correctly followed. (4) The analysis was developed in accordance with applicable QA procedures. No negative findings were documented that resulted in questions about the quality of the data. The qualification team therefore recommends that the qualification status of RIB data set MO0012RIB00065.002 be changed to qualified.

  1. Apparent diffusion coefficient values of normal testis and variations with age

    PubMed Central

    Tsili, Athina C; Giannakis, Dimitrios; Sylakos, Anastasios; Ntorkou, Alexandra; Astrakas, Loukas G; Sofikitis, Nikolaos; Argyropoulou, Maria I

    2014-01-01

    The usefulness of diffusion-weighted magnetic resonance imaging (DWI) in the evaluation of scrotal pathology has recently been reported. A standard reference of normal testicular apparent diffusion coefficient (ADC) values and their variations with age is necessary when interpreting normal testicular anatomy and pathology. We evaluated 147 normal testes using DWI, including 71 testes from 53 men aged 20–39 years (group 1), 67 testes from 42 men aged 40–69 years (group 2) and nine testes from six men older than 70 years (group 3). DWI was performed along the axial plane, using a single shot, multislice spin-echo planar diffusion pulse sequence and b-values of 0 and 900 s mm−2. The mean and standard deviation of the ADC values of normal testicular parenchyma were calculated for each age group separately. Analysis of variance (ANOVA) followed by post hoc analysis (Dunnett T3) was used for statistical purposes. The ADC values (× 10−3 mm2 s−1) of normal testicular tissue were different among age groups (group 1: 1.08 ± 0.13; group 2: 1.15 ± 0.15 and group 3: 1.31 ± 0.22). ANOVA revealed differences in mean ADC among age groups (F = 11.391, P < 0.001). Post hoc analysis showed differences between groups 1 and 2 (P = 0.008) and between groups 1 and 3 (P = 0.043), but not between groups 2 and 3 (P = 0.197). Our findings suggest that ADC values of normal testicular tissue increase with advancing age. PMID:24556745

  2. What is the correct value for the brain: blood partition coefficient for water

    SciTech Connect

    Herscovitch, P.; Raichle, M.E.

    1984-01-01

    A knowledge of the brain: blood partition coefficient (lambda) for water is usually required for the measurement of cerebral blood flow (CBF) with positron emission tomography (PET) and 0-15 labelled water. The correct calculation of this important parameter from the ratio of brain and blood water contents is reviewed, and the effect of physiological variations in these water contents on lambda is demonstrated. The currently accepted value for whole brain lambda is 0.95-0.96 ml/g, calculated from brain and blood water contents of 77g/100g and 80.5g/100g, respectively. However, this value for lambda is incorrect, because in the calculation the blood water content value was not adjusted for the density of blood. The correct value is 0.91 ml/g. Variations in brain or blood water content affect lambda. Over an hematocrit range of 25% to 55%, lambda varies from 0.86 to 0.93 ml/g, due to a decrease in blood water content. lambda changes with age, and varies regionally in the brain, as brain water content is inversely related to lipid and myelin content. The lambda of the human newborn brain, 1.10 ml/g, is considerably higher than in the adult. Differences in lambda between gray and white matter are well known. However, because of variations in water content, the lambda's of thalamus (0.88 ml/g) and caudate nucleus (0.96 ml/g) are less than that of cerebral cortex (0.99 ml/g), while the lambda of corpus callosum (0.89 ml/g) is greater than that of centrum semiovale (0.83 ml/g). These regional variations in lambda will assume more importance as PET resolution improves. The impact of using an incorrect lambda will depend upon the sensitivity of the particular CBF measurement technique to errors in lambda.

  3. Decoupling scattering and absorption of turbid samples using a simple empirical relation between coefficients of the Kubelka-Munk and radiative transfer theories.

    PubMed

    Gaonkar, Harshavardhan Ashok; Kumar, Dinesh; Ramasubramaniam, Rajagopal; Roy, Arindam

    2014-05-01

    Efforts are underway to better understand the absorption properties of micro- and nano-sized particles due to their potential in various photonic applications. However, most of these particles exhibit strong scattering in the spectral regions of interest in addition to absorption. Due to strong interference from scattering, the absorption of these turbid samples cannot be directly measured using conventional spectroscopy techniques. The optical properties of these particles are also different from that of the bulk due to quantum confinement and plasmon resonance effects and cannot be inferred from their bulk properties. By measuring the total transmittance and total reflectance (diffuse and collimated) of turbid samples and using an empirical relation between the coefficients of the Kubelka-Munk and radiative transfer theories, we have demonstrated a method to calculate the absorption and reduced scattering coefficients of turbid samples. This method is capable of extracting the absorption coefficient of turbid samples with an error of 2%. Using this method, we have decoupled the specific absorption and specific reduced scattering coefficients of commercially available micro-sized iron oxide particles. The current method can be used to measure the optical properties of irregularly shaped particle dispersions, which are otherwise difficult to estimate theoretically.

  4. Octanol/water partition coefficients of phthalate esters: A comparison of measured, estimated, and computed values

    SciTech Connect

    Ellington, J.; Floyd, T.

    1995-12-31

    Reliable octanol/water partition coefficients (K{sub ow}) of nine dialkyl phthalate esters are needed in an ongoing benthic organisms toxicity testing program. The equilibrium distribution of an organic chemical between water and octanol (K{sub ow}) is a physical constant that can be used to calculate both bioaccumulation factors (BAFs) and equilibrium constants for sediment-organic carbon partitioning (K{sub oc}). The log K{sub ow}s reported in the literature for a single chemical often span several orders of magnitude. For example, the reported log K{sub ow}s of bis(2-ethylehxyl) phthalate range from a low of 5.11 to a high of 9.61. The log K{sub ow}s of the dialkyl phthalate esters in this study were expected to range from < 2 (dimethyl) to > 8 (didecyl). The slow-stir method as described by de Bruijn has been shown to avoid emulsion formation and allow measure of K{sub ow}s of chemicals with log K{sub ow} > 6. In addition to measurement by the slow-stir method the K{sub ow}s were also determined by a high performance liquid chromatography (HPLC) estimation method and calculated by a computer based program that was designed to calculate physical/chemical properties (SPARC). The greatest difference between the slow-stir and SPARC K{sub ow} values was 0.19 with the other differences less than 0.1 log units. All the HPLC estimated values were at least 0.7 log units lower than the slow-stir value. For example, the log K{sub ow}s determined for dibutly phthalate by the slow-stir, SPARC, and HPLC methods were 4.50 {+-} 0.03, 4.61, and 4.00, respectively.

  5. Results of measurement of radio wave absorption in the ionosphere by the AI method

    NASA Technical Reports Server (NTRS)

    Korinevskaya, N. A.

    1972-01-01

    Median noon absorption values for each month from 1964 through 1967, the diurnal variations of absorption on the regular world days, and the seasonal variations of absorption are given. The dependence of the absorption coefficient on sunspot number is analyzed.

  6. Quantification of the dynamic changes in the absorption coefficient of liquid water at erbium:YAG and carbon dioxide laser wavelengths

    NASA Astrophysics Data System (ADS)

    Shori, Ramesh K.

    The interaction of high-intensity, short-pulsed radiation with liquid water results in dynamic changes in the optical absorption coefficient of water. These changes and their implications, as related to mid-infrared laser ablation of tissue, were not investigated until the late 1980's and early 1990's. Classical models of absorption and heating do not explain the dynamic, non-linear changes in water. The objective of the present work was to quantify the dynamic changes in the absorption coefficient of liquid water as a function of incident energy at three clinically relevant infrared wavelengths (λ = 2.94, 9.6, 10.6 μm). To investigate the changes in the absorption spectrum of water in the 3-μm band, a stable, high-energy Q- switched Er:YAG laser emitting 2.94-μm radiation in a near-perfect TEMoo spatial beam profile was developed. Key to the development of this laser was careful attention to the gain medium, optical pump system, system optics, and the thermal system. The final system design was capable of emitting 110 mJ/pulse at of 2-4 Hz with a lamp lifetime exceeding 12 million pulses The laser was used in two sets of experiments in order to quantify the above changes. First, the laser was used to measure the velocity of the shock front produced by vaporizing a gelatin-based tissue phantom. The measured shock velocity was related to the optical energy absorbed by the tissue phantom and the absorption coefficient, based on the pressure relationships derived using a 1-D piston model for an expanding plume. The shock front velocity measurements indicate that the absorption coefficient is constant for incident fluences less than 20 J/cm2, a result consistent with transmission data. For higher fluences, the data indicate a decrease in the absorption coefficient, which is again consistent with transmission data. Quantification of the absorption coefficient can, however, not be made without violating assumptions that form the basis for the 1-D piston model. Second

  7. Influence of the light propagation models on a linearized photoacoustic image reconstruction of the light absorption coefficient

    NASA Astrophysics Data System (ADS)

    Okawa, Shinpei; Hirasawa, Takeshi; Kushibiki, Toshihiro; Ishihara, Miya

    2015-03-01

    Quantification of the optical properties of the tissues and blood by noninvasive photoacoustic (PA) imaging may provide useful information for screening and early diagnosis of diseases. Linearized 2D image reconstruction algorithm based on PA wave equation and the photon diffusion equation (PDE) can reconstruct the image with computational cost smaller than a method based on 3D radiative transfer equation. However, the reconstructed image is affected by the differences between the actual and assumed light propagations. A quantitative capability of a linearized 2D image reconstruction was investigated and discussed by the numerical simulations and the phantom experiment in this study. The numerical simulations with the 3D Monte Carlo (MC) simulation and the 2D finite element calculation of the PDE were carried out. The phantom experiment was also conducted. In the phantom experiment, the PA pressures were acquired by a probe which had an optical fiber for illumination and the ring shaped P(VDF-TrFE) ultrasound transducer. The measured object was made of Intralipid and Indocyanine green. In the numerical simulations, it was shown that the linearized image reconstruction method recovered the absorption coefficients with alleviating the dependency of the PA amplitude on the depth of the photon absorber. The linearized image reconstruction method worked effectively under the light propagation calculated by 3D MC simulation, although some errors occurred. The phantom experiments validated the result of the numerical simulations.

  8. Absolute absorption coefficient of C6H2 in the mid-UV range at low temperature; implications for the interpretation of Titan atmospheric spectra.

    PubMed

    Bénilan, Y; Bruston, P; Raulin, F; Courtin, R; Guillemin, J C

    1995-01-01

    The interpretation of mid-UV albedo spectra of planetary atmospheres, especially that of Titan, is the main goal of the SIPAT (Spectroscopie uv d'Interet Prebiologique dans l'Atmosphere de Titan) research program. This laboratory experiment has been developed in order to systematically determine the absorption coefficients of molecular compounds which are potential absorbers of scattered sunlight in planetary atmospheres, with high spectral resolution, and at various temperatures below room temperature. From photochemical modelling and experimental simulations, we may expect triacetylene (C6H2) to be present in the atmosphere of Titan, even though it has not yet been detected. We present here the first determination of the absolute absorption coefficient of that compound in the 200-300 nm range and at two temperatures (296 K and 233 K). The temperature dependence of the C6H2 absorption coefficient in that wavelength range is compared to that previously observed in the case of cyanoacetylene (HC3N). We then discuss the implications of the present results for the interpretation of Titan UV spectra, where it appears that large uncertainities can be introduced either by the presence of trace impurities in laboratory samples or by the variations of absorption coefficients with temperature.

  9. Analysis of oscillatory motion of a light airplane at high values of lift coefficient

    NASA Technical Reports Server (NTRS)

    Batterson, J. G.

    1983-01-01

    A modified stepwise regression is applied to flight data from a light research air-plane operating at high angles at attack. The well-known phenomenon referred to as buckling or porpoising is analyzed and modeled using both power series and spline expansions of the aerodynamic force and moment coefficients associated with the longitudinal equations of motion.

  10. Experimental determination of the absorption cross-section and molar extinction coefficient of CdSe and CdTe nanowires.

    PubMed

    Protasenko, Vladimir; Bacinello, Daniel; Kuno, Masaru

    2006-12-21

    Absorption cross-sections and corresponding molar extinction coefficients of solution-based CdSe and CdTe nanowires (NWs) are determined. Chemically grown semiconductor NWs are made via a recently developed solution-liquid-solid (SLS) synthesis, employing low melting Au/Bi bimetallic nanoparticle "catalysts" to induce one-dimensional (1D) growth. Resulting wires are highly crystalline and have diameters between 5 and 12 nm as well as lengths exceeding 10 microm. Narrow diameters, below twice the corresponding bulk exciton Bohr radius of each material, place CdSe and CdTe NWs within their respective intermediate to weak confinement regimes. Supporting this are solution linear absorption spectra of NW ensembles showing blue shifts relative to the bulk band gap as well as structure at higher energies. In the case of CdSe, the wires exhibit band edge emission as well as strong absorption/emission polarization anisotropies at the ensemble and single-wire levels. Analogous photocurrent polarization anisotropies have been measured in recently developed CdSe NW photodetectors. To further support fundamental NW optical/electrical studies as well as to promote their use in device applications, experimental absorption cross-sections are determined using correlated transmission electron microscopy, UV/visible extinction spectroscopy, and inductively coupled plasma atomic emission spectroscopy. Measured CdSe NW cross-sections for 1 microm long wires (diameters, 6-42 nm) range from 6.93 x 10(-13) to 3.91 x 10(-11) cm2 at the band edge (692-715 nm, 1.73-1.79 eV) and between 3.38 x 10(-12) and 5.50 x 10(-11) cm2 at 488 nm (2.54 eV). Similar values are obtained for 1 microm long CdTe NWs (diameters, 7.5-11.5 nm) ranging from 4.32 x 10(-13) to 5.10 x 10(-12) cm2 at the band edge (689-752 nm, 1.65-1.80 eV) and between 1.80 x 10(-12) and 1.99 x 10(-11) cm2 at 2.54 eV. These numbers compare well with previous theoretical estimates of CdSe/CdTe NW cross-sections far to the blue of the

  11. General Boundary-Value Problems for the Heat Conduction Equation with Piecewise-Continuous Coefficients

    NASA Astrophysics Data System (ADS)

    Tatsii, R. M.; Pazen, O. Yu.

    2016-03-01

    A constructive scheme for the construction of a solution of a mixed problem for the heat conduction equation with piecewise-continuous coefficients coordinate-dependent in the final interval is suggested and validated in the present work. The boundary conditions are assumed to be most general. The scheme is based on: the reduction method, the concept of quasi-derivatives, the currently accepted theory of the systems of linear differential equations, the Fourier method, and the modified method of eigenfunctions. The method based on this scheme should be related to direct exact methods of solving mixed problems that do not employ the procedures of constructing Green's functions or integral transformations. Here the theorem of eigenfunction expansion is adapted for the case of coefficients that have discontinuity points of the 1st kind. The results obtained can be used, for example, in investigating the process of heat transfer in a multilayer slab under conditions of ideal thermal contact between the layers. A particular case of piecewise-continuous coefficients is considered. A numerical example of calculation of a temperature field in a real four-layer building slab under boundary conditions of the 3rd kind (conditions of convective heat transfer) that model the phenomenon of fire near one of the external surfaces is given.

  12. Alimentary Tract Absorption (f1 Values) for Radionuclides in Local and Regional Fallout from Nuclear Tests

    PubMed Central

    Ibrahim, Shawki; Simon, Steven L; Bouville, André; Melo, Dunstana; Beck, Harold

    2009-01-01

    This paper presents gastrointestinal absorption fractions (f1 values) for estimating internal doses from local and regional fallout radionuclides due to nuclear tests. The choice of f1 values are based on specific circumstances of weapons test conditions and a review of reported f1 values for elements in different physical and chemical states. Special attention is given to fallout from nuclear tests conducted at the Marshall Islands. We make a distinction between the f1 values for intakes of radioactive materials immediately after deposition (acute intakes) and intakes that occur in the course of months and years after deposition, following incorporation into terrestrial and aquatic foodstuffs (chronic intakes). Multiple f1 values for different circumstances where persons are exposed to radioactive fallout (e.g. local vs. regional fallout and coral vs. continental tests) are presented when supportive information is available. In some cases, our selected f1 values are similar to those adopted by the ICRP (e.g. iodine and most actinides). However, f1 values for cesium and strontium derived from urine bioassay data of the Marshallese population are notably lower than the generic f1 values recommended by ICRP, particularly for acute intakes from local fallout (0.4 and 0.05 for Cs and Sr, respectively. The f1 values presented here form the first complete set of values relevant to realistic dose assessments for exposure to local or regional radioactive fallout. PMID:20622554

  13. Alimentary tract absorption (f1 values) for radionuclides in local and regional fallout from nuclear tests.

    PubMed

    Ibrahim, Shawki A; Simon, Steven L; Bouville, André; Melo, Dunstana; Beck, Harold L

    2010-08-01

    This paper presents gastrointestinal absorption fractions (f1 values) for estimating internal doses from local and regional fallout radionuclides due to nuclear tests. The choice of f1 values are based on specific circumstances of weapons test conditions and a review of reported f1 values for elements in different physical and chemical states. Special attention is given to fallout from nuclear tests conducted at the Marshall Islands. We make a distinction between the f1 values for intakes of radioactive materials immediately after deposition (acute intakes) and intakes that occur in the course of months and years after deposition, following incorporation into terrestrial and aquatic foodstuffs (chronic intakes). Multiple f1 values for different circumstances where persons are exposed to radioactive fallout (e.g., local vs. regional fallout and coral vs. continental tests) are presented when supportive information is available. In some cases, our selected f1 values are similar to those adopted by the International Commission on Radiological Protection (ICRP) (e.g., iodine and most actinides). However, f1 values for cesium and strontium derived from urine bioassay data of the Marshallese population are notably lower than the generic f1 values recommended by ICRP, particularly for acute intakes from local fallout (0.4 and 0.05 for Cs and Sr, respectively). The f1 values presented here form the first complete set of values relevant to realistic dose assessments for exposure to local or regional radioactive fallout.

  14. Numerical solutions of boundary value problems for variable coefficient generalized KdV equations using Lie symmetries

    NASA Astrophysics Data System (ADS)

    Vaneeva, O. O.; Papanicolaou, N. C.; Christou, M. A.; Sophocleous, C.

    2014-09-01

    The exhaustive group classification of a class of variable coefficient generalized KdV equations is presented, which completes and enhances results existing in the literature. Lie symmetries are used for solving an initial and boundary value problem for certain subclasses of the above class. Namely, the found Lie symmetries are applied in order to reduce the initial and boundary value problem for the generalized KdV equations (which are PDEs) to an initial value problem for nonlinear third-order ODEs. The latter problem is solved numerically using the finite difference method. Numerical solutions are computed and the vast parameter space is studied.

  15. Quantifying entanglement of arbitrary-dimensional multipartite pure states in terms of the singular values of coefficient matrices

    NASA Astrophysics Data System (ADS)

    Li, Hui; Wang, Shuhao; Cui, Jianlian; Long, Guilu

    2013-04-01

    The entanglement quantification and classification of multipartite quantum states are two important research fields in quantum information. In this work, we study the entanglement of arbitrary-dimensional multipartite pure states by looking at the averaged partial entropies of various bipartite partitions of the system, namely, the so-called Manhattan distance (l1 norm) of averaged partial entropies (MAPE), and it is proved to be an entanglement measure for pure states. We connected the MAPE with the coefficient matrices, which are important tools in entanglement classification and reexpressed the MAPE for arbitrary-dimensional multipartite pure states by the nonzero singular values of the coefficient matrices. The entanglement properties of the n-qubit Dicke states, arbitrary-dimensional Greenberger-Horne-Zeilinger states, and D3n states are investigated in terms of the MAPE, and the relation between the rank of the coefficient matrix and the degree of entanglement is demonstrated for symmetric states by two examples.

  16. Absorption and scattering cross-section extinction values of silver nanoparticles

    NASA Astrophysics Data System (ADS)

    Hlaing, May; Gebear-Eigzabher, Bellsabel; Roa, Azael; Marcano, Aristides; Radu, Daniela; Lai, Cheng-Yu

    2016-08-01

    We determine the extinction values of silver nanoparticles as a function of their diameter for three different wavelengths (405 nm, 532 nm, and 671 nm) from the values of absorbance and their photothermal lens response. We show that for particles of small diameters (<50 nm) the extinction grows as the cube of the diameter for all three wavelengths. For larger particles the extinction determined from absorbance exhibits a sixth order dependence on the diameters for 532 nm and 671 nm. This kind of behavior is typical of scattering processes that should dominate for large particles. For 405 nm the plasmonic resonant absorption dominates over scattering making difficult the observation of the sixth order dependence even for particles larger than 50 nm. The absorption cross-section measured by the photothermal method does not show the sixth order dependence. It depends on the cube of the particle's diameter for all nanoparticles confirming the scattering free character of this absorption technique and validating the results of the absorbance experiment.

  17. Measurement of the Two-photon Absorption Coefficient of Gallium Phosphide (GaP) Using a Dispersion-minimized Sub-10 Femtosecond Z-scan Measurement System

    DTIC Science & Technology

    2012-09-01

    bandwidth of the pulse. Using the standard laboratory and analysis methods of Sheik- Bahae et al., we obtain a two-photon absorption coefficient, β, of...organic thin-film materials deposited on various substrates. 15 6. References 1. Sheik- Bahae , M.; Said, A. A.; Van Stryland, E. W. High...sensitivity, Single-beam n2 Measurements. Optics Letters 1989, 14 (17). 2. Sheik- Bahae , M.; Said, A. A.; Van Stryland, E. W.; Wei, T-H; Hagan, D. J

  18. Remote Sensing of the Absorption Coefficients and Chlorophyll a Concentration in the U.S. Southern Middle Atlantic Bight from SeaWiFS and MODIS-Aqua

    NASA Technical Reports Server (NTRS)

    Pan, Xiaoju; Mannino, Antonio; Russ, Mary E.; Hooker, Stanford B.

    2008-01-01

    At present, satellite remote sensing of coastal water quality and constituent concentration is subject to large errors as compared to the capability of satellite sensors in oceanic waters. In this study, field measurements collected on a series of cruises within U.S. southern Middle Atlantic Bight (SMAB) were applied to improve retrievals of satellite ocean color products in order to examine the factors that regulate the bio-optical properties within the continental shelf waters of the SMAB. The first objective was to develop improvements in satellite retrievals of absorption coefficients of phytoplankton (a(sub ph)), colored dissolved organic matter (CDOM) (a(sub g)), non-pigmented particles (a(sub d)), and non-pigmented particles plus CDOM (a(sub dg)), and chlorophyll a concentration ([Chl_a]). Several algorithms were compared to derive constituent absorption coefficients from remote sensing reflectance (R(sub rs)) ratios. The validation match-ups showed that the mean absolute percent differences (MAPD) were typically less than 35%, although higher errors were found for a(sub d) retrievals. Seasonal and spatial variability of satellite-derived absorption coefficients and [Chl_a] was apparent and consistent with field data. CDOM is a major contributor to the bio-optical properties of the SMAB, accounting for 35-70% of total light absorption by particles plus CDOM at 443 nm, as compared to 30-45% for phytoplankton and 0-20% for non-pigmented particles. The overestimation of [Chl_a] from the operational satellite algorithms may be attributed to the strong CDOM absorption in this region. River discharge is important in controlling the bio-optical environment, but cannot explain all of the regional and seasonal variability of biogeochemical constituents in the SMAB.

  19. Recommended Partition Coefficient (Kd) Values for Nuclide Partitioning in the Presence of Cellulose Degradation Products

    SciTech Connect

    Serkiz, S.M.

    2001-02-23

    This report documents the data analysis of the results of the described laboratory studies in order to recommend Kd values for use in Performance Assessment modeling of nuclide transport in the presence of CDP.

  20. Exponential Sum Absorption Coefficients of Phosphine from 2750 to 3550/cm for Application to Radiative Transfer Analyses on Jupiter and Saturn

    NASA Technical Reports Server (NTRS)

    Temma, T.; Baines, K. H.; Butler, R. A. H.; Brown, L. R.; Sagui, L.; Kleiner, I.

    2006-01-01

    PH3 exponential sum k coefficients were computed between 2750 and 3550/cm (2.82-3.64 (microns), in view of future application to radiative transfer analyses of Jupiter and Saturn in a phosphine absorption band near 3 microns. The temperature and pressure of this data set cover the ranges from 80 to 350 K and from 10 (exp -3)to 10(exp 1) bars, respectively. Transmission uncertainty incurred by the use of the k coefficients is smaller than a few percent as long as the radiation is confined above an altitude of a few bars in the giant planets. In spectral regions of weak absorption at high pressures close to 10 bars, contributions from far wings of strong absorption lines must be carefully taken into account. Our data set helps map the three-dimensional distribution of PH3 on the giant planets, revealing their global atmospheric dynamics extending down to the deep interior. The complete k coefficient data set of this work is available at the Web site of the NASA Planetary Data System Atmospheres Node.

  1. Control of optical bandgap energy and optical absorption coefficient by geometric parameters in sub-10 nm silicon-nanodisc array structure

    NASA Astrophysics Data System (ADS)

    Fairuz Budiman, Mohd; Hu, Weiguo; Igarashi, Makoto; Tsukamoto, Rikako; Isoda, Taiga; Itoh, Kohei M.; Yamashita, Ichiro; Murayama, Akihiro; Okada, Yoshitaka; Samukawa, Seiji

    2012-02-01

    A sub-10 nm, high-density, periodic silicon-nanodisc (Si-ND) array has been fabricated using a new top-down process, which involves a 2D array bio-template etching mask made of Listeria-Dps with a 4.5 nm diameter iron oxide core and damage-free neutral-beam etching (Si-ND diameter: 6.4 nm). An Si-ND array with an SiO2 matrix demonstrated more controllable optical bandgap energy due to the fine tunability of the Si-ND thickness and diameter. Unlike the case of shrinking Si-ND thickness, the case of shrinking Si-ND diameter simultaneously increased the optical absorption coefficient and the optical bandgap energy. The optical absorption coefficient became higher due to the decrease in the center-to-center distance of NDs to enhance wavefunction coupling. This means that our 6 nm diameter Si-ND structure can satisfy the strict requirements of optical bandgap energy control and high absorption coefficient for achieving realistic Si quantum dot solar cells.

  2. Influence of size, proportion, and absorption coefficient of spherical scatterers on the degree of light polarization and the grain size of speckle pattern.

    PubMed

    Nader, Christelle Abou; Nassif, Rana; Pellen, Fabrice; Le Jeune, Bernard; Le Brun, Guy; Abboud, Marie

    2015-12-10

    In this paper, we present the evolution of speckle pattern polarimetric parameters in response to controlled changes in scatterer sizes, proportions, and the absorption coefficient in media. The experimental study was performed on mixtures of polystyrene microspheres with dye in order to ensure biological medium-like properties. The speckle grain sizes and degrees of polarization for linear and circular light were monitored. We observed helicity flipping in the degree of circular polarization for small scatterer proportion around 25%. Furthermore, linear depolarization decreased slightly for media containing more small particles. Good agreement was shown with numerical results computed using a Monte Carlo simulation of polarized light taking into account our experimental configuration. Speckle grain size also evolves with the increase of small scatterers as well as the media absorption coefficient. Such variations of properties are encountered during fruit maturation, in tissues in precancerous stages, and any transformation that causes a modification in particle proportions and absorption coefficient in biological media. The computed parameters proved to be sensitive to these changes.

  3. Nonlinear absorption coefficient and optically detected electrophonon resonance in cylindrical GaAs/AlAs quantum wires with different confined phonon models

    NASA Astrophysics Data System (ADS)

    Khoa, Doan Quoc; Phuong, Le Thi Thu; Hoi, Bui Dinh

    2017-03-01

    A quantum kinetic equation for electrons interacting with confined phonons is used to investigate the nonlinear absorption of an intense electromagnetic wave by electrons in cylindrical GaAs/AlAs quantum wires. The analytic expression for absorption coefficient is calculated for three models of confined optical phonons: the dielectric continuum (DC), hydrodynamic continuum (HC), and Huang-Zhu (HZ) models. The absorption coefficient depends on the square of the electromagnetic wave amplitude. The electrophonon resonance and optically detected electrophonon resonance (ODEPR) are observed through the absorption spectrum. The full width at half maximum (the line-width) of the ODEPR peaks is obtained by a computational method. The line-width is found to increase with increasing temperature and decrease with increasing the quantum wire radius. In particular, numerical results show that the DC and HZ models lead to a similar behaviour of electron - confined phonon interaction whereas the HC model results in a quite different one, especially at small quantum wire radius. For large quantum wire radii, above mentioned phonon models have equivalent contributions to the ODEPR line-width.

  4. Distribution Coefficients (Kd Values) for Waste Resins Generated from the K and L Disassembly Basin Facilities

    SciTech Connect

    Kaplan, D.I.

    2002-12-02

    The objective of this study was to measure 14C, 129I, and 99Tc Kd values of spent resin generated from the K and L Disassembly Basin Facilities. The scope of the work was to conduct Kd measurements of resins combined in the ratio that they are disposed, 42:58 cation:anion. Because it was not known how these spent resins would be buried, it was necessary to measure the Kd values in such a manner as to simulate both trench and vault disposal. This was accomplished by using an acid-rain simulant (a standard U.S. Environmental Protection Agency protocol) and a cement leachate simulant .

  5. An Improvement to a Method for Measuring the Absorption Coefficient of Atmospheric Dust and other Strongly Absorbing Powders

    DTIC Science & Technology

    1975-07-01

    coefficient. Diffuse reflectance spectroscopy, and in particular the Kubelka - Munk (K-M) theory, can provide such information. A convenient method for...34Uber Den Streukoeffizienten Der Kubelka - Munk -Theorie," Z. Naturforsch, 19a, 28. 3. J. B. Gillespie, J. D. Lindberg and L. S. Laude, 1975 " Kubelka ... Munk Optical Coefficients for a Barium Sulfate White Reflectance Standard," Appl. Opt. 14, 807. 4. F. Grum and G. W. Lucky, 1968, "Optical Sphere

  6. Calibration-free absolute quantification of optical absorption coefficients using acoustic spectra in 3D photoacoustic microscopy of biological tissue.

    PubMed

    Guo, Zijian; Hu, Song; Wang, Lihong V

    2010-06-15

    Optical absorption is closely associated with many physiological important parameters, such as the concentration and oxygen saturation of hemoglobin, and it can be used to quantify the concentrations of nonfluorescent molecules. We propose a method to use acoustic spectra of photoacoustic signals to quantify the absolute optical absorption. This method is self-calibrating and thus insensitive to variations in the optical fluence. Factors such as system bandwidth and acoustic attenuation can affect the quantification but can be canceled by dividing the acoustic spectra measured at two optical wavelengths. Using optical-resolution photoacoustic microscopy, we quantified the absolute optical absorption of black ink samples with various concentrations. We also quantified both the concentration and oxygen saturation of hemoglobin in a live mouse in absolute units.

  7. Donor impurity-related optical absorption coefficients and refractive index changes in a rectangular GaAs quantum dot in the presence of electric field

    NASA Astrophysics Data System (ADS)

    Sheng, Wang; Yun, Kang; Xianli, Li

    2016-11-01

    Within the quasi-one-dimensional effective potential model and effective mass approximation, we obtain the wavefunctions and energy eigenvalues of the ground (j = 1) and first 2 excited states (j = 2 and 3) of a donor impurity in a rectangular GaAs quantum dot in the presence of electric field. The donor impurity-related linear and nonlinear optical absorption as well as refractive index changes for the transitions j = 1-2 and j = 2-3 are investigated. The results show that the impurity position, incident optical intensity and electric field play important roles in the optical absorption coefficients and refractive index changes. We find that the impurity effect induces the blueshift for j = 1-2 and redshift for j = 3-2 in the absence of the electric field, but it leads to redshift for j = 1-2 and blueshift for j = 3-2 in the existence of the field. Also, the optical coefficient for the higher energy transitions j = 2-3 is insensitive to variation of impurity positions, while that for the low energy transition j = 1-2 depends significantly on the positions of impurity. In addition, the saturation and splitting phenomenon of the optical absorption are observed as the incident optical intensity increases. Project supported by the Science and Technology Project of Education Department of Heilongjiang Province of China (No. 12541070).

  8. Absorption spectrum analysis based on singular value decomposition for photoisomerization and photodegradation in organic dyes

    NASA Astrophysics Data System (ADS)

    Kawabe, Yutaka; Yoshikawa, Toshio; Chida, Toshifumi; Tada, Kazuhiro; Kawamoto, Masuki; Fujihara, Takashi; Sassa, Takafumi; Tsutsumi, Naoto

    2015-10-01

    In order to analyze the spectra of inseparable chemical mixtures, many mathematical methods have been developed to decompose them into the components relevant to species from series of spectral data obtained under different conditions. We formulated a method based on singular value decomposition (SVD) of linear algebra, and applied it to two example systems of organic dyes, being successful in reproducing absorption spectra assignable to cis/trans azocarbazole dyes from the spectral data after photoisomerization and to monomer/dimer of cyanine dyes from those during photodegaradation process. For the example of photoisomerization, polymer films containing the azocarbazole dyes were prepared, which have showed updatable holographic stereogram for real images with high performance. We made continuous monitoring of absorption spectrum after optical excitation and found that their spectral shapes varied slightly after the excitation and during recovery process, of which fact suggested the contribution from a generated photoisomer. Application of the method was successful to identify two spectral components due to trans and cis forms of azocarbazoles. Temporal evolution of their weight factors suggested important roles of long lifetimed cis states in azocarbazole derivatives. We also applied the method to the photodegradation of cyanine dyes doped in DNA-lipid complexes which have shown efficient and durable optical amplification and/or lasing under optical pumping. The same SVD method was successful in the extraction of two spectral components presumably due to monomer and H-type dimer. During the photodegradation process, absorption magnitude gradually decreased due to decomposition of molecules and their decaying rates strongly depended on the spectral components, suggesting that the long persistency of the dyes in DNA-complex related to weak tendency of aggregate formation.

  9. The impact of absorption coefficient on polarimetric determination of Berry phase based depth resolved characterization of biomedical scattering samples: a polarized Monte Carlo investigation

    SciTech Connect

    Baba, Justin S; Koju, Vijay; John, Dwayne O

    2016-01-01

    The modulation of the state of polarization of photons due to scatter generates associated geometric phase that is being investigated as a means for decreasing the degree of uncertainty in back-projecting the paths traversed by photons detected in backscattered geometry. In our previous work, we established that polarimetrically detected Berry phase correlates with the mean photon penetration depth of the backscattered photons collected for image formation. In this work, we report on the impact of state-of-linear-polarization (SOLP) filtering on both the magnitude and population distributions of image forming detected photons as a function of the absorption coefficient of the scattering sample. The results, based on Berry phase tracking implemented Polarized Monte Carlo Code, indicate that sample absorption plays a significant role in the mean depth attained by the image forming backscattered detected photons.

  10. Pressure-broadening and narrowing coefficients and temperature dependence measurements of CO2 at 2.68 μm by laser diode absorption spectroscopy for atmospheric applications.

    PubMed

    Ghysels, M; Durry, G; Amarouche, N

    2013-04-15

    By using a tunable diode laser absorption spectrometer in conjunction with a cryogenically cooled multipath cell, we have revisited the air-induced pressure-broadening coefficients and the narrowing coefficients related to the Dicke effect, as well as the temperature dependences, for the R(18) and R(20) lines of the (10°1)I←(00°0) vibrational band at 2.68 μm of carbon dioxide. The selected transitions are used to probe in situ CO2 in the troposphere and the lower stratosphere by using balloon-borne laser sensors. The achieved measurements are thoroughly compared to existing former determinations. The impact of processing the in situ atmospheric CO2 spectra with this new set of molecular data is reported.

  11. A wave based method to predict the absorption, reflection and transmission coefficient of two-dimensional rigid frame porous structures with periodic inclusions

    SciTech Connect

    Deckers, Elke; Claeys, Claus; Atak, Onur; Groby, Jean-Philippe; Dazel, Olivier; Desmet, Wim

    2016-05-01

    This paper presents an extension to the Wave Based Method to predict the absorption, reflection and transmission coefficients of a porous material with an embedded periodic set of inclusions. The porous unit cell is described using the Multi-Level methodology and by embedding Bloch–Floquet periodicity conditions in the weighted residual scheme. The dynamic pressure field in the semi-infinite acoustic domains is approximated using a novel wave function set that fulfils the Helmholtz equation, the Bloch–Floquet periodicity conditions and the Sommerfeld radiation condition. The method is meshless and computationally efficient, which makes it well suited for optimisation studies.

  12. A wave based method to predict the absorption, reflection and transmission coefficient of two-dimensional rigid frame porous structures with periodic inclusions

    NASA Astrophysics Data System (ADS)

    Deckers, Elke; Claeys, Claus; Atak, Onur; Groby, Jean-Philippe; Dazel, Olivier; Desmet, Wim

    2016-05-01

    This paper presents an extension to the Wave Based Method to predict the absorption, reflection and transmission coefficients of a porous material with an embedded periodic set of inclusions. The porous unit cell is described using the Multi-Level methodology and by embedding Bloch-Floquet periodicity conditions in the weighted residual scheme. The dynamic pressure field in the semi-infinite acoustic domains is approximated using a novel wave function set that fulfils the Helmholtz equation, the Bloch-Floquet periodicity conditions and the Sommerfeld radiation condition. The method is meshless and computationally efficient, which makes it well suited for optimisation studies.

  13. Linear and nonlinear optical absorption coefficients and refractive index changes in GaN/Al{sub x}Ga{sub (1−x)}N double quantum wells operating at 1.55 μm

    SciTech Connect

    Dakhlaoui, Hassen

    2015-04-07

    In the present paper, the linear and nonlinear optical absorption coefficients and refractive index changes between the ground and the first excited states in double GaN/Al{sub x}Ga{sub (1−x)}N quantum wells are studied theoretically. The electronic energy levels and their corresponding wave functions are obtained by solving Schrödinger-Poisson equations self-consistently within the effective mass approximation. The obtained results show that the optical absorption coefficients and refractive index changes can be red- and blue-shifted through varying the left quantum well width and the aluminum concentration x{sub b2} of the central barrier, respectively. These structural parameters are found to present optimum values for carrying out the transition of 0.8 eV (1.55 μm). Furthermore, we show that the desired transition can also be achieved by replacing the GaN in the left quantum well with Al{sub y}Ga{sub (1−y)}N and by varying the aluminum concentration y{sub Al}. The obtained results give a new degree of freedom in optoelectronic device applications such as optical fiber telecommunications operating at (1.55 μm)

  14. Donor impurity-related linear and nonlinear intraband optical absorption coefficients in quantum ring: effects of applied electric field and hydrostatic pressure

    PubMed Central

    2012-01-01

    The linear and nonlinear intraband optical absorption coefficients in GaAs three-dimensional single quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and electric field, applied along the growth direction of the heterostructure, the energies of the ground and first excited states of a donor impurity have been found using the effective mass approximation and a variational method. The energies of these states are examined as functions of the dimensions of the structure, electric field, and hydrostatic pressure. We have also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as a function of incident photon energy for several configurations of the system. It is found that the variation of distinct sizes of the structure leads to either a redshift and/or a blueshift of the resonant peaks of the intraband optical spectrum. In addition, we have found that the application of an electric field leads to a redshift, whereas the influence of hydrostatic pressure leads to a blueshift (in the case of on-ring-center donor impurity position) of the resonant peaks of the intraband optical spectrum. PMID:23021497

  15. Influence of image charge effect on impurity-related optical absorption coefficients and refractive index changes in a spherical quantum dot

    NASA Astrophysics Data System (ADS)

    Vartanian, A. L.; Asatryan, A. L.; Vardanyan, L. A.

    2017-03-01

    We have investigated the influence of an image charge effect (ICE) on the energies of the ground and first few excited states of a hydrogen-like impurity in a spherical quantum dot (QD) in the presence of an external electric field. The oscillator strengths of transitions from the 1 s -like state to excited states of 2px and 2pz symmetries are calculated as the functions of the strengths of the confinement potential and the electric field. Also, we have studied the effect of image charges on linear and third-order nonlinear optical absorption coefficients and refractive index changes (RICs). The results show that image charges lead to the decrease of energies for all the hydrogen-like states, to the significant enhancement of the oscillator strengths of transitions between the impurity states, and to comparatively large blue shifts in linear, nonlinear, and total absorption coefficients and refractive index changes. Our results indicate that the total optical characteristics can be controlled by the strength of the confinement and the electric field.

  16. Assessment of in vitro human dermal absorption studies on pesticides to determine default values, opportunities for read-across and influence of dilution on absorption.

    PubMed

    Aggarwal, M; Battalora, M; Fisher, P; Hüser, A; Parr-Dobrzanski, R; Soufi, M; Mostert, V; Strupp, C; Whalley, P; Wiemann, C; Billington, R

    2014-04-01

    Dermal absorption is an integral part of non-dietary human safety risk assessments for agrochemicals. Typically, dermal absorption data for agrochemical active substances are generated from the undiluted formulation concentrate and its spray dilutions. European Food Safety Authority (EFSA) guidance, which combines highly conservative default values, very limited opportunities for read-across from existing data and other overly conservative conclusions, was the driver for this assessment. To investigate the reliability of the EFSA guidance, a homogeneous data-set of 190 GLP and OECD guideline compliant in vitro human skin studies, chosen to match the test method preferred by EU data requirements, was evaluated. These studies represented a wide range of active substances, formulation types, and concentrations. In alignment with EFSA guidance on human exposure assessment, a conservative estimate of absorption (95th percentile) was chosen to define defaults, which were also based on the EFSA worst-case assumption that all material in skin, excluding the first two tape strips, is absorbed. The analysis supports dermal absorption defaults of 6% for liquid concentrates, 2% for solid concentrates, and 30% for all spray dilutions, irrespective of the active substance concentration. Relatively high dermal absorption values for organic solvent-based formulations, compared to water-based or solid concentrates, support their use as worst-case surrogate data for read-across to other formulation types. The current review also shows that dermal absorption of sprays does not increase linearly with increasing dilution, and provides a novel, science-based option for extrapolation from existing data.

  17. Correlation between octanol/water and liposome/water distribution coefficients and drug absorption of a set of pharmacologically active compounds.

    PubMed

    Esteves, Freddy; Moutinho, Carla; Matos, Carla

    2013-06-01

    Absorption and consequent therapeutic action are key issues in the development of new drugs by the pharmaceutical industry. In this sense, different models can be used to simulate biological membranes to predict the absorption of a drug. This work compared the octanol/water and the liposome/water models. The parameters used to relate the two models were the distribution coefficients between liposomes and water and octanol and water and the fraction of drug orally absorbed. For this study, 66 drugs were collected from literature sources and divided into four groups according to charge and ionization degree: neutral; positively charged; negatively charged; and partially ionized/zwitterionic. The results show a satisfactory linear correlation between the octanol and liposome systems for the neutral (R²= 0.9324) and partially ionized compounds (R²= 0.9367), contrary to the positive (R²= 0.4684) and negatively charged compounds (R²= 0.1487). In the case of neutral drugs, results were similar in both models because of the high fraction orally absorbed. However, for the charged drugs (positively, negatively, and partially ionized/zwitterionic), the liposomal model has a more-appropriate correlation with absorption than the octanol model. These results show that the neutral compounds only interact with membranes through hydrophobic bonds, whereas charged drugs favor electrostatic interactions established with the liposomes. With this work, we concluded that liposomes may be a more-appropriate biomembrane model than octanol for charged compounds.

  18. Absorption and Attenuation Coefficients Using the WET Labs ac-s in the Mid-Atlantic Bight: Field Measurements and Data Analysis

    NASA Technical Reports Server (NTRS)

    Ohi, Nobuaki; Makinen, Carla P.; Mitchell, Richard; Moisan, Tiffany A.

    2008-01-01

    Ocean color algorithms are based on the parameterization of apparent optical properties as a function of inherent optical properties. WET Labs underwater absorption and attenuation meters (ac-9 and ac-s) measure both the spectral beam attenuation [c (lambda)] and absorption coefficient [a (lambda)]. The ac-s reports in a continuous range of 390-750 nm with a band pass of 4 nm, totaling approximately 83 distinct wavelengths, while the ac-9 reports at 9 wavelengths. We performed the ac-s field measurements at nine stations in the Mid-Atlantic Bight from water calibrations to data analysis. Onboard the ship, the ac-s was calibrated daily using Milli Q-water. Corrections for the in situ temperature and salinity effects on optical properties of water were applied. Corrections for incomplete recovery of the scattered light in the ac-s absorption tube were performed. The fine scale of spectral and vertical distributions of c (lambda) and a (lambda) were described from the ac-s. The significant relationships between a (674) and that of spectrophotometric analysis and chlorophyll a concentration of discrete water samples were observed.

  19. Combined value of apparent diffusion coefficient-standardized uptake value max in evaluation of post-treated locally advanced rectal cancer

    PubMed Central

    Ippolito, Davide; Fior, Davide; Trattenero, Chiara; Ponti, Elena De; Drago, Silvia; Guerra, Luca; Franzesi, Cammillo Talei; Sironi, Sandro

    2015-01-01

    AIM: To assess the clinical diagnostic value of functional imaging, combining quantitative parameters of apparent diffusion coefficient (ADC) and standardized uptake value (SUV)max, before and after chemo-radiation therapy, in prediction of tumor response of patients with rectal cancer, related to tumor regression grade at histology. METHODS: A total of 31 patients with biopsy proven diagnosis of rectal carcinoma were enrolled in our study. All patients underwent a whole body 18FDG positron emission tomography (PET)/computed tomography (CT) scan and a pelvic magnetic resonance (MR) examination including diffusion weighted (DW) imaging for staging (PET1, RM1) and after completion (6.6 wk) of neoadjuvant treatment (PET2, RM2). Subsequently all patients underwent total mesorectal excision and the histological results were compared with imaging findings. The MR scanning, performed on 1.5 T magnet (Philips, Achieva), included T2-weighted multiplanar imaging and in addition DW images with b-value of 0 and 1000 mm²/s. On PET/CT the SUVmax of the rectal lesion were calculated in PET1 and PET2. The percentage decrease of SUVmax (ΔSUV) and ADC (ΔADC) values from baseline to presurgical scan were assessed and correlated with pathologic response classified as tumor regression grade (Mandard’s criteria; TRG1 = complete regression, TRG5 = no regression). RESULTS: After completion of therapy, all the patients were submitted to surgery. According to the Mandard’s criteria, 22 tumors showed complete (TRG1) or subtotal regression (TRG2) and were classified as responders; 9 tumors were classified as non responders (TRG3, 4 and 5). Considering all patients the mean values of SUVmax in PET 1 was higher than the mean value of SUVmax in PET 2 (P < 0.001), whereas the mean ADC values was lower in RM1 than RM2 (P < 0.001), with a ΔSUV and ΔADC respectively of 60.2% and 66.8%. The best predictors for TRG response were SUV2 (threshold of 4.4) and ADC2 (1.29 × 10-3 mm2/s) with high

  20. Prognostic value of the primary lesion apparent diffusion coefficient (ADC) in nasopharyngeal carcinoma: a retrospective study of 541 cases

    PubMed Central

    Zhang, Yuan; Liu, Xu; Zhang, Yun; Li, Wen-Fei; Chen, Lei; Mao, Yan-Ping; Shen, Jing-Xian; Zhang, Fan; Peng, Hao; Liu, Qing; Sun, Ying; Ma, Jun

    2015-01-01

    The prognostic value of the primary lesion pretreatment apparent diffusion coefficient (ADC), which is obtained by diffusion-weighted magnetic resonance imaging (MR-DWI), remains unknown in nasopharyngeal carcinoma (NPC). Thus, to investigate whether the pretreatment ADC value as measured from the primary site on MR-DWI is an independent prognostic factor in NPC, we retrospectively reviewed a cohort of 541 patients with histologically-proven stage I-IVB NPC. All patients underwent MRI using a 3-Tesla system (Trio Tim; Siemens, Erlangen Germany). To calculate ADC, the primary lesion was designated on the ADC map at the level of the largest tumor diameter to cover most of the lesion, avoiding cystic or necrotic components. Median and mean (±SD) pretreatment ADC were 0.713 and 0.716 ± 0.079 × 10−3 mm2/s, respectively. Univariate and multivariate analysis confirmed high pretreatment ADC was a good prognostic factor for poor local relapse-free survival and disease-free survival. Furthermore, the area under the ROC curve for prediction of local failure significantly increased when pretreatment ADC was combined with T classification (P = 0.004). Thus, pretreatment ADC might provide useful information for predicting outcome and selecting high-risk patients appropriate for more aggressive therapy. Further studies are warranted to investigate the biological basis of this observation. PMID:26184509

  1. Determination of the quasi-TE mode (in-plane) graphene linear absorption coefficient via integration with silicon-on-insulator racetrack cavity resonators.

    PubMed

    Crowe, Iain F; Clark, Nicholas; Hussein, Siham; Towlson, Brian; Whittaker, Eric; Milosevic, Milan M; Gardes, Frederic Y; Mashanovich, Goran Z; Halsall, Matthew P; Vijayaraghaven, Aravind

    2014-07-28

    We examine the near-IR light-matter interaction for graphene integrated cavity ring resonators based on silicon-on-insulator (SOI) race-track waveguides. Fitting of the cavity resonances from quasi-TE mode transmission spectra reveal the real part of the effective refractive index for graphene, n(eff) = 2.23 ± 0.02 and linear absorption coefficient, α(gTE) = 0.11 ± 0.01dBμm(-1). The evanescent nature of the guided mode coupling to graphene at resonance depends strongly on the height of the graphene above the cavity, which places limits on the cavity length for optical sensing applications.

  2. Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells.

    PubMed

    Gao, Feifei; Wang, Yuan; Shi, Dong; Zhang, Jing; Wang, Mingkui; Jing, Xiaoyan; Humphry-Baker, Robin; Wang, Peng; Zakeeruddin, Shaik M; Grätzel, Michael

    2008-08-13

    We report two new heteroleptic polypyridyl ruthenium complexes, coded C101 and C102, with high molar extinction coefficients by extending the pi-conjugation of spectator ligands, with a motivation to enhance the optical absorptivity of mesoporous titania film and charge collection yield in a dye-sensitized solar cell. On the basis of this C101 sensitizer, several DSC benchmarks measured under the air mass 1.5 global sunlight have been reached. Along with an acetonitrile-based electrolyte, the C101 sensitizer has already achieved a strikingly high efficiency of 11.0-11.3%, even under a preliminary testing. More importantly, based on a low volatility 3-methoxypropionitrile electrolyte and a solvent-free ionic liquid electrolyte, cells have corresponding >9.0% and approximately 7.4% efficiencies retained over 95% of their initial performances after 1000 h full sunlight soaking at 60 degrees C. With the aid of electrical impedance measurements, we further disclose that, compared to the cell with an acetonitrile-based electrolyte, a dye-sensitized solar cell with an ionic liquid electrolyte shows a feature of much shorter effective electron diffusion lengths due to the lower electron diffusion coefficients and shorter electron lifetimes in the mesoporous titania film, explaining the photocurrent difference between these two type devices. This highlights the next necessary efforts to further improve the efficiency of cells with ionic liquid electrolytes, facilitating the large-scale production and application of flexible thin film mesoscopic solar cells.

  3. Estimating the absorption coefficient of the bottom layer in four-layered turbid mediums based on the time-domain depth sensitivity of near-infrared light reflectance.

    PubMed

    Sato, Chie; Shimada, Miho; Tanikawa, Yukari; Hoshi, Yoko

    2013-09-01

    Expanding our previously proposed "time segment analysis" for a two-layered turbid medium, this study attempted to selectively determine the absorption coefficient (μa) of the bottom layer in a four-layered human head model with time-domain near-infrared measurements. The difference curve in the temporal profiles of the light attenuation between an object and a reference medium, which are obtained from Monte Carlo simulations, is divided into segments along the time axis, and a slope for each segment is calculated to obtain the depth-dependent μa(μaseg). The reduced scattering coefficient (μs') of the reference is determined by curve fitting with the temporal point spread function derived from the analytical solution of the diffusion equation to the time-resolved reflectance of the object. The deviation of μaseg from the actual μa is expressed by a function of the ratio of μaseg in an earlier time segment to that in a later segment for mediums with different optical properties and thicknesses of the upper layers. Using this function, it is possible to determine the μa of the bottom layer in a four-layered epoxy resin-based phantom. These results suggest that the method reported here has potential for determining the μa of the cerebral tissue in humans.

  4. Performance of Apparent Diffusion Coefficient Values and Conventional MRI Features in Differentiating Tumefactive Demyelinating Lesions From Primary Brain Neoplasms

    PubMed Central

    Mabray, Marc C.; Cohen, Benjamin A.; Villanueva-Meyer, Javier E.; Valles, Francisco E.; Barajas, Ramon F.; Rubenstein, James L.; Cha, Soonmee

    2015-01-01

    OBJECTIVE Tumefactive demyelinating lesions (TDLs) remain one of the most common brain lesions to mimic a brain tumor, particularly primary CNS lymphoma (PCNSL) and high-grade gliomas. The purpose of our study was to evaluate the ability of apparent diffusion coefficient (ADC) values and conventional MRI features to differentiate TDLs from PCNSLs and high-grade gliomas. MATERIALS AND METHODS Seventy-five patients (24 patients with TDLs, 28 with PCNSLs, and 23 with high-grade gliomas) with 168 brain lesions (70 TDLs, 68 PCNSLs, and 30 high-grade gliomas) who underwent DWI before surgery or therapy were included in the study. Minimum ADC (ADCmin) and average ADC (ADCavg) values were calculated for each lesion. ANOVA and ROC analyses were performed. ROC analyses were also performed for the presence of incomplete rim enhancement and for the number of lesions. Multiple-variable logistic regression with ROC analysis was then performed to evaluate performance in multiple-variable models. RESULTS ADCmin was statistically significantly higher (p < 0.01) in TDLs (mean, 0.886; 95% CI, 0.802–0.931) than in PCNSLs (0.547; 95% CI, 0.496–0.598) and high-grade gliomas (0.470; 95% CI, 0.385–0.555). (All ADC values in this article are reported in units of × 10−3 mm2/s.) ADCavg was statistically significantly higher (p < 0.01) in TDLs (mean, 1.362; 95% CI, 1.268–1.456) than in PCNSLs (0.990; 95% CI, 0.919–1.061) but not in high-grade gliomas (1.216; 95% CI, 1.074–1.356). Multiple-variable models showed statistically significant individual effects and superior diagnostic performance on ROC analysis. CONCLUSION TDLs can be diagnosed on preoperative MRI with a high degree of specificity; MRI features of incomplete rim enhancement, high ADC values, and a large number of lesions individually increase the probability and diagnostic confidence that a lesion is a TDL. PMID:26496556

  5. Diffusion coefficients significant in modeling the absorption rate of carbon dioxide into aqueous blends of N-methyldiethanolamine and diethanolamine and of hydrogen sulfide into aqueous N-methyldiethanolamine

    SciTech Connect

    Adams, M.E.; Marshall, T.L.; Rowley, R.L.

    1998-07-01

    Absorption rates of gaseous CO{sub 2} into aqueous blends of N-methyldiethanolamine (MDEA) and diethanolamine (DEA) and of gaseous H{sub 2}S into aqueous MDEA were measured in a quiescent, inverted-tube diffusiometer by monitoring the rate of pressure drop. A numerical model for absorption, diffusion, and reaction of CO{sub 2} and H{sub 2}S in blends of MDEA, DEA, and water was developed. The model was used to regress diffusion coefficients of bicarbonate, carbamate, and MDEAH{sub 2}CO{sub 3} for the case of CO{sub 2} absorption and of bisulfide ion for the case of H{sub 2}S absorption from measured absorption rates. CO{sub 2} absorption rates and diffusion coefficients of bicarbonate, carbamate, and MDEAH{sub 2}CO{sub 3} were obtained at 298.2 K and 318.2 K in aqueous solutions containing 50 mass % total amine at DEA:MDEA mole ratios of 1:20, 1:4, 1L3, and 2:3. H{sub 2}S absorption rates and diffusion coefficients of bisulfide ion were obtained at 298.2 K and 318.2 K in aqueous solutions containing 20, 35, and 50 mass % MDEA.

  6. Aerosol absorption coefficient and Equivalent Black Carbon by parallel operation of AE31 and AE33 aethalometers at the Zeppelin station, Ny Ålesund, Svalbard

    NASA Astrophysics Data System (ADS)

    Eleftheriadis, Konstantinos; Kalogridis, Athina-Cerise; Vratolis, Sterios; Fiebig, Markus

    2016-04-01

    Light absorbing carbon in atmospheric aerosol plays a critical role in radiative forcing and climate change. Despite the long term measurements across the Arctic, comparing data obtained by a variety of methods across stations requires caution. A method for extracting the aerosol absorption coefficient from data obtained over the decades by filter based instrument is still under development. An IASOA Aerosol working group has been initiated to address this and other cross-site aerosol comparison opportunities. Continuous ambient measurements of EBC/light attenuation by means of a Magee Sci. AE-31 aethalometer operating at the Zeppelinfjellet station (474 m asl; 78°54'N, 11°53'E), Ny Ålesund, Svalbard, have been available since 2001 (Eleftheriadis et al, 2009), while a new aethalometer model (AE33, Drinovec et al, 2014) has been installed to operate in parallel from the same inlet since June 2015. Measurements are recorded by a Labview routine collecting all available parameters reported by the two instrument via RS232 protocol. Data are reported at 1 and 10 minute intervals as averages for EBC (μg m-3) and aerosol absorption coefficients (Mm-1) by means of routine designed to report Near Real Time NRT data at the EBAS WDCA database (ebas.nilu.no) Results for the first 6 month period are reported here in an attempt to evaluate comparative performance of the two instruments in terms of their response with respect to the variable aerosol load of light absorbing carbon during the warm and cold seasons found in the high arctic. The application of available conversion schemes for obtaining the absorption coefficient by the two instruments is found to demonstrate a marked difference in their output. During clean periods of low aerosol load (EBC < 30 ng m-3), the two instruments display a better agreement with regression slope for the 880 nm signal between the two at ~ 0.9 compared to a slope at ~ 0.6 during the period of higher absorbing carbon loads (400< EBC<30 ng m

  7. UNDERSTANDING VARIATION IN PARTITION COEFFICIENT KD, VALUES, VOLUME III: AMERICIUM, ARSENIC, CURIUM, IODINE, NEPTUNIUM, RADIUM, AND TECHNETIUM

    EPA Science Inventory

    This report describes the conceptualization, measurement, and use of the partition (or distribution) coefficient, Kd, parameter, and the geochemical aqueous solution and sorbent properties that are most important in controlling adsorption/retardation behavior of selected contamin...

  8. Atmospheric Chemistry of 1-Methoxy 2-Propyl Acetate: UV Absorption Cross Sections, Rate Coefficients, and Products of Its Reactions with OH Radicals and Cl Atoms.

    PubMed

    Zogka, Antonia G; Mellouki, Abdelwahid; Romanias, Manolis N; Bedjanian, Yuri; Idir, Mahmoud; Grosselin, Benoit; Daële, Véronique

    2016-11-17

    The rate coefficients for the reactions of OH and Cl with 1-methoxy 2-propyl acetate (MPA) in the gas phase were measured using absolute and relative methods. The kinetic study on the OH reaction was conducted in the temperature (263-373) K and pressure (1-760) Torr ranges using the pulsed laser photolysis-laser-induced fluorescence technique, a low pressure fast flow tube reactor-quadrupole mass spectrometer, and an atmospheric simulation chamber/GC-FID. The derived Arrhenius expression is kMPA+OH(T) = (2.01 ± 0.02) × 10(-12) exp[(588 ± 123/T)] cm(3) molecule(-1) s(-1). The absolute and relative rate coefficients for the reaction of Cl with MPA were measured at room temperature in the flow reactor and the atmospheric simulation chamber, which led to k(Cl+MPA) = (1.98 ± 0.31) × 10(-10) cm(3) molecule(-1) s(-1). GC-FID, GC-MS, and FT-IR techniques were used to investigate the reaction mechanism in the presence of NO. The products formed from the reaction of MPA with OH and their yields were methyl formate (80 ± 7.3%), acetic acid (50 ± 4.8%), and acetic anhydride (22 ± 2.4%), while for Cl reaction, the obtained yields were 60 ± 5.4, 41 ± 3.8, and 11 ± 1.2%, respectively, for the same products. The UV absorption cross section spectrum of MPA was determined in the wavelength range 210-370 nm. The study has shown no photolysis of MPA under atmospheric conditions. The obtained results are used to derive the atmospheric implication.

  9. Opto-acoustic measurement of the local light absorption coefficient in turbid media: 1. Monte-Carlo simulation of laser fluence distribution at the beam axis beneath the surface of a turbid medium

    SciTech Connect

    Pelivanov, Ivan M; Barskaya, M I; Podymova, N B; Khokhlova, Tanya D; Karabutov, Aleksander A

    2009-09-30

    A new method for measuring the local light absorption coefficient in turbid media, for example, biological tissues, is proposed. The method is based on the fact that the amplitude of the excited opto-acoustic (OA) signal is proportional to the absorbed laser power density (the product of the light absorption coefficient and the laser fluence) at the medium interface. In the first part of the paper, the influence of the laser beam diameter, the light absorption and reduced scattering coefficients on the maximal amplitude of the laser fluence at the laser beam axis in the near-surface layer of the turbid medium is studied by using the Monte-Carlo simulation. The conditions are predicted under which the amplitude of the OA signal detected in a transparent medium in contact with the scattering medium should remain proportional to the light absorption coefficient of the medium under study, when the scattering coefficient in it changes more than twice. The results of the numerical simulation are used for the theoretical substantiation of the OA method being proposed. (measurement of parametrs of laser radiation)

  10. EXTENSION OF THE INVERSE ADDING-DOUBLING METHOD TO THE MEASUREMENT OF WAVELENGTH-DEPENDENT ABSORPTION AND SCATTERING COEFFICIENTS OF BIOLOGICAL SAMPLES

    SciTech Connect

    Allegood, M.S.; Baba, J.S.

    2008-01-01

    Light interaction with biological tissue can be described using three parameters: the scattering and absorption coeffi cients (μs and μa), as well as the anisotropy (g) which describes the directional dependence of the scattered photons. Accurately determining these optical properties for different tissue types at specifi c wavelengths simultaneously would be benefi cial for a variety of different biomedical applications. The goal of this project was to take a user defi ned g-value and determine the remaining two parameters for a specifi ed wavelength range. A fully automated computer program and process was developed to collect data for all wavelengths in a timely and accurate manner. LabVIEW® was used to write programs to automate raw intensity data collection from a spectrometer equipped integrating sphere, conversion of the data into a format for analysis via Scott Prahl’s Inverse Adding-Doubling (IAD) C code execution, and fi nally computation of the optical properties based on the output from the IAD code. To allow data to be passed effi ciently between LabVIEW® and C code program modules, the two were combined into a single program (OPT 3.1). OPT 3.1 was tested using tissue mimicking phantoms. Determination of the absorption and scattering coeffi cients showed excellent agreement with theory for wavelengths where the user inputted single g-value was suffi ciently precise. Future improvements entail providing for multi-wavelength g-value entry to extend the accuracy of results to encompass the complete multispectral range. Ultimately, the data collection process and algorithms developed through this effort will be used to examine actual biological tissues for the purpose of building and refi ning models for light-tissue interactions.

  11. Recommended Distribution Coefficients, Kd Values, for Special Analysis Risk Calculations Related to Waste Disposal and Tank Closure on the Savannah River Site

    SciTech Connect

    Kaplan, D

    2005-08-31

    The purpose of this document is to provide a technically defensible list of distribution coefficients, or Kd values, for use in performance assessment (PA) and special analysis (SA) calculations on the SRS. Only Kd values for radionuclides that have new information related to them or that have recently been recognized as being important are discussed in this report. Some 150 Kd values are provided in this report for various waste-disposal or tank-closure environments: soil, corrosion in grout, oxidizing grout waste, gravel, clay, and reducing concrete environments. Documentation and justification for the selection of each Kd value is provided.

  12. H + O3 Fourier-transform infrared emission and laser absorption studies of OH(X2Pi) radical - An experimental dipole moment function and state-to-state Einstein A coefficients

    NASA Technical Reports Server (NTRS)

    Nelson, David D., Jr.; Schiffman, Aram; Nesbitt, David J.; Orlando, John J.; Burkholder, James B.

    1990-01-01

    FTIR emission/absorption spectroscopy is used to measure the relative intensities of 88 pairs of rovibrational transitions of OH(X2Pi) distributed over 16 vibrational bands. The experimental technique used to obtain the Einstein A ratios is discussed. The dipole moment function which follows from the intensity ratios along with Einstein A coefficients calculated from mu(r) is presented.

  13. H + O3 Fourier-transform infrared emission and laser absorption studies of OH(X2Pi) radical - An experimental dipole moment function and state-to-state Einstein A coefficients

    NASA Astrophysics Data System (ADS)

    Nelson, David D., Jr.; Schiffman, Aram; Nesbitt, David J.; Orlando, John J.; Burkholder, James B.

    1990-11-01

    FTIR emission/absorption spectroscopy is used to measure the relative intensities of 88 pairs of rovibrational transitions of OH(X2Pi) distributed over 16 vibrational bands. The experimental technique used to obtain the Einstein A ratios is discussed. The dipole moment function which follows from the intensity ratios along with Einstein A coefficients calculated from mu(r) is presented.

  14. Ultraviolet absorption cross sections of hydrogen peroxide

    NASA Technical Reports Server (NTRS)

    Lin, C. L.; Rohatgi, N. K.; Demore, W. B.

    1978-01-01

    Absorption cross-sections of hydrogen peroxide vapor and of neutral aqueous solutions of hydrogen peroxide were measured in the wavelength range from 195 to 350 nm at 296 K. The spectrophotometric procedure is described, and the reported cross-sections are compared with values obtained by other researchers. Photodissociation coefficients of atmospheric H2O2 were calculated for direct absorption of unscattered solar radiation, and the vertical distributions of these coefficients are shown for various solar zenith angles.

  15. A k-space Green's function solution for acoustic initial value problems in homogeneous media with power law absorption.

    PubMed

    Treeby, Bradley E; Cox, B T

    2011-06-01

    An efficient Green's function solution for acoustic initial value problems in homogeneous media with power law absorption is derived. The solution is based on the homogeneous wave equation for lossless media with two additional terms. These terms are dependent on the fractional Laplacian and separately account for power law absorption and dispersion. Given initial conditions for the pressure and its temporal derivative, the solution allows the pressure field for any time t>0 to be calculated in a single step using the Fourier transform and an exact k-space time propagator. For regularly spaced Cartesian grids, the former can be computed efficiently using the fast Fourier transform. Because no time stepping is required, the solution facilitates the efficient computation of the pressure field in one, two, or three dimensions without stability constraints. Several computational aspects of the solution are discussed, including the effect of using a truncated Fourier series to represent discrete initial conditions, the use of smoothing, and the properties of the encapsulated absorption and dispersion.

  16. Measurements of Sc I gf-values. [absorption spectroscopy using heat pipe oven

    NASA Technical Reports Server (NTRS)

    Parkinson, W. H.; Reeves, E. M.; Tomkins, F. S.

    1976-01-01

    Absolute gf-values were obtained for 98 transitions in neutral scandium by the hook method using an inductively coupled heat-pipe oven. Of the 98 lines, 51 are classified, 33 are unclassified lines that occur in pairs with the lower energy level identified, and 14 are unclassified but are believed to originate from one of the two lower levels of the ground state. The results are compared with semiempirical and other measurement results in the literature.

  17. On the emission coefficient of uranium plasmas.

    NASA Technical Reports Server (NTRS)

    Schneider, R. T.; Campbell, H. D.; Mack, J. M.

    1973-01-01

    The emission coefficient for uranium plasmas (temperature: 8000 K) was measured for the wavelength range from 1200 to 6000 A. The results were compared to theoretical calculations and other measurements. Reasonable agreement between theoretical predictions and our measurements was found in the region from 1200 to 2000 A. Although it was difficult to make absolute comparisons among the different reported measurements, considerable disagreement was found for the higher wavelength region. A short discussion regarding the overall comparisons is given, and final suggestions are made as to the most appropriate emission coefficient values to be used in future design calculations. The absorption coefficient for the same wavelength interval is also reported.

  18. Estimation of optimal b-value sets for obtaining apparent diffusion coefficient free from perfusion in non-small cell lung cancer.

    PubMed

    Karki, Kishor; Hugo, Geoffrey D; Ford, John C; Olsen, Kathryn M; Saraiya, Siddharth; Groves, Robert; Weiss, Elisabeth

    2015-10-21

    The purpose of this study was to determine optimal sets of b-values in diffusion-weighted MRI (DW-MRI) for obtaining monoexponential apparent diffusion coefficient (ADC) close to perfusion-insensitive intravoxel incoherent motion (IVIM) model ADC (ADCIVIM) in non-small cell lung cancer. Ten subjects had 40 DW-MRI scans before and during radiotherapy in a 1.5 T MRI scanner. Respiratory triggering was applied to the echo-planar DW-MRI with TR ≈ 4500 ms, TE  =  74 ms, eight b-values of 0-1000 μs μm(-2), pixel size  =  1.98 × 1.98 mm(2), slice thickness  =  6 mm, interslice gap  =  1.2 mm, 7 axial slices and total acquisition time ≈6 min. One or more DW-MRI scans together covered the whole tumour volume. Monoexponential model ADC values using various b-value sets were compared to reference-standard ADCIVIM values using all eight b-values. Intra-scan coefficient of variation (CV) of active tumour volumes was computed to compare the relative noise in ADC maps. ADC values for one pre-treatment DW-MRI scan of each of the 10 subjects were computed using b-value pairs from DW-MRI images synthesized for b-values of 0-2000 μs μm(-2) from the estimated IVIM parametric maps and corrupted by various Rician noise levels. The square root of mean of squared error percentage (RMSE) of the ADC value relative to the corresponding ADCIVIM for the tumour volume of the scan was computed. Monoexponential ADC values for the b-value sets of 250 and 1000; 250, 500 and 1000; 250, 650 and 1000; 250, 800 and 1000; and 250-1000 μs μm(-2) were not significantly different from ADCIVIM values (p > 0.05, paired t-test). Mean error in ADC values for these sets relative to ADCIVIM were within 3.5%. Intra-scan CVs for these sets were comparable to that for ADCIVIM. The monoexponential ADC values for other sets-0-1000; 50-1000; 100-1000; 500-1000; and 250 and 800 μs μm(-2) were significantly different from the ADCIVIM values. From Rician noise

  19. Estimation of optimal b-value sets for obtaining apparent diffusion coefficient free from perfusion in non-small cell lung cancer

    NASA Astrophysics Data System (ADS)

    Karki, Kishor; Hugo, Geoffrey D.; Ford, John C.; Olsen, Kathryn M.; Saraiya, Siddharth; Groves, Robert; Weiss, Elisabeth

    2015-10-01

    The purpose of this study was to determine optimal sets of b-values in diffusion-weighted MRI (DW-MRI) for obtaining monoexponential apparent diffusion coefficient (ADC) close to perfusion-insensitive intravoxel incoherent motion (IVIM) model ADC (ADCIVIM) in non-small cell lung cancer. Ten subjects had 40 DW-MRI scans before and during radiotherapy in a 1.5 T MRI scanner. Respiratory triggering was applied to the echo-planar DW-MRI with \\text{TR}≈ 4500 ms, TE  =  74 ms, eight b-values of 0-1000 μs μm-2, pixel size  =  1.98× 1.98 mm2, slice thickness  =  6 mm, interslice gap  =  1.2 mm, 7 axial slices and total acquisition time ≈6 min. One or more DW-MRI scans together covered the whole tumour volume. Monoexponential model ADC values using various b-value sets were compared to reference-standard ADCIVIM values using all eight b-values. Intra-scan coefficient of variation (CV) of active tumour volumes was computed to compare the relative noise in ADC maps. ADC values for one pre-treatment DW-MRI scan of each of the 10 subjects were computed using b-value pairs from DW-MRI images synthesized for b-values of 0-2000 μs μm-2 from the estimated IVIM parametric maps and corrupted by various Rician noise levels. The square root of mean of squared error percentage (RMSE) of the ADC value relative to the corresponding ADCIVIM for the tumour volume of the scan was computed. Monoexponential ADC values for the b-value sets of 250 and 1000; 250, 500 and 1000; 250, 650 and 1000; 250, 800 and 1000; and 250-1000 μs μm-2 were not significantly different from ADCIVIM values (p>0.05 , paired t-test). Mean error in ADC values for these sets relative to ADCIVIM were within 3.5%. Intra-scan CVs for these sets were comparable to that for ADCIVIM. The monoexponential ADC values for other sets—0-1000 50-1000 100-1000 500-1000 and 250 and 800 μs μm-2 were significantly different from the ADCIVIM values. From Rician noise simulation

  20. Energy spectrum based calculation of the half and the tenth value layers for brachytherapy sources using a semiempirical parametrized mass attenuation coefficient formulism

    SciTech Connect

    Yue, Ning J.

    2008-06-15

    As different types of radionuclides (e.g., {sup 131}Cs source) are introduced for clinical use in brachytherapy, the question is raised regarding whether a relatively simple method exists for the derivation of values of the half value layer (HVL) or the tenth value layer (TVL). For the radionuclide that has been clinically used for years, such as {sup 125}I and {sup 103}Pd, the sources have been manufactured and marketed by several vendors with different designs and structures. Because of the nature of emission of low energy photons for these radionuclides, energy spectra of the sources are very dependent on their individual designs. Though values of the HVL or the TVL in certain commonly used shielding materials are relatively small for these low energy photon emitting sources, the question remains how the variations in energy spectra affect the HVL (or TVL) values and whether these values can be calculated with a relatively simple method. A more fundamental question is whether a method can be established to derive the HVL (TVL) values for any brachytherapy sources and for different materials in a relatively straightforward fashion. This study was undertaken to answer these questions. Based on energy spectra, a well established semiempirical mass attenuation coefficient computing scheme was utilized to derive the HVL (TVL) values of different materials for different types of brachytherapy sources. The method presented in this study may be useful to estimate HVL (TVL) values of different materials for brachytherapy sources of different designs and containing different radionuclides.

  1. Energy spectrum based calculation of the half and the tenth value layers for brachytherapy sources using a semiempirical parametrized mass attenuation coefficient formulism.

    PubMed

    Yue, Ning J

    2008-06-01

    As different types of radionuclides (e.g., 131Cs source) are introduced for clinical use in brachytherapy, the question is raised regarding whether a relatively simple method exists for the derivation of values of the half value layer (HVL) or the tenth value layer (TVL). For the radionuclide that has been clinically used for years, such as 125I and 103Pd, the sources have been manufactured and marketed by several vendors with different designs and structures. Because of the nature of emission of low energy photons for these radionuclides, energy spectra of the sources are very dependent on their individual designs. Though values of the HVL or the TVL in certain commonly used shielding materials are relatively small for these low energy photon emitting sources, the question remains how the variations in energy spectra affect the HVL (or TVL) values and whether these values can be calculated with a relatively simple method. A more fundamental question is whether a method can be established to derive the HVL (TVL) values for any brachytherapy sources and for different materials in a relatively straightforward fashion. This study was undertaken to answer these questions. Based on energy spectra, a well established semiempirical mass attenuation coefficient computing scheme was utilized to derive the HVL (TVL) values of different materials for different types of brachytherapy sources. The method presented in this study may be useful to estimate HVL (TVL) values of different materials for brachytherapy sources of different designs and containing different radionuclides.

  2. Cooperative luminescence and absorption in Ytterbium-doped silica fiber and the fiber nonlinear transmission coefficient at λ = 980 nm with a regard to the Ytterbium ion-pairs' effect: Reply

    NASA Astrophysics Data System (ADS)

    Kir'yanov, Alexander V.; Barmenkov, Yuri O.

    2006-07-01

    We reply to the comment [R. Paschotta and A.C. Tropper, Opt. Express, to be published (2006)] on our recent work reporting a study of the cooperative absorption and emission in heavily-doped Ytterbium silica fibers and mechanisms of the fiber nonlinear transmission coefficient reduction due to the Ytterbium ion-pairs’ effect [A.V. Kir’yanov et al., Opt. Express, 14 (9), 3981 (2006)]. We provide some additional evidences for that our work hypotheses and conclusions.

  3. Reflective-tube absorption meter

    NASA Astrophysics Data System (ADS)

    Zaneveld, J. Ronald V.; Bartz, Robert; Kitchen, James C.

    1990-09-01

    The design and calibration of a proposed in situ spectral absorption meter is evaluated using a laboratory prototype. The design includes a silver coated (second-surface) glass tube, a tungsten light source (stabilized by means of optical feedback), a monochromator, and a solid state detector. The device measures the absorption coefficient plus a portion of the volume scattering function. Theoretical analyses and laboratory experiments which explore the magnitude and variation of the errors due to scattering and internal reflections are described. Similar analyses are performed on the Cary 1 18 Spectrophotometer to allow cross calibration. Algorithms to yield the abscrption coefficient and the zenith-sun diffuse attenuation coefficient are presented and evaluated. Simultaneous measurement of the beam attenuation or backscattering coefficient allows use of algoriThms with much narrower error bands. The various methods of obtaining absorption and diffuse attenuation values are compared. Procedures for using reverse osmosis filtration to produce a clean water calibration standard are described. An absorption spectrum for pure water is obtained. Development of the absorption meter is proceeding along two lines: 1) a two-wavelength side-by-side LED is being fabricated to allow an in situ chlorophyll a absorption meter to be constructed, and 2) scientific projects using a shipboard or laboratory flow.-through pumping system are being planned.

  4. Water-solvent partition coefficients and Delta Log P values as predictors for blood-brain distribution; application of the Akaike information criterion.

    PubMed

    Abraham, Michael H; Acree, William E; Leo, Albert J; Hoekman, David; Cavanaugh, Joseph E

    2010-05-01

    It is shown that log P values for water-alkane or water-cyclohexane partitions, and the corresponding Delta log P values when used as descriptors for blood-brain distribution, as log BB, yield equations with very poor correlation coefficients but very good standard deviations, S from 0.25 to 0.33 log units. Using quite large data sets, we have verified that similar S-values apply to predictions of log BB. A suggested model, based on log P for water-dodecane and water-hexadecane partition coefficients, has 109 data points and a fitted S = 0.254 log units. It is essential to include in the model an indicator variable for volatile compounds, and an indicator variable for drugs that contain the carboxylic group. A similar equation based on water-chloroform partition coefficients has 83 data points and a fitted S = 0.287 log units. We can find no causal connection between these log P values and log BB in terms of correlation or in terms of chemical similarity, but conclude that the log P descriptor will yield excellent predictions of log BB provided that predictions are within the chemical space of the compounds used to set up the model. We also show that model based on log P(octanol) and an Abraham descriptor provides a simple and easy method of predicting log BB with an error of no more than 0.31 log units. We have used the Akaike information criterion to investigate the most economic models for log BB.

  5. On the errors in measuring the particle density by the light absorption method

    SciTech Connect

    Ochkin, V. N.

    2015-04-15

    The accuracy of absorption measurements of the density of particles in a given quantum state as a function of the light absorption coefficient is analyzed. Errors caused by the finite accuracy in measuring the intensity of the light passing through a medium in the presence of different types of noise in the recorded signal are considered. Optimal values of the absorption coefficient and the factors capable of multiplying errors when deviating from these values are determined.

  6. Nutritional value of protein hydrolysis products (oligopeptides and free amino acids) as a consequence of absorption and metabolism kinetics

    NASA Technical Reports Server (NTRS)

    Rerat, A.

    1995-01-01

    When pigs were submitted to duodenal infusion of solutions containing a large percentage of small peptides (PEP) or free amino acids with the same pattern (AAL) amino acids appear in the portal blood more rapidly and more uniformly after infusion of PEP then after infusion of AAL, with the notable exception of methionine for which the opposite was true. These differences were lowered when a carbohydrate (maltose dextrin) was present in the solution, but nevertheless remained significant for the first hour after the infusion. The long-term (8-hour) uptake of free amino acids into the liver and the peripheral tissues differed in profile according to the nature of the duodenal infusion. Peripheral uptake was appreciably less well balanced after infusion of free amino acids (deficiency of threonine and phenylalanine) than after infusion of small peptides (deficiency of methionine). Accordingly, in the rat, under conditions of discontinuous enteral nutrition the mixture of small peptides was of greater nutritive value than the mixture of free amino acids. It thus appears that the absorption kinetics which results in important variations in the temporal distribution of free amino acids in the tissues may be at the origin of transitory imbalances in tissue amino acid uptake, and as a result of a lower nutritive value.

  7. Assessment of an extended dataset of in vitro human dermal absorption studies on pesticides to determine default values, opportunities for read-across and influence of dilution on absorption.

    PubMed

    Aggarwal, M; Fisher, P; Hüser, A; Kluxen, F M; Parr-Dobrzanski, R; Soufi, M; Strupp, C; Wiemann, C; Billington, R

    2015-06-01

    Dermal absorption is a key parameter in non-dietary human safety assessments for agrochemicals. Conservative default values and other criteria in the EFSA guidance have substantially increased generation of product-specific in vitro data and in some cases, in vivo data. Therefore, data from 190 GLP- and OECD guideline-compliant human in vitro dermal absorption studies were published, suggesting EFSA defaults and criteria should be revised (Aggarwal et al., 2014). This follow-up article presents data from an additional 171 studies and also the combined dataset. Collectively, the data provide consistent and compelling evidence for revision of EFSA's guidance. This assessment covers 152 agrochemicals, 19 formulation types and representative ranges of spray concentrations. The analysis used EFSA's worst-case dermal absorption definition (i.e., an entire skin residue, except for surface layers of stratum corneum, is absorbed). It confirmed previously proposed default values of 6% for liquid and 2% for solid concentrates, irrespective of active substance loading, and 30% for all spray dilutions, irrespective of formulation type. For concentrates, absorption from solvent-based formulations provided reliable read-across for other formulation types, as did water-based products for solid concentrates. The combined dataset confirmed that absorption does not increase linearly beyond a 5-fold increase in dilution. Finally, despite using EFSA's worst-case definition for absorption, a rationale for routinely excluding the entire stratum corneum residue, and ideally the entire epidermal residue in in vitro studies, is presented.

  8. WE-G-18C-02: Estimation of Optimal B-Value Set for Obtaining Apparent Diffusion Coefficient Free From Perfusion in Non-Small Cell Lung Cancer

    SciTech Connect

    Karki, K; Hugo, G; Ford, J; Saraiya, S; Weiss, E; Olsen, K; Groves, R

    2014-06-15

    Purpose: Diffusion-weighted MRI (DW-MRI) is increasingly being investigated for radiotherapy planning and response assessment. Selection of a limited number of b-values in DW-MRI is important to keep geometrical variations low and imaging time short. We investigated various b-value sets to determine an optimal set for obtaining monoexponential apparent diffusion coefficient (ADC) close to perfusion-insensitive intravoxel incoherent motion (IVIM) model ADC (ADCIVIM) in nonsmall cell lung cancer. Methods: Seven patients had 27 DW-MRI scans before and during radiotherapy in a 1.5T scanner. Respiratory triggering was applied to the echo-planar DW-MRI with TR=4500ms approximately, TE=74ms, pixel size=1.98X1.98mm{sub 2}, slice thickness=4–6mm and 7 axial slices. Diffusion gradients were applied to all three axes producing traceweighted images with eight b-values of 0–1000μs/μm{sup 2}. Monoexponential model ADC values using various b-value sets were compared to ADCIVIM using all b-values. To compare the relative noise in ADC maps, intra-scan coefficient of variation (CV) of active tumor volumes was computed. Results: ADCIVIM, perfusion coefficient and perfusion fraction for tumor volumes were in the range of 880-1622 μm{sup 2}/s, 8119-33834 μm{sup 2}/s and 0.104–0.349, respectively. ADC values using sets of 250, 800 and 1000; 250, 650 and 1000; and 250–1000μs/μm{sup 2} only were not significantly different from ADCIVIM(p>0.05, paired t-test). Error in ADC values for 0–1000, 50–1000, 100–1000, 250–1000, 500–1000, and three b-value sets- 250, 500 and 1000; 250, 650 and 1000; and 250, 800 and 1000μs/μm{sup 2} were 15.0, 9.4, 5.6, 1.4, 11.7, 3.7, 2.0 and 0.2% relative to the reference-standard ADCIVIM, respectively. Mean intrascan CV was 20.2, 20.9, 21.9, 24.9, 32.6, 25.8, 25.4 and 24.8%, respectively, whereas that for ADCIVIM was 23.3%. Conclusion: ADC values of two 3 b-value sets

  9. Infrared absorption by pure CO2 near 3340 cm-1: Measurements and analysis of collisional coefficients and line-mixing effects at subatmospheric pressures

    NASA Astrophysics Data System (ADS)

    Daneshvar, L.; Földes, T.; Buldyreva, J.; Vander Auwera, J.

    2014-12-01

    High resolution Fourier transform spectra of the 21102-00001 band of 12C16O2 near 3340 cm-1 have been recorded and analyzed to extract isolated-line intensities and collisional parameters, and first-order line-mixing coefficients. Voigt, hard-collision Rautian and Sobel'man, and quadratic-speed-dependent Voigt profiles have been used. The line-mixing coefficients measured for the three branches have also been evaluated using an Energy-Corrected Sudden approach employing a symmetric metric in the Liouville space. These coefficients compare very favorably with the experimental results and estimations with an algorithm available in the literature. Results of straightforward ECS-modeling of complete band shapes have been compared to the recorded spectra and future improvements of this model required at subatmospheric pressures have been outlined.

  10. Gliding flight: drag and torque of a hawk and a falcon with straight and turned heads, and a lower value for the parasite drag coefficient.

    PubMed

    Tucker, V A

    2000-12-01

    Raptors - falcons, hawks and eagles in this study - such as peregrine falcons (Falco peregrinus) that attack distant prey from high-speed dives face a paradox. Anatomical and behavioral measurements show that raptors of many species must turn their heads approximately 40 degrees to one side to see the prey straight ahead with maximum visual acuity, yet turning the head would presumably slow their diving speed by increasing aerodynamic drag. This paper investigates the aerodynamic drag part of this paradox by measuring the drag and torque on wingless model bodies of a peregrine falcon and a red-tailed hawk (Buteo jamaicensis) with straight and turned heads in a wind tunnel at a speed of 11.7 m s(-)(1). With a turned head, drag increased more than 50 %, and torque developed that tended to yaw the model towards the direction in which the head pointed. Mathematical models for the drag required to prevent yawing showed that the total drag could plausibly more than double with head-turning. Thus, the presumption about increased drag in the paradox is correct. The relationships between drag, head angle and torque developed here are prerequisites to the explanation of how a raptor could avoid the paradox by holding its head straight and flying along a spiral path that keeps its line of sight for maximum acuity pointed sideways at the prey. Although the spiral path to the prey is longer than the straight path, the raptor's higher speed can theoretically compensate for the difference in distances; and wild peregrines do indeed approach prey by flying along curved paths that resemble spirals. In addition to providing data that explain the paradox, this paper reports the lowest drag coefficients yet measured for raptor bodies (0.11 for the peregrine and 0.12 for the red-tailed hawk) when the body models with straight heads were set to pitch and yaw angles for minimum drag. These values are markedly lower than value of the parasite drag coefficient (C(D,par)) of 0.18 previously

  11. Ultraviolet (250-550  nm) absorption spectrum of pure water.

    PubMed

    Mason, John D; Cone, Michael T; Fry, Edward S

    2016-09-01

    Data for the spectral light absorption of pure water from 250 to 550 nm have been obtained using an integrating cavity made from a newly developed diffuse reflector with a very high UV reflectivity. The data provide the first scattering-independent measurements of absorption coefficients in the spectral gap between well-established literature values for the absorption coefficients in the visible (>400  nm) and UV (<200  nm). A minimum in the absorption coefficient has been observed in the UV at 344 nm; the value is 0.000811±0.000227  m-1.

  12. Tubo-Ovarian Abscess (with/without Pseudotumor Area) Mimicking Ovarian Malignancy: Role of Diffusion-Weighted MR Imaging with Apparent Diffusion Coefficient Values

    PubMed Central

    Wang, Tingting; Li, Wenhua; Wu, Xiangru; Yin, Bing; Chu, Caiting; Ding, Ming; Cui, Yanfen

    2016-01-01

    Objective To assess the added value of diffusion-weighted magnetic resonance imaging (DWI) with apparent diffusion coefficient (ADC) values compared to MRI, for characterizing the tubo-ovarian abscesses (TOA) mimicking ovarian malignancy. Materials and Methods Patients with TOA (or ovarian abscess alone; n = 34) or ovarian malignancy (n = 35) who underwent DWI and MRI were retrospectively reviewed. The signal intensity of cystic and solid component of TOAs and ovarian malignant tumors on DWI and the corresponding ADC values were evaluated, as well as clinical characteristics, morphological features, MRI findings were comparatively analyzed. Receiver operating characteristic (ROC) curve analysis based on logistic regression was applied to identify different imaging characteristics between the two patient groups and assess the predictive value of combination diagnosis with area under the curve (AUC) analysis. Results The mean ADC value of the cystic component in TOA was significantly lower than in malignant tumors (1.04 ± 0 .41 × 10−3 mm2/s vs. 2.42 ± 0.38 × 10−3 mm2/s; p < 0.001). The mean ADC value of the enhanced solid component in 26 TOAs was 1.43 ± 0.16×10−3mm2/s, and 46.2% (12 TOAs; pseudotumor areas) showed significantly higher signal intensity on DW-MRI than in ovarian malignancy (mean ADC value 1.44 ± 0.20×10−3 mm2/s vs.1.18 ± 0.36 × 10−3 mm2/s; p = 0.043). The combination diagnosis of ADC value and dilated tubal structure achieved the best AUC of 0.996. Sensitivity, specificity, positive predictive value (PPV), negative predictive value (NPV), and accuracy of MRI vs. DWI with ADC values for predicting TOA were 47.1%, 91.4%, 84.2%, 64%, and 69.6% vs. 100%, 97.1%, 97.1%, 100%, and 98.6%, respectively. Conclusions DW-MRI is superior to MRI in the assessment of TOA mimicking ovarian malignancy, and the ADC values aid in discriminating the pseudotumor area of TOA from the solid portion of ovarian malignancy. PMID:26894926

  13. Prognostic Value of Diffusion-Weighted Imaging (DWI) Apparent Diffusion Coefficient (ADC) in Patients with Hyperacute Cerebral Infarction Receiving rt-PA Intravenous Thrombolytic Therapy

    PubMed Central

    Sui, Hai-Jing; Yan, Cheng-Gong; Zhao, Zhen-Guo; Bai, Qing-Ke

    2016-01-01

    Background The aim of this study was to investigate the potential value of apparent diffusion coefficient (ADC) of diffusion-weighted imaging (DWI) in the prognosis of patients with hyperacute cerebral infarction (HCI) receiving intravenous thrombolytic therapy with recombinant tissue plasminogen activator (rt-PA). Material/Methods From June 2012 to June 2015, 58 cases of HCI (<6 h) undergoing rt-PA intravenous thrombolytic therapy (thrombolysis group) and 70 cases of HCI (<6 h) undergoing conventional antiplatelet and anticoagulant therapy (control group) in the same period were collected. DWI was conducted on all the subjects, and ADC maps were generated with Functool software to quantify ADC value. The clinical outcomes of HCI patients were observed for 3 months, and prognostic factors were analyzed. Results Before thrombolysis treatment, the lesion area presented high signal intensity on DWI map and low signal intensity on ADC map, and gradually weakened signal intensity on DWI map and gradually enhanced signal intensity on ADC map were observed after thrombolysis. The ADC values of the thrombolysis group were significantly higher than those of the control group after treatment (24 h, 7 d, 30 d, and 90 d) (all P<0.05), and the ADC and rADC values in the thrombolysis group gradually increased over time (all P<0.05). Multiple logistic regression analysis showed that baseline National Institutes of Health Stroke Scale (NIHSS) score, baseline rADC value, and stroke history were the independent factors for the prognosis of HIC patients with thrombolysis (all P<0.05). Conclusions The values of ADC and rADC may provide guidance in the prognosis of HCI patients receiving rt-PA, and the baseline rADC value is the protective factor for the prognosis of HCI patients receiving rt-PA. PMID:27864581

  14. Evaluation of Free Breathing Versus Breath Hold Diffusion Weighted Imaging in Terms Apparent Diffusion Coefficient (ADC) and Signal-to-Noise Ratio (SNR) Values for Solid Abdominal Organs

    PubMed Central

    Herek, Duygu; Karabulut, Nevzat; Kocyıgıt, Ali; Yagcı, Ahmet Baki

    2016-01-01

    Summary Background Our aim was to compare the apparent diffusion coefficient (ADC) values of normal abdominal parenchymal organs and signal-to-noise ratio (SNR) measurements in the same patients with breath hold (BH) and free breathing (FB) diffusion weighted imaging (DWI). Material/Methods Forty-eight patients underwent both BH and FB DWI. Spherical region of interest (ROI) was placed on the right hepatic lobe, spleen, pancreas, and renal cortices. ADC values were calculated for each organ on each sequence using an automated software. Image noise, defined as the standard deviation (SD) of the signal intensities in the most artifact-free area of the image background was measured by placing the largest possible ROI on either the left or the right side of the body outside the object in the recorded field of view. SNR was calculated using the formula: SNR=signal intensity (SI)(organ)/standard deviation (SD)(noise). Results There were no statistically significant differences in ADC values of the abdominal organs between BH and FB DWI sequences (p>0.05). There were statistically significant differences between SNR values of organs on BH and FB DWIs. SNRs were found to be better on FB DWI than BH DWI (p<0.001). Conclusions Free breathing DWI technique reduces image noise and increases SNR for abdominal examinations. Free breathing technique is therefore preferable to BH DWI in the evaluation of abdominal organs by DWI. PMID:27822326

  15. Influence of the nature of the absorption band on the potential performance of high molar extinction coefficient ruthenium(II) polypyridinic complexes as dyes for sensitized solar cells.

    PubMed

    Gajardo, Francisco; Barrera, Mauricio; Vargas, Ricardo; Crivelli, Irma; Loeb, Barbara

    2011-07-04

    When tested in solar cells, ruthenium polypyridinic dyes with extended π systems show an enhanced light-harvesting capacity that is not necessarily reflected by a high (collected electrons)/(absorbed photons) ratio. Provided that metal-to-ligand charge transfer bands, MLCT, are more effective, due to their directionality, than intraligand (IL) π-π* bands for the electron injection process in the solar cell, it seems important to explore and clarify the nature of the absorption bands present in these types of dyes. This article aims to elucidate if all the absorbed photons of these dyes are potentially useful in the generation of electric current. In other words, their potentiality as dyes must also be analyzed from the point of view of their contribution to the generation of excited states potentially useful for direct injection. Focusing on the assignment of the absorption bands and the nature of the emitting state, a systematic study for a series of ruthenium complexes with 4,4'-distyryl-2,2'-dipyridine (LH) and 4,4'-bis[p-(dimethylamino)-α-styryl]-2,2'-bipyridine (LNMe(2)) "chromophoric" ligands was undertaken. The observed experimental results were complemented with TDDFT calculations to elucidate the nature of the absorption bands, and a theoretical model was proposed to predict the available energy that could be injected from a singlet or a triplet excited state. For the series studied, the results indicate that the percentage of MLCT character to the anchored ligand for the lower energy absorption band follows the order [Ru(deebpy)(2)(LNMe(2))](PF(6))(2) > [Ru(deebpy)(2)(LH)](PF(6))(2) > [Ru(deebpy)(LH)(2)](PF(6))(2), where deebpy is 4,4'-bis(ethoxycarbonyl)-2,2'-bipyridine, predicting that, at least from this point of view, their efficiency as dyes should follow the same trend.

  16. Gasoline-Water Distribution Coefficients of Xylidines

    DTIC Science & Technology

    1943-06-01

    sample calculated. The extinction (absorption) of light is related to the concentration of the absorbing group by the Beer - Lambert law. It was neceaaar...the use of a Beckman quartz spectrophotometer . Data obtained 1dth the spectzrograph were checzed with the spectrophotom- eter and were reproducible to...within 5 percent of the value of the distribution coefficient given, The use of the spectrophotometer greatly enhanced the speed with which the

  17. The additional utility of apparent diffusion coefficient values of clear-cell renal cell carcinoma for predicting metastasis during clinical staging

    PubMed Central

    Yoshizako, Takeshi; Hisatoshi, Araki; Mori, Hiroshi; Tamaki, Yukihisa; Ishikawa, Noriyoshi; Kitagaki, Hajime

    2017-01-01

    Background The apparent diffusion coefficient (ADC) value is known to be an indicator of tumor activity. The ADC value of high-grade clear-cell renal cell carcinoma (RCC) is significantly lower than that of low-grade clear-cell RCC. Purpose To investigate the utility of ADC values of clear-cell RCC by comparing ADC values between groups with T1a RCC (tumor size ≤ 4 cm) without metastasis and the group with metastasis. Material and Methods A retrospective review was performed on 51 patients with 51 RCCs who underwent 1.5 T magnetic resonance imaging (MRI) for evaluating a renal mass confirmed pathologically to be clear-cell RCC between January 2010 and August 2014. We compared ADC values between group A (T1a RCC without metastasis, T1aN0M0) and group B (RCC with metastasis) using the Mann–Whitney U test. Results The patients were divided into group A (n = 30; tumor size: median, 24.5 mm; range, 8–40 mm; ADC value [×10−3 mm2/s]: median, 1.71; range, 1.23–2.24) and group B (n = 21; tumor size: median, 87.5 mm; range, 18–150 mm; ADC value [×10−3 mm2/s]: median, 1.35; range, 0.91–1.94). The ADC value differed significantly between the two groups. The area under the receiver operating characteristic curve was 0.869. Using the optimum cutoff value (1.552 × 10−3 mm2/s), ADC had a sensitivity of 80.0% and specificity of 81.0%. Conclusion There was a statistically significant difference in the ADC between group A (T1a clear-cell RCC without distant metastasis) and group B (advanced clear-cell RCC with lymph node metastasis or distant metastasis). PMID:28210496

  18. Correlation of Minimum Apparent Diffusion Coefficient and Maximum Standardized Uptake Value of the Primary Tumor with Clinicopathologic Characteristics in Endometrial Cancer

    PubMed Central

    Sürer Budak, Evrim; Toptaş, Tayfun; Aydın, Funda; Öner, Ali Ozan; Çevikol, Can; Şimşek, Tayup

    2017-01-01

    Objective: To explore the correlation of the primary tumor’s maximum standardized uptake value (SUVmax) and minimum apparent diffusion coefficient (ADCmin) with clinicopathologic features, and to determine their predictive power in endometrial cancer (EC). Methods: A total of 45 patients who had undergone staging surgery after a preoperative evaluation with 18F-fluorodeoxyglucose (FDG) positron emission tomography/computerized tomography (PET/CT) and diffusion-weighted magnetic resonance imaging (DW-MRI) were included in a prospective case-series study with planned data collection. Multiple linear regression analysis was used to determine the correlations between the study variables. Results: The mean ADCmin and SUVmax values were determined as 0.72±0.22 and 16.54±8.73, respectively. A univariate analysis identified age, myometrial invasion (MI) and lymphovascular space involvement (LVSI) as the potential factors associated with ADCmin while it identified age, stage, tumor size, MI, LVSI and number of metastatic lymph nodes as the potential variables correlated to SUVmax. In multivariate analysis, on the other hand, MI was the only significant variable that correlated with ADCmin (p=0.007) and SUVmax (p=0.024). Deep MI was best predicted by an ADCmin cutoff value of ≤0.77 [93.7% sensitivity, 48.2% specificity, and 93.0% negative predictive value (NPV)] and SUVmax cutoff value of >20.5 (62.5% sensitivity, 86.2% specificity, and 81.0% NPV); however, the two diagnostic tests were not significantly different (p=0.266). Conclusion: Among clinicopathologic features, only MI was independently correlated with SUVmax and ADCmin. However, the routine use of 18F-FDG PET/CT or DW-MRI cannot be recommended at the moment due to less than ideal predictive performances of both parameters. PMID:28291007

  19. Diagnostic Value of Diffusion-weighted Imaging and Apparent Diffusion Coefficient Values in the Differentiation of Breast Lesions, Histpathologic Subgroups and Correlatıon with Prognostıc Factors using 3.0 Tesla MR

    PubMed Central

    Akın, Yasin; Uğurlu, M. Ümit; Kaya, Handan; Arıbal, Erkin

    2016-01-01

    Objective The aim of this study was to evaluate the effect of the apparent diffusion coefficient (ADC) and diffusion-weighted imaging in differentiating benign from malignant breast lesions, histopathologic subtypes of breast tumors, and to find a correlation with prognostic factors using 3T MR. Materials and Methods A total of 165 patients aged between 16 and 78 years with 181 histopathologically-verifed breast lesions were enrolled in this study. A 3T MR system and bilateral phased array breast coil was used. Diffusion-weighted imaging was performed with spin echo “echo planar” with “b” values: 50, 400, and 800 seconds/mm2. ADC values were calculated for normal fibroglandular tissue and breast lesions. ADC values of independent groups were compared using Student’s t-test. ROC analysis was used to find a threshold ADC value in the differentiation of lesions. Results The mean ADC values were 1.35±0.16 × 10−3 mm2/s for normal fibroglandular tissue, 1.41±0.24 × 10−3 mm2/s for benign breast lesions and 0.83±0.19 × 10−3 mm2/s for malignant breast lesions. The AUC with ROC analysis was 0.945 and the threshold for ADC was 1.08 × 10−3 mm2/s with a sensitivity and specificity of 92% and 92%, respectively. The threshold value for ADC ratio was 0.9 with 96% sensitivity and 89% specificity. The mean ADC of malignant breast lesions was statistically lower for benign lesions (p<0.01). We found no correlation between the mean ADC values and ER-PR receptor, Her2, and Ki-67 values. Conclusion Diffusion-weighted imaging has high diagnostic value with high sensitivity and specificity in differentiating malignant and benign breast lesions.

  20. QSPR models for prediction of the soil sorption coefficient (log KOC) values of 209 polychlorinated trans-azobenzenes (PCt-ABs).

    PubMed

    Wilczyńska-Piliszek, Agata J; Piliszek, Sławomir; Falandysz, Jerzy

    2012-01-01

    The values of the soil sorption coefficient (K(OC)) have been computed for 209 environmentally relevant trans polychlorinated azobenzenes (PCABs) lacking experimental partitioning data. The quantitative structure-property relationship (QSPR) approach and artificial neural networks (ANN) predictive ability used in models based on geometry optimalization and quantum-chemical structural descriptors, which were computed on the level of density functional theory (DFT) using B3LYP functional and 6-311++G** basis set and of the semi-empirical quantum chemistry method for property parameterization (PM6) of the molecular orbital package (MOPAC). An experimentally available data on physical and chemical properties of PCDD/Fs and PCBs were used as reference data for the QSPR models and ANNs predictions in this study. Both calculation methods gave similar results in term of absolute log K(OC) values, while the PM6 model generated in the MOPAC was a much more efficient compared to the DFT model in GAUSSIAN. The estimated values of log K(OC) varied between 4.93 and 5.62 for mono-, 5.27 and 7.46 for di-, 6.46 and 8.09 for tri-, 6.65 and 9.11 for tetra-, 6.75 and 9.68 for penta-, 6.44 and 10.24 for hexa-, 7.00 and 10.36 for hepta-, 7.09 and 9.82 octa-, 8.94 and 9.71 for nona-Ct-ABs, and 9.26 and 9.34 for deca-Ct-AB. Because of high log K(OC) values PCt-ABs could be classified as compounds with high affinity to the particles of soil, sediments and organic matter.

  1. Time-dependent oral absorption models

    NASA Technical Reports Server (NTRS)

    Higaki, K.; Yamashita, S.; Amidon, G. L.

    2001-01-01

    The plasma concentration-time profiles following oral administration of drugs are often irregular and cannot be interpreted easily with conventional models based on first- or zero-order absorption kinetics and lag time. Six new models were developed using a time-dependent absorption rate coefficient, ka(t), wherein the time dependency was varied to account for the dynamic processes such as changes in fluid absorption or secretion, in absorption surface area, and in motility with time, in the gastrointestinal tract. In the present study, the plasma concentration profiles of propranolol obtained in human subjects following oral dosing were analyzed using the newly derived models based on mass balance and compared with the conventional models. Nonlinear regression analysis indicated that the conventional compartment model including lag time (CLAG model) could not predict the rapid initial increase in plasma concentration after dosing and the predicted Cmax values were much lower than that observed. On the other hand, all models with the time-dependent absorption rate coefficient, ka(t), were superior to the CLAG model in predicting plasma concentration profiles. Based on Akaike's Information Criterion (AIC), the fluid absorption model without lag time (FA model) exhibited the best overall fit to the data. The two-phase model including lag time, TPLAG model was also found to be a good model judging from the values of sum of squares. This model also described the irregular profiles of plasma concentration with time and frequently predicted Cmax values satisfactorily. A comparison of the absorption rate profiles also suggested that the TPLAG model is better at prediction of irregular absorption kinetics than the FA model. In conclusion, the incorporation of a time-dependent absorption rate coefficient ka(t) allows the prediction of nonlinear absorption characteristics in a more reliable manner.

  2. Absorption of 9.6-micron CO2 laser radiation by CO2 at elevated temperatures

    NASA Astrophysics Data System (ADS)

    Robinson, A. M.

    1983-03-01

    Transitions in CO2 gas induced by the absorption of 9.6 micron laser radiation at higher temperatures were examined. Several lines of the 9.6 micron 0011-0012 transition at temperatures between 296-625 K were studied, and the absorption coefficient was determined as a function of temperature. Additional trials were run to define the relative optical broadening coefficients due to He and N2 for the R16-R22 and P16-P22 transitions. The values obtained for the coefficients and the percentage contribution to calculated absorption coefficient at 620 K are provided.

  3. Manganese dioxide causes spurious gold values in flame atomic-absorption readings from HBr-Br2 digestions

    USGS Publications Warehouse

    Campbell, W.L.

    1981-01-01

    False readings, apparently caused by the presence of high concentrations of manganese dioxide, have been observed in our current flame atomic-absorption procedure for the determination of gold. After a hydrobromic acid (HBr)-bromine (Br2) leach, simply heating the sample to boiling to remove excess Br2 prior to extraction with methyl-isobutyl-ketone (MIBK) eliminates these false readings. ?? 1981.

  4. Reconstruction of the absorption spectrum of an object spot from the colour values of the corresponding pixel(s) in its digital image: the challenge of algal colours.

    PubMed

    Coltelli, Primo; Barsanti, Laura; Evangelista, Valter; Frassanito, Anna Maria; Gualtieri, Paolo

    2016-12-01

    A novel procedure for deriving the absorption spectrum of an object spot from the colour values of the corresponding pixel(s) in its image is presented. Any digital image acquired by a microscope can be used; typical applications are the analysis of cellular/subcellular metabolic processes under physiological conditions and in response to environmental stressors (e.g. heavy metals), and the measurement of chromophore composition, distribution and concentration in cells. In this paper, we challenged the procedure with images of algae, acquired by means of a CCD camera mounted onto a microscope. The many colours algae display result from the combinations of chromophores whose spectroscopic information is limited to organic solvents extracts that suffers from displacements, amplifications, and contraction/dilatation respect to spectra recorded inside the cell. Hence, preliminary processing is necessary, which consists of in vivo measurement of the absorption spectra of photosynthetic compartments of algal cells and determination of spectra of the single chromophores inside the cell. The final step of the procedure consists in the reconstruction of the absorption spectrum of the cell spot from the colour values of the corresponding pixel(s) in its digital image by minimization of a system of transcendental equations based on the absorption spectra of the chromophores under physiological conditions.

  5. The emission coefficient of uranium plasmas

    NASA Technical Reports Server (NTRS)

    Schneider, R. T.; Campbell, H. D.; Mack, J. M.

    1973-01-01

    The emission coefficient for uranium plasmas (Temperature: 8000 K) was measured for the wavelength range (200 A - 6000 A). The results are compared to theory and other measurements. The absorption coefficient for the same wavelength interval is also given.

  6. Millimeter and submillimeter wave absorption by atmospheric pollutants and constituents

    NASA Astrophysics Data System (ADS)

    Kolbe, W. F.; Leskovar, B.

    1981-10-01

    Calculated absorption coefficients and rotational transition frequencies are given for a number of polar molecules of interest to pollution and energy research. The results, which are presented in graphical form for microwave frequencies up to 1400 GHz, illustrate the increased absorption line intensities occurring in the submillimeter region. For most species these absorption coefficients attain their maximum values in this region. Included in the calculations are the gases SO2, H2CO, O3, H2O, H2S, OCS, CO, NO, OH, SO, NH3, and CS. A discussion of the techniques currently available for the detection in the submillimeter region of these species is also given.

  7. Radiative properties of the background aerosol: absorption component of extinction.

    PubMed

    Clarke, A D; Charlson, R J

    1985-07-19

    The light-scattering and light-absorption coefficients of the global background aerosol define its single-scatter albedo. Continuous, simultaneous measurements of these optical coefficients were made on a daily basis for the remote marine mid-troposphere; such measurements are essential for assessment of the effects of aerosol on atmospheric radiative transfer. Measurements of light-absorption coefficients made at the Mauna Loa Observatory in Hawaii were higher than expected, and the single-scatter albedo was lower than the value often used in radiative transfer models. Soot appears to be the most likely primary absorber, and hemispheric dispersal of this combustion-derived material is suggested.

  8. Hydroxyl radical reaction rate coefficients as a function of temperature and IR absorption cross sections for CF3CH=CH2 (HFO-1243zf), potential replacement of CF3CH2F (HFC-134a).

    PubMed

    González, Sergio; Jiménez, Elena; Ballesteros, Bernabé; Martínez, Ernesto; Albaladejo, José

    2015-04-01

    CF3CH=CH2 (hydrofluoroolefin, HFO-1243zf) is a potential replacement of high global-warming potential (GWP) hydrofluorocarbon (HFC-134a, CF3CFH2). Both the atmospheric lifetime and the radiative efficiency of HFO-1243zf are parameters needed for estimating the GWP of this species. Therefore, the aim of this work is (i) to estimate the atmospheric lifetime of HFO-1243zf from the reported OH rate coefficients, k OH, determined under tropospheric conditions and (ii) to calculate its radiative efficiency from the reported IR absorption cross sections. The OH rate coefficient at 298 K also allows the estimation of the photochemical ozone creation potential (ε(POCP)). The pulsed laser photolysis coupled to a laser-induced fluorescence technique was used to determine k OH for the reaction of OH radicals with HFO-1243zf as a function of pressure (50-650 Torr of He) and temperature (263-358 K). Gas-phase IR spectra of HFO-1243zf were recorded at room temperature using a Fourier transform IR spectrometer between 500 and 4,000 cm(-1). At all temperatures, k OH did not depend on bath gas concentration (i.e., on the total pressure between 50 and 650 Torr of He). A slight but noticeable T dependence of k OH was observed in the temperature range investigated. The observed behavior is well described by the following Arrhenius expression: k OH(T) = (7.65 ± 0.26) × 10(-13) exp [(165 ± 10) / T] cm(3) molecule(-1) s(-1). Negligible IR absorption of HFO-1243zf was observed at wavenumbers greater than 1,700 cm(-1). Therefore, IR absorption cross sections, [Formula: see text], were determined in the 500-1,700 cm(-1) range. Integrated [Formula: see text] were determined between 650 and 1,800 cm(-1) for comparison purposes. The main diurnal removal pathway for HFO-1243zf is the reaction with OH radicals, which accounts for 64% of the overall loss by homogeneous reactions at 298 K. Globally, the lifetime due to OH reaction (τ OH) was estimated to be 8.7 days under

  9. Absorption Coefficient of Alkali Halides. Part I.

    DTIC Science & Technology

    1979-03-01

    442 LIAY OF ~:S42.~SON T111 ALiSON ,’FlON CU12rCIUNT OF .l~i~ FLUORIVIl: (iviunLvr Iiepcndcncu) (cort .i.j) S’t .~Ue Rne uhr~) ~clo Wvna,br n rt...al. [134j reported their results for the region from 0.170 to 0.197 um and Handi et al. [24] reported results for the range of 35 to 770 pm. Li (331...lection Spectra of Pure and Doped Potassium Iodide at Low Temperatures," Appl. Opt., 7(1), 161-5 (1968). L, __ 243 26. Vergnat, P., Claudel, J., Handi

  10. Charts Adapted from Van Driest's Turbulent Flat-plate Theory for Determining Values of Turbulent Aerodynamic Friction and Heat-transfer Coefficients

    NASA Technical Reports Server (NTRS)

    Lee, Dorothy B; Faget, Maxime A

    1956-01-01

    A modified method of Van Driest's flat-plate theory for turbulent boundary layer has been found to simplify the calculation of local skin-friction coefficients which, in turn, have made it possible to obtain through Reynolds analogy theoretical turbulent heat-transfer coefficients in the form of Stanton number. A general formula is given and charts are presented from which the modified method can be solved for Mach numbers 1.0 to 12.0, temperature ratios 0.2 to 6.0, and Reynolds numbers 0.2 times 10 to the 6th power to 200 times 10 to the 6th power.

  11. Optimization of absorption bands of dye-sensitized and perovskite tandem solar cells based on loss-in-potential values.

    PubMed

    Sobuś, Jan; Ziółek, Marcin

    2014-07-21

    A numerical study of optimal bandgaps of light absorbers in tandem solar cell configurations is presented with the main focus on dye-sensitized solar cells (DSSCs) and perovskite solar cells (PSCs). The limits in efficiency and the expected improvements of tandem structures are investigated as a function of total loss-in-potential (V(L)), incident photon to current efficiency (IPCE) and fill factor (FF) of individual components. It is shown that the optimal absorption onsets are significantly smaller than those derived for multi-junction devices. For example, for double-cell devices the onsets are at around 660 nm and 930 nm for DSSCs with iodide based electrolytes and at around 720 nm and 1100 nm for both DSSCs with cobalt based electrolytes and PSCs. Such configurations can increase the total sunlight conversion efficiency by about 35% in comparison to single-cell devices of the same VL, IPCE and FF. The relevance of such studies for tandem n-p DSSCs and for a proposed new configuration for PSCs is discussed. In particular, it is shown that maximum total losses of 1.7 V for DSSCs and 1.4 V for tandem PSCs are necessary to give any efficiency improvement with respect to the single bandgap device. This means, for example, a tandem n-p DSSC with TiO2 and NiO porous electrodes will hardly work better than the champion single DSSC. A source code of the program used for calculations is also provided.

  12. Accurate and sensitive high-performance liquid chromatographic method for geometrical and structural photoisomers of bilirubin IX alpha using the relative molar absorptivity values.

    PubMed

    Itoh, S; Isobe, K; Onishi, S

    1999-07-02

    It has been reported that considerable differences exist between the relative molar absorptivity values of the geometrical and structural photoisomers of bilirubin. We have devised an accurate HPLC method for photoisomer quantification based on the following principle: the sum of both the integrated peak areas corrected by each factor for each photoisomer, and the integrated peak area of unchanged (ZZ)-bilirubin [(ZZ)-B] after an anaerobic photoirradiation, should be constant and equal to the integrated peak area of initial (ZZ)-bilirubin [(ZZ)-Bi] before photoirradiation. On this basis, the following equation can be used to determine each factor. [equation: see text] alpha, beta, gamma and delta represent the factors used to correct the integrated peak areas of individual bilirubin photoisomers, and they are arranged in the order of the formula. It was demonstrated that the relative 455 nm molar absorptivity values for (ZZ)-bilirubin and all its geometrical and structural photoisomers, i.e., (ZZ)-bilirubin, (ZE)-bilirubin (EZ)-bilirubin, (EZ)-cyclobilirubin (= lumirubin) and (EE)-cyclobilirubin in the HPLC eluent, are, respectively, 1.0, 0.81 (= alpha), 0.54 (= beta), 0.47 (= gamma) and 0.39 (= delta).

  13. Absorption of visible radiation by aerosols in the volcanic plume of mount st. Helens.

    PubMed

    Ogren, J A; Charlson, R J; Radke, L F; Domonkos, S K

    1981-02-20

    Samples of particles from Mount St. Helens were collected in both the stratosphere and troposphere for measurement of the light absorption coefficient. Results indicate that the stratospheric dust had a small but finite absorption coefficient ranging up to 2 x 10(-7) per meter at a wavelength of 0.55 micrometer, which is estimated to yield an albedo for single scatter of 0.98 or greater. Tropospheric results showed similar high values of an albedo for single scatter.

  14. Absorption of visible radiation by aerosols in the volcanic plume of Mount St. Helens

    SciTech Connect

    Ogren, J.A.; Charlson, R.J.; Radke, L.F.; Domonkos, S.K.

    1981-01-01

    Samples of particles from Mount St. Helens were collected in both the stratosphere and troposhere for measurement of the light absorption coefficient. Results indicate that the stratospheric dust had a small but finite absorption coefficient ranging up to 2 x 10-7 per meter at a wavelength of 0.55 micrometer, which is estimated to yield an albedo for single scatter of 0.98 or greater. Tropospheric results showed similar high values of an albedo for single scatter.

  15. An in silico skin absorption model for fragrance materials.

    PubMed

    Shen, Jie; Kromidas, Lambros; Schultz, Terry; Bhatia, Sneha

    2014-12-01

    Fragrance materials are widely used in cosmetics and other consumer products. The Research Institute for Fragrance Materials (RIFM) evaluates the safety of these ingredients and skin absorption is an important parameter in refining systemic exposure. Currently, RIFM's safety assessment process assumes 100% skin absorption when experimental data are lacking. This 100% absorption default is not supportable and alternate default values were proposed. This study aims to develop and validate a practical skin absorption model (SAM) specific for fragrance material. It estimates skin absorption based on the methodology proposed by Kroes et al. SAM uses three default absorption values based on the maximum flux (J(max)) - namely, 10%, 40%, and 80%. J(max) may be calculated by using QSAR models that determine octanol/water partition coefficient (K(ow)), water solubility (S) and permeability coefficient (K(p)). Each of these QSAR models was refined and a semi-quantitative mechanistic model workflow is presented. SAM was validated with a large fragrance-focused data set containing 131 materials. All resulted in predicted values fitting the three-tiered absorption scenario based on Jmax ranges. This conservative SAM may be applied when fragrance material lack skin absorption data.

  16. An unsteady-state method for determining overall coefficient of heat transfer (k-value) of insulated bodies at variable external temperatures

    NASA Astrophysics Data System (ADS)

    Gvozdenac, Dušan

    2015-02-01

    A method for determining k-value of insulated bodies at variable external temperatures is proposed, theoretically described and results of experimental verification are presented in this paper. Theoretical analyses include descriptions of both physical and mathematical models and definition of the extrapolation formula. The method is tested in laboratory conditions on a simple model of insulated chamber and compliance with all testing conditions prescribed by Agreement on Transport of Perishables. The advantage of this method in comparison to any other unsteady- or steady-state method is that it enables k-value determination out of the specialized test stations. This further makes it possible to carry out cheaper and more frequent k-value measurements/control in insulated bodies. Also, the proposed method can be used for testing the k-value of stationary insulated chambers which cannot be objectively tested by means of stationary methods.

  17. X-ray absorption near-edge structure study on the configuration of Cu 2+ /histidine complexes at different pH values

    NASA Astrophysics Data System (ADS)

    Mei-Juan, Yu; Yu, Wang; Wei, Xu

    2016-04-01

    The local configurations around metal ions in metalloproteins are of great significance for understanding their biological functions. Cu2+/histidine (His) is a typical complex existing in many metalloproteins and plays an important role in lots of physiological functions. The three-dimensional (3D) structural configurations of Cu2+/His complexes at different pH values (2.5, 6.5, and 8.5) are quantitatively determined by x-ray absorption near-edge structure (XANES). Generally Cu2+/His complex keeps an octahedral configuration consisting of oxygen atoms from water molecules and oxygen or nitrogen atoms from histidine molecules coordinated around Cu2+. It is proved in this work that the oxygen atoms from water molecules, when increasing the pH value from acid to basic value, are gradually substituted by the Ocarboxyl, Nam, and Nim from hisitidine molecules. Furthermore, the symmetries of Cu2+/His complexes at pH 6.5 and pH 8.5 are found to be lower than at pH 2.5. Project supported by the National Natural Science Foundation of China (Grant No. 11205186).

  18. Novel zinc(II)phthalocyanines bearing azo-containing schiff base: Determination of pKa values, absorption, emission, enzyme inhibition and photochemical properties

    NASA Astrophysics Data System (ADS)

    Kantar, Cihan; Mavi, Vildan; Baltaş, Nimet; İslamoğlu, Fatih; Şaşmaz, Selami

    2016-10-01

    Azo-containing schiff bases are well known and there are many studies about their various properties in literature. However, phthalocyanines bearing azo-containing schiff bases, their spectral, analytical and biological properties are unknown. Therefore, new zinc (II) phthalocyanines bearing azo-containing schiff base were synthesized and investigated to determine pKa values, absorption, emission, enzyme inhibition and photochemical properties. Emission spectra were reported and large Stokes shift values were determined for all compounds, indicating that all molecules exhibit excited state intramolecular proton transfer. These phthalocyanines were the first examples of phthalocyanine showing excited state intramolecular proton transfer. Singlet oxygen quantum yields of zinc (II) phthalocyanines were determined. pKa values and indicator properties of all compounds were investigated by potentiometry. All compounds were assayed for inhibitory activity against bovine milk xanthine oxidase and acetylcholinesterase enzyme in vitro. Compound 2 showed the high inhibitory effect against xanthine oxidase (IC50 = 0.24 ± 0.01 μM). However, phthalocyanine compounds did not show enzyme inhibitor behavior.

  19. Adaptive neuro-fuzzy inference system multi-objective optimization using the genetic algorithm/singular value decomposition method for modelling the discharge coefficient in rectangular sharp-crested side weirs

    NASA Astrophysics Data System (ADS)

    Khoshbin, Fatemeh; Bonakdari, Hossein; Hamed Ashraf Talesh, Seyed; Ebtehaj, Isa; Zaji, Amir Hossein; Azimi, Hamed

    2016-06-01

    In the present article, the adaptive neuro-fuzzy inference system (ANFIS) is employed to model the discharge coefficient in rectangular sharp-crested side weirs. The genetic algorithm (GA) is used for the optimum selection of membership functions, while the singular value decomposition (SVD) method helps in computing the linear parameters of the ANFIS results section (GA/SVD-ANFIS). The effect of each dimensionless parameter on discharge coefficient prediction is examined in five different models to conduct sensitivity analysis by applying the above-mentioned dimensionless parameters. Two different sets of experimental data are utilized to examine the models and obtain the best model. The study results indicate that the model designed through GA/SVD-ANFIS predicts the discharge coefficient with a good level of accuracy (mean absolute percentage error = 3.362 and root mean square error = 0.027). Moreover, comparing this method with existing equations and the multi-layer perceptron-artificial neural network (MLP-ANN) indicates that the GA/SVD-ANFIS method has superior performance in simulating the discharge coefficient of side weirs.

  20. Limiting values of diffusion coefficients of glycine, alanine, [Formula: see text]-amino butyric acid, norvaline and norleucine in a relevant physiological aqueous medium.

    PubMed

    Rodriguez, Diana M; Verissimo, Luis M P; Barros, Marisa C F; Rodrigues, Daniela F S L; Rodrigo, Maria Melia; Esteso, Miguel A; Romero, Carmen M; Ribeiro, Ana C F

    2017-02-01

    The side chain effect on transport in ionic aqueous salt solutions was investigated for [Formula: see text]-amino acids glycine, alanine, [Formula: see text]-amino butyric acid, norvaline, and norleucine --that together define a chemical homologous series based on the length of the characteristic side chain which increases from zero to four carbons, respectively. Binary mutual diffusion coefficients at infinitesimal concentration in aqueous solutions of NaCl (0.15 mol kg (-1)) are measured by means of Taylor dispersion technique for this series and significant differences were found against previous published results for identical systems in pure water. In this way, NaCl effect on the transport of each amino acid is thus assessed and discussed in terms of salting-out effects. Also, solvated Stokes hydrodynamic radii were computed for the series showing comparable results in water and NaCl solution. The new information should prove useful in the design and characterization of transport-controlled systems in physiological and pharmacological studies.

  1. Acoustic Absorption Characteristics of People.

    ERIC Educational Resources Information Center

    Kingsbury, H. F.; Wallace, W. J.

    1968-01-01

    The acoustic absorption characteristics of informally dressed college students in typical classroom seating are shown to differ substantially from data for formally dressed audiences in upholstered seating. Absorption data, expressed as sabins per person or absorption coefficient per square foot, shows that there is considerable variation between…

  2. Photon mass energy transfer coefficients for elements z=1 to 92 and 48 additional substances of dosimetric interest.

    PubMed

    Kato, Hideki

    2014-07-01

    Photon mass energy transfer coefficient is an essential factor when converting photon energy fluence into kinetic energy released per unit mass (kerma). Although mass attenuation coefficient and mass energy absorption coefficients can be looked up in databases, the mass energy transfer coefficient values are still controversial. In this paper, the photon mass energy transfer coefficients for elements Z=1-92 were calculated based on cross-sectional data for each photon interaction type. Mass energy transfer coefficients for 48 compounds and/or mixtures of dosimetric interest were calculated from coefficient data for elements using Bragg's additivity rule. We additionally developed software that can search these coefficient data for any element or substance of dosimetric interest. The database and software created in this paper should prove useful for radiation measurements and/or dose calculations.

  3. Determination of the major groups of phytoplankton pigments from the absorption spectra of total particulate matter

    NASA Technical Reports Server (NTRS)

    Hoepffner, Nicolas; Sathyendranath, Shubha

    1993-01-01

    The contributions of detrital particles and phytoplankton to total light absorption are retrieved by nonlinear regression on the absorption spectra of total particles from various oceanic regions. The model used explains more than 96% of the variance in the observed particle absorption spectra. The resulting absorption spectra of phytoplankton are then decomposed into several Gaussian bands reflecting absorption by phytoplankton pigments. Such a decomposition, combined with high-performance liquid chromatography data on phytoplankton pigment concentrations, allows the computation of specific absorption coefficients for chlorophylls a, b, and c and carotenoids. The spectral values of these in vivo absorption coefficients are then discussed, considering the effects of secondary pigments which were not measured quantitatively. We show that these coefficients can be used to reconstruct the absorption spectra of phytoplankton at various locations and depths. Discrepancies that do occur at some stations are explained in terms of particle size effect. These coefficients can be used to determine the concentrations of phytoplankton pigments in the water, given the absorption spectrum of total particles.

  4. Determination of the major groups of phytoplankton pigments from the absorption spectra of total particulate matter

    NASA Astrophysics Data System (ADS)

    Hoepffner, Nicolas; Sathyendranath, Shubha

    1993-12-01

    The contributions of detrital particles and phytoplankton to total light absorption are retrieved by nonlinear regression on the absorption spectra of total particles from various oceanic regions. The model used explains more than 96% of the variance in the observed particle absorption spectra. The resulting absorption spectra of phytoplankton are then decomposed into several Gaussian bands reflecting absorption by phytoplankton pigments. Such a decomposition, combined with high-performance liquid chromatography data on phytoplankton pigment concentrations, allows the computation of specific absorption coefficients for chlorophylls a, b, and c and carotenoids. The spectral values of these in vivo absorption coefficients are then discussed, considering the effects of secondary pigments which were not measured quantitatively. We show that these coefficients can be used to reconstruct the absorption spectra of phytoplankton at various locations and depths. Discrepancies that do occur at some stations are explained in terms of particle size effect. These coefficients can be used to determine the concentrations of phytoplankton pigments in the water, given the absorption spectrum of total particles.

  5. Monte Carlo Simulation of the Optical Absorption of Hydrogenated Nanocrystalline Silicon Thin Films

    NASA Astrophysics Data System (ADS)

    Besahraoui, Fatiha; Sib, Jamal Dine; Bouizem, Yahia; Chahed, Larbi

    2008-05-01

    The optical absorption coefficient measured by Constant Photocurrent Method (CPM) for nanotextured silicon thin films is apparent affected by light scattering produced in these heterogeneous materials. A detailed Monte Carlo simulation of the absorption spectra and the random optical paths traveled by the scattered photons is presented for the case of nano-Si:H layers. The calculated values of apparent absorption coefficient and the mean optical path depend mainly on the variation of the included nanocrystallites fraction, which favors bulk light scattering phenomena. The particular structure of these materials is a key characteristic of efficient thin films solar cells.

  6. Experimental determination of terahertz atmospheric absorption parameters

    NASA Astrophysics Data System (ADS)

    Slocum, David M.; Goyette, Thomas M.; Giles, Robert H.; Nixon, William E.

    2015-05-01

    The terahertz frequency regime is often used as the `chemical fingerprint' region of the electromagnetic spectrum since many molecules exhibit a dense selection of rotational and vibrational transitions. Water is a major component of the atmosphere and since it has a large dipole moment the propagation of terahertz radiation will be dominated by atmospheric effects. This study will present the results of high-­-resolution broadband measurements of the terahertz atmospheric absorption and detail the technique for directly measuring the pressure broadening coefficients, absolute absorption coefficients, line positions, and continuum effects. Differences between these measured parameters and those tabulated in HITRAN will be discussed. Once the water vapor absorption was characterized, the same technique was used to measure the line parameters for methanol, a trace gas of interest within Earth's atmosphere. Methanol has a dense absorption spectrum in the terahertz frequency region and is an important molecule in fields such as environmental monitoring, security, and astrophysics. The data obtained in the present study will be of immediate use for the remote sensing community, as it is uncommon to measure this many independent parameters as well as to measure the absolute absorption of the transitions. Current models rely on tabulated databases of calculated values for the line parameters measured in this study. Differences between the measured data and those in the databases will be highlighted and discussed.

  7. Infrasound absorption by atmospheric clouds

    NASA Astrophysics Data System (ADS)

    Baudoin, Michael; Coulouvrat, Francois; Thomas, Jean-Louis

    2010-05-01

    A model is developed for the absorption of infrasound by atmospheric clouds made of a suspension of liquid water droplets within a gaseous mixture of water vapor and air. The model is based on the work of D.A. Gubaidullin and R.I. Nigmatulin [Int. J. Multiphase Flow, 26, 207-228, 2000], which is applied to atmospheric clouds. Three physical mechanisms are included : unsteady viscous drag associated with momentum transfers due to the translation of water droplets, unsteady thermal transfers between the liquid and gaseous phases, and mass transfers due to the evaporation or condensation of the water phase. For clouds, in the infrasonic frequency range, phase changes are the dominant mechanisms (around 1 Hz), while viscous and heat transfers become significant only around 100 Hz. Mass transfers involve two physical effects : evaporation and condensation of the water phase at the droplet surface, and diffusion of the water vapor within the gaseous phase. The first one is described through the Hertz-Knudsen-Langmuir theory based on kinetic theory. It involves a little known coefficient known as coefficient of accommodation. The second one is the classical Fick diffusion. For clouds, and unless the coefficient of accommodation is very small (far from the generally recommended value is close to one), diffusion is the main limiting effects for mass transfers. In a second stage, the sound and infrasound absorption is evaluated for various typical clouds up to about 4 km altitude. Above this altitude, the ice content of clouds is dominant compared to their water content, and the present model is not applicable. Cloud thickness, water content, and droplets size distribution are shown to be the major factors influencing the infrasound absorption. A variety of clouds have been analyzed. In most cases, it is shown that infrasound absorption within clouds is several orders larger than classical absorption (due to molecular relaxation of nitrogen and oxygen molecules in presence

  8. Influence of the pH value of a colloidal gold solution on the absorption spectra of an LSPR-assisted sensor

    SciTech Connect

    Zhu, Jin; Li, Wenbin; Zhu, Mao; Zhang, Wei; Niu, Wencheng; Liu, Guohua

    2014-03-15

    The localized surface plasmon resonances (LSPRs) of gold particles assembled on a crystal plate are a powerful tool for biological sensors. Here, we prepare gold colloids in different pH solutions. We monitor the effects of the particle radius and particle coverage on the absorption spectra of AT-cut (r-face dihedral angle of about 3°) crystal plates supporting gold nanoparticles. The surface morphologies were monitored on silicon dioxide substrates using ultraviolet and visible (UV-vis) spectroscopy, and atomic force microscopy (AFM). The results showed that the gold particle coverage decreases with increasing pH value of the gold colloid solution. This phenomenon demonstrates that self-assembled gold surfaces were formed via the electrostatic adsorption of gold particles on the positively charged, ionized amino groups on the crystal plates in the acidic solution. The spectrum of gold nanoparticles with different coverage degree on the crystal plates showed that the LSPR properties are highly dependent on pH.

  9. Optical absorption measurement system

    DOEpatents

    Draggoo, Vaughn G.; Morton, Richard G.; Sawicki, Richard H.; Bissinger, Horst D.

    1989-01-01

    The system of the present invention contemplates a non-intrusive method for measuring the temperature rise of optical elements under high laser power optical loading to determine the absorption coefficient. The method comprises irradiating the optical element with a high average power laser beam, viewing the optical element with an infrared camera to determine the temperature across the optical element and calculating the absorption of the optical element from the temperature.

  10. Triplet extinction coefficients of some laser dyes. II

    SciTech Connect

    Pavlopoulos, T.G.; Golich, D.J.

    1990-01-01

    We measured the triplet extinction coefficients over the laser action spectral region of DODC, DMC, Sulforhodamine B, Rhodamine 575, Coumarin 523, Coumarin 521, Coumarin 504, Coumarin 498, Coumarin 490, LD466, bis-MSB, and BBO. We employed the different lines from an argon and a krypton ion cw laser for excitation. McClure's method was again employed to measure the triplet extinction coefficients. We provide a simplified derivation of McClure's equation. The triplet extinction coefficient of Rhodamine 575 was also measured by using the depletion method and improving it by reconstructing for true triplet-triplet (T-T) absorption. The ET value obtained is in good agreement with the one obtained by McClure's method.

  11. Spectral absorption properties of colored dissolved organic matter (CDOM) and total suspended matter (TSM) of inland waters

    NASA Astrophysics Data System (ADS)

    Song, Kaishan; Liu, Dianwei; Li, Lin; Wang, Zongming; Wang, Yuandong; Jiang, Guangjia

    2010-08-01

    Spectral absorption properties of total suspended matter (TSM) and colored dissolved organic matter (CDOM) are important for the use of the bio-optical model to estimate water quality parameters. This study aims to investigate the variation in the absorption coefficients of TSM and CDOM of inland waters. A total of 92 water samples were collected from Shitoukoumen Reservoir and Songhua Lake in Northeast China, analyzed for TSM and Chl-a, and measured for the absorption coefficient of TSM, CDOM and total pigments using a laboratory spectrophotometer. The absorption coefficient of TSM has been decomposed for phytoplankton and inorganic sediments. The results show that for Shitoukoumen Reservoir, CDOM has strong absorptions with shallow absorption slopes (i.e., the coefficient S in a(λ)=a(λ0)exp[-S(λ- λ0)]) and large absorption at 355 nm; and for Songhua Lake, CDOM follows similar spectral absorption curves but less variation in the S value. The results also show TSM has the average absorption coefficient 5.7 m-1 at 440 nm and 0.93 m-1 at 675 nm, and their concentration is well correlated to TSM with R2 larger than 0.85 at 440 nm over both Songhu Lake and Shitoukoumen Reservoir. In summer, CDOM was mainly terrigenous and had a high proportion of humic acid derived from the decomposition of phytoplankton and there were no obvious difference of S value. The results indicate that inorganic sediments contributed much more absorption than phytoplankton pigments in Shitoukoumen Reservoir than that in Songhua Lake, and there is strong association of TSM concentration to absorption coefficient at 440 nm.

  12. Atmospheric absorption cell characterization

    NASA Astrophysics Data System (ADS)

    1982-06-01

    The measurement capability of the Avionics Laboratory IR Facility was used to evaluate an absorption cell that will be used to simulate atmospheric absorption over horizontal paths of 1 - 10 km in length. Band models were used to characterize the transmittance of carbon dioxide (CO2), nitrogen (N2), and nitrous oxide (N2O) in the cell. The measured transmittance was compared to the calculated values. Nitrous oxide is important in the 4 - 4.5 micron range in shaping the weak line absorption of carbon dioxide. The absorption cell is adequate for simulating atmospheric absorption over these paths.

  13. Free-free absorption of infrared radiation in collisions of electrons with neutral rare-gas atoms

    NASA Technical Reports Server (NTRS)

    Stallcop, J. R.

    1974-01-01

    A relationship between the inverse bremsstrahlung absorption cross section and the electron neutral momentum transfer cross section has been utilized to determine the infrared free-free continuum absorption coefficient for the negative ions of helium, neon, argon, krypton, and xenon. The values of the momentum transfer cross section for this calculation have been obtained from experimental measurements. Analytical expressions for the absorption coefficient have also been developed. From the results of this calculation, it is possible to determine the absorption coefficient per unit electron density per neutral atom for temperatures in the range from 2500 to 25,000 K. The results are compared with those from tabulations of previous calculations and those computed from theoretical values of the phase shifts for the elastic scattering of electrons by neutral atoms.

  14. Quantitative broadband absorption and scattering spectroscopy in turbid media by combined frequency-domain and steady state methodologies

    DOEpatents

    Tromberg, Bruce J.; Berger, Andrew J.; Cerussi, Albert E.; Bevilacqua, Frederic; Jakubowski, Dorota

    2008-09-23

    A technique for measuring broadband near-infrared absorption spectra of turbid media that uses a combination of frequency-domain and steady-state reflectance methods. Most of the wavelength coverage is provided by a white-light steady-state measurement, whereas the frequency-domain data are acquired at a few selected wavelengths. Coefficients of absorption and reduced scattering derived from the frequency-domain data are used to calibrate the intensity of the steady-state measurements and to determine the reduced scattering coefficient at all wavelengths in the spectral window of interest. The absorption coefficient spectrum is determined by comparing the steady-state reflectance values with the predictions of diffusion theory, wavelength by wavelength. Absorption spectra of a turbid phantom and of human breast tissue in vivo, derived with the combined frequency-domain and steady-state technique, agree well with expected reference values.

  15. Millimeter and submillimeter wave absorption by atmospheric pollutants and constituents

    SciTech Connect

    Kolbe, W.F.; Leskovar, B.

    1981-10-01

    Calculated absorption coefficients and rotational transition frequencies are given for a number of polar molecules of interest to pollution and energy research. The results, which are presented in graphical form for microwave frequencies up to 1400 GHz, illustrate the increased absorption line intensities occurring in the submillimeter region. For most species these absorption coefficients attain their maximum values in this region. Included in the calculations are the gases SO/sub 2/, H/sub 2/CO, O/sub 3/, H/sub 2/O, H/sub 2/S, OCS, CO, NO, OH, SO, NH/sub 3/, and CS. A discussion of the techniques currently available for the detection in the submillimeter region of these species is also given.

  16. Enhanced absorption in silicon metamaterials waveguide structure

    NASA Astrophysics Data System (ADS)

    Hamouche, Houria; Shabat, Mohammed M.

    2016-07-01

    Metamaterial waveguide structures for silicon solar cells are a novel approach to antireflection coating structures that can be used for the achievement of high absorption in silicon solar cells. This paper investigates numerically the possibility of improving the performance of a planar waveguide silicon solar cell by incorporating a pair of silicon nitride/metamaterial layer between a semi-infinite glass cover layer and a semi-infinite silicon substrate layer. The optimized layer thicknesses of the pair are determined under the solar spectrum AM1.5 by the effective average reflectance method. The transmission and reflection coefficients are derived by the transfer matrix method for values of metamaterial's refractive index in visible and near-infrared radiation. In addition, the absorption coefficient is examined for several angles of incidence of the transverse electric polarized (TE), transverse magnetic polarized (TM) and the total (TE&TM) guided waves. Numerical results provide an extremely high absorption. The absorptivity of the structure achieves greater than 98 %.

  17. Comparison of vertical aerosol extinction coefficients from in-situ and LIDAR measurements

    NASA Astrophysics Data System (ADS)

    Rosati, B.; Herrmann, E.; Bucci, S.; Fierli, F.; Cairo, F.; Gysel, M.; Tillmann, R.; Größ, J.; Gobbi, G. P.; Di Liberto, L.; Di Donfrancesco, G.; Wiedensohler, A.; Weingartner, E.; Virtanen, A.; Mentel, T. F.; Baltensperger, U.

    2015-07-01

    Vertical profiles of aerosol optical properties were explored in a case study near the San Pietro Capofiume (SPC) ground station during the PEGASOS Po Valley campaign in the summer of 2012. A Zeppelin NT airship was employed to investigate the effect of the dynamics of the planetary boundary layer at altitudes between ~ 50-800 m above ground. Determined properties included the aerosol size distribution, the hygroscopic growth factor, the effective index of refraction and the light absorption coefficient. The first three parameters were used to retrieve the light scattering coefficient. Simultaneously, direct measurements of both the scattering and absorption coefficient were carried out at the SPC ground station. Additionally, a LIDAR system provided aerosol extinction coefficients for a vertically resolved comparison between in-situ and remote sensing results. First, the airborne results at low altitudes were validated with the ground measurements. Agreement within approximately ±25 and ±20% was found for the dry scattering and absorption coefficient, respectively. The single scattering albedo, ranged between 0.83 to 0.95, indicating the importance of the absorbing particles in the Po Valley region. A clear layering of the atmosphere was observed during the beginning of the flight (until ~ 10 local time) before the mixed layer (ML) was fully developed. Highest extinction coefficients were found at low altitudes, in the new ML, while values in the residual layer, which could be probed at the beginning of the flight at elevated altitudes, were lower. At the end of the flight (after ~ 12 local time) the ML was fully developed, resulting in constant extinction coefficients at all altitudes measured on the Zeppelin NT. LIDAR results captured these dynamic features well and good agreement was found for the extinction coefficients compared to the in-situ results, using fixed LIDAR ratios (LR) between 30 and 70 sr for the altitudes probed with the Zeppelin. These LR are

  18. A study of pump power absorption efficiency of a diode side-pumped thin disk laser

    NASA Astrophysics Data System (ADS)

    Guo, Wei-rong; Feng, Chi; Li, Qiang; Yan, Le-lun; Jiang, Meng-hua

    2011-06-01

    A method computing the absorption efficiency with the difference between pump power entering the thin disk and pump power transmitted through the disk is introduced. Compared with directly computing the absorbed power, the method presented here needs much less computation to achieve the same accuracy, making it possible to compare much more absorption efficiency values at higher accuracy with a few parameters varied within certain ranges. Nonabsorption loss values were calculated with absorption coefficient, array distance and round disk radius varied within certain ranges. Results of calculation showed that the nonabsorption loss generally increases with increasing array distance, decreases with increasing round disk radius and decreases with increasing absorption coefficient. The method introduced by this paper presents a theoretical reference for the optimal design of thin disk lasers.

  19. Light Absorption in the Stratosphere: Trend, Soot Aerosol Concentration and Contribution by...

    NASA Technical Reports Server (NTRS)

    Pueschel, R. F.; Verma, S.; Strwwa, A. W.; Ferry, G. V.; Hamill, P.; Vay, S.; Gore, Warren J. Y. (Technical Monitor)

    1997-01-01

    The light absorption coefficient, Beta(a) of the stratospheric aerosol is an important quantity that determines its radiative effects. When combined with the aerosol scattering coefficient, Beta(a) it becomes possible to evaluate the aerosol single scatter albedo, omega = Beta(s)/(Beta(s) + Beta(a)) which is essential for modeling the overall radiative effects of the stratospheric aerosol. Pollack1 determined that omega = 0.98 is a critical value that separates stratospheric cooling from warming.

  20. Petawatt laser absorption bounded

    PubMed Central

    Levy, Matthew C.; Wilks, Scott C.; Tabak, Max; Libby, Stephen B.; Baring, Matthew G.

    2014-01-01

    The interaction of petawatt (1015 W) lasers with solid matter forms the basis for advanced scientific applications such as table-top particle accelerators, ultrafast imaging systems and laser fusion. Key metrics for these applications relate to absorption, yet conditions in this regime are so nonlinear that it is often impossible to know the fraction of absorbed light f, and even the range of f is unknown. Here using a relativistic Rankine-Hugoniot-like analysis, we show for the first time that f exhibits a theoretical maximum and minimum. These bounds constrain nonlinear absorption mechanisms across the petawatt regime, forbidding high absorption values at low laser power and low absorption values at high laser power. For applications needing to circumvent the absorption bounds, these results will accelerate a shift from solid targets, towards structured and multilayer targets, and lead the development of new materials. PMID:24938656

  1. Combined effects of scattering and absorption on laser speckle contrast imaging

    NASA Astrophysics Data System (ADS)

    Khaksari, Kosar; Kirkpatrick, Sean J.

    2016-07-01

    Several variables may affect the local contrast values in laser speckle contrast imaging (LSCI), irrespective of relative motion. It has been suggested that the optical properties of the moving fluid and surrounding tissues can affect LSCI values. However, a detailed study of this has yet to be presented. In this work, we examined the combined effects of the reduced scattering and absorption coefficients on LSCI. This study employs fluid phantoms with different optical properties that were developed to mimic whole blood with varying hematocrit levels. These flow phantoms were imaged with an LSCI system developed for this study. The only variable parameter was the optical properties of the flowing fluid. A negative linear relationship was seen between the changes in contrast and changes in reduced scattering coefficient, absorption coefficient, and total attenuation coefficient. The change in contrast observed due to an increase in the scattering coefficient was greater than what was observed with an increase in the absorption coefficient. The results indicate that optical properties affect contrast values and that they should be considered in the interpretation of LSCI data.

  2. Factor Scores, Structure Coefficients, and Communality Coefficients

    ERIC Educational Resources Information Center

    Goodwyn, Fara

    2012-01-01

    This paper presents heuristic explanations of factor scores, structure coefficients, and communality coefficients. Common misconceptions regarding these topics are clarified. In addition, (a) the regression (b) Bartlett, (c) Anderson-Rubin, and (d) Thompson methods for calculating factor scores are reviewed. Syntax necessary to execute all four…

  3. Optoacoustic spectroscopy and its application to molecular and particle absorption

    NASA Astrophysics Data System (ADS)

    Trees, Charles C.; Voss, Kenneth J.

    1990-09-01

    Light absorption in the ocean has been the least studied optical property because of the difficulties in making accurate measurements. With the previously used techniques, large differences have been reported for the specific absorption coefficient of phytoplankton (cultures and natural assemblages). It is difficult to determine if the diversity in these values are methodological or a function of actual variations in absorption. With the renewed interest and activity in optoacoustic spectroscopy (OAS), which accurately measures absorption, some of these discrepancies should be resolved. In this method, as molecules and particles absorb light from a modulated source, they thermally expand and contract, thereby generating acoustic waves, at the modulation frequency, which are detected by a hydrophone. Optoacoustic spectroscopy is ideally suited for measuring dissolved organic material and particle absorptions because of its high sensitivity (105m1) and the egligible effect of scattered light. In this paper the instrumental design for an optoacoustic spectrophotometer (OAS), which pecifically measures phytoplankton absorption (420-S5Onm), is described. The spectral absorption of dissolved organic material and a phytoplankton culture is presented. OAS holds promise in being able to measure absorption without use of either filtration or concentration techniques.

  4. Cytoplasmic hydrogen ion diffusion coefficient.

    PubMed Central

    al-Baldawi, N F; Abercrombie, R F

    1992-01-01

    The apparent cytoplasmic proton diffusion coefficient was measured using pH electrodes and samples of cytoplasm extracted from the giant neuron of a marine invertebrate. By suddenly changing the pH at one surface of the sample and recording the relaxation of pH within the sample, an apparent diffusion coefficient of 1.4 +/- 0.5 x 10(-6) cm2/s (N = 7) was measured in the acidic or neutral range of pH (6.0-7.2). This value is approximately 5x lower than the diffusion coefficient of the mobile pH buffers (approximately 8 x 10(-6) cm2/s) and approximately 68x lower than the diffusion coefficient of the hydronium ion (93 x 10(-6) cm2/s). A mobile pH buffer (approximately 15% of the buffering power) and an immobile buffer (approximately 85% of the buffering power) could quantitatively account for the results at acidic or neutral pH. At alkaline pH (8.2-8.6), the apparent proton diffusion coefficient increased to 4.1 +/- 0.8 x 10(-6) cm2/s (N = 7). This larger diffusion coefficient at alkaline pH could be explained quantitatively by the enhanced buffering power of the mobile amino acids. Under the conditions of these experiments, it is unlikely that hydroxide movement influences the apparent hydrogen ion diffusion coefficient. PMID:1617134

  5. Thermally induced effect on sub-band gap absorption in Ag doped CdSe thin films

    NASA Astrophysics Data System (ADS)

    Kaur, Jagdish; Sharma, Kriti; Bharti, Shivani; Tripathi, S. K.

    2015-05-01

    Thin films of Ag doped CdSe have been prepared by thermal evaporation using inert gas condensation (IGC) method taking Argon as inert gas. The prepared thin films are annealed at 363 K for one hour. The sub-band gap absorption spectra in the as deposited and annealed thin films have been studied using constant photocurrent method (CPM). The absorption coefficient in the sub-band gap region is described by an Urbach tail in both as deposited and annealed thin films. The value of Urbach energy and number density of trap states have been calculated from the absorption coefficient in the sub-band gap region which have been found to increase after annealing treatment indicating increase in disorderness in the lattice. The energy distribution of the occupied density of states below Fermi level has also been studied using derivative procedure of absorption coefficient.

  6. [Light absorption by suspended particulate matter in Chagan Lake, Jilin].

    PubMed

    Wang, Yuan-Dong; Liu, Dian-Wei; Song, Kai-Shan; Zhang, Bai; Wang, Zong-Ming; Jiang, Guang-Ji; Tang, Xu-Guang; Lei, Xiao-Chun; Wu, Yan-Qing

    2011-01-01

    Spectral characteristics and the magnitudes of light absorption by suspended particulate matter were determined by spectrophotometry in this optically complex Lake Chagan waters for the purpose of surveying the natural variability of the absorption coefficients to parameterize the bio-optical models for converting satellite or in-situ water reflectance signatures into water quality information. Experiments were carried out on seasonal frozen Lake Chagan, one representative inland case-2 water body in Northeast of China. Particulate absorption properties analyzed using the field data on July 15th and October 12th 2009 were measured using the quantitative filter technique to produce absorption spectra containing several fractions that could be attributed to two main optical active constituents (OACs) phytoplankton pigments and non-algal particulates (mineral sediments, and organic detritus). Results suggested that the suspended particulate matter (SPM) concentration was higher while phytoplankton biomass (chlorophyll-a concentration) was lower in July and that in October. The spectral shape of total suspended particulate matter resembled that of non-algal particulates which contributed greater than phytoplankton in total particulate absorption during both periods. An obvious absorption peak occurring at around 440 nm exhibited an increase in phytoplankton contribution in October. Non-algal particulate absorption at 440 nm (a(NAP) (440)) had better correlation with total suspended particulate matter concentration than that with chlorophyll-a over the two periods. Light absorption by phytoplankton pigments in the Chagan lake region was generally lower than that of non-algal components. Chl. a dominating phytoplankton pigment composition functioned exponentially with its absorption coefficients at 440 and 675 nm specifically, the average values of which in July were 0.146 8 m2 x mg(-1) and 0.050 3 respectively while in October they were 0.153 3 and 0.013 2 m2 x mg(-1

  7. Time-resolved postdischarge absolute silicon monoxide density measurement by resonant absorption spectroscopy in a nonthermal atmospheric plasma

    SciTech Connect

    Motret, Olivier; Coursimault, Fabien; Pouvesle, Jean-Michel

    2006-11-01

    In this study we present the technique of resonant absorption spectroscopy diagnostic developed to estimate the density of silicon monoxide (SiO) molecules during the postdischarge of an atmospheric dielectric barrier discharge plasma. The ultraviolet (0,0) rovibrational band of the SiO(A {sup 1}{pi}-X {sup 1}{sigma}{sup +}) electronic transition was investigated. Effective values of absorption coefficient and absorption cross section for the rotational transitions under consideration were calculated. The SiO concentration was estimated by comparison between experimental and computed spectra. The self-absorption in the probe reactor was taken into account in the computed spectra.

  8. Effects of ternary mixed crystal and size on intersubband optical absorption in wurtzite InGaN/GaN core-shell nanowires

    NASA Astrophysics Data System (ADS)

    Liu, W. H.; Yang, S.; Feng, H. M.; Yang, L.; Qu, Y.; Ban, S. L.

    2015-07-01

    Based on the density matrix approach, the effects of ternary mixed crystal and size on intersubband optical absorption coefficients in InxGa1-xN/GaN core-shell nanowires (CSNWs) are investigated. The results show that the optical absorption can be modulated by In component x and the size of CSNWs, since the variation of electron states in these systems. It is found that photonic frequencies of resonant absorption and the absorption coefficient increase obviously when x increases or the radius of InGaN core reduces, while the half-width of the coefficient decreases as its peak becomes higher and sharper. A saturation phenomenon of optical absorption is also found when the incident light intensity exceeds a certain value. The theoretical results are expected to be helpful to develop CSNW optic devices.

  9. Aerosol Absorption Measurements in MILAGRO.

    NASA Astrophysics Data System (ADS)

    Gaffney, J. S.; Marley, N. A.; Arnott, W. P.; Paredes-Miranda, L.; Barnard, J. C.

    2007-12-01

    During the month of March 2006, a number of instruments were used to determine the absorption characteristics of aerosols found in the Mexico City Megacity and nearby Valley of Mexico. These measurements were taken as part of the Department of Energy's Megacity Aerosol Experiment - Mexico City (MAX-Mex) that was carried out in collaboration with the Megacity Interactions: Local and Global Research Observations (MILAGRO) campaign. MILAGRO was a joint effort between the DOE, NSF, NASA, and Mexican agencies aimed at understanding the impacts of a megacity on the urban and regional scale. A super-site was operated at the Instituto Mexicano de Petroleo in Mexico City (designated T-0) and at the Universidad Technologica de Tecamac (designated T-1) that was located about 35 km to the north east of the T-0 site in the State of Mexico. A third site was located at a private rancho in the State of Hidalgo approximately another 35 km to the northeast (designated T-2). Aerosol absorption measurements were taken in real time using a number of instruments at the T-0 and T-1 sites. These included a seven wavelength aethalometer, a multi-angle absorption photometer (MAAP), and a photo-acoustic spectrometer. Aerosol absorption was also derived from spectral radiometers including a multi-filter rotating band spectral radiometer (MFRSR). The results clearly indicate that there is significant aerosol absorption by the aerosols in the Mexico City megacity region. The absorption can lead to single scattering albedo reduction leading to values below 0.5 under some circumstances. The absorption is also found to deviate from that expected for a "well-behaved" soot anticipated from diesel engine emissions, i.e. from a simple 1/lambda wavelength dependence for absorption. Indeed, enhanced absorption is seen in the region of 300-450 nm in many cases, particularly in the afternoon periods indicating that secondary organic aerosols are contributing to the aerosol absorption. This is likely due

  10. Quantum efficiency coefficient for photogeneration of carriers in SbSI nanowires

    NASA Astrophysics Data System (ADS)

    Nowak, M.; Bober, Ł.; Borkowski, B.; Kępińska, M.; Szperlich, P.; Stróż, D.; Sozańska, M.

    2013-10-01

    This paper presents investigations of the quantum efficiency coefficient for the photogeneration of carriers in aligned antimony sulfoiodide (SbSI) nanowires. Therefore the spectral dependences (between 488 and 700 nm) of photoconductivity current (IPC) were measured for temperatures from 263 to 323 K and for different light intensities. The least squares method was applied to fit the experimental IPC data with appropriate theoretical dependence. From this fitting, diffusion length and surface recombination velocity of carriers as well as spectral dependences of quantum efficiency coefficients for different temperatures and different light intensities were obtained. A comparison of the values of absorption coefficient obtained from the measurements of optical diffusive reflectance and from evaluation of the quantum efficiency coefficient is presented.

  11. Determining the Gruneisen coefficient for liquids using the PAZ-scan technique

    NASA Astrophysics Data System (ADS)

    Dantiste, Olivier A.

    Measurement of Gruneisen coefficient is utterly important in developing efficient molecular photoacoustic (PA) contrast agents. It is one of the two parameters that describes how efficient a molecule is in transforming optical energy into sound, the other being absorption coefficient. Using the PAZ-scan technique, the Gruneisen coefficient was obtained for various samples and the values are compared with standard techniques. In a PAZ-scan, the sample is translated through the path of a focused laser beam in small steps while the generated PA signal is recorded. The incident intensity is optimum at the focal point and decreases gradually on either side of the focus. As such, the absorption and the PA signal varies according to the sample properties. Therefore at positions away from the focal point, the incident intensities are weak and the PA signal varies linearly with intensity. A plot of the PA signal versus the intensity is used to obtain the Gruneisen coefficient. Using this technique, the Gruneisen coefficients for crystal violet in two different solvents, food coloring dyes that are dissolved in water were determined. Results show that the linear part of the PAZ-scan can be used to determine the Gruneisen coefficient for liquids.

  12. Changes in scattering and absorption during curing of denta-resin composites: silorane and nanocomposite

    NASA Astrophysics Data System (ADS)

    del Mar Pérez, Maria; Ghinea, Razvan; Ionescu, Ana-Maria; de la Cruz Cardona, Juan

    2011-05-01

    Photocured polymers are widely used in dental applications. The optical properties of the dental composites change during curing; the appearance of the composites also changes. Recently, a new silorane-based composite resin and dental nanocomposite have been introduced. However, research regarding the effect of the silorane monomers or the size filler on appearance after curing of the resin composite is limited. This work aims to examine the optical properties of silorane-based composite and nanocomposite, in terms of scattering and absorption during curing. Six dimethacrylate-based dental resin composite (five universal and one nanocomposite) and one silorane-based dental resin composite (all shades A2 and T) were studied. The curing irradiance was 1100mW/cm2. The spectral reflectance of 1mm thick composite samples against white and black backgrounds were measured both before and after curing, and were converted to scattering and absorption coefficients using the Kubelka-Munk Theory. Both for pre and post-curing dental resin composites, the Albedo coefficient (K/S) shows that absorption prevails over the scattering for short wavelengths while for medium and large wavelengths, the scattering becomes more important, except for the T shade of the nanocomposite. After curing, the scattering and absorption values decreased for both types of materials. Changes in the absorption coefficient values should be caused by changes in the camphorquinone (CQ) absorption, whereas the scattering changes found should be directly attributable to index of refraction changes of the resin during curing.

  13. Absorption of a Massive Scalar Field by Wormhole Space-Times

    NASA Astrophysics Data System (ADS)

    Huang, Hai; Chen, Juhua; Wang, Yongjiu; Jin, Yao

    2017-04-01

    In this paper we consider the problem of the test massive scalar field propagating in the background of a class of wormhole space-times. Basing on the quantum scattering theory, we analyze the Schrödinger-type scalar wave equation and compute transmission coefficients for arbitrary coupling of the field to the background geometry with the WKB approximation. We numerically investigate its absorption cross section and analyze them in the high frequency regime. We find that the absorption cross section oscillates about the geometric optical value and the limit of absorption cross section is uniform in the high frequency regime.

  14. Absorption of a Massive Scalar Field by Wormhole Space-Times

    NASA Astrophysics Data System (ADS)

    Huang, Hai; Chen, Juhua; Wang, Yongjiu; Jin, Yao

    2017-01-01

    In this paper we consider the problem of the test massive scalar field propagating in the background of a class of wormhole space-times. Basing on the quantum scattering theory, we analyze the Schrödinger-type scalar wave equation and compute transmission coefficients for arbitrary coupling of the field to the background geometry with the WKB approximation. We numerically investigate its absorption cross section and analyze them in the high frequency regime. We find that the absorption cross section oscillates about the geometric optical value and the limit of absorption cross section is uniform in the high frequency regime.

  15. Comparison between the spectral diffuse attenuation coefficients and the IOP parameters

    NASA Astrophysics Data System (ADS)

    Mao, Zhihua; Zhou, Yan; Huang, Haiqing; Bai, Yan

    2009-01-01

    The spectral diffuse attenuation coefficients of downward irradiance (Kd) and upward radiance (Ku) are calculated from a profiler spectrometer measured data. Both Kd and Ku are the parameters of apparent optical properties (AOP) and need to be normalized according to the position of the Sun and sky conditions. Three kinds of sky indices are used to indicate the atmospheric conditions of clear, overcast and partly cloudy at the time of measurements. The values of normalized Kd can be compared with the sums of total absorption and backscattering coefficients. The total values from both measured data and the models fit the normalized Kd with the correlation coefficients of 0.85 and 0.81, respectively. The accuracy of Kd is also evaluated by the spectral root mean square error (RMSE) less than 0.15 m-1 in the spectral range from 450 to 700 nm.

  16. Transport coefficients of gluonic fluid

    SciTech Connect

    Das, Santosh K.; Alam, Jan-e

    2011-06-01

    The shear ({eta}) and bulk ({zeta}) viscous coefficients have been evaluated for a gluonic fluid. The elastic, gg{yields}gg and the inelastic, number nonconserving, gg{yields}ggg processes have been considered as the dominant perturbative processes in evaluating the viscous coefficients to entropy density (s) ratios. Recently the processes: gg{yields}ggg has been revisited and a correction to the widely used Gunion-Bertsch (GB) formula has been obtained. The {eta} and {zeta} have been evaluated for gluonic fluid with the formula recently derived. At large {alpha}{sub s} the value of {eta}/s approaches its lower bound, {approx}1/4{pi}.

  17. Temperature Dependent Rate Coefficients for the OH + Pinonaldehyde Reaction

    NASA Astrophysics Data System (ADS)

    Davis, M. E.; Talukdar, R.; Notte, G.; Ellison, G. B.; Ravishankara, A. R.; Burkholder, J. B.

    2005-12-01

    The biogenic emission of monoterpenes is an important source of volatile organic compounds (VOCs) to the atmosphere, approximately 10% of the biogenic hydrocarbons emitted yearly. The oxidation of alpha-pinene, the most abundant monoterpene in the atmosphere, by OH leads to the formation of pinonaldehyde (3-acetyl-2,2-dimethyl-cyclobutyl-ethanal) as a major oxidation product formed in yields > 50%. The atmospheric oxidation of pinonaldehyde will impact radical cycling, ozone formation and air quality on a regional scale. Previous laboratory studies of the OH + pinonaldehyde rate coefficient have used relative rate methods and were limited to room temperature. The reported rate coefficients are in poor agreement with values ranging from 4.0 to 9.1 × 10-11 cm#3 molecule-1 s-1. In this study we have measured absolute rate coefficients to resolve these discrepancies and have extended the measurements to include the temperature dependence. The rate coefficient for the gas phase reaction of OH with pinonaldehyde was measured over the temperature range 297 to 374 K and between 55 and 96 Torr under pseudo first order conditions in OH. Laser-induced fluorescence (LIF) was used to monitor the OH radical which was produced by pulsed laser photolysis. The pinonaldehyde concentration was determined in situ using Fourier transform infrared (FTIR) and UV (185 nm) absorption spectroscopy. The rate coefficient for the OH + pinonaldehyde reaction will be presented. Our results will be compared with previous rate coefficient measurements and the discrepancies and the atmospheric implications of these measurements will be discussed.

  18. Composition Dependence of the Hydrostatic Pressure Coefficients of the Bandgap of ZnSe(1-x)Te(x) Alloys

    NASA Technical Reports Server (NTRS)

    Wu, J.; Yu, K. M.; Walukiewicz, W.; Shan, W.; Ager, J. W., III; Haller, E. E.; Miotkowski, I.; Ramdas, A. K.; Su, Ching-Hua

    2003-01-01

    Optical absorption experiments have been performed using diamond anvil cells to measure the hydrostatic pressure dependence of the fundamental bandgap of ZnSe(sub 1-xTe(sub x) alloys over the entire composition range. The first and second-order pressure coefficients are obtained as a function of composition. Starting from the ZnSe side, the magnitude of both coefficients increases slowly until x approx. 0.7, where the ambient-pressure bandgap reaches a minimum. For larger values of x the coefficients rapidly approach the values of ZnTe. The large deviations of the pressure coefficients from the linear interpolation between ZnSe and ZnTe are explained in terms of the band anticrossing model.

  19. Subgap Absorption in Conjugated Polymers

    DOE R&D Accomplishments Database

    Sinclair, M.; Seager, C. H.; McBranch, D.; Heeger, A. J; Baker, G. L.

    1991-01-01

    Along with X{sup (3)}, the magnitude of the optical absorption in the transparent window below the principal absorption edge is an important parameter which will ultimately determine the utility of conjugated polymers in active integrated optical devices. With an absorptance sensitivity of < 10{sup {minus}5}, Photothermal Deflection Spectroscopy (PDS) is ideal for determining the absorption coefficients of thin films of transparent'' materials. We have used PDS to measure the optical absorption spectra of the conjugated polymers poly(1,4-phenylene-vinylene) (and derivitives) and polydiacetylene-4BCMU in the spectral region from 0.55 eV to 3 eV. Our spectra show that the shape of the absorption edge varies considerably from polymer to polymer, with polydiacetylene-4BCMU having the steepest absorption edge. The minimum absorption coefficients measured varied somewhat with sample age and quality, but were typically in the range 1 cm{sup {minus}1} to 10 cm{sup {minus}1}. In the region below 1 eV, overtones of C-H stretching modes were observed, indicating that further improvements in transparency in this spectral region might be achieved via deuteration of fluorination.

  20. Absorption degree analysis on biogas separation with ionic liquid systems.

    PubMed

    Zhang, Xin; Zhang, Suojiang; Bao, Di; Huang, Ying; Zhang, Xiangping

    2015-01-01

    For biogas upgrading, present work mainly focuses on either thermodynamics or mass transfer properties. A systematical study on these two aspects is important for developing a new biogas separation process. In this work, a new criterion "absorption degree", which combines both thermodynamics and mass transfer properties, was proposed for the first time to comprehensively evaluate the absorption performance. Henry's law constants of CO2 and CH4 in ionic liquids-polyethylene glycol dimethyl ethers mixtures were investigated. The liquid-side mass transfer coefficients (kL) were determined. The results indicate that IL-NHD mixtures exhibit not only a high CO2/CH4 selectivity, but also a fast kL for CO2 absorption. The [bmim][NO3]+NHD mixtures present a high absorption degree value for CO2 but a low value for CH4. For presenting a highest relative absorption degree value, the 50wt% [bmim][NO3]+50wt% NHD mixture is recommended for biogas upgrading.

  1. Orthogonality of spherical harmonic coefficients

    NASA Technical Reports Server (NTRS)

    Mcleod, M. G.

    1980-01-01

    Orthogonality relations are obtained for the spherical harmonic coefficients of functions defined on the surface of a sphere. Following a brief discussion of the orthogonality of Fourier series coefficients, consideration is given to the values averaged over all orientations of the coordinate system of the spherical harmonic coefficients of a function defined on the surface of a sphere that can be expressed in terms of Legendre polynomials for the special case where the function is the sum of two delta functions located at two different points on the sphere, and for the case of an essentially arbitrary function. It is noted that the orthogonality relations derived have found applications in statistical studies of the geomagnetic field.

  2. Absorptivity of water vapor for 10.6 micron radiation

    NASA Technical Reports Server (NTRS)

    Pugh, E. R.; Krech, R. H.

    1982-01-01

    Attention is called to recent measurements of the absorptivity of water vapor to 10.6-micron laser radiation made using shock-heated H2O/H2 and H2O/Ar mixtures and a probe CO2 laser. It is noted that these measurements give values about a factor of 2 lower than Ludwig's (1971) low resolution values. It is also argued that Fowler's (1981) high values are not likely to be caused by excited water molecules. It is shown that very intense laser radiation would be required to obtain any appreciable vibrational nonequilibrium. Within the narrow spectral range of 944-948/cm, no significant variation in absorption coefficient (suitably normalized) is observed as a function of laser line, water vapor concentration, total pressure, or diluent gas.

  3. On the sub-band gap optical absorption in heat treated cadmium sulphide thin film deposited on glass by chemical bath deposition technique

    SciTech Connect

    Chattopadhyay, P.; Karim, B.; Guha Roy, S.

    2013-12-28

    The sub-band gap optical absorption in chemical bath deposited cadmium sulphide thin films annealed at different temperatures has been critically analyzed with special reference to Urbach relation. It has been found that the absorption co-efficient of the material in the sub-band gap region is nearly constant up to a certain critical value of the photon energy. However, as the photon energy exceeds the critical value, the absorption coefficient increases exponentially indicating the dominance of Urbach rule. The absorption coefficients in the constant absorption region and the Urbach region have been found to be sensitive to annealing temperature. A critical examination of the temperature dependence of the absorption coefficient indicates two different kinds of optical transitions to be operative in the sub-band gap region. After a careful analyses of SEM images, energy dispersive x-ray spectra, and the dc current-voltage characteristics, we conclude that the absorption spectra in the sub-band gap domain is possibly associated with optical transition processes involving deep levels and the grain boundary states of the material.

  4. Effects of dielectric values of human body on specific absorption rate following 430, 800, and 1200 MHz RF exposure to ingestible wireless device.

    PubMed

    Xu, L S; Meng, Max Q-H; Hu, Chao

    2010-01-01

    In order to assess the compliance of ingestible wireless device (IWD) within safety guidelines, the SAR, and near fields of IWD in two realistic human body models, whose dielectric values are increased from the original by +/-10% and +/- 20% are studied using the finite-difference time-domain method. The radiation characteristics of the IWD in the human body models with changed and unchanged dielectric values are compared. Simulations are carried out at 13 scenarios where the IWD is placed at center positions of abdomens in the two models at the operation frequency of 430, 800, and 1200 MHz, respectively. Results show that variation of radiation intensity near the surface of abdomen is around 2.5, 2.6, and 3.5 dB within 20% variation of dielectric values corresponding to the frequency of 430, 800, and 1200 MHz, respectively. Electric fields in the anterior of the human body models are higher than those in the posterior for all scenarios. SAR values increase with the increase of conductivities of human body tissues, and usually decrease with the increase of relative permittivities of human body tissues. The effect of the dielectric values of human body on SAR is orientation-, human-body-, and frequency-dependent. A variation up to 20% in conductivities and relative permittivities alone or simultaneously always causes a SAR variation less than 10%, 20%, and 30% at the frequency of 430, 800, and 1200 MHz, respectively. As far as the compliance of safety was concerned, the IWD was safe to be used at the input power less than 12.6, 9.3, and 8.4 mW, according to the IEEE safety standards at the frequency of 430, 800, and 1200 MHz, respectively.

  5. Computed survey spectra of 2-5 micron atmospheric absorption

    NASA Astrophysics Data System (ADS)

    Leslie, D. H.; Lebow, P. S.

    1983-08-01

    Computed high resolution survey spectra of atmospheric absorption coefficient vs wavenumber are presented covering the wavelength region 2-5 micrometers. The 1980 AFGL atmospheric absorption parameter compilation was employed with a mid-latitude, sea-level atmospheric model.

  6. Modified Biserial Correlation Coefficients.

    ERIC Educational Resources Information Center

    Kraemer, Helena Chmura

    1981-01-01

    Asymptotic distribution theory of Brogden's form of biserial correlation coefficient is derived and large sample estimates of its standard error obtained. Its relative efficiency to the biserial correlation coefficient is examined. Recommendations for choice of estimator of biserial correlation are presented. (Author/JKS)

  7. Absorption and scattering of light by VO2 nanoparticle array

    NASA Astrophysics Data System (ADS)

    Yu, Xiaojing; Li, Yi; Wang, Haifang; Zhang, Hu; Zhang, Wei; Huang, Yize

    2009-07-01

    Much attention has been paid to the semiconductor-metal phase transition in vanadium dioxide nanomaterials, accompanied with an abrupt change in its resistivity and near-infrared transmission. The phase transition and optical properties of vanadium dioxide nanoparticles were studied by the mathematical model based on the complex refractive changing with the temperature and wavelength. The optical properties of nano-array were investigated by using the discrete dipole approximation and Mie scattering theory, as well as the absorption and scattering properties of small particles. The results show that the main contribution to the optical response with variational wavelength in the infrared is from absorption cross section comparing with the scattering cross section. It is obvious that the absorption peak of metal phase occurs near 980nm. With the change of temperature, the variation of extinction coefficient is larger in the infrared region than in the visible region. The largest change of extinction coefficient occurs in the near-infrared region. The extincition coefficient is very small in the visible region and there is a maximal value in the infrared region in the nano-array.

  8. Triplet extinction coefficients of some laser dyes. II. Interim technical report

    SciTech Connect

    Pavlopoulos, T.G.; Golich, D.J.

    1989-04-19

    The authors measured the triplet extinction coefficients T over the laser action spectral region of DODC, DMC, Sulforhodamine B, Rhodamine 575, Coumarin 523, Coumarine 521 Coumarin 504, Coumarin 498, Coumarin 490, LD466, bis-MSB, BBO, and OLIG0415. The different lines from an argon- and a krypton-ion cw laser were employed for excitation. McClure's method was again employed to measure the triplet extinction coefficients. The authors provide a simplified derivation of McClure's equation. The triplet extinction coefficient of Rhodamine 575 was also measured by using the depletion method and improving it by reconstructing for true triplet-triplet absorption. The value obtained is in good agreement with the one obtained by McClure's method.

  9. Measurements of H2O-broadening coefficients of O2 A-band lines

    NASA Astrophysics Data System (ADS)

    Delahaye, T.; Landsheere, X.; Pangui, E.; Huet, F.; Hartmann, J.-M.; Tran, H.

    2016-11-01

    We report laboratory measurements of H2O-broadening coefficients of O2 absorption lines in the A-band near 13,000 cm-1. For this, four spectra of oxygen gas mixed with water vapor were recorded with a high resolution Fourier transform spectrometer for total pressures ranging from 125 to 175 Torr at 323 K, and a fifth at 175 Torr and 365 K. Broadening coefficients of 39 transitions (up to J″ = 21) were retrieved from the measured spectra through fits using Galatry line profiles. Values at room temperature (296 K) were then extrapolated and compared with previous determinations in the A-band and millimeter waves region. This enables to resolve some controversial issues related to the inconsistencies between these studies. Finally, comparing our results with the line broadening coefficients by dry air confirms that H2O-broadenings of oxygen lines are, on average, 10% larger than those by dry air.

  10. Near-infrared absorptions of monomethylhydrazine

    NASA Technical Reports Server (NTRS)

    Murray, Mark; Kurtz, Joe

    1993-01-01

    The peak absorption coefficients for two near-infrared absorptions of monomethylhydrazine, CH3-N2H3, (MMH) were measured. Absorption bands located at 1.524 micrometers (6560/cm), 1.557 micrometers (6423/cm), and 1.583 micrometers (6316/cm) are assigned to the Delta upsilon = 2 overtones of the infared N-H stretching fundamentals at 3317, 3245 and 3177/cm. An absorption band located at 1.04 micrometers (9620 +/- 100/cm) is assigned to the Delta upsilon = 3 overtone of one of these fundamentals. The peak absorption coefficients (alpha(sub 10)) at 1.524 micrometers (6560 +/- 20/cm) and 1.04 micrometers (9620 +/- 100/cm) are 31 x 10(exp -3) and 0.97 x 10(exp -3)/(cm atm), respectively. Uncertainties in these coefficients were estimated to be less than +/- 20% due primarily to uncertainties in the partial vapor pressure of MMH.

  11. Enhancing the absorption properties of acoustic porous plates by periodically embedding Helmholtz resonators.

    PubMed

    Groby, J-P; Lagarrigue, C; Brouard, B; Dazel, O; Tournat, V; Nennig, B

    2015-01-01

    This paper studies the acoustical properties of hard-backed porous layers with periodically embedded air filled Helmholtz resonators. It is demonstrated that some enhancements in the acoustic absorption coefficient can be achieved in the viscous and inertial regimes at wavelengths much larger than the layer thickness. This enhancement is attributed to the excitation of two specific modes: Helmholtz resonance in the viscous regime and a trapped mode in the inertial regime. The enhancement in the absorption that is attributed to the Helmholtz resonance can be further improved when a small amount of porous material is removed from the resonator necks. In this way the frequency range in which these porous materials exhibit high values of the absorption coefficient can be extended by using Helmholtz resonators with a range of carefully tuned neck lengths.

  12. Total and Partial Absorption Coefficients for a Nitrogen Plasma

    DTIC Science & Technology

    2014-09-26

    Boulder, CO 80309 ATTN: Dr. Arthur V. Phelps 43 0 - . .. > . v- . - . -, . . " )h A’ I , U’ C ’ -- o. • p Lawrence Berkeley Laboratory University of...Gerald N. Hays Dr. James Chang Dr. Michael G. Mazerakis RiJ University of California Physics Department Irvine, CA 92664 -ATTN: Dr. Gregory Benford Air

  13. Correlation coefficient mapping in fluorescence spectroscopy: tissue classification for cancer detection.

    PubMed

    Crowell, Ed; Wang, Gufeng; Cox, Jason; Platz, Charles P; Geng, Lei

    2005-03-01

    Correlation coefficient mapping has been applied to intrinsic fluorescence spectra of colonic tissue for the purpose of cancer diagnosis. Fluorescence emission spectra were collected of 57 colonic tissue sites in a range of 4 physiological conditions: normal (29), hyperplastic (2), adenomatous (5), and cancerous tissues (21). The sample-sample correlation was used to examine the ability of correlation coefficient mapping to determine tissue disease state. The correlation coefficient map indicates two main categories of samples. These categories were found to relate to disease states of the tissue. Sensitivity, selectivity, predictive value positive, and predictive value negative for differentiation between normal tissue and all other categories were all above 92%. This was found to be similar to, or higher than, tissue classification using existing methods of data reduction. Wavelength-wavelength correlation among the samples highlights areas of importance for tissue classification. The two-dimensional correlation map reveals absorption by NADH and hemoglobin in the samples as negative correlation, an effect not obvious from the one-dimensional fluorescence spectra alone. The integrity of tissue was examined in a time series of spectra of a single tissue sample taken after tissue resection. The wavelength-wavelength correlation coefficient map shows the areas of significance for each fluorophore and their relation to each other. NADH displays negative correlation to collagen and FAD, from the absorption of emission or fluorescence resonance energy transfer. The wavelength-wavelength correlation map for the decay set also clearly shows that there are only three fluorophores of importance in the samples, by the well-defined pattern of the map. The sample-sample correlation coefficient map reveals the changes over time and their impact on tissue classification. Correlation coefficient mapping proves to be an effective method for sample classification and cancer

  14. Absorption of CO laser radiation by NO

    NASA Technical Reports Server (NTRS)

    Hanson, R. K.; Monat, J. P.; Kruger, C. H.

    1976-01-01

    The paper describes absorption calculations and measurements at selected infrared CO laser wavelengths which are nearly coincident with absorption lines in the fundamental vibration-rotation band of NO near 5.3 microns. Initial work was directed towards establishing the optimal CO laser-NO absorption line coincidence for high temperature applications. Measurements of the absorption coefficient at this optimal laser wavelength were carried out, first using a room-temperature absorption cell for high-temperature calculations and then using a shock tube, for the temperature range 630-4000 K, to validate the high temperature calculations.

  15. Scattering and Absorption Properties of Biomaterials for Dental Restorative Applications

    NASA Astrophysics Data System (ADS)

    Fernandez-Oliveras, A.; Rubiño, M.; Pérez, M. M.

    2013-08-01

    The physical understanding of the optical properties of dental biomaterials is mandatory for their final success in restorative applications.Light propagation in biological media is characterized by the absorption coefficient, the scattering coefficient, the scattering phase function,the refractive index, and the surface conditions (roughness). We have employed the inverse adding-doubling (IAD) method to combine transmittance and reflectance measurements performed using an integrating-sphere setup with the results of the previous scattering-anisotropygoniometric measurements. This has led to the determination of the absorption and the scattering coefficients. The aim was to optically characterize two different dental-resin composites (nanocomposite and hybrid) and one type of zirconia ceramic, and comparatively study them. The experimental procedure was conducted under repeatability conditions of measurement in order to determine the uncertainty associated to the optical properties of the biomaterials. Spectral variations of the refraction index and the scattering anisotropy factor were also considered. The whole experimental procedure fulfilled all the necessary requirements to provide optical-property values with lower associated uncertainties. The effective transport coefficient presented a similar spectral behavior for the two composites but completely different for the zirconia ceramic. The results demonstrated that the scattering anisotropy exerted a clearly distinct impact on the optical properties of the zirconia ceramic compared with those of the dental-resin composites.

  16. Coefficients of Effective Length.

    ERIC Educational Resources Information Center

    Edwards, Roger H.

    1981-01-01

    Under certain conditions, a validity Coefficient of Effective Length (CEL) can produce highly misleading results. A modified coefficent is suggested for use when empirical studies indicate that underlying assumptions have been violated. (Author/BW)

  17. PERITONEAL ABSORPTION

    PubMed Central

    Hahn, P. F.; Miller, L. L.; Robscheit-Robbins, F. S.; Bale, W. F.; Whipple, G. H.

    1944-01-01

    The absorption of red cells from the normal peritoneum of the dog can be demonstrated by means of red cells labeled with radio-iron incorporated in the hemoglobin of these red cells. Absorption in normal dogs runs from 20 to 100 per cent of the amount given within 24 hours. Dogs rendered anemic by bleeding absorb red cells a little less rapidly—ranging from 5 to 80 per cent of the injected red cells. Doubly depleted dogs (anemic and hypoproteinemic) absorb even less in the three experiments recorded. This peritoneal absorption varies widely in different dogs and even in the same dog at different times. We do not know the factors responsible for these variations but there is no question about active peritoneal absorption. The intact red cells pass readily from the peritoneal cavity into lymph spaces in diaphragm and other areas of the peritoneum. The red cells move along the lymphatics and through the lymph glands with little or no phagocytosis and eventually into the large veins through the thoracic ducts. PMID:19871404

  18. Nutrient absorption.

    PubMed

    Rubin, Deborah C

    2004-03-01

    Our understanding of nutrient absorption continues to grow, from the development of unique animal models and from studies in which cutting-edge molecular and cellular biologic approaches have been used to analyze the structure and function of relevant molecules. Studies of the molecular genetics of inherited disorders have also provided many new insights into these processes. A major advance in lipid absorption has been the cloning and characterization of several intestinal acyl CoA:monoacylglycerol acyltransferases; these may provide new targets for antiobesity drug therapy. Studies of intestinal cholesterol absorption and reverse cholesterol transport have encouraged the development of novel potential treatments for hyperlipidemia. Observations in genetically modified mice and in humans with mutations in glucose transporter 2 suggest the importance of a separate microsomal membrane transport pathway for glucose transport. The study of iron metabolism has advanced greatly with the identification of the hemochromatosis gene and the continued examination of the genetic regulation of iron absorptive pathways. Several human thiamine transporters have been identified, and their specific roles in different tissues are being explored.

  19. Studying the vertical aerosol extinction coefficient by comparing in situ airborne data and elastic backscatter lidar

    NASA Astrophysics Data System (ADS)

    Rosati, Bernadette; Herrmann, Erik; Bucci, Silvia; Fierli, Federico; Cairo, Francesco; Gysel, Martin; Tillmann, Ralf; Größ, Johannes; Gobbi, Gian Paolo; Di Liberto, Luca; Di Donfrancesco, Guido; Wiedensohler, Alfred; Weingartner, Ernest; Virtanen, Annele; Mentel, Thomas F.; Baltensperger, Urs

    2016-04-01

    Vertical profiles of aerosol particle optical properties were explored in a case study near the San Pietro Capofiume (SPC) ground station during the PEGASOS Po Valley campaign in the summer of 2012. A Zeppelin NT airship was employed to investigate the effect of the dynamics of the planetary boundary layer at altitudes between ˜ 50 and 800 m above ground. Determined properties included the aerosol particle size distribution, the hygroscopic growth factor, the effective index of refraction and the light absorption coefficient. The first three parameters were used to retrieve the light scattering coefficient. Simultaneously, direct measurements of both the scattering and absorption coefficient were carried out at the SPC ground station. Additionally, a single wavelength polarization diversity elastic lidar system provided estimates of aerosol extinction coefficients using the Klett method to accomplish the inversion of the signal, for a vertically resolved comparison between in situ and remote-sensing results. Note, however, that the comparison was for the most part done in the altitude range where the overlap function is incomplete and accordingly uncertainties are larger. First, the airborne results at low altitudes were validated with the ground measurements. Agreement within approximately ±25 and ±20 % was found for the dry scattering and absorption coefficient, respectively. The single scattering albedo, ranged between 0.83 and 0.95, indicating the importance of the absorbing particles in the Po Valley region. A clear layering of the atmosphere was observed during the beginning of the flight (until ˜ 10:00 LT - local time) before the mixing layer (ML) was fully developed. Highest extinction coefficients were found at low altitudes, in the new ML, while values in the residual layer, which could be probed at the beginning of the flight at elevated altitudes, were lower. At the end of the flight (after ˜ 12:00 LT) the ML was fully developed, resulting in

  20. [Phytoplankton Light Absorption Properties During the Blooms in Adjacent Waters of the Changjiang Estuary].

    PubMed

    Liu, Yang-yang; Shen, Fang; Li, Xiu-zhen

    2015-06-01

    Phytoplankton dominant species and their light absorption properties during the blooms occurred in August 2013 in adjacent waters of the Changjiang Estuary were analyzed. The results showed that phytoplankton blooms broke out in 10 out of 34 investigation stations, among which diatom blooms occurred in 6 stations while 3 stations were predominated by dinoflagellate. Phytoplankton absorption coefficients of both bloom and non-bloom waters exhibited large variations, with respective ranges of 0.199-0.832 m(-1) and 0.012-0.109 m(-1), while phytoplankton specific absorption coefficients spanned much narrower range, with the average values of bloom and non-bloom waters being 0.023 and 0.035 m2 x mg(-1), respectively. When transitioned from bloom to non-bloom waters, the proportion of phytoplankton with larger cell size lowered while that of smaller phytoplankton elevated, causing a less extent of package effect and thus higher specific absorption coefficients. Distinctive absorption spectra were observed between different types of bloom (such as diatom and dinoflagellate blooms) with similar phytoplankton cell size, mostly attributed to distinctive accessory pigment composition. The ratios of diadinoxanthin and chlorophyll-c2 concentrations to chlorophyll-a concentration in dinoflagellate blooms were higher than those in diatom blooms, which largely contributed to the shoulder peaks at 465 nm in dinoflagellate blooms.

  1. Spatial variability of absorption properties in Lake Balaton, Hungary

    NASA Astrophysics Data System (ADS)

    Riddick, C. A.; Hunter, P. D.; Tyler, A. N.; Vicente, V. M.; Groom, S.; Horváth, H.; Kovacs, A.; Preston, T.; Presing, M.

    2013-12-01

    In order to improve robustness of current remote sensing algorithms for lake monitoring, it is vital to understand the variability of inherent optical properties (IOPs) within a lake. In this study, absorption coefficients were measured in situ at 38 stations in Lake Balaton, Hungary, using a WET Labs AC-S and AC-9 and compared to concurrent absorption measurements by dual beam spectrophotometry in the laboratory. The spatial variability of bulk and chlorophyll-specific absorption coefficients was examined across 5 basins, demonstrating a gradient in total absorption corresponding to the trophic gradient. Our data suggests that sampling conditions had an impact on particulate absorption, affecting the proportion attributed to non-algal particles (aNAP), phytoplankton (aph) or color dissolved organic matter (aCDOM). The specific absorption of phytoplankton (a*ph) spectra showed a distinct peak in the UV portion of the spectra in Basins 3 and 4 (east), which may be due to the presence of phytoplankton photoprotective pigments to compensate for lower CDOM levels in these basins. In contrast to oceans, particulate attenuation (cp) had a weaker relationship to chlorophyll-a (R2=0.15) than to total suspended matter (R2=0.84), particularly the inorganic fraction. Additionally, the relative contribution of particulate scattering (bp) to attenuation was significantly higher in Lake Balaton (up to 85-99%) than that found in previous lacustrine studies. bp also demonstrated a gradient across the lake, where values increased as the water progressed from phytoplankton-dominated to mineral-dominated. These results provide knowledge of the heterogeneity of the IOPs within Lake Balaton, which is to be considered for the future improvement of bio-optical algorithms for constituent retrieval in inland waters.

  2. The molecular basis of ultrasonic absorption by proteins

    SciTech Connect

    Edmonds, P.D.

    1982-01-01

    This article reviews significant advances in understanding the basis for the magnitude of ultrasonic absorption in proteins and related biological materials. Carstensen and Schwan's accurate and extensive measurements on blood and hemoglobin solutions provided the initial experimental data; these were augmented by data from measurements on aqueous solutions of gelatin, bovine serum albumin, lysozyme, various polypeptides, and amino acids. The initial frequency range of 1-10 MHz was expanded to 0.035-1000 MHz; temperature and pH dependences of absorption were studied. Theoretical approaches included consideration of the relative motion of blood cells in plasma, perturbation of water structure around macromolecules, solvation of charged entities, proton-transfer reactions, and helix-coil transitions. Proton-transfer reactions between amino and carboxylic groups and water proved to be largely responsible for the observed peaks in pH dependence of absorption coefficient; the peaks occurred in the basic and acidic regions corresponding to the pKs for titration of these groups. Such reactions could not account for the magnitude of absorption at physiological pH because only histidine titrated in this range. Extensive analysis, using relaxation theory, and measurements have shown that the proton transfer reaction between the imidazole group of histidine and hydrogen phosphate ion (in solution) provides sufficient volume change for significant ultrasonic absorption at physiological pH. Excellent agreement between theory and experiment was found with the peptide bacitracin in phosphate buffer solutions. By generalizing these results to the case of a protein, Slutsky wt al estimated maximum values of frequency-dependent absorption coefficients for typical tissue and found them to be correct to order of magnitude.

  3. Temperature dependence of the radiative recombination coefficient in crystalline silicon from spectral photoluminescence

    SciTech Connect

    Nguyen, Hieu T. Macdonald, Daniel; Baker-Finch, Simeon C.

    2014-03-17

    The radiative recombination coefficient B(T) in crystalline silicon is determined for the temperature range 90–363 K, and in particular from 270 to 350 K with an interval of 10 K, where only sparse data are available at present. The band-band absorption coefficient established recently by Nguyen et al. [J. Appl. Phys. 115, 043710 (2014)] via photoluminescence spectrum measurements is employed to compute the values of B(T) at various temperatures. The results agree very well with literature data from Trupke et al. [J. Appl. Phys. 94, 4930 (2003).] We present a polynomial parameterization describing the temperature dependence of the product of B(T) and the square of the intrinsic carrier density. We also find that B(T) saturates at a near constant value at room temperature and above for silicon samples with relatively low free carrier densities.

  4. Correlation of solar energetic protons and polar cap absorption

    NASA Astrophysics Data System (ADS)

    Patterson, J. D.; Armstrong, T. P.; Laird, C. M.; Detrick, D. L.; Weatherwax, A. T.

    2001-01-01

    This study shows the results of a model of polar cap absorption events (PCAs) using solar energetic proton flux as an input. The proton data are recorded by the Charged Particle Measurement Experiment (CPME) on board the IMP 8 satellite and are collected by the Applied Physics Laboratory at Johns Hopkins University. The IMP 8 satellite orbits the Earth at distances between 30 and 35 Earth radii, which places it in the solar energetic particle environment throughout most of its orbit. It has been shown in previous studies that these solar energetic particles have direct and immediate access to the polar atmosphere [Reid, 1970]. Our model shows that the majority of the ionization resulting from the influx of solar energetic protons occurs in the altitude range from ~50-90 km. Excess ionization at these altitudes causes enhanced absorption of cosmic HF radio waves. The levels of absorption used for comparison in this study were measured directly by the riometer at South Pole station, Antarctica. The results show a very strong correlation between the incident proton flux and measured path-integrated cosmic HF radio noise absorption for significant events, involving absorptions greater than 1.0 dB. For absorption levels lower than this it is obvious that other phenomena dominate. For HF radio waves the primary contributors to PCA are protons with energies near 20 MeV. This study extends the correlated observations of interplanetary particles and PCA throughout a 9-year period. The close quantitative agreement between the measured and calculated values of absorption supports the validity of the assumptions and suppositions made by this model. The data also suggest a method by which the path-integrated cosmic noise absorption may be used to probe the E and D layers of the ionosphere to determine the effective ion-electron recombination coefficients within these regions.

  5. Seasonal and spatial variability of phytoplankton and non-algal absorption in the surface layer of the Baltic

    NASA Astrophysics Data System (ADS)

    Meler, Justyna; Ostrowska, Mirosława; Stoń-Egiert, Joanna

    2016-10-01

    The paper addresses the seasonal variability of coefficients of light absorption by suspended particulate matter ap(λ) in different regions of the Baltic Sea: open-sea waters, coastal waters, the Gulf of Gdańsk, the Pomeranian Bay and river mouths. We analysed 865 spectra of light absorption by phytoplankton aph(λ) and non-algal particles aNAP(λ) in different seasons during 35 cruises of r/v Oceania in the southern Baltic from 2006 to 2012. Depending on season and region, we found distinct differences in the absorption properties of particles suspended in the water with respect both to the spectral shapes of the coefficients ap(λ), aph(λ) and aNAP(λ), and to the values at the characteristic wavelength of 440 nm. The proportions of phytoplankton governing the absorption properties of the suspended matter varied from 50 to 75%, whereby the greatest spread of these proportions was found in open waters. In contrast, the greatest seasonal variability in the overall absorption coefficients ap occurred in coastal waters. The absolute values of coefficients aph(λ) and aNAP(λ) at wavelength 440 nm in the different types of water and seasons varied respectively over three and four orders of magnitude. In river mouth waters the mean values of aph(440) were nearly twelve times and aNAP(440) over twenty times greater than in open sea waters. The absorption properties of non-algal particles exhibited a greater regional than seasonal variability, achieving the lowest values in open and coastal waters (0.006-0.31 m-1), and the highest ones in river mouths (0.199-4.196 m-1).

  6. Contribution of particulate brown carbon to light absorption in the rural and urban Southeast US

    NASA Astrophysics Data System (ADS)

    Devi, J. Jai; Bergin, Michael H.; Mckenzie, Michael; Schauer, James J.; Weber, Rodney J.

    2016-07-01

    Measurements of wavelength dependent aerosol light absorption coefficients were carried out as part of the Southern Oxidant and Aerosol Study (SOAS) during the summer of 2013 to determine the contribution of light absorbing organic carbon (BrC) to total aerosol light absorption in a rural location (Centreville, AL) and an urban area (Atlanta, GA). The light absorption coefficients in the near UV and visible wavelengths were measured for both ambient air, as well as ambient air heated in a thermal denuder to 200 °C to remove the semi-volatile organic compounds. Atlanta measurements show dominance of semi-volatile brown carbon with an average absorption angstrom exponent (AAE) of 1.4 before heating and about 1.0 after heating. In urban Atlanta, a decrease of about ∼35% in the light absorption coefficient at 370 nm after heating indicates that light absorbing organic compounds are a substantial fraction of the light absorption budget. Furthermore, a considerable increase in the fraction of light absorption by the semi-volatile aerosol occurs during the daytime, likely linked with photochemistry. Measurements at rural Centerville, on the other hand, do not show any major change in AAE with values before and after heating of 0.99 and 0.98, respectively. Overall the results suggest that photochemical aged urban emissions result in the presence of light absorbing BrC, while at rural locations which are dominated by aged aerosol and local biogenic emissions (based on measurements of Angstrom exponents) BrC does not significantly contribute to light absorption.

  7. Determination of optical coefficients and fractal dimensional parameters of cancerous and normal prostate tissues.

    PubMed

    Pu, Yang; Wang, Wubao; Al-Rubaiee, Mohammad; Gayen, Swapan Kumar; Xu, Min

    2012-07-01

    Optical extinction and diffuse reflection spectra of cancerous and normal prostate tissues in the 750 to 860 nm spectral range were measured. Optical extinction measurements using thin ex vivo prostate tissue samples were used to determine the scattering coefficient (μ(s)), while diffuse reflection measurements using thick prostate tissue samples were used to extract the absorption coefficient (μ(a)) and the reduced scattering coefficient (μ'(s)). The anisotropy factor (g) was obtained using the extracted values of μ(s) and μ'(s). The values of fractal dimension (D(f)) of cancerous and normal prostate tissues were obtained by fitting to the wavelength dependence of μ'(s). The number of scattering particles contributing to μ(s) as a function of particle size and the cutoff diameter d(max) as a function of g were investigated using the fractal soft tissue model and Mie theory. Results show that d(max) of the normal tissue is larger than that of the cancerous tissue. The cutoff diameter d(max) is observed to agree with the nuclear size for the normal tissues and the nucleolar size for the cancerous tissues. Transmission spectral polarization imaging measurements were performed that could distinguish the cancerous prostate tissue samples from the normal tissue samples based on the differences between their absorption and scattering parameters.

  8. On the significant enhancement of the continuum-collision induced absorption in H2O+CO2 mixtures

    NASA Astrophysics Data System (ADS)

    Baranov, Yu. I.

    2016-05-01

    The IR spectra of water vapor-carbon dioxide mixtures as well as the spectra of pure gas samples have been recorded using a Fourier-transform infrared spectrometer at a resolution of 0.1 cm-1 in order to explore the effect of colliding CO2 and H2O molecules on their continuum absorptions. The sample temperatures were 294, 311, 325 and 339 K. Measurements have been conducted at several different water vapor partial pressures depending on the cell temperature. Carbon dioxide pressures were kept close to the three values of 103, 207 and 311 kPa (1.02, 2.04 and 3.07 atm). The path length used in the study was 100 m. It was established that, in the region around 1100 cm-1, the continuum absorption coefficient C H2 O + CO2 is about 20 times stronger than the water-nitrogen continuum absorption coefficient CH2O+N2. On the other hand, in the far wing region (2500 cm-1) of the ν3 CO2 fundamental band, the binary absorption coefficient CCO2+H2O appears to be about one order of magnitude stronger than the absorption coefficient CCO2+CO2 in pure carbon dioxide. The continuum interpretation and the main problem of molecular band shape formation are discussed in light of these experimental facts.

  9. Comparison of experimental and modeled absorption enhancement by black carbon (BC) cored polydisperse aerosols under hygroscopic conditions.

    PubMed

    Shamjad, P M; Tripathi, S N; Aggarwal, S G; Mishra, S K; Joshi, Manish; Khan, Arshad; Sapra, B K; Ram, Kirpa

    2012-08-07

    The quantification of the radiative impacts of light absorbing ambient black carbon (BC) particles strongly depends on accurate measurements of BC mass concentration and absorption coefficient (β(abs)). In this study, an experiment has been conducted to quantify the influence of hygroscopic growth of ambient particles on light absorption. Using the hygroscopic growth factor (i.e., Zdanovskii-Stokes-Robinson (ZSR) approach), a model has been developed to predict the chemical composition of particles based on measurements, and the absorption and scattering coefficients are derived using a core-shell assumption with light extinction estimates based on Mie theory. The estimated optical properties agree within 7% for absorption coefficient and 30% for scattering coefficient with that of measured values. The enhancement of absorption is found to vary according to the thickness of the shell and BC mass, with a maximum of 2.3 for a shell thickness of 18 nm for the particles. The findings of this study underline the importance of considering aerosol-mixing states while calculating their radiative forcing.

  10. Reduction of VOC emissions by a membrane-based gas absorption process.

    PubMed

    Li, Rui; Xu, Jun; Wang, Lianjun; Li, Jiansheng; Sun, Xiuyun

    2009-01-01

    A membrane-based gas absorption (MGA) process was evaluated for the removal of volatile organic compounds (VOCs) based on C6H6/N2 mixture. The absorption of C6H6 from a C6H6/N2 mixture was investigated using a hydrophobic polypropylene hollow fiber membrane contactor and the aqueous solution of N-formyl morpholine (NFM) as absorbent. The effects of various factors on the overall mass transfer coefficient was investigated. The experimental results showed that the removal efficiency of C6H6 could reach 99.5% in present studied system. A mathematical model based on resistance-in-series concept was presented to predict the value of overall mass transfer coefficient. The average error between the predicted and experimental values is 7.9%. In addition, conventional packed columns for VOCs removal was also evaluated for comparison.

  11. Measuring Seebeck Coefficient

    NASA Technical Reports Server (NTRS)

    Snyder, G. Jeffrey (Inventor)

    2015-01-01

    A high temperature Seebeck coefficient measurement apparatus and method with various features to minimize typical sources of errors is described. Common sources of temperature and voltage measurement errors which may impact accurate measurement are identified and reduced. Applying the identified principles, a high temperature Seebeck measurement apparatus and method employing a uniaxial, four-point geometry is described to operate from room temperature up to 1300K. These techniques for non-destructive Seebeck coefficient measurements are simple to operate, and are suitable for bulk samples with a broad range of physical types and shapes.

  12. JKTLD: Limb darkening coefficients

    NASA Astrophysics Data System (ADS)

    Southworth, John

    2015-11-01

    JKTLD outputs theoretically-calculated limb darkening (LD) strengths for equations (LD laws) which predict the amount of LD as a function of the part of the star being observed. The coefficients of these laws are obtained by bilinear interpolation (in effective temperature and surface gravity) in published tables of coefficients calculated from stellar model atmospheres by several researchers. Many observations of stars require the strength of limb darkening (LD) to be estimated, which can be done using theoretical models of stellar atmospheres; JKTLD can help in these circumstances.

  13. Absorption properties of type-II InAs/InAsSb superlattices measured by spectroscopic ellipsometry

    SciTech Connect

    Webster, P. T.; Riordan, N. A.; Liu, S.; Zhang, Y.-H.; Johnson, S. R.; Steenbergen, E. H.

    2015-02-09

    Strain-balanced InAs/InAsSb superlattices offer access to the mid- to long-wavelength infrared region with what is essentially a ternary material system at the GaSb lattice constant. The absorption coefficients of InAs/InAsSb superlattices grown by molecular beam epitaxy on (100)-oriented GaSb substrates are measured at room temperature over the 30 to 800 meV photon energy range using spectroscopic ellipsometry, and the miniband structure of each superlattice is calculated using a Kronig-Penney model. The InAs/InAsSb conduction band offset is used as a fitting parameter to align the calculated superlattice ground state transition energy to the measured absorption onset at room temperature and to the photoluminescence peak energy at low temperature. It is observed that the ground state absorption coefficient and transition strength are proportional to the square of the wavefunction overlap and the ground state absorption coefficient approaches a maximum value of around 5780 cm{sup −1} as the wavefunction overlap approaches 100%. The absorption analysis of these samples indicates that the optical joint density of states is weakly dependent on the period thickness and Sb content of the superlattice, and that wavefunction overlap is the principal design parameter in terms of obtaining strong absorption in these structures.

  14. Percutaneous absorption of several chemicals, some pesticides included, in the red-winged blackbird

    USGS Publications Warehouse

    Rogers, J.G.; Cagan, R.H.; Kare, M.R.

    1974-01-01

    Percutaneous absorption in vivo through the skin of the feet of the red-winged blackbird (Agelaius phoeniceus) has been investigated. Absorption after 18-24 hours exposure to 0.01 M solutions of salicylic acid, caffeine, urea, 2,4-D, dieldrin, diethylstilbesterol, and DDT was measured. Of these, only DDT and diethylstilbesterol were not absorbed to a measurable degree. The solvents ethanol, dimethylsulfoxide (DMSO), and vegetable oil were compared with water in their effects on the absorption ofcaffeine, urea, and salicylic acid. Ethanol, DMSO,and oil each decreased percutaneous absorption of salicylic acid. DMSO increased absorption of caffeine, and ethanol had no effect on it. Neither DMSO nor ethanol affected penetration of urea. Partition coefficients (K) (epidermis/water) were determined for all seven penetrants. Compounds with higher values of K showed lower percutaneous absorption. These findings suggest that K may be useful to predict percutaneous absorption in vivo. It appears unlikely that percutaneous absorption contributes greatly to the body burden of 2,4-D and dieldrin in A. phoeniceus.

  15. Pseudopotential calculations and photothermal lensing measurements of two-photon absorption in solids

    SciTech Connect

    White, W.T. III

    1985-11-04

    We have studied two-photon absorption in solids theoretically and experimentally. We have shown that it is possible to use accurate band structure techniques to compute two-photon absorption spectra within 15% of measured values in a wide band-gap material, ZnS. The empirical pseudopotential technique that we used is significantly more accurate than previous models of two-photon absorption in zinc blende materials, including present tunneling theories (which are essentially parabolic-band results in disguise) and the nonparabolic-band formalism of Pidgeon et al. and Weiler. The agreement between our predictions and previous measurements allowed us to use ZnS as a reference material in order to validate a technique for measuring two-photon absorption that was previously untried in solids, pulsed dual-beam thermal lensing. With the validated technique, we examined nonlinear absorption in one other crystal (rutile) and in several glasses, including silicates, borosilicates, and one phosphate glass. Initially, we believed that the absorption edges of all the materials were comparable; however, subsequent evidence suggested that the effective band-gap energies of the glasses were above the energy of two photons in our measurement. Therefore, we attribute the nonlinear absorption that we observed in glasses to impurities or defects. The measured nonlinear absorption coefficients were of the order of a few cm/TW in the glasses and of the order of 10 cm/GW in the crystals, four orders of magnitude higher than in glasses. 292 refs.

  16. Improved input parameters for diffusion models of skin absorption.

    PubMed

    Hansen, Steffi; Lehr, Claus-Michael; Schaefer, Ulrich F

    2013-02-01

    To use a diffusion model for predicting skin absorption requires accurate estimates of input parameters on model geometry, affinity and transport characteristics. This review summarizes methods to obtain input parameters for diffusion models of skin absorption focusing on partition and diffusion coefficients. These include experimental methods, extrapolation approaches, and correlations that relate partition and diffusion coefficients to tabulated physico-chemical solute properties. Exhaustive databases on lipid-water and corneocyte protein-water partition coefficients are presented and analyzed to provide improved approximations to estimate lipid-water and corneocyte protein-water partition coefficients. The most commonly used estimates of lipid and corneocyte diffusion coefficients are also reviewed. In order to improve modeling of skin absorption in the future diffusion models should include the vertical stratum corneum heterogeneity, slow equilibration processes, the absorption from complex non-aqueous formulations, and an improved representation of dermal absorption processes. This will require input parameters for which no suitable estimates are yet available.

  17. X-Ray Attenuation Coefficients from 10 Kev to 100 Mev,

    DTIC Science & Technology

    1957-04-30

    fig. 1). A well- shielded detector measures the shells account for most of the absorption by this intensity of the trinsmitted beam, and any photon...narrow-beam measurements ----------------- 2 1.4. Combination of attenuation coefficients -------------------- 2 1.5. Energy absorption...thickness is increased measures the unlikely to be absorbed. Consequently, the ab- total probability of the interaction processes. sorption coefficient

  18. The rule of unity for human intestinal absorption 2: application to pharmaceutical drugs that are marketed as salts.

    PubMed

    Patel, Raj B; Admire, Brittany; Yalkowsky, Samuel H

    2015-01-01

    The efficiency of the human intestinal absorption (HIA) of the 59 drugs which are marketed as salts is predicted using the rule of unity. Intrinsic aqueous solubilities and partition coefficients along with the drug dose are used to calculate modified absorption potential (MAP) values. These values are shown to be related to the fraction of the dose that is absorbed upon oral administration in humans (FA). It is shown that the MAP value can distinguish between drugs that are poorly absorbed (FA <0.5) and those that are well absorbed (FA ≥ 0.5). Inspection of the data as well as a receiver operative characteristic (ROC) plot shows that a single critical MAP value can be used for predicting efficient human absorption of drugs. This forms the basis of a simple rule of unity based solely on in vitro data for predicting whether or not a drug will be well absorbed at a given dose.

  19. Influence of two-photon absorption on the dynamic behaviors of microring resonators.

    PubMed

    Li, Qiliang; Chen, Haowen; Xu, Jie; Hu, Miao; Zeng, Ran; Zhou, Xuefang; Li, Shuqin

    2017-04-01

    In this paper, we have investigated the influence of two-photon absorption (TPA) on the dynamic behaviors of all-pass and add-drop microring resonators by using two iterative methods along with the linear stability analysis method. While the incident field is above a certain value, the TPA coefficient has greater influence on the steady state for all-pass and add-drop microring resonators. We use the linear stability analysis method to analyze the stability of the steady state solutions and obtain stability conditions. Results obtained have shown that the change of TPA coefficient will lead to different dynamic behaviors; in addition, while the TPA coefficient is small and its change is slight, the dynamic behaviors of the microring resonators will not change much for most regions. At last, we observe the period windows and route from chaotic to period-N in some original chaotic regions due to the fluctuation of the TPA coefficient.

  20. A polar cap absorption model optimization based on the vertical ionograms analysis

    NASA Astrophysics Data System (ADS)

    Zaalov, N. Y.; Moskaleva, E. V.

    2016-11-01

    Space weather events significantly affect the high frequency (HF) radio wave propagation. The now-casting and forecasting of HF radio wave absorption is important for the HF communication industries. This paper assimilates vertical sounding data into an absorption model to improve its performance as a now-casting tool. The approach is a modification of the algorithm elaborated by Sauer and Wilkinson, which is based on the riometer data. The optimization is focused on accounting for short timescale variation of the absorption. It should be noted that the expression of the frequency dependence of absorption induced by the energetic particle precipitation employed in Sauer and Wilkinson model is based on the riometer data at frequencies of 20, 30, and 50 MHz. The approach suggested in this paper provides an opportunity for expanding the frequency dependence of the absorption for frequencies below 10 MHz. The simulation of the vertical ionograms in the polar cap region uses a computational model designed to overcome the high frequency wave propagation problem in high latitude of the Earth. HF radio wave absorption induced by solar UV illumination, X-ray flares and energetic particles precipitation is taken into consideration in our model. The absorption caused by the energetic particle precipitation is emphasized, because the study is focused on HF wave propagation in polar cap region. A comparison of observed and simulated vertical ionograms enables the coefficients, which relate absorption (day-time and night-time) to integral proton flux to be refined. The values of these coefficients determined from evaluation of the data recorded by any reliable ionosonde are valid for absorption calculation in high-latitude region.

  1. Monitoring spacecraft atmosphere contaminants by laser absorption spectroscopy

    NASA Technical Reports Server (NTRS)

    Steinfeld, J. I.

    1975-01-01

    Data were obtained which will provide a test of the accuracy of the differential absorption method for trace contaminant detection in many-component gas mixtures. The necessary accurate absorption coefficient determinations were carried out for several gases; acetonitrile, 1,2-dichloroethane, Freon-113, furan, methyl ethyl ketone, and t-butyl alcohol. The absorption coefficients are displayed graphically. An opto-acoustic method was tested for measuring absorbance, similar to the system described by Dewey.

  2. Near-IR absorption in high-purity photothermorefractive glass and holographic optical elements: measurement and application for high-energy lasers.

    PubMed

    Lumeau, Julien; Glebova, Larissa; Glebov, Leonid B

    2011-10-20

    Volume Bragg gratings (VBGs) in photothermorefractive (PTR) glass are widely used for laser beam control including high-power laser systems. Among them, spectral beam combining based on VBGs is one of the most promising. Achieving 100+ kW of combined laser beams requires the development of PTR glass and VBGs with an extremely low absorption coefficient and therefore methods of its measurement. This paper describes the calorimetric method that was developed for measuring a low absorption coefficient in PTR glass and VBGs. It is based on transmission monitoring of the intrinsic Fabry-Perot interferometer produced by the plane-parallel surfaces of the measured optical elements when heated by high-power laser radiation. An absorption coefficient at 1085 nm as low as 5×10(-5) cm(-1) is demonstrated in pristine PTR glass while an absorption coefficient as low as 1×10(-4) cm(-1) is measured in high-efficiency reflecting Bragg gratings with highest purity. The actual level of absorption in PTR glass allows laser beam control at the 10 kW level, while the 100 kW level would require active cooling and/or decreasing the absorption in PTR Bragg gratings to a value similar to that in virgin PTR glass.

  3. Near-IR absorption in high-purity photothermorefractive glass and holographic optical elements: measurement and application for high-energy lasers

    SciTech Connect

    Lumeau, Julien; Glebova, Larissa; Glebov, Leonid B.

    2011-10-20

    Volume Bragg gratings (VBGs) in photothermorefractive (PTR) glass are widely used for laser beam control including high-power laser systems. Among them, spectral beam combining based on VBGs is one of the most promising. Achieving 100+ kW of combined laser beams requires the development of PTR glass and VBGs with an extremely low absorption coefficient and therefore methods of its measurement. This paper describes the calorimetric method that was developed for measuring a low absorption coefficient in PTR glass and VBGs. It is based on transmission monitoring of the intrinsic Fabry-Perot interferometer produced by the plane-parallel surfaces of the measured optical elements when heated by high-power laser radiation. An absorption coefficient at 1085 nm as low as 5x10{sup -5} cm{sup -1} is demonstrated in pristine PTR glass while an absorption coefficient as low as 1x10{sup -4} cm{sup -1} is measured in high-efficiency reflecting Bragg gratings with highest purity. The actual level of absorption in PTR glass allows laser beam control at the 10 kW level, while the 100 kW level would require active cooling and/or decreasing the absorption in PTR Bragg gratings to a value similar to that in virgin PTR glass.

  4. Implications of NGA for NEHRP site coefficients

    USGS Publications Warehouse

    Borcherdt, Roger D.

    2012-01-01

    Three proposals are provided to update tables 11.4-1 and 11.4-2 of Minimum Design Loads for Buildings and Other Structures (7-10), by the American Society of Civil Engineers (2010) (ASCE/SEI 7-10), with site coefficients implied directly by NGA (Next Generation Attenuation) ground motion prediction equations (GMPEs). Proposals include a recommendation to use straight-line interpolation to infer site coefficients at intermediate values of ̅vs (average shear velocity). Site coefficients are recommended to ensure consistency with ASCE/SEI 7-10 MCER (Maximum Considered Earthquake) seismic-design maps and simplified site-specific design spectra procedures requiring site classes with associated tabulated site coefficients and a reference site class with unity site coefficients. Recommended site coefficients are confirmed by independent observations of average site amplification coefficients inferred with respect to an average ground condition consistent with that used for the MCER maps. The NGA coefficients recommended for consideration are implied directly by the NGA GMPEs and do not require introduction of additional models.

  5. Seasonal variability in the light absorption properties of western Arctic waters: Parameterization of the individual components of absorption for ocean color applications

    NASA Astrophysics Data System (ADS)

    Matsuoka, Atsushi; Hill, Victoria; Huot, Yannick; Babin, Marcel; Bricaud, Annick

    2011-02-01

    The light absorption properties of particulate and dissolved materials strongly influence the propagation of visible light in oceanic waters and therefore the accuracy of ocean color algorithms. While the general absorption properties of these materials have been reported for Arctic waters, their seasonal variability remains unknown. We investigated the light absorption coefficients of phytoplankton [aϕ(λ)], nonalgal particles [aNAP(λ)], and colored dissolved organic matter [aCDOM(λ)] in both coastal and oceanic waters of the western Arctic Ocean from spring to autumn. Values for the chlorophyll a-specific absorption coefficient of phytoplankton [a*ϕ(440)] declined significantly from the ice melt period in the early spring to the summer. Using high-performance liquid chromatography, we show that the decrease in a*ϕ(440) was due to a strong package effect that overwhelmed the influence of the pigment composition. A decrease in the aNAP(λ) values from spring and summer to autumn likely originated from a decrease in the concentration of phytoplanktonic detritus. The aCDOM(λ) near the surface decreased by 34% from spring to summer as a result of photobleaching by solar radiation. The colored dissolved organic matter (CDOM) absorption values then increased significantly during autumn, resulting from the cumulative injection of Alaskan Coastal Waters into the Arctic as well as CDOM generated in situ. Our results suggest that all of the absorption components are tightly linked to biogeochemical processes, and thus the seasonal variability in aϕ(λ), aNAP(λ), and aCDOM(λ) should be taken into account in bio-optical models.

  6. Two-photon absorption in arsenic sulfide glasses

    NASA Astrophysics Data System (ADS)

    Chunaev, D. S.; Snopatin, G. E.; Plotnichenko, V. G.; Karasik, A. Ya.

    2016-10-01

    The two-photon absorption coefficient of 1047-{\\text{nm}} light in {\\text{As}}35{\\text{S}}65 chalcogenide glass has been measured. CW probe radiation has been used to observe the linear absorption in glass induced by two-photon excitation. The induced absorption lifetime was found to be ∼ 2 {\\text{ms}}.

  7. Research on bimodal particle extinction coefficient during Brownian coagulation and condensation for the entire particle size regime

    NASA Astrophysics Data System (ADS)

    Tang, Hong; Lin, Jian-Zhong

    2011-12-01

    The extinction coefficient of atmospheric aerosol particles influences the earth's radiation balance directly or indirectly, and it can be determined by the scattering and absorption characteristics of aerosol particles. The problem of estimating the change of extinction coefficient due to time evolution of bimodal particle size distribution is studied, and two improved methods for calculating the Brownian coagulation coefficient and the condensation growth rate are proposed, respectively. Through the improved method based on Otto kernel, the Brownian coagulation coefficient can be expressed simply in powers of particle volume for the entire particle size regime based on the fitted polynomials of the mean enhancement function. Meanwhile, the improved method based on Fuchs-Sutugin kernel is developed to obtain the condensation growth rate for the entire particle size regime. And then, the change of the overall extinction coefficient of bimodal distributions undergoing Brownian coagulation and condensation can be estimated comprehensively for the entire particle size regime. Simulation experiments indicate that the extinction coefficients obtained with the improved methods coincide fairly well with the true values, which provide a simple, reliable, and general method to estimate the change of extinction coefficient for the entire particle size regime during the bimodal particle dynamic processes.

  8. An environmental and economical solution to sound absorption using straw

    NASA Astrophysics Data System (ADS)

    McGinnes, Courtney; Kleiner, Mendel; Xiang, Ning

    2005-09-01

    The growing attentiveness to using environmentally friendly materials in the building construction industry as a whole has led many architects to research the use of natural materials. Natural fibers, such as straw, are advantageous due to their accessibility, ease of processing, and their ability to be discarded with a lesser environmental impact through biodegradability. While the material focus may have shifted, the need for quality acoustic environments has remained the same. In a set of preliminary studies, the absorption coefficients of sound absorbers using natural fibers have been proven to have comparable values relative to other highly absorptive, nonenvironmentally friendly materials such as mineral wool and fiberglass. The absorption coefficients were evaluated for octave and third-octave frequencies (125 to 4000 Hz) using the impedance tube method with one microphone. While these absorbers may be acoustically effective as well as environmentally friendly, there may be potential concerns in using natural fibers such as their life span, fire rating, and potential health risks, i.e., disposal techniques, allergenic reactions, and insect and fungus infestation.

  9. Two Photon Absorption And Refraction in Bulk of the Semiconducting Materials

    SciTech Connect

    Kumari, Vinay; Kumar, Vinod; Malik, B. P.; Mohan, Devendra; Gaur, Arun

    2011-10-20

    Fast electronic detection systems have opened up a number of new fields like nonlinear optics, optical communication, coherent optics, optical bistability, two/four wave mixing. The interest in this field has been stimulated by the importance of multiphoton processes in many fundamental aspects of physics. It has proved to be an invaluable tool for determining the optical and electronic properties of the solids because of the fact that one gets the information about the bulk of the material rather than the surface one. In this paper we report, the measurement of the nonlinear absorption and refraction from the band gap to half-band gap region of bulk of semiconductors in the direct and indirect band gap crystals with nanosecond laser. The measured theoretical calculated values of two-photon absorption coefficients ({beta}) and nonlinear refraction n{sub 2}({omega}) of direct band gap crystal match the earlier reported theoretical predictions. By making use of these theoretical calculated values, we have estimated {beta} and n{sub 2}({omega}) in the case of indirect band gap crystals. Low value of absorption coefficient in case of indirect band gap crystals have been attributed to phonon assisted transition while reduction in nonlinear refraction is due to the rise in saturation taking place in the absorption.

  10. Refinement of the ice absorption spectrum in the visible using radiance profile measurements in Antarctic snow

    NASA Astrophysics Data System (ADS)

    Picard, Ghislain; Libois, Quentin; Arnaud, Laurent

    2016-11-01

    Ice is a highly transparent material in the visible. According to the most widely used database (IA2008; Warren and Brandt, 2008), the ice absorption coefficient reaches values lower than 10-3 m-1 around 400 nm. These values were obtained from a vertical profile of spectral radiance measured in a single snow layer at Dome C in Antarctica. We reproduced this experiment using an optical fiber inserted in the snow to record 56 profiles from which 70 homogeneous layers were identified. Applying the same estimation method on every layer yields 70 ice absorption spectra. They present a significant variability but absorption coefficients are overall larger than IA2008 by 1 order of magnitude at 400-450 nm. We devised another estimation method based on Bayesian inference that treats all the profiles simultaneously. It reduces the statistical variability and confirms the higher absorption, around 2 × 10-2 m-1 near the minimum at 440 nm. We explore potential instrumental artifacts by developing a 3-D radiative transfer model able to explicitly account for the presence of the fiber in the snow. The simulation shows that the radiance profile is indeed perturbed by the fiber intrusion, but the error on the ice absorption estimate is not larger than a factor of 2. This is insufficient to explain the difference between our new estimate and IA2008. The same conclusion applies regarding the plausible contamination by black carbon or dust, concentrations reported in the literature are insufficient. Considering the large number of profiles acquired for this study and other estimates from the Antarctic Muon and Neutrino Detector Array (AMANDA), we nevertheless estimate that ice absorption values around 10-2 m-1 at the minimum are more likely than under 10-3 m-1. A new estimate in the range 400-600 nm is provided for future modeling of snow, cloud, and sea-ice optical properties. Most importantly, we recommend that modeling studies take into account the large uncertainty of the ice

  11. An Investigation of the Sampling Distribution of the Congruence Coefficient.

    ERIC Educational Resources Information Center

    Broadbooks, Wendy J.; Elmore, Patricia B.

    This study developed and investigated an empirical sampling distribution of the congruence coefficient. The effects of sample size, number of variables, and population value of the congruence coefficient on the sampling distribution of the congruence coefficient were examined. Sample data were generated on the basis of the common factor model and…

  12. Debye–Waller coefficient of heavily deformed nanocrystalline iron1

    PubMed Central

    Abdellatief, M.

    2017-01-01

    Synchrotron radiation X-ray diffraction (XRD) patterns from an extensively ball-milled iron alloy powder were collected at 100, 200 and 300 K. The results were analysed together with those using extended X-ray absorption fine structure, measured on the same sample at liquid nitrogen temperature (77 K) and at room temperature (300 K), to assess the contribution of static disorder to the Debye–Waller coefficient (B iso). Both techniques give an increase of ∼20% with respect to bulk reference iron, a noticeably smaller difference than reported by most of the literature for similar systems. Besides good quality XRD patterns, proper consideration of the temperature diffuse scattering seems to be the key to accurate values of the Debye–Waller coefficient. Molecular dynamics simulations of nanocrystalline iron aggregates, mapped on the evidence provided by XRD in terms of domain size distribution, shed light on the origin of the observed B iso increase. The main contribution to the static disorder is given by the grain boundary, while line and point defects have a much smaller effect. PMID:28381974

  13. Assessment of seawater optical characteristics in the upper 200 m of ocean on their subsurface values

    NASA Astrophysics Data System (ADS)

    Kopelevich, Oleg V.; Prokhorenko, Olga V.

    1994-10-01

    The specific goal of this work is to develop a model and algorithms of using the optical remote sensing and/or the Secchi disk depth data for an assessment of sea water optical characteristics up to 200 m taking into account the vertical stratification. Measurement data of the scattering coefficient b(550) and of the volume scattering function at 1 degree(s), 6 degree(s), 45 degree(s) angles at 550 nm as well as of the absorption coefficient a(390), a(430) at 390 and 430 nm in the Atlantic, Pacific and Indian Oceans were grouped at five layers and were statistically analyzed. Relative standard errors of the a(390), a(430), b(550) values being calculated for deeper layers by their values at 0 - 10 m layer are estimated as 12 - 35%. A model is also developed to estimate the values of the scattering coefficient in the upper 200 m through the Secchi disk depth; the values of the volume scattering function for different layers can be assessed by using the mean scattering phase functions calculated for clear and turbid waters. The spectral absorption coefficients in the upper 200 m can be evaluated in principle by values of the diffuse coefficient KD(490) at 0 - 10 m layer.

  14. Performance analysis of solar powered absorption refrigeration system

    NASA Astrophysics Data System (ADS)

    Abu-Ein, Suleiman Qaseem; Fayyad, Sayel M.; Momani, Waleed; Al-Bousoul, Mamdouh

    2009-12-01

    The present work provides a detailed thermodynamic analysis of a 10 kW solar absorption refrigeration system using ammonia-water mixtures as a working medium. This analysis includes both first law and second law of thermodynamics. The coefficient of performance (COP), exergetic coefficient of performance (ECOP) and the exergy losses (Δ E) through each component of the system at different operating conditions are obtained. The minimum and maximum values of COP and ECOP were found to be at 110 and 200°C generator temperatures respectively. About 40% of the system exergy losses were found to be in the generator. The maximum exergy losses in the absorber occur at generator temperature of 130°C for all evaporator temperatures. A computer simulation model is developed to carry out the calculations and to obtain the results of the present study.

  15. Pioneer 11 observations of trapped particle absorption by Amalthea

    NASA Technical Reports Server (NTRS)

    Mckibben, R. B.; Pyle, K. R.; Simpson, J. A.

    1983-01-01

    The discovery of a microsignatury of trapped radiation in the Amalthea orbit as detected by Pioneer 11 in a flyby of Juptier in 1974 is reported and its implications for the radial diffusion coefficient in Jupiter's inner magnetosphere are discussed. A low energy telescope registered the absorption of low-energy protons as a function of the magnetic L shell durig inbound and outbound trajectories. Drift velocities of the 1 MeV particles were calculated. No correspondingly heightened effects were observed from high-energy electrons or heavier nuclei. Further analysis of the 0.5-8.7 MeV protons showed data to be consistent erosion of the particle drift shadows by a diffusion process. A limit was calculated for the highest diffusion coefficient value for the 1 MeV protons at the Amalthea orbit. The results indicate that the diffusion is driven by fluctuating electric or magnetic fields.

  16. Spectral absorption index in hyperspectral image analysis for predicting moisture contents in pork longissimus dorsi muscles.

    PubMed

    Ma, Ji; Sun, Da-Wen; Pu, Hongbin

    2016-04-15

    Spectral absorption index was proposed to extract the morphological features of the spectral curves in pork meat samples (longissimus dorsi) under the conditions including fresh, frozen-thawed, heated-dehydrated and brined-dehydrated. Savitzky-Golay (SG) smoothing and multiplicative scatter correction (MSC) were used for calibrating both the spectral reflectance and absorbance values. The absorption values were better than the reflectance values and the calibrated spectra by MSC were better than the raw and SG smoothing corrected spectra in building moisture content predictive models. The optimized partial least square regression (PLSR) model attained good results with the MSC calibrated spectral absorption values based on the spectral absorption index features (R(2)P=0.952, RMSEP=1.396) and the optimal wavelengths selected by regression coefficients (R(2)P=0.966, RMSEP=0.855), respectively. The models proved spectral absorption index was promising in spectral analysis to predict moisture content in pork samples using HSI techniques for the first time.

  17. ABSORPTION ANALYZER

    DOEpatents

    Brooksbank, W.A. Jr.; Leddicotte, G.W.; Strain, J.E.; Hendon, H.H. Jr.

    1961-11-14

    A means was developed for continuously computing and indicating the isotopic assay of a process solution and for automatically controlling the process output of isotope separation equipment to provide a continuous output of the desired isotopic ratio. A counter tube is surrounded with a sample to be analyzed so that the tube is exactly in the center of the sample. A source of fast neutrons is provided and is spaced from the sample. The neutrons from the source are thermalized by causing them to pass through a neutron moderator, and the neutrons are allowed to diffuse radially through the sample to actuate the counter. A reference counter in a known sample of pure solvent is also actuated by the thermal neutrons from the neutron source. The number of neutrons which actuate the detectors is a function of a concentration of the elements in solution and their neutron absorption cross sections. The pulses produced by the detectors responsive to each neu tron passing therethrough are amplified and counted. The respective times required to accumulate a selected number of counts are measured by associated timing devices. The concentration of a particular element in solution may be determined by utilizing the following relation: T2/Ti = BCR, where B is a constant proportional to the absorption cross sections, T2 is the time of count collection for the unknown solution, Ti is the time of count collection for the pure solvent, R is the isotopic ratlo, and C is the molar concentration of the element to be determined. Knowing the slope constant B for any element and when the chemical concentration is known, the isotopic concentration may be readily determined, and conversely when the isotopic ratio is known, the chemical concentrations may be determined. (AEC)

  18. Absorption removal of sulfur dioxide by falling water droplets in the presence of inert solid particles

    NASA Astrophysics Data System (ADS)

    Liu, I.-Hung; Chang, Ching-Yuan; Liu, Su-Chin; Chang, I.-Cheng; Shih, Shin-Min

    An experimental analysis of the absorption removal of sulfur dioxide by the free falling water droplets containing the inert solid particles is presented. The wheat flour powder is introduced as the inert solid particles. Tests with and without the flour powder in the water droplets are examined. The mass fluxes and mass transfer coefficients of SO 2 for the cases with and without the flour powder are compared to elucidate the effects of the inert solid particles contained in the water droplets on the gas absorption. The results indicate aignificant difference between the two cases for the concentrations of the flour powder in the absorbent droplets ( Cs) within the ranges of the experimental conditions, namely 0.1 to 10 wt% flour powder in the absorbent droplets. In general, the inert solid particles of the flour powder as the impurities in the water droplets tend to decrease the SO 2 absorption rate for the experimental absorption system under investigation. Various values of Cs cause various levels of the interfacial resistance and affect the gas absorption rate. The interfacial resistance is recognized by introducing an interfacial mass transfer coefficient ks with its reciprocal being proportional to the magnitude of the interfacial resistance. The values of 1/ ks may be computed by the use of the equation 1/ ks=(1/ KOLs-1/ KOL), where KOLs and KOL are the overall liquid-phase mass transfer coefficients with and without the inert solid particles, respectively. The values of ks with Cs of 0.1 to 10 wt% are about 0.295-0.032 cms -1 for absorbing 1000-3000 ppmv SO 2 with the water droplets. This kind of information is useful for the SO 2 removal and the information of acid rain that the impurities of the inert solid particles contaminate the water droplets.

  19. Effective atomic numbers and mass attenuation coefficients of some thermoluminescent dosimetric compounds for total photon interaction

    SciTech Connect

    Shivaramu; Amutha, R.; Ramprasath, V.

    1999-05-01

    Effective atomic numbers for total gamma-ray interaction with some selected thermoluminescent dosimetric compounds such as barium acetate, barium sulfate, calcium carbonate, calcium sulfate, calcium sulfate dihydrate, cadmium sulfate (anhydrous), cadmium sulfate, strontium sulfate, and lithium fluoride have been calculated in the 1-keV to 20-MeV energy region. Experimental mass attenuation coefficients and effective atomic numbers for these compounds at selected photon energies of 26.3, 33.2, 59.54, and 661.6 keV have been obtained from good geometry transmission measurements and compared with theoretical values. The effect of absorption edge on effective atomic numbers and its variation with energy, and nonvalidity of the Bragg`s mixture rule at incident photon energies closer to the absorption edges of constituent elements of compounds are discussed.

  20. Absorption properties of high-latitude Norwegian coastal water: The impact of CDOM and particulate matter

    NASA Astrophysics Data System (ADS)

    Nima, Ciren; Frette, Øyvind; Hamre, Børge; Erga, Svein Rune; Chen, Yi-Chun; Zhao, Lu; Sørensen, Kai; Norli, Marit; Stamnes, Knut; Stamnes, Jakob J.

    2016-09-01

    We present data from measurements and analyses of the spectral absorption due to colored dissolved organic matter (CDOM), total suspended matter (TSM), phytoplankton, and non-algal particles (NAP) in high-latitude northern Norwegian coastal water based on samples taken in spring, summer, and autumn. The Chlorophyll-a (Chl-a) concentration was found to vary significantly with season, whereas regardless of season CDOM was found to be the dominant absorber for wavelengths shorter than 600 nm. The absorption spectral slope S350-500 for CDOM varied between 0.011 and 0.022 nm-1 with mean value and standard deviation given by (0.015 ± 0.002) nm-1. The absorption spectral slope was found to be strongly dependent on the wavelength interval used for fitting. On average, S280-500 was found to be 43% higher than S350-500. A linear relationship was found between the base 10 logarithm of the absorption coefficient at 440 nm [log(ag(440))] and S350-500. Regardless of season, phytoplankton were the dominant component of the TSM absorption indicating little influence from land drainage. The mean values of the Chl-a specific absorption coefficient of phytoplankton aph*(λ) at 440 nm and 676 nm were 0.052 m2 mg-1 and 0.023 m2 mg-1, respectively, and aph*(λ) was found to vary with season, being higher in summer and autumn than in spring. The absorption spectral slope SNAP, which is the spectral slope of absorption spectrum for non-algal particles, was lower than that for European coastal water in general. It varied between 0.0048 and 0.022 nm-1 with mean value and standard deviation given by (0.0083-1 ± 0.003) nm-1. Comparisons of absorption coefficients measured in situ using an ac-9 instrument with those measured in the laboratory from water samples show a good agreement.

  1. Heat transfer coefficient of cryotop during freezing.

    PubMed

    Li, W J; Zhou, X L; Wang, H S; Liu, B L; Dai, J J

    2013-01-01

    Cryotop is an efficient vitrification method for cryopreservation of oocytes. It has been widely used owing to its simple operation and high freezing rate. Recently, the heat transfer performance of cryotop was studied by numerical simulation in several studies. However, the range of heat transfer coefficient in the simulation is uncertain. In this study, the heat transfer coefficient for cryotop during freezing process was analyzed. The cooling rates of 40 percent ethylene glycol (EG) droplet in cryotop during freezing were measured by ultra-fast measurement system and calculated by numerical simulation at different value of heat transfer coefficient. Compared with the results obtained by two methods, the range of the heat transfer coefficient necessary for the numerical simulation of cryotop was determined, which is between 9000 W/(m(2)·K) and 10000 W/(m (2)·K).

  2. Transonic Blunt Body Aerodynamic Coefficients Computation

    NASA Astrophysics Data System (ADS)

    Sancho, Jorge; Vargas, M.; Gonzalez, Ezequiel; Rodriguez, Manuel

    2011-05-01

    In the framework of EXPERT (European Experimental Re-entry Test-bed) accurate transonic aerodynamic coefficients are of paramount importance for the correct trajectory assessment and parachute deployment. A combined CFD (Computational Fluid Dynamics) modelling and experimental campaign strategy was selected to obtain accurate coefficients. A preliminary set of coefficients were obtained by CFD Euler inviscid computation. Then experimental campaign was performed at DNW facilities at NLR. A profound review of the CFD modelling was done lighten up by WTT results, aimed to obtain reliable values of the coefficients in the future (specially the pitching moment). Study includes different turbulence modelling and mesh sensitivity analysis. Comparison with the WTT results is explored, and lessons learnt are collected.

  3. On the relationship between coefficient alpha and composite reliability.

    PubMed

    Peterson, Robert A; Kim, Yeolib

    2013-01-01

    Cronbach's coefficient alpha is the most widely used estimator of the reliability of tests and scales. However, it has been criticized as being a lower bound and hence underestimating true reliability. A popular alternative to coefficient alpha is composite reliability, which is usually calculated in conjunction with structural equation modeling. A quantitative analysis of 2,524 pairs of coefficient alpha and composite reliability values derived from empirical investigations revealed that although the average composite reliability value (.86) exceeded the average corresponding coefficient alpha value (.84), the difference was relatively inconsequential for practical applications such as meta-analysis.

  4. Examination of the Measurement of Absorption Using the Reverberant Room Method for Highly Absorptive Acoustic Foam

    NASA Technical Reports Server (NTRS)

    Hughes, William O.; McNelis, Anne M.; Chris Nottoli; Eric Wolfram

    2015-01-01

    The absorption coefficient for material specimens are needed to quantify the expected acoustic performance of that material in its actual usage and environment. The ASTM C423-09a standard, "Standard Test Method for Sound Absorption and Sound Absorption Coefficients by the Reverberant Room Method" is often used to measure the absorption coefficient of material test specimens. This method has its basics in the Sabine formula. Although widely used, the interpretation of these measurements are a topic of interest. For example, in certain cases the measured Sabine absorption coefficients are greater than 1.0 for highly absorptive materials. This is often attributed to the diffraction edge effect phenomenon. An investigative test program to measure the absorption properties of highly absorbent melamine foam has been performed at the Riverbank Acoustical Laboratories. This paper will present and discuss the test results relating to the effect of the test materials' surface area, thickness and edge sealing conditions. A follow-on paper is envisioned that will present and discuss the results relating to the spacing between multiple piece specimens, and the mounting condition of the test specimen.

  5. Aerosol Scattering and Absorption Properties Over the Central Himalayan Location Nainital: Results from Gvax

    NASA Astrophysics Data System (ADS)

    Gogoi, M. M.; Babu, S.; Nair, V. S.; Satheesh, S.; Naja, M.; Kotamarthi, V. R.

    2012-12-01

    Extensive characterization of aerosols over a central Himalayan location, Nainital (29.4° N, 79.5° E, 1958 m amsl) were carried out during June 2011 to March 2012 under the Ganges Valley Aerosol Experiment (GVAX). Owing to the highly turbid, persistent and increasing aerosol concentration over the Ganges Valley in northern India, their influence on surface dimming, mid-tropospheric warming and monsoon circulations, the experimental site Nainital is best suited for studying the regional distribution of complex aerosol sources, their transport and direct and indirect radiative forcing mechanisms. During the study period, aerosol scattering (absorption) coefficients showed values as high as > 500 Mm-1 (> 50 Mm-1) in local noon time during the onset of winter and early spring and as low as < 300 Mm-1 (< 40 Mm-1) during the summer months. Consequently, aerosol single scattering albedo (SSA) decreased in winter (< 0.9, for 45% of occurrences) with large day-to-day modulations and higher values (> 0.9, for 81% of occurrences) during summer. Based on the spectral distribution of scattering coefficients, fine mode aerosols dominate the summer compared to winter season. The strong absorption during the winter and early spring is associated with the prevalence of biomass burning aerosols and/or dust as reveal by the steep spectral dependence of absorption coefficients (αabs >2.0). These observed seasonal variations are attributed to the dynamics of the atmospheric boundary layer as well as the influence of long range transport over the Himalayan location.

  6. Parametric analysis of a double-effect steam absorption chiller

    NASA Astrophysics Data System (ADS)

    Mohammed Salih Ahmed, Mojahid Sid Ahmed; Gilani, Syed Ihtsham Ul-Haq

    2012-06-01

    The development in the field of refrigeration and cooling systems based on absorption cycles has attained its own internal dynamic in the last decade. A major obstacle for developing model is the lack of available component specifications. These specifications are commonly proprietary of the chiller's manufacturers and normally the available information is not sufficient. This work presented a double-effect parallel-flow-type steam absorption chiller model based on thermodynamic and energy equations. The chiller studied is 1250 RT (Refrigeration Tons) using lithium bromide -water as working pair. The mathematical equations that govern the operation of the steam absorption chiller are developed, and from the available design data the values of the overall heat transfer coefficient multiplied by the heat exchanger surface area and the characteristics of each component of the absorption chiller at the design point are calculated. For thermo physical and thermodynamic properties for lithium bromide-water solution, set of computationally efficient formulations are used. The model gives the required information about temperature, concentration, and flow rate at each state point of the system. The model calculates the heat load at each component as well as the performance of the system.

  7. Highly sensitive absorption measurements in lithium niobate using whispering gallery resonators

    NASA Astrophysics Data System (ADS)

    Leidinger, Markus; Buse, Karsten; Breunig, Ingo

    2015-02-01

    The absorption coefficient of undoped, congruently grown lithium niobate (LiNbO3) for ordinarily and extraordinarily polarized light is measured in the wavelength range from 390 to 2600 nm using whispering gallery resonators (WGRs). These monolithic cavities guide light by total internal reflection. Their high Q-factor provides several hundred meters of propagation for the coupled light in millimetre size resonators allowing for the measurement of absorption coefficients below 10-2 cm-1, where standard methods such as Fourier-transform or grating spectroscopy meet their limit. In this work the lowest measured value is 10-4 cm-1 at 1700 nm wavelength. Furthermore, the known OH- overtone at 1470 nm wavelength can be resolved clearly.

  8. High-Absorption-Efficiency Superlattice Solar Cells by Excitons

    NASA Astrophysics Data System (ADS)

    Nishinaga, Jiro; Kawaharazuka, Atsushi; Onomitsu, Koji; Horikoshi, Yoshiji

    2013-11-01

    The effect of excitonic absorption on solar cell efficiency has been investigated using solar cells with AlGaAs/GaAs superlattice structures. Numerical calculations reveal that excitonic absorption considerably enhances the overall absorption of bulk GaAs. Excitonic absorption shows strong and sharp peaks at the absorption edge and in the energy region above the band gap. Absorption enhancement is also achieved in the AlGaAs/GaAs superlattice. The measured quantum efficiency spectra of the superlattice solar cells are quite similar to the calculated absorption spectra considering the excitonic effect. The superlattice solar cells are confirmed to have high absorption coefficient compared with the GaAs and AlGaAs bulk solar cells. These results suggest that the enhanced absorption by excitons can increase the quantum efficiency of solar cells. This effect is more prominent for the solar cells with small absorption layer thicknesses.

  9. Evaluation of a compact sensor for backscattering and absorption

    NASA Astrophysics Data System (ADS)

    Gainusa Bogdan, Alina; Boss, Emmanuel S.

    2011-07-01

    Seawater inherent optical properties (IOPs) are key parameters in a wide range of applications in environmental studies and oceanographic research. In particular, the absorption coefficient (a) is the typical IOP used to obtain the concentration of chlorophyll-a in the water---a critical parameter in biological oceanography studies and the backscattering coefficient (bb) is used as a measure of turbidity. In this study, we test a novel instrument concept designed to obtain both the absorption and backscattering coefficients. The instrument would emit a collimated monochromatic light beam into the water retrieving the backscattered light intensity as a function of distance from the center of illumination. We use Monte Carlo modeling of light propagation to create an inversion algorithm that translates the signal from such an instrument into values of a and bb. Our results, based on simulations spanning the bulk of natural values of seawater IOP combinations, indicate that a 6.2cm diameter instrument with a radial resolution of 1cm would be capable of predicting bb within less than 13.4% relative difference and a within less than 57% relative difference (for 90% of the inverted a values, the relative errors fall below 29.7%). Additionally, these errors could be further reduced by constraining the inversion algorithm with information from concurrent measurements of other IOPs. Such a compact and relatively simple device could have multiple applications for in situ optical measurements, including a and bb retrievals from instrumentation mounted on autonomous underwater vehicles. Furthermore, the same methodology could possibly be used for an out-of-water sensor.

  10. Determining CDOM Absorption Spectra in Diverse Aquatic Environments Using a Multiple Pathlength, Liquid Core Waveguide System

    NASA Technical Reports Server (NTRS)

    Miller, Richard L.; Belz, Mathias; DelCastillo, Carlos; Trzaska, Rick

    2001-01-01

    We evaluated the accuracy, sensitivity and precision of a multiple pathlength, liquid core waveguide (MPLCW) system for measuring colored dissolved organic matter (CDOM) absorption in the UV-visible spectral range (370-700 nm). The MPLCW has four optical paths (2.0, 9.8, 49.3, and 204 cm) coupled to a single Teflon AF sample cell. Water samples were obtained from inland, coastal and ocean waters ranging in salinity from 0 to 36 PSU. Reference solutions for the MPLCW were made having a refractive index of the sample. CDOM absorption coefficients, aCDOM, and the slope of the log-linearized absorption spectra, S, were compared with values obtained using a dual-beam spectrophotometer. Absorption of phenol red secondary standards measured by the MPLCW at 558 nm were highly correlated with spectrophotometer values and showed a linear response across all four pathlengths. Values of aCDOM measured using the MPLCW were virtually identical to spectrophotometer values over a wide range of concentrations. The dynamic range of aCDOM for MPLCW measurements was 0.002 - 231.5 m-1. At low CDOM concentrations spectrophotometric aCDOM were slightly greater than MPLCW values and showed larger fluctuations at longer wavelengths due to limitations in instrument precision. In contrast, MPLCW spectra followed an exponential to 600 nm for all samples.

  11. TRACK--A new method for the evaluation of low-level extinction coefficient in optical films.

    PubMed

    Vernhes, R; Martinu, L

    2015-11-02

    We develop a rigorous methodology named TRACK based on the collection of multi-angle spectrophotometric transmission and reflection data in order to assess the extinction coefficient of quasi-transparent optical films. The accuracy of extinction coefficient values obtained by this method is not affected by sample non-idealities (thickness non-uniformity, refractive index inhomogeneities, anisotropy, interfaces, etc.) and therefore a simple two-layer (substrate/film) optical model can be used. The method requires the acquisition of transmission and reflection data at two angles of incidence: 10° and 65° in p polarization. Data acquired at 10° provide information about the film thickness and the refractive index, while data collected at 65° are used for absorption evaluation and extinction coefficient computation. We test this method on three types of samples: (i) a CR-39 plastic substrate coated with a thick protective coating; (ii) the same substrate coated with a thin TiO(2) film; (iii) and a thick Si(3)N(4) film deposited on Gorilla glass that presents thickness non-uniformity and refractive index gradient non-idealities. We also compare absorption and extinction coefficient values obtained at 410 and 550 nm by both TRACK and Laser Induced Deflection techniques in the case of a 1 micron thick TiO(2) coating. Both methods display consistent extinction coefficient values in the 10(-4) and 10(-5) ranges at 410 and 550 nm, respectively, which proves the validity of the methodology and provides an estimate of its accuracy limit.

  12. Roughness coefficients for stream channels in Arizona

    USGS Publications Warehouse

    Aldridge, B.N.; Garrett, J.M.

    1973-01-01

           n in which V = mean cross-sectional velocity of flow, in feet per second; R = hydraulic radius at a cross section, which is the cross-sectional area divided by the wetter perimeter, in feet; Se = energy slope; and n = coefficient of roughness. Many research studies have been made to determine "n" values for open-channel flow (Carter and others, 1963). Guidelines for selecting coefficient of roughness for stream channels are given in most of the literature of stream-channel hydraulics, but few of the data relate directly to streams of Arizona, The U.S> Geological Survey, at the request of the Arizona Highway Department, assembled the color photographs and tables of the Manning "n" values in this report to aid highway engineers in the selection of roughness coefficients for Arizona streams. Most of the photographs show channel reaches for which values of "n" have been assigned by experienced Survey personnel; a few photographs are included for reaches where "n" values have been verified. Verified "n" values are computed from a known discharge and measured channel geometry. Selected photographs of stream channels for which "n" values have been verified are included in U.S. Geological Survey Water-Supply Paper 1849 (Barnes, 1967); stereoscopic slides of Barnes' (1967) photographs and additional photographs can be inspected at U.S> Geological Survey offices in: 2555 E. First Street, Tucson; and 5017 Federal Building, 230 N. First Avenue, Phoenix.

  13. The CO2 absorption spectrum in the 2.3 μm transparency window by high sensitivity CRDS: (II) Self-absorption continuum

    NASA Astrophysics Data System (ADS)

    Mondelain, D.; Vasilchenko, S.; Čermák, P.; Kassi, S.; Campargue, A.

    2017-01-01

    The CO2 absorption continuum near 2.3 μm is determined for a series of sub atmospheric pressures (250-750 Torr) by high sensitivity Cavity Ring Down Spectroscopy. An experimental procedure consisting in injecting successively a gas flow of CO2 and synthetic air, keeping constant the gas pressure in the CRDS cell, has been developed. This procedure insures a high stability of the spectra baseline by avoiding changes of the optical alignment due to pressure changes. The CO2 continuum was obtained as the difference between the CO2 absorption coefficient and a local lines simulation using a Voigt profile truncated at ±25 cm-1. Following the results of the preceding analysis of the CO2 rovibrational lines (Vasilchenko S et al. J Quant Spectrosc Radiat Transfer 10.1016/j.jqsrt.2016.07.002, a CO2 line list with intensities obtained by variational calculations and empirical line positions was preferred to the HITRAN line list. A quadratic pressure dependence of the absorption continuum is observed, with an average binary absorption coefficient increasing from 2 to 4×10-8 cm-1 amagat-2 between 4320 and 4380 cm-1. The obtained continuum is found in good agreement with a previous measurement using much higher densities (20 amagat) and a low resolution grating spectrograph and is consistent with values currently used in the analysis of Venus spectra.

  14. Temporal correlation coefficient for directed networks.

    PubMed

    Büttner, Kathrin; Salau, Jennifer; Krieter, Joachim

    2016-01-01

    Previous studies dealing with network theory focused mainly on the static aggregation of edges over specific time window lengths. Thus, most of the dynamic information gets lost. To assess the quality of such a static aggregation the temporal correlation coefficient can be calculated. It measures the overall possibility for an edge to persist between two consecutive snapshots. Up to now, this measure is only defined for undirected networks. Therefore, we introduce the adaption of the temporal correlation coefficient to directed networks. This new methodology enables the distinction between ingoing and outgoing edges. Besides a small example network presenting the single calculation steps, we also calculated the proposed measurements for a real pig trade network to emphasize the importance of considering the edge direction. The farm types at the beginning of the pork supply chain showed clearly higher values for the outgoing temporal correlation coefficient compared to the farm types at the end of the pork supply chain. These farm types showed higher values for the ingoing temporal correlation coefficient. The temporal correlation coefficient is a valuable tool to understand the structural dynamics of these systems, as it assesses the consistency of the edge configuration. The adaption of this measure for directed networks may help to preserve meaningful additional information about the investigated network that might get lost if the edge directions are ignored.

  15. Middle infrared optoelectronic absorption systems for monitoring physiological glucose solutions

    NASA Astrophysics Data System (ADS)

    Martin, W. Blake

    Tight monitoring of the glucose levels for diabetic individuals is essential to control long-term complications. A definitive diabetes management system has yet to be developed for the diabetic. This research investigates the application of middle infrared absorption frequencies for monitoring glucose levels in biological solutions. Three frequencies were identified using a Fourier transform infrared spectrometer and correlated to changes in glucose concentrations. The 1035 +/- 1 cm-1 frequency was determined to be the best representative frequency. Other biological molecules contributed no significant interference to monitoring glucose absorption. A second frequency at 1193 cm-1 was suggested as a representative background absorption frequency, which could be used for more accurate glucose absorption values. Next, a quantum cascade laser optoelectronic absorption system was designed and developed to monitor glucose. After careful alignment and design, the system was used to monitor physiological glucose concentrations. Correlation at 1036 cm-1 with glucose changes was comparable to the previous results. The use of the background absorption frequency was verified. This frequency essentially acts as a calibrating frequency to adjust in real-time to any changes in the background absorption that may alter the accuracy of the predicted glucose value. An evanescent wave cavity ring-down spectroscopy technique was explored to monitor molecules in a biological solution. Visible light at 425 nm was used to monitor hemoglobin in control urine samples. An adsorption isotherm for hemoglobin was detectable to limit of 5.8 nM. Evanescent wave cavity ring-down spectroscopy would be useful for a glucose solution. Given an equivalent system designed for the middle infrared, the molar extinction coefficient of glucose allows for a detectable limit of 45 mg/dl for a free-floating glucose solution, which is below normal physiological concentrations. The future use of a hydrophobic

  16. Calculation of the molar absorptivity of polyphenols by using liquid chromatography with diode array detection: the case of carnosic acid.

    PubMed

    Pelillo, M; Cuvelier, M E; Biguzzi, B; Gallina Toschi, T; Berset, C; Lercker, G

    2004-01-16

    Antioxidant activity of vegetable extracts is related to the nature and the amount of active components, mainly polyphenols; therefore, a correct quantification of these molecules should be required to define their concentration in such kind of vegetable extracts. A fast and accurate method to calculate molar absorption coefficients (epsilon), by using HPLC, has been tested on standard polyphenols and caffeine, and should be widely adapted for standardless quantitative analysis. Molar absorptivity (epsilon) of carnosic acid (CA) was determined from 200 to 300 nm, by the proposed method and those values were compared to tert-butyl-hydroxytoluene (BHT) ones for further comparative quantification.

  17. Comparison of measured and theoretical inverse bremsstrahlung and photoionization absorption of infrared radiation in a H-He plasma.

    NASA Technical Reports Server (NTRS)

    Billman, K. W.; Stallcop, J. R.; Rowley, P. D.; Presley, L. L.

    1972-01-01

    The absorption coefficients of 1.15- and 3.39-micrometer radiation for a homogeneous H-He plasma have been measured in a temperature and electron density range where the major absorption mechanisms are electron-ion inverse bremsstrahlung and neutral-atom photoionization. Measurements were made behind both the incident and reflected shock waves in a driven tube by recording the laser intensity transmitted along the tube diameter as a function of time. The measured values compare well with those obtained from theoretical calculations for a gas in thermodynamic equilibrium.

  18. Optical absorption and radiative heat transport in olivine at high temperature

    NASA Technical Reports Server (NTRS)

    Shankland, T. J.; Nitsan, U.; Duba, A. G.

    1979-01-01

    Results are presented of measurements of the optical absorption spectra (300-8000 nm) of olivine as a function of temperature (300-1700 K) under conditions of controlled and known oxygen fugacity within the stability field of the samples. The absorption spectra are used to calculate the temperature-dependent radiative transfer coefficient of olivine and to numerically study the accuracy of the method. The present absorption measurements in olivine under oxidizing conditions known to be within the olivine stability field indicate that the effective radiative conductivity K(R) is lower than that obtained in previous studies under different experimental conditions. The lower value of K(R) makes it more likely that some of the earth's internal heat is removed by convection and less likely that thermal models involving conduction and radiation alone will satisfactorily explain thermal conditions in the earth's mantle.

  19. Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

    NASA Technical Reports Server (NTRS)

    Meyer, Scott Andrew

    1995-01-01

    The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3x10(exp 17) and 9x10(exp 17) cm(exp -3). The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

  20. Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

    NASA Technical Reports Server (NTRS)

    Meyer, Scott Andrew

    1995-01-01

    The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3 x 10(exp 17) and 9 x 10(exp 17) cm(exp -3). The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

  1. Broadband absorption spectroscopy by combining frequency-domain and steady-state techniques

    NASA Astrophysics Data System (ADS)

    Berger, Andrew J.; Bevilacqua, Frederic; Jakubowski, Dorota B.; Cerussi, Albert E.; Butler, John A.; Hsiang, D.; Tromberg, Bruce J.

    2001-06-01

    A technique for measuring broadband near-infrared absorption spectra of turbid media is presented using a combination of frequency-domain (FD) and steady-state (SS) reflectance methods. Most of the wavelength coverage is provided by a white-light SS measurement, while the FD data are acquired at a few selected wavelengths. Coefficients of absorption ((mu) a) and reduced scattering ((mu) s') derived from the FD data are used to intensity-calibrate the SS measurements and to estimate (mu) s' at all wavelengths in the spectral window of interest. After these steps are performed, (mu) a can be determined by comparing the SS reflectance values to the predictions of diffusion theory, wavelength by wavelength. We present an application of this method to breast tumor characterization. A case study of a fibroadenoma is shown, where different absorption spectra were found between the normal and the tumor sides.

  2. Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

    NASA Technical Reports Server (NTRS)

    Meyer, Scott Andrew

    1995-01-01

    The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3 x 10(exp 17) and 9 x 10(exp 17)/cu cm. The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

  3. Evaluation of Fourier transform coefficients for the diagnosis of rheumatoid arthritis from diffuse optical tomography images

    NASA Astrophysics Data System (ADS)

    Montejo, Ludguier D.; Jia, Jingfei; Kim, Hyun K.; Hielscher, Andreas H.

    2013-03-01

    We apply the Fourier Transform to absorption and scattering coefficient images of proximal interphalangeal (PIP) joints and evaluate the performance of these coefficients as classifiers using receiver operator characteristic (ROC) curve analysis. We find 25 features that yield a Youden index over 0.7, 3 features that yield a Youden index over 0.8, and 1 feature that yields a Youden index over 0.9 (90.0% sensitivity and 100% specificity). In general, scattering coefficient images yield better one-dimensional classifiers compared to absorption coefficient images. Using features derived from scattering coefficient images we obtain an average Youden index of 0.58 +/- 0.16, and an average Youden index of 0.45 +/- 0.15 when using features from absorption coefficient images.

  4. Determine scattering coefficient and anisotropy of scattering of murine tissues using reflectance-mode confocal microscopy

    NASA Astrophysics Data System (ADS)

    Samatham, Ravikant; Jacques, Steven L.

    2013-02-01

    Different techniques have been developed to determine the optical properties of turbid media, which include collimated transmission, diffuse reflectance, adding-doubling and goniometry. While goniometry can be used to determine the anisotropy of scattering (g), other techniques are used to measure the absorption coefficient and reduced scattering coefficient (μs(1-g)). But separating scattering coefficient (μs) and anisotropy of scattering from reduced scattering coefficient has been tricky. We developed an algorithm to determine anisotropy of scattering from the depth dependent decay of reflectance-mode confocal scanning laser microscopy (rCSLM) data. This report presents the testing of the algorithm on tissue phantoms with different anisotropies (g = 0.127 to 0.868, at 488 nm wavelength). Tissue phantoms were made from polystyrene microspheres (6 sizes 0.1-0.5 μm dia.) dispersed in both aqueous solutions and agarose gels. Three dimensional images were captured. The rCSLM-signal followed an exponential decay as a function of depth of the focal volume, R(z)ρexp(-μz) where ρ (dimensionless, ρ = 1 for a mirror) is the local reflectivity and μ [cm-1] is the exponential decay constant. The theory was developed to uniquely map the experimentally determined μ and ρ into the optical scattering properties μs and g. The values of μs and g depend on the composition and microstructure of tissues, and allow characterization of a tissue.

  5. Nitrogen dioxide and kerosene-flame soot calibration of photoacoustic instruments for measurement of light absorption by aerosols

    SciTech Connect

    Arnott, W. Patrick; Moosmu''ller, Hans; Walker, John W.

    2000-12-01

    A nitrogen dioxide calibration method is developed to evaluate the theoretical calibration for a photoacoustic instrument used to measure light absorption by atmospheric aerosols at a laser wavelength of 532.0 nm. This method uses high concentrations of nitrogen dioxide so that both a simple extinction and the photoacoustically obtained absorption measurement may be performed simultaneously. Since Rayleigh scattering is much less than absorption for the gas, the agreement between the extinction and absorption coefficients can be used to evaluate the theoretical calibration, so that the laser gas spectra are not needed. Photoacoustic theory is developed to account for strong absorption of the laser beam power in passage through the resonator. Findings are that the photoacoustic absorption based on heat-balance theory for the instrument compares well with absorption inferred from the extinction measurement, and that both are well within values represented by published spectra of nitrogen dioxide. Photodissociation of nitrogen dioxide limits the calibration method to wavelengths longer than 398 nm. Extinction and absorption at 532 and 1047 nm were measured for kerosene-flame soot to evaluate the calibration method, and the single scattering albedo was found to be 0.31 and 0.20 at these wavelengths, respectively.

  6. Interacting He and Ar atoms: Revised theoretical interaction potential, dipole moment, and collision-induced absorption spectra

    SciTech Connect

    Meyer, Wilfried; Frommhold, Lothar

    2015-09-21

    Coupled cluster quantum chemical calculations of the potential energy surface and the induced dipole surface are reported for the He–Ar van der Waals collisional complex. Spectroscopic parameters are derived from global analytical fits while an accurate value for the long-range dipole coefficient D{sub 7} is obtained by perturbation methods. Collision-induced absorption spectra are computed quantum mechanically and compared with existing measurements.

  7. Interacting He and Ar atoms: Revised theoretical interaction potential, dipole moment, and collision-induced absorption spectra.

    PubMed

    Meyer, Wilfried; Frommhold, Lothar

    2015-09-21

    Coupled cluster quantum chemical calculations of the potential energy surface and the induced dipole surface are reported for the He-Ar van der Waals collisional complex. Spectroscopic parameters are derived from global analytical fits while an accurate value for the long-range dipole coefficient D7 is obtained by perturbation methods. Collision-induced absorption spectra are computed quantum mechanically and compared with existing measurements.

  8. Measurements of scattering and absorption properties of surface aerosols at a semi-arid site, Anantapur

    NASA Astrophysics Data System (ADS)

    Rama Gopal, K.; Balakrishnaiah, G.; Arafath, S. Md.; Raja Obul Reddy, K.; Siva Kumar Reddy, N.; Pavan Kumari, S.; Raghavendra Kumar, K.; Chakradhar Rao, T.; Lokeswara Reddy, T.; Reddy, R. R.; Nazeer Hussain, S.; Vasudeva Reddy, M.; Suresh Babu, S.; Mallikarjuna Reddy, P.

    2017-01-01

    Aerosol optical properties are continuously measured at a semi-arid station, Anantapur from June 2012 to May 2013 which describes the impact of surface aerosols on climate change over the region. Scattering coefficient (σsct) and absorption coefficient (σabs) are obtained from integrating Nephelometer and Aethalometer, respectively. Also, the single scattering albedo (ω0), Scattering/absorption Ångström exponents were examined during the period of study. Diurnal variations of σsct and σabs show a bi-peak pattern with two maxima and one minimum in a day. The largest values of σsct and σabs are obtained in winter while the lowest values are measured in monsoon. From the measurements σsct550 and σabs550 are found to be 110 ± 12.23 Mm- 1 and 33 ± 5.2 Mm- 1, respectively during the study period. An analysis of the ω0 suggests that there is a more absorbing fraction in the particle composition over the measurement site. The ω0 obtained in the surface boundary layer of Anantapur is below the critical value of 0.86 that determines the shift from cooling to warming. A relationship between scattering/absorption coefficients and scattering/absorption Ångström exponent and single scattering albedo is further examined. In order to understand the origins of the air masses in the study region, we performed seven-day back trajectory analyses based on the NOAA HYSPLIT model. These trajectories were computed at several altitudes (3000 m, 1500 m, and 500 m) for June 2012 and May 2013. These results put in evidence the need of efforts to reduce absorbing particles (black carbon) emissions to avoid the possible warming that would result from the reductions of the cooling aerosol only.

  9. A Synthesis of Light Absorption Properties of the Arctic Ocean: Application to Semi-analytical Estimates of Dissolved Organic Carbon Concentrations from Space

    NASA Technical Reports Server (NTRS)

    Matsuoka, A.; Babin, M.; Doxaran, D.; Hooker, S. B.; Mitchell, B. G.; Belanger, S.; Bricaud, A.

    2014-01-01

    The light absorption coefficients of particulate and dissolved materials are the main factors determining the light propagation of the visible part of the spectrum and are, thus, important for developing ocean color algorithms. While these absorption properties have recently been documented by a few studies for the Arctic Ocean [e.g., Matsuoka et al., 2007, 2011; Ben Mustapha et al., 2012], the datasets used in the literature were sparse and individually insufficient to draw a general view of the basin-wide spatial and temporal variations in absorption. To achieve such a task, we built a large absorption database at the pan-Arctic scale by pooling the majority of published datasets and merging new datasets. Our results showed that the total non-water absorption coefficients measured in the Eastern Arctic Ocean (EAO; Siberian side) are significantly higher 74 than in the Western Arctic Ocean (WAO; North American side). This higher absorption is explained 75 by higher concentration of colored dissolved organic matter (CDOM) in watersheds on the Siberian 76 side, which contains a large amount of dissolved organic carbon (DOC) compared to waters off 77 North America. In contrast, the relationship between the phytoplankton absorption (a()) and chlorophyll a (chl a) concentration in the EAO was not significantly different from that in the WAO. Because our semi-analytical CDOM absorption algorithm is based on chl a-specific a() values [Matsuoka et al., 2013], this result indirectly suggests that CDOM absorption can be appropriately erived not only for the WAO but also for the EAO using ocean color data. Derived CDOM absorption values were reasonable compared to in situ measurements. By combining this algorithm with empirical DOC versus CDOM relationships, a semi-analytical algorithm for estimating DOC concentrations for coastal waters at the Pan-Arctic scale is presented and applied to satellite ocean color data.

  10. Second derivative spectrophotometric determination of partition coefficients of phenothiazine derivatives between human erythrocyte ghost membranes and water.

    PubMed

    Kitamura, K; Goto, T; Kitade, T

    1998-08-01

    The absorption spectra of six phenothiazine derivatives, chlorpromazine, triflupromazine, promazine, promethazine, trifluoperazine and prochlorperazine, measured in the solutions containing various amounts of human erythrocyte ghosts (HEG) showed bathocromic shifts according to the amount of HEG. Due to the strong background signals caused by HEG, the baseline compensation was incomplete, even though the sample and the reference solutions contained the same amount of HEG, hence further spectral information could not be obtained. The second derivative spectra of these absorption spectra clearly showed the derivative isosbestic points, indicating that the residual background signal effects were entirely eliminated. The derivative intensity differences of the phenothiazines (DeltaD values) before and after the addition of HEG were measured at a specific wavelength. Using the DeltaD values, the partition coefficients (K(p)) of these drugs were calculated and obtained with R.S.D. of below 10 %. The fractions of partitioned phenothiazines calculated from the K(p) values agreed well with the experimental values. The results indicate that the derivative method can be applicable to the determination of partition coefficients of drugs to HEG without any separation procedures.

  11. Method for Calculating the Optical Diffuse Reflection Coefficient for the Ocular Fundus

    NASA Astrophysics Data System (ADS)

    Lisenko, S. A.; Kugeiko, M. M.

    2016-07-01

    We have developed a method for calculating the optical diffuse reflection coefficient for the ocular fundus, taking into account multiple scattering of light in its layers (retina, epithelium, choroid) and multiple refl ection of light between layers. The method is based on the formulas for optical "combination" of the layers of the medium, in which the optical parameters of the layers (absorption and scattering coefficients) are replaced by some effective values, different for cases of directional and diffuse illumination of the layer. Coefficients relating the effective optical parameters of the layers and the actual values were established based on the results of a Monte Carlo numerical simulation of radiation transport in the medium. We estimate the uncertainties in retrieval of the structural and morphological parameters for the fundus from its diffuse reflectance spectrum using our method. We show that the simulated spectra correspond to the experimental data and that the estimates of the fundus parameters obtained as a result of solving the inverse problem are reasonable.

  12. Molar absorptivities of glucose and other biological molecules in aqueous solutions over the first overtone and combination regions of the near-infrared spectrum.

    PubMed

    Amerov, Airat K; Chen, Jun; Arnold, Mark A

    2004-10-01

    Molar absorptivities are measured for water, glucose, alanine, ascorbate, lactate, triacetin, and urea in the near-infrared spectral region at 37 degrees C. Values are based on the Beer-Lambert law and cover the first overtone (1550-1850 nm; 6450-5400 cm(-1)) and combination (2000-2500 nm; 4000-5000 cm(-1)) spectral windows through aqueous media. Accurate calculations demand accounting for the impact of water displacement upon dissolution of solute. In this regard, water displacement coefficients are measured and reported for each solute. First overtone absorptivities range from 2 to 7 x 10(-5) mM(-1)mm(-1) for all solutes except urea, for which absorptivity values are below 0.5 x 10(-5) mM(-1) mm(-1) across this spectral range. Molar absorptivities over the combination spectral region range from 0.8 to 3.2 x 10(-4) mM(-1) mm(-1), which is a factor of four to five greater than the first overtone absorptivities. Accuracy of the measured values is assessed by comparing calculated or modeled spectra with spectra measured from standard solutions. This comparison reveals accurately modeled spectra in terms of magnitude and position of solute absorption bands. Both actual and modeled spectra from glucose solutions reveal positive and negative absorbance values depending on the measurement wavelength. It is shown that the net absorbance of light is controlled by the magnitude of the absorptivity of glucose compared to the product of the absorptivity of water and the water displacement coefficient for glucose.

  13. Quantum-Confined and Enhanced Optical Absorption of Colloidal PbS Quantum Dots at Wavelengths with Expected Bulk Behavior.

    PubMed

    Debellis, Doriana; Gigli, Giuseppe; Ten Brinck, Stephanie; Infante, Ivan; Giansante, Carlo

    2017-02-08

    Nowadays it is well-accepted to attribute bulk-like optical absorption properties to colloidal PbS quantum dots (QDs) at wavelengths above 400 nm. This assumption permits to describe PbS QD light absorption by using bulk optical constants and to determine QD concentration in colloidal solutions from simple spectrophotometric measurements. Here we demonstrate that PbS QDs experience the quantum confinement regime across the entire near UV-vis-NIR spectral range, therefore also between 350 and 400 nm already proposed to be sufficiently far above the band gap to suppress quantum confinement. This effect is particularly relevant for small PbS QDs (with diameter of ≤4 nm) leading to absorption coefficients that largely differ from bulk values (up to ∼40% less). As a result of the broadband quantum confinement and of the high surface-to-volume ratio peculiar of nanocrystals, suitable surface chemical modification of PbS QDs is exploited to achieve a marked, size-dependent enhancement of the absorption coefficients compared to bulk values (up to ∼250%). We provide empirical relations to determine the absorption coefficients at 400 nm of as-synthesized and ligand-exchanged PbS QDs, accounting for the broadband quantum confinement and suggesting a heuristic approach to qualitatively predict the ligand effects on the optical absorption properties of PbS QDs. Our findings go beyond formalisms derived from Maxwell Garnett effective medium theory to describe QD optical properties and permit to spectrophotometrically calculate the concentration of PbS QD solutions avoiding underestimation due to deviations from the bulk. In perspective, we envisage the use of extended π-conjugated ligands bearing electronically active substituents to enhance light-harvesting in QD solids and suggest the inadequacy of the representation of ligands at the QD surface as mere electric dipoles.

  14. The Corrected Eta-Squared Coefficient: A Value Added Approach.

    ERIC Educational Resources Information Center

    Barnette, J. Jackson; McLean, James E.

    Eta-Squared (ES) is often used as a measure of strength of association of an effect, a measure often associated with effect size. It is also considered the proportion of total variance accounted for by an independent variable. It is simple to compute and interpret. However, it has one critical weakness cited by several authors (C. Huberty, 1994;…

  15. Measurement of the x-ray mass attenuation coefficients of gold in the 38-50-keV energy range

    SciTech Connect

    Islam, M T; Rae, N A; Glover, J L; Barnea, Z; de Jonge, M D; Tran, C Q; Wang, J; Chantler, C T

    2010-11-12

    We used synchrotron x rays to measure the x-ray mass attenuation coefficients of gold at nine energies from 38 to 50 keV with accuracies of 0.1%. Our results are much more accurate than previous measurements in this energy range. A comparison of our measurements with calculated mass attenuation coefficients shows that our measurements fall almost exactly midway between the XCOM and FFAST calculated theoretical values, which differ from one another in this energy region by about 4%, even though the range includes no absorption edge. The consistency and accuracy of these measurements open the way to investigations of the x-ray attenuation in the region of the L absorption edge of gold.

  16. Enhanced absorption cycle computer model

    NASA Astrophysics Data System (ADS)

    Grossman, G.; Wilk, M.

    1993-09-01

    Absorption heat pumps have received renewed and increasing attention in the past two decades. The rising cost of electricity has made the particular features of this heat-powered cycle attractive for both residential and industrial applications. Solar-powered absorption chillers, gas-fired domestic heat pumps, and waste-heat-powered industrial temperature boosters are a few of the applications recently subjected to intensive research and development. The absorption heat pump research community has begun to search for both advanced cycles in various multistage configurations and new working fluid combinations with potential for enhanced performance and reliability. The development of working absorption systems has created a need for reliable and effective system simulations. A computer code has been developed for simulation of absorption systems at steady state in a flexible and modular form, making it possible to investigate various cycle configurations with different working fluids. The code is based on unit subroutines containing the governing equations for the system's components and property subroutines containing thermodynamic properties of the working fluids. The user conveys to the computer an image of his cycle by specifying the different subunits and their interconnections. Based on this information, the program calculates the temperature, flow rate, concentration, pressure, and vapor fraction at each state point in the system, and the heat duty at each unit, from which the coefficient of performance (COP) may be determined. This report describes the code and its operation, including improvements introduced into the present version. Simulation results are described for LiBr-H2O triple-effect cycles, LiCl-H2O solar-powered open absorption cycles, and NH3-H2O single-effect and generator-absorber heat exchange cycles. An appendix contains the user's manual.

  17. Computing spatial information from Fourier coefficient distributions.

    PubMed

    Heinz, William F; Werbin, Jeffrey L; Lattman, Eaton; Hoh, Jan H

    2011-05-01

    The spatial relationships between molecules can be quantified in terms of information. In the case of membranes, the spatial organization of molecules in a bilayer is closely related to biophysically and biologically important properties. Here, we present an approach to computing spatial information based on Fourier coefficient distributions. The Fourier transform (FT) of an image contains a complete description of the image, and the values of the FT coefficients are uniquely associated with that image. For an image where the distribution of pixels is uncorrelated, the FT coefficients are normally distributed and uncorrelated. Further, the probability distribution for the FT coefficients of such an image can readily be obtained by Parseval's theorem. We take advantage of these properties to compute the spatial information in an image by determining the probability of each coefficient (both real and imaginary parts) in the FT, then using the Shannon formalism to calculate information. By using the probability distribution obtained from Parseval's theorem, an effective distance from the uncorrelated or most uncertain case is obtained. The resulting quantity is an information computed in k-space (kSI). This approach provides a robust, facile and highly flexible framework for quantifying spatial information in images and other types of data (of arbitrary dimensions). The kSI metric is tested on a 2D Ising model, frequently used as a model for lipid bilayer; and the temperature-dependent phase transition is accurately determined from the spatial information in configurations of the system.

  18. Series extension: predicting approximate series coefficients from a finite number of exact coefficients

    NASA Astrophysics Data System (ADS)

    Guttmann, Anthony J.

    2016-10-01

    Given the first 20-100 coefficients of a typical generating function of the type that arises in many problems of statistical mechanics or enumerative combinatorics, we show that the method of differential approximants performs surprisingly well in predicting (approximately) subsequent coefficients. These can then be used by the ratio method to obtain improved estimates of critical parameters. In favourable cases, given only the first 20 coefficients, the next 100 coefficients are predicted with useful accuracy. More surprisingly, this is also the case when the method of differential approximants does not do a useful job in estimating the critical parameters, such as those cases in which one has stretched exponential asymptotic behaviour. Nevertheless, the coefficients are predicted with surprising accuracy. As one consequence, significant computer time can be saved in enumeration problems where several runs would normally be made, modulo different primes, and the coefficients constructed from their values modulo different primes. Another is in the checking of newly calculated coefficients. We believe that this concept of approximate series extension opens up a whole new chapter in the method of series analysis.

  19. A generalized concordance correlation coefficient for continuous and categorical data.

    PubMed

    King, T S; Chinchilli, V M

    2001-07-30

    This paper discusses a generalized version of the concordance correlation coefficient for agreement data. The concordance correlation coefficient evaluates the accuracy and precision between two measures, and is based on the expected value of the squared function of distance. We have generalized this coefficient by applying alternative functions of distance to produce more robust versions of the concordance correlation coefficient. In this paper we extend the application of this class of estimators to categorical data as well, and demonstrate similarities to the kappa and weighted kappa statistics. We also introduce a stratified concordance correlation coefficient which adjusts for explanatory factors, and an extended concordance correlation coefficient which measures agreement among more than two responses. With these extensions, the generalized concordance correlation coefficient provides a unifying approach to assessing agreement among two or more measures that are either continuous or categorical in scale.

  20. Water absorption of poly(methyl methacrylate) containing 4-methacryloxyethyl trimellitic anhydride.

    PubMed

    Unemori, Masako; Matsuya, Yoko; Matsuya, Shigeki; Akashi, Akane; Akamine, Akifumi

    2003-04-01

    The amount of water absorption of poly(methyl methacrylate) (PMMA) containing 0, 1, 3 and 5 wt% of an adhesive monomer, 4-methacryloxyethyl trimellitic anhydride (4-META), was measured at 7 degrees C, 37 degrees C and 60 degrees C. After the water uptake reached equilibrium in specimens, they were desorbed to obtain a constant value and the absorption process was repeated. Mass changes in the second desorption were recorded for the storage temperatures of 37 degrees C and 60 degrees C. Multiple regression analyses were conducted on three independent variables, 4-META concentration, storage temperature and absorption-desorption cycle. A statistically significant relationship was found between the maximum water uptake and 4-META concentration, while there was no relationship between the maximum water uptake and diffusion coefficient obtained using the Fick's law. The negative relationship in the latter did not support the free space theory. The significant and positive relationship between the maximum water uptake and 4-META concentration demonstrates that water molecules diffuse through the formation of a hydrogen bond at polar sites. The maximum water uptake was not influenced by temperature, while the diffusion coefficient increased with the rise in temperature. The activation energy was 41-47 and 50-53 kJ/mol in the first and second absorption tests, respectively.

  1. Incomplete intestinal absorption of fructose.

    PubMed Central

    Kneepkens, C M; Vonk, R J; Fernandes, J

    1984-01-01

    Intestinal D-fructose absorption in 31 children was investigated using measurements of breath hydrogen. Twenty five children had no abdominal symptoms and six had functional bowel disorders. After ingestion of fructose (2 g/kg bodyweight), 22 children (71%) showed a breath hydrogen increase of more than 10 ppm over basal values, indicating incomplete absorption: the increase averaged 53 ppm, range 12 to 250 ppm. Four of these children experienced abdominal symptoms. Three of the six children with bowel disorders showed incomplete absorption. Seven children were tested again with an equal amount of glucose, and in three of them also of galactose, added to the fructose. The mean maximum breath hydrogen increases were 5 and 10 ppm, respectively, compared with 103 ppm after fructose alone. In one boy several tests were performed with various sugars; fructose was the only sugar incompletely absorbed, and the effect of glucose on fructose absorption was shown to be dependent on the amount added. It is concluded that children have a limited absorptive capacity for fructose. We speculate that the enhancing effect of glucose and galactose on fructose absorption may be due to activation of the fructose carrier. Apple juice in particular contains fructose in excess of glucose and could lead to abdominal symptoms in susceptible children. PMID:6476870

  2. Coefficient Alpha: A Reliability Coefficient for the 21st Century?

    ERIC Educational Resources Information Center

    Yang, Yanyun; Green, Samuel B.

    2011-01-01

    Coefficient alpha is almost universally applied to assess reliability of scales in psychology. We argue that researchers should consider alternatives to coefficient alpha. Our preference is for structural equation modeling (SEM) estimates of reliability because they are informative and allow for an empirical evaluation of the assumptions…

  3. Algorithm development for predicting biodiversity based on phytoplankton absorption

    NASA Astrophysics Data System (ADS)

    Moisan, Tiffany A. H.; Moisan, John R.; Linkswiler, Matthew A.; Steinhardt, Rachel A.

    2013-03-01

    Ocean color remote sensing has provided the scientific community with unprecedented global coverage of chlorophyll a, an indicator of phytoplankton biomass. Together, satellite-derived chlorophyll a and knowledge of Phytoplankton Functional Types (PFTs) will improve our limited understanding of marine ecosystem responses to physiochemical climate drivers involved in carbon cycle dynamics and linkages. Using cruise data from the Gulf of Maine and the Middle Atlantic Bight (N=269 pairs of HPLC and phytoplankton absorption samples), two modeling approaches were utilized to predict phytoplankton absorption and pigments. Algorithm I predicts the chlorophyll-specific absorption coefficient (aph* (m2 mg chl a-1)) using inputs of temperature, light, and chlorophyll a. Modeled r2 values (400-700 nm) ranged from 0.79 to 0.99 when compared to in situ observations with ˜25% lower r2 values in the UV region. Algorithm II-a utilizes matrix inversion analysis to predict a(m-1, 400-700 nm) and r2 values ranged from 0.89 to 0.99. The prediction of phytoplankton pigments with Algorithm II-b produced r2 values that ranged from 0.40 to 0.93. When used in combination, Algorithm I, and Algorithm II-a are able to use satellite products of SST, PAR, and chlorophyll a (Algorithm I) to predict pigment concentrations and ratios to describe the phytoplankton community. The results of this study demonstrate that the spatial variation in modeled pigment ratios differ significantly from the 10-year SeaWiFS average chlorophyll a data set. Contiguous observations of chlorophyll a and phytoplankton biodiversity will elucidate ecosystem responses with unprecedented complexity.

  4. The gastrointestinal absorption of the actinide elements.

    PubMed

    Harrison, J D

    1991-03-01

    The greatest uncertainty in dose estimates for the ingestion of long-lived, alpha-emitting isotopes of the actinide elements is in the values used for their fractional absorption from the gastrointestinal tract (f1 values). Recent years have seen a large increase in the available data on actinide absorption. Human data are reviewed here, together with animal data, to illustrate the effect on absorption of chemical form, incorporation into food materials, fasting and other dietary factors, and age at ingestion. The f1 values recommended by the International Commission on Radiological Protection, by an Expert Group of the Nuclear Energy Agency and by the National Radiological Protection Board are discussed.

  5. Intraband optical absorption in a single quantum ring: Hydrostatic pressure and intense laser field effects

    NASA Astrophysics Data System (ADS)

    Barseghyan, M. G.

    2016-11-01

    The intraband optical absorption in GaAs/Ga0.7Al0.3As two-dimensional single quantum ring is investigated. Considering the combined effects of hydrostatic pressure and intense laser field the energy of the ground and few excited states has been found using the effective mass approximation and exact diagonalization technique. The energies of these states and the corresponding threshold energy of the intraband optical transitions are examined as a function of hydrostatic pressure for the different values of the laser field parameter. We also investigated the dependencies of the intraband optical absorption coefficient as a function of incident photon energy for different values of hydrostatic pressure and laser field parameter. It is found that the effects of hydrostatic pressure and intense laser field lead to redshift and blueshift of the intraband optical spectrum respectively.

  6. Verification of a two-layer inverse Monte Carlo absorption model using multiple source-detector separation diffuse reflectance spectroscopy.

    PubMed

    Sharma, Manu; Hennessy, Ricky; Markey, Mia K; Tunnell, James W

    2013-12-02

    A two-layer Monte Carlo lookup table-based inverse model is validated with two-layered phantoms across physiologically relevant optical property ranges. Reflectance data for source-detector separations of 370 μm and 740 μm were collected from these two-layered phantoms and top layer thickness, reduced scattering coefficient and the top and bottom layer absorption coefficients were extracted using the inverse model and compared to the known values. The results of the phantom verification show that this method is able to accurately extract top layer thickness and scattering when the top layer thickness ranges from 0 to 550 μm. In this range, top layer thicknesses were measured with an average error of 10% and the reduced scattering coefficient was measured with an average error of 15%. The accuracy of top and bottom layer absorption coefficient measurements was found to be highly dependent on top layer thickness, which agrees with physical expectation; however, within appropriate thickness ranges, the error for absorption properties varies from 12-25%.

  7. Verification of a two-layer inverse Monte Carlo absorption model using multiple source-detector separation diffuse reflectance spectroscopy

    PubMed Central

    Sharma, Manu; Hennessy, Ricky; Markey, Mia K.; Tunnell, James W.

    2013-01-01

    A two-layer Monte Carlo lookup table-based inverse model is validated with two-layered phantoms across physiologically relevant optical property ranges. Reflectance data for source-detector separations of 370 μm and 740 μm were collected from these two-layered phantoms and top layer thickness, reduced scattering coefficient and the top and bottom layer absorption coefficients were extracted using the inverse model and compared to the known values. The results of the phantom verification show that this method is able to accurately extract top layer thickness and scattering when the top layer thickness ranges from 0 to 550 μm. In this range, top layer thicknesses were measured with an average error of 10% and the reduced scattering coefficient was measured with an average error of 15%. The accuracy of top and bottom layer absorption coefficient measurements was found to be highly dependent on top layer thickness, which agrees with physical expectation; however, within appropriate thickness ranges, the error for absorption properties varies from 12–25%. PMID:24466475

  8. Investigation of absorption and scattering characteristics of kiwifruit tissue using a single integrating sphere system*

    PubMed Central

    Fang, Zhen-huan; Fu, Xia-ping; He, Xue-ming

    2016-01-01

    For a quantitative understanding of light interaction with fruit tissue, it is critical to obtain two fundamental parameters: the absorption coefficient and the scattering coefficient of the tissue. This study was to investigate the optical properties of kiwifruit tissue at the wavelength of 632.8 nm. The total reflectance and total transmittance of kiwifruit tissue from three parts (including the flesh part, the seed part, and the seed-base part) were measured using a single integrating sphere system. Based on the measured spectral signals, the absorption coefficient μ a and the reduced scattering coefficient μ s' of kiwifruit tissue were calculated using the inverse adding-doubling (IAD) method. Phantoms made from Intralipid 20% and India ink as well as a Biomimic solid phantom were used for system validation. The mean values of μ a and μ s' of different parts of the kiwifruit were 0.031–0.308 mm−1 and 0.120–0.946 mm−1, respectively. The results showed significant differences among the μ a and μ s' of the three parts of the kiwifruit. The results of this study confirmed the importance of studying the optical properties for a quantitative understanding of light interaction with fruit tissue. Further investigation of fruit optical properties will be extended to a broader spectral region and different kinds of fruits. PMID:27256682

  9. Excitation and temperature dependent exciton-carrier transport in CVD diamond: Diffusion coefficient, recombination lifetime and diffusion length

    NASA Astrophysics Data System (ADS)

    Ščajev, Patrik

    2017-04-01

    Time-resolved induced absorption (IA) and light induced transient grating (LITG) techniques were applied for the investigation of nonequilibrium exciton-carrier diffusion and recombination processes in a high-purity CVD diamond. Injection range from 1015 to 1020 cm-3 carrier density was achieved by combining one photon and two photon excitations. The measurements were performed in the 10-750 K temperature range. The LITG diffusion coefficient peaked at 44 cm2/s value at room temperature under low injection conditions. At lower temperatures it transferred to much lower exciton diffusion coefficient. A strong decrease of diffusion coefficient under higher injection conditions was explained by exciton formation with a low diffusion coefficient and many body effects, as polyexciton and electron-hole droplet formation. High temperature phonon-limited diffusion coefficient was weakly injection dependent. Low excitation carrier lifetime was about 700 ns above 200 K. At lower temperatures, the decay time reduced by two orders of magnitude, which was explained by the formation of biexcitons. At lowest temperatures, an increase of the carrier recombination rate at high injection was attributed to Auger recombinations of polyexcitons and electron-hole droplets. While at high temperatures, the increase of the recombination rate with 490 meV activation energy was observed. The combination of IA and LITG measurements provided effective diffusion lengths in a 0.3-50 μm range, being strongly dependent on the excess carrier density and temperature.

  10. Microwave absorption measurements of melting spherical and nonspherical hydrometeors

    NASA Technical Reports Server (NTRS)

    Hansman, R. J., Jr.

    1986-01-01

    Measurements were made of the absorption behavior of melting and freezing hydrometeors using resonant cavity perturbation techniques at a wavelength of 2.82 cm. Melting ice spheres with equivalent melted diameters between 1.15 and 2.00 mm exhibit a period of strong absorption during melting as predicted by prior theoretical calculations. However, the measured magnitude of the absorption peak exceeds the predicted value. Absorption measuremets of melting oblate and prolate ice ellipsoids also exhibit enhanced absorption during melting.

  11. Measurement of the x-ray mass attenuation coefficient and determination of the imaginary component of the atomic form factor of tin over the energy range of 29-60keV

    NASA Astrophysics Data System (ADS)

    de Jonge, Martin D.; Tran, Chanh Q.; Chantler, Christopher T.; Barnea, Zwi; Dhal, Bipin B.; Paterson, David; Kanter, Elliot P.; Southworth, Stephen H.; Young, Linda; Beno, Mark A.; Linton, Jennifer A.; Jennings, Guy

    2007-03-01

    We use the x-ray extended-range technique (XERT) [C. T. Chantler , Phys. Rev. A 64, 062506 (2001)] to measure the mass attenuation coefficients of tin in the x-ray energy range of 29-60keV to 0.04-3% accuracy, and typically in the range 0.1-0.2% . Measurements made over an extended range of the measurement parameter space are critically examined to identify, quantify, and correct a number of potential experimental systematic errors. These results represent the most extensive experimental data set for tin and include absolute mass attenuation coefficients in the regions of x-ray absorption fine structure, extended x-ray absorption fine structure, and x-ray absorption near-edge structure. The imaginary component of the atomic form factor f2 is derived from the photoelectric absorption after subtracting calculated Rayleigh and Compton scattering cross sections from the total attenuation. Comparison of the result with tabulations of calculated photoelectric absorption coefficients indicates that differences of 1-2% persist between calculated and observed values.

  12. Electromagnetic absorption properties of spacecraft and space debris

    NASA Astrophysics Data System (ADS)

    Micheli, D.; Santoni, F.; Giusti, A.; Delfini, A.; Pastore, R.; Vricella, A.; Albano, M.; Arena, L.; Piergentili, F.; Marchetti, M.

    2017-04-01

    Aim of the work is to present a method to evaluate the electromagnetic absorption properties of spacecraft and space debris. For these objects, the radar detection ability depends mainly on volume, shape, materials type and other electromagnetic reflecting behaviour of spacecraft surface components, such as antennas or thermal blankets, and of metallic components in space debris. The higher the electromagnetic reflection coefficient of such parts, the greater the radar detection possibility. In this research an electromagnetic reverberation chamber is used to measure the absorption cross section (ACS) of four objects which may represent space structure operating components as well as examples of space debris: a small satellite, a composite antenna dish, a Thermal Protection System (TPS) tile and a carbon-based composite missile shell. The ACS mainly depends on geometrical characteristics like apertures, face numbers and bulk porosity, as well as on the type of the material itself. The ACS, which is an electromagnetic measurement, is expressed in squared meters and thus can be compared with the objects geometrical cross section. A small ACS means a quite electromagnetic reflective tendency, which is beneficial for radar observations; on the contrary, high values of ACS indicate a strong absorption of the electromagnetic field, which in turn can result a critical hindering of radar tracking.

  13. Measurement of the iodine partition coefficient

    SciTech Connect

    Furrer, M.; Cripps, R.C.; Gubler, R.

    1985-08-01

    The hydrolysis of iodine is complicated because it involves a number of species that differ considerably in their individual volatilities. Large uncertainties exist in the thermodynamic data of some of the iodine species, especially at temperatures above 25C. Because of this, an experiment was undertaken to measure the partition coefficient under varying physical and chemical conditions. Measurements of P were made for a temperature range of 21 to 113C under well-defined conditions (liquid molar concentration, pH, and redox potential) for inorganic iodine. The experimental results are interpreted with the aid of an analytical model and published thermodynamic data. A good agreement between calculated and measured values was found. The experimental setup allows the determination of very high partition coefficients up to a value of 2.0 X 10W. This is demonstrated by adding cesium-iodide to the fuel pool water of a boiling water reactor.

  14. Triple effect absorption chiller utilizing two refrigeration circuits

    DOEpatents

    DeVault, Robert C.

    1988-01-01

    A triple effect absorption method and apparatus having a high coefficient of performance. Two single effect absorption circuits are combined with heat exchange occurring between a condenser and absorber of a high temperature circuit, and a generator of a low temperature circuit. The evaporators of both the high and low temperature circuits provide cooling to an external heat load.

  15. Analysis of a heat transfer device for measuring film coefficients

    NASA Technical Reports Server (NTRS)

    Medrow, R. A.; Johnson, R. L.; Loomis, W. R.; Wedeven, L. D.

    1975-01-01

    A heat transfer device consisting of a heated rotating cylinder in a bath was analyzed for its effectiveness to determine heat transfer coefficient of fluids. A time dependent analysis shows that the performance is insensitive to the value of heat transfer coefficient with the given rig configuration.

  16. Biases and Standard Errors of Standardized Regression Coefficients

    ERIC Educational Resources Information Center

    Yuan, Ke-Hai; Chan, Wai

    2011-01-01

    The paper obtains consistent standard errors (SE) and biases of order O(1/n) for the sample standardized regression coefficients with both random and given predictors. Analytical results indicate that the formulas for SEs given in popular text books are consistent only when the population value of the regression coefficient is zero. The sample…

  17. A program to compute aquifer-response coefficients

    USGS Publications Warehouse

    Maddock, Thomas

    1974-01-01

    An alternating direction technique is used to solve finite difference equations approximating the flow of water in an aquifer. The solutions produce response coefficients relating pumping from wells to drawdowns within those wells. The product of the response coefficient with the pumping values produces a linear algebraic technological function that can be used for integrating hydrologic phenomena into planning and management models.

  18. An Investigation of the Sampling Distributions of Equating Coefficients.

    ERIC Educational Resources Information Center

    Baker, Frank B.

    1996-01-01

    Using the characteristic curve method for dichotomously scored test items, the sampling distributions of equating coefficients were examined. Simulations indicate that for the equating conditions studied, the sampling distributions of the equating coefficients appear to have acceptable characteristics, suggesting confidence in the values obtained…

  19. Measurements of argon broadened Lorentz width and pressure-induced line shift coefficients in the nu4 band of (C-12)H4

    NASA Technical Reports Server (NTRS)

    Rinsland, Curtis P.; Smith, Mary Ann H.; Devi, V. Malathy; Benner, D. Chris

    1989-01-01

    Room temperature argon broadened halfwidth and pressure-induced line shift coefficients have been determined for 118 transitions in the nu4 band of (C-12)H4 from analysis of high resolution laboratory absorption spectra recorded with the McMath Fourier transform spectrometer operated on Kitt Peak by the National Solar Observatory. Transitions up to J-double-prime = 12 have been measured using a nonlinear least-squares spectral fitting procedure. The variation of the measured halfwidth coefficients with symmetry type and rotational quantum number is very similar to that measured previously for N2 and air broadening, but the absolute values of the argon broadening coefficients are all smaller. On average, the ratio of the argon broadened halfwidth coefficient to the corresponding N2 broadened halfwidth coefficient is 0.877 + or - 0.017 (2 Sigma). More than 95 percent of the pressure-induced shifts are negative with values ranging from -0.0081 to +0.0055/cm atm. The pressure shifts in argon are nearly equal to corresponding values measured previously in N2 and air.

  20. Convection in axially symmetric accretion discs with microscopic transport coefficients

    NASA Astrophysics Data System (ADS)

    Malanchev, K. L.; Postnov, K. A.; Shakura, N. I.

    2017-01-01

    The vertical structure of stationary thin accretion discs is calculated from the energy balance equation with heat generation due to microscopic ion viscosity η and electron heat conductivity κ, both depending on temperature. In the optically thin discs it is found that for the heat conductivity increasing with temperature, the vertical temperature gradient exceeds the adiabatic value at some height, suggesting convective instability in the upper disc layer. There is a critical Prandtl number, Pr = 4/9, above which a Keplerian disc become fully convective. The vertical density distribution of optically thin laminar accretion discs as found from the hydrostatic equilibrium equation cannot be generally described by a polytrope but in the case of constant viscosity and heat conductivity. In the optically thick discs with radiation heat transfer, the vertical disc structure is found to be convectively stable for both absorption-dominated and scattering-dominated opacities, unless a very steep dependence of the viscosity coefficient on temperature is assumed. A polytropic-like structure in this case is found for Thomson scattering-dominated opacity.

  1. Low-Absorption Liquid Crystals for Infrared Beam Steering

    DTIC Science & Technology

    2014-10-17

    goals are: ri~0.2 (at-tSilri),*? (at 1 kHz), and absorption coefficient B 5/cm. 15. SUBJECT TERMS Low absorption, MWIR, chlorinated liquid crystals...spectral region of interest by deuteration, fluorination and chlorination ; 2) Employing thin cell gap by choosing a high birefringence liquid crystal...mixture. First, we synthesized several chlorinated terphenyls and made a eutectic mixture showing a low absorption window in the region of 4-5|a.m

  2. Two and four photon absorption and nonlinear refraction in undoped, chromium doped and copper doped ZnS quantum dots

    NASA Astrophysics Data System (ADS)

    Sharma, Dimple; Malik, B. P.; Gaur, Arun

    2015-12-01

    The ZnS quantum dots (QDs) with Cr and Cu doping were synthesized by chemical co-precipitation method. The nanostructures of the prepared undoped and doped ZnS QDs were characterized by UV-vis spectroscopy, Transmission electron microscopy (TEM) and X-ray diffraction (XRD). The sizes of QDs were found to be within 3-5 nm range. The nonlinear parameters viz. Two photon absorption coefficient (β2), nonlinear refractive index (n2), third order nonlinear susceptibility (χ3) at wavelength 532 nm and Four photon absorption coefficient (β4) at wavelength 1064 nm have been calculated by Z-scan technique using nanosecond Nd:YAG laser in undoped, Cr doped and Cu doped ZnS QDs. Higher values of nonlinear parameters for doped ZnS infer that they are potential material for the development of photonics devices and sensor protection applications.

  3. A program for calculating and plotting soft x-ray optical interaction coefficients for molecules

    SciTech Connect

    Thomas, M.M.; Davis, J.C.; Jacobsen, C.J.; Perera, R.C.C.

    1989-08-01

    Comprehensive tables for atomic scattering factor components, f1 and f2, were compiled by Henke et al. for the extended photon region 50 - 10000 eV. Accurate calculations of optical interaction coefficients for absorption, reflection and scattering by material systems (e.g. filters, multi-layers, etc...), which have widespread application, can be based simply upon the atomic scattering factors for the elements comprising the material, except near the absorption threshold energies. These calculations based upon the weighted sum of f1 and f2 for each atomic species present can be very tedious if done by hand. This led us to develop a user friendly program to perform these calculations on an IBM PC or compatible computer. By entering the chemical formula, density and thickness of up to six molecules, values of the f1, f2, mass absorption transmission efficiencies, attenuation lengths, mirror reflectivities and complex indices of refraction can be calculated and plotted as a function of energy or wavelength. This program will be available distribution. 7 refs., 1 fig.

  4. Estimating varying coefficients for partial differential equation models.

    PubMed

    Zhang, Xinyu; Cao, Jiguo; Carroll, Raymond J

    2017-01-11

    Partial differential equations (PDEs) are used to model complex dynamical systems in multiple dimensions, and their parameters often have important scientific interpretations. In some applications, PDE parameters are not constant but can change depending on the values of covariates, a feature that we call varying coefficients. We propose a parameter cascading method to estimate varying coefficients in PDE models from noisy data. Our estimates of the varying coefficients are shown to be consistent and asymptotically normally distributed. The performance of our method is evaluated by a simulation study and by an empirical study estimating three varying coefficients in a PDE model arising from LIDAR data.

  5. Effect of kinetic boundary condition on the thermal transpiration coefficient

    NASA Astrophysics Data System (ADS)

    Sugimoto, Hiroshi; Amakawa, Kenjiro

    2014-12-01

    The effect of kinetic boundary condition on the free molecular thermal transpiration coefficient γ is analyzed numerically. The Maxwell model boundary condition is applied in its original form in the sense that its accommodation coefficient depends on the speed of incident molecules. The results show that the value of γ depends much on the velocity dependency of the accommodation coefficient. The experimental result, γ < 0.5, can be reproduced if the grazing molecules reflect diffusely. This makes a sharp contrast with the previous works that γ =0.5 for the velocity independent accommodation coefficient.

  6. New consistency tests for high-accuracy measurements of X-ray mass attenuation coefficients by the X-ray extended-range technique

    SciTech Connect

    Chantler, C.T.; Islam, M.T.; Rae, N.A.; Tran, C.Q.; Glover, J.L.; Barnea, Z.

    2012-09-25

    An extension of the X-ray extended-range technique is described for measuring X-ray mass attenuation coefficients by introducing absolute measurement of a number of foils - the multiple independent foil technique. Illustrating the technique with the results of measurements for gold in the 38-50 keV energy range, it is shown that its use enables selection of the most uniform and well defined of available foils, leading to more accurate measurements; it allows one to test the consistency of independently measured absolute values of the mass attenuation coefficient with those obtained by the thickness transfer method; and it tests the linearity of the response of the counter and counting chain throughout the range of X-ray intensities encountered in a given experiment. In light of the results for gold, the strategy to be ideally employed in measuring absolute X-ray mass attenuation coefficients, X-ray absorption fine structure and related quantities is discussed.

  7. The saturable absorption and reverse saturable absorption properties of Cu doped zinc oxide thin films

    NASA Astrophysics Data System (ADS)

    Yao, Cheng-Bao; Wen, Xin; Li, Qiang-Hua; Yan, Xiao-Yan; Li, Jin; Zhang, Ke-Xin; Sun, Wen-Jun; Bai, Li-Na; Yang, Shou-Bin

    2017-03-01

    We present the structure and nonlinear absorption (NLA) properties of Cu-doped ZnO (CZO) films prepared by magnetron sputtering. The films were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The results show that the CZO films can maintain a wurtzite structure. Furthermore, the open-aperture (OA) Z-scan measurements of the film were carried out by nanosecond laser pulse. A transition from saturable absorption (SA) to reverse saturable absorption (RSA) was observed as the excitation intensity increasing. With good excellent nonlinear optical coefficient, the samples were expected to be the potential applications in optical devices.

  8. Valuing Essays: Essaying Values

    ERIC Educational Resources Information Center

    Badley, Graham

    2010-01-01

    The essay regularly comes under attack. It is criticised for being rigidly linear rather than flexible and reflective. I first challenge this view by examining reasons why the essay should be valued as an important genre. Secondly, I propose that in using the essay form students and academics necessarily exemplify their own critical values. Essays…

  9. Phononic glass: a robust acoustic-absorption material.

    PubMed

    Jiang, Heng; Wang, Yuren

    2012-08-01

    In order to achieve strong wide band acoustic absorption under high hydrostatic pressure, an interpenetrating network structure is introduced into the locally resonant phononic crystal to fabricate a type of phononic composite material called "phononic glass." Underwater acoustic absorption coefficient measurements show that the material owns high underwater sound absorption coefficients over 0.9 in 12-30 kHz. Moreover, the quasi-static compressive behavior shows that the phononic glass has a compressive strength over 5 MPa which is crucial for underwater applications.

  10. Determinations of equilibrium segregation, effective segregation and diffusion coefficients for Nd+3 doped in molten YAG

    NASA Astrophysics Data System (ADS)

    Asadian, M.; Saeedi, H.; Yadegari, M.; Shojaee, M.

    2014-06-01

    In this paper, a new mathematical model has been presented to determine the equilibrium segregation (k0) and effective segregation (keff) coefficients for neodymium (Nd) in YAG crystal grown by Czochralski (CZ) method. Determination of diffusion coefficient (DL) of Nd impurity in molten YAG is also investigated. In this model, utilizing Lambert W-function is a new idea to solve the Scheil equation for calculation of effective segregation coefficient. The Nd concentration in the crystal has been measured by optical absorption method to calculate keff. The analyses show that the keff is related to the growth parameters such as crystal growth rate (ug) and crystal rotation rate (ω), ( ug/√{ω}) but it is independent of the Nd concentration in the initial melt (C0). Based on obtained keff and experimental growth data, k0 and DL of Nd in molten YAG have been calculated. For all experiments, the average value of k0=0.216 and DL=1.4×10-6 (cm2/s) are obtained. Our results are corroborated by the theoretical and experimental data from the literature.

  11. Experimental investigation of the iodine partition coefficient

    SciTech Connect

    Kelly, J.L.; Babad, C.J.; Mulder, R.U.

    1985-11-01

    Short-term values of the iodine partition coefficient (IPC) were evaluated experimentally by an air/water system over the following ranges of conditions: temperature = 25 to 70/sup 0/C, pH = 5 to 9, and iodine concentration = 10/sup -9/ to 10/sup -2/ kg iodine/m/sup 3/ H/sub 2/O. The experimental IPC values are relatively independent of temperature over the indicated range, but show a significant dependence on pH and iodine concentration. In basic solutions the short-term values are several orders of magnitude less than the true equilibrium values; in acid solutions, the differences are much less. These results are useful for predicting the disposition of iodine shortly (i.e., 1 to 10 h) after iodine has been released into an air/water environment.

  12. Manning's roughness coefficient for Illinois streams

    USGS Publications Warehouse

    Soong, David T.; Prater, Crystal D.; Halfar, Teresa M.; Wobig, Loren A.

    2012-01-01

    Manning's roughness coefficients for 43 natural and constructed streams in Illinois are reported and displayed on a U.S. Geological Survey Web site. At a majority of the sites, discharge and stage were measured, and corresponding Manning's coefficients—the n-values—were determined at more than one river discharge. The n-values discussed in this report are computed from data representing the stream reach studied and, therefore, are reachwise values. Presentation of the resulting n-values takes a visual-comparison approach similar to the previously published Barnes report (1967), in which photographs of channel conditions, description of the site, and the resulting n-values are organized for each site. The Web site where the data can be accessed and are displayed is at URL http://il.water.usgs.gov/proj/nvalues/.

  13. Analysis of frequency dependent pump light absorption

    NASA Astrophysics Data System (ADS)

    Wohlmuth, Matthias; Pflaum, Christoph

    2011-03-01

    Simulations have to accurately model thermal lensing in order to help improving resonator design of diode pumped solid state lasers. To this end, a precise description of the pump light absorption is an important prerequisite. In this paper, we discuss the frequency dependency of the pump light absorption in the laser crystal and its influence on the simulated laser performance. The results show that the pump light absorption has to include the spectral overlap of the emitting pump source and the absorbing laser material. This information can either be used for a fully frequency dependent absorption model or, at least in the shown examples, to compute an effective value for an exponential Beer-Lambert law of absorption. This is particularly significant at pump wavelengths coinciding with a peak of absorption. Consequences for laser stability and performance are analyzed for different pump wavelengths in a Nd:YAG laser.

  14. Sound absorption by clamped poroelastic plates.

    PubMed

    Aygun, H; Attenborough, K

    2008-09-01

    Measurements and predictions have been made of the absorption coefficient and the surface acoustic impedance of poroelastic plates clamped in a large impedance tube and separated from the rigid termination by an air gap. The measured and predicted absorption coefficient and surface impedance spectra exhibit low frequency peaks. The peak frequencies observed in the absorption coefficient are close to those predicted and measured in the deflection spectra of the clamped poroelastic plates. The influences of the rigidity of the clamping conditions and the width of the air gap have been investigated. Both influences are found to be important. Increasing the rigidity of clamping reduces the low frequency absorption peaks compared with those measured for simply supported plates or plates in an intermediate clamping condition. Results for a closed cell foam plate and for two open cell foam plates made from recycled materials are presented. For identical clamping conditions and width of air gap, the results for the different materials differ as a consequence mainly of their different elasticity, thickness, and cell structure.

  15. Deriving brown carbon from multiwavelength absorption measurements: Method and application to AERONET and Aethalometer observations

    SciTech Connect

    Wang, X.; Heald, C. L.; Sedlacek, A.; de Sa, S. S.; Martin, S. T.; Alexander, M. L.; Watson, T. B.; Aiken, A. C.; Springston, S. R.; Artaxo, P.

    2016-10-13

    The radiative impact of organic aerosols (OA) is a large source of uncertainty in estimating the global direct radiative effect (DRE) of aerosols. This radiative impact includes not only light scattering but also light absorption from a subclass of OA referred to as brown carbon (BrC). However the absorption properties of BrC are poorly understood leading to large uncertainties in modelling studies. To obtain observational constraints from measurements, a simple Absorption Ångström Exponent (AAE) method is often used to separate the contribution of BrC absorption from that of black carbon (BC). However, this attribution method is based on assumptions regarding the spectral dependence of BC that are often violated in the ambient atmosphere. Here we develop a new method that decreases the uncertainties associated with estimating BrC absorption. By applying this method to multi-wavelength absorption aerosol optical depth (AAOD) measurements at AERONET sites worldwide and surface aerosol absorption measurements at multiple ambient sites, we estimate that BrC globally contributes 6-40% of the absorption at 440nm. We find that the mass absorption coefficient of OA (OA-MAC) is positively correlated with BC/OA mass ratio. Based on the variability of BC properties and BC/OA emission ratio, we estimate a range of 0.05-1.2 m2/g for OA-MAC at 440nm. Using the combination of AERONET and OMI UV absorption observations we estimate that the AAE388/440nm for BrC is generally ~4 world-wide, with a smaller value in Europe (< 2). Our analyses of two surface sites (Cape Cod, to the southeast of Boston, and the GoAmazon2014/5 T3 site, to the west of Manaus, Brazil) reveal no significant relationship between BrC absorptivity and photochemical aging in typical urban influenced conditions. However, the absorption of BrC measured during the biomass burning season near Manaus is found to decrease with photochemical aging with a lifetime of ~1 day. This lifetime is

  16. Deriving brown carbon from multiwavelength absorption measurements: Method and application to AERONET and Aethalometer observations

    DOE PAGES

    Wang, X.; Heald, C. L.; Sedlacek, A.; ...

    2016-10-13

    The radiative impact of organic aerosols (OA) is a large source of uncertainty in estimating the global direct radiative effect (DRE) of aerosols. This radiative impact includes not only light scattering but also light absorption from a subclass of OA referred to as brown carbon (BrC). However the absorption properties of BrC are poorly understood leading to large uncertainties in modelling studies. To obtain observational constraints from measurements, a simple Absorption Ångström Exponent (AAE) method is often used to separate the contribution of BrC absorption from that of black carbon (BC). However, this attribution method is based on assumptions regardingmore » the spectral dependence of BC that are often violated in the ambient atmosphere. Here we develop a new method that decreases the uncertainties associated with estimating BrC absorption. By applying this method to multi-wavelength absorption aerosol optical depth (AAOD) measurements at AERONET sites worldwide and surface aerosol absorption measurements at multiple ambient sites, we estimate that BrC globally contributes 6-40% of the absorption at 440nm. We find that the mass absorption coefficient of OA (OA-MAC) is positively correlated with BC/OA mass ratio. Based on the variability of BC properties and BC/OA emission ratio, we estimate a range of 0.05-1.2 m2/g for OA-MAC at 440nm. Using the combination of AERONET and OMI UV absorption observations we estimate that the AAE388/440nm for BrC is generally ~4 world-wide, with a smaller value in Europe (< 2). Our analyses of two surface sites (Cape Cod, to the southeast of Boston, and the GoAmazon2014/5 T3 site, to the west of Manaus, Brazil) reveal no significant relationship between BrC absorptivity and photochemical aging in typical urban influenced conditions. However, the absorption of BrC measured during the biomass burning season near Manaus is found to decrease with photochemical aging with a lifetime of ~1 day. This lifetime is comparable to

  17. Effect of octanol:water partition coefficients of organophosphorus compounds on biodistribution and percutaneous toxicity.

    PubMed

    Czerwinski, Steven E; Skvorak, John P; Maxwell, Donald M; Lenz, David E; Baskin, Steven I

    2006-01-01

    Knowledge of partition coefficient (log P) data can play a critical role in understanding the pharmacokinetic and pharmacodistributive properties of toxic organophosphorus (OP) compounds. Using a recently published gas chromatographic method, the octanol:water log P values for the compounds tabun (GA), sarin (GB), cyclosarin (GF), and O-ethyl-S-(2-diisopropylaminoethyl) methylphosphonothiolate (VX) were determined to be 0.384 +/- 0.033, 0.299 +/- 0.016, 1.038 +/- 0.055, and 0.675 +/- 0.070, respectively. Based on these data, the log P value of the fluorophosphonate fragment, common to GB, soman (GD), and GF, was determined to be -2.256 +/- 0.273. The predictive value for absorption and distribution of the determined log P values was compared to measured values. The time to onset of local fasciculations (47.3, 29.0, 8.8, 8.5, and 6.3 min, respectively) in guinea pigs exposed percutaneously to equilethal doses of GA, VX, GF, GB, or GD was used as an indicator of dermal penetration. There was a good correlation (r = 0.95) between the measured log P value and the rate of onset of local fasciculations. Assuming a direct correspondence, equilibrium tissue:blood log P may be estimated from octanol:water log P. Comparison of the estimated and directly measured tissue:blood log P revealed a correlation of 0.8 for GD in liver, muscle, and adipose tissue. Our results demonstrate the use of log P data to both predict absorption and determine the distribution of OP compounds in tissues. This facilitates further estimates of in vivo OP effects from in vitro experiments.

  18. Biologically-based modeling insights in inhaled vapor absorption and dosimetry.

    PubMed

    Morris, John B

    2012-12-01

    The lung is a route of entry and also a target site for inhaled vapors, therefore, knowledge of the total absorbed dose and/or the dose absorbed in each airway during inhalation exposure is essential. Vapor absorption characteristics result primarily from the fact that vapors demonstrate equilibrium/saturation behavior in fluids. Thus, during inhalation exposures blood and airway tissue vapor concentrations increase to a steady state value and increase no further no matter how long the exposure. High tissue concentrations can be obtained with highly soluble vapors, thus solubility, as measured by blood:air partition coefficient, is a fundamentally important physical/chemical characteristic of vapors. While it is classically thought that vapor absorption occurs only in the alveoli it is now understood that this is not the case. Soluble vapors can be efficiently absorbed in the airways themselves and do not necessarily penetrate to the alveolar level. Such vapors are more likely to injure the proximal than distal airways because that is the site of the greatest delivered dose. There are substantial species differences in airway vapor absorption between laboratory animals and humans making interpretation of laboratory animal inhalation toxicity data difficult. Airway absorption is dependent on vapor solubility and is enhanced by local metabolism and/or direct reaction within airway tissues. Modern simulation models that incorporate terms for solubility, metabolism, and reaction rate accurately predict vapor absorption patterns in both animals and humans and have become essential tools for understanding the pharmacology and toxicology of airborne vapors.

  19. CO2 Capture by Absorption with Potassium Carbonate

    SciTech Connect

    Gary T. Rochelle; Marcus Hilliard; Eric Chen; Babatunde Oyenekan; Ross Dugas; John McLees; Andrew Sexton; Daniel Ellenberger

    2005-10-26

    The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. Modeling of stripper performance suggests that vacuum stripping may be an attractive configuration for all solvents. Flexipac 1Y structured packing performs in the absorber as expected. It provides twice as much mass transfer area as IMTP No.40 dumped packing. Independent measurements of CO{sub 2} solubility give a CO{sub 2} loading that is 20% lower than that Cullinane's values with 3.6 m PZ at 100-120 C. The effective mass transfer coefficient (K{sub G}) in the absorber with 5 m K/2.5 m PZ appears to be 0 to 30% greater than that of 30 wt% MEA.

  20. Functional constraints on phenomenological coefficients

    NASA Astrophysics Data System (ADS)

    Klika, Václav; Pavelka, Michal; Benziger, Jay B.

    2017-02-01

    Thermodynamic fluxes (diffusion fluxes, heat flux, etc.) are often proportional to thermodynamic forces (gradients of chemical potentials, temperature, etc.) via the matrix of phenomenological coefficients. Onsager's relations imply that the matrix is symmetric, which reduces the number of unknown coefficients is reduced. In this article we demonstrate that for a class of nonequilibrium thermodynamic models in addition to Onsager's relations the phenomenological coefficients must share the same functional dependence on the local thermodynamic state variables. Thermodynamic models and experimental data should be validated through consistency with the functional constraint. We present examples of coupled heat and mass transport (thermodiffusion) and coupled charge and mass transport (electro-osmotic drag). Additionally, these newly identified constraints further reduce the number of experiments needed to describe the phenomenological coefficient.

  1. Diffusion coefficients in gravel under unsaturated conditions

    SciTech Connect

    Conca, J.L.; Wright, J. )

    1990-05-01

    Diffusion coefficients were experimentally determined in unsaturated gravel to evaluate the effectiveness of gravel as a diffusion barrier to ionic transport in the vadose zone. Water contents were fixed by use of an ultracentrifuge with an ultralow constant rate flow pump supplying solution to the sample via a rotating seal. Once the gravel was at hydraulic steady state, the electrical conductivity was measured, and the diffusion coefficient calculated using the Nernst-Einstein equation. Diffusion coefficient values for potassium ion (D{sub e}) in four types of angular gravel ranged from 1.7 {times} 10{sup {minus}11} m{sup 2}/s (1.7 {times} 10{sup {minus}7} cm{sup 2}/s) for a 6.3-9.5 mm angular granitic gravel at a volumetric water content of 5.5% to 2.2 {times} 10{sup {minus}14} m{sup 2}/s (2.2 {times} 10{sup {minus}10} cm{sup 2}/s) in a 4.0-6.3 mm quartzite gravel at a volumetric water content of 0.47%. Variations in D{sub e} values resulted primarily from differences in water content which depends on gravel type and particle size.

  2. Wrong Signs in Regression Coefficients

    NASA Technical Reports Server (NTRS)

    McGee, Holly

    1999-01-01

    When using parametric cost estimation, it is important to note the possibility of the regression coefficients having the wrong sign. A wrong sign is defined as a sign on the regression coefficient opposite to the researcher's intuition and experience. Some possible causes for the wrong sign discussed in this paper are a small range of x's, leverage points, missing variables, multicollinearity, and computational error. Additionally, techniques for determining the cause of the wrong sign are given.

  3. Donor impurity-related intraband optical absorption in a single quantum ring: Hydrostatic pressure and intense laser field effects

    NASA Astrophysics Data System (ADS)

    Barseghyan, M. G.

    2016-10-01

    The simultaneous influence of hydrostatic pressure and intense laser field on hydrogenic donor impurity states and intraband optical absorption has been investigated in GaAs/Ga_{1-tilde{x}}Al_{tilde{x}}As quantum ring. The one-electron energy spectrum and wave functions have been found using the effective mass approximation and exact diagonalization technique. The intraband absorption coefficient is calculated for different values of the hydrostatic pressure, intense laser field parameter and different locations of hydrogenic donor impurity. The simultaneous influence of hydrostatic pressure and intense laser field shows that while the increment of the first one leads only to the blueshift of the absorption spectrum, the augmentation of the second one makes the redshift. In addition, both blueshift and redshift of the spectrum have been obtained with the changes of impurity location. The obtained theoretical results indicate good controlling means of the optical spectrum of ring-like structures by the combined influence of the considered factors.

  4. Comprehensive analysis of the optical Kerr coefficient of graphene

    SciTech Connect

    Soh, Daniel B. S.; Hamerly, Ryan; Mabuchi, Hideo

    2016-08-25

    We present a comprehensive analysis of the nonlinear optical Kerr effect in graphene. We directly solve the S-matrix element to calculate the absorption rate, utilizing the Volkov-Keldysh-type crystal wave functions. We then convert to the nonlinear refractive index coefficients through the Kramers-Kronig relation. In this formalism, the source of Kerr nonlinearity is the interplay of optical fields that cooperatively drive the transition from valence to conduction band. This formalism makes it possible to identify and compute the rates of distinct nonlinear processes that contribute to the Kerr nonlinear refractive index coefficient. The four identified mechanisms are two-photon absorption, Raman transition, self-coupling, and quadratic ac Stark effect. As a result, we present a comparison of our theory with recent experimental and theoretical results.

  5. Comprehensive analysis of the optical Kerr coefficient of graphene

    DOE PAGES

    Soh, Daniel B. S.; Hamerly, Ryan; Mabuchi, Hideo

    2016-08-25

    We present a comprehensive analysis of the nonlinear optical Kerr effect in graphene. We directly solve the S-matrix element to calculate the absorption rate, utilizing the Volkov-Keldysh-type crystal wave functions. We then convert to the nonlinear refractive index coefficients through the Kramers-Kronig relation. In this formalism, the source of Kerr nonlinearity is the interplay of optical fields that cooperatively drive the transition from valence to conduction band. This formalism makes it possible to identify and compute the rates of distinct nonlinear processes that contribute to the Kerr nonlinear refractive index coefficient. The four identified mechanisms are two-photon absorption, Raman transition,more » self-coupling, and quadratic ac Stark effect. As a result, we present a comparison of our theory with recent experimental and theoretical results.« less

  6. Comprehensive analysis of the optical Kerr coefficient of graphene

    NASA Astrophysics Data System (ADS)

    Soh, Daniel B. S.; Hamerly, Ryan; Mabuchi, Hideo

    2016-08-01

    We present a comprehensive analysis of the nonlinear optical Kerr effect in graphene. We directly solve the S -matrix element to calculate the absorption rate, utilizing the Volkov-Keldysh-type crystal wave functions. We then convert to the nonlinear refractive index coefficients through the Kramers-Kronig relation. In this formalism, the source of Kerr nonlinearity is the interplay of optical fields that cooperatively drive the transition from valence to conduction band. This formalism makes it possible to identify and compute the rates of distinct nonlinear processes that contribute to the Kerr nonlinear refractive index coefficient. The four identified mechanisms are two-photon absorption, Raman transition, self-coupling, and quadratic ac Stark effect. We also present a comparison of our theory with recent experimental and theoretical results.

  7. Electron mobility and free-carrier absorption in GaAs - Determination of the compensation ratio

    NASA Technical Reports Server (NTRS)

    Walukiewicz, W.; Lagowski, L.; Jastrzebski, L.; Lichtensteiger, M.; Gatos, H. C.

    1979-01-01

    Theoretical calculations of electron mobility and free-carrier absorption in n-type GaAs at room temperature were carried out taking into consideration all major scattering processes. It was found that satisfactory agreement between theoretical and experimental results on free-carrier absorption is obtained only when the effect of compensation is quantitatively taken into account. In conjunction with experimental studies it is shown that the electron mobility (for n greater than 10 to the 15th per cu cm) and free-carrier absorption (for n greater than 10 to the 16th per cu cm) are sufficiently sensitive to the ionized impurity concentration to provide a reliable means for determining the compensation ratio. Convenient procedures are presented for the determination of the compensation ratio from the free-carrier absorption coefficient and from the computed values of room-temperature electron mobility. Values of the compensation ratio obtained by these two procedures are in good agreement provided the carrier-concentration variations in the material are not appreciably greater than 10%.

  8. Relationship of extinction coefficient, air pollution, and meteorological parameters in an urban area during 2007 to 2009.

    PubMed

    Sabetghadam, Samaneh; Ahmadi-Givi, Farhang

    2014-01-01

    Light extinction, which is the extent of attenuation of light signal for every distance traveled by light in the absence of special weather conditions (e.g., fog and rain), can be expressed as the sum of scattering and absorption effects of aerosols. In this paper, diurnal and seasonal variations of the extinction coefficient are investigated for the urban areas of Tehran from 2007 to 2009. Cases of visibility impairment that were concurrent with reports of fog, mist, precipitation, or relative humidity above 90% are filtered. The mean value and standard deviation of daily extinction are 0.49 and 0.39 km(-1), respectively. The average is much higher than that in many other large cities in the world, indicating the rather poor air quality over Tehran. The extinction coefficient shows obvious diurnal variations in each season, with a peak in the morning that is more pronounced in the wintertime. Also, there is a very slight increasing trend in the annual variations of atmospheric extinction coefficient, which suggests that air quality has regressed since 2007. The horizontal extinction coefficient decreased from January to July in each year and then increased between July and December, with the maximum value in the winter. Diurnal variation of extinction is often associated with small values for low relative humidity (RH), but increases significantly at higher RH. Annual correlation analysis shows that there is a positive correlation between the extinction coefficient and RH, CO, PM10, SO2, and NO2 concentration, while negative correlation exists between the extinction and T, WS, and O3, implying their unfavorable impact on extinction variation. The extinction budget was derived from multiple regression equations using the regression coefficients. On average, 44% of the extinction is from suspended particles, 3% is from air molecules, about 5% is from NO2 absorption, 0.35% is from RH, and approximately 48% is unaccounted for, which may represent errors in the data as

  9. Anomalous absorption of laser light on ion acoustic fluctuations

    NASA Astrophysics Data System (ADS)

    Rozmus, Wojciech; Bychenkov, Valery Yu.

    2016-10-01

    Theory of laser light absorption due to ion acoustic turbulence (IAT) is discussed in high Z plasmas where ion acoustic waves are weakly damped. Our theory applies to the whole density range from underdense to critical density plasmas. It includes an absorption rate for the resonance anomalous absorption due to linear conversion of electromagnetic waves into electron plasma oscillations by the IAT near the critical density in addition to the absorption coefficient due to enhanced effective electron collisionality. IAT is driven by large electron heat flux through the return current instability. Stationary spectra of IAT are given by weak plasma turbulence theory and applied in description of the anomalous absorption in the inertial confinement fusion plasmas at the gold walls of a hohlraum. This absorption is anisotropic in nature due to IAT angular anisotropy and differs for p- and s-polarization of the laser radiation. Possible experiments which could identify the resonance anomalous absorption in a laser heated plasma are discussed.

  10. Activity coefficient of aqueous sodium bicarbonate

    SciTech Connect

    Pitzer, Kenneth S.; Peiper, J. Christopher

    1980-09-01

    The determination of the activity coefficient and related properties of sodium bicarbonate presents special problems because of the appreciable vapor pressure of CO2 above such solutions. With the development of reliable equations for the thermodynamic properties of mixed electrolytes, it is possible to determine the parameters for NaHCO3 from cell measurements or NaCl-NaHCO3 mixtures. Literature data are analyzed to illustrate the method and provide interim values, hoever it is noted that further measurements over a wider range of concentrations would yield more definitive results. Lastly, an estimate is also given for the activity coefficient of KHCO3.

  11. Layer coefficients for NHDOT pavement materials

    NASA Astrophysics Data System (ADS)

    Janoo, Vincent C.

    1994-09-01

    In 1992, the New Hampshire Department of Transportation (NHDOT) experimented with the use of reclaimed asphalt concrete as a base course material, identified by NHDOT as reclaimed stabilized base (RSB). The RSB and a control test section were placed on Interstate 93 between exits 18 and 19. The RSB test section was designed to the same structural number (SN) as the control. To evaluate the structural capacity of these test sections, the U.S. Army Cold Regions Research and Engineering Laboratory (CRREL) conducted deflection tests using a Dynatest 8000 falling weight deflectometer (FWD). Preliminary analysis of the results by NHDOT personnel showed higher deflection in the reclaimed asphalt concrete test sections. The explanation was that the layer coefficient used for the RSB layer in the design was probably incorrect. A total of 10 test sections constituting the base course materials used by NHDOT were built near Bow, New Hampshire. CRREL evaluated and estimated the layer coefficients of the base course materials. The test program was developed to characterize the material in more than one way. Tests were conducted with the heavy weight deflectometer (HWD), dynamic cone penetrometer (DCP) and the Clegg hammer. In situ California bearing ratio (CBR) tests were also conducted. The deflection from the HWD were used with the WESDEF back calculation program to determine the layer moduli. The moduli were than used with the AASHTO Design Guide to calculate the layer coefficients. The layer coefficients were also determined with the method proposed by Rohde. The CBR values from the Clegg hammer, in situ CBR and DCP tests were also used in the relationships in the HDM model to determine the layer coefficients.

  12. Determination of permeability coefficients of ophthalmic drugs through different layers of porcine, rabbit and bovine eyes.

    PubMed

    Loch, Christian; Zakelj, Simon; Kristl, Albin; Nagel, Stefan; Guthoff, Rudolf; Weitschies, Werner; Seidlitz, Anne

    2012-08-30

    To treat ophthalmic diseases like glaucoma or inflammatory disorders topically applied ophthalmic formulations such as eye drops are usually used. In addition, novel ophthalmic implants releasing drug substances locally into different parts of the eye are available today. In the work presented here, the permeability coefficients of selected drugs (ciprofloxacin hydrochloride, lidocaine hydrochloride, timolol maleate) for ophthalmic tissues were determined using side-by-side diffusion chambers (so-called Ussing chambers). Sclera, conjunctiva, cornea, choroidea-retina-complex and a complex of conjunctiva-sclera-choroidea-retina were excised from fresh porcine, rabbit and bovine eyes. In the porcine eye tissues the highest P(app) values were obtained for conjunctiva with the exception of lidocaine. Therefore, it can be estimated that a certain amount of drug diffuses or is transported through conjunctiva after application. The P(app) values for sclera were also higher than those for cornea and even more, the surface area of sclera which is available for drug absorption is much larger than that of cornea when applying an implant. The obtained permeability coefficients for sclera and conjunctiva indicate that the administration of periocular implants can be an alternative to topically applied formulations. The complexes of the tissues were a significantly (p<0.01) stronger barrier to the investigated substances than the separated tissues. Distinct differences in permeability coefficients between the investigated animal tissues were observed. Overall the highest P(app) values for all mounted tissues were obtained with the rabbit, followed by porcine and bovine eyes. Because of these distinct interspecies differences one must be very careful when selecting the proper animal model for the permeability experiments.

  13. Subbarrier absorption in a stationary superlattice

    NASA Technical Reports Server (NTRS)

    Arutyunyan, G. M.; Nerkararyan, K. V.

    1984-01-01

    The calculation of the interband absorption coefficient was carried out in the classical case, when the frequency of light was assumed to bind two miniband subbarrier states of different bands. The influence of two dimensional Mott excitons on this absorption was studied and a comparison was made with the experiment. All of these considerations were done taking into account the photon wave vector (the phase spatial heterogeneity). The basic traits of the energy spectra of superlattice semiconductors, their kinetic and optical properties, and possible means of electromagnetic wave intensification were examined. By the density matrix method, a theory of electrical and electromagnetic properties of superlattices was suggested.

  14. Monitoring of MOCVD reactants by UV absorption

    SciTech Connect

    Baucom, K.C.; Killeen, K.P.; Moffat, H.K.

    1995-07-01

    In this paper, we describe how UV absorption measurements can be used to measure the flow rates of metal organic chemical vapor deposition (MOCVD) reactants. This method utilizes the calculation of UV extinction coefficients by measuring the total pressure and absorbance in the neat reactant system. The development of this quantitative reactant flow rate monitor allows for the direct measurement of the efficiency of a reactant bubbler. We demonstrate bubbler efficiency results for TMGa, and then explain some discrepancies found in the TMAl system due to the monomer to dimer equilibrium. Also, the UV absorption spectra of metal organic and hydride MOCVD reactants over the wavelength range 185 to 400 nm are reported.

  15. Linear attenuation coefficients of tissues from 1 keV to 150 keV

    NASA Astrophysics Data System (ADS)

    Böke, Aysun

    2014-09-01

    The linear attenuation coefficients and three interaction processes have been computed for liver, kidney, muscle, fat and for a range of x-ray energies from 1 keV to 150 keV. Molecular photoelectric absorption cross sections were calculated from atomic cross section data. Total coherent (Rayleigh) and incoherent (Compton) scattering cross sections were obtained by numerical integration over combinations of F2m(x) with the Thomson formula and Sm(x) with the Klein-Nishina formula, respectively. For the coherent (Rayleigh) scattering cross section calculations, molecular form factors were obtained from recent experimental data in the literature for values of x<1 Å-1 and from the relativistic modified atomic form factors for values of x≥1 Å-1. With the inclusion of molecular interference effects in the coherent (Rayleigh) scattering, more accurate knowledge of the scatter from these tissues will be provided. The number of elements involved in tissue composition is 5 for liver, 47 for kidney, 44 for muscle and 3 for fat. The results are compared with previously published experimental and theoretical linear attenuation coefficients. In general, good agreement is obtained. The molecular form factors and scattering functions and cross sections are incorporated into a Monte Carlo program. The energy distributions of x-ray photons scattered from tissues have been simulated and the results are presented.

  16. Experimental determination of partition coefficient for β-pinene ozonolysis products in SOA

    NASA Astrophysics Data System (ADS)

    Gensch, Iulia; Hohaus, Thorsten; Kimmel, Joel; Jayne, John T.; Worsnop, Douglas R.; Kiendler-Scharr, Astrid

    2013-04-01

    In the present study, simultaneous measurement of β-pinene ozonolysis products in the gas phase by Proton Transfer Reaction - Time of Flight Mass Spectrometry (PTR-ToFMS) and particle phase by using an Aerosol Collection Module coupled to a Gas Chromatograph - Mass Spectrometer (ACM-GC-MS) were employed to determine the equilibrium partitioning coefficient (Kp) of several semi-volatile organic species. Mean Kp values of 6.7 10-5 ± 2.5 10-5 for nopinone, 4.8 10-4 ± 1.7 10-4 for apoverbenone, 7.0 10-4 ± 1.7 10-4 for oxonopinone and 1.9 10-3 ± 1.1 10-3 for hydroxynopinone were obtained. The results were compared with calculations arising from studies on the gas-particle partitioning, based on the Pankow absorption model. The experimental partition coefficients are two to three orders of magnitudes higher than the calculated values, leading to the conclusion that the amount of semi-volatile organic compounds in secondary organic aerosol (SOA) is currently underestimated by the theory, thus impacting on the modeling of the organic matter in the atmosphere.

  17. Determination of octanol-air partition coefficients and supercooled liquid vapor pressures of PAHs as a function of temperature: Application to gas-particle partitioning in an urban atmosphere

    NASA Astrophysics Data System (ADS)

    Odabasi, Mustafa; Cetin, Eylem; Sofuoglu, Aysun

    Octanol-air partition coefficients ( KOA) for 14 polycyclic aromatic hydrocarbons (PAHs) were determined as a function of temperature using the gas chromatographic retention time method. log KOA values at 25° ranged over six orders of magnitude, between 6.34 (acenaphthylene) and 12.59 (dibenz[ a,h]anthracene). The determined KOA values were within factor of 0.7 (dibenz[ a,h]anthracene) to 15.1 (benz[ a]anthracene) of values calculated as the ratio of octanol-water partition coefficient to dimensionless Henry's law constant. Supercooled liquid vapor pressures ( PL) of 13 PAHs were also determined using the gas chromatographic retention time technique. Activity coefficients in octanol calculated using KOA and PL ranged between 3.2 and 6.2 indicating near-ideal solution behavior. Atmospheric concentrations measured in this study in Izmir, Turkey were used to investigate the partitioning of PAHs between particle and gas-phases. Experimental gas-particle partition coefficients ( Kp) were compared to the predictions of KOA absorption and KSA (soot-air partition coefficient) models. Octanol-based absorptive partitioning model predicted lower partition coefficients especially for relatively volatile PAHs. Ratios of measured/modeled partition coefficients ranged between 1.1 and 15.5 (4.5±6.0, average±SD) for KOA model. KSA model predictions were relatively better and measured to modeled ratios ranged between 0.6 and 5.6 (2.3±2.7, average±SD).

  18. Percutaneous absorption of trihalomethanes, haloacetic acids, and haloketones.

    PubMed

    Xu, Xu; Mariano, Thomas M; Laskin, Jeffrey D; Weisel, Clifford P

    2002-10-01

    Bathing in chlorinated drinking water causes significant exposure to potentially toxic disinfection by-products (DBPs). In the present studies, we measured the permeation coefficients (K(p)) of three important classes of DBPs, trihalomethanes (THMs), haloketones (HKs), and haloacetic acids (HAAs), in aqueous solution across human skin using in vitro diffusion chambers. Linear mixed-effects model was utilized to calculate the steady-state permeability coefficients. The permeability coefficients of THMs ranged from 0.16 to 0.21 cm/h when the donor solution was at 25 degrees C. Bromoform had the highest K(p) value, while chloroform was the least permeable through the skin. THMs were approximately 10 times more permeable than HKs, while the permeability of HAAs through the skin was very low (1 to 3 x 10(-3) cm/h, pH 7). The permeability of HKs tripled as the temperature was increased from room temperature (20 degrees C) to bathing temperature (40 degrees C). A direct relationship was found between the permeability of THMs, but not HKs and HAAs, and their octanol/water partition coefficients. The dermal dose from daily bathing activities was approximated for an average adult using U.S. EPA recommended methods and found to be 40-70% of the daily ingestion dose for the THMs, 10% of the ingestion dose for HKs, and an insignificant percentage of the ingestion dose for the HAAs. In addition to ingestion, dermal absorption is an important route of exposure to THMs and HKs and must be considered in models of risk assessment.

  19. Sound absorption of metallic sound absorbers fabricated via the selective laser melting process

    NASA Astrophysics Data System (ADS)

    Cheng, Li-Wei; Cheng, Chung-Wei; Chung, Kuo-Chun; Kam, Tai-Yan

    2017-01-01

    The sound absorption capability of metallic sound absorbers fabricated using the additive manufacturing (selective laser melting) method is investigated via both the experimental and theoretical approaches. The metallic sound absorption structures composed of periodic cubic cells were made of laser-melted Ti6Al4 V powder. The acoustic impedance equations with different frequency-independent and frequency-dependent end corrections factors are employed to calculate the theoretical sound absorption coefficients of the metallic sound absorption structures. The calculated sound absorption coefficients are in close agreement with the experimental results for the frequencies ranging from 2 to 13 kHz.

  20. Intracavity Dye-Laser Absorption Spectroscopy (IDLAS) for application to planetary molecules

    NASA Technical Reports Server (NTRS)

    Lang, Todd M.; Allen, John E., Jr.

    1990-01-01

    Time-resolved, quasi-continuous wave, intracavity dye-laser absorption spectroscopy is applied to the investigation of absolute absorption coefficients for vibrational-rotational overtone bands of water at visible wavelengths. Emphasis is placed on critical factors affecting detection sensitivity and data analysis. Typical generation-time dependent absorption spectra are given.

  1. Parametric distortion of the optical absorption edge of a magnetic semiconductor by a strong laser field

    SciTech Connect

    Nunes, O.A.C.

    1985-09-15

    The influence of a strong laser field on the optical absorption edge of a direct-gap magnetic semiconductor is considered. It is shown that as the strong laser intensity increases the absorption coefficient is modified so as to give rise to an absorption tail below the free-field forbidden gap. An application is made for the case of the EuO.

  2. What Value "Value Added"?

    ERIC Educational Resources Information Center

    Richards, Andrew

    2015-01-01

    Two quantitative measures of school performance are currently used, the average points score (APS) at Key Stage 2 and value-added (VA), which measures the rate of academic improvement between Key Stage 1 and 2. These figures are used by parents and the Office for Standards in Education to make judgements and comparisons. However, simple…

  3. Factors influencing the stream-aquifer flow exchange coefficient.

    PubMed

    Morel-Seytoux, Hubert J; Mehl, Steffen; Morgado, Kyle

    2014-01-01

    Knowledge of river gain from or loss to a hydraulically connected water table aquifer is crucial in issues of water rights and also when attempting to optimize conjunctive use of surface and ground waters. Typically in groundwater models this exchange flow is related to a difference in head between the river and some point in the aquifer, through a "coefficient." This coefficient has been defined differently as well as the location for the head in the aquifer. This paper proposes a new coefficient, analytically derived, and a specific location for the point where the aquifer head is used in the difference. The dimensionless part of the coefficient is referred to as the SAFE (stream-aquifer flow exchange) dimensionless conductance. The paper investigates the factors that influence the value of this new conductance. Among these factors are (1) the wetted perimeter of the cross-section, (2) the degree of penetration of the cross-section, and (3) the shape of the cross-section. The study shows that these factors just listed are indeed ordered in their respective level of importance. In addition the study verifies that the analytical correct value of the coefficient is matched by finite difference simulation only if the grid system is sufficiently fine. Thus the use of the analytical value of the coefficient is an accurate and efficient alternative to ad hoc estimates for the coefficient typically used in finite difference and finite element methods.

  4. Light Absorption of Stratospheric Aerosols: Long-Term Trend and Contribution by Aircraft

    NASA Technical Reports Server (NTRS)

    Pueschel , R. F.; Gore, Waren J. Y. (Technical Monitor)

    1997-01-01

    Measurements of aerosol light-absorption coefficients are useful for studies of radiative transfer and heating rates. Ogren appears to have published the first light- absorption coefficients in the stratosphere in 1981, followed by Clarke in 1983 and Pueschel in 1992. Because most stratospheric soot appears to be due to aircraft operations, application of an aircraft soot aerosol emission index to projected fuel consumption suggests a threefold increase of soot loading and light absorption by 2025. Together, those four data sets indicate an increase in mid-visible light extinction at a rate of 6 % per year. This trend is similar to the increase per year of sulfuric acid aerosol and of commercial fleet size. The proportionality between stepped-up aircraft operations above the tropopause and increases in stratospheric soot and sulfuric acid aerosol implicate aircraft as a source of stratospheric pollution. Because the strongly light-absorbing soot and the predominantly light-scattering sulfuric acid aerosol increase at similar rates, however, the mid-visible stratospheric aerosol single scatter albedo is expected to remain constant and not approach a critical value of 0.98 at which stratospheric cooling could change to warming.

  5. Transport coefficients of He(+) ions in helium.

    PubMed

    Viehland, Larry A; Johnsen, Rainer; Gray, Benjamin R; Wright, Timothy G

    2016-02-21

    This paper demonstrates that the transport coefficients of (4)He(+) in (4)He can be calculated over wide ranges of E/N, the ratio of the electrostatic field strength to the gas number density, with the same level of precision as can be obtained experimentally if sufficiently accurate potential energy curves are available for the X(2)Σu (+) and A(2)Σg (+) states and one takes into account resonant charge transfer. We start by computing new potential energy curves for these states and testing their accuracy by calculating spectroscopic values for the separate states. It is established that the potentials obtained by extrapolation of results from d-aug-cc-pVXZ (X = 6, 7) basis sets using the CASSCF+MRCISD approach are each in exceptionally close agreement with the best potentials available and with experiment. The potentials are then used in a new computer program to determine the semi-classical phase shifts and the transport cross sections, and from these the gaseous ion transport coefficients are determined. In addition, new experimental values are reported for the mobilities of (4)He(+) in (4)He at 298.7 K, as a function of E/N, where careful consideration is given to minimizing various sources of uncertainty. Comparison with previously measured values establishes that only one set of previous data is reliable. Finally, the experimental and theoretical ion transport coefficients are shown to be in very good to excellent agreement, once corrections are applied to account for quantum-mechanical effects.

  6. Modification of Einstein A Coefficient in Dissipative Gas Medium

    NASA Technical Reports Server (NTRS)

    Cao, Chang-Qi; Cao, Hui; Qin, Ke-Cheng

    1996-01-01

    Spontaneous radiation in dissipative gas medium such as plasmas is investigated by Langevin equations and the modified Weisskopf-Wigner approximation. Since the refractive index of gas medium is expected to be nearly unity, we shall first neglect the medium polarization effect. We show that absorption in plasmas may in certain case modify the Einstein A coefficient significantly and cause a pit in the A coefficient-density curves for relatively low temperature plasmas and also a pit in the A coefficient-temperature curves. In the next, the effect of medium polarization is taken into account in addition. To our surprise, its effect in certain case is quite significant. The dispersive curves show different behaviors in different region of parameters.

  7. Determination of stream reaeration coefficients by use of tracers

    USGS Publications Warehouse

    Kilpatrick, F.A.; Rathbun, R.E.; Yotsukura, Nobuhiro; Parker, G.W.; DeLong, L.L.

    1987-01-01

    Stream reaeration is the physical absorption of oxygen from the atmosphere by a flowing stream. This is the primary process by which a stream replenishes the oxygen consumed in the biodegradation of organic wastes. Prior to 1965, reaeration rate coefficients could be estimated only by indirect methods. In 1965, a direct method of measuring stream reaeration coefficients was developed in which a radioactive tracer gas was injected into a stream--the tracer gas being desorbed from the stream inversely to how oxygen would be absorbed. The technique has since been modified by substituting hydrocarbon gases for the radioactive tracer gas. The slug-injection and constant-rate injection methods of performing gas tracer desorption measurements are described. Emphasis is on the use of rhodamine WT dye as a relatively conservative tracer and propane as the nonconservative gas tracer, on planning field tests, methods of injection, sampling and analysis, and computational techniques to compute desorption and reaeration coefficients. (Author 's abstract)

  8. Seebeck coefficient of one electron

    SciTech Connect

    Durrani, Zahid A. K.

    2014-03-07

    The Seebeck coefficient of one electron, driven thermally into a semiconductor single-electron box, is investigated theoretically. With a finite temperature difference ΔT between the source and charging island, a single electron can charge the island in equilibrium, directly generating a Seebeck effect. Seebeck coefficients for small and finite ΔT are calculated and a thermally driven Coulomb staircase is predicted. Single-electron Seebeck oscillations occur with increasing ΔT, as one electron at a time charges the box. A method is proposed for experimental verification of these effects.

  9. Optimisation of external cavity parameters of a weak absorption laser spectrometer

    SciTech Connect

    Korolenko, P V; Lagunov, V V; Nikolaev, I V; Ochkin, V N; Tskhai, S N; Yatskevich, A N

    2016-03-31

    We consider some peculiar features of the optimisation procedure of external optical cavity parameters of a laser spectrometer, caused by the use of a three-beam measurement scheme and the presence of losses in the mirrors. It is found that the maximum sensitivity to the absorption of an intracavity medium can be achieved only at a certain choice of the value and the ratio of the reflection coefficients of the mirrors. For example, registration of the spectra of the methane impurity in the atmosphere shows that in accordance with the calculation model, for the same resonator Q-factor the use of an input mirror with a smaller reflection coefficient allows the measurement sensitivity to be increased by approximately two times. (laser spectroscopy)

  10. Elastic-Stiffness Coefficients of Titanium Diboride

    PubMed Central

    Ledbetter, Hassel; Tanaka, Takaho

    2009-01-01

    Using resonance ultrasound spectroscopy, we measured the monocrystal elastic-stiffness coefficients, the Voigt Cij, of TiB2. With hexagonal symmetry, TiB2 exhibits five independent Cij: C11, C33, C44, C12, C13. Using Voigt-Reuss-Hill averaging, we converted these monocrystal values to quasiisotropic (polycrystal) elastic stiffnesses. Briefly, we comment on effects of voids. From the Cij, we calculated the Debye characteristic temperature, the Grüneisen parameter, and various sound velocities. Our study resolves the enormous differences between two previous reports of TiB2’s Cij. PMID:27504232

  11. Surface area coefficients for airship envelopes

    NASA Technical Reports Server (NTRS)

    Diehl, W S

    1922-01-01

    In naval architecture, it is customary to determine the wetted surface of a ship by means of some formula which involves the principal dimensions of the design and suitable constants. These formulas of naval architecture may be extended and applied to the calculation of the surface area of airship envelopes by the use of new values of the constants determined for this purpose. Surface area coefficients were calculated from the actual dimensions, surfaces, and volumes of 52 streamline bodies, which form a series covering the entire range of shapes used in the present aeronautical practice.

  12. Gauge Invariance of Thermal Transport Coefficients

    NASA Astrophysics Data System (ADS)

    Ercole, Loris; Marcolongo, Aris; Umari, Paolo; Baroni, Stefano

    2016-10-01

    Thermal transport coefficients are independent of the specific microscopic expression for the energy density and current from which they can be derived through the Green-Kubo formula. We discuss this independence in terms of a kind of gauge invariance resulting from energy conservation and extensivity, and demonstrate it numerically for a Lennard-Jones fluid, where different forms of the microscopic energy density lead to different time correlation functions for the heat flux, all of them, however, resulting in the same value for the thermal conductivity.

  13. Investigation of Absorption Cooling Application Powered by Solar Energy in the South Coast Region of Turkey

    NASA Astrophysics Data System (ADS)

    Babayigit, O.; Aksoy, M. H.; Ozgoren, M.; Solmaz, O.

    2013-04-01

    In this study, an absorption system using ammonia-water (NH3-H2O) solution has been theoretically examined in order to meet the cooling need of a detached building having 150 m2 floor area for Antalya, Mersin and Mugla provinces in Turkey. Hourly dynamic cooling load capacities of the building were determined by using Radiant Time Series (RTS) method in the chosen cities. For the analysis, hourly average meteorological data such as atmospheric air temperature and solar radiation belonging to the years 1998-2008 are used for performance prediction of the proposed system. Thermodynamic relations for each component of absorption cooling system is explained and coefficients of performance of the system are calculated. The maximum daily total radiation data were calculated as 7173 W/m2day on July 15, 7277 W/m2 day on July 19 and 7231 W/m2day on July 19 for Mersin, Antalya and Mugla, respectively on the 23° toward to south oriented panels from horizontal surface. The generator operating temperatures are considered between 90-130°C and the best result for 110°C is found the optimum degree for maximum coefficient of performance (COP) values at the highest solar radiation occurred time during the considered days for each province. The COP values varies between 0.521 and 0.530 for the provinces. In addition, absorber and condenser capacities and thermal efficiency for the absorption cooling system were calculated. The necessary evacuated tube collector area for the different provinces were found in the range of 45 m2 to 47 m2. It is shown that although the initial investment cost is higher for the proposed absorption cooling system, it is economically feasible because of its lower annual operation costs and can successfully be operated for the considered provinces.

  14. Edge Diffraction Coefficients around Critical Rays

    NASA Astrophysics Data System (ADS)

    Fradkin, L.; Harmer, M.; Darmon, M.

    2014-04-01

    The classical GTD (Geometrical Theory of Diffraction) gives a recipe, based on high-frequency asymptotics, for calculating edge diffraction coefficients in the geometrical regions where only diffracted waves propagate. The Uniform GTD extends this recipe to transition zones between irradiated and silent regions, known as penumbra. For many industrial materials, e.g. steels, and frequencies utlized in industrial ultrasonic transducers, that is, around 5 MHz, asymptotics suggested for description of geometrical regions supporting the head waves or transition regions surrounding their boundaries, known as critical rays, prove unsatisfactory. We present a numerical extension of GTD, which is based on a regularized, variable step Simpson's method for evaluating the edge diffraction coefficients in the regions of interference between head waves, diffracted waves and/or reflected waves. In mathematical terms, these are the regions of coalescence of three critical points - a branch point, stationary point and/or pole, respectively. We show that away from the shadow boundaries, near the critical rays the GTD still produces correct values of the edge diffraction coefficients.

  15. Determining the Temperature Coefficient of Reference Resistors

    NASA Astrophysics Data System (ADS)

    Bojkovski, J.; Batagelj, V.; Žužek, V.

    2017-04-01

    The influence of temperature on electrical resistance of standard resistors is presented within this paper. Electrical resistance is like any other quantity temperature dependent. This dependence is specified with the temperature coefficient, which gives the relative change of resistance with temperature. The level of resistance change is not linear as it changes with temperature, and therefore the coefficient is temperature dependent as well. At a certain temperature, its value is equal to zero—the stationary point. Use of the standard resistor at this exact temperature or in a narrow interval around it greatly reduces the influence of temperature on electrical resistance, even if the thermal conditions are not optimal. Measurements of temperature coefficient were taken on a group of standard resistors of the same type in a wide temperature range, and the temperature of the stationary point was determined. Measurements were taken by placing the resistors in an oil bath and changing its set point temperature from 18°C to 38°C. Electrical resistance of each resistor was measured using a resistance bridge, which had its reference resistor placed in a separate thermal enclosure at a constant temperature.

  16. Drag coefficients for winter Antarctic pack ice

    NASA Technical Reports Server (NTRS)

    Wamser, Christian; Martinson, Douglas G.

    1993-01-01

    Air-ice and ice-water drag coefficients referenced to 10-m-height winds for winter Antarctic pack ice based on measurements made from R/V Polarstern during the Winter Weddell Sea Project, 1986 (WWSP-86), and from R/V Akademik Fedorov during the Winter Weddell Gyre Study, 1989 (WWGS-89), are presented. The optimal values of the air-ice drag coefficients, made from turbulent flux measurements, are (1.79 +/- 0.06) x 10 exp -3 for WWSP-86 and (1.45 +/- 0.09) x 10 exp -3 for WWGS-89. A single ice-water drag coefficient for both WWSP-86 and WWGS-89, estimated from periods of ice drift throught to represent free-drift conditions, is (1.13 +/- 0.26) x 10 exp -3, and the ice-water turning angle is 18 +/- 18 deg. It is suggested that for a typical Antarctic winter pack ice cover, the ice cover reduces the momentum flux from the atmosphere to the ocean by about 33 percent.

  17. Field verification of the wind tunnel coefficients

    NASA Technical Reports Server (NTRS)

    Gawronski, W. K.; Mellstrom, J. A.

    1994-01-01

    Accurate information about wind action on antennas is required for reliable prediction of antenna pointing errors in windy weather and for the design of an antenna controller with wind disturbance rejection properties. The wind tunnel data obtained 3 years ago using a scaled antenna model serves as an antenna industry standard, frequently used for the first purpose. The accuracy of the wind tunnel data has often been challenged, since they have not yet been tested in a field environment (full-aized antenna, real wind, actual terrain, etc.). The purpose of this investigation was to obtain selected field measurements and compare them with the available wind tunnel data. For this purpose, wind steady-state torques of the DSS-13 antenna were measured, and dimensionless wind torque coefficients were obtained for a variety of yaw and elevation angles. The results showed that the differences between the wind tunnel torque coefficients and the field torque coefficients were less than 10 percent of their values. The wind-gusting action on the antenna was characterized by the power spectra of the antenna encoder and the antenna torques. The spectra showed that wind gusting primarily affects the antenna principal modes.

  18. Unsteady solute dispersion in Herschel-Bulkley fluid in a tube with wall absorption

    NASA Astrophysics Data System (ADS)

    Rana, Jyotirmoy; Murthy, P. V. S. N.

    2016-11-01

    The axial dispersion of solute in a pulsatile flow of Herschel-Bulkley fluid through a straight circular tube is investigated considering absorption/reaction at the tube wall. The solute dispersion process is described by adopting the generalized dispersion model suggested by Sankarasubramanian and Gill ["Unsteady convective diffusion with interphase mass transfer," Proc. R. Soc. A 333, 115-132 (1973)]. Firstly the exchange, convection, and dispersion coefficients are determined for small and large time, and then the axial mean concentration of a solute in the tube is determined. The effect of power-law index l, yield stress of fluid τy, wall absorption parameter β, amplitude of fluctuating pressure component e, and Womersley frequency parameter α on the convection, dispersion, and mean concentration of solute is discussed for a Herschel-Bulkley fluid in the tube. The single frequency period in the oscillation of dispersion coefficient K2 is observed for small values of α while the double frequency period is noticed for large values of α at small time. Only positive dispersion occurs for small values of α. Both positive and negative dispersion is seen for large values of α. Also, the occurrence of negative dispersion is influenced by the parameters l, τy, β, and e for large values of α. A comparative study of the convection, dispersion, and mean concentration of solute among the Newtonian and non-Newtonian Herschel-Bulkley, power-law, Bingham, and Casson [J. Rana and P. V. S. N. Murthy, "Solute dispersion in pulsatile casson fluid flow in a tube with wall absorption," J. Fluid Mech. 793, 877-914 (2016)] fluid models is presented at small and large time. Also, large time behaviour of non-Newtonian Carreau and Carreau-Yasuda fluid models [J. Rana and P. V. S. N. Murthy, "Unsteady solute dispersion in non-Newtonian fluid flow in a tube with wall absorption," Proc. R. Soc. A 472, 20160294 (2016)] is considered for comparison with other discussed fluid models

  19. High temperature measurement of water vapor absorption

    NASA Technical Reports Server (NTRS)

    Keefer, Dennis; Lewis, J. W. L.; Eskridge, Richard

    1985-01-01

    An investigation was undertaken to measure the absorption coefficient, at a wavelength of 10.6 microns, for mixtures of water vapor and a diluent gas at high temperature and pressure. The experimental concept was to create the desired conditions of temperature and pressure in a laser absorption wave, similar to that which would be created in a laser propulsion system. A simplified numerical model was developed to predict the characteristics of the absorption wave and to estimate the laser intensity threshold for initiation. A non-intrusive method for temperature measurement utilizing optical laser-beam deflection (OLD) and optical spark breakdown produced by an excimer laser, was thoroughly investigated and found suitable for the non-equilibrium conditions expected in the wave. Experiments were performed to verify the temperature measurement technique, to screen possible materials for surface initiation of the laser absorption wave and to attempt to initiate an absorption wave using the 1.5 kW carbon dioxide laser. The OLD technique was proven for air and for argon, but spark breakdown could not be produced in helium. It was not possible to initiate a laser absorption wave in mixtures of water and helium or water and argon using the 1.5 kW laser, a result which was consistent with the model prediction.

  20. Tables of the coefficients A

    NASA Technical Reports Server (NTRS)

    Chandra, N.

    1974-01-01

    Numerical coefficients required to express the angular distribution for the rotationally elastic or inelastic scattering of electrons from a diatomic molecule were tabulated for the case of nitrogen and in the energy range from 0.20 eV to 10.0 eV. Five different rotational states are considered.