Sample records for abundant energy source

  1. An investigation of techniques for the measurement and interpretation of cosmic ray isotopic abundances. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Wiedenbeck, M. E.

    1977-01-01

    An instrument, the Caltech High Energy Isotope Spectrometer Telescope was developed to measure isotopic abundances of cosmic ray nuclei by employing an energy loss - residual energy technique. A detailed analysis was made of the mass resolution capabilities of this instrument. A formalism, based on the leaky box model of cosmic ray propagation, was developed for obtaining isotopic abundance ratios at the cosmic ray sources from abundances measured in local interstellar space for elements having three or more stable isotopes, one of which is believed to be absent at the cosmic ray sources. It was shown that the dominant sources of uncertainty in the derived source ratios are uncorrelated errors in the fragmentation cross sections and statistical uncertainties in measuring local interstellar abundances. These results were applied to estimate the extent to which uncertainties must be reduced in order to distinguish between cosmic ray production in a solar-like environment and in various environments with greater neutron enrichments.

  2. Energy Spectra of Abundant Cosmic-ray Nuclei in Sources, According to the ATIC Experiment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Panov, A. D.; Sokolskaya, N. V.; Zatsepin, V. I., E-mail: panov@dec1.sinp.msu.ru

    One of the main results of the ATIC (Advanced Thin Ionization Calorimeter) experiment is a collection of energy spectra of abundant cosmic-ray nuclei: protons, He, C, O, Ne, Mg, Si, and Fe measured in terms of energy per particle in the energy range from 50 GeV to tens of teraelectronvolts. In this paper, the ATIC energy spectra of abundant primary nuclei are back-propagated to the spectra in sources in terms of magnetic rigidity using a leaky-box approximation of three different GALPROP-based diffusion models of propagation that fit the latest B/C data of the AMS-02 experiment. It is shown that themore » results of a comparison of the slopes of the spectra in sources are weakly model dependent; therefore the differences of spectral indices are reliable data. A regular growth of the steepness of spectra in sources in the range of magnetic rigidity of 50–1350 GV is found for a charge range from helium to iron. This conclusion is statistically reliable with significance better than 3.2 standard deviations. The results are discussed and compared to the data of other modern experiments.« less

  3. Solar particle abundances at energies of greater than 1 MeV per nucleon and the role of interplanetary shocks

    NASA Technical Reports Server (NTRS)

    Cane, H. V.; Reames, D. V.; Von Rosenvinge, T. T.

    1991-01-01

    The abundances of elements in large solar energetic-particle events in the energy range of 2-12 MeV per nucleon are examined. It is confirmed that the abundances relative to mean values vary approximately monotonically as a function of mass, except for He-4; some events show a gradual depletion of heavy ions, whereas a small number displays a gradual increase. A further organization of abundance data is shown, which depends on the longitude of the source region. Enhancements in Fe/C and other heavy elements relative to C occur when source regions are near west 60 deg; the enhancements are attributed to the sampling of a flare-heated material. Depletions of these elements are found to be greatest for source regions near central meridian; they are matched by a steepening of the spectrum and can be understood in terms of diffusive shock acceleration.

  4. HARNESSING OCEAN WAVE ENERGY TO GENERATE ELECTRICITY

    EPA Science Inventory

    A technical challenge to sustainability is finding an energy source that is abundant enough to meet global demands without producing greenhouse gases or radioactive waste. Energy from ocean surface waves can provide the people of this planet a clean, endless power source to me...

  5. Fusion energy science: Clean, safe, and abundant energy through innovative science and technology

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    Fusion energy science combines the study of the behavior of plasmas--the state of matter that forms 99% of the visible universe--with a vision of using fusion--the energy source of the stars--to create an affordable, plentiful, and environmentally benign energy source for humankind. The dual nature of fusion energy science provides an unfolding panorama of exciting intellectual challenge and a promise of an attractive energy source for generations to come. The goal of this report is a comprehensive understanding of plasma behavior leading to an affordable and attractive fusion energy source.

  6. The Development of Science Student Worksheet Based on Education for Environmental Sustainable Development to Enhance Scientific Literacy

    ERIC Educational Resources Information Center

    Ekantini, Anita; Wilujeng, Insih

    2018-01-01

    Indonesia is a country that has abundant renewable energy sources, one of which is hydropower that can be utilized as an alternative energy source. However, fossil energy remains as major supplier of energy needs in all sectors of activity. The Education for Environmental Sustainable Development (EESD) approach can be applied in science education…

  7. Number of hummingbird visits determines flower mite abundance on hummingbird feeders.

    PubMed

    Márquez-Luna, Ubaldo; Vázquez González, María Magdalena; Castellanos, Ignacio; Ortiz-Pulido, Raúl

    2016-08-01

    Members of several genera of mites from the family Melicharidae (Mesostigmata) use hummingbirds as transport host to move from flower to flower, where they feed on pollen and nectar. The factors that influence hummingbird flower mite abundance on host plant flowers are not currently known. Here we tested whether hummingbird flower mite abundance on an artificial nectar source is determined by number of hummingbird visits, nectar energy content or species richness of visiting hummingbirds. We conducted experiments employing hummingbird feeders with sucrose solutions of low, medium, and high energy concentrations, placed in a xeric shrubland. In the first experiment, we recorded the number of visiting hummingbirds and the number of visiting hummingbird species, as well as the abundance of hummingbird flower mites on each feeder. Feeders with the highest sucrose concentration had the most hummingbird visits and the highest flower mite abundances; however, there was no significant effect of hummingbird species richness on mite abundance. In the second experiment, we recorded flower mite abundance on feeders after we standardized the number of hummingbird visits to them. Abundance of flower mites did not differ significantly between feeders when we controlled for hummingbird visits. Our results suggest that nectar energy concentration determines hummingbird visits, which in turn determines flower mite abundance in our feeders. Our results do not support the hypothesis that mites descend from hummingbird nostrils more on richer nectar sources; however, it does not preclude the possibility that flower mites select for nectar concentration at other spatial and temporal scales.

  8. Observed antiprotons and energy dependent confinement of cosmic rays: A conflict?

    NASA Technical Reports Server (NTRS)

    Stephens, S. A.

    1985-01-01

    In the frame work of energy dependent confinement for cosmic rays, the energy spectrum inside the source is flatter than that observed. Antiproton observation suggests large amount of matter is being traversed by cosmic rays in some sources. As a result, secondary particles are produced in abundance. Their spectra was calculated and it is shown that the energy dependent confinement model is in conflict with some observations.

  9. A Speculative Approach to Design A Hybrid System for Green Energy

    NASA Astrophysics Data System (ADS)

    Sharma, Dinesh; Sharma, Purnima K.; Naidu, Praveen V.

    2017-08-01

    Now a day’s demand of energy is increasing all over the world. Because of this demand the fossils fuels are reducing day by day to meet the requirements of energy in daily life of human beings. It is necessary to balance the situation for the increasing energy demand by taking an optimistic overview about the natural renewable energy sources like sun, gust, hydro etc.,. These energy sources only can balance the situation of unbalancing between fossil fuels and increasing energy demand. Renewable energy systems are suitable for off grid services in power generation, to provide services to remote areas to build complex grid infrastructures. India has the abundant source of solar and wind energy. Individually these energy sources have some own advantages and disadvantages; to overcome the disadvantages of individual energy sources we can combine all these sources to make an efficient renewable source nothing but hybrid renewable energy source. In this paper we proposed a hybrid model which is a combination of four renewable energy sources solar, wind, RF signal and living plants to increase the energy efficiency.

  10. National Synchrotron Light Source II

    ScienceCinema

    Hill, John; Dooryhee, Eric; Wilkins, Stuart; Miller, Lisa; Chu, Yong

    2018-01-16

    NSLS-II is a synchrotron light source helping researchers explore solutions to the grand energy challenges faced by the nation, and open up new regimes of scientific discovery that will pave the way to discoveries in physics, chemistry, and biology — advances that will ultimately enhance national security and help drive the development of abundant, safe, and clean energy technologies.

  11. Abundance and Source Population of Suprathermal Heavy Ions in Corotating Interaction Regions

    NASA Astrophysics Data System (ADS)

    Jensema, R. J.; Desai, M. I.; Broiles, T. W.; Dayeh, M. A.

    2015-12-01

    In this study we analyze the abundances of suprathermal heavy ions in 75 Corotating Interaction Region (CIR) events between January 1st 1995 and December 31st 2008. We correlate the heavy ion abundances in these CIRs with those measured in the solar wind and suprathermal populations upstream of these events. Our analysis reveals that the CIR suprathermal heavy ion abundances vary by nearly two orders of magnitude over the solar activity cycle, with higher abundances (e.g., Fe/O) occurring during solar maximum and depleted values occurring during solar minimum. The abundances are also energy dependent, with larger abundances at higher energies, particularly during solar maximum. Following the method used by Mason et al. 2008, we correlate the CIR abundances with the corresponding solar wind and suprathermal values measured during 6-hour intervals for upstream periods spanning 10 days prior to the start of each CIR event. This correlation reveals that suprathermal heavy ions are better correlated with upstream suprathermal abundances measured at the same energy compared with the solar wind heavy ion abundances. Using the 6-hour averaging method, we also identified timeframes of maximum correlation between the CIR and the upstream suprathermal abundances, and find that the time of maximum correlation depends on the energy of the suprathermal ions. We discuss the implications of these results in terms of previous studies of CIR and suprathermal particles, and CIR seed populations and acceleration mechanisms.

  12. Ferrite Research Aimed at Improving Induction Linac Driven FEL performance. Phase 2

    DTIC Science & Technology

    1992-10-01

    energy costs and decrease our dependence on foreign energy sources. SO 2 control has used flue gas desulfurization scrubbers after combustion, coal...minimizing operating costs. . Dry Mode of Operation Conventional flue - gas treatment processes are generally wet systems which generate waste water and wet ...energy source in the United States. So reducing the SO 2 and NOx emission from flue gas will allow use of abundant, high-sulphur coal resources, lower

  13. Elemental composition of solar energetic particles. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Cook, W. R., III

    1981-01-01

    The Low Energy Telescopes on the Voyager spacecraft are used to measure the elemental composition (2 or = Z or = 28) and energy spectra (5 to 15 MeV/nucleon) of solar energetic particles (SEPs) in seven large flare events. Four flare events are selected which have SEP abundance ratios approximately independent of energy/nucleon. The abundances for these events are compared from flare to flare and are compared to solar abundances from other sources: spectroscopy of the photosphere and corona, and solar wind measurements. The four flare average SEP composition is significantly different from the solar composition determined by photospheric spectroscopy. The average SEP composition is in agreement with solar wind abundance results and with a number of recent coronal abundance measurements. The evidence for a common depletion of oxygen in SEPs, the corona and the solar wind relative to the photosphere suggest that the SEPs originate in the corona and that both the SEPs and solar wind sample a coronal composition which is significantly and persistently different from that of the photosphere.

  14. TEA: A Code Calculating Thermochemical Equilibrium Abundances

    NASA Astrophysics Data System (ADS)

    Blecic, Jasmina; Harrington, Joseph; Bowman, M. Oliver

    2016-07-01

    We present an open-source Thermochemical Equilibrium Abundances (TEA) code that calculates the abundances of gaseous molecular species. The code is based on the methodology of White et al. and Eriksson. It applies Gibbs free-energy minimization using an iterative, Lagrangian optimization scheme. Given elemental abundances, TEA calculates molecular abundances for a particular temperature and pressure or a list of temperature-pressure pairs. We tested the code against the method of Burrows & Sharp, the free thermochemical equilibrium code Chemical Equilibrium with Applications (CEA), and the example given by Burrows & Sharp. Using their thermodynamic data, TEA reproduces their final abundances, but with higher precision. We also applied the TEA abundance calculations to models of several hot-Jupiter exoplanets, producing expected results. TEA is written in Python in a modular format. There is a start guide, a user manual, and a code document in addition to this theory paper. TEA is available under a reproducible-research, open-source license via https://github.com/dzesmin/TEA.

  15. TEA: A CODE CALCULATING THERMOCHEMICAL EQUILIBRIUM ABUNDANCES

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Blecic, Jasmina; Harrington, Joseph; Bowman, M. Oliver, E-mail: jasmina@physics.ucf.edu

    2016-07-01

    We present an open-source Thermochemical Equilibrium Abundances (TEA) code that calculates the abundances of gaseous molecular species. The code is based on the methodology of White et al. and Eriksson. It applies Gibbs free-energy minimization using an iterative, Lagrangian optimization scheme. Given elemental abundances, TEA calculates molecular abundances for a particular temperature and pressure or a list of temperature–pressure pairs. We tested the code against the method of Burrows and Sharp, the free thermochemical equilibrium code Chemical Equilibrium with Applications (CEA), and the example given by Burrows and Sharp. Using their thermodynamic data, TEA reproduces their final abundances, but withmore » higher precision. We also applied the TEA abundance calculations to models of several hot-Jupiter exoplanets, producing expected results. TEA is written in Python in a modular format. There is a start guide, a user manual, and a code document in addition to this theory paper. TEA is available under a reproducible-research, open-source license via https://github.com/dzesmin/TEA.« less

  16. Space-based measurements of elemental abundances and their relation to solar abundances

    NASA Technical Reports Server (NTRS)

    Coplan, M. A.; Ogilvie, K. W.; Bochsler, P.; Geiss, J.

    1990-01-01

    The Ion Composition Instrument (ICI) aboard the ISEE-3/ICE spacecraft was in the solar wind continuously from August 1978 to December 1982. The results made it possible to establish long-term average solar wind abundance values for helium, oxygen, neon, silicon, and iron. The Charge-Energy-Mass instrument aboard the CCE spacecraft of the AMPTE mission has measured the abundance of these elements in the magnetosheath and has also added carbon, nitrogen, magnesium, and sulfur to the list. There is strong evidence that these magnetosheath abundances are representative of the solar wind. Other sources of solar wind abundances are Solar Energetic Particle experiments and Apollo lunar foils. When comparing the abundances from all of these sources with photospheric abundances, it is clear that helium is depleted in the solar wind while silicon and iron are enhanced. Solar wind abundances for carbon, nitrogen, oxygen, and neon correlate well with the photospheric values. The incorporation of minor ions into the solar wind appears to depend upon both the ionization times for the elements and the Coulomb drag exerted by the outflowing proton flux.

  17. Implications of new measurements of O-16 + p + C-12,13, N-14,15 for the abundances of C, N isotopes at the cosmic ray source

    NASA Technical Reports Server (NTRS)

    Guzik, T. G.; Wefel, J. P.; Crawford, H. J.; Greiner, D. E.; Lindstrom, P. J.; Schimmerling, W.; Symons, T. J. M.

    1985-01-01

    The fragmentation of a 225 MeV/n O-16 beam was investigated at the Bevalac. Preliminary cross sections for mass = 13, 14, 15 fragments are used to constrain the nuclear excitation functions employed in galactic propagation calculations. Comparison to cosmic ray isotonic data at low energies shows that in the cosmic ray source C-13/C approximately 2% and N-14/0=3-6%. No source abundance of N-15 is required with the current experimental results.

  18. Digestion and Absorption of Carbohydrates

    USDA-ARS?s Scientific Manuscript database

    Carbohydrates are the major dietary sources of energy for humans. While most dietary carbohydrates are derived from multiple botanical sources, lactose and trehalose are the only animal-derived carbohydrates. Digestion of starch, the carbohydrate most abundantly consumed by humans, depends on the c...

  19. The isotopic composition of cosmic ray calcium

    NASA Technical Reports Server (NTRS)

    Krombel, K. E.; Wiedenbeck, M. E.

    1985-01-01

    Data from the high energy cosmic ray experiment on the international sun earth explorer 3 (ISEE-3) spacecraft have been used to study the isotopic composition of cosmic ray calcium at an energy of approx. 260 MeV/amu. The arriving calcium is found to consist of (32 + or - 6)%. A propagation model consistent with both the light and the subiron secondary element abundances was used for the interpretation of the observed calcium composition. The measured 42Ca+43Ca+44Ca abundance is consistent with the calculated secondary production, while the 40Ca abundance implies a source ratio of 40Ca/Fe = (7.0 + or - 1.7)%.

  20. Cosmic-ray elemental abundances from 1 to 10 GeV per amu for boron through nickel

    NASA Technical Reports Server (NTRS)

    Dwyer, Robert; Meyer, Peter

    1987-01-01

    The relative abundances of cosmic-ray nuclei in the charge range boron through nickel over the energy range 1-10 GeV per amu were measured with a balloon-borne detector. The instrument consists of a scintillation and Cerenkov counter telescope with a multiwire proportional chamber hodoscope and has been flown in four high-altitude balloon flights. Good charge resolution (sigma = 0.2 charge units at iron) and high statistical accuracy have been achieved. These data are used to derive the energy dependence of the leakage path length using the leaky box model of propagation and confinement in the galaxy. This energy dependence is found to be best fit by lambda = E(tot) exp -n, where n = 0.49 + or - 0.06 over 1-10 GeV per amu. Relative abundances at the source are consistent with an energy-independent composition.

  1. The Electrification of Energy: Long-Term Trends and Opportunities

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tsao, Jeffrey Y.; Fouquet, Roger; Schubert, E. Fred

    Here, we present and analyze three powerful long-term historical trends in energy, particularly electrical energy, as well as the opportunities and challenges associated with these trends. The first trend is from a world containing a diversity of energy currencies to one whose predominant currency is electricity, driven by electricity’s transportability, exchangeability, and steadily decreasing cost. The second trend is from electricity generated from a diversity of sources to electricity generated predominantly by free-fuel sources, driven by their steadily decreasing cost and long-term abundance. These trends necessitate a just-emerging third trend: from a grid in which electricity is transported uni-directionally, tradedmore » at near-static prices, and consumed under direct human control; to a grid in which electricity is transported bi-directionally, traded at dynamic prices, and consumed under human-tailored agential control. Early acceptance and appreciation of these trends will accelerate their remaking of humanity’s energy landscape into one in which energy is much more affordable, abundant and efficiently deployed than it is today; with major economic, geo-political, and environmental benefits to human society.« less

  2. Bayesian Atmospheric Radiative Transfer (BART)Thermochemical Equilibrium Abundance (TEA) Code and Application to WASP-43b

    NASA Astrophysics Data System (ADS)

    Blecic, Jasmina; Harrington, Joseph; Bowman, Matthew O.; Cubillos, Patricio E.; Stemm, Madison; Foster, Andrew

    2014-11-01

    We present a new, open-source, Thermochemical Equilibrium Abundances (TEA) code that calculates the abundances of gaseous molecular species. TEA uses the Gibbs-free-energy minimization method with an iterative Lagrangian optimization scheme. It initializes the radiative-transfer calculation in our Bayesian Atmospheric Radiative Transfer (BART) code. Given elemental abundances, TEA calculates molecular abundances for a particular temperature and pressure or a list of temperature-pressure pairs. The code is tested against the original method developed by White at al. (1958), the analytic method developed by Burrows and Sharp (1999), and the Newton-Raphson method implemented in the open-source Chemical Equilibrium with Applications (CEA) code. TEA is written in Python and is available to the community via the open-source development site GitHub.com. We also present BART applied to eclipse depths of WASP-43b exoplanet, constraining atmospheric thermal and chemical parameters. This work was supported by NASA Planetary Atmospheres grant NNX12AI69G and NASA Astrophysics Data Analysis Program grant NNX13AF38G. JB holds a NASA Earth and Space Science Fellowship.

  3. Growth of sedimentary Bathyarchaeota on lignin as an energy source.

    PubMed

    Yu, Tiantian; Wu, Weichao; Liang, Wenyue; Lever, Mark Alexander; Hinrichs, Kai-Uwe; Wang, Fengping

    2018-06-05

    Members of the archaeal phylum Bathyarchaeota are among the most abundant microorganisms on Earth. Although versatile metabolic capabilities such as acetogenesis, methanogenesis, and fermentation have been suggested for bathyarchaeotal members, no direct confirmation of these metabolic functions has been achieved through growth of Bathyarchaeota in the laboratory. Here we demonstrate, on the basis of gene-copy numbers and probing of archaeal lipids, the growth of Bathyarchaeota subgroup Bathy-8 in enrichments of estuarine sediments with the biopolymer lignin. Other organic substrates (casein, oleic acid, cellulose, and phenol) did not significantly stimulate growth of Bathyarchaeota Meanwhile, putative bathyarchaeotal tetraether lipids incorporated 13 C from 13 C-bicarbonate only when added in concert with lignin. Our results are consistent with organoautotrophic growth of a bathyarchaeotal group with lignin as an energy source and bicarbonate as a carbon source and shed light into the cycling of one of Earth's most abundant biopolymers in anoxic marine sediment.

  4. Rice husks as a sustainable source of nanostructured silicon for high performance Li-ion battery anodes

    PubMed Central

    Liu, Nian; Huo, Kaifu; McDowell, Matthew T.; Zhao, Jie; Cui, Yi

    2013-01-01

    The recovery of useful materials from earth-abundant substances is of strategic importance for industrial processes. Despite the fact that Si is the second most abundant element in the Earth's crust, processes to form Si nanomaterials is usually complex, costly and energy-intensive. Here we show that pure Si nanoparticles (SiNPs) can be derived directly from rice husks (RHs), an abundant agricultural byproduct produced at a rate of 1.2 × 108 tons/year, with a conversion yield as high as 5% by mass. And owing to their small size (10–40 nm) and porous nature, these recovered SiNPs exhibits high performance as Li-ion battery anodes, with high reversible capacity (2,790 mA h g−1, seven times greater than graphite anodes) and long cycle life (86% capacity retention over 300 cycles). Using RHs as the raw material source, overall energy-efficient, green, and large scale synthesis of low-cost and functional Si nanomaterials is possible. PMID:23715238

  5. A measurement of the cosmic ray elements C to Fe in the two energy intervals 0.5-2.0 GeV/n and 20-60 GeV/n

    NASA Technical Reports Server (NTRS)

    Derrickson, J. H.; Parnell, T. A.; Watts, J. W.; Gregory, J. C.

    1985-01-01

    The study of the cosmic ray abundances beyond 20 GeV/n provides additional information on the propagation and containment of the cosmic rays in the galaxy. Since the average amount of interstellar material traversed by cosmic rays decreases as its energy increases, the source composition undergoes less distortion in this higher energy region. However, data over a wide energy range is necessary to study propagation parameters. Some measurements of some of the primary cosmic ray abundance ratios at both low (near 2 GeV/n) and high (above 20 GeV/n) energy are given and compared to the predictions of the leaky box mode. In particular, the integrated values (above 23.7 GeV/n) for the more abundant cosmic ray elements in the interval C through Fe and the differential flux for carbon, oxygen, and the Ne, Mg, Si group are presented. Limited statistics prevented the inclusion of the odd Z elements.

  6. Iceland's Central Highlands: Nature conservation, ecotourism, and energy resource utilization

    Treesearch

    Bjorn Gunnarsson; Maria-Victoria Gunnarsson

    2002-01-01

    Iceland’s natural resources include an abundance of geothermal energy and hydropower, of which only 10 to 15 percent is currently being utilized. These are clean, renewable sources of energy. The cost to convert these resources to electricity is relatively low, making them attractive and highly marketable for industrial development, particularly for heavy industry....

  7. Recyclable organic solar cells on cellulose nanocrystal substrates

    Treesearch

    Yinhua Zhou; Canek Fuentes-Hernandez; Talha M. Khan; Jen-Chieh Liu; James Hsu; Jae Won Shim; Amir Dindar; Jeffrey P. Youngblood; Robert J. Moon; Bernard Kippelen

    2013-01-01

    Solar energy is potentially the largest source of renewable energy at our disposal, but significant advances are required to make photovoltaic technologies economically viable and, from a life-cycle perspective, environmentally friendly, and consequently scalable. Cellulose nanomaterials are emerging high-value nanoparticles extracted from plants that are abundant,...

  8. Carbon-Nanotube-Based Thermoelectric Materials and Devices

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Blackburn, Jeffrey L.; Ferguson, Andrew J.; Cho, Chungyeon

    Conversion of waste heat to voltage has the potential to significantly reduce the carbon footprint of a number of critical energy sectors, such as the transportation and electricity-generation sectors, and manufacturing processes. Thermal energy is also an abundant low-flux source that can be harnessed to power portable/wearable electronic devices and critical components in remote off-grid locations. As such, a number of different inorganic and organic materials are being explored for their potential in thermoelectric-energy-harvesting devices. Carbon-based thermoelectric materials are particularly attractive due to their use of nontoxic, abundant source-materials, their amenability to high-throughput solution-phase fabrication routes, and the high specificmore » energy (i.e., W g-1) enabled by their low mass. Single-walled carbon nanotubes (SWCNTs) represent a unique 1D carbon allotrope with structural, electrical, and thermal properties that enable efficient thermoelectric-energy conversion. Here, the progress made toward understanding the fundamental thermoelectric properties of SWCNTs, nanotube-based composites, and thermoelectric devices prepared from these materials is reviewed in detail. This progress illuminates the tremendous potential that carbon-nanotube-based materials and composites have for producing high-performance next-generation devices for thermoelectric-energy harvesting.« less

  9. Carbon-Nanotube-Based Thermoelectric Materials and Devices

    DOE PAGES

    Blackburn, Jeffrey L.; Ferguson, Andrew J.; Cho, Chungyeon; ...

    2018-01-22

    Conversion of waste heat to voltage has the potential to significantly reduce the carbon footprint of a number of critical energy sectors, such as the transportation and electricity-generation sectors, and manufacturing processes. Thermal energy is also an abundant low-flux source that can be harnessed to power portable/wearable electronic devices and critical components in remote off-grid locations. As such, a number of different inorganic and organic materials are being explored for their potential in thermoelectric-energy-harvesting devices. Carbon-based thermoelectric materials are particularly attractive due to their use of nontoxic, abundant source-materials, their amenability to high-throughput solution-phase fabrication routes, and the high specificmore » energy (i.e., W g-1) enabled by their low mass. Single-walled carbon nanotubes (SWCNTs) represent a unique 1D carbon allotrope with structural, electrical, and thermal properties that enable efficient thermoelectric-energy conversion. Here, the progress made toward understanding the fundamental thermoelectric properties of SWCNTs, nanotube-based composites, and thermoelectric devices prepared from these materials is reviewed in detail. This progress illuminates the tremendous potential that carbon-nanotube-based materials and composites have for producing high-performance next-generation devices for thermoelectric-energy harvesting.« less

  10. Carbon-Nanotube-Based Thermoelectric Materials and Devices.

    PubMed

    Blackburn, Jeffrey L; Ferguson, Andrew J; Cho, Chungyeon; Grunlan, Jaime C

    2018-03-01

    Conversion of waste heat to voltage has the potential to significantly reduce the carbon footprint of a number of critical energy sectors, such as the transportation and electricity-generation sectors, and manufacturing processes. Thermal energy is also an abundant low-flux source that can be harnessed to power portable/wearable electronic devices and critical components in remote off-grid locations. As such, a number of different inorganic and organic materials are being explored for their potential in thermoelectric-energy-harvesting devices. Carbon-based thermoelectric materials are particularly attractive due to their use of nontoxic, abundant source-materials, their amenability to high-throughput solution-phase fabrication routes, and the high specific energy (i.e., W g -1 ) enabled by their low mass. Single-walled carbon nanotubes (SWCNTs) represent a unique 1D carbon allotrope with structural, electrical, and thermal properties that enable efficient thermoelectric-energy conversion. Here, the progress made toward understanding the fundamental thermoelectric properties of SWCNTs, nanotube-based composites, and thermoelectric devices prepared from these materials is reviewed in detail. This progress illuminates the tremendous potential that carbon-nanotube-based materials and composites have for producing high-performance next-generation devices for thermoelectric-energy harvesting. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Galactic Cosmic Rays: From Earth to Sources

    NASA Technical Reports Server (NTRS)

    Brandt, Theresa J.

    2012-01-01

    For nearly 100 years we have known that cosmic rays come from outer space, yet proof of their origin, as well as a comprehensive understanding of their acceleration, remains elusive. Direct detection of high energy (up to 10(exp 15)eV), charged nuclei with experiments such as the balloon-born, antarctic Trans-Iron Galactic Element Recorder (TIGER) have provided insight into these mysteries through measurements of cosmic ray abundances. The abundance of these rare elements with respect to certain intrinsic properties suggests that cosmic rays include a component of massive star ejecta. Supernovae and their remnants (SNe & SNRs), often occurring at the end of a massive star's life or in an environment including massive star material, are one of the most likely candidates for sources accelerating galactic comic ray nuclei up to the requisite high energies. The Fermi Gamma-ray Space Telescope Large Area Detector (Fermi LAT) has improved our understanding of such sources by widening the window of observable energies and thus into potential sources' energetic processes. In combination with multiwavelength observations, we are now better able to constrain particle populations (often hadron-dominated at GeV energies) and environmental conditions, such as the magnetic field strength. The SNR CTB 37A is one such source which could contribute to the observed galactic cosmic rays. By assembling populations of SNRs, we will be able to more definitively define their contribution to the observed galactic cosmic rays, as well as better understand SNRs themselves. Such multimessenger studies will thus illuminate the long-standing cosmic ray mysteries, shedding light on potential sources, acceleration mechanisms, and cosmic ray propagation.

  12. Effects of disturbance on contribution of energy sources to growth of juvenile chinook salmon (Oncorhynchus tshawytscha) in boreal streams

    USGS Publications Warehouse

    Perry, R.W.; Bradford, M.J.; Grout, J.A.

    2003-01-01

    We used stable isotopes of carbon in a growth-dependent tissue-turnover model to quantify the relative contribution of autochthonous and terrestrial energy sources to juvenile chinook salmon (Oncorhynchus tshawytscha) in five small boreal streams tributary to the upper Yukon River. We used a tissue-turnover model because fish did not grow enough to come into isotopic equilibrium with their diet. In two streams, autochthonous energy sources contributed 23 and 41% to the growth of juvenile salmon. In the other three, fish growth was largely due to terrestrial (i.e., allochthonous) energy sources. This low contribution of autochthonous energy appeared to be related to stream-specific disturbances: a recent forest fire impacted two of the streams and the third was affected by a large midsummer spate during the study. These disturbances reduced the relative abundance of herbivorous macroinvertebrates, the contribution of autochthonous material to other invertebrates, and ultimately, the energy flow between stream algae and fish. Our findings suggest that disturbances to streams can be an important mechanism affecting transfer of primary energy sources to higher trophic levels.

  13. Implications of the experimental results on high energy cosmic rays with regard to their origin

    NASA Technical Reports Server (NTRS)

    Fichtel, C. E.; Linsley, J.

    1985-01-01

    It was shown in an earlier report that current cosmic ray evidence supports a change in the cosmic ray composition in the region between 10 to the 6th power and 10 to the 8th power GeV total energy in the direction of a smaller average value of A. Compared to normal celestial abundances, the heavy nuclei are much less abundant, and, in fact, the composition measurements above 10 to the 8th power GeV are consistent with there being only protons. Here, these results combined with those of the energy spectrum and anisotropy of the comsic rays and other astrophysical information will be examined to try to determine their implications for the origin of the cosmic rays. In this paper, consideration is given to the implications of one or more than one type of source in the galaxy to see which are consistent with the interpretation of current measurements. The nature of the source types that would be required are discussed.

  14. Increased energy expenditure by a seabird in response to higher food abundance

    USGS Publications Warehouse

    Jodice, P.G.R.; Roby, D.D.; Suryan, R.M.; Irons, D.B.; Turco, K.R.; Brown, E.D.; Thedinga, J.F.; Visser, G. Henk

    2006-01-01

    Variability in forage fish abundance strongly affects seabird behavior and reproductive success, although details of this relationship are unclear. During 1997 and 1998, we measured (1) daily energy expenditure (DEE) of 80 parent black-legged kittiwakes Rissa tridactyla at 2 colonies in Prince William Sound, Alaska (North Icy Bay and Shoup Bay), (2) abundance of surface-schooling forage fishes within the foraging range of each colony, and (3) diet composition, energy delivery rates to nestlings, and reproductive success of kittiwakes at these same colonies. Female DEE was highest at North Icy Bay in 1998, while male DEE did not differ by colony year. Abundances of Pacific herring Clupea pallasi and sand lance Ammodytes hexapterus were highest near North Icy Bay in 1998 and nearly egual in density, although Age 1+ herring comprised the majority of the diet there. Energy delivery rates to nestlings, nestling growth rates, and productivity were also highest at North Icy Bay in 1998. We suggest that female kittiwakes responded to the increased abundance of Age 1+ herring near North Icy Bay in 1998 by increasing their DEE, which in turn positively affected reproductive success. Given that adult kittiwakes have been shown to suffer decreased survival as a response to increased energy expenditure during brood rearing, the positive correlation we observed between increased abundance of a high quality food source, parental effort, and productivity is consistent with maximizing lifetime reproductive success. The lack of a response in male DEE suggests that brood-rearing roles in kittiwakes differ between genders. ?? Inter-Research 2006.

  15. A brief review of intermediate controlled nuclear syntheses (ICNS) without harmful radiations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lanjewar, R. B.

    Hadronic mechanics gave birth to new magnecular fuels. The present day demand is of clean energy source that is cheap and abundant. Clean energy can be obtained by harnessing renewable energy sources like solar, wind etc. Nuclear energy conventionally produced by fission reactions emits hazardous radiation and radioactive waste. The requirements of clean and safe energy gets fulfilled by novel fuel that achieved by elevating the traditional quantum mechanics to hadronic mechanics and to hadronic chemistry. In the present paper, a comprehensive review on both the theoretical and experimental aspect of the Intermediate Controlled Nuclear Synthesis (ICNS) as developed bymore » Italian American Scientist Professor R. M. Santilli.« less

  16. Particle Acceleration at the Sun and in the Heliosphere

    NASA Technical Reports Server (NTRS)

    Reames, Donald V.

    1999-01-01

    Energetic particles are accelerated in rich profusion at sites throughout the heliosphere. They come from solar flares in the low corona, from shock waves driven outward by coronal mass ejections (CMEs), from planetary magnetospheres and bow shocks. They come from corotating interaction regions (CIRs) produced by high-speed streams in the solar wind, and from the heliospheric termination shock at the outer edge of the heliospheric cavity. We sample all these populations near Earth, but can distinguish them readily by their element and isotope abundances, ionization states, energy spectra, angular distributions and time behavior. Remote spacecraft have probed the spatial distributions of the particles and examined new sources in situ. Most acceleration sources can be "seen" only by direct observation of the particles; few photons are produced at these sites. Wave-particle interactions are an essential feature in acceleration sources and, for shock acceleration, new evidence of energetic-proton-generated waves has come from abundance variations and from local cross-field scattering. Element abundances often tell us the physics the source plasma itself, prior to acceleration. By comparing different populations, we learn more about the sources, and about the physics of acceleration and transport, than we can possibly learn from one source alone.

  17. Science in 60 – A Clean, Renewable Power Source

    ScienceCinema

    Borup, Rod

    2018-06-12

    Fuel cells have long been one of the most tantalizing clean-energy solutions. They offer electricity from an abundant energy source—hydrogen. Compared to internal combustion engines, fuel cells are more than twice as efficient at converting fuel to power, but are currently dependent on costly platinum. Rod Borup and his team at Los Alamos National Lab are leading efforts to reduce the cost of fuel cells and are exploring alternatives that could eliminate platinum all together.

  18. Seattle's System for Evaluating Energy Options

    NASA Technical Reports Server (NTRS)

    Logie, P.; Macdonald, M. J.

    1982-01-01

    In 1975, the City Council developed a blueprint called "Energy 1990" for meeting Seattle's future electric energy needs. Priorities for addressing or offsetting expected growth in demand are in order: (1) conservation; (2) hydroelectricity; (3) other renewable sources such as wind, biomass, solar, and geothermal energy; (4) abundant nonrenewable resources such as coal, and (5) other renewables. An energy resources planning group was formed and a data base was established. Resource options were investigated and the recommendations were published.

  19. Energy harvesting from low frequency applications using piezoelectric materials

    DOE PAGES

    Li, Huidong; Tian, Chuan; Deng, Z. Daniel

    2014-11-06

    This paper reviewed the state of research on piezoelectric energy harvesters. Various types of harvester configurations, piezoelectric materials, and techniques used to improve the mechanical-to-electrical energy conversion efficiency were discussed. Most of the piezoelectric energy harvesters studied today have focused on scavenging mechanical energy from vibration sources due to their abundance in both natural and industrial environments. Cantilever beams have been the most studied structure for piezoelectric energy harvester to date because of the high responsiveness to small vibrations.

  20. Towards greener and more sustainable batteries for electrical energy storage

    NASA Astrophysics Data System (ADS)

    Larcher, D.; Tarascon, J.-M.

    2015-01-01

    Ever-growing energy needs and depleting fossil-fuel resources demand the pursuit of sustainable energy alternatives, including both renewable energy sources and sustainable storage technologies. It is therefore essential to incorporate material abundance, eco-efficient synthetic processes and life-cycle analysis into the design of new electrochemical storage systems. At present, a few existing technologies address these issues, but in each case, fundamental and technological hurdles remain to be overcome. Here we provide an overview of the current state of energy storage from a sustainability perspective. We introduce the notion of sustainability through discussion of the energy and environmental costs of state-of-the-art lithium-ion batteries, considering elemental abundance, toxicity, synthetic methods and scalability. With the same themes in mind, we also highlight current and future electrochemical storage systems beyond lithium-ion batteries. The complexity and importance of recycling battery materials is also discussed.

  1. Evidence for hydrogen oxidation and metabolic plasticity in widespread deep-sea sulfur-oxidizing bacteria.

    PubMed

    Anantharaman, Karthik; Breier, John A; Sheik, Cody S; Dick, Gregory J

    2013-01-02

    Hydrothermal vents are a well-known source of energy that powers chemosynthesis in the deep sea. Recent work suggests that microbial chemosynthesis is also surprisingly pervasive throughout the dark oceans, serving as a significant CO(2) sink even at sites far removed from vents. Ammonia and sulfur have been identified as potential electron donors for this chemosynthesis, but they do not fully account for measured rates of dark primary production in the pelagic water column. Here we use metagenomic and metatranscriptomic analyses to show that deep-sea populations of the SUP05 group of uncultured sulfur-oxidizing Gammaproteobacteria, which are abundant in widespread and diverse marine environments, contain and highly express genes encoding group 1 Ni, Fe hydrogenase enzymes for H(2) oxidation. Reconstruction of near-complete genomes of two cooccurring SUP05 populations in hydrothermal plumes and deep waters of the Gulf of California enabled detailed population-specific metatranscriptomic analyses, revealing dynamic patterns of gene content and transcript abundance. SUP05 transcripts for genes involved in H(2) and sulfur oxidation are most abundant in hydrothermal plumes where these electron donors are enriched. In contrast, a second hydrogenase has more abundant transcripts in background deep-sea samples. Coupled with results from a bioenergetic model that suggest that H(2) oxidation can contribute significantly to the SUP05 energy budget, these findings reveal the potential importance of H(2) as a key energy source in the deep ocean. This study also highlights the genomic plasticity of SUP05, which enables this widely distributed group to optimize its energy metabolism (electron donor and acceptor) to local geochemical conditions.

  2. Ultra-Heavy Galactic Cosmic Ray Abundances from the SuperTIGER Instrument: evidence for an OB association origin of GCR

    NASA Astrophysics Data System (ADS)

    Murphy, Ryan; Supertiger Collaboration

    2017-01-01

    We report Galactic Cosmic Ray (GCR) abundances of elements from 26Fe to 40Zr measured by the SuperTIGER (Trans-Iron Galactic Element Recorder) instrument during 55 days of exposure on a long-duration balloon flight over Antarctica. SuperTIGER measures charge (Z) and energy (E) using a combination of three scintillator and two Cherenkov detectors, and employs a scintillating fiber hodoscope for event trajectory determination. These observations resolve elemental abundances in this charge range with single-element resolution and good statistics. We also derived GCR source abundances, which support a model of cosmic-ray origin in which the source material consists of a mixture of 19-6+ 11 % material from massive stars and 81% normal interstellar medium (ISM) material with solar system abundances. The results also show a preferential acceleration, ordered by atomic mass (A), of refractory elements over volatile elements by a factor of 4. Both the refractory and volatile elements show a mass-dependent enhancement with similar mass dependence. (now AIP Congressional Science Fellow).

  3. New Constraints on the Geometry and Kinematics of Matter Surrounding the Accretion Flow in X-Ray Binaries from Chandra High-Energy Transmission Grating X-Ray Spectroscopy

    NASA Technical Reports Server (NTRS)

    Tzanavaris, P.; Yaqoob, T.

    2018-01-01

    The narrow, neutral Fe Ka fluorescence emission line in X-ray binaries (XRBs) is a powerful probe of the geometry, kinematics, and Fe abundance of matter around the accretion flow. In a recent study it has been claimed, using Chandra High-Energy Transmission Grating (HETG) spectra for a sample of XRBs, that the circumnuclear material is consistent with a solar-abundance, uniform, spherical distribution. It was also claimed that the Fe Ka line was unresolved in all cases by the HETG. However, these conclusions were based on ad hoc models that did not attempt to relate the global column density to the Fe Ka line emission. We revisit the sample and test a self-consistent model of a uniform, spherical X-ray reprocessor against HETG spectra from 56 observations of 14 Galactic XRBs. We find that the model is ruled out in 13/14 sources because a variable Fe abundance is required. In two sources a spherical distribution is viable, but with nonsolar Fe abundance. We also applied a solar-abundance Compton-thick reflection model, which can account for the spectra that are inconsistent with a spherical model, but spectra with a broader bandpass are required to better constrain model parameters. We also robustly measured the velocity width of the Fe Ka line and found FWHM values of up to approx. 5000 km/s. Only in some spectra was the Fe Ka line unresolved by the HETG.

  4. Iron line emission from a high temperature plasma in Cas A

    NASA Technical Reports Server (NTRS)

    Pravdo, S. H.; Becker, R. H.; Boldt, E. A.; Holt, S. S.; Rothschild, R. E.; Serlemitsos, P. J.; Swank, J. H.

    1976-01-01

    The X-ray spectrum of Cassiopeia A was observed for several days by the proportional counter experiment on board OSO-8. The high energy ( 5 keV) data are fit well by a thermal spectrum. A narrow iron line which is predicted by the thermal model is also observed. The low energy (2-5 keV) data show an excess over the high temperature component which is consistent with the presence of an additional low temperature thermal component. Iron abundance in the source relative to normal cosmic abundance is discussed, as in the relation of this observation to shock wave and multi-component thermal models for supernova remnants.

  5. Preliminary study of fusion reactor: Solution of Grad Shapranov equation

    NASA Astrophysics Data System (ADS)

    Setiawan, Y.; Fermi, N.; Su'ud, Z.

    2012-06-01

    Nuclear fussion is prospective energy sources for the future due to the abundance of the fuel and can be categorized and clean energy sources. The problem is how to contain very hot plasma of temperature few hundreed million degrees safety and reliably. Tokamax type fussion reactors is considered as the most prospective concept. To analyze the plasma confining process and its movement Grad-Shavranov equation must be solved. This paper discuss about solution of Grad-Shavranov equation using Whittaker function. The formulation is then applied to the ITER design and example.

  6. Multi-scale Characterization of Improved Algae Strains

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dale, Taraka T.

    This report relays the important role biofuels such as algae could have in the energy market. The report cites that problem of crude oil becoming less abundant while the demand for energy continues to rise. There are many benefits of producing energy with biofuels such as fewer carbon emissions as well as less land area to produce the same amount of energy compared to other sources of renewable fuels. One challenge that faces biofuels right now is the cost to produce it is high.

  7. Comparisons of microplastic pollution between mudflats and sandy beaches in Hong Kong.

    PubMed

    Lo, Hoi-Shing; Xu, Xiaoyu; Wong, Chun-Yuen; Cheung, Siu-Gin

    2018-05-01

    Most of the previous studies of microplastic pollution on coastal habitats focused on high energy beaches although low energy areas such as mudflats are supposed to retain more microplastics, not to mention that mudflats are biologically more diverse. We quantified and characterized microplastics from 10 mudflats and 10 sandy beaches in Hong Kong spanning from the eastern to western waters. Sediment samples were collected at 1.0 m and 1.5 m above chart datum (CD) and at the strandline. Abundance of microplastics ranged between 0.58 and 2116 items kg -1 sediment with that on mudflats being ten times more than on beaches. Polyethylene (46.9%) was the most abundant and followed by polypropylene (13.8%) and polyethylene terephthalate (13.5%). Expanded polystyrene was the most abundant in the strandline samples but not at 1.0 m and 1.5 m above CD. Although previous studies have concluded that the input from Pearl River is a major source of microplastics on Hong Kong shores, this study has demonstrated that the contribution of local pollution sources such as discharge from sewage treatment plants to microplastic pollution should not be neglected. Copyright © 2018 Elsevier Ltd. All rights reserved.

  8. Nucleosynthesis in Primordial Hypernovae

    NASA Astrophysics Data System (ADS)

    Grimmett, J. J.; Heger, Alexander; Karakas, Amanda I.; Müller, Bernhard

    2018-06-01

    We investigate the relationship between explosion energy and nucleosynthesis in Population III supernovae and provide nucleosynthetic results for the explosions of stars with progenitor masses of 15 M⊙, 20 M⊙, 30 M⊙, 40 M⊙, 60 M⊙, and 80 M⊙, and explosion energies between approximately 1050 erg and 1053 erg. We find that the typical abundance pattern observed in metal-poor stars are best matched by supernovae with progenitor mass in the range 15 M⊙ - 30 M⊙, and explosion energy of ˜(5 - 10) × 1051 erg. In these models, a reverse shock caused by jumps in density between shells of different composition serves to decrease synthesis of chromium and manganese, which is favourable to matching the observed abundances in metal-poor stars. Spherically symmetric explosions of our models with progenitor mass ≥40 M⊙ do not provide yields that are compatible with the iron-peak abundances that are typically observed in metal-poor stars, however, by approximating the yields that we might expect from these models in highly aspherical explosions, we find indications that explosions of stars 40 M⊙ - 80 M⊙ with bipolar jets may be good candidates for the enrichment sources of metal-poor stars with enhanced carbon abundances.

  9. Preserving Source Location Privacy for Energy Harvesting WSNs.

    PubMed

    Huang, Changqin; Ma, Ming; Liu, Yuxin; Liu, Anfeng

    2017-03-30

    Fog (From cOre to edGe) computing employs a huge number of wireless embedded devices to enable end users with anywhere-anytime-to-anything connectivity. Due to their operating nature, wireless sensor nodes often work unattended, and hence are exposed to a variety of attacks. Preserving source-location privacy plays a key role in some wireless sensor network (WSN) applications. In this paper, a redundancy branch convergence-based preserved source location privacy scheme (RBCPSLP) is proposed for energy harvesting sensor networks, with the following advantages: numerous routing branches are created in non-hotspot areas with abundant energy, and those routing branches can merge into a few routing paths before they reach the hotspot areas. The generation time, the duration of routing, and the number of routing branches are then decided independently based on the amount of energy obtained, so as to maximize network energy utilization, greatly enhance privacy protection, and provide long network lifetimes. Theoretical analysis and experimental results show that the RBCPSLP scheme allows a several-fold improvement of the network energy utilization as well as the source location privacy preservation, while maximizing network lifetimes.

  10. Preserving Source Location Privacy for Energy Harvesting WSNs

    PubMed Central

    Huang, Changqin; Ma, Ming; Liu, Yuxin; Liu, Anfeng

    2017-01-01

    Fog (From cOre to edGe) computing employs a huge number of wireless embedded devices to enable end users with anywhere-anytime-to-anything connectivity. Due to their operating nature, wireless sensor nodes often work unattended, and hence are exposed to a variety of attacks. Preserving source-location privacy plays a key role in some wireless sensor network (WSN) applications. In this paper, a redundancy branch convergence-based preserved source location privacy scheme (RBCPSLP) is proposed for energy harvesting sensor networks, with the following advantages: numerous routing branches are created in non-hotspot areas with abundant energy, and those routing branches can merge into a few routing paths before they reach the hotspot areas. The generation time, the duration of routing, and the number of routing branches are then decided independently based on the amount of energy obtained, so as to maximize network energy utilization, greatly enhance privacy protection, and provide long network lifetimes. Theoretical analysis and experimental results show that the RBCPSLP scheme allows a several-fold improvement of the network energy utilization as well as the source location privacy preservation, while maximizing network lifetimes. PMID:28358341

  11. Translational Science for Energy and Beyond.

    PubMed

    McKone, James R; Crans, Debbie C; Martin, Cheryl; Turner, John; Duggal, Anil R; Gray, Harry B

    2016-09-19

    A clear challenge for the coming decades is decreasing the carbon intensity of the global energy supply while simultaneously accommodating a rapid worldwide increase in power demand. Meeting this challenge of providing abundant, clean energy undoubtedly requires synergistic efforts between basic and applied researchers in the chemical sciences to develop and deploy new technologies. Among the available options, solar energy is one of the promising targets because of the high abundance of solar photons over much of the globe. Similarly, decarbonization of the global energy supply will require clean sources of hydrogen to use as reducing equivalents for fuel and chemical feedstocks. In this report, we discuss the importance of translational research-defined as work that explicitly targets basic discovery as well as technology development-in the context of photovoltaics and solar fuels. We focus on three representative research programs encompassing translational research in government, industry, and academia. We then discuss more broadly the benefits and challenges of translational research models and offer recommendations for research programs that address societal challenges in the energy sector and beyond.

  12. Interstellar molecules and dense clouds.

    NASA Technical Reports Server (NTRS)

    Rank, D. M.; Townes, C. H.; Welch, W. J.

    1971-01-01

    Current knowledge of the interstellar medium is discussed on the basis of recent published studies. The subjects considered include optical identification of interstellar molecules, radio molecular lines, interstellar clouds, isotopic abundances, formation and disappearance of interstellar molecules, and interstellar probing techniques. Diagrams are plotted for the distribution of galactic sources exhibiting molecular lines, for hydrogen molecule, hydrogen atom and electron abundances due to ionization, for the densities, velocities and temperature of NH3 in the direction of Sagitarius B2, for the lower rotational energy levels of H2CO, and for temporal spectral variations in masing H2O clouds of the radio source W49. Future applications of the maser and of molecular microscopy in this field are visualized.

  13. Energy for biologic sulfate reduction in a hydrothermally formed ocean on Europa

    NASA Astrophysics Data System (ADS)

    Zolotov, Mikhail Y.; Shock, Everett L.

    2003-04-01

    Formation of a sulfate-bearing ocean on Jupiter's satellite Europa by quenched hydrothermal fluids provides a source of metabolic energy for low-temperature sulfate-reducing organisms that use dissolved H2 as an electron donor. Inhibition of thermodynamically favorable sulfate reduction in cooled hydrothermal fluids creates the potential for biologic reduction. Both high temperature and reduced conditions of ocean-forming hydrothermal solutions favor sulfate reduction in quenched fluids. The maximum amount of energy available to support autotrophic sulfate reduction is on the order of a few kilojoules per kilogram of water and is limited by the low abundances of either H2 or sulfate in ocean-forming fluids. Although this irreplaceable energy source might have supported early life on Europa, maintenance of biologic sulfate reduction throughout the ocean's history would require a supply of organic compounds from endogenic sources or from the satellite's surface.

  14. New Constraints on the Geometry and Kinematics of Matter Surrounding the Accretion Flow in X-Ray Binaries from Chandra High-energy Transmission Grating X-Ray Spectroscopy

    NASA Astrophysics Data System (ADS)

    Tzanavaris, P.; Yaqoob, T.

    2018-03-01

    The narrow, neutral Fe Kα fluorescence emission line in X-ray binaries (XRBs) is a powerful probe of the geometry, kinematics, and Fe abundance of matter around the accretion flow. In a recent study it has been claimed, using Chandra High-Energy Transmission Grating (HETG) spectra for a sample of XRBs, that the circumnuclear material is consistent with a solar-abundance, uniform, spherical distribution. It was also claimed that the Fe Kα line was unresolved in all cases by the HETG. However, these conclusions were based on ad hoc models that did not attempt to relate the global column density to the Fe Kα line emission. We revisit the sample and test a self-consistent model of a uniform, spherical X-ray reprocessor against HETG spectra from 56 observations of 14 Galactic XRBs. We find that the model is ruled out in 13/14 sources because a variable Fe abundance is required. In two sources a spherical distribution is viable, but with nonsolar Fe abundance. We also applied a solar-abundance Compton-thick reflection model, which can account for the spectra that are inconsistent with a spherical model, but spectra with a broader bandpass are required to better constrain model parameters. We also robustly measured the velocity width of the Fe Kα line and found FWHM values of up to ∼5000 km s‑1. Only in some spectra was the Fe Kα line unresolved by the HETG.

  15. Influence of variable rainbow smelt and gizzard shad abundance on walleye diets and growth

    USGS Publications Warehouse

    Fincel, Mark J.; Dembkowski, Daniel J.; Chipps, Steven R.

    2014-01-01

    Prey availability influences growth and condition of walleye (Sander vitreus) in large systems. In Lake Oahe, South Dakota, rainbow smelt (Osmerus mordax) and gizzard shad (Dorosoma cepedianum) are primary prey of walleye, but their abundance varies substantially year to year. To evaluate the influence of gizzard shad and rainbow smelt on walleye diets and growth in Lake Oahe, we compared recent estimates of walleye diets and growth in 2008 through 2010 with those from the late 1990s and early 2000s. Walleye diets differed seasonally with increased piscivory in July and October. In 2008, gizzard shad were the dominant prey item of walleye, representing about 60% of the diets by weight; however, by 2009, gizzard shad declined appreciably in the diet (22%) and were completely absent from walleye diets by 2010. Conversely, rainbow smelt abundance represented 12%, 27%, and 90% of walleye diets by weight in 2008, 2009 and 2010, respectively. Changes in growth corresponded to changes in diets, with the slowest growth occurring when gizzard shad were dominant in the diets and increasing growth every year thereafter. Because gizzard shad are only available during short periods (<3 months) in late summer, walleye can only achieve about 50% of their annual maintenance energy requirements from this prey source. Conversely, rainbow smelt, which are available and consumed year round, provide a continuous energy source that contributes to high growth rates. Nonetheless, when abundant, gizzard shad may provide an important subsidy to Lake Oahe walleye during periods of low rainbow smelt abundance.

  16. Outlook for ultraviolet astronomy

    NASA Technical Reports Server (NTRS)

    Boehm-Vitense, E.

    1981-01-01

    A brief overview of galactic and extragalactic research is given with emphasis on the problems of temperature determination, chemical abundance determination, and the question about the energy sources for the high temperature regions. Stellar astronomy, stellar winds, and the interstellar medium are among the topics covered.

  17. Tolerant yeast in situ detoxifies major class of toxic chemicals while producing ethanol

    USDA-ARS?s Scientific Manuscript database

    Renewable lignocellulosic materials contain abundant sugar source and biofuels conversion including cellulosic ethanol production from lignocellulosic biomass provides a sustainable alternative energy resource for a cleaner environment. In order to release the biomass sugars from the complex cellulo...

  18. Measurement of the fluxes of galactic cosmic ray H-2 and He-3 in 1972 - 1973

    NASA Technical Reports Server (NTRS)

    Teegarden, B. J.; Vonrosenvinge, T. T.; Mcdonald, F. B.; Trainor, J. H.; Webber, W. R.

    1975-01-01

    If a nearby source of low-energy helium is present, which has traversed a relatively small amount of matter and thus has not caused the production of a significant amount of H-2 or He-3, then these abundance ratios will be suppressed, particularly at low energies. This seems to be the most likely explanation for low ratios.

  19. Feasibility study of solar energy in residential electricity generation

    NASA Astrophysics Data System (ADS)

    Solanki, Divyangsinh G.

    With the increasing demand for energy and the concerns about the global environment, along with the steady progress in the field of renewable energy technologies, new opportunities and possibilities are opening up for an efficient utilization of renewable energy sources. Solar energy is undoubtedly the most clean, inexhaustible and abundant source of renewable energy. Photovoltaic (PV) technology is one of the most efficient mean to utilize solar power. The focus of this study was to establish economics of a residential photovoltaic system for a typical home in south Texas. The PV system serves the needs of a typical mid-size home inhibited by a typical family. Assumptions are made for the typical daily energy consumption, and the necessary equipments like solar arrays, batteries, inverter, etc. are sized and evaluated optimally so as to reduce the life cycle cost (LCC) of the system. Calculations are done taking into consideration the economic parameters concerned with the system.

  20. The use of mud as an alternative source for bioelectricity using microbial fuel cells

    NASA Astrophysics Data System (ADS)

    Darmawan, Raden; Widjaja, Arief; Juliastuti, Sri Rachmania; Hendrianie, Nuniek; Hidaya, Chanifah; Sari, Dessy Rosita; Suwito, Morimura, Shigeru; Tominaga, Masato

    2017-05-01

    Alternative energy sources to substitute fossil-based energy is expected, as the fossil energy reserves decreasing every day. Mud is considered to be economical as the material sources for generating the electricity where it could be found easily and abundantly in Indonesia. The existence of a lot of mud that contains organic material has great potential as a source of electrical energy using microbial fuel cells (MFCs). It provides a promising technology by degrading organic compounds to yield the sustainable energy. The different sampling sites were determined to find out the electricity production, i.e. mud from soil water, brackish water and sea water using an anode immersed of 10 cm2. The results suggest that the electricity generation of the three areas are 0.331, 0.327 and 0.398 V (in terms of voltage); 0.221, 0.050 and 0.325 mA (in terms of electric current), respectively. It is investigated that the mud obtained the sea water exhibits the highest power potential compared to that obtained from the brackish and soil water.

  1. Breaking the Biological Barriers to Cellulosic Ethanol: A Joint Research Agenda. A Research Roadmap Resulting from the Biomass to Biofuels Workshop

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    2006-06-30

    A robust fusion of the agricultural, industrial biotechnology, and energy industries can create a new strategic national capability for energy independence and climate protection. In his State of the Union Address (*Bush 2006), President George W. Bush outlined the Advanced Energy Initiative, which seeks to reduce our national dependence on imported oil by accelerating the development of domestic,renewable alternatives to gasoline and diesel fuels. The president has set a national goal of developing cleaner, cheaper, and more reliable alternative energy sources to substantially replace oil imports in the coming years.Fuels derived from cellulosic biomass—the fibrous, woody, and generally inedible portionsmore » of plant matter—offer one such alternative to conventional energy sources that can dramatically impact national economic growth, national energy security, and environmental goals. Cellulosic biomass is an attractive energy feedstock because it is an abundant, domestic, renewable source that can be converted to liquid transportation fuels.These fuels can be used readily by current-generation vehicles and distributed through the existing transportation-fuel infrastructure.« less

  2. Invasive Mussels Alter the Littoral Food Web of a Large Lake: Stable Isotopes Reveal Drastic Shifts in Sources and Flow of Energy

    PubMed Central

    Ozersky, Ted; Evans, David O.; Barton, David R.

    2012-01-01

    We investigated how establishment of invasive dreissenid mussels impacted the structure and energy sources of the littoral benthic food web of a large temperate lake. We combined information about pre- and postdreissenid abundance, biomass, and secondary production of the littoral benthos with results of carbon and nitrogen stable isotope analysis of archival (predreissenid) and recent (postdreissenid) samples of all common benthic taxa. This approach enabled us to determine the importance of benthic and sestonic carbon to the littoral food web before, and more than a decade after dreissenid establishment. Long term dreissenid presence was associated with a 32-fold increase in abundance, 6-fold increase in biomass, and 14-fold increase in secondary production of the littoral benthos. Dreissenids comprised a large portion of the post-invasion benthos, making up 13, 38, and 56% of total abundance, biomass, and secondary production, respectively. The predreissenid food web was supported primarily by benthic primary production, while sestonic material was relatively more important to the postdreissenid food web. The absolute importance of both sestonic material and benthic primary production to the littoral benthos increased considerably following dreissenid establishment. Our results show drastic alterations to food web structure and suggest that dreissenid mussels redirect energy and material from the water column to the littoral benthos both through biodeposition of sestonic material as well as stimulation of benthic primary production. PMID:23284673

  3. Source Book on Plutonium and Its Decontamination

    DTIC Science & Technology

    1973-09-24

    Energy Commisjsion Policy The AEC is the foremoacst regulator of the use of radioactive materials in this country. It derives this power from the...Congress and furthers Its responsibilities in two ways; first, through its licensin~g power and second, by regulation of the activities of its contractors...biological hazard. Plutonium- 239 is of interest because of its abundance in weapons and Pu-238 because of its use in power sources. Half lives for the two

  4. Microbial fuel cells: Running on gas

    NASA Astrophysics Data System (ADS)

    Ren, Zhiyong Jason

    2017-06-01

    Methane is an abundant energy source that is used for power generation in thermal power plants via combustion, but direct conversion to electricity in fuel cells remains challenging. Now, a microbial fuel cell is demonstrated to efficiently convert methane directly to current by careful selection of a consortium of microorganisms.

  5. 77 FR 29167 - Effluent Limitations Guidelines and New Source Performance Standards for the Airport Deicing...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-05-16

    ... reductions in dissolved oxygen, fish kills, reduced organism abundance and species diversity, contamination... 13045: Protection of Children From Environmental Health and Safety Risks H. EO 13211: Energy Effects I... water in residential areas and parkland, and other effects. Today, EPA is promulgating effluent...

  6. Translational Science for Energy and Beyond

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McKone, James R.; Crans, Debbie C.; Martin, Cheryl

    A clear challenge for the coming decades is decreasing the carbon intensity of the global energy supply while simultaneously accommodating a rapid worldwide increase in power demand. Meeting this challenge of providing abundant, clean energy undoubtedly requires synergistic efforts between basic and applied researchers in the chemical sciences to develop and deploy new technologies. Among the available options, solar energy is one of the promising targets because of the high abundance of solar photons over much of the globe. Similarly, decarbonization of the global energy supply will require clean sources of hydrogen to use as reducing equivalents for fuel andmore » chemical feedstocks. In this report, we discuss the importance of translational research -- defined as work that explicitly targets basic discovery as well as technology development -- in the context of photovoltaics and solar fuels. We focus on three representative research programs encompassing translational research in government, industry, and academia. We then discuss more broadly the benefits and challenges of translational research models and offer recommendations for research programs that address societal challenges in the energy sector and beyond.« less

  7. Current development of biorefinery in China.

    PubMed

    Tan, Tianwei; Shang, Fei; Zhang, Xu

    2010-01-01

    To meet the demand of its fast growing economy, China has become already the second largest buyer of crude oil. China is facing critical problems of energy shortage and environment deterioration. Rational and efficient energy use and environment protection are both getting more attention in China. Biomass energy is renewable energy made from biological sources. China's biomass resources are abundant, which could provide energy for future social and economic development. However technologies for biomass resource conversion in China are still just beginning. In this paper, current biomass resource distribution and technologies of biomass energy, including power generation, biofuel production and biomass-based chemical production are reviewed. Copyright 2010 Elsevier Inc. All rights reserved.

  8. Energy for agriculture. A computerized information retrieval system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Stout, B.A.; Myers, C.A.

    Energy may come from the sun or the earth or be the product of plant materials or agricultural wastes. Whatever its source, energy is indispensable to our way of life, beginning with the production, processing, and distribution of abundant, high quality food and fiber supplies. This specialized bibliography on the subject of energy for agriculture contains 2613 citations to the literature for 1973 through May 1979. Originally issued by Michigan State University (MSU), it is being reprinted and distributed by the U.S. Department of Agriculture. The literature citations will be incorporated into AGRICOLA (Agricultural On-Line Access), the comprehensive bibliographic datamore » base maintained by Technical Information Systems (TIS), a component of USDA's Science and Education Administration (SEA). The citations and the listing of research projects will be combined with other relevant references to provide a continuously updated source of information on energy programs in the agricultural field. No abstracts are included.« less

  9. Cosmic-ray energy spectra between 10 and several hundred GeV per atomic mass unit for elements from Ar-18 to Ni-28 - Results from HEAO 3

    NASA Technical Reports Server (NTRS)

    Binns, W. R.; Israel, M. H.; Jones, Michael D.; Kamionkowski, M. P.; Garrard, T. L.

    1988-01-01

    Results from the Heavy Nuclei experiment on HEAO 3 are used to determine the primary abundances of Ni and Fe. Ni and Fe are found to have nearly constant relative abundances over the interval of 10 to about 500 GeV per amu. Individual secondary elements derived principally from interactions of primary Fe nuclei are shown to display a power-law decrease in relative abundance up to about 150 GeV per amu. Ar/Fe and Ca/Fe ratios of 2.6 + or - 0.7 percent and 8.8 + or - 0.7 percent, respectively, are found, confirming a fractionation of source abundances in which elements with high values of the first ionization potential are depleted relative to those with low first ionization potential.

  10. Assessment of Renewable Energy Sources & Municipal Solid Waste for Sustainable Power Generation in Nigeria

    NASA Astrophysics Data System (ADS)

    Aderoju, Olaide M.; Dias, Guerner A.; Echakraoui, Zhour

    2017-12-01

    The demand for Energy in most Sub-Saharan African countries has become unimaginable despite its high potential of natural and renewable resources. The deficit has impeded the regions’ economic growth and sustainability. Nigeria as a nation is blessed with fossil fuels, abundant sunlight, hydro, wind and many among others, but the energy output to its population (185 million) still remains less than 4000MW. Currently, the clamour for an alternative but renewable energy source is the demand of the globe but it is quite expensive to achieve the yield that meets the Nigeria demand. Hence, this study aims at identifying and mapping out various regions with renewable energy potentials. The study also considers municipal solid waste as a consistent and available resource for power generation. Furthermore, this study examines the drawbacks inhibiting the inability to harness these renewable, energy generating potentials in full capacity. The study will enable the authorities and other stakeholders to invest and plan on providing a sustainable energy for the people.

  11. Characterizing isotopic variability of primary production and consumers in Great Plains ecosystems during protracted regional drought

    NASA Astrophysics Data System (ADS)

    Haveles, A. W.; Fox-Dobbs, K.; Talmadge, K. A.; Fetrow, A.; Fox, D. L.

    2012-12-01

    Over the last few years (2010-2012), the Great Plains of the central USA experienced protracted drought conditions, including historically severe drought during Summer, 2011. Drought severity in the region generally decreases with increasing latitude, but episodic drought is a fundamental trait of grassland ecosystems. Documenting above ground energy and nutrient flow with current drought is critical to understanding responses of grassland ecosystems in the region to predicted increased episodicity of rainfall and recurrence of drought due to anthropogenic climate change. Characterization of biogeochemical variability of modern ecosystems at the microhabitat, local landscape, and regional scales is also necessary to interpret biogeochemical records of ancient grasslands based on paleosols and fossil mammals. Here, we characterize three grassland ecosystems that span the drought gradient in the Great Plains (sites in the Texas panhandle, southwest Kansas, and northwest Nebraska). We measured δ13C and δ15N values of plants and consumers to characterize the biogeochemical variability within each ecosystem. Vegetation at each site is a mix of trees, shrubs, herbs, and cool- and warm-growing season grasses (C3 and C4, respectively). Thus, consumers have access to isotopically distinct sources of forage that vary in abundance with microhabitat (e.g., open grassland, shrub thicket, riparian woodland). Observations indicate herbivorous arthropod (grasshoppers and crickets) abundance follows drought severity, with high abundance of many species in Texas, and low abundance of few species in Nebraska. Small mammal (rodents) abundance follows the inverse pattern with 0.8%, 3.2% and 17.2% capture success in Texas, Kansas and Nebraska, respectively. The inverse abundance patterns of consumer groups may result from greater sensitivity of small mammal consumers with high metabolic needs to lower local net primary productivity and forage quality under drought conditions. As a result, ecological interactions among consumer groups likely change as available energy sources decrease. In Kansas, neither C3 nor C4 plants have δ13C values that vary in relation to microhabitat. Most abundant arthropod taxa mainly utilize C3 plant resources. Small mammals have mixed diets derived from both C3 and C4 plant resources. Diets include general herbivory, or consumption of both plants and arthropods. Although C4 resources are available in all study areas, C3 resources are the dominant energy source for all consumers in Kansas, and rodents in Nebraska. Plant δ15N values for C3 and C4 plants, and all consumer species in Kansas were variable. High variability in plant δ15N values (hence consumers) complicates our ability to estimate trophic levels of consumers using δ15N values. Differences in δ15N values of consumers among microhabitats are evident in Kansas and Nebraska, which may result from differences in plant communities or foraging habits. Large isotopic variations within plants, arthropods, and mammals illustrate the need to monitor grassland ecosystems seasonally, and at varying spatial scales to characterize patterns of energy flow and trophic dynamics. Identifying how grassland consumers record local and regional environmental variance will help predict future responses of Great Plains ecosystems to anthropogenic climate change.

  12. Alpha-capture reaction rates for 22 Ne (α , n) via sub-Coulomb alpha-transfer and its effect on final abundances of s-process isotopes

    NASA Astrophysics Data System (ADS)

    Jayatissa, Heshani; Rogachev, Grigory; Koshchiy, Yevgeny; Goldberg, Vladilen; Hooker, Joshua; Hunt, Curtis; Magana, Cordero; Roeder, Brian; Saastamoinen, Antti; Spiridon, Alexandria; Upadhyayula, Sriteja; Trippella, Oscar

    2017-09-01

    The 22 Ne (α , n) reaction is a very important neutron source reaction for the slow neutron capture process (s-process) in asymptotic giant branch stars. These direct measurements are very difficult to carry out at the energy regimes of interest for astrophysics (Gamow energies) due to the extremely small reaction cross section. The large uncertainties introduced when extrapolating direct measurements at high energies down to the Gamow energies can be overcome by measuring the Asymptotic Normalization Coefficients (ANC) of the relevant states using α-transfer reactions at sub-Coulomb energies to reduce the optical model dependence. The study of the 22Ne(6Li,d) and 22Ne(7Li,t) reaction was carried out at the Cyclotron Institute at Texas A&M University. The α-ANC measurements for the near α-threshold resonances of 26Mg provide constraints for the 22Ne(α,n) reaction rate. The effect of this reaction rate on the final abundances of the s-process isotopes will be discussed.

  13. Natural Gas Storage Research at Savannah River National Laboratory

    ScienceCinema

    Anton, Don; Sulic, Martin; Tamburello, David A.

    2018-01-16

    As an alternative to imported oil, scientists at the Department of Energy’s Savannah River National Laboratory are looking at abundant, domestically sourced natural gas, as an alternative transportation fuel. SRNL is investigating light, inexpensive, adsorbed natural gas storage systems that may fuel the next generation of automobiles.

  14. Electrochemical Hydrogen Evolution: Sabatier's Principle and the Volcano Plot

    ERIC Educational Resources Information Center

    Laursen, Anders B.; Varela, Ana Sofia; Dionigi, Fabio; Fanchiu, Hank; Miller, Chandler; Trinhammer, Ole L.; Rossmeisl, Jan; Dahl, Soren

    2012-01-01

    The electrochemical hydrogen evolution reaction (HER) is growing in significance as society begins to rely more on renewable energy sources such as wind and solar power. Thus, research on designing new, inexpensive, and abundant HER catalysts is important. Here, we describe how a simple experiment combined with results from density functional…

  15. Building a Business Case for Compressed Natural Gas in Fleet Applications

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mitchell, G.

    2015-03-19

    Natural gas is a clean-burning, abundant, and domestically produced source of energy. Compressed natural gas (CNG) has recently garnered interest as a transportation fuel because of these attributes and because of its cost savings and price stability compared to conventional petroleum fuels. The National Renewable Energy Laboratory (NREL) developed the Vehicle Infrastructure and Cash-Flow Evaluation (VICE) model to help businesses and fleets evaluate the financial soundness of CNG vehicle and CNG fueling infrastructure projects.

  16. Growing America's Energy Future

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    The emerging U.S. bioenergy industry provides a secure and growing supply of transportation fuels, biopower, and bioproducts produced from a range of abundant, renewable biomass resources. Bioenergy can help ensure a secure, sustainable, and economically sound future by reducing U.S. dependence on foreign oil, developing domestic clean energy sources, and generating domestic green jobs. Bioenergy can also help address growing concerns about climate change by reducing greenhouse gas emissions to create a healthier environment for current and future generations.

  17. The gut microbiota appears to compensate for seasonal diet variation in the wild black howler monkey (Alouatta pigra).

    PubMed

    Amato, Katherine R; Leigh, Steven R; Kent, Angela; Mackie, Roderick I; Yeoman, Carl J; Stumpf, Rebecca M; Wilson, Brenda A; Nelson, Karen E; White, Bryan A; Garber, Paul A

    2015-02-01

    For most mammals, including nonhuman primates, diet composition varies temporally in response to differences in food availability. Because diet influences gut microbiota composition, it is likely that the gut microbiota of wild mammals varies in response to seasonal changes in feeding patterns. Such variation may affect host digestive efficiency and, ultimately, host nutrition. In this study, we investigate the temporal variation in diet and gut microbiota composition and function in two groups (N = 13 individuals) of wild Mexican black howler monkeys (Alouatta pigra) over a 10-month period in Palenque National Park, Mexico. Temporal changes in the relative abundances of individual bacterial taxa were strongly correlated with changes in host diet. For example, the relative abundance of Ruminococcaceae was highest during periods when energy intake was lowest, and the relative abundance of Butyricicoccus was highest when young leaves and unripe fruit accounted for 68 % of the diet. Additionally, the howlers exhibited increased microbial production of energy during periods of reduced energy intake from food sources. Because we observed few changes in howler activity and ranging patterns during the course of our study, we propose that shifts in the composition and activity of the gut microbiota provided additional energy and nutrients to compensate for changes in diet. Energy and nutrient production by the gut microbiota appears to provide an effective buffer against seasonal fluctuations in energy and nutrient intake for these primates and is likely to have a similar function in other mammal species.

  18. Consistency of cosmic-ray source abudances with explosive nucleosynthesis

    NASA Technical Reports Server (NTRS)

    Kozlovsky, B.; Ramaty, R.

    1973-01-01

    A model was examined in which the cosmic ray abundances of elements from C to Fe are consistent with explosive nucleosynthesis. The observed abundance of cosmic rays near the earth, cosmic ray source abundance, and solar system abundance are discussed along with the ratios of cosmic ray sources to the solar system abundances.

  19. A single low-energy, iron-poor supernova as the source of metals in the star SMSS J031300.36-670839.3.

    PubMed

    Keller, S C; Bessell, M S; Frebel, A; Casey, A R; Asplund, M; Jacobson, H R; Lind, K; Norris, J E; Yong, D; Heger, A; Magic, Z; Da Costa, G S; Schmidt, B P; Tisserand, P

    2014-02-27

    The element abundance ratios of four low-mass stars with extremely low metallicities (abundances of elements heavier than helium) indicate that the gas out of which the stars formed was enriched in each case by at most a few--and potentially only one--low-energy supernova. Such supernovae yield large quantities of light elements such as carbon but very little iron. The dominance of low-energy supernovae seems surprising, because it had been expected that the first stars were extremely massive, and that they disintegrated in pair-instability explosions that would rapidly enrich galaxies in iron. What has remained unclear is the yield of iron from the first supernovae, because hitherto no star has been unambiguously interpreted as encapsulating the yield of a single supernova. Here we report the optical spectrum of SMSS J031300.36-670839.3, which shows no evidence of iron (with an upper limit of 10(-7.1) times solar abundance). Based on a comparison of its abundance pattern with those of models, we conclude that the star was seeded with material from a single supernova with an original mass about 60 times that of the Sun (and that the supernova left behind a black hole). Taken together with the four previously mentioned low-metallicity stars, we conclude that low-energy supernovae were common in the early Universe, and that such supernovae yielded light-element enrichment with insignificant iron. Reduced stellar feedback both chemically and mechanically from low-energy supernovae would have enabled first-generation stars to form over an extended period. We speculate that such stars may perhaps have had an important role in the epoch of cosmic reionization and the chemical evolution of early galaxies.

  20. Baseline study of methane emission from anaerobic ponds of palm oil mill effluent treatment.

    PubMed

    Yacob, Shahrakbah; Ali Hassan, Mohd; Shirai, Yoshihito; Wakisaka, Minato; Subash, Sunderaj

    2006-07-31

    The world currently obtains its energy from the fossil fuels such as oil, natural gas and coal. However, the international crisis in the Middle East, rapid depletion of fossil fuel reserves as well as climate change have driven the world towards renewable energy sources which are abundant, untapped and environmentally friendly. Malaysia has abundant biomass resources generated from the agricultural industry particularly the large commodity, palm oil. This paper will focus on palm oil mill effluent (POME) as the source of renewable energy from the generation of methane and establish the current methane emission from the anaerobic treatment facility. The emission was measured from two anaerobic ponds in Felda Serting Palm Oil Mill for 52 weeks. The results showed that the methane content was between 35.0% and 70.0% and biogas flow rate ranged between 0.5 and 2.4 L/min/m(2). Total methane emission per anaerobic pond was 1043.1 kg/day. The total methane emission calculated from the two equations derived from relationships between methane emission and total carbon removal and POME discharged were comparable with field measurement. This study also revealed that anaerobic pond system is more efficient than open digesting tank system for POME treatment. Two main factors affecting the methane emission were mill activities and oil palm seasonal cropping.

  1. Complex metal borohydrides: multifunctional materials for energy storage and conversion

    NASA Astrophysics Data System (ADS)

    Mohtadi, Rana; Remhof, Arndt; Jena, Puru

    2016-09-01

    With the limited supply of fossil fuels and their adverse effect on the climate and the environment, it has become a global priority to seek alternate sources of energy that are clean, abundant, and sustainable. While sources such as solar, wind, and hydrogen can meet the world’s energy demand, considerable challenges remain to find materials that can store and/or convert energy efficiently. This topical review focuses on one such class of materials, namely, multi-functional complex metal borohydrides that not only have the ability to store sufficient amount of hydrogen to meet the needs of the transportation industry, but also can be used for a new generation of metal ion batteries and solar cells. We discuss the material challenges in all these areas and review the progress that has been made to address them, the issues that still need to be resolved and the outlook for the future.

  2. Complex metal borohydrides: multifunctional materials for energy storage and conversion.

    PubMed

    Mohtadi, Rana; Remhof, Arndt; Jena, Puru

    2016-09-07

    With the limited supply of fossil fuels and their adverse effect on the climate and the environment, it has become a global priority to seek alternate sources of energy that are clean, abundant, and sustainable. While sources such as solar, wind, and hydrogen can meet the world's energy demand, considerable challenges remain to find materials that can store and/or convert energy efficiently. This topical review focuses on one such class of materials, namely, multi-functional complex metal borohydrides that not only have the ability to store sufficient amount of hydrogen to meet the needs of the transportation industry, but also can be used for a new generation of metal ion batteries and solar cells. We discuss the material challenges in all these areas and review the progress that has been made to address them, the issues that still need to be resolved and the outlook for the future.

  3. Trace element abundance determinations by Synchrotron X Ray Fluorescence (SXRF) on returned comet nucleus mineral grains

    NASA Technical Reports Server (NTRS)

    Flynn, G. J.; Sutton, S. R.

    1989-01-01

    Trace element analyses were performed on bulk cosmic dust particles by Proton Induced X Ray Emission (PIXE) and Synchrotron X Ray Fluorescence (SXRF). When present at or near chondritic abundances the trace elements K, Ti, Cr, Mn, Cu, Zn, Ga, Ge, Se, and Br are presently detectable by SXRF in particles of 20 micron diameter. Improvements to the SXRF analysis facility at the National Synchrotron Light Source presently underway should increase the range of detectable elements and permit the analysis of smaller samples. In addition the Advanced Photon Source will be commissioned at Argonne National Laboratory in 1995. This 7 to 8 GeV positron storage ring, specifically designed for high-energy undulator and wiggler insertion devices, will be an ideal source for an x ray microprobe with one micron spatial resolution and better than 100 ppb elemental sensitivity for most elements. Thus trace element analysis of individual micron-sized grains should be possible by the time of the comet nucleus sample return mission.

  4. Modeling collision energy transfer in APCI/CID mass spectra of PAHs using thermal-like post-collision internal energy distributions

    NASA Astrophysics Data System (ADS)

    Solano, Eduardo A.; Mohamed, Sabria; Mayer, Paul M.

    2016-10-01

    The internal energy transferred when projectile molecular ions of naphthalene collide with argon gas atoms was extracted from the APCI-CID (atmospheric-pressure chemical ionization collision-induced dissociation) mass spectra acquired as a function of collision energy. Ion abundances were calculated by microcanonical integration of the differential rate equations using the Rice-Ramsperger-Kassel-Marcus rate constants derived from a UB3LYP/6-311G+(3df,2p)//UB3LYP/6-31G(d) fragmentation mechanism and thermal-like vibrational energy distributions p M (" separators=" E , T char ) . The mean vibrational energy excess of the ions was characterized by the parameter Tchar ("characteristic temperature"), determined by fitting the theoretical ion abundances to the experimental breakdown graph (a plot of relative abundances of the ions as a function of kinetic energy) of activated naphthalene ions. According to these results, the APCI ion source produces species below Tchar = 1457 K, corresponding to 3.26 eV above the vibrational ground state. Subsequent collisions heat the ions up further, giving rise to a sigmoid curve of Tchar as a function of Ecom (center-of-mass-frame kinetic energy). The differential internal energy absorption per kinetic energy unit (dEvib/dEcom) changes with Ecom according to a symmetric bell-shaped function with a maximum at 6.38 ± 0.32 eV (corresponding to 6.51 ± 0.27 eV of vibrational energy excess), and a half-height full width of 6.30 ± 1.15 eV. This function imposes restrictions on the amount of energy that can be transferred by collisions, such that a maximum is reached as kinetic energy is increased. This behavior suggests that the collisional energy transfer exhibits a pronounced increase around some specific value of energy. Finally, the model is tested against the CID mass spectra of anthracene and pyrene ions and the corresponding results are discussed.

  5. Modeling collision energy transfer in APCI/CID mass spectra of PAHs using thermal-like post-collision internal energy distributions.

    PubMed

    Solano, Eduardo A; Mohamed, Sabria; Mayer, Paul M

    2016-10-28

    The internal energy transferred when projectile molecular ions of naphthalene collide with argon gas atoms was extracted from the APCI-CID (atmospheric-pressure chemical ionization collision-induced dissociation) mass spectra acquired as a function of collision energy. Ion abundances were calculated by microcanonical integration of the differential rate equations using the Rice-Ramsperger-Kassel-Marcus rate constants derived from a UB3LYP/6-311G+(3df,2p)//UB3LYP/6-31G(d) fragmentation mechanism and thermal-like vibrational energy distributions p M E,T char . The mean vibrational energy excess of the ions was characterized by the parameter T char ("characteristic temperature"), determined by fitting the theoretical ion abundances to the experimental breakdown graph (a plot of relative abundances of the ions as a function of kinetic energy) of activated naphthalene ions. According to these results, the APCI ion source produces species below T char = 1457 K, corresponding to 3.26 eV above the vibrational ground state. Subsequent collisions heat the ions up further, giving rise to a sigmoid curve of T char as a function of E com (center-of-mass-frame kinetic energy). The differential internal energy absorption per kinetic energy unit (dE vib /dE com ) changes with E com according to a symmetric bell-shaped function with a maximum at 6.38 ± 0.32 eV (corresponding to 6.51 ± 0.27 eV of vibrational energy excess), and a half-height full width of 6.30 ± 1.15 eV. This function imposes restrictions on the amount of energy that can be transferred by collisions, such that a maximum is reached as kinetic energy is increased. This behavior suggests that the collisional energy transfer exhibits a pronounced increase around some specific value of energy. Finally, the model is tested against the CID mass spectra of anthracene and pyrene ions and the corresponding results are discussed.

  6. What can nuclear energy do for society.

    NASA Technical Reports Server (NTRS)

    Rom, F. E.

    1971-01-01

    Nuclear fuel is a compact and abundant source of energy. Its cost per unit of energy is less than that of fossil fuel. Disadvantages of nuclear fuel are connected with the high cost of capital equipment required for releasing nuclear energy and the heavy weight of the necessary shielding. In the case of commercial electric power production and marine propulsion the advantages have outweighed the disadvantages. It is pointed out that nuclear commercial submarines have certain advantages compared to surface ships. Nuclear powerplants might make air-cushion vehicles for transoceanic ranges feasible. The problems and advantages of a nuclear aircraft are discussed together with nuclear propulsion for interplanetary space voyages.

  7. Coal Utilization in Schools: Issues and Answers.

    ERIC Educational Resources Information Center

    Pusey, Robert H.

    Coal, at one-third the cost of natural gas and one-fifth the cost of oil, is our cheapest source of energy and is also in abundant supply. Because of significant technological advances, coal-fired equipment now approaches the clean and automatic operational characteristics of gas- and oil-fired boilers. For these reasons, and because schools are…

  8. Recovery of forest residues in the Southern United States

    Treesearch

    Bryce J. Stokes; Donald L. Sirois

    1989-01-01

    In the mid 1970's, the accelerated price increases for petroleum products forced rapid exploration into and adoption of alternative energy sources. A viable option for the forest industry was the recovery of woody biomass from unmerchantable trees and logging residues. Several studies estimated that an abundance of such forest materials existed in the southeastern...

  9. Hydrogen as an energy medium

    NASA Technical Reports Server (NTRS)

    Cox, K. E.

    1976-01-01

    Coal, though abundant in certain geographical locations of the USA poses environmental problems associated with its mining and combustion. Also, nuclear fission energy appears to have problems regarding safety and radioactive waste disposal that are as yet unresolved. The paper discusses hydrogen use and market projection along with energy sources for hydrogen production. Particular attention is given to hydrogen production technology as related to electrolysis and thermochemical water decomposition. Economics of hydrogen will ultimately be determined by the price and availability of future energy carriers such as electricity and synthetic natural gas. Thermochemical methods of hydrogen production appear to offer promise largely in the efficiency of energy conversion and in capital costs over electrolytic methods.

  10. High energy particles and quanta in astrophysics

    NASA Technical Reports Server (NTRS)

    Mcdonald, F. B. (Editor); Fichtel, C. E.

    1974-01-01

    The various subdisciplines of high-energy astrophysics are surveyed in a series of articles which attempt to give an overall view of the subject as a whole by emphasizing the basic physics common to all fields in which high-energy particles and quanta play a role. Successive chapters cover cosmic ray experimental observations, the abundances of nuclei in the cosmic radiation, cosmic electrons, solar modulation, solar particles (observation, relationship to the sun acceleration, interplanetary medium), radio astronomy, galactic X-ray sources, the cosmic X-ray background, and gamma ray astronomy. Individual items are announced in this issue.

  11. All-Fullerene-Based Cells for Nonaqueous Redox Flow Batteries.

    PubMed

    Friedl, Jochen; Lebedeva, Maria A; Porfyrakis, Kyriakos; Stimming, Ulrich; Chamberlain, Thomas W

    2018-01-10

    Redox flow batteries have the potential to revolutionize our use of intermittent sustainable energy sources such as solar and wind power by storing the energy in liquid electrolytes. Our concept study utilizes a novel electrolyte system, exploiting derivatized fullerenes as both anolyte and catholyte species in a series of battery cells, including a symmetric, single species system which alleviates the common problem of membrane crossover. The prototype multielectron system, utilizing molecular based charge carriers, made from inexpensive, abundant, and sustainable materials, principally, C and Fe, demonstrates remarkable current and energy densities and promising long-term cycling stability.

  12. Production of hydrogen driven from biomass waste to power Remote areas away from the electric grid utilizing fuel cells and internal combustion engines vehicles

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tawfik, Hazem

    Recent concerns over the security and reliability of the world’s energy supply has caused a flux towards the research and development of renewable sources. A leading renewable source has been found in the biomass gasification of biological materials derived from organic matters such as wood chips, forest debris, and farm waste that are found in abundance in the USA. Accordingly, there is a very strong interest worldwide in the development of new technologies that provide an in-depth understanding of this economically viable energy source. This work aims to allow the coupling of biomass gasification and fuel cell systems as wellmore » as Internal Combustion Engines (ICE) to produce high-energy efficiency, clean environmental performance and near-zero greenhouse gas emissions. Biomass gasification is a process, which produces synthesis gas (syngas) that contains 19% hydrogen and 20% carbon monoxide from inexpensive organic matter waste. This project main goal is to provide cost effective energy to the public utilizing remote farms’ waste and landfill recycling area.« less

  13. Environmental aspects of the geothermal energy utilisation in Poland

    NASA Astrophysics Data System (ADS)

    Sowiżdżał, Anna; Tomaszewska, Barbara; Drabik, Anna

    2017-11-01

    Geothermal energy is considered as a strategic and sustainable source of renewable energy that can be effectively managed in several economic sectors. In Poland, despite the abundant potential of such resources, its share in the energy mix of renewable energy sources remains insubstantial. The utilisation of geothermal resources in Poland is related to the hydrogeothermal resources, however, numerous researches related to petrogeothermal energy resources are being performed. The utilisation of each type of energy, including geothermal, has an impact on the natural environment. In case of the effective development of geothermal energy resources, many environmental benefits are pointed out. The primary one is the extraction of clean, green energy that is characterised by the zero-emission rate of pollutants into the atmosphere, what considering the current environmental pollution in many Polish cities remains the extremely important issue. On the other hand, the utilisation of geothermal energy might influence the natural environment negatively. Beginning from the phase of drilling, which strongly interferes with the local landscape or acoustic climate, to the stage of energy exploitation. It should be noted that the efficient and sustainable use of geothermal energy resources is closely linked with the current law regulations at national and European level.

  14. Water in Massive protostellar objects: first detection of THz water maser and water inner abundance.

    NASA Astrophysics Data System (ADS)

    Herpin, Fabrice

    2014-10-01

    The formation massive stars is still not well understood. Despite numerous water line observations with Herschel telescope, over a broad range of energies, in most of the observed sources the WISH-KP (Water In Star-forming regions with Herschel, Co-PI: F. Herpin) observations were not able to trace the emission from the hot core. Moreover, water maser model predict that several THz water maser should be detectable in these objects. We aim to detect for the first time the THz maser lines o-H2O 8(2,7)- 7(3,4) at 1296.41106 GHz and p-H2O 7(2,6)- 6(3,3) at 1440.78167 GHz as predicted by the model. We propose two sources for a northern flight as first priority and two other sources for a possible southern flight. This will 1) constrain the maser theory, 2) constrain the physical conditions and water abundance in the inner layers of the prostellar environnement. In addition, we will use the p-H2O 3(3,1)- 4(0,4) thermal line at 1893.68651 GHz (L2 channel) in order to probe the physical conditions and water abundance in the inner layers of the prostellar objects where HIFI-Herschel has partially failed.

  15. Simulation and Evaluation of Small Scale Solar Power Tower Performance under Malaysia Weather Conditions

    NASA Astrophysics Data System (ADS)

    Gamil, A. M.; Gilani, S. I.; Al-Kayiem, H. H.

    2013-06-01

    Solar energy is the most available, clean, and inexpensive source of energy among the other renewable sources of energy. Malaysia is an encouraging location for the development of solar energy systems due to abundant sunshine (10 hours daily with average solar energy received between 1400 and 1900 kWh/m2). In this paper the design of heliostat field of 3 dual-axis heliostat units located in Ipoh, Malaysia is introduced. A mathematical model was developed to estimate the sun position and calculate the cosine losses in the field. The study includes calculating the incident solar power to a fixed target on the tower by analysing the tower height and ground distance between the heliostat and the tower base. The cosine efficiency was found for each heliostat according to the sun movement. TRNSYS software was used to simulate the cosine efficiencies and field hourly incident solar power input to the fixed target. The results show the heliostat field parameters and the total incident solar input to the receiver.

  16. Exploring the Potential Business Case for Synergies Between Natural Gas and Renewable Energy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Cochran, Jaquelin; Zinaman, Owen; Logan, Jeffrey

    2014-02-01

    Natural gas and renewable energy each contribute to economic growth, energy independence, and carbon mitigation, sometimes independently and sometimes collectively. Often, natural gas and renewables are considered competitors in markets, such as those for bulk electricity. This paper attempts to address the question, 'Given near- and long-term needs for abundant, cleaner energy sources and decarbonization, how can more compelling business models be created so that these two domestic forms of energy work in greater concert?' This paper explores revenue opportunities that emerge from systems-level perspectives in 'bulk energy' (large-scale electricity and natural gas production, transmission, and trade) and four 'distributionmore » edge' subsectors: industrial, residential, commercial, and transportation end uses.« less

  17. Geochemical constraints on sources of metabolic energy for chemolithoautotrophy in ultramafic-hosted deep-sea hydrothermal systems.

    PubMed

    McCollom, Thomas M

    2007-12-01

    Numerical models are employed to investigate sources of chemical energy for autotrophic microbial metabolism that develop during mixing of oxidized seawater with strongly reduced fluids discharged from ultramafic-hosted hydrothermal systems on the seafloor. Hydrothermal fluids in these systems are highly enriched in H(2) and CH(4) as a result of alteration of ultramafic rocks (serpentinization) in the subsurface. Based on the availability of chemical energy sources, inferences are made about the likely metabolic diversity, relative abundance, and spatial distribution of microorganisms within ultramafic-hosted systems. Metabolic reactions involving H(2) and CH(4), particularly hydrogen oxidation, methanotrophy, sulfate reduction, and methanogenesis, represent the predominant sources of chemical energy during fluid mixing. Owing to chemical gradients that develop from fluid mixing, aerobic metabolisms are likely to predominate in low-temperature environments (<20-30 degrees C), while anaerobes will dominate higher-temperature environments. Overall, aerobic metabolic reactions can supply up to approximately 7 kJ of energy per kilogram of hydrothermal fluid, while anaerobic metabolic reactions can supply about 1 kJ, which is sufficient to support a maximum of approximately 120 mg (dry weight) of primary biomass production by aerobic organisms and approximately 20-30 mg biomass by anaerobes. The results indicate that ultramafic-hosted systems are capable of supplying about twice as much chemical energy as analogous deep-sea hydrothermal systems hosted in basaltic rocks.

  18. Identifying Galactic Cosmic Ray Origins With Super-TIGER

    NASA Technical Reports Server (NTRS)

    deNolfo, Georgia; Binns, W. R.; Israel, M. H.; Christian, E. R.; Mitchell, J. W.; Hams, T.; Link, J. T.; Sasaki, M.; Labrador, A. W.; Mewaldt, R. A.; hide

    2009-01-01

    Super-TIGER (Super Trans-Iron Galactic Element Recorder) is a new long-duration balloon-borne instrument designed to test and clarify an emerging model of cosmic-ray origins and models for atomic processes by which nuclei are selected for acceleration. A sensitive test of the origin of cosmic rays is the measurement of ultra heavy elemental abundances (Z > or equal 30). Super-TIGER is a large-area (5 sq m) instrument designed to measure the elements in the interval 30 < or equal Z < or equal 42 with individual-element resolution and high statistical precision, and make exploratory measurements through Z = 60. It will also measure with high statistical accuracy the energy spectra of the more abundant elements in the interval 14 < or equal Z < or equal 30 at energies 0.8 < or equal E < or equal 10 GeV/nucleon. These spectra will give a sensitive test of the hypothesis that microquasars or other sources could superpose spectral features on the otherwise smooth energy spectra previously measured with less statistical accuracy. Super-TIGER builds on the heritage of the smaller TIGER, which produced the first well-resolved measurements of elemental abundances of the elements Ga-31, Ge-32, and Se-34. We present the Super-TIGER design, schedule, and progress to date, and discuss the relevance of UH measurements to cosmic-ray origins.

  19. Metagenomic evidence for sulfur lithotrophy by Epsilonproteobacteria as the major energy source for primary productivity in a sub-aerial arctic glacial deposit, Borup Fiord Pass.

    PubMed

    Wright, Katherine E; Williamson, Charles; Grasby, Stephen E; Spear, John R; Templeton, Alexis S

    2013-01-01

    We combined free enenergy calculations and metagenomic analyses of an elemental sulfur (S(0)) deposit on the surface of Borup Fiord Pass Glacier in the Canadian High Arctic to investigate whether the energy available from different redox reactions in an environment predicts microbial metabolism. Many S, C, Fe, As, Mn, and [Formula: see text] oxidation reactions were predicted to be energetically feasible in the deposit, and aerobic oxidation of S(0) was the most abundant chemical energy source. Small subunit ribosomal RNA (SSU rRNA) gene sequence data showed that the dominant phylotypes were Sulfurovum and Sulfuricurvum, both Epsilonproteobacteria known to be capable of sulfur lithotrophy. Sulfur redox genes were abundant in the metagenome, but sox genes were significantly more abundant than reverse dsr (dissimilatory sulfite reductase)genes. Interestingly, there appeared to be habitable niches that were unoccupied at the depth of genome coverage obtained. Photosynthesis and [Formula: see text] oxidation should both be energetically favorable, but we found few or no functional genes for oxygenic or anoxygenic photosynthesis, or for [Formula: see text] oxidation by either oxygen (nitrification) or nitrite (anammox). The free energy, SSU rRNA gene and quantitative functional gene data are all consistent with the hypothesis that sulfur-based chemolithoautotrophy by Epsilonproteobacteria (Sulfurovum and Sulfuricurvum) is the main form of primary productivity at this site, instead of photosynthesis. This is despite the presence of 24-h sunlight, and the fact that photosynthesis is not known to be inhibited by any of the environmental conditions present. This is the first time that Sulfurovum and Sulfuricurvum have been shown to dominate a sub-aerial environment, rather than anoxic or sulfidic settings. We also found that Flavobacteria dominate the surface of the sulfur deposits. We hypothesize that this aerobic heterotroph uses enough oxygen to create a microoxic environment in the sulfur below, where the Epsilonproteobacteria can flourish.

  20. Metagenomic evidence for sulfur lithotrophy by Epsilonproteobacteria as the major energy source for primary productivity in a sub-aerial arctic glacial deposit, Borup Fiord Pass

    PubMed Central

    Wright, Katherine E.; Williamson, Charles; Grasby, Stephen E.; Spear, John R.; Templeton, Alexis S.

    2013-01-01

    We combined free enenergy calculations and metagenomic analyses of an elemental sulfur (S0) deposit on the surface of Borup Fiord Pass Glacier in the Canadian High Arctic to investigate whether the energy available from different redox reactions in an environment predicts microbial metabolism. Many S, C, Fe, As, Mn, and NH4+ oxidation reactions were predicted to be energetically feasible in the deposit, and aerobic oxidation of S0 was the most abundant chemical energy source. Small subunit ribosomal RNA (SSU rRNA) gene sequence data showed that the dominant phylotypes were Sulfurovum and Sulfuricurvum, both Epsilonproteobacteria known to be capable of sulfur lithotrophy. Sulfur redox genes were abundant in the metagenome, but sox genes were significantly more abundant than reverse dsr (dissimilatory sulfite reductase)genes. Interestingly, there appeared to be habitable niches that were unoccupied at the depth of genome coverage obtained. Photosynthesis and NH4+ oxidation should both be energetically favorable, but we found few or no functional genes for oxygenic or anoxygenic photosynthesis, or for NH4+ oxidation by either oxygen (nitrification) or nitrite (anammox). The free energy, SSU rRNA gene and quantitative functional gene data are all consistent with the hypothesis that sulfur-based chemolithoautotrophy by Epsilonproteobacteria (Sulfurovum and Sulfuricurvum) is the main form of primary productivity at this site, instead of photosynthesis. This is despite the presence of 24-h sunlight, and the fact that photosynthesis is not known to be inhibited by any of the environmental conditions present. This is the first time that Sulfurovum and Sulfuricurvum have been shown to dominate a sub-aerial environment, rather than anoxic or sulfidic settings. We also found that Flavobacteria dominate the surface of the sulfur deposits. We hypothesize that this aerobic heterotroph uses enough oxygen to create a microoxic environment in the sulfur below, where the Epsilonproteobacteria can flourish. PMID:23626586

  1. Evidence for Seismogenic Hydrogen Gas, a Potential Microbial Energy Source on Earth and Mars

    NASA Astrophysics Data System (ADS)

    McMahon, Sean; Parnell, John; Blamey, Nigel J. F.

    2016-09-01

    The oxidation of molecular hydrogen (H2) is thought to be a major source of metabolic energy for life in the deep subsurface on Earth, and it could likewise support any extant biosphere on Mars, where stable habitable environments are probably limited to the subsurface. Faulting and fracturing may stimulate the supply of H2 from several sources. We report the H2 content of fluids present in terrestrial rocks formed by brittle fracturing on fault planes (pseudotachylites and cataclasites), along with protolith control samples. The fluids are dominated by water and include H2 at abundances sufficient to support hydrogenotrophic microorganisms, with strong H2 enrichments in the pseudotachylites compared to the controls. Weaker and less consistent H2 enrichments are observed in the cataclasites, which represent less intense seismic friction than the pseudotachylites. The enrichments agree quantitatively with previous experimental measurements of frictionally driven H2 formation during rock fracturing. We find that conservative estimates of current martian global seismicity predict episodic H2 generation by Marsquakes in quantities useful to hydrogenotrophs over a range of scales and recurrence times. On both Earth and Mars, secondary release of H2 may also accompany the breakdown of ancient fault rocks, which are particularly abundant in the pervasively fractured martian crust. This study strengthens the case for the astrobiological investigation of ancient martian fracture systems.

  2. Mixotrophy and intraguild predation - dynamic consequences of shifts between food web motifs

    NASA Astrophysics Data System (ADS)

    Karnatak, Rajat; Wollrab, Sabine

    2017-06-01

    Mixotrophy is ubiquitous in microbial communities of aquatic systems with many flagellates being able to use autotroph as well as heterotroph pathways for energy acquisition. The usage of one over the other pathway is associated with resource availability and the coupling of alternative pathways has strong implications for system stability. We investigated the impact of dominance of different energy pathways related to relative resource availability on system dynamics in the setting of a tritrophic food web motif. This motif consists of a mixotroph feeding on a purely autotroph species while competing for a shared resource. In addition, the autotroph can use an additional exclusive food source. By changing the relative abundance of shared vs. exclusive food source, we shift the food web motif from an intraguild predation motif to a food chain motif. We analyzed the dependence of system dynamics on absolute and relative resource availability. In general, the system exhibits a transition from stable to oscillatory dynamics with increasing nutrient availability. However, this transition occurs at a much lower nutrient level for the food chain in comparison to the intraguild predation motif. A similar transition is also observed with variations in the relative abundance of food sources for a range of nutrient levels. We expect this shift in food web motifs to occur frequently in microbial communities and therefore the results from our study are highly relevant for natural systems.

  3. Thermostable enzymes as biocatalysts in the biofuel industry.

    PubMed

    Yeoman, Carl J; Han, Yejun; Dodd, Dylan; Schroeder, Charles M; Mackie, Roderick I; Cann, Isaac K O

    2010-01-01

    Lignocellulose is the most abundant carbohydrate source in nature and represents an ideal renewable energy source. Thermostable enzymes that hydrolyze lignocellulose to its component sugars have significant advantages for improving the conversion rate of biomass over their mesophilic counterparts. We review here the recent literature on the development and use of thermostable enzymes for the depolymerization of lignocellulosic feedstocks for biofuel production. Furthermore, we discuss the protein structure, mechanisms of thermostability, and specific strategies that can be used to improve the thermal stability of lignocellulosic biocatalysts. Copyright 2010 Elsevier Inc. All rights reserved.

  4. Observations of SO in dark and molecular clouds

    NASA Technical Reports Server (NTRS)

    Rydbeck, O. E. H.; Hjalmarson, A.; Rydbeck, G.; Ellder, J.; Kollberg, E.; Irvine, W. M.

    1980-01-01

    The 1(0)-0(1) transition of SO at 30 GHz has been observed in several sources, including the first detection of sulfur monoxide in cold dark clouds without apparent internal energy sources. The SO transition appears to be an excellent tracer of structure in dark clouds, and the data support suggestions that self-absorption is important in determining emission profiles in such regions for large line-strength transitions. Column densities estimated from a comparison of the results for the two isotopic species indicate a high fractional abundance of SO in dark clouds.

  5. Thermostable Enzymes as Biocatalysts in the Biofuel Industry

    PubMed Central

    Yeoman, Carl J.; Han, Yejun; Dodd, Dylan; Schroeder, Charles M.; Mackie, Roderick I.

    2015-01-01

    Lignocellulose is the most abundant carbohydrate source in nature and represents an ideal renewable energy source. Thermostable enzymes that hydrolyze lignocellulose to its component sugars have significant advantages for improving the conversion rate of biomass over their mesophilic counterparts. We review here the recent literature on the development and use of thermostable enzymes for the depolymerization of lignocellulosic feedstocks for biofuel production. Furthermore, we discuss the protein structure, mechanisms of thermostability, and specific strategies that can be used to improve the thermal stability of lignocellulosic biocatalysts. PMID:20359453

  6. Structure and function of natural sulphide-oxidizing microbial mats under dynamic input of light and chemical energy

    PubMed Central

    Klatt, Judith M; Meyer, Steffi; Häusler, Stefan; Macalady, Jennifer L; de Beer, Dirk; Polerecky, Lubos

    2016-01-01

    We studied the interaction between phototrophic and chemolithoautotrophic sulphide-oxidizing microorganisms in natural microbial mats forming in sulphidic streams. The structure of these mats varied between two end-members: one characterized by a layer dominated by large sulphur-oxidizing bacteria (SOB; mostly Beggiatoa-like) on top of a cyanobacterial layer (B/C mats) and the other with an inverted structure (C/B mats). C/B mats formed where the availability of oxygen from the water column was limited (<5 μm). Aerobic chemolithotrophic activity of the SOB depended entirely on oxygen produced locally by cyanobacteria during high light conditions. In contrast, B/C mats formed at locations where oxygen in the water column was comparatively abundant (>45 μM) and continuously present. Here SOB were independent of the photosynthetic activity of cyanobacteria and outcompeted the cyanobacteria in the uppermost layer of the mat where energy sources for both functional groups were concentrated. Outcompetition of photosynthetic microbes in the presence of light was facilitated by the decoupling of aerobic chemolithotrophy and oxygenic phototrophy. Remarkably, the B/C mats conserved much less energy than the C/B mats, although similar amounts of light and chemical energy were available. Thus ecosystems do not necessarily develop towards optimal energy usage. Our data suggest that, when two independent sources of energy are available, the structure and activity of microbial communities is primarily determined by the continuous rather than the intermittent energy source, even if the time-integrated energy flux of the intermittent energy source is greater. PMID:26405833

  7. Hard-Soft Composite Carbon as a Long-Cycling and High-Rate Anode for Potassium-Ion Batteries

    DOE PAGES

    Jian, Zelang; Hwang, Sooyeon; Li, Zhifei; ...

    2017-05-05

    There exist tremendous needs for sustainable storage solutions for intermittent renewable energy sources, such as solar and wind energy. Thus, systems based on Earth-abundant elements deserve much attention. Potassium-ion batteries represent a promising candidate because of the abundance of potassium resources. As for the choices of anodes, graphite exhibits encouraging potassium-ion storage properties; however, it suffers limited rate capability and poor cycling stability. Here in this paper, nongraphitic carbons as K-ion anodes with sodium carboxymethyl cellulose as the binder are systematically investigated. Compared to hard carbon and soft carbon, a hard–soft composite carbon with 20 wt% soft carbon distributed inmore » the matrix phase of hard carbon microspheres exhibits highly amenable performance: high capacity, high rate capability, and very stable long-term cycling. In contrast, pure hard carbon suffers limited rate capability, while the capacity of pure soft carbon fades more rapidly.« less

  8. Coal as an abundant source of graphene quantum dots

    NASA Astrophysics Data System (ADS)

    Ye, Ruquan; Xiang, Changsheng; Lin, Jian; Peng, Zhiwei; Huang, Kewei; Yan, Zheng; Cook, Nathan P.; Samuel, Errol L. G.; Hwang, Chih-Chau; Ruan, Gedeng; Ceriotti, Gabriel; Raji, Abdul-Rahman O.; Martí, Angel A.; Tour, James M.

    2013-12-01

    Coal is the most abundant and readily combustible energy resource being used worldwide. However, its structural characteristic creates a perception that coal is only useful for producing energy via burning. Here we report a facile approach to synthesize tunable graphene quantum dots from various types of coal, and establish that the unique coal structure has an advantage over pure sp2-carbon allotropes for producing quantum dots. The crystalline carbon within the coal structure is easier to oxidatively displace than when pure sp2-carbon structures are used, resulting in nanometre-sized graphene quantum dots with amorphous carbon addends on the edges. The synthesized graphene quantum dots, produced in up to 20% isolated yield from coal, are soluble and fluorescent in aqueous solution, providing promise for applications in areas such as bioimaging, biomedicine, photovoltaics and optoelectronics, in addition to being inexpensive additives for structural composites.

  9. Coal as an abundant source of graphene quantum dots.

    PubMed

    Ye, Ruquan; Xiang, Changsheng; Lin, Jian; Peng, Zhiwei; Huang, Kewei; Yan, Zheng; Cook, Nathan P; Samuel, Errol L G; Hwang, Chih-Chau; Ruan, Gedeng; Ceriotti, Gabriel; Raji, Abdul-Rahman O; Martí, Angel A; Tour, James M

    2013-01-01

    Coal is the most abundant and readily combustible energy resource being used worldwide. However, its structural characteristic creates a perception that coal is only useful for producing energy via burning. Here we report a facile approach to synthesize tunable graphene quantum dots from various types of coal, and establish that the unique coal structure has an advantage over pure sp2-carbon allotropes for producing quantum dots. The crystalline carbon within the coal structure is easier to oxidatively displace than when pure sp2-carbon structures are used, resulting in nanometre-sized graphene quantum dots with amorphous carbon addends on the edges. The synthesized graphene quantum dots, produced in up to 20% isolated yield from coal, are soluble and fluorescent in aqueous solution, providing promise for applications in areas such as bioimaging, biomedicine, photovoltaics and optoelectronics, in addition to being inexpensive additives for structural composites.

  10. Hard-Soft Composite Carbon as a Long-Cycling and High-Rate Anode for Potassium-Ion Batteries

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jian, Zelang; Hwang, Sooyeon; Li, Zhifei

    There exist tremendous needs for sustainable storage solutions for intermittent renewable energy sources, such as solar and wind energy. Thus, systems based on Earth-abundant elements deserve much attention. Potassium-ion batteries represent a promising candidate because of the abundance of potassium resources. As for the choices of anodes, graphite exhibits encouraging potassium-ion storage properties; however, it suffers limited rate capability and poor cycling stability. Here in this paper, nongraphitic carbons as K-ion anodes with sodium carboxymethyl cellulose as the binder are systematically investigated. Compared to hard carbon and soft carbon, a hard–soft composite carbon with 20 wt% soft carbon distributed inmore » the matrix phase of hard carbon microspheres exhibits highly amenable performance: high capacity, high rate capability, and very stable long-term cycling. In contrast, pure hard carbon suffers limited rate capability, while the capacity of pure soft carbon fades more rapidly.« less

  11. Observations and Thermochemical Calculations for Hot-Jupiter Atmospheres

    NASA Astrophysics Data System (ADS)

    Blecic, Jasmina; Harrington, Joseph; Bowman, M. Oliver; Cubillos, Patricio; Stemm, Madison

    2015-01-01

    I present Spitzer eclipse observations for WASP-14b and WASP-43b, an open source tool for thermochemical equilibrium calculations, and components of an open source tool for atmospheric parameter retrieval from spectroscopic data. WASP-14b is a planet that receives high irradiation from its host star, yet, although theory does not predict it, the planet hosts a thermal inversion. The WASP-43b eclipses have signal-to-noise ratios of ~25, one of the largest among exoplanets. To assess these planets' atmospheric composition and thermal structure, we developed an open-source Bayesian Atmospheric Radiative Transfer (BART) code. My dissertation tasks included developing a Thermochemical Equilibrium Abundances (TEA) code, implementing the eclipse geometry calculation in BART's radiative transfer module, and generating parameterized pressure and temperature profiles so the radiative-transfer module can be driven by the statistical module.To initialize the radiative-transfer calculation in BART, TEA calculates the equilibrium abundances of gaseous molecular species at a given temperature and pressure. It uses the Gibbs-free-energy minimization method with an iterative Lagrangian optimization scheme. Given elemental abundances, TEA calculates molecular abundances for a particular temperature and pressure or a list of temperature-pressure pairs. The code is tested against the original method developed by White at al. (1958), the analytic method developed by Burrows and Sharp (1999), and the Newton-Raphson method implemented in the open-source Chemical Equilibrium with Applications (CEA) code. TEA, written in Python, is modular, documented, and available to the community via the open-source development site GitHub.com.Support for this work was provided by NASA Headquarters under the NASA Earth and Space Science Fellowship Program, grant NNX12AL83H, by NASA through an award issued by JPL/Caltech, and through the Science Mission Directorate's Planetary Atmospheres Program, grant NNX12AI69G.

  12. Biosynthesis of the enzymes of the cellulase system by T. Reesei QM 9414 in the presence of sophorose

    NASA Astrophysics Data System (ADS)

    Gritzali, M.

    1982-12-01

    As conventional, nonrenewable energy sources are rapidly depleted and it was necessary to search for alternative sources of energy. It was increasingly apparent that biomass and waste are alternatives well worth exploring. The sources of biomass and wastes that considered for conversion to useful products are quite diverse, but the most abundant constituent of almost every type is cellulose. Cellulose is cleanly converted to soluble fermentable sugars enzymatically, and cellulose enzymes were isolated from a number of microbial sources. It is generally agreed that the most effective system of enzymes for the conversion of cellulose to glucose is produced by species of the imperfect fungus Trichoderma. The mutant organism Trichoderma reesei QM 9414 is among the best producers of high levels of enzymes; these are extracellular and have carbonhydrate covalently bound to the peptide. Trichoderma produces three types of enzymes which, in a sequential and cooperative manner, convert cellulose to soluble oligosaccharides and glucose.

  13. Seasonal variation in natural abundance of 2H and 18O in urine samples from rural Nigeria

    PubMed Central

    Dugas, Lara R.; Brieger, William; Tayo, Bamidele O.; Alabi, Tunrayo; Schoeller, Dale A.; Luke, Amy

    2015-01-01

    The doubly labeled water (DLW) method is used to measure free-living energy expenditure in humans. Inherent to this technique is the assumption that natural abundances of stable isotopes 2H and 18O in body water remain constant over the course of the measurement period and after elimination of the loading dose of DLW will return to the same predose level. To determine variability in the natural abundances of 2H and 18O in humans living in a region with seasonal shifts in rain patterns and sources of drinking water, over the course of 12 mo we collected weekly urine samples from four individuals living in southwest Nigeria as well as samples of their drinking water. From ongoing regional studies of hypertension, obesity, and energy expenditure, we estimated average water turnover rate, urine volumes, and sodium and potassium excretion. Results suggest that 2H and 18O in urine, mean concentrations of urinary sodium and potassium, urine volume, and total body turnover differed significantly from dry to rainy season. Additionally, seasonal weather variables (mean monthly maximum temperatures, total monthly rainfall, and minimum relative humidity) were all significantly associated with natural abundances in urine. No seasonal difference was observed in drinking water samples. Findings suggest that natural abundances in urine may not remain constant as assumed, and studies incorporating DLW measurements across the transition of seasons should interpret results with caution unless appropriate doses of the tracers are used. PMID:25977450

  14. Chandra observations of dying radio sources in galaxy clusters

    NASA Astrophysics Data System (ADS)

    Murgia, M.; Markevitch, M.; Govoni, F.; Parma, P.; Fanti, R.; de Ruiter, H. R.; Mack, K.-H.

    2012-12-01

    Context. The dying radio sources represent a very interesting and largely unexplored stage of the active galactic nucleus (AGN) evolution. They are considered to be very rare, and almost all of the few known ones were found in galaxy clusters. However, considering the small number detected so far, it has not been possible to draw any firm conclusions about their X-ray environment. Aims: We present X-ray observations performed with the Chandra satellite of the three galaxy clusters Abell 2276, ZwCl 1829.3+6912, and RX J1852.1+5711, which harbor at their center a dying radio source with an ultra-steep spectrum that we recently discovered. Methods: We analyzed the physical properties of the X-ray emitting gas surrounding these elusive radio sources. We determined the global X-ray properties of the clusters, derived the azimuthally averaged profiles of metal abundance, gas temperature, density, and pressure. Furthermore, we estimated the total mass profiles. Results: The large-scale X-ray emission is regular and spherical, suggesting a relaxed state for these systems. Indeed, we found that the three clusters are also characterized by significant enhancements in the metal abundance and declining temperature profiles toward the central region. For all these reasons, we classified RX J1852.1+5711, Abell 2276, and ZwCl 1829.3+6912 as cool-core galaxy clusters. Conclusions: We calculated the non-thermal pressure of the radio lobes assuming that the radio sources are in the minimum energy condition. For all dying sources we found that this is on average about one to two orders of magnitude lower than that of the external gas, as found for many other radio sources at the center of galaxy groups and clusters. We found marginal evidence for the presence of X-ray surface brightness depressions coincident with the fossil radio lobes of the dying sources in A2276 and ZwCl 1829.3+691. We estimated the outburst age and energy output for these two dying sources. The energy power from the AGN outburst is significantly higher than the X-ray luminosity in both clusters. Indeed, it is sufficient that a small fraction of this power is dissipated in the intra-cluster medium to reheat the cool cores. Appendix is available in electronic form at http://www.aanda.org

  15. Chandra Observations of Dying Radio Sources in Galaxy Clusters

    NASA Technical Reports Server (NTRS)

    Murgia, M.; Markevitch, M.; Govoni, F.; Parma, P.; Fanti, R.; de Ruiter, H. R.; Mack, K.-H.

    2012-01-01

    Context. The dying radio sources represent a very interesting and largely unexplored stage of the active galactic nucleus (AGN) evolution. They are considered to be very rare, and almost all of the few known ones were found in galaxy clusters. However, considering the small number detected so far, it has not been possible to draw any firm conclusions about their X-ray environment. Aims. We present X-ray observations performed with the Chandra satellite of the three galaxy clusters Abell 2276, ZwCl 1829.3+6912, and RX J1852.1+5711, which harbor at their center a dying radio source with an ultra-steep spectrum that we recently discovered. Methods. We analyzed the physical properties of the X-ray emitting gas surrounding these elusive radio sources. We determined the global X-ray properties of the clusters, derived the azimuthally averaged profiles of metal abundance, gas temperature, density, and pressure. Furthermore, we estimated the total mass profiles. Results. The large-scale X-ray emission is regular and spherical, suggesting a relaxed state for these systems. Indeed, we found that the three clusters are also characterized by significant enhancements in the metal abundance and declining temperature profiles toward the central region. For all these reasons, we classified RX J1852.1+5711, Abell 2276, and ZwCl 1829.3+6912 as cool-core galaxy clusters. Conclusions. We calculated the non-thermal pressure of the radio lobes assuming that the radio sources are in the minimum energy condition. For all dying sources we found that this is on average about one to two orders of magnitude lower than that of the external gas, as found for many other radio sources at the center of galaxy groups and clusters. We found marginal evidence for the presence of X-ray surface brightness depressions coincident with the fossil radio lobes of the dying sources in A2276 and ZwCl 1829.3+691. We estimated the outburst age and energy output for these two dying sources. The energy power from the AGN outburst is significantly higher than the X-ray luminosity in both clusters. Indeed, it is sufficient that a small fraction of this power is dissipated in the intra-cluster medium to reheat the cool cores.

  16. Empowerment model of biomass in west java

    NASA Astrophysics Data System (ADS)

    Mulyana, C.; Fitriani, N. I.; Saad, A.; Yuliah, Y.

    2017-06-01

    Scarcity of fossil energy accelerates the search of renewable energy sources as the substitution. In West Java, biomass has potential to be developed into bio-briquette because the resources are abundant. The objectives of this research are mapping the potency of biomass as bio-briquette in West Java, and making the model of the empowerment biomass potential involving five fundamental step which are raw material, pre-processing process, conversion mechanism, products, and end user. The main object of this model focused on 3 forms which are solid, liquid, and gas which was made by involving the community component as the owner biomass, district government, academics and researcher communities, related industries as users of biomass, and the central government as the policy holders and investors as a funder. In the model was described their respective roles and mutual relationship one with another so that the bio-briquette as a substitute of fossil fuels can be realized. Application of this model will provide the benefits in renewability energy sources, environmental, socio economical and energy security.

  17. Galactic cosmic ray composition

    NASA Technical Reports Server (NTRS)

    Meyer, J. P.

    1986-01-01

    An assessment is given of the galactic cosmic ray source (GCRS) elemental composition and its correlation with first ionization potential. The isotopic composition of heavy nuclei; spallation cross sections; energy spectra of primary nuclei; electrons; positrons; local galactic reference abundances; comparison of solar energetic particles and solar coronal compositions; the hydrogen; lead; nitrogen; helium; and germanium deficiency problems; and the excess of elements are among the topics covered.

  18. Energy as a Constraint on Habitability in the Subsurface

    NASA Astrophysics Data System (ADS)

    Hoehler, T.

    2008-12-01

    All living things must obtain energy from the environment to grow, to maintain a metabolic steady state, or simply to preserve viability. The availability of energy sources in the environment thus represents a key factor in determining the size, distribution, and activity of biological populations, and ultimately constrains the possibility for life itself. Lacking the abundant energy provided by solar radiation or the products of oxygenic photosynthesis, life in subsurface environments may be limited by energy availability as much as any other factor. The biological requirement for energy is expressed in two dimensions - analogous to the power and voltage requirements of electrical devices - and consideration and quantification of these requirements establishes quantitative boundary conditions on subsurface habitability. The magnitude of these requirements depends significantly on physicochemical environment, as does the provision of biologically-accessible energy from subsurface sources. With this conceptual basis, we are developing an 'energy balance' model that is designed to ultimately predict the habitability of a given environment, with respect to a given metabolism, in quantitative terms (as 'biomass density potential'). The model will develop from conceptual to quantitative as experimental and observational work constrains and quantifies, in natural populations adapted to low energy conditions, the magnitude of the biological energy requirements and the impacts of physicochemical environmental conditions on energy demand and supply.

  19. A new class of galactic discrete gamma ray sources: Chaotic winds of massive stars

    NASA Technical Reports Server (NTRS)

    Chen, Wan; White, Richard L.

    1992-01-01

    We propose a new class of galactic discrete gamma-ray sources, the chaotic, high mass-loss-rate winds from luminous early-type stars. Early-type stellar winds are highly unstable due to intrinsic line-driven instabilities, and so are permeated by numerous strong shocks. These shocks can accelerate a small fraction of thermal electrons and ions to relativistic energies via the first-order Fermi mechanism. A power-law-like photon spectrum extending from keV to above 10 MeV energies is produced by inverse Compton scattering of the extremely abundant stellar UV photons by the relativistic electrons. In addition, a typical pi(sup 0)-decay gamma-ray spectrum is generated by proton-ion interactions in the densest part of the winds.

  20. A balloon measurement of the isotopic composition of galactic cosmic ray iron

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Grove, J.E.

    1989-01-01

    The isotopic composition of galactic cosmic ray iron in the energy interval of approximately 1550 to 2200 MeV/nucleon was measured using a balloon-borne mass spectrometer. The instrument was flown from Palestine, Texas, in May 1984 for greater than 35 hours at an atmospheric depth of approximately 6 g/sq cm. Masses were derived by the Cerenkov-Energy technique. The Cerenkov counter employed a silica aerogel radiator with an index of refraction n = 1.1. Particle energies were measured in a stack of NaI(Tl) scintillators, which also provided particle trajectories. A detailed discussion of the sources of mass uncertainty is presented, including anmore » analytic model of the contribution from fluctuations in the Cerenkov yield from knock-on electrons. The achieved mass resolution is approximately 0.65 amu, which is consistent with the theoretical estimate. An Fe-54/Fe-56 abundance ratio of 0.14(sup +0.18)(sub -0.11) and an 84 percent confidence upper limit of Fe-58/Fe-56 is less than or = to 0.07 at the top of the atmosphere is reported. Combining the data with those of precious measurements of the composition of iron at lower energies, and using a model of the galactic propagation, cosmic-ray source abundance ratios of Fe-54/Fe-56 = 0.064(sup +0.032)(sub -0.027) and Fe-58/F3-56 is less than or = to 0.062 were derived. These values are consistent with the composition of solar system iron and place restrictions on the conditions under which cosmic-ray iron is synthesized.« less

  1. Source abundances of ultra heavy elements derived from UHCRE measurements.

    PubMed

    Domingo, C; Font, J; Baixeras, C; Fernandez, F

    1996-11-01

    A total of 205 tracks have been located, measured, and positively identified as originating from Ultra Heavy (Z > or = 65) cosmic ray ions with energies over 2 GeV/amu in the 10 UHCRE plastic track detector (mainly Lexan polycarbonate) stacks studied by our Group. About 40 values of reduced etch rate S have been obtained along each of these tracks. A method based on determining the gradient of S, together with calibration in accelerators, is used to determine the charge of each ion resulting in one of such tracks to obtain the charge spectrum of the recorded Ultra Heavy ions. The abundance ratio of ions with 87 < or = Z < or = 100 to those with 74 < or = Z < or = 86 as well as that of ions with 81 < or = Z < or = 86 to those with 74 < or = Z < or = 80 are calculated at 0.016 and 0.32, respectively, which agree with the values obtained from measurements in the HEAO-3 and Ariel-6 experiments. The abundance ratio of ions with 70 < or = Z < or = 73 to those with 74 < or = Z < or = 86 is also calculated, but its value (0.074) did not seem to be significant because of our detectors' low registration efficiency in the charge range 70 < or = Z < or = 73. A computer program developed by our Group, based on the Leaky Box cosmic ray propagation model, has been used to determine the source abundances of cosmic ray nuclei with Z > or = 65 inferred from the abundances measured in the UHCRE. It appeared that r-process synthesized elements were overabundant compared to the Solar System abundances, as predicted by other authors.

  2. Synergistic microbial consortium for bioenergy generation from complex natural energy sources.

    PubMed

    Wang, Victor Bochuan; Yam, Joey Kuok Hoong; Chua, Song-Lin; Zhang, Qichun; Cao, Bin; Chye, Joachim Loo Say; Yang, Liang

    2014-01-01

    Microbial species have evolved diverse mechanisms for utilization of complex carbon sources. Proper combination of targeted species can affect bioenergy production from natural waste products. Here, we established a stable microbial consortium with Escherichia coli and Shewanella oneidensis in microbial fuel cells (MFCs) to produce bioenergy from an abundant natural energy source, in the form of the sarcocarp harvested from coconuts. This component is mostly discarded as waste. However, through its usage as a feedstock for MFCs to produce useful energy in this study, the sarcocarp can be utilized meaningfully. The monospecies S. oneidensis system was able to generate bioenergy in a short experimental time frame while the monospecies E. coli system generated significantly less bioenergy. A combination of E. coli and S. oneidensis in the ratio of 1:9 (v:v) significantly enhanced the experimental time frame and magnitude of bioenergy generation. The synergistic effect is suggested to arise from E. coli and S. oneidensis utilizing different nutrients as electron donors and effect of flavins secreted by S. oneidensis. Confocal images confirmed the presence of biofilms and point towards their importance in generating bioenergy in MFCs.

  3. Role of Escherichia coli in Biofuel Production

    PubMed Central

    Koppolu, Veerendra; Vasigala, Veneela KR

    2016-01-01

    Increased energy consumption coupled with depleting petroleum reserves and increased greenhouse gas emissions have renewed our interest in generating fuels from renewable energy sources via microbial fermentation. Central to this problem is the choice of microorganism that catalyzes the production of fuels at high volumetric productivity and yield from cheap and abundantly available renewable energy sources. Microorganisms that are metabolically engineered to redirect renewable carbon sources into desired fuel products are contemplated as best choices to obtain high volumetric productivity and yield. Considering the availability of vast knowledge in genomic and metabolic fronts, Escherichia coli is regarded as a primary choice for the production of biofuels. Here, we reviewed the microbial production of liquid biofuels that have the potential to be used either alone or in combination with the present-day fuels. We specifically highlighted the metabolic engineering and synthetic biology approaches used to improve the production of biofuels from E. coli over the past few years. We also discussed the challenges that still exist for the biofuel production from E. coli and their possible solutions. PMID:27441002

  4. Jellyfish as prey: frequency of predation and selective foraging of Boops boops (Vertebrata, Actinopterygii) on the mauve stinger Pelagia noctiluca (Cnidaria, Scyphozoa).

    PubMed

    Milisenda, Giacomo; Rosa, Sara; Fuentes, Veronica L; Boero, Ferdinando; Guglielmo, Letterio; Purcell, Jennifer E; Piraino, Stefano

    2014-01-01

    In recent years, jellyfish blooms have attracted considerable scientific interest for their potential impacts on human activities and ecosystem functioning, with much attention paid to jellyfish as predators and to gelatinous biomass as a carbon sink. Other than qualitative data and observations, few studies have quantified direct predation of fish on jellyfish to clarify whether they may represent a seasonally abundant food source. Here we estimate predation frequency by the commercially valuable Mediterranean bogue, Boops boops on the mauve stinger jellyfish, Pelagia noctiluca, in the Strait of Messina (NE Sicily). A total of 1054 jellyfish were sampled throughout one year to quantify predation by B. boops from bite marks on partially eaten jellyfish and energy density of the jellyfish. Predation by B. boops in summer was almost twice that in winter, and they selectively fed according to medusa gender and body part. Calorimetric analysis and biochemical composition showed that female jellyfish gonads had significantly higher energy content than male gonads due to more lipids and that gonads had six-fold higher energy content than the somatic tissues due to higher lipid and protein concentrations. Energetically, jellyfish gonads represent a highly rewarding food source, largely available to B. boops throughout spring and summer. During the remainder of the year, when gonads were not very evident, fish predation switched towards less-selective foraging on the somatic gelatinous biomass. P. noctiluca, the most abundant jellyfish species in the Mediterranean Sea and a key planktonic predator, may represent not only a nuisance for human leisure activities and a source of mortality for fish eggs and larvae, but also an important resource for fish species of commercial value, such as B. boops.

  5. Jellyfish as Prey: Frequency of Predation and Selective Foraging of Boops boops (Vertebrata, Actinopterygii) on the Mauve Stinger Pelagia noctiluca (Cnidaria, Scyphozoa)

    PubMed Central

    Fuentes, Veronica L.; Boero, Ferdinando; Guglielmo, Letterio; Purcell, Jennifer E.; Piraino, Stefano

    2014-01-01

    In recent years, jellyfish blooms have attracted considerable scientific interest for their potential impacts on human activities and ecosystem functioning, with much attention paid to jellyfish as predators and to gelatinous biomass as a carbon sink. Other than qualitative data and observations, few studies have quantified direct predation of fish on jellyfish to clarify whether they may represent a seasonally abundant food source. Here we estimate predation frequency by the commercially valuable Mediterranean bogue, Boops boops on the mauve stinger jellyfish, Pelagia noctiluca, in the Strait of Messina (NE Sicily). A total of 1054 jellyfish were sampled throughout one year to quantify predation by B. boops from bite marks on partially eaten jellyfish and energy density of the jellyfish. Predation by B. boops in summer was almost twice that in winter, and they selectively fed according to medusa gender and body part. Calorimetric analysis and biochemical composition showed that female jellyfish gonads had significantly higher energy content than male gonads due to more lipids and that gonads had six-fold higher energy content than the somatic tissues due to higher lipid and protein concentrations. Energetically, jellyfish gonads represent a highly rewarding food source, largely available to B. boops throughout spring and summer. During the remainder of the year, when gonads were not very evident, fish predation switched towards less-selective foraging on the somatic gelatinous biomass. P. noctiluca, the most abundant jellyfish species in the Mediterranean Sea and a key planktonic predator, may represent not only a nuisance for human leisure activities and a source of mortality for fish eggs and larvae, but also an important resource for fish species of commercial value, such as B. boops. PMID:24727977

  6. Metagenomic insights into strategies of carbon conservation and unusual sulfur biogeochemistry in a hypersaline Antarctic lake

    PubMed Central

    Yau, Sheree; Lauro, Federico M; Williams, Timothy J; DeMaere, Matthew Z; Brown, Mark V; Rich, John; Gibson, John AE; Cavicchioli, Ricardo

    2013-01-01

    Organic Lake is a shallow, marine-derived hypersaline lake in the Vestfold Hills, Antarctica that has the highest reported concentration of dimethylsulfide (DMS) in a natural body of water. To determine the composition and functional potential of the microbial community and learn about the unusual sulfur chemistry in Organic Lake, shotgun metagenomics was performed on size-fractionated samples collected along a depth profile. Eucaryal phytoflagellates were the main photosynthetic organisms. Bacteria were dominated by the globally distributed heterotrophic taxa Marinobacter, Roseovarius and Psychroflexus. The dominance of heterotrophic degradation, coupled with low fixation potential, indicates possible net carbon loss. However, abundant marker genes for aerobic anoxygenic phototrophy, sulfur oxidation, rhodopsins and CO oxidation were also linked to the dominant heterotrophic bacteria, and indicate the use of photo- and lithoheterotrophy as mechanisms for conserving organic carbon. Similarly, a high genetic potential for the recycling of nitrogen compounds likely functions to retain fixed nitrogen in the lake. Dimethylsulfoniopropionate (DMSP) lyase genes were abundant, indicating that DMSP is a significant carbon and energy source. Unlike marine environments, DMSP demethylases were less abundant, indicating that DMSP cleavage is the likely source of high DMS concentration. DMSP cleavage, carbon mixotrophy (photoheterotrophy and lithoheterotrophy) and nitrogen remineralization by dominant Organic Lake bacteria are potentially important adaptations to nutrient constraints. In particular, carbon mixotrophy relieves the extent of carbon oxidation for energy production, allowing more carbon to be used for biosynthetic processes. The study sheds light on how the microbial community has adapted to this unique Antarctic lake environment. PMID:23619305

  7. Advanced Heat/Mass Exchanger Technology for Geothermal and Solar Renewable Energy Systems

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Greiner, Miles; Childress, Amy; Hiibel, Sage

    2014-12-16

    Northern Nevada has abundant geothermal and solar energy resources, and these renewable energy sources provide an ample opportunity to produce economically viable power. Heat/mass exchangers are essential components to any energy conversion system. Improvements in the heat/mass exchange process will lead to smaller, less costly (more efficient) systems. There is an emerging heat transfer technology, based on micro/nano/molecular-scale surface science that can be applied to heat/mass exchanger design. The objective is to develop and characterize unique coating materials, surface configurations and membranes capable of accommodating a 10-fold increase in heat/mass exchanger performance via phase change processes (boiling, condensation, etc.) andmore » single phase convective heat/mass transfer.« less

  8. A Short Progress Report on High-Efficiency Perovskite Solar Cells.

    PubMed

    Tang, He; He, Shengsheng; Peng, Chuangwei

    2017-12-01

    Faced with the increasingly serious energy and environmental crisis in the world nowadays, the development of renewable energy has attracted increasingly more attention of all countries. Solar energy as an abundant and cheap energy is one of the most promising renewable energy sources. While high-performance solar cells have been well developed in the last couple of decades, the high module cost largely hinders wide deployment of photovoltaic devices. In the last 10 years, this urgent demand for cost-effective solar cells greatly facilitates the research of solar cells. This paper reviews the recent development of cost-effective and high-efficient solar cell technologies. This report paper covers low-cost and high-efficiency perovskite solar cells. The development and the state-of-the-art results of perovskite solar cell technologies are also introduced.

  9. Tungsten Abundances in Hawaiian Picrites: Implications for the Mantle Sources of Hawaiian Volcanoes

    NASA Astrophysics Data System (ADS)

    Ireland, T. J.; Arevalo, R. D.; Walker, R. J.; McDonough, W. F.

    2008-12-01

    Tungsten abundances have been measured in a suite of Hawaiian picrites (MgO >13 wt.%) from nine Hawaiian shield volcanoes (Mauna Kea, Mauna Loa, Hualalai, Loihi, Koolau, Kilauea, Kohala, Lanai and Molokai). Tungsten concentrations in the parental melts for these volcanoes have been estimated via the intersection of linear W-MgO trends with the putative MgO content of the parental melt (~16 wt.%). Tungsten behaves as a highly incompatible trace element in mafic to ultramafic systems; thus, given an independent assessment of the degree of partial melting for each volcanic center, the W abundances in their mantle sources can be determined. The mantle sources for Hualalai, Kilauea, Kohala and Loihi have non- uniform estimated W abundances of 11, 13, 16 and 27 ng/g, respectively, giving an average source abundance of 17±5 ng/g. This average source abundance is nearly six times more enriched than Depleted MORB Mantle (DMM: 3.0±2.3 ng/g) and slightly elevated relative to the Bulk Silicate Earth (BSE: 13±10 ng/g). The relatively high abundances of W in the Hawaiian sources relative to the DMM can potentially be explained as a consequence of crustal recycling. For example, incorporation of 30% oceanic crust (30 ng/g W), including 3% sediment (1500 ng/g W), into a DMM source could create the W enrichment observed in the Loihi source, consistent with estimates from earlier models based on other trace elements and isotope systems. The Hualalai source, however, has also been suggested to contain a substantial recycled component, as implied by similarly radiogenic 187Os/188Os, yet this source has the lowest estimated W abundance among the volcanic centers studied. The conflict between these results may: 1) reflect chemical differences among recycled components, 2) indicate a more complex history for Hualalai samples, e.g. involvement of a melt percolation component, or 3) implicate other sources of W.

  10. Evidence for Seismogenic Hydrogen Gas, a Potential Microbial Energy Source on Earth and Mars.

    PubMed

    McMahon, Sean; Parnell, John; Blamey, Nigel J F

    2016-09-01

    The oxidation of molecular hydrogen (H2) is thought to be a major source of metabolic energy for life in the deep subsurface on Earth, and it could likewise support any extant biosphere on Mars, where stable habitable environments are probably limited to the subsurface. Faulting and fracturing may stimulate the supply of H2 from several sources. We report the H2 content of fluids present in terrestrial rocks formed by brittle fracturing on fault planes (pseudotachylites and cataclasites), along with protolith control samples. The fluids are dominated by water and include H2 at abundances sufficient to support hydrogenotrophic microorganisms, with strong H2 enrichments in the pseudotachylites compared to the controls. Weaker and less consistent H2 enrichments are observed in the cataclasites, which represent less intense seismic friction than the pseudotachylites. The enrichments agree quantitatively with previous experimental measurements of frictionally driven H2 formation during rock fracturing. We find that conservative estimates of current martian global seismicity predict episodic H2 generation by Marsquakes in quantities useful to hydrogenotrophs over a range of scales and recurrence times. On both Earth and Mars, secondary release of H2 may also accompany the breakdown of ancient fault rocks, which are particularly abundant in the pervasively fractured martian crust. This study strengthens the case for the astrobiological investigation of ancient martian fracture systems. Deep biosphere-Faults-Fault rocks-Seismic activity-Hydrogen-Mars. Astrobiology 16, 690-702.

  11. Solar Pond Potential as A New Renewable Energy in South Sulawesi

    NASA Astrophysics Data System (ADS)

    Fadliah Baso, Nur; Chaerah Gunadin, Indar; Yusran

    2018-03-01

    Renewable energy sources need to be developed to maintain the electric energy availability by utilizing oceanic energy, namely solar pond energy. This energy is highly influenced by several factors including salinity, air temperature and solar radiation. This study was focused on finding the potential of solar pond in South Sulawesi, a region with fairly high solar radiation and abundant salt water raw materials availability. The method used in this study was analyzing the values from the mathematic models of daily horizontal solar radiation, air temperature, wind speed, relative humidity and atmospheric pressure for the last 22 years which were finalized using MATLAB. The findings of this study will show the areas with good potentials to apply solar pond in South Sulawesi that can be utilized in various fields including power generator, industrial heating process, desalination and heating for biomass conversion.

  12. Energy balance in Saturn's upper atmosphere: Joint Lyman-α airglow observations with HST and Cassini

    NASA Astrophysics Data System (ADS)

    Ben-Jaffel, L.; Baines, K. H.; Ballester, G.; Holberg, H. B.; Koskinen, T.; Moses, J. I.; West, R. A.; Yelle, R. V.

    2017-12-01

    We are conducting Hubble Space Telescope UV spectroscopy of Saturn's disk-reflected Lyman-α line (Ly-α) at the same time as Cassini airglow measurements. Saturn's Ly-α emission is composed of solar and interplanetary (IPH) Ly-α photons scattered by its upper atmosphere. The H I Ly-a line probes different upper atmospheric layers down to the homopause, providing an independent way to investigate the H I abundance and energy balance. However, this is a degenerate, multi-parameter, radiative-transfer problem that depends on: H I column density, scattering process by thermal and superthermal hydrogen, time-variable solar and IPH sources, and instrument calibration. Our joint HST-Cassini campaign should break the degeneracy in the Saturn airglow problem. First, line integrated fluxes simultaneously measured by HST/STIS (dayside) and Cassini/UVIS (nightside), avoiding solar variability, should resolve the solar and IPH sources. Second, high-resolution spectroscopy with STIS will reveal superthermal line broadening not accessible with a low-resolution spectrometer like UVIS. Third, a second visit observing the same limb of Saturn will cross-calibrate the instruments and, with the STIS linewidth information, will yield the H I abundance, a key photochemical parameter not measured by Cassini. Finally, the STIS latitudinal mapping of the Ly-α linewidth will be correlated with Cassini's latitudinal temperature profile of the thermosphere, to provide an independent constraint on the thermospheric energy budget, a fundamental outstanding problem for giant planets. Here, we report the first results from the HST-Cassini campaign.

  13. Advancements in solar stills for enhanced flow rate

    NASA Astrophysics Data System (ADS)

    Mishra, Sourav; Dubey, Maneesh; Raghuwanshi, Jitendra; Sharma, Vipin

    2018-05-01

    All over the world there is a scarcity of water and it is difficult to access potable water. Due to this most of the people are affected by diseases that are caused due to drinking of polluted water. There are technologies through which we can purify polluted water but the only problem is these technologies uses electrical energy. Since solar energy is abundant in nature therefore we can use solar as an energy source in solar stills for water distillation. Solar stills can be used in village areas where there is no electricity. It is simple and also economic in construction. This article addresses advancement in solar distillation and usage of nanofluids for enhancement in flow rate.

  14. Manufacturing with the Sun

    NASA Astrophysics Data System (ADS)

    Murphy, L. M.; Hauser, S. G.; Clyne, R. J.

    1992-05-01

    Concentrated solar radiation is now a viable alternative energy source for many advanced manufacturing processes. Researchers at the National Renewable Energy Laboratory (NREL) have demonstrated the feasibility of processes such as solar-induced surface transformation of materials (SISTM), solar-based manufacturing, and solar-pumped lasers. Researchers are also using sunlight to decontaminate water and soils polluted with organic compounds; these techniques could provide manufacturers with innovative alternatives to traditional methods of waste management. The solar technology that is now being integrated into today's manufacturing processes offers even greater potential for tomorrow, especially as applied to the radiation-abundant environment available in space and on the lunar surface.

  15. Seasonal variation in natural abundance of 2H and 18O in urine samples from rural Nigeria.

    PubMed

    Harbison, Justin E; Dugas, Lara R; Brieger, William; Tayo, Bamidele O; Alabi, Tunrayo; Schoeller, Dale A; Luke, Amy

    2015-07-01

    The doubly labeled water (DLW) method is used to measure free-living energy expenditure in humans. Inherent to this technique is the assumption that natural abundances of stable isotopes (2)H and (18)O in body water remain constant over the course of the measurement period and after elimination of the loading dose of DLW will return to the same predose level. To determine variability in the natural abundances of (2)H and (18)O in humans living in a region with seasonal shifts in rain patterns and sources of drinking water, over the course of 12 mo we collected weekly urine samples from four individuals living in southwest Nigeria as well as samples of their drinking water. From ongoing regional studies of hypertension, obesity, and energy expenditure, we estimated average water turnover rate, urine volumes, and sodium and potassium excretion. Results suggest that (2)H and (18)O in urine, mean concentrations of urinary sodium and potassium, urine volume, and total body turnover differed significantly from dry to rainy season. Additionally, seasonal weather variables (mean monthly maximum temperatures, total monthly rainfall, and minimum relative humidity) were all significantly associated with natural abundances in urine. No seasonal difference was observed in drinking water samples. Findings suggest that natural abundances in urine may not remain constant as assumed, and studies incorporating DLW measurements across the transition of seasons should interpret results with caution unless appropriate doses of the tracers are used. Copyright © 2015 the American Physiological Society.

  16. Photochemical conversion of solar energy.

    PubMed

    Balzani, Vincenzo; Credi, Alberto; Venturi, Margherita

    2008-01-01

    Energy is the most important issue of the 21st century. About 85% of our energy comes from fossil fuels, a finite resource unevenly distributed beneath the Earth's surface. Reserves of fossil fuels are progressively decreasing, and their continued use produces harmful effects such as pollution that threatens human health and greenhouse gases associated with global warming. Prompt global action to solve the energy crisis is therefore needed. To pursue such an action, we are urged to save energy and to use energy in more efficient ways, but we are also forced to find alternative energy sources, the most convenient of which is solar energy for several reasons. The sun continuously provides the Earth with a huge amount of energy, fairly distributed all over the world. Its enormous potential as a clean, abundant, and economical energy source, however, cannot be exploited unless it is converted into useful forms of energy. This Review starts with a brief description of the mechanism at the basis of the natural photosynthesis and, then, reports the results obtained so far in the field of photochemical conversion of solar energy. The "grand challenge" for chemists is to find a convenient means for artificial conversion of solar energy into fuels. If chemists succeed to create an artificial photosynthetic process, "... life and civilization will continue as long as the sun shines!", as the Italian scientist Giacomo Ciamician forecast almost one hundred years ago.

  17. Hydrogen and bioenergetics in the Yellowstone geothermal ecosystem

    PubMed Central

    Spear, John R.; Walker, Jeffrey J.; McCollom, Thomas M.; Pace, Norman R.

    2005-01-01

    The geochemical energy budgets for high-temperature microbial ecosystems such as occur at Yellowstone National Park have been unclear. To address the relative contributions of different geochemistries to the energy demands of these ecosystems, we draw together three lines of inference. We studied the phylogenetic compositions of high-temperature (>70°C) communities in Yellowstone hot springs with distinct chemistries, conducted parallel chemical analyses, and carried out thermodynamic modeling. Results of extensive molecular analyses, taken with previous results, show that most microbial biomass in these systems, as reflected by rRNA gene abundance, is comprised of organisms of the kinds that derive energy for primary productivity from the oxidation of molecular hydrogen, H2. The apparent dominance by H2-metabolizing organisms indicates that H2 is the main source of energy for primary production in the Yellowstone high-temperature ecosystem. Hydrogen concentrations in the hot springs were measured and found to range up to >300 nM, consistent with this hypothesis. Thermodynamic modeling with environmental concentrations of potential energy sources also is consistent with the proposed microaerophilic, hydrogen-based energy economy for this geothermal ecosystem, even in the presence of high concentrations of sulfide. PMID:15671178

  18. Coaxial rotatory-freestanding triboelectric nanogenerator for effective energy scavenging from wind

    NASA Astrophysics Data System (ADS)

    Ren, Xiaohu; Fan, Huiqing; Wang, Chao; Ma, Jiangwei; Zhao, Nan

    2018-06-01

    Ambient mechanical energy is one of the most abundant energy sources around us. It is a promising approach to solve the problem of energy and environment by harvesting such energy due to its cost-effectiveness, environmental friendliness and sustainability. Recently, triboelectric nanogenerator (TENG) has been proposed as an effective and promising technology for harvesting ambient mechanical energy. Herein, a coaxial rotatory-freestanding TENG (CRF-TENG) was developed and its theoretical model was constructed. An approximate V–Q–α relationship was derived and the explicit analytical solutions of the transferred charge, output current, voltage and average power are obtained from numerically calculation. Finally, to verify the theoretical results, the real output performances of as-fabricated CRF-TENG were measured. The experimental results are consistent with the theoretical ones. The newly developed TENG mode greatly expands the applicability of TENGs for harvesting energy from ambient rotating mechanical motion.

  19. Metagenomic resolution of microbial functions in deep-sea hydrothermal plumes across the Eastern Lau Spreading Center.

    PubMed

    Anantharaman, Karthik; Breier, John A; Dick, Gregory J

    2016-01-01

    Microbial processes within deep-sea hydrothermal plumes affect ocean biogeochemistry on global scales. In rising hydrothermal plumes, a combination of microbial metabolism and particle formation processes initiate the transformation of reduced chemicals like hydrogen sulfide, hydrogen, methane, iron, manganese and ammonia that are abundant in hydrothermal vent fluids. Despite the biogeochemical importance of this rising portion of plumes, it is understudied in comparison to neutrally buoyant plumes. Here we use metagenomics and bioenergetic modeling to describe the abundance and genetic potential of microorganisms in relation to available electron donors in five different hydrothermal plumes and three associated background deep-sea waters from the Eastern Lau Spreading Center located in the Western Pacific Ocean. Three hundred and thirty one distinct genomic 'bins' were identified, comprising an estimated 951 genomes of archaea, bacteria, eukarya and viruses. A significant proportion of these genomes is from novel microorganisms and thus reveals insights into the energy metabolism of heretofore unknown microbial groups. Community-wide analyses of genes encoding enzymes that oxidize inorganic energy sources showed that sulfur oxidation was the most abundant and diverse chemolithotrophic microbial metabolism in the community. Genes for sulfur oxidation were commonly present in genomic bins that also contained genes for oxidation of hydrogen and methane, suggesting metabolic versatility in these microbial groups. The relative diversity and abundance of genes encoding hydrogen oxidation was moderate, whereas that of genes for methane and ammonia oxidation was low in comparison to sulfur oxidation. Bioenergetic-thermodynamic modeling supports the metagenomic analyses, showing that oxidation of elemental sulfur with oxygen is the most dominant catabolic reaction in the hydrothermal plumes. We conclude that the energy metabolism of microbial communities inhabiting rising hydrothermal plumes is dictated by the underlying plume chemistry, with a dominant role for sulfur-based chemolithoautotrophy.

  20. Probing the CO and methanol snow lines in young protostars. Results from the CALYPSO IRAM-PdBI survey

    NASA Astrophysics Data System (ADS)

    Anderl, S.; Maret, S.; Cabrit, S.; Belloche, A.; Maury, A. J.; André, Ph.; Codella, C.; Bacmann, A.; Bontemps, S.; Podio, L.; Gueth, F.; Bergin, E.

    2016-06-01

    Context. So-called snow lines, indicating regions where abundant volatiles freeze out onto the surface of dust grains, play an important role for planet growth and bulk composition in protoplanetary disks. They can already be observed in the envelopes of the much younger, low-mass Class 0 protostars, which are still in their early phase of heavy accretion. Aims: We aim to use the information on the sublimation regions of different kinds of ices to understand the chemistry of the envelope, its temperature and density structure, and the history of the accretion process. This information is crucial to get the full picture of the early protostellar collapse and the subsequent evolution of young protostars. Methods: As part of the CALYPSO IRAM Large Program, we have obtained observations of C18O, N2H+, and CH3OH towards nearby Class 0 protostars with the IRAM Plateau de Bure interferometer at sub-arcsecond resolution. For four of these sources, we have modeled the emission using a chemical code coupled with a radiative transfer module. Results: We observe an anti-correlation of C18O and N2H+ in NGC 1333-IRAS4A, NGC 1333-IRAS4B, L1157, and L1448C, with N2H+ forming a ring (perturbed by the outflow) around the centrally peaked C18O emission. This emission morphology, which is due to N2H+ being chemically destroyed by CO, reveals the CO and N2 ice sublimation regions in these protostellar envelopes with unprecedented resolution. We also observe compact methanol emission towards three of the sources. Based on our chemical model and assuming temperature and density profiles from the literature, we find that for all four sources the CO snow line appears further inwards than expected from the binding energy of pure CO ices (~855 K). The emission regions of models and observations match for a higher value of the CO binding energy of 1200 K, corresponding to a dust temperature of ~24 K at the CO snow line. The binding energy for N2 ices is modeled at 1000 K, also higher than for pure N2 ices. Furthermore, we find very low CO abundances inside the snow lines in our sources, about an order of magnitude lower than the total CO abundance observed in the gas on large scales in molecular clouds before depletion sets in. Conclusions: The high CO binding energy may hint at CO being frozen out in a polar ice environment like amorphous water ice or in non-polar CO2-rich ice. The low CO abundances are comparable to values found in protoplanetary disks, which may indicate an evolutionary scenario where these low values are already established in the protostellar phase. Based on observations carried out under project number U052 with the IRAM Plateau de Bure Interferometer. IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain).

  1. Models of Cosmic-Ray Origin

    NASA Astrophysics Data System (ADS)

    Shapiro, M. M.

    2001-08-01

    Two models of cosmic-ray genesis are compared: (a) the author s red-dwarf hypothesis requiring the injection of seed particles from coronal mass ejections (CME) prior to shock acceleration, and (b) the direct acceleration of thermal ions and of grains in the ISM, proposed by Meyer, Drury and Ellison. Both models agree that shocks in the expanding envelopes of supernova remnants are principally responsible for acceleration to cosmic-ray energies. Both are designed to overcome the mismatch between the source composition of the Galactic cosmic rays (GCR) and the composition of the thermal ISM gas. Model (a) utilizes the prolific emissions of energetic particles from active dMe and dKe stars via their CME as the agents of seed-particle injection into the ISM. The composition of these seed particles is governed by the FIP (first-ionization potential) selection mechanism that operates for both Galactic cosmic rays and solar energetic particles. Hence it is consistent with the cosmic-ray source composition. Model (b) relies on the sputtering and acceleration of grains in the ISM (along with acceleration of thermal ions) to provide the known source composition. This model considers the FIP ordering of GCR abundances as purely coincidental, and it attributes the relative source abundances to selection according to volatility. Recent cosmic-ray observations in favor of each model are cited.

  2. Metabolic effects of dietary sugar beet pulp or wheat bran in growing female pigs.

    PubMed

    Weber, T E; Kerr, B J

    2012-02-01

    An experiment was conducted to determine the effects of feeding a moderate level of 2 different fiber sources on energy metabolites; mitochondrial biogenesis in the intestine, liver, and muscle; and the expression of some genes that regulate energy metabolism in intestine, liver, muscle, and adipose tissue. Female pigs (n = 36; BW = 15.0 ± 0.7 kg) were fed diets containing no added fiber, 12.5% sugar beet pulp (SBP), or 12.5% wheat bran (WB) for 24 d. Blood samples were collected on d 7 and 24 for cholesterol, glucose, NEFA, and triglyceride analyses. At completion of the experiment, ileum, colon, subcutaneous adipose, and LM samples were obtained from a subset (n = 6) of pigs fed each diet for analysis of tissue mitochondrial DNA (mtDNA) content and mRNA abundance by quantitative real-time reverse-transcription PCR. Glycogen and triglyceride content of liver and LM were determined, and colon content VFA was also determined. The addition of SBP or WB to the diet had no effect (P > 0.55) on ADG, ADFI, or G:F. Serum NEFA and triglycerides were increased (P < 0.05) in pigs fed SBP compared with pigs fed the control diet or WB on d 7, and NEFA remained increased (P < 0.05) on d 24 in pigs fed SBP. Dietary fiber had no effect (P > 0.24) on glycogen and triglyceride content of liver or LM, but colonic acetate concentrations were increased (P < 0.05) in pigs fed either SBP or WB. Pigs fed WB had an increased (P < 0.05) mtDNA content in ileum tissue and increased (P < 0.05) citrate synthase mRNA in colon tissue. In the liver, feeding either SBP or WB led to a decrease (P < 0.05) in mtDNA content, whereas feeding WB decreased (P < 0.05) mtDNA abundance in the LM, and feeding either SBP or WB decreased (P < 0.05) expression of citrate synthase mRNA. Quantitative reverse-transcription PCR revealed that feeding WB increased (P < 0.05) proliferating cell nuclear antigen mRNA abundance in the ileum and colon. Feeding WB increased (P < 0.05) mRNA abundance of a regulator of mitochondrial biogenesis, PPAR coactivator 1 α, in ileum tissue, and increased (P < 0.05) mRNA abundance of another mediator of mitochondrial biogensis, sirtuin 1, in colon tissue. Colonic mRNA expression of fasting-induced adipose factor was increased (P < 0.05) in pigs fed either SBP or WB, and adipose triglyceride lipase mRNA abundance was increased (P < 0.05) in adipose tissue of pigs fed SBP. These data indicate that increasing dietary fiber can increase the capacity of the intestine for oxidative metabolism and induce a repartitioning of energy metabolites depending on fiber source.

  3. Geothermal energy program overview

    NASA Astrophysics Data System (ADS)

    1991-12-01

    The mission of the Geothermal Energy Program is to develop the science and technology necessary for tapping our nation's tremendous heat energy sources contained within the Earth. Geothermal energy is a domestic energy source that can produce clean, reliable, cost-effective heat and electricity for our nation's energy needs. Geothermal energy - the heat of the Earth - is one of our nation's most abundant energy resources. In fact, geothermal energy represents nearly 40 percent of the total U.S. energy resource base and already provides an important contribution to our nation's energy needs. Geothermal energy systems can provide clean, reliable, cost-effective energy for our nation's industries, businesses, and homes in the form of heat and electricity. The U.S. Department of Energy's (DOE) Geothermal Energy Program sponsors research aimed at developing the science and technology necessary for utilizing this resource more fully. Geothermal energy originates from the Earth's interior. The hottest fluids and rocks at accessible depths are associated with recent volcanic activity in the western states. In some places, heat comes to the surface as natural hot water or steam, which have been used since prehistoric times for cooking and bathing. Today, wells convey the heat from deep in the Earth to electric generators, factories, farms, and homes. The competitiveness of power generation with lower quality hydrothermal fluids, geopressured brines, hot dry rock, and magma (the four types of geothermal energy), still depends on the technical advancements sought by DOE's Geothermal Energy Program.

  4. The linkage between nutrient supply, intracellular enzyme abundances and bacterial growth: New evidences from the central carbon metabolism of Corynebacterium glutamicum.

    PubMed

    Noack, Stephan; Voges, Raphael; Gätgens, Jochem; Wiechert, Wolfgang

    2017-09-20

    Corynebacterium glutamicum serves as important production host for small molecular compounds that are derived from precursor molecules of the central carbon metabolism. It is therefore a well-studied model organism of industrial biotechnology. However, a deeper understanding of the regulatory principles underlying the synthesis of central metabolic enzymes under different environmental conditions as well as its impact on cell growth is still missing. We studied enzyme abundances in C. glutamicum in response to growth on: (i) one limiting carbon source by sampling chemostat and fed-batch cultivations and (ii) changing carbon sources provided in excess by sampling batch cultivations. The targeted quantification of 20 central metabolic enzymes by isotope dilution mass spectrometry revealed that cells maintain stable enzyme concentrations when grown on d-glucose as single carbon and energy source and, most importantly, independent of its availability. By contrast, switching from d-glucose to d-fructose, d-mannose, d-arabitol, acetate, l-lactate or l-glutamate results in highly specific enzyme regulation patterns that can partly be explained by the activity of known transcriptional regulators. Based on these experimental results we propose a simple framework for modeling cell population growth as a nested function of nutrient supply and intracellular enzyme abundances. In summary, our study extends the basis for the formulation of predictive mechanistic models of bacterial growth, applicable in industrial bioprocess development. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Distribution and Diversity of Rhodopsin-Producing Microbes in the Chesapeake Bay.

    PubMed

    Maresca, Julia A; Miller, Kelsey J; Keffer, Jessica L; Sabanayagam, Chandran R; Campbell, Barbara J

    2018-07-01

    Although sunlight is an abundant source of energy in surface environments, less than 0.5% of the available photons are captured by (bacterio)chlorophyll-dependent photosynthesis in plants and bacteria. Metagenomic data indicate that 30 to 60% of the bacterial genomes in some environments encode rhodopsins, retinal-based photosystems found in heterotrophs, suggesting that sunlight may provide energy for more life than previously suspected. However, quantitative data on the number of cells that produce rhodopsins in environmental systems are limited. Here, we use total internal reflection fluorescence microscopy to show that the number of free-living microbes that produce rhodopsins increases along the salinity gradient in the Chesapeake Bay. We correlate this functional data with environmental data to show that rhodopsin abundance is positively correlated with salinity and with indicators of active heterotrophy during the day. Metagenomic and metatranscriptomic data suggest that the microbial rhodopsins in the low-salinity samples are primarily found in Actinobacteria and Bacteroidetes , while those in the high-salinity samples are associated with SAR-11 type Alphaproteobacteria IMPORTANCE Microbial rhodopsins are common light-activated ion pumps in heterotrophs, and previous work has proposed that heterotrophic microbes use them to conserve energy when organic carbon is limiting. If this hypothesis is correct, rhodopsin-producing cells should be most abundant where nutrients are most limited. Our results indicate that in the Chesapeake Bay, rhodopsin gene abundance is correlated with salinity, and functional rhodopsin production is correlated with nitrate, bacterial production, and chlorophyll a We propose that in this environment, where carbon and nitrogen are likely not limiting, heterotrophs do not need to use rhodopsins to supplement ATP synthesis. Rather, the light-generated proton motive force in nutrient-rich environments could be used to power energy-dependent membrane-associated processes, such as active transport of organic carbon and cofactors, enabling these organisms to more efficiently utilize exudates from primary producers. Copyright © 2018 American Society for Microbiology.

  6. Complex carbohydrates as a possible source of high energy to formulate functional feeds.

    PubMed

    Ochoa, Leonel; Paniagua Michel, José de Jesús; Olmos-Soto, Jorge

    2014-01-01

    Carbohydrates (CHOs) are the most abundant organic compounds found in living organisms and are a great source of metabolic energy, both for plants and animals. Besides of CHOs great potential to solve animal's energy requirements and diminishing high feed cost, we first must to understand its digestibility and assimilation to avoid several inconvenients. Today, CHOs feed animal inclusions are of great concern about cost-benefits, animal's health status, and environmental pollution. In this chapter, we make a brief description about sugars (DP1-2), oligosaccharides (DP3-9), polysaccharides (DP ≥10), and their essential characteristics to understand the role of marine and terrestrial CHOs in animal nutrition. Subsequently, we talk about basic concepts, CHOs functional benefits, suggestions about their application and successful cases. This information will contribute to produce a new generation of high-quality and energetic functional feed formulations for livestock and aquaculture farms; which must be of low cost, healthy, and environmentally friendly, with the inclusion of prebiotics and probiotics. © 2014 Elsevier Inc. All rights reserved.

  7. Best Practices Handbook for the Collection and Use of Solar Resource Data for Solar Energy Applications: Second Edition

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sengupta, Manajit; Habte, Aron; Gueymard, Christian

    As the world looks for low-carbon sources of energy, solar power stands out as the single most abundant energy resource on Earth. Harnessing this energy is the challenge for this century. Photovoltaics, solar heating and cooling, and concentrating solar power (CSP) are primary forms of energy applications using sunlight. These solar energy systems use different technologies, collect different fractions of the solar resource, and have different siting requirements and production capabilities. Reliable information about the solar resource is required for every solar energy application. This holds true for small installations on a rooftop as well as for large solar powermore » plants; however, solar resource information is of particular interest for large installations, because they require substantial investment, sometimes exceeding 1 billion dollars in construction costs. Before such a project is undertaken, the best possible information about the quality and reliability of the fuel source must be made available. That is, project developers need reliable data about the solar resource available at specific locations, including historic trends with seasonal, daily, hourly, and (preferably) subhourly variability to predict the daily and annual performance of a proposed power plant. Without this data, an accurate financial analysis is not possible. Additionally, with the deployment of large amounts of distributed photovoltaics, there is an urgent need to integrate this source of generation to ensure the reliability and stability of the grid. Forecasting generation from the various sources will allow for larger penetrations of these generation sources because utilities and system operators can then ensure stable grid operations. Developed by the foremost experts in the field who have come together under the umbrella of the International Energy Agency's Solar Heating and Cooling Task 46, this handbook summarizes state-of-the-art information about all the above topics.« less

  8. Long-term patterns of fruit production in five forest types of the South Carolina upper coastal plain

    Treesearch

    Cathryn H. Greenberg; Douglas J. Levey; Charles Kwit; John P. McCarty; Scott F. Pearson; Sarah Sargent; John Kilgo

    2012-01-01

    Fleshy fruit is a key food resource for many vertebrates and may be particularly important energy source to birds during fall migration and winter. Hence, land managers should know how fruit availability varies among forest types, seasons, and years. We quantified fleshy fruit abundance monthly for 9 years (1995–2003) in 56 0.1-ha plots in 5 forest types of South...

  9. High Resolution X-ray Spectroscopy and Star Formation: HETG Observations of the Pre-Main Sequence Stellar Cluster IC 348

    NASA Astrophysics Data System (ADS)

    Principe, David; Huenemoerder, David P.; Schulz, Norbert; Kastner, Joel H.; Weintraub, David; Preibisch, Thomas

    2018-01-01

    We present Chandra High Energy Transmission Grating (HETG) observations of the ∼3 Myr old pre-main sequence (pre-MS) stellar cluster IC 348. With 400-500 cluster members at a distance of ∼300 pc, IC 348 is an ideal target to observe a large number of X-ray sources in a single pointing and is thus an extremely efficient use of Chandra-HETG. High resolution X-ray spectroscopy offers a means to investigate detailed spectral characteristic of X-ray emitting plasmas and their surrounding environments. We present preliminary results where we compare X-ray spectral signatures (e.g., luminosity, temperature, column density, abundance) of the X-ray brightest pre-MS stars in IC 348 with spectral type, multiwavelength signatures of accretion, and the presence of circumstellar disks at multiple stages of pre-MS stellar evolution. Assuming all IC 348 members formed from the same primordial molecular cloud, any disparity between coronal abundances of individual members, as constrained by the identification and strength of emission lines, will constrain the source(s) of coronal chemical evolution at a stage of pre-MS evolution vital to the formation of planets.

  10. Non-thermal recombination - a neglected source of flare hard X-rays and fast electron diagnostics (Corrigendum)

    NASA Astrophysics Data System (ADS)

    Brown, J. C.; Mallik, P. C. V.; Badnell, N. R.

    2010-06-01

    Brown and Mallik (BM) recently claimed that non-thermal recombination (NTR) can be a dominant source of flare hard X-rays (HXRs) from hot coronal and chromospheric sources. However, major discrepancies between the thermal continua predicted by BM and by the Chianti database as well as RHESSI flare data, led us to discover substantial errors in the heuristic expression used by BM to extend the Kramers expressions beyond the hydrogenic case. Here we present the relevant corrected expressions and show the key modified results. We conclude that, in most cases, NTR emission was overestimated by a factor of 1-8 by BM but is typically still large enough (as much as 20-30% of the total emission) to be very important for electron spectral inference and detection of electron spectral features such as low energy cut-offs since the recombination spectra contain sharp edges. For extreme temperature regimes and/or if the Fe abundance were as high as some values claimed, NTR could even be the dominant source of flare HXRs, reducing the electron number and energy budget, problems such as in the extreme coronal HXR source cases reported by e.g. Krucker et al.

  11. Constraining Habitable Environments on Mars by Quantifying Available Geochemical Energy

    NASA Astrophysics Data System (ADS)

    Tierney, L. L.; Jakosky, B. M.

    2009-12-01

    The search for life on Mars includes the availability of liquid water, access to biogenic elements and an energy source. In the past, when water was more abundant on Mars, a source of energy may have been the limiting factor for potential life. Energy, either from photosynthesis or chemosynthesis, is required in order to drive metabolism. Potential martian organisms most likely took advantage of chemosynthetic reactions at and below the surface. Terrestrial chemolithoautotrophs, for example, thrive off of chemical disequilibrium that exists in many environments and use inorganic redox (reduction-oxidation) reactions to drive metabolism and create cellular biomass. The chemical disequilibrium of six different martian environments were modeled in this study and analyzed incorporating a range of water and rock compositions, water:rock mass ratios, atmospheric fugacities, pH, and temperatures. All of these models can be applied to specific sites on Mars including environments similar to Meridiani Planum and Gusev Crater. Both a mass transfer geochemical model of groundwater-basalt interaction and a mixing model of groundwater-hydrothermal fluid interaction were used to estimate hypothetical martian fluid compositions that results from mixing over the entire reaction path. By determining the overall Gibbs free energy yields for redox reactions in the H-O-C-S-Fe-Mn system, the amount of geochemical energy that was available for potential chemolithoautotrophic microorganisms was quantified and the amount of biomass that could have been sustained was estimated. The quantity of biomass that can be formed and supported within a system depends on energy availability, thus sites that have higher levels and fluxes of energy have greater potential to support life. Results show that iron- and sulfur-oxidation reactions would have been the most favorable redox reactions in aqueous systems where groundwater and rock interacted at or near the surface. These types of reactions could have supported between 0.05 and 1.0 grams (dry weight) of biomass per mole of iron or sulfur. The hydrothermal environments would have had numerous redox reactions in the H-O-C-S-Fe-Mn system that could have provided sufficient metabolic energy for potential microorganisms. Methanotrophy, for example, provides the greatest amount of energy at ~760 kJ per mole of methane, which is equivalent to 0.6 grams (dry weight) of biomass. Additional results show that varying the amount of CO2 in the martian atmosphere or adjusting the water:rock ratios has little effect on the resulting Gibbs free energies. The martian values that are reported for available free energy in this study are similar to values that have been calculated for terrestrial systems in hydrothermal settings in which life is known to be abundant. In summary, the models indicate that martian aqueous environments were likely to have been habitable at a wide range of conditions when liquid water was more abundant and would have been able to supply a large amount of energy for potential organisms.

  12. The natural food habits of grizzly bears in Yellowstone National Park, 1973-74

    USGS Publications Warehouse

    Mealey, Stephen Patrick

    1980-01-01

     The natural food habits of grizzly bears (Ursus arctos horribilis Ord) in Yellowstone National Park were investigated in 1973-74 to identify the grizzly's energy sources and trophic level(s), nutrient use, and distribution. Food consumption was determined by scat analysis and field observations. Food quality and digestibility were estimated by chemical analysis. Grizzlies were distributed in 3 distinctive feeding economies: valley/plateau, a grass/rodent economy where grizzlies were intensive diggers; mountain, primarily a grass/springbeauty/root economy where grizzlies were casual diggers; and lake, primarily a fish/grass economy where grizzlies were fishers. The economies occured in areas with fertile soils; distribution of bears within each was related to the occurrence of succulent plants. The feeding cycle in the valley/plateau and mountain economies followed plant phenology. Grizzlies fed primarily on meat before green-up and on succulent herbs afterwards; meat, corms, berries, and nuts became important during the postgrowing season. Succulent grasses and sedges with an importance value percentage of 78.5 were the most important food items consumed. Protein from animal tissue was more digestible than protein from plant tissue. Storage fats were more digestible than structural fats. Food energy and digestibility were directly related. Five principle nutrient materials (listed with their percentage digestibilities) contributed to total energy intake: protein from succulent herbs, 42.8; protein and fat from animal material, 78.1; fat and protein from pine nuts, 73.6; starch, 78.8; and sugar from berries and fruits, digestibility undetermined. Protein from succulent herbs, with a nutritive value percentage of 77.3, was the grizzlies' primary energy source. Because succulent, preflowering herbs had higher protein levels than dry, mature herbs, grizzly use of succulent herbs guaranteed them the highest source of herbaceous protein. Low protein digestibility of succulent herbs was compenstated for by high intake. Grizzlies were digestively flexible and maximized use of protein from plant and animal sources. They were adapted to the most constant and abundant sources of protein: succulent herbs and animal material from open, fertile grasslands. Competition among grizzlies for animal food during the pregrowing season may be regulatory for the grizzly population. The grizzly population level can be partially accounted for by the grizzlies' status as secondary consumers during pregreen-up periods and primary consumers during the growing and postgrowing seasons. The essential environmental requirement was the availability of fertile grasslands and herblands interspersed with cover and capable of maintaining artiodactyls, rodents, and abundant nutritious herbs as sources of food.

  13. Mechanical power efficiency of modified turbine blades

    NASA Astrophysics Data System (ADS)

    Mahmud, Syahir; Sampebatu, Limbran; Kwang, Suendy Ciayadi

    2017-01-01

    Abstract-The problem of energy crisis has become one of the unsolved issues until today. Indonesia has a lot of non-conventional energy sources that does not utilized effectively yet. For that the available resources must utilized efficiently due to the energy crisis and the growing energy needs. Among the abundant resources of energy, one potential source of energy is hydroelectric energy. This research compares the mechanical power efficiency generated by the Darrieus turbine, Savonius turbine and the Darrieus-Savonius turbine. The comparation of the mechanical power amongst the three turbine starts from the measurement of the water flow rate, water temperature, turbine rotation and force on the shaft on each type of turbine. The comparison will show the mechanical power efficiency of each turbine to find the most efficient turbine that can work optimally. The results show that with 0.637m/s flow velocity and 44.827 Watt of water flow power, the Darrieus-Savonius turbine can generate power equal to 29.927 Watt and shaft force around by 17 N. The Darrieus-Savonius turbine provides around 66.76% efficiency betwen the three turbines; Darrieus turbine, Savonius turbine and the Darrieus-Savonius turbine. Overall, the Darrieus Savonius turbine has the ability to work optimally at the research location.

  14. Acetylenotrophy: A hidden but ubiquitous microbial metabolism?

    USGS Publications Warehouse

    Akob, Denise M.; Sutton, John M.; Fierst, Janna L.; Haase, Karl B.; Baesman, Shaun; Luther, George; Miller, Laurence G.; Oremland, Ronald S.

    2018-01-01

    Acetylene (IUPAC name: ethyne) is a colorless, gaseous hydrocarbon, composed of two triple bonded carbon atoms attached to hydrogens (C2H2). When microbiologists and biogeochemists think of acetylene, they immediately think of its use as an inhibitory compound of certain microbial processes and a tracer for nitrogen fixation. However, what is less widely known is that anaerobic and aerobic microorganisms can degrade acetylene, using it as a sole carbon and energy source and providing the basis of a microbial food web. Here, we review what is known about acetylene degrading organisms and introduce the term 'acetylenotrophs' to refer to the microorganisms that carry out this metabolic pathway. In addition, we review the known environmental sources of acetylene and postulate the presence of an hidden acetylene cycle. The abundance of bacteria capable of using acetylene and other alkynes as an energy and carbon source suggests that there are energy cycles present in the environment that are driven by acetylene and alkyne production and consumption that are isolated from atmospheric exchange. Acetylenotrophs may have developed to leverage the relatively high concentrations of acetylene in the pre-Cambrian atmosphere, evolving later to survive in specialized niches where acetylene and other alkynes were produced.

  15. Synergistic Microbial Consortium for Bioenergy Generation from Complex Natural Energy Sources

    PubMed Central

    Yam, Joey Kuok Hoong; Chua, Song-Lin; Zhang, Qichun; Cao, Bin; Chye, Joachim Loo Say

    2014-01-01

    Microbial species have evolved diverse mechanisms for utilization of complex carbon sources. Proper combination of targeted species can affect bioenergy production from natural waste products. Here, we established a stable microbial consortium with Escherichia coli and Shewanella oneidensis in microbial fuel cells (MFCs) to produce bioenergy from an abundant natural energy source, in the form of the sarcocarp harvested from coconuts. This component is mostly discarded as waste. However, through its usage as a feedstock for MFCs to produce useful energy in this study, the sarcocarp can be utilized meaningfully. The monospecies S. oneidensis system was able to generate bioenergy in a short experimental time frame while the monospecies E. coli system generated significantly less bioenergy. A combination of E. coli and S. oneidensis in the ratio of 1 : 9 (v : v) significantly enhanced the experimental time frame and magnitude of bioenergy generation. The synergistic effect is suggested to arise from E. coli and S. oneidensis utilizing different nutrients as electron donors and effect of flavins secreted by S. oneidensis. Confocal images confirmed the presence of biofilms and point towards their importance in generating bioenergy in MFCs. PMID:25097866

  16. Analysis of a pico tubular-type hydro turbine performance by runner blade shape using CFD

    NASA Astrophysics Data System (ADS)

    Park, J. H.; Lee, N. J.; Wata, J. V.; Hwang, Y. C.; Kim, Y. T.; Lee, Y. H.

    2012-11-01

    There has been a considerable interest recently in the topic of renewable energy. This is primarily due to concerns about environmental impacts of fossil fuels. Moreover, fluctuating and rising oil prices, increase in demand, supply uncertainties and other factors have led to increased calls for alternative energy sources. Small hydropower, among other renewable energy sources, has been evaluated to have adequate development value because it is a clean, renewable and abundant energy resource. In addition, small hydropower has the advantage of low cost development by using rivers, agricultural reservoirs, sewage treatment plants, waterworks and water resources. The main concept of the tubular-type hydro turbine is based on the difference in water pressure levels in pipe lines, where the energy which was initially wasted by using a reducing valve at the pipeline of waterworks, is collected by turbine in the hydro power generator. In this study, in order to acquire the performance data of a pico tubular-type hydro turbine, the output power, head and efficiency characteristics by different runner blade shapes are examined. The pressure and velocity distributions with the variation of guide vane and runner vane angle on turbine performance are investigated by using a commercial CFD code.

  17. NLTE Model Atmospheres for Super-Soft X-ray Sources

    NASA Astrophysics Data System (ADS)

    Rauch, Thomas; Werner, Klaus

    2009-09-01

    Spectral analysis by means of fully line-blanketed Non-LTE model atmospheres has arrived at a high level of sophistication. The Tübingen NLTE Model Atmosphere Package (TMAP) is used to calculate plane-parallel NLTE model atmospheres which are in radiative and hydrostatic equilibrium. Although TMAP is not especially designed for the calculation of burst spectra of novae, spectral energy distributions (SEDs) calculated from TMAP models are well suited e.g. for abundance determinations of Super Soft X-ray Sources like nova V4743 Sgr or line identifications in observations of neutron stars with low magnetic fields in low-mass X-ray binaries (LMXBs) like EXO 0748-676.

  18. PHYSICS OF OUR DAYS Physical conditions in potential accelerators of ultra-high-energy cosmic rays: updated Hillas plot and radiation-loss constraints

    NASA Astrophysics Data System (ADS)

    Ptitsyna, Kseniya V.; Troitsky, Sergei V.

    2010-10-01

    We review basic constraints on the acceleration of ultra-high-energy (UHE) cosmic rays (CRs) in astrophysical sources, namely, the geometric (Hillas) criterion and the restrictions from radiation losses in different acceleration regimes. Using the latest available astrophysical data, we redraw the Hillas plot and find potential UHECR accelerators. For the acceleration in the central engines of active galactic nuclei, we constrain the maximal UHECR energy for a given black hole mass. Among active galaxies, only the most powerful ones, radio galaxies and blazars, are able to accelerate protons to UHE, although acceleration of heavier nuclei is possible in much more abundant lower-power Seyfert galaxies.

  19. The ISPM experiment for spectral, composition and anistropy measurements of charged particles at low energie

    NASA Technical Reports Server (NTRS)

    Lanzerotti, L. J.; Gold, R. E.; Anderson, K. A.; Armstrong, T. P.; Lin, R. P.; Krimigis, S. M.; Pick, M.; Roelof, E. C.; Sarris, E. T.; Simnett, G. M.

    1983-01-01

    The Heliosphere Instrument for Spectral, Composition, and Anisotropy at Low Energies (HI-SCALE) designed to measure interplanetary ions and electrons is described. Ions and electrons are detected by five separate solid-state detector telescopes oriented to give complete pitch angle coverage from the spinning spacecraft. Ion elemental abundances are determined by a telescope using a thin front detector element in a three-element telescope. Experiment operation is controlled by a microprocessor-based data system. Inflight calibration is provided by radioactive sources mounted on closable telescope covers. Ion and electron spectral information is determined using broad-energy-range rate channels, and a pulse-height analyzer for more detailed spectra. The instrument weighs 5.775 kg and uses 4.0 W power.

  20. Metal-Free Aqueous Flow Battery with Novel Ultrafiltered Lignin as Electrolyte

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mukhopadhyay, Alolika; Hamel, Jonathan; Katahira, Rui

    As the number of generation sources from intermittent renewable technologies on the electric grid increases, the need for large-scale energy storage devices is becoming essential to ensure grid stability. Flow batteries offer numerous advantages over conventional sealed batteries for grid storage. In this work, for the first time, we investigated lignin, the second most abundant wood derived biopolymer, as an anolyte for the aqueous flow battery. Lignosulfonate, a water-soluble derivative of lignin, is environmentally benign, low cost and abundant as it is obtained from the byproduct of paper and biofuel manufacturing. The lignosulfonate utilizes the redox chemistry of quinone tomore » store energy and undergoes a reversible redox reaction. Here, we paired lignosulfonate with Br2/Br-, and the full cell runs efficiently with high power density. Also, the large and complex molecular structure of lignin considerably reduces the electrolytic crossover, which ensures very high capacity retention. The flowcell was able to achieve current densities of up to 20 mA/cm2 and charge polarization resistance of 15 ohm cm2. This technology presents a unique opportunity for a low-cost, metal-free flow battery capable of large-scale sustainable energy storage.« less

  1. A Metastable Equilibrium Model for the Relative Abundances of Microbial Phyla in a Hot Spring

    PubMed Central

    Dick, Jeffrey M.; Shock, Everett L.

    2013-01-01

    Many studies link the compositions of microbial communities to their environments, but the energetics of organism-specific biomass synthesis as a function of geochemical variables have rarely been assessed. We describe a thermodynamic model that integrates geochemical and metagenomic data for biofilms sampled at five sites along a thermal and chemical gradient in the outflow channel of the hot spring known as “Bison Pool” in Yellowstone National Park. The relative abundances of major phyla in individual communities sampled along the outflow channel are modeled by computing metastable equilibrium among model proteins with amino acid compositions derived from metagenomic sequences. Geochemical conditions are represented by temperature and activities of basis species, including pH and oxidation-reduction potential quantified as the activity of dissolved hydrogen. By adjusting the activity of hydrogen, the model can be tuned to closely approximate the relative abundances of the phyla observed in the community profiles generated from BLAST assignments. The findings reveal an inverse relationship between the energy demand to form the proteins at equal thermodynamic activities and the abundance of phyla in the community. The distance from metastable equilibrium of the communities, assessed using an equation derived from energetic considerations that is also consistent with the information-theoretic entropy change, decreases along the outflow channel. Specific divergences from metastable equilibrium, such as an underprediction of the relative abundances of phototrophic organisms at lower temperatures, can be explained by considering additional sources of energy and/or differences in growth efficiency. Although the metabolisms used by many members of these communities are driven by chemical disequilibria, the results support the possibility that higher-level patterns of chemotrophic microbial ecosystems are shaped by metastable equilibrium states that depend on both the composition of biomass and the environmental conditions. PMID:24023738

  2. Ring current dynamics and plasma sheet sources. [magnetic storms

    NASA Technical Reports Server (NTRS)

    Lyons, L. R.

    1984-01-01

    The source of the energized plasma that forms in geomagnetic storm ring currents, and ring current decay are discussed. The dominant loss processes for ring current ions are identified as charge exchange and resonant interactions with ion-cyclotron waves. Ring current ions are not dominated by protons. At L4 and energies below a few tens of keV, O+ is the most abundant ion, He+ is second, and protons are third. The plasma sheet contributes directly or indirectly to the ring current particle population. An important source of plasma sheet ions is earthward streaming ions on the outer boundary of the plasma sheet. Ion interactions with the current across the geomagnetic tail can account for the formation of this boundary layer. Electron interactions with the current sheet are possibly an important source of plasma sheet electrons.

  3. A Molecular Description of Cellulose Biosynthesis

    PubMed Central

    McNamara, Joshua T.; Morgan, Jacob L.W.; Zimmer, Jochen

    2016-01-01

    Cellulose is the most abundant biopolymer on Earth, and certain organisms from bacteria to plants and animals synthesize cellulose as an extracellular polymer for various biological functions. Humans have used cellulose for millennia as a material and an energy source, and the advent of a lignocellulosic fuel industry will elevate it to the primary carbon source for the burgeoning renewable energy sector. Despite the biological and societal importance of cellulose, the molecular mechanism by which it is synthesized is now only beginning to emerge. On the basis of recent advances in structural and molecular biology on bacterial cellulose synthases, we review emerging concepts of how the enzymes polymerize glucose molecules, how the nascent polymer is transported across the plasma membrane, and how bacterial cellulose biosynthesis is regulated during biofilm formation. Additionally, we review evolutionary commonalities and differences between cellulose synthases that modulate the nature of the cellulose product formed. PMID:26034894

  4. The Role of Hydrogen Sulfide in Evolution and the Evolution of Hydrogen Sulfide in Metabolism and Signaling.

    PubMed

    Olson, Kenneth R; Straub, Karl D

    2016-01-01

    The chemical versatility of sulfur and its abundance in the prebiotic Earth as reduced sulfide (H2S) implicate this molecule in the origin of life 3.8 billion years ago and also as a major source of energy in the first seven-eighths of evolution. The tremendous increase in ambient oxygen ∼ 600 million years ago brought an end to H2S as an energy source, and H2S-dependent animals either became extinct, retreated to isolated sulfide niches, or adapted. The first 3 billion years of molecular tinkering were not lost, however, and much of this biochemical armamentarium easily adapted to an oxic environment where it contributes to metabolism and signaling even in humans. This review examines the role of H2S in evolution and the evolution of H2S metabolism and signaling. ©2016 Int. Union Physiol. Sci./Am. Physiol. Soc.

  5. Anomalous Galactic Cosmic Rays in the Framework of AMS-02

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Khiali, Behrouz; Haino, Sadakazu; Feng, Jie, E-mail: behrouz.khiali@cern.ch

    2017-02-01

    The cosmic-ray (CR) energy spectra of protons and helium nuclei, which are the most abundant components of cosmic radiation, exhibit a remarkable hardening at energies above 100 GeV/nucleon. Recent data from AMS-02 confirm this feature with a higher significance. These data challenge the current models of CR acceleration in Galactic sources and propagation in the Galaxy. Here, we explain the observed break in the spectra of protons and helium nuclei in light of recent advances in CR diffusion theories in turbulent astrophysical sources as being a result of a transition between different CR diffusion regimes. We reconstruct the observed CRmore » spectra using the fact that a transition from normal diffusion to superdiffusion changes the efficiency of particle acceleration and causes the change in the spectral index. We find that calculated proton and helium spectra match the data very well.« less

  6. Origin and propagation of galactic cosmic rays

    NASA Technical Reports Server (NTRS)

    Cesarsky, Catherine J.; Ormes, Jonathan F.

    1987-01-01

    The study of systematic trends in elemental abundances is important for unfolding the nuclear and/or atomic effects that should govern the shaping of source abundances and in constraining the parameters of cosmic ray acceleration models. In principle, much can be learned about the large-scale distributions of cosmic rays in the galaxy from all-sky gamma ray surveys such as COS-B and SAS-2. Because of the uncertainties in the matter distribution which come from the inability to measure the abundance of molecular hydrogen, the results are somewhat controversial. The leaky-box model accounts for a surprising amount of the data on heavy nuclei. However, a growing body of data indicates that the simple picture may have to be abandoned in favor of more complex models which contain additional parameters. Future experiments on the Spacelab and space station will hopefully be made of the spectra of individual nuclei at high energy. Antiprotons must be studied in the background free environment above the atmosphere with much higher reliability and presion to obtain spectral information.

  7. Energy Harvesting from the Animal/Human Body for Self-Powered Electronics.

    PubMed

    Dagdeviren, Canan; Li, Zhou; Wang, Zhong Lin

    2017-06-21

    Living subjects (i.e., humans and animals) have abundant sources of energy in chemical, thermal, and mechanical forms. The use of these energies presents a viable way to overcome the battery capacity limitation that constrains the long-term operation of wearable/implantable devices. The intersection of novel materials and fabrication techniques offers boundless possibilities for the benefit of human health and well-being via various types of energy harvesters. This review summarizes the existing approaches that have been demonstrated to harvest energy from the bodies of living subjects for self-powered electronics. We present material choices, device layouts, and operation principles of these energy harvesters with a focus on in vivo applications. We discuss a broad range of energy harvesters placed in or on various body parts of human and animal models. We conclude with an outlook of future research in which the integration of various energy harvesters with advanced electronics can provide a new platform for the development of novel technologies for disease diagnostics, treatment, and prevention.

  8. Full open-framework batteries for stationary energy storage

    NASA Astrophysics Data System (ADS)

    Pasta, Mauro; Wessells, Colin D.; Liu, Nian; Nelson, Johanna; McDowell, Matthew T.; Huggins, Robert A.; Toney, Michael F.; Cui, Yi

    2014-01-01

    New types of energy storage are needed in conjunction with the deployment of renewable energy sources and their integration with the electrical grid. We have recently introduced a family of cathodes involving the reversible insertion of cations into materials with the Prussian Blue open-framework crystal structure. Here we report a newly developed manganese hexacyanomanganate open-framework anode that has the same crystal structure. By combining it with the previously reported copper hexacyanoferrate cathode we demonstrate a safe, fast, inexpensive, long-cycle life aqueous electrolyte battery, which involves the insertion of sodium ions. This high rate, high efficiency cell shows a 96.7% round trip energy efficiency when cycled at a 5C rate and an 84.2% energy efficiency at a 50C rate. There is no measurable capacity loss after 1,000 deep-discharge cycles. Bulk quantities of the electrode materials can be produced by a room temperature chemical synthesis from earth-abundant precursors.

  9. Investigating energy consumption of coastal vacation rental homes

    NASA Astrophysics Data System (ADS)

    Myers, Sam

    In 2007, vacation rental properties in the United States accounted for more than 22% of the domestic lodging market. These properties are a unique segment of the lodging industry due to their residential design and commercial use. Coastal vacation rental properties represent the largest supply, demand and value of the nation's vacation rental supply. In the case of North Carolina's Outer Banks, tourism is the area's largest source of income, with vacation real estate agencies being the largest accommodation provider. This study uses a multiple regression analysis to investigate the energy consumption of 30 vacation rental homes on Hatteras Island. Hatteras Island's abundant supply of vacation rental homes provided a diverse sample to study energy consumption with a wide range of houses regarding size, age, and location. Since very little research has been conducted on the energy consumption of vacation rental homes, this study aims to contribute detailed information regarding the energy consumption of unique accommodation sector.

  10. Full open-framework batteries for stationary energy storage.

    PubMed

    Pasta, Mauro; Wessells, Colin D; Liu, Nian; Nelson, Johanna; McDowell, Matthew T; Huggins, Robert A; Toney, Michael F; Cui, Yi

    2014-01-01

    New types of energy storage are needed in conjunction with the deployment of renewable energy sources and their integration with the electrical grid. We have recently introduced a family of cathodes involving the reversible insertion of cations into materials with the Prussian Blue open-framework crystal structure. Here we report a newly developed manganese hexacyanomanganate open-framework anode that has the same crystal structure. By combining it with the previously reported copper hexacyanoferrate cathode we demonstrate a safe, fast, inexpensive, long-cycle life aqueous electrolyte battery, which involves the insertion of sodium ions. This high rate, high efficiency cell shows a 96.7% round trip energy efficiency when cycled at a 5C rate and an 84.2% energy efficiency at a 50C rate. There is no measurable capacity loss after 1,000 deep-discharge cycles. Bulk quantities of the electrode materials can be produced by a room temperature chemical synthesis from earth-abundant precursors.

  11. Design guidelines of triboelectric nanogenerator for water wave energy harvesters.

    PubMed

    Ahmed, Abdelsalam; Hassan, Islam; Jiang, Tao; Youssef, Khalid; Liu, Lian; Hedaya, Mohammad; Yazid, Taher Abu; Zu, Jean; Wang, Zhong Lin

    2017-05-05

    Ocean waves are one of the cleanest and most abundant energy sources on earth, and wave energy has the potential for future power generation. Triboelectric nanogenerator (TENG) technology has recently been proposed as a promising technology to harvest wave energy. In this paper, a theoretical study is performed on a duck-shaped TENG wave harvester recently introduced in our work. To enhance the design of the duck-shaped TENG wave harvester, the mechanical and electrical characteristics of the harvester's overall structure, as well as its inner configuration, are analyzed, respectively, under different wave conditions, to optimize parameters such as duck radius and mass. Furthermore, a comprehensive hybrid 3D model is introduced to quantify the performance of the TENG wave harvester. Finally, the influence of different TENG parameters is validated by comparing the performance of several existing TENG wave harvesters. This study can be applied as a guideline for enhancing the performance of TENG wave energy harvesters.

  12. Model Predictive Control-based Power take-off Control of an Oscillating Water Column Wave Energy Conversion System

    NASA Astrophysics Data System (ADS)

    Rajapakse, G.; Jayasinghe, S. G.; Fleming, A.; Shahnia, F.

    2017-07-01

    Australia’s extended coastline asserts abundance of wave and tidal power. The predictability of these energy sources and their proximity to cities and towns make them more desirable. Several tidal current turbine and ocean wave energy conversion projects have already been planned in the coastline of southern Australia. Some of these projects use air turbine technology with air driven turbines to harvest the energy from an oscillating water column. This study focuses on the power take-off control of a single stage unidirectional oscillating water column air turbine generator system, and proposes a model predictive control-based speed controller for the generator-turbine assembly. The proposed method is verified with simulation results that show the efficacy of the controller in extracting power from the turbine while maintaining the speed at the desired level.

  13. Sources of sedimentary PAHs in tropical Asian waters: differentiation between pyrogenic and petrogenic sources by alkyl homolog abundance.

    PubMed

    Saha, Mahua; Togo, Ayako; Mizukawa, Kaoruko; Murakami, Michio; Takada, Hideshige; Zakaria, Mohamad P; Chiem, Nguyen H; Tuyen, Bui Cach; Prudente, Maricar; Boonyatumanond, Ruchaya; Sarkar, Santosh Kumar; Bhattacharya, Badal; Mishra, Pravakar; Tana, Touch Seang

    2009-02-01

    We collected surface sediment samples from 174 locations in India, Indonesia, Malaysia, Thailand, Vietnam, Cambodia, Laos, and the Philippines and analyzed them for polycyclic aromatic hydrocarbons (PAHs) and hopanes. PAHs were widely distributed in the sediments, with comparatively higher concentrations in urban areas (Sigma PAHs: approximately 1000 to approximately 100,000 ng/g-dry) than in rural areas ( approximately 10 to approximately 100g-dry), indicating large sources of PAHs in urban areas. To distinguish petrogenic and pyrogenic sources of PAHs, we calculated the ratios of alkyl PAHs to parent PAHs: methylphenanthrenes to phenanthrene (MP/P), methylpyrenes+methylfluoranthenes to pyrene+fluoranthene (MPy/Py), and methylchrysenes+methylbenz[a]anthracenes to chrysene+benz[a]anthracene (MC/C). Analysis of source materials (crude oil, automobile exhaust, and coal and wood combustion products) gave thresholds of MP/P=0.4, MPy/Py=0.5, and MC/C=1.0 for exclusive combustion origin. All the combustion product samples had the ratios of alkyl PAHs to parent PAHs below these threshold values. Contributions of petrogenic and pyrogenic sources to the sedimentary PAHs were uneven among the homologs: the phenanthrene series had a greater petrogenic contribution, whereas the chrysene series had a greater pyrogenic contribution. All the Indian sediments showed a strong pyrogenic signature with MP/P approximately 0.5, MPy/Py approximately 0.1, and MC/C approximately 0.2, together with depletion of hopanes indicating intensive inputs of combustion products of coal and/or wood, probably due to the heavy dependence on these fuels as sources of energy. In contrast, sedimentary PAHs from all other tropical Asian cities were abundant in alkylated PAHs with MP/P approximately 1-4, MPy/Py approximately 0.3-1, and MC/C approximately 0.2-1.0, suggesting a ubiquitous input of petrogenic PAHs. Petrogenic contributions to PAH homologs varied among the countries: largest in Malaysia whereas inferior in Laos. The higher abundance of alkylated PAHs together with constant hopane profiles suggests widespread inputs of automobile-derived petrogenic PAHs to Asian waters.

  14. Methane Provenance Determined by CH2D2 and 13CH3D Abundances

    NASA Astrophysics Data System (ADS)

    Kohl, I. E.; Giunta, T.; Warr, O.; Ash, J. L.; Ruffine, L.; Sherwood Lollar, B.; Young, E. D.

    2017-12-01

    Determining the provenance of naturally occurring methane gases is of major interest to energy companies and atmospheric climate modelers, among others. Bulk isotopic compositions and other geochemical tracers sometimes fail to provide definitive determinations of sources of methane due to complications from mixing and complicated chemical pathways of origin. Recent measurements of doubly-substituted isotopologues of methane, CH2D2 (UCLA) and 13CH3D (UCLA, CalTech, and MIT) have allowed for major improvements in sourcing natural methane gases. Early work has focused on formation temperatures obtained when the relative abundances of both doubly-substituted mass-18 species are consistent with internal equilibrium. When methane gases do not plot on the thermodynamic equilibrium curve in D12CH2D2 vs D13CH3D space, temperatures determined from D13CH3D values alone are usually spurious, even when appearing reasonable. We find that the equilibrium case is actually rare and almost exclusive to thermogenic gases produced at temperatures exceeding 100°C. All other relevant methane production processes appear to generate gases that are not in isotopologue-temperature equilibrium. When gases show departures from equilibrium as determined by the relationship between CH2D2 and 13CH3D abundances, data fall within empirically defined fields representing formation pathways. These fields are thus far consistent between different geological settings and and between lab experiments and natural samples. We have now defined fields for thermogenic gas production, microbial methanogenesis, low temperature abiotic (Sabatier) synthesis and higher temperature FTT synthesis. The majority of our natural methane data can be explained by mixing between end members originating within these production fields. Mixing can appear complex, resulting in both hyper-clumped and anti-clumped isotopologue abundances. In systems where mixtures dominate and end-members are difficult to sample, mixing models can be used to extrapolate end member compositions. Post formation equilibration with time is evident in some cases and is most likely attributable to anaerobic methane oxidation. Large variation in CH2D2 abundances related to quantum tunneling and /or combinatorial effects is a crucial arbiter for methane sources.

  15. Staphylococcus xylosus fermentation of pork fatty waste: raw material for biodiesel production.

    PubMed

    Marques, Roger Vasques; Paz, Matheus Francisco da; Duval, Eduarda Hallal; Corrêa, Luciara Bilhalva; Corrêa, Érico Kunde

    2016-01-01

    The need for cleaner sources of energy has stirred research into utilising alternate fuel sources with favourable emission and sustainability such as biodiesel. However, there are technical constraints that hinder the widespread use of some of the low cost raw materials such as pork fatty wastes. Currently available technology permits the use of lipolytic microorganisms to sustainably produce energy from fat sources; and several microorganisms and their metabolites are being investigated as potential energy sources. Thus, the aim of this study was to characterise the process of Staphylococcus xylosus mediated fermentation of pork fatty waste. We also wanted to explore the possibility of fermentation effecting a modification in the lipid carbon chain to reduce its melting point and thereby act directly on one of the main technical barriers to obtaining biodiesel from this abundant source of lipids. Pork fatty waste was obtained from slaughterhouses in southern Brazil during evisceration of the carcasses and the kidney casing of slaughtered animals was used as feedstock. Fermentation was performed in BHI broth with different concentrations of fatty waste and for different time periods which enabled evaluation of the effect of fermentation time on the melting point of swine fat. The lowest melting point was observed around 46°C, indicating that these chemical and biological reactions can occur under milder conditions, and that such pre-treatment may further facilitate production of biodiesel from fatty animal waste. Copyright © 2016 Sociedade Brasileira de Microbiologia. Published by Elsevier Editora Ltda. All rights reserved.

  16. Production of butyrate from lysine and the Amadori product fructoselysine by a human gut commensal.

    PubMed

    Bui, Thi Phuong Nam; Ritari, Jarmo; Boeren, Sjef; de Waard, Pieter; Plugge, Caroline M; de Vos, Willem M

    2015-12-01

    Human intestinal bacteria produce butyrate, which has signalling properties and can be used as energy source by enterocytes thus influencing colonic health. However, the pathways and the identity of bacteria involved in this process remain unclear. Here we describe the isolation from the human intestine of Intestinimonas strain AF211, a bacterium that can convert lysine stoichiometrically into butyrate and acetate when grown in a synthetic medium. Intestinimonas AF211 also converts the Amadori product fructoselysine, which is abundantly formed in heated foods via the Maillard reaction, into butyrate. The butyrogenic pathway includes a specific CoA transferase that is overproduced during growth on lysine. Bacteria related to Intestinimonas AF211 as well as the genetic coding capacity for fructoselysine conversion are abundantly present in colonic samples from some healthy human subjects. Our results indicate that protein can serve as a source of butyrate in the human colon, and its conversion by Intestinimonas AF211 and related butyrogens may protect the host from the undesired side effects of Amadori reaction products.

  17. Production of butyrate from lysine and the Amadori product fructoselysine by a human gut commensal

    PubMed Central

    Bui, Thi Phuong Nam; Ritari, Jarmo; Boeren, Sjef; de Waard, Pieter; Plugge, Caroline M.; de Vos, Willem M.

    2015-01-01

    Human intestinal bacteria produce butyrate, which has signalling properties and can be used as energy source by enterocytes thus influencing colonic health. However, the pathways and the identity of bacteria involved in this process remain unclear. Here we describe the isolation from the human intestine of Intestinimonas strain AF211, a bacterium that can convert lysine stoichiometrically into butyrate and acetate when grown in a synthetic medium. Intestinimonas AF211 also converts the Amadori product fructoselysine, which is abundantly formed in heated foods via the Maillard reaction, into butyrate. The butyrogenic pathway includes a specific CoA transferase that is overproduced during growth on lysine. Bacteria related to Intestinimonas AF211 as well as the genetic coding capacity for fructoselysine conversion are abundantly present in colonic samples from some healthy human subjects. Our results indicate that protein can serve as a source of butyrate in the human colon, and its conversion by Intestinimonas AF211 and related butyrogens may protect the host from the undesired side effects of Amadori reaction products. PMID:26620920

  18. Bi-Abundance Ionisation Structure of the Wolf-Rayet Planetary Nebula PB 8

    NASA Astrophysics Data System (ADS)

    Danehkar, A.

    2018-01-01

    The planetary nebula PB 8 around a [WN/WC]-hybrid central star is one of planetary nebulae with moderate abundance discrepancy factors (ADFs 2-3), which could be an indication of a tiny fraction of metal-rich inclusions embedded in the nebula (bi-abundance). In this work, we have constructed photoionisation models to reproduce the optical and infrared observations of the planetary nebula PB 8 using a non-LTE stellar model atmosphere ionising source. A chemically homogeneous model initially used cannot predict the optical recombination lines. However, a bi-abundance model provides a better fit to most of the observed optical recombination lines from N and O ions. The metal-rich inclusions in the bi-abundance model occupy 5.6% of the total volume of the nebula, and are roughly 1.7 times cooler and denser than the mean values of the surrounding nebula. The N/H and O/H abundance ratios in the metal-rich inclusions are 1.0 and 1.7 dex larger than the diffuse warm nebula, respectively. To reproduce the Spitzer spectral energy distribution of PB 8, dust grains with a dust-to-gas ratio of 0.01 (by mass) were also included. It is found that the presence of metal-rich inclusions can explain the heavy element optical recombination lines, while a dual-dust chemistry with different grain species and discrete grain sizes likely produces the infrared continuum of this planetary nebula. This study demonstrates that the bi-abundance hypothesis, which was examined in a few planetary nebulae with large abundance discrepancies (ADFs > 10), could also be applied to those typical planetary nebulae with moderate abundance discrepancies.

  19. Room Temperature Sulfur Battery Cathode Design and Processing Techniques

    NASA Astrophysics Data System (ADS)

    Carter, Rachel

    As the population grows and energy demand increases, climate change threatens causing energy storage research to focus on fulfilling the requirements of two major energy sectors with next generation batteries: (1) portable energy and (2) stationary storage.1 Where portable energy can decrease transportation-related harmful emissions and enable advanced next-generation technologies,1 and stationary storage can facilitate widespread deployment of renewable energy sources, alleviating the demand on fossil fuels and lowering emissions. Portable energy can enable zero-emission transportation and can deploy portable power in advanced electronics across fields including medical and defense. Currently fully battery powered cars are limited in driving distance, which is dictated by the energy density and weight of the state-of-the-art Li-ion battery, and similarly advancement of portable electronics is significantly hindered by heavy batteries with short charge lives. In attempt to enable advanced portable energy, significant research is aiming to improve the conventional Li-ion batteries and explore beyond Li-ion battery chemistries with the primary goal of demonstrating higher energy density to enable lighter weight cells with longer battery life. Further, with the inherent intermittency challenges of our most prominent renewable energy sources, wind and solar, discovery of batteries capable of cost effectively and reliably balancing the generation of the renewable energy sources with the real-time energy demand is required for grid scale viability. Stationary storage will provide load leveling to renewable resources by storing excess energy at peak generation and delivering stored excess during periods of lower generation. This application demands highly abundant, low-cost active materials and long-term cycle stability, since infrastructure costs (combined with the renewable) must compete with burning natural gas. Development of a battery with these characteristics will require exploration of chemistries beyond the Li-ion battery for a system consisting of low cost active materials and promising device performance. (Abstract shortened by ProQuest.).

  20. Hydrogen Gas from Serpentinite, Ophiolites and the Modern Ocean Floor as a Source of Green Energy

    NASA Astrophysics Data System (ADS)

    Coveney, R. M.

    2008-12-01

    Hydrogen gas is emitted by springs associated with serpentinites and extensive carbonate deposits in Oman, The Philippines, the USA and other continental locations. The hydrogen springs contain unusually alkaline fluids with pH values between 11 and 12.5. Other workers have described off-ridge submarine springs with comparably alkaline fluid compositions, serpentinite, abundant free hydrogen gas, and associated carbonate edifices such as Lost City on the Atlantis Massif 15 km west of the Mid-Atlantic Ridge (D.S. Kelley and associates, Science 2005). The association of hydrogen gas with ultramafites is a consistent one that has been attributed to a redox couple involving oxidation of divalent iron to the trivalent state during serpentinization, although other possibilities exist. Some of the hydrogen springs on land are widespread. For example in Oman dozens of alkaline springs (Neal and Stanger, EPSL 1983) can be found over thousands of sq km of outcropping ophiolite. While the deposits in Oman and the Philippines are well-known to much of the geochemical community, little interest seems to have been displayed toward either the ophiolitic occurrences or the submarine deposits for energy production. This may be a mistake as the showings because they could lead to an important source of green energy. Widespread skepticism currently exists about hydrogen as a primary energy source. It is commonly said that free hydrogen does not occur on earth and that it is therefore necessary to use other sources of energy to produce hydrogen, obviating the general environmental benefit. However the existence of numerous occurrences of hydrogen gas associated with ophiolites and submarine occurrences of hydrogen suggests the likelihood that natural hydrogen gas may be an important source of clean energy for modern society remaining to be tapped. Calculations in progress should establish whether or not this is likely to be the case.

  1. Isotopic abundance in atom trap trace analysis

    DOEpatents

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  2. Development of a Short-Lived Radioisotope Production Service (SRPS) for CTTC at the University of Alberta SLOWPOKE Reactor Facility

    DTIC Science & Technology

    2004-12-01

    abundance and neutron cross-section of 17~r (the precursor of 171 Er~~limit,tb~’Xi!Y o~_ 171Er that could be produced and delivered to Suf field to about...the radioisotope being produced. Additional factors relate to the irradiation conditions and include the reactor neutron flux and the irradiation...generally be desirable to have single radioisotopic sources with nuclear characteristics (e.g., half-life, gamma-ray energies and emission rates

  3. R-process Element Cosmic Rays from Neutron Star Mergers

    NASA Astrophysics Data System (ADS)

    Komiya, Yutaka; Shigeyama, Toshikazu

    2017-09-01

    Neutron star mergers (NSMs) are one of the most plausible sources of r-process elements in the universe. Therefore, NSMs can also be a major source of ultra-heavy elements in cosmic rays. In this paper, we first estimate the contribution of r-process elements synthesized in NSMs to the ultra-heavy element cosmic rays (UHCRs) by calculating transport equations that take into account energy loss processes and spallations. We show that the flux of UHCRs accelerated by the NSMs themselves fluctuates by many orders of magnitude on a timescale of several million years and can overwhelm UHCRs accelerated by supernova remnants (SNRs) after an NSM takes place within a few kiloparsec from the solar system. Experiments with very long exposure times using meteorites as UHCR detectors can detect this fluctuation. As a consequence, we show that if NSMs are the primary source of UHCRs, future experiments using meteorites may be able to reveal the event history of NSMs in the solar vicinity. We also describe a possible difference in the abundance pattern and energy spectrum of UHCRs between NSM and SNR accelerations.

  4. Utilization of rapeseed pellet from fatty acid methyl esters production as an energy source.

    PubMed

    Ciunel, Krzysztof; Klugmann-Radziemska, Ewa

    2014-01-01

    Rapeseed pellet - crushed seed residue from oil extraction is a by-product of fatty acid methyl esters production process. As other types of biomass, it can either be burned directly in furnaces or processed to increase its energetic value. Biomass is renewable, abundant and has domestic usage; the sources ofbiomass can help the world reduce its dependence on petroleum products, fossil coal and natural gas. Energetically effective utilization of rapeseed pellet could substantially improve the economic balance of an individual household in which biodiesel for fulfilling the producer's own energetic demand is obtained. In this article, the experimental results of combusting rapeseed pellet in a calorimeter, combustion in a boiler heater and the analysis of the emissions level of different pollutants in exhaust fumes during different stages of biomass boiler operation are presented. It has been proved that the pellet, a by-product of biodiesel production, is not only a valuable substitute of animal fodder, but also an excellent renewable and environmentally friendly energy source, viable for use in household tap water heating installations.

  5. R -process Element Cosmic Rays from Neutron Star Mergers

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Komiya, Yutaka; Shigeyama, Toshikazu

    Neutron star mergers (NSMs) are one of the most plausible sources of r -process elements in the universe. Therefore, NSMs can also be a major source of ultra-heavy elements in cosmic rays. In this paper, we first estimate the contribution of r -process elements synthesized in NSMs to the ultra-heavy element cosmic rays (UHCRs) by calculating transport equations that take into account energy loss processes and spallations. We show that the flux of UHCRs accelerated by the NSMs themselves fluctuates by many orders of magnitude on a timescale of several million years and can overwhelm UHCRs accelerated by supernova remnantsmore » (SNRs) after an NSM takes place within a few kiloparsec from the solar system. Experiments with very long exposure times using meteorites as UHCR detectors can detect this fluctuation. As a consequence, we show that if NSMs are the primary source of UHCRs, future experiments using meteorites may be able to reveal the event history of NSMs in the solar vicinity. We also describe a possible difference in the abundance pattern and energy spectrum of UHCRs between NSM and SNR accelerations.« less

  6. A new measurement of the flux of the light cosmic-ray nuclei at high energies

    NASA Technical Reports Server (NTRS)

    Buckley, J.; Dwyer, J.; Mueller, D.; Swordy, S.; Tang, K. K.

    1994-01-01

    A new cosmic-ray detector utilizing a ring-imaging Cerenkov counter to determine the energy of light cosmic-ray nuclei was flown on high-altitude balloon from Fort Sumner, NM, in 1991 September. We describe the design and performance of this instrument and discuss the data analysis procedures. The measurement provides a new determination of the absolute flux and differential energy spectrum of the primary cosmic-ray species helium between 40 and 320 GeV/nucleon. The experiment also yields the spectra of carbon and oxygen and some information on the intensities of the secondary nuclei Li, Be, and B. A comparison between our results and previous measurements of heavier nuclei (Z greater than or equal to 4) from HEAO 3 and Spacelab 2 indicates good consistency between these measurements. The data set is compared with the results of a leaky box propagation model. We find good agreement with this model if the abundance of helium relative to oxygen at the source is taken to be 25 +/- 6 and if the source spectrum is given by a power law in energy proportional to E(exp -2.15).

  7. Cross-Section Measurements of the Kr86(γ,n) Reaction to Probe the s-Process Branching at Kr85

    NASA Astrophysics Data System (ADS)

    Raut, R.; Tonchev, A. P.; Rusev, G.; Tornow, W.; Iliadis, C.; Lugaro, M.; Buntain, J.; Goriely, S.; Kelley, J. H.; Schwengner, R.; Banu, A.; Tsoneva, N.

    2013-09-01

    We have carried out photodisintegration cross-section measurements on Kr86 using monoenergetic photon beams ranging from the neutron separation energy, Sn=9.86MeV, to 13 MeV. We combine our experimental Kr86(γ,n)Kr85 cross section with results from our recent Kr86(γ,γ') measurement below the neutron separation energy to obtain the complete nuclear dipole response of Kr86. The new experimental information is used to predict the neutron capture cross section of Kr85, an important branching point nucleus on the abundance flow path during s-process nucleosynthesis. Our new and more precise Kr85(n,γ)Kr86 cross section allows us to produce more precise predictions of the Kr86 abundance from s-process models. In particular, we find that the models of the s process in asymptotic giant branch stars of mass <1.5M⊙, where the C13 neutron source burns convectively rather than radiatively, represent a possible solution for the highest Kr86∶Kr82 ratios observed in meteoritic stardust SiC grains.

  8. Cross-section measurements of the 86Kr(γ,n) reaction to probe the s-process branching at 85Kr.

    PubMed

    Raut, R; Tonchev, A P; Rusev, G; Tornow, W; Iliadis, C; Lugaro, M; Buntain, J; Goriely, S; Kelley, J H; Schwengner, R; Banu, A; Tsoneva, N

    2013-09-13

    We have carried out photodisintegration cross-section measurements on 86Kr using monoenergetic photon beams ranging from the neutron separation energy, S(n) = 9.86  MeV, to 13 MeV. We combine our experimental 86Kr(γ,n)85Kr cross section with results from our recent 86Kr(γ,γ') measurement below the neutron separation energy to obtain the complete nuclear dipole response of 86Kr. The new experimental information is used to predict the neutron capture cross section of 85Kr, an important branching point nucleus on the abundance flow path during s-process nucleosynthesis. Our new and more precise 85Kr(n,γ)86Kr cross section allows us to produce more precise predictions of the 86Kr abundance from s-process models. In particular, we find that the models of the s process in asymptotic giant branch stars of mass <1.5M⊙, where the 13C neutron source burns convectively rather than radiatively, represent a possible solution for the highest 86Kr:82Kr ratios observed in meteoritic stardust SiC grains.

  9. A balloon measurement of the isotopic composition of galactic cosmic ray boron, carbon and nitrogen. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Zumberge, J. F.

    1981-01-01

    The isotopic compositions of galactic cosmic ray boron, carbon, and nitrogen were measured at energies near 300 MeV amu, using a balloon-borne instrument at an atmospheric depth of approximately 5 g/sq cm. The calibrations of the detectors comprising the instrument are described. The saturation properties of the cesium iodide scintillators used for measurement of particle energy are studied in the context of analyzing the data for mass. The achieved rms mass resolution varies from approximately 0.3 amu at boron to approximately 0.5 amu at nitrogen, consistent with a theoretical analysis of the contributing factors. Corrected for detector interactions and the effects of the residual atmosphere the results are B-10/B=0.33 (+0.17, -0.11), C-13/C=0.06 (+0.13, -0.11), and N-15/N=0.42 (+0.19, -0.17). A model of galactic propagation and solar modulation is described. Assuming a cosmic ray source composition of solar-like isotopic abundances, the model predicts abundances near Earth consistent with the measurements.

  10. Commercial Bee Pollen with Different Geographical Origins: A Comprehensive Approach

    PubMed Central

    Nogueira, Carla; Iglesias, Antonio; Feás, Xesus; Estevinho, Leticia M.

    2012-01-01

    Since the primordial of humanity, pollen has been considered a good source of nutrients and energy. Its promising healing properties have also been referred to. The present study aimed to characterize, for the first time, eight commercial pollens from Portugal and Spain available on the market studying the legislation on labeling, pollinic origin, physicochemical and microbiological analyses and identification of yeasts. Eleven botanical families were found amongst the samples. The most abundant family and the most dominant pollen was Cistaceae. The moisture content, ash, aw, pH, reducing sugars, carbohydrates, proteins, lipids and energy were analyzed and the specific parameters were within the specifications required by some countries with legislation regarding these parameters. Microbiologically commercial pollen showed acceptable safety for the commercial quality and hygiene. All samples showed negative results for toxigenic species. The microorganisms studied were aerobic mesophiles, yeasts and moulds, coliforms, Escherichia coli, Staphylococcus aureus, Salmonella and sulfite-reducing Clostridium. During the work, six yeasts species were isolated from pollen, with Rhodotorula mucilaginosa being the most abundant, as it was present in four samples. PMID:23109845

  11. Environmentally-benign conversion of biomass residues to electricity

    NASA Astrophysics Data System (ADS)

    Davies, Andrew

    As petroleum resources are finite, it is imperative to use them wisely in energy conversion applications and, at the same time, develop alternative energy sources. Biomass is one of the renewable energy sources that can be used to partially replace fossil fuels. Biomass-based fuels can be produced domestically and can reduce dependency on fuel imports. Due to their abundant supply, and given that to an appreciable extent they can be considered carbon-neutral, their use for power generation is of technological interest. However, whereas biomasses can be directly burned in furnaces, such a conventional direct combustion technique is ill-controlled and typically produces considerable amounts of health-hazardous airborne compounds [1,2]. Thus, an alternative technology for biomass utilization is described herein to address increasing energy needs in an environmentally-benign manner. More specifically, a multi-step process/device is presented to accept granulated or pelletized biomass, and generate an easily-identifiable form of energy as a final product. To achieve low emissions of products of incomplete combustion, the biomass is gasified pyrolytically, mixed with air, ignited and, finally, burned in nominally premixed low-emission flames. Combustion is thus indirect, since the biomass is not directly burned, instead its gaseous pyrolyzates are burned upon mixing with air. Thereby, combustion is well-controlled and can be complete. A demonstration device has been constructed to convert the internal energy of plastics into "clean" thermal energy and, eventually to electricity.

  12. Metagenomic Assembly of the Dominant Zetaproteobacteria in an Iron-oxidizing Hydrothermal Microbial Mat

    NASA Astrophysics Data System (ADS)

    Moyer, C. L.; Fullerton, H.

    2013-12-01

    Iron is the fourth most abundant element in the Earth's crust and is potentially one of the most abundant energy sources on the earth as an electron donor for chemolithoautotrophic growth coupled to Fe(II) oxidation. Despite the rapid abiotic oxidation rate of iron, many microbes have adapted to feeding off this fleeting energy source. One such bacterial class is the Zetaproteobacteria. Iron-dominated microbial mat material was collected with a small-scale syringe sampler from Loihi Seamount, Hawaii. From this sample, gDNA was extracted and prepared for paired-end Illumina sequencing. Reconstruction of SSU rDNA genes using EMERGE allowed for comparison to previous SSU rDNA surveys. Clone libraries and qPCR show these microbial mats to be dominated by Zetaproteobacteria. Results from our in silico reconstruction confirm these initial findings. RDP classification of the EMERGE reconstructed sequences resulted in 44% of the community being identified as Zetaproteobacteria. The most abundant SSU rDNA has 99% similarity to Zeta OTU-2, and only a 94% similarity to M. ferrooxidans PV-1. Zeta OTU-2 has been shown to be the most cosmopolitan population in iron-dominated hydrothermal systems from across Pacific Ocean. Metagenomic assembly has resulted in many contigs with high identity to M. ferrooxidans as identified, by BLAST. However, with large differences in SSU rRNA similarity, M. ferrooxidans PV-1 is not an adequate reference. Current work is focusing on reconstruction of the dominant microbial mat member, without the use of a reference genome through an iterative assembly approach. The resulting 'pan-genome' will be compared to other Zetaproteobacteria (at the class level) and the functional ecology of this cosmopolitan microbial mat community member will be extrapolated. Thus far, we have detected multiple housekeeping genes involved in DNA replication, transcription and translation. The most abundant metabolic gene we have found is Aconitase, a key enzyme in the TCA cycle. The presence of Molybdopterin oxidoreductase, ferric uptake regulation protein, cytochromes, thioredoxin, RuBisCo and other TCA related genes support our hypothesis of chemoautotrophic primary production with the notion that Zetaproteobacteria act as ecosystem engineers driving microbial mat formation and maintenance of their habitat.

  13. Renewable energy scenario in India: Opportunities and challenges

    NASA Astrophysics Data System (ADS)

    Sen, Souvik; Ganguly, Sourav; Das, Ayanangshu; Sen, Joyjeet; Dey, Sourav

    2016-10-01

    Majority of the power generation in India is carried out by conventional energy sources, coal and fossil fuels being the primary ones, which contribute heavily to greenhouse gas emission and global warming. The Indian power sector is witnessing a revolution as excitement grips the nation about harnessing electricity from various renewable energy sources. Electricity generation from renewable sources is increasingly recognized to play an important role for the achievement of a variety of primary and secondary energy policy goals, such as improved diversity and security of energy supply, reduction of local pollutant and global greenhouse gas emissions, regional and rural development, and exploitation of opportunities for fostering social cohesion, value addition and employment generation at the local and regional level. This focuses the solution of the energy crisis on judicious utilization of abundant the renewable energy resources, such as biomass, solar, wind, geothermal and ocean tidal energy. This paper reviews the renewable energy scenario of India as well as extrapolates the future developments keeping in view the consumption, production and supply of power. Research, development, production and demonstration have been carried out enthusiastically in India to find a feasible solution to the perennial problem of power shortage for the past three decades. India has obtained application of a variety of renewable energy technologies for use in different sectors too. There are ample opportunities with favorable geology and geography with huge customer base and widening gap between demand and supply. Technological advancement, suitable regulatory policies, tax rebates, efficiency improvement in consequence to R&D efforts are the few pathways to energy and environment conservation and it will ensure that these large, clean resource bases are exploited as quickly and cost effectively as possible. This paper gives an overview of the potential renewable energy resources in Indian context while evaluating the present status, the energy demand of the country and forecast consumption and production, with the objective to evaluate and assess whether India can sustain its growth and its society with renewable resources.

  14. Silicon to iron abundances in solar cosmic rays and in the sun

    NASA Technical Reports Server (NTRS)

    Vahia, M. N.; Biswas, S.; Durgaprasad, N.

    1985-01-01

    Differential spectra of even charged nuclei between Si and Fe in the August 4, 1972 event were made in the energy region of 10 to 40 MeV/n-1 using rocket borne plastic detectors. The resulting relative abundances of elements and low energy enhancements are obtained and compared with spectroscopically determined photospheric abundances. The implications of the relative abundances on the acceleration mechanisms is discussed.

  15. Electrifying Alaska

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Reinemer, V.

    Alaska's diverse systems for electric power include only 4% by private utilities. Large distances and small markets make transmission impractical for the most part. Rates are variable, although the state average is low. Energy sources, except nuclear, are abundant: half the US coal reserves are in Alaska. In addition, it has geothermal, tidal, biomass, solar, wind, and hydroelectric power. Energy construction and study programs are centered in the Alaska Power Authority and include using waste heat from village diesel generators. Hydro potential is good, but access, distances, and environmental effects must be considered. The Terror Lake, Tyee Lake, Swan Lake,more » and Susitna projects are described and transmission construction, including the 345-kW Railbelt intertie, is discussed. 1 figure.« less

  16. One-Dimensional Metal-Oxide Nanostructures for Solar Photocatalytic Water-Splitting

    NASA Astrophysics Data System (ADS)

    Wang, Fengyun; Song, Longfei; Zhang, Hongchao; Luo, Linqu; Wang, Dong; Tang, Jie

    2017-08-01

    Because of their unique physical and chemical properties, one-dimensional (1-D) metal-oxide nanostructures have been extensively applied in the areas of gas sensors, electrochromic devices, nanogenerators, and so on. Solar water-splitting has attracted extensive research interest because hydrogen generated from solar-driven water splitting is a clean, sustainable, and abundant energy source that not only solves the energy crisis, but also protects the environment. In this comprehensive review, the main synthesis methods, properties, and especially prominent applications in solar water splitting of 1-D metal-oxides, including titanium dioxide (TiO2), zinc oxide (ZnO), tungsten trioxide (WO3), iron oxide (Fe2O3), and copper oxide (CuO) are fully discussed.

  17. Spallative production of Li, Be and B in superbubbles

    NASA Astrophysics Data System (ADS)

    Parizot, Etienne

    We investigate the spallative production of the light elements (Li, Be and B) associated with the evolution of a superbubble (SB) blown by repeated supernova explosions in an OB association. It is shown that if about ten percent of the SN energy can power the acceleration of particles from the material inside the SB, the observed abundances of LiBeB in halo stars, as a function of O, can be explained in a fully consistent way over several decades of metallicity. We investigate two different energy spectra for the EPs: the standard cosmic ray source spectrum and a specific `SB spectrum' as results from Bykov's SB acceleration mechanism. We find that the latter spectrum is more efficient in producing LiBeB, and that the SNR spectrum can be reconciled with the observational data if an imperfect mixing of the SN ejecta with the rest of the SB material and/or a selective acceleration is invoked (enhancing the C and O abundance amongst the EPs by a factor of ˜ 6). One consequence of the model is that the observed linear growth of Be and B abundances as a function of the metallicity expresses a dilution line rather than a continuous, monotonic increase throughout the Galaxy. We also find that the recent 6 Li observations in halo stars fit equally well in the framework of the SB model (see Parizot & Drury, 1999c, for more details).

  18. Just Say No to Carbon Emissions (LBNL Science at the Theater)

    ScienceCinema

    Ramesh, Ramamoorthy; Zhou, Nan; Oldenburg, Curt

    2018-06-15

    Learn about three efforts our grandchildren may thank us for: cheap solar energy, bringing energy efficiency to China, and learning how to store carbon deep underground. Can solar energy be dirt cheap? We're all potentially billionaires when it comes to solar energy. The trick is learning how to convert sunlight to electricity using cheap and plentiful materials. Ramamoorthy Ramesh, an innovative materials scientist at Berkeley Lab, will discuss how he and other researchers are working to make photovoltaic cells using the most abundant elements in the Earth's crust -- materials that are literally as common as dirt. Energy efficiency in China: Nan Zhou is a researcher with Berkeley Labs China Energy Group. She will speak about Chinas energy use and the policies that have been implemented to increase energy efficiency and reduce CO2 emission growth. Her work focuses on building China's capacity to evaluate, adopt and implement low-carbon development strategies. Zhou has an architecture degree from China, and a Master and Ph.D. in Engineering from Japan. Understanding geologic carbon sequestration: Even with continued growth of renewable energy sources such as wind and solar, fossil fuels will likely remain cheap and plentiful for decades to come. Geologist Curt Oldenburg, who heads Berkeley Lab's Geologic Carbon Sequestration Program, will discuss a strategy to reduce carbon emissions from coal and natural gas. It involves pumping compressed CO2 captured from large stationary sources into underground rock formations that can store it for geological time scales.

  19. Just Say No to Carbon Emissions (LBNL Science at the Theater)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ramesh, Ramamoorthy; Zhou, Nan; Oldenburg, Curt

    2010-04-26

    Learn about three efforts our grandchildren may thank us for: cheap solar energy, bringing energy efficiency to China, and learning how to store carbon deep underground. Can solar energy be dirt cheap? We're all potentially billionaires when it comes to solar energy. The trick is learning how to convert sunlight to electricity using cheap and plentiful materials. Ramamoorthy Ramesh, an innovative materials scientist at Berkeley Lab, will discuss how he and other researchers are working to make photovoltaic cells using the most abundant elements in the Earth's crust -- materials that are literally as common as dirt. Energy efficiency inmore » China: Nan Zhou is a researcher with Berkeley Labs China Energy Group. She will speak about Chinas energy use and the policies that have been implemented to increase energy efficiency and reduce CO2 emission growth. Her work focuses on building China's capacity to evaluate, adopt and implement low-carbon development strategies. Zhou has an architecture degree from China, and a Master and Ph.D. in Engineering from Japan. Understanding geologic carbon sequestration: Even with continued growth of renewable energy sources such as wind and solar, fossil fuels will likely remain cheap and plentiful for decades to come. Geologist Curt Oldenburg, who heads Berkeley Lab's Geologic Carbon Sequestration Program, will discuss a strategy to reduce carbon emissions from coal and natural gas. It involves pumping compressed CO2 captured from large stationary sources into underground rock formations that can store it for geological time scales.« less

  20. Timeframe Dependent Fragment Ions Observed in In-Source Decay Experiments with β-Casein Using MALDI MS.

    PubMed

    Sekiya, Sadanori; Nagoshi, Keishiro; Iwamoto, Shinichi; Tanaka, Koichi; Takayama, Mitsuo

    2015-09-01

    The fragment ions observed with time-of-flight (TOF) and quadrupole ion trap (QIT) TOF mass spectrometers (MS) combined with matrix-assisted laser desorption/ionization in-source decay (MALDI-ISD) experiments of phosphorylated analytes β-casein and its model peptide were compared from the standpoint of the residence timeframe of analyte and fragment ions in the MALDI ion source and QIT cell. The QIT-TOF MS gave fragment c-, z'-, z-ANL, y-, and b-ions, and further degraded fragments originating from the loss of neutrals such as H(2)O, NH(3), CH(2)O (from serine), C2H4O (from threonine), and H(3)PO(4), whereas the TOF MS merely showed MALDI source-generated fragment c-, z'-, z-ANL, y-, and w-ions. The fragment ions observed in the QIT-TOF MS could be explained by the injection of the source-generated ions into the QIT cell or a cooperative effect of a little internal energy deposition, a long residence timeframe (140 ms) in the QIT cell, and specific amino acid effects on low-energy CID, whereas the source-generated fragments (c-, z'-, z-ANL, y-, and w-ions) could be a result of prompt radical-initiated fragmentation of hydrogen-abundant radical ions [M + H + H](+) and [M + H - H](-) within the 53 ns timeframe, which corresponds to the delayed extraction time. The further degraded fragment b/y-ions produced in the QIT cell were confirmed by positive- and negative-ion low-energy CID experiments performed on the source-generated ions (c-, z'-, and y-ions). The loss of phosphoric acid (98 u) from analyte and fragment ions can be explained by a slow ergodic fragmentation independent of positive and negative charges.

  1. Timeframe Dependent Fragment Ions Observed in In-Source Decay Experiments with β-Casein Using MALDI MS

    NASA Astrophysics Data System (ADS)

    Sekiya, Sadanori; Nagoshi, Keishiro; Iwamoto, Shinichi; Tanaka, Koichi; Takayama, Mitsuo

    2015-09-01

    The fragment ions observed with time-of-flight (TOF) and quadrupole ion trap (QIT) TOF mass spectrometers (MS) combined with matrix-assisted laser desorption/ionization in-source decay (MALDI-ISD) experiments of phosphorylated analytes β-casein and its model peptide were compared from the standpoint of the residence timeframe of analyte and fragment ions in the MALDI ion source and QIT cell. The QIT-TOF MS gave fragment c-, z'-, z-ANL, y-, and b-ions, and further degraded fragments originating from the loss of neutrals such as H2O, NH3, CH2O (from serine), C2H4O (from threonine), and H3PO4, whereas the TOF MS merely showed MALDI source-generated fragment c-, z'-, z-ANL, y-, and w-ions. The fragment ions observed in the QIT-TOF MS could be explained by the injection of the source-generated ions into the QIT cell or a cooperative effect of a little internal energy deposition, a long residence timeframe (140 ms) in the QIT cell, and specific amino acid effects on low-energy CID, whereas the source-generated fragments (c-, z'-, z-ANL, y-, and w-ions) could be a result of prompt radical-initiated fragmentation of hydrogen-abundant radical ions [M + H + H]+ and [M + H - H]- within the 53 ns timeframe, which corresponds to the delayed extraction time. The further degraded fragment b/y-ions produced in the QIT cell were confirmed by positive- and negative-ion low-energy CID experiments performed on the source-generated ions (c-, z'-, and y-ions). The loss of phosphoric acid (98 u) from analyte and fragment ions can be explained by a slow ergodic fragmentation independent of positive and negative charges.

  2. Innovative thermal energy harvesting for future autonomous applications

    NASA Astrophysics Data System (ADS)

    Monfray, Stephane

    2013-12-01

    As communicating autonomous systems market is booming, the role of energy harvesting will be a key enabler. As example, heat is one of the most abundant energy sources that can be converted into electricity in order to power circuits. Harvesting systems that use wasted heat open new ways to power autonomous sensors when the energy consumption is low, or to create systems of power generators when the conversion efficiency is high. The combination of different technologies (low power μ-processors, μ-batteries, radio, sensors...) with new energy harvesters compatible with large varieties of use-cases with allow to address this booming market. Thanks to the conjunction of ultra-low power electronic development, 3D technologies & Systems in Package approaches, the integration of autonomous sensors and electronics with ambient energy harvesting will be achievable. The applications are very wide, from environment and industrial sensors to medical portable applications, and the Internet of things may also represent in the future a several billions units market.

  3. Metagenomic resolution of microbial functions in deep-sea hydrothermal plumes across the Eastern Lau Spreading Center

    PubMed Central

    Anantharaman, Karthik; Breier, John A; Dick, Gregory J

    2016-01-01

    Microbial processes within deep-sea hydrothermal plumes affect ocean biogeochemistry on global scales. In rising hydrothermal plumes, a combination of microbial metabolism and particle formation processes initiate the transformation of reduced chemicals like hydrogen sulfide, hydrogen, methane, iron, manganese and ammonia that are abundant in hydrothermal vent fluids. Despite the biogeochemical importance of this rising portion of plumes, it is understudied in comparison to neutrally buoyant plumes. Here we use metagenomics and bioenergetic modeling to describe the abundance and genetic potential of microorganisms in relation to available electron donors in five different hydrothermal plumes and three associated background deep-sea waters from the Eastern Lau Spreading Center located in the Western Pacific Ocean. Three hundred and thirty one distinct genomic ‘bins' were identified, comprising an estimated 951 genomes of archaea, bacteria, eukarya and viruses. A significant proportion of these genomes is from novel microorganisms and thus reveals insights into the energy metabolism of heretofore unknown microbial groups. Community-wide analyses of genes encoding enzymes that oxidize inorganic energy sources showed that sulfur oxidation was the most abundant and diverse chemolithotrophic microbial metabolism in the community. Genes for sulfur oxidation were commonly present in genomic bins that also contained genes for oxidation of hydrogen and methane, suggesting metabolic versatility in these microbial groups. The relative diversity and abundance of genes encoding hydrogen oxidation was moderate, whereas that of genes for methane and ammonia oxidation was low in comparison to sulfur oxidation. Bioenergetic-thermodynamic modeling supports the metagenomic analyses, showing that oxidation of elemental sulfur with oxygen is the most dominant catabolic reaction in the hydrothermal plumes. We conclude that the energy metabolism of microbial communities inhabiting rising hydrothermal plumes is dictated by the underlying plume chemistry, with a dominant role for sulfur-based chemolithoautotrophy. PMID:26046257

  4. Electron impact ionization of size selected hydrogen clusters (H2)N: ion fragment and neutral size distributions.

    PubMed

    Kornilov, Oleg; Toennies, J Peter

    2008-05-21

    Clusters consisting of normal H2 molecules, produced in a free jet expansion, are size selected by diffraction from a transmission nanograting prior to electron impact ionization. For each neutral cluster (H2)(N) (N=2-40), the relative intensities of the ion fragments Hn+ are measured with a mass spectrometer. H3+ is found to be the most abundant fragment up to N=17. With a further increase in N, the abundances of H3+, H5+, H7+, and H9+ first increase and, after passing through a maximum, approach each other. At N=40, they are about the same and more than a factor of 2 and 3 larger than for H11+ and H13+, respectively. For a given neutral cluster size, the intensities of the ion fragments follow a Poisson distribution. The fragmentation probabilities are used to determine the neutral cluster size distribution produced in the expansion at a source temperature of 30.1 K and a source pressure of 1.50 bar. The distribution shows no clear evidence of a magic number N=13 as predicted by theory and found in experiments with pure para-H2 clusters. The ion fragment distributions are also used to extract information on the internal energy distribution of the H3+ ions produced in the reaction H2+ + H2-->H3+ +H, which is initiated upon ionization of the cluster. The internal energy is assumed to be rapidly equilibrated and to determine the number of molecules subsequently evaporated. The internal energy distribution found in this way is in good agreement with data obtained in an earlier independent merged beam scattering experiment.

  5. Energy density and variability in abundance of pigeon guillemot prey: Support for the quality-variability trade-off hypothesis

    USGS Publications Warehouse

    Litzow, Michael A.; Piatt, John F.; Abookire, Alisa A.; Robards, Martin D.

    2004-01-01

    1. The quality-variability trade-off hypothesis predicts that (i) energy density (kJ g-1) and spatial-temporal variability in abundance are positively correlated in nearshore marine fishes; and (ii) prey selection by a nearshore piscivore, the pigeon guillemot (Cepphus columba Pallas), is negatively affected by variability in abundance. 2. We tested these predictions with data from a 4-year study that measured fish abundance with beach seines and pigeon guillemot prey utilization with visual identification of chick meals. 3. The first prediction was supported. Pearson's correlation showed that fishes with higher energy density were more variable on seasonal (r = 0.71) and annual (r = 0.66) time scales. Higher energy density fishes were also more abundant overall (r = 0.85) and more patchy at a scale of 10s of km (r = 0.77). 4. Prey utilization by pigeon guillemots was strongly non-random. Relative preference, defined as the difference between log-ratio transformed proportions of individual prey taxa in chick diets and beach seine catches, was significantly different from zero for seven of the eight main prey categories. 5. The second prediction was also supported. We used principal component analysis (PCA) to summarize variability in correlated prey characteristics (energy density, availability and variability in abundance). Two PCA scores explained 32% of observed variability in pigeon guillemot prey utilization. Seasonal variability in abundance was negatively weighted by these PCA scores, providing evidence of risk-averse selection. Prey availability, energy density and km-scale variability in abundance were positively weighted. 6. Trophic interactions are known to create variability in resource distribution in other systems. We propose that links between resource quality and the strength of trophic interactions may produce resource quality-variability trade-offs.

  6. Recyclable organic solar cells on cellulose nanocrystal substrates

    PubMed Central

    Zhou, Yinhua; Fuentes-Hernandez, Canek; Khan, Talha M.; Liu, Jen-Chieh; Hsu, James; Shim, Jae Won; Dindar, Amir; Youngblood, Jeffrey P.; Moon, Robert J.; Kippelen, Bernard

    2013-01-01

    Solar energy is potentially the largest source of renewable energy at our disposal, but significant advances are required to make photovoltaic technologies economically viable and, from a life-cycle perspective, environmentally friendly, and consequently scalable. Cellulose nanomaterials are emerging high-value nanoparticles extracted from plants that are abundant, renewable, and sustainable. Here, we report on the first demonstration of efficient polymer solar cells fabricated on optically transparent cellulose nanocrystal (CNC) substrates. The solar cells fabricated on the CNC substrates display good rectification in the dark and reach a power conversion efficiency of 2.7%. In addition, we demonstrate that these solar cells can be easily separated and recycled into their major components using low-energy processes at room temperature, opening the door for a truly recyclable solar cell technology. Efficient and easily recyclable organic solar cells on CNC substrates are expected to be an attractive technology for sustainable, scalable, and environmentally-friendly energy production. PMID:23524333

  7. Recyclable organic solar cells on cellulose nanocrystal substrates.

    PubMed

    Zhou, Yinhua; Fuentes-Hernandez, Canek; Khan, Talha M; Liu, Jen-Chieh; Hsu, James; Shim, Jae Won; Dindar, Amir; Youngblood, Jeffrey P; Moon, Robert J; Kippelen, Bernard

    2013-01-01

    Solar energy is potentially the largest source of renewable energy at our disposal, but significant advances are required to make photovoltaic technologies economically viable and, from a life-cycle perspective, environmentally friendly, and consequently scalable. Cellulose nanomaterials are emerging high-value nanoparticles extracted from plants that are abundant, renewable, and sustainable. Here, we report on the first demonstration of efficient polymer solar cells fabricated on optically transparent cellulose nanocrystal (CNC) substrates. The solar cells fabricated on the CNC substrates display good rectification in the dark and reach a power conversion efficiency of 2.7%. In addition, we demonstrate that these solar cells can be easily separated and recycled into their major components using low-energy processes at room temperature, opening the door for a truly recyclable solar cell technology. Efficient and easily recyclable organic solar cells on CNC substrates are expected to be an attractive technology for sustainable, scalable, and environmentally-friendly energy production.

  8. Iron-Air Rechargeable Battery: A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    2010-10-01

    GRIDS Project: USC is developing an iron-air rechargeable battery for large-scale energy storage that could help integrate renewable energy sources into the electric grid. Iron-air batteries have the potential to store large amounts of energy at low cost—iron is inexpensive and abundant, while oxygen is freely obtained from the air we breathe. However, current iron-air battery technologies have suffered from low efficiency and short life spans. USC is working to dramatically increase the efficiency of the battery by placing chemical additives on the battery’s iron-based electrode and restructuring the catalysts at the molecular level on the battery’s air-based electrode. Thismore » can help the battery resist degradation and increase life span. The goal of the project is to develop a prototype iron-air battery at significantly cost lower than today’s best commercial batteries.« less

  9. Coupled Triboelectric Nanogenerator Networks for Efficient Water Wave Energy Harvesting.

    PubMed

    Xu, Liang; Jiang, Tao; Lin, Pei; Shao, Jia Jia; He, Chuan; Zhong, Wei; Chen, Xiang Yu; Wang, Zhong Lin

    2018-02-27

    Water wave energy is a promising clean energy source, which is abundant but hard to scavenge economically. Triboelectric nanogenerator (TENG) networks provide an effective approach toward massive harvesting of water wave energy in oceans. In this work, a coupling design in TENG networks for such purposes is reported. The charge output of the rationally linked units is over 10 times of that without linkage. TENG networks of three different connecting methods are fabricated and show better performance for the ones with flexible connections. The network is based on an optimized ball-shell structured TENG unit with high responsivity to small agitations. The dynamic behavior of single and multiple TENG units is also investigated comprehensively to fully understand their performance in water. The study shows that a rational design on the linkage among the units could be an effective strategy for TENG clusters to operate collaboratively for reaching a higher performance.

  10. Basic Research Needs for Solar Energy Utilization. Report of the Basic Energy Sciences Workshop on Solar Energy Utilization, April 18-21, 2005

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lewis, N. S.; Crabtree, G.; Nozik, A. J.

    2005-04-21

    World demand for energy is projected to more than double by 2050 and to more than triple by the end of the century. Incremental improvements in existing energy networks will not be adequate to supply this demand in a sustainable way. Finding sufficient supplies of clean energy for the future is one of society?s most daunting challenges. Sunlight provides by far the largest of all carbon-neutral energy sources. More energy from sunlight strikes the Earth in one hour (4.3 ? 1020 J) than all the energy consumed on the planet in a year (4.1 ? 1020 J). We currently exploitmore » this solar resource through solar electricity ? a $7.5 billion industry growing at a rate of 35?40% per annum ? and solar-derived fuel from biomass, which provides the primary energy source for over a billion people. Yet, in 2001, solar electricity provided less than 0.1% of the world's electricity, and solar fuel from modern (sustainable) biomass provided less than 1.5% of the world's energy. The huge gap between our present use of solar energy and its enormous undeveloped potential defines a grand challenge in energy research. Sunlight is a compelling solution to our need for clean, abundant sources of energy in the future. It is readily available, secure from geopolitical tension, and poses no threat to our environment through pollution or to our climate through greenhouse gases. This report of the Basic Energy Sciences Workshop on Solar Energy Utilization identifies the key scientific challenges and research directions that will enable efficient and economic use of the solar resource to provide a significant fraction of global primary energy by the mid 21st century. The report reflects the collective output of the workshop attendees, which included 200 scientists representing academia, national laboratories, and industry in the United States and abroad, and the U.S. Department of Energy?s Office of Basic Energy Sciences and Office of Energy Efficiency and Renewable Energy.« less

  11. The onset of energetic particle irradiation in Class 0 protostars

    NASA Astrophysics Data System (ADS)

    Favre, C.; López-Sepulcre, A.; Ceccarelli, C.; Dominik, C.; Caselli, P.; Caux, E.; Fuente, A.; Kama, M.; Le Bourlot, J.; Lefloch, B.; Lis, D.; Montmerle, T.; Padovani, M.; Vastel, C.

    2017-12-01

    Context. The early stages of low-mass star formation are likely to be subject to intense ionization by protostellar energetic MeV particles. As a result, the surrounding gas is enriched in molecular ions, such as HCO+ and N2H+. Nonetheless, this phenomenon remains poorly understood for Class 0 objects. Recently, based on Herschel observations taken as part of the key programme Chemical HErschel Surveys of Star forming regions (CHESS), a very low HCO+/N2H+ abundance ratio of about three to four, has been reported towards the protocluster OMC-2 FIR4. This finding suggests a cosmic-ray ionization rate in excess of 10-14 s-1, much higher than the canonical value of ζ = 3 × 10-17 s-1 (value expected in quiescent dense clouds). Aims: We aim to assess the specificity of OMC-2 FIR4, we have extended this study to a sample of sources in low- and intermediate mass. More specifically, we seek to measure the HCO+/N2H+ abundance ratio from high energy lines (J ≥ 6) towards this source sample in order to infer the flux of energetic particles in the warm and dense gas surrounding the protostars. Methods: We have used observations performed with the Heterodyne Instrument for the Far-Infrared spectrometer on board the Herschel Space Observatory towards a sample of nine protostars. Results: We report HCO+/N2H+ abundance ratios in the range of five up to 73 towards our source sample. The large error bars do not allow us to conclude whether OMC-2 FIR4 is a peculiar source. Nonetheless, an important result is that the measured HCO+/N2H+ ratio does not vary with the source luminosity. At the present time, OMC-2 FIR4 remains the only source where a high flux of energetic particles is clearly evident. More sensitive and higher angular resolution observations are required to further investigate this process. Herschel is an ESA space observatory with science instruments provided by European-led principal investigator consortia and with important participation from NASA.

  12. Networks of triboelectric nanogenerators for harvesting water wave energy: a potential approach toward blue energy.

    PubMed

    Chen, Jun; Yang, Jin; Li, Zhaoling; Fan, Xing; Zi, Yunlong; Jing, Qingshen; Guo, Hengyu; Wen, Zhen; Pradel, Ken C; Niu, Simiao; Wang, Zhong Lin

    2015-03-24

    With 70% of the earth's surface covered with water, wave energy is abundant and has the potential to be one of the most environmentally benign forms of electric energy. However, owing to lack of effective technology, water wave energy harvesting is almost unexplored as an energy source. Here, we report a network design made of triboelectric nanogenerators (TENGs) for large-scale harvesting of kinetic water energy. Relying on surface charging effect between the conventional polymers and very thin layer of metal as electrodes for each TENG, the TENG networks (TENG-NW) that naturally float on the water surface convert the slow, random, and high-force oscillatory wave energy into electricity. On the basis of the measured output of a single TENG, the TENG-NW is expected to give an average power output of 1.15 MW from 1 km(2) surface area. Given the compelling features, such as being lightweight, extremely cost-effective, environmentally friendly, easily implemented, and capable of floating on the water surface, the TENG-NW renders an innovative and effective approach toward large-scale blue energy harvesting from the ocean.

  13. Energy minimization strategies and renewable energy utilization for desalination: a review.

    PubMed

    Subramani, Arun; Badruzzaman, Mohammad; Oppenheimer, Joan; Jacangelo, Joseph G

    2011-02-01

    Energy is a significant cost in the economics of desalinating waters, but water scarcity is driving the rapid expansion in global installed capacity of desalination facilities. Conventional fossil fuels have been utilized as their main energy source, but recent concerns over greenhouse gas (GHG) emissions have promoted global development and implementation of energy minimization strategies and cleaner energy supplies. In this paper, a comprehensive review of energy minimization strategies for membrane-based desalination processes and utilization of lower GHG emission renewable energy resources is presented. The review covers the utilization of energy efficient design, high efficiency pumping, energy recovery devices, advanced membrane materials (nanocomposite, nanotube, and biomimetic), innovative technologies (forward osmosis, ion concentration polarization, and capacitive deionization), and renewable energy resources (solar, wind, and geothermal). Utilization of energy efficient design combined with high efficiency pumping and energy recovery devices have proven effective in full-scale applications. Integration of advanced membrane materials and innovative technologies for desalination show promise but lack long-term operational data. Implementation of renewable energy resources depends upon geography-specific abundance, a feasible means of handling renewable energy power intermittency, and solving technological and economic scale-up and permitting issues. Copyright © 2011 Elsevier Ltd. All rights reserved.

  14. The Two Sources of Solar Energetic Particles

    NASA Astrophysics Data System (ADS)

    Reames, Donald V.

    2013-06-01

    Evidence for two different physical mechanisms for acceleration of solar energetic particles (SEPs) arose 50 years ago with radio observations of type III bursts, produced by outward streaming electrons, and type II bursts from coronal and interplanetary shock waves. Since that time we have found that the former are related to "impulsive" SEP events from impulsive flares or jets. Here, resonant stochastic acceleration, related to magnetic reconnection involving open field lines, produces not only electrons but 1000-fold enhancements of 3He/4He and of ( Z>50)/O. Alternatively, in "gradual" SEP events, shock waves, driven out from the Sun by coronal mass ejections (CMEs), more democratically sample ion abundances that are even used to measure the coronal abundances of the elements. Gradual events produce by far the highest SEP intensities near Earth. Sometimes residual impulsive suprathermal ions contribute to the seed population for shock acceleration, complicating the abundance picture, but this process has now been modeled theoretically. Initially, impulsive events define a point source on the Sun, selectively filling few magnetic flux tubes, while gradual events show extensive acceleration that can fill half of the inner heliosphere, beginning when the shock reaches ˜2 solar radii. Shock acceleration occurs as ions are scattered back and forth across the shock by resonant Alfvén waves amplified by the accelerated protons themselves as they stream away. These waves also can produce a streaming-limited maximum SEP intensity and plateau region upstream of the shock. Behind the shock lies the large expanse of the "reservoir", a spatially extensive trapped volume of uniform SEP intensities with invariant energy-spectral shapes where overall intensities decrease with time as the enclosing "magnetic bottle" expands adiabatically. These reservoirs now explain the slow intensity decrease that defines gradual events and was once erroneously attributed solely to slow outward diffusion of the particles. At times the reservoir from one event can contribute its abundances and even its spectra as a seed population for acceleration by a second CME-driven shock wave. Confinement of particles to magnetic flux tubes that thread their source early in events is balanced at late times by slow velocity-dependent migration through a tangled network produced by field-line random walk that is probed by SEPs from both impulsive and gradual events and even by anomalous cosmic rays from the outer heliosphere. As a practical consequence, high-energy protons from gradual SEP events can be a significant radiation hazard to astronauts and equipment in space and to the passengers of high-altitude aircraft flying polar routes.

  15. Materials for Sustainable Energy

    NASA Astrophysics Data System (ADS)

    Crabtree, George

    2009-03-01

    The global dependence on fossil fuels for energy is among the greatest challenges facing our economic, social and political future. The uncertainty in the cost and supply of oil threatens the global economy and energy security, the pollution of fossil combustion threatens human health, and the emission of greenhouse gases threatens global climate. Meeting the demand for double the current global energy use in the next 50 years without damaging our economy, security, environment or climate requires finding alternative sources of energy that are clean, abundant, accessible and sustainable. The transition to greater sustainability involves tapping unused energy flows such as sunlight and wind, producing electricity without carbon emissions from clean coal and high efficiency nuclear power plants, and using energy more efficiently in solid-state lighting, fuel cells and transportation based on plug-in hybrid and electric cars. Achieving these goals requires creating materials of increasing complexity and functionality to control the transformation of energy between light, electrons and chemical bonds. Challenges and opportunities for developing the complex materials and controlling the chemical changes that enable greater sustainability will be presented.

  16. A High-Energy Technology Demonstration Platfom: The First Step in a Stepping Stones Approach to Energy-Rich Space Infrastructures

    NASA Technical Reports Server (NTRS)

    Carrington, Connie; Day, Greg

    2004-01-01

    The sun provides an abundant source of energy in space, which can be used to power exploration vehicles and infrastructures that support exploration. A first step in developing and demonstrating the necessary technologies to support solar-powered exploration could be a 100-kWe-class solar-powered platform in Earth orbit. This platform would utilize advanced technologies in solar power collection and generation, power management and distribution, thermal management, and electric propulsion. It would also provide a power-rich free-flying platform to demonstrate in space a portfolio of technology flight experiments. This paper presents a preliminary design concept for a 100-kWe solar-powered satellite with the capability to use high-powered electric propulsion, and to flight-demonstrate a variety of payload experiments.

  17. Fundamental Pathways for the Adsorption and Transport of Hydrogen on TiO2 Surfaces: Origin for Effective Sensing at about Room Temperature.

    PubMed

    Wang, Zhuo; Xia, Xiaohong; Guo, Meilan; Shao, Guosheng

    2016-12-28

    Effective detection of hydrogen at lowered temperature is highly desirable in promoting safety in using this abundant gas as a clean energy source. Through first-principle calculations in the framework of density functional theory, we find that the high-energy (002) surface for rutile TiO 2 is significantly more effective in adsorbing hydrogen atoms through dissociating hydrogen molecules. The pathways for the dissociation of hydrogen molecules and sequential migration of hydrogen atoms are identified through searching along various transitional states. Pathways of low potential barriers indicate promise for hydrogen sensing, even close to room temperature. This has been proven through sensors made of thin films of well-aligned rutile nanorods, wherein the high-energy (002) surface dictates the top surface of the active layer of the sensors.

  18. Planetary and satellite x ray spectroscopy: A new window on solid-body composition by remote sensing

    NASA Technical Reports Server (NTRS)

    Chenette, D. L.; Wolcott, R. W.; Selesnick, R. S.

    1993-01-01

    The rings and most of the satellites of the outer planets orbit within the radiation belts of their parent bodies. This is an environment with intense fluxes of energetic electrons. As a result, these objects are strong emitters of X-rays. The characteristic X-ray lines from these bodies depend on atomic composition, but they are not sensitive to how the material is arranged in compounds or mixtures. X-ray fluorescence spectral analysis has demonstrated its unique value in the laboratory as a qualitative and quantitative analysis tool. This technique has yet to be fully exploited in a planetary instrument for remote sensing. The characteristic X-ray emissions provide atomic relative abundances. These results are complementary to the molecular composition information obtained from IR, visible, and UV emission spectra. The atomic relative abundances are crucial to understanding the formation and evolution of these bodies. They are also crucial to the proper interpretation of the molecular composition results from the other sensors. The intensities of the characteristic X-ray emissions are sufficiently strong to be measured with an instrument of modest size. Recent developments in X-ray detector technologies and electronic miniaturization have made possible space-flight X-ray imaging and nonimaging spectrometers of high sensitivity and excellent energy resolution that are rugged enough to survive long-duration space missions. Depending on the application, such instruments are capable of resolving elemental abundances of elements from carbon through iron. At the same time, by measuring the bremsstrahlung intensity and energy spectrum, the characteristics of the source electron flux can be determined. We will discuss these concepts, including estimated source strengths, and will describe a small instrument capable of providing this unique channel of information for future planetary missions. We propose to build this instrument using innovative electronics packaging methods to minimize size and weight.

  19. How Close We Are to Achieving Commercially Viable Large-Scale Photobiological Hydrogen Production by Cyanobacteria: A Review of the Biological Aspects

    PubMed Central

    Sakurai, Hidehiro; Masukawa, Hajime; Kitashima, Masaharu; Inoue, Kazuhito

    2015-01-01

    Photobiological production of H2 by cyanobacteria is considered to be an ideal source of renewable energy because the inputs, water and sunlight, are abundant. The products of photobiological systems are H2 and O2; the H2 can be used as the energy source of fuel cells, etc., which generate electricity at high efficiencies and minimal pollution, as the waste product is H2O. Overall, production of commercially viable algal fuels in any form, including biomass and biodiesel, is challenging, and the very few systems that are operational have yet to be evaluated. In this paper we will: briefly review some of the necessary conditions for economical production, summarize the reports of photobiological H2 production by cyanobacteria, present our schemes for future production, and discuss the necessity for further progress in the research needed to achieve commercially viable large-scale H2 production. PMID:25793279

  20. Fe/O ratio behavior as an indicator of solar plasma state at different solar activity manifestations and in periods of their absence

    NASA Astrophysics Data System (ADS)

    Minasyants, Gennady; Minasyants, Tamara; Tomozov, Vladimir

    2018-03-01

    We report the results of the investigation into plasma physical characteristics at various solar activity manifestations and in periods of their absence. These results have been obtained from quantitative estimates of the relative abundance of Fe/O ions in different energy ranges. Maximum values of the Fe/O ratio is shown to correspond to particle fluxes from impulsive flares for ions with energies <2 MeV/n (the most significant manifestation of the FIP effect). In particle fluxes from gradual flares, the Fe/O value decreases smoothly with ion energy and is noticeably inferior to values of fluxes in impulsive events. We have established that the properties of flares of solar cosmic rays indicate their belonging to a separate subclass in the total population of gradual events. Relying on variations in the abundance of Fe/O ions, we propose an explanation of the solar plasma behavior during the development of flares of both classes. Magnetic clouds (a separate type of coronal mass ejections (CME)), which have regions of turbulent compression and are sources of strong geomagnetic storms, exhibit a relative composition of Fe ions comparable to the abundance of Fe in ion fluxes from gradual flares. We have found out that the Fe/O value can be used to detect penetration of energetic flare plasma into the CME body at the initial phase of their joint development and to estimate its relative contribution. During solar minimum with the complete absence of sunspots, the Fe/O ratio during periods of "quiet" solar wind show absolutely low values of Fe/O=0.004-0.010 in the energy range from 2-5 to 30 MeV/n. This is associated with the manifestation of the cosmic ray anomalous component, which causes an increase in the intensity of ion fluxes with a high first ionization potential, including oxygen (O), and elements with a low first ionization potential (Fe) demonstrate the weakening of the fluxes. As for particles with higher energies (Ek>30 MeV/n), the Fe/O increase is due to the decisive influence of galactic cosmic rays on the composition of impurity elements in the solar wind under solar minimum conditions. The relative content of heavy elements in galactic cosmic rays 30-500 MeV/n is similar to values in fluxes from gradual flares during high solar activity. During solar minimum without sunspots, the behavior of Fe/O for different ion energy ranges in plasma flows from coronal holes (CH) and in the solar wind exhibits only minor deviations. At the same time, plasma flows associated with the disturbed frontal CH region can be sources of moderate geomagnetic storms.

  1. Design guidelines of triboelectric nanogenerator for water wave energy harvesters

    NASA Astrophysics Data System (ADS)

    Ahmed, Abdelsalam; Hassan, Islam; Jiang, Tao; Youssef, Khalid; Liu, Lian; Hedaya, Mohammad; Abu Yazid, Taher; Zu, Jean; Wang, Zhong Lin

    2017-05-01

    Ocean waves are one of the cleanest and most abundant energy sources on earth, and wave energy has the potential for future power generation. Triboelectric nanogenerator (TENG) technology has recently been proposed as a promising technology to harvest wave energy. In this paper, a theoretical study is performed on a duck-shaped TENG wave harvester recently introduced in our work. To enhance the design of the duck-shaped TENG wave harvester, the mechanical and electrical characteristics of the harvester’s overall structure, as well as its inner configuration, are analyzed, respectively, under different wave conditions, to optimize parameters such as duck radius and mass. Furthermore, a comprehensive hybrid 3D model is introduced to quantify the performance of the TENG wave harvester. Finally, the influence of different TENG parameters is validated by comparing the performance of several existing TENG wave harvesters. This study can be applied as a guideline for enhancing the performance of TENG wave energy harvesters.

  2. Activation measurement of the 3He(alpha,gamma)7Be cross section at low energy.

    PubMed

    Bemmerer, D; Confortola, F; Costantini, H; Formicola, A; Gyürky, Gy; Bonetti, R; Broggini, C; Corvisiero, P; Elekes, Z; Fülöp, Zs; Gervino, G; Guglielmetti, A; Gustavino, C; Imbriani, G; Junker, M; Laubenstein, M; Lemut, A; Limata, B; Lozza, V; Marta, M; Menegazzo, R; Prati, P; Roca, V; Rolfs, C; Alvarez, C Rossi; Somorjai, E; Straniero, O; Strieder, F; Terrasi, F; Trautvetter, H P

    2006-09-22

    The nuclear physics input from the 3He(alpha,gamma)7Be cross section is a major uncertainty in the fluxes of 7Be and 8B neutrinos from the Sun predicted by solar models and in the 7Li abundance obtained in big-bang nucleosynthesis calculations. The present work reports on a new precision experiment using the activation technique at energies directly relevant to big-bang nucleosynthesis. Previously such low energies had been reached experimentally only by the prompt-gamma technique and with inferior precision. Using a windowless gas target, high beam intensity, and low background gamma-counting facilities, the 3He(alpha,gamma)7Be cross section has been determined at 127, 148, and 169 keV center-of-mass energy with a total uncertainty of 4%. The sources of systematic uncertainty are discussed in detail. The present data can be used in big-bang nucleosynthesis calculations and to constrain the extrapolation of the 3He(alpha,gamma)7Be astrophysical S factor to solar energies.

  3. Micro/Nanostructured Materials for Sodium Ion Batteries and Capacitors.

    PubMed

    Li, Feng; Zhou, Zhen

    2018-02-01

    High-efficiency energy storage technologies and devices have received considerable attention due to their ever-increasing demand. Na-related energy storage systems, sodium ion batteries (SIBs) and sodium ion capacitors (SICs), are regarded as promising candidates for large-scale energy storage because of the abundant sources and low cost of sodium. In the last decade, many efforts, including structural and compositional optimization, effective modification of available materials, and design and exploration of new materials, have been made to promote the development of Na-related energy storage systems. In this Review, the latest developments of micro/nanostructured electrode materials for advanced SIBs and SICs, especially the rational design of unique composites with high thermodynamic stabilities and fast kinetics during charge/discharge, are summarized. In addition to the recent achievements, the remaining challenges with respect to fundamental investigations and commercialized applications are discussed in detail. Finally, the prospects of sodium-based energy storage systems are also described. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Crest: A Balloon-borne Instrument to Measure Cosmic-ray Electrons above TeV Energies

    NASA Astrophysics Data System (ADS)

    Nutter, S.; Anderson, T.; Coutu, S.; Geske, M.; Bower, C.; Musser, J.; Muller, D.; Park, N.; Wakely, S.; Schubnell, M.; Tarle, G.; Yagi, A.

    2009-05-01

    The flux of high-energy (>1 TeV) electrons provides information about the spatial distribution and abundance of nearby cosmic ray sources. CREST, a balloon-borne array of 1024 BaF2 crystals viewed by PMTs, will measure the spectrum of multi-TeV electrons through detection of the x-ray synchrotron photons generated as the electrons traverse the Earth's magnetic field. This method naturally discriminates against the proton and gamma ray backgrounds, and achieves very large detector apertures, since the instrument need only intersect a portion of the kilometers-long line of photons and not the electron itself. Thus CREST's acceptance is several times its geometric area up to energies of 50 TeV, ˜10 times higher in energy than ground based techniques can reach. This measurement will overlap the recent HESS results and extend to higher energies. CREST is scheduled to fly in a long duration circumpolar orbit over Antarctica in 2010. An overview of the detector design and status will be presented.

  5. Global map of solar power production efficiency, considering micro climate factors

    NASA Astrophysics Data System (ADS)

    Hassanpour Adeh, E.; Higgins, C. W.

    2017-12-01

    Natural resources degradation and greenhouse gas emissions are creating a global crisis. Renewable energy is the most reliable option to mitigate this environmental dilemma. Abundancy of solar energy makes it highly attractive source of electricity. The existing global spatial maps of available solar energy are created with various models which consider the irradiation, latitude, cloud cover, elevation, shading and aerosols, and neglect the influence of local meteorological conditions. In this research, the influences of microclimatological variables on solar energy productivity were investigated with an in-field study at the Rabbit Hills solar arrays near Oregon State University. The local studies were extended to a global level, where global maps of solar power were produced, taking the micro climate variables into account. These variables included: temperature, relative humidity, wind speed, wind direction, solar radiation. The energy balance approach was used to synthesize the data and compute the efficiencies. The results confirmed that the solar power efficiency can be directly affected by the air temperature and wind speed.

  6. Measurements of the properties of solar wind plasma relevant to studies of its coronal sources

    NASA Technical Reports Server (NTRS)

    Neugebauer, M.

    1982-01-01

    Interplanetary measurements of the speeds, densities, abundances, and charge states of solar wind ions are diagnostic of conditions in the source region of the solar wind. The absolute values of the mass, momentum, and energy fluxes in the solar wind are not known to an accuracy of 20%. The principal limitations on the absolute accuracies of observations of solar wind protons and alpha particles arise from uncertain instrument calibrations, from the methods used to reduce the data, and from sampling biases. Sampling biases are very important in studies of alpha particles. Instrumental resolution and measurement ambiguities are additional major problems for the observation of ions heavier than helium. Progress in overcoming some of these measurement inadequacies is reviewed.

  7. Carbon dioxide hydrogenation to aromatic hydrocarbons by using an iron/iron oxide nanocatalyst.

    PubMed

    Wang, Hongwang; Hodgson, Jim; Shrestha, Tej B; Thapa, Prem S; Moore, David; Wu, Xiaorong; Ikenberry, Myles; Troyer, Deryl L; Wang, Donghai; Hohn, Keith L; Bossmann, Stefan H

    2014-01-01

    The quest for renewable and cleaner energy sources to meet the rapid population and economic growth is more urgent than ever before. Being the most abundant carbon source in the atmosphere of Earth, CO2 can be used as an inexpensive C1 building block in the synthesis of aromatic fuels for internal combustion engines. We designed a process capable of synthesizing benzene, toluene, xylenes and mesitylene from CO2 and H2 at modest temperatures (T = 380 to 540 °C) employing Fe/Fe3O4 nanoparticles as catalyst. The synthesis of the catalyst and the mechanism of CO2-hydrogenation will be discussed, as well as further applications of Fe/Fe3O4 nanoparticles in catalysis.

  8. Geochemistry characterization, biomarker and determination of correlation, maturity of petroleum from Bangko-Rohil and Duri Bengkalis, Riau

    NASA Astrophysics Data System (ADS)

    Tamboesai, Emrizal Mahidin

    2017-11-01

    Petroleum is the main source of the energy for industry, transportation. Thedemand for crude oil in Indonesia is much higher than its production which leads to current energy crisis. One of solutions for this crisis is to conduct correlation study, which determines the genetic relationship at each oil well. This study is aimed to provide the indication of the genetic relationship (source matter, source rock and the origins) of Bangko and Duri crude oil. The saturated fraction was analyzed using Gas Chromatography (GC). On the basis of the abundance of hydrocarbon aliphatic, the crude oils samples have small ratio value, which is 0,38-0,50 forPr/n-C17 and 0,16-0,18Ph/n-C18. This values indicated that the samples were originated from higher vascular plants (terrestrial). The samples derived from lacustrine environments (lake) have ratio valueof Pr/Ph (2,50-2,90). The calculation from Star diagram have showed that the oil samples in area MB-07, MB-076 dan MB-172 of Bangko with the oil sample in Duri (MD-01) are negatively correlated. The negative correlation indicated that the oil samples have different the genetic relationship source matter and different in enhance oil recovery.

  9. Charging System Optimization of Triboelectric Nanogenerator for Water Wave Energy Harvesting and Storage.

    PubMed

    Yao, Yanyan; Jiang, Tao; Zhang, Limin; Chen, Xiangyu; Gao, Zhenliang; Wang, Zhong Lin

    2016-08-24

    Ocean waves are one of the most promising renewable energy sources for large-scope applications due to the abundant water resources on the earth. Triboelectric nanogenerator (TENG) technology could provide a new strategy for water wave energy harvesting. In this work, we investigated the charging characteristics of utilizing a wavy-structured TENG to charge a capacitor under direct water wave impact and under enclosed ball collision, by combination of theoretical calculations and experimental studies. The analytical equations of the charging characteristics were theoretically derived for the two cases, and they were calculated for various load capacitances, cycle numbers, and structural parameters such as compression deformation depth and ball size or mass. Under the direct water wave impact, the stored energy and maximum energy storage efficiency were found to be controlled by deformation depth, while the stored energy and maximum efficiency can be optimized by the ball size under the enclosed ball collision. Finally, the theoretical results were well verified by the experimental tests. The present work could provide strategies for improving the charging performance of TENGs toward effective water wave energy harvesting and storage.

  10. Conversion of wastes into bioelectricity and chemicals by using microbial electrochemical technologies.

    PubMed

    Logan, Bruce E; Rabaey, Korneel

    2012-08-10

    Waste biomass is a cheap and relatively abundant source of electrons for microbes capable of producing electrical current outside the cell. Rapidly developing microbial electrochemical technologies, such as microbial fuel cells, are part of a diverse platform of future sustainable energy and chemical production technologies. We review the key advances that will enable the use of exoelectrogenic microorganisms to generate biofuels, hydrogen gas, methane, and other valuable inorganic and organic chemicals. Moreover, we examine the key challenges for implementing these systems and compare them to similar renewable energy technologies. Although commercial development is already underway in several different applications, ranging from wastewater treatment to industrial chemical production, further research is needed regarding efficiency, scalability, system lifetimes, and reliability.

  11. Sources of the ultraheavy cosmic rays

    NASA Technical Reports Server (NTRS)

    Margolis, S. H.; Blake, J. B.

    1985-01-01

    The suggestions that the source abundances of cosmic ray nuclei heavier then Fe differ significantly from Solar System abundances are not well supported by the data without assuming preferential acceleration. The Solar System abundances of Pb and Bi are split into r-, standard s-, and cyclic 8-process components; the apprarent deficiency of Pb seen in the HEAO-3 Heavy Nuclei Experiment data might indicate an absence of Pb from the recycling 8-process.

  12. Green materials for sustainable development

    NASA Astrophysics Data System (ADS)

    Purwasasmita, B. S.

    2017-03-01

    Sustainable development is an integrity of multidiscipline concept combining ecological, social and economic aspects to construct a liveable human living system. The sustainable development can be support through the development of green materials. Green materials offers a unique characteristic and properties including abundant in nature, less toxic, economically affordable and versatility in term of physical and chemical properties. Green materials can be applied for a numerous field in science and technology applications including for energy, building, construction and infrastructures, materials science and engineering applications and pollution management and technology. For instance, green materials can be developed as a source for energy production. Green materials including biomass-based source can be developed as a source for biodiesel and bioethanol production. Biomass-based materials also can be transformed into advanced functionalized materials for advanced bio-applications such as the transformation of chitin into chitosan which further used for biomedicine, biomaterials and tissue engineering applications. Recently, cellulose-based material and lignocellulose-based materials as a source for the developing functional materials attracted the potential prospect for biomaterials, reinforcing materials and nanotechnology. Furthermore, the development of pigment materials has gaining interest by using the green materials as a source due to their unique properties. Eventually, Indonesia as a large country with a large biodiversity can enhance the development of green material to strengthen our nation competitiveness and develop the materials technology for the future.

  13. Scalable Production of Si Nanoparticles Directly from Low Grade Sources for Lithium-Ion Battery Anode.

    PubMed

    Zhu, Bin; Jin, Yan; Tan, Yingling; Zong, Linqi; Hu, Yue; Chen, Lei; Chen, Yanbin; Zhang, Qiao; Zhu, Jia

    2015-09-09

    Silicon, one of the most promising candidates as lithium-ion battery anode, has attracted much attention due to its high theoretical capacity, abundant existence, and mature infrastructure. Recently, Si nanostructures-based lithium-ion battery anode, with sophisticated structure designs and process development, has made significant progress. However, low cost and scalable processes to produce these Si nanostructures remained as a challenge, which limits the widespread applications. Herein, we demonstrate that Si nanoparticles with controlled size can be massively produced directly from low grade Si sources through a scalable high energy mechanical milling process. In addition, we systematically studied Si nanoparticles produced from two major low grade Si sources, metallurgical silicon (∼99 wt % Si, $1/kg) and ferrosilicon (∼83 wt % Si, $0.6/kg). It is found that nanoparticles produced from ferrosilicon sources contain FeSi2, which can serve as a buffer layer to alleviate the mechanical fractures of volume expansion, whereas nanoparticles from metallurgical Si sources have higher capacity and better kinetic properties because of higher purity and better electronic transport properties. Ferrosilicon nanoparticles and metallurgical Si nanoparticles demonstrate over 100 stable deep cycling after carbon coating with the reversible capacities of 1360 mAh g(-1) and 1205 mAh g(-1), respectively. Therefore, our approach provides a new strategy for cost-effective, energy-efficient, large scale synthesis of functional Si electrode materials.

  14. Structure of the X-ray source in the Virgo cluster of galaxies

    NASA Technical Reports Server (NTRS)

    Gorenstein, P.; Fabricant, D.; Topka, K.; Tucker, W.; Harnden, F. R., Jr.

    1977-01-01

    High-angular-resolution observations in the 0.15-1.5-keV band with an imaging X-ray telescope shows the extended X-ray source in the Virgo cluster of galaxies to be a diffuse halo of about 15 arcmin core radius surrounding M87. The angular structure of the surface brightness is marginally consistent with either of two simple models: (1) an isothermal (or adiabatic or hydrostatic) sphere plus a point source at M87 accounting for 12% of the total 0.5-1.5-keV intensity or (2) a power-law function without a discrete point source. No evidence for a point source is seen in the 0.15-0.28-keV band, which is consistent with self-absorption by about 10 to the 21st power per sq cm of matter having a cosmic abundance. The power-law models are motivated by the idea that radiation losses regulate the accretion of matter onto M87 and can account for the observed difference in the size of the X-ray source as seen in the present measurements and at higher energies.

  15. Pattern of (Multi)strange (Anti)baryon Production and Search for Deconfinement

    NASA Astrophysics Data System (ADS)

    Rafelski, Johann

    1998-04-01

    We study (multi)strange particle abundances obtained recently in relativistic heavy ion collisions and determine thermal and chemical source parameters(J. Letessier et al., Phys. Lett. B410 (1997) 315--322 hep-ph/9710310 and: Acta Physica Polonica in press, hep- ph/9710340). These are primarily constrained by (multi)strange (anti)baryon relative abundances, which have been measured for Pb--Pb 158 A GeV interactions(I. Kralik, for WA97 collaboration, QM97 Tsukuba, to appear in Nucl. Phys. A) and S-S/W/Pb 200 A GeV interactions(See: proceedings of S'96-Budapest, APH N.S., Heavy Ion Physics 4 (1996) vii--x). We have extended our analysis and have now determined the properties of the particle source using the fitted macro canonical parameters, allowing as required for non-equilibrium dynamics of the locally thermal fireball. We find that in the 158 A GeV Pb--Pb collisions the entropy per baryon, energy per baryon, strangeness per baryon implied by particle spectra are all in the range of values associated commonly with the deconfined QGP phase.

  16. Health effects of arsenic, fluorine, and selenium from indoor burning of Chinese coal.

    PubMed

    Guijian, Liu; Liugen, Zheng; Duzgoren-Aydin, Nurdan S; Lianfen, Gao; Junhua, Liu; Zicheng, Peng

    2007-01-01

    China's economy has developed rapidly in the last two decades, leading to an increase in energy consumption and consequently emissions from energy generation. Coal is a primary energy source in China because of its abundance and will continue to be used in the future. The dominance of coal in energy production is expected to result in increasing levels of exposure to environmental pollution in China. Toxic trace elements emitted during coal combustion are the main sources of indoor air pollution. They are released into the atmosphere mainly in the forms of fine ash and vapors and have the potential to adversely affect human health. Those trace elements, which volatilize during combustion, are hazardous air pollutants (HAPs) and are particularly rich in Chinese coals. Among the HAPs, arsenic (As), fluorine (F), and selenium (Se) have already been identified as pollutants that can induce severe health problems. In this review, the geochemical characteristics of As, F, and Se, including their concentration, distribution, and mode of occurrences in Chinese coal, are documented and discussed. Our investigations have confirmed the current As- and F-induced epidemics in Guizhou (Southwest China) and Se epidemic in Hubei (Northeast China). In this study, diagnostic symptoms of arseniasis, fluorosis, and selenosis are also illustrated.

  17. The Curious Case of High-energy Deuterons in Galactic Cosmic Rays

    NASA Astrophysics Data System (ADS)

    Tomassetti, Nicola; Feng, Jie

    2017-02-01

    A new analysis of cosmic ray (CR) data collected by the SOKOL experiment in space found that the deuteron-to-helium ratio at energies between 500 and 2000 GeV/nucleon takes the value d/He ˜ 1.5. As we will show, this result cannot be explained by standard models of secondary CR production in the interstellar medium and points to the existence of a high-energy source of CR deuterons. To account for the deuteron excess in CRs, we argue that the only viable solution is hadronic interaction processes of accelerated particles inside old supernova remnants (SNRs). From this mechanism, however, the B/C ratio is also expected to increase at energies above ˜50 of GeV/nucleon, in conflict with new precision data just released by the AMS-02 experiment. Hence, if this phenomenon is a real physical effect, hadronic production of CR deuterons must occur in SNRs characterized by low metal abundance. In such a scenario, the sources accelerating C-{N}-O nuclei are not the same as those accelerating helium or protons, so that the connection between d/He ratio and B/C ratio is broken, and the latter cannot be used to place constraints on the production of light isotopes or antiparticles.

  18. Stable isotope analysis of energy dynamics in aquatic ecosystems suggests trophic shifts following severe wildfire

    NASA Astrophysics Data System (ADS)

    Martens, A. M.; Silins, U.; Bladon, K. D.; Williams, C.; Wagner, M. J.; Luchkow, E.

    2015-12-01

    Wildfire alters landscapes and can have significant impacts on stream ecosystems. The 2003 Lost Creek wildfire was one of the most severe on Alberta's eastern rocky mountain slopes, resulting in elevated sediment production and nutrient (phosphorus, nitrogen, and carbon) export in impacted streams. These resulted in increased algal productivity and macroinvertebrate abundance and diversity, and as a result, fish in watersheds draining wildfire affected catchments were larger than those in the same age class from reference (unburned) watersheds. In the present investigation, stable isotope analysis of C and N was utilized to evaluate ecosystem energy dynamics and describe trophic relationships in those watersheds. Aquatic invertebrates from burned catchments showed enrichment in δ13C and δ15N relative to algae suggesting a reliance on algae (autochthony) as a primary source of energy. Invertebrates from unburned systems were depleted in δ13C relative to algae indicating reliance on allochthonous or terrestrial primary energy sources. Preliminary analysis of δ15N in macroinvertebrates showed slight enrichment in burned catchments suggesting a trophic shift. More comprehensive macroinvertebrate sampling and identification has been conducted; isotopic analysis will provide greater resolution of how specific families within feeding guilds have been affected by wildfire. This will provide more robust insights into how wildfires may impact stream ecology in mountain environments.

  19. Solar Radiation Estimated Through Mesoscale Atmospheric Modeling over Northeast Brazil

    NASA Astrophysics Data System (ADS)

    de Menezes Neto, Otacilio Leandro; Costa, Alexandre Araújo; Ramalho, Fernando Pinto; de Maria, Paulo Henrique Santiago

    2009-03-01

    The use of renewable energy sources, like solar, wind and biomass is rapidly increasing in recent years, with solar radiation as a particularly abundant energy source over Northeast Brazil. A proper quantitative knowledge of the incoming solar radiation is of great importance for energy planning in Brazil, serving as basis for developing future projects of photovoltaic power plants and solar energy exploitation. This work presents a methodology for mapping the incoming solar radiation at ground level for Northeast Brazil, using a mesoscale atmospheric model (Regional Atmospheric Modeling System—RAMS), calibrated and validated using data from the network of automatic surface stations from the State Foundation for Meteorology and Water Resources from Ceará (Fundação Cearense de Meteorologia e Recursos Hídricos- FUNCEME). The results showed that the model exhibits systematic errors, overestimating surface radiation, but that, after the proper statistical corrections, using a relationship between the model-predicted cloud fraction, the ground-level observed solar radiation and the incoming solar radiation estimated at the top of the atmosphere, a correlation of 0.92 with a confidence interval of 13.5 W/m2 is found for monthly data. Using this methodology, we found an estimate for annual average incoming solar radiation over Ceará of 215 W/m2 (maximum in October: 260 W/m2).

  20. Population dynamics of electrogenic microbial communities in microbial fuel cells started with three different inoculum sources.

    PubMed

    Ishii, Shun'ichi; Suzuki, Shino; Yamanaka, Yuko; Wu, Angela; Nealson, Kenneth H; Bretschger, Orianna

    2017-10-01

    Microbial fuel cells (MFCs) are one of the bioelectrochemical systems that exploit microorganisms as biocatalysts to degrade organic matters and recover energy as electric power. Here, we explored how the established electrogenic microbial communities were influenced by three different inoculum sources; anaerobic sludge of the wastewater plant, rice paddy field soil, and coastal lagoon sediment. We periodically characterized both electricity generation with sucrose consumption and 16S rRNA-basis microbial community composition. The electrochemical features of MFCs were slightly different among three inocula, and the lagoon sediment-inoculated MFC showed the highest performance in terms of the treatment time. Meanwhile, although the inoculated microbial communities were highly diverse and quite different, only twelve genera affiliated with δ-Proteobacteria, γ-Proteobacteria, Bacilli, Clostridia/Negativicutes or Bacteroidetes were abundantly enriched in all MFC anode communities. Within them, several fermentative genera were clearly different due to the inocula, while the inocula-specific phylotypes were identified in an electrogenic genus Geobacter. The relative abundances of phylotypes closely-related to Geobacter metallireducens were increased in later stages of all the sucrose-fed MFCs. These results indicate that key microbial members for the functional electrogenic community widely exist in natural ecosystems, but the community members presenting in inoculum sources affected the MFC performances. Copyright © 2017 Elsevier B.V. All rights reserved.

  1. Assessment of metal pollution sources by SEM/EDS analysis of solid particles in snow: a case study of Žerjav, Slovenia.

    PubMed

    Miler, Miloš; Gosar, Mateja

    2013-12-01

    Solid particles in snow deposits, sampled in mining and Pb-processing area of Žerjav, Slovenia, have been investigated using scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDS). Identified particles were classified as geogenic-anthropogenic, anthropogenic, and secondary weathering products. Geogenic-anthropogenic particles were represented by scarce Zn- and Pb-bearing ore minerals, originating from mine waste deposit. The most important anthropogenic metal-bearing particles in snow were Pb-, Sb- and Sn-bearing oxides and sulphides. The morphology of these particles showed that they formed at temperatures above their melting points. They were most abundant in snow sampled closest to the Pb-processing plant and least abundant in snow taken farthest from the plant, thus indicating that Pb processing was their predominant source between the last snowfall and the time of sampling. SEM/EDS analysis showed that Sb and Sn contents in these anthropogenic phases were higher and more variable than in natural Pb-bearing ore minerals. The most important secondary weathering products were Pb- and Zn-containing Fe-oxy-hydroxides whose elemental composition and morphology indicated that they mostly resulted from oxidation of metal-bearing sulphides emitted from the Pb-processing plant. This study demonstrated the importance of single particle analysis using SEM/EDS for differentiation between various sources of metals in the environment.

  2. A nematomorph parasite explains variation in terrestrial subsidies to trout streams in Japan

    USGS Publications Warehouse

    Sato, Takuya; Watanabe, Katsutoshi; Tokuchi, Naoko; Kamauchi, Hiromitsu; Harada, Yasushi; Lafferty, Kevin D.

    2011-01-01

    Nematomorph parasites alter the behavior of their orthopteran hosts, driving them to water and creating a source of food for stream salmonids. We investigated whether nematomorphs could explain variation in terrestrial subsidies across several streams. In nine study streams, orthopterans comprise much of the stomach contents of trout (46 +/- 31% on average). Total mass of ingested prey per trout biomass positively correlated with the mass of orthopterans ingested, suggesting that the orthopterans enhanced absolute mass of prey consumption by the trout population. The orthopterans ingested per trout biomass positively correlated with the abundance of nematomorphs in the stream, but not with the abundance of camel crickets (the dominant hosts) around the streams. Streams in conifer plantations had fewer nematomorphs than streams in natural deciduous forests. These results provide the first quantitative evidence that a manipulative parasite can explain variation in the allochthonous energy flow through and across ecosystems.

  3. Statistical methods for thermonuclear reaction rates and nucleosynthesis simulations

    NASA Astrophysics Data System (ADS)

    Iliadis, Christian; Longland, Richard; Coc, Alain; Timmes, F. X.; Champagne, Art E.

    2015-03-01

    Rigorous statistical methods for estimating thermonuclear reaction rates and nucleosynthesis are becoming increasingly established in nuclear astrophysics. The main challenge being faced is that experimental reaction rates are highly complex quantities derived from a multitude of different measured nuclear parameters (e.g., astrophysical S-factors, resonance energies and strengths, particle and γ-ray partial widths). We discuss the application of the Monte Carlo method to two distinct, but related, questions. First, given a set of measured nuclear parameters, how can one best estimate the resulting thermonuclear reaction rates and associated uncertainties? Second, given a set of appropriate reaction rates, how can one best estimate the abundances from nucleosynthesis (i.e., reaction network) calculations? The techniques described here provide probability density functions that can be used to derive statistically meaningful reaction rates and final abundances for any desired coverage probability. Examples are given for applications to s-process neutron sources, core-collapse supernovae, classical novae, and Big Bang nucleosynthesis.

  4. The abundances of hydrogen, helium, oxygen, and iron accelerated in large solar particle events

    NASA Technical Reports Server (NTRS)

    Mazur, J. E.; Mason, G. M.; Klecker, B.; Mcguire, R. E.

    1993-01-01

    Energy spectra measured in 10 large flares with the University of Maryland/Max-Planck-Institut sensors on ISEE I and Goddard Space Flight Center sensors on IMP 8 allowed us to determine the average H, He, O, and Fe abundances as functions of energy in the range of about 0.3-80 MeV/nucleon. Model fits to the spectra of individual events using the predictions of a steady state stochastic acceleration model with rigidity-dependent diffusion provided a means of interpolating small portions of the energy spectra not measured with the instrumentation. Particles with larger mass-to-charge ratios were relatively less abundant at higher energies in the flare-averaged composition. The Fe/O enhancement at low SEP energies was less than the Fe/O ratios observed in He-3-rich flares. Unlike the SEP composition averaged above 5 MeV/nucleon, the average SEP abundances above 0.3 MeV/nucleon were similar to the average solar wind.

  5. Life in the fast lane: fish and foodweb structure in the main channel of large rivers

    USGS Publications Warehouse

    Dettmers, J.M.; Wahl, David H.; Soluk, D.A.; Gutreuter, S.

    2001-01-01

    We studied the main channel of the lower Illinois River and of the Mississippi River just upstream and downstream of its confluence with the Illinois River to describe the abundance, composition, and/or seasonal appearance of components of the main-channel community. Abundance of fishes in the main channel was high, especially adults. Most adult fishes were present in the main channel for either 3 or 4 seasons/y, indicating that fishes regularly reside in the main channel. We documented abundant zooplankton and benthic invertebrates in the main channel, and the presence of these food types in the diets of channel catfish and freshwater drum. All trophic levels were well represented in the main channel, indicating that the main channel supports a unique food web. The main channel also serves as an important energetic link with other riverine habitats (e.g., floodplains, secondary channels, backwater lakes) because of the mobility of resident fishes and because of the varied energy sources supplying this food web. It may be more realistic to view energy flow in large-river systems as a combination of 3 existing concepts, the river continuum concept (downstream transport), the flood pulse concept (lateral transport to the floodplain), and the riverine productivity model (autochthonous production). We urge additional research to quantify the links between the main channel and other habitat types in large rivers because of the apparent importance of main-channel processes in the overall structure and function of large-river ecosystems.

  6. An in-situ phosphorus source for the synthesis of Cu 3P and the subsequent conversion to Cu 3PS 4 nanoparticle clusters

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sheets, Erik J.; Stach, Eric A.; Yang, Wei -Chang

    2015-09-20

    The search for alternative earth abundant semiconducting nanocrystals for sustainable energy applications has brought forth the need for nanoscale syntheses beyond bulk synthesis routes. Of particular interest are metal phosphides and derivative I-V-VI chalcogenides including copper phosphide (Cu 3P) and copper thiophosphate (Cu 3PS 4). Herein, we report a one-pot, solution-based synthesis of Cu 3P nanocrystals utilizing an in-situ phosphorus source: phosphorus pentasulfide (P 2S 5) in trioctylphosphine (TOP). By injecting this phosphorus source into a copper solution in oleylamine (OLA), uniform and size controlled Cu 3P nanocrystals with a phosphorous-rich surface are synthesized. The subsequent reaction of the Cumore » 3P nanocrystals with decomposing thiourea forms nanoscale Cu 3PS 4 particles having p-type conductivity and an effective optical band gap of 2.36 eV.« less

  7. Theoretical studies of massive stars. II - Evolution of a 15 solar-mass star from carbon shell burning to iron core collapse

    NASA Technical Reports Server (NTRS)

    Sparks, W. M.; Endal, A. S.

    1980-01-01

    The evolution of a Population I star of 15 solar masses is described from the carbon shell burning stage to the formation and collapse of an iron core. An unusual aspect of the evolution is that neon ignition occurs off-center and neon burning propagates inward by a series of shell flashes. The extent of the core burning is generally smaller than the Chandrasekhar mass, so that most of the nuclear energy generation occurs in shell sources. Because of degeneracy and the influence of rapid convective mixing, these shell sources are unstable and the core goes through large excursions in temperature and density. The small core also causes the shell sources to converge into a narrow mass region slightly above the Chandrasekhar mass. Thus, the final nucleosynthesis yields are generally small, with silicon being most strongly enhanced with respect to solar system abundances.

  8. Diffuse Galactic antimatter from faint thermonuclear supernovae in old stellar populations

    NASA Astrophysics Data System (ADS)

    Crocker, Roland M.; Ruiter, Ashley J.; Seitenzahl, Ivo R.; Panther, Fiona H.; Sim, Stuart; Baumgardt, Holger; Möller, Anais; Nataf, David M.; Ferrario, Lilia; Eldridge, J. J.; White, Martin; Tucker, Brad E.; Aharonian, Felix

    2017-06-01

    Our Galaxy hosts the annihilation of a few 1043 low-energy positrons every second. Radioactive isotopes capable of supplying such positrons are synthesized in stars, stellar remnants and supernovae. For decades, however, there has been no positive identification of a main stellar positron source, leading to suggestions that many positrons originate from exotic sources like the Galaxy's central supermassive black hole or dark matter annihilation. Here we show that a single type of transient source, deriving from stellar populations of age 3-6 Gyr and yielding ∼0.03 M ⊙ of the positron emitter 44Ti, can simultaneously explain the strength and morphology of the Galactic positron annihilation signal and the Solar System abundance of the 44Ti decay product 44Ca. This transient is likely the merger of two low-mass white dwarfs, observed in external galaxies as the sub-luminous, thermonuclear supernova known as SN 1991bg-like.

  9. US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dennis, R.A.

    1997-05-01

    The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systemsmore » has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.« less

  10. Stabilizing the Performance of High-Capacity Sulfur Composite Electrodes by a New Gel Polymer Electrolyte Configuration.

    PubMed

    Agostini, Marco; Lim, Du Hyun; Sadd, Matthew; Fasciani, Chiara; Navarra, Maria Assunta; Panero, Stefania; Brutti, Sergio; Matic, Aleksandar; Scrosati, Bruno

    2017-09-11

    Increased pollution and the resulting increase in global warming are drawing attention to boosting the use of renewable energy sources such as solar or wind. However, the production of energy from most renewable sources is intermittent and thus relies on the availability of electrical energy-storage systems with high capacity and at competitive cost. Lithium-sulfur batteries are among the most promising technologies in this respect due to a very high theoretical energy density (1675 mAh g -1 ) and that the active material, sulfur, is abundant and inexpensive. However, a so far limited practical energy density, life time, and the scaleup of materials and production processes prevent their introduction into commercial applications. In this work, we report on a simple strategy to address these issues by using a new gel polymer electrolyte (GPE) that enables stable performance close to the theoretical capacity of a low cost sulfur-carbon composite with high loading of active material, that is, 70 % sulfur. We show that the GPE prevents sulfur dissolution and reduces migration of polysulfide species to the anode. This functional mechanism of the GPE membranes is revealed by investigating both its morphology and the Li-anode/GPE interface at various states of discharge/charge using Raman spectroscopy. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Trace element abundances of high-MgO glasses from Kilauea, Mauna Loa and Haleakala volcanoes, Hawaii

    USGS Publications Warehouse

    Wagner, T.P.; Clague, D.A.; Hauri, E.H.; Grove, T.L.

    1998-01-01

    We performed an ion-microprobe study of eleven high-MgO (6.7-14.8 wt%) tholeiite glasses from the Hawaiian volcanoes Kilauea, Mauna Loa and Haleakala. We determined the rare earth (RE), high field strength, and other selected trace element abundances of these glasses, and used the data to establish their relationship to typical Hawaiian shield tholeiite and to infer characteristics of their source. The glasses have trace element abundance characteristics generally similar to those of typical shield tholeiites, e.g. L(light)REE/H(heavy)REE(C1) > 1. The Kilauea and Mauna Loa glasses, however, display trace and major element characteristics that cross geochemical discriminants observed between Kilauea and Mauna Loa shield lavas. The glasses contain a blend of these discriminating chemical characteristics, and are not exactly like the typical shield lavas from either volcano. The production of these hybrid magmas likely requires a complexly zoned source, rather than two unique sources. When corrected for olivine fractionation, the glass data show correlations between CaO concentration and incompatible trace element abundances, indicating that CaO may behave incompatibly during melting of the tholeiite source. Furthermore, the tholeiite source must contain residual garnet and clinopyroxene to account for the variation in trace element abundances of the Kilauea glasses. Inversion modeling indicates that the Kilauea source is flat relative to C1 chondrites, and has a higher bulk distribution coefficient for the HREE than the LREE.

  12. Bent Laue X-ray Fluorescence Imaging of Manganese in Biological Tissues—Preliminary Results

    NASA Astrophysics Data System (ADS)

    Zhu, Ying; Bewer, Brian; Zhang, Honglin; Nichol, Helen; Thomlinson, Bill; Chapman, Dean

    2010-06-01

    Manganese (Mn) is not abundant in human brain tissue, but it is recognized as a neurotoxin. The symptoms of manganese intoxication are similar to Parkinson's disease (PD), but the link between environmental, occupational or dietary Mn exposure and PD in humans is not well established. X-ray Absorption Spectroscopy (XAS) and in particular X-ray fluorescence can provide precise information on the distribution, concentration and chemical form of metals. However the scattered radiation and fluorescence from the adjacent abundant element, iron (Fe), may interfere with and limit the ability to detect ultra-dilute Mn. A bent Laue analyzer based Mn fluorescence detection system has been designed and fabricated to improve elemental specificity in XAS imaging. This bent Laue analyzer of logarithmic spiral shape placed upstream of an energy discriminating detector should improve the energy resolution from hundreds of eV to several eV. The bent Laue detection system was validated by imaging Mn fluorescence from Mn foils, gelatin calibration samples and adult Drosophila at the Hard X-ray MicroAnalysis (HXMA) beamline at the Canadian Light Source (CLS). Optimization of the design parameters, fabrication procedures and preliminary experimental results are presented along with future plans.

  13. Exploring the 13CO/C18O abundance ratio towards Galactic young stellar objects and HII regions

    NASA Astrophysics Data System (ADS)

    Areal, M. B.; Paron, S.; Celis Peña, M.; Ortega, M. E.

    2018-05-01

    Aims: Determining molecular abundance ratios is important not only for the study of Galactic chemistry, but also because they are useful to estimate physical parameters in a large variety of interstellar medium environments. One of the most important molecules for tracing the molecular gas in the interstellar medium is CO, and the 13CO/C18O abundance ratio is usually used to estimate molecular masses and densities of regions with moderate to high densities. Nowadays isotope ratios are in general indirectly derived from elemental abundances ratios. We present the first 13CO/C18O abundance ratio study performed from CO isotope observations towards a large sample of Galactic sources of different natures at different locations. Methods: To study the 13CO/C18O abundance ratio, we used 12CO J = 3 - 2 data obtained from the CO High-Resolution Survey, 13CO and C18O J = 3 - 2 data from the 13CO/C18O (J = 3 - 2) Heterodyne Inner Milky Way Plane Survey, and some complementary data extracted from the James Clerk Maxwell Telescope database. We analyzed a sample of 198 sources composed of young stellar objects (YSOs), and HII and diffuse HII regions as catalogued in the Red MSX Source Survey in 27.°5 ≤ l ≤ 46.°5 and |b|0.°5. Results: Most of the analyzed sources are located in the galactocentric distance range 4.0-6.5 kpc. We found that YSOs have, on average, lower 13CO/C18O abundance ratios than HII and diffuse HII regions. Taking into account that the gas associated with YSOs should be less affected by the radiation than in the case of the others sources, selective far-UV photodissociation of C18O is confirmed. The 13CO/C18O abundance ratios obtained in this work are systematically lower than those predicted from the known elemental abundance relations. These results will be useful in future studies of molecular gas related to YSOs and HII regions based on the observation of these isotopes.

  14. Pine as Fast Food: Foraging Ecology of an Endangered Cockatoo in a Forestry Landscape

    PubMed Central

    Stock, William D.; Finn, Hugh; Parker, Jackson; Dods, Ken

    2013-01-01

    Pine plantations near Perth, Western Australia have provided an important food source for endangered Carnaby’s Cockatoos (Calyptorhynchus latirostris) since the 1940s. Plans to harvest these plantations without re-planting will remove this food source by 2031 or earlier. To assess the impact of pine removal, we studied the ecological association between Carnaby’s Cockatoos and pine using behavioural, nutritional, and phenological data. Pine plantations provided high densities of seed (158 025 seeds ha−1) over a large area (c. 15 000 ha). Carnaby’s Cockatoos fed throughout these plantations and removed almost the entire annual crop of pine cones. Peak cockatoo abundance coincided with pine seed maturation. Pine seed had energy and protein contents equivalent to native food sources and, critically, is available in summer when breeding pairs have young offspring to feed. This strong and enduring ecological association clearly suggests that removing pine will have a significant impact on this endangered species unless restoration strategies, to establish alternative food sources, are implemented. PMID:23593413

  15. AGB nucleosynthesis: The 19F(α, p)22Ne reaction at astrophysical energies

    NASA Astrophysics Data System (ADS)

    D'Agata, G.; Pizzone, R. G.; Spitaleri, C.; Blagus, S.; Figuera, P.; Grassi, L.; Guardo, G. L.; Gulino, M.; Hayakawa, S.; Indelicato, I.; Kshetri, R.; La Cognata, M.; Lamia, L.; Lattuada, M.; Mijatović, T.; Milin, M.; Miljanic, D.; Prepolec, L.; Sergi, M. L.; Skukan, N.; Soic, N.; Tokic, V.; Tumino, A.; Uroic, M.

    2017-06-01

    Learning how 19F is produced and destructed in AGB-stars is crucial. Fluorine abundance is in fact important, given that it is strongly tied to standard and extra-mixing processes taking place in AGB-stars. This kind of objects are considered to be the main sources of fluorine in galactic environment, in which experimental abundances are far overestimated. For this reason the reaction 19F(α, p)22Ne, that represents the main destruction channel in He-rich environment, was studied at energies corresponding to T˜2.108 K. Such reaction has been studied with direct method at Ebeam = 1100 keV for alpha particles impinging on a fluorine target, corresponding to EC.M. ˜ 900 keV, still far from the Gamow window, placed at 390÷800 keV, below the Coulomb barrier (3.81 MeV). An experiment was performed at Rujer Boskovic Institut (Zagreb), applying the Trojan Horse Method. With this experimental procedure we were able to select the quasi-free contribution coming from 6Li(19F,p 22Ne)2H at Ebeam = 6 MeV at kinematically useful angles. We measured the 19F(α, p)22Ne at 0 MeV ≤ EC.M ≤ 0.9 MeV, extracting the two body cross-section in absolute units at energies of astrophysical interest.

  16. Ion componsition of zipper events

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kaye, S.M.; Shelley, E.G.; Sharp, R.D.

    1981-05-01

    A class of ion distributions has recently been identified by Fennell et al. (this issue). The distributions are composed of two components, a low-energy component with peak fluxes directed along the field line and a high-energy component with peak fluxes in the perpendicular direction. The transiton between the two components occur over a very narrow range of energies but can occur anywhere between approximately several hundred electron volts and 20 keV. Because of the appearance of this distribution on an energy versus time spectrogram, the ion events have been called zippers. The purpose of this report is to examine themore » mass composition of the zipper events. We find that the low-energy and parallel component is composed primarily of O/sup +/, with, to a lesser degree, H/sup +/ and a trace of He/sup +/. The high-energy and perpendicular component is predominantly H/sup +/, with the relative abundances of O/sup +/ and He/sup +/ down from those of the low-energy component by a factor of approx.10. These results suggest that whereas the low-energy component is probably ionospheric in origin, the source of the high-energy components is most probably the plsamasheet.« less

  17. Implications of Abundant Gas and Oil for Climate Forcing

    NASA Astrophysics Data System (ADS)

    Edmonds, J.

    2015-12-01

    Perhaps the most important development in the field of energy over the past decade has been the advent of technologies that enable the production of larger volumes of natural gas and oil at lower cost. The availability of more abundant gas and oil is reshaping the global energy system, with implications for both evolving emissions of CO2 and other climate forcers. More abundant gas and oil will also transform the character of greenhouse gas emissions mitigation. We review recent findings regarding the impact of abundant gas and oil for climate forcing and the challenge of emissions mitigation. We find strong evidence that, absent policies to limits its penetration against renewable energy, abundant gas has little observable impact on CO2 emissions, and tends to increase overall climate forcing, though the latter finding is subject to substantial uncertainty. The presence of abundant gas also affects emissions mitigation. There is relatively little literature exploring the implication of expanded gas availability on the difficulty in meeting emissions mitigation goals. However, preliminary results indicate that on global scales abundant gas does not substantially affect the cost of emissions mitigation, even though natural gas could have an expanded role in emissions mitigation scenarios as compared with scenarios in which natural gas is less abundant.

  18. Origin and transport of high energy particles in the galaxy

    NASA Technical Reports Server (NTRS)

    Wefel, John P.

    1987-01-01

    The origin, confinement, and transport of cosmic ray nuclei in the galaxy was studied. The work involves interpretations of the existing cosmic ray physics database derived from both balloon and satellite measurements, combined with an effort directed towards defining the next generation of instruments for the study of cosmic radiation. The shape and the energy dependence of the cosmic ray pathlength distribution in the galaxy was studied, demonstrating that the leaky box model is not a good representation of the detailed particle transport over the energy range covered by the database. Alternative confinement methods were investigated, analyzing the confinement lifetime in these models based upon the available data for radioactive secondary isotopes. The source abundances of several isotopes were studied using compiled nuclear physics data and the detailed transport calculations. The effects of distributed particle acceleration on the secondary to primary ratios were investigated.

  19. Environmental siting suitability analysis for commercial scale ocean renewable energy: A southeast Florida case study

    NASA Astrophysics Data System (ADS)

    Mulcan, Amanda

    This thesis aims to facilitate the siting and implementation of Florida Atlantic University Southeast National Marine Renewable Energy Center (FAU SNMREC) ocean current energy (OCE) projects offshore southeastern Florida through the analysis of benthic anchoring conditions. Specifically, a suitability analysis considering all presently available biologic and geologic datasets within the legal framework of OCE policy and regulation was done. OCE related literature sources were consulted to assign suitability levels to each dataset, ArcGIS interpolations generated seafloor substrate maps, and existing submarine cable pathways were considered for OCE power cables. The finalized suitability map highlights the eastern study area as most suitable for OCE siting due to its abundance of sand/sediment substrate, existing underwater cable route access, and minimal biologic presence. Higher resolution datasets are necessary to locate specific OCE development locales, better understand their benthic conditions, and minimize potentially negative OCE environmental impacts.

  20. Radiological analysis of plutonium glass batches with natural/enriched boron

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rainisch, R.

    2000-06-22

    The disposition of surplus plutonium inventories by the US Department of Energy (DOE) includes the immobilization of certain plutonium materials in a borosilicate glass matrix, also referred to as vitrification. This paper addresses source terms of plutonium masses immobilized in a borosilicate glass matrix where the glass components include both natural boron and enriched boron. The calculated source terms pertain to neutron and gamma source strength (particles per second), and source spectrum changes. The calculated source terms corresponding to natural boron and enriched boron are compared to determine the benefits (decrease in radiation source terms) for to the use ofmore » enriched boron. The analysis of plutonium glass source terms shows that a large component of the neutron source terms is due to (a, n) reactions. The Americium-241 and plutonium present in the glass emit alpha particles (a). These alpha particles interact with low-Z nuclides like B-11, B-10, and O-17 in the glass to produce neutrons. The low-Z nuclides are referred to as target particles. The reference glass contains 9.4 wt percent B{sub 2}O{sub 3}. Boron-11 was found to strongly support the (a, n) reactions in the glass matrix. B-11 has a natural abundance of over 80 percent. The (a, n) reaction rates for B-10 are lower than for B-11 and the analysis shows that the plutonium glass neutron source terms can be reduced by artificially enriching natural boron with B-10. The natural abundance of B-10 is 19.9 percent. Boron enriched to 96-wt percent B-10 or above can be obtained commercially. Since lower source terms imply lower dose rates to radiation workers handling the plutonium glass materials, it is important to know the achievable decrease in source terms as a result of boron enrichment. Plutonium materials are normally handled in glove boxes with shielded glass windows and the work entails both extremity and whole-body exposures. Lowering the source terms of the plutonium batches will make the handling of these materials less difficult and will reduce radiation exposure to operating workers.« less

  1. New Earth-abundant Materials for Large-scale Solar Fuels Generation.

    PubMed

    Prabhakar, Rajiv Ramanujam; Cui, Wei; Tilley, S David

    2018-05-30

    The solar resource is immense, but the power density of light striking the Earth's surface is relatively dilute, necessitating large area solar conversion devices in order to harvest substantial amounts of power for renewable energy applications. In addition, energy storage is a key challenge for intermittent renewable resources such as solar and wind, which adds significant cost to these energies. As the majority of humanity's present-day energy consumption is based on fuels, an ideal solution is to generate renewable fuels from abundant resources such as sunlight and water. In this account, we detail our recent work towards generating highly efficient and stable Earth-abundant semiconducting materials for solar water splitting to generate renewable hydrogen fuel.

  2. Mid-Holocene change in types of degassing volcanoes, using indium in Antarctic ice as a tracer of volcanic source type

    USGS Publications Warehouse

    Hinkley, T.; Matsumoto, A.

    2007-01-01

    Proportions of trace metals in Antarctic ice samples indicate that the type of volcanoes that dominated atmospheric emissions changed at about the middle of the Holocene from relatively mafic, deep source volcanoes to more silicic, shallower-source volcanoes. We base this inference on the strong contrast in the abundances of the trace metal indium (In), relative to other trace metals present in ice, deposited at different times in the past, and on contrasting In abundances in modern emissions of volcanoes of different types. Indium is more abundant in the emissions of deep-source mafic volcanoes than in more felsic, shallower-source volcanoes. Earlier workers have shown, on the basis of petrologic and some meteoritic evidence, that In may be partitioned to the interiors (stony mantles) of differentiated planets, or enriched in the liquids of partly crystallized mafic melts.

  3. Ionized Outflows in 3-D Insights from Herbig-Haro Objects and Applications to Nearby AGN

    NASA Technical Reports Server (NTRS)

    Cecil, Gerald

    1999-01-01

    HST shows that the gas distributions of these objects are complex and clump at the limit of resolution. HST spectra have lumpy emission-line profiles, indicating unresolved sub-structure. The advantages of 3D over slits on gas so distributed are: robust flux estimates of various dynamical systems projected along lines of sight, sensitivity to fainter spectral lines that are physical diagnostics (reddening-gas density, T, excitation mechanisms, abundances), and improved prospects for recovery of unobserved dimensions of phase-space. These advantages al- low more confident modeling for more profound inquiry into underlying dynamics. The main complication is the effort required to link multi- frequency datasets that optimally track the energy flow through various phases of the ISM. This tedium has limited the number of objects that have been thoroughly analyzed to the a priori most spectacular systems. For HHO'S, proper-motions constrain the ambient B-field, shock velocity, gas abundances, mass-loss rates, source duty-cycle, and tie-ins with molecular flows. If the shock speed, hence ionization fraction, is indeed small then the ionized gas is a significant part of the flow energetics. For AGN'S, nuclear beaming is a source of ionization ambiguity. Establishing the energetics of the outflow is critical to determining how the accretion disk loses its energy. CXO will provide new constraints (especially spectral) on AGN outflows, and STIS UV-spectroscopy is also constraining cloud properties (although limited by extinction). HHO's show some of the things that we will find around AGN'S. I illustrate these points with results from ground-based and HST programs being pursued with collaborators.

  4. Roux-en-Y gastric bypass surgery of morbidly obese patients induces swift and persistent changes of the individual gut microbiota.

    PubMed

    Palleja, Albert; Kashani, Alireza; Allin, Kristine H; Nielsen, Trine; Zhang, Chenchen; Li, Yin; Brach, Thorsten; Liang, Suisha; Feng, Qiang; Jørgensen, Nils Bruun; Bojsen-Møller, Kirstine N; Dirksen, Carsten; Burgdorf, Kristoffer S; Holst, Jens J; Madsbad, Sten; Wang, Jun; Pedersen, Oluf; Hansen, Torben; Arumugam, Manimozhiyan

    2016-06-15

    Roux-en-Y gastric bypass (RYGB) is an effective means to achieve sustained weight loss for morbidly obese individuals. Besides rapid weight reduction, patients achieve major improvements of insulin sensitivity and glucose homeostasis. Dysbiosis of gut microbiota has been associated with obesity and some of its co-morbidities, like type 2 diabetes, and major changes of gut microbial communities have been hypothesized to mediate part of the beneficial metabolic effects observed after RYGB. Here we describe changes in gut microbial taxonomic composition and functional potential following RYGB. We recruited 13 morbidly obese patients who underwent RYGB, carefully phenotyped them, and had their gut microbiomes quantified before (n = 13) and 3 months (n = 12) and 12 months (n = 8) after RYGB. Following shotgun metagenomic sequencing of the fecal microbial DNA purified from stools, we characterized the gut microbial composition at species and gene levels followed by functional annotation. In parallel with the weight loss and metabolic improvements, gut microbial diversity increased within the first 3 months after RYGB and remained high 1 year later. RYGB led to altered relative abundances of 31 species (P < 0.05, q < 0.15) within the first 3 months, including those of Escherichia coli, Klebsiella pneumoniae, Veillonella spp., Streptococcus spp., Alistipes spp., and Akkermansia muciniphila. Sixteen of these species maintained their altered relative abundances during the following 9 months. Interestingly, Faecalibacterium prausnitzii was the only species that decreased in relative abundance. Fifty-three microbial functional modules increased their relative abundance between baseline and 3 months (P < 0.05, q < 0.17). These functional changes included increased potential (i) to assimilate multiple energy sources using transporters and phosphotransferase systems, (ii) to use aerobic respiration, (iii) to shift from protein degradation to putrefaction, and (iv) to use amino acids and fatty acids as energy sources. Within 3 months after morbidly obese individuals had undergone RYGB, their gut microbiota featured an increased diversity, an altered composition, an increased potential for oxygen tolerance, and an increased potential for microbial utilization of macro- and micro-nutrients. These changes were maintained for the first year post-RYGB. Current controlled trials (ID NCT00810823 , NCT01579981 , and NCT01993511 ).

  5. Multi-objective generation scheduling with hybrid energy resources

    NASA Astrophysics Data System (ADS)

    Trivedi, Manas

    In economic dispatch (ED) of electric power generation, the committed generating units are scheduled to meet the load demand at minimum operating cost with satisfying all unit and system equality and inequality constraints. Generation of electricity from the fossil fuel releases several contaminants into the atmosphere. So the economic dispatch objective can no longer be considered alone due to the environmental concerns that arise from the emissions produced by fossil fueled electric power plants. This research is proposing the concept of environmental/economic generation scheduling with traditional and renewable energy sources. Environmental/economic dispatch (EED) is a multi-objective problem with conflicting objectives since emission minimization is conflicting with fuel cost minimization. Production and consumption of fossil fuel and nuclear energy are closely related to environmental degradation. This causes negative effects to human health and the quality of life. Depletion of the fossil fuel resources will also be challenging for the presently employed energy systems to cope with future energy requirements. On the other hand, renewable energy sources such as hydro and wind are abundant, inexhaustible and widely available. These sources use native resources and have the capacity to meet the present and the future energy demands of the world with almost nil emissions of air pollutants and greenhouse gases. The costs of fossil fuel and renewable energy are also heading in opposite directions. The economic policies needed to support the widespread and sustainable markets for renewable energy sources are rapidly evolving. The contribution of this research centers on solving the economic dispatch problem of a system with hybrid energy resources under environmental restrictions. It suggests an effective solution of renewable energy to the existing fossil fueled and nuclear electric utilities for the cheaper and cleaner production of electricity with hourly emission targets. Since minimizing the emissions and fuel cost are conflicting objectives, a practical approach based on multi-objective optimization is applied to obtain compromised solutions in a single simulation run using genetic algorithm. These solutions are known as non-inferior or Pareto-optimal solutions, graphically illustrated by the trade-off curves between criterions fuel cost and pollutant emission. The efficacy of the proposed approach is illustrated with the help of different sample test cases. This research would be useful for society, electric utilities, consultants, regulatory bodies, policy makers and planners.

  6. XMM-Newton studies of the supernova remnant G350.0-2.0

    NASA Astrophysics Data System (ADS)

    Karpova, A.; Shternin, P.; Zyuzin, D.; Danilenko, A.; Shibanov, Yu.

    2016-11-01

    We report the results of XMM-Newton observations of the Galactic mixed-morphology supernova remnant G350.0-2.0. Diffuse thermal X-ray emission fills the north-western part of the remnant surrounded by radio shell-like structures. We did not detect any X-ray counterpart of the latter structures, but found several bright blobs within the diffuse emission. The X-ray spectrum of the most part of the remnant can be described by a collisionally ionized plasma model VAPEC with solar abundances and a temperature of ≈0.8 keV. The solar abundances of plasma indicate that the X-ray emission comes from the shocked interstellar material. The overabundance of Fe was found in some of the bright blobs. We also analysed the brightest point-like X-ray source 1RXS J172653.4-382157 projected on the extended emission. Its spectrum is well described by the two-temperature optically thin thermal plasma model MEKAL typical for cataclysmic variable stars. The cataclysmic variable source nature is supported by the presence of a faint (g ≈ 21) optical source with non-stellar spectral energy distribution at the X-ray position of 1RXS J172653.4-382157. It was detected with the XMM-Newton optical/UV monitor in the U filter and was also found in the archival Hα and optical/near-infrared broad-band sky survey images. On the other hand, the X-ray spectrum is also described by the power law plus thermal component model typical for a rotation powered pulsar. Therefore, the pulsar interpretation of the source cannot be excluded. For this source, we derived the upper limit for the pulsed fraction of 27 per cent.

  7. Effects of obesity, energy restriction and neutering on the faecal microbiota of cats.

    PubMed

    Fischer, Manuela M; Kessler, Alexandre M; Kieffer, Dorothy A; Knotts, Trina A; Kim, Kyoungmi; Wei, Alfreda; Ramsey, Jon J; Fascetti, Andrea J

    2017-10-01

    Surveys report that 25-57 % of cats are overweight or obese. The most evinced cause is neutering. Weight loss often fails; thus, new strategies are needed. Obesity has been associated with altered gut bacterial populations and increases in microbial dietary energy extraction, body weight and adiposity. This study aimed to determine whether alterations in intestinal bacteria were associated with obesity, energy restriction and neutering by characterising faecal microbiota using 16S rRNA gene sequencing in eight lean intact, eight lean neutered and eight obese neutered cats before and after 6 weeks of energy restriction. Lean neutered cats had a bacterial profile similar to obese rodents and humans, with a greater abundance (P<0·05) of Firmicutes and lower abundance (P<0·05) of Bacteroidetes compared with the other groups. The greater abundance of Firmicutes in lean neutered cats was due to a bloom in Peptostreptococcaceae. Obese cats had an 18 % reduction in fat mass after energy restriction (P<0·05). Energy reduction was concurrent with significant shifts in two low-abundance bacterial genera and trends in four additional genera. The greatest change was a reduction in the Firmicutes genus, Sarcina, from 4·54 to 0·65 % abundance after energy restriction. The short duration of energy restriction may explain why few bacterial changes were observed in the obese cats. Additional work is needed to understand how neutering, obesity and weight loss are related to changes in feline microbiota and how these microbial shifts affect host physiology.

  8. Chemical Abundance Measurements of Ultra-Faint Dwarf Galaxies Discovered by the Dark Energy Survey

    NASA Astrophysics Data System (ADS)

    Nagasawa, Daniel; Marshall, Jennifer L.; Simon, Joshua D.; Hansen, Terese; Li, Ting; Bernstein, Rebecca; Balbinot, Eduardo; Drlica-Wagner, Alex; Pace, Andrew; Strigari, Louis; Pellegrino, Craig; DePoy, Darren L.; Suntzeff, Nicholas; Bechtol, Keith; Dark Energy Suvey

    2018-01-01

    We present chemical abundance analysis results derived from high-resolution spectroscopy of ultra-faint dwarfs discovered by the Dark Energy Survey. Ultra-faint dwarf galaxies preserve a fossil record of the chemical abundance patterns imprinted by the first stars in the Universe. High-resolution spectroscopic observations of member stars in several recently discovered Milky Way satellites reveal a range of abundance patterns among ultra-faint dwarfs suggesting that star formation processes in the early Universe were quite diverse. The chemical content provides a glimpse not only of the varied nucleosynthetic processes and chemical history of the dwarfs themselves, but also the environment in which they were formed. We present the chemical abundance analysis of these objects and discuss possible explanations for the observed abundance patterns.

  9. Onshore-offshore wind energy resource evaluation based on synergetic use of multiple satellite data and meteorological stations in Jiangsu Province, China

    NASA Astrophysics Data System (ADS)

    Wei, Xianglin; Duan, Yuewei; Liu, Yongxue; Jin, Song; Sun, Chao

    2018-05-01

    The demand for efficient and cost-effective renewable energy is increasing as traditional sources of energy such as oil, coal, and natural gas, can no longer satisfy growing global energy demands. Among renewable energies, wind energy is the most prominent due to its low, manageable impacts on the local environment. Based on meteorological data from 2006 to 2014 and multi-source satellite data (i.e., Advanced Scatterometer, Quick Scatterometer, and Windsat) from 1999 to 2015, an assessment of the onshore and offshore wind energy potential in Jiangsu Province was performed by calculating the average wind speed, average wind direction, wind power density, and annual energy production (AEP). Results show that Jiangsu has abundant wind energy resources, which increase from inland to coastal areas. In onshore areas, wind power density is predominantly less than 200 W/m2, while in offshore areas, wind power density is concentrates in the range of 328-500 W/m2. Onshore areas comprise more than 13,573.24 km2, mainly located in eastern coastal regions with good wind farm potential. The total wind power capacity in onshore areas could be as much as 2.06 x 105 GWh. Meanwhile, offshore wind power generation in Jiangsu Province is calculated to reach 2 x 106 GWh, which is approximately four times the electricity demand of the entire Jiangsu Province. This study validates the effective application of Advanced Scatterometer, Quick Scatterometer, and Windsat data to coastal wind energy monitoring in Jiangsu. Moreover, the methodology used in this study can be effectively applied to other similar coastal zones.

  10. Carbon-Based Functional Materials Derived from Waste for Water Remediation and Energy Storage.

    PubMed

    Ma, Qinglang; Yu, Yifu; Sindoro, Melinda; Fane, Anthony G; Wang, Rong; Zhang, Hua

    2017-04-01

    Carbon-based functional materials hold the key for solving global challenges in the areas of water scarcity and the energy crisis. Although carbon nanotubes (CNTs) and graphene have shown promising results in various fields of application, their high preparation cost and low production yield still dramatically hinder their wide practical applications. Therefore, there is an urgent call for preparing carbon-based functional materials from low-cost, abundant, and sustainable sources. Recent innovative strategies have been developed to convert various waste materials into valuable carbon-based functional materials. These waste-derived carbon-based functional materials have shown great potential in many applications, especially as sorbents for water remediation and electrodes for energy storage. Here, the research progress in the preparation of waste-derived carbon-based functional materials is summarized, along with their applications in water remediation and energy storage; challenges and future research directions in this emerging research field are also discussed. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Artificial photosynthesis: biomimetic approaches to solar energy conversion and storage.

    PubMed

    Kalyanasundaram, K; Graetzel, M

    2010-06-01

    Using sun as the energy source, natural photosynthesis carries out a number of useful reactions such as oxidation of water to molecular oxygen and fixation of CO(2) in the form of sugars. These are achieved through a series of light-induced multi-electron-transfer reactions involving chlorophylls in a special arrangement and several other species including specific enzymes. Artificial photosynthesis attempts to reconstruct these key processes in simpler model systems such that solar energy and abundant natural resources can be used to generate high energy fuels and restrict the amount of CO(2) in the atmosphere. Details of few model catalytic systems that lead to clean oxidation of water to H(2) and O(2), photoelectrochemical solar cells for the direct conversion of sunlight to electricity, solar cells for total decomposition of water and catalytic systems for fixation of CO(2) to fuels such as methanol and methane are reviewed here. Copyright 2010 Elsevier Ltd. All rights reserved.

  12. Different types of maximum power point tracking techniques for renewable energy systems: A survey

    NASA Astrophysics Data System (ADS)

    Khan, Mohammad Junaid; Shukla, Praveen; Mustafa, Rashid; Chatterji, S.; Mathew, Lini

    2016-03-01

    Global demand for electricity is increasing while production of energy from fossil fuels is declining and therefore the obvious choice of the clean energy source that is abundant and could provide security for development future is energy from the sun. In this paper, the characteristic of the supply voltage of the photovoltaic generator is nonlinear and exhibits multiple peaks, including many local peaks and a global peak in non-uniform irradiance. To keep global peak, MPPT is the important component of photovoltaic systems. Although many review articles discussed conventional techniques such as P & O, incremental conductance, the correlation ripple control and very few attempts have been made with intelligent MPPT techniques. This document also discusses different algorithms based on fuzzy logic, Ant Colony Optimization, Genetic Algorithm, artificial neural networks, Particle Swarm Optimization Algorithm Firefly, Extremum seeking control method and hybrid methods applied to the monitoring of maximum value of power at point in systems of photovoltaic under changing conditions of irradiance.

  13. Carbon dioxide hydrogenation to aromatic hydrocarbons by using an iron/iron oxide nanocatalyst

    PubMed Central

    Hodgson, Jim; Shrestha, Tej B; Thapa, Prem S; Moore, David; Wu, Xiaorong; Ikenberry, Myles; Troyer, Deryl L; Wang, Donghai; Hohn, Keith L

    2014-01-01

    Summary The quest for renewable and cleaner energy sources to meet the rapid population and economic growth is more urgent than ever before. Being the most abundant carbon source in the atmosphere of Earth, CO2 can be used as an inexpensive C1 building block in the synthesis of aromatic fuels for internal combustion engines. We designed a process capable of synthesizing benzene, toluene, xylenes and mesitylene from CO2 and H2 at modest temperatures (T = 380 to 540 °C) employing Fe/Fe3O4 nanoparticles as catalyst. The synthesis of the catalyst and the mechanism of CO2-hydrogenation will be discussed, as well as further applications of Fe/Fe3O4 nanoparticles in catalysis. PMID:24991513

  14. Potential use of duckweed based anaerobic digester effluent as a feed source for heterotrophic growth of micro-algae

    NASA Astrophysics Data System (ADS)

    Ahmadi, L.; Dupont, R.

    2013-12-01

    Finding an alternative source of energy for the growing world's demand is a challenging task being considered by many scientists. Various types of renewable energy alternatives are being investigated by researchers around the world. The abundance of duckweed (i.e., Lemna and Wolfia sp.) in wetlands and wastewater lagoons, their rapid growth, and their capacity for nutrient, metal and other contaminant removal from wastewater suggests their potential as an inexpensive source of biomass for biofuel production. Another source of biomass for biofuel and energy production is micro-algae. The large-scale growth of micro-algae can potentially be achieved in a smaller footprint and at a higher rate and lower cost via heterotrophic growth compared to autotrophic growth for specific species that can grow under both conditions. Here we describe two types of research. First, two lab-scale, 5 L anaerobic digesters containing municipal raw wastewater that were set up, maintained and monitored over the course of 6 months using duckweed as the feed source. The pH, salinity, amount of gas production and gas composition were measured on a daily basis. The results from these measurements show that duckweed can be used as a good source of biofuel production in the form of methane gas. The second set of reactors consisted of two 1 L batch fed reactors containing algae (Chlorella vulgaris) grown in the lab environment heterotrophically. The pH and DO were monitored on a daily basis in order to investigate their effect on algae growth. Lipid analysis of the harvested algal biomass was done to investigate the efficiency of harvestable biofuel products. A nutrient solution containing glucose as an energy source was used as the initial feed solution, and the potential substitution of the glucose solution with the organic carbon residue from the duckweed digester effluent was investigated. Methane production, carbon stabilization, and gas composition results from the duckweed fed anaerobic digesters, and the growth and biolipid production of heterotrophic micro-algae fed pure substrate versus residual digester effluent carbon are discussed in detail in this study.

  15. Enabling iron pyrite (FeS2) and related ternary pyrite compounds for high-performance solar energy applications

    NASA Astrophysics Data System (ADS)

    Caban Acevedo, Miguel

    The success of solar energy technologies depends not only on highly efficient solar-to-electrical energy conversion, charge storage or chemical fuel production, but also on dramatically reduced cost, to meet the future terawatt energy challenges we face. The enormous scale involved in the development of impactful solar energy technologies demand abundant and inexpensive materials, as well as energy-efficient and cost-effective processes. As a result, the investigation of semiconductor, catalyst and electrode materials made of earth-abundant and sustainable elements may prove to be of significant importance for the long-term adaptation of solar energy technologies on a larger scale. Among earth-abundant semiconductors, iron pyrite (cubic FeS2) has been considered the most promising solar energy absorber with the potential to achieve terawatt energy-scale deployment. Despite extensive synthetic progress and device efforts, the solar conversion efficiency of iron pyrite has remained below 3% since the 1990s, primarily due to a low open circuit voltage (V oc). The low photovoltage (Voc) of iron pyrite has puzzled scientists for decades and limited the development of cost-effective solar energy technologies based on this otherwise promising semiconductor. Here I report a comprehensive investigation of the syntheses and properties of iron pyrite materials, which reveals that the Voc of iron pyrite is limited by the ionization of a high density of intrinsic bulk defect states despite high density surface states and strong surface Fermi level pinning. Contrary to popular belief, bulk defects most-likely caused by intrinsic sulfur vacancies in iron pyrite must be controlled in order to enable this earth-abundant semiconductor for cost-effective and sustainable solar energy conversion. Lastly, the investigation of iron pyrite presented here lead to the discovery of ternary pyrite-type cobalt phosphosulfide (CoPS) as a highly-efficient earth-abundant catalyst material for electrochemical and solar energy driven hydrogen production.

  16. Solar cosmic ray composition above 10 MeV/nucleon and its energy dependence in the 4 August 1972 event. [including proton, helium, and Fe-group nuclei fluxes

    NASA Technical Reports Server (NTRS)

    Bertsch, D. L.; Biswas, S.; Reames, D. V.

    1974-01-01

    Observations of the proton, helium (C,N,O) and Fe-group nuclei fluxes made during the large 4 August 1972 solar particle event are presented. The results show a small, but significant variation of the composition of multicharged nuclei as a function of energy in the energy region above 10 MeV/nucleon. In particular, the He/(C,N,O) abundance ratio varies by a factor approximately 2 between 10 and 50 MeV/nucleon, and the Fe-group/(C,N,O) ratio suggests a similar variation. Abundance ratios from the 4 August 1972 event are compared as a function of energy with ratios measured in other solar events. At energies approximately greater than 50 MeV/nucleon, the He/(C,N,O) abundance ratio for August 1972 is consistent with all earlier measurements made above that energy.

  17. Photoelectric absorption cross sections with variable abundances

    NASA Technical Reports Server (NTRS)

    Balucinska-Church, Monika; Mccammon, Dan

    1992-01-01

    Polynomial fit coefficients have been obtained for the energy dependences of the photoelectric absorption cross sections of 17 astrophysically important elements. These results allow the calculation of X-ray absorption in the energy range 0.03-10 keV in material with noncosmic abundances.

  18. An Overview of Opportunities for Waste Heat Recovery and Thermal Integration in the Primary Aluminum Industry

    NASA Astrophysics Data System (ADS)

    Nowicki, Cassandre; Gosselin, Louis

    2012-08-01

    Efficient smelters currently consume roughly 13 MWh of electricity per ton of aluminum, while roughly half of that energy is lost as thermal waste. Although waste heat is abundant, current thermal integration in primary aluminum facilities remains limited. This is due to both the low quality of waste heat available and the shortage of potential uses within reasonable distance of identified waste heat sources. In this article, we present a mapping of both heat dissipation processes and heat demands around a sample facility (Alcoa Deschambault Quebec smelter). Our primary aim is to report opportunities for heat recovery and integration in the primary aluminum industry. We consider potential heat-to-sink pairings individually and assess their thermodynamic potential for producing energy savings.

  19. Industries in space to benefit mankind: A view over the next 30 years

    NASA Technical Reports Server (NTRS)

    1977-01-01

    New products, services, and energy sources are available to man through the exploitation of the useful attributes of space and space shuttle operations. Benefits include: (1) industrial fuel conservation through the use of electronic teleconferencing, high temperature turbines, and the space processing of materials; (2) improved health care through the use of biotelemetry, teleoperators, and weightless hospitals; (3) more efficient communication systems such as portable telephones, individual warning devices, and direct satellite broadcasting for educational purposes; (4) more abundant crop growth and controlled climate modification by the use of space-based reflectors to direct the light of the sun and moon to specific areas on earth; (5) solar energy utilization; and (6) reduction in radiation hazards through the use of space-based nuclear fusion reactors.

  20. Major role of nitrite-oxidizing bacteria in dark ocean carbon fixation

    NASA Astrophysics Data System (ADS)

    Pachiadaki, Maria G.; Sintes, Eva; Bergauer, Kristin; Brown, Julia M.; Record, Nicholas R.; Swan, Brandon K.; Mathyer, Mary Elizabeth; Hallam, Steven J.; Lopez-Garcia, Purificacion; Takaki, Yoshihiro; Nunoura, Takuro; Woyke, Tanja; Herndl, Gerhard J.; Stepanauskas, Ramunas

    2017-11-01

    Carbon fixation by chemoautotrophic microorganisms in the dark ocean has a major impact on global carbon cycling and ecological relationships in the ocean’s interior, but the relevant taxa and energy sources remain enigmatic. We show evidence that nitrite-oxidizing bacteria affiliated with the Nitrospinae phylum are important in dark ocean chemoautotrophy. Single-cell genomics and community metagenomics revealed that Nitrospinae are the most abundant and globally distributed nitrite-oxidizing bacteria in the ocean. Metaproteomics and metatranscriptomics analyses suggest that nitrite oxidation is the main pathway of energy production in Nitrospinae. Microautoradiography, linked with catalyzed reporter deposition fluorescence in situ hybridization, indicated that Nitrospinae fix 15 to 45% of inorganic carbon in the mesopelagic western North Atlantic. Nitrite oxidation may have a greater impact on the carbon cycle than previously assumed.

  1. Solar Energy and the Western Asian Countries

    NASA Astrophysics Data System (ADS)

    De Morais Mendonca Teles, Antonio

    2016-07-01

    The Western Asian countries receive the most abundant solar radiation of the world. They also have enormous reserves of oil and natural gas. But the world reserves of those fuels will certainly diminish greatly as the worldwide demand for energy will increase steadily in the coming decades. And the suppliers of energy will have to contend with public concerns about the polluting effects of those fuels and the possible dangers of nuclear energy. Clearly a power source based on an non exhaustible and non-polluting fuel could be expected to find a role. It now appears that such a source is at hand in the solar energy. Here in this paper, under the principles in the United Nations' Agenda 21, we suggest to Western Asian countries, the study and own development of the following technologies based on solar energy; and comment about them: *photo-voltaic solar cell power plants - in the future, its cost per kilowatt-hour will probably be competitive as to other sources of electrical energy. A new technique, the solar non-imaging concentrator, with amorphous silicon-based thin films solar cells at the focus of the concentrators, can collect and intensify solar radiation far better than conventional concentrators do, thus reducing much more the cost; *bio-gas - using biological gas to produce energy and for heating/cooling purposes; *wind generation of electricity - it's nowadays, a non-expensive technique; *water pump for irrigation and human consuming, driving their power from photovoltaic cells; *and the study and own development of solar lasers for peaceful scientific studies. In this new kind of laser, the external necessary pumping energy comes from the high intensity of sunlight, produced with non-imaging concentrators. Solar lasers can give unexpected new great uses for mankind. Those achievements will require international cooperation and transfer of information, sustained research and development work, and some initial subsides by independent governments. Solar energy is in disposition of all human beings for their social and economical better development - in particular of the Western Asian countries - and for the energetic auto-sufficiency of all peoples of our home planet. So, the use of solar energy must be accessible to all peoples on Earth.

  2. How can small hydro energy and other renewable energy mitigate impact of climate change in remote Central Africa: Cameroon case study.

    NASA Astrophysics Data System (ADS)

    Kenfack, Joseph; Bignom, Blaise

    2015-04-01

    Central Africa owns important renewable energy potential, namely hydro, solar and biomass. This important potential is still suffering from poor development up to the point where the sub region is still abundantly using the fossil energy and biomass as main power source. This is harmful to the climate and the situation is still ongoing. The main cause of the poor use of renewable energy is the poor management of resources by governments who have not taken the necessary measures to boost the renewable energy sector. Since the region is experiencing power shortage, thermal plants are among other solutions planned or under construction. Firewood is heavily used in remote areas without a sustainability program behind. This solution is not environment friendly and hence is not a long term solution. Given the fact that the region has the highest hydro potential of the continent, up to one-quarter of the world's tropical forest, important oil production with poor purchase power, the aim of this paper is to identify actions for improved access to sustainable, friendly, affordable energy services to users as well as a significant improvement of energy infrastructure in Central Africa and the promotion of small hydro and other renewable energy. The work will show at first the potential for the three primary energy sources which are solar, biomass and hydro while showing where available the level of development, with an emphasis on small hydro. Then identified obstacles for the promotion of clean energy will be targeted. From lessons learned, suggestions will be made to help the countries develop an approach aiming at developing good clean energy policy to increase the status of renewable energy and better contribute to fight against climate change. Cameroon has a great renewable energy potential and some data are available on energy. From the overview of institutional structure reform of the Cameroon power sector and assessments, specific suggestions based on the weaknesses of the current management of renewable energy sources will be made for the enhancement of the renewable energy and hence sustain energy access and security in general and in remote areas in particular where the fight against poverty is more difficult. We will use several documents, soft and hard from institutions in the region and abroad, and maps when available. |End Text|

  3. Modern Progress and Modern Problems in High Resolution X-ray Absorption from the Cold Interstellar Medium

    NASA Astrophysics Data System (ADS)

    Corrales, Lia; Li, Haochuan; Heinz, Sebastian

    2018-01-01

    With accurate cross-sections and higher signal-to-noise, X-ray spectroscopy can directly measure Milky Way gas and dust-phase metal abundances with few underlying assumptions. The X-ray energy band is sensitive to absorption by all abundant interstellar metals — carbon, oxygen, neon, silicon, magnesium, and iron — whether they are in gas or dust form. High resolution X-ray spectra from Galactic X-ray point sources can be used to directly measure metal abundances from all phases of the interstellar medium (ISM) along singular sight lines. We show our progress for measuring the depth of photoelectric absorption edges from neutral ISM metals, using all the observations of bright Galactic X-ray binaries available in the Chandra HETG archive. The cross-sections we use take into account both the absorption and scattering effects by interstellar dust grains on the iron and silicate spectral features. However, there are many open problems for reconciling X-ray absorption spectroscopy with ISM observations in other wavelengths. We will review the state of the field, lab measurements needed, and ways in which the next generation of X-ray telescopes will contribute.

  4. An astrophysical engine that stores gravitational work as nuclear Coulomb energy

    NASA Astrophysics Data System (ADS)

    Clayton, Donald

    2014-03-01

    I describe supernovae gravity machines that store large internal nuclear Coulomb energy, 0.80Z2A- 1 / 3MeV per nucleus. Excess of it is returned later by electron capture and positron emission. Decay energy manifests as (1) observable gamma-ray lines (2) light curves of supernovae (3) chemical energy of free carbon dissociated from CO molecules (4) huge abundances of radiogenic daughters. I illustrate by rapid silicon burning, a natural epoch in SN II. Gravitational work produces the high temperatures that photoeject nucleons and alpha particles from heavy nuclei. These are retained by other nuclei to balance photoejection rates (quasiequilibrium). The abundance distribution adjusts slowly as remaining abundance of Z = N 28Si decomposes, so p, n, α recaptures hug the Z = N line. This occurs in milliseconds, too rapidly for weak decay to alter bulk Z/N ratio. The figure displays those quasiequilibrium abundances color-coded to their decays. Z = N = 2k nuclei having k < 11 are stable, whereas k > 10 are radioactive owing to excess Coulomb energy. Weak decays radiate that excess energy weeks later to fuel the four macroscopic energetic phenomena cited. How startling to think of the Coulomb nuclear force as storing cosmic energy and its weak decay releasing macroscopic activation to SNII.

  5. Enrichment of very heavy nuclei in the composition of solar accelerated particles.

    NASA Technical Reports Server (NTRS)

    Mogro-Campero, A.; Simpson, J. A.

    1972-01-01

    Measurement of the abundances of the nuclei C, N, O, Ne, Mg, Si, Ar, and Ca and the group Cr-Co relative to oxygen from seven solar energetic-particle events in the energy range from about 14 to 61 MeV per nucleon with a solid-state detector telescope on the OGO-5 satellite, 1968-1971. The differential energy spectra of O (14 to 29 MeV per nucleon) and Cr-Co (3 to 61 MeV per nucleon) have a spectral index of about (-3) for a power law in kinetic energy. The relative abundances of C, N, O, and Ne are in excellent agreement with emulsion studies. However, when compared with the solar photospheric and coronal abundances, the OGO-5 measurements show a large enhancement of relative abundances beginning with Si, and extending to the Cr-Co group. The enhancement over the solar and universal abundances is in rough agreement with the composition of the galactic cosmic radiation.

  6. Lake whitefish diet, condition, and energy density in Lake Champlain and the lower four Great Lakes following dreissenid invasions

    USGS Publications Warehouse

    Herbst, Seth J.; Marsden, J. Ellen; Lantry, Brian F.

    2013-01-01

    Lake Whitefish Coregonus clupeaformis support some of the most valuable commercial freshwater fisheries in North America. Recent growth and condition decreases in Lake Whitefish populations in the Great Lakes have been attributed to the invasion of the dreissenid mussels, zebra mussels Dreissena polymorpha and quagga mussels D. bugensis, and the subsequent collapse of the amphipod, Diporeia, a once-abundant high energy prey source. Since 1993, Lake Champlain has also experienced the invasion and proliferation of zebra mussels, but in contrast to the Great Lakes, Diporeia were not historically abundant. We compared the diet, condition, and energy density of Lake Whitefish from Lake Champlain after the dreissenid mussel invasion to values for those of Lake Whitefish from Lakes Michigan, Huron, Erie, and Ontario. Lake Whitefish were collected using gill nets and bottom trawls, and their diets were quantified seasonally. Condition was estimated using Fulton's condition factor (K) and by determining energy density. In contrast to Lake Whitefish from some of the Great Lakes, those from Lake Champlain Lake Whitefish did not show a dietary shift towards dreissenid mussels, but instead fed primarily on fish eggs in spring, Mysis diluviana in summer, and gastropods and sphaeriids in fall and winter. Along with these dietary differences, the condition and energy density of Lake Whitefish from Lake Champlain were high compared with those of Lake Whitefish from Lakes Michigan, Huron, and Ontario after the dreissenid invasion, and were similar to Lake Whitefish from Lake Erie; fish from Lakes Michigan, Huron, and Ontario consumed dreissenids, whereas fish from Lake Erie did not. Our comparisons of Lake Whitefish populations in Lake Champlain to those in the Great Lakes indicate that diet and condition of Lake Champlain Lake Whitefish were not negatively affected by the dreissenid mussel invasion.

  7. Dehalococcoides abundance and alternate electron acceptor effects on large, flow-through trichloroethene dechlorinating columns.

    PubMed

    Mirza, Babur S; Sorensen, Darwin L; Dupont, R Ryan; McLean, Joan E

    2016-03-01

    Trichloroethene (TCE) in groundwater is a major health concern and biostimulation/bioaugmentation-based strategies have been evaluated to achieve complete reductive dechlorination with varying success. Different carbon sources were hypothesized to stimulate different extents of TCE reductive dechlorination. Ecological conditions that developed different dechlorination stages were investigated by quantitating Dehalococcoides 16S rRNA (Dhc) and reductive dehalogenase gene abundance, and by describing biogeochemical properties of laboratory columns in response to this biostimulation. Eight large columns (183 cm × 15.2 cm), packed with aquifer material from Hill AFB, Utah, that were continuously fed TCE for 7.5 years. Duplicate columns were biostimulated with whey or one of two different Newman Zone® emulsified oil formulations containing either nonionic surfactant (EOLN) or standard surfactant (EOL). Two columns were non-stimulated controls. Complete (whey amended), partial (EOLN amended), limited (EOL), and non-TCE dehalogenating systems (controls) developed over the course of the study. Bioaugmentation of half of the columns with Bachman Road culture 3 years prior to dismantling did not influence the extent of TCE dehalogenation. Multivariate analysis clustered samples by biostimulation treatments and extent of TCE dehalogenation. Dhc, tceA, and bvcA gene concentrations did not show a consistent relationship with TCE dehalogenation but the vcrA gene was more abundant in completely dehalogenating, whey-treated columns. The whey columns developed strongly reducing conditions producing Fe(II), sulfide, and methane. Biostimulation with different carbon and energy sources can support high concentrations of diverse Dhc, but carbon addition has a major influence on biogeochemical processes effecting the extent of TCE dehalogenation.

  8. Carbon analyses of IDP's sectioned in sulfur and supported on beryllium films

    NASA Technical Reports Server (NTRS)

    Bradley, J. P.; Keller, L.; Thomas, K. L.; Vanderwood, T. B.; Brownlee, D. E.

    1993-01-01

    Carbon is the only major element in interplanetary dust whose abundance, distribution and chemical state are not well understood. Information about carbon could clarify the relationship between the various classes of IDP's, conventional meteorites, and sources (e.g., comets vs. asteroids). To date, the most reliable estimates of C abundance in Interplanetary Dust Particles (IDP's) have been obtained by analyzing particles on thick-flat Be substrates using thin-window energy-dispersive spectroscopy in the SEM. These estimates of C abundance are valid only if C is homogeneously distributed, because detected C x-rays originate from the outer 0.1 micrometers of the particle. An alternative and potentially more accurate method of measuring C abundances is to analyze multiple thin sections (each less than 0.1 less than 0.1 micrometers thick) of IDP's. These efforts however, have been stymied because of a lack of a suitable non-carbonaceous embedding medium and the availability of C-free conductive substrates. We have embedded and thin-sectioned IDP's in glassy sulfur, and transferred the thin sections to Be support films approximately 25 nm thick. The sections were then analyzed in a 200 KeV analytical TEM. S sublimes rapidly under vacuum in the TEM, leaving non-embedded sections supported on Be. Apart from quantitative C (and O) analyses, S sectioning dramatically expands the range of analytical measurements that can be performed on a single IDP.

  9. Laser ion source for isobaric heavy ion collider experiment.

    PubMed

    Kanesue, T; Kumaki, M; Ikeda, S; Okamura, M

    2016-02-01

    Heavy-ion collider experiment in isobaric system is under investigation at Relativistic Heavy Ion Collider. For this experiment, ion source is required to maximize the abundance of the intended isotope. The candidate of the experiment is (96)Ru + (96)Zr. Since the natural abundance of particular isotope is low and composition of isotope from ion source depends on the composites of the target, an isotope enriched material may be needed as a target. We studied the performance of the laser ion source required for the experiment for Zr ions.

  10. Enhanced agarose and xylan degradation for production of polyhydroxyalkanoates by co-culture of marine bacterium, Saccharophagus degradans and its contaminant, Bacillus cereus

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sawant, Shailesh S.; Salunke, Bipinchandra K.; Taylor, II, Larry E.

    Over reliance on energy or petroleum products has raised concerns both in regards to the depletion of their associated natural resources as well as their increasing costs. Bioplastics derived from microbes are emerging as promising alternatives to fossil fuel derived petroleum plastics. The development of a simple and eco-friendly strategy for bioplastic production with high productivity and yield, which is produced in a cost effective manner utilising abundantly available renewable carbon sources, would have the potential to result in an inexhaustible global energy source. Here we report the biosynthesis of bioplastic polyhydroxyalkanoates (PHAs) in pure cultures of marine bacterium, Saccharophagusmore » degradans 2-40 ( Sde 2-40), its contaminant, Bacillus cereus, and a co-culture of these bacteria ( Sde 2-40 and B. cereus) degrading plant and algae derived complex polysaccharides. Sde 2-40 degraded the complex polysaccharides agarose and xylan as sole carbon sources for biosynthesis of PHAs. The ability of Sde 2-40 to degrade agarose increased after co-culturing with B. cereus. The association of Sde 2-40 with B. cereus resulted in increased cell growth and higher PHA production (34.5% of dry cell weight) from xylan as a carbon source in comparison to Sde 2-40 alone (22.7% of dry cell weight). Lastly, the present study offers an innovative prototype for production of PHA through consolidated bioprocessing of complex carbon sources by pure and co-culture of microorganisms.« less

  11. Enhanced agarose and xylan degradation for production of polyhydroxyalkanoates by co-culture of marine bacterium, Saccharophagus degradans and its contaminant, Bacillus cereus

    DOE PAGES

    Sawant, Shailesh S.; Salunke, Bipinchandra K.; Taylor, II, Larry E.; ...

    2017-02-28

    Over reliance on energy or petroleum products has raised concerns both in regards to the depletion of their associated natural resources as well as their increasing costs. Bioplastics derived from microbes are emerging as promising alternatives to fossil fuel derived petroleum plastics. The development of a simple and eco-friendly strategy for bioplastic production with high productivity and yield, which is produced in a cost effective manner utilising abundantly available renewable carbon sources, would have the potential to result in an inexhaustible global energy source. Here we report the biosynthesis of bioplastic polyhydroxyalkanoates (PHAs) in pure cultures of marine bacterium, Saccharophagusmore » degradans 2-40 ( Sde 2-40), its contaminant, Bacillus cereus, and a co-culture of these bacteria ( Sde 2-40 and B. cereus) degrading plant and algae derived complex polysaccharides. Sde 2-40 degraded the complex polysaccharides agarose and xylan as sole carbon sources for biosynthesis of PHAs. The ability of Sde 2-40 to degrade agarose increased after co-culturing with B. cereus. The association of Sde 2-40 with B. cereus resulted in increased cell growth and higher PHA production (34.5% of dry cell weight) from xylan as a carbon source in comparison to Sde 2-40 alone (22.7% of dry cell weight). Lastly, the present study offers an innovative prototype for production of PHA through consolidated bioprocessing of complex carbon sources by pure and co-culture of microorganisms.« less

  12. Topics in gamma ray astronomy

    NASA Technical Reports Server (NTRS)

    Ramaty, R.; Lingenfelter, R. E.

    1986-01-01

    Observations of gamma rays from solar flares, gamma ray bursts, the Galactic center, galactic nucleosynthesis, SS433, and Cygnus X-3, and their effects on astrophysical problems are discussed. It is observed that gamma ray spectra from solar flares are applicable to the study of particle acceleration and confinement and the determination of chemical abundances in the solar atmosphere. The gamma ray lines from the compact galactic object SS433 are utilized to examine the acceleration of jets, and analysis of the gamma ray lines of Cygnus X-3 reveal that particles can be accelerated in compact sources to ultrahigh energies.

  13. Manufacturing with the Sun

    NASA Astrophysics Data System (ADS)

    Murphy, Lawrence M.; Hauser, Steven G.; Clyne, Richard J.

    1991-12-01

    Concentrated solar radiation is now a viable alternative source for many advanced manufacturing processes. Researchers at the National Renewable Energy Laboratory (NREL) have demonstrated the feasibility of processes such as solar induced surface transformation of materials (SISTM), solar based manufacturing, and solar pumped lasers. Researchers are also using sunlight to decontaminate water and soils polluted with organic compounds; these techniques could provide manufacturers with innovative alternatives to traditional methods of waste management. The solar technology that is now being integrated into today's manufacturing processes offer greater potential for tomorrow, especially as applied to the radiation abundant environment available in space and on the lunar surface.

  14. Manufacturing with the Sun

    NASA Technical Reports Server (NTRS)

    Murphy, Lawrence M.; Hauser, Steven G.; Clyne, Richard J.

    1991-01-01

    Concentrated solar radiation is now a viable alternative source for many advanced manufacturing processes. Researchers at the National Renewable Energy Laboratory (NREL) have demonstrated the feasibility of processes such as solar induced surface transformation of materials (SISTM), solar based manufacturing, and solar pumped lasers. Researchers are also using sunlight to decontaminate water and soils polluted with organic compounds; these techniques could provide manufacturers with innovative alternatives to traditional methods of waste management. The solar technology that is now being integrated into today's manufacturing processes offer greater potential for tomorrow, especially as applied to the radiation abundant environment available in space and on the lunar surface.

  15. Bioenergy Technologies Office FY 2017 Budget At-A-Glance

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    2016-03-01

    The Bioenergy Technologies Office (BETO) is accelerating the commercialization of first-of-a-kind technologies that use our nation’s abundant renewable biomass resources for the production of advanced biofuels and biobased products. Non-food sources of biomass, such as algae, agricultural residues and forestry trimmings, and energy crops like switchgrass, are being used in BETO-supported, cutting-edge technologies to produce drop-in biofuels, including renewable gasoline, diesel, and jet fuels. BETO is also investigating how to improve the economics of biofuel production by converting biomass into higher-value chemicals and products that historically have always been derived from petroleum.

  16. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wieser, Patti; Hopkins, David

    The DOE Princeton Plasma Physics Laboratory (PPPL) collaborates to develop fusion as a safe, clean and abundant energy source for the future. This video discusses PPPL's research and development on plasma, the fourth state of matter. In this simulation of plasma turbulence inside PPPL's National Spherical Torus Experiment, the colorful strings represent higher and lower electron density in turbulent plasma as it circles around a donut-shaped fusion reactor; red and orange are higher density. This image is among those featured in the slide show, "Plasmas are Hot and Fusion is Cool," a production of PPPL and the Princeton University Broadcastmore » Center.« less

  17. Cold dark energy constraints from the abundance of galaxy clusters

    DOE PAGES

    Heneka, Caroline; Rapetti, David; Cataneo, Matteo; ...

    2017-10-05

    We constrain cold dark energy of negligible sound speed using galaxy cluster abundance observations. In contrast to standard quasi-homogeneous dark energy, negligible sound speed implies clustering of the dark energy fluid at all scales, allowing us to measure the effects of dark energy perturbations at cluster scales. We compare those models and set the stage for using non-linear information from semi-analytical modelling in cluster growth data analyses. For this, we recalibrate the halo mass function with non-linear characteristic quantities, the spherical collapse threshold and virial overdensity, that account for model and redshift-dependent behaviours, as well as an additional mass contributionmore » for cold dark energy. Here in this paper, we present the first constraints from this cold dark matter plus cold dark energy mass function using our cluster abundance likelihood, which self-consistently accounts for selection effects, covariances and systematic uncertainties. We combine cluster growth data with cosmic microwave background, supernovae Ia and baryon acoustic oscillation data, and find a shift between cold versus quasi-homogeneous dark energy of up to 1σ. We make a Fisher matrix forecast of constraints attainable with cluster growth data from the ongoing Dark Energy Survey (DES). For DES, we predict ~ 50 percent tighter constraints on (Ωm, w) for cold dark energy versus wCDM models, with the same free parameters. Overall, we show that cluster abundance analyses are sensitive to cold dark energy, an alternative, viable model that should be routinely investigated alongside the standard dark energy scenario.« less

  18. Cold dark energy constraints from the abundance of galaxy clusters

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Heneka, Caroline; Rapetti, David; Cataneo, Matteo

    We constrain cold dark energy of negligible sound speed using galaxy cluster abundance observations. In contrast to standard quasi-homogeneous dark energy, negligible sound speed implies clustering of the dark energy fluid at all scales, allowing us to measure the effects of dark energy perturbations at cluster scales. We compare those models and set the stage for using non-linear information from semi-analytical modelling in cluster growth data analyses. For this, we recalibrate the halo mass function with non-linear characteristic quantities, the spherical collapse threshold and virial overdensity, that account for model and redshift-dependent behaviours, as well as an additional mass contributionmore » for cold dark energy. Here in this paper, we present the first constraints from this cold dark matter plus cold dark energy mass function using our cluster abundance likelihood, which self-consistently accounts for selection effects, covariances and systematic uncertainties. We combine cluster growth data with cosmic microwave background, supernovae Ia and baryon acoustic oscillation data, and find a shift between cold versus quasi-homogeneous dark energy of up to 1σ. We make a Fisher matrix forecast of constraints attainable with cluster growth data from the ongoing Dark Energy Survey (DES). For DES, we predict ~ 50 percent tighter constraints on (Ωm, w) for cold dark energy versus wCDM models, with the same free parameters. Overall, we show that cluster abundance analyses are sensitive to cold dark energy, an alternative, viable model that should be routinely investigated alongside the standard dark energy scenario.« less

  19. Diet-induced obesity, energy metabolism and gut microbiota in C57BL/6J mice fed Western diets based on lean seafood or lean meat mixtures.

    PubMed

    Holm, Jacob Bak; Rønnevik, Alexander; Tastesen, Hanne Sørup; Fjære, Even; Fauske, Kristin Røen; Liisberg, Ulrike; Madsen, Lise; Kristiansen, Karsten; Liaset, Bjørn

    2016-05-01

    High protein diets may protect against diet-induced obesity, but little is known regarding the effects of different protein sources consumed at standard levels. We investigated how a mixture of lean seafood or lean meat in a Western background diet modulated diet-induced obesity, energy metabolism and gut microbiota. Male C57BL/6J mice fed a Western diet (WD) containing a mixture of lean seafood (seafood WD) for 12weeks accumulated less fat mass than mice fed a WD containing a mixture of lean meat (meat WD). Meat WD-fed mice exhibited increased fasting blood glucose, impaired glucose clearance, elevated fasting plasma insulin and increased plasma and liver lipid levels. We observed no first choice preference for either of the WDs, but over time, mice fed the seafood WD consumed less energy than mice fed the meat WD. Mice fed the seafood WD exhibited higher spontaneous locomotor activity and a lower respiratory exchange ratio (RER) than mice fed the meat WD. Thus, higher activity together with the decreased energy intake contributed to the different phenotypes observed in mice fed the seafood WD compared to mice fed the meat WD. Comparison of the gut microbiomes of mice fed the two WDs revealed significant differences in the relative abundance of operational taxonomic units (OTUs) belonging to the orders Bacteroidales and Clostridiales, with genes involved in metabolism of aromatic amino acids exhibiting higher relative abundance in the microbiomes of mice fed the seafood WD. Copyright © 2016 Elsevier Inc. All rights reserved.

  20. The CNO Bi-cycle in the Open Cluster NGC 752

    NASA Astrophysics Data System (ADS)

    Hawkins, Keith; Schuler, S.; King, J.; The, L.

    2011-01-01

    The CNO bi-cycle is the primary energy source for main sequence stars more massive than the sun. To test our understanding of stellar evolution models using the CNO bi-cycle, we have undertaken light-element (CNO) abundance analysis of three main sequence dwarf stars and three red giant stars in the open cluster NGC 752 utilizing high resolution (R 50,000) spectroscopy from the Keck Observatory. Preliminary results indicate, as expected, there is a depletion of carbon in the giants relative to the dwarfs. Additional analysis is needed to determine if the amount of depletion is in line with model predictions, as seen in the Hyades open cluster. Oxygen abundances are derived from the high-excitation O I triplet, and there is a 0.19 dex offset in the [O/H] abundances between the giants and dwarfs which may be explained by non-local thermodynamic equilibrium (NLTE), although further analysis is needed to verify this. The standard procedure for spectroscopically determining stellar parameters used here allows for a measurement of the cluster metallicity, [Fe/H] = 0.04 ± 0.02. In addition to the Fe abundances we have determined Na, Mg, and Al abundances to determine the status of other nucleosynthesis processes. The Na, Mg and Al abundances of the giants are enhanced relative to the dwarfs, which is consistent with similar findings in giants of other open clusters. Support for K. Hawkins was provided by the NOAO/KPNO Research Experiences for Undergraduates (REU) Program which is funded by the National Science Foundation Research Experiences for Undergraduates Program and the Department of Defense ASSURE program through Scientific Program Order No. 13 (AST-0754223) of the Cooperative Agreement No. AST-0132798 between the Association of Universities for Research in Astronomy (AURA) and the NSF.

  1. Elemental Abundances of Ultra-Heavy Galactic Cosmic Rays from the SuperTIGER Instrument

    NASA Astrophysics Data System (ADS)

    Murphy, Ryan

    2016-07-01

    The SuperTIGER (Trans-Iron Galactic Element Recorder) experiment was launched on a long-duration balloon flight from Williams Field, Antarctica, on December 8, 2012. The instrument measured the relative elemental abundances of Galactic Cosmic Rays (GCR) for charge (Z) Z>10 with excellent charge resolution, displaying well resolved individual element peaks for 10 ≤ Z ≤ 40. During its record-breaking 55-day flight, SuperTIGER collected ˜4.73 x10^{6} Iron nuclei, ˜8 times as many as detected by its predecessor, TIGER, with charge resolution at iron of 0.17 cu. SuperTIGER measures charge (Z) and energy (E) using a combination of three scintillator and two Cherenkov detectors, and employs a scintillating fiber hodoscope for event trajectory determination. The SuperTIGER data have been analyzed to correct for instrument effects and remove events that underwent nuclear interactions within the instrument. The data include more than 600 events in the charge range 30 < Z ≤ 40. SuperTIGER is the first experiment to resolve elemental abundances of every element in this charge range with high statistics and single-element resolution. The relative abundances of the galactic cosmic ray source have been derived from the measured relative elemental abundances using atmospheric and interstellar propagations. The SuperTIGER measured abundances are generally consistent with previous experimental results from TIGER and ACE-CRIS, with improved statistical precision. The SuperTIGER results confirm the earlier results from TIGER, supporting a model of cosmic-ray origin in OB associations, with preferential acceleration of refractory elements over volatile elements ordered by atomic mass (A). A second SuperTIGER Antarctic flight is planned for December 2017. Details of the instrument, flight, data analysis, and ongoing preparations will be presented.

  2. Solar updraft power generator with radial and curved vanes

    NASA Astrophysics Data System (ADS)

    Hafizh, Hadyan; Hamsan, Raziff; Zamri, Aidil Azlan Ahmad; Keprawi, Mohamad Fairuz Mohamad; Shirato, Hiromichi

    2018-02-01

    Solar radiation is the largest source of energy available on earth and the solar updraft power generator (SUPG) is a renewable energy facility capable of harnessing its abundant power. Unlike the conventional wind turbines that harness natural wind in the atmosphere and often encounter with the intermittent issue or even complete cut-off from airflow, the SUPG creates artificial wind as a result of solar-induced convective flows. However, the SUPG has an inherent low total efficiency due to the conversion of thermal energy into pressure energy. Acknowledging the low efficiency and considering its potential as a renewable energy facility, the current work aims to increase the total efficiency by installing a series of guide walls inside the collector. Two types of guide walls were used i.e. radial and curved vanes. The result with curved vanes showed that the updraft velocity is higher compare to those without vanes. About 18% and 64% improvement of updraft velocity and mechanical power were attained respectively. Furthermore, it was observed that the role of radial vanes configuration was more to produce a smooth updraft velocity profile rather than increasing the total efficiency.

  3. Effect of Intrinsic Twist on Length of Crystalline and Disordered Regions in Cellulose Microfibrils

    NASA Astrophysics Data System (ADS)

    Nili, Abdolmadjid; Shklyaev, Oleg; Zhao, Zhen; Zhong, Linghao; Crespi, Vincent

    2013-03-01

    Cellulose is the most abundant biological material in the world. It provides mechanical reinforcement for plant cell wall, and could potentially serve as renewable energy source for biofuel. Native cellulose forms a non-centrosymmetric chiral crystal due to lack of roto-inversion symmetry of constituent glucose chains. Chirality of cellulose crystal could result in an overall twist. Competition between unwinding torsional/extensional and twisting energy terms leads to twist induced frustration along fibril's axis. The accumulated frustration could be the origin of periodic disordered regions observed in cellulose microfibrils. These regions could play significant role in properties of cellulose bundles and ribbons as well as biological implications on plant cell walls. We propose a mechanical model based on Frenkel-Kontorova mechanism to investigate effects of radius dependent twist on crystalline size in cellulose microfibrils. Parameters of the model are adjusted according to all-atom molecular simulations. This work is supported by the US Department of Energy, Office of Basic Energy Sciences as part of The Center for LignoCellulose Structure and Formation, an Energy Frontier Research Center

  4. Enhancement of solar heavy nuclei at high energies in the 4 July 1974 event

    NASA Technical Reports Server (NTRS)

    Bertsch, D. L.; Reames, D.

    1976-01-01

    Relative abundances of energetic nuclei in the 4 July 1974 solar event are presented. The results show a marked enhancement of abundances that systematically increase with nuclear charge numbers in the range of the observation, 6 less than or equal to Z less than or equal to 26 for energies above 15 MeV/nucleon. While such enhancements are commonly seen below 10 MeV/nucleon, most observations at higher energies are found to be consistent with solar system abundances. The energy spectrum of oxygen is observed to be significantly steeper than most other solar events studied in this energy region. It is proposed that these observations are characteristic of particle populations at energies approximately 1 MeV/nucleon, and that the anomalous features observed here may be the result of the high energy extension of such a population that is commonly masked by other processes or populations that might occur in larger solar events.

  5. Fission Signatures for Nuclear Material Detection

    NASA Astrophysics Data System (ADS)

    Gozani, Tsahi

    2009-06-01

    Detection and interdiction of nuclear materials in all forms of transport is one of the most critical security issues facing the United States and the rest of the civilized world. Naturally emitted gamma rays by these materials, while abundant and detectable when unshielded, are low in energy and readily shielded. X-ray radiography is useful in detecting the possible presence of shielding material. Positive detection of concealed nuclear materials requires methods which unequivocally detect specific attributes of the materials. These methods typically involve active interrogation by penetrating radiation of neutrons, photons or other particles. Fortunately, nuclear materials, probed by various types of radiation, yield very unique and often strong signatures. Paramount among them are the detectable fission signatures, namely prompt neutrons and gamma rays, and delayed neutrons gamma rays. Other useful signatures are the nuclear states excited by neutrons, via inelastic scattering, or photons, via nuclear resonance fluorescence and absorption. The signatures are very different in magnitude, level of specificity, ease of excitation and detection, signal to background ratios, etc. For example, delayed neutrons are very unique to the fission process, but are scarce, have low energy, and hence are easily absorbed. Delayed gamma rays are more abundant but "featureless", and have a higher background from natural sources and more importantly, from activation due to the interrogation sources. The prompt fission signatures need to be measured in the presence of the much higher levels of probing radiation. This requires taking special measures to look for the signatures, sometimes leading to a significant sensitivity loss or a complete inability to detect them. Characteristic gamma rays induced in nuclear materials reflecting their nuclear structure, while rather unique, require very high intensity of interrogation radiation and very high resolution in energy and/or time. The trade off of signatures, their means of stimulation, and methods of detection, will be reviewed.

  6. Conditions on Early Mars Might Have Fostered Rapid and Early Development of Life

    NASA Technical Reports Server (NTRS)

    Gibson, Everett K.; McKay, David S.; Thomas-Keprta, Kathie L.; Clemett, Simon J.; Wentworth, Susan J.

    2007-01-01

    The exploration of Mars during the past decades has begun to unveil the history of the planet. The combinations of remote sensing, in situ geochemical compositional measurements and photographic observations from both above and on the surface have shown Mars to have a dynamic and active geologic evolution. Mars geologic evolution clearly had conditions that were suitable for supporting life. For a planet to be able to be habitable, it must have water, carbon sources, energy sources and a dynamic geologic past. Mars meets all of these requirements. The first 600 My of Martian history were ripe for life to develop because of the abundance of (i) Water-carved canyons and oceans or lakes with the early presence of near surface water shown by precipitated carbonates in ALH84001 well-dated at approx.3.9 Gy., (ii) Energy from the original accretional processes, a molten core which generated a strong magnetic field leaving a permanent record in the early crust, early active volcanism continuing throughout Martian history, and, and continuing impact processes, (iii) Carbon and water from possibly extensive volcanic outgassing (i.e. H2O, CO2, CH4, CO, O2, N2, H2S, SO2, etc.) and (iv) some crustal tectonics as revealed by faulting and possible plate movement reflected by the magnetic pattern in the crust. The question arises: "Why would life not evolve from these favorable conditions on early Mars in its first 600 My?" During this period, it seems likely that environmental near-surface conditions on Mars were more favorable to life than at any later time. Standing bodies of water, precipitation and flowing surface water, and possibly abundant hydrothermal energy would all favor the formation of early life. Even if life developed elsewhere (on Earth, Venus, or on other solar systems) and was transported to Mars, the surface conditions were likely very hospitable for that introduced life to multiply and evolve.

  7. Biomass production from electricity using ammonia as an electron carrier in a reverse microbial fuel cell.

    PubMed

    Khunjar, Wendell O; Sahin, Asli; West, Alan C; Chandran, Kartik; Banta, Scott

    2012-01-01

    The storage of renewable electrical energy within chemical bonds of biofuels and other chemicals is a route to decreasing petroleum usage. A critical challenge is the efficient transfer of electrons into a biological host that can covert this energy into high energy organic compounds. In this paper, we describe an approach whereby biomass is grown using energy obtained from a soluble mediator that is regenerated electrochemically. The net result is a separate-stage reverse microbial fuel cell (rMFC) that fixes CO₂ into biomass using electrical energy. We selected ammonia as a low cost, abundant, safe, and soluble redox mediator that facilitated energy transfer to biomass. Nitrosomonas europaea, a chemolithoautotroph, was used as the biocatalyst due to its inherent capability to utilize ammonia as its sole energy source for growth. An electrochemical reactor was designed for the regeneration of ammonia from nitrite, and current efficiencies of 100% were achieved. Calculations indicated that overall bioproduction efficiency could approach 2.7±0.2% under optimal electrolysis conditions. The application of chemolithoautotrophy for industrial bioproduction has been largely unexplored, and results suggest that this and related rMFC platforms may enable biofuel and related biochemical production.

  8. Biomass Production from Electricity Using Ammonia as an Electron Carrier in a Reverse Microbial Fuel Cell

    PubMed Central

    West, Alan C.; Chandran, Kartik; Banta, Scott

    2012-01-01

    The storage of renewable electrical energy within chemical bonds of biofuels and other chemicals is a route to decreasing petroleum usage. A critical challenge is the efficient transfer of electrons into a biological host that can covert this energy into high energy organic compounds. In this paper, we describe an approach whereby biomass is grown using energy obtained from a soluble mediator that is regenerated electrochemically. The net result is a separate-stage reverse microbial fuel cell (rMFC) that fixes CO2 into biomass using electrical energy. We selected ammonia as a low cost, abundant, safe, and soluble redox mediator that facilitated energy transfer to biomass. Nitrosomonas europaea, a chemolithoautotroph, was used as the biocatalyst due to its inherent capability to utilize ammonia as its sole energy source for growth. An electrochemical reactor was designed for the regeneration of ammonia from nitrite, and current efficiencies of 100% were achieved. Calculations indicated that overall bioproduction efficiency could approach 2.7±0.2% under optimal electrolysis conditions. The application of chemolithoautotrophy for industrial bioproduction has been largely unexplored, and results suggest that this and related rMFC platforms may enable biofuel and related biochemical production. PMID:23028643

  9. Structural Optimization of Triboelectric Nanogenerator for Harvesting Water Wave Energy.

    PubMed

    Jiang, Tao; Zhang, Li Min; Chen, Xiangyu; Han, Chang Bao; Tang, Wei; Zhang, Chi; Xu, Liang; Wang, Zhong Lin

    2015-12-22

    Ocean waves are one of the most abundant energy sources on earth, but harvesting such energy is rather challenging due to various limitations of current technologies. Recently, networks formed by triboelectric nanogenerator (TENG) have been proposed as a promising technology for harvesting water wave energy. In this work, a basic unit for the TENG network was studied and optimized, which has a box structure composed of walls made of TENG composed of a wavy-structured Cu-Kapton-Cu film and two FEP thin films, with a metal ball enclosed inside. By combination of the theoretical calculations and experimental studies, the output performances of the TENG unit were investigated for various structural parameters, such as the size, mass, or number of the metal balls. From the viewpoint of theory, the output characteristics of TENG during its collision with the ball were numerically calculated by the finite element method and interpolation method, and there exists an optimum ball size or mass to reach maximized output power and electric energy. Moreover, the theoretical results were well verified by the experimental tests. The present work could provide guidance for structural optimization of wavy-structured TENGs for effectively harvesting water wave energy toward the dream of large-scale blue energy.

  10. Life Cycle Analysis for the Feasibility of Photovoltaic System Application in Indonesia

    NASA Astrophysics Data System (ADS)

    Yudha, H. M.; Dewi, T.; Risma, P.; Oktarina, Y.

    2018-03-01

    Electricity has become the basic need for everyone, from industry to domestic. Today electricity source still depends heavily on fossil fuels that soon will be diminished from the earth in around 50 years. This condition demands us to find the renewable energy to support our everyday life. One of the famous renewable energy sources is from solar, harnessed by energy conversion device named solar cells. Countries like Indonesia are gifted with an abundance of sunlight all the yearlong. The application of solar cells with its photovoltaic (PV) technology harnesses the sunlight and converts it into electricity. Although this technology is emerging very fast, it still has some limitation due to the current PV technology, economic feasibility, and its environmental impacts. Life cycle assessment is the method to analyze and evaluate the sustainability of PV system and its environmental impact. This paper presents literature study of PV system from the cradle to grave, it begins with the material choices (from the first generation and the possibility of the fourth generation), manufacturing process, implementation, and ends it with the after-life effect of PV modules. The result of this study will be the insights look of the PV system application in Indonesia, from the best option of material choice, the best method of application, the energy payback time, and finally the possible after life recycle of PV materials.

  11. Characterization of Mars' seasonal caps using neutron spectroscopy

    USGS Publications Warehouse

    Prettyman, T.H.; Feldman, W.C.; Titus, T.N.

    2009-01-01

    Mars' seasonal caps are characterized during Mars years 26 and 27 (April 2002 to January 2006) using data acquired by the 2001 Mars Odyssey Neutron Spectrometer. Time-dependent maps of the column abundance of seasonal CO 2 surface ice poleward of 60?? latitude in both hemispheres are determined from spatially deconvolved, epithermal neutron counting data. Sources of systematic error are analyzed, including spatial blurring by the spectrometer's broad footprint and the seasonal variations in the abundance of noncondensable gas at high southern latitudes, which are found to be consistent with results reported by Sprague et al. (2004, 2007). Corrections for spatial blurring are found to be important during the recession, when the column abundance of seasonal CO2 ice has the largest latitude gradient. The measured distribution and inventory of seasonal CO2 ice is compared to simulations by a general circulation model (GCM) calibrated using Viking lander pressure data, cap edge functions determined by thermal emission spectroscopy, and other nuclear spectroscopy data sets. On the basis of the amount of CO2 cycled through the caps during years 26 and 27, the gross polar energy balance has not changed significantly since Viking. The distribution of seasonal CO2 ice is longitudinally asymmetric: in the north, deposition rates of CO2 ice are elevated in Acidalia, which is exposed to katabatic winds from Chasma Borealis; in the south, CO2 deposition is highest near the residual cap. During southern recession, CO 2 ice is present longer than calculated by the GCM, which has implications for the local polar energy balance. Copyright 2009 by the American Geophysical Union.

  12. Warmer and drier conditions and nitrogen fertilizer application altered methanotroph abundance and methane emissions in a vegetable soil.

    PubMed

    Ran, Yu; Xie, Jianli; Xu, Xiaoya; Li, Yong; Liu, Yapeng; Zhang, Qichun; Li, Zheng; Xu, Jianming; Di, Hongjie

    2017-01-01

    Methane (CH 4 ) is a potent greenhouse gas, and soil can both be a source and sink for atmospheric CH 4 . It is not clear how future climate change may affect soil CH 4 emissions and related microbial communities. The aim of this study was to determine the interactive effects of a simulated warmer and drier climate scenarios and the application of different nitrogen (N) sources (urea and manure) on CH 4 emissions and related microbial community abundance in a vegetable soil. Greenhouses were used to control simulated climate conditions which gave 2.99 °C warmer and 6.2% lower water content conditions. The field experiment was divided into two phases. At the beginning of phase II, half of the greenhouses were removed to study possible legacy effects of the simulated warmer and drier conditions. The responses in methanogen and methanotroph abundance to a simulated climate change scenario were determined using real-time PCR. The results showed that the simulated warmer and drier conditions in the greenhouses significantly decreased CH 4 emissions largely due to the lower soil moisture content. For the same reason, CH 4 emissions of treatments in phase I were much lower than the same treatments in phase II. The abundance of methanotrophs showed a more significant response than methanogens to the simulated climate change scenario, increasing under simulated drier conditions. Methanogenic community abundance remained low, except where manure was applied which provided a source of organic C that stimulated methanogen growth. Soil moisture content was a major driver for methanotroph abundance and strongly affected CH 4 emissions. The application of N source decreased CH 4 emissions probably because of increased methanotrophic activity. CH 4 emissions were positively correlated to methanogenic abundance and negatively correlated to methanotrophic abundance. These results demonstrate that projected future climate change conditions can have a feedback impact on CH 4 emissions from the soil by altering soil conditions (particularly soil moisture) and related microbial communities.

  13. Multiple scattering from icequakes at Erebus volcano, Antarctica: Implications for imaging at glaciated volcanoes

    NASA Astrophysics Data System (ADS)

    Chaput, J.; Campillo, M.; Aster, R. C.; Roux, P.; Kyle, P. R.; Knox, H.; Czoski, P.

    2015-02-01

    We examine seismic coda from an unusually dense deployment of over 100 short-period and broadband seismographs in the summit region of Mount Erebus volcano on a network with an aperture of approximately 5 km. We investigate the energy-partitioning properties of the seismic wavefield generated by thousands of small icequake sources originating on the upper volcano and use them to estimate Green's functions via coda cross correlation. Emergent coda seismograms suggest that this locale should be particularly amenable to such methods. Using a small aperture subarray, we find that modal energy partition between S and P wave energy between ˜1 and 4 Hz occurs in just a few seconds after event onset and persists for tens of seconds. Spatially averaged correlograms display clear body and surface waves that span the full aperture of the array. We test for stable bidirectional Green's function recovery and note that good symmetry can be achieved at this site even with a geographically skewed distribution of sources. We estimate scattering and absorption mean free path lengths and find a power law decrease in mean free path between 1.5 and 3.3 Hz that suggests a quasi-Rayleigh or Rayleigh-Gans scattering situation. Finally, we demonstrate the existence of coherent backscattering (weak localization) for this coda wavefield. The remarkable properties of scattered seismic wavefields in the vicinity of active volcanoes suggests that the abundant small icequake sources may be used for illumination where temporal monitoring of such dynamic structures is concerned.

  14. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Neilson, Hutch

    Nuclear fusion — the process that powers the sun — offers an environmentally benign, intrinsically safe energy source with an abundant supply of low-cost fuel. It is the focus of an international research program, including the ITER fusion collaboration, which involves seven parties representing half the world’s population. The realization of fusion power would change the economics and ecology of energy production as profoundly as petroleum exploitation did two centuries ago. The 21st century finds fusion research in a transformed landscape. The worldwide fusion community broadly agrees that the science has advanced to the point where an aggressive action plan,more » aimed at the remaining barriers to practical fusion energy, is warranted. At the same time, and largely because of its scientific advance, the program faces new challenges; above all it is challenged to demonstrate the timeliness of its promised benefits. In response to this changed landscape, the Office of Fusion Energy Sciences (OFES) in the US Department of Energy commissioned a number of community-based studies of the key scientific and technical foci of magnetic fusion research. The Research Needs Workshop (ReNeW) for Magnetic Fusion Energy Sciences is a capstone to these studies. In the context of magnetic fusion energy, ReNeW surveyed the issues identified in previous studies, and used them as a starting point to define and characterize the research activities that the advance of fusion as a practical energy source will require. Thus, ReNeW’s task was to identify (1) the scientific and technological research frontiers of the fusion program, and, especially, (2) a set of activities that will most effectively advance those frontiers. (Note that ReNeW was not charged with developing a strategic plan or timeline for the implementation of fusion power.)« less

  15. Mucin- and carbohydrate-stimulated adhesion and subproteome changes of the probiotic bacterium Lactobacillus acidophilus NCFM.

    PubMed

    Celebioglu, Hasan Ufuk; Olesen, Sita Vaag; Prehn, Kennie; Lahtinen, Sampo J; Brix, Susanne; Abou Hachem, Maher; Svensson, Birte

    2017-06-23

    Adhesion to intestinal mucosa is a crucial property for probiotic bacteria. Adhesion is thought to increase host-bacterial interactions, thus potentially enabling health benefits to the host. Molecular events connected with adhesion and surface proteome changes were investigated for the probiotic Lactobacillus acidophilus NCFM cultured with established or emerging prebiotic carbohydrates as carbon source and in the presence of mucin, the glycoprotein of the epithelial mucus layer. Variation in adhesion to HT29-cells and mucin was associated with carbon source and mucin-induced subproteome abundancy differences. Specifically, while growth on fructooligosaccharides (FOS) only stimulated adhesion to intestinal HT-29 cells, cellobiose and polydextrose in addition increased adhesion to mucin. Adhesion to HT-29 cells increased by about 2-fold for bacteria grown on mucin-supplemented glucose. Comparative 2DE-MS surface proteome analysis showed different proteins in energy metabolism appearing on the surface, suggesting they exert moonlighting functions. Mucin-supplemented bacteria had relative abundance of pyruvate kinase and fructose-bisphosphate aldolase increased by about 2-fold while six spots with 3.2-2.1 fold reduced relative abundance comprised elongation factor G, phosphoglycerate kinase, BipAEFTU family GTP-binding protein, ribonucleoside triphosphate reductase, adenylosuccinate synthetase, 30S ribosomal protein S1, and manganese-dependent inorganic pyrophosphatase. Surface proteome of cellobiose- compared to glucose-grown L. acidophilus NCFM had phosphate starvation inducible protein stress-related, thermostable pullulanase, and elongation factor G increasing 4.4-2.4 fold, while GAPDH, elongation factor Ts, and pyruvate kinase were reduced by 2.0-1.5 fold in relative abundance. Addition of recombinant L. acidophilus NCFM elongation factor G and pyruvate kinase to a coated mucin layer significantly suppressed subsequent adhesion of the bacterium. Human diet is important for intestinal health and food components, especially non-digestible carbohydrates can beneficially modify the microbiota. In the present study, effects of emerging and established prebiotic carbohydrates on the probiotic potential of Lactobacillus acidophilus NCFM were investigated by testing adhesion to a mucin layer and intestinal cells, and comparing this with changes in abundancy of surface proteins thought to be important for host interactions. Increased adhesion was observed following culturing of the bacterium with fructooligosaccharides, cellobiose or polydextrose, as well as mucin-supplemented glucose as carbon source. Enhanced adhesion ability can prolong bacterial residence in GIT yielding positive health effects. Higher relative abundance of certain surface proteins under various conditions (i.e. grown on cellobiose or mucin-supplemented glucose) suggested involvement of these proteins in adhesion, as confirmed by competition in case of two recombinantly produced moonlighting proteins. Combination of Lactobacillus acidophilus NCFM with different carbohydrates revealed potential bacterial determinants of synbiotic interactions, including stimulation of adhesion. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Electromagnetic diagnostics of ECR-Ion Sources plasmas: optical/X-ray imaging and spectroscopy

    NASA Astrophysics Data System (ADS)

    Mascali, D.; Castro, G.; Altana, C.; Caliri, C.; Mazzaglia, M.; Romano, F. P.; Leone, F.; Musumarra, A.; Naselli, E.; Reitano, R.; Torrisi, G.; Celona, L.; Cosentino, L. G.; Giarrusso, M.; Gammino, S.

    2017-12-01

    Magnetoplasmas in ECR-Ion Sources are excited from gaseous elements or vapours by microwaves in the range 2.45-28 GHz via Electron Cyclotron Resonance. A B-minimum, magnetohydrodynamic stable configuration is used for trapping the plasma. The values of plasma density, temperature and confinement times are typically ne= 1011-1013 cm-3, 01 eV

  17. Different land use intensities in grassland ecosystems drive ecology of microbial communities involved in nitrogen turnover in soil.

    PubMed

    Meyer, Annabel; Focks, Andreas; Radl, Viviane; Keil, Daniel; Welzl, Gerhard; Schöning, Ingo; Boch, Steffen; Marhan, Sven; Kandeler, Ellen; Schloter, Michael

    2013-01-01

    Understanding factors driving the ecology of N cycling microbial communities is of central importance for sustainable land use. In this study we report changes of abundance of denitrifiers, nitrifiers and nitrogen-fixing microorganisms (based on qPCR data for selected functional genes) in response to different land use intensity levels and the consequences for potential turnover rates. We investigated selected grassland sites being comparable with respect to soil type and climatic conditions, which have been continuously treated for many years as intensely used meadows (IM), intensely used mown pastures (IP) and extensively used pastures (EP), respectively. The obtained data were linked to above ground biodiversity pattern as well as water extractable fractions of nitrogen and carbon in soil. Shifts in land use intensity changed plant community composition from systems dominated by s-strategists in extensive managed grasslands to c-strategist dominated communities in intensive managed grasslands. Along the different types of land use intensity, the availability of inorganic nitrogen regulated the abundance of bacterial and archaeal ammonia oxidizers. In contrast, the amount of dissolved organic nitrogen determined the abundance of denitrifiers (nirS and nirK). The high abundance of nifH carrying bacteria at intensive managed sites gave evidence that the amounts of substrates as energy source outcompete the high availability of inorganic nitrogen in these sites. Overall, we revealed that abundance and function of microorganisms involved in key processes of inorganic N cycling (nitrification, denitrification and N fixation) might be independently regulated by different abiotic and biotic factors in response to land use intensity.

  18. Different Land Use Intensities in Grassland Ecosystems Drive Ecology of Microbial Communities Involved in Nitrogen Turnover in Soil

    PubMed Central

    Meyer, Annabel; Focks, Andreas; Radl, Viviane; Keil, Daniel; Welzl, Gerhard; Schöning, Ingo; Boch, Steffen; Marhan, Sven; Kandeler, Ellen; Schloter, Michael

    2013-01-01

    Understanding factors driving the ecology of N cycling microbial communities is of central importance for sustainable land use. In this study we report changes of abundance of denitrifiers, nitrifiers and nitrogen-fixing microorganisms (based on qPCR data for selected functional genes) in response to different land use intensity levels and the consequences for potential turnover rates. We investigated selected grassland sites being comparable with respect to soil type and climatic conditions, which have been continuously treated for many years as intensely used meadows (IM), intensely used mown pastures (IP) and extensively used pastures (EP), respectively. The obtained data were linked to above ground biodiversity pattern as well as water extractable fractions of nitrogen and carbon in soil. Shifts in land use intensity changed plant community composition from systems dominated by s-strategists in extensive managed grasslands to c-strategist dominated communities in intensive managed grasslands. Along the different types of land use intensity, the availability of inorganic nitrogen regulated the abundance of bacterial and archaeal ammonia oxidizers. In contrast, the amount of dissolved organic nitrogen determined the abundance of denitrifiers (nirS and nirK). The high abundance of nifH carrying bacteria at intensive managed sites gave evidence that the amounts of substrates as energy source outcompete the high availability of inorganic nitrogen in these sites. Overall, we revealed that abundance and function of microorganisms involved in key processes of inorganic N cycling (nitrification, denitrification and N fixation) might be independently regulated by different abiotic and biotic factors in response to land use intensity. PMID:24039974

  19. Metagenomic Analysis of Hot Springs in Central India Reveals Hydrocarbon Degrading Thermophiles and Pathways Essential for Survival in Extreme Environments.

    PubMed

    Saxena, Rituja; Dhakan, Darshan B; Mittal, Parul; Waiker, Prashant; Chowdhury, Anirban; Ghatak, Arundhuti; Sharma, Vineet K

    2016-01-01

    Extreme ecosystems such as hot springs are of great interest as a source of novel extremophilic species, enzymes, metabolic functions for survival and biotechnological products. India harbors hundreds of hot springs, the majority of which are not yet explored and require comprehensive studies to unravel their unknown and untapped phylogenetic and functional diversity. The aim of this study was to perform a large-scale metagenomic analysis of three major hot springs located in central India namely, Badi Anhoni, Chhoti Anhoni, and Tattapani at two geographically distinct regions (Anhoni and Tattapani), to uncover the resident microbial community and their metabolic traits. Samples were collected from seven distinct sites of the three hot spring locations with temperature ranging from 43.5 to 98°C. The 16S rRNA gene amplicon sequencing of V3 hypervariable region and shotgun metagenome sequencing uncovered a unique taxonomic and metabolic diversity of the resident thermophilic microbial community in these hot springs. Genes associated with hydrocarbon degradation pathways, such as benzoate, xylene, toluene, and benzene were observed to be abundant in the Anhoni hot springs (43.5-55°C), dominated by Pseudomonas stutzeri and Acidovorax sp., suggesting the presence of chemoorganotrophic thermophilic community with the ability to utilize complex hydrocarbons as a source of energy. A high abundance of genes belonging to methane metabolism pathway was observed at Chhoti Anhoni hot spring, where methane is reported to constitute >80% of all the emitted gases, which was marked by the high abundance of Methylococcus capsulatus . The Tattapani hot spring, with a high-temperature range (61.5-98°C), displayed a lower microbial diversity and was primarily dominated by a nitrate-reducing archaeal species Pyrobaculum aerophilum . A higher abundance of cell metabolism pathways essential for the microbial survival in extreme conditions was observed at Tattapani. Taken together, the results of this study reveal a novel consortium of microbes, genes, and pathways associated with the hot spring environment.

  20. Reflections on O2 as a Biosignature in Exoplanetary Atmospheres.

    PubMed

    Meadows, Victoria S

    2017-10-01

    Oxygenic photosynthesis is Earth's dominant metabolism, having evolved to harvest the largest expected energy source at the surface of most terrestrial habitable zone planets. Using CO 2 and H 2 O-molecules that are expected to be abundant and widespread on habitable terrestrial planets-oxygenic photosynthesis is plausible as a significant planetary process with a global impact. Photosynthetic O 2 has long been considered particularly robust as a sign of life on a habitable exoplanet, due to the lack of known "false positives"-geological or photochemical processes that could also produce large quantities of stable O 2 . O 2 has other advantages as a biosignature, including its high abundance and uniform distribution throughout the atmospheric column and its distinct, strong absorption in the visible and near-infrared. However, recent modeling work has shown that false positives for abundant oxygen or ozone could be produced by abiotic mechanisms, including photochemistry and atmospheric escape. Environmental factors for abiotic O 2 have been identified and will improve our ability to choose optimal targets and measurements to guard against false positives. Most of these false-positive mechanisms are dependent on properties of the host star and are often strongest for planets orbiting M dwarfs. In particular, selecting planets found within the conservative habitable zone and those orbiting host stars more massive than 0.4 M ⊙ (M3V and earlier) may help avoid planets with abundant abiotic O 2 generated by water loss. Searching for O 4 or CO in the planetary spectrum, or the lack of H 2 O or CH 4 , could help discriminate between abiotic and biological sources of O 2 or O 3 . In advance of the next generation of telescopes, thorough evaluation of potential biosignatures-including likely environmental context and factors that could produce false positives-ultimately works to increase our confidence in life detection. Key Words: Biosignatures-Exoplanets-Oxygen-Photosynthesis-Planetary spectra. Astrobiology 17, 1022-1052.

  1. Identification and quantification of cardiac glycosides in blood and urine samples by HPLC/MS/MS.

    PubMed

    Guan, F; Ishii, A; Seno, H; Watanabe-Suzuki, K; Kumazawa, T; Suzuki, O

    1999-09-15

    Cardiac glycosides (CG) are of forensic importance because of their toxicity and the fact that very limited methods are available for identification of CG in biological samples. In this study, we have developed an identification and quantification method for digoxin, digitoxin, deslanoside, digoxigenin, and digitoxigenin by high-performance liquid chromatography tandem mass spectrometry (HPLC/MS/MS). CG formed abundant [M + NH4]+ ions and much less abundant [M + H]+ ions as observed with electrospray ionization (ESI) source and ammonium formate buffer. Under mild conditions for collision-induced dissociation (CID), each [M + NH4]+ ion fragmented to produce a dominant daughter ion, which was essential to the sensitive method of selected reaction monitoring (SRM) quantification of CG achieved in this study. SRM was compared with selected ion monitoring (SIM) regarding the effects of sample matrixes on the methodology. SRM produced lower detection limits with biological samples than SIM, while both methods produced equal detection limits with CG standards. On the basis of the HPLC/MS/MS results for CG, we have proposed some generalized points for conducting sensitive SRM measurements, in view of the property of analytes as well as instrumental conditions such as the type of HPLC/MS interface and CID parameters. Analytes of which the molecular ion can produce one abundant daughter ion with high yield under CID conditions may be sensitively measured by SRM. ESI is the most soft ionization source developed so far and can afford formation of the fragile molecular ions that are necessary for sensitive SRM detection. Mild CID conditions such as low collision energy and low pressure of collision gas favor production of an abundant daughter ion that is essential to sensitive SRM detection. This knowledge may provide some guidelines for conducting sensitive SRM measurements of very low concentrations of drugs or toxicants in biological samples.

  2. Reflections on O2 as a Biosignature in Exoplanetary Atmospheres

    NASA Astrophysics Data System (ADS)

    Meadows, Victoria S.

    2017-10-01

    Oxygenic photosynthesis is Earth's dominant metabolism, having evolved to harvest the largest expected energy source at the surface of most terrestrial habitable zone planets. Using CO2 and H2O - molecules that are expected to be abundant and widespread on habitable terrestrial planets - oxygenic photosynthesis is plausible as a significant planetary process with a global impact. Photosynthetic O2 has long been considered particularly robust as a sign of life on a habitable exoplanet, due to the lack of known "false positives" - geological or photochemical processes that could also produce large quantities of stable O2. O2 has other advantages as a biosignature, including its high abundance and uniform distribution throughout the atmospheric column and its distinct, strong absorption in the visible and near-infrared. However, recent modeling work has shown that false positives for abundant oxygen or ozone could be produced by abiotic mechanisms, including photochemistry and atmospheric escape. Environmental factors for abiotic O2 have been identified and will improve our ability to choose optimal targets and measurements to guard against false positives. Most of these false-positive mechanisms are dependent on properties of the host star and are often strongest for planets orbiting M dwarfs. In particular, selecting planets found within the conservative habitable zone and those orbiting host stars more massive than 0.4 M⊙ (M3V and earlier) may help avoid planets with abundant abiotic O2 generated by water loss. Searching for O4 or CO in the planetary spectrum, or the lack of H2O or CH4, could help discriminate between abiotic and biological sources of O2 or O3. In advance of the next generation of telescopes, thorough evaluation of potential biosignatures - including likely environmental context and factors that could produce false positives - ultimately works to increase our confidence in life detection.

  3. Reflections on O2 as a Biosignature in Exoplanetary Atmospheres

    PubMed Central

    2017-01-01

    Abstract Oxygenic photosynthesis is Earth's dominant metabolism, having evolved to harvest the largest expected energy source at the surface of most terrestrial habitable zone planets. Using CO2 and H2O—molecules that are expected to be abundant and widespread on habitable terrestrial planets—oxygenic photosynthesis is plausible as a significant planetary process with a global impact. Photosynthetic O2 has long been considered particularly robust as a sign of life on a habitable exoplanet, due to the lack of known “false positives”—geological or photochemical processes that could also produce large quantities of stable O2. O2 has other advantages as a biosignature, including its high abundance and uniform distribution throughout the atmospheric column and its distinct, strong absorption in the visible and near-infrared. However, recent modeling work has shown that false positives for abundant oxygen or ozone could be produced by abiotic mechanisms, including photochemistry and atmospheric escape. Environmental factors for abiotic O2 have been identified and will improve our ability to choose optimal targets and measurements to guard against false positives. Most of these false-positive mechanisms are dependent on properties of the host star and are often strongest for planets orbiting M dwarfs. In particular, selecting planets found within the conservative habitable zone and those orbiting host stars more massive than 0.4 M⊙ (M3V and earlier) may help avoid planets with abundant abiotic O2 generated by water loss. Searching for O4 or CO in the planetary spectrum, or the lack of H2O or CH4, could help discriminate between abiotic and biological sources of O2 or O3. In advance of the next generation of telescopes, thorough evaluation of potential biosignatures—including likely environmental context and factors that could produce false positives—ultimately works to increase our confidence in life detection. Key Words: Biosignatures—Exoplanets—Oxygen—Photosynthesis—Planetary spectra. Astrobiology 17, 1022–1052. PMID:28443722

  4. Diversity, abundance, and possible sources of fecal bacteria in the Yangtze River.

    PubMed

    Sun, Haohao; He, Xiwei; Ye, Lin; Zhang, Xu-Xiang; Wu, Bing; Ren, Hongqiang

    2017-03-01

    The fecal bacteria in natural waters may pose serious risks on human health. Although many source tracking methods have been developed and used to determine the possible sources of the fecal pollution, little is known about the overall diversity and abundance of fecal bacterial community in natural waters. In this study, a method based on fecal bacterial sequence library was introduced to evaluate the fecal bacterial profile in the Yangtze River (Nanjing section). Our results suggested that the Yangtze River water harbors diverse fecal bacteria. Fifty-eight fecal operational taxonomic units (97% identity level) were detected in the Yangtze River water samples and the relative abundance of fecal bacteria in these samples ranged from 0.1 to 8%. It was also found that the relative abundances of the fecal bacteria in locations near to the downstream of wastewater treatment plants were obviously higher than those in other locations. However, the high abundance of fecal bacteria could decrease to the normal level in 2~4 km in the river due to degradation or dilution, and the overall fecal bacteria level changed little when the Yangtze River flew through the Nanjing City. Moreover, the fecal bacteria in the Yangtze River water were found to be highly associated (Spearman rho = 0.804, P < 0.001) with the potential pathogenic bacteria. Collectively, the findings in this study reveal the diversity, abundance, and possible sources of fecal bacteria in the Yangtze River and advance our understandings of the fecal bacteria community in the natural waters.

  5. The Energetic Particles Acceleration, Composition, and Transport (EPACT) experiment on the ISTP/wind spacecraft

    NASA Technical Reports Server (NTRS)

    Reames, D. V.; Von Rosenvinge, T. T.; Ramaty, R.; Mason, G. M.; Hamilton, D. C.; Forman, M. A.; Webber, W. R.

    1990-01-01

    The EPACT experiment will measure abundances, spectra, and angular distributions of particles from 20 keV/amu to 500 MeV/amu. At high energies, isotopes will be resolved up through Z = 26, at intermediate energies elements with Z between 1 and 82 will be observed, and at low energies element abundances above Z = 2 will be resolved for the first time.

  6. On the gas phase fragmentation of protonated uracil: a statistical perspective.

    PubMed

    Rossich Molina, Estefanía; Salpin, Jean-Yves; Spezia, Riccardo; Martínez-Núñez, Emilio

    2016-06-01

    The potential energy surface of protonated uracil has been explored by an automated transition state search procedure, resulting in the finding of 1398 stationary points and 751 reactive channels, which can be categorized into isomerizations between pairs of isomers, unimolecular fragmentations and bimolecular reactions. The use of statistical Rice-Ramsperger-Kassel-Marcus (RRKM) theory and Kinetic Monte Carlo (KMC) simulations allowed us to determine the relative abundances of each fragmentation channel as a function of the ion's internal energy. The KMC/RRKM product abundances are compared with novel mass spectrometry (MS) experiments in the collision energy range 1-6 eV. To facilitate the comparison between theory and experiments, further dynamics simulations are carried out to determine the fraction of collision energy converted into the ion's internal energy. The KMC simulations show that the major fragmentation channels are isocyanic acid and ammonia losses, in good agreement with experiments. The third predominant channel is water loss according to both theory and experiments, although the abundance obtained in the KMC simulations is very low, suggesting that non-statistical dynamics might play an important role in this channel. Isocyanic acid (HNCOH(+)) is also an important product in the KMC simulations, although its abundance is only significant at internal energies not accessible in the MS experiments.

  7. Transcriptome analysis of Haloquadratum walsbyi: vanity is but the surface.

    PubMed

    Bolhuis, Henk; Martín-Cuadrado, Ana Belén; Rosselli, Riccardo; Pašić, Lejla; Rodriguez-Valera, Francisco

    2017-07-03

    Haloquadratum walsbyi dominates saturated thalassic lakes worldwide where they can constitute up to 80-90% of the total prokaryotic community. Despite the abundance of the enigmatic square-flattened cells, only 7 isolates are currently known with 2 genomes fully sequenced and annotated due to difficulties to grow them under laboratory conditions. We have performed a transcriptomic analysis of one of these isolates, the Spanish strain HBSQ001 in order to investigate gene transcription under light and dark conditions. Despite a potential advantage for light as additional source of energy, no significant differences were found between light and dark expressed genes. Constitutive high gene expression was observed in genes encoding surface glycoproteins, light mediated proton pumping by bacteriorhodopsin, several nutrient uptake systems, buoyancy and storage of excess carbon. Two low expressed regions of the genome were characterized by a lower codon adaptation index, low GC content and high incidence of hypothetical genes. Under the extant cultivation conditions, the square hyperhalophile devoted most of its transcriptome towards processes maintaining cell integrity and exploiting solar energy. Surface glycoproteins are essential for maintaining the large surface to volume ratio that facilitates light and organic nutrient harvesting whereas constitutive expression of bacteriorhodopsin warrants an immediate source of energy when light becomes available.

  8. Mesoporous Three-Dimensional Graphene Networks for Highly Efficient Solar Desalination under 1 sun Illumination.

    PubMed

    Kim, Kwanghyun; Yu, Sunyoung; An, Cheolwon; Kim, Sung-Wook; Jang, Ji-Hyun

    2018-05-09

    Solar desalination via thermal evaporation of seawater is one of the most promising technologies for addressing the serious problem of global water scarcity because it does not require additional supporting energy other than infinite solar energy for generating clean water. However, low efficiency and a large amount of heat loss are considered critical limitations of solar desalination technology. The combination of mesoporous three-dimensional graphene networks (3DGNs) with a high solar absorption property and water-transporting wood pieces with a thermal insulation property has exhibited greatly enhanced solar-to-vapor conversion efficiency. 3DGN deposited on a wood piece provides an outstanding value of solar-to-vapor conversion efficiency, about 91.8%, under 1 sun illumination and excellent desalination efficiency of 5 orders salinity decrement. The mass-producible 3DGN enriched with many mesopores efficiently releases the vapors from an enormous area of the surface by heat localization on the top surface of the wood piece. Because the efficient solar desalination device made by 3DGN on the wood piece is highly scalable and inexpensive, it could serve as one of the main sources for the worldwide supply of purified water achieved via earth-abundant materials without an extra supporting energy source.

  9. CoM(M=Fe,Cu,Ni)-embedded nitrogen-enriched porous carbon framework for efficient oxygen and hydrogen evolution reactions

    NASA Astrophysics Data System (ADS)

    Feng, Xiaogeng; Bo, Xiangjie; Guo, Liping

    2018-06-01

    Rational synthesis and development of earth-abundant materials with efficient electrocatalytic activity and stability for water splitting is a critical but challenging step for sustainable energy application. Herein, a family of bimetal (CoFe, CoCu, CoNi) embedded nitrogen-doped carbon frameworks is developed through a facile and simple thermal conversion strategy of metal-doped zeolitic imidazolate frameworks. Thanks to collaborative superiorities of abundant M-N-C species, modulation action of secondary metal, cobalt-based electroactive phases, template effect of MOFs and unique porous structure, bimetal embedded nitrogen-doped carbon frameworks materials manifest good oxygen and hydrogen evolution catalytic activity. Especially, after modulating the species and molar ratio of metal sources, optimal Co0.75Fe0.25 nitrogen-doped carbon framework catalyst just requires a low overpotential of 303 mV to achieve 10 mA cm-2 with a low Tafel slope (39.49 mV dec-1) for oxygen evolution reaction, which even surpasses that of commercial RuO2. In addition, the optimal catalyst can function as an efficient bifunctional electrocatalyst for overall water splitting with satisfying activity and stability. This development offers an attractive direction for the rational design and fabrication of porous carbon materials for electrochemical energy applications.

  10. Dust, Abundances, and the Evolution of Novae

    NASA Astrophysics Data System (ADS)

    Woodward, Charles; Bode, Michael; Evans, Anuerin; Geballe, Thomas; Gehrz, Robert; Helton, Andrew; Krautter, Joachim; Lynch, David; Ness, Jan-Uwe; Rudy, Richard; Schwarz, Greg; Shore, Steve; Starrfield, Sumner; Truran, James; Vanlandingham, Karen; Wagner, R. Mark

    2008-03-01

    Evolved stars are the engines of energy production and chemical evolution in our Universe. They deposit radiative and mechanical energy into their environments. They enrich the ambient ISM with elements synthesized in their interiors and dust grains condensed in their atmospheres. Classical novae (CNe) contribute to this cycle of chemical enrichment through explosive nucleosynthesis and the violent ejection of material dredged from the white dwarf progenitor and mixed with the accreted surface layers. Our capstone study of 10 CNe will provide an ensemble of objects, well-populated in CNe parameter space (fast, slow, 'coronal', dusty) for detailed photoionization modeling and analysis. CNe are laboratories in which several poorly-understood astrophysical processes (e.g., mass transfer, thermonuclear runaway, optically thick winds, common envelope evolution, molecule and grain formation, coronal emission) may be observed. With Spitzer's unique wavelength coverage and point-source sensitivity we can: (i) investigate the in situ formation, astromineralogy, and processing of nova dust, (ii) determine the ejecta elemental abundances resulting from thermonuclear runaway, (iii) constrain the correlation of ejecta mass with progenitor type, (iv) measure the bolometric luminosity of the outburst, and (v) characterize the kinematics and structure of the ejected envelopes. Extensive ground-based and space-based (Chandra, Swift, XMM-Newton) programs led by team CoIs will complement Spitzer CNe observations.

  11. Remote Sensing and Geochemistry of Planetary Surfaces

    NASA Technical Reports Server (NTRS)

    Jakosky, Bruce M.

    2002-01-01

    We have been examining the resources required to support potential life on Mars, as a way of understanding the possible abundance and distribution of life. Based on our understanding of the Earth, the necessary requirements for the environment to allow it to support life are (i) presence of liquid water, (ii) access to the biogenic elements (C, H, O, N, S, P, Ca, Fe, etc.), and (iii) a source of energy to drive chemical disequilibrium, such that the reactions back toward equilibrium can release energy to support metabolism. While even demonstrating that all of these requirements have been met would not mean that life would necessarily exist on Mars, they provide the context in which a search for life or analysis of geochemical characteristics that might be indicative of life might be carried out. Our previous work has focused on the first and third of these characteristics determine where and when liquid water might have been present, and understanding the availability of chemical energy from weathering reactions that might ID support life. In the analysis supported by this grant (covering the time period 2/15/01-2/14/02), we have been examining the second requirement--the abundance of the necessary biogenic elements, their geographical distribution on Mars and the information on the possible vertical distribution within the crust, and their geochemical accessibility and mobility within the crust and at the surface. In particular, our work during the performance period has emphasized phosphorous.

  12. Phlebotomine vector ecology in the domestic transmission of American cutaneous leishmaniasis in Chaparral, Colombia.

    PubMed

    Ferro, Cristina; Marín, Dairo; Góngora, Rafael; Carrasquilla, María C; Trujillo, Jorge E; Rueda, Norma K; Marín, Jaime; Valderrama-Ardila, Carlos; Alexander, Neal; Pérez, Mauricio; Munstermann, Leonard E; Ocampo, Clara B

    2011-11-01

    Phlebotomine vector ecology was studied in the largest recorded outbreak of American cutaneous leishmaniasis in Colombia in 2004. In two rural townships that had experienced contrasting patterns of case incidence, this study evaluated phlebotomine species composition, seasonal abundance, nocturnal activity, blood source, prevalence of Leishmania infection, and species identification. CDC miniature light traps were used to trap the phlebotomines. Traps were set indoors, peridomestically, and in woodlands. Natural infection was determined in pools by polymerase chain reaction-Southern blot, and blood sources and species identification were determined by sequencing. Large differences were observed in population abundance between the two townships evaluated. Lutzomyia longiflocosa was the most abundant species (83.1%). Abundance was higher during months with lower precipitation. Nocturnal activity was associated with human domestic activity. Blood sources identified were mainly human (85%). A high prevalence of infection was found in L. longiflocosa indoors (2.7%) and the peridomestic setting (2.5%). L. longiflocosa was responsible for domestic transmission in Chaparral.

  13. Phlebotomine Vector Ecology in the Domestic Transmission of American Cutaneous Leishmaniasis in Chaparral, Colombia

    PubMed Central

    Ferro, Cristina; Marín, Dairo; Góngora, Rafael; Carrasquilla, María C.; Trujillo, Jorge E.; Rueda, Norma K.; Marín, Jaime; Valderrama-Ardila, Carlos; Alexander, Neal; Pérez, Mauricio; Munstermann, Leonard E.; Ocampo, Clara B.

    2011-01-01

    Phlebotomine vector ecology was studied in the largest recorded outbreak of American cutaneous leishmaniasis in Colombia in 2004. In two rural townships that had experienced contrasting patterns of case incidence, this study evaluated phlebotomine species composition, seasonal abundance, nocturnal activity, blood source, prevalence of Leishmania infection, and species identification. CDC miniature light traps were used to trap the phlebotomines. Traps were set indoors, peridomestically, and in woodlands. Natural infection was determined in pools by polymerase chain reaction–Southern blot, and blood sources and species identification were determined by sequencing. Large differences were observed in population abundance between the two townships evaluated. Lutzomyia longiflocosa was the most abundant species (83.1%). Abundance was higher during months with lower precipitation. Nocturnal activity was associated with human domestic activity. Blood sources identified were mainly human (85%). A high prevalence of infection was found in L. longiflocosa indoors (2.7%) and the peridomestic setting (2.5%). L. longiflocosa was responsible for domestic transmission in Chaparral. PMID:22049038

  14. A Carbon-Free Energy Future

    NASA Astrophysics Data System (ADS)

    Linden, H. R.; Singer, S. F.

    2001-12-01

    It is generally agreed that hydrogen is an ideal energy source, both for transportation and for the generation of electric power. Through the use of fuel cells, hydrogen becomes a high-efficiency carbon-free power source for electromotive transport; with the help of regenerative braking, cars should be able to reach triple the current mileage. Many have visualized a distributed electric supply network with decentralized generation based on fuel cells. Fuel cells can provide high generation efficiencies by overcoming the fundamental thermodynamic limitation imposed by the Carnot cycle. Further, by using the heat energy of the high-temperature fuel cell in co-generation, one can achieve total thermal efficiencies approaching 100 percent, as compared to present-day average power-plant efficiencies of around 35 percent. In addition to reducing CO2 emissions, distributed generation based on fuel cells also eliminates the tremendous release of waste heat into the environment, the need for cooling water, and related limitations on siting. Manufacture of hydrogen remains a key problem, but there are many technical solutions that come into play whenever the cost equations permit . One can visualize both central and local hydrogen production. Initially, reforming of abundant natural gas into mixtures of 80% H2 and 20% CO2 provides a relatively low-emission source of hydrogen. Conventional fossil-fuel plants and nuclear plants can become hydrogen factories using both high-temperature topping cycles and electrolysis of water. Hydro-electric plants can manufacture hydrogen by electrolysis. Later, photovoltaic and wind farms could be set up at favorable locations around the world as hydrogen factories. If perfected, photovoltaic hydrogen production through catalysis would use solar photons most efficiently . For both wind and PV, hydrogen production solves some crucial problems: intermittency of wind and of solar radiation, storage of energy, and use of locations that are not desirable for other economic uses. A hydrogen-based energy future is inevitable as low-cost sources of petroleum and natural gas become depleted with time. However, such fundamental changes in energy systems will take time to accomplish. Coal may survive for a longer time but may not be able to compete as the century draws to a close.

  15. Neutrino-heated winds from millisecond protomagnetars as sources of the weak r-process

    NASA Astrophysics Data System (ADS)

    Vlasov, Andrey D.; Metzger, Brian D.; Lippuner, Jonas; Roberts, Luke F.; Thompson, Todd A.

    2017-06-01

    We explore heavy element nucleosynthesis in neutrino-driven winds from rapidly rotating, strongly magnetized protoneutron stars ('millisecond protomagnetars') for which the magnetic dipole is aligned with the rotation axis, and the field is assumed to be a static force-free configuration. We process the protomagnetar wind trajectories calculated by Vlasov, Metzger & Thompson through the r-process nuclear reaction network SkyNet using contemporary models for the evolution of the wind electron fraction during the protoneutron star cooling phase. Although we do not find a successful second or third-peak r-process for any rotation period P, we show that protomagnetars with P ˜ 1-5 ms produce heavy element abundance distributions that extend to higher nuclear mass number than from otherwise equivalent spherical winds (with the mass fractions of some elements enhanced by factors of ≳100-1000). The heaviest elements are synthesized by outflows emerging along flux tubes that graze the closed zone and pass near the equatorial plane outside the light cylinder. Due to dependence of the nucleosynthesis pattern on the magnetic field strength and rotation rate of the protoneutron star, natural variations in these quantities between core collapse events could contribute to the observed diversity of the abundances of weak r-process nuclei in metal-poor stars. Further diversity, including possibly even a successful third-peak r-process, could be achieved for misaligned rotators with non-zero magnetic inclination with respect to the rotation axis. If protomagnetars are central engines for GRBs, their relativistic jets should contain a high-mass fraction of heavy nuclei of characteristic mass number \\bar{A}≈ 100, providing a possible source for ultrahigh energy cosmic rays comprised of heavy nuclei with an energy spectrum that extends beyond the nominal Grezin-Zatsepin-Kuzmin cut-off for protons or iron nuclei.

  16. Is benthic food web structure related to diversity of marine macrobenthic communities?

    NASA Astrophysics Data System (ADS)

    Sokołowski, A.; Wołowicz, M.; Asmus, H.; Asmus, R.; Carlier, A.; Gasiunaité, Z.; Grémare, A.; Hummel, H.; Lesutiené, J.; Razinkovas, A.; Renaud, P. E.; Richard, P.; Kędra, M.

    2012-08-01

    Numerical structure and the organisation of food webs within macrozoobenthic communities has been assessed in the European waters (Svalbard, Barents Sea, Baltic Sea, North Sea, Atlantic Ocean and the Mediterranean Sea) to address the interactions between biodiversity and ecosystem functioning. Abundance and classical species diversity indices (S, H', J) of macrofaunal communities were related to principal attributes of food webs (relative trophic level and food chain length, FCL) that were determined from carbon and nitrogen stable isotope values. Structure of marine macrobenthos varies substantially at a geographical scale; total abundance ranges from 63 ind. m-2 to 34,517 ind. m-2, species richness varies from 3 to 166 and the Shannon-Weaver diversity index from 0.26 to 3.26 while Pielou's evenness index is below 0.73. The major source of energy for macrobenthic communities is suspended particulate organic matter, consisting of phytoplankton and detrital particles, sediment particulate organic matter, and microphytobenthos in varying proportions. These food sources support the presence of suspension- and deposit-feeding communities, which dominate numerically on the sea floor. Benthic food webs include usually four to five trophic levels (FCL varies from 3.08 to 4.86). Most species are assigned to the second trophic level (primary consumers), fewer species are grouped in the third trophic level (secondary consumers), and benthic top predators are the least numerous. Most species cluster primarily at the lowest trophic level that is consistent with the typical organization of pyramidal food webs. Food chain length increases with biodiversity, highlighting a positive effect of more complex community structure on food web organisation. In more diverse benthic communities, energy is transferred through more trophic levels while species-poor communities sustain a shorter food chain.

  17. Energy in a Planetary Context

    NASA Technical Reports Server (NTRS)

    Hoehler, Tori M.

    2017-01-01

    The potential present day habitability of solar system bodies beyond Earth is limited to subsurface environments, where the availability of energy in biologically useful form is a paramount consideration. Energy availability is commonly quantified in terms of molar Gibbs energy changes for metabolisms of interest, but this can provide an incomplete and even misleading picture. A second aspect of life's requirement for energy - the rate of delivery, or power - strongly influences habitability, biomass abundance, growth rates, and, ultimately, rates of evolution. We are developing an approach to quantify metabolic power, using a cell-scale reactive transport model in which physical and chemical environmental parameters are varied. Simultaneously, we evaluate cell-specific energy flux requirements and their dependence on environmental "extremes". Comparison of metabolic power supply and demand provides a constraint on how biomass abundance varies across a range of environmental parameters, and thereby a prediction of the relative habitability of different environments. We are evaluating the predictive capability of this approach through comparison to observed distributions of microbial abundance in a range of subsurface (predominantly serpentinizing) systems.

  18. Anomalous Abundances in Gaseous Nebulae From Recombination and Collisional Lines: Improved Photoionization and Recombination Studies

    NASA Astrophysics Data System (ADS)

    Pradhan, Anil Kumar; Nahar, S. N.; Eissner, W. B.; Montenegro, M.

    2011-01-01

    A perplexing anomaly arises in the determination of abundances of common elements in gaseous nebulae, as derived from collisionally excited lines (CEL) as opposed to those from Recombination Lines (RCL). The "abundance discrepancy factors" can range from a factor of 2 to an order of magnitude or more. That has led to quite different interpretation of the physical structure and processes in gaseous nebulae, such as temperature fluctuations across the object, or metal-rich concentrations leading to a dual-abundnace scenario. We show that the problem may lie in inaccuracies in photoionization and recombination models neglecting low-energy resonance phenomena due to fine structure. Whereas the atomic physics of electron impact excitation of forbidden lines is well understood, and accurate collision strengths have long been available, that is not generally the case for electron-ion recombination cross sections. A major problem is the inclusion of relativisitic effects as it pertains to the existence of very low-energy fine structure resonances in photoionization cross sections. We carry out new relativistic calculations for photoionization and recombination cross sections using a recently extended version of the Breit-Pauli R-matrix codes, and the unified electron-ion recombination method that subsumes both the radiative and the dielectronic recombination (RR and DR) processes in an ab initio and self-consistent manner. We find that near-thresold resonances manifest themselves within fine structure levels of the ground state of ions, enhancing low-temperature recombination rate coefficients at 1000-10,000 K. The resulting enahncement in level-specific and total recombination rate coefficients should therefore lead to reduced abundances derived from RCL, and in accordance with those from CEL. We present results for photoionization of O II into, and recombination from, O III. Theoretical cross sections are benchmarked against high-resolution measurements from synchrotron based light sources. Work on other atomic species is in progress.

  19. Estimating abundance while accounting for rarity, correlated behavior, and other sources of variation in counts

    USGS Publications Warehouse

    Dorazio, Robert M.; Martin, Juulien; Edwards, Holly H.

    2013-01-01

    The class of N-mixture models allows abundance to be estimated from repeated, point count surveys while adjusting for imperfect detection of individuals. We developed an extension of N-mixture models to account for two commonly observed phenomena in point count surveys: rarity and lack of independence induced by unmeasurable sources of variation in the detectability of individuals. Rarity increases the number of locations with zero detections in excess of those expected under simple models of abundance (e.g., Poisson or negative binomial). Correlated behavior of individuals and other phenomena, though difficult to measure, increases the variation in detection probabilities among surveys. Our extension of N-mixture models includes a hurdle model of abundance and a beta-binomial model of detectability that accounts for additional (extra-binomial) sources of variation in detections among surveys. As an illustration, we fit this model to repeated point counts of the West Indian manatee, which was observed in a pilot study using aerial surveys. Our extension of N-mixture models provides increased flexibility. The effects of different sets of covariates may be estimated for the probability of occurrence of a species, for its mean abundance at occupied locations, and for its detectability.

  20. Estimating abundance while accounting for rarity, correlated behavior, and other sources of variation in counts.

    PubMed

    Dorazio, Robert M; Martin, Julien; Edwards, Holly H

    2013-07-01

    The class of N-mixture models allows abundance to be estimated from repeated, point count surveys while adjusting for imperfect detection of individuals. We developed an extension of N-mixture models to account for two commonly observed phenomena in point count surveys: rarity and lack of independence induced by unmeasurable sources of variation in the detectability of individuals. Rarity increases the number of locations with zero detections in excess of those expected under simple models of abundance (e.g., Poisson or negative binomial). Correlated behavior of individuals and other phenomena, though difficult to measure, increases the variation in detection probabilities among surveys. Our extension of N-mixture models includes a hurdle model of abundance and a beta-binomial model of detectability that accounts for additional (extra-binomial) sources of variation in detections among surveys. As an illustration, we fit this model to repeated point counts of the West Indian manatee, which was observed in a pilot study using aerial surveys. Our extension of N-mixture models provides increased flexibility. The effects of different sets of covariates may be estimated for the probability of occurrence of a species, for its mean abundance at occupied locations, and for its detectability.

  1. Platinum Group Element (PGE) Abundances in Lava Flows Generated by the Hawaiian Plume: Insights into Plume Evolution

    NASA Astrophysics Data System (ADS)

    Shafer, J. T.; Neal, C. R.

    2003-12-01

    Picritic and high-MgO (7.7-24 wt.%) basalt samples from Detroit (/sim81-76 Ma) and Koko (/sim48 Ma) Seamounts along the ESC have been analyzed for PGEs (Ru, Rh, Pd, Ir, and Pt) allowing an examination of how the PGEs in lavas from the Hawaiian plume have changed over time. Major and trace element (including the PGEs) concentrations were quantified by ICP methods at the University of Notre Dame. See Ely et al. (1999, Chem. Geol. 157:219) for the PGE analytical method. Bennett et al. (2000) analyzed Hawaiian picrites and found PGE abundances slightly greater than average MORB and comparable to the low-PGE basaltic komatiites. These authors modeled the PGE abundances of these picrites by using variable amounts of residual sulfide during melting, such that Koolau (low PGE contents) formed from a relatively sulfide-rich source and Loihi (high PGEs) from a sulfide-poor source. Our PGE data from Detroit Seamount show slightly higher PGE abundances than Loihi and Kilauea, suggesting these picrites formed from a source lacking residual sulfide. These results suggest that, if the model of Bennett et al. (2000) is correct, the dilution of plume lava with MORB source, as hypothesized on the basis of depleted isotope ratios and lower trace element abundances than modern Hawaii (Keller et al., 2000, Nature 405:603; Kinman & Neal, 2002, Eos 83:F1282; Regelous et al., 2003, JPet 44:113), was not the controlling factor in PGE abundances. However, since MORB PGE concentrations are not substantially different than low-PGE Hawaiian picrites, incorporation of MORB material within the Hawaiian plume at Detroit Seamount would not have drastically reduced the PGE abundances. Koko Seamount has relatively high PGE concentrations (/sim3-12 times greater than those from Detroit lavas). This may be the result of a lack of residual sulfide facilitated by higher degrees of partial melting. Although our initial data are consistent with variable degrees of partial melting and/or source heterogeneity over the life of the Hawaiian plume, the data from Detroit Seamount can be modeled by, for example, magma mixing between Koko-type "PGE-rich" plume and MORB end members (cf. Kinman & Neal, 2002). The Pt/Ir ratios and PGE abundances of picrites from Detroit and Koko Seamounts and from Hawaii (as analyzed by Bennett et al., 2000) increase in the order: Hawaii (4.8), Detroit (5.8), Koko (8.1). Bennett et al. argued that if more sulfide was retained in the source the PGE profile would be more fractionated and abundances would be lower. Our data suggest the opposite is true. For Koko Seamount to have PGE abundances approximately 3-12 times greater than the high-PGE picrites from Hawaii and yet have a more fractionated profile, the source of the Hawaiian plume must have been relatively PGE-enriched at 48 Ma than it is currently. In addition, the more fractionated profile of Detroit Seamount is consistent with the incorporation of MORB material (Pt/Ir /sim 25.9), thereby raising its Pt/Ir ratio.

  2. Exploring the interior of Venus with seismic and infrasonic techniques

    NASA Astrophysics Data System (ADS)

    Jackson, J. M.; Cutts, J. A.; Pauken, M.; Komjathy, A.; Smrekar, S. E.; Kedar, S.; Mimoun, D.; Garcia, R.; Schubert, G.; Lebonnois, S.; Stevenson, D. J.; Lognonne, P. H.; Zhan, Z.; Ko, J. Y. T.; Tsai, V. C.

    2016-12-01

    The dense atmosphere of Venus, which efficiently couples seismic energy into the atmosphere as infrasonic waves, enables an alternative to conventional seismology: detection of infrasonic waves in the upper atmosphere using either high altitude balloons or orbiting spacecraft. Infrasonic techniques for probing the interior of Venus can be implemented without exposing sensors to the severe surface environments on Venus. This approach takes advantage of the fact that approximately sixty-times the energy from a seismic event on Venus is coupled into the atmosphere on Venus as would occur for a comparable event on Earth. The direct or epicentral wave propagates vertically above the event, and the indirect wave propagates through the planet as a Rayleigh wave and then couples to an infrasonic wave. Although there is abundant evidence of tectonic activity on Venus, questions remain as to whether the planet is still active and whether energy releases are seismic or aseismic. In recent years, seismologists have developed techniques for probing crustal and interior structure in parts of the Earth where there are very few quakes. We have begun an effort to determine if this is also possible for Venus. Just as seismic energy propagates more efficiently upward across the surface atmosphere interface, equally acoustic energy originating in the atmosphere will propagate downwards more effectively. Measurements from a balloon platform in the atmosphere of Venus could assess the nature and spectral content of such sources, while having the ability to identify and discriminate signatures from volcanic events, storm activity, and meteor impacts. We will discuss our ongoing assessment on the feasibility of a balloon acoustic monitoring system. In particular, we will highlight our results of the flight experiment on Earth that will focus on using barometer instruments on a tethered helium-filled balloon in the vicinity of a known seismic source generated by a seismic hammer. Implications for conducting such measurements on Venus, including seismic and aseismic energy sources and propagation through its atmosphere, will also be discussed.

  3. Evaluation of the suitability and performance of cassava waste (peel) extracts in a microbial fuel cell for supplementary and sustainable energy production.

    PubMed

    Adekunle, Ademola; Raghavan, Vijaya

    2017-01-01

    In a number of energy-poor nations, peel from cassava processing represents one of the most abundant sources of lignocellulosic biomass. This peel is mostly discarded indiscriminately and eventually constitutes a problem to the environment. However, energy can be extracted from this peel in a microbial fuel cell. In this study, the viability of cassava peel extract as a substrate in a single-chamber air cathode microbial fuel cell is demonstrated, and optimum performance conditions are explored. The effects of different pretreatments on the extract are also discussed in the context of observed changes in the internal resistances, conductivity and Coulombic efficiencies. At the best conditions examined, the extract from cassava peel fermented for 168 h and adjusted to a pH of 7.63 attained a peak voltage of 687 mV ± 21 mV, a power density of 155 mW m -3 of reactor volume and a Coulombic efficiency of 11 %. Although this energy is limited to direct use, systems exist that can effectively harvest and boost the energy to levels sufficient for supplementary energy usage in cassava producing regions.

  4. Synfuels and the energy transition

    NASA Astrophysics Data System (ADS)

    Balzhiser, R. E.

    1981-08-01

    Various synfuel options and their impact on the electric utility industry are discussed. The energy transition for the U.S.A. is seen as moving from natural fluid fuels to solid fuels and renewable energy resources. The key to this transition is electrification, which can encompass both nuclear and renewable resources, centralized and dispersed technologies. It is shown that the fraction of total energy converted to electricity has risen steadily for the past 30 years, reaching 33% last year. The abundance and cost of production of the various fossil energy resources, including natural gas, heavy oil, oil shale, and coal are considered. EPRI analyses indicate that an integrated-combined-cycle power plant could be competitive with conventional coal plant technology. These plants would use only half the water of current coal-fired plants, would meet tighter sulfur emission standards, and would produce a vitreous ash that is less leachable than the ash from today's coal plants. Solvent-refined coal processes, currently being developed in the U.S.A. are a second approach to converting coal to liquid fuels. It is pointed out, however, that synfuels will complement, not replace, other sources of energy in the continued electrification of the U.S.A.

  5. Energy sources for Nigeria

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Okoroji, C.E.I.

    1982-09-01

    A public consensus has developed on the need for national energy policies and better planning in the utilization of energy resources in Nigeria. A look at Nigeria's energy future is timely as a period of rapid technological growth and industrial development begins. At the present time, Nigeria exports a relatively high percentage (92%) of the petroleum produced annually. In addition, about 95% of all produced natural gas is flared. Only a relatively minor fraction of the coal produced is used and the rest exported to West African countries. Water power in Nigeria is not yet fully developed. Although the depositsmore » of uranium and oil sand may be substantial, the reserves are not currently known. The proportions in which mineral fuels are used are not related to their relative abundance. Based on present production rates, domestic reserves of petroleum will last 20 years, those of natural gas 63 years, and those of coal 1503 years. Nigeria is not currently and is not likely to become self-sufficient in terms of energy requirements. During the past decade, Nigeria's population has increased by 28.4%. Of vital concern for the immediate future in Nigeria are the demands on energy consumption and mineral resources resulting from increasing population pressure.« less

  6. Exploring Ultra-Heavy Cosmic Rays with the Trans-Iron Galactic Element Recorder (TIGER)

    NASA Astrophysics Data System (ADS)

    Link, Jason; Supertiger Collaboration

    2017-01-01

    Elements heavier than iron are primarily synthesized by neutron capture. These elements can be accelerated as cosmic-rays and measuring their abundances at Earth can yield information about galactic cosmic-rays' sources, the acceleration processes and the composition of the universe beyond the boundaries of our solar system. The Trans-Iron Galactic Element Recorder (TIGER) and its larger successor SuperTIGER was designed to measure the abundance of these ultra-heavy cosmic rays between Z=10 and Z=60. These detectors utilize scintillators with a wavelength shifter bar and PMT readout system as well as aerogel and acrylic Cherenkov detectors to identify the charge and energy of a particle and utilize a scintillating fiber hodoscope to provide trajectory information. In this talk I will review the results from this highly successful program, give the status for the next SuperTIGER flight planned for a December 2017 launch from Antarctica, and discuss the future direction of the program.

  7. Declines in deepwater sculpin Myoxocephalus thompsonii energy density associated with the disappearance of Diporeia spp. in lakes Huron and Michigan

    USGS Publications Warehouse

    Pothoven, S.A.; Hondorp, D.W.; Nalepa, T.F.

    2011-01-01

    The deepwater sculpin Myoxocephalus thompsonii is a glacial relict in the Laurentian Great Lakes that primarily consumes two glacial relict crustaceans, Mysis relicta and Diporeia spp. Deepwater sculpin were collected in Lake Michigan off Little Sable Point (in 2001) and Muskegon, Michigan (in 2001 and 2009), and in Lake Huron off Harbor Beach, Michigan (in 2007) for energy density and diet analyses. These sites and years represented differences in available prey. In Lake Michigan, energy densities of deepwater sculpin in 2001 were similar to those reported in 1969-1971. In contrast, energy content declined at least 26% at Muskegon between 2001 and 2009. Overall, energy density was 31-34% higher at a site with abundant Diporeia spp. compared with two sites without Diporeia spp. Deepwater sculpin diets consisted primarily of M. relicta at all sites, but included 10-17% (dry mass) Diporeia spp. at sites where this crustacean was still abundant. Food biomass in stomachs was higher at sites with abundant Diporeia spp. than at those without Diporeia spp. Deepwater sculpin energy density and food biomass in stomachs were similar between two sites without Diporeia spp. despite differences in abundance of remaining prey, M. relicta. Declines in deepwater sculpin energy density suggest the potential for further effects on other species and changes in the flow of energy through the food web of the Great Lakes. Published 2010. This article is a US Government work and is in the public domain in the USA.

  8. The Importance of CO2 Utilizing Chemolithoautotrophic Microorganisms for Carbon Sequestration and Isotope Signatures of SOM in Tropical Rainforest Soils

    NASA Astrophysics Data System (ADS)

    Nowak, M. E.; Behrendt, T.; Quesada, B.; Yanez Serrano, A. M.; Trumbore, S.

    2015-12-01

    Soil organic matter (SOM) is a major compartment of the tropical carbon cycle with up to 26 % of global carbon stocks stored in tropical soils. Understanding factors and processes driving SOM dynamics under changing climate conditions is crucial for predicting the role of tropical forest ecosystems to act as a carbon sink or source. Soil microorganisms are major drivers of the belowground carbon cycle by releasing CO2 by soil respiration but also by stabilizing and storing SOM, as indicated by recent research. Our investigations focus on chemolithoautotrophic microorganisms, a group that relies on CO2 as their carbon source. Chemolithoautotrophic microorganisms have been shown to be highly abundant in soils, whereas their role in SOM sequestration is still poorly understood. In tropical soils, the activity of chemolithoautotropic microbes might be important for generating and stabilizing carbon, especially in the deeper soil, which is rich in CO2 and reduced energy sources like Fe2+. They further might impact carbon isotope signatures (13C and 14C) of SOM, because of enzymatic fractionation during carboxylation and the use of carbon, which has a distinct isotopic composition than other carbon sources at the same depth. In order to study the activity of chemolithoautotropic microbes and their importance for SOM, we conducted isotope and isotope-labelling studies, gas measurements as well as molecular analyses at soils from the Atto site from 0 to 1 meter depth. These soils are classified as Ferralsols and Alisols and represent the most abundant soil types in the Amazon. With this we will be able to gain knowledge about the function and identity of an important group of microorganisms and their contribution to crucial biogeochemical cycles in the world`s most important ecosystem.

  9. Growth of methanogens on a Mars soil simulant.

    PubMed

    Kral, Timothy A; Bekkum, Curtis R; McKay, Christopher P

    2004-12-01

    Currently, the surface of Mars is probably too cold, too dry, and too oxidizing for life, as we know it, to exist. But the subsurface is another matter. Life forms that might exist below the surface could not obtain their energy from photosynthesis, but rather they would have to utilize chemical energy. Methanogens are one type of microorganism that might be able to survive below the surface of Mars. A potential habitat for existence of methanogens on Mars might be a geothermal source of hydrogen, possibly due to volcanic or hydrothermal activity, or the reaction of basalt and anaerobic water, carbon dioxide, which is abundant in the martian atmosphere, and of course, subsurface liquid water. We report here that certain methanogens can grow on a Mars soil simulant when supplied with carbon dioxide, molecular hydrogen, and varying amounts of water.

  10. Major role of nitrite-oxidizing bacteria in dark ocean carbon fixation.

    PubMed

    Pachiadaki, Maria G; Sintes, Eva; Bergauer, Kristin; Brown, Julia M; Record, Nicholas R; Swan, Brandon K; Mathyer, Mary Elizabeth; Hallam, Steven J; Lopez-Garcia, Purificacion; Takaki, Yoshihiro; Nunoura, Takuro; Woyke, Tanja; Herndl, Gerhard J; Stepanauskas, Ramunas

    2017-11-24

    Carbon fixation by chemoautotrophic microorganisms in the dark ocean has a major impact on global carbon cycling and ecological relationships in the ocean's interior, but the relevant taxa and energy sources remain enigmatic. We show evidence that nitrite-oxidizing bacteria affiliated with the Nitrospinae phylum are important in dark ocean chemoautotrophy. Single-cell genomics and community metagenomics revealed that Nitrospinae are the most abundant and globally distributed nitrite-oxidizing bacteria in the ocean. Metaproteomics and metatranscriptomics analyses suggest that nitrite oxidation is the main pathway of energy production in Nitrospinae. Microautoradiography, linked with catalyzed reporter deposition fluorescence in situ hybridization, indicated that Nitrospinae fix 15 to 45% of inorganic carbon in the mesopelagic western North Atlantic. Nitrite oxidation may have a greater impact on the carbon cycle than previously assumed. Copyright © 2017, American Association for the Advancement of Science.

  11. Chemical complexity induced by efficient ice evaporation in the Barnard 5 molecular cloud

    NASA Astrophysics Data System (ADS)

    Taquet, V.; Wirström, E. S.; Charnley, S. B.; Faure, A.; López-Sepulcre, A.; Persson, C. M.

    2017-10-01

    Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. Here we present the detection of the complex organic molecules (COMs) acetaldehyde (CH3CHO) and methyl formate (CH3OCHO), as well as formic acid (HCOOH) and ketene (CH2CO), and the tentative detection of di-methyl ether (CH3OCH3) towards the "methanol hotspot" of Barnard 5 located between two dense cores using the single dish OSO 20 m, IRAM 30 m, and NRO 45 m telescopes. The high energy cis-conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between 1 and 10% relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6%, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as "lukewarm" COMs whereas methyl formate and di-methyl ether were defined as "warm" species. Comparison with previous observations of other types of sources confirms that lukewarm and warm COMs show similar abundances in low-density cold gas whereas the warm COMs tend to be more abundant than the lukewarm species in warm protostellar cores. This abundance evolution suggests either that warm COMs are indeed mostly formed in protostellar environments and/or that lukewarm COMs are efficiently depleted by increased hydrogenation efficiency around protostars.

  12. Thermal relics: Do we know their abundances

    NASA Technical Reports Server (NTRS)

    Kamionkowski, Marc; Turner, Michael S.

    1990-01-01

    The relic abundance of a particle species that was once in thermal equilibrium in the expanding Universe depends upon a competition between the annihilation rate of the species and the expansion rate of the Universe. Assuming that the Universe is radiation dominated at early times the relic abundance is easy to compute and well known. At times earlier than about 1 sec after the bang there is little or no evidence that the Universe had to be radiation dominated, although that is the simplest and standard assumption. Because early-Universe relics are of such importance both to particle physics and to cosmology, three nonstandard possibilities are considered in detail for the Universe at the time a species' abundance froze in: energy density dominated by shear (i.e., anisotropic expansion), energy density dominated by some other nonrelativistic species, and energy density dominated by the kinetic energy of the scalar field that sets the gravitational constant in a Brans-Dicke-Jordan cosmological mode. In the second case the relic abundance is less than the standard value, while in the other two cases it can be enhanced by a significant factor. Two other more exotic possibilities for enhancing the relic abundance of a species are also mentioned--a larger value of Newton's constant at early times (e.g., as might occur in superstring or Kaluza-Klein theories) or a component of the energy density at early times with a very stiff equation of state (p greater than rho/3), e.g., a scalar field phi with potential V(phi) = Beta /phi/ (exp n) with n greater than 4. Results have implications for dark matter searches and searches for particle relics in general.

  13. Limited impact on decadal-scale climate change from increased use of natural gas.

    PubMed

    McJeon, Haewon; Edmonds, Jae; Bauer, Nico; Clarke, Leon; Fisher, Brian; Flannery, Brian P; Hilaire, Jérôme; Krey, Volker; Marangoni, Giacomo; Mi, Raymond; Riahi, Keywan; Rogner, Holger; Tavoni, Massimo

    2014-10-23

    The most important energy development of the past decade has been the wide deployment of hydraulic fracturing technologies that enable the production of previously uneconomic shale gas resources in North America. If these advanced gas production technologies were to be deployed globally, the energy market could see a large influx of economically competitive unconventional gas resources. The climate implications of such abundant natural gas have been hotly debated. Some researchers have observed that abundant natural gas substituting for coal could reduce carbon dioxide (CO2) emissions. Others have reported that the non-CO2 greenhouse gas emissions associated with shale gas production make its lifecycle emissions higher than those of coal. Assessment of the full impact of abundant gas on climate change requires an integrated approach to the global energy-economy-climate systems, but the literature has been limited in either its geographic scope or its coverage of greenhouse gases. Here we show that market-driven increases in global supplies of unconventional natural gas do not discernibly reduce the trajectory of greenhouse gas emissions or climate forcing. Our results, based on simulations from five state-of-the-art integrated assessment models of energy-economy-climate systems independently forced by an abundant gas scenario, project large additional natural gas consumption of up to +170 per cent by 2050. The impact on CO2 emissions, however, is found to be much smaller (from -2 per cent to +11 per cent), and a majority of the models reported a small increase in climate forcing (from -0.3 per cent to +7 per cent) associated with the increased use of abundant gas. Our results show that although market penetration of globally abundant gas may substantially change the future energy system, it is not necessarily an effective substitute for climate change mitigation policy.

  14. Population Pressure, Global Living Standards, and the Promise of Space Solar Power

    NASA Astrophysics Data System (ADS)

    Strickland, John K., Jr.

    2002-01-01

    What many sincere environmentalists advocate: (severe restrictions on energy use, to reduce global warming), may actually end up being very harmful to the environment. Since 85 percent of the global energy use is derived from carbon based fossil fuels, this may seem to be a reasonable position. However, the proponents of energy use restrictions are ignoring some very important relationships. The greatest damage to the environment, in terms of species loss, is loss and/or human modification of habitat. The two greatest threats to habitat seem to be (1) population pressure and (2) logging. Logging does not necessarily permanently occupy the land, while either default squatter occupation or "colonization by policy" is often permanent. Increased population degrades the land by causing over- farming, and also creates an ever greater demand for raw materials and food resources. Poor people have no time nor money to think about or help save the environment. Therefore the greatest threat to species survival is human population growth and its frequent companion: poverty. There is an existing way to reduce population growth, and thus to reduce pressure on habitats, called "raising the standard of living". Wherever it succeeds, population growth slows rapidly. In many European countries, there would be a negative population growth if not for immigration. Personal energy use is closely correlated with living standards, and it is impossible to have a higher living standard without a higher degree of personal energy use. It would seem, however, that extending high living standards to the developing world would create an even greater demand for the use of fossil fuels. The solution to this dilemma can only be found in the use of very high capacity sources of non- fossil energy that do not significantly damage the environment. Are there sources of clean, economical energy with a large enough combined capacity to provide high living standards for the whole world, including those uses of electricity and fuels currently covered by fossil fuels. This is a global replacement load of about 9000 gigawatts. Green theorists are divided on this issue. Some claim that ground based solar, wind, and other renewable sources will supply all the energy we need, ignoring economic costs that severely limit their use. Others would (unrealistically) require the developed countries to reduce their energy consumption per capita to a level closer to that of the developing world, thereby admitting the limitations of the "appropriate" systems they espouse. Both sides in the past have rejected as "non-appropriate" and/or "dangerous" all the chemically clean energy sources of high capacity that have been previously proposed, such as safer nuclear fission, fusion power, and space solar power. If ground based "appropriate" energy sources are not sufficient, the economic and social effects of sudden forced curtailments of fossil energy use could be drastic. This paper supports the thesis that Space Solar Power does have the potential to provide such a clean, abundant, and economical energy source. It will cover both the limitations and promise of ground based energy sources, including the difficulties of using intermittent energy sources. It will discuss whether specified levels of energy cost increases would be damaging to the world economy and whether economical ground based sources alone would have sufficient capacity. It will show how the one major problem of launch costs, (currently preventing economical implementation of Space Solar Power), has a number of quite reasonable solutions. Finally, it will consider whether Space Solar Power, along with the other major space goals of Science &Exploration, Mars Colonization, Non- terrestrial Materials Recovery and Space Tourism, could be another space "killer app" which, by creating a high demand for launch services, could force large reductions in launch costs.

  15. Mechanisms driving postfire abundance of a generalist mammal

    Treesearch

    R. Zwolak; D. E. Pearson; Y. K. Ortega; E. E. Crone

    2012-01-01

    Changes in vertebrate abundance following disturbance are commonly attributed to shifts in food resources or predation pressure, but underlying mechanisms have rarely been tested. We examined four hypotheses for the commonly reported increase in abundance of deer mouse (Peromyscus maniculatus (Wagner, 1845)) following forest fires: source-sink dynamics, decreased...

  16. Three generation production biotechnology of biomass into bio-fuel

    NASA Astrophysics Data System (ADS)

    Zheng, Chaocheng

    2017-08-01

    The great change of climate change, depletion of natural resources, and scarcity of fossil fuel in the whole world nowadays have witnessed a sense of urgency home and abroad among scales of researchers, development practitioners, and industrialists to search for completely brand new sustainable solutions in the area of biomass transforming into bio-fuels attributing to our duty-that is, it is our responsibility to take up this challenge to secure our energy in the near future with the help of sustainable approaches and technological advancements to produce greener fuel from nature organic sources or biomass which comes generally from organic natural matters such as trees, woods, manure, sewage sludge, grass cuttings, and timber waste with a source of huge green energy called bio-fuel. Biomass includes most of the biological materials, livings or dead bodies. This energy source is ripely used industrially, or domestically for rather many years, but the recent trend is on the production of green fuel with different advance processing systems in a greener. More sustainable method. Biomass is becoming a booming industry currently on account of its cheaper cost and abundant resources all around, making it fairly more effective for the sustainable use of the bio-energy. In the past few years, the world has witnessed a remarkable development in the bio-fuel production technology, and three generations of bio-fuel have already existed in our society. The combination of membrane technology with the existing process line can play a vital role for the production of green fuel in a sustainable manner. In this paper, the science and technology for sustainable bio-fuel production will be introduced in detail for a cleaner world.

  17. Green power: A renewable energy resources marketing plan

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Barr, R.C.

    Green power is electricity generated from renewable energy sources such as power generated from the sun, the wind, the heat of the earth, and biomass. Green pricing is the marketing strategy to sell green power to customers who voluntarily pay a premium for it. Green pricing is evolving from the deregulation of the electric industry, the need for clean air, reflected in part as concern over global warming, and technology advances. The goal of the renewable energy marketing plan is to generate enough revenues for a utility to fund power purchase agreements (PPAs) with renewable energy developers or construct itsmore » own renewable facilities. Long-term, fixed price PPAs enable developers to obtain financing to construct new facilities, sometimes taking technological risks which a utility might not take otherwise. The marketing plan is built around different rate premiums for different categories of ratepayers, volunteer customer participation, customer participation recognition, and budget allocations between project costs and power marketing costs. Green prices are higher than those for conventional sources, particularly prices from natural gas fired plants. Natural gas is abundant relative to oil in price per British thermal unit (Btu). Green pricing can help bridge the gap between the current oversupply of gas and the time, not far off, when all petroleum prices will exceed those for renewable energy. The rapid implementation of green pricing is important. New marketing programs will bolster the growing demand for renewable energy evidenced in many national surveys thus decreasing the consumption of power now generated by burning hydrocarbons. This paper sets forth a framework to implement a green power marketing plan for renewable energy developers and utilities working together.« less

  18. Atmospheric energy for subsurface life on Mars?

    NASA Technical Reports Server (NTRS)

    Weiss, B. P.; Yung, Y. L.; Nealson, K. H.

    2000-01-01

    The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H(2) and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H(2) and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H(2)O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life.

  19. Atmospheric energy for subsurface life on Mars?

    PubMed

    Weiss, B P; Yung, Y L; Nealson, K H

    2000-02-15

    The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H(2) and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H(2) and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H(2)O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life.

  20. Advanced Na[Ni0.25Fe0.5Mn0.25]O2/C-Fe3O4 sodium-ion batteries using EMS electrolyte for energy storage.

    PubMed

    Oh, Seung-Min; Myung, Seung-Taek; Yoon, Chong Seung; Lu, Jun; Hassoun, Jusef; Scrosati, Bruno; Amine, Khalil; Sun, Yang-Kook

    2014-03-12

    While much research effort has been devoted to the development of advanced lithium-ion batteries for renewal energy storage applications, the sodium-ion battery is also of considerable interest because sodium is one of the most abundant elements in the Earth's crust. In this work, we report a sodium-ion battery based on a carbon-coated Fe3O4 anode, Na[Ni0.25Fe0.5Mn0.25]O2 layered cathode, and NaClO4 in fluoroethylene carbonate and ethyl methanesulfonate electrolyte. This unique battery system combines an intercalation cathode and a conversion anode, resulting in high capacity, high rate capability, thermal stability, and much improved cycle life. This performance suggests that our sodium-ion system is potentially promising power sources for promoting the substantial use of low-cost energy storage systems in the near future.

  1. Switching of metabolic programs in response to light availability is an essential function of the cyanobacterial circadian output pathway

    PubMed Central

    Puszynska, Anna M; O'Shea, Erin K

    2017-01-01

    The transcription factor RpaA is the master regulator of circadian transcription in cyanobacteria, driving genome-wide oscillations in mRNA abundance. Deletion of rpaA has no effect on viability in constant light conditions, but renders cells inviable in cycling conditions when light and dark periods alternate. We investigated the mechanisms underlying this viability defect, and demonstrate that the rpaA- strain cannot maintain appropriate energy status at night, does not accumulate carbon reserves during the day, and is defective in transcription of genes crucial for utilization of carbohydrate stores at night. Reconstruction of carbon utilization pathways combined with provision of an external carbon source restores energy charge and viability of the rpaA- strain in light/dark cycling conditions. Our observations highlight how a circadian output pathway controls and temporally coordinates essential pathways in carbon metabolism to maximize fitness of cells facing periodic energy limitations. DOI: http://dx.doi.org/10.7554/eLife.23210.001 PMID:28430105

  2. Secondary batteries with multivalent ions for energy storage

    PubMed Central

    Xu, Chengjun; Chen, Yanyi; Shi, Shan; Li, Jia; Kang, Feiyu; Su, Dangsheng

    2015-01-01

    The use of electricity generated from clean and renewable sources, such as water, wind, or sunlight, requires efficiently distributed electrical energy storage by high-power and high-energy secondary batteries using abundant, low-cost materials in sustainable processes. American Science Policy Reports state that the next-generation “beyond-lithium” battery chemistry is one feasible solution for such goals. Here we discover new “multivalent ion” battery chemistry beyond lithium battery chemistry. Through theoretic calculation and experiment confirmation, stable thermodynamics and fast kinetics are presented during the storage of multivalent ions (Ni2+, Zn2+, Mg2+, Ca2+, Ba2+, or La3+ ions) in alpha type manganese dioxide. Apart from zinc ion battery, we further use multivalent Ni2+ ion to invent another rechargeable battery, named as nickel ion battery for the first time. The nickel ion battery generally uses an alpha type manganese dioxide cathode, an electrolyte containing Ni2+ ions, and Ni anode. The nickel ion battery delivers a high energy density (340 Wh kg−1, close to lithium ion batteries), fast charge ability (1 minute), and long cycle life (over 2200 times). PMID:26365600

  3. Crest - A Balloon-borne Instrument To Measure Cosmic-ray Electrons Above TeV Energies.

    NASA Astrophysics Data System (ADS)

    Schubnell, Michael; Anderson, T.; Bower, C.; Coutu, S.; Geske, M.; Müller, D.; Musser, J.; Nutter, S.; Park, N.; Tarlé, G.; Wakely, S.; Yagi, A.

    2009-01-01

    The observation of high energy (E > 1 TeV) electrons in the cosmic radiation provides important information on the distribution and energetics of local cosmic-ray sources. Galactic cosmic-ray electrons are thought to be shock accelerated in supernova remnants as evident from observations of non-thermal X-rays and TeV gamma rays. Their locally observed energy spectrum above 1 TeV is expected to reflect the distribution and abundance of nearby acceleration sites. However, the rates at these energies are low and the direct detection would require unfeasibly large balloons or satellite born detectors. CREST, a balloon-borne detector array of 1024 BaF2 crystals, overcomes this hurdle: it will measure the intensity and spectrum of multi-TeV electrons by detecting synchrotron photons emitted from electrons passing through the earth's magnetic field. Thus CREST's acceptance is several times its geometric area providing sensitivity up to about 50 TeV. Following an engineering flight in spring of 2009, CREST will be flown in a circumpolar orbit on an upcoming Antarctic long-duration balloon flight. This work is supported by NASA and CSBF.

  4. Coherent Wave Measurement Buoy Arrays to Support Wave Energy Extraction

    NASA Astrophysics Data System (ADS)

    Spada, F.; Chang, G.; Jones, C.; Janssen, T. T.; Barney, P.; Roberts, J.

    2016-02-01

    Wave energy is the most abundant form of hydrokinetic energy in the United States and wave energy converters (WECs) are being developed to extract the maximum possible power from the prevailing wave climate. However, maximum wave energy capture is currently limited by the narrow banded frequency response of WECs as well as extended protective shutdown requirements during periods of large waves. These limitations must be overcome in order to maximize energy extraction, thus significantly decreasing the cost of wave energy and making it a viable energy source. Techno-economic studies of several WEC devices have shown significant potential to improve wave energy capture efficiency through operational control strategies that incorporate real-time information about local surface wave motions. Integral Consulting Inc., with ARPA-E support, is partnering with Sandia National Laboratories and Spoondrift LLC to develop a coherent array of wave-measuring devices to relay and enable the prediction of wave-resolved surface dynamics at a WEC location ahead of real time. This capability will provide necessary information to optimize power production of WECs through control strategies, thereby allowing for a single WEC design to perform more effectively across a wide range of wave environments. The information, data, or work presented herein was funded in part by the Advanced Research Projects Agency-Energy (ARPA-E), U.S. Department of Energy, under Award Number DE-AR0000514.

  5. The Potential Role of Formate for Synthesis and Life in Serpentinization Systems

    NASA Astrophysics Data System (ADS)

    Lang, S. Q.; Frueh-Green, G. L.; Bernasconi, S. M.; Brazelton, W. J.; McGonigle, J. M.

    2016-12-01

    The high hydrogen concentrations produced during water-rock serpentinization reactions provide abundant thermodynamic energy that can drive the synthesis of organic compounds both biotically and abiotically. We investigated the synthesis of abiotic carbon and the metabolic pathways of the microbial inhabitants of the high energy but low diversity serpentinite-hosted Lost City Hydrothermal Field. High concentrations of the organic acid formate can be attributed to two sources. In some locations formate lacks detectable 14C, demonstrating it was formed abiotically from mantle-derived CO2. In other locations there is an additional modern contribution to the formate pool, potentially indicating active cycling with modern seawater dissolved inorganic carbon by microorganisms. The presence of this carbon source is likely critical for the survival of the subsurface microbial communities that inhabit alkaline serpentinization environments, where inorganic carbon is severely limited. Archaeal lipids produced by the Lost City Methanosarcinales (LCMS) also largely lack 14C, requiring their carbon source to be similarly 14C-free. Metagenomic evidence suggests that the LCMS could use formate for methanogenesis and, altogether, the data suggests that these organisms cannot rely on inorganic carbon as their carbon source and substrate for methanogenesis. Considering the lack of dissolved inorganic carbon in this system, the ability to utilize formate may have been a key evolutionary adaptation for survival in serpentinite-hosted environments. In the Lost City system, the LCMS apparently rely upon an abiotically produced organic carbon source, which may enable the Lost City microbial ecosystem to survive in the absence of photosynthesis or its byproducts.

  6. Optimization of low cost, non toxic, earth abundant p-type Cu2SnS3 thin film for Photovoltaic application

    NASA Astrophysics Data System (ADS)

    Chaudhari, J. J.; Patel, S.; Joshi, U. S.

    2016-09-01

    Cu2SnS3 (CTS) is one of promising candidate as an absorber material for thin film solar cell. Because of relatively higher prize of Indium and hazardous environmental impact of processing of Gallium, CTS is suitable alternative candidate to Cu2SnS3 (CIGS) based solar cell as its constituent elements such as copper, tin and sulphur are abundantly available in earth's crust. CTS is ternary semiconductor and its energy band gap is 1.5eV, which is perfectly matched with solar energy spectrum for maximum transfer of solar energy into electrical energy through photovoltaic action. The primary methods for the synthesis of CTS are Thermal evaporation, electrochemical, sputtering and wet chemical methods. Here in this paper we have optimized a low cost non-vacuum solution process method for the synthesis of CTS without any external sulfurization. The X-ray diffraction studies showed the formation of phase with the peaks corresponding to (112), (220) and (312) planes. Chemical Solution Deposition (CSD) for the synthesis of CTS is suitable for large area deposition and it includes several routes like solvothermal methods, direct liquid coating and nano ink based technique. The metal Chloride salts and thiourea is used as a source of sulphur to synthesize CTS solution and homogeneous thin films of CTS deposited on glass substrate using spin coating method. Use of abrasive solvent like hydrazine and hydrogen sulphide gas which are used to synthesize CTS thin film have detrimental effect on environment, we report eco friendly solvent based approach to synthesize CTS at low temperature 200 °C.

  7. Modeling unobserved sources of heterogeneity in animal abundance using a Dirichlet process prior

    USGS Publications Warehouse

    Dorazio, R.M.; Mukherjee, B.; Zhang, L.; Ghosh, M.; Jelks, H.L.; Jordan, F.

    2008-01-01

    In surveys of natural populations of animals, a sampling protocol is often spatially replicated to collect a representative sample of the population. In these surveys, differences in abundance of animals among sample locations may induce spatial heterogeneity in the counts associated with a particular sampling protocol. For some species, the sources of heterogeneity in abundance may be unknown or unmeasurable, leading one to specify the variation in abundance among sample locations stochastically. However, choosing a parametric model for the distribution of unmeasured heterogeneity is potentially subject to error and can have profound effects on predictions of abundance at unsampled locations. In this article, we develop an alternative approach wherein a Dirichlet process prior is assumed for the distribution of latent abundances. This approach allows for uncertainty in model specification and for natural clustering in the distribution of abundances in a data-adaptive way. We apply this approach in an analysis of counts based on removal samples of an endangered fish species, the Okaloosa darter. Results of our data analysis and simulation studies suggest that our implementation of the Dirichlet process prior has several attractive features not shared by conventional, fully parametric alternatives. ?? 2008, The International Biometric Society.

  8. The composition of heavy ions in solar energetic particle events

    NASA Technical Reports Server (NTRS)

    Fan, C. Y.; Gloeckler, G.; Hovestadt, D.

    1983-01-01

    Recent advances in determining the elemental, charge state, and isotopic composition of or approximate to 1 to or approximate to 20 MeV per nucleon ions in solar energetic particle (SEP) events and outline our current understanding of the nature of solar and interplanetary processes which may explain the observations. Average values of relative abundances measured in a large number of SEP events were found to be roughly energy independent in the approx. 1 to approx. 20 MeV per nucleon range, and showed a systematic deviation from photospheric abundances which seems to be organized in terms of the first ionization potential of the ion. Direct measurements of the charge states of SEPs revealed the surprisingly common presence of energetic He(+) along with heavy ion with typically coronal ionization states. High resolution measurements of isotopic abundance ratios in a small number of SEP events showed these to be consistent with the universal composition except for the puzzling overabundance of the SEP(22)Ne/(20)Ne relative to this isotopes ratio in the solar wind. The broad spectrum of observed elemental abundance variations, which in their extreme result in composition anomalies characteristic of (3)He rich, heavy ion rich and carbon poor SEP events, along with direct measurements of the ionization states of SEPs provided essential information on the physical characteristics of, and conditions in the source regions, as well as important constraints to possible models for SEP production.

  9. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Nabeel, A.; Khan, M.A.; Husain, S.

    Coal is the most abundant source of energy. However, there is a need to develop cleaner, and more efficient, economical, and convenient coal conversion technologies. It is important to understand the organic chemical structure of coal for achieving real breakthroughs in the development of such coal conversion technologies. A novel computer-assisted modeling technique based on the analysis of {sup 13}C NMR and gel permeation chromatography has been applied to predict the average molecular structure of the acetylated product of a depolymerized bituminous Indian coal. The proposed molecular structure may be of practical use in understanding the mechanism of coal conversionsmore » during the processes of liquefaction, gasification, combustion, and carbonization.« less

  10. Humus-reducing microorganisms and their valuable contribution in environmental processes.

    PubMed

    Martinez, Claudia M; Alvarez, Luis H; Celis, Lourdes B; Cervantes, Francisco J

    2013-12-01

    Humus constitutes a very abundant class of organic compounds that are chemically heterogeneous and widely distributed in terrestrial and aquatic environments. Evidence accumulated during the last decades indicating that humic substances play relevant roles on the transport, fate, and redox conversion of organic and inorganic compounds both in chemically and microbially driven reactions. The present review underlines the contribution of humus-reducing microorganisms in relevant environmental processes such as biodegradation of recalcitrant pollutants and mitigation of greenhouse gases emission in anoxic ecosystems, redox conversion of industrial contaminants in anaerobic wastewater treatment systems, and on the microbial production of nanocatalysts and alternative energy sources.

  11. The economics of abundance: coal and cotton in Lancashire and the world.

    PubMed

    Balderston, Theo

    2010-01-01

    As a subterranean, highly elastic energy source, coal played a vital role in the cotton industry revolution. Coal was also vital to Lancashire's primacy in this revolution, because it was necessary both to the original accumulation of agglomeration economies before the steam age and to their reinforcement during the steam age. In no other part of the world was the cotton industry situated on a coalfield, and the response of other parts of the world cotton industry to Lancashire's agglomeration advantages was dispersal in search of cheap water and/or labour power. Lancashire coal helped to shape the global pattern of cotton production.

  12. Precambrian Lunar Volcanic Protolife

    PubMed Central

    Green, Jack

    2009-01-01

    Five representative terrestrial analogs of lunar craters are detailed relevant to Precambrian fumarolic activity. Fumarolic fluids contain the ingredients for protolife. Energy sources to derive formaldehyde, amino acids and related compounds could be by flow charging, charge separation and volcanic shock. With no photodecomposition in shadow, most fumarolic fluids at 40 K would persist over geologically long time periods. Relatively abundant tungsten would permit creation of critical enzymes, Fischer-Tropsch reactions could form polycyclic aromatic hydrocarbons and soluble volcanic polyphosphates would enable assembly of nucleic acids. Fumarolic stimuli factors are described. Orbital and lander sensors specific to protolife exploration including combined Raman/laser-induced breakdown spectrocsopy are evaluated. PMID:19582224

  13. Spacelab mission 2: Experimental descriptions

    NASA Technical Reports Server (NTRS)

    Clifton, K. S. (Editor)

    1982-01-01

    The second Spacelab Mission and the 12 multidisciplinary experiments selected to fly on board are described. These experiments include the following: vitamin D metabolities and bone demineralization; interaction of oxygen and gravity influenced lignification; ejectable plasma diagnostics package; plasma depletion experiments for ionospheric and radio astronomical studies; small helium cooled IR telescope; elemental composition and energy spectra of cosmic ray nuclei; hard X-ray imaging of clusters of galaxies and other extended X-ray sources; solar magnetic and velocity field measurement system; solar coronal helium abundance Spacelab experiment; solar UV high resolution telescope and spectroraph; solar UV spectral irradiance monitor; and properties of superfluid helium in zero-G.

  14. Abundance of Chemical Elements in RR Lyrae Variables and their Kinematic Parameters

    NASA Astrophysics Data System (ADS)

    Gozha, M. L.; Marsakov, V. A.; Koval', V. V.

    2018-03-01

    A catalog of the chemical and spatial-kinematic parameters of 415 RR Lyrae variables (Lyrids) in the galactic field is compiled. Spectroscopic determinations of the relative abundances of 13 chemical elements in 101 of the RR Lyrae variables are collected from 25 papers published between 1995 and 2017. The data from different sources are reduced to a single solar abundance scale. The mean weighted chemical abundances are calculated with coefficients inversely proportional to the reported errors. An analysis of the deviations in the published relative abundances in each star from the mean square values calculated from them reveals an absence of systematic biases among the results from the various articles. The rectangular coordinates of 407 of the RR Lyrae variables and the components of the three-dimensional (3D) velocities of 401 of the stars are calculated using data from several sources. The collected data on the abundances of chemical elements produced by various nuclear fusion processes for the RR Lyrae variables of the field, as well as the calculated 3D velocities, can be used for studying the evolution of the Galaxy.

  15. Advancing the use of local ecological knowledge for assessing data-poor species in coastal ecosystems.

    PubMed

    Beaudreau, Anne H; Levin, Phillip S

    2014-03-01

    Many of the world's most vulnerable and rapidly changing ecosystems are also among the most data-poor, leading to an increased interest in use of local ecological knowledge (LEK) to document long-term environmental change. The integration of multiple knowledge sources for assessing species abundance and distribution has gained traction over the past decade as a growing number of case studies show concordance between LEK and scientific data. This study advances the use of quantitative approaches for synthesizing LEK by presenting a novel application of bootstrapping and statistical modeling to evaluate variance in ecological observations of fisheries practitioners. We developed an historical record of abundance for 22 marine species in Puget Sound, Washington (USA), using LEK, and we quantified variation in perceptions of abundance trends among fishers, divers, and researchers. These individuals differed in aspects of their information environments, which are characterized by how, when, and where an individual has acquired ecological information. Abundance trends derived from interviews suggest that populations of long-lived rockfishes (Sebastes spp.) have been in decline since at least the 1960s and that three rockfishes protected under the Endangered Species Act were perceived as relatively less abundant than other species. Differences in perception of rockfish abundance trends among age groups were consistent with our hypothesis that the reported magnitude of decline in abundance would increase with age, with younger respondents more likely to report high abundance than older individuals across all periods. Temporal patterns in the mean and variance of reported rockfish abundance indices were qualitatively similar between fishers and researchers; however, fishers reported higher indices of abundance than researchers for all but one rockfish species. The two respondent groups reported similar changes in rockfish abundance from the 1940s to 2000s, except for two recreationally valuable species that fishers perceived as having undergone greater declines than perceived by researchers. When aggregated at appropriate spatial-temporal scales and in a culturally appropriate manner, observations of resource users are a valuable source of ecological information. Continued development of creative analytical tools for synthesizing multiple knowledge sources will be essential for advancing the formal use of LEK in assessments of marine species.

  16. Effect of Tube-Based X-Ray Microtomography Imaging on the Amino Acid and Amine Content of the Murchison CM2 Chondrite

    NASA Technical Reports Server (NTRS)

    Glavin, D. P.; Friedrich, J. M.; Aponte, J. C.; Dworkin, J. P.; Ebel, D. S.; Elsila, J. E.; Hill, M.; McLain, H. L.; Towbin, W. H.

    2017-01-01

    X-ray and synchrotron X-ray micro-computed tomography (micro-CT) are increasingly being used for three dimensional reconnaissance imaging of chondrites and returned extraterrestrial material prior to detailed chemical and mineralogical analyses. Although micro-CT imaging is generally considered to be a non-destructive technique since silicate and metallic minerals in chondrites are not affected by X-ray exposures at the intensities and wavelengths typically used, there are concerns that the use of micro-CT could be detrimental to the organics in carbonaceous chondrites. We recently conducted a synchrotron micro-CT experiment on a powdered sample of the Murchison CM2 carbonaceous chondrite exposed to a monochromatic high energy (approximately 48 kiloelectronvolts) total X-ray radiation dose of approximately 1 kilogray (kGy) using the Advanced Photon Source beamline 13-BMD (13-Bending Magnet-D Beamline) at Argonne National Laboratory and found that there were no detectable changes in the amino acid abundances or enantiomeric compositions in the chondrite after exposure relative to a Murchison control sample that was not exposed. However, lower energy bremsstrahlung X-rays could interact more with amino acids and other lower molecular weight amines in meteorites. To test for this possibility, three separate micro-CT imaging experiments of the Murchison meteorite using the GE Phoenix v/tome/x s 240 kilovolt microfocus high resolution tungsten target X-ray tube instrument at the American Museum of Natural History (AMNH) were conducted and the amino acid abundances and enantiomeric compositions were determined. We also investigated the abundances of the C1-C5 amines in Murchison which were not analyzed in the first study.

  17. Technical Report on Modeling for Quasispecies Abundance Inference with Confidence Intervals from Metagenomic Sequence Data

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    McLoughlin, K.

    2016-01-11

    The overall aim of this project is to develop a software package, called MetaQuant, that can determine the constituents of a complex microbial sample and estimate their relative abundances by analysis of metagenomic sequencing data. The goal for Task 1 is to create a generative model describing the stochastic process underlying the creation of sequence read pairs in the data set. The stages in this generative process include the selection of a source genome sequence for each read pair, with probability dependent on its abundance in the sample. The other stages describe the evolution of the source genome from itsmore » nearest common ancestor with a reference genome, breakage of the source DNA into short fragments, and the errors in sequencing the ends of the fragments to produce read pairs.« less

  18. Anomalous abundances of solar energetic particles and coronal gas: Coulomb effects and First Ionization Potential (FIP) ordering

    NASA Technical Reports Server (NTRS)

    Mullan, D. J.

    1985-01-01

    The first ionization potential (FIP) ordering of elemental abundances in solar energetic particles and in the corona which can both be explained Coulomb effects is discussed. Solar energetic particles (SEP) and coronal gas have anomalous abundances relative to the photosphere. The anomalies are similar in both cases: which led to the conclusion that SEP acceleration is not selective, but merely preserves the source abundances. It is argued that SEP acceleration can be selective, because identical selectivity operates to determine the coronal abundances. The abundance anomalies are ordered by first ionization potential (FIP).

  19. Harvesting the decay energy of 26Al to drive lightning discharge in protoplanetary discs

    NASA Astrophysics Data System (ADS)

    Johansen, Anders; Okuzumi, Satoshi

    2018-01-01

    Chondrules in primitive meteorites likely formed by recrystallisation of dust aggregates that were flash-heated to nearly complete melting. Chondrules may represent the building blocks of rocky planetesimals and protoplanets in the inner regions of protoplanetary discs, but the source of ubiquitous thermal processing of their dust aggregate precursors remains elusive. Here we demonstrate that escape of positrons released in the decay of the short-lived radionuclide 26Al leads to a large-scale charging of dense pebble structures, resulting in neutralisation by lightning discharge and flash-heating of dust and pebbles. This charging mechanism is similar to a nuclear battery where a radioactive source charges a capacitor. We show that the nuclear battery effect operates in circumplanetesimal pebble discs. The extremely high pebble densities in such discs are consistent with conditions during chondrule heating inferred from the high abundance of sodium within chondrules. The sedimented mid-plane layer of the protoplanetary disc may also be prone to charging by the emission of positrons, if the mass density of small dust there is at least an order of magnitude above the gas density. Our results imply that the decay energy of 26Al can be harvested to drive intense lightning activity in protoplanetary discs. The total energy stored in positron emission is comparable to the energy needed to melt all solids in the protoplanetary disc. The efficiency of transferring the positron energy to the electric field nevertheless depends on the relatively unknown distribution and scale-dependence of pebble density gradients in circumplanetesimal pebble discs and in the protoplanetary disc mid-plane layer.

  20. Immunohistochemical localization of GLUT3, MCT1, and MCT2 in the testes of mice and rats: the use of different energy sources in spermatogenesis.

    PubMed

    Kishimoto, Ayuko; Ishiguro-Oonuma, Toshina; Takahashi, Ritei; Maekawa, Mamiko; Toshimori, Kiyotaka; Watanabe, Masahiko; Iwanaga, Toshihiko

    2015-01-01

    Lactate represents a preferential energy substrate of germ cells rather than glucose. Testicular Sertoli cells are believed to produce lactate and pyruvate and to supply these to germ cells, particularly spermatocytes and spermatids. Monocarboxylate transporter (MCT), responsible for the transport of lactate and other monocarboxylates via the cell membrane, is abundant in the testes and sperm (MCT1, MCT2, and MCT4). For the uptake of glucose, germ cells within the seminiferous tubules and sperm have been known to intensely express GLUT3. The present study investigated expression profiles of MCTs and GLUTs and revealed their cellular and subcellular localization in the mouse and rat testis. An in situ hybridization analysis showed significant expressions of MCT1, MCT2, and GLUT3 mRNA in the testis. Immunohistochemically, spermatogonia, spermatocytes, and spermatids expressed MCT1 on their cell surfaces in a stage-dependent manner: in some seminiferous tubules, an intense expression of MCT1 was unique to the spermatogonia. MCT2 was restricted to the tails of elongated spermatids and sperm. An intense immunoreactivity for GLUT3 was shared by spermatocytes, spermatids, and sperm. Sertoli cells were devoid of any immunoreactivities for MCT1, MCT2, and GLUT3. The predominant energy source of germ cells may be lactate and other monocarboxylates--especially for spermatogonia, but glucose and other hexoses may be responsible for an energy supply to spermatocytes and spermatids.

  1. PSII as an in vivo molecular catalyst for the production of energy rich hydroquinones - A new approach in renewable energy.

    PubMed

    Das, Sai; Maiti, Soumen K

    2018-03-01

    One of the pertinent issues in the field of energy science today is the quest for an abundant source of hydrogen or hydrogen equivalents. In this study, phenyl-p-benzoquinone (pPBQ) has been used to generate a molecular store of hydrogen equivalents (phenyl-p-hydroquinone; pPBQH 2 ) from thein vivo splitting of water by photosystem II of the marine cyanobacterium Synechococcus elongatus BDU 70542. Using this technique, 10.8 μmol of pPBQH 2 per mg chlorophyll a can be extracted per minute, an efficiency that is orders of magnitude higher when compared to the techniques present in the current literature. Moreover, the photo-reduction process was stable when tested over longer periods of time. Addition of phenyl-p-benzoquinone on an intermittent basis resulted in the precipitation of phenyl-p-hydroquinone, obviating the need for costly downstream processing units for product recovery. Phenyl-p-hydroquinone so obtained is a molecular store of free energy preserved through the light driven photolysis of water and can be used as a cheap and a renewable source of hydrogen equivalents by employing transition metal catalysts or fuel cells with the concomitant regeneration of phenyl-p-benzoquinone. The cyclic nature of this technique makes it an ideal candidate to be utilized in mankind's transition from fossil fuels to solar fuels. Copyright © 2018 Elsevier B.V. All rights reserved.

  2. The role of natural gas as a primary fuel in the near future, including comparisons of acquisition, transmission and waste handling costs of as with competitive alternatives

    PubMed Central

    2012-01-01

    Natural gas comprises about a quarter of the United States’ energy use. It is more environmentally friendly than oil and coal due to lower carbon dioxide (CO2) emissions per unit, less costly per unit of energy and more readily available domestically in abundant supply. However, due to a number of barriers in the political, infrastructural, pricing and other arenas, the use of natural gas as a significant energy source in the United States has been limited. In our paper, we highlight the favorable qualities of natural gas and its benefits for the consumer, producer, and environment, having compared the costs of the various components of the natural gas business such as drilling and transport to that of coal and oil. Moreover, we touch upon the major issues that have prevented a more prevalent use of the gas, such as the fact that the infrastructure of natural gas is more costly since it is transported though pipelines whereas other energy sources such as oil and coal have flexible systems that use trains, trucks and ships. In addition, the powerful lobbies of the coal and oil businesses, along with the inertia in the congress to pass a national climate change bill further dampens incentives for these industries to invest in natural gas, despite its various attractive qualities. We also include discussions of policy proposals to incentive greater use of natural gas in the future. PMID:22540989

  3. Long-Term Trends and Variability in Spring Development of Calanus finmarchicus in the Southeastern Norwegian Sea during 1996-2012

    NASA Astrophysics Data System (ADS)

    Dupont, N.; Bagøien, E.; Melle, W.

    2016-02-01

    Calanus finmarchicus is the dominant copepod species in the Norwegian Sea in terms of biomass, playing a key role in the ecosystem by transferring energy from primary producers to higher trophic levels. This study analyses the long-term trend of a 17-year time series (1996-2012) on abundance of adult Calanus finmarchicus in the Atlantic water-mass of the southern Norwegian Sea during spring. The long-term trend in spring abundance was assessed by using Generalised Additive Models, while simultaneously accounting for both general population development and inter-annual variation in population development throughout the study period. In one model, we focus on inter-annual changes in timing of the Calanus spring seasonal development by including Mean Stage Composition as a measure for state of population development. Following a short increase during the years 1996 to 2000, the abundance of Calanus finmarchicus decreased strongly until about the year 2010. For the two last years of the studied period, 2011-2012, increasing population abundances are suggested but with less certainty. The model results suggest that the analysis is capturing the G0 generation, displaying a peak for the adults in about mid-April. Inter-annual differences in spring seasonal development, with the peak of adults shifting towards earlier in the season as well as a shorter generation time are suggested. Considering the importance of Calanus finmarchicus as food for planktivorous predators in the Norwegian Sea, our time series analysis suggests relevant changes both with respect to the spring abundance and timing of this food source. The next step is to relate variation in the Calanus time series to environmental factors with special emphasis on climatic drivers.

  4. A molecular line survey toward the nearby galaxies NGC 1068, NGC 253, and IC 342 at 3 mm with the Nobeyama 45 m radio telescope: Impact of an AGN on 1 kpc scale molecular abundances

    NASA Astrophysics Data System (ADS)

    Nakajima, Taku; Takano, Shuro; Kohno, Kotaro; Harada, Nanase; Herbst, Eric

    2018-01-01

    It is important to investigate the relationships between the power sources and the chemical compositions of galaxies in order to understand the scenario of galaxy evolution. We carried out an unbiased molecular line survey towards active galactic nucleus (AGN) host galaxy NGC1068, and prototypical starburst galaxies, NGC 253 and IC 342, with the Nobeyama 45 m telescope in the 3 mm band. The advantage of this line survey is that the obtained spectra have the highest angular resolution ever obtained with single-dish telescopes. In particular, the beam size of this telescope is ˜15″-19″, which is able to separate spatially the nuclear molecular emission from that of the starburst ring (d ˜ 30″) in NGC 1068. We successfully detected approximately 23 molecular species in each galaxy, and calculated rotation temperatures and column densities. We estimate the molecular fractional abundances with respect to 13CO and CS molecules and compare them among three galaxies in order to investigate the chemical signatures of an AGN environment. As a result, we found clear trends in the abundances of molecules surrounding the AGN on a 1-kpc scale. HCN, H13CN, CN, 13CN, and HC3N are more abundant, and CH3CCH is deficient in NGC 1068 compared with the starburst galaxies. High abundances of HCN, H13CN, and HC3N suggest that the circumnuclear disk in NGC 1068 is in a high-temperature environment. The reason for the non-detection of CH3CCH is likely to be dissociation by high-energy radiation or less sublimation of a precursor of CH3CCH from grains.

  5. Chemical composition of the metal-poor carbon star HD 187216.

    NASA Astrophysics Data System (ADS)

    Kipper, T.; Jorgensen, U. G.

    1994-10-01

    We have derived C, N and metal abundances for the metal-deficient late-type (C3,3CH) CH giant HD 187216 (α_2000.0_=19h24m18.6s, δ_2000.0_=+85deg21'56.5"). The oxygen abundance was fixed at logA(O)=7.0, assuming that it follows the trend of oxygen overabundance relative to iron found in halo stars in general. New model atmospheres of metal-poor carbon stars were calculated with continuum opacity sources and molecular lines of CO, CN, C_2_, HCN, C_2_H_2_ and C_3_. Numerical experiments with various assumed input parameters, such as effective temperature, T_eff_, surface gravity, logg, microturbulent velocity, ξ_t_, and dissociation energy of the CN molecule, D_0_(CN), were performed when constructing the model atmospheres and calculating the synthetic spectra. The atmospheric model with T_eff_=3500K, logg=0.4, ξ_t_=3km/s, ^12^C/^13^C=8 and D_0_(CN)=7.9eV was adopted for abundance analysis. The star was found to be extremely metal-deficient, [Fe/H]=-2.48. The carbon abundance is logA(C)=7.33, the nitrogen abundance is logA(N)=5.60 corresponding to [C/Fe]=+1.3, [N/Fe]=+0.2, and [N/C]=-1.1. The carbon isotopic abundance ratio is ^12^C/^13^C=7.0. The abundances of heavy elements produced in the s-process are larger than in early-type CH stars. The ratio of overabundance of heavier s-process elements to that of lighter ones, [hs/ls]=1.0, points to a very high neutron exposure in a single irradiation event. Search for binarity of HD 187216 has failed, and the star can be an intrinsic asymptotic giant branch (AGB) carbon star with some similarities to the C stars in the dwarf galaxies. If the CH characteristics are due to mass transfer it is most likely oxygen-rich material that has been donated. The star possesses both a low nitrogen abundance and a low ^12^C/^13^C ratio, in conflict with the standard stellar evolution theory.

  6. Nontargeted Biomonitoring of Halogenated Organic Compounds in Two Ecotypes of Bottlenose Dolphins (Tursiops truncatus) from the Southern California Bight

    PubMed Central

    2015-01-01

    Targeted environmental monitoring reveals contamination by known chemicals, but may exclude potentially pervasive but unknown compounds. Marine mammals are sentinels of persistent and bioaccumulative contaminants due to their longevity and high trophic position. Using nontargeted analysis, we constructed a mass spectral library of 327 persistent and bioaccumulative compounds identified in blubber from two ecotypes of common bottlenose dolphins (Tursiops truncatus) sampled in the Southern California Bight. This library of halogenated organic compounds (HOCs) consisted of 180 anthropogenic contaminants, 41 natural products, 4 with mixed sources, 8 with unknown sources, and 94 with partial structural characterization and unknown sources. The abundance of compounds whose structures could not be fully elucidated highlights the prevalence of undiscovered HOCs accumulating in marine food webs. Eighty-six percent of the identified compounds are not currently monitored, including 133 known anthropogenic chemicals. Compounds related to dichlorodiphenyltrichloroethane (DDT) were the most abundant. Natural products were, in some cases, detected at abundances similar to anthropogenic compounds. The profile of naturally occurring HOCs differed between ecotypes, suggesting more abundant offshore sources of these compounds. This nontargeted analytical framework provided a comprehensive list of HOCs that may be characteristic of the region, and its application within monitoring surveys may suggest new chemicals for evaluation. PMID:25526519

  7. Insights into the Galactic Cosmic-ray Source from the TIGER Experiment

    NASA Technical Reports Server (NTRS)

    Link, Jason T.; Barbier, L. M.; Binns, W. R.; Christian, E. R.; Cummings, J. R.; Geier, S.; Israel, M. H.; Lodders, K.; Mewaldt,R. A.; Mitchell, J. W.; hide

    2009-01-01

    We report results from 50 days of data accumulated in two Antarctic flights of the Trans-Iron Galactic Element Recorder (TIGER). With a detector system composed of scintillators, Cherenkov detectors, and scintillating optical fibers, TIGER has a geometrical acceptance of 1.7 sq m sr and a charge resolution of 0.23 cu at Iron. TIGER has obtained abundance measurements of some of the rare galactic cosmic rays heavier than iron, including Zn, Ga, Ge, Se, and Sr, as well as the more abundant lighter elements (down to Si). The heavy elements have long been recognized as important probes of the nature of the galactic cosmic-ray source and accelerator. After accounting for fragmentation of cosmic-ray nuclei as they propagate through the Galaxy and the atmosphere above the detector system, the TIGER source abundances are consistent with a source that is a mixture of about 20% ejecta from massive stars and 80% interstellar medium with solar system composition. This result supports a model of cosmic-ray origin in OB associations previously inferred from ACE-CRIS data of more abundant lighter elements. These TIGER data also support a cosmic-ray acceleration model in which elements present in interstellar grains are accelerated preferentially compared with those found in interstellar gas.

  8. Hydrogen production from coal using a nuclear heat source

    NASA Technical Reports Server (NTRS)

    Quade, R. N.

    1976-01-01

    A strong candidate for hydrogen production in the intermediate time frame of 1985 to 1995 is a coal-based process using a high-temperature gas-cooled reactor (HTGR) as a heat source. Expected process efficiencies in the range of 60 to 70% are considerably higher than all other hydrogen production processes except steam reforming of a natural gas. The process involves the preparation of a coal liquid, hydrogasification of that liquid, and steam reforming of the resulting gaseous or light liquid product. A study showing process efficiency and cost of hydrogen vs nuclear reactor core outlet temperature has been completed, and shows diminishing returns at process temperatures above about 1500 F. A possible scenario combining the relatively abundant and low-cost Western coal deposits with the Gulf Coast hydrogen users is presented which provides high-energy density transportation utilizing coal liquids and uranium.

  9. Using Hydrogen Isotopes to Distinguish Allochthony and Autochthony in Hot Springs Ecosystems

    NASA Astrophysics Data System (ADS)

    Hungate, J.; DeSousa, T. M.; Ong, J. C.; Caron, M. M.; Brown, J. R.; Patel, N.; Dijkstra, P.; Hedlund, B. P.; Hungate, B. A.

    2013-12-01

    Hot springs are hosts to abundant and diverse microbial communities. Above the temperature threshold for photosynthesis (~73 degrees C), a variety of chemosynthetic organisms support autochthonous primary production in hot springs ecosystems. These organisms are thought to drive the carbon and energy budgets of these ecosystems, but the importance of energy inputs from the surrounding terrestrial environments - allochthonous inputs - is not well known. Here, we tested the efficacy of stable isotopes of hydrogen in distinguishing autochthonous from allochthonous sources of organic matter in hot springs ecosystems. Under laboratory conditions and in pure culture, we grew autotrophic, mixotrophic, and heterotrophic organisms from the Great Boiling Springs in northern Nevada as well as organisms typical of other hot springs environments. We measured the δ2H composition of biomass, water and organic matter sources used by the organisms to produce that biomass. We also surveyed organic matter in and around hot springs in Nevada and in the Tengchong geothermal region in China, sampling terrestrial plants at the hot springs margin, microorganisms (either scraped from surfaces or in the water column), and organic matter in the sediment accruing in the spring itself as an integrative measure of the relative importance of organic matter sources to the spring ecosystem. We found that autotrophic production in culture results in strongly depleted δ2H signatures, presumably because of fractionation against 2H-H2O during chemosynthesis. The observed difference between microbial biomass and water was larger than that typically found for terrestrial plants during photosynthesis, setting the stage for using δ2H to distinguish allochthonous from autochthonous sources of productivity in hot springs. In surveys of natural hot springs, microbial biomass sampled from the water column or from surfaces was often strongly depleted in δ2H, consistent with in situ chemosynthesis. Organic matter in sediments in the springs, however, was substantially higher in δ2H, consistent with a terrestrial origin. These results indicate that hot springs ecosystems are not biogeochemical islands, but rather receive substantial inputs of organic matter and energy produced on land. These external energy sources should be considered in a full understanding of hot springs biology and biogeochemistry.

  10. High-precision measurement of the light response of BC-418 plastic scintillator to protons with energies from 100 keV to 10 MeV

    NASA Astrophysics Data System (ADS)

    Henzl, Vladimir; Daub, Brian; French, Jennifer; Matthews, June; Kovash, Michael; Wender, Stephen; Famiano, Michael; Koehler, Katrina; Yuly, Mark

    2010-11-01

    The determination of the light response of many organic scintillators to various types of radiation has been a subject of numerous experimental as well as theoretical studies in the past. But while the data on light response to particles with energies above 1 MeV are precise and abundant, the information on light response to very low energy particles (i.e. below 1 MeV) is scarce or completely missing. In this study we measured the light response of a BC-418 scintillator to protons with energies from 100 keV to 10 MeV. The experiment was performed at Weapons Neutron Research Facility at LANSCE, Los Alamos. The neutron beam from a spallation source is used to irradiate the active target made from BC-418 plastic scintillator. The recoiled protons detected in the active target are measured in coincidence with elastically scattered incident neutrons detected by and adjacent liquid scintillator. Time of flight of the incident neutron and the knowledge of scattering geometry allow for a kinematically complete and high-precision measurement of the light response as a function of the proton energy.

  11. Nanocomposite Materials for the Sodium-Ion Battery: A Review.

    PubMed

    Liang, Yaru; Lai, Wei-Hong; Miao, Zongcheng; Chou, Shu-Lei

    2018-02-01

    Clean energy has become an important topic in recent decades because of the serious global issues related to the development of energy, such as environmental contamination, and the intermittence of the traditional energy sources. Creating new battery-related energy storage facilities is an urgent subject for human beings to address and for solutions for the future. Compared with lithium-based batteries, sodium-ion batteries have become the new focal point in the competition for clean energy solutions and have more potential for commercialization due to the huge natural abundance of sodium. Nevertheless, sodium-ion batteries still exhibit some challenges, like inferior electrochemical performance caused by the bigger ionic size of Na + ions, the detrimental volume expansion, and the low conductivity of the active materials. To solve these issues, nanocomposites have recently been applied as a new class of electrodes to enhance the electrochemical performance in sodium batteries based on advantages that include the size effect, high stability, and excellent conductivity. In this Review, the recent development of nanocomposite materials applied in sodium-ion batteries is summarized, and the existing challenges and the potential solutions are presented. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Basin evolution during the transition from continental rifting to subduction: Evidence from the lithofacies and modal petrology of the Jurassic Latady Group, Antarctic Peninsula

    NASA Astrophysics Data System (ADS)

    Willan, Robert C. R.; Hunter, Morag A.

    2005-12-01

    The Jurassic Latady Basin (southern Antarctic Peninsula) developed in a broad rift zone associated with the early stages of Gondwana extension. Early Jurassic sedimentation (˜185 Ma) occurred in small, isolated terrestrial to lacustrine rift basins in the present-day northwest and west and became shallow marine by the early Middle Jurassic. Quantitative modal analysis reveals a high proportion of mature, quartzose sandstone derived from cratonic and quartzose recycled-orogen provenances, most likely in the direction of the Ellsworth-Whitmore Mountains in the Gondwana interior. Sandstones with a more volcanolithic provenance probably represent an influx of sands from a Permian volcanic source in West Antarctica. The Early Jurassic Latady sequence contains abundant volcanic quartz and rhyodacite grains, locally derived from the nearby ignimbrites of the rift-related Mount Poster Formation (˜185 Ma). Between the Middle and Late Jurassic (?160-150 Ma), there was a dramatic change throughout the Latady Basin to higher-energy conditions with marked lateral facies variations. Sandstones contain abundant fresh volcanic detritus and plot in the transitional arc field. Their source was a nearby, active continental margin arc, but there is no outcrop of arc material on the Antarctic Peninsula from this time. A possible source area is preserved on the Thurston Island block to the southwest. However, some fluvial systems still had access to areas of uplifted metamorphic/plutonic basement and quartzose, cratonic sources. Evidence of mixing of fluvial systems from different provenances and the lack of mixing of other fluvial systems suggest a complex topography of variably uplifted fault blocks with fluvial systems constrained in narrow valleys. The change from continental rift- to arc-related sources illustrates the shift from plume- (continental provenances) to continental margin arc-dominated tectonics. Thermal relaxation in the Late Jurassic led to the final phase of deposition in anoxic, deep-water conditions in a sediment-starved marine basin stretching from Ellsworth northward into southern South America.

  13. Molecular electrocatalysts for oxidation of hydrogen using earth-abundant metals: shoving protons around with proton relays.

    PubMed

    Bullock, R Morris; Helm, Monte L

    2015-07-21

    Sustainable, carbon-neutral energy is needed to supplant the worldwide reliance on fossil fuels in order to address the persistent problem of increasing emissions of CO2. Solar and wind energy are intermittent, highlighting the need to develop energy storage on a huge scale. Electrocatalysts provide a way to convert between electrical energy generated by renewable energy sources and chemical energy in the form of chemical bonds. Oxidation of hydrogen to give two electrons and two protons is carried out in fuel cells, but the typical catalyst is platinum, a precious metal of low earth abundance and high cost. In nature, hydrogenases based on iron or iron/nickel reversibly oxidize hydrogen with remarkable efficiencies and rates. Functional models of these enzymes have been synthesized with the goal of achieving electrocatalytic H2 oxidation using inexpensive, earth-abundant metals along with a key feature identified in the [FeFe]-hydrogenase: an amine base positioned near the metal. The diphosphine ligands P(R)2N(R')2 (1,5-diaza-3,7-diphosphacyclooctane with alkyl or aryl groups on the P and N atoms) are used as ligands in Ni, Fe, and Mn complexes. The pendant amines facilitate binding and heterolytic cleavage of H2, placing the hydride on the metal and the proton on the amine. The pendant amines also serve as proton relays, accelerating intramolecular and intermolecular proton transfers. Electrochemical oxidations and deprotonations by an exogeneous amine base lead to catalytic cycles for oxidation of H2 (1 atm) at room temperature for catalysts derived from [Ni(P(Cy)2N(R')2)2](2+), Cp(C6F5)Fe(P(tBu)2N(Bn)2)H, and MnH(P(Ph)2N(Bn)2)(bppm)(CO) [bppm = (PAr(F)2)2CH2]. In the oxidation of H2 catalyzed by [Ni(P(Cy)2N(R')2)2](2+), the initial product observed experimentally is a Ni(0) complex in which two of the pendant amines are protonated. Two different pathways can occur from this intermediate; deprotonation followed by oxidation occurs with a lower overpotential than the alternate pathway involving oxidation followed by deprotonation. The Mn cation [Mn(P(Ph)2N(Bn)2)(bppm)(CO)](+) mediates the rapid (>10(4) s(-1) at -95 °C), reversible heterolytic cleavage of H2. Obtaining the optimal benefit of pendant amines incorporated into the ligand requires that the pendant amine be properly positioned to interact with a M-H or M(H2) bond. In addition, ligands are ideally selected such that the hydride-acceptor ability of the metal and the basicity of a pendant are tuned to give low barriers for heterolytic cleavage of the H-H bond and subsequent proton transfer reactions. Using these principles allows the rational design of electrocatalysts for H2 oxidation using earth-abundant metals.

  14. Widespread kelp-derived carbon in pelagic and benthic nearshore fishes

    USGS Publications Warehouse

    von Biela, Vanessa R.; Newsome, Seth D.; Bodkin, James L.; Kruse, Gordon H.; Zimmerman, Christian E.

    2016-01-01

    Kelp forests provide habitat for diverse and abundant fish assemblages, but the extent to which kelp provides a source of energy to fish and other predators is unclear. To examine the use of kelp-derived energy by fishes we estimated the contribution of kelp- and phytoplankton-derived carbon using carbon (δ13C) and nitrogen (δ15N) isotopes measured in muscle tissue. Benthic-foraging kelp greenling (Hexagrammos decagrammus) and pelagic-foraging black rockfish (Sebastes melanops) were collected at eight sites spanning ∼35 to 60°N from the California Current (upwelling) to Alaska Coastal Current (downwelling) in the northeast Pacific Ocean. Muscle δ13C values were expected to be higher for fish tissue primarily derived from kelp, a benthic macroalgae, and lower for tissue primarily derived from phytoplankton, pelagic microalgae. Muscle δ13C values were higher in benthic-feeding kelp greenling than in pelagic-feeding black rockfish at seven of eight sites, indicating more kelp-derived carbon in greenling as expected. Estimates of kelp carbon contributions ranged from 36 to 89% in kelp greenling and 32 to 65% in black rockfish using carbon isotope mixing models. Isotopic evidence suggests that these two nearshore fishes routinely derive energy from kelp and phytoplankton, across coastal upwelling and downwelling systems. Thus, the foraging mode of nearshore predators has a small influence on their ultimate energy source as energy produced by benthic macroalgae and pelagic microalgae were incorporated in fish tissue regardless of feeding mode and suggest strong and widespread benthic-pelagic coupling. Widespread kelp contributions to benthic- and pelagic-feeding fishes suggests that kelp energy provides a benefit to nearshore fishes and highlights the potential for kelp and fish production to be linked.

  15. Operational Performance Characterization of a Heat Pump System Utilizing Recycled Water as Heat Sink and Heat Source in a Cool and Dry Climate

    DOE PAGES

    Im, Piljae; Liu, Xiaobing; Henderson, Hugh

    2018-01-16

    The wastewater leaving from homes and businesses contains abundant low-grade energy, which can be utilized through heat pump technology to heat and cool buildings. Although the energy in the wastewater has been successfully utilized to condition buildings in other countries, it is barely utilized in the United States, until recently. In 2013, the Denver Museum of Nature & Science at Denver, the United States implemented a unique heat pump system that utilizes recycled wastewater from a municipal water system to cool and heat its 13,000 m 2 new addition. This recycled water heat pump (RWHP) system uses seven 105 kWmore » (cooling capacity) modular water-to-water heat pumps (WWHPs). Each WWHP uses R-410A refrigerant, has two compressors, and can independently provide either 52 °C hot water (HW) or 7 °C chilled water (CHW) to the building. This paper presents performance characterization results of this RWHP system based on the measured data from December 2014 through August 2015. The annual energy consumption of the RWHP system was also calculated and compared with that of a baseline Heating, Ventilation, and Air Conditioning (HVAC) system which meets the minimum energy efficiencies that are allowed by American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) 90.1-2013. The performance analysis results indicate that recycled water temperatures were favorable for effective operation of heat pumps. As a result, on an annual basis, the RWHP system avoided 50% of source energy consumption (resulting from reduction in natural gas consumption although electricity consumption was increased slightly), reduced CO 2 emissions by 41%, and saved 34% in energy costs as compared with the baseline system.« less

  16. Operational Performance Characterization of a Heat Pump System Utilizing Recycled Water as Heat Sink and Heat Source in a Cool and Dry Climate

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Im, Piljae; Liu, Xiaobing; Henderson, Hugh

    The wastewater leaving from homes and businesses contains abundant low-grade energy, which can be utilized through heat pump technology to heat and cool buildings. Although the energy in the wastewater has been successfully utilized to condition buildings in other countries, it is barely utilized in the United States, until recently. In 2013, the Denver Museum of Nature & Science at Denver, the United States implemented a unique heat pump system that utilizes recycled wastewater from a municipal water system to cool and heat its 13,000 m 2 new addition. This recycled water heat pump (RWHP) system uses seven 105 kWmore » (cooling capacity) modular water-to-water heat pumps (WWHPs). Each WWHP uses R-410A refrigerant, has two compressors, and can independently provide either 52 °C hot water (HW) or 7 °C chilled water (CHW) to the building. This paper presents performance characterization results of this RWHP system based on the measured data from December 2014 through August 2015. The annual energy consumption of the RWHP system was also calculated and compared with that of a baseline Heating, Ventilation, and Air Conditioning (HVAC) system which meets the minimum energy efficiencies that are allowed by American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) 90.1-2013. The performance analysis results indicate that recycled water temperatures were favorable for effective operation of heat pumps. As a result, on an annual basis, the RWHP system avoided 50% of source energy consumption (resulting from reduction in natural gas consumption although electricity consumption was increased slightly), reduced CO 2 emissions by 41%, and saved 34% in energy costs as compared with the baseline system.« less

  17. Widespread kelp-derived carbon in pelagic and benthic nearshore fishes suggested by stable isotope analysis

    NASA Astrophysics Data System (ADS)

    von Biela, Vanessa R.; Newsome, Seth D.; Bodkin, James L.; Kruse, Gordon H.; Zimmerman, Christian E.

    2016-11-01

    Kelp forests provide habitat for diverse and abundant fish assemblages, but the extent to which kelp provides a source of energy to fish and other predators is unclear. To examine the use of kelp-derived energy by fishes we estimated the contribution of kelp- and phytoplankton-derived carbon using carbon (δ13C) and nitrogen (δ15N) isotopes measured in muscle tissue. Benthic-foraging kelp greenling (Hexagrammos decagrammus) and pelagic-foraging black rockfish (Sebastes melanops) were collected at eight sites spanning ∼35 to 60°N from the California Current (upwelling) to Alaska Coastal Current (downwelling) in the northeast Pacific Ocean. Muscle δ13C values were expected to be higher for fish tissue primarily derived from kelp, a benthic macroalgae, and lower for tissue primarily derived from phytoplankton, pelagic microalgae. Muscle δ13C values were higher in benthic-feeding kelp greenling than in pelagic-feeding black rockfish at seven of eight sites, indicating more kelp-derived carbon in greenling as expected. Estimates of kelp carbon contributions ranged from 36 to 89% in kelp greenling and 32 to 65% in black rockfish using carbon isotope mixing models. Isotopic evidence suggests that these two nearshore fishes routinely derive energy from kelp and phytoplankton, across coastal upwelling and downwelling systems. Thus, the foraging mode of nearshore predators has a small influence on their ultimate energy source as energy produced by benthic macroalgae and pelagic microalgae were incorporated in fish tissue regardless of feeding mode and suggest strong and widespread benthic-pelagic coupling. Widespread kelp contributions to benthic- and pelagic-feeding fishes suggests that kelp energy provides a benefit to nearshore fishes and highlights the potential for kelp and fish production to be linked.

  18. Catalytic fast pyrolysis of lignocellulosic biomass

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Liu, Changjun; Wang, Huamin; Karim, Ayman M.

    2014-11-21

    Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectivelymore » convert lignocellulose into a liquid fuel—bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.« less

  19. Hydrothermal growth of two dimensional hierarchical MoS2 nanospheres on one dimensional CdS nanorods for high performance and stable visible photocatalytic H2 evolution

    NASA Astrophysics Data System (ADS)

    Chava, Rama Krishna; Do, Jeong Yeon; Kang, Misook

    2018-03-01

    The visible photocatalytic H2 production from water splitting considered as a clean and renewable energy source could solve the problem of greenhouse gas emission from fossil fuels. Despite tremendous efforts, the development of cost effective, highly efficient and more stable visible photocatalysts for splitting of water remains a great challenge. Here, we report the heteronanostructures consisting of hierarchical MoS2 nanospheres grown on 1D CdS nanorods referred to as CdS-MoS2 HNSs as a high performance visible photocatalyst for H2 evolution. The as-synthesized CdS-MoS2 HNSs exhibited ∼11 fold increment of H2 evolution rate when compared to pure CdS nanorods. This remarkable enhanced hydrogen evolution performance can be assigned to the positive synergetic effect from heteronanostructures formed between the CdS and MoS2 components which assist as an electron sink and source for abundant active edge sites and in turn increases the charge separation. This study presents a low-cost visible photocatalyst for solar energy conversion to achieve efficient H2.

  20. High-performance bio-piezoelectric nanogenerator made with fish scale

    NASA Astrophysics Data System (ADS)

    Ghosh, Sujoy Kumar; Mandal, Dipankar

    2016-09-01

    Energy harvesting performance of an efficient flexible bio-piezoelectric nanogenerator (BPNG) is demonstrated, where "bio-waste" transparent fish scale (FSC), composed of self-assembled and ordered collagen nano-fibrils, serves as a self-poled piezoelectric active component, exhibiting intrinsic piezoelectric strength of -5.0 pC/N. The dipolar orientation (˜19%) of the self-polarized FSC collagen is confirmed by the angular dependent near edge X-ray absorption fine structure spectroscopy. The BPNG is able to scavenge several types of ambient mechanical energies such as body movements, machine and sound vibrations, and wind flow which are abundant in living environment. Furthermore, as a power source, it generates the output voltage of 4 V, the short circuit current of 1.5 μA, and the maximum output power density of 1.14 μW/cm2 under repeated compressive normal stress of 0.17 MPa. In addition, serially integrated four BPNGs are able to produce enhanced output voltage of 14 V that turn on more than 50 blue light emitting diodes instantly, proving its essentiality as a sustainable green power source for next generation self-powered implantable medical devices as well as for personal portable electronics with reduced e-waste elements.

  1. Seasonality and abundance of truffles from oak woodlands to red fir forests

    Treesearch

    Malcolm P. North

    2002-01-01

    Truffles are an important food source for many small mammals in forest ecosystems; however, we know little about the seasonality, abundance, or diversity of the truffle community in the Sierra Nevada. This study examined how truffle abundance and diversity varied between oak woodland, ponderosa pine (Pinus ponderosa), mixed-conifer, and red fir (

  2. Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia

    PubMed Central

    Forberg, Daniel; Schwob, Tobias; Zaheer, Muhammad; Friedrich, Martin; Miyajima, Nobuyoshi; Kempe, Rhett

    2016-01-01

    Large-scale energy storage and the utilization of biomass as a sustainable carbon source are global challenges of this century. The reversible storage of hydrogen covalently bound in chemical compounds is a particularly promising energy storage technology. For this, compounds that can be sustainably synthesized and that permit high-weight% hydrogen storage would be highly desirable. Herein, we report that catalytically modified lignin, an indigestible, abundantly available and hitherto barely used biomass, can be harnessed to reversibly store hydrogen. A novel reusable bimetallic catalyst has been developed, which is able to hydrogenate and dehydrogenate N-heterocycles most efficiently. Furthermore, a particular N-heterocycle has been identified that can be synthesized catalytically in one step from the main lignin hydrogenolysis product and ammonia, and in which the new bimetallic catalyst allows multiple cycles of high-weight% hydrogen storage. PMID:27762267

  3. Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia.

    PubMed

    Forberg, Daniel; Schwob, Tobias; Zaheer, Muhammad; Friedrich, Martin; Miyajima, Nobuyoshi; Kempe, Rhett

    2016-10-20

    Large-scale energy storage and the utilization of biomass as a sustainable carbon source are global challenges of this century. The reversible storage of hydrogen covalently bound in chemical compounds is a particularly promising energy storage technology. For this, compounds that can be sustainably synthesized and that permit high-weight% hydrogen storage would be highly desirable. Herein, we report that catalytically modified lignin, an indigestible, abundantly available and hitherto barely used biomass, can be harnessed to reversibly store hydrogen. A novel reusable bimetallic catalyst has been developed, which is able to hydrogenate and dehydrogenate N-heterocycles most efficiently. Furthermore, a particular N-heterocycle has been identified that can be synthesized catalytically in one step from the main lignin hydrogenolysis product and ammonia, and in which the new bimetallic catalyst allows multiple cycles of high-weight% hydrogen storage.

  4. Triacylglycerol Metabolism, Function, and Accumulation in Plant Vegetative Tissues

    DOE PAGES

    Xu, Changcheng; Shanklin, John

    2016-02-03

    One of the most abundant energy-dense storage compounds in eukaryotes are oils in the form of triacylglycerols , and their metabolism plays a key role in cellular energy balance, lipid homeostasis, growth, and maintenance. Plants accumulate oils primarily in seeds and fruits. Moreover, plant oils are used for food and feed and, increasingly, as feedstocks for biodiesel and industrial chemicals. Although plant vegetative tissues do not accumulate significant levels of triacylglycerols, they possess a high capacity for their synthesis, storage, and metabolism. The development of plants that accumulate oil in vegetative tissues presents an opportunity for expanded production of triacylglycerolsmore » as a renewable and sustainable bioenergy source. We review recent progress in the understanding of triacylglycerol synthesis, turnover, storage, and function in leaves and discuss emerging genetic engineering strategies targeted at enhancing triacylglycerol accumulation in biomass crops. Such plants could potentially be modified to produce oleochemical feedstocks or nutraceuticals.« less

  5. Ecological role of bluefin tuna (Thunnus thynnus) fish farms for associated wild fish assemblages in the Mediterranean Sea.

    PubMed

    Stagličić, Nika; Šegvić-Bubić, Tanja; Ugarković, Pero; Talijančić, Igor; Žužul, Iva; Tičina, Vjekoslav; Grubišić, Leon

    2017-12-01

    The ecological effects of tuna fish farms are largely undocumented. This study confirmed their high capacity to attract surrounding wild fish. The aggregation effect persisted year round, without detectable seasonal differences. Farm impact was restricted to close proximity of the sea cages, and was more prominent over the bottom than in the water column strata. Tuna fish farms proved to be high energy trophic resources, as indicated by the enhanced fitness status of two focal species, bogue and seabream. Under abundant food supply, seabream appear to allocate the majority of energy reserves to gonad development. Farm associated bogue had greater parasite loads, with no detrimental effect on fitness status. Overall, tuna fish farms can be regarded as population sources for aggregated wild fish, and under the no fishing conditions within the leasehold areas, can serve as functional marine protected areas. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. STRAWBERRY CRATER ROADLESS AREAS, ARIZONA.

    USGS Publications Warehouse

    Wolfe, Edward W.; Light, Thomas D.

    1984-01-01

    The results of a mineral survey conducted in the Strawberry Crater Roadless Areas, Arizona, indicate little promise for the occurrence of metallic mineral or fossil fuel resources in the area. The area contains deposits of cinder, useful for the production of aggregate block, and for deposits of decorative stone; however, similar deposits occur in great abundance throughout the San Francisco volcanic field outside the roadless areas. There is a possibility that the Strawberry Crater Roadless Areas may overlie part of a crustal magma chamber or still warm pluton related to the San Francisco Mountain stratovolcano or to basaltic vents of late Pleistocene or Holocene age. Such a magma chamber or pluton beneath the Strawberry Crater Roadless Areas might be an energy source from which a hot-, dry-rock geothermal energy system could be developed, and a probable geothermal resource potential is therefore assigned to these areas. 9 refs.

  7. Effects of solar photovoltaic technology on the environment in China.

    PubMed

    Qi, Liqiang; Zhang, Yajuan

    2017-10-01

    Among the various types of renewable energy, solar photovoltaic has elicited the most attention because of its low pollution, abundant reserve, and endless supply. Solar photovoltaic technology generates both positive and negative effects on the environment. The environmental loss of 0.00666 yuan/kWh from solar photovoltaic technology is lower than that from coal-fired power generation (0.05216 yuan/kWh). The negative effects of solar photovoltaic system production include wastewater and waste gas pollutions, the representatives of which contain fluorine, chromium with wastewater and hydrogen fluoride, and silicon tetrachloride gas. Solar panels are also a source of light pollution. Improper disposal of solar cells that have reached the end of their service life harms the environment through the stench they produce and the damage they cause to the soil. So, the positive and negative effects of green energy photovoltaic power generation technology on the environment should be considered.

  8. Strawberry Crater Roadless Areas, Arizona

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wolfe, E.W.; Light, T.D.

    1984-01-01

    The results of a mineral survey conducted in 1980 in the Strawberry Crater Roadless Areas, Arizona, indicate little promise for the occurrence of metallic mineral or fossil fuel resources in the area. The area contains deposits of cinder, useful for the production of aggregate block, and for deposits of decorative stone; however, similar deposits occur in great abundance throughout the San Francisco volcanic field outside the roadless areas. There is a possibility that the Strawberry Crater Roadless Areas may overlie part of a crustal magma chamber or still warm pluton related to the San Francisco Mountain stratovolcano or to basalticmore » vents of late Pleistocene or Holocene age. Such a magma chamber or pluton beneath the Strawberry Crater Roadless Areas might be an energy source from which a hot-, dry-rock geothermal energy system could be developed, and a probable geothermal resource potential is therefore assigned to these areas.« less

  9. Carbon and Carbon Hybrid Materials as Anodes for Sodium-Ion Batteries.

    PubMed

    Zhong, Xiongwu; Wu, Ying; Zeng, Sifan; Yu, Yan

    2018-02-12

    Sodium-ion batteries (SIBs) have attracted much attention for application in large-scale grid energy storage owing to the abundance and low cost of sodium sources. However, low energy density and poor cycling life hinder practical application of SIBs. Recently, substantial efforts have been made to develop electrode materials to push forward large-scale practical applications. Carbon materials can be directly used as anode materials, and they show excellent sodium storage performance. Additionally, designing and constructing carbon hybrid materials is an effective strategy to obtain high-performance anodes for SIBs. In this review, we summarize recent research progress on carbon and carbon hybrid materials as anodes for SIBs. Nanostructural design to enhance the sodium storage performance of anode materials is discussed, and we offer some insight into the potential directions of and future high-performance anode materials for SIBs. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Measurement of Cosmic-Ray TeV Electrons

    NASA Astrophysics Data System (ADS)

    Schubnell, Michael; Anderson, T.; Bower, C.; Coutu, S.; Gennaro, J.; Geske, M.; Mueller, D.; Musser, J.; Nutter, S.; Park, N.; Tarle, G.; Wakely, S.

    2011-09-01

    The Cosmic Ray Electron Synchrotron Telescope (CREST) high-altitude balloon experiment is a pathfinding effort to detect for the first time multi-TeV cosmic-ray electrons. At these energies distant sources will not contribute to the local electron spectrum due to the strong energy losses of the electrons and thus TeV observations will reflect the distribution and abundance of nearby acceleration sites. CREST will detect electrons indirectly by measuring the characteristic synchrotron photons generated in the Earth's magnetic field. The instrument consist of an array of 1024 BaF2 crystals viewed by photomultiplier tubes surrounded by a hermetic scintillator shield. Since the primary electron itself need not traverse the payload, an effective detection area is achieved that is several times the nominal 6.4 m2 instrument. CREST is scheduled to fly in a long duration circumpolar orbit over Antarctica during the 2011-12 season.

  11. DOE Office of Scientific and Technical Information (OSTI.GOV)

    Xu, Changcheng; Shanklin, John

    One of the most abundant energy-dense storage compounds in eukaryotes are oils in the form of triacylglycerols , and their metabolism plays a key role in cellular energy balance, lipid homeostasis, growth, and maintenance. Plants accumulate oils primarily in seeds and fruits. Moreover, plant oils are used for food and feed and, increasingly, as feedstocks for biodiesel and industrial chemicals. Although plant vegetative tissues do not accumulate significant levels of triacylglycerols, they possess a high capacity for their synthesis, storage, and metabolism. The development of plants that accumulate oil in vegetative tissues presents an opportunity for expanded production of triacylglycerolsmore » as a renewable and sustainable bioenergy source. We review recent progress in the understanding of triacylglycerol synthesis, turnover, storage, and function in leaves and discuss emerging genetic engineering strategies targeted at enhancing triacylglycerol accumulation in biomass crops. Such plants could potentially be modified to produce oleochemical feedstocks or nutraceuticals.« less

  12. Hydrogen production from algal biomass - Advances, challenges and prospects.

    PubMed

    Show, Kuan-Yeow; Yan, Yuegen; Ling, Ming; Ye, Guoxiang; Li, Ting; Lee, Duu-Jong

    2018-06-01

    Extensive effort is being made to explore renewable energy in replacing fossil fuels. Biohydrogen is a promising future fuel because of its clean and high energy content. A challenging issue in establishing hydrogen economy is sustainability. Biohydrogen has the potential for renewable biofuel, and could replace current hydrogen production through fossil fuel thermo-chemical processes. A promising source of biohydrogen is conversion from algal biomass, which is abundant, clean and renewable. Unlike other well-developed biofuels such as bioethanol and biodiesel, production of hydrogen from algal biomass is still in the early stage of development. There are a variety of technologies for algal hydrogen production, and some laboratory- and pilot-scale systems have demonstrated a good potential for full-scale implementation. This work presents an elucidation on development in biohydrogen encompassing biological pathways, bioreactor designs and operation and techno-economic evaluation. Challenges and prospects of biohydrogen production are also outlined. Copyright © 2018 Elsevier Ltd. All rights reserved.

  13. Triacylglycerol Metabolism, Function, and Accumulation in Plant Vegetative Tissues.

    PubMed

    Xu, Changcheng; Shanklin, John

    2016-04-29

    Oils in the form of triacylglycerols are the most abundant energy-dense storage compounds in eukaryotes, and their metabolism plays a key role in cellular energy balance, lipid homeostasis, growth, and maintenance. Plants accumulate oils primarily in seeds and fruits. Plant oils are used for food and feed and, increasingly, as feedstocks for biodiesel and industrial chemicals. Although plant vegetative tissues do not accumulate significant levels of triacylglycerols, they possess a high capacity for their synthesis, storage, and metabolism. The development of plants that accumulate oil in vegetative tissues presents an opportunity for expanded production of triacylglycerols as a renewable and sustainable bioenergy source. Here, we review recent progress in the understanding of triacylglycerol synthesis, turnover, storage, and function in leaves and discuss emerging genetic engineering strategies targeted at enhancing triacylglycerol accumulation in biomass crops. Such plants could potentially be modified to produce oleochemical feedstocks or nutraceuticals.

  14. Light-dependent microbial metabolisms drive carbon fluxes on glacier surfaces.

    PubMed

    Franzetti, Andrea; Tagliaferri, Ilario; Gandolfi, Isabella; Bestetti, Giuseppina; Minora, Umberto; Mayer, Christoph; Azzoni, Roberto S; Diolaiuti, Guglielmina; Smiraglia, Claudio; Ambrosini, Roberto

    2016-12-01

    Biological processes on glacier surfaces affect glacier reflectance, influence surface energy budget and glacier response to climate warming, and determine glacier carbon exchange with the atmosphere. Currently, carbon balance of supraglacial environment is assessed as the balance between the activity of oxygenic phototrophs and the respiration rate of heterotrophic organisms. Here we present a metagenomic analysis of tiny wind-blown supraglacial sediment (cryoconite) from Baltoro (Pakistani Karakoram) and Forni (Italian Alps) glaciers, providing evidence for the occurrence in these environments of different and previously neglected metabolic pathways. Indeed, we observed high abundance of heterotrophic anoxygenic phototrophs, suggesting that light might directly supplement the energy demand of some bacterial strains allowing them to use as carbon source organic molecules, which otherwise would be respired. Furthermore, data suggest that CO 2 could be produced also by microbiologically mediated oxidation of CO, which may be produced by photodegradation of organic matter.

  15. Identification and characterisation of isoprene-degrading bacteria in an estuarine environment.

    PubMed

    Johnston, Antonia; Crombie, Andrew T; El Khawand, Myriam; Sims, Leanne; Whited, Gregg M; McGenity, Terry J; Colin Murrell, J

    2017-09-01

    Approximately one-third of volatile organic compounds (VOCs) emitted to the atmosphere consists of isoprene, originating from the terrestrial and marine biosphere, with a profound effect on atmospheric chemistry. However, isoprene provides an abundant and largely unexplored source of carbon and energy for microbes. The potential for isoprene degradation in marine and estuarine samples from the Colne Estuary, UK, was investigated using DNA-Stable Isotope Probing (DNA-SIP). Analysis at two timepoints showed the development of communities dominated by Actinobacteria including members of the genera Mycobacterium, Rhodococcus, Microbacterium and Gordonia. Representative isolates, capable of growth on isoprene as sole carbon and energy source, were obtained from marine and estuarine locations, and isoprene-degrading strains of Gordonia and Mycobacterium were characterised physiologically and their genomes were sequenced. Genes predicted to be required for isoprene metabolism, including four-component isoprene monooxygenases (IsoMO), were identified and compared with previously characterised examples. Transcriptional and activity assays of strains growing on isoprene or alternative carbon sources showed that growth on isoprene is an inducible trait requiring a specific IsoMO. This study is the first to identify active isoprene degraders in estuarine and marine environments using DNA-SIP and to characterise marine isoprene-degrading bacteria at the physiological and molecular level. © 2017 The Authors. Environmental Microbiology published by Society for Applied Microbiology and John Wiley & Sons Ltd.

  16. Hybrid Energy: Combining Nuclear and Other Energy Sources

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kim, Jong Suk; Garcia, Humberto E.

    2015-02-01

    The leading cause of global climate change is generally accepted to be growing emissions of greenhouse gas (GHG) as a result of increased use of fossil fuels [1]. Among various sources of GHG, the global electricity supply sector generates the largest share of GHG emissions (37.5% of total CO2 emissions) [2]. Since the current electricity production heavily relies on fossil fuels, it is envisioned that bolstering generation technologies based on non-emitting energy sources, i.e., nuclear and/or renewables could reduce future GHG emissions. Integrated nuclear-renewable hybrid energy systems HES) are very-low-emitting options, but they are capital-intensive technologies that should operate atmore » full capacities to maximize profits. Hence, electricity generators often pay the grid to take electricity when demand is low, resulting in negative profits for many hours per year. Instead of wasting an excess generation capacity at negative profit during off-peak hours when electricity prices are low, nuclear-renewable HES could result in positive profits by storing and/or utilizing surplus thermal and/or electrical energy to produce useful storable products to meet industrial and transportation demands. Consequently, it is necessary (1) to identify key integrated system options based on specific regions and (2) to propose optimal operating strategy to economically produce products on demand. In prioritizing region-specific HES options, available resources, markets, existing infrastructures, and etc. need to be researched to identify attractive system options. For example, the scarcity of water (market) and the availability of abundant solar radiation make solar energy (resource) a suitable option to mitigate the water deficit the Central-Southern region of the U.S. Thus, a solar energy-driven desalination process would be an attractive option to be integrated into a nuclear power plant to support the production of fresh water in this region. In this work, we introduce a particular HES option proposed for a specific U.S. region and briefly describe our modeling assumptions and procedure utilized for its analysis. Preliminary simulation results are also included addressing several technical characteristics of the proposed nuclear-renewable HES.« less

  17. A reanalysis of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds

    NASA Technical Reports Server (NTRS)

    Jarrold, M. F.; Bowers, M. T.; Defrees, D. J.; Mclean, A. D.; Herbst, E.

    1986-01-01

    New theoretical and experimental results have prompted a reinvestigation of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds. These results pertain principally but not exclusively to the reaction between HOC(+) and H2, which was previously calculated by DeFrees et al. (1984) to possess a large activation energy barrier. New calculations, reported here, indicate that this activation energy barrier is quite small and may well be zero. In addition, experimental results at higher energy and temperature indicate strongly that the reaction proceeds efficiently at interstellar temperatures. If HOC(+) does indeed react efficiently with H2 in interstellar clouds, the calculated HCO(+)/HOC(+) abundance ratio rises to a substantially greater value under standard dense cloud conditions than is deduced via the tentative observation of HOC(+) in Sgr B2.

  18. Role of the Coronal Alfvén Speed in Modulating the Solar-wind Helium Abundance

    NASA Astrophysics Data System (ADS)

    Wang, Y.-M.

    2016-12-01

    The helium abundance He/H in the solar wind is relatively constant at ˜0.04 in high-speed streams, but varies in phase with the sunspot number in slow wind, from ˜0.01 at solar minimum to ˜0.04 at maximum. Suggested mechanisms for helium fractionation have included frictional coupling to protons and resonant interactions with high-frequency Alfvénic fluctuations. We compare He/H measurements during 1995-2015 with coronal parameters derived from source-surface extrapolations of photospheric field maps. We find that the near-Earth helium abundance is an increasing function of the magnetic field strength and Alfvén speed v A in the outer corona, while being only weakly correlated with the proton flux density. Throughout the solar cycle, fast wind is associated with short-term increases in v A near the source surface; resonance with Alfvén waves, with v A and the relative speed of α-particles and protons decreasing with increasing heliocentric distance, may then lead to enhanced He/H at 1 au. The modulation of helium in slow wind reflects the tendency for the associated coronal Alfvén speeds to rise steeply from sunspot minimum, when this wind is concentrated around the source-surface neutral line, to sunspot maximum, when the source-surface field attains its peak strengths. The helium abundance near the source surface may represent a balance between collisional decoupling from protons and Alfvén wave acceleration.

  19. Coarse particle (PM10-2.5) source profiles for emissions from domestic cooking and industrial process in Central India.

    PubMed

    Bano, Shahina; Pervez, Shamsh; Chow, Judith C; Matawle, Jeevan Lal; Watson, John G; Sahu, Rakesh Kumar; Srivastava, Anjali; Tiwari, Suresh; Pervez, Yasmeen Fatima; Deb, Manas Kanti

    2018-06-15

    To develop coarse particle (PM 10-2.5 , 2.5 to 10μm) chemical source profiles, real-world source sampling from four domestic cooking and seven industrial processing facilities were carried out in "Raipur-Bhilai" of Central India. Collected samples were analysed for 32 chemical species including 21 elements (Al, As, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Mo, Na, Ni, Pb, S, Sb, Se, V, and Zn) by atomic absorption spectrophotometry (AAS), 8 water-soluble ions (Na + , K + , Mg 2+ , Ca 2+ , Cl - , F - , NO 3 - , and SO 4 2- ) by ion chromatography, ammonium (NH 4 + ) by spectrophotometry, and carbonaceous fractions (OC and EC) by thermal/optical transmittance. The carbonaceous fractions were most abundant fraction in household fuel and municipal solid waste combustion emissions while elemental species were more abundant in industrial emissions. Most of the elemental species were enriched in PM 2.5 (<2.5μm) size fraction as compared to the PM 10-2.5 fraction. Abundant Ca (13-28%) was found in steel-rolling mill (SRM) and cement production industry (CPI) emissions, with abundant Fe (14-32%) in ferro-manganese (FEMNI), steel production industry (SPI), and electric-arc welding emissions. High coefficients of divergence (COD) values (0.46 to 0.88) among the profiles indicate their differences. These region-specific source profiles are more relevant to source apportionment studies in India than profiles measured elsewhere. Copyright © 2018. Published by Elsevier B.V.

  20. Microbial Colonization of Earth's Subsurface: A Thermodynamically Consistent Perspective

    NASA Astrophysics Data System (ADS)

    Bethke, C. M.; Sanford, R. A.; Jin, Q.; Kirk, M. F.

    2014-12-01

    The nature of how anaerobic microbes have come to distribute themselves within Earth's crust is an ecologic question that must be posed subject to the laws of thermodynamics, but a question that cannot be understood in light of thermodynamics alone. We use here the results of theory and quantitative modeling, field observations, and long-term laboratory experiments to argue that subsurface communities are composed of groups of microbes that cooperate as well as compete, and whose existence reflects a tight balance between reproduction and cell death. The most significant functional groups colonizing the anoxic crust, classified by electron accepting process, are the methanogens, sulfate reducers, and ferric iron reducers. An anaerobe can harvest the energy it needs to live and reproduce only to the extent that energy available to it in the environment exceeds the cell's internal levels. When methanogens transfer or dismutate electrons, they capture little energy, so as to preserve a thermodynamic drive for their catabolic reaction. In this way, they maximize their environmental range, but grow slowly. Sulfate reducers adopt a different strategy, striving to capture energy quickly and grow rapidly. Iron reduction consumes acid, so the energy available to iron reducers varies sharply with pH. The iron reducers can grow rapidly under acidic conditions, but an alkaline environment may leave them insufficient energy to live. Methane producers are vulnerable to exclusion in the subsurface, as is broadly appreciated, but not because of energetic limitations. Instead, the methanogens require abundant energy substrates in order to reproduce quickly enough to replace cells as they die. Sulfate reducers and iron reducers, instead of working to exclude each other by competing for limited energy sources, as is commonly believed, thrive in mutualistic communities. The three functional groups by necessity compete in their environments for limited sources of energy, but the manner in which the groups have come to colonize the subsurface is richer and more nuanced than can be explained by competition alone.

  1. Maternal nutritional manipulation of placental growth and glucose transporter 1 (GLUT-1) abundance in sheep.

    PubMed

    Dandrea, J; Wilson, V; Gopalakrishnan, G; Heasman, L; Budge, H; Stephenson, T; Symonds, M E

    2001-11-01

    Glucose transporter 1 (GLUT-1) is the predominant glucose transporter in the placenta but the extent to which its abundance is nutritionally regulated is unknown. This study investigated the effects of restricted maternal nutrition between day 28 and day 80 of gestation followed by re-feeding to either meet or to exceed the total energy requirements on placental size and GLUT-1 abundance at mid-gestation (that is, day 80) and near to term (that is, days 140-145 of gestation; term = 147 days). Singleton bearing ewes either consumed 8.7-9.9 MJ day(-1) of metabolizable energy (that is, well fed) or 3.2-3.8 MJ day(-1) of metabolizable energy (that is, nutrient restricted) from day 28 to day 80 of gestation, after which stage they consumed either 6.5-7.5 MJ day(-1) (that is, adequately fed) or 8.0-10.9 MJ day(-1) (that is, well fed) of metabolizable energy until near to term. In all ewes, at both sampling dates, the abundance of GLUT-1 was higher in the maternal component than in the fetal component of the placenta. Immunohistochemistry confirmed that GLUT-1 was located in the maternal uterine syncytium. At day 80 of gestation, placental mass was lower (P < 0.05) in the nutrient restricted group, but there was no difference in the abundance of GLUT-1 between the nutrient restricted group and the well fed group. At near term, placental mass was greater (P < 0.05) in ewes that were nutrient restricted during early to mid-gestation and then adequately fed up to term compared with ewes that were well fed during early to mid-gestation. This increase was associated with a higher (P < 0.05) abundance of total placental GLUT-1 and a larger fetus. There was no effect of previous nutrient restriction on placental mass, fetal weight or GLUT-1 abundance at term, when ewes were well fed in the second half of gestation. In conclusion, maternal nutrient restriction between early to mid-gestation alters placental growth but has no effect on placental GLUT-1 abundance. Increasing maternal feed intake to meet calculated energy requirements in previously nutrient restricted ewes during the second half of gestation, increases placental mass and fetal weight, and the abundance of GLUT-1, an adaptation not observed if maternal food intake is increased above requirements.

  2. Test Would Quantify Combustion Oxygen From Different Sources

    NASA Technical Reports Server (NTRS)

    Tapphorn, Ralph M.

    1993-01-01

    Proposed isotope-enrichment scheme enables determination of contributions of dual sources of oxygen for combustion. Liquid oxygen or other artificial stream enriched with O(18) to about 1 percent by weight. Combustion products analyzed by mass spectrometer to measure relative abundances of H2O(18) and H2O(16). From relative abundances of water products measured, one computes relative contribution of oxygen extracted from stream compared to other source of oxygen in combustion process. Used to determine contributions of natural oxygen in air and liquid oxygen supplied in separate stream mixed with air or sent directly into combustion chamber.

  3. Dynamic relationships between body size, species richness, abundance, and energy use in a shallow marine epibenthic faunal community

    PubMed Central

    Labra, Fabio A; Hernández-Miranda, Eduardo; Quiñones, Renato A

    2015-01-01

    We study the temporal variation in the empirical relationships among body size (S), species richness (R), and abundance (A) in a shallow marine epibenthic faunal community in Coliumo Bay, Chile. We also extend previous analyses by calculating individual energy use (E) and test whether its bivariate and trivariate relationships with S and R are in agreement with expectations derived from the energetic equivalence rule. Carnivorous and scavenger species representing over 95% of sample abundance and biomass were studied. For each individual, body size (g) was measured and E was estimated following published allometric relationships. Data for each sample were tabulated into exponential body size bins, comparing species-averaged values with individual-based estimates which allow species to potentially occupy multiple size classes. For individual-based data, both the number of individuals and species across body size classes are fit by a Weibull function rather than by a power law scaling. Species richness is also a power law of the number of individuals. Energy use shows a piecewise scaling relationship with body size, with energetic equivalence holding true only for size classes above the modal abundance class. Species-based data showed either weak linear or no significant patterns, likely due to the decrease in the number of data points across body size classes. Hence, for individual-based size spectra, the SRA relationship seems to be general despite seasonal forcing and strong disturbances in Coliumo Bay. The unimodal abundance distribution results in a piecewise energy scaling relationship, with small individuals showing a positive scaling and large individuals showing energetic equivalence. Hence, strict energetic equivalence should not be expected for unimodal abundance distributions. On the other hand, while species-based data do not show unimodal SRA relationships, energy use across body size classes did not show significant trends, supporting energetic equivalence. PMID:25691966

  4. Determinants of seed removal distance by scatter-hoarding rodents in deciduous forests.

    PubMed

    Moore, Jeffrey E; McEuen, Amy B; Swihart, Robert K; Contreras, Thomas A; Steele, Michael A

    2007-10-01

    Scatter-hoarding rodents should space food caches to maximize cache recovery rate (to minimize loss to pilferers) relative to the energetic cost of carrying food items greater distances. Optimization models of cache spacing make two predictions. First, spacing of caches should be greater for food items with greater energy content. Second, the mean distance between caches should increase with food abundance. However, the latter prediction fails to account for the effect of food abundance on the behavior of potential pilferers or on the ability of caching individuals to acquire food by means other than recovering their own caches. When considering these factors, shorter cache distances may be predicted in conditions of higher food abundance. We predicted that seed caching distances would be greater for food items of higher energy content and during lower ambient food abundance and that the effect of seed type on cache distance variation would be lower during higher food abundance. We recorded distances moved for 8636 seeds of five seed types at 15 locations in three forested sites in Pennsylvania, USA, and 29 forest fragments in Indiana, U.S.A., across five different years. Seed production was poor in three years and high in two years. Consistent with previous studies, seeds with greater energy content were moved farther than less profitable food items. Seeds were dispersed less far in seed-rich years than in seed-poor years, contrary to predictions of conventional models. Interactions were important, with seed type effects more evident in seed-poor years. These results suggest that, when food is superabundant, optimal cache distances are more strongly determined by minimizing energy cost of caching than by minimizing pilfering rates and that cache loss rates may be more strongly density-dependent in times of low seed abundance.

  5. Particle acceleration and gamma rays in solar flares: Recent observations and new modeling

    NASA Astrophysics Data System (ADS)

    Miroshnichenko, L. I.; Gan, W. Q.

    2012-09-01

    Experiments on SMM, GAMMA, Yohkoh, GRANAT, Compton GRO, INTEGRAL, RHESSI and CORONAS-F satellites over the past three decades have provided copious data for fundamental research relating to particle acceleration, transport and energetics of flares and to the ambient abundance of the solar corona, chromosphere and photosphere. We summarize main results of solar gamma-astronomy (including some results of several joint Russian-Chinese projects) and try to appraise critically a real contribution of those results into modern understanding of solar flares, particle acceleration at the Sun and some properties of the solar atmosphere. Recent findings based on the RHESSI, INTEGRAL and CORONAS-F measurements (source locations, spectrum peculiarities, 3He abundance etc.) are especially discussed. Some unusual features of extreme solar events (e.g., 28 October 2003 and 20 January 2005) have been found in gamma-ray production and generation of relativistic particles (solar cosmic rays, or SCR). A number of different plausible assumptions are considered concerning the details of underlying physical processes during large flares: (1) existence of a steeper distribution of surrounding medium density as compared to a standard astrophysical model (HSRA) for the solar atmosphere; (2) enhanced content of the 3He isotope; (3) formation of magnetic trap with specific properties; (4) prevailing non-uniform (e.g., fan-like) velocity (angular) distributions of secondary neutrons, etc. It is emphasized that real progress in this field may be achieved only by combination of gamma-ray data in different energy ranges with multi-wave and energetic particle observations during the same event. We especially note several promising lines for the further studies: (1) resonant acceleration of the 3He ions in the corona; (2) timing of the flare evolution by gamma-ray fluxes in energy range above 90 MeV; (3) separation of gamma-ray fluxes from different sources at/near the Sun (e.g., different acceleration sources/episodes during the same flare, contribution of energetic particles accelerated by the CME-driven shocks etc.); (4) asymmetric magnetic geometry and new magnetic topology models of the near-limb flares; (5) modeling of self-consistent time scenario of the event.

  6. Integration of permanent magnet synchronous generator wind turbines into power grid

    NASA Astrophysics Data System (ADS)

    Abedini, Asghar

    The world is seeing an ever-increasing demand for electrical energy. The future growth of electrical power generation needs to be a mix of technologies including fossil fuels, hydro, nuclear, wind, and solar. The federal and state energy agencies have taken several proactive steps to increase the share of renewable energy in the total generated electrical power. In 2005, 11.1% of the total 1060 GW electricity generation capacity was from Renewable Energy Sources (RES) in the US. The power capacity portfolio included 9.2% from hydroelectric, 0.87% from wind, and 0.7% from biomass. Other renewable power capacity included 2.8 GW of geothermal, 0.4 GW of solar thermal, and 0.2 GW of solar PV. Although the share of renewable energy sources is small compared with the total power capacity, they are experiencing a high and steady growth. The US is leading the world in wind energy growth with a 27% increase in 2006 and a projected 26% increase in 2007, according to the American Wind Energy Association (AWEA). The US Department of Energy benchmarked a goal to meet 5% of the nation's energy need by launching the Wind Powering America (WPA) program. Although renewable energy sources have many benefits, their utilization in the electrical grid does not come without cost. The higher penetration of RES has introduced many technical and non-technical challenges, including power quality, reliability, safety and protection, load management, grid interconnections and control, new regulations, and grid operation economics. RES such as wind and PV are also intermittent in nature. The energy from these sources is available as long as there is wind or sunlight. However, these are energies that are abundant in the world and the power generated from these sources is pollution free. Due to high price of foundation of wind farms, employing variable speed wind turbines to maximize the extracted energy from blowing wind is more beneficial. On the other hand, since wind power is intermittent, integrating energy storage systems with wind farms has attracted a lot of attention. These two subjects are addressed in this dissertation in detail. Permanent Magnet Synchronous Generators (PMSG) are used in variable speed wind turbines. In this thesis, the dynamic of the PMSG is investigated and a power electronic converter is designed to integrate the wind turbine to the grid. The risks of PMSG wind turbines such as low voltage ride through and short circuits, are assessed and the methods of mitigating the risks are discussed. In the second section of the thesis, various methods of smoothing wind turbine output power are explained and compared. Two novel methods of output power smoothing are analyzed: Rotor inertia and Super capacitors. The advantages and disadvantages of each method are explained and the dynamic model of each method is developed. The performance of the system is evaluated by simulating the wind turbine system in each method. The concepts of the methods of smoothing wind power can be implemented in other types of wind turbines such as Doubly Fed Induction Generator (DFIG) wind turbines.

  7. Atmospheric energy for subsurface life on Mars?

    PubMed Central

    Weiss, Benjamin P.; Yung, Yuk L.; Nealson, Kenneth H.

    2000-01-01

    The location and density of biologically useful energy sources on Mars will limit the biomass, spatial distribution, and organism size of any biota. Subsurface Martian organisms could be supplied with a large energy flux from the oxidation of photochemically produced atmospheric H2 and CO diffusing into the regolith. However, surface abundance measurements of these gases demonstrate that no more than a few percent of this available flux is actually being consumed, suggesting that biological activity driven by atmospheric H2 and CO is limited in the top few hundred meters of the subsurface. This is significant because the available but unused energy is extremely large: for organisms at 30-m depth, it is 2,000 times previous estimates of hydrothermal and chemical weathering energy and far exceeds the energy derivable from other atmospheric gases. This also implies that the apparent scarcity of life on Mars is not attributable to lack of energy. Instead, the availability of liquid water may be a more important factor limiting biological activity because the photochemical energy flux can only penetrate to 100- to 1,000-m depth, where most H2O is probably frozen. Because both atmospheric and Viking lander soil data provide little evidence for biological activity, the detection of short-lived trace gases will probably be a better indicator of any extant Martian life. PMID:10660689

  8. Unobtainium? Critical Elements for New Energy Technologies

    NASA Astrophysics Data System (ADS)

    Jaffe, Robert

    2011-03-01

    I will report on a recently completed study jointly sponsored by the APS Panel on Public Affairs (POPA) and the Material Research Society (MRS). The twin pressures of increasing demand for energy and increasing concern about anthropogenic climate change have stimulated research into new sources of energy and novel ways to harvest, transmit, store, transform or conserve it. At the same time, advances in physics, chemistry, and material science have enabled researchers to identify chemical elements with properties that can be finely tuned to their specific needs and to employ them in new energy-related technologies. Elements like dysprosium, gallium, germanium, indium, lanthanum, neodymium, rhenium, or tellurium, which were once laboratory curiosities, now figure centrally when novel energy systems are discussed. Many of these elements are not at present mined, refined, or traded in large quantities. However new technologies can only impact our energy needs if they can be scaled from laboratory, to demonstration, to massive implementation. As a result, some previously unfamiliar elements will be needed in great quantities. We refer to these elements as energy-critical elements (ECEs). Although the technologies in which they are employed and their abundance in the Earth's crust vary greatly, ECEs have many features in common. The purpose of the POPA/MRS study was to evaluate constraints on availability of energy-critical elements and to make recommendations that can help avoid these obstructions.

  9. Using the urtA Gene to Profile Nitrogen Stress Adaptation and Spatio-Temporal Abundance of Synechococcus Clades in the California Current System

    NASA Astrophysics Data System (ADS)

    Chatterjee, T.; Shilova, I. N.; Zehr, J. P.

    2015-12-01

    Among the planet's most abundant photosynthetic groups, the picocyanobacteria Synechococcus contributes nearly a quarter of our global oxygen supply. Urea, from both natural and anthropogenic sources, is an important alternative to the preferred yet limited sources of reduced nitrogen for cyanobacteria in the marine environment. While urea uptake activity has been observed during nitrogen (N) limitation, this stress adaptation is not well-studied in natural habitats. We propose the urtAgene, which encodes the substrate-binding subunit of the urea-uptake ABC transporter, as a molecular marker to profile cell abundance and stress response in relation to N fluctuation. Strains prevalent in temperate waters of the California Current System - Synechococcus CC9311 (clade I), CC9605 (clade II) and CC9902/BL107 (clade IV) - were targeted by clade-specific qPCR assays to measure urtA gene copy abundance in samples from different geographical stations and a time-series. Spatial and seasonal patterns in clade abundance resembled those previously reported by studies using other Synechococcus marker genes, thus validating urtA as a strong marker. Synechococcus clades I and IV were most abundant in coastal and transitional stations, while the more oligotrophic clade II was detected near open waters. Synechococcus abundances were highest before and after the annual upwelling season, as supported by a non clade-specific rbcL-qPCR assay. A lack of correlation between abundance and nitrate availability indicated utilization of alternative nitrogen sources like urea, which was further evidenced by the detection of clade IV urtA transcripts at the station closest to shore. Urea concentrations tend to be highest in coastal environments due to fertilizer runoff, which can stimulate phytoplankton blooms including harmful algal blooms. This study adds to insight on how such environmental factors are related to N-cycling and patterns of urea-assimilating microbial populations like Synechococcus subgroups in the California Current waters of the Pacific Ocean.

  10. Quantifying the Contributions of Environmental Parameters to Ceres Surface Net Radiation Error in China

    NASA Astrophysics Data System (ADS)

    Pan, X.; Yang, Y.; Liu, Y.; Fan, X.; Shan, L.; Zhang, X.

    2018-04-01

    Error source analyses are critical for the satellite-retrieved surface net radiation (Rn) products. In this study, we evaluate the Rn error sources in the Clouds and the Earth's Radiant Energy System (CERES) project at 43 sites from July in 2007 to December in 2007 in China. The results show that cloud fraction (CF), land surface temperature (LST), atmospheric temperature (AT) and algorithm error dominate the Rn error, with error contributions of -20, 15, 10 and 10 W/m2 (net shortwave (NSW)/longwave (NLW) radiation), respectively. For NSW, the dominant error source is algorithm error (more than 10 W/m2), particularly in spring and summer with abundant cloud. For NLW, due to the high sensitivity of algorithm and large LST/CF error, LST and CF are the largest error sources, especially in northern China. The AT influences the NLW error large in southern China because of the large AT error in there. The total precipitable water has weak influence on Rn error even with the high sensitivity of algorithm. In order to improve Rn quality, CF and LST (AT) error in northern (southern) China should be decreased.

  11. Exploring molecular complexity with ALMA (EMoCA): Simulations of branched carbon-chain chemistry in Sgr B2(N)

    NASA Astrophysics Data System (ADS)

    Garrod, R. T.; Belloche, A.; Müller, H. S. P.; Menten, K. M.

    2017-05-01

    Context. Using millimeter wavelength data from the Atacama Large Millimeter/submillimeter Array (ALMA), the EMoCA spectral line survey recently revealed the presence of both the straight-chain (normal) and branched (iso) forms of propyl cyanide (C3H7CN) toward the Galactic Center star-forming source Sgr B2(N2). This was the first interstellar detection of a branched aliphatic molecule. Aims: Through computational methods, we seek to explain the observed I:n ratio for propyl cyanide, and to predict the abundances of the four different forms of the homologous nitrile, butyl cyanide (C4H9CN). We also investigate whether other molecules will show a similar degree of branching, by modeling the chemistry of alkanes up to pentane (C5H12). Methods: We use the coupled three-phase chemical kinetics model, MAGICKAL, to simulate the chemistry of the hot-core source Sgr B2(N2), using an updated chemical network that includes grain-surface/ice-mantle formation routes for branched nitriles and alkanes. The network explicitly considers radical species with an unpaired electron on either the primary or secondary carbon in a chain. We also include mechanisms for the addition of the cyanide radical, CN, to hydrocarbons with multiple bonds between carbon atoms, using activation energy barriers from the literature. We use the EMoCA survey data to search for the straight-chain form of butyl cyanide toward Sgr B2(N2). Results: The observed I:n ratio for propyl cyanide is reproduced by the models, with intermediate to fast warm-up timescales providing the most accurate result. Butyl cyanide is predicted to show similar abundances to propyl cyanide, and to exhibit strong branching, with the sec form clearly dominant over all others. Normal and iso-butyl cyanide are expected to have similar abundances to each other, while the tert form is significantly less abundant. The addition of CN to acetylene and ethene is found to be important to the production of vinyl, ethyl, propyl, and butyl cyanide. The alkanes also show significant branching. We report a non-detection of n-C4H9CN toward Sgr B2(N2), with an abundance at least 1.7 times lower than that of n-C3H7CN. This value is within the range predicted by the chemical models. Conclusions: The models indicate that the degree of branching rises with increasing molecular size. The efficiency of CN addition to unsaturated hydrocarbons boosts the abundances of nitriles in the model, and enhances the ratio of straight-to-branched molecule production. Other types of molecule may be less abundant, but show an even greater degree of branching. The predicted abundance of, in particular, s-C4H9CN, which at its peak is comparable to that of propyl cyanide, makes it a good candidate for future detection toward Sgr B2(N2).

  12. Landscape distribution of food and nesting sites affect larval diet and nest size, but not abundance of Osmia bicornis.

    PubMed

    Coudrain, Valérie; Rittiner, Sarah; Herzog, Felix; Tinner, Willy; Entling, Martin H

    2016-10-01

    Habitat fragmentation is a major threat for beneficial organisms and the ecosystem services they provide. Multiple-habitat users such as wild bees depend on both nesting and foraging habitat. Thus, they may be affected by the fragmentation of at least two habitat types. We investigated the effects of landscape-scale amount of and patch isolation from both nesting habitat (woody plants) and foraging habitat (specific pollen sources) on the abundance and diet of Osmia bicornis L. Trap-nests of O. bicornis were studied in 30 agricultural landscapes of the Swiss Plateau. Nesting and foraging habitats were mapped in a radius of 500 m around the sites. Pollen composition of larval diet changed as isolation to the main pollen source, Ranunculus, increased, suggesting that O. bicornis adapted its foraging strategy in function of the nest proximity to main pollen sources. Abundance of O. bicornis was neither related to isolation or amount of nesting habitat nor to isolation or abundance of food plants. Surprisingly, nests of O. bicornis contained fewer larvae in sites at forest edge compared to isolated sites, possibly due to higher parasitism risk. This study indicates that O. bicornis can nest in a variety of situations by compensating scarcity of its main larval food by exploiting alternative food sources. © 2015 Institute of Zoology, Chinese Academy of Sciences.

  13. Solar flare particles - Energy-dependent composition and relationship to solar composition

    NASA Technical Reports Server (NTRS)

    Crawford, H. J.; Price, P. B.; Cartwright, B. G.; Sullivan, J. D.

    1975-01-01

    Plastic and glass track detectors on rockets and Apollo spacecraft have been used to determine the composition of particles from He to Ni at energies from 0.1 to 50 MeV per nucleon in several solar flares of widely varying intensities. At low energies the composition of solar particles is enriched in heavy elements by an amount, relative to the asymptotic high-energy composition, that increases with atomic number from Z = 2 up to at least Z = 50, that decreases with energy, and that varies from flare to flare. At high energies (usually beyond an energy of 5 to 20 MeV per nucleon) the composition becomes independent of energy and, though somewhat variable from flare to flare, approximates the composition of the solar atmosphere. A table of abundances of the even-Z elements from He to Ni (plus N) in solar particles is constructed by averaging the asymptotic high-energy abundances in several flares.

  14. On global energy scenario, dye-sensitized solar cells and the promise of nanotechnology.

    PubMed

    Reddy, K Govardhan; Deepak, T G; Anjusree, G S; Thomas, Sara; Vadukumpully, Sajini; Subramanian, K R V; Nair, Shantikumar V; Nair, A Sreekumaran

    2014-04-21

    One of the major problems that humanity has to face in the next 50 years is the energy crisis. The rising population, rapidly changing life styles of people, heavy industrialization and changing landscape of cities have increased energy demands, enormously. The present annual worldwide electricity consumption is 12 TW and is expected to become 24 TW by 2050, leaving a challenging deficit of 12 TW. The present energy scenario of using fossil fuels to meet the energy demand is unable to meet the increase in demand effectively, as these fossil fuel resources are non-renewable and limited. Also, they cause significant environmental hazards, like global warming and the associated climatic issues. Hence, there is an urgent necessity to adopt renewable sources of energy, which are eco-friendly and not extinguishable. Of the various renewable sources available, such as wind, tidal, geothermal, biomass, solar, etc., solar serves as the most dependable option. Solar energy is freely and abundantly available. Once installed, the maintenance cost is very low. It is eco-friendly, safely fitting into our society without any disturbance. Producing electricity from the Sun requires the installation of solar panels, which incurs a huge initial cost and requires large areas of lands for installation. This is where nanotechnology comes into the picture and serves the purpose of increasing the efficiency to higher levels, thus bringing down the overall cost for energy production. Also, emerging low-cost solar cell technologies, e.g. thin film technologies and dye-sensitized solar cells (DSCs) help to replace the use of silicon, which is expensive. Again, nanotechnological implications can be applied in these solar cells, to achieve higher efficiencies. This paper vividly deals with the various available solar cells, choosing DSCs as the most appropriate ones. The nanotechnological implications which help to improve their performance are dealt with, in detail. Additionally, the economic and ecological aspects of using nanotechnology are briefly introduced.

  15. Resolution of carbon metabolism and sulfur-oxidation pathways of Metallosphaera cuprina Ar-4 via comparative proteomics.

    PubMed

    Jiang, Cheng-Ying; Liu, Li-Jun; Guo, Xu; You, Xiao-Yan; Liu, Shuang-Jiang; Poetsch, Ansgar

    2014-09-23

    Metallosphaera cuprina is able to grow either heterotrophically on organics or autotrophically on CO2 with reduced sulfur compounds as electron donor. These traits endowed the species desirable for application in biomining. In order to obtain a global overview of physiological adaptations on the proteome level, proteomes of cytoplasmic and membrane fractions from cells grown autotrophically on CO2 plus sulfur or heterotrophically on yeast extract were compared. 169 proteins were found to change their abundance depending on growth condition. The proteins with increased abundance under autotrophic growth displayed candidate enzymes/proteins of M. cuprina for fixing CO2 through the previously identified 3-hydroxypropionate/4-hydroxybutyrate cycle and for oxidizing elemental sulfur as energy source. The main enzymes/proteins involved in semi- and non-phosphorylating Entner-Doudoroff (ED) pathway and TCA cycle were less abundant under autotrophic growth. Also some transporter proteins and proteins of amino acid metabolism changed their abundances, suggesting pivotal roles for growth under the respective conditions. The described work is of great significance: For general microbiology: How do extremophile organisms use their unique metabolic capabilities in adapting to autotrophic and hetetrotrophic growth conditions? Which are important enzymes involved in the metabolic adaptation and which enzyme candidate should be investigated in more detail with microbiological/biochemical approaches? For applied microbiology: Which are the key enzymes and reaction pathways for sulfur oxidation and autotrophic growth? This knowledge should accelerate future design of improved bioleaching processes in biomining industries or bioremediation. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Intrinsic backgrounds from Rn and Kr in the XENON100 experiment

    NASA Astrophysics Data System (ADS)

    Aprile, E.; Aalbers, J.; Agostini, F.; Alfonsi, M.; Amaro, F. D.; Anthony, M.; Arneodo, F.; Barrow, P.; Baudis, L.; Bauermeister, B.; Benabderrahmane, M. L.; Berger, T.; Breur, P. A.; Brown, A.; Brown, E.; Bruenner, S.; Bruno, G.; Budnik, R.; Bütikofer, L.; Calvén, J.; Cardoso, J. M. R.; Cervantes, M.; Cichon, D.; Coderre, D.; Colijn, A. P.; Conrad, J.; Cussonneau, J. P.; Decowski, M. P.; de Perio, P.; Di Gangi, P.; Di Giovanni, A.; Diglio, S.; Eurin, G.; Fei, J.; Ferella, A. D.; Fieguth, A.; Fulgione, W.; Gallo Rosso, A.; Galloway, M.; Gao, F.; Garbini, M.; Geis, C.; Goetzke, L. W.; Greene, Z.; Grignon, C.; Hasterok, C.; Hogenbirk, E.; Itay, R.; Kaminsky, B.; Kazama, S.; Kessler, G.; Kish, A.; Landsman, H.; Lang, R. F.; Lellouch, D.; Levinson, L.; Lin, Q.; Lindemann, S.; Lindner, M.; Lombardi, F.; Lopes, J. A. M.; Manfredini, A.; Maris, I.; Marrodán Undagoitia, T.; Masbou, J.; Massoli, F. V.; Masson, D.; Mayani, D.; Messina, M.; Micheneau, K.; Molinario, A.; Morå, K.; Murra, M.; Naganoma, J.; Ni, K.; Oberlack, U.; Pakarha, P.; Pelssers, B.; Persiani, R.; Piastra, F.; Pienaar, J.; Piro, M.-C.; Pizzella, V.; Plante, G.; Priel, N.; Ramírez García, D.; Rauch, L.; Reichard, S.; Reuter, C.; Rizzo, A.; Rupp, N.; dos Santos, J. M. F.; Sartorelli, G.; Scheibelhut, M.; Schindler, S.; Schreiner, J.; Schumann, M.; Lavina, L. Scotto; Selvi, M.; Shagin, P.; Silva, M.; Simgen, H.; Sivers, M. Von; Stein, A.; Thers, D.; Tiseni, A.; Trinchero, G.; Tunnell, C.; Vargas, M.; Wang, H.; Wang, Z.; Weber, M.; Wei, Y.; Weinheimer, C.; Wittweg, C.; Wulf, J.; Ye, J.; Zhang, Y.

    2018-02-01

    In this paper, we describe the XENON100 data analyses used to assess the target-intrinsic background sources radon (?), thoron (?) and krypton (?). We detail the event selections of high-energy alpha particles and decay-specific delayed coincidences. We derive distributions of the individual radionuclides inside the detector and quantify their abundances during the main three science runs of the experiment over a period of ˜ 4 years, from January 2010 to January 2014. We compare our results to external measurements of radon emanation and krypton concentrations where we find good agreement. We report an observed reduction in concentrations of radon daughters that we attribute to the plating-out of charged ions on the negatively biased cathode.

  17. A new component of cosmic rays of unknown origin at a few MeV per nucleon

    NASA Technical Reports Server (NTRS)

    Gloecker, G.

    1974-01-01

    Recently discovered anomalies in the abundances and energy spectra of quiet time, extraterrestrial hydrogen, helium, carbon, nitrogen, and oxygen require serious revisions of origin theories to account for this new component of cosmic radiation. Abnormally large O/C and N/C ratios, long term intensity variations with time, and radial gradient measurements indicate a non-solar origin for these 2 to 30 MeV/nucleon particles. Ideas suggested to explain these measurements range from acceleration of galactic source material having an unusual composition to local acceleration of particles within the solar cavity. Observations are at present insufficient to choose between these alternate origin models.

  18. Microbial Biomarkers for Native and Agricultural Soil Inputs to Atmospheric Particulate Matter

    NASA Astrophysics Data System (ADS)

    Fulton, J. M.; Herckes, P.; Fraser, M. P.; Collins, J.; Van Mooy, B. A.

    2017-12-01

    Intense dust storms (haboobs) erode desert soils and cause dramatic short-term increases in particulate matter (PM) concentration in the atmosphere. Background atmospheric PM levels in the southwestern United States also commonly exceed the National Ambient Air Quality Standards, so episodic haboobs and normal weather patterns both contribute to aeolian transport. We analyzed fine (PM2.5) and coarse (PM>2.5) dust fractions sampled in Tempe, Arizona for molecular biomarkers indicative of dust sourced from either native or agricultural soils. We focused on pigments and intact polar lipids (IPLs) that were also in soil crusts collected in the region. The PM samples were taken during two weeks (23 July to 5 August 2014) that included two haboobs during the first week and mostly calm weather with minor rainfall during the second week. We detected scytonemin, a diagnostic pigment biomarker for cyanobacteria, in all PM>2.5 samples, but its concentration was highest in haboob dust. Similarly, scytonemin was only abundant in PM2.5 samples taken during haboobs. Scytonemin is an important component of native biological soil crusts, protecting the crust community from UV radiation, and is ca. two orders of magnitude less abundant in disturbed agricultural soils. In biological soil crusts, scytonemin is associated with extracellular polysaccharides that are produced by cyanobacteria and bind soil into cohesive crusts. The association between scytonemin and haboobs suggests that native soil erosion is facilitated by high energy, episodic events that overcome crust cohesion. IPLs were abundant in agricultural soil crusts and included phosphatidylethanolamine from soil bacteria and a glucosylceramide from fungi. These compounds had similar concentration in haboob and background dust, suggesting agricultural or otherwise disturbed soils contribute more to ambient dust. In this study, we employed a new high resolution mass spectrometric method that produces molecular formulas and structural information, even at very low abundance. Employing this analysis on atmospheric PM improves our understanding of mechanisms by which soil crust biomarkers are transferred to lake and ocean sediments and can also contribute to source apportionment models for describing atmospheric dust contamination.

  19. Metagenomic Analysis of Hot Springs in Central India Reveals Hydrocarbon Degrading Thermophiles and Pathways Essential for Survival in Extreme Environments

    PubMed Central

    Saxena, Rituja; Dhakan, Darshan B.; Mittal, Parul; Waiker, Prashant; Chowdhury, Anirban; Ghatak, Arundhuti; Sharma, Vineet K.

    2017-01-01

    Extreme ecosystems such as hot springs are of great interest as a source of novel extremophilic species, enzymes, metabolic functions for survival and biotechnological products. India harbors hundreds of hot springs, the majority of which are not yet explored and require comprehensive studies to unravel their unknown and untapped phylogenetic and functional diversity. The aim of this study was to perform a large-scale metagenomic analysis of three major hot springs located in central India namely, Badi Anhoni, Chhoti Anhoni, and Tattapani at two geographically distinct regions (Anhoni and Tattapani), to uncover the resident microbial community and their metabolic traits. Samples were collected from seven distinct sites of the three hot spring locations with temperature ranging from 43.5 to 98°C. The 16S rRNA gene amplicon sequencing of V3 hypervariable region and shotgun metagenome sequencing uncovered a unique taxonomic and metabolic diversity of the resident thermophilic microbial community in these hot springs. Genes associated with hydrocarbon degradation pathways, such as benzoate, xylene, toluene, and benzene were observed to be abundant in the Anhoni hot springs (43.5–55°C), dominated by Pseudomonas stutzeri and Acidovorax sp., suggesting the presence of chemoorganotrophic thermophilic community with the ability to utilize complex hydrocarbons as a source of energy. A high abundance of genes belonging to methane metabolism pathway was observed at Chhoti Anhoni hot spring, where methane is reported to constitute >80% of all the emitted gases, which was marked by the high abundance of Methylococcus capsulatus. The Tattapani hot spring, with a high-temperature range (61.5–98°C), displayed a lower microbial diversity and was primarily dominated by a nitrate-reducing archaeal species Pyrobaculum aerophilum. A higher abundance of cell metabolism pathways essential for the microbial survival in extreme conditions was observed at Tattapani. Taken together, the results of this study reveal a novel consortium of microbes, genes, and pathways associated with the hot spring environment. PMID:28105025

  20. IR-MALDESI MASS SPECTROMETRY IMAGING OF BIOLOGICAL TISSUE SECTIONS USING ICE AS A MATRIX

    PubMed Central

    Robichaud, Guillaume; Barry, Jeremy A.; Muddiman, David C.

    2014-01-01

    Infrared Matrix-Assisted Laser Desorption Electrospray Ionization (IR-MALDESI) Mass Spectrometry imaging of biological tissue sections using a layer of deposited ice as an energy absorbing matrix was investigated. Dynamics of plume ablation were first explored using a nanosecond exposure shadowgraphy system designed to simultaneously collect pictures of the plume with a camera and collect the FT-ICR mass spectrum corresponding to that same ablation event. Ablation of fresh tissue analyzed with and without using ice as a matrix were both compared using this technique. Effect of spot-to-spot distance, number of laser shots per pixel and tissue condition (matrix) on ion abundance was also investigated for 50 µm thick tissue sections. Finally, the statistical method called design of experiments was used to compare source parameters and determine the optimal conditions for IR-MALDESI of tissue sections using deposited ice as a matrix. With a better understanding of the fundamentals of ablation dynamics and a systematic approach to explore the experimental space, it was possible to improve ion abundance by nearly one order of magnitude. PMID:24385399

  1. Iron K Lines from Gamma Ray Bursts

    NASA Technical Reports Server (NTRS)

    Kallman, T. R.; Meszaros, P.; Rees, M. J.

    2003-01-01

    We present models for reprocessing of an intense flux of X-rays and gamma rays expected in the vicinity of gamma ray burst sources. We consider the transfer and reprocessing of the energetic photons into observable features in the X-ray band, notably the K lines of iron. Our models are based on the assumption that the gas is sufficiently dense to allow the microphysical processes to be in a steady state, thus allowing efficient line emission with modest reprocessing mass and elemental abundances ranging from solar to moderately enriched. We show that the reprocessing is enhanced by down-Comptonization of photons whose energy would otherwise be too high to absorb on iron, and that pair production can have an effect on enhancing the line production. Both "distant" reprocessors such as supernova or wind remnants and "nearby" reprocessors such as outer stellar envelopes can reproduce the observed line fluxes with Fe abundances 30-100 times above solar, depending on the incidence angle. The high incidence angles required arise naturally only in nearby models, which for plausible values can reach Fe line to continuum ratios close to the reported values.

  2. Magnesium in Disease Prevention and Overall Health12

    PubMed Central

    Volpe, Stella Lucia

    2013-01-01

    Magnesium is the fourth most abundant mineral and the second most abundant intracellular divalent cation and has been recognized as a cofactor for >300 metabolic reactions in the body. Some of the processes in which magnesium is a cofactor include, but are not limited to, protein synthesis, cellular energy production and storage, reproduction, DNA and RNA synthesis, and stabilizing mitochondrial membranes. Magnesium also plays a critical role in nerve transmission, cardiac excitability, neuromuscular conduction, muscular contraction, vasomotor tone, blood pressure, and glucose and insulin metabolism. Because of magnesium’s many functions within the body, it plays a major role in disease prevention and overall health. Low levels of magnesium have been associated with a number of chronic diseases including migraine headaches, Alzheimer’s disease, cerebrovascular accident (stroke), hypertension, cardiovascular disease, and type 2 diabetes mellitus. Good food sources of magnesium include unrefined (whole) grains, spinach, nuts, legumes, and white potatoes (tubers). This review presents recent research in the areas of magnesium and chronic disease, with the goal of emphasizing magnesium’s role in disease prevention and overall health. PMID:23674807

  3. Effects of Nitrogen Load on the Function and Diversity of Methanotrophs in the Littoral Wetland of a Boreal Lake

    PubMed Central

    Siljanen, Henri M. P.; Saari, Anne; Bodrossy, Levente; Martikainen, Pertti J.

    2012-01-01

    Methane is the second most abundant greenhouse gas in the atmosphere. A major part of the total methane emissions from lake ecosystems is emitted from littoral wetlands. Methane emissions are significantly reduced by methanotrophs, as they use methane as their sole energy and carbon source. Methanotrophic activity can be either activated or inhibited by nitrogen. However, the effects of nitrogen on methanotrophs in littoral wetlands are unknown. Here we report how nitrogen loading in situ affected the function and diversity of methanotrophs in a boreal littoral wetland. Methanotrophic community composition and functional diversity were analyzed with a particulate methane monooxygenase (pmoA) gene targeted microarray. Nitrogen load had no effects on methane oxidation potential and methane fluxes. Nitrogen load activated pmoA gene transcription of type I (Methylobacter, Methylomonas, and LW21-freshwater phylotypes) methanotrophs, but decreased the relative abundance of type II (Methylocystis, Methylosinus trichosporium, and Methylosinus phylotypes) methanotrophs. Hence, the overall activity of a methanotroph community in littoral wetlands is not affected by nitrogen leached from the catchment area. PMID:22363324

  4. Can ipids in lake sediments help to reconstruct changes in methane availability and methane fluxes in boreal and temperate lakes?

    NASA Astrophysics Data System (ADS)

    Stoetter, T.; van Hardenbroek, M.; Rinta, P.; Schilder, J.; Schubert, C. J.; Heiri, O.

    2013-12-01

    Methane (CH4) is a major greenhouse gas and lakes are an important but poorly studied source of CH4 to the atmosphere. Lipid analysis was used before to identify and quantify CH4 oxidizing bacteria (MOB), giving insight into CH4 oxidation and production in lakes. However, few studies are available that examine how closely the distribution and the carbon isotopic signature (δ13C) of lipids are related to CH4 concentrations and fluxes in different lake ecosystems. In a multi-lake survey we quantified the relationship between lipids, mainly fatty acids (FAs), and CH4 concentrations or fluxes, with the aim of assessing whether FA analysis of lake sediment samples can provide information on past CH4 abundance and production in lakes. The study sites include small lakes in Sweden, Finland, the Netherlands, and Switzerland. Surface sediments collected in the deepest point of the lakes were examined using gas chromatography with flame ionization for determining FA concentrations, gas chromatography mass spectrometry (GC-MS) for identification of individual FAs, and isotope ratio mass spectrometry (IRMS) for determining compound specific δ13C values. Since CH4 is significantly more depleted in 13C than other carbon sources, δ13C is a good tracer for CH4 related processes. The analysis of the acid fraction in the sediments showed that mainly three FAs, identified as C16:1ω7, C16:1ω5 and C18:1ω7, were more depleted in 13C than the others, suggesting that they may originate from MOB. Comparison with literature sources indicated that these FAs are produced by MOB, however, not exclusively. The relative abundance of these depleted FAs showed clear relations to CH4 parameters. For example, increasing abundances were observed with increasing CH4 concentrations in the sediment or with increasing CH4 flux measured at the lake surface. An explanation for these relations would be an increase in MOB biomass with increasing CH4 availability, as they use CH4 as energy and carbon source, which would lead to increasing abundances of MOB produced FAs in the sediment. The presence or absence of oxygen above the sediments seems to have a strong effect on these relationships. In lakes with oxic bottom water, the abundance of depleted FAs shows a stronger rise with increasing CH4 concentrations than in lakes with anoxic bottom waters, suggesting that aerobic CH4 oxidizers are an important source of these depleted FAs. With increasing CH4 concentrations, for example just above the sediment, we find more depleted values in C16:1ω7 and C18:1ω7. This correlation is only strong if we exclude lakes with a strong terrestrial influence. Our preliminary analysis of FAs in surface sediment samples showed clear relations to CH4 parameters measured in the examined lake ecosystems suggesting that it may be possible to use FA analysis of lake sediment records as a proxy for CH4 availability in lakes. However, our results also show that oxygen conditions at the sediment-water interface and organic matter imported from the lake catchment can have a strong effect.

  5. Discovery of interstellar ketenyl (HCCO), a surprisingly abundant radical

    NASA Astrophysics Data System (ADS)

    Agúndez, Marcelino; Cernicharo, José; Guélin, Michel

    2015-05-01

    We conducted radioastronomical observations of 9 dark clouds with the IRAM 30 m telescope. We present the first identification in space of the ketenyl radical (HCCO) toward the starless core Lupus-1A and the molecular cloud L483 and the detection of the related molecules ketene (H2CCO) and acetaldehyde (CH3CHO) in these two sources and 3 additional dark clouds. We also report the detection of the formyl radical (HCO) in the 9 targeted sources and of propylene (CH2CHCH3) in 4 of the observed sources, which significantly extends the number of dark clouds where these molecules are known to be present. We have derived a beam-averaged column density of HCCO of ~5 × 1011 cm-2 in both Lupus-1A and L483, which means that the ketenyl radical is just ~10 times less abundant than ketene in these sources. The non-negligible abundance of HCCO found implies that there must be a powerful formation mechanism able to counterbalance the efficient destruction of this radical through reactions with neutral atoms. The column densities derived for HCO, (0.5-2.7) ×1012 cm-2, and CH2CHCH3, (1.9-4-2) ×1013 cm-2, are remarkably uniform across the sources where these species are detected, confirming their ubiquity in dark clouds. Gas phase chemical models of cold dark clouds can reproduce the observed abundances of HCO, but cannot explain the presence of HCCO in Lupus-1A and L483 and the high abundances derived for propylene. The chemistry of cold dark clouds needs to be revised in light of these new observational results. Based on observations carried out with the IRAM 30 m Telescope. IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain).Tables 3-6 are available in electronic form at http://www.aanda.org

  6. Potentially Habitable Ancient Environments in Gusev Crater, Mars

    NASA Technical Reports Server (NTRS)

    DesMarais, David J.

    2010-01-01

    Habitable environments must sustain liquid water at least intermittently and also provide both chemical building blocks and useful sources of energy for life. Observations by Spirit rover indicate that conditions have probably been too dry to sustain life, at least since the emplacement of the extensive basalts that underlie the plains around the Columbia Memorial Station landing site. Local evidence of relatively minor aqueous alteration [1] probably occurred under conditions where the activity of water was too low to sustain biological processes as we know them. In contrast, multiple bedrock units in West Spur and Husband Hill in the Columbia Hills have been extensively altered. Patterns of elemental abundances are consistent with aqueous processes involving migrating fluids [2]. Fe in several of these units has been extensively oxidized [3]. Conceivably any microbiota present during the aqueous alteration of these rocks might have obtained energy from Fe oxidation. Spirit discovered olivine-rich ultramafic rocks during her descent from Husband Hill southward into Inner Basin. Alteration of similar ultramafic rocks on Earth can yield H2 that can provide both energy and reducing power for microorganisms. Spirit's discovery of deposits rich in ferric sulfate is consistent with the aqueous dissolution and/or alteration of olivine under acidic conditions [2] such as those associated with hydrothermal activity. The oxidation of iron and sulfur that can accompany such activity can be an energy source for life. Hydrothermal systems on Earth that sustain either acidic [4] or neutral to alkaline fluids [5] have been shown to provide this energy. Collectively the observations by Spirit rover are consistent with the possibility that habitable environments existed in Gusev crater at least intermittently in the distant geologic past.

  7. Numerical Approach to Wood Pyrolysis in Considerating Heat Transfer in Reactor Chamber

    NASA Astrophysics Data System (ADS)

    Idris, M.; Novalia, U.

    2017-03-01

    Pyrolysis is the decomposition process of solid biomass into gas, tar and charcoal through thermochemical methods. The composition of biomass consists of cellulose hemi cellulose and lignin, which each will decompose at different temperatures. Currently pyrolysis has again become an important topic to be discussed. Many researchers make and install the pyrolysis reactor to convert biomass waste into clean energy hardware that can be used to help supply energy that has a crisis. Additionally the clean energy derived from biomass waste is a renewable energy, in addition to abundant source also reduce exhaust emissions of fossil energy that causes global warming. Pyrolysis is a method that has long been known by humans, but until now little is known about the phenomenon of the pyrolysis process that occurs in the reactor. One of the Pyrolysis’s phenomena is the heat transfer process from the temperature of the heat source in the reactor and heat the solid waste of biomass. The solid waste of biomass question in this research is rubber wood obtained from one of the company’s home furnishings. Therefore, this study aimed to describe the process of heat transfer in the reactor during the process. ANSYS software was prepared to make the simulation of heat transfer phenomena at the pyrolysis reactor. That’s the numerical calculation carried out for 1200 seconds. Comparison of temperature performed at T1, T2 and T3 to ensure that thermal conductivity is calculated by numerical accordance with experimental data. The distribution of temperature in the reactor chamber specifies the picture that excellent heat conduction effect of the wood near or attached to wooden components, cellulose, hemicellulose and lignin down into gas.

  8. ROLE OF THE CORONAL ALFVÉN SPEED IN MODULATING THE SOLAR-WIND HELIUM ABUNDANCE

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wang, Y.-M., E-mail: yi.wang@nrl.navy.mil

    The helium abundance He/H in the solar wind is relatively constant at ∼0.04 in high-speed streams, but varies in phase with the sunspot number in slow wind, from ∼0.01 at solar minimum to ∼0.04 at maximum. Suggested mechanisms for helium fractionation have included frictional coupling to protons and resonant interactions with high-frequency Alfvénic fluctuations. We compare He/H measurements during 1995–2015 with coronal parameters derived from source-surface extrapolations of photospheric field maps. We find that the near-Earth helium abundance is an increasing function of the magnetic field strength and Alfvén speed v {sub A} in the outer corona, while being onlymore » weakly correlated with the proton flux density. Throughout the solar cycle, fast wind is associated with short-term increases in v {sub A} near the source surface; resonance with Alfvén waves, with v {sub A} and the relative speed of α -particles and protons decreasing with increasing heliocentric distance, may then lead to enhanced He/H at 1 au. The modulation of helium in slow wind reflects the tendency for the associated coronal Alfvén speeds to rise steeply from sunspot minimum, when this wind is concentrated around the source-surface neutral line, to sunspot maximum, when the source-surface field attains its peak strengths. The helium abundance near the source surface may represent a balance between collisional decoupling from protons and Alfvén wave acceleration.« less

  9. History of the solar-type protostar IRAS 16293-2422 as told by the cyanopolyynes

    NASA Astrophysics Data System (ADS)

    Jaber Al-Edhari, A.; Ceccarelli, C.; Kahane, C.; Viti, S.; Balucani, N.; Caux, E.; Faure, A.; Lefloch, B.; Lique, F.; Mendoza, E.; Quenard, D.; Wiesenfeld, L.

    2017-01-01

    Context. Cyanopolyynes are chains of carbon atoms with an atom of hydrogen and a CN group on either side. They are detected almost everywhere in the interstellar medium (ISM), as well as in comets. In the past, they have been used to constrain the age of some molecular clouds, since their abundance is predicted to be a strong function of time. Finally, cyanopolyynes can potentially contain a large portion of molecular carbon. Aims: We present an extensive study of the cyanopolyynes distribution in the solar-type protostar IRAS 16293-2422. The goals are (I) to obtain a census of the cyanopolyynes in this source and of their isotopologues; (II) to derive how their abundance varies across the protostar envelope; and (III) to obtain constraints on the history of IRAS 16293-2422 by comparing the observations with the predictions of a chemical model. Methods: We analysed the data from the IRAM-30 m unbiased millimeter and submillimeter spectral survey towards IRAS 16293-2422 named TIMASSS. The derived spectral line energy distribution (SLED) of each detected cyanopolyyne was compared with the predictions from the radiative transfer code GRenoble Analysis of Protostellar Envelope Spectra (GRAPES) to derive the cyanopolyyne abundances across the envelope of IRAS 16293-2422. Finally, the derived abundances were compared with the predictions of the chemical model UCL_CHEM. Results: We detect several lines from cyanoacetylene (HC3N) and cyanodiacetylene (HC5N), and report the first detection of deuterated cyanoacetylene, DC3N, in a solar-type protostar. We found that the HC3N abundance is roughly constant ( 1.3 × 10-11) in the outer cold envelope of IRAS 16293-2422, and it increases by about a factor 100 in the inner region where the dust temperature exceeds 80 K, namely when the volcano ice desorption is predicted to occur. The HC5N has an abundance similar to HC3N in the outer envelope and about a factor of ten lower in the inner region. The comparison with the chemical model predictions provides constraints on the oxygen and carbon gaseous abundance in the outer envelope and, most importantly, on the age of the source. The HC3N abundance derived in the inner region, and where the increase occurs, also provide strong constraints on the time taken for the dust to warm up to 80 K, which has to be shorter than 103-104 yr. Finally, the cyanoacetylene deuteration is about 50% in the outer envelope and ≤5% in the warm inner region. The relatively low deuteration in the warm region suggests that we are witnessing a fossil of the HC3N abundantly formed in the tenuous phase of the pre-collapse and then frozen into the grain mantles at a later phase. Conclusions: The accurate analysis of the cyanopolyynes in IRAS 16293-2422 unveils an important part of its past story. It tells us that IRAS 16293-2422 underwent a relatively fast (≤105 yr) collapse and a very fast (≤103-104 yr) warming up of the cold material to 80 K.

  10. X-ray reflection from cold white dwarfs in magnetic cataclysmic variables

    NASA Astrophysics Data System (ADS)

    Hayashi, Takayuki; Kitaguchi, Takao; Ishida, Manabu

    2018-02-01

    We model X-ray reflection from white dwarfs (WDs) in magnetic cataclysmic variables (mCVs) using a Monte Carlo simulation. A point source with a power-law spectrum or a realistic post-shock accretion column (PSAC) source irradiates a cool and spherical WD. The PSAC source emits thermal spectra of various temperatures stratified along the column according to the PSAC model. In the point-source simulation, we confirm the following: a source harder and nearer to the WD enhances the reflection; higher iron abundance enhances the equivalent widths (EWs) of fluorescent iron Kα1, 2 lines and their Compton shoulder, and increases the cut-off energy of a Compton hump; significant reflection appears from an area that is more than 90° apart from the position right under the point X-ray source because of the WD curvature. The PSAC simulation reveals the following: a more massive WD basically enhances the intensities of the fluorescent iron Kα1, 2 lines and the Compton hump, except for some specific accretion rate, because the more massive WD makes a hotter PSAC from which higher-energy X-rays are preferentially emitted; a larger specific accretion rate monotonically enhances the reflection because it makes a hotter and shorter PSAC; the intrinsic thermal component hardens by occultation of the cool base of the PSAC by the WD. We quantitatively estimate the influences of the parameters on the EWs and the Compton hump with both types of source. We also calculate X-ray modulation profiles brought about by the WD spin. These depend on the angles of the spin axis from the line of sight and from the PSAC, and on whether the two PSACs can be seen. The reflection spectral model and the modulation model involve the fluorescent lines and the Compton hump and can directly be compared to the data, which allows us to estimate these geometrical parameters with unprecedented accuracy.

  11. Lake Bacterial Assemblage Composition Is Sensitive to Biological Disturbance Caused by an Invasive Filter Feeder

    PubMed Central

    Carrick, Hunter J.; Cavaletto, Joann; Chiang, Edna; Johengen, Thomas H.; Vanderploeg, Henry A.

    2017-01-01

    ABSTRACT One approach to improve forecasts of how global change will affect ecosystem processes is to better understand how anthropogenic disturbances alter bacterial assemblages that drive biogeochemical cycles. Species invasions are important contributors to global change, but their impacts on bacterial community ecology are rarely investigated. Here, we studied direct impacts of invasive dreissenid mussels (IDMs), one of many invasive filter feeders, on freshwater lake bacterioplankton. We demonstrated that direct effects of IDMs reduced bacterial abundance and altered assemblage composition by preferentially removing larger and particle-associated bacteria. While this increased the relative abundances of many free-living bacterial taxa, some were susceptible to filter feeding, in line with efficient removal of phytoplankton cells of <2 μm. This selective removal of particle-associated and larger bacteria by IDMs altered inferred bacterial functional group representation, defined by carbon and energy source utilization. Specifically, we inferred an increased relative abundance of chemoorganoheterotrophs predicted to be capable of rhodopsin-dependent energy generation. In contrast to the few previous studies that have focused on the longer-term combined direct and indirect effects of IDMs on bacterioplankton, our study showed that IDMs act directly as a biological disturbance to which freshwater bacterial assemblages are sensitive. The negative impacts on particle-associated bacteria, which have been shown to be more active than free-living bacteria, and the inferred shifts in functional group representation raise the possibility that IDMs may directly alter bacterially mediated ecosystem functions. IMPORTANCE Freshwater bacteria play fundamental roles in global elemental cycling and are an intrinsic part of local food webs. Human activities are altering freshwater environments, and much has been learned regarding the sensitivity of bacterial assemblages to a variety of these disturbances. Yet, relatively few studies have focused on how species invasion, which is one of the most important aspects of anthropogenic global change, affects freshwater bacterial assemblages. This study focuses on the impact of invasive dreissenid mussels (IDMs), a globally distributed group of invasive species with large impacts on freshwater phyto- and zooplankton assemblages. We show that IDMs have direct effects on lake bacterioplankton abundance, taxonomic composition, and inferred bacterial functional group representation. PMID:28593195

  12. Lake Bacterial Assemblage Composition Is Sensitive to Biological Disturbance Caused by an Invasive Filter Feeder.

    PubMed

    Denef, Vincent J; Carrick, Hunter J; Cavaletto, Joann; Chiang, Edna; Johengen, Thomas H; Vanderploeg, Henry A

    2017-01-01

    One approach to improve forecasts of how global change will affect ecosystem processes is to better understand how anthropogenic disturbances alter bacterial assemblages that drive biogeochemical cycles. Species invasions are important contributors to global change, but their impacts on bacterial community ecology are rarely investigated. Here, we studied direct impacts of invasive dreissenid mussels (IDMs), one of many invasive filter feeders, on freshwater lake bacterioplankton. We demonstrated that direct effects of IDMs reduced bacterial abundance and altered assemblage composition by preferentially removing larger and particle-associated bacteria. While this increased the relative abundances of many free-living bacterial taxa, some were susceptible to filter feeding, in line with efficient removal of phytoplankton cells of <2 μm. This selective removal of particle-associated and larger bacteria by IDMs altered inferred bacterial functional group representation, defined by carbon and energy source utilization. Specifically, we inferred an increased relative abundance of chemoorganoheterotrophs predicted to be capable of rhodopsin-dependent energy generation. In contrast to the few previous studies that have focused on the longer-term combined direct and indirect effects of IDMs on bacterioplankton, our study showed that IDMs act directly as a biological disturbance to which freshwater bacterial assemblages are sensitive. The negative impacts on particle-associated bacteria, which have been shown to be more active than free-living bacteria, and the inferred shifts in functional group representation raise the possibility that IDMs may directly alter bacterially mediated ecosystem functions. IMPORTANCE Freshwater bacteria play fundamental roles in global elemental cycling and are an intrinsic part of local food webs. Human activities are altering freshwater environments, and much has been learned regarding the sensitivity of bacterial assemblages to a variety of these disturbances. Yet, relatively few studies have focused on how species invasion, which is one of the most important aspects of anthropogenic global change, affects freshwater bacterial assemblages. This study focuses on the impact of invasive dreissenid mussels (IDMs), a globally distributed group of invasive species with large impacts on freshwater phyto- and zooplankton assemblages. We show that IDMs have direct effects on lake bacterioplankton abundance, taxonomic composition, and inferred bacterial functional group representation.

  13. Lake Bacterial Assemblage Composition Is Sensitive to Biological Disturbance Caused by an Invasive Filter Feeder

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Denef, Vincent J.; Carrick, Hunter J.; Cavaletto, Joann

    One approach to improve forecasts of how global change will affect ecosystem processes is to better understand how anthropogenic disturbances alter bacterial assemblages that drive biogeochemical cycles. Species invasions are important contributors to global change, but their impacts on bacterial community ecology are rarely investigated. Here, we studied direct impacts of invasive dreissenid mussels (IDMs), one of many invasive filter feeders, on freshwater lake bacterioplankton. We demonstrated that direct effects of IDMs reduced bacterial abundance and altered assemblage composition by preferentially removing larger and particle-associated bacteria. While this increased the relative abundances of many free-living bacterial taxa, some were susceptiblemore » to filter feeding, in line with efficient removal of phytoplankton cells of <2 μm. This selective removal of particle-associated and larger bacteria by IDMs altered inferred bacterial functional group representation, defined by carbon and energy source utilization. Specifically, we inferred an increased relative abundance of chemoorganoheterotrophs predicted to be capable of rhodopsin-dependent energy generation. In contrast to the few previous studies that have focused on the longer-term combined direct and indirect effects of IDMs on bacterioplankton, our study showed that IDMs act directly as a biological disturbance to which freshwater bacterial assemblages are sensitive. The negative impacts on particle-associated bacteria, which have been shown to be more active than free-living bacteria, and the inferred shifts in functional group representation raise the possibility that IDMs may directly alter bacterially mediated ecosystem functions.Freshwater bacteria play fundamental roles in global elemental cycling and are an intrinsic part of local food webs. Human activities are altering freshwater environments, and much has been learned regarding the sensitivity of bacterial assemblages to a variety of these disturbances. Yet, relatively few studies have focused on how species invasion, which is one of the most important aspects of anthropogenic global change, affects freshwater bacterial assemblages. This study focuses on the impact of invasive dreissenid mussels (IDMs), a globally distributed group of invasive species with large impacts on freshwater phyto- and zooplankton assemblages. Here, we show that IDMs have direct effects on lake bacterioplankton abundance, taxonomic composition, and inferred bacterial functional group representation.« less

  14. Lake Bacterial Assemblage Composition Is Sensitive to Biological Disturbance Caused by an Invasive Filter Feeder

    DOE PAGES

    Denef, Vincent J.; Carrick, Hunter J.; Cavaletto, Joann; ...

    2017-05-31

    One approach to improve forecasts of how global change will affect ecosystem processes is to better understand how anthropogenic disturbances alter bacterial assemblages that drive biogeochemical cycles. Species invasions are important contributors to global change, but their impacts on bacterial community ecology are rarely investigated. Here, we studied direct impacts of invasive dreissenid mussels (IDMs), one of many invasive filter feeders, on freshwater lake bacterioplankton. We demonstrated that direct effects of IDMs reduced bacterial abundance and altered assemblage composition by preferentially removing larger and particle-associated bacteria. While this increased the relative abundances of many free-living bacterial taxa, some were susceptiblemore » to filter feeding, in line with efficient removal of phytoplankton cells of <2 μm. This selective removal of particle-associated and larger bacteria by IDMs altered inferred bacterial functional group representation, defined by carbon and energy source utilization. Specifically, we inferred an increased relative abundance of chemoorganoheterotrophs predicted to be capable of rhodopsin-dependent energy generation. In contrast to the few previous studies that have focused on the longer-term combined direct and indirect effects of IDMs on bacterioplankton, our study showed that IDMs act directly as a biological disturbance to which freshwater bacterial assemblages are sensitive. The negative impacts on particle-associated bacteria, which have been shown to be more active than free-living bacteria, and the inferred shifts in functional group representation raise the possibility that IDMs may directly alter bacterially mediated ecosystem functions.Freshwater bacteria play fundamental roles in global elemental cycling and are an intrinsic part of local food webs. Human activities are altering freshwater environments, and much has been learned regarding the sensitivity of bacterial assemblages to a variety of these disturbances. Yet, relatively few studies have focused on how species invasion, which is one of the most important aspects of anthropogenic global change, affects freshwater bacterial assemblages. This study focuses on the impact of invasive dreissenid mussels (IDMs), a globally distributed group of invasive species with large impacts on freshwater phyto- and zooplankton assemblages. Here, we show that IDMs have direct effects on lake bacterioplankton abundance, taxonomic composition, and inferred bacterial functional group representation.« less

  15. Modeling CO, CO2, and H2O Ice Abundances in the Envelopes of Young Stellar Objects in the Magellanic Clouds

    NASA Astrophysics Data System (ADS)

    Pauly, Tyler; Garrod, Robin T.

    2018-02-01

    Massive young stellar objects (MYSOs) in the Magellanic Clouds show infrared absorption features corresponding to significant abundances of CO, CO2, and H2O ice along the line of sight, with the relative abundances of these ices differing between the Magellanic Clouds and the Milky Way. CO ice is not detected toward sources in the Small Magellanic Cloud, and upper limits put its relative abundance well below sources in the Large Magellanic Cloud and the Milky Way. We use our gas-grain chemical code MAGICKAL, with multiple grain sizes and grain temperatures, and further expand it with a treatment for increased interstellar radiation field intensity to model the elevated dust temperatures observed in the MCs. We also adjust the elemental abundances used in the chemical models, guided by observations of H II regions in these metal-poor satellite galaxies. With a grid of models, we are able to reproduce the relative ice fractions observed in MC MYSOs, indicating that metal depletion and elevated grain temperature are important drivers of the MYSO envelope ice composition. Magellanic Cloud elemental abundances have a subgalactic C/O ratio, increasing H2O ice abundances relative to the other ices; elevated grain temperatures favor CO2 production over H2O and CO. The observed shortfall in CO in the Small Magellanic Cloud can be explained by a combination of reduced carbon abundance and increased grain temperatures. The models indicate that a large variation in radiation field strength is required to match the range of observed LMC abundances. CH3OH abundance is found to be enhanced in low-metallicity models, providing seed material for complex organic molecule formation in the Magellanic Clouds.

  16. Comparison of distributed acceleration and standard models of cosmic-ray transport

    NASA Technical Reports Server (NTRS)

    Letaw, J. R.; Silberberg, R.; Tsao, C. H.

    1995-01-01

    Recent cosmic-ray abundance measurements for elements in the range 3 less than or equal to Z less than or equal to 28 and energies 10 MeV/n less than or equal to E less than or equal to 1 TeV/n have been analyzed with computer transport modeling. About 500 elemental and isotopic measurements have been explored in this analysis. The transport code includes the effects of ionization losses, nuclear spallation reactions (including those of secondaries), all nuclear decay modes, stripping and attachment of electrons, escape from the Galaxy, weak reacceleration and solar modulation. Four models of reacceleration (with several submodels of various reacceleration strengths) were explored. A chi (exp 2) analysis show that the reacceleration models yield at least equally good fits to the data as the standard propagation model. However, with reacceleration, the ad hoc assumptions of the standard model regarding discontinuities in the energy dependence of the mean path length traversed by cosmic rays, and in the momentum spectrum of the cosmic-ray source spectrum are eliminated. Futhermore, the difficulty between rigidity dependent leakage and energy independent anisotropy below energies of 10(exp 14) eV is alleviated.

  17. Electricity generation by direct oxidation of glucose in mediatorless microbial fuel cells.

    PubMed

    Chaudhuri, Swades K; Lovley, Derek R

    2003-10-01

    Abundant energy, stored primarily in the form of carbohydrates, can be found in waste biomass from agricultural, municipal and industrial sources as well as in dedicated energy crops, such as corn and other grains. Potential strategies for deriving useful forms of energy from carbohydrates include production of ethanol and conversion to hydrogen, but these approaches face technical and economic hurdles. An alternative strategy is direct conversion of sugars to electrical power. Existing transition metal-catalyzed fuel cells cannot be used to generate electric power from carbohydrates. Alternatively, biofuel cells in which whole cells or isolated redox enzymes catalyze the oxidation of the sugar have been developed, but their applicability has been limited by several factors, including (i) the need to add electron-shuttling compounds that mediate electron transfer from the cell to the anode, (ii) incomplete oxidation of the sugars and (iii) lack of long-term stability of the fuel cells. Here we report on a novel microorganism, Rhodoferax ferrireducens, that can oxidize glucose to CO(2) and quantitatively transfer electrons to graphite electrodes without the need for an electron-shuttling mediator. Growth is supported by energy derived from the electron transfer process itself and results in stable, long-term power production.

  18. Determination of trace metals in TSP and PM2.5 materials collected in the Metropolitan Area of Monterrey, Mexico: A characterization study by XPS, ICP-AES and SEM-EDS

    NASA Astrophysics Data System (ADS)

    González, Lucy T.; Longoria Rodríguez, F. E.; Sánchez-Domínguez, M.; Cavazos, Aleyda; Leyva-Porras, C.; Silva-Vidaurri, L. G.; Askar, Karim Acuña; Kharissov, B. I.; Villarreal Chiu, J. F.; Alfaro Barbosa, J. M.

    2017-11-01

    The concentration levels of trace metals of toxicological importance were evaluated in the total suspended particles (TSP) and particulate matter smaller than 2.5 μm (PM2.5) collected in the Metropolitan Area of Monterrey (MAM) in Mexico. Samples were characterized by inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy with an energy-dispersive spectroscopy system (SEM-EDS). In addition, the data were statistically treated by the methodology of Pearson Correlation (PC) and Principal Components Analysis (PCA) to identify the possible emitting sources. Surface analysis of the particulate matter (PM) by XPS revealed that the most abundant elements were Ca, Al, Na, Zn, Cu and Mg. The deconvolution of the Ca2p, Zn2p and Cu2p signals showed that the main contributors were CaCO3, ZnO and Cu/Cu2O, respectively. The bulk analysis of the PM by ICP-AES showed Fe, Cu and Zn as the most abundant elements. Fe-rich particles presented two different morphologies: the prismatic particles were associated with a natural origin, while the spherical particles with anthropogenic sources. The Zn and Cu were predominantly observed in the sampling stations with high vehicular traffic, and the emitting sources were associated with the burning of fuels from automobiles and the wear of the tires and brakes. The highest concentration of Pb was detected in the sampling station located near the industrial zones, and its cause was associated with the ceramic and glass industries, the burning of fuel oil in power plants and the production of lead-based batteries for automobiles.

  19. Partnership Opportunities | NREL

    Science.gov Websites

    Uncharted Waters of Energy Transformation (Part 2) April 20, 2018 NREL and Hawaiian Electric Navigate Uncharted Waters of Energy Transformation (Part 1) April 20, 2018 Abundant Renewable Energy Resources Exist

  20. Rapid Glucose Depletion Immobilizes Active Myosin-V on Stabilized Actin Cables

    PubMed Central

    Xu, Li; Bretscher, Anthony

    2014-01-01

    Summary Polarization of eukaryotic cells requires organelles and protein complexes to be transported to their proper destinations along the cytoskeleton [1]. When nutrients are abundant, budding yeast grows rapidly transporting secretory vesicles for localized growth and actively segregating organelles [2, 3]. This is mediated by myosin-Vs transporting cargos along F-actin bundles known as actin cables [4]. Actin cables are dynamic structures regulated by assembly, stabilization and disassembly [5]. Polarized growth and actin filament dynamics consume energy. For most organisms, glucose is the preferred energy source and generally represses alternative carbon source usage [6]. Thus upon abrupt glucose depletion, yeast shuts down pathways consuming large amounts of energy, including the vacuolar-ATPase [7, 8], translation [9] and phosphoinositide metabolism [10]. Here we show that glucose withdrawal rapidly (<1 min) depletes ATP levels and the yeast myosin V, Myo2, responds by relocalizing to actin cables, making it the fastest response documented. Myo2 immobilized on cables releases its secretory cargo, defining a new rigor-like state of a myosin-V in vivo. Only actively transporting Myo2 can be converted to the rigor-like state. Glucose depletion has differential effects on the actin cytoskeleton resulting in disassembly of actin patches with concomitant inhibition of endocytosis, and strong stabilization of actin cables, thereby revealing a selective and previously unappreciated ATP requirement for actin cable disassembly. A similar response is seen in HeLa cells to ATP depletion. These findings reveal a new fast-acting energy conservation strategy halting growth by immobilizing myosin-V in a newly described state on selectively stabilized actin cables. PMID:25308080

  1. Can the relativistic light-bending model explain X-ray spectral variations of Seyfert galaxies?

    NASA Astrophysics Data System (ADS)

    Mizumoto, Misaki; Moriyama, Kotaro; Ebisawa, Ken; Mineshige, Shin; Kawanaka, Norita; Tsujimoto, Masahiro

    2018-04-01

    Many Seyfert galaxies are known to exhibit Fe-K broad emission line features in their X-ray energy spectra. The observed lines have three distinct features: (1) the line profiles are skewed and show significant low-energy tails, (2) the Fe-K band has low variability, which produces a broad and deep dip in the root-mean-square (rms) spectra, and (3) photons in this band have time lags behind those in the adjacent energy bands with amplitudes of several Rg/c, where Rg is the gravitational radius. The "relativistic light-bending model" is proposed to explain these observed features, where a compact X-ray source ("lamp post") above an extreme Kerr black hole illuminates the innermost area of the accretion disc. In this paper, we critically examine the relativistic light-bending model by computing the rms spectra and the lag features using a ray-tracing technique, when a lamp post moves vertically on the black hole spin axis. As a result, we found that the observed deep rms dip requires that the iron is extremely overabundant (≳10 solar), whereas the observed lag amplitude is consistent with the normal iron abundance. Furthermore, disappearance of the lag in the high-flux state requires a source height as high as ˜40 Rg, which contradicts the relativistically broad emission line feature. Our simulations agree with the data that the reverberation feature moves to lower frequencies with larger source height; however, if this scenario is correct, the simulations predict the detection of a clear Fe-K lag at low frequencies, which is not constrained in the data. Therefore, we conclude that the relativistic light-bending model may not explain the characteristic Fe-K spectral variations in Seyfert galaxies.

  2. Can the relativistic light-bending model explain X-ray spectral variations of Seyfert galaxies?

    NASA Astrophysics Data System (ADS)

    Mizumoto, Misaki; Moriyama, Kotaro; Ebisawa, Ken; Mineshige, Shin; Kawanaka, Norita; Tsujimoto, Masahiro

    2018-06-01

    Many Seyfert galaxies are known to exhibit Fe-K broad emission line features in their X-ray energy spectra. The observed lines have three distinct features: (1) the line profiles are skewed and show significant low-energy tails, (2) the Fe-K band has low variability, which produces a broad and deep dip in the root-mean-square (rms) spectra, and (3) photons in this band have time lags behind those in the adjacent energy bands with amplitudes of several Rg/c, where Rg is the gravitational radius. The "relativistic light-bending model" is proposed to explain these observed features, where a compact X-ray source ("lamp post") above an extreme Kerr black hole illuminates the innermost area of the accretion disc. In this paper, we critically examine the relativistic light-bending model by computing the rms spectra and the lag features using a ray-tracing technique, when a lamp post moves vertically on the black hole spin axis. As a result, we found that the observed deep rms dip requires that the iron is extremely overabundant (≳10 solar), whereas the observed lag amplitude is consistent with the normal iron abundance. Furthermore, disappearance of the lag in the high-flux state requires a source height as high as ˜40 Rg, which contradicts the relativistically broad emission line feature. Our simulations agree with the data that the reverberation feature moves to lower frequencies with larger source height; however, if this scenario is correct, the simulations predict the detection of a clear Fe-K lag at low frequencies, which is not constrained in the data. Therefore, we conclude that the relativistic light-bending model may not explain the characteristic Fe-K spectral variations in Seyfert galaxies.

  3. Glassy carbon/multi walled carbon nanotube/cadmium sulphide photoanode for light energy storage in vanadium photoelectrochemical cell

    NASA Astrophysics Data System (ADS)

    Peimanifard, Zahra; Rashid-Nadimi, Sahar

    2015-12-01

    The aim of this study is utilizing the artificial photosynthesis, which is an attractive and challenging theme in the photoelectrocatalytic water splitting, to charge the vanadium redox flow battery (VRFB). In this work multi walled carbon nanotube/cadmium sulphide hybrid is employed as a photoanode material to oxidize VO2+ toVO2+ for charging the positive vanadium redox flow battery's half-cell. Characterization studies are also described using the scanning electron microscopic-energy-dispersive X-ray spectroscopy (SEM-EDS), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and UV-Visible methods. The phtoelectrochemical performance is characterized by cyclic voltammetry and chronoamperometry. Applied bias photon-to-current efficiency (ABPE) is achieved for both two and three-electrode configurations. The glassy carbon/multi walled carbon nanotube/cadmium sulphide yields high maximum ABPE of 2.6% and 2.12% in three and two-electrode setups, respectively. These results provide a useful guideline in designing photoelectrochemical cells for charging the vanadium redox flow batteries by sunlight as a low cost, free and abundant energy source, which does not rely on an external power input.

  4. Nuclide Guide and International Chart of Nuclides - 2008

    NASA Astrophysics Data System (ADS)

    Golashvili, T.

    2009-08-01

    New versions of Nuclide Guide and Chart of the Nuclides were developed as a result of Russian-Chinese collaboration. The Nuclide Guide contains the basic information on more than 3000 radioactive and stable nuclides. The characteristics of isomers with half-lives more than 1 ms are included. For each nuclide spin, parity, mass of nuclide, magnetic moment (if available), mass excess, half-life or abundance, decay modes, branching ratios, emitted particles, energies of most intense gamma-rays and their intensities, decay energies and mean values of radiation energy per decay are given. For stable and natural long-lived nuclides cross-sections of thermal neutron induced activation are indicated. The information presented in the Guide was compiled from 5 sources: 1) ENSDF-2008, 2) atomic mass evaluation-2005 by Audi and Wapstra, 3) interactive data bases at web-sites , , 4) original evaluations of authors, 5) recent publications. The International Chart ot Nuclides was developed on the basis of information presented in Nuclide Guide.

  5. Heliosphere Instrument for Spectra, Composition and Anisotropy at Low Energies

    NASA Technical Reports Server (NTRS)

    Lanzerotti, L. J.; Gold, R. E.; Anderson, K. A.; Armstrong, T. P.; Lin, R. P.; Krimigis, S. M.; Pick, M.; Roelof, E. C.; Sarris, E. T.; Simnett, G. M.

    1992-01-01

    The Heliosphere Instrument for Spectra, Composition, and Anisotropy at Low Energies (HI-SCALE) is designed to make measurements of interplanetary ions and electrons throughout the entire Ulysses mission. The ions (E(i) greater than about 50 keV) and electrons (E(e) greater than about 30 keV) are identified uniquely and detected by five separate solid-state detector telescopes that are oriented to give nearly complete pitch-angle coverage from the spinning spacecraft. Ion elemental abundances are determined by Delta E vs E telescope using a thin (5 microns) front solid state detector element in a three-element telescope. Experimental operation is controlled by a microprocessor-based data system. Inflight calibration is provided by radioactive sources mounted on telescope covers which can be closed for calibration purposes and for radiation protection during the course of the mission. Ion and electron spectral information is determined using both broad-energy-range rate channels and a 32 channel pulse-height analyzer for more detailed spectra. Some initial in-ecliptic measurements are presented which demonstrate the features of the instrument.

  6. Production and degradation of polyhydroxyalkanoates in waste environment

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Lee, S.Y.; Choi, J.

    1999-06-01

    Polyhydroxyalkanoates (PHAs) are energy/carbon storage materials accumulated under unfavorable growth condition in the presence of excess carbon source. PHAs are attracting much attention as substitute for non-degradable petrochemically derived plastics because of their similar material properties to conventional plastics and complete biodegradability under natural environment upon disposal. In this paper, PHA production and degradation in waste environment as well as its role in biological phosphorus removal are reviewed. In biological phosphorus removal process, bacteria accumulating polyphosphate (poly P) uptake carbon substrates and accumulate these as PHA by utilizing energy from breaking down poly P under anaerobic conditions. In the followingmore » aerobic condition, accumulated PHA is utilized for energy generation and for the regeneration of poly P. PHA production from waste has been investigated in order to utilize abundant organic compounds in waste water. Since PHA content and PHA productivity that can be obtained are rather low, PHA production from waste product should be considered as a coupled process for reducing the amount of organic waste. PHAs can be rapidly degraded to completion in municipal anaerobic sludge by various microorganisms.« less

  7. Energy Storage Materials from Nature through Nanotechnology: A Sustainable Route from Reed Plants to a Silicon Anode for Lithium-Ion Batteries.

    PubMed

    Liu, Jun; Kopold, Peter; van Aken, Peter A; Maier, Joachim; Yu, Yan

    2015-08-10

    Silicon is an attractive anode material in energy storage devices, as it has a ten times higher theoretical capacity than its state-of-art carbonaceous counterpart. However, the common process to synthesize silicon nanostructured electrodes is complex, costly, and energy-intensive. Three-dimensional (3D) porous silicon-based anode materials have been fabricated from natural reed leaves by calcination and magnesiothermic reduction. This sustainable and highly abundant silica source allows for facile production of 3D porous silicon with very good electrochemical performance. The obtained silicon anode retains the 3D hierarchical architecture of the reed leaf. Impurity leaching and gas release during the fabrication process leads to an interconnected porosity and the reductive treatment to an inside carbon coating. Such anodes show a remarkable Li-ion storage performance: even after 4000 cycles and at a rate of 10 C, a specific capacity of 420 mA h g(-1) is achieved. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Recent developments in organic redox flow batteries: A critical review

    NASA Astrophysics Data System (ADS)

    Leung, P.; Shah, A. A.; Sanz, L.; Flox, C.; Morante, J. R.; Xu, Q.; Mohamed, M. R.; Ponce de León, C.; Walsh, F. C.

    2017-08-01

    Redox flow batteries (RFBs) have emerged as prime candidates for energy storage on the medium and large scales, particularly at the grid scale. The demand for versatile energy storage continues to increase as more electrical energy is generated from intermittent renewable sources. A major barrier in the way of broad deployment and deep market penetration is the use of expensive metals as the active species in the electrolytes. The use of organic redox couples in aqueous or non-aqueous electrolytes is a promising approach to reducing the overall cost in long-term, since these materials can be low-cost and abundant. The performance of such redox couples can be tuned by modifying their chemical structure. In recent years, significant developments in organic redox flow batteries has taken place, with the introduction of new groups of highly soluble organic molecules, capable of providing a cell voltage and charge capacity comparable to conventional metal-based systems. This review summarises the fundamental developments and characterization of organic redox flow batteries from both the chemistry and materials perspectives. The latest advances, future challenges and opportunities for further development are discussed.

  9. Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates.

    PubMed

    Román-Leshkov, Yuriy; Barrett, Christopher J; Liu, Zhen Y; Dumesic, James A

    2007-06-21

    Diminishing fossil fuel reserves and growing concerns about global warming indicate that sustainable sources of energy are needed in the near future. For fuels to be useful in the transportation sector, they must have specific physical properties that allow for efficient distribution, storage and combustion; these properties are currently fulfilled by non-renewable petroleum-derived liquid fuels. Ethanol, the only renewable liquid fuel currently produced in large quantities, suffers from several limitations, including low energy density, high volatility, and contamination by the absorption of water from the atmosphere. Here we present a catalytic strategy for the production of 2,5-dimethylfuran from fructose (a carbohydrate obtained directly from biomass or by the isomerization of glucose) for use as a liquid transportation fuel. Compared to ethanol, 2,5-dimethylfuran has a higher energy density (by 40 per cent), a higher boiling point (by 20 K), and is not soluble in water. This catalytic strategy creates a route for transforming abundant renewable biomass resources into a liquid fuel suitable for the transportation sector, and may diminish our reliance on petroleum.

  10. Size dependent polaronic conduction in hematite

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sharma, Monika; Banday, Azeem; Murugavel, Sevi

    2016-05-23

    Lithium Ion Batteries have been attracted as the major renewable energy source for all portable electronic devices because of its advantages like superior energy density, high theoretical capacity, high specific energy, stable cycling and less memory effects. Recently, α-Fe{sub 2}O{sub 3} has been considered as a potential anode material due to high specific capacity, low cost, high abundance and environmental benignity. We have synthesized α-Fe{sub 2}O{sub 3} with various sizes by using the ball milling and sol-gel procedure. Here, we report the dc conductivity measurement for the crystallite size ranging from 15 nm to 50 nm. It has been observedmore » that the enhancement in the polaronic conductivity nearly two orders in magnitude while reducing the crystallite size from bulk into nano scale level. The enhancement in the conductivity is due to the augmented to compressive strain developed in the material which leads to pronounced decrease in the hopping length of polarons. Thus, nanocrystaline α-Fe{sub 2}O{sub 3} may be a better alternative anode material for lithium ion batteries than earlier reported systems.« less

  11. Relative and contextual contribution of different sources to the composition and abundance of indoor air bacteria in residences.

    PubMed

    Miletto, Marzia; Lindow, Steven E

    2015-12-10

    The study of the microbial communities in the built environment is of critical importance as humans spend the majority of their time indoors. While the microorganisms in living spaces, especially those in the air, can impact health and well-being, little is known of their identity and the processes that determine their assembly. We investigated the source-sink relationships of airborne bacteria in 29 homes in the San Francisco Bay Area. Samples taken in the sites expected to be source habitats for indoor air microbes were analyzed by 16S rRNA-based pyrosequencing and quantitative PCR. The community composition was related to the characteristics of the household collected at the time of sampling, including the number of residents and pets, activity levels, frequency of cooking and vacuum cleaning, extent of natural ventilation, and abundance and type of vegetation surrounding the building. Indoor air harbored a diverse bacterial community dominated by Diaphorobacter sp., Propionibacterium sp., Sphingomonas sp., and Alicyclobacillus sp. Source-sink analysis suggested that outdoor air was the primary source of indoor air microbes in most homes. Bacterial phylogenetic diversity and relative abundance in indoor air did not differ statistically from that in outdoor air. Moreover, the abundance of bacteria in outdoor air was positively correlated with that in indoor air, as would be expected if outdoor air was the main contributor to the bacterial community in indoor bioaerosols. The number of residents, presence of pets, and local tap water also influenced the diversity and size of indoor air microbes. The bacterial load in air increased with the number of residents, activity, and frequency of natural ventilation, and the proportion of bacteria putatively derived from skin increased with the number of residents. Vacuum cleaning increased the signature of pet- and floor-derived bacteria in indoor air, while the frequency of natural ventilation decreased the relative abundance of tap water-derived microorganisms in air. Indoor air in residences harbors a diverse bacterial community originating from both outdoor and indoor sources and is strongly influenced by household characteristics.

  12. Source of metabolizable energy affects gene transcription in metabolic pathways in adipose and liver tissue of nonlactating, pregnant dairy cows.

    PubMed

    Crookenden, M A; Mandok, K S; Grala, T M; Phyn, C V C; Kay, J K; Greenwood, S L; Roche, J R

    2015-02-01

    The objective of this experiment was to determine if transcript abundance of genes involved in metabolic pathways in adipose and liver tissue could provide some explanation for the low efficiency with which ME in autumn pasture is used for BW gain. Nonlactating, pregnant (208 ± 19 d of gestation or approximately 75 d precalving) dairy cows (n = 90) were randomly allocated to either a control diet (i.e., offered fresh autumn pasture to maintenance requirements: 0.55 MJ ME/kg of measured metabolic BW [BW0.75] per day) or, in addition to the control diet, 1 of 2 supplement amounts (2.5 and 5.0 kg DM/d) of autumn pasture or 1 of 4 supplementary feeds (i.e., a control and 2 levels of feeding for each of 5 feeds: 11 groups of cows). Along with autumn pasture, evaluated feeds included spring pasture silage, maize silage, maize grain, and palm kernel expeller. Adipose and liver tissues were biopsied in wk 4 of the experiment and transcript abundance of genes involved in metabolic pathways associated with energy metabolism, lipolysis, and lipogenesis was determined. Additional feed, irrespective of type, increased BW gain (P < 0.01) and this effect was reflected in the expression of genes in adipose and liver tissue. However, autumn pasture had lower energy-use efficiency than the other feeds. Genes involved in both lipogenesis (ACACA, THRSP, GPAM, GPD1, and LPL) and lipolysis (PNPLA2) were upregulated (P < 0.05) in adipose tissue in response to increased ME intake/kilogram BW0.75. Hepatic expression of APOA1 decreased and that of APOB increased (P < 0.05) in cows offered maize grain and maize silage (i.e., starch-containing feeds). In comparison, pasture-fed cows demonstrated a degree of uncoupling of the somatotropic axis, with lower hepatic transcript abundance of both GHR1A and IGF-1 compared with cows offered any of the other 4 feeds. Changes to gene transcription indicate a possible molecular mechanism for the poor BW gain evident in ruminants consuming autumn pasture.

  13. Assessing water source and channel type as factors affecting benthic macroinvertebrate and periphyton assemblages in the highly urbanized Santa Ana River Basin, California

    USGS Publications Warehouse

    Burton, Carmen; Brown, Larry R.; Belitz, Kenneth

    2005-01-01

    The Santa Ana River basin is the largest stream system in Southern California and includes a densely populated coastal area. Extensive urbanization has altered the geomorphology and hydrology of the streams, adversely affecting aquatic communities. We studied macroinvertebrate and periphyton assemblages in relation to two categorical features of the highly engineered hydrologic system-water source and channel type. Four water sources were identified-natural, urban-impacted groundwater, urban runoff, and treated wastewater. Three channel types were identified-natural, channelized with natural bottom, and concrete-lined. Nineteen sites, covering the range of these two categorical features, were sampled in summer 2000. To minimize the effects of different substrate types among sites, artificial substrates were used for assessing macroinvertebrate and periphyton assemblages. Physical and chemical variables and metrics calculated from macroinvertebrate and periphyton assemblage data were compared among water sources and channel types using analysis of variance and multiple comparison tests. Macroinvertebrate metrics exhibiting significant (P < 0.05) differences between water sources included taxa and Ephemeroptera-Plecoptera-Trichoptera richness, relative richness and abundance of nonchironomid dipterans, orthoclads, oligochaetes, and some functional-feeding groups such as parasites and shredders. Periphyton metrics showing significant differences between water sources included blue-green algae biovolume and relative abundance of nitrogen heterotrophic, eutrophic, motile, and pollution-sensitive diatoms. The relative abundance of trichopterans, tanytarsini chironomids, noninsects, and filter feeders, as well as the relative richness and abundance of diatoms, were significantly different between channel types. Most physical variables were related to channel type, whereas chemical variables and some physical variables (e.g., discharge, velocity, and channel width) were related to water source. These associations were reflected in correlations between metrics, chemical variables, and physical variables. Significant improvements in the aquatic ecosystem of the Santa Ana River basin are possible with management actions such as conversion of concrete-lined channels to channelized streams with natural bottoms that can still maintain flood control to protect life and property.

  14. Pricing strategies in inelastic energy markets: can we use less if we can't extract more?

    NASA Astrophysics Data System (ADS)

    Voinov, Alexey; Filatova, Tatiana

    2014-03-01

    Limited supply of nonrenewable energy resources under growing energy demand creates a situation when a marginal change in the quantity supplied or demanded causes non-marginal swings in price levels. The situation is worsened by the fact that we are currently running out of cheap energy resources at the global scale while adaptation to climate change requires extra energy costs. It is often argued that technology and alternative energy will be a solution. However, alternative energy infrastructure also requires additional energy investments, which can further increase the gap between energy demand and supply. This paper presents an explorative model that demonstrates that a smooth transition from an oil-based economy to alternative energy sources is possible only if it is started well in advance while fossil resources are still abundant. Later the transition looks much more dramatic and it becomes risky to rely entirely on technological solutions. It becomes increasingly likely that in addition to technological solutions that can increase supply we will need to find ways to decrease demand and consumption. We further argue that market mechanisms can be just as powerful tools to curb demand as they have traditionally been for stimulating consumption. We observe that individuals who consume more energy resources benefit at the expense of those who consume less, effectively imposing price externalities on the latters. We suggest two transparent and flexible methods of pricing that attempt to eliminate price externalities on energy resources. Such pricing schemes stimulate less consumption and can smooth the transition to renewable energy.

  15. The sialotranscriptome of Antricola delacruzi female ticks is compatible with non-hematophagous behavior and an alternative source of food

    PubMed Central

    Ribeiro, José Marcos C.; Labruna, Marcelo B.; Mans, Ben J.; Maruyama, Sandra Regina; Francischetti, Ivo M. B.; Barizon, Gustavo Canavaci; de Miranda Santos, Isabel K. F.

    2012-01-01

    The hosts for Antricola delacruzi ticks are insectivorous, cave-dwelling bats on which only larvae are found. The mouthparts of nymphal and adult A. delacruzi are compatible with scavenging feeding because the hypostome is small and toothless. How a single blood meal of a larva provides energy for several molts as well as for oviposition by females is not known. Adults of A. delacruzi possibly feed upon an unknown food source in bat guano, a substrate on which nymphal and adult stages are always found. Guano produced by insectivorous bats contains twice the amount of protein and 60 times the amount of iron as beef. In addition, bacteria and chitin-rich fungi proliferate on guano. Comparative data on the transcriptome of the salivary glands of A. delacruzi is nonexistent and would help to understand the physiological adaptations of salivary glands that accompany different sources of food as well as the steps taken by the Acari towards haematophagy, believed to have evolved from scavenging dead animals. Annotation of the transcriptome of salivary glands from female instars of A. delacruzi collected on guano categorized 5.7% of the clusters of expressed genes as putative secreted proteins. They included abundantly expressed TIL domain-containing proteins (possible anti-microbials), an abundantly expressed protein similar to a serum amyloid found in the sialotranscriptomes of Ornithodoros spp., a savignygrin, a family of mucin/peritrophin/cuticle-like proteins, antimicrobials and an HIV envelope-like glycoprotein also found in soft ticks. When comparing the transcriptome of A. delacruzi with those of blood-feeding female soft and hard ticks some notable differences were observed; they consisted of the following transcripts over- or under-represented or absent in the sialotranscriptome of A. delacuzi that may reflect its source of food: ferritin, mucins with chitin-binding domains and TIL domain-containing proteins versus lipocalins, basic tail proteins, metalloproteases, glycine-rich proteins and Kunitz protease inhibitors, respectively. PMID:22306723

  16. Monitoring the Carbon Cycle: Improving Our Ability to Proved Policy Relevant Information

    NASA Astrophysics Data System (ADS)

    Bruhwiler, L.

    2017-12-01

    Humans have altered the energy balance of the climate system mainly by producing and consuming fossil fuels, but also by emissions from food production. Manufacture and use of halocarbons, many of which are also strong greenhouse gases (GHGs) have added to anthropogenic radiative forcing. In response, the global atmosphere has warmed over the last half century at a rate of 0.17°C. The largest contribution to radiative forcing is due to CO2, and at present, about half of all anthropogenic CO2 emissions have been taken up by the oceans and terrestrial biosphere. The size of this "carbon emission discount" may change in the future as more carbon accumulates in the oceans, as human alter landscapes, and as climate changes. Efforts to limit global average temperature increases to 2°C and avoid the most catastrophic consequences of climate change depend on keeping track of both human emissions of greenhouse gases and changes in natural fluxes of carbon and nitrogen that occur in response to human activities and changing climate. Global in situ network observations provide information about changes in global GHG abundances over recent decades, as well as changing distributions between hemispheres. This information gives insight into changes in global and hemispheric sources and sinks of GHGs. It is, however, currently difficult to obtain robust information about regional sources and to discriminate between natural and anthropogenic fluxes. Information about regional sources is needed for GHG policymaking, while discrimination of natural sources is necessary for detection of trends in GHG fluxes and evaluation of coupled carbon cycle climate models. Although column average GHG abundances from space-based remote sensing data could provide considerable constraints on GHG budgets, there are still technical challenges to be overcome. Possible strategies for making progress involve greater increased observational coverage and more international collaboration, as well as improved modeling and assimilation techniques for estimating fluxes from observations.

  17. Low-energy electron-induced chemistry of condensed methanol: implications for the interstellar synthesis of prebiotic molecules.

    PubMed

    Boamah, Mavis D; Sullivan, Kristal K; Shulenberger, Katie E; Soe, ChanMyae M; Jacob, Lisa M; Yhee, Farrah C; Atkinson, Karen E; Boyer, Michael C; Haines, David R; Arumainayagam, Christopher R

    2014-01-01

    In the interstellar medium, UV photolysis of condensed methanol (CH3OH), contained in ice mantles surrounding dust grains, is thought to be the mechanism that drives the formation of "complex" molecules, such as methyl formate (HCOOCH3), dimethyl ether (CH3OCH3), acetic acid (CH3COOH), and glycolaldehyde (HOCH2CHO). The source of this reaction-initiating UV light is assumed to be local because externally sourced UV radiation cannot penetrate the ice-containing dark, dense molecular clouds. Specifically, exceedingly penetrative high-energy cosmic rays generate secondary electrons within the clouds through molecular ionizations. Hydrogen molecules, present within these dense molecular clouds, are excited in collisions with these secondary electrons. It is the UV light, emitted by these electronically excited hydrogen molecules, that is generally thought to photoprocess interstellar icy grain mantles to generate "complex" molecules. In addition to producing UV light, the large numbers of low-energy (< 20 eV) secondary electrons, produced by cosmic rays, can also directly initiate radiolysis reactions in the condensed phase. The goal of our studies is to understand the low-energy, electron-induced processes that occur when high-energy cosmic rays interact with interstellar ices, in which methanol, a precursor of several prebiotic species, is the most abundant organic species. Using post-irradiation temperature-programmed desorption, we have investigated the radiolysis initiated by low-energy (7 eV and 20 eV) electrons in condensed methanol at - 85 K under ultrahigh vacuum (5 x 10(-10) Torr) conditions. We have identified eleven electron-induced methanol radiolysis products, which include many that have been previously identified as being formed by methanol UV photolysis in the interstellar medium. These experimental results suggest that low-energy, electron-induced condensed phase reactions may contribute to the interstellar synthesis of "complex" molecules previously thought to form exclusively via UV photons.

  18. Vibration energy harvesting in a small channel fluid flow using piezoelectric transducer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hassan, Md. Mehedi, E-mail: buetmehedi10@gmail.com; Hossain, Md. Yeam, E-mail: yeamhossain@gmail.com; Mazumder, Rakib, E-mail: rakibmazumder46075@gmail.com

    2016-07-12

    This work is aimed at developing a way to harvest energy from a fluid stream with the application of piezoelectric transducers in a small channel. In this COMSOL Multiphysics based simulation study, it is attempted to harvest energy from the abundant renewable source of energy available in the form of kinetic energy of naturally occurring flow of fluids. The strategy involves harnessing energy from a fluid-actuator through generation of couples, eddies and vortices, resulting from the stagnation and separation of flow around a semi-circular bluff-body attached to a cantilever beam containing a piezoceramic layer. Fluctuation of fluidic pressure impulse onmore » the beam due to vortex shedding and varying lift forces causes the flexible cantilever beam to oscillate in the direction normal to the fluid flow in a periodic manner. The periodic application and release of a mechanical strain upon the beam effected a generation of electric potential within the piezoelectric layer, thus enabling extraction of electrical energy from the kinetic energy of the fluid. The piezoelectric material properties and transducer design are kept unchanged throughout the study, whereas the configuration is tested with different fluids and varying flow characteristics. The size and geometry of the obstructing entity are systematically varied to closely inspect the output from different iterations and for finding the optimum design parameters. The intermittent changes in the generated forces and subsequent variation in the strain on the beam are also monitored to find definitive relationship with the electrical energy output.« less

  19. Estimating the abundance of airborne pollen and fungal spores at variable elevations using an aircraft: how high can they fly?

    PubMed

    Damialis, Athanasios; Kaimakamis, Evangelos; Konoglou, Maria; Akritidis, Ioannis; Traidl-Hoffmann, Claudia; Gioulekas, Dimitrios

    2017-03-16

    Airborne pollen and fungal spores are monitored mainly in highly populated, urban environments, for allergy prevention purposes. However, their sources can frequently be located outside cities' fringes with more vegetation. So as to shed light to this paradox, we investigated the diversity and abundance of airborne pollen and fungal spores at various environmental regimes. We monitored pollen and spores using an aircraft and a car, at elevations from sea level to 2,000 m above ground, in the region of Thesssaloniki, Greece. We found a total of 24 pollen types and more than 15 spore types. Pollen and spores were detected throughout the elevational transect. Lower elevations exhibited higher pollen concentrations in only half of plant taxa and higher fungal spore concentrations in only Ustilago. Pinaceae and Quercus pollen were the most abundant recorded by airplane (>54% of the total). Poaceae pollen were the most abundant via car measurements (>77% of the total). Cladosporium and Alternaria spores were the most abundant in all cases (aircraft: >69% and >17%, car: >45% and >27%, respectively). We conclude that pollen and fungal spores can be diverse and abundant even outside the main source area, evidently because of long-distance transport incidents.

  20. Estimating the abundance of airborne pollen and fungal spores at variable elevations using an aircraft: how high can they fly?

    NASA Astrophysics Data System (ADS)

    Damialis, Athanasios; Kaimakamis, Evangelos; Konoglou, Maria; Akritidis, Ioannis; Traidl-Hoffmann, Claudia; Gioulekas, Dimitrios

    2017-03-01

    Airborne pollen and fungal spores are monitored mainly in highly populated, urban environments, for allergy prevention purposes. However, their sources can frequently be located outside cities’ fringes with more vegetation. So as to shed light to this paradox, we investigated the diversity and abundance of airborne pollen and fungal spores at various environmental regimes. We monitored pollen and spores using an aircraft and a car, at elevations from sea level to 2,000 m above ground, in the region of Thesssaloniki, Greece. We found a total of 24 pollen types and more than 15 spore types. Pollen and spores were detected throughout the elevational transect. Lower elevations exhibited higher pollen concentrations in only half of plant taxa and higher fungal spore concentrations in only Ustilago. Pinaceae and Quercus pollen were the most abundant recorded by airplane (>54% of the total). Poaceae pollen were the most abundant via car measurements (>77% of the total). Cladosporium and Alternaria spores were the most abundant in all cases (aircraft: >69% and >17%, car: >45% and >27%, respectively). We conclude that pollen and fungal spores can be diverse and abundant even outside the main source area, evidently because of long-distance transport incidents.

  1. Label-free quantitative proteomics for the extremely thermophilic bacterium Caldicellulosiruptor obsidiansis reveal distinct abundance patterns upon growth on cellobiose, crystalline cellulose, and switchgrass.

    PubMed

    Lochner, Adriane; Giannone, Richard J; Keller, Martin; Antranikian, Garabed; Graham, David E; Hettich, Robert L

    2011-12-02

    Mass spectrometric analysis of Caldicellulosiruptor obsidiansis cultures grown on four different carbon sources identified 65% of the cells' predicted proteins in cell lysates and supernatants. Biological and technical replication together with sophisticated statistical analysis were used to reliably quantify protein abundances and their changes as a function of carbon source. Extracellular, multifunctional glycosidases were significantly more abundant on cellobiose than on the crystalline cellulose substrates Avicel and filter paper, indicating either disaccharide induction or constitutive protein expression. Highly abundant flagellar, chemotaxis, and pilus proteins were detected during growth on insoluble substrates, suggesting motility or specific substrate attachment. The highly abundant extracellular binding protein COB47_0549 together with the COB47_1616 ATPase might comprise the primary ABC-transport system for cellooligosaccharides, while COB47_0096 and COB47_0097 could facilitate monosaccharide uptake. Oligosaccharide degradation can occur either via extracellular hydrolysis by a GH1 β-glycosidase or by intracellular phosphorolysis using two GH94 enzymes. When C. obsidiansis was grown on switchgrass, the abundance of hemicellulases (including GH3, GH5, GH51, and GH67 enzymes) and certain sugar transporters increased significantly. Cultivation on biomass also caused a concerted increase in cytosolic enzymes for xylose and arabinose fermentation.

  2. Estimating the abundance of airborne pollen and fungal spores at variable elevations using an aircraft: how high can they fly?

    PubMed Central

    Damialis, Athanasios; Kaimakamis, Evangelos; Konoglou, Maria; Akritidis, Ioannis; Traidl-Hoffmann, Claudia; Gioulekas, Dimitrios

    2017-01-01

    Airborne pollen and fungal spores are monitored mainly in highly populated, urban environments, for allergy prevention purposes. However, their sources can frequently be located outside cities’ fringes with more vegetation. So as to shed light to this paradox, we investigated the diversity and abundance of airborne pollen and fungal spores at various environmental regimes. We monitored pollen and spores using an aircraft and a car, at elevations from sea level to 2,000 m above ground, in the region of Thesssaloniki, Greece. We found a total of 24 pollen types and more than 15 spore types. Pollen and spores were detected throughout the elevational transect. Lower elevations exhibited higher pollen concentrations in only half of plant taxa and higher fungal spore concentrations in only Ustilago. Pinaceae and Quercus pollen were the most abundant recorded by airplane (>54% of the total). Poaceae pollen were the most abundant via car measurements (>77% of the total). Cladosporium and Alternaria spores were the most abundant in all cases (aircraft: >69% and >17%, car: >45% and >27%, respectively). We conclude that pollen and fungal spores can be diverse and abundant even outside the main source area, evidently because of long-distance transport incidents. PMID:28300143

  3. Proteome-wide quantitative multiplexed profiling of protein expression: carbon-source dependency in Saccharomyces cerevisiae

    PubMed Central

    Paulo, Joao A.; O’Connell, Jeremy D.; Gaun, Aleksandr; Gygi, Steven P.

    2015-01-01

    The global proteomic alterations in the budding yeast Saccharomyces cerevisiae due to differences in carbon sources can be comprehensively examined using mass spectrometry–based multiplexing strategies. In this study, we investigate changes in the S. cerevisiae proteome resulting from cultures grown in minimal media using galactose, glucose, or raffinose as the carbon source. We used a tandem mass tag 9-plex strategy to determine alterations in relative protein abundance due to a particular carbon source, in triplicate, thereby permitting subsequent statistical analyses. We quantified more than 4700 proteins across all nine samples; 1003 proteins demonstrated statistically significant differences in abundance in at least one condition. The majority of altered proteins were classified as functioning in metabolic processes and as having cellular origins of plasma membrane and mitochondria. In contrast, proteins remaining relatively unchanged in abundance included those having nucleic acid–related processes, such as transcription and RNA processing. In addition, the comprehensiveness of the data set enabled the analysis of subsets of functionally related proteins, such as phosphatases, kinases, and transcription factors. As a resource, these data can be mined further in efforts to understand better the roles of carbon source fermentation in yeast metabolic pathways and the alterations observed therein, potentially for industrial applications, such as biofuel feedstock production. PMID:26399295

  4. Volatile inventory of Mars-2: Primordial sources and fractionating processes

    NASA Technical Reports Server (NTRS)

    Pepin, R. O.

    1987-01-01

    The total volatile inventory of Mars has been modeled using meteoritic and presumed primordial abundances in the early solar system. Evidence is presented which indicates that the elemental abundances of the noble gases on Earth and Mars are similar, and their ratios are comparable to those in average carbonaceous chondrites with the exception of xenon and krypton. In order to account for presently observed variations in gas abundances, two primordial sources were used. One was the solar composition similar to the solar wind, and the other of carbonaceous grains that were the source for trace exotic components. For Mars, a model in which the early, high solar EUV flux with continued hydrogen production by differentiation results in mass fractionation of the primordial atmosphere, early depletion of xenon, and later depletion of gases lighter than krypton. The result is that the primordial Mars water inventory may have been on the order of 20 to 30 km if spread over the planet.

  5. Lunar surface cosmic ray experiment S-152, Apollo 16

    NASA Technical Reports Server (NTRS)

    Fleischer, R. L.; Hart, H. R., Jr.; Carter, M.; Comostock, G. M.; Renshaw, A.; Woods, R. T.

    1973-01-01

    This investigation was directed at determining the energy spectra and abundances of low energy heavy cosmic rays (0.03 E or = 150 MeV/nucleon). The cosmic rays were detected using plastic and glass particle track detectors. Particles emitted during the 17 April 1972 solar flare dominated the spectra for energies below about 70 MeV/nucleon. Two conclusions emerge from the low energy data: (1) The differential energy spectra for solar particles vary rapidly for energies as low as 0.05 MeV/nucleon for iron-group nuclei. (2) The abundance ratio of heavy elements changes with energy at low energies; heavy elements are enhanced relative to higher elements increasingly as the energy decreases. Galactic particle fluxes recorded within the spacecraft are in agreement with those predicted taking into account solar modulation and spacecraft shielding. The composition of the nuclei at energies above 70 MeV/nucleon imply that these particles originate outside the solar system and hence are galactic cosmic rays.

  6. Early Mars: A Warm Wet Niche for Life

    NASA Technical Reports Server (NTRS)

    Gibson, Everett K.; McKay, David S.; Thomas-Keprta, Kathie L.; Clemett, Simon J.

    2010-01-01

    Exploration of Mars has begun to unveil the history of the planet. Combinations of remote sensing, in situ compositional measurements and photographic observations have shown Mars had a dynamic and active geologic evolution. Mars geologic evolution had conditions that were suitable for supporting life. A habitable planet must have water, carbon and energy sources along with a dynamic geologic past. Mars meets all of these requirements. The first 600 Ma of Martian history were ripe for life to develop because of the abundance of: (i) Water-as shown by carved canyons and oceans or lakes with the early presence of near surface water shown by precipitated carbonates in ALH84001, well-dated at approx.3.9 Ga, (ii) Energy from the original accretional processes, a molten core which generated a strong magnetic field leaving a permanent record in the early crust, active volcanism continuing throughout Martian history, and continuing impact processes, (iii) Carbon, water and a likely thicker atmosphere from extensive volcanic outgassing (i.e. H2O, CO2, CH4, CO, O2, N2, H2S, SO2, etc.) and (iv) crustal tectonics as revealed by faulting and possible plate movement reflected by the magnetic patterns in the crust [1]. The question arises: "Why would life not develop from these favorable conditions on Mars in its first 600 Ma?" During this period, environmental near-surface conditions on Mars were more favorable to life than at any later time. Standing bodies of water, precipitation and flowing surface water, and possibly abundant hydrothermal energy would favor the formation of early life. (Even if life developed elsewhere on Earth, Venus, or on other bodies-it was transported to Mars where surface conditions were suitable for life to evolve)

  7. Predictive Modeling of Terrestrial Radiation Exposure from Geologic Materials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Malchow, Russell L.; Haber, Daniel University of Nevada, Las Vegas; Burnley, Pamela

    2015-01-01

    Aerial gamma ray surveys are important for those working in nuclear security and industry for determining locations of both anthropogenic radiological sources and natural occurrences of radionuclides. During an aerial gamma ray survey, a low flying aircraft, such as a helicopter, flies in a linear pattern across the survey area while measuring the gamma emissions with a sodium iodide (NaI) detector. Currently, if a gamma ray survey is being flown in an area, the only way to correct for geologic sources of gamma rays is to have flown the area previously. This is prohibitively expensive and would require complete nationalmore » coverage. This project’s goal is to model the geologic contribution to radiological backgrounds using published geochemical data, GIS software, remote sensing, calculations, and modeling software. K, U and Th are the three major gamma emitters in geologic material. U and Th are assumed to be in secular equilibrium with their daughter isotopes. If K, U, and Th abundance values are known for a given geologic unit the expected gamma ray exposure rate can be calculated using the Grasty equation or by modeling software. Monte Carlo N-Particle Transport software (MCNP), developed by Los Alamos National Laboratory, is modeling software designed to simulate particles and their interactions with matter. Using this software, models have been created that represent various lithologies. These simulations randomly generate gamma ray photons at energy levels expected from natural radiologic sources. The photons take a random path through the simulated geologic media and deposit their energy at the end of their track. A series of nested spheres have been created and filled with simulated atmosphere to record energy deposition. Energies deposited are binned in the same manner as the NaI detectors used during an aerial survey. These models are used in place of the simplistic Grasty equation as they take into account absorption properties of the lithology which the simplistic equation ignores.« less

  8. Prospects for PWNe and SNRs science with the ASTRI mini-array of pre-production small-sized telescopes of the Cherenkov telescope array

    NASA Astrophysics Data System (ADS)

    Burtovoi, A.; Zampieri, L.; Giuliani, A.; Bigongiari, C.; Di Pierro, F.; Stamerra, A.

    2017-01-01

    The development and construction of the Cherenkov Telescope Array (CTA) opens up new opportunities for the study of very high energy (VHE, E > 100 GeV) sources. As a part of CTA, the ASTRI project, led by INAF, has one of the main goals to develop one of the mini-arrays of CTA pre-production telescopes, proposed to be installed at the CTA southern site. Thanks to the innovative dual-mirror optical design of its small-sized telescopes, the ASTRI mini-array will be characterized by a large field of view, an excellent angular resolution and a good sensitivity up to energies of several tens of TeV. Pulsar wind nebulae, along with Supernova Remnants, are among the most abundant sources that will be identified and investigated, with the ultimate goal to move significantly closer to an understanding of the origin of cosmic rays (CR). As part of the ongoing effort to investigate the scientific capabilities for both CTA as a whole and the ASTRI mini-array, we performed simulations of the Vela X region. We simulated its extended VHE γ-ray emission using the results of the detailed H.E.S.S. analysis of this source. We estimated the resolving capabilities of the diffuse emission and the detection significance of the pulsar with both CTA as a whole and the ASTRI mini-array. Moreover with these instruments it will be possible to observe the high-energy end of SNRs spectrum, searching for particles with energies near the cosmic-rays "knee" (E ˜ 1015 eV). We simulated a set of ASTRI mini-array observations for one young and an evolved SNRs in order to test the capabilities of this instrument to discover and study PeVatrons on the Galactic plane.

  9. Catalysts Based on Earth-Abundant Metals for Visible Light-Driven Water Oxidation Reaction.

    PubMed

    Lin, Junqi; Han, Qing; Ding, Yong

    2018-06-04

    Exploration of water oxidation catalyst (WOC) with excellent performance is the key for the overall water splitting reaction, which is a feasible strategy to convert solar energy to chemical energy. Although some compounds composed of noble metals, mainly Ru and Ir, have been reported to catalyze water oxidation with high efficiency, catalysts based on low-cost and earth-abundant transition metals are essential for realizing economical and large-scale light-driven water splitting. Various WOCs containing earth-abundant metals (mainly Mn, Fe, Co, Ni, Cu) have been utilized for visible light-driven water oxidation in recent years. In this Personal Account, we summarize our recent developments in WOCs based on earth-abundant transition metals including polyoxometalates (POMs), metal oxides or bimetal oxides, and metal complexes containing multidentate ligand scaffolds for visible light-driven water oxidation reaction. © 2018 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Anthropogenic water sources and the effects on Sonoran Desert small mammal communities

    PubMed Central

    Switalski, Aaron B.

    2017-01-01

    Anthropogenic water sources (AWS) are developed water sources used as a management tool for desert wildlife species. Studies documenting the effects of AWS are often focused on game species; whereas, the effects on non-target wildlife are less understood. We used live trapping techniques to investigate rodent abundance, biomass, and diversity metrics near AWS and paired control sites; we sampled vegetation to determine rodent-habitat associations in the Sauceda Mountains of the Sonoran Desert in Arizona. A total of 370 individual mammals representing three genera and eight species were captured in 4,800 trap nights from winter 2011 to spring 2012. A multi-response permutation procedure was used to identify differences in small mammal community abundance and biomass by season and treatment. Rodent abundance, biomass, and richness were greater at AWS compared to control sites. Patterns of abundance and biomass were driven by the desert pocket mouse (Chaetodipus penicillatus) which was the most common capture and two times more numerous at AWS compared to controls. Vegetation characteristics, explored using principal components analysis, were similar between AWS and controls. Two species that prefer vegetation structure, Bailey’s pocket mouse (C. baileyi) and white-throated woodrat (Neotoma albigula), had greater abundances and biomass near AWS and were associated with habitat having high cactus density. Although small mammals do not drink free-water, perhaps higher abundances of some species of desert rodents at AWS could be related to artificial structure associated with construction or other resources. Compared to the 30-year average of precipitation for the area, the period of our study occurred during a dry winter. During dry periods, perhaps AWS provide resources to rodents related to moisture. PMID:29134147

  11. Anthropogenic water sources and the effects on Sonoran Desert small mammal communities.

    PubMed

    Switalski, Aaron B; Bateman, Heather L

    2017-01-01

    Anthropogenic water sources (AWS) are developed water sources used as a management tool for desert wildlife species. Studies documenting the effects of AWS are often focused on game species; whereas, the effects on non-target wildlife are less understood. We used live trapping techniques to investigate rodent abundance, biomass, and diversity metrics near AWS and paired control sites; we sampled vegetation to determine rodent-habitat associations in the Sauceda Mountains of the Sonoran Desert in Arizona. A total of 370 individual mammals representing three genera and eight species were captured in 4,800 trap nights from winter 2011 to spring 2012. A multi-response permutation procedure was used to identify differences in small mammal community abundance and biomass by season and treatment. Rodent abundance, biomass, and richness were greater at AWS compared to control sites. Patterns of abundance and biomass were driven by the desert pocket mouse ( Chaetodipus penicillatus ) which was the most common capture and two times more numerous at AWS compared to controls. Vegetation characteristics, explored using principal components analysis, were similar between AWS and controls. Two species that prefer vegetation structure, Bailey's pocket mouse ( C. baileyi ) and white-throated woodrat ( Neotoma albigula) , had greater abundances and biomass near AWS and were associated with habitat having high cactus density. Although small mammals do not drink free-water, perhaps higher abundances of some species of desert rodents at AWS could be related to artificial structure associated with construction or other resources. Compared to the 30-year average of precipitation for the area, the period of our study occurred during a dry winter. During dry periods, perhaps AWS provide resources to rodents related to moisture.

  12. Water and organics in interplanetary dust particles

    NASA Astrophysics Data System (ADS)

    Bradley, John

    Interplanetary dust particles (IDPs) and larger micrometeorites (MMs) impinge on the upper atmosphere where they decelerate at 90 km altitude and settle to the Earths surface. Comets and asteroids are the major sources and the flux, 30,000-40,000 tons/yr, is comparable to the mass of larger meteorites impacting the Earths surface. The sedimentary record suggests that the flux was much higher on the early Earth. The chondritic porous (CP) subset of IDPs together with their larger counterparts, ultracarbonaceous micrometeorites (UCMMs), appear to be unique among known meteoritic materials in that they are composed almost exclusively of anhydrous minerals, some of them contain >> 50% organic carbon by volume as well as the highest abundances of presolar silicate grains including GEMS. D/H and 15N abundances implicate the Oort Cloud or presolar molecular cloud as likely sources of the organic carbon. Prior to atmospheric entry, IDPs and MMs spend 104-105 year lifetimes in solar orbit where their surfaces develop amorphous space weathered rims from exposure to the solar wind (SW). Similar rims are observed on lunar soil grains and on asteroid Itokawa regolith grains. Using valence electron energy-loss spectroscopy (VEELS) we have detected radiolytic water in the rims on IDPs formed by the interaction of solar wind protons with oxygen in silicate minerals. Therefore, IDPs and MMs continuously deliver both water and organics to the earth and other terrestrial planets. The interaction of protons with oxygen-rich minerals to form water is a universal process.

  13. STATISTICAL CHARACTERISTICS OF ELEMENTAL ABUNDANCE RATIOS: OBSERVATIONS FROM THE ACE SPACECRAFT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhao, L.-L.; Zhang, H.

    We statistically analyze the elemental galactic cosmic ray (GCR) composition measurements of elements 5 ≤ Z ≤ 28 within the energy range 30–500 MeV/nucleon from the CRIS instrument on board the ACE spacecraft in orbit about the L1 Lagrange point during the period from 1997 to 2014. Similarly to the last unusual solar minimum, the elevated elemental intensities of all heavy nuclei during the current weak solar maximum in 2014 are ∼40% higher than that of the previous solar maximum in 2002, which has been attributed to the weak modulation associated with low solar activity levels during the ongoing weakestmore » solar maximum since the dawn of space age. In addition, the abundance ratios of heavy nuclei with respect to elemental oxygen are generally independent of kinetic energy per nucleon in the energy region 60–200 MeV/nuc, in good agreement with previous experiments. Furthermore, the abundance ratios of most relatively abundant species, except carbon, exhibit considerable solar-cycle variation, which are obviously positively correlated with the sunspot numbers with about one-year time lag. We also find that the percentage variation of abundance ratios for most elements are approximately identical. These preliminary results provide valuable insights into the characteristics of elemental heavy nuclei composition and place new and significant constraints on future GCR heavy nuclei propagation and modulation models.« less

  14. Restoring piscivorous fish populations in the Laurentian Great Lakes causes seabird dietary change

    USGS Publications Warehouse

    Hebert, C.E.; Weseloh, D.V.C.; Idrissi, A.; Arts, M.T.; O'Gorman, R.; Gorman, O.T.; Locke, B.; Madenjian, C.P.; Roseman, E.F.

    2008-01-01

    Ecosystem change often affects the structure of aquatic communities thereby regulating how much and by what pathways energy and critical nutrients flow through food webs. The availability of energy and essential nutrients to top predators such as seabirds that rely on resources near the water's surface will be affected by changes in pelagic prey abundance. Here, we present results from analysis of a 25-year data set documenting dietary change in a predatory seabird from the Laurentian Great Lakes. We reveal significant declines in trophic position and alterations in energy and nutrient flow over time. Temporal changes in seabird diet tracked decreases in pelagic prey fish abundance. As pelagic prey abundance declined, birds consumed less aquatic prey and more terrestrial food. This pattern was consistent across all five large lake ecosystems. Declines in prey fish abundance may have primarily been the result of predation by stocked piscivorous fishes, but other lake-specific factors were likely also important. Natural resource management activities can have unintended consequences for nontarget ecosystem components. Reductions in pelagic prey abundance have reduced the capacity of the Great Lakes to support the energetic requirements of surface-feeding seabirds. In an environment characterized by increasingly limited pelagic fish resources, they are being offered a Hobsonian choice: switch to less nutritious terrestrial prey or go hungry. ?? 2008 by the Ecological Society of America.

  15. Energy resources - cornucopia or empty barrel?

    USGS Publications Warehouse

    McCabe, P.J.

    1998-01-01

    Over the last 25 yr, considerable debate has continued about the future supply of fossil fuel. On one side are those who believe we are rapidly depleting resources and that the resulting shortages will have a profound impact on society. On the other side are those who see no impending crisis because long-term trends are for cheaper prices despite rising production. The concepts of resources and reserves have historically created considerable misunderstanding in the minds of many nongeologists. Hubbert-type predictions of energy production assume that there is a finite supply of energy that is measurable; however, estimates of resources and reserves are inventories of the amounts of a fossil fuel perceived to be available over some future period of time. As those resources/reserves are depleted over time, additional amounts of fossil fuels are inventoried. Throughout most of this century, for example, crude oil reserves in the United States have represented a 10-14-yr supply. For the last 50 yr, resource crude oil estimates have represented about a 60-70-yr supply for the United States. Division of reserve or resource estimates by current or projected annual consumption therefore is circular in reasoning and can lead to highly erroneous conclusions. Production histories of fossil fuels are driven more by demand than by the geologic abundance of the resource. Examination of some energy resources with well-documented histories leads to two conceptual models that relate production to price. The closed-market model assumes that there is only one source of energy available. Although the price initially may fall because of economies of scale long term, prices rise as the energy source is depleted and it becomes progressively more expensive to extract. By contrast, the open-market model assumes that there is a variety of available energy sources and that competition among them leads to long-term stable or falling prices. At the moment, the United States and the world approximate the open-market model, but in the long run the supply of fossil fuel is finite, and prices inevitably will rise unless alternate energy sources substitute for fossil energy supplies; however, there appears little reason to suspect that long-term price trends will rise significantly over the next few decades.Over the last 25 years, considerable debate has continued about the future supply of fossil fuel. On one side are those who believe that resources are rapidly depleting and that the resulting shortages will have a profound impact on society. On the other side are those who see no impending crisis because longterm trends are for cheaper prices despite rising production. This paper examines historic trends and clarify the foundations on which one may build one's predictions.

  16. Peptostreptococcus productus strain that grows rapidly with CO as the energy source.

    PubMed Central

    Lorowitz, W H; Bryant, M P

    1984-01-01

    Anaerobic bacteria were enriched with a sewage digestor sludge inoculum and a mineral medium supplemented with B-vitamins and 0.05% yeast extract and with a 50% CO-30% N2-20% CO2 (2 atm [202 kPa]) gas phase. Microscopic observation revealed an abundance of gram-positive cocci, 1.0 by 1.4 micron, which occurred in pairs or chains. The coccus, strain U-1, was isolated by using roll tubes with CO as the energy source. Based on morphology, sugars fermented, fermentation products from glucose (H2, acetate, lactate, and succinate), and other features, strain U-1 was identified as Peptostreptococcus productus IIb (similar to the type strain). The doubling time with up to 50% CO was 1.5 h; acetate and CO2 were the major products. In addition, no significant change in the doubling time was observed with 90% CO. Some stock strains were also able to use CO, although not as well. Strain U-1 produced acetate during growth with H2-CO2. Other C1 compounds did not support growth. Most probable numbers of CO utilizers morphologically identical with strain U-1 were 7.5 X 10(6) and 1.1 X 10(5) cells per g for anaerobic digestor sludge and human feces, respectively. PMID:6430231

  17. Molecular hydrogen: An abundant energy source for bacterial activity in nuclear waste repositories

    NASA Astrophysics Data System (ADS)

    Libert, M.; Bildstein, O.; Esnault, L.; Jullien, M.; Sellier, R.

    A thorough understanding of the energy sources used by microbial systems in the deep terrestrial subsurface is essential since the extreme conditions for life in deep biospheres may serve as a model for possible life in a nuclear waste repository. In this respect, H 2 is known as one of the most energetic substrates for deep terrestrial subsurface environments. This hydrogen is produced from abiotic and biotic processes but its concentration in natural systems is usually maintained at very low levels due to hydrogen-consuming bacteria. A significant amount of H 2 gas will be produced within deep nuclear waste repositories, essentially from the corrosion of metallic components. This will consequently improve the conditions for microbial activity in this specific environment. This paper discusses different study cases with experimental results to illustrate the fact that microorganisms are able to use hydrogen for redox processes (reduction of O 2, NO3-, Fe III) in several waste disposal conditions. Consequences of microbial activity include: alteration of groundwater chemistry and shift in geochemical equilibria, gas production or consumption, biocorrosion, and potential modifications of confinement properties. In order to quantify the impact of hydrogen bacteria, the next step will be to determine the kinetic rate of the reactions in realistic conditions.

  18. Geophysical characterization of subaerial hydrothermal manifestations in Punta Banda, Baja California, Mexico.

    NASA Astrophysics Data System (ADS)

    Flores-Marquez, L.; Prol-Ledesma, R. M.; Arango, C.; Canet, C.

    2009-04-01

    Important growth of population in Baja California Peninsula has triggered the need for energy and fresh water. The most sustainable possibility for increasing the availability of fresh water is the use of renewable energy sources in desalination plants. The abundance of geothermal manifestations in the peninsula provides a reliable energy source for desalination purposes. Geothermal development of the Baja California Peninsula dates from the 70's, when the Cerro Prieto geothermal field started producing electricity. Two important cities, Tijuana and Ensenada, are located in the north-western area of Baja California. The city of Ensenada has a desalination plant that is due to be replaced and the geothermal resources of the area could be an option for the new desalination plant. Punta Banda, a region near Ensenada, was specially investigated to determine its geothermal potential. Subaerial springs and the submarine vents were sampled and studied in this work, also geological and geochemical studies were performed, moreover geoelectrical surveys were accomplished to characterize the hydrothermal system at depth. Even though saline intrusion is a severe problem in Ensenada (TDS higher than 3000), thermal springs away from the coast and coastal springs have salinities lower than sea water. According to the geoelectrical models obtained from profiles, the inferred conductive features can be related to thermal anomalies. The existence of hot springs located along a trend suggests that the dynamic of the thermal fluid is restricted by secondary faults.

  19. Effects of Solvent and Ion Source Pressure on the Analysis of Anabolic Steroids by Low Pressure Photoionization Mass Spectrometry.

    PubMed

    Liu, Chengyuan; Zhu, Yanan; Yang, Jiuzhong; Zhao, Wan; Lu, Deen; Pan, Yang

    2017-04-01

    Solvent and ion source pressure were two important factors relating to the photon induced ion-molecule reactions in low pressure photoionization (LPPI). In this work, four anabolic steroids were analyzed by LPPI mass spectrometry. Both the ion species present and their relative abundances could be controlled by switching the solvent and adjusting the ion source pressure. Whereas M •+ , MH + , [M - H 2 O] + , and solvent adducts were observed in positive LPPI, [M - H] - and various oxidation products were abundant in negative LPPI. Changing the solvent greatly affected formation of the ion species in both positive and negative ion modes. The ion intensities of the solvent adduct and oxygen adduct were selectively enhanced when the ion source pressure was elevated from 68 to 800 Pa. The limit of detection could be decreased by increasing the ion source pressure. Graphical Abstract ᅟ.

  20. Effects of Solvent and Ion Source Pressure on the Analysis of Anabolic Steroids by Low Pressure Photoionization Mass Spectrometry

    NASA Astrophysics Data System (ADS)

    Liu, Chengyuan; Zhu, Yanan; Yang, Jiuzhong; Zhao, Wan; Lu, Deen; Pan, Yang

    2017-04-01

    Solvent and ion source pressure were two important factors relating to the photon induced ion-molecule reactions in low pressure photoionization (LPPI). In this work, four anabolic steroids were analyzed by LPPI mass spectrometry. Both the ion species present and their relative abundances could be controlled by switching the solvent and adjusting the ion source pressure. Whereas M•+, MH+, [M - H2O]+, and solvent adducts were observed in positive LPPI, [M - H]- and various oxidation products were abundant in negative LPPI. Changing the solvent greatly affected formation of the ion species in both positive and negative ion modes. The ion intensities of the solvent adduct and oxygen adduct were selectively enhanced when the ion source pressure was elevated from 68 to 800 Pa. The limit of detection could be decreased by increasing the ion source pressure.

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