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Sample records for ac impedance studies

  1. AC impedance study of degradation of porous nickel battery electrodes

    NASA Technical Reports Server (NTRS)

    Lenhart, Stephen J.; Macdonald, D. D.; Pound, B. G.

    1987-01-01

    AC impedance spectra of porous nickel battery electrodes were recorded periodically during charge/discharge cycling in concentrated KOH solution at various temperatures. A transmission line model (TLM) was adopted to represent the impedance of the porous electrodes, and various model parameters were adjusted in a curve fitting routine to reproduce the experimental impedances. Degradation processes were deduced from changes in model parameters with electrode cycling time. In developing the TLM, impedance spectra of planar (nonporous) electrodes were used to represent the pore wall and backing plate interfacial impedances. These data were measured over a range of potentials and temperatures, and an equivalent circuit model was adopted to represent the planar electrode data. Cyclic voltammetry was used to study the characteristics of the oxygen evolution reaction on planar nickel electrodes during charging, since oxygen evolution can affect battery electrode charging efficiency and ultimately electrode cycle life if the overpotential for oxygen evolution is sufficiently low.

  2. Microfabricated AC impedance sensor

    DOEpatents

    Krulevitch, Peter; Ackler, Harold D.; Becker, Frederick; Boser, Bernhard E.; Eldredge, Adam B.; Fuller, Christopher K.; Gascoyne, Peter R. C.; Hamilton, Julie K.; Swierkowski, Stefan P.; Wang, Xiao-Bo

    2002-01-01

    A microfabricated instrument for detecting and identifying cells and other particles based on alternating current (AC) impedance measurements. The microfabricated AC impedance sensor includes two critical elements: 1) a microfluidic chip, preferably of glass substrates, having at least one microchannel therein and with electrodes patterned on both substrates, and 2) electrical circuits that connect to the electrodes on the microfluidic chip and detect signals associated with particles traveling down the microchannels. These circuits enable multiple AC impedance measurements of individual particles at high throughput rates with sufficient resolution to identify different particle and cell types as appropriate for environmental detection and clinical diagnostic applications.

  3. Age-related changes in ac-impedance spectroscopy studies of normal human dentine: further investigations.

    PubMed

    Eldarrat, A H; High, A S; Kale, G M

    2010-01-01

    One of the age-related changes occurring in dentine structure is the formation of peritubular dentine on the inner walls of dentinal tubules leading to complete closure of tubules. Ac-impedance is safe, fast and non-invasive technique. In the last decade, the popularity of the technique has increased in dental research. Several investigators have used the technique to detect tooth cracks and caries. The results of in vitro studies showed that ac-impedance technique was more advanced for caries detection than visual and radiographic methods. However, other studies demonstrated that the accuracy of impedance measurements can be affected by many factors such as remineralization after tooth eruption. A study has been published on effect of age on impedance measurements by the authors for two age groups by employing ac-impedance spectroscopy. Therefore, the aim of this study was to demonstrate the importance of this technique by conducting further investigations on dentine samples of wider age groups. Dentine samples were prepared from extracted sound third molars of known patient age. The ac-impedance measurements were carried out over a wide range of frequency. After performing all electrical measurements, dentine samples were examined under SEM to correlate the electrical measurements with their structure. Impedance measurements showed that there were differences in impedance between young and old dentine. One-way ANOVA of the means of resistance and capacitance for all age groups (20, 25, 30, 40 and 50 years old dentine) revealed a significant difference (ANOVA, P < 0.0001) as a function of age. Applying Tukey's post hoc test, to the same data showed that this difference was due to the 50 years old dentine for resistance and was due to the 40 and 50 years old dentine for capacitance which were statistically different to all other groups. SEM investigation of dentine samples showed that young dentine is characterized by open dentinal tubules distributed all over the

  4. Potentiostatic and ac impedance studies of the hydrogen electrodes used in Ni/H2 batteries

    NASA Technical Reports Server (NTRS)

    Le Helloco, Jean-Guy; Bojkov, Hristo; Parthasarathy, Arvind; Srinivasan, Supramaniam; Appleby, A. J.

    1992-01-01

    In a study of electrode activity for hydrogen evolution and hydrogen ionization, knowledge of the detailed kinetics and of the surface coverage by adsorbed hydrogen is essential. In the Ni/H2 battery, the hydrogen electrode is subjected to high hydrogen pressure; elucidation of the variation of kinetic parameters with hydrogen pressure is therefore of interest. Potentiostatic and ac impedance spectroscopic techniques were used in the present study. The equivalent circuit of the reaction, the kinetic parameters, and their pressure dependence have been determined.

  5. AC impedance spectroscopy studies on solid-state sintered zinc aluminum oxide (ZnAl2O4) ceramics

    NASA Astrophysics Data System (ADS)

    Kumar, B. Rajesh; Rao, T. Subba

    2012-07-01

    In the present investigation Zinc Aluminum Oxide (ZnAl2O4) is prepared by solid-state reaction technique. Dielectric constant (ɛ'), dielectric loss(tan δ), ac conductivity (σac) as a function of temperature are studied by varying frequencies from 100 Hz to 1MHz using an impedance analyzer. The dielectric constant and dielectric loss increases gradually with an increase of temperature, but it decreases with increase of frequency. The ac conductivity (σac) also increases with increases of frequency. The transition peaks for ZnAl2O4 are observed at 490°C, 510°C, 520°C for the frequencies 1 KHz, 10 KHz and 100 KHz. No transition peaks are found for the frequency 100 Hz and 1 MHz because of high conductive loss.

  6. Study of metal corrosion using ac impedance techniques in the STS launch environment

    NASA Technical Reports Server (NTRS)

    Calle, Luz M.

    1989-01-01

    AC impedance measurements were performed to investigate the corrosion resistance of 19 alloys under conditions similar to the STS launch environment. The alloys were: Zirconium 702, Hastelloy C-22, Inconel 625, Hastelloy C-276, Hastelloy C-4, Inconel 600, 7Mo + N, Ferralium 255, Inco Alloy G-3, 20Cb-3, SS 904L, Inconel 825, SS 304LN, SS 316L, SS 317L, ES 2205, SS 304L, Hastelloy B-2, and Monel 400. AC impedance data were gathered for each alloy after one hour immersion time in each of the following three electrolyte solutions: 3.55 percent NaCl, 3.55 percent NaCl-0.1N HCl, and 3.55 percent NaCl-1.0N HCl. The data were analyzed qualitatively using the Nyquist plot and quantitatively using the Bode plot. Polarization resistance, Rp, values were obtained using the Bode plot. Zirconium 702 was the most corrosion resistant alloy in the three electrolytes. The ordering of the other alloys according the their resistance to corrosion varied as the concentration of hydrochloric acid in the electrolyte increased. The corrosion resistance of Zirconium 702 and Ferralium 255 increased as the concentration of hydrochloric acid in the electrolyte increased. The corrosion resistance of the other 17 alloys decreased as the concentration of the hyrdochloric acid in the electrolyte increased.

  7. Corrosion behaviour of galvanized steel and electroplating steel in aqueous solution: AC impedance study and XPS

    NASA Astrophysics Data System (ADS)

    Lebrini, M.; Fontaine, G.; Gengembre, L.; Traisnel, M.; Lerasle, O.; Genet, N.

    2008-08-01

    The efficiency of a new triazole derivative, namely, 2-{(2-hydroxyethyl)[(4-methyl-1 H-1,2,3-benzotriazol-1-yl)methyl]amino}ethanol (TTA) has been studied for corrosion inhibition of galvanized steel and electroplating steel in aqueous solution. Corrosion inhibition was studied using electrochemical impedance spectroscopy (EIS). These studies have shown that TTA was a very good inhibitor. Data obtained from EIS show a frequency distribution and therefore a modelling element with frequency dispersion behaviour, a constant phase element (CPE) has been used. The corrosion behaviour of galvanized steel and electroplating steel in aqueous solution was also investigated in the presence of 4-methyl-1 H-benzotriazole (TTA unsubstituted) by EIS. These studies have shown that the ability of the molecule to adsorb on the steel surface was dependent on the group in triazole ring substituent. X-ray photoelectron spectroscopy surface analysis with TTA shows that it chemisorbed on surface of galvanized steel and electroplating steel.

  8. An electrochemical study of corrosion protection by primer-topcoat systems on 4130 steel with ac impedance and dc methods

    NASA Technical Reports Server (NTRS)

    Mendrek, M. J.; Higgins, R. H.; Danford, M. D.

    1988-01-01

    To investigate metal surface corrosion and the breakdown of metal protective coatings, the ac impedance method is applied to six systems of primer coated and primer topcoated 4130 steel. Two primers were used: a zinc-rich epoxy primer and a red lead oxide epoxy primer. The epoxy-polyamine topcoat was used in four of the systems. The EG and G-PARC Model 368 ac impedance measurement system, along with dc measurements with the same system using the polarization resistance method, were used to monitor changing properties of coated 4230 steel disks immersed in 3.5 percent NaCl solutions buffered at pH 5.4 over periods of 40 to 60 days. The corrosion system can be represented by an electronic analog called an equivalent circuit consisting of resistors and capacitors in specific arrangements. This equivalent circuit parallels the impedance behavior of the corrosion system during a frequency scan. Values for the resistors and capacitors, that can be assigned in the equivalent circuit following a least-squares analysis of the data, describe changes that occur on the corroding metal surface and in the protective coatings. Two equivalent circuits have been determined that predict the correct Bode phase and magnitude of the experimental sample at different immersion times. The dc corrosion current density data are related to equivalent circuit element parameters. Methods for determining corrosion rate with ac impedance parameters are verified by the dc method.

  9. AC impedance analysis of polypyrrole thin films

    NASA Technical Reports Server (NTRS)

    Penner, Reginald M.; Martin, Charles R.

    1987-01-01

    The AC impedance spectra of thin polypyrrole films were obtained at open circuit potentials from -0.4 to 0.4 V vs SCE. Two limiting cases are discussed for which simplified equivalent circuits are applicable. At very positive potentials, the predominantly nonfaradaic AC impedance of polypyrrole is very similar to that observed previously for finite porous metallic films. Modeling of the data with the appropriate equivalent circuit permits effective pore diameter and pore number densities of the oxidized film to be estimated. At potentials from -0.4 to -0.3 V, the polypyrrole film is essentially nonelectronically conductive and diffusion of polymer oxidized sites with their associated counterions can be assumed to be linear from the film/substrate electrode interface. The equivalent circuit for the polypyrrole film at these potentials is that previously described for metal oxide, lithium intercalation thin films. Using this model, counterion diffusion coefficients are determined for both semi-infinite and finite diffusion domains. In addition, the limiting low frequency resistance and capacitance of the polypyrrole thin fims was determined and compared to that obtained previously for thicker films of the polymer. The origin of the observed potential dependence of these low frequency circuit components is discussed.

  10. Equivalent circuit models for ac impedance data analysis

    NASA Technical Reports Server (NTRS)

    Danford, M. D.

    1990-01-01

    A least-squares fitting routine has been developed for the analysis of ac impedance data. It has been determined that the checking of the derived equations for a particular circuit with a commercially available electronics circuit program is essential. As a result of the investigation described, three equivalent circuit models were selected for use in the analysis of ac impedance data.

  11. AC impedance modelling study on porous electrodes of proton exchange membrane fuel cells using an agglomerate model

    NASA Astrophysics Data System (ADS)

    Gerteisen, Dietmar; Hakenjos, Alex; Schumacher, Jürgen O.

    A one-dimensional model of the PEM fuel cell cathode is developed to analyse ac impedance spectra and polarisation curves. The porous gas diffusion electrode is assumed to consist of a network of dispersed catalyst (Pt/C) forming spherically shaped agglomerated zones that are filled with electrolyte. The coupled differential equation system describes: ternary gas diffusion in the backing (O2 , N2 , water vapour), Fickian diffusion and Tafel kinetics for the oxygen reduction reaction (ORR) inside the agglomerates, proton migration with ohmic losses and double-layer charging in the electrode. Measurements are made of a temperature-controlled fuel cell with a geometric area of 1.4 cm × 1.4 cm. Lateral homogeneity is ensured by using a high stoichiometry of λmin . The model predicts the behaviour of measured polarisation curves and impedance spectra. It is found that a better humidification of the electrode leads to a higher volumetric double-layer capacity. The catalyst layer resistance shows the same behaviour depending on the humidification as the membrane resistance. Model parameters, e.g. Tafel slope, ionic resistance and agglomerate radius are varied. A sensitivity analysis of the model parameters is conducted.

  12. Use of AC Impedance Analysis to Study Membrane Changes Related to Acid Secretion in Amphibian Gastric Mucosa

    PubMed Central

    Clausen, Chris; Machen, Terry E.; Diamond, Jared M.

    1983-01-01

    We have applied transepithelial AC impedance techniques to gastric mucosa to reconcile ultrastructural and electrophysiological findings about gastric acid secretion and the mucosal barrier. By fitting impedance data measured at different HCl secretion rates to equivalent circuit models, we extracted capacitances and resistances (as measures of membrane area and ionic conductance, respectively) for the apical and basolateral membranes. The impedance measurements were found to be incompatible with earlier equivalent circuit models that modeled membrane electrical properties as lumped circuits based on one or two cell types. A distributed circuit model was developed that assumed only one dominant electrical pathway (i.e., one cell type), but that incorporated electrical effects arising from long and narrow membrane-lined structures present in the epithelium (e.g., gastric crypts, tubulovesicles, lateral intercellular spaces). This morphologically based model was found to represent the measured data accurately, and to yield values for membrane capacitances consistent with morphometric measurements of membrane areas. The main physiological conclusions from this analysis were as follows: (a) The dominant transepithelial current pathway may reside in the oxyntic cells. (b) The transepithelial conductance increase associated with the onset of acid secretion is entirely due to increased conductance of the apical membrane. This is in turn due entirely to increased area of this membrane, resulting from incorporation of tubulovesicular membrane. (c) When membrane conductances are normalized to actual membrane area by use of membrane capacitances, it turns out that acid secretion is not associated with a change in specific ionic conductance (change in conductance per unit area) at either the apical or basolateral membrane. (d) The puzzlingly low value of transepithelial resistance (≤400 Ω-cm2) arises because there are hundreds or thousands of square centimeters of actual

  13. Synthesis and characterization of cancrinite-type zeolite, and its ionic conductivity study by AC impedance analysis

    NASA Astrophysics Data System (ADS)

    Kriaa, A.; Ben Saad, K.; Hamzaoui, A. H.

    2012-12-01

    The synthesis of cancrinite in the system NaOH-SiO2-Al2O3-NaHCO3-H2O was performed, according to methods described in the literature, in an autoclave under hydrothermal conditions at T = 473 K. The electrical properties of cancrinite-type zeolite pellets were investigated by complex impedance spectroscopy in the temperature range 465-800°C. The effect of temperature on impedance parameters was studied using an impedance analyzer in a wide frequency range (1 Hz to 13 MHz). The real and imaginary parts of complex impedance trace semicircles in the complex plane are plotted. The bulk resistance of the material decreases with rise in temperature. This exhibits a typical negative temperature coefficient of resistance (NTCR) behavior of the material. The results of bulk electrical conductivity and its activation energy are presented. The modulus analysis suggests that the electrical transport processes in the material are very likely to be of electronic nature. Relaxation frequencies follow an Arrhenius behavior with activation energy values not comparable to those found for the electrical conductivity.

  14. Impedance, AC conductivity and dielectric behavior Adeninium Trichloromercurate (II)

    NASA Astrophysics Data System (ADS)

    Fersi, M. Amine; Chaabane, I.; Gargouri, M.

    2016-09-01

    In this work, we report the measurements impedance spectroscopy technique for the organic-inorganic hybrid compound (C5H6N5) HgCl3, 11/2H2O measured in the 209 Hz-5 MHz frequency range from 378 to 428 K. Besides, the Cole-Cole (Z″ versus Z‧) plots were well fitted to an equivalent circuit built up by a parallel combination of resistance (R), fractal capacitance (CPE) and capacitance (C). Furthermore, the AC conductivity was investigated as a function of temperature and frequency in the same range. The experiment results indicated that AC conductivity (σac) was proportional to σdc + A ωS . The obtained results are discussed in terms of the correlated barrier hopping (CBH) model. An agreement between the experimental and theoretical results suggests that the AC conductivity behavior of Adeninium Trichloromercurate (II) can be successfully explained by CBH model. The contribution of single polaron hopping to AC conductivity in a present alloy was also studied.

  15. Equivalent Circuits For AC-Impedance Analysis Of Corrosion

    NASA Technical Reports Server (NTRS)

    Danford, M. D.

    1992-01-01

    Report presents investigation of equivalent circuits for ac-impedance analysis of corrosion. Impedance between specimen and electrolyte measured as function of frequency. Data used to characterize corrosion electrochemical system in terms of equivalent circuit. Eleven resistor/capacitor equivalent-circuit models were analyzed.

  16. HVDC-AC system interaction from AC harmonics. Volume 1. Harmonic impedance calculations. Final report

    SciTech Connect

    Breuer, G D; Chow, J H; Lindh, C B; Miller, N W; Numrich, F H; Price, W W; Turner, A E; Whitney, R R

    1982-09-01

    Improved methods are needed to characterize ac system harmonic behavior for ac filter design for HVDC systems. The purpose of this General Electric Company RP1138 research is to evaluate the present filter design practice and to investigate methods for calculating system harmonic impedances. An overview of ac filter design for HVDC systems and a survey of literature related to filter design have been performed. Two methods for calculating system harmonic impedances have been investigated. In the measurement method, an instrumentation system for measuring system voltage and current has been assembled. Different schemes of using the measurements to calculate system harmonic impedances have been studied. In the analytical method, a procedure to include various operating conditions has been proposed. Computer programs for both methods have been prepared, and the results of the measurement and analytical methods analyzed. A conclusion of the project is that the measurement and analytical methods both provided reasonable results. There are correlations between the measured and analytical results for most harmonics, although there are discrepancies between the assumptions used in the two methods. A sensitivity approach has been proposed to further correlate the results. From the results of the analysis, it is recommended that both methods should be tested further. For the measurement method, more testing should be done to cover different system operating conditions. In the analytical method, more detailed models for representing system components should be studied. In addition, alternative statistical and sensitivity approaches should be attempted.

  17. Characterization of flow-through electrode processes by AC impedance

    SciTech Connect

    Yuh, C.Y. ); Selman, J.R. )

    1993-04-01

    Flow-through porous electrodes, such as packed-bed and fluidized-bed electrodes, are attractive for electrowinning, electro-organic synthesis and flow-battery applications. The extensive surface area of the porous electrodes makes high volumetric reaction rate more possible than in a cell with smooth electrodes. Forced convection also enhances mass-transfer rate and hence reduces concentration polarization. AC-impedance method has been used successfully in characterizing a packed-bed flow-through electrode system. A macrohomogeneous model was developed to simulate the effect of structural, physical and flow parameters. The relative importance of kinetics and mass transfer can be inferred from the AC-impedance analysis. Kinetic information about copper deposition in supported cupric sulfate solution has been obtained successfully using this technique.

  18. AC impedance electrochemical modeling of lithium-ion positive electrodes.

    SciTech Connect

    Dees, D.; Gunen, E.; Abraham, D.; Jansen, A.; Prakash, J.; Chemical Engineering; IIT

    2004-01-01

    Under Department of Energy's Advanced Technology Development Program,various analytical diagnostic studies are being carried out to examine the lithium-ion battery technology for hybrid electric vehicle applications, and a series of electrochemical studies are being conducted to examine the performance of these batteries. An electrochemical model was developed to associate changes that were observed in the post-test analytical diagnostic studies with the electrochemical performance loss during testing of lithium ion batteries. While both electrodes in the lithium-ion cell have been studied using a similar electrochemical model, the discussion here is limited to modeling of the positive electrode. The positive electrode under study has a composite structure made of a layered nickel oxide (LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2}) active material, a carbon black and graphite additive for distributing current, and a PVDF binder all on an aluminum current collector. The electrolyte is 1.2M LiPF{sub 6} dissolved in a mixture of EC and EMC and a Celgard micro-porous membrane is used as the separator. Planar test cells (positive/separator/negative) were constructed with a special fixture and two separator membranes that allowed the placement of a micro-reference electrode between the separator membranes [1]. Electrochemical studies including AC impedance spectroscopy were then conducted on the individual electrodes to examine the performance and ageing effects in the cell. The model was developed by following the work of Professor Newman at Berkeley [2]. The solid electrolyte interface (SEI) region, based on post-test analytical results, was assumed to be a film on the oxide and an oxide layer at the surface of the oxide. A double layer capacity was added in parallel with the Butler-Volmer kinetic expression. The pertinent reaction, thermodynamic, and transport equations were linearized for a small sinusoidal perturbation [3]. The resulting system of differential

  19. ac impedance measurements of molten salt thermal batteries

    NASA Astrophysics Data System (ADS)

    Singh, Pritpal; Guidotti, Ronald A.; Reisner c, David

    Non-destructive testing of thermal batteries without activating them is a challenging proposition. Molten salt thermal batteries are activated by raising their temperature to above the melting point of the salt constituting the electrolyte. One approach that we have considered is to raise the temperature of the molten salt electrolyte to a temperature below the melting point so that the battery does not get activated yet may provide sufficient mobility of the ionic species to be able to obtain some useful ac impedance measurements. This hypothesis was put to the test for two Li(Si)/FeS 2 molten salt batteries with two electrolytes of different melting points—a standard LiCl-KCl eutectic that melts at 352 °C and a LiBr-KBr-LiCl eutectic with a melting point of 319 °C. ac impedance measurements as a function of frequency and temperature below the melting point are presented for single cells and batteries.

  20. Impedance and AC conductivity study of nano crystalline, fine grained multiferroic bismuth ferrite (BiFeO3), synthesized by microwave sintering

    NASA Astrophysics Data System (ADS)

    Kolte, Jayant; Salame, Paresh H.; Daryapurkar, A. S.; Gopalan, P.

    2015-09-01

    In this paper, major reduction in sintering time,temperautre and significant improvement over final density of sitnered sample is reported for the microwave sintered nanocrystalline BiFeO3 (BFO) ceramic. Also, different sintering time and temperatures have been used to tailor the grain size and the final density of the resulting BFO ceramics synthesized from phase pure BFO nanoparticles ( d ¯ ≈ 10 n m ). Microwave sintering resulted in reducing the sintering time substantially (by 1h), and has resulted in submicron sized grains and high resistivity ˜1.8 GΩ-cm. The AC conductivity is seen to follow the Jonscher's power law behavior, suggesting correlated barrier hopping (CBH) mechanism in the sample. The role of oxygen vacancies at high temperature, due to volatility of bismuth, in dielectric and conductivity behavior is also discussed. Further, the sample displayed dielectric anomaly near magnetic transition temperature (˜180 °C) indicating bearing of magnetic moments on the dielectric properties. Using Impedance Spectroscopy (IS) we have established, the electrical heterogeneity of the ceramic BFO reavealing semiconducting nature of grains and insulating nature of grain boundary. This, formation of network of insulating grain boundaries and semiconducting grains could lead to formation of internal barrier layer capacitance (IBLC) leading to high dielectric constant in microwave sintered BFO.

  1. Task 1: Modeling Study of CO Effects on Polymer Electrolyte Fuel Cell Anodes Task 2: Study of Ac Impedance as Membrane/Electrode Manufacturing Diagnostic Tool

    SciTech Connect

    Thomas E. Springer

    1998-01-30

    Carbon monoxide poisoning of polymer electrolyte fuel cell anodes is a key problem to be overcome when operating a polymer electrolyte fuel cell (PEFC) on reformed fuels. CO adsorbs preferentially on the precious metal surface leading to substantial performance losses. Some recent work has explored this problem, primarily using various Pt alloys in attempts to lower the degree of surface deactivation. In their studies of hydrogen oxidation on Pt and Pt alloy (Pt/Sn, Pt/Ru) rotating disk electrodes exposed to H{sub 2}/CO mixtures, Gasteiger et al. showed that a small hydrogen oxidation current is observed well before the onset of major CO oxidative stripping (ca. 0.4 V) on Pt/Ru. However, these workers concluded that such current observed at low anode overpotentials was too low to be of practical value. Nonetheless, MST-11 researchers and others have found experimentally that it is possible to run a PEFC, e.g., with a Pt/Ru anode, in the presence of CO levels in the range 10--100 ppm with little voltage loss. Such experimental results suggest that, in fact, PEFC operation at significant current densities under low anode overpotentials is possible in the presence of such levels of CO, even before resorting to air bleeding into the anode feed stream. The latter approach has been shown to be effective in elimination of Pt anode catalyst poisoning effects at CO levels of 20--50 ppm for cells operating at 80 C with low Pt catalyst loading. The effect of oxygen bleeding is basically to lower P{sub CO} down to extremely low levels in the anode plenum thanks to the catalytic (chemical) oxidation of CO by dioxygen at the anode catalyst. In this modeling work the authors do not include specific description of oxygen bleeding effects and concentrate on the behavior of the anode with feed streams of H{sub 2} or reformate containing low levels of CO. The anode loss is treated in this work as a hydrogen and carbon monoxide electrode kinetics problem, but includes the effects of

  2. A study of optothermal and AC impedance properties of Cr-doped Mn{sub 3}O{sub 4} sprayed thin films

    SciTech Connect

    Larbi, T.; Amara, A.; Ben Said, L.; Ouni, B.; Haj Lakhdar, M.; Amlouk, M.

    2015-10-15

    Highlights: • Outlining adequacy an original combination of several characterization means. • Structural, optical, thermal and electrical properties have been studied. • Opto- thermal analysis shows that band gap can be tuned through Cr doping. • Outlining physical properties for an eventual development of sensing components. - Abstract: Chrome-doped Mn{sub 3}O{sub 4} thin films were grown on the glass substrates by the spray pyrolysis technique at 350 °C. XRD diffraction and Raman spectroscopy analysis revealed that all samples have tetragonal spinel structure with a preferred orientation along the direction (1 0 1). Absorption coefficient has been measured using both transmission and mirage effect. The band gap energy decreases from 2.2 to 1.9 eV with Cr content while Urbach energy value increases from 354 to 473 meV. Also, thermal conductivity was evaluated. Finally, physical properties have been evaluated and discussed in terms of alteration of the band gap edges, electrical patterns and mirage effect.

  3. Study of Influence of Electrode Geometry on Impedance Spectroscopy

    SciTech Connect

    Ahmed, Riaz; Reifsnider, Kenneth L

    2011-01-01

    Electrochemical Impedance Spectroscopy (EIS) is a powerful and proven tool for analyzing AC impedance response. A conventional three electrode EIS method was used to perform the investigation in the present study. Saturated potassium chloride solution was used as the electrolyte and three different material rods were used as working electrodes. Different configurations of electrode area were exposed to the electrolyte as an active area to investigate electrode geometry effects. Counter to working electrode distance was also altered while keeping the working electrode effective area constant to explore the AC response dependence on the variation of ion travel distance. Some controlled experiments were done to validate the experimental setup and to provide a control condition for comparison with experimental results. A frequency range of 100 mHz to 1 MHz was used for all experiments. In our analysis, we have found a noteworthy influence of electrode geometry on AC impedance response. For all electrodes, impedance decreases with the increase of effective area of the electrolyte. High frequency impedance is not as dependent on geometry as low frequency response. The observed phase shift angle drops in the high frequency region with increased working electrode area, whereas at low frequency the reverse is true. Resistance and capacitive reactance both decrease with an increase of area, but resistance response is more pronounce than reactance. For lower frequencies, small changes in working area produce very distinctive EIS variations. Electrode material as well as geometry was systematically varied in the present study. From these and other studies, we hope to develop a fundamental foundation for understanding specific changes in local geometry in fuel cell (and other) electrodes as a method of designing local morphology for specific performance.

  4. Evaluation of the electrode performance for PAFC by using acid absorption, acceleration and ac-impedance measurement

    SciTech Connect

    Kim, Chang-Soo; Song, Rak-Hyun; Choi, Byung-Woo

    1996-12-31

    In PAFC, the degradation on cathode electrode caused by carbon corrosion, platinum dissolution and growth is especially severe. An acceleration test is a good technique for evaluating the degradation of electrode performance, because it does not need long time. Coleman et al used thermal cycling and on-off cycling as an acceleration test. Song et al showed that hydrogen shortage decreased the electrode performance more rapidly than that of air shortage in gas shortage test. Honji et al reported that the rate of coarsening of Pt particle is rapid in open circuit potential and this is one of major causes on the performance degradation of electrode. The cathode performance has been studied by using acid absorption, acceleration and ac-impedance measurements as functions of the polytetrafluoroethylene (PTFE) contents and sintering temperatures of the electrode.

  5. Impedance microflow cytometry for viability studies of microorganisms

    NASA Astrophysics Data System (ADS)

    Di Berardino, Marco; Hebeisen, Monika; Hessler, Thomas; Ziswiler, Adrian; Largiadèr, Stephanie; Schade, Grit

    2011-02-01

    Impedance-based Coulter counters and its derivatives are widely used cell analysis tools in many laboratories and use normally DC or low frequency AC to perform these electrical analyses. The emergence of micro-fabrication technologies in the last decade, however, provides a new means of measuring electrical properties of cells. Microfluidic approaches combined with impedance spectroscopy measurements in the radio frequency (RF) range increase sensitivity and information content and thus push single cell analyses beyond simple cell counting and sizing applications towards multiparametric cell characterization. Promising results have been shown already in the fields of cell differentiation and blood analysis. Here we emphasize the potential of this technology by presenting new data obtained from viability studies on microorganisms. Impedance measurements of several yeast and bacteria strains performed at frequencies around 10 MHz enable an easy discrimination between dead and viable cells. Moreover, cytotoxic effects of antibiotics and other reagents, as well as cell starvation can also be monitored easily. Control analyses performed with conventional flow cytometers using various fluorescent dyes (propidium iodide, oxonol) indicate a good correlation and further highlight the capability of this device. The label-free approach makes on the one hand the use of usually expensive fluorochromes obsolete, on the other hand practically eliminates laborious sample preparation procedures. Until now, online cell monitoring was limited to the determination of viable biomass, which provides rather poor information of a cell culture. Impedance microflow cytometry, besides other aspects, proposes a simple solution to these limitations and might become an important tool for bioprocess monitoring applications in the biotech industry.

  6. Determination of the Si-conducting polymer interfacial properties using A-C impedance techniques

    NASA Technical Reports Server (NTRS)

    Nagasubramanian, G.; Di Stefano, Salvador; Moacanin, Jovan

    1985-01-01

    A study was made of the interfacial properties of poly(pyrrole) (PP) deposited electrochemically onto single crystal p-Si surfaces. The interfacial properties are dependent upon the counterions. The formation of 'quasi-ohmic' and 'nonohmic' contacts, respectively, of PP(ClO4) and PP films doped with other counterions (BF4 and para-toluene sulfonate) with p-Si, are explained in terms of the conductivity of these films and the flat band potential, V(fb), of PP relative to that of p-Si. The PP film seems to passivate or block intrinsic surface states present on the p-Si surface. The differences in the impedance behavior of para-toluene sulfonate doped and ClO4 doped PP are compared.

  7. Corrosion Study Using Electrochemical Impedance Spectroscopy

    NASA Technical Reports Server (NTRS)

    Farooq, Muhammad Umar

    2003-01-01

    Corrosion is a common phenomenon. It is the destructive result of chemical reaction between a metal or metal alloy and its environment. Stainless steel tubing is used at Kennedy Space Center for various supply lines which service the orbiter. The launch pads are also made of stainless steel. The environment at the launch site has very high chloride content due to the proximity to the Atlantic Ocean. Also, during a launch, the exhaust products in the solid rocket boosters include concentrated hydrogen chloride. The purpose of this project was to study various alloys by Electrochemical Impedance Spectroscopy in corrosive environments similar to the launch sites. This report includes data and analysis of the measurements for 304L, 254SMO and AL-6XN in primarily neutral 3.55% NaCl. One set of data for 304L in neutral 3.55%NaCl + 0.1N HCl is also included.

  8. Label-free whole blood cell differentiation based on multiple frequency AC impedance and light scattering analysis in a micro flow cytometer.

    PubMed

    Simon, Peter; Frankowski, Marcin; Bock, Nicole; Neukammer, Jörg

    2016-06-21

    We developed a microfluidic sensor for label-free flow cytometric cell differentiation by combined multiple AC electrical impedance and light scattering analysis. The measured signals are correlated to cell volume, membrane capacity and optical properties of single cells. For an improved signal to noise ratio, the microfluidic sensor incorporates two electrode pairs for differential impedance detection. One-dimensional sheath flow focusing was implemented, which allows single particle analysis at kHz count rates. Various monodisperse particles and differentiation of leukocytes in haemolysed samples served to benchmark the microdevice applying combined AC impedance and side scatter analyses. In what follows, we demonstrate that AC impedance measurements at selected frequencies allow label-free discrimination of platelets, erythrocytes, monocytes, granulocytes and lymphocytes in whole blood samples involving dilution only. Immunofluorescence staining was applied to validate the results of the label-free cell analysis. Reliable differentiation and enumeration of cells in whole blood by AC impedance detection have the potential to support medical diagnosis for patients with haemolysis resistant erythrocytes or abnormally sensitive leucocytes, i.e. for patients suffering from anaemia or leukaemia.

  9. [Experimental study on electrical impedance properties of human hepatoma cells].

    PubMed

    Fang, Yun; Tang, Zhiyuan; Zhang, Qian; Zhao, Xin; Ma, Qing

    2014-10-01

    The AC impedance of human hepatoma SMMC-7721 cells were measured in our laboratory by Agilent 4294A impedance analyzer in the frequency range of 0.01-100 MHz. And then the effect of hematocrit on electrical impedance characteristics of hepatoma cells was observed by electrical impedance spectroscopy, Bode diagram, Nyquist diagram and Nichols diagram. The results showed that firstly, there is a frequency dependence, i.e., the increment of real part and the imaginary part of complex electrical impedance (δZ', δZ"), the increment of the amplitude modulus of complex electrical impedance (δ[Z *]) and phase angle (δθ) were all changed with the increasing frequency. Secondly, it showed cell volume fraction (CVF) dependence, i. e. , the increment of low-frequency limit (δZ'0, δ[Z*] 0), peak (δZ"(p), δθ(p)), area and radius (Nyquist diagram, Nichols diagram) were all increased along with the electric field frequency. Thirdly, there was the presence of two characteristic frequencies: the first characteristic frequency (f(c1)) and the second characteristic frequency (f(c2)), which were originated respectively in the polarization effects of two interfaces that the cell membrane and extracellular fluid, cell membrane and cytoplasm. A conclusion can be drawn that the electrical impedance spectroscopy is able to be used to observe the electrical characteristics of human hepatoma cells, and therefore this method can be used to investigate the electrophysiological mechanisms of liver cancer cells, and provide research tools and observation parameters, and it also has important theoretical value and potential applications for screening anticancer drugs. PMID:25764724

  10. Impedance and modulus spectroscopic study of nano hydroxyapatite

    NASA Astrophysics Data System (ADS)

    Jogiya, B. V.; Jethava, H. O.; Tank, K. P.; Raviya, V. R.; Joshi, M. J.

    2016-05-01

    Hydroxyapatite (Ca10 (PO4)6 (OH)2, HAP) is the main inorganic component of the hard tissues in bones and also important material for orthopedic and dental implant applications. Nano HAP is of great interest due to its various bio-medical applications. In the present work the nano HAP was synthesized by using surfactant mediated approach. Structure and morphology of the synthesized nano HAP was examined by the Powder XRD and TEM. Impedance study was carried out on pelletized sample in a frequency range of 100Hz to 20MHz at room temperature. The variation of dielectric constant, dielectric loss, and a.c. conductivity with frequency of applied field was studied. The Nyquist plot as well as modulus plot was drawn. The Nyquist plot showed two semicircle arcs, which indicated the presence of grain and grain boundary effect in the sample. The typical behavior of the Nyquist plot was represented by equivalent circuit having two parallel RC combinations in series.

  11. Synthesis, dielectric behavior and impedance measurement studies of Cr-substituted Zn-Mn ferrites

    SciTech Connect

    Hankare, P.P.; Patil, R.P.; Garadkar, K.M.; Sasikala, R.; Chougule, B.K.

    2011-03-15

    Graphical abstract: Variation of dielectric constant with frequency. Research highlights: {yields} Sol-gel route synthesized spherical crystalline nanoparticles of ZnMn{sub 1-x}Cr{sub x}FeO{sub 4}. {yields} XRD, DTA, FTIR, SEM, dielectric and impedance study. {yields} The ferrites show concentration dependence of ac electrical conductivity. {yields} Impedance response is dominated by grain boundary behavior. -- Abstract: Nanocrystalline ZnMn{sub 1-x}Cr{sub x}FeO{sub 4} (1.0 {>=} x {>=} 0) ferrites were synthesized by sol-gel technique. X-ray diffraction (XRD) confirmed the formation of single phasic cubic spinel lattice for all the compositions studied. Lattice parameter shows a decreasing trend with an increase in Cr content in the compositions. Formation of spherical nanoparticles was revealed by scanning electron microscopy (SEM) analysis. Infrared spectroscopic studies revealed two main absorption bands in the range 400-800 cm{sup -1} arising due to tetrahedral (A) and octahedral (B) site vibrations. Dielectric constant, dielectric loss tangent, ac conductivity and complex impedance were measured as a function of frequency in the range 20 Hz to 1 MHz. Frequency dependence of dielectric constant shows dielectric dispersion due to the Maxwell-Wagner type of interfacial polarization. The role of chromium in modifying structural and dielectric properties of these ferrites has been explained.

  12. Dielectric and impedance spectroscopic studies of neodymium gallate

    NASA Astrophysics Data System (ADS)

    Sakhya, Anup Pradhan; Dutta, Alo; Sinha, T. P.

    2016-05-01

    The AC electrical properties of a polycrystalline neodymium gallate, NdGaO3 (NGO), synthesized by the sol-gel method have been investigated by employing impedance spectroscopy in the frequency range from 42 Hz to 5 MHz and in the temperature range from 323 K to 593 K. The X-ray diffraction analysis shows that the compound crystallizes in the orthorhombic phase with Pbnm space group at room temperature. Two relaxation processes with different relaxation times are observed from the impedance as well as modulus spectroscopic measurements, which have been attributed to the grain and the grain boundary effects at different temperatures in NGO. The complex impedance data are analyzed by an electrical equivalent circuit consisting of a resistance and a constant phase element in parallel. It has been observed that the value of the capacitance and the resistance associated with the grain boundary is higher than those associated with the grain. The temperature dependent electrical conductivity shows the negative temperature coefficient of resistance. The frequency dependent conductivity spectra are found to follow the power law.

  13. Characterization of protein-immobilized polystyrene nanoparticles using impedance spectroscopy.

    PubMed

    Park, Soo-In; Lee, Sang-Yup

    2014-10-01

    A novel approach for characterization of non-conductive protein-immobilized nanoparticles using AC impedance spectroscopy combined with conductive atomic force microscopy was examined. As AC impedance spectroscopy can provide information on diverse electrical properties such as capacitance and inductance, it is applicable to the characterization of non-conductive substances. Several non-conductive protein-immobilized polystyrene nanoparticles were analyzed using AC impedance spectroscopy, and their impedance spectra were used as markers for nanoparticle identification. Analyses of impedance signals using an electrical circuit model established that the capacitance and inductance of each nanoparticle changed with the adsorbed protein and that impedance spectral differences were characteristic properties of the proteins. From this study, AC impedance spectroscopy was shown to be a useful tool for characterization of non-conductive nanoparticles and is expected to be applicable to the development of sensors for nanomaterials. PMID:25942903

  14. Study of AC/RF properties of SRF ingot niobium

    SciTech Connect

    Dhakal, Pashupati; Tsindlekht, Menachem I; Genkin, Valery M; Ciovati, Gianluigi; Myneni, Ganapati Rao

    2013-09-01

    In an attempt to correlate the performance of superconducting radiofrequency cavities made of niobium with the superconducting properties, we present the results of the magnetization and ac susceptibility of the niobium used in the superconducting radiofrequency cavity fabrication. The samples were subjected to buffer chemical polishing (BCP) surface and high temperature heat treatments, typically applied to the cavities fabrications. The analysis of the results show the different surface and bulk ac conductivity for the samples subjected to BCP and heat treatment. Furthermore, the RF surface impedance is measured on the sample using a TE011 microwave cavity for a comparison to the low frequency measurements.

  15. AC conductivity and Dielectric Study of Chalcogenide Glasses of Se-Te-Ge System

    NASA Astrophysics Data System (ADS)

    Salman, Fathy

    2004-01-01

    The ac conductivity and dielectric properties of glassy system SexTe79 - xGe21, with x = 11, 14, 17 at.%, has been studied at temperatures 300 to 450 K and over a wide range of frequencies (50 Hz to 500 kHz). Experimental results indicate that the ac conductivity and the dielectric constants depend on temperature, frequency and Se content. The conductivity as a function of frequency exhibited two components: dc conductivity s dc, and ac conductivity s ac, where s ac ˜ w s. The mechanism of ac conductivity can be reasonably interpreted in terms of the correlated barrier hopping model (CBH). The activation energies are estimated and discussed. The dependence of ac conductivity and dielectric constants on the Se content x can be interpreted as the effect of Se fraction on the positional disorder. The impedance plot at each temperature appeared as a semicircle passes through the origin. Each semicircle is represented by an equivalent circuit of parallel resistance Rb and capacitance Cb.

  16. Studies of deionization and impedance spectroscopy for blood analyzer

    NASA Astrophysics Data System (ADS)

    Kwong, Charlotte C.; Li, Nan; Ho, Chih-Ming

    2005-11-01

    Blood analysis provides vital information for health conditions. For instance, typical infection response is correlated to an elevated White Blood Cell (WBC) count, while low Red Blood Cell (RBC) count, hemoglobin and hematocrit are caused by anemia or internal bleeding. We are developing two essential modules, deionization (DI) chip and microfluidic cytometer with impedance spectroscopy flow, for enabling the realization of a single platform miniaturized blood analyzer. In the proposed analyzer, blood cells are preliminarily sorted by Dielectrophoretic (DEP) means into sub-groups, differentiated and counted by impedance spectroscopy in a flow cytometer. DEP techniques have been demonstrated to stretch DNA, align Carbon Nanotubes (CNT) and trap cells successfully. However, DEP manipulation does not function in biological media with high conductivity. The DI module is designed to account for this challenge. H Filter will serve as an ion extraction platform in a microchamber. Sample and buffer do not mix well in micro scale allowing the ions being extracted by diffusion without increasing the volume. This can keep the downstream processing time short. Micro scale hydrodynamic focusing is employed to place single cell passing along the central plane of the flow cytometer module. By applying an AC electrical field, suspended cells are polarized, membrane capacitance C m, cytoplasm conductivity σ c, and cytoplasm permittivity ɛ c will vary as functions of frequency. Tracing back the monitored current, the numbers of individual cell species can be evaluated.

  17. Mapping Electrochemical Heterogeneity at Iron Oxide Surfaces: A Local Electrochemical Impedance Study.

    PubMed

    Lucas, Marie; Boily, Jean-François

    2015-12-22

    Alternating current scanning electrochemical microscopy (AC-SECM) was used for the first time to map key electrochemical attributes of oriented hematite (α-Fe2O3) single crystal surfaces at the micron-scale. Localized electrochemical impedance spectra (LEIS) of the (001) and (012) faces provided insight into the spatial variations of local double layer capacitance (C(dl)) and charge transfer resistance (R(ad)). These parameters were extracted by LEIS measurements in the 0.4-8000 Hz range to probe the impedance response generated by the redistribution of water molecules and charge carriers (ions) under an applied AC. These were attributed to local variations in the local conductivity of the sample surfaces. Comparison with global EIS measurements on the same samples uncovered highly comparable frequency-resolved processes, that were broken down into contributions from the bulk hematite, the interface as well as the microelectrode/tip assembly. This work paves the way for new studies aimed at mapping electrochemical processes at the mesoscale on this environmentally and technologically important material.

  18. Computational Study on the Steady-state Impedance of Saturated-core Superconducting Fault Current Limiter

    NASA Astrophysics Data System (ADS)

    Zhang, C.; Tang, Y.; Liang, S.; Ren, L.; Wang, Z.; Xu, Y.

    This paper presents the electromagnetic analysis of a high voltage saturated-core superconducting fault current limiter (SCSFCL). The numerical analyses of a three-dimensional (3D) model is shown, and the specific parameters are given. The model focus on the steady-state impedance of the limiter when connected to the power grid. It analyzed the dependence of steady-state impedance on the AC coil current, and the relationship between oil gap and coil inductance. The results suggest that, adding oil gap between slice of silicon steel can reduce the core cross-section, restrain the ultraharmonic and decrease the steady-state impedance. As the core cross-section of AC limb decreased from 4344 cm2 to 3983 cm2, the total harmonic distortion for voltage decreased from 2.4% to 1.8%, and the impedance decreased from 1.082 Ω to 1.069 Ω(Idc=400A,Iac=1296A).

  19. Potassium polytitanate gas-sensor study by impedance spectroscopy.

    PubMed

    Fedorov, F S; Varezhnikov, A S; Kiselev, I; Kolesnichenko, V V; Burmistrov, I N; Sommer, M; Fuchs, D; Kübel, C; Gorokhovsky, A V; Sysoev, V V

    2015-10-15

    Nanocrystalline potassium polytitanates K2O·nTiO2·mH2O represent a new type of semiconducting compounds which are characterized by a high specific surface that makes them promising for use in gas sensors. In this work, we have studied potassium polytitanate mesoporous nanoparticle agglomerates placed over a SiO2/Si substrate equipped with multiple coplanar electrodes to measure the electrical response to various organic vapors, 1000 ppm of concentration, mixed with air by impedance spectrometry in range of the 10(-2)-10(6) Hz. The recorded impedance data for each sensor segment are associated with RC components of an equivalent circuit which are applied to selectively recognize the test vapors exploiting a "multisensor array" approach. PMID:26515008

  20. Study of dielectric and impedance properties of Mn ferrites

    NASA Astrophysics Data System (ADS)

    Mujasam Batoo, Khalid

    2011-02-01

    The paper reports on the effect of Al substitution on the structural and electrical properties of bulk ferrite series of basic composition MnFe 2-2 xAl 2 xO 4 (0.0≤ x≤0.5) synthesized using solid state reaction method. XRD analysis confirms that all the samples exhibit single phase cubic spinel structure excluding presence of any secondary phase. The dielectric constant shows a normal behaviour with frequency, whereas the loss tangent exhibits an anomalous behaviour with frequency for all compositions. Variation of dielectric properties and ac conductivity with frequency reveals that the dispersion is due to Maxwell-Wagner type of interfacial polarization in general and hopping of charge between Fe +2 and Fe +3 as well as between Mn +2 and Mn +3 ions at octahedral sites. The complex impedance plane spectra shows the presence of two semicircles up to x=0.2, and only one semicircle for the higher values of x. The analysis of the data shows that the resistive and capacitive properties of the Mn ferrite are mainly due to processes associated with grain and grain boundaries.

  1. Study of surfactant-skin interactions by skin impedance measurements.

    PubMed

    Lu, Guojin; Moore, David J

    2012-02-01

    The stratum corneum (SC) plays a very critical physiological role as skin barrier in regulating water loss through the skin and protects the body from a wide range of physical and chemical exogenous insults. Surfactant-containing formulations can induce skin damage and irritation owing to surfactant absorption and penetration. It is generally accepted that reduction in skin barrier properties occurs only after surfactants have penetrated/permeated into the skin barrier. To mitigate the harshness of surfactant-based cleansing products, penetration/permeation of surfactants should be reduced. Skin impedance measurements have been taken in vitro on porcine skin using vertical Franz diffusion cells to investigate the impact of surfactants, temperature and pH on skin barrier integrity. These skin impedance results demonstrate excellent correlation with other published methods for assessing skin damage and irritation from different surfactant chemistry, concentration, pH, time of exposure and temperature. This study demonstrates that skin impedance can be utilized as a routine approach to screen surfactant-containing formulations for their propensity to compromise the skin barrier and hence likely lead to skin irritation. PMID:21923733

  2. Study of surfactant-skin interactions by skin impedance measurements.

    PubMed

    Lu, Guojin; Moore, David J

    2012-02-01

    The stratum corneum (SC) plays a very critical physiological role as skin barrier in regulating water loss through the skin and protects the body from a wide range of physical and chemical exogenous insults. Surfactant-containing formulations can induce skin damage and irritation owing to surfactant absorption and penetration. It is generally accepted that reduction in skin barrier properties occurs only after surfactants have penetrated/permeated into the skin barrier. To mitigate the harshness of surfactant-based cleansing products, penetration/permeation of surfactants should be reduced. Skin impedance measurements have been taken in vitro on porcine skin using vertical Franz diffusion cells to investigate the impact of surfactants, temperature and pH on skin barrier integrity. These skin impedance results demonstrate excellent correlation with other published methods for assessing skin damage and irritation from different surfactant chemistry, concentration, pH, time of exposure and temperature. This study demonstrates that skin impedance can be utilized as a routine approach to screen surfactant-containing formulations for their propensity to compromise the skin barrier and hence likely lead to skin irritation.

  3. The investigation of dielectric properties and ac conductivity of new ceramic diphosphate Ag0.6Na0.4FeP2O7 using impedance spectroscopy method

    NASA Astrophysics Data System (ADS)

    Nasri, S.; Megdiche, M.; Gargouri, M.

    2016-10-01

    In this paper, Ag0.6Na0.4FeP2O7 has been synthesized by solid state reaction method. The ceramic compound was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrational spectroscopy and impedance measurements. In fact, the investigated sample has shown single phase type monoclinic structure with P21/C space group. The frequency-dependent electrical data are analyzed in the frame-work of conductivity and electric modulus formalisms. The real and imaginary parts of complex impedance are well fitted to equivalent circuit model based on the Z-View-software. Besides, the observed frequency dependence of conductivity is found to obey Jonscher's universal law. The temperature dependence of both ac conductivity and the parameter s is reasonably well interpreted by the correlated barrier hopping (CBH). The theoretical fitting between the proposed model and the experimental data showed good agreement. The contribution of single polaron and bipolaron hopping to a.c. conductivity in present compound is also studied. The ionic conductivity is discussed on the basis of the structural characteristics of the sample.

  4. Impedance studies of a green blend polymer electrolyte based on PVA and Aloe-vera

    NASA Astrophysics Data System (ADS)

    Selvalakshmi, S.; Mathavan, T.; Vijaya, N.; Selvasekarapandian, Premalatha, M.; Monisha, S.

    2016-05-01

    The development of polymer electrolyte materials for energy generating and energy storage devices is a challenge today. A new type of blended green electrolyte based on Poly-vinyl alcohol (PVA) and Aloe-vera has been prepared by solution casting technique. The blending of polymers may lead to the increase in stability due to one polymer portraying itself as a mechanical stiffener and the other as a gelled matrix supported by the other. The prepared blend electrolytes were subjected to Ac impedance studies. It has been found out that the polymer film in which 1 gm of PVA was dissolved in 40 ml of Aloe-vera extract exhibits highest conductivity and its value is 3.08 × 10-4 S cm-1.

  5. AC Conductivity Studies in Lithium-Borate Glass Containing Gold Nanoparticles

    NASA Astrophysics Data System (ADS)

    Shivaprakash, Y.; Anavekar, R. V.

    2011-07-01

    Gold nanoparticles have been synthesized in a base glass with composition 30Li2O-70B2O3 using gold chloride (HAuCl4.3H2O) as a dopant. The samples are characterized using XRD, ESR, SEM and optical absorption in the visible range. AC conductivity studies have been performed at RT over a frequency range 100 to 10 MHz. The dc conductivity is calculated from the complex impedence plot. The dc conductivity is found to be increasing with the increase of dopant concentration. AC conductivity data is fitted with Almond-West law with power exponent `s'. The values of `s' is found to lie in the range of 0.70-0.73.

  6. Pore Characteristics of Chitosan Scaffolds Studied by Electrochemical Impedance Spectroscopy

    PubMed Central

    Tully-Dartez, Stephanie; Cardenas, Henry E.

    2010-01-01

    In this study, a novel approach, electrochemical impedance spectroscopy (EIS), was used to examine the pore characteristics of chitosan scaffolds under aqueous conditions. The EIS was run with a constant current of 0.1 mA with the frequency sweep of 106 to 10−4 Hz. The resulting complex impedance measurement was then used to calculate porosity, which was determined to be 71%. Scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP), two commonly used methods for scaffold characterization, were used to independently evaluate the pore characteristics and compare with that of EIS. The SEM and MIP were performed and analyzed under standard conditions. The pore diameter values found by SEM and MIP are 107 μm and 82 μm, respectively, indicating that both the image-based (SEM) and pressure-based (MIP) analyses provide similar results. The porosity of 73% calculated by MIP is comparable to that of EIS. From these results, it can be suggested that EIS, a relatively nondestructive test, is able to obtain comparable data on pore characteristics, as compared to SEM and MIP. The advantage of the EIS as an nondestructive test is that it can be performed under physiologically relevant conditions, whereas SEM and MIP require dry samples and vacuum conditions for measurement. These benefits make EIS a viable option for the characterization and long-term observation of tissue-engineered scaffolds. PMID:19580421

  7. Ambulatory impedance cardiography in hypertension: a validation study.

    PubMed

    McFetridge-Durdle, Judith A; Routledge, Faye S; Parry, Monica J E; Dean, C R T; Tucker, B

    2008-09-01

    The management of hypertension is improved by knowledge of the hemodynamics underlying blood pressure. Impedance Cardiography (ICG) provides data on a range of hemodynamic variables that affect blood pressure. However, ICG captures only fixed descriptions of hemodynamic characteristics. Improvements in ambulatory technology have led to the development of the Ambulatory Impedance Monitor (AIM) which records hemodynamic data during the activities of daily living. The purpose of this study was to evaluate the sensitivity of the AIM to detect hemodynamic changes associated with postural shift in persons with hypertension. Using a repeated measures cross-over design, sitting and standing hemodynamic measures were taken in seventeen persons with hypertension while wearing the AIM-BpTRU system designed for standard office use and the AIM-Spacelabs system designed for ambulatory monitoring. Both AIM-blood pressure monitoring systems detected significant changes from sitting to standing posture in heart rate (p=0.03), stroke volume (p=0.002), left ventricular ejection time (p<0.001), systemic vascular resistance (p=0.03) and diastolic blood pressure (p<0.001). Additionally, both systems generated measures of cardiac function that were positively correlated (p<0.001) and not significantly different (p>0.05). Our findings support previous work and demonstrate that the AIM provides valid and reliable estimates of cardiac function in persons with hypertension. PMID:18234557

  8. Electrochemical impedance spectroscopy study on corrosion inhibition of benzyltriethylammonium chloride

    NASA Astrophysics Data System (ADS)

    Idris, Mohd Nazri; Daud, Abdul Razak; Othman, Norinsan Kamil

    2013-11-01

    Electrochemical Impedance Spectroscopy (EIS) was employed to study the corrosion inhibition behavior of benzyltriethylammonium chloride (BTC) for carbon steel corrosion. The inhibition efficiency was investigated in 1.0 M HCl solution at room temperature (25°C) by varying the BTC concentration. EIS results indicated that the double layer capacitance of electrolyte/carbon steel interface decreases with the increasing of BTC concentration and consequently enhances the polarization resistance of equivalence Randles circuit. The results indicated that inhibition efficiency of as high as 65% could be achieved when 10mM BTC was present in 1.0 M HCl solution as compared to inhibitor-free solution. The inhibition process of BTC on the carbon steel corrosion was found to obey Langmuir adsorption isotherm. This study revealed that BTC is suitable to be used as a corrosion inhibitor in acid media.

  9. Study of impedance spectra for dry and wet EarEEG electrodes.

    PubMed

    Kappel, Simon L; Kidmose, Preben

    2015-01-01

    EarEEG is a novel recordings concept where electrodes are embedded on the surface of an earpiece customized to the individual anatomical shape of the users ear. A key parameter for recording EEG signals of good quality is a stable and low impedance electrode-body interface. This study characterizes the impedance for dry and wet EarEEG electrodes in a study of 10 subjects. A custom made and automated setup was used to characterize the impedance spectrum from 0.1 Hz-2 kHz. The study of dry electrodes showed a mean (standard deviation) low frequency impedance of the canal electrodes of 1.2 MΩ (1.4 MΩ) and the high frequency impedance was 230 kΩ (220 kΩ). For wet electrodes the low frequency impedance was 34 kΩ (37 kΩ) and the high frequency impedance was 5.1 kΩ (4.4 kΩ). The high standard deviation of the impedance for dry electrodes imposes very high requirements for the input impedance of the amplifier in order to achieve an acceptable common-mode rejection. The wet electrode impedance was in line with what is typical for a wet electrode interface.

  10. Measurement uncertainty in pulmonary vascular input impedance and characteristic impedance estimated from pulsed-wave Doppler ultrasound and pressure: clinical studies on 57 pediatric patients.

    PubMed

    Tian, Lian; Hunter, Kendall S; Kirby, K Scott; Ivy, D Dunbar; Shandas, Robin

    2010-06-01

    Pulmonary vascular input impedance better characterizes right ventricular (RV) afterload and disease outcomes in pulmonary hypertension compared to the standard clinical diagnostic, pulmonary vascular resistance (PVR). Early efforts to measure impedance were not routine, involving open-chest measurement. Recently, the use of pulsed-wave (PW) Doppler-measured velocity to non-invasively estimate instantaneous flow has made impedance measurement more practical. One critical concern remains with clinical use: the measurement uncertainty, especially since previous studies only incorporated random error. This study utilized data from a large pediatric patient population to comprehensively examine the systematic and random error contributions to the total impedance uncertainty and determined the least error prone methodology to compute impedance from among four different methods. We found that the systematic error contributes greatly to the total uncertainty and that one of the four methods had significantly smaller propagated uncertainty; however, even when this best method is used, the uncertainty can be large for input impedance at high harmonics and for the characteristic impedance modulus. Finally, we found that uncertainty in impedance between normotensive and hypertensive patient groups displays no significant difference. It is concluded that clinical impedance measurement would be most improved by advancements in instrumentation, and the best computation method is proposed for future clinical use of the input impedance.

  11. Structural and AC conductivity study of CdTe nanomaterials

    NASA Astrophysics Data System (ADS)

    Das, Sayantani; Banerjee, Sourish; Sinha, T. P.

    2016-04-01

    Cadmium telluride (CdTe) nanomaterials have been synthesized by soft chemical route using mercapto ethanol as a capping agent. Crystallization temperature of the sample is investigated using differential scanning calorimeter. X-ray diffraction and transmission electron microscope measurements show that the prepared sample belongs to cubic structure with the average particle size of 20 nm. Impedance spectroscopy is applied to investigate the dielectric relaxation of the sample in a temperature range from 313 to 593 K and in a frequency range from 42 Hz to 1.1 MHz. The complex impedance plane plot has been analyzed by an equivalent circuit consisting of two serially connected R-CPE units, each containing a resistance (R) and a constant phase element (CPE). Dielectric relaxation peaks are observed in the imaginary parts of the spectra. The frequency dependence of real and imaginary parts of dielectric permittivity is analyzed using modified Cole-Cole equation. The temperature dependence relaxation time is found to obey the Arrhenius law having activation energy ~0.704 eV. The frequency dependent conductivity spectra are found to follow the power law. The frequency dependence ac conductivity is analyzed by power law.

  12. Carbon Nanotube-Based Supercapacitors with Excellent ac Line Filtering and Rate Capability via Improved Interfacial Impedance.

    PubMed

    Rangom, Yverick; Tang, Xiaowu Shirley; Nazar, Linda F

    2015-07-28

    We report the fabrication of high-performance, self-standing composite sp(2)-carbon supercapacitor electrodes using single-walled carbon nanotubes (CNTs) as conductive binder. The 3-D mesoporous mesh architecture of CNT-based composite electrodes grants unimpaired ionic transport throughout relatively thick films and allows superior performance compared to graphene-based devices at an ac line frequency of 120 Hz. Metrics of 601 μF/cm(2) with a -81° phase angle and a rate capability (RC) time constant of 199 μs are obtained for thin carbon films. The free-standing carbon films were obtained from a chlorosulfonic acid dispersion and interfaced to stainless steel current collectors with various surface treatments. CNT electrodes were able to cycle at 200 V/s and beyond, still showing a characteristic parallelepipedic cyclic votammetry shape at 1 kV/s. Current densities are measured in excess of 6400 A/g, and the electrodes retain more than 98% capacity after 1 million cycles. These promising results are attributed to a reduction of series resistance in the film through the CNT conductive network and especially to the surface treatment of the stainless steel current collector. PMID:26046685

  13. Carbon Nanotube-Based Supercapacitors with Excellent ac Line Filtering and Rate Capability via Improved Interfacial Impedance.

    PubMed

    Rangom, Yverick; Tang, Xiaowu Shirley; Nazar, Linda F

    2015-07-28

    We report the fabrication of high-performance, self-standing composite sp(2)-carbon supercapacitor electrodes using single-walled carbon nanotubes (CNTs) as conductive binder. The 3-D mesoporous mesh architecture of CNT-based composite electrodes grants unimpaired ionic transport throughout relatively thick films and allows superior performance compared to graphene-based devices at an ac line frequency of 120 Hz. Metrics of 601 μF/cm(2) with a -81° phase angle and a rate capability (RC) time constant of 199 μs are obtained for thin carbon films. The free-standing carbon films were obtained from a chlorosulfonic acid dispersion and interfaced to stainless steel current collectors with various surface treatments. CNT electrodes were able to cycle at 200 V/s and beyond, still showing a characteristic parallelepipedic cyclic votammetry shape at 1 kV/s. Current densities are measured in excess of 6400 A/g, and the electrodes retain more than 98% capacity after 1 million cycles. These promising results are attributed to a reduction of series resistance in the film through the CNT conductive network and especially to the surface treatment of the stainless steel current collector.

  14. An impedance study on admiralty brass dezincification originated by microbiologically influenced corrosion.

    PubMed

    Ibars, J R; Polo, J L; Moreno, D A; Ranninger, C; Bastidas, J M

    2004-09-30

    In this article we describe a field study of biofouling and microbiologically influenced corrosion (MIC) of admiralty brass heat exchanger tubes in contact with running fresh water on the river Tagus close to Almaraz nuclear power plant in Spain. Dezincification originated by biofouling and MIC was studied using impedance, polarization resistance, gravimetric, scanning electron microscopy (SEM), and X-ray diffraction (XRD) measurements. Close correlation was observed between the biofilms formed and the corrosion process (dezincification) using the different experimental techniques. Impedance data showed a capacitive behavior including two time constants. Kramers-Kronig (KK) transforms were used to validate impedance data. The admiralty tubes' impedance data satisfied the KK relations.

  15. An impedance study on admiralty brass dezincification originated by microbiologically influenced corrosion.

    PubMed

    Ibars, J R; Polo, J L; Moreno, D A; Ranninger, C; Bastidas, J M

    2004-09-30

    In this article we describe a field study of biofouling and microbiologically influenced corrosion (MIC) of admiralty brass heat exchanger tubes in contact with running fresh water on the river Tagus close to Almaraz nuclear power plant in Spain. Dezincification originated by biofouling and MIC was studied using impedance, polarization resistance, gravimetric, scanning electron microscopy (SEM), and X-ray diffraction (XRD) measurements. Close correlation was observed between the biofilms formed and the corrosion process (dezincification) using the different experimental techniques. Impedance data showed a capacitive behavior including two time constants. Kramers-Kronig (KK) transforms were used to validate impedance data. The admiralty tubes' impedance data satisfied the KK relations. PMID:15334412

  16. Otosclerosis in a black child: diagnostic acoustic impedance studies.

    PubMed

    Schweitzer, V G; Lilly, D J

    1984-10-01

    Otosclerosis classically describes an osteodystrophic change in the bony labyrinth and stapes footplate, of autosomal dominant inheritance, reported rare under the age of 5, extremely "rare" in the Oriental and Black race, "non-existent" in the American Indian, and with a clinical incidence of 5 per 1000 Caucasians. The differential diagnosis of a non-effusion conductive hearing loss in a child should include otosclerosis, congenital malleus or footplate fixation, tympanosclerotic fixation, congenital cholesteatoma, lysis of the incus long process, Paget's disease, osteogenesis imperfecta, and fibromuscular hyperplasia of the renal artery. Presented is a case report of a 14-year-old black male with bilateral clinical otosclerosis and a persistent stapedial artery. Preoperative multiple-frequency tympanometry and Zwislocki acoustic reactance and resistance analysis demonstrated absence of the "W" resonance pattern on high-frequency tympanometry and the classic friction and stiffness patterns of otosclerotic fixation. Repeat multiple-frequency tympanometry testing post-stapedectomy demonstrated prosthesis articulation. Prosthesis position can be monitored postoperatively by these acoustic impedance studies. PMID:6500827

  17. Hygroscopic particle behavior studied by interdigitated array microelectrode impedance sensors.

    PubMed

    Schindelholz, Eric; Tsui, Lok-kun; Kelly, Robert G

    2014-01-01

    The hygroscopic behavior of soluble salts bears importance in many research fields including atmospheric sciences, corrosion, porous building materials, and pharmaceuticals. Several methods have been used to study deliquescence (solid to liquid) and efflorescence (liquid to solid) phase transitions of these salts. In this study, we measured the deliquescence and efflorescence RH values of single salt microparticles deposited on an interdigitated microelectrode sensor via electrical impedance. The salts examined were NaCl, LiCl, NaBr, KCl, and MgCl2. Measured values were in agreement with in situ optical microscopic observations and, with the exception of MgCl2, literature values. In the case of MgCl2, deliquescence occurred at 33% RH and 12-15% RH, with the latter range being previously unreported. The depressed deliquescence RH was hypothesized to be a result of the formation of a metastable MgCl2 hydrate. Incomplete efflorescence of MgCl2 was also observed after exposure to <1.5% RH for up to 22 h due to formation of solid shells which trapped fluid. The phenomena elucidated by these results provide an explanation for the anomalous water retention and uptake behavior of MgCl2 below 33% RH reported elsewhere in the literature. The results presented in this study validate the use of this method as an alternative or complementary method for study of bulk-phase transitions of substrate-deposited particles across a broad RH range. These findings also demonstrate the utility of this method for detection of fluid trapping which cannot be directly ascertained by gravimetric and line-of-sight techniques commonly used in the study of hygroscopic particles.

  18. AC impedance analysis of ionic and electronic conductivities in electrode mixture layers for an all-solid-state lithium-ion battery

    NASA Astrophysics Data System (ADS)

    Siroma, Zyun; Sato, Tomohiro; Takeuchi, Tomonari; Nagai, Ryo; Ota, Akira; Ioroi, Tsutomu

    2016-06-01

    The ionic and electronic effective conductivities of an electrode mixture layers for all-solid-state lithium-ion batteries containing Li2Ssbnd P2S5 as a solid electrolyte were investigated by AC impedance measurements and analysis using a transmission-line model (TLM). Samples containing graphite (graphite electrodes) or LiNi0.5Co0.2Mn0.3O2 (NCM electrodes) as the active material were measured under a "substrate | sample | bulk electrolyte | sample | substrate" configuration (ion-electron connection) and a "substrate | sample | substrate" configuration (electron-electron connection). Theoretically, if the electronic resistance is negligibly small, which is the case with our graphite electrodes, measurement with the ion-electron connection should be effective for evaluating ionic conductivity. However, if the electronic resistance is comparable to the ionic resistance, which is the case with our NCM electrodes, the results with the ion-electron connection may contain some inherent inaccuracy. In this report, we theoretically and practically demonstrate the advantage of analyzing the results with the electron-electron connection, which gives both the ionic and electronic conductivities. The similarity of the behavior of ionic conductivity with the graphite and NCM electrodes confirms the reliability of this analysis.

  19. AC Conductivity Studies of Lithium Based Phospho Vanadate Glasses

    NASA Astrophysics Data System (ADS)

    Nagendra, K.; Babu, G. Satish; Reddy, C. Narayana; Gowda, Veeranna

    2011-07-01

    Glasses in the system xLi2SO4-20Li2O-(80-x) [80P2O5-20V2O5] (5⩾x⩾20 mol%) has been prepared by melt quenching method. Dc and ac conductivity has been studied over a wide range of frequency (10 Hz to 10 MHz) and temperature (298 K-523 K). The dc conductivity found to increase with increase of Li2SO4 concentration. The ac conductivities have been fitted to the Almond-West type single power law equation σ(ω) = σ(0)+Aωs where `s' is the power law exponent. The ac conductivity found to increase with increase of Li2SO4 concentration. An attempt is made to elucidate the enhancement of lithium ion conduction in phosphor-vanadate glasses by considering the expansion of network structure.

  20. Studies on Electrical behavior of Glucose using Impedance Spectroscopy

    NASA Astrophysics Data System (ADS)

    Juansah, Jajang; Yulianti, Wina

    2016-01-01

    In this work we report the electrical characteristics of glucose at different frequencies. We show the correlation between electrical properties (impedance, reactance, resistance and conductance) of glucose and glucose concentration. Electrical property measurements on glucose solution were performed in order to formulate the correlation. The measurements were conducted for frequencies between 50 Hz and 1 MHz. From the measurements, we developed a single-pole Cole-Cole graph as a function of glucose concentration.

  1. Application of the A.C. Admittance technique to double layer studies on polycrystalline gold electrodes

    NASA Astrophysics Data System (ADS)

    Fawcett, W. R.; Kovacova, Zuzana; Motheo, Arthur J.; Foss, Colby A., Jr.

    1992-02-01

    A detailed examination of the dependence of the a.c. admittance of a cell containing a polycrystalline gold electrode has been made in the double layer region as a function of d.c. potential, a.c. frequency, and electrode history. It is shown that the interfacial impedance of a gold electrode with a carefully prepared surface can be treated under these circumstances as a constant phase element when it is in contact with an aqueous solution containing 0.05 M KClO4. Analysis of the frequency dependence of the cell impedance gives the surface inhomogeneity parameter n which turns out to be very close to unity. Although the electrode surface is only slightly inhomogeneous on a microscopic scale, a very large frequency dispersion of the impedance is observed experimentally. A method of estimating the true specific capacity of the electrode is presented, and conditions for carrying out the experiments in a reproducible manner are discussed.

  2. Study on A.C. electrical properties of pure and L-serine doped ADP crystals

    NASA Astrophysics Data System (ADS)

    Joshi, J. H.; Dixit, K. P.; Joshi, M. J.; Parikh, K. D.

    2016-05-01

    Ammonium Dihydrogen Phosphate (ADP) crystals have a wide range of applications in integrated and nonlinear optics. Amino acids having significant properties like molecular chirality, zwitter ionic nature, etc. attracted many researchers to dope them in various NLO crystals. In the present study, pure and different weight percentage L-serine doped ADP crystals were grown by slow solvent evaporation technique at room temperature. The A.C. electrical study was carried out for palletized samples at room temperature. The Nyquist plot showed two semi circles for pure ADP indicated the effect of grain and grain boundary, whereas the doped ADP samples exhibited the single semi circle suggesting the effect of grain. The values resistance and capacitance for grain and grain boundary were calculated. The effect of doping was clearly seen in the grain capacitance and resistance values. The dielectric constant and dielectric loss decreased with increase in frequency for all samples. The Jonscher power law was applied for A.C. conductivity for pure and doped ADP samples. The imaginary part of modulus and impedance versus frequency were drawn and the value of stretch exponent (β) was calculated for all the samples.

  3. A Comparative Study of Four Impedance Eduction Methodologies Using Several Test Liners

    NASA Technical Reports Server (NTRS)

    Watson, Willie R.; Jones, Michael G.

    2013-01-01

    A comparative study of four commonly used impedance eduction methods is presented for a range of liner structures and test conditions. Two of the methods are restricted to uniform flow while the other two accommodate both uniform and boundary layer flows. Measurements on five liner structures (a rigid-wall insert, a ceramic tubular liner, a wire mesh liner, a low porosity conventional liner, and a high porosity conventional liner) are obtained using the NASA Langley Grazing Flow Impedance Tube. The educed impedance of each liner is presented for forty-two test conditions (three Mach numbers and fourteen frequencies). In addition, the effects of moving the acoustic source from upstream to downstream and the refractive effects of the mean boundary layer on the wire mesh liner are investigated. The primary conclusions of the study are that: (1) more accurate results are obtained for the upstream source, (2) the uniform flow methods produce nearly identical impedance spectra at and below Mach 0.3 but significant scatter in the educed impedance occurs at the higher Mach number, (3) there is better agreement in educed impedance among the methods for the conventional liners than for the rigid-wall insert, ceramic, or wire mesh liner, and (4) the refractive effects of the mean boundary layer on the educed impedance of the wire mesh liner are generally small except at Mach 0.5.

  4. The Study of Porous Media with AC Electrokinetics

    NASA Astrophysics Data System (ADS)

    Pengra, David B.; Wong, Po-Zen

    1996-11-01

    Electrokinetic phenomena, which involve the coupling of fluid and electric currents, are present in many porous media systems. They arise from the presence of a space charge layer at the fluid/solid interface, and depend on characteristics of the interface and properties of the porous material. Although understood for years, electrokinetic phenomena have been typically too weak to use as an experimental probe of such systems. Recently we have shown that modern instrumentation, based on AC excitations, can be used to measure electrokinetic response in porous rock. From the measurements we derive the permeability of the rock exactly, and study other physicochemical properties. We review electrokinetic theory, describe our results for porous rock, and discuss present research using the AC techniques. Research supported by the Gas Research Institute, Contract 5090-260-1953, and National Science Foundation Grant DMR-9405672.

  5. Ac magnetic susceptibility study of in vivo nanoparticle biodistribution

    NASA Astrophysics Data System (ADS)

    Gutiérrez, L.; Mejías, R.; Barber, D. F.; Veintemillas-Verdaguer, S.; Serna, C. J.; Lázaro, F. J.; Morales, M. P.

    2011-06-01

    We analysed magnetic nanoparticle biodistribution, before and after cytokine conjugation, in a mouse model by ac susceptibility measurements of the corresponding resected tissues. Mice received repeated intravenous injections of nanoparticle suspension for two weeks and they were euthanized 1 h after the last injection. In general, only 10% of the total injected nanoparticles after multiple exposures were found in tissues. The rest of the particles may probably be metabolized or excreted by the organism. Our findings indicate that the adsorption of interferon to DMSA-coated magnetic nanoparticles changes their biodistribution, reducing the presence of nanoparticles in lungs and therefore their possible toxicity. The specific targeting of the particles to tumour tissues by the use of an external magnetic field has also been studied. Magnetic nanoparticles were observed by transmission electron microscopy in the targeted tissue and quantified by ac magnetic susceptibility.

  6. AC Conductivity Studies of Lithium Based Phospho Vanadate Glasses

    SciTech Connect

    Nagendra, K.; Babu, G. Satish; Gowda, Veeranna; Reddy, C. Narayana

    2011-07-15

    Glasses in the system xLi{sub 2}SO{sub 4}-20Li{sub 2}O-(80-x) [80P{sub 2}O{sub 5}-20V{sub 2}O{sub 5}](5{>=}x{>=}20 mol%) has been prepared by melt quenching method. Dc and ac conductivity has been studied over a wide range of frequency (10 Hz to 10 MHz) and temperature (298 K-523 K). The dc conductivity found to increase with increase of Li{sub 2}SO{sub 4} concentration. The ac conductivities have been fitted to the Almond-West type single power law equation {sigma}({omega}) = {sigma}(0)+A{omega}{sup s} where 's' is the power law exponent. The ac conductivity found to increase with increase of Li{sub 2}SO{sub 4} concentration. An attempt is made to elucidate the enhancement of lithium ion conduction in phosphor-vanadate glasses by considering the expansion of network structure.

  7. Impedance Scaling and Impedance Control

    NASA Astrophysics Data System (ADS)

    Chou, W.; Griffin, J.

    1997-05-01

    When a machine becomes really large, such as the Really Large Hadron Collider (RLHC),(G. W. Foster and E. Malamud, Fermilab-TM-1976 (June, 1996).) of which the circumference could reach the order of megameters, beam instability could be an essential bottleneck. This paper studies the scaling of the instability threshold vs. machine size when the coupling impedance scales in a ``normal'' way. It is shown that the beam would be intrinsically unstable for the RLHC. As a possible solution to this problem, it is proposed to introduce local impedance inserts for controlling the machine impedance. In the longitudinal plane, this could be done by using a heavily detuned rf cavity (e.g., a biconical structure), which could provide large imaginary impedance with the right sign (i.e., inductive or capacitive) while keeping the real part small. In the transverse direction, a carefully designed variation of the cross section of a beam pipe could generate negative impedance that would partially compensate the transverse impedance in one plane.

  8. Comparative Study of Impedance Eduction Methods, Part 2: NASA Tests and Methodology

    NASA Technical Reports Server (NTRS)

    Jones, Michael G.; Watson, Willie R.; Howerton, Brian M.; Busse-Gerstengarbe, Stefan

    2013-01-01

    A number of methods have been developed at NASA Langley Research Center for eduction of the acoustic impedance of sound-absorbing liners mounted in the wall of a flow duct. This investigation uses methods based on the Pridmore-Brown and convected Helmholtz equations to study the acoustic behavior of a single-layer, conventional liner fabricated by the German Aerospace Center and tested in the NASA Langley Grazing Flow Impedance Tube. Two key assumptions are explored in this portion of the investigation. First, a comparison of results achieved with uniform-flow and shear-flow impedance eduction methods is considered. Also, an approach based on the Prony method is used to extend these methods from single-mode to multi-mode implementations. Finally, a detailed investigation into the effects of harmonic distortion on the educed impedance is performed, and the results are used to develop guidelines regarding acceptable levels of harmonic distortion

  9. Electron transfer at the contact between Al electrode and gold nanoparticles of polymer: Nanoparticle resistive switching devices studied by alternating current impedance spectroscopy

    SciTech Connect

    Ouyang, Jianyong

    2013-12-02

    Electron transfer at the contact between an Al electrode and Au nanoparticles of polymer:nanoparticle devices is studied by ac impedance spectroscopy. The devices have a polystyrene layer embedded with Au nanoparticles capped with conjugated 2-naphthalenethiol sandwiched between Al and MoO{sub 3}/Al electrodes, and they exhibit electrode-sensitive resistive switches. The devices in the pristine or high resistance state have high capacitance. The capacitance decreases after the devices switch to a low resistance state by a voltage scan. The change in the capacitance is attributed to the voltage-induced change on the electronic structure of the contact between the Al electrode and Au nanoparticles.

  10. Studies of longitudinal profile of electron bunches and impedance measurements at Indus-2 synchrotron radiation source

    NASA Astrophysics Data System (ADS)

    Garg, Akash Deep; Yadav, S.; Kumar, Mukesh; Shrivastava, B. B.; Karnewar, A. K.; Ojha, A.; Puntambekar, T. A.

    2016-04-01

    Indus-2 is a 3rd generation synchrotron radiation source at the Raja Ramanna Centre for Advanced Technology (RRCAT) in India. We study the longitudinal profile of electrons in Indus-2 by using dual sweep synchroscan streak camera at visible diagnostic beamline. In this paper, the longitudinal profiles of electron bunch are analyzed by filling beam current in a single bunch mode. These studies are carried at injection energy (550 MeV) and at ramped beam energy (2.5 GeV). The effects of the wakefield generated interactions between the circulating electrons and the surrounding vacuum chamber are analyzed in terms of measured effects on longitudinal beam distribution. The impedance of the storage ring is obtained by fitting the solutions of Haissinski equation to the measured bunch lengthening with different impedance models. The impedance of storage ring obtained by a series R+L impedance model indicates a resistance (R) of 1350±125 Ω, an inductance (L) of 180±25 nH and broadband impedance of 2.69 Ω. These results are also compared with the values obtained from measured synchronous phase advancing and scaling laws. These studies are very useful in better understanding and control of the electromagnetic interactions.

  11. Single cells and intracellular processes studied by a plasmonic-based electrochemical impedance microscopy

    NASA Astrophysics Data System (ADS)

    Wang, Wei; Foley, Kyle; Shan, Xiaonan; Wang, Shaopeng; Eaton, Seron; Nagaraj, Vinay J.; Wiktor, Peter; Patel, Urmez; Tao, Nongjian

    2011-03-01

    Electrochemical impedance spectroscopy is a crucial tool for the detection and study of various biological substances, from DNA and proteins to viruses and bacteria. It does not require any labelling species, and methods based on it have been developed to study cellular processes (such as cell spreading, adhesion, invasion, toxicology and mobility). However, data have so far lacked spatial information, which is essential for investigating heterogeneous processes and imaging high-throughput microarrays. Here, we report an electrochemical impedance microscope based on surface plasmon resonance that resolves local impedance with submicrometre spatial resolution. We have used an electrochemical impedance microscope to monitor the dynamics of cellular processes (apoptosis and electroporation of individual cells) with millisecond time resolution. The high spatial and temporal resolution makes it possible to study individual cells, but also resolve subcellular structures and processes without labels, and with excellent detection sensitivity (~2 pS). We also describe a model that simulates cellular and electrochemical impedance microscope images based on local dielectric constant and conductivity.

  12. Single cells and intracellular processes studied by a plasmonic-based electrochemical impedance microscopy.

    PubMed

    Wang, Wei; Foley, Kyle; Shan, Xiaonan; Wang, Shaopeng; Eaton, Seron; Nagaraj, Vinay J; Wiktor, Peter; Patel, Urmez; Tao, Nongjian

    2011-03-01

    Electrochemical impedance spectroscopy is a crucial tool for the detection and study of various biological substances, from DNA and proteins to viruses and bacteria. It does not require any labelling species, and methods based on it have been developed to study cellular processes (such as cell spreading, adhesion, invasion, toxicology and mobility). However, data have so far lacked spatial information, which is essential for investigating heterogeneous processes and imaging high-throughput microarrays. Here, we report an electrochemical impedance microscope based on surface plasmon resonance that resolves local impedance with submicrometre spatial resolution. We have used an electrochemical impedance microscope to monitor the dynamics of cellular processes (apoptosis and electroporation of individual cells) with millisecond time resolution. The high spatial and temporal resolution makes it possible to study individual cells, but also resolve subcellular structures and processes without labels, and with excellent detection sensitivity (~2 pS). We also describe a model that simulates cellular and electrochemical impedance microscope images based on local dielectric constant and conductivity.

  13. Mapping Electrical Impedance Spectra of the Healthy Oral Mucosa: a Pilot Study

    PubMed Central

    Richter, Ivica; Alajbeg, Ivan; Boras, Vanja Vučićević; Rogulj, Ana Andabak

    2015-01-01

    Objective Electrical impedance is the resistance to the electric current flow through a tissue and depends on the tissue’s structure and chemical composition. The aim of this study was to map electrical impedance spectra for each region of the healthy oral mucosa. Materials and Methods Electrical impedance was measured in 30 participants with healthy oral mucosa. Measurements were performed in 14 points on the right and the left side of the oral cavity, and repeated after 7 and 14 days respectively. Results The lowest values were measured on the tongue dorsum and the highest values were measured on the hard palate. No significant differences were found between the right and the left side. Significantly higher values were found in females on the upper labial mucosa, tongue dorsum and the ventral tongue. Significant difference between smokers and non-smokers on the lower labial mucosa and floor of the mouth was found. Electrical impedance was negatively correlated with salivary flow on the upper labial mucosa, hard palate, tongue dorsum and sublingual mucosa. Higher variability of measurements was found at low frequencies. Conclusions Electrical impedance mostly depends on the degree of mucosal keratinization. Demographic and clinical factors probably affect its values. Further studies with bigger number of participants are required. PMID:27688418

  14. Mapping Electrical Impedance Spectra of the Healthy Oral Mucosa: a Pilot Study

    PubMed Central

    Richter, Ivica; Alajbeg, Ivan; Boras, Vanja Vučićević; Rogulj, Ana Andabak

    2015-01-01

    Objective Electrical impedance is the resistance to the electric current flow through a tissue and depends on the tissue’s structure and chemical composition. The aim of this study was to map electrical impedance spectra for each region of the healthy oral mucosa. Materials and Methods Electrical impedance was measured in 30 participants with healthy oral mucosa. Measurements were performed in 14 points on the right and the left side of the oral cavity, and repeated after 7 and 14 days respectively. Results The lowest values were measured on the tongue dorsum and the highest values were measured on the hard palate. No significant differences were found between the right and the left side. Significantly higher values were found in females on the upper labial mucosa, tongue dorsum and the ventral tongue. Significant difference between smokers and non-smokers on the lower labial mucosa and floor of the mouth was found. Electrical impedance was negatively correlated with salivary flow on the upper labial mucosa, hard palate, tongue dorsum and sublingual mucosa. Higher variability of measurements was found at low frequencies. Conclusions Electrical impedance mostly depends on the degree of mucosal keratinization. Demographic and clinical factors probably affect its values. Further studies with bigger number of participants are required.

  15. Impedance and self-discharge mechanism studies of nickel metal hydride batteries for energy storage applications

    NASA Astrophysics Data System (ADS)

    Zhu, Wenhua; Zhu, Ying; Tatarchuk, Bruce

    2013-04-01

    Nickel metal hydride battery packs have been found wide applications in the HEVs (hybrid electric vehicles) through the on-board rapid energy conservation and efficient storage to decrease the fossil fuel consumption rate and reduce CO2 emissions as well as other harmful exhaust gases. In comparison to the conventional Ni-Cd battery, the Ni-MH battery exhibits a relatively higher self-discharge rate. In general, there are quite a few factors that speed up the self-discharge of the electrodes in the sealed nickel metal hydride batteries. This disadvantage eventually reduces the overall efficiency of the energy conversion and storage system. In this work, ac impedance data were collected from the nickel metal hydride batteries. The self-discharge mechanism and battery capacity degradation were analyzed and discussed for further performance improvement.

  16. Monitoring of CRT by means of impedance multiple measurements - simulation studies

    NASA Astrophysics Data System (ADS)

    Lewandowska, M.; Wtorek, J.; Bujnowski, A.; Mierzejewski, L.

    2010-04-01

    Cardiac resynchronization therapy (CRT) is a very promising treatment for patients with congestive heart failure. An Impedance Cardiography (ICG) is used for evaluation of heart mechanical activity. A simulation study with the use of a FEM model was performed. The developed realistic model of the thorax, based on CT data obtained from examination of a 68-year-old man, consisted of 212 000 tetrahedral elements. Different configurations of electrodes allowing extraction of ventricular components from impedance signal were examined. The associated sensitivity distributions were calculated for different phases of heart contraction and blood distribution inside the thorax. These sensitivity distributions were compared to that obtained for a uniform model of the thorax described by average conductivity. The performed simulation studies proved that it is possible to extract ventricular components of impedance signal with a reasonable accuracy.

  17. AC biosusceptometry in the study of drug delivery.

    PubMed

    Corá, L A; Romeiro, F G; Stelzer, M; Américo, M F; Oliveira, R B; Baffa, O; Miranda, J R A

    2005-06-15

    Conventionally, pharmaceutical substances are administered orally because the gastrointestinal tract possesses the appropriate features for drug absorption. Nevertheless, the gastrointestinal tract physiology is complex and influenced by many factors. These factors must be completely understood for the optimization of oral drug delivery systems. Although in vitro tests provide information about release and drug absorption profiles, in vivo studies are essential, due to the biological variability. Several techniques have been employed in an attempt to conveniently characterize the behavior of solid dosage forms in vivo. The noninvasive biomagnetic technique of alternate current biosusceptometry (ACB) has been used in studies focusing on gastrointestinal motility and, more recently, to evaluate the performance of magnetic dosage forms. This article will discuss the main characteristics of AC biosusceptometry and its applicability for determination of the relationship between the human gastrointestinal tract and orally administered pharmaceutical dosage forms.

  18. A combined complex electrical impedance and acoustic emission study in limestone samples under uniaxial loading

    NASA Astrophysics Data System (ADS)

    Saltas, V.; Fitilis, I.; Vallianatos, F.

    2014-12-01

    In the present work, complex electrical impedance measurements in the frequency range of 10 mHz to 1 MHz were carried out in conjunction with acoustic emission monitoring in limestone samples subjected to linear and stepped-like uniaxial loading, up to ultimate failure. Cole-Cole plots of the complex impedance during the stepped loading of limestone have been used to discriminate the contributions of grains interior, grain boundaries and electrode polarization effects to the overall electrical behavior. The latter is well-described with an equivalent-circuit model which comprises components of constant phase elements and resistances in parallel connection. Electrical conductivity increases upon uniaxial loading giving rise to negative values of effective activation volume. This is a strong experimental evidence for the generation of transient electric signals recorded prior to seismic events and may be attributed to charge transfer (proton conduction) due to cracks generation and propagation as a result of the applied stress. The time-series of ac-conductivity at two distinct frequencies (10 kHz, 200 kHz) during linear loading of limestone samples exhibits a strong correlation with the acoustic emission activity obeying the same general self-similar law for critical phenomena that has been reported for the energy release before materials fracture.

  19. The Influence of Nanopore Dimensions on the Electrochemical Properties of Nanopore Arrays Studied by Impedance Spectroscopy

    PubMed Central

    Kant, Krishna; Priest, Craig; Shapter, Joe G.; Losic, Dusan

    2014-01-01

    The understanding of the electrochemical properties of nanopores is the key factor for better understanding their performance and applications for nanopore-based sensing devices. In this study, the influence of pore dimensions of nanoporous alumina (NPA) membranes prepared by an anodization process and their electrochemical properties as a sensing platform using impedance spectroscopy was explored. NPA with four different pore diameters (25 nm, 45 nm and 65 nm) and lengths (5 μm to 20 μm) was used and their electrochemical properties were explored using different concentration of electrolyte solution (NaCl) ranging from 1 to 100 μM. Our results show that the impedance and resistance of nanopores are influenced by the concentration and ion species of electrolytes, while the capacitance is independent of them. It was found that nanopore diameters also have a significant influence on impedance due to changes in the thickness of the double layer inside the pores. PMID:25393785

  20. A new approach to the study of impedance characteristics of tympanic membrane.

    PubMed

    Bogomolov, A V; Dragan, S P

    2015-01-01

    A new approach to studying the tympanic membrane impedance characteristics, based on the analysis of polyharmonic acoustic signals reflected by the tympanic membrane, is described. For this purpose, the acoustic pressure and the phase difference between the acoustic vibrations in two sections of a waveguide sealingly connecting the external auditory meatus and a generator of polyharmonic audio signals is measured. By processing the results of measurements, the estimates of the frequency-dependent reflection coefficients, absorption coefficients, and components of the acoustic impedance of the tympanic membrane are calculated. The features that principally distinguish the developed approach from other approaches are the absence of the necessity to create a positive pressure in the external auditory meatus, the absence of ultrasonic radiation into the external auditory meatus and a high-intensity sound, and the possibility of direct measurement of the tympanic membrane impedance in the audio frequency range with any step. PMID:26518544

  1. Impedance study of membrane dehydration and compression in proton exchange membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Le Canut, Jean-Marc; Latham, Ruth; Mérida, Walter; Harrington, David A.

    Electrochemical impedance spectroscopy (EIS) is used to measure drying and rehydration in proton exchange membrane fuel cells running under load. The hysteresis between forward and backward acquisition of polarization curves is shown to be largely due to changes in the membrane resistance. Drying tests are carried out with hydrogen and simulated reformate (hydrogen and carbon dioxide), and quasi-periodic drying and rehydration conditions are studied. The membrane hydration state is clearly linked to the high-frequency arc in the impedance spectrum, which increases in size for dry conditions indicating an increase in membrane resistance. Changes in impedance spectra as external compression is applied to the cell assembly show that EIS can separate membrane and interfacial effects, and that changes in membrane resistance dominate. Reasons for the presence of a capacitance in parallel with the membrane resistance are discussed.

  2. Studies on LiFePO 4 as cathode material using impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Schmidt, Jan Philipp; Chrobak, Thorsten; Ender, Moses; Illig, Jörg; Klotz, Dino; Ivers-Tiffée, Ellen

    Lithium iron phosphate is a promising cathode material for the use in hybrid electrical vehicles (HEV) meeting the demands of good stability during cycling and safe operation due to reduced risk of thermal runaway. However, slow solid state diffusion and poor electrical conductivity reduce power capability. For further improvement, the identification of the rate determining processes is necessary. Electrochemical impedance spectroscopy (EIS) has proven to be a powerful tool for the characterization of electrochemical systems. In this contribution a deconvolution of the impedance with the distribution of relaxation times (DRTs) is used to obtain a better resolution in frequency domain. Therewith, the relevant loss processes are identified and an impedance model is developed. Using DRT and CNLS-fit allows the determination of time constants and polarization resistances of all relevant loss processes. Furthermore, their temperature behavior is studied and a physical interpretation is provided.

  3. In situ anodization of aluminum surfaces studied by x-ray reflectivity and electrochemical impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Bertram, F.; Zhang, F.; Evertsson, J.; Carlà, F.; Pan, J.; Messing, M. E.; Mikkelsen, A.; Nilsson, J.-O.; Lundgren, E.

    2014-07-01

    We present results from the anodization of an aluminum single crystal [Al(111)] and an aluminum alloy [Al 6060] studied by in situ x-ray reflectivity, in situ electrochemical impedance spectroscopy and ex situ scanning electron microscopy. For both samples, a linear increase of oxide film thickness with increasing anodization voltage was found. However, the slope is much higher in the single crystal case, and the break-up of the oxide film grown on the alloy occurs at a lower anodization potential than on the single crystal. The reasons for these observations are discussed as are the measured differences observed for x-ray reflectivity and electrochemical impedance spectroscopy.

  4. In situ anodization of aluminum surfaces studied by x-ray reflectivity and electrochemical impedance spectroscopy

    SciTech Connect

    Bertram, F. Evertsson, J.; Messing, M. E.; Mikkelsen, A.; Lundgren, E.; Zhang, F.; Pan, J.; Carlà, F.; Nilsson, J.-O.

    2014-07-21

    We present results from the anodization of an aluminum single crystal [Al(111)] and an aluminum alloy [Al 6060] studied by in situ x-ray reflectivity, in situ electrochemical impedance spectroscopy and ex situ scanning electron microscopy. For both samples, a linear increase of oxide film thickness with increasing anodization voltage was found. However, the slope is much higher in the single crystal case, and the break-up of the oxide film grown on the alloy occurs at a lower anodization potential than on the single crystal. The reasons for these observations are discussed as are the measured differences observed for x-ray reflectivity and electrochemical impedance spectroscopy.

  5. BOLD signal effects of transcranial alternating current stimulation (tACS) in the alpha range: A concurrent tACS-fMRI study.

    PubMed

    Vosskuhl, Johannes; Huster, René J; Herrmann, Christoph S

    2016-10-15

    Many studies have proven transcranial alternating current stimulation (tACS) to manipulate brain activity. Until now it is not known, however, how these manipulations in brain activity are represented in brain metabolism or how spatially specific these changes are. Alpha-tACS has been shown to enhance the amplitude of the individual alpha frequency (IAF) and a negative correlation between alpha amplitude and occipital BOLD signal was reported in numerous EEG/fMRI experiments. Thus, alpha-tACS was chosen to test the effects of tACS on the BOLD signal. A reduction thereof was expected during alpha-tACS which shows the spatial extent of tACS effects beyond modeling studies. Three groups of subjects were measured in an MRI scanner, receiving tACS at either their IAF (N=11), 1Hz (control; N=12) or sham (i.e., no stimulation - a second control; N=11) while responding to a visual vigilance task. Stimulation was administered in an interleaved pattern of tACS-on runs and tACS-free baseline periods. The BOLD signal was analyzed in response to tACS-onset during resting state and in response to seldom target stimuli. Alpha-tACS at 1.0mA reduced the task-related BOLD response to visual targets in the occipital cortex as compared to tACS-free baseline periods. The deactivation was strongest in an area where the BOLD signal was shown to correlate negatively with alpha amplitude. A direct effect of tACS on resting state BOLD signal levels could not be shown. Our findings suggest that tACS-related changes in BOLD activity occur only as a modulation of an existing BOLD response.

  6. A study on the impact of lithium-ion cell relaxation on electrochemical impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Barai, Anup; Chouchelamane, Gael H.; Guo, Yue; McGordon, Andrew; Jennings, Paul

    2015-04-01

    Lithium-ion (Li-ion) batteries are of great interest to the automotive industry due to their higher power and energy density, higher cell voltage, longer cycle life and lower self-discharge compared to other battery chemistries. Electrochemical impedance spectroscopy is a powerful tool employed to investigate the fundamental electrochemical reactions within a Li-ion battery cell, which relates to state of charge, internal temperature and state of health. Its effectiveness has established it as a core method to study electrochemical behaviour of batteries in both off-line and on-line applications. In this work it is shown that in addition to state of charge, internal temperature and state of health, the time period between the removal of an electrical load and the impedance measurement affects the results. The study of five commercially available cells of varying capacities and electrode chemistries show that, regardless of cell type, maximum impedance change takes place within the first 4 h of the relaxation period. The root cause of this impedance change has been discussed from an electrochemical perspective.

  7. Electrochemical Impedance Spectroscopy Study on Corrosion Protection of Acrylate Nanocomposite on Mild Steel Doped Carbon Nanotubes

    NASA Astrophysics Data System (ADS)

    Mahmud, M. R.; Akhir, M. M.; Shamsudin, M. S.; Afaah, A. N.; Aadila, A.; Asib, N. A. M.; Alrokayan, Salman A. H.; Khan, Haseeb A.; Harun, M. K.; Rusop, M.; Abdullah, S.

    2015-05-01

    Acrylate:carbon nanotubes (A:CNTs) nanocomposite thin film was prepared by sol- gel technique. The corrosion coating protection of acrylate:carbon nanotubes (CNTs) nanocomposite thin film has been coated on mild steel characterised by electrochemical impedance spectrometer (EIS) measurement and equivalent circuit model are employed to analyse coating impedance for corrosion protection. In this study, 3.5 w/v % sodium chloride (NaCl) solution was immersed the acrylate:carbon nanotubes nanocomposite thin film. As the results, the surface morphology were found that there formation of carbon nanotubes with good distribution on acrylate-based coating. From EIS measurement, A:CNTs nanocomposite thin film with 0.4 w/v % contain of CNTs was exhibited the highest coating impedance from Nyquist graph after immersed in sodium chloride solution and may provide the excellent corrosion protection. The Bode plots have shown the impedance is high at the beginning from the time at high frequency and slightly decreases with value of frequency become smaller.

  8. Comparative study of electrolyte additives using electrochemical impedance spectroscopy on symmetric cells

    NASA Astrophysics Data System (ADS)

    Petibon, R.; Sinha, N. N.; Burns, J. C.; Aiken, C. P.; Ye, Hui; VanElzen, Collette M.; Jain, Gaurav; Trussler, S.; Dahn, J. R.

    2014-04-01

    The effect of various electrolyte additives and additive combinations added to a 1 M LiPF6 EC:EMC electrolyte on the positive and negative electrodes surface of 1 year old wound LiCoO2/graphite cells and Li[Ni0.4Mn0.4Co0.2])O2/graphite cells was studied using electrochemical impedance spectroscopy (EIS) on symmetric cells. The additives tested were: vinylene carbonate (VC), trimethoxyboroxine (TMOBX), fluoroethylene carbonate (FEC), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), and H2O alone or in combination. In general, compared to control electrolyte, the additives tested reduced the impedance of the positive electrode and increased the impedance of the negative electrode with the exception of LiTFSI in Li[Ni0.4Mn0.4Co0.2]O2/graphite wound cells. Higher charge voltage led to higher positive electrode impedance, with the exception of 2%VC + 2% FEC, and 2% LiTFSI. In some cases, some additives when mixed with another controlled the formation of the SEI at one electrode, and shared the formation of the SEI at one electrode when mixed with a different additive.

  9. Impedance study of tea with added taste compounds using conducting polymer and metal electrodes.

    PubMed

    Dhiman, Mopsy; Kapur, Pawan; Ganguli, Abhijit; Singla, Madan Lal

    2012-09-01

    In this study the sensing capabilities of a combination of metals and conducting polymer sensing/working electrodes for tea liquor prepared by addition of different compounds using an impedance mode in frequency range 1 Hz-100 KHz at 0.1 V potential has been carried out. Classification of six different tea liquor samples made by dissolving various compounds (black tea liquor + raw milk from milkman), (black tea liquor + sweetened clove syrup), (black tea liquor + sweetened ginger syrup), (black tea liquor + sweetened cardamom syrup), (black tea liquor + sweet chocolate syrup) and (black tea liquor + vanilla flavoured milk without sugar) using six different working electrodes in a multi electrode setup has been studied using impedance and further its PCA has been carried out. Working electrodes of Platinum (Pt), Gold (Au), Silver (Ag), Glassy Carbon (GC) and conducting polymer electrodes of Polyaniline (PANI) and Polypyrrole (PPY) grown on an ITO surface potentiostatically have been deployed in a three electrode set up. The impedance response of these tea liquor samples using number of working electrodes shows a decrease in the real and imaginary impedance values presented on nyquist plots depending upon the nature of the electrode and amount of dissolved salts present in compounds added to tea liquor/solution. The different sensing surfaces allowed a high cross-selectivity in response to the same analyte. From Principal Component Analysis (PCA) plots it was possible to classify tea liquor in 3-4 classes using conducting polymer electrodes; however tea liquors were well separated from the PCA plots employing the impedance data of both conducting polymer and metal electrodes. PMID:23035436

  10. Spectroscopy study of the dynamics of the transencephalic electrical impedance in the perinatal brain during hypoxia.

    PubMed

    Seoane, Fernando; Lindecrantz, Kaj; Olsson, Torsten; Kjellmer, Ingemar; Flisberg, Anders; Bågenholm, Ralph

    2005-10-01

    Hypoxia/ischaemia is the most common cause of brain damage in neonates. Thousands of newborn children suffer from perinatal asphyxia every year. The cells go through a response mechanism during hypoxia/ischaemia, to maintain the cellular viability and, as a response to the hypoxic/ischaemic insult, the composition and the structure of the cellular environment are altered. The alterations in the ionic concentration of the intra- and extracellular and the consequent cytotoxic oedema, cell swelling, modify the electrical properties of the constituted tissue. The changes produced can be easily measured using electrical impedance instrumentation. In this paper, we report the results from an impedance spectroscopy study on the effects of the hypoxia on the perinatal brain. The transencephalic impedance, both resistance and reactance, was measured in newborn piglets using the four-electrode method in the frequency range from 20 kHz to 750 kHz and the experimental results were compared with numerical results from a simulation of a suspension of cells during cell swelling. The experimental results make clear the frequency dependence of the bioelectrical impedance, confirm that the variation of resistance is more sensitive at low than at high frequencies and show that the reactance changes substantially during hypoxia. The resemblance between the experimental and numerical results proves the validity of modelling tissue as a suspension of cells and confirms the importance of the cellular oedema process in the alterations of the electrical properties of biological tissue. The study of the effects of hypoxia/ischaemia in the bioelectrical properties of tissue may lead to the development of useful clinical tools based on the application of bioelectrical impedance technology.

  11. Electrochemical cell design for the impedance studies of chlorine evolution at DSA anodes

    NASA Astrophysics Data System (ADS)

    Silva, J. F.; Dias, A. C.; Araújo, P.; Brett, C. M. A.; Mendes, A.

    2016-08-01

    A new electrochemical cell design suitable for the electrochemical impedance spectroscopy (EIS) studies of chlorine evolution on Dimensionally Stable Anodes (DSA®) has been developed. Despite being considered a powerful tool, EIS has rarely been used to study the kinetics of chlorine evolution at DSA anodes. Cell designs in the open literature are unsuitable for the EIS analysis at high DSA anode current densities for chlorine evolution because they allow gas accumulation at the electrode surface. Using the new cell, the impedance spectra of the DSA anode during chlorine evolution at high sodium chloride concentration (5 mol dm-3 NaCl) and high current densities (up to 140 mA cm-2) were recorded. Additionally, polarization curves and voltammograms were obtained showing little or no noise. EIS and polarization curves evidence the role of the adsorption step in the chlorine evolution reaction, compatible with the Volmer-Heyrovsky and Volmer-Tafel mechanisms.

  12. Electrochemical cell design for the impedance studies of chlorine evolution at DSA(®) anodes.

    PubMed

    Silva, J F; Dias, A C; Araújo, P; Brett, C M A; Mendes, A

    2016-08-01

    A new electrochemical cell design suitable for the electrochemical impedance spectroscopy (EIS) studies of chlorine evolution on Dimensionally Stable Anodes (DSA(®)) has been developed. Despite being considered a powerful tool, EIS has rarely been used to study the kinetics of chlorine evolution at DSA anodes. Cell designs in the open literature are unsuitable for the EIS analysis at high DSA anode current densities for chlorine evolution because they allow gas accumulation at the electrode surface. Using the new cell, the impedance spectra of the DSA anode during chlorine evolution at high sodium chloride concentration (5 mol dm(-3) NaCl) and high current densities (up to 140 mA cm(-2)) were recorded. Additionally, polarization curves and voltammograms were obtained showing little or no noise. EIS and polarization curves evidence the role of the adsorption step in the chlorine evolution reaction, compatible with the Volmer-Heyrovsky and Volmer-Tafel mechanisms.

  13. Electrochemical cell design for the impedance studies of chlorine evolution at DSA(®) anodes.

    PubMed

    Silva, J F; Dias, A C; Araújo, P; Brett, C M A; Mendes, A

    2016-08-01

    A new electrochemical cell design suitable for the electrochemical impedance spectroscopy (EIS) studies of chlorine evolution on Dimensionally Stable Anodes (DSA(®)) has been developed. Despite being considered a powerful tool, EIS has rarely been used to study the kinetics of chlorine evolution at DSA anodes. Cell designs in the open literature are unsuitable for the EIS analysis at high DSA anode current densities for chlorine evolution because they allow gas accumulation at the electrode surface. Using the new cell, the impedance spectra of the DSA anode during chlorine evolution at high sodium chloride concentration (5 mol dm(-3) NaCl) and high current densities (up to 140 mA cm(-2)) were recorded. Additionally, polarization curves and voltammograms were obtained showing little or no noise. EIS and polarization curves evidence the role of the adsorption step in the chlorine evolution reaction, compatible with the Volmer-Heyrovsky and Volmer-Tafel mechanisms. PMID:27587166

  14. Electrical impedance measurements in the arm and the leg during a thirty day bed rest study

    NASA Technical Reports Server (NTRS)

    Cardus, David; Jaweed, Mazher; McTaggart, Wesley

    1995-01-01

    The need to detect, follow, and understand the effects of gravity on body fluid distribution is a constant stimulus to the quest for new techniques in this area of research. One of these techniques is electrical bioimpedance spectroscopy (BIS). Although not new, this is a technique whose applications to biomedical research are fairly recent. What is new is the development of instrumentation that has made practical the use of impedance spectroscopy in the biomedical setting, particularly in studies involving human subjects. The purpose of this paper is to report impedance spectroscopy observations made on a subject who was submitted to bed rest for a period of thirty days. These observations were made as part of a study on muscle atrophy during a thirty day head down bed rest. Since bed rest studies are very costly in human and financial terms, and technically difficult to realize, we felt that even though the present study deals only with a single case it was worthy of reporting because it illustrates kinds of questions impedance spectroscopy may help to answer in microgravity research.

  15. Single cells and intracellular processes studied by a plasmonic-based electrochemical impedance microscopy

    PubMed Central

    Wang, Wei; Foley, Kyle; Shan, Xiaonan; Wang, Shaopeng; Eaton, Seron; Nagaraj, Vinay J; Wiktor, Peter; Patel, Urmez; Tao, Nongjian

    2012-01-01

    We report an electrochemical impedance microscope (EIM) based on surface plasmon resonance. The new EIM can resolve local impedance with sub-micron spatial resolution, and monitor dynamics of various processes, such as apoptosis and electroporation of individual cells with millisecond time resolution. The high spatial and temporal resolution images make it possible to not only study individual cells, but also resolve the sub-cellular structures and processes without labels. The detection sensitivity achieved with the current setup is ~2 pS, which is excellent considering the conductance of a single ion channel is in the range of 5–400 pS. We describe also a model that simulates the EIM images of cells based on local dielectric constant and conductivity. PMID:21336333

  16. Influence of heart motion on cardiac output estimation by means of electrical impedance tomography: a case study.

    PubMed

    Proença, Martin; Braun, Fabian; Rapin, Michael; Solà, Josep; Adler, Andy; Grychtol, Bartłomiej; Bohm, Stephan H; Lemay, Mathieu; Thiran, Jean-Philippe

    2015-06-01

    Electrical impedance tomography (EIT) is a non-invasive imaging technique that can measure cardiac-related intra-thoracic impedance changes. EIT-based cardiac output estimation relies on the assumption that the amplitude of the impedance change in the ventricular region is representative of stroke volume (SV). However, other factors such as heart motion can significantly affect this ventricular impedance change. In the present case study, a magnetic resonance imaging-based dynamic bio-impedance model fitting the morphology of a single male subject was built. Simulations were performed to evaluate the contribution of heart motion and its influence on EIT-based SV estimation. Myocardial deformation was found to be the main contributor to the ventricular impedance change (56%). However, motion-induced impedance changes showed a strong correlation (r = 0.978) with left ventricular volume. We explained this by the quasi-incompressibility of blood and myocardium. As a result, EIT achieved excellent accuracy in estimating a wide range of simulated SV values (error distribution of 0.57 ± 2.19 ml (1.02 ± 2.62%) and correlation of r = 0.996 after a two-point calibration was applied to convert impedance values to millilitres). As the model was based on one single subject, the strong correlation found between motion-induced changes and ventricular volume remains to be verified in larger datasets.

  17. What Impedes or Enhances My Studying? The Interrelation between Approaches to Learning, Factors Influencing Study Progress and Earned Credits

    ERIC Educational Resources Information Center

    Hailikari, Telle Katriina; Parpala, Anna

    2014-01-01

    The aim of the study is to explore how students' experiences of enhancing and impeding factors and approaches to learning are related to students' study progress. A total of 93 students from the Faculty of Arts and Humanities participated in the study by answering a Learn-questionnaire regarding their experiences of the enhancing and…

  18. A study of concrete slab damage detection based on the electromechanical impedance method.

    PubMed

    Hu, Xianyan; Zhu, Hongping; Wang, Dansheng

    2014-10-23

    Piezoelectric lead zirconate titanate (PZT) is being gradually applied into practice as a new intelligent material for structural health monitoring. In order to study the damage detection properties of PZT on concrete slabs, simply supported reinforced concrete slabs with piezoelectric patches attached to their surfaces were chosen as the research objects and the Electromechanical Impedance method (EMI) was adopted for research. Five kinds of damage condition were designed to test the impedance values at different frequency bands. Consistent rules are found by calculation and analysis. Both the root mean square deviation (RMSD) and the correlation coefficient deviation (CCD) damage indices are capable of detecting the structural damage. The newly proposed damage index Ry/Rx can also predict the changes well. The numerical and experimental studies verify that the Electromechanical Impedance method can accurately predict changes in the amount of damage in reinforced concrete slabs. The damage index changes regularly with the distance of damages to the sensor. This relationship can be used to determine the damage location. The newly proposed damage index Ry/Rx is accurate in determining the damage location.

  19. A Study of Concrete Slab Damage Detection Based on the Electromechanical Impedance Method

    PubMed Central

    Hu, Xianyan; Zhu, Hongping; Wang, Dansheng

    2014-01-01

    Piezoelectric lead zirconate titanate (PZT) is being gradually applied into practice as a new intelligent material for structural health monitoring. In order to study the damage detection properties of PZT on concrete slabs, simply supported reinforced concrete slabs with piezoelectric patches attached to their surfaces were chosen as the research objects and the Electromechanical Impedance method (EMI) was adopted for research. Five kinds of damage condition were designed to test the impedance values at different frequency bands. Consistent rules are found by calculation and analysis. Both the root mean square deviation (RMSD) and the correlation coefficient deviation (CCD) damage indices are capable of detecting the structural damage. The newly proposed damage index Ry/Rx can also predict the changes well. The numerical and experimental studies verify that the Electromechanical Impedance method can accurately predict changes in the amount of damage in reinforced concrete slabs. The damage index changes regularly with the distance of damages to the sensor. This relationship can be used to determine the damage location. The newly proposed damage index Ry/Rx is accurate in determining the damage location. PMID:25341438

  20. Effect of counterions on the formation of ohmic contact between p-Si and poly(pyrrole) film - An ac impedance analysis

    NASA Technical Reports Server (NTRS)

    Nagsubramanian, G.; Distefano, S.; Moacanin, J.

    1986-01-01

    Conditions under which poly(pyrrole) (PP) films form ohmic contact with single-crystal p-Si are described. Counterions affect both the conductivity and flatband potential, V(FB), values of poly(pyrrole). While paratoluene-sulfonate-doped PP acts like a switch, the impedance behavior of PP films doped with ClO4(-), BF4(-), or PF6(-) allows evaluation of the V(FB) of these films. The formation of 'quasi-ohmic' and 'nonohmic' contacts, respectively, of PP (ClO4) and PP films doped with other counterions, with p-Si, are explained in terms of conductivity of these films and V(FB) of PP films with respect to that of p-Si. PP film seems to passivate or block intrinsic surface states present on p-Si surface.

  1. Origin of Capacity Fading in Nano-Sized Co3O4Electrodes: Electrochemical Impedance Spectroscopy Study

    PubMed Central

    2008-01-01

    Transition metal oxides have been suggested as innovative, high-energy electrode materials for lithium-ion batteries because their electrochemical conversion reactions can transfer two to six electrons. However, nano-sized transition metal oxides, especially Co3O4, exhibit drastic capacity decay during discharge/charge cycling, which hinders their practical use in lithium-ion batteries. Herein, we prepared nano-sized Co3O4with high crystallinity using a simple citrate-gel method and used electrochemical impedance spectroscopy method to examine the origin for the drastic capacity fading observed in the nano-sized Co3O4anode system. During cycling, AC impedance responses were collected at the first discharged state and at every subsequent tenth discharged state until the 100th cycle. By examining the separable relaxation time of each electrochemical reaction and the goodness-of-fit results, a direct relation between the charge transfer process and cycling performance was clearly observed.

  2. Impedance Mismatch study between the Microwave Generator and the PUPR Plasma Machine

    NASA Astrophysics Data System (ADS)

    Gaudier, Jorge R.; Castellanos, Ligeia; Encarnación, Kabir; Zavala, Natyaliz; Rivera, Ramón; Farahat, Nader; Leal, Edberto

    2006-12-01

    Impedance mismatch inside the connection from the microwave power generator to the plasma machine is studied. A magnetron power generator transmits microwaves of 2.45 GHz and variable power from 50W to 5000W, through a flexible rectangular waveguide to heat plasma inside a Mirror Cusp devise located at the Polytechnic University of Puerto Rico. Before the production of plasma, the residual gas of the devise must be extracted by a vacuum system (5Torr or better), then Argon gas is injected to the machine. The microwaves heat the Argon ions to initiate ionization and plasma is produced. A dielectric wall is used inside the rectangular waveguide to isolate the plasma machine and maintain vacuum. Even though the dielectric will not block the wave propagation, some absorption of microwaves will occur. This absorption will cause reflection, reducing the efficiency of the power transfer. Typically a thin layer of Teflon is used, but measurements using this dielectric show a significant reflection of power back to the generator. Due to the high-power nature of the generator (5KW), this mismatch is not desirable. An electromagnetic field solver based on the Finite Difference Time Domain Method(FDTD) is used to model the rectangular waveguide connection. The characteristic impedance of the simulation is compared with the analytical formula expression and a good agreement is obtain. Furthermore the Teflon-loaded guide is modeled using the above program and the input impedance is computed. The reflection coefficient is calculated based on the transmission line theory with the characteristic and input impedances. Based on the simulation results it is possible to optimize the thickness, shape and dielectric constant of the material, in order to seal the connection with a better match.

  3. Impedance Mismatch study between the Microwave Generator and the PUPR Plasma Machine

    SciTech Connect

    Gaudier, Jorge R.; Castellanos, Ligeia; Encarnacion, Kabir; Zavala, Natyaliz; Rivera, Ramon; Farahat, Nader; Leal, Edberto

    2006-12-04

    Impedance mismatch inside the connection from the microwave power generator to the plasma machine is studied. A magnetron power generator transmits microwaves of 2.45 GHz and variable power from 50W to 5000W, through a flexible rectangular waveguide to heat plasma inside a Mirror Cusp devise located at the Polytechnic University of Puerto Rico. Before the production of plasma, the residual gas of the devise must be extracted by a vacuum system (5Torr or better), then Argon gas is injected to the machine. The microwaves heat the Argon ions to initiate ionization and plasma is produced. A dielectric wall is used inside the rectangular waveguide to isolate the plasma machine and maintain vacuum. Even though the dielectric will not block the wave propagation, some absorption of microwaves will occur. This absorption will cause reflection, reducing the efficiency of the power transfer. Typically a thin layer of Teflon is used, but measurements using this dielectric show a significant reflection of power back to the generator. Due to the high-power nature of the generator (5KW), this mismatch is not desirable. An electromagnetic field solver based on the Finite Difference Time Domain Method(FDTD) is used to model the rectangular waveguide connection. The characteristic impedance of the simulation is compared with the analytical formula expression and a good agreement is obtain. Furthermore the Teflon-loaded guide is modeled using the above program and the input impedance is computed. The reflection coefficient is calculated based on the transmission line theory with the characteristic and input impedances. Based on the simulation results it is possible to optimize the thickness, shape and dielectric constant of the material, in order to seal the connection with a better match.

  4. Thoracic artificial lung impedance studies using computational fluid dynamics and in vitro models.

    PubMed

    Schewe, Rebecca E; Khanafer, Khalil M; Orizondo, Ryan A; Cook, Keith E

    2012-03-01

    Current thoracic artificial lungs (TALs) possess blood flow impedances greater than the natural lungs, resulting in abnormal pulmonary hemodynamics when implanted. This study sought to reduce TAL impedance using computational fluid dynamics (CFD). CFD was performed on TAL models with inlet and outlet expansion and contraction angles, θ, of 15°, 45°, and 90°. Pulsatile blood flow was simulated for flow rates of 2-6 L/min, heart rates of 80 and 100 beats/min, and inlet pulsatilities of 3.75 and 2. Pressure and flow data were used to calculate the zeroth and first harmonic impedance moduli, Z(0) and Z(1), respectively. The 45° and 90° models were also tested in vitro under similar conditions. CFD results indicate Z(0) increases as stroke volume and θ increase. At 4 L/min, 100 beats/min, and a pulsatility of 3.75, Z(0) was 0.47, 0.61, and 0.79 mmHg/(L/min) for the 15°, 45°, and 90° devices, respectively. Velocity band and vector plots also indicate better flow patterns in the 45° device. At the same conditions, in vitro Z (0) were 0.69 ± 0.13 and 0.79 ± 0.10 mmHg/(L/min), respectively, for the 45° and 90° models. These Z(0) are 65% smaller than previous TAL designs. In vitro, Z(1) increased with flow rate but was small and unlikely to significantly affect hemodynamics. The optimal design for flow patterns and low impedance was the 45° model. PMID:22009316

  5. Effect of Yttrium Doping in Barium Zirconium Titanate Ceramics: A Structural, Impedance, and Modulus Spectroscopy Study

    NASA Astrophysics Data System (ADS)

    Badapanda, Tanmaya; Cavalcante, Laécio Santos; da Luz, Geraldo Eduardo; Batista, Nouga Cardoso; Anwar, Shahid; Longo, Elson

    2013-09-01

    In the current article, we studied the effect of yttrium [Y3+] ions' substitution on the structure and electric behavior of barium zirconate titanate (BZT) ceramics with a general formula [Ba1- x Y2 x/3](Zr0.25Ti0.75)O3 (BYZT) with [ x = 0, 0.025, and 0.05] which were prepared by the solid-state reaction method. X-ray diffraction patterns indicate that these ceramics have a single phase with a perovskite-type cubic structure. Rietveld refinement data confirmed [BaO12], [ZrO6], [TiO6], and [YO6] clusters in the cubic lattice. The Y3+ ions' effects on the electric conductivity behavior of BZT ceramics as a function of temperature and frequency are described, which are based on impedance spectroscopy analyses. The complex impedance plots display a double semicircle which highlights the influences of grain and grain boundary on the ceramics. Impedance analyses showed that the resistance decreased with the increasing temperature and resulted in a negative temperature coefficient of the resistance property in all compositions. Modulus plots represent a non-Debye-type dielectric relaxation which is related to the grain and grain boundary as well as temperature-dependent electric relaxation phenomenon and an enhancement in the mobility barrier by Y3+ ions. Moreover, the electric conductivity increases with the replacement of Ba2+ by Y3+ ions may be due to the rise in oxygen vacancies.

  6. Study of the Dynamics of Transcephalic Cerebral Impedance Data during Cardio-Vascular Surgery

    NASA Astrophysics Data System (ADS)

    Atefi, S. R.; Seoane, F.; Lindecrantz, K.

    2013-04-01

    Postoperative neurological deficits are one of the risks associated with cardio vascular surgery, necessitating development of new techniques for cerebral monitoring. In this study an experimental observation regarding the dynamics of transcephalic Electrical Bioimpedance (EBI) in patients undergoing cardiac surgery with and without extracorporeal circulation (ECC) was conducted to investigate the potential use of electrical Bioimpedance for cerebral monitoring in cardio vascular surgery. Tetrapolar transcephalic EBI measurements at single frequency of 50 kHz were recorded prior to and during cardio vascular surgery. The obtained results show that the transcephalic impedance decreases in both groups of patients as operation starts, however slight differences in these two groups were also observed with the cerebral impedance reduction in patients having no ECC being less common and not as pronounced as in the ECC group. Changes in the cerebral impedance were in agreement with changes of haematocrit and temperature. The origin of EBI changes is still unexplained however these results encourage us to continue investigating the application of electrical bioimpedance cerebral monitoring clinically.

  7. Study of corrosion of super martensitic stainless steel under alternating current in artificial seawater with electrochemical impedance spectroscopy

    SciTech Connect

    Reyes, T.; Bhola, S.; Olson, D. L.; Mishra, B.

    2011-06-23

    The assessment of corrosion requires the use of tools able to quantify the corrosion but often times also qualify it. Electrochemical Impedance Spectroscopy (EIS) is a laboratory tool that can provide both qualification and quantification of corrosion. EIS was successfully used to compare the thickness of the corrosion products formed during the application of different alternating current (AC) densities as well as to characterize pitting. When EIS is applied at the open circuit potential, the technique is nondestructive and predicts the corrosion behavior of the electrode. It can also be used at cathodic potentials while still being nondestructive, providing information about the electrode reaction kinetics, diffusion and electrical double layer.

  8. Fabrication and study of AC electro-osmotic micropumps

    NASA Astrophysics Data System (ADS)

    Guo, Xin

    In this thesis, microelectrode arrays of micropumps have been designed, fabricated and characterized for transporting microfluid by AC electro-osmosis (ACEO). In particular, the 3D stepped electrode design which shows superior performance to others in literature is adopted for making micropumps, and the performance of such devices has been studied and explored. A novel fabrication process has also been developed in the work, realizing 3D stepped electrodes on a flexible substrate, which is suitable for biomedical use, for example glaucoma implant. There are three major contributions to ACEO pumping in the work. First, a novel design of 3D "T-shaped" discrete electrode arrays was made using PolyMUMPsRTM process. The breakthrough of this work was discretizing the continuous 3D stepped electrodes which were commonly seen in the past research. The "T-shaped" electrodes did not only create ACEO flows on the top surfaces of electrodes but also along the side walls between separated electrodes. Secondly, four 3D stepped electrode arrays were designed, fabricated and tested. It was found from the experiment that PolyMUMPsRTM ACEO electrodes usually required a higher driving voltage than gold electrodes for operation. It was also noticed that a simulation based on the modified model taking into account the surface oxide of electrodes showed a better agreement with the experimental results. It thus demonstrated the possibility that the surface oxide of electrodes had impact on fluidic pumping. This methodology could also be applied to metal electrodes with a native oxide layer such as titanium and aluminum. Thirdly, a prototype of the ACEO pump with 3D stepped electrode arrays was first time realized on a flexible substrate using Kapton polyimide sheets and packaged with PDMS encapsulants. Comprehensive experimental testing was also conducted to evaluate the mechanical properties as well as the pumping performance. The experimental findings indicated that this fabrication

  9. Dielectric properties and study of AC electrical conduction mechanisms by non-overlapping small polaron tunneling model in Bis(4-acetylanilinium) tetrachlorocuprate(II) compound

    NASA Astrophysics Data System (ADS)

    Abkari, A.; Chaabane, I.; Guidara, K.

    2016-09-01

    In the present work, the synthesis and characterization of the Bis(4-acetylanilinium) tetrachlorocuprate(II) compound are presented. The structure of this compound is analyzed by X-ray diffraction which confirms the formation of single phase and is in good agreement the literature. Indeed, the Thermo gravimetric Analysis (TGA) shows that the decomposition of the compound is observed in the range of 420-520 K. However, the differential thermal analysis (DTA) indicates the presence of a phase transition at T=363 k. Furthermore, the dielectric properties and AC conductivity were studied over a temperature range (338-413 K) and frequency range (200 Hz-5 MHz) using complex impedance spectroscopy. Dielectric measurements confirmed such thermal analyses by exhibiting the presence of an anomaly in the temperature range of 358-373 K. The complex impedance plots are analyzed by an electrical equivalent circuit consisting of resistance, constant phase element (CPE) and capacitance. The activation energy values of two distinct regions are obtained from log σT vs 1000/T plot and are found to be E=1.27 eV (T<363 K) and E=1.09 eV (363 Kac conductivity, σac, has been analyzed by Jonscher's universal power law σ(ω)=σdc+Aωs. The value of s is to be temperature-dependent, which has a tendency to increase with temperature and the non-overlapping small polaron tunneling (NSPT) model is the most applicable conduction mechanism in the title compound. Complex impedance spectra of [C8H10NO]2CuCl4 at different temperatures.

  10. Theoretical and experimental study of the input impedance of the cylindrical cavity-backed rectangular slot antennas

    NASA Technical Reports Server (NTRS)

    Li, Ming-Yi; Hummer, Kenneth A.; Chang, Kai

    1991-01-01

    The authors study the input impedance of a cylindrical cavity-backed slot antenna based on mode matching and the complex Poynting theorem. Two cavity-backed slot antennas were fabricated to verify the theory. The numerical results agree very well with measurements. Two resonant frequencies were found from the input impedance. One resonant frequency is attributed to the rectangular slot and the other is due to the cavity. The slot length controls the first resonant frequency and has a much stronger effect on the input impedance at the antenna operating frequency as compared with the cavity length.

  11. Body fat measurement by bioelectrical impedance and air displacement plethysmography: a cross-validation study to design bioelectrical impedance equations in Mexican adults

    PubMed Central

    Macias, Nayeli; Alemán-Mateo, Heliodoro; Esparza-Romero, Julián; Valencia, Mauro E

    2007-01-01

    Background The study of body composition in specific populations by techniques such as bio-impedance analysis (BIA) requires validation based on standard reference methods. The aim of this study was to develop and cross-validate a predictive equation for bioelectrical impedance using air displacement plethysmography (ADP) as standard method to measure body composition in Mexican adult men and women. Methods This study included 155 male and female subjects from northern Mexico, 20–50 years of age, from low, middle, and upper income levels. Body composition was measured by ADP. Body weight (BW, kg) and height (Ht, cm) were obtained by standard anthropometric techniques. Resistance, R (ohms) and reactance, Xc (ohms) were also measured. A random-split method was used to obtain two samples: one was used to derive the equation by the "all possible regressions" procedure and was cross-validated in the other sample to test predicted versus measured values of fat-free mass (FFM). Results and Discussion The final model was: FFM (kg) = 0.7374 * (Ht2 /R) + 0.1763 * (BW) - 0.1773 * (Age) + 0.1198 * (Xc) - 2.4658. R2 was 0.97; the square root of the mean square error (SRMSE) was 1.99 kg, and the pure error (PE) was 2.96. There was no difference between FFM predicted by the new equation (48.57 ± 10.9 kg) and that measured by ADP (48.43 ± 11.3 kg). The new equation did not differ from the line of identity, had a high R2 and a low SRMSE, and showed no significant bias (0.87 ± 2.84 kg). Conclusion The new bioelectrical impedance equation based on the two-compartment model (2C) was accurate, precise, and free of bias. This equation can be used to assess body composition and nutritional status in populations similar in anthropometric and physical characteristics to this sample. PMID:17697388

  12. Electron Impedances

    SciTech Connect

    P Cameron

    2011-12-31

    It is only recently, and particularly with the quantum Hall effect and the development of nanoelectronics, that impedances on the scale of molecules, atoms and single electrons have gained attention. In what follows the possibility that characteristic impedances might be defined for the photon and the single free electron is explored is some detail, the premise being that the concepts of electrical and mechanical impedances are relevant to the elementary particle. The scale invariant quantum Hall impedance is pivotal in this exploration, as is the two body problem and Mach's principle.

  13. Mechanistic insights into UV-induced electron transfer from PCBM to titanium oxide in inverted-type organic thin film solar cells using AC impedance spectroscopy.

    PubMed

    Kuwabara, Takayuki; Iwata, Chiaki; Yamaguchi, Takahiro; Takahashi, Kohshin

    2010-08-01

    An inverted organic bulk-heterojunction solar cell containing amorphous titanium oxide (TiOx) as an electron collection electrode with the structure ITO/TiO(x)/[6,6]-phenyl C(61) butyric acid methyl ester (PCBM): regioregular poly(3-hexylthiophene) (P3HT)/poly(3,4-ethylenedioxylenethiophene):poly(4-styrene sulfonic acid)/Au (TiO(x) cell) was fabricated. Its complicated photovoltaic properties were investigated by photocurrent-voltage and alternating current impedance spectroscopy measurements. The TiO(x) cell required a significant amount of time (approximately 60 min) to reach its maximum power conversion efficiency (PCE) of 2.6%. To investigate the reason for this slow photoresponse, we investigated the influences of UV light and water molecules adsorbed on the TiO(x) layer. Surface treatment of the TiO(x) cell with water induced a rapid photoresponse and enhanced the performance, giving a PCE of 2.97%. However, the durability of the treated cell was considerably inferior that of the untreated cell because of UV-induced photodegradation. The cause of the rapid photoresponse of the treated cell was attributed to the formation of hydrogen bonds between adsorbed water molecules and carbonyl oxygen atoms in PCBM close to the TiO(x) surface. When the TiO(x) surface was positively charged by UV-induced holes, the carbonyl oxygen in PCBM close to the TiO(x) surface can quickly join to the TiO(x) surface, rapidly transporting photogenerated electrons from PCBM to TiO(x) in competition with the photocatalyzed degradation. The experimental results suggested that the slow photoresponse of the untreated TiO(x) cell was because the morphology of the photoactive organic layer changed gradually upon irradiation to improve the transport of photocarriers at the TiO(x)/PCBM:P3HT interface.

  14. Gastroesophageal reflux in asymptomatic obese subjects: An esophageal impedance-pH study

    PubMed Central

    Akyüz, Filiz; Uyanıkoglu, Ahmet; Ermis, Fatih; Arıcı, Serpil; Akyüz, Ümit; Baran, Bülent; Pinarbasi, Binnur; Gul, Nurdan

    2015-01-01

    AIM: To investigate the relationship between reflux and body mass index (BMI) in the asymptomatic obese population using the impedance-pH technique. METHODS: Gastroesophageal reflux is frequent in the obese population. However, the relationship between acid reflux and BMI in asymptomatic obese people is unclear. Forty-six obese (BMI > 25 kg/m2) people were enrolled in this prospective study. We evaluated the demographic findings and 24-h impedance pH values of the whole group. Gas, acid (pH < 4), weak acid (pH = 4-7) and weak alkaline (pH ≥ 7) reflux parameters were analyzed. RESULTS: The mean age of patients was 49.47 ± 12.24 years, and half of them were men. The mean BMI was 30.64 ± 3.95 kg/m2 (25.14-45.58 kg/m2). BMI of 23 was over 30 kg/m2. Seventeen patients had a comorbidity (hypertension, diabetes mellitus, or ischemic heart disease). Endoscopic examination revealed esophagitis in 13 of the 28 subjects (10 Grade A, 3 Grade B). The subjects were divided into two groups according to BMI (< 30 and > 30 kg/m2). Demographic and endoscopic findings, and impedance results were similar in these two groups. However, there was a positive correlation between BMI and total and supine pH < 4 episodes (P = 0.002, r = 0.414; P = 0.000, r = 0.542), pH < 4 reflux time (P = 0.015, r = 0.319; P = 0.003, r = 0.403), and DeMeester score (P = 0.012, r = 0.333). CONCLUSION: Acid reflux is correlated with BMI in asymptomatic obese individuals. PMID:25780302

  15. Using two-dimensional impedance maps to study weak scattering in sparse random media.

    PubMed

    Luchies, Adam C; Oelze, Michael L

    2016-04-01

    Impedance maps (ZMs) have been proposed as a tool for modeling acoustic properties of tissue microstructure. Three-dimensional (3D) ZMs are constructed from a series of adjacent histological tissue slides that have been stained to emphasize acoustic impedance structures. The power spectrum of a 3DZM can be related to the ultrasound backscatter coefficient, which can be further reduced to a form factor. The goal of this study is to demonstrate the ability to estimate form factors using two-dimensional (2D) ZMs instead of 3DZMs, which have reduced computational and financial cost. The proposed method exploits the properties of isotropic media to estimate the correlation coefficient from slices before estimating the 3D volume power spectrum. Simulated sparse collections of objects were used to study the method by comparing the results obtained using 2DZMs to those predicted by theory. 2DZM analysis was conducted on normal rabbit liver histology and compared to 3DZM analysis of the same histology. The mean percent error between effective scatterer diameter estimates from 2DZMs and 3DZMs of rabbit liver histology was <10% when using three 2DZMs. The results suggest that 2DZMs are a feasible alternative to 3DZMs when estimating form factors for sparse collections of objects. PMID:27106304

  16. Intergrain connectivity of MgB{sub 2} ceramics studied by impedance analysis

    SciTech Connect

    Wang, C. C.; Wang, C.; Zeng, R.; Dou, S. X.

    2010-07-15

    First, by using of the conventional Rowell analysis, we demonstrated that the addition of nano BN particles can effectively eliminate MgO and pores in MgB{sub 2} resulting in a very high density and good connectivity of BN-doped MgB{sub 2}. Then, another method--low-frequency dielectric impedance analysis--was introduced to characterize the properties of the grain boundaries of MgB{sub 2}. A comparative impedance study was performed in the frequency range from 100 Hz to 100 MHz on pure and nano BN-doped MgB{sub 2}. The study revealed some following interesting results: (1) a dielectric resonance around frequency of 10{sup 8} in both samples was observed, which was argued to be related to an inductance-capacitance and (2) the pure sample has two dielectric relaxations originating from intergrains, while the doped sample has only one intergranular contribution. This convinces that the electric connectivity of the doped sample is really improved by the addition of nano BN particles. Our results indicate that dielectric technique may be a useful tool to characterize the grain boundary properties and grain boundary-related properties of MgB{sub 2}.

  17. Application of electrochemical impedance spectroscopy: A phase behavior study of babassu biodiesel-based microemulsions.

    PubMed

    Pereira, Thulio C; Conceição, Carlos A F; Khan, Alamgir; Fernandes, Raquel M T; Ferreira, Maira S; Marques, Edmar P; Marques, Aldaléa L B

    2016-11-01

    Microemulsions are thermodynamically stable systems of two immiscible liquids, one aqueous and the other of organic nature, with a surfactant and/or co-surfactant adsorbed in the interface between the two phases. Biodiesel-based microemulsions, consisting of alkyl esters of fatty acids, open a new means of analysis for the application of electroanalytical techniques, and is advantageous as it eliminates the required pre-treatment of a sample. In this work, the phase behaviours of biodiesel-based microemulsions were investigated through the electrochemical impedance spectroscopy (EIS) technique. We observed thatan increase in the amount of biodiesel in the microemulsion formulation increases the resistance to charge transfer at the interface. Also, the electrical conductivity measurements revealed that a decrease or increase in electrical properties depends on the amount of biodiesel. EIS studies of the biodiesel-based microemulsion samples showed the presence of two capacitive arcs: one high-frequency and the other low-frequency. Thus, the formulation of microemulsions plays an important role in estimating the electrical properties through the electrochemical impedance spectroscopy technique.

  18. Studies of phase transition and impedance behavior of Ba(Zr, Ti)O3 ceramics

    NASA Astrophysics Data System (ADS)

    Sateesh, P.; Omprakash, J.; Kumar, G. S.; Prasad, G.

    2015-02-01

    Ceramic samples of Barium Zirconium Titanate (BaZrxTi1-xO3 (BZT)) were synthesized by conventional solid-state reaction method with different concentrations of x(= 0.05 (BZT1), 0.10 (BZT2), 0.15 (BZT3), 0.20 (BZT4), 0.25 (BZT5), 0.30 (BZT6)). Phase confirmation of the samples was done by X-ray diffraction (XRD) technique. All the compositions are in cubic structure. XRD pattern was recorded for samples sintered at different sintering temperatures. Lattice parameters increased with addition of Zr+4. Doping with Zr+4 into Barium titanate resulted in interesting changes of electrical properties (dielectric, impedance and ferroelectiricity). The strong influence of Zr doping on the phase transition characteristics of the BZT ceramics was studied from the dielectric response of the samples. Diffusivity of phase transition of the BZT ceramic samples increase with Zr+4 concentration, indicating changes from normal to diffuse transition to relaxor phase transition behavior. Impedance spectroscopy reveals the presence of temperature-dependent grain, grain boundary effects. Polarization-Electricfield (PE) loop measurements are also done on the samples.

  19. Application of electrochemical impedance spectroscopy: A phase behavior study of babassu biodiesel-based microemulsions

    NASA Astrophysics Data System (ADS)

    Pereira, Thulio C.; Conceição, Carlos A. F.; Khan, Alamgir; Fernandes, Raquel M. T.; Ferreira, Maira S.; Marques, Edmar P.; Marques, Aldaléa L. B.

    2016-11-01

    Microemulsions are thermodynamically stable systems of two immiscible liquids, one aqueous and the other of organic nature, with a surfactant and/or co-surfactant adsorbed in the interface between the two phases. Biodiesel-based microemulsions, consisting of alkyl esters of fatty acids, open a new means of analysis for the application of electroanalytical techniques, and is advantageous as it eliminates the required pre-treatment of a sample. In this work, the phase behaviours of biodiesel-based microemulsions were investigated through the electrochemical impedance spectroscopy (EIS) technique. We observed thatan increase in the amount of biodiesel in the microemulsion formulation increases the resistance to charge transfer at the interface. Also, the electrical conductivity measurements revealed that a decrease or increase in electrical properties depends on the amount of biodiesel. EIS studies of the biodiesel-based microemulsion samples showed the presence of two capacitive arcs: one high-frequency and the other low-frequency. Thus, the formulation of microemulsions plays an important role in estimating the electrical properties through the electrochemical impedance spectroscopy technique.

  20. Application of electrochemical impedance spectroscopy: A phase behavior study of babassu biodiesel-based microemulsions.

    PubMed

    Pereira, Thulio C; Conceição, Carlos A F; Khan, Alamgir; Fernandes, Raquel M T; Ferreira, Maira S; Marques, Edmar P; Marques, Aldaléa L B

    2016-11-01

    Microemulsions are thermodynamically stable systems of two immiscible liquids, one aqueous and the other of organic nature, with a surfactant and/or co-surfactant adsorbed in the interface between the two phases. Biodiesel-based microemulsions, consisting of alkyl esters of fatty acids, open a new means of analysis for the application of electroanalytical techniques, and is advantageous as it eliminates the required pre-treatment of a sample. In this work, the phase behaviours of biodiesel-based microemulsions were investigated through the electrochemical impedance spectroscopy (EIS) technique. We observed thatan increase in the amount of biodiesel in the microemulsion formulation increases the resistance to charge transfer at the interface. Also, the electrical conductivity measurements revealed that a decrease or increase in electrical properties depends on the amount of biodiesel. EIS studies of the biodiesel-based microemulsion samples showed the presence of two capacitive arcs: one high-frequency and the other low-frequency. Thus, the formulation of microemulsions plays an important role in estimating the electrical properties through the electrochemical impedance spectroscopy technique. PMID:27276278

  1. Combined Impedance Probe and Langmuir Probe Studies of the Low-Latitude E Region

    NASA Technical Reports Server (NTRS)

    Rowland, D. E.; Pfaff, R. F.; Steigies, C. T.

    2008-01-01

    The EQUIS-2 sounding rocket and radar campaign, launched from Kwajalein Atoll in 2004, included a mission to study low-latitude irregularities and electrodynamics, led by NASA GSFC. This mission included two instrumented rockets launched into the nighttime E region (apogee near 120 km), which included comprehensive electrodynamics and neutral density instrumentation. These rockets carried the first of a new generation of impedance probes, that utilize a wide-band drive signal to simultaneously measure the impedance of an antenna in a plasma as a function of frequency from 7 kEIz to 4 MHz. at a rapid cadence. This technique promises to permit true plasma spectroscopy, and resulted in the identification of multiple plasma resonances and accurate measurements of the plasma density, even in the low density nighttime E region. We present analyses of the technique and resulting spectra, and show how these data may be combined with fixed-bias Langmuir Probe data to infer the temperature structure of the E region as well as providing accurate absolute calibrations for the very high time resolution fixed-bias probe data. The data is shown to agree well with data from ionosonde, the ALTAIR radar, and the Peruvian beacon experiment.

  2. Bio-impedance detector for Staphylococcus aureus exposed to magnetic fields

    NASA Astrophysics Data System (ADS)

    Younis Yacoob Aldosky, Haval; Barwari, Waleed Jameel Omar; Salih Al-mlaly, Janan M.

    2012-12-01

    Rapid detection of viability and growth of pathogenic microorganisms is very important in many applications such as food and drug production, health care, and national defense. Measurements on the electrical characteristics of cells have been used successfully in the past to detect many different physiological events. The effect of electromagnetic fields on the growth of bacteria (Staphylococcus aureus) was studied with the bio-impedance technique. The growth situations of bacteria in the absence and presence of different intensities of static and alternative magnetic fields were examined and analyzed. The results show that the impedance of bacteria fell in the presence of DC magnetic fields. In contrast the impedance increased when the bacteria were exposed to AC magnetic fields. Based on these results the bacterial growth indicated by the change in the impedance is inhibited under DC magnetic fields and enhanced under AC fields.

  3. AC/RF Superconductivity

    SciTech Connect

    Ciovati, Gianluigi

    2015-02-01

    This contribution provides a brief introduction to AC/RF superconductivity, with an emphasis on application to accelerators. The topics covered include the surface impedance of normal conductors and superconductors, the residual resistance, the field dependence of the surface resistance, and the superheating field.

  4. A study of gadolinia-doped ceria electrolyte by electrochemical impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Zhang, Lei; Liu, Feng; Brinkman, Kyle; Reifsnider, Kenneth L.; Virkar, Anil V.

    2014-02-01

    Samples of Gd2O3-doped CeO2 (GDC) were fabricated by sintering of powder compacts. Impedance spectra were measured from 400 °C to 675 °C in air by electrochemical impedance spectroscopy (EIS). Above ∼500 °C, high frequency arc was not semicircular but could be fitted with a constant phase element (CPE). Above ∼625 °C, high frequency arc could not be resolved due to a significant contribution from the inductive load. The impedance spectra were described using a simple equivalent circuit which included the leads/instrument impedance. The leads/instrument impedance was measured over a range of frequencies and temperatures. The high frequency part of the impedance after subtracting leads/instrument impedance could be resolved even at the highest measurement temperature and was described by a semicircle representative of transport across grain boundaries. From these measurements, grain and grain boundary resistivities were determined. The corresponding activation energies were 0.69 eV and 1.11 eV, respectively. The grain boundary capacitance was nearly independent of temperature. The present results show that grain boundary effects can be described by a resistor and a capacitor. Relevant equivalent circuit parameters were obtained from intercepts, maxima and minima in impedance diagrams.

  5. A new application of electrical impedance spectroscopy for measuring glucose metabolism: a phantom study

    NASA Astrophysics Data System (ADS)

    Dhurjaty, Sreeram; Qiu, Yuchen; Tan, Maxine; Liu, Hong; Zheng, Bin

    2015-03-01

    Glucose metabolism relates to biochemical processes in living organisms and plays an important role in diabetes and cancer-metastasis. Although many methods are available for measuring glucose metabolism-activities, from simple blood tests to positron emission tomography, currently there is no robust and affordable device that enables monitoring of glucose levels in real-time. In this study we tested feasibility of applying a unique resonance-frequency based electronic impedance spectroscopy (REIS) device that has been, recently developed to measure and monitor glucose metabolism levels using a phantom study. In this new testing model, a multi-frequency electrical signal sequence is applied and scanned through the subject. When the positive reactance of an inductor inside the device cancels out the negative reactance of the capacitance of the subject, the electrical impedance reaches a minimum value and this frequency is defined as the resonance frequency. The REIS system has a 24-bit analog-to-digital signal convertor and a frequency-resolution of 100Hz. In the experiment, two probes are placed inside a 100cc container initially filled with distilled water. As we gradually added liquid-glucose in increments of 1cc (250mg), we measured resonance frequencies and minimum electrical signal values (where A/D was normalized to a full scale of 1V). The results showed that resonance frequencies monotonously decreased from 243kHz to 178kHz, while the minimum voltages increased from 405mV to 793mV as the added amount of glucose increased from 0 to 5cc. The study demonstrated the feasibility of applying this new REIS technology to measure and/or monitor glucose levels in real-time in future.

  6. Crystal structure, NMR study, dielectric relaxation and AC conductivity of a new compound [Cd3(SCN)2Br6(C2H9N2)2]n

    NASA Astrophysics Data System (ADS)

    Saidi, K.; Kamoun, S.; Ayedi, H. Ferid; Arous, M.

    2013-11-01

    The crystal structure, the 13C NMR spectroscopy and the complex impedance have been carried out on [Cd3(SCN)2Br6(C2H9N2)2]n. Crystal structure shows a 2D polymeric network built up of two crystallographically independent cadmium atoms with two different octahedral coordinations. This compound exhibits a phase transition at (T=355±2 K) which has been characterized by differential scanning calorimetry (DSC), X-rays powder diffraction, AC conductivity and dielectric measurements. Examination of 13C CP/MAS line shapes shows indirect spin-spin coupling (14N and 13C) with a dipolar coupling constant of 1339 Hz. The AC conductivity of this compound has been carried out in the temperature range 325-376 K and the frequency range from 10-2 Hz to 10 MHz. The impedance data were well fitted to two equivalent electrical circuits. The results of the modulus study reveal the presence of two distinct relaxation processes. One, at low frequency side, is thermally activated due to the ionic conduction of the crystal and the other, at higher frequency side, gradually disappears when temperature reaches 355 K which is attributed to the localized dipoles in the crystal. Moreover, the temperature dependence of DC-conductivity in both phases follows the Arrhenius law and the frequency dependence of σ(ω,T) follows Jonscher's universal law. The near values of activation energies obtained from the conductivity data and impedance confirm that the transport is through the ion hopping mechanism.

  7. The Pt(111)/electrolyte interface under oxygen reduction reaction conditions: an electrochemical impedance spectroscopy study.

    PubMed

    Bondarenko, Alexander S; Stephens, Ifan E L; Hansen, Heine A; Pérez-Alonso, Francisco J; Tripkovic, Vladimir; Johansson, Tobias P; Rossmeisl, Jan; Nørskov, Jens K; Chorkendorff, Ib

    2011-03-01

    The Pt(111)/electrolyte interface has been characterized during the oxygen reduction reaction (ORR) in 0.1 M HClO(4) using electrochemical impedance spectroscopy. The surface was studied within the potential region where adsorption of OH* and O* species occur without significant place exchange between the adsorbate and Pt surface atoms (0.45-1.15 V vs RHE). An equivalent electric circuit is proposed to model the Pt(111)/electrolyte interface under ORR conditions within the selected potential window. This equivalent circuit reflects three processes with different time constants, which occur simultaneously during the ORR at Pt(111). Density functional theory (DFT) calculations were used to correlate and interpret the results of the measurements. The calculations indicate that the coadsorption of ClO(4)* and Cl* with OH* is unlikely. Our analysis suggests that the two-dimensional (2D) structures formed in O(2)-free solution are also formed under ORR conditions. PMID:21244087

  8. Numerical Study of Three Dimensional Effects in Longitudinal Space-Charge Impedance

    SciTech Connect

    Halavanau, A.; Piot, P.

    2015-06-01

    Longitudinal space-charge (LSC) effects are generally considered as detrimental in free-electron lasers as they can seed instabilities. Such “microbunching instabilities” were recently shown to be potentially useful to support the generation of broadband coherent radiation pulses [1, 2]. Therefore there has been an increasing interest in devising accelerator beamlines capable of sustaining this LSC instability as a mechanism to produce a coherent light source. To date most of these studies have been carried out with a one-dimensional impedance model for the LSC. In this paper we use a N-body “Barnes-Hut” algorithm [3] to simulate the 3D space charge force in the beam combined with elegant [4] and explore the limitation of the 1D model often used

  9. Degradation of Bilayer Organic Light-Emitting Diodes Studied by Impedance Spectroscopy.

    PubMed

    Sato, Shuri; Takata, Masashi; Takada, Makoto; Naito, Hiroyoshi

    2016-04-01

    The degradation of bilayer organic light-emitting diodes (OLEDs) with a device structure of N,N'-di(1-naphthyl)-N,N'-diphenylbenzidine (α-NPD) (hole transport layer) and tris-(8-hydroxyquinolate)aluminum (Alq3) (emissive layer and electron transport layer) has been studied by impedance spectroscopy and device simulation. Two modulus peaks are found in the modulus spectra of the OLEDs below the electroluminescence threshold. After aging of the OLEDs, the intensity of electroluminescence is degraded and the modulus peak due to the Alq3 layer is shifted to lower frequency, indicating that the resistance of the Alq3 layer is increased. Device simulation reveals that the increase in the resistance of the Alq3 layer is due to the decrease in the electron mobility in the Alq3 layer. PMID:27451634

  10. A study of some features of ac and dc electric power systems for a space station

    NASA Technical Reports Server (NTRS)

    Hanania, J. I.

    1983-01-01

    This study analyzes certain selected topics in rival dc and high frequency ac electric power systems for a Space Station. The interaction between the Space Station and the plasma environment is analyzed, leading to a limit on the voltage for the solar array and a potential problem with resonance coupling at high frequencies. Certain problems are pointed out in the concept of a rotary transformer, and further development work is indicated in connection with dc circuit switching, special design of a transmission conductor for the ac system, and electric motors. The question of electric shock hazards, particularly at high frequency, is also explored. and a problem with reduced skin resistance and therefore increased hazard with high frequency ac is pointed out. The study concludes with a comparison of the main advantages and disadvantages of the two rival systems, and it is suggested that the choice between the two should be made after further studies and development work are completed.

  11. Impedance calculation for ferrite inserts

    SciTech Connect

    Breitzmann, S.C.; Lee, S.Y.; Ng, K.Y.; /Fermilab

    2005-01-01

    Passive ferrite inserts were used to compensate the space charge impedance in high intensity space charge dominated accelerators. They study the narrowband longitudinal impedance of these ferrite inserts. they find that the shunt impedance and the quality factor for ferrite inserts are inversely proportional to the imaginary part of the permeability of ferrite materials. They also provide a recipe for attaining a truly passive space charge impedance compensation and avoiding narrowband microwave instabilities.

  12. Study of Electrical Properties in SHI Irradiated 6H-SiC Crystals using Low Temperature Impedance Spectroscopy

    NASA Astrophysics Data System (ADS)

    Viswanathan, E.; Murugaraj, R.; Selvakumar, S.; Kanjilal, D.; Sivaji, K.

    2011-07-01

    In the present work, low temperature impedance measurements were made on the pristine and Ag12+ ions irradiated 6H-SiC samples. The conductivity properties were studied at low temperature. The activation energies were calculated from the Arrhenius plot of d.c conductivity and impedance relaxation time. The activation energy was comparatively higher for the irradiated samples and found to be electronic conduction. From the study we observe the lower conductivity values exhibited for 300 K irradiated sample due to severe damage than the 80 K irradiated sample. The damage production mechanism and the change in electrical properties are discussed.

  13. Simulational studies of epitaxial semiconductor superlattices: Quantum dynamical phenomena in ac and dc electric fields

    SciTech Connect

    Reynolds, J.

    1997-10-08

    Using high-accuracy numerical methods the author investigates the dynamics of independent electrons in both ideal and realistic superlattices subject to arbitrary ac and/or dc electric fields. For a variety of superlattice potentials, optically excited initial wave packets, and combinations of ac and dc electric fields, he numerically solves the time-dependent Schroedinger equation. In the case of ideal periodic superlattice potentials, he investigates a long list of dynamical phenomena involving multiple miniband transitions and time-dependent electric fields. These include acceleration effects associated with interminiband transitions in strong fields, Zener resonances between minibands, dynamic localization with ac fields, increased single-miniband transport with an auxiliary resonant ac field, and enhanced or suppressed interminiband probability exchange using an auxiliary ac field. For all of the cases studied, the resulting time-dependent wave function is analyzed by projecting the data onto convenient orthonormal bases. This allows a detailed comparison with approximately analytic treatments. In an effort to explain the rapid decay of experimentally measured Bloch oscillation (BO) signals the author incorporates a one-dimensional representation of interface roughness (IR) into their superlattice potential. He shows that as a result of IR, the electron dynamics can be characterized in terms of many discrete, incommensurate frequencies near the Block frequency. Chapters 2, 3, 4 and 5 have been removed from this report and will be processed separately.

  14. Marketing information system online design for craftsmen small medium enterprises (case study: craftsmen ac)

    NASA Astrophysics Data System (ADS)

    Fitriana, Rina; Kurniawan, Wawan; Barlianto, Anung; Adriansyah Putra, Rizki

    2016-02-01

    AC is small and medium enterprises which is engaged in the field of crafts. This SME (Small Medium Enterprise) didn't have an integrated information system for managing sales. This research aims to design a marketing Information system online as applications that built as web base. The integrated system is made to manage sales and expand its market share. This study uses a structured analysis and design in its approach to build systems and also implemented a marketing framework of STP (Segmentation, Targeting, Positioning) and 4P (Price, Product, Place, Promotion) to obtain market analysis. The main market target customer craftsmen AC is women aged 13 years to 35 years. The products produced by AC are shoes, brooch, that are typical of the archipelago. The prices is range from Rp. 2000 until Rp. 400.000. Marketing information system online can be used as a sales transaction document, promoting the goods, and for customer booking products.

  15. A PARAMETRIC STUDY OF BCS RF SURFACE IMPEDANCE WITH MAGNETIC FIELD USING THE XIAO CODE

    SciTech Connect

    Reece, Charles E.; Xiao, Binping

    2013-09-01

    A recent new analysis of field-dependent BCS rf surface impedance based on moving Cooper pairs has been presented.[1] Using this analysis coded in Mathematica TM, survey calculations have been completed which examine the sensitivities of this surface impedance to variation of the BCS material parameters and temperature. The results present a refined description of the "best theoretical" performance available to potential applications with corresponding materials.

  16. Study of High-Frequency Impedance of Small-Angle Tapers and Collimators

    SciTech Connect

    Stupakov, Gennady; Podobedov, B.; /Brookhaven

    2010-06-04

    Collimators and transitions in accelerator vacuum chambers often include small-angle tapering to lower the wakefields generated by the beam. While the low-frequency impedance is well described by Yokoya's formula (for axisymmetric geometry), much less is known about the behavior of the impedance in the high frequency limit. In this paper we develop an analytical approach to the highfrequency regime for round collimators and tapers. Our analytical results are compared with computer simulations using the code ECHO.

  17. Exploring How Substance Use Impedes Engagement along the HIV Care Continuum: A Qualitative Study

    PubMed Central

    Gwadz, Marya; de Guzman, Rebecca; Freeman, Robert; Kutnick, Alexandra; Silverman, Elizabeth; Leonard, Noelle R.; Ritchie, Amanda Spring; Muñoz-Plaza, Corinne; Salomon, Nadim; Wolfe, Hannah; Hilliard, Christopher; Cleland, Charles M.; Honig, Sylvie

    2016-01-01

    Drug use is associated with low uptake of HIV antiretroviral therapy (ART), an under-studied step in the HIV care continuum, and insufficient engagement in HIV primary care. However, the specific underlying mechanisms by which drug use impedes these HIV health outcomes are poorly understood. The present qualitative study addresses this gap in the literature, focusing on African-American/Black and Hispanic persons living with HIV (PLWH) who had delayed, declined, or discontinued ART and who also were generally poorly engaged in health care. Participants (N = 37) were purposively sampled from a larger study for maximum variation on HIV indices. They engaged in 1–2 h audio-recorded in-depth semi-structured interviews on HIV histories guided by a multilevel social-cognitive theory. Transcripts were analyzed using a systematic content analysis approach. Consistent with the existing literature, heavy substance use, but not casual or social use, impeded ART uptake, mainly by undermining confidence in medication management abilities and triggering depression. The confluence of African-American/Black or Hispanic race/ethnicity, poverty, and drug use was associated with high levels of perceived stigma and inferior treatment in health-care settings compared to their peers. Furthermore, providers were described as frequently assuming participants were selling their medications to buy drugs, which strained provider–patient relationships. High levels of medical distrust, common in this population, created fears of ART and of negative interactions between street drugs and ART, but participants could not easily discuss this concern with health-care providers. Barriers to ART initiation and HIV care were embedded in other structural- and social-level challenges, which disproportionately affect low-income African-American/Black and Hispanic PLWH (e.g., homelessness, violence). Yet, HIV management was cyclical. In collaboration with trusted providers and ancillary staff

  18. Exploring How Substance Use Impedes Engagement along the HIV Care Continuum: A Qualitative Study.

    PubMed

    Gwadz, Marya; de Guzman, Rebecca; Freeman, Robert; Kutnick, Alexandra; Silverman, Elizabeth; Leonard, Noelle R; Ritchie, Amanda Spring; Muñoz-Plaza, Corinne; Salomon, Nadim; Wolfe, Hannah; Hilliard, Christopher; Cleland, Charles M; Honig, Sylvie

    2016-01-01

    Drug use is associated with low uptake of HIV antiretroviral therapy (ART), an under-studied step in the HIV care continuum, and insufficient engagement in HIV primary care. However, the specific underlying mechanisms by which drug use impedes these HIV health outcomes are poorly understood. The present qualitative study addresses this gap in the literature, focusing on African-American/Black and Hispanic persons living with HIV (PLWH) who had delayed, declined, or discontinued ART and who also were generally poorly engaged in health care. Participants (N = 37) were purposively sampled from a larger study for maximum variation on HIV indices. They engaged in 1-2 h audio-recorded in-depth semi-structured interviews on HIV histories guided by a multilevel social-cognitive theory. Transcripts were analyzed using a systematic content analysis approach. Consistent with the existing literature, heavy substance use, but not casual or social use, impeded ART uptake, mainly by undermining confidence in medication management abilities and triggering depression. The confluence of African-American/Black or Hispanic race/ethnicity, poverty, and drug use was associated with high levels of perceived stigma and inferior treatment in health-care settings compared to their peers. Furthermore, providers were described as frequently assuming participants were selling their medications to buy drugs, which strained provider-patient relationships. High levels of medical distrust, common in this population, created fears of ART and of negative interactions between street drugs and ART, but participants could not easily discuss this concern with health-care providers. Barriers to ART initiation and HIV care were embedded in other structural- and social-level challenges, which disproportionately affect low-income African-American/Black and Hispanic PLWH (e.g., homelessness, violence). Yet, HIV management was cyclical. In collaboration with trusted providers and ancillary staff

  19. Exploring How Substance Use Impedes Engagement along the HIV Care Continuum: A Qualitative Study.

    PubMed

    Gwadz, Marya; de Guzman, Rebecca; Freeman, Robert; Kutnick, Alexandra; Silverman, Elizabeth; Leonard, Noelle R; Ritchie, Amanda Spring; Muñoz-Plaza, Corinne; Salomon, Nadim; Wolfe, Hannah; Hilliard, Christopher; Cleland, Charles M; Honig, Sylvie

    2016-01-01

    Drug use is associated with low uptake of HIV antiretroviral therapy (ART), an under-studied step in the HIV care continuum, and insufficient engagement in HIV primary care. However, the specific underlying mechanisms by which drug use impedes these HIV health outcomes are poorly understood. The present qualitative study addresses this gap in the literature, focusing on African-American/Black and Hispanic persons living with HIV (PLWH) who had delayed, declined, or discontinued ART and who also were generally poorly engaged in health care. Participants (N = 37) were purposively sampled from a larger study for maximum variation on HIV indices. They engaged in 1-2 h audio-recorded in-depth semi-structured interviews on HIV histories guided by a multilevel social-cognitive theory. Transcripts were analyzed using a systematic content analysis approach. Consistent with the existing literature, heavy substance use, but not casual or social use, impeded ART uptake, mainly by undermining confidence in medication management abilities and triggering depression. The confluence of African-American/Black or Hispanic race/ethnicity, poverty, and drug use was associated with high levels of perceived stigma and inferior treatment in health-care settings compared to their peers. Furthermore, providers were described as frequently assuming participants were selling their medications to buy drugs, which strained provider-patient relationships. High levels of medical distrust, common in this population, created fears of ART and of negative interactions between street drugs and ART, but participants could not easily discuss this concern with health-care providers. Barriers to ART initiation and HIV care were embedded in other structural- and social-level challenges, which disproportionately affect low-income African-American/Black and Hispanic PLWH (e.g., homelessness, violence). Yet, HIV management was cyclical. In collaboration with trusted providers and ancillary staff

  20. Application of alternating current impedance to fuel cell modeling

    SciTech Connect

    Springer, T.E.

    1999-05-02

    AC impedance has provided a useful diagnostic tool in the Los Alamos polymer electrolyte fuel cell (PEFC) program. The author reviews the techniques he has used in ac impedance modeling. These techniques include equation implementation, model simplification and verification, least squares fitting, application of two-dimensional Laplace equation solvers handling complex interfacial boundary conditions, and interpretation of impedance features. The separate features of the complete electrode model are explained by analytic examples.

  1. Temperature dependent dielectric and conductivity studies of polyvinyl alcohol-ZnO nanocomposite films by impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Hemalatha, K. S.; Sriprakash, G.; Ambika Prasad, M. V. N.; Damle, R.; Rukmani, K.

    2015-10-01

    Dielectric and conductivity behaviors of nano ZnO doped polyvinyl alcohol (PVA) composites for various concentrations of dopant were investigated using impedance spectroscopy for a wide range of temperatures (303 K-423 K) and frequencies (5 Hz-30 MHZ). The dielectric properties of host polymer matrix have been improved by the addition of nano ZnO and are found to be highly temperature dependent. Anomalous dielectric behavior was observed in the frequency range of 2.5 MHz-5 MHz. Increase in dielectric permittivity and dielectric loss was observed with respect to temperature. The Cole-Cole plot could be modeled by low resistance regions in a high resistance matrix and the lowest resistance was observed for the 10 mol. % films. The imaginary part of the electric modulus showed asymmetric peaks with the relaxation following Debye nature below and non-Debye nature above the peaks. The ac conductivity is found to obey Jonscher's power law, whereas the variation of dc conductivity with temperature was found to follow Arrhenius behavior. Two different activation energy values were obtained from Arrhenius plot indicating that two conduction mechanisms are involved in the composite films. Fitting the ac conductivity data to Jonscher's law indicates that large polaron assisted tunneling is the most likely conduction mechanism in the composites. Maximum conductivity is observed at 423 K for all the samples and it is optimum for 10 mol. % ZnO doped PVA composite film. Significant increase in dc and ac conductivities in these composite films makes them a potential candidate for application in electronic devices.

  2. Temperature dependent dielectric and conductivity studies of polyvinyl alcohol-ZnO nanocomposite films by impedance spectroscopy

    SciTech Connect

    Hemalatha, K. S.; Damle, R.; Rukmani, K.; Sriprakash, G.; Ambika Prasad, M. V. N.

    2015-10-21

    Dielectric and conductivity behaviors of nano ZnO doped polyvinyl alcohol (PVA) composites for various concentrations of dopant were investigated using impedance spectroscopy for a wide range of temperatures (303 K–423 K) and frequencies (5 Hz–30 MHZ). The dielectric properties of host polymer matrix have been improved by the addition of nano ZnO and are found to be highly temperature dependent. Anomalous dielectric behavior was observed in the frequency range of 2.5 MHz–5 MHz. Increase in dielectric permittivity and dielectric loss was observed with respect to temperature. The Cole-Cole plot could be modeled by low resistance regions in a high resistance matrix and the lowest resistance was observed for the 10 mol. % films. The imaginary part of the electric modulus showed asymmetric peaks with the relaxation following Debye nature below and non-Debye nature above the peaks. The ac conductivity is found to obey Jonscher's power law, whereas the variation of dc conductivity with temperature was found to follow Arrhenius behavior. Two different activation energy values were obtained from Arrhenius plot indicating that two conduction mechanisms are involved in the composite films. Fitting the ac conductivity data to Jonscher's law indicates that large polaron assisted tunneling is the most likely conduction mechanism in the composites. Maximum conductivity is observed at 423 K for all the samples and it is optimum for 10 mol. % ZnO doped PVA composite film. Significant increase in dc and ac conductivities in these composite films makes them a potential candidate for application in electronic devices.

  3. Dielectric and impedance spectroscopic studies of 0.8BaTiO3-0.2Bi0.5K0.5TiO3 lead-free ceramics

    NASA Astrophysics Data System (ADS)

    Ramesh, M. N. V.; Ramesh, K. V.

    2015-06-01

    0.8BaTiO3-0.2Bi0.5K0.5TiO3 (BT-BKT20) lead-free ceramics were prepared by conventional solid state reaction method followed by high energy ball milling. The formation of a single phase tetragonal structure in the material was confirmed by X-ray diffraction. Frequency and temperature-dependent dielectric studies show relaxor behavior in the BT-BKT20 which was found to obey modified Curie-Weiss law with degree of diffuseness 1.573. Complex impedance and electric modulus spectroscopy studies reveal temperature-dependent relaxation process in the material. The Cole-Cole plots were measured at high temperatures at which grain effect was observed. Impedance and electric modulus spectroscopy studies show non-Debye kind of conductivity relaxation process in the present material. Activation energies were calculated from impedance and electric modulus spectroscopy and the values of activation energy indicated that the conduction is ionic in nature. AC and DC conductivity have been measured and studied at different temperatures.

  4. Feasibility studies of electrical impedance spectroscopy for monitoring tissue response to photodynamic therapy

    NASA Astrophysics Data System (ADS)

    Wilson, Brian C.; Osterman, Kendra S.; Hoopes, P. Jack; Lilge, Lothar D.; Paulsen, Keith D.

    1998-05-01

    Electrical impedance spectroscopy (EIS) has been evaluated as a non- or minimally-invasive technique to monitor the acute tissue response to photodynamic therapy (PDT). In this study the EIS spectra of normal muscle tissue in the rat hind leg were monitored immediately before and at time intervals up to 96 hours post-PDT treatment with different photosensitizers (Photofrin, ALA-induced PpIX, BenzoPorphyrin Derivative), at varying photosensitizer and light doses. EIS measurements were made using a pair of solid matrix Ag-AgCl electrodes placed parallel to one another on either side of the muscle mass and interfaced to a precision LCR impedance meter scanning the frequency range 1 - 1000 KHz. Independent histological grading of tissue injury was performed on tissue sections from treated and untreated legs at the 96 hour end point. Significant and PDT dose-dependent changes in the EIS spectra following treatment were observed, including increases in conductivity which correlated with the immediate post-PDT edematous response with Photofrin and ALA and which resolved or partially-resolved over the measurement time course. Photofrin treatments exhibited a clear drug dose response at 96 hours that was evident in both the EIS spectra and the histological sections. These changes included significant tissue necrosis as well as edema, inflammation and early fibroplasia. The BPD data were less clear, but potentially quite interesting. Most striking were below unity ratios of treated-to-untreated muscle spectra components at 24 hours which reversed to above unity by 96 hours in the through skin measurements. This phenomenon is indicative of a tissue response distinctly different than that observed with Photofrin or ALA. These data also suggest that EIS measured changes are sensitive enough to detect differences in PDT-initiated tissue damage that may be photosensitize-specific. While the data are derived from a small number of animals, the findings are quite encouraging in

  5. Impedance studies of the thin film LiMn2O4/electrolyteinterface

    SciTech Connect

    Striebel, Kathryn A.; Sakai, E.; Cairns, Elton J.

    2001-04-07

    Room-temperature impedance measurements of a thin-film LiMn2O4/LiPF6-EC-DMC interface have been used to identify the spontaneous formation Li2Mn2O4 at the interface at room temperature at voltages of 3.7 and higher. The impedance of the LiMn2O4 films exhibited two time constants: at about 14 kHz and 60 to 200 Hz. The high frequency loop is dependent on film morphology and was attributed to the substrate/oxide interface. The low frequency behavior was dependent on both state-of-charge (SOC) and time at a given SOC. At full charge the impedance in this electrolyte was stable at room temperature over several days. At high lithium contents, film OCV and impedance tended to grow logarithmically with time, with lower rates for lower Mn3+ content in the film. The increased impedance was removed by oxidation of the film to 4.5V vs. Li/Li+. The observations are consistent with a reversible disproportionation of part of the LiMn2O4 into Li2Mn2O4 and a lithium-deficient spinel. With extended constant current cycling part of the Li2Mn2O4 degrades to the Mn2O3 and the process is no longer reversible.

  6. Study of Rust Effect on the Corrosion Behavior of Reinforcement Steel Using Impedance Spectroscopy

    NASA Astrophysics Data System (ADS)

    Bensabra, Hakim; Azzouz, Noureddine

    2013-12-01

    Most studies on corrosion of steel reinforcement in concrete are conducted on steel samples with polished surface (free of all oxides) in order to reproduce the same experimental conditions. However, before embedding in concrete, the steel bars are often covered with natural oxides (rust), which are formed during exposure to the atmosphere. The presence of this rust may affect the electrochemical behavior of steel rebar in concrete. In order to understand the effect of rust on the corrosion behavior of reinforcement steel, potentiodynamic and electrochemical impedance spectroscopy (EIS) tests were carried out in a simulated concrete pore solution using steel samples with two different surface conditions: polished and rusted samples. The obtained results have shown that the presence of rust on the steel bar has a negative effect on its corrosion behavior, with or without the presence of chlorides. This detrimental effect can be explained by the fact that the rust provokes a decrease of the electrolyte resistance at the metal-concrete interface and reduces the repassivating ability. In addition, the rust layer acts as a barrier against the hydroxyl ion diffusion, which prevents the realkalinization phenomenon.

  7. High Resistivity Lipid Bilayers Assembled on Polyelectrolyte Multilayer Cushions: An Impedance Study.

    PubMed

    Diamanti, Eleftheria; Gregurec, Danijela; Rodríguez-Presa, María José; Gervasi, Claudio A; Azzaroni, Omar; Moya, Sergio E

    2016-06-28

    Supported membranes on top of polymer cushions are interesting models of biomembranes as cell membranes are supported on a polymer network of proteins and sugars. In this work lipid vesicles formed by a mixture of 30% 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) and 70% 1,2-dioleoyl-sn-glycero-3-phospho-l-serine (DOPS) are assembled on top of a polyelectrolyte multilayer (PEM) cushion of poly(allylamine hydrochloride) (PAH) and poly(styrene sodium sulfonate) (PSS). The assembly results in the formation of a bilayer on top of the PEM as proven by means of the quartz crystal microbalance with dissipation technique (QCM-D) and by cryo-transmission electron microscopy (cryo-TEM). The electrical properties of the bilayer are studied by electrochemical impedance spectroscopy (EIS). The bilayer supported on the PEMs shows a high resistance, on the order of 10(7) Ω cm(2), which is indicative of a continuous, dense bilayer. Such resistance is comparable with the resistance of black lipid membranes. This is the first time that such values are obtained for lipid bilayers supported on PEMs. The assembly of polyelectrolytes on top of a lipid bilayer decreases the resistance of the bilayer up to 2 orders of magnitude. The assembly of the polyelectrolytes on the lipids induces defects or pores in the bilayer which in turn prompts a decrease in the measured resistance.

  8. High Resistivity Lipid Bilayers Assembled on Polyelectrolyte Multilayer Cushions: An Impedance Study.

    PubMed

    Diamanti, Eleftheria; Gregurec, Danijela; Rodríguez-Presa, María José; Gervasi, Claudio A; Azzaroni, Omar; Moya, Sergio E

    2016-06-28

    Supported membranes on top of polymer cushions are interesting models of biomembranes as cell membranes are supported on a polymer network of proteins and sugars. In this work lipid vesicles formed by a mixture of 30% 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) and 70% 1,2-dioleoyl-sn-glycero-3-phospho-l-serine (DOPS) are assembled on top of a polyelectrolyte multilayer (PEM) cushion of poly(allylamine hydrochloride) (PAH) and poly(styrene sodium sulfonate) (PSS). The assembly results in the formation of a bilayer on top of the PEM as proven by means of the quartz crystal microbalance with dissipation technique (QCM-D) and by cryo-transmission electron microscopy (cryo-TEM). The electrical properties of the bilayer are studied by electrochemical impedance spectroscopy (EIS). The bilayer supported on the PEMs shows a high resistance, on the order of 10(7) Ω cm(2), which is indicative of a continuous, dense bilayer. Such resistance is comparable with the resistance of black lipid membranes. This is the first time that such values are obtained for lipid bilayers supported on PEMs. The assembly of polyelectrolytes on top of a lipid bilayer decreases the resistance of the bilayer up to 2 orders of magnitude. The assembly of the polyelectrolytes on the lipids induces defects or pores in the bilayer which in turn prompts a decrease in the measured resistance. PMID:27267089

  9. Crew Quarters (CQ) and Electromagnetic Interference (EMI) Measurement Facility Combined Impedance Study

    NASA Technical Reports Server (NTRS)

    Scully, Robert C.

    2011-01-01

    This report documents an investigation into observed failures associated with conducted susceptibility testing of Crew Quarters (CQ) hardware in the Johnson Space Center (JSC) Electromagnetic Interference (EMI) Measurement Facility, and the work accomplished to identify the source of the observed behavior. Investigation led to the conclusion that the hardware power input impedance was interacting with the facility power impedance leading to instability at the observed frequencies of susceptibility. Testing performed in other facilities did not show this same behavior, pointing back to the EMI Measurement Facility power as the potential root cause. A LISN emulating the Station power bus impedance was inserted into the power circuit, and the susceptibility was eliminated from the measurements.

  10. Comparative Study of Impedance Eduction Methods. Part 1; DLR Tests and Methodology

    NASA Technical Reports Server (NTRS)

    Busse-Gerstengarbe, Stefan; Bake, Friedrich; Enghardt, Lars; Jones, Michael G.

    2013-01-01

    The absorption efficiency of acoustic liners used in aircraft engines is characterized by the acoustic impedance. World wide, many grazing ow test rigs and eduction methods are available that provide values for that impedance. However, a direct comparison and assessment of the data of the di erent rigs and methods is often not possible because test objects and test conditions are quite di erent. Only a few papers provide a direct comparison. Therefore, this paper together with a companion paper, present data measured with a reference test object under similar conditions in the DLR and NASA grazing ow test rigs. Additionally, by applying the in-house methods Liner Impedance Non-Uniform ow Solving algorithm (LINUS, DLR) and Convected Helmhholtz Equation approach (CHE, NASA) on the data sets, similarities and differences due to underlying theory are identi ed and discussed.

  11. Impedance spectroscopy study of anodic growth of zirconium oxide film in NaOH medium

    NASA Astrophysics Data System (ADS)

    Pauporté, T.; Finne, J.; Lincot, D.

    2005-06-01

    The growth of anodic oxide films on zirconium metal has been followed up to 300 V by electrochemical impedance spectroscopy and scanning electron microscopy. The maximum layer thickness is 720 nm, the dielectric constant of the film is measured at 19.5 and the growth constant is 2.4 nm V-1. Above 50 V, the presence of two impedance relaxations between 1 Hz and 200 kHz reveals a bilayered structure. This may be a consequence of a lower resistivity of the outer layer induced by some electrolytic solution infiltration into film defects.

  12. Ac Impedance Spectroscopic Studies on Li2xPb2xBaP2O7

    NASA Astrophysics Data System (ADS)

    Vijayakumar, M.; Selvasekarapandian, S.

    2002-12-01

    The complex diphosphate (P2O7)4- ions have been used as a building blocks in wide variety of crystal phases for a wide spectrum of physical and chemical properties. Lithium barium diphsophate doped with lead {Li2-xPb2xBaP2O7 (x = 0, 0.2 & 0.4)} has been prepared by solid state reaction method The conductivity is found to be decreasing with the doping of lead. The lithium ion dynamics parameters such as hopping frequency and relaxation frequency were calculated from the frequency dependent conductivity and modulus analysis.

  13. Cell Electrical Impedance as a Novel Approach for Studies on Senescence Not Based on Biomarkers

    PubMed Central

    Cha, Jung-Joon; Park, Yangkyu; Yun, Joho; Kim, Hyeon Woo; Park, Chang-Ju; Kang, Giseok; Jung, Minhyun; Pak, Boryeong; Jin, Suk-Won

    2016-01-01

    Senescence of cardiac myocytes is frequently associated with heart diseases. To analyze senescence in cardiac myocytes, a number of biomarkers have been isolated. However, due to the complex nature of senescence, multiple markers are required for a single assay to accurately depict complex physiological changes associated with senescence. In single cells, changes in both cytoplasm and cell membrane during senescence can affect the changes in electrical impedance. Based on this phenomenon, we developed MEDoS, a novel microelectrochemical impedance spectroscopy for diagnosis of senescence, which allows us to precisely measure quantitative changes in electrical properties of aging cells. Using cardiac myocytes isolated from 3-, 6-, and 18-month-old isogenic zebrafish, we examined the efficacy of MEDoS and showed that MEDoS can identify discernible changes in electrical impedance. Taken together, our data demonstrated that electrical impedance in cells at different ages is distinct with quantitative values; these results were comparable with previously reported ones. Therefore, we propose that MEDoS be used as a new biomarker-independent methodology to obtain quantitative data on the biological senescence status of individual cells. PMID:27812531

  14. Local impedance measurement of an electrode/single-pentacene-grain interface by frequency-modulation scanning impedance microscopy

    NASA Astrophysics Data System (ADS)

    Kimura, Tomoharu; Kobayashi, Kei; Yamada, Hirofumi

    2015-08-01

    The device performances of organic thin film transistors are often limited by the metal-organic interface because of the disordered molecular layers at the interface and the energy barriers against the carrier injection. It is important to study the local impedance at the interface without being affected by the interface morphology. We combined frequency modulation atomic force microscopy with scanning impedance microscopy (SIM) to sensitively measure the ac responses of the interface to an ac voltage applied across the interface and the dc potential drop at the interface. By using the frequency-modulation SIM (FM-SIM) technique, we characterized the interface impedance of a Pt electrode and a single pentacene grain as a parallel circuit of a contact resistance and a capacitance. We found that the reduction of the contact resistance was caused by the reduction of the energy level mismatch at the interface by the FM-SIM measurements, demonstrating the usefulness of the FM-SIM technique for investigation of the local interface impedance without being affected by its morphology.

  15. Local impedance measurement of an electrode/single-pentacene-grain interface by frequency-modulation scanning impedance microscopy

    SciTech Connect

    Kimura, Tomoharu; Yamada, Hirofumi; Kobayashi, Kei

    2015-08-07

    The device performances of organic thin film transistors are often limited by the metal–organic interface because of the disordered molecular layers at the interface and the energy barriers against the carrier injection. It is important to study the local impedance at the interface without being affected by the interface morphology. We combined frequency modulation atomic force microscopy with scanning impedance microscopy (SIM) to sensitively measure the ac responses of the interface to an ac voltage applied across the interface and the dc potential drop at the interface. By using the frequency-modulation SIM (FM-SIM) technique, we characterized the interface impedance of a Pt electrode and a single pentacene grain as a parallel circuit of a contact resistance and a capacitance. We found that the reduction of the contact resistance was caused by the reduction of the energy level mismatch at the interface by the FM-SIM measurements, demonstrating the usefulness of the FM-SIM technique for investigation of the local interface impedance without being affected by its morphology.

  16. Tethered bilayer lipid membranes studied by simultaneous attenuated total reflectance infrared spectroscopy and electrochemical impedance spectroscopy

    PubMed Central

    Erbe, Andreas; Bushby, Richard J.; Evans, Stephen D.; Jeuken, Lars J. C.

    2013-01-01

    The formation of tethered lipid bilayer membranes (tBLMs) from unilamelar vesicles of egg yolk phosphatidylcholine (EggPC) on mixed self–assembled monolayers (SAMs) from varying ratios of 6-mercaptohexanol and EO3Cholesteryl on gold has been monitored by simultaneous attenuated total reflectance fourier transform infrared (ATR–FTIR) spectroscopy and electrochemical impedance spectroscopy (EIS). The influence of the lipid orientation (and hence the anisotropy) of lipids on a gold film on the dichroic ratio was studied by simulations of spectra with a matrix method for anisotropic layers. It is shown that for certain tilt angles of the dielectric tensor of the adsorbed anisotropic layer dispersive and negative absorption bands are possible. The experimental data indicates that the structure of the assemblies obtained varies with varying SAM composition. On SAMs with a high content of EO3Cholesteryl, tBLMs with reduced fluidity are formed. For SAMs with high content of 6-mercaptohexanol, the results are consistent with the adsorption of flattened vesicles, while spherical vesicles have been found in a small range of surface compositions. The kinetics of the adsorption process is consistent with the assumption of spherical vesicles as long–living intermediates for surfaces of high 6-mercaptohexanol content. No long–living spherical vesicles have been detected for surfaces with large fraction of EO3Cholesteryl tethers. The observed differences between the surfaces suggest that for the formation of tBLMs (unlike supported BLMs) no critical surface coverage of vesicles is needed prior to lipid bilayer formation. PMID:17388505

  17. Numerical study of dc-biased ac-electrokinetic flow over symmetrical electrodes.

    PubMed

    Yang Ng, Wee; Ramos, Antonio; Cheong Lam, Yee; Rodriguez, Isabel

    2012-03-01

    This paper presents a numerical study of DC-biased AC-electrokinetic (DC-biased ACEK) flow over a pair of symmetrical electrodes. The flow mechanism is based on a transverse conductivity gradient created through incipient Faradaic reactions occurring at the electrodes when a DC-bias is applied. The DC biased AC electric field acting on this gradient generates a fluid flow in the form of vortexes. To understand more in depth the DC-biased ACEK flow mechanism, a phenomenological model is developed to study the effects of voltage, conductivity ratio, channel width, depth, and aspect ratio on the induced flow characteristics. It was found that flow velocity on the order of mm/s can be produced at higher voltage and conductivity ratio. Such rapid flow velocity is one of the highest reported in microsystems technology using electrokinetics. PMID:22662084

  18. Numerical study of dc-biased ac-electrokinetic flow over symmetrical electrodes

    PubMed Central

    Yang Ng, Wee; Ramos, Antonio; Cheong Lam, Yee; Rodriguez, Isabel

    2012-01-01

    This paper presents a numerical study of DC-biased AC-electrokinetic (DC-biased ACEK) flow over a pair of symmetrical electrodes. The flow mechanism is based on a transverse conductivity gradient created through incipient Faradaic reactions occurring at the electrodes when a DC-bias is applied. The DC biased AC electric field acting on this gradient generates a fluid flow in the form of vortexes. To understand more in depth the DC-biased ACEK flow mechanism, a phenomenological model is developed to study the effects of voltage, conductivity ratio, channel width, depth, and aspect ratio on the induced flow characteristics. It was found that flow velocity on the order of mm/s can be produced at higher voltage and conductivity ratio. Such rapid flow velocity is one of the highest reported in microsystems technology using electrokinetics. PMID:22662084

  19. Nonlinear dynamics studies in the Fermilab tevatron using an AC dipole

    SciTech Connect

    Miyamoto,R.; Jansson, A.; Syphers, M. J.; Kopp, S. E.

    2009-05-04

    An AC dipole magnet produces a sinusoidally oscillating dipole field with frequency close to betatron frequency and excites large sustained oscillations of beam particles circulating in a synchrotron. Observation of such oscillations with beam position monitors allows direct measurements of a synchrotron's nonlinear parameters. This paper presents experimental studies to measure perturbative effects of sextupole and octupole fields, performed in the Fermilab Tevatron using an ACdipole.

  20. Kinetics of electrochemically controlled surface reactions on bulk and thin film metals studied with Fourier transform impedance spectroscopy and surface plasmon resonance techniques

    NASA Astrophysics Data System (ADS)

    Assiongbon, Kankoe A.

    2005-07-01

    In the work presented in this thesis, the surface sensitive electrochemical techniques of cyclic voltametry (CV), potential step (PS) and Fourier transform impedance spectroscopy (FT-EIS), as well as the optical technique of surface plasmon resonance (SPR), were used to probe a wide variety of surface processes at various metal/liquid interface. Three polycrystalline metals (Au, Ta and Cu) and a Cr-coated gold film were used for these studies in different aqueous environments. A combination of CV with FT-EIS and PS was used to investigate electronic and structural proprieties of a modified bulk electrode of Au. This experimental system involved under potential deposition (UPD) of Bi3+ on Au in a supporting aqueous electrolyte containing ClO-4 . UPD range of Bi3+ was determined, and adsorption kinetics of Bi3+ in the presence of coadsorbing anion, ClO-4 were quantified. Potentiodynamic growth of oxide films of Ta in the following electrolytes NaNO3, NaNO3 + 5wt% H2O2, NaOH and NaOH + 5wt% H2O2 had been investigated. The oxide films were grown in the range -0.1 → +0.4V (high electric field) at a scan rate of 10 mV/s. Time resolved A.C. impedance spectroscopy measurements in the frequency range (0.1--20 KHz) were performed to characterize the surface reactions of oxide formation. The results are interpreted in terms of charge conductivity O2- through the oxide film, and disintegration of H2O2 into OH-. In a high pH medium (pH 12), dissociation of H2O2 was catalytically enhanced. This led to destabilization of the electrogenerated tantalum oxide surface film in the form of a soluble hexatantalate species. In contrast with the electrolytes, NaNO3, NaNO3 + 5wt% H2O2, NaOH, where only the oxide growth was observed, the A.C. impedance spectroscopy measurements in NaOH + 5wt% H 2O2 showed competition between oxide formation and its removal. These results are relevant for chemical slurry design in chemical mechanical polishing (CMP) of Ta. Further investigations were

  1. Single cell studies of mouse embryonic stem cell (mESC) differentiation by electrical impedance measurements in a microfluidic device.

    PubMed

    Zhou, Ying; Basu, Srinjan; Laue, Ernest; Seshia, Ashwin A

    2016-07-15

    Biological populations of cells show considerable cell-to-cell variability. Study of single cells and analysis of cell heterogeneity are considered to be critical in understanding biological processes such as stem cell differentiation and cancer development. Recent advances in lab-on-a-chip techniques have allowed single-cell capture in microfluidic channels with the possibility of precise environmental control and high throughput of experiments with minimal usage of samples and reagents. In recent years, label-free techniques such as electrical impedance spectroscopy have emerged as a non-invasive approach to studying cell properties. In this study, we have designed and fabricated a microfluidic device that combines hydrodynamic trapping of single cells in pre-defined locations with the capability of running electrical impedance measurements within the same device. We have measured mouse embryonic stem cells (mESCs) at different states during differentiation (t=0h, 24h and 48h) and quantitatively analysed the changes in electrical parameters of cells during differentiation. A marked increase in the magnitude of the cell impedance is found during cell differentiation, which can be attributed to an increase in cell size. The analysis of the measurements shows that the nucleus-to-cytoplasm ratio decreases during this process. The degree of cell heterogeneity is observed to be the highest when the cells are at the transition state (24h), compare with cells at undifferentiated (0h) and fully differentiated (48h) states. The device enables highly efficient single cell trapping and provides sensitive, label-free electrical impedance measurements of individual cells, enabling the possibility of quantitatively analysing their physical state as well as studying the associated heterogeneity of a cell population.

  2. Single cell studies of mouse embryonic stem cell (mESC) differentiation by electrical impedance measurements in a microfluidic device

    PubMed Central

    Zhou, Ying; Basu, Srinjan; Laue, Ernest; Seshia, Ashwin A.

    2016-01-01

    Biological populations of cells show considerable cell-to-cell variability. Study of single cells and analysis of cell heterogeneity are considered to be critical in understanding biological processes such as stem cell differentiation and cancer development. Recent advances in lab-on-a-chip techniques have allowed single-cell capture in microfluidic channels with the possibility of precise environmental control and high throughput of experiments with minimal usage of samples and reagents. In recent years, label-free techniques such as electrical impedance spectroscopy have emerged as a non-invasive approach to studying cell properties. In this study, we have designed and fabricated a microfluidic device that combines hydrodynamic trapping of single cells in pre-defined locations with the capability of running electrical impedance measurements within the same device. We have measured mouse embryonic stem cells (mESCs) at different states during differentiation (t=0 h, 24 h and 48 h) and quantitatively analysed the changes in electrical parameters of cells during differentiation. A marked increase in the magnitude of the cell impedance is found during cell differentiation, which can be attributed to an increase in cell size. The analysis of the measurements shows that the nucleus-to-cytoplasm ratio decreases during this process. The degree of cell heterogeneity is observed to be the highest when the cells are at the transition state (24 h), compare with cells at undifferentiated (0 h) and fully differentiated (48 h) states. The device enables highly efficient single cell trapping and provides sensitive, label-free electrical impedance measurements of individual cells, enabling the possibility of quantitatively analysing their physical state as well as studying the associated heterogeneity of a cell population. PMID:26963790

  3. Report of the SSC impedance workshop

    SciTech Connect

    1985-10-28

    This workshop focused attention on the transverse, single-bunch instability and the detailed analysis of the broadband impedance which would drive it. Issues discussed included: (1) single bunch stability -- impact of impedance frequency shape, coupled-mode vs. fast blowup regimes, possible stopband structure; (2) numerical estimates of transverse impedance of inner bellows and sliding contact shielded bellows; (3) analytic estimates of pickup and kicker impedance contributions; and (4) feasibility studies of wire and beam measurements of component impedance.

  4. S4AC Case Study: Enhancing Underserved Seniors' Access to Health Promotion Programs.

    PubMed

    Koehn, Sharon; Habib, Sanzida; Bukhari, Syeda

    2016-03-01

    The Seniors Support Services for South Asian Community (S4AC) project was developed in response to the underutilization of available recreation and seniors' facilities by South Asian seniors who were especially numerous in a suburban neighbourhood in British Columbia. Addressing the problem required the collaboration of the municipality and a registered non-profit agency offering a wide range of services and programs to immigrant and refugee communities. Through creative outreach and accommodation, the project has engaged more than 100 Punjabi-speaking seniors annually in diverse exercise activities. Case study research methods with staff and current and former senior participants of S4AC include participant observation, individual interviews, and focus groups. Viewed through the critical interpretive lens of the "candidacy framework", findings reveal the myriad ways in which access to health promotion and physical activity for immigrant older adults is a complex iterative process of negotiation at multiple levels.

  5. AC susceptibility study at the inter- and intragranular properties in (Bi,Pb):2223 superconductor

    SciTech Connect

    Pop, A.V.; Ciurchea, D.; Ilonca, G.; Deltour, R.; Harabor, A.

    1997-11-20

    The temperature and amplitude of AC field dependencies of both inter- and intragranular T{sub p} and T{sub g} temperatures of the imaginary peaks of {chi}{double_prime} has been studied for a sintered single phase (Bi,Pb):2223 superconductor. The AC field dependencies for T{sub p} and T{sub g} and the relation between inter- and intragrain force densities were discussed by using Mueller critical-state model. From the {chi}{double_prime} curve, the values of intergrain magnetic critical current density J{sub cJ} was obtained via the application of Beans` critical state model. J{sub cJ}(T) dependence near {Tc} agree with the assumption of SNS intergrain junctions.

  6. A study on calculation method for mechanical impedance of air spring

    NASA Astrophysics Data System (ADS)

    Changgeng, SHUAI; Penghui, LI; Rustighi, Emiliano

    2016-09-01

    This paper proposes an approximate analytic method of obtaining the mechanical impedance of air spring. The sound pressure distribution in cylindrical air spring is calculated based on the linear air wave theory. The influences of different boundary conditions on the acoustic pressure field distribution in cylindrical air spring are analysed. A 1-order ordinary differential matrix equation for the state vector of revolutionary shells under internal pressure is derived based on the non-moment theory of elastic thin shell. Referring to the transfer matrix method, a kind of expanded homogeneous capacity high precision integration method is introduced to solve the non-homogeneous matrix differential equation. Combined the solved stress field of shell with the calculated sound pressure field in air spring under the displacement harmonic excitation, the approximate analytical expression of the input and transfer mechanical impedance for the air spring can be achieved. The numerical simulation with the Comsol Multiphysics software verifies the correctness of theoretical analysis result.

  7. Microstructural studies of AgNbO{sub 3} ceramic by using complex impedance spectroscopy

    SciTech Connect

    Gangaprasad, K.; Rao, T. Durga; Niranjan, Manish K.; Asthana, Saket

    2015-06-24

    Lead-free piezoelectric silver niobate ceramic was synthesized by conventional solid state route. Room temperature X-ray diffraction pattern revealed that the sample crystallizes in single phase orthorhombic perovskite structure. Scanning electron micrographs of AgNbO{sub 3} ceramic showed that the average grain size is in the range 2–3 µm. The electrical properties were investigated by using impedance spectroscopy. Appearance of single semicircular arc in the Nyquist plot indicated the presence of grain contribution in the sample. Single RC parallel circuit model was employed to extract bulk capacitance (C{sub b}), resistance (R{sub b}) and electrical conductivity (σ{sub b}). The activation energy calculated from impedance and modulus data indicate that same types of charge carriers (oxygen vacancy movements) are responsible for conduction and relaxation.

  8. Microstructural studies of AgNbO3 ceramic by using complex impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Gangaprasad, K.; Rao, T. Durga; Niranjan, Manish K.; Asthana, Saket

    2015-06-01

    Lead-free piezoelectric silver niobate ceramic was synthesized by conventional solid state route. Room temperature X-ray diffraction pattern revealed that the sample crystallizes in single phase orthorhombic perovskite structure. Scanning electron micrographs of AgNbO3 ceramic showed that the average grain size is in the range 2-3 µm. The electrical properties were investigated by using impedance spectroscopy. Appearance of single semicircular arc in the Nyquist plot indicated the presence of grain contribution in the sample. Single RC parallel circuit model was employed to extract bulk capacitance (Cb), resistance (Rb) and electrical conductivity (σb). The activation energy calculated from impedance and modulus data indicate that same types of charge carriers (oxygen vacancy movements) are responsible for conduction and relaxation.

  9. ACS experiment for atmospheric studies on "ExoMars-2016" Orbiter

    NASA Astrophysics Data System (ADS)

    Korablev, O. I.; Montmessin, F.; Fedorova, A. A.; Ignatiev, N. I.; Shakun, A. V.; Trokhimovskiy, A. V.; Grigoriev, A. V.; Anufreichik, K. A.; Kozlova, T. O.

    2015-12-01

    ACS is a set of spectrometers for atmospheric studies (Atmospheric Chemistry Suite). It is one of the Russian instruments for the Trace Gas Orbiter (TGO) of the Russian-European "ExoMars" program. The purpose of the experiment is to study the Martian atmosphere by means of two observations regimes: sensitive trace gases measurements in solar occultations and by monitoring the atmospheric state during nadir observations. The experiment will allow us to approach global problems of Mars research such as current volcanism, and the modern climate status and its evolution. Also, the experiment is intended to solve the mystery of methane presence in the Martian atmosphere. Spectrometers of the ACS set cover the spectral range from the near IR-range (0.7 μm) to the thermal IR-range (17 μm) with spectral resolution λ/Δλ reaching 50000. The ACS instrument consists of three independent IR spectrometers and an electronics module, all integrated in a single unit with common mechanical, electrical and thermal interfaces. The article gives an overview of scientific tasks and presents the concept of the experiment.

  10. Theoretical study of electromagnetic electron cyclotron waves in the presence of AC field in Uranian magnetosphere

    NASA Astrophysics Data System (ADS)

    Pandey, R. S.; Kaur, Rajbir

    2015-10-01

    Electromagnetic electron cyclotron (EMEC) waves with temperature anisotropy in the magnetosphere of Uranus have been studied in present work. EMEC waves are investigated using method of characteristic solution by kinetic approach, in presence of AC field. In 1986, Voyager 2 encounter with Uranus revealed that magnetosphere of Uranus exhibit non-Maxwellian high-energy tail distribution. So, the dispersion relation, real frequency and growth rate are evaluated using Lorentzian Kappa distribution function. Effect of temperature anisotropy, AC frequency and number density of particles is found. The study is also extended to oblique propagation of EMEC waves in presence and absence of AC field. Through comprehensive mathematical analysis it is found that when EMEC wave propagates parallel to intrinsic magnetic field of Uranus, its growth is more enhanced than in case of oblique propagation. Results are also discussed in context to magnetosphere of Earth and also gives theoretical explanation to existence of high energetic particles observed by Voyager 2 in the magnetosphere of Uranus. The results can present a further insight into the nature of electron-cyclotron instability condition for the whistler mode waves in the outer radiation belts of Uranus or other space plasmas.

  11. An Experimental Study on the Effect of Temperature on Piezoelectric Sensors for Impedance-Based Structural Health Monitoring

    PubMed Central

    Baptista, Fabricio G.; Budoya, Danilo E.; de Almeida, Vinicius A. D.; Ulson, Jose Alfredo C.

    2014-01-01

    The electromechanical impedance (EMI) technique is considered to be one of the most promising methods for developing structural health monitoring (SHM) systems. This technique is simple to implement and uses small and inexpensive piezoelectric sensors. However, practical problems have hindered its application to real-world structures, and temperature effects have been cited in the literature as critical problems. In this paper, we present an experimental study of the effect of temperature on the electrical impedance of the piezoelectric sensors used in the EMI technique. We used 5H PZT (lead zirconate titanate) ceramic sensors, which are commonly used in the EMI technique. The experimental results showed that the temperature effects were strongly frequency-dependent, which may motivate future research in the SHM field. PMID:24434878

  12. Thermal annealing study on P3HT: PCBM based bulk heterojunction organic solar cells using impedance spectroscopy

    SciTech Connect

    Gollu, Sankara Rao; Sharma, Ramakant G, Srinivas Gupta, Dipti

    2014-10-15

    Recently, Thermal annealing is an important process for bulk heterojunction organic solar cells (BHJ OSCs) to improve the device efficiency and performance of the organic solar cells. Here in, we have examined the changes in the efficiency and morphology of P3HT: PCBM film according to the thermal annealing temperature to find the changes during the annealing process by measuring the optical absorption, atomic force microscope and X-ray diffraction. We also investigated the effect of different annealing process conditions (without, pre- and post-annealing) on the device performance of the inverted bulk heterojunction organic solar cells consist the structure of ITO/ ZnO / P3HT: PCBM / MoO{sub 3}/ Al by measuring AC impedance characteristics. Particularly, the power conversion efficiency (PCE), crystalline nature of the polymer, light absorption and the surface smoothness of P3HT: PCBM films are significantly improved after the annealing process. These results indicated the improvement in terms of PCE, interface smoothness between the P3HT: PCBM and MoO{sub 3} layers of the post annealed device originated from the decrease of series resistance between P3HT: PCBM layer and Al electrodes, which could be due to decrease in the effective life time of charge carriers.

  13. Performance and impedance studies of thin, porous molybdenum and tungsten electrodes for the alkali metal thermoelectric converter

    NASA Technical Reports Server (NTRS)

    Wheeler, B. L.; Williams, R. M.; Jeffries-Nakamura, B.; Lamb, J. L.; Loveland, M. E.; Bankston, C. P.; Cole, T.

    1988-01-01

    Columnar, porous, magnetron-sputtered molybdenum and tungsten films show optimum performance as alkali metal thermoelectric converter electrodes at thicknesses less than 1.0 micron when used with molybdenum or nickel current collector grids. Power densities of 0.40 W/sq cm for 0.5-micron molybdenum films at 1200 K and 0.35 W/sq cm for 0.5-micron tungsten films at 1180 K were obtained at electrode maturity after 40-90 h. Sheet resistances of magnetron sputter deposited films on sodium beta-double-prime-alumina solid electrolyte (BASE) substrates were found to increase very steeply as thickness is decreased below about 0.3-double-prime 0.4-micron. The ac impedance data for these electrodes have been interpreted in terms of contributions from the bulk BASE and the porous electrode/BASE interface. Voltage profiles of operating electrodes show that the total electrode area, of electrodes with thickness less than 2.0 microns, is not utilized efficiently unless a fairly fine (about 1 x 1 mm) current collector grid is employed.

  14. Study on electromechanical impedance characteristics of part of structures made of CFRP

    NASA Astrophysics Data System (ADS)

    Malinowski, Paweł H.; Wandowski, Tomasz; Ostachowicz, Wiesław M.

    2016-04-01

    Carbon Fibre Reinforced Polymers (CFRP) are more and more used in many branches of industry. Researchers are developing numerous techniques of non-destructive assessment of the structures made out of CFRP such as guided waves, ultrasonics, laser induced fluorescence and others. In this research we focus on electromechanical impedance (EMI) technique. In this technique a piezoelectric sensor is either surface mounted or embedded into investigated host structure. The electrical quantities of the sensor are measured for wide frequency range. Due to piezoelectric effect the electrical response of the sensor is related to mechanical response of the structure to which the sensors is bonded to. In the reported research impedance spectra in the vicinity of the transducer thickness mode were investigated as well as the lower frequency range. The spectra that were analysed were gathered from samples with surface treatment such as thermal degradation and samples adhesively bonded with film adhesive with symmetric and unsymmetric bond. Moreover, the samples with modified adhesive bonds were investigated. These spectra for different cases were compared with reference measurement results gathered from pristine samples. Numerical indexes for comparison of the EMI characteristics were proposed. The comparison of the indexes was also conducted. In the experimental part of the research the piezoelectric transducer was mounted at the sample surface. Measurements were conducted using HIOKI Impedance Analyzer IM3570.

  15. Acoustic impedance studies in Triassic reservoirs in the Netherlands - application to development and exploration

    SciTech Connect

    Griffiths, M.; Ford, J.

    1995-08-01

    Simple and cost effective seismic forward modelling techniques have been used in conjunction with petrophysical and geological data to provide an integrated approach to understanding the seismic response of Triassic gas reservoirs onshore and offshore Netherlands. Analysis shows that for the Volpriehausen Sandstone in the offshore sector a relationship exists between reservoir acoustic impedance and porosity such that an increase in porosity leads to a decrease in acoustic impedance. Data can be sub-divided on the basis of fluid fill and cementation with trends for both gas and water cases. Regression analysis has defined the optimum relationship for each fluid case and these relationships have been used to predict the acoustic impedance profiles for a variety of reservoir scenarios. Modelling shows that the highest seismic amplitudes and the greatest relative amplitude variation with fluid fill are related to high porosity reservoir. In the onshore sector, analysis for the Roet Sandstone has shown that even small scale variations in reservoir properties can be recorded within the detail of the seismic response. Results from seismic forward modelling compare with amplitude variations observed in real data and suggest that, within the limitations of the dataset and methodology, the technique can be used to predict reservoir attributes from the seismic response. So far, the technique has been sucessfully applied to both exploration and field development projects.

  16. Study of DC and AC electric field effect on Pisum sativum seeds growth

    NASA Astrophysics Data System (ADS)

    Mahmood, Bahar; Jaleh, Sojoodi; Yasaman, Yasaie

    2014-07-01

    In this research the effect of electric field on two groups of wet and dry Pisum sativum seeds growth was studied. To generate the required electric field a parallel-plate capacitor with round copper plates of 30 cm diameter was used. The experiments were performed once in fixed exposure duration of 8 min in variable DC electric field of 0.25-1.5 kV/m. The other experiments were performed in variable fields of 50-125 kV/m in fixed exposure duration of 8 min, in two groups of AC and DC electric fields. The experiments were repeated three times. In each experiment 10 seeds were used and there was a sham exposed group for comparison, too. After application of electric field, the seeds were kept for six days in the same growth chamber with the temperature of 25 ± 1 °C and 12 h light/12 h darkness. On the 6th day length of stems and height of roots were measured. After doing statistical analysis, in low intensities of DC electric field, the highest significant increase of mean growth (The average of stem length and the height of roots) was seen in 1.5 kV/m in wet seeds. In high intensities of DC and AC electric fields, the highest significant increase of mean growth was seen in AC electric field of 100 kV/m in wet seeds.

  17. Introducing AC inductive reactance with a power tool

    NASA Astrophysics Data System (ADS)

    Bryant, Wesley; Baker, Blane

    2016-09-01

    The concept of reactance in AC electrical circuits is often non-intuitive and difficult for students to grasp. In order to address this lack of conceptual understanding, classroom exercises compare the predicted resistance of a power tool, based on electrical specifications, to measured resistance. Once students discover that measured resistance is smaller than expected, they are asked to explain these observations using previously studied principles of magnetic induction. Exercises also introduce the notion of inductive reactance and impedance in AC circuits and, ultimately, determine self-inductance of the motor windings within the power tool.

  18. Structural, dielectric and impedance studies of polycrystalline La0.6Gd0.2Ca0.2MnO3

    NASA Astrophysics Data System (ADS)

    Nandan K., R.; Rubankumar, A.; Kalainathan, S.

    2016-05-01

    Polycrystalline materials of Gd doped La1-xCaxMnO3 were prepared by Sol-Gel technique using citric acid as a chelating agent at 9000 C. The single phase formation of Gd doped LCMO were determined by Powder XRD, dielectric studies and impedance studies is investigated. The existence of dielectric relaxation and release of space charges were observed in the dielectric constant and real part of impedance plots respectively. The shift in the peaks for imaginary part of impedance revealed the existence of relaxation process due to oxygen vacancy. The existence of single semicircle in the cole-cole plot confirms the dielectric relaxation in the prepared sample.

  19. Models of Longitudinal Space-Charge Impedance for the Study of theMicrobunching Instability

    SciTech Connect

    Venturini, Marco

    2008-03-10

    A 1D model of space-charge impedance, assuming atransversely uniform beam with circular cross-section, has been proposedand is being extensively used in the modelling of the microbunchinginstability of relevance for the beam delivery systems of x-ray FELs. Inthis paper we investigate the limitation of the model when applied tostudying the effect of shot noise--one of the sources of themicrobunching instability. We make comparison witha fully 3D calculationand identify the upper end of the frequency spectrum for applicability ofthe 1D model. Relaxation of the assumptions regarding axis-symmetry anduniformity of the transverse density is also reviewed.

  20. Retention studies of recoiling daughter nuclides of 225Ac in polymer vesicles.

    PubMed

    Wang, G; de Kruijff, R M; Rol, A; Thijssen, L; Mendes, E; Morgenstern, A; Bruchertseifer, F; Stuart, M C A; Wolterbeek, H T; Denkova, A G

    2014-02-01

    Alpha radionuclide therapy is steadily gaining importance and a large number of pre-clinical and clinical studies have been carried out. However, due to the recoil effects the daughter recoil atoms, most of which are alpha emitters as well, receive energies that are much higher than the energies of chemical bonds resulting in decoupling of the radionuclide from common targeting agents. Here, we demonstrate that polymer vesicles (i.e. polymersomes) can retain recoiling daughter nuclei based on an experimental study examining the retention of (221)Fr and (213)Bi when encapsulating (225)Ac. PMID:24374072

  1. Retention studies of recoiling daughter nuclides of 225Ac in polymer vesicles.

    PubMed

    Wang, G; de Kruijff, R M; Rol, A; Thijssen, L; Mendes, E; Morgenstern, A; Bruchertseifer, F; Stuart, M C A; Wolterbeek, H T; Denkova, A G

    2014-02-01

    Alpha radionuclide therapy is steadily gaining importance and a large number of pre-clinical and clinical studies have been carried out. However, due to the recoil effects the daughter recoil atoms, most of which are alpha emitters as well, receive energies that are much higher than the energies of chemical bonds resulting in decoupling of the radionuclide from common targeting agents. Here, we demonstrate that polymer vesicles (i.e. polymersomes) can retain recoiling daughter nuclei based on an experimental study examining the retention of (221)Fr and (213)Bi when encapsulating (225)Ac.

  2. A Comparison Study of Normal-Incidence Acoustic Impedance Measurements of a Perforate Liner

    NASA Technical Reports Server (NTRS)

    Schultz, Todd; Liu, Fei; Cattafesta, Louis; Sheplak, Mark; Jones, Michael

    2009-01-01

    The eduction of the acoustic impedance for liner configurations is fundamental to the reduction of noise from modern jet engines. Ultimately, this property must be measured accurately for use in analytical and numerical propagation models of aircraft engine noise. Thus any standardized measurement techniques must be validated by providing reliable and consistent results for different facilities and sample sizes. This paper compares normal-incidence acoustic impedance measurements using the two-microphone method of ten nominally identical individual liner samples from two facilities, namely 50.8 mm and 25.4 mm square waveguides at NASA Langley Research Center and the University of Florida, respectively. The liner chosen for this investigation is a simple single-degree-of-freedom perforate liner with resonance and anti-resonance frequencies near 1.1 kHz and 2.2 kHz, respectively. The results show that the ten measurements have the most variation around the anti-resonance frequency, where statistically significant differences exist between the averaged results from the two facilities. However, the sample-to-sample variation is comparable in magnitude to the predicted cross-sectional area-dependent cavity dissipation differences between facilities, providing evidence that the size of the present samples does not significantly influence the results away from anti-resonance.

  3. Hydrogen-terminated detonation nanodiamond: Impedance spectroscopy and thermal stability studies

    NASA Astrophysics Data System (ADS)

    Su, Shi; Li, Jiangling; Kundrát, Vojtěch; Abbot, Andrew M.; Ye, Haitao

    2013-01-01

    In this paper, we investigated the effect of hydrogen termination on the electrical properties and impedance spectra of detonation nanodiamond. The impedance spectra revealed that the hydrogen-termination process increases the electrical conductivity by four orders of magnitude at room temperature. An equivalent circuit has been proposed to correlate with the conduction mechanism. Arrhenius plot showed that there were two different activation energy levels located at 0.089 eV and 0.63 eV between 50 °C and 400 °C. The possible physical mechanism corresponding to these activation energy levels has been discussed. Hydrogen-terminated detonation nanodiamond has been further annealed at different temperatures prior to FTIR and XPS measurements in order to understand their thermal stability. The results demonstrated that the surface oxidization occurred between 100 °C and 150 °C. However, the C-H bonds could partially survive when the temperature reaches 400 °C in air.

  4. Isolation of sequences flanking Ac insertion sites by Ac casting.

    PubMed

    Wang, Dafang; Peterson, Thomas

    2013-01-01

    Localizing Ac insertions is a fundamental task in studying Ac-induced mutation and chromosomal rearrangements involving Ac elements. Researchers may sometimes be faced with the situation in which the sequence flanking one side of an Ac/Ds element is known, but the other flank is unknown. Or, a researcher may have a small sequence surrounding the Ac/Ds insertion site and needs to obtain additional flanking genomic sequences. One way to rapidly clone unknown Ac/Ds flanking sequences is via a PCR-based method termed Ac casting. This approach utilizes the somatic transposition activity of Ac during plant development, and provides an efficient means for short-range genome walking. Here we describe the principle of Ac casting, and show how it can be applied to isolate Ac macrotransposon insertion sites.

  5. Electrical impedance tomography to evaluate air distribution prior to extubation in very-low-birth-weight infants: a feasibility study

    PubMed Central

    de Souza Rossi, Felipe; Yagui, Ana Cristina Zanon; Haddad, Luciana Branco; Deutsch, Alice D'Agostini; Rebello, Celso Moura

    2013-01-01

    OBJECTIVES: Nasal continuous positive airway pressure is used as a standard of care after extubation in very-low-birth-weight infants. A pressure of 5 cmH2O is usually applied regardless of individual differences in lung compliance. Current methods for evaluation of lung compliance and air distribution in the lungs are thus imprecise for preterm infants. This study used electrical impedance tomography to determine the feasibility of evaluating the positive end-expiratory pressure level associated with a more homogeneous air distribution within the lungs before extubation. METHODS: Ventilation homogeneity was defined by electrical impedance tomography as the ratio of ventilation between dependent and non-dependent lung areas. The best ventilation homogeneity was achieved when this ratio was equal to 1. Just before extubation, decremental expiratory pressure levels were applied (8, 7, 6 and 5 cmH20; 3 minutes each step), and the pressure that determined the best ventilation homogeneity was defined as the best positive end-expiratory pressure. RESULTS: The best positive end-expiratory pressure value was 6.3±1.1 cmH20, and the mean continuous positive airway pressure applied after extubation was 5.2±0.4 cmH20 (p = 0.002). The extubation failure rate was 21.4%. X-Ray and blood gases after extubation were also checked. CONCLUSION: This study demonstrates that electrical impedance tomography can be safely and successfully used in patients ready for extubation to suggest the best ventilation homogeneity, which is influenced by the level of expiratory pressure applied. In this feasibility study, the best lung compliance was found with pressure levels higher than the continuous positive airway pressure levels that are usually applied for routine extubation. PMID:23644854

  6. High-impedance wire grid method to study spatiotemporal behavior of hot electron clump generated in a plasma

    SciTech Connect

    Terasaka, K. Kato, Y.; Tanaka, M. Y.; Yoshimura, S.; Morisaki, T.; Furuta, K.; Aramaki, M.

    2014-11-15

    High-impedance Wire Grid (HIWG) detector has been developed to study spatiotemporal behavior of a hot electron clump generated in an electron cyclotron resonance (ECR) plasma. By measuring the floating potentials of the wire electrodes, and generating structure matrix made of geometrical means of the floating potentials, the HIWG detector reconstructs the spatial distribution of high-temperature electron clump at an arbitrary instant of time. Time slices of the spike event in floating potential revealed the growth and decay process of a hot spot occurs in an ECR plasma.

  7. A study on transmission characteristics and specific absorption rate using impedance-matched electrodes for various human body communication.

    PubMed

    Machida, Yuta; Yamamoto, Takahiko; Koshiji, Kohji

    2013-01-01

    Human body communication (HBC) is a new communication technology that has presented potential applications in health care and elderly support systems in recent years. In this study, which is focused on a wearable transmitter and receiver for HBC in a body area network (BAN), we performed electromagnetic field analysis and simulation using the finite difference time domain (FDTD) method with various models of the human body. Further we redesigned a number of impedance-matched electrodes to allow transmission without stubs or transformers. The specific absorption rate (SAR) and transmission characteristics S21 of these electrode structures were compared for several models.

  8. Transport in fuel cells: Electrochemical impedance spectroscopy and neutron imaging studies

    NASA Astrophysics Data System (ADS)

    Aaron, Douglas Scott

    This dissertation focuses on two powerful methods of performing in-situ studies of transport limitations in fuel cells. The first is electrochemical impedance spectroscopy (EIS) while the second is neutron imaging. Three fuel cell systems are studied in this work: polymer electrolyte membrane fuel cells (PEMFCs), microbial fuel cells (MFCs) and enzyme fuel cells (EFCs). The first experimental section of this dissertation focuses on application of EIS and neutron imaging to an operating PEMFC. The effects of cathode-side humidity and flow rate, as well as cell temperature and a transient response to cathode-side humidity, were studied for a PEMFC via EIS. It was found that increased air humidity in the cathode resulted in greatly reduced cathode resistance as well as a significant reduction in membrane resistance. The anode resistance was only slightly reduced in this case. Increased air flow rate was observed to have little effect on any resistance in the PEMFC, though slight reductions in both the anode and the cathode were observed. Increased cell temperature resulted in decreased cathode and anode resistances. Finally, the transient response to increased humidity exhibited unstable behavior for both the anode and the cathode resistances and the PEMFC power output. Neutron imaging allowed the calculation of water content throughout the PEMFC, showing a maximum in water content at the cathode gas diffusion layer - membrane interface. The second experimental section of this dissertation delves into the world of microbial fuel cells. Multiple long-term observations of changes in internal resistances were performed and illustrated the reduction in anode resistance as the bacterial community was established. Over this same time period, the cathode resistance was observed to have increased; these two phenomena suggest that the anode improved over time while the cathode suffered from degradation. Increased anode fluid ionic strength and flow rate both led to significant

  9. Investigation of nanocrystalline CdS/Si diode using complex impedance spectroscopy

    SciTech Connect

    El-Gendy, Y.A.; Yahia, I.S.; Yakuphanoglu, F.

    2012-11-15

    Highlights: ► CdS/n-Si device was fabricated as a heterostructure. ► AFM was used to examine the structure of CdS/n-Si. ► Complex impedance Z′and Z″were calculated. ► AC conductivity was explained by the power law relation. ► CBH model was used to describe the AC conduction mechanism. -- Abstract: CdS/n-Si device was fabricated via depositing CdS thin film onto pre-cleaned n-silicon substrates. The atomic force microscope was used to examine the crystal size of the deposited films and its roughness. The AC conductivity and the real part of complex impedance Z′as a function of frequency at different temperatures were studied. The AC conductivity dependence of the applied frequency was explained on the basis of the power law relation. The bulk resistance has been calculated at different temperatures from the complex impedance Z″. The temperature dependence of capacitance for CdS/n-Si device at different frequencies was also investigated.

  10. The effect of enterotoxigenic Escherichia coli F4ab,ac on early-weaned piglets: a gene expression study.

    PubMed

    Schroyen, M; Goddeeris, B M; Stinckens, A; Verhelst, R; Janssens, S; Cox, E; Georges, M; Niewold, T; Buys, N

    2013-03-15

    Diarrhoea in neonatal and early-weaned piglets due to enterotoxigenic Escherichia coli-F4 (ETEC-F4) is an important problem in the pig farming industry. There is substantial evidence for a genetic basis for susceptibility to ETEC-F4 since not all pigs suffer from diarrhoea after an ETEC-F4 infection. A region on SSC13 has been found to be in close linkage to the susceptibility of piglets for ETEC-F4ab,ac. Potential candidate genes on SSC13 have been examined and although some polymorphisms were found to be in linkage disequilibrium with the phenotype, the causative mutation has not yet been found. In this study we are looking at the expression of porcine genes in relation to ETEC-F4ab,ac. With the aid of the Affymetrix GeneChip Porcine Genome Array we were able to find differentially expressed genes between ETEC-F4ab,ac receptor positive (Fab,acR(+)) piglets without diarrhoea and F4ab,acR(+) piglets with diarrhoea or F4ab,acR(-) animals. Since the susceptibility to ETEC-F4ab,ac was described as a Mendelian trait, it is not so surprisingly that only two differentially expressed genes, transferrin receptor (TFRC) and trefoil factor 1 (TFF1), came out of the analysis. Although both genes could pass for functional candidate genes only TFRC also mapped to the region on SSC13 associated with susceptibility for ETEC-F4, which makes TFRC a positional functional candidate gene. Validation by qRT-PCR confirmed the differential expression of TFRC and TFF1. In piglets without diarrhoea, the expression of both genes was higher in F4ab,acR(+) than in F4ab,acR(-) piglets. Similarly, TFRC and TFF1 expression in F4ab,acR(+) piglets without diarrhoea was also higher than in F4ab,acR(+) piglets with diarrhoea. Consequently, although both genes might not play a role as receptor for F4 fimbriae, they could be of great importance during an ETEC-F4 outbreak. An upregulation of TFRC can be a consequence of the piglets ability to raise an effective immune response. An elevation of TFF1, a

  11. Serotonergic genes and depressive disorder in acute coronary syndrome: The Korean depression in ACS (K-DEPACS) study.

    PubMed

    Kim, Jae-Min; Stewart, Robert; Kang, Hee-Ju; Bae, Kyung-Yeol; Kim, Sung-Wan; Shin, Il-Seon; Hong, Young Joon; Ahn, Youngkeun; Jeong, Myung Ho; Park, Sung-Woo; Kim, Young-Hoon; Yoon, Jin-Sang

    2015-06-01

    Genes coding for the serotonergic pathway have been associated with depressive disorders. However, these associations have rarely been tested in acute coronary syndrome (ACS) patients vulnerable to depression. This study aimed to investigate whether polymorphisms of serotonin transporter (5-HTT) and serotonin 2a receptor (5-HTR2a) genes are associated with occurrence of depressive disorder in ACS. 969 patients with recently developed ACS were recruited at baseline, and 711 were followed 1 year thereafter. Depressive disorder was diagnosed according to DSM-IV criteria, and analysed as an outcome at baseline (prevalence), and follow up (incidence and persistence). Genotypes were ascertained for 5-HTTLPR, STin2 VNTR, 5-HTR2a 102T/C, and 5-HTR2a 1438A/G. Logistic regression models were used to investigate associations. The 5-HTTLPR s/s genotype was independently associated with depressive disorder prevalence and persistence following ACS, but no significant associations were found with the other polymorphisms. ACS patients with the 5-HTTLPR s allele are thus potentially susceptible to depressive disorder in the early phase after ACS, and with its persistence over the subsequent year.

  12. Long-term toxicity study on transgenic rice with Cry1Ac and sck genes.

    PubMed

    Zhang, Min; Zhuo, Qin; Tian, Yuan; Piao, Jianhua; Yang, Xiaoguang

    2014-01-01

    In the present work, we evaluated the chronic effects of the transgenic insect-resistant rice carrying Cry1Ac and sck genes on Sprague-Dawley (SD) rats through a 78-week feeding study. Based on the gender and weight, 180 SD rats were randomly and evenly assigned into three groups. GM rice and non-GM rice were separately formulated into diets at high levels. AIN-93 diet was used as a nutritional control. Body weight, food consumption, hematology and serum chemistry were monitored regularly. Rats were sacrificed for organ weight measurement and pathological examination at 52 weeks and 78 weeks. Body weight, food consumption, mortality rates, tumor incidences and pathological findings showed no significant difference among the three groups. Although certain differences in some hematology, serum chemistry parameters and relative organ weights were observed between GM rice group and control groups, they were not considered as treatment-related. Taken together, long-term intake of transgenic rice carrying Cry1Ac and sck genes at a high level exerts no unintended adverse effects on rats.

  13. Impedance spectroscopy study of a catechol-modified activated carbon electrode as active material in electrochemical capacitor

    NASA Astrophysics Data System (ADS)

    Cougnon, C.; Lebègue, E.; Pognon, G.

    2015-01-01

    Modified activated carbon (Norit S-50) electrodes with electrochemical double layer (EDL) capacitance and redox capacitance contributions to the electric charge storage were tested in 1 M H2SO4 to quantify the benefit and the limitation of the surface redox reactions on the electrochemical performances of the resulting pseudo-capacitive materials. The electrochemical performances of an electrochemically anodized carbon electrode and a catechol-modified carbon electrode, which make use both EDL capacitance of the porous structure of the carbon and redox capacitance, were compared to the performances obtained for the pristine carbon. Nitrogen gas adsorption measurements have been used for studying the impact of the grafting on the BET surface area, pore size distribution, pore volume and average pore diameter. The electrochemical behavior of carbon materials was studied by cyclic voltammetry and electrochemical impedance spectroscopy (EIS). The EIS data were discussed by using a complex capacitance model that allows defining the characteristic time constant, the global capacitance and the frequency at which the maximum charge stored is reached. The EIS measurements were achieved at different dc potential values where a redox activity occurs and the evolution of the capacitance and the capacitive relaxation time with the electrode potential are presented. Realistic galvanostatic charge/discharge measurements performed at different current rates corroborate the results obtained by impedance.

  14. Charge Carrier Conduction Mechanism in PbS Quantum Dot Solar Cells: Electrochemical Impedance Spectroscopy Study.

    PubMed

    Wang, Haowei; Wang, Yishan; He, Bo; Li, Weile; Sulaman, Muhammad; Xu, Junfeng; Yang, Shengyi; Tang, Yi; Zou, Bingsuo

    2016-07-20

    With its properties of bandgap tunability, low cost, and substrate compatibility, colloidal quantum dots (CQDs) are becoming promising materials for optoelectronic applications. Additionally, solution-processed organic, inorganic, and hybrid ligand-exchange technologies have been widely used in PbS CQDs solar cells, and currently the maximum certified power conversion efficiency of 9.9% has been reported by passivation treatment of molecular iodine. Presently, there are still some challenges, and the basic physical mechanism of charge carriers in CQDs-based solar cells is not clear. Electrochemical impedance spectroscopy is a monitoring technology for current by changing the frequency of applied alternating current voltage, and it provides an insight into its electrical properties that cannot be measured by direct current testing facilities. In this work, we used EIS to analyze the recombination resistance, carrier lifetime, capacitance, and conductivity of two typical PbS CQD solar cells Au/PbS-TBAl/ZnO/ITO and Au/PbS-EDT/PbS-TBAl/ZnO/ITO, in this way, to better understand the charge carriers conduction mechanism behind in PbS CQD solar cells, and it provides a guide to design high-performance quantum-dots solar cells. PMID:27176547

  15. Electrochemical Impedance Studies on Tribocorrosion Behavior of Plasma-Sprayed Al2O3 Coatings

    NASA Astrophysics Data System (ADS)

    Liu, Zhe; Chu, Zhenhua; Chen, Xueguang; Dong, Yanchun; Yang, Yong; Li, Yingzhen; Yan, Dianran

    2015-06-01

    In this paper, the tribocorrosion of plasma-sprayed Al2O3 coatings in simulated seawater was investigated by electrochemical impedance spectroscopy (EIS) technique, complemented by scanning electron microscopy to observe the morphology of the tribocorrosion attack. Base on EIS of plasma-sprayed Al2O3 coatings undergoing long-time immersion in simulated seawater, the corrosion process of Al2O3 coatings can be divided into the earlier stage of immersion (up to 20 h) and the later stage (beyond 20 h). Then, the wear tests were carried out on the surface of Al2O3 coating undergoing different times of immersion to investigate the influence of wear on corrosion at different stages. The coexistence of wear and corrosion condition had been created by a boron nitride grinding head rotating on the surface of coatings corroded in simulated seawater. The measured EIS and the values of the fitting circuit elements showed that wear accelerated corrosion at the later stage, meanwhile, corrosion accelerated wear with the immersion time increasing.

  16. Sensitivity study of an ultrasound coupled transrectal electrical Impedance Tomography system for prostate imaging

    NASA Astrophysics Data System (ADS)

    Wan, Y.; Halter, R.; Borsic, A.; Manwaring, P.; Hartov, A.; Paulsen, K.

    2010-04-01

    In 2009, prostate cancer ranks as the most common cancer and the second most fatal cancer in men in the United States. Unfortunately, the current clinical diagnostic methods (e.g. prostate-specific antigen (PSA), digital rectal examination, endorectal MRI, transrectal ultrasound, biopsy) used for detecting and staging prostate cancer are limited. It has been shown that cancerous prostate tissue has significantly different electrical properties when compared to benign tissues. Based on these electrical property findings, a TransRectal Electrical Impedance Tomography (TREIT) system is proposed as a novel prostate imaging modality. The TREIT system is comprised of an array of electrodes interfaced with a clinical TransRectal UltraSound (TRUS) probe. We evaluate this imaging system through series of phantom imaging experiments to assess the system's ability to image high and low contrast objects at various positions. We found that the TREIT system can easily discern high contrast inclusions of 1 cm in diameter at distances centered at 2 times the radius of the TREIT probe away from the probe surface. Furthermore, this technology's ability to detect low contrast inclusions suggests that it has the potential to successfully detect prostate cancer.

  17. Electrical impedance myography for the assessment of children with muscular dystrophy: a preliminary study

    PubMed Central

    Rutkove, S B; Darras, B T

    2013-01-01

    Electrical impedance myography (EIM) provides a non-invasive approach for quantifying the severity of neuromuscular disease. Here we determine how well EIM data correlates to functional and ultrasound (US) measures of disease in children with Duchenne muscular dystrophy (DMD) and healthy subjects. Thirteen healthy boys, aged 2-12 years and 14 boys with DMD aged 4-12 years underwent both EIM and US measurements of deltoid, biceps, wrist flexors, quadriceps, tibialis anterior, and medial gastrocnemius. EIM measurements were performed with a custom-designed probe using a commercial multifrequency bioimpedance device. US luminosity data were quantified using a gray-scale analysis approach. Children also underwent the 6-minute walk test, timed tests and strength measurements. EIM and US data were combined across muscles. EIM 50 kHz phase was able to discriminate DMD children from healthy subjects with 98% accuracy. In the DMD patients, average EIM phase measurements also correlated well with standard functional measures. For example the 50 kHz phase correlated with the Northstar Ambulatory Assessment test (R = 0.83, p = 0.02). EIM 50 kHz phase and US correlated as well, with R = −0.79 (p < 0.001). These results show that EIM provides valuable objective measures Duchenne muscular dystrophy severity. PMID:23894248

  18. Effects of Operating Conditions on Internal Resistances in Enzyme Fuel Cells Studied via Electrochemical Impedance Spectroscopy

    SciTech Connect

    Aaron, D; Borole, Abhijeet P; Yiacoumi, Sotira; Tsouris, Costas

    2012-01-01

    Enzyme fuel cells (EFCs) offer some advantages over traditional precious-metal-catalyzed fuel cells, such as polymer electrolyte membrane fuel cells (PEMFCs). However, EFCs exhibit far less power output than PEMFCs and have relatively short life spans before materials must be replaced. In this work, electrochemical impedance spectroscopy (EIS) is used to analyze the internal resistances throughout the EFC at a variety of operating conditions. EIS analysis is focused primarily on the resistances of the anode, solution/membrane, and cathode. Increased enzyme loading results in improved power output and reductions in internal resistance. Conditions are identified for which enzyme loading does not limit the EFC performance. EIS experiments are also reported for EFCs operated continuously for 2 days; power output declines sharply over time, while all internal resistances increase. Drying of the cathode and enzyme/mediator degradation are believed to have contributed to this behavior. Finally, experiments are performed at varying air-humidification temperatures. Little effect on internal resistances or power output is observed. However, it is anticipated that increased air humidification can improve longevity by delivering more water to the cathode. Improvements to the enzymatic cathode are needed for EFC development. These improvements need to focus on improving transport rather than increasing enzyme loading.

  19. Charge Carrier Conduction Mechanism in PbS Quantum Dot Solar Cells: Electrochemical Impedance Spectroscopy Study.

    PubMed

    Wang, Haowei; Wang, Yishan; He, Bo; Li, Weile; Sulaman, Muhammad; Xu, Junfeng; Yang, Shengyi; Tang, Yi; Zou, Bingsuo

    2016-07-20

    With its properties of bandgap tunability, low cost, and substrate compatibility, colloidal quantum dots (CQDs) are becoming promising materials for optoelectronic applications. Additionally, solution-processed organic, inorganic, and hybrid ligand-exchange technologies have been widely used in PbS CQDs solar cells, and currently the maximum certified power conversion efficiency of 9.9% has been reported by passivation treatment of molecular iodine. Presently, there are still some challenges, and the basic physical mechanism of charge carriers in CQDs-based solar cells is not clear. Electrochemical impedance spectroscopy is a monitoring technology for current by changing the frequency of applied alternating current voltage, and it provides an insight into its electrical properties that cannot be measured by direct current testing facilities. In this work, we used EIS to analyze the recombination resistance, carrier lifetime, capacitance, and conductivity of two typical PbS CQD solar cells Au/PbS-TBAl/ZnO/ITO and Au/PbS-EDT/PbS-TBAl/ZnO/ITO, in this way, to better understand the charge carriers conduction mechanism behind in PbS CQD solar cells, and it provides a guide to design high-performance quantum-dots solar cells.

  20. Electrical impedance myography for the assessment of children with muscular dystrophy: a preliminary study

    NASA Astrophysics Data System (ADS)

    Rutkove, S. B.; Darras, B. T.

    2013-04-01

    Electrical impedance myography (EIM) provides a non-invasive approach for quantifying the severity of neuromuscular disease. Here we determine how well EIM data correlates to functional and ultrasound (US) measures of disease in children with Duchenne muscular dystrophy (DMD) and healthy subjects. Thirteen healthy boys, aged 2-12 years and 14 boys with DMD aged 4-12 years underwent both EIM and US measurements of deltoid, biceps, wrist flexors, quadriceps, tibialis anterior, and medial gastrocnemius. EIM measurements were performed with a custom-designed probe using a commercial multifrequency bioimpedance device. US luminosity data were quantified using a gray-scale analysis approach. Children also underwent the 6-minute walk test, timed tests and strength measurements. EIM and US data were combined across muscles. EIM 50 kHz phase was able to discriminate DMD children from healthy subjects with 98% accuracy. In the DMD patients, average EIM phase measurements also correlated well with standard functional measures. For example the 50 kHz phase correlated with the Northstar Ambulatory Assessment test (R = 0.83, p = 0.02). EIM 50 kHz phase and US correlated as well, with R = -0.79 (p < 0.001). These results show that EIM provides valuable objective measures Duchenne muscular dystrophy severity.

  1. ADVANCES IN IMPEDANCE THEORY

    SciTech Connect

    Stupakov, G.; /SLAC

    2009-06-05

    We review recent progress in the following areas of the impedance theory: calculation of impedance of tapers and small angle collimators; optical approximation and parabolic equation for the high-frequency impedance; impedance due to resistive inserts in a perfectly conducting pipe.

  2. Impedance analysis of acupuncture points and pathways

    NASA Astrophysics Data System (ADS)

    Teplan, Michal; Kukučka, Marek; Ondrejkovičová, Alena

    2011-12-01

    Investigation of impedance characteristics of acupuncture points from acoustic to radio frequency range is addressed. Discernment and localization of acupuncture points in initial single subject study was unsuccessfully attempted by impedance map technique. Vector impedance analyses determined possible resonant zones in MHz region.

  3. (abstract) Scaling Nominal Solar Cell Impedances for Array Design

    NASA Technical Reports Server (NTRS)

    Mueller, Robert L; Wallace, Matthew T.; Iles, Peter

    1994-01-01

    This paper discusses a task the objective of which is to characterize solar cell array AC impedance and develop scaling rules for impedance characterization of large arrays by testing single solar cells and small arrays. This effort is aimed at formulating a methodology for estimating the AC impedance of the Mars Pathfinder (MPF) cruise and lander solar arrays based upon testing single cells and small solar cell arrays and to create a basis for design of a single shunt limiter for MPF power control of flight solar arrays having very different inpedances.

  4. Design studies for the Mead-Phoenix 500 kV AC transmission project

    SciTech Connect

    Thallam, R.S.; Lundquist, T.G.; Gerlach, D.W.; Atmuri, S.R.; Selin, D.A.

    1995-10-01

    The Mead-Phoenix 500 kV ac line is 243 miles long and runs parallel to the existing Mead-Liberty 345 kV line. This line is planned for 70% series and 70% shunt compensation; it also incorporates the first application of a 50 kV phase shifting transformer that enables a 1,300 MW transmission capacity. This paper presents the design studies that were undertaken in arriving at the equipment ratings and insulation levels that lead to the equipment specifications. The shunt reactor switching requirements utilizing MOV across the breaker, line switching with line connected arresters and the breaker transient recovery voltage are also dealt with in the paper.

  5. Comparative Study of DC and AC Microgrids in Commercial Buildings Across Different Climates and Operating Profiles: Preprint

    SciTech Connect

    Fregosi, D.; Ravula, S.; Brhlik, D.; Saussele, J.; Frank, S.; Bonnema, E.; Scheib, J.; Wilson, E.

    2015-04-22

    Bosch has developed and demonstrated a novel DC microgrid system designed to maximize utilization efficiency for locally generated photovoltaic energy while offering high reliability, safety, redundancy, and reduced cost compared to equivalent AC systems. Several demonstration projects validating the system feasibility and expected efficiency gains have been completed and additional ones are in progress. This work gives an overview of the Bosch DC microgrid system and presents key results from a large simulation study done to estimate the energy savings of the Bosch DC microgrid over conventional AC systems. The study examined the system performance in locations across the United States for several commercial building types and operating profiles and found that the Bosch DC microgrid uses generated PV energy 6%–8% more efficiently than traditional AC systems.

  6. Application of electrical impedance tomography in diagnosis of emphysema--a clinical study.

    PubMed

    Eyüboğlu, B M; Oner, A F; Baysal, U; Biber, C; Keyf, A I; Yilmaz, U; Erdoğan, Y

    1995-08-01

    In this paper, electrical impedance tomography (EIT) ventilation images from a group of 12 patients (11 patients with emphysema and one patient with only chronic obstructive pulmonary disease (COPD) (chronic bronchitis) and a group of 15 normal subjects were acquired using a Sheffield mark 1 EIT system, at the levels of second, fourth and sixth intercostal spaces. Patients were diagnosed based on CT scans of the thorax, pulmonary function tests and posteroanterior x-ray graphs. One of the patients with emphysema has also a malignant lung tumour. Ventilation-related conductivity changes at total lung capacity (TLC) relative to residual volume were measured quantitatively in EIT images. These quantitative values demonstrate marked differences compared to those values obtained from the EIT images of 15 normal subjects. The EIT images of the patients were also compared with the CT images. In addition to the visual examination of the EIT images a statistical confidence test is applied to compare the images of the patients with the images of the normal subjects. Prior to statistical analysis all images are normalized with TLC to minimize the effect of mismatch between the TLC of different subjects. A normal mean image is created by averaging the normalized images from the normal subjects, at each intercostal space level. Than a 95% confidence interval is defined for each normal mean image. For each image of the patients, a confidence test image, which represents the deviations from the 95% confidence interval of the normal mean image, is created. The regions with emphysematous bulla and parencyhma are detectable in the confidence test images as regions of positive and negative deviations from the confidence interval of the normal mean, respectively. In the test images, it is possible to differentiate emphysematous parenchyma from emphysematous bulla, tumour structure, and COPD. However, the emphysematous bulla, the tumour structure, and COPD result in the same type of

  7. Electrical impedance along connective tissue planes associated with acupuncture meridians

    PubMed Central

    Ahn, Andrew C; Wu, Junru; Badger, Gary J; Hammerschlag, Richard; Langevin, Helene M

    2005-01-01

    Background Acupuncture points and meridians are commonly believed to possess unique electrical properties. The experimental support for this claim is limited given the technical and methodological shortcomings of prior studies. Recent studies indicate a correspondence between acupuncture meridians and connective tissue planes. We hypothesized that segments of acupuncture meridians that are associated with loose connective tissue planes (between muscles or between muscle and bone) visible by ultrasound have greater electrical conductance (less electrical impedance) than non-meridian, parallel control segments. Methods We used a four-electrode method to measure the electrical impedance along segments of the Pericardium and Spleen meridians and corresponding parallel control segments in 23 human subjects. Meridian segments were determined by palpation and proportional measurements. Connective tissue planes underlying those segments were imaged with an ultrasound scanner. Along each meridian segment, four gold-plated needles were inserted along a straight line and used as electrodes. A parallel series of four control needles were placed 0.8 cm medial to the meridian needles. For each set of four needles, a 3.3 kHz alternating (AC) constant amplitude current was introduced at three different amplitudes (20, 40, and 80 μAmps) to the outer two needles, while the voltage was measured between the inner two needles. Tissue impedance between the two inner needles was calculated based on Ohm's law (ratio of voltage to current intensity). Results At the Pericardium location, mean tissue impedance was significantly lower at meridian segments (70.4 ± 5.7 Ω) compared with control segments (75.0 ± 5.9 Ω) (p = 0.0003). At the Spleen location, mean impedance for meridian (67.8 ± 6.8 Ω) and control segments (68.5 ± 7.5 Ω) were not significantly different (p = 0.70). Conclusion Tissue impedance was on average lower along the Pericardium meridian, but not along the Spleen

  8. Corrosion protection of copper by polypyrrole film studied by electrochemical impedance spectroscopy and the electrochemical quartz microbalance

    NASA Astrophysics Data System (ADS)

    Lei, Yanhua; Ohtsuka, Toshiaki; Sheng, Nan

    2015-12-01

    Polypyrrole (PPy) films were synthesized on copper in solution of sodium di-hydrogen phosphate and phytate for corrosion protection. The protection properties of PPy films were comparatively investigated in NaCl solution. During two months immersion, the PPy film doped with phytate anions, working as a cationic perm-selective membrane, inhibited the dissolution of copper to 1% of bare copper. Differently, the PPy film doped with di-hydrogen phosphate anions, possessing anionic perm-selectivity, was gradually reduced, and inhibited the dissolution to 7.8% of bare copper. Degradation of the PPy films was studied by comparing the electrochemical impedance spectroscopy change at different immersion time and Raman spectra change after immersion.

  9. Rapid Electron Transport Phenomenon in the Bis(terpyridine) Metal Complex Wire: Marcus Theory and Electrochemical Impedance Spectroscopy Study.

    PubMed

    Maeda, Hiroaki; Sakamoto, Ryota; Nishihara, Hiroshi

    2015-10-01

    The authors reported previously that bis(terpyiridne)iron(II) complex oligomer wires possess outstanding long-range intrawire electron transport ability. Here, molecular arrays of gold-electrode-bis(terpyridine)iron(II)-ferrocene are constructed by stepwise coordination as simple models of the oligomer wire system. The fast electron transfer between the terminal ferrocene and the gold electrode through the bis(terpyiridne)iron(II) complex unit is studied by potential step chronoamperometry (PSCA) and electrochemical impedance spectroscopy (EIS). Tafel plots derived from PSCA are analyzed based on Marcus theory. The plots reveal greater first-order electron transfer rate constant, weaker electronic coupling between the terminal ferrocene and the gold electrode, and smaller reorganization energy than shown by a conventional ferrocenylalkanethiol self-assembled monolayer. The electron transfer rate constants estimated by EIS agree with the PSCA results.

  10. Dopant effects on 2-ethyl-1-hexanol: A dual-channel impedance spectroscopy and neutron scattering study

    NASA Astrophysics Data System (ADS)

    Singh, Lokendra P.; Raihane, Ahmed; Alba-Simionesco, Christiane; Richert, Ranko

    2015-01-01

    A two-channel impedance technique has been used to study the relaxation behavior of 2-ethyl-1-hexanol with polar and non-polar dopants at the few percent concentration level over a wide temperature and frequency range. The non-polar dopants shift both the Debye and the primary structural relaxation time in the same direction, to shorter times for 3-methylpentane and to longer times for squalane, consistent with the relative glass transition temperatures (Tg) of the components. By contrast, polar dopants such as water or methanol modify the α-process towards slower dynamics and increased amplitude, while the Debye process is accelerated and with a decreased amplitude. This effect of adding water to alcohol is explained by water promoting more compact structures with reduced Kirkwood correlation factors. This picture is consistent with a shift in the neutron scattering pre-peak to lower scattering vectors and with simulation work on alcohol-water systems.

  11. Dopant effects on 2-ethyl-1-hexanol: a dual-channel impedance spectroscopy and neutron scattering study.

    PubMed

    Singh, Lokendra P; Raihane, Ahmed; Alba-Simionesco, Christiane; Richert, Ranko

    2015-01-01

    A two-channel impedance technique has been used to study the relaxation behavior of 2-ethyl-1-hexanol with polar and non-polar dopants at the few percent concentration level over a wide temperature and frequency range. The non-polar dopants shift both the Debye and the primary structural relaxation time in the same direction, to shorter times for 3-methylpentane and to longer times for squalane, consistent with the relative glass transition temperatures (Tg) of the components. By contrast, polar dopants such as water or methanol modify the α-process towards slower dynamics and increased amplitude, while the Debye process is accelerated and with a decreased amplitude. This effect of adding water to alcohol is explained by water promoting more compact structures with reduced Kirkwood correlation factors. This picture is consistent with a shift in the neutron scattering pre-peak to lower scattering vectors and with simulation work on alcohol-water systems.

  12. Study of caffeine as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)

    NASA Astrophysics Data System (ADS)

    Solehudin, Agus; Berman, Ega Taqwali; Nurdin, Isdiriayani

    2015-09-01

    The corrosion behaviour of steel surface in the absence and presence of caffeine in 3.5% NaCl solution containing dissolved H2S gas is studied using electrochemical impedance spectroscopy (EIS). The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H2S at different caffeine concentrations showed that corrosion rate of carbon steel decreases with increasing of caffeine concentrations from 0 to 0,1 mmol/l. Whereas, the corrosion rate increase with increasing of caffeine concentrations from 1 to 10 mmol/l. It is clear that no inhibition efficiency increases with increasing inhibitor concentration. The optimum value of inhibition efficiency was 90% at a caffeine concentration of 0.1 mmol/l. This suggests that caffeine's performance as a corrosion inhibitor is more effective at a concentration of 0.1 mmol/l.

  13. Dopant effects on 2-ethyl-1-hexanol: A dual-channel impedance spectroscopy and neutron scattering study

    SciTech Connect

    Singh, Lokendra P.; Richert, Ranko; Raihane, Ahmed; Alba-Simionesco, Christiane

    2015-01-07

    A two-channel impedance technique has been used to study the relaxation behavior of 2-ethyl-1-hexanol with polar and non-polar dopants at the few percent concentration level over a wide temperature and frequency range. The non-polar dopants shift both the Debye and the primary structural relaxation time in the same direction, to shorter times for 3-methylpentane and to longer times for squalane, consistent with the relative glass transition temperatures (T{sub g}) of the components. By contrast, polar dopants such as water or methanol modify the α-process towards slower dynamics and increased amplitude, while the Debye process is accelerated and with a decreased amplitude. This effect of adding water to alcohol is explained by water promoting more compact structures with reduced Kirkwood correlation factors. This picture is consistent with a shift in the neutron scattering pre-peak to lower scattering vectors and with simulation work on alcohol-water systems.

  14. Plasmonic-Based Electrochemical Impedance Spectroscopy: Application to Molecular Binding

    PubMed Central

    Lu, Jin; Wang, Wei; Wang, Shaopeng; Shan, Xiaonan; Li, Jinghong; Tao, Nongjian

    2012-01-01

    Plasmonic-based electrochemical impedance spectroscopy (P-EIS) is developed to investigate molecular binding on surfaces. Its basic principle relies on the sensitive dependence of surface plasmon resonance (SPR) signal on surface charge density, which is modulated by applying an AC potential to a SPR chip surface. The AC component of the SPR response gives the electrochemical impedance, and the DC component provides the conventional SPR detection. The plasmonic-based impedance measured over a range of frequency is in quantitative agreement with the conventional electrochemical impedance. Compared to the conventional SPR detection, P-EIS is sensitive to molecular binding taking place on the chip surface, and less sensitive to bulk refractive index changes or non-specific binding. Moreover, this new approach allows for simultaneous SPR and surface impedance analysis of molecular binding processes. PMID:22122514

  15. Electric properties of carbon nano-onion/polyaniline composites: a combined electric modulus and ac conductivity study

    NASA Astrophysics Data System (ADS)

    Papathanassiou, Anthony N.; Mykhailiv, Olena; Echegoyen, Luis; Sakellis, Ilias; Plonska-Brzezinska, Marta E.

    2016-07-01

    The complex electric modulus and the ac conductivity of carbon nano-onion/polyaniline composites were studied from 1 mHz to 1 MHz at isothermal conditions ranging from 15 K to room temperature. The temperature dependence of the electric modulus and the dc conductivity analyses indicate a couple of hopping mechanisms. The distinction between thermally activated processes and the determination of cross-over temperature were achieved by exploring the temperature dependence of the fractional exponent of the dispersive ac conductivity and the bifurcation of the scaled ac conductivity isotherms. The results are analyzed by combining the granular metal model (inter-grain charge tunneling of extended electron states located within mesoscopic highly conducting polyaniline grains) and a 3D Mott variable range hopping model (phonon assisted tunneling within the carbon nano-onions and clusters).

  16. Extra-cellular volume estimation by electrical impedance--phase measurement or curve fitting: a comparative study.

    PubMed

    Goovaerts, H G; Faes, T J; de Valk-de Roo, G W; ten Bolscher, M; Netelenbosch, J C; van der Vijgh, W J; Heethaar, R M

    1998-11-01

    In order to determine body fluid shifts between the intra- and extra-cellular spaces, multifrequency impedance measurement is performed. According to the Cole-Cole extrapolation, lumped values of intra- and extra-cellular conduction can be estimated which are commonly expressed in resistances Ri and Re respectively. For this purpose the magnitude and phase of the impedance under study are determined at a number of frequencies in the range between 5 kHz and 1 MHz. An approach to determine intra- and extra-cellular conduction on the basis of Bode analysis is presented in this article. On this basis, estimation of the ratio between intra- and extra-cellular conduction could be performed by phase measurement only, midrange in the bandwidth of interest. An important feature is that the relation between intra- and extra-cellular conduction can be continuously monitored by phase measurement and no curve fitting whatsoever is required. Based on a two frequency measurement determining Re at 4 kHz and phi(max) at 64 kHz it proved possible to estimate extra-cellular volume (ECV) more accurately compared with the estimation based on extrapolation according to the Cole-Cole model in 26 patients. Reference values of ECV were determined by sodium bromide. The results show a correlation of 0.90 with the reference method. The average error of ECV estimation was -3.6% (SD 8.4), whereas the Cole-Cole extrapolation showed an error of 13.2% (SD 9.5). An important feature of the proposed approach is that the relation between intra- and extra-cellular conduction can be continuously monitored by phase measurement and no curve fitting whatsoever is required.

  17. Local impedance imaging of boron-doped polycrystalline diamond thin films

    SciTech Connect

    Zieliński, A.; Ryl, J.; Burczyk, L.; Darowicki, K.

    2014-09-29

    Local impedance imaging (LII) was used to visualise surficial deviations of AC impedances in polycrystalline boron-doped diamond (BDD). The BDD thin film electrodes were deposited onto the highly doped silicon substrates via microwave plasma-enhanced CVD. The studied boron dopant concentrations, controlled by the [B]/[C] ratio in plasma, ranged from 1 × 10{sup 16} to 2 × 10{sup 21} atoms cm{sup −3}. The BDD films displayed microcrystalline structure, while the average size of crystallites decreased from 1 to 0.7 μm with increasing [B]/[C] ratios. The application of LII enabled a direct and high-resolution investigation of local distribution of impedance characteristics within the individual grains of BDD. Such an approach resulted in greater understanding of the microstructural control of properties at the grain level. We propose that the obtained surficial variation of impedance is correlated to the areas of high conductance which have been observed at the grain boundaries by using LII. We also postulate that the origin of high conductivity is due to either preferential boron accumulation, the presence of defects, or sp{sup 2} regions in the intragrain regions. The impedance modulus recorded by LII was in full agreement with the bulk impedance measurements. Both variables showed a decreasing trend with increasing [B]/[C] ratios, which is consistent with higher boron incorporation into BDD film.

  18. Design and validation of a multi-electrode bioimpedance system for enhancing spatial resolution of cellular impedance studies.

    PubMed

    Alexander, Frank A; Celestin, Michael; Price, Dorielle T; Nanjundan, Meera; Bhansali, Shekhar

    2013-07-01

    This paper reports the design and evaluation of a multi-electrode design that improves upon the statistical significance and spatial resolution of cellular impedance data measured using commercial electric cell-substrate impedance sensing (ECIS) systems. By evaluating cellular impedance using eight independent sensing electrodes, position-dependent impedance measurements can be recorded across the device and compare commonly used equivalent circuit and mathematical models for extraction of cell parameters. Data from the 8-electrode device was compared to data taken from commercial electric cell-substrate impedance sensing (ECIS) system by deriving a relationship between equivalent circuit and mathematically modelled parameters. The impedance systems were evaluated and compared by investigating the effects of arsenic trioxide (As2O3), a well-established chemotherapeutic agent, on ovarian cancer cells. Impedance spectroscopy, a non-destructive, label-free technique, was used to continuously measure the frequency-dependent cellular properties, without adversely affecting the cells. The importance of multiple measurements within a cell culture was demonstrated; and the data illustrated that the non-uniform response of cells within a culture required redundant measurements in order to obtain statistically significant data, especially for drug discovery applications. Also, a correlation between equivalent circuit modelling and mathematically modelled parameters was derived, allowing data to be compared across different modelling techniques.

  19. Structural and AC loss study for pure and doped MgB{sub 2} superconductor

    SciTech Connect

    Hansdah, J. S.; Sarun, P. M.

    2015-06-24

    Superconducting polycrystalline bulk MgB{sub 2} samples doped with n-C, n-Y{sub 2}O{sub 3} and n-Ho{sub 2}O{sub 3} were prepared by powder-in-sealed (PIST) method. XRD measurement shows the influence of dopants on phase and lattice parameters of samples. The ac susceptibility measurement reveals ac loss and activation energy of the samples. Nano-C doped sample shows less ac loss in all frequency (208 Hz – 999 Hz) among the doped samples; whereas n-Ho{sub 2}O{sub 3} doped sample shows highest ac loss. The activation energy is high for rare earth (n-Y{sub 2}O{sub 3} and n-Ho{sub 2}O{sub 3}) doped samples as compare to n-C doped samples which reveals the enhancement in flux-pinning properties of these materials.

  20. Structural and AC loss study for pure and doped MgB2 superconductor

    NASA Astrophysics Data System (ADS)

    Hansdah, J. S.; Sarun, P. M.

    2015-06-01

    Superconducting polycrystalline bulk MgB2 samples doped with n-C, n-Y2O3 and n-Ho2O3 were prepared by powder-in-sealed (PIST) method. XRD measurement shows the influence of dopants on phase and lattice parameters of samples. The ac susceptibility measurement reveals ac loss and activation energy of the samples. Nano-C doped sample shows less ac loss in all frequency (208 Hz - 999 Hz) among the doped samples; whereas n-Ho2O3 doped sample shows highest ac loss. The activation energy is high for rare earth (n-Y2O3 and n-Ho2O3) doped samples as compare to n-C doped samples which reveals the enhancement in flux-pinning properties of these materials.

  1. Impedance studies of Ni/Cd and Ni/H2 cells using the cell case as a reference electrode

    NASA Technical Reports Server (NTRS)

    Reid, Margaret A.

    1989-01-01

    Impedance measurements have been made on several Ni/Cd and Ni/H2 flightweight cells using the case as a reference electrode. For these measurements the voltage of the case with respect to the anode or cathode is unimportant provided that it remains stable during the measurement of the impedance. In the cells measured so far, the voltages of the cell cases with respect to the individual electrodes differ from cell to cell even at the same overall cell voltage, but they remains stable with time. The measurements can thus be used to separate the cell impedance into the contributions of each electrode, allowing improved diagnosis of cell problems.

  2. Impedance studies of nickel/cadmium and nickel/hydrogen cells using the cell case as a reference electrode

    NASA Technical Reports Server (NTRS)

    Reid, Margaret A.

    1990-01-01

    Impedance measurements have been made on several Ni/Cd and Ni/H2 flight-weight cells using the case as a reference electrode. For these measurements, the voltage of the case with respect to the anode or cathode is unimportant provided that it remains stable during the measurement of the impedance. In the cells measured so far, the voltage of the cell cases with respect to the individual electrodes differ from cell to cell, even at the same overall cell voltage, but they remain stable with time. The measurements can thus be used to separate the cell impedance into the contributions of each electrode, allowing improved diagnosis of cell problems.

  3. Dielectric, ferroelectrics properties and impedance spectroscopy analysis of the [(Na0.535K0.480)0.966Li0.058](Nb0.90Ta0.10)O3-based lead-free ceramics

    NASA Astrophysics Data System (ADS)

    Saidi, M.; Chaouchi, A.; D'Astorg, S.; Rguiti, M.; Courtois, C.

    2015-04-01

    Polycrystalline of [(Na0.535K0.480)0.966Li0.058](Nb0.90Ta0.10)O3 samples were prepared using the high-temperature solid-state reaction technique. X-ray diffraction (XRD) analysis indicates the formation of a single-phase with orthorhombic structure. AC impedance plots were used as tool to analyze the electrical behavior of the sample as a function of frequency at different temperatures. The AC impedance studies revealed the presence of grain effect, from 425°C onwards. Complex impedance analysis indicated non-Debye type dielectric relaxation. The Nyquist plot showed the negative temperature coefficient of resistance (NTCR) characteristic of NKLNT. The AC conductivity results were used to correlate with the barrier hopping (CBH) model to evaluate the binding energy (Wm), the minimum hopping distance (Rmin), the density of states at Fermi level (N(Ef)), and the activation energy of the compound.

  4. A 52-week safety study in cynomolgus macaques for genetically modified rice expressing Cry1Ab/1Ac protein.

    PubMed

    Mao, Jie; Sun, Xing; Cheng, Jian-Hua; Shi, Yong-Jie; Wang, Xin-Zheng; Qin, Jun-Jie; Sang, Zhi-Hong; He, Kun; Xia, Qing

    2016-09-01

    A 52-week feeding study in cynomolgus macaques was carried out to evaluate the safety of Bt rice Huahui 1 (HH1), a transgenic rice line expressing Cry1Ab/1Ac protein. Monkeys were fed a diet with 20% or 60% HH1 rice, 20% or 60% parental rice (Minghui 63, MH63), normal diet, normal diet spiked with purified recombinant Cry1Ab/1Ac fusion protein or bovine serum albumin (BSA) respectively. During the feeding trail, clinical observations were conducted daily, and multiple parameters, including body weight, body temperature, electrocardiogram, hematology, blood biochemistry, serum metabolome and gut microbiome were examined at regular intervals. Upon sacrifice, the organs were weighted, and the macroscopic, microscopic and electron microscopic examinations were performed. The results show no adverse or toxic effects of Bt rice HH1 or Cry1Ab/1Ac fusion protein on monkeys. Therefore, the present 52-week primate feeding study suggests that the transgenic rice containing Cry 1Ab/1Ac is equivalent to its parental rice line MH63. PMID:27338709

  5. A 52-week safety study in cynomolgus macaques for genetically modified rice expressing Cry1Ab/1Ac protein.

    PubMed

    Mao, Jie; Sun, Xing; Cheng, Jian-Hua; Shi, Yong-Jie; Wang, Xin-Zheng; Qin, Jun-Jie; Sang, Zhi-Hong; He, Kun; Xia, Qing

    2016-09-01

    A 52-week feeding study in cynomolgus macaques was carried out to evaluate the safety of Bt rice Huahui 1 (HH1), a transgenic rice line expressing Cry1Ab/1Ac protein. Monkeys were fed a diet with 20% or 60% HH1 rice, 20% or 60% parental rice (Minghui 63, MH63), normal diet, normal diet spiked with purified recombinant Cry1Ab/1Ac fusion protein or bovine serum albumin (BSA) respectively. During the feeding trail, clinical observations were conducted daily, and multiple parameters, including body weight, body temperature, electrocardiogram, hematology, blood biochemistry, serum metabolome and gut microbiome were examined at regular intervals. Upon sacrifice, the organs were weighted, and the macroscopic, microscopic and electron microscopic examinations were performed. The results show no adverse or toxic effects of Bt rice HH1 or Cry1Ab/1Ac fusion protein on monkeys. Therefore, the present 52-week primate feeding study suggests that the transgenic rice containing Cry 1Ab/1Ac is equivalent to its parental rice line MH63.

  6. Biocompatible Silver-containing a-C:H and a-C coatings: AComparative Study

    SciTech Connect

    Endrino, Jose Luis; Allen, Matthew; Escobar Galindo, Ramon; Zhang, Hanshen; Anders, Andre; Albella, Jose Maria

    2007-04-01

    Hydrogenated diamond-like-carbon (a-C:H) and hydrogen-free amorphous carbon (a-C) coatings are known to be biocompatible and have good chemical inertness. For this reason, both of these materials are strong candidates to be used as a matrix that embeds metallic elements with antimicrobial effect. In this comparative study, we have incorporated silver into diamond-like carbon (DLC) coatings by plasma based ion implantation and deposition (PBII&D) using methane (CH4) plasma and simultaneously depositing Ag from a pulsed cathodic arc source. In addition, we have grown amorphous carbon - silver composite coatings using a dual-cathode pulsed filtered cathodic-arc (FCA) source. The silver atomic content of the deposited samples was analyzed using glow discharge optical spectroscopy (GDOES). In both cases, the arc pulse frequency of the silver cathode was adjusted in order to obtain samples with approximately 5 at.% of Ag. Surface hardness of the deposited films was analyzed using the nanoindentation technique. Cell viability for both a-C:H/Ag and a-C:/Ag samples deposited on 24-well tissue culture plates has been evaluated.

  7. Human aquaporin 4 gating dynamics in dc and ac electric fields: A molecular dynamics study

    NASA Astrophysics Data System (ADS)

    Garate, J.-A.; English, Niall J.; MacElroy, J. M. D.

    2011-02-01

    Water self-diffusion within human aquaporin 4 has been studied using molecular dynamics (MD) simulations in the absence and presence of external ac and dc electric fields. The computed diffusive (pd) and osmotic (pf) permeabilities under zero-field conditions are (0.718 ± 0.24) × 10-14 cm3 s-1 and (2.94 ± 0.47) × 10-14 cm3 s-1, respectively; our pf agrees with the experimental value of (1.50 ± 0.6) × 10-14 cm3 s-1. A gating mechanism has been proposed in which side-chain dynamics of residue H201, located in the selectivity filter, play an essential role. In addition, for nonequilibrium MD in external fields, it was found that water dipole orientation within the constriction region of the channel is affected by electric fields (e-fields) and that this governs the permeability. It was also found that the rate of side-chain flipping motion of residue H201 is increased in the presence of e-fields, which influences water conductivity further.

  8. AC Impedance Behavior of LaNi3.55Mn0.4Al0.3Co0.6Fe0.15 Hydrogen-Storage Alloy: Effect of Surface Area

    NASA Astrophysics Data System (ADS)

    Tliha, M.; Khaldi, C.; Lamloumi, J.

    2016-04-01

    The decrease of Cobalt content in alloy is very beneficial to reduce the production cost of the alloy, whereas the effect of Co on cycle life of the AB5-type hydrogen-storage alloys is extremely important. Therefore, it is interesting to investigate low-Co and/or Co-free AB5-type alloys in which Co was substituted by other elements. Iron is a key element in the development of low-Co AB5-type alloys. The aim of this work is to systematically investigate the effect of the real surface area on the all kinetic properties of a low-Co LaNi3.55Mn0.4Al0.3Co0.6Fe0.15 alloy under cycling using electrochemical impedance spectroscopy (EIS) technique. All kinetic properties of the electrode, such as exchange density, limiting current density, high-rate charge/discharge ability, cycle life time, electrocatalytic activity, and diffusion rate are related to the real surface area. During the EIS analysis, interestingly, we found that with increasing number of charge/discharge cycles, the metal hydride alloy powders undergo micro-cracking into smaller particles, and thus the real surface area of the alloy increases, which then influences the kinetic properties of the electrode reactions.

  9. AC Dielectric Properties and Positron Annihilation Study on Co and Ti Substitution Effect on Ca-Sr M-Hexaferrites

    NASA Astrophysics Data System (ADS)

    Mahmoud, K. R.; Eraky, M. R.

    2016-06-01

    The dependence of AC conductivity σ AC, dielectric constant έ, and dielectric loss tangent tan δ on frequency and composition have been investigated at room temperature for polycrystalline Ca0.5Sr0.5Co x Ti x Fe12 - 2 x O19 (where 0.0 ≤ x ≤ 0.8) hexaferrites. It was found that the parameters σ AC, ɛ ', and tan δ have maximum values at x = 0.4 of the Co and Ti substitution. The behavior of σ AC, ɛ ', and tan δ with frequency and composition was explained on the basis of the hopping conduction mechanism and the Koops model. Positron annihilation lifetime spectroscopy (PALS) was used to investigate the defects and changes in electron density for hexaferrite samples. The PAL parameters ( τ 1, I 1, τ 2, I 2, and mean lifetime) show that altering the doping percentage of the Co and Ti ions affects the size and concentration of defects. The results reveal that there are some large voids in the studied samples. The obtained results indicate the high sensitivity of the PALS technique to the enhanced structure changes with changing composition of the investigated samples and correlate the results with the measured electrical parameters.

  10. Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)

    NASA Astrophysics Data System (ADS)

    Solehudin, Agus; Nurdin, Isdiriayani

    2014-03-01

    Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70°C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H2S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

  11. Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)

    SciTech Connect

    Solehudin, Agus; Nurdin, Isdiriayani

    2014-03-24

    Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70°C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H{sub 2}S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

  12. Corrosion Behavior of Surface-Treated Implant Ti-6Al-4V by Electrochemical Polarization and Impedance Studies

    NASA Astrophysics Data System (ADS)

    Paul, Subir; Yadav, Kasturi

    2011-04-01

    Implant materials for orthopedic and heart surgical services demand a better corrosion resistance material than the presently used titanium alloys, where protective oxide layer breaks down on a prolonged stay in aqueous physiological human body, giving rise to localized corrosion of pitting, crevice, and fretting corrosion. A few surface treatments on Ti alloy, in the form of anodization, passivation, and thermal oxidation, followed by soaking in Hank solution have been found to be very effective in bringing down the corrosion rate as well as producing high corrosion resistance surface film as reflected from electrochemical polarization, cyclic polarization, and Electrochemical Impedance Spectroscopy (EIS) studies. The XRD study revealed the presence of various types of oxides along with anatase and rutile on the surface, giving rise to high corrosion resistance film. While surface treatment of passivation and thermal oxidation could reduce the corrosion rate by 1/5th, anodization in 0.3 M phosphoric acid at 16 V versus stainless steel cathode drastically brought down the corrosion rate by less than ten times. The mechanism of corrosion behavior and formation of different surface films is better understood from the determination of EIS parameters derived from the best-fit equivalent circuit.

  13. Study of the DEF Feedback Control System in AC Operation of Superconducting Tokamak

    NASA Astrophysics Data System (ADS)

    Wang, Hua; Luo, Jiarong; Yuan, Qiping; Xu, Congdong

    2007-02-01

    AC operation with multiple full cycles has been successfully performed on the superconducting tokamak HT-7. In the experiment, it was discovered that the saturation of the transformer magnetic flux with DEF, a signal name, was one of key aspects that affected the AC operation. The conditions of DEF were examined through the DEF feedback control system. By controlling the working patterns of the subsystems, namely the poloidal field control system and density control system, it was guaranteed that DEF would remain in the non-saturated status.

  14. Development of an analytical tool to study power quality of AC power systems for large spacecraft

    NASA Technical Reports Server (NTRS)

    Kraft, L. Alan; Kankam, M. David

    1991-01-01

    A harmonic power flow program applicable to space power systems with sources of harmonic distortion is described. The algorithm is a modification of the Electric Power Research Institute's HARMFLO program which assumes a three phase, balanced, AC system with loads of harmonic distortion. The modified power flow program can be used with single phase, AC systems. Early results indicate that the required modifications and the models developed are quite adequate for the analysis of a 20 kHz testbed built by General Dynamics Corporation. This is demonstrated by the acceptable correlation of present results with published data. Although the results are not exact, the discrepancies are relatively small.

  15. Development of an analytical tool to study power quality of ac power systems for large spacecraft

    NASA Technical Reports Server (NTRS)

    Kraft, L. A.; Kankam, M. D.

    1991-01-01

    A harmonic power flow program applicable to space power systems with sources of harmonic distortion is described. The algorithm is a modification of Electric Power Research Institute's HARMFLO program which assumes a three-phase, balanced, ac system with loads of harmonic distortion. The modified power flow program can be used with single phase, ac systems. Early results indicate that the required modifications and the models developed are quite adequate for the analysis of a 20-kHz testbed built by General Dynamics Corporation. This is demonstrated by the acceptable correlation of the present results with published data. Although the results are not exact, the discrepancies are relatively small.

  16. Ethical Crossroads: A Study of Factors Impeding Professional Growth in Initial Teacher Education in Zimbabwe

    ERIC Educational Resources Information Center

    Mswazi, J. L.; Shumba, A.

    2008-01-01

    Research on current discourses on educational change in general and teacher education in particular have identified reasons why some teacher education courses fail to connect with trainees. This study sought to investigate factors that underlie pre-service teachers' resistance to an innovative religious and moral education course. A descriptive…

  17. Gastro-oesophageal reflux is common in oligosymptomatic patients with dental erosion: A pH-impedance and endoscopic study

    PubMed Central

    Materna, Andrea; Martig, Lukas; Lussi, Adrian

    2015-01-01

    Background Dental erosion is a complication of gastro-oesophageal reflux disease (GORD) according to the Montreal consensus statement. However, GORD has not been comprehensively characterized in patients with dental erosions and pH-impedance measures have not been reported. Objectives Characterize GORD in patients with dental erosions using 24-h multichannel intraluminal pH-impedance measurements (pH-MII) and endoscopy. Methods This single-centre study investigated reflux in successive patients presenting to dentists with dental erosion using pH-MII and endoscopy. Results Of the 374 patients, 298 (80%) reported GORD symptoms <2 per week, 72 (19%) had oesophagitis and 59 (16%) had a hiatal hernia. In the 349 with pH-MII the mean percentage time with a pH <4 (95% CI) was 11.0 (9.3–12.7), and 34.4% (31.9–36.9) for a pH <5.5, a critical threshold for dental tissue. The mean numbers of total, acidic and weakly acidic reflux episodes were 71 (63–79), 43 (38–49) and 31 (26–35), respectively. Of the reflux episodes, 19% (17–21) reached the proximal oesophagus. In 241 (69%) patients reflux was abnormal using published normal values for acid exposure time and reflux episodes. No significant associations between the severity of dental erosions and any reflux variables were found. The presence of GORD symptoms and of oesophagitis or a hiatal hernia was associated with greater reflux, but not with increased dental erosion scores. Conclusions Significant oligosymptomatic gastro-oesophageal reflux occurs in the majority of patients with dental erosion. The degree of dental erosion did not correlate with any of the accepted quantitative reflux indicators. Definition of clinically relevant reflux parameters by pH-MII for dental erosion and of treatment guidelines are outstanding. Gastroenterologists and dentists need to be aware of the widely prevalent association between dental erosion and atypical GORD. PMID:25922678

  18. Low temperature dielectric and impedance studies on magnetoelectric Pb(Fe0.5Nb0.5)O3 ceramic

    NASA Astrophysics Data System (ADS)

    Matteppanavar, Shidaling; Shivaraja, I.; Rayaprol, Sudhindra; Angadi, Basavaraj

    2016-05-01

    The structural, microstructural, low temperature dielectric and impedance properties of Pb(Fe0.5Nb0.5)O3 (PFN) ceramic prepared by single step solid-state reaction method have been investigated. Processing parameters such as calcination, sintering temperature and sintering durations were optimized to get better dielectric properties. It was found that the above ceramics sintered at 1050 °C for 4 hr exhibited single phase, maximum density and uniform microstructure. X-ray diffraction (XRD) and neutron diffraction (ND) reveals that the system exhibit single phase without any kind of secondary phases at room temperature (RT) with monoclinic crystal structure (Cm). Surface morphology of the compounds was studied by Scanning electron microscope (SEM). Impedance spectroscopy is used to study the electrical behaviour of PFN in the frequency range from 100Hz to 1MHz and in the temperature range from 120 to 293 K. The frequency-dependent electrical data are analyzed by impedance formalisms. The complex impedance shows the relaxation (conduction) mechanism in the sample.

  19. Electrochemical Impedance Spectroscopy study in micro-grain structured amorphous silicon anodes for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Paloukis, Fotis; Elmasides, Costas; Farmakis, Filippos; Selinis, Petros; Neophytides, Stylianos G.; Georgoulas, Nikolaos

    2016-11-01

    In this paper, a study of the lithiation mechanism of micro-grain structured silicon anode is presented. Micro-grain amorphous silicon was deposited on special copper foil and it is shown that after several decades of galvanostatic cycles, it preserves its granular nature with minor degradation. In order to shed light on the lithiation mechanisms of the micro-grain silicon, Electrochemical Impedance Spectroscopy (EIS) was conducted on silicon half-cells at various State-of-Charge (SoC) and various discharging current values and the Solid-Electrolyte Interphase (SEI) RSEI and polarization resistance Rpol were determined. Results reveal that Rpol highly increases for cell voltages lower than 0.2 V and it strongly depends on the discharging C-rate. From X-ray Photoelectron Spectroscopy (XPS) measurements combined with surface sputtering, the existence of a LixSiyOz interlayer between SEI and silicon is confirmed, which is believed to play an important role to the lithium kinetics. Finally, combining our results, a lithiation mechanism of the micro-grain silicon anode is proposed.

  20. Detection of Non-Cavitated Occlusal Caries with Impedance Spectroscopy and Laser Fluorescence: an In Vitro Study

    PubMed Central

    Mortensen, Diana; Dannemand, Katrine; Twetman, Svante; Keller, Mette Kirstine

    2014-01-01

    Objective: To evaluate the performance of an impedance spectroscopy technology for detecting non-cavitated occlusal caries lesions in permanent teeth in vitro. The method was compared with a commonly used laser fluorescence device and validated against histology. Material and Methodology: A non-cavitated sample of 100 extracted posterior teeth was randomly selected and assessed for caries on enamel and dentin level with aid of CarioScan PRO (ACIS) and DIAGNOdent pen (LF pen) by three examiners. After the measurements, the extension of the lesion was histologically determined as gold standard. Sensitivity, specificity, accuracy and receiver-operating curves were calculated. Intra- and inter-examiner reproducibility was expressed by intra class correlation coefficients. Results: The histological caries prevalence was 99% and 41% exhibited dentin caries. The ACIS technique displayed high specificities but almost negligible sensitivities at readings >50. A similar pattern was noted for the LF pen at readings >30. The intra- and inter-examiner reproducibility varied between 0.47 and 0.98 and the values were generally lower for the ACIS technique than for the LF pen. The inter-examiner agreement reached excellent levels with both methods. Conclusions: In vitro,the ACIS technique showed a low ability to disclose occlusal caries lesions in the enamel and/or dentin of non-cavitated permanent molars. However, further in vivo studies of permanent occlusal surfaces are needed to mirror the clinical situation. PMID:24799965

  1. New impedance and electrochemical image techniques for biological applications

    NASA Astrophysics Data System (ADS)

    Tao, N. J.

    2010-03-01

    A method to image local surface impedance and electrochemical current optically is developed for biological applications. The principle of the impedance imaging is based on sensitive dependence of surface plasmon resonance (SPR) on local surface charge density. The technique can image local surface impedance and charge while providing simultaneously a conventional surface plasmon resonance (SPR) image. By applying a potential modulation to a sensor surface, it is possible to obtain an image of the DC component, and the amplitude and phase images of the AC component. The DC image provides local molecular binding, as found in the conventional SPR imaging technique. The AC images are directly related to the local impedance of the surface. This imaging capability may be used as a new detection platform for DNA and protein microarrays, a new method for analyzing local molecular binding and interfacial processes and a new tool for imaging cells and tissues.

  2. Electrochemical Impedance Studies on Single and Multi-Walled Carbon Nanotubes--Polymer Nanocomposites for Biosensors Development.

    PubMed

    Tertiş, Mihaela; Florea, Anca; Feier, Bogdan; Marian, Iuliu Ovidiu; Silaghi-Dumitrescu, Luminţa; Cristea, Alexandru; Săndulescu, Robert; Cristea, Cecilia

    2015-05-01

    Advances in nanoscience have allowed scientists to incorporate new nanomaterials in biosensing platforms. Carbon nanotubes are nanomaterials that facilitate the charge transfer between the bioelement and the transducer. Electrochemical impedance spectroscopy is a useful technique for the modified surface characterization. In the present approach electrochemical impedance spectroscopy was used to characterize the electrodes modified with different types of carbon nanotubes (single and multi-wall) according to their morphology and electrochemical behavior. By using Nyquist and Bode diagrams it was possible to assign the appropriate circuit considering all possible contributors. The charge transfer resistances as well as the time constants were calculated for all five types of investigated carbon nanotubes.

  3. Increased Ac excision (iae): Arabidopsis thaliana mutations affecting Ac transposition.

    PubMed

    Jarvis, P; Belzile, F; Page, T; Dean, C

    1997-05-01

    The maize transposable element Ac is highly active in the heterologous hosts tobacco and tomato, but shows very much reduced levels of activity in Arabidopsis. A mutagenesis experiment was undertaken with the aim of identifying Arabidopsis host factors responsible for the observed low levels of Ac activity. Seed from a line carrying a single copy of the Ac element inserted into the streptomycin phosphotransferase (SPT) reporter fusion, and which displayed typically low levels of Ac activity, were mutagenized using gamma rays. Nineteen mutants displaying high levels of somatic Ac activity, as judged by their highly variegated phenotypes, were isolated after screening the M2 generation on streptomycin-containing medium. The mutations fall into two complementation groups, iae1 and iae2, are unlinked to the SPT::Ac locus and segregate in a Mendelian fashion. The iae1 mutation is recessive and the iae2 mutation is semi-dominant. The iae1 and iae2 mutants show 550- and 70-fold increases, respectively, in the average number of Ac excision sectors per cotyledon. The IAE1 locus maps to chromosome 2, whereas the SPT::Ac reporter maps to chromosome 3. A molecular study of Ac activity in the iae1 mutant confirmed the very high levels of Ac excision predicted using the phenotypic assay, but revealed only low levels of Ac re-insertion. Analyses of germinal transposition in the iae1 mutant demonstrated an average germinal excision frequency of 3% and a frequency of independent Ac re-insertions following germinal excision of 22%. The iae mutants represents a possible means of improving the efficiency of Ac/Ds transposon tagging systems in Arabidopsis, and will enable the dissection of host involvement in Ac transposition and the mechanisms employed for controlling transposable element activity.

  4. Wakefields and coupling impedances

    NASA Astrophysics Data System (ADS)

    Kurennoy, Sergey

    1995-02-01

    After a short introduction of the wake potentials and coupling impedances, a few new results in impedance calculations are discussed. The first example is a new analytical method for calculating impedances of axisymmetric structures in the low frequency range, below the cutoff frequency of the vacuum chamber. The second example demonstrates that even very small discontinuities on a smooth waveguide can result in appearance of trapped modes, with frequencies slightly below the waveguide cutoff frequency. The high-frequency (above the cutoff) behavior of the coupling impedance of many small discontinuities is discussed in the third example.

  5. Impedance spectroscopy of manganite films prepared by metalorganic chemical vapor deposition.

    PubMed

    Nakamura, Toshihiro; Homma, Kohei; Tachibana, Kunihide

    2011-09-01

    Polycrystalline Pr(1-x)CaxMnO3 (PCMO) films were prepared by liquid source metalorganic chemical vapor deposition using in situ infrared spectroscopic monitoring. The electric properties of the PCMO-based devices with Ni and Al electrodes (Ni-PCMO-Ni and Al-PCMO-Al devices) were studied by dc current-voltage (I-V) measurements and ac impedance spectroscopy. The current varied linearly with the applied voltage in Ni-PCMO-Ni devices, while nonlinear behavior was observed in I-V curves for Al-PCMO-Al devices. Impedance spectra were also different between Ni-PCMO-Ni and Al-PCMO-Al devices. The Cole-Cole plots for the Ni-PCMO-Ni devices showed only a single semicircular arc, which was assigned to the PCMO bulk impedance. Impedance spectra for the Al-PCMO-Al devices had two distinct components, which could be attributed to the PCMO bulk and to the interface between the PCMO film and the Al electrode, respectively. The bias dependence of the impedance spectra suggested that the resistance switching in the Al-PCMO-Al devices was mainly due to the resistance change in the interface between the film and the electrode. The metal electrode plays an important role in the resistance switching in the PCMO-based devices. The choice of the optimum metal electrodes is essential to the ReRAM application of the manganite-based devices.

  6. Study of the Dependency on Magnetic Field and Bias Voltage of an AC-Biased TES Microcalorimeter

    NASA Technical Reports Server (NTRS)

    Gottardi, L.; Bruijn, M.; denHartog, R.; Hoevers, H.; deKorte, P.; vanderKuur, J.; Linderman, M.; Adams, J.; Bailey, C.; Bandler, S.; Chervenak, J.; Eckart, M.; Finkbeiner, F.; Kelley, R.; Kilbourne, C.; Porter, F.; Sadlier, J.; Smith, S.

    2012-01-01

    At SRON we are studying the performance of a Goddard Space Flight Center single pixel TES microcalorimeter operated in an AC bias configuration. For x-ray photons at 6 keV the pixel shows an x-ray energy resolution Delta E(sub FWHM) = 3.7 eV, which is about a factor 2 worse than the energy resolution observed in an identical DC-biased pixel. In order to better understand the reasons for this discrepancy we characterized the detector as a function of temperature, bias working point and applied perpendicular magnetic field. A strong periodic dependency of the detector noise on the TES AC bias voltage is measured. We discuss the results in the framework of the recently observed weak-link behaviour of a TES microcalorimeter.

  7. Enhanced capacitance of composite TiO2 nanotube/boron-doped diamond electrodes studied by impedance spectroscopy.

    PubMed

    Siuzdak, K; Bogdanowicz, R; Sawczak, M; Sobaszek, M

    2015-01-14

    We report on novel composite nanostructures based on boron-doped diamond thin films grown on top of TiO2 nanotubes. The nanostructures made of BDD-modified titania nanotubes showed an increase in activity and performance when used as electrodes in electrochemical environments. The BDD thin films (∼200-500 nm) were deposited using microwave plasma assisted chemical vapor deposition (MW PA CVD) onto anodically fabricated TiO2 nanotube arrays. The influence of boron-doping level, methane admixture and growth time on the performance of the Ti/TiO2/BDD electrode was studied in detail. Scanning electron microscopy (SEM) was applied to investigate the surface morphology and grain size distribution. Moreover, the chemical composition of TiO2/BDD electrodes was investigated by means of micro-Raman spectroscopy. The composite electrodes TiO2/BDD are characterized by a significantly higher capacitive current compared to BDD films deposited directly onto a Ti substrate. The novel composite electrode of TiO2 nanotube arrays overgrown by boron-doped diamond (BDD) immersed in 0.1 M NaNO3 can deliver a specific capacitance of 2.10, 4.79, and 7.46 mF cm(-2) at a scan rate of 10 mV s(-1) for a [B]/[C] ratio of 2k, 5k and 10k, respectively. The substantial improvement of electrochemical performance and the excellent rate capability could be attributed to the synergistic effect of TiO2 treatment in CH4 : H2 plasma and the high electrical conductivity of BDD layers. The analysis of electrochemical impedance spectra using an electric equivalent circuit allowed us to determine the surface area on the basis of the value of constant phase element.

  8. Enhanced capacitance of composite TiO2 nanotube/boron-doped diamond electrodes studied by impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Siuzdak, K.; Bogdanowicz, R.; Sawczak, M.; Sobaszek, M.

    2014-12-01

    We report on novel composite nanostructures based on boron-doped diamond thin films grown on top of TiO2 nanotubes. The nanostructures made of BDD-modified titania nanotubes showed an increase in activity and performance when used as electrodes in electrochemical environments. The BDD thin films (~200-500 nm) were deposited using microwave plasma assisted chemical vapor deposition (MW PA CVD) onto anodically fabricated TiO2 nanotube arrays. The influence of boron-doping level, methane admixture and growth time on the performance of the Ti/TiO2/BDD electrode was studied in detail. Scanning electron microscopy (SEM) was applied to investigate the surface morphology and grain size distribution. Moreover, the chemical composition of TiO2/BDD electrodes was investigated by means of micro-Raman spectroscopy. The composite electrodes TiO2/BDD are characterized by a significantly higher capacitive current compared to BDD films deposited directly onto a Ti substrate. The novel composite electrode of TiO2 nanotube arrays overgrown by boron-doped diamond (BDD) immersed in 0.1 M NaNO3 can deliver a specific capacitance of 2.10, 4.79, and 7.46 mF cm-2 at a scan rate of 10 mV s-1 for a [B]/[C] ratio of 2k, 5k and 10k, respectively. The substantial improvement of electrochemical performance and the excellent rate capability could be attributed to the synergistic effect of TiO2 treatment in CH4 : H2 plasma and the high electrical conductivity of BDD layers. The analysis of electrochemical impedance spectra using an electric equivalent circuit allowed us to determine the surface area on the basis of the value of constant phase element.

  9. Studies of the Use of Electrochemical Impedance Spectroscopy to Characterize and Assess the Performance of Lacquers Used to Protect Aluminum Sheet and Can Ends

    NASA Astrophysics Data System (ADS)

    Ali, Mohammad

    This study involved investigating the feasibility of using Electrochemical Impedance Spectroscopy to assess the performance of coatings used to protect aluminum in beverage containers, and developing an accelerated testing procedure. In the preliminary investigation, tests were performed to ensure that the EIS systems at hand are capable, functional and consistent. This was followed by EIS testing of kitchen-aluminum foil and high-impedance epoxy polymer as a baseline for chemically-active and chemically-inert systems. The ability of EIS to differentiate between intact and flawed coatings was tested by investigating deliberately damaged coatings. The effects of varying the pH and oxygen content on the performance of the coated aluminum samples were also tested. From this investigation, it has been concluded that EIS can be used to differentiate between intact and flawed coatings and detect corrosion before it is visually observable. Signatures of corrosion have been recorded and a preliminary testing procedure has been drawn.

  10. Electrical biopsy of irradiated intestinal tissue with a simple electrical impedance spectroscopy system for radiation enteropathy in rats--a pilot study.

    PubMed

    Huang, Yu-Jie; Huang, Eng-Yen; Lu, Yi-Yu; Chen, Cheng-Yu; Cheng, Kuo-Sheng

    2011-09-01

    Electrical impedance is one of the most often used parameters for characterizing material properties, especially in biomedical applications. Electrical impedance spectroscopy (EIS), used for revealing both resistive and capacitive characteristics, is good for use in tissue characterization. In this study, a portable and simple EIS system based on a commercially available chip was used to assess rat intestinal tissues following irradiation. The EIS results were fitted to a resistor and capacitor electrical circuit model to solve the electrical properties of the tissue. The variation in the tissue's electrical characteristics was compared to the morphological and histological findings. From the experimental results, it was clear that the electrical properties, based on receiver operation curve analysis, demonstrated good detection performance relative to the histological changes. The electrical parameters of the tissues could be used to distinguish the tissue's status for investigation, which introduced a concept of 'electrical biopsy', and this 'electrical biopsy' approach may be used to complement histological examinations.

  11. Effect of low-temperature conditions on passive layer growth in Li intercalation materials: In situ impedance study

    SciTech Connect

    Barsoukov, E.; Kim, J.H.; Kim, J.H.; Yoon, C.O.; Lee, H.

    1998-08-01

    Electrochemical impedance spectroscopy has been applied to investigate the formation of insulating layers at the surfaces of microscopic particles of mesocarbon microbeads (MCMB), graphite, and hard carbon during the first Li-intercalation into these materials at ambient temperature as well as at {minus}20 C. Investigations were carried out in a three-electrode sandwich cell, designed for impedance measurements in the frequency range 64 kHz to 5 mHz. The impedance spectra, obtained in the potential range 1.5 and 0.02 V during the first charge, were analyzed by complex nonlinear least square fits. A new model, taking into account the porous structure of the intercalation material, electrochemical processes at the interface, as well as spherical diffusion of Li ions toward the centers of the particles, has been used for this analysis. The first intercalation at {minus}20 C results in formation of an insulating layer, which is about 90 times thinner than in the room-temperature case, as concluded from an analysis of experimental results. The irreversible capacity loss, which is 1.3 times larger at {minus}20 C that at room temperature, is ascribed to the formation of a porous precipitate of electrolyte decomposition products on the particle surface. Additional Li intercalation at room temperature results in an irreversible capacity loss of 26% from the initial value, and formation of a composite layer, including low-temperature and room-temperature deposited components.

  12. Electrochemical impedance spectroscopy to study physiological changes affecting the red blood cell after invasion by malaria parasites.

    PubMed

    Ribaut, Clotilde; Reybier, Karine; Reynes, Olivier; Launay, Jérôme; Valentin, Alexis; Fabre, Paul Louis; Nepveu, Françoise

    2009-04-15

    The malaria parasite, Plasmodium falciparum, invades human erythrocytes and induces dramatic changes in the host cell. The idea of this work was to use RBC modified electrode to perform electrochemical impedance spectroscopy (EIS) with the aim of monitoring physiological changes affecting the erythrocyte after invasion by the malaria parasite. Impedance cell-based devices are potentially useful to give insight into cellular behavior and to detect morphological changes. The modelling of impedance plots (Nyquist diagram) in equivalent circuit taking into account the presence of the cellular layer, allowed us pointing out specific events associated with the development of the parasite such as (i) strong changes in the host cell cytoplasm illustrated by changes in the film capacity, (ii) perturbation of the ionic composition of the host cell illustrated by changes in the film resistance, (iii) releasing of reducer (lactic acid or heme) and an enhanced oxygen consumption characterized by changes in the charge transfer resistance and in the Warburg coefficient characteristic of the redox species diffusion. These results show that the RBC-based device may help to analyze strategic events in the malaria parasite development constituting a new tool in antimalarial research.

  13. Performance of Two Bioelectrical Impedance Analyses in the Diagnosis of Overweight and Obesity in Children and Adolescents: The FUPRECOL Study

    PubMed Central

    Ramírez-Vélez, Robinson; Correa-Bautista, Jorge Enrique; Martínez-Torres, Javier; González-Ruíz, Katherine; González-Jiménez, Emilio; Schmidt-RioValle, Jacqueline; Garcia-Hermoso, Antonio

    2016-01-01

    This study aimed to determine thresholds for percentage of body fat (BF%) corresponding to the cut-off values for overweight/obesity as recommended by the International Obesity Task Force (IOTF), using two bioelectrical impedance analyzers (BIA), and described the likelihood of increased cardiometabolic risk in our cohort defined by the IOTF and BF% status. Participants included 1165 children and adolescents (54.9% girls) from Bogotá (Colombia). Body mass index (BMI) was calculated from height and weight. BF% of each youth was assessed first using the Tanita BC-418® followed by a Tanita BF-689®. The sensitivity and specificity of both devices and their ability to correctly classify children as overweight/obesity (≥2 standard deviation), as defined by IOTF, was investigated using receiver operating characteristic (ROC) by sex and age groups (9–11, 12–14, and 13–17 years old); Area under curve (AUC) values were also reported. For girls, the optimal BF% threshold for classifying into overweight/obesity was found to be between 25.2 and 28.5 (AUC = 0.91–0.97) and 23.9 to 26.6 (AUC = 0.90–0.99) for Tanita BC-418® and Tanita BF-689®, respectively. For boys, the optimal threshold was between 16.5 and 21.1 (AUC = 0.93–0.96) and 15.8 to 20.6 (AUC = 0.92–0.94) by Tanita BC-418® and Tanita BF-689®, respectively. All AUC values for ROC curves were statistically significant and there were no differences between AUC values measured by both BIA devices. The BF% values associated with the IOTF-recommended BMI cut-off for overweight/obesity may require age- and sex-specific threshold values in Colombian children and adolescents aged 9–17 years and could be used as a surrogate method to identify individuals at risk of excess adiposity. PMID:27782039

  14. Esophageal Impedance Monitoring: Clinical Pearls and Pitfalls.

    PubMed

    Ravi, Karthik; Katzka, David A

    2016-09-01

    The development of intraluminal esophageal impedance monitoring has improved our ability to detect and measure gastroesophageal reflux without dependence on acid content. This ability to detect previously unrecognized weak or nonacid reflux episodes has had important clinical implications in the diagnosis and management of gastroesophageal reflux disease (GERD). In addition, with the ability to assess bolus transit within the esophageal lumen, impedance monitoring has enhanced the recognition and characterization of esophageal motility disorders in patients with nonobstructive dysphagia. The assessment of the intraluminal movement of gas and liquid has also been proven to be of diagnostic value in conditions such as rumination syndrome and excessive belching. Further, alternative applications of impedance monitoring, such as the measurement of mucosal impedance, have provided novel insights into assessing esophageal mucosal integrity changes as a consequence of inflammatory change. Future applications for esophageal impedance monitoring also hold promise in esophageal conditions other than GERD. However, despite all of the clinical benefits afforded by esophageal impedance monitoring, important clinical and technical shortcomings limit its diagnostic value and must be considered when interpreting study results. Overinterpretation of studies or application of impedance monitoring in patients can have deleterious clinical implications. This review will highlight the clinical benefits and limitations of esophageal impedance monitoring and provide clinical pearls and pitfalls associated with this technology.

  15. Esophageal Impedance Monitoring: Clinical Pearls and Pitfalls.

    PubMed

    Ravi, Karthik; Katzka, David A

    2016-09-01

    The development of intraluminal esophageal impedance monitoring has improved our ability to detect and measure gastroesophageal reflux without dependence on acid content. This ability to detect previously unrecognized weak or nonacid reflux episodes has had important clinical implications in the diagnosis and management of gastroesophageal reflux disease (GERD). In addition, with the ability to assess bolus transit within the esophageal lumen, impedance monitoring has enhanced the recognition and characterization of esophageal motility disorders in patients with nonobstructive dysphagia. The assessment of the intraluminal movement of gas and liquid has also been proven to be of diagnostic value in conditions such as rumination syndrome and excessive belching. Further, alternative applications of impedance monitoring, such as the measurement of mucosal impedance, have provided novel insights into assessing esophageal mucosal integrity changes as a consequence of inflammatory change. Future applications for esophageal impedance monitoring also hold promise in esophageal conditions other than GERD. However, despite all of the clinical benefits afforded by esophageal impedance monitoring, important clinical and technical shortcomings limit its diagnostic value and must be considered when interpreting study results. Overinterpretation of studies or application of impedance monitoring in patients can have deleterious clinical implications. This review will highlight the clinical benefits and limitations of esophageal impedance monitoring and provide clinical pearls and pitfalls associated with this technology. PMID:27325223

  16. A preliminary study on the prediction of damaged areas on ordinary concrete and lightweight concrete using electromechanical impedance technique with different frequency ranges

    NASA Astrophysics Data System (ADS)

    Cho, K. J.; Na, S.; Jang, J. G.; Lee, H. K.

    2014-03-01

    The electromechanical impedance (EMI) method for NDE uses a single piezoelectric material to act as an actuator and a sensor simultaneously, and the EMI method is suitable for structures with complex surfaces. However, this technique still has wide range of problems which needs to be investigated. For one, locating damaged areas on a host structure precisely is known to be extremely difficult as this non-model based technique heavily relies on the variations in the impedance signatures. In this study, an attempt to locate the damaged areas on an ordinary concrete panel and a lightweight concrete panel using bottom ash is carried out by using different frequency ranges. Since the sensing range decreases as the excitation frequency of piezoelectric material increases, one can possibly predict the damaged areas by analyzing the impedance signatures from different frequency ranges. Statistical analysis method such as root mean square deviation (RMSD) is applied to determine the changes of the experimental structures, and the RMSD values of low frequency range and high frequency range are compared to verify the relationship between the frequency range and sensing range. Furthermore, the applicability of this method to locating the damaged areas is investigated on various materials including the lightweight concrete.

  17. Impedance of the amphibian lens.

    PubMed

    Duncan, G; Patmore, L; Pynsent, P B

    1981-03-01

    1. The electrical resistance of the perfused frog lens was measured using separate internal current passing and voltage measuring electrodes. 2. The resistance values obtained using voltage clamp and direct and alternating current techniques were in good agreement. 3. The voltage transients induced in response to current steps were multi-exponential in form. Increasing the external K concentration reduced both the amplitude of the voltage response and the rise time. 4. The impedance characteristics were investigated in more detail using alternating current analysis techniques. 5. In an equivalent-circuit modelling study it was assumed that there were two major pathways for current flow in the lens. The first through the surface membranes and the second through the inner fibre membranes via the narrow extracellular spaces. 6. The experimental impedance loci could not be adequately fitted by a simple two time constant model and a third time constant was introduced which may represent diffusion polarization effects in the extracellular spaces. 7. The three time constant model gave good and consistent fits to impedance data from a number of preparations. 8. The form of the impedance loci was also dependent on the external K concentration, but the only fitted parameter which changed consistently with external K was the surface membrane resistance (Rs).

  18. Impedance of the amphibian lens.

    PubMed Central

    Duncan, G; Patmore, L; Pynsent, P B

    1981-01-01

    1. The electrical resistance of the perfused frog lens was measured using separate internal current passing and voltage measuring electrodes. 2. The resistance values obtained using voltage clamp and direct and alternating current techniques were in good agreement. 3. The voltage transients induced in response to current steps were multi-exponential in form. Increasing the external K concentration reduced both the amplitude of the voltage response and the rise time. 4. The impedance characteristics were investigated in more detail using alternating current analysis techniques. 5. In an equivalent-circuit modelling study it was assumed that there were two major pathways for current flow in the lens. The first through the surface membranes and the second through the inner fibre membranes via the narrow extracellular spaces. 6. The experimental impedance loci could not be adequately fitted by a simple two time constant model and a third time constant was introduced which may represent diffusion polarization effects in the extracellular spaces. 7. The three time constant model gave good and consistent fits to impedance data from a number of preparations. 8. The form of the impedance loci was also dependent on the external K concentration, but the only fitted parameter which changed consistently with external K was the surface membrane resistance (Rs). PMID:6973626

  19. Calibration of electrical impedance tomography

    SciTech Connect

    Daily, W; Ramirez, A

    2000-05-01

    Over the past 10 years we have developed methods for imaging the electrical resistivity of soil and rock formations. These technologies have been called electrical resistance tomography of ERT (e.g. Daily and Owen, 1991). Recently we have been striving to extend this capability to include images of electric impedance--with a new nomenclature of electrical impedance tomography or EIT (Ramirez et al., 1999). Electrical impedance is simply a generalization of resistance. Whereas resistance is the zero frequency ratio of voltage and current, impedance includes both the magnitude and phase relationship between voltage and current at frequency. This phase and its frequency behavior is closely related to what in geophysics is called induced polarization or (Sumner, 1976). Why is this phase or IP important? IP is known to be related to many physical phenomena of importance so that image of IP will be maps of such things as mineralization and cation exchange IP (Marshall and Madden, 1959). Also, it is likely that IP, used in conjunction with resistivity, will yield information about the subsurface that can not be obtained by either piece of information separately. In order to define the accuracy of our technologies to image impedance we have constructed a physical model of known impedance that can be used as a calibration standard. It consists of 616 resistors, along with some capacitors to provide the reactive response, arranged in a three dimensional structure as in figure 1. Figure 2 shows the construction of the network and defines the coordinate system used to describe it. This network of components is a bounded and discrete version of the unbounded and continuous medium with which we normally work (the subsurface). The network has several desirable qualities: (1) The impedance values are known (to the accuracy of the component values). (2) The component values and their 3D distribution is easily controlled. (3) Error associated with electrode noise is eliminated. (4

  20. Upper critical field and AC-Susceptibility studies on FeTe0.5Se0.5 superconductor

    NASA Astrophysics Data System (ADS)

    Zargar, Rayees A.; Pal, Anand; Hafiz, A. K.; Awana, V. P. S.

    2015-06-01

    In this study we present synthesis and characterization of FeTe0.5Se0.5 sample that has been prepared by solid state reaction route by encapsulation of stoichiometric high purity (5N) ingredients in an evacuated quartz tube at 750 °C. The resultant compound is crystallized in single phase tetragonal structure with space group P4/nmm, having lattice parameters a = 3.792(1) Å and c = 6.0081(3) Å. The studied compound is superconducting at below 13K in both magnetic and transport measurements. Further superconductivity is barely affected by external applied magnetic field, giving rise to upper critical field of above 180 Tesla at 0 K. The sample is studied extensively for AC susceptibility measurements in superconducting state. The AC drive field and frequency are varied from 1-13 Oe and 33-9999 Hz respectively. It is concluded that though the grain boundaries of this superconductor are mainly metallic the minor (undetectable in XRD) foreign phases and the role of porosity cannot be ruled out completely. This is because both frequency and amplitude affects slightly the superconductivity coupling temperature of the grains.

  1. Ag incorporated Mn3O4/AC nanocomposite based supercapacitor devices with high energy density and power density.

    PubMed

    Nagamuthu, S; Vijayakumar, S; Muralidharan, G

    2014-12-14

    Silver incorporated Mn3O4/amorphous carbon (AC) nanocomposites are synthesized by a green chemistry method. X-ray diffraction studies revealed the structural changes in Mn3O4/AC nanocomposites attributable to the addition of silver. Cyclic voltammetry, charge-discharge and ac-impedance studies indicated that the Ag-Mn3O4/AC-5 electrode was the most suitable candidate for supercapacitor applications. From the galvanostatic charge-discharge studies, a higher specific capacitance of 981 F g(-1) at a specific current of 1 A g(-1) was obtained. An Ag-Mn3O4/AC-symmetric supercapacitor consisting of an Ag-incorporated Mn3O4/AC composite as an anode as well as a cathode, and an asymmetric supercapacitor consisting of an Ag-incorporated Mn3O4/AC composite as a cathode and an activated carbon as an anode have been fabricated. The symmetric device exhibits a specific cell capacitance of 72 F g(-1) at a specific current of 1 A g(-1) whereas the asymmetric device delivers a specific cell capacitance of 180 F g(-1) at a high current rate of 10 A g(-1). The asymmetric supercapacitor device yields a high energy density of 81 W h kg(-1). This is higher than that of lead acid batteries and comparable with that of nickel hydride batteries.

  2. Quantification of Inlet Impedance Concept and a Study of the Rayleigh Formula for Noise Radiation from Ducted Fan Engines

    NASA Technical Reports Server (NTRS)

    Posey, Joe W.; Dunn, M. H.; Farassat, F.

    2004-01-01

    This paper addresses two aspects of duct propagation and radiation which can contribute to more efficient fan noise predictions. First, we assess the effectiveness of Rayleigh's formula as a ducted fan noise prediction tool. This classical result which predicts the sound produced by a piston in a flanged duct is expanded to include the uniform axial inflow case. Radiation patterns using Rayleigh's formula with single radial mode input are compared to those obtained from the more precise ducted fan noise prediction code TBIEM3D. Agreement between the two methods is excellent in the peak noise regions both forward and aft. Next, we use TBIEM3D to calculate generalized radiation impedances and power transmission coefficients. These quantities are computed for a wide range of operating parameters. Results were obtained for higher Mach numbers, frequencies, and circumferential mode orders than have been previously published. Viewed as functions of frequency, calculated trends in lower order inlet impedances and power transmission coefficients are in agreement with known results. The relationships are more oscillatory for higher order modes and higher Mach numbers.

  3. Impedance Biosensing to detect food allergens, endocrine disrupting chemicals, and food pathogens

    NASA Astrophysics Data System (ADS)

    Radhakrishnan, Rajeswaran

    Electrochemical impedance biosensors can be viewed as an AC electroanalytical method for the analyte detection in the fields of biomedicine, environmental monitoring, and food and agriculture, amongst others. The most common format for AC impedance biosensing involves surface immobilization of an antibody, receptor protein, DNA strand, or other species capable of bio-recognition, and AC impedance detection of the binding event. Technological application of AC impedance biosensors has been hindered by several obstacles, including the more complex circuitry required for AC relative to DC electrochemistry, chemical and physical interference arising from non-specific adsorption, and the stability and reproducibility of protein immobilization. One focus of these PhD studies is on methods to reduce or compensate for non-specific adsorption, including sample dilution, site blocking with BSA, and the use of control electrodes onto which reference antibodies are immobilized. Examples that will be presented include impedance detection of food pathogens, such as Listeria monocytogenes, using a mouse monoclonal antibody immobilized onto an Au electrode. This yields detection limits of 5 CFU/ml and 4 CFU/ml for ideal solutions and filtered tomato extract, respectively. Control experiments with an Au electrode onto which a mouse monoclonal antibody to GAPDH is immobilized demonstrate that non-specific adsorption is insignificant for the system and methodology studied here. Control experiments with Salmonella enterica demonstrate no cross-reactivity to this food pathogen. In addition, Detection of two endocrine-disrupting chemicals (EDC), norfluoxetine and BDE-47, is reported here by impedance biosensing, with a detection limit of 8.5 and 1.3 ng/ml for norfluoxetine and BDE-47, respectively. Additional research has focused on alternative substrates and linker chemistries for protein immobilization, including the use of degenerate (highly doped) Si and bidendate thiol monolayer

  4. Flow time through esophagogastric junction derived during high-resolution impedance-manometry studies: a novel parameter for assessing esophageal bolus transit

    PubMed Central

    Lin, Zhiyue; Imam, Hala; Nicodème, Frèdèric; Carlson, Dustin A.; Lin, Chen-Yuan; Yim, Brandon; Kahrilas, Peter J.

    2014-01-01

    This study aimed to develop and validate a method to measure bolus flow time (BFT) through the esophagogastric junction (EGJ) using a high-resolution impedance-manometry (HRIM) sleeve. Ten healthy subjects were studied with concurrent HRIM and videofluoroscopy; another 15 controls were studied with HRIM alone. HRIM studies were performed using a 4.2-mm-outer diameter assembly with 36 pressure sensors at 1-cm intervals and 18 impedance segments at 2-cm intervals (Given Imaging, Los Angeles, CA). HRIM and fluoroscopic data from four barium swallows, two in the supine and two in the upright position, were analyzed to create a customized MATLAB program to calculate BFT using a HRIM sleeve comprising three sensors positioned at the crural diaphragm. Bolus transit through the EGJ measured during blinded review of fluoroscopy was almost identical to BFT calculated with the HRIM sleeve, with the nadir impedance deflection point used as the signature of bolus presence. Good correlation existed between videofluoroscopy for measurement of upper sphincter relaxation to beginning of flow [R = 0.97, P < 0.001 (supine) and R = 0.77, P < 0.01 (upright)] and time to end of flow [R = 0.95, P < 0.001 (supine) and R = 0.82, P < 0.01 (upright)]. The medians and interquartile ranges (IQR) of flow time though the EGJ in 15 healthy subjects calculated using the virtual sleeve were 3.5 s (IQR 2.3–3.9 s) in the supine position and 3.2 s (IQR 2.3–3.6 s) in the upright position. BFT is a new metric that provides important information about bolus transit through the EGJ. An assessment of BFT will determine when the EGJ is open and will also provide a useful method to accurately assess trans-EGJ pressure gradients during flow. PMID:24852565

  5. Summary of the impedance working group

    SciTech Connect

    Chao, A.W.

    1995-05-01

    The impedance working group concentrated on the LHC design during the workshop. They look at the impedance contributions of liner, beam position monitors, shielded bellows, experimental chambers, superconducting cavities, recombination chambers, space charge, kickers, and the resistive wall. The group concluded that the impedance budgeting and the conceptual designs of the vacuum chamber components looked basically sound. It also noted, not surprisingly, that a large amount of studies are to be carried out further, and it ventured to give a partial list of these studies.

  6. Dielectric, Impedance and Conduction Behavior of Double Perovskite Pr2CuTiO6 Ceramics

    NASA Astrophysics Data System (ADS)

    Mahato, Dev K.; Sinha, T. P.

    2016-08-01

    Polycrystalline Pr2CuTiO6 (PCT) ceramics exhibits dielectric, impedance and modulus characteristics as a possible material for microelectronic devices. PCT was synthesized through the standard solid-state reaction method. The dielectric permittivity, impedance and electric modulus of PCT have been studied in a wide frequency (100 Hz-1 MHz) and temperature (303-593 K) range. Structural analysis of the compound revealed a monoclinic phase at room temperature. Complex impedance Cole-Cole plots are used to interpret the relaxation mechanism, and grain boundary contributions towards conductivity have been estimated. From electrical modulus formalism polarization and conductivity relaxation behavior in PCT have been discussed. Normalization of the imaginary part of impedance (Z″) and the normalized imaginary part of modulus (M″) indicates contributions from both long-range and localized relaxation effects. The grain boundary resistance along with their relaxation frequencies are plotted in the form of an Arrhenius plot with activation energy 0.45 eV and 0.46 eV, respectively. The ac conductivity mechanism has been discussed.

  7. Preliminary Geological Maps of the Ac-H-10 Rongo and Ac-H-15 Zadeni Quadrangles: An integrated Mapping Study Using Dawn Spacecraft Data

    NASA Astrophysics Data System (ADS)

    Platz, T.; Nathues, A.; Crown, D. A.; Mest, S. C.; Williams, D. A.; Hoffmann, M.; Schäfer, M.; Sizemore, H. G.; Yingst, R. A.; Ruesch, O.; Buczkowski, D.; Kneissl, T.; Schmedemann, N.; Hughson, K.; Preusker, F.; Russell, C. T.

    2015-12-01

    We used geologic mapping applied to Dawn spacecraft data as a tool to understand the geologic history of the Ac-H-10 Rongo and Ac-H-15 Zadeni quadrangles of dwarf planet Ceres. These regions, Rongo and Zadeni, are located between 22°S-22°N and 288°-360°E and 65-90°S and 0°-360°E, respectively. The Rongo Quadrangle hosts a number of features: 1) the southwest portion is dissected by curvilinear structures likely caused by Yalode basin formation; 2) the central part is marked by dome-like constructs up to 100 km across; 3) a peculiar bright, c.4 km tall, conical structure informally known as the 'pyramid'; 4) impact craters of various diameters appear moderately to highly degraded or are partially buried; and 5) bright material is primarily exposed in the central portion and often associated with craters. Rongo crater (68 km across) exhibits a central peak and scalloped walls indicative of its degraded appearance. The Zadeni Quadrangle is characterised by impact craters up to 130 km in diameter of which Zadeni crater is the largest. Impact craters across all sizes exhibit fresh to highly degraded morphologies or are partially buried. Many craters developed central peaks. Inter-crater plains are generally hummocky with isolated regions of smooth-textured surfaces. The south pole area (85-90°S) is poorly illuminated and may host a large impact structure. At the time of this writing geologic mapping was performed on Framing Camera (FC) mosaics from Approach (1.3 km/px) and Survey (415 m/px) orbits, including clear filter and colour images and digital terrain models derived from stereo images. In Fall 2015 images from the High Altitude Mapping Orbit (140 m/px) will be used to refine the mapping, followed by Low Altitude Mapping Orbit (35 m/px) starting in December 2015. Support of the Dawn Instrument, Operations, and Science Teams is acknowledged. This work is supported by grants from NASA through the Dawn project, and from the German and Italian Space Agencies.

  8. Combining TMS and tACS for Closed-Loop Phase-Dependent Modulation of Corticospinal Excitability: A Feasibility Study

    PubMed Central

    Raco, Valerio; Bauer, Robert; Tharsan, Srikandarajah; Gharabaghi, Alireza

    2016-01-01

    Background: The corticospinal excitability indexed by motor evoked potentials (MEPs) following transcranial magnetic stimulation (TMS) of the sensorimotor cortex is characterized by large variability. The instantaneous phase of cortical oscillations at the time of the stimulation has been suggested as a possible source of this variability. To explore this hypothesis, a specific phase needs to be targeted by TMS pulses with high temporal precision. Objective: The aim of this feasibility study was to introduce a methodology capable of exploring the effects of phase-dependent stimulation by the concurrent application of alternating current stimulation (tACS) and TMS. Method: We applied online calibration and closed-loop TMS to target four specific phases (0°, 90°, 180° and 270°) of simultaneous 20 Hz tACS over the primary motor cortex (M1) of seven healthy subjects. Result: The integrated stimulation system was capable of hitting the target phase with high precision (SD ± 2.05 ms, i.e., ± 14.45°) inducing phase-dependent MEP modulation with a phase lag (CI95% = −40.37° to −99.61°) which was stable across subjects (p = 0.001). Conclusion: The combination of different neuromodulation techniques facilitates highly specific brain state-dependent stimulation, and may constitute a valuable tool for exploring the physiological and therapeutic effect of phase-dependent stimulation, e.g., in the context of neurorehabilitation. PMID:27252625

  9. Improving neuron-to-electrode surface attachment via alkanethiol self-assembly: an alternating current impedance study.

    PubMed

    Slaughter, Gymama E; Bieberich, Erhard; Wnek, Gary E; Wynne, Kenneth J; Guiseppi-Elie, Anthony

    2004-08-17

    examined by alternating current impedance (50 mV p-t-p at 4 kHz). CA- and 11-AUT-SAM-modified surfaces when serving as a foundation or covalently immobilized adhesion proteins produced highly stable and reproducible temporal impedance responses. On the basis of the magnitude and the reproducibility of the impedance responses, the CA-SAM-modified surfaces were identified as being best suited for optimal neuron-to-electrode contact with laminin. Laminin performed best when compared to collagen and fibronectin. Covalent immobilization of the adhesion-promoting proteins results in enhanced NESA by tightly anchoring cells to the electrode.

  10. Synthesis, crystal structure, NMR study and AC conductivity of [(C3H7)4N]2Cd2ClF5 compound

    NASA Astrophysics Data System (ADS)

    Hajji, Rachid; Oueslati, Abderrazak; Body, Monique; Hlel, Faouzi

    2015-08-01

    The [(C3H7)4N]2Cd2ClF5 compound was crystallized in the triclinic system with space group P1. The crystal structure consists of organic-inorganic layers, stacked along direction. The organic part consists of two cations types. The inorganic layer is made up of Cd2ClF5 dimmers composed of two in-equivalent irregular tetrahedra sharing one edge (Cl-F). The MAS NMR spectra showed two, three and five isotropic resonances relative to 111Cd, 13C and 19F nuclei, respectively. DSC measurement disclosed a phase transition at around 380 K. The impedance spectroscopy and AC electrical conductivity measurements of our compound were taken from 209 Hz to 5 MHz over the temperature range of 350-381 K. Nyquist plots ( Z″ vs Z') show semicircle arcs at different temperatures, and an electrical equivalent circuit has been proposed to explain the impedance results. The circuits consist of the parallel combination of bulk resistance ( R), capacitance ( C) and fractal capacitance (CPE). The conductivity σ p follows the Arrhenius relation. The near value of activation energies obtained from the conductivity data and circuit equivalent confirms that the transport is through hopping mechanism. The analysis of the experimental data shows that the reorientation motion of [N(C3H7)4]+ cations and/or [Cd2ClF5]2- anions is probably responsible for the observed conductivity.

  11. Kinetic studies of the stress corrosion cracking of D6AC steel

    NASA Technical Reports Server (NTRS)

    Noronha, P. J.

    1975-01-01

    The effect of load interactions on the crack growth velocity of D6AC steel under stress corrosion cracking conditions was determined. The environment was a 3.5 percent salt solution. The modified-wedge opening load specimens were fatigue precracked and subjected to a deadweight loading in creep machines. The effects of load shedding on incubation times and crack growth rates were measured using high-sensitivity compliance measurement techniques. Load shedding results in an incubation time, the length of which depends on the amount of load shed and the baseline stress intensity. The sequence of unloading the specimen also controls the subsequent incubation period. The incubation period is shorter when load shedding passes through zero load than when it does not if the specimen initially had the same baseline stress intensity. The crack growth rates following the incubation period are also different from the steady-state crack growth rate at the operating stress intensity. These data show that the susceptibility of this alloy system to stress corrosion cracking depends on the plane-strain fracture toughness and on the yield strength of the material.

  12. Estimates of Acausal Joint Impedance Models

    PubMed Central

    Perreault, Eric J.

    2013-01-01

    Estimates of joint or limb impedance are commonly used in the study of how the nervous system controls posture and movement, and how that control is altered by injury to the neural or musculoskeletal systems. Impedance characterizes the dynamic relationship between an imposed perturbation of joint position and the torques generated in response. While there are many practical reasons for estimating impedance rather than its inverse, admittance, it is an acausal representation of the limb mechanics that can lead to difficulties in interpretation or use. The purpose of this study was to explore the acausal nature of nonparametric estimates of joint impedance representations to determine how they are influenced by common experimental and computational choices. This was accomplished by deriving discrete-time realizations of first-and second-order derivatives to illustrate two key difficulties in the physical interpretation of impedance impulse response functions. These illustrations were provided using both simulated and experimental data. It was found that the shape of the impedance impulse response depends critically on the selected sampling rate, and on the bandwidth and noise characteristics of the position perturbation used during the estimation process. These results provide important guidelines for designing experiments in which nonparametric estimates of impedance will be obtained, especially when those estimates are to be used in a multistep identification process. PMID:22907963

  13. Dielectric and impedance behavior of neodymium substituted strontium hexaferrite

    NASA Astrophysics Data System (ADS)

    Bhat, Bilal Hamid; Samad, Rubiya; Want, Basharat

    2016-09-01

    In this study, dielectric behavior and complex impedance of neodymium (Nd) substituted strontium hexaferrite system: Sr1- x Nd x Fe12O19 ( x = 0.0, 0.05, 0.1, 0.15, 0. 20), synthesized by citrate precursor technique, have been evaluated as a function of applied frequency and temperature. Variation of dielectric constant and dielectric loss with frequency shows the identical behavior for all the compositions. The value of dielectric constant increases with Nd doping. Relaxation process is observed in the composition x = 0.20, and the peaks in this composition shift toward the higher-frequency region as the temperature increases. The dielectric constants show temperature-independent behavior at low temperature, whereas at higher temperatures it increases for all the frequencies. The AC conductivity follows Jonscher's power law, showing that conduction mechanism is due to polaron hopping. Complex impedance as a function of composition and temperature is used to examine the role of grain and grain boundary in the prepared material. Cole-cole plot shows only one semicircle up to x = 0.15, while as for x = 0.20 two semicircles are observed. The conduction mechanism is explained on the basis of both grain and grain boundary.

  14. Impedance-based analysis and study of phase sensitivity in slow-wave two-beam accelerators

    SciTech Connect

    Wurtele, J.S. ); Whittum, D.H. , Tsukuba, Oho, Ibaraki, 305 ); Sessler, A.M. )

    1992-07-01

    This paper presents a new formalism which makes the analysis and understanding of both the relativistic klystron (RK) and the standing-wave free-electron laser (SWFEL) two-beam accelerator (TBA) available to a wide audience of accelerator physicists. A coupling impedance'' for both the RK and SWFEWL is introduced, which can include realistic cavity features, such as beam and vacuum ports, in a simple manner. The RK and SWFEL macroparticle equations, which govern the energy and phase evolution of successive bunches in the beam, are of identical form, differing only by multiplicative factors. Expressions are derived for the phase and amplitude sensitivities of the TBA schemes to errors (shot-to-shot jitter) in current and energy. The analysis allows, for the first time, relative comparisons of the RK and the SWFEL TBAs.

  15. Impedance-based analysis and study of phase sensitivity in slow-wave two-beam accelerators

    SciTech Connect

    Wurtele, J.S.; Whittum, D.H.; Sessler, A.M.

    1992-06-01

    This paper presents a new formalism which makes the analysis and understanding of both the relativistic klystron (RK) and the standing-wave free-electron laser (SWFEL) two-beam accelerator (TBA) available to a wide audience of accelerator physicists. A ``coupling impedance`` for both the RK and SWFEWL is introduced, which can include realistic cavity features, such as beam and vacuum ports, in a simple manner. The RK and SWFEL macroparticle equations, which govern the energy and phase evolution of successive bunches in the beam, are of identical form, differing only by multiplicative factors. Expressions are derived for the phase and amplitude sensitivities of the TBA schemes to errors (shot-to-shot jitter) in current and energy. The analysis allows, for the first time, relative comparisons of the RK and the SWFEL TBAs.

  16. Impedance modelling of pipes

    NASA Astrophysics Data System (ADS)

    Creasy, M. Austin

    2016-03-01

    Impedance models of pipes can be used to estimate resonant frequencies of standing waves and model acoustic pressure of closed and open ended pipes. Modelling a pipe with impedance methods allows additional variations to the pipe to be included in the overall model as a system. Therefore an actuator can be attached and used to drive the system and the impedance model is able to include the dynamics of the actuator. Exciting the pipe system with a chirp signal allows resonant frequencies to be measured in both the time and frequency domain. The measurements in the time domain are beneficial for introducing undergraduates to resonances without needing an understanding of fast Fourier transforms. This paper also discusses resonant frequencies in open ended pipes and how numerous texts incorrectly approximate the resonant frequencies for this specific pipe system.

  17. Study of Ac Dielectrophoretic Process of SiC Nanowires: A Universal Method for Alignment of Semiconductor Nanowires.

    PubMed

    Yao, Limei; Cui, Yan; Cong, Haining; Zheng, Jinju; Shang, Minghui; Yang, Zuobao; Yang, Weiyou; Wei, Guodong; Gao, Fengmei

    2016-04-01

    In this study, the dielectrophoretic processes of SiC nanowires suspended in three typical solvents, (highly purified water, ethanol and isopropanol) were systematically investigated. Optical microscope and SEM characterizations were used to observe the order of SiC nanowires on the surface of gold microchannels. The gold microchannels were induced by Ac dielectrophoresis of the corresponding dispersion solutions of SiC nanowires, with a concentration of 0.1 mg/mL. The study shows that the dielectrophoresis process is an effective way of synthesizing highly oriented SiC nanoarrays using isopropanol solution. The results also show that the arrangement of SiC nanowires on the interdigital electrode configuration not only depend on the kind of solvent used, but also on the applied frequency (1000 Hz~1 MHz) and voltage (1 V~20 V). PMID:27451739

  18. Electron paramagnetic resonance spectral study of [Mn(acs)2(2-pic)2(H2O)2] single crystals

    NASA Astrophysics Data System (ADS)

    Kocakoç, Mehpeyker; Tapramaz, Recep

    2016-03-01

    Acesulfame potassium salt is a synthetic and non-caloric sweetener. It is also important chemically for its capability of being ligand in coordination compounds, because it can bind over Nitrogen and Oxygen atoms of carbonyl and sulfonyl groups and ring oxygen. Some acesulfame containing transition metal ion complexes with mixed ligands exhibit solvato and thermo chromic properties and these properties make them physically important. In this work single crystals of Mn+2 ion complex with mixed ligand, [Mn(acs)2(2-pic)2(H2O)2], was studied with electron paramagnetic resonance (EPR) spectroscopy. EPR parameters were determined. Zero field splitting parameters indicated that the complex was highly symmetric. Variable temperature studies showed no detectable chance in spectra.

  19. Study of Ac Dielectrophoretic Process of SiC Nanowires: A Universal Method for Alignment of Semiconductor Nanowires.

    PubMed

    Yao, Limei; Cui, Yan; Cong, Haining; Zheng, Jinju; Shang, Minghui; Yang, Zuobao; Yang, Weiyou; Wei, Guodong; Gao, Fengmei

    2016-04-01

    In this study, the dielectrophoretic processes of SiC nanowires suspended in three typical solvents, (highly purified water, ethanol and isopropanol) were systematically investigated. Optical microscope and SEM characterizations were used to observe the order of SiC nanowires on the surface of gold microchannels. The gold microchannels were induced by Ac dielectrophoresis of the corresponding dispersion solutions of SiC nanowires, with a concentration of 0.1 mg/mL. The study shows that the dielectrophoresis process is an effective way of synthesizing highly oriented SiC nanoarrays using isopropanol solution. The results also show that the arrangement of SiC nanowires on the interdigital electrode configuration not only depend on the kind of solvent used, but also on the applied frequency (1000 Hz~1 MHz) and voltage (1 V~20 V).

  20. Rotor damage detection by using piezoelectric impedance

    NASA Astrophysics Data System (ADS)

    Qin, Y.; Tao, Y.; Mao, Y. F.

    2016-04-01

    Rotor is a core component of rotary machinery. Once the rotor has the damage, it may lead to a major accident. Thus the quantitative rotor damage detection method based on piezoelectric impedance is studied in this paper. With the governing equation of piezoelectric transducer (PZT) in a cylindrical coordinate, the displacement along the radius direction is derived. The charge of PZT is calculated by the electric displacement. Then, by the use of the obtained displacement and charge, an analytic piezoelectric impedance model of the rotor is built. Given the circular boundary condition of a rotor, annular elements are used as the analyzed objects and spectral element method is used to set up the damage detection model. The Electro-Mechanical (E/M) coupled impedance expression of an undamaged rotor is deduced with the application of a low-cost impedance test circuit. A Taylor expansion method is used to obtain the approximate E/M coupled impedance expression for the damaged rotor. After obtaining the difference between the undamaged and damaged rotor impedance, a rotor damage detection method is proposed. This method can directly calculate the change of bending stiffness of the structural elements, it follows that the rotor damage can be effectively detected. Finally, a preset damage configuration is used for the numerical simulation. The result shows that the quantitative damage detection algorithm based on spectral element method and piezoelectric impedance proposed in this paper can identify the location and the severity of the damaged rotor accurately.

  1. Tracking of electrochemical impedance of batteries

    NASA Astrophysics Data System (ADS)

    Piret, H.; Granjon, P.; Guillet, N.; Cattin, V.

    2016-04-01

    This paper presents an evolutionary battery impedance estimation method, which can be easily embedded in vehicles or nomad devices. The proposed method not only allows an accurate frequency impedance estimation, but also a tracking of its temporal evolution contrary to classical electrochemical impedance spectroscopy methods. Taking into account constraints of cost and complexity, we propose to use the existing electronics of current control to perform a frequency evolutionary estimation of the electrochemical impedance. The developed method uses a simple wideband input signal, and relies on a recursive local average of Fourier transforms. The averaging is controlled by a single parameter, managing a trade-off between tracking and estimation performance. This normalized parameter allows to correctly adapt the behavior of the proposed estimator to the variations of the impedance. The advantage of the proposed method is twofold: the method is easy to embed into a simple electronic circuit, and the battery impedance estimator is evolutionary. The ability of the method to monitor the impedance over time is demonstrated on a simulator, and on a real Lithium ion battery, on which a repeatability study is carried out. The experiments reveal good tracking results, and estimation performance as accurate as the usual laboratory approaches.

  2. Superconducting active impedance converter

    DOEpatents

    Ginley, David S.; Hietala, Vincent M.; Martens, Jon S.

    1993-01-01

    A transimpedance amplifier for use with high temperature superconducting, other superconducting, and conventional semiconductor allows for appropriate signal amplification and impedance matching to processing electronics. The amplifier incorporates the superconducting flux flow transistor into a differential amplifier configuration which allows for operation over a wide temperature range, and is characterized by high gain, relatively low noise, and response times less than 200 picoseconds over at least a 10-80 K. temperature range. The invention is particularly useful when a signal derived from either far-IR focal plane detectors or from Josephson junctions is to be processed by higher signal/higher impedance electronics, such as conventional semiconductor technology.

  3. Superconducting active impedance converter

    DOEpatents

    Ginley, D.S.; Hietala, V.M.; Martens, J.S.

    1993-11-16

    A transimpedance amplifier for use with high temperature superconducting, other superconducting, and conventional semiconductors allows for appropriate signal amplification and impedance matching to processing electronics. The amplifier incorporates the superconducting flux flow transistor into a differential amplifier configuration which allows for operation over a wide temperature range, and is characterized by high gain, relatively low noise, and response times less than 200 picoseconds over at least a 10-80 K. temperature range. The invention is particularly useful when a signal derived from either far-IR focal plane detectors or from Josephson junctions is to be processed by higher signal/higher impedance electronics, such as conventional semiconductor technology. 12 figures.

  4. Impedance and modulus studies of magnetic ceramic oxide Ba2Co2Fe12O22 (Co2Y) doped with Bi2O3

    NASA Astrophysics Data System (ADS)

    Costa, M. M.; Pires, G. F. M.; Terezo, A. J.; Graça, M. P. F.; Sombra, A. S. B.

    2011-08-01

    Polycrystalline samples of a layered magnetic ceramic oxide, Ba2Co2Fe12O22 (Co2Y), doped with Bi2O3 were prepared by the solid state reaction method. The dielectric impedance properties were studied over the range of frequency between 1 Hz-1MHz and in the temperature range of 313-493 K, using the modulus formalism. The impedance plot showed a first semicircle at high frequency which was assigned to the grain intrinsic effect and a second semicircle, at lower frequencies, which corresponds to grain boundary polarization (conduction phenomenon). A complex modulus spectrum was used to understand the mechanism of the electrical transport process, which indicates that a non-exponential type of conductivity relaxation characterizes this material. The values of the activation energy of the compound (calculated both from dc conductivity and the modulus spectrum) are very similar, suggesting that the relaxation process may be attributed to the same type of charge carriers. The dielectric measurements were studied by fitting the electrical modulus with the Havriliak-Negami function, including the conductivity parameters. The study demonstrates that the investigation of dielectric relaxation, conductivity, and loss of the ferrite materials, as a function of temperature, are essential for future microwave absorption applications of this material.

  5. Bollgard II cotton: compositional analysis and feeding studies of cottonseed from insect-protected cotton (Gossypium hirsutum L.) producing the Cry1Ac and Cry2Ab2 proteins.

    PubMed

    Hamilton, Kathryn A; Pyla, Paul D; Breeze, Matthew; Olson, Tammy; Li, Menghe; Robinson, Edwin; Gallagher, Sean P; Sorbet, Roy; Chen, Yin

    2004-11-17

    Bollgard II cotton event 15985 producing the Cry1Ac and Cry2Ab2 proteins has been developed by genetic modification to broaden the spectrum of insects to which the plant is tolerant and to provide an insect resistance management tool to impede the onset of resistance. The purpose of this study was to evaluate the composition and nutrition of Bollgard II cotton, relative to the use for food and animal feed, compared to that of conventional cotton varieties. Compositional analyses were conducted to measure proximate, fiber, amino acid, fatty acid, gossypol, and mineral contents of cottonseed from a total of 14 U.S. field sites over two years. Compositional analysis results showed that the cottonseed and cottonseed oil from Bollgard II cotton were comparable in their composition to those of the conventional control cotton line and other commercial varieties. The composition data are supported by nutritional safety studies conducted with dairy cows, catfish, and quail. Results from these studies showed that Bollgard II performed similarly to the conventional control cotton varieties. These data demonstrate that Bollgard II cotton is compositionally and nutritionally equivalent to conventional cotton varieties. These data support the conclusion that Bollgard II cotton is as safe and nutritious as conventional cotton for food and feed use.

  6. Impedance spectroscopy for the detection and identification of unknown toxins

    NASA Astrophysics Data System (ADS)

    Riggs, B. C.; Plopper, G. E.; Paluh, J. L.; Phamduy, T. B.; Corr, D. T.; Chrisey, D. B.

    2012-06-01

    Advancements in biological and chemical warfare has allowed for the creation of novel toxins necessitating a universal, real-time sensor. We have used a function-based biosensor employing impedance spectroscopy using a low current density AC signal over a range of frequencies (62.5 Hz-64 kHz) to measure the electrical impedance of a confluent epithelial cell monolayer at 120 sec intervals. Madin Darby canine kidney (MDCK) epithelial cells were grown to confluence on thin film interdigitated gold electrodes. A stable impedance measurement of 2200 Ω was found after 24 hrs of growth. After exposure to cytotoxins anthrax lethal toxin and etoposide, the impedance decreased in a linear fashion resulting in a 50% drop in impedance over 50hrs showing significant difference from the control sample (~20% decrease). Immunofluorescent imaging showed that apoptosis was induced through the addition of toxins. Similarities of the impedance signal shows that the mechanism of cellular death was the same between ALT and etoposide. A revised equivalent circuit model was employed in order to quantify morphological changes in the cell monolayer such as tight junction integrity and cell surface area coverage. This model showed a faster response to cytotoxin (2 hrs) compared to raw measurements (20 hrs). We demonstrate that herein that impedance spectroscopy of epithelial monolayers serves as a real-time non-destructive sensor for unknown pathogens.

  7. Impedances of Tevatron separators

    SciTech Connect

    K. Y. Ng

    2003-05-28

    The impedances of the Tevatron separators are revisited and are found to be negligibly small in the few hundred MHz region, except for resonances at 22.5 MHz. The later are contributions from the power cables which may drive head-tail instabilities if the bunch is long enough.

  8. Longitudinal impedance of RHIC

    SciTech Connect

    Blaskiewicz, M.; Brennan, J. M.; Mernick, K.

    2015-05-03

    The longitudinal impedance of the two RHIC rings has been measured using the effect of potential well distortion on longitudinal Schottky measurements. For the blue RHIC ring Im(Z/n) = 1.5±0.2Ω. For the yellow ring Im(Z/n) = 5.4±1Ω.

  9. Implantable Impedance Plethysmography

    PubMed Central

    Theodor, Michael; Ruh, Dominic; Ocker, Martin; Spether, Dominik; Förster, Katharina; Heilmann, Claudia; Beyersdorf, Friedhelm; Manoli, Yiannos; Zappe, Hans; Seifert, Andreas

    2014-01-01

    We demonstrate by theory, as well as by ex vivo and in vivo measurements that impedance plethysmography, applied extravascularly directly on large arteries, is a viable method for monitoring various cardiovascular parameters, such as blood pressure, with high accuracy. The sensor is designed as an implant to monitor cardiac events and arteriosclerotic progression over the long term. PMID:25123467

  10. Impedance adaptation methods of the piezoelectric energy harvesting

    NASA Astrophysics Data System (ADS)

    Kim, Hyeoungwoo

    In this study, the important issues of energy recovery were addressed and a comprehensive investigation was performed on harvesting electrical power from an ambient mechanical vibration source. Also discussed are the impedance matching methods used to increase the efficiency of energy transfer from the environment to the application. Initially, the mechanical impedance matching method was investigated to increase mechanical energy transferred to the transducer from the environment. This was done by reducing the mechanical impedance such as damping factor and energy reflection ratio. The vibration source and the transducer were modeled by a two-degree-of-freedom dynamic system with mass, spring constant, and damper. The transmissibility employed to show how much mechanical energy that was transferred in this system was affected by the damping ratio and the stiffness of elastic materials. The mechanical impedance of the system was described by electrical system using analogy between the two systems in order to simply the total mechanical impedance. Secondly, the transduction rate of mechanical energy to electrical energy was improved by using a PZT material which has a high figure of merit and a high electromechanical coupling factor for electrical power generation, and a piezoelectric transducer which has a high transduction rate was designed and fabricated. The high g material (g33 = 40 [10-3Vm/N]) was developed to improve the figure of merit of the PZT ceramics. The cymbal composite transducer has been found as a promising structure for piezoelectric energy harvesting under high force at cyclic conditions (10--200 Hz), because it has almost 40 times higher effective strain coefficient than PZT ceramics. The endcap of cymbal also enhances the endurance of the ceramic to sustain ac load along with stress amplification. In addition, a macro fiber composite (MFC) was employed as a strain component because of its flexibility and the high electromechanical coupling

  11. Recycler short kicker beam impedance

    SciTech Connect

    Crisp, Jim; Fellenz, Brian; /Fermilab

    2009-07-01

    Measured longitudinal and calculated transverse beam impedance is presented for the short kicker magnets being installed in the Fermilab Recycler. Fermi drawing number ME-457159. The longitudinal impedance was measured with a stretched wire and the Panofsky equation was used to estimate the transverse impedance. The impedance of 3319 meters (the Recycler circumference) of stainless vacuum pipe is provided for comparison. Although measurements where done to 3GHz, impedance was negligible above 30MHz. The beam power lost to the kicker impedance is shown for a range of bunch lengths. The measurements are for one kicker assuming a rotation frequency of 90KHz. Seven of these kickers are being installed.

  12. Impedance adaptation for optimal robot-environment interaction

    NASA Astrophysics Data System (ADS)

    Ge, Shuzhi Sam; Li, Yanan; Wang, Chen

    2014-02-01

    In this paper, impedance adaptation is investigated for robots interacting with unknown environments. Impedance control is employed for the physical interaction between robots and environments, subject to unknown and uncertain environments dynamics. The unknown environments are described as linear systems with unknown dynamics, based on which the desired impedance model is obtained. A cost function that measures the tracking error and interaction force is defined, and the critical impedance parameters are found to minimise it. Without requiring the information of the environments dynamics, the proposed impedance adaptation is feasible in a large number of applications where robots physically interact with unknown environments. The validity of the proposed method is verified through simulation studies.

  13. Electrical properties of double perovskite oxide Sr2LaSbO6: An impedance spectroscopic study

    NASA Astrophysics Data System (ADS)

    Dutta, Alo; Kumari, Premlata; Sinha, T. P.

    2015-09-01

    The Rietveld refinement of the room temperature x-ray diffraction pattern of double perovskite oxide, Sr2LaSbO6 (SLS) synthesized by the solid-state reaction technique shows monoclinic phase with P21/ n symmetry, which is substantiated by the Raman spectrum of the sample. The dielectric relaxation of SLS is investigated in the temperature range from 30°C to 300°C and in the frequency range from 50 Hz to 1 MHz. The Cole-Cole model is used to explain the dielectric relaxation of SLS. The most probable relaxation frequencies at various temperatures are found to obey the Arrhenius law with an activation energy of 0.36 eV, which indicates that the polaron hopping plays the main role in the dielectric relaxation of SLS. The complex impedance plane plots are analyzed by an electrical equivalent circuit consisting of a resistance and a constant phase element. The frequency dependent conductivity spectra obey the power law. [Figure not available: see fulltext.

  14. Impedance plethysmography in the diagnosis of asymptomatic deep vein thrombosis in hip surgery. A venography-controlled study.

    PubMed

    Agnelli, G; Cosmi, B; Ranucci, V; Renga, C; Mosca, S; Lupattelli, L; Di Filippo, P; Rinonapoli, E; Nenci, G G

    1991-11-01

    We prospectively evaluated the accuracy of computerized impedance plethysmography (CIP) in the diagnosis of asymptomatic deep vein thrombosis (DVT) in 246 consecutive high-risk patients scheduled for hip surgery, with bilateral venography used for comparison. The CIP was performed as a surveillance program every third day. If the CIP remained negative, bilateral venography was performed on postoperative day 10 +/- 1 or on day of treatment 14 +/- 1 in nonoperated-on patients. If the CIP became positive, venography was performed within 24 hours. The sensitivity and specificity of CIP for proximal and distal DVT were 19% (confidence interval [CI], 13% to 24%) and 91% (CI, 87% to 94%), respectively. The positive and negative predictive values were 52% (CI, 38% to 65%) and 70% (CI, 65% to 74%), respectively. The sensitivity and specificity of CIP for proximal DVT were 24% (CI, 13% to 34%) and 90% (CI, 87% to 94%), respectively; the positive and negative predictive values were 31% (CI, 20% to 51%) and 87% (CI, 83% to 90%), respectively. We conclude that, because of its low sensitivity, CIP cannot be used in the surveillance of DVT in high-risk patients or for outcome measurements in clinical trials on DVT prophylaxis.

  15. Epigastric impedance: a non-invasive method for the assessment of gastric emptying and motility.

    PubMed Central

    McClelland, G R; Sutton, J A

    1985-01-01

    The impedance of the epigastrium to a 4 mA, 100 KHz AC current increases while liquids of low electrical conductivity are being drunk. Logically, the decline which follows occurs as the liquid leaves the stomach. This impedance measurement of gastric emptying proved comparable with the dye dilution method. In a placebo controlled trial the impedance method recorded significantly faster gastric emptying rates after metoclopramide. The impedance trace contains regular activity in the 2-4 cycle/min range consistent with gastric contractions. This non-invasive and technically simple method may thus provide a measure of simultaneous gastric emptying rates and motility. PMID:3891533

  16. Superconducting transition in ruthenocuprate RuSr2GdCu2O8 viewed from the studies of the imaginary part of ac susceptibility

    NASA Astrophysics Data System (ADS)

    Zivkovic, I.; Drobac, D.; Ariosa, D.; Berger, H.; Pavuna, D.; Prester, M.

    2002-12-01

    We have measured two structurally similar superconducting systems, RuSr2GdCu2O8 and GdBa2Cu3O7 by means of high-resolution ac susceptibility. The real and the imaginary part of ac susceptibility of both bulk-ceramic and powdered samples have been studied down to the very small magnetic-field levels. We show that there are significant differences in the evolution of superconductivity in the two studied superconducting systems. In particular, we show that the superconducting transition in the grains in RuSr2GdCu2O8 system is masked with intrinsic magnetism of complex origin.

  17. Operation Method for AC Motor Control during Power Interruption in Direct AC/AC Converter System

    NASA Astrophysics Data System (ADS)

    Shizu, Keiichiro; Azuma, Satoshi

    Direct AC/AC converters have been studied due to their potential use in power converters with no DC-link capacitor, which can contribute to the miniaturization of power converters. However, the absence of a DC-link capacitor makes it difficult to control the AC motor during power interruption. First, this paper proposes a system that realizes AC motor control during power interruption by utilizing a clamp capacitor. In general, direct AC/AC converters have a clamp circuit consisting of a rectifier diode(s) and a clamp capacitor in order to avoid over-voltages. In the proposed system, there is an additional semiconductor switch reverse-parallel to the rectifier diode(s), and the clamp capacitor voltage can be utilized for AC motor control by turning on the additional switch. Second, this paper discusses an operation method for AC motor control and clamp capacitor voltage control during power interruption. In the proposed method “DC-link voltage control”, the kinetic energy in the AC motor is transformed into electrical energy and stored in the clamp capacitor; the clamp capacitor is therefore charged and the capacitor voltage is controlled to remain constant at an instruction value. Third, this paper discusses a switching operation during power interruption. A dead-time is introduced between the operation of turning off all switches on the rectifier side and the operation of turning on the additional switch, which prevents the occurrence of a short circuit between the interrupted power source and the clamp capacitor. Finally, experimental results are presented. During power interruptions, an output current was continuously obtained and the clamp capacitor voltage was maintained to be equal to the instruction value of the capacitor voltage. These results indicate that both AC motor control and capacitor voltage control were successfully achieved by using the proposed system.

  18. Do mathematical model studies settle the controversy on the origin of cardiac synchronous trans-thoracic electrical impedance variations? A systematic review.

    PubMed

    de Sitter, A; Verdaasdonk, R M; Faes, T J C

    2016-09-01

    Impedance cardiography (ICG) is a method to evaluate cardiac-stroke volume and cardiac-output by measuring the cardiac-synchronous changes in the dynamic trans-thoracic electrical impedance (ΔZ). Clinical evaluations on the accuracy of ICG showed varying results. Consequently, the classic assumption in ICG-the aorta as a main source of ΔZ-is questioned and subsequently investigated in simulation studies using mathematical models of the electrical resistivity of the human body. The aim is to review the consensus in mathematical modelling studies that investigate the origin of the ΔZ as measured in ICG. In a systematic literature search, studies were identified and surveyed with reference to characteristics, such as included organs and their resistivity and geometries, electrode positions and calculation of ΔZ, to review the consensus between mathematical modelling studies that investigate the origin of the ΔZ as measured in ICG. Thirteen papers showed considerable variation in the model's characteristics with varying or contradicting outcomes for the ΔZ 's origin. For instance, 11 studies excluded perfused muscle tissue, implying implicitly their insignificance, while 3 other studies included muscle tissue and indicated it as the most important origin of ΔZ. In conclusion, the reviewed papers show a lack of consensus with respect to both the modelled characteristics as well as the model outcomes and, as a result, these studies failed to settle the controversy on ΔZ 's origin. Recommendations have been added to improve future mathematical model studies.

  19. Antenna pattern control using impedance surfaces

    NASA Technical Reports Server (NTRS)

    Balanis, Constantine A.; Liu, Kefeng; Tirkas, Panayiotis A.

    1993-01-01

    During the period of this research project, a comprehensive study of pyramidal horn antennas was conducted. Full-wave analytical and numerical techniques were developed to analyze horn antennas with or without impedance surfaces. Based on these full-wave analytic techniques, research was conducted on the use of impedance surfaces on the walls of the horn antennas to control the antenna radiation patterns without a substantial loss of antenna gain. It was found that the use of impedance surfaces could modify the antenna radiation patterns. In addition to the analytical and numerical models, experimental models were also constructed and they were used to validate the predictions. Excellent agreement between theoretical predictions and the measured data was obtained for pyramidal horns with perfectly conducting surfaces. Very good comparisons between numerical and experimental models were also obtained for horns with impedance surfaces.

  20. Mechanism of the formation for thoracic impedance change.

    PubMed

    Kuang, Ming-Xing; Xiao, Qiu-Jin; Cui, Chao-Ying; Kuang, Nan-Zhen; Hong, Wen-Qin; Hu, Ai-Rong

    2010-03-01

    The purpose of this study is to investigate the mechanism of the formation for thoracic impedance change. On the basis of Ohm's law and the electrical field distribution in the cylindrical volume conductor, the formula about the thoracic impedance change are deduced, and they are demonstrated with the model experiment. The results indicate that the thoracic impedance change caused by single blood vessel is directly proportional to the ratio of the impedance change to the basal impedance of the blood vessel itself, to the length of the blood vessel appearing between the current electrodes, and to the basal impedance between two detective electrodes on the chest surface, while it is inversely proportional to the distance between the blood vessel and the line joining two detective electrodes. The thoracic impedance change caused by multiple blood vessels together is equal to the algebraic addition of all thoracic impedance changes resulting from the individual blood vessels. That is, the impedance changes obey the principle of adding scalars in the measurement of the electrical impedance graph. The present study can offer the theoretical basis for the waveform reconstruction of Impedance cardiography (ICG).

  1. Increases in cerebrovascular impedance in older adults.

    PubMed

    Zhu, Yong-Sheng; Tseng, Benjamin Y; Shibata, Shigeki; Levine, Benjamin D; Zhang, Rong

    2011-08-01

    This study explored a novel method for measuring cerebrovascular impedance to quantify the relationship between pulsatile changes in cerebral blood flow (CBF) and arterial pressure. Arterial pressure in the internal or common carotid artery (applanation tonometry), CBF velocity in the middle cerebral artery (transcranial Doppler), and end-tidal CO(2) (capnography) were measured in six young (28 ± 4 yr) and nine elderly subjects (70 ± 6 yr). Transfer function method was used to estimate cerebrovascular impedance. Under supine resting conditions, CBF velocity was reduced in the elderly despite the fact that they had higher arterial pressure than young subjects. As expected, cerebrovascular resistance index was increased in the elderly. In both young and elderly subjects, impedance modulus was reduced gradually in the frequency range of 0.78-8 Hz. Phase was negative in the range of 0.78-4.3 Hz and fluctuated at high frequencies. Compared with the young, impedance modulus increased by 38% in the elderly in the range of 0.78-2 Hz and by 39% in the range of 2-4 Hz (P < 0.05). Moreover, increases in impedance were correlated with reductions in CBF velocity. Collectively, these findings demonstrate the feasibility of assessing cerebrovascular impedance using the noninvasive method developed in this study. The estimated impedance modulus and phase are similar to those observed in the systemic circulation and other vascular beds. Moreover, increases in impedance in the elderly suggest that arterial stiffening, besides changes in cerebrovascular resistance, contributes to reduction in CBF with age.

  2. Identification of some factors affecting pharmaceutical active compounds (PhACs) removal in real wastewater. Case study of fungal treatment of reverse osmosis concentrate.

    PubMed

    Badia-Fabregat, Marina; Lucas, Daniel; Gros, Meritxell; Rodríguez-Mozaz, Sara; Barceló, Damià; Caminal, Glòria; Vicent, Teresa

    2015-01-01

    Many technologies are being developed for the efficient removal of micropollutants from wastewater and, among them, fungal degradation is one of the possible alternative biological treatments. In this article, some factors that might affect pharmaceutically active compounds (PhACs) removal in a fungal treatment of real wastewater were identified in batch bioreactor treating reverse osmosis concentrate (ROC) from urban wastewater treatment plant (WWTP). We found that degradation of PhACs by Trametes versicolor was enhanced by addition of external nutrients (global removal of 44%). Moreover, our results point out that high aeration might be involved in the increase in the concentration of some PhACs. In fact, conjugation and deconjugation processes (among others) affect the removal assessment of emerging contaminants when working with real concentrations in comparison to experiments with spiked samples. Moreover, factors that could affect the quantification of micropollutants at lab-scale experiments were studied.

  3. Identification of some factors affecting pharmaceutical active compounds (PhACs) removal in real wastewater. Case study of fungal treatment of reverse osmosis concentrate.

    PubMed

    Badia-Fabregat, Marina; Lucas, Daniel; Gros, Meritxell; Rodríguez-Mozaz, Sara; Barceló, Damià; Caminal, Glòria; Vicent, Teresa

    2015-01-01

    Many technologies are being developed for the efficient removal of micropollutants from wastewater and, among them, fungal degradation is one of the possible alternative biological treatments. In this article, some factors that might affect pharmaceutically active compounds (PhACs) removal in a fungal treatment of real wastewater were identified in batch bioreactor treating reverse osmosis concentrate (ROC) from urban wastewater treatment plant (WWTP). We found that degradation of PhACs by Trametes versicolor was enhanced by addition of external nutrients (global removal of 44%). Moreover, our results point out that high aeration might be involved in the increase in the concentration of some PhACs. In fact, conjugation and deconjugation processes (among others) affect the removal assessment of emerging contaminants when working with real concentrations in comparison to experiments with spiked samples. Moreover, factors that could affect the quantification of micropollutants at lab-scale experiments were studied. PMID:25464308

  4. Impedance spectroscopic analysis of composite electrode from activated carbon/conductive materials/ruthenium oxide for supercapacitor applications

    SciTech Connect

    Taer, E.; Awitdrus,; Farma, R.; Deraman, M. Talib, I. A.; Ishak, M. M.; Omar, R.; Dolah, B. N. M.; Basri, N. H.; Othman, M. A. R.; Kanwal, S.

    2015-04-16

    Activated carbon powders (ACP) were produced from the KOH treated pre-carbonized rubber wood sawdust. Different conductive materials (graphite, carbon black and carbon nanotubes (CNTs)) were added with a binder (polivinylidene fluoride (PVDF)) into ACP to improve the supercapacitive performance of the activated carbon (AC) electrodes. Symmetric supercapacitor cells, fabricated using these AC electrodes and 1 molar H{sub 2}SO{sub 4} electrolyte, were analyzed using a standard electrochemical impedance spectroscopy technique. The addition of graphite, carbon black and CNTs was found effective in reducing the cell resistance from 165 to 68, 23 and 49 Ohm respectively, and increasing the specific capacitance of the AC electrodes from 3 to 7, 17, 32 F g{sup −1} respectively. Since the addition of CNTs can produce the highest specific capacitance, CNTs were chosen as a conductive material to produce AC composite electrodes that were added with 2.5 %, 5 % and 10 % (by weight) electro-active material namely ruthenium oxide; PVDF binder and CNTs contents were kept at 5 % by weight in each AC composite produced. The highest specific capacitance of the cells obtained in this study was 86 F g{sup −1}, i.e. for the cell with the resistance of 15 Ohm and composite electrode consists of 5 % ruthenium oxide.

  5. Impedance spectroscopic analysis of composite electrode from activated carbon/conductive materials/ruthenium oxide for supercapacitor applications

    NASA Astrophysics Data System (ADS)

    Taer, E.; Deraman, M.; Talib, I. A.; Awitdrus, Farma, R.; Ishak, M. M.; Omar, R.; Dolah, B. N. M.; Basri, N. H.; Othman, M. A. R.; Kanwal, S.

    2015-04-01

    Activated carbon powders (ACP) were produced from the KOH treated pre-carbonized rubber wood sawdust. Different conductive materials (graphite, carbon black and carbon nanotubes (CNTs)) were added with a binder (polivinylidene fluoride (PVDF)) into ACP to improve the supercapacitive performance of the activated carbon (AC) electrodes. Symmetric supercapacitor cells, fabricated using these AC electrodes and 1 molar H2SO4 electrolyte, were analyzed using a standard electrochemical impedance spectroscopy technique. The addition of graphite, carbon black and CNTs was found effective in reducing the cell resistance from 165 to 68, 23 and 49 Ohm respectively, and increasing the specific capacitance of the AC electrodes from 3 to 7, 17, 32 F g-1 respectively. Since the addition of CNTs can produce the highest specific capacitance, CNTs were chosen as a conductive material to produce AC composite electrodes that were added with 2.5 %, 5 % and 10 % (by weight) electro-active material namely ruthenium oxide; PVDF binder and CNTs contents were kept at 5 % by weight in each AC composite produced. The highest specific capacitance of the cells obtained in this study was 86 F g-1, i.e. for the cell with the resistance of 15 Ohm and composite electrode consists of 5 % ruthenium oxide.

  6. Angiostrongylus cantonensis cathepsin B-like protease (Ac-cathB-1) is involved in host gut penetration.

    PubMed

    Long, Ying; Cao, Binbin; Yu, Liang; Tukayo, Meks; Feng, Chonglv; Wang, Yinan; Luo, Damin

    2015-01-01

    Although the global spread of the emerging zoonosis, human angiostrongyliasis, has attracted increasing attention, understanding of specific gene function has been impeded by the inaccessibility of genetic manipulation of the pathogen nematode causing this disease, Angiostrongylus cantonensis. Many parasitic proteases play key roles in host-parasite interactions, but those of A. cantonensis are always expressed as the inactive form in prokaryotic expression systems, thereby impeding functional studies. Hence, a lentiviral system that drives secreted expression of target genes fused to a Myc-His tag was used to obtain recombinant Ac-cathB-1 with biological activity. Although this class of proteases was always reported to function in nutrition and immune evasion in parasitic nematodes, recombinant Ac-cathB-1 was capable of hydrolysis of fibronectin and laminin as well as the extracellular matrix of IEC-6 monolayer, so that the intercellular space of the IEC-6 monolayer increased 5.15 times as compared to the control, while the shape of the adherent cells partly rounded up. This suggests a probable role for this protease in intestinal epithelial penetration. The inhibition of Ac-cathB-1 enzymatic activity with antiserum partly suppressed larval penetration ability in the isolated intestine. Thus, an effective system for heterologous expression of parasite proteases is presented for studying gene function in A. cantonensis; and Ac-cathB-1 was related to larval penetration ability in the host small intestine.

  7. Angiostrongylus cantonensis cathepsin B-like protease (Ac-cathB-1) is involved in host gut penetration

    PubMed Central

    Long, Ying; Cao, Binbin; Yu, Liang; Tukayo, Meks; Feng, Chonglv; Wang, Yinan; Luo, Damin

    2015-01-01

    Although the global spread of the emerging zoonosis, human angiostrongyliasis, has attracted increasing attention, understanding of specific gene function has been impeded by the inaccessibility of genetic manipulation of the pathogen nematode causing this disease, Angiostrongylus cantonensis. Many parasitic proteases play key roles in host-parasite interactions, but those of A. cantonensis are always expressed as the inactive form in prokaryotic expression systems, thereby impeding functional studies. Hence, a lentiviral system that drives secreted expression of target genes fused to a Myc-His tag was used to obtain recombinant Ac-cathB-1 with biological activity. Although this class of proteases was always reported to function in nutrition and immune evasion in parasitic nematodes, recombinant Ac-cathB-1 was capable of hydrolysis of fibronectin and laminin as well as the extracellular matrix of IEC-6 monolayer, so that the intercellular space of the IEC-6 monolayer increased 5.15 times as compared to the control, while the shape of the adherent cells partly rounded up. This suggests a probable role for this protease in intestinal epithelial penetration. The inhibition of Ac-cathB-1 enzymatic activity with antiserum partly suppressed larval penetration ability in the isolated intestine. Thus, an effective system for heterologous expression of parasite proteases is presented for studying gene function in A. cantonensis; and Ac-cathB-1 was related to larval penetration ability in the host small intestine. PMID:26682577

  8. Angiostrongylus cantonensis cathepsin B-like protease (Ac-cathB-1) is involved in host gut penetration.

    PubMed

    Long, Ying; Cao, Binbin; Yu, Liang; Tukayo, Meks; Feng, Chonglv; Wang, Yinan; Luo, Damin

    2015-01-01

    Although the global spread of the emerging zoonosis, human angiostrongyliasis, has attracted increasing attention, understanding of specific gene function has been impeded by the inaccessibility of genetic manipulation of the pathogen nematode causing this disease, Angiostrongylus cantonensis. Many parasitic proteases play key roles in host-parasite interactions, but those of A. cantonensis are always expressed as the inactive form in prokaryotic expression systems, thereby impeding functional studies. Hence, a lentiviral system that drives secreted expression of target genes fused to a Myc-His tag was used to obtain recombinant Ac-cathB-1 with biological activity. Although this class of proteases was always reported to function in nutrition and immune evasion in parasitic nematodes, recombinant Ac-cathB-1 was capable of hydrolysis of fibronectin and laminin as well as the extracellular matrix of IEC-6 monolayer, so that the intercellular space of the IEC-6 monolayer increased 5.15 times as compared to the control, while the shape of the adherent cells partly rounded up. This suggests a probable role for this protease in intestinal epithelial penetration. The inhibition of Ac-cathB-1 enzymatic activity with antiserum partly suppressed larval penetration ability in the isolated intestine. Thus, an effective system for heterologous expression of parasite proteases is presented for studying gene function in A. cantonensis; and Ac-cathB-1 was related to larval penetration ability in the host small intestine. PMID:26682577

  9. Acoustic ground impedance meter

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J. (Inventor)

    1984-01-01

    A method and apparatus are presented for measuring the acoustic impedance of a surface in which the surface is used to enclose one end of the chamber of a Helmholz resonator. Acoustic waves are generated in the neck of the resonator by a piston driven by a variable speed motor through a cam assembly. The acoustic waves are measured in the chamber and the frequency of the generated acoustic waves is measured by an optical device. These measurements are used to compute the compliance and conductance of the chamber and surface combined. The same procedure is followed with a calibration plate having infinite acoustic impedance enclosing the chamber of the resonator to compute the compliance and conductance of the chamber alone. Then by subtracting, the compliance and conductance for the surface is obtained.

  10. Superconducting active impedance converter

    SciTech Connect

    Ginley, D.S.; Hietala, V.M.; Martens, J.S.

    1992-12-31

    This invention is comprised of a transimpedance amplifier for use with high temperature superconducting, other superconducting, and conventional semiconductor allows for appropriate signal amplification and impedance matching to processing electronics. The amplifier incorporates the superconducting flux flow transistor into a differential amplifier configuration which allows for operation over a wide temperature range, and is characterized by high gain, relatively low noise, and response times less than 200 picoseconds over at least a 10--80 K temperature range. The invention is particularly useful when a signal derived from either far-IR focal plane detectors or from Josephson junctions is to be processed by higher signal/higher impedance electronics, such as conventional semiconductor technology.

  11. Impedance Measurement Box

    ScienceCinema

    Christophersen, Jon

    2016-07-12

    Energy storage devices, primarily batteries, are now more important to consumers, industries and the military. With increasing technical complexity and higher user expectations, there is also a demand for highly accurate state-of-health battery assessment techniques. IMB incorporates patented, proprietary, and tested capabilities using control software and hardware that can be part of an embedded monitoring system. IMB directly measures the wideband impedance spectrum in seconds during battery operation with no significant impact on service life. It also can be applied to batteries prior to installation, confirming health before entering active service, as well as during regular maintenance. For more information about this project, visit http://www.inl.gov/rd100/2011/impedance-measurement-box/

  12. Impedance Measurement Box

    SciTech Connect

    Christophersen, Jon

    2011-01-01

    Energy storage devices, primarily batteries, are now more important to consumers, industries and the military. With increasing technical complexity and higher user expectations, there is also a demand for highly accurate state-of-health battery assessment techniques. IMB incorporates patented, proprietary, and tested capabilities using control software and hardware that can be part of an embedded monitoring system. IMB directly measures the wideband impedance spectrum in seconds during battery operation with no significant impact on service life. It also can be applied to batteries prior to installation, confirming health before entering active service, as well as during regular maintenance. For more information about this project, visit http://www.inl.gov/rd100/2011/impedance-measurement-box/

  13. Impedance Measurement Box

    SciTech Connect

    Morrison, William

    2014-11-20

    The IMB 50V software provides functionality for design of impedance measurement tests or sequences of tests, execution of these tests or sequences, processing measured responses and displaying and saving of the results. The software consists of a Graphical User Interface that allows configuration of measurement parameters and test sequencing, a core engine that controls test sequencing, execution of measurements, processing and storage of results and a hardware/software data acquisition interface with the IMB hardware system.

  14. Gynecologic electrical impedance tomograph

    NASA Astrophysics Data System (ADS)

    Korjenevsky, A.; Cherepenin, V.; Trokhanova, O.; Tuykin, T.

    2010-04-01

    Electrical impedance tomography extends to the new and new areas of the medical diagnostics: lungs, breast, prostate, etc. The feedback from the doctors who use our breast EIT diagnostic system has induced us to develop the 3D electrical impedance imaging device for diagnostics of the cervix of the uterus - gynecologic impedance tomograph (GIT). The device uses the same measuring approach as the breast imaging system: 2D flat array of the electrodes arranged on the probe with handle is placed against the body. Each of the 32 electrodes of the array is connected in turn to the current source while the rest electrodes acquire the potentials on the surface. The current flows through the electrode of the array and returns through the remote electrode placed on the patient's limb. The voltages are measured relative to another remote electrode. The 3D backprojection along equipotential surfaces is used to reconstruct conductivity distribution up to approximately 1 cm in depth. Small number of electrodes enables us to implement real time imaging with a few frames per sec. rate. The device is under initial testing and evaluation of the imaging capabilities and suitability of usage.

  15. Acoustic ground impedance meter

    NASA Technical Reports Server (NTRS)

    Zuckerwar, A. J.

    1981-01-01

    A compact, portable instrument was developed to measure the acoustic impedance of the ground, or other surfaces, by direct pressure-volume velocity measurement. A Helmholz resonator, constructed of heavy-walled stainless steel but open at the bottom, is positioned over the surface having the unknown impedance. The sound source, a cam-driven piston of known stroke and thus known volume velocity, is located in the neck of the resonator. The cam speed is a variable up to a maximum 3600 rpm. The sound pressure at the test surface is measured by means of a microphone flush-mounted in the wall of the chamber. An optical monitor of the piston displacement permits measurement of the phase angle between the volume velocity and the sound pressure, from which the real and imaginary parts of the impedance can be evaluated. Measurements using a 5-lobed cam can be made up to 300 Hz. Detailed design criteria and results on a soil sample are presented.

  16. Impedance studies of the cell Ag/AgI/Ag beta alumina/AgI/Ag. Technical report No. 15, August 1987-August 1988

    SciTech Connect

    Breiter, M.W.; Drstak, H.; Maly-Schreiber, M.

    1988-07-01

    The construction of the cell Ag/AgI/Ag beta alumina/AgI/Ag is described. The impedance of this cell was measured between .001 and 10000 Hz at temperatures between 20 and 550 C. At temperatures below 100 C the cell impedance is determined to a large extent by the bulk resistance of the AgI layer and to a smaller extent by the impedance of the interface Ag/Agi. At temperatures between 160 and 350 C the impedance is controlled by the bulk resistance of the Ag beta alumina and an impedance due to contact problems between Ag and AgI. The bulk resistance of the beta' alumina becomes predominant between 350 and 550 C. A hindrance due to the transfer of silver ions from AgI to Ag beta' alumina was not observable in the whole temperature range.

  17. Binding studies of L-tryptophan to human serum albumin with nanogold-structured sensor by piezoelectric quartz crystal impedance analysis.

    PubMed

    Long, Yumei; Yao, Shouzhuo; Chen, Jinhua

    2011-12-01

    Nanogold-modified sensor was constructed and applied to study the binding of L-tryptophan to human serum albumin (HSA) in situ by piezoelectric quartz crystal impedance (PQCI) analysis. It was interesting that the as-prepared nanogold modified sensor was more sensitive and biocompatible than bare gold electrode. The frequency changes due to protein adsorption on the nanogold-modified sensor might be described as a sum of two exponential functions and detailed explanation was given. Additionally, the kinetics of the binding process was also investigated. The binding constant (K) and the number of binding site (n) for the binding process without competitor are fitted to be 1.07 x 10(4) (mol l(-1))(-1) s(-1) and 1.13, respectively, and 2.24 x 10(3) (mol l-(1))(-1) s(-1) and 1.18, respectively for the binding process with competitor.

  18. Comparative study of structural, optical and impedance measurements on V{sub 2}O{sub 5} and V-Ce mixed oxide thin films

    SciTech Connect

    Malini, D. Rachel; Sanjeeviraja, C.

    2015-06-24

    Vanadium pentoxide (V{sub 2}O{sub 5}) and Vanadium-Cerium mixed oxide thin films at different molar ratios of V{sub 2}O{sub 5} and CeO{sub 2} have been deposited at 200 W rf power by rf planar magnetron sputtering in pure argon atmosphere. The structural and optical properties were studied by taking X-ray diffraction and transmittance and absorption spectra respectively. The amorphous thin films show an increase in transmittance and optical bandgap with increase in CeO{sub 2} content in as-prepared thin films. The impedance measurements for as-deposited thin films show an increase in electrical conductivity with increase in CeO{sub 2} material.

  19. Towards a graphene-based quantum impedance standard

    SciTech Connect

    Kalmbach, C.-C.; Schurr, J. Ahlers, F. J.; Müller, A.; Novikov, S.; Lebedeva, N.; Satrapinski, A.

    2014-08-18

    Precision measurements of the quantum Hall resistance with alternating current (ac) in the kHz range were performed on epitaxial graphene in order to assess its suitability as a quantum standard of impedance. The quantum Hall plateaus measured with alternating current were found to be flat within one part in 10{sup 7}. This is much better than for plain GaAs quantum Hall devices and shows that the magnetic-flux-dependent capacitive ac losses of the graphene device are less critical. The observed frequency dependence of about −8 × 10{sup −8}/kHz is comparable in absolute value to the positive frequency dependence of plain GaAs devices, but the negative sign is attributed to stray capacitances which we believe can be minimized by a careful design of the graphene device. Further improvements thus may lead to a simpler and more user-friendly quantum standard for both resistance and impedance.

  20. Module Twelve: Series AC Resistive-Reactive Circuits; Basic Electricity and Electronics Individualized Learning System.

    ERIC Educational Resources Information Center

    Bureau of Naval Personnel, Washington, DC.

    The module covers series circuits which contain both resistive and reactive components and methods of solving these circuits for current, voltage, impedance, and phase angle. The module is divided into six lessons: voltage and impedance in AC (alternating current) series circuits, vector computations, rectangular and polar notation, variational…

  1. Investigation of electrical properties of Mn doped tin oxide nanoparticles using impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Azam, Ameer; Ahmed, Arham S.; Chaman, M.; Naqvi, A. H.

    2010-11-01

    Manganese doped tin oxide nanoparticles with manganese content varying from 0 to 15 mol % were synthesized using sol-gel method. The structural and compositional analysis was carried out using x-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive x-ray analysis (EDAX). Dielectric and impedance spectroscopy was carried out at room temperature to explore the electrical properties of Mn doped SnO2. XRD analysis indicated the formation of single phase rutile type tetragonal structure of all the samples. The crystallite size was observed to vary from 16.2 to 7.1 nm as the Mn content was increased. The XRD, SEM, and EDAX results corroborated the successful doping of Mn in the SnO2 matrix. Complex impedance analysis was used to distinguish the grain and grain boundary contributions to the system, suggesting the dominance of grain boundary resistance in the doped samples. The dielectric constant ɛ', dielectric loss tan δ and ac conductivity σac were studied as a function of frequency and composition and the behavior has been explained on the basis of Maxwell-Wagner interfacial model. All the dielectric parameters were found to decrease with the increase in doping concentration. Moreover, it has been observed that the dielectric loss approaches to zero in case of high dopant concentration (9%, 15%) at high frequencies.

  2. -383 A/C tumor necrosis factor receptor 1 polymorphism and ankylosing spondylitis in Mexicans: a preliminary study.

    PubMed

    Corona-Sanchez, Esther Guadalupe; Muñoz-Valle, José Francisco; Gonzalez-Lopez, Laura; Sanchez-Hernandez, Julia Dolores; Vazquez-Del Mercado, Monica; Ontiveros-Mercado, Heriberto; Huerta, Miguel; Trujillo, Xochitl; Rocha-Muñoz, Alberto Daniel; Celis, Alfredo; Ortega-Flores, Ricardo; Gamez-Nava, Jorge Ivan

    2012-08-01

    The objective of this study was to evaluate the differences in allele and genotype frequencies of -383 tumor necrosis factor receptor 1 (TNFR1) polymorphism between ankylosing spondylitis (AS) and controls. Mexican Mestizos with AS were matched by gender, age, and ethnicity with healthy controls and compared in allele and genotype frequencies of the -383 TNFR1 polymorphism. Polymorphisms were genotyped using PCR-RFLP. The AA genotype occurred at a higher frequency in the AS group (92%) compared with controls (79%, P = 0.03). A allele was increased in AS (96% vs. 88%, P = 0.015) and was associated with genetic susceptibility for AS (odds ratio = 3.48, 95% CI = 1.23-10.61). This preliminary study is the first assessing the association of the -383 A/C TNFR1 polymorphism with AS, although it has the limitation of a small sample size. These data are of interest for the genetic epidemiology of AS in the Mexican population, requiring further investigation in other countries.

  3. A modelling study to inform specification and optimal electrode placement for imaging of neuronal depolarization during visual evoked responses by electrical and magnetic detection impedance tomography.

    PubMed

    Gilad, O; Horesh, L; Holder, D S

    2009-06-01

    Electrical impedance tomography (EIT) has the potential to achieve non-invasive functional imaging of fast neuronal activity in the human brain due to opening of ion channels during neuronal depolarization. Local changes of resistance in the cerebral cortex are about 1%, but the size and location of changes recorded on the scalp are unknown. The purpose of this work was to develop an anatomically realistic finite element model of the adult human head and use it to predict the amplitude and topography of changes on the scalp, and so inform specification for an in vivo measuring system. A detailed anatomically realistic finite element (FE) model of the head was produced from high resolution MRI. Simulations were performed for impedance changes in the visual cortex during evoked activity with recording of scalp potentials by electrodes or magnetic flux density by magnetoencephalography (MEG) in response to current injected with electrodes. The predicted changes were validated by recordings in saline filled tanks and with boundary voltages measured on the human scalp. Peak changes were 1.03 +/- 0.75 microV (0.0039 +/- 0.0034%) and 27 +/- 13 fT (0.2 +/- 0.5%) respectively, which yielded an estimated peak signal-to-noise ratio of about 4 for in vivo averaging over 10 min and 1 mA current injection. The largest scalp changes were over the occipital cortex. This modelling suggests, for the first time, that reproducible changes could be recorded on the scalp in vivo in single channels, although a higher SNR would be desirable for accurate image production. The findings suggest that an in vivo study is warranted in order to determine signal size but methods to improve SNR, such as prolonged averaging or other signal processing may be needed for accurate image production.

  4. A comparison of measurements of lean body mass derived by bioelectrical impedance, skinfold thickness and total body potassium. A study in obese and non-obese normal subjects.

    PubMed

    Fulcher, G R; Farrer, M; Walker, M; Rodham, D; Clayton, B; Alberti, K M

    1991-05-01

    The measurement of body composition is an important part of metabolic and epidemiological research, but most currently available methods are complex and expensive. We have, therefore, compared measurements of fat mass (FM) and lean body mass (LBM), obtained using a commercially available bioelectrical impedance monitor (The Holtain Body Composition Monitor) (IMP), and by measuring skinfold thickness (SFT), with values obtained by measuring total body potassium (TBK). Twenty subjects, 10 with a body mass index (BMI) less than 30 (kg m-2), (non-obese) and 10 with BMI greater than or equal to 30 (obese) took part in the study. There was a strongly significant linear relationship between LBM calculated from TBK and that calculated from impedance (IMP), in both non-obese and obese groups analysed separately (non-obese: r = 0.92; p less than 0.001 and obese: r = 0.92; p less than 0.001) and together (all: r = 0.89; p less than 0.001). LBM calculated from TBK was strongly linearly correlated with values derived from SFT for non-obese (r = 0.91; p less than 0.001) but not for obese subjects. Mean values of LBM of non-obese subjects derived by each method were not significantly different (TBK: 51.3 +/- 10.40 kg; IMP: 53.18 +/- 10.37 kg; SFT: 48.87 +/- 9.48 kg), but significant differences existed when the subjects were obese (TBK: 51.86 +/- 9.65 kg; IMP: 58.69 +/- 8.55 kg; SFT: 67.61 +/- 8.14 kg; p less than 0.01).(ABSTRACT TRUNCATED AT 250 WORDS)

  5. A modelling study to inform specification and optimal electrode placement for imaging of neuronal depolarization during visual evoked responses by electrical and magnetic detection impedance tomography.

    PubMed

    Gilad, O; Horesh, L; Holder, D S

    2009-06-01

    Electrical impedance tomography (EIT) has the potential to achieve non-invasive functional imaging of fast neuronal activity in the human brain due to opening of ion channels during neuronal depolarization. Local changes of resistance in the cerebral cortex are about 1%, but the size and location of changes recorded on the scalp are unknown. The purpose of this work was to develop an anatomically realistic finite element model of the adult human head and use it to predict the amplitude and topography of changes on the scalp, and so inform specification for an in vivo measuring system. A detailed anatomically realistic finite element (FE) model of the head was produced from high resolution MRI. Simulations were performed for impedance changes in the visual cortex during evoked activity with recording of scalp potentials by electrodes or magnetic flux density by magnetoencephalography (MEG) in response to current injected with electrodes. The predicted changes were validated by recordings in saline filled tanks and with boundary voltages measured on the human scalp. Peak changes were 1.03 +/- 0.75 microV (0.0039 +/- 0.0034%) and 27 +/- 13 fT (0.2 +/- 0.5%) respectively, which yielded an estimated peak signal-to-noise ratio of about 4 for in vivo averaging over 10 min and 1 mA current injection. The largest scalp changes were over the occipital cortex. This modelling suggests, for the first time, that reproducible changes could be recorded on the scalp in vivo in single channels, although a higher SNR would be desirable for accurate image production. The findings suggest that an in vivo study is warranted in order to determine signal size but methods to improve SNR, such as prolonged averaging or other signal processing may be needed for accurate image production. PMID:19491442

  6. Studies of structural, optical, dielectric relaxation and ac conductivity of different alkylbenzenesulfonic acids doped polypyrrole nanofibers

    NASA Astrophysics Data System (ADS)

    Hazarika, J.; Kumar, A.

    2016-01-01

    Polypyrrole (PPy) nanofibers doped with alkylbenzenesulfonic acids (ABSA) have been synthesized using interfacial polymerization method. HRTEM studies confirm the formation of PPy nanofibers with average diameter ranging from 13 nm to 25 nm. Broad X-ray diffraction peak in 2 θ range 20-23.46° reveals amorphous structure of PPy nanofibers. The ordering or crystallinity of polymer chains increases, while their interplanar spacing (d) and interchain separation (R) decreases for short alkyl chain ABSA doped PPy nanofibers. FTIR studies reveal that short alkyl chain ABSA doped PPy nanofibers show higher value of "effective conjugation length". PPy nanofibers doped with short alkyl chain ABSA dopant exhibit smaller optical band gap. TGA studies show enhanced thermal stability of short alkyl chain ABSA doped PPy nanofibers. Decrease in dielectric permittivity ε ‧ (ω) with increasing frequency suggests presence of electrode polarization effects. Linear decrease in dielectric loss ε ″ (ω) with increasing frequency suggests dominant effect of dc conductivity process. Low value of non-exponential exponent β (<1) reveals non-Debye relaxation of charge carriers. Scaling of imaginary modulus (M ″) reveals that the charge carriers follow the same relaxation mechanism. Moreover, the charge carriers in PPy nanofibers follow the correlated barrier hopping (CBH) transport mechanism.

  7. Conjugation, immunoreactivity, and immunogenicity of calix[4]arenes; model study to potential calix[4]arene-based Ac3+ chelators.

    PubMed

    Grote Gansey, M H; de Haan, A S; Bos, E S; Verboom, W; Reinhoudt, D N

    1999-01-01

    For the development of calix[4]arene-based radiotherapeutic agents, the conjugation to biomolecules and immunogenicity in mice of potential 225Ac3+-chelating calix[4]arenes were studied. A calix[4]arene triethyl ester isothiocyanate and a bis(calix[4]arene) hexacarboxylic acid, containing a masked thiol functionality, were used in conjugation experiments to a mouse monoclonal antibody and serum albumins. All characterization techniques indicate that only the calix[4]arene carboxylic acid is successfully conjugated to the biomolecules. The immunoreactivity of the conjugates is not impaired when up to 6 equiv of calixarene are bound to the monoclonal antibody. Animal tests indicated that the immunogenicity toward the calix[4]arene is strongly influenced by the nature of the carrier, the dosage, and the injection method. No immune response occurred when a homologous carrier was used or when a heterologous carrier was applied at a dosage of 10 microg per immunization via intravenous injection. Under all other conditions, the presence of antibodies directed against the calix[4]arene was demonstrated. Thus, for the application in radioimmunotherapy, the conjugation of a calix[4]arene to a humanized antibody will probably not lead to an immune response, and the immunoreactivity will not be disturbed.

  8. Study on preferred crystal orientations of Mg-Zr-O composite protective layer in AC-PDP

    NASA Astrophysics Data System (ADS)

    Bingang, G.; Chunliang, L.; Zhongxiao, S.; Liu, L.; Yufeng, F.; Xing, X.; Duowang, F.

    2006-11-01

    In order to study the preferred crystal orientations of Mg-Zr-O composite protective layers in PDP, Mg-Zr-O composite protective layers were deposited by Electron-beam Evaporator using (MgO+ZrO{2}) powder mixture as evaporation source material. X-ray diffractometer (XRD) was used to determine preferred crystal orientations of Mg-Zr-O composite protective layers, surface morphologies of films were analyzed by FESEM and voltage characteristics were examined in a testing macroscopic discharge cell of AC-PDP. On the basis of experimental analysis, the influence of oxide addition and deposition conditions on preferred orientations of Mg-Zr-O composite protective layers were investigated. The results showed that the preferred orientations of Mg-Zr-O films were determined by lattice distortion of MgO crystal. The deposition conditions have great effects on the preferred orientations of Mg-Zr-O films. The preferred orientations affect voltage characteristics through affecting surface morphology of Mg-Zr-O films. A small amount of Zr solution in MgO can decrease firing voltage compared with using pure MgO film. Firing voltage is closely related with the [ ZrO{2}/(MgO+ZrO{2})] ratio of evaporation source materials.

  9. Impedance group summary

    NASA Astrophysics Data System (ADS)

    Blaskiewicz, M.; Dooling, J.; Dyachkov, M.; Fedotov, A.; Gluckstern, R.; Hahn, H.; Huang, H.; Kurennoy, S.; Linnecar, T.; Shaposhnikova, E.; Stupakov, G.; Toyama, T.; Wang, J. G.; Weng, W. T.; Zhang, S. Y.; Zotter, B.

    1999-12-01

    The impedance working group was charged to reply to the following 8 questions relevant to the design of high-intensity proton machines such as the SNS or the FNAL driver. These questions were first discussed one by one in the whole group, then each ne of them assigned to one member to summarize. On the lst morning these contributions were publicly read, re-discussed and re-written where required—hence they are not the opinion of a particular person, but rather the averaged opinion of all members of the working group. (AIP)

  10. Highly sensitive pseudo-differential ac-nanocalorimeter for the study of the glass transition

    SciTech Connect

    Laarraj, Mohcine; Adhiri, Rahma; Moussetad, Mohamed; Ouaskit, Said; Guttin, Christophe; Richard, Jacques; Garden, Jean-Luc

    2015-11-15

    We present a nanocalorimeter designed for the measurement of the dynamic heat capacity of thin films. The microfabricated sensor, the thermal conditioning of the sensor, as well as the highly stable and low noise electronic chain allow measurements of the real and imaginary parts of the complex specific heat with a resolution Δ C/C of about 10{sup −5}. The performances of this quasi-differential nanocalorimeter were tested on a model of polymeric glass-former, the polyvinyl acetate (PVAc). The high stability and low noise of the device are essential for accurate studies on non-equilibrium slow relaxing systems such as glasses.

  11. Potential applications of a small high-surface-area platinum electrode as an implanted impedance biosensor or recording electrode

    NASA Astrophysics Data System (ADS)

    Duan, Yvonne Y.; Millard, Rodney E.; Tykocinski, Michael; Lui, Xuguang; Clark, Graeme M.; Cowan, Robert S. C.

    2001-03-01

    A small Platinum (Pt) electrode (geometric area: ~0.43 mm2) was treated in an electrochemical etching process, to produce a highly porous columnar thin layer (~600 nm) on the surface of the electrode. The modified Pt electrode (Pt-p) showed similar electrical properties to a platinum-black electrode but with high mechanical integrity. Previous studies of chronic stimulation had also shown good biocompatibility and surface stability over several months implantation. This paper discusses the potential applications of the modified electrode as an implanted bio-sensor: (1) as a recording electrode compared to an untreated Pt electrode. (2) as a probe in detecting electrical characteristics of living biological material adjacent to the electrode in vivo, which may correlate to inflammation or trauma repair. Results of electrochemical impedance spectroscopy (EIS) revealed much lower electrode interface polarisation impedance, reduced overall electrode impedance, and a largely constant impedance above 100 Hz for the Pt-p electrode compared with untreated Pt electrodes. This provides a platform for recording biological events with low noise interference. Results of A.C. impedance spectroscopy of the high surface area electrode only reflect changes in the surrounding biological environment in the frequency range (1 k Hz to 100 k Hz), interference from electrode polarisation impedance can be neglected. The results imply that the surface-modified electrode is a good candidate for application to implantable biosensors for detecting bio-electric events. The modification procedure and its high surface area concept could have application to a smart MEMS device or microelectrode.

  12. Creating dynamic equivalent PV circuit models with impedance spectroscopy for arc-fault modeling.

    SciTech Connect

    Johnson, Jay Dean; Kuszmaul, Scott S.; Strauch, Jason E.; Schoenwald, David Alan

    2011-06-01

    Article 690.11 in the 2011 National Electrical Code{reg_sign} (NEC{reg_sign}) requires new photovoltaic (PV) systems on or penetrating a building to include a listed arc fault protection device. Currently there is little experimental or empirical research into the behavior of the arcing frequencies through PV components despite the potential for modules and other PV components to filter or attenuate arcing signatures that could render the arc detector ineffective. To model AC arcing signal propagation along PV strings, the well-studied DC diode models were found to inadequately capture the behavior of high frequency arcing signals. Instead dynamic equivalent circuit models of PV modules were required to describe the impedance for alternating currents in modules. The nonlinearities present in PV cells resulting from irradiance, temperature, frequency, and bias voltage variations make modeling these systems challenging. Linearized dynamic equivalent circuits were created for multiple PV module manufacturers and module technologies. The equivalent resistances and capacitances for the modules were determined using impedance spectroscopy with no bias voltage and no irradiance. The equivalent circuit model was employed to evaluate modules having irradiance conditions that could not be measured directly with the instrumentation. Although there was a wide range of circuit component values, the complex impedance model does not predict filtering of arc fault frequencies in PV strings for any irradiance level. Experimental results with no irradiance agree with the model and show nearly no attenuation for 1 Hz to 100 kHz input frequencies.

  13. Dissection of the Mechanical Impedance Components of the Outer Hair Cell Using a Chloride-Channel Blocker

    NASA Astrophysics Data System (ADS)

    Harasztosi, Csaba; Gummer, Anthony W.

    2011-11-01

    The voltage-dependent chloride-channel blocker anthracene-9-carboxylic acid (9AC) has been found to reduce the imaginary but not the real part of the mechanical impedance of the organ of Corti, suggesting that the effective stiffness of outer hair cells (OHCs) is reduced by 9AC. To examine whether 9AC interacts directly with the motor protein prestin to reduce the membrane component of the impedance, the patch-clamp technique in whole-cell configuration was used to measure the nonlinear capacitance (NLC) of isolated OHCs and, as control, prestin-transfected human embryonic kidney 293 (HEK293) cells. Extracellular application of 9AC significantly reduced the NLC of both OHCs and HEK293 cells. Intracellular 9AC did not influence the blocking effect of the extracellular applied drug. These results suggest that 9AC interacts directly with prestin, reducing the effective stiffness of the motor, and that the interaction is extracellular.

  14. Development of a computer algorithm for the analysis of variable-frequency AC drives: Case studies included

    NASA Technical Reports Server (NTRS)

    Kankam, M. David; Benjamin, Owen

    1991-01-01

    The development of computer software for performance prediction and analysis of voltage-fed, variable-frequency AC drives for space power applications is discussed. The AC drives discussed include the pulse width modulated inverter (PWMI), a six-step inverter and the pulse density modulated inverter (PDMI), each individually connected to a wound-rotor induction motor. Various d-q transformation models of the induction motor are incorporated for user-selection of the most applicable model for the intended purpose. Simulation results of selected AC drives correlate satisfactorily with published results. Future additions to the algorithm are indicated. These improvements should enhance the applicability of the computer program to the design and analysis of space power systems.

  15. Dynamic electrochemical impedance spectroscopy reconstructed from continuous impedance measurement of single frequency during charging/discharging

    NASA Astrophysics Data System (ADS)

    Huang, Jun; Li, Zhe; Zhang, Jianbo

    2015-01-01

    In this study, a novel implementation of dynamic electrochemical impedance spectroscopy (DEIS) is proposed. The method first measures the impedance continuously at a single frequency during one charging/discharging cycle, then repeats the measurement at a number of other selected frequencies. The impedance spectrum at a specific SOC is obtained by interpolating and collecting the impedance at all of the selected frequencies. The charge transfer resistance, Rct, from the DEIS is smaller than that from the steady EIS in a wide state-of-charge (SOC) range from 0.4 to 1.0, the Rct during charging is generally smaller than that during discharging for the battery chemistry used in this study.

  16. Relationship between Body mass index (BMI) and body fat percentage, estimated by bioelectrical impedance, in a group of Sri Lankan adults: a cross sectional study

    PubMed Central

    2013-01-01

    Background Body Mass Index (BMI) is used as a useful population-level measure of overweight and obesity. It is used as the same for both sexes and for all ages of adults. The relationship between BMI and body fat percentage (BF %) has been studied in various ethnic groups to estimate the capacity of BMI to predict adiposity. We aimed to study the BMI–BF% relationship, in a group of South Asian adults who have a different body composition compared to presently studied ethnic groups. We examined the influence of age, gender in this relationship and assessed its’ linearity or curvilinearity. Methods A cross sectional study was conducted, where adults of 18–83 years were grouped into young (18–39 years) middle aged (40–59 years) and elderly (>60 years). BF% was estimated from bioelectrical impedance analysis. Pearsons’ correlation coefficient(r) was calculated to see the relationship between BMI-BF% in the different age groups. Multiple regression analysis was performed to determine the effect of age and gender in the relationship and polynomial regression was carried out to see its’ linearity. The relationships between age-BMI, age-BF % were separately assessed. Results Out of 1114 participants, 49.1% were males. The study sample represented a wide range of BMI values (14.8-41.1 kg/m2,Mean 23.8 ± 4.2 kg/m2). A significant positive correlation was observed between BMI-BF%, in males (r =0.75, p < 0.01; SEE = 4.17) and in females (r = 0.82, p < 0.01; SEE = 3.54) of all ages. Effect of age and gender in the BMI-BF% relationship was significant (p < 0.001); with more effect from gender. Regression line found to be curvilinear in nature at higher BMI values where females (p < 0.000) having a better fit of the curve compared to males (p < 0.05). In both genders, with increase of age, BMI seemed to increase in curvilinear fashion, whereas BF% increased in a linear fashion. Conclusions BMI strongly correlate with BF

  17. Scheme for rapid adjustment of network impedance

    DOEpatents

    Vithayathil, John J.

    1991-01-01

    A static controlled reactance device is inserted in series with an AC electric power transmission line to adjust its transfer impedance. An inductor (reactor) is serially connected with two back-to-back connected thyristors which control the conduction period and hence the effective reactance of the inductor. Additional reactive elements are provided in parallel with the thyristor controlled reactor to filter harmonics and to obtain required range of variable reactance. Alternatively, the static controlled reactance device discussed above may be connected to the secondary winding of a series transformer having its primary winding connected in series to the transmission line. In a three phase transmission system, the controlled reactance device may be connected in delta configuration on the secondary side of the series transformer to eliminate triplen harmonics.

  18. Dielectric spectroscopy studies and ac electrical conductivity on (AuZn)/TiO2/p-GaAs(110) MIS structures

    NASA Astrophysics Data System (ADS)

    Şafak Asar, Yasemin; Asar, Tarık; Altındal, Şemsettin; Özçelik, Süleyman

    2015-09-01

    In this study, we investigated temperature and voltage dependence of dielectric properties and ac electrical conductivity (σac) of (AuZn)/TiO2/p-GaAs(110) metal-insulator-semiconductor structures in the temperature range of 80-290 K using the capacitance-voltage ? and conductance-voltage ? measurements at 1 MHz. The intersection/crossing behaviour of C-V plots at sufficiently high forward biases and the increase in σac with increasing temperature was attributed to the lack of sufficient number of enough free charge carriers at low temperatures. The values of the dielectric constant (ε‧), dielectric loss (ε″), loss tangent ?, ac electrical conductivity (σac), the real and imaginary parts of electric modulus (?) were found to be strong functions of temperature and applied bias voltage. The Cole-Cole plots between ? have shown only one semicircle for each temperature. This indicates one of the relaxation processes was suppressed and this can be attributed to the surface polarization effect. On the other hand, ? plot has a peak for each temperature. The ? plots revealed two linear regions with different slopes for sufficiently high forward biases (0.0, 0.5, and 1.0 V) which correspond to low (80-200 K) and moderate/intermediate (230-290 K) temperatures. Thus, the values of activation energy (Ea) were obtained from the slope of these Arrhenius plots for two linear regions as 87.3 and 3.4 meV, respectively, at 1.0 V. On the other hand, Mott plots have only one linear region except for 260 and 290 K and Mott parameters were determined from these plots at 0.0, 0.5 and 1.0 V.

  19. Ionospheric effects to antenna impedance

    NASA Technical Reports Server (NTRS)

    Bethke, K. H.

    1986-01-01

    The reciprocity between high power satellite antennas and the surrounding plasma are examined. The relevant plasma states for antenna impedance calculations are presented and plasma models, and hydrodynamic and kinetic theory, are discussed. A theory from which a variation in antenna impedance with regard to the radiated power can be calculated for a frequency range well above the plasma resonance frequency is give. The theory can include photo and secondary emission effects in antenna impedance calculations.

  20. [Studies on the low skin impedance points and the feature of its distribution along the channels by microcomputer. I. Observation on the reliability of the measurement].

    PubMed

    Hu, X; Wu, B; Xu, J; Hao, J

    1990-01-01

    According to the requirement of channel research, a system for the measurement of skin impedance had been designed and a series of experiments to check the reliability of this system had also been done. The facts demonstrated that the pressure exerted by the exploring electrode, the duration of switch-on as well as the number of times of repeated measurements all showed no conspicuous influences on the skin impedance. The results are stable and reliable. Moreover, the measurement and data processing are controlled by microcomputer. Thus, the method of measurement of skin impedance along the channels has been developed to a higher level. Under the conditions of our experiment, the impedance of the low skin impedance points (LSIPs) are about 108k omega, which are quite low than that of the non-LSIPs around them. The difference between the two is highly significant. Both the impedance of LSIPs and non-LSIPs are stable, without marked variation. These results provide the prerequisites indispensable for the further observation on the feature of the distribution of LSIPs.

  1. Impedance analysis of the PEP-II vacuum chamber

    SciTech Connect

    Ng, C.K.; Weiland, T.

    1995-05-01

    The PEP-II high energy ring (HER) vacuum chamber consists of a copper tube with periodically spaced pumping slots. The impedance of the vacuum chamber due to the slots is analyzed. Both narrow-band and broadband impedances are considered as well as longitudinal and transverse components thereof. It is found that although the broad-band impedance is tolerable, the narrow-band impedance may exceed the instability limit given by the natural damping with no feedback system on. Traveling wave modes in the chamber are the major source of this high value narrow-band impedance. We also study the dependences of the impedance on the slot length and the geometrical cross section.

  2. Transverse impedance measurement in RHIC and the AGS

    SciTech Connect

    Biancacci, Nicolo; Blaskiewicz, M.; Dutheil, Y.; Liu, C.; Mernick, M.; Minty, M.; White, S. M.

    2014-05-12

    The RHIC luminosity upgrade program aims for an increase of the polarized proton luminosity by a factor 2. To achieve this goal a significant increase in the beam intensity is foreseen. The beam coupling impedance could therefore represent a source of detrimental effects for beam quality and stability at high bunch intensities. For this reason it is essential to quantify the accelerator impedance budget and the major impedance sources, and possibly cure them. In this MD note we summarize the results of the 2013 transverse impedance measurements in the AGS and RHIC. The studies have been performed measuring the tune shift as a function of bunch intensity and deriving the total accelerator machine transverse impedance. For RHIC, we could obtain first promising results of impedance localization measurements as well.

  3. Transverse beam coupling impedance of the CERN Proton Synchrotron

    NASA Astrophysics Data System (ADS)

    Persichelli, S.; Migliorati, M.; Biancacci, N.; Gilardoni, S.; Metral, E.; Salvant, B.

    2016-04-01

    Beam coupling impedance is a fundamental parameter to characterize the electromagnetic interaction of a particle beam with the surrounding environment. Synchrotron machine performances are critically affected by instabilities and collective effects triggered by beam coupling impedance. In particular, transverse beam coupling impedance is expected to impact beam dynamics of the CERN Proton Synchrotron (PS), since a significant increase in beam intensity is foreseen within the framework of the LHC Injectors Upgrade (LIU) project. In this paper we describe the study of the transverse beam coupling impedance of the PS, taking into account the main sources of geometrical impedance and the contribution of indirect space charge at different energies. The total machine impedance budget, determined from beam-based dedicated machine measurement sessions, is also discussed and compared with the theoretical model.

  4. Optically stimulated differential impedance spectroscopy

    DOEpatents

    Maxey, Lonnie C; Parks, II, James E; Lewis, Sr., Samuel A; Partridge, Jr., William P

    2014-02-18

    Methods and apparatuses for evaluating a material are described. Embodiments typically involve use of an impedance measurement sensor to measure the impedance of a sample of the material under at least two different states of illumination. The states of illumination may include (a) substantially no optical stimulation, (b) substantial optical stimulation, (c) optical stimulation at a first wavelength of light, (d) optical stimulation at a second wavelength of light, (e) a first level of light intensity, and (f) a second level of light intensity. Typically a difference in impedance between the impedance of the sample at the two states of illumination is measured to determine a characteristic of the material.

  5. IMPEDANCE OF FINITE LENGTH RESISTOR

    SciTech Connect

    KRINSKY, S.; PODOBEDOV, B.; GLUCKSTERN, R.L.

    2005-05-15

    We determine the impedance of a cylindrical metal tube (resistor) of radius a, length g, and conductivity {sigma}, attached at each end to perfect conductors of semi-infinite length. Our main interest is in the asymptotic behavior of the impedance at high frequency, k >> 1/a. In the equilibrium regime, , the impedance per unit length is accurately described by the well-known result for an infinite length tube with conductivity {sigma}. In the transient regime, ka{sup 2} >> g, we derive analytic expressions for the impedance and wakefield.

  6. Effects of Liner Geometry on Acoustic Impedance

    NASA Technical Reports Server (NTRS)

    Jones, Michael G.; Tracy, Maureen B.; Watson, Willie R.; Parrott, Tony L.

    2002-01-01

    Current aircraft engine nacelles typically contain acoustic liners consisting of perforated sheets bonded onto honeycomb cavities. Numerous models have been developed to predict the acoustic impedance of these liners in the presence of grazing flow, and to use that information with aeroacoustic propagation codes to assess nacelle liner noise suppression. Recent efforts have provided advances in impedance education methodologies that offer more accurate determinations of acoustic liner properties in the presence of grazing flow. The current report provides the results of a parametric study, in which a finite element method was used to assess the effects of variations of the following geometric parameters on liner impedance, with and without the presence of grazing flow: percent open area, sheet thickness, sheet thickness-to-hole diameter ratio and cavity depth. Normal incidence acoustic impedances were determined for eight acoustic liners, consisting of punched aluminum facesheets bonded to hexcell honeycomb cavities. Similar liners were tested in the NASA Langley Research Center grazing incidence tube to determine their response in the presence of grazing flow. The resultant data provide a quantitative assessment of the effects of these perforate, single-layer liner parameters on the acoustic impedance of the liner.

  7. Experimental study of two-phase fluid flow in two different porosity types of sandstone by P-wave velocity and electrical Impedance measurement

    NASA Astrophysics Data System (ADS)

    Honda, H.; Mitani, Y.; Kitamura, K.; Ikemi, H.; Takaki, S.

    2015-12-01

    Carbon dioxide (CO2) capture and storage (CCS) is recently expected as the promising method to reduce greenhouse gas emissions. It is important to investigate CO2 behavior in the reservoir, to evaluate the safety and to account the stored CO2 volume. In this study, experimental investigation is conducted to discuss the relationships between injected fluid speed (Flow rate: FR) or capillary number (Ca) and non-wetting fluid flow by compressional wave velocity (Vp) and electrical impedance (Z). In the experiment, N2 and supercritical CO2 were injected into the two sandstones with different porosity (φ), Berea sandstone (φ: 18 %), and Ainoura sandstone (φ: 11.9 %). The dimension of the rock specimens is cored cylinder with a 35 mm diameter and 70 mm height. Experimental conditions are nearly same as the reservoir of deep underground (Confining pressure:15MPa, 40℃). Initial conditions of the specimen are brine (0.1wt%-KCl) saturated. Four piezo-electrical transducers (PZTs) are set on the each surface of the top, middle, lower of the specimen to monitor the CO2 bahavior by Vp. To measuring Z, we use for electrodes method with Ag-AgCl electrodes. Four electrodes are wounded around specimen on the both sides of PZTs. We measured the changes of these parameters with injecting N2, injected fluid speed (FR), the differential pore pressure (DP), N2 saturation (SN2), P-wave velocity (Vp) and electrical impedance (Z), respectively. We also estimated the Ca from measured FR. From these experimental results, there are no obvious Vp changes with increasing Ca, while Z measurement indicates clear and continuous increment. In regards to Vp, Vp reduced at the small FR (0.1 to 0.2 ml/min). As the Ca increases, Vp doesn't indicate large reduction. On the other hand, Z is more sensitive to change the fluid saturation than Vp. It is well-known that both of Vp and Z are the function of fluid saturation. Though, these experimental results are not consistent with previous studies. In

  8. Electrical transport properties of CoMn0.2-xGaxFe1.8O4 ferrites using complex impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Tsay, Chien-Yie; Lin, Yi-Hsiang; Wang, Yao-Ming; Chang, Horng-Yi; Lei, Chien-Ming; Jen, Shien-Uang

    2016-05-01

    In this study, we report the influence of Ga content on the microstructural, magnetic, and AC impedance properties of Co-based ferrites with compositions of CoMn0.2-xGaxFe1.8O4 (x=0, 0.1, and 0.2) prepared by the solid-state reaction method. Experimental results showed that the as-prepared Co-based ferrites had a single-phase spinel structure; the Curie temperature of Co-based ferrites decreased with increasing Ga content. All ferrite samples exhibited a typical hysteresis behavior with good values of saturation magnetization at room temperature. The electrical properties of Co-based ferrites were investigated using complex impedance spectroscopy analysis in the frequency range of 100 kHz-50 MHz at temperatures of 150 to 250 oC. The impedance analysis revealed that the magnitudes of the real part (Z') and the imaginary part (Z") of complex impedance decreased with increasing temperature. Only one semicircle was observed in each complex impedance plane plot, which revealed that the contribution to conductivity was from the grain boundaries. It was found that the relaxation time for the grain boundary (τgb) also decreased with increasing temperature. The values of resistance for the grain boundary (Rgb) significantly increased with increasing Ga content, which indicated that the incorporation of Ga into Co-based ferrites enhanced the electrical resistivity.

  9. Monolithically compatible impedance measurement

    DOEpatents

    Ericson, Milton Nance; Holcomb, David Eugene

    2002-01-01

    A monolithic sensor includes a reference channel and at least one sensing channel. Each sensing channel has an oscillator and a counter driven by the oscillator. The reference channel and the at least one sensing channel being formed integrally with a substrate and intimately nested with one another on the substrate. Thus, the oscillator and the counter have matched component values and temperature coefficients. A frequency determining component of the sensing oscillator is formed integrally with the substrate and has an impedance parameter which varies with an environmental parameter to be measured by the sensor. A gating control is responsive to an output signal generated by the reference channel, for terminating counting in the at least one sensing channel at an output count, whereby the output count is indicative of the environmental parameter, and successive ones of the output counts are indicative of changes in the environmental parameter.

  10. In vivo impedance spectroscopy of deep brain stimulation electrodes

    NASA Astrophysics Data System (ADS)

    Lempka, Scott F.; Miocinovic, Svjetlana; Johnson, Matthew D.; Vitek, Jerrold L.; McIntyre, Cameron C.

    2009-08-01

    Deep brain stimulation (DBS) represents a powerful clinical technology, but a systematic characterization of the electrical interactions between the electrode and the brain is lacking. The goal of this study was to examine the in vivo changes in the DBS electrode impedance that occur after implantation and during clinically relevant stimulation. Clinical DBS devices typically apply high-frequency voltage-controlled stimulation, and as a result, the injected current is directly regulated by the impedance of the electrode-tissue interface. We monitored the impedance of scaled-down clinical DBS electrodes implanted in the thalamus and subthalamic nucleus of a rhesus macaque using electrode impedance spectroscopy (EIS) measurements ranging from 0.5 Hz to 10 kHz. To further characterize our measurements, equivalent circuit models of the electrode-tissue interface were used to quantify the role of various interface components in producing the observed electrode impedance. Following implantation, the DBS electrode impedance increased and a semicircular arc was observed in the high-frequency range of the EIS measurements, commonly referred to as the tissue component of the impedance. Clinically relevant stimulation produced a rapid decrease in electrode impedance with extensive changes in the tissue component. These post-operative and stimulation-induced changes in impedance could play an important role in the observed functional effects of voltage-controlled DBS and should be considered during clinical stimulation parameter selection and chronic animal research studies.

  11. Electrical Impedance Tomography of Electrolysis

    PubMed Central

    Meir, Arie; Rubinsky, Boris

    2015-01-01

    The primary goal of this study is to explore the hypothesis that changes in pH during electrolysis can be detected with Electrical Impedance Tomography (EIT). The study has relevance to real time control of minimally invasive surgery with electrolytic ablation. To investigate the hypothesis, we compare EIT reconstructed images to optical images acquired using pH-sensitive dyes embedded in a physiological saline agar gel phantom treated with electrolysis. We further demonstrate the biological relevance of our work using a bacterial E.Coli model, grown on the phantom. The results demonstrate the ability of EIT to image pH changes in a physiological saline phantom and show that these changes correlate with cell death in the E.coli model. The results are promising, and invite further experimental explorations. PMID:26039686

  12. Experimental and theoretical study of AC electrical conduction mechanisms of Organic-inorganic hybrid compound Bis (4-acetylanilinium) tetrachlorocadmiate (II)

    NASA Astrophysics Data System (ADS)

    Jellibi, A.; Chaabane, I.; Guidara, K.

    2016-06-01

    A new organic-inorganic bis (4-acetylaniline) tetrachlorocadmate [C8H10NO]2[CdCl4] can be obtained by slow evaporation at room temperature and characterized by X-ray powder diffraction. It crystallized in an orthorhombic system (Cmca space group). The material electrical properties were characterized by impedance spectroscopy technique in the frequency range from 209 Hz-5 MHz and temperature 413 to 460 K. Besides, the impedance plots show semicircle arcs at different temperatures and an electrical equivalent circuit has been proposed to interpret the impedance results. The circuits consist of the parallel combination of a resistance (R), capacitance (C) and fractal capacitance (CPE). The variation of the exponent s as a function of temperature suggested that the conduction mechanism in Bis (4-acetylanilinium) tetrachlorocadmiate compound is governed by two processes which can be ascribed to a hopping transport mechanism: correlated barrier hopping (CBH) model below 443 K and the small polaron tunneling (SPT) model above 443 K.

  13. Smokeless tobacco consumption impedes metabolic, cellular, apoptotic and systemic stress pattern: A study on Government employees in Kolkata, India

    PubMed Central

    Biswas, Sushobhan; Manna, Krishnendu; Das, Ujjal; Khan, Amitava; Pradhan, Anirban; Sengupta, Aaveri; Bose, Surajit; Ghosh, Saurabh; Dey, Sanjit

    2015-01-01

    Smokeless tobacco (SLT) remains a threat amongst a large population across the globe and particularly in India. The oral use of tobacco has been implicated to cause physiological stress leading to extreme toxicological challenge. The study included 47 SLT-users and 44 non-users providing a spectrum of pathophysiological, clinico-biochemical, antioxidant parameters, cell cycle progression study of PBMC and morphological changes of red blood cells (RBC). The expressions of p53, p21, Bax, Bcl-2, IL-6, TNF- α, Cox-2, iNOS were analyzed from thirteen representative SLT-users and twelve non-users. Difference in CRP, random glucose, serum cholesterol, TG, HLDL-C, LDL-C, VLDL-C, neutrophil count, monocyte count, ESR, SOD (PBMC) and TBARS (RBC membrane) were found to be statistically significant (p < 0.05) between the studied groups. The current study confers crucial insight into SLT mediated effects on systemic toxicity and stress. This has challenged the metabolic condition leading to a rise in the inflammatory status, increased apoptosis and RBC membrane damage. The above findings were substantiated with metabolic, clinical and biochemical parameters. This is possibly the first ever in-depth report and remains an invaluable document on the fatal effects of SLT. PMID:26669667

  14. [Cardiac output monitoring by impedance cardiography in cardiac surgery].

    PubMed

    Shimizu, H; Seki, S; Mizuguchi, A; Tsuchida, H; Watanabe, H; Namiki, A

    1990-04-01

    The cardiac output monitoring by impedance cardiography, NCCOM3, was evaluated in adult patients (n = 12) who were subjected to coronary artery bypass grafting. Values of cardiac output measured by impedance cardiography were compared to those by the thermodilution method. Changes of base impedance level used as an index of thoracic fluid volume were also investigated before and after cardiopulmonary bypass (CPB). Correlation coefficient (r) of the values obtained by thermodilution with impedance cardiography was 0.79 and the mean difference was 1.29 +/- 16.9 (SD)% during induction of anesthesia. During the operation, r was 0.83 and the mean difference was -14.6 +/- 18.7%. The measurement by impedance cardiography could be carried out through the operation except when electro-cautery was used. Base impedance level before CPB was significantly lower as compared with that after CPB. There was a negative correlation between the base impedance level and central venous pressure (CVP). No patients showed any signs suggesting lung edema and all the values of CVP, pulmonary artery pressure and blood gas analysis were within normal ranges. From the result of this study, it was concluded that cardiac output monitoring by impedance cardiography was useful in cardiac surgery, but further detailed examinations will be necessary on the relationship between the numerical values of base impedance and the clinical state of the patients. PMID:2362347

  15. Impedance in School Screening Programs.

    ERIC Educational Resources Information Center

    Robarts, John T.

    1985-01-01

    This paper examines the controversy over use of impedance screening in public schools to identify students with hearing problems, including otitis media, a common ear condition in infants and young children. It cites research that questions the value of pure tone screening as a single test and raises critics' objections to the use of impedance,…

  16. Ultra-wideband impedance sensor

    DOEpatents

    McEwan, T.E.

    1999-03-16

    The ultra-wideband impedance sensor (UWBZ sensor, or Z-sensor) is implemented in differential and single-ended configurations. The differential UWBZ sensor employs a sub-nanosecond impulse to determine the balance of an impedance bridge. The bridge is configured as a differential sample-and-hold circuit that has a reference impedance side and an unknown impedance side. The unknown impedance side includes a short transmission line whose impedance is a function of the near proximity of objects. The single-ended UWBZ sensor eliminates the reference side of the bridge and is formed of a sample and hold circuit having a transmission line whose impedance is a function of the near proximity of objects. The sensing range of the transmission line is bounded by the two-way travel time of the impulse, thereby eliminating spurious Doppler modes from large distant objects that would occur in a microwave CW impedance bridge. Thus, the UWBZ sensor is a range-gated proximity sensor. The Z-sensor senses the near proximity of various materials such as metal, plastic, wood, petroleum products, and living tissue. It is much like a capacitance sensor, yet it is impervious to moisture. One broad application area is the general replacement of magnetic sensors, particularly where nonferrous materials need to be sensed. Another broad application area is sensing full/empty levels in tanks, vats and silos, e.g., a full/empty switch in water or petroleum tanks. 2 figs.

  17. Ultra-wideband impedance sensor

    DOEpatents

    McEwan, Thomas E.

    1999-01-01

    The ultra-wideband impedance sensor (UWBZ sensor, or Z-sensor) is implemented in differential and single-ended configurations. The differential UWBZ sensor employs a sub-nanosecond impulse to determine the balance of an impedance bridge. The bridge is configured as a differential sample-and-hold circuit that has a reference impedance side and an unknown impedance side. The unknown impedance side includes a short transmission line whose impedance is a function of the near proximity of objects. The single-ended UWBZ sensor eliminates the reference side of the bridge and is formed of a sample and hold circuit having a transmission line whose impedance is a function of the near proximity of objects. The sensing range of the transmission line is bounded by the two-way travel time of the impulse, thereby eliminating spurious Doppler modes from large distant objects that would occur in a microwave CW impedance bridge. Thus, the UWBZ sensor is a range-gated proximity sensor. The Z-sensor senses the near proximity of various materials such as metal, plastic, wood, petroleum products, and living tissue. It is much like a capacitance sensor, yet it is impervious to moisture. One broad application area is the general replacement of magnetic sensors, particularly where nonferrous materials need to be sensed. Another broad application area is sensing full/empty levels in tanks, vats and silos, e.g., a full/empty switch in water or petroleum tanks.

  18. A time-based potential step analysis of electrochemical impedance incorporating a constant phase element: a study of commercially pure titanium in phosphate buffered saline.

    PubMed

    Ehrensberger, Mark T; Gilbert, Jeremy L

    2010-05-01

    The measurement of electrochemical impedance is a valuable tool to assess the electrochemical environment that exists at the surface of metallic biomaterials. This article describes the development and validation of a new technique, potential step impedance analysis (PSIA), to assess the electrochemical impedance of materials whose interface with solution can be modeled as a simplified Randles circuit that is modified with a constant phase element. PSIA is based upon applying a step change in voltage to a working electrode and analyzing the subsequent current transient response in a combined time and frequency domain technique. The solution resistance, polarization resistance, and interfacial capacitance are found directly in the time domain. The experimental current transient is numerically transformed to the frequency domain to determine the constant phase exponent, alpha. This combined time and frequency approach was tested using current transients generated from computer simulations, from resistor-capacitor breadboard circuits, and from commercially pure titanium samples immersed in phosphate buffered saline and polarized at -800 mV or +1000 mV versus Ag/AgCl. It was shown that PSIA calculates equivalent admittance and impedance behavior over this range of potentials when compared to standard electrochemical impedance spectroscopy. This current transient approach characterizes the frequency response of the system without the need for expensive frequency response analyzers or software.

  19. Impedance spectroscopy study of SiO2-Li2O:Nd2O3 glasses

    SciTech Connect

    Pereia, R.; Gozzo, C B; Guedes, I.; Boatner, Lynn A; Terezo, A J; Costa, M M

    2014-01-01

    In the present study, neodymium-doped lithium silicate glasses have been prepared by the conventional melt-quenching technique. The dielectric properties, electric modulus and electrical conductivity of SiO2-Li2O (SiLi-0Nd) and SiO2-Li2O:Nd2O3 (SiLi-1.35Nd) have been studied from 1 Hz to 1 MHz in the 333 423 K temperature range. At a given temperature and frequency, we observe that the resistivity increases while the conductivity accordingly decreases when neodymium ions are added to the glass matrix. The activation energy of two distinct regions was evaluated from the ln( dc)=f(1/T) plot and was found to be E1(T<363K)=0.61(0.66)eV and E2(T>363K)=1.26(1.09)eV for SiLi-0Nd (SiLi-1,35Nd). The dielectric constant ( Re) decreases while the dielectric loss (tan ( )) increases under Nd2O3 doping. We also observe that for both glasses, Re and tan ( ) tend to increase with increasing temperature and decrease with increasing frequency.

  20. Effect of the magnetic material on AC losses in HTS conductors in AC magnetic field carrying AC transport current

    NASA Astrophysics Data System (ADS)

    Wan, Xing-Xing; Huang, Chen-Guang; Yong, Hua-Dong; Zhou, You-He

    2015-11-01

    This paper presents an investigation on the AC losses in several typical superconducting composite conductors using the H-formulation model. A single superconducting strip with ferromagnetic substrate or cores and a stack of coated conductors with ferromagnetic substrates are studied. We consider all the coated conductors carrying AC transport currents and simultaneously exposed to perpendicular AC magnetic fields. The influences of the amplitude, frequency, phase difference and ferromagnetic materials on the AC losses are investigated. The results show that the magnetization losses of single strip and stacked strips have similar characteristics. The ferromagnetic substrate can increase the magnetization loss at low magnetic field, and decrease the loss at high magnetic field. The ferromagnetic substrate can obviously increase the transport loss in stacked strips. The trends of total AC losses of single strip and stacked strips are similar when they are carrying current or exposed to a perpendicular magnetic field. The effect of the frequency on the total AC losses of single strip is related to the amplitude of magnetic field. The AC losses decrease with increasing frequency in low magnetic field region while increase in high magnetic field region. As the phase difference changes, there is a periodic variation for the AC losses. Moreover, when the strip is under only the transport current and magnetic field, the ferromagnetic cores will increase the AC losses for large transport current or field.

  1. ACS: ALMA Common Software

    NASA Astrophysics Data System (ADS)

    Chiozzi, Gianluca; Šekoranja, Matej

    2013-02-01

    ALMA Common Software (ACS) provides a software infrastructure common to all ALMA partners and consists of a documented collection of common patterns and components which implement those patterns. The heart of ACS is based on a distributed Component-Container model, with ACS Components implemented as CORBA objects in any of the supported programming languages. ACS provides common CORBA-based services such as logging, error and alarm management, configuration database and lifecycle management. Although designed for ALMA, ACS can and is being used in other control systems and distributed software projects, since it implements proven design patterns using state of the art, reliable technology. It also allows, through the use of well-known standard constructs and components, that other team members whom are not authors of ACS easily understand the architecture of software modules, making maintenance affordable even on a very large project.

  2. Impedance analysis of porous carbon electrodes to predict rate capability of electric double-layer capacitors

    NASA Astrophysics Data System (ADS)

    Yoo, Hyun Deog; Jang, Jong Hyun; Ryu, Ji Heon; Park, Yuwon; Oh, Seung M.

    2014-12-01

    Electrochemical impedance analysis is performed to predict the rate capability of two commercial activated carbon electrodes (RP20 and MSP20) for electric double-layer capacitor. To this end, ac impedance data are fitted with an equivalent circuit that comprises ohmic resistance and impedance of intra-particle pores. To characterize the latter, ionic accessibility into intra-particle pores is profiled by using the fitted impedance parameters, and the profiles are transformed into utilizable capacitance plots as a function of charge-discharge rate. The rate capability that is predicted from the impedance analysis is well-matched with that observed from a charge-discharge rate test. It is found that rate capability is determined by ionic accessibility as well as ohmic voltage drop. A lower value in ionic accessibility for MSP20 is attributed to smaller pore diameter, longer length, and higher degree of complexity in pore structure.

  3. A 90-day subchronic feeding study of genetically modified maize expressing Cry1Ac-M protein in Sprague-Dawley rats.

    PubMed

    Liu, Pengfei; He, Xiaoyun; Chen, Delong; Luo, Yunbo; Cao, Sishuo; Song, Huan; Liu, Ting; Huang, Kunlun; Xu, Wentao

    2012-09-01

    The cry1Ac-M gene, coding one of Bacillus thuringiensis (Bt) crystal proteins, was introduced into maize H99 × Hi IIB genome to produce insect-resistant GM maize BT-38. The food safety assessment of the BT-38 maize was conducted in Sprague-Dawley rats by a 90-days feeding study. We incorporated maize grains from BT-38 and H99 × Hi IIB into rodent diets at three concentrations (12.5%, 25%, 50%) and administered to Sprague-Dawley rats (n=10/sex/group) for 90 days. A commercialized rodent diet was fed to an additional group as control group. Body weight, feed consumption and toxicological response variables were measured, and gross as well as microscopic pathology were examined. Moreover, detection of residual Cry1Ac-M protein in the serum of rats fed with GM maize was conducted. No death or adverse effects were observed in the current feeding study. No adverse differences in the values of the response variables were observed between rats that consumed diets containing GM maize BT-38 and non-GM maize H99 × Hi IIB. No detectable Cry1Ac-M protein was found in the serum of rats after feeding diets containing GM maize for 3 months. The results demonstrated that BT-38 maize is as safe as conventional non-GM maize.

  4. AC conductivity and its scaling behavior in MgO-Li2O-B2O3-Bi2O3 glasses

    NASA Astrophysics Data System (ADS)

    Purnima, M.; Bale, Shashidhar; Samee, M. A.; Ahmmad, Shaik Kareem; Rahman, Syed

    2013-02-01

    In the present work, the compositional dependence of density, refractive index and glass transition temperature of xMgO-(25-x)Li2O-50B2O3-25Bi2O3 glasses is studied. Impedance spectroscopy technique is employed on these samples and the data are analyzed using Cole-Cole type impedance response function. The AC conductivity behavior of the present glasses has been investigated in the frequency range from 100 Hz to 1 MHz and as a function of temperature the measured AC data are analyzed using the Jonscher’s universal power law to explain the observed dispersive behavior of the electrical conductivity. The temperature and composition dependence scaling behavior in the AC conductivity are satisfactorily explained by scaling the AC conductivity σ‧(ω) by hopping frequency ωp. The frequency response of dielectric constant ɛ‧ and dielectric loss tanδ as a function of temperature were studied. The tanδ peak shifts to higher frequency with increasing temperature, indicating dipolar relaxation character of dielectric loss in the present glasses.

  5. The Impedance Response of Semiconductors: An Electrochemical Engineering Perspective.

    ERIC Educational Resources Information Center

    Orazem, Mark E.

    1990-01-01

    Shows that the principles learned in the study of mass transport, thermodynamics, and kinetics associated with electrochemical systems can be applied to the transport and reaction processes taking place within a semiconductor. Describes impedance techniques and provides several graphs illustrating impedance data for diverse circuit systems. (YP)

  6. Twelve years evolution of skin as seen by electrical impedance

    NASA Astrophysics Data System (ADS)

    Nicander, Ingrid; Emtestam, Lennart; Åberg, Peter; Ollmar, Stig

    2010-04-01

    Twelve years ago we reported an electrical impedance baseline study related to age, sex and body locations. The results showed significant differences between different anatomical locations and ages. In this study, the same participants were recalled to explore how the skin had evolved at the individual level over time. A total of 50 subjects, divided into an older and a younger group, were recalled for measurements of electrical impedance at eight anatomical locations. Readings were taken with an electrical impedance spectrometer. Information was extracted from the impedance spectra using indices based on magnitude and phase at two frequencies as in the earlier study. All included body sites had undergone alterations over time, and the size of the changes varied at different locations. The results also showed that changes in the younger group were different over time compared with the older group. In conclusion: Electrical impedance can be used to monitor skin evolution over time and baseline characteristics differ between various locations.

  7. AcsA-AcsB: The core of the cellulose synthase complex from Gluconacetobacter hansenii ATCC23769.

    PubMed

    McManus, John B; Deng, Ying; Nagachar, Nivedita; Kao, Teh-hui; Tien, Ming

    2016-01-01

    The gram-negative bacterium, Gluconacetobacter hansenii, produces cellulose of exceptionally high crystallinity in comparison to the cellulose of higher plants. This bacterial cellulose is synthesized and extruded into the extracellular medium by the cellulose synthase complex (CSC). The catalytic component of this complex is encoded by the gene AcsAB. However, several other genes are known to encode proteins critical to cellulose synthesis and are likely components of the bacterial CSC. We have purified an active heterodimer AcsA-AcsB from G. hansenii ATCC23769 to homogeneity by two different methods. With the purified protein, we have determined how it is post-translationally processed, forming the active heterodimer AcsA-AcsB. Additionally, we have performed steady-state kinetic studies on the AcsA-AcsB complex. Finally through mutagenesis studies, we have explored the roles of the postulated CSC proteins AcsC, AcsD, and CcpAx. PMID:26672449

  8. AcsA-AcsB: The core of the cellulose synthase complex from Gluconacetobacter hansenii ATCC23769.

    PubMed

    McManus, John B; Deng, Ying; Nagachar, Nivedita; Kao, Teh-hui; Tien, Ming

    2016-01-01

    The gram-negative bacterium, Gluconacetobacter hansenii, produces cellulose of exceptionally high crystallinity in comparison to the cellulose of higher plants. This bacterial cellulose is synthesized and extruded into the extracellular medium by the cellulose synthase complex (CSC). The catalytic component of this complex is encoded by the gene AcsAB. However, several other genes are known to encode proteins critical to cellulose synthesis and are likely components of the bacterial CSC. We have purified an active heterodimer AcsA-AcsB from G. hansenii ATCC23769 to homogeneity by two different methods. With the purified protein, we have determined how it is post-translationally processed, forming the active heterodimer AcsA-AcsB. Additionally, we have performed steady-state kinetic studies on the AcsA-AcsB complex. Finally through mutagenesis studies, we have explored the roles of the postulated CSC proteins AcsC, AcsD, and CcpAx.

  9. Impedance-estimation methods, modeling methods, articles of manufacture, impedance-modeling devices, and estimated-impedance monitoring systems

    DOEpatents

    Richardson, John G.

    2009-11-17

    An impedance estimation method includes measuring three or more impedances of an object having a periphery using three or more probes coupled to the periphery. The three or more impedance measurements are made at a first frequency. Three or more additional impedance measurements of the object are made using the three or more probes. The three or more additional impedance measurements are made at a second frequency different from the first frequency. An impedance of the object at a point within the periphery is estimated based on the impedance measurements and the additional impedance measurements.

  10. I/O impedance controller

    DOEpatents

    Ruesch, Rodney; Jenkins, Philip N.; Ma, Nan

    2004-03-09

    There is disclosed apparatus and apparatus for impedance control to provide for controlling the impedance of a communication circuit using an all-digital impedance control circuit wherein one or more control bits are used to tune the output impedance. In one example embodiment, the impedance control circuit is fabricated using circuit components found in a standard macro library of a computer aided design system. According to another example embodiment, there is provided a control for an output driver on an integrated circuit ("IC") device to provide for forming a resistor divider network with the output driver and a resistor off the IC device so that the divider network produces an output voltage, comparing the output voltage of the divider network with a reference voltage, and adjusting the output impedance of the output driver to attempt to match the output voltage of the divider network and the reference voltage. Also disclosed is over-sampling the divider network voltage, storing the results of the over sampling, repeating the over-sampling and storing, averaging the results of multiple over sampling operations, controlling the impedance with a plurality of bits forming a word, and updating the value of the word by only one least significant bit at a time.

  11. Impedance and dielectric properties of mercury cuprate at nonsuperconducting state

    NASA Astrophysics Data System (ADS)

    Özdemir, Z. Güven; Çataltepe, Ö. Aslan; Onbaşlı, Ü.

    2015-10-01

    In this paper, impedance and dielectric properties of nonsuperconducting state of the mercury-based cuprate have been investigated by impedance measurements within the frequency interval of 10 Hz-10 MHz for the first time. The dielectric loss factor (tgδ) and ac conductivity (σac) parameters have also been calculated for non-superconducting state. According to impedance spectroscopy analysis, the equivalent circuit of the mercury cuprate system manifests itself as a semicircle in the Nyquist plot that corresponds to parallel connected resistance-capacitance circuit. The oscillation frequency of the circuit has been determined as approximately 45 kHz which coincides with the low frequency radio waves. Moreover, it has been revealed that the mercury-based cuprate investigated has high dielectric constants and hence it may be utilized in microelectronic industry such as capacitors, memory devices etc., at room temperature. In addition, negative capacitance (NC) effect has been observed for the mercury cuprate regardless of the operating temperatures at nonsuperconducting state. Referring to dispersions in dielectric properties, the main contribution to dielectric response of the system has been suggested as dipolar and interfacial polarization mechanisms.

  12. Sources and effects of electrode impedance during deep brain stimulation

    PubMed Central

    Butson, Christopher R.; Maks, Christopher B.; McIntyre, Cameron C.

    2013-01-01

    Objective Clinical impedance measurements for deep brain stimulation (DBS) electrodes in human patients are normally in the range 500–1500 Ω. DBS devices utilize voltage-controlled stimulation; therefore, the current delivered to the tissue is inversely proportional to the impedance. The goals of this study were to evaluate the effects of various electrical properties of the tissue medium and electrode-tissue interface on the impedance and to determine the impact of clinically relevant impedance variability on the volume of tissue activated (VTA) during DBS. Methods Axisymmetric finite-element models (FEM) of the DBS system were constructed with explicit representation of encapsulation layers around the electrode and implanted pulse generator. Impedance was calculated by dividing the stimulation voltage by the integrated current density along the active electrode contact. The models utilized a Fourier FEM solver that accounted for the capacitive components of the electrode-tissue interface during voltage-controlled stimulation. The resulting time- and space-dependent voltage waveforms generated in the tissue medium were superimposed onto cable model axons to calculate the VTA. Results The primary determinants of electrode impedance were the thickness and conductivity of the encapsulation layer around the electrode contact and the conductivity of the bulk tissue medium. The difference in the VTA between our low (790 Ω) and high (1244 Ω) impedance models with typical DBS settings (−3 V, 90 μs, 130 Hz pulse train) was 121 mm3, representing a 52% volume reduction. Conclusions Electrode impedance has a substantial effect on the VTA and accurate representation of electrode impedance should be an explicit component of computational models of voltage-controlled DBS. Significance Impedance is often used to identify broken leads (for values >2000 Ω) or short circuits in the hardware (for values <50 Ω); however, clinical impedance values also represent an important

  13. The impedance spectroscopic study and dielectric relaxation in A(Ni1/3Ta2/3)O3 [A=Ba, Ca and Sr

    NASA Astrophysics Data System (ADS)

    Hoque, Md M.; Dutta, A.; Kumar, S.; Sinha, T. P.

    2012-09-01

    We present the results of impedance spectroscopic study with its analytical interpretations in the framework of electric modulus formalism for Barium Nickel Tantalate Ba(Ni1/3Ta2/3)O3 (BNT), Calcium Nickel Tantalate Ca(Ni1/3Ta2/3)O3 (CNT) and Strontium Nickel Tantalate Sr(Ni1/3Ta2/3)O3 (SNT) synthesized by the solid-state reaction technique. The results of powder X-ray diffraction study reveal that BNT and SNT crystallize in cubic structure with lattice parameter a=4.07 Å and 3.98 Å respectively, whereas CNT crystallizes in monoclinic structure having lattice parameters, a=5.71 Å, b=13.45 Å and c=5.47 Å with β=118.3°. The logarithmic angular frequency dependence of the real part of complex dielectric permittivity and loss tangent as a function of temperature indicate significant dielectric relaxation in the samples, which have been explained by the Debye theory. The frequency dependence of the loss peak and the imaginary part of electrical modulus are found to obey the Arrhenius law. The relaxation mechanism of these samples is modeled by the Cole-Cole equation. This confirms that the polarization mechanism in BNT, CNT and SNT is due to the bulk effect arising in semiconductive grains. The scaling behavior of imaginary part of electric modulus M″ suggests that the relaxation describes the same mechanism at various temperatures but relaxation frequency is strongly temperature dependent. The normalized peak positions of tan δ/tan δm and M″/M″m versus log ω for BNT, CNT and SNT do not overlap completely and are very close to each other. These indicate the presence of both long-range and localized relaxation. Due to their high dielectric constant and low loss tangent, these materials may find several technological applications such as in capacitors, resonators, filters and integrated circuits.

  14. In Vivo Imaging of Twist Drill Drainage for Subdural Hematoma: A Clinical Feasibility Study on Electrical Impedance Tomography for Measuring Intracranial Bleeding in Humans

    PubMed Central

    Xu, Canhua; Yang, Bin; Li, Jianbo; Fu, Feng; Fei, Zhou; Dong, Xiuzhen

    2013-01-01

    Intracranial bleeding is one of the most severe medical emergencies in neurosurgery. Early detection or diagnosis would largely reduce the rate of disability and mortality, and improve the prognosis of the patients. Electrical Impedance Tomography (EIT) can non-invasively image the internal resistivity distribution within a human body using a ring of external electrodes, and is thus a promising technique to promptly detect the occurrence of intracranial bleedings because blood differs from other brain tissues in resistivity. However, so far there is no experimental study that has determined whether the intracranial resistivity changes in humans could be repeatedly detected and imaged by EIT. Hence, we for the first time attempt to clinically validate this by in vivo imaging the influx and efflux of irrigating fluid (5% dextrose in water, D5W) during the twist-drill drainage operation for the patients with subdural hematoma (SDH). In this study, six patients (four male, two female) with subacute or chronic SDH received the surgical operation in order to evacuate the hematoma around subdural region, and EIT measurements were performed simultaneously on each patient’s head. The results showed that the resistivity significantly increased on the corresponding position of EIT images during the influx of D5W and gradually decreased back to baseline during the efflux. In the quantitative analysis, the average resistivity values demonstrated the similar results and had highly linear correlation (R2 = 0.93±0.06) with the injected D5W volumes, as well as the area of the resistivity gain(R2 = 0.94±0.05). In conclusion, it was clinically validated that intracranial resistivity changes in humans were detectable and quantifiable by the EIT method. After further technical improvements, EIT has the great potential of being a routine neuroimaging tool for early detection of intracranial bleedings. PMID:23372808

  15. Thickness-, Composition-, and Magnetic-Field-Dependent Complex Impedance Spectroscopy of Granular-Type-Barrier Co/Co-Al2O3/Co MTJs

    NASA Astrophysics Data System (ADS)

    Tuan, Nguyen Anh; Anh, Nguyen Tuan; Nga, Nguyen Tuyet; Tue, Nguyen Anh; Van Cuong, Giap

    2016-06-01

    The alternating-current (ac) electrical properties of granular-type-barrier magnetic tunnel junctions (GBMTJs) based on Co/Co x (Al2O3)1- x ( t)/Co trilayer structures have been studied using complex impedance spectroscopy (CIS). Their CIS characteristics were investigated in external magnetic fields varying from 0 kOe to 3 kOe as a function of Co composition x at 10 at.%, 25 at.%, and 35 at.%, with barrier layer thickness t of 20 nm to 90 nm. The influence of these factors on the behaviors of the ac impedance response of the GBMTJs was deeply investigated and attributed to the dielectric or conducting nature of the Co-Al2O3 barrier layer. The most remarkable typical phenomena observed in these behaviors, even appearing paradoxical, include lower impedance for thicker t for each given x, a declining trend of Z with increasing x, a clear decrease of Z with H, and especially a partition of Z into zones according to the H value. All these effects are analyzed and discussed to demonstrate that diffusion-type and mass-transfer-type phenomena can be inferred from processes such as spin tunneling and Coulomb or spin blockade in the Co-Al2O3 barrier layer.

  16. Transthoracic defibrillation: effect of sternotomy on chest impedance.

    PubMed

    Kerber, R E; Vance, S; Schomer, S J; Mariano, D J; Charbonnier, F

    1992-07-01

    The purpose of this study was to determine the effect of sternotomy on transthoracic impedance, a major determinant of current flow and defibrillation success. Transthoracic impedance was determined by using a validated test-pulse technique that does not require actual shocks. Seventeen patients undergoing median sternotomy were studied prospectively. Transthoracic impedance was determined before operation, 3 to 5 days after operation and (in eight patients) greater than or equal to 1 month after operation. When measured using paddle electrodes placed in the standard apex-right parasternal defibrillating position, transthoracic impedance declined after sternotomy in all patients, from 77 +/- 18 to 59 +/- 17 omega (p less than 0.01); smaller declines were demonstrated by using other electrode positions. Transthoracic impedance remained below the preoperative level in the eight patients who underwent a second set of measurements at least 1 month after operation. Six normal subjects not undergoing sternotomy underwent serial transthoracic impedance measurements at least 5 days apart; mean transthoracic impedance did not change. It is concluded that transthoracic impedance declines after sternotomy. At any operator-selected energy level a higher current flow will result after sternotomy; this may facilitate postoperative defibrillation.

  17. Modifying the acoustic impedance of polyurea-based composites

    NASA Astrophysics Data System (ADS)

    Nantasetphong, Wiroj; Amirkhizi, Alireza V.; Jia, Zhanzhan; Nemat-Nasser, Sia

    2013-04-01

    Acoustic impedance is a material property that depends on mass density and acoustic wave speed. An impedance mismatch between two media leads to the partial reflection of an acoustic wave sent from one medium to another. Active sonar is one example of a useful application of this phenomenon, where reflected and scattered acoustic waves enable the detection of objects. If the impedance of an object is matched to that of the surrounding medium, however, the object may be hidden from observation (at least directly) by sonar. In this study, polyurea composites are developed to facilitate such impedance matching. Polyurea is used due to its excellent blast-mitigating properties, easy casting, corrosion protection, abrasion resistance, and various uses in current military technology. Since pure polyurea has impedance higher than that of water (the current medium of interest), low mass density phenolic microballoon particles are added to create composite materials with reduced effective impedances. The volume fraction of particles is varied to study the effect of filler quantity on the acoustic impedance of the resulting composite. The composites are experimentally characterized via ultrasonic measurements. Computational models based on the method of dilute-randomly-distributed inclusions are developed and compared with the experimental results. These experiments and models will facilitate the design of new elastomeric composites with desirable acoustic impedances.

  18. Aberration corrected environmental STEM (AC ESTEM) for dynamic in-situ gas reaction studies of nanoparticle catalysts

    NASA Astrophysics Data System (ADS)

    Boyes, E. D.; Gai, P. L.

    2014-06-01

    Environmental scanning transmission electron microscopy (ESTEM) with aberration correction (AC) has recently been added to the capabilities of the more established ETEM for analysis of heterogeneous nanoparticle based catalysts. It has helped to reveal the importance and potentially unique properties of individual atoms as active sites in their own right as well as pathways between established nanoparticles. A new capability is introduced for dynamic in-situ experiments under controlled conditions of specimen temperature and gas environment related to real world conditions pertinent to a range of industrial and societal priorities for new and improved chemical processes, materials, fuels, pharmaceutical products and processes, and in control or remediation of environmental emissions.

  19. XPS and electrochemical impedance spectroscopy studies on effects of the porcelain firing process on surface and corrosion properties of two nickel-chromium dental alloys.

    PubMed

    Qiu, Jing; Tang, Chun-bo; Zhu, Zhi-jun; Zhou, Guo-xing; Wang, Jie; Yang, Yi; Wang, Guo-ping

    2013-11-01

    The aim of this study was to evaluate the effects of a simulated porcelain firing process on the surface, corrosion behavior and cell culture response of two nickel-chromium (Ni-Cr) dental alloys. A Be-free alloy and a Be-containing alloy were tested. Before porcelain firing, as-cast specimens were examined for surface composition using X-ray photoelectron spectroscopy and metallurgical phases using X-ray diffraction. Corrosion behaviors were evaluated using electrochemical impedance spectroscopy. 3T3 fibroblasts were cultured and exposed indirectly to specimens. MTT assays were counted after 3 and 6 days. The cell culture mediums exposed to specimens were analyzed for metal ion release. After porcelain firing, similar specimens were examined for the same properties. In both as-cast and fired conditions, the Be-free Ni-Cr alloy showed significantly more resistance to corrosion than the Be-containing Ni-Cr alloy, which exhibited BeNi phase. After porcelain firing, the corrosion resistance of the Be-free Ni-Cr alloy decreased statistically, corresponding with evident decreases of Cr and Ni oxides on the alloy surface. Also, the alloy's MTT assay decreased significantly corresponding with an obvious increase of Ni-ion release after the firing. For the Be-containing Ni-Cr alloy, the firing process led to increases of surface oxides and metallic Be, while its corrosion resistance and cell culture response were not significantly changed after porcelain firing. The results suggested that the corrosion resistance and biocompatibility of the Be-free Ni-Cr alloy decreased after porcelain firing, whereas the firing process had little effect on the same properties of the Be-containing Ni-Cr alloy. PMID:23881280

  20. XPS and electrochemical impedance spectroscopy studies on effects of the porcelain firing process on surface and corrosion properties of two nickel-chromium dental alloys.

    PubMed

    Qiu, Jing; Tang, Chun-bo; Zhu, Zhi-jun; Zhou, Guo-xing; Wang, Jie; Yang, Yi; Wang, Guo-ping

    2013-11-01

    The aim of this study was to evaluate the effects of a simulated porcelain firing process on the surface, corrosion behavior and cell culture response of two nickel-chromium (Ni-Cr) dental alloys. A Be-free alloy and a Be-containing alloy were tested. Before porcelain firing, as-cast specimens were examined for surface composition using X-ray photoelectron spectroscopy and metallurgical phases using X-ray diffraction. Corrosion behaviors were evaluated using electrochemical impedance spectroscopy. 3T3 fibroblasts were cultured and exposed indirectly to specimens. MTT assays were counted after 3 and 6 days. The cell culture mediums exposed to specimens were analyzed for metal ion release. After porcelain firing, similar specimens were examined for the same properties. In both as-cast and fired conditions, the Be-free Ni-Cr alloy showed significantly more resistance to corrosion than the Be-containing Ni-Cr alloy, which exhibited BeNi phase. After porcelain firing, the corrosion resistance of the Be-free Ni-Cr alloy decreased statistically, corresponding with evident decreases of Cr and Ni oxides on the alloy surface. Also, the alloy's MTT assay decreased significantly corresponding with an obvious increase of Ni-ion release after the firing. For the Be-containing Ni-Cr alloy, the firing process led to increases of surface oxides and metallic Be, while its corrosion resistance and cell culture response were not significantly changed after porcelain firing. The results suggested that the corrosion resistance and biocompatibility of the Be-free Ni-Cr alloy decreased after porcelain firing, whereas the firing process had little effect on the same properties of the Be-containing Ni-Cr alloy.

  1. Induced optical metric in the non-impedance-matched media

    NASA Astrophysics Data System (ADS)

    Mousavi, S. A.; Roknizadeh, R.; Sahebdivan, S.

    2016-11-01

    In non-magnetic anisotropic media, the behavior of electromagnetic waves depends on the polarization and direction of the incident light. Therefore, to tame the unwanted wave responses such as polarization dependent reflections, the artificial impedance-matched media are suggested to be used in optical devices like invisibility cloak or super lenses. Nevertheless, developing the impedance-matched media is far from trivial in practice. In this paper, we are comparing the samples of both impedance-matched and non-impedance-matched (non-magnetic) media regarding their electromagnetic response in constructing a well-defined optical metric. In the case of similar anisotropic patterns, we show that the optical metric in an impedance-matched medium for unpolarized light is the same as the optical metric of an electrical birefringent medium when the extraordinary mode is concerned. By comparing the eikonal equation in an empty curved space-time and its counterparts in the medium, we have shown that a non-impedance-matched medium can resemble an optical metric for a particular polarization. As an example of non-impedance-matched materials, we are studying a medium with varying optical axis profile. We show that such a medium can be an alternative to impedance-matched materials in various optical devices.

  2. Input impedance of microstrip antennas

    NASA Technical Reports Server (NTRS)

    Deshpande, M. D.; Bailey, M. C.

    1982-01-01

    Using Richmond's reaction integral equation, an expression is derived for the input impedance of microstrip patch antennas excited by either a microstrip line or a coaxial probe. The effects of the finite substrate thickness, a dielectric protective cover, and associated surface waves are properly included by the use of the exact dyadic Green's function. Using the present formulation the input impedance of a rectangular microstrip antenna is determined and compared with experimental and earlier calculated results.

  3. Traveling-wave electrokinetic micropumps: velocity, electrical current, and impedance measurements.

    PubMed

    García-Sánchez, P; Ramos, A; Green, N G; Morgan, H

    2008-09-01

    An array of microelectrodes covered in an electrolyte and energized by a traveling-wave potential produces net movement of the fluid. Arrays of platinum microelectrodes of two different characteristic sizes have been studied. For both sizes of arrays, at low voltages (<2 V pp) the electrolyte flow is in qualitative agreement with the linear theory of ac electroosmosis. At voltages above a threshold, the direction of fluid flow is reversed. The electrical impedance of the electrode-electrolyte system was measured after the experiments, and changes in the electrical properties of the electrolyte were observed. Measurements of the electrical current during pumping of the electrolyte are also reported. Transient behaviors in both electrical current and fluid velocity were observed. The Faradaic currents probably generate conductivity gradients in the liquid bulk, which in turn give rise to electrical forces. These effects are discussed in relation to the fluid flow observations.

  4. Study on AC-DC Electrical Conductivities in Warm Dense Matter Generated by Pulsed-power Discharge with Isochoric Vessel

    NASA Astrophysics Data System (ADS)

    Sasaki, Toru; Ohuchi, Takumi; Takahashi, Takuya; Kawaguchi, Yoshinari; Saito, Hirotaka; Miki, Yasutoshi; Takahashi, Kazumasa; Kikuchi, Takashi; Aso, Tsukasa; Harada, Nob.

    2016-03-01

    To observe AC and DC electrical conductivity in warm dense matter (WDM), we have demonstrated to apply the spectroscopic ellipsometry for a pulsed-power discharge with isochoric vessel. At 10 μs from the beginning of discharge, the generated parameters by using pulsed-power discharge with isochoric vessel are 0.1 ρ s (ρ s: solid density) of density and 4000 K of temperature, respectively. The DC electrical conductivity for above parameters is estimated to be 104 S/m. In order to measure the AC electrical conductivity, we have developed a four-detector spectroscopic ellipsometer with a multichannel spectrometer. The multichannel spectrometer, in which consists of a 16-channel photodiode array, a two-stages voltage adder, and a flat diffraction grating, has 10 MHz of the frequency response with covered visible spectrum. For applying the four-detector spectroscopic ellipsometer, we observe the each observation signal evolves the polarized behavior compared to the ratio as I 1/I 2.

  5. Concentration dependence of nanochannel impedance and the determination of surface charge

    NASA Astrophysics Data System (ADS)

    Schiffbauer, Jarrod; Liel, Uri; Yossifon, Gilad

    2014-03-01

    In this paper, we demonstrate the variation of nanochannel impedance with bulk (reservoir) electrolyte concentration. The impedance of a nanochannel is shown to correspond to a characteristic deformed semicircular arc. The degree of deformation decreases with increasing concentration, and at a sufficiently low concentration the complex impedance saturates, becoming essentially independent of the reservoir concentration. This behavior is indicative of a surface-conduction dominant regime. Here we demonstrate that this effect extends beyond dc conductance and affects the ac response of the system as well, including both phase relationship and magnitude. The nanochannel resistance, obtained from low-voltage ac measurements, is then used to extract the nanochannel surface charge density. This is found to increase in magnitude with increasing electrolyte concentration.

  6. Aortic Input Impedance during Nitroprusside Infusion

    PubMed Central

    Pepine, Carl J.; Nichols, W. W.; Curry, R. C.; Conti, C. Richard

    1979-01-01

    Beneficial effects of nitroprusside infusion in heart failure are purportedly a result of decreased afterload through “impedance” reduction. To study the effect of nitroprusside on vascular factors that determine the total load opposing left ventricular ejection, the total aortic input impedance spectrum was examined in 12 patients with heart failure (cardiac index <2.0 liters/min per m2 and left ventricular end diastolic pressure >20 mm Hg). This input impedance spectrum expresses both mean flow (resistance) and pulsatile flow (compliance and wave reflections) components of vascular load. Aortic root blood flow velocity and pressure were recorded continuously with a catheter-tip electromagnetic velocity probe in addition to left ventricular pressure. Small doses of nitroprusside (9-19 μg/min) altered the total aortic input impedance spectrum as significant (P < 0.05) reductions in both mean and pulsatile components were observed within 60-90 s. With these acute changes in vascular load, left ventricular end diastolic pressure declined (44%) and stroke volume increased (20%, both P < 0.05). Larger nitroprusside doses (20-38 μg/min) caused additional alteration in the aortic input impedance spectrum with further reduction in left ventricular end diastolic pressure and increase in stroke volume but no additional changes in the impedance spectrum or stroke volume occurred with 39-77 μg/min. Improved ventricular function persisted when aortic pressure was restored to control values with simultaneous phenylephrine infusion in three patients. These data indicate that nitroprusside acutely alters both the mean and pulsatile components of vascular load to effect improvement in ventricular function in patients with heart failure. The evidence presented suggests that it may be possible to reduce vascular load and improve ventricular function independent of aortic pressure reduction. PMID:457874

  7. AC and Phase Sensing of Nanowires for Biosensing.

    PubMed

    Crescentini, Marco; Rossi, Michele; Ashburn, Peter; Lombardini, Marta; Sangiorgi, Enrico; Morgan, Hywel; Tartagni, Marco

    2016-04-19

    Silicon nanowires are label-free sensors that allow real-time measurements. They are economical and pave the road for point-of-care applications but require complex readout and skilled personnel. We propose a new model and technique for sensing nanowire sensors using alternating currents (AC) to capture both magnitude and phase information from the sensor. This approach combines the advantages of complex impedance spectroscopy with the noise reduction performances of lock-in techniques. Experimental results show how modifications of the sensors with different surface chemistries lead to the same direct-current (DC) response but can be discerned using the AC approach.

  8. AC and Phase Sensing of Nanowires for Biosensing

    PubMed Central

    Crescentini, Marco; Rossi, Michele; Ashburn, Peter; Lombardini, Marta; Sangiorgi, Enrico; Morgan, Hywel; Tartagni, Marco

    2016-01-01

    Silicon nanowires are label-free sensors that allow real-time measurements. They are economical and pave the road for point-of-care applications but require complex readout and skilled personnel. We propose a new model and technique for sensing nanowire sensors using alternating currents (AC) to capture both magnitude and phase information from the sensor. This approach combines the advantages of complex impedance spectroscopy with the noise reduction performances of lock-in techniques. Experimental results show how modifications of the sensors with different surface chemistries lead to the same direct-current (DC) response but can be discerned using the AC approach. PMID:27104577

  9. The ac53, ac78, ac101, and ac103 Genes Are Newly Discovered Core Genes in the Family Baculoviridae

    PubMed Central

    Garavaglia, Matías Javier; Miele, Solange Ana Belén; Iserte, Javier Alonso; Belaich, Mariano Nicolás

    2012-01-01

    The family Baculoviridae is a large group of insect viruses containing circular double-stranded DNA genomes of 80 to 180 kbp, which have broad biotechnological applications. A key feature to understand and manipulate them is the recognition of orthology. However, the differences in gene contents and evolutionary distances among the known members of this family make it difficult to assign sequence orthology. In this study, the genome sequences of 58 baculoviruses were analyzed, with the aim to detect previously undescribed core genes because of their remote homology. A routine based on Multi PSI-Blast/tBlastN and Multi HaMStR allowed us to detect 31 of 33 accepted core genes and 4 orthologous sequences in the Baculoviridae which were not described previously. Our results show that the ac53, ac78, ac101 (p40), and ac103 (p48) genes have orthologs in all genomes and should be considered core genes. Accordingly, there are 37 orthologous genes in the family Baculoviridae. PMID:22933288

  10. Structural and impedance studies of LiNi0.5Mn1.5O4 synthesized by sol-gel method

    NASA Astrophysics Data System (ADS)

    Lobo, Laurel Simon; Rubankumar, A.; Kalainathan, S.

    2016-05-01

    LiNi0.5Mn1.5O4 is synthesized by sol-gel method by using succinic acid as chelating agent. X-ray diffraction pattern confirms the material is spinel cubic structure with Fd3m space group. Impedance spectroscopy analysis of spinel LiNi0.5Mn1.5O4 was performed under a wide frequency and temperature range of 50 Hz to 5 MHz and 303 K to 783 K respectively. The hopping of the electrons, ionic conductivity and activation energy were analyzed from the relaxation frequency of the imaginary impedance (Z"). The activation energy Ea is calculated from the Arrhenius plots and it is found to be 0.3713 eV, which indicates the existence of oxygen vacancy in the material. Nyquist plot indicates the presence of grain effect in the material and suppression in the grain effect is observed with increasing temperature.

  11. AC properties of low-pass RC filters embedded in printed circuit boards

    NASA Astrophysics Data System (ADS)

    Winiarski, Paweł; Kłossowicz, Adam; Steplewski, Wojciech; Borecki, Janusz; Nitsch, Karol; Dziedzic, Andrzej

    2013-07-01

    Impedance Spectroscopy (IS) is a widely used measurement technique for determining the characteristics of a variety of materials and systems. Analysis of object's AC-response can allow determine of different electrical properties due to its structure. IS can also be used to study electronic components such as gas and humidity sensors, thermistors, varistors, capacitors or resistors. The resulting impedance spectrum can be approximated by electrical equivalent circuit. However, It is difficult to find papers dedicated to the electronic systems investigated by IS method. For this reason authors analyzed properties of RC low-pass filters embedded in printed circuit boards using IS technique. These four-contact structures were made of special Ohmega/FaradFlex® composite material. It consists of a resistive/capacitive core containing OhmegaPly RCM layer (resistive NiP alloy) laminated to FaradFlex dielectric of Oak-Mitsui company. Analysis of the measurements results using impedance spectroscopy allowed a more precise determination of the filter parameters than an analysis using standard method based on ideal components. Additionally selected filters were subjected to one of the aging process (thermal aging or thermal-humidity exposure), and found that this results in a frequency shift of the filter.

  12. Nanojacketing and dejacketing of ds-DNA: a nondestructive characterization of a nanojacketed sample by impedance spectroscopy.

    PubMed

    Nandi, Sudipta; Mukherjee, Pratap; Kundu, Aniruddha; Nandi, Arun K

    2014-03-13

    A facile approach of nanojacketing DNA in intact conformation is evolved by the in situ polymerization of o-methoxyaniline (OMA) at 30 °C using HAuCl4 as an oxidant and DNA as a soft template. It concomitantly produces poly(o-methoxyaniline) (POMA) and a Au nanojacket encapsulating the double stranded DNA (ds-DNA). The POMA chains remain adhered to the Au nanojacket, facilitating the dissolution of nanojacketed DNA (DNA-Au-POMA) in organic solvent without affecting its conformation. Digestion of the nanojacketed system with saturated iodine solution dejackets the ds-DNA with retention of its conformation, leaving the POMA nanotube. The nanojacketing and dejacketing phenomena are established by transmission electron microscopy (TEM), UV-vis spectroscopy, and CD spectroscopy, and the nanostructure is further characterized by FTIR, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The impedance study of the DNA-Au-POMA sample suggests the Cole-Cole plots at both the impedance and modulus planes and the values of capacitance and electron-transfer resistance of the material (R(et)) are calculated to be 13.74 pF and 388 kΩ, respectively. The presence of a single Debye peak in both the impedance and modulus vs frequency plots suggests an isotropic nature of the system, and the frequency dependent ac-conductivity suggests the presence of short-range translational and reorientational (localized) hopping of charge carriers at lower and higher frequency region.

  13. Summary of Human Ankle Mechanical Impedance During Walking

    PubMed Central

    Rouse, Elliott J.; Krebs, Hermano Igo

    2016-01-01

    The human ankle joint plays a critical role during walking and understanding the biomechanical factors that govern ankle behavior and provides fundamental insight into normal and pathologically altered gait. Previous researchers have comprehensively studied ankle joint kinetics and kinematics during many biomechanical tasks, including locomotion; however, only recently have researchers been able to quantify how the mechanical impedance of the ankle varies during walking. The mechanical impedance describes the dynamic relationship between the joint position and the joint torque during perturbation, and is often represented in terms of stiffness, damping, and inertia. The purpose of this short communication is to unify the results of the first two studies measuring ankle mechanical impedance in the sagittal plane during walking, where each study investigated differing regions of the gait cycle. Rouse et al. measured ankle impedance from late loading response to terminal stance, where Lee et al. quantified ankle impedance from pre-swing to early loading response. While stiffness component of impedance increases significantly as the stance phase of walking progressed, the change in damping during the gait cycle is much less than the changes observed in stiffness. In addition, both stiffness and damping remained low during the swing phase of walking. Future work will focus on quantifying impedance during the “push off” region of stance phase, as well as measurement of these properties in the coronal plane. PMID:27766187

  14. 7 CFR 1737.31 - Area Coverage Survey (ACS).

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 11 2011-01-01 2011-01-01 false Area Coverage Survey (ACS). 1737.31 Section 1737.31... Studies-Area Coverage Survey and Loan Design § 1737.31 Area Coverage Survey (ACS). (a) The Area Coverage Survey (ACS) is a market forecast of service requirements of subscribers in a proposed service area....

  15. 7 CFR 1737.31 - Area Coverage Survey (ACS).

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 11 2013-01-01 2013-01-01 false Area Coverage Survey (ACS). 1737.31 Section 1737.31... Studies-Area Coverage Survey and Loan Design § 1737.31 Area Coverage Survey (ACS). (a) The Area Coverage Survey (ACS) is a market forecast of service requirements of subscribers in a proposed service area....

  16. 7 CFR 1737.31 - Area Coverage Survey (ACS).

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 11 2012-01-01 2012-01-01 false Area Coverage Survey (ACS). 1737.31 Section 1737.31... Studies-Area Coverage Survey and Loan Design § 1737.31 Area Coverage Survey (ACS). (a) The Area Coverage Survey (ACS) is a market forecast of service requirements of subscribers in a proposed service area....

  17. Studies of the pulse charge of lead-acid batteries for PV applications. Part II. Impedance of the positive plate revisited

    NASA Astrophysics Data System (ADS)

    Kirchev, A.; Delaille, A.; Perrin, M.; Lemaire, E.; Mattera, F.

    In the second part of this publication series, dedicated to the pulse charge of the lead-acid battery, a special attention is paid to the impedance spectrum of the positive plate as a source for estimation of the electrostatic capacitance of the double layer (C dl) on the surface of the positive active mass. The impedance spectra were measured at open circuit for different states of charge (SoC) in H 2SO 4 with specific gravity 1.24 and 1.28 g ml -1. A substantial difference was observed in the impedance spectra of partially charged and partially discharged positive plates keeping the same value of the SOC. The impedance data were subjected to inductance error correction, followed by differential impedance analysis (DIA). Considering the results from DIA, the recently published equivalent circuits of the positive plate in charged and in discharged state and the gel-crystal model of the lead dioxide, we proposed a model of the positive plate in partial state of charge (PSoC). The analysis of the obtained experimental results using this model and DIA show that the double layer capacitance is not frequency distributed. The influence of the state of charge and state of health on the model parameters is discussed. One of the most interesting results is the dependence of C dl on SOC-it features a hysteresis at which the values of C dl during the charge are 5-6 times higher than the corresponding ones during the discharge. This result was discussed in terms of changes in the double layer structure considering the gel-crystal model of the lead dioxide. During the discharge in H 2SO 4 with specific gravity 1.28 g ml -1 a passivation process was detected as a high frequency pseudo-inductive loop in the Nyquist plots in PSoC. The passivation time constant is higher at 50-60% SOC and decreases to zero in the end of the discharge. During the charge in both electrolytes, pseudo-inductive time constant was observed too. It was attributed to the phenomena of the dehydration of Pb

  18. AC magnetohydrodynamic microfluidic switch

    SciTech Connect

    Lemoff, A V; Lee, A P

    2000-03-02

    A microfluidic switch has been demonstrated using an AC Magnetohydrodynamic (MHD) pumping mechanism in which the Lorentz force is used to pump an electrolytic solution. By integrating two AC MHD pumps into different arms of a Y-shaped fluidic circuit, flow can be switched between the two arms. This type of switch can be used to produce complex fluidic routing, which may have multiple applications in {micro}TAS.

  19. Impedance of a beam tube with antechamber

    SciTech Connect

    Barry, W.; Lambertson, G.R.; Voelker, F.

    1986-08-01

    A beam vacuum chamber was proposed to allow synchrotron light to radiate from a circulating electron beam into an antechamber containing photon targets, pumps, etc. To determine the impedance such a geometry would present to the beam, electromagnetic measurements were carried out on a section of chamber using for low frequencies a current-carrying wire and for up to 16 GHz, a resonance perturbation method. Because the response of such a chamber would depend on upstream and downstream restrictions of aperture yet to be determined, the resonance studies were analyzed in some generality. The favorable conclusion of these studies is that the antechamber makes practically no contribution to either the longitudinal or the transverse impedances.

  20. Impedance and domain wall mass determination in cylindrical wire with circular anisotropy

    NASA Astrophysics Data System (ADS)

    Ziman, J.; Kladivová, M.; Šuhajová, V.

    2015-11-01

    A study of single magnetic domain wall contribution to impedance due to its oscillation in the intermediate frequency region (100 kHz to a few MHz) is presented for a domain wall between circular domains. A simple theoretical model of the wall trapped in a quadratic potential well is proposed, for which the possible influence of skin effect is tested using a scalar permeability model. From this model, for parameters of the Co68.2Fe4.3Si12.5B15 wire used in the experiment, it follows that the frequency dependence of domain wall contribution to impedance exhibits a single maximum at the frequency of an ac current equal to the natural frequency ω0 of the domain wall moving in the quadratic potential well. Experimental dependence confirmed the existence of this maximum, and it made it possible to obtain the value of natural frequency ω0. From the theoretical model it follows that this parameter depends on inertial domain wall mass. Additional experimental procedures are proposed to measure parameters of the quadratic potential well in which the wall is trapped, and the value of domain wall mass per unit area 1.64 ×10-9 kgm-2 was obtained.

  1. Study of the Effect of Lubricant Emulsion Percentage and Tool Material on Surface Roughness in Machining of EN-AC 48000 Alloy

    NASA Astrophysics Data System (ADS)

    Soltani, E.; Shahali, H.; Zarepour, H.

    2011-01-01

    In this paper, the effect of machining parameters, namely, lubricant emulsion percentage and tool material on surface roughness has been studied in machining process of EN-AC 48000 aluminum alloy. EN-AC 48000 aluminum alloy is an important alloy in industries. Machining of this alloy is of vital importance due to built-up edge and tool wear. A L9 Taguchi standard orthogonal array has been applied as experimental design to investigate the effect of the factors and their interaction. Nine machining tests have been carried out with three random replications resulting in 27 experiments. Three type of cutting tools including coated carbide (CD1810), uncoated carbide (H10), and polycrystalline diamond (CD10) have been used in this research. Emulsion percentage of lubricant is selected at three levels including 3%, 5% and 10%. Statistical analysis has been employed to study the effect of factors and their interactions using ANOVA method. Moreover, the optimal factors level has been achieved through signal to noise ratio (S/N) analysis. Also, a regression model has been provided to predict the surface roughness. Finally, the results of the confirmation tests have been presented to verify the adequacy of the predictive model. In this research, surface quality was improved by 9% using lubricant and statistical optimization method.

  2. Impedances of Laminated Vacuum Chambers

    SciTech Connect

    Burov, A.; Lebedev, V.; /Fermilab

    2011-06-22

    First publications on impedance of laminated vacuum chambers are related to early 70s: those are of S. C. Snowdon [1] and of A. G. Ruggiero [2]; fifteen years later, a revision paper of R. Gluckstern appeared [3]. All the publications were presented as Fermilab preprints, and there is no surprise in that: the Fermilab Booster has its laminated magnets open to the beam. Being in a reasonable mutual agreement, these publications were all devoted to the longitudinal impedance of round vacuum chambers. The transverse impedance and the flat geometry case were addressed in more recent paper of K. Y. Ng [4]. The latest calculations of A. Macridin et al. [5] revealed some disagreement with Ref. [4]; this fact stimulated us to get our own results on that matter. Longitudinal and transverse impendances are derived for round and flat laminated vacuum chambers. Results of this paper agree with Ref. [5].

  3. An Ac transposon system based on maize chromosome 4S for isolating long-distance-transposed Ac tags in the maize genome.

    PubMed

    Wang, Fei; Li, Zhaoying; Fan, Jun; Li, Pengfei; Hu, Wei; Wang, Gang; Xu, Zhengkai; Song, Rentao

    2010-12-01

    Transposon tagging is an important tool for gene isolation and functional studies. In maize, several transposon-tagging systems have been developed, mostly using Activator/Dissociation (Ac/Ds) and Mutator systems. Here, we establish another Ac-based transposon system with the donor Ac tightly linked with sugary1 (su1) on maize chromosome 4S. Newly transposed Ac (tr-Acs) were detected based on a negative dosage effect, and long-distance-transposed Ac events were identified and isolated from the donor Ac by a simple backcross scheme. In this study, we identified 208 independent long-distance-transposed Ac lines. Thirty-one flanking sequences of these tr-Acs were isolated and localized in the maize genome. As found in previous studies, the tr-Acs preferentially inserted into genic sequences. The distribution of tr-Acs is not random. In our study, the tr-Acs preferentially transposed into chromosomes 1, 2, 9 and 10. We discuss the preferential distribution of tr-Acs from Ac systems. Our system is complementary to two other Ac-based regional-mutagenesis systems in maize, and the combined use of these systems will achieve an even and high-density distribution of Ac elements throughout the maize genome for functional-genomics studies.

  4. Propagation of quasiplane waves along an impedance boundary

    NASA Technical Reports Server (NTRS)

    Mcaninch, G. L.; Myers, M. K.

    1988-01-01

    The parabolic approximation for the acoustic equations of motion is applied to the study of the sound field generated by a time harmonic plane wave at grazing incidence to a finite impedance boundary. The resulting equations possess a solution which may be expressed in terms of the complementary error function. Asymptotic expansion of this solution for field points near the boundary provides results compatible with those for a point source on the boundary for both the soft boundary (finite impedance) and hard boundary (the limit in which the impedance becomes infinite) cases. The presence of a surface wave in the solution is also established.

  5. Measurement and simulation of the RHIC abort kicker longitudinal impedence

    SciTech Connect

    Abreu,N.P.; Hahn,H.; Choi, E.

    2009-09-01

    In face of the new upgrades for RHIC the longitudinal impedance of the machine plays an important role in setting the threshold for instabilities and the efficacy of some systems. In this paper we describe the measurement of the longitudinal impedance of the abort kicker for RHIC as well as computer simulations of the structure. The impedance measurement was done by the S{sub 21} wire method covering the frequency range from 9 kHz to 2.5 GHz. We observed a sharp resonance peak around 10 MHz and a broader peak around 20 MHz in both, the real and imaginary part, of the Z/n. These two peaks account for a maximum imaginary longitudinal impedance of j15 {Omega}, a value an order of magnitude larger than the estimated value of j0.2 {Omega}, which indicates that the kicker is one of the main sources of longitudinal impedance in the machine. A computer model was constructed for simulations in the CST MWS program. Results for the magnet input and the also the beam impedance are compared to the measurements. A more detail study of the system properties and possible changes to reduce the coupling impedance are presented.

  6. Stimuli dependent impedance of conductive magnetorheological elastomers

    NASA Astrophysics Data System (ADS)

    Wang, Yu; Xuan, Shouhu; Dong, Bo; Xu, Feng; Gong, Xinglong

    2016-02-01

    The structure dependent impedance of conductive magnetorheological elastomers (MREs) under different loads and magnetic fields has been studied in this work. By increasing the weight fraction of iron particles, the conductivity of the MREs increased. Dynamic mechanical measurements and synchrotron radiation x-ray computed tomography (SR-CT) were used and they provided reasons for the electrical properties changing significantly under pressure and magnetic field stimulation. The high sensitivity of MREs to external stimuli renders them suitable for application in force or magnetic field sensors. The equivalent circuit model was proposed to analyze the impedance response of MREs and it fits the experimental results very well. Each circuit component reflected the change of the inner interface under different conditions, thus relative changes in the microstructure could be distinguished. This method could be used not only to detect the structural changes in the MRE but also to provide a great deal of valuable information for the further understanding of the MR mechanism.

  7. Nonlinear acoustic impedance of thermoacoustic stack

    NASA Astrophysics Data System (ADS)

    Ge, Huan; Fan, Li; Xiao, Shu-yu; Tao, Sha; Qiu, Mei-chen; Zhang, Shu-yi; Zhang, Hui

    2012-09-01

    In order to optimize the performances of the thermoacoustic refrigerator working with the high sound pressure level, the nonlinear acoustic characteristics of the thermoacoustic stack in the resonant pipe are studied. The acoustic fluid impedance of the stack made of copper mesh and set up in a resonant pipe is measured in the acoustic fields with different intensities. It is found that when the sound pressure level in the pipe increases to a critical value, the resistance of the stack increases nonlinearly with the sound pressure, while the reactance of the stack keeps constant. Based on the experimental results, a theory model is set up to describe the acoustic characteristics of the stack, according to the rigid frame theory and Forchheimmer equation. Furthermore, the influences of the sound pressure level, operating frequency, volume porosity, and length of the stack on the nonlinear impedance of the stack are evaluated.

  8. Impedance issues in the CERN SPS

    NASA Astrophysics Data System (ADS)

    Linnecar, T.

    1999-12-01

    The future use of the CERN SPS accelerator as injector for the Large Hadron Collider, LHC, and the possible use of the SPS as a neutrino source for the Gran Sasso experiment are pushing the maximum intensity requirements of the accelerator much higher than achieved up to now. At the same time the requirements on beam quality are becoming far more stringent. The SPS machine, built in the 70's, is not a "smooth" machine. It contains many discontinuities in vacuum chamber cross-section and many cavity-like objects, as well as the 5 separate RF systems at present installed. All these lead to a high impedance, seen by the beam, spread over a wide frequency range. As a result there is a constant fight against instabilities, both single and multi bunch, as the intensity increases. A program of studies is under way in the SPS to identify, reduce, and remove where possible the sources of these impedances.

  9. Density functional theory studies of actinide(III) motexafins (An-Motex2+, An = Ac, Cm, Lr). Structure, stability, and comparison with lanthanide(III) motexafins.

    PubMed

    Cao, Xiaoyan; Li, Quansong; Moritz, Anna; Xie, Zhizhong; Dolg, Michael; Chen, Xuebo; Fang, Weihai

    2006-04-17

    Newly developed relativistic energy-consistent 5f-in-core actinide pseudopotentials and corresponding (7s6p5d1f)/[5s4p3d1f] basis sets in the segmented contraction scheme, combined with density functional theory methods, have been used to study the molecular structure and chemical properties of selected actinide(III) motexafins (An-Motex2+, An = Ac, Cm, Lr). Structure and stability are discussed, and a comparison to the lanthanide(III) motexafins (Ln-Motex2+, Ln = La, Gd, Lu) is made. The actinide element is found to reside above the mean N5 motexafin plane, and the larger the cation, the greater the observed out-of-plane displacement. It is concluded that the actinium(III), curium(III), and lawrencium(III) cations are tightly bound to the macrocyclic skeleton, yielding stable structures. However, the calculated metal-ligand gas-phase binding energy for An-Motex2+ is about 1-2 eV lower than that of Ln-Motex2+, implying a lower stability of An-Motex2+ compared to Ln-Motex2+. Results including solvent effects imply that Ac-Motex2+ is the most stable complex in aqueous solution and should be the best candidate for experimentalists to get stable actinide(III) motexafin complexes. PMID:16602805

  10. Impedance spectroscopy study of 2, 2, 7, 7' -tetra kis-(N,N-di-4-methoxy phenyl amino)-9,9'-spirobifluorene thin films

    NASA Astrophysics Data System (ADS)

    Rana, Omwati; Agrawal, Kalpana; Rajput, S. S.; Zulfequar, M.; Husain, M.; Kamalasanan, M. N.; Srivastava, Ritu

    2016-05-01

    The electrical properties of thermally evaporated film of 2,2,7,7'-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9'-spirobifluorene (Spiro MeO TAD) have been investigated for hole only devices as a function of temperatures at frequency range from 1Hz to 1 MHz using Impedance spectroscopy. Cole-Cole plots, at each temperature, show semicircles that can be modeled with a contact resistance and parallel resistance -capacitor(R-C) circuits. Bulk resistance decreases and electrical conductivity increases with increasing temperature which indicate negative temperature coefficient of resistance nature and short range translational type hopping mechanism in Spiro MeO TAD thin films.

  11. AcMNPV ac143 (odv-e18) is essential for mediating budded virus production and is the 30th baculovirus core gene.

    PubMed

    McCarthy, Christina B; Theilmann, David A

    2008-05-25

    Autographa californica multiple nucleopolyhedrovirus (AcMNPV) ac143 (odv-e18) is a late gene that encodes for a predicted 9.6 kDa structural protein that locates to the occlusion derived viral envelope and viral induced intranuclear microvesicles [Braunagel, S.C., He, H., Ramamurthy, P., and Summers, M.D. (1996). Transcription, translation, and cellular localization of three Autographa californica nuclear polyhedrosis virus structural proteins: ODV-E18, ODV-E35, and ODV-EC27. Virology 222, 100-114.]. In this study we demonstrate that ac143 is actually a previously unrecognized core gene and that it is essential for mediating budded virus production. To examine the role of ac143 in the baculovirus life cycle, we used the AcMNPV bacmid system to generate an ac143 knockout (KO) virus (AcBAC(ac142)(REP-ac143KO)). Fluorescence and light microscopy showed that infection by AcBAC(ac142)(REP-ac143KO) is limited to a single cell and titration assays confirmed that AcBAC(ac142)(REP-ac143KO) was unable to produce budded virus (BV). Progression to very late phases of the viral infection was evidenced by the development of occlusion bodies in the nuclei of transfected cells. This correlated with the fact that viral DNA replication was unaffected in AcBAC(ac142)(REP-ac143KO) transfected cells. The entire ac143 promoter, which includes three late promoter motifs, is contained within the ac142 open reading frame. Different deletion mutants of this region showed that the integrity of the ac142-ac143 core gene cluster was required for the bacmids to display wild-type patterns of viral replication, BV production and RNA transcription.

  12. AcMNPV ac143 (odv-e18) is essential for mediating budded virus production and is the 30th baculovirus core gene

    SciTech Connect

    McCarthy, Christina B.; Theilmann, David A.

    2008-05-25

    Autographa californica multiple nucleopolyhedrovirus (AcMNPV) ac143 (odv-e18) is a late gene that encodes for a predicted 9.6 kDa structural protein that locates to the occlusion derived viral envelope and viral induced intranuclear microvesicles [Braunagel, S.C., He, H., Ramamurthy, P., and Summers, M.D. (1996). Transcription, translation, and cellular localization of three Autographa californica nuclear polyhedrosis virus structural proteins: ODV-E18, ODV-E35, and ODV-EC27. Virology 222, 100-114.]. In this study we demonstrate that ac143 is actually a previously unrecognized core gene and that it is essential for mediating budded virus production. To examine the role of ac143 in the baculovirus life cycle, we used the AcMNPV bacmid system to generate an ac143 knockout (KO) virus (AcBAC{sup ac142REP-ac143KO}). Fluorescence and light microscopy showed that infection by AcBAC{sup ac142REP-ac143KO} is limited to a single cell and titration assays confirmed that AcBAC{sup ac142REP-ac143KO} was unable to produce budded virus (BV). Progression to very late phases of the viral infection was evidenced by the development of occlusion bodies in the nuclei of transfected cells. This correlated with the fact that viral DNA replication was unaffected in AcBAC{sup ac142REP-ac143KO} transfected cells. The entire ac143 promoter, which includes three late promoter motifs, is contained within the ac142 open reading frame. Different deletion mutants of this region showed that the integrity of the ac142-ac143 core gene cluster was required for the bacmids to display wild-type patterns of viral replication, BV production and RNA transcription.

  13. AC conductivity and relaxation mechanism in (Nd1/2Li1/2)(Fe1/2V1/2)O3 ceramics

    NASA Astrophysics Data System (ADS)

    Nath, Susmita; Barik, Subrat Kumar; Choudhary, R. N. P.

    2016-05-01

    In the present study we have synthesized polycrystalline sample of (Nd1/2Li1/2)(Fe1/2V1/2)O3 ceramic by a standard high-temperature solid-state reaction technique. Studies of dielectric and electrical properties of the compound have been carried out in a wide range of temperature (RT - 400 °C) and frequency (1kHz - 1MHz) using complex impedance spectroscopic technique. The imaginary vs. real component of the complex impedance plot (Nyquist plot) of the prepared sample exhibits the existence of grain, grain boundary contributions in the complex electrical parameters and negative temperature coefficient of resistance (NTCR) type behavior like semiconductor. Details study of ac conductivity plot reveals that the material obeys universal Jonscher's power law.

  14. Impedance Biosensors: Applications to Sustainability and Remaining Technical Challenges

    PubMed Central

    2015-01-01

    Due to their all-electrical nature, impedance biosensors have significant potential for use as simple and portable sensors for environmental studies and environmental monitoring. Detection of two endocrine-disrupting chemicals (EDC), norfluoxetine and BDE-47, is reported here by impedance biosensing, with a detection limit of 8.5 and 1.3 ng/mL for norfluoxetine and BDE-47, respectively. Although impedance biosensors have been widely studied in the academic literature, commercial applications have been hindered by several technical limitations, including possible limitations to small analytes, the complexity of impedance detection, susceptibility to nonspecific adsorption, and stability of biomolecule immobilization. Recent research into methods to overcome these obstacles is briefly reviewed. New results demonstrating antibody regeneration atop degenerate (highly doped) Si are also reported. Using 0.2 M KSCN and 10 mM HF for antibody regeneration, peanut protein Ara h 1 is detected daily during a 30 day trial. PMID:25068095

  15. Characteristic impedance of microstrip lines

    NASA Technical Reports Server (NTRS)

    Bailey, M. C.; Deshpande, M. D.

    1989-01-01

    The dyadic Green's function for a current embedded in a grounded dielectric slab is used to analyze microstrip lines at millimeter wave frequencies. The dyadic Green's function accounts accurately for fringing fields and dielectric cover over the microstrip line. Using Rumsey's reaction concept, an expression for the characteristic impedance is obtained. The numerical results are compared with other reported results.

  16. A Monte Carlo simulation of range for an invasive impedance respiration monitor.

    PubMed

    Valenta, H L; Fischer, S K

    1990-01-01

    One method of rate responsive pacing utilizes an analog of minute ventilation as the input to the rate control algorithm. A measure of the intravenous impedance along the pacing catheter is a convenient means of determining minute ventilation. Design of the impedance converter requires a knowledge of the range of DC and AC impedance signals. During normal and deep breathing, 116 AC measurements were taken from 34 Electrophysiology (EP) patients and 31 DC measurements were taken from 13 EP patients. The patient data produced skewed distributions with a normal AC mean of 0.45 +/- 0.40 ohms p-p, a deep AC mean of 2.0 +/- 1.6 ohms and a DC mean of 44 +/- 13 ohms. An eight variable static model was derived from prior work. Five of the physiological variables were chosen from established clinical ranges, one geometrical variable was chosen from prior work and two were selected by matching the statistics of a Monte Carlo analysis of the model with the statistics of the patient data. The blood resistivity was obtained from prior work. A simulation of 1000 measurements produced a normal breathing range of 0 to 2.24 ohms, a deep breathing range of 0 to 9.6 ohms and a DC range of 19 to 100 ohms. PMID:2334765

  17. PEP-X IMPEDANCE AND INSTABILITY CALCULATIONS

    SciTech Connect

    Bane, K.L.F.; Lee, L.-Q.; Ng, C.; Stupakov, G.; au Wang, L.; Xiao, L.; /SLAC

    2010-08-25

    PEP-X, a next generation, ring-based light source is designed to run with beams of high current and low emittance. Important parameters are: energy 4.5 GeV, circumference 2.2 km, beam current 1.5 A, and horizontal and vertical emittances, 185 pm by 8 pm. In such a machine it is important that impedance driven instabilities not degrade the beam quality. In this report they study the strength of the impedance and its effects in PEP-X. For the present, lacking a detailed knowledge of the vacuum chamber shape, they create a straw man design comprising important vacuum chamber objects to be found in the ring, for which they then compute the wake functions. From the wake functions they generate an impedance budget and a pseudo-Green function wake representing the entire ring, which they, in turn, use for performing microwave instability calculations. In this report they, in addition, consider in PEP-X the transverse mode-coupling, multi-bunch transverse, and beam-ion instabilities.

  18. A study of X100 pipeline steel passivation in mildly alkaline bicarbonate solutions using electrochemical impedance spectroscopy under potentiodynamic conditions and Mott-Schottky

    NASA Astrophysics Data System (ADS)

    Gadala, Ibrahim M.; Alfantazi, Akram

    2015-12-01

    The key steps involved in X100 pipeline steel passivation in bicarbonate-based simulated soil solutions from the pre-passive to transpassive potential regions have been analyzed here using a step-wise anodizing-electrochemical impedance spectroscopy (EIS) routine. Pre-passive steps involve parallel dissolution-adsorption in early stages followed by clear diffusion-adsorption control shortly before iron hydroxide formation. Aggressive NS4 chlorides/sulfate promote steel dissolution whilst inhibiting diffusion in pre-passive steps. Diffusive and adsorptive effects remain during iron hydroxide formation, but withdraw shortly thereafter during its removal and the development of the stable iron carbonate passive layer. Passive layer protectiveness is evaluated using EIS fitting, current density analysis, and correlations with semiconductive parameters, consistently revealing improved robustness in colder, bicarbonate-rich, chloride/sulfate-free conditions. Ferrous oxide formation at higher potentials results in markedly lower impedances with disordered behavior, and the involvement of the iron(III) valence state is observed in Mott-Schottky tests exclusively for 75 °C conditions.

  19. Wearable Multi-Frequency and Multi-Segment Bioelectrical Impedance Spectroscopy for Unobtrusively Tracking Body Fluid Shifts during Physical Activity in Real-Field Applications: A Preliminary Study

    PubMed Central

    Villa, Federica; Magnani, Alessandro; Maggioni, Martina A.; Stahn, Alexander; Rampichini, Susanna; Merati, Giampiero; Castiglioni, Paolo

    2016-01-01

    Bioelectrical Impedance Spectroscopy (BIS) allows assessing the composition of body districts noninvasively and quickly, potentially providing important physiological/clinical information. However, neither portable commercial instruments nor more advanced wearable prototypes simultaneously satisfy the demanding needs of unobtrusively tracking body fluid shifts in different segments simultaneously, over a broad frequency range, for long periods and with high measurements rate. These needs are often required to evaluate exercise tests in sports or rehabilitation medicine, or to assess gravitational stresses in aerospace medicine. Therefore, the aim of this work is to present a new wearable prototype for monitoring multi-segment and multi-frequency BIS unobtrusively over long periods. Our prototype guarantees low weight, small size and low power consumption. An analog board with current-injecting and voltage-sensing electrodes across three body segments interfaces a digital board that generates square-wave current stimuli and computes impedance at 10 frequencies from 1 to 796 kHz. To evaluate the information derivable from our device, we monitored the BIS of three body segments in a volunteer before, during and after physical exercise and postural shift. We show that it can describe the dynamics of exercise-induced changes and the effect of a sit-to-stand maneuver in active and inactive muscular districts separately and simultaneously. PMID:27187389

  20. Wearable Multi-Frequency and Multi-Segment Bioelectrical Impedance Spectroscopy for Unobtrusively Tracking Body Fluid Shifts during Physical Activity in Real-Field Applications: A Preliminary Study.

    PubMed

    Villa, Federica; Magnani, Alessandro; Maggioni, Martina A; Stahn, Alexander; Rampichini, Susanna; Merati, Giampiero; Castiglioni, Paolo

    2016-01-01

    Bioelectrical Impedance Spectroscopy (BIS) allows assessing the composition of body districts noninvasively and quickly, potentially providing important physiological/clinical information. However, neither portable commercial instruments nor more advanced wearable prototypes simultaneously satisfy the demanding needs of unobtrusively tracking body fluid shifts in different segments simultaneously, over a broad frequency range, for long periods and with high measurements rate. These needs are often required to evaluate exercise tests in sports or rehabilitation medicine, or to assess gravitational stresses in aerospace medicine. Therefore, the aim of this work is to present a new wearable prototype for monitoring multi-segment and multi-frequency BIS unobtrusively over long periods. Our prototype guarantees low weight, small size and low power consumption. An analog board with current-injecting and voltage-sensing electrodes across three body segments interfaces a digital board that generates square-wave current stimuli and computes impedance at 10 frequencies from 1 to 796 kHz. To evaluate the information derivable from our device, we monitored the BIS of three body segments in a volunteer before, during and after physical exercise and postural shift. We show that it can describe the dynamics of exercise-induced changes and the effect of a sit-to-stand maneuver in active and inactive muscular districts separately and simultaneously. PMID:27187389

  1. Equivalent Electrical Circuit Representations of AC Quantized Hall Resistance Standards

    PubMed Central

    Cage, M. E.; Jeffery, A.; Matthews, J.

    1999-01-01

    We use equivalent electrical circuits to analyze the effects of large parasitic impedances existing in all sample probes on four-terminal-pair measurements of the ac quantized Hall resistance RH. The circuit components include the externally measurable parasitic capacitances, inductances, lead resistances, and leakage resistances of ac quantized Hall resistance standards, as well as components that represent the electrical characteristics of the quantum Hall effect device (QHE). Two kinds of electrical circuit connections to the QHE are described and considered: single-series “offset” and quadruple-series. (We eliminated other connections in earlier analyses because they did not provide the desired accuracy with all sample probe leads attached at the device.) Exact, but complicated, algebraic equations are derived for the currents and measured quantized Hall voltages for these two circuits. Only the quadruple-series connection circuit meets our desired goal of measuring RH for both ac and dc currents with a one-standard-deviation uncertainty of 10−8 RH or less during the same cool-down with all leads attached at the device. The single-series “offset” connection circuit meets our other desired goal of also measuring the longitudinal resistance Rx for both ac and dc currents during that same cool-down. We will use these predictions to apply small measurable corrections, and uncertainties of the corrections, to ac measurements of RH in order to realize an intrinsic ac quantized Hall resistance standard of 10−8 RH uncertainty or less.

  2. Superconducting shielded core reactor with reduced AC losses

    DOEpatents

    Cha, Yung S.; Hull, John R.

    2006-04-04

    A superconducting shielded core reactor (SSCR) operates as a passive device for limiting excessive AC current in a circuit operating at a high power level under a fault condition such as shorting. The SSCR includes a ferromagnetic core which may be either closed or open (with an air gap) and extends into and through a superconducting tube or superconducting rings arranged in a stacked array. First and second series connected copper coils each disposed about a portion of the iron core are connected to the circuit to be protected and are respectively wound inside and outside of the superconducting tube or rings. A large impedance is inserted into the circuit by the core when the shielding capability of the superconducting arrangement is exceeded by the applied magnetic field generated by the two coils under a fault condition to limit the AC current in the circuit. The proposed SSCR also affords reduced AC loss compared to conventional SSCRs under continuous normal operation.

  3. Theory of the ac spin-valve effect.

    PubMed

    Kochan, Denis; Gmitra, Martin; Fabian, Jaroslav

    2011-10-21

    The spin-valve complex magnetoimpedance of symmetric ferromagnet-normal-metal-ferromagnet junctions is investigated within the drift-diffusion (standard) model of spin injection. The ac magnetoresistance-the real part difference of the impedances of the parallel and antiparallel magnetization configurations-exhibits an overall damped oscillatory behavior, as an interplay of the diffusion and spin relaxation times. In wide junctions the ac magnetoresistance oscillates between positive and negative values, reflecting resonant amplification and depletion of the spin accumulation, while the line shape for thin tunnel junctions is predicted to be purely Lorentzian. The ac spin-valve effect could be a technique to extract spin transport and spin relaxation parameters in the absence of a magnetic field and for a fixed sample size. PMID:22107552

  4. Tevatron AC dipole system

    SciTech Connect

    Miyamoto, R.; Kopp, S.E.; Jansson, A.; Syphers, M.J.; /Fermilab

    2007-06-01

    The AC dipole is an oscillating dipole magnet which can induce large amplitude oscillations without the emittance growth and decoherence. These properties make it a good tool to measure optics of a hadron synchrotron. The vertical AC dipole for the Tevatron is powered by an inexpensive high power audio amplifier since its operating frequency is approximately 20 kHz. The magnet is incorporated into a parallel resonant system to maximize the current. The use of a vertical pinger magnet which has been installed in the Tevatron made the cost relatively inexpensive. Recently, the initial system was upgraded with a more powerful amplifier and oscillation amplitudes up to 2-3{sigma} were achieved with the 980 GeV proton beam. This paper discusses details of the Tevatron AC dipole system and also shows its test results.

  5. AC-3 audio coder

    NASA Astrophysics Data System (ADS)

    Todd, Craig

    1995-12-01

    AC-3 is a system for coding up to 5.1 channels of audio into a low bit-rate data stream. High quality may be obtained with compression ratios approaching 12-1 for multichannel audio programs. The high compression ratio is achieved by methods which do not increase decoder memory, and thus cost. The methods employed include: the transmission of a high frequency resolution spectral envelope; and a novel forward/backward adaptive bit allocation algorithm. In order to satisfy practical requirements of an emissions coder, the AC-3 syntax includes a number of features useful to broadcasters and consumers. These features include: loudness uniformity between programs; dynamic range control; and broadcaster control of downmix coefficients. The AC-3 coder has been formally selected for inclusion of the U.S. HDTV broadcast standard, and has been informally selected for several additional applications.

  6. Level structure and reflection asymmetric shape in sup 223 Ac

    SciTech Connect

    Sheline, R.K.; Liang, C.F.; Paris, P. )

    1990-07-20

    Mass separated sources of {sup 227}Pa (separated as PaF{sub 4}{sup +} ions) were used to study the level structure of {sup 223}Ac following alpha decay. The levels in {sup 223}Ac are interpreted as K = 5/2{sup {plus minus}} parity doublet bands which occur naturally in reflection asymmetric models and the multiphonon octupole model. The anomalous structure of the K = 3/2{sup {minus}} band is explained in terms of Coriolis coupling. The low lying parity doublet bands in {sup 223}Ac, {sup 225}Ac, and {sup 227}Ac are compared and contrasted.

  7. Early Medication Nonadherence After Acute Myocardial Infarction: Insights into Actionable Opportunities from the TRANSLATE-ACS Study

    PubMed Central

    Mathews, Robin; Peterson, Eric D.; Honeycutt, Emily; Chin, Chee Tang; Effron, Mark B.; Zettler, Marjorie; Fonarow, Gregg C.; Henry, Timothy D.; Wang, Tracy Y.

    2015-01-01

    Background Nonadherence to prescribed evidence-based medications after acute myocardial infarction (MI) can contribute to worse outcomes and higher costs. We sought to better understand the modifiable factors contributing to early nonadherence of evidence-based medications after acute MI. Methods and Results We assessed 7,425 acute MI patients treated with percutaneous coronary intervention (PCI) at 216 United States hospitals participating in TRANSLATE-ACS between 04/2010–05/2012. Using the validated Morisky instrument to assess cardiovascular medication adherence at 6 weeks post-MI, we stratified patients into self-reported high (score 8), moderate (score 6–7), and low (score <6) adherence groups. Moderate and low adherence was reported in 25% and 4% of patients, respectively. One-third of low adherence patients described missing doses of antiplatelet therapy at least twice a week after PCI. Signs of depression and patient-reported financial hardship due to medication expenses were independently associated with a higher likelihood of medication nonadherence. Patients were more likely to be adherent at 6 weeks if they had follow-up appointments made prior to discharge and had a provider explain potential side effects of their medications. Lower medication adherence may be associated with a higher risk of 3-month death/readmission (adjusted HR 1.35, 95% CI 0.98, 1.87) although this did not reach statistical significance. Conclusions Even early after MI, a substantial proportion of patients report suboptimal adherence to prescribed medications. Tailored patient education and pre-discharge planning may represent actionable opportunities to optimize patient adherence and clinical outcomes. Clinical Trial Registry Information clinical trial #NCT01088503; URL: https://clinicaltrials.gov/ct2/show/NCT01088503 PMID:26038524

  8. Single HeLa and MCF-7 cell measurement using minimized impedance spectroscopy and microfluidic device

    NASA Astrophysics Data System (ADS)

    Wang, Min-Haw; Kao, Min-Feng; Jang, Ling-Sheng

    2011-06-01

    This study presents an impedance measurement system for single-cell capture and measurement. The microwell structure which utilizes nDEP force is used to single-cell capture and a minimized impedance spectroscopy which includes a power supply chip, an impedance measurement chip and a USB microcontroller chip is used to single-cell impedance measurement. To improve the measurement accuracy of the proposed system, Biquadratic fitting is used in this study. The measurement accuracy and reliability of the proposed system are compared to those of a conventional precision impedance analyzer. Moreover, a stable material, latex beads, is used to study the impedance measurement using the minimized impedance spectroscopy with cell-trapping device. Finally, the proposed system is used to measure the impedance of HeLa cells and MCF-7 cells. The impedance of single HeLa cells decreased from 9.55 × 103 to 3.36 × 103 Ω and the impedance of single MCF-7 cells decreased from 3.48 × 103 to 1.45 × 103 Ω at an operate voltage of 0.5 V when the excitation frequency was increased from 11 to 101 kHz. The results demonstrate that the proposed impedance measurement system successfully distinguishes HeLa cells and MCF-7 cells.

  9. ac bidirectional motor controller

    NASA Technical Reports Server (NTRS)

    Schreiner, K.

    1988-01-01

    Test data are presented and the design of a high-efficiency motor/generator controller at NASA-Lewis for use with the Space Station power system testbed is described. The bidirectional motor driver is a 20 kHz to variable frequency three-phase ac converter that operates from the high-frequency ac bus being designed for the Space Station. A zero-voltage-switching pulse-density-modulation technique is used in the converter to shape the low-frequency output waveform.

  10. Actinide sulfides in the gas phase: experimental and theoretical studies of the thermochemistry of AnS (An = Ac, Th, Pa, U, Np, Pu, Am and Cm).

    PubMed

    Pereira, Cláudia C L; Marsden, Colin J; Marçalo, Joaquim; Gibson, John K

    2011-07-28

    The gas-phase thermochemistry of actinide monosulfides, AnS, was investigated experimentally and theoretically. Fourier transform ion cyclotron resonance mass spectrometry was employed to study the reactivity of An(+) and AnO(+) (An = Th, Pa, U, Np, Pu, Am and Cm) with CS(2) and COS, as well as the reactivity of the produced AnS(+) with oxidants (COS, CO(2), CH(2)O and NO). From these experiments, An(+)-S bond dissociation energies could be bracketed. Density functional theory studies of the energetics of neutral and monocationic AnS (An = Ac, Th, Pa, U, Np, Pu, Am and Cm) provided values for bond dissociation energies and ionization energies; the computed energetics of neutral and monocationic AnO were also obtained for comparison. The theoretical data, together with comparisons with known An(+)-O bond dissociation energies and M(+)-S and M(+)-O dissociation energies for the early transition metals, allowed for the refining of the An(+)-S bond dissociation energy ranges obtained from experiment. Examination of the reactivity of AnS(+) with dienes, coupled to comparisons with reactivities of the AnO(+) analogues, systematic considerations and the theoretical results, allowed for the estimation of the ionization energies of the AnS; the bond dissociation energies of neutral AnS were consequently derived. Estimates for the case of AcS were also made, based on correlations of the data for the other An and the electronic energetics of neutral and ionic An. The nature of the bonding in the elementary molecular actinide chalcogenides (oxides and sulfides) is discussed, based on both the experimental data and the computed electronic structures. DFT calculations of ionization energies for the actinide atoms and the diatomic sulfides and oxides are relatively reliable, but the calculation of bond dissociation energies is not uniformly satisfactory, either with DFT or CCSD(T). A key conclusion from both the experimental and theoretical results is that the 5f electrons do not

  11. Actinide sulfides in the gas phase: experimental and theoretical studies of the thermochemistry of AnS (An = Ac, Th, Pa, U, Np, Pu, Am and Cm).

    PubMed

    Pereira, Cláudia C L; Marsden, Colin J; Marçalo, Joaquim; Gibson, John K

    2011-07-28

    The gas-phase thermochemistry of actinide monosulfides, AnS, was investigated experimentally and theoretically. Fourier transform ion cyclotron resonance mass spectrometry was employed to study the reactivity of An(+) and AnO(+) (An = Th, Pa, U, Np, Pu, Am and Cm) with CS(2) and COS, as well as the reactivity of the produced AnS(+) with oxidants (COS, CO(2), CH(2)O and NO). From these experiments, An(+)-S bond dissociation energies could be bracketed. Density functional theory studies of the energetics of neutral and monocationic AnS (An = Ac, Th, Pa, U, Np, Pu, Am and Cm) provided values for bond dissociation energies and ionization energies; the computed energetics of neutral and monocationic AnO were also obtained for comparison. The theoretical data, together with comparisons with known An(+)-O bond dissociation energies and M(+)-S and M(+)-O dissociation energies for the early transition metals, allowed for the refining of the An(+)-S bond dissociation energy ranges obtained from experiment. Examination of the reactivity of AnS(+) with dienes, coupled to comparisons with reactivities of the AnO(+) analogues, systematic considerations and the theoretical results, allowed for the estimation of the ionization energies of the AnS; the bond dissociation energies of neutral AnS were consequently derived. Estimates for the case of AcS were also made, based on correlations of the data for the other An and the electronic energetics of neutral and ionic An. The nature of the bonding in the elementary molecular actinide chalcogenides (oxides and sulfides) is discussed, based on both the experimental data and the computed electronic structures. DFT calculations of ionization energies for the actinide atoms and the diatomic sulfides and oxides are relatively reliable, but the calculation of bond dissociation energies is not uniformly satisfactory, either with DFT or CCSD(T). A key conclusion from both the experimental and theoretical results is that the 5f electrons do not

  12. The effects of pulmonary circulation pulsatility on the impedance cardiogram.

    PubMed

    Saito, Y; Goto, T; Terasaki, H; Hayashida, Y; Morioka, T

    1983-11-01

    To study the effects of pulmonary blood flow on the impedance cardiogram, the pattern of pulmonary blood flow was alternated from pulsatile to non pulsatile, or the reverse, using our extracorporeal bypass-method on anaesthetized dogs. The thoracic impedance cardiogram was recorded from band electrodes placed around the neck and upper abdomen. During nonpulsatile pulmonary blood flow, the height of the diastolic phase of the delta Z wave was lower than that during pulsatile pulmonary blood flow. The area under the impedance curve decreased during nonpulsatile pulmonary blood flow. This appeared to be more obvious as the pulmonary arterial flow was reduced. The results suggest that the pulmonary blood flow might have substantial effects on the impedance cardiogram.

  13. Impedance Calculations for the NSLS-II Storage Rings

    SciTech Connect

    Blednykh,A.; Ferreira, M.; Krinsky, S.

    2009-05-04

    Impedance of two vacuum chamber components, Bellows and BPM, is considered in some detail. In order to avoid generation of Higher-Order Modes (HOM's) in the NSLS-II bellows, we designed a new low-impedance RF shielding consisting of 6 wide and 2 narrow metal plates without opening slots between them. The short-range wakepotential has been optimized taking into account vertical offset of RF fingers from their nominal position. The results were compared with data of bellows designed at other laboratories. Narrow-band impedance of the BPM Button has been studied. TE-modes in the BPM button were suppressed by a factor of 8 by modification of existing housings. Two new types of housings are shown. The total impedance of the NSLS-II storage ring is discussed in terms of the loss factor and the vertical kick factor for a 3mm-Gaussian bunch.

  14. A quantitative skin impedance test to diagnose spinal cord injury

    PubMed Central

    Ugur, Mukden; Arslan, Yunus Ziya; Palamar, Deniz

    2009-01-01

    The purpose of this study was to develop a quantitative skin impedance test that could be used to diagnose spinal cord injury (SCI) if any, especially in unconscious and/or non-cooperative SCI patients. To achieve this goal, initially skin impedance of the sensory key points of the dermatomes (between C3 and S1 bilaterally) was measured in 15 traumatic SCI patients (13 paraplegics and 2 tetraplegics) and 15 control subjects. In order to classify impedance values and to observe whether there would be a significant difference between patient and subject impedances, an artificial neural network (ANN) with back-propagation algorithm was employed. Validation results of the ANN showed promising performance. It could classify traumatic SCI patients with a success rate of 73%. By assessing the experimental protocols and the validation results, the proposed method seemed to be a simple, objective, quantitative, non-invasive and non-expensive way of assessing SCI in such patients. PMID:19301045

  15. Deletion of AcMNPV ac146 eliminates the production of budded virus.

    PubMed

    Dickison, Virginia L; Willis, Leslie G; Sokal, Nadia R; Theilmann, David A

    Autographa californica multiple nucleopolyhedrovirus (AcMNPV) ac146 is a highly conserved gene in the Alpha- and Betabaculovirus genera that has an unknown function. Northern blot analysis and transcript mapping showed that ac146 is transcribed at late times post infection as a 1.2 kb mRNA. To determine the role of ac146 in the baculovirus life cycle ac146 knock out viruses were constructed. Transfection and plaque assays showed that all the ac146 deletions produced a single cell phenotype indicating that no infectious budded virus (BV) was produced, however occlusion bodies were formed. The lack of BV production was confirmed by viral titration utilizing both qPCR and TCID₅₀. Analysis of BV and occlusion derived virus (ODV) revealed that AC146 is associated with both forms of the virus and is modified specifically in ODV. This study therefore demonstrates that AC146 is a late virion associated protein and is essential for the viral life cycle.

  16. Tevatron optics measurements using an AC dipole

    SciTech Connect

    Miyamoto, R.; Kopp, S.E.; Jansson, A.; Syphers, M.J.; /Fermilab

    2007-06-01

    The AC dipole is a device to study beam optics of hadron synchrotrons. It can produce sustained large amplitude oscillations with virtually no emittance growth. A vertical AC dipole for the Tevatron is recently implemented and a maximum oscillation amplitude of 2{sigma} (4{sigma}) at 980 GeV (150 GeV) is achieved [1]. When such large oscillations are measured with the BPM system of the Tevatron (20 {micro}m resolution), not only linear but even nonlinear optics can be directly measured. This paper shows how to measure {beta} function using an AC dipole and the result is compared to the other measurement. The paper also shows a test to detect optics changes when small changes are made in the Tevatron. Since an AC dipole is nondestructive, it allows frequent measurements of the optics which is necessary for such an test.

  17. The AC-120: The advanced commercial transport

    NASA Technical Reports Server (NTRS)

    Duran, David; Griffin, Ernest; Mendoza, Saul; Nguyen, Son; Pickett, Tim; Noernberg, Clemm

    1993-01-01

    The main objective of this design was to fulfill a need for a new airplane to replace the aging 100 to 150 passenger, 1500 nautical mile range aircraft such as the Douglas DC9 and Boeing 737-100 airplanes. After researching the future aircraft market, conducting extensive trade studies, and analysis on different configurations, the AC-120 Advanced Commercial Transport final design was achieved. The AC-120's main design features include the incorporation of a three lifting surface configuration which is powered by two turboprop engines. The AC-120 is an economically sensitive aircraft which meets the new FM Stage Three noise requirements, and has lower NO(x) emissions than current turbofan powered airplanes. The AC-120 also improves on its contemporaries in passenger comfort, manufacturing, and operating cost.

  18. A Comparative Study on AC Conductivity and Dielectric Behavior of Multiwalled Carbon Nanotubes and Polyaniline Coated Multiwalled Carbon Nanotubes Filled High Density Polyethylene-Carbon Black Nanocomposites

    SciTech Connect

    Dinesh, P.; Renukappa, N. M.; Siddaramaiah; Lee, J. H.; Jeevananda, T.

    2010-10-04

    This paper presents an experimental investigation on AC conductivity and dielectric behavior of carbon black reinforced high density polyethylene (HDPE-CB) and HDPE-CB filled with multiwalled carbon nanotubes (MWNTs-CB-HDPE) and Polyaniline (PAni) coated MWNTs-CB-HDPE nanocomposites. The electrical properties such as dielectric constant ({epsilon}'), dissipation factor (tan {delta}) and AC conductivity ({sigma}{sub ac}) of nanocomposites have been measured with reference to the weight fraction (0.5 and 1 wt% MWNTs), frequency (75 KHz-30 MHz), temperature (25-90 deg. C) and sea water ageing. The experimental results showed that the increased AC conductivity and dielectric constant of the nanocomposites were influenced by PAni coated MWNTs in HDPE-CB nanocomposites. The value of dielectric constant and tan {delta} decreased with increasing frequency. Further more, above 5 MHz the AC conductivity increases drastically whereas significant effect on tan {delta} was observed in less than 1 MHz.

  19. Electrical impedance measurements of root canal length.

    PubMed

    Meredith, N; Gulabivala, K

    1997-06-01

    Electronic methods are now widely used during endodontic treatment for the assessment of root canal length. These commonly measure the electrical resistance or impedance between the root canal and the buccal mucosa. A number of studies have been undertaken to determine the accuracy of commercially available instruments. The aims of this investigation were to determine the electrical impedance characteristics of the root canal and periapical tissues in vivo, measure the changes relative to the distance of an endodontic instrument from the apical constriction and propose an equivalent circuit modelling the periapical tissues. The length of the root canals of 20 previously untreated teeth were determined using radiographic and electronic methods. Minimal canal preparation was carried out and measurements were made with a size 10 K-Flex file. A microprocessor-controlled LCR analyser was used to measure the electrical impedance characteristics of each root canal. The instrument measured the series and parallel resistive (RS, RP) and capacitance (CS, CP) component of the tissues at two test frequencies, 100 Hz and 1 kHz. Measurements were made for each root canal when the diagnostic file was placed at the apical constriction and repeated when the file was withdrawn to -0.5, -1.0, -1.5, -2.0 and -5.0 mm from the foramen. Readings were taken for each canal after the canal had been dried with paper points, and flooded first with deionised water and then with sodium hypochlorite. The root canals were then prepared, cleaned and obturated using standard endodontic procedures. The LCR analyser selected the series resistance component as the major measurement parameter. There was a clear increase in series resistance (RS) with increasing distance from the radiographic apex for dry canals and those containing deionised water and sodium hypochlorite. The mean resistance for dry canals was markedly higher than for those containing fluid, ranging from 22.19 k omega to 92.07 k omega

  20. Damage detection technique by measuring laser-based mechanical impedance

    SciTech Connect

    Lee, Hyeonseok; Sohn, Hoon

    2014-02-18

    This study proposes a method for measurement of mechanical impedance using noncontact laser ultrasound. The measurement of mechanical impedance has been of great interest in nondestructive testing (NDT) or structural health monitoring (SHM) since mechanical impedance is sensitive even to small-sized structural defects. Conventional impedance measurements, however, have been based on electromechanical impedance (EMI) using contact-type piezoelectric transducers, which show deteriorated performances induced by the effects of a) Curie temperature limitations, b) electromagnetic interference (EMI), c) bonding layers and etc. This study aims to tackle the limitations of conventional EMI measurement by utilizing laser-based mechanical impedance (LMI) measurement. The LMI response, which is equivalent to a steady-state ultrasound response, is generated by shooting the pulse laser beam to the target structure, and is acquired by measuring the out-of-plane velocity using a laser vibrometer. The formation of the LMI response is observed through the thermo-mechanical finite element analysis. The feasibility of applying the LMI technique for damage detection is experimentally verified using a pipe specimen under high temperature environment.

  1. Electrochemical impedance spectroscopy study on the corrosion of the weld zone of 3Cr steel welded joints in CO2 environments

    NASA Astrophysics Data System (ADS)

    Xu, Li-ning; Zhu, Jin-yang; Lu, Min-xu; Zhang, Lei; Chang, Wei

    2015-05-01

    The welded joints of 3Cr pipeline steel were fabricated with commercial welding wire using the gas tungsten arc welding (GTAW) technique. Potentiodynamic polarization curves, linear polarization resistance (LPR), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), and energy-dispersive spectrometry (EDS) were used to investigate the corrosion resistance and the growth of a corrosion film on the weld zone (WZ). The changes in electrochemical characteristics of the film were obtained through fitting of the EIS data. The results showed that the average corrosion rate of the WZ in CO2 environments first increased, then fluctuated, and finally decreased gradually. The formation of the film on the WZ was divided into three stages: dynamic adsorption, incomplete-coverage layer formation, and integral layer formation.

  2. Field and laboratory studies on the impact of two Bt rice lines expressing a fusion protein Cry1Ab/1Ac on aquatic organisms.

    PubMed

    Wang, Yongmo; Huang, Jiacheng; Hu, Huawei; Li, Jianhong; Liu, Biao; Zhang, Guoan

    2013-06-01

    Genetically modified (GM) rice expressing Bt toxins is at the edge of commercial release in China. However, little information is available concerning the impact of Bt rice on aquatic organisms which are abundant in paddy field. A two-year study was conducted to assess the effects of two GM rice lines expressing a fusion protein Cry1Ab/1Ac (Bt rice) on three groups of zooplankton, rotifers, cladocerans and copepods in field conditions. Multi-factor ANOVA revealed that the population densities of rotifers, cladocerans and copepods in paddy field varied significantly between years and rice developmental stages, but did not differ significantly between Bt and non-Bt rice treatments. In all the field investigations, only one significant difference was found on copepods in the tillering stage of 2009, but the difference was not related to the presence of the Cry toxin. Under open-air conditions, we simulated the farming practice of straw mulch, using Bt rice straw as a food source for the water flea Daphnia hyalina. After one and two months of culture, the density of D. hyalina did not differ between Bt rice treatments and non-Bt rice treatments. A laboratory experiment found that purified Bt toxins Cry1Ab and Cry1Ac had no toxic effect on D. hyalina even in the treatment in which the Bt toxin concentration was as high as 2500ng/ml. Those above results indicate that the two Bt rice lines have no negative effect on the three groups of zooplankton. However, further studies are needed to compare the effects of Bt rice and non-Bt rice on the paddy zooplankton community in the context of integrated pest management which includes the use of pesticides. PMID:23523003

  3. Time and frequency dependence of disposable ECG electrode-skin impedance.

    PubMed

    Olson, W H; Schmincke, D R; Henley, B L

    1979-01-01

    The magnitude and phase of disposable electrode-skin impedance were studied as functions of time, 0-48 hours, and frequency, 1 Hz-1 kHz. For both unabraded and mildly abraded skin, the impedance decreased as a function of time steadily or exponentially with time constants of several hours. Impedance decreased as a function of frequency by factors of 2 to 20 with greatest change at low frequencies. For heavily abraded skin, the impedance decreased slightly and then increased as a function of time especially at low frequencies. Impedance imbalance between pairs of identical electrodes applied in a like manner to the forearm were often greater than k omega, nearly equal to individual electrode-skin impedances, and decreased with time. Electrode impedance imbalance is particularly important because it affects noise levels in ECG recordings.

  4. The quantum Hall impedance standard

    NASA Astrophysics Data System (ADS)

    Schurr, J.; Kučera, J.; Pierz, K.; Kibble, B. P.

    2011-02-01

    Alternating current measurements of double-shielded quantum Hall devices have revealed a fascinating property of which only a quantum effect is capable: it can detect its own frequency dependence and convert it to a current dependence which can be used to eliminate both of them. According to an experimentally verified model, the residual frequency dependence is smaller than the measuring uncertainty of 1.3 × 10-9 kHz-1. In this way, a highly precise quantum standard of impedance can be established, without having to correct for any calculated frequency dependence and without the need for any artefact with a calculated frequency dependence. Nothing else like that is known to us and we hope that our results encourage other national metrology institutes to also apply it to impedance metrology and further explore its beautiful properties.

  5. 21 CFR 870.2750 - Impedance phlebograph.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Impedance phlebograph. 870.2750 Section 870.2750...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2750 Impedance phlebograph. (a) Identification. An impedance phlebograph is a device used to provide a visual display of...

  6. 21 CFR 870.2750 - Impedance phlebograph.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Impedance phlebograph. 870.2750 Section 870.2750...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2750 Impedance phlebograph. (a) Identification. An impedance phlebograph is a device used to provide a visual display of...

  7. 21 CFR 870.2770 - Impedance plethysmograph.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false Impedance plethysmograph. 870.2770 Section 870...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2770 Impedance plethysmograph. (a) Identification. An impedance plethysmograph is a device used to estimate peripheral...

  8. 21 CFR 870.2770 - Impedance plethysmograph.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Impedance plethysmograph. 870.2770 Section 870...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2770 Impedance plethysmograph. (a) Identification. An impedance plethysmograph is a device used to estimate peripheral...

  9. 21 CFR 870.2750 - Impedance phlebograph.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Impedance phlebograph. 870.2750 Section 870.2750...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2750 Impedance phlebograph. (a) Identification. An impedance phlebograph is a device used to provide a visual display of...

  10. 21 CFR 870.2750 - Impedance phlebograph.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false Impedance phlebograph. 870.2750 Section 870.2750...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2750 Impedance phlebograph. (a) Identification. An impedance phlebograph is a device used to provide a visual display of...

  11. 21 CFR 870.2770 - Impedance plethysmograph.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false Impedance plethysmograph. 870.2770 Section 870...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2770 Impedance plethysmograph. (a) Identification. An impedance plethysmograph is a device used to estimate peripheral...

  12. 21 CFR 870.2770 - Impedance plethysmograph.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false Impedance plethysmograph. 870.2770 Section 870...) MEDICAL DEVICES CARDIOVASCULAR DEVICES Cardiovascular Monitoring Devices § 870.2770 Impedance plethysmograph. (a) Identification. An impedance plethysmograph is a device used to estimate peripheral...

  13. [Research on Electrical Impedance Tomography Technology].

    PubMed

    Chang, Feiba; Zhang, Hehua; Yan, Lexian; Yin, Jun

    2016-01-01

    This article reviews the principle of electrical impedance tomography imaging and measurement system; focuses on electrical impedance tomography imaging detection system of incentive mode and several typical image reconstruction algorithm of electrical impedance imaging; and objectively compares and effectively evaluates several image reconstruction algorithm.

  14. Feasibility of Bioelectrical Impedance Spectroscopy Measurement before and after Thoracentesis

    PubMed Central

    Weyer, Sören; Pauly, Karolin; Napp, Andreas; Dreher, Michael; Leonhardt, Steffen; Marx, Nikolaus; Schauerte, Patrick; Mischke, Karl

    2015-01-01

    Background. Bioelectrical impedance spectroscopy is applied to measure changes in tissue composition. The aim of this study was to evaluate its feasibility in measuring the fluid shift after thoracentesis in patients with pleural effusion. Methods. 45 participants (21 with pleural effusion and 24 healthy subjects) were included. Bioelectrical impedance was analyzed for “Transthoracic,” “Foot to Foot,” “Foot to Hand,” and “Hand to Hand” vectors in low and high frequency domain before and after thoracentesis. Healthy subjects were measured at a single time point. Results. The mean volume of removed pleural effusion was 1169 ± 513 mL. The “Foot to Foot,” “Hand to Hand,” and “Foot to Hand” vector indicated a trend for increased bioelectrical impedance after thoracentesis. Values for the low frequency domain in the “Transthoracic” vector increased significantly (P < 0.001). A moderate correlation was observed between the amount of removed fluid and impedance change in the low frequency domain using the “Foot to Hand” vector (r = −0.7). Conclusion. Bioelectrical impedance changes in correlation with the thoracic fluid level. It was feasible to monitor significant fluid shifts and loss after thoracentesis in the “Transthoracic” vector by means of bioelectrical impedance spectroscopy. The trial is registered with Registration Numbers IRB EK206/11 and NCT01778270. PMID:25861647

  15. Impedance Spectroscopy of Human Erythrocytes: Constant Phase Angle Characteristics and a Membrane Phase Transition

    NASA Astrophysics Data System (ADS)

    Bao, Jian-Zhong

    Impedance spectroscopy can be used as a tool for studying the structure of materials, including living cells. The measurements of the electrical impedance of human erythrocytes in the frequency range from 1 Hz to 10 MHz, and for temperatures from 4^circC to 40 ^circC are presented in this dissertation. In order to achieve high sensitivity in this frequency range, we embedded the cells in the pores of a filter, which constrains the current to pass through the cells in the pores and forces the cells into a well defined geometric form. To correct the measurement errors, we extend a calibration procedure to include both real and imaginary parts of the impedance to obtain a complete calibration, and we have proved that this improved calibration procedure works successfully. Based on the geometry of the cells embedded in the filter a circuit model is proposed for the cell-filter -electrolyte system. A constant-phase-angle (CPA) element, i.e., an impedance of the form Z = A/(jomega) ^{alpha}, where A is a constant, j = sqrt{-1}, omega is angular frequency, and 0 < alpha < 1, has been used to describe the ac response of the interface between the cell surface and the electrolyte solution, i.e., the electrical double layer. CPA element is believed to be closely related to the fractal structure of the interface, with alpha approaching one when the interface becomes increasingly smooth. The CPA and other elements of the circuit model are determined by a complex non-linear least squares (CNLS) fit, which simultaneously fits the real and imaginary parts of the experimental data to the circuit model. The specific membrane capacitance is determined to be 0.901 +/- 0.036 muF/cm ^2, and the specific cytoplasm conductivity to be 0.413 +/- 0.031 S/m at 26 ^circC, which are in good agreement with published data. The temperature dependence of the cytoplasm conductivity, membrane capacitance, and CPA element has been obtained. The membrane capacitance increases markedly at about 37^circ

  16. Dielectric and complex impedance properties of tetravalent hafnium (HF 4+) integrated cobalt ferrite

    NASA Astrophysics Data System (ADS)

    Sanchez, Luis

    The work presented in this thesis was carried out to understand the effects of tetravalent hafnium (Hf4+) ion on the crystal structure and phase, surface morphology, electrical, dielectric and complex impedance properties of cobalt ferrite (CoFe2O4; CFO). Hafnium incorporated cobalt ferrite, CoFe2-xHfxO4, with x = 0.00, 0.05, 0.075, 0.10, 0.15 and 0.20 were prepared by the standard solid state ceramic synthesis method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) characterizations were performed to determine the structural properties. Most important aspect of this study is to explore the dielectric and complex impedance properties as a function of variable temperature (T=300-1000 K) and frequency (f=20 Hz -1 MHz). Room temperature and the temperature dependence of dielectric constant, loss factor, complex impedance, and the ac resistivity measurements enabled us to understand the effect of temperature and frequency on the electrical and dielectric properties on CoFe2-xHfxO4 and, thus, to derive structure-property relation. X-ray diffraction (XRD) patterns for Hf-incorporated CFO confirm the formation of majority of CFO spinel [with space group Fd3m (227)] phase, in addition to the small amount of HfO2 monoclinic [space group, P1 21/c (14)] phase leading to formation of CFO-Hf composites. The lattice constant values derived from XRD for CFO-Hf were found to increase from 8.374 A (x = 0.000) to 8.391 A (x = 0.200). The lattice expansion is significant at the very first step of Hf-incorporation and then slows down with progressive Hf-incorporation. SEM imaging analysis indicates that Hf resides at the grain boundaries for CFO-Hf. The dielectric constant (epsilon') of CFO-Hf is T-independent at T<450 K, at which point increasing trend prevails. A grain bulk-boundary based two-layer model, where semiconducting-grains separated by insulating-grain boundaries, satisfactorily accounts for epsilon- T (>450 K) variation. Correspondingly, electrical

  17. Electron density dependence of impedance probe plasma potential measurements

    SciTech Connect

    Walker, D. N.; Blackwell, D. D.; Amatucci, W. E.

    2015-08-15

    In earlier works, we used spheres of various sizes as impedance probes in demonstrating a method of determining plasma potential, φ{sub p}, when the probe radius is much larger than the Debye length, λ{sub D}. The basis of the method in those works [Walker et al., Phys. Plasmas 13, 032108 (2006); ibid. 15, 123506 (2008); ibid. 17, 113503 (2010)] relies on applying a small amplitude signal of fixed frequency to a probe in a plasma and, through network analyzer-based measurements, determining the complex reflection coefficient, Γ, for varying probe bias, V{sub b}. The frequency range of the applied signal is restricted to avoid sheath resonant effects and ion contributions such that ω{sub pi} ≪ ω ≪ ω{sub pe}, where ω{sub pi} is the ion plasma frequency and ω{sub pe} is the electron plasma frequency. For a given frequency and applied bias, both Re(Z{sub ac}) and Im(Z{sub ac}) are available from Γ. When Re(Z{sub ac}) is plotted versus V{sub b}, a minimum predicted by theory occurs at φ{sub p} [Walker et al., Phys. Plasmas 17, 113503 (2010)]. In addition, Im(Z{sub ac}) appears at, or very near, a maximum at φ{sub p}. As n{sub e} decreases and the sheath expands, the minimum becomes harder to discern. The purpose of this work is to demonstrate that when using network analyzer-based measurements, Γ itself and Im(Z{sub ac}) and their derivatives are useful as accompanying indicators to Re(Z{sub ac}) in these difficult cases. We note the difficulties encountered by the most commonly used plasma diagnostic, the Langmuir probe. Spherical probe data is mainly used in this work, although we present limited data for a cylinder and a disk. To demonstrate the effect of lowered density as a function of probe geometry, we compare the cylinder and disk using only the indicator Re(Z{sub ac})

  18. Constant current loop impedance measuring system that is immune to the effects of parasitic impedances

    NASA Technical Reports Server (NTRS)

    Anderson, Karl F. (Inventor)

    1994-01-01

    A constant current loop measuring system is provided for measuring a characteristic of an environment. The system comprises a first impedance positionable in the environment, a second impedance coupled in series with said first impedance and a parasitic impedance electrically coupled to the first and second impedances. A current generating device, electrically coupled in series with the first and second impedances, provides a constant current through the first and second impedances to produce first and second voltages across the first and second impedances, respectively, and a parasitic voltage across the parasitic impedance. A high impedance voltage measuring device measures a voltage difference between the first and second voltages independent of the parasitic voltage to produce a characteristic voltage representative of the characteristic of the environment.

  19. Effect of Electrode Belt and Body Positions on Regional Pulmonary Ventilation- and Perfusion-Related Impedance Changes Measured by Electric Impedance Tomography

    PubMed Central

    Ericsson, Elin; Tesselaar, Erik; Sjöberg, Folke

    2016-01-01

    Ventilator-induced or ventilator-associated lung injury (VILI/VALI) is common and there is an increasing demand for a tool that can optimize ventilator settings. Electrical impedance tomography (EIT) can detect changes in impedance caused by pulmonary ventilation and perfusion, but the effect of changes in the position of the body and in the placing of the electrode belt on the impedance signal have not to our knowledge been thoroughly evaluated. We therefore studied ventilation-related and perfusion-related changes in impedance during spontaneous breathing in 10 healthy subjects in five different body positions and with the electrode belt placed at three different thoracic positions using a 32-electrode EIT system. We found differences between regions of interest that could be attributed to changes in the position of the body, and differences in impedance amplitudes when the position of the electrode belt was changed. Ventilation-related changes in impedance could therefore be related to changes in the position of both the body and the electrode belt. Perfusion-related changes in impedance were probably related to the interference of major vessels. While these findings give us some insight into the sources of variation in impedance signals as a result of changes in the positions of both the body and the electrode belt, further studies on the origin of the perfusion-related impedance signal are needed to improve EIT further as a tool for the monitoring of pulmonary ventilation and perfusion. PMID:27253433

  20. Impedance analysis of an enhanced piezoelectric biosensor

    NASA Astrophysics Data System (ADS)

    Kim, Gi-Ho

    This study investigated the usefulness and characteristics of a five-megahertz quartz crystal resonator oscillating in a thickness-shear mode as a sensor of biological pathogens such as Salmonella typhimurium . An impedance analyzer measured the impedance of the oscillating quartz crystal, which determined all mechanical properties of the oscillating quartz and its immediate environment. In this study, the impedance behavior of the bare crystal was characterized in air and in potassium phosphate buffer solution. The potassium phosphate buffer was a Newtonian liquid. The resonance frequency of the oscillating quartz shifted down about 900 Hz by contacting with the buffer. An immobilized-antibody layer on the quartz surface behaved like a rigid mass when immersed in the buffer solution. The quartz crystal with immobilized antibodies was characterized in various solutions containing antibody- coated paramagnetic microspheres and varying concentrations of Salmonella typhimurium (102 - 108 cells/ml). The Salmonella cells were captured by antibody- coated paramagnetic microspheres, and then these complexes were moved magnetically to the oscillating quartz and were captured by antibodies immobilized on the crystal surface. The response of the crystal was expressed in terms of equivalent circuit parameters. The motional inductance and the motional resistance increased as a function of the concentration of Salmonella. The viscous damping was the main contribution to the resistance and the inductance in a liquid environment. The load resistance was the most effective and sensitive circuit parameter. A magnetic force was a useful method to collect the complexes of Salmonella-microspheres on the crystal surface and enhance the response sensor. In this system, the detection limit, based on resistance monitoring, was about 103 cells/ml.

  1. AC power systems handbook

    SciTech Connect

    Whitaker, J.

    1991-01-01

    Transient disturbances are what headaches are made of. Whatever you call them-spikes, surges, are power bumps-they can take your equipment down and leave you with a complicated and expensive repair job. Protection against transient disturbances is a science that demands attention to detail. This book explains how the power distribution system works, what can go wrong with it, and how to protect a facility against abnormalities. system grounding and shielding are covered in detail. Each major method of transient protection is analyzed and its relative merits discussed. The book provides a complete look at the critical elements of the ac power system. Provides a complete look at the ac power system from generation to consumption. Discusses the mechanisms that produce transient disturbances and how to protect against them. Presents diagrams to facilitate system design. Covers new areas, such as the extent of the transient disturbance problem, transient protection options, and stand-by power systems.

  2. A study on reintegration of street children in Burundi: experienced violence and maltreatment are associated with mental health impairments and impeded educational progress.

    PubMed

    Crombach, Anselm; Bambonyé, Manassé; Elbert, Thomas

    2014-01-01

    Street children are exposed to violence, and subsist in poor and generally precarious conditions. In conflict regions, institutional care facilities are often the only well established way to care for vulnerable children. Providing access to school education is considered to be key to allow successful integration into society. However, adverse effects of psychological disorders may pose another serious obstacle. In semi-structured interviews in a sample of 112 Burundian male youths (mean age = 15.9 years), we assessed exposure to traumatic stressors, regularly and recently occurring violence as well as prevalence of posttraumatic stress disorder (PTSD), depression, substance dependence, suicidal risk, and progress in school. Former street children (n = 32) and other vulnerable children (n = 50) in a residential center were compared to children living in the streets (n = 15) or with families (n = 15). While the children living in the center were less regularly exposed to violence and reported less substance dependence than street children, PTSD symptoms were common among the former street children. Furthermore, we provided empirical evidence that for the children living in the center, recently experienced violence - mostly minor physical conflicts, psychological violence and neglect - was associated with increased PTSD symptomatology and impeded progress in school. In a population of children who experienced many traumatic incidences and a lot of violence, even minor violent events may trigger and reinforce PTSD symptoms. Hence controlling exposure to violence and addressing mental ill-health in vulnerable children is mandatory for reintegration.

  3. Study of low concentration CO poisoning of Pt anode in a proton exchange membrane fuel cell using spatial electrochemical impedance spectroscopy

    NASA Astrophysics Data System (ADS)

    Reshetenko, Tatyana V.; Bethune, Keith; Rubio, Miguel A.; Rocheleau, Richard

    2014-12-01

    This paper presents experimental and modeling results of the effect of low CO concentration (2 ppm) on the spatial performance of PEMFC as well as its spatial electrochemical impedance spectroscopy (EIS) responses. The cell was operated at constant current using various cathode gases: air, O2 and H2. Due to CO adsorption on the Pt anode and its poisoning, the cell voltage decreased and spatial current redistribution was observed. The steady state voltage losses were 0.089, 0.280 and 0.295 V for the H2/O2, H2/air and H2/H2 gas configurations, respectively. EIS data revealed a pseudo-inductive behavior in the low frequency region for inlet segments of the cell operated under H2/air and H2/H2 conditions. Operation with O2 as an oxidant did not cause any pseudo-inductance. Analysis of the EIS and anode overpotential data suggested that CO oxidation occurred via chemical or electrochemical mechanisms, or a combination of both depending on the selected cathode gas. The spatial EIS data were analyzed using the equivalent electric circuits approach. The distributions of the equivalent electric circuit parameters are presented and discussed. A current distribution model and EIS interpolation technique were successfully applied for detailed analysis of CO effects on the spatial PEMFC performance and EIS.

  4. A study on reintegration of street children in Burundi: experienced violence and maltreatment are associated with mental health impairments and impeded educational progress

    PubMed Central

    Crombach, Anselm; Bambonyé, Manassé; Elbert, Thomas

    2014-01-01

    Street children are exposed to violence, and subsist in poor and generally precarious conditions. In conflict regions, institutional care facilities are often the only well established way to care for vulnerable children. Providing access to school education is considered to be key to allow successful integration into society. However, adverse effects of psychological disorders may pose another serious obstacle. In semi-structured interviews in a sample of 112 Burundian male youths (mean age = 15.9 years), we assessed exposure to traumatic stressors, regularly and recently occurring violence as well as prevalence of posttraumatic stress disorder (PTSD), depression, substance dependence, suicidal risk, and progress in school. Former street children (n = 32) and other vulnerable children (n = 50) in a residential center were compared to children living in the streets (n = 15) or with families (n = 15). While the children living in the center were less regularly exposed to violence and reported less substance dependence than street children, PTSD symptoms were common among the former street children. Furthermore, we provided empirical evidence that for the children living in the center, recently experienced violence – mostly minor physical conflicts, psychological violence and neglect – was associated with increased PTSD symptomatology and impeded progress in school. In a population of children who experienced many traumatic incidences and a lot of violence, even minor violent events may trigger and reinforce PTSD symptoms. Hence controlling exposure to violence and addressing mental ill-health in vulnerable children is mandatory for reintegration. PMID:25566123

  5. Electrolyte ion adsorption and charge blocking effect at the hematite/aqueous solution interface: an electrochemical impedance study using multivariate data analysis.

    PubMed

    Shimizu, K; Nyström, J; Geladi, P; Lindholm-Sethson, B; Boily, J-F

    2015-05-01

    A model-free multivariate analysis using singular value decomposition is employed to refine an equivalent electrical circuit model in order to probe the electrochemical properties of the hematite/water interface in dilute NaCl and NH4Cl solutions using electrochemical impedance spectroscopy. The result shows that the surface protonation is directly related to the mobility and trapping of charge carriers at the mineral surface. Moreover, the point of zero charge can be found at pH where the charge transfer resistance is the highest, in addition to the minimum double layer capacitance. The inner-sphere interaction of the NH4(+) ion with the surface is indicated by an increase of capacitance for charge carrier trapping from the protonated surface as well as lower double layer capacitance and open circuit potential. It is clear that the intrinsic electrochemical activity of hematite depends on the degree of surface (de)protonation and other inner-sphere adsorption, as these processes affect the charge carrier density in the surface state. This work also highlights an important synergistic effect of the two spectral analyses that enables EIS to be utilized in an in-depth investigation of mineral/water interfaces. PMID:25857599

  6. Preliminary Results on Different Impedance Contrast Agents for Pulmonary Perfusion Imaging with Electrical Impedance Tomography

    NASA Astrophysics Data System (ADS)

    Nguyen, D. T.; Kosobrodov, R.; Barry, M. A.; Chik, W.; Pouliopoulos, J.; Oh, T. I.; Thiagalingam, A.; McEwan, A.

    2013-04-01

    Recent studies in animal models suggest that the use of small volume boluses of NaCl as an impedance contrast agent can significantly improve pulmonary perfusion imaging by Electrical Impedance Tomography (EIT). However, these studies used highly concentrated NaCl solution (20%) which may have adverse effects on the patients. In a pilot experiment, we address this problem by comparing a number of different Impedance Contrast Boluses (ICBs). Conductivity changes in the lungs of a sheep after the injection of four different ICBs were compared, including three NaCl-based ICBs and one glucose-based ICB. The following procedure was followed for each ICB. Firstly, ventilation was turned off to provide an apneic window of approximately 40s to image the conductivity changes due to the ICB. Each ICB was then injected through a pig-tail catheter directly into the right atrium. EIT images were acquired throughout the apnea to capture the conductivity change. For each ICB, the experiment was repeated three times. The three NaCl-based ICB exhibited similar behaviour in which following the injection of each of these ICBs, the conductivity of each lung predictably increased. The effect of the ICB of 5% glucose solution was inconclusive. A small decrease in conductivity in the left lung was observed in two out of three cases and none was discernible in the right lung.

  7. Impedance spectroscopy of food mycotoxins

    NASA Astrophysics Data System (ADS)

    Bilyy, Oleksandr I.; Yaremyk, Roman Ya.; Kotsyumbas, Ihor Ya.; Kotsyumbas, Halyna I.

    2012-01-01

    A new analytical method of high-selective detection of mycotoxins in food and feed are considered. A method is based on optical registration the changes of conduct of the electric polarized bacterial agents in solution at the action of the external gradient electric fields. Measuring are conducted in integrated electrode-optical cuvette of the special construction, which provides the photometric analysis of forward motion of the objects registration in liquid solution under act of the enclosed electric field and simultaneous registration of kinetics of change of electrical impedance parameters solution and electrode system.

  8. DIFFERENTIAL SOIL IMPEDANCE OBSTACLE DETECTION

    SciTech Connect

    Maximillian J. Kieba; Christopher J. Ziolkowski

    2004-06-30

    This project develops a new and unique obstacle detection sensor for horizontal directional drilling (HDD) equipment. The development of this new technology will greatly improve the reliability and safety of natural gas HDD construction practices. This sensor utilizes a differential soil impedance measurement technique that will be sensitive to the presence of plastic and ceramic, as well as metallic obstacles. The use of HDD equipment has risen significantly in the gas industry because HDD provides a much more cost-effective and less disruptive method for gas pipe installation than older, trenching methods. However, there have been isolated strikes of underground utilities by HDD equipment, which may have been avoided if methods were available to detect other underground obstacles when using HDD systems. GTI advisors from the gas industry have ranked the value of solving the obstacle detection problem as the most important research and development project for GTI to pursue using Federal Energy Regulatory Commission (FERC) funds available through its industry partner, GRI. GTI proposes to develop a prototype down-hole sensor system that is simple and compact. The sensor utilizes an impedance measurement technique that is sensitive to the presence of metallic or nonmetallic objects in the proximity of the HDD head. The system will use a simple sensor incorporated into the drill head. The impedance of the soil will be measured with a low frequency signal injected through the drill head itself. A pair of bridge type impedance sensors, mounted orthogonal to one another, is coupled to the soil. Inclusions in the soil will cause changes to the sensor balance distinguishable from homogeneous soil. The sensor will provide range and direction data for obstacles near the HDD head. The goal is to provide a simple, robust system that provides the information required to avoid obstacles. This must be done within the size and ruggedness constraints of the HDD equipment. Imaging

  9. DIFFERENTIAL SOIL IMPEDANCE OBSTACLE DETECTION

    SciTech Connect

    Maximillian J. Kieba

    2003-10-01

    This project develops a new and unique obstacle detection sensor for horizontal directional drilling (HDD) equipment. The development of this new technology will greatly improve the reliability and safety of natural gas HDD construction practices. This sensor utilizes a differential soil impedance measurement technique that will be sensitive to the presence of plastic and ceramic, as well as metallic obstacles. The use of HDD equipment has risen significantly in the gas industry because HDD provides a much more cost-effective and less disruptive method for gas pipe installation than older, trenching methods. However, there have been isolated strikes of underground utilities by HDD equipment, which may have been avoided if methods were available to detect other underground obstacles when using HDD systems. GTI advisors from the gas industry have ranked the value of solving the obstacle detection problem as the most important research and development project for GTI to pursue using Federal Energy Regulatory Commission (FERC) funds available through its industry partner, GRI. GTI proposes to develop a prototype down-hole sensor system that is simple and compact. The sensor utilizes an impedance measurement technique that is sensitive to the presence of metallic or nonmetallic objects in the proximity of the HDD head. The system will use a simple sensor incorporated into the drill head. The impedance of the soil will be measured with a low frequency signal injected through the drill head itself. A pair of bridge type impedance sensors, mounted orthogonal to one another, is coupled to the soil. Inclusions in the soil will cause changes to the sensor balance distinguishable from homogeneous soil. The sensor will provide range and direction data for obstacles near the HDD head. The goal is to provide a simple, robust system that provides the information required to avoid obstacles. This must be done within the size and ruggedness constraints of the HDD equipment. Imaging

  10. DIFFERENTIAL SOIL IMPEDANCE OBSTACLE DETECTION

    SciTech Connect

    Maximillian J. Kieba

    2003-04-01

    This project develops a new and unique obstacle detection sensor for horizontal directional drilling (HDD) equipment. The development of this new technology will greatly improve the reliability and safety of natural gas HDD construction practices. This sensor utilizes a differential soil impedance measurement technique that will be sensitive to the presence of plastic and ceramic, as well as metallic obstacles. The use of HDD equipment has risen significantly in the gas industry because HDD provides a much more cost-effective and less disruptive method for gas pipe installation than older, trenching methods. However, there have been isolated strikes of underground utilities by HDD equipment, which may have been avoided if methods were available to detect other underground obstacles when using HDD systems. GTI advisors from the gas industry have ranked the value of solving the obstacle detection problem as the most important research and development project for GTI to pursue using Federal Energy Regulatory Commission (FERC) funds available through its industry partner, GRI. GTI proposes to develop a prototype down-hole sensor system that is simple and compact. The sensor utilizes an impedance measurement technique that is sensitive to the presence of metallic or nonmetallic objects in the proximity of the HDD head. The system will use a thin film sensor conformal with the drill head. The impedance of the soil will be measured with a low frequency signal injected through the drill head itself. A pair of bridge type impedance sensors, mounted orthogonal to one another, is capacitively coupled to the soil. Inclusions in the soil will cause changes to the sensor balance distinguishable from homogeneous soil. The sensor will provide range and direction data for obstacles near the HDD head. The goal is to provide a simple, robust system that provides the information required to avoid obstacles. This must be done within the size and ruggedness constraints of the HDD

  11. DIFFERENTIAL SOIL IMPEDANCE OBSTACLE DETECTION

    SciTech Connect

    Maximillian J. Kieba

    2003-01-30

    This project develops a new and unique obstacle detection sensor for horizontal directional drilling (HDD) equipment. The development of this new technology will greatly improve the reliability and safety of natural gas HDD construction practices. This sensor utilizes a differential soil impedance measurement technique that will be sensitive to the presence of plastic and ceramic, as well as metallic obstacles. The use of HDD equipment has risen significantly in the gas industry because HDD provides a much more cost-effective and less disruptive method for gas pipe installation than older, trenching methods. However, there have been isolated strikes of underground utilities by HDD equipment, which may have been avoided if methods were available to detect other underground obstacles when using HDD systems. GTI advisors from the gas industry have ranked the value of solving the obstacle detection problem as the most important research and development project for GTI to pursue using Federal Energy Regulatory Commission (FERC) funds available through its industry partner, GRI. GTI proposes to develop a prototype down-hole sensor system that is simple and compact. The sensor utilizes an impedance measurement technique that is sensitive to the presence of metallic or nonmetallic objects in the proximity of the HDD head. The system will use a thin film sensor conformal with the drill head. The impedance of the soil will be measured with a low frequency signal injected through the drill head itself. A pair of bridge type impedance sensors, mounted orthogonal to one another, is capacitively coupled to the soil. Inclusions in the soil will cause changes to the sensor balance distinguishable from homogeneous soil. The sensor will provide range and direction data for obstacles near the HDD head. The goal is to provide a simple, robust system that provides the information required to avoid obstacles. This must be done within the size and ruggedness constraints of the HDD

  12. DIFFERENTIAL SOIL IMPEDANCE OBSTACLE DETECTION

    SciTech Connect

    Maximillian J. Kieba

    2002-08-30

    This project develops a new and unique obstacle detection sensor for horizontal directional drilling (HDD) equipment. The development of this new technology will greatly improve the reliability and safety of natural gas HDD construction practices. This sensor utilizes a differential soil impedance measurement technique that will be sensitive to the presence of plastic and ceramic, as well as metallic obstacles. The use of HDD equipment has risen significantly in the gas industry because HDD provides a much more cost-effective and less disruptive method for gas pipe installation than older, trenching methods. However, there have been isolated strikes of underground utilities by HDD equipment, which may have been avoided if methods were available to detect other underground obstacles when using HDD systems. GTI advisors from the gas industry have ranked the value of solving the obstacle detection problem as the most important research and development project for GTI to pursue using Federal Energy Regulatory Commission (FERC) funds available through its industry partner, GRI. GTI proposes to develop a prototype down-hole sensor system that is simple and compact. The sensor utilizes an impedance measurement technique that is sensitive to the presence of metallic or nonmetallic objects in the proximity of the HDD head. The system will use a thin film sensor conformal with the drill head. The impedance of the soil will be measured with a low frequency signal injected through the drill head itself. A pair of bridge type impedance sensors, mounted orthogonal to one another, is capacitively coupled to the soil. Inclusions in the soil will cause changes to the sensor balance distinguishable from homogeneous soil. The sensor will provide range and direction data for obstacles near the HDD head. The goal is to provide a simple, robust system that provides the information required to avoid obstacles. This must be done within the size and ruggedness constraints of the HDD

  13. DIFFERENTIAL SOIL IMPEDANCE OBSTACLE DETECTION

    SciTech Connect

    Maximillian J. Kieba

    2002-11-27

    This project develops a new and unique obstacle detection sensor for horizontal directional drilling (HDD) equipment. The development of this new technology will greatly improve the reliability and safety of natural gas HDD construction practices. This sensor utilizes a differential soil impedance measurement technique that will be sensitive to the presence of plastic and ceramic, as well as metallic obstacles. The use of HDD equipment has risen significantly in the gas industry because HDD provides a much more cost-effective and less disruptive method for gas pipe installation than older, trenching methods. However, there have been isolated strikes of underground utilities by HDD equipment, which may have been avoided if methods were available to detect other underground obstacles when using HDD systems. GTI advisors from the gas industry have ranked the value of solving the obstacle detection problem as the most important research and development project for GTI to pursue using Federal Energy Regulatory Commission (FERC) funds available through its industry partner, GRI. GTI proposes to develop a prototype down-hole sensor system that is simple and compact. The sensor utilizes an impedance measurement technique that is sensitive to the presence of metallic or nonmetallic objects in the proximity of the HDD head. The system will use a thin film sensor conformal with the drill head. The impedance of the soil will be measured with a low frequency signal injected through the drill head itself. A pair of bridge type impedance sensors, mounted orthogonal to one another, is capacitively coupled to the soil. Inclusions in the soil will cause changes to the sensor balance distinguishable from homogeneous soil. The sensor will provide range and direction data for obstacles near the HDD head. The goal is to provide a simple, robust system that provides the information required to avoid obstacles. This must be done within the size and ruggedness constraints of the HDD

  14. CMP-Neu5Ac Hydroxylase Null Mice as a Model for Studying Metabolic Disorders Caused by the Evolutionary Loss of Neu5Gc in Humans

    PubMed Central

    Kwon, Deug-Nam; Choi, Yun-Jung; Cho, Ssang-Goo; Park, Chankyu; Seo, Han Geuk; Song, Hyuk; Kim, Jin-Hoi

    2015-01-01

    The purpose of this study was to identify the modification/turnover of gene products that are altered in humans due to evolutionary loss of Neu5Gc. CMP-Neu5Ac hydroxylase- (Cmah-) deficient mice show the infiltration of Kupffer cells within liver sinusoids, whereas body and liver weight develop normally. Pathway analysis by use of Illumina MouseRef-8 v2 Expression BeadChip provided evidence that a number of biological pathways, including the glycolysis, gluconeogenesis, TCA cycle, and pentose phosphate pathways, as well as glycogen metabolism-related gene expression, were significantly upregulated in Cmah-null mice. The intracellular glucose supply in Cmah-null mice resulted in mitochondrial dysfunction, oxidative stress, and the advanced glycation end products accumulation that could further induce oxidative stress. Finally, low sirtuin-1 and sirtuin-3 gene expressions due to higher NADH/NAD in Cmah-null mice decreased Foxo-1 and MnSOD gene expression, suggesting that oxidative stress may result in mitochondrial dysfunction in Cmah-null mouse. The present study suggests that mice with CMAH deficiency can be taken as an important model for studying metabolic disorders in humans. PMID:26558285

  15. Electrochemical impedance spectroscopy of metal alloys in the space transportation system launch environment

    NASA Technical Reports Server (NTRS)

    Calle, Luz

    1990-01-01

    AC impedance measurements were performed to investigate the corrosion resistance of 18 alloys under conditions similar to the Space Transportation System (STS) launch environment. The alloys were: (1) zirconium 702; (2) Hastelloy C-22, C-276, C-4, and B-2; (3) Inconel 600 and 825; (4) Ferralium 255; (5) Inco Alloy G-3; (6) 20Cb-3; (7) SS 904L, 304LN, 316L, 317L, and 304L; (8) ES 2205; and (9) Monel 400. AC impedance data were gathered for each alloy at various immersion times in 3.55 percent NaCl-0.1N HCl. Polarization resistance values were obtained for the Nyguist plots at each immersion time using the EQUIVALENT CIRCUIT software package available with the 388 electrochemical impedance software. Hastelloy C-22 showed the highest overall values for polarization resistance while Monel 400 and Inconel 600 had the lowest overall values. There was good general correlation between the corrosion performance of the alloys at the beach corrosion testing site, and the expected rate of corrosion as predicted based on the polarization resistance values obtained. The data indicate that electrochemical impedance spectroscopy can be used to predict the corrosion performance of metal alloys.

  16. Journal bearing impedance descriptions for rotordynamic applications

    NASA Technical Reports Server (NTRS)

    Childs, D.; Moes, H.; Van Leeuwen, H.

    1976-01-01

    The paper deals with the development of analytic descriptions for plain circumferentially-symmetric fluid journal bearings, which are suitable for use in rotor dynamic analysis. The bearing impedance vector is introduced, which defines the bearing reaction force components as a function of the bearing motion. Impedances are derived directly for the Ocvirk (short) and Sommerfeld (long) bearings, and the relationships between the impedance vector and the more familiar mobility vector are developed and used to derive analytic impedance for finite-length bearings. The static correctness of the finite-length cavitating impedance is verified. Analytic stiffness and damping coefficient definitions are derived in terms of an impedance vector for small motion around an equilibrium position and demonstrated for the finite-length cavitating impedance. Nonlinear transient rotordynamic simulations are presented for the short pi and 2-pi impedances and the finite-length cavitating impedance. It is shown that finite-length impedance yields more accurate results for substantially less computer time than the short-bearing numerical-pressure-integration approach.

  17. Reactivity at the Ln2NiO4+δ/electrolyte interface (Ln = La, Nd) studied by Electrochemical Impedance Spectroscopy and Transmission Electron Microscopy

    NASA Astrophysics Data System (ADS)

    Montenegro-Hernández, Alejandra; Soldati, Analía; Mogni, Liliana; Troiani, Horacio; Schreiber, Anja; Soldera, Flavio; Caneiro, Alberto

    2014-11-01

    Chemical reactivity between Ln2NiO4+δ (Ln: La, Nd) electrodes and Y0.08Zr0.92O1.96 (YSZ) and Ce0.9Gd0.1O1.95 (CGO) electrolytes was analyzed by Electrochemical Impedance Spectroscopy (EIS) and Focused Ion Beam-Transmission Electron Microscopy (FIB-TEM) techniques. Ln2NiO4+δ electrodes were deposited onto CGO and YSZ electrolytes by aerography and treated at 900 °C during 1 h in order to promote electrode adhesion. EIS spectra were collected between 500 and 800 °C in dry air. The Polarization Resistances (PR) values for La2NiO4/CGO/La2NiO4 cell are higher than those of La2NiO4/YSZ/La2NiO4. The PR for both cells and its evolution in time suggest that chemical reactivity is developed at 900 °C during the adhesion treatment and at T higher than 650 °C during the EIS measurements. The PR for Nd2NiO4/CGO/Nd2NiO4 and Nd2NiO4/YSZ/Nd2NiO4 are much lower than those of La2NiO4/CGO/La2NiO4 and La2NiO4/YSZ/La2NiO4 cells. These values and the slight increase of PR with time for Nd2NiO4 (NNO) electrodes indicate that the strength of chemical reactivity is much lower than that of La2NiO4 (LNO). TEM results confirmed that reactivity between CGO and LNO is much higher than that of YSZ and LNO and also confirm that the strength of reactivity is appreciably lower for NNO as electrode material.

  18. Li storage and impedance spectroscopy studies on Co3O4, CoO, and CoN for Li-ion batteries.

    PubMed

    Reddy, M V; Prithvi, Gundlapalli; Loh, Kian Ping; Chowdari, B V R

    2014-01-01

    The compounds, CoN, CoO, and Co3O4 were prepared in the form of nano-rod/particles and we investigated the Li-cycling properties, and their use as an anode material. The urea combustion method, nitridation, and carbothermal reduction methods were adopted to prepare Co3O4, CoN, and CoO, respectively. X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and the Brunauer-Emmett-Teller (BET) surface and density methods were used to characterise the materials. Cyclic voltammetry (CV) was performed and galvanostatic cycling tests were also conducted up to 60-70 cycles. The observed reversible capacity of all compounds is of the increasing order CoO, Co3O4, CoN and all compounds showed negligible capacity fading. CoO allows for Li2O and Co metal to form during the discharge cycle, allowing for a high theoretical capacity of 715 mA h g(-1). Co3O4 allows for 4 Li2O and 3Co to form, and has a theoretical capacity of 890 mAhg(-1). CoN is the best anode material of the three because the nitrogen allows for Li3N and Co to form, resulting in an even higher theoretical capacity of 1100 mAhg(-1) due to the Li3N and Co metal formation. Irrespective of morphology the charge profiles of all three compounds showed a major plateaux ~2.0 V vs. Li and potential values are almost unchanged irrespective of crystal structure. Electrochemical impedance spectroscopy (EIS) was performed to understand variation resistance and capacitance values.

  19. Correcting electrode impedance effects in broadband SIP measurements

    NASA Astrophysics Data System (ADS)

    Huisman, Johan Alexander; Zimmermann, Egon; Esser, Odilia; Haegel, Franz-Hubert; Vereecken, Harry

    2016-04-01

    Broadband spectral induced polarization (SIP) measurements of the complex electrical resistivity can be affected by the contact impedance of the potential electrodes above 100 Hz. In this study, we present a correction procedure to remove electrode impedance effects from SIP measurements. The first step in this correction procedure is to estimate the electrode impedance using a measurement with reversed current and potential electrodes. In a second step, this estimated electrode impedance is used to correct SIP measurements based on a simplified electrical model of the SIP measurement system. We evaluated this new correction procedure using SIP measurements on water because of the well-defined dielectric properties. It was found that the difference between the corrected and expected phase of the complex electrical resistivity of water was below 0.1 mrad at 1 kHz for a wide range of electrode impedances. In addition, SIP measurements on a saturated unconsolidated sediment sample with two types of potential electrodes showed that the measured phase of the electrical resistivity was very similar (difference <0.2 mrad) up to a frequency of 10 kHz after the effect of the different electrode impedances was removed. Finally, SIP measurements on variably saturated unconsolidated sand were made. Here, the plausibility of the phase of the electrical resistivity was improved for frequencies up to 1 kHz, but errors remained for higher frequencies due to the approximate nature of the electrode impedance estimates and some remaining unknown parasitic capacitances that led to current leakage. It was concluded that the proposed correction procedure for SIP measurements improved the accuracy of the phase measurements by an order of magnitude in the kHz frequency range. Further improvement of this accuracy requires a method to accurately estimate parasitic capacitances in situ.

  20. Spheromak Impedance and Current Amplification

    SciTech Connect

    Fowler, T K; Hua, D D; Stallard, B W

    2002-01-31

    It is shown that high current amplification can be achieved only by injecting helicity on the timescale for reconnection, {tau}{sub REC}, which determines the effective impedance of the spheromak. An approximate equation for current amplification is: dI{sub TOR}{sup 2}/dt {approx} I{sup 2}/{tau}{sub REC} - I{sub TOR}{sup 2}/{tau}{sub closed} where I is the gun current, I{sub TOR} is the spheromak toroidal current and {tau}{sub CLOSED} is the ohmic decay time of the spheromak. Achieving high current amplification, I{sub TOR} >> I, requires {tau}{sub REC} <<{tau}{sub CLOSED}. For resistive reconnection, this requires reconnection in a cold zone feeding helicity into a hot zone. Here we propose an impedance model based on these ideas in a form that can be implemented in the Corsica-based helicity transport code. The most important feature of the model is the possibility that {tau}{sub REC} actually increases as the spheromak temperature increases, perhaps accounting for the ''voltage sag'' observed in some experiments, and a tendency toward a constant ratio of field to current, B {proportional_to} I, or I{sub TOR} {approx} I. Program implications are discussed.

  1. AC methods for detection and monitoring of crevice corrosion

    NASA Astrophysics Data System (ADS)

    Rawat, Ashwani Kumar

    Crevice corrosion represents one of the most deleterious forms of localized corrosion which can lead to unpredicted catastrophic failures of structural and engineering components. Crevice corrosion is typically encountered in metals and alloys which exhibit a passive behavior (e.g. stainless steels, aluminum and aluminum alloys, nickel base alloys, and titanium and titanium base alloys) in electrolytic solutions. Due to the extensive application of these metals and alloys in chemical, petrochemical, marine environments, and power industries, crevice corrosion has been a subject of intense investigation in the past two decades. Most of the studies have focused on understanding the mechanism of crevice corrosion and the control measures for specific engineering structures. However, there are few, if any, commercially available methods for the detection of initiation or monitoring of crevice corrosion propagation. This is due to the fact that crevice corrosion often takes place in shielded areas of metal/alloy surfaces which are optically inaccessible and the visual examination of the metal in crevice is extremely difficult. Most of the research efforts in this area have been directed towards comparative evaluation of crevice corrosion resistance of different alloys in a variety of electrolytes. In order to detect initiation and monitor the propagation rate of crevice corrosion in highly passivated alloys, an innovative, non-destructive, in situ research methodology based on the use of Electrochemical Impedance Spectroscopy (EIS) has been developed. This research technique is based on the fact that (i) crevice corroding sites possess lower interfacial impedance compared to the passivated surfaces (ii) the crevice has a very high solution resistance, resulting in an extremely high iR drop from the crevice to the bulk solution (iii) placement of the probing electrodes (e.g. Counter Electrode and Reference Electrode) directly inside the crevice environment drastically

  2. Revealing the charge transport mechanism of a photoelectrochemical cell: analysis using A.C. voltage perturbation.

    PubMed

    Patel, Dipal B; Chauhan, Khushbu R; Mukhopadhyay, Indrajit

    2014-10-14

    In this paper, we have carefully investigated the operation of a photoelectrochemical (PEC) cell configured of PbOx|Fe(CN)6(-4/-3)|Pt in the accumulation, flat band, depletion, inversion and deep-depletion regions using impedance measurements. The increases in the photocurrent for the different regions differ in their nature: a logarithmic increase in the depletion region, a linear increase in the inversion region along with a linear increase in the dark current and an exponential increase in the photo- and dark current in the deep-depletion region. All these variations are studied in detail to correlate these observations to the charge transfer mechanisms. The characteristics of the impedance spectrum itself can be assigned to the mentioned regions. We have found that the maximum photocurrent of the PEC cell, in the present investigation, can be extracted when the cell is working in the inversion region, while the maximum rate of the increase in photocurrent is found when the junction behaves as an ideal Schottky diode with a single RC element. Systematic experiments are suggested to establish a correlation between the observations obtained from the photocurrent, impedance, conductance, low frequency and high frequency capacitance measurements. It was found that light induced trap states in the semiconductor limit the photocurrent which has a linear dependency on the irradiance. A detailed investigation with A.C. conductivity measurements showed that the trap states actively participate in the current mechanism via a hopping phenomenon with small activation energies of 0.2 and 0.8 meV. The hopping rate increased exponentially with the applied bias under dark and illumination conditions. We also show a new way of finding the potential at which the maximum photocurrent will be extracted from the PEC cell, wherein the hopping via trap states is a dominating charge transfer mechanism. This study will help in pin pointing the key affecting parameters which limit the

  3. Temperature dependence of acoustic impedance for specific fluorocarbon liquids.

    PubMed

    Marsh, Jon N; Hall, Christopher S; Wickline, Samuel A; Lanza, Gregory M

    2002-12-01

    Recent studies by our group have demonstrated the efficacy of perfluorocarbon liquid nanoparticles for enhancing the reflectivity of tissuelike surfaces to which they are bound. The magnitude of this enhancement depends in large part on the difference in impedances of the perfluorocarbon, the bound substrate, and the propagating medium. The impedance varies directly with temperature because both the speed of sound and the mass density of perfluorocarbon liquids are highly temperature dependent. However, there are relatively little data in the literature pertaining to the temperature dependence of the acoustic impedance of these compounds. In this study, the speed of sound and density of seven different fluorocarbon liquids were measured at specific temperatures between 20 degrees C and 45 degrees C. All of the samples demonstrated negative, linear dependencies on temperature for both speed of sound and density and, consequently, for the acoustic impedance. The slope of sound speed was greatest for perfluorohexane (-278 +/- 1.5 cm/s-degrees C) and lowest for perfluorodichlorooctane (-222 +/- 0.9 cm/s-degrees C). Of the compounds measured, perfluorohexane exhibited the lowest acoustic impedance at all temperatures, and perfluorodecalin the highest at all temperatures. Computations from a simple transmission-line model used to predict reflectivity enhancement from surface-bound nanoparticles are discussed in light of these results.

  4. ac electroosmosis in rectangular microchannels.

    PubMed

    Campisi, Michele; Accoto, Dino; Dario, Paolo

    2005-11-22

    Motivated by the growing interest in ac electroosmosis as a reliable no moving parts strategy to control fluid motion in microfluidic devices for biomedical applications, such as lab-on-a-chip, we study transient and steady-state electrokinetic phenomena (electroosmosis and streaming currents) in infinitely extended rectangular charged microchannels. With the aid of Fourier series and Laplace transforms we provide a general formal solution of the problem, which is used to study the time-dependent response to sudden ac applied voltage differences in case of finite electric double layer. The Debye-Huckel approximation has been adopted to allow for an algebraic solution of the Poisson-Boltzmann problem in Fourier space. We obtain the expressions of flow velocity profiles, flow rates, streaming currents, as well as expressions of the complex hydraulic and electrokinetic conductances. We analyze in detail the dependence of the electrokinetic conductance on the extension of linear dimensions relative to the Debye length, with an eye on finite electric double layer effects. PMID:16351310

  5. Physical and electrical models for interpreting AC and DC transport measurements in polymer solar cells

    NASA Astrophysics Data System (ADS)

    McIntyre, Max; Tzolov, Marian; Cossel, Raquel; Peeler, Seth

    We have fabricated and studied bulk heterojunction solar cells using a mixture of the low bandgap material PCPDTBT and PCBM-C60. Our transport studies show that the devices in dark have good rectification and they respond to AC voltage as a simple RC circuit. The illumination causes an additional contribution to the impedance, which varies with the level of illumination. One proposed model is that photo-generated charges can become trapped in potential wells. These charges then follow a Debye relaxation process, which contributes to a varying dielectric constant. Another proposed model is based on a RC circuit model with two capacitors which can describe the varying capacitance behavior. The physical mechanism for this model is that photo-generated charges become accumulated at the interface between PCPDTBT and PCBM-C60 and form an additional layer of charge. We will show that our circuit models and their analogous physical models can predict the AC and DC responses of polymer solar cells.

  6. Micelles driven magnetite (Fe3O4) hollow spheres and a study on AC magnetic properties for hyperthermia application

    NASA Astrophysics Data System (ADS)

    Goswami, Madhuri Mandal; Dey, Chaitali; Bandyopadhyay, Ayan; Sarkar, Debasish; Ahir, Manisha

    2016-11-01

    Here we have discussed about designing the magnetic particles for hyperthermia therapy and done some studies in this direction. We have used oleylamine micelles as template to synthesize hollow-nanospheres (HNS) of magnetite by solvo-thermal technique. We have shown that oleylamine plays an important role to generate hollow particles. Structural analysis was done by XRD measurement and morphological measurements like SEM and TEM was performed to confirm the shape and size of hollow sphere particles. The detail magnetic measurements give an idea about the application of these HNS for magnetic heating in hyperthermia therapy. In vitro cytotoxicity studies reveal that tolerable dose rate for these particles can be significantly high and particles are non-toxic in nature. Being hollow in structure and magnetic in nature such materials will also be useful in other application fields like in drug delivery, drug release, arsenic and heavy metal removal by adsorption technique, magnetic separation etc.

  7. TRANSVERSE IMPEDANCE MEASUREMENT AT THE RHIC.

    SciTech Connect

    ZHANG,S.Y.; HUANG,H.; CAMERON,P.; DREES,A.; FLILLER,R.; SATOGATA,T.

    2002-06-02

    The RHIC transverse impedance was measured during the last operation run. Measurement of the imaginary part of the broadband impedance was the main goal. No large difference between the two rings was found nor in either plane. The measured tune shift is larger than the expected by a factor of 2.5 to 3. Several other issues such as the real part impedance measurement are also presented.

  8. IMPEDANCE BUDGET FOR CRAB CAVITY IN MEIC ELECTRON RING

    SciTech Connect

    S. Ahmed, B. Yunn, G. Krafft

    2012-07-01

    The Medium Energy Electron-Ion Collider (MEIC) at Jefferson Lab has been envisioned as a first stage high energy particle accelerator beyond the 12 GeV upgrade of CEBAF. The estimate of impedance budget is important from the view point of beam stability and matching with other accelerator components driving currents. The detailed study of impedance budget for electron ring has been performed by considering the current design parameters of the e-ring. A comprehensive picture of the calculations involved in this study has been illustrated in the paper.

  9. A note on the calculation of sound propagation over impedance jumps and screens

    NASA Astrophysics Data System (ADS)

    Rasmussen, K. B.

    1982-10-01

    Reference is made to the large number of papers over the last 10 years on point source propagation over thin screens located on finite impedance ground. Of late, attention has also been given to sound propagation over flat ground having regions of differing impedance. The goal of the study presented here is to highlight the similarities between some of the theoretical approaches to the screen problem and the impedance jump problem. It is shown that the procedure described here for predicting sound propagation over impedance discontinuities may be calculated much more efficiently than hitherto supposed. A plane screen located on an impedance boundary is considered, with use made of the theoretical ideas employed by Thomasson (1978). An equation that can be used for estimating sound propagation over two-impedance surfaces as well as infinitely long screens is derived.

  10. Factors affecting bioelectrical impedance measurements in humans.

    PubMed

    Deurenberg, P; Weststrate, J A; Paymans, I; van der Kooy, K

    1988-12-01

    In several groups of young healthy subjects the effect of the ingestion of a meal, of drinking normal tea or beef tea, of exercise and of the menstrual cycle on body impedance was assessed. The day-to-day reproducibility of the method was also investigated under standardized conditions. Two to four hours after ingestion of a meal, body impedance had decreased by about 13-17 Ohms in comparison with body impedance in the fasting state. Drinking 200 ml of normal tea did not result in a change of body impedance, but drinking 200 ml beef tea lowered the body impedance significantly by 4 +/- 4 Ohms. Moderate exercise on a bicycle ergometer (90 min, 100 W) did not influence body impedance, but strenuous exercise (90 min, 175 W) resulted in a decrease of 9 +/- 11 Ohms in body impedance. In general, changes in body impedance during the menstrual cycle were small, and only the difference between measurements of body impedance 1 week before the onset of the menstruation and again 1 week after menstruation (8 +/- 9 Ohms) was statistically significant. Under standardized conditions (in the morning, in the fasting state after emptying the bladder) the within-person between-day variation was found to be 2.8 per cent (13 Ohms).

  11. Adaptive Impedance Control Of Redundant Manipulators

    NASA Technical Reports Server (NTRS)

    Seraji, Homayoun; Colbaugh, Richard D.; Glass, Kristin L.

    1994-01-01

    Improved method of controlling mechanical impedance of end effector of redundant robotic manipulator based on adaptive-control theory. Consists of two subsystems: adaptive impedance controller generating force-control inputs in Cartesian space of end effector to provide desired end-effector-impedance characteristics, and subsystem implementing algorithm that maps force-control inputs into torques applied to joints of manipulator. Accurate control of end effector and effective utilization of redundancy achieved simultaneously by use of method. Potential use to improve performance of such typical impedance-control tasks as deburring edges and accommodating transitions between unconstrained and constrained motions of end effectors.

  12. Numerical Study for the Three-Dimensional Rayleigh Taylor Instability through the TVD/AC Scheme and Parallel Computation

    NASA Astrophysics Data System (ADS)

    Li, X. L.; Jin, B. X.; Glimm, J.

    1996-07-01

    The Rayleigh-Taylor instability is a gravity driven instability of a contact surface between fluids of different densities. The growth of this instability is sensitive to numerical or physical mass diffusion. For this reason, high resolution of the contact discontinuity is particularly important. In this paper, we address this problem using a second-order TVD finite difference scheme with artificial compression. We describe our numerical simulations of the 3D Rayleigh-Taylor instability using this scheme. The numerical solutions are compared to (a) the exact 2D solution in the linear regime and (b) numerical solutions using the TVD scheme and the front tracking method. The computational program is used to study the evolution of a single bubble and 3D bubble merger, i.e., the nonlinear evolution of a single mode and the process of nonlinear mode-mode interaction.

  13. Do changes in transcardiac impedance modulation correlate with haemodynamic status?

    PubMed

    Weiss, S M; Einstein, R; Matthews, R J; Leer, T W; Cincunegui, J L; McCulloch, R

    1992-06-01

    Implantable cardiac pacemakers and defibrillators have the ability to revert a variety of arrhythmias to normal sinus rhythm. For correct operation, such devices require accurate arrhythmia classification. Arrhythmia classification by these devices could be improved with the addition of a suitable haemodynamic sensor. This study investigated the use of transcardiac impedance for haemodynamic sensing. Ventricular fibrillation, ventricular tachycardia, electro-mechanical dissociation and five rates of ventricular pacing, each having a different associated level of haemodynamic compromise, were induced in each of seven mongrel dogs. The amplitude responses of the modulations of transcardiac impedance were compared with those of arterial pulse pressure (an established measure of haemodynamic status), and changes in cycle length. The correlation coefficient for changes in transcardiac impedance modulation amplitude and arterial pulse pressure was found to be 0.89. For transcardiac impedance modulation amplitude and cycle length, the correlation coefficient was 0.77, and for arterial pulse pressure and cycle length, the correlation coefficient was 0.85. In the acute anaesthetised dog, changes in the amplitude of transcardiac impedance modulations were shown to reflect different levels of haemodynamic status. PMID:1642572

  14. Uncertainty Analysis of the Grazing Flow Impedance Tube

    NASA Technical Reports Server (NTRS)

    Brown, Martha C.; Jones, Michael G.; Watson, Willie R.

    2012-01-01

    This paper outlines a methodology to identify the measurement uncertainty of NASA Langley s Grazing Flow Impedance Tube (GFIT) over its operating range, and to identify the parameters that most significantly contribute to the acoustic impedance prediction. Two acoustic liners are used for this study. The first is a single-layer, perforate-over-honeycomb liner that is nonlinear with respect to sound pressure level. The second consists of a wire-mesh facesheet and a honeycomb core, and is linear with respect to sound pressure level. These liners allow for evaluation of the effects of measurement uncertainty on impedances educed with linear and nonlinear liners. In general, the measurement uncertainty is observed to be larger for the nonlinear liners, with the largest uncertainty occurring near anti-resonance. A sensitivity analysis of the aerodynamic parameters (Mach number, static temperature, and static pressure) used in the impedance eduction process is also conducted using a Monte-Carlo approach. This sensitivity analysis demonstrates that the impedance eduction process is virtually insensitive to each of these parameters.

  15. Development of a wearable multi-frequency impedance cardiography device.

    PubMed

    Weyer, Sören; Menden, Tobias; Leicht, Lennart; Leonhardt, Steffen; Wartzek, Tobias

    2015-02-01

    Cardiovascular diseases as well as pulmonary oedema can be early diagnosed using vital signs and thoracic bio-impedance. By recording the electrocardiogram (ECG) and the impedance cardiogram (ICG), vital parameters are captured continuously. The aim of this study is the continuous monitoring of ECG and multi-frequency ICG by a mobile system. A mobile measuring system, based on 'low-power' ECG, ICG and an included radio transmission is described. Due to the high component integration, a board size of only 6.5 cm×5 cm could be realized. The measured data can be transmitted via Bluetooth and visualized on a portable monitor. By using energy-efficient hardware, the system can operate for up to 18 hs with a 3 V battery, continuously sending data via Bluetooth. Longer operating times can be realized by decreased transfer rates. The relative error of the impedance measurement was less than 1%. The ECG and ICG measurements allow an approximate calculation of the heart stroke volume. The ECG and the measured impedance showed a high correlation to commercial devices (r=0.83, p<0.05). In addition to commercial devices, the developed system allows a multi-frequency measurement of the thoracic impedance between 5-150 kHz.

  16. High-precision impedance spectroscopy: a strategy demonstrated on PZT.

    PubMed

    Boukamp, Bernard A; Blank, Dave H A

    2011-12-01

    Electrochemical impedance spectroscopy (EIS) has been recognized as a very powerful tool for studying charge and mass transport and transfer in a wide variety of electrically or electrochemically active systems. Sophisticated modeling programs make it possible to extract parameters from the impedance data, thus contributing to a better understanding of the system or material properties. For an accurate analysis, a correct modeling function is needed; this is often in the form of an equivalent circuit. It is not always possible to define the modeling function from visual inspection of the impedance dispersion. Small contributions to the overall dispersion can be masked, and hence overlooked. In this publication, a strategy is presented for high-precision impedance data analysis. A Kramers-Kronig test is used for the essential data validation. An iterative process of partial analysis and subtraction assists in deconvoluting the impedance spectrum, yielding both a vi- able model function and a set of necessary starting values for the full complex nonlinear least squares (CNLS) modeling. The advantage and possibilities of this strategy are demonstrated with an analysis of the ionic and electronic conductivity of lead zirconate titanate (PZT) as functions of temperature and oxygen partial pressure. PMID:23443688

  17. AC corrosion -- A new challenge to pipeline integrity

    SciTech Connect

    Gummow, R.A.; Wakelin, R.G.; Segall, S.M.

    1998-12-31

    Corrosion of steel by alternating current was investigated as far back as the early 1900`s. These early studies and others in the 1950--60`s indicated that AC corrosion of steel was only a fraction of an equivalent amount of direct current (i.e. less than 1% of a like amount of DC) and in addition was controlled to negligible levels when cathodic protection was applied to industry standards. In 1986 however, an investigation into a corrosion failure on a high pressure gas pipeline in Germany indicated that the sole cause of the failure was AC corrosion. This corrosion failure on an otherwise well protected pipeline resulted in the initiation of several laboratory and field studies which indicated, that above a certain minimum AC current density, normal levels of cathodic protection will not control AC corrosion to acceptable levels and that AC mitigation is often required to prevent serious corrosion. Several other AC corrosion sites were discovered at coating holidays during the follow-up investigations in Germany. A graph, relating AC voltage to holiday size at the minimum AC current density for corrosion, is presented to assist the pipeline operator in determining whether or not a pipeline is susceptible to AC corrosion activity.

  18. AC corrosion -- a new threat to pipeline integrity?

    SciTech Connect

    Gummow, R.A.; Wakelin, R.G.; Segall, S.M.

    1996-12-31

    Corrosion of steel by alternating current was investigated as far back as the early 1900`s. These early studies and others in the 1950--60`s indicated that AC corrosion of steel was only a fraction of an equivalent amount of direct current (i.e., less than 1% of a like amount of DC) and in addition was controlled to negligible levels with cathodic protection applied to industry standards. In 1986 however, an investigation into a corrosion failure on a high pressure gas pipeline in Germany indicated that the sole cause of the failure was AC corrosion. This corrosion failure on an otherwise well protected pipeline resulted in several laboratory and field studies which indicated, that above a certain minimum AC current density, standard levels of cathodic protection will not control AC corrosion and AC mitigation is required to prevent further corrosion. Several other corrosion anomalies were discovered at coating holidays during the follow-up investigations in Germany. The authors have investigated several corrosion occurrences on pipelines in Ontario during the last 2--3 years which appear to be caused by AC corrosion. This presentation traces the literature record on AC electrolysis from the past to the present and discusses the key parameters which determine the likelihood of corrosion attack. Several case histories of suspected AC corrosion will be discussed and guidelines on how to assess whether or not a pipeline is susceptible to AC corrosion will be offered.

  19. AC resistance measuring instrument

    DOEpatents

    Hof, P.J.

    1983-10-04

    An auto-ranging AC resistance measuring instrument for remote measurement of the resistance of an electrical device or circuit connected to the instrument includes a signal generator which generates an AC excitation signal for application to a load, including the device and the transmission line, a monitoring circuit which provides a digitally encoded signal representing the voltage across the load, and a microprocessor which operates under program control to provide an auto-ranging function by which range resistance is connected in circuit with the load to limit the load voltage to an acceptable range for the instrument, and an auto-compensating function by which compensating capacitance is connected in shunt with the range resistance to compensate for the effects of line capacitance. After the auto-ranging and auto-compensation functions are complete, the microprocessor calculates the resistance of the load from the selected range resistance, the excitation signal, and the load voltage signal, and displays of the measured resistance on a digital display of the instrument. 8 figs.

  20. AC Resistance measuring instrument

    DOEpatents

    Hof, Peter J.

    1983-01-01

    An auto-ranging AC resistance measuring instrument for remote measurement of the resistance of an electrical device or circuit connected to the instrument includes a signal generator which generates an AC excitation signal for application to a load, including the device and the transmission line, a monitoring circuit which provides a digitally encoded signal representing the voltage across the load, and a microprocessor which operates under program control to provide an auto-ranging function by which range resistance is connected in circuit with the load to limit the load voltage to an acceptable range for the instrument, and an auto-compensating function by which compensating capacitance is connected in shunt with the range resistance to compensate for the effects of line capacitance. After the auto-ranging and auto-compensation functions are complete, the microprocessor calculates the resistance of the load from the selected range resistance, the excitation signal, and the load voltage signal, and displays of the measured resistance on a digital display of the instrument.