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Sample records for ac stark shift

  1. Diffusive suppression of AC-Stark shifts in atomic magnetometers

    PubMed Central

    Sulai, I. A.; Wyllie, R.; Kauer, M.; Smetana, G. S.; Wakai, R. T.; Walker, T. G.

    2016-01-01

    In atomic magnetometers, the vector AC-Stark shift associated with circularly polarized light generates spatially varying effective magnetic fields, which limit the magnetometer response and serve as sources of noise. We describe a scheme whereby optically pumping a small subvolume of the magnetometer cell and relying on diffusion to transport polarized atoms allows a magnetometer to be operated with minimal sensitivity to the AC-Stark field. © 2013 Optical Society of America PMID:23503278

  2. DC and subcycle-resolved AC Stark shifts in Helium

    NASA Astrophysics Data System (ADS)

    Liu, Aihua; Thumm, Uwe

    2012-06-01

    We are developing a finite element discrete variable representation (FE-DVR) code to model the response of two-electron atoms to ultra-short pulses of EM radiation. Our first numerical results for the DC stark shift of helium deviate significantly from previous [1] single-active-electron (SAE), but are in close agreement with improved SAE calculations that include the effect of core polarization in the external field. For 3x10^14 W/cm^2 infra red fields, we calculate sub-IR-cycle- resolved instantaneous (AC) level shifts of low-lying bound He states that also strongly deviate from the SAE prediction [1]. We plan to apply our code to model recently measured subcycle time-resolved absorption spectra [2].[4pt] [1] F. He, C. Ruiz, A. Becker, and U. Thumm, J. Phys. B 44, 211001 (2011).[0pt] [2] H. Wang, M. Chini, S. Chen, C.-H. Zhang, F. He, Y. Cheng, Y. Wu, U. Thumm, and Z. Chang, Phys. Rev. Lett. 105, 143002 (2010); M. Chini, Z. Chang et al., to be published.

  3. External versus self-induced ac Stark shift

    NASA Astrophysics Data System (ADS)

    Gil, L.; Lippi, G. L.

    2015-07-01

    An oscillating electromagnetic (e.m.) field driving a dipole transition induces a well-known energy level shift, commonly described in a dressed state representation [1]. Experimentally, the effect arises when irradiating a sample (atomic, molecular, etc.) with an e.m. field which is resonant (or quasi-resonant) with a transition between energy levels. The source of the e.m. field is, in such a case, unaffected by the interaction and the field's amplitude (or intensity) is used by the experimenter as a control parameter to vary the level shift. Even in those situations where one (or multiple) pump field(s) and one (or multiple) probe field(s) are employed, the picture remains the same, regardless of the more complex mathematical description of the levels involved: the e.m. field amplitude remains an independent control parameter. This is by far the most common situation encountered in spectroscopy when studying an energy level shift.

  4. Trapped ion 88Sr+ optical clock systematic uncertainties - AC Stark shift determination

    NASA Astrophysics Data System (ADS)

    Barwood, GP; Huang, G.; King, SA; Klein, HA; Gill, P.

    2016-06-01

    A recent comparison between two trapped-ion 88Sr+ optical clocks at the UK. National Physical Laboratory demonstrated agreement to 4 parts in 1017. One of the uncertainty contributions to the optical clock absolute frequency arises from the blackbody radiation shift which in turn depends on uncertainty in the knowledge of the differential polarisability between the two clocks states. Whilst a recent NRC measurement has determined the DC differential polarisability to high accuracy, there has been no experimental verification to date of the dynamic correction to the DC Stark shift. We report a measurement of the scalar AC Stark shift at 1064 nm with measurements planned at other wavelengths. Our preliminary result using a fibre laser at 1064 nm agrees with calculated values to within ∼3%.

  5. Two attosecond pulse transient absorption spectroscopy and extraction of the instantaneous AC Stark shift in helium

    NASA Astrophysics Data System (ADS)

    Bækhøj, Jens E.; Bojer Madsen, Lars

    2016-07-01

    In two attosecond pulse absorption spectroscopy (TAPAS) the use of two attosecond XUV pulses allows the extraction of atomic and molecular quantum mechanical dipole phases from spectroscopic measurements. TAPAS relies on interference between processes that individually only include a single XUV photon, and therefore does not rely on high intensity attosecond pulses. To show the usefulness and limitations of the TAPAS method we investigate its capability of capturing the instantaneous AC Stark shift induced by a midinfrared 3200 nm pulse in the | 1{{s}}2{{p}}> state of helium.

  6. ac Stark shift measurements of the clock transition in cold Cs atoms: Scalar and tensor light shifts of the D2 transition

    NASA Astrophysics Data System (ADS)

    Costanzo, G. A.; Micalizio, S.; Godone, A.; Camparo, J. C.; Levi, F.

    2016-06-01

    The ac Stark shift, or light shift, is a physical phenomenon that plays a fundamental role in many applications ranging from basic atomic physics to applied quantum electronics. Here, we discuss experiments testing light-shift theory in a cold-atom cesium fountain clock for the Cs D2 transition (i.e., 6 2S1 /2→6 2P3 /2 at 852 nm). Cold-atom fountains represent a nearly ideal system for the study of light shifts: (1) The atoms can be perturbed by a field of arbitrary character (e.g., coherent field or nonclassical field); (2) there are no trapping fields to complicate data interpretation; (3) the probed atoms are essentially motionless in their center-of-mass reference frame, T ˜ 1 μK; and (4) the atoms are in an essentially collisionless environment. Moreover, in the present work the resolution of the Cs excited-state hyperfine splittings implies that the D2 ac Stark shift contains a nonzero tensor polarizability contribution, which does not appear in vapor phase experiments due to Doppler broadening. Here, we test the linearity of the ac Stark shift with field intensity, and measure the light shift as a function of field frequency, generating a "light-shift curve." We have improved on the previous best test of theory by a factor of 2, and after subtracting the theoretical scalar light shift from the experimental light-shift curves, we have isolated and tested the tensor light shift for an alkali D2 transition.

  7. Dielectric waveguide gas-filled stark shift modulator

    DOEpatents

    Hutchinson, Donald P.; Richards, Roger K.

    2003-07-22

    An optical modulator includes a dielectric waveguide for receiving an optical beam and coupling energy of the optical beam into the waveguide. At least one Stark material is provided in the waveguide. A bias circuit generates a bias signal to produce an electrical field across the Stark material to shift at least one of the Stark absorption frequencies towards the frequency of the optical beam. A circuit for producing a time varying electric field across the Stark material modulates the optical beam. At least a portion of the bias field can be generated by an alternating bias signal, such as a square wave. A method of modulating optical signals includes the steps of providing a dielectric waveguide for receiving an optical beam and coupling energy of the optical beam into the waveguide, the waveguide having at least one Stark material disposed therein, and varying an electric field imposed across the Stark material.

  8. Anisotropic exciton Stark shift in black phosphorus

    NASA Astrophysics Data System (ADS)

    Chaves, A.; Low, Tony; Avouris, P.; ćakır, D.; Peeters, F. M.

    2015-04-01

    We calculate the excitonic spectrum of few-layer black phosphorus by direct diagonalization of the effective mass Hamiltonian in the presence of an applied in-plane electric field. The strong attractive interaction between electrons and holes in this system allows one to investigate the Stark effect up to very high ionizing fields, including also the excited states. Our results show that the band anisotropy in black phosphorus becomes evident in the direction-dependent field-induced polarizability of the exciton.

  9. Experimental Stark Shift of Some Xe II UV Lines

    SciTech Connect

    Djurovic, S.; Cirisan, M.; Pelaez, R. J.; Aparicio, J. A.; Mar, S.

    2008-10-22

    Stark broadening and shift of Xe II lines have been the subject of many experimental and theoretical studie. Here, the results of Stark shift measurements for six Xe II lines are presented. All given results are here reported for the first time. Two lines belong to 5d-6p, two to 5d-7p and one to 5d-4f transition. In this experiment pulsed arc plasma made of mixture of 95% helium and 5% xenon was used. Measured electron densities and temperatures were in the range of (0.2-1.8)10{sup 23}m{sup -3} and 18300-25500 K respectively.

  10. Experimental Stark widths and shifts of Ti II spectral lines

    NASA Astrophysics Data System (ADS)

    Manrique, J.; Aguilera, J. A.; Aragón, C.

    2016-10-01

    Stark widths and shifts of Ti II lines with wavelengths in the range 2500-4600 Å have been determined by laser-induced breakdown spectroscopy. The temperature and electron density of the plasma vary in the ranges 11 970-15 520 K and (2.0-7.2) × 1017 cm-3, respectively, for the different measurement instants from 0.6 to 1.8 μs. The samples used are fused glass discs with different titanium concentrations, selected to control the self-absorption of the lines. The Stark widths and shifts are compared with the experimental and theoretical data available in the literature.

  11. Solvent stark effects and spectral shifts. II

    SciTech Connect

    Nicol, M; Swain, J; Shum, Y Y; Merin, R; Chen, R H.H.

    1981-03-01

    Solvent shifts of the energies of the lowest /sup 1/L/sub a/ bands of the electronic absorption spectra of anthracene, chrysene, phenanthrene, and tetracene and of the lowest /sup 1/L/sub b/ bands of the electronic absorption spectra of naphthalene, phenanthrene, chrysene, and picene are reported. The origins of these shifts are analyzed in terms of theories developed by Baur and Nicol and by Abe. Satisfactory fits of the experimental data are obtained for theoretical expressions derived from both theories, but discrepancies are observed between the relative magnitudes assigned to the various contributions to the shifts by the two theories. The magnitudes of the parameters of the Baur and Nicol theory, relating solvent shifts to the dielectric constant and refractive index of the solvent, are found to be the same within experimental precision for the /sup 1/L/sub a/ transitions in all of the molecules studied; a similar regularity of the parameters for the /sup 1/L/sub b/ transitions also is observed.

  12. Engineering large Stark shifts for control of individual clock state qubits

    NASA Astrophysics Data System (ADS)

    Lee, A. C.; Smith, J.; Richerme, P.; Neyenhuis, B.; Hess, P. W.; Zhang, J.; Monroe, C.

    2016-10-01

    In quantum information science, the external control of qubits must be balanced with the extreme isolation of the qubits from the environment. Atomic qubit systems typically mitigate this balance through the use of gated laser fields that can create superpositions and entanglement between qubits. Here we propose the use of high-order optical Stark shifts from optical fields to manipulate the splitting of atomic qubits that are insensitive to other types of fields. We demonstrate a fourth-order ac Stark shift in a trapped atomic ion system that does not require extra laser power beyond that needed for other control fields. We individually address a chain of tightly spaced trapped ions and show how these controlled shifts can produce an arbitrary product state of 10 ions as well as generate site-specific magnetic field terms in a simulated spin Hamiltonian.

  13. Stark Shift Measurement of Some Xe III Lines

    SciTech Connect

    Djurovic, S.; Cirisaif, M.; Pelaez, R. J.; Aparicio, J. A.; Mar, S.

    2008-10-22

    Examination of ionized xenon spectrum is of a great interest for plasma diagnostic purposes, theory testing and different applications. In this paper, we present Stark shift data for one blue and five UV Xe III lines. One line belongs to the 5d-6p transition, while all other lines belong to 6s-6p transition. Most of the existing papers are devoted to Stark width measurements and only one paper deals with shift data of the lines studied herein. A low-pressure pulsed arc with 95% of helium and 5% of xenon was used as a plasma source. All measurements were performed under following plasma conditions: electron density (0.2-1.4)10{sup 23}m{sup -3} and electron temperature 18000-23000 K.

  14. Individual Optical Addressing of Atomic Clock Qubits With Stark Shifts

    NASA Astrophysics Data System (ADS)

    Lee, Aaron; Smith, Jacob; Richerme, Phillip; Neyenhuis, Brian; Hess, Paul; Zhang, Jiehang; Monroe, Chris

    2016-05-01

    In recent years, trapped ions have proven to be a versatile quantum information platform, enabled by their long lifetimes and high gate fidelities. Some of the most promising trapped ion systems take advantage of groundstate hyperfine ``clock'' qubits, which are insensitive to background fields to first order. This same insensitivity also makes σz manipulations of the qubit impractical, eliminating whole classes of operations. We prove there exists a fourth-order light shift, or four-photon Stark shift, of the clock states derived from two coherent laser beams whose beatnote is close to the qubit splitting. Using a mode-locked source generates a large light shift with only modest laser powers, making it a practical σz operation on a clock qubit. We experimentally verify and measure the four-photon Stark shift and demonstrate its use to coherently individually address qubits in a chain of 10 Yb 171 ions with low crosstalk. We use this individual addressing to prepare arbitrary product states with high fidelity and also to apply independent σz terms transverse to an Ising Hamiltonian. This work is supported by the ARO Atomic Physics Program, the AFOSR MURI on Quantum Measurement and Verification, and the NSF Physics Frontier Center at JQI.

  15. Stark widths and shifts for spectral lines of Sn IV

    NASA Astrophysics Data System (ADS)

    de Andrés-García, I.; Alonso-Medina, A.; Colón, C.

    2016-01-01

    In this paper, we present theoretical Stark widths and shifts calculated corresponding to 66 spectral lines of Sn IV. We use the Griem semi-empirical approach and the COWAN computer code. For the intermediate coupling calculations, the standard method of least-squares fitting from experimental energy levels was used. Data are presented for an electron density of 1017 cm-3 and temperatures T = 1.1-5.0 (104 K). The matrix elements used in these calculations have been determined from 34 configurations of Sn IV: 4d10ns(n = 5-10), 4d10nd(n = 5-8), 4d95s2, 4d95p2, 4d95s5d, 4d85s5p2 and 4d105g for even parity and 4d10np(n = 5-8), 4d10nf (n = 4-6), 4d95snp(n = 5-8), 4d85s25p and 4d95snf (n = 4-10) for odd parity. Also, in order to test the matrix elements used in our calculations, we present calculated values of radiative lifetimes of 14 levels of Sn IV. There is good agreement between our calculations and the experimental radiative lifetimes obtained from the bibliography. The spectral lines of Sn IV are observed in UV spectra of HD 149499 B obtained with the Far Ultraviolet Spectroscopic Explorer, the Goddard High Resolution Spectrograph and the International Ultraviolet Explorer. Theoretical trends of the Stark broadening parameter versus the temperature for relevant lines are presented. Also our values of Stark broadening parameters have been compared with the data available in the bibliography.

  16. Influence of Stark shift and atomic coherence on entanglement of two qubits

    NASA Astrophysics Data System (ADS)

    Bashkirov, Eugene K.; Mastuygin, Michail

    2015-03-01

    In this paper we have investigated the atom-atom entanglement for degenerate two-photon Tavis-Cummings model with taking into account Stark shift and initial atomic coherence. Considering different initial coherent states we have derived that the atom-atom entanglement can be greatly increased or decreased due to the presence of the Stark shift. In addition, we have derived that the entanglement sudden death effect vanishes due to the presence of Stark shift for some initial states.

  17. Influence of the Stark Shift on Entanglement Sudden Death and Birth in Cavity QED

    NASA Astrophysics Data System (ADS)

    Zhang, Jian-Song; Chen, Ai-Xi; Wu, Kun-Hua

    2011-01-01

    We investigate the entanglement dynamics of two two-level atoms interacting with two vacuum fields of two spatially separated cavities with the Stark effects by employing the concurrence. It is shown that the entanglement sudden death (ESD) and birth (ESB) could be controlled by adjusting the Stark-shift parameters. If the Stark-shift parameters are chosen appropriately, then ESD and ESB phenomena will appear. In addition, the appearance of ESD before or after ESB depends on the Stark-shift values.

  18. Observation and cancellation of a perturbing dc stark shift in strontium optical lattice clocks.

    PubMed

    Lodewyck, Jérôme; Zawada, Michal; Lorini, Luca; Gurov, Mikhail; Lemonde, Pierre

    2012-03-01

    We report on the observation of a dc Stark frequency shift at the 10-(13) level by comparing two strontium optical lattice clocks. This frequency shift arises from the presence of electric charges trapped on dielectric surfaces placed under vacuum close to the atomic sample. We show that these charges can be eliminated by shining UV light on the dielectric surfaces, and characterize the residual dc Stark frequency shift on the clock transition at the 10-(18) level by applying an external electric field. This study shows that the dc Stark shift can play an important role in the accuracy budget of lattice clocks, and should be duly taken into account.

  19. Observation and cancellation of a perturbing dc stark shift in strontium optical lattice clocks.

    PubMed

    Lodewyck, Jérôme; Zawada, Michal; Lorini, Luca; Gurov, Mikhail; Lemonde, Pierre

    2012-03-01

    We report on the observation of a dc Stark frequency shift at the 10-(13) level by comparing two strontium optical lattice clocks. This frequency shift arises from the presence of electric charges trapped on dielectric surfaces placed under vacuum close to the atomic sample. We show that these charges can be eliminated by shining UV light on the dielectric surfaces, and characterize the residual dc Stark frequency shift on the clock transition at the 10-(18) level by applying an external electric field. This study shows that the dc Stark shift can play an important role in the accuracy budget of lattice clocks, and should be duly taken into account. PMID:22481773

  20. On the Stark Widths and Shifts of Ar II 472.68 nm Spectral Line

    SciTech Connect

    Mijatovic, Z.; Gajo, T.; Vujicic, B.; Djurovic, S.; Kobilarov, R.

    2008-10-22

    Stark widths and shifts of Ar II 472.68 nm spectral line were measured from T-tube plasmas. Plasma electron density ranged 1.8-2.210{sup 17} cm{sup -3}, while temperature ranged 20000-43000 K. Obtained results of widths and shifts were compared with measured results of other authors.

  1. Influence of Stark Shift on Entanglement of Two Qubits in the Two-Photon Tavis-Cummings Model

    NASA Astrophysics Data System (ADS)

    Mastyugin, M. S.; Bashkirov, E. K.

    2015-09-01

    Considering two-atom degenerate two-photon Tavis-Cummings model, we investigate the entanglement between two atoms prepared initially in the coherent disentangled states and cavity field prepared in few-photon Fock state, and study the effect of the Stark shift on entanglement. The results show that the atom-atom negativity evolve periodically with time and the periods are affected by the Stark shift and initial coherent atomic state and that the atom-atom entanglement can be greatly enhanced due to the presence of Stark shift. We also have shown that entanglement sudden death effect vanishes for some parameters of the considered system due to the presence of Stark shift. In addition, the entanglement sudden death effect vanishes due to the presence of Stark shift. We have derived that the dynamic Stark shift can be used to control entanglement between two initially disentangled atoms.

  2. Static multipole polarisabilities and second-order Stark shift in francium

    NASA Technical Reports Server (NTRS)

    Khan, F.; Khandelwal, G. S.; Wilson, J. W.

    1988-01-01

    The multipole polarizability of the ground state of francium is calculated by utilizing both the variational technique of Davison and the quantum defect theory underlying the Bates-Damgaard method. This approach is also shown to yield reasonable results for other alkali atoms. Second-order Stark shift for the ground state of francium is presented as a function of field strength for possible future experimental comparison.

  3. Static multipole polarisabilities and second-order Stark shift in francium.

    PubMed

    Khan, F; Khandelwal, G S; Wilson, J W

    1988-01-01

    The multipole polarisability of the ground state of francium is calculated by utilising both the variational technique of Davison and the quantum defect theory underlying the Bates-Damgaard method. This approach is also shown to yield reasonable results for other alkali atoms. Second-order Stark shift for the ground state of francium is presented as a function of field strength for possible future experimental comparison. PMID:11539071

  4. Stark-shift-chirped rapid-adiabatic-passage technique among three states

    SciTech Connect

    Rangelov, A. A.; Vitanov, N. V.; Yatsenko, L. P.; Shore, B. W.; Halfmann, T.; Bergmann, K.

    2005-11-15

    We show that the technique of Stark-chirped rapid adiabatic passage (SCRAP), hitherto used for complete population transfer between two quantum states, offers a simple and robust method for complete population transfer amongst three states in atoms and molecules. In this case SCRAP uses three laser pulses: a strong far-off-resonant pulse modifies the transition frequencies by inducing dynamic Stark shifts and thereby creating time-dependent level crossings amongst the three diabatic states, while near-resonant and moderately strong pump and Stokes pulses, appropriately offset in time, drive the population between the initial and final states via adiabatic passage. The population transfer efficiency is robust to variations in the intensities of the lasers, as long as these intensities are sufficiently large to enforce adiabatic evolution. With suitable pulse timings the population in the (possibly decaying) intermediate state can be minimized, as with stimulated Raman adiabatic passage (STIRAP). This technique applies to one-photon as well as multiphoton transitions and it is also applicable to media exhibiting inhomogeneous broadening; these features represent clear advantages over STIRAP by overcoming the inevitable dynamical Stark shifts that accompany multiphoton transitions as well as unwanted detunings, e.g., induced by Doppler shifts.

  5. Influence of the ac Stark effect on multiphoton transitions in molecules

    NASA Astrophysics Data System (ADS)

    Meerts, W. Leo; Ozier, Irving; Hougen, Jon T.

    1989-05-01

    A multiphoton mechanism for molecular beam transitions is presented which relies on a large first-order ac Stark effect to modulate the energy separation of the initial and final states of the multiphoton transition, but which does not require the presence of any intermediate level(s). The theoretical formalism uses ideas from the laser multiphoton literature for a two-level system interacting with a monochromatic electromagnetic radiation field, together with a close analog of the rotating wave approximation. The diagonal matrix elements of the Hamiltonian operator corresponding to the large ac Stark effect are removed by a mathematical substitution which in effect transforms appropriate differences of these diagonal elements into transition moments involving higher harmonics of the frequency of the monochromatic radiation field. The electric field strength of the true monochromatic radiation field is ``distributed'' among the higher harmonics of the effective field according to an expression involving Bessel functions. Because these Bessel functions are bounded, there exists for a given time t of exposure to the radiation, a threshold for the magnitude of the transition dipole matrix element coupling the two levels: Below this threshold, the transition probability in a traditional one-photon molecular beam electric resonance experiment cannot be made unity simply by increasing the amplitude of the radiation field. In fact, if the coupling matrix element is small enough, the molecular beam electric resonance signal cannot be detected within exposure time t. The algebraic formalism described above is checked by computer solution of an initial value problem involving four real coupled linear differential equations. It is then used to explain the multiphoton transitions previously observed in molecular beam electric resonance studies on the two symmetric top molecules OPF3 and CH3 CF3, where the number of photons involved in a given transition varies from 1

  6. Stark Widths and Shifts Dependence on the Rest Core Charge of the Emitters within ns-np Transition Arrays

    SciTech Connect

    Scepanovic, Mara; Puric, Jagos

    2010-01-21

    Stark width and shift simultaneous dependence on the upper level ionization potential and rest core charge of the emitter has been evaluated and discussed. It has been verified that the found relations, connecting Stark broadening parameters with upper level ionization potential and rest core charge of the emitters for particular electron temperature and density, can be used for prediction of Stark line width and shift data in case of ions for which observed data, or more detailed calculations, are not yet available. Stark widths and shifts published data are used to demonstrate the existence of other kinds of regularities within similar spectra of different elements and their ionization stages. The emphasis is on the Stark parameter dependence on the upper level ionization potential and on the rest core charge for the lines from similar spectra of multiply charged ions. The found relations connecting Stark widths and shift parameters with upper level ionization potential, rest core charge and electron temperature were used for a prediction of new Stark broadening data, thus avoiding much more complicated procedures.

  7. High-accuracy time- and space-resolved Stark shift measurements

    SciTech Connect

    Bailey, J.E.; Adams, R.; Carlson, A.L.; Ching, C.H.; Filuk, A.B.; Lake, P.

    1996-07-01

    Stark-shift measurements using emission spectroscopy are a powerful tool for advancing understanding in many plasma physics experiments. The authors use simultaneous 2-D-spatial and time-resolved spectra to study the electric field evolution in the 20 TW Particle Beam Fusion Accelerator II ion diode acceleration gap. Fiber optic arrays transport light from the gap to remote streaked spectrographs operated in a multiplexed mode that enables recording time-resolved spectra from eight spatial locations on a single instrument. Design optimization and characterization measurements of the multiplexed spectrograph properties include the astigmatism, resolution, dispersion variation, and sensitivity. A semi-automated line-fitting procedure determines the Stark shift and the related uncertainties. Fields up to 10 MV/cm are measured with an accuracy {+-}2--4%. Detailed tests of the fitting procedure confirm that the wavelength shift uncertainties are accurate to better than {+-}20%. Development of an active spectroscopy probe technique that uses laser-induced fluorescence from an injected atomic beam to obtain 3-D space- and time-resolved measurements of the electric and magnetic fields is in progress.

  8. High-precision Stark shift measurements in excited states of indium using an atomic beam

    NASA Astrophysics Data System (ADS)

    Majumder, P. K.; Carter, A. L.; Augenbraun, B. L.; Rupasinghe, P. M.; Vilas, N. B.

    2016-05-01

    A recent precision measurement in our group of the indium scalar polarizability within the 410 nm 5p1 / 2 --> 6s1 / 2 transition showed excellent agreement with ab initio atomic theory. We are now completing a measurement of the polarizability within the 6s1 / 2 --> 6p1 / 2 excited-state transition. In our experiment, two external cavity semiconductor diode lasers interact transversely with a collimated indium atomic beam. We tune the 410 nm laser to the 5p1 / 2 --> 6s1 / 2 transition, keeping the laser locked to the exact Stark-shifted resonance frequency. We overlap a 1343 nm infrared laser to reach the 6p1 / 2 state. The very small infrared absorption in our atomic beam is detected using two-tone FM spectroscopy. Monitoring the two-step excitation signal in a field-free supplemental vapor cell provides frequency reference and calibration. Precisely calibrated electric fields of 5 - 15 kV/cm produce Stark shifts of order 100 MHz for this excited state. Experimental details, latest results, and comparison to theory will be discussed. In the near future, The same infrared laser will be tuned to 1291 nm to study the scalar and tensor polarizability of the 6p3 / 2 excited state providing a distinct test of atomic theory. Work supported by NSF Grant # 1404206.

  9. The AC-Stark Effect in Nitric Oxide Induced by Rapidly Swept Continuous Wave Quantum Cascade Lasers

    SciTech Connect

    Duxbury, Geoffrey; Kelly, James F.; Blake, Thomas A.; Langford, Nigel

    2012-05-07

    A large AC Stark effect has been observed when nitric oxide, at low pressure in a long optical path (100 m) Herriot cell, is subjected to infrared radiation from a rapidly swept, continuous wave infrared quantum cascade laser. As the frequency sweep rate of the laser is increased, an emission signal induced by rapid passage, occurs after the laser frequency has passed through the resonance of a molecular absorption line. At very high sweep rates a laser field-induced splitting of the absorptive part of the signal is observed, due to the AC Stark effect. This splitting is related to the Autler-Townes mixing of the hyperfine transitions, which lie within the lambda doublet components of the transition, under the Doppler broadened envelope.

  10. Effects of the Stark Shift on the Evolution of the Field Entropy and Entanglement in the Two-Photon Jaynes-Cummings Model

    NASA Technical Reports Server (NTRS)

    Fang, Mao Fa

    1996-01-01

    The evolution of the field entropy in the two-photon JCM in the presence of the Stark shift is investigated, and the effects of the dynamic Stark shift on the evolution of the field entropy and entanglement between the atom and field, are examined. The results show that the dynamic Stark shift plays an important role in the evolution of the field entropy in two-photon processes.

  11. The chemical bond in external electric fields: energies, geometries, and vibrational Stark shifts of diatomic molecules.

    PubMed

    Sowlati-Hashjin, Shahin; Matta, Chérif F

    2013-10-14

    It is shown that the response of molecular properties of diatomics such as the total energy, the bond length, and the vibrational Stark shift to an external homogenous electric field (EF) can be predicted from field-free observable properties such as the equilibrium bond length, the bond dissociation energy, the polarizability and dipole moment functions, and the vibrational frequency. Delley [J. Mol. Struct.: THEOCHEM 434, 229 (1998)] suggested to approximate the potential energy surface under an EF by a Morse function augmented with a EF term proportional to the internuclear separation. In this work, this term is replaced by the expression of the field-induced energy change which yields a field-perturbed Morse potential that tends to a constant asymptotic limit when the EF term itself become proportional to the sum of the polarizabilities of the separated atoms. The model is validated by comparison with direct calculations on nine diatomics, five homo-nuclear (H2, N2, O2, F2, and Cl2) and four hetero-nuclear (HF, HCl, CO, and NO), covering a range and combinations of dipole moments and polarizabilities. Calculations were conducted at the quadratic configuration interaction with single and double excitations (QCISD) and density functional theory (DFT)-B3LYP levels of theory using the 6-311++G(3df,2pd) basis set. All results agree closely at the two levels of theory except for the Stark effect of NO which is not correctly predicted by QCISD calculations as further calculations, including at the coupled cluster with single and double excitation (CCSD) level of theory, demonstrate.

  12. The motional Stark effect diagnostic for ITER using a line-shift approach.

    PubMed

    Foley, E L; Levinton, F M; Yuh, H Y; Zakharov, L E

    2008-10-01

    The United States has been tasked with the development and implementation of a motional Stark effect (MSE) system on ITER. In the harsh ITER environment, MSE is particularly susceptible to degradation, as it depends on polarimetry, and the polarization reflection properties of surfaces are highly sensitive to thin film effects due to plasma deposition and erosion of a first mirror. Here we present the results of a comprehensive study considering a new MSE-based approach to internal plasma magnetic field measurements for ITER. The proposed method uses the line shifts in the MSE spectrum (MSE-LS) to provide a radial profile of the magnetic field magnitude. To determine the utility of MSE-LS for equilibrium reconstruction, studies were performed using the ESC-ERV code system. A near-term opportunity to test the use of MSE-LS for equilibrium reconstruction is being pursued in the implementation of MSE with laser-induced fluorescence on NSTX. Though the field values and beam energies are very different from ITER, the use of a laser allows precision spectroscopy with a similar ratio of linewidth to line spacing on NSTX as would be achievable with a passive system on ITER. Simulation results for ITER and NSTX are presented, and the relative merits of the traditional line polarization approach and the new line-shift approach are discussed.

  13. Measurement and compensation of optical Stark shifts for manipulating the terahertz-separated qubit in C40a+

    NASA Astrophysics Data System (ADS)

    Haze, Shinsuke; Yamazaki, Rekishu; Toyoda, Kenji; Urabe, Shinji

    2009-11-01

    We describe the measurement and compensation of optical Stark shifts induced by an off-resonant pulse for manipulating the terahertz-separated states 3D23/2-3D25/2 , in a single trapped C40a+ ion. These states can be used as a quantum bit and are coupled by a two-photon stimulated Raman transition with phase-locked light sources bridged by an optical comb generator. The induced optical Stark shift is measured by Ramsey interferometry. We estimate the power ratio of Raman beams that cancel the level shift with an uncertainty of 170 Hz. A shift of the same amount as this uncertainty is estimated to give rise to an infidelity of approximately 7.6×10-4 during a π/2 rotation operation.

  14. Shift measurements of the stark-broadened ionized helium lines at 1640 and 1215 angstrom. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Vanzandt, J. R.

    1976-01-01

    Time-resolved measurements were made of the shifts of the ionized helium lines at 1,640 A (n = 3 approaches 2) and 1,215 A (n = 4 approaches 2), and of the Stark profile of the 1,215 A wavelength line. An electromagnetic shock tube was used as a light source. The plasma conditions corresponded to electron temperatures of approximately 3.5 eV and electron densities of 0.8 to 1.8 x 10 to the 17th power/cubic cm. The measured shifts fell between two previous estimates of plasma polarization shifts. The measured Stark width of the 1,215 A wavelength line was up to 30% greater than the theoretical width.

  15. Quantum mechanical calculation of electric fields and vibrational Stark shifts at active site of human aldose reductase

    SciTech Connect

    Wang, Xianwei; Zhang, John Z. H.; He, Xiao

    2015-11-14

    Recent advance in biophysics has made it possible to directly measure site-specific electric field at internal sites of proteins using molecular probes with C = O or C≡N groups in the context of vibrational Stark effect. These measurements directly probe changes of electric field at specific protein sites due to, e.g., mutation and are very useful in protein design. Computational simulation of the Stark effect based on force fields such as AMBER and OPLS, while providing good insight, shows large errors in comparison to experimental measurement due to inherent difficulties associated with point charge based representation of force fields. In this study, quantum mechanical calculation of protein’s internal electrostatic properties and vibrational Stark shifts was carried out by using electrostatically embedded generalized molecular fractionation with conjugate caps method. Quantum calculated change of mutation-induced electric field and vibrational Stark shift is reported at the internal probing site of enzyme human aldose reductase. The quantum result is in much better agreement with experimental data than those predicted by force fields, underscoring the deficiency of traditional point charge models describing intra-protein electrostatic properties.

  16. Nanocathodoluminescence Reveals Mitigation of the Stark Shift in InGaN Quantum Wells by Si Doping.

    PubMed

    Griffiths, James T; Zhang, Siyuan; Rouet-Leduc, Bertrand; Fu, Wai Yuen; Bao, An; Zhu, Dandan; Wallis, David J; Howkins, Ashley; Boyd, Ian; Stowe, David; Kappers, Menno J; Humphreys, Colin J; Oliver, Rachel A

    2015-11-11

    Nanocathodoluminescence reveals the spectral properties of individual InGaN quantum wells in high efficiency light emitting diodes. We observe a variation in the emission wavelength of each quantum well, in correlation with the Si dopant concentration in the quantum barriers. This is reproduced by band profile simulations, which reveal the reduction of the Stark shift in the quantum wells by Si doping. We demonstrate nanocathodoluminescence is a powerful technique to optimize doping in optoelectronic devices.

  17. Nanocathodoluminescence Reveals Mitigation of the Stark Shift in InGaN Quantum Wells by Si Doping.

    PubMed

    Griffiths, James T; Zhang, Siyuan; Rouet-Leduc, Bertrand; Fu, Wai Yuen; Bao, An; Zhu, Dandan; Wallis, David J; Howkins, Ashley; Boyd, Ian; Stowe, David; Kappers, Menno J; Humphreys, Colin J; Oliver, Rachel A

    2015-11-11

    Nanocathodoluminescence reveals the spectral properties of individual InGaN quantum wells in high efficiency light emitting diodes. We observe a variation in the emission wavelength of each quantum well, in correlation with the Si dopant concentration in the quantum barriers. This is reproduced by band profile simulations, which reveal the reduction of the Stark shift in the quantum wells by Si doping. We demonstrate nanocathodoluminescence is a powerful technique to optimize doping in optoelectronic devices. PMID:26488912

  18. Nanocathodoluminescence Reveals Mitigation of the Stark Shift in InGaN Quantum Wells by Si Doping

    PubMed Central

    2015-01-01

    Nanocathodoluminescence reveals the spectral properties of individual InGaN quantum wells in high efficiency light emitting diodes. We observe a variation in the emission wavelength of each quantum well, in correlation with the Si dopant concentration in the quantum barriers. This is reproduced by band profile simulations, which reveal the reduction of the Stark shift in the quantum wells by Si doping. We demonstrate nanocathodoluminescence is a powerful technique to optimize doping in optoelectronic devices. PMID:26488912

  19. Stark shift and field ionization of arsenic donors in {sup 28}Si-silicon-on-insulator structures

    SciTech Connect

    Lo, C. C. Morton, J. J. L.; Simmons, S.; Lo Nardo, R.; Weis, C. D.; Schenkel, T.; Tyryshkin, A. M.; Lyon, S. A.; Meijer, J.; Rogalla, D.; Bokor, J.

    2014-05-12

    We develop an efficient back gate for silicon-on-insulator (SOI) devices operating at cryogenic temperatures and measure the quadratic hyperfine Stark shift parameter of arsenic donors in isotopically purified {sup 28}Si-SOI layers using such structures. The back gate is implemented using MeV ion implantation through the SOI layer forming a metallic electrode in the handle wafer, enabling large and uniform electric fields up to 2 V/μm to be applied across the SOI layer. Utilizing this structure, we measure the Stark shift parameters of arsenic donors embedded in the {sup 28}Si-SOI layer and find a contact hyperfine Stark parameter of η{sub a} = −1.9 ± 0.7 × 10{sup −3} μm{sup 2}/V{sup 2}. We also demonstrate electric-field driven dopant ionization in the SOI device layer, measured by electron spin resonance.

  20. Dynamic Stark effect and forbidden-transition spectrallineshapes

    SciTech Connect

    Stalnaker, Jason E.; Budker, D.; Freedman, S.J.; Guzman, J.S.; Rochester, S.M.; Yashchuk, V.V.

    2005-12-15

    We report on an experimental and theoretical study of thedynamic (ac) Stark effect on a for bidden transition. A general frameworkfor parameterizing and describing off-resonant ac-Stark shifts ispresented. A model is developed to calculate spectral line shapesresulting from resonant excitation of atoms in an intense standinglight-wave in the presence of off-resonant ac-Stark shifts. The model isused in the analysis and interpretation of a measurement of the ac-Starkshifts of the static-electric-field-induced 6s2 1S0 -->5d6s 3D1transition at 408 nm in atomic Yb. The results are in agreement withestimates of the ac-Stark shift of the transition under the assumptionthat the shift is dominated by that of the 6s2 1S0 ground state. Adetailed description of the experiment and analysis is presented. Abi-product of this work is an ind ependent determination (from thesaturation behavior of the 408-nm transition) of the Stark transitionpolarizability, which is found to be in agreement with our earliermeasurement. This work is part of the ongoing effort aimed at a precisionmeasurement of atomic parity-violation effects in Yb.

  1. Donor hyperfine Stark shift and the role of central-cell corrections in tight-binding theory.

    PubMed

    Usman, Muhammad; Rahman, Rajib; Salfi, Joe; Bocquel, Juanita; Voisin, Benoit; Rogge, Sven; Klimeck, Gerhard; Hollenberg, Lloyd L C

    2015-04-22

    Atomistic tight-binding (TB) simulations are performed to calculate the Stark shift of the hyperfine coupling for a single arsenic (As) donor in silicon (Si). The role of the central-cell correction is studied by implementing both the static and the non-static dielectric screenings of the donor potential, and by including the effect of the lattice strain close to the donor site. The dielectric screening of the donor potential tunes the value of the quadratic Stark shift parameter (η2) from -1.3 × 10(-3) µm(2) V(-2) for the static dielectric screening to -1.72 × 10(-3) µm(2) V(-2) for the non-static dielectric screening. The effect of lattice strain, implemented by a 3.2% change in the As-Si nearest-neighbour bond length, further shifts the value of η2 to -1.87 × 10(-3) µm(2) V(-2), resulting in an excellent agreement of theory with the experimentally measured value of -1.9 ± 0.2 × 10(-3) µm(2) V(-2). Based on our direct comparison of the calculations with the experiment, we conclude that the previously ignored non-static dielectric screening of the donor potential and the lattice strain significantly influence the donor wave function charge density and thereby leads to a better agreement with the available experimental data sets. PMID:25783758

  2. Molecular quantum mechanical gradients within the polarizable embedding approach--application to the internal vibrational Stark shift of acetophenone.

    PubMed

    List, Nanna Holmgaard; Beerepoot, Maarten T P; Olsen, Jógvan Magnus Haugaard; Gao, Bin; Ruud, Kenneth; Jensen, Hans Jørgen Aagaard; Kongsted, Jacob

    2015-01-21

    We present an implementation of analytical quantum mechanical molecular gradients within the polarizable embedding (PE) model to allow for efficient geometry optimizations and vibrational analysis of molecules embedded in large, geometrically frozen environments. We consider a variational ansatz for the quantum region, covering (multiconfigurational) self-consistent-field and Kohn-Sham density functional theory. As the first application of the implementation, we consider the internal vibrational Stark effect of the C=O group of acetophenone in different solvents and derive its vibrational linear Stark tuning rate using harmonic frequencies calculated from analytical gradients and computed local electric fields. Comparisons to PE calculations employing an enlarged quantum region as well as to a non-polarizable embedding scheme show that the inclusion of mutual polarization between acetophenone and water is essential in order to capture the structural modifications and the associated frequency shifts observed in water. For more apolar solvents, a proper description of dispersion and exchange-repulsion becomes increasingly important, and the quality of the optimized structures relies to a larger extent on the quality of the Lennard-Jones parameters. PMID:25612701

  3. Molecular quantum mechanical gradients within the polarizable embedding approach—Application to the internal vibrational Stark shift of acetophenone

    SciTech Connect

    List, Nanna Holmgaard Jensen, Hans Jørgen Aagaard; Kongsted, Jacob; Beerepoot, Maarten T. P.; Gao, Bin; Ruud, Kenneth; Olsen, Jógvan Magnus Haugaard

    2015-01-21

    We present an implementation of analytical quantum mechanical molecular gradients within the polarizable embedding (PE) model to allow for efficient geometry optimizations and vibrational analysis of molecules embedded in large, geometrically frozen environments. We consider a variational ansatz for the quantum region, covering (multiconfigurational) self-consistent-field and Kohn–Sham density functional theory. As the first application of the implementation, we consider the internal vibrational Stark effect of the C=O group of acetophenone in different solvents and derive its vibrational linear Stark tuning rate using harmonic frequencies calculated from analytical gradients and computed local electric fields. Comparisons to PE calculations employing an enlarged quantum region as well as to a non-polarizable embedding scheme show that the inclusion of mutual polarization between acetophenone and water is essential in order to capture the structural modifications and the associated frequency shifts observed in water. For more apolar solvents, a proper description of dispersion and exchange–repulsion becomes increasingly important, and the quality of the optimized structures relies to a larger extent on the quality of the Lennard-Jones parameters.

  4. Stark-shift measurement of the {sup 2}S{sub 1/2}, F=3{yields}F=4 hyperfine transition of {sup 133}Cs

    SciTech Connect

    Godone, Aldo; Calonico, Davide; Levi, Filippo; Micalizio, Salvatore; Calosso, Claudio

    2005-06-15

    In this paper we report the measurement of the frequency Stark shift of the ground-state hyperfine transition of {sup 133}Cs observed in a vapor cell through a {lambda} excitation scheme. The measured value of the quadratic Stark coefficient is k=(-2.05{+-}0.04)x10{sup -10} Hz/(V/m){sup 2} when the electric field is perpendicular to the quantization axis. A comparison with the values previously reported in literature is given in view of its interest for the evaluation of the blackbody radiation shift in the primary frequency standards.

  5. Measuring the Fr Weak Nuclear Charge by Observing a Linear Stark Shift with Small Atomic Samples

    SciTech Connect

    Bouchiat, Marie-Anne

    2008-03-28

    We study the chirality of ground-state alkali atoms in E and B fields, dressed with a circularly-polarized beam near-detuned (< or approx. )1 GHz) from an E-field-assisted forbidden transition such as 7S-8S in Fr. We predict parity violating energy shifts of their sublevels, linear in E and the weak nuclear charge Q{sub W}. A dressing beam of 10 kW/cm{sup 2} at 506 nm produces a shift of {approx}100 {mu}Hz at E=100 V/cm, B > or approx. 50 mG which should be observable with {approx}10{sup 4} Fr atoms confined in an optical dipole trap. We discuss optimal conditions, parameter reversals, and a calibration procedure to measure Q{sub W}.

  6. Microwave Stark decelerator for polar molecules

    SciTech Connect

    Enomoto, Katsunari; Momose, Takamasa

    2005-12-15

    We propose a method to decelerate polar molecules from a beam using a microwave field. A moving standing wave of a microwave electric field causes an ac Stark shift to polar molecules and decelerates them. The method is applicable to polar molecules in rotational ground states and can be used to directly load a microwave trap. Numerical simulations are presented indicating large phase-space acceptance volume.

  7. Elimination of the Stark shift from the vibrational transition frequency of optically trapped {sup 174}Yb{sup 6}Li molecules

    SciTech Connect

    Kajita, Masatoshi; Gopakumar, Geetha; Abe, Minori; Hada, Masahiko

    2011-08-15

    Transition frequencies of cold molecules must be accurately evaluated to test the variance in the proton-to-electron mass ratio. Measuring the X {sup 2}{Sigma}(v,N)=(0,0){yields}(1,0) transition frequency of optically trapped {sup 174}Yb{sup 6}Li molecules is a promising method for achieving this goal. The Stark shifts induced by trap and probe (for the Raman transition) lasers are eliminated by choosing appropriate frequencies (magic frequencies) during the construction of the optical lattice. In the far-off resonance region, the Stark shift is found to be less than 10{sup -16} even when the laser frequencies are detuned from the magic frequencies by {approx}1 MHz.

  8. Manifestation of anomalous Floquet states with longevity in dynamic fractional Stark ladder with high AC electric fields

    NASA Astrophysics Data System (ADS)

    Nemoto, Yuya; Ohno, Fumitaka; Maeshima, Nobuya; Hino, Ken-ichi

    2016-09-01

    We examine a resonance structure of Floquet state in dynamic fractional Stark ladder (DFSL) realized in biased semiconductor superlattices driven by a terahertz cw laser on the basis of the R-matrix Floquet theory. To do this, we calculate an excess density of state ρ (ex)(E) corresponding to lifetime of the Floquet state with a fractional matching ratio η, where η is the ratio of a Bloch frequency ΩB to a laser frequency ω, namely, η =ΩB / ω. The results for η = 3 / 2 demonstrate the appearance of discernibly large peaks associated with Floquet states with longevity in a region of relatively high laser-intensity. The underlying physics is discussed in terms of an analytical expression of ρ (ex)(E) and the associated Green function in which ponderomotive couplings are included in a non-perturbative way.

  9. The origin of the unusual Qy red shift in LH1-RC complexes from purple bacteria Thermochromatium tepidum as revealed by Stark absorption spectroscopy.

    PubMed

    Ma, Fei; Yu, Long-Jiang; Wang-Otomo, Zheng-Yu; van Grondelle, Rienk

    2015-12-01

    Native LH1-RC of photosynthetic purple bacteria Thermochromatium (Tch.) tepidum, B915, has an ultra-red BChl a Qy absorption. Two blue-shifted complexes obtained by chemical modification, B893 and B882, have increasing full widths at half maximum (FWHM) and decreasing transition dipole oscillator strength. 77K Stark absorption spectroscopy studies were employed for the three complexes, trying to understand the origin of the 915 nm absorption. We found that Tr(∆α) and |∆μ| of both Qy and carotenoid (Car) bands are larger than for other purple bacterial LH complexes reported previously. Moreover, the red shifts of the Qy bands are associated with (1) increasing Tr(∆α) and |∆μ| of the Qy band, (2) the red shift of the Car Stark signal and (3) the increasing |∆μ| of the Car band. Based on the results and the crystal structure, a combined effect of exciton-charge transfer (CT) states mixing, and inhomogeneous narrowing of the BChl a site energy is proposed to be the origin of the 915 nm absorption. CT-exciton state mixing has long been found to be the origin of strong Stark signal in LH1 and special pair, and the more extent of the mixing in Tch. tepidum LH1 is mainly the consequence of the shorter BChl-BChl distances. The less flexible protein structure results in a smaller site energy disorder (inhomogeneous narrowing), which was demonstrated to be able to influence |∆μ| and absorption.

  10. The STARK-B database VAMDC node: a repository for spectral line broadening and shifts due to collisions with charged particles

    NASA Astrophysics Data System (ADS)

    Sahal-Bréchot, S.; Dimitrijević, M. S.; Moreau, N.; Ben Nessib, N.

    2015-05-01

    Accurate spectroscopic diagnostics and modeling require the knowledge of numerous collisional line profiles. Access to such data via an online database has become indispensable. The STARK-B database is aimed at meeting these needs for widths and shifts of isolated lines of neutral and ionized elements due to electron and ion impacts. This database of the Paris Observatory is a result of scientific cooperation between S Sahal-Bréchot (LERMA) and M S Dimitrijević (AOB). Access to it is free, and it was opened online at the end of 2008. STARK-B is a node of the Virtual Atomic and Molecular Data Centre (VAMDC) and thus complies with VAMDC and Virtual Observatory standards. VAMDC is a European Union-funded collaboration among groups involved in the generation and use of interoperable atomic and molecular data. STARK-B now contains all our semiclassical-perturbation (SCP) calculated data for more than 123 neutral or ionized elements as published in international refereed journals. It is devoted to modeling and spectroscopic diagnostics of stellar atmospheres and envelopes, laboratory plasmas, laser equipment, and technological plasmas. Hence, the range of temperatures and densities covered by the tables is broad and depends on the ionization degree of the radiating atom. The modified semiempirical (MSE) results of calculations have begun to be implemented. In this paper, we highlight the key points of the method and the assumptions used in the calculations, which have lately been revisited. Then we present the database and its recent developments, as well as our ongoing work and our plans for the future.

  11. Theoretical Stark widths and shifts of spectral lines of 2p5nf and 2p55g configurations of Mg III

    NASA Astrophysics Data System (ADS)

    Moreno-Díaz, Cristina; Alonso-Medina, Aurelia; Colón, Cristóbal

    2014-11-01

    In this paper, we report theoretical Stark widths and shifts calculated using the Griem semi-empirical approach, which corresponds to 111 spectral lines of Mg III. The values of these Stark broadening parameters of spectral lines that arise from levels of 2p5nf and 2p55g configurations of Mg III are presented in the literature for the first time. The aim of this work is to provide values to estimate the electron density of plasma Mg III in astrophysics and industrial applications. The data are presented for the temperatures T = 0.5-10.0 (104 K) and for an electron density of 1017 cm-3. The matrix of elements used in these calculations has been determined from 23 configurations of Mg III: 2s22p6, 2s22p53p, 2s22p54p, 2s22p54f and 2s22p55f for the even parity and 2s22p5ns (n = 3-6), 2s22p5nd (n = 3-9), 2s22p55g and 2s2p6np (n = 3-8) for the odd parity. For the intermediate coupling calculations, we use the standard method of least square fitting from experimental energy levels by means of Cowan’s computer code. Lines with wavelengths of 134.6460, 135.2800, 189.0380, 190.0043, 192.8424, 408.2939 and 409.4375 nm have high probabilities and also have high values of broadening. Therefore, these lines can be used in some applications. A common regularity for the Stark width of the 189.038 nm spectral line of Mg III is discussed.

  12. Sub-Doppler Spectra of Infrared Hyperfine Transitions of Nitric Oxide Using a Pulse Modulated Quantum Cascade Laser: Rapid Passage, Free Induction Decay and the AC Stark Effect

    SciTech Connect

    Duxbury, Geoffrey; Kelly, James F.; Blake, Thomas A.; Langford, Nigel

    2012-05-07

    Using a low power, rapid (nsec) pulse-modulated quantum cascade (QC) laser, collective coherent effects in the 5 {micro}m spectrum of nitric oxide have been demonstrated by the observation of sub-Doppler hyperfine splitting and also Autler-Townes splitting of Doppler broadened lines. For nitrous oxide, experiments and model calculations have demonstrated that two main effects occur with ulsemodulated (chirped) quantum cascade lasers: free induction decay signals, and signals induced by rapid passage during the laser chirp. In the open shell molecule, NO, in which both {Lambda}-doubling splitting and hyperfine structure occur, laser field-induced coupling between the hyperfine levels of the two {Lambda}-doublet components can induce a large AC Stark effect. This may be observed as sub-Doppler structure, field-induced splittings, or Autler-Townes splitting of a Doppler broadened line. These represent an extension of the types of behaviour observed in the closed shell molecule nitrous oxide, using the same apparatus, when probed with an 8 {micro}m QC laser.

  13. Sub-Doppler spectra of infrared hyperfine transitions of nitric oxide using a pulse modulated quantum cascade laser: rapid passage, free induction decay, and the ac Stark effect.

    PubMed

    Duxbury, Geoffrey; Kelly, James F; Blake, Thomas A; Langford, Nigel

    2012-05-01

    Using a low power, rapid (nsec) pulse-modulated quantum cascade (QC) laser, collective coherent effects in the 5 μm spectrum of nitric oxide have been demonstrated by the observation of sub-Doppler hyperfine splitting and also Autler-Townes splitting of Doppler broadened lines. For nitrous oxide, experiments and model calculations have demonstrated that two main effects occur with pulse-modulated (chirped) quantum cascade lasers: free induction decay signals, and signals induced by rapid passage during the laser chirp. In the open shell molecule, NO, in which both Λ-doubling splitting and hyperfine structure occur, laser field-induced coupling between the hyperfine levels of the two Λ-doublet components can induce a large ac Stark effect. This may be observed as sub-Doppler structure, field-induced splittings, or Autler-Townes splitting of a Doppler broadened line. These represent an extension of the types of behaviour observed in the closed shell molecule nitrous oxide, using the same apparatus, when probed with an 8 μm QC laser.

  14. Measurement of Isotope Shifts, Hyperfine Splittings and Stark Shift for the Ytterbium (6S)2 SINGLET-S(0) to (6S6P) TRIPLET-P(1) Transition Using AN Acousto-Optically Modulated Laser Beam.

    NASA Astrophysics Data System (ADS)

    Li, Jian

    1995-11-01

    Accurate measurements of isotope shifts, hyperfine splittings and Stark shifts are of interest for studying atomic structure. This thesis reports a new method to precisely measure small frequency intervals. This was done using an acousto-optic modulator to frequency shift part of a laser beam. The frequency shifted and unshifted laser beams were then superimposed and excited an atomic beam. The laser frequency was scanned across the transition while fluorescence produced by the radiative decay of the excited state was detected by a photomultiplier. Each transition generated two peaks in the spectrum separated by the acousto-optic modulation frequency, which permitted the frequency to be calibrated. This method was tested by measuring the isotope shifts and hyperfine splittings of the ytterbium rm (6s)^2 ^1S_0to(6s6p) ^3P_1 transition at 555.6 nm. The shifts (MHz) relative to ^{176} Yb are: ^{173}Yb {it F}=7/2,-1432.1+/-1.2; ^{171}Yb {it F}=1/2, -1176.9+/-1.1; ^{174}Yb, 953.8+/-1.0; ^{172}Yb 1953.9+/-1.6; ^{170}Yb 3240.4+/-2.8; ^{173}Yb {it F}=5/2,3265.8+/-2.8; ^ {168}Yb, 4611.9+/-4.4; ^ {171,173}Yb {it F}=3/2,4760.1 +/-3.7 where the negative sign indicates that the transition occurs at a lower frequency than in ^{176}Yb. The magnetic dipole (a) and electric quadrupole (b) hyperfine coupling constants (MHz) of the (6s6p) ^3P_1 state for ^{171,173}Yb were determined to be a_{171}=3959.1 +/-3.0, a_{173}=-1094.44+/-0.84 and b_{173}=-827.89+/-0.85. These results were in agreement with the most accurate data found in the literature that were obtained by measuring frequency shifts using a Fabry Perot etalon whose length was stabilized with a helium neon laser locked to an iodine line. In contrast, our method uses cheaper and simpler apparatus. Next, the Stark shift of the ytterbium rm (6s)^2 ^1S_0to(6s6p) ^3P_1 transition was measured by passing the atomic beam through a uniform electric field. The Stark shift rate was found to be -15.419+/-0.048 kHz/(kV/cm)^2. No

  15. Entropy squeezing and atomic inversion in the k-photon Jaynes—Cummings model in the presence of the Stark shift and a Kerr medium: A full nonlinear approach

    NASA Astrophysics Data System (ADS)

    H, R. Baghshahi; M, K. Tavassoly; A, Behjat

    2014-07-01

    The interaction between a two-level atom and a single-mode field in the k-photon Jaynes—Cummings model (JCM) in the presence of the Stark shift and a Kerr medium is studied. All terms in the Hamiltonian, such as the single-mode field, its interaction with the atom, the contribution of the Stark shift and the Kerr medium effects are considered to be f-deformed. In particular, the effect of the initial state of the radiation field on the dynamical evolution of some physical properties such as atomic inversion and entropy squeezing are investigated by considering different initial field states (coherent, squeezed and thermal states).

  16. Stark Width and Shift Measurements for the 696.543nm ArI Line using Degenerate Four-Wave Mixing (DFWM) Spectroscopy

    NASA Astrophysics Data System (ADS)

    Dzierżȩga, K.; Bratasz, Ł.

    Sub-Doppler degenerate four-wave mixing (DFWM) spectroscopy in phase- conjugate configuration has been used to study Stark width and shift of the 696.543nm ArI line in a local thermal equilibrium argon arc plasma. DFWM spectroscopy has been used for line profile measurements as well as for plasma diagnostics. At high laser intensities, the relationship between DFWM signal intensity and plasma temperature has been experimentally determined and then used for plasma diagnostics. In the range of low laser intensities the measured line profile has been approximated by a third power of a Lorentzian profile with line width depending on laser intensity. The results of plasma diagnostics by DFWM have been compared to those by commonly used optical emission spectroscopy. This comparison shows that the methods give similar results within the uncertainty limits.

  17. Anticrossing effects in Stark spectra of helium

    NASA Astrophysics Data System (ADS)

    Windholz, L.; Drozdowski, R.; Wasowicz, T. J.; Kwela, J.

    2005-06-01

    In the spectral range between 480 nm and 630 nm the Stark effect of the transitions n 1Q-2 1S, n 1Q-2 1P and n 3Q-2 3P (n=3-10, Q=S, P,...) was studied using electric field up to 1500 kV/cm. For such a high field the Stark splitting becomes greater than the simple structure of the atom. Hence anticrossings of the Stark components of the same magnetic quantum number occur. The experimental results have been compared with the theoretically determined shifts. The results of calculations show good agreement with observation.

  18. The Stark effect in linear potentials

    NASA Astrophysics Data System (ADS)

    Robinett, R. W.

    2010-01-01

    We examine the Stark effect (the second-order shifts in the energy spectrum due to an external constant force) for two one-dimensional model quantum mechanical systems described by linear potentials, the so-called quantum bouncer (defined by V(z) = Fz for z > 0 and V(z) = ∞ for z < 0) and the symmetric linear potential (given by V(z) = F|z|). We show how straightforward use of the most obvious properties of the Airy function solutions and simple Taylor expansions gives closed form results for the Stark shifts in both systems. These exact results are then compared to other approximation techniques, such as perturbation theory and WKB methods. These expressions add to the small number of closed-form descriptions available for the Stark effect in model quantum mechanical systems.

  19. Stark broadening of Kr UV spectral lines

    SciTech Connect

    Cirisan, M.; Djurovic, S.; Pelaez, R. J.; Aparicio, J. A.; Mar, S.

    2011-01-15

    This work reports new data for the Stark parameters of doubly ionized krypton spectral lines. Stark widths and shifts of Kr iii lines belonging to the UV region (245-300 nm) have been measured. A low-pressure pulsed arc, containing a mixture of 8% krypton and 92% helium, was used as a plasma source. Measured electron densities and electron temperatures were in the range (0.7-2.0)x10{sup 23} m{sup -3} and 16 000-20 000 K, respectively. Experimentally obtained data were compared to theoretical results calculated using simplified modified semiempirical formulas.

  20. Stark echo modulation for quantum memories

    NASA Astrophysics Data System (ADS)

    Arcangeli, A.; Ferrier, A.; Goldner, Ph.

    2016-06-01

    Quantum memories for optical and microwave photons provide key functionalities in quantum processing and communications. Here we propose a protocol well adapted to solid-state ensemble-based memories coupled to cavities. It is called Stark echo modulation memory (SEMM) and allows large storage bandwidths and low noise. This is achieved in an echo-like sequence combined with phase shifts induced by small electric fields through the linear Stark effect. We investigated the protocol for rare-earth nuclear spins and found a high suppression of unwanted collective emissions that is compatible with single-photon-level operation. Broadband storage together with high fidelity for the Stark retrieval process is also demonstrated. SEMM could be used to store optical or microwave photons in ions and/or spins. This includes nitrogen-vacancy centers in diamond and rare-earth-doped crystals, which are among the most promising solid-state quantum memories.

  1. Stark Widths of Spectral Lines of Neutral Neon

    NASA Astrophysics Data System (ADS)

    Dimitrijević, Milan S.; Simić, Zoran; Kovačević, Andjelka; Valjarević, Aleksandar; Sahal-Bréchot, Sylvie

    2015-12-01

    In order to complete Stark broadening data for Ne I spectral lines which are needed for analysis of stellar atmospheres, collisional widths and shifts (the so-called Stark broadening parameters) of 29 isolated spectral lines of neutral neon have been determined within the impact semiclassical perturbation method. Calculations have been performed for the broadening by collisions with electrons, protons and ionized helium for astrophysical applications, and for collisions with ionized neon and argon for laboratory plasma diagnostics. The shifts have been compared with existing experimental values. The obtained data will be included in the STARK-B database, which is a part of the Virtual Atomic and Molecular Data Center - VAMDC.

  2. Stark shift and electric-field-induced dissociation of excitons in monolayer MoS2 and h BN /MoS2 heterostructures

    NASA Astrophysics Data System (ADS)

    Haastrup, Sten; Latini, Simone; Bolotin, Kirill; Thygesen, Kristian S.

    2016-07-01

    Efficient conversion of photons into electrical current in two-dimensional semiconductors requires, as a first step, the dissociation of the strongly bound excitons into free electrons and holes. Here we calculate the dissociation rates and energy shift of excitons in monolayer MoS2 as a function of an applied in-plane electric field. The dissociation rates are obtained as the inverse lifetime of the resonant states of a two-dimensional hydrogenic Hamiltonian which describes the exciton within the Mott-Wannier model. The resonances are computed using complex scaling, and the effective masses and screened electron-hole interaction defining the hydrogenic Hamiltonian are computed from first principles. For field strengths above 0.1 V/nm the dissociation lifetime is shorter than 1 ps, which is below the lifetime associated with competing decay mechanisms. Interestingly, encapsulation of the MoS2 layer in just two layers of hexagonal boron nitride (h BN ), enhances the dissociation rate by around one order of magnitude due to the increased screening. This shows that dielectric engineering is an effective way to control exciton lifetimes in two-dimensional materials.

  3. The Stark Effect in Linear Potentials

    ERIC Educational Resources Information Center

    Robinett, R. W.

    2010-01-01

    We examine the Stark effect (the second-order shifts in the energy spectrum due to an external constant force) for two one-dimensional model quantum mechanical systems described by linear potentials, the so-called quantum bouncer (defined by V(z) = Fz for z greater than 0 and V(z) = [infinity] for z less than 0) and the symmetric linear potential…

  4. A classical examination of the Stark effect in hydrogen

    NASA Astrophysics Data System (ADS)

    Hooker, Andrew; Greene, Chris H.; Clark, William

    1997-04-01

    The response of a hydrogen atom to a perturbative electric field (the Stark effect) is presented from a classical viewpoint. In previous studies Hezel et al. (T. P. Hezel, C. E. Burkhardt, M. Ciocca, and J. J. Leventhal, Am. J. Phys. 60), 324 (1992). examined the linear Stark effect classically and found that the linear Stark splitting of the degenerate hydrogenic energy levels (n-states) corresponds to a rotation of the plane of the electron orbit about the electric field vector. In the present work we find classical energy shifts (not just precession frequencies) in the hydrogen atom in situations that correspond to both the linear and quadratic Stark effects. We then compare these classical energy shifts to the exact quantum mechanical values for the Stark effect. We find that the linear Stark effect can be accurately reproduced classically (given the correct initial conditions). In contrast, quantum mechanical results for the quadratic Stark effect cannot be accurately reproduced classically, except in the correspondence principle limit of large principal quantum numbers n. A paper based on this work has been recently submitted to Phys. Rev. A(Preprints of this paper are avaliable on the internet at ftp://fermion.colorado.edu/pub/preprints/Sta rk/ .). This work was supported in part by the National Science Foundation.

  5. Why an ac magnetic field shifts the irreversibility line in type-II superconductors.

    PubMed

    Brandt, Ernst Helmut; Mikitik, Grigorii P

    2002-07-01

    We show that for a thin superconducting strip placed in a transverse dc magnetic field--the typical geometry of experiments with high-T(c) superconductors--the application of a weak ac magnetic field perpendicular to the dc field generates a dc voltage in the strip. This voltage leads to the decay of the critical currents circulating in the strip, and eventually the equilibrium state of the superconductor is established. This relaxation is not due to thermally activated flux creep but to the "walking" motion of vortices in the two-dimensional critical state of the strip with in-plane ac field. Our theory explains the shaking effect that was used for detecting phase transitions of the vortex lattice in superconductors.

  6. Anisotropic stark effect and electric-field noise suppression for phosphorus donor qubits in silicon.

    PubMed

    Sigillito, A J; Tyryshkin, A M; Lyon, S A

    2015-05-29

    We report the use of novel, capacitively terminated coplanar waveguide resonators to measure the quadratic Stark shift of phosphorus donor qubits in Si. We confirm that valley repopulation leads to an anisotropic spin-orbit Stark shift depending on electric and magnetic field orientations relative to the Si crystal. By measuring the linear Stark effect, we estimate the effective electric field due to strain in our samples. We show that in the presence of this strain, electric-field sources of decoherence can be non-negligible. Using our measured values for the Stark shift, we predict magnetic fields for which the spin-orbit Stark effect cancels the hyperfine Stark effect, suppressing decoherence from electric-field noise. We discuss the limitations of these noise-suppression points due to random distributions of strain and propose a method for overcoming them. PMID:26066457

  7. Anisotropic stark effect and electric-field noise suppression for phosphorus donor qubits in silicon.

    PubMed

    Sigillito, A J; Tyryshkin, A M; Lyon, S A

    2015-05-29

    We report the use of novel, capacitively terminated coplanar waveguide resonators to measure the quadratic Stark shift of phosphorus donor qubits in Si. We confirm that valley repopulation leads to an anisotropic spin-orbit Stark shift depending on electric and magnetic field orientations relative to the Si crystal. By measuring the linear Stark effect, we estimate the effective electric field due to strain in our samples. We show that in the presence of this strain, electric-field sources of decoherence can be non-negligible. Using our measured values for the Stark shift, we predict magnetic fields for which the spin-orbit Stark effect cancels the hyperfine Stark effect, suppressing decoherence from electric-field noise. We discuss the limitations of these noise-suppression points due to random distributions of strain and propose a method for overcoming them.

  8. The Stark II reality.

    PubMed

    Memel, Sherwin L; Grosvenor, John C

    2003-02-01

    The long awaited final regulations in Phase I of a two-phase rulemaking process under the Stark II law were published on January 4, 2001. The Phase I final rules govern interpretation of the Stark law as it is applied to referrals by a physician for designated categories of health services to entities in which the referring physician has a financial interest. These new regulations are of particular concern to specialists, such as orthopaedic surgeons, whose practices are oriented to ancillary services that are considered designated health services, such as radiology, physical therapy and durable medical equipment, and where the availability of clear guidance is essential to ensure that medically necessary care is provided in a manner that complies with law. However, rather than the "brightline" guidance that the healthcare community sought, the new regulations create uncertainty in areas that had not existed before. The new regulations require physicians to evaluate the full range of their business and professional relationships to avoid the risk of nonpayment of claims, civil money penalties, or program exclusion after the effective date of the new regulations. PMID:12567126

  9. Pressure dependence of backbone chemical shifts in the model peptides Ac-Gly-Gly-Xxx-Ala-NH2.

    PubMed

    Erlach, Markus Beck; Koehler, Joerg; Crusca, Edson; Kremer, Werner; Munte, Claudia E; Kalbitzer, Hans Robert

    2016-06-01

    For a better understanding of nuclear magnetic resonance (NMR) detected pressure responses of folded as well as unstructured proteins the availability of data from well-defined model systems are indispensable. In this work we report the pressure dependence of chemical shifts of the backbone atoms (1)H(α), (13)C(α) and (13)C' in the protected tetrapeptides Ac-Gly-Gly-Xxx-Ala-NH2 (Xxx one of the 20 canonical amino acids). Contrary to expectation the chemical shifts of these nuclei have a nonlinear dependence on pressure in the range from 0.1 to 200 MPa. The polynomial pressure coefficients B 1 and B 2 are dependent on the type of amino acid studied. The coefficients of a given nucleus show significant linear correlations suggesting that the NMR observable pressure effects in the different amino acids have at least partly the same physical cause. In line with this observation the magnitude of the second order coefficients of nuclei being direct neighbors in the chemical structure are also weakly correlated. PMID:27335085

  10. Pressure dependence of backbone chemical shifts in the model peptides Ac-Gly-Gly-Xxx-Ala-NH2.

    PubMed

    Erlach, Markus Beck; Koehler, Joerg; Crusca, Edson; Kremer, Werner; Munte, Claudia E; Kalbitzer, Hans Robert

    2016-06-01

    For a better understanding of nuclear magnetic resonance (NMR) detected pressure responses of folded as well as unstructured proteins the availability of data from well-defined model systems are indispensable. In this work we report the pressure dependence of chemical shifts of the backbone atoms (1)H(α), (13)C(α) and (13)C' in the protected tetrapeptides Ac-Gly-Gly-Xxx-Ala-NH2 (Xxx one of the 20 canonical amino acids). Contrary to expectation the chemical shifts of these nuclei have a nonlinear dependence on pressure in the range from 0.1 to 200 MPa. The polynomial pressure coefficients B 1 and B 2 are dependent on the type of amino acid studied. The coefficients of a given nucleus show significant linear correlations suggesting that the NMR observable pressure effects in the different amino acids have at least partly the same physical cause. In line with this observation the magnitude of the second order coefficients of nuclei being direct neighbors in the chemical structure are also weakly correlated.

  11. On the Absolutely Continuous Spectrum of Stark Operators

    NASA Astrophysics Data System (ADS)

    Perelman, Galina

    The stability of the absolutely continuous spectrum of the one-dimensional Stark operator under perturbations of the potential is discussed. The focus is on proving this stability under minimal assumptions on smoothness of the perturbation. A general criterion is presented together with some applications. These include the case of periodic perturbations where we show that any perturbation vL1()∩H-1/2() preserves the a.c. spectrum.

  12. Optical Stark effect in 2D semiconductors

    NASA Astrophysics Data System (ADS)

    Sie, Edbert J.; McIver, James W.; Lee, Yi-Hsien; Fu, Liang; Kong, Jing; Gedik, Nuh

    2016-05-01

    Semiconductors that are atomically thin can exhibit novel optical properties beyond those encountered in the bulk compounds. Monolayer transition-metal dichalcogenides (TMDs) are leading examples of such semiconductors that possess remarkable optical properties. They obey unique selection rules where light with different circular polarization can be used for selective photoexcitation at two different valleys in the momentum space. These valleys constitute bandgaps that are normally locked in the same energy. Selectively varying their energies is of great interest for applications because it unlocks the potential to control valley degree of freedom, and offers a new promising way to carry information in next-generation valleytronics. In this proceeding paper, we show that the energy gaps at the two valleys can be shifted relative to each other by means of the optical Stark effect in a controllable valley-selective manner. We discuss the physics of the optical Stark effect, and we describe the mechanism that leads to its valleyselectivity in monolayer TMD tungsten disulfide (WS2).

  13. On the shift of the electroluminescence spectra of In{sub x}Ga{sub 1−x}N/GaN structures with various indium contents and various substrate materials caused by the stark effect and mechanical stresses

    SciTech Connect

    Veleschuk, V. P. Vlasenko, A. I.; Kisselyuk, M. P.; Vlasenko, Z. K.; Khmil’, D. N.; Borshch, V. V.

    2015-08-15

    The shift between the maxima of the electroluminescence spectra of In{sub x}Ga{sub 1−x}N/GaN structures is measured at forward and reverse bias depending on the indium content x in the quantum well and on the substrate material (SiC, AuSn/Si, and Al{sub 2}O{sub 3}). It is established that this shift increases as the indium concentration in the In{sub x}Ga{sub 1−x}N layer and mechanical stresses from the substrate increase.

  14. Stark effect induced microcavity polariton solitons.

    PubMed

    Zhang, W L; Wu, X M; Wang, F; Ma, R; Li, X F; Rao, Y J

    2015-06-15

    This paper proposes a way of generating polariton solitons (PSs) in a semiconductor microcavity using Stark effect as the trigger mechanism. A Stark pulse performing as the writing beam is used to excite non-resonant fluctuations of polariton, which finally evolves into bright PSs. It is found that a branch of PS solutions versus pump parameters could be found through optimizing parameters of the Stark pulse, and polarization of the generated PS is dependent on the writing beam. PMID:26193554

  15. Imaging Electric Fields in SERS and TERS Using the Vibrational Stark Effect

    PubMed Central

    Marr, James M.; Schultz, Zachary D.

    2013-01-01

    Electric fields associated with Raman enhancements are typically inferred from changes in the observed scattering intensity. Here we use the vibrational Stark effect from a nitrile reporter to determine the electric field dependent frequency shift of cyanide (CN) on a gold (Au) surface. Electroplated Au surfaces with surface enhanced Raman (SERS) activity exhibit larger Stark shifts near the edge and in areas with large roughness. The Stark shift is observed to correlate with intensity of a co-adsorbed thiophenol molecule. Gap-mode Tip enhanced Raman scattering (TERS), using a Au nanoparticle tip, show dramatic shifts in the CN stretch that correlate to enhancement factors of 1013 in the gap region. The observed peak widths indicate the largest fields are highly localized. Changes in the nitrile stretch frequency provide a direct measurement of the electric fields in SERS and TERS experiments. PMID:24273634

  16. Molecular Beam Optical Stark Spectroscopy of Magnesium Deuteride

    NASA Astrophysics Data System (ADS)

    Steimle, Timothy; Zhang, Ruohan; Wang, Hailing

    2014-06-01

    Light polar, paramagnetic molecules, such as magnesium hydride, MgH, are attractive for slowing and trapping experiments because these molecules have both non-zero permanent electric dipole, μel, and magnetic dipole, μm moments. The permanent electric dipole moment is particularly relevant to Stark deceleration which depends on the ratio of the Stark shift to molecular mass. Here we report on the Stark effect in the (0,0) A2Π - X 2Σ+ band system of a cold molecular beam sample of magnesium deuteride, MgD. The lines associated with the lowest rotational levels are detected for the first time. The field-free spectrum was analyzed to produce an improved set of fine structure parameters for the A2Π(v = 0) state. The observed electric field induced splittings and shifts were analyzed to produce permanent electric dipole moments, μel,of 2.561(10)D and 1.34(8)D for A2Π(v = 0) and X2Σ+(v=0)states, respectively. This is the first molecular beam study of MgD.

  17. Stark broadening of B IV spectral lines

    NASA Astrophysics Data System (ADS)

    Dimitrijević, Milan S.; Christova, Magdalena; Simić, Zoran; Kovačević, Andjelka; Sahal-Bréchot, Sylvie

    2016-08-01

    Stark broadening parameters for 157 multiplets of helium-like boron (B IV) have been calculated using the impact semiclassical perturbation formalism. Obtained results have been used to investigate the regularities within spectral series. An example of the influence of Stark broadening on B IV lines in DO white dwarfs is given.

  18. Stark broadening data for stellar plasma research.

    NASA Astrophysics Data System (ADS)

    Dimitrijević, M. S.

    Results of an effort to provide to astrophysicists and physicists an as much as possible complete set of Stark broadening parameters needed for stellar opacity calculations, stellar atmosphere modelling, abundance determinations and diagnostics of different plasmas in astrophysics, physics and plasma technology, are presented. Stark broadening has been considered within the semiclassical perturbation, and the modified semiempirical approaches.

  19. Vibrational Stark effects calibrate the sensitivity of vibrational probes for electric fields in proteins.

    PubMed

    Suydam, Ian T; Boxer, Steven G

    2003-10-21

    Infrared spectroscopy is widely used to probe local environments and dynamics in proteins. The introduction of a unique vibration at a specific site of a protein or more complex assembly offers many advantages over observing the spectra of an unmodified protein. We have previously shown that infrared frequency shifts in proteins can arise from differences in the local electric field at the probe vibration. Thus, vibrational frequencies can be used to map electric fields in proteins at many sites or to measure the change in electric field due to a perturbation. The Stark tuning rate gives the sensitivity of a vibrational frequency to an electric field, and for it to be useful, the Stark tuning rate should be as large as possible. Vibrational Stark effect spectroscopy provides a direct measurement of the Stark tuning rate and allows a quantitative interpretation of frequency shifts. We present vibrational Stark spectra of several bond types, extending our work on nitriles and carbonyls and characterizing four additional bond types (carbon-fluorine, carbon-deuterium, azide, and nitro bonds) that are potential probes for electric fields in proteins. The measured Stark tuning rates, peak positions, and extinction coefficients provide the primary information needed to design amino acid analogues or labels to act as probes of local environments in proteins.

  20. Wannier-Stark localization in InAs/(GaIn)Sb superlattice diodes

    NASA Astrophysics Data System (ADS)

    Bürkle, L.; Fuchs, F.; Ahlswede, E.; Pletschen, W.; Schmitz, J.

    2001-07-01

    We present experimental evidence for the formation of localized Wannier-Stark states in the depletion region of low band-gap InAs/(GaIn)Sb superlattice (SL) infrared photodiodes. In the photocurrent spectra of reverse-biased photodiodes, maxima are observed, that spectrally shift when the strength of the electric field in the depletion region of the diode is changed. Taking into account the spatially indirect type-II nature of interband transitions in InAs/(GaIn)Sb SL's, the spectral positions of the observed maxima can be explained in the framework of localized Wannier-Stark states. Besides photocurrent spectra, the current-voltage (I-V) characteristics of the diodes were investigated. In the reverse-bias regime dominated by Zener tunneling the differential resistance of the diodes reveals an oscillatory behavior. These oscillations are due to a resonant enhancement of the Zener tunneling current by Wannier-Stark states in the depletion region of the SL diode. A model is presented that quantitatively describes the occurrence of the oscillations in the I-V curves. In addition, the influence of a magnetic field on the Wannier-Stark oscillations in the Zener current was investigated. While the period of the oscillations in the I-V curves is conserved, the resonances are shifted, reflecting the energy shift introduced in the Wannier-Stark states by the magnetic field. This voltage shift exhibits a strong dependence on the magnetic-field orientation.

  1. Large polarization-dependent exciton optical Stark effect in lead iodide perovskites.

    PubMed

    Yang, Ye; Yang, Mengjin; Zhu, Kai; Johnson, Justin C; Berry, Joseph J; van de Lagemaat, Jao; Beard, Matthew C

    2016-01-01

    A strong interaction of a semiconductor with a below-bandgap laser pulse causes a blue-shift of the bandgap transition energy, known as the optical Stark effect. The energy shift persists only during the pulse duration with an instantaneous response time. The optical Stark effect has practical relevance for applications, including quantum information processing and communication, and passively mode-locked femtosecond lasers. Here we demonstrate that solution-processable lead-halide perovskites exhibit a large optical Stark effect that is easily resolved at room temperature resulting from the sharp excitonic feature near the bandedge. We also demonstrate that a polarized pump pulse selectively shifts one spin state producing a spin splitting of the degenerate excitonic states. Such selective spin manipulation is an important prerequisite for spintronic applications. Our result implies that such hybrid semiconductors may have great potential for optoelectronic applications beyond photovoltaics. PMID:27577007

  2. Large polarization-dependent exciton optical Stark effect in lead iodide perovskites

    DOE PAGES

    Yang, Ye; Yang, Mengjin; Zhu, Kai; Johnson, Justin C.; Berry, Joseph J.; van de Lagemaat, Jao; Beard, Matthew C.

    2016-08-31

    A strong interaction of a semiconductor with a below-bandgap laser pulse causes a blue-shift of the bandgap transition energy, known as the optical Stark effect. The energy shift persists only during the pulse duration with an instantaneous response time. The optical Stark effect has practical relevance for applications, including quantum information processing and communication, and passively mode-locked femtosecond lasers. Here we demonstrate that solution-processable lead-halide perovskites exhibit a large optical Stark effect that is easily resolved at room temperature resulting from the sharp excitonic feature near the bandedge. We also demonstrate that a polarized pump pulse selectively shifts one spinmore » state producing a spin splitting of the degenerate excitonic states. Such selective spin manipulation is an important prerequisite for spintronic applications. Lastly, our result implies that such hybrid semiconductors may have great potential for optoelectronic applications beyond photovoltaics.« less

  3. Large polarization-dependent exciton optical Stark effect in lead iodide perovskites

    NASA Astrophysics Data System (ADS)

    Yang, Ye; Yang, Mengjin; Zhu, Kai; Johnson, Justin C.; Berry, Joseph J.; van de Lagemaat, Jao; Beard, Matthew C.

    2016-08-01

    A strong interaction of a semiconductor with a below-bandgap laser pulse causes a blue-shift of the bandgap transition energy, known as the optical Stark effect. The energy shift persists only during the pulse duration with an instantaneous response time. The optical Stark effect has practical relevance for applications, including quantum information processing and communication, and passively mode-locked femtosecond lasers. Here we demonstrate that solution-processable lead-halide perovskites exhibit a large optical Stark effect that is easily resolved at room temperature resulting from the sharp excitonic feature near the bandedge. We also demonstrate that a polarized pump pulse selectively shifts one spin state producing a spin splitting of the degenerate excitonic states. Such selective spin manipulation is an important prerequisite for spintronic applications. Our result implies that such hybrid semiconductors may have great potential for optoelectronic applications beyond photovoltaics.

  4. Large polarization-dependent exciton optical Stark effect in lead iodide perovskites

    PubMed Central

    Yang, Ye; Yang, Mengjin; Zhu, Kai; Johnson, Justin C.; Berry, Joseph J.; van de Lagemaat, Jao; Beard, Matthew C.

    2016-01-01

    A strong interaction of a semiconductor with a below-bandgap laser pulse causes a blue-shift of the bandgap transition energy, known as the optical Stark effect. The energy shift persists only during the pulse duration with an instantaneous response time. The optical Stark effect has practical relevance for applications, including quantum information processing and communication, and passively mode-locked femtosecond lasers. Here we demonstrate that solution-processable lead-halide perovskites exhibit a large optical Stark effect that is easily resolved at room temperature resulting from the sharp excitonic feature near the bandedge. We also demonstrate that a polarized pump pulse selectively shifts one spin state producing a spin splitting of the degenerate excitonic states. Such selective spin manipulation is an important prerequisite for spintronic applications. Our result implies that such hybrid semiconductors may have great potential for optoelectronic applications beyond photovoltaics. PMID:27577007

  5. Precision measurement of transition matrix elements via light shift cancellation.

    PubMed

    Herold, C D; Vaidya, V D; Li, X; Rolston, S L; Porto, J V; Safronova, M S

    2012-12-14

    We present a method for accurate determination of atomic transition matrix elements at the 10(-3) level. Measurements of the ac Stark (light) shift around "magic-zero" wavelengths, where the light shift vanishes, provide precise constraints on the matrix elements. We make the first measurement of the 5s - 6p matrix elements in rubidium by measuring the light shift around the 421 and 423 nm zeros through diffraction of a condensate off a sequence of standing wave pulses. In conjunction with existing theoretical and experimental data, we find 0.3235(9)ea(0) and 0.5230(8)ea(0) for the 5s - 6p(1/2) and 5s - 6p(3/2) elements, respectively, an order of magnitude more accurate than the best theoretical values. This technique can provide needed, accurate matrix elements for many atoms, including those used in atomic clocks, tests of fundamental symmetries, and quantum information. PMID:23368314

  6. Transverse stability in a Stark decelerator

    SciTech Connect

    Meerakker, Sebastiaan Y. T. van de; Bethlem, Hendrick L.; Vanhaecke, Nicolas; Meijer, Gerard

    2006-02-15

    The concept of phase stability in a Stark decelerator ensures that polar molecules can be accelerated, guided, or decelerated without loss; molecules within a certain position and velocity interval are kept together throughout the deceleration process. In this paper the influence of the transverse motion on phase stability in a Stark decelerator is investigated. For typical deceleration experiments--i.e., for high values of the phase angle {phi}{sub 0}--the transverse motion considerably enhances the region in phase space for which phase stable deceleration occurs. For low values of {phi}{sub 0}, however, the transverse motion reduces the acceptance of a Stark decelerator and unstable regions in phase space appear. These effects are quantitatively explained in terms of a coupling between the longitudinal and transverse motion. The predicted longitudinal acceptance of a Stark decelerator is verified by measurements on a beam of OH (X {sup 2}{pi}{sub 3/2},J=3/2) radicals passing through a Stark decelerator.

  7. Measurement of Linear Stark Interference in {sup 199}Hg

    SciTech Connect

    Loftus, T. H.; Swallows, M. D.; Griffith, W. C.; Romalis, M. V.; Heckel, B. R.; Fortson, E. N.

    2011-06-24

    We present measurements of Stark interference in the 6{sup 1}S{sub 0}{yields}6{sup 3}P{sub 1} transition in {sup 199}Hg, a process whereby a static electric field E mixes magnetic dipole and electric quadrupole couplings into an electric dipole transition, leading to E-linear energy shifts similar to those produced by a permanent atomic electric dipole moment (EDM). The measured interference amplitude, a{sub SI}=(a{sub M1}+a{sub E2})=(5.8{+-}1.5)x10{sup -9} (kV/cm){sup -1}, agrees with relativistic, many-body predictions and confirms that earlier central-field estimates are a factor of 10 too large. More importantly, this study validates the capability of the {sup 199}Hg EDM search apparatus to resolve nontrivial, controlled, and sub-nHz Larmor frequency shifts with EDM-like characteristics.

  8. Valley-selective optical Stark effect in monolayer WS2

    NASA Astrophysics Data System (ADS)

    Gedik, Nuh

    Monolayer semiconducting transition-metal dichalcogenides (TMDs) have a pair of valleys that, by time-reversal symmetry, are energetically degenerate. Lifting the valley degeneracy in these materials is of great interest because it would allow for valley specific band engineering and offer additional control in valleytronic applications. In this talk, I will show that circularly polarized light, which breaks time-reversal symmetry, can be used to lift the valley degeneracy by means of the optical Stark effect. We demonstrate that this effect is capable of raising the exciton level in monolayer TMD WS2 by as much as 18 meV in a controllable valley-selective manner. The resulting energy shift is extremely large, comparable to the shift that would be obtained using a very high magnetic field (approximately 100 Tesla). These results offer a novel way to control valley degree of freedom, and may provide a means to realize new valley-selective Floquet topological state of matter.

  9. Valley selective optical Stark effect in monolayer WS2

    NASA Astrophysics Data System (ADS)

    Sie, Edbert J.; McIver, James W.; Lee, Yi-Hsien; Fu, Liang; Kong, Jing; Gedik, Nuh

    2015-03-01

    Monolayer semiconductors, such as WS2, have a pair of valleys that, by time-reversal symmetry, are energetically degenerate. Lifting the valley degeneracy in these materials is of great interest because it would allow for valley specific band engineering and offer additional control in valleytronic applications. Here we show that circularly polarized light, which breaks time-reversal symmetry, can be used to lift the valley degeneracy by means of the optical Stark effect. We demonstrate that this effect is capable of raising the exciton level in monolayer WS2 by as much as 18 meV in a controllable valley selective manner. The resulting energy shift is extremely large, comparable to the shift that would be obtained using a very high magnetic field (200 Tesla). These results offer a novel way to control valley degree of freedom, and may provide a means to realize new valley-selective Floquet topological state of matter.

  10. A high spatial resolution Stokes polarimeter for motional Stark effect imaging.

    PubMed

    Thorman, Alex; Michael, Clive; Howard, John

    2013-06-01

    We describe an enhanced temporally switched interfero-polarimeter that has been successfully deployed for high spatial resolution motional Stark effect imaging on the KSTAR superconducting tokamak. The system utilizes dual switching ferroelectric liquid crystal waveplates to image the full Stokes vector of elliptically polarized and Doppler-shifted Stark-Zeeman Balmer-alpha emission from high energy neutral beams injected into the magnetized plasma. We describe the optical system and compare its performance against a Mueller matrix model that takes account of non-ideal performance of the switching ferro-electric liquid crystal waveplates and other polarizing components. PMID:23822345

  11. Sub-Doppler Stark Spectroscopy in the A−X (1,0) Band of CN

    SciTech Connect

    Hall, G.E.; Hause, M.L.; Sears, T.J.

    2009-11-26

    The effect of external electric fields has been measured in hyperfine-resolved sub-Doppler transitions in the A {sup 2}{Pi}-X {sup 2}{Sigma} (1,0) band of the CN radical near 10900 cm{sup -1}. Static electric fields less than 1 kV/cm are sufficient to mix the most closely spaced {Lambda}-dpublets in the A state, leading to Stark spectra with both new and shifted resonances. Simulations of the saturation-dip Stark spectral line profiles allow extraction of the A-state permanent electric dipole moment with a magnitude of 0.06 {+-} 0.02 D.

  12. A high spatial resolution Stokes polarimeter for motional Stark effect imaging

    SciTech Connect

    Thorman, Alex; Michael, Clive; Howard, John

    2013-06-15

    We describe an enhanced temporally switched interfero-polarimeter that has been successfully deployed for high spatial resolution motional Stark effect imaging on the KSTAR superconducting tokamak. The system utilizes dual switching ferroelectric liquid crystal waveplates to image the full Stokes vector of elliptically polarized and Doppler-shifted Stark-Zeeman Balmer-alpha emission from high energy neutral beams injected into the magnetized plasma. We describe the optical system and compare its performance against a Mueller matrix model that takes account of non-ideal performance of the switching ferro-electric liquid crystal waveplates and other polarizing components.

  13. Light shift measurements in a Cesium Fountain without the use of mechanical shutters

    NASA Technical Reports Server (NTRS)

    Tjoelker, Robert L.; Enzer, D. G.; Klipstein, W. M.

    2005-01-01

    We present measurements confirming operation of a cesium fountain frequency standard with light shift below 10^-15 (and with evidence suggesting it is several orders of magnitude below this level) but without the use of mechanical shutters. Suppression of the light shift is realized using a master-slave laser configuration by reducing the overall optical power delivered to the physics package as well as spoiling the injection of the slave, causing it to lase far off resonance (1-2 nm) as proposed by the authors several years ago [l]. In the absence of any mitigation, this (AC Stark) shift, due to near-resonant laser light reaching the atoms during their microwave interrogation period, is the largest shift in such frequency standards (2x10^-11 for Our fountain). Mechanical shutters provided adequate light attenuation but have been prone to failure.

  14. Laser-assisted Stark deceleration of polar diatomic molecules in the Χ1Σ state

    NASA Astrophysics Data System (ADS)

    Huang, Yunxia; Xu, Shuwu; Yang, Xiaohua

    2016-07-01

    The traditional Stark deceleration method is difficult to apply in chemically stable polar diatomic molecules in their ground (Χ1Σ) state because the Χ1Σ state normally experiences little Stark shift and the rovibronic ground level is mostly high-field-seeking. To solve this problem, we propose a laser-assisted Stark deceleration scheme to decelerate such molecules in the present paper. Our results show that, owing to the transverse bunching effect of the applied red-detuning laser beam, the molecules of the high-field-seeking level |J = 0, M = 0> in the Χ1Σ state can be effectively decelerated. Furthermore, the present scheme is more effective because the interaction between the molecules and the combined fields can produce the pseudo-first-order Stark effect, and thus increase the depth of the effective potential. Compared to those molecules in the low-field-seeking state |J = 1, MΩ = ‑1> in the usual electrostatic Stark deceleration, a higher molecular density and lower velocity can be achieved under an equivalent initial phase angle.

  15. Laser-assisted Stark deceleration of polar diatomic molecules in the Χ1Σ state

    NASA Astrophysics Data System (ADS)

    Huang, Yunxia; Xu, Shuwu; Yang, Xiaohua

    2016-07-01

    The traditional Stark deceleration method is difficult to apply in chemically stable polar diatomic molecules in their ground (Χ1Σ) state because the Χ1Σ state normally experiences little Stark shift and the rovibronic ground level is mostly high-field-seeking. To solve this problem, we propose a laser-assisted Stark deceleration scheme to decelerate such molecules in the present paper. Our results show that, owing to the transverse bunching effect of the applied red-detuning laser beam, the molecules of the high-field-seeking level |J = 0, M = 0> in the Χ1Σ state can be effectively decelerated. Furthermore, the present scheme is more effective because the interaction between the molecules and the combined fields can produce the pseudo-first-order Stark effect, and thus increase the depth of the effective potential. Compared to those molecules in the low-field-seeking state |J = 1, MΩ = -1> in the usual electrostatic Stark deceleration, a higher molecular density and lower velocity can be achieved under an equivalent initial phase angle.

  16. Nominees Serve Up Stark Differences on Education

    ERIC Educational Resources Information Center

    Klein, Alyson

    2012-01-01

    During the recently concluded presidential nominating conventions, President Barack Obama and former Massachusetts Gov. Mitt Romney offered stark choices on K-12 policy while downplaying areas of agreement between their two parties--and the tensions within each party on education issues. In Charlotte, North Carolina, last week, the Democrats put a…

  17. Full color modulation of firefly luciferase through engineering with unified Stark effect.

    PubMed

    Cai, Duanjun; Marques, Miguel A L; Nogueira, Fernando

    2013-11-01

    The firefly luciferase has been a unique marking tool used in various bioimaging techniques. Extensive color modulation is strongly required to meet special marking demands; however, intentional and accurate wavelength tuning has yet to be achieved. Here, we demonstrate that the color shift of the firefly chromophore (OxyLH2-1) by internal and external fields can be described as a unified Stark shift. Electrostatic microenvironmental effects on fluorescent spectroscopy are modeled in vacuo through effective electric fields by using time-dependent density functional theory. A complete visible fluorescence spectrum of firefly chromophore is depicted, which enables one to control the emission in a specific color. As an application, the widely observed pH-correlated color shift is proved to be associated with the local Stark field generated by the trace water-ions (vicinal hydronium and hydroxide ions) at active sites close to the OxyLH2-1.

  18. Motional Stark effect diagnostic on TEXTOR

    NASA Astrophysics Data System (ADS)

    Jakubowska, K.; De Bock, M.; Jaspers, R.; von Hellermann, M.; Shmaenok, L.

    2004-10-01

    A motional Stark effect diagnostic at the tokamak TEXTOR has been constructed and brought recently into operation. In contrast to diagnostics used on other tokamaks, this diagnostic reveals the direction of the magnetic field from the intensity ratio of the π and σ components of the emitted Balmer-α and not from a polarization measurement of a single line. Moreover, the complete spectrum is measured which allows determining the radial position of the measurement, and in principle the radial electric field.

  19. Calibration of Electric Field Induced Energy Level Shifts in Argon

    NASA Astrophysics Data System (ADS)

    Hebner, Greg

    1999-10-01

    Argon is a commonly used gas in a number of discharges. As such it is an ideal candidate for spectroscopic based electric field measurements within the sheath and bulk discharge regions. Recently, measurements demonstrated the use of the Stark induced shifts of high lying energy levels in Argon to make spatially and temporally resolved electric field measurements [1]. However, that method relied on the cross calibration of known and calculable shifts in helium discharges to calibrate, in-situ, the energy level shifts in Argon. This poster shows the use of an atomic beam system to calibrate the electric field induced shift of high lying energy levels directly. In addition, data on very high lying argon levels, up to the 20 F manifold, were obtained. Comparison of our electric field induced energy level shift calibration curves with previous work will be shown. The possibility of using this system to calibrate energy level shifts in other gases of technological interest to the microelectronics and lighting industry will be discussed. [1]. J. B. Kim, K. Kawamura, Y. W. Choi, M. D. Bowden, K. Muraoka and V. Helbig, IEEE Transactions on Plasma Science, 26(5), 1556 (1998). This work was performed at Sandia National Laboratories and supported by the United States Department of Energy (DE-AC04-94AL85000).

  20. Analytic wave model of Stark deceleration dynamics

    SciTech Connect

    Gubbels, Koos; Meijer, Gerard; Friedrich, Bretislav

    2006-06-15

    Stark deceleration relies on time-dependent inhomogeneous electric fields which repetitively exert a decelerating force on polar molecules. Fourier analysis reveals that such fields, generated by an array of field stages, consist of a superposition of partial waves with well-defined phase velocities. Molecules whose velocities come close to the phase velocity of a given wave get a ride from that wave. For a square-wave temporal dependence of the Stark field, the phase velocities of the waves are found to be odd-fraction multiples of a fundamental phase velocity {lambda}/{tau}, with {lambda} and {tau} the spatial and temporal periods of the field. Here we study explicitly the dynamics due to any of the waves as well as due to their mutual perturbations. We first solve the equations of motion for the case of single-wave interactions and exploit their isomorphism with those for the biased pendulum. Next we analyze the perturbations of the single-wave dynamics by other waves and find that these have no net effect on the phase stability of the acceleration or deceleration process. Finally, we find that a packet of molecules can also ride a wave which results from an interference of adjacent waves. In this case, small phase stability areas form around phase velocities that are even-fraction multiples of the fundamental velocity. A detailed comparison with classical trajectory simulations and with experiment demonstrates that the analytic 'wave model' encompasses all the longitudinal physics encountered in a Stark decelerator.

  1. Vibrational Stark Effect Probes for Nucleic Acids

    PubMed Central

    Silverman, Lisa N.; Pitzer, Michael E.; Ankomah, Peter O.; Boxer, Steven G.; Fenlon, Edward E.

    2008-01-01

    The vibrational Stark effect (VSE) has proven to be an effective method for the study of electric fields in proteins via the use of infrared probes. In order to explore the use of VSE in nucleic acids, the Stark spectroscopy of nine structurally diverse nucleosides was investigated. These nucleosides contained nitrile or azide probes in positions that correspond to both the major and minor grooves of DNA. The nitrile probes showed better characteristics and exhibited absorption frequencies over a broad range; i.e., from 2253 cm−1 for 2′-O-cyanoethyl ribonucleosides 8 and 9 to 2102 cm−1 for a 13C-labeled 5-thiocyanatomethyl-2’-deoxyuridine 3c. The largest Stark tuning rate observed was |Δµ| = 1.1 cm−1/(MV/cm) for both 5-cyano-2′-deoxyuridine 1 and N2-nitrile-2′-deoxyguanosine 7. The latter is a particularly attractive probe because of its high extinction coefficient (ε = 412 M−1cm−1) and ease of incorporation into oligomers. PMID:17877390

  2. Stark parameters irregularities of Xe II lines obtained by transitions from ({sup 3}P{sub 1})6plevels

    SciTech Connect

    Mar, S.; Pelaez, R. J.; Rodriguez, F.; Aparicio, J. A.

    2008-10-22

    Stark widths and shifts of some Xe II lines belonging to the supermultiplets with upper levels ({sup 3}P{sub 1})6p were measured using a pulsed discharge lamp. Plasma parameters, i.e. electron density and temperature, in this experiment were in the range from 0.2 to 1.4x10{sup 23} m{sup -3} and from 18000 to 23000 K, respectively. Lines obtained by transitions from levels ({sup 3}P{sub 1})6p show some strong intra-supermultiplet irregularities in their Stark widths and shifts. These results and the measurements obtained in previous works were used here to analyse the main irregularities that can appear in the case of Xe II. This study may be very useful for obtaining Stark parameters of non-measured lines, using the known parameters of other lines belonging to similar transitions.

  3. Enhanced Stark Tuning of Single InAs (211 )B Quantum Dots due to Nonlinear Piezoelectric Effect in Zincblende Nanostructures

    NASA Astrophysics Data System (ADS)

    Germanis, S.; Katsidis, C.; Tsintzos, S.; Stavrinidis, A.; Konstantinidis, G.; Florini, N.; Kioseoglou, J.; Dimitrakopulos, G. P.; Kehagias, Th.; Hatzopoulos, Z.; Pelekanos, N. T.

    2016-07-01

    We report enhanced Stark tuning of single exciton lines in self-assembled (211 )B InAs quantum dots (QDs) as a consequence of pronounced piezoelectric effects in polar orientations, making this QD system particularly sensitive to relatively "small" applied external fields. The Stark shifts in the first hundreds of kilovolts per centimeter of applied external field are at least 2.5 times larger, compared to those observed in nonpiezoelectric (100) InAs QDs of similar size. To account quantitatively for the observed transition energies and Stark shifts, we utilize a graded In-composition potential profile, as deduced from local strain analysis performed on high-resolution transmission microscopy images of the QDs. Our results provide a direct demonstration of the importance of nonlinear piezoelectric effects in zincblende semiconductors.

  4. Electrostatically Shielded Quantum Confined Stark Effect Inside Polar Nanostructures

    PubMed Central

    2009-01-01

    The effect of electrostatic shielding of the polarization fields in nanostructures at high carrier densities is studied. A simplified analytical model, employing screened, exponentially decaying polarization potentials, localized at the edges of a QW, is introduced for the ES-shielded quantum confined Stark effect (QCSE). Wave function trapping within the Debye-length edge-potential causes blue shifting of energy levels and gradual elimination of the QCSE red-shifting with increasing carrier density. The increase in the e−h wave function overlap and the decrease of the radiative emission time are, however, delayed until the “edge-localization” energy exceeds the peak-voltage of the charged layer. Then the wave function center shifts to the middle of the QW, and behavior becomes similar to that of an unbiased square QW. Our theoretical estimates of the radiative emission time show a complete elimination of the QCSE at doping densities ≥1020 cm−3, in quantitative agreement with experimental measurements. PMID:20596407

  5. Engineering Stark Potentials for Precision Measurements: Optical Lattice Clock and Electrodynamic Surface Trap

    SciTech Connect

    Katori, Hidetoshi; Takamoto, Masao; Hachisu, Hidekazu; Fujiki, Jun; Higashi, Ryoichi; Yasuda, Masami; Kishimoto, Tetsuo

    2005-05-05

    Employing the engineered electric fields, we demonstrate novel platforms for precision measurements with neutral atoms. (1) Applying the light shift cancellation technique, atoms trapped in an optical lattice reveal 50-Hz-narrow optical spectrum, yielding nearly an order of magnitude improvement over existing neutral-atom-based clocks. (2) Surface Stark trap has been developed to manipulate scalar atoms that are intrinsically robust to decoherence.

  6. Stark broadening measurements in plasmas produced by laser ablation of hydrogen containing compounds

    NASA Astrophysics Data System (ADS)

    Burger, Miloš; Hermann, Jörg

    2016-08-01

    We present a method for the measurement of Stark broadening parameters of atomic and ionic spectral lines based on laser ablation of hydrogen containing compounds. Therefore, plume emission spectra, recorded with an echelle spectrometer coupled to a gated detector, were compared to the spectral radiance of a plasma in local thermal equilibrium. Producing material ablation with ultraviolet nanosecond laser pulses in argon at near atmospheric pressure, the recordings take advantage of the spatially uniform distributions of electron density and temperature within the ablated vapor. By changing the delay between laser pulse and detector gate, the electron density could be varied by more than two orders of magnitude while the temperature was altered in the range from 6,000 to 14,000 K. The Stark broadening parameters of transitions were derived from their simultaneous observation with the hydrogen Balmer alpha line. In addition, assuming a linear increase of Stark widths and shifts with electron density for non-hydrogenic lines, our measurements indicate a change of the Stark broadening-dependence of Hα over the considered electron density range. The presented results obtained for hydrated calcium sulfate (CaSO4ṡ2H2O) can be extended to any kind of hydrogen containing compounds.

  7. Experimental measurements of Stark widths for Mn I lines in long laser spark

    NASA Astrophysics Data System (ADS)

    Popov, Andrey M.; Akhmetzhanov, Timur F.; Labutin, Timur A.; Zaytsev, Sergey M.; Zorov, Nikita B.; Chekalin, Nikolay V.

    2016-11-01

    We report the experimental Stark widths of Mn I lines belonging to multiplets z6P° → a6S and z6D° → a6D in long spark induced by laser. We have used aluminum alloy containing 80 ppm of manganese as a target to avoid strong self-absorption of Mn I lines. Its absence was proved by the comparison of observed intensities with relative strengths of lines within multiplets. Electron density of plasma estimated by Mg I (5172.68 Å) and Al II (2816.18 Å) lines was within the range of (4-30) × 1016 cm- 3. The shortest possible gate allowed the observation of symmetric atomic and ionic lines. The spatial profiles of plasma temperature and electron density along the axis of long spark demonstrated that both values were lower than for spherical plasma. Measured Stark widths of resonance multiplet z6P° → a6S decrease from 0.075 Å for its first component to 0.055 Å for the last one, while Stark widths of components of multiplet z6D° → a6D increase from 0.095 Å to 0.125 Å. No Stark shifting was observed for the studied multiplets.

  8. Science Translator: An Interview with Louisa Stark.

    PubMed

    Stark, Louisa A

    2015-07-01

    The Genetics Society of America's Elizabeth W. Jones Award for Excellence in Education recognizes significant and sustained impact on genetics education. The 2015 awardee, Louisa Stark, has made a major impact on global access to genetics education through her work as director of the University of Utah Genetic Science Learning Center. The Center's Learn.Genetics and Teach.Genetics websites are the most widely used online genetic education resources in the world. In 2014, they were visited by 18 million students, educators, scientists, and members of the public. With over 60 million page views annually, Learn.Genetics is among the most used sites on the Web. PMID:26170441

  9. Science Translator: An Interview with Louisa Stark.

    PubMed

    Stark, Louisa A

    2015-07-01

    The Genetics Society of America's Elizabeth W. Jones Award for Excellence in Education recognizes significant and sustained impact on genetics education. The 2015 awardee, Louisa Stark, has made a major impact on global access to genetics education through her work as director of the University of Utah Genetic Science Learning Center. The Center's Learn.Genetics and Teach.Genetics websites are the most widely used online genetic education resources in the world. In 2014, they were visited by 18 million students, educators, scientists, and members of the public. With over 60 million page views annually, Learn.Genetics is among the most used sites on the Web.

  10. Stark Broadening in Compact Stars: Xe VI Lines

    NASA Astrophysics Data System (ADS)

    Dimitrijević, Milan S.; Simić, Zoran; Kovačević, Andjelka; Valjarević, Aleksandar; Sahal-Bréchot, Sylvie

    2015-12-01

    We will consider Stark broadening of non hydrogenic spectral lines in the impact approximation in compact stars: pre-white dwarf and white dwarf atmospheres. In order to show an example, Stark broadening parameters have been calculated, using the impact semiclassical perturbation approach for four Xe VI spectral lines. Obtained results have been used to demonstrate the influence of Stark broadening in DA and DB white dwarf atmospheres.

  11. Atomic Models for Motional Stark Effects Diagnostics

    SciTech Connect

    Gu, M F; Holcomb, C; Jayakuma, J; Allen, S; Pablant, N A; Burrell, K

    2007-07-26

    We present detailed atomic physics models for motional Stark effects (MSE) diagnostic on magnetic fusion devices. Excitation and ionization cross sections of the hydrogen or deuterium beam traveling in a magnetic field in collisions with electrons, ions, and neutral gas are calculated in the first Born approximation. The density matrices and polarization states of individual Stark-Zeeman components of the Balmer {alpha} line are obtained for both beam into plasma and beam into gas models. A detailed comparison of the model calculations and the MSE polarimetry and spectral intensity measurements obtained at the DIII-D tokamak is carried out. Although our beam into gas models provide a qualitative explanation for the larger {pi}/{sigma} intensity ratios and represent significant improvements over the statistical population models, empirical adjustment factors ranging from 1.0-2.0 must still be applied to individual line intensities to bring the calculations into full agreement with the observations. Nevertheless, we demonstrate that beam into gas measurements can be used successfully as calibration procedures for measuring the magnetic pitch angle through {pi}/{sigma} intensity ratios. The analyses of the filter-scan polarization spectra from the DIII-D MSE polarimetry system indicate unknown channel and time dependent light contaminations in the beam into gas measurements. Such contaminations may be the main reason for the failure of beam into gas calibration on MSE polarimetry systems.

  12. Observation of a motional Stark effect to determine the second-order Doppler effect.

    PubMed

    Hagel, G; Battesti, R; Nez, F; Julien, L; Biraben, F

    2002-11-11

    The high resolution two-photon spectroscopy of hydrogen is often limited by the second-order Doppler effect. To determine this effect, we apply a magnetic field perpendicular to the atomic beam. This field induces a quadratic motional Stark shift proportional, as the second-order Doppler effect, to v(2) (v atomic velocity). For some magnetic field, these two effects are opposite and the total shift due to the atomic velocity is reduced. We present the first observation of this effect for the 1S-3S transition in hydrogen.

  13. Significance of decay mechanism into continuum in dynamical Wannier-Stark ladder

    SciTech Connect

    Nemoto, Yuya; Maeshima, Nobuya; Hino, Ken-ichi

    2013-12-04

    We examine the resonance structure of photodressed electron states of laser-driven Wannier-Stark ladder, namely, dynamic Wannier-Stark ladder, in terms of the excess density of states (DOS) closely related to a lifetime of the state of concern. It is revealed that the resonance structure in the strong laser-field region shows clear dependence on the ratio, η, of a Bloch-frequency to a laser frequency. As the laser strength increases, for η = 1, the excess DOS becomes involved with a lot of newly-growing resonance peaks. This result would be understood from the viewpoint of a Fano-like decay-mechanism caused by a multichannel continuum effect, in marked contrast to the cases of larger η’s; for η = 3, the excess DOS just is found to show a pronounced red-shift of a single dominant peak caused by a single-channel continuum effect.

  14. 1. VIEW LOOKING WEST AT STARK MILL WAREHOUSES FROM ROOF ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. VIEW LOOKING WEST AT STARK MILL WAREHOUSES FROM ROOF OF MILL. THE WAREHOUSES WERE BUILT USING SLOW-BURNING TIMBER AND BRICK CONSTRUCTION AND INCLUDED THE PICKER ROOM. NOTE ORIGINAL WATER TANK ON LEFT AND BOILER STACK IN RIGHT BACKGROUND. - Stark Mill, Warehouses, 117 Corinth Road, Hogansville, Troup County, GA

  15. 1. VIEW FROM ROOF OF MILL LOOKING SOUTHWEST AT STARK ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. VIEW FROM ROOF OF MILL LOOKING SOUTHWEST AT STARK MILL HOUSING ON CORINTH ROAD. THESE FRONT GABLE BUNGALOWS WERE BUILT AS OVERSEERS HOUSES FOR NEW ENGLAND SOUTHERN MILLS IN HOGANSVILLE IN 1923-1924. THE MILL ENGINEERS FOR STARK MILL, LOCKWOOD GREENE COMPANY, ALSO BUILT THE NEW WORKER HOUSING. - 110 Corinth Road (House), 110 Corinth Road, Hogansville, Troup County, GA

  16. Quantitative calibration of radiofrequency NMR Stark effects

    NASA Astrophysics Data System (ADS)

    Tarasek, Matthew R.; Kempf, James G.

    2011-10-01

    Nuclear magnetic resonance (NMR) Stark responses can occur in quadrupolar nuclei for an electric field oscillating at twice the usual NMR frequency (2ω0). Calibration of responses to an applied E field is needed to establish nuclear spins as probes of native E fields within material and molecular systems. We present an improved approach and apparatus for accurate measurement of quadrupolar Stark effects. Updated values of C14 (the response parameter in cubic crystals) were obtained for both 69Ga and 75As in GaAs. Keys to improvement include a modified implementation of voltage dividers to assess the 2ω0 amplitude, |E|, and the stabilization of divider response by reduction of stray couplings in 2ω0 circuitry. Finally, accuracy was enhanced by filtering sets of |E| through a linear response function that we established for the radiofrequency amplifier. Our approach is verified by two types of spectral results. Steady-state 2ω0 excitation to presaturate NMR spectra yielded C14 = (2.59 ± 0.06) × 1012 m-1 for 69Ga at room-temperature and 14.1 T. For 75As, we obtained (3.1 ± 0.1) × 1012 m-1. Both values reconcile with earlier results from 77 K and below 1 T, whereas current experiments are at room temperature and 14.1 T. Finally, we present results where few-microsecond pulses of the 2ω0 field induced small (tens of Hz) changes in high-resolution NMR line shapes. There too, spectra collected vs |E| agree with the model for response, further establishing the validity of our protocols to specify |E|.

  17. Preparations for the motional Stark effect diagnostic on EAST

    SciTech Connect

    Fu, J.; Li, Y. Y.; Lyu, B. Sheng, P.; Wan, B. N.; Zhang, Y.; Yin, X. H.; Yu, Y.; Ye, M. Y.; Shi, Y. J.

    2014-11-15

    Measurement and control of the current profile is essential for high performance and steady state operation of Experimental Advanced Superconducting Tokamak (EAST). For this purpose, a conventional Motional Stark Effect (MSE) diagnostics utilizing photoelastic modulators is proposed and investigated. The pilot experiment includes one channel to verify the feasibility of MSE, whose sightline intersects with Neutral Beam Injection at major radius of R = 2.12 m. A beam splitter is adopted for simultaneous measurements of Stark multiplets and their polarization directions. A simplified simulation code was also developed to explore the Stark splitting spectra. Finally, the filter is optimized based on the viewing geometry and neutral beam parameters.

  18. Stark-assisted population control of coherent CS(2) 4f and 5p Rydberg wave packets studied by femtosecond time-resolved photoelectron spectroscopy.

    PubMed

    Knappenberger, Kenneth L; Lerch, Eliza-Beth W; Wen, Patrick; Leone, Stephen R

    2007-09-28

    A two-color (3+1(')) pump-probe scheme is employed to investigate Rydberg wave packet dynamics in carbon disulfide (CS(2) (*)). The state superpositions are created within the 4f and 5p Rydberg manifolds by three photons of the 400 nm pump pulse, and their temporal evolution is monitored with femtosecond time-resolved photoelectron spectroscopy using an 800 nm ionizing probe pulse. The coherent behavior of the non-stationary superpositions are observed through wavepacket revivals upon ionization to either the upper (12) or lower (32) spin-orbit components of CS(2) (+). The results show clearly that the composition of the wavepacket can be efficiently controlled by the power density of the excitation pulse over a range from 500 GWcm(2) to 10 TWcm(2). The results are consistent with the anticipated ac-Stark shift for 400 nm light and demonstrate an effective method for population control in molecular systems. Moreover, it is shown that Rydberg wavepackets can be formed in CS(2) with excitation power densities up to 10 TWcm(2) without significant fragmentation. The exponential 1e population decay (T(1)) of specific excited Rydberg states are recovered by analysis of the coherent part of the signal. The dissociation lifetimes of these states are typically 1.5 ps. However, a region exhibiting a more rapid decay ( approximately 800 fs) is observed for states residing in the energy range of 74 450-74 550 cm(-1), suggestive of an enhanced surface crossing in this region.

  19. Measurements of some ZnII Stark widths

    SciTech Connect

    Mayo, R.; Ortiz, M.

    2008-10-22

    The Stark broadening parameters of six lines of Zn II (4 measured for the first time) have been measured in a plasma produced by ablation of a Cd-Zn alloy with a Nd:YAG laser. The broadening parameters were obtained in molecular Argon at 6 Torr. A Boltzmann plot was used to obtain the plasma temperature and published values of the Stark broadening in Cd II and Saha's equation to obtain the electron density. The Local Thermodynamic Equilibrium condition was checked. Contributions to broadening arising from a mechanism different from the Stark broadening as well as self-absorption influence were estimated for every studied line. A comparison is made with previous experimental values and recent theoretical estimates of the Stark broadening where possible.

  20. Vibrational solvatochromism of nitrile infrared probes: beyond the vibrational Stark dipole approach.

    PubMed

    Błasiak, Bartosz; Ritchie, Andrew W; Webb, Lauren J; Cho, Minhaeng

    2016-07-21

    Systematic probing of local environments around biopolymers is important for understanding their functions. Therefore, there has been growing interest in in situ measurements of molecular granularity and heterogeneity through the systematic analysis of vibrational frequency shifts of carbonyl and nitrile infrared probes by vibrational Stark dipole theory. However, here we show that the nitrile vibrational frequency shift induced by its interaction with the surrounding molecules cannot be solely described by electric field-based theory because of the exchange-repulsion and dispersion interaction contributions. Considering a variety of molecular environments ranging from bulk solutions to protein environments, we explore the distinct scenarios of solute-environment contacts and their traces in vibrational frequency shifts. We believe that the present work could provide a set of clues that could be potentially used to design a rigorous theoretical model linking vibrational solvatochromism and molecular topology in complex heterogeneous environments. PMID:27326899

  1. 1. VIEW LOOKING NORTHWEST AT MAIN ELEVATION OF STARK MILL, ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    1. VIEW LOOKING NORTHWEST AT MAIN ELEVATION OF STARK MILL, A REINFORCED CONCRETE MILL BUILT BY NEW ENGLAND SOUTHERN MILLS IN 1923-24. THE MILL WAS DESIGNED BY LOCKWOOD GREENE ENGINEERS, AND CONTAINED 35,000 SPINDLES FOR MAKING TIRE FABRICS. PART OF THE WEAVING WOULD TAKE PLACE AT HOGANSVILLE MILL (BUILT c. 1900), ANOTHER NEW ENGLAND SOUTHERN MILL NEARBY, UNTIL THE DEMOLITION OF THAT MILL IN THE 1970s. - Stark Mill, 117 Corinth Road, Hogansville, Troup County, GA

  2. "Stark" reality: self-referral rule holds risk and opportunity.

    PubMed

    Lebowitz, P H

    2001-01-01

    On January 4, 2001, the Health Care Financing Administration (now the Center for Medicare and Medicaid Services or CMS) issued Phase I of the final Stark II regulations (Final Rule). The Final Rule implements the Ethics in Patient Referral Act of 1989 (Stark I), as amended by the Omnibus Budget and Reconciliation Act of 1993 (Stark II), collectively the Stark Law. It is intended to provide more flexibility to providers by interpreting the prohibitions narrowly and the exceptions broadly. Generally, the Stark Law prohibits physicians from referring Medicare or Medicaid patients to an entity for the provision of "designated health services (DHS)" if the physician (or a member of the physician's immediate family) has a direct or indirect financial relationship with the entity. The Final Rule establishes two principal exceptions to the referral prohibition that apply to both ownership/investment interests and compensation arrangements. The physician service exception permits referrals for DHS that are furnished by a member or physician in the same group practice as the referring physician, or under their supervision. The in-office ancillary services exception permits referral for provision of DHS in the same building in which the referring physician or his group routinely provides the full range of the group's or physician's medical services. The final regulations redefine the prior description of radiology and radiation therapy services subject to Stark II. The principal change is to segregate radiation therapy and supplies from radiology and other imaging services. It is uncertain whether Stark Law enforcement will be a priority under the Bush Administration. Nonetheless, because the Final Rule offers more flexibility than the proposed rule, providers and suppliers should revisit proposed and abandoned arrangements that they believed to be prohibited.

  3. Surfing Stark II: prohibition against self-referrals.

    PubMed

    Swibel, H J; Zaremski, M J

    1995-02-01

    In 1989, the Chairman of the House Ways and Means Subcommittee on Health, Fortney (Pete) Stark (D.-Calif.), turned the health care industry on its ear by introducing the "Ethics in Patient Referrals Act" to Congress. The bill, commonly known as "Stark I," prohibited physician referrals to entities in which they held a financial interest. As Stark's bill made its way through Congress, its substance was dramatically reduced by the legislative process. Ultimately, the law was incorporated as part of the Omnibus Budget Reconciliation Act of 1990. Stark I's main thrust is that it bars physicians from referring Medicare patients to clinical laboratories with which they have a financial relationship. Furthermore, laboratories providing those services must report information concerning any ownership arrangements between the referring physician and the laboratory. Now, to complicate the picture, providers must contend with amendments to the original law that extend the reach of its prohibitions. Called "Stark II," these amendments took effect on January 1, 1995. In this article, guidelines for dealing successfully with the requirements of the law are outlined.

  4. Simple Analytic Formula for the Stark Recurrence Spectrum

    NASA Astrophysics Data System (ADS)

    Flores-Rueda, Heric; Jensen, R. V.; Wright, J. D.; Morgan, T. J.

    2001-05-01

    Characterization of the structure of the recurrence spectrum in a strong electric field has attracted recent experimental and theoretical attention [1, 2]. Theoretical approaches have included a purely quantum mechanical explanation based on the regularities in the Stark photoabsorption spectrum, a semiquantal approach focusing on quantized energy levels and semiclassical ideas using closed orbit theory. In the present work we have used the results of our previous study [2] to find simple analytic formula that can be used to obtain the structure of the Stark recurrence spectrum. Both peak locations and amplitudes for Stark recurrences are found to be in good agreement when compared with experimental data for Rydberg Helium m = 1 states. Work supported by the National Science Foundation. [1] V. Kondratovich and J. Delos, Phys. Rev. A 57, 4604 (1998) [2] R. V. Jensen, H. Flores-Rueda, J. D. Wright, M. L. Keeler and T. J. Morgan, Phys. Rev. A 62, 53410 (2000)

  5. Higher-order resonances in a Stark decelerator

    SciTech Connect

    Meerakker, Sebastiaan Y.T. van de; Bethlem, Hendrick L.; Vanhaecke, Nicolas; Meijer, Gerard

    2005-05-15

    The motion of polar molecules can be controlled by time-varying inhomogeneous electric fields. In a Stark decelerator, this is exploited to select a fraction of a molecular beam that is accelerated, transported, or decelerated. Phase stability ensures that the selected bunch of molecules is kept together throughout the deceleration process. In this paper an extended description of phase stability in a Stark decelerator is given, including higher-order effects. This analysis predicts a wide variety of resonances that originate from the spatial and temporal periodicity of the electric fields. These resonances are experimentally observed using a beam of OH ({sup 2}{pi}{sub 3/2},v=0,J=3/2) radicals passing through a Stark decelerator.

  6. Method for measuring Doppler shifts in arc-heated flows.

    PubMed

    Aeschliman, D P; Hill, R A

    1972-01-01

    A novel method of determining both the Doppler and Stark shifts in a single measurement of spectral lines emitted by the arc-heated flow from a plasma jet has been successfully demonstrated. The method uses a spherical mirror arranged with its optical axis coincident with the optical axis of a Fabry-Perot interferometer and with its center of curvature at the center line of the flow. The common optical axis lies at an angle to the flow. With this system, both red-and blue-shifted line profiles are recorded in the same spectral scan. If conditions are such that the red-and blue-shifted profiles are not resolvable, the blue-shifted component is chopped so that the recorded signal consists of the envelopes of both the red-shifted profile and the superimposed red-and blue-shifted profiles. The wavelength difference between the blue-and red-shifted line profiles is exactly twice the Doppler shift integrated along a line of sight through the flow and is independent of a Stark shift. The Stark shift is given by the wavelength difference between the absolute line center and the midpoint of the red-and blue-shifted lines. Abel inversion of integrated line shift data has yielded radial velocity profiles to an accuracy of +/-3% in a supersonic, arc-heated argon flow.

  7. Existence of the Stark-Wannier quantum resonances

    SciTech Connect

    Sacchetti, Andrea

    2014-12-15

    In this paper, we prove the existence of the Stark-Wannier quantum resonances for one-dimensional Schrödinger operators with smooth periodic potential and small external homogeneous electric field. Such a result extends the existence result previously obtained in the case of periodic potentials with a finite number of open gaps.

  8. Robust Algorithm for Computing Statistical Stark Broadening of Spectral Lines

    SciTech Connect

    Iglesias, C A; Sonnad, V

    2010-02-10

    A method previously developed to solve large-scale linear systems is applied to statistical Stark broadened line shape calculations. The method is formally exact, numerically stable, and allows optimization of the integration over the quasi-static field to assure numerical accuracy. Furthermore, the method does not increase the computational effort and often can decrease it compared to the conventional approach.

  9. West Orange Collaborative STARK Program, 2002-2003 Evaluation Report

    ERIC Educational Resources Information Center

    Lowther, Deborah L.; Ross, Steven M.; McDonald, Aaron; Wang, Weiping; Thompson, Laura

    2003-01-01

    This report summarizes the Year 2 evaluation study results of the Students and Teachers Accessing Real-time Knowledge (STARK) Program in the West Orange Consolidated Independent School District (CSID). The overall purpose of the evaluation was twofold: (a) to provide formative evaluation data to the participant schools to serve as a basis for…

  10. West Orange Collaborative STARK Program. 2003-2004 Evaluation Report

    ERIC Educational Resources Information Center

    Lowther, Deborah L.; Thompson, Laura; Ross, Steven M.; McDonald, Aaron; Wang, Weiping

    2004-01-01

    This report summarizes the results of the Year 3 evaluation study of the Students and Teachers Accessing Real-time Knowledge (STARK) Program in the West Orange Consolidated Independent School District (CSID). The overall purpose of the evaluation was twofold: (a) to provide formative evaluation data to the participant schools to serve as a basis…

  11. Precise dipole moment of methanol by microwave Stark spectroscopy III: Parent 12CH316OH species

    NASA Astrophysics Data System (ADS)

    Mukhopadhyay, Indra; Sastry, K. V. L. N.

    2015-06-01

    In this work, precise Stark effect measurements have been carried out on several transitions in the first four torsional states of methanol. The Stark shifted transition frequencies for a wide range of steady electric field have been measured with an accuracy of approximately ±10 kHz. Detailed analysis of the data allowed for the determination of the dipole moment components in the first four torsional states of the ground vibrational state. The extrapolated zero field frequencies of the transitions studied have been determined and found to be in perfect agreement with known values. For the torsional ground state the values of μa = 0.8961(2) and μb = 1.4201(9) have been obtained, whereas for the first excited torsional state the corresponding values obtained are 0.9035(1) and 1.4317(5) (These values are in Debye, denoted by D). These values confirm the fact that the dipole moment values increase at a considerable rate as one move toward higher torsional states as seen in previous studies. To our knowledge, this is the first time the most accurate and elaborate dipole moment values of methanol are being reported.

  12. Stark Broadening Analysis Using Optical Spectroscopy of the Dense Plasma Focus

    NASA Astrophysics Data System (ADS)

    Ross, Patrick; Bennett, Nikki; Dutra, Eric; Hagen, E. Chris; Hsu, Scott; Hunt, Gene; Koch, Jeff; Waltman, Tom; NSTec DPF Team

    2015-11-01

    To aid in validating numerical modeling of MA-class dense plasma focus (DPF) devices, spectroscopic measurements of the Gemini Dense Plasma Focus (DPF) were performed using deuterium and deuterium/dopant (argon/krypton) gas. The spectroscopic measurements were made using a fiber-coupled spectrometer and streak camera. Stark line-broadening analysis was applied to the deuterium beta emission (486 nm) in the region near the breakdown of the plasma and during the run-down and run-in phases of the plasma evolution. Densities in the range of 1e17 to low 1e18 cm-3 were obtained. These values are in agreement with models of the DPF performed using the LSP code. The spectra also show a rise and fall with time, indicative of the plasma sheath passing by the view port. Impurity features were also identified in the spectra which grew in intensity as the gas inside the DPF was discharged repeatedly without cycling. Implications of this impurity increase for D-T discharges (without fresh gas fills between every discharge) will be discussed. This work was done by National Security Technologies, LLC, under Contract No. DE-AC52-06NA25946, and by Los Alamos National Laboratory, under Contract no. DE-AC52-06NA25396 with the U.S. Department of Energy. DOE/NV/25946-2515.

  13. The Stark truth: what your physician clients should know about Stark Law and the Anti-Kickback Statute.

    PubMed

    Taormina, Melissa

    2013-01-01

    This article summarizes key features of Stark Law and the Anti-Kickback Statute, statutes used to fight health care fraud and abuse within Medicare and Medicaid, and explains how attorneys can help health care providers comply with these laws. PMID:23614270

  14. VAMDC FP7 project and STARK-B database: C II Stark broadening parameters for white dwarf atmospheres research

    SciTech Connect

    Larbi-Terzi, Neila; Ben Nessib, Nebil; Sahal-Brechot, Sylvie; Dimitrijevic, Milan S.

    2010-11-23

    Stark broadening parameters of C II lines were determined within 3s-np spectral series within the semiclassical perturbation method. The atomic energy levels needed for calculations were taken from TOPBASE as well as the oscillator strengths, calculated additionally using the Coulomb approximation (the method of Bates and Damgaard). The both results were compared and the disagreement is found only in one case where the configuration mixing allows a forbidden transition to a close perturbing energy level. Calculations were performed for plasma conditions relevant for atmospheres of DQ white dwarfs and for a new type of white dwarfs, with surface composed mostly of carbon, discovered in 2007 by Dufour et al.. The aim of this work is to provide accurate C II Stark broadening data, which are crucial for this type of white dwarf atmosphere modellisation. Obtained results will be included in STARK-B database (http://stark-b.obspm.fr/), entering in the FP7 project of European Virtual Atomic and Molecular Data Center VAMDC aiming at building an interoperable e-Infrastructure for the exchange of atomic and molecular data (http://www.vamdc.org/).

  15. The Ion Line Stark Parameters Dependence on the Emitter Rest Core Charge and the Electron Temperature within Ns-Np Transition Arrays

    SciTech Connect

    Scepanovic, Mara; Puric, Jagos

    2007-04-23

    Recently published Stark widths and shifts measured and calculated data and their dependence on the upper level ionization potential {chi} are used here to demonstrate the existence of the other kinds of reularities within similar spectra of different elements and their ionization stage. The emphasis is on the Stark parameter dependence on the rest core charge and the electron temperatures for the lines from similar spectra. The found relations connecting Stark broadening and shift parameters and upper level ionization potential, rest core charge and electron temperature were used for a prediction of new Stark broadening data, avoiding much more comlicated procedures. For opacity calculations and investigation of stellar atmosphere, when a large number of line broadening data was required, present investigation are useful in enlarging the number of required data. This field of research remains largely open to other demonstrations of regularities and similarities, as long as one can relate the same kind of spectroscopic transition. Also, the attained dependencies can be used as an additional criteria for checking accuracy of the particular theoretical and experimental data from diferent sources.

  16. Vibrational stark effects to identify ion pairing and determine reduction potentials in electrolyte-free environments

    DOE PAGES

    Mani, Tomoyasu; Grills, David C.; Miller, John R.

    2015-01-02

    A recently-developed instrument for time-resolved infrared detection following pulse radiolysis has been used to measure the ν(C≡N) IR band of the radical anion of a CN-substituted fluorene in tetrahydrofuran. Specific vibrational frequencies can exhibit distinct frequency shifts due to ion-pairing, which can be explained in the framework of the vibrational Stark effect. Measurements of the ratio of free ions and ion-pairs in different electrolyte concentrations allowed us to obtain an association constant and free energy change for ion-pairing. As a result, this new method has the potential to probe the geometry of ion-pairing and allows the reduction potentials of moleculesmore » to be determined in the absence of electrolyte in an environment of low dielectric constant.« less

  17. Vibrational stark effects to identify ion pairing and determine reduction potentials in electrolyte-free environments

    SciTech Connect

    Mani, Tomoyasu; Grills, David C.; Miller, John R.

    2015-01-02

    A recently-developed instrument for time-resolved infrared detection following pulse radiolysis has been used to measure the ν(C≡N) IR band of the radical anion of a CN-substituted fluorene in tetrahydrofuran. Specific vibrational frequencies can exhibit distinct frequency shifts due to ion-pairing, which can be explained in the framework of the vibrational Stark effect. Measurements of the ratio of free ions and ion-pairs in different electrolyte concentrations allowed us to obtain an association constant and free energy change for ion-pairing. As a result, this new method has the potential to probe the geometry of ion-pairing and allows the reduction potentials of molecules to be determined in the absence of electrolyte in an environment of low dielectric constant.

  18. Stark Spectroscopy of Rubrene. I. Electroabsorption Spectroscopy and Molecular Parameters.

    PubMed

    Iimori, Toshifumi; Ito, Ryuichi; Ohta, Nobuhiro; Nakano, Hideyuki

    2016-06-30

    Electroabsorption spectroscopy investigation and the determination of molecular parameters for rubrene dispersed in a poly(methyl methacrylate) (PMMA) matrix are reported. The features of the band system in the absorption spectrum in PMMA are analogous to those in solutions. The changes in the electric dipole moment and the polarizability between the excited and ground states are determined from analysis of the Stark effect in the absorption band. The change in the transition dipole moment in the presence of an external electric field is also observed. Although rubrene is predicted to be classified as a nonpolar molecule, there is a contribution of the difference in the electric dipole moment between the excited and ground states to the electroabsorption spectrum. The origin of the nonzero difference in the electric dipole moment is argued. Stark fluorescence spectroscopy investigation is reported in Part II of this series. PMID:27257765

  19. Cosmic Shear - with ACS Pure Parallel Observations

    NASA Astrophysics Data System (ADS)

    Ratnatunga, Kavan

    2002-07-01

    The ACS, with greater sensitivity and sky coverage, will extend our ability to measure the weak gravitational lensing of galaxy images caused by the large scale distribution of dark matter. We propose to use the ACS in pure parallel {non- proprietary} mode, following the guidelines of the ACS Default Pure Parallel Program. Using the HST Medium Deep Survey WFPC2 database we have measured cosmic shear at arc-min angular scales. The MDS image parameters, in particular the galaxy orientations and axis ratios, are such that any residual corrections due to errors in the PSF or jitter are much smaller than the measured signal. This situation is in stark contrast with ground-based observations. We have also developed a statistical analysis procedure to derive unbiased estimates of cosmic shear from a large number of fields, each of which has a very small number of galaxies. We have therefore set the stage for measurements with the ACS at fainter apparent magnitudes and smaller, 10 arc-second scales corresponding to larger cosmological distances. We will adapt existing MDS WFPC2 maximum likelihood galaxy image analysis algorithms to work with the ACS. The analysis would also yield an online database similar to that in archive.stsci.edu/mds/

  20. Hydrogen Stark broadening by different kinds of model microfields

    NASA Astrophysics Data System (ADS)

    Seidel, J.

    1980-07-01

    A new model microfield is defined (the theta process) which in conjunction with the kangaroo process, is used to demonstrate the effects of different model microfields on hydrogen line profiles. The differences in the statistical features of the models give an estimate of the uncertainties associated with the method of model microfields. Stark broadening of hydrogen Lyman lines by either electrons or ions is investigated specifically.

  1. Stark spectroscopy of CdTe and CdMnTe quantum dots embedded in n-i-p diodes

    SciTech Connect

    Kłopotowski, Ł. Fronc, K.; Wojnar, P.; Wiater, M.; Wojtowicz, T.; Karczewski, G.

    2014-05-28

    We investigate charging effects in CdTe and Cd{sub 1−x}Mn{sub x}Te quantum dots embedded in n-i-p diodes. The tunneling of holes out of the dots at reverse bias and hole injection at forward bias control the dot charge state and allow for its electric field tuning. Furthermore, we analyze the Stark shifts of the photoluminescence transitions and evaluate the effect of the electric field on the binding of the observed excitonic complexes. We find that the binding can be strengthened or weakened depending on the zero-field alignment of the electron and hole wavefunctions.

  2. Stark spectroscopy of CdTe and CdMnTe quantum dots embedded in n-i-p diodes

    NASA Astrophysics Data System (ADS)

    Kłopotowski, Ł.; Fronc, K.; Wojnar, P.; Wiater, M.; Wojtowicz, T.; Karczewski, G.

    2014-05-01

    We investigate charging effects in CdTe and Cd1-xMnxTe quantum dots embedded in n-i-p diodes. The tunneling of holes out of the dots at reverse bias and hole injection at forward bias control the dot charge state and allow for its electric field tuning. Furthermore, we analyze the Stark shifts of the photoluminescence transitions and evaluate the effect of the electric field on the binding of the observed excitonic complexes. We find that the binding can be strengthened or weakened depending on the zero-field alignment of the electron and hole wavefunctions.

  3. Stark effect of atomic helium second triplet series in electric fields up to 1600 kV cm-1

    NASA Astrophysics Data System (ADS)

    Windholz, L.; Winklhofer, E.; Drozdowski, R.; Kwela, J.; Waşowicz, T. J.; Heldt, J.

    2008-12-01

    We present experimental and theoretical investigations of the spectral series 2 3P-n 3Q (n=3-10, Q=S, P, D, ..., n-1) in electric fields up to 1600 kV cm-1. Such fields cause—for n>6—shifts of the upper levels of the observed transitions which are larger than the separation between levels with different principal quantum numbers. The patterns belonging to a certain principal quantum number become similar to hydrogen patterns; they are nearly symmetric and show a nearly linear Stark shift in higher electric fields. The applied fields were high enough that patterns belonging to neighboring principal quantum numbers begin to overlap, which leads to interesting level-anticrossing effects. The experimental results are compared with numerical calculations taking into account mixing between states of different principal quantum numbers and also between singlet and triplet states. The agreement between experimental and theoretical line shifts is quite good.

  4. Vibrational anharmonicity and vibrational Stark effect of sulfate ions trapped in potassium, rubidium and cesium chromate.

    PubMed

    Pejov, L; Petrusevski, V M

    2000-04-01

    Room and low temperature (approximately 100 K) FT-IR and Raman spectra of the sulfate doped K2CrO4, Rb2CrO4 and Cs2CrO4 were recorded. The positions of the nu1, nu3, and nu4 fundamental mode components of the dopant anions were measured. Nine (out of possible ten) second-order stretch-stretch vibrational transitions of the dopant anions were detected. On the basis of these data, the anharmonicity constants and the corresponding harmonic eigenvalues were calculated for several vibrational transitions using second-order perturbation theory expressions. The anharmonicity of the studied second-order transitions of the type nu1 + nu3i increases in the order (SO4/K2CrO4) < (SO4/Rb2CrO4) < (SO4/Cs2CrO4), while for those of the type nu3j + nu3i it basically follows the trend: (SO4/K2CrO4) > (SO4/Rb2CrO4) < (SO4/Cs2CrO4). The measured relative Stark splittings of the nu3 and nu4 mode components of the dopant SO4(2-) anions, as well as the average X13i/3i3j values decrease in the order (SO4/K2CrO4) > (SO4/Rb2CrO4) > (SO4/Cs2CrO4). In all cases, the splitting is larger for nu3 than for nu4 modes, indicating a smaller angular than the bond length distortion. The theory of vibrational Stark effect suggests that the observed frequency shifts of the nu1, nu3 and nu4 mode components may be attributed to the increase of the field strength at the doped anion site going from K2CrO4 to Cs2CrO4. The Stark splitting of these modes, on the other hand, implies that the internal crystalline field vector is almost parallel to the (hypothetical) C2 axis of the slightly distorted dopant tetrahedral anions.

  5. Stark cell optoacoustic detection of constituent gases in sample

    NASA Technical Reports Server (NTRS)

    Margolis, J. S.; Shumate, M. S. (Inventor)

    1980-01-01

    An optoacoustic detector for gas analysis is implemented with Stark effect cell modulation for switching a beam in and out of coincidence with a spectral line of a constituent gas in order to eliminate the heating effect of laser energy in the cell as a source of background noise. By using a multiline laser, and linearly sweeping the DC bias voltage while exciting the cell with a multiline laser, it is possible to obtain a spectrum from which to determine the combinations of excited constituents and determine their concentrations in parts per million.

  6. Imaging motional Stark effect measurements at ASDEX Upgrade

    NASA Astrophysics Data System (ADS)

    Ford, O. P.; Burckhart, A.; McDermott, R.; Pütterich, T.; Wolf, R. C.

    2016-11-01

    This paper presents an overview of results from the Imaging Motional Stark Effect (IMSE) diagnostic obtained during its first measurement campaign at ASDEX Upgrade since installation as a permanent diagnostic. A brief overview of the IMSE technique is given, followed by measurements of a standard H-mode discharge, which are compared to equilibrium reconstructions showing good agreement where expected. The development of special discharges for the calibration of pitch angle is reported and safety factor profile changes during sawteeth crashes are shown, which can be resolved to a few percent due to the high sensitivity at good time resolution of the new IMSE system.

  7. Modeling of Stark-Zeeman Lines in Magnetized Hydrogen Plasmas

    NASA Astrophysics Data System (ADS)

    Rosato, J.; Bufferand, H.; Capes, H.; Koubiti, M.; Godbert-Mouret, L.; Marandet, Y.; Stamm, R.

    2015-12-01

    The action of electric and magnetic fields on atomic species results in a perturbation of the energy level structure, which alters the shape of spectral lines. In this work, we present the Zeeman-Stark line shape simulation method and perform new calculations of hydrogen Lyman and Balmer lines, in the framework of magnetic fusion research. The role of the Zeeman effect, fine structure and the plasma's non-homogeneity along the line-of-sight are investigated. Under specific conditions, our results are applicable to DA white dwarf atmospheres.

  8. Density measurements using coherence imaging spectroscopy based on Stark broadeninga)

    NASA Astrophysics Data System (ADS)

    Lischtschenko, O.; Bystrov, K.; De Temmerman, G.; Howard, J.; Jaspers, R. J. E.; König, R.

    2010-10-01

    A coherence imaging camera has been set up at Pilot-PSI. The system is to be used for imaging the plasma density through the Stark effect broadening of the Hγ line. Local density values are then obtained by the Abel inversion of the measured interferometric fringe contrast. This report will present the instrument setup and proof-of-principle demonstration. The inverted spatial electron density profiles obtained near the cascaded arc source of Pilot-PSI in discharges with axial magnetic field of B=0.4 T are compared with an independent measurement of electron density by Thomson scattering and good agreement is found.

  9. Influence of electric field on spectral positions of dislocation-related luminescence peaks in silicon: Stark effect

    NASA Astrophysics Data System (ADS)

    Mchedlidze, T.; Arguirov, T.; Kittler, M.; Hoang, T.; Holleman, J.; Schmitz, J.

    2007-11-01

    Spectral positions of dislocation-related luminescence (DRL) peaks from dislocation loops located close to a p-n junction in silicon were shifted by carrier injection level. We suppose that the excitonic transition energies of DRL were reduced by an effective electric field at dislocation sites due to quadratic Stark effect (QSE). The field results from built-in junction field reduced by carrier injection. A constant of the shift, obtained from fitting of the data with QSE equation, was 0.0186meV /(kV/cm)2. The effect can explain the diversity of DRL spectra in silicon and may allow tuning and modulation of DRL for future photonic applications.

  10. Rydberg-Stark states in oscillating electric fields

    NASA Astrophysics Data System (ADS)

    Zhelyazkova, V.; Hogan, S. D.

    2015-12-01

    Experimental and theoretical studies of the effects of weak radio-frequency electric fields on Rydberg-Stark states with electric dipole moments as large as 10,000 D are reported. High-resolution laser spectroscopic studies of Rydberg states with principal quantum number n = 52 and 53 were performed in pulsed supersonic beams of metastable helium with the excited atoms detected by pulsed electric field ionisation. Experiments were carried out in the presence of sinusoidally oscillating electric fields with frequencies of 20 MHz, amplitudes of up to 120 mV/cm, and dc offsets of up to 4.4 V/cm. In weak fields, the experimentally recorded spectra are in excellent agreement with the results of calculations carried out using Floquet methods to account for electric dipole couplings in the oscillating fields. This highlights the validity of these techniques for the accurate calculation of the Stark energy level structure in such fields, and the limitations of the calculations in stronger fields where n-mixing and higher order contributions become important.

  11. Instrumentation for a multichord motional Stark effect diagnostic in KSTAR

    NASA Astrophysics Data System (ADS)

    Chung, J.; Ko, J.; De Bock, M. F. M.; Jaspers, R. J. E.

    2014-11-01

    The motional Stark effect (MSE) diagnostic is used to measure the radial magnetic pitch angle profile in neutral beam heated plasmas. This information is used to calculate the safety factor, q, with magnetic equilibrium reconstruction codes such as EFIT. The MSE diagnostic is important during active shaping of the q profile to optimize confinement and stability, and it has become a key diagnostic in high performance tokamaks. A multichord photo-elastic modulator (PEM) based MSE system is being developed for a real-time plasma current profile control in Korea Superconducting Tokamak Advanced Research (KSTAR). The PEM-based approach is a standard method that measures the polarization direction of a single Stark line with narrow tunable bandpass filters. A tangential view of the heating beam provides good spatial resolution of 1-3 cm, which provides an opportunity to install 25 spatial channels spanning the major radius from 1.74 m to 2.84 m. Application of real-time control is a long-term technical goal after commissioning the diagnostic in KSTAR, which is expected in 2015. In this paper, we describe the design of this newly-constructed multichord MSE diagnostic in KSTAR.

  12. Motional, isotope and quadratic Stark effects in Rydberg-Stark deceleration and electric trapping of H and D

    NASA Astrophysics Data System (ADS)

    Hogan, S. D.; Seiler, Ch; Merkt, F.

    2013-02-01

    Hydrogen and deuterium Rydberg atoms, initially moving at velocities of 600 and 560 m s-1, respectively, in pulsed supersonic beams, have been decelerated and electrostatically trapped following adiabatic 90° deflection from their initial axis of propagation to minimize collisions with the trailing edge of the gas pulses. The time evolution of the potential energy surfaces, over which the atoms undergoing deceleration travel during the trap-loading process, is analogous to that of a moving electrodynamic trap. It has been studied in the laboratory-fixed frame of reference and in the continuously moving frame of reference defined by the instantaneous position of the electric-field minimum around which the atoms are located. The importance of the quadratic Stark effect in the deceleration of samples in Rydberg states with principal quantum numbers above 35 has also been investigated by comparison of experimental results with predictions resulting from the numerical calculation of particle trajectories. The data presented for deuterium atoms represent the first application of Rydberg-Stark deceleration and trapping for this atom. Comparison of the rate of loss of n = 30 H and D atoms from the trap enables one to conclude that it is not affected by the particle dynamics during deceleration and trap loading.

  13. Stark Spectroscopy of Rubrene. II. Stark Fluorescence Spectroscopy and Fluorescence Quenching Induced by an External Electric Field.

    PubMed

    Iimori, Toshifumi; Ito, Ryuichi; Ohta, Nobuhiro

    2016-07-21

    We report Stark fluorescence spectroscopy investigation of rubrene dispersed in a poly(methyl methacrylate) film. The features of the fluorescence spectrum are analogous to those in solutions. In the Stark fluorescence spectrum, the decrease of the fluorescence quantum yield in the presence of an external electric field is observed. This result shows that the yield of nonradiative decay processes is increased by the application of an external electric field. It is known that the fluorescence quantum yield for rubrene, which is nearly unity at room temperature, depends on temperature, and a major nonradiative decay process in photoexcited rubrene is ascribed to a thermally activated intersystem crossing (ISC). Equations that express the field-induced fluorescence quenching in terms of the molecular parameters are derived from the ensemble average of electric field effects on the activation energy of the reaction rate constant in random orientation systems. The molecular parameters are then extracted from the observed data. It is inferred that the field-induced increase in the yield of other intramolecular and intermolecular photophysical processes in addition to the ISC should be taken into account. PMID:27341859

  14. RHIC spin flipper AC dipole controller

    SciTech Connect

    Oddo, P.; Bai, M.; Dawson, C.; Gassner, D.; Harvey, M.; Hayes, T.; Mernick, K.; Minty, M.; Roser, T.; Severino, F.; Smith, K.

    2011-03-28

    The RHIC Spin Flipper's five high-Q AC dipoles which are driven by a swept frequency waveform require precise control of phase and amplitude during the sweep. This control is achieved using FPGA based feedback controllers. Multiple feedback loops are used to and dynamically tune the magnets. The current implementation and results will be presented. Work on a new spin flipper for RHIC (Relativistic Heavy Ion Collider) incorporating multiple dynamically tuned high-Q AC-dipoles has been developed for RHIC spin-physics experiments. A spin flipper is needed to cancel systematic errors by reversing the spin direction of the two colliding beams multiple times during a store. The spin flipper system consists of four DC-dipole magnets (spin rotators) and five AC-dipole magnets. Multiple AC-dipoles are needed to localize the driven coherent betatron oscillation inside the spin flipper. Operationally the AC-dipoles form two swept frequency bumps that minimize the effect of the AC-dipole dipoles outside of the spin flipper. Both AC bumps operate at the same frequency, but are phase shifted from each other. The AC-dipoles therefore require precise control over amplitude and phase making the implementation of the AC-dipole controller the central challenge.

  15. Identification of ion-pair structures in solution by vibrational stark effects

    DOE PAGES

    Hack, John; Mani, Tomoyasu; Grills, David C.; Miller, John R.

    2016-01-25

    Here, ion pairing is a fundamental consideration in many areas of chemistry and has implications in a wide range of sciences and technologies that include batteries and organic photovoltaics. Ions in solution are known to inhabit multiple possible states, including free ions (FI), contact ion pairs (CIP), and solvent-separated ion pairs (SSIP). However, in solutions of organic radicals and nonmetal electrolytes, it is often difficult to distinguish between these states. In the first part of this work, we report evidence for the formation of SSIPs in low-polarity solvents and distinct measurements of CIP, SSIP, and FI, by using the ν(C≡N)more » infrared (IR) band of a nitrile-substituted fluorene radical anion. Use of time-resolved IR detection following pulse radiolysis allowed us to unambiguously assign the peak of the FI. In the presence of nonmetal electrolytes, two distinct red-shifted peaks were observed and assigned to the CIP and SSIP. The assignments are interpreted in the framework of the vibrational Stark effect (VSE) and are supported by (1) the solvent dependence of ion-pair populations, (2) the observation of a cryptand-separated sodium ion pair that mimics the formation of SSIPs, and (3) electronic structure calculations. In the second part of this work, we show that a blue-shift of the ν(C≡N) IR band due to the VSE can be induced in a nitrile-substituted fluorene radical anion by covalently tethering it to a metal-chelating ligand that forms an intramolecular ion pair upon reduction and complexation with sodium ion. This adds support to the conclusion that the shift in IR absorptions by ion pairing originates from the VSE. These results combined show that we can identify ion-pair structures by using the VSE, including the existence of SSIPs in a low-polarity solvent.« less

  16. Identification of Ion-Pair Structures in Solution by Vibrational Stark Effects.

    PubMed

    Hack, John; Grills, David C; Miller, John R; Mani, Tomoyasu

    2016-02-18

    Ion pairing is a fundamental consideration in many areas of chemistry and has implications in a wide range of sciences and technologies that include batteries and organic photovoltaics. Ions in solution are known to inhabit multiple possible states, including free ions (FI), contact ion pairs (CIP), and solvent-separated ion pairs (SSIP). However, in solutions of organic radicals and nonmetal electrolytes, it is often difficult to distinguish between these states. In the first part of this work, we report evidence for the formation of SSIPs in low-polarity solvents and distinct measurements of CIP, SSIP, and FI, by using the ν(C≡N) infrared (IR) band of a nitrile-substituted fluorene radical anion. Use of time-resolved IR detection following pulse radiolysis allowed us to unambiguously assign the peak of the FI. In the presence of nonmetal electrolytes, two distinct red-shifted peaks were observed and assigned to the CIP and SSIP. The assignments are interpreted in the framework of the vibrational Stark effect (VSE) and are supported by (1) the solvent dependence of ion-pair populations, (2) the observation of a cryptand-separated sodium ion pair that mimics the formation of SSIPs, and (3) electronic structure calculations. In the second part of this work, we show that a blue-shift of the ν(C≡N) IR band due to the VSE can be induced in a nitrile-substituted fluorene radical anion by covalently tethering it to a metal-chelating ligand that forms an intramolecular ion pair upon reduction and complexation with sodium ion. This adds support to the conclusion that the shift in IR absorptions by ion pairing originates from the VSE. These results combined show that we can identify ion-pair structures by using the VSE, including the existence of SSIPs in a low-polarity solvent. PMID:26807492

  17. Identification of Ion-Pair Structures in Solution by Vibrational Stark Effects.

    PubMed

    Hack, John; Grills, David C; Miller, John R; Mani, Tomoyasu

    2016-02-18

    Ion pairing is a fundamental consideration in many areas of chemistry and has implications in a wide range of sciences and technologies that include batteries and organic photovoltaics. Ions in solution are known to inhabit multiple possible states, including free ions (FI), contact ion pairs (CIP), and solvent-separated ion pairs (SSIP). However, in solutions of organic radicals and nonmetal electrolytes, it is often difficult to distinguish between these states. In the first part of this work, we report evidence for the formation of SSIPs in low-polarity solvents and distinct measurements of CIP, SSIP, and FI, by using the ν(C≡N) infrared (IR) band of a nitrile-substituted fluorene radical anion. Use of time-resolved IR detection following pulse radiolysis allowed us to unambiguously assign the peak of the FI. In the presence of nonmetal electrolytes, two distinct red-shifted peaks were observed and assigned to the CIP and SSIP. The assignments are interpreted in the framework of the vibrational Stark effect (VSE) and are supported by (1) the solvent dependence of ion-pair populations, (2) the observation of a cryptand-separated sodium ion pair that mimics the formation of SSIPs, and (3) electronic structure calculations. In the second part of this work, we show that a blue-shift of the ν(C≡N) IR band due to the VSE can be induced in a nitrile-substituted fluorene radical anion by covalently tethering it to a metal-chelating ligand that forms an intramolecular ion pair upon reduction and complexation with sodium ion. This adds support to the conclusion that the shift in IR absorptions by ion pairing originates from the VSE. These results combined show that we can identify ion-pair structures by using the VSE, including the existence of SSIPs in a low-polarity solvent.

  18. Atom-interferometric measurement of Stark level splittings

    NASA Astrophysics Data System (ADS)

    Zhao, Jianming; Raithel, Georg

    2016-05-01

    Rydberg atoms are highly sensitive to external electric fields due to their large polarizability, scaling as n7 (n is the principal quantum number). In cesium, nS Rydberg levels mix with nearby (n-4) high- l states, forming sequences of avoided crossings. Mixed adiabatic/diabatic passages through these crossings are employed as beam splitters and recombiners in an atom-interferometric measurement of energy level splittings. We subject cold cesium atoms to laser-excitation, electric-field and detection sequences that constitute an (internal-state) atom interferometer. For the read-out of the interferometer we utilize state-dependent collisions, which selectively remove atoms of one kind from the detected signal. We investigate the dependence of the interferometric signal on timing and field parameters, and find good agreement with quantum simulations of the interferometer. Fourier analysis of the interferometric signals yield coherence frequencies that agree with corresponding energy-level differences in calculated Stark maps.

  19. Probing the classical/quantal boundary using the Stark effect

    NASA Astrophysics Data System (ADS)

    Baugh, Joseph Frederick

    The boundary between classical physics and quantum physics is examined using the Stark effect on sodium atoms in a constant electric field. Coherent states composed of linear superpositions of the hydrogenic stationary states are created by applying a low amplitude, ˜5 V/cm, nanosecond electric field pulse. The pulse periodically drives the atoms to a realm where many stationary states lie within a very narrow energy range. These coherent superpositions exhibit localized electronic probability densities and therefore qualify as wave packets, time-dependent states for which constructive and destructive interference leads to a localized, moving probability density. Using a cw laser these wave packet states are excited and their attributes are probed in the frequency domain rather than the time domain. Computer simulations are used to show how coherent linear combinations of hydrogenic basis states emulate the orbital motion of a classical particle.

  20. Improved spectral analysis for the motional Stark effect diagnostica)

    NASA Astrophysics Data System (ADS)

    Ko, J.; Klabacha, J.

    2012-10-01

    The magnetic pitch angle and the magnitude from reversed field pinch plasmas in the Madison symmetric torus (MST) have been routinely obtained from fully resolved motional Stark effect (MSE) spectrum analyses. Recently, the spectrum fit procedure has been improved by initializing and constraining the fit parameters based on the MSE model in the atomic data and analysis structure. A collisional-radiative model with level populations nlm-resolved up to n = 4 and a simple Born approximation for ion-impact cross sections is used for this analysis. Measurement uncertainty is quantified by making MSE measurements with multiple views of a single spatial location, ranging 5%-15% for typical MST operation conditions. A multi-view fit improves the goodness of fit of MSE spectral features and background.

  1. Static Properties and Stark Effect of the Ground State of the HD Molecular Ion

    NASA Technical Reports Server (NTRS)

    Bhatia, A. K.; Drachman, Richard J.

    1999-01-01

    We have calculated static properties of the ground state of the HD(+) ion and its lowest-lying P-state without making use of the Born-Oppenheimer approximation, as was done in the case of H2(+) and D2(+) [Phys. Rev. A 58, 2787 (1998)]. The ion is treated as a three-body system whose ground state is spherically symmetric. The wavefunction is of generalized Hylleraas type, but it is necessary to include high powers of the internuclear distance to localize the nuclear motion. We obtain good values of the energies of the ground S-state and lowest P-state and compare them with earlier calculations. Expectation values are obtained for various operators, the Fermi contact parameters, and the permanent quadrupole moment. The cusp conditions are also calculated. The polarizability was then calculated using second-order perturbation theory with intermediate P pseudostates. Since the nuclei in HD(+) are not of equal mass there is dipole coupling between the lowest two rotational states, which are almost degenerate. This situation is carefully analyzed, and the Stark shift is calculated variationally as a function of the applied electric field.

  2. Asymmetries in the motional Stark effect emission on the DIII-D tokamak

    NASA Astrophysics Data System (ADS)

    Victor, B. S.; Holcomb, C. T.; Allen, S. L.; Meyer, W. H.; Makowski, M. A.; Thorman, A.

    2016-11-01

    Spectrometer measurements and filter upgrades to a motional Stark effect polarimeter measuring the outer half-radius of the DIII-D tokamak helped to identify asymmetries in the polarization angle of Stark-split emission. The measured polarization angle of the π components differs and is not orthogonal to the σ component. These differences persist over a range of densities and with low levels of background light. It is suggested that the difference in the polarization angle between components is from a change in the ellipticity of the emitted light across the Stark components coupled with imperfect polarization preservation from an in-vessel mirror.

  3. The motional stark effect with laser-induced fluorescence diagnostic

    NASA Astrophysics Data System (ADS)

    Foley, E. L.; Levinton, F. M.

    2010-05-01

    The motional Stark effect (MSE) diagnostic is the worldwide standard technique for internal magnetic field pitch angle measurements in magnetized plasmas. Traditionally, it is based on using polarimetry to measure the polarization direction of light emitted from a hydrogenic species in a neutral beam. As the beam passes through the magnetized plasma at a high velocity, in its rest frame it perceives a Lorentz electric field. This field causes the H-alpha emission to be split and polarized. A new technique under development adds laser-induced fluorescence (LIF) to a diagnostic neutral beam (DNB) for an MSE measurement that will enable radially resolved magnetic field magnitude as well as pitch angle measurements in even low-field (<1 T) experiments. An MSE-LIF system will be installed on the National Spherical Torus Experiment (NSTX) at the Princeton Plasma Physics Laboratory. It will enable reconstructions of the plasma pressure, q-profile and current as well as, in conjunction with the existing MSE system, measurements of radial electric fields.

  4. Molecular beam optical Stark study of rhodium mononitride.

    PubMed

    Ma, Tongmei; Gengler, Jamie; Wang, Zhong; Wang, Hailing; Steimle, Timothy C

    2007-06-28

    The optical Stark effect in the Q(1) and R(0) lines of the [15.1]1-X (1)Sigma+ (1,0) band of rhodium mononitride (RhN) were recorded and analyzed to determine the permanent electric dipole moments mu for the X (1)Sigma+(upsilon=0) and [15.1]1(upsilon=1) states to be 2.43(5) and 1.75(1) D, respectively. The determined dipole moments are compared to predicted values obtained from density functional theory [Stevens et al., Chem. Phys. Lett. 421, 281 (2006)] and an all-electron ab initio calculation [Shim et al., J. Mol. Struct. THEOCHEM 393, 127 (1997)]. A simple single configuration molecular orbital correlation diagram is used to rationalize the relative values of mu for the 4d mononitrides and RhO. An electronic configuration for the [15.1]1 state is proposed based on the interpretation of the (103)Rh and (14)N magnetic hyperfine interactions.

  5. Shifting Attention

    ERIC Educational Resources Information Center

    Ingram, Jenni

    2014-01-01

    This article examines the shifts in attention and focus as one teacher introduces and explains an image that represents the processes involved in a numeric problem that his students have been working on. This paper takes a micro-analytic approach to examine how the focus of attention shifts through what the teacher and students do and say in the…

  6. A molecular beam-optical Stark study of the A sup 2. Pi. -- X sup 2. Sigma. band system of YO

    SciTech Connect

    Steimle, T.C.; Shirley, J.E. )

    1990-03-15

    The permanent electric dipole moments of yttrium monoxide YO in its {ital X} {sup 2}{Sigma}{sup +}, {ital A} {sup 2}{Pi}{sub 3/2}, and {ital A} {sup 2}{Pi}{sub 1/2} states have been experimentally determined from an analysis of the Stark shifts in the optical spectrum of a molecular beam sample. The determined values are 4.45(7), 3.68(2), and 3.22(8) D, respectively. The results are discussed in terms of bonding models for YO and are compared to recent theoretical predictions.

  7. Examining the impact of the new Stark rules on joint ventures.

    PubMed

    Washlick, John R

    2008-11-01

    The new Stark rules will affect joint ventures involving physicians and hospitals in four primary areas: Services provided "under arrangement". "Per click" lease arrangements. Percentage-based compensation. "Stand-in-the-shoes" provisions.

  8. Photonic Bloch oscillations and Wannier-Stark ladders in exponentially chirped Bragg gratings.

    PubMed

    Wilkinson, P B

    2002-05-01

    The formation of photonic Bloch oscillations and Wannier-Stark ladders is demonstrated in an exponentially chirped one-dimensional Bragg grating. The photonic Bloch oscillations are investigated using Hamiltonian optics, and direct analogies are made with electron dynamics in periodic potentials. The results of transfer matrix calculations are presented, which show the existence of a photonic Wannier-Stark ladder that should be detectable in experiments.

  9. Optimizing the Stark-decelerator beamline for the trapping of cold molecules using evolutionary strategies

    SciTech Connect

    Gilijamse, Joop J.; Kuepper, Jochen; Hoekstra, Steven; Vanhaecke, Nicolas; Meerakker, Sebastiaan Y. T. van de; Meijer, Gerard

    2006-06-15

    We demonstrate feedback control optimization for the Stark deceleration and trapping of neutral polar molecules using evolutionary strategies. In a Stark-decelerator beamline, pulsed electric fields are used to decelerate OH radicals and subsequently store them in an electrostatic trap. The efficiency of the deceleration and trapping process is determined by the exact timings of the applied electric field pulses. Automated optimization of these timings yields an increase of 40% of the number of trapped OH radicals.

  10. Fluid Shifts

    NASA Technical Reports Server (NTRS)

    Stenger, Michael B.; Hargens, Alan R.; Dulchavsky, Scott A.; Ebert, Douglas J.; Lee, Stuart M. C.; Laurie, Steven S.; Garcia, Kathleen M.; Sargsyan, Ashot E.; Martin, David S.; Liu, John; Macias, Brandon R.; Arbeille, Philippe; Danielson, Richard; Chang, Douglas; Gunga, Hanns-Christian; Johnston, Smith L.; Westby, Christian M.; Ploutz-Snyder, Robert J.; Smith, Scott M.

    2016-01-01

    We hypothesize that microgravity-induced cephalad fluid shifts elevate intracranial pressure (ICP) and contribute to VIIP. We will test this hypothesis and a possible countermeasure in ISS astronauts.

  11. ACS: ALMA Common Software

    NASA Astrophysics Data System (ADS)

    Chiozzi, Gianluca; Šekoranja, Matej

    2013-02-01

    ALMA Common Software (ACS) provides a software infrastructure common to all ALMA partners and consists of a documented collection of common patterns and components which implement those patterns. The heart of ACS is based on a distributed Component-Container model, with ACS Components implemented as CORBA objects in any of the supported programming languages. ACS provides common CORBA-based services such as logging, error and alarm management, configuration database and lifecycle management. Although designed for ALMA, ACS can and is being used in other control systems and distributed software projects, since it implements proven design patterns using state of the art, reliable technology. It also allows, through the use of well-known standard constructs and components, that other team members whom are not authors of ACS easily understand the architecture of software modules, making maintenance affordable even on a very large project.

  12. Fluid Shifts

    NASA Technical Reports Server (NTRS)

    Stenger, M. B.; Hargens, A.; Dulchavsky, S.; Ebert, D.; Lee, S.; Laurie, S.; Garcia, K.; Sargsyan, A.; Martin, D.; Lui, J.; Macias, B.; Arbeille, P.; Danielson, R.; Chang, D.; Gunga, H.; Johnston, S.; Westby, C.; Ribeiro, L.; Ploutz-Snyder, R.; Smith, S.

    2015-01-01

    INTRODUCTION: Mechanisms responsible for the ocular structural and functional changes that characterize the visual impairment and intracranial pressure (ICP) syndrome (VIIP) are unclear, but hypothesized to be secondary to the cephalad fluid shift experienced in spaceflight. This study will relate the fluid distribution and compartmentalization associated with long-duration spaceflight with VIIP symptoms. We also seek to determine whether the magnitude of fluid shifts during spaceflight, as well as the VIIP-related effects of those shifts, can be predicted preflight with acute hemodynamic manipulations, and also if lower body negative pressure (LBNP) can reverse the VIIP effects. METHODS: Physiologic variables will be examined pre-, in- and post-flight in 10 International Space Station crewmembers including: fluid compartmentalization (D2O and NaBr dilution); interstitial tissue thickness (ultrasound); vascular dimensions and dynamics (ultrasound and MRI (including cerebrospinal fluid pulsatility)); ocular measures (optical coherence tomography, intraocular pressure, ultrasound); and ICP measures (tympanic membrane displacement, otoacoustic emissions). Pre- and post-flight measures will be assessed while upright, supine and during 15 deg head-down tilt (HDT). In-flight measures will occur early and late during 6 or 12 month missions. LBNP will be evaluated as a countermeasure during HDT and during spaceflight. RESULTS: The first two crewmembers are in the preflight testing phase. Preliminary results characterize the acute fluid shifts experienced from upright, to supine and HDT postures (increased stroke volume, jugular dimensions and measures of ICP) which are reversed with 25 millimeters Hg LBNP. DISCUSSION: Initial results indicate that acute cephalad fluid shifts may be related to VIIP symptoms, but also may be reversible by LBNP. The effect of a chronic fluid shift has yet to be evaluated. Learning Objectives: Current spaceflight VIIP research is described

  13. Vibrational Stark Effects of Carbonyl Probes Applied to Reinterpret IR and Raman Data for Enzyme Inhibitors in Terms of Electric Fields at the Active Site.

    PubMed

    Schneider, Samuel H; Boxer, Steven G

    2016-09-15

    IR and Raman frequency shifts have been reported for numerous probes of enzyme transition states, leading to diverse interpretations. In the case of the model enzyme ketosteroid isomerase (KSI), we have argued that IR spectral shifts for a carbonyl probe at the active site can provide a connection between the active site electric field and the activation free energy (Fried et al. Science 2014, 346, 1510-1514). Here we generalize this approach to a much broader set of carbonyl probes (e.g., oxoesters, thioesters, and amides), first establishing the sensitivity of each probe to an electric field using vibrational Stark spectroscopy, vibrational solvatochromism, and MD simulations, and then applying these results to reinterpret data already in the literature for enzymes such as 4-chlorobenzoyl-CoA dehalogenase and serine proteases. These results demonstrate that the vibrational Stark effect provides a general framework for estimating the electrostatic contribution to the catalytic rate and may provide a metric for the design or modification of enzymes. Opportunities and limitations of the approach are also described. PMID:27541577

  14. Fluid Shifts

    NASA Technical Reports Server (NTRS)

    Stenger, M.; Hargens, A.; Dulchavsky, S.; Ebert, D.; Lee, S.; Lauriie, S.; Garcia, K.; Sargsyan, A.; Martin, D.; Ribeiro, L.; Lui, J.; Macias, B.; Arbeille, P.; Danielson, R.; Chang, D.; Johnston, S.; Ploutz-Snyder, R.; Smith, S.

    2016-01-01

    NASA is focusing on long-duration missions on the International Space Station (ISS) and future exploration-class missions beyond low-Earth orbit. Visual acuity changes observed after short-duration missions were largely transient, but more than 50% of ISS astronauts experienced more profound, chronic changes with objective structural and functional findings such as papilledema and choroidal folds. Globe flattening, optic nerve sheath dilation, and optic nerve tortuosity also are apparent. This pattern is referred to as the visual impairment and intracranial pressure (VIIP) syndrome. VIIP signs and symptoms, as well as postflight lumbar puncture data, suggest that elevated intracranial pressure (ICP) may be associated with the spaceflight-induced cephalad fluid shifts, but this hypothesis has not been tested. The purpose of this study is to characterize fluid distribution and compartmentalization associated with long-duration spaceflight, and to correlate these findings with vision changes and other elements of the VIIP syndrome. We also seek to determine whether the magnitude of fluid shifts during spaceflight, as well as the VIIP-related effects of those shifts, is predicted by the crewmember's preflight conditions and responses to acute hemodynamic manipulations (such as head-down tilt). Lastly, we will evaluate the patterns of fluid distribution in ISS astronauts during acute reversal of fluid shifts through application of lower body negative pressure (LBNP) interventions to characterize and explain general and individual responses. METHODS: We will examine a variety of physiologic variables in 10 long-duration ISS crewmembers using the test conditions and timeline presented in the Figure below. Measures include: (1) fluid compartmentalization (total body water by D2O, extracellular fluid by NaBr, intracellular fluid by calculation, plasma volume by CO rebreathe, interstitial fluid by calculation); (2) forehead/eyelids, tibia, calcaneus tissue thickness (by

  15. Ac irreversibility line of bismuth-based high temperature superconductors

    SciTech Connect

    Mehdaoui, A.; Beille, J.; Berling, D.; Loegel, B.; Noudem, J.G.; Tournier, R.

    1997-09-01

    We discuss the magnetic properties of lead doped Bi-2223 bulk samples obtained through combined magnetic melt texturing and hot pressing (MMTHP). The ac complex susceptibility measurements are achieved over a broad ac field range (1 Oe{lt}h{sub ac}{lt}100 Oe) and show highly anisotropic properties. The intergranular coupling is improved in the direction perpendicular to the applied stress and magnetic field direction, and an intragranular loss peak is observed for the first time. A comparison is made with other bismuth-based compounds and it is shown that the MMTHP process shifts the ac irreversibility line (ac IL) toward higher fields. It is also shown that all the ac IL{close_quote}s for quasi 2D bismuth-based compounds show a nearly quadratic temperature dependence and deviate therefore strongly from the linear behavior observed in quasi 3D compounds and expected from a critical state model.{copyright} {ital 1997 Materials Research Society.}

  16. Experimental Stark halfwidths of the ionized oxygen and silicon spectral lines

    NASA Astrophysics Data System (ADS)

    Gavanski, L.; Belmonte, M. T.; Savić, I.; Djurović, S.

    2016-04-01

    In this paper, we present experimental Stark halfwidths of spectral lines of singly ionized oxygen and singly and double ionized silicon. The observed spectral lines were emitted from plasma produced in a small electromagnetically driven T-tube. The plasma electron density was 1.45 × 1023 m-3 and the electron temperature was 15 000 K. The obtained results were compared with the available experimental results of other authors, as well as with some theoretical Stark halfwidth values. The obtained results, the analysis of experimental results and the comparison with theoretical results might be of interest in astrophysics. For example, the obtained Stark halfwidths can be useful for abundance determination, the calculation of stellar opacities, the interpretation and modelling of stellar spectra, the estimation of the relative transfer through the stellar plasma, etc.

  17. Dynamic Stark control: model studies based on the photodissociation of IBr.

    PubMed

    Sanz-Sanz, Cristina; Richings, Gareth W; Worth, Graham A

    2011-01-01

    The Stark effect is produced when a static field alters molecular states. When the field applied is time dependent, the process is known as the dynamic Stark effect. Of particular interest for the control of molecular dynamics is the Non-Resonant Dynamic Stark Effect (NRDSE), in which the time dependent field is unable to effect a one-photon excitation. The intermediate strength laser pulse instead shapes the potential energy surfaces (PES) and so guides the evolution of the system. A prototype control scheme uses the NRDSE to change the topography of PES in regions where they intersect, thus providing control over photochemistry. Following earlier experimental work, in this paper we study the NRDSE on a new 3 state model of the IBr molecule to gain insight into the mechanism of control at the avoided crossing that governs the branching ratio of the photodissociation.

  18. Fluid Shifts

    NASA Technical Reports Server (NTRS)

    Stenger, Michael; Hargens, A.; Dulchavsky, S.; Ebert, D.; Lee, S.; Sargsyan, A.; Martin, D.; Lui, J.; Macias, B.; Arbeille, P.; Platts, S.

    2014-01-01

    NASA is focusing on long-duration missions on the International Space Station (ISS) and future exploration-class missions beyond low Earth orbit. Visual acuity changes observed after short-duration missions were largely transient, but more than 30% of ISS astronauts experience more profound, chronic changes with objective structural and functional findings such as papilledema and choroidal folds. Globe flattening, optic nerve sheath dilation, and optic nerve tortuosity also are apparent. This pattern is referred to as the visual impairment and intracranial pressure (VIIP) syndrome. VIIP signs and symptoms, as well as postflight lumbar puncture data, suggest that elevated intracranial pressure (ICP) may be associated with the space flight-induced cephalad fluid shifts, but this hypothesis has not been tested. The purpose of this study is to characterize fluid distribution and compartmentalization associated with long-duration space flight, and to correlate these findings with vision changes and other elements of the VIIP syndrome. We also seek to determine whether the magnitude of fluid shifts during space flight, as well as the VIIP-related effects of those shifts, is predicted by the crewmember's pre-flight condition and responses to acute hemodynamic manipulations (such as head-down tilt). Lastly, we will evaluate the patterns of fluid distribution in ISS astronauts during acute reversal of fluid shifts through application of lower body negative pressure (LBNP) interventions to characterize and explain general and individual responses. We will examine a variety of physiologic variables in 10 long-duration ISS crewmembers using the test conditions and timeline presented in the Figure below. Measures include: (1) fluid compartmentalization (total body water by D2O, extracellular fluid by NaBr, intracellular fluid by calculation, plasma volume by CO rebreathe, interstitial fluid by calculation); (2) forehead/eyelids, tibia, calcaneus tissue thickness (by ultrasound

  19. Microfabricated AC impedance sensor

    DOEpatents

    Krulevitch, Peter; Ackler, Harold D.; Becker, Frederick; Boser, Bernhard E.; Eldredge, Adam B.; Fuller, Christopher K.; Gascoyne, Peter R. C.; Hamilton, Julie K.; Swierkowski, Stefan P.; Wang, Xiao-Bo

    2002-01-01

    A microfabricated instrument for detecting and identifying cells and other particles based on alternating current (AC) impedance measurements. The microfabricated AC impedance sensor includes two critical elements: 1) a microfluidic chip, preferably of glass substrates, having at least one microchannel therein and with electrodes patterned on both substrates, and 2) electrical circuits that connect to the electrodes on the microfluidic chip and detect signals associated with particles traveling down the microchannels. These circuits enable multiple AC impedance measurements of individual particles at high throughput rates with sufficient resolution to identify different particle and cell types as appropriate for environmental detection and clinical diagnostic applications.

  20. On the Road to Expansion: Canton Public/Stark County District Library 1929-1997.

    ERIC Educational Resources Information Center

    Croston, Kendel R.

    This paper covers the history of the Canton Public/Stark County District Library (CPL), focusing on the years 1929-1997. The paper focuses on the broadening of the library's services, including the development of reference services, service to young adults, and a variety of outreach activities. A literature review discusses the history of the…

  1. AC magnetohydrodynamic microfluidic switch

    SciTech Connect

    Lemoff, A V; Lee, A P

    2000-03-02

    A microfluidic switch has been demonstrated using an AC Magnetohydrodynamic (MHD) pumping mechanism in which the Lorentz force is used to pump an electrolytic solution. By integrating two AC MHD pumps into different arms of a Y-shaped fluidic circuit, flow can be switched between the two arms. This type of switch can be used to produce complex fluidic routing, which may have multiple applications in {micro}TAS.

  2. Improvement of the quantum confined Stark effect characteristics by means of energy band profile modulation: The case of Gaussian quantum wells

    NASA Astrophysics Data System (ADS)

    Ramírez-Morales, A.; Martínez-Orozco, J. C.; Rodríguez-Vargas, I.

    2011-11-01

    We study the quantum confined stark effect (QCSE) characteristics in Gaussian quantum wells (GQW). This special energy band profile is built varying the aluminum concentration of the AlGaAs ternary alloy in Gaussian fashion. The semi-empirical sp3s* tight-binding model including spin is used to obtain the energy Stark shifts (ESS) and the wave-function Gaussian spatial overlap (GSO) between electrons and holes for different electric field strengths, quantum well widths and aluminum concentrations. We find that both the ESS and the GSO depend parabolically with respect to the electric field strength and the quantum well width. These QCSE characteristics show an asymmetry for the electric field in the forward and reverse directions, related directly to the different band-offset of electrons and holes, being the negative electric fields (reverse direction) more suitable to reach greater ESS. Two important features are presented by this special energy band profile: (1) reductions of the ESS and (2) enhancements of the GSO of tents to hundreds with respect to parabolic and rectangular quantum wells. Even more, tailoring the quantum well width it is possible to reach GSO of thousands with respect to rectangular quantum wells. Finally, it is important to mention that similar results could be obtained in other quantum well heterostructures of materials such as nitrides, oxides (ZnO), and SiGe whenever the confinement band profiles are modulated in Gaussian form.

  3. Isolation of sequences flanking Ac insertion sites by Ac casting.

    PubMed

    Wang, Dafang; Peterson, Thomas

    2013-01-01

    Localizing Ac insertions is a fundamental task in studying Ac-induced mutation and chromosomal rearrangements involving Ac elements. Researchers may sometimes be faced with the situation in which the sequence flanking one side of an Ac/Ds element is known, but the other flank is unknown. Or, a researcher may have a small sequence surrounding the Ac/Ds insertion site and needs to obtain additional flanking genomic sequences. One way to rapidly clone unknown Ac/Ds flanking sequences is via a PCR-based method termed Ac casting. This approach utilizes the somatic transposition activity of Ac during plant development, and provides an efficient means for short-range genome walking. Here we describe the principle of Ac casting, and show how it can be applied to isolate Ac macrotransposon insertion sites.

  4. Tevatron AC dipole system

    SciTech Connect

    Miyamoto, R.; Kopp, S.E.; Jansson, A.; Syphers, M.J.; /Fermilab

    2007-06-01

    The AC dipole is an oscillating dipole magnet which can induce large amplitude oscillations without the emittance growth and decoherence. These properties make it a good tool to measure optics of a hadron synchrotron. The vertical AC dipole for the Tevatron is powered by an inexpensive high power audio amplifier since its operating frequency is approximately 20 kHz. The magnet is incorporated into a parallel resonant system to maximize the current. The use of a vertical pinger magnet which has been installed in the Tevatron made the cost relatively inexpensive. Recently, the initial system was upgraded with a more powerful amplifier and oscillation amplitudes up to 2-3{sigma} were achieved with the 980 GeV proton beam. This paper discusses details of the Tevatron AC dipole system and also shows its test results.

  5. AC-3 audio coder

    NASA Astrophysics Data System (ADS)

    Todd, Craig

    1995-12-01

    AC-3 is a system for coding up to 5.1 channels of audio into a low bit-rate data stream. High quality may be obtained with compression ratios approaching 12-1 for multichannel audio programs. The high compression ratio is achieved by methods which do not increase decoder memory, and thus cost. The methods employed include: the transmission of a high frequency resolution spectral envelope; and a novel forward/backward adaptive bit allocation algorithm. In order to satisfy practical requirements of an emissions coder, the AC-3 syntax includes a number of features useful to broadcasters and consumers. These features include: loudness uniformity between programs; dynamic range control; and broadcaster control of downmix coefficients. The AC-3 coder has been formally selected for inclusion of the U.S. HDTV broadcast standard, and has been informally selected for several additional applications.

  6. Stark spectroscopy of a probe lithium beam excited with two dye lasers as a technique to study a high-power ion-beam diode

    SciTech Connect

    Knyazev, B. A.; An, W.; Bluhm, H.

    2012-03-15

    A non-disturbing measurement of electric field distributions is a subject of special interest in plasma physics and high-voltage devices. In this paper we describe a diagnostic technique for remote sensing of electric fields via injection of a probe beam of lithium atoms and cascade excitation of resonance fluorescence with two broadband dye lasers. The fluorescence spectrum was recorded using a monochromator equipped with an optical multi-channel analyser. The magnitude of the local electric field was retrieved from the Stark-shifted components of the 3d-2plithium spectral line. The technique was applied to measurements of the electric field in the applied-B-field high-voltage diode of the 1 TW KALIF ion-beam accelerator.

  7. Stark spectroscopy of a probe lithium beam excited with two dye lasers as a technique to study a high-power ion-beam diode.

    PubMed

    Knyazev, B A; An, W; Bluhm, H

    2012-03-01

    A non-disturbing measurement of electric field distributions is a subject of special interest in plasma physics and high-voltage devices. In this paper we describe a diagnostic technique for remote sensing of electric fields via injection of a probe beam of lithium atoms and cascade excitation of resonance fluorescence with two broadband dye lasers. The fluorescence spectrum was recorded using a monochromator equipped with an optical multi-channel analyser. The magnitude of the local electric field was retrieved from the Stark-shifted components of the 3d-2p lithium spectral line. The technique was applied to measurements of the electric field in the applied-B-field high-voltage diode of the 1 TW KALIF ion-beam accelerator. PMID:22462900

  8. Measurement of atomic Stark parameters of many Mn I and Fe I spectral lines using GMAW process

    NASA Astrophysics Data System (ADS)

    Zielinska, S.; Pellerin, S.; Dzierzega, K.; Valensi, F.; Musiol, K.; Briand, F.

    2010-11-01

    The particular character of the welding arc working in pure argon, whose emission spectrum consists of many spectral lines strongly broadened by the Stark effect, has allowed measurement, sometimes for the first time, of the Stark parameters of 15 Mn I and 10 Fe I atomic spectral lines, and determination of the dependence on temperature of normalized Stark broadening in Ne = 1023 m-3 of the 542.4 nm atomic iron line. These results show that special properties of the MIG plasma may be useful in this domain because composition of the wire-electrode may be easily adapted to the needs of an experiment.

  9. ac bidirectional motor controller

    NASA Technical Reports Server (NTRS)

    Schreiner, K.

    1988-01-01

    Test data are presented and the design of a high-efficiency motor/generator controller at NASA-Lewis for use with the Space Station power system testbed is described. The bidirectional motor driver is a 20 kHz to variable frequency three-phase ac converter that operates from the high-frequency ac bus being designed for the Space Station. A zero-voltage-switching pulse-density-modulation technique is used in the converter to shape the low-frequency output waveform.

  10. Reactive intermediates in 4He nanodroplets: Infrared laser Stark spectroscopy of dihydroxycarbene

    NASA Astrophysics Data System (ADS)

    Broderick, Bernadette M.; McCaslin, Laura; Moradi, Christopher P.; Stanton, John F.; Douberly, Gary E.

    2015-04-01

    Singlet dihydroxycarbene ( HO C ̈ OH ) is produced via pyrolytic decomposition of oxalic acid, captured by helium nanodroplets, and probed with infrared laser Stark spectroscopy. Rovibrational bands in the OH stretch region are assigned to either trans,trans- or trans,cis-rotamers on the basis of symmetry type, nuclear spin statistical weights, and comparisons to electronic structure theory calculations. Stark spectroscopy provides the inertial components of the permanent electric dipole moments for these rotamers. The dipole components for trans, trans- and trans, cis-rotamers are (μa, μb) = (0.00, 0.68(6)) and (1.63(3), 1.50(5)), respectively. The infrared spectra lack evidence for the higher energy cis,cis-rotamer, which is consistent with a previously proposed pyrolytic decomposition mechanism of oxalic acid and computations of HO C ̈ OH torsional interconversion and tautomerization barriers.

  11. Initial operation of a newly developed multichord motional Stark effect diagnostic in KSTAR

    NASA Astrophysics Data System (ADS)

    Chung, J.; Ko, J.; Wi, H.; Messmer, M.; Schenkelaars, S.; Scheffer, M.; Jaspers, R. J. E.

    2016-11-01

    A photo-elastic modulator based 25-chord motional Stark effect (MSE) diagnostic has been successfully developed and commissioned in Korea Superconducting Tokamak Advanced Research. The diagnostic measures the radial magnetic pitch angle profile of the Stark splitting of a D-alpha line at 656.1 nm by the electric field associated with the neutral deuterium heating beam. A tangential view of the neutral beam provides a good spatial resolution of 1-3 cm for covering the major radius from 1.74 m to 2.28 m, and the time resolution is achieved at 10 ms. An in-vessel calibration before the vacuum closing as well as an in situ calibration during the tokamak operation was performed by means of specially designed polarized lighting sources. In this work, we present the final design of the installed MSE diagnostic and the first results of the commissioning.

  12. Can the Stark-Einstein law resolve the measurement problem from an animate perspective?

    PubMed

    Thaheld, Fred H

    2015-09-01

    Analysis of the Stark-Einstein law as it applies to the retinal molecule, which is part of the rhodopsin molecule within the rod cells of the retina, reveals that it may provide the solution to the measurement problem from an animate perspective. That it represents a natural boundary where the Schrödinger equation or wave function automatically goes from linear to nonlinear while remaining in a deterministic state. It will be possible in the near future to subject this theory to empirical tests as has been previously proposed. This analysis provides a contrast to the many decades well studied and debated inanimate measurement problem and would represent an addition to the Stark-Einstein law involving information carried by the photon.

  13. Reactive intermediates in {sup 4}He nanodroplets: Infrared laser Stark spectroscopy of dihydroxycarbene

    SciTech Connect

    Broderick, Bernadette M.; Moradi, Christopher P.; Douberly, Gary E.; McCaslin, Laura; Stanton, John F.

    2015-04-14

    Singlet dihydroxycarbene (HOC{sup ¨}OH) is produced via pyrolytic decomposition of oxalic acid, captured by helium nanodroplets, and probed with infrared laser Stark spectroscopy. Rovibrational bands in the OH stretch region are assigned to either trans,trans- or trans,cis-rotamers on the basis of symmetry type, nuclear spin statistical weights, and comparisons to electronic structure theory calculations. Stark spectroscopy provides the inertial components of the permanent electric dipole moments for these rotamers. The dipole components for trans, trans- and trans, cis-rotamers are (μ{sub a}, μ{sub b}) = (0.00, 0.68(6)) and (1.63(3), 1.50(5)), respectively. The infrared spectra lack evidence for the higher energy cis,cis-rotamer, which is consistent with a previously proposed pyrolytic decomposition mechanism of oxalic acid and computations of HOC{sup ¨}OH torsional interconversion and tautomerization barriers.

  14. Femtosecond laser detection of Stark-decelerated and trapped methylfluoride molecules

    NASA Astrophysics Data System (ADS)

    Meng, Congsen; van der Poel, Aernout P. P.; Cheng, Cunfeng; Bethlem, Hendrick L.

    2015-08-01

    We demonstrate deceleration and trapping of methylfluoride (CH3F ) molecules in the low-field-seeking component of the J =1 ,K =1 state using a combination of a conventional Stark decelerator and a traveling wave decelerator. The methylfluoride molecules are detected by nonresonant multiphoton ionization using a femtosecond laser. Subsequent mass and velocity selection of the produced ions enables us to eliminate most background signal resulting from thermal gas in our vacuum chamber. This detection method can be applied to virtually any molecule, thereby enhancing the scope of molecules that can be Stark decelerated. Methylfluoride is so far the heaviest and most complex molecule that has been decelerated to rest. Typically we trap 2 ×104 CH3F molecules at a peak density of 4.5 ×107 cm-3 and a temperature of 40 mK.

  15. Kickbacks, stark violations, client billing, and joint ventures: facts and controversies.

    PubMed

    Mannava, Kathleen A; Bercovitch, Lionel; Grant-Kels, Jane M

    2013-01-01

    Many current business trends in the field of dermatopathology deserve ethical scrutiny. An important point to consider in these analyses is that which is legal is not necessarily ethical. We examine the topics of client billing, contractual joint ventures, and health information technology donations, including both the legal implications as pertaining to the Stark Law and Anti-Kickback Statute, and the ethical ramifications of these practices. PMID:24160283

  16. Spatial heterodyne Stokes vector imaging of the motional Stark-Zeeman multiplet.

    PubMed

    Howard, John; Chung, Jinil

    2012-10-01

    We present a general Stokes interferometer/polarimeter suitable for polarimetric imaging the elliptically polarized motional Stark-Zeeman multiplet. We also introduce a fully phase-heterodyne spatial multiplex variant of the system that has been used for imaging of Balmer alpha emission from the heating neutral beam in the KSTAR super-conducting tokamak in Korea. The polarimeter performance is illustrated using various polarization test targets. PMID:23126853

  17. Kickbacks, stark violations, client billing, and joint ventures: facts and controversies.

    PubMed

    Mannava, Kathleen A; Bercovitch, Lionel; Grant-Kels, Jane M

    2013-01-01

    Many current business trends in the field of dermatopathology deserve ethical scrutiny. An important point to consider in these analyses is that which is legal is not necessarily ethical. We examine the topics of client billing, contractual joint ventures, and health information technology donations, including both the legal implications as pertaining to the Stark Law and Anti-Kickback Statute, and the ethical ramifications of these practices.

  18. NMR Stark Spectroscopy: New Methods to Calibrate NMR Sensitivity to Electric Fields

    NASA Astrophysics Data System (ADS)

    Tarasek, Matthew R.

    The influence of electrostatics on NMR parameters is well accepted. Thus, NMR is a promising route to probe electrical features within molecules and materials. However, applications of NMR Stark effects (E-field induced changes in spin energy levels) have been elusive. I have developed new approaches to resolve NMR Stark effects from an applied E field. This calibrates nuclear probes whose spectral response might later be used to evaluate internal E fields that are critical to function, such as those due to local charge distributions or sample structure. I will present two novel experimental approaches for direct calibration of NMR quadrupolar Stark effects (QSEs). In the first, steady-state (few-second) excitation by an E field at twice the NMR frequency (2ω 0) is used to saturate spin magnetization. The extent of saturation vs. E-field amplitude calibrates the QSE response rate, while measurements vs sample orientation determine tensorial character. The second method instead synchronizes short (few µs) pulses of the 2ω0 E field with a multiple-pulse NMR sequence. This, “POWER” (Perturbations Observed With Enhanced Resolution) approach enables more accurate measure of small QSEs (i.e. few Hz spectral changes). A 2nd key advantage is the ability to define tensorial response without reorienting the sample, but instead varying the phase of the 2ω0 field. I will describe these experiments and my home-built NMR “Stark probe”, employed on a conventional wide-bore solid-state NMR system. Results with GaAs demonstrate each method, while extensions to a wider array of molecular and material systems may now be possible using these methods.

  19. AC/RF Superconductivity

    SciTech Connect

    Ciovati, Gianluigi

    2015-02-01

    This contribution provides a brief introduction to AC/RF superconductivity, with an emphasis on application to accelerators. The topics covered include the surface impedance of normal conductors and superconductors, the residual resistance, the field dependence of the surface resistance, and the superheating field.

  20. Stark effect modeling in the detailed opacity code SCO-RCG

    NASA Astrophysics Data System (ADS)

    Pain, J.-C.; Gilleron, F.; Gilles, D.

    2016-05-01

    The broadening of lines by Stark effect is an important tool for inferring electron density and temperature in plasmas. Stark-effect calculations often rely on atomic data (transition rates, energy levels,...) not always exhaustive and/or valid for isolated atoms. We present a recent development in the detailed opacity code SCO-RCG for K-shell spectroscopy (hydrogen- and helium-like ions). This approach is adapted from the work of Gilles and Peyrusse. Neglecting non-diagonal terms in dipolar and collision operators, the line profile is expressed as a sum of Voigt functions associated to the Stark components. The formalism relies on the use of parabolic coordinates within SO(4) symmetry. The relativistic fine-structure of Lyman lines is included by diagonalizing the hamiltonian matrix associated to quantum states having the same principal quantum number n. The resulting code enables one to investigate plasma environment effects, the impact of the microfield distribution, the decoupling between electron and ion temperatures and the role of satellite lines (such as Li-like 1snℓn'ℓ' — 1s 2 nℓ, Be-like, etc.). Comparisons with simpler and widely-used semi-empirical models are presented.

  1. Stark effect spectroscopy of Rhodobacter sphaeroides and Rhodopseudomonas viridis reaction centers

    PubMed Central

    Lockhart, David J.; Boxer, Steven G.

    1988-01-01

    The nature of the initially excited state of the primary electron donor or special pair has been investigated by Stark effect spectroscopy for reaction centers from the photosynthetic bacteria Rhodopseudomonas viridis and Rhodobacter sphaeroides at 77 K. The data provide values for the magnitude of the difference in permanent dipole moment between the ground and excited state, [unk]Δμ[unk], and the angle [unk] between Δμ and the transition dipole moment for the electronic transition. [unk]Δμ[unk] and [unk] for the lowest-energy singlet electronic transition associated with the special pair primary electron donor were found to be very similar for the two species. [unk]Δμ[unk] for this transition is substantially larger than for the Qy transitions of the monomeric pigments in the reaction center or for pure monomeric bacteriochlorophylls, for which Stark data are also reported. We conclude that the excited state of the special pair has substantial charge-transfer character, and we suggest that charge separation in bacterial photosynthesis is initiated immediately upon photoexcitation of the special pair. Data for Rhodobacter sphaeroides between 340 and 1340 nm are presented and discussed in the context of the detection of charge-transfer states by Stark effect spectroscopy. PMID:16578825

  2. Stark Profiles In Plasmas Interacting With A Strong Oscillatory Quasi-Monochromatic Electric Field

    SciTech Connect

    Sauvan, P.; Oks, E.; Renner, O.; Weber, S.

    2010-10-29

    This paper presents an advanced analysis of the spectroscopic signatures of the interaction of a strong oscillating Quasi-monochromatic Electric Field (QEF), generated by a high-power short-pulse laser, with a preformed laser-produced plasma. The computation of a synthetic spectrum emitted by such plasmas requires the calculation of the Stark line shape in the presence of a QEF and the evaluation of the QEF intensity profile throughout the line of sight in the plasma. As for the Stark profiles in hot dense plasmas submitted to a strong QEF, they are calculated using the so-called Floquet-Liouville formalism. In this formalism, the Liouville space, usually used for the calculation of Stark profiles in dense plasmas, and the Floquet theory, developed to solve time-periodic problems, have been joined together to solve the time-dependent Liouville equation. A second kind of simulations involving Particle-In-Cell PIC kinetic simulations is required for the calculation of the QEF inhomogeneous intensity and the exotic features exhibited in the spectroscopic diagnostic. The global synthetic profile is obtained integrating all individual contributions for every time and location in the plasma. Finally, a spectroscopic analysis of the experimental Al He {beta} line is performed using the tools presented in this work. The spectroscopic signatures of the QEF show up as prominent satellites, non symmetrical with respect to the unperturbed line and distinguishable from the di-electronic satellites.

  3. A Simultaneous Discovery: The Case of Johannes Stark and Antonino Lo Surdo

    NASA Astrophysics Data System (ADS)

    Leone, Matteo; Paoletti, Alessandro; Robotti, Nadia

    2004-09-01

    In 1913 the German physicist Johannes Stark (1874 1957) and the Italian physicist Antonino Lo Surdo (1880 1949)discovered virtually simultaneously and independently that hydrogen spectral lines are split into components by an external electric field. Both of their discoveries ensued from studies on the same phenomenon, the Doppler effect in canal rays, but they arose in different theoretical contexts. Stark had been working within the context of the emerging quantum theory, following a research program aimed at studying the effect of an electric field on spectral lines. Lo Surdo had been working within the context of the classical theory, and his was an accidental discovery. Both discoveries, however, played important roles in the history of physics: Stark’s discovery contributed to the establishment of both the old and the new quantum theories; Lo Surdo’s discovery led Antonio Garbasso (1871 1933)to introduce research on the quantum theory into Italian physics. Ironically, soon after their discoveries, both Stark and Lo Surdo rejected developments in modern physics and allied themselves with the political and racial programs of Hitler and Mussolini.

  4. Stark broadening of impurity absorption lines by inhomogeneous electric fields in highly compensated germanium

    NASA Astrophysics Data System (ADS)

    Harada, Y.; Fujii, K.; Ohyama, T.; Itoh, K. M.; Haller, E. E.

    1996-06-01

    Stark broadening of Zeeman absorption lines caused by inhomogeneous electric fields in highly compensated Ge has been studied by means of far-infrared magneto-optical absorption spectroscopy measurements. A number of transmutation-doped Ge single crystals with a systematically varying compensation ratio were employed. The broadening of the full width at half maximum (FWHM) of an absorption line of the Ga acceptor is studied as a function of excitation light intensity with above-band-gap energy. The FWHM increases with decreasing intensity of the band-edge light excitation. Observation of the theoretically predicted 4/3-power law of Stark broadening, due to ionized impurities, is reported. The line broadening originates in the Stark effect, due to inhomogeneous electric fields caused by the random distribution of ionized impurities. In order to understand the mechanism for the line broadening in detail, a numerical approach based on a Monte Carlo simulation has been performed. The results of this simulation show that the inhomogeneity of the field distribution becomes larger with increasing concentration of ionized impurities. The simulation based on a perfectly random distribution for an initial impurity arrangement gives a fairly good agreement with the experimental results. We conclude that the distribution of impurities in transmutation-doped Ge samples is close to random.

  5. [Calculating the stark broadening of welding arc spectra by Fourier transform method].

    PubMed

    Pan, Cheng-Gang; Hua, Xue-Ming; Zhang, Wang; Li, Fang; Xiao, Xiao

    2012-07-01

    It's the most effective and accurate method to calculate the electronic density of plasma by using the Stark width of the plasma spectrum. However, it's difficult to separate Stark width from the composite spectrum linear produced by several mechanisms. In the present paper, Fourier transform was used to separate the Lorentz linear from the spectrum observed, thus to get the accurate Stark width. And we calculated the distribution of the TIG welding arc plasma. This method does not need to measure arc temperature accurately, to measure the width of the plasma spectrum broadened by instrument, and has the function to reject the noise data. The results show that, on the axis, the electron density of TIG welding arc decreases with the distance from tungsten increasing, and changes from 1.21 X 10(17) cm(-3) to 1.58 x 10(17) cm(-3); in the radial, the electron density decreases with the distance from axis increasing, and near the tungsten zone the biggest electronic density is off axis. PMID:23016315

  6. Calculation of the shifts of argon spectral lines

    SciTech Connect

    Christova, M.; Andreev, N.; Christov, L.; Dimitrijevic, M. S.

    2008-10-22

    Shifts due to collisions with charged particles (Stark broadening ) and neutral atoms, were determined for nine argon spectral lines corresponding to the transitions 3p{sup 5}nd-3p{sup 5}4p for n = 4-7, 3p{sup 5}6s-3p{sup 5}4d and 3p{sup 5}4p'-3p{sup 5}4s in order to estimate their usability for the research and diagnostics of a plasma in a surface-wave discharge at atmospheric pressure.

  7. AC power systems handbook

    SciTech Connect

    Whitaker, J.

    1991-01-01

    Transient disturbances are what headaches are made of. Whatever you call them-spikes, surges, are power bumps-they can take your equipment down and leave you with a complicated and expensive repair job. Protection against transient disturbances is a science that demands attention to detail. This book explains how the power distribution system works, what can go wrong with it, and how to protect a facility against abnormalities. system grounding and shielding are covered in detail. Each major method of transient protection is analyzed and its relative merits discussed. The book provides a complete look at the critical elements of the ac power system. Provides a complete look at the ac power system from generation to consumption. Discusses the mechanisms that produce transient disturbances and how to protect against them. Presents diagrams to facilitate system design. Covers new areas, such as the extent of the transient disturbance problem, transient protection options, and stand-by power systems.

  8. Increased Ac excision (iae): Arabidopsis thaliana mutations affecting Ac transposition.

    PubMed

    Jarvis, P; Belzile, F; Page, T; Dean, C

    1997-05-01

    The maize transposable element Ac is highly active in the heterologous hosts tobacco and tomato, but shows very much reduced levels of activity in Arabidopsis. A mutagenesis experiment was undertaken with the aim of identifying Arabidopsis host factors responsible for the observed low levels of Ac activity. Seed from a line carrying a single copy of the Ac element inserted into the streptomycin phosphotransferase (SPT) reporter fusion, and which displayed typically low levels of Ac activity, were mutagenized using gamma rays. Nineteen mutants displaying high levels of somatic Ac activity, as judged by their highly variegated phenotypes, were isolated after screening the M2 generation on streptomycin-containing medium. The mutations fall into two complementation groups, iae1 and iae2, are unlinked to the SPT::Ac locus and segregate in a Mendelian fashion. The iae1 mutation is recessive and the iae2 mutation is semi-dominant. The iae1 and iae2 mutants show 550- and 70-fold increases, respectively, in the average number of Ac excision sectors per cotyledon. The IAE1 locus maps to chromosome 2, whereas the SPT::Ac reporter maps to chromosome 3. A molecular study of Ac activity in the iae1 mutant confirmed the very high levels of Ac excision predicted using the phenotypic assay, but revealed only low levels of Ac re-insertion. Analyses of germinal transposition in the iae1 mutant demonstrated an average germinal excision frequency of 3% and a frequency of independent Ac re-insertions following germinal excision of 22%. The iae mutants represents a possible means of improving the efficiency of Ac/Ds transposon tagging systems in Arabidopsis, and will enable the dissection of host involvement in Ac transposition and the mechanisms employed for controlling transposable element activity.

  9. Ge/SiGe quantum well for photonic applications: modelling of the quantum confined Stark effect

    NASA Astrophysics Data System (ADS)

    Isella, Giovanni; Ballabio, Andrea; Frigerio, Jacopo

    2016-05-01

    Ge quantum wells are emerging as a relevant material system for enabling fast and power-efficient optical modulation in the framework of Si-photonics. The need for reliable designs of QW structures, matching given operating wavelengths and bias voltages, calls for the implementation of modelling tools capturing the optical properties of SiGe heterostructures. Here we report on the calculation of the quantum confined Stark effect based on an eight-band k×p model. The obtained spectra are analysed and compared with experimental data showing a good agreement between calculation and measurements.

  10. Stark Effect Spectroscopy of Mono- and Few-Layer MoS2.

    PubMed

    Klein, J; Wierzbowski, J; Regler, A; Becker, J; Heimbach, F; Müller, K; Kaniber, M; Finley, J J

    2016-03-01

    We demonstrate electrical control of the A-exciton interband transition in mono- and few-layer MoS2 crystals embedded into photocapacitor devices via the DC Stark effect. Electric field-dependent low-temperature photoluminescence spectroscopy reveals a significant tuneability of the A-exciton transition energy up to ∼ 16 meV from which we extract the mean DC exciton polarizability ⟨β̅N⟩ = (0.58 ± 0.25) × 10(-8) Dm V(-1). The exciton polarizability is shown to be layer-independent, indicating a strong localization of both electron and hole wave functions in each individual layer.

  11. Revisiting the Stark Broadening by fluctuating electric fields using the Continuous Time Random Walk Theory

    NASA Astrophysics Data System (ADS)

    Capes, H.; Christova, M.; Boland, D.; Catoire, F.; Godbert-Mouret, L.; Koubiti, M.; Mekkaoui, A.; Rosato, J.; Marandet, Y.; Stamm, R.

    2010-10-01

    Stark broadening of atomic lines in plasmas is calculated by modelling the plasma stochastic electric field using the CTRW approach [1,2]. This allows retaining non Markovian terms in the Schrödinger equation averaged over the electric field fluctuations. As an application we consider a special case of a non separable CTRW process, the so called Kangaroo process [3]. An analytic expression for the line profile is presented for arbitrary waiting time distribution functions. A preliminary application to the hydrogen Lyman α line is discussed.

  12. Application of Stark Tuned Laser for Interferometry and Polarimetry in Plasmas

    SciTech Connect

    H.K. Park; K.C. Lee; B. Deng; C.W. Domier; M. Johnson; B. Nathan; and N.C. Luhmann, Jr.

    2001-09-07

    A Stark-tuned optically pumped far-infrared CH(subscript ''3'')OH laser at 119 mm has been successfully applied in the Far Infrared Tangential Interferometer/Polarimeter (FIReTIP) system for the National Spherical Torus Experiment (NSTX). The system will provide temporally and radially resolved 2-D electron density profile [n(subscript ''e'')(r,t)] and toroidal field profile [B(subscript ''T'')(r,t)] data. In the 2001 campaign, a single channel interferometer system has been operated and tested for the Faraday rotation measurement. A plan for improvement and upgrading of the FIReTIP is discussed.

  13. Supersymmetric factorization yields exact solutions to the molecular Stark-effect problem for stretched states

    SciTech Connect

    Lemeshko, Mikhail; Mustafa, Mustafa; Kais, Sabre; Friedrich, Bretislav

    2011-04-15

    By invoking supersymmetry, we found a condition under which the Stark-effect problem for a polar and polarizable molecule subject to nonresonant electric fields becomes exactly solvable for the |J-tilde=m,m> family of stretched states. The analytic expressions for the wave function and eigenenergy and other expectation values allow one to readily reverse-engineer the problem of finding the values of the interaction parameters required for creating quantum states with preordained characteristics. The method also allows the construction of families of isospectral potentials, realizable with combined fields.

  14. Stark Effect Spectroscopy of Mono- and Few-Layer MoS2.

    PubMed

    Klein, J; Wierzbowski, J; Regler, A; Becker, J; Heimbach, F; Müller, K; Kaniber, M; Finley, J J

    2016-03-01

    We demonstrate electrical control of the A-exciton interband transition in mono- and few-layer MoS2 crystals embedded into photocapacitor devices via the DC Stark effect. Electric field-dependent low-temperature photoluminescence spectroscopy reveals a significant tuneability of the A-exciton transition energy up to ∼ 16 meV from which we extract the mean DC exciton polarizability ⟨β̅N⟩ = (0.58 ± 0.25) × 10(-8) Dm V(-1). The exciton polarizability is shown to be layer-independent, indicating a strong localization of both electron and hole wave functions in each individual layer. PMID:26845085

  15. From molecular control to quantum technology with the dynamic Stark effect.

    PubMed

    Bustard, Philip J; Wu, Guorong; Lausten, Rune; Townsend, Dave; Walmsley, Lan A; Stolow, Albert; Sussman, Benjamin J

    2011-01-01

    The non-resonant dynamic Stark effect is a powerful and general way of manipulating ultrafast processes in atoms, molecules, and solids with exquisite precision. We discuss the physics behind this effect, and demonstrate its efficacy as a method of control in a variety of systems. These applications range from the control of molecular rotational dynamics to the manipulation of chemical reaction dynamics, and from the suppression of vacuum fluctuation effects in coherent preparation of matter, to the dynamic generation of bandwidth for storage of broadband quantum states of light. PMID:22452088

  16. From molecular control to quantum technology with the dynamic Stark effect.

    PubMed

    Bustard, Philip J; Wu, Guorong; Lausten, Rune; Townsend, Dave; Walmsley, Lan A; Stolow, Albert; Sussman, Benjamin J

    2011-01-01

    The non-resonant dynamic Stark effect is a powerful and general way of manipulating ultrafast processes in atoms, molecules, and solids with exquisite precision. We discuss the physics behind this effect, and demonstrate its efficacy as a method of control in a variety of systems. These applications range from the control of molecular rotational dynamics to the manipulation of chemical reaction dynamics, and from the suppression of vacuum fluctuation effects in coherent preparation of matter, to the dynamic generation of bandwidth for storage of broadband quantum states of light.

  17. Passive stabilization of a hole spin qubit using the optical Stark effect

    NASA Astrophysics Data System (ADS)

    Ramsay, A. J.

    2016-02-01

    The extrinsic dephasing of a hole spin confined to a self-assembled quantum dot is dominated by charge noise acting on an electric-field-dependent g -factor. Here we propose the use of the optical Stark effect to reduce the sensitivity of the effective hole Zeeman energy to fluctuations in the local electric field. Calculations using measured quantum dot parameters are presented, and they demonstrate a factor of 10-100 reduction in the extrinsic dephasing. Compared to active stabilization methods, this technique should benefit from reduced experimental complexity.

  18. [The reconstruction of welding arc 3D electron density distribution based on Stark broadening].

    PubMed

    Zhang, Wang; Hua, Xue-Ming; Pan, Cheng-Gang; Li, Fang; Wang, Min

    2012-10-01

    The three-dimensional electron density is very important for welding arc quality control. In the present paper, Side-on characteristic line profile was collected by a spectrometer, and the lateral experimental data were approximated by a polynomial fitting. By applying an Abel inversion technique, the authors obtained the radial intensity distribution at each wavelength and thus constructed a profile for the radial positions. The Fourier transform was used to separate the Lorentz linear from the spectrum reconstructed, thus got the accurate Stark width. And we calculated the electronic density three-dimensional distribution of the TIG welding are plasma. PMID:23285847

  19. [Determination of electron density in atmospheric pressure radio frequency dielectric barrier discharges by Stark broadening].

    PubMed

    Li, Sen; Liu, Zhong-wei; Chen, Qiang; Liu, Fu-ping; Wang, Zheng-duo; Yang, Li-zhen

    2012-01-01

    The use of high frequency power to generate plasma at atmospheric pressure is a relatively new development. An apparatus of atmospheric pressure radio frequency dielectric barrier discharge was constructed. Plasma emission based measurement of electron density in discharge columns from Stark broadening Ar is discribed. The spacial profile of electron density was studied. In the middle of the discharge column, as the input power increases from 138 to 248 W, the electron density rises from 4.038 x 10(21) m(-3) to 4.75 x 10(21) m(-3). PMID:22497121

  20. Stark effect in ensembles of polar (0001) Al{sub 0.5}Ga{sub 0.5}N/GaN quantum dots and comparison with semipolar (11−22) ones

    SciTech Connect

    Leroux, M.; Brault, J.; Kahouli, A.; Damilano, B.; Mierry, P. de; Korytov, M.; Maghraoui, D.; Kim, Je-Hyung; Cho, Yong-Hoon

    2014-07-21

    This work presents a continuous-wave photoluminescence study of Al{sub 0.5}Ga{sub 0.5}N/GaN quantum dots grown by ammonia-assisted molecular beam epitaxy on sapphire, either on the wurtzite polar (0001) or the semipolar (11−22) plane. Due to interface polarization discontinuities, the polar dots are strongly red-shifted by the Stark effect and emit in the visible range. Carrier injection screening of the polarization charges has been studied. A model relying on average dot heights and dot height variances, as measured by transmission electron microscopy, is proposed. It can account for the injection dependent luminescence energies and efficiencies. The electric field discontinuity deduced from the fittings is in good agreement with theoretical expectations for our barrier composition. On the contrary, semipolar quantum dot ensembles always emit above the gap of GaN strained to Al{sub 0.5}Ga{sub 0.5}N. Their luminescence linewidth is significantly lower than that of polar ones, and their energy does not shift with injection. Our study then confirms the expected strong decrease of the Stark effect for (11−22) grown (Al,Ga)N/GaN heterostructures.

  1. AC propulsion system for an electric vehicle, phase 2

    NASA Technical Reports Server (NTRS)

    Slicker, J. M.

    1983-01-01

    A second-generation prototype ac propulsion system for a passenger electric vehicle was designed, fabricated, tested, installed in a modified Mercury Lynx vehicle and track tested at the Contractor's site. The system consisted of a Phase 2, 18.7 kw rated ac induction traction motor, a 192-volt, battery powered, pulse-width-modulated, transistorized inverter packaged for under rear seat installation, a 2-axis, 2-speed, automatically-shifted mechanical transaxle and a microprocessor-based powertrain/vehicle controller. A diagnostics computer to assist tuning and fault finding was fabricated. Dc-to-mechanical-system efficiency varied from 78% to 82% as axle speed/torque ranged from 159 rpm/788 nm to 65 rpm/328 nm. Track test efficiency results suggest that the ac system will be equal or superior to dc systems when driving urban cycles. Additional short-term work is being performed under a third contract phase (AC-3) to raise transaxle efficiency to predicted levels, and to improve starting and shifting characteristics. However, the long-term challenge to the system's viability remains inverter cost. A final report on the Phase 2 system, describing Phase 3 modifications, will be issued at the conclusion of AC-3.

  2. Stark spectrum simulation for X2Y4 molecules: Application to the ν12 band of ethylene in a high-silica zeolite

    NASA Astrophysics Data System (ADS)

    Sanzharov, Maxim; Rotger, Maud; Loëte, Michel; Boudon, Vincent; Zvereva-Loëte, Natalia; Ballandras, Anthony; Weber, Guy

    2012-04-01

    The influence of an electric field of silicalite-1-zeolite on the FTIR vibrational absorption spectrum of ethylene has been simulated and compared to experimental spectra. The presence of silicalite-1 produces a global shift and a change of the structure of vibrational bands. To explain the global shift of the ν12 band (CH2 scissor mode) and therefore to estimate an effective average field produced by silicalite-1, Stark calculations were performed. These calculations were based on a tensorial formalism implemented in the D2hTDS-ST package [M. Sanzharov, M. Rotger, C. Wenger, M. Loëte, V. Boudon, and A. Rouzée, J. Quant. Spectrosc. Radiat. Transf. 112, 41 (2011)], 10.1016/j.jqsrt.2010.08.023. The value of the field obtained using tensorial formalism (8-11 GV/m) is compared with values obtained using ab initio calculations. A theory of the molecular alignment in the electric field using tensorial formalism is also developed to model the interaction of ethylene in contact with a zeolite environment.

  3. Stark spectrum simulation for X2Y4 molecules: application to the ν12 band of ethylene in a high-silica zeolite.

    PubMed

    Sanzharov, Maxim; Rotger, Maud; Loëte, Michel; Boudon, Vincent; Zvereva-Loëte, Natalia; Ballandras, Anthony; Weber, Guy

    2012-04-01

    The influence of an electric field of silicalite-1-zeolite on the FTIR vibrational absorption spectrum of ethylene has been simulated and compared to experimental spectra. The presence of silicalite-1 produces a global shift and a change of the structure of vibrational bands. To explain the global shift of the ν(12) band (CH(2) scissor mode) and therefore to estimate an effective average field produced by silicalite-1, Stark calculations were performed. These calculations were based on a tensorial formalism implemented in the D(2h)TDS-ST package [M. Sanzharov, M. Rotger, C. Wenger, M. Loëte, V. Boudon, and A. Rouzée, J. Quant. Spectrosc. Radiat. Transf. 112, 41 (2011)]. The value of the field obtained using tensorial formalism (8-11 GV/m) is compared with values obtained using ab initio calculations. A theory of the molecular alignment in the electric field using tensorial formalism is also developed to model the interaction of ethylene in contact with a zeolite environment.

  4. AC resistance measuring instrument

    DOEpatents

    Hof, P.J.

    1983-10-04

    An auto-ranging AC resistance measuring instrument for remote measurement of the resistance of an electrical device or circuit connected to the instrument includes a signal generator which generates an AC excitation signal for application to a load, including the device and the transmission line, a monitoring circuit which provides a digitally encoded signal representing the voltage across the load, and a microprocessor which operates under program control to provide an auto-ranging function by which range resistance is connected in circuit with the load to limit the load voltage to an acceptable range for the instrument, and an auto-compensating function by which compensating capacitance is connected in shunt with the range resistance to compensate for the effects of line capacitance. After the auto-ranging and auto-compensation functions are complete, the microprocessor calculates the resistance of the load from the selected range resistance, the excitation signal, and the load voltage signal, and displays of the measured resistance on a digital display of the instrument. 8 figs.

  5. AC Resistance measuring instrument

    DOEpatents

    Hof, Peter J.

    1983-01-01

    An auto-ranging AC resistance measuring instrument for remote measurement of the resistance of an electrical device or circuit connected to the instrument includes a signal generator which generates an AC excitation signal for application to a load, including the device and the transmission line, a monitoring circuit which provides a digitally encoded signal representing the voltage across the load, and a microprocessor which operates under program control to provide an auto-ranging function by which range resistance is connected in circuit with the load to limit the load voltage to an acceptable range for the instrument, and an auto-compensating function by which compensating capacitance is connected in shunt with the range resistance to compensate for the effects of line capacitance. After the auto-ranging and auto-compensation functions are complete, the microprocessor calculates the resistance of the load from the selected range resistance, the excitation signal, and the load voltage signal, and displays of the measured resistance on a digital display of the instrument.

  6. Non-resonant dynamic stark control of vibrational motion with optimized laser pulses.

    PubMed

    Thomas, Esben F; Henriksen, Niels E

    2016-06-28

    The term dynamic Stark control (DSC) has been used to describe methods of quantum control related to the dynamic Stark effect, i.e., a time-dependent distortion of energy levels. Here, we employ analytical models that present clear and concise interpretations of the principles behind DSC. Within a linearly forced harmonic oscillator model of vibrational excitation, we show how the vibrational amplitude is related to the pulse envelope, and independent of the carrier frequency of the laser pulse, in the DSC regime. Furthermore, we shed light on the DSC regarding the construction of optimal pulse envelopes - from a time-domain as well as a frequency-domain perspective. Finally, in a numerical study beyond the linearly forced harmonic oscillator model, we show that a pulse envelope can be constructed such that a vibrational excitation into a specific excited vibrational eigenstate is accomplished. The pulse envelope is constructed such that high intensities are avoided in order to eliminate the process of ionization.

  7. Non-resonant dynamic stark control of vibrational motion with optimized laser pulses

    NASA Astrophysics Data System (ADS)

    Thomas, Esben F.; Henriksen, Niels E.

    2016-06-01

    The term dynamic Stark control (DSC) has been used to describe methods of quantum control related to the dynamic Stark effect, i.e., a time-dependent distortion of energy levels. Here, we employ analytical models that present clear and concise interpretations of the principles behind DSC. Within a linearly forced harmonic oscillator model of vibrational excitation, we show how the vibrational amplitude is related to the pulse envelope, and independent of the carrier frequency of the laser pulse, in the DSC regime. Furthermore, we shed light on the DSC regarding the construction of optimal pulse envelopes - from a time-domain as well as a frequency-domain perspective. Finally, in a numerical study beyond the linearly forced harmonic oscillator model, we show that a pulse envelope can be constructed such that a vibrational excitation into a specific excited vibrational eigenstate is accomplished. The pulse envelope is constructed such that high intensities are avoided in order to eliminate the process of ionization.

  8. Theoretical study of the Stark broadening for Mg IV spectral lines of astrophysical interest

    NASA Astrophysics Data System (ADS)

    de Andrés-García, I.; You, C.; Alonso-Medina, A.; Colón, C.

    2016-08-01

    Emission lines of Mg IV have been detected in the Far Ultraviolet Spectroscopic Explorer (FUSE) spectrum of LS V +46º21 star and in the Space Telescope Imaging Spectrograph (STIS) spectrum of BD +28º4211 star. This fact justifies our interest in providing spectroscopic parameters of Mg IV. Stark broadening parameters for 169 spectral lines of Mg IV have been calculated by using the Griem semi-empirical approach. The matrix elements used in these calculations has been determined from 13 configurations of Mg IV: 2s12p6, 2s22p4ns (n = 3-5), 2s22p4nd (n = 3-5) and 2s22p45g for even parity and 2s22p5, 2s22p4np (n = 3, 4) and 2s22p4nf (n = 4, 5) for odd parity. Our calculations were made by using the Cowan code. Data are presented for an electron density of 1017 cm-3 and temperatures T = 1.0-10.0 (104 K). Also we present calculated values of transition probabilities for 30 spectral lines and radiative lifetimes corresponding to its upper levels. These values were analyzed using the data found in the literature. Theoretical trends of the Stark broadening parameters versus the temperature for several lines of astrophysical interest are presented.

  9. Non-resonant dynamic stark control of vibrational motion with optimized laser pulses.

    PubMed

    Thomas, Esben F; Henriksen, Niels E

    2016-06-28

    The term dynamic Stark control (DSC) has been used to describe methods of quantum control related to the dynamic Stark effect, i.e., a time-dependent distortion of energy levels. Here, we employ analytical models that present clear and concise interpretations of the principles behind DSC. Within a linearly forced harmonic oscillator model of vibrational excitation, we show how the vibrational amplitude is related to the pulse envelope, and independent of the carrier frequency of the laser pulse, in the DSC regime. Furthermore, we shed light on the DSC regarding the construction of optimal pulse envelopes - from a time-domain as well as a frequency-domain perspective. Finally, in a numerical study beyond the linearly forced harmonic oscillator model, we show that a pulse envelope can be constructed such that a vibrational excitation into a specific excited vibrational eigenstate is accomplished. The pulse envelope is constructed such that high intensities are avoided in order to eliminate the process of ionization. PMID:27369515

  10. Theoretical study of the Stark broadening for Mg IV spectral lines of astrophysical interest

    NASA Astrophysics Data System (ADS)

    de Andrés-García, I.; You, C.; Alonso-Medina, A.; Colón, C.

    2016-11-01

    Emission lines of Mg IV have been detected in the Far Ultraviolet Spectroscopic Explorer (FUSE) spectrum of LS V +46°21 star and in the Space Telescope Imaging Spectrograph (STIS) spectrum of BD +28°4211 star. This fact justifies our interest in providing spectroscopic parameters of Mg IV. Stark broadening parameters for 169 spectral lines of Mg IV have been calculated by using the Griem semi-empirical approach. The matrix elements used in these calculations has been determined from 13 configurations of Mg IV: 2s12p6, 2s22p4ns (n = 3-5), 2s22p4nd (n = 3-5) and 2s22p45g for even parity and 2s22p5, 2s22p4np (n = 3, 4) and 2s22p4nf (n = 4, 5) for odd parity. Our calculations were made by using the Cowan code. Data are presented for an electron density of 1017 cm-3 and temperatures T = 1.0-10.0 (104 K). Also we present calculated values of transition probabilities for 30 spectral lines and radiative lifetimes corresponding to its upper levels. These values were analysed using the data found in the literature. Theoretical trends of the Stark broadening parameters versus the temperature for several lines of astrophysical interest are presented.

  11. Reply to "Comment on `Test of the Stark-effect theory using photoionization microscopy' "

    NASA Astrophysics Data System (ADS)

    Zhao, L. B.; Fabrikant, I. I.; Du, M. L.

    2015-06-01

    The frame-transformation (FT) theory which describes the dynamics of nonhydrogenic atoms in an external uniform electric field was tested for the process of photoionization in a Stark field by Zhao et al. [Phys. Rev. A 86, 053413 (2012), 10.1103/PhysRevA.86.053413]. Differential cross sections from the FT theory were found to be inconsistent with those from the fully quantum-mechanical coupled-channel theory. The discrepancy was attributed to the frame transformation of irregular wave functions. In a recent investigation, Giannakeas et al. [Phys. Rev. A 91, 067401 (2015), 10.1103/PhysRevA.91.067401] draw a different conclusion. They show that the FT theory generates irregular wave functions in good agreement with exact solutions for low angular momenta, although an obvious disagreement is seen for high angular momenta. We performed test calculations for numerous Stark states and found that our original conclusion remains valid, namely, the Fano-Harmin frame transformation for the irregular wave function is inaccurate.

  12. The motional Stark effect polarimeter in the HL-2A tokamak.

    PubMed

    Yu, D L; Wei, Y L; Xia, F; Cao, J Y; Chen, C Y; Liu, L; Chen, W J; Ji, X Q; Liu, Y; Yan, L W; Yang, Q W; Duan, X R

    2014-05-01

    A 7-channel motional Stark effect polarimeter based on four polarizers and a spectrometer has been developed in the HL-2A tokamak, which is the first time successful utilizing this kind of polarimeter on a tokamak. The accuracy of the angle can reach ±0.25° in the calibration experiments. Pilot experiments of measuring the magnetic pitch angle have been successfully carried out in the weak motional Stark effect plasma discharge with toroidal magnetic field of ~1.3 T and beam energy of ~25 keV/amu. The pitch angles of magnetic field are obtained for 7 spatial points covering 24 cm along major radius with time resolution of 40 ms; the profiles of safety factor are obtained by combining with the Equilibrium and Reconstruction Fitting Code. The core value of safety factor (q) is less than 1 during the sawtooth oscillation and the position of q = 1 surface is well consistent with the results measured by soft X-ray array.

  13. The motional Stark effect polarimeter in the HL-2A tokamak

    SciTech Connect

    Yu, D. L. Wei, Y. L.; Xia, F.; Cao, J. Y.; Chen, C. Y.; Liu, L.; Chen, W. J.; Ji, X. Q.; Liu, Y.; Yan, L. W.; Yang, Q. W.; Duan, X. R.

    2014-05-15

    A 7-channel motional Stark effect polarimeter based on four polarizers and a spectrometer has been developed in the HL-2A tokamak, which is the first time successful utilizing this kind of polarimeter on a tokamak. The accuracy of the angle can reach ±0.25° in the calibration experiments. Pilot experiments of measuring the magnetic pitch angle have been successfully carried out in the weak motional Stark effect plasma discharge with toroidal magnetic field of ∼1.3 T and beam energy of ∼25 keV/amu. The pitch angles of magnetic field are obtained for 7 spatial points covering 24 cm along major radius with time resolution of 40 ms; the profiles of safety factor are obtained by combining with the Equilibrium and Reconstruction Fitting Code. The core value of safety factor (q) is less than 1 during the sawtooth oscillation and the position of q = 1 surface is well consistent with the results measured by soft X-ray array.

  14. Full-dimensional control of the radiationless decay in pyrazine using the dynamic Stark effect

    SciTech Connect

    Saab, Mohamad Lasorne, Benjamin Gatti, Fabien; Sala, Matthieu; Guérin, Stéphane

    2014-10-07

    We present a full quantum-mechanical study of the laser control of the radiationless decay between the B{sub 3u}(nπ{sup *}) and B{sub 2u}(ππ{sup *}) states of pyrazine using the dynamic Stark effect. In contrast to our previous study [Sala et al., J. Chem. Phys. 140, 194309 (2014)], where a four-dimensional model was used, all the 24 degrees of freedom are now included in order to test the robustness of the strategy of control. Using a vibronic coupling Hamiltonian model in a diabatic representation, the multi-layer version of the multi-configuration time-dependent Hartree method is exploited to propagate the corresponding wave packets. We still observe a trapping of the wavepacket on the B{sub 2u}(ππ{sup *}) potential energy surface due to the Stark effect for a longer time than the “non-resonant field-free” B{sub 2u}(ππ{sup *}) lifetime.

  15. Collective electronic excitations in a semiconductor superlattice in the Landau and Wannier-Stark ladder regime

    NASA Astrophysics Data System (ADS)

    Margulis, Vl. A.; Makarov, S. V.; Piterimova, T. V.; Gaiduk, E. A.

    2003-05-01

    Using a mean-field approximation, we have developed a systematic treatment of collective electronic modes in a semiconductor superlattice (SL) in the presence of strong electric and magnetic fields parallel to the SL axis. The spectrum of collective modes with zero wavevector along the SL axis is shown to consist of a principle magnetoplasmon mode and an infinite set of Bernstein-like modes. For non-zero wavevector along the SL axis, in addition to the cyclotron modes, extra collective modes are found at the frequencies \\vert Nω_c± Mω_s\\vert, which we call cyclotron-Stark modes (ω_c and ω_s are respectively the cyclotron and Stark frequencies, N and M are integer numbers). The frequencies of the modes propagating in “oblique” direction with respect to the SL axis show oscillatory behavior as a function of electric field strength. All the modes considered have very weak spatial dispersion and they are not Landau damped. The specific predictions made for the dispersion relations of the collective excitations should be observable in resonant Raman scattering experiments.

  16. Identification of /sup 233/Ac

    SciTech Connect

    Chu, Y.Y.; Zhou, M.L.

    1983-09-01

    We report in this paper identification of the new isotope /sup 233/Ac. Uranium targets were irradiated with 28 GeV protons; after rapid retrieval of the target and separation of actinium from thorium, /sup 233/Ac was allowed to decay into the known /sup 233/Th daughter. Exhaustive chemical purification was employed to permit the identification of /sup 233/Th via its characteristic ..gamma.. radiations. The half-life derived for /sup 233/Ac from several experiments is 2.3 +- 0.3 min. The production cross section for /sup 233/Ac is 100 ..mu..b.

  17. AC and DC power transmission

    SciTech Connect

    Not Available

    1985-01-01

    The technical and economic assessment of AC and DC transmission systems; long distance transmission, cable transmission, system inter-connection, voltage support, reactive compensation, stabilisation of systems; parallel operation of DC links with AC systems; comparison between alternatives for particular schemes. Design and application equipment: design, testing and application of equipment for HVDC, series and shunt static compensated AC schemes, including associated controls. Installations: overall design of stations and conductor arrangements for HVDC, series and shunt static AC schemes including insulation co-ordination. System analysis and modelling.

  18. The ac propulsion system for an electric vehicle, phase 1

    NASA Technical Reports Server (NTRS)

    Geppert, S.

    1981-01-01

    A functional prototype of an electric vehicle ac propulsion system was built consisting of a 18.65 kW rated ac induction traction motor, pulse width modulated (PWM) transistorized inverter, two speed mechanically shifted automatic transmission, and an overall drive/vehicle controller. Design developmental steps, and test results of individual components and the complex system on an instrumented test frame are described. Computer models were developed for the inverter, motor and a representative vehicle. A preliminary reliability model and failure modes effects analysis are given.

  19. Islam and the "universal" gender difference in religious commitment: a brief report in response to Stark (2002).

    PubMed

    Schumm, Walter R

    2004-06-01

    Stark (2002) demonstrated across 57 nations that men were less likely to report being religiously oriented than were women. He concluded that a physiological difference in risk-taking among younger males might account for disinterest in religion among such males, although he would prefer to explain the gender difference as a consequence of socialization. One socialization hypothesis overlooked by Stark was that Islam as a religion might have been developed, in a small part, as a response to the gender differential observed in earlier religions. Reanalysis of Stark's 2002 data indicates that Islamic nations were more likely to yield smaller gender differences on religious questions, although the effect ranged from p<.06 to a significant p<.005, depending on the method of analysis.

  20. The application of weak electric field pulses to measure the pseudo-Stark split by photon echo beating

    NASA Astrophysics Data System (ADS)

    Lisin, V. N.; Shegeda, A. M.; Samartsev, V. V.

    2016-07-01

    A novel scheme for determining the pseudo-Stark splitting of optical lines has been suggested and tested in experiment. The scheme allows one to observe the beating of a photon echo waveform under conditions of overlap in time between a weak electric pulse and its echo-pulse. The pseudo-Stark splitting is equal to the inverse average modulation period of the echo waveform. The photon echo beating of the R1-line in Ruby has been observed. The dependence of the inverse average modulation period of the echo waveform on the average value of the electric field over the optically excited volume has been found. The obtained values of the pseudo-Stark parameter are in good agreement with known literature data.

  1. Digital ac monitor

    DOEpatents

    Hart, G.W.; Kern, E.C. Jr.

    1987-06-09

    An apparatus and method is provided for monitoring a plurality of analog ac circuits by sampling the voltage and current waveform in each circuit at predetermined intervals, converting the analog current and voltage samples to digital format, storing the digitized current and voltage samples and using the stored digitized current and voltage samples to calculate a variety of electrical parameters; some of which are derived from the stored samples. The non-derived quantities are repeatedly calculated and stored over many separate cycles then averaged. The derived quantities are then calculated at the end of an averaging period. This produces a more accurate reading, especially when averaging over a period in which the power varies over a wide dynamic range. Frequency is measured by timing three cycles of the voltage waveform using the upward zero crossover point as a starting point for a digital timer. 24 figs.

  2. Digital ac monitor

    DOEpatents

    Hart, George W.; Kern, Jr., Edward C.

    1987-06-09

    An apparatus and method is provided for monitoring a plurality of analog ac circuits by sampling the voltage and current waveform in each circuit at predetermined intervals, converting the analog current and voltage samples to digital format, storing the digitized current and voltage samples and using the stored digitized current and voltage samples to calculate a variety of electrical parameters; some of which are derived from the stored samples. The non-derived quantities are repeatedly calculated and stored over many separate cycles then averaged. The derived quantities are then calculated at the end of an averaging period. This produces a more accurate reading, especially when averaging over a period in which the power varies over a wide dynamic range. Frequency is measured by timing three cycles of the voltage waveform using the upward zero crossover point as a starting point for a digital timer.

  3. Cooling Floor AC Systems

    NASA Astrophysics Data System (ADS)

    Jun, Lu; Hao, Ding; Hong, Zhang; Ce, Gao Dian

    The present HVAC equipments for the residential buildings in the Hot-summer-and-Cold-winter climate region are still at a high energy consuming level. So that the high efficiency HVAC system is an urgently need for achieving the preset government energy saving goal. With its advantage of highly sanitary, highly comfortable and uniform of temperature field, the hot-water resource floor radiation heating system has been widely accepted. This paper has put forward a new way in air-conditioning, which combines the fresh-air supply unit and such floor radiation system for the dehumidification and cooling in summer or heating in winter. By analyze its advantages and limitations, we found that this so called Cooling/ Heating Floor AC System can improve the IAQ of residential building while keep high efficiency quality. We also recommend a methodology for the HVAC system designing, which will ensure the reduction of energy cost of users.

  4. Surface acoustic BLOCH oscillations, the Wannier-Stark ladder, and Landau-Zener tunneling in a solid.

    PubMed

    de Lima, M M; Kosevich, Yu A; Santos, P V; Cantarero, A

    2010-04-23

    We present the experimental observation of Bloch oscillations, the Wannier-Stark ladder, and Landau-Zener tunneling of surface acoustic waves in perturbed grating structures on a solid substrate. A model providing a quantitative description of our experimental observations, including multiple Landau-Zener transitions of the anticrossed surface acoustic Wannier-Stark states, is developed. The use of a planar geometry for the realization of the Bloch oscillations and Landau-Zener tunneling allows a direct access to the elastic field distribution. The vertical surface displacement has been measured by interferometry.

  5. Observation of the Stark effect in υ+ = 0 Rydberg states of NO: a comparison between predissociating and bound states

    NASA Astrophysics Data System (ADS)

    Jones, N. J. A.; Minns, R. S.; Patel, R.; Fielding, H. H.

    2008-09-01

    The Stark spectra of Rydberg states of NO below the υ+ = 0 ionization limit, with principal quantum numbers n = 25-30, have been investigated in the presence of dc electric fields in the range 0-150 V cm-1. The Stark states were accessed by two-colour, double-resonance excitation via the υ' = 0, N' = 0 rovibrational state of the A2Σ+ state. The N(2D) atoms produced by predissociation were measured by (2 + 1) resonance-enhanced multiphoton ionization, and compared with pulsed-field ionization spectra of the bound Rydberg state population (Patel et al 2007 J. Phys. B: At. Mol. Opt. Phys. 40 1369).

  6. Generation of Stark spectral components in Nd:YAP and Nd:YAG lasers by using volume Bragg gratings

    SciTech Connect

    Vorob'ev, Nikolai S; Glebov, L B

    2009-01-31

    Generation of Stark spectral components in free-running Q-switched Nd:YAP (1064 nm and 1073 nm) and Nd:YAG (1062 nm) lasers is obtained. For this purpose reflecting volume Bragg gratings placed into the laser resonator and permitting to tune the laser emission spectrum were used. Stable generation of Stark components in both lasers is obtained. The possibility of obtaining two-frequency generation in an Nd-glass laser with the help of these gratings is shown. (control of laser radiation parameters)

  7. Diagnostics of AC excited Atmospheric Pressure Plasma Jet with He for Biomedical Applications

    NASA Astrophysics Data System (ADS)

    Hori, Masaru; Takeda, Keigo; Kumakura, Takumi; Ishikawa, Kenji; Tanaka, Hiromasa; Kondo, Hiroki; Sekine, Makoto; Nakai, Yoshihiro

    2014-10-01

    Atmospheric pressure plasma jets (APPJ) are frequently used for biomedical applications. Reactive species generated by the APPJ play important roles for treatments of biomedical samples. Therefore, high density APPJ sources are required to realize the high performance. Our group has developed AC excited Ar APPJ with electron density as high as 1015 cm-3, and realized the selective killing of cancer cells and the inactivate spores of Penicillium digitatum. Recently, a new spot-size AC excited APPJ with He gas have been developed. In this study, the He APPJ was characterized by using spectroscopy. The plasma was discharged at a He flow rate of 5 slm and a discharge voltage of AC 9 kV. Gas temperature and electron density of the APPJ were measured by optical emission spectroscopy. From theoretical fitting of 2nd positive system of N2 emission (380.4 nm) and Stark broadening of Balmer β line of H atom (486.1 nm), the gas temperature and the electron density was estimated to be 299 K and 3.4. × 1015 cm-3. The AC excited He APPJ has a potential to realize high density with room temperature and become a very powerful tool for biomedical applications.

  8. Gear shift control mechanism

    SciTech Connect

    Janson, D.A.

    1987-03-10

    A gear shift control mechanism is described comprising: multiple shift rods directed substantially parallel to one another, each rod carrying a shift fork for axial movement; a shift lever supported for pivotal movement about a first axis directed parallel to the axes of the shift rods and for pivotal movement about a second axis directed substantially perpendicular to the axes of the shift rods. The lever is moveable about the first axis and the second axis into engagement with a selected shift fork; interlock means located on each lateral side of the shift lever and mounted for pivotal movement about the first axis for blocking engagement with the shift forks; detent means for holding the shift lever in multiple predetermined angular positions about the second axis; and spring means located on a lateral side of the shift lever and mounted for pivotal movement about the first axis into interference contact with the shift forks for producing a force tending to resiliently bias the shift lever out of engagement with the selected shift fork.

  9. Compressive Shift Retrieval

    NASA Astrophysics Data System (ADS)

    Ohlsson, Henrik; Eldar, Yonina C.; Yang, Allen Y.; Sastry, S. Shankar

    2014-08-01

    The classical shift retrieval problem considers two signals in vector form that are related by a shift. The problem is of great importance in many applications and is typically solved by maximizing the cross-correlation between the two signals. Inspired by compressive sensing, in this paper, we seek to estimate the shift directly from compressed signals. We show that under certain conditions, the shift can be recovered using fewer samples and less computation compared to the classical setup. Of particular interest is shift estimation from Fourier coefficients. We show that under rather mild conditions only one Fourier coefficient suffices to recover the true shift.

  10. Definition of Shifts of Optical Transitions Frequencies due to Pulse Perturbation Action by the Photon Echo Signal Form

    NASA Astrophysics Data System (ADS)

    Lisin, V. N.; Shegeda, A. M.; Samartsev, V. V.

    2015-09-01

    A relative phase shift between the different groups of excited dipoles, which appears as result of its frequency splitting due to action of a pulse of electric or magnetic fields, depends on a time, if the pulse overlaps in time with echo-pulse. As а consequence, the echo waveform is changed. The echo time form is modulated. The inverse modulation period well enough approximates Zeeman and pseudo-Stark splitting in the cases of magnetic and, therefore, electrical fields. Thus the g-factors of ground 4I15/2 and excited 4F9/2 optical states of Er3+ ion in LuLiF4 and YLiF4 have been measured and pseudo-Stark shift of R1 line in ruby has been determined.

  11. Nanometer-scale monitoring of quantum-confined Stark effect and emission efficiency droop in multiple GaN/AlN quantum disks in nanowires

    NASA Astrophysics Data System (ADS)

    Zagonel, L. F.; Tizei, L. H. G.; Vitiello, G. Z.; Jacopin, G.; Rigutti, L.; Tchernycheva, M.; Julien, F. H.; Songmuang, R.; Ostasevicius, T.; de la Peña, F.; Ducati, C.; Midgley, P. A.; Kociak, M.

    2016-05-01

    We report on a detailed study of the intensity dependent optical properties of individual GaN/AlN quantum disks (QDisks) embedded into GaN nanowires (NW). The structural and optical properties of the QDisks were probed by high spatial resolution cathodoluminescence (CL) in a scanning transmission electron microscope (STEM). By exciting the QDisks with a nanometric electron beam at currents spanning over three orders of magnitude, strong nonlinearities (energy shifts) in the light emission are observed. In particular, we find that the amount of energy shift depends on the emission rate and on the QDisk morphology (size, position along the NW and shell thickness). For thick QDisks (>4 nm), the QDisk emission energy is observed to blueshift with the increase of the emission intensity. This is interpreted as a consequence of the increase of carriers density excited by the incident electron beam inside the QDisks, which screens the internal electric field and thus reduces the quantum confined Stark effect (QCSE) present in these QDisks. For thinner QDisks (<3 nm ), the blueshift is almost absent in agreement with the negligible QCSE at such sizes. For QDisks of intermediate sizes there exists a current threshold above which the energy shifts, marking the transition from unscreened to partially screened QCSE. From the threshold value we estimate the lifetime in the unscreened regime. These observations suggest that, counterintuitively, electrons of high energy can behave ultimately as single electron-hole pair generators. In addition, when we increase the current from 1 to 10 pA the light emission efficiency drops by more than one order of magnitude. This reduction of the emission efficiency is a manifestation of the "efficiency droop" as observed in nitride-based 2D light emitting diodes, a phenomenon tentatively attributed to the Auger effect.

  12. Status of motional Stark effect and Zeeman effect diagnostics for KSTAR

    NASA Astrophysics Data System (ADS)

    Ko, Jinseok; Chung, Jinil; de Bock, Maarten; KSTAR Team

    2014-10-01

    The motional Stark effect (MSE) diagnostic system is under development aiming at commissioning in 2015. The design and fabrication of the polarization preserving front optics has been complete, including the multi-layer dielectric coated mirror and beam splitter, the latter being required to split the incident light into that above 600 nm for MSE and that below 600 nm for the Charge Exchange Spectroscopy (CES) that shares the front optics with MSE. The bandpass filters with a sharp transmission function and a minimum distortion against tilting have been procured. Both the analog lock-in and the post-processing numerical Fourier transform will be exploited. The Li-beam based Zeeman effect (ZE) diagnostic system is under conceptual design. Its details on the design are introduced in this work including the radial resolution and sensitivity to the change of the magnetic field pitch near the pedestal region. Work supported by the Ministry of Science, ICT and Future Planning, Korea.

  13. Stark spectroscopy of CuPc organic semiconductor with a submicron metal-electrode grating

    NASA Astrophysics Data System (ADS)

    Blinov, L. M.; Lazarev, V. V.; Yudin, S. G.; Palto, S. P.

    2016-02-01

    The optical and electro-optical properties of organic copper phthalocyanine semiconductor (α- CuPc) have been investigated by Stark (electroabsorption) spectroscopy using a metal electrode grating with a submicron (0.88 μm) interelectrode distance. Differences between dipole moments (Δμ) and polarizabilities (Δα) in the excited and ground states of α-CuPc are measured for a nanoscale semiconductor film. It is concluded that the extremely high values of Δμ and Δα are in principle not parameters of individual α-CuPc molecules: they are determined by exciton effects specifically in the polycrystalline medium with a characteristic morphology of hyperfine films, which depends on the structure of the samples and their fabrication technology.

  14. First mirror contamination studies for polarimetry motional Stark effect measurements for ITER

    SciTech Connect

    Kuldkepp, M.; Rachlew, E.; Hawkes, N.C.; Schunke, B.

    2004-10-01

    The motional Stark effect (MSE) diagnostic on the International Thermonuclear Experimental Reactor will need to guide the light through a labyrinth of mirrors to provide neutron shielding. Knowledge of how the mirrors change the polarization is essential for accurate determination of the q profile. The optical properties of the plasma facing mirror are also expected to change with time due to deposition/erosion. For the purpose of examining this experimentally a detector system, identical to the JET MSE system, using twin photoelastic modulators was constructed. Measurements have been performed on freshly prepared mirrors, on mirrors after exposure to plasmas in Tore Supra, and labyrinth designs. The result shows a significant effect on the optical properties and demonstrate the need for in situ monitoring. The measured properties of the labyrinth closely follow the Mueller matrix formalism. With a correct choice of material the angle change introduced by the four mirrors furthest away from the plasma will be below 1 deg.

  15. Plasma density characterization at SPARC_LAB through Stark broadening of Hydrogen spectral lines

    NASA Astrophysics Data System (ADS)

    Filippi, F.; Anania, M. P.; Bellaveglia, M.; Biagioni, A.; Chiadroni, E.; Cianchi, A.; Di Giovenale, D.; Di Pirro, G.; Ferrario, M.; Mostacci, A.; Palumbo, L.; Pompili, R.; Shpakov, V.; Vaccarezza, C.; Villa, F.; Zigler, A.

    2016-09-01

    Plasma-based acceleration techniques are of great interest for future, compact accelerators due to their high accelerating gradient. Both particle-driven and laser-driven Plasma Wakefield Acceleration experiments are foreseen at the SPARC_LAB Test Facility (INFN National Laboratories of Frascati, Italy), with the aim to accelerate high-brightness electron beams. In order to optimize the efficiency of the acceleration in the plasma and preserve the quality of the accelerated beam, the knowledge of the plasma electron density is mandatory. The Stark broadening of the Hydrogen spectral lines is one of the candidates used to characterize plasma density. The implementation of this diagnostic for plasma-based experiments at SPARC_LAB is presented.

  16. A switched ring Stark decelerator for both light and heavy polar molecules

    NASA Astrophysics Data System (ADS)

    Hou, Shunyong; Wang, Qin; Deng, Lianzhong; Yin, Jianping

    2016-03-01

    There is increasing interest in cold heavy polar molecular species for their applications in fundamental physics, such as the tests of the electron’s electric dipole moment. Here we propose a switched ring Stark decelerator suitable for slowing both light and heavy polar molecules. Two typical polar molecular species, ND3 and 205TlF, are employed to test the feasibility of our scheme with the help of trajectory calculation. Our proposed scheme is found to share many advantages with the state-of-the-art traveling wave decelerator, yet with relatively simple electronics and flexible operation modes. Sub-millikelvin molecular samples can be conveniently obtained in our decelerator using a combined operation mode. These monochromatic beams are ideal starting points for precise studies of molecular collision, cold chemistry and high-resolution spectroscopy.

  17. Single Molecule Quantum-Confined Stark Effect Measurements of Semiconductor Nanoparticles at Room Temperature

    PubMed Central

    2012-01-01

    We measured the quantum-confined Stark effect (QCSE) of several types of fluorescent colloidal semiconductor quantum dots and nanorods at the single molecule level at room temperature. These measurements demonstrate the possible utility of these nanoparticles for local electric field (voltage) sensing on the nanoscale. Here we show that charge separation across one (or more) heterostructure interface(s) with type-II band alignment (and the associated induced dipole) is crucial for an enhanced QCSE. To further gain insight into the experimental results, we numerically solved the Schrödinger and Poisson equations under self-consistent field approximation, including dielectric inhomogeneities. Both calculations and experiments suggest that the degree of initial charge separation (and the associated exciton binding energy) determines the magnitude of the QCSE in these structures. PMID:23075136

  18. Communication: Induced photoemission from nonadiabatic dynamics assisted by dynamical Stark effect.

    PubMed

    Arasaki, Yasuki; Scheit, Simona; Takatsuka, Kazuo

    2013-04-28

    Through nonadiabatic interaction due to electron transfer as that in alkali halides, vibrational dynamics on the ionic potential energy surface (large dipole moment) is coupled to that on the covalent surface (small dipole moment). Thus, population transfer between the states should cause long-range electron jump between two remote sites, which thereby leads to a sudden change of the large molecular dipole moment. Therefore, by making repeated use of the dynamical Stark effect, one may expect emission of photons from it. We show with coupled quantum wavepacket dynamics calculation that such photoemission can indeed occur and can be controlled by an external field. The present photoemission can offer an alternative scheme to study femtosecond and subfemtosecond vibrational and electronic dynamics and may serve as a unique optical source. PMID:23635103

  19. A simple formula for estimating Stark widths of neutral lines. [of stellar atmospheres

    NASA Technical Reports Server (NTRS)

    Freudenstein, S. A.; Cooper, J.

    1978-01-01

    A simple formula for the prediction of Stark widths of neutral lines similar to the semiempirical method of Griem (1968) for ion lines is presented. This formula is a simplification of the quantum-mechanical classical path impact theory and can be used for complicated atoms for which detailed calculations are not readily available, provided that the effective position of the closest interacting level is known. The expression does not require the use of a computer. The formula has been applied to a limited number of neutral lines of interest, and the width obtained is compared with the much more complete calculations of Bennett and Griem (1971). The agreement generally is well within 50% of the published value for the lines investigated. Comparisons with other formulas are also made. In addition, a simple estimate for the ion-broadening parameter is given.

  20. Computation of the Stark effect in P impurity states in silicon

    NASA Astrophysics Data System (ADS)

    Debernardi, A.; Baldereschi, A.; Fanciulli, M.

    2006-07-01

    We compute within the effective-mass theory and without adjustable parameters the Stark effect for shallow P donors in Si with anisotropic band structure. Valley-orbit coupling is taken into account in a nonperturbative way and scattering effects of the impurity core are included to properly describe low-lying impurity states. The ground-state energy slightly decreases with increasing electric field up to a critical value Ecr˜25keV/cm , at which the donor can be ionized by tunneling due to a field-induced mixing of the “ 1s -like” singlet ground state with a “ 2p0 -like” excited state in zero field. The resulting ground-state wave function at high field extends significantly outside the potential barrier surrounding the impurity. Calculations of the hyperfine splitting and of the A -shell superhyperfine coupling constants as a function of the electric field complete the work.

  1. The trouble with orbits: The Stark effect in the old and the new quantum theory

    NASA Astrophysics Data System (ADS)

    Duncan, Anthony; Janssen, Michel

    2014-11-01

    The old quantum theory and Schrödinger's wave mechanics (and other forms of quantum mechanics) give the same results for the line splittings in the first-order Stark effect in hydrogen, the leading terms in the splitting of the spectral lines emitted by a hydrogen atom in an external electric field. We examine the account of the effect in the old quantum theory, which was hailed as a major success of that theory, from the point of view of wave mechanics. First, we show how the new quantum mechanics solves a fundamental problem that one runs into in the old quantum theory with the Stark effect. It turns out that, even without an external field, it depends on the coordinates in which the quantum conditions are imposed which electron orbits are allowed in a hydrogen atom. The allowed energy levels and hence the line splittings are independent of the coordinates used but the size and eccentricity of the orbits are not. In the new quantum theory, this worrisome non-uniqueness of orbits turns into the perfectly innocuous non-uniqueness of bases in Hilbert space. Second, we review how the so-called WKB (Wentzel-Kramers-Brillouin) approximation method for solving the Schrödinger equation reproduces the quantum conditions of the old quantum theory amended by some additional half-integer terms. These extra terms remove the need for some arbitrary extra restrictions on the allowed orbits that the old quantum theory required over and above the basic quantum conditions.

  2. Operation Method for AC Motor Control during Power Interruption in Direct AC/AC Converter System

    NASA Astrophysics Data System (ADS)

    Shizu, Keiichiro; Azuma, Satoshi

    Direct AC/AC converters have been studied due to their potential use in power converters with no DC-link capacitor, which can contribute to the miniaturization of power converters. However, the absence of a DC-link capacitor makes it difficult to control the AC motor during power interruption. First, this paper proposes a system that realizes AC motor control during power interruption by utilizing a clamp capacitor. In general, direct AC/AC converters have a clamp circuit consisting of a rectifier diode(s) and a clamp capacitor in order to avoid over-voltages. In the proposed system, there is an additional semiconductor switch reverse-parallel to the rectifier diode(s), and the clamp capacitor voltage can be utilized for AC motor control by turning on the additional switch. Second, this paper discusses an operation method for AC motor control and clamp capacitor voltage control during power interruption. In the proposed method “DC-link voltage control”, the kinetic energy in the AC motor is transformed into electrical energy and stored in the clamp capacitor; the clamp capacitor is therefore charged and the capacitor voltage is controlled to remain constant at an instruction value. Third, this paper discusses a switching operation during power interruption. A dead-time is introduced between the operation of turning off all switches on the rectifier side and the operation of turning on the additional switch, which prevents the occurrence of a short circuit between the interrupted power source and the clamp capacitor. Finally, experimental results are presented. During power interruptions, an output current was continuously obtained and the clamp capacitor voltage was maintained to be equal to the instruction value of the capacitor voltage. These results indicate that both AC motor control and capacitor voltage control were successfully achieved by using the proposed system.

  3. Reaching for 80%: How Post Secondary Opportunities in High Schools Are Changing the College Going Culture in Stark County, Ohio

    ERIC Educational Resources Information Center

    Rochford, Joseph A.; O'Neill, Adrienne; Gelb, Adele; Ross, Kimberly J.

    2011-01-01

    In 2002, the Stark County Preschool through College (P-16) Compact set the goal of achieving an 80% college going rate. Such a goal seemed both audacious and daunting for a community where in 2001 only 17.9% of the adults held a Bachelor's Degree, or higher, and where only 49% of all high school graduates went directly to college. Nine years have…

  4. Expanding College Opportunity: An Annual Report on Dual Credit and Other Post Secondary Opportunities for Stark County High School Students

    ERIC Educational Resources Information Center

    Rochford, Joseph A.; O'Neill, Adrienne; Gelb, Adele; Ross, Kimberly J.; Ughrin, Tina

    2014-01-01

    This is the eighth annual report by the Stark Education Partnership on dual enrollment and other post secondary opportunities (PSOs) for the county's high school students. In addition to dual enrollment, this report looks at a portfolio of the county's PSOs that includes Canton Early College High School, and the opportunity to bank future college…

  5. ACS CCD Stability Monitor

    NASA Astrophysics Data System (ADS)

    Grogin, Norman

    2012-10-01

    A moderately crowded stellar field in the cluster 47 Tuc {6 arcmin West of the cluster core} is observed every four months with the WFC. The first visit exercises the full suite of broad and narrow band imaging filters and sub-array modes; following visits observe with only the six most popular Cycle 18 filters in full-frame mode. The positions and magnitudes of objects will be used to monitor local and large scale variations in the plate scale and the sensitivity of the detectors and to derive an independent measure of the detector CTE. One exposure in each sub-array mode with the WFC will allow us to verify that photometry obtained in full-frame and in sub-array modes are repeatable to better than 1%. This test is important for the ACS Photometric Cross-Calibration program, which uses sub-array exposures. This program may receive additional orbits to investigate ORIENT-dependent geometric distortion, which motivates the ORIENT and BETWEEN requirement on the first visit.

  6. Sustainable AC/AC hybrid electrochemical capacitors in aqueous electrolyte approaching the performance of organic systems

    NASA Astrophysics Data System (ADS)

    Abbas, Qamar; Babuchowska, Paulina; Frąckowiak, Elżbieta; Béguin, François

    2016-09-01

    A high energy hybrid AC/AC electrochemical capacitor has been realized in aqueous Li2SO4+KI electrolyte mixture. Owing to the redox processes associated with the 2I-/I2 system, the positive electrode operates in narrow potential range and displays high capacity. During prolonged potentiostatic floating at 1.6 V, the hybrid cell demonstrates remarkably stable capacitance and resistance. Analyses by temperature programmed desorption after floating at 1.6 V proved that oxidation of the positive AC electrode is prevented by the use of Li2SO4+KI, which enables the maximum potential of this electrode to be shifted below the water oxidation potential. When charged at 0.2 A g-1 up to U = 1.6 V, the hybrid cell displays a high capacitance of 75 F g-1 (300 F g-1 per mass of one electrode) compared to 47 F g-1 (188 F g-1 per mass of one electrode) for a symmetric cell in Li2SO4. At 0.2 A g-1 up to 1.6 V, the hybrid capacitor in Li2SO4+KI displays an energy density of 26 Wh kg-1 which approaches the energy density of 30.9 Wh kg-1 measured when the same carbon is implemented in a capacitor using TEABF4/ACN electrolyte and charged up to 2.5 V.

  7. AC photovoltaic module magnetic fields

    SciTech Connect

    Jennings, C.; Chang, G.J.; Reyes, A.B.; Whitaker, C.M.

    1997-12-31

    Implementation of alternating current (AC) photovoltaic (PV) modules, particularly for distributed applications such as PV rooftops and facades, may be slowed by public concern about electric and magnetic fields (EMF). This paper documents magnetic field measurements on an AC PV module, complementing EMF research on direct-current PV modules conducted by PG and E in 1993. Although not comprehensive, the PV EMF data indicate that 60 Hz magnetic fields (the EMF type of greatest public concern) from PV modules are comparable to, or significantly less than, those from household appliances. Given the present EMF research knowledge, AC PV module EMF may not merit considerable concern.

  8. Silicon based light emitters utilizing radiation from dislocations; electric field induced shift of the dislocation-related luminescence

    NASA Astrophysics Data System (ADS)

    Arguirov, T.; Mchedlidze, T.; Kittler, M.; Reiche, M.; Wilhelm, T.; Hoang, T.; Holleman, J.; Schmitz, J.

    2009-05-01

    Dislocation rich regions can be controllably formed at a certain location inside a silicon wafer. We studied the light emission properties of such regions located in an electric field of a p-n junction under different excitation conditions. It was found that the luminescence spectra of the dislocations are significantly influenced by the presence of the junction. The dislocation-related luminescence peak position appears red-shifted due to the built-in electric field. A suppression of that field by photo-generation of carriers or by applying a forward bias voltage at the junction leads to a gradual decrease in the energy position of the peaks. The dependence of the peak position on the electric field was found to be a quadratic function, similar to that observed for semiconductor nanostructures. We show that the shift of the peak position is due to the Stark effect on dislocation-related excitonic states. The characteristic constant of the shift, obtained by fitting the data with the quadratic Stark effect equation, was 0.0186 meV/(kV/cm) 2. The observed effect opens new possibilities for integration of a silicon based light emitter, combining the radiation from dislocations with a Stark effect based modulator.

  9. A study of protein-carotenoid interactions in the astaxanthin-protein crustacyanin by absorption and Stark spectroscopy; evidence for the presence of three spectrally distinct species.

    PubMed

    Krawczyk, S; Britton, G

    2001-01-12

    Molecular mechanisms underlying the peculiar spectral properties of the carotenoid astaxanthin in alpha-crustacyanin, the blue carotenoprotein isolated from the exoskeleton of the lobster Homarus gammarus, were investigated by comparing the basic electrooptical parameters of astaxanthin free in vitro with those of astaxanthin in the complex. Absorption and electroabsorption (Stark effect) spectra were obtained for alpha-crustacyanin in low-temperature glasses to provide information about the molecular interactions that lead to the large bathochromic shift of the spectra resulting from this complexation. The low-temperature spectra reveal the presence of at least three spectral forms of alpha-crustacyanin, with vibronic (0-0) transitions at 14000 cm(-1), 13500 cm(-1) and 11600 cm(-1) (corresponding to approximately 630, 660 and 780 nm, respectively, at room temperature) and with relative aboundance 85%, 10% and 5%. The longer wavelength absorbing species have not previously been detected. The changes in polarizability and in permanent dipole moments associated with the S0-->S2 electronic transition for all these forms are about 1.5 times larger than for isolated astaxanthin. The results are discussed with reference to the symmetric polarization model for astaxanthin in alpha-crustacyanin. PMID:11341939

  10. Observation of an optical Stark effect on vibrational and rotational transitions

    SciTech Connect

    Rahn, L.A.; Farrow, R.L.; Koszykowski, M.L.; Mattern, P.L.

    1980-08-25

    Vibrational and rotational Raman transitions are shown to be shifted to lower frequencies in the presence of a nonresonant, high-intensity optical field. Experimental results using coherent anti-Stokes Raman spectroscopy for hydrogen and nitrogen are presented. The magnitude of the observed shift is in agreement with a calculation which considers the coupling of the optical field to the internuclear separation via the molecular electronic polarizability. The magnitude of the shift is predicted to be proportional to the optical field intensity.

  11. Chemical shifts in biomolecules

    PubMed Central

    Case, David A.

    2013-01-01

    Summary NMR chemical shifts are sensitive probes of stucture and dynamics in proteins. Empirical models, based on a large database of measured shifts, take an input structure and provide increasingly accurate estimates of the corresponding shifts. Quantum chemical calculations can provide the same information, with greater generality but (currently) with less accuracy. These methods are now providing new ways to approach NMR structure determination, and new insights into the conformational dynamics of proteins. PMID:23422068

  12. Two-step phase-shifting SPIDER

    NASA Astrophysics Data System (ADS)

    Zheng, Shuiqin; Cai, Yi; Pan, Xinjian; Zeng, Xuanke; Li, Jingzhen; Li, Ying; Zhu, Tianlong; Lin, Qinggang; Xu, Shixiang

    2016-09-01

    Comprehensive characterization of ultrafast optical field is critical for ultrashort pulse generation and its application. This paper combines two-step phase-shifting (TSPS) into the spectral phase interferometry for direct electric-field reconstruction (SPIDER) to improve the reconstruction of ultrafast optical-fields. This novel SPIDER can remove experimentally the dc portion occurring in traditional SPIDER method by recording two spectral interferograms with π phase-shifting. As a result, the reconstructed results are much less disturbed by the time delay between the test pulse replicas and the temporal widths of the filter window, thus more reliable. What is more, this SPIDER can work efficiently even the time delay is so small or the measured bandwidth is so narrow that strong overlap happens between the dc and ac portions, which allows it to be able to characterize the test pulses with complicated temporal/spectral structures or narrow bandwidths.

  13. Two-step phase-shifting SPIDER

    PubMed Central

    Zheng, Shuiqin; Cai, Yi; Pan, Xinjian; Zeng, Xuanke; Li, Jingzhen; Li, Ying; Zhu, Tianlong; Lin, Qinggang; Xu, Shixiang

    2016-01-01

    Comprehensive characterization of ultrafast optical field is critical for ultrashort pulse generation and its application. This paper combines two-step phase-shifting (TSPS) into the spectral phase interferometry for direct electric-field reconstruction (SPIDER) to improve the reconstruction of ultrafast optical-fields. This novel SPIDER can remove experimentally the dc portion occurring in traditional SPIDER method by recording two spectral interferograms with π phase-shifting. As a result, the reconstructed results are much less disturbed by the time delay between the test pulse replicas and the temporal widths of the filter window, thus more reliable. What is more, this SPIDER can work efficiently even the time delay is so small or the measured bandwidth is so narrow that strong overlap happens between the dc and ac portions, which allows it to be able to characterize the test pulses with complicated temporal/spectral structures or narrow bandwidths. PMID:27666528

  14. Electron Stark Broadening Database for Atomic N, O, and C Lines

    NASA Technical Reports Server (NTRS)

    Liu, Yen; Yao, Winifred M.; Wray, Alan A.; Carbon, Duane F.

    2012-01-01

    A database for efficiently computing the electron Stark broadening line widths for atomic N, O, and C lines is constructed. The line width is expressed in terms of the electron number density and electronatom scattering cross sections based on the Baranger impact theory. The state-to-state cross sections are computed using the semiclassical approximation, in which the atom is treated quantum mechanically whereas the motion of the free electron follows a classical trajectory. These state-to-state cross sections are calculated based on newly compiled line lists. Each atomic line list consists of a careful merger of NIST, Vanderbilt, and TOPbase line datasets from wavelength 50 nm to 50 micrometers covering the VUV to IR spectral regions. There are over 10,000 lines in each atomic line list. The widths for each line are computed at 13 electron temperatures between 1,000 K 50,000 K. A linear least squares method using a four-term fractional power series is then employed to obtain an analytical fit for each line-width variation as a function of the electron temperature. The maximum L2 error of the analytic fits for all lines in our line lists is about 5%.

  15. Comment on "Test of the Stark-effect theory using photoionization microscopy"

    NASA Astrophysics Data System (ADS)

    Giannakeas, P.; Robicheaux, F.; Greene, Chris H.

    2015-06-01

    An article by Zhao et al. [Phys. Rev. A 86, 053413 (2012), 10.1103/PhysRevA.86.053413] tests the local frame transformation (LFT) theory by comparing it with benchmark coupled-channel calculations. The system under consideration is an alkali-metal atom that is two-photon ionized in the presence of a static external electric field. Zhao et al. state that the differential cross sections computed in the LFT theory disagree with their supposedly more accurate coupled-channel calculations. They went on to diagnose the discrepancy and claimed that it originates in an inaccurate correspondence between the irregular functions in spherical and parabolic-cylindrical coordinates, a correspondence that lies at the heart of LFT theory. We have repeated the same tests and find that our calculations rule out the discrepancies that were claimed in Zhao et al. [Phys. Rev. A 86, 053413 (2012), 10.1103/PhysRevA.86.053413] to exist between the LFT approximation and the exact calculations. This Comment thus helps to clarify the accuracy of the Harmin-Fano theory and demonstrates that it is in fact remarkably accurate not only for the total photoionization cross section in the Stark effect, but also for the differential cross section in photoionization microscopy.

  16. Design of a New Optical System for Alcator C-Mod Motional Stark Effect Diagnostic

    SciTech Connect

    Ko, Jinseok; Scott, Steve; Manfred, Bitter; Lerner, Lerner

    2009-11-12

    The motional Stark effect (MSE) diagnostic on Alcator C-Mod uses an in-vessel optical system (five lenses and three mirrors) to relay polarized light to an external polarimeter because port access limitations on Alcator C-Mod preclude a direct view of the diagnostic beam. The system experiences unacceptable, spurious drifts of order several degrees in measured pitch angle over the course of a run day. Recent experiments illuminated the MSE diagnostic with polarized light of fixed orientation as heat was applied to various optical elements. A large change in measured angle was observed as two particular lenses were heated, indicating that thermal-stress-induced birefringence is a likely cause of the spurious variability. Several new optical designs have been evaluated to eliminate the affected in-vessel lenses and to replace the focusing they provide with curved mirrors; however, ray tracing calculations imply that this method is not feasible. A new approach is under consideration that utilizes in situ calibrations with in-vessel reference polarized light sources. 2008 American Institute of Physics.

  17. Excited electronic state mixing in 7-azaindole. Quantitative measurements using the Stark effect.

    PubMed

    Young, Justin W; Pozun, Zachary D; Jordan, Kenneth D; Pratt, David W

    2013-12-12

    Stark effect measurements of the +280 cm(-1) vibronic band at ∼286 nm in the high resolution S1-S0 fluorescence excitation spectrum of 7-azaindole (7AI) in a molecular beam show that the permanent (electric) dipole moment (PDM) of the upper state vibrational level reached in this transition is 4.6 D, twice as large as the PDM of the zero-point level of the S1 state. This large difference is attributed to state mixing with a more polar state. EOM-CSSD calculations suggest that this more polar state is σπ* in nature and that it crosses the ππ* state in energy along the coordinate connecting the two potential energy minima. Such state mixing apparently provides more facile access to conical intersections with the ground state, and subsequent hydrogen atom detachment reactions, since independent studies by Sakota and Sekiya have shown that the N-H stretching frequency of 7AI is significantly reduced when it is excited to the +280 cm(-1) vibrational level of the S1 state.

  18. Note: Spectral motional Stark effect diagnostic for measurement of magnetic fields below 0.3 T

    NASA Astrophysics Data System (ADS)

    Lizunov, A.; Donin, A.; Savkin, V.

    2013-08-01

    The paper reports on development of the spectral motional Stark effect (MSE) diagnostic in the midplane of the gas dynamic trap (GDT) linear system for magnetic confinement of anisotropic hot-ion plasma. The axially symmetric GDT vacuum magnetic field has a minimum value in the midplane, which varies from 0.2 to 0.35 T in different regimes of operation. Buildup of 15 keV ion population generates a diamagnetic reduction of magnetic field in the plasma core of up to 30% in the maximum density region, as measured by the existing eight-line MSE diagnostic. Commissioning of the midplane MSE provided first direct measurements of diamagnetic modifications in the minimum magnetic field GDT section, a necessary complement to the understanding of equilibrium and self-organization of high-β plasmas in GDT. Making use of the stable short-pulse diagnostic beam and calibration of the apparent spectral width of beam emission lines allow for the measurement of the plasma magnetic field of 0.29 ± 0.007 T with the integration time of 200 μs.

  19. Robotic calibration of the motional Stark effect diagnostic on Alcator C-Mod.

    PubMed

    Mumgaard, Robert T; Scott, Steven D; Ko, Jinseok

    2014-05-01

    The capability to calibrate diagnostics, such as the Motional Stark Effect (MSE) diagnostic, without using plasma or beam-into-gas discharges will become increasingly important on next step fusion facilities due to machine availability and operational constraints. A robotic calibration system consisting of a motorized three-axis positioning system and a polarization light source capable of generating arbitrary polarization states with a linear polarization angle accuracy of <0.05° has been constructed and has been used to calibrate the MSE diagnostic deployed on Alcator C-Mod. The polarization response of the complex diagnostic is shown to be fully captured using a Fourier expansion of the detector signals in terms of even harmonics of the input polarization angle. The system's high precision robotic control of position and orientation allow it to be used also to calibrate the geometry of the instrument's view. Combined with careful measurements of the narrow bandpass spectral filters, this system fully calibrates the diagnostic without any plasma discharges. The system's high repeatability, flexibility, and speed has been exploited to quantify several systematics in the MSE diagnostic response, providing a more complete understanding of the diagnostic performance.

  20. Robotic calibration of the motional Stark effect diagnostic on Alcator C-Mod

    NASA Astrophysics Data System (ADS)

    Mumgaard, Robert T.; Scott, Steven D.; Ko, Jinseok

    2014-05-01

    The capability to calibrate diagnostics, such as the Motional Stark Effect (MSE) diagnostic, without using plasma or beam-into-gas discharges will become increasingly important on next step fusion facilities due to machine availability and operational constraints. A robotic calibration system consisting of a motorized three-axis positioning system and a polarization light source capable of generating arbitrary polarization states with a linear polarization angle accuracy of <0.05° has been constructed and has been used to calibrate the MSE diagnostic deployed on Alcator C-Mod. The polarization response of the complex diagnostic is shown to be fully captured using a Fourier expansion of the detector signals in terms of even harmonics of the input polarization angle. The system's high precision robotic control of position and orientation allow it to be used also to calibrate the geometry of the instrument's view. Combined with careful measurements of the narrow bandpass spectral filters, this system fully calibrates the diagnostic without any plasma discharges. The system's high repeatability, flexibility, and speed has been exploited to quantify several systematics in the MSE diagnostic response, providing a more complete understanding of the diagnostic performance.

  1. Robotic calibration of the motional Stark effect diagnostic on Alcator C-Mod

    SciTech Connect

    Mumgaard, Robert T.; Scott, Steven D.; Ko, Jinseok

    2014-05-15

    The capability to calibrate diagnostics, such as the Motional Stark Effect (MSE) diagnostic, without using plasma or beam-into-gas discharges will become increasingly important on next step fusion facilities due to machine availability and operational constraints. A robotic calibration system consisting of a motorized three-axis positioning system and a polarization light source capable of generating arbitrary polarization states with a linear polarization angle accuracy of <0.05° has been constructed and has been used to calibrate the MSE diagnostic deployed on Alcator C-Mod. The polarization response of the complex diagnostic is shown to be fully captured using a Fourier expansion of the detector signals in terms of even harmonics of the input polarization angle. The system's high precision robotic control of position and orientation allow it to be used also to calibrate the geometry of the instrument's view. Combined with careful measurements of the narrow bandpass spectral filters, this system fully calibrates the diagnostic without any plasma discharges. The system's high repeatability, flexibility, and speed has been exploited to quantify several systematics in the MSE diagnostic response, providing a more complete understanding of the diagnostic performance.

  2. Magnetohydrodynamic interference with the edge pedestal motional Stark effect diagnostic on DIII-D.

    PubMed

    King, J D; Makowski, M A; Holcomb, C T; Allen, S L; Hill, D N; La Haye, R J; Turco, F; Petty, C C; Van Zeeland, M A; Rhodes, T L; Meyer, W H; Geer, R; Morse, E C

    2011-03-01

    Accurate measurement of internal magnetic field direction using motional Stark effect (MSE) polarimetry in the edge pedestal is desired for nearly all tokamak scenario work. A newly installed 500 kHz 32-channel digitizer on the MSE diagnostic of DIII-D allows full spectral information of the polarimeter signal to be recovered for the first time. Fourier analysis of this data has revealed magnetohydrodynamic (MHD) fluctuations in the plasma edge pedestal at ρ ≥ 0.92. By correlating edge localized mode fluctuations seen on lock-in amplifier outputs with MSE spectrograms, it has been shown that edge pedestal tearing mode fluctuations cause interference with MSE second harmonic instrument frequencies. This interference results in unrecoverable errors in the real-time polarization angle measurement that are more than an order of magnitude larger than typical polarimeter uncertainties. These errors can cause as much as a 38% difference in local q. By using a redundant measure of the linear polarization found at the fourth harmonic photo-elastic modulator (PEM) frequency, MHD interference can be avoided. However, because of poorer signal-to-noise the fourth harmonic signal computed polarization angle shows no improvement over the MHD polluted second harmonics. MHD interference could be avoided in future edge pedestal tokamak polarimeters by utilizing PEMs with higher fundamental frequencies and a greater separation between their frequencies.

  3. State-to-state inelastic scattering of Stark-decelerated OH radicals with Ar atoms.

    PubMed

    Scharfenberg, Ludwig; Kłos, Jacek; Dagdigian, Paul J; Alexander, Millard H; Meijer, Gerard; van de Meerakker, Sebastiaan Y T

    2010-09-28

    The Stark deceleration method exploits the concepts of charged particle accelerator physics to produce molecular beams with a tunable velocity. These tamed molecular beams offer interesting perspectives for precise crossed beam scattering studies as a function of the collision energy. The method has advanced sufficiently to compete with state-of-the-art beam methods that are used for scattering studies throughout. This is demonstrated here for the scattering of OH radicals (X(2)Pi(3/2), J = 3/2, f) with Ar atoms, a benchmark system for the scattering of open-shell molecules with atoms. Parity-resolved integral state-to-state inelastic scattering cross sections are measured at collision energies between 80 and 800 cm(-1). The threshold behavior and collision energy dependence of 13 inelastic scattering channels is accurately determined. Excellent agreement is obtained with the cross sections predicted by close-coupling scattering calculations based on the most accurate ab initio OH + Ar potential energy surfaces to date. PMID:20657906

  4. Stark sexual display divergence among jumping spider populations in the face of gene flow.

    PubMed

    Blackburn, Gwylim S; Maddison, Wayne P

    2014-11-01

    Gene flow can inhibit evolutionary divergence by eroding genetic differences between populations. A current aim in speciation research is to identify conditions in which selection overcomes this process. We focused on a state of limited differentiation, asking whether selection enables divergence with gene flow in a set of Habronattus americanus jumping spider populations that exhibit three distinct male sexual display morphs. We found that each population is at high frequency or fixed for a single morph. These strong phenotypic differences contrast with low divergence at 210 AFLP markers, suggesting selection has driven or maintains morph divergence. Coinciding patterns of isolation by distance and 'isolation by phenotype' (i.e. increased genetic divergence among phenotypically contrasting populations) across the study area support several alternative demographic hypotheses for display divergence, each of which entails gene flow. Display-associated structure appears broadly distributed across the genome and the markers producing this pattern do not stand out from background levels of differentiation. Overall, the results suggest selection can promote stark sexual display divergence in the face of gene flow among closely related populations. PMID:25266277

  5. Dipole moment of methanol by microwave stark spectroscopy IV: 13CD316OH species

    NASA Astrophysics Data System (ADS)

    Mukhopadhyay, Indra; Sastry, K. V. L. N.

    2015-10-01

    In this work, Stark effect measurements have been carried out on several transitions C-13 substituted species of triply-deuterated (D3) methanol. The analysis of the data allowed the determination of the dipole moment components in the first two torsional states of the ground vibrational state of this species. The extrapolated zero field frequencies of the transitions studied have been determined and found to be in excellent agreement with known values. For the torsional ground state the values {in Debye (D)} of μa = 0.9080(9) and μb = 1.4378(10) have been obtained for this species. These values increase for the first excited state as was observed for other species. The dipole moment values are considerably higher than the non-deuterated species. To our knowledge the present study represents the measurement of the most accurate dipole moment values of 13CD3OH for the first time. The results obtained will prove useful for radio astronomy and in understanding of large amplitude internal energy pathways in polyatomic molecules.

  6. Beyond Zeeman spectroscopy: Magnetic-field diagnostics with Stark-dominated line shapes

    SciTech Connect

    Tessarin, S.; Mikitchuk, D.; Doron, R.; Stambulchik, E.; Kroupp, E.; Maron, Y.; Hammer, D. A.; Jacobs, V. L.; Seely, J. F.; Oliver, B. V.; Fisher, A.

    2011-09-15

    A recently suggested spectroscopic approach for magnetic-field determination in plasma is employed to measure magnetic fields in an expanding laser-produced plasma plume in an externally applied magnetic field. The approach enables the field determination in a diagnostically difficult regime for which the Zeeman-split patterns are not resolvable, as is often encountered under the conditions characteristic of high-energy-density plasmas. Here, such conditions occur in the high-density plasma near the laser target, due to the dominance of Stark broadening. A pulsed-power system is used to generate magnetic fields with a peak magnitude of 25 T at the inner-electrode surface in a coaxial configuration. An aluminum target attached to the inner electrode surface is then irradiated by a laser beam to produce the expanding plasma that interacts with the applied azimuthal magnetic field. A line-shape analysis of the Al III 4s-4p doublet (5696 and 5722 A) enables the simultaneous determination of the magnetic field and the electron density. The measured magnetic fields are generally found to agree with those expected in a vacuum based on the pulsed-power system current. Examples of other transitions that can be used to diagnose a wide range of plasma and magnetic field parameters are presented.

  7. Design of a new optical system for Alcator C-Mod motional Stark effect diagnostic

    SciTech Connect

    Ko, Jinseok; Scott, Steve; Bitter, Manfred; Lerner, Scott

    2008-10-15

    The motional Stark effect (MSE) diagnostic on Alcator C-Mod uses an in-vessel optical system (five lenses and three mirrors) to relay polarized light to an external polarimeter because port access limitations on Alcator C-Mod preclude a direct view of the diagnostic beam. The system experiences unacceptable, spurious drifts of order several degrees in measured pitch angle over the course of a run day. Recent experiments illuminated the MSE diagnostic with polarized light of fixed orientation as heat was applied to various optical elements. A large change in measured angle was observed as two particular lenses were heated, indicating that thermal-stress-induced birefringence is a likely cause of the spurious variability. Several new optical designs have been evaluated to eliminate the affected in-vessel lenses and to replace the focusing they provide with curved mirrors; however, ray tracing calculations imply that this method is not feasible. A new approach is under consideration that utilizes in situ calibrations with in-vessel reference polarized light sources.

  8. Stark Broadening of High-order Radio Recombination Lines toward the Orion Nebula

    NASA Astrophysics Data System (ADS)

    Alexander, J.; Gulyaev, S.

    2016-09-01

    We report the results of observations and analyses of 41 {{Δ }}n=1,\\ldots ,5 hydrogen radio recombination lines from the Orion nebula (M42) at 5.5 to 6.5 GHz, with a spectral sensitivity (channel-to-channel standard deviation) of ≈ 2 {mJy}. Observations were conducted at the Australia Telescope Compact Array. A 1 GHz bandwidth allowed simultaneous detection of up to 11 spectral lines of equal {{Δ }}n that were stacked to enable accurate measurement of line widths. Collisional widths in the range of principal quantum numbers n from 100 to 179 are found to be consistent with predictions of electron impact Stark broadening theory. An Orion nebula model with density inhomogeneities (clumps) and gradients of temperature and density is consistent with our data. We reanalyze the data of Smirnov et al. and Bell et al. and find excellent agreement between all statistically significant measurements and theory. Our findings confirm the absence of line narrowing for n = 100...179.

  9. Supersymmetry identifies molecular Stark states whose eigenproperties can be obtained analytically

    NASA Astrophysics Data System (ADS)

    Lemeshko, Mikhail; Mustafa, Mustafa; Kais, Sabre; Friedrich, Bretislav

    2011-06-01

    We made use of supersymmetric (SUSY) quantum mechanics to find the condition under which the Stark effect problem for a polar and polarizable closed-shell diatomic molecule subjected to collinear electrostatic and nonresonant radiative fields becomes exactly solvable. The condition \\Delta \\omega = \\frac{\\omega^2}{4 (m+1)^2 } connects values of the dimensionless parameters ω and Δω that characterize the strengths of the permanent and induced dipole interactions of the molecule with the respective fields. The exact solutions are obtained for the \\vert \\skew5\\tilde{J}=m,m;\\omega,\\Delta \\omega\\rangle family of 'stretched' states. The field-free and strong-field limits of the combined-fields problem were found to exhibit supersymmetry and shape invariance, which is indeed the reason why they are analytically solvable. By making use of the analytic form of the \\vert \\skew5\\tilde{J}=m,m;\\omega,\\Delta \\omega\\rangle wavefunctions, we obtained simple formulae for the expectation values of the space-fixed electric dipole moment, the alignment cosine and the angular momentum squared, and derived a 'sum rule' that combines the above expectation values into a formula for the eigenenergy. The analytic expressions for the characteristics of the strongly oriented and aligned states provide direct access to the values of the interaction parameters required for creating such states in the laboratory.

  10. Spectral shift amplification.

    PubMed

    Han, Pin

    2012-12-01

    The behavior of a limited bandwidth light wave reflected from a material interface is studied theoretically. It is shown that near the anomalous dispersion zone, if the incident center wavelength is shifted by a small amount, this shift can be amplified by about three times in the reflected light. PMID:23202082

  11. Style Shift in Translation

    ERIC Educational Resources Information Center

    Al-Qinai, Jamal

    2009-01-01

    The phenomenon of style shift in translated texts is ascribed mainly to textual incompatibility in terms of rhetorical asymmetry and divergence at the formality level. Mandatory shifts result from a systematic dissimilarity between the source language and the target language in terms of the underlying system of syntax, semantics and rhetorical…

  12. Spectral shift amplification.

    PubMed

    Han, Pin

    2012-12-01

    The behavior of a limited bandwidth light wave reflected from a material interface is studied theoretically. It is shown that near the anomalous dispersion zone, if the incident center wavelength is shifted by a small amount, this shift can be amplified by about three times in the reflected light.

  13. Making Shifts toward Proficiency

    ERIC Educational Resources Information Center

    McGatha, Maggie B.; Bay-Williams, Jennifer M.

    2013-01-01

    The Leading for Mathematical Proficiency (LMP) Framework (Bay-Williams et al.) has three components: (1) The Standards for Mathematical Practice; (2) Shifts in classroom practice; and (3) Teaching skills. This article briefly describes each component of the LMP framework and then focuses more in depth on the second component, the shifts in…

  14. Topology of surfaces for molecular Stark energy, alignment, and orientation generated by combined permanent and induced electric dipole interactions

    SciTech Connect

    Schmidt, Burkhard; Friedrich, Bretislav

    2014-02-14

    We show that combined permanent and induced electric dipole interactions of linear polar and polarizable molecules with collinear electric fields lead to a sui generis topology of the corresponding Stark energy surfaces and of other observables – such as alignment and orientation cosines – in the plane spanned by the permanent and induced dipole interaction parameters. We find that the loci of the intersections of the surfaces can be traced analytically and that the eigenstates as well as the number of their intersections can be characterized by a single integer index. The value of the index, distinctive for a particular ratio of the interaction parameters, brings out a close kinship with the eigenproperties obtained previously for a class of Stark states via the apparatus of supersymmetric quantum mechanics.

  15. Dependence of the time of the appearance of a Stark echo response on irreversible relaxation of a system

    NASA Astrophysics Data System (ADS)

    Akhmedshina, E. N.; Nefed'ev, L. A.; Garnaeva, G. I.

    2016-09-01

    The dependence of the time of the appearance of a Stark (gradient) echo response on the irreversible transverse relaxation time of a system in the nanosecond range and on the width of the excitation region of an inhomogeneously broadened line has been investigated. It has been shown that the use of nonresonant laser pulses with an artificially created spatial inhomogeneity makes it possible to determine the relaxation time in the nanosecond range from the time of the appearance of a Stark (gradient) echo response, which is a more accurate method than the method of determining the relaxation time from the decay of the intensity by varying time intervals of the exposure to inhomogeneous electromagnetic fields.

  16. A photoelastic-modulator-based motional Stark effect polarimeter for ITER that is insensitive to polarized broadband background reflections.

    PubMed

    Thorman, A; Michael, C; De Bock, M; Howard, J

    2016-07-01

    A motional Stark effect polarimeter insensitive to polarized broadband light is proposed. Partially polarized background light is anticipated to be a significant source of systematic error for the ITER polarimeter. The proposed polarimeter is based on the standard dual photoelastic modulator approach, but with the introduction of a birefringent delay plate, it generates a sinusoidal spectral filter instead of the usual narrowband filter. The period of the filter is chosen to match the spacing of the orthogonally polarized Stark effect components, thereby increasing the effective signal level, but resulting in the destructive interference of the broadband polarized light. The theoretical response of the system to an ITER like spectrum is calculated and the broadband polarization tolerance is verified experimentally.

  17. A photoelastic-modulator-based motional Stark effect polarimeter for ITER that is insensitive to polarized broadband background reflections

    NASA Astrophysics Data System (ADS)

    Thorman, A.; Michael, C.; De Bock, M.; Howard, J.

    2016-07-01

    A motional Stark effect polarimeter insensitive to polarized broadband light is proposed. Partially polarized background light is anticipated to be a significant source of systematic error for the ITER polarimeter. The proposed polarimeter is based on the standard dual photoelastic modulator approach, but with the introduction of a birefringent delay plate, it generates a sinusoidal spectral filter instead of the usual narrowband filter. The period of the filter is chosen to match the spacing of the orthogonally polarized Stark effect components, thereby increasing the effective signal level, but resulting in the destructive interference of the broadband polarized light. The theoretical response of the system to an ITER like spectrum is calculated and the broadband polarization tolerance is verified experimentally.

  18. Topology of surfaces for molecular Stark energy, alignment, and orientation generated by combined permanent and induced electric dipole interactions.

    PubMed

    Schmidt, Burkhard; Friedrich, Bretislav

    2014-02-14

    We show that combined permanent and induced electric dipole interactions of linear polar and polarizable molecules with collinear electric fields lead to a sui generis topology of the corresponding Stark energy surfaces and of other observables - such as alignment and orientation cosines - in the plane spanned by the permanent and induced dipole interaction parameters. We find that the loci of the intersections of the surfaces can be traced analytically and that the eigenstates as well as the number of their intersections can be characterized by a single integer index. The value of the index, distinctive for a particular ratio of the interaction parameters, brings out a close kinship with the eigenproperties obtained previously for a class of Stark states via the apparatus of supersymmetric quantum mechanics.

  19. Electron density determination in the divertor volume of ASDEX Upgrade via Stark broadening of the Balmer lines

    NASA Astrophysics Data System (ADS)

    Potzel, S.; Dux, R.; Müller, H. W.; Scarabosio, A.; Wischmeier, M.; ASDEX Upgrade Team

    2014-02-01

    In this article we present the development of a new diagnostic capable of determining the electron density in the divertor volume of ASDEX Upgrade (AUG). It is based on the spectroscopic measurement of the Stark broadening of the Balmer lines. In this work two approaches of calculating the Stark broadening, i.e. the unified theory and the model microfield method, are compared. It will be shown that both approaches yield similar results in the case of Balmer lines with high upper principal quantum numbers n. In addition, for typical AUG parameters the influence of the Zeeman splitting on the high n Balmer lines is found to be negligible. Moreover, an assumption for the Doppler broadening of Tn = 5 eV, which is the maximum Frank-Condon dissociation energy of recycled neutrals, is sufficient. The initial electron density measurements performed using this method are found to be consistent with both Langmuir probe and pressure gauge data.

  20. Shifting scintillator neutron detector

    SciTech Connect

    Clonts, Lloyd G; Cooper, Ronald G; Crow, Jr., Morris Lowell; Hannah, Bruce W; Hodges, Jason P; Richards, John D; Riedel, Richard A

    2014-03-04

    Provided are sensors and methods for detecting thermal neutrons. Provided is an apparatus having a scintillator for absorbing a neutron, the scintillator having a back side for discharging a scintillation light of a first wavelength in response to the absorbed neutron, an array of wavelength-shifting fibers proximate to the back side of the scintillator for shifting the scintillation light of the first wavelength to light of a second wavelength, the wavelength-shifting fibers being disposed in a two-dimensional pattern and defining a plurality of scattering plane pixels where the wavelength-shifting fibers overlap, a plurality of photomultiplier tubes, in coded optical communication with the wavelength-shifting fibers, for converting the light of the second wavelength to an electronic signal, and a processor for processing the electronic signal to identify one of the plurality of scattering plane pixels as indicative of a position within the scintillator where the neutron was absorbed.

  1. Thermal Line Shift and Broadening of Ho(3+) in Y3AI5O12 and Lu3AIO12

    NASA Technical Reports Server (NTRS)

    Snoke, Elizabeth R.; Armagan, Guzin; Grew, Gary W.; Barnes, Norman P.; Walsh, Brian M.

    1995-01-01

    The interaction between the active ion and the host lattice manifests itself in two distinct ways: the static interaction with the crystal field that causes the splitting of the free ion energy levels and the active interaction through the surrounding phonon system that produces temperature dependent characteristics in the optical spectrum of the ion (e.g. line broadening and line shift). The strength of the splitting depends heavily on the electronic configuration of the atom. The model give by McCumber and Sturge describes the thermal effects on line width and position above 77 K with Raman scattering of Debye model phonons. These processes predict a Lorentzian line shape. However, below 77 K the principal contributions are from crystal inhomogeneities that result in a Gaussian line shape. We have investigated the experimental Stark levels as well as the thermal effects on the line width and the position of trivalent holmium ions in both yttrium aluminum garnet, Y3Al5O12 (YAG) and lutetium aluminum garnet, Lu3Al5O12 (LuAG) crystals. We have compared the Stark levels of the (5)I(6) state, and the thermal line shift and broadening of an isolated transition (Z2 to X13) between the (5)I(8) and (5)I(6) stark levels in these crystals. This transition occurs in the near infrared region at approximately 1117 nm.

  2. Determination of Stark parameters by cross-calibration in a multi-element laser-induced plasma

    PubMed Central

    Liu, Hao; Truscott, Benjamin S.; Ashfold, Michael N. R.

    2016-01-01

    We illustrate a Stark broadening analysis of the electron density Ne and temperature Te in a laser-induced plasma (LIP), using a model free of assumptions regarding local thermodynamic equilibrium (LTE). The method relies on Stark parameters determined also without assuming LTE, which are often unknown and unavailable in the literature. Here, we demonstrate that the necessary values can be obtained in situ by cross-calibration between the spectral lines of different charge states, and even different elements, given determinations of Ne and Te based on appropriate parameters for at least one observed transition. This approach enables essentially free choice between species on which to base the analysis, extending the range over which these properties can be measured and giving improved access to low-density plasmas out of LTE. Because of the availability of suitable tabulated values for several charge states of both Si and C, the example of a SiC LIP is taken to illustrate the consistency and accuracy of the procedure. The cross-calibrated Stark parameters are at least as reliable as values obtained by other means, offering a straightforward route to extending the literature in this area. PMID:27170026

  3. Determination of Stark parameters by cross-calibration in a multi-element laser-induced plasma.

    PubMed

    Liu, Hao; Truscott, Benjamin S; Ashfold, Michael N R

    2016-05-12

    We illustrate a Stark broadening analysis of the electron density Ne and temperature Te in a laser-induced plasma (LIP), using a model free of assumptions regarding local thermodynamic equilibrium (LTE). The method relies on Stark parameters determined also without assuming LTE, which are often unknown and unavailable in the literature. Here, we demonstrate that the necessary values can be obtained in situ by cross-calibration between the spectral lines of different charge states, and even different elements, given determinations of Ne and Te based on appropriate parameters for at least one observed transition. This approach enables essentially free choice between species on which to base the analysis, extending the range over which these properties can be measured and giving improved access to low-density plasmas out of LTE. Because of the availability of suitable tabulated values for several charge states of both Si and C, the example of a SiC LIP is taken to illustrate the consistency and accuracy of the procedure. The cross-calibrated Stark parameters are at least as reliable as values obtained by other means, offering a straightforward route to extending the literature in this area.

  4. Deconvolution of Stark broadened spectra for multi-point density measurements in a flow Z-pinch

    SciTech Connect

    Vogman, G. V.; Shumlak, U.

    2011-10-13

    Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian function associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. As a result, these measurements are used to gain a better understanding of Z-pinch equilibria.

  5. Deconvolution of Stark broadened spectra for multi-point density measurements in a flow Z-pinch

    DOE PAGES

    Vogman, G. V.; Shumlak, U.

    2011-10-13

    Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian functionmore » associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. As a result, these measurements are used to gain a better understanding of Z-pinch equilibria.« less

  6. Determination of Stark parameters by cross-calibration in a multi-element laser-induced plasma

    NASA Astrophysics Data System (ADS)

    Liu, Hao; Truscott, Benjamin S.; Ashfold, Michael N. R.

    2016-05-01

    We illustrate a Stark broadening analysis of the electron density Ne and temperature Te in a laser-induced plasma (LIP), using a model free of assumptions regarding local thermodynamic equilibrium (LTE). The method relies on Stark parameters determined also without assuming LTE, which are often unknown and unavailable in the literature. Here, we demonstrate that the necessary values can be obtained in situ by cross-calibration between the spectral lines of different charge states, and even different elements, given determinations of Ne and Te based on appropriate parameters for at least one observed transition. This approach enables essentially free choice between species on which to base the analysis, extending the range over which these properties can be measured and giving improved access to low-density plasmas out of LTE. Because of the availability of suitable tabulated values for several charge states of both Si and C, the example of a SiC LIP is taken to illustrate the consistency and accuracy of the procedure. The cross-calibrated Stark parameters are at least as reliable as values obtained by other means, offering a straightforward route to extending the literature in this area.

  7. Shifts of the H sub. beta. line in dense hydrogen plasmas

    SciTech Connect

    Mijatovic, Z.; Pavlov, M.; Djurovic, S. )

    1991-06-01

    The H{sub {beta}} line shifts were measured in dense {ital ssT}-shaped-tube plasmas for electron densities from 2.1{times}10{sup 17} to 7.8{times}10{sup 17} cm{sup {minus}3} and temperatures between 19 000 and 35 000 K. Comparisons of these shifts with recent theories (H. R. Griem, Phys. Rev. A 28, 1596 (1983); 38, 2943 (1988)) that take the dynamical quadratic Stark effect for {Delta}{ital n}=0 and {ital n}{prime}={ital n}+1 interactions and ion quadrupole effects into account are presented. Also, comparisons with some experimental results (H. L. Wiese, D. E. Kelleher, and D. R. Paquette, Phys. Rev. A 6, 1132 (1972)) were made. Our results are in agreement with an extrapolated experimental best fit to the experimental results of Wiese {ital et} {ital al}., but the measured shifts are larger than the theories predict.

  8. Blackbody radiation shift in the {sup 87}Rb frequency standard

    SciTech Connect

    Safronova, M. S.; Jiang Dansha; Safronova, U. I.

    2010-08-15

    The operation of atomic clocks is generally carried out at room temperature, whereas the definition of the second refers to the clock transition in an atom at absolute zero. This implies that the clock transition frequency should be corrected in practice for the effect of finite temperature, of which the leading contributor is the blackbody radiation (BBR) shift. Experimental measurements of the BBR shifts are difficult. In this work, we have calculated the blackbody radiation shift of the ground-state hyperfine microwave transition in {sup 87}Rb using the relativistic all-order method and carried out a detailed evaluation of the accuracy of our final value. Particular care is taken to accurately account for the contributions from highly excited states. Our predicted value for the Stark coefficient, k{sub S}=-1.240(4)x10{sup -10} Hz/(V/m){sup 2}, is three times more accurate than the previous calculation [E. J. Angstman, V. A. Dzuba, and V. V. Flambaum, Phys. Rev. A 74, 023405 (2006)].

  9. The ac53, ac78, ac101, and ac103 Genes Are Newly Discovered Core Genes in the Family Baculoviridae

    PubMed Central

    Garavaglia, Matías Javier; Miele, Solange Ana Belén; Iserte, Javier Alonso; Belaich, Mariano Nicolás

    2012-01-01

    The family Baculoviridae is a large group of insect viruses containing circular double-stranded DNA genomes of 80 to 180 kbp, which have broad biotechnological applications. A key feature to understand and manipulate them is the recognition of orthology. However, the differences in gene contents and evolutionary distances among the known members of this family make it difficult to assign sequence orthology. In this study, the genome sequences of 58 baculoviruses were analyzed, with the aim to detect previously undescribed core genes because of their remote homology. A routine based on Multi PSI-Blast/tBlastN and Multi HaMStR allowed us to detect 31 of 33 accepted core genes and 4 orthologous sequences in the Baculoviridae which were not described previously. Our results show that the ac53, ac78, ac101 (p40), and ac103 (p48) genes have orthologs in all genomes and should be considered core genes. Accordingly, there are 37 orthologous genes in the family Baculoviridae. PMID:22933288

  10. Semiconductor ac static power switch

    NASA Technical Reports Server (NTRS)

    Vrancik, J.

    1968-01-01

    Semiconductor ac static power switch has long life and high reliability, contains no moving parts, and operates satisfactorily in severe environments, including high vibration and shock conditions. Due to their resistance to shock and vibration, static switches are used where accidental switching caused by mechanical vibration or shock cannot be tolerated.

  11. Shape-Shifting Plastic

    SciTech Connect

    2015-05-20

    A new plastic developed by ORNL and Washington State University transforms from its original shape through a series of temporary shapes and returns to its initial form. The shape-shifting process is controlled through changes in temperature

  12. Pure shift NMR.

    PubMed

    Zangger, Klaus

    2015-04-01

    Although scalar-coupling provides important structural information, the resulting signal splittings significantly reduce the resolution of NMR spectra. Limited resolution is a particular problem in proton NMR experiments, resulting in part from the limited proton chemical shift range (∼10 ppm) but even more from the splittings due to scalar coupling to nearby protons. "Pure shift" NMR spectroscopy (also known as broadband homonuclear decoupling) has been developed for disentangling overlapped proton NMR spectra. The resulting spectra are considerably simplified as they consist of single lines, reminiscent of proton-decoupled C-13 spectra at natural abundance, with no multiplet structure. The different approaches to obtaining pure shift spectra are reviewed here and several applications presented. Pure shift spectra are especially useful for highly overlapped proton spectra, as found for example in reaction mixtures, natural products and biomacromolecules.

  13. Our World: Fluid Shift

    NASA Video Gallery

    Learn about the circulatory system and how gravity aids blood flow in our bodies here on Earth. Find out how NASA flight surgeons help the astronauts deal with the fluid shift that happens during s...

  14. Refinement of the semiclassical theory of the Stark broadening of hydrogen spectral lines in plasmas

    NASA Astrophysics Data System (ADS)

    Oks, Eugene

    2015-02-01

    Stark broadening (SB) of hydrogen, deuterium, and tritium lines (H-lines) is an important diagnostic tool for many applications. The most "user-friendly" are semiclassical theories of the SB of H-lines: their results can be expressed analytically in a relatively simple form for any H-line. The simplest semiclassical theory is the so-called Conventional Theory (CT), which is frequently referred to as Griem's theory. While by now there are several significantly more advanced semiclassical "non-CT" theories of the SB, Griem's CT is still used by a number of groups performing laboratory experiments or astrophysical observations for the comparison with their experimental or observational results. In the present study we engage unexplored capabilities of the CT for creating analytically a more accurate CT. First, we take into account that the perturbing electrons actually do not move as free particles: rather they move in a dipole potential V=·r/r3, where r is the radius-vector of the perturbing electrons and is the mean value of the radius vector of the atomic electron. Second, Griem's definition of the so-called Weisskopf radius was not quite accurate. Third, in his book of year 1974, Griem suggested changing so-called strong collision constant without changing the Weisskopf radius, while in reality the choices of the Weisskopf radius and of the strong collision constant are interrelated. We show that the above refinements of the CT increase the electron broadening - especially for warm dense plasmas emitting H-lines. By comparison with benchmark experiments concerning the Hα line we demonstrate that the effect of the ion dynamics (neglected in any CT) might be slightly smaller than previously thought, while the effect of the acceleration of perturbing electrons by the ion field in the vicinity of the radiating atom (neglected in any CT) might be greater than previously thought.

  15. Effect of higher-order multipole moments on the Stark line shape

    NASA Astrophysics Data System (ADS)

    Gomez, T. A.; Nagayama, T.; Kilcrease, D. P.; Montgomery, M. H.; Winget, D. E.

    2016-08-01

    Spectral line shapes are sensitive to plasma conditions and are often used to diagnose electron density of laboratory plasmas as well as astrophysical plasmas. Stark line-shape models take into account the perturbation of the radiator's energy structure due to the Coulomb interaction with the surrounding charged particles. Solving this Coulomb interaction is challenging and is commonly approximated via a multipole expansion. However, most models include only up to the second term of the expansion (the dipole term). While there have been studies on the higher-order terms due to one of the species (i.e., either ions or electrons), there is no model that includes the terms beyond dipole from both species. Here, we investigate the importance of the higher-order multipole terms from both species on the Hβ line shape. First, we find that it is important to include higher-order terms consistently from both ions and electrons to reproduce measured line-shape asymmetry. Next, we find that the line shape calculated with the dipole-only approximation becomes inaccurate as density increases. It is necessary to include up to the third (quadrupole) term to compute the line shape accurately within 2%. Since most existing models include only up to the dipole terms, the densities inferred with such models are in question. We find that the model without the quadrupole term slightly underestimates the density, and the discrepancy becomes as large as 12% at high densities. While the case of study is limited to Hβ, we expect similar impact on other lines.

  16. Measuring electric fields and noncovalent interactions using the vibrational stark effect.

    PubMed

    Fried, Stephen D; Boxer, Steven G

    2015-04-21

    Over the past decade, we have developed a spectroscopic approach to measure electric fields inside matter with high spatial (<1 Å) and field (<1 MV/cm) resolution. The approach hinges on exploiting a physical phenomenon known as the vibrational Stark effect (VSE), which ultimately provides a direct mapping between observed vibrational frequencies and electric fields. Therefore, the frequency of a vibrational probe encodes information about the local electric field in the vicinity around the probe. The VSE method has enabled us to understand in great detail the underlying physical nature of several important biomolecular phenomena, such as drug-receptor selectivity in tyrosine kinases, catalysis by the enzyme ketosteroid isomerase, and unidirectional electron transfer in the photosynthetic reaction center. Beyond these specific examples, the VSE has provided a conceptual foundation for how to model intermolecular (noncovalent) interactions in a quantitative, consistent, and general manner. The starting point for research in this area is to choose (or design) a vibrational probe to interrogate the particular system of interest. Vibrational probes are sometimes intrinsic to the system in question, but we have also devised ways to build them into the system (extrinsic probes), often with minimal perturbation. With modern instruments, vibrational frequencies can increasingly be recorded with very high spatial, temporal, and frequency resolution, affording electric field maps correspondingly resolved in space, time, and field magnitude. In this Account, we set out to explain the VSE in broad strokes to make its relevance accessible to chemists of all specialties. Our intention is not to provide an encyclopedic review of published work but rather to motivate the underlying framework of the methodology and to describe how we make and interpret the measurements. Using certain vibrational probes, benchmarked against computer models, it is possible to use the VSE to measure

  17. Photophysics of fulvene under the non-resonant stark effect. Shaping the conical intersection seam.

    PubMed

    Ruiz-Barragan, Sergi; Blancafort, Lluís

    2013-01-01

    We introduce a mechanistic strategy to control the excited state lifetime of fulvene based on shaping the topography of an extended seam of intersection with the non-resonant dynamic Stark effect. Fulvene has a very short excited state lifetime due to an energetically accessible seam of intersection which lies along the methylene torsion coordinate, and the initial decay occurs at the seam segment around the planar conical intersection structure. We have followed a three-step approach to simulate the control. First, we have calculated the effect of a non-resonant electric field on the potential energy surface at the ab initio level, including the field in a self-consistent way. The relative energy of the planar segment of the seam is increased by the non-resonant field. In the second step we simulate the control carrying out MCTDH quantum dynamics propagations under a static non-resonant field to derive the main control mechanisms. At moderately intense fields (epsilon < or = 0.03 a.u.) the decay is faster as compared to the field free case because the vibrational overlap between the excited and ground state vibrational functions is increased. However, at more intense fields (epsilon = 0.04 a.u.) the planar conical intersection is energetically inaccessible and the decay occurs at a slower time scale, at the segment of the seam with more twisted geometries. In the third step, the control over the dynamics is exerted with a non-resonant dynamic field. The acceleration of the decay due to the improved vibrational overlap does not occur, but the decay can be made slower with a dynamic field of 0.08 a.u. The results show the viability of our approach to control the photophysics shaping the topology of the conical intersection seam, and they prove that the extended nature of the seam is crucial for simulating and understanding the control.

  18. Molecular Electronic Shift Registers

    NASA Technical Reports Server (NTRS)

    Beratan, David N.; Onuchic, Jose N.

    1990-01-01

    Molecular-scale shift registers eventually constructed as parts of high-density integrated memory circuits. In principle, variety of organic molecules makes possible large number of different configurations and modes of operation for such shift-register devices. Several classes of devices and implementations in some specific types of molecules proposed. All based on transfer of electrons or holes along chains of repeating molecular units.

  19. Vehicular transmission shift mechanism

    SciTech Connect

    Okubo, K.

    1988-12-27

    This patent describes a vehicular transmission having a main speed change mechanism and a sub speed change mechanism both housed within a transmission case. The main speed change mechanism has gear trains in plural shifting stages provided between input and output shafts and capable of being established selectively and also has a plurality of synchronizing mechanisms operable by shift forks to establish the gear trains selectively. The sub speed change mechanism has a reduction gear train for obtaining a still lower speed than the lowest shifting stage in the main speed change mechanism and also has a sub speed gear shifting synchronizing mechanism operable by a sub speed gear shift fork to establish the reduction gear train. This sub speed change mechanism is disposed in parallel with the main speed change mechanism, the sub speed gear shift fork having means connected to one end of a lever pivotably supported at an intermediate part thereof by a pivot pin, the pivot pin being mounted on the transmission case from the outside thereof.

  20. AC Magnetic Field Frequency Dependence of Magnetoacoustic Emission

    NASA Technical Reports Server (NTRS)

    Namkung, M.; Wincheski, B.; Fulton, J. P.; DeNale, R.

    1992-01-01

    Our recent study has proved a strong correlation between the low-frequency AC applied magnetic field amplitude dependence of the asymmetry of the magnetoacoustic emission (MAE) burst and the strength of the domain wall-defect interaction in iron-base ferromagnets. For the present study the AC magnetic field frequency dependence of the asymmetry has been investigated in the range of 1 to 200 Hz. When represented by the third moment of the rectified acoustic emission pulses, the asymmetry becomes a bell-shaped function of frequency with its center located around 25 Hz. This experiment has been performed with low carbon, high yield stress steel specimens of three different levels of domain wall-defect interaction strength. The results show that the increase in the interaction strength causes a vertical down shift of the asymmetry in the entire frequency range investigated.

  1. ACS Expands Role In High School Chemistry.

    ERIC Educational Resources Information Center

    Chemical and Engineering News, 1979

    1979-01-01

    Describes some of the services and programs of special interests to high school chemistry teachers that are being provided by ACS, and meant to make ACS membership more attractive to the teachers. (GA)

  2. A driving scheme to reduce AC LED flicker

    NASA Astrophysics Data System (ADS)

    Tan, Jianchuan; Narendran, Nadarajah

    2013-09-01

    Light flicker is a common but unwelcome phenomenon in conventional lighting applications. In solid-state lighting, driving or dimming methods also give rise to light flicker. AC LED products in today's marketplace suffer from flicker, which stems from the arrangement of the micro-LEDs and the driving method. Research has shown that light flicker can be a health hazard to humans. Several solutions have been proposed to reduce light flicker in solid-state lighting applications; however, most have drawbacks in terms of power and other performance. This paper proposes a circuit design to reduce light flicker from AC LEDs while maintaining a normal power factor and high power efficiency. The circuit is composed of one resistive branch and one capacitive branch, and each branch drives a load which is made up of high-voltage LEDs. Percent flicker, power factor, and power efficiency were selected as three metrics, and their benchmarks were set to evaluate the performance of this circuit. Phase shift between the two branches was selected as a factor that could determine the circuit performance. The variations of percent flicker, power factor, and power efficiency as a function of phase shift were identified by theoretical analysis and were verified by experiments. The experimental results show that an optimal solution can be achieved for this circuit design at proper phase shift, where the benchmarks of the three metrics are reached.

  3. Absorption driven focus shift

    NASA Astrophysics Data System (ADS)

    Harrop, N.; Wolf, S.; Maerten, O.; Dudek, K.; Ballach, S.; Kramer, R.

    2016-03-01

    Modern high brilliance near infrared lasers have seen a tremendous growth in applications throughout the world. Increased productivity has been achieved by higher laser power and increased brilliance of lasers. Positive impacts on the performance and costs of parts are opposed to threats on process stability and quality, namely shift of focus position over time. A high initial process quality will be reduced by contamination of optics, eventually leading to a focus shift or even destruction of the optics. Focus analysis at full power of multi-kilowatt high brilliance lasers is a very demanding task because of high power densities in the spot and the high power load on optical elements. With the newly developed high power projection optics, the High-Power Micro-Spot Monitor High Brilliance (HP-MSM-HB) is able to measure focus diameter as low as 20 μm at power levels up to 10 kW at very low internal focus shift. A main driving factor behind thermally induced focus shift is the absorption level of the optical element. A newly developed measuring system is designed to determine the relative absorption level in reference to a gold standard. Test results presented show a direct correlation between absorption levels and focus shift. The ability to determine the absorption level of optical elements as well as their performance at full processing power before they are put to use, enables a high level of quality assurance for optics manufacturers and processing head manufacturers alike.

  4. Precise measurement of the Stark shift within the 5P1/2 -->6S1/2 transition in 115In

    NASA Astrophysics Data System (ADS)

    Lorenzo, A. T.; Ranjit, G.; Majumder, P. K.

    2011-05-01

    We are pursuing a series of precise atomic structure measurements in Group IIIA elements--currently thallium and indium--designed to test recent ab initio theoretical calculations in these systems. In indium, a two-step, two-color vapor cell hyperfine spectroscopy experiment was recently completed in our laboratory. Previously, an atomic beam system in conjunction with a thallium oven source and high-voltage field plates was used to complete a precise scalar polarizability measurement in thallium. In our current work, we have designed a new indium atomic beam source, and are pursuing a precision measurement of the indium atomic polarizability within the 410 nm 5P 1/2 --> 6S1/2 transition. The new source is capable of reaching 1100 °C and contains a series of parallel effusive slits to produce a dense, collimated beam of indium. We intersect the laser transversely with the atomic beam in the presence of a precisely calibrated electric field of 30 kV/cm. Frequency modulation of the laser, and simultaneous piezoelectric modulation of the atomic beam allows a dual-frequency lock-in detection scheme. This produces a zero-background atomic absorption spectrum of high signal-to-noise ratio. Our goal is to achieve a polarizability measurement at the 1% level of accuracy or better, which will provide a stringent new test of the atomic theory calculations.

  5. Predicting catastrophic shifts.

    PubMed

    Weissmann, Haim; Shnerb, Nadav M

    2016-05-21

    Catastrophic shifts are known to pose a serious threat to ecology, and a reliable set of early warning indicators is desperately needed. However, the tools suggested so far have two problems. First, they cannot discriminate between a smooth transition and an imminent irreversible shift. Second, they aimed at predicting the tipping point where a state loses its stability, but in noisy spatial system the actual transition occurs when an alternative state invades. Here we suggest a cluster tracking technique that solves both problems, distinguishing between smooth and catastrophic transitions and to identify an imminent shift in both cases. Our method may allow for the prediction, and thus hopefully the prevention of such transitions, avoiding their destructive outcomes. PMID:26970446

  6. Stark broadening for diagnostics of the electron density in non-equilibrium plasma utilizing isotope hydrogen alpha lines

    SciTech Connect

    Yang, Lin; Tan, Xiaohua; Wan, Xiang; Chen, Lei; Jin, Dazhi; Qian, Muyang; Li, Gongping

    2014-04-28

    Two Stark broadening parameters including FWHM (full width at half maximum) and FWHA (full width at half area) of isotope hydrogen alpha lines are simultaneously introduced to determine the electron density of a pulsed vacuum arc jet. To estimate the gas temperature, the rotational temperature of the C{sub 2} Swan system is fit to 2500 ± 100 K. A modified Boltzmann-plot method with b{sub i}-factor is introduced to determine the modified electron temperature. The comparison between results of atomic and ionic lines indicates the jet is in partial local thermodynamic equilibrium and the electron temperature is close to 13 000 ± 400 K. Based on the computational results of Gig-Card calculation, a simple and precise interpolation algorithm for the discrete-points tables can be constructed to obtain the traditional n{sub e}-T{sub e} diagnostic maps of two Stark broadening parameters. The results from FWHA formula by the direct use of FWHM = FWHA and these from the diagnostic map are different. It can be attributed to the imprecise FWHA formula form and the deviation between FWHM and FWHA. The variation of the reduced mass pair due to the non-equilibrium effect contributes to the difference of the results derived from two hydrogen isotope alpha lines. Based on the Stark broadening analysis in this work, a corrected method is set up to determine n{sub e} of (1.10 ± 0.08) × 10{sup 21} m{sup −3}, the reference reduced mass μ{sub 0} pair of (3.30 ± 0.82 and 1.65 ± 0.41), and the ion kinetic temperature of 7900 ± 1800 K.

  7. Paleomagnetism of the Zn-rich Pennsylvanian Stark black shale, Kansas City area, U.S.A.

    NASA Astrophysics Data System (ADS)

    Kawasaki, K.; Symons, D. T.; Coveney, R. M.

    2007-05-01

    Paleomagnetic results are reported from the metalliferous Stark black shale (Heebner-type) in the Upper Pennsylvanian Kansas City Group. Paleomagnetic analysis of 400 specimens from 28 sites gives a characteristic remanent magnetization (ChRM) in 17 sites that yields a Late Mississippian to Middle Pennsylvanian paleopole at 32.2 ° N 128.5 ° E (dp = 4.7° and dm = 8.8°). The fact that the observed age is slightly older than the host rock age indicates that the shale's mineralization has a syngenetic origin. The main remanence carrier in the Stark Shale is single or psudosingle domain magnetite or titanomagnetite. Trace hematite, which was generated during modern weathering, likely causes the slightly older age by steepening the primary ChRM by ~2°. The large oval of 95 % confidence is interpreted to be caused by the formation of clay-magnetite aggregates during sediment transport that are easily biased by the gentle paleocurrent at each site acting on their large flat surface. Therefore, the scattered distribution of the site mean remanence declinations found for the Stark Shale is evidence of a detrital remanent magnetization that is formed by primary sedimentary processes and not of remagnetization by secondary hydrothermal processes. The finding that the primary ChRM directions of Heebner-type black shales are so easily scattered by sedimentary processes implies that a highly clustered ChRM direction in a mineralized black shale, such as in Zn-Pb rich SEDEX deposits, is evidence of coeval or post-depositional hydrothermal fluids.

  8. 1H, 13C and 15N NMR assignments of the aciniform spidroin (AcSp1) repetitive domain of Argiope trifasciata wrapping silk.

    PubMed

    Xu, Lingling; Tremblay, Marie-Laurence; Meng, Qing; Liu, Xiang-Qin; Rainey, Jan K

    2012-10-01

    Spider silk is one of nature's most remarkable biomaterials due to extraordinary strength and toughness not found in today's synthetic materials. Of the seven types of silk, wrapping silk (AcSp1) is the most extensible of the types of silks and has no sequence similarity to the other types. Here we report the chemical shifts for the AcSp1 199 amino acid protein repeat unit and its anticipated secondary structure based on secondary chemical shifts. PMID:21989955

  9. Phase-sensitive detection of both inductive and non-inductive ac voltages in ferromagnetic resonance

    NASA Astrophysics Data System (ADS)

    Weiler, Mathias; Shaw, Justin M.; Nembach, Hans T.; Schoen, Martin A.; Boone, Carl T.; Silva, Thomas J.

    2014-03-01

    Spin pumping causes significant damping in ultrathin ferromagnetic/normal metal (NM) multilayers via spin-current generation of both dc and ac character in the NM system. While the nonlinear dc component has been investigated in detail by utilization of the inverse spin Hall effect (iSHE) in NMs, much less is known about the linear ac component that is presumably much larger in the small-excitation limit. We measured generated ac voltages in a wide variety of Permalloy/NM multilayers via vector-network-analyzer ferromagnetic resonance. We employ a custom, impedance-matched, broadband microwave coupler that features a ferromagnetic thin film reference resonator to accurately compare ac voltage amplitudes and phases between varieties of multilayers. By use of the fact that inductive and ac iSHE signals are phase-shifted by π/2, we find that inductive signals are major contributors in all investigated samples. It is only by comparison of the phase and amplitude of the recorded ac voltages between multiple samples that we can extract the non-inductive contributions due to spin-currents. Voltages due to the ac iSHE in Permalloy(10nm)/platinum(5nm) bilayers are weaker than inductive signals, in agreement with calculations based upon recent theoretical predictions. M.W. acknowledges financial support by the German Academic Exchange service (DAAD).

  10. Simultaneous distribution of AC and DC power

    DOEpatents

    Polese, Luigi Gentile

    2015-09-15

    A system and method for the transport and distribution of both AC (alternating current) power and DC (direct current) power over wiring infrastructure normally used for distributing AC power only, for example, residential and/or commercial buildings' electrical wires is disclosed and taught. The system and method permits the combining of AC and DC power sources and the simultaneous distribution of the resulting power over the same wiring. At the utilization site a complementary device permits the separation of the DC power from the AC power and their reconstruction, for use in conventional AC-only and DC-only devices.

  11. Demonstration of photon Bloch oscillations and Wannier-Stark ladders in dual-periodical multilayer structures based on porous silicon.

    PubMed

    Estevez, J Octavio; Arriaga, Jesús; Mendez-Blas, Antonio; Reyes-Ayona, Edgar; Escorcia, José; Agarwal, Vivechana

    2012-07-23

    : Theoretical demonstration and experimental evidence of photon Bloch oscillations and Wannier-Stark ladders (WSLs) in dual-periodical (DP) multilayers, based on porous silicon, are presented. An introduction of the linear gradient in refractive indices in DP structure, which is composed by stacking two different periodic substructures N times, resulted in the appearance of WSLs. Theoretical time-resolved reflection spectrum shows the photon Bloch oscillations with a period of 130 fs. Depending on the values of the structural parameters, one can observe the WSLs in the near infrared or visible region which may allow the generation of terahertz radiation with a potential applications in several fields like imaging.

  12. A new species of Neoperla from China, with a redescription of the female of N. mnong Stark, 1987 (Plecoptera, Perlidae).

    PubMed

    Chen, Zhi-Teng; Du, Yu-Zhou

    2016-01-01

    A new species of the Neoperla clymene group (Plecoptera, Perlidae), Neoperla chebalinga sp. n. from Guangdong Province of southern China is described, illustrated, and compared with related taxa. The new species is characterized by the slender aedeagal tube, strongly sclerotized dorsally, and weakly sclerotized ventrally with an upcurved, medial, finger-like membranous lobe. Additionally the aedeagal sac gradually tapers to a blunt apex with a dorsoapical patch of spines. A supplementary description of the female of Neoperla mnong Stark, 1987 from Guangdong Province, China is also given. PMID:27667948

  13. A new species of Neoperla from China, with a redescription of the female of N. mnong Stark, 1987 (Plecoptera, Perlidae).

    PubMed

    Chen, Zhi-Teng; Du, Yu-Zhou

    2016-01-01

    A new species of the Neoperla clymene group (Plecoptera, Perlidae), Neoperla chebalinga sp. n. from Guangdong Province of southern China is described, illustrated, and compared with related taxa. The new species is characterized by the slender aedeagal tube, strongly sclerotized dorsally, and weakly sclerotized ventrally with an upcurved, medial, finger-like membranous lobe. Additionally the aedeagal sac gradually tapers to a blunt apex with a dorsoapical patch of spines. A supplementary description of the female of Neoperla mnong Stark, 1987 from Guangdong Province, China is also given.

  14. A new species of Neoperla from China, with a redescription of the female of N. mnong Stark, 1987 (Plecoptera, Perlidae)

    PubMed Central

    Chen, Zhi-Teng; Du, Yu-Zhou

    2016-01-01

    Abstract A new species of the Neoperla clymene group (Plecoptera, Perlidae), Neoperla chebalinga sp. n. from Guangdong Province of southern China is described, illustrated, and compared with related taxa. The new species is characterized by the slender aedeagal tube, strongly sclerotized dorsally, and weakly sclerotized ventrally with an upcurved, medial, finger-like membranous lobe. Additionally the aedeagal sac gradually tapers to a blunt apex with a dorsoapical patch of spines. A supplementary description of the female of Neoperla mnong Stark, 1987 from Guangdong Province, China is also given. PMID:27667948

  15. Demonstration of photon Bloch oscillations and Wannier-Stark ladders in dual-periodical multilayer structures based on porous silicon

    NASA Astrophysics Data System (ADS)

    Estevez, J. Octavio; Arriaga, Jesús; Mendez-Blas, Antonio; Reyes-Ayona, Edgar; Escorcia, José; Agarwal, Vivechana

    2012-07-01

    Theoretical demonstration and experimental evidence of photon Bloch oscillations and Wannier-Stark ladders (WSLs) in dual-periodical (DP) multilayers, based on porous silicon, are presented. An introduction of the linear gradient in refractive indices in DP structure, which is composed by stacking two different periodic substructures N times, resulted in the appearance of WSLs. Theoretical time-resolved reflection spectrum shows the photon Bloch oscillations with a period of 130 fs. Depending on the values of the structural parameters, one can observe the WSLs in the near infrared or visible region which may allow the generation of terahertz radiation with a potential applications in several fields like imaging.

  16. A new species of Neoperla from China, with a redescription of the female of N. mnong Stark, 1987 (Plecoptera, Perlidae)

    PubMed Central

    Chen, Zhi-Teng; Du, Yu-Zhou

    2016-01-01

    Abstract A new species of the Neoperla clymene group (Plecoptera, Perlidae), Neoperla chebalinga sp. n. from Guangdong Province of southern China is described, illustrated, and compared with related taxa. The new species is characterized by the slender aedeagal tube, strongly sclerotized dorsally, and weakly sclerotized ventrally with an upcurved, medial, finger-like membranous lobe. Additionally the aedeagal sac gradually tapers to a blunt apex with a dorsoapical patch of spines. A supplementary description of the female of Neoperla mnong Stark, 1987 from Guangdong Province, China is also given.

  17. Trophic shift, not collapse

    USGS Publications Warehouse

    Madenjian, Charles P.; Rutherford, Edward S.; Stow, Craig A.; Roseman, Edward F.; He, Ji X.

    2013-01-01

    scientists who are closely monitoring Lake Huron’s food web, we believe that the ongoing changes are more accurately characterized as a trophic shift in which benthic pathways have become more prominent. While decreases in abundance have occurred for some species, others are experiencing improved reproduction resulting in the restoration of several important native species.

  18. Eluding catastrophic shifts

    PubMed Central

    Villa Martín, Paula; Bonachela, Juan A.; Levin, Simon A.; Muñoz, Miguel A.

    2015-01-01

    Transitions between regimes with radically different properties are ubiquitous in nature. Such transitions can occur either smoothly or in an abrupt and catastrophic fashion. Important examples of the latter can be found in ecology, climate sciences, and economics, to name a few, where regime shifts have catastrophic consequences that are mostly irreversible (e.g., desertification, coral reef collapses, and market crashes). Predicting and preventing these abrupt transitions remains a challenging and important task. Usually, simple deterministic equations are used to model and rationalize these complex situations. However, stochastic effects might have a profound effect. Here we use 1D and 2D spatially explicit models to show that intrinsic (demographic) stochasticity can alter deterministic predictions dramatically, especially in the presence of other realistic features such as limited mobility or spatial heterogeneity. In particular, these ingredients can alter the possibility of catastrophic shifts by giving rise to much smoother and easily reversible continuous ones. The ideas presented here can help further understand catastrophic shifts and contribute to the discussion about the possibility of preventing such shifts to minimize their disruptive ecological, economic, and societal consequences. PMID:25825772

  19. Eluding catastrophic shifts.

    PubMed

    Villa Martín, Paula; Bonachela, Juan A; Levin, Simon A; Muñoz, Miguel A

    2015-04-14

    Transitions between regimes with radically different properties are ubiquitous in nature. Such transitions can occur either smoothly or in an abrupt and catastrophic fashion. Important examples of the latter can be found in ecology, climate sciences, and economics, to name a few, where regime shifts have catastrophic consequences that are mostly irreversible (e.g., desertification, coral reef collapses, and market crashes). Predicting and preventing these abrupt transitions remains a challenging and important task. Usually, simple deterministic equations are used to model and rationalize these complex situations. However, stochastic effects might have a profound effect. Here we use 1D and 2D spatially explicit models to show that intrinsic (demographic) stochasticity can alter deterministic predictions dramatically, especially in the presence of other realistic features such as limited mobility or spatial heterogeneity. In particular, these ingredients can alter the possibility of catastrophic shifts by giving rise to much smoother and easily reversible continuous ones. The ideas presented here can help further understand catastrophic shifts and contribute to the discussion about the possibility of preventing such shifts to minimize their disruptive ecological, economic, and societal consequences.

  20. Two-center three-electron bonding in ClNH3 revealed via helium droplet infrared laser Stark spectroscopy: Entrance channel complex along the Cl + NH3 → ClNH2 + H reaction

    NASA Astrophysics Data System (ADS)

    Moradi, Christopher P.; Xie, Changjian; Kaufmann, Matin; Guo, Hua; Douberly, Gary E.

    2016-04-01

    Pyrolytic dissociation of Cl2 is employed to dope helium droplets with single Cl atoms. Sequential addition of NH3 to Cl-doped droplets leads to the formation of a complex residing in the entry valley to the substitution reaction Cl + NH3 → ClNH2 + H. Infrared Stark spectroscopy in the NH stretching region reveals symmetric and antisymmetric vibrations of a C3v symmetric top. Frequency shifts from NH3 and dipole moment measurements are consistent with a ClNH3 complex containing a relatively strong two-center three-electron (2c-3e) bond. The nature of the 2c-3e bonding in ClNH3 is explored computationally and found to be consistent with the complexation-induced blue shifts observed experimentally. Computations of interconversion pathways reveal nearly barrierless routes to the formation of this complex, consistent with the absence in experimental spectra of two other complexes, NH3Cl and Cl-HNH2, which are predicted in the entry valley to the hydrogen abstraction reaction Cl + NH3 → HCl + NH2.

  1. Two-center three-electron bonding in ClNH3 revealed via helium droplet infrared laser Stark spectroscopy: Entrance channel complex along the Cl + NH3 → ClNH2 + H reaction.

    PubMed

    Moradi, Christopher P; Xie, Changjian; Kaufmann, Matin; Guo, Hua; Douberly, Gary E

    2016-04-28

    Pyrolytic dissociation of Cl2 is employed to dope helium droplets with single Cl atoms. Sequential addition of NH3 to Cl-doped droplets leads to the formation of a complex residing in the entry valley to the substitution reaction Cl + NH3 → ClNH2 + H. Infrared Stark spectroscopy in the NH stretching region reveals symmetric and antisymmetric vibrations of a C3v symmetric top. Frequency shifts from NH3 and dipole moment measurements are consistent with a ClNH3 complex containing a relatively strong two-center three-electron (2c-3e) bond. The nature of the 2c-3e bonding in ClNH3 is explored computationally and found to be consistent with the complexation-induced blue shifts observed experimentally. Computations of interconversion pathways reveal nearly barrierless routes to the formation of this complex, consistent with the absence in experimental spectra of two other complexes, NH3Cl and Cl-HNH2, which are predicted in the entry valley to the hydrogen abstraction reaction Cl + NH3 → HCl + NH2. PMID:27131544

  2. Molecular-beam optical Stark and Zeeman study of the A {sup 2}{Pi}--X {sup 2}{Sigma}{sup +} (0,0) band system of BaF

    SciTech Connect

    Steimle, Timothy C.; Frey, Sarah; Le, Anh; DeMille, David; Rahmlow, David A.; Linton, Colan

    2011-07-15

    The A {sup 2}{Pi}-X {sup 2}{Sigma}{sup +} (0,0) band system of barium monofluoride (BaF) has been recorded using high-resolution laser-induced fluorescence spectroscopy both field-free and in the presence of static magnetic and electric fields. The field-free spectra for the {sup 135}BaF, {sup 137}BaF, and {sup 138}BaF isotopologues were modeled to generate an improved set of spectroscopic constants for the A {sup 2}{Pi}({upsilon} = 0) and X {sup 2}{Sigma}{sup +}({upsilon} = 0) states. The observed optical Stark shifts for the {sup 138}BaF isotopologue were analyzed to produce the permanent electric dipole moments of 1.50(2) and 1.31(2) D for the A {sup 2}{Pi}{sub 1/2}({upsilon} = 0) and A {sup 2}{Pi}{sub 3/2} ({upsilon} = 0) states, respectively. The observed optical Zeeman shifts for the {sup 138}BaF isotopologue were analyzed to produce a set of magnetic g factors for the A {sup 2}{Pi}({upsilon} = 0) and X {sup 2}{Sigma}{sup +}({upsilon} = 0) states.

  3. An Overview Of The Motional Stark Effect Diagnostic On DIII-D And Design Work For An ITER MSE

    SciTech Connect

    Holcomb, C T; Allen, S L; Makowski, M A; Jayakumar, R J; Gu, M F; Lerner, S; Morris, K L; Latkowski, J; Moller, J M; Meyer, W; Ellis, R; Geer, R; Behne, D; Chipman, R; Smith, P; McClain, S

    2007-09-20

    The advanced tokamak research program at DIII-D relies critically on the measurement of the current density profile. This was made possible by the development of a Motional Stark Effect (MSE) polarimeter that was first installed in 1992. Three major upgrades have since occurred, and improvements in our understanding of critical performance issues and calibration techniques are ongoing. In parallel with these improvements, we have drawn on our DIII-D experience to begin studies and design work for MSE on burning plasmas and ITER. This paper first reviews how Motional Stark Effect polarimetry (MSE) is used to determine the tokamak current profile. It uses the DIII-D MSE system as an example, and shows results from the latest upgrade that incorporates an array of channels from a new counter-Ip injected neutral beam. The various calibration techniques presently used are reviewed. High-leverage or unresolved issues affecting MSE performance and reliability in ITER are discussed. Next, we show a four-mirror collection optics design for the two ITER MSE views. Finally, we discuss measurements of the polarization properties of a few candidate mirrors for the ITER MSE.

  4. Optical Stark spectroscopy of the B̃(1)A('')(000)←X̃(1)A(')(000) system of copper hydroxide.

    PubMed

    Wang, Fang; Steimle, Timothy C

    2011-01-01

    The B̃(1)A('')(000)←X̃(1)A(')(000) band system of a cold beam of CuOH has been studied field-free and in the presence of a static electric field. The Stark tuning of the low-J levels of the X̃(1)A(')(000) state were analyzed to give a value of 3.968(32) D for the a-component of the permanent electric dipole moment, μ(a). An upper limit of 0.3 D for μ(a)(B̃(1)A('')) is established from the lack of observable Stark tuning for the low-J levels of the B̃(1)A('')(000) state. The experimental value for μ(a)(X̃(1)A(')) is compared to theoretical predictions and other Cu-containing molecules. A molecular orbital correlation diagram is used to rationalize the large change in μ(a) upon excitation. The electronegativity of OH was determined to be 2.81 from a comparison of the determined μ(a) with the experimental μ values for CuF, CuO, and CuS.

  5. Optical Stark spectroscopy of the B~1A''(000)<--X~1A'(000) system of copper hydroxide

    NASA Astrophysics Data System (ADS)

    Wang, Fang; Steimle, Timothy C.

    2011-01-01

    The tilde B{}^1A^' ' (000)←tilde X{}^1A^' (000) band system of a cold beam of CuOH has been studied field-free and in the presence of a static electric field. The Stark tuning of the low-J levels of the tilde X{}^1A^' (000) state were analyzed to give a value of 3.968(32) D for the a-component of the permanent electric dipole moment, μa. An upper limit of 0.3 D for μa(tilde B{}^1A^' ' ) is established from the lack of observable Stark tuning for the low-J levels of the tilde B{}^1A^' ' (000) state. The experimental value for μa(tilde X{}^1A^' ) is compared to theoretical predictions and other Cu-containing molecules. A molecular orbital correlation diagram is used to rationalize the large change in μa upon excitation. The electronegativity of OH was determined to be 2.81 from a comparison of the determined μa with the experimental μ values for CuF, CuO, and CuS.

  6. Multiple Temperature-Sensing Behavior of Green and Red Upconversion Emissions from Stark Sublevels of Er3+

    PubMed Central

    Cao, Baosheng; Wu, Jinlei; Wang, Xuehan; He, Yangyang; Feng, Zhiqing; Dong, Bin

    2015-01-01

    Upconversion luminescence properties from the emissions of Stark sublevels of Er3+ were investigated in Er3+-Yb3+-Mo6+-codoped TiO2 phosphors in this study. According to the energy levels split from Er3+, green and red emissions from the transitions of four coupled energy levels, 2H11/2(I)/2H11/2(II), 4S3/2(I)/4S3/2(II), 4F9/2(I)/4F9/2(II), and 2H11/2(I) + 2H11/2(II)/4S3/2(I) + 4S3/2(II), were observed under 976 nm laser diode excitation. By utilizing the fluorescence intensity ratio (FIR) technique, temperature-dependent upconversion emissions from these four coupled energy levels were analyzed at length. The optical temperature-sensing behaviors of sensing sensitivity, measurement error, and operating temperature for the four coupled energy levels are discussed, all of which are closely related to the energy gap of the coupled energy levels, FIR value, and luminescence intensity. Experimental results suggest that Er3+-Yb3+-Mo6+-codoped TiO2 phosphor with four pairs of energy levels coupled by Stark sublevels provides a new and effective route to realize multiple optical temperature-sensing through a wide range of temperatures in an independent system. PMID:26690431

  7. Stark level analysis of the spectral line shape of electronic transitions in rare earth ions embedded in host crystals

    NASA Astrophysics Data System (ADS)

    Steinkemper, H.; Fischer, S.; Hermle, M.; Goldschmidt, J. C.

    2013-05-01

    Rare earth ions embedded in host crystals are of great interest for many applications. Due to the crystal field of the host material, the energy levels of the rare earth ions split into several Stark levels. The resulting broadening of the spectral line shapes of transitions between those levels determines the upconversion phenomena, especially under broad-spectrum illumination, which are relevant for photovoltaics for instance. In this paper, we present a method to determine the spectral line shape of energy level transitions of rare earth ions from the absorption spectrum of the investigated material. A parameter model is used to describe the structure of the individual energy levels based on a representation of the Stark splitting. The parameters of the model are then determined with an evolutionary optimization algorithm. The described method is applied to the model system of β-NaEr0.2Y0.8F4. The results indicate that for illumination with a wavelength around 1523 nm, simple upconversion processes such as two-step absorption or direct energy transfer are less efficient than commonly assumed. Hence a sequence of efficient processes is suggested as an explanation for the high upconversion quantum yield of β-NaEr0.2Y0.8F4, which has not yet been reported in the literature.

  8. Effects of 946-nm thermal shift and broadening on Nd3+:YAG laser performance

    NASA Astrophysics Data System (ADS)

    Seyed Ebrahim, Pourmand; Ghasem, Rezaei

    2015-12-01

    Spectroscopic properties of flashlamp pumped Nd3+:YAG laser are studied as a function of temperature in a range from -30 °C to 60 °C. The spectral width and shift of quasi three-level 946.0-nm inter-Stark emission within the respective intermanifold transitions of 4F3/2 → 4I9/2 are investigated. The 946.0-nm line shifts toward the shorter wavelength and broadens. In addition, the threshold power and slope efficiency of the 946.0-nm laser line are quantified with temperature. The lower the temperature, the lower the threshold power is and the higher the slope efficiency of the 946.0-nm laser line is, thus the higher the laser output is. This phenomenon is attributed to the ion-phonon interaction and the thermal population in the ground state. Project supported by Estahban Branch, Islamic Azad University.

  9. Small-Signal ac Analysis

    NASA Technical Reports Server (NTRS)

    Jagielski, James M.; Chen, Jess

    1987-01-01

    Program simulates power circuits and systems. Small Signal A.C. Analysis program (SSAC) valuable tool for design and analysis of electrical-power-system circuits. By combining "black box" power-system components operating in specified manner, user characterizes system modeled. Menu-driven program proved simple and cost effective in development and modification of arbitrary power-system configurations. Package includes sample data from Dynamic Explorer satellite family. Results compared favorable to calculations from such general circuit-analysis programs as SPICE. Written in FORTRAN 77.

  10. Effect of the magnetic material on AC losses in HTS conductors in AC magnetic field carrying AC transport current

    NASA Astrophysics Data System (ADS)

    Wan, Xing-Xing; Huang, Chen-Guang; Yong, Hua-Dong; Zhou, You-He

    2015-11-01

    This paper presents an investigation on the AC losses in several typical superconducting composite conductors using the H-formulation model. A single superconducting strip with ferromagnetic substrate or cores and a stack of coated conductors with ferromagnetic substrates are studied. We consider all the coated conductors carrying AC transport currents and simultaneously exposed to perpendicular AC magnetic fields. The influences of the amplitude, frequency, phase difference and ferromagnetic materials on the AC losses are investigated. The results show that the magnetization losses of single strip and stacked strips have similar characteristics. The ferromagnetic substrate can increase the magnetization loss at low magnetic field, and decrease the loss at high magnetic field. The ferromagnetic substrate can obviously increase the transport loss in stacked strips. The trends of total AC losses of single strip and stacked strips are similar when they are carrying current or exposed to a perpendicular magnetic field. The effect of the frequency on the total AC losses of single strip is related to the amplitude of magnetic field. The AC losses decrease with increasing frequency in low magnetic field region while increase in high magnetic field region. As the phase difference changes, there is a periodic variation for the AC losses. Moreover, when the strip is under only the transport current and magnetic field, the ferromagnetic cores will increase the AC losses for large transport current or field.

  11. ac electroosmosis in rectangular microchannels.

    PubMed

    Campisi, Michele; Accoto, Dino; Dario, Paolo

    2005-11-22

    Motivated by the growing interest in ac electroosmosis as a reliable no moving parts strategy to control fluid motion in microfluidic devices for biomedical applications, such as lab-on-a-chip, we study transient and steady-state electrokinetic phenomena (electroosmosis and streaming currents) in infinitely extended rectangular charged microchannels. With the aid of Fourier series and Laplace transforms we provide a general formal solution of the problem, which is used to study the time-dependent response to sudden ac applied voltage differences in case of finite electric double layer. The Debye-Huckel approximation has been adopted to allow for an algebraic solution of the Poisson-Boltzmann problem in Fourier space. We obtain the expressions of flow velocity profiles, flow rates, streaming currents, as well as expressions of the complex hydraulic and electrokinetic conductances. We analyze in detail the dependence of the electrokinetic conductance on the extension of linear dimensions relative to the Debye length, with an eye on finite electric double layer effects. PMID:16351310

  12. Theoretical and experimental investigation of the interactions between [emim]Ac and water molecules

    NASA Astrophysics Data System (ADS)

    Ding, Zhen-Dong; Chi, Zhen; Gu, Wen-Xiu; Gu, Sheng-Ming; Wang, Hai-Jun

    2012-05-01

    Density functional theory (DFT) calculations, atom in molecules (AIM) theory, natural bond orbital (NBO) analysis and infrared (IR) spectroscopy were performed to investigate the interactions between water molecules and ionic liquid 1-ethyl-3-methylimidazolium acetate ([emim]Ac). It was found that [emim]Ac interacts with water molecules mainly via H-bonds, and the anionic part of [emim]Ac plays a major role in the interaction with H2O. The energies of H-bonds were estimated from spectral shifts of hydroxy antisymmetric stretching vibration. Moreover, the experimental results also indicated that hydroxy of water mainly interacts with the COO- of [emim]Ac. Further studies indicated that the intensity of hydroxy stretching vibrations tend to be stronger with the increase of the concentration of water. In addition, the frequency of hydroxy stretching vibrations showed clearly red-shift, and the COO- vibrational frequency gradually shifted to the lower wavenumber region, which were indicative of extended hydrogen bonded network.

  13. Electron density measurements of atmospheric-pressure non-thermal N{sub 2} plasma jet by Stark broadening and irradiance intensity methods

    SciTech Connect

    Xiao, Dezhi; Shen, Jie; Lan, Yan; Xie, Hongbing; Shu, Xingsheng; Meng, Yuedong; Li, Jiangang; Cheng, Cheng E-mail: paul.chu@cityu.edu.hk; Chu, Paul K. E-mail: paul.chu@cityu.edu.hk

    2014-05-15

    An atmospheric-pressure non-thermal plasma jet excited by high frequency alternating current using nitrogen is developed and the electron density in the active region of this plasma jet is investigated by two different methods using optical emission spectroscopy, Stark broadening, and irradiance intensity method. The irradiance intensity method shows that the average electron density is about 10{sup 20}/m{sup 3} which is slightly smaller than that by the Stark broadening method. However, the trend of the change in the electron density with input power obtained by these two methods is consistent.

  14. Improved transistorized AC motor controller for battery powered urban electric passenger vehicles

    NASA Technical Reports Server (NTRS)

    Peak, S. C.

    1982-01-01

    An ac motor controller for an induction motor electric vehicle drive system was designed, fabricated, tested, evaluated, and cost analyzed. A vehicle performance analysis was done to establish the vehicle tractive effort-speed requirements. These requirements were then converted into a set of ac motor and ac controller requirements. The power inverter is a three-phase bridge using power Darlington transistors. The induction motor was optimized for use with an inverter power source. The drive system has a constant torque output to base motor speed and a constant horsepower output to maximum speed. A gear shifting transmission is not required. The ac controller was scaled from the base 20 hp (41 hp peak) at 108 volts dec to an expanded horsepower and battery voltage range. Motor reversal was accomplished by electronic reversal of the inverter phase sequence. The ac controller can also be used as a boost chopper battery charger. The drive system was tested on a dynamometer and results are presented. The current-controlled pulse width modulation control scheme yielded improved motor current waveforms. The ac controller favors a higher system voltage.

  15. Catastrophic shifts in ecosystems

    NASA Astrophysics Data System (ADS)

    Scheffer, Marten; Carpenter, Steve; Foley, Jonathan A.; Folke, Carl; Walker, Brian

    2001-10-01

    All ecosystems are exposed to gradual changes in climate, nutrient loading, habitat fragmentation or biotic exploitation. Nature is usually assumed to respond to gradual change in a smooth way. However, studies on lakes, coral reefs, oceans, forests and arid lands have shown that smooth change can be interrupted by sudden drastic switches to a contrasting state. Although diverse events can trigger such shifts, recent studies show that a loss of resilience usually paves the way for a switch to an alternative state. This suggests that strategies for sustainable management of such ecosystems should focus on maintaining resilience.

  16. Elective automatic shift transmission

    SciTech Connect

    Redzinski, G.E.

    1986-09-02

    For use in vehicle of the type having an engine coupled with traction wheels through a driveline including a change-speed transmission, the transmission includes drive direction reversing means, a drive direction selector for manual control of the reversing means and having a forward and reverse position, the transmission including ratio changing means, a manual gear selector for operation of the ratio changing means for shifting the transmission into a selected gear, and control means responsive to a control signal for upshifting and downshifting between first and second gears.

  17. Extensión del Formalismo de Orbitales de Defecto Cuántico al tratamiento del efecto Stark (SQDO).

    NASA Astrophysics Data System (ADS)

    Menéndez, J. M.; Martín, I.; Velasco, A. M.

    El estudio experimental de las interacciones de átomos Rydberg altamente excitados con campos eléctricos ha experimentado un creciente interés durante las dos últimas décadas debido, en gran medida, al desarrollo de nuevas técnicas para crear y estudiar átomos Rydberg en el laboratorio. Acompañando a estas nuevas técnicas experimentales, es necesario el desarrollo de modelos teóricos que nos permitan contrastar sus medidas y conocer mejor los fundamentos de los mismos. Desde el punto de vista teórico el conocimiento del desdoblamiento de los niveles energéticos de un átomo en función de la magnitud del campo eléctrico aplicado (lo que se conoce como mapa Stark) es el mejor punto de partida para la descripción del sistema y un prerrequisito fundamental para el cálculo de distintas propiedades atómicas en presencia del campo eléctrico tales como intensidades de transición, umbrales de ionización de campo eléctrico, tiempos de vida, posición y anchura de cruces evitados, etc. En este trabajo presentamos la adaptación del método de orbitales de defecto cuántico [1,2,3] al tratamiento del efecto Stark (SQDO) [4] y su aplicación al cálculo de los desdoblamientos energéticos y fuerzas de oscilador de estados Rydberg en los átomos de Li, Na y K. El propósito de este estudio es, por un lado, desarrollar métodos fiables para la determinación de propiedades atómicas en presencia de campos eléctricos y, por otro, mostrar la fiabilidad de las funciones de onda QDO en la descripción del efecto Stark en sistemas atómicos.

  18. Shifted genus expanded W ∞ algebra and shifted Hurwitz numbers

    NASA Astrophysics Data System (ADS)

    Zheng, Quan

    2016-05-01

    We construct the shifted genus expanded W ∞ algebra, which is isomorphic to the central subalgebra A ∞ of infinite symmetric group algebra and to the shifted Schur symmetrical function algebra Λ* defined by Okounkov and Olshanskii. As an application, we get some differential equations for the generating functions of the shifted Hurwitz numbers; thus, we can express the generating functions in terms of the shifted genus expanded cut-and-join operators.

  19. Shifting seasons, climate change and ecosystem consequences

    NASA Astrophysics Data System (ADS)

    Thackeray, Stephen; Henrys, Peter; Hemming, Deborah; Huntingford, Chris; Bell, James; Leech, David; Wanless, Sarah

    2014-05-01

    In recent decades, the seasonal timing of many biological events (e.g. flowering, breeding, migration) has shifted. These phenological changes are believed to be one of the most conspicuous biological indicators of climate change. Rates and directions of phenological change have differed markedly among species, potentially threatening the seasonal synchrony of key species interactions and ultimately ecosystem functioning. Differences in phenological change among-species at different trophic levels, and with respect to other broad species traits, are likely to be driven by variations in the climatic sensitivity of phenological events. However, as yet, inconsistencies in analytical methods have hampered broad-scale assessments of variation in climate sensitivity among taxonomic and functional groups of organisms. In this presentation, results will be presented from a current collaborative project (http://www.ceh.ac.uk/sci_programmes/shifting-seasons-uk.html) in which many UK long-term data sets are being integrated in order to assess relationships between temperature/precipitation, and the timing of seasonal events for a wide range of plants and animals. Our aim is to assess which organism groups (in which locations/habitats) are most sensitive to climate. Furthermore, the role of anthropogenic climate change as a driver of phenological change is being assessed.

  20. Transmission shift control assembly

    SciTech Connect

    Dzioba, D.L.

    1989-04-18

    This patent describes a transmission shift control assembly mounted on a steering column having a longitudinal axis comprising: bracket means secured to the steering column; transmission shift cable means having a portion secured to the bracket means and a portion linearly movable relative to the secured portion; mounting means on the bracket cable drive arm means having an axis and being rotatably mounted on the rotary axis on the mounting means oblique to the longitudinal axis and including a cable connecting portion secured to the movable portion of the cable means and lever mounting means adjacent the mounting means; operator control means including lever means, pin means for pivotally mounting the lever means on the lever mounting means on an axis substantially perpendicular to the rotary axis and positioning arm means formed on the lever means and extending from the pin means; and detent gate means disposed on the bracket means in position to abut the positioning arm means for limiting the extent of pivotal movement of the lever means.

  1. Stark broadening measurement of the electron density in an atmospheric pressure argon plasma jet with double-power electrodes

    SciTech Connect

    Qian Muyang; Ren Chunsheng; Wang Dezhen; Zhang Jialiang; Wei Guodong

    2010-03-15

    Characteristics of a double-power electrode dielectric barrier discharge of an argon plasma jet generated at the atmospheric pressure are investigated in this paper. Time-averaged optical emission spectroscopy is used to measure the plasma parameters, of which the excitation electron temperature is determined by the Boltzmann's plot method whereas the gas temperature is estimated using a fiber thermometer. Furthermore, the Stark broadening of the hydrogen Balmer H{sub {beta}} line is applied to measure the electron density, and the simultaneous presence of comparable Doppler, van der Waals, and instrumental broadenings is discussed. Besides, properties of the jet discharge are also studied by electrical diagnosis. It has been found that the electron densities in this argon plasma jet are on the order of 10{sup 14} cm{sup -3}, and the excitation temperature, gas temperature, and electron density increase with the applied voltage. On the other hand, these parameters are inversely proportional to the argon gas flow rate.

  2. Quantum-confined Stark effect on spatially indirect excitons in CdTe/Cdx Zn1-x Te quantum wells

    NASA Astrophysics Data System (ADS)

    Haas, H.; Magnea, N.; Dang, Le Si

    1997-01-01

    The quantum-confined Stark effect is studied in the mixed type-I/type-II CdTe/Cdx Zn1-x Te strained heterostructures. The type-II nature of the light-hole excitons is unambiguously confirmed by the blueshift observed under increasing electric field, in good agreement with calculations. On the other hand, the heavy-hole excitons are redshifted as expected for type-I excitons. The peculiar valence-band alignment, resulting from the sign reversal of the strain between the wells and the barriers, is used to detect the electric-field induced mixing of LH1 and HH2 confined hole states. An accurate value for the long-disputed chemical valence-band offset of CdTe/ZnTe system is extracted as ΔEV=(11+/-3)% of the band-gap difference between unstrained CdTe and ZnTe materials.

  3. A new Stark decelerator based surface scattering instrument for studying energy transfer at the gas-surface interface

    SciTech Connect

    Engelhart, Daniel P.; Grätz, Fabian; Wagner, Roman J. V.; Wodtke, Alec M.; Schäfer, Tim; Haak, Henrik; Meijer, Gerard

    2015-04-15

    We report on the design and characterization of a new apparatus for performing quantum-state resolved surface scattering experiments. The apparatus combines optical state-specific molecule preparation with a compact hexapole and a Stark decelerator to prepare carrier gas-free pulses of quantum-state pure CO molecules with velocities controllable between 33 and 1000 m/s with extremely narrow velocity distributions. The ultrahigh vacuum surface scattering chamber includes homebuilt ion and electron detectors, a closed-cycle helium cooled single crystal sample mount capable of tuning surface temperature between 19 and 1337 K, a Kelvin probe for non-destructive work function measurements, a precision leak valve manifold for targeted adsorbate deposition, an inexpensive quadrupole mass spectrometer modified to perform high resolution temperature programmed desorption experiments and facilities to clean and characterize the surface.

  4. Study on the Characteristics of Wire Grid Polarizer for Alcator C-Mod Motional Stark Effect Diagnostic

    NASA Astrophysics Data System (ADS)

    Ko, Jinseok; Scott, Steve

    2005-10-01

    A wire grid polarizer (WGP) has been installed on the in-vessel optics module of the Motional Stark Effect (MSE) diagnostic system in Alcator C-Mod tokamak. The polarized light produced by this WGP can be utilized to measure the change in polarization angle by Faraday rotation through the diagnostic system when the tokamak is operated in its normal condition. Intensive WGP tests on the off-site optical table have been done to investigate the effect of non-normal incidence on the WGP which is indeed the situation inside the tokamak. A model has been developed to understand and simulate various effects of the WGP structure such as changes in angle-of-incidence and reflection/transmission coefficients due to the anti-reflection coating layer and the glass substrate. These analytic predictions and test results are compared with the tests in the tokamak where the in-vessel WGP is used.

  5. Dynamic Stark Spectroscopic Measurements of Microwave Electric Fields Inside the Plasma Near a High-Power Antenna

    NASA Astrophysics Data System (ADS)

    Klepper, C. C.; Isler, R. C.; Hillairet, J.; Martin, E. H.; Colas, L.; Ekedahl, A.; Goniche, M.; Harris, J. H.; Hillis, D. L.; Panayotis, S.; Pegourié, B.; Lotte, Ph.; Colledani, G.; Martin, V.; Tore Supra Lower Hybrid Systems Technical Team

    2013-05-01

    Fully dynamic Stark effect visible spectroscopy was used for the first time to directly measure the local rf electric field in the boundary plasma near a high-power antenna in high-performance, magnetically confined, fusion energy experiment. The measurement was performed in the superconducting tokamak Tore Supra, in the near field of a 1-3 MW, lower-hybrid, 3.7 GHz wave-launch antenna, and combined with modeling of neutral atom transport to estimate the local rf electric field amplitude (as low as 1-2kV/cm) and direction in this region. The measurement was then shown to be consistent with the predicted values from a 2D full-wave propagation model. Notably the measurement confirmed that the electric field direction deviates substantially from the direction in which it is launched by the waveguides as it penetrates only a few cm radially inward into the plasma from the waveguides, consistent with the model.

  6. A temporally and spatially resolved electron density diagnostic method for the edge plasma based on Stark broadening

    NASA Astrophysics Data System (ADS)

    Zafar, A.; Martin, E. H.; Shannon, S. C.; Isler, R. C.; Caughman, J. B. O.

    2016-11-01

    An electron density diagnostic (≥1010 cm-3) capable of high temporal (ms) and spatial (mm) resolution is currently under development at Oak Ridge National Laboratory. The diagnostic is based on measuring the Stark broadened, Doppler-free spectral line profile of the n = 6-2 hydrogen Balmer series transition. The profile is then fit to a fully quantum mechanical model including the appropriate electric and magnetic field operators. The quasi-static approach used to calculate the Doppler-free spectral line profile is outlined here and the results from the model are presented for H-δ spectra for electron densities of 1010-1013 cm-3. The profile shows complex behavior due to the interaction between the magnetic substates of the atom.

  7. Real-time Magnetic Field Pitch Angle Estimation With a Motional Stark Effect Diagnostic Using Kalman Filtering

    SciTech Connect

    Coelho, R.; Alves, D.

    2008-03-12

    The real-time amplitude estimation of selective harmonics from an Avalanche Photo Diode (APD) signal of a Motion Stark Effect diagnostic is addressed using a Kalman filter. The proposed technique is shown to be much more robust and provide less noisy estimates than a lock-in amplifier scheme. In addition, the negative impact of Edge Localised Modes (ELMs) is minimized, reducing significantly the biasing in the amplitude estimation and ultimately allowing for the pitch angle estimation in the vicinity of the ELM. The inherent biasing in the amplitude estimation due to the 50Hz modulation in the NBI power grid is also easily circumvented with such a technique, rendering dispensable any further filtering of the data.

  8. Phase shifting interferometer

    DOEpatents

    Sommargren, G.E.

    1999-08-03

    An interferometer is disclosed which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 11 figs.

  9. Phase shifting interferometer

    DOEpatents

    Sommargren, Gary E.

    1999-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  10. Phase shifting diffraction interferometer

    DOEpatents

    Sommargren, G.E.

    1996-08-29

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 8 figs.

  11. Phase shifting diffraction interferometer

    DOEpatents

    Sommargren, Gary E.

    1996-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  12. Shifting epidemiology of Flaviviridae.

    PubMed

    Petersen, Lyle R; Marfin, Anthony A

    2005-04-01

    The dengue, West Nile, Japanese encephalitis and yellow fever viruses are important mosquito-borne viruses whose epidemiology is shifting in response to changing societal factors, such as increasing commerce, urbanization of rural areas, and population growth. All four viruses are expanding geographically, as exemplified by the emergence of West Nile virus in the Americas and Japanese encephalitis virus in Australasia. The large, recent global outbreaks of severe neurological disease caused by West Nile virus, the increasing frequency of dengue hemorrhagic fever outbreaks in the Americas, and the emergence of yellow fever virus vaccination-associated viscerotropic disease, are new clinical epidemiologic trends. These worrisome epidemiologic trends will probably continue in coming decades, as a reversal of their societal and biological drivers is not in sight. Nevertheless, the substantial reductions in Japanese encephalitis virus incidence resulting from vaccination programs and economic development in some Asian countries provide some encouragement within this overall guarded outlook.

  13. An automatically-shifted two-speed transaxle system for an electric vehicle

    NASA Technical Reports Server (NTRS)

    Gordon, H. S.; Hassman, G. V.

    1980-01-01

    An automatic shifting scheme for a two speed transaxle for use with an electric vehicle propulsion system is described. The transaxle system was to be installed in an instrumented laboratory propulsion system of an ac electric vehicle drive train. The transaxle which had been fabricated is also described.

  14. ac susceptibility of an assembly of nanomagnets: Combined effects of surface anisotropy and dipolar interactions

    NASA Astrophysics Data System (ADS)

    Vernay, F.; Sabsabi, Z.; Kachkachi, H.

    2014-09-01

    We compute the ac susceptibility of a weakly dipolar-interacting monodisperse assembly of magnetic nanoclusters with oriented anisotropy. For this purpose, we first compute the relaxation rate in a longitudinal magnetic field of a single nanomagnet taking account of both dipolar interactions in the case of dilute assemblies and surface anisotropy. We then study the behavior of the real and imaginary components of the ac susceptibility as functions of temperature, frequency, surface anisotropy, and interparticle interactions. We find that the surface anisotropy induces an upward shift of the temperature at the maximum of the ac susceptibility components and that its effects may be tuned so as to screen out the effects of interactions. The phenomenological Vogel-Fulcher law for the effect of dipolar interaction on the relaxation rate is revisited within our formalism and a semianalytical expression is given for the effective temperature in terms of inter alia the applied field, surface anisotropy, and dipolar interaction.

  15. Hydraulically actuated well shifting tool

    SciTech Connect

    Roth, B.A.

    1992-10-20

    This patent describes a hydraulically actuated shifting tool for actuating a sliding member in a well tool. It comprises: a housing having a hydraulic fluid bore therein; shifting dog means positioned on the housing for movement away and toward the housing; locking dog means positioned on the housing for movement away and toward the body; shifting dog hydraulic actuating means in fluid communication with the bore for causing engagement of the shifting dogs with the sliding member; locking dog hydraulic actuating means in communication with the bore for causing engagement of the locking dogs with the locking means; and hydraulic shifting means in communication with the bore for causing relative movement between the shifting dog means and the locking dog means for shifting the sliding sleeve.

  16. Transitions among H Stark substates induced by time-varying, weak static electric fields

    NASA Astrophysics Data System (ADS)

    Butz, A.; Koch, P. M.; Schultz, K. D.; Wilson, J.

    2002-05-01

    Our laboratory produces H Rydberg atoms (typically 14 keV) with a collision/laser method. H^+-Xe collisions produce H(n) atoms. A 100 kV/cm field ionizes n>9. In F1 near 30 kV/cm, a CO2 laser transfers 50% of (n,n_1,|m|)=(7,0,0) atoms to (10,0,0) (or other chosen substate). They fly through F2 and are excited in F3 with a CO2 laser from n=10 substates to n>24 substates. Each F is transverse between parallel plates, but we separately control the voltage to all six plates. If all Fi are parallel and F_2, F3 exceed a few V/cm, population stays on the (10,0,0) substate, and we get a `simple' excitation spectrum in F_3. If F2 or F3 (or both) is too weak or antiparallel, we detect new excitation peaks in F3 from atoms moved into other n=10 substates. Our experimental goal is careful, quantitative measurements and interpretation of these excitation spectra to understand where the population goes. Our theoretical goal is a model for this process similar to that for Majorana depolarization of magnetic substates in Lamb-shift polarized ion sourcesfootnote G.G. Ohlsen, Los Alamos Report LA-3949 (1968); W.J. Thompson, Nucl. Instr. Meth. A 333, 443 (1993). .

  17. Three phase AC motor controller

    DOEpatents

    Vuckovich, Michael; Wright, Maynard K.; Burkett, John P.

    1984-03-20

    A motor controller for a three phase AC motor (10) which is adapted to operate bidirectionally from signals received either from a computer (30) or a manual control (32). The controller is comprised of digital logic circuit means which implement a forward and reverse command signal channel (27, 29) for the application of power through the forward and reverse power switching relays (16, 18, 20, 22). The digital logic elements are cross coupled to prevent activation of both channels simultaneously and each includes a plugging circuit (65, 67) for stopping the motor upon the removal of control signal applied to one of the two channels (27, 29) for a direction of rotation desired. Each plugging circuit (65, 67) includes a one-shot pulse signal generator (88, 102) which outputs a single pulse signal of predetermined pulsewidth which is adapted to inhibit further operation of the application of power in the channel which is being activated and to apply a reversal command signal to the other channel which provides a reversed phase application of power to the motor for a period defined by the pulse-width output of the one-shot signal generator to plug the motor (10) which will then be inoperative until another rotational command signal is applied to either of the two channels.

  18. Superconductor coil geometry and ac losses

    NASA Technical Reports Server (NTRS)

    Pierce, T. V., Jr.; Zapata, R. N.

    1976-01-01

    An empirical relation is presented which allows simple computation of volume-averaged winding fields from central fields for coils of small rectangular cross sections. This relation suggests that, in certain applications, ac-loss minimization can be accomplished by use of low winding densities, provided that hysteresis losses are independent of winding density. The ac-loss measurements on coils wound of twisted multifilamentary composite superconductors show no significant dependence on ac losses on winding density, thus permitting the use of winding density as an independent design parameter in loss minimization.

  19. Shift related dietary intake in day and shift workers.

    PubMed

    Lennernäs, M; Hambraeus, L; Akerstedt, T

    1995-12-01

    To study the impact of work hours on eating habits the dietary intake of 96 male industrial workers on day work and two- and three-shift work was investigated using repeated 24 h recall. The intake of energy, 14 nutrients, and coffee and tea was computed, using a nutrient data base, for 8 h work and shifts (day, morning, afternoon, night) and for the 24-h periods including these work shifts. No changes in intake of energy, nutrients and coffee/tea were observed between 8 h morning and afternoon shifts, but there was a reduction in intake during 8 h night shifts. Night shift work caused a redistribution of food and coffee intake, but not an overall 24 h reduction. On the whole, the energy-intake and the quality of food intake (percentages of energy from macronutrients and density of micronutrients) were not affected by shift work, although the intake of carbohydrates was lower in day- and three-shift workers during days off. The intake of alcohol was higher during days off in all groups. In summary, two- and three-shift work in this study affected the circadian distribution of food intakes and coffee consumption, but not the overall 24-h consumption.

  20. Enhanced adsorption of benzene vapor on granular activated carbon under humid conditions due to shifts in hydrophobicity and total micropore volume.

    PubMed

    Liu, Han-Bing; Yang, Bing; Xue, Nan-Dong

    2016-11-15

    A series of hydrophobic-modified (polydimethylsiloxane (PDMS) coating) activated carbons (ACs) were developed to answer a fundamental question: what are the determinants that dominate the adsorption on ACs under humid conditions? Using column experiments, an inter-comparison among bare-AC and PDMS-coated ACs was conducted regarding the association of surface characteristics and adsorption capacity. Primary outcomes occurred in two dominating markers, hydrophobicity and total micropore volume, which played a key role in water adsorption on ACs. However, their contributions to water adsorption on ACs substantially differed under different Pwater/Pair conditions. Hydrophobicity was the only contributor in Pwater/Pair=0.1-0.6, while the two markers contributed equally in Pwater/Pair=0.7-1.0. Furthermore, PDMS-coated AC had a significant increase in benzene adsorption capacities compared to bare-AC at 0-90% relative humidity, while these differences were not significant among PDMS-coated ACs. It is thus presumed that the balance between the two markers can be shifted to favor almost unchanged benzene adsorption capacities among PDMS-coated ACs over a large range of relative humidity. These findings suggest potential benefits of PDMS coating onto ACs in enhancing selective adsorption of hydrophobic volatile organic compounds under high humid conditions. To develop new porous materials with both high total micropore volume and hydrophobicity should thus be considered. PMID:27450334

  1. Blackbody radiation shift of the {sup 133}Cs hyperfine transition frequency

    SciTech Connect

    Micalizio, Salvatore; Godone, Aldo; Calonico, Davide; Levi, Filippo; Lorini, Luca

    2004-05-01

    We report the theoretical evaluations of the static scalar polarizability of the {sup 133}Cs ground state and of the blackbody radiation shift induced on the transition frequency between the two hyperfine levels with m{sub F}=0. This shift is of fundamental importance in the evaluation of the accuracy of the primary frequency standards based on atomic fountains and is employed in the realization of the SI second in the International Atomic Time scale at the level of 1x10{sup -15}. Our computed value for the polarizability is {alpha}{sub 0}=(6.600{+-}0.016)x10{sup -39}C m{sup 2}/V in agreement at the level of 1x10{sup -3} with recent theoretical and experimental values. As regards the blackbody radiation shift we find for the relative hyperfine transition frequency {beta}=(-1.49{+-}0.07)x10{sup -14} at T=300 K in agreement with frequency measurements reported by our group and by Bauch and Schroeder [Phys. Rev. Lett. 78, 622 (1997)]. This value is lower by 2x10{sup -15} than that obtained with measurements based on the dc Stark shift and than the value commonly accepted up to now.

  2. ACS after SM4: New Life for an Old Workhorse

    NASA Astrophysics Data System (ADS)

    Golimowski, David; Anderson, Jay; Armstrong, Amber; Arslanian, Steve; Bedin, Luigi; Bohlin, Ralph; Boyce, Kevin; Chapman, George; Cheng, Edward; Chiaberge, Marco; Cox, Colin; Desiardins, Tyler; Dye, Darryl; Ellis, Tracy; Ferguson, Brian; Fruchter, Andrew; Grogin, Norman; Lim, Pey Lian; Loose, Markus; Lucas, Ray; Lupie, Olivia; Mack, Jennifer; Maybhate, Aparna; Mil, Kathleen; Mutchler, Max; Ricardo, Raphael; Scott, Barbara; Serrano, Beverly; Sirianni, Marco; Smith, Linda; Suchkov, Anatoly A.; Waczynski, Augustyn; Welty, Alan; Wheeler, Thomas; Wilson, Erin

    2010-07-01

    The ACS CCD Electronics Box Replacement (CEB-R) installed during SM4 features a Teledyne SIDECAR ASIC that permits optimization of the WFC via adjustment of CCD clock voltages, bias voltages, and pixel transmission timing. An on-orbit campaign to optimize the performance of the WFC was undertaken at the start of the SMOV period. Initial tests with pre-SM4 default voltages and timing patterns showed that WFC's performance matches or exceeds its pre-failure levels, notwithstanding the expected increases in dark current and hot pixels and the decline in charge-transfer efficiency due to prolonged exposure to HST's radiation environment. One WFC CCD exhibited anomalous behavior when operated with nondefault settings of its reset drain voltage. Consequently, the optimization campaign was truncated after two iterations, and ACS science operations commenced with the pre-SM4 default configuration. Several artifacts attributed to the CEB-R appear in post-SM4 WFC images: large-scale but stable bias gradients, low-level but temporally variable horizontal stripes, a signal-dependent bias shift, and amplifier crosstalk. STScI has developed algorithms for the correction or mitigation of these electronic artifacts as well as for the restoration of images affected by continuously degrading CTE. Standalone correction packages are now or will soon be publicly available. These packages will be incorporated into the calacs package of the OPUS data pipeline by September 2011.

  3. Portable shift register

    SciTech Connect

    Halbig, J.K.; Bourret, S.C.; Hansen, W.J.; Hicks, D.V.; Klosterbuer, S.F.; Krick, M.S.

    1994-01-01

    An electronics package for a small, battery-operated, self-contained, neutron coincidence counter based on a portable shift-register (PSR) has been developed. The counter was developed for applications not adequately addressed by commercial packages, including in-plant measurements to demonstrate compliance with regulations (domestic and international), in-plant process control, and in-field measurements (environmental monitoring or safeguards). Our package's features, which address these applications, include the following: Small size for portability and ease of installation;battery or mains operation; a built-in battery to power the unit and a typical detector such as a small sample counter, for over 6 h if power lines are bad or noisy, if there is a temporary absence of power, or if portability is desired; complete support, including bias, for standard neutron detectors; a powerful communications package to easily facilitate robust external control over a serial port; and a C-library to simplify creating external control programs in computers or other controllers. Whereas the PSR specifically addresses the applications mentioned above, it also performs all the measurements made by previous electronics packages for neutron coincidence counters developed at Los Alamos and commercialized. The PSR electronics package, exclusive of carrying handle, is 8 by 10 by 20 cm; it contains the circuit boards, battery, and bias supply and weighs less than 2 kg. This instrument package is the second in an emerging family of portable measurement instruments being developed; the first was the Miniature and Modular Multichannel Analyzer (M[sup 3]CA). The PSR makes extensive use of hardware and software developed for the M[sup 3]CA; like the M[sup 3]CA, it is intended primarily for use with an external controller interfaced over a serial channel.

  4. Mid-infrared signatures of hydroxyl containing water clusters: Infrared laser Stark spectroscopy of OH–H{sub 2}O and OH(D{sub 2}O){sub n} (n = 1-3)

    SciTech Connect

    Hernandez, Federico J.; Brice, Joseph T.; Leavitt, Christopher M.; Liang, Tao; Douberly, Gary E.; Raston, Paul L.; Pino, Gustavo A.

    2015-10-28

    Small water clusters containing a single hydroxyl radical are synthesized in liquid helium droplets. The OH–H{sub 2}O and OH(D{sub 2}O){sub n} clusters (n = 1-3) are probed with infrared laser spectroscopy in the vicinity of the hydroxyl radical OH stretch vibration. Experimental band origins are qualitatively consistent with ab initio calculations of the global minimum structures; however, frequency shifts from isolated OH are significantly over-predicted by both B3LYP and MP2 methods. An effective Hamiltonian that accounts for partial quenching of electronic angular momentum is used to analyze Stark spectra of the OH–H{sub 2}O and OH–D{sub 2}O binary complexes, revealing a 3.70(5) D permanent electric dipole moment. Computations of the dipole moment are in good agreement with experiment when large-amplitude vibrational averaging is taken into account. Polarization spectroscopy is employed to characterize two vibrational bands assigned to OH(D{sub 2}O){sub 2}, revealing two nearly isoenergetic cyclic isomers that differ in the orientation of the non-hydrogen-bonded deuterium atoms relative to the plane of the three oxygen atoms. The dipole moments for these clusters are determined to be approximately 2.5 and 1.8 D for “up-up” and “up-down” structures, respectively. Hydroxyl stretching bands of larger clusters containing three or more D{sub 2}O molecules are observed shifted approximately 300 cm{sup −1} to the red of the isolated OH radical. Pressure dependence studies and ab initio calculations imply the presence of multiple cyclic isomers of OH(D{sub 2}O){sub 3}.

  5. Shift work, safety, and aging.

    PubMed

    Folkard, Simon

    2008-04-01

    It has long been recognized that older shift workers may have shorter and more disturbed day sleeps between successive night shifts than their younger colleagues. This has given rise to considerable concern over the safety of aging shift workers because of the increasing age of the work force and increases in retirement age. Because there have been no direct studies of the combined effects of shift work and age on safety, the present paper begins by reviewing the literature relating safety to features of shift systems. It then considers the general effect of age on occupational injury rates before examining existing evidence of the combined effects of shift work and age on performance capabilities. The results of the literature review indicate that when the a priori risk is constant, there is reasonably clear evidence that injury rates are higher at night, and that they increase over successive night shifts more rapidly than over successive day shifts. Further, although occupational injuries are less frequent in older workers, those that do occur tend to be more serious. Finally, there is some suggestive evidence from studies of objectively measured performance capabilities that older workers may be less able to both maintain their performance over the course of a night shift and cope with longer spans of successive night shifts. It is concluded that it seems possible, even though unproven as yet, that older workers may be at greater risk both to injury and accident on the night shift. There is a strong need for future epidemiological studies of the combined effects of shift work and age on injuries and accidents, and that these should attempt to separate the effects of age per se from those of generation. PMID:18484360

  6. AC electric field induced dielectrophoretic assembly behavior of gold nanoparticles in a wide frequency range

    NASA Astrophysics Data System (ADS)

    Liu, Weiyu; Wang, Chunhui; Ding, Haitao; Shao, Jinyou; Ding, Yucheng

    2016-05-01

    In this work, we focus on frequency-dependence of pearl chain formations (PCF) of gold nanoparticles driven by AC dielectrophoresis (DEP), especially in a low field-frequency range, where induced double-layer charging effect at ideally polarizable surfaces on particle DEP behavior and surrounding liquid motion need not be negligible. As field frequency varies, grown features of DEP assembly structures ranging from low-frequency non-bridged gap to high-frequency single gold nanoparticle-made nanowires bridging the electrodes are demonstrated experimentally. Specifically, at 10 kHz, a kind of novel channel-like structure with parallel opposing banks is formed at the center of interelectrode gap. In stark contrast, at 1 MHz, thin PCF with diameter of 100 nm is created along the shortest distance of the isolation spacing. Moreover, a particular conductive path of nanoparticle chains is produced at 1 MHz in a DEP device embedded with multiple floating electrodes. A theoretical framework taking into account field-induced double-layer polarization at both the particle/electrolyte and electrode/electrolyte interface is developed to correlate these experimental observations with induced-charge electrokinetic (ICEK) phenomenon. And a RC circuit model is helpful in accounting for the formation of this particular non-bridged channel-like structure induced by a low-frequency AC voltage. As compared to thin PCF formed at high field frequency that effectively short circuits the electrode pair, though it is difficult for complete PCF bridging to occur at low frequency, the non-bridged conducting microstructure has potential to further miniaturize the size of electrode gap fabricated by standard micromachining process and may find useful application in biochemical sensing.

  7. High School Teachers Win ACS Prizes

    NASA Astrophysics Data System (ADS)

    Editorial Staff, Jce

    2009-07-01

    William E. Snyder is the 2009 winner of the ACS Division of Chemical Education Central Region Award for Excellence in High School Teaching; Sally Mitchell is the winner of the 2009 James Bryant Conant Award in High School Chemistry Teaching.

  8. Tevatron optics measurements using an AC dipole

    SciTech Connect

    Miyamoto, R.; Kopp, S.E.; Jansson, A.; Syphers, M.J.; /Fermilab

    2007-06-01

    The AC dipole is a device to study beam optics of hadron synchrotrons. It can produce sustained large amplitude oscillations with virtually no emittance growth. A vertical AC dipole for the Tevatron is recently implemented and a maximum oscillation amplitude of 2{sigma} (4{sigma}) at 980 GeV (150 GeV) is achieved [1]. When such large oscillations are measured with the BPM system of the Tevatron (20 {micro}m resolution), not only linear but even nonlinear optics can be directly measured. This paper shows how to measure {beta} function using an AC dipole and the result is compared to the other measurement. The paper also shows a test to detect optics changes when small changes are made in the Tevatron. Since an AC dipole is nondestructive, it allows frequent measurements of the optics which is necessary for such an test.

  9. The AC-120: The advanced commercial transport

    NASA Technical Reports Server (NTRS)

    Duran, David; Griffin, Ernest; Mendoza, Saul; Nguyen, Son; Pickett, Tim; Noernberg, Clemm

    1993-01-01

    The main objective of this design was to fulfill a need for a new airplane to replace the aging 100 to 150 passenger, 1500 nautical mile range aircraft such as the Douglas DC9 and Boeing 737-100 airplanes. After researching the future aircraft market, conducting extensive trade studies, and analysis on different configurations, the AC-120 Advanced Commercial Transport final design was achieved. The AC-120's main design features include the incorporation of a three lifting surface configuration which is powered by two turboprop engines. The AC-120 is an economically sensitive aircraft which meets the new FM Stage Three noise requirements, and has lower NO(x) emissions than current turbofan powered airplanes. The AC-120 also improves on its contemporaries in passenger comfort, manufacturing, and operating cost.

  10. Quantized beam shifts in graphene

    SciTech Connect

    de Melo Kort-Kamp, Wilton Junior; Sinitsyn, Nikolai; Dalvit, Diego Alejandro Roberto

    2015-10-08

    We predict the existence of quantized Imbert-Fedorov, Goos-Hanchen, and photonic spin Hall shifts for light beams impinging on a graphene-on-substrate system in an external magnetic field. In the quantum Hall regime the Imbert-Fedorov and photonic spin Hall shifts are quantized in integer multiples of the fine structure constant α, while the Goos-Hanchen ones in multiples of α2. We investigate the influence on these shifts of magnetic field, temperature, and material dispersion and dissipation. An experimental demonstration of quantized beam shifts could be achieved at terahertz frequencies for moderate values of the magnetic field.

  11. Shifts in fisheries management: adapting to regime shifts

    PubMed Central

    King, Jacquelynne R.; McFarlane, Gordon A.; Punt, André E.

    2015-01-01

    For many years, fisheries management was based on optimizing yield and maintaining a target biomass, with little regard given to low-frequency environmental forcing. However, this policy was often unsuccessful. In the last two to three decades, fisheries science and management have undergone a shift towards balancing sustainable yield with conservation, with the goal of including ecosystem considerations in decision-making frameworks. Scientific understanding of low-frequency climate–ocean variability, which is manifested as ecosystem regime shifts and states, has led to attempts to incorporate these shifts and states into fisheries assessment and management. To date, operationalizing these attempts to provide tactical advice has met with limited success. We review efforts to incorporate regime shifts and states into the assessment and management of fisheries resources, propose directions for future investigation and outline a potential framework to include regime shifts and changes in ecosystem states into fisheries management.

  12. Measurement of the blackbody radiation shift of the {sup 133}Cs hyperfine transition in an atomic fountain

    SciTech Connect

    Levi, Filippo; Calonico, Davide; Lorini, Luca; Micalizio, Salvatore; Godone, Aldo

    2004-09-01

    We used a Cs fountain to measure the Stark shift of the ground-state hyperfine transition frequency in cesium (9.2 GHz) due to the electric field of the blackbody radiation. The relative shift at 300 K deduced from our measurements, including the leading and the second-order term in temperature, is (-1.45{+-}0.09)x10{sup -14} and agrees with our recent theoretical evaluation (-1.51{+-}0.07)x10{sup -14} [Micalizio et al. Phys. Rev. A 69, 053401 (2004)]. These values differ from that currently used (-1.735{+-}0.003)x10{sup -14}, with significant implications on frequency standards accuracy, on clocks comparison and on a variety of high-precision physics tests, such as the time stability of fundamental constants.

  13. Tunable room-temperature spin-selective optical Stark effect in solution-processed layered halide perovskites

    PubMed Central

    Giovanni, David; Chong, Wee Kiang; Dewi, Herlina Arianita; Thirumal, Krishnamoorthy; Neogi, Ishita; Ramesh, Ramamoorthy; Mhaisalkar, Subodh; Mathews, Nripan; Sum, Tze Chien

    2016-01-01

    Ultrafast spin manipulation for opto–spin logic applications requires material systems that have strong spin-selective light-matter interaction. Conventional inorganic semiconductor nanostructures [for example, epitaxial II to VI quantum dots and III to V multiple quantum wells (MQWs)] are considered forerunners but encounter challenges such as lattice matching and cryogenic cooling requirements. Two-dimensional halide perovskite semiconductors, combining intrinsic tunable MQW structures and large oscillator strengths with facile solution processability, can offer breakthroughs in this area. We demonstrate novel room-temperature, strong ultrafast spin-selective optical Stark effect in solution-processed (C6H4FC2H4NH3)2PbI4 perovskite thin films. Exciton spin states are selectively tuned by ~6.3 meV using circularly polarized optical pulses without any external photonic cavity (that is, corresponding to a Rabi energy of ~55 meV and equivalent to applying a 70 T magnetic field), which is much larger than any conventional system. The facile halide and organic replacement in these perovskites affords control of the dielectric confinement and thus presents a straightforward strategy for tuning light-matter coupling strength. PMID:27386583

  14. Self-screening of the quantum confined Stark effect by the polarization induced bulk charges in the quantum barriers

    SciTech Connect

    Zhang, Zi-Hui; Liu, Wei; Ju, Zhengang; Tiam Tan, Swee; Ji, Yun; Kyaw, Zabu; Zhang, Xueliang; Wang, Liancheng; Wei Sun, Xiao E-mail: volkan@stanfordalumni.org; Volkan Demir, Hilmi E-mail: volkan@stanfordalumni.org

    2014-06-16

    InGaN/GaN light-emitting diodes (LEDs) grown along the polar orientations significantly suffer from the quantum confined Stark effect (QCSE) caused by the strong polarization induced electric field in the quantum wells, which is a fundamental problem intrinsic to the III-nitrides. Here, we show that the QCSE is self-screened by the polarization induced bulk charges enabled by designing quantum barriers. The InN composition of the InGaN quantum barrier graded along the growth orientation opportunely generates the polarization induced bulk charges in the quantum barrier, which well compensate the polarization induced interface charges, thus avoiding the electric field in the quantum wells. Consequently, the optical output power and the external quantum efficiency are substantially improved for the LEDs. The ability to self-screen the QCSE using polarization induced bulk charges opens up new possibilities for device engineering of III-nitrides not only in LEDs but also in other optoelectronic devices.

  15. Facultatively internal fertilization and anomalous embryonic development of a non-copulatory sculpin Hemilepidotus gilberti Jordan and Starks (Scorpaeniformes: Cottidae).

    PubMed

    Hayakawa; Munehara

    2001-01-01

    Fertilized residual eggs were observed in the ovaries of spent females of a non-copulatory sculpin Hemilepidotus gilberti Jordan and Starks. Fertilized eggs were present in 23 of 35 females, and approximately 38% of the total residual eggs (n=227) were fertilized. These eggs were thought to be fertilized facultatively with spermatozoa that entered the ovary through ovarian fluid during spawning. The high calcium concentration (1.42+/-0.21 mM kg(-1)) in ovarian fluid, which is beyond the threshold concentration required for fertilization, may allow internal fertilization to occur. Embryos at various developmental stages were observed, but all were deformed and surrounded by unhardened chorions. Since no larvae were observed, all the fertilized residual eggs would have degenerated in the ovary in accordance with other unfertilized residual eggs. These observations suggest that the ovary of the oviparous fish H. gilberti is an unsuitable environment for embryos to develop, possibly because it may be unable to supply developing embryos with needed elements, such as oxygen.

  16. Infrared Laser Stark Spectroscopy of the OH\\cdot\\cdot\\cdotCH3OH Complex Isolated in Superfluid Helium Droplets

    NASA Astrophysics Data System (ADS)

    Leavitt, Christopher M.; Brice, Joseph T.; Douberly, Gary E.; Hernandez, Federico J.; Pino, Gustavo A.

    2015-06-01

    The elimination of volatile organic compounds (VOCs) from the atmosphere is initiated by reactions with OH, NO3 and O3. For oxygenated VOCs, such as alcohols, ketones, ethers, etc., reactions occur nearly exclusively with the hydroxyl radical. Furthermore, the potential energy surfaces associated with reactions between OH and oxygenated VOCs generally feature a pre-reactive complex, stabilized by hydrogen bonding, which results in rate constants that exhibit large negative temperature dependencies. This was explicitly demonstrated recently for the OH + methanol (MeOH) reaction, where the rate constant increased by nearly two orders of magnitude when the temperature decreased from 200 K to below 70 K, highlighting the potential impact of this reaction in the interstellar medium (ISM). In this study, we trap this postulated pre-reactive complex formed between OH and MeOH using He nanodroplet isolation (HENDI) techniques, and probe this species using a combination of mass spectrometry and infrared laser Stark spectroscopy. Atkinson, R.; Arey, J., Chem. Rev. 2003, 103, 4605-4638. Mellouki, A.; Le Bras, G.; Sidebottom, H., Chem. Rev. 2003, 103, 5077-5096. Smith, I. W. M.; Ravishankara, A. R., J. Phys. Chem. A 2002, 106, 4798-4807 Shannon, R. J.; Blitz, M. A.; Goddard, A.; Heard, D. E., Nat. Chem. 2013, 5, 745-749. Martin, J. C. G.; Caravan, R. L.; Blitz, M. A.; Heard, D. E.; Plane, J. M. C., J. Phys. Chem. A 2014, 118, 2693-2701.

  17. Tunable room-temperature spin-selective optical Stark effect in solution-processed layered halide perovskites.

    PubMed

    Giovanni, David; Chong, Wee Kiang; Dewi, Herlina Arianita; Thirumal, Krishnamoorthy; Neogi, Ishita; Ramesh, Ramamoorthy; Mhaisalkar, Subodh; Mathews, Nripan; Sum, Tze Chien

    2016-06-01

    Ultrafast spin manipulation for opto-spin logic applications requires material systems that have strong spin-selective light-matter interaction. Conventional inorganic semiconductor nanostructures [for example, epitaxial II to VI quantum dots and III to V multiple quantum wells (MQWs)] are considered forerunners but encounter challenges such as lattice matching and cryogenic cooling requirements. Two-dimensional halide perovskite semiconductors, combining intrinsic tunable MQW structures and large oscillator strengths with facile solution processability, can offer breakthroughs in this area. We demonstrate novel room-temperature, strong ultrafast spin-selective optical Stark effect in solution-processed (C6H4FC2H4NH3)2PbI4 perovskite thin films. Exciton spin states are selectively tuned by ~6.3 meV using circularly polarized optical pulses without any external photonic cavity (that is, corresponding to a Rabi energy of ~55 meV and equivalent to applying a 70 T magnetic field), which is much larger than any conventional system. The facile halide and organic replacement in these perovskites affords control of the dielectric confinement and thus presents a straightforward strategy for tuning light-matter coupling strength. PMID:27386583

  18. Optical Stark Spectroscopy of the tilde{A}2Π- tilde{X}2Σ+ Band of BaOH

    NASA Astrophysics Data System (ADS)

    Frey, Sarah E.; Steimle, Timothy C.

    2011-06-01

    Transitions of the tilde{A}2Π- tilde{X}2Σ+ band system of barium monohydroxide, BaOH, were observed and recorded from 11483-11485 Cm-1 and 12041-12044 Cm-1. The features were readily identified using the results of the Doppler-limited measurements. The laser induced fluorescence (LIF) spectrum was analyzed to give optimized field-free excited state parameters. The parameters for the tilde{X}2Σ+ state were constrained to the previously determined values. The permanent electric dipole moments for the tilde{X}2Σ+ and tilde{A}2Π states have been determined from the analysis of the optical Stark spectra for the R21(0.5), Q21(1.5), and R2(0.5) lines. The obtained values were μ(tilde{X}2Σ+)= 1.426(38)D and μ(tilde{A}2Π)= 0.477(7) D. The results are compared with predicted values from semi-empirical models and those for CaOH and SrOH. J. G. Wang, J. D. Tandy and P. F. Bernath J. Mol. Spectrosc. 252, 31 (2008) M. A. Anderson, M. D. Allen, W. L. Barclay, Jr, and L. M. Ziurys Chem. Phys. Lett 205, 415 (1993) T. C. Steimle, D. A. Fletcher, K. Y. Jung and C. T. Scurlock J. Chem. Phys. 96, 2556 (1992).

  19. Water-gas shift reaction

    SciTech Connect

    Newsome, D.S.

    1980-01-01

    A review covers the industrial applications of the water-gas shift reaction in hydrogen manufacturing, removing CO from ammonia synthesis feeds, and detoxifying town gas; and the catalyst characteristics, reaction kinetics, and reaction mechanisms of the water-gas shift reactions catalyzed by iron-based, copper-based, or sulfided cobalt-molybdenum catalysts.

  20. The Compton Effect Red Shift

    NASA Astrophysics Data System (ADS)

    Kierein, John

    2004-05-01

    In 1923 (Phil Mag. 46, 897.) A. H. Compton noted that the Compton effect produces a red shift for all wavelengths when the scattered electron is free and not bound to an atom or molecule. He suggested that the red shift in the visible spectrum at the limb of the sun is larger than that at the center due to the Compton effect from the greater number of free electrons in the sun's atmosphere along the line of sight. Kierein and Sharp (1968, Solar Physics 3, 450) quantified this and showed a good correlation of red shift observations with the variation in the number of these electrons along the line of sight from center to limb and suggested that the quasar red shift and cosmological red shift could be similarly explained. Grote Reber mapped and measured the background hectometric radiation and found it to be unexpectedly bright. In 1968 (J. Franklin Inst. 285,1), while describing these measurements and maps he explained this brightness as being due to the Compton effect causing the cosmological red shift and accelerating intergalactic electrons. The resulting universe is static. The predicted red shift from the Compton effect deviates from Hubble's law only at large red shifts.

  1. 78 FR 39345 - ACS Wireless, Inc.; Notice of Application

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-07-01

    ... COMMISSION ACS Wireless, Inc.; Notice of Application AGENCY: Securities and Exchange Commission (``Commission...''). Summary of Application: ACS Wireless, Inc. (``ACS Wireless'') seeks an order under section 3(b)(2) of the..., owning, holding or trading in securities. ACS Wireless is primarily engaged in providing...

  2. 21 CFR 888.1240 - AC-powered dynamometer.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false AC-powered dynamometer. 888.1240 Section 888.1240...) MEDICAL DEVICES ORTHOPEDIC DEVICES Diagnostic Devices § 888.1240 AC-powered dynamometer. (a) Identification. An AC-powered dynamometer is an AC-powered device intended for medical purposes to...

  3. 21 CFR 886.4440 - AC-powered magnet.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false AC-powered magnet. 886.4440 Section 886.4440 Food... DEVICES OPHTHALMIC DEVICES Surgical Devices § 886.4440 AC-powered magnet. (a) Identification. An AC-powered magnet is an AC-powered device that generates a magnetic field intended to find and...

  4. 21 CFR 886.1630 - AC-powered photostimulator.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false AC-powered photostimulator. 886.1630 Section 886...) MEDICAL DEVICES OPHTHALMIC DEVICES Diagnostic Devices § 886.1630 AC-powered photostimulator. (a) Identification. An AC-powered photostimulator is an AC-powered device intended to provide light stimulus...

  5. 21 CFR 886.1850 - AC-powered slitlamp biomicroscope.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false AC-powered slitlamp biomicroscope. 886.1850... (CONTINUED) MEDICAL DEVICES OPHTHALMIC DEVICES Diagnostic Devices § 886.1850 AC-powered slitlamp biomicroscope. (a) Identification. An AC-powered slitlamp biomicroscope is an AC-powered device that is...

  6. 21 CFR 886.4440 - AC-powered magnet.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false AC-powered magnet. 886.4440 Section 886.4440 Food... DEVICES OPHTHALMIC DEVICES Surgical Devices § 886.4440 AC-powered magnet. (a) Identification. An AC-powered magnet is an AC-powered device that generates a magnetic field intended to find and...

  7. 21 CFR 886.4440 - AC-powered magnet.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false AC-powered magnet. 886.4440 Section 886.4440 Food... DEVICES OPHTHALMIC DEVICES Surgical Devices § 886.4440 AC-powered magnet. (a) Identification. An AC-powered magnet is an AC-powered device that generates a magnetic field intended to find and...

  8. 21 CFR 886.4440 - AC-powered magnet.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false AC-powered magnet. 886.4440 Section 886.4440 Food... DEVICES OPHTHALMIC DEVICES Surgical Devices § 886.4440 AC-powered magnet. (a) Identification. An AC-powered magnet is an AC-powered device that generates a magnetic field intended to find and...

  9. 21 CFR 886.4440 - AC-powered magnet.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false AC-powered magnet. 886.4440 Section 886.4440 Food... DEVICES OPHTHALMIC DEVICES Surgical Devices § 886.4440 AC-powered magnet. (a) Identification. An AC-powered magnet is an AC-powered device that generates a magnetic field intended to find and...

  10. Metabolic impact of shift work.

    PubMed

    Zimberg, Ioná Zalcman; Fernandes Junior, Silvio A; Crispim, Cibele Aparecida; Tufik, Sergio; de Mello, Marco Tulio

    2012-01-01

    In developing countries, shift work represents a considerable contingent workforce. Recently, studies have shown that overweight and obesity are more prevalent in shift workers than day workers. In addition, shift work has been associated with a higher propensity for the development of many metabolic disorders, such as insulin resistance, diabetes, dislipidemias and metabolic syndrome. Recent data have pointed that decrease of the sleep time, desynchronization of circadian rhythm and alteration of environmental aspects are the main factors related to such problems. Shortened or disturbed sleep is among the most common health-related effects of shift work. The plausible physiological and biological mechanisms are related to the activation of the autonomic nervous system, inflammation, changes in lipid and glucose metabolism, and related changes in the risk for atherosclerosis, metabolic syndrome, and type II diabetes. The present review will discuss the impact of shift work on obesity and metabolic disorders and how disruption of sleep and circadian misalignment may contribute to these metabolic dysfunctions.

  11. Local Electric Field Strength in a Hollow Cathode Determined by Stark Splitting of the 2S Level of Hydrogen Isotopes by Optogalvanic Spectroscopy

    SciTech Connect

    Perez, C.; Rosa, M. I. de la; Gruetzmacher, K.; Fuentes, L. M.; Gonzalo, A. B.

    2008-10-22

    In this work we present Doppler-free two-photon optogalvanic spectroscopy as a tool to measure the electric field strength in the cathode fall region of a hollow cathode discharge via the Stark splitting of the 2S level of atomic deuterium. The strong electric field strength present in the hollow cathode is determined for various discharge conditions which allows studying the corresponding variations of the cathode fall, and its changes with discharge operation time.

  12. Systematic experimental study of the Stark broadening of C II, C III, N II, N III, O II and O III spectral lines

    SciTech Connect

    Blagojevic, B.; Popovic, M. V.; Konjevic, N.

    1999-04-01

    We report the experimental Stark widths of plasma broadened lines belonging to 3s-3p and 3p-3d transitions of singly and doubly ionized C, N and O emitters. The light source was a low pressure pulsed arc. The plasma electron densities were determined from the width of the Hell P{sub {alpha}} line while the electron temperatures were measured from the relative line intensities of five N II spectral lines.

  13. AC Electrokinetics of Physiological Fluids for Biomedical Applications.

    PubMed

    Lu, Yi; Liu, Tingting; Lamanda, Ariana C; Sin, Mandy L Y; Gau, Vincent; Liao, Joseph C; Wong, Pak Kin

    2015-12-01

    Alternating current (AC) electrokinetics is a collection of processes for manipulating bulk fluid mass and embedded objects with AC electric fields. The ability of AC electrokinetics to implement the major microfluidic operations, such as pumping, mixing, concentration, and separation, makes it possible to develop integrated systems for clinical diagnostics in nontraditional health care settings. The high conductivity of physiological fluids presents new challenges and opportunities for AC electrokinetics-based diagnostic systems. In this review, AC electrokinetic phenomena in conductive physiological fluids are described followed by a review of the basic microfluidic operations and the recent biomedical applications of AC electrokinetics. The future prospects of AC electrokinetics for clinical diagnostics are presented.

  14. Cancellation of nonlinear Zeeman shifts with light shifts

    NASA Astrophysics Data System (ADS)

    Jensen, K.; Acosta, V. M.; Higbie, J. M.; Ledbetter, M. P.; Rochester, S. M.; Budker, D.

    2009-02-01

    Nonlinear Zeeman (NLZ) shifts arising from magnetic-field mixing of the two hyperfine ground states in alkali-metal atoms lead to splitting of magnetic-resonance lines. This is a major source of sensitivity degradation and the so-called “heading errors” of alkali-metal-vapor atomic magnetometers operating in the geophysical field range (B≈0.2-0.7G) . Here, it is shown theoretically and experimentally that NLZ shifts can be effectively canceled by light shifts caused by a laser field of appropriate intensity, polarization, and frequency, a technique that can be readily applied in practical situations.

  15. Deletion of AcMNPV ac146 eliminates the production of budded virus.

    PubMed

    Dickison, Virginia L; Willis, Leslie G; Sokal, Nadia R; Theilmann, David A

    Autographa californica multiple nucleopolyhedrovirus (AcMNPV) ac146 is a highly conserved gene in the Alpha- and Betabaculovirus genera that has an unknown function. Northern blot analysis and transcript mapping showed that ac146 is transcribed at late times post infection as a 1.2 kb mRNA. To determine the role of ac146 in the baculovirus life cycle ac146 knock out viruses were constructed. Transfection and plaque assays showed that all the ac146 deletions produced a single cell phenotype indicating that no infectious budded virus (BV) was produced, however occlusion bodies were formed. The lack of BV production was confirmed by viral titration utilizing both qPCR and TCID₅₀. Analysis of BV and occlusion derived virus (ODV) revealed that AC146 is associated with both forms of the virus and is modified specifically in ODV. This study therefore demonstrates that AC146 is a late virion associated protein and is essential for the viral life cycle.

  16. Health effects of shift work.

    PubMed

    LaDou, J

    1982-12-01

    More than 13.5 million American workers, close to 20 percent of the work force, are assigned to evening or night shifts. In some industries such as automobile, petrochemical and textile manufacturing the proportion of shift workers is greater than 50 percent. As the popularity of shift work and other "alternative work schedules" grows, concern is increasing over the disturbance created in the lives of workers and their families by these economically and socially useful innovations. Twenty percent of workers are unable to tolerate shift work. Daily physiologic variations termed circadian rhythms are interactive and require a high degree of phase relationship to produce subjective feelings of wellbeing. Disturbance of these activities, circadian desynchronization, whether from passage over time zones or from shift rotation, results in health effects such as disturbance of the quantity and quality of sleep, disturbance of gastrointestinal and other organ system activities, and aggravation of diseases such as diabetes mellitus, epilepsy and thyrotoxicosis. Worker selection can reduce the number of health problems resulting from shift work. The periodic examination of shift workers is recommended.

  17. Health Effects of Shift Work

    PubMed Central

    LaDou, Joseph

    1982-01-01

    More than 13.5 million American workers, close to 20 percent of the work force, are assigned to evening or night shifts. In some industries such as automobile, petrochemical and textile manufacturing the proportion of shift workers is greater than 50 percent. As the popularity of shift work and other “alternative work schedules” grows, concern is increasing over the disturbance created in the lives of workers and their families by these economically and socially useful innovations. Twenty percent of workers are unable to tolerate shift work. Daily physiologic variations termed circadian rhythms are interactive and require a high degree of phase relationship to produce subjective feelings of wellbeing. Disturbance of these activities, circadian desynchronization, whether from passage over time zones or from shift rotation, results in health effects such as disturbance of the quantity and quality of sleep, disturbance of gastrointestinal and other organ system activities, and aggravation of diseases such as diabetes mellitus, epilepsy and thyrotoxicosis. Worker selection can reduce the number of health problems resulting from shift work. The periodic examination of shift workers is recommended. PMID:6962577

  18. [Shift work and cardiometabolic risk].

    PubMed

    Copertaro, Alfredo; Barbaresi, Mariella; Bracci, Massimo

    2009-11-01

    Shift work is frequently associated with coronary heart disease. Medical research indicate metabolic disturbance among shift workers, which is characterized by associated modifications in the concentration of serum glucose and serum lipids, hypertension and obesity, especially addominal weight. Atrasversal study has been carried out: 193 (126 females and 67 males) healthcare shift workers were compared with 221 (160 females and 61 males) day workers. Medical history, health examination including anthropometric and arterial blood pressure measurements were assessed. All participants were submitted a standardized questionnaire on health-related behaviours and biochemical determinations (fasting plasma glucose, HDL-cholesterol, triglycerides). Job seniority of shift work resulted at 13.5 +/- 8.2 among shift workers and 19.0 +/- 11.3 among day workers. Assessment of the metabolic syndrome relevance was defined according to the criterions proposed by the International Diabetes Federation. The 20% shift workers (33% males and 13% females) was affected by metabolic syndrome against 12% non shift workers (20% males and 9% females). The most frequently altered parameter, apart from metabolic syndrome, was high abdominal obesity, which occurred in 64% of the sample (70% shift workers vs 58% day workers). The results of multiple logistic regression attested the presence of a higher relative risk among shift workers regarding both the prevalence of a metabolic syndrome (OR 2,1 - 95% Cl 1.15-3.86) and the excess in abdominal obesity (OR 1.8 - 95% Cl 1.16-3.25). After adjusting confusing factors such as smoke, age, alchool, consumption, physical activity, scholastic degree, a OR 2.9 - 95%Cl 1,53-5.53 and a OR 1.9 - 95%.Cl 1.32-3.86 were confirmed. PMID:20066881

  19. Cyclotron and linac production of Ac-225.

    PubMed

    Melville, Graeme; Allen, Barry J

    2009-04-01

    Radium needles that were once implanted into tumours as a cancer treatment are now obsolete and constitute a radioactive waste problem, as their half-life is 1600 years. The reduction of radium by photonuclear transmutation by bombarding Ra-226 with high-energy photons from a medical linear accelerator (linac) has been investigated. A linac dose of 2800 Gy produced about 2.4 MBq (64 microCi) of Ra-225, which decays to Ac-225 and can then be used for 'Targeted Alpha Therapy' (TAT) of cancer. This result, while consistent with theoretical calculations, is far too low to be of practical use unless much larger quantities of radium are irradiated. The increasing application of Ac-225 for cancer therapy indicates the potential need for its increased production and availability. This paper investigates the possibility of producing of Ac-225 in commercial quantities, which could potentially reduce obsolete radioactive material and displace the need for expensive importation of Ac-225 from the USA and Russia in the years ahead. Scaled up production of Ac-225 could theoretically be achieved by the use of a high current cyclotron or linac. Production specifications are determined for a linac in terms of current, pulse length and frequency, as well as an examination of other factors such as radiation issues and radionuclei separation. Yields are compared with those calculated for the Australian National Cyclotron in Sydney.

  20. Design and synthesis of 225Ac radioimmunopharmaceuticals.

    PubMed

    McDevitt, Michael R; Ma, Dangshe; Simon, Jim; Frank, R Keith; Scheinberg, David A

    2002-12-01

    The alpha-particle-emitting radionuclides 213Bi, 211At, 224Ra are under investigation for the treatment of leukemias, gliomas, and ankylosing spondylitis, respectively. 213Bi and 211At were attached to monoclonal antibodies and used as targeted immunotherapeutic agents while unconjugated 224Ra chloride selectively seeks bone. 225Ac possesses favorable physical properties for radioimmunotherapy (10d half-life and 4 net alpha particles), but has a history of unfavorable radiolabeling chemistry and poor metal-chelate stability. We selected functionalized derivatives of DOTA as the most promising to pursue from out of a group of potential 225Ac chelate compounds. A two-step synthetic process employing either MeO-DOTA-NCS or 2B-DOTA-NCS as the chelating moiety was developed to attach 225Ac to monoclonal antibodies. This method was tested using several different IgG systems. The chelation reaction yield in the first step was 93+/-8% radiochemically pure (n=26). The second step yielded 225Ac-DOTA-IgG constructs that were 95+/-5% radiochemically pure (n=27) and the mean percent immunoreactivity ranged from 25% to 81%, depending on the antibody used. This process has yielded several potential novel targeted 225Ac-labeled immunotherapeutic agents that may now be evaluated in appropriate model systems and ultimately in humans.

  1. ac propulsion system for an electric vehicle

    NASA Technical Reports Server (NTRS)

    Geppert, S.

    1980-01-01

    It is pointed out that dc drives will be the logical choice for current production electric vehicles (EV). However, by the mid-80's, there is a good chance that the price and reliability of suitable high-power semiconductors will allow for a competitive ac system. The driving force behind the ac approach is the induction motor, which has specific advantages relative to a dc shunt or series traction motor. These advantages would be an important factor in the case of a vehicle for which low maintenance characteristics are of primary importance. A description of an EV ac propulsion system is provided, taking into account the logic controller, the inverter, the motor, and a two-speed transmission-differential-axle assembly. The main barrier to the employment of the considered propulsion system in EV is not any technical problem, but inverter transistor cost.

  2. Atrial-caval shunting (ACS) after trauma.

    PubMed

    Kudsk, K A; Sheldon, G F; Lim, R C

    1982-02-01

    Since 1968 the atrial-caval shunt (ACS), along with inflow occlusion at the porta hepatis, has been used at San Francisco General Hospital in 18 trauma patients to control massive hemorrhage from the inferior vena cava, hepatic veins, or liver. Thirteen patients died from irreversible shock. Five patients survived their initial injuries; one of them died 45 days later from the complications of shock and sepsis. No patients survived who sustained blunt trauma and were admitted in cardiac arrest. Only one of ten patients with BP less than 70 mm Hg after resuscitation survived, whereas four of eight with BP greater than 70 mm Hg survived. ACS was used to control caval injuries in seven patients (one survivor), severe hepatic parenchymal fractures in four patients (two survivors), and combined hepatic and caval injuries in seven patients (two survivors). Survivors had an average of 5.75 associated injuries; nonsurvivors had 3.8. No complications of ACS occurred in the surviving patients.

  3. Beneficial Effects of Adenylyl Cyclase Type 6 (AC6) Expression Persist Using a Catalytically Inactive AC6 Mutant

    PubMed Central

    Tang, Tong; Lai, Ngai Chin; Miyanohara, Atsushi; Guo, Tracy; Tang, Rouying; Firth, Amy L.; Yuan, Jason X.; Hammond, H. Kirk

    2011-01-01

    Cardiac-directed expression of AC6 has pronounced favorable effects on cardiac function possibly not linked with cAMP production. To determine rigorously whether cAMP generation is required for the beneficial effects of increased AC6 expression, we generated a catalytically inactive AC6 mutant (AC6mut) that has markedly diminished cAMP generating capacity by replacing aspartic acid with alanine at position 426 in the C1 domain (catalytic region) of AC6. Gene transfer of AC6 or AC6mut (adenovirus-mediated) in adult rat cardiac myocytes resulted in similar expression levels and intracellular distribution, but AC6mut expression was associated with marked reduction in cAMP production. Despite marked reduction in cAMP generation, AC6mut influenced intracellular signaling events similarly to that observed after expression of catalytically intact AC6. For example, both AC6 and AC6mut reduced phenylephrine-induced cardiac myocyte hypertrophy and apoptosis (p < 0.001), expression of cardiac ankyrin repeat protein (p < 0.01), and phospholamban (p < 0.05). AC6mut expression, similar to its catalytically intact cohort, was associated with increased Ca2+ transients in cardiac myocytes after isoproterenol stimulation. Many of the biological effects of AC6 expression are replicated by a catalytically inactive AC6 mutant, indicating that the mechanisms for these effects do not require increased cAMP generation. PMID:21127130

  4. Refining the shifted topological vertex

    SciTech Connect

    Drissi, L. B.; Jehjouh, H.; Saidi, E. H.

    2009-01-15

    We study aspects of the refining and shifting properties of the 3d MacMahon function C{sub 3}(q) used in topological string theory and BKP hierarchy. We derive the explicit expressions of the shifted topological vertex S{sub {lambda}}{sub {mu}}{sub {nu}}(q) and its refined version T{sub {lambda}}{sub {mu}}{sub {nu}}(q,t). These vertices complete results in literature.

  5. A novel wireless power and data transmission AC to DC converter for an implantable device.

    PubMed

    Liu, Jhao-Yan; Tang, Kea-Tiong

    2013-01-01

    This article presents a novel AC to DC converter implemented by standard CMOS technology, applied for wireless power transmission. This circuit combines the functions of the rectifier and DC to DC converter, rather than using the rectifier to convert AC to DC and then supplying the required voltage with regulator as in the transitional method. This modification can reduce the power consumption and the area of the circuit. This circuit also transfers the loading condition back to the external circuit by the load shift keying(LSK), determining if the input power is not enough or excessive, which increases the efficiency of the total system. The AC to DC converter is fabricated with the TSMC 90nm CMOS process. The circuit area is 0.071mm(2). The circuit can produce a 1V DC voltage with maximum output current of 10mA from an AC input ranging from 1.5V to 2V, at 1MHz to 10MHz. PMID:24110077

  6. A novel wireless power and data transmission AC to DC converter for an implantable device.

    PubMed

    Liu, Jhao-Yan; Tang, Kea-Tiong

    2013-01-01

    This article presents a novel AC to DC converter implemented by standard CMOS technology, applied for wireless power transmission. This circuit combines the functions of the rectifier and DC to DC converter, rather than using the rectifier to convert AC to DC and then supplying the required voltage with regulator as in the transitional method. This modification can reduce the power consumption and the area of the circuit. This circuit also transfers the loading condition back to the external circuit by the load shift keying(LSK), determining if the input power is not enough or excessive, which increases the efficiency of the total system. The AC to DC converter is fabricated with the TSMC 90nm CMOS process. The circuit area is 0.071mm(2). The circuit can produce a 1V DC voltage with maximum output current of 10mA from an AC input ranging from 1.5V to 2V, at 1MHz to 10MHz.

  7. Transient AC voltage related phenomena for HVDC schemes connected to weak AC systems

    SciTech Connect

    Pilotto, L.A.S.; Szechtman, M. ); Hammad, A.E. )

    1992-07-01

    In this paper a didactic explanation of voltage stability associated phenomena at HVDC terminals is presented. Conditions leading to ac voltage collapse problems are identified. A mechanism that excites control-induced voltage oscillations is shown. The voltage stability factor is used for obtaining the maximum power limits of ac/dc systems operating with different control strategies. Correlation to Pd {times} Id curves is given. Solutions for eliminating the risks of voltage collapse and for avoiding control-induced oscillations are discussed. The results are supported by detailed digital simulations of a weak ac/dc system using EMTP.

  8. Synthesis of Visible-Light-Responsive Cu and N-Codoped AC/TiO2 Photocatalyst Through Microwave Irradiation.

    PubMed

    Tian, Fei; Wu, Zhansheng; Yan, Yujun; Ye, Bang-Ce; Liu, Dandan

    2016-12-01

    N-Cu-activated carbon (AC)/TiO2 nanoparticles were prepared by the sol-gel technique through microwave irradiation to modify the visible-light response of TiO2. Their structure, surface chemical composition, and optical absorption properties were characterized. The results showed that the codoped particles had a higher surface area and smaller particle size than pure AC/TiO2 and monodoped AC/TiO2. X-ray photoelectron spectroscopy of N-Cu-AC/TiO2 showed that Cu atoms replaced Ti atom sites, whereas N atoms occupied the O atom sites and interstitial sites in the TiO2 lattice, which changed the electric and band-gap structures of the photocatalyst. N or Cu monodoping of AC/TiO2 reduced the energy band gap of TiO2 from 2.86 eV to 2.81 or 2.61 eV, respectively. In (N, Cu)-codoped AC/TiO2, N and Cu were incorporated into the TiO2 framework and narrowed the band gap of TiO2 to 2.47 eV, causing a large red shift and enhancing visible-light utilization efficiency. Photocatalytic activities were further examined by formaldehyde degradation under visible-light irradiation. N-Cu-AC/TiO2 was found to have the highest activity (ca. 94.4 % formaldehyde degradation efficiency) and to be easily recyclable. These results show an important and innovative method of improving AC/TiO2 activity by modifying the nonmetallic and metallic species.

  9. Synthesis of Visible-Light-Responsive Cu and N-Codoped AC/TiO2 Photocatalyst Through Microwave Irradiation

    NASA Astrophysics Data System (ADS)

    Tian, Fei; Wu, Zhansheng; Yan, Yujun; Ye, Bang-Ce; Liu, Dandan

    2016-06-01

    N-Cu-activated carbon (AC)/TiO2 nanoparticles were prepared by the sol-gel technique through microwave irradiation to modify the visible-light response of TiO2. Their structure, surface chemical composition, and optical absorption properties were characterized. The results showed that the codoped particles had a higher surface area and smaller particle size than pure AC/TiO2 and monodoped AC/TiO2. X-ray photoelectron spectroscopy of N-Cu-AC/TiO2 showed that Cu atoms replaced Ti atom sites, whereas N atoms occupied the O atom sites and interstitial sites in the TiO2 lattice, which changed the electric and band-gap structures of the photocatalyst. N or Cu monodoping of AC/TiO2 reduced the energy band gap of TiO2 from 2.86 eV to 2.81 or 2.61 eV, respectively. In (N, Cu)-codoped AC/TiO2, N and Cu were incorporated into the TiO2 framework and narrowed the band gap of TiO2 to 2.47 eV, causing a large red shift and enhancing visible-light utilization efficiency. Photocatalytic activities were further examined by formaldehyde degradation under visible-light irradiation. N-Cu-AC/TiO2 was found to have the highest activity (ca. 94.4 % formaldehyde degradation efficiency) and to be easily recyclable. These results show an important and innovative method of improving AC/TiO2 activity by modifying the nonmetallic and metallic species.

  10. AcsA-AcsB: The core of the cellulose synthase complex from Gluconacetobacter hansenii ATCC23769.

    PubMed

    McManus, John B; Deng, Ying; Nagachar, Nivedita; Kao, Teh-hui; Tien, Ming

    2016-01-01

    The gram-negative bacterium, Gluconacetobacter hansenii, produces cellulose of exceptionally high crystallinity in comparison to the cellulose of higher plants. This bacterial cellulose is synthesized and extruded into the extracellular medium by the cellulose synthase complex (CSC). The catalytic component of this complex is encoded by the gene AcsAB. However, several other genes are known to encode proteins critical to cellulose synthesis and are likely components of the bacterial CSC. We have purified an active heterodimer AcsA-AcsB from G. hansenii ATCC23769 to homogeneity by two different methods. With the purified protein, we have determined how it is post-translationally processed, forming the active heterodimer AcsA-AcsB. Additionally, we have performed steady-state kinetic studies on the AcsA-AcsB complex. Finally through mutagenesis studies, we have explored the roles of the postulated CSC proteins AcsC, AcsD, and CcpAx. PMID:26672449

  11. AcsA-AcsB: The core of the cellulose synthase complex from Gluconacetobacter hansenii ATCC23769.

    PubMed

    McManus, John B; Deng, Ying; Nagachar, Nivedita; Kao, Teh-hui; Tien, Ming

    2016-01-01

    The gram-negative bacterium, Gluconacetobacter hansenii, produces cellulose of exceptionally high crystallinity in comparison to the cellulose of higher plants. This bacterial cellulose is synthesized and extruded into the extracellular medium by the cellulose synthase complex (CSC). The catalytic component of this complex is encoded by the gene AcsAB. However, several other genes are known to encode proteins critical to cellulose synthesis and are likely components of the bacterial CSC. We have purified an active heterodimer AcsA-AcsB from G. hansenii ATCC23769 to homogeneity by two different methods. With the purified protein, we have determined how it is post-translationally processed, forming the active heterodimer AcsA-AcsB. Additionally, we have performed steady-state kinetic studies on the AcsA-AcsB complex. Finally through mutagenesis studies, we have explored the roles of the postulated CSC proteins AcsC, AcsD, and CcpAx.

  12. A dry-cooled AC quantum voltmeter

    NASA Astrophysics Data System (ADS)

    Schubert, M.; Starkloff, M.; Peiselt, K.; Anders, S.; Knipper, R.; Lee, J.; Behr, R.; Palafox, L.; Böck, A. C.; Schaidhammer, L.; Fleischmann, P. M.; Meyer, H.-G.

    2016-10-01

    The paper describes a dry-cooled AC quantum voltmeter system operated up to kilohertz frequencies and 7 V rms. A 10 V programmable Josephson voltage standard (PJVS) array was installed on a pulse tube cooler (PTC) driven with a 4 kW air-cooled compressor. The operating margins at 70 GHz frequencies were investigated in detail and found to exceed 1 mA Shapiro step width. A key factor for the successful chip operation was the low on-chip power consumption of 65 mW in total. A thermal interface between PJVS chip and PTC cold stage was used to avoid a significant chip overheating. By installing the cryocooled PJVS array into an AC quantum voltmeter setup, several calibration measurements of dc standards and calibrator ac voltages up to 2 kHz frequencies were carried out to demonstrate the full functionality. The results are discussed and compared to systems with standard liquid helium cooling. For dc voltages, a direct comparison measurement between the dry-cooled AC quantum voltmeter and a liquid-helium based 10 V PJVS shows an agreement better than 1 part in 1010.

  13. AC power generation from microbial fuel cells

    NASA Astrophysics Data System (ADS)

    Lobo, Fernanda Leite; Wang, Heming; Forrestal, Casey; Ren, Zhiyong Jason

    2015-11-01

    Microbial fuel cells (MFCs) directly convert biodegradable substrates to electricity and carry good potential for energy-positive wastewater treatment. However, the low and direct current (DC) output from MFC is not usable for general electronics except small sensors, yet commercial DC-AC converters or inverters used in solar systems cannot be directly applied to MFCs. This study presents a new DC-AC converter system for MFCs that can generate alternating voltage in any desired frequency. Results show that AC power can be easily achieved in three different frequencies tested (1, 10, 60 Hz), and no energy storage layer such as capacitors was needed. The DC-AC converter efficiency was higher than 95% when powered by either individual MFCs or simple MFC stacks. Total harmonic distortion (THD) was used to investigate the quality of the energy, and it showed that the energy could be directly usable for linear electronic loads. This study shows that through electrical conversion MFCs can be potentially used in household electronics for decentralized off-grid communities.

  14. Manipulating Flames with AC Electric Fields

    NASA Astrophysics Data System (ADS)

    Bishop, Kyle

    2013-11-01

    Time-oscillating electric fields applied to plasmas present in flames create steady flows of gas capable of shaping, directing, enhancing, or even extinguishing flames. Interestingly, electric winds induced by AC electric fields can be stronger that those due to static fields of comparable magnitude. Furthermore, unlike static fields, the electric force due to AC fields is localized near the surface of the flame. Consequently, the AC response depends only on the local field at the surface of the flame - not on the position of the electrodes used to generate the field. These results suggest that oscillating electric fields can be used to manipulate and control combustion processes at a distance. To characterize and explain these effects, we investigate a simple experimental system comprising a laminar methane-air flame positioned between two parallel-plate electrodes. We quantify both the electric and hydrodynamic response of the flame as a function of frequency and magnitude of the applied field. A theoretical model shows how steady gas flows emerge from the time-averaged electrical force due to the field-induced motion of ions generated within the flame and by their disappearance by recombination. These results provide useful insights into the application of AC fields to direct combustion processes.

  15. Ac-dc converter firing error detection

    SciTech Connect

    Gould, O.L.

    1996-07-15

    Each of the twelve Booster Main Magnet Power Supply modules consist of two three-phase, full-wave rectifier bridges in series to provide a 560 VDC maximum output. The harmonic contents of the twelve-pulse ac-dc converter output are multiples of the 60 Hz ac power input, with a predominant 720 Hz signal greater than 14 dB in magnitude above the closest harmonic components at maximum output. The 720 Hz harmonic is typically greater than 20 dB below the 500 VDC output signal under normal operation. Extracting specific harmonics from the rectifier output signal of a 6, 12, or 24 pulse ac-dc converter allows the detection of SCR firing angle errors or complete misfires. A bandpass filter provides the input signal to a frequency-to-voltage converter. Comparing the output of the frequency-to-voltage converter to a reference voltage level provides an indication of the magnitude of the harmonics in the ac-dc converter output signal.

  16. Integrated reformer and shift reactor

    DOEpatents

    Bentley, Jeffrey M.; Clawson, Lawrence G.; Mitchell, William L.; Dorson, Matthew H.

    2006-06-27

    A hydrocarbon fuel reformer for producing diatomic hydrogen gas is disclosed. The reformer includes a first reaction vessel, a shift reactor vessel annularly disposed about the first reaction vessel, including a first shift reactor zone, and a first helical tube disposed within the first shift reactor zone having an inlet end communicating with a water supply source. The water supply source is preferably adapted to supply liquid-phase water to the first helical tube at flow conditions sufficient to ensure discharge of liquid-phase and steam-phase water from an outlet end of the first helical tube. The reformer may further include a first catalyst bed disposed in the first shift reactor zone, having a low-temperature shift catalyst in contact with the first helical tube. The catalyst bed includes a plurality of coil sections disposed in coaxial relation to other coil sections and to the central longitudinal axis of the reformer, each coil section extending between the first and second ends, and each coil section being in direct fluid communication with at least one other coil section.

  17. Progress on advanced dc and ac induction drives for electric vehicles

    NASA Technical Reports Server (NTRS)

    Schwartz, H. J.

    1982-01-01

    Progress is reported in the development of complete electric vehicle propulsion systems, and the results of tests on the Road Load Simulator of two such systems representative of advanced dc and ac drive technology are presented. One is the system used in the DOE's ETV-1 integrated test vehicle which consists of a shunt wound dc traction motor under microprocessor control using a transistorized controller. The motor drives the vehicle through a fixed ratio transmission. The second system uses an ac induction motor controlled by transistorized pulse width modulated inverter which drives through a two speed automatically shifted transmission. The inverter and transmission both operate under the control of a microprocessor. The characteristics of these systems are also compared with the propulsion system technology available in vehicles being manufactured at the inception of the DOE program and with an advanced, highly integrated propulsion system upon which technology development was recently initiated.

  18. High voltage AC/AC electrochemical capacitor operating at low temperature in salt aqueous electrolyte

    NASA Astrophysics Data System (ADS)

    Abbas, Qamar; Béguin, François

    2016-06-01

    We demonstrate that an activated carbon (AC)-based electrochemical capacitor implementing aqueous lithium sulfate electrolyte in 7:3 vol:vol water/methanol mixture can operate down to -40 °C with good electrochemical performance. Three-electrode cell investigations show that the faradaic contributions related with hydrogen chemisorption in the negative AC electrode are thermodynamically unfavored at -40 °C, enabling the system to work as a typical electrical double-layer (EDL) capacitor. After prolonged floating of the AC/AC capacitor at 1.6 V and -40°C, the capacitance, equivalent series resistance and efficiency remain constant, demonstrating the absence of ageing related with side redox reactions at this temperature. Interestingly, when temperature is increased back to 24 °C, the redox behavior due to hydrogen storage reappears and the system behaves as a freshly prepared one.

  19. Screening of the quantum-confined Stark effect in AlN/GaN nanowire superlattices by germanium doping

    SciTech Connect

    Hille, P. Müßener, J.; Becker, P.; Teubert, J.; Schörmann, J.; Eickhoff, M.; Mata, M. de la; Rosemann, N.; Chatterjee, S.; Magén, C.; Arbiol, J.

    2014-03-10

    We report on electrostatic screening of polarization-induced internal electric fields in AlN/GaN nanowire heterostructures with germanium-doped GaN nanodiscs embedded between AlN barriers. The incorporation of germanium at concentrations above 10{sup 20} cm{sup –3} shifts the photoluminescence emission energy of GaN nanodiscs to higher energies accompanied by a decrease of the photoluminescence decay time. At the same time, the thickness-dependent shift in emission energy is significantly reduced. In spite of the high donor concentration, a degradation of the photoluminescence properties is not observed.

  20. Stark Spectroscopy on Photoactive Yellow Protein, E46Q, and a Nonisomerizing Derivative, Probes Photo-Induced Charge Motion

    PubMed Central

    Premvardhan, L. L.; van der Horst, M. A.; Hellingwerf, K. J.; van Grondelle, R.

    2003-01-01

    The change in the electrostatic properties on excitation of the cofactor of wild-type photoactive yellow protein (WT-PYP) have been directly determined using Stark-effect spectroscopy. We find that, instantaneously on photon absorption, there is a large change in the permanent dipole moment, \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\setlength{\\oddsidemargin}{-69pt} \\begin{document} \\begin{equation*}{\\vert}{\\Delta}{\\vec{{\\mu}}}{\\vert},\\end{equation*}\\end{document} (26 Debye) and in the polarizability, \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\setlength{\\oddsidemargin}{-69pt} \\begin{document} \\begin{equation*}\\overline{{\\Delta}{\\alpha}},\\end{equation*}\\end{document} (1000 Å3). We expect such a large degree of charge motion to have a significant impact on the photocycle that is associated with the important blue-light negative phototactic response of Halorhodospira halophila. Furthermore, changing E46 to Q in WT-PYP does not significantly alter its electrostatic properties, whereas, altering the chromophore to prevent it from undergoing trans-cis isomerization results in a significant diminution of \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\setlength{\\oddsidemargin}{-69pt} \\begin{document} \\begin{equation*}{\\vert}{\\Delta}{\\vec{{\\mu}}}{\\vert}\\end{equation*}\\end{document} and \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\setlength{\\oddsidemargin}{-69pt} \\begin{document} \\begin{equation*}\\overline{{\\Delta}{\\alpha}}.\\end{equation*}\\end{document} We

  1. Electronic-resonance-enhanced coherent anti-Stokes Raman scattering of nitric oxide: Saturation and Stark effects

    NASA Astrophysics Data System (ADS)

    Chai, Ning; Lucht, Robert P.; Kulatilaka, Waruna D.; Roy, Sukesh; Gord, James R.

    2010-08-01

    A theoretical analysis of electronic-resonance-enhanced (ERE) coherent anti-Stokes Raman scattering (CARS) of NO is described. The time-dependent density-matrix equations for the nonlinear ERE-CARS process are derived and manipulated into a form suitable for direct numerical integration. In the ERE-CARS configuration considered in this paper, the pump and Stokes beams are far from electronic-resonance. The visible 532 and 591 nm laser beams are used to excite Q-branch Raman resonances in the vibrational bands of the X Π2 electronic state of NO. An ultraviolet probe beam at 236 nm is used to excite P-, Q-, or R-branch transitions in the (v '=0, v″=1) band of the A Σ2+-X Π2 electronic system of NO molecule. Experimental spectra are obtained either by scanning the ultraviolet probe beam while keeping the Stokes frequency fixed (probe scans) or by scanning the Stokes frequency while keeping the probe frequency fixed (Stokes scans). The calculated NO ERE-CARS spectra are compared with experimental spectra, and good agreement is observed between theory and experiment in terms of spectral peak locations and relative intensities. The effects of saturation of the two-photon Raman-resonant Q-branch transitions, the saturation of a one-photon electronic-resonant P-, Q-, or R-branch transitions in the A Σ2+-X Π2 electronic system, and the coupling of these saturation processes are investigated. The coupling of the saturation processes for the probe and Raman transitions is complex and exhibits behavior similar to that observed in the electromagnetic induced transparency process. The probe scan spectra are significantly affected by Stark broadening due to the interaction of the pump and Stokes radiation with single-photon resonances between the upper vibration-rotation probe level in the A Σ2+ electronic levels and vibration-rotation levels in higher lying electronic levels. The ERE-CARS signal intensity is found to be much less sensitive to variations in the

  2. Temperature-dependent, competitive 1,3-acyl shift versus decarbonylation of a cyclopropanone intermediate

    PubMed Central

    Erden, Ihsan; Ma, Jingxiang; Gärtner, Christian; Azimi, Saeed; Gronert, Scott

    2013-01-01

    Photooxygenation of 1,1,3-trimethyl-1,2-dihydropentalene gives an unstable endoperoxide which upon decomposition delivers a bicyclic cyclopropanone intermediate; this species either extrudes CO to give a cycloheptadienone or undergoes a 1,3-acyl shift, both processes occurring most likely in a stepwise manner via diradical intermediates. Alternatively, C3a-C4 cleavage in the dioxygen diradical derived from the endoperoxide yields a 2-cyclopropyl substituted cyclopentadienone epoxide. PMID:23956469

  3. The shifting foundations of nursing.

    PubMed

    Law, Kate; Aranda, Kay

    2010-08-01

    In this paper we argue that the concerns generated by the development of Foundation Degrees and the Assistant and Associate Practitioner roles have rekindled some of the unresolved debates regarding the status and identity of nursing and nurses. Through the application of the sociological theories of professionalisation and nostalgia we have identified the shifting and unresolved nature of nursing. We argue that these theories continue to have resonance in the current climate of change and 'upskilling' of the health care workforce and argue, that the shifts illuminated are perhaps so significant as to demonstrate that we have entered a post-nursing era.

  4. 48 CFR Appendixes A-C to Chapter 7 - [Reserved

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 5 2014-10-01 2014-10-01 false A Appendixes A-C to Chapter 7 Federal Acquisition Regulations System AGENCY FOR INTERNATIONAL DEVELOPMENT Appendixes A-C to Chapter 7...

  5. 48 CFR Appendixes A-C to Chapter 7 - [Reserved

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 5 2010-10-01 2010-10-01 false A Appendixes A-C to Chapter 7 Federal Acquisition Regulations System AGENCY FOR INTERNATIONAL DEVELOPMENT Appendixes A-C to Chapter 7...

  6. 21 CFR 886.1630 - AC-powered photostimulator.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ...) Identification. An AC-powered photostimulator is an AC-powered device intended to provide light stimulus which allows measurement of retinal or visual function by perceptual or electrical methods (e.g.,...

  7. Broadband Interferometer for Measuring Transmitted Wavefronts of Optical Bandpass Filters for HST (ACS)

    NASA Technical Reports Server (NTRS)

    Boucarut, R. A.; Leviton, D. B.

    1998-01-01

    The transmitted wavefronts of optical filters for the Hubble Space Telescope (HST) Advanced Camera for Surveys (ACS) are characterized using the Wildly and Openly Modified Broadband Achromatic Twyman Green (WOMBAT) Interferometer developed in the NASA/GSFC Optics Branch's Diffraction Grating Evaluation Facility (DGEF). Because only four of thirty-three of ACS's optical bandpass filters transmit the 633 nm light of most commercial interferometers, a broadband interferometer is required to verify specified transmitted wavefront of ACS filters. WOMBAT's design is a hybrid of the BAT interferometer developed by JPL used for HST Wide Field and Planetary Camera 2 (WFPC-2) filters and a WYKO 400 phase shifting interferometer. It includes a broadband light source, monochromator, off-axis, parabolic collimating and camera mirrors, an aluminum-coated fused silica beam splitter, flat retroreflecting mirrors for the test and reference arms, and a LTV-sensitive CCD camera. An outboarded, piezo-electric phase shifter holds the flat mirror in the interferometer's reference arm. The interferometer is calibrated through interaction between the WYKO system's software and WONMAT hardware for the test wavelength of light entering the beam splitter. Phase-shifted interferograms of the filter mounted in the test arm are analyzed using WYKO's Vision' software. Filters as large as 90 mm in diameter have been measured over a wavelength range from 200 to 1100 nm with a sensitivity of lambda/200 rms at lambda = 633 nm. Results of transmitted wavefront measurements are shown for ACS fixed band pass and spatially-variable bandpass filters for a variety of wavelengths.

  8. Spectral diffusion of neutral and charged exciton transitions in single CdSe/ZnS nanocrystals due to quantum-confined Stark effect

    NASA Astrophysics Data System (ADS)

    Ihara, Toshiyuki; Kanemitsu, Yoshihiko

    2014-11-01

    Photoluminescence (PL) fluctuations of single semiconductor nanocrystals (NCs), such as PL blinking and spectral diffusion (SD), reflect the quantum nature of charges in the NCs. Through simultaneous measurements of PL spectra and lifetimes on single CdSe/ZnS NCs, PL of neutral excitons is found to exhibit a unique behavior of SD, which is accompanied by changes of radiative recombination lifetime. We find that the SD of neutral excitons originated from the quantum-confined Stark effect, which also affects the SD of charged excitons observed during PL blinking.

  9. Real-time data processing and magnetic field pitch angle estimation of the JET motional Stark effect diagnostic based on Kalman filtering

    SciTech Connect

    Coelho, R.; Alves, D. [Instituto de Plasmas e Fusao Nuclear, Associacao Euratom Hawkes, N.; Brix, M. [Euratom Collaboration: JET EFDA Contributors

    2009-06-15

    A novel technique for the real-time measurement of the magnetic field pitch angle in JET discharges using the motional Stark effect diagnostic is presented. Kalman filtering techniques are adopted to estimate the amplitude of the avalanche photodiode signals' harmonics that are relevant for the pitch angle calculation. The proposed technique {l_brace}for extended technical details of the generic algorithm see [R. Coelho and D. Alves, IEEE Trans. Plasma Sci. 37, 164 (2009)]{r_brace} is shown to be much more robust and provides less noisy estimates than an equivalent lock-in amplifier scheme, in particular when dealing with edge localized modes.

  10. 21 CFR 880.5500 - AC-powered patient lift.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false AC-powered patient lift. 880.5500 Section 880.5500 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED... Devices § 880.5500 AC-powered patient lift. (a) Identification. An AC-powered lift is an...

  11. Methods for Addressing Missing Data with Applications from ACS Exams

    ERIC Educational Resources Information Center

    Brandriet, Alexandra; Holme, Thomas

    2015-01-01

    As part of the ACS Examinations Institute (ACS-EI) national norming process, student performance data sets are collected from professors at colleges and universities from around the United States. Because the data sets are collected on a volunteer basis, the ACS-EI often receives data sets with only students' total scores and without the students'…

  12. 21 CFR 880.5500 - AC-powered patient lift.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 8 2011-04-01 2011-04-01 false AC-powered patient lift. 880.5500 Section 880.5500... Devices § 880.5500 AC-powered patient lift. (a) Identification. An AC-powered lift is an electrically powered device either fixed or mobile, used to lift and transport patients in the horizontal or...

  13. 21 CFR 880.5500 - AC-powered patient lift.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 8 2013-04-01 2013-04-01 false AC-powered patient lift. 880.5500 Section 880.5500... Devices § 880.5500 AC-powered patient lift. (a) Identification. An AC-powered lift is an electrically powered device either fixed or mobile, used to lift and transport patients in the horizontal or...

  14. 21 CFR 880.5500 - AC-powered patient lift.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 8 2014-04-01 2014-04-01 false AC-powered patient lift. 880.5500 Section 880.5500... Devices § 880.5500 AC-powered patient lift. (a) Identification. An AC-powered lift is an electrically powered device either fixed or mobile, used to lift and transport patients in the horizontal or...

  15. 21 CFR 880.5500 - AC-powered patient lift.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 8 2012-04-01 2012-04-01 false AC-powered patient lift. 880.5500 Section 880.5500... Devices § 880.5500 AC-powered patient lift. (a) Identification. An AC-powered lift is an electrically powered device either fixed or mobile, used to lift and transport patients in the horizontal or...

  16. 7 CFR 1737.31 - Area Coverage Survey (ACS).

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 11 2011-01-01 2011-01-01 false Area Coverage Survey (ACS). 1737.31 Section 1737.31... Studies-Area Coverage Survey and Loan Design § 1737.31 Area Coverage Survey (ACS). (a) The Area Coverage Survey (ACS) is a market forecast of service requirements of subscribers in a proposed service area....

  17. 7 CFR 1737.31 - Area Coverage Survey (ACS).

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 11 2013-01-01 2013-01-01 false Area Coverage Survey (ACS). 1737.31 Section 1737.31... Studies-Area Coverage Survey and Loan Design § 1737.31 Area Coverage Survey (ACS). (a) The Area Coverage Survey (ACS) is a market forecast of service requirements of subscribers in a proposed service area....

  18. 7 CFR 1737.31 - Area Coverage Survey (ACS).

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 11 2012-01-01 2012-01-01 false Area Coverage Survey (ACS). 1737.31 Section 1737.31... Studies-Area Coverage Survey and Loan Design § 1737.31 Area Coverage Survey (ACS). (a) The Area Coverage Survey (ACS) is a market forecast of service requirements of subscribers in a proposed service area....

  19. Leadership Shifts in Changing Field

    ERIC Educational Resources Information Center

    Zubrzycki, Jaclyn

    2013-01-01

    As groups representing local and state education players struggle to remain relevant in a policy conversation often dominated by foundations, think tanks, new advocacy groups, and political and business figures, a shift in leadership has been under way at major associations. Most of the changes have come as part of the natural churn; former…

  20. Shifting Patterns of Deadly Violence.

    ERIC Educational Resources Information Center

    Seiden, Richard H.; Freitas, Raymond P.

    1980-01-01

    While it is true that the total suicide rates has varied little, this composite figure masks a dramatic shift in the risk of suicide by age. In recent years there has been a reduction of suicide at older ages reciprocated by an unprecedented increase of suicide and homicide at younger ages. (Author)

  1. Illinois Shifting Gears Policy Evaluation

    ERIC Educational Resources Information Center

    Weitzel, Peter C.

    2009-01-01

    Illinois Shifting Gears is a multilevel initiative that has simultaneously created bridge programs in the field and altered state policy to facilitate the creation of more programs in the future. These efforts have informed each other, giving policymakers the opportunity to interact with practitioners, troubleshoot bridge programs, and make…

  2. Anthropometric changes and fluid shifts

    NASA Technical Reports Server (NTRS)

    Thornton, W. E.; Hoffler, G. W.; Rummel, J. A.

    1974-01-01

    Several observations of body size, shape, posture, and configuration were made to document changes resulting from direct effects of weightlessness during the Skylab 4 mission. After the crewmen were placed in orbit, a number of anatomical and anthropometric changes occurred including a straightening of the thoracolumbar spine, a general decrease in truncal girth, and an increase in height. By the time of the earliest in-flight measurement on mission day 3, all crewmen had lost more than two liters of extravascular fluid from the calf and thigh. The puffy facies, the bird legs effect, the engorgement of upper body veins, and the reduced volume of lower body veins were all documented with photographs. Center-of-mass measurements confirmed a fluid shift cephalad. This shift remained throughout the mission until recovery, when a sharp reversal occurred; a major portion of the reversal was completed in a few hours. The anatomical changes are of considerable scientific interest and of import to the human factors design engineer, but the shifts of blood and extravascular fluid are of more consequence. It is hypothesized that the driving force for the fluid shift is the intrinsic and unopposed lower limb elasticity that forces venous blood and then other fluid cephalad.

  3. The Shift Needed for Sustainability

    ERIC Educational Resources Information Center

    Smith, Peter A. C.; Sharicz, Carol

    2011-01-01

    Purpose: The purpose of this action research is to begin to assess to what extent organizations have in practice begun to make the shift towards triple bottom line (TBL) sustainability. Design/methodology/approach: A definition of TBL sustainability is provided, and key elements of TBL sustainability considered necessary to success are identified…

  4. Technology Counts 2012: Virtual Shift

    ERIC Educational Resources Information Center

    Education Week, 2012

    2012-01-01

    Virtual education is moving into that intersection where rising popularity meets calls for greater accountability. How the virtual education movement responds to those calls will have a significant impact on how it evolves in K-12 over the next five to 10 years. This report tackles this shift in the virtual education landscape. It examines the…

  5. Wavelength-shifted Cherenkov radiators

    NASA Technical Reports Server (NTRS)

    Krider, E. P.; Jacobson, V. L.; Pifer, A. E.; Polakos, P. A.; Kurz, R. J.

    1976-01-01

    The scintillation and Cherenkov responses of plastic Cherenkov radiators containing different wavelength-shifting fluors in varying concentrations have been studied in beams of low energy protons and pions. For cosmic ray applications, where large Cherenkov to scintillation ratios are desired, the optimum fluor concentrations are 0.000025 by weight or less.

  6. Electrical stress-induced instability of amorphous indium-gallium-zinc oxide thin-film transistors under bipolar ac stress

    SciTech Connect

    Lee, Sangwon; Jeon, Kichan; Park, Jun-Hyun; Kim, Sungchul; Kong, Dongsik; Kim, Dong Myong; Kim, Dae Hwan; Kim, Sangwook; Kim, Sunil; Hur, Jihyun; Park, Jae Chul; Song, Ihun; Kim, Chang Jung; Park, Youngsoo; Jung, U-In

    2009-09-28

    Bipolar ac stress-induced instability of amorphous indium-gallium-zinc oxide (a-IGZO) thin-film transistors is comparatively investigated with that under a positive dc gate bias stress. While the positive dc gate bias stress-induced threshold voltage shift ({delta}V{sub T}) is caused by the charge trapping into the interface/gate dielectric as reported in previous works, the dominant mechanism of the ac stress-induced {delta}V{sub T} is observed to be due to the increase in the acceptorlike deep states of the density of states (DOS) in the a-IGZO active layer. Furthermore, it is found that the variation of deep states in the DOS makes a parallel shift in the I{sub DS}-V{sub GS} curve with an insignificant change in the subthreshold slope, as well as the deformation of the C{sub G}-V{sub G} curves.

  7. Pressure broadening and shift rates for Ar (s-p) transitions observed in an Ar-He discharge

    NASA Astrophysics Data System (ADS)

    Eshel, Ben; Rice, Christopher A.; Perram, Glen P.

    2016-08-01

    The pressure broadening and shift rates have been measured for the 801.699 nm (s5 →p8), 800.836 nm (s4 →p6) and 795.036 nm (s3 →p4) transitions in argon perturbed by 10-200 Torr of helium and argon at a temperature of 440 ± 20 K using a radio-frequency, capacitively coupled discharge. For a 10% Ar in He plasma the pressure broadening and shift rates were measured as 14.18 ± 0.65 and 1.81 ± 0.30 MHz / Torr, 17.85 ± 0.78 and 0.72 ± 0.32 MHz / Torr, and 16.59 ± 1.22 and 2.94 ± 0.48 MHz / Torr for the 801.699 nm, 800.836 nm and 795.036 nm transitions, respectively. The influence of the slightly varying gas temperature on the broadening and shift rates is less than 1%. Stark broadening and shifting by electrons in the discharge are not measurable due to low electron densities and temperatures. Phase-changing collisional cross-sections in the literature decrease with temperature, in good agreement with the Lindholm-Foley T-0.2 trend based on the Lennard-Jones potential. Further investigation of the Ar*-Ar and Ar*-He interaction potentials is necessary to understand the behavior of the cross sections.

  8. Ac-SDKP suppresses TNF-α-induced ICAM-1 expression in endothelial cells via inhibition of IκB kinase and NF-κB activation.

    PubMed

    Zhu, Liping; Yang, Xiao-Ping; Janic, Branislava; Rhaleb, Nour-Eddine; Harding, Pamela; Nakagawa, Pablo; Peterson, Edward L; Carretero, Oscar A

    2016-05-01

    N-acetyl-seryl-aspartyl-lysyl-proline (Ac-SDKP) is a naturally occurring tetrapeptide that prevents inflammation and fibrosis in hypertension and other cardiovascular diseases. We previously showed that, in angiotensin II-induced hypertension, Ac-SDKP decreased the activation of nuclear transcription factor NF-κB, whereas, in experimental autoimmune myocarditis and hypertension animal models, it also reduced the expression of endothelial leukocyte adhesion molecule ICAM-1. However, the mechanisms by which Ac-SDKP downregulated ICAM-1 expression are still unclear. TNF-α is a proinflammatory cytokine that induces ICAM-1 expression in various cell types via TNF receptor 1 and activation of the classical NF-κB pathway. We hypothesized that in endothelial cells Ac-SDKP suppresses TNF-α-induced ICAM-1 expression by decreasing IKK phosphorylation that as a consequence leads to a decrease of IκB phosphorylation and NF-κB activation. To test this hypothesis, human coronary artery endothelial cells were treated with Ac-SDKP and then stimulated with TNF-α. We found that TNF-α-induced ICAM-1 expression was significantly decreased by Ac-SDKP in a dose-dependent manner. Ac-SDKP also decreased TNF-α-induced NF-κB translocation from cytosol to nucleus, as assessed by electrophoretic mobility shift assay, which correlated with a decrease in IκB phosphorylation. In addition, we found that Ac-SDKP decreased TNF-α-induced IKK phosphorylation and IKK-β expression. However, Ac-SDKP had no effect on TNF-α-induced phosphorylation of p38 MAP kinase or ERK. Thus we conclude that Ac-SDKP inhibition of TNF-α activation of canonical, i.e., IKK-β-dependent, NF-κB pathway and subsequent decrease in ICAM-1 expression is achieved via inhibition of IKK-β.

  9. Shift control mechanism for a manual transmission

    SciTech Connect

    Gugin, D.G.

    1991-08-06

    This patent describes a shift control mechanism for a manual transmission having a transmission gear housing and a manual shift selecting lever. It comprises a shift selecting shaft mounted within the transmission gear housing for rotation and axial translation in response to selective manipulation of the shift selecting lever; a shift sleeve supported from the transmission gear housing; an actuating member secured to the shift selecting shaft for rotation and axial translation with the shift selecting shaft; synchronizer assemblies; the actuating member individually operating the synchronizer assemblies in response to selected manipulation of the shift selecting lever; alignment guide means interactive between the shift selecting shaft and the transmission gear housing to permit axial translation of the shift selecting shaft only when the shift selecting shaft has been rotated to align a locator means with a locating means.

  10. Size-Dependent Raman Shifts for nanocrystals

    PubMed Central

    Gao, Yukun; Zhao, Xinmei; Yin, Penggang; Gao, Faming

    2016-01-01

    Raman spectroscopy is a very sensitive tool for probing semiconductor nanocrystals. The underlying mechanism behind the size-dependent Raman shifts is still quite controversial. Here we offer a new theoretical method for the quantum confinement effects on the Raman spectra of semiconductor nanocrystals. We propose that the shift of Raman spectra in nanocrystals can result from two overlapping effects: the quantum effect shift and surface effect shift. The quantum effect shift is extracted from an extended Kubo formula, the surface effect shift is determined via the first principles calculations. Fairly good prediction of Raman shifts can be obtained without the use of any adjustable parameter. Closer analysis shows that the size-dependent Raman shifts in Si nanocrystals mainly result from the quantum effect shifts. For nanodiamond, the proportion of surface effect shift in Raman shift is up to about 40%. Such model can also provide a good baseline for using Raman spectroscopy as a tool to measure size. PMID:27102066

  11. Size-Dependent Raman Shifts for nanocrystals.

    PubMed

    Gao, Yukun; Zhao, Xinmei; Yin, Penggang; Gao, Faming

    2016-04-22

    Raman spectroscopy is a very sensitive tool for probing semiconductor nanocrystals. The underlying mechanism behind the size-dependent Raman shifts is still quite controversial. Here we offer a new theoretical method for the quantum confinement effects on the Raman spectra of semiconductor nanocrystals. We propose that the shift of Raman spectra in nanocrystals can result from two overlapping effects: the quantum effect shift and surface effect shift. The quantum effect shift is extracted from an extended Kubo formula, the surface effect shift is determined via the first principles calculations. Fairly good prediction of Raman shifts can be obtained without the use of any adjustable parameter. Closer analysis shows that the size-dependent Raman shifts in Si nanocrystals mainly result from the quantum effect shifts. For nanodiamond, the proportion of surface effect shift in Raman shift is up to about 40%. Such model can also provide a good baseline for using Raman spectroscopy as a tool to measure size.

  12. A HTS scanning magnet and AC operation

    NASA Astrophysics Data System (ADS)

    Hatanaka, K.; Nakagawa, J.; Fukuda, M.; Yorita, T.; Saito, T.; Sakemi, Y.; Kawaguchi, T.; Noda, K.

    2010-04-01

    A scanning magnet using high-temperature superconductor (HTS) wire was designed, built, and tested for its suitability as a beam scanner. After successful cooling tests, the magnet performance was studied using DC and AC currents. With DC current the magnet was successfully operated to generate designed field distributions and effective length. In AC mode, the magnet was operated at frequencies of 30-59 Hz and a temperature of 77 K as well as 10-20 Hz and 20 K. The power losses dissipated in the coils were measured and compared with the model calculations. The observed losses per cycle were independent of the frequency and the scaling law of the transport current was consistent with theoretical predictions for hysteretic losses in HTS wires.

  13. RHIC AC DIPOLE DESIGN AND CONSTRUCTION.

    SciTech Connect

    BAI,M.; METH,M.; PAI,C.; PARKER,B.; PEGGS,S.; ROSER,T.; SANDERS,R.; TRBOJEVIC,D.; ZALTSMAN,A.

    2001-06-18

    Two ac dipoles with vertical and horizontal magnetic field have been proposed at RHIC for applications in linear and non-linear beam dynamics and spin manipulations. A magnetic field amplitude of 380 Gm is required to produce a coherent oscillation of 5 times the rms beam size at the top energy. We take the ac dipole frequency to be 1.0% of the revolution frequency away from the betatron frequency. To achieve the strong magnetic field with minimum power loss, an air-core magnet with two seven turn winding of low loss Litz wire resonating at 64 kHz is designed. The system is also designed to allow one to connect the two magnet winding in series to resonate at 37 kHz for the spin manipulation. Measurements of a half length prototype magnet are also presented.

  14. THE ACS NEARBY GALAXY SURVEY TREASURY

    SciTech Connect

    Dalcanton, Julianne J.; Williams, Benjamin F.; Rosema, Keith; Gogarten, Stephanie M.; Christensen, Charlotte; Gilbert, Karoline; Hodge, Paul; Seth, Anil C.; Dolphin, Andrew; Holtzman, Jon; Skillman, Evan D.; Weisz, Daniel; Cole, Andrew; Girardi, Leo; Karachentsev, Igor D.; Olsen, Knut; Freeman, Ken; Gallart, Carme; De Jong, Roelof S. E-mail: ben@astro.washington.edu E-mail: stephanie@astro.washington.edu E-mail: fabio@astro.washington.edu E-mail: aseth@cfa.harvard.edu

    2009-07-15

    The ACS Nearby Galaxy Survey Treasury (ANGST) is a systematic survey to establish a legacy of uniform multi-color photometry of resolved stars for a volume-limited sample of nearby galaxies (D < 4 Mpc). The survey volume encompasses 69 galaxies in diverse environments, including close pairs, small and large groups, filaments, and truly isolated regions. The galaxies include a nearly complete range of morphological types spanning a factor of {approx}10{sup 4} in luminosity and star formation rate. The survey data consist of images taken with the Advanced Camera for Surveys (ACS) on the Hubble Space Telescope (HST), supplemented with archival data and new Wide Field Planetary Camera 2 (WFPC2) imaging taken after the failure of ACS. Survey images include wide field tilings covering the full radial extent of each galaxy, and single deep pointings in uncrowded regions of the most massive galaxies in the volume. The new wide field imaging in ANGST reaches median 50% completenesses of m {sub F475W} = 28.0 mag, m {sub F606W} = 27.3 mag, and m {sub F814W} = 27.3 mag, several magnitudes below the tip of the red giant branch (TRGB). The deep fields reach magnitudes sufficient to fully resolve the structure in the red clump. The resulting photometric catalogs are publicly accessible and contain over 34 million photometric measurements of >14 million stars. In this paper we present the details of the sample selection, imaging, data reduction, and the resulting photometric catalogs, along with an analysis of the photometric uncertainties (systematic and random), for both ACS and WFPC2 imaging. We also present uniformly derived relative distances measured from the apparent magnitude of the TRGB.

  15. AC plasma anemometer—characteristics and design

    NASA Astrophysics Data System (ADS)

    Marshall, Curtis; Matlis, Eric; Corke, Thomas; Gogineni, Sivaram

    2015-08-01

    The characteristics and design of a high-bandwidth flow sensor that uses an AC glow discharge (plasma) as the sensing element is presented. The plasma forms in the air gap between two protruding low profile electrodes attached to a probe body. The output from the anemometer is an amplitude modulated version of the AC voltage input that contains information about the mean and fluctuating velocity components. The anemometer circuitry includes resistance and capacitance elements that simulate a dielectric-barrier to maintain a diffuse plasma, and a constant-current feedback control that maintains operation within the desired glow discharge regime over an extended range of air velocities. Mean velocity calibrations are demonstrated over a range from 0 to 140 m s-1. Over this velocity range, the mean output voltage varied linearly with air velocity, providing a constant static sensitivity. The effect of the electrode gap and input AC carrier frequency on the anemometer static sensitivity and dynamic response are investigated. Experiments are performed to compare measurements obtained with a plasma sensor operating at two AC carrier frequencies against that of a constant-temperature hot-wire. All three sensors were calibrated against the same known velocity reference. An uncertainty based on the standard deviation of the velocity calibration fit was applied to the mean and fluctuating velocity measurements of the three sensors. The motivation is not to replace hot-wires as a general measurement tool, but rather as an alternative to hot-wires in harsh environments or at high Mach numbers where they either have difficulty in surviving or lack the necessary frequency response.

  16. Graphs for Isotopes of 89-Ac (Actinium)

    NASA Astrophysics Data System (ADS)

    Sukhoruchkin, S. I.; Soroko, Z. N.

    This document is part of the Supplement containing the complete sets of data of Subvolume B `Nuclei with Z = 55 - 100' of Volume 22 `Nuclear Binding Energies and Atomic Masses' of Landolt-Börnstein - Group I `Elementary Particles, Nuclei and Atoms', and additionally including data for nuclei with Z = 101 - 130. It provides a graphic representation of nucleon separation energies and residual interaction parameters for isotopes of the chemical element 89-Ac (Actinium, atomic number Z = 89).

  17. Large aperture ac interferometer for optical testing.

    PubMed

    Moore, D T; Murray, R; Neves, F B

    1978-12-15

    A 20-cm clear aperture modified Twyman-Green interferometer is described. The system measures phase with an AC technique called phase-lock interferometry while scanning the aperture with a dual galvanometer scanning system. Position information and phase are stored in a minicomputer with disk storage. This information is manipulated with associated software, and the wavefront deformation due to a test component is graphically displayed in perspective and contour on a CRT terminal. PMID:20208642

  18. Highlights of the Dallas ACS Meeting

    NASA Astrophysics Data System (ADS)

    Wildeman, Thomas R.; Freilich, Mark; Kelter, Paul B.

    1998-06-01

    Without a doubt, a primary feature of the 1998 Spring National Meeting in Dallas was the High School Program, which was organized by George Hague, and the impact that the Texas teachers had on other participants. Over 150 teachers registered for the meeting and participated in the program. Their organizational skills were used to reinstitute the High School/College Interface Luncheon. (The High School/College Interface Luncheon will also be held at the Fall ACS Meeting in Boston.)

  19. Magic wavelength for the hydrogen 1 S -2 S transition: Contribution of the continuum and the reduced-mass correction

    NASA Astrophysics Data System (ADS)

    Adhikari, C. M.; Kawasaki, A.; Jentschura, U. D.

    2016-09-01

    Recently, we studied the magic wavelength for the atomic hydrogen 1 S -2 S transition [A. Kawasaki, Phys. Rev. A 92, 042507 (2015), 10.1103/PhysRevA.92.042507]. An explicit summation over virtual atomic states of the discrete part of the hydrogen spectrum was performed to evaluate the atomic polarizability. In this paper, we supplement the contribution of the continuum part of the spectrum and add the reduced-mass correction. The magic wavelength, at which the lowest-order ac Stark shifts of the 1 S and 2 S states are equal, is found to be 514.6 nm. The ac Stark shift at the magic wavelength is -221.6 Hz /(kW /cm2) , and the slope of the ac Stark shift at the magic wavelength under a change of the driving laser frequency is -0.2157 Hz /[GHz (kW /cm2)] .

  20. Phase-shift calibration algorithm for phase-shifting interferometry.

    PubMed

    Chen, X; Gramaglia, M; Yeazell, J A

    2000-11-01

    We propose a novel phase-shift calibration algorithm. With this technique we determine the unknown phase shift between two interferograms by examining the sums and differences of the intensities on each interferogram at the same spatial location, i.e., I1(x, y) +/- I2(x, y). These intensities are normalized so that they become sinusoidal in form. A uniformly illuminated region of the interferograms that contains at least a 2pi variation in phase is examined. The extrema of these sums and differences are found in this region and are used to find the unknown phase shift. An error analysis of the algorithm is provided. In addition, an error-correction algorithm is implemented. The method is tested by numerical simulation and implemented experimentally. The numerical tests, including digitization error, indicate that the phase step has a root-mean-square (RMS) phase error of less than 10(-6) deg. Even in the presence of added intensity noise (5% amplitude) the RMS error does not exceed 1 deg. The accuracy of the technique is not sensitive to nonlinearity in the interferogram. PMID:11059603

  1. 78 FR 49318 - Availability of Draft Advisory Circular (AC) 90-106A and AC 20-167A

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-13

    ... Systems (78 FR 34935-34958) (Docket No.: FAA-2013-0485; Notice No. 1209). AC 90-106A, Enhanced Flight... the Federal Register published on April 11, 2000 (65 FR 19477-19478), as well as at http://DocketsInfo... Federal Aviation Administration Availability of Draft Advisory Circular (AC) 90-106A and AC 20-...

  2. Level structure and reflection asymmetric shape in sup 223 Ac

    SciTech Connect

    Sheline, R.K.; Liang, C.F.; Paris, P. )

    1990-07-20

    Mass separated sources of {sup 227}Pa (separated as PaF{sub 4}{sup +} ions) were used to study the level structure of {sup 223}Ac following alpha decay. The levels in {sup 223}Ac are interpreted as K = 5/2{sup {plus minus}} parity doublet bands which occur naturally in reflection asymmetric models and the multiphonon octupole model. The anomalous structure of the K = 3/2{sup {minus}} band is explained in terms of Coriolis coupling. The low lying parity doublet bands in {sup 223}Ac, {sup 225}Ac, and {sup 227}Ac are compared and contrasted.

  3. Common path point diffraction interferometer using liquid crystal phase shifting

    NASA Technical Reports Server (NTRS)

    Mercer, Carolyn R. (Inventor)

    1997-01-01

    A common path point diffraction interferometer uses dyed, parallel nematic liquid crystals which surround an optically transparent microsphere. Coherent, collimated and polarized light is focused on the microsphere at a diameter larger than that of the microsphere. A portion of the focused light passes through the microsphere to form a spherical wavefront reference beam and the rest of the light is attenuated by the dyed liquid crystals to form an object beam. The two beams form an interferogram which is imaged by a lens onto an electronic array sensor and into a computer which determines the wavefront of the object beam. The computer phase shifts the interferogram by stepping up an AC voltage applied across the liquid crystals without affecting the reference beam.

  4. Absorption of ac fields in amorphous indium-oxide films

    SciTech Connect

    Ovadyahu, Z.

    2014-08-20

    Absorption data from applied ac fields in Anderson-localized amorphous indium-oxide (In{sub x}O) films are shown to be frequency and disorder dependent. The absorption shows a roll-off at a frequency which is much lower than the electron-electron scattering rate of the material when it is in the diffusive regime. This is interpreted as evidence for discreteness of the energy spectrum of the deeply localized regime. This is consistent with recent many-body localization scenarios. As the metal-insulator transition is approached, the absorption shifts to higher frequencies. Comparing with the previously obtained results on the crystalline version of indium-oxide (In{sub 2}O{sub 3−x}) implies a considerably higher inelastic electron-phonon scattering rate in the amorphous material. The range over which the absorption versus frequency decreases may indicate that a wide distribution of localization length is a common feature in these systems.

  5. Broadband AC Conductivity of XUV Excited Warm Dense Gold

    NASA Astrophysics Data System (ADS)

    Chen, Z.; Tsui, Y.; Toleikis, S.; Hering, P.; Brown, S.; Curry, C.; Tanikawa, T.; Hoeppner, H.; Levy, M.; Goede, S.; Ziaja-Motyka, B.; Rethfeld, B.; Recoules, Vanina; Ng, A.; Glenzer, S.

    2015-11-01

    The properties of ultrafast laser excited warm dense gold have been extensively studied in the past decade. In those studies, a 400nm ultrashort laser pulse was used to excite the 5 d electrons in gold to 6s/p state. Here we will present our recent study of warm dense gold with 245eV, 70fs pulses to selectively excite 4 f electrons using the XUV-FEL at FLASH. The AC conductivity of the warm dense gold was measured at different wavelengths (485nm, 520nm, 585nm, 640nm and 720nm) to cover the range from 5 d-6 s / p interband transitions to 6 s/ p intraband transitions. Preliminary result suggests that the onset of 5 d-6 s / p band transition shifts from 2.3eV to ~ 2eV, which is in agreement with the study of 400nm laser pulse excited warm dense gold. More detailed analysis of our data will also be presented.

  6. Temperature Dependencies of Linewidths, Positions, and Line Shifts of Spectral Transitions of Trivalent Neodymium Ions in Ceramic Nd3+:Y2O3

    NASA Astrophysics Data System (ADS)

    Pedraza, Francisco; Khachatryan, Edward; Dennis, Robert; Nash, Kelly; Sardar, Dhiraj

    2010-10-01

    Effects of temperature on widths and shifts of the spectral lines of Nd^3+ in Y2O3 polycrystalline ceramic have been investigated. The spectral lines corresponding to the inter-Stark transitions R1 -> Y1 (1074 nm) and R1-> X3 (914 nm) within the ^4F3/2 -> ^4I11/2 and ^4F3/2 -> ^4I9/2 transitions, respectively, have been studied. The widths of these lines and their shifts have been measured as a function of temperature in 10K- 300K range. The spectral linewidths of both transitions are found to increase with increasing temperature. This research was supported by the National Science Foundation Grant No. DMR-0934218.

  7. Development of a hardware-based AC microgrid for AC stability assessment

    NASA Astrophysics Data System (ADS)

    Swanson, Robert R.

    As more power electronic-based devices enable the development of high-bandwidth AC microgrids, the topic of microgrid power distribution stability has become of increased interest. Recently, researchers have proposed a relatively straightforward method to assess the stability of AC systems based upon the time-constants of sources, the net bus capacitance, and the rate limits of sources. In this research, a focus has been to develop a hardware test system to evaluate AC system stability. As a first step, a time domain model of a two converter microgrid was established in which a three phase inverter acts as a power source and an active rectifier serves as an adjustable constant power AC load. The constant power load can be utilized to create rapid power flow transients to the generating system. As a second step, the inverter and active rectifier were designed using a Smart Power Module IGBT for switching and an embedded microcontroller as a processor for algorithm implementation. The inverter and active rectifier were designed to operate simultaneously using a synchronization signal to ensure each respective local controller operates in a common reference frame. Finally, the physical system was created and initial testing performed to validate the hardware functionality as a variable amplitude and variable frequency AC system.

  8. Molecular biology of maize Ac/Ds elements: an overview.

    PubMed

    Lazarow, Katina; Doll, My-Linh; Kunze, Reinhard

    2013-01-01

    Maize Activator (Ac) is one of the prototype transposable elements of the hAT transposon superfamily, members of which were identified in plants, fungi, and animals. The autonomous Ac and nonautonomous Dissociation (Ds) elements are mobilized by the single transposase protein encoded by Ac. To date Ac/Ds transposons were shown to be functional in approximately 20 plant species and have become the most widely used transposable elements for gene tagging and functional genomics approaches in plants. In this chapter we review the biology, regulation, and transposition mechanism of Ac/Ds elements in maize and heterologous plants. We discuss the parameters that are known to influence the functionality and transposition efficiency of Ac/Ds transposons and need to be considered when designing Ac transposase expression constructs and Ds elements for application in heterologous plant species.

  9. Water-gas shift reaction

    SciTech Connect

    Newsome, D.S.

    1980-01-01

    Recent kinetic and mechanistic studies of the water-gas shift reaction, H/sub 2/O(g) + CO(g) reversible CO/sub 2/ + H/sub 2/(g), catalyzed by iron and copper catalysts are reviewed. Composition, structure, active sites, preparation methods, additives, and poisons are discussed relative to each catalyst. New water-gas shift reaction catalyst systems studied are Mo-magnesia, Ni - Mo, Co - Mo, sulfided Co - Mo - Cs, sulfided Co - Mo, sulfided Ni - Mo, Co - Mo - Ni with added alkaki, and Co - Mo with added alkali, Cesium carbonate - cesium acetate - potassium carbonate or potassium acetate - Co - Mo is claimed to be an especially active catalyst. These new catalyst systems are sulfur tolerant and hold promise as catalysts for hydrogenation of high-sulfur coals. (BLM)

  10. Looping through the Lamb Shift

    SciTech Connect

    Hazi, A U

    2007-02-06

    Sometimes in science, a small measurement can have big ramifications. For a team of Livermore scientists, such was the case when they measured a small shift in the spectrum of extremely ionized atoms of uranium. The measurement involves the Lamb shift, a subtle change in the energy of an electron orbiting an atom's nucleus. The precision of the Livermore result was 10 times greater than that of existing measurements, making it the best measurement to date of a complicated correction to the simplest quantum description of how atoms behave. The measurement introduces a new realm in the search for deviations between the theory of quantum electrodynamics (QED), which is an extension of quantum mechanics, and the real world. Such deviations, if discovered, would have far-reaching consequences, indicating that QED is not a fundamental theory of nature.

  11. Anthropometric changes and fluid shifts

    NASA Technical Reports Server (NTRS)

    Thornton, W. E.; Hoffler, G. W.; Rummel, J. A.

    1977-01-01

    In an effort to obtain the most comprehensive and coherent picture of changes under weightlessness, a set of measurements on Skylab 2 was initiated and at every opportunity, additional studies were added. All pertinent information from ancillary sources were gleaned and collated. On Skylab 2, the initial anthropometric studies were scheduled in conjunction with muscle study. A single set of facial photographs was made in-flight. Additional measurements were made on Skylab 3, with photographs and truncal and limb girth measurements in-flight. Prior to Skylab 4, it was felt there was considerable evidence for large and rapid fluid shifts, so a series of in-flight volume and center of mass measurements and infrared photographs were scheduled to be conducted in the Skylab 4 mission. A number of changes were properly documented for the first time, most important of which were the fluid shifts. The following description of Skylab anthropometrics address work done on Skylab 4 primarily.

  12. Boosting Shift-Invariant Features

    NASA Astrophysics Data System (ADS)

    Hörnlein, Thomas; Jähne, Bernd

    This work presents a novel method for training shift-invariant features using a Boosting framework. Features performing local convolutions followed by subsampling are used to achieve shift-invariance. Other systems using this type of features, e.g. Convolutional Neural Networks, use complex feed-forward networks with multiple layers. In contrast, the proposed system adds features one at a time using smoothing spline base classifiers. Feature training optimizes base classifier costs. Boosting sample-reweighting ensures features to be both descriptive and independent. Our system has a lower number of design parameters as comparable systems, so adapting the system to new problems is simple. Also, the stage-wise training makes it very scalable. Experimental results show the competitiveness of our approach.

  13. Shift work and endocrine disorders.

    PubMed

    Ulhôa, M A; Marqueze, E C; Burgos, L G A; Moreno, C R C

    2015-01-01

    The objective of this review was to investigate the impact of shift and night work on metabolic processes and the role of alterations in the sleep-wake cycle and feeding times and environmental changes in the occurrence of metabolic disorders. The literature review was performed by searching three electronic databases for relevant studies published in the last 10 years. The methodological quality of each study was assessed, and best-evidence synthesis was applied to draw conclusions. The literature has shown changes in concentrations of melatonin, cortisol, ghrelin, and leptin among shift workers. Melatonin has been implicated for its role in the synthesis and action of insulin. The action of this hormone also regulates the expression of transporter glucose type 4 or triggers phosphorylation of the insulin receptor. Therefore, a reduction in melatonin can be associated with an increase in insulin resistance and a propensity for the development of diabetes. Moreover, shift work can negatively affect sleep and contribute to sedentarism, unhealthy eating habits, and stress. Recent studies on metabolic processes have increasingly revealed their complexity. Physiological changes induced in workers who invert their activity-rest cycle to fulfill work hours include disruptions in metabolic processes.

  14. Shift Work and Endocrine Disorders

    PubMed Central

    Ulhôa, M. A.; Marqueze, E. C.; Burgos, L. G. A.; Moreno, C. R. C.

    2015-01-01

    The objective of this review was to investigate the impact of shift and night work on metabolic processes and the role of alterations in the sleep-wake cycle and feeding times and environmental changes in the occurrence of metabolic disorders. The literature review was performed by searching three electronic databases for relevant studies published in the last 10 years. The methodological quality of each study was assessed, and best-evidence synthesis was applied to draw conclusions. The literature has shown changes in concentrations of melatonin, cortisol, ghrelin, and leptin among shift workers. Melatonin has been implicated for its role in the synthesis and action of insulin. The action of this hormone also regulates the expression of transporter glucose type 4 or triggers phosphorylation of the insulin receptor. Therefore, a reduction in melatonin can be associated with an increase in insulin resistance and a propensity for the development of diabetes. Moreover, shift work can negatively affect sleep and contribute to sedentarism, unhealthy eating habits, and stress. Recent studies on metabolic processes have increasingly revealed their complexity. Physiological changes induced in workers who invert their activity-rest cycle to fulfill work hours include disruptions in metabolic processes. PMID:25892993

  15. Generalized phase-shifting color digital holography

    NASA Astrophysics Data System (ADS)

    Nomura, Takanori; Kawakami, Takaaki; Shinomura, Kazuma

    2016-06-01

    Two methods to apply the generalized phase-shifting digital holography to color digital holography are proposed. One is wave-splitting generalized phase-shifting color digital holography. This is realized by using a color Bayer camera. Another is multiple exposure generalized phase-shifting color digital holography. This is realized by the wavelength-dependent phase-shifting devices. Experimental results for both generalized phase-shifting color digital holography are presented to confirm the proposed methods.

  16. An automatic AC/DC thermal voltage converter and AC voltage calibration system

    NASA Astrophysics Data System (ADS)

    Lentner, K. J.; Flach, D. R.; Bell, B. A.

    1985-10-01

    An automatic ac/dc difference calibration system is described which uses direct measurement of thermoelement emfs. In addition to ac/dc difference testing, the system can be used to measure some important characteristics of thermoelements, as well as to calibrate ac voltage calibrators and precision voltmeters. The system operates over a frquency range from 20 Hz to 100 kHz, covering the voltage range from 0.5 V to 1 kv. For all voltages the total measurement uncertainties expected (including the uncertainty of the specific reference thermal converters used) were 50 parts per million (ppm) at frequencies from 20 Hz to 20 kHz, inclusive, and 100 ppm at higher frequencies up to 100 kHz.

  17. Automatic ac/dc thermal voltage converter and ac voltage calibration system

    NASA Astrophysics Data System (ADS)

    Lentner, K. J.; Flach, D. R.; Bell, B. A.

    1984-11-01

    An automatic ac/dc difference calibration system is described which uses direct measurement of thermoelement emfs. In addition to ac/dc difference testing, the system can be used to measure some important characteristics of thermoelements, as well as to calibrate ac voltage calibrators and precision voltmeters. The system operates over a frequency range from 20 Hz to 100 kHz, covering the voltage range from 0.5 V to 1 kv. For all voltages the total measurement uncertainties expected (including the uncertainty of the specific reference thermal converters used) were 50 parts per million (ppm) at frequencies from 20 Hz to 20 kHz, inclusive, and 100 ppm at higher frequencies up to 100 kHz.

  18. Paradigm shifts in Medicare reform.

    PubMed

    Jones, S B; Etheredge, L

    1996-04-01

    Reforms passed by Congress and vetoed by the president during the past year would have accelerated initiatives already transforming Medicare. Operating in a rapidly changing insurance marketplace, Medicare is shifting from a social insurance model toward a private individual insurance model-expanding the number and type of alternative health plans it offers-and growing numbers of beneficiaries are enrolling in these plans. Such reforms, especially if bolstered by legislative reforms that are likely to resurface after the November elections, will rewrite the social contract enacted more than 30 years ago. They require fundamental shifts in ways of thinking about the federal government's responsibilities; the Medicare program's management; relations between the Medicare program and doctors, hospitals, and other health care providers; and the role of beneficiaries in the Medicare program. The likely deferral of further legislative attempts to reform Medicare affords an opportunity to step back and consider these ongoing changes. It is not easy to describe paradigm shifts accurately, but there are advantages to trying. First, conceptual comparisons can allow public discussion to go beyond budget scorekeeping and media soundbites to consider how different the Medicare program will be if it evolves in the new ways being proposed. Second, a conceptual framework can assist health policy analysts to target what to watch for in tracking changes, to assess the tradeoffs involved, and to advise about the needs for refining legislation. This paper includes examples of what to watch for in tracking the implemented changes. The paradigm shifts are summarized below, then described individually in terms of directions of change along a number of continuums. Note that complete paradigm shifts, from one end of a continuum to the other, are seldom completely realized nor even far advanced. But Medicare's ongoing reforms, accelerated by legislative proposals, seem likely predecessors of

  19. Deletion of the AcMNPV core gene ac109 results in budded virions that are non-infectious

    SciTech Connect

    Fang Minggang; Nie, Yingchao; Theilmann, David A.

    2009-06-20

    Autographa californica multiple nucleopolyhedrovirus (AcMNPV) ac109 is a core gene and its function in the virus life cycle is unknown. To determine its role in the baculovirus life cycle, we used the AcMNPV bacmid system to generate an ac109 deletion virus (vAc{sup 109KO}). Fluorescence and light microscopy showed that transfection of vAc{sup 109KO} results in a single-cell infection phenotype. Viral DNA replication is unaffected and the development of occlusion bodies in vAc{sup 109KO}-transfected cells evidenced progression to the very late phases of viral infection. Western blot and confocal immunofluorescence analysis showed that AC109 is expressed in the cytoplasm and nucleus throughout infection. In addition, AC109 is a structural protein as it was detected in both budded virus (BV) and occlusion derived virus in both the envelope and nucleocapsid fractions. Titration assays by qPCR and TCID{sub 50} showed that vAc{sup 109KO} produced BV but the virions are non-infectious. The vAc{sup 109KO} BV were indistinguishable from the BV of repaired and wild type control viruses as determined by negative staining and electron microscopy.

  20. Deletion of the AcMNPV core gene ac109 results in budded virions that are non-infectious.

    PubMed

    Fang, Minggang; Nie, Yingchao; Theilmann, David A

    2009-06-20

    Autographa californica multiple nucleopolyhedrovirus (AcMNPV) ac109 is a core gene and its function in the virus life cycle is unknown. To determine its role in the baculovirus life cycle, we used the AcMNPV bacmid system to generate an ac109 deletion virus (vAc(109KO)). Fluorescence and light microscopy showed that transfection of vAc(109KO) results in a single-cell infection phenotype. Viral DNA replication is unaffected and the development of occlusion bodies in vAc(109KO)-transfected cells evidenced progression to the very late phases of viral infection. Western blot and confocal immunofluorescence analysis showed that AC109 is expressed in the cytoplasm and nucleus throughout infection. In addition, AC109 is a structural protein as it was detected in both budded virus (BV) and occlusion derived virus in both the envelope and nucleocapsid fractions. Titration assays by qPCR and TCID(50) showed that vAc(109KO) produced BV but the virions are non-infectious. The vAc(109KO) BV were indistinguishable from the BV of repaired and wild type control viruses as determined by negative staining and electron microscopy.