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Sample records for account blocked property

  1. 31 CFR 589.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Blocked account; blocked property. 589.301 Section 589.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY UKRAINE RELATED SANCTIONS...

  2. 31 CFR 588.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account; blocked property. 588.301 Section 588.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WESTERN BALKANS...

  3. 31 CFR 551.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account; blocked property. 551.301 Section 551.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SOMALIA SANCTIONS...

  4. 31 CFR 541.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account; blocked property. 541.301 Section 541.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY ZIMBABWE SANCTIONS...

  5. 31 CFR 551.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Blocked account; blocked property. 551.301 Section 551.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SOMALIA SANCTIONS REGULATIONS...

  6. 31 CFR 551.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Blocked account; blocked property. 551.301 Section 551.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SOMALIA SANCTIONS REGULATIONS...

  7. 31 CFR 551.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Blocked account; blocked property. 551.301 Section 551.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SOMALIA SANCTIONS REGULATIONS...

  8. 31 CFR 551.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Blocked account; blocked property. 551.301 Section 551.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SOMALIA SANCTIONS REGULATIONS...

  9. 31 CFR 548.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Blocked account; blocked property. 548.301 Section 548.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS...

  10. 31 CFR 548.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Blocked account; blocked property. 548.301 Section 548.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS...

  11. 31 CFR 548.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Blocked account; blocked property. 548.301 Section 548.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS...

  12. 31 CFR 548.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Blocked account; blocked property. 548.301 Section 548.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS...

  13. 31 CFR 548.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account; blocked property. 548.301 Section 548.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS...

  14. 31 CFR 510.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Blocked account; blocked property. 510.301 Section 510.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH KOREA SANCTIONS REGULATIONS...

  15. 31 CFR 510.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Blocked account; blocked property. 510.301 Section 510.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH KOREA SANCTIONS REGULATIONS...

  16. 31 CFR 510.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Blocked account; blocked property. 510.301 Section 510.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH KOREA SANCTIONS REGULATIONS...

  17. 31 CFR 510.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Blocked account; blocked property. 510.301 Section 510.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH KOREA SANCTIONS REGULATIONS...

  18. 31 CFR 545.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account; blocked property. 545.301 Section 545.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY TALIBAN (AFGHANISTAN)...

  19. 31 CFR 594.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Blocked account; blocked property. 594.301 Section 594.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS...

  20. 31 CFR 594.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Blocked account; blocked property. 594.301 Section 594.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS...

  1. 31 CFR 594.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account; blocked property. 594.301 Section 594.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM...

  2. 31 CFR 594.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Blocked account; blocked property. 594.301 Section 594.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS...

  3. 31 CFR 576.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Blocked account; blocked property. 576.301 Section 576.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRAQ STABILIZATION AND INSURGENCY...

  4. 31 CFR 576.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Blocked account; blocked property. 576.301 Section 576.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRAQ STABILIZATION AND INSURGENCY...

  5. 31 CFR 576.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Blocked account; blocked property. 576.301 Section 576.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRAQ STABILIZATION AND INSURGENCY...

  6. 31 CFR 576.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Blocked account; blocked property. 576.301 Section 576.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRAQ STABILIZATION AND INSURGENCY...

  7. 31 CFR 562.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Blocked account; blocked property. 562.301 Section 562.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  8. 31 CFR 562.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Blocked account; blocked property. 562.301 Section 562.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  9. 31 CFR 562.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Blocked account; blocked property. 562.301 Section 562.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  10. 31 CFR 562.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Blocked account; blocked property. 562.301 Section 562.301 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  11. 31 CFR 560.322 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... name of the Government of Iran, any Iranian financial institution, or any other person whose property and interests in property are blocked pursuant to § 560.211, or in which the Government of Iran,...

  12. 31 CFR 537.209 - Expenses of maintaining blocked property; liquidation of blocked account.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Expenses of maintaining blocked property; liquidation of blocked account. 537.209 Section 537.209 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE...

  13. 31 CFR 585.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property in interest-bearing accounts. 585.203 Section 585.203 Money and Finance: Treasury Regulations... blocked property in interest-bearing accounts. (a)(1) Any person, including a U.S. financial institution... subsequent to July 15, 1992, is not being held in an interest-bearing account or otherwise invested in...

  14. 31 CFR 595.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Holding of certain types of blocked property in interest-bearing accounts. 595.203 Section 595.203 Money and Finance: Treasury Regulations... TERRORISM SANCTIONS REGULATIONS Prohibitions § 595.203 Holding of certain types of blocked property...

  15. 31 CFR 536.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Holding of certain types of blocked property in interest-bearing accounts. 536.203 Section 536.203 Money and Finance: Treasury Regulations... NARCOTICS TRAFFICKING SANCTIONS REGULATIONS Prohibitions § 536.203 Holding of certain types of...

  16. 31 CFR 536.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Holding of certain types of blocked property in interest-bearing accounts. 536.203 Section 536.203 Money and Finance: Treasury Regulations... NARCOTICS TRAFFICKING SANCTIONS REGULATIONS Prohibitions § 536.203 Holding of certain types of...

  17. 31 CFR 515.319 - Blocked account.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account. 515.319 Section 515... § 515.319 Blocked account. The term blocked account shall mean an account in which any designated national has an interest, with respect to which account payments, transfers or withdrawals or...

  18. 31 CFR 515.319 - Blocked account.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Blocked account. 515.319 Section 515... § 515.319 Blocked account. The term blocked account shall mean an account in which any designated national has an interest, with respect to which account payments, transfers or withdrawals or...

  19. 31 CFR 515.319 - Blocked account.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Blocked account. 515.319 Section 515... § 515.319 Blocked account. The term blocked account shall mean an account in which any designated national has an interest, with respect to which account payments, transfers or withdrawals or...

  20. 31 CFR 515.319 - Blocked account.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Blocked account. 515.319 Section 515... § 515.319 Blocked account. The term blocked account shall mean an account in which any designated national has an interest, with respect to which account payments, transfers or withdrawals or...

  1. 31 CFR 515.319 - Blocked account.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Blocked account. 515.319 Section 515... § 515.319 Blocked account. The term blocked account shall mean an account in which any designated national has an interest, with respect to which account payments, transfers or withdrawals or...

  2. 31 CFR 500.319 - Blocked account.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Blocked account. 500.319 Section 500... § 500.319 Blocked account. The term blocked account shall mean an account in which any designated national has an interest, with respect to which account payments, transfers or withdrawals of...

  3. 31 CFR 536.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... NARCOTICS TRAFFICKING SANCTIONS REGULATIONS Prohibitions § 536.203 Holding of certain types of blocked... party on both accounts must be the same and must clearly indicate the specially designated narcotics... narcotics trafficker, the name of the account to which interest is credited must be the same. (b)...

  4. 31 CFR 536.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... property in interest-bearing accounts. 536.203 Section 536.203 Money and Finance: Treasury Regulations... property in interest-bearing accounts. (a)(1) Any person, including a U.S. financial institution, currently... to the effective date, is not being held in an interest-bearing account, or otherwise invested in...

  5. 31 CFR 536.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property in interest-bearing accounts. 536.203 Section 536.203 Money and Finance: Treasury Regulations... property in interest-bearing accounts. (a)(1) Any person, including a U.S. financial institution, currently... to the effective date, is not being held in an interest-bearing account, or otherwise invested in...

  6. 31 CFR 575.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property in interest-bearing accounts. 575.203 Section 575.203 Money and Finance: Treasury Regulations... interest-bearing accounts. (a) Any person, including a U.S. financial institution, currently holding... effective date, is not being held in an interest-bearing account, or otherwise invested in a...

  7. 31 CFR 595.203 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property in interest-bearing accounts. 595.203 Section 595.203 Money and Finance: Treasury Regulations... interest-bearing accounts. (a)(1) Any person, including a U.S. financial institution, currently holding... effective date, is not being held in an interest-bearing account, or otherwise invested in a...

  8. 31 CFR 500.205 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... “domestic bank” includes any FSLIC-insured institution (as defined in 12 CFR 561.1). (j) For the purposes of... property in interest-bearing accounts. 500.205 Section 500.205 Money and Finance: Treasury Regulations... interest-bearing accounts. (a) Except as provided by paragraphs (d), (e) and (f) of this section, or...

  9. 31 CFR 515.205 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... domestic bank includes any FSLIC-insured institution (as defined in 12 CFR 561.1). (j) For the purposes of... property in interest-bearing accounts. 515.205 Section 515.205 Money and Finance: Treasury Regulations... interest-bearing accounts. (a) Except as provided by paragraphs (d), (e) and (f) of this section, or...

  10. 31 CFR 515.205 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... domestic bank includes any FSLIC-insured institution (as defined in 12 CFR 561.1). (j) For the purposes of... property in interest-bearing accounts. 515.205 Section 515.205 Money and Finance: Treasury Regulations... interest-bearing accounts. (a) Except as provided by paragraphs (d), (e) and (f) of this section, or...

  11. 31 CFR 515.205 - Holding of certain types of blocked property in interest-bearing accounts.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... domestic bank includes any FSLIC-insured institution (as defined in 12 CFR 561.1). (j) For the purposes of... property in interest-bearing accounts. 515.205 Section 515.205 Money and Finance: Treasury Regulations... interest-bearing accounts. (a) Except as provided by paragraphs (d), (e) and (f) of this section, or...

  12. Property Blocks: Games and Activities.

    ERIC Educational Resources Information Center

    Humphreys, Alan, Ed.; Dailey, Jean, Ed.

    This pamphlet describes the property blocks produced by MINNEMAST, and discusses their use in the development of thinking processes. Classification systems, including block diagrams and tree diagrams, are discussed. Sixteen classroom activities and eleven games which use the blocks are described. Suggestions to the teacher for further reading are…

  13. 31 CFR 536.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING SANCTIONS REGULATIONS... specially designated narcotics trafficker or in which a specially designated narcotics trafficker has...

  14. 31 CFR 536.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING SANCTIONS REGULATIONS... specially designated narcotics trafficker or in which a specially designated narcotics trafficker has...

  15. 31 CFR 536.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING SANCTIONS... name of a specially designated narcotics trafficker or in which a specially designated...

  16. 31 CFR 536.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING SANCTIONS REGULATIONS... specially designated narcotics trafficker or in which a specially designated narcotics trafficker has...

  17. 31 CFR 536.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING SANCTIONS REGULATIONS... specially designated narcotics trafficker or in which a specially designated narcotics trafficker has...

  18. 31 CFR 544.301 - Blocked account; blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION... license from the Office of Foreign Assets Control expressly authorizing such action. Note to §...

  19. 31 CFR 515.508 - Payments to blocked accounts in domestic banks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... accounts in domestic banks. (a) Any payment or transfer of credit to a blocked account in a domestic bank... transaction including, but not by way of limitation, any transfer of credit, or payment of an obligation... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Payments to blocked accounts...

  20. 31 CFR 500.508 - Payments to blocked accounts in domestic banks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... in domestic banks. (a) Any payment or transfer of credit to a blocked account in a domestic bank in... transaction including, but not by way of limitation, any transfer of credit, or payment of an obligation... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Payments to blocked accounts...

  1. Stumbling Blocks in the Implementation of Accounting Education Reform: Evidence from Hong Kong

    ERIC Educational Resources Information Center

    Chen, Theodore T. Y.

    2016-01-01

    In determining whether stumbling blocks exist in the implementation of accounting education reform in Hong Kong, a survey questionnaire was sent to all accounting departments at public universities representing accounting academics, and the Hong Kong Institute of Certified Public Accountants representing the profession. The survey showed that both…

  2. 31 CFR 560.423 - Offshore transactions involving blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Government of Iran, an Iranian financial institution, or any other person whose property and interests in property are blocked pursuant to § 560.211, or property in which the Government of Iran, an...

  3. Structure and Properties of Block Copolymers of Polystyrene and Polybutadiene

    NASA Astrophysics Data System (ADS)

    Askadskii, Andrei A.; Andryushchenko, T. A.; Zubov, P. I.

    1984-08-01

    Recent studies of the structure and properties of block copolymers of polystyrene and polybutadiene are reviewed, with special emphasis on the effect of the structure and of the formation conditions for the samples on the interrelated physico-mechanical properties. Problems associated with the macro- and micro-layering of block copolymer solutions are examined in detail. Work on the analysis of block copolymer structures from measurements of sorption characteristics is reviewed in the light of an assumed relaxation mechanism for the sorption and swelling processes. The prospects of controlling the structure and properties of block copolymers are shown to be good. The bibliography contains 190 references.

  4. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Prohibited transactions involving blocked property. 598.203 Section 598.203 Money and Finance: Treasury Regulations Relating to Money and... SANCTIONS REGULATIONS Prohibitions § 598.203 Prohibited transactions involving blocked property. (a)...

  5. Determining the Mechanical Properties of Lattice Block Structures

    NASA Technical Reports Server (NTRS)

    Wilmoth, Nathan

    2013-01-01

    Lattice block structures and shape memory alloys possess several traits ideal for solving intriguing new engineering problems in industries such as aerospace, military, and transportation. Recent testing at the NASA Glenn Research Center has investigated the material properties of lattice block structures cast from a conventional aerospace titanium alloy as well as lattice block structures cast from nickel-titanium shape memory alloy. The lattice block structures for both materials were sectioned into smaller subelements for tension and compression testing. The results from the cast conventional titanium material showed that the expected mechanical properties were maintained. The shape memory alloy material was found to be extremely brittle from the casting process and only compression testing was completed. Future shape memory alloy lattice block structures will utilize an adjusted material composition that will provide a better quality casting. The testing effort resulted in baseline mechanical property data from the conventional titanium material for comparison to shape memory alloy materials once suitable castings are available.

  6. Piezoelectric Properties of Non-Polar Block Copolymers

    SciTech Connect

    Pester, Christian; Ruppel, Markus A; Schoberth, Heiko; Schmidt, K.; Liedel, Clemens; Van Rijn, Patrick; Littrell, Ken; Schindler, Kerstin; Hiltl, Stephanie; Czubak, Thomas; Mays, Jimmy; Urban, Volker S; Boker, Alexander

    2011-01-01

    Piezoelectric properties in non-polar block copolymers are a novelty in the field of electroactive polymers. The piezoelectric susceptibility of poly(styrene-b-isoprene) block copolymer lamellae is found to be up to an order of magnitude higher when compared to classic piezoelectric materials. The electroactive response increases with temperature and is found to be strongest in the disordered phase.

  7. 31 CFR 537.407 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 537.407 Section 537.407 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  8. 31 CFR 548.407 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 548.407 Section 548.407 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  9. 31 CFR 548.407 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 548.407 Section 548.407 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  10. 31 CFR 548.407 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 548.407 Section 548.407 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  11. 31 CFR 548.407 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 548.407 Section 548.407 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  12. 31 CFR 548.407 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 548.407 Section 548.407 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  13. 31 CFR 594.408 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 594.408 Section 594.408 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  14. 31 CFR 544.407 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 544.407 Section 544.407 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  15. 31 CFR 535.508 - Payments to blocked accounts in domestic banks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Iran or any Iranian entity is hereby authorized: Provided, Such payment or transfer shall not be made... the interest of Iran or an Iranian entity to any other country or person. (b) This section does not authorize: (1) Any payment or transfer to any blocked account held in a name other than that of Iran or...

  16. 31 CFR 576.408 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 576.408 Section 576.408 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  17. 31 CFR 576.408 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 576.408 Section 576.408 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  18. 31 CFR 576.408 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 576.408 Section 576.408 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  19. 31 CFR 576.408 - Payments from blocked accounts to satisfy obligations prohibited.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Payments from blocked accounts to satisfy obligations prohibited. 576.408 Section 576.408 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  20. 31 CFR 593.203 - Holding of blocked funds in interest-bearing accounts; investment and reinvestment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...-bearing accounts; investment and reinvestment. 593.203 Section 593.203 Money and Finance: Treasury... blocked funds in interest-bearing accounts; investment and reinvestment. (a) Except as provided in..., subject to § 593.201(a) shall hold or place such funds in a blocked interest-bearing account located...

  1. 31 CFR 593.203 - Holding of blocked funds in interest-bearing accounts; investment and reinvestment.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...-bearing accounts; investment and reinvestment. 593.203 Section 593.203 Money and Finance: Treasury... blocked funds in interest-bearing accounts; investment and reinvestment. (a) Except as provided in..., subject to § 593.201(a) shall hold or place such funds in a blocked interest-bearing account located...

  2. 31 CFR 594.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 106 of the USA PATRIOT Act of 2001 (Pub. L. 107-56, Oct. 26, 2001) amended section 203 of the... Attorney General, to have committed, or to pose a significant risk of committing, acts of terrorism that... act for or on behalf of, any person whose property or interests in property are blocked pursuant...

  3. 18 CFR 367.1010 - Account 101, Service company property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 101, Service company property. 367.1010 Section 367.1010 Conservation of Power and Water Resources FEDERAL ENERGY... GAS ACT Balance Sheet Chart of Accounts § 367.1010 Account 101, Service company property. (a)...

  4. 18 CFR 367.3030 - Account 303, Miscellaneous intangible property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 303, Miscellaneous intangible property. 367.3030 Section 367.3030 Conservation of Power and Water Resources FEDERAL... NATURAL GAS ACT Service Company Property Chart of Accounts § 367.3030 Account 303,...

  5. 18 CFR 367.3990 - Account 399, Other tangible property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 399, Other tangible property. 367.3990 Section 367.3990 Conservation of Power and Water Resources FEDERAL ENERGY... GAS ACT Service Company Property Chart of Accounts § 367.3990 Account 399, Other tangible...

  6. 18 CFR 367.9240 - Account 924, Property insurance.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 924, Property insurance. 367.9240 Section 367.9240 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY... ACT Operation and Maintenance Expense Chart of Accounts § 367.9240 Account 924, Property insurance....

  7. 18 CFR 367.1010 - Account 101, Service company property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 101, Service company property. 367.1010 Section 367.1010 Conservation of Power and Water Resources FEDERAL ENERGY... GAS ACT Balance Sheet Chart of Accounts § 367.1010 Account 101, Service company property. (a)...

  8. 18 CFR 367.3990 - Account 399, Other tangible property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 399, Other tangible property. 367.3990 Section 367.3990 Conservation of Power and Water Resources FEDERAL ENERGY... GAS ACT Service Company Property Chart of Accounts § 367.3990 Account 399, Other tangible...

  9. 31 CFR 538.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Prohibited transactions involving blocked property. 538.201 Section 538.201 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SUDANESE...

  10. 31 CFR 545.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Prohibited transactions involving blocked property. 545.201 Section 545.201 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY TALIBAN...

  11. 31 CFR 544.204 - Expenses of maintaining blocked physical property; liquidation of blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WEAPONS OF MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Prohibitions § 544.204 Expenses of... of Foreign Assets Control, be sold or liquidated and the net proceeds placed in a blocked...

  12. Properties of concrete blocks prepared with low grade recycled aggregates.

    PubMed

    Poon, Chi-Sun; Kou, Shi-cong; Wan, Hui-wen; Etxeberria, Miren

    2009-08-01

    Low grade recycled aggregates obtained from a construction waste sorting facility were tested to assess the feasibility of using these in the production of concrete blocks. The characteristics of the sorted construction waste are significantly different from that of crushed concrete rubbles that are mostly derived from demolition waste streams. This is due to the presence of higher percentages of non-concrete components (e.g. >10% soil, brick, tiles etc.) in the sorted construction waste. In the study reported in this paper, three series of concrete block mixtures were prepared by using the low grade recycled aggregates to replace (i) natural coarse granite (10mm), and (ii) 0, 25, 50, 75 and 100% replacement levels of crushed stone fine (crushed natural granite <5mm) in the concrete blocks. Test results on properties such as density, compressive strength, transverse strength and drying shrinkage as well as strength reduction after exposure to 800 degrees C are presented below. The results show that the soil content in the recycled fine aggregate was an important factor in affecting the properties of the blocks produced and the mechanical strength deceased with increasing low grade recycled fine aggregate content. But the higher soil content in the recycled aggregates reduced the reduction of compressive strength of the blocks after exposure to high temperature due probably to the formation of a new crystalline phase. The results show that the low grade recycled aggregates obtained from the construction waste sorting facility has potential to be used as aggregates for making non-structural pre-cast concrete blocks.

  13. 18 CFR 367.9240 - Account 924, Property insurance.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ...) Recoveries from insurance companies or others for property damages must be credited to the account charged... insurance premiums were charged. The following items must be included in this account: (1) Premiums payable... charged as indicated. (1) Materials and supplies and stores equipment, to account 163, Stores...

  14. Hydration effects on the electronic properties of eumelanin building blocks

    NASA Astrophysics Data System (ADS)

    Assis Oliveira, Leonardo Bruno; L. Fonseca, Tertius; Costa Cabral, Benedito J.; Coutinho, Kaline; Canuto, Sylvio

    2016-08-01

    Theoretical results for the electronic properties of eumelanin building blocks in the gas phase and water are presented. The building blocks presently investigated include the monomeric species DHI (5,6-dihydroxyindole) or hydroquinone (HQ), DHICA (5,6-dihydroxyindole-2-carboxylic acid), indolequinone (IQ), quinone methide (MQ), two covalently bonded dimers [HM ≡ HQ + MQ and IM ≡ IQ + MQ], and two tetramers [HMIM ≡ HQ + IM, IMIM ≡ IM + IM]. The electronic properties in water were determined by carrying out sequential Monte Carlo/time dependent density functional theory calculations. The results illustrate the role played by hydrogen bonding and electrostatic interactions in the electronic properties of eumelanin building blocks in a polar environment. In water, the dipole moments of monomeric species are significantly increased ([54-79]%) relative to their gas phase values. Recently, it has been proposed that the observed enhancement of the higher-energy absorption intensity in eumelanin can be explained by excitonic coupling among eumelanin protomolecules [C.-T. Chen et al., Nat. Commun. 5, 3859 (2014)]. Here, we are providing evidence that for DHICA, IQ, and HMIM, the electronic absorption toward the higher-energy end of the spectrum ([180-220] nm) is enhanced by long-range Coulombic interactions with the water environment. It was verified that by superposing the absorption spectra of different eumelanin building blocks corresponding to the monomers, dimers, and tetramers in liquid water, the behaviour of the experimental spectrum, which is characterised by a nearly monotonic decay from the ultraviolet to the infrared, is qualitatively reproduced. This result is in keeping with a "chemical disorder model," where the broadband absorption of eumelanin pigments is determined by the superposition of the spectra associated with the monomeric and oligomeric building blocks.

  15. Hydration effects on the electronic properties of eumelanin building blocks.

    PubMed

    Assis Oliveira, Leonardo Bruno; L Fonseca, Tertius; Costa Cabral, Benedito J; Coutinho, Kaline; Canuto, Sylvio

    2016-08-28

    Theoretical results for the electronic properties of eumelanin building blocks in the gas phase and water are presented. The building blocks presently investigated include the monomeric species DHI (5,6-dihydroxyindole) or hydroquinone (HQ), DHICA (5,6-dihydroxyindole-2-carboxylic acid), indolequinone (IQ), quinone methide (MQ), two covalently bonded dimers [HM ≡ HQ + MQ and IM ≡ IQ + MQ], and two tetramers [HMIM ≡ HQ + IM, IMIM ≡ IM + IM]. The electronic properties in water were determined by carrying out sequential Monte Carlo/time dependent density functional theory calculations. The results illustrate the role played by hydrogen bonding and electrostatic interactions in the electronic properties of eumelanin building blocks in a polar environment. In water, the dipole moments of monomeric species are significantly increased ([54-79]%) relative to their gas phase values. Recently, it has been proposed that the observed enhancement of the higher-energy absorption intensity in eumelanin can be explained by excitonic coupling among eumelanin protomolecules [C.-T. Chen et al., Nat. Commun. 5, 3859 (2014)]. Here, we are providing evidence that for DHICA, IQ, and HMIM, the electronic absorption toward the higher-energy end of the spectrum ([180-220] nm) is enhanced by long-range Coulombic interactions with the water environment. It was verified that by superposing the absorption spectra of different eumelanin building blocks corresponding to the monomers, dimers, and tetramers in liquid water, the behaviour of the experimental spectrum, which is characterised by a nearly monotonic decay from the ultraviolet to the infrared, is qualitatively reproduced. This result is in keeping with a "chemical disorder model," where the broadband absorption of eumelanin pigments is determined by the superposition of the spectra associated with the monomeric and oligomeric building blocks. PMID:27586929

  16. 31 CFR 544.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Payments and transfers to blocked... WEAPONS OF MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Licenses, Authorizations and Statements of Licensing Policy § 544.504 Payments and transfers to blocked accounts in U.S. financial institutions....

  17. Dielectric and other properties of polyimide aerogels containing fluorinated blocks.

    PubMed

    Meador, Mary Ann B; McMillon, Emily; Sandberg, Anna; Barrios, Elizabeth; Wilmoth, Nathan G; Mueller, Carl H; Miranda, Félix A

    2014-05-14

    The dielectric and other properties of a series of low-density polyimide block copolymer aerogels have been characterized. Two different anhydride-capped polyimide oligomers were synthesized: one from 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) and 4,4'-oxidianiline (ODA) and the other from biphenyl-3,3',4,4'-tetracarboxylic dianhydride and ODA. The oligomers were combined with 1,3,5-triaminophenoxybenzene to form a block copolymer networked structure that gelled in under 1 h. The polyimide gels were supercritically dried to give aerogels with relative dielectric constants as low as 1.08. Increasing the amount of 6FDA blocks by up to 50% of the total dianhydride decreased the density of the aerogels, presumably by increasing the free volume and also by decreasing the amount of shrinkage seen upon processing, resulting in a concomitant decrease in the dielectric properties. In this study, we have also altered the density independent of fluorine substitution by changing the polymer concentration in the gelation reactions and showed that the change in dielectric due to density is the same with and without fluorine substitution. The aerogels with the lowest dielectric properties and lowest densities still had compressive moduli of 4-8 MPa (40 times higher than silica aerogels at the same density), making them suitable as low dielectric substrates for lightweight antennas for aeronautic and space applications.

  18. Guidelines for School Property Accounting in Colorado, Part II--General Fixed Asset Accounts.

    ERIC Educational Resources Information Center

    Stiverson, Clare L.

    The second publication of a series of three issued by the Colorado Department of Education is designed as a guide for local school districts in the development of a property accounting system. It defines and classifies groups of accounts whereby financial information, taken from inventory records, may be transcribed into debit and credit entries…

  19. 48 CFR 2045.371 - Property accountability procedures.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 48 Federal Acquisition Regulations System 6 2010-10-01 2010-10-01 true Property accountability procedures. 2045.371 Section 2045.371 Federal Acquisition Regulations System NUCLEAR REGULATORY COMMISSION CONTRACT MANAGEMENT GOVERNMENT PROPERTY Providing Government Property to Contractors 2045.371...

  20. 77 FR 40948 - Additional Designation of Persons Whose Property and Interests in Property Are Blocked Pursuant...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-11

    ... Persons Contributing to the Conflict in Somalia'' AGENCY: Office of Foreign Assets Control, Treasury... in Somalia.'' FOR FURTHER INFORMATION CONTACT: Assistant Director, Compliance Outreach... Executive Order ``Blocking Property of Certain Persons Contributing to the Conflict in Somalia''...

  1. 48 CFR 2045.371 - Property accountability procedures.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 6 2014-10-01 2014-10-01 false Property accountability procedures. 2045.371 Section 2045.371 Federal Acquisition Regulations System NUCLEAR REGULATORY COMMISSION... accountability procedures. (a) The threshold for detailed reporting of capitalized equipment by contractors...

  2. 48 CFR 2045.371 - Property accountability procedures.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 6 2011-10-01 2011-10-01 false Property accountability procedures. 2045.371 Section 2045.371 Federal Acquisition Regulations System NUCLEAR REGULATORY COMMISSION... accountability procedures. (a) The threshold for detailed reporting of capitalized equipment by contractors...

  3. 48 CFR 2045.371 - Property accountability procedures.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 48 Federal Acquisition Regulations System 6 2012-10-01 2012-10-01 false Property accountability procedures. 2045.371 Section 2045.371 Federal Acquisition Regulations System NUCLEAR REGULATORY COMMISSION... accountability procedures. (a) The threshold for detailed reporting of capitalized equipment by contractors...

  4. 48 CFR 2045.371 - Property accountability procedures.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 6 2013-10-01 2013-10-01 false Property accountability procedures. 2045.371 Section 2045.371 Federal Acquisition Regulations System NUCLEAR REGULATORY COMMISSION... accountability procedures. (a) The threshold for detailed reporting of capitalized equipment by contractors...

  5. 48 CFR 245.103-71 - Transferring Government property accountability.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 48 Federal Acquisition Regulations System 3 2014-10-01 2014-10-01 false Transferring Government... ACQUISITION REGULATIONS SYSTEM, DEPARTMENT OF DEFENSE CONTRACT MANAGEMENT GOVERNMENT PROPERTY General 245.103-71 Transferring Government property accountability. Follow the procedures at PGI 245.103-71...

  6. 48 CFR 245.103-71 - Transferring Government property accountability.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 48 Federal Acquisition Regulations System 3 2013-10-01 2013-10-01 false Transferring Government... ACQUISITION REGULATIONS SYSTEM, DEPARTMENT OF DEFENSE CONTRACT MANAGEMENT GOVERNMENT PROPERTY General 245.103-71 Transferring Government property accountability. Follow the procedures at PGI 245.103-71...

  7. 31 CFR 562.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 562.504 Section 562.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  8. 31 CFR 593.203 - Holding of blocked funds in interest-bearing accounts; investment and reinvestment.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Holding of blocked funds in interest-bearing accounts; investment and reinvestment. 593.203 Section 593.203 Money and Finance: Treasury... TREASURY FORMER LIBERIAN REGIME OF CHARLES TAYLOR SANCTIONS REGULATIONS Prohibitions § 593.203 Holding...

  9. 31 CFR 510.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 510.504 Section 510.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH KOREA SANCTIONS REGULATIONS...

  10. 31 CFR 562.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 562.504 Section 562.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  11. 31 CFR 562.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 562.504 Section 562.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  12. 31 CFR 562.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 562.504 Section 562.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  13. 31 CFR 576.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 576.504 Section 576.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  14. 31 CFR 576.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 576.504 Section 576.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  15. 31 CFR 576.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 576.504 Section 576.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  16. 31 CFR 576.504 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Payments and transfers to blocked accounts in U.S. financial institutions. 576.504 Section 576.504 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  17. 18 CFR 367.3030 - Account 303, Miscellaneous intangible property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 303, Miscellaneous intangible property. 367.3030 Section 367.3030 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE PUBLIC UTILITY HOLDING COMPANY ACT OF 2005, FEDERAL POWER ACT AND...

  18. (Electro)Mechanical Properties of Olefinic Block Copolymers

    NASA Astrophysics Data System (ADS)

    Spontak, Richard

    2014-03-01

    Conventional styrenic triblock copolymers (SBCs) swollen with a midblock-selective oil have been previously shown to exhibit excellent electromechanical properties as dielectric elastomers. In this class of electroactive polymers, compliant electrodes applied as active areas to opposing surfaces of an elastomer attract each other, and thus compress the elastomer due to the onset of a Maxwell stress, upon application of an external electric field. This isochoric process is accompanied by an increase in lateral area, which yields the electroactuation strain (measuring beyond 300% in SBC systems). Performance parameters such as the Maxwell stress, transverse strain, dielectric breakdown, energy density and electromechanical efficiency are determined directly from the applied electric field and resulting electroactuation strain. In this study, the same principle used to evaluate SBC systems is extended to olefinic block copolymers (OBCs), which can be described as randomly-coupled multiblock copolymers that consist of crystallizable polyethylene hard segments and rubbery poly(ethylene-co-octene) soft segments. Considerations governing the development of a methodology to fabricate electroresponsive OBC systems are first discussed for several OBCs differing in composition and bulk properties. Evidence of electroactuation in selectively-solvated OBC systems is presented and performance metrics measured therefrom are quantitatively compared with dielectric elastomers derived from SBC and related materials.

  19. Multifunctional Poly(N-vinylcarbazole)-Based Block Copolymers and their Nanofabrication and Photosensitizing Properties.

    PubMed

    Tam, Wing Yan; Mak, Chris S K; Ng, Alan Man Ching; Djurišić, Aleksandra B; Chan, Wai Kin

    2009-04-20

    The synthesis of poly(N-vinylcarbazole)-based block copolymers functionalized with rhenium diimine complexes or pendant terpyridine ligands is reported. The copolymers are synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization, and they exhibit interesting morphological properties as a result of the phase separation between different blocks. The rhenium complex polymer block may function as a photosensitizer, while the terpyridine-containing polymer block can be used as the template for nanofabrication by selective deposition of zinc complexes.

  20. 77 FR 6657 - Blocking Property of the Government of Iran and Iranian Financial Institutions

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-08

    .... eastern standard time on February 6, 2012. (Presidential Sig.) THE WHITE HOUSE, February 5, 2012. [FR Doc... February 8, 2012 Part III The President Executive Order 13599--Blocking Property of the Government of Iran... President ] Executive Order 13599 of February 5, 2012 Blocking Property of the Government of Iran...

  1. 78 FR 79726 - Designation of Four Individuals Pursuant to Executive Order 13581, “Blocking Property of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-12-31

    ...The Treasury Department's Office of Foreign Assets Control (``OFAC'') is publishing the names of four individuals whose property and interests in property are blocked pursuant to Executive Order 13581 of July 24, 2011, ``Blocking Property of Transnational Criminal...

  2. Tailoring Phase Behavior and Mechanical Properties in Thermoplastic Elastomers through Block Sequence and Macromolecular Architecture

    NASA Astrophysics Data System (ADS)

    Burns, Adam; Register, Richard

    2015-03-01

    Block copolymers exhibit unique properties which depend not only on the identities of the constituent blocks but also the block sequence and macromolecular architecture. Thermoplastic elastomers (TPEs) are a prime example. In TPEs the arrangement of glassy end blocks flanking a long rubbery midblock gives rise to a physically cross-linked, elastic solid. Exchanging the glassy blocks for crystalline blocks can improve the processability and solvent resistance, but adversely affects the mechanical performance. The block sequence crystalline-glassy-rubbery-glassy-crystalline has been developed to combine the advantages of both crystalline and glassy blocks. Careful selection of block lengths produces materials in which the order-disorder transition temperature lies below the melting point of the crystalline block, ensuring that the melt will be homogeneous above the melting point. Access to single-phase melts provides a large reduction in viscosity and elasticity over conventional TPEs, which remain microphase-separated in the melt. Inserting the glassy blocks between the crystalline and rubbery blocks produces a vitreous layer surrounding the crystalline domains, which improves the room-temperature mechanical performance. Incorporating the crystalline-glassy-rubbery motif into the arms of star block copolymers adds another level of control. The star architecture introduces a permanent cross-link at the center of the star without appreciably affecting the phase behavior.

  3. 47 CFR 36.352 - Other property plant and equipment expenses-Account 6510 (Class B telephone companies); Accounts...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 47 Telecommunication 2 2011-10-01 2011-10-01 false Other property plant and equipment expenses... Plant Expenses-Other § 36.352 Other property plant and equipment expenses—Account 6510 (Class B... based on the separation of Account 2001—Telecommunications Plant in Service. Network Operations Expenses...

  4. 31 CFR 536.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING... property or interests in property of a specially designated narcotics trafficker that are in the...

  5. 31 CFR 536.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING... property or interests in property of a specially designated narcotics trafficker that are in the...

  6. 31 CFR 536.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING... property or interests in property of a specially designated narcotics trafficker that are in the...

  7. 31 CFR 536.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING... property or interests in property of a specially designated narcotics trafficker that are in the...

  8. 31 CFR 536.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS TRAFFICKING... property or interests in property of a specially designated narcotics trafficker that are in the...

  9. 26 CFR 1.168(i)-7 - Accounting for MACRS property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 26 Internal Revenue 2 2014-04-01 2014-04-01 false Accounting for MACRS property. 1.168(i)-7....168(i)-7 Accounting for MACRS property. (a) In general. A taxpayer may account for MACRS property (as...) Change in method of accounting. A change to comply with this section for depreciable assets placed...

  10. 31 CFR 547.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... children in armed conflict in the Democratic Republic of the Congo in violation of applicable international law; (iv) To have committed serious violations of international law involving the targeting of... blocked pursuant to paragraph (a) of this section. Note 2 to paragraph (a) of § 547.201: The...

  11. 31 CFR 547.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... children in armed conflict in the Democratic Republic of the Congo in violation of applicable international law; (iv) To have committed serious violations of international law involving the targeting of... blocked pursuant to paragraph (a) of this section. Note 2 to paragraph (a) of § 547.201: The...

  12. 31 CFR 560.211 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... in the United States, that hereafter come within the United States, or that are or hereafter come within the possession or control of any United States person, including any foreign branch, are blocked... the United States, that hereafter come within the United States, or that are or hereafter come...

  13. 31 CFR 593.201 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Charles Taylor; (ii) To have been a senior official of the former Liberian regime headed by Charles Taylor... the identifier into Appendix A to 31 CFR chapter V. In addition, section 203 of the International Emergency Economic Powers Act (50 U.S.C. 1701-1706) (“IEEPA”) explicitly authorizes the blocking of...

  14. 49 CFR 1242.16 - Road property damaged-other (account XX-19-48).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 9 2014-10-01 2014-10-01 false Road property damaged-other (account XX-19-48... Structures § 1242.16 Road property damaged—other (account XX-19-48). Separate common expenses in proportion... accounts: Road Property Damaged—Running (XX-17-48) Road Property Damaged—Switching (XX-18-48)...

  15. 49 CFR 1242.16 - Road property damaged-other (account XX-19-48).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 9 2013-10-01 2013-10-01 false Road property damaged-other (account XX-19-48... Structures § 1242.16 Road property damaged—other (account XX-19-48). Separate common expenses in proportion... accounts: Road Property Damaged—Running (XX-17-48) Road Property Damaged—Switching (XX-18-48)...

  16. 49 CFR 1242.16 - Road property damaged-other (account XX-19-48).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 9 2012-10-01 2012-10-01 false Road property damaged-other (account XX-19-48... Structures § 1242.16 Road property damaged—other (account XX-19-48). Separate common expenses in proportion... accounts: Road Property Damaged—Running (XX-17-48) Road Property Damaged—Switching (XX-18-48)...

  17. 49 CFR 1242.16 - Road property damaged-other (account XX-19-48).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 9 2011-10-01 2011-10-01 false Road property damaged-other (account XX-19-48... Structures § 1242.16 Road property damaged—other (account XX-19-48). Separate common expenses in proportion... accounts: Road Property Damaged—Running (XX-17-48) Road Property Damaged—Switching (XX-18-48)...

  18. 49 CFR 1242.16 - Road property damaged-other (account XX-19-48).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 9 2010-10-01 2010-10-01 false Road property damaged-other (account XX-19-48... Structures § 1242.16 Road property damaged—other (account XX-19-48). Separate common expenses in proportion... accounts: Road Property Damaged—Running (XX-17-48) Road Property Damaged—Switching (XX-18-48)...

  19. 31 CFR 560.211 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... property and interests in property of the Government of Iran, including the Central Bank of Iran, that are... interests in property of any Iranian financial institution, including the Central Bank of Iran, that are in... controlled by, or operating for or on behalf of, NIOC or NICO; the Central Bank of Iran; or the purchase...

  20. 75 FR 81716 - Additional Designation Pursuant to Executive Order 13469 of July 25, 2008 “Blocking Property of...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-28

    ... ``Blocking Property of Additional Persons Undermining Democratic Processes or Institutions in Zimbabwe... ``Blocking Property of Additional Persons Undermining Democratic Processes or Institutions in Zimbabwe'' (the... issued Executive Order 13469 with respect to Zimbabwe pursuant to, inter alia, the...

  1. 78 FR 32304 - Designation of Entity Pursuant to Executive Order 13224 of September 23, 2001, “Blocking Property...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-05-29

    ... ``Blocking Property of the Government of Syria and Prohibiting Certain Transactions with Respect to Syria... 17, 2011 ``Blocking Property of the Government of Syria and Prohibiting Certain Transactions with Respect to Syria'' (collectively, the ``Orders''). OFAC is also publishing identifying...

  2. Accountability.

    ERIC Educational Resources Information Center

    Mullen, David J., Ed.

    This monograph, prepared to assist Georgia elementary principals to better understand accountability and its implications for educational improvement, sets forth many of the theoretical and philosophical bases from which accountability is being considered. Leon M. Lessinger begins this 5-paper presentation by describing the need for accountability…

  3. Accountability.

    ERIC Educational Resources Information Center

    Lashway, Larry

    1999-01-01

    This issue reviews publications that provide a starting point for principals looking for a way through the accountability maze. Each publication views accountability differently, but collectively these readings argue that even in an era of state-mandated assessment, principals can pursue proactive strategies that serve students' needs. James A.…

  4. Accountability.

    ERIC Educational Resources Information Center

    The Newsletter of the Comprehensive Center-Region VI, 1999

    1999-01-01

    Controversy surrounding the accountability movement is related to how the movement began in response to dissatisfaction with public schools. Opponents see it as one-sided, somewhat mean-spirited, and a threat to the professional status of teachers. Supporters argue that all other spheres of the workplace have accountability systems and that the…

  5. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FOREIGN NARCOTICS KINGPIN..., in property or interests in property of a specially designated narcotics trafficker is prohibited. (b... specially designated narcotics trafficker is prohibited. This prohibition includes but is not limited to...

  6. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FOREIGN NARCOTICS KINGPIN..., in property or interests in property of a specially designated narcotics trafficker is prohibited. (b... specially designated narcotics trafficker is prohibited. This prohibition includes but is not limited to...

  7. 26 CFR 1.167(a)-7 - Accounting for depreciable property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 26 Internal Revenue 2 2013-04-01 2013-04-01 false Accounting for depreciable property. 1.167(a)-7 Section 1.167(a)-7 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED....167(a)-7 Accounting for depreciable property. (a) Depreciable property may be accounted for...

  8. 26 CFR 1.167(a)-7 - Accounting for depreciable property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... contained in 26 CFR part 1 edition revised as of April 1, 2011, applies to taxable years beginning before... 26 Internal Revenue 2 2014-04-01 2014-04-01 false Accounting for depreciable property. 1.167(a)-7....167(a)-7 Accounting for depreciable property. (a) Depreciable property may be accounted for...

  9. 26 CFR 1.167(a)-7 - Accounting for depreciable property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 26 Internal Revenue 2 2012-04-01 2012-04-01 false Accounting for depreciable property. 1.167(a)-7 Section 1.167(a)-7 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED....167(a)-7 Accounting for depreciable property. (a) Depreciable property may be accounted for...

  10. Deviations from the Gutenberg-Richter law on account of a random distribution of block sizes

    NASA Astrophysics Data System (ADS)

    Sibiryakov, B. P.

    2015-10-01

    This paper studies properties of a continuum with structure. The characteristic size of the structure governs the fact that difference relations are nonautomatically transformed into differential ones. It is impossible to consider an infinitesimal volume of a body, to which the major conservation laws could be applied, because the minimum representative volume of the body must contain at least a few elementary microstructures. The corresponding equations of motion are equations of infinite order, solutions of which include, along with usual sound waves, unusual waves with abnormally low velocities without a lower limit. It is shown that in such media weak perturbations can increase or decrease outside the limits. The number of complex roots of the corresponding dispersion equation, which can be interpreted as the number of unstable solutions, depends on the specific surface of cracks and is an almost linear dependence on a logarithmic scale, as in the seismological Gutenberg-Richter law. If the distance between one pore (crack) to another one is a random value with some distribution, we must write another dispersion equation and examine different scenarios depending on the statistical characteristics of the random distribution. In this case, there are sufficient deviations from the Gutenberg-Richter law and this theoretical result corresponds to some field and laboratory observations.

  11. Deviations from the Gutenberg–Richter law on account of a random distribution of block sizes

    SciTech Connect

    Sibiryakov, B. P.

    2015-10-27

    This paper studies properties of a continuum with structure. The characteristic size of the structure governs the fact that difference relations are nonautomatically transformed into differential ones. It is impossible to consider an infinitesimal volume of a body, to which the major conservation laws could be applied, because the minimum representative volume of the body must contain at least a few elementary microstructures. The corresponding equations of motion are equations of infinite order, solutions of which include, along with usual sound waves, unusual waves with abnormally low velocities without a lower limit. It is shown that in such media weak perturbations can increase or decrease outside the limits. The number of complex roots of the corresponding dispersion equation, which can be interpreted as the number of unstable solutions, depends on the specific surface of cracks and is an almost linear dependence on a logarithmic scale, as in the seismological Gutenberg–Richter law. If the distance between one pore (crack) to another one is a random value with some distribution, we must write another dispersion equation and examine different scenarios depending on the statistical characteristics of the random distribution. In this case, there are sufficient deviations from the Gutenberg–Richter law and this theoretical result corresponds to some field and laboratory observations.

  12. 47 CFR 36.352 - Other property plant and equipment expenses-Account 6510 (Class B telephone companies); Accounts...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 2 2010-10-01 2010-10-01 false Other property plant and equipment expenses... Section 36.352 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES... Plant Expenses-Other § 36.352 Other property plant and equipment expenses—Account 6510 (Class...

  13. 47 CFR 36.352 - Other property plant and equipment expenses-Account 6510 (Class B telephone companies); Accounts...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 47 Telecommunication 2 2013-10-01 2013-10-01 false Other property plant and equipment expenses... Section 36.352 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES... Plant Expenses-Other § 36.352 Other property plant and equipment expenses—Account 6510 (Class...

  14. 47 CFR 36.352 - Other property plant and equipment expenses-Account 6510 (Class B telephone companies); Accounts...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 47 Telecommunication 2 2014-10-01 2014-10-01 false Other property plant and equipment expenses... Section 36.352 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES... Plant Expenses-Other § 36.352 Other property plant and equipment expenses—Account 6510 (Class...

  15. 47 CFR 36.352 - Other property plant and equipment expenses-Account 6510 (Class B telephone companies); Accounts...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 47 Telecommunication 2 2012-10-01 2012-10-01 false Other property plant and equipment expenses... Section 36.352 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED) COMMON CARRIER SERVICES... Plant Expenses-Other § 36.352 Other property plant and equipment expenses—Account 6510 (Class...

  16. 48 CFR 1852.245-77 - List of installation-accountable property and services.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Government Property, the Contractor is authorized use of the types of property and services listed below, to...-accountable property and services. 1852.245-77 Section 1852.245-77 Federal Acquisition Regulations System... CLAUSES Texts of Provisions and Clauses 1852.245-77 List of installation-accountable property and...

  17. 77 FR 41243 - Blocking Property of Persons Threatening the Peace, Security, or Stability of Burma

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-07-13

    ... criteria in subsection 1(a) of this order would be detrimental to the interests of the United States, and I... person in the United States. Sec. 9. For those persons whose property and interests in property are blocked pursuant to this order who might have a constitutional presence ] in the United......

  18. 31 CFR 562.406 - Entities owned by a person whose property and interests in property are blocked.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Entities owned by a person whose property and interests in property are blocked. 562.406 Section 562.406 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  19. 31 CFR 510.406 - Entities owned by a person whose property and interests in property are blocked.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Entities owned by a person whose property and interests in property are blocked. 510.406 Section 510.406 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH KOREA SANCTIONS...

  20. 31 CFR 562.406 - Entities owned by a person whose property and interests in property are blocked.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Entities owned by a person whose property and interests in property are blocked. 562.406 Section 562.406 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  1. 31 CFR 562.406 - Entities owned by a person whose property and interests in property are blocked.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Entities owned by a person whose property and interests in property are blocked. 562.406 Section 562.406 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  2. 31 CFR 562.406 - Entities owned by a person whose property and interests in property are blocked.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Entities owned by a person whose property and interests in property are blocked. 562.406 Section 562.406 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY IRANIAN HUMAN RIGHTS ABUSES...

  3. 18 CFR 367.3991 - Account 399.1, Asset retirement costs for service company property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 399.1, Asset retirement costs for service company property. 367.3991 Section 367.3991 Conservation of Power and Water..., FEDERAL POWER ACT AND NATURAL GAS ACT Service Company Property Chart of Accounts § 367.3991 Account...

  4. 18 CFR 367.1011 - Account 101.1, Property under capital leases.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 101.1, Property under capital leases. 367.1011 Section 367.1011 Conservation of Power and Water Resources FEDERAL ENERGY... GAS ACT Balance Sheet Chart of Accounts § 367.1011 Account 101.1, Property under capital leases....

  5. 18 CFR 367.3991 - Account 399.1, Asset retirement costs for service company property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 399.1, Asset retirement costs for service company property. 367.3991 Section 367.3991 Conservation of Power and Water..., FEDERAL POWER ACT AND NATURAL GAS ACT Service Company Property Chart of Accounts § 367.3991 Account...

  6. 18 CFR 367.1080 - Account 108, Accumulated provision for depreciation of service company property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ..., Accumulated provision for depreciation of service company property. 367.1080 Section 367.1080 Conservation of... Account 108, Accumulated provision for depreciation of service company property. (a) This account must be credited with the following: (1) Amounts charged to account 403, Depreciation expense (§ 367.4030), or...

  7. 48 CFR 1852.245-71 - Installation-accountable Government property.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Government property. 1852.245-71 Section 1852.245-71 Federal Acquisition Regulations System NATIONAL... Provisions and Clauses 1852.245-71 Installation-accountable Government property. As prescribed in 1845.107-70(b)(1), insert the following clause: Installation-Accountable Government Property (JAN 2011) (a)...

  8. 31 CFR 589.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Termination and acquisition of an interest in blocked property. 589.403 Section 589.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  9. 31 CFR 537.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Termination and acquisition of an interest in blocked property. 537.403 Section 537.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  10. 31 CFR 537.201 - Prohibited transactions involving certain blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Prohibited transactions involving certain blocked property. 537.201 Section 537.201 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  11. 31 CFR 551.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Termination and acquisition of an interest in blocked property. 551.403 Section 551.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  12. 31 CFR 541.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Termination and acquisition of an interest in blocked property. 541.403 Section 541.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  13. 31 CFR 551.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Termination and acquisition of an interest in blocked property. 551.403 Section 551.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  14. 31 CFR 551.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Termination and acquisition of an interest in blocked property. 551.403 Section 551.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  15. 31 CFR 551.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Termination and acquisition of an interest in blocked property. 551.403 Section 551.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  16. 31 CFR 551.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Termination and acquisition of an interest in blocked property. 551.403 Section 551.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  17. 31 CFR 548.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Termination and acquisition of an interest in blocked property. 548.403 Section 548.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  18. 31 CFR 548.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Termination and acquisition of an interest in blocked property. 548.403 Section 548.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  19. 31 CFR 548.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Termination and acquisition of an interest in blocked property. 548.403 Section 548.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  20. 31 CFR 548.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Termination and acquisition of an interest in blocked property. 548.403 Section 548.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  1. 31 CFR 548.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Termination and acquisition of an interest in blocked property. 548.403 Section 548.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  2. 31 CFR 510.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Termination and acquisition of an interest in blocked property. 510.403 Section 510.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH...

  3. 31 CFR 510.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Termination and acquisition of an interest in blocked property. 510.403 Section 510.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH...

  4. 31 CFR 510.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Termination and acquisition of an interest in blocked property. 510.403 Section 510.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH...

  5. 31 CFR 510.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Termination and acquisition of an interest in blocked property. 510.403 Section 510.403 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NORTH...

  6. 31 CFR 594.404 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Termination and acquisition of an interest in blocked property. 594.404 Section 594.404 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY...

  7. 24 CFR 570.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... rehabilitation of primarily residential properties containing no more than four dwelling units (and accessory... dwelling unit). (2) An escrow account shall not be used unless the contract between the property owner and... contact governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made...

  8. 24 CFR 1003.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... rehabilitation of primarily residential properties containing no more than four dwelling units (and accessory... dwelling unit). (2) An escrow account shall not be used unless the contract between the property owner and... governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made until...

  9. 24 CFR 570.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... rehabilitation of primarily residential properties containing no more than four dwelling units (and accessory... dwelling unit). (2) An escrow account shall not be used unless the contract between the property owner and... contact governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made...

  10. 18 CFR 367.4050 - Account 405, Amortization of other property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 405, Amortization of other property. 367.4050 Section 367.4050 Conservation of Power and Water Resources FEDERAL..., Amortization of other property. (a) When authorized by the Commission, this account must include charges...

  11. 18 CFR 367.4211 - Account 421.1, Gain on disposition of property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 421.1, Gain on disposition of property. 367.4211 Section 367.4211 Conservation of Power and Water Resources FEDERAL ENERGY..., Gain on disposition of property. This account must be credited with the gain on the sale,...

  12. 18 CFR 367.4050 - Account 405, Amortization of other property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 405, Amortization of other property. 367.4050 Section 367.4050 Conservation of Power and Water Resources FEDERAL..., Amortization of other property. (a) When authorized by the Commission, this account must include charges...

  13. 18 CFR 367.4212 - Account 421.2, Loss on disposition of property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 421.2, Loss on disposition of property. 367.4212 Section 367.4212 Conservation of Power and Water Resources FEDERAL ENERGY..., Loss on disposition of property. This account must be charged with the loss on the sale,...

  14. 48 CFR 1852.245-71 - Installation-accountable Government property.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Document (or installation equivalent) to transfer accountability to the Government within 5 working days... Government property. 1852.245-71 Section 1852.245-71 Federal Acquisition Regulations System NATIONAL... Provisions and Clauses 1852.245-71 Installation-accountable Government property. As prescribed in...

  15. Assessment of the thermal and physical properties of masonry block products

    SciTech Connect

    Valore, R. Jr.; Tuluca, A.; Caputo, A.

    1988-09-01

    The objective of this study was to assess the current knowledge on the thermal and physical properties of concrete masonry units and fired clay bricks, and to outline directions for further research. In particular, the authors attempted to uncover the areas where thermal properties data are missing or are questionable, to define the type of testing required to fill in the gaps, and to characterize representative masonry blocks on which the testing should be undertaken. US building codes and standards were examined with respect to the thermal properties of masonry block products. It was concluded that the majority of these codes and standards contain insufficient and/or outdated information regarding concrete masonry units and fired clay bricks, thereby distorting the requirements for walls built with masonry units. A comprehensive bibliography search was performed and the thermal properties data obtained were listed and analyzed. Relationships were derived between oven dry density and thermal conductivity for various concretes, clays, and loose fills. The relationship between moisture content and thermal conductivity was also examined. Areas with incomplete and/or contradictory information were identified. Based on these data gaps and on data quality problems, new testing programs were recommended and improvements to current testing procedures were proposed. The study also suggest low-cost test procedures which could be applied to large numbers of masonry blocks. 228 refs., 26 figs., 31 tabs.

  16. Morphology And Local Mechanical Properties Of A Block Copolymer Cell Substrate

    NASA Astrophysics Data System (ADS)

    Wall, Craig; Yermolenko, Ivan; Krishnan, G. Rajesh; Sarkar, Debanjan; Alexander, John

    2014-03-01

    Atomic force microscopy (AFM) was applied for the characterization of morphology and mechanical properties of a block copolymer coating designed for biomaterials applications. The material is a block-copolymer with poly(ethylene glycol) as one block and a peptide as second block, which are connected through urethane bonds. The AFM images obtained in amplitude modulation mode revealed the morphology is characterized by micron-scale sheaf-like structures embedded in a more homogeneous and, presumably, amorphous matrix. The self-assembly of the peptide segments is responsible for the formation of the ordered sheaf structures and this phenomenon was common for different variations of the components. Maps of elastic modulus and work of adhesion of the block copolymer, which also differentiate the matrix and ordered regions, were obtained with Hybrid mode at different tip-force levels. The quantitative estimates show that elastic modulus varies in the MPa range and work of adhesion in the hundreds of mJ/m2 range. These data are compared with AFM-based nanoindentation that was performed at higher tip-force level. The results indicate that material surface is more complicated and they suggest in-depth morphology variations. A tentative model of the structural organization is proposed.

  17. Insulin/poly(ethylene glycol)-block-poly(L-lysine) Complexes: Physicochemical Properties and Protein Encapsulation.

    PubMed

    Pippa, Natassa; Kalinova, Radostina; Dimitrov, Ivaylo; Pispas, Stergios; Demetzos, Costas

    2015-06-01

    Insulin (INS) was encapsulated into complexes with poly(ethylene glycol)-block-poly(L-lysine) (PEG-b-PLys), which is a polypeptide-based block copolymer (a neutral-cationic block polyelectrolyte). The particular cationic-neutral block copolymer can complex INS molecules in aqueous media via electrostatic interactions. Light-scattering techniques are used to study the complexation process and structure of the hybrid nanoparticles in a series of buffers, as a function of protein concentration. The physicochemical and structural characteristics of the complexes depend on the ionic strength of the aqueous medium, while the concentration of PEG-b-PLys was constant through the series of solutions. As INS concentration increased the size distribution of the complexes decreased, especially at the highest ionic strength. The size/structure of complexes diluted in biological medium indicated that the copolymer imparts stealth properties and colloidal and biological stability to the complexes, features that could in turn affect the clearance properties in vivo. Therefore, these studies could be a rational roadmap for designing the optimum complexes/effective nanocarriers for proteins and peptides. PMID:25974620

  18. Block Copolymer Modified Epoxy Amine System for Reactive Rotational Molding: Structures, Properties and Processability

    NASA Astrophysics Data System (ADS)

    Lecocq, Eva; Nony, Fabien; Tcharkhtchi, Abbas; Gérard, Jean-François

    2011-05-01

    Poly(styrene-butadiene-methylmethacrylate) (SBM) and poly(methylmethacrylate-butyle-acrylate-methylmethacrylate) (MAM) triblock copolymers have been dissolved in liquid DGEBA epoxy resin which is subsequently polymerized by meta-xylene diamine (MXDA) or Jeffamine EDR-148. A chemorheology study of these formulations by plate-plate rheology and by thermal analysis has allowed to conclude that the addition of these copolymer blocks improve the reactive rotational moulding processability without affecting the processing time. Indeed, it prevents the pooling of the formulation at the bottom of the mould and a too rapid build up of resin viscosity of these thermosetting systems. The morphology of the cured blends examined by scanning electron microscopy (SEM) shows an increase of fracture surface area and thereby a potential increase of the toughness with the modification of epoxy system. Dynamic mechanical spectroscopy (DMA) and opalescence of final material show that the block PMMA, initially miscible, is likely to induce phase separation from the epoxy-amine matrix. Thereby, the poor compatibilisation between the toughener and the matrix has a detrimental effect on the tensile mechanical properties. The compatibilisation has to be increased to improve in synergy the processability and the final properties of these block copolymer modified formulations. First attempts could be by adapting the length and ratio of each block.

  19. Experimental study on properties of methane diffusion of coal block under triaxial compressive stress.

    PubMed

    Zhao, Hong-Bao

    2014-01-01

    Taking the standard size coal block samples defined by ISRM as research objects, both properties of methane diffusion of coal block under triaxial compressive stress and characteristic influences caused by methane pressure were systematically studied with thermo-fluid-solid coupling with triaxial servocontrolled seepage equipment of methane-containing coal. The result shows the methane diffusion property of coal block under triaxial compressive stress was shown in four-stage as follow, first is sharply reduce stage, second is hyperbolic reduce stage, third is close to a fixed value stage, fourth stage is 0. There is a special point making the reduced rate of characteristic curve of methane diffusion speed become sharply small; the influences of shape of methane diffusion speed characteristic curve caused by methane pressure are not obvious, which only is shown in numerical size of methane diffusion speed. Test time was extended required by appear of the special point makes the reduce rate of methane diffusion speed become sharply small. The fitting four-phase relation of methane diffusion of coal block under triaxial compressive stress was obtained, and the idea is proposed that influences of the fitting four-phase relation caused by methane pressure were only shown in value of fitting parameters.

  20. Experimental Study on Properties of Methane Diffusion of Coal Block under Triaxial Compressive Stress

    PubMed Central

    Zhao, Hong-Bao

    2014-01-01

    Taking the standard size coal block samples defined by ISRM as research objects, both properties of methane diffusion of coal block under triaxial compressive stress and characteristic influences caused by methane pressure were systematically studied with thermo-fluid-solid coupling with triaxial servocontrolled seepage equipment of methane-containing coal. The result shows the methane diffusion property of coal block under triaxial compressive stress was shown in four-stage as follow, first is sharply reduce stage, second is hyperbolic reduce stage, third is close to a fixed value stage, fourth stage is 0. There is a special point making the reduced rate of characteristic curve of methane diffusion speed become sharply small; the influences of shape of methane diffusion speed characteristic curve caused by methane pressure are not obvious, which only is shown in numerical size of methane diffusion speed. Test time was extended required by appear of the special point makes the reduce rate of methane diffusion speed become sharply small. The fitting four-phase relation of methane diffusion of coal block under triaxial compressive stress was obtained, and the idea is proposed that influences of the fitting four-phase relation caused by methane pressure were only shown in value of fitting parameters. PMID:25531000

  1. Activation of spleen cells by ArtinM may account for its immunomodulatory properties.

    PubMed

    Silva, Thiago Aparecido da; Souza, Maria Aparecida de; Cecílio, Nerry Tatiana; Roque-Barreira, Maria Cristina

    2014-09-01

    ArtinM is a D-mannose-binding lectin extracted from Artocarpus heterophyllus that promotes interleukin-12 production by macrophages and dendritic cells. This property is considered responsible for T helper 1 immunity induced in vivo after ArtinM administration. In this study, we investigated the effect of native (jArtinM) and recombinant (rArtinM) forms of lectin on murine spleen cells and isolated T lymphocytes. We found that ArtinM binds to the surface of spleen cells. This interaction, which was blocked by D-mannose, induced cell activation, as manifested by increased mitochondrial activity, interleukin-2 production, and cell proliferation. We verified that a 30-times higher concentration of rArtinM was required to trigger optimal activation of spleen cells compared with that needed with jArtinM, although these proteins have identical sugar recognition properties and use the same signaling molecules to trigger cell activation. Because the distinction between native and recombinant is restricted to their tertiary structure (tetrameric and monomeric, respectively), we postulated that the multi-valence of jArtinM accounts for its superiority in promoting clustering of cell surface glycoreceptors and activation. The jArtinM and rArtinM activation effect exerted on spleen cells was reproduced on purified CD4(+) T cells. Our results suggest that ArtinM interaction with T cells leads to responses that may act in concert with the interleukin-12 produced by antigen-presenting cells to modulate immunity toward the T helper 1 axis. Further studies are necessary to dissect ArtinM/T-cell interactions to more fully understand the immunomodulation induced by carbohydrate recognition. PMID:24842046

  2. Activation of spleen cells by ArtinM may account for its immunomodulatory properties.

    PubMed

    Silva, Thiago Aparecido da; Souza, Maria Aparecida de; Cecílio, Nerry Tatiana; Roque-Barreira, Maria Cristina

    2014-09-01

    ArtinM is a D-mannose-binding lectin extracted from Artocarpus heterophyllus that promotes interleukin-12 production by macrophages and dendritic cells. This property is considered responsible for T helper 1 immunity induced in vivo after ArtinM administration. In this study, we investigated the effect of native (jArtinM) and recombinant (rArtinM) forms of lectin on murine spleen cells and isolated T lymphocytes. We found that ArtinM binds to the surface of spleen cells. This interaction, which was blocked by D-mannose, induced cell activation, as manifested by increased mitochondrial activity, interleukin-2 production, and cell proliferation. We verified that a 30-times higher concentration of rArtinM was required to trigger optimal activation of spleen cells compared with that needed with jArtinM, although these proteins have identical sugar recognition properties and use the same signaling molecules to trigger cell activation. Because the distinction between native and recombinant is restricted to their tertiary structure (tetrameric and monomeric, respectively), we postulated that the multi-valence of jArtinM accounts for its superiority in promoting clustering of cell surface glycoreceptors and activation. The jArtinM and rArtinM activation effect exerted on spleen cells was reproduced on purified CD4(+) T cells. Our results suggest that ArtinM interaction with T cells leads to responses that may act in concert with the interleukin-12 produced by antigen-presenting cells to modulate immunity toward the T helper 1 axis. Further studies are necessary to dissect ArtinM/T-cell interactions to more fully understand the immunomodulation induced by carbohydrate recognition.

  3. An evacuation model accounting for elementary students' individual properties

    NASA Astrophysics Data System (ADS)

    Tang, Tie-Qiao; Chen, Liang; Guo, Ren-Yong; Shang, Hua-Yan

    2015-12-01

    In this paper, we propose a cellular automata model for pedestrian flow to investigate the effects of elementary students' individual properties on the evacuation process in a classroom with two exits. In this model, each student's route choice behavior is determined by the capacity of his current route to each exit, the distance between his current position and the corresponding exit, the repulsive interactions between his adjacent students and him, and the congestion degree near each exit; the elementary students are sorted into rational and irrational students. The simulation results show that the irrational students' proportion has significant impacts on the evacuation process and efficiency, and that all students simultaneously evacuating may be inefficient.

  4. 77 FR 12837 - Notice of Release of the Exposure Draft, Accounting for Impairment of General Property, Plant...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-03-02

    ..., Plant, and Equipment Remaining in Use AGENCY: Federal Accounting Standards Advisory Board. ACTION..., Accounting for Impairment of General Property, Plant, and Equipment Remaining in Use. The Exposure Draft...

  5. Choice of optimal properties of molding compounds for extrusion of block supports and catalysts with the honeycomb structure

    SciTech Connect

    Prokof`ev, V.Yu.; Il`in, A.P.; Shirokov, Yu.G.; Yurchenko, E.N.

    1995-09-20

    Properties of compounds for molding of block supports and catalysts with the honeycomb structure have been studied. The examples studied include ultraporcelain, alumina, titanium dioxide, clays, and graphite. The molding properties of these compounds are characterized by such parameters as the relationship between deformations, relaxation time, power for destruction of the coagulation structure, and flow index. For molding of blocks with the honeycomb structure compounds with enhanced plastic properties and a stable coagulation structure are suggested.

  6. Anti-Biofouling Properties of Comblike Block Copolymers with Amphiphilic Side Chains

    SciTech Connect

    Krishnan,S.; Ayothi, R.; Hexemer, A.; Finlay, J.; Sohn, K.; Perry, R.; Ober, C.; Kramer, E.; Callow, M.; et al.

    2006-01-01

    Surfaces of novel block copolymers with amphiphilic side chains were studied for their ability to influence the adhesion of marine organisms. The surface-active polymer, obtained by grafting fluorinated molecules with hydrophobic and hydrophilic blocks to a block copolymer precursor, showed interesting bioadhesion properties. Two different algal species, one of which adhered strongly to hydrophobic surfaces, and the other, to hydrophilic surfaces, showed notably weak adhesion to the amphiphilic surfaces. Both organisms are known to secrete adhesive macromolecules, with apparently different wetting characteristics, to attach to underwater surfaces. The ability of the amphiphilic surface to undergo an environment-dependent transformation in surface chemistry when in contact with the extracellular polymeric substances is a possible reason for its antifouling nature. Near-edge X-ray absorption fine structure spectroscopy (NEXAFS) was used, in a new approach based on angle-resolved X-ray photoelectron spectroscopy (XPS), to determine the variation in chemical composition within the top few nanometers of the surface and also to study the surface segregation of the amphiphilic block. A mathematical model to extract depth-profile information from the normalized NEXAFS partial electron yield is developed.

  7. Accounting Issues: An Essay Series Part IV--Property, Plant, & Equipment

    ERIC Educational Resources Information Center

    Laux, Judy

    2007-01-01

    This fourth article in a series of theoretical essays intended to supplement the introductory financial accounting course is dedicated to the topic of property, plant, and equipment (PP&E), including both the accounting treatment and its related conceptual connections. The paper also addresses the measurement dilemmas, scandalous accounting…

  8. 18 CFR 367.4040 - Account 404, Amortization of limited-term property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 404, Amortization of limited-term property. 367.4040 Section 367.4040 Conservation of Power and Water Resources... COMPANY ACT OF 2005, FEDERAL POWER ACT AND NATURAL GAS ACT UNIFORM SYSTEM OF ACCOUNTS FOR...

  9. 18 CFR 367.4040 - Account 404, Amortization of limited-term property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Account 404, Amortization of limited-term property. 367.4040 Section 367.4040 Conservation of Power and Water Resources... COMPANY ACT OF 2005, FEDERAL POWER ACT AND NATURAL GAS ACT UNIFORM SYSTEM OF ACCOUNTS FOR...

  10. 18 CFR 367.4040 - Account 404, Amortization of limited-term property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Account 404, Amortization of limited-term property. 367.4040 Section 367.4040 Conservation of Power and Water Resources... COMPANY ACT OF 2005, FEDERAL POWER ACT AND NATURAL GAS ACT UNIFORM SYSTEM OF ACCOUNTS FOR...

  11. 18 CFR 367.4040 - Account 404, Amortization of limited-term property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 404, Amortization of limited-term property. 367.4040 Section 367.4040 Conservation of Power and Water Resources... COMPANY ACT OF 2005, FEDERAL POWER ACT AND NATURAL GAS ACT UNIFORM SYSTEM OF ACCOUNTS FOR...

  12. 18 CFR 367.1080 - Account 108, Accumulated provision for depreciation of service company property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 108, Accumulated provision for depreciation of service company property. 367.1080 Section 367.1080 Conservation of... COMPANY ACT OF 2005, FEDERAL POWER ACT AND NATURAL GAS ACT Balance Sheet Chart of Accounts §...

  13. Amphiphilic Spider Silk-Like Block Copolymers with Tunable Physical Properties and Morphology for Biomedical Applications

    NASA Astrophysics Data System (ADS)

    Huang, Wenwen; Krishnaji, Sreevidhya; Kaplan, David; Cebe, Peggy

    2013-03-01

    Silk-based materials are important candidates for biomedical applications because of their excellent biocompatibility and biodegradability. To generate silk amphiphilic biopolymers with potential use in guided tissue repair and drug delivery, a novel family of spider silk-like block copolymers was synthesized by recombinant DNA technology. Block copolymer thermal properties, structural conformations, protein-water interactions, and self-assembly morphologies were studied with respect to well controlled protein amino acid sequences. A theoretical model was used to predict the heat capacity of the protein and protein-water complex. Using thermal analysis, two glass transitions were observed: Tg1 is related to conformational changes caused by bound water removal, while Tg2 (>Tg1) is the glass transition of dry protein. Real-time infrared spectroscopy and X-ray diffraction confirmed that different secondary structural changes occur during the two Tg relaxations. Using scanning electron microscopy, fibrillar networks and hollow vesicles are observed, depending on protein block copolymer sequence. This study provides a deeper understanding of the relationship between protein physical properties and amino acid sequence, with implications for design of other protein-based materials. Support was provided from the NSF CBET-0828028 and the MRI Program under DMR-0520655 for thermal analysis instrumentation.

  14. The properties of batrachotoxin-modified cardiac Na channels, including state-dependent block by tetrodotoxin

    PubMed Central

    1987-01-01

    Batrachotoxin (BTX) modification and tetrodotoxin (TTX) block of BTX- modified Na channels were studied in single cardiac cells of neonatal rats using the whole-cell patch-clamp recording technique. The properties of BTX-modified Na channels in heart are qualitatively similar to those in nerve. However, quantitative differences do exist between the modified channels of these two tissues. In the heart, the shift of the conductance-voltage curve for the modified channel was less pronounced, the maximal activation rate constant, (tau m)max, of modified channels was considerably slower, and the slow inactivation of the BTX-modified cardiac Na channels was only partially abolished. TTX blocked BTX-modified mammalian cardiac Na channels and the block decreased over the potential range of -80 to -40 mV. The apparent dissociation constant of TTX changed from 0.23 microM at -50 mV to 0.69 microM at 0 mV. No further reduction of block was observed at potentials greater than -40 mV. This is the potential range over which gating from closed to open states occurred. These results were explained by assuming that TTX has a higher affinity for closed BTX- modified channels than for open modified channels. Hence, the TTX- binding rate constants are considered to be state dependent rather than voltage dependent. This differs from the voltage dependence of TTX block reported for BTX-modified Na channels from membrane vesicles incorporated into lipid bilayers and from amphibian node of Ranvier. PMID:2443605

  15. Structure-property relationships in multilayered polymeric system and olefinic block copolymers

    NASA Astrophysics Data System (ADS)

    Khariwala, Devang

    diffusion. Subsequently, the oxygen permeability was directly related to the composition profile in each layer and changed as the interdiffusion proceeded. This methodology enabled the extraction of the mutual diffusion co-efficient, D, for the Nylon-6/EVOH system. The effect of comonomer content in EVOH on the mutual diffusion coefficient was also studied by comparing the kinetics of interdiffusion of Nylon-6 with two EVOHs containing 24 and 44 mole % ethylene. Chapter 3. Exciting new developments in polyolefin synthesis give rise to olefinic block copolymers with properties typical of thermoplastic elastomers. The block copolymers synthesized by chain shuttling technology consist of crystallizable ethylene-octene blocks with low comonomer content and high melting temperature (hard blocks), alternating with amorphous ethylene-octene blocks with high comonomer content and low glass transition temperature (soft blocks). This study describes the material science of these unique polymers as characterized by thermal analysis, X-ray diffraction, microscopy, and tensile deformation. The crystallizable blocks are long enough to form well-organized lamellar crystals with the orthorhombic unit cell and high melting temperature. The lamellae are organized into space-filling spherulites in all compositions even in copolymers with only 18 wt% hard block. The morphology is consistent with crystallization from a miscible melt. Crystallization of the hard blocks forces segregation of the noncrystallizable soft blocks into the interlamellar regions. Good separation of hard and soft blocks in the solid state is confirmed by distinct and separate beta- and alpha-relaxations in all the block copolymers. Compared to statistical ethylene-octene copolymers, the blocky architecture imparts a substantially higher crystallization temperature, a higher melting temperature and a better organized crystalline morphology, while maintaining a lower glass transition temperature. The differences between

  16. 18 CFR 367.2820 - Account 282, Accumulated deferred income taxes-Other property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ..., Accumulated deferred income taxes-Other property. 367.2820 Section 367.2820 Conservation of Power and Water... 282, Accumulated deferred income taxes—Other property. (a) This account must include the tax deferrals resulting from adoption of the principle of comprehensive inter-period income tax allocation described...

  17. 18 CFR 367.2820 - Account 282, Accumulated deferred income taxes-Other property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ..., Accumulated deferred income taxes-Other property. 367.2820 Section 367.2820 Conservation of Power and Water... 282, Accumulated deferred income taxes—Other property. (a) This account must include the tax deferrals resulting from adoption of the principle of comprehensive inter-period income tax allocation described...

  18. 18 CFR 367.2820 - Account 282, Accumulated deferred income taxes-Other property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ..., Accumulated deferred income taxes-Other property. 367.2820 Section 367.2820 Conservation of Power and Water... 282, Accumulated deferred income taxes—Other property. (a) This account must include the tax deferrals resulting from adoption of the principle of comprehensive inter-period income tax allocation described...

  19. 18 CFR 367.2820 - Account 282, Accumulated deferred income taxes-Other property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ..., Accumulated deferred income taxes-Other property. 367.2820 Section 367.2820 Conservation of Power and Water... 282, Accumulated deferred income taxes—Other property. (a) This account must include the tax deferrals resulting from adoption of the principle of comprehensive inter-period income tax allocation described...

  20. 76 FR 2193 - Designation Pursuant to Executive Order 13396 of February 7, 2006, “Blocking Property of Certain...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-01-12

    ..., ``Blocking Property of Certain Persons Contributing to the Conflict in C te d'Ivoire'' AGENCY: Office of... Persons Contributing to the Conflict in C te d'Ivoire'' (the ``Order''). DATES: The designation by...

  1. Effect of Orientation on Tensile Properties of Inconel 718 Block Fabricated with Electron Beam Freeform Fabrication (EBF3)

    NASA Technical Reports Server (NTRS)

    Bird, R. Keith; Atherton, Todd S.

    2010-01-01

    Electron beam freeform fabrication (EBF3) direct metal deposition processing was used to fabricate an Inconel 718 bulk block deposit. Room temperature tensile properties were measured as a function of orientation and location within the block build. This study is a follow-on activity to previous work on Inconel 718 EBF3 deposits that were too narrow to allow properties to be measured in more than one orientation

  2. The neuromuscular blocking properties of a series of bis-quaternary tropeïnes

    PubMed Central

    Haining, C. G.; Johnston, R. G.; Smith, J. M.

    1960-01-01

    Linkage of two tropine esters through their nitrogen atoms by the chain -[CH2]m-O-CO-[CH2]n-CO-O-[CH2]m-, in which m was 2 or 3 and n varied from 0 to 6, gave compounds which produced neuromuscular block without depolarization. Reversibility be neostigmine was confirmed for a few compounds. Potency was found to depend upon the tropine ester employed and upon the values of n and m. Short duration and hypotensive properties were favoured by the higher values of n. The duration of action of the compound based on the phenylacetic acid ester of tropine, in which n=4 and m=2, varied considerably in different species. Epimerization, in which the relative positions of the methyl group and the linking chain on the quaternary tropane nitrogen atom were reversed, did not produce subtances having more favourable properties than those possessed by the unepimerized compounds. PMID:14398886

  3. Polymer electrolyte membranes from fluorinated polyisoprene-block-sulfonated polystyrene: Membrane structure and transport properties

    SciTech Connect

    Sodeye, Akinbode; Huang, Tianzi; Gido, Samuel; Mays, Jimmy

    2011-01-01

    With a view to optimizing morphology and ultimately properties, membranes have been cast from relatively inexpensive block copolymer ionomers of fluorinated polyisoprene-block-sulfonated polystyrene (FISS) with various sulfonation levels, in both the acid form and the cesium neutralized form. The morphology of these membranes was characterized by transmission electron microscopy and ultra-small angle X-ray scattering, as well as water uptake, proton conductivity and methanol permeability within the temperature range from 20 to 60 C. Random phase separated morphologies were obtained for all samples except the cesium sample with 50 mol% sulfonation. The transport properties increased with increasing degree of sulfonation and temperature for all samples. The acid form samples absorbed more water than the cesium samples with a maximum swelling of 595% recorded at 60 C for the acid sample having 50 mol% sulfonation. Methanol permeability for the latter sample was more than an order of magnitude less than for Nafion 112 but so was the proton conductivity within the plane of the membrane at 20 C. Across the plane of the membrane this sample had half the conductivity of Nafion 112 at 60 C.

  4. 31 CFR 575.503 - Payments and transfers to blocked accounts in U.S. financial institutions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... the Government of Iraq is hereby authorized, including incidental foreign exchange transactions... transfer represents, directly or indirectly, a transfer of any interest of the Government of Iraq to any... account held in a name other than that of the Government of Iraq where such government is the...

  5. 77 FR 10808 - Designation of One Entity Pursuant to Executive Order 13572 of April 29, 2011, “Blocking Property...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-02-23

    ..., 2011, ``Blocking Property of Certain Persons With Respect to Human Rights Abuses in Syria'' AGENCY... of Certain Persons with Respect to Human Rights Abuses in Syria.'' DATES: The designation by the... Property of Certain Persons with Respect to Human Rights Abuses in Syria,'' (the ``Order'') pursuant...

  6. 47 CFR 36.171 - Property held for future telecommunications use-Account 2002; Telecommunications plant under...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ...-Account 2002; Telecommunications plant under construction-Account 2003; and Telecommunications plant adjustment-Account 2005. 36.171 Section 36.171 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED... Telecommunications Property Telecommunications Plant-Other § 36.171 Property held for future telecommunications...

  7. 47 CFR 36.171 - Property held for future telecommunications use-Account 2002; Telecommunications plant under...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ...-Account 2002; Telecommunications plant under construction-Account 2003; and Telecommunications plant adjustment-Account 2005. 36.171 Section 36.171 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED... Telecommunications Property Telecommunications Plant-Other § 36.171 Property held for future telecommunications...

  8. 47 CFR 36.171 - Property held for future telecommunications use-Account 2002; Telecommunications plant under...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ...-Account 2002; Telecommunications plant under construction-Account 2003; and Telecommunications plant adjustment-Account 2005. 36.171 Section 36.171 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED... Telecommunications Property Telecommunications Plant-Other § 36.171 Property held for future telecommunications...

  9. 47 CFR 36.171 - Property held for future telecommunications use-Account 2002; Telecommunications plant under...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ...-Account 2002; Telecommunications plant under construction-Account 2003; and Telecommunications plant adjustment-Account 2005. 36.171 Section 36.171 Telecommunication FEDERAL COMMUNICATIONS COMMISSION (CONTINUED... Telecommunications Property Telecommunications Plant-Other § 36.171 Property held for future telecommunications...

  10. Property Accounting for State and Local School Systems. Bulletin, 1959, No. 22

    ERIC Educational Resources Information Center

    Reason, Paul L., Comp.; Tankard, George G., Jr., Comp.

    1959-01-01

    This handbook is a guide to property accounting for local and State school systems. It classifies and defines the specific items of information about land, buildings, and equipment that need to be comparable among local school systems and among States, and presents additional terminology essential to their effective use. As such, it is concerned…

  11. 18 CFR 367.4211 - Account 421.1, Gain on disposition of property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 421.1, Gain on disposition of property. 367.4211 Section 367.4211 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE PUBLIC UTILITY HOLDING COMPANY ACT OF 2005, FEDERAL POWER ACT AND...

  12. 18 CFR 367.1110 - Account 111, Accumulated provision for amortization of service company property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 111, Accumulated provision for amortization of service company property. 367.1110 Section 367.1110 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS...

  13. 18 CFR 367.4114 - Account 411.4, Investment tax credit adjustments, service company property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 411.4, Investment tax credit adjustments, service company property. 367.4114 Section 367.4114 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE PUBLIC UTILITY HOLDING COMPANY ACT OF...

  14. 18 CFR 367.4212 - Account 421.2, Loss on disposition of property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Account 421.2, Loss on disposition of property. 367.4212 Section 367.4212 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE PUBLIC UTILITY HOLDING COMPANY ACT OF 2005, FEDERAL POWER ACT AND...

  15. 18 CFR 367.1110 - Account 111, Accumulated provision for amortization of service company property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 111, Accumulated provision for amortization of service company property. 367.1110 Section 367.1110 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS...

  16. 18 CFR 367.4114 - Account 411.4, Investment tax credit adjustments, service company property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Account 411.4, Investment tax credit adjustments, service company property. 367.4114 Section 367.4114 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER...

  17. 48 CFR 1852.245-74 - Contractor accountable on-site Government property.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... Supply and Equipment Management Officer. That property shall be utilized in the performance of this... and Equipment Management Officer or any other formally designated representatives of the Contracting...) Comply with shelf-life requirements; (4) Provide for accountability and control (using the NASA...

  18. Replication of engine block cylinder bridge microstructure and mechanical properties with lab scale 319 Al alloy billet castings

    SciTech Connect

    Lombardi, A.; D'Elia, F.; Ravindran, C.; MacKay, R.

    2014-01-15

    In recent years, aluminum alloy gasoline engine blocks have in large part successfully replaced nodular cast iron engine blocks, resulting in improved vehicle fuel efficiency. However, because of the inadequate wear resistance properties of hypoeutectic Al–Si alloys, gray iron cylinder liners are required. These liners cause the development of large tensile residual stress along the cylinder bores and necessitate the maximization of mechanical properties in this region to prevent premature engine failure. The aim of this study was to replicate the engine cylinder bridge microstructure and mechanical properties following TSR treatment (which removes the sand binder to enable easy casting retrieval) using lab scale billet castings of the same alloy composition with varying cooling rates. Comparisons in microstructure between the engine block and the billet castings were carried out using optical and scanning electron microscopy, while mechanical properties were assessed using tensile testing. The results suggest that the microstructure at the top and middle of the engine block cylinder bridge was successfully replicated by the billet castings. However, the microstructure at the bottom of the cylinder was not completely replicated due to variations in secondary phase morphology and distribution. The successful replication of engine block microstructure will enable the future optimization of heat treatment parameters. - Highlights: • A method to replicate engine block microstructure was developed. • Billet castings will allow cost effective optimization of heat treatment process. • The replication of microstructure in the cylinder region was mostly successful. • Porosity was more clustered in the billet castings compared to the engine block. • Mechanical properties were lower in billet castings due to porosity and inclusions.

  19. Differences in Membrane Properties in Simulated Cases of Demyelinating Neuropathies: Internodal Focal Demyelinations without Conduction Block

    PubMed Central

    Daskalova, M. S.; Alexandrov, A. S.

    2006-01-01

    The membrane properties (intracellular, extracellular, electrotonic potentials, strength-duration time constants, rheobasic currents and recovery cycles), which can now be measured in healthy subjects and patients with demyelinating neuropathies, are investigated in simulated cases of focal reduction (70%) of the myelin sheath in one, two and three successive internodal segments along the length of human motor fibres. The internodally focally demyelinated cases (termed as IFD1, IFD2 and IFD3, respectively) are simulated using our previous double cable model of the fibres. The results show that the intracellular potentials are with reduced amplitude and slowed conduction velocity in the vicinity of demyelinated segments, however the segmental conduction block is not achieved. The radial decline of the extracellular potential amplitudes slightly increases with the increase of the radial distance and demyelination. In contrast, the electrotonic potentials, strength-duration time constants and rheobases are normal. In the recovery cycles, the refractoriness, supernormality and less late subnormality are close to the normal, showing that the pathology is relatively minor. The obtained abnormalities in the potentials and excitability properties provide new information about the pathophysiology of the demyelinated human motor axons and can be observed in vivo in patients with acquired demyelinating neuropathies. PMID:19669452

  20. Vertically Aligned Nanoplate Particles Directed by Block Copolymer Domains for Anisotropic Properties

    NASA Astrophysics Data System (ADS)

    Krook, Nadia; Meth, Jeffrey; Murray, Christopher; Riggleman, Robert; Composto, Russell

    During common processing methods, anisotropic fillers in polymer nanocomposites align in the direction of flow, parallel to the surfaces, thus enhancing properties in the plane of the substrate. This research aims to create thin film nanocomposites with perpendicularly aligned anisotropic particles to improve properties in the out-of-plane direction. The demonstrated work explores vertical orientation of rare-earth fluoride nanoplates in lamellar-forming poly(styrene- b-methyl methacrylate) to establish a platform that controls the alignment of any planar particle. Currently, gadolinium fluoride (GdF3) rhombus nanoplates with the longest and shortest diagonal dimensions of ~30 nm and ~25 nm, respectively, have been specially synthesized with the potential to intercalate the block copolymer (BCP) domains. By employing a ternary brush blend layer to neutralize silicon substrates to both BCP domains, vertical lamellae orientation has been enabled with an optimum film thickness of ~110 nm. The GdF3 surfaces are chemically modified to drive the plates to a specific BCP domain. After surface modification, the dispersion of GdF3 in homopolymer will first be shown followed by morphology results from integrating GdF3 into the BCP using scanning and transmission electron microscopy.

  1. Nanomechanical properties of multi-block copolymer microspheres for drug delivery applications.

    PubMed

    Moshtagh, P R; Rauker, J; Sandker, M J; Zuiddam, M R; Dirne, F W A; Klijnstra, E; Duque, L; Steendam, R; Weinans, H; Zadpoor, A A

    2014-06-01

    Biodegradable polymeric microspheres are interesting drug delivery vehicles for site-specific sustained release of drugs used in treatment of osteoarthritis. We study the nano-mechanical properties of microspheres composed of hydrophilic multi-block copolymers, because the release profile of the microspheres may be dependent on the mechanical interactions between the host tissues and the microspheres that aim to incorporate between the cartilage surfaces. Three different sizes of monodisperse microspheres, namely 5, 15, and 30μm, were tested in both dry and hydrated (swollen) states. Atomic force microscopy was used for measuring nanoindentation-based force-displacement curves that were later used for calculating the Young׳s moduli using the Hertz׳s contact theory. For every microsphere size and condition, the measurements were repeated 400-500 times at different surface locations and the histograms of the Young׳s modulus were plotted. The mean Young׳s modulus of 5, 15, and 30μm microspheres were respectively 56.1±71.1 (mean±SD), 94.6±103.4, and 57.6±58.6MPa under dry conditions and 226.4±54.2, 334.5±128.7, and 342.5±136.8kPa in the swollen state. The histograms were not represented well by the average Young׳s modulus and showed three distinct peaks in the dry state and one distinct peak in the swollen state. The peaks under dry conditions are associated with the different parts of the co-polymeric material at the nano-scale. The measured mechanical properties of swollen microspheres are within the range of the nano-scale properties of cartilage, which could favor integration of the microspheres with the host tissue.

  2. 76 FR 54534 - Designation of One Entity Pursuant to Executive Order 13572 of April 29, 2011, “Blocking Property...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-01

    ..., 2011, ``Blocking Property of Certain Persons with Respect to Human Rights Abuses in Syria'' AGENCY... Persons with Respect to Human Rights Abuses in Syria.'' DATES: The designation by the Director of OFAC of... Persons with Respect to Human Rights Abuses in Syria,'' (the ``Order'') pursuant to, inter alia,...

  3. 3 CFR 13553 - Executive Order 13553 of September 28, 2010. Blocking Property of Certain Persons With Respect to...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    .... Blocking Property of Certain Persons With Respect to Serious Human Rights Abuses by the Government of Iran... Human Rights Abuses by the Government of Iran and Taking Certain Other Actions By the authority vested..., or responsible for ordering, controlling, or otherwise directing, the commission of serious...

  4. Differences in Membrane Properties in Simulated Cases of Demyelinating Neuropathies: Internodal Focal Demyelinations with Conduction Block

    PubMed Central

    Daskalova, M. S.; Alexandrov, A. S.

    2006-01-01

    The aim of this study is to investigate the membrane properties (potentials and axonal excitability indices) in the case of myelin wrap reduction (96%) in one, two and three consecutive internodes along the length of human motor nerve fibre. The internodally focally demyelinated cases (termed as IFD1, IFD2 and IFD3, respectively, with one, two and three demyelinated internodes are simulated using our previous double cable model of the fibre. The progressively greater increase of focal loss of myelin lamellae blocks the invasion of the intracellular potentials into the demyelinated zones. For all investigated cases, the radial decline of the extracellular potential amplitudes increases with the increase of the radial distance and demyelination, whereas the electrotonic potentials show a decrease in the slow part of the depolarizing and hyperpolarizing responses. The time constants are shorter and the rheobases higher for the IFD2 and IFD3 cases than for the normal case. In the recovery cycles, the same cases have less refractoriness, greater supernormality and less late subnormality than the normal case. The simulated membrane abnormalities can be observed in vivo in patients with demyelinating forms of Guillain-Barré syndrome. The study provides new information about the pathophysiology of acquired demyelinating neuropathies. PMID:19669456

  5. Recruitment and blocking properties of the CardioFit stimulation lead

    NASA Astrophysics Data System (ADS)

    Ahilea Anholt, Tamar; Ayal, Shai; Goldberg, Joshua A.

    2011-06-01

    The CardioFit vagal stimulation system has been developed as a proposed therapy for congestive heart failure (CHF). CardioFit is to be implanted in several hundred CHF patients enrolled in the INOVATE-HF clinical trial, an FDA approved study. The CardioFit stimulation lead (CSL), which is a cuff electrode that delivers stimulation pulses to the right cervical vagus, was designed to recruit efferent cardiac vagal fibers while minimizing unwanted recruitment of other fibers. This paper presents the CSL and measurements of its recruiting and blocking properties when placed on isolated porcine vagus nerves maintained at an elevated temperature in oxygenated artificial cerebrospinal fluid. Using charge balanced quasi-trapezoidal pulses driven through the CSL, we show in eight out of nine nerves a 63% ± 13% (mean ± SD) unidirectional attenuation of the A-fiber compound action potential attained at a current of 3.0 ± 0.8 mA. The threshold for the activation of A- and B-fibers was found to be 0.3 ± 0.17 mA and 2.5 ± 1.1 mA, respectively. The results presented here should help to guide the optimal parameters used in the upcoming deployment of the CardioFit system.

  6. 47 CFR 36.171 - Property held for future telecommunications use-Account 2002; Telecommunications plant under...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 2 2010-10-01 2010-10-01 false Property held for future telecommunications use-Account 2002; Telecommunications plant under construction-Account 2003; and Telecommunications plant adjustment-Account 2005. 36.171 Section 36.171 Telecommunication FEDERAL COMMUNICATIONS COMMISSION...

  7. 49 CFR 1242.37 - Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 9 2014-10-01 2014-10-01 false Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00). 1242.37 Section 1242.37 Transportation Other Regulations Relating to... (accounts XX-26-39 and 62-26-00). Separate common expenses in each account in proportion to the...

  8. 49 CFR 1242.37 - Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 9 2013-10-01 2013-10-01 false Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00). 1242.37 Section 1242.37 Transportation Other Regulations Relating to... (accounts XX-26-39 and 62-26-00). Separate common expenses in each account in proportion to the...

  9. 49 CFR 1242.37 - Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 9 2012-10-01 2012-10-01 false Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00). 1242.37 Section 1242.37 Transportation Other Regulations Relating to... (accounts XX-26-39 and 62-26-00). Separate common expenses in each account in proportion to the...

  10. 49 CFR 1242.37 - Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 9 2011-10-01 2011-10-01 false Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00). 1242.37 Section 1242.37 Transportation Other Regulations Relating to... (accounts XX-26-39 and 62-26-00). Separate common expenses in each account in proportion to the...

  11. 25 CFR 900.58 - Do the same accountability and control procedures described above apply to Federal property?

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 25 Indians 2 2012-04-01 2012-04-01 false Do the same accountability and control procedures described above apply to Federal property? 900.58 Section 900.58 Indians BUREAU OF INDIAN AFFAIRS... Organization Management Systems Property Management System Standards § 900.58 Do the same accountability...

  12. 25 CFR 900.58 - Do the same accountability and control procedures described above apply to Federal property?

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 25 Indians 2 2011-04-01 2011-04-01 false Do the same accountability and control procedures described above apply to Federal property? 900.58 Section 900.58 Indians BUREAU OF INDIAN AFFAIRS... Organization Management Systems Property Management System Standards § 900.58 Do the same accountability...

  13. 25 CFR 900.58 - Do the same accountability and control procedures described above apply to Federal property?

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 25 Indians 2 2014-04-01 2014-04-01 false Do the same accountability and control procedures described above apply to Federal property? 900.58 Section 900.58 Indians BUREAU OF INDIAN AFFAIRS... Organization Management Systems Property Management System Standards § 900.58 Do the same accountability...

  14. 25 CFR 900.58 - Do the same accountability and control procedures described above apply to Federal property?

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 25 Indians 2 2013-04-01 2013-04-01 false Do the same accountability and control procedures described above apply to Federal property? 900.58 Section 900.58 Indians BUREAU OF INDIAN AFFAIRS... Organization Management Systems Property Management System Standards § 900.58 Do the same accountability...

  15. Surface-compositional Properties of Lava Plains in Syria-Thaumasia Block, Mars

    NASA Astrophysics Data System (ADS)

    Huang, J.; Xiao, L.; Kraft, M. D.; Christensen, P. R.; Edwards, C. S.; Ruff, S. W.; Dohm, J.

    2012-12-01

    Mars has a long and complex volcanic history (Greeley and Spudis, 1981; Carr, 2006). Among abundant plain-style volcanism and various edifices, Tharsis bulge is a prominent and long-lasting (Werner, 2009) volcanic province. However, there is little report about compositional variations before and after Tharsis uplift. The Syria- Thaumasia block (STB) is a complex tectono-volcanic province related to the Tharsis bulge. Understanding its formation is critical to characterizing the early history and planetary evolution of Mars. The STB lies at the southern edge of Tharsis bulge. It consists of lava plains (Syria, Solis, Sinai and Thaumasia Plana) bounded by an arcuate region of higher topography (Thaumasia Highlands, Melas Dorsa and Coprates Rise) and Valles Marineris to the north. Previous work on surface thermophysical properties (Christensen, 1988; Jakosky et al., 2000; Putzig and Mellon, 2007) and visible/near infrared and thermal infrared remote sensing spectroscopic compositional analysis (Bandfield, 2000; Bibring et al., 2006; Rogers and Christensen, 2007) had been done only in a global scale, but regional study of both surface thermophysical properties and compositions for each of the distinct lava plains in STB is lacking. In this study, we characterize a variety of volcanic features, including lava tubes, channels and their relationships with wrinkle ridges within lava plains using THEMIS infrared data (100 m/pixel: Christensen et al., 2004), CTX data (6 m/pixel: Malin et al., 2007) and HiRISE data (25 cm/pixel: McEwen et al., 2007). We assessed the surface thermophysical properties and compositions of lava plains using TES data (Christensen et al., 2001). The geomorphic features imply the lava emplacement mechanisms, while their relationships indicate the chronologic relationships between Tharsis uplift and lava emplacement. The compositional results show variations within the lava plains (Table 1), while the thermophysical results show the compositional

  16. Relation between blocking property against UV-rays by dyed fabric and its color fastness to light

    NASA Astrophysics Data System (ADS)

    Mima, Tomoko; Sato, Masako

    2002-06-01

    It is predicted if the dye strongly absorbed the ray in shorter UV wavelength, the ray energy might destroy the dye structure. Color fastness of dyed fabric is also an important character from a viewpoint of aesthetic sense and textile end use. The purpose of this study is to investigate the relation between the blocking property of dyed fabric against UV-rays and its color fastness to light. The cotton fabrics dyed with different types of direct dyes (red, blue and yellow) and their dye solutions were respectively irradiated by xenon arc lamp. The results were as follow. Color fading of dyed fabrics depended on the structure of dyes. Even the dye having lower fastness property to light, the darker shade fabrics dyed with them were examined still remaining higher UV blocking property.

  17. Rheology and interfacial properties of aqueous solutions of the diblock polyelectrolyte poly(styrene-block-acrylic acid)

    NASA Astrophysics Data System (ADS)

    Kimerling, Abigail

    In aqueous solutions diblock polyelectrolytes with amphiphilic character form aggregate structures, which affect physical properties such as viscosity, elasticity, surface tension, and film hydrophilicity. Potential applications for diblock polyelectrolyte solutions include coatings, inks, oil recovery agents, personal care products, and biomaterials. By varying the diblock polyelectrolyte and solution properties, the solutions can be tuned to meet the needs of particular applications. The research objective was to identify the influences of block length, pH, and ionic strength on the rheological and interfacial properties of poly(styrene- b-acrylic acid) (PS-PAA) solutions. Six polymers with varied PS and PAA block lengths were examined, all at 1.0 wt% in aqueous solutions. The hydrophobicity of the PS block causes the formation of spherical micelles in aqueous solutions. Increasing the solution pH ionizes the PAA block, which leads to an increase in micelle corona thickness due to repulsions between chains. Major trends observed in the rheological and interfacial properties can be understood in terms of expected changes in the micelle size and interfacial self-assembly with pH, ionic strength, and block length. Addition of NaOH was found to increase the solution pH and initially led to increases in solution viscosity, elasticity, surface tension, and film hydrophilicity. This effect was attributed to creation of larger micelles and greater inter-micellar repulsions as the PAA chain became more fully charged. However, when the concentration of NaOH exceeded a critical value, the solution viscosity, elasticity, and film hydrophilicity decreased. It is believed this was due to charge shielding by excess sodium ions, leading to shrinkage of the micelle corona and smaller micelles. Increasing the PS-PAA solution ionic strength by adding NaCl also provided charge shielding, as observed by decreases in solution viscosity and elasticity. Increasing the length of either

  18. Polybenzimidazole block copolymers for fuel cell: synthesis and studies of block length effects on nanophase separation, mechanical properties, and proton conductivity of PEM.

    PubMed

    Maity, Sudhangshu; Jana, Tushar

    2014-05-14

    A series of meta-polybenzimidazole-block-para-polybenzimidazole (m-PBI-b-p-PBI), segmented block copolymers of PBI, were synthesized with various structural motifs and block lengths by condensing the diamine terminated meta-PBI (m-PBI-Am) and acid terminated para-PBI (p-PBI-Ac) oligomers. NMR studies and existence of two distinct glass transition temperatures (Tg), obtained from dynamical mechanical analysis (DMA) results, unequivocally confirmed the formation of block copolymer structure through the current polymerization methodology. Appropriate and careful selection of oligomers chain length enabled us to tailor the block length of block copolymers and also to make varieties of structural motifs. Increasingly distinct Tg peaks with higher block length of segmented block structure attributed the decrease in phase mixing between the meta-PBI and para-PBI blocks, which in turn resulted into nanophase segregated domains. The proton conductivities of proton exchange membrane (PEM) developed from phosphoric acid (PA) doped block copolymer membranes were found to be increasing substantially with increasing block length of copolymers even though PA loading of these membranes did not alter appreciably with varying block length. For example when molecular weight (Mn) of blocks were increased from 1000 to 5500 then the proton conductivities at 160 °C of resulting copolymers increased from 0.05 to 0.11 S/cm. Higher block length induced nanophase separation between the blocks by creating less morphological barrier within the block which facilitated the movement of the proton in the block and hence resulting higher proton conductivity of the PEM. The structural varieties also influenced the phase separation and proton conductivity. In comparison to meta-para random copolymers reported earlier, the current meta-para segmented block copolymers were found to be more suitable for PBI-based PEM.

  19. Flight control systems properties and problems. Volume 2: Block diagram compendium

    NASA Technical Reports Server (NTRS)

    Johnston, D. E.

    1975-01-01

    A compendium of stability augmentation system and autopilot block diagrams is presented. Descriptive materials for 48 different types of aircraft systems are provided. A broad representation of the many mechanical approaches which have been used for aircraft control is developed.

  20. 31 CFR 560.422 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... the transfer of property (including any property interest) away from the Government of Iran, an... property interest) is transferred or attempted to be transferred to the Government of Iran, an Iranian... § 560.211, such property shall be deemed to be property in which the Government of Iran, an...

  1. PF9404C, a new slow NO donor with beta receptor blocking properties

    PubMed Central

    Villarroya, Mercedes; Herrero, Carlos J; Ruíz-Nuño, Ana; de Pascual, Ricardo; del Valle, Mercedes; Michelena, Pedro; Grau, Manuel; Carrasco, Emilio; López, Manuela G; García, Antonio G

    1999-01-01

    PF9404C is the S-S diesteroisomer of a novel blocker of beta adrenergic receptors with vasodilatory properties. It causes a concentration-dependent relaxation of rat aorta helical strips pre-contracted with 10−6 M noradrenaline (NA; IC50 33 nM). It was equipotent to nitroglycerin (NTG; IC50 49 nM), but much more potent than isosorbide dinitrate (ISD; IC50 15,000 nM).Oxyhaemoglobin (10 μM) shifted to the right the concentration-response curve for the relaxation induced by PF9404C (IC50 530 nM) or NTG (IC50 61 nM).Either methylene blue (MB) or ODQ (1 μM each) largely prevented the vasorelaxing responses to increasing concentrations of PF9404C or NTG.In rat aorta smooth muscle cells, PF9404C increased the formation of cyclic GMP from 3 pmol mg−1 protein in basal conditions, to 53 pmol mg−1 protein in 10 μM PF9404C. Neither metoprolol nor carvedilol enhanced cyclic GMP.In the electrically driven guinea-pig left atrium, PF9404C blocked the inotropic effects of isoprenaline in a concentration-dependent manner. Its IC50 (30 nM) was similar to that for S-propranolol (22.4 nM) and lower than the IC50s for metoprolol (120 nM) and atenolol (192 nM). The beta-adrenergic ligand (−)-[3H]-CGP12177 (0.2 nM) was displaced from its binding to rat brain membranes with Ki of 7 nM, 17 nM, 170 nM and 1.2 μM respectively for PF9404C, S-(−)propranolol, metoprolol, and atenolol.The data are consistent with the idea that the S-S diesteroisomer PF9404C, is a potent vasorelaxing agent, as well as a blocker of cardiac beta adrenergic receptors. The mechanism of its vasorelaxing effects involves the slow generation of NO. This molecule can, therefore, exhibit antihypertensive and cardioprotective actions through a double mechanism, NO donation and beta blockade. PMID:10588927

  2. John H. Dillon Medal: Tapered Block Copolymers: Tuning Self-Assembly and Properties by Manipulating Monomer Segment Distributions

    NASA Astrophysics Data System (ADS)

    Epps, Thomas

    The self-assembly of block copolymers (BCPs) presents unique opportunities to design materials with attractive chemical and mechanical properties based on the ability of BCPs to form periodic structures with nanoscale domain spacings. One area of recent progress in our group focuses on the behavior of tapered BCPs in which the segment distribution at the interface between blocks is synthetically varied to tune morphology, domain density profiles, thermal transitions as well as mechanical and transport properties. Two application targets for these materials are lithium-ion conducting membranes for batteries and nanostructured thin films for nanotemplates and barrier membranes. In the first target area, we found that the taper volume fraction and composition allow us to manipulate the self-assembly of salt-doped BCPs in a well-defined manner that permits optimization of morphology and ion-content. Additionally, we found that the tapered interfaces influence the glass-transition behavior of the ion-conducting block leading to significant changes in lithium-ion transport (ion conductivity). In the second target area, we found the taper content alters the rate of self-assembly as well as the rate of island/hole formation (and ultimate island/hole size) upon thermal annealing. Additionally, using reflectivity techniques, we probed the domain density profiles as a function of taper composition and linked these profiles to changes in domain spacing and glass transition temperature. Overall, these studies show the versatility of tapering to provide a unique handle for simultaneously optimizing multiple materials properties.

  3. 31 CFR 542.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... transfer of property (including any property interest) away from the Government of Syria or any other... transferred or attempted to be transferred to the Government of Syria or any other person whose property...

  4. Multifunctional imine-POSS as uncommon 3D nanobuilding blocks for supramolecular hybrid materials: synthesis, structural characterization, and properties.

    PubMed

    Janeta, Mateusz; John, Łukasz; Ejfler, Jolanta; Lis, Tadeusz; Szafert, Sławomir

    2016-08-01

    In this article, we report on the chemistry and the spectroscopic properties of well-defined imino-functionalized polyoctahedral oligomeric silsesquioxanes (imine-POSS) with various substitutions. Our efforts were mainly focused on side chains with sizable aryl groups possessing hydroxyl, nitro, and halide moieties. Such a choice enabled us to track their reduction abilities to secondary amine-POSS, tautomerization effects, and thermal properties. We also report for the first time the solid-state structures of five imino-functionalized cage-like octasilsesquioxanes. These structures provide unique examples of the complexities of three-dimensional packing motifs and their relationship with the assembly of tunable materials from nanobuilding blocks.

  5. 25 CFR 900.58 - Do the same accountability and control procedures described above apply to Federal property?

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Organization Management Systems Property Management System Standards § 900.58 Do the same accountability and..., DEPARTMENT OF THE INTERIOR, AND INDIAN HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES...

  6. 49 CFR 1242.51 - Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00).

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 9 2013-10-01 2013-10-01 false Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00). 1242.51 Section 1242.51 Transportation Other Regulations Relating to... (accounts XX-27-39 and 62-27-00). Separate common expenses in proportion to the separation of common...

  7. 49 CFR 1242.51 - Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00).

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 9 2014-10-01 2014-10-01 false Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00). 1242.51 Section 1242.51 Transportation Other Regulations Relating to... (accounts XX-27-39 and 62-27-00). Separate common expenses in proportion to the separation of common...

  8. 49 CFR 1242.51 - Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00).

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 9 2011-10-01 2011-10-01 false Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00). 1242.51 Section 1242.51 Transportation Other Regulations Relating to... (accounts XX-27-39 and 62-27-00). Separate common expenses in proportion to the separation of common...

  9. Scaling properties and fractality in the distribution of coding segments in eukaryotic genomes revealed through a block entropy approach

    NASA Astrophysics Data System (ADS)

    Athanasopoulou, Labrini; Athanasopoulos, Stavros; Karamanos, Kostas; Almirantis, Yannis

    2010-11-01

    Statistical methods, including block entropy based approaches, have already been used in the study of long-range features of genomic sequences seen as symbol series, either considering the full alphabet of the four nucleotides or the binary purine or pyrimidine character set. Here we explore the alternation of short protein-coding segments with long noncoding spacers in entire chromosomes, focusing on the scaling properties of block entropy. In previous studies, it has been shown that the sizes of noncoding spacers follow power-law-like distributions in most chromosomes of eukaryotic organisms from distant taxa. We have developed a simple evolutionary model based on well-known molecular events (segmental duplications followed by elimination of most of the duplicated genes) which reproduces the observed linearity in log-log plots. The scaling properties of block entropy H(n) have been studied in several works. Their findings suggest that linearity in semilogarithmic scale characterizes symbol sequences which exhibit fractal properties and long-range order, while this linearity has been shown in the case of the logistic map at the Feigenbaum accumulation point. The present work starts with the observation that the block entropy of the Cantor-like binary symbol series scales in a similar way. Then, we perform the same analysis for the full set of human chromosomes and for several chromosomes of other eukaryotes. A similar but less extended linearity in semilogarithmic scale, indicating fractality, is observed, while randomly formed surrogate sequences clearly lack this type of scaling. Genomic sequences always present entropy values much lower than their random surrogates. Symbol sequences produced by the aforementioned evolutionary model follow the scaling found in genomic sequences, thus corroborating the conjecture that “segmental duplication-gene elimination” dynamics may have contributed to the observed long rangeness in the coding or noncoding alternation in

  10. 31 CFR 536.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS... the transfer of property (including any property interest) away from a specially designated narcotics trafficker, such property shall no longer be deemed to be property in which a specially designated...

  11. 31 CFR 536.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS... the transfer of property (including any property interest) away from a specially designated narcotics trafficker, such property shall no longer be deemed to be property in which a specially designated...

  12. 31 CFR 536.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS... the transfer of property (including any property interest) away from a specially designated narcotics trafficker, such property shall no longer be deemed to be property in which a specially designated...

  13. 31 CFR 536.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS... the transfer of property (including any property interest) away from a specially designated narcotics trafficker, such property shall no longer be deemed to be property in which a specially designated...

  14. 31 CFR 536.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY NARCOTICS... the transfer of property (including any property interest) away from a specially designated narcotics trafficker, such property shall no longer be deemed to be property in which a specially designated...

  15. 31 CFR 595.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... transfer of property (including any property interest) away from a specially designated terrorist, such property shall no longer be deemed to be property in which a specially designated terrorist has or has had an interest, or which is held in the name of a specially designated terrorist, unless there exists...

  16. The effect of water absorption on the viscoelastic properties of poly(styrene-block-isobutylene-block-styrene) for use in biomedical applications

    NASA Astrophysics Data System (ADS)

    Fittipaldi, Mauro; Rodriguez, Luis A.; Grace, Landon R.

    2015-05-01

    The decrease in glass transition temperature and change in creep compliance due to water diffusion in a biocompatible thermoplastic elastomer was studied and quantified. Knowledge of the mechanical and viscoelastic performance of the styrene-isobutylene-styrene block (SIBS) copolymer is important to determine the feasibility of certain in-vivo applications. Furthermore, the deterioration in these types of properties due to the plasticizing effect of water must be well understood for long term usage. Samples were formed with an injection molding press and fully dried prior to immersion in distilled water at 37°C. Water diffusion kinetics were studied for four different SIBS copolymers of varying molecular weight and styrene content by measuring weight changes as a function of time. These gravimetric diffusion studies showed an inverse relationship between diffusivity and styrene content and molecular weight for the first thousand hours of immersion. Measurements of storage modulus, loss modulus, tangent delta, strain recovery and creep compliance were performed using a dynamic mechanical analyzer for the high molecular weight, high styrene content SIBS version at different absorbed water contents. A measurable and nearly linear decrease of the glass transition temperature and creep recovery with respect to water content was observed for the samples tested even at relatively low water content: an increase in water content of 0.27% correlated to a decrease of 4°C in glass transition temperature while a 0.16% weight increase corresponded to a 12.5% decrease in creep recovery. These quantified material properties restrict the use of SIBS in certain implantable operations that undergo cyclic strains, and in sterilization techniques that require high temperatures. As such, they are important to understand in order to determine the viability of in vivo usage of this biocompatible polymer.

  17. Micromechanical modeling of elastic properties of cortical bone accounting for anisotropy of dense tissue.

    PubMed

    Salguero, Laura; Saadat, Fatemeh; Sevostianov, Igor

    2014-10-17

    The paper analyzes the connection between microstructure of the osteonal cortical bone and its overall elastic properties. The existing models either neglect anisotropy of the dense tissue or simplify cortical bone microstructure (accounting for Haversian canals only). These simplifications (related mostly to insufficient mathematical apparatus) complicate quantitative analysis of the effect of microstructural changes - produced by age, microgravity, or some diseases - on the overall mechanical performance of cortical bone. The present analysis fills this gap; it accounts for anisotropy of the dense tissue and uses realistic model of the porous microstructure. The approach is based on recent results of Sevostianov et al. (2005) and Saadat et al. (2012) on inhomogeneities in a transversely-isotropic material. Bone's microstructure is modeled according to books of Martin and Burr (1989), Currey (2002), and Fung (1993) and includes four main families of pores. The calculated elastic constants for porous cortical bone are in agreement with available experimental data. The influence of each of the pore types on the overall moduli is examined.

  18. Comparison of surface properties of random, block, and graft copolymers having perfluoroalkyl and silicone-containing side chains.

    PubMed

    Kim, Dong-Kwon; Lee, Soo-Bok

    2002-03-15

    Fluorosilicone copolymers of random, block, and graft with both perfluoroalkyl and silicone-containing side chains were synthesized, and their surface properties and surface modification effects on PVC film were compared. It can be confirmed that the fluorosilicone copolymers of random, block, and graft exhibit very low surface free energies of 9-13 dyn/cm, depending on the perfluoroalkyl group content and their molecular structure. The inherent surface free energies of the fluorosilicone copolymers are significantly influenced by their molecular structure and perfluoroalkyl group content. It can also be found that the fluorosilicone copolymers are very effective for lowering surface free energy. The surface free energy of a copolymer/PVC blend strongly varies with perfluoroalkyl group content as well as molecular structure. The molecular structure of a fluorosilicone copolymer is as important as the perfluoroalkyl group content for their inherent surface free energies and surface modification of other polymers.

  19. Modal interaction in ultrasonic welding block sonotrodes induced by the mistuning of the material properties

    NASA Astrophysics Data System (ADS)

    Brouet, Francois; Twiefel, Jens; Wallaschek, Jörg

    2016-10-01

    In many ultrasonic applications, block sonotrodes are serially coupled with other tuned components to transmit the longitudinal vibration to the workpiece. Uniform vibration amplitude of the output surface is an important criterion for determining quality. It is known that amplitude uniformity is related to other non-tuned modes. In this paper, another type of modal interaction is used to quantify distortion of the first longitudinal mode, when the system exhibits a loss of symmetry (mistuning) and near natural frequencies.

  20. 31 CFR 540.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Government of the Russian Federation, such property shall no longer be deemed to be property in which the Government of the Russian Federation has or has had an interest unless there exists in the property another interest of the Government of the Russian Federation, the transfer of which has not been effected...

  1. 31 CFR 540.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... Government of the Russian Federation, such property shall no longer be deemed to be property in which the Government of the Russian Federation has or has had an interest unless there exists in the property another interest of the Government of the Russian Federation, the transfer of which has not been effected...

  2. 49 CFR 1242.51 - Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 9 2010-10-01 2010-10-01 false Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00). 1242.51 Section 1242.51 Transportation Other Regulations Relating to... FOR RAILROADS 1 Operating Expenses-Equipment § 1242.51 Dismantling retired property and...

  3. 49 CFR 1242.51 - Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00).

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 9 2012-10-01 2012-10-01 false Dismantling retired property and depreciation (accounts XX-27-39 and 62-27-00). 1242.51 Section 1242.51 Transportation Other Regulations Relating to... FOR RAILROADS 1 Operating Expenses-Equipment § 1242.51 Dismantling retired property and...

  4. 49 CFR 1242.37 - Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00).

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 9 2010-10-01 2010-10-01 false Dismantling retired property and depreciation (accounts XX-26-39 and 62-26-00). 1242.37 Section 1242.37 Transportation Other Regulations Relating to... FOR RAILROADS 1 Operating Expenses-Equipment § 1242.37 Dismantling retired property and...

  5. 47 CFR 36.504 - Accumulated depreciation-Property held for future telecommunications use-Account 3200.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 47 Telecommunication 2 2010-10-01 2010-10-01 false Accumulated depreciation-Property held for future telecommunications use-Account 3200. 36.504 Section 36.504 Telecommunication FEDERAL... TELECOMMUNICATIONS COMPANIES 1 Reserves and Deferrals § 36.504 Accumulated depreciation—Property held for...

  6. Quantum dot-block copolymer hybrids with improved properties and their application to quantum dot light-emitting devices.

    PubMed

    Zorn, Matthias; Bae, Wan Ki; Kwak, Jeonghun; Lee, Hyemin; Lee, Changhee; Zentel, Rudolf; Char, Kookheon

    2009-05-26

    To combine the optical properties of CdSe@ZnS quantum dots (QDs) with the electrical properties of semiconducting polymers, we prepared QD/polymer hybrids by grafting a block copolymer (BCP) containing thiol-anchoring moieties (poly(para-methyl triphenylamine-b-cysteamine acrylamide)) onto the surfaces of QDs through the ligand exchange procedure. The prepared QD/polymer hybrids possess improved processability such as enhanced solubility in various organic solvents as well as the film formation properties along with the improved colloidal stability derived from the grafted polymer shells. We also demonstrated light-emitting diodes based on QD/polymer hybrids, exhibiting the improved device performance (i.e., 3-fold increase in the external quantum efficiency) compared with the devices prepared by pristine (unmodified) QDs.

  7. Molecular modeling of the elastomeric properties of repeating units and building blocks of resilin, a disordered elastic protein.

    PubMed

    Khandaker, Md Shahriar K; Dudek, Daniel M; Beers, Eric P; Dillard, David A; Bevan, David R

    2016-08-01

    The mechanisms responsible for the properties of disordered elastomeric proteins are not well known. To better understand the relationship between elastomeric behavior and amino acid sequence, we investigated resilin, a disordered rubber-like protein, found in specialized regions of the cuticle of insects. Resilin of Drosophila melanogaster contains Gly-rich repetitive motifs comprised of the amino acids, PSSSYGAPGGGNGGR, which confer elastic properties to resilin. The repetitive motifs of insect resilin can be divided into smaller partially conserved building blocks: PSS, SYGAP, GGGN and GGR. Using molecular dynamics (MD) simulations, we studied the relative roles of SYGAP, and its less common variants SYSAP and TYGAP, on the elastomeric properties of resilin. Results showed that SYGAP adopts a bent structure that is one-half to one-third the end-to-end length of the other motifs having an equal number of amino acids but containing SYSAP or TYGAP substituted for SYGAP. The bent structure of SYGAP forms due to conformational freedom of glycine, and hydrogen bonding within the motif apparently plays a role in maintaining this conformation. These structural features of SYGAP result in higher extensibility compared to other motifs, which may contribute to elastic properties at the macroscopic level. Overall, the results are consistent with a role for the SYGAP building block in the elastomeric properties of these disordered proteins. What we learned from simulating the repetitive motifs of resilin may be applicable to the biology and mechanics of other elastomeric biomaterials, and may provide us the deeper understanding of their unique properties.

  8. Molecular modeling of the elastomeric properties of repeating units and building blocks of resilin, a disordered elastic protein.

    PubMed

    Khandaker, Md Shahriar K; Dudek, Daniel M; Beers, Eric P; Dillard, David A; Bevan, David R

    2016-08-01

    The mechanisms responsible for the properties of disordered elastomeric proteins are not well known. To better understand the relationship between elastomeric behavior and amino acid sequence, we investigated resilin, a disordered rubber-like protein, found in specialized regions of the cuticle of insects. Resilin of Drosophila melanogaster contains Gly-rich repetitive motifs comprised of the amino acids, PSSSYGAPGGGNGGR, which confer elastic properties to resilin. The repetitive motifs of insect resilin can be divided into smaller partially conserved building blocks: PSS, SYGAP, GGGN and GGR. Using molecular dynamics (MD) simulations, we studied the relative roles of SYGAP, and its less common variants SYSAP and TYGAP, on the elastomeric properties of resilin. Results showed that SYGAP adopts a bent structure that is one-half to one-third the end-to-end length of the other motifs having an equal number of amino acids but containing SYSAP or TYGAP substituted for SYGAP. The bent structure of SYGAP forms due to conformational freedom of glycine, and hydrogen bonding within the motif apparently plays a role in maintaining this conformation. These structural features of SYGAP result in higher extensibility compared to other motifs, which may contribute to elastic properties at the macroscopic level. Overall, the results are consistent with a role for the SYGAP building block in the elastomeric properties of these disordered proteins. What we learned from simulating the repetitive motifs of resilin may be applicable to the biology and mechanics of other elastomeric biomaterials, and may provide us the deeper understanding of their unique properties. PMID:26851528

  9. Self-assembly of short peptides to form hydrogels: design of building blocks, physical properties and technological applications.

    PubMed

    Fichman, Galit; Gazit, Ehud

    2014-04-01

    Hydrogels are unique supramolecular solid-like assemblies composed mainly of water molecules that are held by molecular networks. Physical hydrogels that are formed by a set of non-covalent interactions to establish a well-ordered scaffold devoid of any chemical cross-linking are especially intriguing for various biotechnological and medical applications. Peptides are particularly interesting building blocks of physical gels because of the role of polypeptides as structural elements in biological systems, the extensive ability for their chemical and biological decoration and functionalization, and the facile synthesis of natural and modified peptides. This review describes the assembly and properties of physical hydrogels that have been formed by the self-association of very simple peptide building blocks. Natural short peptides, as short as dipeptides, can form ordered gel assemblies. Moreover, in the case of N-terminal protection, even a protected amino acid can serve as an efficient hydrogelator. Further elucidation of hydrogelators' assembly, as well as the characterization of their physical properties, can guide the rational design of building blocks for a desired application. The possible mechanism of self-assembly is discussed in line with the chemical nature of the short peptides. Different methods have been used to induce hydrogel assembly, which may significantly affect the mechanical characteristics of the resulting gels. Here, special emphasis is given to methods that allow either spatial control of hydrogel formation or modulation of physical properties of the gel. Finally, the parameters that influence hydrogelation are described, and insights for their design are provided. PMID:23958781

  10. Cooperativity in A-tract structure and bending properties of composite TnAn blocks.

    PubMed

    Haran, T E; Crothers, D M

    1989-04-01

    The existence of intrinsically curved DNA molecules incorporating short runs of adenines is undisputed, but none of the current models can explain the entire experimental data set. Recently, Burkhoff and Tullius [Burkhoff, A. M., & Tullius, T. D. (1988) Nature 331, 455-457] offered an explanation for Hagerman's observations on A4T4N2 vs T4A4N2 polymers [Hagerman, P. J. (1986) Nature 321, 449-450], which showed that A4T4N2 multimers migrate anomalously slowly on polyacrylamide gels and T4A4N2 multimers migrate normally. In A4T4N2 multimers Burkhoff and Tullius observe a hydroxy-radical cutting pattern associated with bent DNA and a B-like cutting pattern in T4A4N2. They attribute this difference in cutting pattern to a clash in the TA step of T4A4N2 and suggest that TA4N5 might already adopt an unbent B-DNA conformation [Tullius T. D., & Burkhoff, A. M. (1988) in Structure and Expression. Vol. 3: DNA Bending and Curvature (Olson, W. K., Sarma, M. H., Sarma, R. H., & Sundaralingam, M., Eds.) pp 77-85, Adenine Press, Guilderland, NY]. We show that the conformation adopted by TnAn blocks is similar to that of AnTn blocks. Two A-tract structures of opposite polarity coexist in both blocks. Moreover, we demonstrate a cooperative buildup of a T-tract structure adjacent to an A-tract structure that cannot be predicted by any of the current models. We conclude that AA steps do not assume the same conformation in long tracts of A's as in isolated AA steps. Therefore, the assumption of nearest-neighbor models, that global curvature is an additive phenomenon of local effects, is invalid. PMID:2742812

  11. 31 CFR 544.403 - Termination and acquisition of an interest in blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... MASS DESTRUCTION PROLIFERATORS SANCTIONS REGULATIONS Interpretations § 544.403 Termination and... pursuant to this part results in the transfer of property (including any property interest) away from a... of this chapter, the transfer of which has not been effected pursuant to license or...

  12. 31 CFR 585.201 - Prohibited transactions involving blocked property; transactions with respect to securities.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Prohibited transactions involving..., 1992, no property or interest in property of the Government of the FRY (S&M), or that is held in the... international agreement or any contract entered into or any license or permit granted before 12:01 a.m....

  13. Unique inner pore properties of BK channels revealed by quaternary ammonium block.

    PubMed

    Li, Weiyan; Aldrich, Richard W

    2004-07-01

    Potassium channels have a very wide distribution of single-channel conductance, with BK type Ca(2+)-activated K(+) channels having by far the largest. Even though crystallographic views of K(+) channel pores have become available, the structural basis underlying BK channels' large conductance has not been completely understood. In this study we use intracellularly applied quaternary ammonium compounds to probe the pore of BK channels. We show that molecules as large as decyltriethylammonium (C(10)) and tetrabutylammonium (TBA) have much faster block and unblock rates in BK channels when compared with any other tested K(+) channel types. Additionally, our results suggest that at repolarization large QA molecules may be trapped inside blocked BK channels without slowing the overall process of deactivation. Based on these findings we propose that BK channels may differ from other K(+) channels in its geometrical design at the inner mouth, with an enlarged cavity and inner pore providing less spatially restricted access to the cytoplasmic solution. These features could potentially contribute to the large conductance of BK channels. PMID:15197222

  14. Mechanical properties of poly(dimethylsiloxane)-block-poly(2-methyloxazoline) polymersomes probed by atomic force microscopy.

    PubMed

    Jaskiewicz, Karmena; Makowski, Marcin; Kappl, Michael; Landfester, Katharina; Kroeger, Anja

    2012-08-28

    Poly(dimethylsiloxane)-block-poly(2-methyloxazoline) (PDMS-b-PMOXA) vesicles were characterized by a combination of dynamic light scattering (DLS), cryogenic transmission electron microscopy (cryo-TEM), and atomic force microscopy imaging and force spectroscopy (AFM). From DLS data, a hydrodynamic radius of ~150 nm was determined, and cryo-TEM micrographs revealed a bilayer thickness of ~16 nm. In AFM experiments on a silicon wafer substrate, adsorption led to a stable spherical caplike conformation of the polymersomes, whereas on mica, adsorption resulted also in vesicle fusion and formation of bilayer patches or multilayer stacks. This indicates a delicate balance between the mechanical stability of PDMS-b-PMOXA polymersomes on one hand and the driving forces for spreading on the other. A Young's modulus of 17 ± 11 MPa and a bending modulus of 7 ± 5 × 10(-18) J were derived from AFM force spectroscopy measurements. Therefore, the elastic response of the PDMS-b-PMOXA polymersomes to external stimuli is much closer to that of lipid vesicles compared to other types of polymersomes, such as polystyrene-block-poly(acrylic acid) (PS-b-PAA).

  15. Enhanced thermoelectric properties in bulk nanowire heterostructure-based nanocomposites through minority carrier blocking.

    PubMed

    Yang, Haoran; Bahk, Je-Hyeong; Day, Tristan; Mohammed, Amr M S; Snyder, G Jeffrey; Shakouri, Ali; Wu, Yue

    2015-02-11

    To design superior thermoelectric materials the minority carrier blocking effect in which the unwanted bipolar transport is prevented by the interfacial energy barriers in the heterogeneous nanostructures has been theoretically proposed recently. The theory predicts an enhanced power factor and a reduced bipolar thermal conductivity for materials with a relatively low doping level, which could lead to an improvement in the thermoelectric figure of merit (ZT). Here we show the first experimental demonstration of the minority carrier blocking in lead telluride-silver telluride (PbTe-Ag2Te) nanowire heterostructure-based nanocomposites. The nanocomposites are made by sintering PbTe-Ag2Te nanowire heterostructures produced in a highly scalable solution-phase synthesis. Compared with Ag2Te nanowire-based nanocomposite produced in similar method, the PbTe-Ag2Te nanocomposite containing ∼5 atomic % PbTe exhibits enhanced Seebeck coefficient, reduced thermal conductivity, and ∼40% improved ZT, which can be well explained by the theoretical modeling based on the Boltzmann transport equations when energy barriers for both electrons and holes at the heterostructure interfaces are considered in the calculations. For this p-type PbTe-Ag2Te nanocomposite, the barriers for electrons, that is, minority carriers, are primarily responsible for the ZT enhancement. By extending this approach to other nanostructured systems, it represents a key step toward low-cost solution-processable nanomaterials without heavy doping level for high-performance thermoelectric energy harvesting.

  16. Property Accounting. A Handbook of Standard Terminology and a Guide for Classifying Information about Education Property. State Educational Records and Reports Series: Handbook III, Revised 1977.

    ERIC Educational Resources Information Center

    Seibert, Ivan N.

    This handbook is offered as a resource for local, intermediate, state, and federal education officials to assist in the identification, organization, and definition of data and information about education property. An introduction and directions are followed by a discussion of concepts associated with property accounting and some general…

  17. Multifunctional imine-POSS as uncommon 3D nanobuilding blocks for supramolecular hybrid materials: synthesis, structural characterization, and properties.

    PubMed

    Janeta, Mateusz; John, Łukasz; Ejfler, Jolanta; Lis, Tadeusz; Szafert, Sławomir

    2016-08-01

    In this article, we report on the chemistry and the spectroscopic properties of well-defined imino-functionalized polyoctahedral oligomeric silsesquioxanes (imine-POSS) with various substitutions. Our efforts were mainly focused on side chains with sizable aryl groups possessing hydroxyl, nitro, and halide moieties. Such a choice enabled us to track their reduction abilities to secondary amine-POSS, tautomerization effects, and thermal properties. We also report for the first time the solid-state structures of five imino-functionalized cage-like octasilsesquioxanes. These structures provide unique examples of the complexities of three-dimensional packing motifs and their relationship with the assembly of tunable materials from nanobuilding blocks. PMID:27438046

  18. Nanomechanical properties of solvent cast polystyrene and poly(methyl methacrylate) polymer blends and self-assembled block copolymers

    NASA Astrophysics Data System (ADS)

    Lorenzoni, Matteo; Evangelio, Laura; Nicolet, Célia; Navarro, Christophe; San Paulo, Alvaro; Rius, Gemma; Pérez-Murano, Francesc

    2015-07-01

    The nanomechanical properties of solvent-cast polymer thin films have been investigated using PeakForce™ Quantitative Nanomechanical Mapping. The samples consisted of films of polystyrene (PS) and poly(methyl methacrylate) (PMMA) obtained after the dewetting of toluene solution on a polymeric brush layer. Additionally, we have probed the mechanical properties of poly(styrene-b-methyl methacrylate) block copolymers (BCP) as randomly oriented thin films. The probed films have a critical thickness <50 nm and present features to be resolved <42 nm. The Young's modulus values obtained through several nanoindentation experiments present a good agreement with previous literature, suggesting that the PeakForce™ technique could be crucial for BCP investigations, e.g., as a predictor of the mechanical stability of the different phases.

  19. Biophysical properties of dermal building-blocks affects extra cellular matrix assembly in 3D endogenous macrotissue.

    PubMed

    Urciuolo, F; Garziano, A; Imparato, G; Panzetta, V; Fusco, S; Casale, C; Netti, P A

    2016-01-29

    The fabrication of functional tissue units is one of the major challenges in tissue engineering due to their in vitro use in tissue-on-chip systems, as well as in modular tissue engineering for the construction of macrotissue analogs. In this work, we aim to engineer dermal tissue micromodules obtained by culturing human dermal fibroblasts into porous gelatine microscaffold. We proved that such stromal cells coupled with gelatine microscaffolds are able to synthesize and to assemble an endogenous extracellular matrix (ECM) resulting in tissue micromodules, which evolve their biophysical features over the time. In particular, we found a time-dependent variation of oxygen consumption kinetic parameters, of newly formed ECM stiffness and of micromodules self-aggregation properties. As consequence when used as building blocks to fabricate larger tissues, the initial tissue micromodules state strongly affects the ECM organization and maturation in the final macrotissue. Such results highlight the role of the micromodules properties in controlling the formation of three-dimensional macrotissue in vitro, defining an innovative design criterion for selecting tissue-building blocks for modular tissue engineering.

  20. The physical properties of supramolecular peptide assemblies: from building block association to technological applications.

    PubMed

    Adler-Abramovich, Lihi; Gazit, Ehud

    2014-01-01

    Bio-inspired nano-materials can be formed by the ordered assembly of elementary building blocks using recognition modules and structural elements. Among the biological sources, peptides and proteins are of special interest due to their role as major structural elements in all living systems, ranging from bacteria to humans in a continuum of magnitudes, from the nano-scale to the macro-scale. Peptides, as short as dipeptides, contain all the molecular information needed to form well-ordered structures at the nano-scale. Here, in light of the significant advancements in the field of peptide nanostructures in the last few years, we provide an updated overview of this subject. The use of these nanostructures was indeed recently demonstrated in various fields including the design of molecular motors based on nanostructure complexation with a metal-organic framework, the delivery of therapeutic agents, the development of energy storage devices and the fabrication of piezoelectric-based sensors. PMID:25099656

  1. Comparison of the Fouling Release Properties of Hydrophobic Fluorinated and Hydrophilic PEGylated Block Copolymer Surfaces

    SciTech Connect

    Krishnan,S.; Wang, N.; Ober, C.; Finlay, J.; Callow, M.; Callow, J.; Hexemer, A.; Sohn, K.; Kramer, E.; Fischer, D.

    2006-01-01

    To understand the role of surface wettability in adhesion of cells, the attachment of two different marine algae was studied on hydrophobic and hydrophilic polymer surfaces. Adhesion of cells of the diatom Navicula and sporelings (young plants) of the green macroalga Ulva to an underwater surface is mainly by interactions between the surface and the adhesive exopolymers, which the cells secrete upon settlement and during subsequent colonization and growth. Two types of block copolymers, one with poly(ethylene glycol) side-chains and the other with liquid crystalline, fluorinated side-chains, were used to prepare the hydrophilic and hydrophobic surfaces, respectively. The formation of a liquid crystalline smectic phase in the latter inhibited molecular reorganization at the surface, which is generally an issue when a highly hydrophobic surface is in contact with water. The adhesion strength was assessed by the fraction of settled cells (Navicula) or biomass (Ulva) that detached from the surface in a water flow channel with a wall shear stress of 53 Pa. The two species exhibited opposite adhesion behavior on the same sets of surfaces. While Navicula cells released more easily from hydrophilic surfaces, Ulva sporelings showed higher removal from hydrophobic surfaces. This highlights the importance of differences in cell-surface interactions in determining the strength of adhesion of cells to substrates.

  2. Heart Block

    MedlinePlus

    ... Block Explore Heart Block What Is... Electrical System & EKG Results Types Causes Who Is at Risk Signs & ... heart block. Doctors use a test called an EKG (electrocardiogram) to help diagnose heart block. This test ...

  3. 26 CFR 1.167(f)-1 - Reduction of salvage value taken into account for certain personal property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... the straight line method of depreciation in computing the depreciation allowance for the station wagon... method to the straight line method (in which salvage value is accounted for in determining the annual... the property. A files his income tax returns on a calendar year basis and uses the straight...

  4. 26 CFR 1.167(a)-7 - Accounting for depreciable property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ..., unadjusted for depreciation or salvage, shall be removed from the asset account and shall be charged to the depreciation reserve. Amounts representing salvage ordinarily are credited to the depreciation reserve. Where... asset shall be removed from the asset account, and the depreciation reserve shall be charged with...

  5. 24 CFR 570.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... for immediate deposit into an escrow account for use in funding loans and grants for the... neighborhood-scale non-residential space within the same structure, if any, e.g., a store front below a... contact governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made...

  6. 24 CFR 1003.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... line of credit for immediate deposit into an escrow account for use in funding loans and grants for the... neighborhood-scale non-residential space within the same structure, if any, e.g., a store front below a... governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made until...

  7. 24 CFR 570.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... for immediate deposit into an escrow account for use in funding loans and grants for the... neighborhood-scale non-residential space within the same structure, if any, e.g., a store front below a... contact governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made...

  8. 24 CFR 1003.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... line of credit for immediate deposit into an escrow account for use in funding loans and grants for the... neighborhood-scale non-residential space within the same structure, if any, e.g., a store front below a... governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made until...

  9. Rheological and Mechanical Properties of Crosslinked Block Copolymer Nanofiber and Polystyrene Blends.

    NASA Astrophysics Data System (ADS)

    Ma, Sungwon; Thio, Yonathan

    2009-03-01

    The mechanical and rheological properties of blends of crosslinked and uncrosslinked poly(styrene)-b-poly(isoprene) copolymer with commercially available polystyrene were studied. Cylindrical morphology of PS-b-PI copolymer was employed for generating nanofiber morphology. Cold vulcanization process using sulfur monochloride (S2Cl2) was used to preserve the morphology. Blends of uncrosslinked PS-b-PI copolymer with neat polystyrene were also prepared. Both blend samples were prepared by solvent casting method with the filler contents varying between 0.5 and 10 wt%. The mechanical and rheological properties were characterized and the microstructures of the fiber and the systems were imaged. The dynamic moduli (G' and G'') of the crosslinked system increased with increasing the fiber content compared to the uncrosslinked system. The results were compared to the rheological model by fitting to Cross-Williamson. This blend study indicated critical volume concentration of nanofiber between 5 and 10 wt% of nanofiber content.

  10. Self-assembled clay films with a platelet–void multilayered nanostructure and flame-blocking properties

    PubMed Central

    Wang, Ya-Chi; Huang, Ting-Kai; Tung, Shih-Huang; Wu, Tzong-Ming; Lin, Jiang-Jen

    2013-01-01

    Polymeric composite films with a high loading of nano-size silicates can hardly meet the increasingly stringent fireproof and smoke-free requirements during burning. Thus, it is desirable to prepare pure clay films that can block air, heat, and flame. Here we report an organic-free clay film capable of both flame- and heat-shielding. The film was prepared from the self-assembly of nanometer-thick silicate platelets derived from the exfoliation of natural clays. The self-assembled film has a highly regular multilayered nanostructure over a large area and an appreciable volume of air entrapped in between. The combination of regular structure and substantial air volume contributes to the low thermal conductivity and flame blocking property of the film. It was demonstrated that the film can shield flame over hour duration and prevent temperature rising on the backside of film. This remarkable clay film has a myriad of uses including gas barrier, heat insulator, and fireproof devices. PMID:24018554

  11. Self-assembled clay films with a platelet-void multilayered nanostructure and flame-blocking properties.

    PubMed

    Wang, Ya-Chi; Huang, Ting-Kai; Tung, Shih-Huang; Wu, Tzong-Ming; Lin, Jiang-Jen

    2013-01-01

    Polymeric composite films with a high loading of nano-size silicates can hardly meet the increasingly stringent fireproof and smoke-free requirements during burning. Thus, it is desirable to prepare pure clay films that can block air, heat, and flame. Here we report an organic-free clay film capable of both flame- and heat-shielding. The film was prepared from the self-assembly of nanometer-thick silicate platelets derived from the exfoliation of natural clays. The self-assembled film has a highly regular multilayered nanostructure over a large area and an appreciable volume of air entrapped in between. The combination of regular structure and substantial air volume contributes to the low thermal conductivity and flame blocking property of the film. It was demonstrated that the film can shield flame over hour duration and prevent temperature rising on the backside of film. This remarkable clay film has a myriad of uses including gas barrier, heat insulator, and fireproof devices.

  12. The influence of electron beam irradiation on the mechanical and thermal properties of Poly (ether-block-amide) blends

    NASA Astrophysics Data System (ADS)

    Murray, Kieran A.; Kennedy, James E.; McEvoy, Brian; Vrain, Olivier; Ryan, Damien; Cowman, Richard; Higginbotham, Clement L.

    2014-01-01

    High energy electron beam irradiation of Poly (ether-block-amide) (Pebax) can induce modifications and/or degradation to transpire in the material subsequent to treatment. To minimise this, Pebax was blended with three stabilisers where each formulation was subjected to electron beam radiation at doses of 25, 50 and 75 kGy. Mechanical testing revealed that the virgin Pebax and the Pebax blended with Irganox B215 provided the best radiation resistance in terms of the tensile strength, elongation at break and Young's modulus. Upon increase in radiation dose from 25 to 75 kGy, a gradual diminution was observed for the melt flow index (MFI) of the virgin Pebax, whereas Pebax blended with Irganox B215 had a minute effect on the properties post irradiation. This study provides evidence that the stabilisers used can either promote undesirable effects or enhance the radiation resistance of Pebax material following radiation exposure.

  13. Preparation and interfacial properties of a novel biodegradable polymer surfactant: poly(ethylene oxide monooleate-block-DL-lactide).

    PubMed

    Nishino, Satoru; Kitamura, Yoshiro; Kishida, Akio; Yoshizawa, Hidekazu

    2005-11-01

    In this paper, we report a novel synthesis of poly(ethylene oxide monooleate-block-DL-lactide) (MOPEO-PLA) in the presence of stannous 2-ethylhexanoate catalyst. By utilizing the surfactant property and the reactive double bond of the amphiphilic MOPEO-PLA, various characteristics of PLA microspheres, such as surface and internal structure, surface morphology, release property, and so on, may potentially be controlled. MOPEO-PLA was found to be hydrophobic enough to prevent loss by dissolution into aqueous solution, which is often a problem for MOPEO. Furthermore, the interfacial tension measurements of a MOPEO-PLA/toluene/water system revealed that MOPEO-PLA had a good surface activity almost equal to that of MOPEO. The MOPEO-PLA/PLA blend films were prepared by solvent casting on a water layer. Contact-angle measurements of MOPEO-PLA/PLA blend films confirmed that the hydrophilic PEO segments were selectivity accumulated at the oil/water interface. Moreover, the surface free energy on the 'water side' of the MOPEO-PLA/PLA blend films was increased because of the increase in polar components as a result of the ether bonds of the PEO segments. Schematic illustration of the adsorption property of a) MOPEO-PLA with a high-molecular-weight PLA segment and b) MOPEO-PLA with a low-molecular-weight PLA segment at an ethyl acetate/water interface. PMID:16245272

  14. Basic properties of a three-dimensional spring-block model with long-range stress transfer

    SciTech Connect

    Jansen, Florian; Hergarten, Stefan

    2006-02-15

    Spring-block models have been very useful for understanding slip complexity of earthquakes. So far, however, they have been restricted to one or two dimensions or simple nearest-neighbor stress transfer. Here, we set up a three-dimensional spring-block model with long-range stress transfer and, in a second step, implement several simplifications to realize a considerable gain in computational efficiency. Qualitatively, the two versions do not differ and we use the fast version to investigate basic properties of the model and to compare to the Olami Feder Christensen (OFC) model. The spatial distribution of hypocenters is found to be scale free. At the end of a simulation of 10{sup 7} events, it takes a value of D{sub 2}{approx_equal}1.8{+-}0.1. At this point, however, the spatial slip organization is not stationary yet and the fractal dimension still grows slightly. This does not affect respective frequency size statistics, though, which exhibit a clear power law with a characteristic cutoff that depends on the grid size. The statistics appear smoother than in the OFC model and lack the kink between events of size 1 and 2. In addition, strong periodicities of large events as in the OFC model do not occur in our model. In stark contrast to the OFC model, results remain the same if periodic boundaries are used. Another significant difference is the stableness of results against imposed disorder. Contrary to the OFC model, results do not change if threshold values are randomly distributed in an interval of {+-}10% around the mean value. Concluding, the model that we propose shares the main properties of the OFC model, but outreaches the latter in being stable in a larger set of configurations.

  15. Property Transmission: An Explanatory Account of the Role of Similarity Information in Causal Inference

    ERIC Educational Resources Information Center

    White, Peter A.

    2009-01-01

    Many kinds of common and easily observed causal relations exhibit property transmission, which is a tendency for the causal object to impose its own properties on the effect object. It is proposed that property transmission becomes a general and readily available hypothesis used to make interpretations and judgments about causal questions under…

  16. Protein based Block Copolymers

    PubMed Central

    Rabotyagova, Olena S.; Cebe, Peggy; Kaplan, David L.

    2011-01-01

    Advances in genetic engineering have led to the synthesis of protein-based block copolymers with control of chemistry and molecular weight, resulting in unique physical and biological properties. The benefits from incorporating peptide blocks into copolymer designs arise from the fundamental properties of proteins to adopt ordered conformations and to undergo self-assembly, providing control over structure formation at various length scales when compared to conventional block copolymers. This review covers the synthesis, structure, assembly, properties, and applications of protein-based block copolymers. PMID:21235251

  17. Using blocking peptides to control and analyze the mechanical properties of single fibrin fibers

    NASA Astrophysics Data System (ADS)

    Maddi, Pranav; O'Brien, E. Tim, III; Gorkun, Oleg; Falvo, Michael R.

    2011-10-01

    Fibrin is the main structural protein involved in blood clotting, and exhibits high strength and elasticity. Fibrin study traditionally focuses on fully formed clots, whereas we employ new AFM nanoManipulation techniques to study single fibrin fiber mechanics. We used 4 and 10 residue peptides to interfere with the knob-hole and αC interactions involved in fibrin polymerization to evaluate the contribution of each interaction to the fiber's mechanical properties. We varied the concentration of each peptide present during polymerization to find the concentration that inhibited polymerization by half. The presence of either peptide during fibrin polymerization did not affect single fiber breaking strain (δLL0). The breaking force of all treated fibers reduced from 10-50nN to 2-10nN, suggesting treated fibers are thinner or are the same diameter with some inhibition of interactions. Fibers polymerized with the knob-hole targeting peptide visibly lost elasticity after 100% strain, while fibers polymerized with the αC targeting peptide lost elasticity after reaching 150% strain, suggesting that the knob-hole interactions control single fiber elasticity.

  18. The properties of conformal blocks, the AGT hypothesis, and knot polynomials

    NASA Astrophysics Data System (ADS)

    Morozov, A. A.

    2016-09-01

    Various properties of correlators of the two-dimensional conformal field theory are discussed. Specifically, their relation to the partition function of the four-dimensional supersymmetric theory is analyzed. In addition to being of interest in its own right, this relation is of practical importance. For example, it is much easier to calculate the known expressions for the partition function of supersymmetric theory than to calculate directly the expressions for correlators in conformal theory. The examined representation of conformal theory correlators as a matrix model serves the same purpose. The integral form of these correlators allows one to generalize the obtained results for the Virasoro algebra to more complicated cases of the W algebra or the quantum Virasoro algebra. This provides an opportunity to examine more complex configurations in conformal field theory. The three-dimensional Chern-Simons theory is discussed in the second part of the present review. The current interest in this theory stems largely from its relation to the mathematical knot theory (a rather well-developed area of mathematics known since the 17th century). The primary objective of this theory is to develop an algorithm that allows one to distinguish different knots (closed loops in three-dimensional space). The basic way to do this is by constructing the so-called knot invariants.

  19. 48 CFR 1852.245-71 - Installation-accountable Government property.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... physical confines of the NASA installation that provided the property unless authorized by the Contracting... property, and the Contractor shall comply with the following: NASA Procedural Requirements (NPR) 4100.1, NASA Materials Inventory Management Manual; NASA Procedural Requirements (NPR) 4200.1, NASA...

  20. 48 CFR 1852.245-71 - Installation-accountable Government property.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... physical confines of the NASA installation that provided the property unless authorized by the Contracting... property, and the Contractor shall comply with the following: NASA Procedural Requirements (NPR) 4100.1, NASA Materials Inventory Management Manual; NASA Procedural Requirements (NPR) 4200.1, NASA...

  1. 48 CFR 1852.245-71 - Installation-accountable Government property.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... physical confines of the NASA installation that provided the property unless authorized by the Contracting... property, and the Contractor shall comply with the following: NASA Procedural Requirements (NPR) 4100.1, NASA Materials Inventory Management Manual; NASA Procedural Requirements (NPR) 4200.1, NASA...

  2. 24 CFR 1003.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... neighborhood-scale non-residential space within the same structure, if any, e.g., a store front below a... governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made until after... accordance with the requirements of U.S. Treasury Financial Manual, paragraph 6-2075.30. (5) Funds...

  3. 24 CFR 570.511 - Use of escrow accounts for rehabilitation of privately owned residential property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... neighborhood-scale non-residential space within the same structure, if any, e.g., a store front below a... contact governed by the requirements of 24 CFR 85.36. No deposit to the escrow account shall be made until... erroneously drawn in accordance with the requirements of U.S. Treasury Financial Manual, paragraph...

  4. Blocking and associability change.

    PubMed

    Jones, Peter M; Haselgrove, Mark

    2013-07-01

    Blocking of learning about a conditioned stimulus (the "blocked" cue) occurs when it is trained alongside an additional stimulus (the "blocking" cue) that has been previously presented with the outcome. A number of theories (e.g., N. J. Mackintosh. 1975a. A Theory of Attention: Variations in the Associability of Stimuli With Reinforcement. Psychological Review, 82, 276-298; J. M. Pearce & G. Hall. 1980. A Model for Pavlovian Learning: Variation in the Effectiveness of Conditioned But Not Unconditioned Stimuli. Psychological Review, 87, 532-552) account for this attenuation in learning by proposing that attention paid to the blocked cue is restricted. In three experiments, we examined the associability of both blocked and blocking cues. In Experiment 1, rats were trained with a blocking protocol before being given a test discrimination composed of two components; one of these components required the use of the previously blocked cue as a discriminative stimulus, and the other component was soluble by using the blocking cue. To our surprise, the component that depended on the blocked cue was more readily solved than the component dependent on the blocking cue. The results of Experiments 2 and 3 suggest that this is due to the quantity of exposure that each stimulus received during initial training. Implications for theories of blocking, and more widely associative learning, are discussed.

  5. 31 CFR 515.549 - Bank accounts and other property of non-Cuban citizens who were in Cuba on or after July 8, 1963.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... non-Cuban citizens who were in Cuba on or after July 8, 1963. 515.549 Section 515.549 Money and... Licensing Policy § 515.549 Bank accounts and other property of non-Cuban citizens who were in Cuba on or... accounts and other property of non-Cuban citizens who have left Cuba, provided that they submit...

  6. Thermoelectric properties of FeAs based superconductors, with thick perovskite- and Sm-O fluorite-type blocking layers

    NASA Astrophysics Data System (ADS)

    Singh, S. J.; Shimoyama, J.; Ogino, H.; Kishio, K.

    2015-11-01

    The transport properties (electrical resistivity, Hall and Seebeck coefficient, and thermal conductivity) of iron based superconductors with thick perovskite-type oxide blocking layers and fluorine-doped SmFeAsO were studied to explore their possible potential for thermoelectric applications. The thermal conductivity of former compounds depicts the dominated role of phonon and its value decreases rapidly below the Tc, suggesting the addition of scattering of phonons. Both the Seebeck coefficient (S) and Hall coefficient (RH) of all samples were negative in the whole temperature region below 300 K, indicating that the major contribution to the normal state conductivity is by electrons. In addition, the profile of S(T) and RH(T) of all samples have similar behaviours as would be expected for a multi-band superconductors. Although the estimated thermoelectric figure of merit (ZT) of these compounds was much lower than that of practically applicable thermoelectric materials, however its improvement can be expected by optimizing microstructure of the polycrystalline materials, such as densification and grain orientation.

  7. Chemical Analysis and Aqueous Solution Properties of Charged Amphiphilic Block Copolymers PBA-b-PAA Synthesized by MADIX

    SciTech Connect

    Jacquin,M.; Muller, P.; Talingting-Pabalan, R.; Cottet, H.; Berret, J.; Futterer, T.; Theodoly, O.

    2007-01-01

    We have linked the structural and dynamic properties in aqueous solution of amphiphilic charged diblock copolymers poly(butyl acrylate)-b-poly(acrylic acid), PBA-b-PAA, synthesized by controlled radical polymerization, with the physico-chemical characteristics of the samples. Despite product imperfections, the samples self-assemble in melt and aqueous solutions as predicted by monodisperse microphase separation theory. However, the PBA core are abnormally large; the swelling of PBA cores is not due to AA (the Flory parameter ?PBA/PAA, determined at 0.25, means strong segregation), but to h-PBA homopolymers (content determined by liquid chromatography at the point of exclusion and adsorption transition, LC-PEAT). Beside the dominant population of micelles detected by scattering experiments, capillary electrophoresis CE analysis permitted detection of two other populations, one of h-PAA, and the other of free PBA-b-PAA chains, that have very short PBA blocks and never self-assemble. Despite the presence of these free unimers, the self-assembly in solution was found out of equilibrium: the aggregation state is history dependant and no unimer exchange between micelles occurs over months (time-evolution SANS). The high PBA/water interfacial tension, measured at 20 mN/m, prohibits unimer exchange between micelles. PBA-b-PAA solution systems are neither at thermal equilibrium nor completely frozen systems: internal fractionation of individual aggregates can occur.

  8. Correlating bulk properties and nanoscale rearrangement during UV-initiated gelation of hybrid nanoparticle/ block copolymer systems

    NASA Astrophysics Data System (ADS)

    Juggernauth, K. Anne; Seifert, Soenke; Love, Brian

    2013-03-01

    We use rheology and Small Angle X-Ray Scattering (SAXS) to investigate UV initiated gel formation in aqueous dispersions of clay nanoparticles in the presence of poly(ethyleneoxide-b-propyleneoxide-b-ethyleneoxide) block copolymer surfactants (Pluronics®) and small amounts of a photoacid generator (PAG). This material system demonstrates stable liquid-like behavior in the absence of UV but undergoes bulk gelation upon UV exposure. Rheology was used to monitor the bulk properties of a series of samples undergoing UV exposure and confirm bulk gel formation. We further probe nanoparticle rearrangement using time resolved synchrotron SAXS with simultaneous UV exposure. Time dependent SAXS indicate an absence of long range order and crystallinity while changes in the scattering profile are related to short range interparticle interactions leading to a stable or arrested structure. Finally, we compare the time scales for structural rearrangement of nanoparticles with the bulk gelation behavior. Our results show that the kinetics for local structural changes between particles and bulk gelation from UV exposure are strongly correlated.

  9. Effect of composition and nanostructure on CO2/N-2 transport properties of supported alkyl-imidazolium block copolymer membranes

    SciTech Connect

    Nguyen, PT; Wiesenauer, EF; Gin, DL; Noble, RD

    2013-03-01

    Polymerized room-temperature ionic liquids (poly(RTIL)s) have garnered attention as new and interesting membrane materials for CO2/light gas separations because they combine the high CO2 affinity and thermal and chemical stability of RTILs, with the physical and mechanical properties of polymeric materials. Our group recently synthesized a new type of block copolymer (BCP) combining an imidazolium-based poly(RTIL) and an alkyl non-ionic polymer. These alkyl-b-ionic BCPs phase-separate into ordered nanostructures. Prior work investigating gas transport through phase-separated BCPs is very limited, and none has included RTIL-based BCP systems. However it has been shown that nanoscale phase-separation could facilitate gas transport via nanostructure orientation control or phase connectivity improvement. We have successfully made defect-free, thin-film composite membranes with these novel alkyl-imidazolium BCPs as a 3-20 mu m thick top layer, and determined their CO2/N-2 separation properties via single-gas permeability measurements and selectivity calculations. These new BCP materials were found to have distinct advantages over the analogous physical blends of the parent homopolymers with respect to membrane fabrication. The composition of the BCP top layer, which is directly connected to the type of nanostructure formed, was found to have a significant effect on CO2 permeability (i.e., it can increase CO2 permeability by two orders of magnitude up to an observed value of 9300 barrer). This improvement is mainly due to a large increase in the diffusion coefficient in the ordered nanostructures compared to amorphous BCP materials. (C) 2012 Elsevier B.V. All rights reserved.

  10. Testing block subdivision algorithms on block designs

    NASA Astrophysics Data System (ADS)

    Wiseman, Natalie; Patterson, Zachary

    2016-01-01

    Integrated land use-transportation models predict future transportation demand taking into account how households and firms arrange themselves partly as a function of the transportation system. Recent integrated models require parcels as inputs and produce household and employment predictions at the parcel scale. Block subdivision algorithms automatically generate parcel patterns within blocks. Evaluating block subdivision algorithms is done by way of generating parcels and comparing them to those in a parcel database. Three block subdivision algorithms are evaluated on how closely they reproduce parcels of different block types found in a parcel database from Montreal, Canada. While the authors who developed each of the algorithms have evaluated them, they have used their own metrics and block types to evaluate their own algorithms. This makes it difficult to compare their strengths and weaknesses. The contribution of this paper is in resolving this difficulty with the aim of finding a better algorithm suited to subdividing each block type. The proposed hypothesis is that given the different approaches that block subdivision algorithms take, it's likely that different algorithms are better adapted to subdividing different block types. To test this, a standardized block type classification is used that consists of mutually exclusive and comprehensive categories. A statistical method is used for finding a better algorithm and the probability it will perform well for a given block type. Results suggest the oriented bounding box algorithm performs better for warped non-uniform sites, as well as gridiron and fragmented uniform sites. It also produces more similar parcel areas and widths. The Generalized Parcel Divider 1 algorithm performs better for gridiron non-uniform sites. The Straight Skeleton algorithm performs better for loop and lollipop networks as well as fragmented non-uniform and warped uniform sites. It also produces more similar parcel shapes and patterns.

  11. Tuning thermoresponsive behavior of diblock copolymers and their gold core hybrids. Part 2. How properties change depending on block attachment to gold nanoparticles.

    PubMed

    Chen, Ning; Xiang, Xu; Heiden, Patricia A

    2013-04-15

    Thermoresponsive diblock copolymers of di(ethylene glycol) methyl ether methacrylate (DEGMA) and oligo(ethylene glycol) methyl ether acrylate (OEGA) were synthesized by reversible addition-fragmentation chain transfer polymerization, allowing us to prepare diblocks with a thiol group at the desired chain end, and bond that block to a ~20 nm gold nanoparticle core. The cloud point and coil-globule transition window were measured by UV-vis spectroscopy. The gold core lowered the cloud point and narrowed the coil-globule transition window of all the diblock hybrids, but raised the cloud point of statistical copolymer hybrids that had similar cloud points. The extent of the change in the thermo-response properties of the hybrid diblock copolymers was more significant when the gold was bonded to the DEGMA block than the OEGA block. This block is less hydrophilic and sterically hindered than OEGA and may adsorb more effectively to the gold so that the hydration of the outer OEGA block is relatively unaffected by the Au core. This work indicates that diblock copolymers allow factors such as steric bulk and the effects on arrangement around a metal core to be effective tools for manipulating thermo-responsive properties that are not as significant with statistical copolymers.

  12. A Fluid Block Schedule

    ERIC Educational Resources Information Center

    Ubben, Gerald C.

    1976-01-01

    Achieving flexibility without losing student accountability is a challenge that faces every school. With a fluid block schedule, as described here, accountability is maintained without inhibiting flexibility. An additional advantage is that three levels of schedule decision making take some of the pressure off the principal. (Editor)

  13. 18 CFR 367.1011 - Account 101.1, Property under capital leases.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... under capital leases. 367.1011 Section 367.1011 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE PUBLIC UTILITY HOLDING COMPANY ACT OF 2005... date, (4) Original cost or fair market value of property leased, (5) Future minimum lease payments,...

  14. 18 CFR 367.1011 - Account 101.1, Property under capital leases.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... under capital leases. 367.1011 Section 367.1011 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE PUBLIC UTILITY HOLDING COMPANY ACT OF 2005... date, (4) Original cost or fair market value of property leased, (5) Future minimum lease payments,...

  15. Designing poly[(R)-3-hydroxybutyrate]-based polyurethane block copolymers for electrospun nanofiber scaffolds with improved mechanical properties and enhanced mineralization capability.

    PubMed

    Liu, Kerh Li; Choo, Eugene Shi Guang; Wong, Siew Yee; Li, Xu; He, Chao Bin; Wang, John; Li, Jun

    2010-06-10

    Efforts to mineralize electrospun hydrophobic polyester scaffold often require prior surface modification such as plasma or alkaline treatment, which may affect the mechanical integrity of the resultant scaffold. Here through rational design we developed a series of polyurethane block copolymers containing poly[(R)-3-hydroxybutyrate] (PHB) as hard segment and poly(ethylene glycol) (PEG) as soft segment that could be easily fabricated into mineralizable electrospun scaffold without the need of additional surface treatment. To ensure that the block copolymers do not swell excessively in water, PEG content in the polymers was kept below 50 wt %. To obtain good dry and hydrated state mechanical properties with limited PEG, low-molecular-weight PHB-diol with M(n) 1230 and 1790 were used in various molar feed ratios. The macromolecular characteristics of the block copolymers were confirmed by (1)H NMR spectroscopy, gel permeation chromatography (GPC), and thermal gravimetric analyses (TGA). With the incorporation of the hydrophilic PEG segments, the surface and bulk hydrophilicity of the block copolymers were significantly improved. Differential scanning calorimetry (DSC) revealed that the block copolymers had low PHB crystallinity and no PEG crystallinity. This was further confirmed by X-ray diffraction analyses (XRD) in both dry and hydrated states. With short PHB segments and soft PEG coupled together, the block copolymers were no longer brittle. Tensile measurements showed that the block copolymers with higher PEG content or shorter PHB segments were more ductile. Furthermore, their ductility was enhanced in hydrated states with one particular example showing increment in strain at break from 1090 to 1962%. The block copolymers were fabricated into an electrospun fibrous scaffold that was easily mineralized by simple incubation in simulated body fluid. The materials have good potential for bone regeneration application and may be extended to other applications by

  16. Effective Transport Properties Accounting for Electrochemical Reactions of Proton-Exchange Membrane Fuel Cell Catalyst Layers

    SciTech Connect

    Pharoah, Jon; Choi, Hae-Won; Chueh, Chih-Che; Harvey, David

    2011-07-01

    There has been a rapidly growing interest in three-dimensional micro-structural reconstruction of fuel cell electrodes so as to derive more accurate descriptors of the pertinent geometric and effective transport properties. Due to the limited accessibility of experiments based reconstruction techniques, such as dual-beam focused ion beam-scanning electro microscopy or micro X-Ray computed tomography, within sample micro-structures of the catalyst layers in polymer electrolyte membrane fuel cells (PEMFCs), a particle based numerical model is used in this study to reconstruct sample microstructure of the catalyst layers in PEMFCs. Then the reconstructed sample structure is converted into the computational grid using body-fitted/cut-cell based unstructured meshing technique. Finally, finite volume methods (FVM) are applied to calculate effective properties on computational sample domains.

  17. Analysis of G-block distributions and their impact on gel properties of in vitro epimerized mannuronan.

    PubMed

    Aarstad, Olav; Strand, Berit Løkensgard; Klepp-Andersen, Lise Mari; Skjåk-Bræk, Gudmund

    2013-10-14

    This paper reports a study of the distribution and function of homopolymeric guluronic acid blocks (G-blocks) in enzymatically modified alginate. High molecular weight mannuronan was incubated with one native (AlgE6) and two engineered G-block generating mannuronan C-5 epimerases (AlgE64 and EM1). These samples were found to contain G-blocks with a DP ranging from 20 to approximately 50, lacking the extremely long G-blocks (DP > 100) found in algal alginates. Calcium gels from epimerized materials were highly compressible and exhibited higher syneresis and rupture strength but lower Youngs modulus than gels made from algal polymers of similar G-content. Addition of extremely long G-blocks to the epimerized alginate resulted in decreased syneresis and rupture strength and an increased Young's modulus that can be explained by reinforcement of the cross-linking zones at the cost of length and/or numbers of elastic segments. The presence and impact of these extremely long G-blocks found in natural alginates suggest that alginate gels can be viewed as a nanocomposite material.

  18. Accounting for the analytical properties of the quark propagator from the Dyson-Schwinger equation

    NASA Astrophysics Data System (ADS)

    Dorkin, S. M.; Kaptari, L. P.; Kämpfer, B.

    2015-05-01

    An approach based on combined solutions of the Bethe-Salpeter (BS) and Dyson-Schwinger (DS) equations within the ladder-rainbow approximation in the presence of singularities is proposed to describe the meson spectrum as quark-antiquark bound states. We consistently implement in the BS equation the quark propagator functions from the DS equation, with and without pole-like singularities, and show that, by knowing the precise positions of the poles and their residues, one is able to develop reliable methods of obtaining finite interaction BS kernels and to solve the BS equation numerically. We show that, for bound states with masses M <1 GeV, there are no singularities in the propagator functions when employing the infrared part of the Maris-Tandy kernel in truncated BS-DS equations. For M >1 GeV, however, the propagator functions reveal pole-like structures. Consequently, for each type of meson (unflavored, strange, and charmed) we analyze the relevant intervals of M where the pole-like singularities of the corresponding quark propagator influence the solution of the BS equation and develop a framework within which they can be consistently accounted for. The BS equation is solved for pseudoscalar and vector mesons. Results are in good agreement with experimental data. Our analysis is directly related to the future physics program at FAIR with respect to open charm degrees of freedom.

  19. Accounting for the dispersion in the x ray properties of early-type galaxies

    NASA Technical Reports Server (NTRS)

    White, Raymond E., III; Sarazin, Craig L.

    1990-01-01

    The x ray luminosities of early-type galaxies are correlated with their optical (e.g., blue) luminosities (L sub X approx. L sub B exp 1.6), but the x ray luminosities exhibit considerable scatter for a given optical luminosity L sub B. This dispersion in x ray luminosity is much greater than the dispersion of other properties of early-type galaxies (for a given L sub B), such as luminosity scale-length, velocity dispersion, color, and metallicity. Here, researchers consider several possible sources for the dispersion in x ray luminosity. Some of the scatter in x ray luminosity may result from stellar population variations between galaxies with similar L sub B. Since the x ray emitting gas is from accumulated stellar mass loss, the L sub X dispersion may be due to variations in integrated stellar mass loss rates. Another possible cause of the L sub X dispersion may be variations in the amount of cool material in the galaxies; cool gas may act as an energy sink for the hot gas. Infrared emission may be used to trace such cool material, so researchers look for a correlation between the infrared emission and the x ray emission of early-type galaxies at fixed L sub B. Velocity dispersion variations between galaxies of similar L sub B may also contribute to the L sub X dispersion. The most likely a priori source of the dispersion in L sub X is probably the varying amount of ram-pressure stripping in a range of galaxy environments. The hot gaseous halos of early-type galaxies can be stripped in encounters with other galaxies or with ambient cluster gas if the intracluster gas is sufficiently dense. Researchers find that the most likely cause of dispersion in the x ray properties of early type galaxies is probably the ram-pressure stripping of gaseous halos from galaxies. For a sample of 81 early-type galaxies with x ray luminosities or upper limits derived from Einstein Observatory observations (CFT) researchers calculated the cumulative distribution of angular distances

  20. Population Blocks.

    ERIC Educational Resources Information Center

    Smith, Martin H.

    1992-01-01

    Describes an educational game called "Population Blocks" that is designed to illustrate the concept of exponential growth of the human population and some potential effects of overpopulation. The game material consists of wooden blocks; 18 blocks are painted green (representing land), 7 are painted blue (representing water); and the remaining…

  1. 31 CFR 597.303 - Blocked account; blocked funds.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FOREIGN TERRORIST ORGANIZATIONS SANCTIONS... a foreign terrorist organization or its agent or in which a foreign terrorist organization or...

  2. 31 CFR 597.303 - Blocked account; blocked funds.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FOREIGN TERRORIST ORGANIZATIONS SANCTIONS... a foreign terrorist organization or its agent or in which a foreign terrorist organization or...

  3. 31 CFR 597.303 - Blocked account; blocked funds.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FOREIGN TERRORIST ORGANIZATIONS SANCTIONS... a foreign terrorist organization or its agent or in which a foreign terrorist organization or...

  4. 31 CFR 597.303 - Blocked account; blocked funds.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FOREIGN TERRORIST ORGANIZATIONS SANCTIONS... a foreign terrorist organization or its agent or in which a foreign terrorist organization or...

  5. 31 CFR 597.303 - Blocked account; blocked funds.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY FOREIGN TERRORIST ORGANIZATIONS SANCTIONS... a foreign terrorist organization or its agent or in which a foreign terrorist organization or...

  6. Design, synthesis, and properties of a new class of building blocks for assembly of molecule-based magnets

    NASA Astrophysics Data System (ADS)

    Misiolek, Andrzej Wladyslaw

    In this work, mono and dianions of the tetrone 1 were proposed as discrete building blocks for assembly of molecular magnets.* These anionic subunits are designed to form extended multidimensional structures upon complexation with metal rations. This particular framework also was chosen so that dianion 12- (or its derivatives) would possess a paramagnetic triplet as a ground state. High quality ab-initio CASSCF(14, 12)/6-31+G* calculations showed that indeed the singlet-triplet gap of metal complexes of 1 2- is small and its sign and magnitude tongly depends on structural modifications. For example a 17.3 kcal/mol preference for a singlet is predicted for isolated 12- while the triplet state is preferred by 4.3 kcal/mol for the symmetrically coordinated complex 1(AlF2)2.* Synthetic procedures leading to a family of neutral aryl substituted tetrones (2) has been developed and electrochemical studies have shown that they may be reversibly reduced in two successive one-electron processes to mono- and dianions. These mono- and dianions have been generated on a preparative scale by reduction of the parent tetrones with alkali metals under anaerobic conditions. Solutions of anions were characterized by Vis-NIR, NMR and EPR spectroscopy. EPR of the anion radicals 2- reveals the high symmetry of the spin delocalisation. Spectroscopic studies of dianions were hampered by low solubility and aggregation phenomena and no definite answer concerning their ground spin states could be obtained. Several attempts were made to grow single crystals of 2 - and 22- in order to probe the self-assembling properties of those species and to obtain definite answers concerning the ground state of the dianion. These attempts turned out to be successful only for alkali metal salts of the monoanion (t-Bu) 8(MeO)42-. Its K + salt crystallized as 1-D chains with the expected bridging and chelating mode of coordination. The closely related Na+ salt, recently crystallized by Robert Gentner, shows a

  7. 49 CFR 1242.30 - Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 9 2013-10-01 2013-10-01 false Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17-00, 62-18-00, and 62-19-00). 1242.30 Section 1242.30....30 Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39,...

  8. 49 CFR 1242.30 - Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 9 2010-10-01 2010-10-01 false Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17-00, 62-18-00, and 62-19-00). 1242.30 Section 1242.30....30 Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39,...

  9. Physicochemical properties of pH-controlled polyion complex (PIC) micelles of poly(acrylic acid)-based double hydrophilic block copolymers and various polyamines.

    PubMed

    Warnant, J; Marcotte, N; Reboul, J; Layrac, G; Aqil, A; Jerôme, C; Lerner, D A; Gérardin, C

    2012-05-01

    The physicochemical properties of polyion complex (PIC) micelles were investigated in order to characterize the cores constituted of electrostatic complexes of two oppositely charged polyelectrolytes. The pH-sensitive micelles were obtained with double hydrophilic block copolymers containing a poly(acrylic acid) block linked to a modified poly(ethylene oxide) block and various polyamines (polylysine, linear and branched polyethyleneimine, polyvinylpyridine, and polyallylamine). The pH range of micellization in which both components are ionized was determined for each polyamine. The resulting PIC micelles were characterized using dynamic light scattering and small-angle X-ray scattering experiments (SAXS). The PIC micelles presented a core-corona nanostructure with variable polymer density contrasts between the core and the corona, as revealed by the analysis of the SAXS curves. It was shown that PIC micelle cores constituted by polyacrylate chains and polyamines were more or less dense depending on the nature of the polyamine. It was also determined that the density of the cores of the PIC micelles depended strongly on the nature of the polyamine. These homogeneous cores were surrounded by a large hairy corona of hydrated polyethylene oxide block chains. Auramine O (AO) was successfully entrapped in the PIC micelles, and its fluorescence properties were used to get more insight on the core properties. Fluorescence data confirmed that the cores of such micelles are quite compact and that their microviscosity depended on the nature of the polyamine. The results obtained on these core-shell micelles allow contemplating a wide range of applications in which the AO probe would be replaced by various cationic drugs or other similarly charged species to form drug nanocarriers or new functional nanodevices.

  10. Properties of Transmission and Leaky Modes in a Plasmonic Waveguide Constructed by Periodic Subwavelength Metallic Hollow Blocks.

    PubMed

    Wu, Jin Jei; Wu, Chien Jang; Shen, Jian Qi; Hou, Da Jun; Lo, Wen Chen

    2015-01-01

    Based on the concept of low-frequency spoof surface plasmon polaritons (spoof SPPs), a kind of leaky mode is proposed in a waveguide made of a subwavelength metal-block array with open slots. Numerical results reveal that a new transmission mode is found in the periodic subwavelength metal open blocks. This modal field is located inside the interior of a hollow block compared with that in a solid metal block array. The dispersion curve shows that such a new SPPs mode has a negative slope, crossing the light line, and then going into a zone of leaky mode at higher frequencies. The leaky mode has a wider frequency bandwidth, and this can lead to a radiation scanning angle of 53° together with high radiation efficiency. Based on the individual characteristics exhibited by a frequency-dependent radiation pattern for the present leaky mode, the waveguide structure can have potential applications such as frequency dividers and demultiplexers. Experimental verification of such a leaky mode at microwave has been performed, and the experimental results are found to be consistent with the theoretical analysis.

  11. Properties of Transmission and Leaky Modes in a Plasmonic Waveguide Constructed by Periodic Subwavelength Metallic Hollow Blocks

    PubMed Central

    Jei Wu, Jin; Jang Wu, Chien; Qi Shen, Jian; Hou, Da Jun; Chen Lo, Wen

    2015-01-01

    Based on the concept of low-frequency spoof surface plasmon polaritons (spoof SPPs), a kind of leaky mode is proposed in a waveguide made of a subwavelength metal-block array with open slots. Numerical results reveal that a new transmission mode is found in the periodic subwavelength metal open blocks. This modal field is located inside the interior of a hollow block compared with that in a solid metal block array. The dispersion curve shows that such a new SPPs mode has a negative slope, crossing the light line, and then going into a zone of leaky mode at higher frequencies. The leaky mode has a wider frequency bandwidth, and this can lead to a radiation scanning angle of 53° together with high radiation efficiency. Based on the individual characteristics exhibited by a frequency-dependent radiation pattern for the present leaky mode, the waveguide structure can have potential applications such as frequency dividers and demultiplexers. Experimental verification of such a leaky mode at microwave has been performed, and the experimental results are found to be consistent with the theoretical analysis. PMID:26403387

  12. Properties of Transmission and Leaky Modes in a Plasmonic Waveguide Constructed by Periodic Subwavelength Metallic Hollow Blocks.

    PubMed

    Wu, Jin Jei; Wu, Chien Jang; Shen, Jian Qi; Hou, Da Jun; Lo, Wen Chen

    2015-01-01

    Based on the concept of low-frequency spoof surface plasmon polaritons (spoof SPPs), a kind of leaky mode is proposed in a waveguide made of a subwavelength metal-block array with open slots. Numerical results reveal that a new transmission mode is found in the periodic subwavelength metal open blocks. This modal field is located inside the interior of a hollow block compared with that in a solid metal block array. The dispersion curve shows that such a new SPPs mode has a negative slope, crossing the light line, and then going into a zone of leaky mode at higher frequencies. The leaky mode has a wider frequency bandwidth, and this can lead to a radiation scanning angle of 53° together with high radiation efficiency. Based on the individual characteristics exhibited by a frequency-dependent radiation pattern for the present leaky mode, the waveguide structure can have potential applications such as frequency dividers and demultiplexers. Experimental verification of such a leaky mode at microwave has been performed, and the experimental results are found to be consistent with the theoretical analysis. PMID:26403387

  13. Characterization of the sodium channel blocking properties of the major metabolites of cocaine in single cardiac myocytes.

    PubMed

    Crumb, W J; Clarkson, C W

    1992-06-01

    Clinical reports indicate that almost 30% of cocaine overdose-related deaths occur 2 to 5 hr after administration, when an appreciable amount of cocaine can be expected to have been converted to metabolites. We investigated the effects of the three major metabolites of cocaine: benzoylecgonine, ecgonine methyl ester and norcocaine on sodium channels in isolated guinea pig myocytes using the whole cell variant of the patch clamp technique at 16 +/- 0.5 degrees C. Benzoylecgonine and ecgonine methyl ester did not produce a significant block of sodium current at a concentration of 100 microM. In contrast, 30 microM norcocaine was found to reduce sodium current in a use-dependent manner qualitatively similar to cocaine. The time course of sodium current block development and recovery were characterized. With 30 microM norcocaine, two phases of block development were defined: a rapid phase (tau = 11.9 +/- 11.6 msec) and a slow phase (tau = 2.2 +/- 0.5 sec). Recovery from drug-induced block at -140 mV was approximately twice as fast for norcocaine (tau = 4.6 +/- 1.7 sec, n = 7) compared to cocaine (tau = 8.4 +/- 0.9 sec, n = 6). Norcocaine was found to have a higher affinity for inactivated cardiac sodium channels (Kdi = 5.7 +/- 0.9 microM) than cocaine (Kdi = 7.8 +/- 1.2 microM) (P less than .01); however, norcocaine produced less use-dependent block due to its faster unbinding kinetics. These data indicate that although norcocaine and cocaine are potent sodium channel blockers, benzoylecgonine and ecgonine methyl ester are ineffective blockers at clinically relevant concentrations (i.e., less than or equal to 100 microM).

  14. 41 CFR 102-36.245 - Are we accountable for the personal property that has been reported excess, and who is...

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... responsible for the care and handling costs? Yes, you are accountable for the excess personal property until the time it is picked up by the designated recipient or its agent. You are responsible for all care and handling charges while the excess personal property is going through the screening and...

  15. 41 CFR 102-36.245 - Are we accountable for the personal property that has been reported excess, and who is...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... responsible for the care and handling costs? Yes, you are accountable for the excess personal property until the time it is picked up by the designated recipient or its agent. You are responsible for all care and handling charges while the excess personal property is going through the screening and...

  16. 41 CFR 102-36.245 - Are we accountable for the personal property that has been reported excess, and who is...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... responsible for the care and handling costs? Yes, you are accountable for the excess personal property until the time it is picked up by the designated recipient or its agent. You are responsible for all care and handling charges while the excess personal property is going through the screening and...

  17. 41 CFR 102-36.245 - Are we accountable for the personal property that has been reported excess, and who is...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... responsible for the care and handling costs? Yes, you are accountable for the excess personal property until the time it is picked up by the designated recipient or its agent. You are responsible for all care and handling charges while the excess personal property is going through the screening and...

  18. 41 CFR 102-36.245 - Are we accountable for the personal property that has been reported excess, and who is...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... responsible for the care and handling costs? Yes, you are accountable for the excess personal property until the time it is picked up by the designated recipient or its agent. You are responsible for all care and handling charges while the excess personal property is going through the screening and...

  19. 49 CFR 1242.30 - Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 9 2012-10-01 2012-10-01 false Dismantling retired road property and depreciation....30 Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17..., switching and other) in proportion to the separation of common repair and maintenance expenses...

  20. 49 CFR 1242.30 - Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 9 2014-10-01 2014-10-01 false Dismantling retired road property and depreciation....30 Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17..., switching and other) in proportion to the separation of common repair and maintenance expenses...

  1. 49 CFR 1242.30 - Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 9 2011-10-01 2011-10-01 false Dismantling retired road property and depreciation....30 Dismantling retired road property and depreciation (accounts XX-17-39, XX-18-39, XX-19-39, 62-17..., switching and other) in proportion to the separation of common repair and maintenance expenses...

  2. Ionic Blocks

    ERIC Educational Resources Information Center

    Sevcik, Richard S.; Gamble, Rex; Martinez, Elizabet; Schultz, Linda D.; Alexander, Susan V.

    2008-01-01

    "Ionic Blocks" is a teaching tool designed to help middle school students visualize the concepts of ions, ionic compounds, and stoichiometry. It can also assist high school students in reviewing their subject mastery. Three dimensional blocks are used to represent cations and anions, with color indicating charge (positive or negative) and size…

  3. Optical and conductive properties of as-synthesized organic-capped TiO₂ nanorods highly dispersible in polystyrene-block-poly(methyl methacrylate) diblock copolymer.

    PubMed

    Cano, Laida; Di Mauro, Angela Evelyn; Striccoli, Marinella; Curri, M Lucia; Tercjak, Agnieszka

    2014-07-23

    As-synthesized organic-capped TiO2 nanorods were incorporated into polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) diblock copolymer to achieve TiO2/PS-b-PMMA nanocomposites with enhanced optical and conductive properties. The specific surface chemistry of TiO2 nanorods derived from the colloidal synthetic approach allowed their prompt incorporation in the PS-b-PMMA block copolymer template up to 50 wt %, which resulted in films with an extended coverage of highly dispersed nanoparticles for contents higher than 30 wt %. At such high nanorod contents, the films fabricated by the prepared nanocomposites demonstrated enhanced optical properties. Atomic force microscopy investigation of the nanocomposite films showed a cylindrical morphology for low nanorod contents. Conversely, higher nanorod contents resulted upon removal of the organic component in the nanocomposites with UV treatment in overall nanorod coverage of the film surface with the concomitant formation of charge percolation paths, which led to noticeable conductivity values. EFM and PF-TUNA measurements confirmed the conductive properties of the composites at nanoscale, whereas semiconductor analyzer measurements provided their macroscale characterization. In addition, an increase in the UV-vis absorption was observed with the increase in the nanorod content along with a remarkable conductivity of the overall film.

  4. Enhancing Energetic Properties and Sensitivity by Incorporating Amino and Nitramino Groups into a 1,2,4-Oxadiazole Building Block.

    PubMed

    Tang, Yongxing; Gao, Haixiang; Mitchell, Lauren A; Parrish, Damon A; Shreeve, Jean'ne M

    2016-01-18

    A single nitrogen-rich heterocyclic ring with many energetic groups is expected to exhibit excellent detonation performance. We report an effective approach for the synthesis of 3-amino-5-nitramino-1,2,4-oxadiazole, which has nitramino and amino groups in the same building block. The single-crystal X-ray structure shows layered hydrogen-bonding pairs as well as the presence of a water molecule which ensure insensitivity. Through incorporation of a cation, the hydrazinium or hydroxylammonium salts exhibit good energetic performance and acceptable sensitivities. PMID:26617389

  5. Enhancing Energetic Properties and Sensitivity by Incorporating Amino and Nitramino Groups into a 1,2,4-Oxadiazole Building Block.

    PubMed

    Tang, Yongxing; Gao, Haixiang; Mitchell, Lauren A; Parrish, Damon A; Shreeve, Jean'ne M

    2016-01-18

    A single nitrogen-rich heterocyclic ring with many energetic groups is expected to exhibit excellent detonation performance. We report an effective approach for the synthesis of 3-amino-5-nitramino-1,2,4-oxadiazole, which has nitramino and amino groups in the same building block. The single-crystal X-ray structure shows layered hydrogen-bonding pairs as well as the presence of a water molecule which ensure insensitivity. Through incorporation of a cation, the hydrazinium or hydroxylammonium salts exhibit good energetic performance and acceptable sensitivities.

  6. 3 CFR 13582 - Executive Order 13582 of August 17, 2011. Blocking Property of the Government of Syria and...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Property of the Government of Syria and Prohibiting Certain Transactions With Respect to Syria 13582 Order... Property of the Government of Syria and Prohibiting Certain Transactions With Respect to Syria By the... of Syria's continuing escalation of violence against the people of Syria and with respect to...

  7. Synthesis and characterization of a disubstituted piperazine derivative with T-type channel blocking action and analgesic properties

    PubMed Central

    Pudukulatham, Zubaidha; Zhang, Fang-Xiong; Gadotti, Vinicius M; M’Dahoma, Said; Swami, Prabhuling; Tamboli, Yasinalli

    2016-01-01

    Background T-type calcium channels are important contributors to signaling in the primary afferent pain pathway and are thus important targets for the development of analgesics. It has been previously reported that certain piperazine-based compounds such as flunarizine are able to inhibit T-type calcium channels. Thus, we hypothesized that novel piperazine compounds could potentially act as analgesics. Results Here, we have created a series of 14 compound derivatives around a diphenyl methyl-piperazine core pharmacophore. Testing their effects on transiently expressed Cav3.2 calcium channels revealed one derivative (3-((4-(bis(4-fluorophenyl)methyl)piperazin-1-yl)methyl)-4-(2-methoxyphenyl)-1,2,5-oxadiazole 2-oxide, compound 10e) as a potent blocker. 10e mediate tonic block of these channels with an IC50 of around 4 micromolar. 10e also blocked Cav3.1 and Cav3.3 channels, but only weakly affected high-voltage-activated Cav1.2 and Cav2.2 channels. Intrathecal delivery of 10e mediated relief from formalin and complete Freund’s adjuvant induced inflammatory pain that was ablated by genetic knockout of Cav3.2 channels. Conclusions Altogether, our data identify a novel T-type calcium channel blocker with tight structure activity relationship (SAR) and relevant in vivo efficacy in inflammatory pain conditions. PMID:27053601

  8. Effects of temperature, packaging and electron beam irradiation processing conditions on the property behaviour of Poly (ether-block-amide) blends.

    PubMed

    Murray, Kieran A; Kennedy, James E; McEvoy, Brian; Vrain, Olivier; Ryan, Damien; Cowman, Richard; Higginbotham, Clement L

    2014-06-01

    The radiation stability of Poly (ether-block-amide) (PEBA) blended with a multifunctional phenolic antioxidant and a hindered amide light stabiliser was examined under various temperatures, packaging and electron beam processing conditions. FTIR revealed that there were slight alterations to the PEBA before irradiation; however, these became more pronounced following irradiation. The effect of varying the temperature, packaging and processing conditions on the resultant PEBA properties was apparent. For example, rheology demonstrated that the structural properties could be enhanced by manipulating the aforementioned criteria. Mechanical testing exhibited less radiation resistance when the PEBA samples were vacuum packed and exposed to irradiation. MFI and AFM confirmed that the melting strength and surface topography could be reduced/increased depending on the conditions employed. From this study it was concluded that virgin PEBA submerged in dry ice with non-vacuum packaging during the irradiation process, provided excellent radiation resistance (20.9% improvement) in contrast to the traditional method. PMID:24863239

  9. Effects of temperature, packaging and electron beam irradiation processing conditions on the property behaviour of Poly (ether-block-amide) blends.

    PubMed

    Murray, Kieran A; Kennedy, James E; McEvoy, Brian; Vrain, Olivier; Ryan, Damien; Cowman, Richard; Higginbotham, Clement L

    2014-06-01

    The radiation stability of Poly (ether-block-amide) (PEBA) blended with a multifunctional phenolic antioxidant and a hindered amide light stabiliser was examined under various temperatures, packaging and electron beam processing conditions. FTIR revealed that there were slight alterations to the PEBA before irradiation; however, these became more pronounced following irradiation. The effect of varying the temperature, packaging and processing conditions on the resultant PEBA properties was apparent. For example, rheology demonstrated that the structural properties could be enhanced by manipulating the aforementioned criteria. Mechanical testing exhibited less radiation resistance when the PEBA samples were vacuum packed and exposed to irradiation. MFI and AFM confirmed that the melting strength and surface topography could be reduced/increased depending on the conditions employed. From this study it was concluded that virgin PEBA submerged in dry ice with non-vacuum packaging during the irradiation process, provided excellent radiation resistance (20.9% improvement) in contrast to the traditional method.

  10. Comparison of Gating Properties and Use-Dependent Block of Nav1.5 and Nav1.7 Channels by Anti-Arrhythmics Mexiletine and Lidocaine

    PubMed Central

    Wang, Ying; Mi, Jianxun; Lu, Ka; Lu, Yanxin; Wang, KeWei

    2015-01-01

    Mexiletine and lidocaine are widely used class IB anti-arrhythmic drugs that are considered to act by blocking voltage-gated open sodium currents for treatment of ventricular arrhythmias and relief of pain. To gain mechanistic insights into action of anti-arrhythmics, we characterized biophysical properties of Nav1.5 and Nav1.7 channels stably expressed in HEK293 cells and compared their use-dependent block in response to mexiletine and lidocaine using whole-cell patch clamp recordings. While the voltage-dependent activation of Nav1.5 or Nav1.7 was not affected by mexiletine and lidocaine, the steady-state fast and slow inactivation of Nav1.5 and Nav1.7 were significantly shifted to hyperpolarized direction by either mexiletine or lidocaine in dose-dependent manner. Both mexiletine and lidocaine enhanced the slow component of closed-state inactivation, with mexiletine exerting stronger inhibition on either Nav1.5 or Nav1.7. The recovery from inactivation of Nav1.5 or Nav1.7 was significantly prolonged by mexiletine compared to lidocaine. Furthermore, mexiletine displayed a pronounced and prominent use-dependent inhibition of Nav1.5 than lidocaine, but not Nav1.7 channels. Taken together, our findings demonstrate differential responses to blockade by mexiletine and lidocaine that preferentially affect the gating of Nav1.5, as compared to Nav1.7; and mexiletine exhibits stronger use-dependent block of Nav1.5. The differential gating properties of Nav1.5 and Nav1.7 in response to mexiletine and lidocaine may help explain the drug effectiveness and advance in new designs of safe and specific sodium channel blockers for treatment of cardiac arrhythmia or pain. PMID:26068619

  11. Comparison of Gating Properties and Use-Dependent Block of Nav1.5 and Nav1.7 Channels by Anti-Arrhythmics Mexiletine and Lidocaine.

    PubMed

    Wang, Ying; Mi, Jianxun; Lu, Ka; Lu, Yanxin; Wang, KeWei

    2015-01-01

    Mexiletine and lidocaine are widely used class IB anti-arrhythmic drugs that are considered to act by blocking voltage-gated open sodium currents for treatment of ventricular arrhythmias and relief of pain. To gain mechanistic insights into action of anti-arrhythmics, we characterized biophysical properties of Nav1.5 and Nav1.7 channels stably expressed in HEK293 cells and compared their use-dependent block in response to mexiletine and lidocaine using whole-cell patch clamp recordings. While the voltage-dependent activation of Nav1.5 or Nav1.7 was not affected by mexiletine and lidocaine, the steady-state fast and slow inactivation of Nav1.5 and Nav1.7 were significantly shifted to hyperpolarized direction by either mexiletine or lidocaine in dose-dependent manner. Both mexiletine and lidocaine enhanced the slow component of closed-state inactivation, with mexiletine exerting stronger inhibition on either Nav1.5 or Nav1.7. The recovery from inactivation of Nav1.5 or Nav1.7 was significantly prolonged by mexiletine compared to lidocaine. Furthermore, mexiletine displayed a pronounced and prominent use-dependent inhibition of Nav1.5 than lidocaine, but not Nav1.7 channels. Taken together, our findings demonstrate differential responses to blockade by mexiletine and lidocaine that preferentially affect the gating of Nav1.5, as compared to Nav1.7; and mexiletine exhibits stronger use-dependent block of Nav1.5. The differential gating properties of Nav1.5 and Nav1.7 in response to mexiletine and lidocaine may help explain the drug effectiveness and advance in new designs of safe and specific sodium channel blockers for treatment of cardiac arrhythmia or pain. PMID:26068619

  12. Tacticity-induced changes in the micellization and degradation properties of poly(lactic acid)-block-poly(ethylene glycol) copolymers.

    PubMed

    Agatemor, Christian; Shaver, Michael P

    2013-03-11

    Poly(lactic acid)-block-poly(ethylene glycol) copolymers (PLA-b-PEG) featuring varying tacticities (atactic, heterotactic, isotactic) in the PLA block were synthesized and investigated for their micellar stability, degradation, and thermal properties. Utilizing tin(II) bis(2-ethylhexanoate), aluminum salan, and aluminum salen catalysts, the copolymers were synthesized through the ring-opening polymerization of d-, l-, rac-, or a blend of l- and rac-lactide using monomethoxy-poly(ethylene glycol) as a macroinitiator. The critical micelle concentration, which reflects the micellar stability, was probed using a fluorescence spectroscopic method with pyrene as the probe. The copolymers were degraded in a methanolic solution of 1,5,7-triaza-bicyclo[4.4.0]dec-5-ene and the degradation was measured by (1)H NMR spectroscopic and gel permeation chromatographic analyses. Differential scanning calorimetry and thermogravimetric analysis provided information on the thermal properties of the copolymers. Atactic and heterotactic microstructures in the PLA block resulted in lower micellar stability, as well as faster degradation and shorter erosion time compared to polymers with high isotactic enchainment (Pm). By modification of the Pm, micellar stability, degradation, and erosion rates of the copolymers can be tuned to specific biomedical applications. Interestingly, while tin(II) bis(2-ethylhexanoate) and aluminum salan-catalyzed PLA-b-PEG copolymers exhibited similar micellization behavior, the aluminum salen-catalyzed PLA-b-PEG exhibited unique behavior at high micelle concentration in the presence of the pyrene probe. This unique behavior can be attributed to the disintegration of the micelles through the interactions of long isotactic stereoblock segments. PMID:23402292

  13. Superalloy Lattice Block Structures

    NASA Technical Reports Server (NTRS)

    Nathal, M. V.; Whittenberger, J. D.; Hebsur, M. G.; Kantzos, P. T.; Krause, D. L.

    2004-01-01

    Initial investigations of investment cast superalloy lattice block suggest that this technology will yield a low cost approach to utilize the high temperature strength and environmental resistance of superalloys in lightweight, damage tolerant structural configurations. Work to date has demonstrated that relatively large superalloy lattice block panels can be successfully investment cast from both IN-718 and Mar-M247. These castings exhibited mechanical properties consistent with the strength of the same superalloys measured from more conventional castings. The lattice block structure also accommodates significant deformation without failure, and is defect tolerant in fatigue. The potential of lattice block structures opens new opportunities for the use of superalloys in future generations of aircraft applications that demand strength and environmental resistance at elevated temperatures along with low weight.

  14. Electrospun nanofibrous scaffolds of segmented polyurethanes based on PEG, PLLA and PTMC blocks: Physico-chemical properties and morphology.

    PubMed

    Trinca, Rafael Bergamo; Abraham, Gustavo A; Felisberti, Maria Isabel

    2015-11-01

    Biocompatible polymeric scaffolds are crucial for successful tissue engineering. Biomedical segmented polyurethanes (SPUs) are an important and versatile class of polymers characterized by a broad spectrum of compositions, molecular architectures, properties and applications. Although SPUs are versatile materials that can be designed by different routes to cover a wide range of properties, they have been infrequently used for the preparation of electrospun nanofibrous scaffolds. This study reports the preparation of new electrospun polyurethane scaffolds. The segmented polyurethanes were synthesized using low molar masses macrodyols (poly(ethylene glycol), poly(l-lactide) and poly(trimethylene carbonate)) and 1,6-hexane diisocyanate and 1,4-butanodiol as isocyanate and chain extensor, respectively. Different electrospinning parameters such as solution properties and processing conditions were evaluated to achieve smooth, uniform bead-free fibers. Electrospun micro/nanofibrous structures with mean fiber diameters ranging from 600nm to 770nm were obtained by varying the processing conditions. They were characterized in terms of thermal and dynamical mechanical properties, swelling degree and morphology. The elastomeric polyurethane scaffolds exhibit interesting properties that could be appropriate as biomimetic matrices for soft tissue engineering applications. PMID:26249621

  15. Electrospun nanofibrous scaffolds of segmented polyurethanes based on PEG, PLLA and PTMC blocks: Physico-chemical properties and morphology.

    PubMed

    Trinca, Rafael Bergamo; Abraham, Gustavo A; Felisberti, Maria Isabel

    2015-11-01

    Biocompatible polymeric scaffolds are crucial for successful tissue engineering. Biomedical segmented polyurethanes (SPUs) are an important and versatile class of polymers characterized by a broad spectrum of compositions, molecular architectures, properties and applications. Although SPUs are versatile materials that can be designed by different routes to cover a wide range of properties, they have been infrequently used for the preparation of electrospun nanofibrous scaffolds. This study reports the preparation of new electrospun polyurethane scaffolds. The segmented polyurethanes were synthesized using low molar masses macrodyols (poly(ethylene glycol), poly(l-lactide) and poly(trimethylene carbonate)) and 1,6-hexane diisocyanate and 1,4-butanodiol as isocyanate and chain extensor, respectively. Different electrospinning parameters such as solution properties and processing conditions were evaluated to achieve smooth, uniform bead-free fibers. Electrospun micro/nanofibrous structures with mean fiber diameters ranging from 600nm to 770nm were obtained by varying the processing conditions. They were characterized in terms of thermal and dynamical mechanical properties, swelling degree and morphology. The elastomeric polyurethane scaffolds exhibit interesting properties that could be appropriate as biomimetic matrices for soft tissue engineering applications.

  16. Neuromuscular block

    PubMed Central

    Bowman, W C

    2006-01-01

    Descriptions of the South American arrow poisons known as curares were reported by explorers in the 16th century, and their site of action in producing neuromuscular block was determined by Claude Bernard in the mid-19th century. Tubocurarine, the most important curare alkaloid, played a large part in experiments to determine the role of acetylcholine in neuromuscular transmission, but it was not until after 1943 that neuromuscular blocking drugs became established as muscle relaxants for use during surgical anaesthesia. Tubocurarine causes a number of unwanted effects, and there have been many attempts to replace it. The available drugs fall into two main categories: the depolarising blocking drugs and the nondepolarising blocking drugs. The former act by complex mixed actions and are now obsolete with the exception of suxamethonium, the rapid onset and brief duration of action of which remain useful for intubation at the start of surgical anaesthesia. The nondepolarising blocking drugs are reversible acetylcholine receptor antagonists. The main ones are the atracurium group, which possess a built-in self-destruct mechanism that makes them especially useful in kidney or liver failure, and the vecuronium group, which are especially free from unwanted side effects. Of this latter group, the compound rocuronium is of especial interest because its rapid onset of action allows it to be used for intubation, and there is promise that its duration of action may be rapidly terminated by a novel antagonist, a particular cyclodextrin, that chelates the drug, thereby removing it from the acetylcholine receptors. PMID:16402115

  17. 3 CFR 13536 - Executive Order 13536 of April 12, 2010. Blocking Property of Certain Persons Contributing to the...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... Property of Certain Persons Contributing to the Conflict in Somalia 13536 Order 13536 Presidential... Persons Contributing to the Conflict in Somalia By the authority vested in me as President by the... deterioration of the security situation and the persistence of violence in Somalia, and acts of piracy and...

  18. 76 FR 52209 - Blocking Property of the Government of Syria and Prohibiting Certain Transactions With Respect to...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-08-22

    .... (Presidential Sig.) THE WHITE HOUSE, August 17, 2011. [FR Doc. 2011-21505 Filed 8-19-11; 8:45 am] Billing code... Property of the Government of Syria and Prohibiting Certain Transactions With Respect to Syria By the... of Syria's continuing escalation of violence against the people of Syria and with respect to...

  19. 3 CFR 13573 - Executive Order 13573 of May 18, 2011. Blocking Property of Senior Officials of the Government of...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Property of Senior Officials of the Government of Syria 13573 Order 13573 Presidential Documents Executive... Government of Syria By the authority vested in me as President by the Constitution and the laws of the United... with respect to the Government of Syria's continuing escalation of violence against the people of...

  20. 3 CFR 13572 - Executive Order 13572 of April 29, 2011. Blocking Property of Certain Persons With Respect to...

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... Property of Certain Persons With Respect to Human Rights Abuses in Syria 13572 Order 13572 Presidential... Persons With Respect to Human Rights Abuses in Syria By the authority vested in me as President by the... 13460 of February 13, 2008, finding that the Government of Syria's human rights abuses, including...

  1. 3 CFR 13599 - Executive Order 13599 of February 5, 2012. Blocking Property of the Government of Iran and...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... Property of the Government of Iran and Iranian Financial Institutions 13599 Order 13599 Presidential... Government of Iran and Iranian Financial Institutions By the authority vested in me as President by the... Iran and other Iranian banks to conceal transactions of sanctioned parties, the deficiencies in...

  2. 3 CFR 13617 - Executive Order 13617 of June 25, 2012. Blocking Property of the Government of the Russian...

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... Property of the Government of the Russian Federation Relating to the Disposition of Highly Enriched Uranium... to the Disposition of Highly Enriched Uranium Extracted From Nuclear Weapons By the authority vested... the Disposition of Highly Enriched Uranium Extracted from Nuclear Weapons, dated February 18,...

  3. Effects of electron beam irradiation on the property behaviour of poly(ether-block-amide) blended with various stabilisers

    NASA Astrophysics Data System (ADS)

    Murray, Kieran A.; Kennedy, James E.; Barron, Valerie; McEvoy, Brian; Vrain, Olivier; Ryan, Damien; Cowman, Richard; Higginbotham, Clement L.

    2015-05-01

    Radiosterilisation can induce modifications and/or degradation to transpire in poly(ether-block-amide) (PEBA) following irradiation. The current investigation utilises combined synergistic mixtures of stabilisers to minimise these effects, by melt blending them with the PEBA material. Hindered amine stabilisers (HAS), primary antioxidants and secondary antioxidants were the stabilisers incorporate to reduce/eliminate the effects of 50 kGy electron beam irradiation dose on the material. Results were discussed by comparing the stabilising efficiency of mixtures on the PEBA material in contrast to the control sample. Dynamic frequency sweeps demonstrated the formation of crosslinks, where the degree of crosslinking was dependent on the combination of stabilisers mixed in the base material (PEBA). The storage modulus displayed that PEBA blended with Irganox 565 had very slight changes in contrast to all other samples following irradiation. However, since this sample is a phenol containing system, severe discolouration was observed in comparison to other samples due to the oxidation of the hindered phenol. Overall, this study provides compelling evidence that a combined synergistic mixture of Irganox 565 (multifunctional phenolic antioxidant) and Tinuvin 783 (hindered amide light stabiliser) with PEBA, resulted in the best radiation stability.

  4. Inorganic-Organic Nanohybrid Materials of Layered Zinc Hydroxide Nitrate with Intercalated Salicylate: Preparation, Characterization and UV-Blocking Properties

    NASA Astrophysics Data System (ADS)

    Liu, Jiexiang; Zhang, Yongqing; Zhang, Xiaoguang

    2016-02-01

    Intercalation of salicylate (Sal) into layered zinc hydroxide nitrate (ZHN) nanohybrid materials was successfully synthesized by the coprecipitation method. The effect of pH, crystallization method, temperature and time of hydrothermal treatment on preparation was investigated in detail and compared. The products were confirmed by X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR), thermogravimetry and differential thermal analysis (TG-DTA), and scanning electron microscope (SEM). The results revealed that ZHN-Sal with pure phase and good crystallinity was obtained at pH = 6.0-6.5, 60∘C and 3h of temperature and time of hydrothermal treatment. The TG-DTA data indicated that the intercalated Sal had a high stability compared to the isolated. And the phases and compositions of the sample calcined at increasing temperatures were also identified by XRPD and FTIR techniques. Furthermore, ZHN-Sal exhibited an improved UV-blocking ability, showing it can be used as a potential alternative matrix for the UV blocker.

  5. Hybrid metal-coordinate transient networks: using bio-inspired building blocks to engineer the mechanical properties of physical hydrogels

    NASA Astrophysics Data System (ADS)

    Grindy, Scott; Barrett, Devin; Messersmith, Phillip; Holten-Andersen, Niels

    2014-03-01

    Recently, metal-coordinate complex crosslinks have been suggested to contribute to the self-healing properties of mussel byssi. Two specific amino acid derivatives - 3,4 dihydroxy-L-phenylalanine (dopa) and histidine (his) - are known to form coordinate complexes with trivalent and divalent ions (respectively) in aqueous solutions. We show here that, by functionalizing poly(ethylene glycol) polymers with dopa and his we are (1) able to characterize the fundamental kinetics and energetics of each specific metal-ligand pair using small amplitude oscillatory shear rheology and (2) create hybrid networks using various mixtures of metals and ligands. From this information, we can design gels with specific target mechanical properties by tailoring the amounts and types of metal-ligand crosslinks present in the gel network, resulting in the ability to engineer the mechanical relaxation spectrum. This work provides basic understanding necessary to intelligently design materials which incorporate metal-ligand crosslinks in more complex architectures.

  6. Block People.

    ERIC Educational Resources Information Center

    Peterson, Rayma

    1999-01-01

    Discusses an activity in which students in an after-school art class drew one another on pieces of 2-by-4 scrap lumber in order to create a class portrait in three dimensions. Stresses that the portraits on the wood blocks were done in-the-round, or each side was covered. (CMK)

  7. Imide/arylene ether block copolymers

    NASA Technical Reports Server (NTRS)

    Jensen, B. J.; Hergenrother, P. M.; Bass, R. G.

    1991-01-01

    Two series of imide/arylene either block copolymers were prepared using an arylene ether block and either an amorphous or semi-crystalline imide block. The resulting copolymers were characterized and selected physical and mechanical properties were determined. These results, as well as comparisons to the homopolymer properties, are discussed.

  8. A Solution-Processable (Tetraaniline-b-Polyethylene Glycol)3 Star-Shaped Rod-Coil Block Copolymer with Enhanced Electrochromic Properties.

    PubMed

    Cao, Linyu; Gong, Chen; Yang, Jiping

    2016-02-01

    A novel electroactive star-shaped rod-coil copolymer composed of a benzene core and three symmetrically positioned tetraaniline-b-poly(ethylene glycol) arms, (TAni-b-PEG)3 rod-coil block copolymer, is synthesized successfully and characterized using Fourier transform infrared spectroscopy (FTIR), UV-vis, (1)H NMR, and matrix-assisted laser desorption/ionization (MALDI) mass spectrometry. Uniform and high-quality (TAni-b-PEG)3 thin films onto indium tin oxide-coated glass surface are fabricated simply from its DMF solution. Resulting (TAni-b-PEG)3 copolymer thin films possess excellent electrochromic properties with a high optical contrast of 73.3%, superb coloration efficiency of 318.5 cm(2) C(-1) at 750 nm. Very short switching times, that is, 2.11 s and 2.14 s for coloring and bleaching times, respectively, are observed as well. The mechanism of these impressive electrochromic properties of (TAni-b-PEG)3 thin films possessed is proposed based on the atomic force microscopy investigation, star-shaped molecular geometry, synergetic electronic and ionic conductivity and amphiphilic self-assembly feature of (TAni-b-PEG)3 copolymer, which can self-assemble to form cylinder pattern consisting of quick pathways for electronic charges and ionic species, respectively. PMID:26663524

  9. Core-shell nanoparticles as building blocks for the bottom-up production of functional nanocomposites: PbTe-PbS thermoelectric properties.

    PubMed

    Ibáñez, Maria; Zamani, Reza; Gorsse, Stéphane; Fan, Jiandong; Ortega, Silvia; Cadavid, Doris; Morante, Joan Ramon; Arbiol, Jordi; Cabot, Andreu

    2013-03-26

    The bottom-up assembly of nanocrystals provides access to a three-dimensional composition control at the nanoscale not attainable by any other technology. In particular, colloidal nanoheterostructures, with intrinsic multiphase organization, are especially appealing building blocks for the bottom-up production of nanocomposites. In the present work, we use PbTe-PbS as the model material system and thermoelectricity as the paradigmatic application to investigate the potential of the bottom-up assembly of core-shell nanoparticles to produce functional nanocomposites. With this goal in mind, a rapid, high-yield and scalable colloidal synthetic route to prepare grams of PbTe@PbS core-shell nanoparticles with unprecedented narrow size distributions and exceptional composition control is detailed. PbTe@PbS nanoparticles were used as building blocks for the bottom-up production of PbTe-PbS nanocomposites with tuned composition. In such PbTe-PbS nanocomposites, synergistic nanocrystal doping effects result in up to 10-fold higher electrical conductivities than in pure PbTe and PbS nanomaterials. At the same time, the acoustic impedance mismatch between PbTe and PbS phases and a partial phase alloying provide PbTe-PbS nanocomposites with strongly reduced thermal conductivities. As a result, record thermoelectric figures of merit (ZT) of ∼1.1 were obtained from undoped PbTe and PbS phases at 710 K. These high ZT values prove the potential of the proposed processes to produce efficient functional nanomaterials with programmable properties. PMID:23448184

  10. In situ tracer tests to determine retention properties of a block scale fracture network in granitic rock at the Aspö Hard Rock Laboratory, Sweden.

    PubMed

    Andersson, Peter; Byegård, Johan; Tullborg, Eva-Lena; Doe, Thomas; Hermanson, Jan; Winberg, Anders

    2004-06-01

    Experiments were conducted at the Aspö Hard Rock Laboratory in order to improve the understanding of radionuclide retention properties of fractured crystalline bedrock in the 10-100 m scale (TRUE Block Scale Project, jointly funded by ANDRA, ENRESA, Nirex, JNC, Posiva and SKB). A series of tracer experiments were performed using sorbing tracers in three different flow paths. The different flow paths had Euclidian lengths of 14, 17 and 33 m, respectively, and one to three water conducting structures. Four tests were performed using different cocktails made up of radioactive sorbing tracers (22,24Na+, 42K+, 47Ca2+, 85Sr2+, 83,86Rb+, 131,133Ba2+ and 134,137Cs+). For each tracer injection, the breakthrough of sorbing tracers was compared to the breakthrough of a conservative tracer, 82Br-, 131I-, HTO and 186ReO4-, respectively. In the two longer flow paths, no breakthrough of 83Rb+ and 137Cs+ was observed after 8 months of pumping. Selected tracer tests were subject to basic modelling in which a one-dimensional (1D) advection-dispersion model, including surface sorption, and an unlimited matrix diffusion were used for the interpretation of the results. The results of the modelling indicated that there is a slightly higher mass transfer into a highly porous material in the block-scale experiment compared with in situ experiments performed over shorter distances and significantly higher than what would have been expected from laboratory data obtained from studies of the interactions in nonaltered intact rock.

  11. Core-shell nanoparticles as building blocks for the bottom-up production of functional nanocomposites: PbTe-PbS thermoelectric properties.

    PubMed

    Ibáñez, Maria; Zamani, Reza; Gorsse, Stéphane; Fan, Jiandong; Ortega, Silvia; Cadavid, Doris; Morante, Joan Ramon; Arbiol, Jordi; Cabot, Andreu

    2013-03-26

    The bottom-up assembly of nanocrystals provides access to a three-dimensional composition control at the nanoscale not attainable by any other technology. In particular, colloidal nanoheterostructures, with intrinsic multiphase organization, are especially appealing building blocks for the bottom-up production of nanocomposites. In the present work, we use PbTe-PbS as the model material system and thermoelectricity as the paradigmatic application to investigate the potential of the bottom-up assembly of core-shell nanoparticles to produce functional nanocomposites. With this goal in mind, a rapid, high-yield and scalable colloidal synthetic route to prepare grams of PbTe@PbS core-shell nanoparticles with unprecedented narrow size distributions and exceptional composition control is detailed. PbTe@PbS nanoparticles were used as building blocks for the bottom-up production of PbTe-PbS nanocomposites with tuned composition. In such PbTe-PbS nanocomposites, synergistic nanocrystal doping effects result in up to 10-fold higher electrical conductivities than in pure PbTe and PbS nanomaterials. At the same time, the acoustic impedance mismatch between PbTe and PbS phases and a partial phase alloying provide PbTe-PbS nanocomposites with strongly reduced thermal conductivities. As a result, record thermoelectric figures of merit (ZT) of ∼1.1 were obtained from undoped PbTe and PbS phases at 710 K. These high ZT values prove the potential of the proposed processes to produce efficient functional nanomaterials with programmable properties.

  12. In situ tracer tests to determine retention properties of a block scale fracture network in granitic rock at the Äspö Hard Rock Laboratory, Sweden

    NASA Astrophysics Data System (ADS)

    Andersson, Peter; Byegård, Johan; Tullborg, Eva-Lena; Doe, Thomas; Hermanson, Jan; Winberg, Anders

    2004-06-01

    Experiments were conducted at the Äspö Hard Rock Laboratory in order to improve the understanding of radionuclide retention properties of fractured crystalline bedrock in the 10-100 m scale (TRUE Block Scale Project, jointly funded by ANDRA, ENRESA, Nirex, JNC, Posiva and SKB). A series of tracer experiments were performed using sorbing tracers in three different flow paths. The different flow paths had Euclidian lengths of 14, 17 and 33 m, respectively, and one to three water conducting structures. Four tests were performed using different cocktails made up of radioactive sorbing tracers ( 22,24Na +, 42K +, 47Ca 2+, 85Sr 2+, 83,86Rb +, 131,133Ba 2+ and 134,137Cs +). For each tracer injection, the breakthrough of sorbing tracers was compared to the breakthrough of a conservative tracer, 82Br -, 131I -, HTO and 186ReO 4-, respectively. In the two longer flow paths, no breakthrough of 83Rb + and 137Cs + was observed after 8 months of pumping. Selected tracer tests were subject to basic modelling in which a one-dimensional (1D) advection-dispersion model, including surface sorption, and an unlimited matrix diffusion were used for the interpretation of the results. The results of the modelling indicated that there is a slightly higher mass transfer into a highly porous material in the block-scale experiment compared with in situ experiments performed over shorter distances and significantly higher than what would have been expected from laboratory data obtained from studies of the interactions in nonaltered intact rock.

  13. Radar Scattering and Block Size Properties of Lunar Crater Ejecta From Mini-RF and LROC NAC Data

    NASA Technical Reports Server (NTRS)

    Spudis, P. D.; Baloga, S. M.; Glaze, L. S.; Dixit, V.; Pantone, S. M.; Juvanescu, I.

    2012-01-01

    A major objective of the Mini-RF experiment is to distinguish lunar surfaces that may contain water/ice deposits [1,2]. Better understanding of the backscattering properties of craters of varying age and size is crucial for interpreting data received from the Mini-RF. The Mini-RF transmits a circularly polarized RF electromagnetic energy and coherently receives orthogonal linear polarization echoes [1]. The Mini- RF maps in two separate bands ( =12.6 and 4.5 cm) at a high resolution mode of 30 m/pixel [1]. Given the variables mentioned, the four stokes parameters are reconstructed. The Circular Polarization Ratio (CPR) is calculated for the purposes of understanding subsurface and surface roughness. The CPR is determined from reflections acquired from the ratio of power of the transmitted radio wave in same sense to the reflected radio wave in the opposite sense [1]. Ice in the permanently shadowed regions (PSRs) would be transparent to radar, but the inclusions of materials and imperfections would cause the radio wave to reflect multiple times [3], enhancing the number of same sense reflections and increasing the CPR. In addition, ice also displays the coherent backscatter opposition effect (CBOE), an interferrometric addition of same sense backscatter that further increases the CPR of ice targets [7]. High CPR values also correlate to multiple reflections and are typically associated with very rough surfaces [3]. The average dry lunar surface has a CPR in the range of 0.2-0.4 at 48deg incidence [3]. The purpose of this study is to begin to quantify degrees of surface wavelength-scale roughness with CPR and to understand how such surface roughness is created and gradually destroyed by erosion on the lunar surface. Another goal is to identify and isolate the possible causes of high CPR within the shadowed areas of anomalous polar craters [3]. All the studied craters are non-polar, so that we can see into their interiors in NAC images. The idea is to understand what

  14. pH- and Electro-Responsive Properties of Poly(acrylic acid) and Poly(acrylic acid)-block-poly(acrylic acid-grad-styrene) Brushes Studied by Quartz Crystal Microbalance with Dissipation Monitoring.

    PubMed

    Borisova, O V; Billon, L; Richter, R P; Reimhult, E; Borisov, O V

    2015-07-14

    We report on the synthesis of novel pH- and electro-responsive polyelectrolyte brushes from a gold substrate by direct one-step nitroxide-mediated polymerization of acrylic acid (AA) or copolymerization of AA and styrene (S). In the latter case, amphiphilic brushes of block-gradient copolymers PAA-b-(PAA-grad-PS) comprising one PAA block and one block with the gradient sequence of AA and S were obtained. The block-gradient copolymers are initiated from the surface by the start of the PAA block. The brushes were characterized by XPS and ellipsometry. (1)H NMR confirmed the gradient sequence of the PAA-grad-PS copolymer block. The pH- and electro-responsive properties of the brushes were studied by quartz crystal microbalance with dissipation monitoring (QCM-D) in combination with electrochemistry. This method provides evidence of swelling of the PAA brushes proportional to the contour length of the chains at elevated pH, whereas the response functions of the block-gradient copolymers are more complex and point to intermolecular aggregation in the brush at low pH. Monitoring of the changes in resonance frequency and dissipation of the QCM-D also demonstrates that application of negative voltage to the substrate leads to swelling of the brush; application of a positive voltage provokes only a transient collapse of the brush in proportion to the applied voltage. PMID:26070329

  15. pH- and Electro-Responsive Properties of Poly(acrylic acid) and Poly(acrylic acid)-block-poly(acrylic acid-grad-styrene) Brushes Studied by Quartz Crystal Microbalance with Dissipation Monitoring.

    PubMed

    Borisova, O V; Billon, L; Richter, R P; Reimhult, E; Borisov, O V

    2015-07-14

    We report on the synthesis of novel pH- and electro-responsive polyelectrolyte brushes from a gold substrate by direct one-step nitroxide-mediated polymerization of acrylic acid (AA) or copolymerization of AA and styrene (S). In the latter case, amphiphilic brushes of block-gradient copolymers PAA-b-(PAA-grad-PS) comprising one PAA block and one block with the gradient sequence of AA and S were obtained. The block-gradient copolymers are initiated from the surface by the start of the PAA block. The brushes were characterized by XPS and ellipsometry. (1)H NMR confirmed the gradient sequence of the PAA-grad-PS copolymer block. The pH- and electro-responsive properties of the brushes were studied by quartz crystal microbalance with dissipation monitoring (QCM-D) in combination with electrochemistry. This method provides evidence of swelling of the PAA brushes proportional to the contour length of the chains at elevated pH, whereas the response functions of the block-gradient copolymers are more complex and point to intermolecular aggregation in the brush at low pH. Monitoring of the changes in resonance frequency and dissipation of the QCM-D also demonstrates that application of negative voltage to the substrate leads to swelling of the brush; application of a positive voltage provokes only a transient collapse of the brush in proportion to the applied voltage.

  16. Remote-sensing based technique to account for sub-grid scale variability of land surface properties

    NASA Technical Reports Server (NTRS)

    Crosson, William L.; Laymon, Charles A.

    1995-01-01

    A method has been presented for the representation of sub-grid scale variability of surface properties within a land surface processes model. The method uses remotely-sensed data to directly or indirectly estimate probability density functions (PDF's) or key surface variables. Application of this technique in a coupled land surface-atmosphere model requires only grid-scale values of the variables of interest, obtained from low-resolution satellite imagery or surface/remote sensing data assimilation. The PDF's of each controlling surface property are superimposed on the respective grid-scale values to simulate sub-grid scale heterogeneity. Sensitivity studies will be carried out to ascertain the relative importance of the heterogeneity of several variables, and the degree to which non-linear property-process interactions impact large-scale fluxes.

  17. Photoacoustic determination of optical properties of aerosol particles collected on filters: development of a method taking into account substrate reflectivity.

    PubMed

    Röhl, R; McClenny, W A; Palmer, R A

    1982-02-01

    The absorptivity of soot and methylene blue particles collected on Teflon filters is derived from photoacoustic measurements by least squares fitting a simple expression based on Beer's law to the experimental data. Refinements of the expression take into account the diffuse reflection of light by the filter substrate, yielding a base 10 absorptivity at 600 nm for soot of 3.00 +/- 0.37 m(2)/g. This value is in close agreement with the result of transmission measurements performed on the same samples (3.08 +/- 0.05 m(2)/g). PMID:20372465

  18. Pineapple and banana pectins comprise fewer homogalacturonan building blocks with a smaller degree of polymerization as compared with yellow passion fruit and lemon pectins: implication for gelling properties.

    PubMed

    Yapo, Beda M

    2009-04-13

    Pectins are viewed as multiblock cobiopolymers of different pectic polysaccharides, notably, homogalacturonan (HG) and rhamnogalacturonan I (RG I). Furthermore, on the basis of HGs isolated from different (pectins from) dicot cell walls, HG is supposed to have an average degree of polymerization (DP) of approximately 100 irrespective of the plant source. To validate or invalidate these suppositions, pectins from both monocot (pineapple and banana) and dicot (yellow passion fruit and lemon) cell walls were examined. The results show that all the extracted pectins comprise HGs as well as type I and II arabinogalactan side chain-containing RGs I, but of significantly (p < 0.05) different relative proportions; lemon pectin being the richest in HGs, followed by yellow passion fruit pectin. The HG building blocks of each pectin are homogeneous with respect to the molecular size but have a significantly (p < 0.05) reduced length in monocot pectins (59-67) compared to dicot ones (93-102). Lemon pectin displayed the highest degree of esterification (DE), viscosity-average molecular weight (M(v)), and gelling ability, whereas with similar DEs and a higher M(v), banana pectin exhibited a lower gelling ability than yellow passion fruit pectin. It is concluded that both the HG amount and DP strongly influence the gelling properties of pectin.

  19. Photophysical properties and photochemistry of substituted cinnamates and cinnamic acids for UVB blocking: effect of hydroxy, nitro, and fluoro substitutions at ortho, meta, and para positions.

    PubMed

    Promkatkaew, Malinee; Suramitr, Songwut; Karpkird, Thitinun; Wanichwecharungruang, Supason; Ehara, Masahiro; Hannongbua, Supa

    2014-03-01

    Photophysical properties and photochemistry of various substituted cinnamates and cinnamic acids for ultraviolet B blocking were investigated experimentally and theoretically. This series includes monohydroxy, -nitro, and -fluoro derivatives. The absorption spectra were satisfactorily reproduced by the direct SAC-CI method with respect to the peak position and intensity. The transition character of the low-lying two ππ* and σπ* states for these 18 derivatives was analyzed. The para derivatives have a different transition character of the ππ* transitions compared with those of the ortho and meta derivatives. To elucidate the relaxation mechanism, the emission spectra were observed with oxygen quenching and the photostability was examined experimentally. The calculated radiative lifetimes indicate that the ortho- and meta-substituted derivatives have longer lifetimes for emission than the para derivatives. The potential energy curves of the first and second singlet excited states of the hydroxy derivatives as well as the vertical singlet and triplet transitions were examined to investigate the relaxation qualitatively. The ortho and meta derivatives have an energy barrier or flat surface in S1 resulting in fluorescence, whereas the para derivatives show nonradiative decay without an energy barrier. The para-hydroxy derivative was found to be an excellent UV absorber based on its broad absorption in the UVB/UVA regions, less emission, and higher photostability.

  20. Effect of casting solvents on the properties of styrene-butadiene-styrene block copolymers studied by positron annihilation techniques. [Temperature effects

    SciTech Connect

    Djermouni, B.; Ache, H.J.

    1980-01-01

    The positron annihilation technique was used to study the properties of styrene-butadiene-styrene block copolymers obtained by casting them in four different solvents: toluene, carbon tetrachloride, ethyl acetate, and methyl ethyl ketone. The positron annihilation rates plotted as a function of temperature show in all films irregularities at -70 and +85/sup 0/C which were attributed to the onset of motions in the polybutadiene and polystyrene domaines, respectively. In addition to that, two irregularities were observed at -14 and +10/sup 0/C if a poor solvent, such as ethyl acetate or methyl ethyl ketone, was used, while films cast in a good solvent such as toluene or carbon tetrachloride show only one additional irregularity on the lambda/sup 2/-T curves at -14/sup 0/C. The latter results were explained in terms of the interfacial model by assuming that these irregularities correspond to the glass transition of interlayer phases between the pure polystyrene and the pure polybutadiene phases. The one which shows the irregularity at -14/sup 0/C could be the phase in which polybutadiene is the major component, while the transition at +10/sup 0/C can be attributed to a phase in which polystyrene is the dominating factor.

  1. Educational Accountability

    ERIC Educational Resources Information Center

    Pincoffs, Edmund L.

    1973-01-01

    Discusses educational accountability as the paradigm of performance contracting, presents some arguments for and against accountability, and discusses the goals of education and the responsibility of the teacher. (Author/PG)

  2. Taking into account the heterogeneity and the temporal variability of the soil structure to implement relevant soil hydraulic properties

    NASA Astrophysics Data System (ADS)

    Cousin, Isabelle; Tetegan, Marion; Chabbi, Abad; Korboulewski, Nathalie

    2013-04-01

    Due to its position at the interface between the atmosphere and the vadose zone, the soil significantly contributes to the partitioning of rainfall into infiltration and overland flow, and, as a consequence, to the water feeding to plants and to the water aquifer level. The characteristics of the soil are usually described at the scale of the horizon, the latter being considered as the elementary component of the pedological maps and soil databases. As far as hydraulic properties are concerned - the water retention curve and the unsaturated hydraulic conductivity, the two essential soil characteristics for the description of soil water transfers -, their estimation at the horizon scale is then of major interest. Nevertheless, even at this scale, the horizon can usually not be considered neither as a homogeneous volume, nor as a time-stable system. As a consequence, methodologies have to be developed to characterize i) the degree of heterogeneity of the soil structure, ii) the evolution of the structure with time, and iii) if possible, the equivalent properties of such heterogeneous horizons. The surface horizons and the stony horizons can be considered as representative models of soil horizons to test these methodologies: the first ones because their fine structure evolves rapidly, under the effect of human agricultural activities - compaction by wheeling, fragmentation by tillage - of climate, or of faunal and vegetal actions; the second ones because the strong difference in material and in bulk density between fine earth and rock fragments lead to complex hydric behaviors. Based on several examples, the objectives of this presentation will then be i) to describe the temporal evolution of soil hydraulic properties in cultivated horizons, ii) to present methodologies for the estimation of equivalent soil hydraulic properties in stony horizons, and iii) to discuss the contribution of this new methodologies compared to old ones to better estimate the soil hydric

  3. Large Block Test Final Report

    SciTech Connect

    Lin, W

    2001-12-01

    This report documents the Large-Block Test (LBT) conducted at Fran Ridge near Yucca Mountain, Nevada. The LBT was a thermal test conducted on an exposed block of middle non-lithophysal Topopah Spring tuff (Tptpmn) and was designed to assist in understanding the thermal-hydrological-mechanical-chemical (THMC) processes associated with heating and then cooling a partially saturated fractured rock mass. The LBT was unique in that it was a large (3 x 3 x 4.5 m) block with top and sides exposed. Because the block was exposed at the surface, boundary conditions on five of the six sides of the block were relatively well known and controlled, making this test both easier to model and easier to monitor. This report presents a detailed description of the test as well as analyses of the data and conclusions drawn from the test. The rock block that was tested during the LBT was exposed by excavation and removal of the surrounding rock. The block was characterized and instrumented, and the sides were sealed and insulated to inhibit moisture and heat loss. Temperature on the top of the block was also controlled. The block was heated for 13 months, during which time temperature, moisture distribution, and deformation were monitored. After the test was completed and the block cooled down, a series of boreholes were drilled, and one of the heater holes was over-cored to collect samples for post-test characterization of mineralogy and mechanical properties. Section 2 provides background on the test. Section 3 lists the test objectives and describes the block site, the site configuration, and measurements made during the test. Section 3 also presents a chronology of events associated with the LBT, characterization of the block, and the pre-heat analyses of the test. Section 4 describes the fracture network contained in the block. Section 5 describes the heating/cooling system used to control the temperature in the block and presents the thermal history of the block during the test

  4. Stages of transformation of block elements

    NASA Astrophysics Data System (ADS)

    Babeshko, V. A.; Evdokimova, O. V.; Babeshko, O. M.

    2016-05-01

    The property to have various representations is investigated for the block elements describing the solutions of boundary-value problems for sets of partial differential equations in the regions with a boundary. These representations have various destinations. One of the representations, which is called packed, is convenient for constructing solutions in block structures on the basis of solutions in separate blocks. Another representation, which is called unpacked, is convenient for a detailed investigation of the properties of solutions in an individual block of the block structure.

  5. Olfactory Blocking and Odorant Similarity in the Honeybee

    ERIC Educational Resources Information Center

    Gerber, Bertram; Giurfa, Martin; Guerrieri, Fernando; Lachnit, Harald

    2005-01-01

    Blocking occurs when previous training with a stimulus A reduces (blocks) subsequent learning about a stimulus B, when A and B are trained in compound. The question of whether blocking exists in olfactory conditioning of proboscis extension reflex (PER) in honeybees is under debate. The last published accounts on blocking in honeybees state that…

  6. Compressible Solution Properties of Amorphous Polystyrene-block-Polybutadiene, Crystalline Polystyrene-block-Poly(Hydrogenated Polybutadiene) and Their Corresponding Homopolymers: Fluid-Fluid, Fluid-Solid and Fluid-Micelle Phase Transitions in Propane and Propylene

    SciTech Connect

    Hong, Kunlun; Mays, Jimmy; Winoto, Winoto; Radosz, Maciej

    2009-01-01

    Abstract Polystyrene, polybutadiene, hydrogenated polybutadiene, and styrene diblock copolymers of these homopolymers can form homogenous solutions in compressible solvents, such as propane and propylene, which separate into two bulk phases upon reducing pressure. The cloud and micellization pressures for homopolymer and diblock copolymers are generally found to be higher in propane than in propylene, except for hydrogenated polybutadiene and polystyrene-block-(hydrogenated polybutadiene). Hydrogenated polybutadiene homopolymers and copolymers exhibit relatively pressure-independent crystallization and melting observed in both propane and propylene solutions.

  7. Fabrication and study of properties of magnetite nanoparticles in hybrid micelles of polystyrene- block-polyethylene oxide and sodium dodecyl sulfate

    NASA Astrophysics Data System (ADS)

    Loginova, T. P.; Timofeeva, G. I.; Lependina, O. L.; Shandintsev, V. A.; Matyushin, A. A.; Khotina, I. A.; Shtykova, E. V.

    2016-01-01

    Magnetite nanoparticles have been formed for the first time in hybrid micelles of polystyrene- block-polyethylene oxide and sodium dodecyl sulfate in water by ultrasonic treatment at room temperature. An analysis by small-angle X-ray scattering and transmission electron microscopy (TEM) showed that magnetite nanoparticles in hybrid micelles of block copolymer and sodium dodecyl sulfate are polydesperse (have sizes from 0.5 to 20 nm). The specific magnetization of solid samples has been measured.

  8. Types of Heart Block

    MedlinePlus

    ... Block Explore Heart Block What Is... Electrical System & EKG Results Types Causes Who Is at Risk Signs & ... the P and the R waves on the EKG (electrocardiogram). First-degree heart block may not cause ...

  9. 76 FR 28434 - Notice of Issuance of Statement of Federal Financial Accounting Standard 40, Definitional Changes...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-05-17

    ... Standard 6, Accounting for Property, Plant, and Equipment AGENCY: Federal Accounting Standards Advisory... Statement of Federal Financial Accounting Standard 6, Accounting for Property, Plant, and Equipment....

  10. On the topological properties of the cross-shareholding networks of listed companies in China: Taking shareholders’ cross-shareholding relationships into account

    NASA Astrophysics Data System (ADS)

    Li, Huajiao; An, Haizhong; Gao, Xiangyun; Huang, Jiachen; Xu, Qun

    2014-07-01

    Shareholders are the owners of listed companies, and their relationships can directly affect the structure of the stock market. In this paper, we analyze the topological properties and evolution of the cross-shareholding networks of listed companies in the past 5 years in China from 2007 to 2011, an infrequently considered topic, by taking shareholders’ cross-shareholding relationships into account. This analysis arrives at a deeper insight into the inner characteristics of China’s stock market. We find that the cross-shareholding networks of listed companies with shareholders’ cross-shareholding relationships display statistical features that reveal the stock market’s complex relationships more precisely. In particular, the results show that when the shareholders’ cross-shareholding relationships are considered, first, the In-degree and Out-degree of the cross-shareholding networks follow power-law distribution and the R2 of the linear regression analysis of the cumulative degree distribution is relatively higher; second, the modularity of the communities is larger; finally, both the number of members of top-ranked communities and the number of communities that have a large number of members are larger than those of which only considering the relationships between shareholders and listed companies are taken into account. Such cross-shareholding networks analysis taking shareholders’ cross-shareholding relations into account would be a helpful tool for supervisory departments and for stock market researchers to grasp the inner cross-shareholding relationships of listed companies in China, and it will be also helpful for the further researches about the “agent problems” in the stock markets from a whole point of view.

  11. DNA block copolymers: functional materials for nanoscience and biomedicine.

    PubMed

    Schnitzler, Tobias; Herrmann, Andreas

    2012-09-18

    We live in a world full of synthetic materials, and the development of new technologies builds on the design and synthesis of new chemical structures, such as polymers. Synthetic macromolecules have changed the world and currently play a major role in all aspects of daily life. Due to their tailorable properties, these materials have fueled the invention of new techniques and goods, from the yogurt cup to the car seat belts. To fulfill the requirements of modern life, polymers and their composites have become increasingly complex. One strategy for altering polymer properties is to combine different polymer segments within one polymer, known as block copolymers. The microphase separation of the individual polymer components and the resulting formation of well defined nanosized domains provide a broad range of new materials with various properties. Block copolymers facilitated the development of innovative concepts in the fields of drug delivery, nanomedicine, organic electronics, and nanoscience. Block copolymers consist exclusively of organic polymers, but researchers are increasingly interested in materials that combine synthetic materials and biomacromolecules. Although many researchers have explored the combination of proteins with organic polymers, far fewer investigations have explored nucleic acid/polymer hybrids, known as DNA block copolymers (DBCs). DNA as a polymer block provides several advantages over other biopolymers. The availability of automated synthesis offers DNA segments with nucleotide precision, which facilitates the fabrication of hybrid materials with monodisperse biopolymer blocks. The directed functionalization of modified single-stranded DNA by Watson-Crick base-pairing is another key feature of DNA block copolymers. Furthermore, the appropriate selection of DNA sequence and organic polymer gives control over the material properties and their self-assembly into supramolecular structures. The introduction of a hydrophobic polymer into DBCs

  12. Invasion of Wolbachia at the residential block level is associated with local abundance of Stegomyia aegypti, yellow fever mosquito, populations and property attributes.

    PubMed

    Hoffmann, A A; Goundar, A A; Long, S A; Johnson, P H; Ritchie, S A

    2014-08-01

    Wolbachia can suppress dengue and control mosquito populations and this depends on the successful invasion of Wolbachia-infected mosquitoes into local populations. Ovitrap data collected during the recent invasion of wMel-infected Stegomyia aegypti (Diptera: Culicidae) (Linnaeus) into Gordonvale near Cairns, Australia, were used to identify variables that help predict the success of localized invasion. Based on the variance in Wolbachia frequencies across Gordonvale as well as at another release site at Yorkeys Knob in comparison to simulations, it was estimated that on average 2-4 females contributed eggs to an ovitrap. By collating ovitrap data from two collection periods at the start of the release from residential blocks, it was found that uninfected mosquitoes had a patchy distribution across the release site. Residential blocks with relatively high uninfected mosquito numbers were less easily invaded by Wolbachia than blocks with low numbers. The numbers of uninfected mosquitoes in ovitraps were negatively correlated with the proportion of brick houses in a residential block, whereas local Wolbachia frequencies were correlated positively with this variable as well as negatively with the amount of shading in a yard and availability of breeding sites. These findings point to proxy measures for predicting the ease of localized invasion of Wolbachia. PMID:25171611

  13. Creative Construction: Unit Blocks.

    ERIC Educational Resources Information Center

    Texas Child Care, 1999

    1999-01-01

    Describes the use of unit blocks with young children in early childhood education (ECE) settings to expand all areas of the curriculum. Discusses the origin of blocks in ECE programs, presents developmental stages of block play, describes children's building styles, and makes recommendations for getting started in block play for children of…

  14. Nanoparticles: scaffolds and building blocks.

    PubMed

    Shenhar, Roy; Rotello, Vincent M

    2003-07-01

    Nanoparticles provide key tools for bridging the gap between "bottom-up" synthetic methods and "top-down" fabrication. In this Account we describe some of the unique structural aspects of nanoparticles and the use of these attributes to the creation of devices with tunable specificity and environmental response. We also explore the use of nanoparticles as "building blocks" for the creation of nanocomposite materials that feature structural control from the molecular to the micron scale.

  15. Accountability Overboard

    ERIC Educational Resources Information Center

    Chieppo, Charles D.; Gass, James T.

    2009-01-01

    This article reports that special interest groups opposed to charter schools and high-stakes testing have hijacked Massachusetts's once-independent board of education and stand poised to water down the Massachusetts Comprehensive Assessment System (MCAS) tests and the accountability system they support. President Barack Obama and Massachusetts…

  16. Painless Accountability.

    ERIC Educational Resources Information Center

    Brown, R. W.; And Others

    The computerized Painless Accountability System is a performance objective system from which instructional programs are developed. Three main simplified behavioral response levels characterize this system: (1) cognitive, (2) psychomotor, and (3) affective domains. Each of these objectives are classified by one of 16 descriptors. The second major…

  17. Accounting Specialist.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. Center on Education and Training for Employment.

    This publication identifies 20 subjects appropriate for use in a competency list for the occupation of accounting specialist, 1 of 12 occupations within the business/computer technologies cluster. Each unit consists of a number of competencies; a list of competency builders is provided for each competency. Titles of the 20 units are as follows:…

  18. 31 CFR 500.556 - Joint bank accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Joint bank accounts. 500.556 Section..., Authorizations and Statements of Licensing Policy § 500.556 Joint bank accounts. Specific licenses are issued unblocking a portion of or all of a blocked joint bank account where a non-blocked applicant...

  19. Picture of All Solutions of Successive 2-Block Maxbet Problems

    ERIC Educational Resources Information Center

    Choulakian, Vartan

    2011-01-01

    The Maxbet method is a generalized principal components analysis of a data set, where the group structure of the variables is taken into account. Similarly, 3-block[12,13] partial Maxdiff method is a generalization of covariance analysis, where only the covariances between blocks (1, 2) and (1, 3) are taken into account. The aim of this paper is…

  20. Block copolymer investigations

    NASA Astrophysics Data System (ADS)

    Yufa, Nataliya A.

    The research presented in this thesis deals with various aspects of block copolymers on the nanoscale: their behavior at a range of temperatures, their use as scaffolds, or for creation of chemically striped surfaces, as well as the behavior of metals on block copolymers under the influence of UV light, and the healing behavior of copolymers. Invented around the time of World War II, copolymers have been used for decades due to their macroscopic properties, such as their ability to be molded without vulcanization, and the fact that, unlike rubber, they can be recycled. In recent years, block copolymers (BCPs) have been used for lithography, as scaffolds for nano-objects, to create a magnetic hard drive, as well as in photonic and other applications. In this work we used primarily atomic force microscopy (AFM) and transmission electron microscopy (TEM), described in Chapter II, to conduct our studies. In Chapter III we demonstrate a new and general method for positioning nanoparticles within nanoscale grooves. This technique is suitable for nanodots, nanocrystals, as well as DNA. We use AFM and TEM to demonstrate selective decoration. In Chapters IV and V we use AFM and TEM to study the structure of polymer surfaces coated with metals and self-assembled monolayers. We describe how the surfaces were created, exhibit their structure on the nanoscale, and prove that their macroscopic wetting properties have been altered compared to the original polymer structures. Finally, Chapters VI and VII report out in-situ AFM studies of BCP at high temperatures, made possible only recently with the invention of air-tight high-temperature AFM imaging cells. We locate the transition between disordered films and cylinders during initial ordering. Fluctuations of existing domains leading to domain coarsening are also described, and are shown to be consistent with reptation and curvature minimization. Chapter VII deals with the healing of PS-b-PMMA following AFM-tip lithography or

  1. Automatic blocking of nested loops

    NASA Technical Reports Server (NTRS)

    Schreiber, Robert; Dongarra, Jack J.

    1990-01-01

    Blocked algorithms have much better properties of data locality and therefore can be much more efficient than ordinary algorithms when a memory hierarchy is involved. On the other hand, they are very difficult to write and to tune for particular machines. The reorganization is considered of nested loops through the use of known program transformations in order to create blocked algorithms automatically. The program transformations used are strip mining, loop interchange, and a variant of loop skewing in which invertible linear transformations (with integer coordinates) of the loop indices are allowed. Some problems are solved concerning the optimal application of these transformations. It is shown, in a very general setting, how to choose a nearly optimal set of transformed indices. It is then shown, in one particular but rather frequently occurring situation, how to choose an optimal set of block sizes.

  2. A Nonlinear Multi-Scale Interaction Model for Atmospheric Blocking: The Eddy-Blocking Matching Mechanism

    NASA Astrophysics Data System (ADS)

    Luo, Dehai; Cha, Jing; Zhong, Linhao; Dai, Aiguo

    2014-05-01

    In this paper, a nonlinear multi-scale interaction (NMI) model is used to propose an eddy-blocking matching (EBM) mechanism to account for how synoptic eddies reinforce or suppress a blocking flow. It is shown that the spatial structure of the eddy vorticity forcing (EVF) arising from upstream synoptic eddies determines whether an incipient block can grow into a meandering blocking flow through its interaction with the transient synoptic eddies from the west. Under certain conditions, the EVF exhibits a low-frequency oscillation on timescales of 2-3 weeks. During the EVF phase with a negative-over- positive dipole structure, a blocking event can be resonantly excited through the transport of eddy energy into the incipient block by the EVF. As the EVF changes into an opposite phase, the blocking decays. The NMI model produces life cycles of blocking events that resemble observations. Moreover, it is shown that the eddy north-south straining is a response of the eddies to a dipole- or Ω-type block. In our model, as in observations, two synoptic anticyclones (cyclones) can attract and merge with one another as the blocking intensifies, but only when the feedback of the blocking on the eddies is included. Thus, we attribute the eddy straining and associated vortex interaction to the feedback of the intensified blocking on synoptic eddies. The results illustrate the concomitant nature of the eddy deformation, whose role as a PV source for the blocking flow becomes important only during the mature stage of a block. Our EBM mechanism suggests that an incipient block flow is amplified (or suppressed) under certain conditions by the EVF coming from the upstream of the blocking region.

  3. Blocking Losses on an Optical Communications Link

    NASA Technical Reports Server (NTRS)

    Moision, Bruce; Piazzolla, Sabino

    2011-01-01

    Many photon-counting photo-detectors have the property that they become inoperative for some time after detection event. We say the detector is blocked during this time.Blocking produces losses when using the detector as a photon-counter to detect a communications signal. In this paper, we characterize blocking losses for single detectors and for arrays of detectors. For arrays, we discuss conditions under which the output may be approximated as a Poisson point process, and provide a simple approximation to the blocking loss. We show how to extend the analysis to arrays of non-uniformly illuminated arrays.

  4. Learning with Large Blocks.

    ERIC Educational Resources Information Center

    Cartwright, Sally

    1990-01-01

    Discusses how large hollow blocks can meet many preschool children's learning needs through creative dramatic play, and also gives some guidelines on how these blocks can be constructed by parents and teachers. (BB)

  5. Block That Pain!

    MedlinePlus

    ... combination produces a unique effect, blocking pain-sensing neurons without impairing signals from other cells. In contrast, ... surgical procedures block activity in all types of neurons. This can cause numbness, paralysis, and other nervous ...

  6. 26 CFR 1.468B-6 - Escrow accounts, trusts, and other funds used during deferred exchanges of like-kind property...

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... exchange with R. The sales agreement provides that T will transfer property (the relinquished property) to R and R will transfer replacement property to T. R's obligation to transfer replacement property to T is secured by cash equal to the fair market value of the relinquished property, which R...

  7. Block Scheduling. Research Brief

    ERIC Educational Resources Information Center

    Muir, Mike

    2003-01-01

    What are the effects of block scheduling? Results of transitioning from traditional to block scheduling are mixed. Some studies indicate no change in achievement results, nor change in teachers' opinions about instructional strategies. Other studies show that block scheduling doesn't work well for Advanced Placement or Music courses, that "hard to…

  8. Block LU factorization

    NASA Technical Reports Server (NTRS)

    Demmel, James W.; Higham, Nicholas J.; Schreiber, Robert S.

    1992-01-01

    Many of the currently popular 'block algorithms' are scalar algorithms in which the operations have been grouped and reordered into matrix operations. One genuine block algorithm in practical use is block LU factorization, and this has recently been shown by Demmel and Higham to be unstable in general. It is shown here that block LU factorization is stable if A is block diagonally dominant by columns. Moreover, for a general matrix the level of instability in block LU factorization can be founded in terms of the condition number kappa(A) and the growth factor for Gaussian elimination without pivoting. A consequence is that block LU factorization is stable for a matrix A that is symmetric positive definite or point diagonally dominant by rows or columns as long as A is well-conditioned.

  9. 31 CFR 500.558 - Accounts of blocked partnerships.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... are issued unblocking partnerships established under the laws of North Korea, North Viet-Nam, Cambodia, or South Viet-Nam, as follows: (a) Where all of the general partners and limited partners, if any, have emigrated from North Korea, North Viet-Nam, Cambodia, or South Viet-Nam and have...

  10. Juvenile Accountability Block Grants Program Reauthorization Act of 2013

    THOMAS, 113th Congress

    Rep. Scott, Robert C. "Bobby" [D-VA-3

    2013-06-13

    07/15/2013 Referred to the Subcommittee on Crime, Terrorism, Homeland Security, and Investigations. (All Actions) Tracker: This bill has the status IntroducedHere are the steps for Status of Legislation:

  11. Functionalized block copolymers as adhesion promoters

    SciTech Connect

    Kent, M.S.; Saunders, R.

    1995-03-01

    The goal of this work is to develop novel functionalized block copolymers to promote adhesion at inorganic substrate/polymer interfaces. We envision several potential advantages of functionalized block copolymers over small molecule coupling agents. Greater control over the structure of the interphase region should result through careful design of the backbone of the copolymer. The number of chains per area, the degree of entanglement between the copolymer and the polymer matrix, the number of sites per chain able to attach to the substrate, and the hydrophobicity of the interphase region can all be strongly affected by the choice of block lengths and the monomer sequence. In addition, entanglement between the copolymer and the polymer matrix, if achieved, should contribute significantly to adhesive strength. Our program involves four key elements: the synthesis of suitable functionalized block copolymers, characterization of the conformation of the copolymers at the interface by neutron reflectivity and atomic force microscopy, characterization of the degree of bonding by spectroscopy, and measurement of the mechanical properties of the interface. In this paper we discuss block copolymers designed as adhesion promoters for the copper/epoxy interface. We have synthesized a diblock with one block containing imidazole groups to bond to copper and a second block containing secondary amines to react with the epoxy matrix. We have also prepared a triblock copolymer containing a hydrophobic middle block. Below we describe the synthesis of the block copolymers by living, ring-opening metathesis polymerization (ROMP) and the first characterization data obtained by neutron reflectivity.

  12. The self-assembly of copolymers with one hydrophobic and one polyelectrolyte block in aqueous media: a dissipative particle dynamics study.

    PubMed

    Lísal, Martin; Limpouchová, Zuzana; Procházka, Karel

    2016-06-28

    The reversible self-assembly of symmetrical block copolymers consisting of one hydrophobic block and one ionizable polyelectrolyte block of the same length has been studied in aqueous solutions by dissipative particle dynamics simulations. In addition to three standard dissipative particle dynamics forces (conservative soft repulsion, dissipative and stochastic forces), explicit interaction between smeared charges on ions and on ionized polymer beads described by the electrostatic potential with appropriately localized charges was taken into account. The self-assembly and properties of formed core-shell micelles were investigated as functions of the degree of ionization for systems differing in the hydrophobicity of the non-ionized polyelectrolyte block and in the compatibility of the polymer blocks. This study shows that micelles undergo massive dissociation with increasing degree of ionization. The simulation data compare well with the predictions of scaling theories for systems with soluble polyelectrolytes on a semi-quantitative level and broaden the knowledge of systems in poor solvents. PMID:27254381

  13. The self-assembly of copolymers with one hydrophobic and one polyelectrolyte block in aqueous media: a dissipative particle dynamics study.

    PubMed

    Lísal, Martin; Limpouchová, Zuzana; Procházka, Karel

    2016-06-28

    The reversible self-assembly of symmetrical block copolymers consisting of one hydrophobic block and one ionizable polyelectrolyte block of the same length has been studied in aqueous solutions by dissipative particle dynamics simulations. In addition to three standard dissipative particle dynamics forces (conservative soft repulsion, dissipative and stochastic forces), explicit interaction between smeared charges on ions and on ionized polymer beads described by the electrostatic potential with appropriately localized charges was taken into account. The self-assembly and properties of formed core-shell micelles were investigated as functions of the degree of ionization for systems differing in the hydrophobicity of the non-ionized polyelectrolyte block and in the compatibility of the polymer blocks. This study shows that micelles undergo massive dissociation with increasing degree of ionization. The simulation data compare well with the predictions of scaling theories for systems with soluble polyelectrolytes on a semi-quantitative level and broaden the knowledge of systems in poor solvents.

  14. Island custom blocking technique

    SciTech Connect

    Carabetta, R.J. )

    1988-03-01

    The technique of Island blocking is being used more frequently since the advent of our new head and neck blocking techniques and the implementation of a newly devised lung protocol. The system presented affords the mould room personnel a quick and accurate means of island block fabrication without the constant remeasuring or subtle shifting to approximate correct placement. The cookie cutter is easily implemented into any department's existing block cutting techniques. The device is easily and inexpensively made either in a machine shop or acquired by contacting the author.

  15. Precision synthesis of poly(ionic liquid)-based block copolymers by cobalt-mediated radical polymerization and preliminary study of their self-assembling properties.

    PubMed

    Coupillaud, Paul; Fèvre, Maréva; Wirotius, Anne-Laure; Aissou, Karim; Fleury, Guillaume; Debuigne, Antoine; Detrembleur, Christophe; Mecerreyes, David; Vignolle, Joan; Taton, Daniel

    2014-02-01

    A poly(ionic liquid)-based block copolymer (PIL BCP), namely, poly(vinyl acetate)-b-poly(N-vinyl-3-butylimidazolium bromide), PVAc-b-PVBuImBr, is synthesized by sequential cobalt-mediated radical polymerization (CMRP). A PVAc precursor is first prepared at 30 °C in bulk by CMRP of VAc, using bis(acetylacetonato)cobalt(II), Co(acac)2, and a radical source (V-70). Growth of PVBuImBr from PVAc-Co(acac)2 is accomplished by CMRP in DMF/MeOH (2:1, v/v). This PIL BCP self-assembles in the sub-micron size range into aggregated core-shell micelles in THF, whereas polymeric vesicles are observed in water, as evidenced by dynamic light scattering (DLS) and transmission electron microscopy (TEM). Thin-solid sample cut from raw materials analyzed by TEM shows an ordered lamellar organization by temperature-dependent synchrotron small-angle X-ray scattering (SAXS). Anion exchange can be accomplished to achieve the corresponding PIL BCP with bis(trifluorosulfonyl)imide (Tf2 N(-)) anions, which also gives rise to an ordered lamellar phase in bulk samples. A complete suppression of SAXS second-order reflection suggests that this compound has a symmetric volume fraction (f ≈ 0.5). SAXS characterization of both di- and triblock PIL BCP analogues previously reported also shows a lamellar phase of very similar behavior, with only an increase of the period by about 8% at 60 °C.

  16. The role of water on the structure and mechanical properties of a thermoplastic natural block co-polymer from squid sucker ring teeth.

    PubMed

    Rieu, Clément; Bertinetti, Luca; Schuetz, Roman; Salinas-Zavala, Cesar Ca; Weaver, James C; Fratzl, Peter; Miserez, Ali; Masic, Admir

    2016-01-01

    Hard biological polymers exhibiting a truly thermoplastic behavior that can maintain their structural properties after processing are extremely rare and highly desirable for use in advanced technological applications such as 3D-printing, biodegradable plastics and robust composites. One exception are the thermoplastic proteins that comprise the sucker ring teeth (SRT) of the Humboldt jumbo squid (Dosidicus gigas). In this work, we explore the mechanical properties of reconstituted SRT proteins and demonstrate that the material can be re-shaped by simple processing in water and at relatively low temperature (below 100 °C). The post-processed material maintains a high modulus in the GPa range, both in the dry and the wet states. When transitioning from low to high humidity, the material properties change from brittle to ductile with an increase in plastic deformation, where water acts as a plasticizer. Using synchrotron x-ray scattering tools, we found that water mostly influences nano scale structure, whereas at the molecular level, the protein structure remains largely unaffected. Furthermore, through simultaneous in situ x-ray scattering and mechanical tests, we show that the supramolecular network of the reconstituted SRT material exhibits a progressive alignment along the strain direction, which is attributed to chain alignment of the amorphous domains of SRT proteins. The high modulus in both dry and wet states, combined with their efficient thermal processing characteristics, make the SRT proteins promising substitutes for applications traditionally reserved for petroleum-based thermoplastics. PMID:27588938

  17. The role of water on the structure and mechanical properties of a thermoplastic natural block co-polymer from squid sucker ring teeth.

    PubMed

    Rieu, Clément; Bertinetti, Luca; Schuetz, Roman; Salinas-Zavala, Cesar Ca; Weaver, James C; Fratzl, Peter; Miserez, Ali; Masic, Admir

    2016-09-02

    Hard biological polymers exhibiting a truly thermoplastic behavior that can maintain their structural properties after processing are extremely rare and highly desirable for use in advanced technological applications such as 3D-printing, biodegradable plastics and robust composites. One exception are the thermoplastic proteins that comprise the sucker ring teeth (SRT) of the Humboldt jumbo squid (Dosidicus gigas). In this work, we explore the mechanical properties of reconstituted SRT proteins and demonstrate that the material can be re-shaped by simple processing in water and at relatively low temperature (below 100 °C). The post-processed material maintains a high modulus in the GPa range, both in the dry and the wet states. When transitioning from low to high humidity, the material properties change from brittle to ductile with an increase in plastic deformation, where water acts as a plasticizer. Using synchrotron x-ray scattering tools, we found that water mostly influences nano scale structure, whereas at the molecular level, the protein structure remains largely unaffected. Furthermore, through simultaneous in situ x-ray scattering and mechanical tests, we show that the supramolecular network of the reconstituted SRT material exhibits a progressive alignment along the strain direction, which is attributed to chain alignment of the amorphous domains of SRT proteins. The high modulus in both dry and wet states, combined with their efficient thermal processing characteristics, make the SRT proteins promising substitutes for applications traditionally reserved for petroleum-based thermoplastics.

  18. Rapid self-assembly of block copolymers to photonic crystals

    DOEpatents

    Xia, Yan; Sveinbjornsson, Benjamin R; Grubbs, Robert H; Weitekamp, Raymond; Miyake, Garret M; Atwater, Harry A; Piunova, Victoria; Daeffler, Christopher Scot; Hong, Sung Woo; Gu, Weiyin; Russell, Thomas P.

    2016-07-05

    The invention provides a class of copolymers having useful properties, including brush block copolymers, wedge-type block copolymers and hybrid wedge and polymer block copolymers. In an embodiment, for example, block copolymers of the invention incorporate chemically different blocks comprising polymer size chain groups and/or wedge groups that significantly inhibit chain entanglement, thereby enhancing molecular self-assembly processes for generating a range of supramolecular structures, such as periodic nanostructures and microstructures. The present invention also provides useful methods of making and using copolymers, including block copolymers.

  19. High power thyristors with 5 kV blocking voltage. Volume 1: Development of high-voltage-thyristors (4.5 kV) with good dynamic properties

    NASA Technical Reports Server (NTRS)

    Lock, K.; Patalong, H.; Platzoeder, K.

    1979-01-01

    Using neutron irradiated silicon with considerably lower spread in resistivity as compared to conventionally doped silicon it was possible to produce power thyristors with breakdown voltages between 3.5 kV and 5.5 kV. The thyristor pellets have a diameter of 50 mm. Maximum average on-state currents of 600 to 800 A can be reached with these elements. The dynamic properties of the thryistors could be improved to allow standard applications up to maximum repetitive voltages of 4.5 kV.

  20. Congenital complete atrioventricular block.

    PubMed Central

    Kertesz, N J; Fenrich, A L; Friedman, R A

    1997-01-01

    Congenital complete atrioventricular block is found in 1 of 22,000 live births. Over time, it has become apparent that these patients represent not a single distinct disease process, but several processes with the common manifestation of atrioventricular block. The evaluation of these patients to determine their risk of sudden death and need for pacing is not well defined. Images PMID:9456483

  1. High Relief Block Printing.

    ERIC Educational Resources Information Center

    Foster, Michael

    1989-01-01

    Explains a method of block printing using styrofoam shapes to make high relief. Describes the creation of the block design as well as the actual printing process. Uses a range of paper types for printing so children can see the results of using different media. (LS)

  2. Surviving Block Scheduling.

    ERIC Educational Resources Information Center

    Haley, Marjorie

    A discussion of block scheduling for second language instruction looks at the advantages and disadvantages and offers some suggestions for classroom management and course organization. It is argued that block scheduling may offer a potential solution to large classes, insufficient time for labs, too little individualized instruction; few…

  3. Thermally actuated wedge block

    DOEpatents

    Queen, Jr., Charles C.

    1980-01-01

    This invention relates to an automatically-operating wedge block for maintaining intimate structural contact over wide temperature ranges, including cryogenic use. The wedging action depends on the relative thermal expansion of two materials having very different coefficients of thermal expansion. The wedge block expands in thickness when cooled to cryogenic temperatures and contracts in thickness when returned to room temperature.

  4. Development of Alkali Activated Geopolymer Masonry Blocks

    NASA Astrophysics Data System (ADS)

    Venugopal, K.; Radhakrishna; Sasalatti, Vinod

    2016-09-01

    Cement masonry units are not considered as sustainable since their production involves consumption of fuel, cement and natural resources and therefore it is essential to find alternatives. This paper reports on making of geopolymer solid & hollow blocks and masonry prisms using non conventional materials like fly ash, ground granulated blast furnace slag (GGBFS) and manufactured sand and curing at ambient temperature. They were tested for water absorption, initial rate of water absorption, dry density, dimensionality, compressive, flexural and bond-strength which were tested for bond strength with and without lateral confinement, modulus of elasticity, alternative drying & wetting and masonry efficiency. The properties of geopolymer blocks were found superior to traditional masonry blocks and the masonry efficiency was found to increase with decrease in thickness of cement mortar joints. There was marginal difference in strength between rendered and unrendered geopolymer masonry blocks. The percentage weight gain after 7 cycles was less than 6% and the percentage reduction in strength of geopolymer solid blocks and hollow blocks were 26% and 28% respectively. Since the properties of geopolymer blocks are comparatively better than the traditional masonry they can be strongly recommended for structural masonry.

  5. Multi-level block permutation

    PubMed Central

    Winkler, Anderson M.; Webster, Matthew A.; Vidaurre, Diego; Nichols, Thomas E.; Smith, Stephen M.

    2015-01-01

    Under weak and reasonable assumptions, mainly that data are exchangeable under the null hypothesis, permutation tests can provide exact control of false positives and allow the use of various non-standard statistics. There are, however, various common examples in which global exchangeability can be violated, including paired tests, tests that involve repeated measurements, tests in which subjects are relatives (members of pedigrees) — any dataset with known dependence among observations. In these cases, some permutations, if performed, would create data that would not possess the original dependence structure, and thus, should not be used to construct the reference (null) distribution. To allow permutation inference in such cases, we test the null hypothesis using only a subset of all otherwise possible permutations, i.e., using only the rearrangements of the data that respect exchangeability, thus retaining the original joint distribution unaltered. In a previous study, we defined exchangeability for blocks of data, as opposed to each datum individually, then allowing permutations to happen within block, or the blocks as a whole to be permuted. Here we extend that notion to allow blocks to be nested, in a hierarchical, multi-level definition. We do not explicitly model the degree of dependence between observations, only the lack of independence; the dependence is implicitly accounted for by the hierarchy and by the permutation scheme. The strategy is compatible with heteroscedasticity and variance groups, and can be used with permutations, sign flippings, or both combined. We evaluate the method for various dependence structures, apply it to real data from the Human Connectome Project (HCP) as an example application, show that false positives can be avoided in such cases, and provide a software implementation of the proposed approach. PMID:26074200

  6. Nanostructured particles from multi scale building blocks

    NASA Astrophysics Data System (ADS)

    Hampsey, J. Eric

    Nanotechnology has emerged as one of the most exciting new and developing fields in science today. New nanoscale materials and devices such as nanoparticles, nanocomposites, nanowires, and nanosensors could revolutionize the 21st century in the same way that the transistor and Internet led to the information age. One key component in developing these new technologies is to assemble individual atomic and molecular building blocks into larger structures with fundamentally new properties and functions. Nature is very efficient at assembling multi scale building blocks such as proteins, lipids, and minerals into nanostructured materials such as bone, teeth, diatoms, eggshells, seashells, cell membranes, and DNA. Surfactant and colloidal building block can also be assembled into different nanoscale materials and devices by utilizing hydrophobic/hydrophilic and other surface interactions. Using these concepts, this dissertation focuses on the syntheses and applications of nanostructured particles assembled from multi scale building blocks. Important factors in the synthesis of the particles include particle size, particle morphology, pore size and pore structure. Five different types of nanostructured particles assembled from different multi scale building blocks are demonstrated in this work: (1) Spherical metal/silica mesoporous particles with high surface areas and controllable pore sizes, pore structures, and metal content are synthesized from surfactant, silicate, and metal building blocks for catalytic applications; (2) Mesoporous hollow spheres with controllable pore sizes and pore structures are synthesized from surfactant, silica, and polystyrene building blocks; (3) Spherical mesoporous carbon particles with controllable pore sizes and pore structures are templated from silica particles assembled from silica and surfactant building blocks; (4) Spherical mesoporous, microporous, and bimodal carbon particles are synthesized from sucrose and silica building blocks

  7. Benzodipyrrolidone (BDP)-based polymer semiconductors containing a series of chalcogen atoms: comprehensive investigation of the effect of heteroaromatic blocks on intrinsic semiconducting properties.

    PubMed

    Lee, Kyu Cheol; Park, Won-Tae; Noh, Yong-Young; Yang, Changduk

    2014-04-01

    In order to determine the effects of actual 'chalcogen atoms' on semiconducting properties for application in a variety of optoelectronic devices, a class of donor (D)-acceptor (A) polymer semiconductors, namely PBDP-Fu, PBDP-Th, and PBDP-Se, containing the recently formulated benzodipyrrolidone (BDP) accepting unit and furan (Fu), thiophene (Th), or selenophene (Se) as a donating unit has been synthesized, characterized, and used in an active layer of organic field-effect transistors (OFETs). With the LUMO levels being comparatively consistent for all three polymers (-3.58 to -3.60 eV) due to the dominant BDP contribution to the polymer backbone, the HOMO energies are somewhat sensitive to the structurally distinctive feature of the donor counits used. Utilizing a combination of X-ray diffraction (XRD) and atomic force microscopy (AFM), it is apparent that further crystalline domains occur with edge-on orientation for the polymers (PBDP-Th and PBDP-Se) with relatively heavier chalcogen atoms such as Th and Se, compared with PBDP-Fu which has a rather amorphous nature. Investigation of their OFET performance indicates that all the polymers show well balanced ambipolar operations. The desirable morphological structures of both the PBDP-Th and PBDP-Se result in higher mobilities in OFETs than those of PBDP-Fu. In particular, 200 °C annealed PBDP-Se OFETs results in ambipolarity being mobile for both holes of up to 1.7 × 10(-2) cm(2)/V·s and electrodes of up to 1.9 × 10(-2) cm(2)/V·s. In addition, OFETs with PBDP-Th show nearly equivalent charge carrier mobilities for both holes (μ(h) = 1.2 × 10(-2) cm(2)/V·s) and electrons (μ(e) = 1.1 × 10(-2) cm(2)/V·s). Consequently, we systematically demonstrate how the manipulation of existing heteroaromatics can modulate the electronic properties of conjugated D-A polymers, elucidating structure-property relationships that are desirable for the rational design of next generation materials. PMID:24620709

  8. Light extraction block with curved surface

    DOEpatents

    Levermore, Peter; Krall, Emory; Silvernail, Jeffrey; Rajan, Kamala; Brown, Julia J.

    2016-03-22

    Light extraction blocks, and OLED lighting panels using light extraction blocks, are described, in which the light extraction blocks include various curved shapes that provide improved light extraction properties compared to parallel emissive surface, and a thinner form factor and better light extraction than a hemisphere. Lighting systems described herein may include a light source with an OLED panel. A light extraction block with a three-dimensional light emitting surface may be optically coupled to the light source. The three-dimensional light emitting surface of the block may includes a substantially curved surface, with further characteristics related to the curvature of the surface at given points. A first radius of curvature corresponding to a maximum principal curvature k.sub.1 at a point p on the substantially curved surface may be greater than a maximum height of the light extraction block. A maximum height of the light extraction block may be less than 50% of a maximum width of the light extraction block. Surfaces with cross sections made up of line segments and inflection points may also be fit to approximated curves for calculating the radius of curvature.

  9. The first bis-cyanoxime: synthesis and properties of a new versatile and accessible polydentate bifunctional building block for coordination and supramolecular chemistry.

    PubMed

    Cheadle, Carl; Gerasimchuk, Nikolay; Barnes, Charles L; Tyukhtenko, Sergiy I; Silchenko, Svitlana

    2013-04-14

    , >2.89 Å, mostly electrostatic Tl···O contacts, involving oxygen atoms of the amide-group and the oxime-group of neighboring units. Among several possible binding modes, the coordination of the bis-cyanoxime dianion of 2 adopted in complex 4 is unusual, and evidenced its great potential as a versatile building block for coordination and supramolecular chemistry.

  10. Characterization of blocked isocyanates

    NASA Astrophysics Data System (ADS)

    Mirčeva, A.; Janežič, M.; Žigon, M.; Malavašič, T.

    1992-03-01

    An ionomer crosslinker on the basis of partly blocked hexamethylene isocyanurate was synthesized and characterized by FTIR and NMR spectroscopy and by gel permeation chromatography. To determine the selectivity of the blocking reaction. model compounds were also prepared. Deblocking and curing courses were studied by FTIR thermal methods. The selectivity of the blocking reaction was found to be poor and therefore the obtained ionomer crosslinker consisted of different monomer and oligomer components. Deblocking and curing were highly temperature dependent. Curing was more efficient in one-pack systems consisting of the ionomer crosslinker and of an OH groups rich ionomer polyurethane resin.

  11. Effect of size of TiO2 nanoparticles embedded into stratum corneum on ultraviolet-A and ultraviolet-B sun-blocking properties of the skin.

    PubMed

    Popov, Alexey P; Lademann, Jürgen; Priezzhev, Alexander V; Myllylä, Risto

    2005-01-01

    Recently there has been a strong demand to protect human skin against negative effects of the UV solar light. This problem is interesting due to the increased frequency of human diseases caused by such radiation. We aim to evaluate how the optical properties of the horny layer of skin can be effectively changed by imbedding TiO2 fine particles to achieve the maximal attenuation of the UV solar radiation. In-depth distribution of TiO2 particles embedded into the skin by multiple administration of sunscreens is determined experimentally using the tape-stripping technique. A computer code implementing the Monte Carlo method is developed to simulate photon migration within the 20-microm-thick horny layer filled with nanosized TiO2 spheres, 25 to 200 nm in diameter. Dependencies of the UV radiation of two wavelengths (310 and 400 nm) absorbed by and totally reflected from, as well as transmitted through the horny layer on the size of TiO2 particles are obtained and analyzed. The most attenuating particles are found to be 62 and 122 nm in diameter for 310- and 400-nm light, respectively. The former could be suggested as the main fraction to be used in sunscreens to prevent erythema.

  12. In vitro anticancer activity of docetaxel-loaded micelles based on poly(ethylene oxide)-poly(epsilon-caprolactone) block copolymers: Do nanocarrier properties have a role?

    PubMed

    Ostacolo, Luisanna; Marra, Monica; Ungaro, Francesca; Zappavigna, Silvia; Maglio, Giovanni; Quaglia, Fabiana; Abbruzzese, Alberto; Caraglia, Michele

    2010-12-01

    In this paper we have investigated the behavior of core-shell poly(ethylene oxide)-poly(epsilon-caprolactone) (PEO-PCL) micelles derived from copolymers with linear triblock (TR) and 4-arm star-diblock (ST) architectures for the delivery of docetaxel (DTX). DTX was loaded inside micelles (DTX-TR(m) and DTX-ST(m)) with high efficiency and released slowly for more than two weeks. DTX-loaded micelles based on both copolymers had very similar properties in terms of mean size, zeta potential, loading ability and release rate in buffered saline. However, the stability of DTX-ST(m) was very poor in aqueous media with proteins resulting in a strong and progressive aggregation. We studied the effect of increasing concentrations of free DTX or DTX-loaded micelles on growth inhibition of human breast MCF-7 and MDA-MB468 and prostate PC3 and DU145 adenocarcinoma cell lines. DTX-loaded TR micelles induced cell growth inhibition similarly to free DTX whereas DTX-ST(m) showed lower cytotoxicity. On the other hand, by normalizing IC(50) values for the actual amount of DTX released from micelles in the medium, DTX-loaded ST micelles became more active than free DTX in all cell lines tested. Both free DTX and DTX-loaded TR micelles displayed a significantly lower cytotoxic activity in G(2)/M phase synchronized cells, whereas cytotoxicity of DTX-loaded ST micelles did not change. Cytotoxicity was related to micelle stability, uptake and release rate in cell culture media. Our results suggest that for a correct interpretation of cytotoxicity of nanocarriers, the evaluation of their behavior in biologically relevant conditions is of utmost importance to select proper systems for further in vivo testing.

  13. Optoelectronics using block copolymers.

    SciTech Connect

    Botiz, I.; Darling, S. B.; Center for Nanoscale Materials

    2010-05-01

    Block copolymers, either as semiconductors themselves or as structure directors, are emerging as a promising class of materials for understanding and controlling processes associated with both photovoltaic energy conversion and light emitting devices.

  14. Resolving writer's block.

    PubMed Central

    Huston, P.

    1998-01-01

    PROBLEM BEING ADDRESSED: Writer's block, or a distinctly uncomfortable inability to write, can interfere with professional productivity. OBJECTIVE OF PROGRAM: To identify writer's block and to outline suggestions for its early diagnosis, treatment, and prevention. MAIN COMPONENTS OF PROGRAM: Once the diagnosis has been established, a stepwise approach to care is recommended. Mild blockage can be resolved by evaluating and revising expectations, conducting a task analysis, and giving oneself positive feedback. Moderate blockage can be addressed by creative exercises, such as brainstorming and role-playing. Recalcitrant blockage can be resolved with therapy. Writer's block can be prevented by taking opportunities to write at the beginning of projects, working with a supportive group of people, and cultivating an ongoing interest in writing. CONCLUSIONS: Writer's block is a highly treatable condition. A systematic approach can help to alleviate anxiety, build confidence, and give people the information they need to work productively. PMID:9481467

  15. Blocked tear duct

    MedlinePlus

    ... your baby may have an eye infection called conjunctivitis . ... increase the chance of other infections, such as conjunctivitis. ... be prevented. Proper treatment of nasal infections and conjunctivitis may reduce the risk of having a blocked ...

  16. Block copolymer battery separator

    DOEpatents

    Wong, David; Balsara, Nitash Pervez

    2016-04-26

    The invention herein described is the use of a block copolymer/homopolymer blend for creating nanoporous materials for transport applications. Specifically, this is demonstrated by using the block copolymer poly(styrene-block-ethylene-block-styrene) (SES) and blending it with homopolymer polystyrene (PS). After blending the polymers, a film is cast, and the film is submerged in tetrahydrofuran, which removes the PS. This creates a nanoporous polymer film, whereby the holes are lined with PS. Control of morphology of the system is achieved by manipulating the amount of PS added and the relative size of the PS added. The porous nature of these films was demonstrated by measuring the ionic conductivity in a traditional battery electrolyte, 1M LiPF.sub.6 in EC/DEC (1:1 v/v) using AC impedance spectroscopy and comparing these results to commercially available battery separators.

  17. Cell block eleven (left) and cell block fifteen, looking from ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Cell block eleven (left) and cell block fifteen, looking from cell block two into the "Death Row" exercise yard - Eastern State Penitentiary, 2125 Fairmount Avenue, Philadelphia, Philadelphia County, PA

  18. View of cell block eight (left), cell block seven, and ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View of cell block eight (left), cell block seven, and southwest guard tower, looking from cell block eight roof - Eastern State Penitentiary, 2125 Fairmount Avenue, Philadelphia, Philadelphia County, PA

  19. Exploring the influence of the poly(4-vinyl pyridine) segment on the solution properties and thermal phase behaviours of oligo(ethylene glycol) methacrylate-based block copolymers: the different aggregation processes with various morphologies.

    PubMed

    Dai, Yalan; Wu, Peiyi

    2016-08-01

    The assembly properties, thermal phase behavior and microdynamics of well-defined P(MEO2MA-co-OEGMA)-b-P4VP, (poly(2-(2-methoxyethoxy)ethylmethacrylate)-co-poly(oligo(ethylene glycol) methacrylate))-b-poly(4-vinyl pyridine), in aqueous solution during heating are investigated in detail by dynamic light scattering (DLS), turbidity measurements, temperature-variable (1)H NMR and FTIR spectroscopy in combination with two-dimensional correlation spectroscopy (2Dcos) and the perturbation correlation moving window (PCMW) technique. It is observed that the chain length of the relatively hydrophobic P4VP segment strongly affects the temperature-induced phase transition behavior of the block copolymers: the copolymers with shorter P4VP7/10 segments exhibit an abrupt phase transition process, while the copolymer with longer P4VP19 blocks presents a relatively gradual transition behavior. Moreover, the two systems with different P4VP segment lengths have different morphologies in aqueous solution: a single-chain globule for shorter P4VP7/10 systems and a core-shell micelle consisting of a relatively hydrophobic P4VP core and a hydrophilic POEGMA-based shell for the longer P4VP19 system. Analysis of spectral results clearly illustrates that the dehydration of the C[double bond, length as m-dash]O groups at the linkages between backbones and pendant chains predominates the sharp phase transition of P(MEO2MA-co-OEGMA)-b-P4VP10, while the dehydration of hydrophobic C-H groups on the side chains in P(MEO2MA-co-OEGMA)-b-P4VP19 leads to the continuous increase of the hydrodynamic diameter (Dh) upon heating. PMID:27425657

  20. Superalloy Lattice Block Structures

    NASA Technical Reports Server (NTRS)

    Whittenberger, J. D.; Nathal, M. V.; Hebsur, M. G.; Kraus, D. L.

    2003-01-01

    In their simplest form, lattice block panels are produced by direct casting and result in lightweight, fully triangulated truss-like configurations which provide strength and stiffness [2]. The earliest realizations of lattice block were made from A1 and steels, primarily under funding from the US Navy [3]. This work also showed that the mechanical efficiency (eg., specific stiffness) of lattice block structures approached that of honeycomb structures [2]. The lattice architectures are also less anisotropic, and the investment casting route should provide a large advantage in cost and temperature capability over honeycombs which are limited to alloys that can be processed into foils. Based on this early work, a program was initiated to determine the feasibility of extending the high temperature superalloy lattice block [3]. The objective of this effort was to provide an alternative to intermetallics and composites in achieving a lightweight high temperature structure without sacrificing the damage tolerance and moderate cost inherent in superalloys. To establish the feasibility of the superalloy lattice block concept, work was performed in conjunction with JAMCORP, Inc. Billerica, MA, to produce a number of lattice block panels from both IN71 8 and Mar-M247.

  1. Growing Up with Their Blocks.

    ERIC Educational Resources Information Center

    Winarski, Diana L.

    1995-01-01

    Describes one teacher's use of traditional wooden blocks in fifth-grade curriculum. Notes that use of blocks can teach communication, teamwork, precision, and arithmetic concepts. Also describes four easy classroom block projects. (TM)

  2. Block Coloplyer Nanoreactors for Inorganic Cluster Synthesis

    NASA Astrophysics Data System (ADS)

    Cohen, Robert E.

    1997-03-01

    We have generalized our work on the spatial confinement of inorganic clusters in block copolymers to a nanoreactor scheme for cluster synthesis. Using this new methodology, a wide range of inorganic clusters can be synthesized from a single block copolymer starting material. Metals are selectively sequestered into domains of the heterogeneous block copolymer morphology, either from aqueous solutions of suitably chosen salts or via vapor permeation of organometallic compounds. Once "loaded", these metal-containing domains serve as localized reaction sites for cluster synthesis. The metal-sequestering sites are rejuvenated, rendering the nanoreactors capable of being reloaded with more of the same metal, or another, for further cluster synthesis. Magnetic and optical properties of free-standing block copolymer films containing various types of nanoclusters will be discussed.

  3. Atmospheric Blocking and Atlantic Multidecadal Ocean Variability

    NASA Technical Reports Server (NTRS)

    Hakkinen, Sirpa; Rhines, Peter B.; Worthen, Denise L.

    2011-01-01

    Atmospheric blocking over the northern North Atlantic, which involves isolation of large regions of air from the westerly circulation for 5 days or more, influences fundamentally the ocean circulation and upper ocean properties by affecting wind patterns. Winters with clusters of more frequent blocking between Greenland and western Europe correspond to a warmer, more saline subpolar ocean. The correspondence between blocked westerly winds and warm ocean holds in recent decadal episodes (especially 1996 to 2010). It also describes much longer time scale Atlantic multidecadal ocean variability (AMV), including the extreme pre-greenhouse-gas northern warming of the 1930s to 1960s. The space-time structure of the wind forcing associated with a blocked regime leads to weaker ocean gyres and weaker heat exchange, both of which contribute to the warm phase of AMV.

  4. 31 CFR 515.551 - Joint bank accounts.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Joint bank accounts. 515.551 Section..., Authorizations, and Statements of Licensing Policy § 515.551 Joint bank accounts. (a) Specific licenses are issued unblocking a portion of or all of a joint bank account blocked by reason of the fact that one...

  5. 31 CFR 515.551 - Joint bank accounts.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Joint bank accounts. 515.551 Section..., Authorizations, and Statements of Licensing Policy § 515.551 Joint bank accounts. (a) Specific licenses are issued unblocking a portion of or all of a joint bank account blocked by reason of the fact that one...

  6. 31 CFR 515.551 - Joint bank accounts.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Joint bank accounts. 515.551 Section..., Authorizations, and Statements of Licensing Policy § 515.551 Joint bank accounts. (a) Specific licenses are issued unblocking a portion of or all of a joint bank account blocked by reason of the fact that one...

  7. 31 CFR 515.551 - Joint bank accounts.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Joint bank accounts. 515.551 Section..., Authorizations, and Statements of Licensing Policy § 515.551 Joint bank accounts. (a) Specific licenses are issued unblocking a portion of or all of a joint bank account blocked by reason of the fact that one...

  8. 31 CFR 515.551 - Joint bank accounts.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Joint bank accounts. 515.551 Section..., Authorizations, and Statements of Licensing Policy § 515.551 Joint bank accounts. (a) Specific licenses are issued unblocking a portion of or all of a joint bank account blocked by reason of the fact that one...

  9. Backward and forward blocking in human electrodermal conditioning: blocking requires an assumption of outcome additivity.

    PubMed

    Mitchell, Chris J; Lovibond, Peter F

    2002-10-01

    Blocking was observed in two human Pavlovian conditioning studies in which colour cues signalled shock. Both forward (Experiment 1) and backward (Experiment 2) blocking was demonstrated, but only when prior verbal and written instructions suggested that if two signals of shock (A+ and B+) were presented together, a double shock would result (AB++). In this case, participants could assume that the outcome magnitude was additive. Participants given non-additivity instructions (A+ and B+ combined would result in the same outcome, a single shock) failed to show blocking. Modifications required for associative models of learning, and normative statistical accounts of causal induction, to account for the impact of additivity instructions on the blocking effect, are discussed. It is argued that the blocking shown in the present experiments resulted from the operation, not of an error-correction learning rule, nor of a simple contingency detection mechanism, but of a more complex inferential process based on propositional knowledge. Consistent with the present data, blocking is a logical outcome of an A+/AB+ design only if participants can assume that outcomes will be additive. PMID:12350284

  10. Elementary and Secondary Education Property Accounting. A Handbook of Standard Terminology and a Guide for Classifying Information About Education Property. State Educational Records and Reports Series: Handbook III, Revised 1977.

    ERIC Educational Resources Information Center

    Davis (Robert) Associates, Inc., Atlanta, GA.

    The purposes of this handbook are to provide a comprehensive guide to standard terminology relating to property (sites, buildings, and equipment) used in education, a list of suggested data items useful in describing property, general data items useful in describing property, and general guidelines that can assist the reader in understanding and…

  11. Mixing thermodynamics of block-random copolymers

    NASA Astrophysics Data System (ADS)

    Beckingham, Bryan Scott

    Random copolymerization of A and B monomers represents a versatile method to tune interaction strengths between polymers, as ArB random copolymers will exhibit a smaller effective Flory interaction parameter chi; (or interaction energy density X) upon mixing with A or B homopolymers than upon mixing A and B homopolymers with each other, and the ArB composition can be tuned continuously. Thus, the incorporation of a random copolymer block into the classical block copolymer architecture to yield "block-random" copolymers introduces an additional tuning mechanism for the control of structure-property relationships, as the interblock interactions and physical properties can be tuned continuously through the random block's composition. However, typical living or controlled polymerizations produce compositional gradients along the "random" block, which can in turn influence the phase behavior. This dissertation demonstrates a method by which narrow-distribution copolymers of styrene and isoprene of any desired composition, with no measurable down-chain gradient, are synthesized. This synthetic method is then utilized to incorporate random copolymers of styrene and isoprene as blocks into block-random copolymers in order to examine the resulting interblock mixing thermodynamics. A series of well-defined near-symmetric block and block-random copolymers (S-I, Bd-S, I-SrI, S-SrI and Bd-S rI diblocks, where S is polystyrene, I is polyisoprene and Bd is polybutadiene), with varying molecular weight and random-block composition are synthesized and the mixing thermodynamics---via comparison of their interaction energy densities, X---of their hydrogenated derivatives is examined through measurement of the order-disorder transition (ODT) temperature. Hydrogenated derivatives of I-SrI and S-SrI block-random copolymers, both wherein the styrene aromaticity is retained and derivatives wherein the styrene units are saturated to vinylcyclohexane (VCH), are found to hew closely to the

  12. 31 CFR 587.505 - Entries in certain accounts for normal service charges authorized.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... charges authorized. (a) A U.S. financial institution is authorized to debit any blocked account held at... of that blocked account. (b) As used in this section, the term normal service charge shall include... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Entries in certain accounts...

  13. The first row anomaly and recoupled pair bonding in the halides of the late p-block elements.

    PubMed

    Dunning, Thom H; Woon, David E; Leiding, Jeff; Chen, Lina

    2013-02-19

    The dramatic differences between the properties of molecules formed from the late p-block elements of the first row of the periodic table (N-F) and those of the corresponding elements in subsequent rows is well recognized as the first row anomaly. Certain properties of the atoms, such as the relative energies and spatial extents of the ns and np orbitals, can explain some of these differences, but not others. In this Account, we summarize the results of our recent computational studies of the halides of the late p-block elements. Our studies point to a single underlying cause for many of these differences: the ability of the late p-block elements in the second and subsequent rows of the periodic table to form recoupled pair bonds and recoupled pair bond dyads with very electronegative ligands. Recoupled pair bonds form when an electron in a singly occupied ligand orbital recouples the pair of electrons in a doubly occupied lone pair orbital on the central atom, leading to a central atom-ligand bond. Recoupled pair bond dyads occur when a second ligand forms a bond with the orbital left over from the initial recoupled pair bond. Recoupled pair bonds and recoupled pair bond dyads enable the late p-block elements to form remarkably stable hypervalent compounds such as PF(5) and SF(6) and lead to unexpected excited states in smaller halides of the late p-block elements such as SF and SF(2). Recoupled pair bonding also causes the F(n-1)X-F bond energies to oscillate dramatically once the normal valences of the central atoms have been satisfied. In addition, recoupled pair bonding provides a lower-energy pathway for inversion in heavily fluorinated compounds (PF(3) and PF(2)H, but not PH(2)F and PH(3)) and leads to unusual intermediates and products in reactions involving halogens and late p-block element compounds, such as (CH(3))(2)S + F(2). Although this Account focuses on the halides of the second row, late p-block elements, recoupled pair bonds and recoupled pair

  14. The First Row Anomaly and Recoupled Pair Bonding in the Halides of the Late p-Block Elements

    PubMed Central

    2012-01-01

    The dramatic differences between the properties of molecules formed from the late p-block elements of the first row of the periodic table (N–F) and those of the corresponding elements in subsequent rows is well recognized as the first row anomaly. Certain properties of the atoms, such as the relative energies and spatial extents of the ns and np orbitals, can explain some of these differences, but not others. In this Account, we summarize the results of our recent computational studies of the halides of the late p-block elements. Our studies point to a single underlying cause for many of these differences: the ability of the late p-block elements in the second and subsequent rows of the periodic table to form recoupled pair bonds and recoupled pair bond dyads with very electronegative ligands. Recoupled pair bonds form when an electron in a singly occupied ligand orbital recouples the pair of electrons in a doubly occupied lone pair orbital on the central atom, leading to a central atom-ligand bond. Recoupled pair bond dyads occur when a second ligand forms a bond with the orbital left over from the initial recoupled pair bond. Recoupled pair bonds and recoupled pair bond dyads enable the late p-block elements to form remarkably stable hypervalent compounds such as PF5 and SF6 and lead to unexpected excited states in smaller halides of the late p-block elements such as SF and SF2. Recoupled pair bonding also causes the Fn–1X–F bond energies to oscillate dramatically once the normal valences of the central atoms have been satisfied. In addition, recoupled pair bonding provides a lower-energy pathway for inversion in heavily fluorinated compounds (PF3 and PF2H, but not PH2F and PH3) and leads to unusual intermediates and products in reactions involving halogens and late p-block element compounds, such as (CH3)2S + F2. Although this Account focuses on the halides of the second row, late p-block elements, recoupled pair bonds and recoupled pair bond dyads are

  15. Property.

    ERIC Educational Resources Information Center

    Piele, Philip K.

    Several court cases involving acquisition, use, and disposal of property by institutions of higher education are briefly summarized in this chapter. Cases discussed touch on such topics as municipal annexation of university property; repurchase of properties temporarily allocated to faculty members; implications of zoning laws and zoning board…

  16. A Place for Block Play.

    ERIC Educational Resources Information Center

    Moore, Gary T.

    1997-01-01

    Discusses the importance of block play--including its contributions to perceptual, fine motor, and cognitive development--and components of a good preschool block play area. Recommends unit blocks complemented by stacking blocks, toys, beads, cubes, and Brio wooden toys. Makes recommendations for space, size, locations and connections to other…

  17. Tuning the magnetic properties of Zn1-xCoxO films

    SciTech Connect

    Ney, V.; Ye, S.; Kammermeier, T.; Ollefs, K.; Ney, A.; Kaspar, Tiffany C.; Chambers, Scott A.; Wilhelm, F.; Rogalev, A.

    2010-06-01

    We compare the magnetic properties of two types of Co-doped ZnO films grown on sapphire with distinct structural quality. SQUID magnetometry as well as element-specific synchrotron studies reveal pure paramagnetic behavior for the samples with the highest structural quality, whereas samples with reduced structural quality exhibit superparamagnetic blocking behavior. In this sample signatures of phase separation are detected by X-ray diffraction and X-ray linear dichroism which accounts for the superparamagnetic blocking.

  18. Spice Blocks Melanoma Growth

    ERIC Educational Resources Information Center

    Science Teacher, 2005

    2005-01-01

    Curcumin, the pungent yellow spice found in both turmeric and curry powders, blocks a key biological pathway needed for development of melanoma and other cancers, according to a study that appears in the journal Cancer. Researchers from The University of Texas M. D. Anderson Cancer Center demonstrate how curcumin stops laboratory strains of…

  19. Flattening basic blocks.

    SciTech Connect

    Utke, J.; Mathematics and Computer Science

    2006-01-01

    The application of cross country elimination strategies requires access to the computational graph or at least subgraphs for certain scopes, e.g. a basic block. Under the presence of aliased variables the construction of these (sub)graphs encounters ambiguities. We propose an algorithm to construct ambiguity free subgraphs.

  20. Ischemic Nerve Block.

    ERIC Educational Resources Information Center

    Williams, Ian D.

    This experiment investigated the capability for movement and muscle spindle function at successive stages during the development of ischemic nerve block (INB) by pressure cuff. Two male subjects were observed under six randomly ordered conditions. The duration of index finger oscillation to exhaustion, paced at 1.2Hz., was observed on separate…

  1. What's behind Block Scheduling?

    ERIC Educational Resources Information Center

    Gierke, Carolyn

    1999-01-01

    Discussion of block scheduling in secondary schools focuses on its impact on the school library media center. Discusses increased demand for library services, scheduling classes, the impact on librarians' time, teaching information technology, local area networks, and the increased pace of activity. (LRW)

  2. Investigation of the Pressure Distribution in a Flow of a Viscous Fluid in a Pipeline Under Hydraulic-Shock Conditions with Account for the Relaxation Properties of the Fluid

    NASA Astrophysics Data System (ADS)

    Kudinov, I. V.; Kudinov, V. A.

    2014-03-01

    An exact analytical solution of the hyperbolic equation defining the pressure distribution in a viscous fluid flowing in a pipeline under the conditions of a hydraulic shock with account for the relaxation properties of the fluid has been obtained. It was established, based on a comparison of calculation and experimental data, that the relaxation properties of such a fluid determine the degree of nonstationarity of its fl ow and, hence, the wall friction of the fluid or its shear stress. It is shown that, in the case of nonstationary movement of a viscous fluid in a pipeline under hydraulic-shock conditions, the pressure jump caused by the hydraulic shock differs markedly in form (it is longer in time) from that in the case of quasi-stationary movement of this fluid under the identical conditions. The same effect (although weaker) was detected for decrease in the indicated pressure jump.

  3. Accounting for the dissociating properties of organic chemicals in LCIA: an uncertainty analysis applied to micropollutants in the assessment of freshwater ecotoxicity.

    PubMed

    Morais, Sérgio Alberto; Delerue-Matos, Cristina; Gabarrell, Xavier

    2013-03-15

    In life cycle impact assessment (LCIA) models, the sorption of the ionic fraction of dissociating organic chemicals is not adequately modeled because conventional non-polar partitioning models are applied. Therefore, high uncertainties are expected when modeling the mobility, as well as the bioavailability for uptake by exposed biota and degradation, of dissociating organic chemicals. Alternative regressions that account for the ionized fraction of a molecule to estimate fate parameters were applied to the USEtox model. The most sensitive model parameters in the estimation of ecotoxicological characterization factors (CFs) of micropollutants were evaluated by Monte Carlo analysis in both the default USEtox model and the alternative approach. Negligible differences of CFs values and 95% confidence limits between the two approaches were estimated for direct emissions to the freshwater compartment; however the default USEtox model overestimates CFs and the 95% confidence limits of basic compounds up to three orders and four orders of magnitude, respectively, relatively to the alternative approach for emissions to the agricultural soil compartment. For three emission scenarios, LCIA results show that the default USEtox model overestimates freshwater ecotoxicity impacts for the emission scenarios to agricultural soil by one order of magnitude, and larger confidence limits were estimated, relatively to the alternative approach. PMID:23434828

  4. International Accounting and the Accounting Educator.

    ERIC Educational Resources Information Center

    Laribee, Stephen F.

    The American Assembly of Collegiate Schools of Business (AACSB) has been instrumental in internationalizing the accounting curriculum by means of accreditation requirements and standards. Colleges and universities have met the AACSB requirements either by providing separate international accounting courses or by integrating international topics…

  5. Property.

    ERIC Educational Resources Information Center

    Piele, Philip K.; Johnson, Margaret M.

    This chapter deals with 1981 cases involving disputes over property. Cases involving the detachment and attachment of land continue to dominate the property chapter with 11 cases reported, the same number summarized in last year's chapter. One case involving school board referenda raised the interesting question of whether or not a state could…

  6. Property.

    ERIC Educational Resources Information Center

    Bickel, Robert D.; Zeller, Trisha A.

    A number of cases related to property issues involving institutions of higher education are examined in this chapter. Cases discussed touch on such topics as funding for property and equipment acquisition; opposition to building construction or demolition; zoning issues; building construction and equipment contracts; and lease agreements. Current…

  7. Managing access block.

    PubMed

    Cameron, Peter; Scown, Paul; Campbell, Donald

    2002-01-01

    There is pessimism regarding the ability of the Acute Health Sector to manage access block for emergency and elective patients. Melbourne Health suffered an acute bed crisis in 2001 resulting in record ambulance diversions and emergency department (ED) delays. We conducted an observational study to reduce access block for emergency patients whilst maintaining elective throughput at Melbourne Health. This involved a clinician-led taskforce using previously proven principles for organisational change to implement 51 actions to improve patient access over a three-month period. The primary outcome measures were ambulance diversion, emergency patients waiting more than 12 hours for an inpatient bed, elective throughput and theatre cancellations. Despite a reduction in multi-day bed numbers all primary objectives were met, ambulance diversion decreased to minimal levels, 12-hour waits decreased by 40% and elective throughput was maintained. Theatre cancellations were also minimised. We conclude that access block can be improved by clinician-led implementation of proven process improvements over a short time frame. The ability to sustain change over the longer term requires further study.

  8. A Harmonious Accounting Duo?

    ERIC Educational Resources Information Center

    Schapperle, Robert F.; Hardiman, Patrick F.

    1992-01-01

    Accountants have urged "harmonization" of standards between the Governmental Accounting Standards Board and the Financial Accounting Standards Board, recommending similar reporting of like transactions. However, varying display of similar accounting events does not necessarily indicate disharmony. The potential for problems because of differing…

  9. Block 3. This photograph depicts the northern view of Block ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Block 3. This photograph depicts the northern view of Block 2 towards the May D & F Tower from the main path along the western facades - Skyline Park, 1500-1800 Arapaho Street, Denver, Denver County, CO

  10. Arbitrary lattice symmetries via block copolymer nanomeshes

    PubMed Central

    Majewski, Pawel W.; Rahman, Atikur; Black, Charles T.; Yager, Kevin G.

    2015-01-01

    Self-assembly of block copolymers is a powerful motif for spontaneously forming well-defined nanostructures over macroscopic areas. Yet, the inherent energy minimization criteria of self-assembly give rise to a limited library of structures; diblock copolymers naturally form spheres on a cubic lattice, hexagonally packed cylinders and alternating lamellae. Here, we demonstrate multicomponent nanomeshes with any desired lattice symmetry. We exploit photothermal annealing to rapidly order and align block copolymer phases over macroscopic areas, combined with conversion of the self-assembled organic phase into inorganic replicas. Repeated photothermal processing independently aligns successive layers, providing full control of the size, symmetry and composition of the nanoscale unit cell. We construct a variety of symmetries, most of which are not natively formed by block copolymers, including squares, rhombuses, rectangles and triangles. In fact, we demonstrate all possible two-dimensional Bravais lattices. Finally, we elucidate the influence of nanostructure on the electrical and optical properties of nanomeshes. PMID:26100566

  11. Block copolymers for opto-electronics

    NASA Astrophysics Data System (ADS)

    Sun, Sam-Shajing; Fan, Zhen; Wang, Yiqing; Taft, Charles; Haliburton, James H.; Maaref, Shahin; Ledbetter, Abram J.; Bonner, Carl E.

    2004-05-01

    A D(donor)-B(bridge)-A(acceptor)-B(bridge)-type block copolymer system has been developed and preliminarily examined for potential opto-electronic photovoltaic functions. The unique feature of the device includes a primary DBAB-type block copolymer backbone, where D and A are conjugated donor and acceptor polymer blocks, and B is a non-conjugated and flexible chain, a π orbital stacked and conjugated chain self-assembled and ordered "secondary structure", and a donor/acceptor asymmetric layers sandwiched D/A columnar "tertiary structure". This structure is expected to improve photovoltaic power conversion efficiency significantly in comparison to most existing organic or polymeric donor/acceptor binary photovoltaic systems due to the reduction of "exciton loss", the "carrier loss", as well as the "photon loss" via three-dimensional space and energy level optimizations. Preliminary experimental results revealed better morphology and opto-electronic properties of DBAB vs. D/A blends.

  12. Block Transfer Handbook: Constructing and Negotiating Block Transfer Agreements.

    ERIC Educational Resources Information Center

    Finlay, Finola

    The purpose of this handbook is to provide resources for institutions or articulation committees who are engaged in the task of investigating the feasibility of block transfer agreements. Block transfer is the process whereby a block of credits is granted to students who have successfully completed a certificate, diploma, or cluster of courses…

  13. View southeast of caps for blocks for JFK; blocks are ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    View southeast of caps for blocks for JFK; blocks are used to support ship when it is repositioned to paint inaccessible areas masked by original support blocks. - Naval Base Philadelphia-Philadelphia Naval Shipyard, Carpentry Shop, League Island, Philadelphia, Philadelphia County, PA

  14. A discrete element modelling approach for block impacts on trees

    NASA Astrophysics Data System (ADS)

    Toe, David; Bourrier, Franck; Olmedo, Ignatio; Berger, Frederic

    2015-04-01

    These past few year rockfall models explicitly accounting for block shape, especially those using the Discrete Element Method (DEM), have shown a good ability to predict rockfall trajectories. Integrating forest effects into those models still remain challenging. This study aims at using a DEM approach to model impacts of blocks on trees and identify the key parameters controlling the block kinematics after the impact on a tree. A DEM impact model of a block on a tree was developed and validated using laboratory experiments. Then, key parameters were assessed using a global sensitivity analyse. Modelling the impact of a block on a tree using DEM allows taking into account large displacements, material non-linearities and contacts between the block and the tree. Tree stems are represented by flexible cylinders model as plastic beams sustaining normal, shearing, bending, and twisting loading. Root soil interactions are modelled using a rotation stiffness acting on the bending moment at the bottom of the tree and a limit bending moment to account for tree overturning. The crown is taken into account using an additional mass distribute uniformly on the upper part of the tree. The block is represented by a sphere. The contact model between the block and the stem consists of an elastic frictional model. The DEM model was validated using laboratory impact tests carried out on 41 fresh beech (Fagus Sylvatica) stems. Each stem was 1,3 m long with a diameter between 3 to 7 cm. Wood stems were clamped on a rigid structure and impacted by a 149 kg charpy pendulum. Finally an intensive simulation campaign of blocks impacting trees was done to identify the input parameters controlling the block kinematics after the impact on a tree. 20 input parameters were considered in the DEM simulation model : 12 parameters were related to the tree and 8 parameters to the block. The results highlight that the impact velocity, the stem diameter, and the block volume are the three input

  15. A novel power block for CSP systems

    SciTech Connect

    Mittelman, Gur; Epstein, Michael

    2010-10-15

    Concentrating Solar Thermal Power (CSP) and in particular parabolic trough, is a proven large-scale solar power technology. However, CSP cost is not yet competitive with conventional alternatives unless subsidized. Current CSP plants typically include a condensing steam cycle power block which was preferably designed for a continuous operation and higher operating conditions and therefore, limits the overall plant cost effectiveness and deployment. The drawbacks of this power block are as follows: (i) no power generation during low insolation periods (ii) expensive, large condenser (typically water cooled) due to the poor extracted steam properties (high specific volume, sub-atmospheric pressure) and (iii) high installation and operation costs. In the current study, a different power block scheme is proposed to eliminate these obstacles. This power block includes a top Rankine cycle with a back pressure steam turbine and a bottoming Kalina cycle comprising another back pressure turbine and using ammonia-water mixture as a working fluid. The bottoming (moderate temperature) cycle allows power production during low insolation periods. Because of the superior ammonia-water vapor properties, the condensing system requirements are much less demanding and the operation costs are lowered. Accordingly, air cooled condensers can be used with lower economical penalty. Another advantage is that back pressure steam turbines have a less complex design than condensing steam turbines which make their costs lower. All of these improvements could make the combined cycle unit more cost effective. This unit can be applicable in both parabolic trough and central receiver (solar tower) plants. The potential advantage of the new power block is illustrated by a detailed techno-economical analysis of two 50 MW parabolic trough power plants, comparing between the standard and the novel power block. The results indicate that the proposed plant suggests a 4-11% electricity cost saving

  16. The poor man's cell block

    PubMed Central

    Darlington, Ann

    2010-01-01

    The authors describe a simple method for making formalin or isopropyl alcohol vapour fixed cell blocks from fine needle aspiration cytology specimens that we refer to as ‘The Poor Man's Cell Block.’ PMID:20671053

  17. Fermion-scalar conformal blocks

    DOE PAGES

    Iliesiu, Luca; Kos, Filip; Poland, David; Pufu, Silviu S.; Simmons-Duffin, David; Yacoby, Ran

    2016-04-13

    In this study, we compute the conformal blocks associated with scalar-scalar-fermionfermion 4-point functions in 3D CFTs. Together with the known scalar conformal blocks, our result completes the task of determining the so-called ‘seed blocks’ in three dimensions. In addition, conformal blocks associated with 4-point functions of operators with arbitrary spins can now be determined from these seed blocks by using known differential operators.

  18. Porous block nanofiber composite filters

    DOEpatents

    Ginley, David S.; Curtis, Calvin J.; Miedaner, Alexander; Weiss, Alan J.; Paddock, Arnold

    2016-08-09

    Porous block nano-fiber composite (110), a filtration system (10) and methods of using the same are disclosed. An exemplary porous block nano-fiber composite (110) includes a porous block (100) having one or more pores (200). The porous block nano-fiber composite (110) also includes a plurality of inorganic nano-fibers (211) formed within at least one of the pores (200).

  19. CORE SATURATION BLOCKING OSCILLATOR

    DOEpatents

    Spinrad, R.J.

    1961-10-17

    A blocking oscillator which relies on core saturation regulation to control the output pulse width is described. In this arrangement an external magnetic loop is provided in which a saturable portion forms the core of a feedback transformer used with the thermionic or semi-conductor active element. A first stationary magnetic loop establishes a level of flux through the saturation portion of the loop. A second adjustable magnet moves the flux level to select a saturation point giving the desired output pulse width. (AEC)

  20. Building Curriculum during Block Play

    ERIC Educational Resources Information Center

    Andrews, Nicole

    2015-01-01

    Blocks are not just for play! In this article, Nicole Andrews describes observing the interactions of three young boys enthusiastically engaged in the kindergarten block center of their classroom, using blocks in a building project that displayed their ability to use critical thinking skills, physics exploration, and the development of language…