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Sample records for accurate transition frequencies

  1. Accurate measurements of transition frequencies and isotope shifts of laser-trapped francium.

    PubMed

    Sanguinetti, S; Calabrese, R; Corradi, L; Dainelli, A; Khanbekyan, A; Mariotti, E; de Mauro, C; Minguzzi, P; Moi, L; Stancari, G; Tomassetti, L; Veronesi, S

    2009-04-01

    An interferometric method is used to improve the accuracy of the 7S-7P transition frequencies of three francium isotopes by 1 order of magnitude. The deduced isotope shifts for 209-211Fr confirm the ISOLDE data. The frequency of the D2 transition of 212Fr--the accepted reference for all Fr isotope shifts--is revised, and a significant difference with the ISOLDE value is found. Our results will be a benchmark for the accuracy of the theory of Fr energy levels, a necessary step to investigate fundamental symmetries. PMID:19340162

  2. Accurate far-infrared rotational frequencies of carbon monoxide

    NASA Technical Reports Server (NTRS)

    Varberg, Thomas D.; Evenson, Kenneth M.

    1992-01-01

    This study presents high-resolution measurements of the pure rotational absorption spectrum of CO in its ground state for the range J arcsec - 5-37. A least-squares fit to this data set, augmented by previous microwave measurements of the J arcsec = 0-4 rotational transitions in the literature, determined accurate values for the molecular constants. A table of calculated CO rotational frequencies is provided for the range J arcsec = 0-45.

  3. High Frequency QRS ECG Accurately Detects Cardiomyopathy

    NASA Technical Reports Server (NTRS)

    Schlegel, Todd T.; Arenare, Brian; Poulin, Gregory; Moser, Daniel R.; Delgado, Reynolds

    2005-01-01

    High frequency (HF, 150-250 Hz) analysis over the entire QRS interval of the ECG is more sensitive than conventional ECG for detecting myocardial ischemia. However, the accuracy of HF QRS ECG for detecting cardiomyopathy is unknown. We obtained simultaneous resting conventional and HF QRS 12-lead ECGs in 66 patients with cardiomyopathy (EF = 23.2 plus or minus 6.l%, mean plus or minus SD) and in 66 age- and gender-matched healthy controls using PC-based ECG software recently developed at NASA. The single most accurate ECG parameter for detecting cardiomyopathy was an HF QRS morphological score that takes into consideration the total number and severity of reduced amplitude zones (RAZs) present plus the clustering of RAZs together in contiguous leads. This RAZ score had an area under the receiver operator curve (ROC) of 0.91, and was 88% sensitive, 82% specific and 85% accurate for identifying cardiomyopathy at optimum score cut-off of 140 points. Although conventional ECG parameters such as the QRS and QTc intervals were also significantly longer in patients than controls (P less than 0.001, BBBs excluded), these conventional parameters were less accurate (area under the ROC = 0.77 and 0.77, respectively) than HF QRS morphological parameters for identifying underlying cardiomyopathy. The total amplitude of the HF QRS complexes, as measured by summed root mean square voltages (RMSVs), also differed between patients and controls (33.8 plus or minus 11.5 vs. 41.5 plus or minus 13.6 mV, respectively, P less than 0.003), but this parameter was even less accurate in distinguishing the two groups (area under ROC = 0.67) than the HF QRS morphologic and conventional ECG parameters. Diagnostic accuracy was optimal (86%) when the RAZ score from the HF QRS ECG and the QTc interval from the conventional ECG were used simultaneously with cut-offs of greater than or equal to 40 points and greater than or equal to 445 ms, respectively. In conclusion 12-lead HF QRS ECG employing

  4. Accurate transition rates for intercombination lines of singly ionized nitrogen

    SciTech Connect

    Tayal, S. S.

    2011-01-15

    The transition energies and rates for the 2s{sup 2}2p{sup 2} {sup 3}P{sub 1,2}-2s2p{sup 3} {sup 5}S{sub 2}{sup o} and 2s{sup 2}2p3s-2s{sup 2}2p3p intercombination transitions have been calculated using term-dependent nonorthogonal orbitals in the multiconfiguration Hartree-Fock approach. Several sets of spectroscopic and correlation nonorthogonal functions have been chosen to describe adequately term dependence of wave functions and various correlation corrections. Special attention has been focused on the accurate representation of strong interactions between the 2s2p{sup 3} {sup 1,3}P{sub 1}{sup o} and 2s{sup 2}2p3s {sup 1,3}P{sub 1}{sup o}levels. The relativistic corrections are included through the one-body mass correction, Darwin, and spin-orbit operators and two-body spin-other-orbit and spin-spin operators in the Breit-Pauli Hamiltonian. The importance of core-valence correlation effects has been examined. The accuracy of present transition rates is evaluated by the agreement between the length and velocity formulations combined with the agreement between the calculated and measured transition energies. The present results for transition probabilities, branching fraction, and lifetimes have been compared with previous calculations and experiments.

  5. Accurate Determination of Conformational Transitions in Oligomeric Membrane Proteins

    PubMed Central

    Sanz-Hernández, Máximo; Vostrikov, Vitaly V.; Veglia, Gianluigi; De Simone, Alfonso

    2016-01-01

    The structural dynamics governing collective motions in oligomeric membrane proteins play key roles in vital biomolecular processes at cellular membranes. In this study, we present a structural refinement approach that combines solid-state NMR experiments and molecular simulations to accurately describe concerted conformational transitions identifying the overall structural, dynamical, and topological states of oligomeric membrane proteins. The accuracy of the structural ensembles generated with this method is shown to reach the statistical error limit, and is further demonstrated by correctly reproducing orthogonal NMR data. We demonstrate the accuracy of this approach by characterising the pentameric state of phospholamban, a key player in the regulation of calcium uptake in the sarcoplasmic reticulum, and by probing its dynamical activation upon phosphorylation. Our results underline the importance of using an ensemble approach to characterise the conformational transitions that are often responsible for the biological function of oligomeric membrane protein states. PMID:26975211

  6. Accurate rest-frequencies of ketenimine (CH2CNH) at submillimetre wavelength

    NASA Astrophysics Data System (ADS)

    Degli Esposti, C.; Dore, L.; Bizzocchi, L.

    2014-05-01

    Context. Imine compounds are thought to have a role in the interstellar formation of complex organic species, including pre-biotic molecules. Ketenimine (CH2CNH) is one of the four imines discovered in space. It was identified in Sgr B2(N-LMH) through the detection of three rotational lines in absorption. Aims: We present an extensive laboratory study of the ground-state rotational spectrum of CH2CNH at submillimetre wavelengths, aimed at obtaining accurate rest-frequencies for radio-astronomical searches. Methods: The investigation was carried out using a source-modulation microwave spectrometer equipped with a cell that is coupled to a pyrolysis apparatus working at 1000°. The spectrum was recorded in the frequency range 80-620 GHz with the detection of 150 transitions. Results: The newly measured transition frequencies were analysed with previously available microwave and far-infrared data, yielding accurate rotational constants of CH2CNH, the complete sets of quartic and sextic centrifugal distortion constants, and three octic constants. Several transitions exhibit a hyperfine structure due to the quadrupole and spin-rotation couplings of the 14N nucleus, which were accounted for in the analysis. Conclusions: The determined spectroscopic constants allowed for the computation of a list of highly accurate rest-frequencies for astrophysical purposes in the submillimetre and THz region with 1σ uncertainties that are lower than 0.1 km s-1 in radial equivalent velocity. Full Tables 1 and 3 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/565/A66

  7. The absolute frequency of the 87Sr optical clock transition

    NASA Astrophysics Data System (ADS)

    Campbell, Gretchen K.; Ludlow, Andrew D.; Blatt, Sebastian; Thomsen, Jan W.; Martin, Michael J.; de Miranda, Marcio H. G.; Zelevinsky, Tanya; Boyd, Martin M.; Ye, Jun; Diddams, Scott A.; Heavner, Thomas P.; Parker, Thomas E.; Jefferts, Steven R.

    2008-10-01

    The absolute frequency of the 1S0-3P0 clock transition of 87Sr has been measured to be 429 228 004 229 873.65 (37) Hz using lattice-confined atoms, where the fractional uncertainty of 8.6 × 10-16 represents one of the most accurate measurements of an atomic transition frequency to date. After a detailed study of systematic effects, which reduced the total systematic uncertainty of the Sr lattice clock to 1.5 × 10-16, the clock frequency is measured against a hydrogen maser which is simultaneously calibrated to the US primary frequency standard, the NIST Cs fountain clock, NIST-F1. The comparison is made possible using a femtosecond laser based optical frequency comb to phase coherently connect the optical and microwave spectral regions and by a 3.5 km fibre transfer scheme to compare the remotely located clock signals.

  8. How Accurate Are Transition States from Simulations of Enzymatic Reactions?

    PubMed Central

    2015-01-01

    The rate expression of traditional transition state theory (TST) assumes no recrossing of the transition state (TS) and thermal quasi-equilibrium between the ground state and the TS. Currently, it is not well understood to what extent these assumptions influence the nature of the activated complex obtained in traditional TST-based simulations of processes in the condensed phase in general and in enzymes in particular. Here we scrutinize these assumptions by characterizing the TSs for hydride transfer catalyzed by the enzyme Escherichia coli dihydrofolate reductase obtained using various simulation approaches. Specifically, we compare the TSs obtained with common TST-based methods and a dynamics-based method. Using a recently developed accurate hybrid quantum mechanics/molecular mechanics potential, we find that the TST-based and dynamics-based methods give considerably different TS ensembles. This discrepancy, which could be due equilibrium solvation effects and the nature of the reaction coordinate employed and its motion, raises major questions about how to interpret the TSs determined by common simulation methods. We conclude that further investigation is needed to characterize the impact of various TST assumptions on the TS phase-space ensemble and on the reaction kinetics. PMID:24860275

  9. Accurate rotational rest-frequencies of CH2NH at submillimetre wavelengths

    NASA Astrophysics Data System (ADS)

    Dore, L.; Bizzocchi, L.; Degli Esposti, C.

    2012-08-01

    Context. Methanimine (CH2NH) has been detected in different astronomical sources, both galactic (as in several "hot cores", the circumstellar enevolope IRC+10216, and the L183 pre-stellar core) and extragalactic, and is considered a pre-biotic interstellar molecule. Its ground-state rotational spectrum has been studied in the laboratory up to 172 GHz, well below the spectral ranges covered by Herschel/HIFI and the ALMA bands 9 and 10. Aims: In this laboratory study, we extend into the submillimetre-wave region the detection of the rotational spectrum of CH2NH in its vibrational ground state. Methods: The investigation was carried out using a source-modulation microwave spectrometer equipped with a cell coupled to a pyrolysis apparatus working at 1150 °C. The spectrum was recorded in the frequency range 329-629 GHz, with the detection of 58 transitions. Results: The newly measured transition frequencies, along with those available from previous microwave studies, allow us to determine fairly accurate rotational constants of CH2NH and the complete sets of quartic and sextic centrifugal distortion constants, in addition to two octic constants. Several transitions have an hyperfine structure due to the 14N nucleus, which was accounted for in the analysis. Conclusions: The determined spectroscopic constants make it possible to build a list of very accurate rest-frequencies for astrophysical purposes in the THz region with 1σ uncertainties lower than 0.01 km s-1 in radial equivalent velocity. Table 1 is only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/544/A19

  10. Accurate Evaluation Method of Molecular Binding Affinity from Fluctuation Frequency

    NASA Astrophysics Data System (ADS)

    Hoshino, Tyuji; Iwamoto, Koji; Ode, Hirotaka; Ohdomari, Iwao

    2008-05-01

    Exact estimation of the molecular binding affinity is significantly important for drug discovery. The energy calculation is a direct method to compute the strength of the interaction between two molecules. This energetic approach is, however, not accurate enough to evaluate a slight difference in binding affinity when distinguishing a prospective substance from dozens of candidates for medicine. Hence more accurate estimation of drug efficacy in a computer is currently demanded. Previously we proposed a concept of estimating molecular binding affinity, focusing on the fluctuation at an interface between two molecules. The aim of this paper is to demonstrate the compatibility between the proposed computational technique and experimental measurements, through several examples for computer simulations of an association of human immunodeficiency virus type-1 (HIV-1) protease and its inhibitor (an example for a drug-enzyme binding), a complexation of an antigen and its antibody (an example for a protein-protein binding), and a combination of estrogen receptor and its ligand chemicals (an example for a ligand-receptor binding). The proposed affinity estimation has proven to be a promising technique in the advanced stage of the discovery and the design of drugs.

  11. Frequency shift of hyperfine transitions due to blackbody radiation

    SciTech Connect

    Angstmann, E. J.; Dzuba, V. A.; Flambaum, V. V.

    2006-08-15

    We have performed calculations of the size of the frequency shift induced by a static electric field on the clock transition frequencies of the hyperfine splitting in Yb{sup +}, Rb, Cs, Ba{sup +}, and Hg{sup +}. The calculations are used to find the frequency shifts due to blackbody radiation which are needed for accurate frequency measurements and improvements of the limits on variation of the fine-structure constant {alpha}. Our result for Cs [{delta}{nu}/E{sup 2}=-2.26(2)x10{sup -10}Hz/(V/m){sup 2}] is in good agreement with early measurements and ab initio calculations. We present arguments against recent claims that the actual value might be smaller. The difference ({approx}10%) is due to the contribution of the continuum spectrum in the sum over intermediate states.

  12. Predicting accurate line shape parameters for CO2 transitions

    NASA Astrophysics Data System (ADS)

    Gamache, Robert R.; Lamouroux, Julien

    2013-11-01

    The vibrational dependence of CO2 half-widths and line shifts are given by a modification of the model proposed by Gamache and Hartmann [Gamache R, Hartmann J-M. J Quant Spectrosc Radiat Transfer 2004;83:119]. This model allows the half-widths and line shifts for a ro-vibrational transition to be expressed in terms of the number of vibrational quanta exchanged in the transition raised to a power and a reference ro-vibrational transition. Calculations were made for 24 bands for lower rotational quantum numbers from 0 to 160 for N2-, O2-, air-, and self-collisions with CO2. These data were extrapolated to J″=200 to accommodate several databases. Comparison of the CRB calculations with measurement gives very high confidence in the data. In the model a Quantum Coordinate is defined by (c1 |Δν1|+c2 |Δν2|+c3|Δν3|)p. The power p is adjusted and a linear least-squares fit to the data by the model expression is made. The procedure is iterated on the correlation coefficient, R, until [|R|-1] is less than a threshold. The results demonstrate the appropriateness of the model. The model allows the determination of the slope and intercept as a function of rotational transition, broadening gas, and temperature. From the data of the fits, the half-width, line shift, and the temperature dependence of the half-width can be estimated for any ro-vibrational transition, allowing spectroscopic CO2 databases to have complete information for the line shape parameters.

  13. Precise laboratory measurements of methanol rotational transition frequencies in the 5 to 13 GHz region

    NASA Astrophysics Data System (ADS)

    Breckenridge, S. M.; Kukolich, S. G.

    1995-01-01

    Rotational transitions for CH3OH were measured in the 5-13 GHz range with a precision and accuracy of a few kilohertz or less using a Flygare-Balle type pulsed-beam Fourier transform microwave spectrometer. The accurate center frequencies measured should be useful in determining accurate Doppler shifts and making positive molecule identification in radio astronomy.

  14. Rotational frequencies of transition metal hydrides for astrophysical searches in the far-infrared

    NASA Technical Reports Server (NTRS)

    Brown, John M.; Beaton, Stuart P.; Evenson, Kenneth M.

    1993-01-01

    Accurate frequencies for the lowest rotational transitions of five transition metal hydrides (CrH, FeH, CoH, NiH, and CuH) in their ground electronic states are reported to help the identification of these species in astrophysical sources from their far-infrared spectra. Accurate frequencies are determined in two ways: for CuH, by calculation from rotational constants determined from higher J transitions with an accuracy of 190 kHz; for the other species, by extrapolation to zero magnetic field from laser magnetic resonance spectra with an accuracy of 0.7 MHz.

  15. Importance of level mixing on accurate [Fe II] transition rates

    NASA Astrophysics Data System (ADS)

    Deb, N. C.; Hibbert, A.

    2010-12-01

    Context. In a very recent measurement Gurell et al. (2009, A&A, 508, 525) commented that while the theoretical lifetime of a 4G5.5 is approximately one tenth of the lifetime of b 2H5.5 the corresponding measurement shows this to be close to one fifth. This large discrepancy is attributed to the effect of inadequate level mixing in the theoretical calculations. Aims: The aim of this work is to make a detailed analysis of these level mixing effects on transitions from various lower levels to the a 4G5.5 and b 2H5.5 levels given in three previous calculations and in the present more extensive CI calculation. Methods: The CIV3 structure codes of Hibbert (1975, Comput. Phys. Commun., 9, 141) and Hibbert et al. (1991, Comput. Phys. Commun., 64, 455) are used in the present work, combined with our “fine-tuning” extrapolation process. Results: The calculated mixing between the upper levels, obtained in previous calculations, is shown to be too weak. The stronger mixing determined in our work gives rise to a calculated lifetime for b 2H5.5 within 3% of the measured value. On the other hand our calculated lifetime for a 4G5.5 is around 20% lower than the measured value, which has fairly wide error bars. Conclusions: Our enhanced calculations explain the difference between previous calculations of the b 2H5.5 lifetime and the recent measured value and confirm the latter. We also suggest a somewhat higher value than experiment for the lifetime of a 4G5.5.

  16. A Novel Multimode Waveguide Coupler for Accurate Power Measurement of Traveling Wave Tube Harmonic Frequencies

    NASA Technical Reports Server (NTRS)

    Wintucky, Edwin G.; Simons, Rainee N.

    2014-01-01

    This paper presents the design, fabrication and test results for a novel waveguide multimode directional coupler (MDC). The coupler fabricated from two dissimilar waveguides is capable of isolating the power at the second harmonic frequency from the fundamental power at the output port of a traveling-wave tube (TWT). In addition to accurate power measurements at harmonic frequencies, a potential application of the MDC is in the design of a beacon source for atmospheric propagation studies at millimeter-wave frequencies.

  17. Absolute frequency measurements and hyperfine structures of the molecular iodine transitions at 578 nm

    NASA Astrophysics Data System (ADS)

    Kobayashi, Takumi; Akamatsu, Daisuke; Hosaka, Kazumoto; Inaba, Hajime; Okubo, Sho; Tanabe, Takehiko; Yasuda, Masami; Onae, Atsushi; Hong, Feng-Lei

    2016-04-01

    We report absolute frequency measurements of 81 hyperfine components of the rovibrational transitions of molecular iodine at 578 nm using the second harmonic generation of an 1156-nm external-cavity diode laser and a fiber-based optical frequency comb. The relative uncertainties of the measured absolute frequencies are typically $1.4\\times10^{-11}$. Accurate hyperfine constants of four rovibrational transitions are obtained by fitting the measured hyperfine splittings to a four-term effective Hamiltonian including the electric quadrupole, spin-rotation, tensor spin-spin, and scalar spin-spin interactions. The observed transitions can be good frequency references at 578 nm, and are especially useful for research using atomic ytterbium since the transitions are close to the $^{1}S_{0}-^{3}P_{0}$ clock transition of ytterbium.

  18. Low noise frequency synthesizer with self-calibrated voltage controlled oscillator and accurate AFC algorithm

    NASA Astrophysics Data System (ADS)

    Peng, Qin; Jinbo, Li; Jian, Kang; Xiaoyong, Li; Jianjun, Zhou

    2014-09-01

    A low noise phase locked loop (PLL) frequency synthesizer implemented in 65 nm CMOS technology is introduced. A VCO noise reduction method suited for short channel design is proposed to minimize PLL output phase noise. A self-calibrated voltage controlled oscillator is proposed in cooperation with the automatic frequency calibration circuit, whose accurate binary search algorithm helps reduce the VCO tuning curve coverage, which reduces the VCO noise contribution at PLL output phase noise. A low noise, charge pump is also introduced to extend the tuning voltage range of the proposed VCO, which further reduces its phase noise contribution. The frequency synthesizer generates 9.75-11.5 GHz high frequency wide band local oscillator (LO) carriers. Tested 11.5 GHz LO bears a phase noise of-104 dBc/Hz at 1 MHz frequency offset. The total power dissipation of the proposed frequency synthesizer is 48 mW. The area of the proposed frequency synthesizer is 0.3 mm2, including bias circuits and buffers.

  19. Distributed fiber sensing system with wide frequency response and accurate location

    NASA Astrophysics Data System (ADS)

    Shi, Yi; Feng, Hao; Zeng, Zhoumo

    2016-02-01

    A distributed fiber sensing system merging Mach-Zehnder interferometer and phase-sensitive optical time domain reflectometer (Φ-OTDR) is demonstrated for vibration measurement, which requires wide frequency response and accurate location. Two narrow line-width lasers with delicately different wavelengths are used to constitute the interferometer and reflectometer respectively. A narrow band Fiber Bragg Grating is responsible for separating the two wavelengths. In addition, heterodyne detection is applied to maintain the signal to noise rate of the locating signal. Experiment results show that the novel system has a wide frequency from 1 Hz to 50 MHz, limited by the sample frequency of data acquisition card, and a spatial resolution of 20 m, according to 200 ns pulse width, along 2.5 km fiber link.

  20. Electron heating mode transition induced by mixing radio frequency and ultrahigh frequency dual frequency powers in capacitive discharges

    NASA Astrophysics Data System (ADS)

    Sahu, B. B.; Han, Jeon G.

    2016-05-01

    Electron heating mode transitions induced by mixing the low- and high-frequency power in dual-frequency nitrogen discharges at 400 mTorr pressure are presented. As the low-frequency (13.56 MHz) power decreases and high-frequency (320 MHz) power increases for the fixed power of 200 W, there is a transition of electron energy distribution function (EEDF) from Druyvesteyn to bi-Maxwellian type characterized by a distinguished warm electron population. It is shown that this EEDF evolution is attributed to the transition from collisional to collisionless stochastic heating of the low-energy electrons.

  1. Direct Simulations of Transition and Turbulence Using High-Order Accurate Finite-Difference Schemes

    NASA Technical Reports Server (NTRS)

    Rai, Man Mohan

    1997-01-01

    In recent years the techniques of computational fluid dynamics (CFD) have been used to compute flows associated with geometrically complex configurations. However, success in terms of accuracy and reliability has been limited to cases where the effects of turbulence and transition could be modeled in a straightforward manner. Even in simple flows, the accurate computation of skin friction and heat transfer using existing turbulence models has proved to be a difficult task, one that has required extensive fine-tuning of the turbulence models used. In more complex flows (for example, in turbomachinery flows in which vortices and wakes impinge on airfoil surfaces causing periodic transitions from laminar to turbulent flow) the development of a model that accounts for all scales of turbulence and predicts the onset of transition may prove to be impractical. Fortunately, current trends in computing suggest that it may be possible to perform direct simulations of turbulence and transition at moderate Reynolds numbers in some complex cases in the near future. This seminar will focus on direct simulations of transition and turbulence using high-order accurate finite-difference methods. The advantage of the finite-difference approach over spectral methods is that complex geometries can be treated in a straightforward manner. Additionally, finite-difference techniques are the prevailing methods in existing application codes. In this seminar high-order-accurate finite-difference methods for the compressible and incompressible formulations of the unsteady Navier-Stokes equations and their applications to direct simulations of turbulence and transition will be presented.

  2. Relationship between the transition frequency of local fluid flow and the peak frequency of attenuation

    NASA Astrophysics Data System (ADS)

    Cao, Cheng-Hao; Zhang, Hong-Bing; Pan, Yi-Xin; Teng, Xin-Bao

    2016-03-01

    Local fluid flow (LFF) at the mesoscopic scale is the main dissipation mechanism of seismic waves in heterogeneous porous media within the seismic frequency band. LFF is easily influenced by the structure and boundary conditions of the porous media, which leads to different behaviors of the peak frequency of attenuation. The associated transition frequency can provide detailed information about the trend of LFF; therefore, research on the transition frequency of LFF and its relationship with the peak frequency of the corresponding attenuation (i.e., inverse of quality factor) facilitates the detailed understanding of the effect of inner structures and boundary conditions in porous media. In this study, we firstly obtain the transition frequency of fluid flux based on Biot's theory of poroelasticity and the fast Fourier transform algorithm in a sample containing one repeating unit cell (RUC). We then analyze changes of these two frequencies in porous media with different porous properties. Finally, we extend our analysis to the influence of the undrained boundary condition on the transition frequency and peak frequency in porous media with multiple RUCs. This setup can facilitate the understanding of the effect from the undrained boundary condition. Results demonstrate that these two frequencies have the same trend at low water saturation, but amplitude variations differ between the frequencies as the amount of saturation increases. However, for cases of high water saturation, both the trend and the amplitude variation of these two frequencies fit well with each other.

  3. Switch over to the high frequency rf systems near transition

    SciTech Connect

    Brennan, J.M.; Wei, J.

    1988-01-01

    The purpose of this note is to point out that since bunch narrowing naturally occurs in the acceleration process in the vicinity of transition, it should be possible to switch over to the high frequency system close to transition when the bunch has narrowed enough to fit directly into the high frequency bucket. The advantage of this approach is the simplicity, no extra components or gymnastics are required of the low frequency system. The disadvantage, of course, is for protons which do not go through transition. But on the other hand, there is no shortage of intensity for protons and so it should be possible to keep the phase space area low for protons, and then matching to the high frequency bucket should be easily accomplished by adiabatic compression. 3 refs., 7 figs.

  4. Effective and accurate approach for modeling of commensurate-incommensurate transition in krypton monolayer on graphite.

    PubMed

    Ustinov, E A

    2014-10-01

    Commensurate-incommensurate (C-IC) transition of krypton molecular layer on graphite received much attention in recent decades in theoretical and experimental researches. However, there still exists a possibility of generalization of the phenomenon from thermodynamic viewpoint on the basis of accurate molecular simulation. Recently, a new technique was developed for analysis of two-dimensional (2D) phase transitions in systems involving a crystalline phase, which is based on accounting for the effect of temperature and the chemical potential on the lattice constant of the 2D layer using the Gibbs-Duhem equation [E. A. Ustinov, J. Chem. Phys. 140, 074706 (2014)]. The technique has allowed for determination of phase diagrams of 2D argon layers on the uniform surface and in slit pores. This paper extends the developed methodology on systems accounting for the periodic modulation of the substrate potential. The main advantage of the developed approach is that it provides highly accurate evaluation of the chemical potential of crystalline layers, which allows reliable determination of temperature and other parameters of various 2D phase transitions. Applicability of the methodology is demonstrated on the krypton-graphite system. Analysis of phase diagram of the krypton molecular layer, thermodynamic functions of coexisting phases, and a method of prediction of adsorption isotherms is considered accounting for a compression of the graphite due to the krypton-carbon interaction. The temperature and heat of C-IC transition has been reliably determined for the gas-solid and solid-solid system. PMID:25296827

  5. Effective and accurate approach for modeling of commensurate–incommensurate transition in krypton monolayer on graphite

    SciTech Connect

    Ustinov, E. A.

    2014-10-07

    Commensurate–incommensurate (C-IC) transition of krypton molecular layer on graphite received much attention in recent decades in theoretical and experimental researches. However, there still exists a possibility of generalization of the phenomenon from thermodynamic viewpoint on the basis of accurate molecular simulation. Recently, a new technique was developed for analysis of two-dimensional (2D) phase transitions in systems involving a crystalline phase, which is based on accounting for the effect of temperature and the chemical potential on the lattice constant of the 2D layer using the Gibbs–Duhem equation [E. A. Ustinov, J. Chem. Phys. 140, 074706 (2014)]. The technique has allowed for determination of phase diagrams of 2D argon layers on the uniform surface and in slit pores. This paper extends the developed methodology on systems accounting for the periodic modulation of the substrate potential. The main advantage of the developed approach is that it provides highly accurate evaluation of the chemical potential of crystalline layers, which allows reliable determination of temperature and other parameters of various 2D phase transitions. Applicability of the methodology is demonstrated on the krypton–graphite system. Analysis of phase diagram of the krypton molecular layer, thermodynamic functions of coexisting phases, and a method of prediction of adsorption isotherms is considered accounting for a compression of the graphite due to the krypton–carbon interaction. The temperature and heat of C-IC transition has been reliably determined for the gas–solid and solid–solid system.

  6. An Accurate Quartic Force Field and Vibrational Frequencies for HNO and DNO

    NASA Technical Reports Server (NTRS)

    Dateo, Christopher E.; Lee, Timothy J.; Schwenke, David W.

    1994-01-01

    An accurate ab initio quartic force field for HNO has been determined using the singles and doubles coupled-cluster method that includes a perturbational estimate of the effects of connected triple excitations, CCSD(T), in conjunction with the correlation consistent polarized valence triple zeta (cc-pVTZ) basis set. Improved harmonic frequencies were determined with the cc-pVQZ basis set. Fundamental vibrational frequencies were determined using a second-order perturbation theory analysis and also using variational calculations. The N-0 stretch and bending fundamentals are determined well from both vibrational analyses. The H-N stretch, however, is shown to have an unusually large anharmonic correction, and is not well determined using second-order perturbation theory. The H-N fundamental is well determined from the variational calculations, demonstrating the quality of the ab initio quartic force field. The zero-point energy of HNO that should be used in isodesmic reactions is also discussed.

  7. The Calculation of Accurate Harmonic Frequencies of Large Molecules: The Polycyclic Aromatic Hydrocarbons, a Case Study

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Arnold, James O. (Technical Monitor)

    1996-01-01

    The vibrational frequencies and infrared intensities of naphthalene neutral and cation are studied at the self-consistent-field (SCF), second-order Moller-Plesset (MP2), and density functional theory (DFT) levels using a variety of one-particle basis sets. Very accurate frequencies can be obtained at the DFT level in conjunction with large basis sets if they are scaled with two factors, one for the C-H stretches and a second for all other modes. We also find remarkably good agreement at the B3LYP/4-31G level using only one scale factor. Unlike the neutral PAHs where all methods do reasonably well for the intensities, only the DFT results are accurate for the PAH cations. The failure of the SCF and MP2 methods is caused by symmetry breaking and an inability to describe charge delocalization. We present several interesting cases of symmetry breaking in this study. An assessment is made as to whether an ensemble of PAH neutrals or cations could account for the unidentified infrared bands observed in many astronomical sources.

  8. Ab Initio Potential Energy Surfaces and the Calculation of Accurate Vibrational Frequencies

    NASA Technical Reports Server (NTRS)

    Lee, Timothy J.; Dateo, Christopher E.; Martin, Jan M. L.; Taylor, Peter R.; Langhoff, Stephen R. (Technical Monitor)

    1995-01-01

    Due to advances in quantum mechanical methods over the last few years, it is now possible to determine ab initio potential energy surfaces in which fundamental vibrational frequencies are accurate to within plus or minus 8 cm(exp -1) on average, and molecular bond distances are accurate to within plus or minus 0.001-0.003 Angstroms, depending on the nature of the bond. That is, the potential energy surfaces have not been scaled or empirically adjusted in any way, showing that theoretical methods have progressed to the point of being useful in analyzing spectra that are not from a tightly controlled laboratory environment, such as vibrational spectra from the interstellar medium. Some recent examples demonstrating this accuracy will be presented and discussed. These include the HNO, CH4, C2H4, and ClCN molecules. The HNO molecule is interesting due to the very large H-N anharmonicity, while ClCN has a very large Fermi resonance. The ab initio studies for the CH4 and C2H4 molecules present the first accurate full quartic force fields of any kind (i.e., whether theoretical or empirical) for a five-atom and six-atom system, respectively.

  9. Precise Measurement of Vibrational Transition Frequency of Optically Trapped Molecules

    NASA Astrophysics Data System (ADS)

    Kajita, Masatoshi; Gopakumar, Geetha; Abe, Minori; Hada, Masahiko

    2013-06-01

    We propose to measure the X^{2}Σ(v,N,F,M) =( 0,0,3/2,±3/2) →( v_{u},0,3/2,±3/2) ( v_{u}=1,2,3,4,,,,) transition frequencies of X^{6}Li molecules with the uncertainty lower than 10^{-16} (X: ^{174}Yb, ^{88}Sr, ^{40}Ca). Molecules are produced by photo-association of cold atoms and trapped in the optical lattices. Measurement with molecules in optical lattices is particularly advantageous for precision measurements because (1) the molecules and probe laser interact for a long time, (2) molecules are localized within the Lamb-Dicke region, (3) the measurement is possible with a large number of molecules, and (4) collision effects are suppressed (molecules are trapped at different positions in 2D lattices). Using the proper trap laser frequency, the Stark shift induced by the trap laser is eliminated as the Stark energy shift of the upper and lower states are equal (magic frequency). When the trap laser frequency is shifted from the magic frequency by 1 MHz, the Stark shift is less than 3×10^{-15}. The N=0→0 transition is one-photon forbidden, and it is stimulated by Raman transition using two lasers. When one of two Raman lasers is higher than the magic frequency and another is lower, the total Stark shift induced by two Raman lasers can be eliminated. Measurement of molecular vibrational transition frequencies is useful to test the variation in the proton-to-electron mass ratio. The ^{1}S_{0}-^{3}% P_{0} transition frequencies of ^{27}Al^{+} ion or ^{87}Sr atom are useful as the reference.

  10. Robust Blind Frequency and Transition Time Estimation for Frequency Hopping Systems

    NASA Astrophysics Data System (ADS)

    Fu, Kuo-Ching; Chen, Yung-Fang

    2010-12-01

    In frequency hopping spread spectrum (FHSS) systems, two major problems are timing synchronization and frequency estimation. A blind estimation scheme is presented for estimating frequency and transition time without using reference signals. The scheme is robust in the sense that it can avoid the unbalanced sampling block problem that occurs in existing maximum likelihood-based schemes, which causes large errors in one of the estimates of frequency. The proposed scheme has a lower computational cost than the maximum likelihood-based greedy search method. The estimated parameters are also used for the subsequent time and frequency tracking. The simulation results demonstrate the efficacy of the proposed approach.

  11. Amplitude Variation of Bottom Simulating Reflection with Respect to Frequency - Transitional Base or Attenuation?

    USGS Publications Warehouse

    Lee, Myung W.

    2007-01-01

    The amplitude of a bottom simulating reflection (BSR), which occurs near the phase boundary between gas hydrate-bearing sediments and underlying gas-filled sediments, strongly depends on the frequency content of a seismic signal, as well as the impedance contrast across the phase boundary. A strong-amplitude BSR, detectable in a conventional seismic profile, is a good indicator of the presence of free gas beneath the phase boundary. However, the BSR as observed in low-frequency multichannel seismic data is generally difficult to identify in high-frequency, single-channel seismic data. To investigate the frequency dependence of BSR amplitudes, single-channel seismic data acquired with an air gun source at Blake Ridge, which is located off the shore of South Carolina, were analyzed in the frequency range of 10-240 Hz. The frequency-dependent impedance contrast caused by the velocity dispersion in partially gas saturated sediments is important to accurately analyze BSR amplitude. Analysis indicates that seismic attenuation of gas hydrate-bearing sediments, velocity dispersion, and a transitional base all contribute to the frequency-dependent BSR amplitude variation in the frequency range of 10-500 Hz. When velocity dispersion is incorporated into the BSR amplitude analysis, the frequency-dependent BSR amplitude at Blake Ridge can be explained with gas hydrate-bearing sediments having a quality factor of about 250 and a transitional base with a thickness of about 1 meter.

  12. An accurate 3D inspection system using heterodyne multiple frequency phase-shifting algorithm

    NASA Astrophysics Data System (ADS)

    Xiao, Zhenzhong; Chee, Oichoo; Asundi, Anand

    This paper presents an accurate 3D inspection system for industrial applications, which uses digital fringe projection technology. The system consists of two CCD cameras and a DLP projector. The mathematical model of the 3D inspection system with 10 distortion parameters for each camera is proposed. A heterodyne multiple frequency phase-shifting algorithm is employed for overcoming the unwrapping problem of phase functions and for a reliable unwrapping procedure. The redundant phase information is used to increase the accuracy of the 3D reconstruction. To demonstrate the effectiveness of our system, a standard sphere was used for testing. The verification test for the 3D inspection systems are based on the VDI standard 2634. The result shows the proposed system can be used for industrial quality inspection with high measurement precision.

  13. Accurate formula for dissipative interaction in frequency modulation atomic force microscopy

    SciTech Connect

    Suzuki, Kazuhiro; Matsushige, Kazumi; Yamada, Hirofumi; Kobayashi, Kei; Labuda, Aleksander

    2014-12-08

    Much interest has recently focused on the viscosity of nano-confined liquids. Frequency modulation atomic force microscopy (FM-AFM) is a powerful technique that can detect variations in the conservative and dissipative forces between a nanometer-scale tip and a sample surface. We now present an accurate formula to convert the dissipation power of the cantilever measured during the experiment to damping of the tip-sample system. We demonstrated the conversion of the dissipation power versus tip-sample separation curve measured using a colloidal probe cantilever on a mica surface in water to the damping curve, which showed a good agreement with the theoretical curve. Moreover, we obtained the damping curve from the dissipation power curve measured on the hydration layers on the mica surface using a nanometer-scale tip, demonstrating that the formula allows us to quantitatively measure the viscosity of a nano-confined liquid using FM-AFM.

  14. Accurate formula for dissipative interaction in frequency modulation atomic force microscopy

    NASA Astrophysics Data System (ADS)

    Suzuki, Kazuhiro; Kobayashi, Kei; Labuda, Aleksander; Matsushige, Kazumi; Yamada, Hirofumi

    2014-12-01

    Much interest has recently focused on the viscosity of nano-confined liquids. Frequency modulation atomic force microscopy (FM-AFM) is a powerful technique that can detect variations in the conservative and dissipative forces between a nanometer-scale tip and a sample surface. We now present an accurate formula to convert the dissipation power of the cantilever measured during the experiment to damping of the tip-sample system. We demonstrated the conversion of the dissipation power versus tip-sample separation curve measured using a colloidal probe cantilever on a mica surface in water to the damping curve, which showed a good agreement with the theoretical curve. Moreover, we obtained the damping curve from the dissipation power curve measured on the hydration layers on the mica surface using a nanometer-scale tip, demonstrating that the formula allows us to quantitatively measure the viscosity of a nano-confined liquid using FM-AFM.

  15. Accurate Time/Frequency Transfer Method Using Bi-Directional WDM Transmission

    NASA Technical Reports Server (NTRS)

    Imaoka, Atsushi; Kihara, Masami

    1996-01-01

    An accurate time transfer method is proposed using b-directional wavelength division multiplexing (WDM) signal transmission along a single optical fiber. This method will be used in digital telecommunication networks and yield a time synchronization accuracy of better than 1 ns for long transmission lines over several tens of kilometers. The method can accurately measure the difference in delay between two wavelength signals caused by the chromatic dispersion of the fiber in conventional simple bi-directional dual-wavelength frequency transfer methods. We describe the characteristics of this difference in delay and then show that the accuracy of the delay measurements can be obtained below 0.1 ns by transmitting 156 Mb/s times reference signals of 1.31 micrometer and 1.55 micrometers along a 50 km fiber using the proposed method. The sub-nanosecond delay measurement using the simple bi-directional dual-wavelength transmission along a 100 km fiber with a wavelength spacing of 1 nm in the 1.55 micrometer range is also shown.

  16. Measurement of the lowest millimeter-wave transition frequency of the CH radical

    SciTech Connect

    Truppe, S.; Hendricks, R. J.; Hinds, E. A.; Tarbutt, M. R.

    2014-01-01

    The CH radical offers a sensitive way to test the hypothesis that fundamental constants measured on Earth may differ from those observed in other parts of the universe. The starting point for such a comparison is to have accurate laboratory frequencies. Here, we measure the frequency of the lowest millimeter-wave transition of CH, near 535 GHz, with an accuracy of 0.6 kHz. This improves the uncertainty by roughly two orders of magnitude over previous determinations and opens the way for sensitive new tests of varying constants.

  17. Frequency and amplitude transitioned waveforms mitigate the onset response in high frequency nerve block

    PubMed Central

    Gerges, Meana; Foldes, Emily L.; Ackermann, D. Michael; Bhadra, Narendra; Bhadra, Niloy; Kilgore, Kevin L.

    2010-01-01

    High frequency alternating currents (HFAC) have proven to be a reversible and rapid method of blocking peripheral nerve conduction, holding promise for treatment of disorders associated with undesirable neuronal activity. The delivery of HFAC is characterized by a transient period of neural firing at its inception, termed the “onset response”. The onset response is minimized for higher frequencies and higher amplitudes, but requires larger currents. However, complete block can be maintained at lower frequencies and amplitudes, using lower currents. In this in-vivo study on whole mammalian peripheral nerves, we demonstrate a method to minimize the onset response by initiating the block using a stimulation paradigm with a high frequency and large amplitude, and then transitioning to a low frequency and low amplitude waveform, reducing the currents required to maintain the conduction block. In five of six animals it was possible to transition from a 30 kHz to a 10 kHz waveform without inducing any transient neural firing. The minimum transition time was 0.03 sec. Transition activity was minimized or eliminated with longer transition times. The results of this study show that this method is feasible for achieving a nerve block with minimal onset responses and current amplitude requirements. PMID:20966536

  18. Recommended Rest Frequencies for Observed Interstellar Molecular Microwave Transitions - 2002 Revision

    National Institute of Standards and Technology Data Gateway

    SRD 116 NIST Recommended Rest Frequencies for Observed Interstellar Molecular Microwave Transitions - 2002 Revision (Web, free access)   Critically evaluated transition frequencies for the molecular transitions detected in interstellar and circumstellar clouds are presented.

  19. Towards more accurate numerical modeling of impedance based high frequency harmonic vibration

    NASA Astrophysics Data System (ADS)

    Lim, Yee Yan; Kiong Soh, Chee

    2014-03-01

    The application of smart materials in various fields of engineering has recently become increasingly popular. For instance, the high frequency based electromechanical impedance (EMI) technique employing smart piezoelectric materials is found to be versatile in structural health monitoring (SHM). Thus far, considerable efforts have been made to study and improve the technique. Various theoretical models of the EMI technique have been proposed in an attempt to better understand its behavior. So far, the three-dimensional (3D) coupled field finite element (FE) model has proved to be the most accurate. However, large discrepancies between the results of the FE model and experimental tests, especially in terms of the slope and magnitude of the admittance signatures, continue to exist and are yet to be resolved. This paper presents a series of parametric studies using the 3D coupled field finite element method (FEM) on all properties of materials involved in the lead zirconate titanate (PZT) structure interaction of the EMI technique, to investigate their effect on the admittance signatures acquired. FE model updating is then performed by adjusting the parameters to match the experimental results. One of the main reasons for the lower accuracy, especially in terms of magnitude and slope, of previous FE models is the difficulty in determining the damping related coefficients and the stiffness of the bonding layer. In this study, using the hysteretic damping model in place of Rayleigh damping, which is used by most researchers in this field, and updated bonding stiffness, an improved and more accurate FE model is achieved. The results of this paper are expected to be useful for future study of the subject area in terms of research and application, such as modeling, design and optimization.

  20. The 10 Hz Frequency: A Fulcrum For Transitional Brain States

    PubMed Central

    Garcia-Rill, E.; D’Onofrio, S.; Luster, B.; Mahaffey, S.; Urbano, F. J.; Phillips, C.

    2016-01-01

    A 10 Hz rhythm is present in the occipital cortex when the eyes are closed (alpha waves), in the precentral cortex at rest (mu rhythm), in the superior and middle temporal lobe (tau rhythm), in the inferior olive (projection to cerebellar cortex), and in physiological tremor (underlying all voluntary movement). These are all considered resting rhythms in the waking brain which are “replaced” by higher frequency activity with sensorimotor stimulation. That is, the 10 Hz frequency fulcrum is replaced on the one hand by lower frequencies during sleep, or on the other hand by higher frequencies during volition and cognition. The 10 Hz frequency fulcrum is proposed as the natural frequency of the brain during quiet waking, but is replaced by higher frequencies capable of permitting more complex functions, or by lower frequencies during sleep and inactivity. At the center of the transition shifts to and from the resting rhythm is the reticular activating system, a phylogenetically preserved area of the brain essential for preconscious awareness.

  1. Diffusion Monte Carlo for Accurate Dissociation Energies of 3d Transition Metal Containing Molecules.

    PubMed

    Doblhoff-Dier, Katharina; Meyer, Jörg; Hoggan, Philip E; Kroes, Geert-Jan; Wagner, Lucas K

    2016-06-14

    Transition metals and transition metal compounds are important to catalysis, photochemistry, and many superconducting systems. We study the performance of diffusion Monte Carlo (DMC) applied to transition metal containing dimers (TMCDs) using single-determinant Slater-Jastrow trial wavefunctions and investigate the possible influence of the locality and pseudopotential errors. We find that the locality approximation can introduce nonsystematic errors of up to several tens of kilocalories per mole in the absolute energy of Cu and CuH if Ar or Mg core pseudopotentials (PPs) are used for the 3d transition metal atoms. Even for energy differences such as binding energies, errors due to the locality approximation can be problematic if chemical accuracy is sought. The use of the Ne core PPs developed by Burkatzki et al. (J. Chem. Phys. 2008, 129, 164115), the use of linear energy minimization rather than unreweighted variance minimization for the optimization of the Jastrow function, and the use of large Jastrow parametrizations reduce the locality errors. In the second section of this article, we study the general performance of DMC for 3d TMCDs using a database of binding energies of 20 TMCDs, for which comparatively accurate experimental data is available. Comparing our DMC results to these data for our results that compare best with experiment, we find a mean unsigned error (MUE) of 4.5 kcal/mol. This compares well with the achievable accuracy in CCSDT(2)Q (MUE = 4.6 kcal/mol) and the best all-electron DFT results (MUE = 4.5 kcal/mol) for the same set of systems (Truhlar et al. J. Chem. Theory Comput. 2015, 11, 2036-2052). The mean errors in DMC depend less on the exchange-correlation functionals used to generate the trial wavefunction than the corresponding mean errors in the underlying DFT calculations. Furthermore, the QMC results obtained for each molecule individually vary less with the functionals used. These observations are relevant for systems such as

  2. nu-2 band of H2 O-16 - Line strengths and transition frequencies

    NASA Technical Reports Server (NTRS)

    Toth, Robert A.

    1991-01-01

    High-resolution spectra of H2 O-16 were recorded with a Fourier-transform spectrometer covering transitions in the (010)-(000) band from 1066 to 2582/cm. The measured line frequencies were used along with additional data taken from studies at microwave and far-infrared frequencies in an analysis to obtain rotational energies of levels in the (000) and (010) states. Measurements of the line strengths were fitted by least squares to a model in which the dipole moment matrix elements were represented by as many as 19 expansion coefficients. The results produced computed line strength values that are in excellent agreement, on the average, with the 874 experimental transitions included in the analysis. These results provide a more accurate representation of the line positions and strengths for the (010)-(000) band than are currently available on the HITRAN absorption line parameter compilation.

  3. Precise Measurement of ^{40}CaH^{+} Vibrational Transition Frequency

    NASA Astrophysics Data System (ADS)

    Kajita, Masatoshi; Abe, Minori

    2013-06-01

    Small number of molecular ions in a linear trap can be sympathetically cooled with atomic ions and form a string crystal at the position, where the electric field is zero. Molecular ions in a strinc crystal are advantageous to measure the transition frequencies without Stark shift induced by the trap electric field, but it is required to localize small number of molecular ions in a single quantum state. ^{40}CaH^{+} molecular ion is advantageous to solve this problem, because (1) molecular ion with rotational constant of 141 GHz is localized in the vibrational-rotational ground state when the surrounding temperature is lower than 10 K, and (2) there is no hyperfine splitting in the J=0 state. In this presentation, we porpose to measure the ^{40}CaH^{+} X^{1}% Σ( v,N,F,M) =(0,0,1/2,±1/2) → (v_{u},0,1/2,±1/2) (v_{u}=1,2,3,,,) transition with the uncertainty lower than 10^{-16}. With these transitions, Zeeman shift is less than 10^{-16}/G (given by the slight dependence of schielding effect by electron cloud on the vibrational state) and electric quadrupole shift is zero because of F=1/2. The J=0→0 transition is one-photon forbidden, and it can be observed also by Raman transition using two lasers. Stark shift induced by Raman lasers actually dominates the measurement uncertainty. When v=0→1 transition is observed using Raman lasers in the 6000-15000 /cm, Stark shift with saturation power is of the order of 1.5×10^{-14} and it is higher for overtone transitions. With the following Raman laser frequencies, total Stark shift induced by two Raman lasers is zero. v=0→1 24527 /cm and 23079 /cm v=0→2 24600 /cm and 21745 /cm v=0→3 26237 /cm and 22017 /cm v=0→4 25354 /cm and 19814 /cm The ^{40}CaH^{+} X^{1}Σ( v,N,F,M) =(0,0,1/2,±1/2) →(v_{u},0,1/2,±1/2) (v_{u}=1,2,3,,,) transition can be measured with the uncertainty lower than 10^{-16}, and it is useful to test the variation in the proton-to-electron mass ratio.

  4. Accurate nonrelativistic ground-state energies of 3d transition metal atoms

    SciTech Connect

    Scemama, A.; Applencourt, T.; Giner, E.; Caffarel, M.

    2014-12-28

    We present accurate nonrelativistic ground-state energies of the transition metal atoms of the 3d series calculated with Fixed-Node Diffusion Monte Carlo (FN-DMC). Selected multi-determinantal expansions obtained with the CIPSI (Configuration Interaction using a Perturbative Selection made Iteratively) method and including the most prominent determinants of the full configuration interaction expansion are used as trial wavefunctions. Using a maximum of a few tens of thousands determinants, fixed-node errors on total DMC energies are found to be greatly reduced for some atoms with respect to those obtained with Hartree-Fock nodes. To the best of our knowledge, the FN-DMC/(CIPSI nodes) ground-state energies presented here are the lowest variational total energies reported so far. They differ from the recently recommended non-variational values of McCarthy and Thakkar [J. Chem. Phys. 136, 054107 (2012)] only by a few percents of the correlation energy. Thanks to the variational property of FN-DMC total energies, our results provide exact lower bounds for the absolute value of all-electron correlation energies, |E{sub c}|.

  5. Measurement of the muonium 1S-2S transition frequency

    SciTech Connect

    Jungmann, K.; Baird, P. E. G.; Barr, J. R. M.; Berkeland, D.; Boshier, M. G.; Braun, B.; Eaton, G. H.; Ferguson, A. I.; Geerds, H.; Hughes, V. W.; Maas, F.; Matthias, B. E.; Matousek, P.; Persaud, M.; Putlitz, G. zu; Reinhard, I.; Riis, E.; Sandars, P. G. H.; Schwarz, W.; Toner, W. T.

    1995-04-01

    Resonant ionization spectroscopy has been employed for measuring the 1{sup 2}S1/2-2{sup 2}S1/2 frequency difference in the hydrogen-like muonium atom to 2 455 529 002(33)(46) MHz. The 1S-2S two-photon transition was induced Doppler-free using two counter-propagating laser beams. The 2S state was photo-ionized by a third photon from the same laser field. The measurement agrees with QED theory within two standard deviations. The mass of the positive muon can be extracted from the isotope shifts in this transition to hydrogen and deuterium to 105.658 80(29)(43) MeV/c{sup 2}.

  6. Measurement of the muonium 1S-2S transition frequency

    SciTech Connect

    Jungmann, K.; Baird, P.E.G.; Barr, J.R.M.; Berkeland, D.; Boshier, M.G.; Braun, B.; Eaton, G.H.; Ferguson, A.I.; Geerds, H.; Hughes, V.W.; Maas, F.; Matthias, B.E.; Matousek, P.; Persaud, M.; zu Putlitz, G.; Reinhard, I.; Riis, E.; Sandars, P.G.H.; Schwarz, W.; Toner, W.T.; Towrie, M.; Willmann, L.; Woodle, K.A.; Woodman, G.

    1995-04-01

    Resonant ionization spectroscopy has been employed for measuring the 1{sup 2}{ital S}{sub 1/2}{minus}2{sup 2}{ital S}{sub 1/2} frequency difference in the hydrogen-like muonium atom to 2 455 529 002(33)(46) MHz. The 1S-2S two-photon transition was induced Doppler-free using two counter-propagating laser beams. The 2S state was photo-ionized by a third photon from the same laser field. The measurement agrees with QED theory within two standard deviations. The mass of the positive muon can be extracted from the isotope shifts in this transition to hydrogen and deuterium to 105.658 80(29)(43) MeV/c{sup 2}. {copyright} 1995 {ital American} {ital Institute} {ital of} {ital Physics}

  7. Direct frequency comb optical frequency standard based on two-photon transitions of thermal atoms.

    PubMed

    Zhang, S Y; Wu, J T; Zhang, Y L; Leng, J X; Yang, W P; Zhang, Z G; Zhao, J Y

    2015-01-01

    Optical clocks have been the focus of science and technology research areas due to their capability to provide highest frequency accuracy and stability to date. Their superior frequency performance promises significant advances in the fields of fundamental research as well as practical applications including satellite-based navigation and ranging. In traditional optical clocks, ultrastable optical cavities, laser cooling and particle (atoms or a single ion) trapping techniques are employed to guarantee high stability and accuracy. However, on the other hand, they make optical clocks an entire optical tableful of equipment, and cannot work continuously for a long time; as a result, they restrict optical clocks used as very convenient and compact time-keeping clocks. In this article, we proposed, and experimentally demonstrated, a novel scheme of optical frequency standard based on comb-directly-excited atomic two-photon transitions. By taking advantage of the natural properties of the comb and two-photon transitions, this frequency standard achieves a simplified structure, high robustness as well as decent frequency stability, which promise widespread applications in various scenarios. PMID:26459877

  8. Direct frequency comb optical frequency standard based on two-photon transitions of thermal atoms

    PubMed Central

    Zhang, S. Y.; Wu, J. T.; Zhang, Y. L.; Leng, J. X.; Yang, W. P.; Zhang, Z. G.; Zhao, J. Y.

    2015-01-01

    Optical clocks have been the focus of science and technology research areas due to their capability to provide highest frequency accuracy and stability to date. Their superior frequency performance promises significant advances in the fields of fundamental research as well as practical applications including satellite-based navigation and ranging. In traditional optical clocks, ultrastable optical cavities, laser cooling and particle (atoms or a single ion) trapping techniques are employed to guarantee high stability and accuracy. However, on the other hand, they make optical clocks an entire optical tableful of equipment, and cannot work continuously for a long time; as a result, they restrict optical clocks used as very convenient and compact time-keeping clocks. In this article, we proposed, and experimentally demonstrated, a novel scheme of optical frequency standard based on comb-directly-excited atomic two-photon transitions. By taking advantage of the natural properties of the comb and two-photon transitions, this frequency standard achieves a simplified structure, high robustness as well as decent frequency stability, which promise widespread applications in various scenarios. PMID:26459877

  9. Measurements of the frequency spectrum of transition radiation

    NASA Technical Reports Server (NTRS)

    Cherry, M. L.; Mueller, D.

    1977-01-01

    We report a measurement of the frequency spectrum of X-ray transition radiation. X rays were generated by electrons of 5 and 9 GeV in radiators of multiple polypropylene foils, and detected in the range 4 to 30 keV with a calibrated single-crystal Bragg spectrometer. The experimental results closely reproduce the features of the theoretically predicted spectrum. In particular, the pronounced interference pattern of multifoil radiators and the expected hardening of the radiation with increasing foil thickness are clearly observed. The overall intensity of the radiation is somewhat lower than predicted by calculations.

  10. Accurate determination of the superfluid-insulator transition in the one-dimensional Bose-Hubbard model

    NASA Astrophysics Data System (ADS)

    Zakrzewski, Jakub; Delande, Dominique

    2008-11-01

    The quantum phase transition point between the insulator and the superfluid phase at unit filling factor of the infinite one-dimensional Bose-Hubbard model is numerically computed with a high accuracy. The method uses the infinite system version of the time evolving block decimation algorithm, here tested in a challenging case. We provide also the accurate estimate of the phase transition point at double occupancy.

  11. A Proposed Frequency Synthesis Approach to Accurately Measure the Angular Position of a Spacecraft

    NASA Technical Reports Server (NTRS)

    Bagri, D. S.

    2005-01-01

    This article describes an approach for measuring the angular position of a spacecraft with reference to a nearby calibration source (quasar) with an accuracy of a few tenths of a nanoradian using a very long baseline interferometer of two antennas that measures the interferometer phase with a modest accuracy. It employs (1) radio frequency phase to determine the spacecraft position with high precision and (2) multiple delay measurements using either frequency tones or telemetry signals at different frequency spacings to resolve ambiguity of the location of the fringe (cycle) containing the direction of the spacecraft.

  12. Absolute frequency and isotope shift of the magnesium (3 s2) 1S0→(3 s 3 d ) 1D2 two-photon transition by direct frequency-comb spectroscopy

    NASA Astrophysics Data System (ADS)

    Peters, E.; Reinhardt, S.; Hänsch, Th. W.; Udem, Th.

    2015-12-01

    We use a picosecond frequency-doubled mode-locked titanium sapphire laser to generate a frequency comb at 431 nm in order to probe the (3 s2) 1S0 →(3 s 3 d ) 1D2 transition in atomic magnesium. Using a second, self-referenced femtosecond frequency comb, the absolute transition frequency and the 24Mg and 26Mg isotope shift is determined relative to a global-positioning-system-referenced hydrogen maser. Our result for the transition frequency of the main isotope 24Mg of 1 391 128 606.14 (12 ) MHz agrees with previous measurements and reduces its uncertainty by four orders of magnitude. For the isotope shift we find δ ν26 ,24=3915.13 (39 ) MHz. Accurate values for transition frequencies in Mg are relevant in astrophysics and to test atomic structure calculations.

  13. Simultaneous transmission of accurate time and stable frequency through bidirectional channel over telecommunication infrastructure with excessive spans

    NASA Astrophysics Data System (ADS)

    Vojtech, Josef; Smotlacha, Vladimir; Skoda, Pavel

    2015-09-01

    In this paper, we present simultaneous transmission of accurate time and stable frequency over 306 km long fiber link. The fiber link belongs to the Time and Frequency infrastructure that is being gradually developed and which shares fiber footprint with data network. The link had been originally deployed with wavelength division multiplexing systems for C and L band systems. But it has been recently upgraded to support 800 GHz wide super-channel with single signal path for both directions. This bidirectional super-channel spans over two extensive segments with attenuation of 28 and 25 dB.

  14. ACCURATE ESTIMATIONS OF STELLAR AND INTERSTELLAR TRANSITION LINES OF TRIPLY IONIZED GERMANIUM

    SciTech Connect

    Dutta, Narendra Nath; Majumder, Sonjoy E-mail: sonjoy@gmail.com

    2011-08-10

    In this paper, we report on weighted oscillator strengths of E1 transitions and transition probabilities of E2 transitions among different low-lying states of triply ionized germanium using highly correlated relativistic coupled cluster (RCC) method. Due to the abundance of Ge IV in the solar system, planetary nebulae, white dwarf stars, etc., the study of such transitions is important from an astrophysical point of view. The weighted oscillator strengths of E1 transitions are presented in length and velocity gauge forms to check the accuracy of the calculations. We find excellent agreement between calculated and experimental excitation energies. Oscillator strengths of few transitions, wherever studied in the literature via other theoretical and experimental approaches, are compared with our RCC calculations.

  15. Accurate calculation of vibrational frequencies using explicitly correlated coupled-cluster theory.

    PubMed

    Rauhut, Guntram; Knizia, Gerald; Werner, Hans-Joachim

    2009-02-01

    The recently proposed explicitly correlated CCSD(T)-F12x (x = a,b) approximations [T. B. Adler, G. Knizia, and H.-J. Werner, J. Chem. Phys. 127, 221106 (2007)] are applied to compute equilibrium structures and harmonic as well as anharmonic vibrational frequencies for H(2)O, HCN, CO(2), CH(2)O, H(2)O(2), C(2)H(2), CH(2)NH, C(2)H(2)O, and the trans-isomer of 1,2-C(2)H(2)F(2). Using aug-cc-pVTZ basis sets, the CCSD(T)-F12a equilibrium geometries and harmonic vibrational frequencies are in very close agreement with CCSD(T)/aug-cc-pV5Z values. The anharmonic frequencies are evaluated using vibrational self-consistent field and vibrational configuration interaction methods based on automatically generated potential energy surfaces. The mean absolute deviation of the CCSD(T)-F12a/aug-cc-pVTZ anharmonic frequencies from experimental values amounts to only 4.0 cm(-1). PMID:19206956

  16. Molecular Simulation of the Free Energy for the Accurate Determination of Phase Transition Properties of Molecular Solids

    NASA Astrophysics Data System (ADS)

    Sellers, Michael; Lisal, Martin; Brennan, John

    2015-06-01

    Investigating the ability of a molecular model to accurately represent a real material is crucial to model development and use. When the model simulates materials in extreme conditions, one such property worth evaluating is the phase transition point. However, phase transitions are often overlooked or approximated because of difficulty or inaccuracy when simulating them. Techniques such as super-heating or super-squeezing a material to induce a phase change suffer from inherent timescale limitations leading to ``over-driving,'' and dual-phase simulations require many long-time runs to seek out what frequently results in an inexact location of phase-coexistence. We present a compilation of methods for the determination of solid-solid and solid-liquid phase transition points through the accurate calculation of the chemical potential. The methods are applied to the Smith-Bharadwaj atomistic potential's representation of cyclotrimethylene trinitramine (RDX) to accurately determine its melting point (Tm) and the alpha to gamma solid phase transition pressure. We also determine Tm for a coarse-grain model of RDX, and compare its value to experiment and atomistic counterpart. All methods are employed via the LAMMPS simulator, resulting in 60-70 simulations that total 30-50 ns. Approved for public release. Distribution is unlimited.

  17. WWVB: A Half Century of Delivering Accurate Frequency and Time by Radio

    PubMed Central

    Lombardi, Michael A; Nelson, Glenn K

    2014-01-01

    In commemoration of its 50th anniversary of broadcasting from Fort Collins, Colorado, this paper provides a history of the National Institute of Standards and Technology (NIST) radio station WWVB. The narrative describes the evolution of the station, from its origins as a source of standard frequency, to its current role as the source of time-of-day synchronization for many millions of radio controlled clocks. PMID:26601026

  18. Frequency comb assisted measurement of fundamental transitions of cold H3+, H2D+ and D2H+

    NASA Astrophysics Data System (ADS)

    Jusko, Pavol; Konietzko, Christoph; Schlemmer, Stephan; Asvany, Oskar

    2016-01-01

    H3+ and two of its deuterated variants have been trapped and cooled in a 4 K trap machine, and their fundamental vibrational transitions probed with the laser induced reactions method. With the help of a frequency comb system the line centers are determined with high accuracy and precision, typically well below 1 MHz. For the deuterated variants, ground state combination differences allow for comparison with existing rotational THz data, and the accurate prediction thereof.

  19. Accurate vibrational frequencies using the self-consistent-charge density-functional tight-binding method

    NASA Astrophysics Data System (ADS)

    Małolepsza, Edyta; Witek, Henryk A.; Morokuma, Keiji

    2005-09-01

    An optimization technique for enhancing the quality of repulsive two-body potentials of the self-consistent-charge density-functional tight-binding (SCC-DFTB) method is presented and tested. The new, optimized potentials allow for significant improvement of calculated harmonic vibrational frequencies. Mean absolute deviation from experiment computed for a group of 14 hydrocarbons is reduced from 59.0 to 33.2 cm -1 and maximal absolute deviation, from 436.2 to 140.4 cm -1. A drawback of the new family of potentials is a lower quality of reproduced geometrical and energetic parameters.

  20. Highly Accurate Frequency Calculations of Crab Cavities Using the VORPAL Computational Framework

    SciTech Connect

    Austin, T.M.; Cary, J.R.; Bellantoni, L.; /Argonne

    2009-05-01

    We have applied the Werner-Cary method [J. Comp. Phys. 227, 5200-5214 (2008)] for extracting modes and mode frequencies from time-domain simulations of crab cavities, as are needed for the ILC and the beam delivery system of the LHC. This method for frequency extraction relies on a small number of simulations, and post-processing using the SVD algorithm with Tikhonov regularization. The time-domain simulations were carried out using the VORPAL computational framework, which is based on the eminently scalable finite-difference time-domain algorithm. A validation study was performed on an aluminum model of the 3.9 GHz RF separators built originally at Fermi National Accelerator Laboratory in the US. Comparisons with measurements of the A15 cavity show that this method can provide accuracy to within 0.01% of experimental results after accounting for manufacturing imperfections. To capture the near degeneracies two simulations, requiring in total a few hours on 600 processors were employed. This method has applications across many areas including obtaining MHD spectra from time-domain simulations.

  1. TTVFast: An efficient and accurate code for transit timing inversion problems

    SciTech Connect

    Deck, Katherine M.; Agol, Eric; Holman, Matthew J.; Nesvorný, David

    2014-06-01

    Transit timing variations (TTVs) have proven to be a powerful technique for confirming Kepler planet candidates, for detecting non-transiting planets, and for constraining the masses and orbital elements of multi-planet systems. These TTV applications often require the numerical integration of orbits for computation of transit times (as well as impact parameters and durations); frequently tens of millions to billions of simulations are required when running statistical analyses of the planetary system properties. We have created a fast code for transit timing computation, TTVFast, which uses a symplectic integrator with a Keplerian interpolator for the calculation of transit times. The speed comes at the expense of accuracy in the calculated times, but the accuracy lost is largely unnecessary, as transit times do not need to be calculated to accuracies significantly smaller than the measurement uncertainties on the times. The time step can be tuned to give sufficient precision for any particular system. We find a speed-up of at least an order of magnitude relative to dynamical integrations with high precision using a Bulirsch-Stoer integrator.

  2. Ab initio molecular dynamics with noisy and cheap quantum Monte Carlo forces: accurate calculation of vibrational frequencies

    NASA Astrophysics Data System (ADS)

    Luo, Ye; Sorella, Sandro

    2014-03-01

    We introduce a general and efficient method for the calculation of vibrational frequencies of electronic systems, ranging from molecules to solids. By performing damped molecular dynamics with ab initio forces, we show that quantum vibrational frequencies can be evaluated by diagonalizing the time averaged position-position or force-force correlation matrices, although the ionic motion is treated on the classical level within the Born-Oppenheimer approximation. The novelty of our approach is to evaluate atomic forces with QMC by means of a highly accurate and correlated variational wave function which is optimized simultaneously during the dynamics. QMC is an accurate and promising many-body technique for electronic structure calculation thanks to massively parallel computers. However, since infinite statistics is not feasible, property evaluation may be affected by large noise that is difficult to harness. Our approach controls the QMC stochastic bias systematically and gives very accurate results with moderate computational effort, namely even with noisy forces. We prove the accuracy and efficiency of our method on the water monomer[A. Zen et al., JCTC 9 (2013) 4332] and dimer. We are currently working on the challenging problem of simulating liquid water at ambient conditions.

  3. Accurate quantification of water-macromolecule exchange induced frequency shift: effects of reference substance.

    PubMed

    Leutritz, Tobias; Hilfert, Liane; Smalla, Karl-Heinz; Speck, Oliver; Zhong, Kai

    2013-01-01

    Water-macromolecule exchange induces a bulk water frequency shift contributing to the contrast in phase imaging. For separating the effects of the water-macromolecule exchange and the macromolecule susceptibility, appropriate internal or external references are needed. In this study, two internal reference compounds, 2,2,3,3-tetradeuterio-3-trimethylsilyl-propionate (TMSP) and 1,4-dioxane, were used to study the macromolecule-dependent water frequency shift in a bovine serum albumin (BSA)-water system in detail. For TMSP, the water-macromolecule exchange shift depended on both the BSA and the reference concentration and stabilized to a value of 0.025 ppm/mM (298 K, TMSP concentrations > 30 mM). For dioxane, the dependency of the water-macromolecule exchange shift on the BSA concentration is independent of dioxane at low concentrations. The resulting shift was smaller (0.009 ppm/mM) when compared with using higher TMSP concentrations as reference. This discrepancy might be due to additional dioxane-water interactions. Measurements with an external chloroform reference in a coaxial geometry showed a shift of -0.013 ppm/mM resulting from the opposing effects of macromolecules in water exchange-induced shift and diamagnetic susceptibility shift. All these effects should be considered in the interpretation of tissue phase contrast. From the experimental data, the equilibrium binding constant between BSA and TMSP has been quantified to be K(d) = 1.3 ± 0.4, and the estimated number of interaction sites for BSA is 12.7 ± 2.6. PMID:22374834

  4. A transition radiation detector for RHIC featuring accurate tracking and dE/dx particle identification

    SciTech Connect

    O`Brien, E.; Lissauer, D.; McCorkle, S.; Polychronakos, V.; Takai, H.; Chi, C.Y.; Nagamiya, S.; Sippach, W.; Toy, M.; Wang, D.; Wang, Y.F.; Wiggins, C.; Willis, W.; Cherniatin, V.; Dolgoshein, B.; Bennett, M.; Chikanian, A.; Kumar, S.; Mitchell, J.T.; Pope, K.

    1991-12-31

    We describe the results of a test ran involving a Transition Radiation Detector that can both distinguish electrons from pions which momenta greater titan 0.7 GeV/c and simultaneously track particles passing through the detector. The particle identification is accomplished through a combination of the detection of Transition Radiation from the electron and the differences in electron and pion energy loss (dE/dx) in the detector. The dE/dx particle separation is most, efficient below 2 GeV/c while particle ID utilizing Transition Radiation effective above 1.5 GeV/c. Combined, the electron-pion separation is-better than 5 {times} 10{sup 2}. The single-wire, track-position resolution for the TRD is {approximately}230 {mu}m.

  5. Accurate Cross Sections for Excitation of Resonance Transitions in Atomic Oxygen

    NASA Technical Reports Server (NTRS)

    Tayal, S. S.

    2004-01-01

    Electron collision excitation cross sections for the resonance 2p(sup)4 (sup 3)P-2p(sup 3)3s (sup 3)S(sup 0), 2p(sup 4) (sup 3)P-2p(sup 3)3d (sup 3)D(sup 0), 2p4 (sup 3)P-2p(sup 3)3s (sup 3)D(sup 0), 2p(sup 4) (sup 3)P-2p(sup 3)3s (sup 3)P(sup 0) and 2p(sup 4) (sup 3)P-2s2p(sup 5) (sup 3)P(sup 0) transitions have been calculated by using the R matrix with a pseudostates approach for incident electron energies from near threshold to 100 eV. The excitation of these transition sgives rise to strong atomic oxygen emission features at 1304, 1027, 989, 878, and 792 Angstrom in the spectra of several planetary atmospheres. We included 22 spectroscopic bound and autoionizing states and 30 pseudostates in the close-coupling expansion. The target wave functions are chosen to properly account for the important correlation and relaxation effects. The effect of coupling to the continuum is included through the use of pseudostates. The contribution of the ionization continuum is significant for resonance transitions. Measured absolute direct excitation cross sections of 0 I are reported by experimental groups from the Jet Propulsion Laboratory and Johns Hopkins University. Good agreement is noted for the 2p(sup)4 (sup 3)P-2p(sup 3)3s (sup 3)S(sup 0) transition (lambda 1304 Ang) with measured cross sections from both groups that agree well with each other. There is disagreement between experiments for other transitions. Our results support the measured cross sections from the Johns Hopkins University for the 2p(sup 4) (sup 3)P-2p(sup 3)3d (sup 3)D(sup 0) and 2p4 (sup 3)P-2p(sup 3)3s (sup 3)D(sup 0) transitions, while for the 2p4 (sup 3)P-2p(sup 3)3s (sup 3)D(sup 0) transition the agreement is switched to the measured cross sections from the Jet Propulsion Laboratory.

  6. Elimination of the Stark shift from the vibrational transition frequency of optically trapped {sup 174}Yb{sup 6}Li molecules

    SciTech Connect

    Kajita, Masatoshi; Gopakumar, Geetha; Abe, Minori; Hada, Masahiko

    2011-08-15

    Transition frequencies of cold molecules must be accurately evaluated to test the variance in the proton-to-electron mass ratio. Measuring the X {sup 2}{Sigma}(v,N)=(0,0){yields}(1,0) transition frequency of optically trapped {sup 174}Yb{sup 6}Li molecules is a promising method for achieving this goal. The Stark shifts induced by trap and probe (for the Raman transition) lasers are eliminated by choosing appropriate frequencies (magic frequencies) during the construction of the optical lattice. In the far-off resonance region, the Stark shift is found to be less than 10{sup -16} even when the laser frequencies are detuned from the magic frequencies by {approx}1 MHz.

  7. Self-referenced, accurate and sensitive optical frequency comb spectroscopy with a virtually imaged phased array spectrometer.

    PubMed

    Kowzan, Grzegorz; Lee, Kevin F; Paradowska, Magdalena; Borkowski, Mateusz; Ablewski, Piotr; Wójtewicz, Szymon; Stec, Kamila; Lisak, Daniel; Fermann, Martin E; Trawiński, Ryszard S; Masłowski, Piotr

    2016-03-01

    We present a cavity-enhanced direct optical frequency comb spectroscopy system with a virtually imaged phased array (VIPA) spectrometer and either a dither or a Pound-Drever-Hall (PDH) locking scheme used for stable transmission of the comb through the cavity. A self-referenced scheme for frequency axis calibration is shown along with an analysis of its accuracy. A careful comparison between both locking schemes is performed based on near-IR measurements of the carbon monoxide ν=3←0 band P branch transitions in a gas sample with known composition. The noise-equivalent absorptions (NEA) for the PDH and dither schemes are 9.9×10-10  cm-1 and 5.3×10-9  cm-1, respectively. PMID:26974094

  8. Accurate measurements of cross-plane thermal conductivity of thin films by dual-frequency time-domain thermoreflectance (TDTR)

    NASA Astrophysics Data System (ADS)

    Jiang, Puqing; Huang, Bin; Koh, Yee Kan

    2016-07-01

    Accurate measurements of the cross-plane thermal conductivity Λcross of a high-thermal-conductivity thin film on a low-thermal-conductivity (Λs) substrate (e.g., Λcross/Λs > 20) are challenging, due to the low thermal resistance of the thin film compared with that of the substrate. In principle, Λcross could be measured by time-domain thermoreflectance (TDTR), using a high modulation frequency fh and a large laser spot size. However, with one TDTR measurement at fh, the uncertainty of the TDTR measurement is usually high due to low sensitivity of TDTR signals to Λcross and high sensitivity to the thickness hAl of Al transducer deposited on the sample for TDTR measurements. We observe that in most TDTR measurements, the sensitivity to hAl only depends weakly on the modulation frequency f. Thus, we performed an additional TDTR measurement at a low modulation frequency f0, such that the sensitivity to hAl is comparable but the sensitivity to Λcross is near zero. We then analyze the ratio of the TDTR signals at fh to that at f0, and thus significantly improve the accuracy of our Λcross measurements. As a demonstration of the dual-frequency approach, we measured the cross-plane thermal conductivity of a 400-nm-thick nickel-iron alloy film and a 3-μm-thick Cu film, both with an accuracy of ˜10%. The dual-frequency TDTR approach is useful for future studies of thin films.

  9. Accurate measurements of cross-plane thermal conductivity of thin films by dual-frequency time-domain thermoreflectance (TDTR).

    PubMed

    Jiang, Puqing; Huang, Bin; Koh, Yee Kan

    2016-07-01

    Accurate measurements of the cross-plane thermal conductivity Λcross of a high-thermal-conductivity thin film on a low-thermal-conductivity (Λs) substrate (e.g., Λcross/Λs > 20) are challenging, due to the low thermal resistance of the thin film compared with that of the substrate. In principle, Λcross could be measured by time-domain thermoreflectance (TDTR), using a high modulation frequency fh and a large laser spot size. However, with one TDTR measurement at fh, the uncertainty of the TDTR measurement is usually high due to low sensitivity of TDTR signals to Λcross and high sensitivity to the thickness hAl of Al transducer deposited on the sample for TDTR measurements. We observe that in most TDTR measurements, the sensitivity to hAl only depends weakly on the modulation frequency f. Thus, we performed an additional TDTR measurement at a low modulation frequency f0, such that the sensitivity to hAl is comparable but the sensitivity to Λcross is near zero. We then analyze the ratio of the TDTR signals at fh to that at f0, and thus significantly improve the accuracy of our Λcross measurements. As a demonstration of the dual-frequency approach, we measured the cross-plane thermal conductivity of a 400-nm-thick nickel-iron alloy film and a 3-μm-thick Cu film, both with an accuracy of ∼10%. The dual-frequency TDTR approach is useful for future studies of thin films. PMID:27475589

  10. Saturated CO{sub 2} absorption near 1.6 μm for kilohertz-accuracy transition frequencies

    SciTech Connect

    Burkart, Johannes Romanini, Daniele; Campargue, Alain; Kassi, Samir; Sala, Tommaso; Marangoni, Marco

    2015-05-21

    Doppler-free saturated-absorption Lamb dips were measured on weak rovibrational lines of {sup 12}C{sup 16}O{sub 2} between 6189 and 6215 cm{sup −1} at sub-Pa pressures using optical feedback frequency stabilized cavity ring-down spectroscopy. By referencing the laser source to an optical frequency comb, transition frequencies for ten lines of the 30013←00001 band P-branch and two lines of the 31113←01101 hot band R-branch were determined with an accuracy of a few parts in 10{sup 11}. Involving rotational quantum numbers up to 42, the data were used for improving the upper level spectroscopic constants. These results provide a highly accurate reference frequency grid over the spectral interval from 1599 to 1616 nm.

  11. Highly accurate quartic force fields, vibrational frequencies, and spectroscopic constants for cyclic and linear C3H3(+).

    PubMed

    Huang, Xinchuan; Taylor, Peter R; Lee, Timothy J

    2011-05-19

    High levels of theory have been used to compute quartic force fields (QFFs) for the cyclic and linear forms of the C(3)H(3)(+) molecular cation, referred to as c-C(3)H(3)(+) and l-C(3)H(3)(+). Specifically, the singles and doubles coupled-cluster method that includes a perturbational estimate of connected triple excitations, CCSD(T), has been used in conjunction with extrapolation to the one-particle basis set limit, and corrections for scalar relativity and core correlation have been included. The QFFs have been used to compute highly accurate fundamental vibrational frequencies and other spectroscopic constants by use of both vibrational second-order perturbation theory and variational methods to solve the nuclear Schrödinger equation. Agreement between our best computed fundamental vibrational frequencies and recent infrared photodissociation experiments is reasonable for most bands, but there are a few exceptions. Possible sources for the discrepancies are discussed. We determine the energy difference between the cyclic and linear forms of C(3)H(3)(+), obtaining 27.9 kcal/mol at 0 K, which should be the most reliable available. It is expected that the fundamental vibrational frequencies and spectroscopic constants presented here for c-C(3)H(3)(+) and l-C(3)H(3)(+) are the most reliable available for the free gas-phase species, and it is hoped that these will be useful in the assignment of future high-resolution laboratory experiments or astronomical observations. PMID:21510653

  12. Highly Accurate Quartic Force Fields, Vibrational Frequencies, and Spectroscopic Constants for Cyclic and Linear C3H3(+)

    NASA Technical Reports Server (NTRS)

    Huang, Xinchuan; Taylor, Peter R.; Lee, Timothy J.

    2011-01-01

    High levels of theory have been used to compute quartic force fields (QFFs) for the cyclic and linear forms of the C H + molecular cation, referred to as c-C H + and I-C H +. Specifically the 33 3333 singles and doubles coupled-cluster method that includes a perturbational estimate of connected triple excitations, CCSD(T), has been used in conjunction with extrapolation to the one-particle basis set limit and corrections for scalar relativity and core correlation have been included. The QFFs have been used to compute highly accurate fundamental vibrational frequencies and other spectroscopic constants using both vibrational 2nd-order perturbation theory and variational methods to solve the nuclear Schroedinger equation. Agreement between our best computed fundamental vibrational frequencies and recent infrared photodissociation experiments is reasonable for most bands, but there are a few exceptions. Possible sources for the discrepancies are discussed. We determine the energy difference between the cyclic and linear forms of C H +, 33 obtaining 27.9 kcal/mol at 0 K, which should be the most reliable available. It is expected that the fundamental vibrational frequencies and spectroscopic constants presented here for c-C H + 33 and I-C H + are the most reliable available for the free gas-phase species and it is hoped that 33 these will be useful in the assignment of future high-resolution laboratory experiments or astronomical observations.

  13. A stable frequency comb directly referenced to rubidium electromagnetically induced transparency and two-photon transitions

    SciTech Connect

    Hou, Dong; Wu, Jiutao; Zhang, Shuangyou; Ren, Quansheng; Zhang, Zhigang; Zhao, Jianye

    2014-03-17

    We demonstrate an approach to create a stable erbium-fiber-based frequency comb at communication band by directly locking the combs to two rubidium atomic transitions resonances (electromagnetically induced transparency absorption and two-photon absorption), respectively. This approach directly transfers the precision and stability of the atomic transitions to the comb. With its distinguishing feature of compactness by removing the conventional octave-spanning spectrum and f-to-2f beating facilities and the ability to directly control the comb's frequency at the atomic transition frequency, this stable optical comb can be widely used in optical communication, frequency standard, and optical spectroscopy and microscopy.

  14. Evaluation of the Time-Derivative Coupling for Accurate Electronic State Transition Probabilities from Numerical Simulations.

    PubMed

    Meek, Garrett A; Levine, Benjamin G

    2014-07-01

    Spikes in the time-derivative coupling (TDC) near surface crossings make the accurate integration of the time-dependent Schrödinger equation in nonadiabatic molecular dynamics simulations a challenge. To address this issue, we present an approximation to the TDC based on a norm-preserving interpolation (NPI) of the adiabatic electronic wave functions within each time step. We apply NPI and two other schemes for computing the TDC in numerical simulations of the Landau-Zener model, comparing the simulated transfer probabilities to the exact solution. Though NPI does not require the analytical calculation of nonadiabatic coupling matrix elements, it consistently yields unsigned population transfer probability errors of ∼0.001, whereas analytical calculation of the TDC yields errors of 0.0-1.0 depending on the time step, the offset of the maximum in the TDC from the beginning of the time step, and the coupling strength. The approximation of Hammes-Schiffer and Tully yields errors intermediate between NPI and the analytical scheme. PMID:26279558

  15. Accurate Lineshapes from Sub-1 cm-1 Resolution Sum Frequency Generation Vibrational Spectroscopy of α-Pinene at Room Temperature

    SciTech Connect

    Mifflin, Amanda L.; Velarde Ruiz Esparza, Luis A.; Ho, Junming; Psciuk, Brian; Negre, Christian; Ebben, Carlena J.; Upshur, Mary Alice; Lu, Zhou; Strick, Benjamin; Thomson, Regan; Batista, Victor; Wang, Hongfei; Geiger, Franz M.

    2015-02-26

    Room temperature sub-wavenumber high-resolution broadband sum frequency generation (HR-BB-SFG) spectra of the common terpene (+)-α-pinene reveal ten peaks in the C–H stretching region. The spectral resolution exceeds that of Fourier transform infrared, femtosecond stimulated Raman, and traditional BB-SFG and scanning SFG spectroscopy of the same molecule. Experiment and simulation show the spectral lineshapes to be accurate. Homogeneous vibrational decoherence lifetimes of up to 1.7 psec are assigned to specific oscillators and compare favorably to lifetimes computed from density functional tight binding molecular dynamics calculations, while phase-resolved spectra yield orientation information for them. We propose the new spectroscopy as an attractive alternative to time-resolved vibrational spectroscopy or heterodyne-detection schemes for studying vibrational energy relaxation and vibrational coherences in molecules.

  16. Numerical Computation of a Continuous-thrust State Transition Matrix Incorporating Accurate Hardware and Ephemeris Models

    NASA Technical Reports Server (NTRS)

    Ellison, Donald; Conway, Bruce; Englander, Jacob

    2015-01-01

    A significant body of work exists showing that providing a nonlinear programming (NLP) solver with expressions for the problem constraint gradient substantially increases the speed of program execution and can also improve the robustness of convergence, especially for local optimizers. Calculation of these derivatives is often accomplished through the computation of spacecraft's state transition matrix (STM). If the two-body gravitational model is employed as is often done in the context of preliminary design, closed form expressions for these derivatives may be provided. If a high fidelity dynamics model, that might include perturbing forces such as the gravitational effect from multiple third bodies and solar radiation pressure is used then these STM's must be computed numerically. We present a method for the power hardward model and a full ephemeris model. An adaptive-step embedded eight order Dormand-Prince numerical integrator is discussed and a method for the computation of the time of flight derivatives in this framework is presented. The use of these numerically calculated derivatieves offer a substantial improvement over finite differencing in the context of a global optimizer. Specifically the inclusion of these STM's into the low thrust missiondesign tool chain in use at NASA Goddard Spaceflight Center allows for an increased preliminary mission design cadence.

  17. Accurate van der Waals coefficients between fullerenes and fullerene-alkali atoms and clusters: Modified single-frequency approximation

    NASA Astrophysics Data System (ADS)

    Tao, Jianmin; Mo, Yuxiang; Tian, Guocai; Ruzsinszky, Adrienn

    2016-08-01

    Long-range van der Waals (vdW) interaction is critically important for intermolecular interactions in molecular complexes and solids. However, accurate modeling of vdW coefficients presents a great challenge for nanostructures, in particular for fullerene clusters, which have huge vdW coefficients but also display very strong nonadditivity. In this work, we calculate the coefficients between fullerenes, fullerene and sodium clusters, and fullerene and alkali atoms with the hollow-sphere model within the modified single-frequency approximation (MSFA). In the MSFA, we assume that the electron density is uniform in a molecule and that only valence electrons in the outmost subshell of atoms contribute. The input to the model is the static multipole polarizability, which provides a sharp cutoff for the plasmon contribution outside the effective vdW radius. We find that the model can generate C6 in excellent agreement with expensive wave-function-based ab initio calculations, with a mean absolute relative error of only 3 % , without suffering size-dependent error. We show that the nonadditivities of the coefficients C6 between fullerenes and C60 and sodium clusters Nan revealed by the model agree remarkably well with those based on the accurate reference values. The great flexibility, simplicity, and high accuracy make the model particularly suitable for the study of the nonadditivity of vdW coefficients between nanostructures, advancing the development of better vdW corrections to conventional density functional theory.

  18. Transition Densities and Sample Frequency Spectra of Diffusion Processes with Selection and Variable Population Size

    PubMed Central

    Živković, Daniel; Steinrücken, Matthias; Song, Yun S.; Stephan, Wolfgang

    2015-01-01

    Advances in empirical population genetics have made apparent the need for models that simultaneously account for selection and demography. To address this need, we here study the Wright–Fisher diffusion under selection and variable effective population size. In the case of genic selection and piecewise-constant effective population sizes, we obtain the transition density by extending a recently developed method for computing an accurate spectral representation for a constant population size. Utilizing this extension, we show how to compute the sample frequency spectrum in the presence of genic selection and an arbitrary number of instantaneous changes in the effective population size. We also develop an alternate, efficient algorithm for computing the sample frequency spectrum using a moment-based approach. We apply these methods to answer the following questions: If neutrality is incorrectly assumed when there is selection, what effects does it have on demographic parameter estimation? Can the impact of negative selection be observed in populations that undergo strong exponential growth? PMID:25873633

  19. Accurate and agile digital control of optical phase, amplitude and frequency for coherent atomic manipulation of atomic systems.

    PubMed

    Thom, Joseph; Wilpers, Guido; Riis, Erling; Sinclair, Alastair G

    2013-08-12

    We demonstrate a system for fast and agile digital control of laser phase, amplitude and frequency for applications in coherent atomic systems. The full versatility of a direct digital synthesis radiofrequency source is faithfully transferred to laser radiation via acousto-optic modulation. Optical beatnotes are used to measure phase steps up to 2π, which are accurately implemented with a resolution of ≤ 10 mrad. By linearizing the optical modulation process, amplitude-shaped pulses of durations ranging from 500 ns to 500 ms, in excellent agreement with the programmed functional form, are demonstrated. Pulse durations are limited only by the 30 ns rise time of the modulation process, and a measured extinction ratio of > 5 × 10(11) is achieved. The system presented here was developed specifically for controlling the quantum state of trapped ions with sequences of multiple laser pulses, including composite and bichromatic pulses. The demonstrated techniques are widely applicable to other atomic systems ranging across quantum information processing, frequency metrology, atom interferometry, and single-photon generation. PMID:23938787

  20. Accurate spectroscopic calculations of 21 electronic states of ClO radical including transition properties

    NASA Astrophysics Data System (ADS)

    Wang, Xinxin; Shi, Deheng; Sun, Jinfeng; Zhu, Zunlue

    2016-08-01

    The potential energy curves were calculated for the 21 states (X2Π, A2Π, 32Π, 42Π, 52Π, 12Σ+, 22Σ+, 32Σ+, 12Σ-, 22Σ-, 32Σ-, 12Δ, 22Δ, 32Δ, 12Φ, 14Σ+, a4Σ-, 24Σ-, 14Π, 24Π and 14Δ), which originated from the two lowest dissociation channels of ClO radical. The calculations were done for internuclear separations approximately from 0.08 to 1.10 nm using the CASSCF method, which was followed by the icMRCI approach with the aug-cc-pV5Z basis set. Of these 21 states, the 14Π, 24Π, 32Δ, 42Π, 52Π, 12Φ, 32Σ+, 14Δ and 24Σ- states are repulsive. The 12Δ, 12Σ-, 14Σ+, 22Σ-, 12Σ+, 22Σ+, 22Δ and 32Σ- states are very weakly bound. Only the A2Π state has one barrier. The avoided crossing exists between the A2Π and the 32Π state. However, the avoided crossing does not generate any double wells. Core- valence correlation correction was accounted for at the level of an aug-cc-pCVQZ basis set. Scalar relativistic correction was included by the third-order Douglas-Kroll Hamiltonian approximation at the level of an aug-cc-pVQZ basis set. All the potential energy curves were extrapolated to the complete basis set limit. The spectroscopic parameters were determined. The 12Σ-, 22Σ-, 32Σ- and 14Σ+ states may be very difficult to be detected in an experiment, since each of these Λ-S states has only one or two vibrational states. The Franck-Condon factors and radiative lifetimes were calculated for several low vibrational levels of the A2Π - X2Π, 32Π - a4Σ-, 22Δ - a4Σ- and 32Σ- - 12Σ- transitions. The spin-orbit coupling effect on the spectroscopic parameters of the X2Π, A2Π, 32Π, a4Σ- and 22Σ+ states were discussed. The spectroscopic properties reported here can be expected to be reliably predicted ones.

  1. IGS-global ionospheric maps for accurate computation of GPS single- frequency ionospheric delay-simulation study

    NASA Astrophysics Data System (ADS)

    Farah, A.

    The Ionospheric delay is still one of the largest sources of error that affects the positioning accuracy of any satellite positioning system. This problem could be solved due to the dispersive nature of the Ionosphere by combining simultaneous measurements of signals at two different frequencies but it is still there for single- frequency users. Much effort has been made in establishing models for single- frequency users to make this effect as small as possible. These models vary in accuracy, input data and computational complexity, so the choice between the different models depends on the individual circumstances of the user. From the simulation point of view, the model needed should be accurate with a global coverage and good description to the Ionosphere's variable nature with both time and location. The author reviews some of these established models, starting with the BENT model, the Klobuchar model and the IRI (International Reference Ionosphere) model. Since quiet a long time, Klobuchar model considers the most widely used model ever in this field, due to its simplicity and time saving. Any GPS user could find Klobuchar model's coefficients in the broadcast navigation message. CODE, Centre for Orbit Determination in Europe provides a new set of coefficients for Klobuchar model, which gives more accurate results for the Ionospheric delay computation. IGS (International GPS Service) services include providing GPS community with a global Ionospheric maps in IONEX-format (IONosphere Map Exchange format) which enables the computation of the Ionospheric delay at the desired location and time. The study was undertaken from GPS-data simulation point of view. The aim was to select a model for the simulation of GPS data that gives a good description of the Ionosphere's nature with a high degree of accuracy in computing the Ionospheric delay that yields to better-simulated data. A new model developed by the author based on IGS global Ionospheric maps. A comparison

  2. On the use of spring baseflow recession for a more accurate parameterization of aquifer transit time distribution functions

    NASA Astrophysics Data System (ADS)

    Farlin, J.; Maloszewski, P.

    2013-05-01

    Baseflow recession analysis and groundwater dating have up to now developed as two distinct branches of hydrogeology and have been used to solve entirely different problems. We show that by combining two classical models, namely the Boussinesq equation describing spring baseflow recession, and the exponential piston-flow model used in groundwater dating studies, the parameters describing the transit time distribution of an aquifer can be in some cases estimated to a far more accurate degree than with the latter alone. Under the assumption that the aquifer basis is sub-horizontal, the mean transit time of water in the saturated zone can be estimated from spring baseflow recession. This provides an independent estimate of groundwater transit time that can refine those obtained from tritium measurements. The approach is illustrated in a case study predicting atrazine concentration trend in a series of springs draining the fractured-rock aquifer known as the Luxembourg Sandstone. A transport model calibrated on tritium measurements alone predicted different times to trend reversal following the nationwide ban on atrazine in 2005 with different rates of decrease. For some of the springs, the actual time of trend reversal and the rate of change agreed extremely well with the model calibrated using both tritium measurements and the recession of spring discharge during the dry season. The agreement between predicted and observed values was however poorer for the springs displaying the most gentle recessions, possibly indicating a stronger influence of continuous groundwater recharge during the summer months.

  3. Accurate spectroscopic calculations of 21 electronic states of ClO radical including transition properties.

    PubMed

    Wang, Xinxin; Shi, Deheng; Sun, Jinfeng; Zhu, Zunlue

    2016-08-01

    The potential energy curves were calculated for the 21 states (X(2)Π, A(2)Π, 3(2)Π, 4(2)Π, 5(2)Π, 1(2)Σ(+), 2(2)Σ(+), 3(2)Σ(+), 1(2)Σ(-), 2(2)Σ(-), 3(2)Σ(-), 1(2)Δ, 2(2)Δ, 3(2)Δ, 1(2)Φ, 1(4)Σ(+), a(4)Σ(-), 2(4)Σ(-), 1(4)Π, 2(4)Π and 1(4)Δ), which originated from the two lowest dissociation channels of ClO radical. The calculations were done for internuclear separations approximately from 0.08 to 1.10nm using the CASSCF method, which was followed by the icMRCI approach with the aug-cc-pV5Z basis set. Of these 21 states, the 1(4)Π, 2(4)Π, 3(2)Δ, 4(2)Π, 5(2)Π, 1(2)Φ, 3(2)Σ(+), 1(4)Δ and 2(4)Σ(-) states are repulsive. The 1(2)Δ, 1(2)Σ(-), 1(4)Σ(+), 2(2)Σ(-), 1(2)Σ(+), 2(2)Σ(+), 2(2)Δ and 3(2)Σ(-) states are very weakly bound. Only the A(2)Π state has one barrier. The avoided crossing exists between the A(2)Π and the 3(2)Π state. However, the avoided crossing does not generate any double wells. Core- valence correlation correction was accounted for at the level of an aug-cc-pCVQZ basis set. Scalar relativistic correction was included by the third-order Douglas-Kroll Hamiltonian approximation at the level of an aug-cc-pVQZ basis set. All the potential energy curves were extrapolated to the complete basis set limit. The spectroscopic parameters were determined. The 1(2)Σ(-), 2(2)Σ(-), 3(2)Σ(-) and 1(4)Σ(+) states may be very difficult to be detected in an experiment, since each of these Λ-S states has only one or two vibrational states. The Franck-Condon factors and radiative lifetimes were calculated for several low vibrational levels of the A(2)Π - X(2)Π, 3(2)Π - a(4)Σ(-), 2(2)Δ - a(4)Σ(-) and 3(2)Σ(-) - 1(2)Σ(-) transitions. The spin-orbit coupling effect on the spectroscopic parameters of the X(2)Π, A(2)Π, 3(2)Π, a(4)Σ(-) and 2(2)Σ(+) states were discussed. The spectroscopic properties reported here can be expected to be reliably predicted ones. PMID:27111157

  4. Determination of transit time distribution and Rabi frequency by applying regularized inverse on Ramsey spectra

    SciTech Connect

    Park, Young-Ho; Lee, Soo Heyong; Park, Sang Eon; Lee, Ho Seong; Kwon, Taeg Yong

    2007-04-23

    The authors report on a method to determine the Rabi frequency and transit time distribution of atoms that are essential for proper operation of atomic beam frequency standards. Their method, which employs alternative regularized inverse on two Ramsey spectra measured at different microwave powers, can be used for the frequency standards with short Ramsey cavity as well as long ones. The authors demonstrate that uncertainty in Rabi frequency obtained from their method is 0.02%.

  5. Vocational Rehabilitation Professionals' Identified Transition Competencies: Importance, Frequency, and Preparedness

    ERIC Educational Resources Information Center

    Plotner, Anthony J.

    2009-01-01

    Services and programs for transition-age youth with disabilities have been fragmented and inadequate (Noonan, 2004; Oertle & Trach, 2007; Sitlington, Clark, & Kolstoe, 2000). These often-ineffective services have contributed to the sizeable gap betweens students with disabilities and their peers without disabilities in employment and other aspects…

  6. Frequency transitions in odor-evoked neural oscillations

    PubMed Central

    Ito, Iori; Bazhenov, Maxim; Ong, Rose Chik-ying; Raman, Baranidharan; Stopfer, Mark

    2009-01-01

    Summary In many species sensory stimuli elicit the oscillatory synchronization of groups of neurons. What determines the properties of these oscillations? In the olfactory system of the moth we found that odors elicited oscillatory synchronization through a neural mechanism like that described in locust and Drosophila. During responses to long odor pulses, oscillations suddenly slowed as net olfactory receptor neuron (ORN) output decreased; thus, stimulus intensity appeared to determine oscillation frequency. However, changing the concentration of the odor had little effect upon oscillatory frequency. Our recordings in vivo and computational models based on these results suggested the main effect of increasing odor concentration was to recruit additional, less well-tuned ORNs whose firing rates were tightly constrained by adaptation and saturation. Thus, in the periphery, concentration is encoded mainly by the size of the responsive ORN population, and oscillation frequency is set by the adaptation and saturation of this response. PMID:20005825

  7. High-Frequency CTD Measurements for Accurate GPS/acoustic Sea-floor Crustal Deformation Measurement System

    NASA Astrophysics Data System (ADS)

    Tadokoro, K.; Yasuda, K.; Taniguchi, S.; Uemura, Y.; Matsuhiro, K.

    2015-12-01

    The GPS/acoustic sea-floor crustal deformation measurement system has developed as a useful tool to observe tectonic deformation especially at subduction zones. One of the factors preventing accurate GPS/acoustic sea-floor crustal deformation measurement is horizontal heterogeneity of sound speed in the ocean. It is therefore necessary to measure the gradient directly from sound speed structure. We report results of high-frequency CTD measurements using Underway CTD (UCTD) in the Kuroshio region. We perform the UCTD measurements on May 2nd, 2015 at two stations (TCA and TOA) above the sea-floor benchmarks installed across the Nankai Trough, off the south-east of Kii Peninsula, middle Japan. The number of measurement points is six at each station along circles with a diameter of 1.8 nautical miles around the sea-floor benchmark. The stations TCA and TOA are located on the edge and the interior of the Kuroshio current, respectively, judging from difference in sea water density measured at the two stations, as well as a satellite image of sea-surface temperature distribution. We detect a sound speed gradient of high speeds in the southern part and low speeds in the northern part at the two stations. At the TCA station, the gradient is noticeable down to 300 m in depth; the maximum difference in sound speed is +/- 5 m/s. The sound speed difference is as small as +/- 1.3 m/s at depths below 300 m, which causes seafloor benchmark positioning error as large as 1 m. At the TOA station, the gradient is extremely small down to 100 m in depth. The maximum difference in sound speed is less than +/- 0.3 m/s that is negligible small for seafloor benchmark positioning error. Clear gradient of high speed is observed to the depths; the maximum difference in sound speed is +/- 0.8-0.9 m/s, causing seafloor benchmark positioning error of several tens centimeters. The UCTD measurement is effective tool to detect sound speed gradient. We establish a method for accurate sea

  8. A high-frequency, secondary instability of crossflow vortices that leads to transition

    NASA Technical Reports Server (NTRS)

    Kohama, Yasuaki; Saric, William S.; Hoos, Jon A.

    1991-01-01

    Three-dimensional boundary-layer transition experiments are currently being conducted on a 45 deg swept wing in the Arizona State University Unsteady Wind Tunnel. Crossflow-dominated transition is produced via a model with contoured end liners to simulate infinite swept-wing flow. Fixed-wavelength, stationary and travelling crossflow vortices are observed. The frequencies of the most amplified travelling waves are in agreement with linear-stability theory; however travelling waves at frequencies an order of magnitude higher than predicted are also observed near transition. Near the transition location, the distorted boundary layer is due to the stationary crossflow vortex and is subject to a Rayleigh-type instability in the stream direction. As a result, a high-frequency secondary instability is detected in the transition region and spatial relations of the process are well documented by coupled use of flow visualization and hot-wire measurements.

  9. FAST TRACK COMMUNICATION: Characterization of frequency-dependent glass transition temperature by Vogel-Fulcher relationship

    NASA Astrophysics Data System (ADS)

    Bai, Yu; Jin, Li

    2008-08-01

    The complex mechanical modulus of polymer and polymer based composite materials showed a frequency-dependent behaviour during glass transition relaxation, which was historically modelled by the Arrhenius equation. However, this might not be true in a broad frequency domain based on the experience from the frequency dependence of the complex dielectric permittivity, which resulted from the same glass transition relaxation as for the complex mechanical modulus. Considering a good correspondence between dielectric and mechanical relaxation during glass transition, the Vogel-Fulcher relationship, previously proposed for the frequency dependence of dielectric permittivity, is introduced for that of the mechanical modulus; and the corresponding static glass transition temperature (Tf) was first determined for polymer and polymer based composite materials.

  10. NEW ACCURATE MEASUREMENT OF {sup 36}ArH{sup +} AND {sup 38}ArH{sup +} RO-VIBRATIONAL TRANSITIONS BY HIGH RESOLUTION IR ABSORPTION SPECTROSCOPY

    SciTech Connect

    Cueto, M.; Herrero, V. J.; Tanarro, I.; Doménech, J. L.; Cernicharo, J.; Barlow, M. J.; Swinyard, B. M.

    2014-03-01

    The protonated argon ion, {sup 36}ArH{sup +}, was recently identified in the Crab Nebula from Herschel spectra. Given the atmospheric opacity at the frequency of its J = 1-0 and J = 2-1 rotational transitions (617.5 and 1234.6 GHz, respectively), and the current lack of appropriate space observatories after the recent end of the Herschel mission, future studies on this molecule will rely on mid-infrared observations. We report on accurate wavenumber measurements of {sup 36}ArH{sup +} and {sup 38}ArH{sup +} rotation-vibration transitions in the v = 1-0 band in the range 4.1-3.7 μm (2450-2715 cm{sup –1}). The wavenumbers of the R(0) transitions of the v = 1-0 band are 2612.50135 ± 0.00033 and 2610.70177 ± 0.00042 cm{sup –1} (±3σ) for {sup 36}ArH{sup +} and {sup 38}ArH{sup +}, respectively. The calculated opacity for a gas thermalized at a temperature of 100 K and with a linewidth of 1 km s{sup –1} of the R(0) line is 1.6 × 10{sup –15} × N({sup 36}ArH{sup +}). For column densities of {sup 36}ArH{sup +} larger than 1 × 10{sup 13} cm{sup –2}, significant absorption by the R(0) line can be expected against bright mid-IR sources.

  11. On the use of spring baseflow recession for a more accurate parameterization of aquifer transit time distribution functions

    NASA Astrophysics Data System (ADS)

    Farlin, J.; Maloszewski, P.

    2012-12-01

    Baseflow recession analysis and groundwater dating have up to now developed as two distinct branches of hydrogeology and were used to solve entirely different problems. We show that by combining two classical models, namely Boussinesq's Equation describing spring baseflow recession and the exponential piston-flow model used in groundwater dating studies, the parameters describing the transit time distribution of an aquifer can be in some cases estimated to a far more accurate degree than with the latter alone. Under the assumption that the aquifer basis is sub-horizontal, the mean residence time of water in the saturated zone can be estimated from spring baseflow recession. This provides an independent estimate of groundwater residence time that can refine those obtained from tritium measurements. This approach is demonstrated in a case study predicting atrazine concentration trend in a series of springs draining the fractured-rock aquifer known as the Luxembourg Sandstone. A transport model calibrated on tritium measurements alone predicted different times to trend reversal following the nationwide ban on atrazine in 2005 with different rates of decrease. For some of the springs, the best agreement between observed and predicted time of trend reversal was reached for the model calibrated using both tritium measurements and the recession of spring discharge during the dry season. The agreement between predicted and observed values was however poorer for the springs displaying the most gentle recessions, possibly indicating the stronger influence of continuous groundwater recharge during the dry period.

  12. Absolute Frequency Measurements of the D1 and D2 Transitions in Aatomic Li

    NASA Astrophysics Data System (ADS)

    Sheets, Donal; Almaguer, Jose; Baron, Jacob; Elgee, Peter; Rowan, Michael; Stalnaker, Jason

    2014-05-01

    We present preliminary results from our measurements of the D1 and D2 transitions in Li. The data were obtained from a collimated atomic beam excited by light from an extended cavity diode laser. The frequency of the diode laser was stabilized to an optical frequency comb, providing absolute frequency measurement and control of the excitation laser frequency. These measurements will provide a stringent test of atomic structure calculations and yield information about the nuclear structure. We also discuss plans to extend the technique to other high-lying states in lithium. Funded by the NIST Precision Measurements Grant and NSF Award #1305591.

  13. Non-Maxwellian to Maxwellian transitions of atmospheric microplasmas at microwave frequencies

    NASA Astrophysics Data System (ADS)

    Lee, M. U.; Jeong, S. Y.; Won, I. H.; Sung, S. K.; Yun, G. S.; Lee, J. K.

    2016-07-01

    Particle-in-cell/Monte Carlo simulations and numerical analysis of a single particle motion are performed for atmospheric He microplasmas at microwave frequencies to determine the characteristics of non-Maxwellian to Maxwellian transition. The left and the right regimes of Paschen curve, divided by this transition, reveal that the transition frequencies depend on the gap of electrodes and the neutral gas pressure to follow scaling laws for a new extended Paschen law. The fluid models are reasonable at the right-side regime of Paschen breakdown areas, but not on the left side, which is highly kinetic for electrons. The plasmas driven by weaker electric fields of high enough frequencies at the right-side Paschen regime breed more energetic electrons.

  14. Biomechanical mechanism for transitions in phase and frequency of arm and leg swing during walking.

    PubMed

    Kubo, Masayoshi; Wagenaar, Robert C; Saltzman, Elliot; Holt, Kenneth G

    2004-08-01

    As humans increase walking speed, there are concurrent transitions in the frequency ratio between arm and leg movements from 2:1 to 1:1 and in the phase relationship between the movements of the two arms from in-phase to out-of-phase. Superharmonic resonance of a pendulum with monofrequency excitation had been proposed as a potential model for this phenomenon. In this study, an alternative model of paired pendulums with multiple-frequency excitations is explored. It was predicted that the occurrence of the concurrent transitions was a function of (1) changes in the magnitude ratio of shoulder accelerations at step and stride frequencies that accompany changes in walking speed and (2) proximity of these frequencies to the natural resonance frequencies of the arms modeled as a pair of passive pendulums. Model predictions were compared with data collected from 14 healthy young subjects who were instructed to walk on a treadmill. Walking speeds were manipulated between 0.18 and 1.52 m/s in steps of 0.22 m/s. Kinematic data for the arms and shoulders were collected using a 3D motion analysis system, and simulations were conducted in which the movements of a double-pendulum system excited by the accelerations at the suspension point were analyzed to determine the extent to which the arms acted as passive pendulums. It was confirmed that the acceleration waveforms at the shoulder are composed primarily of stride and step frequency components. Between the shoulders, the stride frequency components were out-of-phase, while the step frequency components were in-phase. The amplitude ratio of the acceleration waveform components at the step and stride frequencies changed as a function of walking speed and were associated with the occurrence of the transitions. Simulation results using these summed components as excitatory inputs to the double-pendulum system were in agreement with actual transitions in 80% of the cases. The potential role of state-dependent active muscle

  15. Calibrating transition-metal energy levels and oxygen bands in first-principles calculations: Accurate prediction of redox potentials and charge transfer in lithium transition-metal oxides

    NASA Astrophysics Data System (ADS)

    Seo, Dong-Hwa; Urban, Alexander; Ceder, Gerbrand

    2015-09-01

    Transition-metal (TM) oxides play an increasingly important role in technology today, including applications such as catalysis, solar energy harvesting, and energy storage. In many of these applications, the details of their electronic structure near the Fermi level are critically important for their properties. We propose a first-principles-based computational methodology for the accurate prediction of oxygen charge transfer in TM oxides and lithium TM (Li-TM) oxides. To obtain accurate electronic structures, the Heyd-Scuseria-Ernzerhof (HSE06) hybrid functional is adopted, and the amount of exact Hartree-Fock exchange (mixing parameter) is adjusted to reproduce reference band gaps. We show that the HSE06 functional with optimal mixing parameter yields not only improved electronic densities of states, but also better energetics (Li-intercalation voltages) for LiCo O2 and LiNi O2 as compared to the generalized gradient approximation (GGA), Hubbard U corrected GGA (GGA +U ), and standard HSE06. We find that the optimal mixing parameters for TM oxides are system specific and correlate with the covalency (ionicity) of the TM species. The strong covalent (ionic) nature of TM-O bonding leads to lower (higher) optimal mixing parameters. We find that optimized HSE06 functionals predict stronger hybridization of the Co 3 d and O 2 p orbitals as compared to GGA, resulting in a greater contribution from oxygen states to charge compensation upon delithiation in LiCo O2 . We also find that the band gaps of Li-TM oxides increase linearly with the mixing parameter, enabling the straightforward determination of optimal mixing parameters based on GGA (α =0.0 ) and HSE06 (α =0.25 ) calculations. Our results also show that G0W0@GGA +U band gaps of TM oxides (M O ,M =Mn ,Co ,Ni ) and LiCo O2 agree well with experimental references, suggesting that G0W0 calculations can be used as a reference for the calibration of the mixing parameter in cases when no experimental band gap has been

  16. A time domain based method for the accurate measurement of Q-factor and resonance frequency of microwave resonators

    SciTech Connect

    Gyüre, B.; Márkus, B. G.; Bernáth, B.; Simon, F.; Murányi, F.

    2015-09-15

    We present a novel method to determine the resonant frequency and quality factor of microwave resonators which is faster, more stable, and conceptually simpler than the yet existing techniques. The microwave resonator is pumped with the microwave radiation at a frequency away from its resonance. It then emits an exponentially decaying radiation at its eigen-frequency when the excitation is rapidly switched off. The emitted microwave signal is down-converted with a microwave mixer, digitized, and its Fourier transformation (FT) directly yields the resonance curve in a single shot. Being a FT based method, this technique possesses the Fellgett (multiplex) and Connes (accuracy) advantages and it conceptually mimics that of pulsed nuclear magnetic resonance. We also establish a novel benchmark to compare accuracy of the different approaches of microwave resonator measurements. This shows that the present method has similar accuracy to the existing ones, which are based on sweeping or modulating the frequency of the microwave radiation.

  17. Spectral line shapes and frequencies of the molecular oxygen B-band R-branch transitions

    NASA Astrophysics Data System (ADS)

    Domysławska, Jolanta; Wójtewicz, Szymon; Masłowski, Piotr; Cygan, Agata; Bielska, Katarzyna; Trawiński, Ryszard S.; Ciuryło, Roman; Lisak, Daniel

    2015-04-01

    We present the line-shape parameters for the first 11 lines of the oxygen B-band R-branch self-broadened transitions measured at low pressures by the Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectrometer (PDH-locked FS-CRDS) linked to the optical frequency comb. The collisional self-broadening, shifting and narrowing parameters were determined together with the quadratic speed-dependence as well as phase- and velocity-changing correlations parameters. The absolute frequencies of the transitions with combined standard uncertainties below 150 kHz are reported. Dependence of line parameters on choice of the line-shape model is discussed.

  18. Frequency-domain readout multiplexing of transition-edge sensor arrays

    NASA Astrophysics Data System (ADS)

    Lanting, T. M.; Arnold, K.; Cho, Hsiao-Mei; Clarke, John; Dobbs, Matt; Holzapfel, William; Lee, Adrian T.; Lueker, M.; Richards, P. L.; Smith, A. D.; Spieler, H. G.

    2006-04-01

    We have demonstrated frequency-domain readout multiplexing of eight channels for superconducting transition-edge sensor bolometer arrays. The multiplexed readout noise is 6.5 pA/√Hz, well below the bolometer dark noise of 15-20 pA/√Hz. We measure an upper limit on crosstalk of 0.004 between channels adjacent in frequency which meets our design requirement of 0.01. We have observed vibration insensitivity in our frequency-domain multiplexed transition-edge sensors, making this system very attractive for telescope and satellite observations. We also discuss extensions to our multiplexed readout. In particular, we are developing a SQUID flux-locked loop that is entirely cold and collaborating on digital multiplexer technology in order to scale up the number of multiplexed channels.

  19. The application of intraoperative transit time flow measurement to accurately assess anastomotic quality in sequential vein grafting

    PubMed Central

    Yu, Yang; Zhang, Fan; Gao, Ming-Xin; Li, Hai-Tao; Li, Jing-Xing; Song, Wei; Huang, Xin-Sheng; Gu, Cheng-Xiong

    2013-01-01

    OBJECTIVES Intraoperative transit time flow measurement (TTFM) is widely used to assess anastomotic quality in coronary artery bypass grafting (CABG). However, in sequential vein grafting, the flow characteristics collected by the conventional TTFM method are usually associated with total graft flow and might not accurately indicate the quality of every distal anastomosis in a sequential graft. The purpose of our study was to examine a new TTFM method that could assess the quality of each distal anastomosis in a sequential graft more reliably than the conventional TTFM approach. METHODS Two TTFM methods were tested in 84 patients who underwent sequential saphenous off-pump CABG in Beijing An Zhen Hospital between April and August 2012. In the conventional TTFM method, normal blood flow in the sequential graft was maintained during the measurement, and the flow probe was placed a few centimetres above the anastomosis to be evaluated. In the new method, blood flow in the sequential graft was temporarily reduced during the measurement by placing an atraumatic bulldog clamp at the graft a few centimetres distal to the anastomosis to be evaluated, while the position of the flow probe remained the same as in the conventional method. This new TTFM method was named the flow reduction TTFM. Graft flow parameters measured by both methods were compared. RESULTS Compared with the conventional TTFM, the flow reduction TTFM resulted in significantly lower mean graft blood flow (P < 0.05); in contrast, yielded significantly higher pulsatility index (P < 0.05). Diastolic filling was not significantly different between the two methods and was >50% in both cases. Interestingly, the flow reduction TTFM identified two defective middle distal anastomoses that the conventional TTFM failed to detect. Graft flows near the defective distal anastomoses were improved substantially after revision. CONCLUSIONS In this study, we found that temporary reduction of graft flow during TTFM seemed to

  20. Theoretical transition frequencies beyond 0.1 ppb accuracy in H2+, HD+, and antiprotonic helium

    NASA Astrophysics Data System (ADS)

    Korobov, Vladimir I.; Hilico, Laurent; Karr, Jean-Philippe

    2014-03-01

    We present improved theoretical calculations of transition frequencies for the fundamental transitions (L=0,v=1)→(L'=0,v'=0) in the hydrogen molecular ions H2+ and HD+ with a relative uncertainty 4×10-11 and for the two-photon transitions in the antiprotonic helium atom with a relative uncertainty 10-10. To do that, the one-loop self-energy correction of order α(Zα )6 is derived in the two Coulomb center approximation, and numerically evaluated in the case of the aforementioned transitions. The final results also include a complete set of other spin-independent corrections of order mα7. The leading order corrections of α2ln3(Zα )-2(Zα)6 are also considered that allows one to estimate a magnitude of yet uncalculated contributions.

  1. Transition radiation at radio frequencies from ultrahigh-energy neutrino-induced showers

    NASA Astrophysics Data System (ADS)

    Motloch, Pavel; Alvarez-Muñiz, Jaime; Privitera, Paolo; Zas, Enrique

    2016-02-01

    Coherent radiation at radio frequencies from high-energy showers fully contained in a dense radio-transparent medium—like ice, salt, soil, or regolith—has been extensively investigated as a promising technique to search for ultrahigh-energy neutrinos. Additional emission in the form of transition radiation may occur when a neutrino-induced shower produced close to the Earth's surface emerges from the ground into atmospheric air. We present the first detailed evaluation of transition radiation from high-energy showers crossing the boundary between two different media. We found that transition radiation is sizable over a wide solid angle and coherent up to ˜1 GHz . These properties encourage further work to evaluate the potential of a large-aperture ultrahigh-energy neutrino experiment based on the detection of transition radiation.

  2. Accurate ab Initio Quartic Force Fields, Vibrational Frequencies, and Heats of Formation for FCN, FNC, ClCN, and ClNC

    NASA Technical Reports Server (NTRS)

    Lee, Timothy J.; Martin, Jan M. L.; Dateo, Christopher E.; Taylor, Peter R.

    1995-01-01

    The XCN and XNC (X = F, Cl) isomers have been investigated using the CCSD(T) method in conjunction with correlation consistent basis sets. Equilibrium geometries, harmonic frequencies, anharmonic constants, fundamental frequencies, and heats of formation have been evaluated. Agreement with experiment for the fundamental frequencies is very good, even for nu(sub 2), for CICN, which is subject to a strong Fermi resonance with 2nu(sub 3). It is also shown that a second-order perturbation theory approach to solving the nuclear Schroedinger equation gives results in excellent agreement with essentially exact variational calculations. This is true even for nu(sub 2) of ClCN, provided that near-singular terms are eliminated from the perturbation theory formulas and the appropriate Fermi interaction energy matrix is then diagonalized. A band at 615/cm, tentatively assigned as the Cl-N stretch in ClNC in matrix isolation experiments, is shown not to be due to ClNC. Accurate atomization energies are determined and are used to evaluate accurate heats of formation (3.1 +/- 1.5, 33.2 +/- 1.5, 72.6 +/- 1.5, and 75.9 +/- 1.5 kcal/mol for FCN, ClCN, FNC, and ClNC, respectively). It is expected that the theoretical heats of formation for FCN, FNC, and ClNC are the most accurate available.

  3. Collision-induced radio-frequency transitions in CH 3I

    NASA Astrophysics Data System (ADS)

    Tamassia, F.; Danieli, R.; Scappini, F.

    1999-02-01

    The highly sensitive method of radio-frequency-infrared double resonance inside a CO 2 laser is applied to study collision-induced transitions in CH 3I in a four-level double resonance scheme. Pure nuclear quadrupole resonances are observed as the result of collision population transfer between different rotational levels. The intensity ratios of the collision-induced dips to the corresponding three-level double resonance signals are measured for a number of transitions in the ground and excited vibrational states. Collision selection rules in the pure gas and in mixtures with polar and non-polar gases are discussed.

  4. Accurate absolute frequencies of the {nu}{sub 1}+{nu}{sub 3} band of {sup 13}C{sub 2}H{sub 2} determined using an infrared mode-locked Cr:YAG laser frequency comb

    SciTech Connect

    Madej, Alan A.; Bernard, John E.; John Alcock, A.; Czajkowski, Andrzej; Chepurov, Sergei

    2006-04-15

    Absolute frequency measurements, with up to 1x10{sup -11} level accuracies, are presented for 60 lines of the P and R branches for the {nu}{sub 1}+{nu}{sub 3} band of {sup 13}C{sub 2}H{sub 2} at 1.5 {mu}m (194 THz). The measurements were made using cavity-enhanced, diode-laser-based saturation spectroscopy. With one laser system stabilized to the P(16) line and a second laser system stabilized to the line whose frequency was to be determined, a Cr:YAG frequency comb was employed to accurately measure the tetrahertz level frequency intervals. The results are compared with recent work from other groups and indicate that these lines would form a basis for a high-quality atlas of reference frequencies for this region of the spectrum.

  5. Absolute molecular transition frequencies measured by three cavity-enhanced spectroscopy techniques.

    PubMed

    Cygan, A; Wójtewicz, S; Kowzan, G; Zaborowski, M; Wcisło, P; Nawrocki, J; Krehlik, P; Śliwczyński, Ł; Lipiński, M; Masłowski, P; Ciuryło, R; Lisak, D

    2016-06-01

    Absolute frequencies of unperturbed (12)C(16)O transitions from the near-infrared (3-0) band were measured with uncertainties five-fold lower than previously available data. The frequency axis of spectra was linked to the primary frequency standard. Three different cavity enhanced absorption and dispersion spectroscopic methods and various approaches to data analysis were used to estimate potential systematic instrumental errors. Except for a well established frequency-stabilized cavity ring-down spectroscopy, we applied the cavity mode-width spectroscopy and the one-dimensional cavity mode-dispersion spectroscopy for measurement of absorption and dispersion spectra, respectively. We demonstrated the highest quality of the dispersion line shape measured in optical spectroscopy so far. We obtained line positions of the Doppler-broadened R24 and R28 transitions with relative uncertainties at the level of 10(-10). The pressure shifting coefficients were measured and the influence of the line asymmetry on unperturbed line positions was analyzed. Our dispersion spectra are the first demonstration of molecular spectroscopy with both axes of the spectra directly linked to the primary frequency standard, which is particularly desirable for the future reference-grade measurements of molecular spectra. PMID:27276950

  6. Absolute molecular transition frequencies measured by three cavity-enhanced spectroscopy techniques

    NASA Astrophysics Data System (ADS)

    Cygan, A.; Wójtewicz, S.; Kowzan, G.; Zaborowski, M.; Wcisło, P.; Nawrocki, J.; Krehlik, P.; Śliwczyński, Ł.; Lipiński, M.; Masłowski, P.; Ciuryło, R.; Lisak, D.

    2016-06-01

    Absolute frequencies of unperturbed 12C16O transitions from the near-infrared (3-0) band were measured with uncertainties five-fold lower than previously available data. The frequency axis of spectra was linked to the primary frequency standard. Three different cavity enhanced absorption and dispersion spectroscopic methods and various approaches to data analysis were used to estimate potential systematic instrumental errors. Except for a well established frequency-stabilized cavity ring-down spectroscopy, we applied the cavity mode-width spectroscopy and the one-dimensional cavity mode-dispersion spectroscopy for measurement of absorption and dispersion spectra, respectively. We demonstrated the highest quality of the dispersion line shape measured in optical spectroscopy so far. We obtained line positions of the Doppler-broadened R24 and R28 transitions with relative uncertainties at the level of 10-10. The pressure shifting coefficients were measured and the influence of the line asymmetry on unperturbed line positions was analyzed. Our dispersion spectra are the first demonstration of molecular spectroscopy with both axes of the spectra directly linked to the primary frequency standard, which is particularly desirable for the future reference-grade measurements of molecular spectra.

  7. Electron heating mode transition induced by ultra-high frequency in atmospheric microplasmas for biomedical applications

    SciTech Connect

    Kwon, H. C.; Won, I. H.; Lee, J. K.

    2012-04-30

    The electron heating mode transition induced by ultra-high frequency in atmospheric-pressure microplasmas was investigated using particle-in-cell simulation with a Monte Carlo collision. Interestingly, this discharge mode transition is accompanied by non-monotonic evolution of electron kinetics such as effective electron temperature, plasma density, and electron energy on the electrode. In this study, the highest flux of energetic electrons ({epsilon} > 4 eV) usable for tailoring the surface chemistry in atmospheric microplasmas is obtained at the specific frequency (400 MHz), where an optimal trade-off is established between the amplitude of sheath oscillations and the power coupled to electrons for sub-millimeter dimensions (200 {mu}m).

  8. Laser frequency stabilization to excited state transitions using electromagnetically induced transparency in a cascade system

    SciTech Connect

    Abel, R. P.; Mohapatra, A. K.; Bason, M. G.; Pritchard, J. D.; Weatherill, K. J.; Raitzsch, U.; Adams, C. S.

    2009-02-16

    We demonstrate laser frequency stabilization to excited state transitions using cascade electromagnetically induced transparency. Using a room temperature Rb vapor cell as a reference, we stabilize a first diode laser to the D{sub 2} transition and a second laser to a transition from the intermediate 5P{sub 3/2} state to a highly excited state with principal quantum number n=19-70. A combined laser linewidth of 280{+-}50 kHz over a 100 {mu}s time period is achieved. This method may be applied generally to any cascade system and allows laser stabilization to an atomic reference in the absence of a direct absorption signal.

  9. Potential of electric quadrupole transitions in radium isotopes for single-ion optical frequency standards

    SciTech Connect

    Versolato, O. O.; Wansbeek, L. W.; Jungmann, K.; Timmermans, R. G. E.; Willmann, L.; Wilschut, H. W.

    2011-04-15

    We explore the potential of the electric quadrupole transitions 7s {sup 2}S{sub 1/2}-6d {sup 2}D{sub 3/2}, 6d {sup 2}D{sub 5/2} in radium isotopes as single-ion optical frequency standards. The frequency shifts of the clock transitions due to external fields and the corresponding uncertainties are calculated. Several competitive {sup A}Ra{sup +} candidates, with A= 223-229, are identified. In particular, we show that the transition 7s {sup 2}S{sub 1/2} (F=2,m{sub F}=0)-6d {sup 2}D{sub 3/2} (F=0,m{sub F}=0) at 828 nm in {sup 223}Ra{sup +}, with no linear Zeeman and electric quadrupole shifts, stands out as a relatively simple case, which could be exploited as a compact, robust, and low-cost atomic clock operating at a fractional frequency uncertainty of 10{sup -17}. With more experimental effort, the {sup 223,225,226}Ra{sup +} clocks could be pushed to a projected performance reaching the 10{sup -18} level.

  10. Computer Generation of Subduction Frequencies for 2ND Order Phase Transitions in Two-Dimensions

    NASA Astrophysics Data System (ADS)

    Deonarine, Samaroo

    The Landau theory of 2nd order phase transitions and Group theory Criteria are used to predict which subgroups G (L-HOOK EQ) G(,0) can occur in transitions for 2-D systems (plane-group to plane-group and diperiodic to diperiodic). Previous work 1 on the 17 plane space groups has been based on the tables of Coxeter & Moser 2 and the International Tables of X-ray Crystallography (ITXRC, 1965) 3 . These tables do not exhaust all the possible subgroups of a space group 4 . Since such explicit tables are non-existent for other families of space groups we have developed algorithms that make a systematic search of the parent unit cell of G(,0) to locate the origin and orientation of all its subgroups G, G (L-HOOK EQ) G(,0). We have written a RATFOR/FORTRAN program for the VAX 11-780 which will generate the subduction frequencies. (DIAGRAM, TABLE OR GRAPHIC OMITTED...PLEASE SEE DAI). for allowed second order phase transitions in 2-dimensional systems that are describable by the 80 diperiodic Groups G(,0) and G 5 . Our program gives a complete tabulation (Origin, new Translation Sublattice, Subduction Frequency, Subgroup and its Generators) of the allowed continuous or second order phase transitions from a parent diperiodic group G(,0) to another diperiodic subgroup G.

  11. Blackbody radiation shift of the {sup 133}Cs hyperfine transition frequency

    SciTech Connect

    Micalizio, Salvatore; Godone, Aldo; Calonico, Davide; Levi, Filippo; Lorini, Luca

    2004-05-01

    We report the theoretical evaluations of the static scalar polarizability of the {sup 133}Cs ground state and of the blackbody radiation shift induced on the transition frequency between the two hyperfine levels with m{sub F}=0. This shift is of fundamental importance in the evaluation of the accuracy of the primary frequency standards based on atomic fountains and is employed in the realization of the SI second in the International Atomic Time scale at the level of 1x10{sup -15}. Our computed value for the polarizability is {alpha}{sub 0}=(6.600{+-}0.016)x10{sup -39}C m{sup 2}/V in agreement at the level of 1x10{sup -3} with recent theoretical and experimental values. As regards the blackbody radiation shift we find for the relative hyperfine transition frequency {beta}=(-1.49{+-}0.07)x10{sup -14} at T=300 K in agreement with frequency measurements reported by our group and by Bauch and Schroeder [Phys. Rev. Lett. 78, 622 (1997)]. This value is lower by 2x10{sup -15} than that obtained with measurements based on the dc Stark shift and than the value commonly accepted up to now.

  12. Microwave Frequency Transitions Requiring Laser Ablated Uranium Metal Discovered Using Chirp-Pulse Fourier Transform Spectroscopy

    NASA Astrophysics Data System (ADS)

    Long, B. E.; Cooke, S. A.

    2014-06-01

    A rod of depleted uranium metal (mp = 1,132° C) has been ablated with the fundamental operating frequency of a Nd:YAG laser. The resulting ablation plume of uranium was then mixed with argon gas and expanded between the transmit/receive horn antennae of a chirp-pulse Fourier transform microwave spectrometer. The recorded spectra show nine strong transitions which are not present when the laser is not used in the experimental procedure. A series of experiments in which the backing gas conditions were altered provides evidence that the nine observed transitions are carried by the same species. Should the transitions be from one species it is most likely an asymmetric top. The transitions persist even when ultra-pure argon is used as the sole backing gas. The oxide coating of the uranium metal likely provides a source of oxygen and, presently, the ``top" candidate for the unknown molecule is UO_3, which is known to have C_2v symmetry. Double resonance experiments are planned to aid transition assignments. A plausible explanation for an elusive assignment to date is the presence of pseudo-rotation.

  13. Absorption coefficient, transition probability, and collision-broadening frequency of dimethylether at He-Xe laser 3.51-micron wavelength

    NASA Technical Reports Server (NTRS)

    Siegman, A. E.; Wang, S. C.

    1970-01-01

    Absorptivity, transition probability and collision broadening frequency of dimethylether at 3.51 micron He-Xe laser wavelength, noting pressure dependence, transition lifetime and saturation intensity

  14. Absolute frequency measurement of the ^1S0<->^3P0 clock transition at 578.4 nm in ytterbium

    NASA Astrophysics Data System (ADS)

    Hoyt, Chad; Barber, Zeb; Oates, Chris; Fortier, Tara; Diddams, Scott

    2005-05-01

    We report the first precision absolute frequency measurements of the highly forbidden (6s^2)^1S0<->(6s6p)^3P0 optical clock transition at 578.4 nm in two odd isotopes of ytterbium. Atoms are cooled to tens of microkelvins in two successive stages of laser cooling and magneto-optical trapping that use transitions at 398.9 nm and 555.8 nm, respectively. The resulting trapped atomic cloud is irradiated with excitation light at 578.4 nm and absorption is detected by monitoring trapped atom depletion. With the laser on resonance, we demonstrate trap depletions of more than 80 % relative to the off-resonance case. Absolute frequency measurements are made for ^171Yb (I=1/2) and ^173Yb (I=5/2) with an uncertainty of 4.4 kHz using a femtosecond-laser frequency comb calibrated by the NIST cesium fountain clock. The natural linewidth of these J=0 to J=0 transitions is ˜10 mHz, making them well-suited to support a new generation of optical atomic clocks based on confinement in an optical lattice. Lattice-based optical clocks have the potential to surpass the performance of the best current atomic clocks by orders of magnitude. The accurate ytterbium frequency knowledge presented here (nearly a million-fold reduction in uncertainty) will greatly expedite Doppler- and recoil-free lattice spectroscopy.

  15. Seismic-frequency anelasticity of quartz through the α-β phase transition

    NASA Astrophysics Data System (ADS)

    Redfern, S. A.; Peng, Z.

    2012-12-01

    The anelastic response of single-crystal and polycrystalline quartz and quartz-rich sandstones to applied stress at low frequencies has been investigated by dynamic mechanical analysis and force torsion pendulum measurements. The dynamic modulus was measured on heating and cooling through the α-β phase transition under shear and bending stress applied at low frequency (~ 1 Hz). Single crystal quartz shows highly anisotropic properties in both the real and imaginary part of the modulus. Polycrystalline novaculite quartz displays the α-β phase transition temperatures (Tc) around 8 °C higher than seen in single crystal quartz, due to the pinning stress effect of grain boundaries. The properties of the sandstone vary with heating and cooling cycles as the cementation and microfracturing of the grain structure changes at high temperature. The phase transition in quartz is ferrobielastic, and as such energy differences between domains in the transformation microstructure arise under conditions of applied shear stress. Pre-transition softening and an increase in anelastic loss above Tc are attributed to ferrobielastic switching of incipient domain microstructures that arise in the silica microstructure. The influence of temperature on this microstructure is to induce increased switching of domain as a response to thermal stress inherent in the anisotropic thermal expansion of the polycrystalline structure. These results indicate that ferrobielastic switching in quartz is an important mechanism in controlling changes in mechanical properties. As such, we anticipate that it will induce measurable anomalies in seismic signatures of the Earth's crust in regions of high thermal flux. This transition may be responsible for observed seismic velocity reductions and tectonic weakening in western North America and in certain parts of Tibetan plateau.

  16. A -90 dBc@ 10 kHz Phase Noise Fractional-N Frequency Synthesizer with Accurate Loop Bandwidth Control Circuit

    NASA Astrophysics Data System (ADS)

    Dosho, Shiro

    2006-06-01

    This paper describes a -90 dBc@10 kHz phase noise fractional-N frequency synthesizer of 110 M-180 MHz output with accurate loop bandwidth control. Stable phase noise characteristics are achieved by controlling the bandwidth correctly, even if the PLL uses a noisy but small ring oscillator. Digital controller adjusts voltage controlled oscillator (VCO) gain and time constant of the loop filter. Analog controller compensates temperature variance. Test chip fabricated on 0.13 μm CMOS process shows stable and 6.8 dB improvement of the phase noise performance is achieved against process and environmental variations.

  17. An Accurate Quartic Force Field, Fundamental Frequencies, and Binding Energy for the High Energy Density Material T(d)N4

    NASA Technical Reports Server (NTRS)

    Lee, Timothy J.; Martin, Jan M. L.; Kwak, Dochan (Technical Monitor)

    2002-01-01

    The CCSD(T) method has been used to compute a highly accurate quartic force field and fundamental frequencies for all N-14 and N-15 isotopomers of the high energy density material T(sub d)N(sub 4). The computed fundamental frequencies show beyond doubt that the bands observed in a matrix isolation experiment by Radziszewski and coworkers are not due to different isotopomers of T(sub d)N(sub 4). The most sophisticated thermochemical calculations to date yield a N(sub 4) -> 2N(sub 2) heat of reaction of 182.22 +/- 0.5 kcal/mol at 0 K (180.64 +/- 0.5 at 298 K). It is hoped that the data reported herein will aid in the ultimate detection of T(sub d)N(sub 4).

  18. The Transitional Protoplanetary Disk Frequency as a Function of Age: Disk Evolution In the Coronet Cluster, Taurus, and Other 1-8 Myr Old Regions

    NASA Astrophysics Data System (ADS)

    Currie, Thayne; Sicilia-Aguilar, Aurora

    2011-05-01

    We present Spitzer 3.6-24 μm photometry and spectroscopy for stars in the 1-3 Myr old Coronet Cluster, expanding upon the survey of Sicilia-Aguilar et al. Using sophisticated radiative transfer models, we analyze these new data and those from Sicilia-Aguilar et al. to identify disks with evidence for substantial dust evolution consistent with disk clearing: transitional disks. We then analyze data in Taurus and others young clusters—IC 348, NGC 2362, and η Cha—to constrain the transitional disk frequency as a function of time. Our analysis confirms previous results finding evidence for two types of transitional disks—those with inner holes and those that are homologously depleted. The percentage of disks in the transitional phase increases from ~15%-20% at 1-2 Myr to >=50% at 5-8 Myr the mean transitional disk lifetime is closer to ~1 Myr than 0.1-0.5 Myr, consistent with previous studies by Currie et al. and Sicilia-Aguilar et al. In the Coronet Cluster and IC 348, transitional disks are more numerous for very low mass M3-M6 stars than for more massive K5-M2 stars, while Taurus lacks a strong spectral-type-dependent frequency. Assuming standard values for the gas-to-dust ratio and other disk properties, the lower limit for the masses of optically thick primordial disks is M disk ≈ 0.001-0.003 M sstarf. We find that single color-color diagrams do not by themselves uniquely identify transitional disks or primordial disks. Full spectral energy distribution modeling is required to accurately assess disk evolution for individual sources and inform statistical estimates of the transitional disk population in large samples using mid-IR colors.

  19. The Transitional Protoplanetary Disk Frequency as a Function of Age: Disk Evolution in the Coronet Cluster, Taurus, and Other 1--8 Myr-old Regions

    NASA Technical Reports Server (NTRS)

    Currie, Thayne; Sicilia-Aguilar, Auora

    2011-01-01

    We present Spitzer 3.6-24 micron photometry and spectroscopy for stars in the 1-3 Myr-old Coronet Cluster, expanding upon the survey of Sicilia-Aguilar et al. (2008). Using sophisticated radiative transfer models, we analyze these new data and those from Sicilia-Aguilar et al. (2008) to identify disks with evidence for substantial dust evolution consistent with disk clearing: transitional disks. We then analyze data in Taurus and others young clusters - IC 348, NGC 2362, and eta Cha -- to constrain the transitional disk frequency as a function of time. Our analysis confirms previous results finding evidence for two types of transitional disks -- those with inner holes and those that are homologously depleted. The percentage of disks in the transitional phase increases from approx.15-20% at 1-2 Myr to > 50% at 5-8 Myr; the mean transitional disk lifetime is closer to approx. 1 Myr than 0.1-0.5 Myr, consistent with previous studies by Currie et al. (2009) and Sicilia-Aguilar et al. (2009). In the Coronet Cluster and IC 348, transitional disks are more numerous for very low-mass M3--M6 stars than for more massive K5-M2 stars, while Taurus lacks a strong spectral type-dependent frequency. Assuming standard values for the gas-to-dust ratio and other disk properties, the lower limit for the masses of optically-thick primordial disks is Mdisk approx. 0.001-0.003 M*. We find that single color-color diagrams do not by themselves uniquely identify transitional disks or primordial disks. Full SED modeling is required to accurately assess disk evolution for individual sources and inform statistical estimates of the transitional disk population in large samples using mid-IR colors.

  20. THE TRANSITIONAL PROTOPLANETARY DISK FREQUENCY AS A FUNCTION OF AGE: DISK EVOLUTION IN THE CORONET CLUSTER, TAURUS, AND OTHER 1-8 Myr OLD REGIONS

    SciTech Connect

    Currie, Thayne; Sicilia-Aguilar, Aurora

    2011-05-01

    We present Spitzer 3.6-24 {mu}m photometry and spectroscopy for stars in the 1-3 Myr old Coronet Cluster, expanding upon the survey of Sicilia-Aguilar et al. Using sophisticated radiative transfer models, we analyze these new data and those from Sicilia-Aguilar et al. to identify disks with evidence for substantial dust evolution consistent with disk clearing: transitional disks. We then analyze data in Taurus and others young clusters-IC 348, NGC 2362, and {eta} Cha-to constrain the transitional disk frequency as a function of time. Our analysis confirms previous results finding evidence for two types of transitional disks-those with inner holes and those that are homologously depleted. The percentage of disks in the transitional phase increases from {approx}15%-20% at 1-2 Myr to {>=}50% at 5-8 Myr; the mean transitional disk lifetime is closer to {approx}1 Myr than 0.1-0.5 Myr, consistent with previous studies by Currie et al. and Sicilia-Aguilar et al. In the Coronet Cluster and IC 348, transitional disks are more numerous for very low mass M3-M6 stars than for more massive K5-M2 stars, while Taurus lacks a strong spectral-type-dependent frequency. Assuming standard values for the gas-to-dust ratio and other disk properties, the lower limit for the masses of optically thick primordial disks is M{sub disk} {approx} 0.001-0.003 M{sub *}. We find that single color-color diagrams do not by themselves uniquely identify transitional disks or primordial disks. Full spectral energy distribution modeling is required to accurately assess disk evolution for individual sources and inform statistical estimates of the transitional disk population in large samples using mid-IR colors.

  1. Lymphatic vessels transition to state of summation above a critical contraction frequency.

    PubMed

    Meisner, Joshua K; Stewart, Randolph H; Laine, Glen A; Quick, Christopher M

    2007-07-01

    Although behavior of lymphatic vessels is analogous to that of ventricles, which completely relax between contractions, and blood vessels, which maintain a tonic constriction, the mixture of contractile properties can yield behavior unique to lymphatic vessels. In particular, because of their limited refractory period and slow rate of relaxation, lymphatic vessels lack the contractile properties that minimize summation in ventricles. We, therefore, hypothesized that lymphatic vessels transition to a state of summation when lymphatic vessel contraction frequency exceeds a critical value. We used an isovolumic, controlled-flow preparation to compare the time required for full relaxation with the time available to relax during diastole. We measured transmural pressure and diameter on segments of spontaneously contracting bovine mesenteric lymphatic vessels during 10 isovolumic volume steps. We found that beat-to-beat period (frequency(-1)) decreased with increases in diameter and that total contraction time was constant or slightly increased with diameter. We further found that the convergence of beat-to-beat period and contraction cycle duration predicted a critical transition value, beyond which the vessel does not have time to fully relax. This incomplete relaxation and resulting mechanical summation significantly increase active tension in diastole. Because this transition occurs within a physiological range, contraction summation may represent a fundamental feature of lymphatic vessel function. PMID:17363681

  2. Computational IR spectroscopy of water: OH stretch frequencies, transition dipoles, and intermolecular vibrational coupling constants

    NASA Astrophysics Data System (ADS)

    Choi, Jun-Ho; Cho, Minhaeng

    2013-05-01

    The Hessian matrix reconstruction method initially developed to extract the basis mode frequencies, vibrational coupling constants, and transition dipoles of the delocalized amide I, II, and III vibrations of polypeptides and proteins from quantum chemistry calculation results is used to obtain those properties of delocalized O-H stretch modes in liquid water. Considering the water symmetric and asymmetric O-H stretch modes as basis modes, we here develop theoretical models relating vibrational frequencies, transition dipoles, and coupling constants of basis modes to local water configuration and solvent electric potential. Molecular dynamics simulation was performed to generate an ensemble of water configurations that was in turn used to construct vibrational Hamiltonian matrices. Obtaining the eigenvalues and eigenvectors of the matrices and using the time-averaging approximation method, which was developed by the Skinner group, to calculating the vibrational spectra of coupled oscillator systems, we could numerically simulate the O-H stretch IR spectrum of liquid water. The asymmetric line shape and weak shoulder bands were quantitatively reproduced by the present computational procedure based on vibrational exciton model, where the polarization effects on basis mode transition dipoles and inter-mode coupling constants were found to be crucial in quantitatively simulating the vibrational spectra of hydrogen-bond networking liquid water.

  3. Tuning of Strouhal number for high propulsive efficiency accurately predicts how wingbeat frequency and stroke amplitude relate and scale with size and flight speed in birds.

    PubMed Central

    Nudds, Robert L.; Taylor, Graham K.; Thomas, Adrian L. R.

    2004-01-01

    The wing kinematics of birds vary systematically with body size, but we still, after several decades of research, lack a clear mechanistic understanding of the aerodynamic selection pressures that shape them. Swimming and flying animals have recently been shown to cruise at Strouhal numbers (St) corresponding to a regime of vortex growth and shedding in which the propulsive efficiency of flapping foils peaks (St approximately fA/U, where f is wingbeat frequency, U is cruising speed and A approximately bsin(theta/2) is stroke amplitude, in which b is wingspan and theta is stroke angle). We show that St is a simple and accurate predictor of wingbeat frequency in birds. The Strouhal numbers of cruising birds have converged on the lower end of the range 0.2 < St < 0.4 associated with high propulsive efficiency. Stroke angle scales as theta approximately 67b-0.24, so wingbeat frequency can be predicted as f approximately St.U/bsin(33.5b-0.24), with St0.21 and St0.25 for direct and intermittent fliers, respectively. This simple aerodynamic model predicts wingbeat frequency better than any other relationship proposed to date, explaining 90% of the observed variance in a sample of 60 bird species. Avian wing kinematics therefore appear to have been tuned by natural selection for high aerodynamic efficiency: physical and physiological constraints upon wing kinematics must be reconsidered in this light. PMID:15451698

  4. Liquid-glass transition as the freezing of characteristic acoustic frequencies

    SciTech Connect

    Sanditov, D. S.

    2010-11-15

    Half-quantum interpretation is proposed for the liquid-glass transition as the freezing of characteristic acoustic frequencies (degrees of freedom) that are related to the molecular mobility of delocalized excited kinetic units, namely, linear quantum oscillators. There exists a correlation between the energy quantum of an elementary excitation (atom delocalization energy) and the glass transition temperature, which is proportional to the characteristic Einstein temperature. By analogy with the Einstein theory of the heat capacity of solids, the temperature range of the concentration of excited atoms in an amorphous medium is divided into the following two regions: a high-temperature region with a linear temperature dependence of this concentration and a low-temperature region, where the concentration of excited atoms decreases exponentially to the limiting minimum value (about 3%). At this value, the viscosity increases to a critical value (about 10{sup 12} Pa s), which corresponds to the glass transition temperature, i.e., the temperature of freezing the mobility of excited kinetic units. The temperature dependence of the free activation energy of viscous flow in the glass transition range is specified by the temperature dependence of the relative number of excited atoms.

  5. A geometric frequency-magnitude scaling transition: Measuring b = 1.5 for large earthquakes

    NASA Astrophysics Data System (ADS)

    Yoder, Mark R.; Holliday, James R.; Turcotte, Donald L.; Rundle, John B.

    2012-04-01

    We identify two distinct scaling regimes in the frequency-magnitude distribution of global earthquakes. Specifically, we measure the scaling exponent b = 1.0 for "small" earthquakes with 5.5 < m < 7.6 and b = 1.5 for "large" earthquakes with 7.6 < m < 9.0. This transition at mt = 7.6, can be explained by geometric constraints on the rupture. In conjunction with supporting literature, this corroborates theories in favor of fully self-similar and magnitude independent earthquake physics. We also show that the scaling behavior and abrupt transition between the scaling regimes imply that earthquake ruptures have compact shapes and smooth rupture-fronts.

  6. Toward accurate thermochemical models for transition metals : G3large basis sets for atoms Sc-Zn.

    SciTech Connect

    Mayhall, N. J.; Raghavachari, K.; Redfern, P. C.; Curtiss, L. A.; Rassolov, V.; Indiana Univ.; Univ. of South Carolina

    2008-04-01

    An augmented valence triple-zeta basis set, referred to as G3Large, is reported for the first-row transition metal elements Sc through Zn. The basis set is constructed in a manner similar to the G3Large basis set developed previously for other elements (H-Ar, K, Ca, Ga-Kr) and used as a key component in Gaussian-3 theory. It is based on a contraction of a set of 15s13p5d Gaussian primitives to 8s7p3d, and also includes sets of f and g polarization functions, diffuse spd functions, and core df polarization functions. The basis set is evaluated with triples-augmented coupled cluster [CCSD(T)] and Brueckner orbital [BD(T)] methods for a small test set involving energies of atoms, atomic ions, and diatomic hydrides. It performs well for the low-lying s{yields}d excitation energies of atoms, atomic ionization energies, and the dissociation energies of the diatomic hydrides. The Brueckner orbital-based BD(T) method performs substantially better than Hartree-Fock-based CCSD(T) for molecules such as NiH, where the starting unrestricted Hartree-Fock wavefunction suffers from a high degree of spin contamination. Comparison with available data for geometries of transition metal hydrides also shows good agreement. A smaller basis set without core polarization functions, G3MP2Large, is also defined.

  7. Broad Frequency LTCC Vertical Interconnect Transition for Multichip Modules and System on Package Applications

    NASA Technical Reports Server (NTRS)

    Decrossas, Emmanuel; Glover, Michael D.; Porter, Kaoru; Cannon, Tom; Mantooth, H. Alan; Hamilton, M. C.

    2013-01-01

    Various stripline structures and flip chip interconnect designs for high-speed digital communication systems implemented in low temperature co-fired ceramic (LTCC) substrates are studied in this paper. Specifically, two different transition designs from edge launch 2.4 millimeter connectors to stripline transmission lines embedded in LTCC are discussed. After characterizing the DuPont (sup trademark) 9K7 green tape, different designs are proposed to improve signal integrity for high-speed digital data. The full-wave simulations and experimental data validate the presented designs over a broad frequency band from Direct Current to 50 gigahertz and beyond.

  8. The nature and role of quantized transition states in the accurate quantum dynamics of the reaction O + H2 yields OH + H

    NASA Technical Reports Server (NTRS)

    Chatfield, David C.; Friedman, Ronald S.; Lynch, Gillian C.; Truhlar, Donald G.; Schwenke, David W.

    1993-01-01

    Accurate quantum mechanical dynamics calculations are reported for the reaction probabilities of O(3P) + H2 yields OH + H with zero total angular momentum on a single potential energy surface. The results show that the reactive flux is gated by quantized transition states up to the highest energy studied, which corresponds to a total energy of 1.90 eV. The quantized transition states are assigned and compared to vibrationally adiabatic barrier maxima; their widths and transmission coefficients are determined; and they are classified as variational, supernumerary of the first kind, and supernumerary of the second kind. Their effects on state-selected and state-to-state reactivity are discussed in detail.

  9. Accurate Potential Energy Surface, Rovibrational Energy Levels, and Transitions of Ammonia C_{3v} Isotopologues: ^{14}NH_3, ^{15}NH_3, ^{14}ND_3 and ^{14}NT_3

    NASA Astrophysics Data System (ADS)

    Huang, Xinchuan; Schwenke, David W.; Lee, Timothy J.

    2009-06-01

    A further refined, global potential energy surface (PES) is computed for the C_{3v} symmetry isotopologues of ammonia, including ^{14}NH_3, ^{15}NH_3, ^{14}ND_3 and ^{14}NT_3. The refinement procedure was similar to that used in our previously reported PES, but now extends to higher J energy levels and other isotopologues. Both the diagonal Born-Oppenheimer correction and the non-adiabatic correction were included. J=0-6 rovibrational energy levels and transition frequencies of ^{14}NH_3 computed on this PES are in excellent agreement with HITRAN data. Statistics on nearly 4100 transitions and more than 1000 energy levels demonstrate the accuracy achieved by the state-of-the-art "Best Theory + Experiment" strategy. Most transition frequencies are of ±0.01-0.02 cm^{-1} accuracy. Similar accuracy has been found on ^{15}NH_3 J=0-3 rovibrational energy levels. Several transitions and energy levels in HITRAN have been identified as unreliable or suspicious, and some have been re-assigned. For ^{14}ND_3 and ^{14}NT_3, J=0-3 calculations have been performed. Agreement for pure rotation-inversion transitions is nearly perfect, with more reliable energy levels presented. On the other hand, our J=0 results suggest a re-analysis on the ^{14}ND_3 ν_1 band origin is needed. Finally, we will discuss possible future refinements leading to an even better final PES for Ammonia. X. Huang, D.W. Schwenke, and T.J. Lee, J. Chem. Phys. 129, 214304 (2008).

  10. Accurate electronic and chemical properties of 3d transition metal oxides using a calculated linear response U and a DFT + U(V) method

    NASA Astrophysics Data System (ADS)

    Xu, Zhongnan; Joshi, Yogesh V.; Raman, Sumathy; Kitchin, John R.

    2015-04-01

    We validate the usage of the calculated, linear response Hubbard U for evaluating accurate electronic and chemical properties of bulk 3d transition metal oxides. We find calculated values of U lead to improved band gaps. For the evaluation of accurate reaction energies, we first identify and eliminate contributions to the reaction energies of bulk systems due only to changes in U and construct a thermodynamic cycle that references the total energies of unique U systems to a common point using a DFT + U(V ) method, which we recast from a recently introduced DFT + U(R) method for molecular systems. We then introduce a semi-empirical method based on weighted DFT/DFT + U cohesive energies to calculate bulk oxidation energies of transition metal oxides using density functional theory and linear response calculated U values. We validate this method by calculating 14 reactions energies involving V, Cr, Mn, Fe, and Co oxides. We find up to an 85% reduction of the mean average error (MAE) compared to energies calculated with the Perdew-Burke-Ernzerhof functional. When our method is compared with DFT + U with empirically derived U values and the HSE06 hybrid functional, we find up to 65% and 39% reductions in the MAE, respectively.

  11. Accurate electronic and chemical properties of 3d transition metal oxides using a calculated linear response U and a DFT + U(V) method

    SciTech Connect

    Xu, Zhongnan; Kitchin, John R.; Joshi, Yogesh V.; Raman, Sumathy

    2015-04-14

    We validate the usage of the calculated, linear response Hubbard U for evaluating accurate electronic and chemical properties of bulk 3d transition metal oxides. We find calculated values of U lead to improved band gaps. For the evaluation of accurate reaction energies, we first identify and eliminate contributions to the reaction energies of bulk systems due only to changes in U and construct a thermodynamic cycle that references the total energies of unique U systems to a common point using a DFT + U(V ) method, which we recast from a recently introduced DFT + U(R) method for molecular systems. We then introduce a semi-empirical method based on weighted DFT/DFT + U cohesive energies to calculate bulk oxidation energies of transition metal oxides using density functional theory and linear response calculated U values. We validate this method by calculating 14 reactions energies involving V, Cr, Mn, Fe, and Co oxides. We find up to an 85% reduction of the mean average error (MAE) compared to energies calculated with the Perdew-Burke-Ernzerhof functional. When our method is compared with DFT + U with empirically derived U values and the HSE06 hybrid functional, we find up to 65% and 39% reductions in the MAE, respectively.

  12. Abrupt and gradual transitions between low and hyperexcited firing frequencies in neuronal models with fast synaptic excitation: A comparative study

    NASA Astrophysics Data System (ADS)

    Rotstein, Horacio G.

    2013-12-01

    Hyperexcitability of neuronal networks is one of the hallmarks of epileptic brain seizure generation, and results from a net imbalance between excitation and inhibition that promotes excessive abnormal firing frequencies. The transition between low and high firing frequencies as the levels of recurrent AMPA excitation change can occur either gradually or abruptly. We used modeling, numerical simulations, and dynamical systems tools to investigate the biophysical and dynamic mechanisms that underlie these two identified modes of transition in recurrently connected neurons via AMPA excitation. We compare our results and demonstrate that these two modes of transition are qualitatively different and can be linked to different intrinsic properties of the participating neurons.

  13. Layering effects on low frequency modes in n-layered MX2 transition metal dichalcogenides.

    PubMed

    Cammarata, Antonio; Polcar, Tomas

    2016-02-14

    n-Layered (n = 2, 3, 4) MX2 transition metal dichalcogenides (M = Mo, W; X = S, Se, Te) have been studied using DFT techniques. Long-range van der Waals forces have been modeled using the Grimme correction to capture interlayer interactions. We study the dynamic and electronic dependence of atomic displacement on the number of layers. We find that the displacement patterns mainly affected by a change in the layer number are low-frequency modes at Γ and A k-points; such modes are connected with the intrinsic tribological response. We disentangle electro-phonon coupling by combining orbital polarization, covalency and cophonicity analysis with phonon band calculations. We find that the frequency dependence on the number of layers and the atomic type has a non-trivial relation with the electronic charge distribution in the interlayer region. We show that the interlayer electronic density can be adjusted by appropriately tuning M-X cophonicity, acting as a knob to control vibrational frequencies, hence the intrinsic frictional response. The present results can be exploited to study the electro-phonon coupling effects in TMD-based materials beyond tribological applications. PMID:26806673

  14. Doppler-free two-photon absorption spectroscopy of rovibronic transition of naphthalene calibrated with an optical frequency comb

    NASA Astrophysics Data System (ADS)

    Nishiyama, A.; Nakashima, K.; Matsuba, A.; Misono, M.

    2015-12-01

    We performed Doppler-free two-photon absorption spectroscopy of naphthalene using an optical frequency comb as a frequency reference. Rotationally resolved rovibronic spectra were observed, and absolute frequencies of the rovibronic transitions were determined with an uncertainty of several tens of kHz. The resolution and precision of our system are finer than the natural width of naphthalene. We assigned 1466 lines of the Q (Ka) Q (J) transition and calculated molecular constants. We attribute systematic spectral line shifts to the Coriolis interaction, and discuss the origin of the spectral linewidths.

  15. Accurate spectroscopic properties of 19 low-lying states of PCl radical including the electronic transition properties

    NASA Astrophysics Data System (ADS)

    Wang, Xinxin; Shi, Deheng; Sun, Jinfeng; Zhu, Zunlue

    2015-02-01

    The spectroscopic properties are in detail studied for the 11Σ-, 21Σ-, b1Σ+, c1Π, 21Π, 31Π, a1Δ, 21Δ, X3Σ-, C3Σ-, 33Σ-, 13Σ+, A3Π, B3Π, 33Π, 13Δ, 23Δ, 15Σ- and 15Π states, which are yielded from the first two dissociation limits, P(4Su) + Cl(2Pu) and P(2Du) + Cl(2Pu), of the PCl radical. Of the nineteen states, the 33Σ-, 13Σ+, 13Δ, 23Δ and 15Π states are the repulsive ones. The 21Σ-, 21Δ and 15Σ- states and the second well of A3Π state are very weakly-bound ones. The A3Π and B3Π states, the B3Π and 33Π states, and the 21Π and 31Π states have the avoided crossings. The A3Π state is found to possess the double well. The potential energy curves (PECs) are calculated with the CASSCF method followed by the internally contracted MRCI approach with Davidson correction together with the Dunning's correlation-consistent basis sets, aug-cc-pV6Z. To improve the quality of PECs, core-valence correlation and scalar relativistic correction calculations are included simultaneously. The PECs are extrapolated to the complete basis set limit. The vibrational properties are evaluated for several weakly-bound states. The spectroscopic parameters are determined, and compared with those available in the literature. The Franck-Condon factors and radiative lifetimes of the transitions from the A3Π, B3Π and 33Π states to the X3Σ- state and from the c1Π, 21Π and 31Π states to the a1Δ state are calculated for several low vibrational states. And some necessary discussion is performed. Analyses demonstrate that the spectroscopic properties of PCl radical reported in this paper can be expected to be reliably predicted ones.

  16. Accurate rest frequencies for the submillimetre-wave lines of C{3}O in ground and vibrationally excited states below 400 cm-1

    NASA Astrophysics Data System (ADS)

    Bizzocchi, L.; Degli Esposti, C.; Dore, L.

    2008-12-01

    The submillimetre-wave spectrum of C3O (X^1Σ^+) has been investigated in the laboratory using a source-modulation microwave spectrometer equipped with a gas-phase flow pyrolysis system for the production of unstable chemical species. C3O was produced by thermal decomposition of fumaryl chloride at 900 °C. Thirty-seven new rotational transitions were observed in the frequency range 307-740 GHz for the ground vibrational state, reaching a J quantum number as high as 76. Additionally, new millimetre-wave and submillimetre-wave lines were recorded for the bending fundamental v5 = 1, and for its overtones v5 = 2 and v5 = 3 whose rotational spectra have been identified for the first time. The new laboratory measurements provide much improved rest frequencies in the submillimetre spectral region for the ground state spectra of C3O, and for the first levels of its low-energy v5 vibrational ladder, useful for the radioastronomical identification of their rotational lines in the ISM. Tables 5 to 8 are only available in electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/492/875

  17. Tuning of Kilopixel Transition Edge Sensor Bolometer Arrays with a Digital Frequency Multiplexed Readout System

    NASA Astrophysics Data System (ADS)

    MacDermid, Kevin; Hyland, Peter; Aubin, Francois; Bissonnette, Eric; Dobbs, Matt; Hubmayr, Johannes; Smecher, Graeme; Wairrach, Shahjahen

    2009-12-01

    A digital frequency multiplexing (DfMUX) system has been developed and used to tune large arrays of transition edge sensor (TES) bolometers read out with SQUID arrays for mm-wavelength cosmology telescopes. The DfMUX system multiplexes the input bias voltages and output currents for several bolometers on a single set of cryogenic wires. Multiplexing reduces the heat load on the camera's sub-Kelvin cryogenic detector stage. In this paper we describe the algorithms and software used to set up and optimize the operation of the bolometric camera. The algorithms are implemented on soft processors embedded within FPGA devices operating on each backend readout board. The result is a fully parallelized implementation for which the setup time is independent of the array size.

  18. Phase transition studies in barium and strontium titanates at microwave frequencies

    NASA Technical Reports Server (NTRS)

    Dahiya, Jai N.

    1993-01-01

    The objectives were the following: to understand the phase transformations in barium and strontium titanates as the crystals go from one temperature to the other; and to study the dielectric behavior of barium and strontium titanate crystals at a microwave frequency of 9.12 GHz and as a function of temperature. Phase transition studies in barium and strontium titanate are conducted using a cylindrical microwave resonant cavity as a probe. The cavity technique is quite successful in establishing the phase changes in these crystals. It appears that dipole relaxation plays an important role in the behavior of the dielectric response of the medium loading the cavity as phase change takes place within the sample. The method of a loaded resonant microwave cavity as applied in this work has proven to be sensitive enough to monitor small phase changes of the cavity medium.

  19. Frequency domain impedance measurements of erythrocytes. Constant phase angle impedance characteristics and a phase transition.

    PubMed Central

    Bao, J Z; Davis, C C; Schmukler, R E

    1992-01-01

    We report measurements of the electrical impedance of human erythrocytes in the frequency range from 1 Hz to 10 MHz, and for temperatures from 4 to 40 degrees C. In order to achieve high sensitivity in this frequency range, we embedded the cells in the pores of a filter, which constrains the current to pass through the cells in the pores. Based on the geometry of the cells embedded in the filter a circuit model is proposed for the cell-filter saline system. A constant phase angle (CPA) element, i.e., an impedance of the form Z = A/(j omega)alpha, where A is a constant, j = square root of -1, omega is angular frequency, and 0 less than alpha less than 1 has been used to describe the ac response of the interface between the cell surface and the electrolyte solution, i.e., the electrical double layer. The CPA and other elements of the circuit model are determined by a complex nonlinear least squares (CNLS) fit, which simultaneously fits the real and imaginary parts of the experimental data to the circuit model. The specific membrane capacitance is determined to be 0.901 +/- 0.036 microF/cm2, and the specific cytoplasm conductivity to be 0.413 +/- 0.031 S/m at 26 degrees C. The temperature dependence of the cytoplasm conductivity, membrane capacitance, and CPA element has been obtained. The membrane capacitance increases markedly at approximately 37 degrees C, which suggests a phase transition in the cell membrane. PMID:1600086

  20. Frequency domain impedance measurements of erythrocytes. Constant phase angle impedance characteristics and a phase transition.

    PubMed

    Bao, J Z; Davis, C C; Schmukler, R E

    1992-05-01

    We report measurements of the electrical impedance of human erythrocytes in the frequency range from 1 Hz to 10 MHz, and for temperatures from 4 to 40 degrees C. In order to achieve high sensitivity in this frequency range, we embedded the cells in the pores of a filter, which constrains the current to pass through the cells in the pores. Based on the geometry of the cells embedded in the filter a circuit model is proposed for the cell-filter saline system. A constant phase angle (CPA) element, i.e., an impedance of the form Z = A/(j omega)alpha, where A is a constant, j = square root of -1, omega is angular frequency, and 0 less than alpha less than 1 has been used to describe the ac response of the interface between the cell surface and the electrolyte solution, i.e., the electrical double layer. The CPA and other elements of the circuit model are determined by a complex nonlinear least squares (CNLS) fit, which simultaneously fits the real and imaginary parts of the experimental data to the circuit model. The specific membrane capacitance is determined to be 0.901 +/- 0.036 microF/cm2, and the specific cytoplasm conductivity to be 0.413 +/- 0.031 S/m at 26 degrees C. The temperature dependence of the cytoplasm conductivity, membrane capacitance, and CPA element has been obtained. The membrane capacitance increases markedly at approximately 37 degrees C, which suggests a phase transition in the cell membrane. PMID:1600086

  1. Accurate Predictions of Mean Geomagnetic Dipole Excursion and Reversal Frequencies, Mean Paleomagnetic Field Intensity, and the Radius of Earth's Core Using McLeod's Rule

    NASA Technical Reports Server (NTRS)

    Voorhies, Coerte V.; Conrad, Joy

    1996-01-01

    The geomagnetic spatial power spectrum R(sub n)(r) is the mean square magnetic induction represented by degree n spherical harmonic coefficients of the internal scalar potential averaged over the geocentric sphere of radius r. McLeod's Rule for the magnetic field generated by Earth's core geodynamo says that the expected core surface power spectrum (R(sub nc)(c)) is inversely proportional to (2n + 1) for 1 less than n less than or equal to N(sub E). McLeod's Rule is verified by locating Earth's core with main field models of Magsat data; the estimated core radius of 3485 kn is close to the seismologic value for c of 3480 km. McLeod's Rule and similar forms are then calibrated with the model values of R(sub n) for 3 less than or = n less than or = 12. Extrapolation to the degree 1 dipole predicts the expectation value of Earth's dipole moment to be about 5.89 x 10(exp 22) Am(exp 2)rms (74.5% of the 1980 value) and the expected geomagnetic intensity to be about 35.6 (mu)T rms at Earth's surface. Archeo- and paleomagnetic field intensity data show these and related predictions to be reasonably accurate. The probability distribution chi(exp 2) with 2n+1 degrees of freedom is assigned to (2n + 1)R(sub nc)/(R(sub nc). Extending this to the dipole implies that an exceptionally weak absolute dipole moment (less than or = 20% of the 1980 value) will exist during 2.5% of geologic time. The mean duration for such major geomagnetic dipole power excursions, one quarter of which feature durable axial dipole reversal, is estimated from the modern dipole power time-scale and the statistical model of excursions. The resulting mean excursion duration of 2767 years forces us to predict an average of 9.04 excursions per million years, 2.26 axial dipole reversals per million years, and a mean reversal duration of 5533 years. Paleomagnetic data show these predictions to be quite accurate. McLeod's Rule led to accurate predictions of Earth's core radius, mean paleomagnetic field

  2. Vocational Rehabilitation Counselors' Identified Transition Competencies: Perceived Importance, Frequency, and Preparedness

    ERIC Educational Resources Information Center

    Plotner, Anthony J.; Trach, John S.; Strauser, David R.

    2012-01-01

    Vocational rehabilitation (VR) professionals are critical partners in the transition process for students with disabilities; therefore, they are required to develop transition service delivery proficiencies. VR professional perceptions of transition competencies are seldom examined due to the perception that transition falls mainly on school-based…

  3. The effect of large amplitude motions on the transition frequency redshift in hydrogen bonded complexes: A physical picture

    SciTech Connect

    Mackeprang, Kasper; Kjaergaard, Henrik G.; Salmi, Teemu; Hänninen, Vesa; Halonen, Lauri

    2014-05-14

    We describe the vibrational transitions of the donor unit in water dimer with an approach that is based on a three-dimensional local mode model. We perform a perturbative treatment of the intermolecular vibrational modes to improve the transition wavenumber of the hydrogen bonded OH-stretching transition. The model accurately predicts the transition wavenumbers of the vibrations in water dimer compared to experimental values and provides a physical picture that explains the redshift of the hydrogen bonded OH-oscillator. We find that it is unnecessary to include all six intermolecular modes in the vibrational model and that their effect can, to a good approximation, be computed using a potential energy surface calculated at a lower level electronic structure method than that used for the unperturbed model.

  4. SU-D-18C-05: Variable Bolus Arterial Spin Labeling MRI for Accurate Cerebral Blood Flow and Arterial Transit Time Mapping

    SciTech Connect

    Johnston, M; Jung, Y

    2014-06-01

    Purpose: Arterial spin labeling (ASL) is an MRI perfusion imaging method from which quantitative cerebral blood flow (CBF) maps can be calculated. Acquisition with variable post-labeling delays (PLD) and variable TRs allows for arterial transit time (ATT) mapping and leads to more accurate CBF quantification with a scan time saving of 48%. In addition, T1 and M0 maps can be obtained without a separate scan. In order to accurately estimate ATT and T1 of brain tissue from the ASL data, variable labeling durations were invented, entitled variable-bolus ASL. Methods: All images were collected on a healthy subject with a 3T Siemens Skyra scanner. Variable-bolus Psuedo-continuous ASL (PCASL) images were collected with 7 TI times ranging 100-4300ms in increments of 700ms with TR ranging 1000-5200ms. All boluses were 1600ms when the TI allowed, otherwise the bolus duration was 100ms shorter than the TI. All TI times were interleaved to reduce sensitivity to motion. Voxel-wise T1 and M0 maps were estimated using a linear least squares fitting routine from the average singal from each TI time. Then pairwise subtraction of each label/control pair and averaging for each TI time was performed. CBF and ATT maps were created using the standard model by Buxton et al. with a nonlinear fitting routine using the T1 tissue map. Results: CBF maps insensitive to ATT were produced along with ATT maps. Both maps show patterns and averages consistent with literature. The T1 map also shows typical T1 contrast. Conclusion: It has been demonstrated that variablebolus ASL produces CBF maps free from the errors due to ATT and tissue T1 variations and provides M0, T1, and ATT maps which have potential utility. This is accomplished with a single scan in a feasible scan time (under 6 minutes) with low sensivity to motion.

  5. Frequency ratio of two optical clock transitions in 171Yb+ and constraints on the time variation of fundamental constants.

    PubMed

    Godun, R M; Nisbet-Jones, P B R; Jones, J M; King, S A; Johnson, L A M; Margolis, H S; Szymaniec, K; Lea, S N; Bongs, K; Gill, P

    2014-11-21

    Singly ionized ytterbium, with ultranarrow optical clock transitions at 467 and 436 nm, is a convenient system for the realization of optical atomic clocks and tests of present-day variation of fundamental constants. We present the first direct measurement of the frequency ratio of these two clock transitions, without reference to a cesium primary standard, and using the same single ion of 171Yb+. The absolute frequencies of both transitions are also presented, each with a relative standard uncertainty of 6×10(-16). Combining our results with those from other experiments, we report a threefold improvement in the constraint on the time variation of the proton-to-electron mass ratio, μ/μ=0.2(1.1)×10(-16)  yr(-1), along with an improved constraint on time variation of the fine structure constant, α/α=-0.7(2.1)×10(-17)  yr(-1). PMID:25479482

  6. On a Mechanism for Limiting the Frequency and Energy Characteristics of Lasers on Self-terminating Transitions of Metal Atoms

    NASA Astrophysics Data System (ADS)

    Yudin, N. A.; Yudin, N. N.

    2016-04-01

    Electrophysical approach to estimation of conditions for efficient pumping of active medium of lasers on selfterminating transitions of metal atoms in a gas discharge tube with electrodes in cold buffer zones is used. Existence of processes that enhance the effect of the well-known mechanism of limitation of radiation frequency and energy characteristics caused by the presence of a pre-pulse electron concentration in the discharge circuit of lasers on self-terminating transitions of metal atoms is demonstrated. The mechanism of influence of these processes on frequency and energy characteristics of lasers on self-terminating transitions of metal atoms and the technical methods of neutralization of these processes are considered. It is shown that the practical efficiency of a copper vapor laser can attain ~10% under conditions of neutralization of these processes.

  7. Rapid, Sensitive, and Accurate Evaluation of Drug Resistant Mutant (NS5A-Y93H) Strain Frequency in Genotype 1b HCV by Invader Assay.

    PubMed

    Yoshimi, Satoshi; Ochi, Hidenori; Murakami, Eisuke; Uchida, Takuro; Kan, Hiromi; Akamatsu, Sakura; Hayes, C Nelson; Abe, Hiromi; Miki, Daiki; Hiraga, Nobuhiko; Imamura, Michio; Aikata, Hiroshi; Chayama, Kazuaki

    2015-01-01

    Daclatasvir and asunaprevir dual oral therapy is expected to achieve high sustained virological response (SVR) rates in patients with HCV genotype 1b infection. However, presence of the NS5A-Y93H substitution at baseline has been shown to be an independent predictor of treatment failure for this regimen. By using the Invader assay, we developed a system to rapidly and accurately detect the presence of mutant strains and evaluate the proportion of patients harboring a pre-treatment Y93H mutation. This assay system, consisting of nested PCR followed by Invader reaction with well-designed primers and probes, attained a high overall assay success rate of 98.9% among a total of 702 Japanese HCV genotype 1b patients. Even in serum samples with low HCV titers, more than half of the samples could be successfully assayed. Our assay system showed a better lower detection limit of Y93H proportion than using direct sequencing, and Y93H frequencies obtained by this method correlated well with those of deep-sequencing analysis (r = 0.85, P <0.001). The proportion of the patients with the mutant strain estimated by this assay was 23.6% (164/694). Interestingly, patients with the Y93H mutant strain showed significantly lower ALT levels (p=8.8 x 10-4), higher serum HCV RNA levels (p=4.3 x 10-7), and lower HCC risk (p=6.9 x 10-3) than those with the wild type strain. Because the method is both sensitive and rapid, the NS5A-Y93H mutant strain detection system established in this study may provide important pre-treatment information valuable not only for treatment decisions but also for prediction of disease progression in HCV genotype 1b patients. PMID:26083687

  8. Effective Landau-Zener transitions in the circuit dynamical Casimir effect with time-varying modulation frequency

    NASA Astrophysics Data System (ADS)

    Dodonov, A. V.; Militello, B.; Napoli, A.; Messina, A.

    2016-05-01

    We consider the dissipative single-qubit circuit QED architecture in which the atomic transition frequency undergoes a weak external time modulation. For sinusoidal modulation with linearly varying frequency we derive effective Hamiltonians that resemble the Landau-Zener problem of finite duration associated with a two- or multilevel systems. The corresponding off-diagonal coupling coefficients originate either from the rotating or the counter-rotating terms in the Rabi Hamiltonian, depending on the values of the modulation frequency. It is demonstrated that in the dissipationless case one can accomplish almost complete transitions between the eigenstates of the bare Rabi Hamiltonian even for relatively short durations of the frequency sweep. To assess the experimental feasibility of our scheme we solved numerically the phenomenological and the microscopic quantum master equations in the Markovian regime at zero temperature. Both models exhibit qualitatively similar behavior and indicate that photon generation from vacuum via effective Landau-Zener transitions could be implemented with the current technology on the time scales of a few microseconds. Moreover, unlike the harmonic dynamical Casimir effect implementations, our proposal does not require precise knowledge of the resonant modulation frequency to accomplish meaningful photon generation.

  9. Tunability over three frequency bands induced by mode transition in relativistic backward wave oscillator with strong end reflections

    SciTech Connect

    Wu, Ping; Deng, Yuqun; Fan, Juping; Teng, Yan; Shi, Yanchao; Sun, Jun

    2014-10-15

    This paper presents an efficient approach to realizing the frequency tunability of a relativistic backward wave oscillator (RBWO) over three frequency bands by mode transition without changing the slow wave structure (SWS). It is figured out that the transition of the operation mode in the RBWO can be efficiently achieved by using the strong end reflection of the SWS. This mode transition results in the tunability of the RBWO over three frequency bands at high power and high efficiency without changing the SWS. In numerical simulation, the output frequency of the RBWO can jump over 7.9 GHz in C-band, 9.9 GHz in X-band, and 12.4 GHz in Ku-band with output power exceeding 3.0 GW and conversion efficiency higher than 35% by just reasonably transforming the structures of the front and post resonant reflectors which provide the strong end reflection for the SWS.

  10. Transition frequencies of the D lines of K39 , K40 , and K41 measured with a femtosecond laser frequency comb

    NASA Astrophysics Data System (ADS)

    Falke, Stephan; Tiemann, Eberhard; Lisdat, Christian; Schnatz, Harald; Grosche, Gesine

    2006-09-01

    We report measurements of the transition frequencies 4sS1/22-4pP1/22 and 4sS1/22-4pP3/22 of the potassium isotopes 39, 40, and 41 through an atomic beam experiment with a fractional uncertainty of about 2×10-10 . For frequency calibration, a fs-laser comb referenced to a Cs atomic clock was used. Compared to previous results, hyperfine constants for the states 4pP1/22 and 4pP3/22 and isotope shifts are given with a considerably reduced uncertainty. This paper also resolves the discrepancy of transition frequencies measured by Banerjee [Phys. Rev. A 70, 052505 (2004)] and Scherf [Z. Phys. D 36, 31 (1996)] and the hyperfine constant A(K39,P1/22) reported by Banerjee [Europhys. Lett. 65, 172 (2004)] and Bendali [J. Phys. B 14, 4231 (1981)].

  11. Transition from Townsend to radio-frequency homogeneous dielectric barrier discharge in a roll-to-roll configuration

    NASA Astrophysics Data System (ADS)

    Bazinette, R.; Paillol, J.; Massines, F.

    2016-06-01

    The aim of this paper is to better understand the transition from Townsend to radio-frequency homogeneous dielectric barrier discharge (DBD) at atmospheric pressure. The study is done in an Ar/NH3 Penning mixture for an electrode configuration adapted to roll-to-roll plasma surface treatment. The study was led in a frequency range running from 50 kHz up to 8.3 MHz leading to different DBD modes with a 1 mm gas gap: Glow (GDBD), Townsend (TDBD), and Radio-frequency (RF-DBD). In the frequency range between TDBD and RF-DBD, from 250 kHz to 2.3 MHz, additional discharges are observed outside the inter-electrode gas gap. Because each high voltage electrode are inside a dielectric barrel, these additional discharges occur on the side of the barrel where the gap is larger. They disappear when the RF-DBD mode is attained in the 1 mm inter-electrode gas gap, i.e., for frequencies equal or higher than 3 MHz. Fast imaging and optical emission spectroscopy show that the additional discharges are radio-frequency DBDs while the inter-electrode discharge is a TDBD. The RF-DBD discharge mode is attained when electrons drift becomes low enough compared to the voltage oscillation frequency to limit electron loss at the anode. To check that the additional discharges are due to a larger gas gap and a lower voltage amplitude, the TDBD/RF-DBD transition is investigated as a function of the gas gap and the applied voltage frequency and amplitude. Results show that the increase in the frequency at constant gas gap or in the gas gap at constant frequency allows to obtain RF-DBD instead of TDBD. At low frequency and large gap, the increase in the applied voltage allows RF-DBD/TDBD transition. As a consequence, an electrode configuration allowing different gap values is a solution to successively have different discharge modes with the same applied voltage.

  12. Frequency stabilization of a 1083 nm fiber laser to ⁴He transition lines with optical heterodyne saturation spectroscopies.

    PubMed

    Gong, W; Peng, X; Li, W; Guo, H

    2014-07-01

    Two kinds of optical heterodyne saturation spectroscopies, namely, frequency modulation spectroscopy (FMS) and modulation transfer spectroscopy (MTS), are demonstrated for locking a fiber laser to the transition lines of metastable (4)He atoms around 1083 nm. The servo-loop error signals of FMS and MTS for stabilizing laser frequency are optimized by studying the dependence of the peak-to-peak amplitude and slope on the optical power of pump and probe beams. A comparison of the stabilization performances of FMS/MTS and polarization spectroscopy (PS) is presented, which shows that MTS exhibits relatively superior performance with the least laser frequency fluctuation due to its flat-background dispersive signal, originated from the four-wave mixing process. The Allan deviation of the stabilized laser frequency is 5.4 × 10(-12)@100 s with MTS for data acquired in 1000 s, which is sufficiently applicable for fields like laser cooling, optical pumping, and optical magnetometry. PMID:25085123

  13. Frequency stabilization of a 1083 nm fiber laser to {sup 4}He transition lines with optical heterodyne saturation spectroscopies

    SciTech Connect

    Gong, W.; Peng, X. Li, W.; Guo, H.

    2014-07-15

    Two kinds of optical heterodyne saturation spectroscopies, namely, frequency modulation spectroscopy (FMS) and modulation transfer spectroscopy (MTS), are demonstrated for locking a fiber laser to the transition lines of metastable {sup 4}He atoms around 1083 nm. The servo-loop error signals of FMS and MTS for stabilizing laser frequency are optimized by studying the dependence of the peak-to-peak amplitude and slope on the optical power of pump and probe beams. A comparison of the stabilization performances of FMS/MTS and polarization spectroscopy (PS) is presented, which shows that MTS exhibits relatively superior performance with the least laser frequency fluctuation due to its flat-background dispersive signal, originated from the four-wave mixing process. The Allan deviation of the stabilized laser frequency is 5.4 × 10{sup −12}@100 s with MTS for data acquired in 1000 s, which is sufficiently applicable for fields like laser cooling, optical pumping, and optical magnetometry.

  14. Frequency stabilization of a 1083 nm fiber laser to 4He transition lines with optical heterodyne saturation spectroscopies

    NASA Astrophysics Data System (ADS)

    Gong, W.; Peng, X.; Li, W.; Guo, H.

    2014-07-01

    Two kinds of optical heterodyne saturation spectroscopies, namely, frequency modulation spectroscopy (FMS) and modulation transfer spectroscopy (MTS), are demonstrated for locking a fiber laser to the transition lines of metastable 4He atoms around 1083 nm. The servo-loop error signals of FMS and MTS for stabilizing laser frequency are optimized by studying the dependence of the peak-to-peak amplitude and slope on the optical power of pump and probe beams. A comparison of the stabilization performances of FMS/MTS and polarization spectroscopy (PS) is presented, which shows that MTS exhibits relatively superior performance with the least laser frequency fluctuation due to its flat-background dispersive signal, originated from the four-wave mixing process. The Allan deviation of the stabilized laser frequency is 5.4 × 10-12@100 s with MTS for data acquired in 1000 s, which is sufficiently applicable for fields like laser cooling, optical pumping, and optical magnetometry.

  15. The discharge mode transition and O(5p1) production mechanism of pulsed radio frequency capacitively coupled plasma

    NASA Astrophysics Data System (ADS)

    Liu, X. Y.; Hu, J. T.; Liu, J. H.; Xiong, Z. L.; Liu, D. W.; Lu, X. P.; Shi, J. J.

    2012-07-01

    The discharge mode transition from uniform plasma across the gas gap to the α mode happens at the rising phase of the pulsed radio frequency capacitively coupled plasma (PRF CCP). This transition is attributed to the fast increasing stochastic heating at the edge of sheath. In the second stage with the stable current and voltage amplitude, the consistency between experimental and numerical spatial-temporal 777 nm emission profile suggests that He* and He2* dominate the production of O(5p1) through dissociation and excitation of O2. Finally, the sterilization efficiency of PRF CCP is found to be higher than that of plasma jet.

  16. Heating mode transition in a hybrid direct current/dual-frequency capacitively coupled CF{sub 4} discharge

    SciTech Connect

    Zhang, Quan-Zhi; Wang, You-Nian; Bogaerts, Annemie

    2014-06-14

    Computer simulations based on the particle-in-cell/Monte Carlo collision method are performed to study the plasma characteristics and especially the transition in electron heating mechanisms in a hybrid direct current (dc)/dual-frequency (DF) capacitively coupled CF{sub 4} discharge. When applying a superposed dc voltage, the plasma density first increases, then decreases, and finally increases again, which is in good agreement with experiments. This trend can be explained by the transition between the four main heating modes, i.e., DF coupling, dc and DF coupling, dc source dominant heating, and secondary electron dominant heating.

  17. Frequency of close companions among Kepler planets—a transit time variation study

    SciTech Connect

    Xie, Ji-Wei; Wu, Yanqin; Lithwick, Yoram E-mail: wu@astro.utoronto.ca

    2014-07-10

    A transiting planet exhibits sinusoidal transit time variations (TTVs) if perturbed by a companion near a mean-motion resonance. We search for sinusoidal TTVs in more than 2600 Kepler candidates, using the publicly available Kepler light curves (Q0-Q12). We find that the TTV fractions rise strikingly with the transit multiplicity. Systems where four or more planets transit enjoy a TTV fraction that is roughly five times higher than those where a single planet transits, and about twice as high as those for doubles and triples. In contrast, models in which all transiting planets arise from similar dynamical configurations predict comparable TTV fractions among these different systems. One simple explanation for our results is that there are at least two different classes of Kepler systems, one closely packed and one more sparsely populated.

  18. Transitions between various diffuse discharge modes in atmospheric-pressure helium in the medium-frequency range

    NASA Astrophysics Data System (ADS)

    Boisvert, J.-S.; Margot, J.; Massines, F.

    2016-08-01

    In this paper, we investigate DBDs in the medium frequency range (MF, 0.3–3 MHz). More precisely, for a 2 inter-dielectric gap in helium at atmospheric pressure, the frequency is varied from 1.0 to 2.7 MHz. The generated discharge shows similarities with both the low-frequency atmospheric-pressure glow discharge (APGD) and the atmospheric pressure capacitively coupled radio-frequency (CCRF) discharge. In the frequency range under investigation, two diffuse discharge modes can be observed depending on the voltage applied between the electrodes. At low applied voltage, the discharge emissions are barely visible and are concentrated in the center of the gas gap similarly to CCRF discharges in the Ω mode where the electron density is concentrated in the bulk. Ohmic heating is the main power transfer mechanism. At higher applied voltage, the discharge emissions are 10 times more intense and are closer to the dielectric surfaces similarly to the more common radio-frequency α mode. These two discharge modes can be observed in the same experimental conditions with the amplitude of the applied voltage as sole control parameter. The gas temperature obtained from N2 impurities rotational spectrum increases from room temperature to about 500 K while the power density rises from 10‑1 to 101 W cm‑3 when the applied voltage is increased. In addition, when the discharge transits back and forth from the Ω to the α mode, a hysteresis is observed. The transition from the Ω to the α mode occurs abruptly with a large RMS current increase while the transition from the α to the Ω mode is rather smooth with no significant discontinuity in the RMS current.

  19. Transitions.

    ERIC Educational Resources Information Center

    Nathanson, Jeanne H., Ed.

    1993-01-01

    This theme issue on transitions for individuals with disabilities contains nine papers discussing transition programs and issues. "Transition Issues for the 1990s," by Michael J. Ward and William D. Halloran, discusses self-determination, school responsibility for transition, continued educational engagement of at-risk students, and service…

  20. Calculation of high-pressure phase transitions in solid N2 and the pressure dependence of intramolecular mode frequencies

    NASA Technical Reports Server (NTRS)

    Chandrasekharan, V.; Etters, R. D.; Kobashi, K.

    1983-01-01

    A calculation that minimizes the energy of solid N2 with respect to a rhombohedral distortion of the Pm 3n structure shows that a low-temperature phase transition occurs into the R 3c calcite structure at P = 19.2 kbar with a volume change of 0.125 cu cm/mole. This transition agrees with recent Raman scattering measurements. Another transition from R 3c into R3(bar)m is predicted at P = 67.5 kbar, with a volume change of 0.1 cu cm/mole. The pressure dependence of the intramolecular mode frequencies for the R 3c structure are in reasonably good agreement with the two main branches observed experimentally.

  1. The Accuracy of Measurements of the Spectral-Line Frequencies in the Studies of the Rotational Transitions of the 16O12C32S Molecule in the Millimeter and Submillimeter Wave Ranges

    NASA Astrophysics Data System (ADS)

    Golubiatnikov, G. Yu; Belov, S. P.; Lapinov, A. V.

    2016-01-01

    The absolute error of determining the center frequency of the molecule spectral line during a single measurement, which is obtained by fitting the line shape to the model profile, is usually significantly smaller than the statistical spread in the frequencies of the repeated measurements. We discuss the possible causes of the systematic errors leading to an increase in the uncertainty of measurements of the line-center frequency. For an example of the multiple spectral measurements of the rotational transitions of the 16O12C32S molecule in the millimeter- and submillimeter-wave ranges (with a frequency of up to 522 GHz), by the Lamb-dip method, we determine the absolute error of the performed measurements, which amounts to 0 .4 kHz. New precision values of the center frequencies of the rotational transitions of the 16O12C32S molecule and more accurate values of the rotational constants, which are calculated using the measured frequencies, are presented.

  2. Observation and absolute frequency measurements of the 1S0-3P0 optical clock transition in neutral ytterbium.

    PubMed

    Hoyt, C W; Barber, Z W; Oates, C W; Fortier, T M; Diddams, S A; Hollberg, L

    2005-08-19

    We report the direct excitation of the highly forbidden (6s2) 1S0 <--> (6s6p) 3P0 optical transition in two odd isotopes of neutral ytterbium. As the excitation laser frequency is scanned, absorption is detected by monitoring the depletion from an atomic cloud at approximately 70 microK in a magneto-optical trap. The measured frequency in 171Yb (F=1/2) is 518,295,836,591.6 +/- 4.4 kHz. The measured frequency in 173Yb (F=5/2) is 518,294,576,847.6 +/- 4.4 kHz. Measurements are made with a femtosecond-laser frequency comb calibrated by the National Institute of Standards and Technology cesium fountain clock and represent nearly a 10(6)-fold reduction in uncertainty. The natural linewidth of these J=0 to J=0 transitions is calculated to be approximately 10 mHz, making them well suited to support a new generation of optical atomic clocks based on confinement in an optical lattice. PMID:16196856

  3. Frequency-domain multiplexed readout of transition-edge sensor arrays with a superconducting quantum interference device

    NASA Astrophysics Data System (ADS)

    Lanting, T. M.; Cho, Hsiao-Mei; Clarke, John; Holzapfel, W. L.; Lee, Adrian T.; Lueker, M.; Richards, P. L.; Dobbs, Matt A.; Spieler, Helmuth; Smith, A.

    2005-03-01

    We demonstrate an eight-channel frequency-domain readout multiplexer for superconducting transition-edge sensors (TESs). Each sensor is biased with a sinusoidal voltage at a unique frequency. The sensor currents are summed and measured with a single superconducting quantum interference device (SQUID) array. The 100-element SQUID array is operated with shunt feedback electronics that have a slew rate of 1.2×107Φ0/s at 1MHz. The multiplexer readout noise is 6.5pA/√Hz , which is well below the expected sensor noise of 15pA /√Hz . We measure an upper limit on adjacent channel crosstalk of 0.004, which meets our design requirements. The demodulated noise spectra of multiplexed TESs are white at frequencies down to 200mHz.

  4. Transitions.

    ERIC Educational Resources Information Center

    Field, David; And Others

    1992-01-01

    Includes four articles: "Career Aspirations" (Field); "Making the Transition to a New Curriculum" (Baker, Householder); "How about a 'Work to School' Transition?" (Glasberg); and "Technological Improvisation: Bringing CNC to Woodworking" (Charles, McDuffie). (SK)

  5. Absolute optical frequency measurements of the cesium D1 transitions and their effect on alpha, the fine-structured constant

    NASA Astrophysics Data System (ADS)

    Calkins, Keith Gordon

    The fine-structure constant or electromagnetic coupling constant, alpha e, is a dimensionless ratio which unites many physics subfields. Although known precisely via experiments in each subfield, there is disagreement within and between subfields. In particular, precise values obtained via electron ge - 2 experiments which depend heavily on QED calculations have not always been in agreement with those obtained via muon g mu - 2 experiments. Also, solid state measurements (quantum hall effect and AC Josephson effect) often disagree with neutronic hmn measurements. alphae is often said to vary with energy but the question remains as to whether or not its low energy value is stable now or has been stable over the history of the universe. Improved precision helps resolve these issues as they relate to physics, possibly beyond the standard model. The Optical Frequency Measurements group in the Time and Frequency Division at the National Institute of Science and Technology (NIST, Boulder, CO) developed and maintains a femtosecond laser frequency comb which is calibrated with respect to the cesium fountain clock implementation of the second. A single frequency component of the femtosecond laser comb is used together with a solid state diode laser and cesium thermal beam to precisely measure the cesium D1 F ∈ {3,4} transition frequencies. The value of fD1centroid = 335 116 048 748.1(2.4) kHz obtained for the transition centroid is over fifteen times more precise than the most recent previous measurement. A precise value for the cesium D1 hyperfine splitting fHFe = 1 167 723.6(4.7) kHz is reported as well. This value is also over fifteen times more precise than the most recent previous measurement. These new neutral 133Cs 6s 2 S½ → 6p 2 P½ transition (D1) frequencies, when combined with the 2002 CODATA values of the Rydberg, proton/electron mass ratio, cesium atomic mass, and cesium recoil frequency, provide an almost QED-free value of alpha: alphae = 1/137.036 0000

  6. Transition.

    ERIC Educational Resources Information Center

    Thompson, Sandy, Ed.; And Others

    1990-01-01

    This "feature issue" focuses on transition from school to adult life for persons with disabilities. Included are "success stories," brief program descriptions, and a list of resources. Individual articles include the following titles and authors: "Transition: An Energizing Concept" (Paul Bates); "Transition Issues for the 1990s" (William Halloran…

  7. Absolute frequency measurement of the 7s2 1S0-7s7p 1P1 transition in Ra225

    NASA Astrophysics Data System (ADS)

    Santra, B.; Dammalapati, U.; Groot, A.; Jungmann, K.; Willmann, L.

    2014-10-01

    Transition frequencies were determined for transitions in Ra in an atomic beam and for reference lines in Te2 molecules in a vapor cell. The absolute frequencies were calibrated against a GPS stabilized Rb clock by means of an optical frequency comb. The 7s21S0(F=1/2)-7s7p1P1(F =3/2) transition in Ra225 was determined to be 621042124(2)MHz. The measurements provide input for designing efficient and robust laser cooling of Ra atoms in preparation of a search for a permanent electric dipole moment in Ra isotopes.

  8. Adaptation of frequency-domain readout for Transition Edge Sensor bolometers for the POLARBEAR-2 Cosmic Microwave Background experiment

    NASA Astrophysics Data System (ADS)

    Hattori, Kaori; Arnold, Kam; Barron, Darcy; Dobbs, Matt; de Haan, Tijmen; Harrington, Nicholas; Hasegawa, Masaya; Hazumi, Masashi; Holzapfel, William L.; Keating, Brian; Lee, Adrian T.; Morii, Hideki; Myers, Michael J.; Smecher, Graeme; Suzuki, Aritoki; Tomaru, Takayuki

    2013-12-01

    The POLARBEAR-2 Cosmic Microwave Background (CMB) experiment aims to observe B-mode polarization with high sensitivity to explore gravitational lensing of CMB and inflationary gravitational waves. POLARBEAR-2 is an upgraded experiment based on POLARBEAR-1, which had first light in January 2012. For POLARBEAR-2, we will build a receiver that has 7588 Transition Edge Sensor (TES) bolometers coupled to two-band (95 and 150 GHz) polarization-sensitive antennas. For the large array's readout, we employ digital frequency-domain multiplexing and multiplex 32 bolometers through a single superconducting quantum interference device (SQUID). An 8-bolometer frequency-domain multiplexing readout has been deployed with the POLARBEAR-1 experiment. Extending that architecture to 32 bolometers requires an increase in the bandwidth of the SQUID electronics to 3 MHz. To achieve this increase in bandwidth, we use Digital Active Nulling (DAN) on the digital frequency multiplexing platform. In this paper, we present requirements and improvements on parasitic inductance and resistance of cryogenic wiring and capacitors used for modulating bolometers. These components are problematic above 1 MHz. We also show that our system is able to bias a bolometer in its superconducting transition at 3 MHz.

  9. Tuning the Attempt Frequency of Protein Folding Dynamics via Transition-State Rigidification: Application to Trp-cage

    PubMed Central

    Abaskharon, Rachel M.; Culik, Robert M.; Woolley, G. Andrew; Gai, Feng

    2015-01-01

    The attempt frequency or prefactor (k0) of the transition state rate equation of protein folding kinetics has been estimated to be on the order of 106 s−1, which is many orders of magnitude smaller than that of chemical reactions. Herein, we use the mini-protein Trp-cage to show that it is possible to significantly increase the value of k0 for a protein folding reaction by rigidifying the transition state. This is achieved by reducing the conformational flexibility of a key structural element (i.e., an α-helix) formed in the transition state via photoisomerization of an azobenzene cross-linker. We find that this strategy not only decreases the folding time of the Trp-cage peptide by more than an order of magnitude (to ~100 ns at 25 °C) but also exposes parallel folding pathways, allowing us to provide, to the best of our knowledge, the first quantitative assessment of the curvature of the transition state free energy surface of a protein. PMID:26120378

  10. Magnetic structure and frequency scaling of limit-cycle oscillations close to L- to H-mode transitions

    NASA Astrophysics Data System (ADS)

    Birkenmeier, G.; Cavedon, M.; Conway, G. D.; Manz, P.; Stroth, U.; Fischer, R.; Fuchert, G.; Happel, T.; Laggner, F. M.; Maraschek, M.; Medvedeva, A.; Nikolaeva, V.; Prisiazhniuk, D.; Pütterich, T.; Ryter, F.; Shao, L. M.; Willensdorfer, M.; Wolfrum, E.; Zohm, H.; the ASDEX Upgrade Team

    2016-08-01

    Limit-cycle oscillations (LCOs) close to the power threshold of L- to H-mode transitions are investigated in plasmas of ASDEX Upgrade. During this phase, referred to as I-phase, a strong magnetic activity in the poloidal magnetic field {{\\overset{\\centerdot}{{B}} }θ} with an up–down asymmetry is found. In some cases, the regular LCOs during I-phase transition smoothly into a phase with intermittent bursts which have similar properties to type-III edge localised modes (ELMs). Indications of precursors during the intermittent phase as well as in the regular LCO phase point to a common nature of the I-phase and type-III ELMs. The LCO frequency measured in a set of discharges with different plasma currents and magnetic fields scales as f∼ ≤ft(B\\text{t}1/2I\\text{p}3/2\\right)/(nT) .

  11. Excess of low frequency vibrational modes and glass transition: A molecular dynamics study for soft spheres at constant pressure

    NASA Astrophysics Data System (ADS)

    Flores-Ruiz, Hugo M.; Naumis, Gerardo G.

    2009-10-01

    Using molecular dynamics at constant pressure, the relationship between the excess of low frequency vibrational modes (known as the boson peak) and the glass transition is investigated for a truncated Lennard-Jones potential. It is observed that the quadratic mean displacement is enhanced by such modes, as predicted using a harmonic Hamiltonian for metastable states. As a result, glasses loose mechanical stability at lower temperatures than the corresponding crystal, since the Lindemann criteria are observed, as is also deduced from density functional theory. Finally, we found that the average force and elastic constant are reduced in the glass due to such excess of modes. The ratio between average elastic constants can be approximated using the 2/3 rule between melting and glass transition temperatures.

  12. Evaluation of variation in ( m_p/m_e) from the frequency difference between the 15N2+ and 87Sr transitions

    NASA Astrophysics Data System (ADS)

    Kajita, Masatoshi

    2016-07-01

    The uncertainty of the 87Sr1 S0-3 P0 transition frequency (429 THz) has been reduced to the level of 10^{-18}. Also, the 15N2+ Q(0) vibrational transition frequency is expected to be measured with an uncertainty of 10^{-17} , and the v = 0-7 transition frequency (422 THz) is close to the 87Sr transition frequency. In this paper, we propose a test for the variation in the proton-to-electron mass ratio μ via precise measurement of the difference (f_d=7 THz) between these transition frequencies. By measuring f_d within the uncertainty of 10^{-16}, a variation in μ of 4 × 10^{-18} can be detected. The 15N2+ v =0 -7 Q(0) transition frequency is free from Zeeman and electric quadrupole shifts. The dc Stark coefficient is about 0.2 mHz/(V/cm)2, and the measurement of f_d with an uncertainty lower than 10^{-16} appears to be attainable using molecular ions in a string crystal. The 15N2+ transition frequency is observed via the two-photon excitation of a laser with a wavelength of 1422 nm (laser A). Another laser with a wavelength of 1396 nm (laser B) is used as a 87Sr clock laser after frequency doubling. The frequency difference between lasers A and B (3.5 THz) should be measured using a frequency comb. Lasers A and B can be transferred to another laboratory via an optical fiber. Therefore, a sensitive test of the variation in μ can be performed in cooperation between two distant laboratories.

  13. Atomic Transition Frequencies, Isotope Shifts, and Sensitivity to Variation of the Fine Structure Constant for Studies of Quasar Absorption Spectra

    NASA Astrophysics Data System (ADS)

    Berengut, J. C.; Dzuba, V. A.; Flambaum, V. V.; King, J. A.; Kozlov, M. G.; Murphy, M. T.; Webb, J. K.

    Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental "constants" in the Universe. A change in the fine structure constant, α = {e}2/hslash c , could be detected via shifts in the frequencies of atomic transitions in quasar absorption systems. Recent studies using 140 absorption systems from the Keck telescope and 153 from the Very Large Telescope, suggest that α varies spatially (61). That is, in one direction on the sky α seems to have been smaller at the time of absorption, while in the opposite direction it seems to have been larger.

  14. Dynamics of electronic transitions and frequency dependence of negative capacitance in semiconductor diodes under high forward bias

    SciTech Connect

    Bansal, Kanika; Datta, Shouvik; Henini, Mohamed; Alshammari, Marzook S.

    2014-09-22

    We observed qualitatively dissimilar frequency dependence of negative capacitance under high charge injection in two sets of functionally different junction diodes: III-V based light emitting and Si-based non-light emitting diodes. Using an advanced approach based on bias activated differential capacitance, we developed a generalized understanding of negative capacitance phenomenon which can be extended to any diode based device structure. We explained the observations as the mutual competition of fast and slow electronic transition rates which are different in different devices. This study can be useful in understanding the interfacial effects in semiconductor heterostructures and may lead to superior device functionality.

  15. Effective theory for the nonrigid rotor in an electromagnetic field: Toward accurate and precise calculations of E2 transitions in deformed nuclei

    DOE PAGESBeta

    Coello Pérez, Eduardo A.; Papenbrock, Thomas F.

    2015-07-27

    In this paper, we present a model-independent approach to electric quadrupole transitions of deformed nuclei. Based on an effective theory for axially symmetric systems, the leading interactions with electromagnetic fields enter as minimal couplings to gauge potentials, while subleading corrections employ gauge-invariant nonminimal couplings. This approach yields transition operators that are consistent with the Hamiltonian, and the power counting of the effective theory provides us with theoretical uncertainty estimates. We successfully test the effective theory in homonuclear molecules that exhibit a large separation of scales. For ground-state band transitions of rotational nuclei, the effective theory describes data well within theoreticalmore » uncertainties at leading order. To probe the theory at subleading order, data with higher precision would be valuable. For transitional nuclei, next-to-leading-order calculations and the high-precision data are consistent within the theoretical uncertainty estimates. In addition, we study the faint interband transitions within the effective theory and focus on the E2 transitions from the 02+ band (the “β band”) to the ground-state band. Here the predictions from the effective theory are consistent with data for several nuclei, thereby proposing a solution to a long-standing challenge.« less

  16. Effective theory for the nonrigid rotor in an electromagnetic field: Toward accurate and precise calculations of E2 transitions in deformed nuclei

    SciTech Connect

    Coello Pérez, Eduardo A.; Papenbrock, Thomas F.

    2015-07-27

    In this paper, we present a model-independent approach to electric quadrupole transitions of deformed nuclei. Based on an effective theory for axially symmetric systems, the leading interactions with electromagnetic fields enter as minimal couplings to gauge potentials, while subleading corrections employ gauge-invariant nonminimal couplings. This approach yields transition operators that are consistent with the Hamiltonian, and the power counting of the effective theory provides us with theoretical uncertainty estimates. We successfully test the effective theory in homonuclear molecules that exhibit a large separation of scales. For ground-state band transitions of rotational nuclei, the effective theory describes data well within theoretical uncertainties at leading order. To probe the theory at subleading order, data with higher precision would be valuable. For transitional nuclei, next-to-leading-order calculations and the high-precision data are consistent within the theoretical uncertainty estimates. In addition, we study the faint interband transitions within the effective theory and focus on the E2 transitions from the 02+ band (the “β band”) to the ground-state band. Here the predictions from the effective theory are consistent with data for several nuclei, thereby proposing a solution to a long-standing challenge.

  17. Cloud frequency climatology at the Andes/Amazon transition: 1. Seasonal and diurnal cycles

    NASA Astrophysics Data System (ADS)

    Halladay, Kate; Malhi, Yadvinder; New, Mark

    2012-12-01

    Tropical montane regions present a complex local climate but one that may be very sensitive to local and global change. Therefore, it is important to assess their current climatological state, and to understand how the large-scale circulation may affect local-scale cloud patterns. We examine the cloud climatology of a tropical Andean montane region in the context of tropical South American climate in terms of seasonal/diurnal cycles using a corrected ISCCP (International Satellite Cloud Climatology Project) DX cloud product (1983-2008), MODIS (Moderate Resolution Imaging Spectroradiometer) MOD35 visible cloud flags (2000-2008) and ground-based cloud observations. Cloud climatologies were compared for three elevation zones: highlands (puna grassland), eastern slope (the montane forest) and lowlands. We found that in the dry season (JJA) the study area is part of a localized region of higher cloud frequency relative to other parts the eastern slope, and also relative to the adjacent highlands and lowlands. The highlands exhibited the greatest amplitude mean annual cycle of cloud frequency, with a minimum in June for all times of day. There were contrasts between the three zones with regard to the month in which the minimum cloud frequency occurs between different times of day. Higher lowland and eastern slope cloud frequencies compared with those on the puna in the early hours in the wet season suggest low-level convergence at lower elevations. Comparisons between satellite products show that ISCCP and MODIS produce very similar annual cycles although the absolute cloud frequencies are higher in ISCCP data.

  18. Training 2;6-Year-Olds to Produce the Transitive Construction: The Role of Frequency, Semantic Similarity and Shared Syntactic Distribution

    ERIC Educational Resources Information Center

    Abbot-Smith, Kirsten; Lieven, Elena; Tomasello, Michael

    2004-01-01

    Childers and Tomasello (2001) found that training 2 1/2-year-olds on the English transitive construction greatly improves their performance on a post-test in which they must use novel verbs in that construction. In the current study, we replicated Childers and Tomasello's finding, but using a much lower frequency of transitive verbs and models in…

  19. Frequency Scale Factors for Some Double-Hybrid Density Functional Theory Procedures: Accurate Thermochemical Components for High-Level Composite Protocols.

    PubMed

    Chan, Bun; Radom, Leo

    2016-08-01

    In the present study, we have obtained geometries and frequency scale factors for a number of double-hybrid density functional theory (DH-DFT) procedures. We have evaluated their performance for obtaining thermochemical quantities [zero-point vibrational energies (ZPVE) and thermal corrections for 298 K enthalpies (ΔH298) and 298 K entropies (S298)] to be used within high-level composite protocols (using the W2X procedure as a probe). We find that, in comparison with the previously prescribed protocol for optimization and frequency calculations (B3-LYP/cc-pVTZ+d), the use of contemporary DH-DFT methods such as DuT-D3 and DSD-type procedures leads to a slight overall improved performance compared with B3-LYP. A major strength of this approach, however, lies in the better robustness of the DH-DFT methods in that the largest deviations are notably smaller than those for B3-LYP. In general, the specific choices of the DH-DFT procedure and the associated basis set do not drastically change the performance. Nonetheless, we find that the DSD-PBE-P86/aug'-cc-pVTZ+d combination has a very slight edge over the others that we have examined, and we recommend its general use for geometry optimization and vibrational frequency calculations, in particular within high-level composite methods such as the higher-level members of the WnX series of protocols. The scale factors determined for DSD-PBE-P86/aug'-cc-pVTZ+d are 0.9830 (ZPVE), 0.9876 (ΔH298), and 0.9923 (S298). PMID:27471908

  20. Homoclinic and chaotic transitions in the rf (radio frequency) superconducting quantum interference device (SQUID). Presentation paper

    SciTech Connect

    Jacobs, E.W.; Bulsara, A.R.; Schieve, W.C.

    1989-06-01

    We consider a simple model of the flux in an rf superconducting quantum-interference device (SQUID) subjected to an external periodic magnetic field. The dynamic equation describing the flux response of the SQUID is solved analytically in the absence of damping and external driving terms. These terms are then introduced as perturbations, and the Melnikov function for the system is constructed. The transition from periodic to chaotic behavior is studied through a calculation of the Lyapunov exponents for the systems, and the dimension of the strange attracting set is calculated.

  1. Design and fabrication of a low-frequency (1-3 MHz) ultrasound transducer for accurate placement of screw implants in the spine

    NASA Astrophysics Data System (ADS)

    Manbachi, Amir; Lee, Mike; Foster, F. Stuart; Ginsberg, Howard J.; Cobbold, Richard S. C.

    2014-03-01

    In 2012 approximately 800,000 spinal fusion surgeries were performed in the United States, requiring the insertion of screws into the pedicles. Their exact placement is critical and made complex due to limited visibility of the spine, continuous bleeding in the exposed regions, and variability in morphologies. The alarmingly high rate of screw misplacements (up to 20%) reported in the literature is of major concern since such misplacements can place the surrounding vital structures at risk. A potential guidance method for determining the best screw trajectory is by the use of real-time ultrasound imaging similar to that used for intravascular imaging. An endovascular transducer could be inserted into the pedicle to image the anatomy from within and identify bone boundaries. A major challenge of imaging within bone is high signal attenuation. The rapid increase of attenuation with frequency requires much lower frequencies (1-3 MHz) than those used in intravascular imaging. This study describes the custom design and fabrication of 2 MHz ultrasound probes (3.5 mm diameter/ 11 Fr) for pedicle screw guidance. Three transducer designs are explored to provide improved sensitivity and signal to noise ratio, compared to the previously tested transducer within the pedicle. Experimental measurements are compared with the results obtained using various simulation tools. The work reported in this paper represents the first stage in our ultimate goal of developing a 32- element phased array that is capable of generating a radial B-mode image.

  2. Accurate absolute reference frequencies from 1511 to 1545 nm of the {nu}{sub 1}+{nu}{sub 3} band of {sup 12}C{sub 2}H{sub 2} determined with laser frequency comb interval measurements

    SciTech Connect

    Madej, Alan A.; Alcock, A. John; Czajkowski, Andrzej; Bernard, John E.; Chepurov, Sergei

    2006-10-15

    Absolute frequency measurements, with uncertainties as low as 2 kHz (1x10{sup -11}), are presented for the {nu}{sub 1}+{nu}{sub 3} band of {sup 12}C{sub 2}H{sub 2} at 1.5 {mu}m (194-198 THz). The measurements were made using cavity-enhanced, diode-laser-based saturation spectroscopy. With one laser system stabilized to the P(16) line of {sup 13}C{sub 2}H{sub 2} and a system stabilized to the line in {sup 12}C{sub 2}H{sub 2} whose frequency was to be determined, a Cr:YAG laser-based frequency comb was employed to measure the frequency intervals. The systematic uncertainty is notably reduced relative to that of previous studies, and the region of measured lines has been extended. Improved molecular constants are obtained.

  3. Transit-time devices as local oscillators for frequencies above 100 GHz

    NASA Technical Reports Server (NTRS)

    Eisele, H.; Kidner, C.; Haddad, G. I.

    1992-01-01

    Very promising preliminary experimental results have been obtained from GaAs IMPATT diodes at F-band frequencies (75 mW, 3.5 percent at 111.1 GHz and 20 mW, 1.4 percent at 120.6 GHz) and from GaAs TUNNETT diodes at W-band frequencies (26 mW, 1.6 percent at 87.2 GHz and 32 mW, 2.6 percent at 93.5 GHz). These results indicate that IMPATT, MITATT and TUNNETT diodes have the highest potential of delivering significant amounts of power at Terahertz frequencies. As shown recently, the noise performance of GaAs W-band IMPATT diodes can compete with that of Gunn devices. Since TUNNETT diodes take advantage of the quieter tunnel injection, they are expected to be especially suited for low-noise local oscillators. This paper will focus on the two different design principles for IMPATT and TUNNETT diodes, the material parameters involved in the design and some aspects of the present device technology. Single-drift flat-profile GaAs D-band IMPATT diodes had oscillations up to 129 GHz with 9 mW, 0.9 percent at 128.4 GHz. Single-drift GaAs TUNNETT diodes had oscillations up to 112.5 GHz with 16 mW and output power levels up to 33 mW and efficiencies up to 3.4 percent around 102 GHz. These results are the best reported so far from GaAs IMPATT and TUNNETT diodes.

  4. VizieR Online Data Catalog: Propenal (CH2CHCHO) transition frequencies (Daly+,

    NASA Astrophysics Data System (ADS)

    Daly, A. M.; Bermudez, C.; Kolesnikova, L.; Alonso, J. L.

    2015-08-01

    A commercially available sample of liquid propenal (b.p.=125°C) was used without further purification. Propenal spectrum was acquired using two different spectrometers. A recently upgraded Stark-modulation spectrometer employing 33kHz modulation frequency and phase-sensitive detection was used to cover the 26-110GHz range. Millimeter- and submillimeter-wave measurements, over the 50-660GHz range, were performed using a direct absorption spectrometer recently constructed at the University of Valladolid. See section 2 for further details. (2 data files).

  5. Order-disorder transition in conflicting dynamics leading to rank-frequency generalized beta distributions

    NASA Astrophysics Data System (ADS)

    Alvarez-Martinez, R.; Martinez-Mekler, G.; Cocho, G.

    2011-01-01

    The behavior of rank-ordered distributions of phenomena present in a variety of fields such as biology, sociology, linguistics, finance and geophysics has been a matter of intense research. Often power laws have been encountered; however, their validity tends to hold mainly for an intermediate range of rank values. In a recent publication (Martínez-Mekler et al., 2009 [7]), a generalization of the functional form of the beta distribution has been shown to give excellent fits for many systems of very diverse nature, valid for the whole range of rank values, regardless of whether or not a power law behavior has been previously suggested. Here we give some insight on the significance of the two free parameters which appear as exponents in the functional form, by looking into discrete probabilistic branching processes with conflicting dynamics. We analyze a variety of realizations of these so-called expansion-modification models first introduced by Wentian Li (1989) [10]. We focus our attention on an order-disorder transition we encounter as we vary the modification probability p. We characterize this transition by means of the fitting parameters. Our numerical studies show that one of the fitting exponents is related to the presence of long-range correlations exhibited by power spectrum scale invariance, while the other registers the effect of disordering elements leading to a breakdown of these properties. In the absence of long-range correlations, this parameter is sensitive to the occurrence of unlikely events. We also introduce an approximate calculation scheme that relates this dynamics to multinomial multiplicative processes. A better understanding through these models of the meaning of the generalized beta-fitting exponents may contribute to their potential for identifying and characterizing universality classes.

  6. Accurate frequency domain measurement of the best linear time-invariant approximation of linear time-periodic systems including the quantification of the time-periodic distortions

    NASA Astrophysics Data System (ADS)

    Louarroudi, E.; Pintelon, R.; Lataire, J.

    2014-10-01

    Time-periodic (TP) phenomena occurring, for instance, in wind turbines, helicopters, anisotropic shaft-bearing systems, and cardiovascular/respiratory systems, are often not addressed when classical frequency response function (FRF) measurements are performed. As the traditional FRF concept is based on the linear time-invariant (LTI) system theory, it is only approximately valid for systems with varying dynamics. Accordingly, the quantification of any deviation from this ideal LTI framework is more than welcome. The “measure of deviation” allows us to define the notion of the best LTI (BLTI) approximation, which yields the best - in mean square sense - LTI description of a linear time-periodic LTP system. By taking into consideration the TP effects, it is shown in this paper that the variability of the BLTI measurement can be reduced significantly compared with that of classical FRF estimators. From a single experiment, the proposed identification methods can handle (non-)linear time-periodic [(N)LTP] systems in open-loop with a quantification of (i) the noise and/or the NL distortions, (ii) the TP distortions and (iii) the transient (leakage) errors. Besides, a geometrical interpretation of the BLTI approximation is provided, leading to a framework called vector FRF analysis. The theory presented is supported by numerical simulations as well as real measurements mimicking the well-known mechanical Mathieu oscillator.

  7. Methods and systems for low frequency seismic and infrasound detection of geo-pressure transition zones

    DOEpatents

    Shook, G. Michael; LeRoy, Samuel D.; Benzing, William M.

    2006-07-18

    Methods for determining the existence and characteristics of a gradational pressurized zone within a subterranean formation are disclosed. One embodiment involves employing an attenuation relationship between a seismic response signal and increasing wavelet wavelength, which relationship may be used to detect a gradational pressurized zone and/or determine characteristics thereof. In another embodiment, a method for analyzing data contained within a response signal for signal characteristics that may change in relation to the distance between an input signal source and the gradational pressurized zone is disclosed. In a further embodiment, the relationship between response signal wavelet frequency and comparative amplitude may be used to estimate an optimal wavelet wavelength or range of wavelengths used for data processing or input signal selection. Systems for seismic exploration and data analysis for practicing the above-mentioned method embodiments are also disclosed.

  8. Systems for low frequency seismic and infrasound detection of geo-pressure transition zones

    DOEpatents

    Shook, G. Michael; LeRoy, Samuel D.; Benzing, William M.

    2007-10-16

    Methods for determining the existence and characteristics of a gradational pressurized zone within a subterranean formation are disclosed. One embodiment involves employing an attenuation relationship between a seismic response signal and increasing wavelet wavelength, which relationship may be used to detect a gradational pressurized zone and/or determine characteristics thereof. In another embodiment, a method for analyzing data contained within a response signal for signal characteristics that may change in relation to the distance between an input signal source and the gradational pressurized zone is disclosed. In a further embodiment, the relationship between response signal wavelet frequency and comparative amplitude may be used to estimate an optimal wavelet wavelength or range of wavelengths used for data processing or input signal selection. Systems for seismic exploration and data analysis for practicing the above-mentioned method embodiments are also disclosed.

  9. Accurate spectroscopic properties of 10 Λ-S states and 25 Ω states of BS+ cation including the electronic transition properties

    NASA Astrophysics Data System (ADS)

    Wang, Xinxin; Shi, Deheng; Zhou, Dan; Zhu, Zunlue; Sun, Jinfeng

    2015-11-01

    The potential energy curves of 10 Λ-S states of BS+ yielded from the first four dissociation limits are calculated by the internally contracted multireference configuration interaction approach with the Davidson correction. The core-valence correlation and scalar relativistic corrections are included. Basis on the calculated potential energy curves, the spectroscopic parameters are evaluated. All the PECs are extrapolated to the complete basis set limit. The spin-orbit coupling are taken into account by the state interaction method with the Breit-Pauli Hamiltonian. Finally, the transition dipole moments, Franck-Condon Factors and radiative lifetimes of transitions from the 23Π0-, 23Π0+, 23Σ0- and 23Σ1- states to ground state 13Π2 are predicted for future experiment.

  10. Relapse frequency in transitioning from natalizumab to dimethyl fumarate: assessment of risk factors.

    PubMed

    Zurawski, Jonathan; Flinn, Ashley; Sklover, Lindsay; Sloane, Jacob A

    2016-08-01

    Risk of relapse after natalizumab (NAT) cessation and switch to dimethyl fumarate (DMF) is unknown. The objective of this paper is to identify the risk and associated risk factors for relapse after switching from NAT to DMF in relapsing-remitting multiple sclerosis. Patients (n = 30) were treated with NAT for ≥12 months and then switched to DMF in a mean of 50 days. Patient age, annualized relapse rates (ARR), Expanded Disability Status Scale scores (EDSS), and lymphocyte counts were assessed. Overall, eight patients (27 %) had relapses after switching to DMF. Five patients (17 %) suffered severe relapses with multifocal clinical and radiological findings. New lesions by MRI (T2 hyperintense or enhancing) were observed in 35 % of patients. Relapses occurred at a mean of 3.5 months after NAT cessation. Patient age and elevated ARR prior to NAT use were significantly associated with risk of relapse after switch to DMF. Once on DMF for 4 months prior to relapse, lymphocyte count decreased more significantly in patients without relapses than those with relapses. Switching from NAT to DMF correlated with increased relapses. Young patient age, high ARR and stability of lymphocyte counts were risk factors for relapse after transition from NAT to DMF. PMID:27193310

  11. Energetic electron avalanches and mode transitions in planar inductively coupled radio-frequency driven plasmas operated in oxygen

    SciTech Connect

    Zaka-ul-Islam, M.; Niemi, K.; Gans, T.; O'Connell, D.

    2011-07-25

    Space and phase resolved optical emission spectroscopic measurements reveal that in certain parameter regimes, inductively coupled radio-frequency driven plasmas exhibit three distinct operation modes. At low powers, the plasma operates as an alpha-mode capacitively coupled plasma driven through the dynamics of the plasma boundary sheath potential in front of the antenna. At high powers, the plasma operates in inductive mode sustained through induced electric fields due to the time varying currents and associated magnetic fields from the antenna. At intermediate powers, close to the often observed capacitive to inductive (E-H) transition regime, energetic electron avalanches are identified to play a significant role in plasma sustainment, similar to gamma-mode capacitively coupled plasmas. These energetic electrons traverse the whole plasma gap, potentially influencing plasma surface interactions as exploited in technological applications.

  12. Detection of low-frequency lambda-doublet transitions of the free 12CH and 13CH radicals

    PubMed Central

    McCarthy, M. C.; Mohamed, S.; Brown, J. M.; Thaddeus, P.

    2006-01-01

    By Fourier transform microwave spectroscopy, lambda-doubling transitions of 12CH and 13CH in the lowest rotational levels of the X2∏1/2 ground state have been directly detected, which has not been done previously. For both radicals, hyperfine-split lines have been measured to an accuracy of better than 1 ppm between 3 and 15 GHz, an improvement of at least 2 orders of magnitude over previous laboratory data. The measured frequencies have been combined with all previous data for CH and 13CH in the v = 0 level of the X2∏ electronic state to determine improved hyperfine parameters. The production of CH from various gases also has been studied and, with methanol, the yield of CH relative to OH. Astronomical studies of CH in higher rotational levels and 13CH can now be undertaken on the basis of the present work. PMID:16894169

  13. Low-frequency Raman modes as fingerprints of layer stacking configurations of transition metal dichalcogenides

    NASA Astrophysics Data System (ADS)

    Liang, Liangbo; Puretzky, Alexander; Sumpter, Bobby; Meunier, Vincent; Geohegan, David; David B. Geohegan Team; Vincent Meunier Team

    The tunable optoelectronic properties of stacked two-dimensional (2D) crystal monolayers are determined by their stacking orientation, order, and atomic registry. Atomic-resolution Z-contrast scanning transmission electron microscopy (AR-Z-STEM) can be used to determine the exact atomic registration between different layers in few-layer 2D stacks; however, fast and relatively inexpensive optical characterization techniques are essential for rapid development of the field. Using two- and three-layer MoSe2 and WSe2 crystals synthesized by chemical vapor deposition, we show that the generally unexplored low-frequency (LF) Raman modes (<50 cm-1) that originate from interlayer vibrations can serve as fingerprints to characterize not only the number of layers, but also their stacking configurations [Puretzky and Liang et al, ACS Nano 2015, 9, 6333]. First-principles Raman calculations and group theory analysis corroborate the experimental assignments determined by AR-Z-STEM and show that the calculated LF mode fingerprints are related to the 2D crystal symmetries. Our combined experimental/theoretical work demonstrates the LF Raman modes potentially more effective than HF Raman modes to probe the layer stacking and interlayer interaction for 2D materials. The authors acknowledge support from Eugene P. Wigner Fellowship at the Oak Ridge National Laboratory and the Center for Nanophase Materials Sciences, a DOE Office of Science User Facility.

  14. Spatial frequency heterodyne imaging of aqueous phase transitions inside multi-walled carbon nanotubes.

    PubMed

    Schunk, F M; Rand, D; Rose-Petruck, C

    2015-12-14

    The evaporation and condensation of water on multi-walled carbon nanotube (MWCNT) surfaces was studied as a function of temperature and time using X-ray spatial frequency heterodyne imaging (SFHI). SFHI is an imaging modality that produces an absorption and scatter image in a single exposure, and has increased sensitivity to variations in electron density relative to more common place X-ray imaging techniques. Differing features exhibited in the temporal scatter intensity profiles recorded during evaporation and condensation revealed the existence of an absorption-desorption hysteresis. Effects on the aforementioned phenomena due to chemical functionalization of the carbon nanotube surfaces were also monitored. The increased interaction potential between the functionalized MWCNT walls and water molecules altered the evaporation event time scale and increased the temperature at which condensation could take place. Theoretical calculations were used to correlate the shape of the observed scatter profiles during condensation to changes in the MWCNT cross section geometry and configuration of the contained water volume. Changes in evaporation time scales with temperature coincided with the boiling point for confined water predicted by the Kelvin equation, indicating that a thermodynamic description of mesoscopic confined water is permissible in some instances. PMID:26549826

  15. Masturbation Frequency and Sexual Function Domains Are Associated With Serum Reproductive Hormone Levels Across the Menopausal Transition

    PubMed Central

    Zheng, Huiyong; Avis, Nancy E.; Greendale, Gail A.; Harlow, Siobán D.

    2015-01-01

    Objective: To determine whether reproductive hormones are related to sexual function during the menopausal transition. Design: The Study of Women's Health Across the Nation (SWAN) is a multiethnic cohort study of the menopausal transition located at seven US sites. At baseline, the 3302 community-based participants, aged 42–52, had an intact uterus and at least one ovary and were not using exogenous hormones. Participants self-identified as White, Black, Hispanic, Chinese, or Japanese. At baseline and at each of the 10 follow-up visits, sexual function was assessed by self-administered questionnaires, and blood was drawn to assay serum levels of T, estradiol, FSH, SHBG, and dehydroepiandrosterone sulfate. Main Outcome Measures: Self-reported frequency of masturbation, sexual desire, sexual arousal, orgasm, and pain during intercourse. Results: Masturbation, sexual desire, and arousal were positively associated with T. Masturbation, arousal, and orgasm were negatively associated with FSH. Associations were modest. Estradiol was not related to any measured sexual function domain. Pain with intercourse was not associated with any hormone. Conclusions: Reproductive hormones were associated with sexual function in midlife women. T was positively associated, supporting the role of androgens in female sexual function. FSH was negatively associated, supporting the role of menopausal status in female sexual function. The modest associations in this large study suggest that the relationships are subtle and may be of limited clinical significance. PMID:25412335

  16. Direct measurement of transition frequencies in isolated pHe+ atoms, and new CPT-violation limits on the antiproton charge and mass.

    PubMed

    Hori, M; Eades, J; Hayano, R S; Ishikawa, T; Pirkl, W; Widmann, E; Yamaguchi, H; Torii, H A; Juhász, B; Horváth, D; Yamazaki, T

    2003-09-19

    A radio frequency quadrupole decelerator and achromatic momentum analyzer were used to decelerate antiprotons and produce p4He+ and p3He+ atoms in ultra-low-density targets, where collision-induced shifts of the atomic transition frequencies were negligible. The frequencies at near-vacuo conditions were measured by laser spectroscopy to fractional precisions of (6-19) x 10(-8). By comparing these with QED calculations and the antiproton cyclotron frequency, we set a new limit of 1 x 10(-8) on possible differences between the antiproton and proton charges and masses. PMID:14525361

  17. Performance of Frequency Division Multiplexing Readout System for AC-Biased Transition-Edge Sensor X-ray Microcalorimeters

    NASA Astrophysics Data System (ADS)

    Yamamoto, R.; Sakai, K.; Takei, Y.; Yamasaki, N. Y.; Mitsuda, K.

    2014-08-01

    Frequency division multiplexing (FDM) is a promising approach to read out a large format transition-edge sensor (TES) array for future astrophysical missions. We constructed a four channel FDM readout system using baseband feedback in the MHz band. We demonstrated the principle of our FDM method with an actual TES array, a multiplexing SQUID and LC band-pass filters under 100 mK. The resonant frequencies of LC filters were consistent with the design value with an accuracy of better than 3 %. We successfully obtained X-ray pulses from two TESs simultaneously but the energy resolution was degraded to about 100 eV at 5.9 keV and crosstalk effects were observed. The origin of the crosstalk effects is investigated by modified setups. Based on comparative experiments and numerical calculations, we conclude that the non-linearity of the SQUID is the cause of some of the crosstalk effects. Unlike the regular crosstalk effect from the adjoining channels, the crosstalk effect due to non-linearity observed in this paper occurs in all channels. Solving these problems will help us to obtain FDM readout with sufficient energy resolution.

  18. Generalized transition state theory calculations for the reactions D+H2 and H+D2 using an accurate potential energy surface: Explanation of the kinetic isotope effect

    NASA Astrophysics Data System (ADS)

    Garrett, Bruce C.; Truhlar, Donald G.

    1980-03-01

    Rate constants are calculated for the reactions D+H2→DH+H and H+D2→HD+D and compared to measured values. An accurate potential energy surface, based on the ab initio calculations of Liu and Siegbahn, was used. Rates were calculated using both conventional transition state theory and canonical variational theory. In the former, the generalized transition state dividing surface is located at the saddle point; in the latter it is located to maximize the generalized free energy of activation. We show that, in the absence of tunneling corrections, locating the generalized-transition-state dividing surface variationally has an important quantitative effect on the predicted rate constants for these systems and that, when tunneling is included, most of the effect of using a better dividing surface can be included in conventional transition state theory for these systems by using a consistent transmission coefficient for quantal scattering by the vibrationally adiabatic potential energy curve. Tunneling effects are important for these reactions even for temperatures larger than 400 K. We show how to separate classical recrossing effects from quantal corrections on reaction-coordinate motion in both the transmission coefficients and the kinetic isotope effects. Our most complete calculations are in excellent agreement with most of the measured rate constants and kinetic isotope effects.

  19. Using ecological forecasting of future vegetation transition and fire frequency change in the Sierra Nevada to assess fire management strategies

    NASA Astrophysics Data System (ADS)

    Thorne, J. H.; Schwartz, M. W.; Holguin, A. J.; Moritz, M.; Batllori, E.; Folger, K.; Nydick, K.

    2013-12-01

    Ecological systems may respond in complex manners as climate change progresses. Among the responses, site-level climate conditions may cause a shift in vegetation due to the physiological tolerances of plant species, and the fire return interval may change. Natural resource managers challenged with maintaining ecosystem health need a way to forecast how these processes may affect every location, in order to determine appropriate management actions and prioritize locations for interventions. We integrated climate change-driven vegetation type transitions with projected change in fire frequency for 45,203 km2 of the southern Sierra Nevada, California, containing over 10 land management agencies as well as private lands. This Magnitude of Change (MOC) approach involves classing vegetation types in current time according to their climate envelopes, and identifying which sites will in the future have climates beyond what that vegetation currently occurs in. Independently, fire models are used to determine the change in fire frequency for each site. We examined 82 vegetation types with >50 grid cell occurrences. We found iconic resources such as the giant sequoia, lower slope oak woodlands, and high elevation conifer forests are projected as highly vulnerable by models that project a warmer drier future, but not as much by models that project a warmer future that is not drier than current conditions. Further, there were strongly divergent vulnerabilities of these forest types across land ownership (National Parks versus US Forest Service lands), and by GCM. For example, of 50 giant sequoia (Sequoiadendron giganteum) groves and complexes, all but 3 (on Sierra National Forest) were in the 2 highest levels of risk of climate and fire under the GFDL A2 projection, while 15 groves with low-to-moderate risk were found on both the National Parks and National Forests 18 in the 2 under PCM A2. Landscape projections of potential MOC suggest that the region is likely to experience

  20. Measurement of absolute transition frequencies of {sup 87}Rb to nS and nD Rydberg states by means of electromagnetically induced transparency

    SciTech Connect

    Mack, Markus; Karlewski, Florian; Hattermann, Helge; Hoeckh, Simone; Jessen, Florian; Cano, Daniel; Fortagh, Jozsef

    2011-05-15

    We report the measurement of absolute excitation frequencies of {sup 87}Rb to nS and nD Rydberg states. The Rydberg transition frequencies are obtained by observing electromagnetically induced transparency on a rubidium vapor cell. The accuracy of the measurement of each state is < or approx. 1 MHz, which is achieved by frequency stabilizing the two diode lasers employed for the spectroscopy to a frequency comb and a frequency comb calibrated wavelength meter, respectively. Based on the spectroscopic data we determine the quantum defects of {sup 87}Rb, and compare it with previous measurements on {sup 85}Rb. We determine the ionization frequency from the 5S{sub 1/2}(F=1) ground state of {sup 87}Rb to 1010.029 164 6(3)THz, providing the binding energy of the ground state with an accuracy improved by two orders of magnitude.

  1. Accurate multiconfiguration calculations of energy levels, lifetimes, and transition rates for the silicon isoelectronic sequence. Ti IX - Ge XIX, Sr XXV, Zr XXVII, Mo XXIX

    NASA Astrophysics Data System (ADS)

    Jönsson, P.; Radžiūtė, L.; Gaigalas, G.; Godefroid, M. R.; Marques, J. P.; Brage, T.; Froese Fischer, C.; Grant, I. P.

    2016-01-01

    Multiconfiguration Dirac-Hartree-Fock (MCDHF) calculations and relativistic configuration interaction (RCI) calculations are performed for states of the 3s23p2, 3s3p3 and 3s23p3d configurations in the Si-like ions Ti IX - Ge XIX, Sr XXV, Zr XXVII and Mo XXIX. Valence and core-valence electron correlation effects are accounted for through large configuration state function expansions. Calculated energy levels are compared with data from other calculations and with experimental data from the reference databases. Lifetime and transition rates along with uncertainty estimations are given for all ions. Energies from the calculations are in excellent agreement with observations and computed wavelength are almost of spectroscopic accuracy, aiding line identification in spectra. Full Tables 2, 3, and 5 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/585/A26

  2. New Accurate Wavenumbers of H35Cl^+ and H37Cl^+ Rovibrational Transitions in the v=0-1 Band of the ^2Π State.

    NASA Astrophysics Data System (ADS)

    Domenech, Jose Luis; Cueto, Maite; Herrero, Victor Jose; Tanarro, Isabel; Cernicharo, Jose; Drouin, Brian

    2015-06-01

    HCl^+ is a key intermediate in the interstellar chemistry of chlorine. It has been recently identified in space from Herschel's spectra and it has also been detected in the laboratory through its optical emission, infrared and mm-wave spectra. Now that Hershchel is decomissioned, further astrophysical studies on this radical ion will likely rely on ground-based observations in the mid-infrared. We have used a difference frequency laser spectrometer coupled to a hollow cathode discharge to measure the absorption spectrum of H35Cl^+ and H37Cl^+ in the v=0-1 band of the ^2Π state with Dopppler limited resolution. The accuracy of the individual measurements (˜ 10 MHz (3σ)) relies on a solid state wavemeter referenced to an iodine-stabilized Ar^+ laser. The new data are being fit using the CALPGM software from JPL, and the current status will be presented. M. De Luca et al., Astrophys. J. Lett. 751, L37 (2012) W. D. Sheasley and C. W. Mathews, J. Mol. Spectrosc. 47, 420 (1973) P. B. Davies, P. A. Hamilton, B. A. Johnson, Mol. Phys. 57, 217 (1986) H. Gupta, B. J. Drouin, and J. C. Pearson, Astrophys. J. Lett. 751, L37 (2012)

  3. Red-shifted cyanide stretching frequencies in cyanide-bridged transition metal donor-acceptor complexes. Support for vibronic coupling

    SciTech Connect

    Watzky, M.A.; Endicott, J.F.; Song, X.

    1996-06-05

    Patterns in the cyanide stretching frequencies have been examined in several series of monometal- and CN{sup {minus}} bridged transition metal complexes. Metal-to-cyanide back-bonding can be identified as a major factor contributing to red shifts of v{sub CN} in monometal complexes. This effect is complicated in cyanide-bridged complexes in two ways: (a) when both metals can back-bond to cyanide, the net interaction is repulsive and results in a blue shift of v{sub CN}: and (b) when a donor and acceptor are bridged, V{sub CN} undergoes a substantial red shift (sometimes more than 60 cm{sup {minus}1} lower in energy than the parent monometal complex). These effects can be described by simple perturbational models for the electronic interactions. Monometal cyanide complexes and CN{sup {minus}}-bridged backbonding metals can be treated in terms of their perturbations of the CN{sup {minus}} {pi} and {pi}* orbitals by using a simple, Hueckel-like, three-center perturbational treatment of electronic interactions. However, bridged donor-acceptor pairs are best described by a vibronic model in which it is assumed that the extent of electronic delocalization is in equilibrium with variations of some nuclear coordinates. Consistent with this approach, it is found that (a) the oscillator strength of the donor-acceptor charge transfer (DACT) absorption is roughly proportional to the red shift of v{sub CN} and (b) there are strong symmetry constraints on the coupling.

  4. Atomic sulfur: Frequency measurement of the J = 0 left arrow 1 fine-structure transition at 56.3 microns by laser magnetic resonance

    NASA Technical Reports Server (NTRS)

    Brown, John M.; Evenson, Kenneth M.; Zink, Lyndon R.

    1994-01-01

    The J = 0 left arrow 1 fine-structure transition in atomic sulfur (S I) in its ground (3)P state has been detected in the laboratory by far-infrared laser magnetic resonance. The fine-structure interval has been measured accurately as 5,322,492.9 +/- 2.8 MHz which corresponds to a wavelength of 56.325572 +/- 0.000030 micrometers.

  5. Identification of main-sequence stars with mid-infrared excesses: Frequency of beta Pictoris analogs and transition disk systems

    NASA Astrophysics Data System (ADS)

    Uzpen, Brian Robert

    spectroscopy is obtained for a large subset of the mid-IR excess sources for the purpose of stellar and circumstellar characterization. Finally, a statistical analysis of a complete stellar sample is investigated to determine that the frequency of dusty mid-IR debris disks is 0.3±0.3% and transition disks is 1.2±0.6%. The frequencies of these mid-IR excess sources are used to constrain disk lifetimes to 5±2 Myr.

  6. Accurate measurement of time

    NASA Astrophysics Data System (ADS)

    Itano, Wayne M.; Ramsey, Norman F.

    1993-07-01

    The paper discusses current methods for accurate measurements of time by conventional atomic clocks, with particular attention given to the principles of operation of atomic-beam frequency standards, atomic hydrogen masers, and atomic fountain and to the potential use of strings of trapped mercury ions as a time device more stable than conventional atomic clocks. The areas of application of the ultraprecise and ultrastable time-measuring devices that tax the capacity of modern atomic clocks include radio astronomy and tests of relativity. The paper also discusses practical applications of ultraprecise clocks, such as navigation of space vehicles and pinpointing the exact position of ships and other objects on earth using the GPS.

  7. Finite Frequency Traveltime Tomography of Lithospheric and Upper Mantle Structures beneath the Cordillera-Craton Transition in Southwestern Canada

    NASA Astrophysics Data System (ADS)

    Chen, Y.; Gu, Y. J.; Hung, S. H.

    2014-12-01

    Based on finite-frequency theory and cross-correlation teleseismic relative traveltime data from the USArray, Canadian National Seismograph Network (CNSN) and Canadian Rockies and Alberta Network (CRANE), we present a new tomographic model of P-wave velocity perturbations for the lithosphere and upper mantle beneath the Cordillera-cration transition region in southwestern Canada. The inversion procedure properly accounts for the finite-volume sensitivities of measured travel time residuals, and the resulting model shows a greater resolution of upper mantle velocity heterogeneity beneath the study area than earlier approaches based on the classical ray-theoretical approach. Our model reveals a lateral change of P velocities from -0.5% to 0.5% down to ~200-km depth in a 50-km wide zone between the Alberta Basin and the foothills of the Rocky Mountains, which suggests a sharp structural gradient along the Cordillera deformation front. The stable cratonic lithosphere, delineated by positive P-velocity perturbations of 0.5% and greater, extends down to a maximum depth of ~180 km beneath the Archean Loverna Block (LB). In comparison, the mantle beneath the controversial Medicine Hat Block (MHB) exhibits significantly higher velocities in the uppermost mantle and a shallower (130-150 km depth) root, generally consistent with the average depth of the lithosphere-asthenosphere boundary beneath Southwest Western Canada Sedimentary Basin (WCSB). The complex shape of the lithospheric velocities under the MHB may be evidence of extensive erosion or a partial detachment of the Precambrian lithospheric root. Furthermore, distinct high velocity anomalies in LB and MHB, which are separated by 'normal' mantle block beneath the Vulcan structure (VS), suggest different Archean assembly and collision histories between these two tectonic blocks.

  8. Analysis of methods for calculating the transition frequencies of the torsional vibration of acrolein isomers in the ground ( S 0) electronic state

    NASA Astrophysics Data System (ADS)

    Koroleva, L. A.; Tyulin, V. I.; Matveev, V. K.; Pentin, Yu. A.

    2013-05-01

    B3LYP, MP2, CCSD(T), and MP4/MP2 in the 6-311G( d, p), 6-311++G( d, p), cc-pVTZ, aug-cc-pVTZ bases used to calculate the transition frequencies of torsional vibration of trans- and cis-isomers of acrolein in the ground electronic state ( S 0) are analyzed. It is found that for trans-isomers, all methods of calculation except for B3LYP in the cc-pVTZ basis yield good agreement between the calculated and experimental values. It is noted that for the cis-isomer of acrolein, no method of calculation confirms the experimental value of the frequency of torsional vibration (138 cm-1). It is shown that the calculated and experimental values for obertones at 273.0 cm-1 and other transitions of torsional vibration are different for this isomer in particular. However, it is established that in some calculation methods (B3LYP, MP2), the frequency of the torsional vibration of the cis-isomer coincides with another experimental value of this frequency (166.5 cm-1). It is concluded that in analyzing the vibrational structure of the UV spectrum, the calculated and experimental values of its obertone (331.3 cm-1) coincide, along with its frequency. It is also noted that the frequency of torsional vibration for the cis-isomer (166.5 cm-1) can also be found in other experimental works if we change the allocation of torsional transition 18{1/1}.

  9. Comparison of one-particle basis set extrapolation to explicitly correlated methods for the calculation of accurate quartic force fields, vibrational frequencies, and spectroscopic constants: application to H2O, N2H+, NO2+, and C2H2.

    PubMed

    Huang, Xinchuan; Valeev, Edward F; Lee, Timothy J

    2010-12-28

    One-particle basis set extrapolation is compared with one of the new R12 methods for computing highly accurate quartic force fields (QFFs) and spectroscopic data, including molecular structures, rotational constants, and vibrational frequencies for the H(2)O, N(2)H(+), NO(2)(+), and C(2)H(2) molecules. In general, agreement between the spectroscopic data computed from the best R12 and basis set extrapolation methods is very good with the exception of a few parameters for N(2)H(+) where it is concluded that basis set extrapolation is still preferred. The differences for H(2)O and NO(2)(+) are small and it is concluded that the QFFs from both approaches are more or less equivalent in accuracy. For C(2)H(2), however, a known one-particle basis set deficiency for C-C multiple bonds significantly degrades the quality of results obtained from basis set extrapolation and in this case the R12 approach is clearly preferred over one-particle basis set extrapolation. The R12 approach used in the present study was modified in order to obtain high precision electronic energies, which are needed when computing a QFF. We also investigated including core-correlation explicitly in the R12 calculations, but conclude that current approaches are lacking. Hence core-correlation is computed as a correction using conventional methods. Considering the results for all four molecules, it is concluded that R12 methods will soon replace basis set extrapolation approaches for high accuracy electronic structure applications such as computing QFFs and spectroscopic data for comparison to high-resolution laboratory or astronomical observations, provided one uses a robust R12 method as we have done here. The specific R12 method used in the present study, CCSD(T)(R12), incorporated a reformulation of one intermediate matrix in order to attain machine precision in the electronic energies. Final QFFs for N(2)H(+) and NO(2)(+) were computed, including basis set extrapolation, core-correlation, scalar

  10. Sub-MHz accuracy measurement of the S(2) 2-0 transition frequency of D2 by Comb-Assisted Cavity Ring Down spectroscopy

    NASA Astrophysics Data System (ADS)

    Mondelain, D.; Kassi, S.; Sala, T.; Romanini, D.; Gatti, D.; Campargue, A.

    2016-08-01

    The line position of the very weak S(2) transition of deuterium in the 2-0 band has been measured with a Comb-Assisted Cavity Ring Down spectrometer. The high sensitivity spectra were recorded at 5 and 10 mbar with a Noise Equivalent Absorption, αmin, of 8 × 10-11 cm-1. The line positions at 5 and 10 mbar were measured with sub-MHz accuracy (460 and 260 kHz, respectively). After correction of the line pressure-shift, the frequency at zero pressure of the S(2) transition of the first overtone band was determined to be 187 104 299.51 ± 0.50 MHz. This value agrees within 1.7 MHz with the frequency obtained from the best available ab initio calculations and corresponds to only 15% of the claimed theoretical uncertainty.

  11. Accurate quantum chemical calculations

    NASA Technical Reports Server (NTRS)

    Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Taylor, Peter R.

    1989-01-01

    An important goal of quantum chemical calculations is to provide an understanding of chemical bonding and molecular electronic structure. A second goal, the prediction of energy differences to chemical accuracy, has been much harder to attain. First, the computational resources required to achieve such accuracy are very large, and second, it is not straightforward to demonstrate that an apparently accurate result, in terms of agreement with experiment, does not result from a cancellation of errors. Recent advances in electronic structure methodology, coupled with the power of vector supercomputers, have made it possible to solve a number of electronic structure problems exactly using the full configuration interaction (FCI) method within a subspace of the complete Hilbert space. These exact results can be used to benchmark approximate techniques that are applicable to a wider range of chemical and physical problems. The methodology of many-electron quantum chemistry is reviewed. Methods are considered in detail for performing FCI calculations. The application of FCI methods to several three-electron problems in molecular physics are discussed. A number of benchmark applications of FCI wave functions are described. Atomic basis sets and the development of improved methods for handling very large basis sets are discussed: these are then applied to a number of chemical and spectroscopic problems; to transition metals; and to problems involving potential energy surfaces. Although the experiences described give considerable grounds for optimism about the general ability to perform accurate calculations, there are several problems that have proved less tractable, at least with current computer resources, and these and possible solutions are discussed.

  12. Radio frequency-power and the ring-mode to red-mode transition in an inductively coupled plasma

    SciTech Connect

    Coffer, J. G.; Camparo, J. C.

    2012-04-15

    The optical output of an alkali-metal inductively coupled plasma (alkali-ICP) plays an important role in both atomic magnetometers and atomic clocks, producing these devices' atomic signals through optical pumping. Unfortunately, though the alkali-ICP's optical pumping efficiency grows exponentially with temperature, at relatively high temperatures ({approx}140 deg. C) the discharge transitions from ''ring mode'' to ''red mode'', which is a spectral change in the plasma's output that corresponds broadly to a transition from ''good emission'' for optical pumping to ''poor emission.'' Recently, evidence has accumulated pointing to radiation trapping as the mechanism driving the ring-mode to red-mode transition, suggesting that the phenomenon is primarily linked to the alkali vapor's temperature. However, observations of the transition made in the 1960 s, demonstrating that the ICP temperature associated with the transition depended on rf-power, would appear to cast doubt on this mechanism. Here, we carefully investigate the influence of rf-power on the ring-mode to red-mode transition, finding that rf-power only affects the transition through discharge heating. Thus, the present work shows that the primary effect of rf-power on the ring-mode to red-mode transition can be understood in terms of the radiation trapping mechanism.

  13. Radio frequency-power and the ring-mode to red-mode transition in an inductively coupled plasma

    NASA Astrophysics Data System (ADS)

    Coffer, J. G.; Camparo, J. C.

    2012-04-01

    The optical output of an alkali-metal inductively coupled plasma (alkali-ICP) plays an important role in both atomic magnetometers and atomic clocks, producing these devices' atomic signals through optical pumping. Unfortunately, though the alkali-ICP's optical pumping efficiency grows exponentially with temperature, at relatively high temperatures (˜140 °C) the discharge transitions from "ring mode" to "red mode," which is a spectral change in the plasma's output that corresponds broadly to a transition from "good emission" for optical pumping to "poor emission." Recently, evidence has accumulated pointing to radiation trapping as the mechanism driving the ring-mode to red-mode transition, suggesting that the phenomenon is primarily linked to the alkali vapor's temperature. However, observations of the transition made in the 1960 s, demonstrating that the ICP temperature associated with the transition depended on rf-power, would appear to cast doubt on this mechanism. Here, we carefully investigate the influence of rf-power on the ring-mode to red-mode transition, finding that rf-power only affects the transition through discharge heating. Thus, the present work shows that the primary effect of rf-power on the ring-mode to red-mode transition can be understood in terms of the radiation trapping mechanism.

  14. Sampling frequency trade-offs in the assessment of mean transit times of tropical montane catchment waters under semi-steady-state conditions

    NASA Astrophysics Data System (ADS)

    Timbe, E.; Windhorst, D.; Celleri, R.; Timbe, L.; Crespo, P.; Frede, H.-G.; Feyen, J.; Breuer, L.

    2015-03-01

    Precipitation event samples and weekly based water samples from streams and soils were collected in a tropical montane cloud forest catchment for 2 years and analyzed for stable water isotopes in order to understand the effect of sampling frequency in the performance of three lumped-parameter distribution functions (exponential-piston flow, linear-piston flow and gamma) which were used to estimate mean transit times of waters. Precipitation data, used as input function for the models, were aggregated to daily, weekly, bi-weekly, monthly and bi-monthly sampling resolutions, while analyzed frequencies for outflows went from weekly to bi-monthly. By using different scenarios involving diverse sampling frequencies, this study reveals that the effect of lowering the sampling frequency depends on the water type. For soil waters, with transit times on the order of few weeks, there was a clear trend of over predictions. In contrast, the trend for stream waters, which have a more damped isotopic signal and mean transit times on the order of 2 to 4 years, was less clear and showed a dependence on the type of model used. The trade-off to coarse data resolutions could potentially lead to misleading conclusions on how water actually moves through the catchment, notwithstanding that these predictions could reach better fitting efficiencies, fewer uncertainties, errors and biases. For both water types an optimal sampling frequency seems to be 1 or at most 2 weeks. The results of our analyses provide information for the planning of future fieldwork in similar Andean or other catchments.

  15. Behavior of the low-frequency conductivity of silver iodide nanocomposites in the superionic phase transition region

    NASA Astrophysics Data System (ADS)

    Vergent'ev, T. Yu.; Koroleva, E. Yu.; Kurdyukov, D. A.; Naberezhnov, A. A.; Filimonov, A. V.

    2013-01-01

    The behavior of the specific conductivity of composites based on silver iodide embedded in porous glasses with an average pore diameter of 7 ± 1 nm and in artificial opals with a pore diameter of 40-100 nm has been investigated in the temperature range from 300 to 500 K. It has been shown that a decrease in the characteristic pore size does not lead to a change in the order of the phase transition and that the temperature of the transition to the superionic state of silver iodide in a porous glass and in an opal upon heating is close to the phase transition temperature T c in the bulk material (˜420 K). Upon cooling, the phase transition temperature T c significantly decreases, and the phase transition becomes diffuse. With a decrease in the pore size, the region of the temperature hysteresis of the phase transition increases. The dc conductivities of the composites have been estimated from the impedance diagrams. The temperature dependence of the dc conductivity of both composites has a thermally activated nature, and the slope of the curve σ(1/ T) changes near the phase transition, which indicates a change in the activation energy. The activation energies in the low-temperature and high-temperature phases have been estimated at ˜450-470 and ˜100 meV, respectively. The equivalent electrical circuit describing the charge transfer processes in the studied samples has been proposed.

  16. Observation and Absolute Frequency Measurements of the {sup 1}S{sub 0}-{sup 3}P{sub 0} Optical Clock Transition in Neutral Ytterbium

    SciTech Connect

    Hoyt, C.W.; Barber, Z.W.; Oates, C.W.; Fortier, T.M.; Diddams, S.A.; Hollberg, L.

    2005-08-19

    We report the direct excitation of the highly forbidden (6s{sup 2}){sup 1}S{sub 0}{r_reversible}(6s6p){sup 3}P{sub 0} optical transition in two odd isotopes of neutral ytterbium. As the excitation laser frequency is scanned, absorption is detected by monitoring the depletion from an atomic cloud at {approx}70 {mu}K in a magneto-optical trap. The measured frequency in {sup 171}Yb (F=1/2) is 518 295 836 591.6{+-}4.4 kHz. The measured frequency in {sup 173}Yb (F=5/2) is 518 294 576 847.6{+-}4.4 kHz. Measurements are made with a femtosecond-laser frequency comb calibrated by the National Institute of Standards and Technology cesium fountain clock and represent nearly a 10{sup 6}-fold reduction in uncertainty. The natural linewidth of these J=0 to J=0 transitions is calculated to be {approx}10 mHz, making them well suited to support a new generation of optical atomic clocks based on confinement in an optical lattice.

  17. Theoretical studies for the N{sub 2}–N{sub 2}O van der Waals complex: The potential energy surface, intermolecular vibrations, and rotational transition frequencies

    SciTech Connect

    Zheng, Rui; Zheng, Limin; Yang, Minghui E-mail: yangmh@wipm.ac.cn; Lu, Yunpeng E-mail: yangmh@wipm.ac.cn

    2015-10-21

    Theoretical studies of the potential energy surface (PES) and bound states are performed for the N{sub 2}–N{sub 2}O van der Waals (vdW) complex. A four-dimensional intermolecular PES is constructed at the level of single and double excitation coupled-cluster method with a non-iterative perturbation treatment of triple excitations [CCSD(T)] with aug-cc-pVTZ basis set supplemented with bond functions. Two equivalent T-shaped global minima are located, in which the O atom of N{sub 2}O monomer is near the N{sub 2} monomer. The intermolecular fundamental vibrational states are assigned by inspecting the orientation of the nodal surface of the wavefunctions. The calculated frequency for intermolecular disrotation mode is 23.086 cm{sup −1}, which is in good agreement with the available experimental data of 22.334 cm{sup −1}. A negligible tunneling splitting with the value of 4.2 MHz is determined for the ground vibrational state and the tunneling splitting increases as the increment of the vibrational frequencies. Rotational levels and transition frequencies are calculated for both isotopomers {sup 14}N{sub 2}–N{sub 2}O and {sup 15}N{sub 2}–N{sub 2}O. The accuracy of the PES is validated by the good agreement between theoretical and experimental results for the transition frequencies and spectroscopic parameters.

  18. Theoretical studies for the N2-N2O van der Waals complex: The potential energy surface, intermolecular vibrations, and rotational transition frequencies.

    PubMed

    Zheng, Rui; Zheng, Limin; Lu, Yunpeng; Yang, Minghui

    2015-10-21

    Theoretical studies of the potential energy surface (PES) and bound states are performed for the N2-N2O van der Waals (vdW) complex. A four-dimensional intermolecular PES is constructed at the level of single and double excitation coupled-cluster method with a non-iterative perturbation treatment of triple excitations [CCSD(T)] with aug-cc-pVTZ basis set supplemented with bond functions. Two equivalent T-shaped global minima are located, in which the O atom of N2O monomer is near the N2 monomer. The intermolecular fundamental vibrational states are assigned by inspecting the orientation of the nodal surface of the wavefunctions. The calculated frequency for intermolecular disrotation mode is 23.086 cm(-1), which is in good agreement with the available experimental data of 22.334 cm(-1). A negligible tunneling splitting with the value of 4.2 MHz is determined for the ground vibrational state and the tunneling splitting increases as the increment of the vibrational frequencies. Rotational levels and transition frequencies are calculated for both isotopomers (14)N2-N2O and (15)N2-N2O. The accuracy of the PES is validated by the good agreement between theoretical and experimental results for the transition frequencies and spectroscopic parameters. PMID:26493904

  19. Vibrational frequency shifts of fluid nitrogen fundamental and hot band transitions as a function of pressure and temperature

    SciTech Connect

    Schmidt, S.C.; Schiferl, D.; Zinn, A.S.; Ragan, D.D.; Moore, D.S.

    1989-01-01

    Coherent anti-Stokes Raman scattering (CARS) and spontaneous Raman spectroscopy have been used to obtain vibrational spectra of shock-compressed and static high-pressure fluid nitrogen, respectively. Vibrational frequencies were obtained from the CARS data using a semiclassical model for these spectra. Spontaneous Raman vibrational frequencies were determined by fitting data using a Lorentz shape line. A functional form was found for the dependence of the vibrational frequency on pressure and temperature to 40 GPa and 5000 K, respectively. The result is compared to a recent theoretical model. 6 refs., 2 figs., 1 tab.

  20. First Laboratory Measurement of the J = 1 - 0 Transitions of 36ArH+ and38ArH+: New, Improved Rest Frequencies for Astronomical Searches

    NASA Astrophysics Data System (ADS)

    Bizzocchi, Luca; Dore, Luca; Degli Esposti, Claudio; Tamassia, Filippo

    2016-04-01

    The recent detections of {}36{{ArH}}+ and {}38{{ArH}}+ in the interstellar medium have triggered interest in argonium. This molecular cation has proved to be widespread in our galaxy in the diffuse medium and may serve as a very specific tracer of atomic gas and as a proxy for the cosmic-ray ionization rate. Pure rotational transitions of the two isotopologues detected in the ISM have never been recorded in the laboratory until this work. Here, we report on the first detection of the J=1≤ftarrow 0 transition of both {}36{{ArH}}+ and {}38{{ArH}}+ produced in a low-pressure glow discharge. All of the rotational and ro-vibrational transition frequencies available have been analyzed in global multi-isotopologues fit to give a comprehensive set of isotopic independent spectroscopic parameters. These data allow us to compute an improved set of rotational and ro-vibrational rest frequencies to assist astronomical searches of {}{{ArH}}+.

  1. Frequency Ratio of Two Optical Clock Transitions in Yb+ 171 and Constraints on the Time Variation of Fundamental Constants

    NASA Astrophysics Data System (ADS)

    Godun, R. M.; Nisbet-Jones, P. B. R.; Jones, J. M.; King, S. A.; Johnson, L. A. M.; Margolis, H. S.; Szymaniec, K.; Lea, S. N.; Bongs, K.; Gill, P.

    2014-11-01

    Singly ionized ytterbium, with ultranarrow optical clock transitions at 467 and 436 nm, is a convenient system for the realization of optical atomic clocks and tests of present-day variation of fundamental constants. We present the first direct measurement of the frequency ratio of these two clock transitions, without reference to a cesium primary standard, and using the same single ion of Yb+ 171 . The absolute frequencies of both transitions are also presented, each with a relative standard uncertainty of 6 ×1 0-16. Combining our results with those from other experiments, we report a threefold improvement in the constraint on the time variation of the proton-to-electron mass ratio, μ ˙ /μ =0.2 (1.1 )×1 0-16 yr-1 , along with an improved constraint on time variation of the fine structure constant, α ˙ /α =-0.7 (2.1 )×1 0-17 yr-1 .

  2. The discharge mode transition and O({sup 5}p{sub 1}) production mechanism of pulsed radio frequency capacitively coupled plasma

    SciTech Connect

    Liu, X. Y.; Hu, J. T.; Liu, J. H.; Xiong, Z. L.; Liu, D. W.; Lu, X. P.; Shi, J. J.

    2012-07-23

    The discharge mode transition from uniform plasma across the gas gap to the {alpha} mode happens at the rising phase of the pulsed radio frequency capacitively coupled plasma (PRF CCP). This transition is attributed to the fast increasing stochastic heating at the edge of sheath. In the second stage with the stable current and voltage amplitude, the consistency between experimental and numerical spatial-temporal 777 nm emission profile suggests that He* and He{sub 2}* dominate the production of O({sup 5}p{sub 1}) through dissociation and excitation of O{sub 2}. Finally, the sterilization efficiency of PRF CCP is found to be higher than that of plasma jet.

  3. Predicting stability and change in frequency of intoxication from the college years to beyond: individual-difference and role transition variables.

    PubMed

    Gotham, H J; Sher, K J; Wood, P K

    1997-11-01

    The authors examined whether individual-difference variables (e.g., family history of alcoholism, sex, personality traits, positive alcohol expectancies) and role transition-related variables (full-time work status, marital status, parenthood) moderate the "maturing-out" process whereby young adults who drink heavily during college decrease their drinking in the following years. Analyses were based on 288 young adults, assessed as full-time students (mostly college seniors, Year 4 of a larger study) and 3 years later (Year 7) when all had earned bachelor's degrees, and the analyses showed that frequency of intoxication (per week) decreased significantly (p < .0001). Entering the workforce full time, being male, and being less open to experience were associated with decreased postcollege drinking. Furthermore, relatively extraverted individuals were more likely to continue a pattern of frequent intoxication from Year 4 to year 7. The findings stress the importance of studying how individual-difference variables predict behavior across role transitions. PMID:9358692

  4. Sampling frequency trade-offs in the assessment of mean transit times of tropical montane catchment waters under semi-steady-state conditions

    NASA Astrophysics Data System (ADS)

    Timbe, E.; Windhorst, D.; Celleri, R.; Timbe, L.; Crespo, P.; Frede, H.-G.; Feyen, J.; Breuer, L.

    2014-11-01

    Stream and soil waters were collected on a weekly basis in a tropical montane cloud forest catchment for two years and analyzed for stable water isotopes in order to infer transit time distribution functions and to define the mean transit times. Depending on the water type (stream or soil water), lumped distribution functions such as Exponential-Piston flow, Linear-Piston flow and Gamma models using temporal isotopic variations of precipitation event samples as input, were fitted. Samples were aggregated to daily, weekly, biweekly, monthly and bimonthly time scales in order to check the sensitivity of temporal sampling on model predictions. The study reveals that the effect of decreasing sampling frequency depends on the water type. For soil waters with transit times in the order of weeks to months, there was a clear trend of over prediction. In contrast, the trend of prediction for stream waters, with a dampened isotopic signal and mean transit times in the order of 2 to 4 years, was less clear and depending on the type of model used. The trade-off to coarse data resolutions could potentially lead to misleading conclusions on how water actually moves through the catchment, while at the same time predictions can reach better fitting efficiencies, lesser uncertainties, errors and biases. For both water types an optimal sampling frequency seems to be one or at most two weeks. The results of our analyses provide information for the planning (in particular in terms of cost-benefit and time requirements) of future fieldwork in similar Andean or other catchments.

  5. Progress Report on a Portable TI:SAPPHIRE Comb Laser with Frequencies Referring to Cesium Atom Two-Photon Transitions

    NASA Astrophysics Data System (ADS)

    Cheng, Wang-Yau; Wu, Chien-Ming; Liu, Tz-Wei; Chen, Yo-Huan

    2010-06-01

    A portable Ti:sapphire comb laser would contribute significantly to generalize comb-laser applications, such as the astro-comb missions or other interdisciplinary collaborations. To develop a portable comb laser, three barriers lie ahead: one is to miniaturize and robotize the frequency reference system of the comb laser; the second is to ensure the long-term frequency accuracy without satellite connection, and the third is to miniaturize the pumping laser system. We developed two hand-size cesium-stabilized diode lasers at 822 nm and 884 nm to serve as frequency references for a comb laser and we carried out a comb-laser-based CPT experiment with one single cesium cell that might offer a locking procedure for long-term comb laser accuracy. We will also report our plans and progress on a fiber laser pumped Ti:sapphire comb laser.

  6. Spectral Index and Quasi-Periodic Oscillation Frequency Correlation in Black Hole (BH) Sources: Observational Evidence of Two Phases and Phase Transition in BHs

    NASA Technical Reports Server (NTRS)

    Titarchuk, Lev; Fiorito, Ralph

    2004-01-01

    Recent studies have shown that strong correlations are observed between the low frequencies (1-10 Hz) of quasiperiodic oscillations (QPOs) and the spectral power law index of several Black Hole (BH) candidate sources, in low hard states, steep power-law (soft) states and in transition between these states. The observations indicate that the X-ray spectrum of such state (phases) show the presence of a power-law component and are sometimes related to simultaneous radio emission indicated the probable presence of a jet. Strong QPOs (less than 20% rms) are present in the power density spectrum in the spectral range where the power-law component is dominant ( i.e. 60-90% ). This evidence contradicts the dominant long standing interpretation of QPOs as a signature of the thermal accretion disk. We present the data from the literature and our own data to illustrate the dominance of power-law index-QPO frequency correlations. We provide a model, that identifies and explains the origin of the QPOs and how they are imprinted on the properties of power-law flux component. We argue the existence of a bounded compact coronal region which is a natural consequence of the adjustment of Keplerian disk flow to the innermost sub-Keplerian boundary conditions near the central object and that ultimately leads to the formation of a transition layer (TL) between the adjustment radius and the innermost boundary. The model predicts two phases or states dictated by the photon upscattering produced in the TL: (1) hard state, in which the TL is optically thin and very hot (kT approx. greater than 50 keV) producing photon upscattering via thermal Componization; the photon spectrum index Gamma appprox.1.5 for this state is dictated by gravitational energy release and Compton cooling in an optically thin shock near the adjustment radius; (2) a soft state which is optically thick and relatively cold (approx. less than 5 keV); the index for this state, Gamma approx. 2.8 is determined by soft

  7. Changes in LH pulse frequency and amplitude in intact mares during the transition into the breeding season.

    PubMed

    Fitzgerald, B P; Affleck, K J; Barrows, S P; Murdoch, W L; Barker, K B; Loy, R G

    1987-03-01

    Two groups of mares were exposed to an abrupt, artificial increase or a natural increase in daylength. In both groups, mean LH pulse frequency increased with time of year and was accompanied by a reciprocal decrease in LH pulse amplitude. A non-pulsatile pattern of LH secretion was observed in some mares sampled close to the day of ovulation. Maximum mean LH pulse frequency and the onset of the breeding season occurred earlier in those mares exposed to an abrupt artificial increase in daylength. In blood samples collected frequently, mean serum LH concentrations increased in relation to time of year. However, during 60 days before ovulation, when LH pulse frequency increased, mean daily serum LH values only increased on Day -3 before ovulation. The magnitude of the periovulatory LH rise was greater before the second than the first ovulation of the breeding season. These results support the hypothesis that, in the mare, a photoperiod-induced seasonal alteration in LH pulse frequency and/or amplitude may play a role in the onset of the breeding season. PMID:3572880

  8. Experimentally constrained CA1 fast-firing parvalbumin-positive interneuron network models exhibit sharp transitions into coherent high frequency rhythms

    PubMed Central

    Ferguson, Katie A.; Huh, Carey Y. L.; Amilhon, Bénédicte; Williams, Sylvain; Skinner, Frances K.

    2013-01-01

    The coupling of high frequency oscillations (HFOs; >100 Hz) and theta oscillations (3–12 Hz) in the CA1 region of rats increases during REM sleep, indicating that it may play a role in memory processing. However, it is unclear whether the CA1 region itself is capable of providing major contributions to the generation of HFOs, or if they are strictly driven through input projections. Parvalbumin-positive (PV+) interneurons may play an essential role in these oscillations due to their extensive connections with neighboring pyramidal cells, and their characteristic fast-spiking. Thus, we created mathematical network models to investigate the conditions under which networks of CA1 fast-spiking PV+ interneurons are capable of producing high frequency population rhythms. We used whole-cell patch clamp recordings of fast-spiking, PV+ cells in the CA1 region of an intact hippocampal preparation in vitro to derive cellular properties, from which we constrained an Izhikevich-type model. Novel, biologically constrained network models were constructed with these individual cell models, and we investigated networks across a range of experimentally determined excitatory inputs and inhibitory synaptic strengths. For each network, we determined network frequency and coherence. Network simulations produce coherent firing at high frequencies (>90 Hz) for parameter ranges in which PV-PV inhibitory synaptic conductances are necessarily small and external excitatory inputs are relatively large. Interestingly, our networks produce sharp transitions between random and coherent firing, and this sharpness is lost when connectivity is increased beyond biological estimates. Our work suggests that CA1 networks may be designed with mechanisms for quickly gating in and out of high frequency coherent population rhythms, which may be essential in the generation of nested theta/high frequency rhythms. PMID:24155715

  9. Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects.

    PubMed

    O'Brien, Maria; McEvoy, Niall; Hanlon, Damien; Hallam, Toby; Coleman, Jonathan N; Duesberg, Georg S

    2016-01-01

    Layered inorganic materials, such as the transition metal dichalcogenides (TMDs), have attracted much attention due to their exceptional electronic and optical properties. Reliable synthesis and characterization of these materials must be developed if these properties are to be exploited. Herein, we present low-frequency Raman analysis of MoS2, MoSe2, WSe2 and WS2 grown by chemical vapour deposition (CVD). Raman spectra are acquired over large areas allowing changes in the position and intensity of the shear and layer-breathing modes to be visualized in maps. This allows detailed characterization of mono- and few-layered TMDs which is complementary to well-established (high-frequency) Raman and photoluminescence spectroscopy. This study presents a major stepping stone in fundamental understanding of layered materials as mapping the low-frequency modes allows the quality, symmetry, stacking configuration and layer number of 2D materials to be probed over large areas. In addition, we report on anomalous resonance effects in the low-frequency region of the WS2 Raman spectrum. PMID:26766208

  10. Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects

    NASA Astrophysics Data System (ADS)

    O'Brien, Maria; McEvoy, Niall; Hanlon, Damien; Hallam, Toby; Coleman, Jonathan N.; Duesberg, Georg S.

    2016-01-01

    Layered inorganic materials, such as the transition metal dichalcogenides (TMDs), have attracted much attention due to their exceptional electronic and optical properties. Reliable synthesis and characterization of these materials must be developed if these properties are to be exploited. Herein, we present low-frequency Raman analysis of MoS2, MoSe2, WSe2 and WS2 grown by chemical vapour deposition (CVD). Raman spectra are acquired over large areas allowing changes in the position and intensity of the shear and layer-breathing modes to be visualized in maps. This allows detailed characterization of mono- and few-layered TMDs which is complementary to well-established (high-frequency) Raman and photoluminescence spectroscopy. This study presents a major stepping stone in fundamental understanding of layered materials as mapping the low-frequency modes allows the quality, symmetry, stacking configuration and layer number of 2D materials to be probed over large areas. In addition, we report on anomalous resonance effects in the low-frequency region of the WS2 Raman spectrum.

  11. Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects

    PubMed Central

    O’Brien, Maria; McEvoy, Niall; Hanlon, Damien; Hallam, Toby; Coleman, Jonathan N.; Duesberg, Georg S.

    2016-01-01

    Layered inorganic materials, such as the transition metal dichalcogenides (TMDs), have attracted much attention due to their exceptional electronic and optical properties. Reliable synthesis and characterization of these materials must be developed if these properties are to be exploited. Herein, we present low-frequency Raman analysis of MoS2, MoSe2, WSe2 and WS2 grown by chemical vapour deposition (CVD). Raman spectra are acquired over large areas allowing changes in the position and intensity of the shear and layer-breathing modes to be visualized in maps. This allows detailed characterization of mono- and few-layered TMDs which is complementary to well-established (high-frequency) Raman and photoluminescence spectroscopy. This study presents a major stepping stone in fundamental understanding of layered materials as mapping the low-frequency modes allows the quality, symmetry, stacking configuration and layer number of 2D materials to be probed over large areas. In addition, we report on anomalous resonance effects in the low-frequency region of the WS2 Raman spectrum. PMID:26766208

  12. Comparison of resonance frequencies of major atomic lines in 398-423 nm

    NASA Astrophysics Data System (ADS)

    Enomoto, Katsunari; Hizawa, Nagisa; Suzuki, Takahiro; Kobayashi, Kaori; Moriwaki, Yoshiki

    2016-05-01

    We have demonstrated spectroscopy of Ca, Rb, In, K, Ga, and Yb atomic lines in 398-423 nm. Using an etalon of an ultralow-expansion coefficient, we have determined ratios of the resonance frequencies of these atoms. The etalon has small group-delay-dispersion mirrors to be an accurate frequency reference over a wavelength span of a few tens of nanometer. The etalon resonance frequencies are calibrated with accurately known transition frequencies of Ca at 423 nm and Rb at 422 nm. Based on this calibration, the absolute frequencies are also determined for some atomic lines with smaller uncertainties than earlier reports.

  13. Study on the mode-transition of nanosecond-pulsed dielectric barrier discharge between uniform and filamentary by controlling pressures and pulse repetition frequencies

    NASA Astrophysics Data System (ADS)

    Yu, S.; Pei, X.; Hasnain, Q.; Nie, L.; Lu, X.

    2016-02-01

    In this paper, we investigate the temporally resolved evolution of the nanosecond pulsed dielectric barrier discharge (DBD) in a moderate 6 mm discharge gap under various pressures and pulse repetition frequencies (PRFs) by intensified charge-coupled device (ICCD) images, using dry air and its components oxygen and nitrogen. It is found that the pressures are very different when the mode transits between uniform and filamentary in air, oxygen, and nitrogen. The PRFs can also obviously affect the mode-transition. The transition mechanism in the pulsed DBD is not Townsend-to-Streamer, which is dominant in the traditional alternating-voltage DBD. The pulsed DBD in a uniform mode develops in the form of plane ionization wave due to overlap of primary avalanches, while the increase in pressure disturbs the overlap and discharge develops in streamer, corresponding to the filamentary mode. Increasing the initial electron density by pre-ionization may contribute to discharge uniformity at higher pressures. We also found that the dependence of homogeneity upon PRF is a non-monotonic one.

  14. Radio-frequency measurements of coherent transition and Cherenkov radiation: Implications for high-energy neutrino detection

    SciTech Connect

    Gorham, Peter W.; Saltzberg, David P.; Schoessow, Paul; Gai, Wei; Power, John G.; Konecny, Richard; Conde, M. E.

    2000-12-01

    We report on measurements of (11--18)-cm wavelength radio emission from interactions of 15.2 MeV pulsed electron bunches at the Argonne Wakefield Accelerator. The electrons were observed both in a configuration where they produced primarily transition radiation from an aluminum foil, and in a configuration designed for the electrons to produce Cherenkov radiation in a silica sand target. Our aim was to emulate the large electron excess expected to develop during an electromagnetic cascade initiated by an ultrahigh-energy particle. Such charge asymmetries are predicted to produce strong coherent radio pulses, which are the basis for several experiments to detect high-energy neutrinos from the showers they induce in Antarctic ice and in the lunar regolith. We detected coherent emission which we attribute both to transition and possibly Cherenkov radiation at different levels depending on the experimental conditions. We discuss implications for experiments relying on radio emission for detection of electromagnetic cascades produced by ultrahigh-energy neutrinos.

  15. Radio-frequency measurements of coherent transition and cherenkov radiation: implications for high-energy neutrino detection

    PubMed

    Gorham; Saltzberg; Schoessow; Gai; Power; Konecny; Conde

    2000-12-01

    We report on measurements of (11-18)-cm wavelength radio emission from interactions of 15.2 MeV pulsed electron bunches at the Argonne Wakefield Accelerator. The electrons were observed both in a configuration where they produced primarily transition radiation from an aluminum foil, and in a configuration designed for the electrons to produce Cherenkov radiation in a silica sand target. Our aim was to emulate the large electron excess expected to develop during an electromagnetic cascade initiated by an ultrahigh-energy particle. Such charge asymmetries are predicted to produce strong coherent radio pulses, which are the basis for several experiments to detect high-energy neutrinos from the showers they induce in Antarctic ice and in the lunar regolith. We detected coherent emission which we attribute both to transition and possibly Cherenkov radiation at different levels depending on the experimental conditions. We discuss implications for experiments relying on radio emission for detection of electromagnetic cascades produced by ultrahigh-energy neutrinos. PMID:11138159

  16. Temperature-modulated calorimetry of the frequency dependence of the glass transition of poly(ethylene terephthalate) and ....

    SciTech Connect

    Wunderlich, B.; Okazaki, I.

    1997-03-01

    Temperature-modulated differential scanning calorimetry, TMDSC, is new technique that permits to measure the apparent heat capacity vs modulation frequency. The method is briefly described and a quasi- isothermal measurement method is used to derive the kinetic parameters for PET and PS. A first-order kinetics expression was used to describe the approach to equilibrium and point out the limits caused by asymmetry and cooperativity of the kinetics. Use of a complex description of heat capacity and entropy is discussed. Activation energies vary from 75 to 350 kJ/mol, dependent on thermal pretreatment and the preexponential factor is correlated with the activation energy.

  17. Quadrature frequency resolved spectroscopy (QFRS) of radiative transitions of Er3+ and Nd3+ ions in chalcogenide glasses (ChGs)

    NASA Astrophysics Data System (ADS)

    Aoki, T.; Saitou, D.; Fujimoto, K.; Fujihashi, C.; Shimakawa, K.; Koughia, K.; Kasap, S. O.

    2010-11-01

    Wideband quadrature frequency resolved spectroscopy (QFRS) of photoluminescence (PL) lifetime distributions from 2 ns to 160 s is shown to be very effective in elucidating the characteristic features of radiative transitions of Er3+ ions in GeGaSe and GeGaS chalcogenides glasses (ChGs). Undoped GeGaSe ChGs show triple-peak lifetime distributions of which two short-lifetimes are associated with singlet-triplet excitons and longest-lifetime, ~20 s, with radiative tunnelling (RT) of distant-pairs (DPs). Er-doped GeGaSe and GeGaS ChGs exhibit a double-peak lifetime distribution, consisting of a peak at ~3.3 and ~5.3 ms, respectively, a characteristic of the Er3+ luminescence centre and another peak at ~20 s, similar to that of undoped GeGaSe ChGs. It is shown that the QFRS can separate and analyse two mixed radiative transitions of Nd3+ ions, 4F3/2V4I15/2 and 4F5/2,2H9/2V4I15/2 in GaLaS ChGs. From the QFRS results we can experimentally extract the branching ratio βJ and lifetime τ approx 77 (μs for 4 lasing transitions 4F3/2→4IJ(J = 9/2, 11/2, 13/2, 15/2) of Nd3+ ions in GaLaS ChGs, in particular, the weakest transition 4F3/2→4I15/2.

  18. Frequency discriminating laser

    SciTech Connect

    Thomas, M.D.

    1987-10-20

    A laser is described for discriminating between a higher gain transition and a lower gain transition to permit the laser to lase at the lower gain transition. It consists of: a laser cavity, including more than two mirrors each of which is highly transmissive at the frequency of the higher gain transition, one of which is partially reflective at the frequency of the lower gain transition, and all but the one of which are highly reflective at the frequency of the lower gain transition; an active laser medium disposed within the cavity; and means for pumping the active laser medium.

  19. Five-year tracking of Plasmodium falciparum allele frequencies in a holoendemic area with indistinct seasonal transitions

    PubMed Central

    Akala, Hoseah M; Achieng, Angela O; Eyase, Fredrick L; Juma, Dennis W; Ingasia, Luiser; Cheruiyot, Agnes C; Okello, Charles; Omariba, Duke; Owiti, Eunice A; Muriuki, Catherine; Yeda, Redemptah; Andagalu, Ben; Johnson, Jacob D; Kamau, Edwin

    2014-01-01

    Background The renewed malaria eradication efforts require an understanding of the seasonal patterns of frequency of polymorphic variants in order to focus limited funds productively. Although cross-sectional studies in holoendemic areas spanning a single year could be useful in describing parasite genotype status at a given point, such information is inadequate in describing temporal trends in genotype polymorphisms. For Plasmodium falciparum isolates from Kisumu District Hospital, Plasmodium falciparum chloroquine-resistance transporter gene (Pfcrt-K76T) and P. falciparum multidrug resistance gene 1 (PfMDR1-N86Y), were analyzed for polymorphisms and parasitemia changes in the 53 months from March 2008 to August 2012. Observations were compared with prevailing climatic factors, including humidity, rainfall, and temperature. Methods Parasitemia (the percentage of infected red blood cells per total red blood cells) was established by microscopy for P. falciparum malaria-positive samples. P. falciparum DNA was extracted from whole blood using a Qiagen DNA Blood Mini Kit. Single nucleotide polymorphism identification at positions Pfcrt-K76T and PfMDR1-N86Y was performed using real-time polymerase chain reaction and/or sequencing. Data on climatic variables were obtained from http://www.tutiempo.net/en/. Results A total of 895 field isolates from 2008 (n=169), 2009 (n=161), 2010 (n=216), 2011 (n=223), and 2012 (n=126) showed large variations in monthly frequency of PfMDR1-N86Y and Pfcrt-K76T as the mutant genotypes decreased from 68.4%±15% and 38.1%±13% to 29.8%±18% and 13.3%±9%, respectively. The mean percentage of parasitemia was 2.61%±1.01% (coefficient of variation 115.86%; n=895). There was no correlation between genotype or parasitemia and climatic factors. Conclusion This study shows variability in the frequency of Pfcrt-K76T and PfMDR1-N86Y polymorphisms during the study period, bringing into focus the role of cross-sectional studies in describing temporal

  20. Absolute frequency of an atomic hydrogen maser clock

    NASA Technical Reports Server (NTRS)

    Peters, H. E.; Hall, R. G.; Percival, D. B.

    1972-01-01

    An accurate determination was made of the unperturbed atomic hydrogen ground state hyperfine transition frequency (F=1,m=0 - F=0,m=0) in reference to present world wide realizations of internationally defined time interval. In relation to the international atomic time system, the composite value is 1,420,405,751.7755 plus or minus 0.0031 HZ.

  1. Definition of Shifts of Optical Transitions Frequencies due to Pulse Perturbation Action by the Photon Echo Signal Form

    NASA Astrophysics Data System (ADS)

    Lisin, V. N.; Shegeda, A. M.; Samartsev, V. V.

    2015-09-01

    A relative phase shift between the different groups of excited dipoles, which appears as result of its frequency splitting due to action of a pulse of electric or magnetic fields, depends on a time, if the pulse overlaps in time with echo-pulse. As а consequence, the echo waveform is changed. The echo time form is modulated. The inverse modulation period well enough approximates Zeeman and pseudo-Stark splitting in the cases of magnetic and, therefore, electrical fields. Thus the g-factors of ground 4I15/2 and excited 4F9/2 optical states of Er3+ ion in LuLiF4 and YLiF4 have been measured and pseudo-Stark shift of R1 line in ruby has been determined.

  2. SPECTROSCOPIC CONSTANTS AND VIBRATIONAL FREQUENCIES FOR l-C{sub 3}H{sup +} AND ISOTOPOLOGUES FROM HIGHLY ACCURATE QUARTIC FORCE FIELDS: THE DETECTION OF l-C{sub 3}H{sup +} IN THE HORSEHEAD NEBULA PDR QUESTIONED

    SciTech Connect

    Huang Xinchuan; Fortenberry, Ryan C.; Lee, Timothy J.

    2013-05-10

    Very recently, molecular rotational transitions observed in the photon-dominated region of the Horsehead nebula have been attributed to l-C{sub 3}H{sup +}. In an effort to corroborate this finding, we employed state-of-the-art and proven high-accuracy quantum chemical techniques to compute spectroscopic constants for this cation and its isotopologues. Even though the B rotational constant from the fit of the observed spectrum and our computations agree to within 20 MHz, a typical level of accuracy, the D rotational constant differs by more than 40%, while the H rotational constant differs by three orders of magnitude. With the likely errors in the rotational transition energies resulting from this difference in D on the order of 1 MHz for the lowest observed transition (J = 4 {yields} 3) and growing as J increases, the assignment of the observed rotational lines from the Horsehead nebula to l-C{sub 3}H{sup +} is questionable.

  3. Spectroscopic Constants and Vibrational Frequencies for l-C3H+ and Isotopologues from Highly Accurate Quartic Force Fields: The Detection of l-C3H+ in the Horsehead Nebula PDR Questioned

    NASA Astrophysics Data System (ADS)

    Huang, Xinchuan; Fortenberry, Ryan C.; Lee, Timothy J.

    2013-05-01

    Very recently, molecular rotational transitions observed in the photon-dominated region of the Horsehead nebula have been attributed to l-C3H+. In an effort to corroborate this finding, we employed state-of-the-art and proven high-accuracy quantum chemical techniques to compute spectroscopic constants for this cation and its isotopologues. Even though the B rotational constant from the fit of the observed spectrum and our computations agree to within 20 MHz, a typical level of accuracy, the D rotational constant differs by more than 40%, while the H rotational constant differs by three orders of magnitude. With the likely errors in the rotational transition energies resulting from this difference in D on the order of 1 MHz for the lowest observed transition (J = 4 → 3) and growing as J increases, the assignment of the observed rotational lines from the Horsehead nebula to l-C3H+ is questionable.

  4. Spectroscopic Constants and Vibrational Frequencies for l-C3H+ and Isotopologues from Highly-Accurate Quartic Force Fields: The Detection of l-C3H+ in the Horsehead Nebula PDR Questioned

    NASA Technical Reports Server (NTRS)

    Huang, Xinchuan; Fortenberry, Ryan Clifton; Lee, Timothy J.

    2013-01-01

    Very recently, molecular rotational transitions observed in the photon-dominated region of the Horsehead nebula have been attributed to l-C3H+. In an effort to corroborate this finding, we employed state-of-the art and proven high-accuracy quantum chemical techniques to compute spectroscopic constants for this cation and its isotopologues. Even though the B rotational constant from the fit of the observed spectrum and our computations agree to within 20 MHz, a typical level of accuracy, the D rotational constant differs by more than 40%, while the H rotational constant differs by three orders of magnitude. With the likely errors in the rotational transition energies resulting from this difference in D on the order of 1 MHz for the lowest observed transition (J = 4 yields 3) and growing as J increases, the assignment of the observed rotational lines from the Horsehead nebula to l-C3H+ is questionable.

  5. From amorphous to microcrystalline: Phase transition in rapid synthesis of hydrogenated silicon thin film in low frequency inductively coupled plasmas

    SciTech Connect

    Xiao, S. Q.; Xu, S.; Wei, D. Y.; Huang, S. Y.; Zhou, H. P.; Xu, Y.

    2010-12-01

    Hydrogenated silicon (Si:H) thin films were fabricated on glass substrates by low frequency inductively coupled plasma-assisted chemical vapor deposition using a silane precursor with low hydrogen dilution at room temperature. The crystallinity and microstructure properties of the Si:H thin films deposited at different inductive radio-frequency (rf) power density were systematically studied by Raman spectroscopy, x-ray diffraction, and scanning electron microscopy. We found that at a low rf power density of 16.7 to 20.8 mW/cm{sup 3}, the structure of silicon thin films evolves from a completely amorphous phase to an intermediate phase containing both amorphous and microcrystalline silicon. As the power density is increased to a moderate value of 25 mW/cm{sup 3}, a highly crystallized (111)-preferred hydrogenated microcrystalline silicon ({mu}c-Si:H) film featuring a vertically aligned cone-shaped structure, is emerging. Both the crystallinity and deposition rate exhibit a monotonic increase with the increase in the rf power density, reaching a maximum value of 85% and 1.07 nm/s, respectively, at a power density of 41.7 mW/cm{sup 3}. Scanning electron microscopy reveals that continuous and dense {mu}c-Si:H films with grain size of tens to hundreds nanometers can be achieved deterministically without the formation of amorphous incubation layer, and this is of great importance for synthesis of multilayer structures in p-i-n solar cells. The formation mechanism of the {mu}c-Si:H films and the elimination of the amorphous incubation layer are explained in terms of the high electron density and the plasma-surface interactions.

  6. Effects of molecular weight on the liquid-liquid transition in polystyrene melts studied by low-frequency anelastic spectroscopy

    NASA Astrophysics Data System (ADS)

    Wu, X. B.; Shang, S. Y.; Xu, Q. L.; Zhu, Z. G.

    2008-04-01

    A substantial internal friction peak associated with the liquid-liquid transition (Tll) has been observed in polystyrene (PS) melts with different molecular weights Mw. The peak is of the relaxation type and suggested to be caused by the cooperative rearrangement of PS chains. The relaxation time follows the Vogel-Fulcher-Tamman equation. With increasing Mw, the PS melt exhibits a higher energy barrier, a smaller concentration of mobile species, and a stronger coupling between mobile species at Tll. In addition, to quantify the strength of the temperature dependence of the relaxation time, a parameter mll is defined for PS melt according to Angell's fragility concept. The value of mll decreases with increasing Mw, indicating a slower cooperative rearrangement of PS chains toward Tll. Moreover, at Mw⩽52.5kg/mol, mll rapidly drops with Mw, while it more slowly decreases at Mw>52.5kg/mol. The fact suggests more topological constraints due to the intrachain interactions in very long chains.

  7. Spectral Index and Quasi-Periodic Oscillation Frequency Correlation in Black Hole Sources: Observational Evidence of Two Phases and Phase Transition in Black Holes

    NASA Technical Reports Server (NTRS)

    Titarchuk, Lev; Fiorito, Ralph

    2004-01-01

    Recent studies have shown that strong correlations are observed between the low frequencies (1-10 Hz) of quasi-periodic oscillations (QPOs) and the spectral power law index of several black hole (BH) candidate sources, in low (hard) states, steep power law (soft) states, and transitions between these states. The observations indicate that the X-ray spectra of such state (phases) show the presence of a power-law component and are sometimes related to simultaneous radio emission, indicating the probable presence of a jet. Strong QPOs (>20% rms) are present in the power density spectrum in the spectral range where the power-law component is dominant (i.e., 60%90%). This evidence contradicts the dominant, long-standing interpretation of QPOs as a signature of the thermal accretion disk. We present the data from the literature and our own data to illustrate the dominance of power-law index-QPO frequency correlations. We provide a model that identifies and explains the origin of the QPOs and how they are imprinted on the properties of the power-law flux component. We argue for the existence of a bounded compact coronal region that is a natural consequence of the adjustment of the Keplerian disk flow to the innermost sub-Keplerian boundary conditions near the central object and that ultimately leads to the formation of a transition layer (TL) between the adjustment radius and the innermost boundary. The model predicts two phases or states dictated by the photon upscattering produced in the TL: (1) a hard state, in which the TL is optically thin and very hot (kT approximately greater than 50 keV), producing photon upscattering via thermal Comptonization (the photon spectrum index Gamma approximates 1.7 for this state is dictated by gravitational energy release and Compton cooling in an optically thin shock near the adjustment radius), and (2) a soft state that is optically thick and relatively cold (kT approximately less than 5 keV the index for this state, Gamma

  8. A 2.5-dimensional method for the prediction of structure-borne low-frequency noise from concrete rail transit bridges.

    PubMed

    Li, Qi; Song, Xiaodong; Wu, Dingjun

    2014-05-01

    Predicting structure-borne noise from bridges subjected to moving trains using the three-dimensional (3D) boundary element method (BEM) is a time consuming process. This paper presents a two-and-a-half dimensional (2.5D) BEM-based procedure for simulating bridge-borne low-frequency noise with higher efficiency, yet no loss of accuracy. The two-dimensional (2D) BEM of a bridge with a constant cross section along the track direction is adopted to calculate the spatial modal acoustic transfer vectors (MATVs) of the bridge using the space-wave number transforms of its 3D modal shapes. The MATVs calculated using the 2.5D method are then validated by those computed using the 3D BEM. The bridge-borne noise is finally obtained through the MATVs and modal coordinate responses of the bridge, considering time-varying vehicle-track-bridge dynamic interaction. The presented procedure is applied to predict the sound pressure radiating from a U-shaped concrete bridge, and the computed results are compared with those obtained from field tests on Shanghai rail transit line 8. The numerical results match well with the measured results in both time and frequency domains at near-field points. Nevertheless, the computed results are smaller than the measured ones for far-field points, mainly due to the sound radiation from adjacent spans neglected in the current model. PMID:24815255

  9. Monitoring of slip at the transition zone on the plate interface estimated from non-volcanic deep low-frequency tremors in southwestern Japan

    NASA Astrophysics Data System (ADS)

    Ishida, R.; Hiramatsu, Y.; Obara, K.; Matsuzawa, T.

    2011-12-01

    In southwestern Japan, non-volcanic deep low-frequency (DLF) tremors (e.g., Obara, 2002) and short-term slow slip events (S-SSEs; e.g., Obara et al., 2004) occur in temporal and spatial coincidence with the active stages of DLF tremors (Obara et al., 2004). Based on this feature, Hiramatsu et al. (2008) proposed a method to monitor slip at the transition zone between the locked and aseismic slip zones on the plate interface using DLF tremors. In this study, we applied the method as the same way of previous studies (Hiramatsu et al., 2008; Hirose et al., 2010) and estimated the long-term average slip rate at the transition zone from DLF tremors in southwestern Japan. We also estimated the slip distributions of S-SSEs from DLF tremors using the modified envelope correlation method (ECM) tremor catalog (Maeda and Obara, 2009) and the hourly centroid tremor catalog (Obara et al., 2010) along with the ECM tremor catalog (Obara, 2002) in southwestern Japan. The modified ECM applied both the differential travel time and the spatial distribution of mean square amplitudes to estimate a tremor's spatial location and radiation energy. The hourly centroid tremor catalog is constructed using a clustering process to estimate centroid locations, revealing clear depth-dependent behavior of the tremor activity. The cumulative seismic moment from 2001 to 2009 increases at a constant rate, indicating a constant moment release rate in the long-term average. We estimated slip rate at the transition zone using the formula ˙ {M0} = μ S_˙ {U}, where ˙ {M0} is the moment release rate, μ the rigidity, S the fault area that is related to the slip of S-SSEs in each region, and ˙ {U} the slip rate. We obtained the slip rates of 4.1 ± 0.5 cm/yr, 3.7 ± 0.6 cm/yr, and 2.6 ± 0.2 cm/yr in the western Shikoku, northern Kii peninsula, and Tokai regions, respectively, at the transition zone through the analyzed period. The slip deficit rate at the transition zone in each region is 2.6cm/yr, 2

  10. Grading More Accurately

    ERIC Educational Resources Information Center

    Rom, Mark Carl

    2011-01-01

    Grades matter. College grading systems, however, are often ad hoc and prone to mistakes. This essay focuses on one factor that contributes to high-quality grading systems: grading accuracy (or "efficiency"). I proceed in several steps. First, I discuss the elements of "efficient" (i.e., accurate) grading. Next, I present analytical results…

  11. Illuminating the Transition Between Steady Sliding and Episodic Tremor and Slow Slip Using Low Frequency Earthquakes at the Downdip Edge

    NASA Astrophysics Data System (ADS)

    Creager, K. C.; Sweet, J.; Vidale, J. E.; Houston, H.

    2012-12-01

    Using data from the Array of Arrays and CAFE experiments, we have identified eight Low-Frequency Earthquake (LFE) families on the subduction plate interface, under the Olympic Peninsula, Washington State. We analyze the time history of each during the time interval 2007-2012. The updip-most family (LFE1) only lights up during the well-known northern Cascadia Episodic Tremor and Slip (ETS) events that recur every 15 months. The recurrence intervals shorten from updip LFE1 to the downdip-most family (LFE4), which repeats every 14 days; 30 times more frequently. This presentation focuses on the downdip family. See the Sweet presentation, this session, for an analysis of the updip-most LFE family. LFEs from family 4 typically have durations of about one hour, with as many as 100 repeats during that time. Unlike their updip counterparts, they occur as discrete events without other LFEs or tremor visible during that time. They are strongly modulated by tidal shear stress. Twice as many LFEs occur during encouraging shear stress as during discouraging times. In contrast, these same LFEs occur when tidal normal stress is compressive which should inhibit slip. To reconcile LFE occurrence with favorable tidal Coulomb stress requires that the friction coefficient be less than 0.2 .This extreme sensitivity to very small shear stresses also suggests near lithostatic pore fluid pressures. We propose that the bursts of LFEs in this family correspond to discrete slow-slip events that occur with remarkable regularity. To add up to plate rates, each burst would correspond to a little more than 1 mm of slip, and each individual LFE to a little less than 0.1 mm, assuming all the slip occurs in the form of LFE activity and each LFE ruptures the same spot. One of these event sequences was captured by our 1-km aperture 80-element Big Skidder Array in 2008. Careful stacked correlation functions from 32 LFEs relative to a reference event showed S-P times varied only up to 0.02s, which

  12. Frequency Measurements of Al+ and Hg+ Optical Standards

    NASA Astrophysics Data System (ADS)

    Itano, W. M.; Bergquist, J. C.; Rosenband, T.; Wineland, D. J.; Hume, D.; Chou, C.-W.; Jefferts, S. R.; Heavner, T. P.; Parker, T. E.; Diddams, S. A.; Fortier, T. M.

    2010-02-01

    Frequency standards based on narrow optical transitions in 27Al+ and 199Hg+ ions have been developed at NIST. Both standards have absolute reproducibilities of a few parts in 1017. This is about an order of magnitude better than the fractional uncertainty of the SI second, which is based on the 133Cs hyperfine frequency. Use of femtosecond laser frequency combs makes it possible to compare the optical frequency standards to microwave frequency standards or to each other. The ratio of the Al+ and Hg+ frequencies can be measured more accurately than the reproducibility of the primary cesium frequency standards. Frequency measurements made over time can be used to set limits on the time variation of fundamental constants, such as the fine structure constant α or the quark masses.

  13. Frequency Standards and Metrology

    NASA Astrophysics Data System (ADS)

    Maleki, Lute

    2009-04-01

    imaging an event horizon (Invited) / S. Doeleman. Optically-pumped space cesium clock for Galileo: results of the breadboard / R. Ruffieux ... [et al.] -- pt. IV. Optical clocks I: lattice clocks. Optical lattice clock: seven years of progress and next steps (Invited) / H. Katori, M. Takamoto and T. Akatsuka. The Yb optical lattice clock (Invited) / N. D. Demke ... [et al.]. Optical Lattice clock with Sr atoms (Invited) / P. G. Westergaard ... [et al.]. Development of an optical clock based on neutral strontium atoms held in a lattice trap / E. A. Curtis ... [et al.]. Decoherence and losses by collisions in a [symbol]Sr lattice clock / J. S. R. Vellore Winfred ... [et al.]. Lattice Yb optical clock and cryogenic Cs fountain at INRIM / F. Levi ... [et al.] -- pt. V. Optical clocks II: ion clocks. [Symbol]Yb+ single-ion optical frequency standards (Invited) / Chr. Tamm ... [et al.]. An optical clock based on a single trapped [symbol]Sr+ ion (Invited) / H. S. Margolis ... [et al.]. A trapped [symbol]Yb+ ion optical frequency standard based on the [symbol] transition (Invited) / P. Gill ... [et al.]. Overview of highly accurate RF and optical frequency standards at the National Research Council of Canada (Invited) / A. A. Madej ... [et al.] -- pt. VI. Optical frequency combs. Extreme ultraviolet frequency combs for spectroscopy (Invited) / A. Ozawa ... [et al.]. Development of an optical clockwork for the single trapped strontium ion standard at 445 THz / J. E. Bernard ... [et al.]. A phase-coherent link between the visible and infrared spectral ranges using a combination of CW OPO and femtosecond laser frequency comb / E. V. Kovalchuk and A. Peters. Improvements to the robustness of a TI: sapphire-based femtosecond comb at NPL / V. Tsatourian ... [et al.] -- pt. VII. Atomic microwave standards. NIST FI and F2 (Invited) / T. P. Heavner ... [et al.]. Atomic fountains for the USNO master clock (Invited) / C. Ekstrom ... [et al.]. The transportable cesium fountain clock NIM5

  14. Fast stabilization of a CO{sub 2} laser for a frequency standard at 10 {mu}m

    SciTech Connect

    Pisani, M.Q.; Sassi, M.P.; Zucco, M.

    1994-12-31

    A CO{sub 2} laser has been frequency stabilized to an OsO{sub 4} transition with a control bandwidth of 10 kHz. The obtained spectral purity of the laser is 100 Hz. The realization of very accurate frequency standards and experiments of high resolution spectroscopy in the 10 {mu}m region are made possible by this source.

  15. Accurate monotone cubic interpolation

    NASA Technical Reports Server (NTRS)

    Huynh, Hung T.

    1991-01-01

    Monotone piecewise cubic interpolants are simple and effective. They are generally third-order accurate, except near strict local extrema where accuracy degenerates to second-order due to the monotonicity constraint. Algorithms for piecewise cubic interpolants, which preserve monotonicity as well as uniform third and fourth-order accuracy are presented. The gain of accuracy is obtained by relaxing the monotonicity constraint in a geometric framework in which the median function plays a crucial role.

  16. Accurate Finite Difference Algorithms

    NASA Technical Reports Server (NTRS)

    Goodrich, John W.

    1996-01-01

    Two families of finite difference algorithms for computational aeroacoustics are presented and compared. All of the algorithms are single step explicit methods, they have the same order of accuracy in both space and time, with examples up to eleventh order, and they have multidimensional extensions. One of the algorithm families has spectral like high resolution. Propagation with high order and high resolution algorithms can produce accurate results after O(10(exp 6)) periods of propagation with eight grid points per wavelength.

  17. Absolute frequency measurement of the neutral 40Ca optical frequency standard at 657 nm based on microkelvin atoms

    NASA Astrophysics Data System (ADS)

    Wilpers, G.; Oates, C. W.; Diddams, S. A.; Bartels, A.; Fortier, T. M.; Oskay, W. H.; Bergquist, J. C.; Jefferts, S. R.; Heavner, T. P.; Parker, T. E.; Hollberg, L.

    2007-04-01

    We report an absolute frequency measurement of the optical clock transition at 657 nm in 40Ca with a relative uncertainty of 7.5 × 10-15, one of the most accurate frequency measurements of a neutral atom optical transition to date. The frequency (455 986 240 494 135.8 ± 3.4) Hz was measured by stabilizing a diode laser system to a spectroscopic signal derived from an ensemble of 106 atoms cooled in two stages to a temperature of 10 µK. The measurement used a femtosecond-laser-based frequency comb to compare the Ca transition frequency with that of the single-ion 199Hg+ optical frequency standard at NIST. The Hg+ frequency was simultaneously calibrated relative to the NIST Cs fountain via the NIST time scale to yield an absolute value for the Ca transition frequency. The relative fractional instability between the two optical standards was 2 × 10-15 for 10 s of averaging time and 2 × 10-16 for 2000 s.

  18. IMPROVED log(gf) VALUES FOR LINES OF Ti I AND ABUNDANCE DETERMINATIONS IN THE PHOTOSPHERES OF THE SUN AND METAL-POOR STAR HD 84937 (ACCURATE TRANSITION PROBABILITIES FOR Ti I)

    SciTech Connect

    Lawler, J. E.; Guzman, A.; Wood, M. P.; Sneden, C.; Cowan, J. J. E-mail: adrianaguzman2014@u.northwestern.edu E-mail: chris@verdi.as.utexas.edu

    2013-04-01

    New atomic transition probability measurements for 948 lines of Ti I are reported. Branching fractions from Fourier transform spectra and from spectra recorded using a 3 m echelle spectrometer are combined with published radiative lifetimes from laser-induced fluorescence measurements to determine these transition probabilities. Generally good agreement is found in comparisons to the NIST Atomic Spectra Database. The new Ti I data are applied to re-determine the Ti abundance in the photospheres of the Sun and metal-poor star HD 84937 using many lines covering a range of wavelength and excitation potential to explore possible non-local thermal equilibrium effects. The variation of relative Ti/Fe abundance with metallicity in metal-poor stars observed in earlier studies is supported in this study.

  19. Note: A frequency modulated wireless interrogation system exploiting narrowband acoustic resonator for remote physical quantity measurement

    NASA Astrophysics Data System (ADS)

    Droit, C.; Martin, G.; Ballandras, S.; Friedt, J.-M.

    2010-05-01

    We demonstrate the wireless conversion of frequency modulation to amplitude modulation by radio frequency resonators as means of accurately determining the resonance frequency of passive acoustoelectronic sensors. The emitted frequency modulated radio frequency pulses are generated by a pulsed radar for probing a surface acoustic wave based sensor. The sharp sign transition of the amplitude modulated received signal provides a signal on which a feedback loop is locked to monitor the resonance signal. The strategy is demonstrated using a full software implementation on a generic hardware, resulting in 2 Hz resolution at 1 s integration time limited by the proportional feedback loop.

  20. Magic wavelengths for terahertz clock transitions

    SciTech Connect

    Zhou Xiaoji; Xu Xia; Chen Xuzong; Chen Jingbiao

    2010-01-15

    Magic wavelengths for laser trapping of boson isotopes of alkaline-earth metal atoms Sr, Ca, and Mg are investigated while considering terahertz clock transitions between the {sup 3}P{sub 0}, {sup 3}P{sub 1}, and {sup 3}P{sub 2} metastable triplet states. Our calculation shows that magic wavelengths for laser trapping do exist. This result is important because those metastable states have already been used to make accurate clocks in the terahertz frequency domain. Detailed discussions for magic wavelengths for terahertz clock transitions are given in this article.

  1. An ultra-stable optical frequency standard for telecommunication purposes based upon the 5S1/2 → 5D5/2 two-photon transition in rubidium

    NASA Astrophysics Data System (ADS)

    Terra, Osama; Hussein, Hatem

    2016-02-01

    In this study, we report the development of a frequency standard for optical fiber communication applications based on a two-photon transition in rubidium at 385.2 THz. This standard kills two birds with one stone in the sense it is capable of providing us with two highly stable serviceable wavelengths at 778.1 and 1556.2 nm. In this system, we exploit the narrow line-width of a fiber laser emitting at 1556.2 nm in conjunction with an erbium-doped fiber amplifier to generate a sufficient second harmonic laser beam at 778.1 nm in a periodically polled lithium niobate waveguide mixer in order to probe and frequency-lock the laser to the 5S1/2 ( F g = 3)-5D5/2 ( F e = 5) hyperfine two-photon transition component in 85Rb. The metrological performance of the standard is evaluated with the aid of an optical frequency comb synthesizer. Allan variance measurement shows a stability of 4 × 10-12 at 1 s (limited by the comb stability), reaching a floor of 6.8 × 10-13 at 1000 s. After correction of all the major systematic frequency shifts including the light shift, the absolute frequency is found to be 385 285 142 374.0 (5.0) kHz. Moreover, the absolute frequencies of most of the hyperfine components of the 5S1/2-5D5/2 transition of the two naturally existing rubidium isotopes are measured using a femtosecond frequency comb synthesizer after stabilizing a laser on each component.

  2. Absolute frequency measurement of 1S0(F = 1/2)-3P0(F = 1/2) transition of 171Yb atoms in a one-dimensional optical lattice at KRISS

    NASA Astrophysics Data System (ADS)

    Park, Chang Yong; Yu, Dai-Hyuk; Lee, Won-Kyu; Eon Park, Sang; Kim, Eok Bong; Lee, Sun Kyung; Cho, Jun Woo; Yoon, Tai Hyun; Mun, Jongchul; Jong Park, Sung; Kwon, Taeg Yong; Lee, Sang-Bum

    2013-04-01

    We measured the absolute frequency of the optical clock transition 1S0(F = 1/2)-3P0(F = 1/2) of 171Yb atoms confined in a one-dimensional optical lattice and it was determined to be 518 295 836 590 863.5(8.1) Hz. The frequency was measured against Terrestrial Time (TT; the SI second on the geoid) using an optical frequency comb of which the frequency was phase-locked to an H-maser as a flywheel oscillator traceable to TT. The magic wavelength was also measured as 394 798.48(79) GHz. The results are in good agreement with two previous measurements of other institutes within the specified uncertainty of this work.

  3. High-precision frequency measurement of the 423-nm Ca i line

    SciTech Connect

    Salumbides, E. J.; Maslinskas, V.; Dildar, I. M.; Wolf, A. L.; Duijn, E.-J. van; Eikema, K. S. E.; Ubachs, W.

    2011-01-15

    We have performed an accurate frequency calibration of the 4s{sup 2} {sup 1}S{sub 0{yields}}4s4p {sup 1}P{sub 1} principal resonance line of the neutral calcium atom at 423 nm. Doppler-free cw excitation on a Ca atomic beam was performed by utilizing a Sagnac geometry in the alignment of the excitation beams. From frequency calibrations against a frequency comb, stabilized to a global positioning system (GPS) disciplined Rb standard, the transition frequency is determined at 709 078 373.01(35) MHz for the main {sup 40}Ca isotope. Slightly lower accuracies are obtained for the transition frequencies of the less abundant isotopes. The achieved fractional uncertainty of 5x10{sup -10} exceeds the requirements for including this transition in investigations that aim to probe a possible variation in the fine-structure constant {alpha} on cosmological time scales.

  4. Frequency spirals

    NASA Astrophysics Data System (ADS)

    Ottino-Löffler, Bertrand; Strogatz, Steven H.

    2016-09-01

    We study the dynamics of coupled phase oscillators on a two-dimensional Kuramoto lattice with periodic boundary conditions. For coupling strengths just below the transition to global phase-locking, we find localized spatiotemporal patterns that we call "frequency spirals." These patterns cannot be seen under time averaging; they become visible only when we examine the spatial variation of the oscillators' instantaneous frequencies, where they manifest themselves as two-armed rotating spirals. In the more familiar phase representation, they appear as wobbly periodic patterns surrounding a phase vortex. Unlike the stationary phase vortices seen in magnetic spin systems, or the rotating spiral waves seen in reaction-diffusion systems, frequency spirals librate: the phases of the oscillators surrounding the central vortex move forward and then backward, executing a periodic motion with zero winding number. We construct the simplest frequency spiral and characterize its properties using analytical and numerical methods. Simulations show that frequency spirals in large lattices behave much like this simple prototype.

  5. Accurate maser positions for MALT-45

    NASA Astrophysics Data System (ADS)

    Jordan, Christopher; Bains, Indra; Voronkov, Maxim; Lo, Nadia; Jones, Paul; Muller, Erik; Cunningham, Maria; Burton, Michael; Brooks, Kate; Green, James; Fuller, Gary; Barnes, Peter; Ellingsen, Simon; Urquhart, James; Morgan, Larry; Rowell, Gavin; Walsh, Andrew; Loenen, Edo; Baan, Willem; Hill, Tracey; Purcell, Cormac; Breen, Shari; Peretto, Nicolas; Jackson, James; Lowe, Vicki; Longmore, Steven

    2013-10-01

    MALT-45 is an untargeted survey, mapping the Galactic plane in CS (1-0), Class I methanol masers, SiO masers and thermal emission, and high frequency continuum emission. After obtaining images from the survey, a number of masers were detected, but without accurate positions. This project seeks to resolve each maser and its environment, with the ultimate goal of placing the Class I methanol maser into a timeline of high mass star formation.

  6. Applications of Kinetic Inductance: Parametric Amplifier & Phase Shifter, 2DEG Coupled Co-planar Structures & Microstrip to Slotline Transition at RF Frequencies

    NASA Astrophysics Data System (ADS)

    Surdi, Harshad

    Kinetic inductance springs from the inertia of charged mobile carriers in alternating electric fields and it is fundamentally different from the magnetic inductance which is only a geometry dependent property. The magnetic inductance is proportional to the volume occupied by the electric and magnetic fields and is often limited by the number of turns of the coil. Kinetic inductance on the other hand is inversely proportional to the density of electrons or holes that exert inertia, the unit mass of the charge carriers and the momentum relaxation time of these charge carriers, all of which can be varied merely by modifying the material properties. Highly sensitive and broadband signal amplifiers often broaden the field of study in astrophysics. Quantum-noise limited travelling wave kinetic inductance parametric amplifiers offer a noise figure of around 0.5 K +/- 0.3 K as compared to 20 K in HEMT signal amplifiers and can be designed to operate to cover the entire W-band (75 GHz -- 115 GHz). The research cumulating to this thesis involves applying and exploiting kinetic inductance properties in designing a W-band orthogonal mode transducer, quadratic gain phase shifter with a gain of ~49 dB over a meter of microstrip transmission line. The phase shifter will help in measuring the maximum amount of phase shift Deltaφmax(I) that can be obtained from half a meter transmission line which helps in predicting the gain of a travelling wave parametric amplifier. In another project, a microstrip to slot line transition is designed and optimized to operate at 150 GHz and 220 GHz frequencies, that is used as a part of horn antenna coupled microwave kinetic inductance detector proposed to operate from 138 GHz to 250 GHz. In the final project, kinetic inductance in a 2D electron gas (2DEG) is explored by design, simulation, fabrication and experimentation. A transmission line model of a 2DEG proposed by Burke (1999), is simulated and verified experimentally by fabricating a

  7. Identification by UV resonance Raman spectroscopy of an imino tautomer of 5-hydroxy-2′-deoxycytidine, a powerful base analog transition mutagen with a much higher unfavored tautomer frequency than that of the natural residue 2′-deoxycytidine

    PubMed Central

    Suen, Wu; Spiro, Thomas G.; Sowers, Lawrence C.; Fresco, Jacques R.

    1999-01-01

    UV resonance Raman spectroscopy was used to detect and estimate the frequency of the unfavored imino tautomer of the transition mutagen 5-hydroxy-2′-deoxycytidine (HO5dCyt) in its anionic form. In DNA, this 2′-deoxycytidine analog arises from the oxidation of 2′-deoxycytidine and induces C → T transitions with 102 greater frequency than such spontaneous transitions. An imino tautomer marker carbonyl band (≈1650 cm−1) is enhanced at ≈65°C against an otherwise stable spectrum of bands associated with the favored amino tautomer. This band is similarly present in the UV resonance Raman spectra of the imino cytidine analogs N3-methylcytidine at high pH and N4-methoxy-2′-deoxycytidine at pH 7 and displays features attributable to the imino form of C residues and their derivatives. The fact that the imino tautomer of HO5dCyt occurs at a frequency consistent with its high mutagenic enhancement lends strong support to the hypothesis that unfavored base tautomers play important roles in the mispair intermediates of replication leading to substitution mutations. PMID:10200291

  8. Frequency Standards and Metrology

    NASA Astrophysics Data System (ADS)

    Maleki, Lute

    2009-04-01

    imaging an event horizon (Invited) / S. Doeleman. Optically-pumped space cesium clock for Galileo: results of the breadboard / R. Ruffieux ... [et al.] -- pt. IV. Optical clocks I: lattice clocks. Optical lattice clock: seven years of progress and next steps (Invited) / H. Katori, M. Takamoto and T. Akatsuka. The Yb optical lattice clock (Invited) / N. D. Demke ... [et al.]. Optical Lattice clock with Sr atoms (Invited) / P. G. Westergaard ... [et al.]. Development of an optical clock based on neutral strontium atoms held in a lattice trap / E. A. Curtis ... [et al.]. Decoherence and losses by collisions in a [symbol]Sr lattice clock / J. S. R. Vellore Winfred ... [et al.]. Lattice Yb optical clock and cryogenic Cs fountain at INRIM / F. Levi ... [et al.] -- pt. V. Optical clocks II: ion clocks. [Symbol]Yb+ single-ion optical frequency standards (Invited) / Chr. Tamm ... [et al.]. An optical clock based on a single trapped [symbol]Sr+ ion (Invited) / H. S. Margolis ... [et al.]. A trapped [symbol]Yb+ ion optical frequency standard based on the [symbol] transition (Invited) / P. Gill ... [et al.]. Overview of highly accurate RF and optical frequency standards at the National Research Council of Canada (Invited) / A. A. Madej ... [et al.] -- pt. VI. Optical frequency combs. Extreme ultraviolet frequency combs for spectroscopy (Invited) / A. Ozawa ... [et al.]. Development of an optical clockwork for the single trapped strontium ion standard at 445 THz / J. E. Bernard ... [et al.]. A phase-coherent link between the visible and infrared spectral ranges using a combination of CW OPO and femtosecond laser frequency comb / E. V. Kovalchuk and A. Peters. Improvements to the robustness of a TI: sapphire-based femtosecond comb at NPL / V. Tsatourian ... [et al.] -- pt. VII. Atomic microwave standards. NIST FI and F2 (Invited) / T. P. Heavner ... [et al.]. Atomic fountains for the USNO master clock (Invited) / C. Ekstrom ... [et al.]. The transportable cesium fountain clock NIM5

  9. High density terahertz frequency comb produced by coherent synchrotron radiation

    PubMed Central

    Tammaro, S.; Pirali, O.; Roy, P.; Lampin, J.-F.; Ducournau, G.; Cuisset, A.; Hindle, F.; Mouret, G.

    2015-01-01

    Frequency combs have enabled significant progress in frequency metrology and high-resolution spectroscopy extending the achievable resolution while increasing the signal-to-noise ratio. In its coherent mode, synchrotron radiation is accepted to provide an intense terahertz continuum covering a wide spectral range from about 0.1 to 1 THz. Using a dedicated heterodyne receiver, we reveal the purely discrete nature of this emission. A phase relationship between the light pulses leads to a powerful frequency comb spanning over one decade in frequency. The comb has a mode spacing of 846 kHz, a linewidth of about 200 Hz, a fractional precision of about 2 × 10−10 and no frequency offset. The unprecedented potential of the comb for high-resolution spectroscopy is demonstrated by the accurate determination of pure rotation transitions of acetonitrile. PMID:26190043

  10. Autonomous Rubidium Clock Weak Frequency Jump Detector for Onboard Navigation Satellite System.

    PubMed

    Khare, Akshay; Arora, Rajat; Banik, Alak; Mehta, Sanjay D

    2016-02-01

    Frequency jumps are common in rubidium frequency sources. They affect the estimation of user position in navigational satellite systems. These jumps must be detected and corrected immediately as they have direct impact on the navigation system integrity. A novel weak frequency jump detector is proposed based on a Kalman filter with a multi-interval approach. This detector can be applied for both "sudden" and "slow" frequency transitions. In this detection method, noises of clock data are reduced by Kalman filtering, for accurate estimation of jump size with less latency. Analysis on in-orbit rubidium atomic frequency standard (RAFS) phase telemetry data shows that the detector can be used for fast detection and correction of weak frequency jumps. Furthermore, performance comparison of different existing frequency jump detection techniques with the proposed detector is discussed. A multialgorithm-based strategy is proposed depending on the jump size and latency for onboard navigation satellites having RAFS as the primary frequency source. PMID:26685233

  11. Transition from precise to accurate critical dimension metrology

    NASA Astrophysics Data System (ADS)

    Ukraintsev, Vladimir A.; Tsai, Margaret C.; Lii, Tom; Jackson, Ricky A.

    2007-03-01

    A new measurement system analysis (MSA) methodology has been developed at Texas Instruments (TI) to evaluate the status of the 65 nm technology critical dimension (CD) metrology and its readiness for production. Elements of the methodology were used in a previously reported scatterometry evaluation [1]. At every critical process level the precision, bias, linearity and total measurement uncertainty (TMU) were evaluated for metrology fleet over extended periods of time, and with the technology representative set of samples. The samples with variations that fully covered and often exceeded process space were pre-calibrated by CD atomic force microscope (AFM). CD AFM measurement precision was determined for every analyzed process level based on repeated measurements conducted over several days. The National Institute of Standards and Technologies (NIST) traceable standards were used to verify CD AFM line CD and scale calibrations. Therefore, for the first time the NIST traceability has been established for CD metrology at every critical process level for the entire technology. The data indicates an overall healthy status of the 65 nm CD metrology. Sub-nanometer accuracy has been established for gate CD metrology. The thorough CD metrology characterization and specifically absolute CD calibration were instrumental in seamless technology transfer from 200 mm to 300 mm fabs. The qualification of CD metrology also revealed several problems. Most of these are well-known from previous studies and should soon be addressed. CD scanning electron microscopy (SEM) has a systematic problem with bias of CD measurements. The problem is common for several front-end and back-end of line process levels. For most process levels, TMU of CD SEM is noticeably affected by sample modification inflicted by electron irradiation (shrinkage, charging, buildups, etc.). This causes problems, especially in the case of fleet TMU evaluation. An improved data collection methodology should be devised to minimize the impact of sample modification on fleet TMU measurements. The reported progress in semiconductor industrial CD metrology became possible after a recent breakthrough in line CD standard technology [2,3], recognition of CD AFM as an instrument for CD traceability [4,5] and development of the concept and mathematical tools for TMU analysis [6,7].

  12. Indirect Terahertz Spectroscopy of Molecular Ions Using Highly Accurate and Precise Mid-Ir Spectroscopy

    NASA Astrophysics Data System (ADS)

    Mills, Andrew A.; Ford, Kyle B.; Kreckel, Holger; Perera, Manori; Crabtree, Kyle N.; McCall, Benjamin J.

    2009-06-01

    With the advent of Herschel and SOFIA, laboratory methods capable of providing molecular rest frequencies in the terahertz and sub-millimeter regime are increasingly important. As of yet, it has been difficult to perform spectroscopy in this wavelength region due to the limited availability of radiation sources, optics, and detectors. Our goal is to provide accurate THz rest frequencies for molecular ions by combining previously recorded microwave transitions with combination differences obtained from high precision mid-IR spectroscopy. We are constructing a Sensitive Resolved Ion Beam Spectroscopy setup which will harness the benefits of kinematic compression in a molecular ion beam to enable very high resolution spectroscopy. This ion beam is interrogated by continuous-wave cavity ringdown spectroscopy using a home-made widely tunable difference frequency laser that utilizes two near-IR lasers and a periodically-poled lithium niobate crystal. Here, we report our efforts to optimize our ion beam spectrometer and to perform high-precision and high-accuracy frequency measurements using an optical frequency comb. footnote

  13. NNLOPS accurate associated HW production

    NASA Astrophysics Data System (ADS)

    Astill, William; Bizon, Wojciech; Re, Emanuele; Zanderighi, Giulia

    2016-06-01

    We present a next-to-next-to-leading order accurate description of associated HW production consistently matched to a parton shower. The method is based on reweighting events obtained with the HW plus one jet NLO accurate calculation implemented in POWHEG, extended with the MiNLO procedure, to reproduce NNLO accurate Born distributions. Since the Born kinematics is more complex than the cases treated before, we use a parametrization of the Collins-Soper angles to reduce the number of variables required for the reweighting. We present phenomenological results at 13 TeV, with cuts suggested by the Higgs Cross section Working Group.

  14. Precision Measurement of Carbon Dioxide Hotband Transition at 4.3 Micron Using a Hot Cell

    NASA Astrophysics Data System (ADS)

    Luo, Pei-Ling; Tian, Jyun-Yu; Chen, Hshan-Chen; Lien, Yu-Hung; Shy, Jow-Tsong

    2011-06-01

    We report a mid-IR spectrometer based on a difference frequency generation (DFG). This tunable CW DFG source covers the spectral range from 2.6 {μ}m to 4.7 {μ}m with an output power of a few mW. The saturation spectrum of the 12C16O2 hot band 0111 - 0110 P(30) transition is greatly enhanced by using a 40 cm long hot cell. The saturated absorption S/N ratio of over 1000 at 1 Hz bandwidth is achieved. We investigate the linewidth analysis and absolute frequency measurement of this transition. This transition center frequency of 69,267,228.761(15) MHz and the transition linewidth of 3.040(36) MHz are accurately measured.

  15. Accurate determination of the fine-structure intervals in the 3P ground states of C-13 and C-12 by far-infrared laser magnetic resonance

    NASA Technical Reports Server (NTRS)

    Cooksy, A. L.; Saykally, R. J.; Brown, J. M.; Evenson, K. M.

    1986-01-01

    Accurate values are presented for the fine-structure intervals in the 3P ground state of neutral atomic C-12 and C-13 as obtained from laser magnetic resonance spectroscopy. The rigorous analysis of C-13 hyperfine structure, the measurement of resonant fields for C-12 transitions at several additional far-infrared laser frequencies, and the increased precision of the C-12 measurements, permit significant improvement in the evaluation of these energies relative to earlier work. These results will expedite the direct and precise measurement of these transitions in interstellar sources and should assist in the determination of the interstellar C-12/C-13 abundance ratio.

  16. How to accurately bypass damage

    PubMed Central

    Broyde, Suse; Patel, Dinshaw J.

    2016-01-01

    Ultraviolet radiation can cause cancer through DNA damage — specifically, by linking adjacent thymine bases. Crystal structures show how the enzyme DNA polymerase η accurately bypasses such lesions, offering protection. PMID:20577203

  17. The 31S0-33P0 transition in the aluminum isotope ion 26A1+: a potentially superior passive laser frequency standard and spectrum analyzer.

    PubMed Central

    Yu, N; Dehmelt, H; Nagourney, W

    1992-01-01

    The aluminum 26 isotope ion is proposed here as a possible candidate for a superior atomic clock. For this even isotope, the extraordinarily long lifetime of the 33P0 state offers a potential clock transition (31S0-33P0) linewidth of 300 microHz. The mF = 0 --> 0 transition has only a quadratic Zeeman shift approximately 4 x 10(-18) at 0.1 Gauss magnetic field, compared to approximately 10(-8) for the hydrogen maser. Electronic quadrupole moments vanish for both J and J' states and with them shifts due to electric field gradients. All shifts have been estimated and are orders of magnitude less than for Hg+ and Ba+, which are being studied as atomic clock elements. PMID:11607314

  18. Accurate Evaluation of Quantum Integrals

    NASA Technical Reports Server (NTRS)

    Galant, David C.; Goorvitch, D.

    1994-01-01

    Combining an appropriate finite difference method with Richardson's extrapolation results in a simple, highly accurate numerical method for solving a Schr\\"{o}dinger's equation. Important results are that error estimates are provided, and that one can extrapolate expectation values rather than the wavefunctions to obtain highly accurate expectation values. We discuss the eigenvalues, the error growth in repeated Richardson's extrapolation, and show that the expectation values calculated on a crude mesh can be extrapolated to obtain expectation values of high accuracy.

  19. Frequencies of solar oscillations

    NASA Technical Reports Server (NTRS)

    Libbrecht, K. G.; Woodard, M. F.; Kaufman, J. M.

    1990-01-01

    Solar oscillations have been observed at three different spatial scales at Big Bear Solar Observatory during 1986-1987 and, using three data sets, a new and more accurate table of solar oscillation frequencies has been compiled. The oscillations, which are presented as functions of radial order n and spherical harmonic degree l, are averages over azimuthal order and therefore approximate the normal mode frequencies of a nonrotating, spherically symmetric sun, near solar minimum. The table contains frequencies for most of the solar p and f modes with l between 0 and 1860, n between 0 and 26, and oscillation mode frequencies between 1.0 and 5.3.

  20. VizieR Online Data Catalog: Ro-vibration transitions of the protonated argon ion (Cueto+, 2014)

    NASA Astrophysics Data System (ADS)

    Cueto, M.; Cernicharo, J.; Barlow, M. J.; Swinyard, B. M.; Herrero, V. J.; Tanarro, I.; Domenech, J. L.

    2016-04-01

    We did accurate laboratory measurement of 19 lines of the v=1-0 band of 36ArH+ and 38ArH+. The new wavenumbers have improved the Dunham-type fit to all published rotation and vibration-rotation data for all isotopologues of this molecule, allowing more accurate predictions of other transitions for any of them. Table3 contains all published observed frequencies of all isotopologues, as well as the values calculated from our fit. (1 data file).

  1. How the transition frequencies of microtubule dynamic instability (nucleation, catastrophe, and rescue) regulate microtubule dynamics in interphase and mitosis: analysis using a Monte Carlo computer simulation.

    PubMed Central

    Gliksman, N R; Skibbens, R V; Salmon, E D

    1993-01-01

    Microtubules (MTs) in newt mitotic spindles grow faster than MTs in the interphase cytoplasmic microtubule complex (CMTC), yet spindle MTs do not have the long lengths or lifetimes of the CMTC microtubules. Because MTs undergo dynamic instability, it is likely that changes in the durations of growth or shortening are responsible for this anomaly. We have used a Monte Carlo computer simulation to examine how changes in the number of MTs and changes in the catastrophe and rescue frequencies of dynamic instability may be responsible for the cell cycle dependent changes in MT characteristics. We used the computer simulations to model interphase-like or mitotic-like MT populations on the basis of the dynamic instability parameters available from newt lung epithelial cells in vivo. We started with parameters that produced MT populations similar to the interphase newt lung cell CMTC. In the simulation, increasing the number of MTs and either increasing the frequency of catastrophe or decreasing the frequency of rescue reproduced the changes in MT dynamics measured in vivo between interphase and mitosis. Images PMID:8298190

  2. Microfabricated ion frequency standard

    DOEpatents

    Schwindt, Peter; Biedermann, Grant; Blain, Matthew G.; Stick, Daniel L.; Serkland, Darwin K.; Olsson, III, Roy H.

    2010-12-28

    A microfabricated ion frequency standard (i.e. an ion clock) is disclosed with a permanently-sealed vacuum package containing a source of ytterbium (Yb) ions and an octupole ion trap. The source of Yb ions is a micro-hotplate which generates Yb atoms which are then ionized by a ultraviolet light-emitting diode or a field-emission electron source. The octupole ion trap, which confines the Yb ions, is formed from suspended electrodes on a number of stacked-up substrates. A microwave source excites a ground-state transition frequency of the Yb ions, with a frequency-doubled vertical-external-cavity laser (VECSEL) then exciting the Yb ions up to an excited state to produce fluorescent light which is used to tune the microwave source to the ground-state transition frequency, with the microwave source providing a precise frequency output for the ion clock.

  3. Kinetics of the reaction of the heaviest hydrogen atom with H2, the 4Heμ + H2 → 4HeμH + H reaction: experiments, accurate quantal calculations, and variational transition state theory, including kinetic isotope effects for a factor of 36.1 in isotopic mass.

    PubMed

    Fleming, Donald G; Arseneau, Donald J; Sukhorukov, Oleksandr; Brewer, Jess H; Mielke, Steven L; Truhlar, Donald G; Schatz, George C; Garrett, Bruce C; Peterson, Kirk A

    2011-11-14

    The neutral muonic helium atom (4)Heμ, in which one of the electrons of He is replaced by a negative muon, may be effectively regarded as the heaviest isotope of the hydrogen atom, with a mass of 4.115 amu. We report details of the first muon spin rotation (μSR) measurements of the chemical reaction rate constant of (4)Heμ with molecular hydrogen, (4)Heμ + H(2) → (4)HeμH + H, at temperatures of 295.5, 405, and 500 K, as well as a μSR measurement of the hyperfine coupling constant of muonic He at high pressures. The experimental rate constants, k(Heμ), are compared with the predictions of accurate quantum mechanical (QM) dynamics calculations carried out on a well converged Born-Huang (BH) potential energy surface, based on complete configuration interaction calculations and including a Born-Oppenheimer diagonal correction. At the two highest measured temperatures the agreement between the quantum theory and experiment is good to excellent, well within experimental uncertainties that include an estimate of possible systematic error, but at 295.5 K the quantum calculations for k(Heμ) are below the experimental value by 2.1 times the experimental uncertainty estimates. Possible reasons for this discrepancy are discussed. Variational transition state theory calculations with multidimensional tunneling have also been carried out for k(Heμ) on the BH surface, and they agree with the accurate QM rate constants to within 30% over a wider temperature range of 200-1000 K. Comparisons between theory and experiment are also presented for the rate constants for both the D + H(2) and Mu + H(2) reactions in a novel study of kinetic isotope effects for the H + H(2) reactions over a factor of 36.1 in isotopic mass of the atomic reactant. PMID:22088068

  4. Parity nonconservation in atomic Zeeman transitions

    SciTech Connect

    Angstmann, E. J.; Dinh, T. H.; Flambaum, V. V.

    2005-11-15

    We discuss the possibility of measuring nuclear anapole moments in atomic Zeeman transitions and perform the necessary calculations. Advantages of using Zeeman transitions include variable transition frequencies and the possibility of enhancement of parity nonconservation effects.

  5. Calcium optical frequency standard with ultracold atoms: Approaching 10{sup -15} relative uncertainty

    SciTech Connect

    Degenhardt, Carsten; Stoehr, Hardo; Lisdat, Christian; Wilpers, Guido; Schnatz, Harald; Lipphardt, Burghard; Nazarova, Tatiana; Pottie, Paul-Eric; Sterr, Uwe; Helmcke, Juergen; Riehle, Fritz

    2005-12-15

    An optical frequency standard based on an ensemble of neutral calcium atoms laser-cooled to 12 {mu}K has been realized. By using ultracold atoms, one major previous source of uncertainty, the residual Doppler effect, was reduced. We show that cold collisions contribute a negligible amount to the uncertainty. The influence of a temporal evolution of the phase of the laser pulses used to interrogate the clock transition was measured and corrected for. The frequency of the clock transition at 657 nm was referenced to the caesium fountain clock of PTB utilizing a femtosecond comb generator with a fractional uncertainty of 1.2x10{sup -14}. The transition frequency was determined to be (455 986 240 494 144{+-}5.3) Hz, making the calcium clock transition one of the most accurately known optical transitions. A frequency stability of 3x10{sup -15} at 100 s averaging time was achieved and the noise contributions that limit to the observed stability were analyzed in detail. Additionally, the natural linewidth of the clock transition has been determined.

  6. Accurate spectroscopic characterization of oxirane: A valuable route to its identification in Titan's atmosphere and the assignment of unidentified infrared bands

    SciTech Connect

    Puzzarini, Cristina; Biczysko, Malgorzata; Bloino, Julien; Barone, Vincenzo

    2014-04-20

    In an effort to provide an accurate spectroscopic characterization of oxirane, state-of-the-art computational methods and approaches have been employed to determine highly accurate fundamental vibrational frequencies and rotational parameters. Available experimental data were used to assess the reliability of our computations, and an accuracy on average of 10 cm{sup –1} for fundamental transitions as well as overtones and combination bands has been pointed out. Moving to rotational spectroscopy, relative discrepancies of 0.1%, 2%-3%, and 3%-4% were observed for rotational, quartic, and sextic centrifugal-distortion constants, respectively. We are therefore confident that the highly accurate spectroscopic data provided herein can be useful for identification of oxirane in Titan's atmosphere and the assignment of unidentified infrared bands. Since oxirane was already observed in the interstellar medium and some astronomical objects are characterized by very high D/H ratios, we also considered the accurate determination of the spectroscopic parameters for the mono-deuterated species, oxirane-d1. For the latter, an empirical scaling procedure allowed us to improve our computed data and to provide predictions for rotational transitions with a relative accuracy of about 0.02% (i.e., an uncertainty of about 40 MHz for a transition lying at 200 GHz).

  7. ACCURATE SPECTROSCOPIC CHARACTERIZATION OF OXIRANE: A VALUABLE ROUTE TO ITS IDENTIFICATION IN TITAN’S ATMOSPHERE AND THE ASSIGNMENT OF UNIDENTIFIED INFRARED BANDS

    PubMed Central

    Puzzarini, Cristina; Biczysko, Malgorzata; Bloino, Julien; Barone, Vincenzo

    2015-01-01

    In an effort to provide an accurate spectroscopic characterization of oxirane, state-of-the-art computational methods and approaches have been employed to determine highly accurate fundamental vibrational frequencies and rotational parameters. Available experimental data were used to assess the reliability of our computations, and an accuracy on average of 10 cm−1 for fundamental transitions as well as overtones and combination bands has been pointed out. Moving to rotational spectroscopy, relative discrepancies of 0.1%, 2%–3%, and 3%–4% were observed for rotational, quartic, and sextic centrifugal-distortion constants, respectively. We are therefore confident that the highly accurate spectroscopic data provided herein can be useful for identification of oxirane in Titan’s atmosphere and the assignment of unidentified infrared bands. Since oxirane was already observed in the interstellar medium and some astronomical objects are characterized by very high D/H ratios, we also considered the accurate determination of the spectroscopic parameters for the mono-deuterated species, oxirane-d1. For the latter, an empirical scaling procedure allowed us to improve our computed data and to provide predictions for rotational transitions with a relative accuracy of about 0.02% (i.e., an uncertainty of about 40 MHz for a transition lying at 200 GHz). PMID:26543240

  8. Practical aspects of spatially high accurate methods

    NASA Technical Reports Server (NTRS)

    Godfrey, Andrew G.; Mitchell, Curtis R.; Walters, Robert W.

    1992-01-01

    The computational qualities of high order spatially accurate methods for the finite volume solution of the Euler equations are presented. Two dimensional essentially non-oscillatory (ENO), k-exact, and 'dimension by dimension' ENO reconstruction operators are discussed and compared in terms of reconstruction and solution accuracy, computational cost and oscillatory behavior in supersonic flows with shocks. Inherent steady state convergence difficulties are demonstrated for adaptive stencil algorithms. An exact solution to the heat equation is used to determine reconstruction error, and the computational intensity is reflected in operation counts. Standard MUSCL differencing is included for comparison. Numerical experiments presented include the Ringleb flow for numerical accuracy and a shock reflection problem. A vortex-shock interaction demonstrates the ability of the ENO scheme to excel in simulating unsteady high-frequency flow physics.

  9. Digital varying-frequency generator

    NASA Technical Reports Server (NTRS)

    Allen, M. J.

    1977-01-01

    Generator employs up/down counters, digital-to-analog converters, and integrator to determine frequency and time duration of output. Circuit can be used where varying signal must be controlled accurately over long period of time.

  10. Kinetics of the Reaction of the Heaviest Hydrogen Atom with H2, the 4Heμ + H2 -> 4HeμΗ + H Reaction: Experiments, Accurate Quantal Calculations, and Variational Transition State Theory, including Kinetic Isotope Effects for a Factor of 36.1 in Isotopic Mass

    SciTech Connect

    Fleming, Donald G.; Arseneau, Donald J.; Sukhorukov, Oleksandr; Brewer, Jess H.; Mielke, Steven L.; Truhlar, Donald G.; Schatz, George C.; Garrett, Bruce C.; Peterson, Kirk A.

    2011-11-14

    The neutral muonic helium atom {sup 4}He{mu}, in which one of the electrons of He is replaced by a negative muon, may be effectively regarded as the heaviest isotope of the hydrogen atom, with a mass of 4.115 amu. We report details of the first muon spin rotation ({mu}SR) measurements of the chemical reaction rate constant of {sup 4}He{mu} with molecular hydrogen, {sup 4}He{mu} + H{sub 2} {yields} {sup 4}He{mu}H + H, at temperatures of 295.5, 405, and 500 K, as well as a {mu}SR measurement of the hyperfine coupling constant of muonic He at high pressures. The experimental rate constants, k{sub He{mu}}, are compared with the predictions of accurate quantum mechanical (QM) dynamics calculations carried out on a well converged Born-Huang (BH) potential energy surface, based on complete configuration interaction calculations and including a Born-Oppenheimer diagonal correction. At the two highest measured temperatures the agreement between the quantum theory and experiment is good to excellent, well within experimental uncertainties that include an estimate of possible systematic error, but at 295.5 K the quantum calculations for k{sub He{mu}} are below the experimental value by 2.1 times the experimental uncertainty estimates. Possible reasons for this discrepancy are discussed. Variational transition state theory calculations with multidimensional tunneling have also been carried out for k{sub He{mu}} on the BH surface, and they agree with the accurate QM rate constants to within 30% over a wider temperature range of 200-1000 K. Comparisons between theory and experiment are also presented for the rate constants for both the D + H{sub 2} and Mu + H{sub 2} reactions in a novel study of kinetic isotope effects for the H + H{sub 2} reactions over a factor of 36.1 in isotopic mass of the atomic reactant.

  11. Evaluation of high-frequency mean streamwater transit-time estimates using groundwater age and dissolved silica concentrations in a small forested watershed

    USGS Publications Warehouse

    Peters, Norman E.; Burns, Douglas A.; Aulenbach, Brent T.

    2014-01-01

    Many previous investigations of mean streamwater transit times (MTT) have been limited by an inability to quantify the MTT dynamics. Here, we draw on (1) a linear relation (r 2 = 0.97) between groundwater 3H/3He ages and dissolved silica (Si) concentrations, combined with (2) predicted streamwater Si concentrations from a multiple-regression relation (R 2 = 0.87) to estimate MTT at 5-min intervals for a 23-year time series of streamflow [water year (WY) 1986 through 2008] at the Panola Mountain Research Watershed, Georgia. The time-based average MTT derived from the 5-min data was ~8.4 ± 2.9 years and the volume-weighted (VW) MTT was ~4.7 years for the study period, reflecting the importance of younger runoff water during high flow. The 5-min MTTs are normally distributed and ranged from 0 to 15 years. Monthly VW MTTs averaged 7.0 ± 3.3 years and ranged from 4 to 6 years during winter and 8–10 years during summer. The annual VW MTTs averaged 5.6 ± 2.0 years and ranged from ~5 years during wet years (2003 and 2005) to >10 years during dry years (2002 and 2008). Stormflows are composed of much younger water than baseflows, and although stormflow only occurs ~17 % of the time, this runoff fraction contributed 39 % of the runoff during the 23-year study period. Combining the 23-year VW MTT (including stormflow) with the annual average baseflow for the period (~212 mm) indicates that active groundwater storage is ~1,000 mm. However, the groundwater storage ranged from 1,040 to 1,950 mm using WY baseflow and WY VW MTT. The approach described herein may be applicable to other watersheds underlain by granitoid bedrock, where weathering is the dominant control on Si concentrations in soils, groundwater, and streamwater.

  12. Frequency curves

    USGS Publications Warehouse

    Riggs, H.C.

    1968-01-01

    This manual describes graphical and mathematical procedures for preparing frequency curves from samples of hydrologic data. It also discusses the theory of frequency curves, compares advantages of graphical and mathematical fitting, suggests methods of describing graphically defined frequency curves analytically, and emphasizes the correct interpretations of a frequency curve.

  13. Encoding voice fundamental frequency into vibrotactile frequency.

    PubMed

    Rothenberg, M; Molitor, R D

    1979-10-01

    Measured in this study was the ability of eight hearing and five deaf subjects to identify the stress pattern in a short sentence from the variation in voice fundamental frequency (F0), when presented aurally (for hearing subjects) and when transformed into vibrotactile pulse frequency. Various transformations from F0 to pulse frequency were tested in an attempt to determine an optimum transformation, the amount of F0 information that could be transmitted, and what the limitations in the tactile channel might be. The results indicated that a one- or two-octave reduction of F0 vibrotactile frequency (transmitting every second or third glottal pulse) might result in a significant ability to discriminate the intonation patterns associated with moderate-to-strong patterns of sentence stress in English. However, accurate reception of the details of the intonation pattern may require a slower than normal pronounciation because of an apparent temporal indeterminacy of about 200 ms in the perception of variations in vibrotactile frequency. A performance deficit noted for the two prelingually, profoundly deaf subjects with marginally discriminable encodings offers some support for our previous hypothesis that there is a natural association between auditory pitch and perceived vibrotactile frequency. PMID:159917

  14. Predict amine solution properties accurately

    SciTech Connect

    Cheng, S.; Meisen, A.; Chakma, A.

    1996-02-01

    Improved process design begins with using accurate physical property data. Especially in the preliminary design stage, physical property data such as density viscosity, thermal conductivity and specific heat can affect the overall performance of absorbers, heat exchangers, reboilers and pump. These properties can also influence temperature profiles in heat transfer equipment and thus control or affect the rate of amine breakdown. Aqueous-amine solution physical property data are available in graphical form. However, it is not convenient to use with computer-based calculations. Developed equations allow improved correlations of derived physical property estimates with published data. Expressions are given which can be used to estimate physical properties of methyldiethanolamine (MDEA), monoethanolamine (MEA) and diglycolamine (DGA) solutions.

  15. Accurate thickness measurement of graphene

    NASA Astrophysics Data System (ADS)

    Shearer, Cameron J.; Slattery, Ashley D.; Stapleton, Andrew J.; Shapter, Joseph G.; Gibson, Christopher T.

    2016-03-01

    Graphene has emerged as a material with a vast variety of applications. The electronic, optical and mechanical properties of graphene are strongly influenced by the number of layers present in a sample. As a result, the dimensional characterization of graphene films is crucial, especially with the continued development of new synthesis methods and applications. A number of techniques exist to determine the thickness of graphene films including optical contrast, Raman scattering and scanning probe microscopy techniques. Atomic force microscopy (AFM), in particular, is used extensively since it provides three-dimensional images that enable the measurement of the lateral dimensions of graphene films as well as the thickness, and by extension the number of layers present. However, in the literature AFM has proven to be inaccurate with a wide range of measured values for single layer graphene thickness reported (between 0.4 and 1.7 nm). This discrepancy has been attributed to tip-surface interactions, image feedback settings and surface chemistry. In this work, we use standard and carbon nanotube modified AFM probes and a relatively new AFM imaging mode known as PeakForce tapping mode to establish a protocol that will allow users to accurately determine the thickness of graphene films. In particular, the error in measuring the first layer is reduced from 0.1-1.3 nm to 0.1-0.3 nm. Furthermore, in the process we establish that the graphene-substrate adsorbate layer and imaging force, in particular the pressure the tip exerts on the surface, are crucial components in the accurate measurement of graphene using AFM. These findings can be applied to other 2D materials.

  16. Virus mutation frequencies can be greatly underestimated by monoclonal antibody neutralization of virions.

    PubMed Central

    Holland, J J; de la Torre, J C; Steinhauer, D A; Clarke, D; Duarte, E; Domingo, E

    1989-01-01

    Monoclonal antibody-resistant mutants have been widely used to estimate virus mutation frequencies. We demonstrate that standard virion neutralization inevitably underestimates monoclonal antibody-resistant mutant genome frequencies of vesicular stomatitis virus, due to phenotypic masking-mixing when wild-type (wt) virions are present in thousandsfold greater numbers. We show that incorporation of antibody into the plaque overlay medium (after virus penetration at 37 degrees C) can provide accurate estimates of genome frequencies of neutral monoclonal antibody-resistant mutant viruses in wt clones. By using this method, we have observed two adjacent G----A base transition frequencies in the I3 epitope to be of the order of 10(-4) in a wt glycine codon. This appears to be slightly lower than the frequencies observed at other sites for total (viable and nonviable) virus genomes when using a direct sequence approach. Images PMID:2479770

  17. Towards an accurate bioimpedance identification

    NASA Astrophysics Data System (ADS)

    Sanchez, B.; Louarroudi, E.; Bragos, R.; Pintelon, R.

    2013-04-01

    This paper describes the local polynomial method (LPM) for estimating the time-invariant bioimpedance frequency response function (FRF) considering both the output-error (OE) and the errors-in-variables (EIV) identification framework and compare it with the traditional cross— and autocorrelation spectral analysis techniques. The bioimpedance FRF is measured with the multisine electrical impedance spectroscopy (EIS) technique. To show the overwhelming accuracy of the LPM approach, both the LPM and the classical cross— and autocorrelation spectral analysis technique are evaluated through the same experimental data coming from a nonsteady-state measurement of time-varying in vivo myocardial tissue. The estimated error sources at the measurement frequencies due to noise, σnZ, and the stochastic nonlinear distortions, σZNL, have been converted to Ω and plotted over the bioimpedance spectrum for each framework. Ultimately, the impedance spectra have been fitted to a Cole impedance model using both an unweighted and a weighted complex nonlinear least square (CNLS) algorithm. A table is provided with the relative standard errors on the estimated parameters to reveal the importance of which system identification frameworks should be used.

  18. Impedance Scaling for Small Angle Transitions

    SciTech Connect

    Stupakov, G.; Bane, Karl; Zagorodnov, I.; /DESY

    2010-10-27

    Based on the parabolic equation approach to Maxwell's equations we have derived scaling properties of the high frequency impedance/short bunch wakefields of structures. For the special case of small angle transitions we have shown the scaling properties are valid for all frequencies. Using these scaling properties one can greatly reduce the calculation time of the wakefield/impedance of long, small angle, beam pipe transitions, like one often finds in insertion regions of storage rings. We have tested the scaling with wakefield simulations of 2D and 3D models of such transitions, and found that the scaling works well. In modern ring-based light sources one often finds insertion devices having extremely small vertical apertures (on the order of millimeters) to allow for maximal undulator fields reaching the beam. Such insertion devices require that there be beam pipe transitions from these small apertures to the larger cross-sections (normally on the order of centimeters) found in the rest of the ring. The fact that there may be many such transitions, and that these transitions introduce beam pipe discontinuities very close to the beam path, means that their impedance will be large and, in fact, may dominate the impedance budget of the entire ring. To reduce their impact on impedance, the transitions are normally tapered gradually over a long distance. The accurate calculation of the impedance or wakefield of these long transitions, which are typically 3D objects (i.e. they do not have cylindrical symmetry), can be quite a challenging numerical task. In this report we present a method of obtaining the impedance of a long, small angle transition from the calculation of a scaled, shorter one. Normally, the actual calculation is obtained from a time domain simulation of the wakefield in the structure, where the impedance can be obtained by performing a Fourier transform. We shall see that the scaled calculation reduces the computer time and memory requirements

  19. Gravitationally induced quantum transitions

    NASA Astrophysics Data System (ADS)

    Landry, A.; Paranjape, M. B.

    2016-06-01

    In this paper, we calculate the probability for resonantly inducing transitions in quantum states due to time-dependent gravitational perturbations. Contrary to common wisdom, the probability of inducing transitions is not infinitesimally small. We consider a system of ultracold neutrons, which are organized according to the energy levels of the Schrödinger equation in the presence of the Earth's gravitational field. Transitions between energy levels are induced by an oscillating driving force of frequency ω . The driving force is created by oscillating a macroscopic mass in the neighborhood of the system of neutrons. The neutron lifetime is approximately 880 sec while the probability of transitions increases as t2. Hence, the optimal strategy is to drive the system for two lifetimes. The transition amplitude then is of the order of 1.06 ×10-5, and hence with a million ultracold neutrons, one should be able to observe transitions.

  20. Accurate ab Initio Spin Densities

    PubMed Central

    2012-01-01

    We present an approach for the calculation of spin density distributions for molecules that require very large active spaces for a qualitatively correct description of their electronic structure. Our approach is based on the density-matrix renormalization group (DMRG) algorithm to calculate the spin density matrix elements as a basic quantity for the spatially resolved spin density distribution. The spin density matrix elements are directly determined from the second-quantized elementary operators optimized by the DMRG algorithm. As an analytic convergence criterion for the spin density distribution, we employ our recently developed sampling-reconstruction scheme [J. Chem. Phys.2011, 134, 224101] to build an accurate complete-active-space configuration-interaction (CASCI) wave function from the optimized matrix product states. The spin density matrix elements can then also be determined as an expectation value employing the reconstructed wave function expansion. Furthermore, the explicit reconstruction of a CASCI-type wave function provides insight into chemically interesting features of the molecule under study such as the distribution of α and β electrons in terms of Slater determinants, CI coefficients, and natural orbitals. The methodology is applied to an iron nitrosyl complex which we have identified as a challenging system for standard approaches [J. Chem. Theory Comput.2011, 7, 2740]. PMID:22707921

  1. Hyperfine structure and isotope shifts of transitions in neutral and singly ionized ytterbium

    NASA Technical Reports Server (NTRS)

    Berends, R. W.; Maleki, L.

    1992-01-01

    The present experimental investigation of the hyperfine structure and isotopic shifts of transitions in neutral and singly-ionized Yb, which constitute a system of some interest to microwave-frequency standards, used counterpropagating pump and probe laser beams directed through a hollow-cathode discharge lamp. The results obtained are in agreement with previous measurements except in the case of the Yb-173(+) 6 2P0 sub 3/2 state, which is more accurately determined.

  2. Transition Planning

    ERIC Educational Resources Information Center

    Statfeld, Jenna L.

    2011-01-01

    Post-school transition is the movement of a child with disabilities from school to activities that occur after the completion of school. This paper provides information about: (1) post-school transition; (2) transition plan; (3) transition services; (4) transition planning; (5) vocational rehabilitation services; (6) services that are available…

  3. Frequency Combs

    NASA Astrophysics Data System (ADS)

    Hänsch, Theodor W.; Picqué, Nathalie

    Much of modern research in the field of atomic, molecular, and optical science relies on lasers, which were invented some 50 years ago and perfected in five decades of intense research and development. Today, lasers and photonic technologies impact most fields of science and they have become indispensible in our daily lives. Laser frequency combs were conceived a decade ago as tools for the precision spectroscopy of atomic hydrogen. Through the development of optical frequency comb techniques, technique a setup of the size 1 ×1 m2, good for precision measurements of any frequency, and even commercially available, has replaced the elaborate previous frequency-chain schemes for optical frequency measurements, which only worked for selected frequencies. A true revolution in optical frequency measurements has occurred, paving the way for the creation of all-optical clocks clock with a precision that might approach 10-18. A decade later, frequency combs are now common equipment in all frequency metrology-oriented laboratories. They are also becoming enabling tools for an increasing number of applications, from the calibration of astronomical spectrographs to molecular spectroscopy. This chapter first describes the principle of an optical frequency comb synthesizer. Some of the key technologies to generate such a frequency comb are then presented. Finally, a non-exhaustive overview of the growing applications is given.

  4. Accurate parameter estimation for unbalanced three-phase system.

    PubMed

    Chen, Yuan; So, Hing Cheung

    2014-01-01

    Smart grid is an intelligent power generation and control console in modern electricity networks, where the unbalanced three-phase power system is the commonly used model. Here, parameter estimation for this system is addressed. After converting the three-phase waveforms into a pair of orthogonal signals via the α β-transformation, the nonlinear least squares (NLS) estimator is developed for accurately finding the frequency, phase, and voltage parameters. The estimator is realized by the Newton-Raphson scheme, whose global convergence is studied in this paper. Computer simulations show that the mean square error performance of NLS method can attain the Cramér-Rao lower bound. Moreover, our proposal provides more accurate frequency estimation when compared with the complex least mean square (CLMS) and augmented CLMS. PMID:25162056

  5. Note-accurate audio segmentation based on MPEG-7

    NASA Astrophysics Data System (ADS)

    Wellhausen, Jens

    2003-12-01

    Segmenting audio data into the smallest musical components is the basis for many further meta data extraction algorithms. For example, an automatic music transcription system needs to know where the exact boundaries of each tone are. In this paper a note accurate audio segmentation algorithm based on MPEG-7 low level descriptors is introduced. For a reliable detection of different notes, both features in the time and the frequency domain are used. Because of this, polyphonic instrument mixes and even melodies characterized by human voices can be examined with this alogrithm. For testing and verification of the note accurate segmentation, a simple music transcription system was implemented. The dominant frequency within each segment is used to build a MIDI file representing the processed audio data.

  6. Universal MOSFET gate impedance model for 200 MHz-20 GHz frequency range

    NASA Astrophysics Data System (ADS)

    Bandi, Sri Priya R.; Washburn, Clyde; Mukund, P. R.; Kolnik, Jan; Paradis, Ken; Howard, Steve; Burleson, Jeff

    2006-07-01

    The scaling of CMOS technology to 100 nm and below and the endless pursuit of higher operating frequencies drives the need to accurately model effects such as gate leakage and the deterioration of transport characteristics that dominate at those feature sizes and frequencies. Current modeling techniques are frequency limited and require different models for different frequency ranges in order to achieve accuracy goals. In the foundry world, high frequency models are typically empirical in nature and significantly lag their low frequency counterparts in terms of availability. This tends to slow the adoption of new foundry technologies for high performance applications such as extremely high data rate serializer/deserializer (SERDES) transceiver cores. However, design cycle time and time to market while transitioning between technology nodes can be reduced by incorporating a re-usable, industry-standard model. This work proposes such a model for device gate impedance that is simulator-friendly, compact, frequency-independent, and relatively portable across technology nodes. This semi-empirical gate impedance model is based on depletion in the poly-silicon gate electrode. The model performs accurately over 200 MHz-20 GHz at different bias conditions and widths and has been verified by measured data in three technology nodes. The model and model parameter behavior are consistent across technology nodes thereby enabling re-usability and portability.

  7. Differential equation based method for accurate approximations in optimization

    NASA Technical Reports Server (NTRS)

    Pritchard, Jocelyn I.; Adelman, Howard M.

    1990-01-01

    A method to efficiently and accurately approximate the effect of design changes on structural response is described. The key to this method is to interpret sensitivity equations as differential equations that may be solved explicitly for closed form approximations, hence, the method is denoted the Differential Equation Based (DEB) method. Approximations were developed for vibration frequencies, mode shapes and static displacements. The DEB approximation method was applied to a cantilever beam and results compared with the commonly-used linear Taylor series approximations and exact solutions. The test calculations involved perturbing the height, width, cross-sectional area, tip mass, and bending inertia of the beam. The DEB method proved to be very accurate, and in most cases, was more accurate than the linear Taylor series approximation. The method is applicable to simultaneous perturbation of several design variables. Also, the approximations may be used to calculate other system response quantities. For example, the approximations for displacements are used to approximate bending stresses.

  8. 38 CFR 4.46 - Accurate measurement.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2013-07-01 2013-07-01 false Accurate measurement. 4... RATING DISABILITIES Disability Ratings The Musculoskeletal System § 4.46 Accurate measurement. Accurate measurement of the length of stumps, excursion of joints, dimensions and location of scars with respect...

  9. 38 CFR 4.46 - Accurate measurement.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2010-07-01 2010-07-01 false Accurate measurement. 4... RATING DISABILITIES Disability Ratings The Musculoskeletal System § 4.46 Accurate measurement. Accurate measurement of the length of stumps, excursion of joints, dimensions and location of scars with respect...

  10. 38 CFR 4.46 - Accurate measurement.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2011-07-01 2011-07-01 false Accurate measurement. 4... RATING DISABILITIES Disability Ratings The Musculoskeletal System § 4.46 Accurate measurement. Accurate measurement of the length of stumps, excursion of joints, dimensions and location of scars with respect...

  11. 38 CFR 4.46 - Accurate measurement.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2014-07-01 2014-07-01 false Accurate measurement. 4... RATING DISABILITIES Disability Ratings The Musculoskeletal System § 4.46 Accurate measurement. Accurate measurement of the length of stumps, excursion of joints, dimensions and location of scars with respect...

  12. 38 CFR 4.46 - Accurate measurement.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 38 Pensions, Bonuses, and Veterans' Relief 1 2012-07-01 2012-07-01 false Accurate measurement. 4... RATING DISABILITIES Disability Ratings The Musculoskeletal System § 4.46 Accurate measurement. Accurate measurement of the length of stumps, excursion of joints, dimensions and location of scars with respect...

  13. Towards the computations of accurate spectroscopic parameters and vibrational spectra for organic compounds

    NASA Astrophysics Data System (ADS)

    Hochlaf, M.; Puzzarini, C.; Senent, M. L.

    2015-07-01

    We present multi-component computations for rotational constants, vibrational and torsional levels of medium-sized molecules. Through the treatment of two organic sulphur molecules, ethyl mercaptan and dimethyl sulphide, which are relevant for atmospheric and astrophysical media, we point out the outstanding capabilities of explicitly correlated coupled clusters (CCSD(T)-F12) method in conjunction with the cc-pVTZ-F12 basis set for the accurate predictions of such quantities. Indeed, we show that the CCSD(T)-F12/cc-pVTZ-F12 equilibrium rotational constants are in good agreement with those obtained by means of a composite scheme based on CCSD(T) calculations that accounts for the extrapolation to the complete basis set (CBS) limit and core-correlation effects [CCSD(T)/CBS+CV], thus leading to values of ground-state rotational constants rather close to the corresponding experimental data. For vibrational and torsional levels, our analysis reveals that the anharmonic frequencies derived from CCSD(T)-F12/cc-pVTZ-F12 harmonic frequencies and anharmonic corrections (Δν = ω - ν) at the CCSD/cc-pVTZ level closely agree with experimental results. The pattern of the torsional transitions and the shape of the potential energy surfaces along the torsional modes are also well reproduced using the CCSD(T)-F12/cc-pVTZ-F12 energies. Interestingly, this good accuracy is accompanied with a strong reduction of the computational costs. This makes the procedures proposed here as schemes of choice for effective and accurate prediction of spectroscopic properties of organic compounds. Finally, popular density functional approaches are compared with the coupled cluster (CC) methodologies in torsional studies. The long-range CAM-B3LYP functional of Handy and co-workers is recommended for large systems.

  14. Blackbody radiation shift in the {sup 87}Rb frequency standard

    SciTech Connect

    Safronova, M. S.; Jiang Dansha; Safronova, U. I.

    2010-08-15

    The operation of atomic clocks is generally carried out at room temperature, whereas the definition of the second refers to the clock transition in an atom at absolute zero. This implies that the clock transition frequency should be corrected in practice for the effect of finite temperature, of which the leading contributor is the blackbody radiation (BBR) shift. Experimental measurements of the BBR shifts are difficult. In this work, we have calculated the blackbody radiation shift of the ground-state hyperfine microwave transition in {sup 87}Rb using the relativistic all-order method and carried out a detailed evaluation of the accuracy of our final value. Particular care is taken to accurately account for the contributions from highly excited states. Our predicted value for the Stark coefficient, k{sub S}=-1.240(4)x10{sup -10} Hz/(V/m){sup 2}, is three times more accurate than the previous calculation [E. J. Angstman, V. A. Dzuba, and V. V. Flambaum, Phys. Rev. A 74, 023405 (2006)].

  15. Accurate Optical Lattice Clock with {sup 87}Sr Atoms

    SciTech Connect

    Le Targat, Rodolphe; Baillard, Xavier; Fouche, Mathilde; Brusch, Anders; Tcherbakoff, Olivier; Rovera, Giovanni D.; Lemonde, Pierre

    2006-09-29

    We report a frequency measurement of the {sup 1}S{sub 0}-{sup 3}P{sub 0} transition of {sup 87}Sr atoms in an optical lattice clock. The frequency is determined to be 429 228 004 229 879(5) Hz with a fractional uncertainty that is comparable to state-of-the-art optical clocks with neutral atoms in free fall. The two previous measurements of this transition were found to disagree by about 2x10{sup -13}, i.e., almost 4 times the combined error bar and 4 to 5 orders of magnitude larger than the claimed ultimate accuracy of this new type of clocks. Our measurement is in agreement with one of these two values and essentially resolves this discrepancy.

  16. Accurate orbit propagation with planetary close encounters

    NASA Astrophysics Data System (ADS)

    Baù, Giulio; Milani Comparetti, Andrea; Guerra, Francesca

    2015-08-01

    We tackle the problem of accurately propagating the motion of those small bodies that undergo close approaches with a planet. The literature is lacking on this topic and the reliability of the numerical results is not sufficiently discussed. The high-frequency components of the perturbation generated by a close encounter makes the propagation particularly challenging both from the point of view of the dynamical stability of the formulation and the numerical stability of the integrator. In our approach a fixed step-size and order multistep integrator is combined with a regularized formulation of the perturbed two-body problem. When the propagated object enters the region of influence of a celestial body, the latter becomes the new primary body of attraction. Moreover, the formulation and the step-size will also be changed if necessary. We present: 1) the restarter procedure applied to the multistep integrator whenever the primary body is changed; 2) new analytical formulae for setting the step-size (given the order of the multistep, formulation and initial osculating orbit) in order to control the accumulation of the local truncation error and guarantee the numerical stability during the propagation; 3) a new definition of the region of influence in the phase space. We test the propagator with some real asteroids subject to the gravitational attraction of the planets, the Yarkovsky and relativistic perturbations. Our goal is to show that the proposed approach improves the performance of both the propagator implemented in the OrbFit software package (which is currently used by the NEODyS service) and of the propagator represented by a variable step-size and order multistep method combined with Cowell's formulation (i.e. direct integration of position and velocity in either the physical or a fictitious time).

  17. Efficient Geometric Probabilities of Multi-Transiting Exoplanetary Systems from CORBITS

    NASA Astrophysics Data System (ADS)

    Brakensiek, Joshua; Ragozzine, Darin

    2016-04-01

    NASA’s Kepler Space Telescope has successfully discovered thousands of exoplanet candidates using the transit method, including hundreds of stars with multiple transiting planets. In order to estimate the frequency of these valuable systems, it is essential to account for the unique geometric probabilities of detecting multiple transiting extrasolar planets around the same parent star. In order to improve on previous studies that used numerical methods, we have constructed an efficient, semi-analytical algorithm called the Computed Occurrence of Revolving Bodies for the Investigation of Transiting Systems (CORBITS), which, given a collection of conjectured exoplanets orbiting a star, computes the probability that any particular group of exoplanets can be observed to transit. The algorithm applies theorems of elementary differential geometry to compute the areas bounded by circular curves on the surface of a sphere. The implemented algorithm is more accurate and orders of magnitude faster than previous algorithms, based on comparisons with Monte Carlo simulations. We use CORBITS to show that the present solar system would only show a maximum of three transiting planets, but that this varies over time due to dynamical evolution. We also used CORBITS to geometrically debias the period ratio and mutual Hill sphere distributions of Kepler's multi-transiting planet candidates, which results in shifting these distributions toward slightly larger values. In an Appendix, we present additional semi-analytical methods for determining the frequency of exoplanet mutual events, i.e., the geometric probability that two planets will transit each other (planet–planet occultation, relevant to transiting circumbinary planets) and the probability that this transit occurs simultaneously as they transit their star. The CORBITS algorithms and several worked examples are publicly available.

  18. Mapping the QCD Phase Transition with Accreting Compact Stars

    SciTech Connect

    Blaschke, D.; Poghosyan, G.; Grigorian, H.

    2008-10-29

    We discuss an idea for how accreting millisecond pulsars could contribute to the understanding of the QCD phase transition in the high-density nuclear matter equation of state (EoS). It is based on two ingredients, the first one being a ''phase diagram'' of rapidly rotating compact star configurations in the plane of spin frequency and mass, determined with state-of-the-art hybrid equations of state, allowing for a transition to color superconducting quark matter. The second is the study of spin-up and accretion evolution in this phase diagram. We show that the quark matter phase transition leads to a characteristic line in the {omega}-M plane, the phase border between neutron stars and hybrid stars with a quark matter core. Along this line a drop in the pulsar's moment of inertia entails a waiting point phenomenon in the accreting millisecond pulsar (AMXP) evolution: most of these objects should therefore be found along the phase border in the {omega}-M plane, which may be viewed as the AMXP analog of the main sequence in the Hertzsprung-Russell diagram for normal stars. In order to prove the existence of a high-density phase transition in the cores of compact stars we need population statistics for AMXPs with sufficiently accurate determination of their masses, spin frequencies and magnetic fields.

  19. Moons over Jupiter: transits and shadow transits

    NASA Astrophysics Data System (ADS)

    Rogers, J. H.; et al.

    2003-06-01

    There is no more beautiful illustration of orbital motions than the movements of Jupiter's satellites. Every six years, their movements are most strikingly displayed, when the jovian system is presented edge-on to Earth. This means that there is a higher frequency of multiple transits over the face of the planet, as all the moons transit across the equatorial zone, whereas in other years Ganymede and Callisto transit near the poles or not at all. Also, for a few months, the satellites pass in front of each other, displaying mutual eclipses and occultations. In 2002/2003 we have been able to observe a fine series of these multiple and mutual events. On the cover, and on these pages, are some of the highest-resolution images received.

  20. Benchmarking accurate spectral phase retrieval of single attosecond pulses

    NASA Astrophysics Data System (ADS)

    Wei, Hui; Le, Anh-Thu; Morishita, Toru; Yu, Chao; Lin, C. D.

    2015-02-01

    A single extreme-ultraviolet (XUV) attosecond pulse or pulse train in the time domain is fully characterized if its spectral amplitude and phase are both determined. The spectral amplitude can be easily obtained from photoionization of simple atoms where accurate photoionization cross sections have been measured from, e.g., synchrotron radiations. To determine the spectral phase, at present the standard method is to carry out XUV photoionization in the presence of a dressing infrared (IR) laser. In this work, we examine the accuracy of current phase retrieval methods (PROOF and iPROOF) where the dressing IR is relatively weak such that photoelectron spectra can be accurately calculated by second-order perturbation theory. We suggest a modified method named swPROOF (scattering wave phase retrieval by omega oscillation filtering) which utilizes accurate one-photon and two-photon dipole transition matrix elements and removes the approximations made in PROOF and iPROOF. We show that the swPROOF method can in general retrieve accurate spectral phase compared to other simpler models that have been suggested. We benchmark the accuracy of these phase retrieval methods through simulating the spectrogram by solving the time-dependent Schrödinger equation numerically using several known single attosecond pulses with a fixed spectral amplitude but different spectral phases.

  1. CC/DFT Route toward Accurate Structures and Spectroscopic Features for Observed and Elusive Conformers of Flexible Molecules: Pyruvic Acid as a Case Study.

    PubMed

    Barone, Vincenzo; Biczysko, Malgorzata; Bloino, Julien; Cimino, Paola; Penocchio, Emanuele; Puzzarini, Cristina

    2015-09-01

    The structures and relative stabilities as well as the rotational and vibrational spectra of the three low-energy conformers of pyruvic acid (PA) have been characterized using a state-of-the-art quantum-mechanical approach designed for flexible molecules. By making use of the available experimental rotational constants for several isotopologues of the most stable PA conformer, Tc-PA, the semiexperimental equilibrium structure has been derived. The latter provides a reference for the pure theoretical determination of the equilibrium geometries for all conformers, thus confirming for these structures an accuracy of 0.001 Å and 0.1 deg for bond lengths and angles, respectively. Highly accurate relative energies of all conformers (Tc-, Tt-, and Ct-PA) and of the transition states connecting them are provided along with the thermodynamic properties at low and high temperatures, thus leading to conformational enthalpies accurate to 1 kJ mol(-1). Concerning microwave spectroscopy, rotational constants accurate to about 20 MHz are provided for the Tt- and Ct-PA conformers, together with the computed centrifugal-distortion constants and dipole moments required to simulate their rotational spectra. For Ct-PA, vibrational frequencies in the mid-infrared region accurate to 10 cm(-1) are reported along with theoretical estimates for the transitions in the near-infrared range, and the corresponding infrared spectrum including fundamental transitions, overtones, and combination bands has been simulated. In addition to the new data described above, theoretical results for the Tc- and Tt-PA conformers are compared with all available experimental data to further confirm the accuracy of the hybrid coupled-cluster/density functional theory (CC/DFT) protocol applied in the present study. Finally, we discuss in detail the accuracy of computational models fully based on double-hybrid DFT functionals (mainly at the B2PLYP/aug-cc-pVTZ level) that avoid the use of very expensive CC

  2. Frequency scanning interferometry with nanometer precision using a vertical-cavity surface-emitting laser diode under scanning speed control

    NASA Astrophysics Data System (ADS)

    Kakuma, Seiichi

    2015-12-01

    Frequency scanning interferometry technique with a nanometer precision using a vertical-cavity surface-emitting laser diode (VCSEL) is presented. Since the frequency scanning of the VCSEL is linearized by the phase-locked-loop technique, the gradient of the interference fringe order can be precisely determined using linear least squares fitting. This enables a length measurement with a precision better than a quarter wavelength, and the absolute fringe number including the integer part at the atomic transition spectrum (rubidium-D2 line) is accurately determined. The validity of the method is demonstrated by excellent results of block gauge measurement with a root mean square error better than 5 nm.

  3. Accurate energy levels for singly ionized platinum (Pt II)

    NASA Technical Reports Server (NTRS)

    Reader, Joseph; Acquista, Nicolo; Sansonetti, Craig J.; Engleman, Rolf, Jr.

    1988-01-01

    New observations of the spectrum of Pt II have been made with hollow-cathode lamps. The region from 1032 to 4101 A was observed photographically with a 10.7-m normal-incidence spectrograph. The region from 2245 to 5223 A was observed with a Fourier-transform spectrometer. Wavelength measurements were made for 558 lines. The uncertainties vary from 0.0005 to 0.004 A. From these measurements and three parity-forbidden transitions in the infrared, accurate values were determined for 28 even and 72 odd energy levels of Pt II.

  4. Extracting transition rates from zero-polarizability spectroscopy

    NASA Astrophysics Data System (ADS)

    Zuhrianda, Zuhrianda; Safronova, Marianna S.; Safronova, Ulyana I.; Clark, Charles W.

    2016-05-01

    Accurate knowledge of atomic properties has been critical for the design and interpretation of experiments, quantifying and reducing uncertainties and decoherence, and development of concepts for next-generation experiments and precision measurement techniques. We predict a sequence of magic-zero wavelengths for which ac Stark shift vanishes for the Sr excited 5 s 5p3P0 state, and provide a general roadmap for extracting transition matrix elements using precise frequency measurements. We demonstrate that such measurements can serve as a best global benchmark of the spectroscopic accuracy that is required for the development of high-precision predictive methods. These magic-zero wavelengths are also needed for state-selective atom manipulation for implementation of quantum logic operations. We also identify five magic wavelengths of the 5s21S0 - 5 s 5 p3P0 Sr clock transition between 350 nm and 500 nm which can also serve as precision benchmarks.

  5. FTS Studies of the 17O Enriched Isotopologues of CO_2 Toward Creating a Complete and Highly Accurate Reference Standard

    NASA Astrophysics Data System (ADS)

    Elliott, Ben; Sung, Keeyoon; Brown, Linda; Miller, Charles

    2014-06-01

    The proliferation and increased abilities of remote sensing missions for the monitoring of planetary atmospheric gas species has spurred the need for complete and accurate spectroscopic reference standards. As a part of our ongoing effort toward creating a global carbon dioxide (CO2) frequency reference standard, we report new FTS measurements of the 17O enriched isotopologues of CO2. The first measurements were taken in the ν3 region (2200 - 2450 cm-1, 65 - 75 THz), have absolute calibration accuracies of 100 kHz (3E-6 cm-1), comparable to the uncertainties for typical sub-millimeter/THz spectroscopy. Such high absolute calibration accuracy has become regular procedure for the cases of linear molecules such as CO2 and CO for FTS measurements at JPL, and enables us to produce measured transition frequencies for entire bands with accuracies that rival those of early heterodyne measurements for individual beat notes. Additionally, by acquiring spectra of multiple carbon dioxide isotopologues simultaneously, we have begun to construct a self-consistent frequency grid based on CO2 that extends from 20 - 200 THz. These new spectroscopic reference standards are a significant step towards minimizing CO2 retrieval errors from remote sensing applications, especially those involving targets with predominantly CO2 atmospheres such as Mars, Venus and candidate terrestrial exoplanets where minor isotopologues will make significant contributions to the radiance signals.

  6. The IUPAC Database of Rotational-Vibrational Energy Levels and Transitions of Water Isotopologues from Experiment and Theory

    NASA Astrophysics Data System (ADS)

    Császár, Attila G.; Furtenbacher, T.; Tennyson, Jonathan; Bernath, Peter F.; Brown, Linda R.; Campargue, Alain; Daumont, Ludovic; Gamache, Robert R.; Hodges, Joseph T.; Naumenko, Olga V.; Polyansky, Oleg L.; Rothman, Laurence S.; Vandaele, Ann Carine; Zobov, Nikolai F.

    2014-06-01

    The results of an IUPAC Task Group formed in 2004 on "A Database of Water Transitions from Experiment and Theory" (Project No. 2004-035-1-100) are presented. Energy levels and recommended labels involving exact and approximate quantum numbers for the main isotopologues of water in the gas phase, H216O, H218O, H217O, HD16O, HD18O, HD17O, D216O, D218O, and D217O, are determined from measured transition wavenumbers. The transition wavenumbers and energy levels are validated using the MARVEL (measured active rotational-vibrational energy levels) approach and first-principles nuclear motion computations. The extensive data, e.g., more than 200,000 transitions have been handled for H216O, including lines and levels that are required for analysis and synthesis of spectra, thermochemical applications, the construction of theoretical models, and the removal of spectral contamination by ubiquitous water lines. These datasets can also be used to assess where measurements are lacking for each isotopologue and to provide accurate frequencies for many yet-to-be measured transitions. The lack of high-quality frequency calibration standards in the near infrared is identified as an issue that has hindered the determination of high-accuracy energy levels at higher frequencies. The generation of spectra using the MARVEL energy levels combined with transition intensities computed using high accuracy ab initio dipole moment surfaces are discussed.

  7. Influence of modulation frequency in rubidium cell frequency standards

    NASA Technical Reports Server (NTRS)

    Audoin, C.; Viennet, J.; Cyr, N.; Vanier, J.

    1983-01-01

    The error signal which is used to control the frequency of the quartz crystal oscillator of a passive rubidium cell frequency standard is considered. The value of the slope of this signal, for an interrogation frequency close to the atomic transition frequency is calculated and measured for various phase (or frequency) modulation waveforms, and for several values of the modulation frequency. A theoretical analysis is made using a model which applies to a system in which the optical pumping rate, the relaxation rates and the RF field are homogeneous. Results are given for sine-wave phase modulation, square-wave frequency modulation and square-wave phase modulation. The influence of the modulation frequency on the slope of the error signal is specified. It is shown that the modulation frequency can be chosen as large as twice the non-saturated full-width at half-maximum without a drastic loss of the sensitivity to an offset of the interrogation frequency from center line, provided that the power saturation factor and the amplitude of modulation are properly adjusted.

  8. Continuous, Multielement, Hot-Film Transition Gage

    NASA Technical Reports Server (NTRS)

    Holmes, B.; Mcpherson, J.; Harris, F.; Diamond, J.; Johnson, N.; Chapman, J.

    1986-01-01

    Accurate measurement of location where laminar boundary layer undergoes transition to turbulent one serves many purposes in basic aero-dynamic research and developmental testing. Individual gages must be staggered to prevent formation of turbulence at gages downstream. This arrangement precludes accurate measurements of laminar/turbulent transition regions along streamline. Complete understanding of performance, stability, and control of laminar-flow airplane requires knowledge of transition locations on wing surface, empennage surfaces, fuselage, and nacelles. Visual, acoustic, and electronic methods capable of providing this transition information.

  9. Frequency-wavelength calculator with table of dielectric properties

    NASA Technical Reports Server (NTRS)

    Thompson, L. L.

    1972-01-01

    Frequency-wavelength calculator has been developed which rapidly and accurately calculates wavelength of given frequency in specific dielectric material. Unit fits into shirt pocket and includes table of dielectric properties and one-step calculator.

  10. Detection and accurate localization of harmonic chipless tags

    NASA Astrophysics Data System (ADS)

    Dardari, Davide

    2015-12-01

    We investigate the detection and localization properties of harmonic tags working at microwave frequencies. A two-tone interrogation signal and a dedicated signal processing scheme at the receiver are proposed to eliminate phase ambiguities caused by the short signal wavelength and to provide accurate distance/position estimation even in the presence of clutter and multipath. The theoretical limits on tag detection and localization accuracy are investigated starting from a concise characterization of harmonic backscattered signals. Numerical results show that accuracies in the order of centimeters are feasible within an operational range of a few meters in the RFID UHF band.

  11. Accurate potential energy, dipole moment curves, and lifetimes of vibrational states of heteronuclear alkali dimers

    SciTech Connect

    Fedorov, Dmitry A.; Varganov, Sergey A.; Derevianko, Andrei

    2014-05-14

    We calculate the potential energy curves, the permanent dipole moment curves, and the lifetimes of the ground and excited vibrational states of the heteronuclear alkali dimers XY (X, Y = Li, Na, K, Rb, Cs) in the X{sup 1}Σ{sup +} electronic state using the coupled cluster with singles doubles and triples method. All-electron quadruple-ζ basis sets with additional core functions are used for Li and Na, and small-core relativistic effective core potentials with quadruple-ζ quality basis sets are used for K, Rb, and Cs. The inclusion of the coupled cluster non-perturbative triple excitations is shown to be crucial for obtaining the accurate potential energy curves. A large one-electron basis set with additional core functions is needed for the accurate prediction of permanent dipole moments. The dissociation energies are overestimated by only 14 cm{sup −1} for LiNa and by no more than 114 cm{sup −1} for the other molecules. The discrepancies between the experimental and calculated harmonic vibrational frequencies are less than 1.7 cm{sup −1}, and the discrepancies for the anharmonic correction are less than 0.1 cm{sup −1}. We show that correlation between atomic electronegativity differences and permanent dipole moment of heteronuclear alkali dimers is not perfect. To obtain the vibrational energies and wave functions the vibrational Schrödinger equation is solved with the B-spline basis set method. The transition dipole moments between all vibrational states, the Einstein coefficients, and the lifetimes of the vibrational states are calculated. We analyze the decay rates of the vibrational states in terms of spontaneous emission, and stimulated emission and absorption induced by black body radiation. In all studied heteronuclear alkali dimers the ground vibrational states have much longer lifetimes than any excited states.

  12. Accurate potential energy, dipole moment curves, and lifetimes of vibrational states of heteronuclear alkali dimers

    NASA Astrophysics Data System (ADS)

    Fedorov, Dmitry A.; Derevianko, Andrei; Varganov, Sergey A.

    2014-05-01

    We calculate the potential energy curves, the permanent dipole moment curves, and the lifetimes of the ground and excited vibrational states of the heteronuclear alkali dimers XY (X, Y = Li, Na, K, Rb, Cs) in the X1Σ+ electronic state using the coupled cluster with singles doubles and triples method. All-electron quadruple-ζ basis sets with additional core functions are used for Li and Na, and small-core relativistic effective core potentials with quadruple-ζ quality basis sets are used for K, Rb, and Cs. The inclusion of the coupled cluster non-perturbative triple excitations is shown to be crucial for obtaining the accurate potential energy curves. A large one-electron basis set with additional core functions is needed for the accurate prediction of permanent dipole moments. The dissociation energies are overestimated by only 14 cm-1 for LiNa and by no more than 114 cm-1 for the other molecules. The discrepancies between the experimental and calculated harmonic vibrational frequencies are less than 1.7 cm-1, and the discrepancies for the anharmonic correction are less than 0.1 cm-1. We show that correlation between atomic electronegativity differences and permanent dipole moment of heteronuclear alkali dimers is not perfect. To obtain the vibrational energies and wave functions the vibrational Schrödinger equation is solved with the B-spline basis set method. The transition dipole moments between all vibrational states, the Einstein coefficients, and the lifetimes of the vibrational states are calculated. We analyze the decay rates of the vibrational states in terms of spontaneous emission, and stimulated emission and absorption induced by black body radiation. In all studied heteronuclear alkali dimers the ground vibrational states have much longer lifetimes than any excited states.

  13. Mill profiler machines soft materials accurately

    NASA Technical Reports Server (NTRS)

    Rauschl, J. A.

    1966-01-01

    Mill profiler machines bevels, slots, and grooves in soft materials, such as styrofoam phenolic-filled cores, to any desired thickness. A single operator can accurately control cutting depths in contour or straight line work.

  14. Remote balance weighs accurately amid high radiation

    NASA Technical Reports Server (NTRS)

    Eggenberger, D. N.; Shuck, A. B.

    1969-01-01

    Commercial beam-type balance, modified and outfitted with electronic controls and digital readout, can be remotely controlled for use in high radiation environments. This allows accurate weighing of breeder-reactor fuel pieces when they are radioactively hot.

  15. Understanding the Code: keeping accurate records.

    PubMed

    Griffith, Richard

    2015-10-01

    In his continuing series looking at the legal and professional implications of the Nursing and Midwifery Council's revised Code of Conduct, Richard Griffith discusses the elements of accurate record keeping under Standard 10 of the Code. This article considers the importance of accurate record keeping for the safety of patients and protection of district nurses. The legal implications of records are explained along with how district nurses should write records to ensure these legal requirements are met. PMID:26418404

  16. Frequency-domain measurement of luminescent lanthanide chelates.

    PubMed

    Hyppänen, Iko; Soukka, Tero; Kankare, Jouko

    2010-08-01

    The sinusoidal modulation of excitation intensity and phase-sensitive detection of emission is ideally suitable for the accurate determination of the lifetime and intensity of lanthanide luminescence. In this work we elaborate on the general mathematical and instrumental techniques of the frequency-domain (FD) measurements in the low-frequency domain below 100 kHz. A modular FD luminometer is constructed by using a UV-LED as the excitation source, proper light filters in the excitation and emission paths, a photomultiplier with a fast preamplifier, and a conventional dual-phase lock-in amplifier. Starting from the set of linear differential equations governing the excited-state processes of the lanthanide chelates, an equation linking the luminescence intensity to the general form of the excitation modulation was derived. Application to the sinusoidal modulation in the Euler's exponential form gives the expression for the in-phase and out-of-phase signals of a dual-phase lock-in amplifier. It is shown that by using a relatively large number of logarithmically equidistant modulation frequencies it is possible to use the Kramers-Kronig relation for checking the compatibility of the out-of-phase and in-phase signals. As an example, the emission from two different europium(III) chelates were measured by using 200 modulation frequencies between 10 Hz and 100 kHz. In addition to the conventional transition between (5)D(0) and (7)F(2) levels emitting at 615 nm, also the emission from the transition between (5)D(1) and (7)F(1) levels at ca. 540 nm was measured. The latter emission was also measured at different temperatures, yielding the energy difference between the (5)D(1) and (5)D(0) levels. The relatively large number of modulation frequencies allows also an accurate determination of lifetimes and corresponding amplitudes by using an appropriate nonlinear regression method. Comparison of the time-domain and frequency-domain methods shows that the weighting of data is

  17. Extratropical Transitions in Atlantic Canada: Impacts and Adaptive Responses

    NASA Astrophysics Data System (ADS)

    Masson, Athena; Catto, Norm

    2013-04-01

    . Storm surge damage occurred along the north shore of the Bonavista Peninsula. Similar effects, differing only in the size of the affected areas, have resulted from several extratropical transitions which have impacted Atlantic Canada since July 1989. Extratropical transition "Leslie" impacted Newfoundland on 10-11 September 2012. Although the area affected was comparable to "Igor", wind velocities and rainfall totals were less, fortunately limiting damage. Preparation, advance warning to the population, proaction, and response efforts all showed significant improvement, however, indicating that the experience gained from coping with "Igor" had been successfully applied in adaptation to "Leslie". Extratropical transitions pose a significantly different set of challenges for adaptation in comparison to purely tropical hurricanes, and responses and adaptation strategies should be tailored to address these specific events. Calculating the frequency, magnitude and intensity of potential shifts is important for accurate forecasting and public awareness, safety management, preparedness, and adaptation. Available data indicate an increase in extratropical frequency and severity in Atlantic Canada since 1991, but there are difficulties in establishing the extent and nature of transition for previous storm events. A cautionary policy would assume no significant changes in extratropical transition frequency for Atlantic Canada, but would also acknowledge that large events remain probable.

  18. An asymptotic preserving unified gas kinetic scheme for frequency-dependent radiative transfer equations

    NASA Astrophysics Data System (ADS)

    Sun, Wenjun; Jiang, Song; Xu, Kun; Li, Shu

    2015-12-01

    This paper presents an extension of previous work (Sun et al., 2015 [22]) of the unified gas kinetic scheme (UGKS) for the gray radiative transfer equations to the frequency-dependent (multi-group) radiative transfer system. Different from the gray radiative transfer equations, where the optical opacity is only a function of local material temperature, the simulation of frequency-dependent radiative transfer is associated with additional difficulties from the frequency-dependent opacity. For the multiple frequency radiation, the opacity depends on both the spatial location and the frequency. For example, the opacity is typically a decreasing function of frequency. At the same spatial region the transport physics can be optically thick for the low frequency photons, and optically thin for high frequency ones. Therefore, the optical thickness is not a simple function of space location. In this paper, the UGKS for frequency-dependent radiative system is developed. The UGKS is a finite volume method and the transport physics is modeled according to the ratio of the cell size to the photon's frequency-dependent mean free path. When the cell size is much larger than the photon's mean free path, a diffusion solution for such a frequency radiation will be obtained. On the other hand, when the cell size is much smaller than the photon's mean free path, a free transport mechanism will be recovered. In the regime between the above two limits, with the variation of the ratio between the local cell size and photon's mean free path, the UGKS provides a smooth transition in the physical and frequency space to capture the corresponding transport physics accurately. The seemingly straightforward extension of the UGKS from the gray to multiple frequency radiation system is due to its intrinsic consistent multiple scale transport modeling, but it still involves lots of work to properly discretize the multiple groups in order to design an asymptotic preserving (AP) scheme in all

  19. Robust adiabatic sum frequency conversion.

    PubMed

    Suchowski, Haim; Prabhudesai, Vaibhav; Oron, Dan; Arie, Ady; Silberberg, Yaron

    2009-07-20

    We discuss theoretically and demonstrate experimentally the robustness of the adiabatic sum frequency conversion method. This technique, borrowed from an analogous scheme of robust population transfer in atomic physics and nuclear magnetic resonance, enables the achievement of nearly full frequency conversion in a sum frequency generation process for a bandwidth up to two orders of magnitude wider than in conventional conversion schemes. We show that this scheme is robust to variations in the parameters of both the nonlinear crystal and of the incoming light. These include the crystal temperature, the frequency of the incoming field, the pump intensity, the crystal length and the angle of incidence. Also, we show that this extremely broad bandwidth can be tuned to higher or lower central wavelengths by changing either the pump frequency or the crystal temperature. The detailed study of the properties of this converter is done using the Landau-Zener theory dealing with the adiabatic transitions in two level systems. PMID:19654679

  20. Active Faraday optical frequency standard.

    PubMed

    Zhuang, Wei; Chen, Jingbiao

    2014-11-01

    We propose the mechanism of an active Faraday optical clock, and experimentally demonstrate an active Faraday optical frequency standard based on narrow bandwidth Faraday atomic filter by the method of velocity-selective optical pumping of cesium vapor. The center frequency of the active Faraday optical frequency standard is determined by the cesium 6 (2)S(1/2) F=4 to 6 (2)P(3/2) F'=4 and 5 crossover transition line. The optical heterodyne beat between two similar independent setups shows that the frequency linewidth reaches 281(23) Hz, which is 1.9×10(4) times smaller than the natural linewidth of the cesium 852-nm transition line. The maximum emitted light power reaches 75 μW. The active Faraday optical frequency standard reported here has advantages of narrow linewidth and reduced cavity pulling, which can readily be extended to other atomic transition lines of alkali and alkaline-earth metal atoms trapped in optical lattices at magic wavelengths, making it useful for new generation of optical atomic clocks. PMID:25361349

  1. Dynamic mode decomposition of H-type transition to turbulence

    NASA Astrophysics Data System (ADS)

    Sayadi, Taraneh; Nichols, Joseph; Schmid, Peter; Moin, Parviz

    2012-11-01

    Dynamic mode decomposition (DMD) is applied to a direct numerical simulation database of H-type transition to turbulence of a compressible, nominally-zero-pressure-gradient, spatially developing flat-plate boundary layer. The objective of this work is to identify the structures of dynamical importance throughout the transition region. DMD, viewed as an optimal phase averaging process in the context of the triple decomposition, is employed to assess the contribution of each coherent structure to the total Reynolds shear stress. In this region, it is observed that the total Reynolds shear stress gradient can be estimated accurately from only a few low-frequency DMD modes. These low-frequency modes are observed to correspond to the legs of hairpin vortices. Furthermore, DMD is applied to a large-eddy simulation (LES) database of the same configuration, generated using the dynamic Smagorinsky subgrid-scale model. The low-frequency DMD modes extracted from the LES, are, however, of lower amplitude than in the DNS, resulting in an underprediction of the Reynolds shear stress gradient and corresponding skin-friction coefficients. Supported by the PSAAP program of DoE.

  2. Generation of multiple optical frequencies referenced to a frequency comb for precision free-space frequency transfer

    NASA Astrophysics Data System (ADS)

    Chun, Byung Jae; Kang, Hyun Jay; Kim, Young-Jin; Kim, Seung-Woo

    2016-03-01

    Generating multiple optical frequencies referenced to the frequency standard is an important task in optical clock dissemination and optical communication. An apparatus for frequency-comb-referenced generation of multiple optical frequencies is demonstrated for high-precision free-space transfer of multiple optical frequencies. The relative linewidth and frequency instability at each channel corresponds to sub-1 Hz and 1.06×10-15 at 10 s averaging time, respectively. During the free-space transfer, the refractive index change of transmission media caused by atmospheric turbulences induces phase and frequency noise on optical frequencies. These phase and frequency noise causes induced linewidth broadening and frequency shift in optical frequencies which can disturb the accurate frequency transfer. The proposed feedback loop with acousto-optic modulator can monitor and compensate phase/frequency noise on optical frequencies. As a result, a frequency-comb-referenced single optical mode is compensated with a high signal to noise ratio (SNR) of 80 dB. By sharing the same optical paths, this feedback loop is confirmed to be successfully transferred to the neighboring wavelength channels (a 100 GHz spaced channel). This result confirms our proposed system can transfer optical frequencies to the remote site in free-space without performance degradation.

  3. Transition and laminar instability

    NASA Technical Reports Server (NTRS)

    Mack, L. M.

    1977-01-01

    The linear stability theory was applied to the problem of boundary layer transition in incompressible flow. The theory was put into a form suitable for three-dimensional boundary layers; both the temporal and spatial theories were examined; and a generalized Gaster relation for three-dimensional boundary layers was derived. Numerical examples include the stability characteristics of Falkner-Skan boundary layers, the accuracy of the two-dimensional Gaster relation for these boundary layers, and the magnitude and direction of the group velocity for oblique waves in the Blasius boundary layer. Available experiments which bear on the validity of stability theory and its relation to transition are reviewed and the stability theory is applied to transition prediction. The amplitude method is described in which the wide band disturbance amplitude in the boundary layer is estimated from stability theory and an interaction relation for the initial amplitude density of the most unstable frequency.

  4. Can blind persons accurately assess body size from the voice?

    PubMed

    Pisanski, Katarzyna; Oleszkiewicz, Anna; Sorokowska, Agnieszka

    2016-04-01

    Vocal tract resonances provide reliable information about a speaker's body size that human listeners use for biosocial judgements as well as speech recognition. Although humans can accurately assess men's relative body size from the voice alone, how this ability is acquired remains unknown. In this study, we test the prediction that accurate voice-based size estimation is possible without prior audiovisual experience linking low frequencies to large bodies. Ninety-one healthy congenitally or early blind, late blind and sighted adults (aged 20-65) participated in the study. On the basis of vowel sounds alone, participants assessed the relative body sizes of male pairs of varying heights. Accuracy of voice-based body size assessments significantly exceeded chance and did not differ among participants who were sighted, or congenitally blind or who had lost their sight later in life. Accuracy increased significantly with relative differences in physical height between men, suggesting that both blind and sighted participants used reliable vocal cues to size (i.e. vocal tract resonances). Our findings demonstrate that prior visual experience is not necessary for accurate body size estimation. This capacity, integral to both nonverbal communication and speech perception, may be present at birth or may generalize from broader cross-modal correspondences. PMID:27095264

  5. Differential equation based method for accurate approximations in optimization

    NASA Technical Reports Server (NTRS)

    Pritchard, Jocelyn I.; Adelman, Howard M.

    1990-01-01

    This paper describes a method to efficiently and accurately approximate the effect of design changes on structural response. The key to this new method is to interpret sensitivity equations as differential equations that may be solved explicitly for closed form approximations, hence, the method is denoted the Differential Equation Based (DEB) method. Approximations were developed for vibration frequencies, mode shapes and static displacements. The DEB approximation method was applied to a cantilever beam and results compared with the commonly-used linear Taylor series approximations and exact solutions. The test calculations involved perturbing the height, width, cross-sectional area, tip mass, and bending inertia of the beam. The DEB method proved to be very accurate, and in msot cases, was more accurate than the linear Taylor series approximation. The method is applicable to simultaneous perturbation of several design variables. Also, the approximations may be used to calculate other system response quantities. For example, the approximations for displacement are used to approximate bending stresses.

  6. Frequency doubled operation of a ground state depleted laser using the Nd(3+)(4)F(sub 3/2)-(4)I(sub 9/2) transition in Y2SiO5

    NASA Astrophysics Data System (ADS)

    Beach, R.; Albrecht, G.; Mitchell, S.; Comaskey, B.; Solarz, R.; Krupke, William F.; Brandle, C.; Berkstresser, G.

    1990-01-01

    A ground state depleted (GSD) laser has been demonstrated at 912 nm in the form of a Q-switched oscillator operating on the Nd(3+) F-4(sub 3/2) - I-4(sub 9/2) transition in Y2SiO5. Samarium scandium gallium garnet has been demonstrated effective at selectively suppressing the competing and much stronger F-4(sub 3/2) - I-4(sub 11/2) lasing transition. Efficient harmonic generation has been demonstrated using non-critically phase matched KNbO3.

  7. Electrical Conductivity in Transition Metals

    ERIC Educational Resources Information Center

    Talbot, Christopher; Vickneson, Kishanda

    2013-01-01

    The aim of this "Science Note" is to describe how to test the electron-sea model to determine whether it accurately predicts relative electrical conductivity for first-row transition metals. In the electron-sea model, a metal crystal is viewed as a three-dimensional array of metal cations immersed in a sea of delocalised valence…

  8. Optical frequency standards based on mercury and aluminum ions

    NASA Astrophysics Data System (ADS)

    Itano, W. M.; Bergquist, J. C.; Brusch, A.; Diddams, S. A.; Fortier, T. M.; Heavner, T. P.; Hollberg, L.; Hume, D. B.; Jefferts, S. R.; Lorini, L.; Parker, T. E.; Rosenband, T.; Stalnaker, J. E.

    2007-09-01

    Single-trapped-ion frequency standards based on a 282 nm transition in 199Hg+ and on a 267 nm transition in 27Al + have been developed at NIST over the past several years. Their frequencies are measured relative to each other and to the NIST primary frequency standard, the NIST-F1 cesium fountain, by means of a self-referenced femtosecond laser frequency comb. Both ion standards have demonstrated instabilities and inaccuracies of less than 1 × 10 -16.

  9. EMR Gage Would Measure Coal Thickness Accurately

    NASA Technical Reports Server (NTRS)

    King, J. D.; Rollwitz, W. L.

    1982-01-01

    Laboratory tests indicate electron magnetic resonance (EMR) would be effective in measuring thickness of coal overlying rock substrate. In prototype dual-frequency EMR system, Sample is irradiated by two radio frequencies. Signals are mixed, producing sum and difference output frequencies that are detected by receiver. Magnetic field is varied to scan resonant spot through sample. In system designed for field use, electromagnet is U-shaped, so that sample can be adjacent to, rather than inside the probe. Same coil is used for transmitting and receiving.

  10. A highly accurate interatomic potential for argon

    NASA Astrophysics Data System (ADS)

    Aziz, Ronald A.

    1993-09-01

    A modified potential based on the individually damped model of Douketis, Scoles, Marchetti, Zen, and Thakkar [J. Chem. Phys. 76, 3057 (1982)] is presented which fits, within experimental error, the accurate ultraviolet (UV) vibration-rotation spectrum of argon determined by UV laser absorption spectroscopy by Herman, LaRocque, and Stoicheff [J. Chem. Phys. 89, 4535 (1988)]. Other literature potentials fail to do so. The potential also is shown to predict a large number of other properties and is probably the most accurate characterization of the argon interaction constructed to date.

  11. Physical origin of the frequency shifts in cesium beam frequency standards: Related environmental sensitivity

    NASA Technical Reports Server (NTRS)

    Audoin, Claude; Dimarcq, N.; Giordano, V.; Viennet, J.

    1990-01-01

    When observed in a cesium beam frequency standard, the hyperfine transition frequency of the atoms differs slightly from the invariant transition frequency of the unperturbed atoms at rest. The various physical and technical origins of the frequency offsets are stated. They relate to fundamental physical effects, to the method of probing the atomic resonance and to the frequency control of the slaved oscillator. The variation of the frequency offsets under a change of the value of the internal operating characteristics is considered. The sensitivity to a change of the magnetic induction, the microwave power, and the temperature is given. A comparison is made of the sensitivity of cesium beam frequency standards of the commercially available type, making use of magnetic state selection, and of devices under study, in which the state preparation and detection is accomplished optically. The pathways between the external stimuli and the physical origin of the frequency offsets are specified.

  12. Improved line frequencies for the nucleic acid base uracil for a radioastronomical search

    NASA Astrophysics Data System (ADS)

    Brünken, S.; McCarthy, M. C.; Thaddeus, P.; Godfrey, P. D.; Brown, R. D.

    2006-11-01

    Aims.We report new laboratory spectroscopic data on the rotational spectrum of the pyrimidine nucleic acid base uracil (C4H4N2O2). The dataset has been extended both into the microwave region and towards mm-wavelengths with the aim of providing accurate transition rest frequencies for astrophysical searches. Methods: .The microwave measurements have been performed with a molecular beam Fourier transform microwave spectrometer in the frequency range from 9-19 GHz and the mm-wave band transitions have been recorded with a Stark-modulated free jet spectrometer up to 100 GHz. The global dataset has been analysed with a standard S-reduced Hamiltonian and precise spectroscopic parameters up to quartic order have been obtained. The hyperfine structure due to the two 14N nuclei has been resolved in the microwave measurements and the nuclear quadrupole coupling constants could be derived to high accuracy. Results: .Based on the new laboratory data and analysis, highly precise rotational transition rest frequencies are available for astrophysical important lines of uracil up to 300 GHz.

  13. Middle Grades Transition Programs around the Globe

    ERIC Educational Resources Information Center

    Andrews, Colin; Bishop, Penny

    2012-01-01

    Transitions into and out of the middle grades can be challenging for many reasons. Students need to acclimate to new policies, practices, and buildings; teachers require accurate data about their new students' capacities; and families must navigate relationships with new personnel. All school transitions present different and, at times, puzzling…

  14. The Supported Teen: Transitioning to High School

    ERIC Educational Resources Information Center

    Dorman, Benton

    2012-01-01

    Transition plans for students with special needs provide support for social and academic success while giving students an accurate picture of what to expect in high school. The Texas Comprehensive Center recommends that schools develop a comprehensive transition plan district-wide. This district plan must include the cooperation of staff from the…

  15. Accurate pointing of tungsten welding electrodes

    NASA Technical Reports Server (NTRS)

    Ziegelmeier, P.

    1971-01-01

    Thoriated-tungsten is pointed accurately and quickly by using sodium nitrite. Point produced is smooth and no effort is necessary to hold the tungsten rod concentric. The chemically produced point can be used several times longer than ground points. This method reduces time and cost of preparing tungsten electrodes.

  16. Accurate estimators of correlation functions in Fourier space

    NASA Astrophysics Data System (ADS)

    Sefusatti, E.; Crocce, M.; Scoccimarro, R.; Couchman, H. M. P.

    2016-08-01

    Efficient estimators of Fourier-space statistics for large number of objects rely on fast Fourier transforms (FFTs), which are affected by aliasing from unresolved small-scale modes due to the finite FFT grid. Aliasing takes the form of a sum over images, each of them corresponding to the Fourier content displaced by increasing multiples of the sampling frequency of the grid. These spurious contributions limit the accuracy in the estimation of Fourier-space statistics, and are typically ameliorated by simultaneously increasing grid size and discarding high-frequency modes. This results in inefficient estimates for e.g. the power spectrum when desired systematic biases are well under per cent level. We show that using interlaced grids removes odd images, which include the dominant contribution to aliasing. In addition, we discuss the choice of interpolation kernel used to define density perturbations on the FFT grid and demonstrate that using higher order interpolation kernels than the standard Cloud-In-Cell algorithm results in significant reduction of the remaining images. We show that combining fourth-order interpolation with interlacing gives very accurate Fourier amplitudes and phases of density perturbations. This results in power spectrum and bispectrum estimates that have systematic biases below 0.01 per cent all the way to the Nyquist frequency of the grid, thus maximizing the use of unbiased Fourier coefficients for a given grid size and greatly reducing systematics for applications to large cosmological data sets.

  17. AN ACCURATE FLUX DENSITY SCALE FROM 1 TO 50 GHz

    SciTech Connect

    Perley, R. A.; Butler, B. J. E-mail: BButler@nrao.edu

    2013-02-15

    We develop an absolute flux density scale for centimeter-wavelength astronomy by combining accurate flux density ratios determined by the Very Large Array between the planet Mars and a set of potential calibrators with the Rudy thermophysical emission model of Mars, adjusted to the absolute scale established by the Wilkinson Microwave Anisotropy Probe. The radio sources 3C123, 3C196, 3C286, and 3C295 are found to be varying at a level of less than {approx}5% per century at all frequencies between 1 and 50 GHz, and hence are suitable as flux density standards. We present polynomial expressions for their spectral flux densities, valid from 1 to 50 GHz, with absolute accuracy estimated at 1%-3% depending on frequency. Of the four sources, 3C286 is the most compact and has the flattest spectral index, making it the most suitable object on which to establish the spectral flux density scale. The sources 3C48, 3C138, 3C147, NGC 7027, NGC 6542, and MWC 349 show significant variability on various timescales. Polynomial coefficients for the spectral flux density are developed for 3C48, 3C138, and 3C147 for each of the 17 observation dates, spanning 1983-2012. The planets Venus, Uranus, and Neptune are included in our observations, and we derive their brightness temperatures over the same frequency range.

  18. Accurate oscillator strengths for interstellar ultraviolet lines of Cl I

    NASA Technical Reports Server (NTRS)

    Schectman, R. M.; Federman, S. R.; Beideck, D. J.; Ellis, D. J.

    1993-01-01

    Analyses on the abundance of interstellar chlorine rely on accurate oscillator strengths for ultraviolet transitions. Beam-foil spectroscopy was used to obtain f-values for the astrophysically important lines of Cl I at 1088, 1097, and 1347 A. In addition, the line at 1363 A was studied. Our f-values for 1088, 1097 A represent the first laboratory measurements for these lines; the values are f(1088)=0.081 +/- 0.007 (1 sigma) and f(1097) = 0.0088 +/- 0.0013 (1 sigma). These results resolve the issue regarding the relative strengths for 1088, 1097 A in favor of those suggested by astronomical measurements. For the other lines, our results of f(1347) = 0.153 +/- 0.011 (1 sigma) and f(1363) = 0.055 +/- 0.004 (1 sigma) are the most precisely measured values available. The f-values are somewhat greater than previous experimental and theoretical determinations.

  19. Accurate finite difference methods for time-harmonic wave propagation

    NASA Technical Reports Server (NTRS)

    Harari, Isaac; Turkel, Eli

    1994-01-01

    Finite difference methods for solving problems of time-harmonic acoustics are developed and analyzed. Multidimensional inhomogeneous problems with variable, possibly discontinuous, coefficients are considered, accounting for the effects of employing nonuniform grids. A weighted-average representation is less sensitive to transition in wave resolution (due to variable wave numbers or nonuniform grids) than the standard pointwise representation. Further enhancement in method performance is obtained by basing the stencils on generalizations of Pade approximation, or generalized definitions of the derivative, reducing spurious dispersion, anisotropy and reflection, and by improving the representation of source terms. The resulting schemes have fourth-order accurate local truncation error on uniform grids and third order in the nonuniform case. Guidelines for discretization pertaining to grid orientation and resolution are presented.

  20. Rotation frequency relay for hydrogenerator

    SciTech Connect

    Matveev, V.V.

    1980-09-01

    The rotation frequency relay (RFR) is one of the most critical elements of automatic control system of the hydrogenerators. Accurate fixing of braking, subsynchronous and acceleration angular speeds contribute to operational reliability of many units of mechanical and electrical parts of the hydrogenerator and vise versa. Both experimental and theoretical investigations were performed on hydrogenerators. It was concluded that the rotation frequency relay, where an integrated voltage of the regulator generator is used as reference voltage and the elements of comparison are executed on the operating amplifiers, has a fairly high accuracy and stability of settings, and practically does not require regulation for manufacture and operation.

  1. Observation of transitions in lithiumlike germanium

    NASA Technical Reports Server (NTRS)

    Behring, W. E.; Seely, J. F.; Brown, C. M.; Feldman, U.; Knauer, J. P.

    1989-01-01

    Transitions of the type n = 2-2, n = 2-3 and n = 3-4 in Li-like Ge(29+) have been observed in the spectrum from a laser-produced plasma. The energy levels and ionization energy of Ge(29+) were derived from the observed wavelengths. The wavelength of the 2s 2S1/2-2p 2P3/2 transition is sufficiently accurate to determine the quantum-electrodynamic contribution to the transition energy.

  2. Feedback about More Accurate versus Less Accurate Trials: Differential Effects on Self-Confidence and Activation

    ERIC Educational Resources Information Center

    Badami, Rokhsareh; VaezMousavi, Mohammad; Wulf, Gabriele; Namazizadeh, Mahdi

    2012-01-01

    One purpose of the present study was to examine whether self-confidence or anxiety would be differentially affected by feedback from more accurate rather than less accurate trials. The second purpose was to determine whether arousal variations (activation) would predict performance. On Day 1, participants performed a golf putting task under one of…

  3. Cerebral cortical activity associated with non-experts' most accurate motor performance.

    PubMed

    Dyke, Ford; Godwin, Maurice M; Goel, Paras; Rehm, Jared; Rietschel, Jeremy C; Hunt, Carly A; Miller, Matthew W

    2014-10-01

    This study's specific aim was to determine if non-experts' most accurate motor performance is associated with verbal-analytic- and working memory-related cerebral cortical activity during motor preparation. To assess this, EEG was recorded from non-expert golfers executing putts; EEG spectral power and coherence were calculated for the epoch preceding putt execution; and spectral power and coherence for the five most accurate putts were contrasted with that for the five least accurate. Results revealed marked power in the theta frequency bandwidth at all cerebral cortical regions for the most accurate putts relative to the least accurate, and considerable power in the low-beta frequency bandwidth at the left temporal region for the most accurate compared to the least. As theta power is associated with working memory and low-beta power at the left temporal region with verbal analysis, results suggest non-experts' most accurate motor performance is associated with verbal-analytic- and working memory-related cerebral cortical activity during motor preparation. PMID:25058623

  4. Numerical evaluation of the incomplete airy functions and their application to high frequency scattering and diffraction

    NASA Technical Reports Server (NTRS)

    Constantinides, E. D.; Marhefka, R. J.

    1992-01-01

    The incomplete Airy integrals serve as canonical functions for the uniform ray optical solutions to several high frequency scattering and diffraction problems that involve a class of integrals characterized by two stationary points that are arbitrarily close to one another or to an integration endpoint. Integrals of such analytical properties describe transition region phenomena associated with composite shadow boundaries. An efficient and accurate method for computing the incomplete Airy functions would make the solutions to such problems useful for engineering purposes. Here, a convergent series solution form for the incomplete Airy functions is derived. Asymptotic expansions involving several terms were also developed and serve as large argument approximations. The combination of the series solution form with the asymptotic formulae provides for an efficient and accurate computation of the incomplete Airy functions. Validation of accuracy is accomplished using direct numerical integration data.

  5. Feedback about more accurate versus less accurate trials: differential effects on self-confidence and activation.

    PubMed

    Badami, Rokhsareh; VaezMousavi, Mohammad; Wulf, Gabriele; Namazizadeh, Mahdi

    2012-06-01

    One purpose of the present study was to examine whether self-confidence or anxiety would be differentially affected byfeedback from more accurate rather than less accurate trials. The second purpose was to determine whether arousal variations (activation) would predict performance. On day 1, participants performed a golf putting task under one of two conditions: one group received feedback on the most accurate trials, whereas another group received feedback on the least accurate trials. On day 2, participants completed an anxiety questionnaire and performed a retention test. Shin conductance level, as a measure of arousal, was determined. The results indicated that feedback about more accurate trials resulted in more effective learning as well as increased self-confidence. Also, activation was a predictor of performance. PMID:22808705

  6. Accurate Anharmonic IR Spectra from Integrated Cc/dft Approach

    NASA Astrophysics Data System (ADS)

    Barone, Vincenzo; Biczysko, Malgorzata; Bloino, Julien; Carnimeo, Ivan; Puzzarini, Cristina

    2014-06-01

    The recent implementation of the computation of infrared (IR) intensities beyond the double harmonic approximation [1] paved the route to routine calculations of infrared spectra for a wide set of molecular systems. Contrary to common beliefs, second-order perturbation theory is able to deliver results of high accuracy provided that anharmonic resonances are properly managed [1,2]. It has been already shown for several small closed- and open shell molecular systems that the differences between coupled cluster (CC) and DFT anharmonic wavenumbers are mainly due to the harmonic terms, paving the route to introduce effective yet accurate hybrid CC/DFT schemes [2]. In this work we present that hybrid CC/DFT models can be applied also to the IR intensities leading to the simulation of highly accurate fully anharmonic IR spectra for medium-size molecules, including ones of atmospheric interest, showing in all cases good agreement with experiment even in the spectral ranges where non-fundamental transitions are predominant[3]. [1] J. Bloino and V. Barone, J. Chem. Phys. 136, 124108 (2012) [2] V. Barone, M. Biczysko, J. Bloino, Phys. Chem. Chem. Phys., 16, 1759-1787 (2014) [3] I. Carnimeo, C. Puzzarini, N. Tasinato, P. Stoppa, A. P. Charmet, M. Biczysko, C. Cappelli and V. Barone, J. Chem. Phys., 139, 074310 (2013)

  7. Improved calculations of the lowest vibrational transitions in HeH{sup +}

    SciTech Connect

    Bubin, Sergiy; Stanke, Monika; Kedziera, Dariusz; Adamowicz, Ludwik

    2007-08-15

    More accurate variational calculations of the lowest three pure vibrational states (v=0,1,2) of the {sup 4}HeH{sup +} molecular ion have been carried out without assuming the Born-Oppenheimer approximation. In the calculations we included the complete set of {alpha}{sup 2} relativistic corrections, i.e., mass-velocity, Darwin, spin-spin, and orbit-orbit. This allowed us to improve the agreement between the theory and the experiment for the vibrational frequencies of the 1{yields}0 and 2{yields}1 transitions as compared to our previous calculations [Stanke et al., Phys. Rev. Lett. 96, 233002 (2006)].

  8. New model accurately predicts reformate composition

    SciTech Connect

    Ancheyta-Juarez, J.; Aguilar-Rodriguez, E. )

    1994-01-31

    Although naphtha reforming is a well-known process, the evolution of catalyst formulation, as well as new trends in gasoline specifications, have led to rapid evolution of the process, including: reactor design, regeneration mode, and operating conditions. Mathematical modeling of the reforming process is an increasingly important tool. It is fundamental to the proper design of new reactors and revamp of existing ones. Modeling can be used to optimize operating conditions, analyze the effects of process variables, and enhance unit performance. Instituto Mexicano del Petroleo has developed a model of the catalytic reforming process that accurately predicts reformate composition at the higher-severity conditions at which new reformers are being designed. The new AA model is more accurate than previous proposals because it takes into account the effects of temperature and pressure on the rate constants of each chemical reaction.

  9. Accurate colorimetric feedback for RGB LED clusters

    NASA Astrophysics Data System (ADS)

    Man, Kwong; Ashdown, Ian

    2006-08-01

    We present an empirical model of LED emission spectra that is applicable to both InGaN and AlInGaP high-flux LEDs, and which accurately predicts their relative spectral power distributions over a wide range of LED junction temperatures. We further demonstrate with laboratory measurements that changes in LED spectral power distribution with temperature can be accurately predicted with first- or second-order equations. This provides the basis for a real-time colorimetric feedback system for RGB LED clusters that can maintain the chromaticity of white light at constant intensity to within +/-0.003 Δuv over a range of 45 degrees Celsius, and to within 0.01 Δuv when dimmed over an intensity range of 10:1.

  10. Accurate mask model for advanced nodes

    NASA Astrophysics Data System (ADS)

    Zine El Abidine, Nacer; Sundermann, Frank; Yesilada, Emek; Ndiaye, El Hadji Omar; Mishra, Kushlendra; Paninjath, Sankaranarayanan; Bork, Ingo; Buck, Peter; Toublan, Olivier; Schanen, Isabelle

    2014-07-01

    Standard OPC models consist of a physical optical model and an empirical resist model. The resist model compensates the optical model imprecision on top of modeling resist development. The optical model imprecision may result from mask topography effects and real mask information including mask ebeam writing and mask process contributions. For advanced technology nodes, significant progress has been made to model mask topography to improve optical model accuracy. However, mask information is difficult to decorrelate from standard OPC model. Our goal is to establish an accurate mask model through a dedicated calibration exercise. In this paper, we present a flow to calibrate an accurate mask enabling its implementation. The study covers the different effects that should be embedded in the mask model as well as the experiment required to model them.

  11. Accurate guitar tuning by cochlear implant musicians.

    PubMed

    Lu, Thomas; Huang, Juan; Zeng, Fan-Gang

    2014-01-01

    Modern cochlear implant (CI) users understand speech but find difficulty in music appreciation due to poor pitch perception. Still, some deaf musicians continue to perform with their CI. Here we show unexpected results that CI musicians can reliably tune a guitar by CI alone and, under controlled conditions, match simultaneously presented tones to <0.5 Hz. One subject had normal contralateral hearing and produced more accurate tuning with CI than his normal ear. To understand these counterintuitive findings, we presented tones sequentially and found that tuning error was larger at ∼ 30 Hz for both subjects. A third subject, a non-musician CI user with normal contralateral hearing, showed similar trends in performance between CI and normal hearing ears but with less precision. This difference, along with electric analysis, showed that accurate tuning was achieved by listening to beats rather than discriminating pitch, effectively turning a spectral task into a temporal discrimination task. PMID:24651081

  12. Two highly accurate methods for pitch calibration

    NASA Astrophysics Data System (ADS)

    Kniel, K.; Härtig, F.; Osawa, S.; Sato, O.

    2009-11-01

    Among profiles, helix and tooth thickness pitch is one of the most important parameters of an involute gear measurement evaluation. In principle, coordinate measuring machines (CMM) and CNC-controlled gear measuring machines as a variant of a CMM are suited for these kinds of gear measurements. Now the Japan National Institute of Advanced Industrial Science and Technology (NMIJ/AIST) and the German national metrology institute the Physikalisch-Technische Bundesanstalt (PTB) have each developed independently highly accurate pitch calibration methods applicable to CMM or gear measuring machines. Both calibration methods are based on the so-called closure technique which allows the separation of the systematic errors of the measurement device and the errors of the gear. For the verification of both calibration methods, NMIJ/AIST and PTB performed measurements on a specially designed pitch artifact. The comparison of the results shows that both methods can be used for highly accurate calibrations of pitch standards.

  13. Accurate modeling of parallel scientific computations

    NASA Technical Reports Server (NTRS)

    Nicol, David M.; Townsend, James C.

    1988-01-01

    Scientific codes are usually parallelized by partitioning a grid among processors. To achieve top performance it is necessary to partition the grid so as to balance workload and minimize communication/synchronization costs. This problem is particularly acute when the grid is irregular, changes over the course of the computation, and is not known until load time. Critical mapping and remapping decisions rest on the ability to accurately predict performance, given a description of a grid and its partition. This paper discusses one approach to this problem, and illustrates its use on a one-dimensional fluids code. The models constructed are shown to be accurate, and are used to find optimal remapping schedules.

  14. Accurate Guitar Tuning by Cochlear Implant Musicians

    PubMed Central

    Lu, Thomas; Huang, Juan; Zeng, Fan-Gang

    2014-01-01

    Modern cochlear implant (CI) users understand speech but find difficulty in music appreciation due to poor pitch perception. Still, some deaf musicians continue to perform with their CI. Here we show unexpected results that CI musicians can reliably tune a guitar by CI alone and, under controlled conditions, match simultaneously presented tones to <0.5 Hz. One subject had normal contralateral hearing and produced more accurate tuning with CI than his normal ear. To understand these counterintuitive findings, we presented tones sequentially and found that tuning error was larger at ∼30 Hz for both subjects. A third subject, a non-musician CI user with normal contralateral hearing, showed similar trends in performance between CI and normal hearing ears but with less precision. This difference, along with electric analysis, showed that accurate tuning was achieved by listening to beats rather than discriminating pitch, effectively turning a spectral task into a temporal discrimination task. PMID:24651081

  15. An accurate registration technique for distorted images

    NASA Technical Reports Server (NTRS)

    Delapena, Michele; Shaw, Richard A.; Linde, Peter; Dravins, Dainis

    1990-01-01

    Accurate registration of International Ultraviolet Explorer (IUE) images is crucial because the variability of the geometrical distortions that are introduced by the SEC-Vidicon cameras ensures that raw science images are never perfectly aligned with the Intensity Transfer Functions (ITFs) (i.e., graded floodlamp exposures that are used to linearize and normalize the camera response). A technique for precisely registering IUE images which uses a cross correlation of the fixed pattern that exists in all raw IUE images is described.

  16. Generating clock signals for a cycle accurate, cycle reproducible FPGA based hardware accelerator

    DOEpatents

    Asaad, Sameth W.; Kapur, Mohit

    2016-01-05

    A method, system and computer program product are disclosed for generating clock signals for a cycle accurate FPGA based hardware accelerator used to simulate operations of a device-under-test (DUT). In one embodiment, the DUT includes multiple device clocks generating multiple device clock signals at multiple frequencies and at a defined frequency ratio; and the FPG hardware accelerator includes multiple accelerator clocks generating multiple accelerator clock signals to operate the FPGA hardware accelerator to simulate the operations of the DUT. In one embodiment, operations of the DUT are mapped to the FPGA hardware accelerator, and the accelerator clock signals are generated at multiple frequencies and at the defined frequency ratio of the frequencies of the multiple device clocks, to maintain cycle accuracy between the DUT and the FPGA hardware accelerator. In an embodiment, the FPGA hardware accelerator may be used to control the frequencies of the multiple device clocks.

  17. Accurate phase-shift velocimetry in rock.

    PubMed

    Shukla, Matsyendra Nath; Vallatos, Antoine; Phoenix, Vernon R; Holmes, William M

    2016-06-01

    Spatially resolved Pulsed Field Gradient (PFG) velocimetry techniques can provide precious information concerning flow through opaque systems, including rocks. This velocimetry data is used to enhance flow models in a wide range of systems, from oil behaviour in reservoir rocks to contaminant transport in aquifers. Phase-shift velocimetry is the fastest way to produce velocity maps but critical issues have been reported when studying flow through rocks and porous media, leading to inaccurate results. Combining PFG measurements for flow through Bentheimer sandstone with simulations, we demonstrate that asymmetries in the molecular displacement distributions within each voxel are the main source of phase-shift velocimetry errors. We show that when flow-related average molecular displacements are negligible compared to self-diffusion ones, symmetric displacement distributions can be obtained while phase measurement noise is minimised. We elaborate a complete method for the production of accurate phase-shift velocimetry maps in rocks and low porosity media and demonstrate its validity for a range of flow rates. This development of accurate phase-shift velocimetry now enables more rapid and accurate velocity analysis, potentially helping to inform both industrial applications and theoretical models. PMID:27111139

  18. Accurate Molecular Polarizabilities Based on Continuum Electrostatics

    PubMed Central

    Truchon, Jean-François; Nicholls, Anthony; Iftimie, Radu I.; Roux, Benoît; Bayly, Christopher I.

    2013-01-01

    A novel approach for representing the intramolecular polarizability as a continuum dielectric is introduced to account for molecular electronic polarization. It is shown, using a finite-difference solution to the Poisson equation, that the Electronic Polarization from Internal Continuum (EPIC) model yields accurate gas-phase molecular polarizability tensors for a test set of 98 challenging molecules composed of heteroaromatics, alkanes and diatomics. The electronic polarization originates from a high intramolecular dielectric that produces polarizabilities consistent with B3LYP/aug-cc-pVTZ and experimental values when surrounded by vacuum dielectric. In contrast to other approaches to model electronic polarization, this simple model avoids the polarizability catastrophe and accurately calculates molecular anisotropy with the use of very few fitted parameters and without resorting to auxiliary sites or anisotropic atomic centers. On average, the unsigned error in the average polarizability and anisotropy compared to B3LYP are 2% and 5%, respectively. The correlation between the polarizability components from B3LYP and this approach lead to a R2 of 0.990 and a slope of 0.999. Even the F2 anisotropy, shown to be a difficult case for existing polarizability models, can be reproduced within 2% error. In addition to providing new parameters for a rapid method directly applicable to the calculation of polarizabilities, this work extends the widely used Poisson equation to areas where accurate molecular polarizabilities matter. PMID:23646034

  19. Accurate phase-shift velocimetry in rock

    NASA Astrophysics Data System (ADS)

    Shukla, Matsyendra Nath; Vallatos, Antoine; Phoenix, Vernon R.; Holmes, William M.

    2016-06-01

    Spatially resolved Pulsed Field Gradient (PFG) velocimetry techniques can provide precious information concerning flow through opaque systems, including rocks. This velocimetry data is used to enhance flow models in a wide range of systems, from oil behaviour in reservoir rocks to contaminant transport in aquifers. Phase-shift velocimetry is the fastest way to produce velocity maps but critical issues have been reported when studying flow through rocks and porous media, leading to inaccurate results. Combining PFG measurements for flow through Bentheimer sandstone with simulations, we demonstrate that asymmetries in the molecular displacement distributions within each voxel are the main source of phase-shift velocimetry errors. We show that when flow-related average molecular displacements are negligible compared to self-diffusion ones, symmetric displacement distributions can be obtained while phase measurement noise is minimised. We elaborate a complete method for the production of accurate phase-shift velocimetry maps in rocks and low porosity media and demonstrate its validity for a range of flow rates. This development of accurate phase-shift velocimetry now enables more rapid and accurate velocity analysis, potentially helping to inform both industrial applications and theoretical models.

  20. A new model for broadband waveguide to microstrip transition design

    NASA Technical Reports Server (NTRS)

    Ponchak, George E.; Downey, Alan N.

    1986-01-01

    A new model is presented which permits the prediction of the resonant frequencies created by antipodal finline waveguide to microstrip transitions. The transition is modeled as a tapered transmission line in series with an infinite set of coupled resonant circuits. The resonant circuits are modeled as simple microwave resonant cavities of which the resonant frequencies are easily determined. The model is developed and the resonant frequencies determined for several different transitions. Experimental results are given to confirm the models.

  1. Microbalance accurately measures extremely small masses

    NASA Technical Reports Server (NTRS)

    Patashnick, H.

    1970-01-01

    Oscillating fiber microbalance has a vibrating quartz fiber as balance arm to hold the mass to be weighed. Increasing fiber weight decreases its resonant frequency. Scaler and timer measure magnitude of the shift. This instrument withstands considerable physical abuse and has calibration stability at normal room temperatures.

  2. Accurate and consistent automatic seismocardiogram annotation without concurrent ECG.

    PubMed

    Laurin, A; Khosrow-Khavar, F; Blaber, A P; Tavakolian, Kouhyar

    2016-09-01

    Seismocardiography (SCG) is the measurement of vibrations in the sternum caused by the beating of the heart. Precise cardiac mechanical timings that are easily obtained from SCG are critically dependent on accurate identification of fiducial points. So far, SCG annotation has relied on concurrent ECG measurements. An algorithm capable of annotating SCG without the use any other concurrent measurement was designed. We subjected 18 participants to graded lower body negative pressure. We collected ECG and SCG, obtained R peaks from the former, and annotated the latter by hand, using these identified peaks. We also annotated the SCG automatically. We compared the isovolumic moment timings obtained by hand to those obtained using our algorithm. Mean  ±  confidence interval of the percentage of accurately annotated cardiac cycles were [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text] for levels of negative pressure 0, -20, -30, -40, and  -50 mmHg. LF/HF ratios, the relative power of low-frequency variations to high-frequency variations in heart beat intervals, obtained from isovolumic moments were also compared to those obtained from R peaks. The mean differences  ±  confidence interval were [Formula: see text], [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text] for increasing levels of negative pressure. The accuracy and consistency of the algorithm enables the use of SCG as a stand-alone heart monitoring tool in healthy individuals at rest, and could serve as a basis for an eventual application in pathological cases. PMID:27510446

  3. Spectroscopically Accurate Line Lists for Application in Sulphur Chemistry

    NASA Astrophysics Data System (ADS)

    Underwood, D. S.; Azzam, A. A. A.; Yurchenko, S. N.; Tennyson, J.

    2013-09-01

    Monitoring sulphur chemistry is thought to be of great importance for exoplanets. Doing this requires detailed knowledge of the spectroscopic properties of sulphur containing molecules such as hydrogen sulphide (H2S) [1], sulphur dioxide (SO2), and sulphur trioxide (SO3). Each of these molecules can be found in terrestrial environments, produced in volcano emissions on Earth, and analysis of their spectroscopic data can prove useful to the characterisation of exoplanets, as well as the study of planets in our own solar system, with both having a possible presence on Venus. A complete, high temperature list of line positions and intensities for H32 2 S is presented. The DVR3D program suite is used to calculate the bound ro-vibration energy levels, wavefunctions, and dipole transition intensities using Radau coordinates. The calculations are based on a newly determined, spectroscopically refined potential energy surface (PES) and a new, high accuracy, ab initio dipole moment surface (DMS). Tests show that the PES enables us to calculate the line positions accurately and the DMS gives satisfactory results for line intensities. Comparisons with experiment as well as with previous theoretical spectra will be presented. The results of this study will form an important addition to the databases which are considered as sources of information for space applications; especially, in analysing the spectra of extrasolar planets, and remote sensing studies for Venus and Earth, as well as laboratory investigations and pollution studies. An ab initio line list for SO3 was previously computed using the variational nuclear motion program TROVE [2], and was suitable for modelling room temperature SO3 spectra. The calculations considered transitions in the region of 0-4000 cm-1 with rotational states up to J = 85, and includes 174,674,257 transitions. A list of 10,878 experimental transitions had relative intensities placed on an absolute scale, and were provided in a form suitable

  4. Isomerism of Cyanomethanimine: Accurate Structural, Energetic, and Spectroscopic Characterization.

    PubMed

    Puzzarini, Cristina

    2015-11-25

    The structures, relative stabilities, and rotational and vibrational parameters of the Z-C-, E-C-, and N-cyanomethanimine isomers have been evaluated using state-of-the-art quantum-chemical approaches. Equilibrium geometries have been calculated by means of a composite scheme based on coupled-cluster calculations that accounts for the extrapolation to the complete basis set limit and core-correlation effects. The latter approach is proved to provide molecular structures with an accuracy of 0.001-0.002 Å and 0.05-0.1° for bond lengths and angles, respectively. Systematically extrapolated ab initio energies, accounting for electron correlation through coupled-cluster theory, including up to single, double, triple, and quadruple excitations, and corrected for core-electron correlation and anharmonic zero-point vibrational energy, have been used to accurately determine relative energies and the Z-E isomerization barrier with an accuracy of about 1 kJ/mol. Vibrational and rotational spectroscopic parameters have been investigated by means of hybrid schemes that allow us to obtain rotational constants accurate to about a few megahertz and vibrational frequencies with a mean absolute error of ∼1%. Where available, for all properties considered, a very good agreement with experimental data has been observed. PMID:26529434

  5. Frequency spectrum analyzer with phase-lock

    DOEpatents

    Boland, Thomas J.

    1984-01-01

    A frequency-spectrum analyzer with phase-lock for analyzing the frequency and amplitude of an input signal is comprised of a voltage controlled oscillator (VCO) which is driven by a ramp generator, and a phase error detector circuit. The phase error detector circuit measures the difference in phase between the VCO and the input signal, and drives the VCO locking it in phase momentarily with the input signal. The input signal and the output of the VCO are fed into a correlator which transfers the input signal to a frequency domain, while providing an accurate absolute amplitude measurement of each frequency component of the input signal.

  6. Low frequency acoustic and electromagnetic scattering

    NASA Technical Reports Server (NTRS)

    Hariharan, S. I.; Maccamy, R. C.

    1986-01-01

    This paper deals with two classes of problems arising from acoustics and electromagnetics scattering in the low frequency stations. The first class of problem is solving Helmholtz equation with Dirichlet boundary conditions on an arbitrary two dimensional body while the second one is an interior-exterior interface problem with Helmholtz equation in the exterior. Low frequency analysis show that there are two intermediate problems which solve the above problems accurate to 0(k/2/ log k) where k is the frequency. These solutions greatly differ from the zero frequency approximations. For the Dirichlet problem numerical examples are shown to verify the theoretical estimates.

  7. Low frequency acoustic and electromagnetic scattering

    NASA Technical Reports Server (NTRS)

    Hariharan, S. I.; Maccamy, R. C.

    1983-01-01

    This paper deals with two classes of problems arising from acoustics and electromagnetics scattering in the low frequency stations. The first class of problem is solving Helmholtz equation with Dirichlet boundary conditions on an arbitrary two dimensional body while the second one is an interior-exterior interface problem with Helmholtz equation in the exterior. Low frequency analysis show that there are two intermediate problems which solve the above problems accurate to 0(k(2) log k) where k is the frequency. These solutions greatly differ from the zero frequency approximations. For the Dirichlet problem numerical examples are shown to verify the theoretical estimates.

  8. Phoneme categorization relying solely on high-frequency energy.

    PubMed

    Vitela, A Davi; Monson, Brian B; Lotto, Andrew J

    2015-01-01

    Speech perception studies generally focus on the acoustic information present in the frequency regions below 6 kHz. Recent evidence suggests that there is perceptually relevant information in the higher frequencies, including information affecting speech intelligibility. This experiment examined whether listeners are able to accurately identify a subset of vowels and consonants in CV-context when only high-frequency (above 5 kHz) acoustic information is available (through high-pass filtering and masking of lower frequency energy). The findings reveal that listeners are capable of extracting information from these higher frequency regions to accurately identify certain consonants and vowels. PMID:25618101

  9. Phoneme categorization relying solely on high-frequency energy

    PubMed Central

    Vitela, A. Davi; Monson, Brian B.; Lotto, Andrew J.

    2015-01-01

    Speech perception studies generally focus on the acoustic information present in the frequency regions below 6 kHz. Recent evidence suggests that there is perceptually relevant information in the higher frequencies, including information affecting speech intelligibility. This experiment examined whether listeners are able to accurately identify a subset of vowels and consonants in CV-context when only high-frequency (above 5 kHz) acoustic information is available (through high-pass filtering and masking of lower frequency energy). The findings reveal that listeners are capable of extracting information from these higher frequency regions to accurately identify certain consonants and vowels. PMID:25618101

  10. Accurately Mapping M31's Microlensing Population

    NASA Astrophysics Data System (ADS)

    Crotts, Arlin

    2004-07-01

    We propose to augment an existing microlensing survey of M31 with source identifications provided by a modest amount of ACS {and WFPC2 parallel} observations to yield an accurate measurement of the masses responsible for microlensing in M31, and presumably much of its dark matter. The main benefit of these data is the determination of the physical {or "einstein"} timescale of each microlensing event, rather than an effective {"FWHM"} timescale, allowing masses to be determined more than twice as accurately as without HST data. The einstein timescale is the ratio of the lensing cross-sectional radius and relative velocities. Velocities are known from kinematics, and the cross-section is directly proportional to the {unknown} lensing mass. We cannot easily measure these quantities without knowing the amplification, hence the baseline magnitude, which requires the resolution of HST to find the source star. This makes a crucial difference because M31 lens m ass determinations can be more accurate than those towards the Magellanic Clouds through our Galaxy's halo {for the same number of microlensing events} due to the better constrained geometry in the M31 microlensing situation. Furthermore, our larger survey, just completed, should yield at least 100 M31 microlensing events, more than any Magellanic survey. A small amount of ACS+WFPC2 imaging will deliver the potential of this large database {about 350 nights}. For the whole survey {and a delta-function mass distribution} the mass error should approach only about 15%, or about 6% error in slope for a power-law distribution. These results will better allow us to pinpoint the lens halo fraction, and the shape of the halo lens spatial distribution, and allow generalization/comparison of the nature of halo dark matter in spiral galaxies. In addition, we will be able to establish the baseline magnitude for about 50, 000 variable stars, as well as measure an unprecedentedly deta iled color-magnitude diagram and luminosity

  11. Accurate measurement of unsteady state fluid temperature

    NASA Astrophysics Data System (ADS)

    Jaremkiewicz, Magdalena

    2016-07-01

    In this paper, two accurate methods for determining the transient fluid temperature were presented. Measurements were conducted for boiling water since its temperature is known. At the beginning the thermometers are at the ambient temperature and next they are immediately immersed into saturated water. The measurements were carried out with two thermometers of different construction but with the same housing outer diameter equal to 15 mm. One of them is a K-type industrial thermometer widely available commercially. The temperature indicated by the thermometer was corrected considering the thermometers as the first or second order inertia devices. The new design of a thermometer was proposed and also used to measure the temperature of boiling water. Its characteristic feature is a cylinder-shaped housing with the sheath thermocouple located in its center. The temperature of the fluid was determined based on measurements taken in the axis of the solid cylindrical element (housing) using the inverse space marching method. Measurements of the transient temperature of the air flowing through the wind tunnel using the same thermometers were also carried out. The proposed measurement technique provides more accurate results compared with measurements using industrial thermometers in conjunction with simple temperature correction using the inertial thermometer model of the first or second order. By comparing the results, it was demonstrated that the new thermometer allows obtaining the fluid temperature much faster and with higher accuracy in comparison to the industrial thermometer. Accurate measurements of the fast changing fluid temperature are possible due to the low inertia thermometer and fast space marching method applied for solving the inverse heat conduction problem.

  12. Accurate upwind methods for the Euler equations

    NASA Technical Reports Server (NTRS)

    Huynh, Hung T.

    1993-01-01

    A new class of piecewise linear methods for the numerical solution of the one-dimensional Euler equations of gas dynamics is presented. These methods are uniformly second-order accurate, and can be considered as extensions of Godunov's scheme. With an appropriate definition of monotonicity preservation for the case of linear convection, it can be shown that they preserve monotonicity. Similar to Van Leer's MUSCL scheme, they consist of two key steps: a reconstruction step followed by an upwind step. For the reconstruction step, a monotonicity constraint that preserves uniform second-order accuracy is introduced. Computational efficiency is enhanced by devising a criterion that detects the 'smooth' part of the data where the constraint is redundant. The concept and coding of the constraint are simplified by the use of the median function. A slope steepening technique, which has no effect at smooth regions and can resolve a contact discontinuity in four cells, is described. As for the upwind step, existing and new methods are applied in a manner slightly different from those in the literature. These methods are derived by approximating the Euler equations via linearization and diagonalization. At a 'smooth' interface, Harten, Lax, and Van Leer's one intermediate state model is employed. A modification for this model that can resolve contact discontinuities is presented. Near a discontinuity, either this modified model or a more accurate one, namely, Roe's flux-difference splitting. is used. The current presentation of Roe's method, via the conceptually simple flux-vector splitting, not only establishes a connection between the two splittings, but also leads to an admissibility correction with no conditional statement, and an efficient approximation to Osher's approximate Riemann solver. These reconstruction and upwind steps result in schemes that are uniformly second-order accurate and economical at smooth regions, and yield high resolution at discontinuities.

  13. The first accurate description of an aurora

    NASA Astrophysics Data System (ADS)

    Schröder, Wilfried

    2006-12-01

    As technology has advanced, the scientific study of auroral phenomena has increased by leaps and bounds. A look back at the earliest descriptions of aurorae offers an interesting look into how medieval scholars viewed the subjects that we study.Although there are earlier fragmentary references in the literature, the first accurate description of the aurora borealis appears to be that published by the German Catholic scholar Konrad von Megenberg (1309-1374) in his book Das Buch der Natur (The Book of Nature). The book was written between 1349 and 1350.

  14. Are Kohn-Sham conductances accurate?

    PubMed

    Mera, H; Niquet, Y M

    2010-11-19

    We use Fermi-liquid relations to address the accuracy of conductances calculated from the single-particle states of exact Kohn-Sham (KS) density functional theory. We demonstrate a systematic failure of this procedure for the calculation of the conductance, and show how it originates from the lack of renormalization in the KS spectral function. In certain limits this failure can lead to a large overestimation of the true conductance. We also show, however, that the KS conductances can be accurate for single-channel molecular junctions and systems where direct Coulomb interactions are strongly dominant. PMID:21231333

  15. Accurate density functional thermochemistry for larger molecules.

    SciTech Connect

    Raghavachari, K.; Stefanov, B. B.; Curtiss, L. A.; Lucent Tech.

    1997-06-20

    Density functional methods are combined with isodesmic bond separation reaction energies to yield accurate thermochemistry for larger molecules. Seven different density functionals are assessed for the evaluation of heats of formation, Delta H 0 (298 K), for a test set of 40 molecules composed of H, C, O and N. The use of bond separation energies results in a dramatic improvement in the accuracy of all the density functionals. The B3-LYP functional has the smallest mean absolute deviation from experiment (1.5 kcal mol/f).

  16. New law requires 'medically accurate' lesson plans.

    PubMed

    1999-09-17

    The California Legislature has passed a bill requiring all textbooks and materials used to teach about AIDS be medically accurate and objective. Statements made within the curriculum must be supported by research conducted in compliance with scientific methods, and published in peer-reviewed journals. Some of the current lesson plans were found to contain scientifically unsupported and biased information. In addition, the bill requires material to be "free of racial, ethnic, or gender biases." The legislation is supported by a wide range of interests, but opposed by the California Right to Life Education Fund, because they believe it discredits abstinence-only material. PMID:11366835

  17. Metric transition

    NASA Technical Reports Server (NTRS)

    1992-01-01

    This report describes NASA's metric transition in terms of seven major program elements. Six are technical areas involving research, technology development, and operations; they are managed by specific Program Offices at NASA Headquarters. The final program element, Institutional Management, covers both NASA-wide functional management under control of NASA Headquarters and metric capability development at the individual NASA Field Installations. This area addresses issues common to all NASA program elements, including: Federal, state, and local coordination; standards; private industry initiatives; public-awareness initiatives; and employee training. The concluding section identifies current barriers and impediments to metric transition; NASA has no specific recommendations for consideration by the Congress.

  18. Frequency-comb referenced spectroscopy of v4- and v5-excited hot bands in the 1.5 μm spectrum of C2H2

    NASA Astrophysics Data System (ADS)

    Twagirayezu, Sylvestre; Cich, Matthew J.; Sears, Trevor J.; McRaven, Christopher P.; Hall, Gregory E.

    2015-10-01

    Doppler-free transition frequencies for v4- and v5-excited hot bands have been measured in the v1 + v3 band region of the spectrum of acetylene using saturation dip spectroscopy with an extended cavity diode laser referenced to a frequency comb. The frequency accuracy of the measured transitions, as judged from line shape model fits and comparison to known frequencies in the v1 + v3 band itself, is between 3 and 22 kHz. This is some three orders of magnitude improvement on the accuracy and precision of previous line position estimates that were derived from the analysis of high-resolution Fourier transform infrared absorption spectra. Comparison to transition frequencies computed from constants derived from published Fourier transform infrared spectra shows that some upper rotational energy levels suffer specific perturbations causing energy level shifts of up to several hundred MHz. These perturbations are due to energy levels of the same rotational quantum number derived from nearby vibrational levels that become degenerate at specific energies. Future identification of the perturbing levels will provide accurate relative energies of excited vibrational levels of acetylene in the 7100-7600 cm-1 energy region.

  19. Computed distributions of rotovibrational transitions in LiH (X^1SIGMA^+^) and LiH^+^ (X^2SIGMA^+^).

    NASA Astrophysics Data System (ADS)

    Gianturco, F. A.; Gori Giorgi, P.; Berriche, H.; Gadea, F. X.

    1996-06-01

    Accurate potential energy curves for the ground electronic states of LiH and LiH^+^ are employed to generate vibrational and rotational levels over a broad range of J values for both systems. The corresponding dipole functions are computed and used to obtain the frequency and intensity distributions of all relevant transitions between bound states for pure vibrational excitations, pure rotational excitations and for dipole allowed rovibrational processes. This extensive set of absorption data for both molecules is employed to locate the most likely region in the infrared spectrum where characteristic lines could be observed. Such data should be useful in experimental attempts to search for LiH and LiH^+^ lines at high redshifts. We found that transitions between ionic levels will be markedly less intense than those for the neutral system and that transitions between rotationally `hot' levels will be markedly more intense than those between low-J levels.

  20. Accurate basis set truncation for wavefunction embedding

    NASA Astrophysics Data System (ADS)

    Barnes, Taylor A.; Goodpaster, Jason D.; Manby, Frederick R.; Miller, Thomas F.

    2013-07-01

    Density functional theory (DFT) provides a formally exact framework for performing embedded subsystem electronic structure calculations, including DFT-in-DFT and wavefunction theory-in-DFT descriptions. In the interest of efficiency, it is desirable to truncate the atomic orbital basis set in which the subsystem calculation is performed, thus avoiding high-order scaling with respect to the size of the MO virtual space. In this study, we extend a recently introduced projection-based embedding method [F. R. Manby, M. Stella, J. D. Goodpaster, and T. F. Miller III, J. Chem. Theory Comput. 8, 2564 (2012)], 10.1021/ct300544e to allow for the systematic and accurate truncation of the embedded subsystem basis set. The approach is applied to both covalently and non-covalently bound test cases, including water clusters and polypeptide chains, and it is demonstrated that errors associated with basis set truncation are controllable to well within chemical accuracy. Furthermore, we show that this approach allows for switching between accurate projection-based embedding and DFT embedding with approximate kinetic energy (KE) functionals; in this sense, the approach provides a means of systematically improving upon the use of approximate KE functionals in DFT embedding.

  1. Accurate radiative transfer calculations for layered media.

    PubMed

    Selden, Adrian C

    2016-07-01

    Simple yet accurate results for radiative transfer in layered media with discontinuous refractive index are obtained by the method of K-integrals. These are certain weighted integrals applied to the angular intensity distribution at the refracting boundaries. The radiative intensity is expressed as the sum of the asymptotic angular intensity distribution valid in the depth of the scattering medium and a transient term valid near the boundary. Integrated boundary equations are obtained, yielding simple linear equations for the intensity coefficients, enabling the angular emission intensity and the diffuse reflectance (albedo) and transmittance of the scattering layer to be calculated without solving the radiative transfer equation directly. Examples are given of half-space, slab, interface, and double-layer calculations, and extensions to multilayer systems are indicated. The K-integral method is orders of magnitude more accurate than diffusion theory and can be applied to layered scattering media with a wide range of scattering albedos, with potential applications to biomedical and ocean optics. PMID:27409700

  2. Fast and accurate propagation of coherent light

    PubMed Central

    Lewis, R. D.; Beylkin, G.; Monzón, L.

    2013-01-01

    We describe a fast algorithm to propagate, for any user-specified accuracy, a time-harmonic electromagnetic field between two parallel planes separated by a linear, isotropic and homogeneous medium. The analytical formulation of this problem (ca 1897) requires the evaluation of the so-called Rayleigh–Sommerfeld integral. If the distance between the planes is small, this integral can be accurately evaluated in the Fourier domain; if the distance is very large, it can be accurately approximated by asymptotic methods. In the large intermediate region of practical interest, where the oscillatory Rayleigh–Sommerfeld kernel must be applied directly, current numerical methods can be highly inaccurate without indicating this fact to the user. In our approach, for any user-specified accuracy ϵ>0, we approximate the kernel by a short sum of Gaussians with complex-valued exponents, and then efficiently apply the result to the input data using the unequally spaced fast Fourier transform. The resulting algorithm has computational complexity , where we evaluate the solution on an N×N grid of output points given an M×M grid of input samples. Our algorithm maintains its accuracy throughout the computational domain. PMID:24204184

  3. How Accurately can we Calculate Thermal Systems?

    SciTech Connect

    Cullen, D; Blomquist, R N; Dean, C; Heinrichs, D; Kalugin, M A; Lee, M; Lee, Y; MacFarlan, R; Nagaya, Y; Trkov, A

    2004-04-20

    I would like to determine how accurately a variety of neutron transport code packages (code and cross section libraries) can calculate simple integral parameters, such as K{sub eff}, for systems that are sensitive to thermal neutron scattering. Since we will only consider theoretical systems, we cannot really determine absolute accuracy compared to any real system. Therefore rather than accuracy, it would be more precise to say that I would like to determine the spread in answers that we obtain from a variety of code packages. This spread should serve as an excellent indicator of how accurately we can really model and calculate such systems today. Hopefully, eventually this will lead to improvements in both our codes and the thermal scattering models that they use in the future. In order to accomplish this I propose a number of extremely simple systems that involve thermal neutron scattering that can be easily modeled and calculated by a variety of neutron transport codes. These are theoretical systems designed to emphasize the effects of thermal scattering, since that is what we are interested in studying. I have attempted to keep these systems very simple, and yet at the same time they include most, if not all, of the important thermal scattering effects encountered in a large, water-moderated, uranium fueled thermal system, i.e., our typical thermal reactors.

  4. Accurate shear measurement with faint sources

    SciTech Connect

    Zhang, Jun; Foucaud, Sebastien; Luo, Wentao E-mail: walt@shao.ac.cn

    2015-01-01

    For cosmic shear to become an accurate cosmological probe, systematic errors in the shear measurement method must be unambiguously identified and corrected for. Previous work of this series has demonstrated that cosmic shears can be measured accurately in Fourier space in the presence of background noise and finite pixel size, without assumptions on the morphologies of galaxy and PSF. The remaining major source of error is source Poisson noise, due to the finiteness of source photon number. This problem is particularly important for faint galaxies in space-based weak lensing measurements, and for ground-based images of short exposure times. In this work, we propose a simple and rigorous way of removing the shear bias from the source Poisson noise. Our noise treatment can be generalized for images made of multiple exposures through MultiDrizzle. This is demonstrated with the SDSS and COSMOS/ACS data. With a large ensemble of mock galaxy images of unrestricted morphologies, we show that our shear measurement method can achieve sub-percent level accuracy even for images of signal-to-noise ratio less than 5 in general, making it the most promising technique for cosmic shear measurement in the ongoing and upcoming large scale galaxy surveys.

  5. Accurate pose estimation for forensic identification

    NASA Astrophysics Data System (ADS)

    Merckx, Gert; Hermans, Jeroen; Vandermeulen, Dirk

    2010-04-01

    In forensic authentication, one aims to identify the perpetrator among a series of suspects or distractors. A fundamental problem in any recognition system that aims for identification of subjects in a natural scene is the lack of constrains on viewing and imaging conditions. In forensic applications, identification proves even more challenging, since most surveillance footage is of abysmal quality. In this context, robust methods for pose estimation are paramount. In this paper we will therefore present a new pose estimation strategy for very low quality footage. Our approach uses 3D-2D registration of a textured 3D face model with the surveillance image to obtain accurate far field pose alignment. Starting from an inaccurate initial estimate, the technique uses novel similarity measures based on the monogenic signal to guide a pose optimization process. We will illustrate the descriptive strength of the introduced similarity measures by using them directly as a recognition metric. Through validation, using both real and synthetic surveillance footage, our pose estimation method is shown to be accurate, and robust to lighting changes and image degradation.

  6. Accurate determination of characteristic relative permeability curves

    NASA Astrophysics Data System (ADS)

    Krause, Michael H.; Benson, Sally M.

    2015-09-01

    A recently developed technique to accurately characterize sub-core scale heterogeneity is applied to investigate the factors responsible for flowrate-dependent effective relative permeability curves measured on core samples in the laboratory. The dependency of laboratory measured relative permeability on flowrate has long been both supported and challenged by a number of investigators. Studies have shown that this apparent flowrate dependency is a result of both sub-core scale heterogeneity and outlet boundary effects. However this has only been demonstrated numerically for highly simplified models of porous media. In this paper, flowrate dependency of effective relative permeability is demonstrated using two rock cores, a Berea Sandstone and a heterogeneous sandstone from the Otway Basin Pilot Project in Australia. Numerical simulations of steady-state coreflooding experiments are conducted at a number of injection rates using a single set of input characteristic relative permeability curves. Effective relative permeability is then calculated from the simulation data using standard interpretation methods for calculating relative permeability from steady-state tests. Results show that simplified approaches may be used to determine flowrate-independent characteristic relative permeability provided flow rate is sufficiently high, and the core heterogeneity is relatively low. It is also shown that characteristic relative permeability can be determined at any typical flowrate, and even for geologically complex models, when using accurate three-dimensional models.

  7. Theoretical Studies of Atomic Transitions

    SciTech Connect

    Charlotte Froese Fischer

    2005-07-08

    Atomic structure calculations were performed for properties such as energy levels, binding energies, transition probabilities, lifetimes, hyperfine structure, and isotope shifts. Accurate computational procedures were devised so that properties could be predicted even when they could not be obtained from experiment, and to assist in the identification of observed data. The method used was the multiconfiguration Hartree-Fock (MCHF) method, optionally corrected for relativistic effects in the Breit-Pauli approximation. Fully relativistic Dirac-Fock calculations also were performed using the GRASP code A database of energy levels, lifetimes, and transition probabilities was designed and implemented and, at present, includes many results for Be-like to Ar-like.

  8. Radar frequency radiation

    NASA Astrophysics Data System (ADS)

    Malowicki, E.

    1981-11-01

    A method is presented for the determination of radar frequency radiation power densities that the PAVE PAWS radar system could produce in its air and ground environment. The effort was prompted by the concern of the people in the vicinity of OTIS AFB MA and BEALE AFB CA about the possible radar frequency radiation hazard of the PAVE PAWS radar. The method is based on the following main assumptions that: (a) the total field can be computed as the vector summation of the individual fields due to each antenna element; (b) the individual field can be calculated using distances for which the field point is in the far field of the antenna element. An RFR computer program was coded for the RADC HE 6180 digital computer and exercised to calculate the radiation levels in the air and ground space for the present baseline and the possible Six DB and 10 DB growth systems of the PAVE PAWS radar system at OTIS AFB MA. The average radiation levels due to the surveillance fence were computed for three regions: in the air space in front of the radar, at the radar hazard fence at OTIS AFB MA and at representative ground points in the OTIS AFB vicinity. It was concluded that the radar frequency radiation of PAVE PAWS does not present a hazard to personnel provided there is no entry to the air hazard zone or to the area within the hazard fence. The method developed offers a cost effective way to determine radiation levels from a phased array radar especially in the near field and transition regions.

  9. Accurate prediction of the ammonia probes of a variable proton-to-electron mass ratio

    NASA Astrophysics Data System (ADS)

    Owens, A.; Yurchenko, S. N.; Thiel, W.; Špirko, V.

    2015-07-01

    A comprehensive study of the mass sensitivity of the vibration-rotation-inversion transitions of 14NH3, 15NH3, 14ND3 and 15ND3 is carried out variationally using the TROVE approach. Variational calculations are robust and accurate, offering a new way to compute sensitivity coefficients. Particular attention is paid to the Δk = ±3 transitions between the accidentally coinciding rotation-inversion energy levels of the ν2 = 0+, 0-, 1+ and 1- states, and the inversion transitions in the ν4 = 1 state affected by the `giant' l-type doubling effect. These transitions exhibit highly anomalous sensitivities, thus appearing as promising probes of a possible cosmological variation of the proton-to-electron mass ratio μ. Moreover, a simultaneous comparison of the calculated sensitivities reveals a sizeable isotopic dependence which could aid an exclusive ammonia detection.

  10. Different ways to active optical frequency standards

    NASA Astrophysics Data System (ADS)

    Pan, Duo; Xue, Xiaobo; Zhang, Xiaogang; Chen, Jingbiao

    2016-06-01

    Active optical frequency standard, or active optical clock, is a new concept of optical frequency standard, where a weak feedback with phase coherence information in optical bad-cavity limitation is formed, and the continuous self-sustained coherent stimulated emission between two atomic transition levels with population inversion is realized. Through ten years of both theoretical and experimental exploration, the narrow linewidth and suppression of cavity pulling effect of active optical frequency standard have been initially proved. In this paper, after a simple review, we will mainly present the most recent experimental progresses of active optical frequency standards in Peking University, including 4-level cesium active optical frequency standards and active Faraday optical frequency standards. The future development of active optical frequency standards is also discussed.

  11. X-Ray Transition Energies Database

    National Institute of Standards and Technology Data Gateway

    SRD 128 X-Ray Transition Energies Database (Web, free access)   This X-ray transition table provides the energies and wavelengths for the K and L transitions connecting energy levels having principal quantum numbers n = 1, 2, 3, and 4. The elements covered include Z = 10, neon to Z = 100, fermium. There are two unique features of this data base: (1) a serious attempt to have all experimental values on a scale consistent with the International System of measurement (the SI) and (2) inclusion of accurate theoretical estimates for all transitions.

  12. Hermetic optical-fiber iodine frequency standard.

    PubMed

    Light, Philip S; Anstie, James D; Benabid, Fetah; Luiten, Andre N

    2015-06-15

    We have built an optical-frequency standard based on interrogating iodine vapor that has been trapped within the hollow core of a hermetically sealed kagome-lattice photonic crystal fiber. A frequency-doubled Nd:YAG laser locked to a hyperfine component of the P(142)37-0 I2127 transition using modulation transfer spectroscopy shows a frequency stability of 3×10(-11) at 100 s. We discuss the impediments in integrating this all-fiber standard into a fully optical-fiber-based system, and suggest approaches that could improve performance of the frequency standard substantially. PMID:26076241

  13. Atomic frequency standards at NICT

    NASA Astrophysics Data System (ADS)

    Ido, T.; Fujieda, M.; Hachisu, H.; Hayasaka, K.; Kajita, M.; Kojima, R.; Kumagai, M.; Locke, C.; Li, Y.; Matsubara, K.; Nogami, A.; Shiga, N.; Yamaguchi, A.; Koyama, Y.; Hosokawa, M.; Hanado, Y.

    2011-10-01

    Various activities of atomic frequency standards studied in National Institute of Information and Communications Technology (NICT) are briefly reviewed. After BIPM accepted the first cesium fountain clock in NICT as a reference to determine International Atomic Time (TAI), efforts to further reduce the uncertainty of collision shifts are ongoing. A second fountain clock using atomic molasses is being built to enable the operation with less atomic density. Single ion clock using calcium has been pursued for several years in NICT. The absolute frequency measured in 2008 has CIPM to adopt the Ca+ clock transition as a part of the list of radiation (LoR) to realize the meter. Sr lattice clock has started its operation last year. The absolute frequency agreed well with those obtained in other institutes. Study of stable cavities to stabilize clock lasers are also introduced.

  14. Improved Tracking of an Atomic-Clock Resonance Transition

    NASA Technical Reports Server (NTRS)

    Prestage, John D.; Chung, Sang K.; Tu, Meirong

    2010-01-01

    An improved method of making an electronic oscillator track the frequency of an atomic-clock resonance transition is based on fitting a theoretical nonlinear curve to measurements at three oscillator frequencies within the operational frequency band of the transition (in other words, at three points within the resonance peak). In the measurement process, the frequency of a microwave oscillator is repeatedly set at various offsets from the nominal resonance frequency, the oscillator signal is applied in a square pulse of the oscillator signal having a suitable duration (typically, of the order of a second), and, for each pulse at each frequency offset, fluorescence photons of the transition in question are counted. As described below, the counts are used to determine a new nominal resonance frequency. Thereafter, offsets are determined with respect to the new resonance frequency. The process as described thus far is repeated so as to repeatedly adjust the oscillator to track the most recent estimate of the nominal resonance frequency.

  15. Accurate Thermal Stresses for Beams: Normal Stress

    NASA Technical Reports Server (NTRS)

    Johnson, Theodore F.; Pilkey, Walter D.

    2003-01-01

    Formulations for a general theory of thermoelasticity to generate accurate thermal stresses for structural members of aeronautical vehicles were developed in 1954 by Boley. The formulation also provides three normal stresses and a shear stress along the entire length of the beam. The Poisson effect of the lateral and transverse normal stresses on a thermally loaded beam is taken into account in this theory by employing an Airy stress function. The Airy stress function enables the reduction of the three-dimensional thermal stress problem to a two-dimensional one. Numerical results from the general theory of thermoelasticity are compared to those obtained from strength of materials. It is concluded that the theory of thermoelasticity for prismatic beams proposed in this paper can be used instead of strength of materials when precise stress results are desired.

  16. Accurate Thermal Stresses for Beams: Normal Stress

    NASA Technical Reports Server (NTRS)

    Johnson, Theodore F.; Pilkey, Walter D.

    2002-01-01

    Formulations for a general theory of thermoelasticity to generate accurate thermal stresses for structural members of aeronautical vehicles were developed in 1954 by Boley. The formulation also provides three normal stresses and a shear stress along the entire length of the beam. The Poisson effect of the lateral and transverse normal stresses on a thermally loaded beam is taken into account in this theory by employing an Airy stress function. The Airy stress function enables the reduction of the three-dimensional thermal stress problem to a two-dimensional one. Numerical results from the general theory of thermoelasticity are compared to those obtained from strength of materials. It is concluded that the theory of thermoelasticity for prismatic beams proposed in this paper can be used instead of strength of materials when precise stress results are desired.

  17. Highly accurate articulated coordinate measuring machine

    DOEpatents

    Bieg, Lothar F.; Jokiel, Jr., Bernhard; Ensz, Mark T.; Watson, Robert D.

    2003-12-30

    Disclosed is a highly accurate articulated coordinate measuring machine, comprising a revolute joint, comprising a circular encoder wheel, having an axis of rotation; a plurality of marks disposed around at least a portion of the circumference of the encoder wheel; bearing means for supporting the encoder wheel, while permitting free rotation of the encoder wheel about the wheel's axis of rotation; and a sensor, rigidly attached to the bearing means, for detecting the motion of at least some of the marks as the encoder wheel rotates; a probe arm, having a proximal end rigidly attached to the encoder wheel, and having a distal end with a probe tip attached thereto; and coordinate processing means, operatively connected to the sensor, for converting the output of the sensor into a set of cylindrical coordinates representing the position of the probe tip relative to a reference cylindrical coordinate system.

  18. The thermodynamic cost of accurate sensory adaptation

    NASA Astrophysics Data System (ADS)

    Tu, Yuhai

    2015-03-01

    Living organisms need to obtain and process environment information accurately in order to make decisions critical for their survival. Much progress have been made in identifying key components responsible for various biological functions, however, major challenges remain to understand system-level behaviors from the molecular-level knowledge of biology and to unravel possible physical principles for the underlying biochemical circuits. In this talk, we will present some recent works in understanding the chemical sensory system of E. coli by combining theoretical approaches with quantitative experiments. We focus on addressing the questions on how cells process chemical information and adapt to varying environment, and what are the thermodynamic limits of key regulatory functions, such as adaptation.

  19. Accurate numerical solutions of conservative nonlinear oscillators

    NASA Astrophysics Data System (ADS)

    Khan, Najeeb Alam; Nasir Uddin, Khan; Nadeem Alam, Khan

    2014-12-01

    The objective of this paper is to present an investigation to analyze the vibration of a conservative nonlinear oscillator in the form u" + lambda u + u^(2n-1) + (1 + epsilon^2 u^(4m))^(1/2) = 0 for any arbitrary power of n and m. This method converts the differential equation to sets of algebraic equations and solve numerically. We have presented for three different cases: a higher order Duffing equation, an equation with irrational restoring force and a plasma physics equation. It is also found that the method is valid for any arbitrary order of n and m. Comparisons have been made with the results found in the literature the method gives accurate results.

  20. Accurate Telescope Mount Positioning with MEMS Accelerometers

    NASA Astrophysics Data System (ADS)

    Mészáros, L.; Jaskó, A.; Pál, A.; Csépány, G.

    2014-08-01

    This paper describes the advantages and challenges of applying microelectromechanical accelerometer systems (MEMS accelerometers) in order to attain precise, accurate, and stateless positioning of telescope mounts. This provides a completely independent method from other forms of electronic, optical, mechanical or magnetic feedback or real-time astrometry. Our goal is to reach the subarcminute range which is considerably smaller than the field-of-view of conventional imaging telescope systems. Here we present how this subarcminute accuracy can be achieved with very cheap MEMS sensors and we also detail how our procedures can be extended in order to attain even finer measurements. In addition, our paper discusses how can a complete system design be implemented in order to be a part of a telescope control system.

  1. Accurate metacognition for visual sensory memory representations.

    PubMed

    Vandenbroucke, Annelinde R E; Sligte, Ilja G; Barrett, Adam B; Seth, Anil K; Fahrenfort, Johannes J; Lamme, Victor A F

    2014-04-01

    The capacity to attend to multiple objects in the visual field is limited. However, introspectively, people feel that they see the whole visual world at once. Some scholars suggest that this introspective feeling is based on short-lived sensory memory representations, whereas others argue that the feeling of seeing more than can be attended to is illusory. Here, we investigated this phenomenon by combining objective memory performance with subjective confidence ratings during a change-detection task. This allowed us to compute a measure of metacognition--the degree of knowledge that subjects have about the correctness of their decisions--for different stages of memory. We show that subjects store more objects in sensory memory than they can attend to but, at the same time, have similar metacognition for sensory memory and working memory representations. This suggests that these subjective impressions are not an illusion but accurate reflections of the richness of visual perception. PMID:24549293

  2. Apparatus for accurately measuring high temperatures

    DOEpatents

    Smith, Douglas D.

    1985-01-01

    The present invention is a thermometer used for measuring furnace temperaes in the range of about 1800.degree. to 2700.degree. C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

  3. Apparatus for accurately measuring high temperatures

    DOEpatents

    Smith, D.D.

    The present invention is a thermometer used for measuring furnace temperatures in the range of about 1800/sup 0/ to 2700/sup 0/C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

  4. Toward Accurate and Quantitative Comparative Metagenomics.

    PubMed

    Nayfach, Stephen; Pollard, Katherine S

    2016-08-25

    Shotgun metagenomics and computational analysis are used to compare the taxonomic and functional profiles of microbial communities. Leveraging this approach to understand roles of microbes in human biology and other environments requires quantitative data summaries whose values are comparable across samples and studies. Comparability is currently hampered by the use of abundance statistics that do not estimate a meaningful parameter of the microbial community and biases introduced by experimental protocols and data-cleaning approaches. Addressing these challenges, along with improving study design, data access, metadata standardization, and analysis tools, will enable accurate comparative metagenomics. We envision a future in which microbiome studies are replicable and new metagenomes are easily and rapidly integrated with existing data. Only then can the potential of metagenomics for predictive ecological modeling, well-powered association studies, and effective microbiome medicine be fully realized. PMID:27565341

  5. The importance of accurate atmospheric modeling

    NASA Astrophysics Data System (ADS)

    Payne, Dylan; Schroeder, John; Liang, Pang

    2014-11-01

    This paper will focus on the effect of atmospheric conditions on EO sensor performance using computer models. We have shown the importance of accurately modeling atmospheric effects for predicting the performance of an EO sensor. A simple example will demonstrated how real conditions for several sites in China will significantly impact on image correction, hyperspectral imaging, and remote sensing. The current state-of-the-art model for computing atmospheric transmission and radiance is, MODTRAN® 5, developed by the US Air Force Research Laboratory and Spectral Science, Inc. Research by the US Air Force, Navy and Army resulted in the public release of LOWTRAN 2 in the early 1970's. Subsequent releases of LOWTRAN and MODTRAN® have continued until the present. Please verify that (1) all pages are present, (2) all figures are correct, (3) all fonts and special characters are correct, and (4) all text and figures fit within the red margin lines shown on this review document. Complete formatting information is available at http://SPIE.org/manuscripts Return to the Manage Active Submissions page at http://spie.org/submissions/tasks.aspx and approve or disapprove this submission. Your manuscript will not be published without this approval. Please contact author_help@spie.org with any questions or concerns. The paper will demonstrate the importance of using validated models and local measured meteorological, atmospheric and aerosol conditions to accurately simulate the atmospheric transmission and radiance. Frequently default conditions are used which can produce errors of as much as 75% in these values. This can have significant impact on remote sensing applications.

  6. The high cost of accurate knowledge.

    PubMed

    Sutcliffe, Kathleen M; Weber, Klaus

    2003-05-01

    Many business thinkers believe it's the role of senior managers to scan the external environment to monitor contingencies and constraints, and to use that precise knowledge to modify the company's strategy and design. As these thinkers see it, managers need accurate and abundant information to carry out that role. According to that logic, it makes sense to invest heavily in systems for collecting and organizing competitive information. Another school of pundits contends that, since today's complex information often isn't precise anyway, it's not worth going overboard with such investments. In other words, it's not the accuracy and abundance of information that should matter most to top executives--rather, it's how that information is interpreted. After all, the role of senior managers isn't just to make decisions; it's to set direction and motivate others in the face of ambiguities and conflicting demands. Top executives must interpret information and communicate those interpretations--they must manage meaning more than they must manage information. So which of these competing views is the right one? Research conducted by academics Sutcliffe and Weber found that how accurate senior executives are about their competitive environments is indeed less important for strategy and corresponding organizational changes than the way in which they interpret information about their environments. Investments in shaping those interpretations, therefore, may create a more durable competitive advantage than investments in obtaining and organizing more information. And what kinds of interpretations are most closely linked with high performance? Their research suggests that high performers respond positively to opportunities, yet they aren't overconfident in their abilities to take advantage of those opportunities. PMID:12747164

  7. Accurate Weather Forecasting for Radio Astronomy

    NASA Astrophysics Data System (ADS)

    Maddalena, Ronald J.

    2010-01-01

    The NRAO Green Bank Telescope routinely observes at wavelengths from 3 mm to 1 m. As with all mm-wave telescopes, observing conditions depend upon the variable atmospheric water content. The site provides over 100 days/yr when opacities are low enough for good observing at 3 mm, but winds on the open-air structure reduce the time suitable for 3-mm observing where pointing is critical. Thus, to maximum productivity the observing wavelength needs to match weather conditions. For 6 years the telescope has used a dynamic scheduling system (recently upgraded; www.gb.nrao.edu/DSS) that requires accurate multi-day forecasts for winds and opacities. Since opacity forecasts are not provided by the National Weather Services (NWS), I have developed an automated system that takes available forecasts, derives forecasted opacities, and deploys the results on the web in user-friendly graphical overviews (www.gb.nrao.edu/ rmaddale/Weather). The system relies on the "North American Mesoscale" models, which are updated by the NWS every 6 hrs, have a 12 km horizontal resolution, 1 hr temporal resolution, run to 84 hrs, and have 60 vertical layers that extend to 20 km. Each forecast consists of a time series of ground conditions, cloud coverage, etc, and, most importantly, temperature, pressure, humidity as a function of height. I use the Liebe's MWP model (Radio Science, 20, 1069, 1985) to determine the absorption in each layer for each hour for 30 observing wavelengths. Radiative transfer provides, for each hour and wavelength, the total opacity and the radio brightness of the atmosphere, which contributes substantially at some wavelengths to Tsys and the observational noise. Comparisons of measured and forecasted Tsys at 22.2 and 44 GHz imply that the forecasted opacities are good to about 0.01 Nepers, which is sufficient for forecasting and accurate calibration. Reliability is high out to 2 days and degrades slowly for longer-range forecasts.

  8. Molecular frequency reference at 1.56  μm using a 12C16O overtone transition with the noise-immune cavity-enhanced optical heterodyne molecular spectroscopy method.

    PubMed

    Saraf, Shailendhar; Berceau, Paul; Stochino, Alberto; Byer, Robert; Lipa, John

    2016-05-15

    We report on a molecular clock based on the interrogation of the 3ν rotational-vibrational combination band at 1563 nm of carbon monoxide C1612O. The laser stabilization scheme is based on the noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) technique in frequency modulation (FM) saturation spectroscopy. We use a high-finesse ultra-low expansion (ULE) glass optical cavity with CO as the molecular reference for long-term stabilization of the cavity resonance. We report an Allan deviation of 1.8×10-12 at 1 s that improves to ∼3.5×10-14 with 1000 s of averaging. PMID:27176959

  9. Frequency Comb-Referenced Spectroscopy in the ν1 + ν3 Region of Acetylene

    NASA Astrophysics Data System (ADS)

    Cich, Matthew J.; Forthomme, Damien; Hall, Gregory E.; Mcraven, Christopher P.; Sears, Trevor J.; Twagirayezu, Sylvestre

    2014-06-01

    class="MsoNormal">By using saturation dip absorption spectroscopy with an extended cavity diode laser locked to a frequency comb, we have measured the rest frequencies of transitions in the ν4 = 1 and ν5 = 1 hot bands in the ν1 + ν3 combination band of acetylene. The measured line frequencies are accurate to approximately 20 kHz i.e. approximately one part in 1011. Positions of the hot-band lines quoted in the HITRAN database, which are derived from the analysis of high-resolution FTIR spectra, are of the order of 10's of MHz in error. These measurements were undertaken because pressure broadened lineshape measurements of rotational lines in the combination band indicated that weak underlying hot band features were not correctly accounted for on the basis of their previously reported positions. As a result, measured line profiles in the band could not be accurately fit leading to errors of up to 1% in acetylene concentrations derived from the measurements. In addition, the pressure broadened P(11) line in the ν1 + ν3 combination band has been studied as a function of varying concentration of the absorber in nitrogen. Mixture concentrations of 1, 5 and 10% at 296 K and pressures between a few Torr and one atmosphere were made and the measurements analyzed using two different speeddependent broadening models. These experiments are designed to test the additivity of contributions to pressure broadening and shift in speed-dependent line-shape modeling, i.e. whether the lineshape parameters follow partial pressure weighting in the binary mixtures. P(11) is relatively isolated with respect to underlying hot band transitions and neighboring transitions of the same band, but it was found that the accurate positions of underlying hot-band transitions were crucial to the successful modeling of the observed line shapes, even though these lines are typically 100-1000 times weaker than P(11) itself and are many Doppler line widths removed from the line center

  10. Nonlinear frequency coupling in dual radio-frequency driven atmospheric pressure plasmas

    SciTech Connect

    Waskoenig, J.; Gans, T.

    2010-05-03

    Plasma ionization, and associated mode transitions, in dual radio-frequency driven atmospheric pressure plasmas are governed through nonlinear frequency coupling in the dynamics of the plasma boundary sheath. Ionization in low-power mode is determined by the nonlinear coupling of electron heating and the momentary local plasma density. Ionization in high-power mode is driven by electron avalanches during phases of transient high electric fields within the boundary sheath. The transition between these distinctly different modes is controlled by the total voltage of both frequency components.

  11. 40 CFR 93.104 - Frequency of conformity determinations.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 21 2012-07-01 2012-07-01 false Frequency of conformity determinations..., Funded or Approved Under Title 23 U.S.C. or the Federal Transit Laws § 93.104 Frequency of conformity... implementation plan. (b) Frequency of conformity determinations for transportation plans. (1) Each...

  12. 40 CFR 93.104 - Frequency of conformity determinations.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 21 2013-07-01 2013-07-01 false Frequency of conformity determinations..., Funded or Approved Under Title 23 U.S.C. or the Federal Transit Laws § 93.104 Frequency of conformity... implementation plan. (b) Frequency of conformity determinations for transportation plans. (1) Each...

  13. 40 CFR 93.104 - Frequency of conformity determinations.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 20 2014-07-01 2013-07-01 true Frequency of conformity determinations..., Funded or Approved Under Title 23 U.S.C. or the Federal Transit Laws § 93.104 Frequency of conformity... implementation plan. (b) Frequency of conformity determinations for transportation plans. (1) Each...

  14. RSRM Chamber Pressure Oscillations: Transit Time Models and Unsteady CFD

    NASA Technical Reports Server (NTRS)

    Nesman, Tom; Stewart, Eric

    1996-01-01

    Space Shuttle solid rocket motor low frequency internal pressure oscillations have been observed since early testing. The same type of oscillations also are present in the redesigned solid rocket motor (RSRM). The oscillations, which occur during RSRM burn, are predominantly at the first three motor cavity longitudinal acoustic mode frequencies. Broadband flow and combustion noise provide the energy to excite these modes at low levels throughout motor burn, however, at certain times during burn the fluctuating pressure amplitude increases significantly. The increased fluctuations at these times suggests an additional excitation mechanism. The RSRM has inhibitors on the propellant forward facing surface of each motor segment. The inhibitors are in a slot at the segment field joints to prevent burning at that surface. The aft facing segment surface at a field joint slot burns and forms a cavity of time varying size. Initially the inhibitor is recessed in the field joint cavity. As propellant burns away the inhibitor begins to protrude into the bore flow. Two mechanisms (transit time models) that are considered potential pressure oscillation excitations are cavity-edge tones, and inhibitor hole-tones. Estimates of frequency variation with time of longitudinal acoustic modes, cavity edge-tones, and hole-tones compare favorably with frequencies measured during motor hot firing. It is believed that the highest oscillation amplitudes occur when vortex shedding frequencies coincide with motor longitudinal acoustic modes. A time accurate computational fluid dynamic (CFD) analysis was made to replicate the observations from motor firings and to observe the transit time mechanisms in detail. FDNS is the flow solver used to detail the time varying aspects of the flow. The fluid is approximated as a single-phase ideal gas. The CFD model was an axisymmetric representation of the RSRM at 80 seconds into burn.Deformation of the inhibitors by the internal flow was determined

  15. Approaching system equilibrium with accurate or not accurate feedback information in a two-route system

    NASA Astrophysics Data System (ADS)

    Zhao, Xiao-mei; Xie, Dong-fan; Li, Qi

    2015-02-01

    With the development of intelligent transport system, advanced information feedback strategies have been developed to reduce traffic congestion and enhance the capacity. However, previous strategies provide accurate information to travelers and our simulation results show that accurate information brings negative effects, especially in delay case. Because travelers prefer to the best condition route with accurate information, and delayed information cannot reflect current traffic condition but past. Then travelers make wrong routing decisions, causing the decrease of the capacity and the increase of oscillations and the system deviating from the equilibrium. To avoid the negative effect, bounded rationality is taken into account by introducing a boundedly rational threshold BR. When difference between two routes is less than the BR, routes have equal probability to be chosen. The bounded rationality is helpful to improve the efficiency in terms of capacity, oscillation and the gap deviating from the system equilibrium.

  16. Rainfall intensity-duration-frequency formulas.

    USGS Publications Warehouse

    Chen, C.-L.

    1983-01-01

    A new general rainfall intensity-duration-frequency formula is presented, utilizing a method similar to, but more accurate than one previously developed. The previously developed formula was based on the average depth-duration ratio of about 40% and the mean depth-frequency ratio of 1.48. It is shown that this formula is only a particular form of the writer's more general formulation. -from Author

  17. Satellite time and frequency transfer (STIFT)

    NASA Technical Reports Server (NTRS)

    Vessot, R. F. C.

    1983-01-01

    The concept of placing a hydrogen maser high stability clock in Earth orbit to provide accurate time and frequency comparisons worldwide to major timing centers and to a large number of radio observatory antenna sites involved in VLBI measurements was studied. The proposal was chiefly directed toward studies and initial hardware designs for time comparisons between hydrogen maser frequency standards and to modifications of the hydrogen maser for long-term use in space.

  18. Trapped-Ion Optical Frequency Standards

    NASA Astrophysics Data System (ADS)

    Schmidt, Piet O.; Leroux, Ian D.

    Optical frequency standards based on trapped atoms are the most accurate measurement devices we have available. They not only serve as superior time keepers but also lend themselves to a wide variety of applications ranging from tests of fundamental physics to the measurement of heights in relativistic geodesy. This chapter provides an introduction to the basics of optical frequency standards and clocks based on trapped ions and their applications.

  19. Radio frequency interference at the geostationary orbit

    NASA Technical Reports Server (NTRS)

    Sue, M. K.

    1981-01-01

    Growing demands on the frequency spectrum have increased the possibility of radio frequency interference (RFI). Various approaches to obtain in orbit RFI data are compared; this comparision indicates that the most practical way to obtain RFI data for a desired orbit (such as a geostationary orbit) is through the extrapolation of in orbit RFI measurements by a low orbit satellite. It is concluded that a coherent RFI program that uses both experimental data and analytical predictions provides accurate RFI data at minimal cost.

  20. [Humanitarian transition].

    PubMed

    Mattei, Jean-François; Troit, Virginie

    2016-02-01

    In two centuries, modern humanitarian action has experienced several fractures often linked to crises. Although its professionalism and intervention force remain indisputable, it faces, since the 2000s, a new context that limits its ability to act and confronts it with new dilemmas, even though it must deal with needs for aid of unprecedented scale. These difficulties reveal a humanitarian transition period that was not anticipated. This transition period reflects the change from a dominant paradigm of North-South solidarity of Western origin to a much more complex model. This article provides a summary of the current mutations that are dominated by the States' assertion of sovereignty. Among the possible solutions, it argues for an ethical approach and a better integration of the research carried out in the Global South, prerequisites for building a true partnership and placing the victims at the heart of the operations which involve them. PMID:26936180

  1. Eliminating Transitions

    ERIC Educational Resources Information Center

    Gallick, Barb; Lee, Lisa

    2010-01-01

    Adults often find themselves transitioning from one activity to another in a short time span. Most of the time, they do not feel they have a lot of control over their schedules, but wish that they could carve out extended time to relax and focus on one project. Picture a group of children in the block area who have spent 15 or 20 minutes building…

  2. Frequency Comb Generation in Superconducting Resonators

    NASA Astrophysics Data System (ADS)

    Pappas, David; Erickson, Robert; Vissers, Michael; Ku, Hsiang-Sheng

    2015-03-01

    We have generated frequency combs spanning 0.5 to 20 GHz in superconducting λ = 2 resonators at T =3 K. Thin films of niobium-titanium nitride enabled this development due to their low loss, high nonlinearity, low frequency dispersion, and high critical temperature. The combs nucleate as sidebands around multiples of the pump frequency. Selection rules for the allowed frequency emission are calculated using perturbation theory, and the measured spectrum is shown to agree with the theory. Sideband spacing is measured to be accurate to 1 part in 108 The sidebands coalesce into a continuous comb structure observed to cover at least several frequency octaves. Generation of combs in this frequency range allows for unprecedented analysis of this non-linear phenomena in the time domain. We acknowledge DARPA and the NIST Quantum Information program.

  3. Higher order accurate partial implicitization: An unconditionally stable fourth-order-accurate explicit numerical technique

    NASA Technical Reports Server (NTRS)

    Graves, R. A., Jr.

    1975-01-01

    The previously obtained second-order-accurate partial implicitization numerical technique used in the solution of fluid dynamic problems was modified with little complication to achieve fourth-order accuracy. The Von Neumann stability analysis demonstrated the unconditional linear stability of the technique. The order of the truncation error was deduced from the Taylor series expansions of the linearized difference equations and was verified by numerical solutions to Burger's equation. For comparison, results were also obtained for Burger's equation using a second-order-accurate partial-implicitization scheme, as well as the fourth-order scheme of Kreiss.

  4. Trends in hypersonic boundary layer stability and transition research

    NASA Astrophysics Data System (ADS)

    Kimmel, Roger L.

    1999-01-01

    Boundary layer transition impacts hypersonic vehicle performance more profoundly than low speed vehicle performance. Accurate prediction is difficult due to the sensitivity of transition to initial conditions. Computational tools continue to improve, but their use is limited largely to specialists. Ground testing continues to be a valuable tool, but new facility development is slow. Emphasis on transition control methods will increase as our understanding of the physics of hypersonic transition improves.

  5. Laser frequency stabilization using bichromatic crossover spectroscopy

    SciTech Connect

    Jeong, Taek; Seb Moon, Han

    2015-03-07

    We propose a Doppler-free spectroscopic method named bichromatic crossover spectroscopy (BCS), which we then use for the frequency stabilization of an off-resonant frequency that does not correspond to an atomic transition. The observed BCS in the 5S{sub 1/2} → 5P{sub 1/2} transition of {sup 87}Rb is related to the hyperfine structure of the conventional saturated absorption spectrum of this transition. Furthermore, the Doppler-free BCS is numerically calculated by considering all of the degenerate magnetic sublevels of the 5S{sub 1/2} → 5P{sub 1/2} transition in an atomic vapor cell, and is found to be in good agreement with the experimental results. Finally, we successfully achieve modulation-free off-resonant locking at the center frequency between the two 5S{sub 1/2}(F = 1 and 2) → 5P{sub 1/2}(F′ = 1) transitions using a polarization rotation of the BCS. The laser frequency stability was estimated to be the Allan variance of 2.1 × 10{sup −10} at 1 s.

  6. Quantifying evolutionary dynamics from variant-frequency time series.

    PubMed

    Khatri, Bhavin S

    2016-01-01

    From Kimura's neutral theory of protein evolution to Hubbell's neutral theory of biodiversity, quantifying the relative importance of neutrality versus selection has long been a basic question in evolutionary biology and ecology. With deep sequencing technologies, this question is taking on a new form: given a time-series of the frequency of different variants in a population, what is the likelihood that the observation has arisen due to selection or neutrality? To tackle the 2-variant case, we exploit Fisher's angular transformation, which despite being discovered by Ronald Fisher a century ago, has remained an intellectual curiosity. We show together with a heuristic approach it provides a simple solution for the transition probability density at short times, including drift, selection and mutation. Our results show under that under strong selection and sufficiently frequent sampling these evolutionary parameters can be accurately determined from simulation data and so they provide a theoretical basis for techniques to detect selection from variant or polymorphism frequency time-series. PMID:27616332

  7. Frequency response and design parameters for differential microbarometers.

    PubMed

    Mentink, Johan H; Evers, Läslo G

    2011-07-01

    The study of infrasound is experiencing a renaissance since it was chosen as a verification technique for the Comprehensive Nuclear-Test-Ban Treaty. Source identification is one of the main topics of research which involves detailed knowledge on the source time function, the atmosphere as medium of propagation, and the measurement system. Applications are also foreseen in using infrasound as passive probe for the upper atmosphere, taking the field beyond its monitoring application. Infrasound can be conveniently measured with differential microbarometers. An accurate description of the instrument response is an essential need to be able to attribute the recorded infrasound to a certain source or atmospheric properties. In this article, a detailed treatment is given of the response of a differential microbarometer to acoustic signals. After an historical introduction, a basic model for the frequency response is derived with its corresponding poles and zeros. The results are explained using electric analogs. In addition, thermal conduction is added to the model in order to capture the transition between adiabatic and isothermal behavior. Also discussed are high-frequency effects and the effect of external temperature variations. Eventually, the design parameters for differential microbarometers are derived. PMID:21786875

  8. Communication: Vibrationally resolved photoelectron spectroscopy of the tetracyanoquinodimethane (TCNQ) anion and accurate determination of the electron affinity of TCNQ

    NASA Astrophysics Data System (ADS)

    Zhu, Guo-Zhu; Wang, Lai-Sheng

    2015-12-01

    Tetracyanoquinodimethane (TCNQ) is widely used as an electron acceptor to form highly conducting organic charge-transfer solids. Surprisingly, the electron affinity (EA) of TCNQ is not well known and has never been directly measured. Here, we report vibrationally resolved photoelectron spectroscopy (PES) of the TCNQ- anion produced using electrospray and cooled in a cryogenic ion trap. Photoelectron spectrum taken at 354.7 nm represents the detachment transition from the ground state of TCNQ- to that of neutral TCNQ with a short vibrational progression. The EA of TCNQ is measured accurately to be 3.383 ± 0.001 eV (27 289 ± 8 cm-1), compared to the 2.8 ± 0.1 eV value known in the literature and measured previously using collisional ionization technique. In addition, six vibrational peaks are observed in the photoelectron spectrum, yielding vibrational frequencies for three totally symmetric modes of TCNQ. Two-photon PES via a bound electronic excited state of TCNQ- at 3.100 eV yields a broad low kinetic energy peak due to fast internal conversion to vibrationally excited levels of the anion ground electronic state. The high EA measured for TCNQ underlies its ability as a good electron acceptor.

  9. Communication: Vibrationally resolved photoelectron spectroscopy of the tetracyanoquinodimethane (TCNQ) anion and accurate determination of the electron affinity of TCNQ

    SciTech Connect

    Zhu, Guo-Zhu; Wang, Lai-Sheng

    2015-12-14

    Tetracyanoquinodimethane (TCNQ) is widely used as an electron acceptor to form highly conducting organic charge-transfer solids. Surprisingly, the electron affinity (EA) of TCNQ is not well known and has never been directly measured. Here, we report vibrationally resolved photoelectron spectroscopy (PES) of the TCNQ{sup −} anion produced using electrospray and cooled in a cryogenic ion trap. Photoelectron spectrum taken at 354.7 nm represents the detachment transition from the ground state of TCNQ{sup −} to that of neutral TCNQ with a short vibrational progression. The EA of TCNQ is measured accurately to be 3.383 ± 0.001 eV (27 289 ± 8 cm{sup −1}), compared to the 2.8 ± 0.1 eV value known in the literature and measured previously using collisional ionization technique. In addition, six vibrational peaks are observed in the photoelectron spectrum, yielding vibrational frequencies for three totally symmetric modes of TCNQ. Two-photon PES via a bound electronic excited state of TCNQ{sup −} at 3.100 eV yields a broad low kinetic energy peak due to fast internal conversion to vibrationally excited levels of the anion ground electronic state. The high EA measured for TCNQ underlies its ability as a good electron acceptor.

  10. Population variability complicates the accurate detection of climate change responses.

    PubMed

    McCain, Christy; Szewczyk, Tim; Bracy Knight, Kevin

    2016-06-01

    The rush to assess species' responses to anthropogenic climate change (CC) has underestimated the importance of interannual population variability (PV). Researchers assume sampling rigor alone will lead to an accurate detection of response regardless of the underlying population fluctuations of the species under consideration. Using population simulations across a realistic, empirically based gradient in PV, we show that moderate to high PV can lead to opposite and biased conclusions about CC responses. Between pre- and post-CC sampling bouts of modeled populations as in resurvey studies, there is: (i) A 50% probability of erroneously detecting the opposite trend in population abundance change and nearly zero probability of detecting no change. (ii) Across multiple years of sampling, it is nearly impossible to accurately detect any directional shift in population sizes with even moderate PV. (iii) There is up to 50% probability of detecting a population extirpation when the species is present, but in very low natural abundances. (iv) Under scenarios of moderate to high PV across a species' range or at the range edges, there is a bias toward erroneous detection of range shifts or contractions. Essentially, the frequency and magnitude of population peaks and troughs greatly impact the accuracy of our CC response measurements. Species with moderate to high PV (many small vertebrates, invertebrates, and annual plants) may be inaccurate 'canaries in the coal mine' for CC without pertinent demographic analyses and additional repeat sampling. Variation in PV may explain some idiosyncrasies in CC responses detected so far and urgently needs more careful consideration in design and analysis of CC responses. PMID:26725404

  11. Accurate Fission Data for Nuclear Safety

    NASA Astrophysics Data System (ADS)

    Solders, A.; Gorelov, D.; Jokinen, A.; Kolhinen, V. S.; Lantz, M.; Mattera, A.; Penttilä, H.; Pomp, S.; Rakopoulos, V.; Rinta-Antila, S.

    2014-05-01

    The Accurate fission data for nuclear safety (AlFONS) project aims at high precision measurements of fission yields, using the renewed IGISOL mass separator facility in combination with a new high current light ion cyclotron at the University of Jyväskylä. The 30 MeV proton beam will be used to create fast and thermal neutron spectra for the study of neutron induced fission yields. Thanks to a series of mass separating elements, culminating with the JYFLTRAP Penning trap, it is possible to achieve a mass resolving power in the order of a few hundred thousands. In this paper we present the experimental setup and the design of a neutron converter target for IGISOL. The goal is to have a flexible design. For studies of exotic nuclei far from stability a high neutron flux (1012 neutrons/s) at energies 1 - 30 MeV is desired while for reactor applications neutron spectra that resembles those of thermal and fast nuclear reactors are preferred. It is also desirable to be able to produce (semi-)monoenergetic neutrons for benchmarking and to study the energy dependence of fission yields. The scientific program is extensive and is planed to start in 2013 with a measurement of isomeric yield ratios of proton induced fission in uranium. This will be followed by studies of independent yields of thermal and fast neutron induced fission of various actinides.

  12. Fast and Provably Accurate Bilateral Filtering

    NASA Astrophysics Data System (ADS)

    Chaudhury, Kunal N.; Dabhade, Swapnil D.

    2016-06-01

    The bilateral filter is a non-linear filter that uses a range filter along with a spatial filter to perform edge-preserving smoothing of images. A direct computation of the bilateral filter requires $O(S)$ operations per pixel, where $S$ is the size of the support of the spatial filter. In this paper, we present a fast and provably accurate algorithm for approximating the bilateral filter when the range kernel is Gaussian. In particular, for box and Gaussian spatial filters, the proposed algorithm can cut down the complexity to $O(1)$ per pixel for any arbitrary $S$. The algorithm has a simple implementation involving $N+1$ spatial filterings, where $N$ is the approximation order. We give a detailed analysis of the filtering accuracy that can be achieved by the proposed approximation in relation to the target bilateral filter. This allows us to to estimate the order $N$ required to obtain a given accuracy. We also present comprehensive numerical results to demonstrate that the proposed algorithm is competitive with state-of-the-art methods in terms of speed and accuracy.

  13. Accurate Prediction of Docked Protein Structure Similarity.

    PubMed

    Akbal-Delibas, Bahar; Pomplun, Marc; Haspel, Nurit

    2015-09-01

    One of the major challenges for protein-protein docking methods is to accurately discriminate nativelike structures. The protein docking community agrees on the existence of a relationship between various favorable intermolecular interactions (e.g. Van der Waals, electrostatic, desolvation forces, etc.) and the similarity of a conformation to its native structure. Different docking algorithms often formulate this relationship as a weighted sum of selected terms and calibrate their weights against specific training data to evaluate and rank candidate structures. However, the exact form of this relationship is unknown and the accuracy of such methods is impaired by the pervasiveness of false positives. Unlike the conventional scoring functions, we propose a novel machine learning approach that not only ranks the candidate structures relative to each other but also indicates how similar each candidate is to the native conformation. We trained the AccuRMSD neural network with an extensive dataset using the back-propagation learning algorithm. Our method achieved predicting RMSDs of unbound docked complexes with 0.4Å error margin. PMID:26335807

  14. Accurate lineshape spectroscopy and the Boltzmann constant

    PubMed Central

    Truong, G.-W.; Anstie, J. D.; May, E. F.; Stace, T. M.; Luiten, A. N.

    2015-01-01

    Spectroscopy has an illustrious history delivering serendipitous discoveries and providing a stringent testbed for new physical predictions, including applications from trace materials detection, to understanding the atmospheres of stars and planets, and even constraining cosmological models. Reaching fundamental-noise limits permits optimal extraction of spectroscopic information from an absorption measurement. Here, we demonstrate a quantum-limited spectrometer that delivers high-precision measurements of the absorption lineshape. These measurements yield a very accurate measurement of the excited-state (6P1/2) hyperfine splitting in Cs, and reveals a breakdown in the well-known Voigt spectral profile. We develop a theoretical model that accounts for this breakdown, explaining the observations to within the shot-noise limit. Our model enables us to infer the thermal velocity dispersion of the Cs vapour with an uncertainty of 35 p.p.m. within an hour. This allows us to determine a value for Boltzmann's constant with a precision of 6 p.p.m., and an uncertainty of 71 p.p.m. PMID:26465085

  15. Fast and Provably Accurate Bilateral Filtering.

    PubMed

    Chaudhury, Kunal N; Dabhade, Swapnil D

    2016-06-01

    The bilateral filter is a non-linear filter that uses a range filter along with a spatial filter to perform edge-preserving smoothing of images. A direct computation of the bilateral filter requires O(S) operations per pixel, where S is the size of the support of the spatial filter. In this paper, we present a fast and provably accurate algorithm for approximating the bilateral filter when the range kernel is Gaussian. In particular, for box and Gaussian spatial filters, the proposed algorithm can cut down the complexity to O(1) per pixel for any arbitrary S . The algorithm has a simple implementation involving N+1 spatial filterings, where N is the approximation order. We give a detailed analysis of the filtering accuracy that can be achieved by the proposed approximation in relation to the target bilateral filter. This allows us to estimate the order N required to obtain a given accuracy. We also present comprehensive numerical results to demonstrate that the proposed algorithm is competitive with the state-of-the-art methods in terms of speed and accuracy. PMID:27093722

  16. How Accurate are SuperCOSMOS Positions?

    NASA Astrophysics Data System (ADS)

    Schaefer, Adam; Hunstead, Richard; Johnston, Helen

    2014-02-01

    Optical positions from the SuperCOSMOS Sky Survey have been compared in detail with accurate radio positions that define the second realisation of the International Celestial Reference Frame (ICRF2). The comparison was limited to the IIIaJ plates from the UK/AAO and Oschin (Palomar) Schmidt telescopes. A total of 1 373 ICRF2 sources was used, with the sample restricted to stellar objects brighter than BJ = 20 and Galactic latitudes |b| > 10°. Position differences showed an rms scatter of 0.16 arcsec in right ascension and declination. While overall systematic offsets were < 0.1 arcsec in each hemisphere, both the systematics and scatter were greater in the north.

  17. Accurate adiabatic correction in the hydrogen molecule

    SciTech Connect

    Pachucki, Krzysztof; Komasa, Jacek

    2014-12-14

    A new formalism for the accurate treatment of adiabatic effects in the hydrogen molecule is presented, in which the electronic wave function is expanded in the James-Coolidge basis functions. Systematic increase in the size of the basis set permits estimation of the accuracy. Numerical results for the adiabatic correction to the Born-Oppenheimer interaction energy reveal a relative precision of 10{sup −12} at an arbitrary internuclear distance. Such calculations have been performed for 88 internuclear distances in the range of 0 < R ⩽ 12 bohrs to construct the adiabatic correction potential and to solve the nuclear Schrödinger equation. Finally, the adiabatic correction to the dissociation energies of all rovibrational levels in H{sub 2}, HD, HT, D{sub 2}, DT, and T{sub 2} has been determined. For the ground state of H{sub 2} the estimated precision is 3 × 10{sup −7} cm{sup −1}, which is almost three orders of magnitude higher than that of the best previous result. The achieved accuracy removes the adiabatic contribution from the overall error budget of the present day theoretical predictions for the rovibrational levels.

  18. Accurate adiabatic correction in the hydrogen molecule

    NASA Astrophysics Data System (ADS)

    Pachucki, Krzysztof; Komasa, Jacek

    2014-12-01

    A new formalism for the accurate treatment of adiabatic effects in the hydrogen molecule is presented, in which the electronic wave function is expanded in the James-Coolidge basis functions. Systematic increase in the size of the basis set permits estimation of the accuracy. Numerical results for the adiabatic correction to the Born-Oppenheimer interaction energy reveal a relative precision of 10-12 at an arbitrary internuclear distance. Such calculations have been performed for 88 internuclear distances in the range of 0 < R ⩽ 12 bohrs to construct the adiabatic correction potential and to solve the nuclear Schrödinger equation. Finally, the adiabatic correction to the dissociation energies of all rovibrational levels in H2, HD, HT, D2, DT, and T2 has been determined. For the ground state of H2 the estimated precision is 3 × 10-7 cm-1, which is almost three orders of magnitude higher than that of the best previous result. The achieved accuracy removes the adiabatic contribution from the overall error budget of the present day theoretical predictions for the rovibrational levels.

  19. MEMS accelerometers in accurate mount positioning systems

    NASA Astrophysics Data System (ADS)

    Mészáros, László; Pál, András.; Jaskó, Attila

    2014-07-01

    In order to attain precise, accurate and stateless positioning of telescope mounts we apply microelectromechanical accelerometer systems (also known as MEMS accelerometers). In common practice, feedback from the mount position is provided by electronic, optical or magneto-mechanical systems or via real-time astrometric solution based on the acquired images. Hence, MEMS-based systems are completely independent from these mechanisms. Our goal is to investigate the advantages and challenges of applying such devices and to reach the sub-arcminute range { that is well smaller than the field-of-view of conventional imaging telescope systems. We present how this sub-arcminute accuracy can be achieved with very cheap MEMS sensors. Basically, these sensors yield raw output within an accuracy of a few degrees. We show what kind of calibration procedures could exploit spherical and cylindrical constraints between accelerometer output channels in order to achieve the previously mentioned accuracy level. We also demonstrate how can our implementation be inserted in a telescope control system. Although this attainable precision is less than both the resolution of telescope mount drive mechanics and the accuracy of astrometric solutions, the independent nature of attitude determination could significantly increase the reliability of autonomous or remotely operated astronomical observations.

  20. Accurate, reliable prototype earth horizon sensor head

    NASA Technical Reports Server (NTRS)

    Schwarz, F.; Cohen, H.

    1973-01-01

    The design and performance is described of an accurate and reliable prototype earth sensor head (ARPESH). The ARPESH employs a detection logic 'locator' concept and horizon sensor mechanization which should lead to high accuracy horizon sensing that is minimally degraded by spatial or temporal variations in sensing attitude from a satellite in orbit around the earth at altitudes in the 500 km environ 1,2. An accuracy of horizon location to within 0.7 km has been predicted, independent of meteorological conditions. This corresponds to an error of 0.015 deg-at 500 km altitude. Laboratory evaluation of the sensor indicates that this accuracy is achieved. First, the basic operating principles of ARPESH are described; next, detailed design and construction data is presented and then performance of the sensor under laboratory conditions in which the sensor is installed in a simulator that permits it to scan over a blackbody source against background representing the earth space interface for various equivalent plant temperatures.

  1. Accurate lineshape spectroscopy and the Boltzmann constant.

    PubMed

    Truong, G-W; Anstie, J D; May, E F; Stace, T M; Luiten, A N

    2015-01-01

    Spectroscopy has an illustrious history delivering serendipitous discoveries and providing a stringent testbed for new physical predictions, including applications from trace materials detection, to understanding the atmospheres of stars and planets, and even constraining cosmological models. Reaching fundamental-noise limits permits optimal extraction of spectroscopic information from an absorption measurement. Here, we demonstrate a quantum-limited spectrometer that delivers high-precision measurements of the absorption lineshape. These measurements yield a very accurate measurement of the excited-state (6P1/2) hyperfine splitting in Cs, and reveals a breakdown in the well-known Voigt spectral profile. We develop a theoretical model that accounts for this breakdown, explaining the observations to within the shot-noise limit. Our model enables us to infer the thermal velocity dispersion of the Cs vapour with an uncertainty of 35 p.p.m. within an hour. This allows us to determine a value for Boltzmann's constant with a precision of 6 p.p.m., and an uncertainty of 71 p.p.m. PMID:26465085

  2. Fast and Accurate Exhaled Breath Ammonia Measurement

    PubMed Central

    Solga, Steven F.; Mudalel, Matthew L.; Spacek, Lisa A.; Risby, Terence H.

    2014-01-01

    This exhaled breath ammonia method uses a fast and highly sensitive spectroscopic method known as quartz enhanced photoacoustic spectroscopy (QEPAS) that uses a quantum cascade based laser. The monitor is coupled to a sampler that measures mouth pressure and carbon dioxide. The system is temperature controlled and specifically designed to address the reactivity of this compound. The sampler provides immediate feedback to the subject and the technician on the quality of the breath effort. Together with the quick response time of the monitor, this system is capable of accurately measuring exhaled breath ammonia representative of deep lung systemic levels. Because the system is easy to use and produces real time results, it has enabled experiments to identify factors that influence measurements. For example, mouth rinse and oral pH reproducibly and significantly affect results and therefore must be controlled. Temperature and mode of breathing are other examples. As our understanding of these factors evolves, error is reduced, and clinical studies become more meaningful. This system is very reliable and individual measurements are inexpensive. The sampler is relatively inexpensive and quite portable, but the monitor is neither. This limits options for some clinical studies and provides rational for future innovations. PMID:24962141

  3. Frequency noise in frequency swept fiber laser.

    PubMed

    Pedersen, Anders Tegtmeier; Rottwitt, Karsten

    2013-04-01

    This Letter presents a measurement of the spectral content of frequency shifted pulses generated by a lightwave synthesized frequency sweeper. We found that each pulse is shifted in frequency with very high accuracy. We also discovered that noise originating from light leaking through the acousto- optical modulators and forward propagating Brillouin scattering appear in the spectrum. PMID:23546253

  4. Extensive and Highly Accurate Line Lists for Hydrogen Halides

    NASA Astrophysics Data System (ADS)

    Li, G.; Bernath, P. F.; Gordon, I. E.; Rothman, L. S.; Richard, C.; Le Roy, R. J.; Coxon, J. A.; Hajigeorgiou, P.

    2011-06-01

    New dipole moment functions (DMF) for the ground X 1Σ+ electronic states of the hydrogen halides (HF, HCl, HBr, HI) have been obtained using a direct fit approach that fits the best available and appropriately weighted experimental line intensity data for individual ro-vibrational transitions. Combining the newly developed (taking into account the most recent experiments) empirical potential energy functions and the DMFs, line positions and line intensities of the hydrogen halides and their isotopologues have been calculated numerically using program LEVEL. In addition, new semi-empirical algorithms for assigning line-shape parameters for these species have been developed. Using these improvements, new line lists for hydrogen halides were created to update the HITRAN spectroscopic database. These new lists are more accurate and significantly more extensive than those included in the current version of the database (HITRAN2008). R.J. Le Roy, ``LEVEL 8.0, 2007'', University of Waterloo Chemical Physics Research Report CP-663 (2007); see http://leroy.uwaterloo.ca/programs/. L.S. Rothman, I.E. Gordon, A. Barbe, D.C. Benner, P.F. Bernath, et al., ``The HITRAN 2008 Molecular Spectroscopic Database,'' JQSRT 110, 532-572 (2009).

  5. Accurate VUV Laboratory Measurements of Fe III Transitions for Astrophysical Applications

    NASA Technical Reports Server (NTRS)

    Blackwell-Whitehead, R. J.; Pickering, J. C.; Smillie, D.; Nave, G.; Szabo, C. I.; Smith, Peter L.; Nielsen, K. E.; Peters, G.

    2006-01-01

    We report preliminary measurements of Fe III spectra in the 1150 to 2500 A wavelength interval. Spectra have been recorded with an iron-neon Penning discharge lamp (PDL) between 1600 and 2500 A at Imperial College (IC) using high resolution Fourier (FT) transform spectroscopy. These FT spectrometer measurements were extended beyond 1600 A to 1150 A using high-resolution grating spectroscopy at the National Institute of Standards and Technology (NIST). These recorded spectra represent the first radiometrically calibrated measurements of a doubly-ionized iron-group element spectrum combining the techniques of vacuum ultraviolet FT and grating spectroscopy. The spectral range of the new laboratory measurements corresponds to recent HST/STIS observations of sharp-lined B stars and of Eta Carinae. The new improved atomic data can be applied to abundance studies and diagnostics of astrophysical plasmas.

  6. Accurate VUV laboratory measurements of Fe III transitions for astrophysical applications

    NASA Astrophysics Data System (ADS)

    Blackwell-Whitehead, R. J.; Pickering, J. C.; Smillie, D.; Nave, G.; Szabo, C. I.; Smith, Peter L.; Nielsen, K. E.; Peters, G.

    We report preliminary measurements of Fe III spectra in the 1150 to 2500 Å wavelength interval. Spectra have been recorded with an iron-neon Penning discharge lamp (PDL) between 1600 and 2500Å at Imperial College (IC) using high resolution Fourier (FT) transform spectroscopy. These FT spectrometer measurements were extended beyond 1600Å to 1150Å using high-resolution grating spectroscopy at the National Institute of Standards and Technology (NIST). These recorded spectra represent the first radiometrically calibrated measurements of a doubly-ionized iron--group element spectrum combining the techniques of vacuum ultraviolet FT and grating spectroscopy. The spectral range of the new laboratory measurements corresponds to recent HST/STIS observations of sharp-lined B stars and of Eta Carinae. The new improved atomic data can be applied to abundance studies and diagnostics of astrophysical plasmas.

  7. Dynamo Transition

    SciTech Connect

    Verma, M. K.; Yadav, R.; Chandra, M.; Paul, S.; Wahi, P.

    2010-11-23

    In this article we review the experimental and numerical results related to the dynamo transitions. Recent experiments of Von Karman Sodium (VKS) exhibit various dynamo states including constant, time-periodic, and chaotic magnetic fields. Similarly pseudospectral simulations of dynamo show constant, time-periodic, quasiperiodic, and chaotic magnetic field configurations. One of the windows for the magnetic Prandtl number of unity shows period doubling route to chaos. Quasiperiodic route to chaos has been reported for the Prandtl number of 0.5. The dynamo simulations also reveal coexisting multiple attractors that were obtained for different initial conditions.

  8. A Catalog of Transit Timing Posterior Distributions for all Kepler Planet Candidate Transit Events

    NASA Astrophysics Data System (ADS)

    Montet, Benjamin Tyler; Becker, Juliette C.; Johnson, John Asher

    2015-12-01

    Kepler has ushered in a new era of planetary dynamics, enabling the detection of interactions between multiple planets in transiting systems for hundreds of systems. These interactions, observed as transit timing variations (TTVs), have been used to find non-transiting companions to transiting systems and to measure masses, eccentricities, and inclinations of transiting planets. Often, physical parameters are inferred by comparing the observed light curve to the result of a photodynamical model, a time-intensive process that often ignores the effects of correlated noise in the light curve. Catalogs of transit timing observations have previously neglected non-Gaussian uncertainties in the times of transit, uncertainties in the transit shape, and short cadence data. Here, I present a catalog of not only times of transit centers, but also posterior distributions on the time of transit for every planet candidate transit event in the Kepler data, developed through importance sampling of each transit. This catalog allows one to marginalize over uncertainties in the transit shape and incorporate short cadence data, the effects of correlated noise, and non-Gaussian posteriors. Our catalog will enable dynamical studies that reflect accurately the precision of Kepler and its limitations without requiring the computational power to model the light curve completely with every integration. I will also present our open-source N-body photodynamical modeling code, which integrates planetary and stellar orbits accounting for the effects of GR, tidal effects, and Doppler beaming.

  9. Comprehensive time series analysis of the transiting extrasolar planet WASP-33b

    NASA Astrophysics Data System (ADS)

    Kovács, G.; Kovács, T.; Hartman, J. D.; Bakos, G. Á.; Bieryla, A.; Latham, D.; Noyes, R. W.; Regály, Zs.; Esquerdo, G. A.

    2013-05-01

    Context. HD 15082 (WASP-33) is the hottest and fastest rotating star known to harbor a transiting extrasolar planet (WASP-33b). The lack of high precision radial velocity (RV) data stresses the need for precise light curve analysis and gathering further RV data. Aims: By using available photometric and RV data, we perform a blend analysis, compute more accurate system parameters, confine the planetary mass, and, attempt to cast light on the observed transit anomalies. Methods: We combined the original HATNet observations and various followup data to jointly analyze the signal content and extract the transit component and used our RV data to aid the global parameter determination. Results: The blend analysis of the combination of multicolor light curves yields the first independent confirmation of the planetary nature of WASP-33b. We clearly identify three frequency components in the 15-21 d-1 regime with amplitudes 7-5 mmag. These frequencies correspond to the δ Scuti-type pulsation of the host star. None of these pulsation frequencies or their low-order linear combinations are in close resonance with the orbital frequency. We show that these pulsation components explain some but not all of the observed transit anomalies. The grand-averaged transit light curve shows that there is a ~1.5 mmag brightening shortly after the planet passes the mid-transit phase. Although the duration and amplitude of this brightening varies, it is visible even through the direct inspections of the individual transit events (some 40-60% of the followup light curves show this phenomenon). We suggest that the most likely explanation of this feature is the presence of a well-populated spot belt which is highly inclined to the orbital plane. This geometry is consistent with the inference from the spectroscopic anomalies. Finally, we constrain the planetary mass to Mp = 3.27 ± 0.73 MJ by using our RV data collected by the TRES spectrograph. Appendix A is available in electronic form at http

  10. C-type transitions in methyl formate

    NASA Technical Reports Server (NTRS)

    Plummer, Grant M.; Herbst, Eric; De Lucia, Frank C.

    1987-01-01

    Based on previously determined spectral constants for methyl formate in its ground torsional degenerate substate, the frequencies and intensities of forbidden c-type transitions in this molecule, which is represented by a large number of lines in OMC-1, are calculated along with other 'forbidden' transitions labeled x-type. The stronger c-type transitions below 300 GHz with angular momentum quantum number of 30 or less and with upper state rotational energy of 350/cm or less are included in a list of spectral frequencies presented in this paper. Because the c-type transitions borrow intensity from the b-type transitions, the intensities of strongly affected b-type spectra are recalculated and presented.

  11. How flatbed scanners upset accurate film dosimetry.

    PubMed

    van Battum, L J; Huizenga, H; Verdaasdonk, R M; Heukelom, S

    2016-01-21

    Film is an excellent dosimeter for verification of dose distributions due to its high spatial resolution. Irradiated film can be digitized with low-cost, transmission, flatbed scanners. However, a disadvantage is their lateral scan effect (LSE): a scanner readout change over its lateral scan axis. Although anisotropic light scattering was presented as the origin of the LSE, this paper presents an alternative cause. Hereto, LSE for two flatbed scanners (Epson 1680 Expression Pro and Epson 10000XL), and Gafchromic film (EBT, EBT2, EBT3) was investigated, focused on three effects: cross talk, optical path length and polarization. Cross talk was examined using triangular sheets of various optical densities. The optical path length effect was studied using absorptive and reflective neutral density filters with well-defined optical characteristics (OD range 0.2-2.0). Linear polarizer sheets were used to investigate light polarization on the CCD signal in absence and presence of (un)irradiated Gafchromic film. Film dose values ranged between 0.2 to 9 Gy, i.e. an optical density range between 0.25 to 1.1. Measurements were performed in the scanner's transmission mode, with red-green-blue channels. LSE was found to depend on scanner construction and film type. Its magnitude depends on dose: for 9 Gy increasing up to 14% at maximum lateral position. Cross talk was only significant in high contrast regions, up to 2% for very small fields. The optical path length effect introduced by film on the scanner causes 3% for pixels in the extreme lateral position. Light polarization due to film and the scanner's optical mirror system is the main contributor, different in magnitude for the red, green and blue channel. We concluded that any Gafchromic EBT type film scanned with a flatbed scanner will face these optical effects. Accurate dosimetry requires correction of LSE, therefore, determination of the LSE per color channel and dose delivered to the film. PMID:26689962

  12. Accurate paleointensities - the multi-method approach

    NASA Astrophysics Data System (ADS)

    de Groot, Lennart

    2016-04-01

    The accuracy of models describing rapid changes in the geomagnetic field over the past millennia critically depends on the availability of reliable paleointensity estimates. Over the past decade methods to derive paleointensities from lavas (the only recorder of the geomagnetic field that is available all over the globe and through geologic times) have seen significant improvements and various alternative techniques were proposed. The 'classical' Thellier-style approach was optimized and selection criteria were defined in the 'Standard Paleointensity Definitions' (Paterson et al, 2014). The Multispecimen approach was validated and the importance of additional tests and criteria to assess Multispecimen results must be emphasized. Recently, a non-heating, relative paleointensity technique was proposed -the pseudo-Thellier protocol- which shows great potential in both accuracy and efficiency, but currently lacks a solid theoretical underpinning. Here I present work using all three of the aforementioned paleointensity methods on suites of young lavas taken from the volcanic islands of Hawaii, La Palma, Gran Canaria, Tenerife, and Terceira. Many of the sampled cooling units are <100 years old, the actual field strength at the time of cooling is therefore reasonably well known. Rather intuitively, flows that produce coherent results from two or more different paleointensity methods yield the most accurate estimates of the paleofield. Furthermore, the results for some flows pass the selection criteria for one method, but fail in other techniques. Scrutinizing and combing all acceptable results yielded reliable paleointensity estimates for 60-70% of all sampled cooling units - an exceptionally high success rate. This 'multi-method paleointensity approach' therefore has high potential to provide the much-needed paleointensities to improve geomagnetic field models for the Holocene.

  13. Important Nearby Galaxies without Accurate Distances

    NASA Astrophysics Data System (ADS)

    McQuinn, Kristen

    2014-10-01

    The Spitzer Infrared Nearby Galaxies Survey (SINGS) and its offspring programs (e.g., THINGS, HERACLES, KINGFISH) have resulted in a fundamental change in our view of star formation and the ISM in galaxies, and together they represent the most complete multi-wavelength data set yet assembled for a large sample of nearby galaxies. These great investments of observing time have been dedicated to the goal of understanding the interstellar medium, the star formation process, and, more generally, galactic evolution at the present epoch. Nearby galaxies provide the basis for which we interpret the distant universe, and the SINGS sample represents the best studied nearby galaxies.Accurate distances are fundamental to interpreting observations of galaxies. Surprisingly, many of the SINGS spiral galaxies have numerous distance estimates resulting in confusion. We can rectify this situation for 8 of the SINGS spiral galaxies within 10 Mpc at a very low cost through measurements of the tip of the red giant branch. The proposed observations will provide an accuracy of better than 0.1 in distance modulus. Our sample includes such well known galaxies as M51 (the Whirlpool), M63 (the Sunflower), M104 (the Sombrero), and M74 (the archetypal grand design spiral).We are also proposing coordinated parallel WFC3 UV observations of the central regions of the galaxies, rich with high-mass UV-bright stars. As a secondary science goal we will compare the resolved UV stellar populations with integrated UV emission measurements used in calibrating star formation rates. Our observations will complement the growing HST UV atlas of high resolution images of nearby galaxies.

  14. Towards Accurate Application Characterization for Exascale (APEX)

    SciTech Connect

    Hammond, Simon David

    2015-09-01

    Sandia National Laboratories has been engaged in hardware and software codesign activities for a number of years, indeed, it might be argued that prototyping of clusters as far back as the CPLANT machines and many large capability resources including ASCI Red and RedStorm were examples of codesigned solutions. As the research supporting our codesign activities has moved closer to investigating on-node runtime behavior a nature hunger has grown for detailed analysis of both hardware and algorithm performance from the perspective of low-level operations. The Application Characterization for Exascale (APEX) LDRD was a project concieved of addressing some of these concerns. Primarily the research was to intended to focus on generating accurate and reproducible low-level performance metrics using tools that could scale to production-class code bases. Along side this research was an advocacy and analysis role associated with evaluating tools for production use, working with leading industry vendors to develop and refine solutions required by our code teams and to directly engage with production code developers to form a context for the application analysis and a bridge to the research community within Sandia. On each of these accounts significant progress has been made, particularly, as this report will cover, in the low-level analysis of operations for important classes of algorithms. This report summarizes the development of a collection of tools under the APEX research program and leaves to other SAND and L2 milestone reports the description of codesign progress with Sandia’s production users/developers.

  15. How flatbed scanners upset accurate film dosimetry

    NASA Astrophysics Data System (ADS)

    van Battum, L. J.; Huizenga, H.; Verdaasdonk, R. M.; Heukelom, S.

    2016-01-01

    Film is an excellent dosimeter for verification of dose distributions due to its high spatial resolution. Irradiated film can be digitized with low-cost, transmission, flatbed scanners. However, a disadvantage is their lateral scan effect (LSE): a scanner readout change over its lateral scan axis. Although anisotropic light scattering was presented as the origin of the LSE, this paper presents an alternative cause. Hereto, LSE for two flatbed scanners (Epson 1680 Expression Pro and Epson 10000XL), and Gafchromic film (EBT, EBT2, EBT3) was investigated, focused on three effects: cross talk, optical path length and polarization. Cross talk was examined using triangular sheets of various optical densities. The optical path length effect was studied using absorptive and reflective neutral density filters with well-defined optical characteristics (OD range 0.2-2.0). Linear polarizer sheets were used to investigate light polarization on the CCD signal in absence and presence of (un)irradiated Gafchromic film. Film dose values ranged between 0.2 to 9 Gy, i.e. an optical density range between 0.25 to 1.1. Measurements were performed in the scanner’s transmission mode, with red-green-blue channels. LSE was found to depend on scanner construction and film type. Its magnitude depends on dose: for 9 Gy increasing up to 14% at maximum lateral position. Cross talk was only significant in high contrast regions, up to 2% for very small fields. The optical path length effect introduced by film on the scanner causes 3% for pixels in the extreme lateral position. Light polarization due to film and the scanner’s optical mirror system is the main contributor, different in magnitude for the red, green and blue channel. We concluded that any Gafchromic EBT type film scanned with a flatbed scanner will face these optical effects. Accurate dosimetry requires correction of LSE, therefore, determination of the LSE per color channel and dose delivered to the film.

  16. Coherent Backscattering Reveals the Anderson Transition.

    PubMed

    Ghosh, S; Delande, D; Miniatura, C; Cherroret, N

    2015-11-13

    We develop an accurate finite-time scaling analysis of the angular width of the coherent backscattering (CBS) peak for waves propagating in 3D random media. Applying this method to ultracold atoms in optical speckle potentials, we show how to determine both the mobility edge and the critical exponent of the Anderson transition from the temporal behavior of the CBS width. Our method could be used in experiments to fully characterize the 3D Anderson transition. PMID:26613427

  17. Coherent Backscattering Reveals the Anderson Transition

    NASA Astrophysics Data System (ADS)

    Ghosh, S.; Delande, D.; Miniatura, C.; Cherroret, N.

    2015-11-01

    We develop an accurate finite-time scaling analysis of the angular width of the coherent backscattering (CBS) peak for waves propagating in 3D random media. Applying this method to ultracold atoms in optical speckle potentials, we show how to determine both the mobility edge and the critical exponent of the Anderson transition from the temporal behavior of the CBS width. Our method could be used in experiments to fully characterize the 3D Anderson transition.

  18. Observation of millimeter-wave oscillations from resonant tunneling diodes and some theoretical considerations of ultimate frequency limits

    NASA Technical Reports Server (NTRS)

    Sollner, T. C. L. G.; Brown, E. R.; Goodhue, W. D.; Le, H. Q.

    1987-01-01

    Recent observations of oscillation frequencies up to 56 GHz in resonant tunneling structures are discussed in relation to calculations by several authors of the ultimate frequency limits of these devices. It is found that calculations relying on the Wentzel-Kramers-Brillouin (WKB) approximation give limits well below the observed oscillation frequencies. Two other techniques for calculating the upper frequency limit were found to give more reasonable results. One method employs the solution of the time-dependent Schroedinger equation obtained by Kundrotas and Dargys (1986); the other uses the energy width of the transmission function for electrons through the double-barrier structure. This last technique is believed to be the most accurate since it is based on general results for the lifetime of any resonant state. It gives frequency limits on the order of 1 THz for two recently fabricated structures. It appears that the primary limitation of the oscillation frequency for double-barrier resonant-tunneling diodes is imposed by intrinsic device circuit parameters and by the transit time of the depletion layer rather than by time delays encountered in the double-barrier region.

  19. Stimulated coherent transition radiation

    SciTech Connect

    Hung-chi Lihn

    1996-03-01

    Coherent radiation emitted from a relativistic electron bunch consists of wavelengths longer than or comparable to the bunch length. The intensity of this radiation out-numbers that of its incoherent counterpart, which extends to wavelengths shorter than the bunch length, by a factor equal to the number of electrons in the bunch. In typical accelerators, this factor is about 8 to 11 orders of magnitude. The spectrum of the coherent radiation is determined by the Fourier transform of the electron bunch distribution and, therefore, contains information of the bunch distribution. Coherent transition radiation emitted from subpicosecond electron bunches at the Stanford SUNSHINE facility is observed in the far-infrared regime through a room-temperature pyroelectric bolometer and characterized through the electron bunch-length study. To measure the bunch length, a new frequency-resolved subpicosecond bunch-length measuring system is developed. This system uses a far-infrared Michelson interferometer to measure the spectrum of coherent transition radiation through optical autocorrelation with resolution far better than existing time-resolved methods. Hence, the radiation spectrum and the bunch length are deduced from the autocorrelation measurement. To study the stimulation of coherent transition radiation, a special cavity named BRAICER is invented. Far-infrared light pulses of coherent transition radiation emitted from electron bunches are delayed and circulated in the cavity to coincide with subsequent incoming electron bunches. This coincidence of light pulses with electron bunches enables the light to do work on electrons, and thus stimulates more radiated energy. The possibilities of extending the bunch-length measuring system to measure the three-dimensional bunch distribution and making the BRAICER cavity a broadband, high-intensity, coherent, far-infrared light source are also discussed.

  20. A Biochemical Magic Frequency

    NASA Technical Reports Server (NTRS)

    Weber, Arthur L.

    1993-01-01

    Life is composed principally of four classes of biomolecules - protein, nucleic acid, polysaccharide and lipid. Using 1) estimates of the reducing equivalents (electron pairs) needed to synthesize these biomolecules from carbon dioxide, and 2) measurements of the molecular composition of different organisms, we calculated the average number of electron pairs required for the reduction of carbon dioxide to biological carbon (electron pairs/carbon atom). These calculations showed that the carbon of the Earths biosphere is at the reduction level of formaldehyde that requires 2 electron pairs/carbon atom to be synthesized from carbon dioxide. This was also the reduction level of carbon of individual organisms, except for those that stored large amounts of fuel as lipid. Since this chemical property of life is easily discovered and probably universal, it's most likely known by other intelligent life in the universe. It could be the one thing we know about other carbon-based life in the universe, and the one thing that other intelligent life knows about us. We believe this common knowledge that formaldehyde represents the reduction level of life's carbon could lead to the selection of the 72.83814 GHz line of the 0,0,0,1,0,1 ground-state rotational transition of formaldehyde as a frequency for interstellar communication.

  1. Accurate theoretical chemistry with coupled pair models.

    PubMed

    Neese, Frank; Hansen, Andreas; Wennmohs, Frank; Grimme, Stefan

    2009-05-19

    Quantum chemistry has found its way into the everyday work of many experimental chemists. Calculations can predict the outcome of chemical reactions, afford insight into reaction mechanisms, and be used to interpret structure and bonding in molecules. Thus, contemporary theory offers tremendous opportunities in experimental chemical research. However, even with present-day computers and algorithms, we cannot solve the many particle Schrodinger equation exactly; inevitably some error is introduced in approximating the solutions of this equation. Thus, the accuracy of quantum chemical calculations is of critical importance. The affordable accuracy depends on molecular size and particularly on the total number of atoms: for orientation, ethanol has 9 atoms, aspirin 21 atoms, morphine 40 atoms, sildenafil 63 atoms, paclitaxel 113 atoms, insulin nearly 800 atoms, and quaternary hemoglobin almost 12,000 atoms. Currently, molecules with up to approximately 10 atoms can be very accurately studied by coupled cluster (CC) theory, approximately 100 atoms with second-order Møller-Plesset perturbation theory (MP2), approximately 1000 atoms with density functional theory (DFT), and beyond that number with semiempirical quantum chemistry and force-field methods. The overwhelming majority of present-day calculations in the 100-atom range use DFT. Although these methods have been very successful in quantum chemistry, they do not offer a well-defined hierarchy of calculations that allows one to systematically converge to the correct answer. Recently a number of rather spectacular failures of DFT methods have been found-even for seemingly simple systems such as hydrocarbons, fueling renewed interest in wave function-based methods that incorporate the relevant physics of electron correlation in a more systematic way. Thus, it would be highly desirable to fill the gap between 10 and 100 atoms with highly correlated ab initio methods. We have found that one of the earliest (and now

  2. A time-accurate adaptive grid method and the numerical simulation of a shock-vortex interaction

    NASA Technical Reports Server (NTRS)

    Bockelie, Michael J.; Eiseman, Peter R.

    1990-01-01

    A time accurate, general purpose, adaptive grid method is developed that is suitable for multidimensional steady and unsteady numerical simulations. The grid point movement is performed in a manner that generates smooth grids which resolve the severe solution gradients and the sharp transitions in the solution gradients. The temporal coupling of the adaptive grid and the PDE solver is performed with a grid prediction correction method that is simple to implement and ensures the time accuracy of the grid. Time accurate solutions of the 2-D Euler equations for an unsteady shock vortex interaction demonstrate the ability of the adaptive method to accurately adapt the grid to multiple solution features.

  3. How Accurate Is Pierce's Theory of Traveling Wave Tube?

    NASA Astrophysics Data System (ADS)

    Simon, D. H.; Chernin, D.; Wong, P.; Zhang, P.; Lau, Y. Y.; Dong, C. F.; Hoff, B.; Gilgenbach, R. M.

    2015-11-01

    This paper provides a rigorous test of the accuracy of Pierce's classical theory of traveling wave tubes (TWTs). The EXACT dispersion relation for a dielectric TWT is derived, from which the spatial amplification rate, ki, is calculated. This ki is compared with that obtained from Pierce's widely used 3-wave theory and his more general 4-wave theory (which includes the reverse propagating circuit mode). We have used various procedures to extract Pierce's gain parameter C and space charge parameter Q from the exact dispersion relation. We find that, in general, the 3-wave theory is a poor representation to the exact dispersion relation if C >0.05. However, the 4-wave theory gives excellent agreement even for C as high as 0.12 and over more than 20 percent bandwidth, if the quantity (k2 × C3) is evaluated accurately as a function of frequency, and if Q is expanded to first order in the wavenumber k, where Q is the difference between the exact dispersion relation and its 4-wave representation in which Q is set to zero. Similar tests will be performed on the disk-on-rod slow wave TWT, for which the hot tube dispersion relation including all space harmonics has been obtained. Supported by AFOSR FA9550-14-1-0309, FA9550-15-1-0097, AFRL FA9451-14-1-0374, and L-3 Communications.

  4. A fast approach for accurate content-adaptive mesh generation.

    PubMed

    Yang, Yongyi; Wernick, Miles N; Brankov, Jovan G

    2003-01-01

    Mesh modeling is an important problem with many applications in image processing. A key issue in mesh modeling is how to generate a mesh structure that well represents an image by adapting to its content. We propose a new approach to mesh generation, which is based on a theoretical result derived on the error bound of a mesh representation. In the proposed method, the classical Floyd-Steinberg error-diffusion algorithm is employed to place mesh nodes in the image domain so that their spatial density varies according to the local image content. Delaunay triangulation is next applied to connect the mesh nodes. The result of this approach is that fine mesh elements are placed automatically in regions of the image containing high-frequency features while coarse mesh elements are used to represent smooth areas. The proposed algorithm is noniterative, fast, and easy to implement. Numerical results demonstrate that, at very low computational cost, the proposed approach can produce mesh representations that are more accurate than those produced by several existing methods. Moreover, it is demonstrated that the proposed algorithm performs well with images of various kinds, even in the presence of noise. PMID:18237961

  5. Accurate measurement of RF exposure from emerging wireless communication systems

    NASA Astrophysics Data System (ADS)

    Letertre, Thierry; Monebhurrun, Vikass; Toffano, Zeno

    2013-04-01

    Isotropic broadband probes or spectrum analyzers (SAs) may be used for the measurement of rapidly varying electromagnetic fields generated by emerging wireless communication systems. In this paper this problematic is investigated by comparing the responses measured by two different isotropic broadband probes typically used to perform electric field (E-field) evaluations. The broadband probes are submitted to signals with variable duty cycles (DC) and crest factors (CF) either with or without Orthogonal Frequency Division Multiplexing (OFDM) modulation but with the same root-mean-square (RMS) power. The two probes do not provide accurate enough results for deterministic signals such as Worldwide Interoperability for Microwave Access (WIMAX) or Long Term Evolution (LTE) as well as for non-deterministic signals such as Wireless Fidelity (WiFi). The legacy measurement protocols should be adapted to cope for the emerging wireless communication technologies based on the OFDM modulation scheme. This is not easily achieved except when the statistics of the RF emission are well known. In this case the measurement errors are shown to be systematic and a correction factor or calibration can be applied to obtain a good approximation of the total RMS power.

  6. Accurate Ritz Wavelengths of Parity-forbidden [Co II] and [V II] Lines of Astrophysical Interest

    NASA Astrophysics Data System (ADS)

    Ruffoni, M. P.; Pickering, J. C.

    2013-08-01

    We report a comprehensive list of accurate Ritz wavelengths for parity-forbidden [Co II] and [V II] lines obtained from the analysis of energy levels measured in the laboratory with Fourier transform emission spectroscopy. Such lines, particularly those in the infrared, are in demand for the analysis of low-density astrophysical plasmas in and around objects such as planetary nebulae, star-forming regions, and active galactic nuclei. Transitions between all known metastable levels of Co II and V II are included in our analysis, producing wavelengths for 1477 [V II] lines and 782 [Co II] lines. Of these, 170 [V II] lines and 171 [Co II] lines arise from transitions with calculated transition probabilities greater than 1 × 10-2 s-1 and upper level excitations of less than 5 eV, and thus are likely to be observed in astrophysical spectra.

  7. ACCURATE RITZ WAVELENGTHS OF PARITY-FORBIDDEN [Co II] AND [V II] LINES OF ASTROPHYSICAL INTEREST

    SciTech Connect

    Ruffoni, M. P.; Pickering, J. C.

    2013-08-15

    We report a comprehensive list of accurate Ritz wavelengths for parity-forbidden [Co II] and [V II] lines obtained from the analysis of energy levels measured in the laboratory with Fourier transform emission spectroscopy. Such lines, particularly those in the infrared, are in demand for the analysis of low-density astrophysical plasmas in and around objects such as planetary nebulae, star-forming regions, and active galactic nuclei. Transitions between all known metastable levels of Co II and V II are included in our analysis, producing wavelengths for 1477 [V II] lines and 782 [Co II] lines. Of these, 170 [V II] lines and 171 [Co II] lines arise from transitions with calculated transition probabilities greater than 1 Multiplication-Sign 10{sup -2} s{sup -1} and upper level excitations of less than 5 eV, and thus are likely to be observed in astrophysical spectra.

  8. Wavenumber Measurements of CO 2 Transitions in 1.5-μm Atmospheric Window Using an External-Cavity Diode Laser

    NASA Astrophysics Data System (ADS)

    Chou, Che-Chung; Lin, Tyson; Shy, Jow-Tsong

    2001-01-01

    Using an external-cavity diode laser (ECDL) as the light source, we have observed the spectrum of CO2 in the 1.5-μm atmospheric window including the (3001)I ← (0000) and (3111)I ← (0110)I bands. Good signal-to-noise ratio allowed us to lock the frequency of our ECDL to the absorption line centers. Wavenumber measurements of the transitions with accuracy about 6.6 × 10-4 cm-1 are made with the help of a precision wavemeter calibrated to the accurate C2H2 frequency references in the 1.5-μm wavelength region. Molecular constants are obtained by making the least-squares fits of the measured transition wavenumbers. The rotational and centrifugal distortion constants are consistent with the previous results using high-resolution Fourier transform spectroscopy. However, the band centers are different with previous results by several thousandth reciprocal centimeters.

  9. ACCURATE CHARACTERIZATION OF HIGH-DEGREE MODES USING MDI OBSERVATIONS

    SciTech Connect

    Korzennik, S. G.; Rabello-Soares, M. C.; Schou, J.; Larson, T. P.

    2013-08-01

    We present the first accurate characterization of high-degree modes, derived using the best Michelson Doppler Imager (MDI) full-disk full-resolution data set available. A 90 day long time series of full-disk 2 arcsec pixel{sup -1} resolution Dopplergrams was acquired in 2001, thanks to the high rate telemetry provided by the Deep Space Network. These Dopplergrams were spatially decomposed using our best estimate of the image scale and the known components of MDI's image distortion. A multi-taper power spectrum estimator was used to generate power spectra for all degrees and all azimuthal orders, up to l = 1000. We used a large number of tapers to reduce the realization noise, since at high degrees the individual modes blend into ridges and thus there is no reason to preserve a high spectral resolution. These power spectra were fitted for all degrees and all azimuthal orders, between l = 100 and l = 1000, and for all the orders with substantial amplitude. This fitting generated in excess of 5.2 Multiplication-Sign 10{sup 6} individual estimates of ridge frequencies, line widths, amplitudes, and asymmetries (singlets), corresponding to some 5700 multiplets (l, n). Fitting at high degrees generates ridge characteristics, characteristics that do not correspond to the underlying mode characteristics. We used a sophisticated forward modeling to recover the best possible estimate of the underlying mode characteristics (mode frequencies, as well as line widths, amplitudes, and asymmetries). We describe in detail this modeling and its validation. The modeling has been extensively reviewed and refined, by including an iterative process to improve its input parameters to better match the observations. Also, the contribution of the leakage matrix on the accuracy of the procedure has been carefully assessed. We present the derived set of corrected mode characteristics, which includes not only frequencies, but line widths, asymmetries, and amplitudes. We present and discuss

  10. Accurate Determination of Torsion and Pure Bending Moment for Viscoelastic Measurements

    NASA Astrophysics Data System (ADS)

    Wang, Yun-Che; Ko, Chih-Chin; Shiau, Li-Ming

    Measurements of time-dependent material properties in the context of linear viscoelasticity, at a given frequency and temperature, require accurate determination of both loading and deformation that are subjected to the testing materials. A pendulum-type viscoelastic spectroscopy is developed to experimentally measure loss tangent and the magnitude of dynamic modulus of solid materials. The mechanical system of the device is based on the behavior of the cantilever beam, and torsion and pure bending moment are generated from the interaction between a permanent magnet and the Helmholtz coils. The strength of the magnetic interactions may be determined with a material with known mechanical properties, such as aluminum 6061T4 alloy. The sensitivity of the torque measurement is on the order of one micro N-m level. With the high accurate torque measurement and deformation detection from a laser-based displacement measurement system, viscoelastic properties of materials can be experimentally measured in different frequency regimes. Sinusoidal driving signals are adopted for measuring complex modulus in the sub-resonant regime, and dc bias driving for creep tests in the low frequency limit. At structural resonant frequencies, the full-width-at-half-maximum (FWHM) method or Lorentzian curve fitting method is adopted to extract material properties. The completion of determining material properties in the wide frequency spectrum may help to identify the deformation mechanisms of the material and to create better models for simulation work.

  11. Towards a scalable and accurate quantum approach for describing vibrations of molecule–metal interfaces

    PubMed Central

    Madebene, Bruno; Ulusoy, Inga; Mancera, Luis; Scribano, Yohann; Chulkov, Sergey

    2011-01-01

    Summary We present a theoretical framework for the computation of anharmonic vibrational frequencies for large systems, with a particular focus on determining adsorbate frequencies from first principles. We give a detailed account of our local implementation of the vibrational self-consistent field approach and its correlation corrections. We show that our approach is both robust, accurate and can be easily deployed on computational grids in order to provide an efficient computational tool. We also present results on the vibrational spectrum of hydrogen fluoride on pyrene, on the thiophene molecule in the gas phase, and on small neutral gold clusters. PMID:22003450

  12. Searching for an Oscillating Massive Scalar Field as a Dark Matter Candidate Using Atomic Hyperfine Frequency Comparisons

    NASA Astrophysics Data System (ADS)

    Hees, A.; Guéna, J.; Abgrall, M.; Bize, S.; Wolf, P.

    2016-08-01

    We use 6 yrs of accurate hyperfine frequency comparison data of the dual rubidium and caesium cold atom fountain FO2 at LNE-SYRTE to search for a massive scalar dark matter candidate. Such a scalar field can induce harmonic variations of the fine structure constant, of the mass of fermions, and of the quantum chromodynamic mass scale, which will directly impact the rubidium/caesium hyperfine transition frequency ratio. We find no signal consistent with a scalar dark matter candidate but provide improved constraints on the coupling of the putative scalar field to standard matter. Our limits are complementary to previous results that were only sensitive to the fine structure constant and improve them by more than an order of magnitude when only a coupling to electromagnetism is assumed.

  13. Searching for an Oscillating Massive Scalar Field as a Dark Matter Candidate Using Atomic Hyperfine Frequency Comparisons.

    PubMed

    Hees, A; Guéna, J; Abgrall, M; Bize, S; Wolf, P

    2016-08-01

    We use 6 yrs of accurate hyperfine frequency comparison data of the dual rubidium and caesium cold atom fountain FO2 at LNE-SYRTE to search for a massive scalar dark matter candidate. Such a scalar field can induce harmonic variations of the fine structure constant, of the mass of fermions, and of the quantum chromodynamic mass scale, which will directly impact the rubidium/caesium hyperfine transition frequency ratio. We find no signal consistent with a scalar dark matter candidate but provide improved constraints on the coupling of the putative scalar field to standard matter. Our limits are complementary to previous results that were only sensitive to the fine structure constant and improve them by more than an order of magnitude when only a coupling to electromagnetism is assumed. PMID:27541455

  14. VizieR Online Data Catalog: Ketenimine (CH2CNH) submm rest-frequencies (Degli Esposti+, 2014)

    NASA Astrophysics Data System (ADS)

    Degli Esposti, C.; Dore, L.; Bizzocchi, L.

    2014-04-01

    Imine compounds are thought to have a role in the interstellar formation of complex organic species, including pre-biotic molecules. Ketenimine (CH2CNH) is one of the four imines discovered in space. It was identified in Sgr B2(N-LMH) through the detection of three rotational lines in absorption. We present an extensive laboratory study of the ground-state rotational spectrum of CH2CNH at submillimetre wavelengths, aimed at obtaining accurate rest-frequencies for radio-astronomical searches. The investigation was carried out using a source-modulation microwave spectrometer equipped with a cell that is coupled to a pyrolysis apparatus working at 1000°. The spectrum was recorded in the frequency range 80-620GHz with the detection of 150 transitions. (2 data files).

  15. Are National HFC Inventory Reports Accurate?

    NASA Astrophysics Data System (ADS)

    Lunt, M. F.; Rigby, M. L.; Ganesan, A.; Manning, A.; O'Doherty, S.; Prinn, R. G.; Saito, T.; Harth, C. M.; Muhle, J.; Weiss, R. F.; Salameh, P.; Arnold, T.; Yokouchi, Y.; Krummel, P. B.; Steele, P.; Fraser, P. J.; Li, S.; Park, S.; Kim, J.; Reimann, S.; Vollmer, M. K.; Lunder, C. R.; Hermansen, O.; Schmidbauer, N.; Young, D.; Simmonds, P. G.

    2014-12-01

    Hydrofluorocarbons (HFCs) were introduced as replacements for ozone depleting chlorinated gases due to their negligible ozone depletion potential. As a result, these potent greenhouse gases are now rapidly increasing in atmospheric mole fraction. However, at present, less than 50% of HFC emissions, as inferred from models combined with atmospheric measurements (top-down methods), can be accounted for by the annual national reports to the United Nations Framework Convention on Climate Change (UNFCCC). There are at least two possible reasons for the discrepancy. Firstly, significant emissions could be originating from countries not required to report to the UNFCCC ("non-Annex 1" countries). Secondly, emissions reports themselves may be subject to inaccuracies. For example the HFC emission factors used in the 'bottom-up' calculation of emissions tend to be technology-specific (refrigeration, air conditioning etc.), but not tuned to the properties of individual HFCs. To provide a new top-down perspective, we inferred emissions using high frequency HFC measurements from the Advanced Global Atmospheric Gases Experiment (AGAGE) and the National Institute for Environmental Studies (NIES) networks. Global and regional emissions information was inferred from these measurements using a coupled Eulerian and Lagrangian system, based on NCAR's MOZART model and the UK Met Office NAME model. Uncertainties in this measurement and modelling framework were investigated using a hierarchical Bayesian inverse method. Global and regional emissions estimates for five of the major HFCs (HFC-134a, HFC-125, HFC-143a, HFC-32, HFC-152a) from 2004-2012 are presented. It was found that, when aggregated, the top-down estimates from Annex 1 countries agreed remarkably well with the reported emissions, suggesting the non-Annex 1 emissions make up the difference with the top-down global estimate. However, when these HFC species are viewed individually we find that emissions of HFC-134a are over

  16. Effect of intermolecular potential on compressible Couette flow in slip and transitional regimes

    NASA Astrophysics Data System (ADS)

    Weaver, Andrew B.; Venkattraman, A.; Alexeenko, Alina A.

    2014-10-01

    The effect of intermolecular potentials on compressible, planar flow in slip and transitional regimes is investigated using the direct simulation Monte Carlo method. Two intermolecular interaction models, the variable hard sphere (VHS) and the Lennard-Jones (LJ) models, are first compared for subsonic and supersonic Couette flows of argon at temperatures of 40, 273, and 1,000 K, and then for Couette flows in the transitional regime ranging from Knudsen numbers (Kn) of 0.0051 to 1. The binary scattering model for elastic scattering using the Lennard-Jones (LJ) intermolecular potential proposed recently [A. Venkattraman and A. Alexeenko, "Binary scattering model for Lennard-Jones potential: Transport coefficients and collision integrals for non-equilibrium gas flow simulations," Phys. Fluids 24, 027101 (2012)] is shown to accurately reproduce both the theoretical collision frequency in an equilibrium gas as well as the theoretical viscosity variation with temperature. The use of a repulsive-attractive instead of a purely repulsive potential is found to be most important in the continuum and slip regimes as well as in flows with large temperature variations. Differences in shear stress of up to 28% between the VHS and LJ models is observed at Kn=0.0051 and is attributed to differences in collision frequencies, ultimately affecting velocity gradients at the wall. For Kn=1 where the Knudsen layer expands the entire domain, the effect of the larger collision frequency in the LJ model relative to VHS diminishes, and a 7% difference in shear stress is observed.

  17. PIC-MCC Simulations of Capacitive High-Frequency Discharge Dynamics with Nanoparticles

    NASA Astrophysics Data System (ADS)

    Schweigert, Irina V.

    A new combined particle-in-cell Monte Carlo collision (PIC-MCC) approach is discussed for accurate and fast simulation of a radio-frequency (rf) discharge at a low gas pressure and high plasma density. Test calculations of the heating mode transition in a capacitively coupled rf-discharge in helium and argon show a good agreement with experimental data. The combined PIC-MCC algorithm is very efficient, especially for the collisionless regime of electron heating. Using this algorithm, the properties of a capacitively coupled 13.56 MHz discharge are studied in a mixture of Ar/C2H2 with nanoparticles of different sizes. For the description of plasma-dust interaction a kinetic model is introduced. The dust surface potential and discharge parameters are calculated self-consistently. In this model, any assumption about electron and ion energy distribution functions is not used. This allows us to calculate accurately the dust particle charging. The transport of dust is calculated by using the fluid approach. It is shown that at the initial stage of the growth, nanoparticles are accumulated near the sheath-plasma boundaries, where the ionization rate has maximum value. The nanoparticles suppress the ionization due to the absorbing of fast electrons and stimulate a quick change of the plasma parameters followed by the transition between different modes of discharge operation.

  18. Radioactive transitions in the helium isoelectronic sequence

    NASA Technical Reports Server (NTRS)

    Dalgarno, A.

    1971-01-01

    The principles of the atomic spectrum theory are used to quantitatively analyze radiation transitions in two-electron helium-like atomic systems. Quantum theoretical methods, describing absorption and emission of a single photon in a radiative transition between two stationary states of an atomic system, reproduced the energy level diagram for the low lying states of helium. Reliable values are obtained from accurate variationally determined two-electron nonrelativistic wave functions for radiative transition probabilities of 2 3p states in the helium isoelectric sequence, and for the 2 1s and 2 3s1 states of the helium sequence.

  19. Organ vascularity and metastatic frequency.

    PubMed Central

    Weiss, L.; Haydock, K.; Pickren, J. W.; Lane, W. W.

    1980-01-01

    The "hemodynamic" or "mechanical" theory proposes that the frequency of metastases in different organs is primarily determined by the numbers of cancer cells delivered to them in their arterial blood. This theory has not yet been adequately tested in man because reproducible, noninvasive measurements of organ blood flow have only recently become available. Correlation between these data and the metastatic frequency in 10 organs, in groups of patients with primary cancers in 15 anatomic sites, has therefore been sought. No correlation was obtained between metastatic frequency and organ weights, blood volumes, blood volumes per gram, "transit times," or blood flow. However, correlations significant at the 4-8% level were obtained between organ blood flow per gram and metastatic frequency in 4 of 5 groups of primary cancers with initial venous drainage into the portal system, compared with 1 of 10 draining into the caval system. At present, no definitive explanation can be offered for the apparent compliance of one set of primary cancers with the "hemodynamic" theory of metastasis, but not the others. PMID:7446696

  20. Frequency-comb referenced spectroscopy of v₄₋ and v₅₋excited hot bands in the 1.5 and μm spectrum of C₂H₂

    SciTech Connect

    Twagirayezu, Sylvestre; Cich, Matthew J.; Sears, Trevor J.; McRaven, Christopher P.; Hall, Gregory E.

    2015-07-14

    Doppler-free transition frequencies for v₄₋ and v₅₋excited hot bands have been measured in the v₁ + v₃ band region of the spectrum of acetylene using saturation dip spectroscopy with an extended cavity diode laser referenced to a frequency comb. The frequency accuracy of the measured transitions, as judged from line shape model fits and comparison to known frequencies in the v₁ + v₃ band itself, is between 3 and 22 kHz. This is some three orders of magnitude improvement on the accuracy and precision of previous line position estimates that were derived from the analysis of high-resolution Fourier transform infrared absorption spectra. Comparison to transition frequencies computed from constants derived from published Fourier transform infrared spectra shows that some upper rotational energy levels suffer specific perturbations causing energy level shifts of up to several hundred MHz. These perturbations are due to energy levels of the same rotational quantum number derived from nearby vibrational levels that become degenerate at specific energies. Future identification of the perturbing levels will provide accurate relative energies of excited vibrational levels of acetylene in the 7100–7600 cm⁻¹ energy region.