Science.gov

Sample records for acid fracture conductivity

  1. Hydraulic conductivity of rock fractures

    SciTech Connect

    Zimmerman, R.W.; Bodvarsson, G.S.

    1994-10-01

    Yucca Mountain, Nevada contains numerous geological units that are highly fractured. A clear understanding of the hydraulic conductivity of fractures has been identified as an important scientific problem that must be addressed during the site characterization process. The problem of the flow of a single-phase fluid through a rough-walled rock fracture is discussed within the context of rigorous fluid mechanics. The derivation of the cubic law is given as the solution to the Navier-Stokes equations for flow between smooth, parallel plates, the only fracture geometry that is amenable to exact treatment. The various geometric and kinetic conditions that are necessary in order for the Navier-Stokes equations to be replaced by the more tractable lubrication or Hele-Shaw equations are studied and quantified. Various analytical and numerical results are reviewed pertaining to the problem of relating the effective hydraulic aperture to the statistics of the aperture distribution. These studies all lead to the conclusion that the effective hydraulic aperture is always less than the mean aperture, by a factor that depends on the ratio of the mean value of the aperture to its standard deviation. The tortuosity effect caused by regions where the rock walls are in contact with each other is studied using the Hele-Shaw equations, leading to a simple correction factor that depends on the area fraction occupied by the contact regions. Finally, the predicted hydraulic apertures are compared to measured values for eight data sets from the literature for which aperture and conductivity data were available on the same fracture. It is found that reasonably accurate predictions of hydraulic conductivity can be made based solely on the first two moments of the aperture distribution function, and the proportion of contact area. 68 refs.

  2. Well-test analysis following a closed-fracture acidizing treatment

    SciTech Connect

    Daneshi, T. ); Soliman, M.Y.; Hunt, J.L. )

    1990-12-01

    A model representing fluid flow in a reservoir treated with closed-fracture acidizing (CFA) is presented. The model is characterized by a low-conductivity fracture (representing the closed fracture) and highly conductive wormholes (owing to acid flow). Application of the model to pressure-transient data analysis following a CFA treatment is presented through a field example.

  3. Estimating the hydraulic conductivity of two-dimensional fracture networks

    NASA Astrophysics Data System (ADS)

    Leung, C. T.; Zimmerman, R. W.

    2010-12-01

    Most oil and gas reservoirs, as well as most potential sites for nuclear waste disposal, are naturally fractured. In these sites, the network of fractures will provide the main path for fluid to flow through the rock mass. In many cases, the fracture density is so high as to make it impractical to model it with a discrete fracture network (DFN) approach. For such rock masses, it would be useful to have recourse to analytical, or semi-analytical, methods to estimate the macroscopic hydraulic conductivity of the fracture network. We have investigated single-phase fluid flow through stochastically generated two-dimensional fracture networks. The centres and orientations of the fractures are uniformly distributed, whereas their lengths follow either a lognormal distribution or a power law distribution. We have considered the case where the fractures in the network each have the same aperture, as well as the case where the aperture of each fracture is directly proportional to the fracture length. The discrete fracture network flow and transport simulator NAPSAC, developed by Serco (Didcot, UK), is used to establish the “true” macroscopic hydraulic conductivity of the network. We then attempt to match this conductivity using a simple estimation method that does not require extensive computation. For our calculations, fracture networks are represented as networks composed of conducting segments (bonds) between nodes. Each bond represents the region of a single fracture between two adjacent intersections with other fractures. We assume that the bonds are arranged on a kagome lattice, with some fraction of the bonds randomly missing. The conductance of each bond is then replaced with some effective conductance, Ceff, which we take to be the arithmetic mean of the individual conductances, averaged over each bond, rather than over each fracture. This is in contrast to the usual approximation used in effective medium theories, wherein the geometric mean is used. Our

  4. Numerical modeling of thermal conductive heating in fractured bedrock.

    PubMed

    Baston, Daniel P; Falta, Ronald W; Kueper, Bernard H

    2010-01-01

    Numerical modeling was employed to study the performance of thermal conductive heating (TCH) in fractured shale under a variety of hydrogeological conditions. Model results show that groundwater flow in fractures does not significantly affect the minimum treatment zone temperature, except near the beginning of heating or when groundwater influx is high. However, fracture and rock matrix properties can significantly influence the time necessary to remove all liquid water (i.e., reach superheated steam conditions) in the treatment area. Low matrix permeability, high matrix porosity, and wide fracture spacing can contribute to boiling point elevation in the rock matrix. Consequently, knowledge of these properties is important for the estimation of treatment times. Because of the variability in boiling point throughout a fractured rock treatment zone and the absence of a well-defined constant temperature boiling plateau in the rock matrix, it may be difficult to monitor the progress of thermal treatment using temperature measurements alone. PMID:20550586

  5. Performance of vertical fractured wells with multiple finite-conductivity fractures

    NASA Astrophysics Data System (ADS)

    Ren, Junjie; Guo, Ping

    2015-12-01

    Multiple fractures originating from a vertical wellbore are usually observed in hydraulic fracturing treatments. Most of the previous models for vertical fractured wells are based on single-planar fractures that may be symmetric or asymmetric about the wellbore, but few studies have been devoted to multiple-planar fractures. This paper presents a new semi-analytical solution in Laplace space for the pressure responses of a vertical fractured well, producing at a constant flow rate through multiple finite-conductivity fractures. The solution is presented in Laplace space so that the effects of the wellbore storage and skin factor can be easily incorporated by Duhamel’s principle, and then the solution in real space can be obtained using the numerical inversion algorithm proposed by Stehfest. Pressure response curves are plotted and the effects of the relevant parameters on these are analyzed. It is found that with the increase of the fracture number, smaller pressure depletion will appear under the same conditions, and the interaction between fractures takes place much earlier and becomes much stronger. We find that with the increase of the fracture number, the duration of the wellbore storage period becomes shorter, and the bilinear flow appears earlier. Decreasing the angles between fractures and increasing the fracture asymmetry coefficient will lead to a stronger interaction between them, and will then affect the bilinear flow and linear flow behaviors. The present model can be used to interpret the pressure data of the vertical fractured wells with multiple fractures and to provide more accurate dynamic parameters.

  6. Partially penetrating fractures: Pressure transient analysis of an infinite conductivity fracture

    SciTech Connect

    Rodriguez, F.; Cinco-Ley, H.; Horne, R.N.

    1984-04-01

    The effect of the partial penetration of an infinite conductivity fracture on the transient pressure behavior of a vertically fractured well is investigated. Analysis of results shows that the pressure behavior of a well intersected by a partially-penetrating infinite conductivity vertical fracture can be divided into three flow periods: 1) the early time flow period which is characterized by a formation linear flow as in the case of a fully-penetrating infinite-conductivity vertical fracture, 2) the infinite-acting flow period and 3) the pseudoradial flow period which develops after the effects of the vertical boundaries of the reservoir are felt in the pressure behavior of the well. A log-log graph of log(h /SUB f/ /h)p /SUB wD/ versus log t /SUB Dxf/ shows a slope of one half during the early time flow period of a well with an infinite-conductivity partially penetrating fracture. The time for the end of the early time flow period is directly related to the square of the dimensionless height of the fracture, h /SUB fD/, which is defined as the ratio between the height of the fracture and its half length.

  7. Measurement of Fracture Geometry for Accurate Computation of Hydraulic Conductivity

    NASA Astrophysics Data System (ADS)

    Chae, B.; Ichikawa, Y.; Kim, Y.

    2003-12-01

    Fluid flow in rock mass is controlled by geometry of fractures which is mainly characterized by roughness, aperture and orientation. Fracture roughness and aperture was observed by a new confocal laser scanning microscope (CLSM; Olympus OLS1100). The wavelength of laser is 488nm, and the laser scanning is managed by a light polarization method using two galvano-meter scanner mirrors. The system improves resolution in the light axis (namely z) direction because of the confocal optics. The sampling is managed in a spacing 2.5 μ m along x and y directions. The highest measurement resolution of z direction is 0.05 μ m, which is the more accurate than other methods. For the roughness measurements, core specimens of coarse and fine grained granites were provided. Measurements were performed along three scan lines on each fracture surface. The measured data were represented as 2-D and 3-D digital images showing detailed features of roughness. Spectral analyses by the fast Fourier transform (FFT) were performed to characterize on the roughness data quantitatively and to identify influential frequency of roughness. The FFT results showed that components of low frequencies were dominant in the fracture roughness. This study also verifies that spectral analysis is a good approach to understand complicate characteristics of fracture roughness. For the aperture measurements, digital images of the aperture were acquired under applying five stages of uniaxial normal stresses. This method can characterize the response of aperture directly using the same specimen. Results of measurements show that reduction values of aperture are different at each part due to rough geometry of fracture walls. Laboratory permeability tests were also conducted to evaluate changes of hydraulic conductivities related to aperture variation due to different stress levels. The results showed non-uniform reduction of hydraulic conductivity under increase of the normal stress and different values of

  8. Hydraulic characterization for steam enhanced remediation conducted in fractured rock.

    PubMed

    Stephenson, Kyle M; Novakowski, Kent; Davis, Eva; Heron, Gorm

    2006-01-10

    To explore the viability of Steam Enhanced Remediation (SER) in fractured rock a small-scale steam injection and water/vapour extraction pilot study was conducted at the former Loring Air Force Base in northern Maine, USA. A detailed well testing program was undertaken to assist in the design of the injection and extraction well array, and to assess the possibility of off-site heat and contaminant migration. A structurally complex limestone having low matrix porosity and a sparse distribution of fractures underlies the study site. To characterize the groundwater and steam flow pathways, single-well slug tests and more than 100 pulse interference tests were conducted. The results of the well testing indicate that the study site is dominated by steeply dipping bedding plane fractures that are interconnected only between some wells in the injection/extraction array. The SER system was designed to take advantage of interconnected fractures located at depth in the eastern end of the site. An array of 29 wells located in an area of 60 by 40 m was used for steam injection and water/vapour extraction. The migration of heat was monitored in several wells using thermistor arrays having a 1.5 m vertical spacing. Temperature measurements obtained during and after the 3 month steam injection period showed that heat migration generally occurred along those fracture features identified by the pulse interference testing. Based on these results, it is concluded that the pulse interference tests were valuable in assisting with the design of the injection/extraction well geometry and in predicting the migration pathways of the hot water associated with the steam injection. The pulse interference test method should also prove useful in support of any other remedial method dependant on the fracture network for delivery of remedial fluid or extraction of contaminants. PMID:16310888

  9. Proton conducting membrane using a solid acid

    NASA Technical Reports Server (NTRS)

    Haile, Sossina M. (Inventor); Chisholm, Calum (Inventor); Boysen, Dane A. (Inventor); Narayanan, Sekharipuram R. (Inventor)

    2006-01-01

    A solid acid material is used as a proton conducting membrane in an electrochemical device. The solid acid material can be one of a plurality of different kinds of materials. A binder can be added, and that binder can be either a nonconducting or a conducting binder. Nonconducting binders can be, for example, a polymer or a glass. A conducting binder enables the device to be both proton conducting and electron conducting.

  10. Proton conducting membrane using a solid acid

    NASA Technical Reports Server (NTRS)

    Chisholm, Calum (Inventor); Narayanan, Sekharipuram R. (Inventor); Boysen, Dane (Inventor); Haile, Sossina M. (Inventor)

    2002-01-01

    A solid acid material is used as a proton conducting membrane in an electrochemical device. The solid acid material can be one of a plurality of different kinds of materials. A binder can be added, and that binder can be either a nonconducting or a conducting binder. Nonconducting binders can be, for example, a polymer or a glass. A conducting binder enables the device to be both proton conducting and electron conducting. The solid acid material has the general form M.sub.a H.sub.b (XO.sub.t).sub.c.

  11. Simulated evolution of fractures and fracture networks subject to thermal cooling: A coupled discrete element and heat conduction model

    SciTech Connect

    Huang, Hai; Plummer, Mitchell; Podgorney, Robert

    2013-02-01

    Advancement of EGS requires improved prediction of fracture development and growth during reservoir stimulation and long-term operation. This, in turn, requires better understanding of the dynamics of the strongly coupled thermo-hydro-mechanical (THM) processes within fractured rocks. We have developed a physically based rock deformation and fracture propagation simulator by using a quasi-static discrete element model (DEM) to model mechanical rock deformation and fracture propagation induced by thermal stress and fluid pressure changes. We also developed a network model to simulate fluid flow and heat transport in both fractures and porous rock. In this paper, we describe results of simulations in which the DEM model and network flow & heat transport model are coupled together to provide realistic simulation of the changes of apertures and permeability of fractures and fracture networks induced by thermal cooling and fluid pressure changes within fractures. Various processes, such as Stokes flow in low velocity pores, convection-dominated heat transport in fractures, heat exchange between fluid-filled fractures and solid rock, heat conduction through low-permeability matrices and associated mechanical deformations are all incorporated into the coupled model. The effects of confining stresses, developing thermal stress and injection pressure on the permeability evolution of fracture and fracture networks are systematically investigated. Results are summarized in terms of implications for the development and evolution of fracture distribution during hydrofracturing and thermal stimulation for EGS.

  12. Zoledronic Acid in Reducing Clinical Fracture and Mortality after Hip Fracture

    PubMed Central

    Lyles, Kenneth W.; Colón-Emeric, Cathleen S.; Magaziner, Jay S.; Adachi, Jonathan D.; Pieper, Carl F.; Mautalen, Carlos; Hyldstrup, Lars; Recknor, Chris; Nordsletten, Lars; Moore, Kathy A.; Lavecchia, Catherine; Zhang, Jie; Mesenbrink, Peter; Hodgson, Patricia K.; Abrams, Ken; Orloff, John J.; Horowitz, Zebulun; Eriksen, Erik Fink; Boonen, Steven

    2008-01-01

    BACKGROUND Mortality is increased after a hip fracture, and strategies that improve outcomes are needed. METHODS In this randomized, double-blind, placebo-controlled trial, 1065 patients were assigned to receive yearly intravenous zoledronic acid (at a dose of 5 mg), and 1062 patients were assigned to receive placebo. The infusions were first administered within 90 days after surgical repair of a hip fracture. All patients received supplemental vitamin D and calcium. The median follow-up was 1.9 years. The primary end point was a new clinical fracture. RESULTS The rates of any new clinical fracture were 8.6% in the zoledronic acid group and 13.9% in the placebo group, a 35% risk reduction (P = 0.001); the respective rates of a new clinical vertebral fracture were 1.7% and 3.8% (P = 0.02), and the respective rates of new nonvertebral fractures were 7.6% and 10.7% (P = 0.03). In the safety analysis, 101 of 1054 patients in the zoledronic acid group (9.6%) and 141 of 1057 patients in the placebo group (13.3%) died, a reduction of 28% in deaths from any cause in the zoledronic-acid group (P = 0.01). The most frequent adverse events in patients receiving zoledronic acid were pyrexia, myalgia, and bone and musculoskeletal pain. No cases of osteonecrosis of the jaw were reported, and no adverse effects on the healing of fractures were noted. The rates of renal and cardiovascular adverse events, including atrial fibrillation and stroke, were similar in the two groups. CONCLUSIONS An annual infusion of zoledronic acid within 90 days after repair of a low-trauma hip fracture was associated with a reduction in the rate of new clinical fractures and improved survival. (ClinicalTrials.gov number, NCT00046254.) PMID:18427590

  13. Conductance Studies of Aqueous Succinic Acid

    NASA Astrophysics Data System (ADS)

    Apelblat, Alexander; Barthel, Josef

    1992-03-01

    Conductance measurements of aqueous solutions of succinic acid and of di-sodium succinate were performed from 278.15 to 308.15 K and the limiting conductances λ0 (1/2 Succ2- ) are reported. The Waiden product is independent of temperature: λ0(1/2 Succ2-)*η(T) = 0.503 ± 0.001. The salt conductances closely obey the Onsager limiting law. The evaluation of the equilibrium constants for the primary and secondary steps of dissociation, K1 and K2, and the limiting conductances of the hydrosuccinate ion, λ0(HSucc-), are discussed using the Quint and Viallard conductance equation

  14. Potentially Conductive Channels in Fracture Cements of Low Permeability Rocks

    NASA Astrophysics Data System (ADS)

    Wright, E.; Landry, C. J.; Eichhubl, P.

    2015-12-01

    Natural fractures in shale reservoirs are frequently filled with mineral cement that lacks any residual fracture porosity that is visible under the petrographic microscope. These fully cemented fractures are generally interpreted to be impermeable for fluid flow. Scanning electron microscopy of calcite, dolomite, and barite fracture cements from a variety of shale reservoirs, prepared using broad ion beam milling, provides evidence of open to partially healed elongate pores that are on the order of hundreds of nanometers in aperture. In calcite fracture cement, these pores have consistent apertures of about 100 nm. In dolomite and barite, apertures are up to 500 nm. These pores have been previously overlooked because traditional thin sectioning and polishing destroys sub-micron details of the fracture cement pore structure. Ion milling preserves these details with a minimum of sample damage during sample preparation. Electron backscatter diffraction shows that these pores occur along grain boundaries within the blocky or columnar fracture cement. While partially healed, these pores, arranged along grain boundaries, are frequently sufficiently well connected acting as channels for fluid flow along and across fully cemented natural fractures. In shale reservoirs of ultra-low matrix permeability, these grain boundary channels may thus provide fracture permeability significantly contributing to reservoir production where intersected or indirectly reactivated by hydraulic fractures.

  15. Conductance Studies on Aqueous Citric Acid

    NASA Astrophysics Data System (ADS)

    Apelblat, Alexander; Barthel, Josef

    1991-02-01

    Conductance measurements of citric acid and neutral citrates (tri-lithium citrate, tri-sodium citrate and tri-potassium citrate) were performed in water at 278.15 to 308.15 K. The equilibrium constants for the primary and secondary steps of dissociation, Kx and K2, and the limiting conductances, λ0(H2Cit-), λ°(1/2 HCit2-), and λ0(1/3 Cit3-) are reported as a function of temperature. They are obtained by application of the Quint and Viallard conductance equation. The enthalpies of dissociation are estimated.

  16. HYDRAULIC CHARACTERIZATION FOR STEAM ENHANCED REMEDIATION CONDUCTED IN FRACTURED ROCK

    EPA Science Inventory

    Remediation of fractured rock sites contaminated by non-aqueous phase liquids has long been recognized as the most difficult undertaking of any site clean-up. This is primarily the result of the complexity of the fracture framework, which governs the groundwater flow pathways and...

  17. Transient pressure behavior for a horizontal well with multiple finite-conductivity fractures in tight reservoirs

    NASA Astrophysics Data System (ADS)

    Guo, Jingjing; Wang, Haitao; Zhang, Liehui

    2015-08-01

    Horizontal drilling and multi-stage hydraulic fracturing have been common and efficient practices in exploitation of tight reservoirs. Establishing corresponding mathematical models and analyzing transient pressure behaviors of this type of well-reservoir configuration can provide a better understanding of fluid flow patterns in formation as well as estimations of important parameters. Most current models proposed for fractured horizontal wells in tight reservoirs do not incorporate either reservoir permeability loss during the production, which is believed to be non-ignorable or finite conductivity of hydraulic fractures. A coupling model for a multi-fractured horizontal well (MFHW) in tight reservoirs is presented in this article, in which finite conductivity of hydraulic fractures and stress-dependant reservoir permeability are taken into account simultaneously. A semi-analytical solution is obtained in the Laplace domain by using source function theory, Laplace transformation, perturbation technique, discretization of fractures, and superposition principle. Analysis of transient pressure responses indicates that several characteristic flow periods of fractured horizontal wells in tight reservoirs can be identified, including linear flow in fracture, bi-linear flow, linear flow in reservoir, pseudo-radial flow around fractures, and pseudo-radial flow around the horizontal wellbore and fractures. Parametric analysis shows that fracture conductivity, fracture spacing, fracture length, permeability modulus, and skin effect can significantly influence the transient pressure responses of fractured horizontal wells in tight reservoirs. The model presented in this article can be applied to obtain important parameters pertinent to reservoir or fractures by type curve matching, and it can also provide useful information for optimizing fracture parameters. Finally, the model presented in this article can also be easily extended to dual-porosity cases.

  18. Electrical conductivity of acidic sulfate solution

    NASA Astrophysics Data System (ADS)

    Majima, Hiroshi; Peters, Ernest; Awakura, Yasuhiro; Park, Sung Kook

    1987-03-01

    The electrical conductivities of the aqueous solution system of H2SO4-MSO4 (involving ZnSO4, MgSO4, Na2SO4, and (NH4)2SO4), reported by Tozawa et al., were examined in terms of a (H2O) and H+ ion concentration. The equations to compute the concentrations of various species in aqueous sulfuric acid solutions containing metal sulfates were derived for a typical example of the H2SO4-ZnSO4-MgSO4-(Na2SO4)-H2O system. It was found that the H+ ion concentrations in concentrated sulfuric acid solutions corresponding to practical zinc electrowinning solutions are very high and remain almost constant with or without the addition of metal sulfates. The addition of metal sulfates to aqueous sulfuric acid solution causes a decrease in electrical conductivity, and this phenomenon is attributed to a decrease in water activity, which reflects a decrease in the amount of free water. The relationship between conductivity and water activity at a constant H+ ion concentration is independent of the kind of sulfates added. On the other hand, any increase in H+ ion concentration results in an increase in electrical conductivity. A novel method for the prediction of electrical conductivity of acidic sulfate solution is proposed that uses the calculated data of water activity and the calculated H+ ion concentration. Also, the authors examined an extension of the Robinson-Bower equation to calculate water activity in quarternary solutions based on molarity instead of molality, and found that such calculated values are in satisfactory agreement with those determined experimentally by a transpiration method.

  19. A borehole fluid conductivity logging method for the determination of fracture inflow parameters

    SciTech Connect

    Tsang, Chin-Fu

    1987-10-01

    It is of much current interest to determine the flow characteristics of fractures intersecting a wellbore to provide data in the estimation of the hydrologic behavior of fractured rocks. The fluid inflow rates from the fractures into the wellbore are important quantities to measure. Often these inflows are at very low rates. One often finds that only a few percent of the fractures identified by core inspection and geophysical logging are water-conducting fractures, the rest being closed, clogged, or isolated from the water flow system. A new procedure is proposed and a corresponding method of analysis developed to locate water-conducting fractures and obtain fracture inflow parameters by means of a time sequence of electric conductivity logs of the borehole fluid. The physical basis of the analysis method is discussed. The procedure is applied to an existing set of data, which shows initiation and growth of nine conductivity peaks in a 900-m section of a 1690-m borehole, corresponding to nine water-conducting fractures intersecting the borehole. We are able to match all nine peaks and determine the flow rates from these fractures. 16 refs., 28 figs., 5 tabs.

  20. The Apparent Conductivity for Steady Unsaturated Flow in Periodically Fractured Porous Media

    NASA Astrophysics Data System (ADS)

    Martinez, M. J.; Dykhuizen, R. C.; Eaton, R. R.

    1992-11-01

    The influence of horizontal fractures on the steady seepage of moisture in variably saturated porous media is analyzed by analytical and numerical means. The fractures are assumed to contain many open (dry) regions, and to be distributed periodically in two dimensions. The dry regions of the fracture form a barrier to moisture flow through the geologic medium. An idealized two-dimensional model that maximizes the barrier effect of the fractures is analyzed. The results of the analysis quantify the effect of the dry regions of the fractures on global water flow through the fractured medium. An apparent conductivity is determined such that the fractured system can be replaced by a homogeneous medium for describing steady unsaturated flow. An asymptotic analysis yields an analytic expression for the apparent hydraulic conductivity through such a system in the limit of small sorptive number (fracture spacing divided by a characteristic capillary suction) for the intact matrix material. The apparent hydraulic conductivity for arbitrary spacing and sorptive number is determined by numerical means. The numerical model accounts for variable hydraulic conductivity as a function of the local pressure head, whereas the asymptotic solution represents the limit of constant conductivity. The numerical results confirm the analytical solution as a lower bound on the apparent hydraulic conductivity.

  1. Increased fracture penetration and productivity using xanthan gelled acid in massive carbonate formations

    SciTech Connect

    Molon, J.P.; Fox, K.B.

    1983-03-01

    A measurable improvement in productivity can be achieved using xanthan gelled acid to stimulate carbonate formations. Well productivity results were compared to conventional acid fracture treatments. The significant improvements over classical acid fracturing techniques are due to the improved control of acid leakoff rates, retarded reaction rate and improved fracture width maintenance. The difficulties involved in acid fracturing massive Middle East carbonate formations are discussed and solutions are proposed using gelled acid technology. Some limitations in computer predictions of acid fracturing results are also discussed.

  2. Atypical femoral fracture following zoledronic acid treatment.

    PubMed

    Ataoğlu, Baybars; Kaptan, Ahmet Yiğit; Eren, Toygun Kağan; Yapar, Ali Ekber; Berkay, Ahmet Fırat

    2016-04-01

    A 68-year-old female patient admitted to our clinic with right anterior thigh pain ongoing for six months and which increased in last two months. The patient had no trauma history. The patient had been followed-up for 15 years because of osteoporosis and administrated alendronate and ibandronate treatment for 10 years. Patient had three shots of zoledronate once a year during the last three years. Her pain was increasing when she was walking. Physical examination revealed pain in her right thigh. Radiogram showed thickened lateral cortex of the subtrochanteric area. Magnetic resonance imaging also showed thickening and edema of the same area. These images were correlated with atypical fracture in right femoral subthrochanteric zone. Dual energy X-ray absorptiometry revealed that T score was -3.3 in lumbar region and -2.5 in femoral neck. Zoledronate treatment was ended. Prophylactic surgical fixation was performed with titanium elastic nails. PMID:26874637

  3. SIMPLE ANALYTICAL MODEL FOR HEAT FLOW IN FRACTURES - APPLICATION TO STEAM ENHANCED REMEDIATION CONDUCTED IN FRACTURED ROCK

    EPA Science Inventory

    Remediation of fractured rock sites contaminated by non-aqueous phase liquids has long been recognized as the most difficult undertaking of any site clean-up. Recent pilot studies conducted at the Edwards Air Force Base in California and the former Loring Air Force Base in Maine ...

  4. SIMPLE ANALYTICAL MODEL FOR HEAT FLOW IN FRACTURES-APPLICATION TO STEAM ENHANCED REMEDIATION CONDUCTED IN FRACTURED ROCK

    EPA Science Inventory

    Remediation of fractured rock sites contaminated by non-aqueous phase liquids has long been recognized as the most difficult undertaking of any site clean-up. Recent pilot studies conducted at the Edwards Air Force Base in California and the former Loring Air Force Base in Maine ...

  5. Effects of Boric Acid on Fracture Healing: An Experimental Study.

    PubMed

    Gölge, Umut Hatay; Kaymaz, Burak; Arpaci, Rabia; Kömürcü, Erkam; Göksel, Ferdi; Güven, Mustafa; Güzel, Yunus; Cevizci, Sibel

    2015-10-01

    Boric acid (BA) has positive effects on bone tissue. In this study, the effects of BA on fracture healing were evaluated in an animal model. Standard closed femoral shaft fractures were created in 40 male Sprague-Dawley rats under general anesthesia. The rats were allocated into five groups (n = 8 each): group 1, control with no BA; groups 2 and 3, oral BA at doses of 4 and 8 mg/kg/day, respectively; group 4, local BA (8 mg/kg); and group 5, both oral and local BA (8 mg/kg/day orally and 8 mg/kg locally). After closed fracture creation, the fracture line was opened with a mini-incision, and BA was locally administered to the fracture area in groups 4 and 5. In groups 2, 3, and 5, BA was administered by gastric gavage daily until sacrifice. The rats were evaluated by clinical, radiological, and histological examinations. The control group (group 1) significantly differed from the local BA-exposed groups (groups 4 and 5) in the clinical evaluation. Front-rear and lateral radiographs revealed significant differences between the local BA-exposed groups and the control and other groups (p < 0.05). Clinical and radiological evaluations demonstrated adequate agreement between observers. The average histological scores significantly differed across groups (p = 0.007) and were significantly higher in groups 4 and 5 which were the local BA (8 mg/kg) and both oral and local BA (8 mg/kg/day orally and 8 mg/kg locally), respectively, compared to the controls. This study suggests that BA may be useful in fracture healing. Further research is required to demonstrate the most effective local dosage and possible use of BA-coated implants. PMID:25846213

  6. METHOD DEVELOPMENT FOR DETERMINING THE HYDRAULIC CONDUCTIVITY OF FRACTURED POROUS MEDIA

    SciTech Connect

    Dixon, K.

    2013-09-30

    Plausible, but unvalidated, theoretical model constructs for unsaturated hydraulic conductivity of fractured porous media are currently used in Performance Assessment (PA) modeling for cracked saltstone and concrete (Flach 2011). The Nuclear Regulatory Commission (NRC) has expressed concern about the lack of model support for these assumed Moisture Characteristic Curves (MCC) data, as noted in Requests for Additional Information (RAIs) PA-8 and SP-4 (Savannah River Remediation, LLC, 2011). The objective of this task was to advance PA model support by developing an experimental method for determining the hydraulic conductivity of fractured cementitious materials under unsaturated conditions, and to demonstrate the technique on fractured saltstone samples. The task was requested through Task Technical Request (TTR) HLW-SSF-TTR-2012-0016 and conducted in accordance with Task Technical & Quality Assurance Plan (TTQAP) SRNL-TR-2012-00090. Preliminary method development previously conducted by Kohn et al. (2012) identified transient outflow extraction as the most promising method for characterizing the unsaturated properties of fractured porous media. While the research conducted by Kohn et al. (2012) focused on fractured media analogs such as stacked glass slides, the current task focused directly on fractured saltstone. For this task, four sample types with differing fracture geometries were considered: 1) intact saltstone, 2) intact saltstone with a single saw cut, smooth surface fracture, 3) micro-fractured saltstone (induced by oven drying), and 4) micro-fractured saltstone with a single, fully-penetrating, rough-surface fracture. Each sample type was tested initially for saturated hydraulic conductivity following method ASTM D 5084 using a flexible wall permeameter. Samples were subsequently tested using the transient outflow extraction method to determine cumulative outflow as a function of time and applied pressure. Of the four sample types tested, two yielded

  7. Thoracic compression fractures as a result of shock from a conducted energy weapon: a case report.

    PubMed

    Winslow, James E; Bozeman, William P; Fortner, Michael C; Alson, Roy L

    2007-11-01

    The Taser is an electrical conducted energy weapon used by law enforcement officers throughout the United States and the world. Though generally regarded as safe, conducted energy weapons can produce injuries. In this case report we describe for the first time thoracic spine compression fractures resulting from a conducted energy weapon discharge. Physicians who may care for patients who have been exposed to a conducted energy weapon discharge should be aware of this as a possible complication. PMID:17826867

  8. Superprotonic Solid Acids Thermochemistry, Structure, and Conductivity

    NASA Astrophysics Data System (ADS)

    Ikeda, Ayako

    In this work, in order to investigate the thermochemistry and property of the superprotonic solid acid compounds, the measurement methods were established for in situ observation, because superprotonic phases are neither stable at room temperature nor freezable to room temperature. A humidity-controlled TG, DSC and AC impedance measurement system, and high temperature stage for XRD were built for thermal analysis and characterization of the solid acid compounds. The thermodynamic and kinetics of the dehydration and hydration of CsH 2PO4 is investigated by TG, DSC, and XRD analysis. By making use of the enhanced kinetics afforded by SiO2, the phase boundary between CsH2PO4, CsPO3, and dehydrated liquid was precisely determined. The stability of CsH2PO4 and the liquid dehydrate, CsH2(1-x)PO4-x(l), were confirmed by the complete reversal of dehydration to recover these phases in the appropriate temperature and water partial pressure ranges. Rehydration and conversion of CsPO3(s) to CsH2PO4(s) occurs over a period of several hours, depending on temperature, water partial pressure, and morphology of the metaphosphate. High and small particles favor rapid dehydration, whereas the temperature dependence of the rehydration kinetics is nonmonotonic, reaching its fastest rate in the vicinity of the superprotonic transition. Doping Rb and K into CDP was examined and the stable region of Cs 1-xRbxH2PO4 and Cs1-xKxH2PO 4 are determined by in situ XRD and DSC measurement. Then the effects of doping to the structure and conductivity are discussed. It was found that Rb has whole-range solubility for both cubic and monoclinic CDP. Ts increases and Td decrease with Rb content. K has 27% solubility for cubic CDP, T s and Td decrease with K content. The eutectic temperature is 208 +/- 2°C. The lattice size of Rb- or K- doped CDP depends on the averaged cation size. Conductivity linearly decreases by dopant concentration. The impact of K doping is deeper than that of Rb for the

  9. Evaluation of Geochemical Fracture Conductivity Alterations in Shale under Laboratory Conditions

    NASA Astrophysics Data System (ADS)

    Radonjic, M.; Olabode, A.

    2015-12-01

    In large scale subsurface injection of carbondioxide as obtainable in carbon sequestration programs and in environmentally friendly hydraulic fracturing processes (using supercritical CO2), rock-fluid interaction can affect reservoir and seal rocks properties which are essential in monitoring the progress of these operations. The mineralogical components of sedimentary rocks are geochemically active particularly under enormous earth stresses. While geomechanical properties such as rock stiffness, Poisson's ratio and fracture geometry largely govern fluid flow characteristics in deep fractured formations, the effect of mineralization can lead to flow impedance in the presence of favorable geochemical and thermodynamic conditions. Experimental works which employed the use of analytical tools such as ICP-OES, XRD, SEM/EDS, TOC and BET techniques in investigating diagenetic and micro-structural properties of crushed shale caprock/CO2-brine system concluded that net precipitation reaction processes can affect the distribution of petrophysical nanopores in the shale as a result of rock-fluid interactions. Simulation results previously reported, suggest that influx-induced mineral dissolution/precipitation reactions within clay-based sedimentary rocks can continuously close micro-fracture networks, though injection pressure and effective-stress transformation first rapidly expand these fractures. This experimental modelling research investigated the impact of in-situ geochemical precipitation on conductivity of fractures under geomechanical stress conditions. Conductivity is measured as differential-pressure drop equivalence, using a pressure pulse-decay liquid permeametry/core flooding system, as geochemically saturated-fluid is transported through composite cores with embedded micro-tubings that mimic fractures. The reactive fluid is generated from crushed shale rocks of known mineralogical composition when flooded with aqueous CO2 at elevated temperature and pressure

  10. Application of multipole array sonic logging to acid hydralic fracturing

    NASA Astrophysics Data System (ADS)

    Tao, Guo; Gao, Kun; Wang, Bing; Ma, Yong

    2007-06-01

    Multipole array sonic logging tools have widely been employed in Chinese oilfields in recent years. We have developed a software package for rock mechanical analysis with multipole array sonic logs. This advanced data processing method and software have been applied to the Tahe oilfield in Northern West China to provide guidance to acid hydraulic fracturing design and evaluation. In this paper, we present the field examples of such data processing and applications to demonstrate the validity and advantages of our method and software package.

  11. Crosswell seismic investigation of hydraulically conductive, fracture bedrock near Mirror Lake, New Hampshire

    USGS Publications Warehouse

    Ellefsen, K.J.; Hsieh, P.A.; Shapiro, A.M.

    2002-01-01

    Near Mirror Lake, New Hampshire (USA), hydraulically conductive, fractured bedrock was investigated with the crosswell seismic method to determine whether this method could provide any information about hydraulic conductivity between wells. To this end, crosswell seismic data, acoustic logs from boreholes, image logs from boreholes, and single borehole hydraulic tests were analyzed. The analysis showed that, first, the P-wave velocities from the acoustic logs tended to be higher in schist than they were in granite. (Schist and granite were the dominant rock types). Second, the P-wave velocities from the acoustic logs tended to be low near fractures. Third, the hydraulic conductivity was always low (always less than to 10-8 m/s) where no fractures intersected the borehole, but the hydraulic conductivity ranged from low to high (from less than to 10-10 m/s to 10-4 m/s) where one or more fractures intersected the borehole. Fourth, high hydraulic conductivities were slightly more frequent when the P-wave velocity was low (less than 5200 m/s) than when it was high (greater than or equal to 5200 m/s). The interpretation of this statistical relation was that the fractures tended to increase the hydraulic conductivity and to lower the P-wave velocity. This statistical relation was applied to a velocity tomogram to create a map showing the probability of high hydraulic conductivity; the map was consistent with results from independent hydraulic tests. ?? 2002 Elsevier Science B.V. All rights reserved.

  12. ANALYSIS OF A GAS-PHASE PARTITIONING TRACER TEST CONDUCTED THROUGH FRACTURED MEDIA

    EPA Science Inventory

    The gas-phase partitioning tracer method was used to estimate non-aqueous phase liquid (NAPL), water, and air saturations in the vadose zone at a chlorinated-solvent contaminated field site in Tucson, AZ. The tracer test was conducted in a fractured clay system that is the confin...

  13. Effective-stress-law behavior of Austin chalk rocks for deformation and fracture conductivity

    SciTech Connect

    Warpinski, N.R.; Teufel, L.W.

    1994-08-01

    Austin chalk core has been tested to determine the effective law for deformation of the matrix material and the stress-sensitive conductivity of the natural fractures. For deformation behavior, two samples provided data on the variations of the poroelastic parameter, {alpha}, for Austin chalk, giving values around 0.4. The effective-stress-law behavior of a Saratoga limestone sample was also measured for the purpose of obtaining a comparison with a somewhat more porous carbonate rock. {alpha} for this rock was found to be near 0.9. The low {alpha} for the Austin chalk suggests that stresses in the reservoir, or around the wellbore, will not change much with changes in pore pressure, as the contribution of the fluid pressure is small. Three natural fractures from the Austin chalk were tested, but two of the fractures were very tight and probably do not contribute much to production. The third sample was highly conductive and showed some stress sensitivity with a factor of three reduction in conductivity over a net stress increase of 3000 psi. Natural fractures also showed a propensity for permanent damage when net stressed exceeded about 3000 psi. This damage was irreversible and significantly affected conductivity. {alpha} was difficult to determine and most tests were inconclusive, although the results from one sample suggested that {alpha} was near unity.

  14. Interpretation of injection-withdrawal tracer experiments conducted between two wells in a large single fracture.

    PubMed

    Novakowski, K S; Bickerton, G; Lapcevic, P

    2004-09-01

    Tracer experiments conducted using a flow field established by injecting water into one borehole and withdrawing water from another are often used to establish connections and investigate dispersion in fractured rock. As a result of uncertainty in the uniqueness of existing models used for interpretation, this method has not been widely used to investigate more general transport processes including matrix diffusion or advective solute exchange between mobile and immobile zones of fluid. To explore the utility of the injection-withdrawal method as a general investigative tool and with the intent to resolve the transport processes in a discrete fracture, two tracer experiments were conducted using the injection-withdrawal configuration. The experiments were conducted in a fracture which has a large aperture (>500 microm) and horizontally pervades a dolostone formation. One experiment was conducted in the direction of the hydraulic gradient and the other in the direction opposite to the natural gradient. Two tracers having significantly different values of the free-water diffusion coefficient were used. To interpret the experiments, a hybrid numerical-analytical model was developed which accounts for the arcuate shape of the flow field, advection-dispersion in the fracture, diffusion into the matrix adjacent to the fracture, and the presence of natural flow in the fracture. The model was verified by comparison to a fully analytical solution and to a well-known finite-element model. Interpretation of the tracer experiments showed that when only one tracer, advection-dispersion, and matrix diffusion are considered, non-unique results were obtained. However, by using multiple tracers and by accounting for the presence of natural flow in the fracture, unique interpretations were obtained in which a single value of matrix porosity was estimated from the results of both experiments. The estimate of porosity agrees well with independent measurements of porosity obtained from

  15. Identification, characterization, and analysis of hydraulically conductive fractures in granitic basement rocks, Millville, Massachusetts

    USGS Publications Warehouse

    Paillet, Frederick L.; Ollila, P.W.

    1994-01-01

    A suite of geophysical logs designed to identify and characterize fractures and water production in fractures was run in six bedrock boreholes at a ground-water contamination site near the towns of Millville and Uxbridge in south-central Massachusetts. The geophysical logs used in this study included conventional gamma, single-point resistance, borehole fluid resistivity, caliper, spontaneous potential, and temperature; and the borehole televiewer and heat-pulse flowmeter, which are not usually used to log bedrock water-supply wells. Downward flow under ambient hydraulic-head conditions was measured in three of the boreholes at the site, and the profile of fluid column resistivity inferred from the logs indicated downward flow in all six boreholes. Steady injection tests at about 1.0 gallon per minute were used to identify fractures capable of conducting flow under test conditions. Sixteen of 157 fracturesidentified on the televiewer logs and interpreted as permeable fractures in the data analysis were determined to conduct flow under ambient hydraulic-head conditions or during injection. Hydraulic-head monitoring in the bedrock boreholes indicated a consistent head difference between the upper and lower parts of the boreholes. This naturally occurring hydraulic-head condition may account, in part, for the transport of contaminants from the overlying soil into the bedrock aquifer. The downward flow may also account for the decrease in contaminant concentrations found in some boreholes after routine use of the boreholes as water-supply wells was discontinued.

  16. Immunohistochemical Localization of Key Arachidonic Acid Metabolism Enzymes during Fracture Healing in Mice

    PubMed Central

    Lin, Hsuan-Ni; O’Connor, J. Patrick

    2014-01-01

    This study investigated the localization of critical enzymes involved in arachidonic acid metabolism during the initial and regenerative phases of mouse femur fracture healing. Previous studies found that loss of cyclooxygenase-2 activity impairs fracture healing while loss of 5-lipoxygenase activity accelerates healing. These diametric results show that arachidonic acid metabolism has an essential function during fracture healing. To better understand the function of arachidonic acid metabolism during fracture healing, expression of cyclooxygenase-1 (COX-1), cyclooxygenase -2 (COX-2), 5-lipoxygenase (5-LO), and leukotriene A4 hydrolase (LTA4H) was localized by immunohistochemistry in time-staged fracture callus specimens. All four enzymes were detected in leukocytes present in the bone marrow and attending inflammatory response that accompanied the fracture. In the tissues surrounding the fracture site, the proportion of leukocytes expressing COX-1, COX-2, or LTA4H decreased while those expressing 5-LO remained high at 4 and 7 days after fracture. This may indicate an inflammation resolution function for 5-LO during fracture healing. Only COX-1 was consistently detected in fracture callus osteoblasts during the later stages of healing (day 14 after fracture). In contrast, callus chondrocytes expressed all four enzymes, though 5-LO appeared to be preferentially expressed in newly differentiated chondrocytes. Most interestingly, osteoclasts consistently and strongly expressed COX-2. In addition to bone surfaces and the growth plate, COX-2 expressing osteoclasts were localized at the chondro-osseous junction of the fracture callus. These observations suggest that arachidonic acid mediated signaling from callus chondrocytes or from callus osteoclasts at the chondro-osseous junction regulate fracture healing. PMID:24516658

  17. Delayed fracture of Ni-Ti superelastic alloys in acidic and neutral fluoride solutions.

    PubMed

    Yokoyama, Ken'ichi; Kaneko, Kazuyuki; Moriyama, Keiji; Asaoka, Kenzo; Sakai, Jun'ichi; Nagumo, Michihiko

    2004-04-01

    Hydrogen-related degradation of the mechanical properties of a Ni-Ti superelastic alloy has been examined by means of delayed fracture tests in acidic and neutral fluoride solutions and hydrogen thermal desorption analysis. Delayed fracture took place in both solutions; the time to fracture was shorter in the acidic solutions than in the neutral solutions with the same fluoride concentration. The time to fracture was reduced in both solutions when applied stress exceeded the critical stress for martensite transformation. In the acidic solutions, Ni-Ti superelastic alloy underwent general corrosion and absorbed substantial amounts of hydrogen. Fractographic features suggested that the delayed fracture in the acidic solutions was attributable to hydrogen embrittlement, whereas in the neutral solutions, a different fracture mode appeared associated with localized corrosion only in the vicinity of the fracture initiation area. In the neutral solutions, the amount of absorbed hydrogen was much less than that in the acidic solutions, and the delayed fracture was likely to be induced by active path corrosion accompanying hydrogen absorption. The results of the present study imply that the hydrogen-related degradation of performance of Ni-Ti superelastic alloys occurs in the presence of fluoride. PMID:14999757

  18. Field determination of the three-dimensional hydraulic conductivity tensor of anisotropic media 2. Methodology and application to fractured rocks.

    USGS Publications Warehouse

    Hsieh, P.A.; Neuman, S.P.; Stiles, G.K.; Simpson, E.S.

    1985-01-01

    The analytical solutions developed in the first paper can be used to interpret the results of cross-hole tests conducted in anisotropic porous or fractured media. Test results from a granitic rock near Oracle in southern Arizona are presented to illustrate how the method works for fractured rocks. At the site, the Oracle granite is shown to respond as a near-uniform, anisotropic medium, the hydraulic conductivity of which is strongly controlled by the orientations of major fracture sets. The cross-hole test results are shown to be consistent with the results of more than 100 single- hole packer tests conducted at the site. -from Authors

  19. Measurement of soil and rock fractural hydraulic conductivities using falling head infiltration experiment of single-ring permeameter

    NASA Astrophysics Data System (ADS)

    Chen, X.; Zhang, Z. C.; Shi, P.; Cheng, Q. B.

    2012-04-01

    Southwest China Karst is a fragile area for ecological system because of thin soil and underlying rock fracures. Soil and rock fractural hydraulic conductivities in this area determine infiltration, runoff and water retaining in soil and rock fractures for plant utilization. Determination of soil and rock fractural hydraulic conductivities is very tough due to strong heterogeneous. In this paper, we designed a single-ring permeameter to measure the hydraulic conductivities based on falling head infiltration experiment. The experiments were conducted in two karst areas in southwest China: a hillslope in Huanjiang County, northwest Guangxi for measuring soil hydraulic conductivities and a profile at the small catchment of Chenqi in the Puding basin of Guizhou for measuring fractural hydraulic conductivities. The results show that surface soil hydraulic conductivity is 2.386×10-4 m/s, much larger than 2.004×10-5 m/s for the soil at 30cm depth. Soil hydraulic conductivities are generally increased from the bottom to the top along the hillslope, and this increase is particularly significant for the soil at 30cm depth. The fractural hydraulic conductivities were determined for the limestone profile with three fractures crossing in vertical and horizontal directions. The effective fractural aperture was determined according to calibration of water head variations of the ponded water in the single ring permeameter, which can be simulated by a numerical model based on Navier-Stokes equations and measured with an automatic observation equipment. The hydraulic conductivities were then estimated in terms of the cubic law equation. The estimated effective fractural aperture is 0.25mm for the horizontal fracture, and 0.25 and 0.5mm for the two vertical fractures crossing the horizontal in the right and left sides, respectively. The corresponding hydraulic conductivity is 0.051 m/s for the horizontal fracture and 0.051 and 0.204m/s for the two vertical fractures in the right

  20. Validation of non-Darcian flow effects in slug tests conducted in fractured rock boreholes

    NASA Astrophysics Data System (ADS)

    Quinn, Patryk M.; Parker, Beth L.; Cherry, John A.

    2013-04-01

    SummaryA series of rising and falling head slug tests with different initial applied head differentials (ΔHo) were conducted in open fractured dolostone and sandstone boreholes using straddle packers isolating specific depth intervals (1.5 m length) to examine the influence of non-Darcian flow. The open holes were developed and inspected using video and acoustic televiewing (ATV) to ensure that evidence of skin effects due to drilling were absent. The transmissivity (T) values obtained from both the rising and falling head slug tests were very similar at low initial applied head; however, the T values were progressively smaller at larger ΔHo, suggesting error due to non-Darcian flow. Non-Darcian flow behavior was confirmed by constant head step tests conducted in the same test intervals where the injection rate (Q) vs. applied head (dH) relationship became non-linear at relatively low injection rates, and the non-Darcian data also resulted in lower T values. For a series of slug tests conducted at different ΔHo, non-Darcian flow effects gradually increased as ΔHo increased, consistent with the trends for constant head step tests conducted in the same test intervals. To maintain Darcian flow conditions in the fractured dolostone and sandstone tested in this study, ΔHo must be kept small, generally less than 0.2 m. This study demonstrates that by conducting both "stepped" slug tests and constant head step tests, the Darcian flow assumption for both types of tests can be rigorously validated. However, when only slug tests are conducted, it is necessary to conduct a series of "stepped" slug tests, including tests with small applied head differentials, to avoid errors due to non-Darcian flow.

  1. Ionic conductivity and glass transition of phosphoric acids

    SciTech Connect

    Wang, Yangyang; Lane, Nathan A; Sun, Che-Nan; Fan, Fei; Zawodzinski, Thomas; Sokolov, Alexei P

    2013-01-01

    Here we report the low-temperature dielectric and viscoelastic properties of phosphoric acids in the range of H2O:P2O5 1.5 5. Both dielectric and viscosity measurements allow us to determine the glass-transition temperatures of phosphoric acids. The obtained glass-transition temperatures are in good agreement with previous differential scanning calorimetric measurements. Moreover, our analysis reveals moderate decoupling of ionic conductivity from structural relaxation in the vicinity of the glass transition.

  2. Ferromagnetic Conducting Lignosulfonic Acid-doped Polyaniline Nanocomposites

    NASA Technical Reports Server (NTRS)

    Viswansthan, Tito (Inventor); Berry, Brian (Inventor)

    2004-01-01

    A conductive ferromagnetic composition of matter comprising sulfonated lignin or a sulfonated polyflavonoid, or derivatives thereof, and ferromagnetic iron oxide particles is disclosed. Among the uses of the composition is to shield electromagnetic radiation. The ferromagnetic iron oxide particles of the composition are surprisingly stable to acid, and are easily and inexpensively formed from iron cations in solution.

  3. Radium and barium removal through blending hydraulic fracturing fluids with acid mine drainage.

    PubMed

    Kondash, Andrew J; Warner, Nathaniel R; Lahav, Ori; Vengosh, Avner

    2014-01-21

    Wastewaters generated during hydraulic fracturing of the Marcellus Shale typically contain high concentrations of salts, naturally occurring radioactive material (NORM), and metals, such as barium, that pose environmental and public health risks upon inadequate treatment and disposal. In addition, fresh water scarcity in dry regions or during periods of drought could limit shale gas development. This paper explores the possibility of using alternative water sources and their impact on NORM levels through blending acid mine drainage (AMD) effluent with recycled hydraulic fracturing flowback fluids (HFFFs). We conducted a series of laboratory experiments in which the chemistry and NORM of different mix proportions of AMD and HFFF were examined after reacting for 48 h. The experimental data combined with geochemical modeling and X-ray diffraction analysis suggest that several ions, including sulfate, iron, barium, strontium, and a large portion of radium (60-100%), precipitated into newly formed solids composed mainly of Sr barite within the first ∼ 10 h of mixing. The results imply that blending AMD and HFFF could be an effective management practice for both remediation of the high NORM in the Marcellus HFFF wastewater and beneficial utilization of AMD that is currently contaminating waterways in northeastern U.S.A. PMID:24367969

  4. Fractures

    PubMed Central

    Hall, Michael C.

    1963-01-01

    Recent studies on the epidemiology and repair of fractures are reviewed. The type and severity of the fracture bears a relation to the age, sex and occupation of the patient. Bone tissue after fracture shows a process of inflammation and repair common to all members of the connective tissue family, but it repairs with specific tissue. Cartilage forms when the oxygen supply is outgrown. After a fracture, the vascular bed enlarges. The major blood supply to healing tissue is from medullary vessels and destruction of them will cause necrosis of the inner two-thirds of the cortex. Callus rapidly mineralizes, but full mineralization is achieved slowly; increased mineral metabolism lasts several years after fracture. PMID:13952119

  5. Electrical conduction in macroscopically oriented deoxyribonucleic and hyaluronic acid samples

    NASA Astrophysics Data System (ADS)

    Kutnjak, Zdravko; Lahajnar, Gojmir; Filipič, Cene; Podgornik, Rudolf; Nordenskiöld, Lars; Korolev, Nikolay; Rupprecht, Allan

    2005-04-01

    Measurements of the quasistatic and frequency dependent electrical conductivity below 1 MHz were carried out on wet-spun, macroscopically oriented, calf thymus deoxyribonucleic (DNA) and umbilical cord hyaluronic acid (HA) bulk samples. The frequency dependence of the electrical conductivity in the frequency range of approximately 10-3-106Hz of both materials is surprisingly rather similar. Temperature dependence of the quasistatic electrical conductivity above the low temperature saturation plateau can be well described by the activated Arrhenius law with the activation energy of ≈0.8eV for both DNA and HA. We discuss the meaning of these findings for the possible conduction mechanism in these particular charged polyelectrolytes.

  6. Fractures

    MedlinePlus

    ... commonly happen because of car accidents, falls, or sports injuries. Other causes are low bone density and osteoporosis, which cause weakening of the bones. Overuse can cause stress fractures, which are very small cracks in the ...

  7. Fractures

    MedlinePlus

    A fracture is a break, usually in a bone. If the broken bone punctures the skin, it is called an open ... falls, or sports injuries. Other causes are low bone density and osteoporosis, which cause weakening of the ...

  8. Estimating Hydraulic Conductivities in a Fractured Shale Formation from Pressure Pulse Testing and 3d Modeling

    NASA Astrophysics Data System (ADS)

    Courbet, C.; DICK, P.; Lefevre, M.; Wittebroodt, C.; Matray, J.; Barnichon, J.

    2013-12-01

    In the framework of its research on the deep disposal of radioactive waste in shale formations, the French Institute for Radiological Protection and Nuclear Safety (IRSN) has developed a large array of in situ programs concerning the confining properties of shales in their underground research laboratory at Tournemire (SW France). One of its aims is to evaluate the occurrence and processes controlling radionuclide migration through the host rock, from the disposal system to the biosphere. Past research programs carried out at Tournemire covered mechanical, hydro-mechanical and physico-chemical properties of the Tournemire shale as well as water chemistry and long-term behaviour of the host rock. Studies show that fluid circulations in the undisturbed matrix are very slow (hydraulic conductivity of 10-14 to 10-15 m.s-1). However, recent work related to the occurrence of small scale fractures and clay-rich fault gouges indicate that fluid circulations may have been significantly modified in the vicinity of such features. To assess the transport properties associated with such faults, IRSN designed a series of in situ and laboratory experiments to evaluate the contribution of both diffusive and advective process on water and solute flux through a clay-rich fault zone (fault core and damaged zone) and in an undisturbed shale formation. As part of these studies, Modular Mini-Packer System (MMPS) hydraulic testing was conducted in multiple boreholes to characterize hydraulic conductivities within the formation. Pressure data collected during the hydraulic tests were analyzed using the nSIGHTS (n-dimensional Statistical Inverse Graphical Hydraulic Test Simulator) code to estimate hydraulic conductivity and formation pressures of the tested intervals. Preliminary results indicate hydraulic conductivities of 5.10-12 m.s-1 in the fault core and damaged zone and 10-14 m.s-1 in the adjacent undisturbed shale. Furthermore, when compared with neutron porosity data from borehole

  9. Spontaneous Acetabular Periprosthetic Fracture in a Patient Continuously Having Zoledronic Acid

    PubMed Central

    Tantavisut, Saran; Thanakit, Voranuch; Ngarmukos, Srihatach; Wilairatana, Vajara; Wangroongsub, Yongsak

    2014-01-01

    Zoledronic acid has been used for prevention of osteolytic and osteoblastic bone metastasis. This case report illustrates an undesirable consequence from prolonged usage of zoledronic acid in bone metastasis prevention. Periprosthetic acetabular fracture in a patient treated with zoledronic acid for 7 years was reported. The clinical presentation, radiographic and pathological results were described. This is a rare complication after total hip arthroplasty which should not be ignored especially in patients who received long term bisphosphonate. PMID:25177464

  10. Fatty acids in sparry calcite fracture fills and microsparite cement of septarian diagenetic concretions

    NASA Astrophysics Data System (ADS)

    Pearson, M. J.; Hendry, J. P.; Taylor, C. W.; Russell, M. A.

    2005-04-01

    Sparry calcite fracture fills and concretion body cements in concretions from the Flodigarry Shale Member of the Staffin Shale Formation, Isle of Skye, Scotland, entrap and preserve mineral and organic materials of sedimentary and diagenetic origin. Fatty acids are a major component of the lipids recovered by decarbonation and comprise mainly n-alkanoic and α-ω dicarboxylic acids. Two generations of fracture-fill calcite (early brown and later yellow) and the concretion body microspar yield significantly different fatty acid profiles. Early brown calcites yield mainly medium-chain n-alkanoic acids with strong even predominance; later yellow calcites are dominated by α-ω dicarboxylic acids with no even predominance. Both fracture fills lack the long-chain n-alkanoic and α-ω dicarboxylic acids additionally recovered from the concretion bodies. The absence of longer chain acids in the calcite spar fracture fills is inferred to result from the transport of fatty acids by septarian mineralising fluids whereby low-aqueous solubility of longer chain acids or their salts accounts for their relative immobility. Comparative experiments have been carried out using conventional solvent extraction on the concretion body and associated shales, both decarbonated and untreated. Extracted lipid yields are higher, but the fatty acids probably derive from mixed locations in the rock including both kerogen- and carbonate-associated lipid pools. Only experiments involving decarbonation yielded α-ω dicarboxylic acids in molecular distributions probably controlled mainly by fluid transport. Alkane biomarker ratios indicate very low thermal maturity has been experienced by the concretions and their host sediments. Septarian cracks lined by brown calcite formed during early burial. Microbial CO 2 from sulphate-reducing bacteria was probably the main source of mineralising carbonate. Emplacement of the later septarian fills probably involved at least one episode of fluid invasion.

  11. Geochemical modelling of EGS fracture stimulation applying weak and strong acid treatments

    NASA Astrophysics Data System (ADS)

    Sigfusson, Bergur; Sif Pind Aradottir, Edda

    2015-04-01

    Engineered Geothermal systems (EGS) provide geothermal power by tapping into the Earth's deep geothermal resources that are otherwise not exploitable due to lack of water and fractures, location or rock type. EGS technologies have the potential to cost effectively produce large amounts of electricity almost anywhere in the world. The EGS technology creates permeability in the rock by hydro-fracturing the reservoir with cold water pumped into the first well (the injection well) at a high pressure. The second well (the production well) intersects the stimulated fracture system and returns the hot water to the surface where electricity can be generated. A significant technological hurdle is ensuring effective connection between the wells and the fracture system and to control the deep-rooted fractures (can exceed 5 000 m depth). A large area for heat transfer and sufficient mass flow needs to be ensured between wells without creating fast flowing paths in the fracture network. Maintaining flow through the fracture system can cause considerable energy penalty to the overall process. Therefore, chemical methods to maintain fractures and prevent scaling can be necessary to prevent excessive pressure build up in the re-injection wells of EGS systems. The effect of different acid treatments on the porosity development of selected rock types was simulated with the aid of the Petrasim interface to the Toughreact simulation code. The thermodynamic and kinetic database of Aradottir et al. (2014) was expanded to include new minerals and the most important fluoride bearing species involved in mineral reactions during acid stimulation of geothermal systems. A series of simulations with injection waters containing fluoric acid, hydrochloric acid and CO2 or mixtures thereof were then carried out and porosity development in the fracture system monitored. The periodic injection of weak acid mixtures into EGS systems may be cost effective in some isolated cases to prevent pressure

  12. Application of fracture-flow hydrogeology to acid-mine drainage at the Bunker Hill Mine, Kellogg, Idaho

    NASA Astrophysics Data System (ADS)

    Lachmar, Thomas E.

    1994-03-01

    The mechanics of groundwater flow through fractured rock has become an object of major research interest during recent years. This project has investigated the flow of groundwater through fractured Precambrian metaquartzite rocks in a portion of the Bunker Hill Mine near Kellogg, Idaho. Groundwater flow through these types of rocks is largely dependent upon the properties of fractures such as faults, joints and relict bedding planes. Groundwater that flows into the mine via the fractures is acidic and is contaminated by heavy metals, which results in a severe acid mine drainage problem. A more complete understanding of how the fractures influence the groundwater flow system is a prerequisite of the evaluation of reclamation alternatives to reduce acid drainage from the mine. Fracture mapping techniques were used to obtain detailed information on the fracture properties observed in the New East Reed drift of the Bunker Hill Mine. The information obtained includes fracture type, orientation, trace length, the number of visible terminations, roughness, waviness, infilling material, and a qualitative measure of the amount of water flowing through each fracture. The hydrogeologic field data collected include routine measurements of the discharge from four individual structural features and four areas where large quantities of water are discharging from vertical rock bolts, the depths to water in three piezometer nests at the ground surface, the pressure variations in four diamond drillholes, and constant discharge flow tests conducted on three of the diamond drillholes. The field data indicate that relict bedding planes are the primary conduits for groundwater flow, and suggest that the two major joint sets that are present connect water flowing through the discontinuous bedding planes. The three minor joint sets that are present do not seem to have a significant impact on groundwater flow, but along with the two major joint sets may store relatively large quantities of

  13. Highly Conductive and Reliable Copper-Filled Isotropically Conductive Adhesives Using Organic Acids for Oxidation Prevention

    NASA Astrophysics Data System (ADS)

    Chen, Wenjun; Deng, Dunying; Cheng, Yuanrong; Xiao, Fei

    2015-07-01

    The easy oxidation of copper is one critical obstacle to high-performance copper-filled isotropically conductive adhesives (ICAs). In this paper, a facile method to prepare highly reliable, highly conductive, and low-cost ICAs is reported. The copper fillers were treated by organic acids for oxidation prevention. Compared with ICA filled with untreated copper flakes, the ICA filled with copper flakes treated by different organic acids exhibited much lower bulk resistivity. The lowest bulk resistivity achieved was 4.5 × 10-5 Ω cm, which is comparable to that of commercially available Ag-filled ICA. After 500 h of 85°C/85% relative humidity (RH) aging, the treated ICAs showed quite stable bulk resistivity and relatively stable contact resistance. Through analyzing the results of x-ray diffraction, x-ray photoelectron spectroscopy, and thermogravimetric analysis, we found that, with the assistance of organic acids, the treated copper flakes exhibited resistance to oxidation, thus guaranteeing good performance.

  14. Tranexamic acid in hip fracture patients: a protocol for a randomised, placebo controlled trial on the efficacy of tranexamic acid in reducing blood loss in hip fracture patients

    PubMed Central

    Gausden, Elizabeth Bishop; Garner, Matthew R; Warner, Stephen J; Levack, Ashley; Nellestein, Andrew M; Tedore, Tiffany; Flores, Eva; Lorich, Dean G

    2016-01-01

    Introduction There is a high incidence of blood transfusion following hip fractures in elderly patients. Tranexamic acid (TXA) has proven efficacy in decreasing blood loss in general trauma patients as well as patients undergoing elective orthopaedic surgery. A randomised controlled trial will measure the effect of TXA in a population of patients undergoing hip fracture surgery. Methods This is a double-blinded, randomised placebo-controlled trial. Patients admitted through the emergency room that are diagnosed with an intertrochanteric or femoral neck fracture will be eligible for enrolment and randomised to either treatment with 1 g of intravenous TXA or intravenous saline at the time of skin incision. Patients undergoing percutaneous intervention for non-displaced or minimally displaced femoral neck fractures will not be eligible for enrolment. Postoperative transfusion rates will be recorded and blood loss will be calculated from serial haematocrits. Ethics and dissemination This protocol was approved by the Institutional Review Board (IRB) and is registered with clinicaltrials.gov. The findings of the trial will be disseminated through peer-reviewed journals and conference presentations. Trial registration number NCT01940536. PMID:27329438

  15. Estimating hydraulic conductivity of fractured rocks from high-pressure packer tests with an Izbash's law-based empirical model

    NASA Astrophysics Data System (ADS)

    Chen, Yi-Feng; Hu, Shao-Hua; Hu, Ran; Zhou, Chuang-Bing

    2015-04-01

    High-pressure packer test (HPPT) is an enhanced constant head packer test for characterizing the permeability of fractured rocks under high-pressure groundwater flow conditions. The interpretation of the HPPT data, however, remains difficult due to the transition of flow conditions in the conducting structures and the hydraulic fracturing-induced permeability enhancement in the tested rocks. In this study, a number of HPPTs were performed in the sedimentary and intrusive rocks located at 450 m depth in central Hainan Island. The obtained Q-P curves were divided into a laminar flow phase (I), a non-Darcy flow phase (II), and a hydraulic fracturing phase (III). The critical Reynolds number for the deviation of flow from linearity into phase II was 25-66. The flow of phase III occurred in sparsely to moderately fractured rocks, and was absent at the test intervals of perfect or poor intactness. The threshold fluid pressure between phases II and III was correlated with RQD and the confining stress. An Izbash's law-based analytical model was employed to calculate the hydraulic conductivity of the tested rocks in different flow conditions. It was demonstrated that the estimated hydraulic conductivity values in phases I and II are basically the same, and are weakly dependent on the injection fluid pressure, but it becomes strongly pressure dependent as a result of hydraulic fracturing in phase III. The hydraulic conductivity at different test intervals of a borehole is remarkably enhanced at highly fractured zone or contact zone, but within a rock unit of weak heterogeneity, it decreases with the increase of depth.

  16. ANALYSIS OF A GAS-PHASE PARTITIONING TRACER TEST CONDUCTED IN AN UNSATURATED FRACTURED-CLAY FORMATION

    EPA Science Inventory

    The gas-phase partitioning tracer method was used to estimate non-aqueous phase liquid (NAPL), water, and air saturations in the vadose zone at a chlorinated-solvent contaminated field site in Tucson, AZ. The tracer test was conducted in a fractured-clay system that is the confin...

  17. IDENTIFYING HYDRAULICALLY CONDUCTIVE FRACTURES WITH A SLOW-VELOCITY BOREHOLE FLOWMETER.

    USGS Publications Warehouse

    Hess, Alfred E.

    1986-01-01

    The U. S. Geological Survey used a recently developed heat-pulse flowmeter to measure very slow borehole axial water velocities in granitic rock at a site near Lac du Bonnet, Manitoba, Canada. The flowmeter was used with other geophysical measurements to locate and identify hydraulically conducting fractures contributing to the very slow vertical water flow in the two boreholes selected for study. The heat-pulse flowmeter has a flow-measuring range in water of 0. 06-6m/min, and can resolve velocity differences as slow as 0. 01 m/min. This is an order of magnitude slower than the stall speed of spinner flowmeters. The flowmeter is 1. 16 m long and 44 mm in diameter. It was calibrated in columns of 76 and 152 mm diameter, to correspond to the boreholes studied. The heat-pulse flowmeter system is evaluated, and problems peculiar to the measurement of very slow axial water velocities in boreholes are discussed.

  18. Reflection seismic imaging of a hydraulically conductive fracture zone in a high noise area, Forsmark, Sweden

    NASA Astrophysics Data System (ADS)

    Juhlin, C.; Stephens, M. B.; Cosma, C.

    2007-05-01

    borehole shows that the reflection corresponds to a hydraulically conductive fracture zone that was intersected at about 320 m depth.

  19. Subgroup Variations in Bone Mineral Density Response to Zoledronic Acid After Hip Fracture

    PubMed Central

    Magaziner, Jay S; Orwig, Denise L; Lyles, Kenneth W; Nordsletten, Lars; Boonen, Steven; Adachi, Jonathan D; Recknor, Chris; Colón-Emeric, Cathleen S; Mesenbrink, Peter; Bucci-Rechtweg, Christina; Su, Guoqin; Johnson, Rasheeda; Pieper, Carl F

    2014-01-01

    Minimizing post-fracture bone loss is an important aspect of recovery from hip fracture, and determination of factors that affect bone mineral density (BMD) response to treatment after hip fracture may assist in the development of targeted therapeutic interventions. A post hoc analysis of the HORIZON Recurrent Fracture Trial was done to determine the effect of zoledronic acid (ZOL) on total hip (TH) and femoral neck (FN) BMD in subgroups with low-trauma hip fracture. A total of 2127 patients were randomized (1:1) to yearly infusions of ZOL 5 mg (n = 1065) or placebo (n = 1062) within 90 days of operation for low-trauma hip fracture. The 1486 patients with a baseline and at least one post-baseline BMD assessment at TH or FN (ZOL = 745, placebo = 741) were included in the analyses. Percentage change from baseline in TH and FN BMD was assessed at months 12 and 24 and compared across subgroups of hip fracture patients. Percentage change from baseline in TH and FN BMD at months 12 and 24 was greater (p < 0.05) in ZOL-treated patients compared with placebo in most subgroups. Treatment-by-subgroup interactions (p < 0.05) indicated that a greater effect on BMD was observed for TH BMD at month 12 in females, in patients in the lower tertile body mass index at baseline (≤22.6 kg/m2), and in patients with baseline FN BMD T-score of ≤ –2.5; for FN BMD in patients who received ZOL for >6 weeks post-surgery; and for TH and FN BMD in patients with a history of one or more prior fractures. All interactions were limited to the first 12 months after treatment with none observed for the 24-month comparisons. (Clinical trial registration number NCT00046254.) PMID:24839241

  20. Estimation of the hydraulic conductivity of a two-dimensional fracture network using effective medium theory and power-law averaging

    NASA Astrophysics Data System (ADS)

    Zimmerman, R. W.; Leung, C. T.

    2009-12-01

    Most oil and gas reservoirs, as well as most potential sites for nuclear waste disposal, are naturally fractured. In these sites, the network of fractures will provide the main path for fluid to flow through the rock mass. In many cases, the fracture density is so high as to make it impractical to model it with a discrete fracture network (DFN) approach. For such rock masses, it would be useful to have recourse to analytical, or semi-analytical, methods to estimate the macroscopic hydraulic conductivity of the fracture network. We have investigated single-phase fluid flow through generated stochastically two-dimensional fracture networks. The centers and orientations of the fractures are uniformly distributed, whereas their lengths follow a lognormal distribution. The aperture of each fracture is correlated with its length, either through direct proportionality, or through a nonlinear relationship. The discrete fracture network flow and transport simulator NAPSAC, developed by Serco (Didcot, UK), is used to establish the “true” macroscopic hydraulic conductivity of the network. We then attempt to match this value by starting with the individual fracture conductances, and using various upscaling methods. Kirkpatrick’s effective medium approximation, which works well for pore networks on a core scale, generally underestimates the conductivity of the fracture networks. We attribute this to the fact that the conductances of individual fracture segments (between adjacent intersections with other fractures) are correlated with each other, whereas Kirkpatrick’s approximation assumes no correlation. The power-law averaging approach proposed by Desbarats for porous media is able to match the numerical value, using power-law exponents that generally lie between 0 (geometric mean) and 1 (harmonic mean). The appropriate exponent can be correlated with statistical parameters that characterize the fracture density.

  1. Polaron conductivity mechanism in potassium acid phthalate crystal: AC-conductivity investigation

    NASA Astrophysics Data System (ADS)

    Filipič, Cene; Levstik, Iva; Levstik, Adrijan; Hadži, Dušan

    2016-08-01

    The complex dielectric constant, \\varepsilon *(ν ,T), of potassium acid phthalate monocrystal (KAP) was investigated over the broad frequency and temperature range. While the imaginary part of dielectric constant ε‧‧(ν) increases rapidly with increasing temperature in the studied temperature range, the real part of dielectric constant ε‧(ν) increases only at high temperatures; there is almost no change of ε‧(ν) below 200 K. Both values of ε‧ and ε‧‧ are frequency dependent; the values increase with decreasing frequencies. At temperatures below 450 K the ac electrical conductivity and dielectric constant follow simultaneously the universal dielectric response (UDR). The analysis of the temperature dependence of the UDR parameter s in terms of the theoretical model for small polarons revealed that this mechanism governs the charge transport in KAP crystal in the studied temperature range.

  2. Phosphonic Acids for Interfacial Engineering of Transparent Conductive Oxides.

    PubMed

    Paniagua, Sergio A; Giordano, Anthony J; Smith, O'Neil L; Barlow, Stephen; Li, Hong; Armstrong, Neal R; Pemberton, Jeanne E; Brédas, Jean-Luc; Ginger, David; Marder, Seth R

    2016-06-22

    Transparent conducting oxides (TCOs), such as indium tin oxide and zinc oxide, play an important role as electrode materials in organic-semiconductor devices. The properties of the inorganic-organic interface-the offset between the TCO Fermi level and the relevant transport level, the extent to which the organic semiconductor can wet the oxide surface, and the influence of the surface on semiconductor morphology-significantly affect device performance. This review surveys the literature on TCO modification with phosphonic acids (PAs), which has increasingly been used to engineer these interfacial properties. The first part outlines the relevance of TCO surface modification to organic electronics, surveys methods for the synthesis of PAs, discusses the modes by which they can bind to TCO surfaces, and compares PAs to alternative organic surface modifiers. The next section discusses methods of PA monolayer deposition, the kinetics of monolayer formation, and structural evidence regarding molecular orientation on TCOs. The next sections discuss TCO work-function modification using PAs, tuning of TCO surface energy using PAs, and initiation of polymerizations from TCO-tethered PAs. Finally, studies that examine the use of PA-modified TCOs in organic light-emitting diodes and organic photovoltaics are compared. PMID:27227316

  3. Determining the distribution of hydraulic conductivity in a fractured limestone aquifer by simultaneous injection and geophysical logging

    USGS Publications Warehouse

    Morin, R.H.; Hess, A.E.; Paillet, Frederick L.

    1988-01-01

    A field technique for assessing the vertical distribution of hydraulic conductivity in an aquifer was applied to a fractured carbonate formation in southeastern Nevada. The technique combines the simultaneous use of fluid injection and geophysical logging to measure in situ vertical distributions of fluid velocity and hydraulic head down the borehole; these data subsequently are analyzed to arrive at quantitative estimates of hydraulic conductivity across discrete intervals in the aquifer. The results of this analysis identified the contact margin between the Anchor and Dawn Members of the Monte Cristo Limestone as being the dominant transmissive unit. -from Authors

  4. Fracture hydraulic conductivity in the Mexico City clayey aquitard: Field piezometer rising-head tests

    NASA Astrophysics Data System (ADS)

    Vargas, Carlos; Ortega-Guerrero, Adrián

    A regional lacustrine aquitard covers the main aquifer of the metropolitan area of Mexico City. The aquitard's hydraulic conductivity (K') is fundamental for evaluating the natural protection of the aquifer against a variety of contaminants present on the surface and its hydraulic response. This study analyzes the distribution and variation of K' in the plains of Chalco, Texcoco and Mexico City (three of the six former lakes that existed in the Basin of Mexico), on the basis of 225 field-permeability tests, in nests of existing piezometers located at depths of 2-85 m. Tests were interpreted using the Hvorslev method and some by the Bouwer-Rice method. Results indicate that the distribution of K' fits log-Gaussian regression models. Dominant frequencies for K' in the Chalco and Texcoco plains range between 1E-09 and 1E-08 m/s, with similar population means of 1.19E-09 and 1.7E-09 m/s, respectively, which are one to two orders of magnitude higher than the matrix conductivity. In the Mexico City Plain the population mean is near by one order of magnitude lower; K'=2.6E-10 m/s. The contrast between the measured K' and that of the matrix is attributed to the presence of fractures in the upper 25-40 m, which is consistent with the findings of previous studies on solute migration in the aquitard. Un imperméable régional d'origine lacustre recouvre le principal aquifère de la zone urbaine de la ville de Mexico. La conductivité hydraulique K' de cet imperméable est fondamentale pour évaluer la protection naturelle de l'aquifère, contre les différents contaminants présents en surface, et sa réponse hydraulique. Cette étude analyse et les variations de K' dans les plaines de Chalco, Texcoco et Mexico (trois des six anciens lacs qui existaient dans le Bassin de Mexico), sur la base de 225 essais de perméabilité sur le terrain, réalisés en grappes dans des piézomètres existants entre 2 et 85 m de profondeur. Les essais ont été interprétés avec la m

  5. Proteins, dietary acid load, and calcium and risk of postmenopausal fractures in the E3N French women prospective study.

    PubMed

    Dargent-Molina, Patricia; Sabia, Sèverine; Touvier, Mathilde; Kesse, Emmanuelle; Bréart, Gérard; Clavel-Chapelon, Françoise; Boutron-Ruault, Marie-Christine

    2008-12-01

    Excess dietary proteins and "acid ash" diets have been suspected to increase the risk of osteoporosis, but experimental and epidemiological evidence is mixed. We aimed to determine whether the association between protein intake and the overall acid-base equilibrium of the diet (as renal net acid excretion [RNAE] estimate) and fracture risk vary according to calcium intake. During an average of 8.37 +/- 1.73 yr of follow-up, 2408 women reported a fracture (excluding high-impact trauma) among 36,217 postmenopausal women from the E3N prospective study. We used Cox regression models to study the interaction between calcium and, respectively, proteins and RNAE, from the 1993 dietary questionnaire for fracture risk determination, adjusting for potential confounders. There was no overall association between fracture risk and total protein or RNAE. However, in the lowest quartile of calcium (<400 mg/1000 kcal), high protein intake was associated with a significant increased fracture risk (RR = 1.51 for highest versus lowest quartile; 95% CI, 1.17-1.94). An increasing fracture risk with increasing animal protein intake was also observed (trend, p < 0.0001). A similar pattern of interaction for fracture risk was observed between RNAE and calcium. In this Western population of postmenopausal women with normal to high protein intake and fairly high calcium intake, there was no overall association between total protein or RNAE and fracture risk. However, there was some evidence that high protein-high acid ash diets were associated with an increased risk of fracture when calcium intake was low (<400 mg/1000 kcal). PMID:18665794

  6. Characterization of Fatty Acid Composition in Bone Marrow Fluid From Postmenopausal Women: Modification After Hip Fracture.

    PubMed

    Miranda, Melissa; Pino, Ana María; Fuenzalida, Karen; Rosen, Clifford J; Seitz, Germán; Rodríguez, J Pablo

    2016-10-01

    Bone marrow adipose tissue (BMAT) is associated with low bone mass, although the functional consequences for skeletal maintenance of increased BMAT are currently unclear. BMAT might have a role in systemic energy metabolism, and could be an energy source as well as an endocrine organ for neighboring bone cells, releasing cytokines, adipokines and free fatty acids into the bone marrow microenvironment. The aim of the present report was to compare the fatty acid composition in the bone marrow supernatant fluid (BMSF) and blood plasma of postmenopausal women women (65-80 years old). BMSF was obtained after spinning the aspirated bone marrow samples; donors were classified as control, osteopenic or osteoporotic after dual-energy X-ray absorptiometry. Total lipids from human bone marrow fluid and plasma were extracted, converted to the corresponding methyl esters, and finally analyzed by a gas chromatographer coupled with a mass spectrometer. Results showed that fatty acid composition in BMSF was dynamic and distinct from blood plasma, implying significance in the locally produced lipids. The fatty acid composition in the BMSF was enriched in saturated fatty acid and decreased in unsaturated fatty acids as compared to blood plasma, but this relationship switched in women who suffered a hip fracture. On the other hand, there was no relationship between BMSF and bone mineral density. In conclusion, lipid composition of BMSF is distinct from the circulatory compartment, most likely reflecting the energy needs of the marrow compartment. J. Cell. Biochem. 117: 2370-2376, 2016. © 2016 Wiley Periodicals, Inc. PMID:27416518

  7. A mechanistic model of wormhole growth in carbonate matrix acidizing and acid fracturing

    SciTech Connect

    Hung, K.M.; Hill, A.D.; Sepehrnoorl, K.

    1989-01-01

    A mathematical model that describes the growth and competition of wormholes during ann acidizing treatment in a carbonate formation was developed. The model is initialized with the distribution of largest pores. Wormhole characteristics (size, length, and distribution) were found too be controlled by acid-injection, diffusion, and fluid-loss rates.

  8. The effect of 6 versus 9 years of zoledronic acid treatment in osteoporosis: a randomized second extension to the HORIZON-Pivotal Fracture Trial (PFT).

    PubMed

    Black, Dennis M; Reid, Ian R; Cauley, Jane A; Cosman, Felicia; Leung, Ping Chung; Lakatos, Peter; Lippuner, Kurt; Cummings, Steven R; Hue, Trisha F; Mukhopadhyay, Amitava; Tan, Monique; Aftring, R Paul; Eastell, Richard

    2015-05-01

    While bisphosphonates reduce fracture risk over 3 to 5 years, the optimal duration of treatment is uncertain. In a randomized extension study (E1) of the Health Outcomes and Reduced Incidence with Zoledronic Acid Once Yearly-Pivotal Fracture Trial (HORIZON-PFT), zoledronic acid (ZOL) 5 mg annually for 6 years showed maintenance of bone mineral density (BMD), decrease in morphometric vertebral fractures, and a modest reduction in bone turnover markers (BTMs) compared with discontinuation after 3 years. To investigate the longer-term efficacy and safety of ZOL, a second extension (E2) was conducted to 9 years in which women on ZOL for 6 years in E1 were randomized to either ZOL (Z9) or placebo (Z6P3) for 3 additional years. In this multicenter, randomized, double-blind study, 190 women were randomized to Z9 (n = 95) and Z6P3 (n = 95). The primary endpoint was change in total hip BMD at year 9 vs. year 6 in Z9 compared with Z6P3. Other secondary endpoints included fractures, BTMs, and safety. From year 6 to 9, the mean change in total hip BMD was -0.54% in Z9 vs. -1.31% in Z6P3 (difference 0.78%; 95% confidence interval [CI]: -0.37%, 1.93%; p = 0.183). BTMs showed small, non-significant increases in those who discontinued after 6 years compared with those who continued for 9 years. The number of fractures was low and did not significantly differ by treatment. While generally safe, there was a small increase in cardiac arrhythmias (combined serious and non-serious) in the Z9 group but no significant imbalance in other safety parameters. The results suggest almost all patients who have received six annual ZOL infusions can stop medication for up to 3 years with apparent maintenance of benefits. PMID:25545380

  9. Using Conductivity Measurements to Determine the Identities and Concentrations of Unknown Acids: An Inquiry Laboratory Experiment

    ERIC Educational Resources Information Center

    Smith, K. Christopher; Garza, Ariana

    2015-01-01

    This paper describes a student designed experiment using titrations involving conductivity measurements to identify unknown acids as being either HCl or H[subscript 2]SO[subscript 4], and to determine the concentrations of the acids, thereby improving the utility of standard acid-base titrations. Using an inquiry context, students gain experience…

  10. Electrical characterization of proton conducting polymer electrolyte based on bio polymer with acid dopant

    NASA Astrophysics Data System (ADS)

    Kalaiselvimary, J.; Pradeepa, P.; Sowmya, G.; Edwinraj, S.; Prabhu, M. Ramesh

    2016-05-01

    This study describes the biodegradable acid doped films composed of chitosan and Perchloric acid with different ratios (2.5 wt %, 5 wt %, 7.5 wt %, 10 wt %) was prepared by the solution casting technique. The temperature dependence of the proton conductivity of complex electrolytes obeys the Arrhenius relationship. Proton conductivity of the prepared polymer electrolyte of the bio polymer with acid doped was measured to be approximately 5.90 × 10-4 Scm-1. The dielectric data were analyzed using Complex impedance Z*, Dielectric loss ɛ', Tangent loss for prepared polymer electrolyte membrane with the highest conductivity samples at various temperature.

  11. Relations among water levels, specific conductance, and depths of bedrock fractures in four road-salt-contaminated wells in Maine, 2007–9

    USGS Publications Warehouse

    Schalk, Charles W.; Stasulis, Nicholas W.

    2012-01-01

    Data on groundwater-level, specific conductance (a surrogate for chloride), and temperature were collected continuously from 2007 through 2009 at four bedrock wells known to be affected by road salts in an effort to determine the effects of road salting and fractures in bedrock that intersect the well at a depth below the casing on the presence of chloride in groundwater. Dissolved-oxygen data collected periodically also were used to make inferences about the interaction of fractures and groundwater flow. Borehole geophysical tools were used to determine the depths of fractures in each well that were actively contributing flow to the well, under both static and pumped conditions; sample- and measurement-depths were selected to correspond to the depths of these active fractures. Samples of water from the wells, collected at depths corresponding to active bedrock fractures, were analyzed for chloride concentration and specific conductance; from these analyses, a linear relation between chloride concentration and specific conductance was established, and continuous and periodic measurements of specific conductance were assumed to represent chloride concentration of the well water at the depth of measurement. To varying degrees, specific conductance increased in at least two of the wells during winter and spring thaws; the shallowest well, which also was closest to the road receiving salt treatment during the winter, exhibited the largest changes in specific conductance during thaws. Recharge events during summer months, long after application of road salt had ceased for the year, also produced increases in specific conductance in some of the wells, indicating that chloride which had accumulated or sequestered in the overburden was transported to the wells throughout the year. Geophysical data and periodic profiles of water quality along the length of each well’s borehole indicated that the greatest changes in water quality were associated with active fractures; in

  12. DETERMINATION OF CARBOXYLIC ACIDS BY ION-EXCLUSION CHROMATOGRAPHY WITH NON-SUPPRESSED CONDUCTIVITY AND OPTICAL DETECTORS

    EPA Science Inventory

    Determination of carboxylic acids using non-suppressed conductivity and UV detections is described. The background conductance of 1-octanesulfonic acid, hexane sulfonic acid and sulfuric acid at varying concentrations was determined. Using 0.2 mM 1-octanesulfonic acid as a mobile...

  13. DETERMINATION OF CARBOXYLIC ACIDS BY ION-EXCLUSION CHROMATOGRAPHY WITH NON-SUPPRESSED CONDUCTIVITY AND OPTICAL DETECTORS

    EPA Science Inventory

    Determination of carboxylic acids using non-suppressed conductivity and UV detections is described. he background conductance of I-octanesulfonic acid, hexane sulfonic acid and sulfuric acid at varying concentrations was determined. sing 0.2 MM I-octanesulfonic acid as a mobile p...

  14. Highly conductive PEDOT:PSS treated with formic acid for ITO-free polymer solar cells.

    PubMed

    Mengistie, Desalegn A; Ibrahem, Mohammed A; Wang, Pen-Cheng; Chu, Chih-Wei

    2014-02-26

    We proposed a facile film treatment with formic acid to enhance the conductivity of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) by 4 orders of magnitude. The effect of formic acid concentration on conductivity was investigated; conductivity increased fast with increasing concentration up to 10 M and then increased slightly, the highest conductivity being 2050 S cm(-1) using 26 M concentration. Formic acid treated PEDOT:PSS films also exhibited very high transmittances. The mechanism of conductivity enhancement was explored through SEM, AFM, and XPS. Formic acid with its high dielectric constant screens the charge between PEDOT and PSS bringing about phase separation between them. Increased carrier concentration, removal of PSS from the film, morphology, and conformation change with elongated and better connected PEDOT chains are the main mechanisms of conductivity enhancement. ITO-free polymer solar cells were also fabricated using PEDOT:PSS electrodes treated with different concentrations of formic acid and showed equal performance to that of ITO electrodes. The concentrated acid treatment did not impair the desirable film properties as well as stability and performance of the solar cells. PMID:24460075

  15. A simple procedure for estimating the effective hydraulic conductivity of a two-dimensional saturated or partly-saturated fracture network

    SciTech Connect

    Zimmerman, R.W.; Bodvarsson, G.S.

    1995-04-01

    Many of the sites that have been proposed as potential locations of underground radioactive waste respositories contain fractured rocks. When modeling the hydrological behavior of these sites, for either the purpose of site characterization or performance assessment, computational gridblocks are often used that contain large numbers of individual fractures. In order to treat these gridblocks as equivalent continua, it is necessary to develop a procedure for relating the hydraulic properties of the individual fractures, and the topology of the fracture network, to the overall gridblock-scale permeability. The purpose of this paper is to describe a simple upscaling procedure, and demonstrate its use in cases of both saturated and unsaturated flow. The effective medium theory developed by Kirkpatrick has been used as the basis for a procedure for finding the effective gridblock-scale conductivity of a two-dimensional fracture network. In contrast to computationally-intensive flow simulations, the proposed procedure requires only the solution of a single nonlinear equation. The method has been tested against some previously published numerical simulations of flow through saturated and unsaturated networks, and in both cases yields reasonably accurate predictions of the macroscopic hydraulic conductivity.

  16. Aspects of fracture morphology exhibited in the stress corrosion behavior of Ti-155 in methanol-hydrochloric acid solution

    SciTech Connect

    Simbi, D.J.; Scully, J.C.

    1997-04-01

    Stress corrosion cracking (SCC) of Ti-155 was investigated in methanol-hydrochloric acid solution in preexposure and anodic polarization experiments using specimens with tensile axis in the parallel or transverse orientation to the rolling direction. Intergranular penetration data showed a dependence of the intergranular corrosion process on preexposure time. Susceptibility to SCC increased with increasing preexposure time and applied anodic current density. Fractographic analysis by scanning electro microscope (SEM) of fractured specimen surfaces in preexposure and anodic polarization experiments showed a fracture morphology comprised of intergranular at the exposure surface edge, an intermediate transgranular cleavage zone, and a terminal ductile region. These observations supported the view that intergranular fracture and transgranular cleavage occurring during SCC of titanium in MeOH-HCl solution is caused by mechanisms related to anodic dissolution and hydrogen embrittlement (HE), respectively. A mechanism to describe the simultaneous occurrence of dissolution and HE at the grain boundary was suggested.

  17. Enhanced charge transport in highly conducting PEDOT-PSS films after acid treatment

    NASA Astrophysics Data System (ADS)

    Shiva, V. Akshaya; Bhatia, Ravi; Menon, Reghu

    The high electrical conductivity, good stability, high strength, flexibility and good transparency of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS), make it useful for many applications including polymeric anodes for organic photovoltaics, light-emitting diodes, flexible electrodes, supercapacitors, electrochromic devices, field-effect transistors and antistatic-coatings. However, the electrical conductivity of PEDOT-PSS has to be increased significantly for replacement of indium tin oxide (ITO) as the transparent electrode in optoelectronic devices. The as prepared (pristine) PEDOT-PSS film prepared from the PEDOT-PSS aqueous solution usually has conductivity below 1Scm-1, remarkably lower than ITO. Significant conductivity enhancement has been observed on transparent and conductive PEDOT-PSS films after a treatment with inorganic acids. Our study investigates the charge transport in pristine and H2SO4, HNO3, HCl treated PEDOT-PSS films. We have treated the films with various concentrations of acids to probe the effect of the acid treatment on the conduction mechanism. The study includes the measurement of dc and electric field dependent conductivity of films in the temperature range of 4.2K-300K. We have also performed magneto-resistance measurements in the range of 0-5T. An enhancement by a factor of~103 has been observed in the room temperature conductivity. The detailed magneto-transport studies explain the various mechanisms for the conductivity enhancement observed.

  18. Enhancing proton conduction via doping of supramolecular liquid crystals (4-alkoxybenzoic acids) with imidazole

    NASA Astrophysics Data System (ADS)

    Liang, Ting; Wu, Yong; Tan, Shuai; Yang, Xiaohui; Wei, Bingzhuo

    2015-09-01

    Enhancing proton conduction via doping was first achieved in hydrogen-bonded liquid crystals consisting of benzoic acids. Supramolecular liquid crystals formed by pure 4-alkoxybenzoic acids (nAOBA, n = 8, 10, 12) exhibited the maximum proton conductivity of 5.0 × 10-8 S cm-1. Doping of nAOBA with 25 mol% imidazole (Im0.25) had little impact on mesomorphism but increased proton conductivities by at least 3 orders of magnitude. The liquid crystals formed by nAOBA-Im0.25 exhibited the maximum proton conductivity of 1.9 × 10-4 S cm-1. It was proposed that structure diffusion of imidazole bridged interdimer proton transfer to form continuous conducting pathways in mesomorphic nAOBA-Im0.25.

  19. CHARACTERIZATION OF H CANYON CONDUCTIVITY METER INDICATIONS WITH ELEVATED URANIUM IN NITRIC ACID

    SciTech Connect

    Nash, C

    2007-10-31

    Solution conductivity data from the 1CU conductivity meter in H-Canyon shows that uranium concentration in the 0 to 30 gram per liter (g/L) range has no statistically significant effect on the calibration of free nitric acid measurement. Based on these results, no additional actions are needed on the 1CU Conductivity Meter prior to or during the processing of uranium solutions in the 0 to 30 g/L range. A model based only on free nitric acid concentration is shown to be appropriate for explaining the data. Data uncertainties for the free acid measurement of uranium-bearing solutions are 8.5% or less at 95% confidence. The analytical uncertainty for calibrating solutions is an order of magnitude smaller only when uranium is not present, allowing use of a more accurate analytical procedure. Literature work shows that at a free nitric acid level of 0.33 M, uranium concentration of 30 g/L and 25 C, solution conductivity is 96.4% of that of a uranium-free solution. The level of uncertainties in the literature data and its fitting equation do not justify calibration changes based on this small depression in solution conductivity. This work supports preparation of H-Canyon processing of Super Kukla fuel; however, the results will be applicable to the processing of any similar concentration uranium and nitric acid solution. Super Kukla fuel processing will increase the uranium concentration above the nominal zero to 10 g/L level, though not above 30 g/L. This work examined free nitric acid levels ranging from 0.18 to 0.52 molar. Temperature ranged from 27.9 to 28.3 C during conductivity testing. The data indicates that sequential order of measurement is not a significant factor. The conductivity meter was thus flushed effectively between measurements as desired.

  20. Relevance of Aromatic Amino Acids for Electron Conduction along Geobacter Pili Protein

    NASA Astrophysics Data System (ADS)

    Adhikari, Ramesh; Malvankar, Nikhil; Tuominen, Mark; Lovley, Derek

    It has been proposed that the charge transport though Geobacter sulfurreducens pili protein occurs through the aromatic amino acids forming helical conducting chain within pili. X-ray studies of pili show that the aromatic amino acids are packed close enough (3-4 Å) for pi-stacking to occur. Conductivity of the pili network increases with lowering temperature indicating metallic-like transport mechanism. However due to the complexity of charge percolation path in 3D network, the intrinsic conductivity of an individual pili was not known. Here, we report transport measurements of individual pili of G. sulfurreducens. The conductivity, similar to that of organic polymers, shows that the pili may have implications in materials research. In addition, the conductivity value is sufficient to explain the respiration rate of the G. sulfurreducens. Further studies of pili from different natural and genetically modified species with varying amount of aromatic amino acid density demonstrate that it can play a decisive role on the magnitude of the conductivity. This research was supported by the Office of Naval Research (ONR) and National Science Foundation (NSF) Center for Hierarchical Manufacturing (CHM). Nikhil S. Malvankar holds a Career Award from the Burroughs Wellcome Fund.

  1. Sulfation of metal-organic framework: Opportunities for acid catalysis and proton conductivity

    SciTech Connect

    Goesten, M.G.; Stavitski, E.; Juan-Alcaniz, J.; Ramos-Fernandez, E.V.; Sai Sankar Gupta, K.B.; van Bekkum, H.; Gascon, J. and Kapteijn, F.

    2011-05-24

    A new post-functionalization method for metal-organic frameworks (MOFs) has been developed to introduce acidity for catalysis. Upon treatment with a mixture of triflic anhydride and sulfuric acid, chemically stable MOF structures MIL-101(Cr) and MIL-53(Al) can be sulfated, resulting in a Broensted sulfoxy acid group attached to up to 50% of the aromatic terephthalate linkers of the structure. The sulfated samples have been extensively characterized by solid-state NMR, XANES, and FTIR spectroscopy. The functionalized acidic frameworks show catalytic activity similar to that of acidic polymers like Nafion{reg_sign} display in the esterification of n-butanol with acetic acid (TOF {approx} 1 min{sup -1} {at} 343 K). Water adsorbs strongly up to 4 molecules per sulfoxy acid group, and an additional 2 molecules are taken up at lower temperatures in the 1-D pore channels of S-MIL-53(Al). The high water content and Broensted acidity provide the structure S-MIL-53(Al) a high proton conductivity up to moderate temperatures.

  2. Formation of Electrically Conducting Polypyrrole Fine Lines in Arachidic Acid Langmuir-Blodgett Films

    NASA Astrophysics Data System (ADS)

    Sha, Seimei; Hirata, Nobuaki; Ikezaki, Kazuo; Kaihatu, Minoru; Moriizumi, Toyosaka

    1995-07-01

    A new method is proposed for preparing electrically conducting fine lines in Langmuir-Blodgett films: during transference of arachidic acid L film containing pyrrole monomers to an indium-tin-oxide (ITO)-coated glass substrate, a voltage was applied between the ITO and the platinum counterelectrode dipped in the water subphase. From microscopic observations and conductivity measurements, it was confirmed that conducting filaments of polypyrrole were formed by this new method along the contact line between the substrate and the water surface by electrochemical polymerization of pyrrole monomers in an arachidic L film.

  3. Abiogenic and Microbial Controls on Volatile Fatty Acids in Precambrian Crustal Fracture Waters

    NASA Astrophysics Data System (ADS)

    McDermott, J. M.; Heuer, V.; Tille, S.; Moran, J.; Slater, G.; Sutcliffe, C. N.; Glein, C. R.; Hinrichs, K. U.; Sherwood Lollar, B.

    2015-12-01

    Saline fracture waters within the Precambrian Shield rocks of Canada and South Africa have been sequestered underground over geologic timescales up to 1.1-1.8 Ga [1, 2]. These fluids are rich in H2 derived from radiolysis and hydration of mafic and ultramafic rocks [1, 2, 3] and host a low-biomass, low-diversity microbial ecosystem at some sites [2]. The abiogenic or biogenic nature of geochemical processes has important implications for bioavailable carbon sources and the role played by abiotic organic synthesis in sustaining a chemosynthetic deep biosphere. Volatile fatty acids (VFAs) are simple carboxylic acids that may support microbial communities in such environments, such as those found in terrestrial [4] and deep-sea [5] hot springs. We present abundance and δ13C analysis for VFAs in a spectrum of Canadian Shield fluids characterized by varying dissolved H2, CH4, and C2+ n-alkane compositions. Isotope mass balance indicates that microbially mediated fermentation of carbon-rich graphitic sulfides may produce the elevated levels of acetate (39-273 μM) found in Birchtree and Thompson mine. In contrast, thermodynamic considerations and isotopic signatures of the notably higher acetate (1.2-1.9 mM), as well as formate and propionate abundances (371-816 μM and 20-38 μM, respectively) found at Kidd Creek mine suggest a role for abiogenic production via reduction of dissolved inorganic carbon with H2 for formate, and oxidation of C2+ n-alkanes for acetate and propionate, along with possible microbial cycling. VFAs comprise the bulk of dissolved and total organic carbon in the mines surveyed, and as such represent a potential key substrate for life. [1] Holland et al. (2013) Nature 497: 367-360. [2] Lin et al. (2006) Science 314: 479-482. [3] Sherwood Lollar et al. (2014) Nature 516: 379-382. [4] Windman et al. (2007) Astrobiology 7(6): 873-890. [5] Lang et al. (2010) Geochim. Cosmochim. Acta 92: 82-99.

  4. Conceptualizing Spatially Dynamic Groundwater-Surface Water Interactions along a Fractured Sedimentary Bedrock Riverbed through Electrical Resistivity and Induced Conductivity Measurements

    NASA Astrophysics Data System (ADS)

    Steelman, C. M.; Kennedy, C. S.; Parker, B. L.

    2014-12-01

    The Eramosa River located within the Grand River Watershed in Ontario, Canada, resides upon a densely fractured dolostone aquifer with abundant dissolution-enhanced channel features. While the bedrock aquifer represents a major component of the total water supply for the surrounding region, potential effects of increased groundwater extraction on surface water and surrounding ecosystems are not yet fully understood. In general, little is known about the nature of the interaction between surface water and groundwater along densely fractured sedimentary bedrock riverbeds. For instance, the timing and magnitude of groundwater discharge to surface water and surface water recharge in a fractured carbonate rock environment is expected to differ significantly from its alluvial channel analogs due to the presence of highly transmissive, planar and strongly orientated discrete fracture features that control flow. Non-invasive geophysical methods represent an opportunity to evaluate shallow groundwater dynamics with minimal environmental risk to biota and, ultimately enhance the interpretation of direct hydrogeologic data. Preliminary spatial electrical conductivity measurements collected along a 200 m reach of the river, suggests a seasonally dynamic hyporheic response over a riffle-pool sequence. Based on these results, time-lapse electrical resistivity measurements are being collected every 2-3 weeks along two ~50 m transects perpendicular to the river: the first transect considers changes across an intact bedrock section with exposed vertical and horizontal fracturing along the riverbed, while the second is positioned across a weathered bedrock section with a thin layer of course gravel and sand alluvium. The objective of this study is to collect electrical resistivity snapshots across the riverbed (6-8 m depths) to non-invasively quantify temporal and spatial changes in groundwater-surface water mixing from low to high-stage periods through multiple seasonal cycles

  5. Inhibition of cystic fibrosis transmembrane conductance regulator chloride channel currents by arachidonic acid.

    PubMed

    Linsdell, P

    2000-06-01

    Chloride permeation through the cystic fibrosis transmembrane conductance regulator (CFTR) Cl- channel is inhibited by a number of different classes of organic anions which are able to enter and block the channel pore from its cytoplasmic end. Here I show, using patch clamp recording from CFTR-transfected baby hamster kidney cell lines, that the cis-unsaturated fatty acid arachidonic acid also inhibits CFTR Cl- currents when applied to the cytoplasmic face of excised membrane patches. This inhibition was of a relatively high affinity compared with other known CFTR inhibitors, with an apparent Kd of 6.5 +/- 0.9 microM. However, in contrast with known CFTR pore blockers, inhibition by arachidonic acid was only very weakly voltage dependent, and was insensitive to the extracellular Cl- concentration. Arachidonic acid-mediated inhibition of CFTR Cl- currents was not abrogated by inhibitors of lipoxygenases, cyclooxygenases or cytochrome P450, suggesting that arachidonic acid itself, rather than some metabolite, directly affects CFTR. Similar inhibition of CFTR Cl- currents was seen with other fatty acids, with the rank order of potency linoleic > or = arachidonic > or = oleic > elaidic > or = palmitic > or = myristic. These results identify fatty acids as novel high affinity modulators of the CFTR Cl- channel. PMID:10914639

  6. Geophysical conceptualization of a fractured sedimentary bedrock riverbed using ground-penetrating radar and induced electrical conductivity

    NASA Astrophysics Data System (ADS)

    Steelman, C. M.; Kennedy, C. S.; Parker, B. L.

    2015-02-01

    Bedrock rivers exhibit very different hydraulic and ecological regimes compared to alluvial rivers. Groundwater-surface water interaction in rivers that flow directly on sedimentary bedrock surfaces with exposed fracture and conduit networks is generally based on alluvial river conceptual models. However, the dual and triple porosity systems of sedimentary rock (e.g., matrix, fractures and vugs) leads to highly variable hydraulic pathways and groundwater velocities that, in turn, result in processes that are very different than those derived from alluvial concepts. Relative to alluvial rivers there has been very little direct examination of dynamic interactions, such as fluxes, groundwater velocities, and mechanisms affecting water quality across the channel interface; this is largely because bedrock rivers are difficult to instrument and monitor given their heterogeneous and anisotropic flow systems. In this study, we evaluate the capacity of non-invasive, low impact ground-penetrating radar and frequency-domain electromagnetic induction methods capable of detecting discrete fracture and conduit features, mapping complex distributions of lithostratigraphic interfaces, and providing information about formation properties along a partially exposed section of the Eramosa River located in Ontario, Canada. Geophysical data are supported by direct hydrogeologic and geologic information obtained from a nearby borehole piezometer cluster and a continuous 15 m rock core. Valuable insights were gained into the lateral extent and geometry of structurally-controlled whydrostratigraphic units (e.g., dissolution-enhanced fractures, epikarst and karst features), which are expected to strongly influence groundwater and surface water interaction along the channel. An integrated application of GPR and EMI methods was necessary to fully understand the complex geometry of geologic boundaries and karst features within the shallow bedrock aquifer. The identification of epikarst below

  7. Use of weak acids to determine the bulk diffusion limitation of H+ ion conductance through the gramicidin channel.

    PubMed Central

    Decker, E R; Levitt, D G

    1988-01-01

    The addition of 2 M formic acid at pH 3.75 increased the single channel H+ ion conductance of gramicidin channels 12-fold at 200 mV. Other weak acids (acetic, lactic, oxalic) produce a similar, but smaller increase. Formic acid (and other weak acids) also blocks the K+ conductance at pH 3.75, but not at pH 6.0 when the anion form predominates. This increased H+ conductance and K+ block can be explained by formic acid (HF) binding to the mouth of the gramicidin channel (Km = 1 M) and providing a source of H+ ions. A kinetic model is derived, based on the equilibrium binding of formic acid to the channel mouth, that quantitatively predicts the conductance for different mixtures of H+, K+, and formic acid. The binding of the neutral formic acid to the mouth of the gramicidin channel is directly supported by the observation that a neutral molecule with a similar structure, formamide (and malonamide and acrylamide), blocks the K+ conductance at pH 6.0. The H+ conductance in the presence of formic acid provides a lower bound for the intrinsic conductance of the gramicidin channel when there is no diffusion limitation at the channel mouth. The 12-fold increase in conductance produced by formic acid suggests that greater than 90% of the total resistance to H+ results from diffusion limitation in the bulk solution. PMID:2449253

  8. Measurement of field-saturated hydraulic conductivity on fractured rock outcrops near Altamura (Southern Italy) with an adjustable large ring infiltrometer

    USGS Publications Warehouse

    Caputo, M.C.; de Carlo, L.; Masciopinto, C.; Nimmo, J.R.

    2010-01-01

    Up to now, field studies set up to measure field-saturated hydraulic conductivity to evaluate contamination risks, have employed small cylinders that may not be representative of the scale of measurements in heterogeneous media. In this study, a large adjustable ring infiltrometer was designed to be installed on-site directly on rock to measure its field-saturated hydraulic conductivity. The proposed device is inexpensive and simple to implement, yet also very versatile, due to its large adjustable diameter that can be fixed on-site. It thus allows an improved representation of the natural system's heterogeneity, while also taking into consideration irregularities in the soil/rock surface. The new apparatus was tested on an outcrop of karstic fractured limestone overlying the deep Murge aquifer in the South of Italy, which has recently been affected by untreated sludge disposal, derived from municipal and industrial wastewater treatment plants. The quasi-steady vertical flow into the unsaturated fractures was investigated by measuring water levels during infiltrometer tests. Simultaneously, subsurface electrical resistivity measurements were used to visualize the infiltration of water in the subsoil, due to unsaturated water flow in the fractures. The proposed experimental apparatus works well on rock outcrops, and allows the repetition of infiltration tests at many locations in order to reduce model uncertainties in heterogeneous media. ?? 2009 Springer-Verlag.

  9. Hydraulic conductivity study of compacted clay soils used as landfill liners for an acidic waste.

    PubMed

    Hamdi, Noureddine; Srasra, Ezzeddine

    2013-01-01

    Three natural clayey soils from Tunisia were studied to assess their suitability for use as a liner for an acid waste disposal site. An investigation of the effect of the mineral composition and mechanical compaction on the hydraulic conductivity and fluoride and phosphate removal of three different soils is presented. The hydraulic conductivity of these three natural soils are 8.5 × 10(-10), 2.08 × 10(-9) and 6.8 × 10(-10)m/s for soil-1, soil-2 and soil-3, respectively. Soil specimens were compacted under various compaction strains in order to obtain three wet densities (1850, 1950 and 2050 kg/m(3)). In this condition, the hydraulic conductivity (k) was reduced with increasing density of sample for all soils. The test results of hydraulic conductivity at long-term (>200 days) using acidic waste solution (pH=2.7, charged with fluoride and phosphate ions) shows a decrease in k with time only for natural soil-1 and soil-2. However, the specimens of soil-2 compressed to the two highest densities (1950 and 2050 kg/m(3)) are cracked after 60 and 20 days, respectively, of hydraulic conductivity testing. This damage is the result of a continued increase in the internal stress due to the swelling and to the effect of aggressive wastewater. The analysis of anions shows that the retention of fluoride is higher compared to phosphate and soil-1 has the highest sorption capacity. PMID:22980909

  10. Nose fracture

    MedlinePlus

    Fracture of the nose; Broken nose; Nasal fracture; Nasal bone fracture; Nasal septal fracture ... A fractured nose is the most common fracture of the face. It ... with other fractures of the face. Sometimes a blunt injury can ...

  11. Conductivity Measurements of Synthesized Heteropoly Acid Membranes for Proton Exchange Membrane Fuel Cells

    SciTech Connect

    Record, K.A.; Haley, B.T.; Turner, J.

    2006-01-01

    Fuel cell technology is receiving attention due to its potential to be a pollution free method of electricity production when using renewably produced hydrogen as fuel. In a Proton Exchange Membrane (PEM) fuel cell H2 and O2 react at separate electrodes, producing electricity, thermal energy, and water. A key component of the PEM fuel cell is the membrane that separates the electrodes. DuPont’s Nafion® is the most commonly used membrane in PEM fuel cells; however, fuel cell dehydration at temperatures near 100°C, resulting in poor conductivity, is a major hindrance to fuel cell performance. Recent studies incorporating heteropoly acids (HPAs) into membranes have shown an increase in conductivity and thus improvement in performance. HPAs are inorganic materials with known high proton conductivities. The primary objective of this work is to measure the conductivity of Nafion, X-Ionomer membranes, and National Renewable Energy Laboratory (NREL) Developed Membranes that are doped with different HPAs at different concentrations. Four-point conductivity measurements using a third generation BekkTech conductivity test cell are used to determine membrane conductivity. The effect of multiple temperature and humidification levels is also examined. While the classic commercial membrane, Nafion, has a conductivity of approximately 0.10 S/cm, measurements for membranes in this study range from 0.0030 – 0.58 S/cm, depending on membrane type, structure of the HPA, and the relative humidity. In general, the X-ionomer with H6P2W21O71 HPA gave the highest conductivity and the Nafion with the 12-phosphotungstic (PW12) HPA gave the lowest. The NREL composite membranes had conductivities on the order of 0.0013 – 0.025 S/cm.

  12. Study on the Effects of Adipic Acid on Properties of Dicyandiamide-Cured Electrically Conductive Adhesive and the Interaction Mechanism

    NASA Astrophysics Data System (ADS)

    Wang, Ling; Wan, Chao; Fu, Yonggao; Chen, Hongtao; Liu, Xiaojian; Li, Mingyu

    2014-01-01

    A small quantity of adipic acid was found to improve the performance of dicyandiamide-cured electrically conductive adhesive (ECA) by enhancing its electrical conductivity and mechanical properties. The mechanism of action of the adipic acid and its effects on the ECA were examined. The results indicated that adipic acid replaced the electrically insulating lubricant on the surface of the silver flakes, which significantly improved the electrical conductivity. Specifically, one of the acidic functional groups in adipic acid reacted with the silver flakes, and an amidation reaction occurred between the other acidic functional group in adipic acid and the dicyandiamide, which participated in the curing reaction. Therefore, adipic acid may act as a coupling agent to improve the overall ECA performance.

  13. Pyrrole-hyaluronic acid conjugates for decreasing cell binding to metals and conducting polymers

    PubMed Central

    Lee, Jae Young; Schmidt, Christine E.

    2010-01-01

    Surface modification of electrically conductive biomaterials has been studied to improve biocompatibility for a number of applications, such as implantable sensors and microelectrode arrays. In this study, we electrochemically coated electrodes with biocompatible and non-cell adhesive hyaluronic acid (HA) to reduce cellular adhesion for potential use in neural prostheses. To this end, pyrrole-conjugated hyaluronic acid (PyHA) was synthesized and employed for electrochemical coating of platinum, indium-tin-oxide, and polystyrene sulfonate-doped polypyrrole electrodes. This PyHA conjugate consists of (1) a pyrrole moiety that allows the compound to be electrochemically deposited onto a conductive substrate and (2) non-adhesive HA to minimize cell adhesion and to potentially decrease inflammatory tissue responses. Our characterization results showed the presence of a hydrophilic p(PyHA) layer on the modified electrode, and impedance measurements revealed impedance that was statistically the same as the unmodified electrode. We found that the p(PyHA)-coated electrodes minimized adhesion and migration of fibroblasts and astrocytes for a minimum of up to 3 months. Also, the coating was stable in physiological solution for 3 months and also stable against enzymatic degradation by hyaluronidase. These studies suggest that this p(PyHA)-coating has the potential to be used to mask conducting electrodes from adverse glial responses that occur upon implantation. In addition, electrochemical coating with PyHA can be potentially extended for the surface modification of other metallic and conducting substances such as stents and biosensors. PMID:20558330

  14. Low proton conductance of plant cuticles and its relevance to the acid-growth theory

    SciTech Connect

    Dreyer, S.A.; Seymour, V.; Cleland, R.E.

    1981-09-01

    Evidence obtained on the relation between the pH of the medium and the growth of intact stem sections is compatible with the acid-growth theory only if the proton conductance of the cuticle is an effective barrier to the entry or exit of protons from the tissue. By measuring the rate at which protons cross frozen-thawed epidermal strips of sunflower (Helianthus annus L.) and soybean hypocotyls (Glycine max Morr.) and enzymically isolated cuticles of Berberis aquifolium Persh. and tomato (Lycopersicum esculentum Mill.) fruit, we have now demonstrated the low proton conductance of the cuticular layer. Unless the conductance is enhanced by abrasion of the cuticle or by removal of the cuticular waxes, proton movement into and out of a tissue across the cuticle will be significant only over long time periods.

  15. Exceptionally crystalline and conducting acid doped polyaniline films by level surface assisted solution casting approach

    NASA Astrophysics Data System (ADS)

    Puthirath, Anand B.; Methattel Raman, Shijeesh; Varma, Sreekanth J.; Jayalekshmi, S.

    2016-04-01

    Emeraldine salt form of polyaniline (PANI) was synthesized by chemical oxidative polymerisation method using ammonium persulfate as oxidant. Resultant emeraldine salt form of PANI was dedoped using ammonia solution and then re-doped with camphor sulphonic acid (CSA), naphthaline sulphonic acid (NSA), hydrochloric acid (HCl), and m-cresol. Thin films of these doped PANI samples were deposited on glass substrates using solution casting method with m-cresol as solvent. A level surface was employed to get homogeneous thin films of uniform thickness. Detailed X-ray diffraction studies have shown that the films are exceptionally crystalline. The crystalline peaks observed in the XRD spectra can be indexed to simple monoclinic structure. FTIR and Raman spectroscopy studies provide convincing explanation for the exceptional crystallinity observed in these polymer films. FESEM and AFM images give better details of surface morphology of doped PANI films. The DC electrical conductivity of the samples was measured using four point probe technique. It is seen that the samples also exhibit quite high DC electrical conductivity, about 287 S/cm for CSA doped PANI, 67 S/cm for NSA doped PANI 65 S/cm for HCl doped PANI, and just below 1 S/cm for m-cresol doped PANI. Effect of using the level surface for solution casting is studied and correlated with the observed crystallinity.

  16. Hydraulic conductivity study of compacted clay soils used as landfill liners for an acidic waste

    SciTech Connect

    Hamdi, Noureddine; Srasra, Ezzeddine

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer Examined the hydraulic conductivity evolution as function of dry density of Tunisian clay soil. Black-Right-Pointing-Pointer Follow the hydraulic conductivity evolution at long-term of three clay materials using the waste solution (pH=2.7). Black-Right-Pointing-Pointer Determined how compaction affects the hydraulic conductivity of clay soils. Black-Right-Pointing-Pointer Analyzed the concentration of F and P and examined the retention of each soil. - Abstract: Three natural clayey soils from Tunisia were studied to assess their suitability for use as a liner for an acid waste disposal site. An investigation of the effect of the mineral composition and mechanical compaction on the hydraulic conductivity and fluoride and phosphate removal of three different soils is presented. The hydraulic conductivity of these three natural soils are 8.5 Multiplication-Sign 10{sup -10}, 2.08 Multiplication-Sign 10{sup -9} and 6.8 Multiplication-Sign 10{sup -10} m/s for soil-1, soil-2 and soil-3, respectively. Soil specimens were compacted under various compaction strains in order to obtain three wet densities (1850, 1950 and 2050 kg/m{sup 3}). In this condition, the hydraulic conductivity (k) was reduced with increasing density of sample for all soils. The test results of hydraulic conductivity at long-term (>200 days) using acidic waste solution (pH = 2.7, charged with fluoride and phosphate ions) shows a decrease in k with time only for natural soil-1 and soil-2. However, the specimens of soil-2 compressed to the two highest densities (1950 and 2050 kg/m{sup 3}) are cracked after 60 and 20 days, respectively, of hydraulic conductivity testing. This damage is the result of a continued increase in the internal stress due to the swelling and to the effect of aggressive wastewater. The analysis of anions shows that the retention of fluoride is higher compared to phosphate and soil-1 has the highest sorption capacity.

  17. Young's modulus and fracture during Knoop indentation of potassium, rubidium, cesium, and ammonium acid phthalate single crystals on the (010) plane

    NASA Astrophysics Data System (ADS)

    Sizova, N. L.; Moiseeva, N. A.

    2012-12-01

    The correlation of the anisotropy of the Young's modulus of organic single crystals of potassium, rubidium, cesium, and ammonium acid phthalates with strain and fracture patterns during Knoop indentation on the (010) cleavage plane in the [001] and [100] directions has been studied. The data on the maximum anisotropy of the strain and fracture patterns of the ammonium acid phthalate single crystal have been discussed in view of the published data on the structure, mechanical, elastic, and X-ray spectral properties of these crystals.

  18. Nose fracture

    MedlinePlus

    Fracture of the nose; Broken nose; Nasal fracture; Nasal bone fracture; Nasal septal fracture ... A fractured nose is the most common fracture of the face. It usually occurs after an injury and often occurs with ...

  19. Administration of Tranexamic Acid Reduces Postoperative Blood Loss in Calcaneal Fractures: A Randomized Controlled Trial.

    PubMed

    Xie, Bing; Tian, Jing; Zhou, Da-peng

    2015-01-01

    The present randomized controlled trial was undertaken to evaluate the effect of tranexamic acid (TXA) on reducing postoperative blood loss in calcaneal fractures. A total of 90 patients with a unilateral closed calcaneal fracture were randomized to the TXA (n = 45) and control (n = 45) groups. The corresponding groups received 15 mg/kg body weight of TXA or placebo (0.9% sodium chloride solution) intravenously before the skin incision was made. Open reduction and internal fixation was performed for all patients and selective bone grafting was performed. The patients were examined 3 months after surgery. The intraoperative and postoperative blood loss, blood test results, and wound complications were compared between the 2 groups. The complications of TXA were also investigated. No statistically significant differences were found in the baseline characteristics between the TXA and control groups. Also, no significant difference was noted in the intraoperative blood loss between the 2 groups. However, in the TXA group, the postoperative blood loss during the first 24 hours was significantly lower than that in the control group (110.0 ± 160.0 mL versus 320.0 ± 360.0 mL; p < .001). The incidence of wound complications was also reduced compared with that in the control group (7.3% versus 23.8%; p = .036). No significant difference was found in the incidence of thromboembolic events or adverse drug reactions between the 2 groups. We concluded that preoperative single-dose TXA can effectively reduce postoperative blood loss and wound complications in patients with calcaneal fractures and that no significant side effects developed compared with the control group. PMID:26310621

  20. Skull fracture

    MedlinePlus

    Basilar skull fracture; Depressed skull fracture; Linear skull fracture ... Skull fractures may occur with head injuries . The skull provides good protection for the brain. However, a severe impact ...

  1. Separation and determination of degradation products of acid orange 7 by capillary electrophoresis/capacitively coupled contactless conductivity detector.

    PubMed

    Wang, Xin; Xiong, Ya; Xie, Tianyao; Sharma, Virender K; Tu, Yuting; Yang, Jiannan; Tian, Shuanghong; He, Chun

    2013-07-15

    Capillary electrophoresis (CE) with capacitively coupled contactless conductivity detector (C(4)D) was developed to separate azo-dyestuff acid orange 7 (AO7) and its six degradation products. The analyzed products were sulfamic acid, oxalic acid, benzenesulfonic acid, 4-hydroxybenzene sulfonic acid, phthalic acid, and 4-aminobenzene sulfonic acid. In developing the method, types and concentrations of running buffers, injecting voltage and time, and applied voltage were tested to obtain optimum conditions to analyze target compounds. The separation was successfully achieved within 10 min using a fused-silica capillary under the following conditions: 20 mmol L(-1) acetate acid buffer, electrokinetic injection of -12 kV × 10 s, and applied voltage of -13 kV. The developed method was applied to analyze degradation products in situ during the reaction of AO7 with Fenton reagent (Fe(II)+H2O2 at pH 4.0). PMID:23622525

  2. Plasma phosphatidylcholine concentrations of polyunsaturated fatty acids are differentially associated with hop bone mineral density and hip fracture in older adults: The Framingham Osteoporosis Study

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Polyunsaturated fatty acids (PUFA) may influence bone health. Our objective was to examine associations between plasma phosphatidylcholine (PC) PUFA concentrations and hip measures: 1) femoral neck bone mineral density (FN-BMD) (n=765); 2) 4-y change in FN-BMD (n=556); and 3) hip fracture risk (n=76...

  3. Comparison of alternative representations of hydraulic-conductivity anisotropy in folded fractured-sedimentary rock: Modeling groundwater flow in the Shenandoah Valley (USA)

    USGS Publications Warehouse

    Yager, R.M.; Voss, C.I.; Southworth, S.

    2009-01-01

    A numerical representation that explicitly represents the generalized three-dimensional anisotropy of folded fractured-sedimentary rocks in a groundwater model best reproduces the salient features of the flow system in the Shenandoah Valley, USA. This conclusion results from a comparison of four alternative representations of anisotropy in which the hydraulic-conductivity tensor represents the bedrock structure as (model A) anisotropic with variable strikes and dips, (model B) horizontally anisotropic with a uniform strike, (model C) horizontally anisotropic with variable strikes, and (model D) isotropic. Simulations using the US Geological Survey groundwater flow and transport model SUTRA are based on a representation of hydraulic conductivity that conforms to bedding planes in a three-dimensional structural model of the valley that duplicates the pattern of folded sedimentary rocks. In the most general representation, (model A), the directions of maximum and medium hydraulic conductivity conform to the strike and dip of bedding, respectively, while the minimum hydraulic-conductivity direction is perpendicular to bedding. Model A produced a physically realistic flow system that reflects the underlying bedrock structure, with a flow field that is significantly different from those produced by the other three models. ?? Springer-Verlag 2009.

  4. Degradation studies of transparent conductive electrodes on electroactive poly(vinylidene fluoride) for uric acid measurements

    NASA Astrophysics Data System (ADS)

    Cardoso, Vanessa F.; Martins, Pedro; Botelho, Gabriela; Rebouta, Luis; Lanceros-Méndez, Senentxu; Minas, Graca

    2010-08-01

    Biochemical analysis of physiological fluids using, for example, lab-on-a-chip devices requires accurate mixing of two or more fluids. This mixing can be assisted by acoustic microagitation using a piezoelectric material, such as the β-phase of poly(vinylidene fluoride) (β-PVDF). If the analysis is performed using optical absorption spectroscopy and β-PVDF is located in the optical path, the material and its conductive electrodes must be transparent. Moreover, if, to improve the transmission of the ultrasonic waves to the fluids, the piezoelectric transducer is placed inside the fluidic structures, its degradation must be assessed. In this paper, we report on the degradation properties of transparent conductive oxides, namely, indium tin oxide (ITO) and aluminum-doped zinc oxide, when they are used as electrodes for providing acoustic microagitation. The latter promotes mixing of chemicals involved in the measurement of uric acid concentration in physiological fluids. The results are compared with those for aluminum electrodes. We find that β-PVDF samples with ITO electrodes do not degrade either with or without acoustic microagitation.

  5. The effect of formic acid concentration on the conductivity and corrosion resistance of chromium carbide coatings electroplated with trivalent chromium

    NASA Astrophysics Data System (ADS)

    Lu, Chen-En; Pu, Nen-Wen; Hou, Kung-Hsu; Tseng, Chun-Chieh; Ger, Ming-Der

    2013-10-01

    Different concentrations of formic acid were added into a trivalent chromium electroplating solution to produce chromium carbide (Crsbnd C) coatings. The influence of the formic acid concentration on chemical composition, microstructure, surface morphology, corrosion resistance, conductivity and carbon content of the resulting Crsbnd C coatings was studied. Formic acid was found to increase the carbon content in the coatings so as to form Crsbnd C films. These coatings had a nearly amorphous structure containing Cr, Cr2O3, and various Crsbnd C compounds with carbon content uniformly distributed throughout the coatings. The carbon content and the conductivity of the Crsbnd C layer were correlated with formic acid concentration. For a formic acid concentration of 2 M, the Crsbnd C layer had the highest carbon content (∼28%), the lowest contact resistance, and the best corrosion resistance along with a corrosion current density of ∼6.4 × 10-7 A/cm2.

  6. The Effect of 3 Versus 6 Years of Zoledronic Acid Treatment of Osteoporosis: A Randomized Extension to the HORIZON-Pivotal Fracture Trial (PFT)

    PubMed Central

    Black, Dennis M; Reid, Ian R; Boonen, Steven; Bucci-Rechtweg, Christina; Cauley, Jane A; Cosman, Felicia; Cummings, Steven R; Hue, Trisha F; Lippuner, Kurt; Lakatos, Peter; Leung, Ping Chung; Man, Zulema; Martinez, Ruvie Lou Maria; Tan, Monique; Ruzycky, Mary Ellen; Su, Guoqin; Eastell, Richard

    2012-01-01

    Zoledronic acid 5 mg (ZOL) annually for 3 years reduces fracture risk in postmenopausal women with osteoporosis. To investigate long-term effects of ZOL on bone mineral density (BMD) and fracture risk, the Health Outcomes and Reduced Incidence with Zoledronic acid Once Yearly–Pivotal Fracture Trial (HORIZON-PFT) was extended to 6 years. In this international, multicenter, double-blind, placebo-controlled extension trial, 1233 postmenopausal women who received ZOL for 3 years in the core study were randomized to 3 additional years of ZOL (Z6, n = 616) or placebo (Z3P3, n = 617). The primary endpoint was femoral neck (FN) BMD percentage change from year 3 to 6 in the intent-to-treat (ITT) population. Secondary endpoints included other BMD sites, fractures, biochemical bone turnover markers, and safety. In years 3 to 6, FN-BMD remained constant in Z6 and dropped slightly in Z3P3 (between-treatment difference = 1.04%; 95% confidence interval 0.4 to 1.7; p = 0.0009) but remained above pretreatment levels. Other BMD sites showed similar differences. Biochemical markers remained constant in Z6 but rose slightly in Z3P3, remaining well below pretreatment levels in both. New morphometric vertebral fractures were lower in the Z6 (n = 14) versus Z3P3 (n = 30) group (odds ratio = 0.51; p = 0.035), whereas other fractures were not different. Significantly more Z6 patients had a transient increase in serum creatinine >0.5 mg/dL (0.65% versus 2.94% in Z3P3). Nonsignificant increases in Z6 of atrial fibrillation serious adverse events (2.0% versus 1.1% in Z3P3; p = 0.26) and stroke (3.1% versus 1.5% in Z3P3; p = 0.06) were seen. Postdose symptoms were similar in both groups. Reports of hypertension were significantly lower in Z6 versus Z3P3 (7.8% versus 15.1%, p < 0.001). Small differences in bone density and markers in those who continued versus those who stopped treatment suggest residual effects, and therefore, after 3 years of annual ZOL, many patients may discontinue

  7. 2-Hydroxy-4-methylbenzenesulfonic acid dihydrate: Crystal structure, vibrational spectra, proton conductivity, and thermal stability

    NASA Astrophysics Data System (ADS)

    Pisareva, A. V.; Shilov, G. V.; Karelin, A. I.; Dobrovolsky, Yu. A.; Pisarev, R. V.

    2010-03-01

    The crystal and molecular structure of 2-hydroxy4-methylbenzenesulfonic acid dihydrate C6H3(CH3)(OHSO- 3 H5O2 + (I) was studied by X-ray diffraction and vibrational spectroscopy. The compound crystallized in the monoclinic crystal system; crystal data: a=10.853(2) Å, b=7.937(2) Å, c=12.732(3) Å, β=112.13(3)°, V=1015.9(4)Å3,Z=4,dcalc=1.466g/cm3,spacegroupP21/c,Rf=0.0486,GOOF=1.161.The S-O distances in the sulfonate group differed substantially (S1-O2 1.439(2) Å, S1-O3 1.455(2) Å, and S1-O4 1.464(2) Å. The symmetry of the H5O2 cation decreased due to proton displacement toward one of the two water molecules. XRD data on the asymmetry of H5O2 were confirmed by IR and Raman spectral data. The strong triplet at 2900, 3166, 3377 cm-1 in the IR spectrum of I corresponds to different types of H-bond and shifted to 2185, 2363, 2553 cm-1 after deuteration. The proton conductivity of the compound was measured by impedance spectroscopy: 6 × 10-7 S/cm at 298 K (32 rel %), E act=0.4±0.01 eV. The conductivity increased to 10-3 S/cm, Eact=0.1 eV when ambient humidity increased to 60 rel %.

  8. Abscisic Acid Induces Rapid Reductions in Mesophyll Conductance to Carbon Dioxide.

    PubMed

    Sorrentino, Giuseppe; Haworth, Matthew; Wahbi, Said; Mahmood, Tariq; Zuomin, Shi; Centritto, Mauro

    2016-01-01

    The rate of photosynthesis (A) of plants exposed to water deficit is a function of stomatal (gs) and mesophyll (gm) conductance determining the availability of CO2 at the site of carboxylation within the chloroplast. Mesophyll conductance often represents the greatest impediment to photosynthetic uptake of CO2, and a crucial determinant of the photosynthetic effects of drought. Abscisic acid (ABA) plays a fundamental role in signalling and co-ordination of plant responses to drought; however, the effect of ABA on gm is not well-defined. Rose, cherry, olive and poplar were exposed to exogenous ABA and their leaf gas exchange parameters recorded over a four hour period. Application with ABA induced reductions in values of A, gs and gm in all four species. Reduced gm occurred within one hour of ABA treatment in three of the four analysed species; indicating that the effect of ABA on gm occurs on a shorter timescale than previously considered. These declines in gm values associated with ABA were not the result of physical changes in leaf properties due to altered turgor affecting movement of CO2, or caused by a reduction in the sub-stomatal concentration of CO2 (Ci). Increased [ABA] likely induces biochemical changes in the properties of the interface between the sub-stomatal air-space and mesophyll layer through the actions of cooporins to regulate the transport of CO2. The results of this study provide further evidence that gm is highly responsive to fluctuations in the external environment, and stress signals such as ABA induce co-ordinated modifications of both gs and gm in the regulation of photosynthesis. PMID:26862904

  9. Abscisic Acid Induces Rapid Reductions in Mesophyll Conductance to Carbon Dioxide

    PubMed Central

    Sorrentino, Giuseppe; Haworth, Matthew; Wahbi, Said; Mahmood, Tariq; Zuomin, Shi; Centritto, Mauro

    2016-01-01

    The rate of photosynthesis (A) of plants exposed to water deficit is a function of stomatal (gs) and mesophyll (gm) conductance determining the availability of CO2 at the site of carboxylation within the chloroplast. Mesophyll conductance often represents the greatest impediment to photosynthetic uptake of CO2, and a crucial determinant of the photosynthetic effects of drought. Abscisic acid (ABA) plays a fundamental role in signalling and co-ordination of plant responses to drought; however, the effect of ABA on gm is not well-defined. Rose, cherry, olive and poplar were exposed to exogenous ABA and their leaf gas exchange parameters recorded over a four hour period. Application with ABA induced reductions in values of A, gs and gm in all four species. Reduced gm occurred within one hour of ABA treatment in three of the four analysed species; indicating that the effect of ABA on gm occurs on a shorter timescale than previously considered. These declines in gm values associated with ABA were not the result of physical changes in leaf properties due to altered turgor affecting movement of CO2, or caused by a reduction in the sub-stomatal concentration of CO2 (Ci). Increased [ABA] likely induces biochemical changes in the properties of the interface between the sub-stomatal air-space and mesophyll layer through the actions of cooporins to regulate the transport of CO2. The results of this study provide further evidence that gm is highly responsive to fluctuations in the external environment, and stress signals such as ABA induce co-ordinated modifications of both gs and gm in the regulation of photosynthesis. PMID:26862904

  10. Low urine pH and acid excretion do not predict bone fractures or the loss of bone mineral density: a prospective cohort study

    PubMed Central

    2010-01-01

    Background The acid-ash hypothesis, the alkaline diet, and related products are marketed to the general public. Websites, lay literature, and direct mail marketing encourage people to measure their urine pH to assess their health status and their risk of osteoporosis. The objectives of this study were to determine whether 1) low urine pH, or 2) acid excretion in urine [sulfate + chloride + 1.8x phosphate + organic acids] minus [sodium + potassium + 2x calcium + 2x magnesium mEq] in fasting morning urine predict: a) fragility fractures; and b) five-year change of bone mineral density (BMD) in adults. Methods Design: Cohort study: the prospective population-based Canadian Multicentre Osteoporosis Study. Multiple logistic regression was used to examine associations between acid excretion (urine pH and urine acid excretion) in fasting morning with the incidence of fractures (6804 person years). Multiple linear regression was used to examine associations between acid excretion with changes in BMD over 5-years at three sites: lumbar spine, femoral neck, and total hip (n = 651). Potential confounders controlled included: age, gender, family history of osteoporosis, physical activity, smoking, calcium intake, vitamin D status, estrogen status, medications, renal function, urine creatinine, body mass index, and change of body mass index. Results There were no associations between either urine pH or acid excretion and either the incidence of fractures or change of BMD after adjustment for confounders. Conclusion Urine pH and urine acid excretion do not predict osteoporosis risk. PMID:20459740

  11. Electrically conductive PVC layers filled with active carbon containing H+-conducting porous structures of sulfuric acid complexes of cyclams on fabrics

    NASA Astrophysics Data System (ADS)

    Tsivadze, A. Yu.; Fridman, A. Ya.; Morozova, E. M.; Sokolova, N. P.; Voloshchuk, A. M.; Petukhova, G. A.; Bardyshev, I. I.; Gorbunov, A. M.; Novikov, A. K.; Polyakova, I. Ya.; Titova, V. N.; Yavich, A. A.; Petrova, N. V.; Krasil'nikova, O. K.

    2015-07-01

    Electrically conductive PVC layers are synthesized. The layers are filled with active carbons containing porous H+-conductive structures of hydroxyethylcyclam/sulfuric acid complexes crosslinked with cellulose fabric. They are interlaid with layers based on the same structures containing added benzene and hexane adsorbates and solvates. It is found that upon anode or cathode polarization of the layers as H+-conductive electrochemical bridges in air and in the vapor and liquid phases of benzene and hexane, either the electroreduction of H+ to H2 or the electrooxidation of H2O to O2 occurs in the areas of contact between active carbon particles and the complexes. The dependences of rates of H2 and O2 formation on the voltage are studied. The magnitudes of overvoltage and the constants of electrochemical reactions are found to depend on the composition of a layer.

  12. Studies of structural, optical, dielectric relaxation and ac conductivity of different alkylbenzenesulfonic acids doped polypyrrole nanofibers

    NASA Astrophysics Data System (ADS)

    Hazarika, J.; Kumar, A.

    2016-01-01

    Polypyrrole (PPy) nanofibers doped with alkylbenzenesulfonic acids (ABSA) have been synthesized using interfacial polymerization method. HRTEM studies confirm the formation of PPy nanofibers with average diameter ranging from 13 nm to 25 nm. Broad X-ray diffraction peak in 2 θ range 20-23.46° reveals amorphous structure of PPy nanofibers. The ordering or crystallinity of polymer chains increases, while their interplanar spacing (d) and interchain separation (R) decreases for short alkyl chain ABSA doped PPy nanofibers. FTIR studies reveal that short alkyl chain ABSA doped PPy nanofibers show higher value of "effective conjugation length". PPy nanofibers doped with short alkyl chain ABSA dopant exhibit smaller optical band gap. TGA studies show enhanced thermal stability of short alkyl chain ABSA doped PPy nanofibers. Decrease in dielectric permittivity ε ‧ (ω) with increasing frequency suggests presence of electrode polarization effects. Linear decrease in dielectric loss ε ″ (ω) with increasing frequency suggests dominant effect of dc conductivity process. Low value of non-exponential exponent β (<1) reveals non-Debye relaxation of charge carriers. Scaling of imaginary modulus (M ″) reveals that the charge carriers follow the same relaxation mechanism. Moreover, the charge carriers in PPy nanofibers follow the correlated barrier hopping (CBH) transport mechanism.

  13. Comparison of chondroitin sulfate and hyaluronic Acid doped conductive polypyrrole films for adipose stem cells.

    PubMed

    Björninen, Miina; Siljander, Aliisa; Pelto, Jani; Hyttinen, Jari; Kellomäki, Minna; Miettinen, Susanna; Seppänen, Riitta; Haimi, Suvi

    2014-09-01

    Polypyrrole (PPy) is a conductive polymer that has aroused interest due to its biocompatibility with several cell types and high tailorability as an electroconductive scaffold coating. This study compares the effect of hyaluronic acid (HA) and chondroitin sulfate (CS) doped PPy films on human adipose stem cells (hASCs) under electrical stimulation. The PPy films were synthetized electrochemically. The surface morphology of PPy-HA and PPy-CS was characterized by an atomic force microscope. A pulsed biphasic electric current (BEC) was applied via PPy films non-stimulated samples acting as controls. Viability, attachment, proliferation and osteogenic differentiation of hASCs were evaluated by live/dead staining, DNA content, Alkaline phosphatase activity and mineralization assays. Human ASCs grew as a homogenous cell sheet on PPy-CS surfaces, whereas on PPy-HA cells clustered into small spherical structures. PPy-CS supported hASC proliferation significantly better than PPy-HA at the 7 day time point. Both substrates equally triggered early osteogenic differentiation of hASCs, although mineralization was significantly induced on PPy-CS compared to PPy-HA under BEC. These differences may be due to different surface morphologies originating from the CS and HA dopants. Our results suggest that PPy-CS in particular is a potential osteogenic scaffold coating for bone tissue engineering. PMID:24823653

  14. Simultaneous determination of nitric acid and uranium concentrations in aqueous solution from measurements of electrical conductivity, density, and temperature

    SciTech Connect

    Spencer, B.B.

    1991-01-01

    Nuclear fuel reprocessing plants handle aqueous solutions of nitric acid and uranium in large quantities. Automatic control of process operations requires reliable measurements of these solutes concentration, but this is difficult to directly measure. Physical properties such as solution density and electrical conductivity vary with solute concentration and temperature. Conductivity, density and temperature can be measured accurately with relatively simple and inexpensive devices. These properties can be used to determine solute concentrations will good correlations. This paper provides the appropriate correlations for solutions containing 2 to 6 Molar (M) nitric acid and 0 to 300 g/L uranium metal at temperatures from 25--90{degrees}C. The equations are most accurate below 5 M nitric acid, due to a broad maximum in the conductivity curve at 6 M. 12 refs., 9 figs., 6 tabs.

  15. Spatially Modulating Interfacial Properties of Transparent Conductive Oxides: Patterning Work Function with Phosphonic Acid Self-Assembled Monolayers

    SciTech Connect

    Knesting, Kristina M.; Hotchkiss, Peter J.; MacLeod, Bradley A.; Marder, Seth R.; Ginger, David S.

    2011-09-29

    The interface between an organic semiconductor and a transparent conducting oxide is crucial to the performance of organic optoelectronics. We use microcontact printing to pattern pentafluorobenzyl phosphonic acid self-assembled monolayers (SAMs) on indium tin oxide (ITO). We obtain high-fidelity patterns with sharply defined edges and with large work function contrast (comparable to that obtained from phosphonic acid SAMs deposited from solution).

  16. Kinetics of the electrochemical mineralization of perfluorooctanoic acid on ultrananocrystalline boron doped conductive diamond electrodes.

    PubMed

    Urtiaga, Ane; Fernández-González, Carolina; Gómez-Lavín, Sonia; Ortiz, Inmaculada

    2015-06-01

    This work deals with the electrochemical degradation and mineralization of perfluorooctanoic acid (PFOA). Model aqueous solutions of PFOA (100mg/L) were electro-oxidized under galvanostatic conditions in a flow-by undivided cell provided with a tungsten cathode and an anode formed by a commercial ultrananocrystalline boron doped diamond (BDD) coating on a niobium substrate. A systematic experimental study was conducted in order to analyze the influence of the following operation variables: (i) the supporting electrolyte, NaClO4 (1.4 and 8.4g/L) and Na2SO4 (5g/L); (ii) the applied current density, japp, in the range 50-200 A/m(2) and (iii) the hydrodynamic conditions, in terms of flowrate in the range 0.4×10(-4)-1.7×10(-4)m(3)/s and temperature in the range 293-313K. After 6h of treatment and at japp 200A/m(2), PFOA removal was higher than 93% and the mineralization ratio, obtained from the decrease of the total organic carbon (TOC) was 95%. The electrochemical generation of hydroxyl radicals in the supporting electrolyte was experimentally measured based on their reaction with dimethyl sulfoxide. The enhanced formation of hydroxyl radicals at higher japp was related to the faster kinetics of PFOA removal. The fitting of experimental data to the proposed kinetic model provided the first order rate constants of PFOA degradation, kc(1) that moved from 2.06×10(-4) to 15.58×10(-4)s(-1), when japp varied from 50 to 200A/m(2). PMID:24981910

  17. An electrically conductive 3D scaffold based on a nonwoven web of poly(L-lactic acid) and conductive poly(3,4-ethylenedioxythiophene).

    PubMed

    Niu, Xufeng; Rouabhia, Mahmoud; Chiffot, Nicolas; King, Martin W; Zhang, Ze

    2015-08-01

    This study was to demonstrate that an extremely thin coating of poly(3,4-ethylenedioxythiophene) (PEDOT) on nonwoven microfibrous poly(l-lactic acid) (PLLA) web is of sufficient electrical conductivity and stability in aqueous environment to sustain electrical stimulation (ES) to cultured human skin fibroblasts. The PEDOT imparted the web a surface resistivity of approximately 0.1 KΩ/square without altering the web morphology. X-ray photoelectron spectroscopy demonstrated that the surface chemistry of the PLLA/PEDOT is characteristic of both PLLA and PEDOT. The PEDOT-coated web also showed higher hydrophilicity, lower glass transition temperature and unchanged fiber crystallinity and thermal stability compared with the PLLA web. The addition of PEDOT to the web marginally increased the web's tensile strength and lowered the elongation. An electrical stability test showed that the PLLA/PEDOT structure was more stable than a polypyrrole treated PLLA fabric, showing only a slow deterioration in conductivity when exposed to culture medium. The cytotoxicity test showed that the PLLA/PEDOT scaffold was not cytotoxic and supported human dermal fibroblast adhesion, migration, and proliferation. Preliminary ES experiments have demonstrated that this conductive web mediated effective ES to fibroblasts. Therefore, this new conductive biodegradable scaffold may be used to electrically modulate cellular activity and tissue regeneration. PMID:25630631

  18. Waterflood-induced fractures

    SciTech Connect

    Dikken, B.J.; Niko, H.

    1987-01-01

    Fracturing occurs quite often in water injection wells, with sometimes unforeseen consequences on waterflood sweep efficiency. One of the causes of fracturing is often the cooling of hot formations by cold injection water. A special version of a thermal reservoir simulator for prototype applications has thus been constructed that is capable of dealing with propagating waterflood-induces hydraulic fractures. With this simulator, fracture propagation and the effect of growing fractures on the sweep efficiency are studied. Infinite fracture conductivity is assumed. The limitation to a very high leak-off fractures justifies disregarding the changes in fracture volume. Fracture growth is calculated using the concept of a critical stress intensity factor. Both poro- and thermo-elastic changes in the horizontal stresses are calculated numerically and their influence on the fracture initiation/propagation is continuously taken into account. In addition, a model of fracture wall impairment because of filter-cake build-up due to poor quality injection water is included. Results are presented for both thermal and isothermal situations. It is observed in isothermal cases that the voidage replacement ratio (volume balance during injection) determined to a great extent the length to which the fracture eventually may grow.

  19. Development of Conducting Polyaniline/ Poly(Lactic Acid) Nanofibers by Electrospinning

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Ultrafine fibers consisting of blends of polyaniline doped with p-toluene sulfonic acid and poly(L-lactic acid) were prepared by electrospinning. The presence of polyaniline resulted in fibers with diameters as thin as 100– 200 nm and a significant reduction of bead formation. These fibers were visu...

  20. Electrical conductivity measurements of aqueous boric acid at 25--350{degree}C at saturation vapor pressure. Final report

    SciTech Connect

    Ho, P.C.; Palmer, D.A.

    1995-09-01

    Electrical conductance measurements of aqueous boric acid solutions (15-110 g/kg-H{sub 2}O {equivalent_to} 0.251--1.815 mol/kg-H{sub 2}O) were measured over the temperature range 25 to 75 C at saturation vapor pressures in glass cells with parallel platinum electrodes. Sixteen series of measurements were made involving three samples of boric acid from different sources. Conductance measurements were also made at 15.5 and 30.5 g/kg-H{sub 2}O over the temperature range 100 to 350 C at 50 C intervals with a metallic cell fitted with concentric platinum electrodes. The specific conductances of H{sub 3}BO{sub 3} (aq)were calculated after correction for the conductance of the solvent (water) and are tabulated in this report. At the specific conditions requested in the project description, namely a concentration of 110 g/kg-H{sub 2}O and 65 C, the specific conductance of boric acid is 293.2 {+-} 1.8 microSiemens/cm based on duplicate measurements of four independent solutions. The results from these tests will be utilized by the Tokamak Physics Experimental Project (TPX).

  1. Novel Proton Conducting Solid Bio-polymer Electrolytes Based on Carboxymethyl Cellulose Doped with Oleic Acid and Plasticized with Glycerol

    NASA Astrophysics Data System (ADS)

    Chai, M. N.; Isa, M. I. N.

    2016-06-01

    The plasticized solid bio-polymer electrolytes (SBEs) system has been formed by introducing glycerol (Gly) as the plasticizer into the carboxymethyl cellulose (CMC) doped with oleic acid (OA) via solution casting techniques. The ionic conductivity of the plasticized SBEs has been studied using Electrical Impedance Spectroscopy. The highest conductivity achieved is 1.64 × 10‑4 S cm‑1 for system containing 40 wt. % of glycerol. FTIR deconvolution technique had shown that the conductivity of CMC-OA-Gly SBEs is primarily influenced by the number density of mobile ions. Transference number measurement has shown that the cation diffusion coefficient and ionic mobility is higher than anion which proved the plasticized polymer system is a proton conductor.

  2. Effects of the amino acid sequence on thermal conduction through β-sheet crystals of natural silk protein.

    PubMed

    Zhang, Lin; Bai, Zhitong; Ban, Heng; Liu, Ling

    2015-11-21

    Recent experiments have discovered very different thermal conductivities between the spider silk and the silkworm silk. Decoding the molecular mechanisms underpinning the distinct thermal properties may guide the rational design of synthetic silk materials and other biomaterials for multifunctionality and tunable properties. However, such an understanding is lacking, mainly due to the complex structure and phonon physics associated with the silk materials. Here, using non-equilibrium molecular dynamics, we demonstrate that the amino acid sequence plays a key role in the thermal conduction process through β-sheets, essential building blocks of natural silks and a variety of other biomaterials. Three representative β-sheet types, i.e. poly-A, poly-(GA), and poly-G, are shown to have distinct structural features and phonon dynamics leading to different thermal conductivities. A fundamental understanding of the sequence effects may stimulate the design and engineering of polymers and biopolymers for desired thermal properties. PMID:26455593

  3. Novel Proton Conducting Solid Bio-polymer Electrolytes Based on Carboxymethyl Cellulose Doped with Oleic Acid and Plasticized with Glycerol

    PubMed Central

    Chai, M. N.; Isa, M. I. N.

    2016-01-01

    The plasticized solid bio-polymer electrolytes (SBEs) system has been formed by introducing glycerol (Gly) as the plasticizer into the carboxymethyl cellulose (CMC) doped with oleic acid (OA) via solution casting techniques. The ionic conductivity of the plasticized SBEs has been studied using Electrical Impedance Spectroscopy. The highest conductivity achieved is 1.64 × 10−4 S cm−1 for system containing 40 wt. % of glycerol. FTIR deconvolution technique had shown that the conductivity of CMC-OA-Gly SBEs is primarily influenced by the number density of mobile ions. Transference number measurement has shown that the cation diffusion coefficient and ionic mobility is higher than anion which proved the plasticized polymer system is a proton conductor. PMID:27265642

  4. An evaluation of the effects of acid rain on low conductivity headwater streams in Pennsylvania

    USGS Publications Warehouse

    Ritter, John R.; Brown, Ann E.

    1981-01-01

    Analyses of water collected at 32 sites on headwater streams in Pennsylvania during low-flow conditions in 1970-80 were compared to pre-1971 data to evaluate whether acid rain had changed the chemistry of the streams in the previous decade. Most pH, alkalinity, and sulfate values of the samples collected in 1970-80 fell within the ranges of values for samples collected before 1971. The limited data indicate, however, that pH may have increased and alkalinity and sulfate may have decreased with time.

  5. A human dietary arachidonic acid supplementation study conducted in a metabolic research unit: rationale and design.

    PubMed

    Nelson, G J; Kelley, D S; Emken, E A; Phinney, S D; Kyle, D; Ferretti, A

    1997-04-01

    While there are many reports of studies that fed arachidonic acid (AA) to animals, there are very few reports of AA feeding to humans under controlled conditions. This 130-d study was conceived as a controlled, symmetrical crossover design with healthy, adult male volunteers. They lived in the metabolic research unit (MRU) of the Western Human Nutrition Research (WHNRC) for the entire study. All food was prepared by the WHNRC kitchen. The basal (low-AA) diet consisted of natural foods (30 en% fat, 15 en% protein, and 55 en% carbohydrate), containing 210 mg/d of AA, and met the recommended daily allowance for all nutrients. The high-AA (intervention) diet was similar except that 1.5 g/d of AA in the form of a triglyceride containing 50% AA replaced an equal amount of high-oleic safflower oil in the basal diet. The subjects (ages 20 to 39) were within -10 to +20% of ideal body weight, nonsmoking, and not allowed alcohol in the MRU. Their exercise level was constant, and their body weights were maintained within 2% of entry level. Subjects were initially fed the low-AA diet for 15 d. On day 16, half of the subjects (group A) wee placed on the high-AA diet, and the other group (B) remained on the low-AA diets. On day 65, the two groups switched diets. On day 115, group B returned to the low-AA diet. This design, assuming no carryover effect, allowed us to merge the data from the two groups, with the data comparison days being 65 (low-AA) and 115 (high-AA) for group B and 130 (low-AA) and 65 (high-AA) for group A. The main indices studied were the fatty acid composition of the plasma, red blood cells, platelets, and adipose tissue; in vitro platelet aggregation, bleeding times, clotting factors; immune response as measured by delayed hypersensitivity skin tests, cellular proliferation of peripheral blood mononuclear cells in response to various mitogens and antigens, natural killer cell activity, and response to measles/mumps/rubella and influenza vaccines; the

  6. Folic-Acid-Modified Conducting Polymer: Electrochemical Detection of the Cell Attachment.

    PubMed

    Azak, Hacer; Barlas, Firat Baris; Yildiz, Huseyin Bekir; Gulec, Kadri; Demir, Bilal; Demirkol, Dilek Odaci; Timur, Suna

    2016-04-01

    Here, postfunctionalization and bioapplication of a π-conjugated polymer named 4-[4H-dithieno(3,2-b:2',3'-d)pyrrol-4-yl]aniline (DTP-aryl-NH2 ) are reported, which is successfully synthesized via electropolymerization onto the glassy carbon electrode. Folic acid (FA) is used to modify the amino functional polymer via N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride/N-hydroxysuccinimide chemistry for the further steps. The selective adhesion of folate receptor positive cells on the surface is followed by the electrochemical methods. Cyclic voltammetry and electrochemical impedance spectroscopy have been used to characterize stepwise modification of the electroactive surface. After optimization studies such as scan rate during the polymer deposition, FA amount for the efficient surface targeting, incubation time with the cells etc., analytical characterization is carried out. The surface morphologies at each step are imaged by using fluorescence microscopy. PMID:26671168

  7. Researches on current distribution and plate conductivity of valve-regulated lead-acid batteries

    NASA Astrophysics Data System (ADS)

    Huang, Tao; Ou, Wenjun; Feng, Bo; Huang, Binbin; Liu, Minyi; Zhao, Wenchao; Guo, Yonglang

    2012-07-01

    A cell with tall plates was simulated by two cells and the controlled voltage with time was successfully used to measure the response current-time curves. It indicates that the current in the upper part of the plate is much higher than that in the lower part in early stage of the discharge, but in late stage, it is reversed, especially at high discharge rates. The upper part of the plate has higher capacity and deeper depth of discharge (DOD) so that the active mass degrades and sheds more quickly in cyclic applications. In the initial discharge, the lead sulfate formed at positive plates produces the internal stress and enhances the electric connection among the active mass particles. But the positive active mass only contributes a little to the conductivity of plates. The negative active mass with a bit shrinking but no passivation has better conductivity than the expanded active mass. The higher ohmic polarization of the active mass appears at higher discharge rates, in the upper part of the plates, in the late stage of the discharge, in aged battery, especially for negative plates.

  8. Proton conductive inorganic-organic hybrid membranes functionalized with phosphonic acid for polymer electrolyte fuel cell

    NASA Astrophysics Data System (ADS)

    Umeda, Junji; Suzuki, Masashi; Kato, Masaki; Moriya, Makoto; Sakamoto, Wataru; Yogo, Toshinobu

    Proton conductive sol-gel derived hybrid membranes were synthesized from aromatic derivatives of methoxysilanes and ethyl 2-[3-(dihydroxyphosphoryl)-2-oxapropyl]acrylate (EPA). Two aromatic derivatives of methoxysilanes with different number of methoxy groups were used as the starting materials. Hybrid membranes from difunctional (methyldimethoxysilylmethyl)styrene (MDMSMS(D))/EPA revealed a higher chemical stability and mechanical properties than those from monofunctional (dimethylmethoxysilylmethyl)styrene (DMMSMS(M))/EPA. The membrane-electrode assembly (MEA) using the hybrid membranes as electrolytes worked as a fuel cell at 100 °C under saturated humidity. The DMMSMS(M)/EPA membrane-based MEA showed a larger current density than that from MDMSMS(D)/EPA. On the other hand, the MDMSMS(D)/EPA membrane-based MEA exhibited higher open circuit voltages than the DMMSMS(M)/EPA-based MEA, and was stable during fuel cell operation at 80 °C at least for 48 h.

  9. Proton-conducting polymer membrane comprised of a copolymer of 2-acrylamido-2-methylpropanesulfonic acid and 2-hydroxyethyl methacrylate

    NASA Astrophysics Data System (ADS)

    Walker, Charles W.

    In order to identify a proton-conducting polymer membrane suitable for replacing Nafion ® 117 in direct methanol fuel cells (DMFC), we prepared a cross-linked copolymer of hydrophilic 2-acrylamido-2-methylpropanesulfonic acid (AMPS) and 2-hydroxyethyl methacrylate (HEMA). Fumed silicas were also added in an attempt to increase the amount of water adsorbed by the membrane and to enhance water retention. Hydrated copolymer membranes adsorbed significantly more water than Nafion ® 117, but were no better at retaining water during drying under ambient conditions. Films composed of 4% AMPS—96% HEMA had a room temperature proton conductivity of 0.029 S cm -1, which increased to 0.06 S cm -1 at 80 °C.

  10. A report on the Round Robin Program conducted to evaluate the proposed ASTM standard test method for determining the plane strain crack arrest fracture toughness, K/sub Ia/, of ferritic materials

    SciTech Connect

    Barker, D.B.; Chona, R.; Fourney, W.L.; Irwin, G.R.

    1988-01-01

    This report summarizes the results from a Round Robin Program that was conducted during 1983-1985 to evaluate a proposed ASTM Test Method for Crack Arrest Fracture Toughness of Ferritic Materials. The Round Robin attracted a total of twenty-seven participants from the United States, Canada, Europe and Japan, each of whom agreed to test three specimens of A514 bridge steel, three specimens of A588 bridge steel, and six specimens of A533 Grade B Class 1 reactor pressure vessel steel. Twenty-one participants completed their testing and forwarded test results for inclusion and discussion in this report. Modifications to the proposed test method that are called for in the light of the experience gained from the Round Robin are also discussed. The test method has been revised and is currently in the process of being considered by ASTM Committee E-24 on Fracture Testing as a Proposed Standard Test Method. 20 refs., 44 figs., 6 tabs.

  11. Effect of pH on visualization of fatty acids as myelin figures in mouse adipose tissue by freeze-fracture electron microscopy.

    PubMed

    Amende, L M; Blanchette-Mackie, E J; Chernick, S S; Scow, R O

    1985-10-23

    We studied the effect of pH on visualization of fatty acids as myelin figures in young mouse epididymal adipose tissue. Fatty acid content of the tissue was increased to 12.4 nmol/mg wet weight by treating the tissue with 380 microM isoproterenol at pH 7.4 for 15 min in the absence of glucose and albumin. Myelin figures were found in freeze-fracture replicas of isoproterenol-treated tissue fixed with glutaraldehyde at pH 7.4 and then incubated and glycerinated at pH 8.1. Myelin figures were seen in replicas as concave or convex laminated sheets and long cylindrical multilamellar structures in fat cells and extracellular space. Myelin figures were sometimes seen in cells extending from the surface of intracellular lipid droplets, the site of lipolysis, to the cell surface and extracellular space. Myelin figures were not found in isoproterenol-treated tissue fixed at pH 7.4 and processed at pH 7.0. Smooth-surfaced droplets, instead, were found in these tissues in the extracellular space. Neither myelin figures nor smooth-surfaced droplets were found in tissues treated with insulin and glucose (to reduce fatty acid content to 1.4 nmol/mg), fixed at pH 7.4 and processed at either pH 8.1 or pH 7.0. Lowering pH of the media to 4.5 during processing of tissues treated with isoproterenol at pH 9.0 caused disappearance of myelin figures and appearance of smooth-surfaced droplets in the extracellular space. Myelin figures were found in replicas of tissue treated with isoproterenol for 15 min at pH 7.4, incubated 10 min at pH 8.4, quick-frozen and then freeze-fractured, indicating that formation of myelin figures was not dependent on glutaraldehyde fixation and glycerol infiltration of the tissue. Our findings show that excess fatty acids in adipose tissue can be visualized as myelin figures if the tissue is exposed to pH 8.1-9.0 and maintained at or above pH 7.4, or as smooth-surfaced droplets if the tissue is processed at pH 7.0 or 4.5. We conclude that myelin figures

  12. Fabrication and Protein Conjugation of Aligned Polypyrrole-Poly(L-lactic acid) Fibers Film with the Conductivity and Stability.

    PubMed

    Qin, Jiabang; Huang, Zhongbing; Yin, Guangfu; Yang, Anneng; Han, Wei

    2016-03-01

    The conducting composite scaffold, including fiber-cores of aligned poly(L-lactic acid) (PLLA) and shell-layer of polypyrrole (PPy), was fabricated, and then bovine serum albumin (BSA) was conjugated on the PPy shell-layer. Aligned PLLA fibers (about 300 nm diameter) were obtained by electrospinning and rotating drum collection, and then coated by PPy nanoparticles (NPs, about 50 nm diameter) via chemical oxidation. The surface resistivity of PPy-PLLA fibers film were 0.971, 0.874 kΩ. cm at the fiber's vertical and parallel directions, respectively. The results of PPy-PLLA fibers film immersed in phosphate buffer saline for 8 d indicated that the fibers morphology and the film conductivity were not significantly changed, and the fluorescent images showed that FITC-labeled BSA (FITC-BSA) were successfully conjugated in the fibers film with carbodiimide chemistry, and the largest amount of FITC-BSA conjugated in the fibers film from 100 μg/mL proteins solution was 31.31 μg/cm2 due to lots of poly(glutamic acid) in surface-nanogrooves of the fibers surface. Under electrical stimulation of 100 mV, the fibers film was accompanied the release of all conjugated FITC-BSA with the detachment of some PPy NPs. These results suggested that PPy-PLLA fibers film would be potentially applied in the construction of degradable tissue engineering scaffold with protein factors, especially neurotrophic factors for nerve tissue repair. PMID:27455643

  13. Ozone and simulated acid rain effects on growth root hydraulic conductivity, and photosynthesis of red spruce

    SciTech Connect

    Lee, W.S.; Chevone, B.I.; Seiler, J.R.

    1987-04-01

    Three-year-old red spruce seedlings were exposed to ozone (O/sub 3/) at 0.00 (control) or 0.10 ppm, 4 hr/d, 3 d/wk in combination with simulated rain (pH 3.0 or 5.6, 1 hr/d, 2 d/wk at 0.75 cm/hr) for 10 wks. All seedlings were submitted to two drought cycles after the 10-wk-treatment. O/sub 3/ significantly decreased root hydraulic conductivity (Lp) by 21% after 10 wks across all rain pHs. The reduction of Lp in seedlings treated with O/sub 3/ was enhanced by drought stress. Rain pH alone did not affect Lp during the 10-wks-exposure and drought cycles. However, the O/sub 3/ effect on Lp was more severe at pH 5.6 than at pH 3.0. Rain at pH 3.0 stimulated shoot height growth by 31% compared with pH 5.6 across all O/sub 3/ treatments. However, root, shoot, and total dry weight of seedlings were not changed by any treatments. Neither O/sub 3/ nor rain pH affected net photosynthetic (P/sub i/) response to branch water potential in plants subjected to one or two drought cycles. However, P/sub i/ was less sensitive to water potential after two drought cycles, indicating physiological adjustment to drought stress.

  14. A model for mammalian cochlear hair cell differentiation in vitro: effects of retinoic acid on cytoskeletal proteins and potassium conductances.

    PubMed

    Helyer, R; Cacciabue-Rivolta, D; Davies, D; Rivolta, M N; Kros, C J; Holley, M C

    2007-02-01

    We have established a model for the in-vitro differentiation of mouse cochlear hair cells and have used it to explore the influence of retinoic acid on proliferation, cytoskeletal proteins and voltage-gated potassium conductances. The model is based on the conditionally immortal cell line University of Sheffield/ventral otocyst-epithelial cell line clone 36 (US/VOT-E36), derived from ventral otic epithelial cells of the mouse at embryonic day 10.5 and transfected with a reporter for myosin VIIa. Retinoic acid did not increase cell proliferation but led to up-regulation of myosin VIIa and formation of prominent actin rings that gave rise to numerous large, linear actin bundles. Cells expressing myosin VIIa had larger potassium conductances and did not express the cyclin-dependent kinase inhibitor p27(kip1). US/VOT-E36 endogenously expressed the voltage-gated potassium channel alpha-subunits Kv1.3 and Kv2.1, which we subsequently identified in embryonic and neonatal hair cells in both auditory and vestibular sensory epithelia in vivo. These subunits could underlie the embryonic and neonatal delayed-rectifiers recorded in nascent hair cells in vivo. Kv2.1 was particularly prominent on the basolateral membrane of cochlear inner hair cells. Kv1.3 was distributed throughout all hair cells but tended to be localized to the cuticular plates. US/VOT-E36 recapitulates a coherent pattern of cell differentiation under the influence of retinoic acid and will provide a convenient model for screening the effects of other extrinsic factors on the differentiation of cochlear epithelial cell types in vitro. PMID:17331193

  15. Effect of a bioabsorbable, super-high molecular weight poly-D,L-lactic acid plate containing recombinant human bone morphogenetic protein-2 for fracture healing

    PubMed Central

    ZHOU, NING-FENG; HUANG, YU-FENG; WANG, JIN-WU

    2015-01-01

    The aim of this study was to investigate the effect of a bioabsorbable, super-high molecular weight poly-D,L-lactic acid (PDLLA) plate exhibiting the sustained release of recombinant human bone morphogenetic protein-2 (rhBMP-2) (PDLLA-rhBMP-2) on the treatment of fracture with internal fixation. A total of 32 New Zealand rabbits were randomly allocated to one of four groups (2, 4, 8 and 12 weeks), and a 2.5-mm middle ulnar osteotomy was performed bilaterally. The right side (experimental side) was fixed internally with PDLLA-rhBMP-2, and the left side (control side) was fixed with a normal PDLLA plate. At 2, 4, 8 and 12 weeks after surgery, the gross pathology of the ulnas was examined and radiographic, histological and computer image analyses were performed. The results demonstrated that the ulna fractures were fixed stably with the two bioactive plates at 2, 4, 8 and 12 weeks after surgery. At the 8-week time-point, 7 rabbits exhibited good healing at the osteotomy site on the experimental side. At 12 weeks after surgery, 8 rabbits exhibited good healing at the osteotomy site on both sides, but the experimental side showed enhanced compatibility between the plates and surrounding tissue, faster bone formation, a greater bone regeneration mass and better medullary canal structure compared with the control side. In conclusion, PPLLA-rhBMP-2 may be effectively used to treat fracture or nonunion at a non-weight-bearing site. PMID:26640559

  16. Fractured Surface

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site] Context image for PIA03084 Fractured Surface

    These fractures and graben are part of Gordii Fossae, a large region that has undergone stresses which have cracked the surface.

    Image information: VIS instrument. Latitude 16.6S, Longitude 234.3E. 18 meter/pixel resolution.

    Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.

    NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  17. Cytocompatibility of a conductive nanofibrous carbon nanotube/poly (L-Lactic acid) composite scaffold intended for nerve tissue engineering

    PubMed Central

    Kabiri, Mahboubeh; Oraee-Yazdani, Saeed; Dodel, Masumeh; Hanaee-Ahvaz, Hana; Soudi, Sara; Seyedjafari, Ehsan; Salehi, Mohammad; Soleimani, Masoud

    2015-01-01

    The purpose of this study was to fabricate a conductive aligned nanofibrous substrate and evaluate its suitability and cytocompatibility with neural cells for nerve tissue engineering purposes. In order to reach these goals, we first used electrospinning to fabricate single-walled carbon-nanotube (SWCNT) incorporated poly(L-lactic acid) (PLLA) nanofibrous scaffolds and then assessed its cytocompatibility with olfactory ensheathing glial cells (OEC). The plasma treated scaffolds were characterized using scanning electron microscopy and water contact angle. OECs were isolated from olfactory bulb of GFP Sprague-Dawley rats and characterized using OEC specific markers via immunocytochemistry and flow cytometery. The cytocompatibility of the conductive aligned nano-featured scaffold was assessed using microscopy and MTT assay. We indicate that doping of PLLA polymer with SWCNT can augment the aligned nanosized substrate with conductivity, making it favorable for nerve tissue engineering. Our results demonstrated that SWCNT/PLLA composite scaffold promote the adhesion, growth, survival and proliferation of OEC. Regarding the ideal physical, topographical and electrical properties of the scaffold and the neurotrophic and migratory features of the OECs, we suggest this scaffold and the cell/scaffold construct as a promising platform for cell delivery to neural defects in nerve tissue engineering approaches. PMID:26600751

  18. Polypyrrole-coated electrospun poly(lactic acid) fibrous scaffold: effects of coating on electrical conductivity and neural cell growth.

    PubMed

    Sudwilai, Thitima; Ng, Jun Jye; Boonkrai, Chatikorn; Israsena, Nipan; Chuangchote, Surawut; Supaphol, Pitt

    2014-01-01

    Neuronal activities play critical roles in both neurogenesis and neural regeneration. In that sense, electrically conductive and biocompatible biomaterial scaffolds can be applied in various applications of neural tissue engineering. In this study, we fabricated a novel biomaterial for neural tissue engineering applications by coating electrospun poly(lactic acid) (PLA) nanofibers with a conducting polymer, polypyrole (PPy), via admicellar polymerization. Optimal conditions for polymerization and preparation of PPy-coated electrospun PLA nanofibers were obtained by comparing results from scanning electron microscopy, X-ray photoelectron spectrometer, and surface conductivity tests. In vitro cell culture experiments showed that PPy-coated electrospun PLA fibrous scaffold is not toxic. The scaffold could support attachment and migration of neural progenitor cells. Neurons derived from progenitor exhibited long neurite outgrowth under electrical stimulation. Our study concluded that PPy-coated electrospun PLA fibers had a good biocompatibility with neural progenitor cells and may serve as a promising material for controlling progenitor cell behaviors and enhancing neural repair. PMID:24933469

  19. Fabrication and characterization of poly(lactic acid)/acetyl tributyl citrate/carbon black as conductive polymer composites.

    PubMed

    Yu, Jiugao; Wang, Ning; Ma, Xiaofei

    2008-03-01

    By using acetyl tributyl citrate (ATBC) as the plasticizer of poly(lactic acid) (PLA) and carbon black (CB) as conductive filler, electrically conductive polymer composites (CPC) with different CB and ATBC contents were prepared. FTIR revealed that the interaction existed between PLA/ATBC matrix and CB filler and ATBC could improve this interaction. The rheology showed that ATBC could obviously decrease the shear viscosity and improve the fluidity of the composites but just the reverse for CB. With the increasing of CB contents, the enforcement effect, storage modulus, and glass-transition temperature increased but the elongation at break decreased. PLA/ATBC/CB composites exhibited the low electrical percolation thresholds of 0.516, 1.20, 2.46, and 2.74 vol % CB at 30, 20, 10, and 0 wt % ATBC. The conductivity of the composite containing 3.98 vol % CB and 30 wt % ATBC reached 1.60 S/cm. Scanning electron microscopy revealed that the addition of ATBC facilitated the dispersion of the CB in the PLA matrix. Water vapor permeability (WVP) showed that, at the same CB contents, the more ATBC contents there were, the less the values of WVP were. PMID:18290627

  20. Elbow Fractures

    MedlinePlus

    ... and held together with pins and wires or plates and screws. Fractures of the distal humerus (see ... doctor. These fractures usually require surgical repair with plates and/or screw, unless they are stable. SIGNS ...

  1. Is vaccenic acid (18:1t n-7) associated with an increased incidence of hip fracture? An explanation for the calcium paradox.

    PubMed

    Hamazaki, Kei; Suzuki, Nobuo; Kitamura, Kei-Ichiro; Hattori, Atsuhiko; Nagasawa, Tetsuro; Itomura, Miho; Hamazaki, Tomohito

    2016-06-01

    High calcium intake may increase hip fracture (HF) incidence. This phenomenon, known as the calcium paradox, might be explained by vaccenic acid (18:1t n-7, VA), the highly specific trans fatty acid (TFA) present in dairy products. First, we ecologically investigated the relationship between 18:1 TFA intake and HF incidence using data from 12 to 13 European countries collected before 2000; then we measured the effects of VA and elaidic acid (18:1t n-9, EA) on osteoblasts from goldfish scales (tissues very similar to mammalian bone), with alkaline phosphatase as a marker; and finally we measured the effect of VA on mRNA expression in the scales for the major bone proteins type I collagen and osteocalcin. HF incidence was significantly correlated with 18:1 TFA intake in men (r=0.57) and women (r=0.65). Incubation with 1μmol/L VA and EA for 48h significantly decreased alkaline phosphatase activity by 25% and 21%, respectively. Incubation of scales with 10μmol/L VA for 48h significantly decreased mRNA expression for type I collagen and osteocalcin (by about 50%). In conclusion, VA may be causatively related to HF and could explain the calcium paradox. It may be prudent to reduce 18:1 TFA intake, irrespective of trans positions, to prevent HF. PMID:27269708

  2. Olecranon Fractures.

    PubMed

    Brolin, Tyler J; Throckmorton, Thomas

    2015-11-01

    Olecranon fractures are common upper extremity injuries, with all but nondisplaced fractures treated surgically. There has been a recent shift in the surgical management of these fractures from tension band wiring to locking plate fixation and intramedullary nailing; however, this comes with increased implant cost. Although most patients can expect good outcomes after these various techniques, there is little information to guide a surgeon's treatment plan. This article reviews the epidemiology, classification, treatment, and outcomes of olecranon fractures. PMID:26498547

  3. Measurement of Solute Diffusion Behavior in Fractured Waste Glass Media

    SciTech Connect

    Saripalli, Kanaka P.; Lindberg, Michael J.; Meyer, Philip D.

    2008-10-01

    Determination of aqueous phase diffusion coefficients of solutes through fractured media is essential for understanding and modeling contaminants transport at many hazardous waste disposal sites. No methods for earlier measurements are available for the characterization of diffusion in fractured glass blocks. We report here the use of time-lag diffusion experimental method to assess the diffusion behavior of three different solutes (Cs, Sr and Pentafluoro Benzoic Acid or PFBA) in fractured, immobilized low activity waste (ILAW) glass forms. A fractured media time-lag diffusion experimental apparatus that allows the measurement of diffusion coefficients has been designed and built for this purpose. Use of time-lag diffusion method, a considerably easier experimental method than the other available methods, was not previously demonstrated for measuring diffusion in any fractured media. Hydraulic conductivity, porosity and diffusion coefficients of a solute were experimentally measured in fractured glass blocks using this method for the first time. Results agree with the range of properties reported for similar rock media earlier, indicating that the time-lag experimental method can effectively characterize the diffusion coefficients of fractured ILAW glass media.

  4. Fabrication of conductive NGF-conjugated polypyrrole-poly(l-lactic acid) fibers and their effect on neurite outgrowth.

    PubMed

    Zeng, Jingwen; Huang, Zhongbing; Yin, Guangfu; Qin, Jiabang; Chen, Xianchun; Gu, Jianwen

    2013-10-01

    In order to fabricate a tissue scaffold with the neurotrophic and electrical activities, conductive nerve growth factor (NGF)-conjugated polypyrrole-poly(l-lactic acid) (PPy-PLLA) composite fibers were prepared by oxidation polymerization and EDC chemistry with poly-l-lysine. PPy nanoparticles (∼70nm diameter) accumulated on PLLA fiber surface to form a rough thick shell (∼200nm thickness). These NGF-conjugated PPy-PLLA fibers could support PC12 neurite outgrowth and extension. Especially, 40% and 74% increase in PC12 neurite outgrowth and extension, respectively, could be obtained under electrical stimulation of 100mV/cm voltages through the composite fibers. A mechanism for the interaction between neurite extension and the NGF-conjugated PPy-PLLA fibers under electro-stimulation was proposed, to explain the synergistic effect of the rough PPy shell, conjugated NGF and electricity on neurite outgrowth and elongation. PMID:23759386

  5. Seeking enhanced lead/acid battery performance through the use of conductive tin-dioxide-coated glass-flakes

    NASA Astrophysics Data System (ADS)

    Lam, L. T.; Lim, O.; Ozgun, H.; Rand, D. A. J.

    1994-02-01

    The aim of this research is to raise the level of active-material utilization in the positive plates of lead/acid batteries (without diminishing other performance characteristics) and, thereby, to increase the energy output per unit weight. The strategy is to increase the electrical conductivity of the material by adding a proprietary particulate that consists of glass-flakes coated with a thin (less than 5 microns) layer of tin dioxide. The particulates are incorporated in positive plates that are prepared as automotive designs under a wide range of processing conditions, i.e., paste densities, acid-to-oxide ratios, low-/high-temperature (3BS/4BS) curing. Plate performance is evaluated in terms of active-material utilization, cold-cranking capability, repetitive reserve capacity, and life endurance under the Japanese Industrial Standard (JIS) procedure. Compared with untreated cells, the following benefits of adding the particulates to positive plates have been confirmed: (1) acceleration of the formation process; (2) increase in the BET surface area of formed materials; (3) improvement in active-material utilization at the 5-h and 20-h discharge rates; (4) maintenance of cycleability under repetitive, reserve-capacity duty; (5) increase in cycle life under the JIS schedule. The encouraging outcomes of this research suggest that further benefits are likely to be gained by designing elongated particulates of lighter weight. This will increase the number of counts per unit area and, thereby, will improve the contact between the individual particles of the positive active material and will further enhance the electrical conductivity of the plate.

  6. An in situ generated carbon as integrated conductive additive for hierarchical negative plate of lead-acid battery

    NASA Astrophysics Data System (ADS)

    Saravanan, M.; Ganesan, M.; Ambalavanan, S.

    2014-04-01

    In this work, we report an in situ generated carbon from sugar as additive in the Negative Active Mass (NAM) which enhances the charge-discharge characteristics of the lead-acid cells. In situ formed sugar derived carbon (SDC) with leady oxide (LO) provides a conductive network and excellent protection against NAM irreversible lead sulfation. The effect of SDC and carbon black (CB) added negative plates are characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), galvanostatic charge-discharge, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), respectively. The results show that subtle changes in the addition of carbon to NAM led to subsequent changes on the performance during partial-state-of-charge (PSoC) operations in lead-acid cells. Furthermore, SDC added cells exhibit remarkable improvement in the rate capability, active material utilization, cycle performance and charge acceptance compared to that of the conventional CB added cells. The impact of SDC with LO at various synthesis conditions on the electrochemical performance of the negative plate is studied systematically.

  7. Determination of five priority haloacetic acids by capillary electrophoresis with contactless conductivity detection and solid phase extraction preconcentration.

    PubMed

    Kubáň, Petr; Makarõtševa, Natalja; Kiplagat, Isaac K; Kaljurand, Mihkel

    2012-03-01

    A sensitive capillary electrophoretic separation method with contactless conductivity detection (C4D) for analysis of five priority haloacetic acids (HAA5) is presented. The analytes were baseline separated in an electrolyte composed of 20 mM 2-(N-Morpholino) ethanesulfonic acid (MES), 20 mM L-histidine (HIS), and 30 μM cetyltrimethylammonium bromide (CTAB) at pH 6.0 in less than 4 min. A simplified solid-phase extraction (SPE) preconcentration procedure on highly cross-linked polystyrene-divinylbenzene (PS-DVB) type sorbent was developed and optimized with respect to short preconcentration time. HAA5 from a 25-mL sample aliquot of tap and swimming pool water could be preconcentrated in less than 5 min using an in-house made SPE column with recoveries ranging from 23 to 98%. Combining the SPE preconcentration procedure with capillary electrophoretic analysis, the attained limits of detection were between 6.1 and 12.2 μg/L with total analysis time of less than 10 min. PMID:22517640

  8. COPII-dependent export of cystic fibrosis transmembrane conductance regulator from the ER uses a di-acidic exit code

    PubMed Central

    Wang, Xiaodong; Matteson, Jeanne; An, Yu; Moyer, Bryan; Yoo, Jin-San; Bannykh, Sergei; Wilson, Ian A.; Riordan, John R.; Balch, William E.

    2004-01-01

    Cystic fibrosis (CF) is a childhood hereditary disease in which the most common mutant form of the CF transmembrane conductance regulator (CFTR) ΔF508 fails to exit the endoplasmic reticulum (ER). Export of wild-type CFTR from the ER requires the coat complex II (COPII) machinery, as it is sensitive to Sar1 mutants that disrupt normal coat assembly and disassembly. In contrast, COPII is not used to deliver CFTR to ER-associated degradation. We find that exit of wild-type CFTR from the ER is blocked by mutation of a consensus di-acidic ER exit motif present in the first nucleotide binding domain. Mutation of the code disrupts interaction with the COPII coat selection complex Sec23/Sec24. We propose that the di-acidic exit code plays a key role in linking CFTR to the COPII coat machinery and is the primary defect responsible for CF in ΔF508-expressing patients. PMID:15479737

  9. COPII-dependent export of cystic fibrosis transmembrane conductance regulator from the ER uses a di-acidic exit code.

    PubMed

    Wang, Xiaodong; Matteson, Jeanne; An, Yu; Moyer, Bryan; Yoo, Jin-San; Bannykh, Sergei; Wilson, Ian A; Riordan, John R; Balch, William E

    2004-10-11

    Cystic fibrosis (CF) is a childhood hereditary disease in which the most common mutant form of the CF transmembrane conductance regulator (CFTR) DeltaF508 fails to exit the endoplasmic reticulum (ER). Export of wild-type CFTR from the ER requires the coat complex II (COPII) machinery, as it is sensitive to Sar1 mutants that disrupt normal coat assembly and disassembly. In contrast, COPII is not used to deliver CFTR to ER-associated degradation. We find that exit of wild-type CFTR from the ER is blocked by mutation of a consensus di-acidic ER exit motif present in the first nucleotide binding domain. Mutation of the code disrupts interaction with the COPII coat selection complex Sec23/Sec24. We propose that the di-acidic exit code plays a key role in linking CFTR to the COPII coat machinery and is the primary defect responsible for CF in DeltaF508-expressing patients. PMID:15479737

  10. Enhancement of root hydraulic conductivity by methyl jasmonate and the role of calcium and abscisic acid in this process.

    PubMed

    Sánchez-Romera, Beatriz; Ruiz-Lozano, Juan Manuel; Li, Guowei; Luu, Doan-Trung; Martínez-Ballesta, Maria del Carmen; Carvajal, Micaela; Zamarreño, Angel María; García-Mina, Jose María; Maurel, Christophe; Aroca, Ricardo

    2014-04-01

    The role of jasmonic acid in the induction of stomatal closure is well known. However, its role in regulating root hydraulic conductivity (L) has not yet been explored. The objectives of the present research were to evaluate how JA regulates L and how calcium and abscisic acid (ABA) could be involved in such regulation. We found that exogenous methyl jasmonate (MeJA) increased L of Phaseolus vulgaris, Solanum lycopersicum and Arabidopsis thaliana roots. Tomato plants defective in JA biosynthesis had lower values of L than wild-type plants, and that L was restored by addition of MeJA. The increase of L by MeJA was accompanied by an increase of the phosphorylation state of the aquaporin PIP2. We observed that MeJA addition increased the concentration of cytosolic calcium and that calcium channel blockers inhibited the rise of L caused by MeJA. Treatment with fluoridone, an inhibitor of ABA biosynthesis, partially inhibited the increase of L caused by MeJA, and tomato plants defective in ABA biosynthesis increased their L after application of MeJA. It is concluded that JA enhances L and that this enhancement is linked to calcium and ABA dependent and independent signalling pathways. PMID:24131347

  11. Rapid and direct determination of glyphosate, glufosinate, and aminophosphonic acid by online preconcentration CE with contactless conductivity detection.

    PubMed

    See, Hong Heng; Hauser, Peter C; Ibrahim, Wan Aini Wan; Sanagi, Mohd Marsin

    2010-01-01

    Rapid and direct online preconcentration followed by CE with capacitively coupled contactless conductivity detection (CE-C(4)D) is evaluated as a new approach for the determination of glyphosate, glufosinate (GLUF), and aminophosphonic acid (AMPA) in drinking water. Two online preconcentration techniques, namely large volume sample stacking without polarity switching and field-enhanced sample injection, coupled with CE-C(4)D were successfully developed and optimized. Under optimized conditions, LODs in the range of 0.01-0.1 microM (1.7-11.1 microg/L) and sensitivity enhancements of 48- to 53-fold were achieved with the large volume sample stacking-CE-C(4)D method. By performing the field-enhanced sample injection-CE-C(4)D procedure, excellent LODs down to 0.0005-0.02 microM (0.1-2.2 microg/L) as well as sensitivity enhancements of up to 245- to 1002-fold were obtained. Both techniques showed satisfactory reproducibility with RSDs of peak height of better than 10%. The newly established approaches were successfully applied to the analysis of glyphosate, glufosinate, and aminophosphonic acid in spiked tap drinking water. PMID:20119968

  12. Permeability of naturally fractured reservoirs

    SciTech Connect

    Teufel, L.W. )

    1991-03-01

    Hydraulic fracture stress data collected from carbonate and clastic reservoirs show that the minimum horizontal in situ stress decreases with reservoir depletion and pore pressure drawdown. The reduction in minimum horizontal stress is, in part, a poro-elastic effect that is linear with pore pressure drawdown and can be approximated by an unlaxial compaction model. The observed change in horizontal stress is equal to 40% to 80% of the net change in pore pressure. This type of stress behavior has important implications for reservoir management of naturally fractured reservoirs, because conductivity of fractures is highly stress sensitive. Laboratory studies clearly demonstrate that with increasing effective normal stress fracture apertures close and conductivity decreases. Accordingly, in sharp contrast to the standard procedure, predictions of changes in fracture permeability during reservoir depletion should not be made simply as a function of pore pressure drawdown, but more importantly should be based on how the effective in situ stresses change during drawdown and the orientation of natural fractures relative to the in situ stress field. The increase in the effective overburden stress will be the largest and equal to the magnitude of the pore pressure decline because the overburden stress is constant and does not change with drawdown. However, the increase in the effective minimum horizontal stress will be much smaller. Accordingly, for a reservoir with several sets of fractures with similar morphology, the reduction in fracture conductivity during drawdown will be greatest for horizontal fractures and least for vertical fractures aligned with the maximum horizontal stress direction.

  13. The Effect of 3-Thiopheneacetic Acid in the Polymerization of a Conductive Electrotextile for Use in Biosensor Development

    PubMed Central

    McGraw, Shannon K.; Alocilja, Evangelyn; Senecal, Andre; Senecal, Kris

    2013-01-01

    Investigations were conducted to develop an electrotextile using a nonwoven polypropylene fiber platform conformally coated in a conductive, functionalized copolymer of polypyrrole and 3-thiopheneacetic acid (3TAA). The objectives of this study were to determine: (1) if the inclusion of 3TAA in the polymerization process would have an effect on the availability of binding sites in the high-surface area electrotextile for biorecognition elements and (2) how the increase in the concentration of 3TAA would affect the physical characteristics of the coating, resistivity of the sample and availability of binding sites. It was found that the addition of 3TAA to the polymerization process resulted in an increase in the size of the polypyrrole coating, as well as the material resistivity and available binding sites for biorecognition elements. These factors were used to determine which of the tested concentrations was best for biosensor development. A polymer coated membrane sample containing a concentration within the range of 10–50 mg/mL of 3TAA was selected as the best for future biosensor work. PMID:25586259

  14. Sports fractures.

    PubMed Central

    DeCoster, T. A.; Stevens, M. A.; Albright, J. P.

    1994-01-01

    Fractures occur in athletes and dramatically influence performance during competitive and recreational activities. Fractures occur in athletes as the result of repetitive stress, acute sports-related trauma and trauma outside of athletics. The literature provides general guidelines for treatment as well as a variety of statistics on the epidemiology of fractures by sport and level of participation. Athletes are healthy and motivated patients, and have high expectations regarding their level of function. These qualities make them good surgical candidates. Although closed treatment methods are appropriate for most sports fractures, an aggressive approach to more complicated fractures employing current techniques may optimize their subsequent performance. PMID:7719781

  15. Comparison of short-term effects of insulin and essential fatty acids on the slowed nerve conduction of streptozotocin diabetes in rats.

    PubMed

    Julu, P O; Mutamba, A

    1991-11-01

    Early effects of insulin and essential fatty acids on nerve conduction were studied. Insulin-dependent diabetes was induced in rats using streptozocin (65 mg/kg, i.p.); control rats were treated with buffer. Five weeks later, diabetic rats were divided into 5 groups. Two groups were given oral essential fatty acids (75% linoleic and 9% gamma-linolenic acids) for a further 3 and 5 days, respectively. Two other groups received subcutaneous insulin for a further 3 or 5 days. A group of diabetic rats were left without further treatment. Motor nerve conduction velocity was measured terminally in all rats by stimulating the sciatic nerve and recording EMGs in the gastrocnemius muscle under urethane anaesthesia. Sensory nerve conduction velocity was measured by stimulating and recording from the saphenous nerve trunk. Diabetic rats had significantly slowed motor and sensory nerve conduction velocities after 5 weeks (16.7%, P less than 0.001). Three days treatment with either insulin or fatty acids corrected the slowed motor nerve conduction velocity to a normal level. Conduction velocity in myelinated sensory nerves was still 10% slower in diabetic rats treated with insulin for 3 days (P less than 0.01). It was above the control level by 11% in diabetic rats treated with fatty acids for the same period (P less than 0.01). Conduction velocities in both sensory and motor nerves were normal in diabetic rats treated with either insulin or fatty acids for 5 days. It was concluded that both insulin and essential fatty acids had early effects on nerve conduction in diabetic rats. The speed of their actions, and the magnitudes of responses were different in sensory and motor nerves. PMID:1663993

  16. Efficient high-permeability fracturing offshore

    SciTech Connect

    Phillipi, M.; Farabee, M.

    1996-12-31

    Offshore operators can more efficiently and effectively perform high-permeability and conventional hydraulic fracture treatments by blending treatment slurries under microprocessor control, adding undiluted acid on-the-fly, and altering sand concentrations and other slurry properties instantaneously. A two-skid system has been designed with these considerations in mind. The system, which can be shipped efficiently in ISO containers, has been tested on fluids up to 210-cp viscosity and can step or ramp sand concentrations up to a maximum of 20 lb/gal. All additives, including acid treatments, are added on-the-fly; leftover additives and acids may be stored for future jobs. The system may be applied in most conditions, including offshore wells requiring conventional or high-permeability fracture treatments and certain land-based wells in remote areas where a compact skid is needed. Three significant benefits have resulted from using the compact-skid system: offshore operators have been able to ship the skid system at 20% of shipping costs of non-ISO equipment; on-the-fly mixing has prevented material waste associated with batch-mixing; and volumes pumped on actual jobs have closely matched job designs. Data have been collected from several Gulf of Mexico jobs run with the two-part skid system that has been designed for conducting hydraulic fracture treatments from offshore rigs.

  17. Numerical Modeling of Fracture Propagation in Naturally Fractured Formations

    NASA Astrophysics Data System (ADS)

    Wang, W.; Prodanovic, M.; Olson, J. E.; Schultz, R.

    2015-12-01

    Hydraulic fracturing consists of injecting fluid at high pressure and high flowrate to the wellbore for the purpose of enhancing production by generating a complex fracture network. Both tensile failure and shear failure occur during the hydraulic fracturing treatment. The shear event can be caused by slip on existing weak planes such as faults or natural fractures. From core observation, partially cemented and fully cemented opening mode natural fractures, often with considerable thickness are widely present. Hydraulic fractures can propagate either within the natural fracture (tensile failure) or along the interface between the natural fracture and the rock matrix (tensile/shear failure), depending on the relative strength of cement and rock matrix materials, the bonding strength of interface, as well as the presence of any heterogeneities. In this study, we evaluate the fracture propagation both experimentally and numerically. We embed one or multiple inclusions of different mechanical properties within synthetic hydrostone samples in order to mimic cemented natural fractures and rock. A semi-circular bending test is performed for each set of properties. A finite element model built with ABAQUS is used to mimic the semi-circular bending test and study the fracture propagation path, as well as the matrix-inclusion bonding interface status. Mechanical properties required for the numerical model are measured experimentally. The results indicate that the match between experiment and modeling fracture path are extremely sensitive to the chosen interface (bonding) model and related parameters. The semi-circular bending test is dry and easily conducted, providing a good platform for validating numerical approaches. A validated numerical model will enable us to add pressurized fluid within the crack and simulate hydraulic fracture-natural fracture interaction in the reservoir conditions, ultimately providing insights into the extent of the fracture network.

  18. Spontaneous fractures of the mandible concept & treatment strategy

    PubMed Central

    Marcussen, Mette

    2016-01-01

    Background Spontaneous fractures of the mandible dispose a surgical challenge in comparisons to fractures caused by trauma due to several complicating factors. Additionally: controversies exist concerning the terminology of the field. Material and Methods We conducted a retrospective study of all patients with mandibular fractures, with exclusion of fractures of the coronoid process and the alveolar process, treated at the Department of Oral and Maxillofacial Surgery, Aalborg University Hospital, Denmark between February 2003 and February 2013. Data collected from the medical records included sex, age, cause of fracture, site of fracture, and treatment. Results We identified 517 patients with 684 mandible fractures. Twenty-five of these were spontaneous fractures and 659 fractures were of traumatic origin. Condylar fractures rarely occur spontaneously, but constitute the majority of the traumatic fractures. Excluding these fractures from the analysis, we found a non-surgical approach in 14 of 24 (58%) of the spontaneous fractures and 110 of 376 (29%) of the traumatic fractures. This was statistically significant. Conclusions We found a statistical significant difference in favor of non-surgical approach in spontaneous fractures and we discussed the treatment challenges of these fractures. We addressed the terminological controversies regarding pathological fractures, and suggested the term spontaneous fractures denoting a fracture occurring during normal jaw function being either pathological or non-pathological. Key words:Mandibular fractures, spontaneous fractures, pathological fractures, traumatic fractures, treatment. PMID:26636905

  19. Dynamic supported liquid membrane tip extraction of glyphosate and aminomethylphosphonic acid followed by capillary electrophoresis with contactless conductivity detection.

    PubMed

    See, Hong Heng; Hauser, Peter C; Sanagi, M Marsin; Ibrahim, Wan Aini Wan

    2010-09-10

    A dynamic supported liquid membrane tip extraction (SLMTE) procedure for the effective extraction and preconcentration of glyphosate (GLYP) and its metabolite aminomethylphosphonic acid (AMPA) in water has been investigated. The SLMTE procedure was performed in a semi-automated dynamic mode and demonstrated a greater performance against a static extraction. Several important extraction parameters such as donor phase pH, cationic carrier concentration, type of membrane solvent, type of acceptor stripping phase, agitation and extraction time were comprehensively optimized. A solution of Aliquat-336, a cationic carrier, in dihexyl ether was selected as the supported liquid incorporated into the membrane phase. Quantification of GLYP and AMPA was carried out using capillary electrophoresis with contactless conductivity detection. An electrolyte solution consisting of 12 mM histidine (His), 8 mM 2-(N-morpholino)ethanesulfonic acid (MES), 75 microM cetyltrimethylammonium bromide (CTAB), 3% methanol, pH 6.3, was used as running buffer. Under the optimum extraction conditions, the method showed good linearity in the range of 0.01-200 microg/L (GLYP) and 0.1-400 microg/L (AMPA), acceptable reproducibility (RSD 5-7%, n=5), low limits of detection of 0.005 microg/L for GLYP and 0.06 microg/L for AMPA, and satisfactory relative recoveries (90-94%). Due to the low cost, the SLMTE device was disposed after each run which additionally eliminated the possibility of carry-over between runs. The validated method was tested for the analysis of both analytes in spiked tap water and river water with good success. PMID:20696433

  20. Thermal shock fracture mechanics analysis of a semi-infinite medium based on the dual-phase-lag heat conduction model

    PubMed Central

    Wang, B.; Li, J. E.; Yang, C.

    2015-01-01

    The generalized lagging behaviour in solids is very important in understanding heat conduction in small-scale and high-rate heating. In this paper, an edge crack in a semi-infinite medium subjected to a heat shock on its surface is studied under the framework of the dual-phase-lag (DPL) heat conduction model. The transient thermal stress in the medium without crack is obtained first. This stress is used as the crack surface traction with an opposite sign to formulate the crack problem. Numerical results of thermal stress intensity factor are obtained as the functions of crack length and thermal shock time. Crack propagation predictions are conducted and results based on the DPL model and those based on the classical Fourier heat conduction model are compared. The thermal shock strength that the medium can sustain without catastrophic failure is established according to the maximum local stress criterion and the stress intensity factor criterion. PMID:25663805

  1. Hip fracture - discharge

    MedlinePlus

    Inter-trochanteric fracture repair - discharge; Subtrochanteric fracture repair - discharge; Femoral neck fracture repair - discharge; Trochanteric fracture repair - discharge; Hip pinning surgery - discharge

  2. Enhanced conductivity of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film by acid treatment for indium tin oxide-free organic solar cells

    NASA Astrophysics Data System (ADS)

    Lin, Chun-Chiao; Huang, Chih-Kuo; Hung, Yu-Chieh; Chang, Mei-Ying

    2016-08-01

    An acid treatment is used in the enhancement of the conductivity of the conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) thin film, which is often used as the anode in organic solar cells. There are three types of acid treatment for PEDOT:PSS thin film: hydrochloric, sulfuric, and phosphoric acid treatments. In this study, we examine and compare these three ways with each other for differences in conductivity. Hydrochloric acid results in the highest conductivity enhancement, from 0.3 to 1109 S/cm. We also discuss the optical transmittance, conductivity, surface roughness, surface morphology, and stability, as well as the factors that can influence device efficiency. The devices are fabricated using an acid-treated PEDOT:PSS thin film as the anode. The highest power conversion efficiency was 1.32%, which is a large improvement over that of the unmodified organic solar cell (0.21%). It is comparable to that obtained when using indium tin oxide (ITO) as an electrode, ca. 1.46%.

  3. Laboratory Visualization of Hydraulic Fracture Propagation and Interaction with a Network of Preexisting Fractures

    NASA Astrophysics Data System (ADS)

    Nakagawa, S.; Kneafsey, T. J.; Borglin, S. E.

    2015-12-01

    We present optical visualization experiments of hydraulic fracture propagation within transparent rock-analogue samples containing a network of preexisting fractures. Natural fractures and heterogeneities in rock have a great impact on hydraulic fracture propagation and resulting improvements in reservoir permeability. In recent years, many sophisticated numerical simulations on hydraulic fracturing have been conducted. Laboratory experiments on hydraulic fracturing are often performed with acoustic emission (Micro Earthquake) monitoring, which allows detection and location of fracturing and fracture propagation. However, the detected fractures are not necessarily hydraulically produced fractures which provide permeable pathways connected to the injection (and production) well. The primary objectives of our visualization experiments are (1) to obtain quantitative visual information of hydraulic fracture propagation affected by pre-existing fractures and (2) to distinguish fractures activated by the perturbed stress field away from the injected fluid and hydraulically produced fractures. The obtained data are also used to develop and validate a new numerical modeling technique (TOUGH-RBSN [Rigid-Body-Spring-Network] model) for hydraulic fracturing simulations, which is presented in a companion paper. The experiments are conducted using transparent soda-lime glass cubes (10 cm × 10 cm × 10 cm) containing either (1) 3D laser-engraved artificial fractures and fracture networks or (2) a random network of fractures produced by rapid thermal quenching. The strength (and also the permeability for the latter) of the fractures can be altered to examine their impact on hydraulic fracturing. The cubes are subjected to true-triaxial stress within a polyaxial loading frame, and hydraulic fractures are produced by injecting fluids with a range of viscosity into an analogue borehole drilled in the sample. The visual images of developing fractures are obtained both through a port

  4. Thermal conductivity and acid dissolution behavior of MgO-ZrO 2 ceramics for use in LWR inert matrix fuel

    NASA Astrophysics Data System (ADS)

    Medvedev, P. G.; Lambregts, M. J.; Meyer, M. K.

    2006-02-01

    Dual-phase MgO-ZrO 2 ceramics are proposed for use in inert matrix fuel for disposition of plutonium and minor actinides in existing light water reactors. The concept for use of this composite material was developed with the intent to capitalize on the known advantages of the composite's constituents: high thermal conductivity of MgO, and stability of ZrO 2 in LWR coolant. The study presented in this paper addressed the thermal conductivity and nitric acid solubility of MgO-ZrO 2 ceramics. Thermal analysis, based on experimental and analytical techniques, established that the product of all investigated compositions has the thermal conductivity superior to that of UO 2. Nitric acid dissolution experiments showed that only the free MgO phase dissolves in the nitric acid, leaving behind a porous pellet consisting of a ZrO 2-based solid solution.

  5. Optimizing fracture stimulation using treatment-well tiltmeters and integrated fracture modeling

    SciTech Connect

    Mayerhofer, M.; Stutz, L.; Davis, E.; Wolhart, S.

    2006-05-15

    This paper covers the optimization of hydraulic fracture treatments in a new coalbed methane (CBM) reservoir in Wyoming. A multiwell pilot project was conducted in the Copper Ridge (CR) field to assess future development potential. Hydraulic fracture mapping was successfully performed with treatment-well tiltmeters on six wells including the first-ever used on propped treatments. The mapped fracture height was then used to calibrate the fracture model, perform on-site fracture-design changes, and optimize future fracture treatments. This paper shows how early use of fracture diagnostics can assist in the development of a new reservoir.

  6. Acid-induced increase in electrical conductance of guinea pig duodenal mucosa in vitro. Temporary protection by combined effects of bicarbonate and prostaglandin E2.

    PubMed

    Macherey, H J; Petersen, K U

    1991-03-01

    Electrical conductance as a sensitive indicator of acid damage has been investigated in guinea pig duodenal mucosa using Ussing-chamber techniques. Reductions of luminal pH from 7.4 to 3.0, 2.3, or 2.0 caused concentration-dependent, progressive increases in conductance, accompanied (pH 2.0) by a continuous increase in hydrogen permeation as determined by pH-stat titration. Increases in conductance and hydrogen flux were related to base-line conductance, with higher values conditioning for a sooner onset and/or more marked elevation. Conductance increases were prevented by timely back titration. Recently, it has been shown that serosal HCO3 reduces conductance by actions dependent on prostaglandins and serosal Na and sensitive to loop diuretics. Here, serosal HCO3 delayed the onset of acid-induced conductance increase by approximately 8 minutes, an effect reduced by omission of serosal Na and during exposure to serosal furosemide (10(-3) mol/L). In the presence of serosal indomethacin (10(-4) mol/L) and HCO3, prostaglandin E2 (10(-6) mol/L serosal bath) delayed the conductance increase. Because HCO3 secretion is negligible in this model, these results indicate effects of HCO3/prostaglandin E2 beyond mere buffering of invading hydrogen. These results are consistent with intracellular actions that tighten the paracellular pathway against acid and thus provide temporary protection from acid injury. In agreement with this view, HCO3 also limited conductance increases after luminal alkalinization by a furosemide-sensitive action. PMID:1993487

  7. Gout increases risk of fracture: A nationwide population-based cohort study.

    PubMed

    Tzeng, Huey-En; Lin, Che-Chen; Wang, I-Kuan; Huang, Po-Hao; Tsai, Chun-Hao

    2016-08-01

    There is still debate on whether high uric acid increases bone mineral density (BMD) against osteoporotic fracture or bone resorption caused by gout inflammation. This study aimed to evaluate whether gout offers a protective effect on bone health or not. We conducted a nationwide population-based retrospective cohort study to evaluate the association between gout history and risk factors of fracture.A retrospective cohort study was designed using the claim data from Longitudinal Health Insurance Database (LHID). A total of 43,647 subjects with gout and a cohort of 87,294 comparison subjects without gout were matched in terms of age and sex between 2001 and 2009, and the data were followed until December 31, 2011. The primary outcome of the study was the fracture incidence, and the impacts of gout on fracture risks were analyzed using the Cox proportional hazards model.After an 11-year follow-up period, 6992 and 11,412 incidents of fracture were reported in gout and comparison cohorts, respectively. The overall incidence rate of fracture in individuals with gout was nearly 23%, which was higher than that in individuals without gout (252 vs 205 per 10,000 person-years) at an adjusted hazard ratio of 1.17 (95% confidence interval = 1.14-1.21). Age, sex, and fracture-associated comorbidities were adjusted accordingly. As for fracture locations, patients with gout were found at significant higher fracture risks for upper/lower limbs and spine fractures. In gout patient, the user of allopurinol or benzbromarone has significantly lower risk of facture than nonusers.Gout history is considered as a risk factor for fractures, particularly in female individuals and fracture sites located at the spine or upper/lower limbs. PMID:27559970

  8. Possible involvement of K+-conductance in the action of gamma-aminobutyric acid in the guinea-pig hippocampus.

    PubMed Central

    Inoue, M.; Matsuo, T.; Ogata, N.

    1985-01-01

    The mechanism underlying the action of gamma-aminobutyric acid (GABA) in the hippocampus was investigated using guinea-pig brain slices. GABA either superfused or applied directly by microiontophoresis produced a biphasic response in pyramidal cells, comprising hyperpolarizing and depolarizing components. When different concentrations of GABA were applied to the same neurone, the lower concentrations generally produced a hyperpolarization-predominant response, while higher concentrations resulted in a depolarization-predominant response. The depolarizing component of the response to GABA was augmented in a medium containing a low concentration of Cl-, relatively unaffected by a change in external K+ concentration, and blocked by picrotoxin (2 X 10(-5) M). The depolarizing response to GABA persisted in a Ca2+-free medium in which the concentration of Na+ was reduced to 13 mM. Combined application of low doses of picrotoxin and bicuculline eliminated the major part of the depolarizing component of the biphasic response to GABA and produced a relatively pure hyperpolarizing response. The reversal potential of this pharmacologically 'isolated' hyperpolarizing response to GABA was estimated, from the current-voltage relationships, to be about -90 mV and was the same as that of the hyperpolarization induced by baclofen. When the membrane was successively hyperpolarized by inward direct current (d.c.) injections, the reversal point of the 'pharmacologically isolated' hyperpolarizing response to GABA coincided with that of the post-burst hyperpolarization. Low concentrations of Cl- in the bathing medium had no noticeable effect on the hyperpolarizing component of the response to GABA, whereas it markedly increased the amplitude of the depolarizing component. These results suggest that the action of GABA in the hippocampus may involve an activation of K+ conductance. PMID:2413946

  9. Discrete modeling of hydraulic fracturing processes in a complex pre-existing fracture network

    NASA Astrophysics Data System (ADS)

    Kim, K.; Rutqvist, J.; Nakagawa, S.; Houseworth, J. E.; Birkholzer, J. T.

    2015-12-01

    Hydraulic fracturing and stimulation of fracture networks are widely used by the energy industry (e.g., shale gas extraction, enhanced geothermal systems) to increase permeability of geological formations. Numerous analytical and numerical models have been developed to help understand and predict the behavior of hydraulically induced fractures. However, many existing models assume simple fracturing scenarios with highly idealized fracture geometries (e.g., propagation of a single fracture with assumed shapes in a homogeneous medium). Modeling hydraulic fracture propagation in the presence of natural fractures and homogeneities can be very challenging because of the complex interactions between fluid, rock matrix, and rock interfaces, as well as the interactions between propagating fractures and pre-existing natural fractures. In this study, the TOUGH-RBSN code for coupled hydro-mechanical modeling is utilized to simulate hydraulic fracture propagation and its interaction with pre-existing fracture networks. The simulation tool combines TOUGH2, a simulator of subsurface multiphase flow and mass transport based on the finite volume approach, with the implementation of a lattice modeling approach for geomechanical and fracture-damage behavior, named Rigid-Body-Spring Network (RBSN). The discrete fracture network (DFN) approach is facilitated in the Voronoi discretization via a fully automated modeling procedure. The numerical program is verified through a simple simulation for single fracture propagation, in which the resulting fracture geometry is compared to an analytical solution for given fracture length and aperture. Subsequently, predictive simulations are conducted for planned laboratory experiments using rock-analogue (soda-lime glass) samples containing a designed, pre-existing fracture network. The results of a preliminary simulation demonstrate selective fracturing and fluid infiltration along the pre-existing fractures, with additional fracturing in part

  10. Effect of suppressor current intensity on the determination of glyphosate and aminomethylphosphonic acid by suppressed conductivity ion chromatography.

    PubMed

    Dimitrakopoulos, Ioannis K; Thomaidis, Nikolaos S; Megoulas, Nikolaos C; Koupparis, Michael A

    2010-05-28

    This paper presents the application of ion chromatography with electrolytic eluent generation and mobile phase suppression for the direct conductimetric detection of glyphosate and its degradation product aminomethylphosphonic acid (AMPA). The compounds were separated on a Dionex AS18 anion exchange column with a 12-40 mM KOH step gradient from 9 to 9.5 min. The effect of the suppressor current intensity on the electrostatic interaction of these amphoteric compounds with the suppressor cation exchange membranes was evaluated. A suppressor current gradient technique was proposed for the limitation of peak broadening and baseline noise, in order to improve method sensitivity and detectability. It was observed that residual sample carbonates co-eluted with AMPA when a large injection loop was installed for the low level determination of both compounds in natural waters. For this reason, glyphosate was isocratically eluted using 33 mM KOH in order to decrease analysis time within 10 min and a column clean up step using 100 mM KOH was used to ensure retention time reproducibility. The developed method was applied to the analysis of drinking and natural water and it was further successfully applied to orange samples with slight modifications. Instrumental LOD for glyphosate was 0.24 microg/L, while method LOD was 0.54 microg/L for spring waters and 0.01 mg/kg for oranges using a 1000 microL direct loop injection of the sample. Intra-day and inter-day precision (as %RSD) for water samples was 4.6% and 12% at a spiking level of 2 microg/L, and the recovery ranged from 64% to 88% depending on sample conductivity. For orange samples, the inter-day precision was 1.4% at a spiking level of 4.4 mg/kg, while overall recovery was 103%. The developed method is direct, fast, sensitive and relatively inexpensive, and could be used as an ideal fast screening tool for the monitoring of glyphosate residues in water and fruit samples. PMID:20399436

  11. Sensitivity of the active fracture model parameter to fracture network orientation and injection scenarios

    NASA Astrophysics Data System (ADS)

    Başağaoğlu, Hakan; Succi, Sauro; Manepally, Chandrika; Fedors, Randall; Wyrick, Danielle Y.

    2009-09-01

    Active fractures refer to the portions of unsaturated, connected fractures that actively conduct water. The active fracture model parameter accounts for the reduction in the number of fractures carrying water and in the fracture-matrix interface area in field-scale simulations of flow and transport in unsaturated fractured rocks. One example includes the numerical analyses of the fault test results at the Yucca Mountain site, Nevada (USA). In such applications, the active fracture model parameter is commonly used as a calibration parameter without relating it to fracture network orientations and infiltration rates. A two-dimensional, multiphase lattice-Boltzmann model was used in this study to investigate the sensitivity of the active fracture model parameter to fracture network orientation and injection scenarios for an unsaturated, variable dipping, and geometrically simple fracture network. The active fracture model parameter differed by as much as 0.11-0.44 when the effects of fracture network orientation, injection rate, and injection mode were included in the simulations. Hence, the numerical results suggest that the sensitivity of the active fracture model parameter to fracture network orientation, injection rates, and injection modes should be explored at the field-scale to strengthen the technical basis and range of applicability of the active fracture model.

  12. Electrochemical impedance based chiral analysis of anti-ascorbutic drug: l-Ascorbic acid and d-ascorbic acid using C-dots decorated conductive polymer nano-composite electrode.

    PubMed

    Pandey, Indu; Kant, Rama

    2016-03-15

    Clinical manifestations owing to l-ascorbic acid for scurvy as comparison to d-ascorbic acid and challenges of chiral purity are overcome by using chiral selective conductive polymer nanocomposite which mimics antibodies and enzymes. A novel chiral selective imprinted polyaniline-ferrocene-sulfonic acid film has been electrochemically fabricated on C-dots modified pencil graphite electrode. The performance of the obtained l-ascorbic acid or d-ascorbic acid chiral selective sensor was investigated by electrochemical impedance spectroscopy, cyclic and differential pulse voltammetry. The surface characteristics of the C-dots, chiral sensor before and after the de-doping of chiral d- and l-ascorbic acid were characterized by scanning electron microscopy, Raman spectroscopy and X-ray diffraction spectroscopy. Excellent recognition results were obtained by difference in electron transfer resistance. The proposed chiral sensor is capable of measuring d-ascorbic acid or l-ascorbic acid in aqueous as well as in real and commercial samples within the range of 0.020-0.187 nM and 0.003-0.232 nM with detection limit of 0.00073 nM and 0.00016 nM, respectively. The proposed method has also been examined for the chiral selective recognition of ascorbic acid isomers (d- and l-) quantitatively, in complicated matrices of real samples. PMID:26499067

  13. Fracture Management

    MedlinePlus

    ... to hold the fracture in the correct position. • Fiberglass casting is lighter and stronger and the exterior ... with your physician if this occurs. • When a fiberglass cast is used in conjunction with a GORE- ...

  14. In situ spazialisation of flow laws in a fractured media with multi-parametric measurements (pressure, deformation, water conductivity) and 2d coupled hydro-mechanical (h.m) modelling.

    NASA Astrophysics Data System (ADS)

    Charmoille, A.; Cappa, F.; Guglielmie, Y.

    2003-04-01

    Our field experiments have been realized at the Coaraze experimental site which is located in the external Alps of south-eastern France. This site corresponds to a reservoir made up of a 20 m thick pile of fractured Cretaceous limestone limited at the bottom and the top by an impervious layer. The 19,000 m3 of calcareous rock are drained by a spring which is located on a vertical fault contact between limestone and impervious marls. This fault plays the role of a natural dam for the water stocked in the reservoir. The spring is closed with a water-gate, thus, it’s possible to control the piezometric level in the reservoir by opening or closing the gate. The surface of the massif has been clogged to avoid that some leaks appear during the closure of the water-gate, when the water head is increasing. In a first experiment, we realized some hydraulic tests to characterise the different discontinuity behaviours affecting the massif. Those tests consist in pumping and water injection with for target to evaluate the field of hydraulic conductivity in the different fracture. Pumping has been realized in the discontinuity assumed permeable. Water injection has been realized between inflatable packers in the discontinuity assumed to be low permeable. For the second experimentation, we choose two areas in the field of discontinuity tested in the first phase in order to follow the rock and water behaviour during water pressure elevation in the massif. Thus, we focus our attention on one drain constituted by a tectonic fracture and one stratigraphic joint connected to the drain. During these experiments, we proceed of the following way: we closed the water gate three times for duration of 10 to 15 minutes. Thus, we induce three successive piezometric head elevations in the reservoir. Between the tap closures, the reservoir is drained during about ten minutes. The different parameters are recorded during all the experiments, when the water head is increasing and when it is

  15. Integrated Analysis of Flow, Temperature, and Specific-Conductance Logs and Depth-Dependent Water-Quality Samples from Three Deep Wells in a Fractured-Sandstone Aquifer, Ventura County, California

    USGS Publications Warehouse

    Williams, John H.; Knutson, Kevin D.

    2009-01-01

    Analysis of flow, temperature, and specific-conductance logs and depth-dependent water-quality samples collected under ambient and pumped conditions provided a preliminary delineation of flow zones and water quality in three deep abandoned water-supply wells. The integrated analysis was completed as part of the characterization of a fractured-sandstone aquifer in the mountainous setting of the Santa Susana Field Laboratory in southern Ventura County, California. In the deepest well, which was 1,768 feet deep and had the highest specific capacity (120 gallons per minute per foot), flow zones were detected at 380 feet (base of casing) and at 440, 595, and 770 feet in the open hole. Under ambient conditions, measured flow was downward from the 380- and 440-foot zones to the 595- and 770-foot zones. Under pumped conditions, most of flow was contributed by the 595-foot zone. Flow from the 380- and 440-foot zones appeared to have lower specific conductance and higher trichloroethylene concentrations than that from the 595-foot zone. In the shallowest well, which was reportedly 940 feet deep but only logged to 915 feet due to blockage, flow zones were detected behind the perforated casing and at 867 feet in the open hole. Under ambient conditions, downward and upward flows appeared to exit at a zone behind the perforated casing at 708 feet. Most of the pumped flow was contributed from zones behind the perforated casing between 565 and 708 feet. Pumped flow also was contributed by zones at 867 feet and below the logged depth. Volatile organic compounds were not detected in the ambient and pumped flows. In the third well, which was 1,272 feet deep and had the lowest specific capacity (3.6 gallons per minute per foot), flow zones were detected in the open hole above and just below the water level near 337 feet and at 615, 785, 995, and 1,070 feet. Under ambient conditions, measured flow in well was downward from the shallowmost zones to the 995-foot zone. Fracture zones at

  16. Coordinated studies in support of hydraulic fracturing of coalbed methane. Annual report, November 1991-December 1992

    SciTech Connect

    Not Available

    1993-04-01

    The purpose of the work is to characterize common and potential fracturing fluids in terms of coal-fluid interactions to identify reasons for less than satisfactory performance and to ultimately devise alternative fluids and treatment procedures to optimize production following hydraulic fracturing. The laboratory data reported herein has proven helpful in designing improved hydraulic fracturing treatments and remedial treatments in the Black Warrior Basin. Acid inhibitors, scale inhibitors, additives to improve coal relative permeability to gas, and non-damaging polymer systems for hydraulic fracturing have been screened in coal damage tests. The optimum conditions for creating field-like foams in the laboratory have been explored. Tests have been run to identify minimum polymer and surfactant concentrations for applications of foam in coal. The roll of 100 mesh sand in controlling leakoff and impairing conductivity in coal has been investigated.

  17. Natural Bile Acids and Synthetic Analogues Modulate Large Conductance Ca2+-activated K+ (BKCa) Channel Activity in Smooth Muscle Cells

    PubMed Central

    Dopico, Alejandro M.; Walsh, John V.; Singer, Joshua J.

    2002-01-01

    Bile acids have been reported to produce relaxation of smooth muscle both in vitro and in vivo. The cellular mechanisms underlying bile acid–induced relaxation are largely unknown. Here we demonstrate, using patch-clamp techniques, that natural bile acids and synthetic analogues reversibly increase BKCa channel activity in rabbit mesenteric artery smooth muscle cells. In excised inside-out patches bile acid–induced increases in channel activity are characterized by a parallel leftward shift in the activity-voltage relationship. This increase in BKCa channel activity is not due to Ca2+-dependent mechanism(s) or changes in freely diffusible messengers, but to a direct action of the bile acid on the channel protein itself or some closely associated component in the cell membrane. For naturally occurring bile acids, the magnitude of bile acid–induced increase in BKCa channel activity is inversely related to the number of hydroxyl groups in the bile acid molecule. By using synthetic analogues, we demonstrate that such increase in activity is not affected by several chemical modifications in the lateral chain of the molecule, but is markedly favored by polar groups in the side of the steroid rings opposite to the side where the methyl groups are located, which stresses the importance of the planar polarity of the molecule. Bile acid–induced increases in BKCa channel activity are also observed in smooth muscle cells freshly dissociated from rabbit main pulmonary artery and gallbladder, raising the possibility that a direct activation of BKCa channels by these planar steroids is a widespread phenomenon in many smooth muscle cell types. Bile acid concentrations that increase BKCa channel activity in mesenteric artery smooth muscle cells are found in the systemic circulation under a variety of human pathophysiological conditions, and their ability to enhance BKCa channel activity may explain their relaxing effect on smooth muscle. PMID:11865021

  18. Permeability damage to natural fractures caused by fracturing fluid polymers

    SciTech Connect

    Gall, B.L.; Sattler, A.R.; Maloney, D.R.; Raible, C.J.

    1988-04-01

    Formation damage studies using artificially fractured, low-permeability sandstone cores indicate that viscosified fracturing fluids can severely restrict gas flow through these types of narrow fractures. These studies were performed in support of the Department of Energy's Multiwell Experiment (MWX). Extensive geological and production evaluations at the MWX site indicate that the presence of a natural fracture system is largely responsible for unstimulated gas production. The laboratory formation damage studies were designed to examine changes in cracked core permeability to gas caused by fracturing fluid residues introduced into such narrow fractures during fluid leakoff. Polysaccharide polymers caused significant reduction (up to 95%) to gas flow through cracked cores. Polymer fracturing fluid gels used in this study included hydroxypropyl guar, hydroxyethyl cellulose, and xanthan gum. In contrast, polyacrylamide gels caused little or no reduction in gas flow through cracked cores after liquid cleanup. Other components of fracturing fluids (surfactants, breakers, etc.) caused less damage to gas flows. Other factors affecting gas flow through cracked cores were investigated, including the effects of net confining stress and non-Darcy flow parameters. Results are related to some of the problems observed during the stimulation program conducted for the MWX. 24 refs., 4 figs., 7 tabs.

  19. Fracture Dissolution of Carbonate Rock: An Innovative Process for Gas Storage

    SciTech Connect

    James W. Castle; Ronald W. Falta; David Bruce; Larry Murdoch; Scott E. Brame; Donald Brooks

    2006-10-31

    ) that allow for the easy removal of calcium waste from the well. Physical and chemical analysis of core samples taken from prospective geologic formations for the acid dissolution process confirmed that many of the limestone samples readily dissolved in concentrated hydrochloric acid. Further, some samples contained oily residues that may help to seal the walls of the final cavern structure. These results suggest that there exist carbonate rock formations well suited for the dissolution technology and that the presence of inert impurities had no noticeable effect on the dissolution rate for the carbonate rock. A sensitivity analysis was performed for characteristics of hydraulic fractures induced in carbonate formations to enhance the dissolution process. Multiple fracture simulations were conducted using modeling software that has a fully 3-D fracture geometry package. The simulations, which predict the distribution of fracture geometry and fracture conductivity, show that the stress difference between adjacent beds is the physical property of the formations that has the greatest influence on fracture characteristics by restricting vertical growth. The results indicate that by modifying the fracturing fluid, proppant type, or pumping rate, a fracture can be created with characteristics within a predictable range, which contributes to predicting the geometry of storage caverns created by acid dissolution of carbonate formations. A series of three-dimensional simulations of cavern formation were used to investigate three different configurations of the acid-dissolution process: (a) injection into an open borehole with production from that same borehole and no fracture; (b) injection into an open borehole with production from that same borehole, with an open fracture; and (c) injection into an open borehole connected by a fracture to an adjacent borehole from which the fluids are produced. The two-well configuration maximizes the overall mass transfer from the rock to the

  20. Previous Fractures at Multiple Sites Increase the Risk for Subsequent Fractures: The Global Longitudinal Study of Osteoporosis in Women

    PubMed Central

    Gehlbach, Stephen; Saag, Kenneth G.; Adachi, Jonathan D.; Hooven, Fred H.; Flahive, Julie; Boonen, Steven; Chapurlat, Roland D.; Compston, Juliet E.; Cooper, Cyrus; Díez-Perez, Adolfo; Greenspan, Susan L.; LaCroix, Andrea Z.; Netelenbos, J. Coen; Pfeilschifter, Johannes; Rossini, Maurizio; Roux, Christian; Sambrook, Philip N.; Silverman, Stuart; Siris, Ethel S.; Watts, Nelson B.; Lindsay, Robert

    2016-01-01

    Previous fractures of the hip, spine, or wrist are well-recognized predictors of future fracture, but the role of other fracture sites is less clear. We sought to assess the relationship between prior fracture at 10 skeletal locations and incident fracture. The Global Longitudinal Study of Osteoporosis in Women (GLOW) is an observational cohort study being conducted in 17 physician practices in 10 countries. Women ≥ 55 years answered questionnaires at baseline and at 1 and/or 2 years (fractures in previous year). Of 60,393 women enrolled, follow-up data were available for 51,762. Of these, 17.6%, 4.0%, and 1.6% had suffered 1, 2, or ≥3 fractures since age 45. During the first 2 years of follow-up, 3149 women suffered 3683 incident fractures. Compared with women with no prior fractures, women with 1, 2, or ≥ 3 prior fractures were 1.8-, 3.0-, and 4.8-fold more likely to have any incident fracture; those with ≥3 prior fractures were 9.1-fold more likely to sustain a new vertebral fracture. Nine of 10 prior fracture locations were associated with an incident fracture. The strongest predictors of incident spine and hip fractures were prior spine fracture (hazard ratio 7.3) and hip (hazard ratio 3.5). Prior rib fractures were associated with a 2.3-fold risk of subsequent vertebral fracture, previous upper leg fracture predicted a 2.2-fold increased risk of hip fracture; women with a history of ankle fracture were at 1.8-fold risk of future fracture of a weight-bearing bone. Our findings suggest that a broad range of prior fracture sites are associated with an increased risk of incident fractures, with important implications for clinical assessments and risk model development. PMID:22113888

  1. Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow

    SciTech Connect

    Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

    2013-08-01

    Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel

  2. Pediatric Thighbone (Femur) Fracture

    MedlinePlus

    ... fractures in infants under 1 year old is child abuse. Child abuse is also a leading cause of thighbone fracture ... contact sports • Being in a motor vehicle accident • Child abuse Types of Femur Fractures (Classification) Femur fractures vary ...

  3. Hydraulic fracturing-1

    SciTech Connect

    Not Available

    1990-01-01

    This book contains papers on hydraulic fracturing. Topics covered include: An overview of recent advances in hydraulic fracturing technology; Containment of massive hydraulic fracture; and Fracturing with a high-strength proppant.

  4. Tracer transport in fractured crystalline rock: Evidence of nondiffusive breakthrough tailing

    USGS Publications Warehouse

    Becker, M.W.; Shapiro, A.M.

    2000-01-01

    Extended tailing of tracer breakthrough is often observed in pulse injection tracer tests conducted in fractured geologic media. This behavior has been attributed to diffusive exchange of tracer between mobile fluids traveling through channels in fractures and relatively stagnant fluid between fluid channels, along fracture walls, or within the bulk matrix. We present a field example where tracer breakthrough tailing apparently results from nondiffusive transport. Tracer tests were conducted in a fractured crystalline rock using both a convergent and weak dipole injection and pumping scheme. Deuterated water, bromide, and pentafluorobenzoic acid were selected as tracers for their wide range in molecular diffusivity. The late time behavior of the normalized breakthrough curves were consistent for all tracers, even when the pumping rate was changed. The lack of separation between tracers of varying diffusivity indicates that strong breakthrough tailing in fractured geologic media may be caused by advective transport processes. This finding has implications for the interpretation of tracer tests designed to measure matrix diffusion in situ and the prediction of contaminant transport in fractured rock.

  5. Is It a Simple Stress Fracture or Bisphosphonate-related Atypical Fracture?

    PubMed

    Kang, Soo Yong; Baek, Ji-Hoon; Kang, Bun Jung; Kim, Min Kyu; Lee, Han-Jun

    2012-11-01

    A number of reports regarding atypical fractures of the femur have raised questions concerning the possible correlation between long-term bisphosphonate treatment and the occurrence of insufficiency fractures in the proximal femur. However, clinically, it is often confused whether is it a fatigue fracture because of implant induced stress concentration or a bisphosphonate-related atypical fracture, especially in a patient with a subtrochanteric fracture who receive bisphosphonate therapy after open reduction and internal fixation, such as dynamic hip screw (DHS) fixation for previous ipsilateral femoral neck or intertrochanteric fracture. The authors experienced a case of a progressive femoral insufficiency fracture in a woman who had been on Fosamax (Alendronic acid with Vitamin D; Merck & Co. Inc, NJ, USA) therapy for four years after ipsilateral femoral neck fracture treated with a two hole DHS system. Despite a high suspicion of an insufficiency femoral subtrochanteric fracture by bone scan, the occult fracture progressed to a displaced femoral subtrochanteric fracture one year after. The fracture site was fixed with a 6 hole DHS plate, and six months after reoperation the patient had no symptoms and the fracture site had united without any complication. PMID:24524043

  6. Relative Permeability of Fractured Rock

    SciTech Connect

    Mark D. Habana

    2002-06-30

    Contemporary understanding of multiphase flow through fractures is limited. Different studies using synthetic fractures and various fluids have yielded different relative permeability-saturation relations. This study aimed to extend the understanding of multiphase flow by conducting nitrogen-water relative permeability experiments on a naturally-fractured rock from The Geysers geothermal field. The steady-state approach was used. However, steady state was achieved only at the endpoint saturations. Several difficulties were encountered that are attributed to phase interference and changes in fracture aperture and surface roughness, along with fracture propagation/initiation. Absolute permeabilities were determined using nitrogen and water. The permeability values obtained change with the number of load cycles. Determining the absolute permeability of a core is especially important in a fractured rock. The rock may change as asperities are destroyed and fractures propagate or st rain harden as the net stresses vary. Pressure spikes occurred in water a solute permeability experiments. Conceptual models of an elastic fracture network can explain the pressure spike behavior. At the endpoint saturations the water relative permeabilities obtained are much less than the nitrogen gas relative permeabilities. Saturations were determined by weighing and by resistivity calculations. The resistivity-saturation relationship developed for the core gave saturation values that differ by 5% from the value determined by weighing. Further work is required to complete the relative permeability curve. The steady-state experimental approach encountered difficulties due to phase interference and fracture change. Steady state may not be reached until an impractical length of time. Thus, unsteady-state methods should be pursued. In unsteady-state experiments the challenge will be in quantifying rock fracture change in addition to fluid flow changes.

  7. Hydrostructural Characterization of Fracture Networks

    NASA Astrophysics Data System (ADS)

    Doe, T. W.; Hermanson, J.

    2007-12-01

    Over the past 30 years, research in underground laboratories for radioactive waste has led to the development of integrated site investigation and modeling methods for fracture networks. These activities began with the Stripa Project in central Sweden from 1977 to 1992 and have continued worldwide. Experiments on the scale of 100- 200 meter blocks have demonstrated the effectiveness of integrating testing during drilling, pressure monitoring, geologic description, flow logging, pressure transient testing, and groundwater chemistry to define fracture network geometries, particularly with respect to the identification of major features, background fractures, and compartmentalization. Major features are those large fractures or fracture zones that control the flow at the scale of interest, and must be simulated as deterministic features. Background fractures are defined stochastically, and provide connectivity between deterministic features. Based on the experience of block-scale investigations, it is possible to develop a clear picture of hydraulic networks using an integrated structural geologic, hydraulic, and hydrochemical approach. Although fracture network characterization requires a good geologic description of fractures and fracture zones from core and image logging, not all geologic features are water-conducting. Identifying water-conducting fractures begins with measurements of flow during drilling and flow logging immediately afterwards to identify significant conducting features. Major flow features must be hydraulically isolated using multiple point piezometer systems, if subsequent investigation methods are to be successful. Once installed, the pressure responses in the piezometers to subsequent drilling provide key information on connectivity and compartmentalization. Generally with three holes are sufficient to develop initial conceptual models of the major, controlling features. Subsequent boreholes test these geometric hypotheses and provide bases

  8. Hydraulic Aperture Reduction of Shale Fractures Due to Mechanical Stressing, with Characterization of Physical Fracture Evolution Using Comuted Tomography

    NASA Astrophysics Data System (ADS)

    Crandall, D.; Gill, M.; Moore, J.

    2014-12-01

    Flow in fractured shale is a topic of interest for both production from non-traditional fractured shale reservoirs and for estimating the leakage potential of sealing formations above geologic carbon dioxide repositories. The hydraulic aperture of a fracture quantifies how much fluid can be transported through a fracture, similarly to how permeability describes fluid flow through porous media. The advantage of defining the fracture hydraulic aperture as opposed to permeability, is that this property can be easily scaled up to fracture reservoir simulators. Many parameters affect the hydraulic aperture, however, including the fracture roughness, the physical aperture distribution, and the tortuosity of flow paths within the fracture.The computed tomography (CT) and flow facility at NETL has conducted an analysis of the changes in both physical and hydraulic aperture as fractures were subjected to varying external confining stresses. Changes in fracture geometry were tracked through the use of non-destructive CT imaging, allowing the determination of the physical aperture distribution, while hydraulic fracture apertures were derived from experimental fracture flow measurements. In order to evaluate the effects of fracture roughness and geometry, two fractures with different degrees of roughness were used. Tests were conducted with locally sourced shale.Experimental results show that the volume change in the fracture is a non-linear function of the confining pressure, and both physical and hydraulic apertures decrease rapidly as the fracture is first compressed.

  9. Fracture healing and lipid mediators.

    PubMed

    O'Connor, J Patrick; Manigrasso, Michaele B; Kim, Brian D; Subramanian, Sangeeta

    2014-01-01

    Lipid mediators regulate bone regeneration during fracture healing. Prostaglandins and leukotrienes are well-known lipid mediators that regulate inflammation and are synthesized from the Ω-6 fatty acid, arachidonic acid. Cyclooxygenase (COX-1 or COX-2) and 5-lipoxygenase (5-LO) catalyze the initial enzymatic steps in the synthesis of prostaglandins and leukotrienes, respectively. Inhibition or genetic ablation of COX-2 activity impairs fracture healing in animal models. Genetic ablation of COX-1 does not affect the fracture callus strength in mice, suggesting that COX-2 activity is primarily responsible for regulating fracture healing. Inhibition of cyclooxygenase activity with nonsteroidal anti-inflammatory drugs (NSAIDs) is performed clinically to reduce heterotopic ossification, although clinical evidence that NSAID treatment impairs fracture healing remains controversial. In contrast, inhibition or genetic ablation of 5-LO activity accelerates fracture healing in animal models. Even though prostaglandins and leukotrienes regulate inflammation, loss of COX-2 or 5-LO activity appears to primarily affect chondrogenesis during fracture healing. Prostaglandin or prostaglandin analog treatment, prostaglandin-specific synthase inhibition and prostaglandin or leukotriene receptor antagonism also affect callus chondrogenesis. Unlike the Ω-6-derived lipid mediators, lipid mediators derived from Ω-3 fatty acids, such as resolvin E1 (RvE1), have anti-inflammatory activity. In vivo, RvE1 can inhibit osteoclastogenesis and limit bone resorption. Although Ω-6 and Ω-3 lipid mediators have clear-cut effects on inflammation, the role of these lipid mediators in bone regeneration is more complex, with apparent effects on callus chondrogenesis and bone remodeling. PMID:24795811

  10. Rapid separation of fatty acids using a poly(vinyl alcohol) coated capillary in nonaqueous capillary electrophoresis with contactless conductivity detection.

    PubMed

    Buglione, Lucia; See, Hong Heng; Hauser, Peter C

    2013-07-01

    The determination of fatty acids by nonaqueous CZE with capacitively coupled contactless conductivity detection was investigated. A new deoxycholate-based BGE, which had previously been found to give significantly improved baseline stability in the determination of lipophilic organic ammonium ions, was found to be similarly beneficial for the determination of the anions. The use of a PVA-coated capillary was required for suppression of the EOF and to obtain well reproducible results. The complete separation of 12 fatty acids could be achieved with 10 mM DOC in methanol within 6 min under optimized conditions. The PVA-coated capillary demonstrated outstanding stability over 300 runs with no sign of depletion of the PVA layer. Method validation showed a good linearity range from 0.75 to 25 μM with correlation coefficients between 0.9949 and 0.9979. The LOD was determined as 0.5 μM for all fatty acids. The developed approach was successfully demonstrated for the separation of free fatty acids in commercial and home-made edible oil. PMID:23797990

  11. Physical Properties of Fractured Porous Media

    NASA Astrophysics Data System (ADS)

    Mohammed, T. E.; Schmitt, D. R.

    2015-12-01

    The effect of fractures on the physical properties of porous media is of considerable interest to oil and gas exploration as well as enhanced geothermal systems and carbon capture and storage. This work represents an attempt to study the effect fractures have on multiple physical properties of rocks. An experimental technique to make simultaneous electric and ultrasonic measurements on cylindrical core plugs is developed. Aluminum end caps are mounted with ultrasonic transducers to transmit pules along the axis of the cylinder while non-polarizing electrodes are mounted on the sides of the core to make complex conductivity measurements perpendicular to the cylinder axis. Electrical measurements are made by applying a sinusoidal voltage across the measurement circuit that consist of a resister and the sample in series. The magnitude and phase of the signal across the sample is recorded relative to the input signal across a range of frequencies. Synthetic rock analogs are constructed using sintered glass beads with fractures imbedded in them. The fracture location, size and orientation are controlled and each fractured specimen has an unfractured counterpart. Porosity, Permeability, electrical conductivity and ultrasonic velocity measurements are conducted on each sample with the complex electrical conductivities recorded at frequencies from 10hz to 1 Mhz. These measurements allow us to examine the changes induced by these mesoscale fractures on the embedding porous medium. Of particular interest is the effect of fracture orientation on electrical conductivity of the rock. Seismic anisotropy caused by fractures is a well understood phenomenon with many rock physics models dedicated to its understanding. The effect of fractures on electrical conductivity is less well understood with electrical anisotropy scarcely investigated in the literature. None the less, using electrical conductivity to characterize fractures can add an extra constraint to characterization based

  12. Fracture mechanisms and fracture control in composite structures

    NASA Astrophysics Data System (ADS)

    Kim, Wone-Chul

    Four basic failure modes--delamination, delamination buckling of composite sandwich panels, first-ply failure in cross-ply laminates, and compression failure--are analyzed using linear elastic fracture mechanics (LEFM) and the J-integral method. Structural failures, including those at the micromechanical level, are investigated with the aid of the models developed, and the critical strains for crack propagation for each mode are obtained. In the structural fracture analyses area, the fracture control schemes for delamination in a composite rib stiffener and delamination buckling in composite sandwich panels subjected to in-plane compression are determined. The critical fracture strains were predicted with the aid of LEFM for delamination and the J-integral method for delamination buckling. The use of toughened matrix systems has been recommended for improved damage tolerant design for delamination crack propagation. An experimental study was conducted to determine the onset of delamination buckling in composite sandwich panel containing flaws. The critical fracture loads computed using the proposed theoretical model and a numerical computational scheme closely followed the experimental measurements made on sandwich panel specimens of graphite/epoxy faceskins and aluminum honeycomb core with varying faceskin thicknesses and core sizes. Micromechanical models of fracture in composites are explored to predict transverse cracking of cross-ply laminates and compression fracture of unidirectional composites. A modified shear lag model which takes into account the important role of interlaminar shear zones between the 0 degree and 90 degree piles in cross-ply laminate is proposed and criteria for transverse cracking have been developed. For compressive failure of unidirectional composites, pre-existing defects play an important role. Using anisotropic elasticity, the stress state around a defect under a remotely applied compressive load is obtained. The experimentally

  13. Fracture behavior of the Space Shuttle thermal protection system

    NASA Technical Reports Server (NTRS)

    Komine, A.; Kobayashi, A. S.

    1983-01-01

    Stable crack-growth and fracture-toughness experiments were conducted using precracked specimens machined from LI-900 reusable surface insulation (RSI) tiles of the Space Shuttle thermal protection system (TPS) at room temperature. Similar fracture experiments were conducted on fracture specimens with preexisting cracks at the interface of the tile and the strain isolation pad (SIP). Stable crack growth was not observed in the LI-900 tile fracture specimens which had a fracture toughness of 12.0 kPa sq rt of m. The intermittent subcritical crack growth at the tile-pad interface of the fracture specimens was attributed to successive local pull-outs due to tensile overload in the LI-900 tile and cannot be characterized by linear elastic fracture mechanics. No subcritical interfacial crack growth was observed in the fracture specimens with densified LI-900 tiles where brittle fracture initiated at an interior point away from the densification.

  14. Application of geophysical methods for fracture characterization

    SciTech Connect

    Lee, K.H.; Majer, E.L.; McEvilly, T.V. |; Morrison, H.F. |

    1990-01-01

    One of the most crucial needs in the design and implementation of an underground waste isolation facility is a reliable method for the detection and characterization of fractures in zones away from boreholes or subsurface workings. Geophysical methods may represent a solution to this problem. If fractures represent anomalies in the elastic properties or conductive properties of the rocks, then the seismic and electrical techniques may be useful in detecting and characterizing fracture properties. 7 refs., 3 figs.

  15. Proximal Femoral Geometry as Fracture Risk Factor in Female Patients with Osteoporotic Hip Fracture

    PubMed Central

    Han, Jun

    2016-01-01

    Background Proximal femoral geometry may be a risk factor of osteoporotic hip fractures. However, there existed great differences among studies depending on race, sex and age of subjects. The purpose of the present study is to analyze proximal femoral geometry and bone mineral density (BMD) in the osteoporotic hip fracture patients. Furthermore, we investigated proximal femoral geometric parameters affecting fractures, and whether the geometric parameters could be an independent risk factor of fractures regardless of BMD. Methods This study was conducted on 197 women aged 65 years or more who were hospitalized with osteoporotic hip fracture (femur neck fractures ; 84, intertrochanteric fractures; 113). Control group included 551 women who visited to check osteoporosis. Femur BMD and proximal femoral geometry for all subjects were measured using dual energy X-ray absorptiometry (DXA), and compared between the control and fracture groups. Besides, proximal femoral geometric parameters associated with fractures were statistically analyzed. Results There were statistically significant differences in the age and weight, cross-sectional area (CSA)/length/width of the femoral neck and BMD of the proximal femur between fracture group and control group. BMD of the proximal femur in the control group was higher than in the fracture group. For the femoral neck fractures group, the odds ratio (OR) for fractures decrease in the CSA and neck length (NL) of the femur increased by 1.97 times and 1.73 times respectively, regardless of BMD. The OR for fractures increase in the femoral neck width increased by 1.53 times. In the intertrochanteric fracture group, the OR for fractures increase in the femoral neck width increased by 1.45 times regardless of BMD. Conclusions We found that an increase of the femoral neck width could be a proximal femoral geometric parameter which plays important roles as a risk factor for fracture independently of BMD. PMID:27622182

  16. Influence of Rock Fabric on Hydraulic Fracture Propagation: Laboratory Study

    NASA Astrophysics Data System (ADS)

    Stanchits, S. A.; Desroches, J.; Burghardt, J.; Surdi, A.; Whitney, N.

    2014-12-01

    Massive hydraulic fracturing is required for commercial gas production from unconventional reservoirs. These reservoirs are often highly fractured and heterogeneous, which may cause significant fracture complexity and also arrest propagation of hydraulic fractures, leading to production decrease. One of the goals of our study was to investigate the influence of rock fabric features on near-wellbore fracture geometry and complexity. We performed a series of laboratory tests on Niobrara outcrop shale blocks with dimensions of 30 x 30 x 36 inches in a true-triaxial loading frame. Acoustic Emission (AE) technique was applied to monitor hydraulic fracture initiation and dynamics of fracture propagation. After the tests, the shape of the created hydraulic fracture was mapped by goniometry technique. To estimate fracture aperture, particles of different sizes were injected with fracturing fluid. In all tests, AE analysis indicated hydraulic fracture initiation prior to breakdown or the maximum of wellbore pressure. In most tests, AE analysis revealed asymmetrical hydraulic fracture shapes. Post-test analysis demonstrated good correspondence of AE results with the actual 3D shape of the fracture surface map. AE analysis confirmed that in some of these tests, the hydraulic fracture approached one face of the block before the maximum wellbore pressure had been reached. We have found that in such cases the propagation of hydraulic fracture in the opposite direction was arrested by the presence of mineralized interfaces. Mapping the distribution of injected particles confirmed the creation of a narrow-width aperture in the vicinity of pre-existing interfaces, restricting fracture conductivity. Based on the results of our study, we concluded that the presence of planes of weakness, such as mineralized natural fractures, can result in the arrest of hydraulic fracture propagation, or in poor fracture geometries with limited aperture, that in turn could lead to high net pressure

  17. Updated status of conductance/capacity correlation studies to determine the state-of-health of automotive and stand-by lead/acid batteries

    NASA Astrophysics Data System (ADS)

    Feder, D. O.; Hlavac, M. J.; McShane, S. J.

    1994-02-01

    For the past seven years, Midtronics has developed and manufactured battery conductance testers for determining the condition of automotive batteries. This paper presents a further refinement of the technology. Studies by automobile manufacturers, automotive battery manufacturers, as well as testing by Midtronics and an independent test laboratory have established the utility of conductance technology in evaluating the condition of automotive batteries, even at very low states-of-charge. The use of conductance to determine the state-of-health of stand-by batteries has attracted increasing worldwide interest among both battery manufacturers and users. Attention has focused first on the area of valve-regulated lead/acid batteries (VRBs) for which there are no reliable diagnostics other than a cumbersome discharge test. Several recent studies have demonstrated the validity of conductance testing as an accurate predictor of battery capacity in railroad, electric power utility, stand-by power and telecommunications applications. Other benefits includes: (1) for the first time, tests have resulted in the accumulation and publication of large quantities of actual capacity data for individual valve-regulated cells and batteries that will serve as a standard against which conductance results can be compared; (2) results of these capacity tests have shown both unusually wide-spread capacity variation and significant numbers of premature capacity failures in valve-regulated cells over a wide range of applications in telecommunications, UPS, photovoltaic and railroad signaling systems; these failures have appeared to occur without regard to specific manufacturers, design, application or use environment; (3) in addition, both users and manufacturers have generally become more knowledgeable of performance characteristics, ageing mechanisms and failure modes of valve-regulated cells, so that it is now clearly recognized that the number of serious failure modes significantly

  18. Permeability enhancement using high energy gas fracturing

    SciTech Connect

    Chu, T.Y.; Cuderman, J.F.; Jung, J.; Jacobson, R.D.

    1986-01-01

    This paper reports the results of a preliminary study of using High Energy Gas Fracturing (HEGF) techniques for geothermal well stimulation. Experiments conducted in the G-tunnel complex at the Nevada Test Site (NTS) showed that multiple fractures could be created in water-filled boreholes using HEGF. Therefore, the method is potentially useful for geothermal well stimulation. 4 refs., 11 figs.

  19. Gallic acid and exercise training improve motor function, nerve conduction velocity but not pain sense reflex after experimental sciatic nerve crush in male rats

    PubMed Central

    Hajimoradi, Maryam; Fazilati, Mohammad; Gharib-Naseri, Mohammad Kazem; Sarkaki, Alireza

    2015-01-01

    Objective: The aim of present study was to evaluate the effects of oral administration of gallic acid (GA) for 21 days alone and in combination with exercise on nerve conduction velocity and sensory and motor functions in rats with sciatic nerve crush. Materials and Methods: Seventy adult male Wistar rats (250-300 g) were divided randomly into 7 groups with 10 in each: 1) Control (Cont), 2) Crushed + Vehicle (Cr +Veh), 3-5) Crushed + gallic acid (Cr+GA) (50, 100, and 200 mg/kg/2 mL, orally), 6) Crushed + exercise (Cr+Exe), and 7) Crushed + exercise + effective dose of gallic acid (Cr+Exe +GA200) for 21 days. In order to establish an animal model of sciatic nerve crush, equivalent to 7 kg of force pressed on 2-3 mm of sciatic nerve for 30 s, three times with 30 s intervals. Pain sense reflex in hot plate, motor coordination in rotarod, and sciatic nerve conduction velocity (SNCV) in all groups were tested. Data were analyzed using one-way ANOVA followed by Tukey’s post hoc test and p<0.05 has assigned as the significant difference. Results: Pain threshold was increased significantly in untreated crushed rats while motor function and SNCV were decreased in all groups with nerve crush (p<0.05, p<0.01, p<0.001 vs. control). Pain reflex latency was not changed in treated groups. Motor coordination and SNCV were improved in groups Cr+GA200 and Cr+Exe + GA200 (p<0.05, p<0.01 vs. Cr+Veh). Conclusion: GA, dose-dependently, may have therapeutic potential to improve the peripheral nerve degeneration, which is most likely related, at least in part, to its antioxidant and therapeutic properties. PMID:26445710

  20. Factors Controlling Wellbore Imaging of Fractures

    NASA Astrophysics Data System (ADS)

    Al-Fahmi, M. M.; Cartwright, J. A.

    2015-12-01

    There are many scientific and engineering methods in petroleum industry for collecting data about small fractures in subsurface. The acquired data is predominantly indirect, and constrained by the bounds of technology and the subtle nature of small fractures. Among the various data types, cores and wellbore images reliably provide the data to observe small fractures, and help characterize important fracture properties such as density, geometry and aperture. There is, however, a major uncertainty about how thorough is the illustration of the small fractures in the wellbore electrical images which are widely used instead of cutting core for practical and economical grounds. We present novel results to help with understanding the potential and limits of wellbore electrical imagers to detect small fractures. We compare and discuss observations from high-quality microresistivity images and their equivalent core samples that are obtained from sub-horizontal wells drilled into carbonate hydrocarbon reservoirs in eastern Arabia. We observed that the wellbore images give limited and inconsistent fracture sampling. The reduction in fracture sampling is related to the fracture nature that defies the imager-resolution capacity. We propose that the imaging capacity is constrained by: 1) degree of fracture roughness, 2) contrast between resistivity and conductivity of the geologic features, 3) effective stress action that is increasing and decreasing fracture aperture, and 4) fracture intake of drilling fluids under a variable fluid pressure balancing between wellbore and reservoir. The wellbore imaging outcomes influence fracture studies, particularly the areas of measuring static and dynamic properties of reservoir fractures and estimating trends and magnitudes of in situ stress.

  1. Coordinated studies in support of hydraulic fracturing of coalbed methane. Annual report, January 1993-April 1994

    SciTech Connect

    Penny, G.S.; Conway, M.W.

    1994-08-01

    The production of natural gas from coal typically requires stimulation in the form of hydraulic fracturing and, more recently, cavity completions. The results of hydraulic fracturing treatments have ranged from extremely successful to less than satisfactory. The purpose of this work is to characterize common and potential fracturing fluids in terms of coal-fluid interactions to identify reasons for less than satisfactory performance and to ultimately devise alternative fluids and treatment procedures to optimize production following hydraulic fracturing. The laboratory data reported herein has proven helpful in designing improved hydraulic fracturing treatments and remedial treatments in the Black Warrior Basin. Acid inhibitors, scale inhibitors, additives to improve coal relative permeability to gas, and non-damaging polymer systems for hydraulic fracturing have been screened in coal damage tests. The optimum conditions for creating field-like foams in the laboratory have been explored. Tests have been run to identify minimum polymer and surfactant concentrations for applications of foam in coal. The roll of 100 mesh sand in controlling leakoff and impairing conductivity in coal has been investigated. The leakoff and proppant transport of fluids with breaker has been investigated and recommendations have been made for breaker application to minimize damage potential in coal. A data base called COAL`S has been created in Paradox (trademark) for Windows to catalogue coalbed methane activities in the Black Warrior and San Juan Basins.

  2. Radial head fracture - aftercare

    MedlinePlus

    Elbow fracture - radial head - aftercare ... the radius bone, just below your elbow. A fracture is a break in your bone. The most common cause of a radial head fracture is falling with an outstretched arm.

  3. Hand fracture - aftercare

    MedlinePlus

    ... this page: //medlineplus.gov/ency/patientinstructions/000552.htm Hand fracture - aftercare To use the sharing features on ... need to be repaired with surgery. Types of hand fractures Your fracture may be in one of ...

  4. Tissue and size-related changes in the fatty acid and stable isotope signatures of the deep sea grenadier fish Coryphaenoides armatus from the Charlie-Gibbs Fracture Zone region of the Mid-Atlantic Ridge

    NASA Astrophysics Data System (ADS)

    Mayor, Daniel J.; Sharples, Caroline J.; Webster, Lynda; Walsham, Pamela; Lacaze, Jean-Pierre; Cousins, Nicola J.

    2013-12-01

    Coryphaenoides armatus is a cosmopolitan deep-sea fish that plays a major role in the ecology of abyssal ecosystems. We investigated the trophic ecology and physiology of this species by determining the δ13C, δ15N and fatty acid signatures of muscle, liver and ovary tissues of individuals collected from ∼2700 m to the north and south of the Charlie-Gibbs Fracture Zone (CGFZ) of the Mid-Atlantic Ridge, NE Atlantic. Fatty acid and δ13C data both suggested that C. armatus shows an ontogenetic dietary shift, with the relative contributions of benthic and pelagic prey decreasing and increasing respectively as the animals grow. They also indicated that dietary overlap between animals living to the north and south of the CGFZ increases as they grow, suggesting that larger animals forage over greater distances and are not hindered by the presence of the CGFZ. Comparison of tissue-specific fatty acid signatures with previously published data suggests compositional homeostasis of the fatty acids 20:5(n-3) and 22:6(n-3) in the muscle, and 18:1(n-9) in the liver tissues. We ascribe this primarily to strict physiological requirements for these compounds, rather than simply to their abundance in the diet. We pose several speculative mechanisms to explain the observed trends in tissue-specific δ13C and δ15N values, illustrating some of the numerous processes that can influence the isotopic signatures of bulk tissues.

  5. Electrically controlled release of benzoic acid from poly(3,4-ethylenedioxythiophene)/alginate matrix: effect of conductive poly(3,4-ethylenedioxythiophene) morphology.

    PubMed

    Paradee, Nophawan; Sirivat, Anuvat

    2014-08-01

    A drug-loaded conductive polymer/hydrogel blend, benzoic acid-loaded poly(3,4-ethylenedioxythiophene/alginate (BA-loaded PEDOT/Alg) hydrogel, was used as a carrier/matrix for an electrical stimuli transdermal drug delivery system (TDDS). The effects of cross-linking ratio, PEDOT particle size, and electric field strength on the release mechanism and the diffusion coefficient (D) of BA were examined by using a modified Franz-diffusion cell. The diffusion scaling exponent value of BA is close to 0.5 which refers to the diffusion controlled mechanism, or the Fickian diffusion as the BA release mechanism. The D increased when there was a decrease in the cross-linking ratio due to the mesh size-hindering effect. When increasing electric field strength, the D of BA-loaded PEDOT/Alg hydrogel increased because the cathode-BA(-) electrorepulsion, electroinduced alginate expansion, and PEDOT electroneutralization simultaneously occurred. The highest D belonged to a blend with the smallest PEDOT particle and highest electrical conductivity. The D of BA was a function of the matrix mesh size except when drug size/mesh size was lower than 2.38 × 10(-3), where D of BA became mesh size independent as the matrix mesh size was extremely large. Thus, the fabricated conductive polymer hydrogel blends have a great potential to be used in TDDS under electrical stimulation. PMID:25059579

  6. Dynamic fracture toughness determined using molecular dynamics

    SciTech Connect

    Swadener, J. G.; Baskes, M. I.; Nastasi, Michael Anthony,

    2004-01-01

    Molecular dynamics (MD) simulations of fracture in crystalline silicon are conducted in order to determine the dynamic fracture toughness. The MD simulations show how the potential energy released during fracture is partitioned into surface energy, energy stored in defects and kinetic energy. First, the MD fracture simulations are shown to produce brittle fracture and be in reasonable agreement with experimental results. Then dynamic hcture toughness is calculated as the sum of the surface energy and the energy stored as defects directly from the MD models. Models oriented to produce fracture on either (111) or (101) planes are used. For the (101) fracture orientation, equilibrium crack speeds of greater than 80% of the Rayleigh wave speed are obtained. Crack speeds initially show a steep increase with increasing energy release rate followed by a much more gradual increase. No plateau in crack speed is observed for static energy release rates up to 20 J/m{sup 2}. At the point where the change in crack speed behavior occur, the dynamic fracture toughness (J{sub d}) is still within 10% of two times the surface energy (2{gamma}{sub 0}) and changing very slowly. From these MD simulations, it appears that the change in crack speed behavior is due to a change in the kinetic energy generation during dynamic fracture. In addition, MD simulations of facture in silicon with defects were conducted. The addition of defects increases the inelastic dissipation and the energy stored in defects.

  7. Fracturing Experiment 2016

    SciTech Connect

    Brown, Donald W.; Keppler, H.; Kuriyagawa, Michio; Murphy, Hugh D.; Walter, Fritz

    1982-09-27

    Experiment 2016 was conducted on June 20 and 21, 1982. This experiment represented our third attempt at a fracture connection between the bottom of hole EE-2, and the openhole section of EE-3. The primary objective of Experiment 2016 was to hydraulically connect holes EE-2 and EE-3, utilizing a greater amount of injected fluid--1.3 million gallons were pumped into EE-2--and somewhat higher injection rates up to 35 BPM (as compared to 30 BPM during Expt. 2012).

  8. Economic viability of geriatric hip fracture centers.

    PubMed

    Clement, R Carter; Ahn, Jaimo; Mehta, Samir; Bernstein, Joseph

    2013-12-01

    Management of geriatric hip fractures in a protocol-driven center can improve outcomes and reduce costs. Nonetheless, this approach has not spread as broadly as the effectiveness data would imply. One possible explanation is that operating such a center is not perceived as financially worthwhile. To assess the economic viability of dedicated hip fracture centers, the authors built a financial model to estimate profit as a function of costs, reimbursement, and patient volume in 3 settings: an average US hip fracture program, a highly efficient center, and an academic hospital without a specific hip fracture program. Results were tested with sensitivity analysis. A local market analysis was conducted to assess the feasibility of supporting profitable hip fracture centers. The results demonstrate that hip fracture treatment only becomes profitable when the annual caseload exceeds approximately 72, assuming costs characteristic of a typical US hip fracture program. The threshold of profitability is 49 cases per year for high-efficiency hip fracture centers and 151 for the urban academic hospital under review. The largest determinant of profit is reimbursement, followed by costs and volume. In the authors’ home market, 168 hospitals offer hip fracture care, yet 85% fall below the 72-case threshold. Hip fracture centers can be highly profitable through low costs and, especially, high revenues. However, most hospitals likely lose money by offering hip fracture care due to inadequate volume. Thus, both large and small facilities would benefit financially from the consolidation of hip fracture care at dedicated hip fracture centers. Typical US cities have adequate volume to support several such centers. PMID:24579222

  9. Characterization of Hydraulically Induced Fractures from Monitoring and Production Data Using Ensemble Kalman Filtering

    NASA Astrophysics Data System (ADS)

    Hakim Elahi, S.; Jafarpour, B.

    2014-12-01

    Characterization of hydraulically induced fractures in unconventional oil and gas development can significantly improve production efficiency and reduce the related environmental impacts. Microseismic monitoring is the primary technology for imaging the initiation and growth of the induced fractures. While fracture geometric attributes and distribution can be inferred from recorded microseismic measurements, delineating the open fractures that contribute to production and quantifying their hydraulic properties require complementary flow and transport data such as tracer and production measurements. We consider estimating fracture geometric attribute and conductivity from combined microseismic, production, and tracer data. To this end, we use a forward model with geomechanical considerations to predict the microseismic and tracer response for hydraulically fractured formations and apply a hierarchical ensemble Kalman filtering approach to update the fracture geometric and hydraulic properties. We investigate the applicability of our estimation approach by consider several case studies with different number of fracture stages, fracture length scales, and hydraulic conductivity. We first update fracture dimensions using microseismic and tracer data that do not contain any information about flow properties. We then estimate the hydraulic conductivity of the fractures from tracer and production data. The proposed fracture imaging framework can be applied in real-time to guide the fracturing process, to monitor the fracture growth, and to optimize the hydraulic fracturing design and minimize potential environmental impacts. Moreover, calibration of the fracture conductivity can be used to predict future production and identify candidate regions for re-fracturing.

  10. Experimental and Analytical Research on Fracture Processes in ROck

    SciTech Connect

    Herbert H.. Einstein; Jay Miller; Bruno Silva

    2009-02-27

    Experimental studies on fracture propagation and coalescence were conducted which together with previous tests by this group on gypsum and marble, provide information on fracturing. Specifically, different fracture geometries wsere tested, which together with the different material properties will provide the basis for analytical/numerical modeling. INitial steps on the models were made as were initial investigations on the effect of pressurized water on fracture coalescence.

  11. Chenodeoxycholic acid stimulates Cl− secretion via cAMP signaling and increases cystic fibrosis transmembrane conductance regulator phosphorylation in T84 cells

    PubMed Central

    Ao, Mei; Sarathy, Jayashree; Domingue, Jada; Alrefai, Waddah A.

    2013-01-01

    High levels of chenodeoxycholic acid (CDCA) and deoxycholic acid stimulate Cl− secretion in mammalian colonic epithelia. While different second messengers have been implicated in this action, the specific signaling pathway has not been fully delineated. Using human colon carcinoma T84 cells, we elucidated this cascade assessing Cl− transport by measuring I− efflux and short-circuit current (Isc). CDCA (500 μM) rapidly increases I− efflux, and we confirmed by Isc that it elicits a larger response when added to the basolateral vs. apical surface. However, preincubation with cytokines increases the monolayer responsiveness to apical addition by 55%. Nystatin permeabilization studies demonstrate that CDCA stimulates an eletrogenic apical Cl− but not a basolateral K+ current. Furthermore, CDCA-induced Isc was inhibited (≥67%) by bumetanide, BaCl2, and the cystic fibrosis transmembrane conductance regulator (CFTR) inhibitor CFTRinh-172. CDCA-stimulated Isc was decreased 43% by the adenylate cyclase inhibitor MDL12330A and CDCA increases intracellular cAMP concentration. The protein kinase A inhibitor H89 and the microtubule disrupting agent nocodazole, respectively, cause 94 and 47% reductions in CDCA-stimulated Isc. Immunoprecipitation with CFTR antibodies, followed by sequential immunoblotting with Pan-phospho and CFTR antibodies, shows that CDCA increases CFTR phosphorylation by approximately twofold. The rapidity and side specificity of the response to CDCA imply a membrane-mediated process. While CDCA effects are not blocked by the muscarinic receptor antagonist atropine, T84 cells possess transcript and protein for the bile acid G protein-coupled receptor TGR5. These results demonstrate for the first time that CDCA activates CFTR via a cAMP-PKA pathway involving microtubules and imply that this occurs via a basolateral membrane receptor. PMID:23761628

  12. Formation fracturing kills Indonesian blowout

    SciTech Connect

    Wizyodiazjo, S.; Salech, M.; Sumanta, K.

    1982-11-15

    Dynamic killing methods without fracturing could not be applied in killing PT-29 blowout, due to the reservoir rock properties (shaley sand formation). A special fracturing and acidizing technique was required in order to allow the calculated kill rate of 40 bbl/ min. A low injection rate of 0.5 bbl/min with high injection pressure of 1,250 psi occurred due to a degree of formation damage and the mud cake covering the sand face. The calculated formation fracture pressure of 1,393 psi was a reliable value compared to actual fracture pressure of 1,400 psi. The designed killing rate of 40 bbl/ min could not reach the blowout well due to some leak-off of the injected fluid in unexpected directions of the induced fractures. Clearing PT-29 of all debris was very important for immediate well capping. The capping operation was done after the fire was extinguished; although the well was still flowing gas and water, no hazard of explosion was detected. The exact subsurface position of the blowout well of PT-29 was uncertain due to the lack of directional survey data. This problem reduced the effectiveness of the killing operation. A reliable water supply is important to the success of the killing job. Once the fracture had been induced, kill fluid had to be pumped continuously; any interruption might cause the fracture to heal. Deviation and directional survey data on every vertical or directional well are absolutely important for accurate relief well drilling purposes in case it is required.

  13. Hydrogen fracture toughness tester completion

    SciTech Connect

    Morgan, Michael J.

    2015-09-30

    The Hydrogen Fracture Toughness Tester (HFTT) is a mechanical testing machine designed for conducting fracture mechanics tests on materials in high-pressure hydrogen gas. The tester is needed for evaluating the effects of hydrogen on the cracking properties of tritium reservoir materials. It consists of an Instron Model 8862 Electromechanical Test Frame; an Autoclave Engineering Pressure Vessel, an Electric Potential Drop Crack Length Measurement System, associated computer control and data acquisition systems, and a high-pressure hydrogen gas manifold and handling system.

  14. Fracture channel waves

    SciTech Connect

    Nihei, K.T.; Yi, W.; Myer, L.R.; Cook, N.G.; Schoenberg, M.

    1999-03-01

    The properties of guided waves which propagate between two parallel fractures are examined. Plane wave analysis is used to obtain a dispersion equation for the velocities of fracture channel waves. Analysis of this equation demonstrates that parallel fractures form an elastic waveguide that supports two symmetric and two antisymmetric dispersive Rayleigh channel waves, each with particle motions and velocities that are sensitive to the normal and tangential stiffnesses of the fractures. These fracture channel waves degenerate to shear waves when the fracture stiffnesses are large, to Rayleigh waves and Rayleigh-Lamb plate waves when the fracture stiffnesses are low, and to fracture interface waves when the fractures are either very closely spaced or widely separated. For intermediate fracture stiffnesses typical of fractured rock masses, fracture channel waves are dispersive and exhibit moderate to strong localization of guided wave energy between the fractures. The existence of these waves is examined using laboratory acoustic measurements on a fractured marble plate. This experiment confirms the distinct particle motion of the fundamental antisymmetric fracture channel wave (A{sub 0} mode) and demonstrates the ease with which a fracture channel wave can be generated and detected. {copyright} 1999 American Geophysical Union

  15. Hydraulic Fracturing of Heterogeneous Rock Monitored by Acoustic Emission

    NASA Astrophysics Data System (ADS)

    Stanchits, Sergey; Burghardt, Jeffrey; Surdi, Aniket

    2015-11-01

    In this paper, the results of laboratory studies of hydraulic fracture in homogeneous sandstone blocks with man-made interfaces and heterogeneous shale blocks with weak natural interfaces are reported. Tests were conducted under similar stress conditions, with fluids of different viscosity and at different injection rates. The measurements and analysis allows the identification of fracture initiation and behavior. Fracturing with high-viscosity fluids resulted in stable fracture propagation initiated before breakdown, while fracturing with low-viscosity fluids resulted in unstable fracture propagation initiated almost simultaneously with breakdown. Analysis also allows us to measure the fluid volume entering the fracture and the fracture volume. Monitoring of acoustic emission hypocenter localizations, indicates the development of created fractured area including the intersection with interfaces, fluid propagation along interfaces, crossing interfaces, and approaching the boundaries of the block. We observe strong differences in hydraulic fracture behavior, fracture geometry and fracture propagation speed, when fracturing with water and high-viscosity fluids. We also observed distinct differences between sandstone blocks and shale blocks, when a certain P-wave velocity ray path is intersected by the hydraulic fracture. The velocity increases in sandstones and decreases in shale.

  16. Laboratory Visualization Experiments of Temperature-induced Fractures Around a Borehole (Cryogenic Fracturing) in Shale and Analogue Rock Samples

    NASA Astrophysics Data System (ADS)

    Kneafsey, T. J.; Nakagawa, S.; Wu, Y. S.; Mukhopadhyay, S.

    2014-12-01

    In tight shales, hydraulic fracturing is the dominant method for improving reservoir permeability. However, injecting water-based liquids can induce formation damage and disposal problems, thus other techniques are being sought. One alternative to hydraulic fracturing is producing fractures thermally, using low-temperature fluids (cryogens). The primary consequence of thermal stimulation is that shrinkage fractures are produced around the borehole wall. Recently, cryogenic stimulation produced some promising results when the cryogen (typically liquid nitrogen and cold nitrogen gas) could be brought to reservoir depth. Numerical modeling also showed possible significant increases in gas production from a shale reservoir after cryogenic stimulation. However, geometry and the dynamic behavior of these thermally induced fractures under different stress regimes and rock anisotropy and heterogeneity is not yet well understood.Currently, we are conducting a series of laboratory thermal fracturing experiments on Mancos Shale and transparent glass blocks, by injecting liquid nitrogen under atmospheric pressure into room temperature blocks under various anisotropic stress states. The glass blocks allow clear optical visualization of fracture development and final fracturing patterns. For the shale blocks, X-ray CT is used to image both pre-existing and induced fractures. Also, the effect of borehole orientation with respect to the bedding planes and aligned preexisting fractures is examined. Our initial experiment on a uniaxially compressed glass block showed fracturing behavior which was distinctly different from conventional hydraulic fracturing. In addition to tensile fractures in the maximum principal stress directions, the thermal contraction by the cryogen induced (1) chaotic, spalling fractures around the borehole wall, and (2) a series of disk-shaped annular fractures perpendicular to the borehole. When applied to a horizontal borehole, the propagation plane of the

  17. Treatment of neglected femoral neck fracture

    PubMed Central

    Jain, Anil K; Mukunth, R; Srivastava, Amit

    2015-01-01

    Intra-capsular femoral neck fractures are seen commonly in elderly people following a low energy trauma. Femoral neck fracture has a devastating effect on the blood supply of the femoral head, which is directly proportional to the severity of trauma and displacement of the fracture. Various authors have described a wide array of options for treatment of neglected/nonunion (NU) femoral neck fracture. There is lack of consensus in general, regarding the best option. This Instructional course article is an analysis of available treatment options used for neglected femoral neck fracture in the literature and attempt to suggest treatment guides for neglected femoral neck fracture. We conducted the “Pubmed” search with the keywords “NU femoral neck fracture and/or neglected femoral neck fracture, muscle-pedicle bone graft in femoral neck fracture, fibular graft in femoral neck fracture and valgus osteotomy in femoral neck fracture.” A total of 203 print articles were obtained as the search result. Thirty three articles were included in the analysis and were categorized into four subgroups based on treatment options. (a) treated by muscle-pedicle bone grafting (MPBG), (b) closed/open reduction internal fixation and fibular grafting (c) open reduction and internal fixation with valgus osteotomy, (d) miscellaneous procedures. The data was pooled from all groups for mean neglect, the type of study (prospective or retrospective), classification used, procedure performed, mean followup available, outcome, complications, and reoperation if any. The outcome of neglected femoral neck fracture depends on the duration of neglect, as the changes occurring in the fracture area and fracture fragments decides the need and type of biological stimulus required for fracture union. In stage I and stage II (Sandhu's staging) neglected femoral neck fracture osteosynthesis with open reduction and bone grafting with MPBG or Valgus Osteotomy achieves fracture union in almost 90% cases

  18. Role of Fracture and Repair Type on Pain and Opioid Use After Hip Fracture in the Elderly

    PubMed Central

    Strike, Sophia A.; Sieber, Frederick E.; Gottschalk, Allan; Mears, Simon C.

    2013-01-01

    Background and Purpose: Pain after hip fracture repair is related to worse functional outcomes and higher fracture care costs than that for patients with no or less pain. However, to our knowledge, few studies have examined the roles of hip fracture type or surgical procedure as factors influencing postoperative pain or opioid analgesic requirements. Our goal was to determine whether the type of hip fracture or hip fracture repair affects postoperative pain or opioid analgesic requirements in the elderly patient. Methods: We conducted a retrospective review of 231 patients ≥65 years old admitted to a hip fracture center for surgical repair. Fracture patterns were classified into femoral neck (FN) versus intertrochanteric (IT), stable versus unstable, and type of surgical repair. Demographic and intraoperative variables, postoperative pain scores, and opioid analgesic use data were collected and analyzed according to the type of hip fracture and type of surgical repair. Results: There were no differences in postoperative pain when comparing FN versus IT fractures, stable versus unstable fractures, or type of surgical repair. Patients with FN fractures had higher analgesic requirements on postoperative days 1, 2, and 3. There was no difference in postoperative analgesic requirements among patients with stable versus unstable fractures or type of surgical repair. Otherwise, there were no differences in postoperative pain or opioid analgesic use based on the surgical repair or fracture type. Overall, patients with hip fracture experienced low levels of pain. PMID:24600530

  19. Hydrologic imaging of fractured rock

    SciTech Connect

    Karasaki, Kenzi; Cohen, A.; Cook, P.; Freifeld, B.; Grossenbacher, K.; Peterson, J.; Vasco, D.

    1995-12-31

    Various geophysical and hydrologic tests were conducted in a cluster of nine wells to image the hydrologic connections of a fractured rock mass. Results of intra-borehole flow surveys and cross-hole radar and seismic tomography surveys correlated very well, and indicated that there is a major feature at a depth of 30m. Systematic injection tests were conducted in all nine wells. Three to four intervals in each well were isolated using pneumatic packers. Each interval was equipped with a high resolution pressure transducer. Some 130 injections tests were conducted, and more than 4,100 cross-hole transient pressure measurements were obtained. A computer algorithm was developed to analyze such massive interference data systematically. As a result of the analysis, an image of the fracture connections emerged which is consistent with the geophysical data.

  20. Fracture characteristics of balloon films

    NASA Technical Reports Server (NTRS)

    Portanova, Marc A.

    1989-01-01

    An attempt was made to determine the failure modes of high altitude scientific balloons through an investigation of the fracture characteristics of the thin polyethylene films. Two films were the subject of the evaluation, Winzen Int.'s Stratafilm SF-85 and Raven Industries' Astro-E. Research began with an investigation of the film's cold brittleness point and it's effect on the ultimate strength and elasticity of the polyethylene film. A series of preliminary investigations were conducted to develop an understanding of the material characteristics. The primary focus of this investigation was on the notch sensitivity of the films. Simple stress strain tests were also conducted to enable analysis employing fracture toughness parameters. Studies were conducted on both film types at 23 C (room temperature), -60 C, -90 C, and -120 C.

  1. Acid-resistant calcium silicate-based composite implants with high-strength as load-bearing bone graft substitutes and fracture fixation devices.

    PubMed

    Wei, Chung-Kai; Ding, Shinn-Jyh

    2016-09-01

    To achieve the excellent mechanical properties of biodegradable materials used for cortical bone graft substitutes and fracture fixation devices remains a challenge. To this end, the biomimetic calcium silicate/gelatin/chitosan oligosaccharide composite implants were developed, with an aim of achieving high strength, controlled degradation, and superior osteogenic activity. The work focused on the effect of gelatin on mechanical properties of the composites under four different kinds of mechanical stresses including compression, tensile, bending, and impact. The evaluation of in vitro degradability and fatigue at two simulated body fluid (SBF) of pH 7.4 and 5.0 was also performed, in which the pH 5.0 condition simulated clinical conditions caused by bacterial induced local metabolic acidosis or tissue inflammation. In addition, human mesenchymal stem cells (hMSCs) were sued to examine osteogenic activity. Experimental results showed that the appropriate amount of gelatin positively contributed to failure enhancement in compressive and impact modes. The 10wt% gelatin-containing composite exhibits the maximum value of the compressive strength (166.1MPa), which is within the reported compressive strength for cortical bone. The stability of the bone implants was apparently affected by the in vitro fatigue, but not by the initial pH environments (7.4 or 5.0). The gelatin not only greatly enhanced the degradation of the composite when soaked in the dynamic SBF solution, but effectively promoted attachment, proliferation, differentiation, and formation of mineralization of hMSCs. The 10wt%-gelatin composite with high initial strength may be a potential implant candidate for cortical bone repair and fracture fixation applications. PMID:27254281

  2. Estimation of Fracture Porosity in an Unsaturated Fractured Welded Tuff Using Gas Tracer Testing

    SciTech Connect

    B.M. Freifeild

    2001-10-18

    Kinematic fracture porosity is an important hydrologic transport parameter for predicting the potential of rapid contaminant migration through fractured rock. The transport velocity of a solute moving within a fracture network is inversely related to the fracture porosity. Since fracture porosity is often one or two orders of magnitude smaller than matrix porosity, and fracture permeability is often orders of magnitude greater than matrix permeability, solutes may travel significantly faster in the fracture network than in the surrounding matrix. This dissertation introduces a new methodology for conducting gas tracer tests using a field portable mass spectrometer along with analytical tools for estimating fracture porosity using the measured tracer concentration breakthrough curves. Field experiments were conducted at Yucca Mountain, Nevada, consisting of air-permeability transient testing and gas-tracer-transport tests. The experiments were conducted from boreholes drilled within an underground tunnel as part of an investigation of rock mass hydrological behavior. Air-permeability pressure transients, recorded during constant mass flux injections, have been analyzed using a numerical inversion procedure to identify fracture permeability and porosity. Dipole gas tracer tests have also been conducted from the same boreholes used for air-permeability testing. Mass breakthrough data has been analyzed using a random walk particle-tracking model, with a dispersivity that is a function of the advective velocity. The estimated fracture porosity using the tracer test and air-injection test data ranges from .001 to .015. These values are an order of magnitude greater than the values estimated by others using hydraulically estimated fracture apertures. The estimates of porosity made using air-permeability test data are shown to be highly sensitive to formation heterogeneity. Uncertainty analyses performed on the gas tracer test results show high confidence in the parameter

  3. Selective perceptions of hydraulic fracturing.

    PubMed

    Sarge, Melanie A; VanDyke, Matthew S; King, Andy J; White, Shawna R

    2015-01-01

    Hydraulic fracturing (HF) is a focal topic in discussions about domestic energy production, yet the American public is largely unfamiliar and undecided about the practice. This study sheds light on how individuals may come to understand hydraulic fracturing as this unconventional production technology becomes more prominent in the United States. For the study, a thorough search of HF photographs was performed, and a systematic evaluation of 40 images using an online experimental design involving N = 250 participants was conducted. Key indicators of hydraulic fracturing support and beliefs were identified. Participants showed diversity in their support for the practice, with 47 percent expressing low support, 22 percent high support, and 31 percent undecided. Support for HF was positively associated with beliefs that hydraulic fracturing is primarily an economic issue and negatively associated with beliefs that it is an environmental issue. Level of support was also investigated as a perceptual filter that facilitates biased issue perceptions and affective evaluations of economic benefit and environmental cost frames presented in visual content of hydraulic fracturing. Results suggested an interactive relationship between visual framing and level of support, pointing to a substantial barrier to common understanding about the issue that strategic communicators should consider. PMID:26399946

  4. Gel placement in fractured systems

    SciTech Connect

    Seright, R.S.

    1995-11-01

    This paper examines several factors that can have an important effect on gel placement in fractured systems, including gelant viscosity, degree of gelation, and gravity. For an effective gel treatment, the conductivity of the fracture must be reduced and a viable flow path must remain open between the wellbore and mobile oil in the reservoir. During placement, the gelant that``leaks off`` from the fracture into the rock plays an important role in determining how well a gel treatment will reduce channeling. For a given volume of gelant injected the distance of gelant leakoff is greater for a viscous gelant than for a low-viscosity gelant. In one method to minimize gelant leakoff, sufficient gelation is designed to occur before the gelant leaves the wellbore. The authors investigated this approach in numerous experiments with both fractured and unfractured cores. They studied Cr(III)/acetate/hydrolyzed polyacrylamide (HPAM), resorcinol/formaldehyde, Cr(III)/xanthan, aluminum/citrate/HPAM, and other gelants and gels with various delay times between gelant preparation and injection. Their results suggest both hope and caution concerning the injection of gels into fractured systems.

  5. Experimental studies of rock fracture behavior related to hydraulic fracture

    NASA Astrophysics Data System (ADS)

    Ma, Zifeng

    The objective of this experimental investigation stems from the uncontrollable of the hydraulic fracture shape in the oil and gas production field. A small-scale laboratory investigation of crack propagation in sandstone was first performed with the objective to simulate the field fracture growth. Test results showed that the fracture resistance increased with crack extension, assuming that there was an interaction between crack faces (bridging, interlocking, and friction). An acoustic emission test was conducted to examine the existence of the interaction by locating AE events and analyzing waveform. Furthermore, the effects of confining stress, loading rate, stress field, and strength heterogeneous on the tortuosity of the fracture surface were experimentally investigated in the study. Finally, a test was designed and conducted to investigate the crack propagation in a stratified media with permeability contrast. Crack was observed to arrested in an interface. The phenomenon of delamination along an interface between layers with permeability contrast was observed. The delamination was proposed to be the cause of crack arrest and crack jump in the saturated stratified materials under confinement test.

  6. Formation and characterization of conductive thin layers of copper sulfide (Cu xS) on the surface of polyethylene and polyamide by the use of higher polythionic acids

    NASA Astrophysics Data System (ADS)

    Ancutiene, Ingrida; Janickis, Vitalijus; Ivanauskas, Remigijus

    2006-04-01

    Layers of copper sulfide of varying composition and properties are formed on the surface of polyethylene and polyamide by a sorption-diffusion method using solutions of higher polythionic acids, H 2S nO 6. The concentration of sulfur adsorbed-diffused into PE and PA depends on the degree of the acid sulfurity, n, the temperature of the solution and the period of the polymer treatment. The amount of copper in a sulfide (Cu xS) layer formed after the sulfured polymer treatment with a solution of Cu(I-II) salt is strongly dependent on the concentration of sulfur in the PE and PA. By the chemical analysis of the obtained sulfide layers was determined that a value of x in the Cu xS layers varies in the interval 1 < x < 2. The microscopic investigation of transverse sections of PE and PA samples with copper sulfide layers showed that the major part of copper sulfide is in the surface matrix of the polymer. X-ray diffraction studies of the Cu xS layers obtained seven phases: with x = 2 (chalcocite), 1.9375 (djurleite), 1.8 (digenite), 1.75 (anilite), 1.12 (yarrowite), 1.06 (talnakhite) and 1 (covellite). The measurements of the electrical conductance of Cu xS layers (0.1-4 S cm -2) showed that its value greatly depends on the conditions of PE and PA interaction with H 2S nO 6 and of further interaction with Cu(I-II) salt solution, on the chemical and phase composition of the layer.

  7. Combining pH and electrical conductivity measurements to improve titrimetric methods to determine ammonia nitrogen, volatile fatty acids and inorganic carbon concentrations.

    PubMed

    Charnier, C; Latrille, E; Lardon, L; Miroux, J; Steyer, J P

    2016-05-15

    Volatile fatty acids (VFA), inorganic carbon (IC) and total ammonia nitrogen (TAN) are key variables in the current context of anaerobic digestion (AD). Accurate measurements like gas chromatography and infrared spectrometry have been developed to follow the concentration of these compounds but none of these methods are affordable for small AD units. Only titration methods answer the need for small plant monitoring. The existing methods accuracy was assessed in this study and reveals a lack of accuracy and robustness to control AD plants. To solve these issues, a new titrimetric device to estimate the VFA, IC and TAN concentrations with an improved accuracy was developed. This device named SNAC (System of titration for total ammonia Nitrogen, volatile fatty Acids and inorganic Carbon) has been developed combining the measurement of electrical conductivity and pH. SNAC were tested on 24 different plant samples in a range of 0-0.16 mol.L(-1) TAN, 0.01-0.21 mol.L(-1) IC and 0-0.04 mol.L(-1) VFA. The standard error was about 0.012 mol.L(-1) TAN, 0.015 mol.L(-1) IC and 0.003 mol.L(-1) VFA. The coefficient of determination R(2) between the estimated and reference data was 0.95, 0.94 and 0.95 for TAN, IC and VFA respectively. Using the same data, current methods based on key pH points lead to standard error more than 14.5 times higher on VFA and more than 1.2 times higher on IC. These results show that SNAC is an accurate tool to improve the management of AD plant. PMID:27010787

  8. Paratrooper's Ankle Fracture: Posterior Malleolar Fracture

    PubMed Central

    Young, Ki Won; Cho, Jae Ho; Kim, Hyung Seuk; Cho, Hun Ki; Lee, Kyung Tai

    2015-01-01

    Background We assessed the frequency and types of ankle fractures that frequently occur during parachute landings of special operation unit personnel and analyzed the causes. Methods Fifty-six members of the special force brigade of the military who had sustained ankle fractures during parachute landings between January 2005 and April 2010 were retrospectively analyzed. The injury sites and fracture sites were identified and the fracture types were categorized by the Lauge-Hansen and Weber classifications. Follow-up surveys were performed with respect to the American Orthopedic Foot and Ankle Society ankle-hindfoot score, patient satisfaction, and return to preinjury activity. Results The patients were all males with a mean age of 23.6 years. There were 28 right and 28 left ankle fractures. Twenty-two patients had simple fractures and 34 patients had comminuted fractures. The average number of injury and fractures sites per person was 2.07 (116 injuries including a syndesmosis injury and a deltoid injury) and 1.75 (98 fracture sites), respectively. Twenty-three cases (41.07%) were accompanied by posterior malleolar fractures. Fifty-five patients underwent surgery; of these, 30 had plate internal fixations. Weber type A, B, and C fractures were found in 4, 38, and 14 cases, respectively. Based on the Lauge-Hansen classification, supination-external rotation injuries were found in 20 cases, supination-adduction injuries in 22 cases, pronation-external rotation injuries in 11 cases, tibiofibular fractures in 2 cases, and simple medial malleolar fractures in 2 cases. The mean follow-up period was 23.8 months, and the average follow-up American Orthopedic Foot and Ankle Society ankle-hindfoot score was 85.42. Forty-five patients (80.36%) reported excellent or good satisfaction with the outcome. Conclusions Posterior malleolar fractures occurred in 41.07% of ankle fractures sustained in parachute landings. Because most of the ankle fractures in parachute injuries were

  9. Hydraulic-fracture propagation in layered rock: experimental studies of fracture containment

    SciTech Connect

    Teufel, L. W.; Clark, J. A.

    1981-01-01

    Fracture geometry is an important concern in the design of a massive hydraulic fracture treatment for improved natural gas recovery from tight gas sands. Possible prediction of vertical fracture growth and containment in layered rock requires an improved understanding of the parameters which may control fracture growth across layer interfaces. We have conducted laboratory hydraulic fracture experiments and elastic finite element studies which show that at least two distinct geologic conditions may inhibit or contain the vertical growth of hydraulic fractures in layered rock; (1) a weak interfacial shear strength of the layers and (2) a compressional increase in the minimum horizontal stress in the bounding layer. The second condition is more important and more likely to occur at depth. Variations in the horizontal stress can result from differences in elastic properties of individual layers in a layered rock sequence. A compressional increase in the minimum horizontal stress can occur in going from high shear modulus into low shear modulus layers.

  10. Size and Geometry Effects on Rock Fracture Toughness: Mode I Fracture

    NASA Astrophysics Data System (ADS)

    Ayatollahi, M. R.; Akbardoost, J.

    2014-03-01

    In this paper, the effects of specimen size and geometry on the apparent mode I fracture toughness ( K c) of an Iranian white marble (Neyriz) are studied. A number of fracture tests were conducted on center-cracked circular disk (CCCD) specimens with different radii to investigate the size effects on K c. The experimental results demonstrate that the apparent fracture toughness increases in bigger specimens. In order to explain the experimental results, the modified maximum tangential stress (MMTS) criterion is used, where higher order terms of the Williams' series expansion are included in the maximum tangential stress criterion. It is shown that the MMTS criterion provides good estimates for the apparent fracture toughness of Neyriz marble, obtained from fracture tests of edge-cracked triangular specimens. It is, therefore, concluded that the proposed criterion is able to account for the size and geometry effects on the fracture resistance of rocks simultaneously.

  11. Laboratory hydraulic fracturing experiments in intact and pre-fractured rock

    USGS Publications Warehouse

    Zoback, M.D.; Rummel, F.; Jung, R.; Raleigh, C.B.

    1977-01-01

    Laboratory hydraulic fracturing experiments were conducted to investigate two factors which could influence the use of the hydrofrac technique for in-situ stress determinations; the possible dependence of the breakdown pressure upon the rate of borehole pressurization, and the influence of pre-existing cracks on the orientation of generated fractures. The experiments have shown that while the rate of borehole pressurization has a marked effect on breakdown pressures, the pressure at which hydraulic fractures initiate (and thus tensile strength) is independent of the rate of borehole pressurization when the effect of fluid penetration is negligible. Thus, the experiments indicate that use of breakdown pressures rather than fracture initiation pressures may lead to an erroneous estimate of tectonic stresses. A conceptual model is proposed to explain anomalously high breakdown pressures observed when fracturing with high viscosity fluids. In this model, initial fracture propagation is presumed to be stable due to large differences between the borehole pressure and that within the fracture. In samples which contained pre-existing fractures which were 'leaky' to water, we found it possible to generate hydraulic fractures oriented parallel to the direction of maximum compression if high viscosity drilling mud was used as the fracturing fluid. ?? 1977.

  12. Surrogate-based optimization of hydraulic fracturing in pre-existing fracture networks

    NASA Astrophysics Data System (ADS)

    Chen, Mingjie; Sun, Yunwei; Fu, Pengcheng; Carrigan, Charles R.; Lu, Zhiming; Tong, Charles H.; Buscheck, Thomas A.

    2013-08-01

    Hydraulic fracturing has been used widely to stimulate production of oil, natural gas, and geothermal energy in formations with low natural permeability. Numerical optimization of fracture stimulation often requires a large number of evaluations of objective functions and constraints from forward hydraulic fracturing models, which are computationally expensive and even prohibitive in some situations. Moreover, there are a variety of uncertainties associated with the pre-existing fracture distributions and rock mechanical properties, which affect the optimized decisions for hydraulic fracturing. In this study, a surrogate-based approach is developed for efficient optimization of hydraulic fracturing well design in the presence of natural-system uncertainties. The fractal dimension is derived from the simulated fracturing network as the objective for maximizing energy recovery sweep efficiency. The surrogate model, which is constructed using training data from high-fidelity fracturing models for mapping the relationship between uncertain input parameters and the fractal dimension, provides fast approximation of the objective functions and constraints. A suite of surrogate models constructed using different fitting methods is evaluated and validated for fast predictions. Global sensitivity analysis is conducted to gain insights into the impact of the input variables on the output of interest, and further used for parameter screening. The high efficiency of the surrogate-based approach is demonstrated for three optimization scenarios with different and uncertain ambient conditions. Our results suggest the critical importance of considering uncertain pre-existing fracture networks in optimization studies of hydraulic fracturing.

  13. Numerical investigation of hydraulic fracture network propagation in naturally fractured shale formations

    NASA Astrophysics Data System (ADS)

    Zou, Yushi; Zhang, Shicheng; Ma, Xinfang; Zhou, Tong; Zeng, Bo

    2016-03-01

    Hydraulic fracture network (HFN) propagation in naturally fractured shale formations is investigated numerically using a 3D complex fracturing model based on the discrete element method. To account for the plastic deformation behavior of shales, the Drucker-Prager plasticity model is incorporated into the fracturing model. Parametric studies are then conducted for different Young's moduli, horizontal differential stresses, natural fracture (NF) properties, injection rates, and number and spacing of perforation clusters. Numerical results show that horizontal differential stress primarily determines the generation of a complex HFN. The plastic deformation of shale can reduce the stimulated reservoir volume; this is more obvious with Young's modulus of less than 20 GPa. In addition, a higher injection rate could largely increase the fracture complexity index (FCI). Moreover, increasing perforation cluster numbers per fracturing stage is beneficial for increasing the FCI, but it also increases the potential merging of neighboring fractures, which may lead to non-uniform development of HFN in far-wellbore regions. To achieve uniform development of HFN within a fracturing stage, the distribution of NFs should be fully considered. The results presented here may provide improved understanding of HFN generation and are favorable for optimizing fracturing treatment designs for shale formations.

  14. A numerical approach for pressure transient analysis of a vertical well with complex fractures

    NASA Astrophysics Data System (ADS)

    Wan, Yizhao; Liu, Yuewu; Liu, Wenchao; Han, Guofeng; Niu, Congcong

    2016-05-01

    A new well test model for a vertical fractured well is developed based on a discrete-fracture model in which the fractures are discretized as one dimensional (1-D) entities. The model overcomes the weakness of complex meshing, a large number of grids, and instability in conventional stripe-fracture models. Then, the discrete-fracture model is implemented using a hybrid element finite-element method. Triangular elements are used for matrix and line elements for the fractures. The finite element formulation is validated by comparing with the semi-analytical solution of a single vertical fractured well. The accuracy of the approach is shown through several examples with different fracture apertures, fracture conductivity, and fracture amount. Results from the discrete-fracture model agree reasonably well with the stripe-fracture model and the analytic solutions. The advantages of the discrete-fracture model are presented in mesh generation, computational improvement, and abilities to handle complex fractures like wedge-shaped fractures and fractures with branches. Analytical results show that the number of grids in the discrete-fracture model is 10 % less than stripe-fracture model, and computational efficiency increases by about 50 %. The more fractures there are, the more the computational efficiency increases.

  15. Fabrication of sulfonated poly(ether ether ketone)-based hybrid proton-conducting membranes containing carboxyl or amino acid-functionalized titania by in situ sol-gel process

    NASA Astrophysics Data System (ADS)

    Yin, Yongheng; Xu, Tao; He, Guangwei; Jiang, Zhongyi; Wu, Hong

    2015-02-01

    Functionalized titania are used as fillers to modify the sulfonated poly(ether ether ketone) (SPEEK) membrane for improved proton conductivity and methanol barrier property. The functionalized titania sol which contains proton conductive carboxylic acid groups or amino acid groups are derived from a facile chelation method using different functional additives. Then the novel SPEEK/carboxylic acid-functionalized titania (SPEEK/TC) and SPEEK/amino acid-functionalized titania (SPEEK/TNC) hybrid membranes are fabricated via in situ sol-gel method. The anti-swelling property and thermal stability of hybrid membranes are enhanced owing to the formation of electrostatic force between SPEEK and titania nanoparticles. The hybrid membranes exhibit higher proton conductivity than plain SPEEK membrane because more proton transfer sites are provided by the functionalized titania nanoparticles. Particularly, the proton conductivity of SPEEK/TNC membrane with 15% filler content reaches up to 6.24 × 10-2 S cm-1, which is 3.5 times higher than that of the pure SPEEK membrane. For methanol permeability, the SPEEK/TNC membranes possess the lowest values because the acid-base interaction between sulfonic acid groups in SPEEK and amino groups in functionalized titania leads to a more compact membrane structure.

  16. Hip fracture programs: are they effective?

    PubMed

    Kates, Stephen L

    2016-01-01

    This manuscript will evaluate the published evidence on efficacy of organized hip fracture programs to determine if they improve patient outcomes. A detailed literature search was conducted to find manuscripts published in the past 20 years about organized hip fracture care programs. Seventeen programs with published results were identified from this detailed search and these were evaluated and synthesized in the following manuscript. Organized hip fracture programs offer significant benefits to patients, care providers and health systems. The more complex program designs have a more profound effect on improvement in outcomes for hip fracture patients. Most programs have reported reduced length of stay, reduced in-hospital mortality rates, and reduced complications. Some programs have reported reduced costs and reduced readmission rates after implementing an organized hip fracture program. PMID:26768285

  17. Advanced Hydraulic Fracturing Technology for Unconventional Tight Gas Reservoirs

    SciTech Connect

    Stephen Holditch; A. Daniel Hill; D. Zhu

    2007-06-19

    The objectives of this project are to develop and test new techniques for creating extensive, conductive hydraulic fractures in unconventional tight gas reservoirs by statistically assessing the productivity achieved in hundreds of field treatments with a variety of current fracturing practices ranging from 'water fracs' to conventional gel fracture treatments; by laboratory measurements of the conductivity created with high rate proppant fracturing using an entirely new conductivity test - the 'dynamic fracture conductivity test'; and by developing design models to implement the optimal fracture treatments determined from the field assessment and the laboratory measurements. One of the tasks of this project is to create an 'advisor' or expert system for completion, production and stimulation of tight gas reservoirs. A central part of this study is an extensive survey of the productivity of hundreds of tight gas wells that have been hydraulically fractured. We have been doing an extensive literature search of the SPE eLibrary, DOE, Gas Technology Institute (GTI), Bureau of Economic Geology and IHS Energy, for publicly available technical reports about procedures of drilling, completion and production of the tight gas wells. We have downloaded numerous papers and read and summarized the information to build a database that will contain field treatment data, organized by geographic location, and hydraulic fracture treatment design data, organized by the treatment type. We have conducted experimental study on 'dynamic fracture conductivity' created when proppant slurries are pumped into hydraulic fractures in tight gas sands. Unlike conventional fracture conductivity tests in which proppant is loaded into the fracture artificially; we pump proppant/frac fluid slurries into a fracture cell, dynamically placing the proppant just as it occurs in the field. From such tests, we expect to gain new insights into some of the critical issues in tight gas fracturing, in

  18. Influence of humic acid applications on modulus of rupture, aggregate stability, electrical conductivity, carbon and nitrogen content of a crusting problem soil

    NASA Astrophysics Data System (ADS)

    Gümüş, İ.; Şeker, C.

    2015-11-01

    Soil structure is often said to be the key to soil productivity since a fertile soil, with desirable soil structure and adequate moisture supply, constitutes a productive soil. Soil structure influences soil water movement and retention, erosion, crusting, nutrient recycling, root penetration and crop yield. The objective of this work is to study humic acid (HA) application on some physical and chemical properties in weakly structured soils. The approach involved establishing a plot experiment in laboratory conditions. Different rates of HA (control, 0.5, 1, 2 and 4 %) were applied to soil during three incubation periods (21, 42 and 62 days). At the end of the each incubation period, the changes in physicochemical properties were measured. Generally, HA addition increased electrical conductivity values during all incubation periods. HA applications decreased soil modulus of rupture. Application of HA at the rate of 4 % significantly increased soil organic carbon contents. HA applications at the rate of 4 % significantly increased both mean soil total nitrogen content and aggregate stability after three incubation periods (p < 0.05). Therefore, HA has the potential to improve the structure of soil in the short term.

  19. Enhanced Photosynthesis and Growth in atquac1 Knockout Mutants Are Due to Altered Organic Acid Accumulation and an Increase in Both Stomatal and Mesophyll Conductance.

    PubMed

    Medeiros, David B; Martins, Samuel C V; Cavalcanti, João Henrique F; Daloso, Danilo M; Martinoia, Enrico; Nunes-Nesi, Adriano; DaMatta, Fábio M; Fernie, Alisdair R; Araújo, Wagner L

    2016-01-01

    Stomata control the exchange of CO2 and water vapor in land plants. Thus, whereas a constant supply of CO2 is required to maintain adequate rates of photosynthesis, the accompanying water losses must be tightly regulated to prevent dehydration and undesired metabolic changes. Accordingly, the uptake or release of ions and metabolites from guard cells is necessary to achieve normal stomatal function. The AtQUAC1, an R-type anion channel responsible for the release of malate from guard cells, is essential for efficient stomatal closure. Here, we demonstrate that mutant plants lacking AtQUAC1 accumulated higher levels of malate and fumarate. These mutant plants not only display slower stomatal closure in response to increased CO2 concentration and dark but are also characterized by improved mesophyll conductance. These responses were accompanied by increases in both photosynthesis and respiration rates, without affecting the activity of photosynthetic and respiratory enzymes and the expression of other transporter genes in guard cells, which ultimately led to improved growth. Collectively, our results highlight that the transport of organic acids plays a key role in plant cell metabolism and demonstrate that AtQUAC1 reduce diffusive limitations to photosynthesis, which, at least partially, explain the observed increments in growth under well-watered conditions. PMID:26542441

  20. A novel conducting poly(p-aminobenzene sulphonic acid)-based electrochemical sensor for sensitive determination of Sudan I and its application for detection in food stuffs.

    PubMed

    Li, Bang Lin; Luo, Jun Hua; Luo, Hong Qun; Li, Nian Bing

    2015-04-15

    In the present work, a new method for the determination of Sudan I has been developed based on a conducting poly(p-aminobenzene sulphonic acid) (poly(p-ABSA)) film modified electrode. The new electrochemical sensor showed strong accumulation ability and excellent electrocatalytic activity for Sudan I. Electrochemical oxidation signal of Sudan I at the poly(p-ABSA) modified glassy carbon electrode (poly(p-ABSA)/GCE) was significantly increased when compared to that at the bare GCE. The experimental conditions such as amount of alcohol, pH of buffer solution, accumulation time, and instrumental parameters for square wave anodic stripping voltammetry were optimised for the determination of Sudan I. Under optimum conditions, the linear regression equation of Sudan I was ip=1.868+0.1213c (ip: μA, c: μgL(-1), R=0.9981) from 1 to 500 μg L(-1) with a detection limit of 0.3 μg L(-1). Finally, this sensor was successfully employed to detect Sudan I in some hot chili and ketchup samples. PMID:25466064

  1. Epidemiology of fragility fractures.

    PubMed

    Friedman, Susan M; Mendelson, Daniel Ari

    2014-05-01

    As the world population of older adults-in particular those over age 85-increases, the incidence of fragility fractures will also increase. It is predicted that the worldwide incidence of hip fractures will grow to 6.3 million yearly by 2050. Fractures result in significant financial and personal costs. Older adults who sustain fractures are at risk for functional decline and mortality, both as a function of fractures and their complications and of the frailty of the patients who sustain fractures. Identifying individuals at high risk provides an opportunity for both primary and secondary prevention. PMID:24721358

  2. Mechanical degradation of fuel cell membranes under fatigue fracture tests

    NASA Astrophysics Data System (ADS)

    Khorasany, Ramin M. H.; Sadeghi Alavijeh, Alireza; Kjeang, Erik; Wang, G. G.; Rajapakse, R. K. N. D.

    2015-01-01

    The effects of cyclic stresses on the fatigue and mechanical stability of perfluorosulfonic acid (PFSA) membranes are experimentally investigated under standard fuel cell conditions. The experiments are conducted ex-situ by subjecting membrane specimens to cyclic uniaxial tension at controlled temperature and relative humidity. The fatigue lifetime is measured in terms of the number of cycles until ultimate fracture. The results indicate that the membrane fatigue lifetime is a strong function of the applied stress, temperature, and relative humidity. The fatigue life increases exponentially with reduced stresses in all cases. The effect of temperature is found to be more significant than that of humidity, with reduced fatigue life at high temperatures. The maximum membrane strain at fracture is determined to decrease exponentially with increasing membrane lifetime. At a given fatigue life, a membrane exposed to fuel cell conditions is shown to accommodate more plastic strain before fracture than one exposed to room conditions. Overall, the proposed ex-situ membrane fatigue experiment can be utilized to benchmark the fatigue lifetime of new materials in a fraction of the time and cost associated with conventional in-situ accelerated stress testing methods.

  3. Hydraulic Fracturing Fluid Reaction with Shale in Experiments at Unconventional Gas Reservoir Conditions

    NASA Astrophysics Data System (ADS)

    Paukert, A. N.; Hakala, A.; Jarvis, K. B.

    2015-12-01

    Despite the marked increase in hydraulic fracturing for unconventional natural gas production over the past decade, reactions between hydraulic fracturing fluids (HFF) and shale reservoirs remain poorly reported in the scientific literature. Shale-HFF interaction could cause mineral dissolution, releasing matter from the shale, or mineral precipitation that degrades reservoir permeability. Furthermore, data are limited on whether scale inhibitors are effective at preventing mineral precipitation and whether these inhibitors adversely affect reservoir fluid chemistry and permeability. To investigate HFF-rock interaction within shale reservoirs, we conducted flow-through experiments exposing Marcellus Shale to synthetic HFF at reservoir conditions (66oC, 20MPa). Outcrop shale samples were cored, artificially fractured, and propped open with quartz sand. Synthetic HFFs were mixed with chemical additives similar to those used for Marcellus Shale gas wells in Ohio and Southwestern Pennsylvania (FracFocus.org). We evaluated differences between shale reactions with HFF made from natural freshwater and reactions with HFF made from synthetic produced water (designed to simulate produced water that is diluted and re-used for subsequent hydraulic fracturing). We also compared reactions with HFFs including hydrochloric acid (HCl) to represent the initial acid stage, and HFFs excluding HCl. Reactions were determined through changes in fluid chemistry and X-ray CT and SEM imaging of the shale before and after experiments. Results from experiments with HFF containing HCl showed dissolution of primary calcite, as expected. Experiments using HFF made from synthetic produced water had significant mineral precipitation, particularly of barium and calcium sulfates. X-ray CT images from these experiments indicate precipitation of minerals occurred either along the main fracture or within smaller splay fractures, depending on fluid composition. These experiments suggest that HFF

  4. Pain-relief medication and risk of fractures.

    PubMed

    Vestergaard, Peter

    2008-09-01

    Medications to treat pain are in widespread use and any change in the risk of fracture may consequently have a significant impact at a population level. Strong analgesics of the opiate and opiate-like group are associated with an increased risk of fractures probably from an increased risk of falls resulting from the dizziness induced by these drugs. However, not all strong analgesics are associated with an increased risk of fractures. The differences are not readily explained from variations in pharmacokinetic properties. Weak analgesics mainly interact with the prostaglandin system; these drugs include non-steroidal anti-inflammatory drugs (NSAIDs), acetylsalicylic acid and acetaminophen. Acetaminophen is associated with an increased risk of fractures while acetylsalicylic acid is not. Some but not all NSAIDs are associated with an increased fracture risk, and the differences are not explained by variations in pharmacokinetic properties. More research is needed to determine if some analgesics are safer than others with respect to fracture risk. PMID:18691002

  5. Hydraulic fracturing in granite under geothermal conditions

    USGS Publications Warehouse

    Solberg, P.; Lockner, D.; Byerlee, J.D.

    1980-01-01

    The experimental hydraulic fracturing of granite under geothermal conditions produces tensile fracture at rapid fluid injection rates and shear fracture at slow injection rates and elevated differential stress levels. A sudden burst of acoustic emission activity accompanies tensile fracture formation whereas the acoustic emission rate increases exponentially prior to shear fracture. Temperature does not significantly affect the failure mechanism, and the experimental results have not demonstrated the occurrence of thermal fracturing. A critical result of these experiments is that fluid injection at intermediate rates and elevated differential stress levels increases permeability by more than an order of magnitude without producing macroscopic fractures, and low-level acoustic emission activity occurs simultaneously near the borehole and propagates outward into the specimen with time. Permeability measurements conducted at atmospheric pressure both before and after these experiments show that increased permeability is produced by permanent structural changes in the rock. Although results of this study have not demonstrated the occurrence of thermal fracturing, they suggest that fluid injection at certain rates in situ may markedly increase local permeability. This could prove critical to increasing the efficiency of heat exchange for geothermal energy extraction from hot dry rock. ?? 1980.

  6. Near-tip-screenout hydraulic fracturing of oil wells in the Bach Ho field, offshore Vietnam

    SciTech Connect

    Hung, L.V.; San, N.T.; Shelomentsev, A.G.; Tronov, J.A.; Lam, D.D.; Thomas, R.L.; Fox, T.; Bisdikian, C.

    1995-10-01

    The first hydraulic fracturing of wells in Vietnam were successfully performed Offshore in the Bach Ho (White Tiger) Oil Field. Near-tip-screenouts rather than tip-screenout treatments were performed. The goal of the project was to improve production from existing wells rather than drill new wells and reduce the cost per barrel produced. This case study involves wells with multiple perforated zones completed in the Oligocene sandstone. Zones were selectively fractured in order to optimize production. A detailed description candidate selection, design, execution and evaluation processes are presented. The Bach Ho field has been producing for 8 years but not at its potential due to various reasons including drilling and completion fluid damage. Although acidizing was an option for damage removal, hydraulic fracturing was selected as a way to bypass near-wellbore damage and generate a negative skin. Production simulators were used to quantify post-frac production. Due to suspected high closure stress, high strength proppant was selected and ramped in a high temperature fracturing fluid. Calibration treatments were conducted on several wells to quantify fluid leak-off, fracture height and Young`s modulus. Based on the results of the calibration treatment, fracture designs were modified. As predicted by computer simulation, near-tip-screenouts occurred as planned. The treatments were performed using a work boat with skid pumping/blending equipment, a computer monitoring/operation center and a laboratory. Strict QC procedures were followed to ensure the quality of all products. Post-frac well tests results and production data are presented. Overall, the fracturing campaign was very successful with wells showing negative skins and up to a five fold increase of production in agreement with systems analysis predictions.

  7. Seismic characterization of naturally fractured reservoirs

    NASA Astrophysics Data System (ADS)

    Bansal, Reeshidev

    Many hydrocarbon reservoirs have sufficient porosity but low permeability (for example, tight gas sands and coal beds). However, such reservoirs are often naturally fractured. The fracture patterns in these reservoirs can control flow and transport properties, and therefore, play an important role in drilling production wells. On the scale of seismic wavelengths, closely spaced parallel fractures behave like an anisotropic media, which precludes the response of individual fractures in the seismic data. There are a number of fracture parameters which are needed to fully characterize a fractured reservoir. However, seismic data may reveal only certain fracture parameters and those are fracture orientation, crack density and fracture infill. Most of the widely used fracture characterization methods such as S-wave splitting analysis or amplitude vs. offset and azimuth (AVOA) analysis fail to render desired results in laterally varying media. I have conducted a systematic study of the response of fractured reservoirs with laterally varying elastic and fracture properties, and I have developed a scheme to invert for the fracture parameters. I have implemented a 3D finite-difference method to generate multicomponent synthetic seismic data in general anisotropic media. I applied the finite-difference algorithm in both Standard and Rotated Staggered grids. Standard Staggered grid is used for media having symmetry up to orthorhombic (isotropic, transversely isotropic, and orthorhombic), whereas Rotated Staggered grid is implemented for monoclinic and triclinic media. I have also developed an efficient and accurate ray-bending algorithm to compute seismic traveltimes in 3D anisotropic media. AVOA analysis is equivalent to the first-order Born approximation. However, AVOA analysis can be applied only in a laterally uniform medium, whereas the Born-approximation does not pose any restriction on the subsurface structure. I have developed an inversion scheme based on a ray

  8. Infant skull fracture (image)

    MedlinePlus

    Skull fractures may occur with head injuries. Although the skull is both tough and resilient and provides excellent ... or blow can result in fracture of the skull and may be accompanied by injury to the ...

  9. Fractures in anisotropic media

    NASA Astrophysics Data System (ADS)

    Shao, Siyi

    Rocks may be composed of layers and contain fracture sets that cause the hydraulic, mechanical and seismic properties of a rock to be anisotropic. Coexisting fractures and layers in rock give rise to competing mechanisms of anisotropy. For example: (1) at low fracture stiffness, apparent shear-wave anisotropy induced by matrix layering can be masked or enhanced by the presence of a fracture, depending on the fracture orientation with respect to layering, and (2) compressional-wave guided modes generated by parallel fractures can also mask the presence of matrix layerings for particular fracture orientations and fracture specific stiffness. This report focuses on two anisotropic sources that are widely encountered in rock engineering: fractures (mechanical discontinuity) and matrix layering (impedance discontinuity), by investigating: (1) matrix property characterization, i.e., to determine elastic constants in anisotropic solids, (2) interface wave behavior in single-fractured anisotropic media, (3) compressional wave guided modes in parallel-fractured anisotropic media (single fracture orientation) and (4) the elastic response of orthogonal fracture networks. Elastic constants of a medium are required to understand and quantify wave propagation in anisotropic media but are affected by fractures and matrix properties. Experimental observations and analytical analysis demonstrate that behaviors of both fracture interface waves and compressional-wave guided modes for fractures in anisotropic media, are affected by fracture specific stiffness (controlled by external stresses), signal frequency and relative orientation between layerings in the matrix and fractures. A fractured layered medium exhibits: (1) fracture-dominated anisotropy when the fractures are weakly coupled; (2) isotropic behavior when fractures delay waves that are usually fast in a layered medium; and (3) matrix-dominated anisotropy when the fractures are closed and no longer delay the signal. The

  10. Bone fracture repair - slideshow

    MedlinePlus

    ... page: //medlineplus.gov/ency/presentations/100077.htm Bone fracture repair - series To use the sharing features on ... to slide 4 out of 4 Indications Overview Fractures of the bones are classified in a number ...

  11. Forearm Fractures in Children

    MedlinePlus

    .org Forearm Fractures in Children The forearm is the part of the arm between the wrist and the elbow. It is ... two bones: the radius and the ulna. Forearm fractures are common in childhood, accounting for more than ...

  12. Nasal fracture - aftercare

    MedlinePlus

    ... page: //medlineplus.gov/ency/patientinstructions/000554.htm Nasal fracture - aftercare To use the sharing features on this ... that gives your nose its shape. A nasal fracture occurs when the bony part of your nose ...

  13. Nasal fracture (image)

    MedlinePlus

    A nasal fracture is a break in the bone over the ridge of the nose. It usually results from a blunt ... and is one of the most common facial fracture. Symptoms of a broken nose include pain, blood ...

  14. Hip fracture surgery

    MedlinePlus

    ... neck fracture repair; Trochanteric fracture repair; Hip pinning surgery; Osteoarthritis-hip ... You may receive general anesthesia before this surgery. This means ... spinal anesthesia. With this kind of anesthesia, medicine is ...

  15. Electrically conductive proppant and methods for detecting, locating and characterizing the electrically conductive proppant

    DOEpatents

    Cannan, Chad; Bartel, Lewis; Palisch, Terrence; Aldridge, David

    2015-01-13

    Electrically conductive proppants and methods for detecting, locating, and characterizing same are provided. The electrically conductive proppant can include a substantially uniform coating of an electrically conductive material having a thickness of at least 500 nm. The method can include injecting a hydraulic fluid into a wellbore extending into a subterranean formation at a rate and pressure sufficient to open a fracture therein, injecting into the fracture a fluid containing the electrically conductive proppant, electrically energizing the earth at or near the fracture, and measuring three dimensional (x, y, and z) components of electric and magnetic field responses at a surface of the earth or in an adjacent wellbore.

  16. Pediatric Open Fractures.

    PubMed

    Trionfo, Arianna; Cavanaugh, Priscilla K; Herman, Martin J

    2016-07-01

    Open fractures in children are rare and are typically associated with better prognoses compared with their adult equivalents. Regardless, open fractures pose a challenge because of the risk of healing complications and infection, leading to significant morbidity even in the pediatric population. Therefore, the management of pediatric open fractures requires special consideration. This article comprehensively reviews the initial evaluation, classification, treatment, outcomes, and controversies of open fractures in children. PMID:27241379

  17. Electrically conductive material

    DOEpatents

    Singh, J.P.; Bosak, A.L.; McPheeters, C.C.; Dees, D.W.

    1993-09-07

    An electrically conductive material is described for use in solid oxide fuel cells, electrochemical sensors for combustion exhaust, and various other applications possesses increased fracture toughness over available materials, while affording the same electrical conductivity. One embodiment of the sintered electrically conductive material consists essentially of cubic ZrO[sub 2] as a matrix and 6-19 wt. % monoclinic ZrO[sub 2] formed from particles having an average size equal to or greater than about 0.23 microns. Another embodiment of the electrically conductive material consists essentially at cubic ZrO[sub 2] as a matrix and 10-30 wt. % partially stabilized zirconia (PSZ) formed from particles having an average size of approximately 3 microns. 8 figures.

  18. Electrically conductive material

    DOEpatents

    Singh, Jitendra P.; Bosak, Andrea L.; McPheeters, Charles C.; Dees, Dennis W.

    1993-01-01

    An electrically conductive material for use in solid oxide fuel cells, electrochemical sensors for combustion exhaust, and various other applications possesses increased fracture toughness over available materials, while affording the same electrical conductivity. One embodiment of the sintered electrically conductive material consists essentially of cubic ZrO.sub.2 as a matrix and 6-19 wt. % monoclinic ZrO.sub.2 formed from particles having an average size equal to or greater than about 0.23 microns. Another embodiment of the electrically conductive material consists essentially at cubic ZrO.sub.2 as a matrix and 10-30 wt. % partially stabilized zirconia (PSZ) formed from particles having an average size of approximately 3 microns.

  19. Fractured tooth (image)

    MedlinePlus

    A tooth can be chipped or fractured during an accident or a bad fall. A tooth that is chipped or not badly fractured can usually be handled on a nonemergency basis. A tooth that is badly fractured may have exposed nerve ...

  20. Hydraulic Fracturing Mineback Experiment in Complex Media

    NASA Astrophysics Data System (ADS)

    Green, S. J.; McLennan, J. D.

    2012-12-01

    Hydraulic fracturing (or "fracking") for the recovery of gas and liquids from tight shale formations has gained much attention. This operation which involves horizontal well drilling and massive hydraulic fracturing has been developed over the last decade to produce fluids from extremely low permeability mudstone and siltstone rocks with high organic content. Nearly thirteen thousand wells and about one hundred and fifty thousand stages within the wells were fractured in the US in 2011. This operation has proven to be successful, causing hundreds of billions of dollars to be invested and has produced an abundance of natural gas and is making billions of barrels of hydrocarbon liquids available for the US. But, even with this commercial success, relatively little is clearly known about the complexity--or lack of complexity--of the hydraulic fracture, the extent that the newly created surface area contacts the high Reservoir Quality rock, nor the connectivity and conductivity of the hydraulic fractures created. To better understand this phenomena in order to improve efficiency, a large-scale mine-back experiment is progressing. The mine-back experiment is a full-scale hydraulic fracture carried out in a well-characterized environment, with comprehensive instrumentation deployed to measure fracture growth. A tight shale mudstone rock geologic setting is selected, near the edge of a formation where one to two thousand feet difference in elevation occurs. From the top of the formation, drilling, well logging, and hydraulic fracture pumping will occur. From the bottom of the formation a horizontal tunnel will be mined using conventional mining techniques into the rock formation towards the drilled well. Certain instrumentation will be located within this tunnel for observations during the hydraulic fracturing. After the hydraulic fracturing, the tunnel will be extended toward the well, with careful mapping of the created hydraulic fracture. Fracturing fluid will be

  1. Abiotic reversible self-assembly of fulvic and humic acid aggregates in low electrolytic conductivity solutions by dynamic light scattering and zeta potential investigation.

    PubMed

    Esfahani, Milad Rabbani; Stretz, Holly A; Wells, Martha J M

    2015-12-15

    The aggregation of humic substances and their interaction with filtration media (membranes, soils) has implications for our understanding of membrane fouling during water treatment, the facilitated transport of contaminants, and the transport of organic matter through the microbial loop. To investigate the aggregation of fulvic and humic acids in low electrolytic conductivity solutions, laboratory studies of simulated environmental water samples as well as actual environmental water samples were examined. Intensity-, volume-, and number-based particle size distributions (PSDs) were obtained by dynamic light scattering. Aggregates were categorized into three ranges, i.e., 10-100 nm, 100-1000 nm, and >1 μm. Individual biomacromolecules and the aggregates between 10 nm and 1 μm were presumed to be precursors for the formation of a large 5-μm-sized-particle. The self-assembly of the large-in-volume, few-in-number, 5-μm-sized particle was observed in real-time and occurred in unfiltered samples and in samples filtered (0.45 μm) at a nominal size one order of magnitude smaller. The supramicrometer-sized particle formed, dissipated, and spontaneously re-formed over turbulent/quiescent cycles in the presence of sodium azide indicating reversible abiotic self-assembly. Zeta potential analyses demonstrated that colloidal stability increased as concentration increased. DLS studies of the environmental water samples were comparable to those of the simulated laboratory samples. The operational range of the instrumentation used in these experiments was 0.6 nm-6 μm; therefore, aggregates larger than 6 μm may exist in these solutions. PMID:26282742

  2. Simulating conservative tracers in fractured till under realistic timescales.

    PubMed

    Helmke, M F; Simpkins, W W; Horton, R

    2005-01-01

    Discrete-fracture and dual-porosity models are infrequently used to simulate solute transport through fractured unconsolidated deposits, despite their more common application in fractured rock where distinct flow regimes are hypothesized. In this study, we apply four fracture transport models--the mobile-immobile model (MIM), parallel-plate discrete-fracture model (PDFM), and stochastic and deterministic discrete-fracture models (DFMs)--to demonstrate their utility for simulating solute transport through fractured till. Model results were compared to breakthrough curves (BTCs) for the conservative tracers potassium bromide (KBr), pentafluorobenzoic acid (PFBA), and 1,4-piperazinediethanesulfonic acid (PIPES) in a large-diameter column of fractured till. Input parameters were determined from independent field and laboratory methods. Predictions of Br BTCs were not significantly different among models; however, the stochastic and deterministic DFMs were more accurate than the MIM or PDFM when predicting PFBA and PIPES BTCs. DFMs may be more applicable than the MIM for tracers with small effective diffusion coefficients (De) or for short timescales due to differences in how these models simulate diffusion or incorporate heterogeneities by their fracture networks. At large scales of investigation, the more computationally efficient MIM and PDFM may be more practical to implement than the three-dimensional DFMs, or a combination of model approaches could be employed. Regardless of the modeling approach used, fractures should be incorporated routinely into solute transport models in glaciated terrain. PMID:16324009

  3. Fracture Characterization in the Astor Pass Geothermal Field, Nevada

    NASA Astrophysics Data System (ADS)

    Walsh, D. C.; Reeves, D. M.; Pohll, G.; Lyles, B. F.; Cooper, C. A.

    2011-12-01

    The Astor Pass geothermal field, near Pyramid Lake, NV, is under study as a site of potential geothermal energy production. Three wells have been completed in the graben of this typical Basin and Range geologic setting. Lithologies include a layer of unconsolidated sediment (basin fill) underlain by various tertiary volcanic units and granodiorite and metavolcanic basement rock. Characterization of fractures within the relatively impermeable rock matrix is being conducted for the three wells. Statistical analysis of fracture orientation, densities, and spacing obtained from borehole imaging logs is used to determine stress orientation and to generate a statistically equivalent Discrete Fracture Network (DFN) model. Fractures at depth are compared to fracture data collected in nearby outcrops of the same lithologic stratigraphy. Fracture geometry and density is correlated to mechanically discrete layers within the stratigraphy to test whether variations in fracturing can be attributed to variations in Young's modulus. Correlation of fracture geometry and densities with spinner flowmeter logs and distributed temperature sensor records are made in an effort to identify potential flowing fracture zones intersecting the borehole. Mean fracture aperture is obtained from open fracture counts and reservoir-scale transmissivity values (computed from a 30 day pump test) in the absence of readily available aperture data. The goal of this thorough fracture characterization is to create a physically relevant model which may be coupled with a multipurpose fluid flow and thermal simulator for investigation of geothermal reservoir behavior, particularly at the borehole scale.

  4. Bone mineral density testing after fragility fracture

    PubMed Central

    Posen, Joshua; Beaton, Dorcas E.; Sale, Joanna; Bogoch, Earl R.

    2013-01-01

    Abstract Objective To determine the proportion of patients with fragility fractures who can be expected to have low bone mineral density (BMD) at the time of fracture and to assist FPs in deciding whether to refer patients for BMD testing. Data sources MEDLINE, EMBASE, and CINAHL were searched from the earliest available dates through September 2009. Study selection English-language articles reporting BMD test results of patients with fragility fractures who were managed in an orthopedic environment (eg, fracture clinic, emergency management by orthopedic surgeons, inpatients) were eligible for review. While the orthopedic environment has been identified as an ideal point for case finding, FPs are often responsible for investigation and treatment. Factors that potentially influenced BMD test results (eg, selection of fracture types, exclusion criteria) were identified. Studies with 2 or more selection factors of potential influence were flagged, and rates of low BMD were calculated including and excluding these studies. Synthesis The distribution of the proportion of persons with low BMD was summarized across studies using descriptive statistics. We calculated lower boundaries on this distribution, using standard statistical thresholds, to determine a lower threshold of the expected rate of low BMD. Conclusion Family physicians evaluating patients with fragility fractures can expect that at least two-thirds of patients with fragility fractures who are older than 50 years of age will have low BMD (T score ≤ −1.0). With this a priori expectation, FPs might more readily conduct a fracture risk assessment and pursue warranted fracture risk reduction strategies following fragility fracture. PMID:24336562

  5. Polymers for acid thickening

    SciTech Connect

    Dixon, K.W.

    1980-09-30

    Acids, thickened with branched emulsion or suspension polymers of diallyldimethylammonium chloride are useful as oil well drilling and fracturing fluids for stimulating well production and in other applications, such as thickeners for cosmetics, paints, adhesives, textiles and printing inks.

  6. Talus fractures: surgical principles.

    PubMed

    Rush, Shannon M; Jennings, Meagan; Hamilton, Graham A

    2009-01-01

    Surgical treatment of talus fractures can challenge even the most skilled foot and ankle surgeon. Complicated fracture patterns combined with joint dislocation of variable degrees require accurate assessment, sound understanding of principles of fracture care, and broad command of internal fixation techniques needed for successful surgical care. Elimination of unnecessary soft tissue dissection, a low threshold for surgical reduction, liberal use of malleolar osteotomy to expose body fracture, and detailed attention to fracture reduction and joint alignment are critical to the success of treatment. Even with the best surgical care complications are common and seem to correlate with injury severity and open injuries. PMID:19121756

  7. Characteristics of bone turnover in the long bone metaphysis fractured patients with normal or low Bone Mineral Density (BMD).

    PubMed

    Wölfl, Christoph; Schweppenhäuser, Daniela; Gühring, Thorsten; Takur, Caner; Höner, Bernd; Kneser, Ulrich; Grützner, Paul Alfred; Kolios, Leila

    2014-01-01

    The incidence of osteoporotic fractures increases as our population ages. Until now, the exact biochemical processes that occur during the healing of metaphyseal fractures remain unclear. Diagnostic instruments that allow a dynamic insight into the fracture healing process are as yet unavailable. In the present matched pair analysis, we study the time course of the osteoanabolic markers bone specific alkaline phosphatase (BAP) and transforming growth factor β1 (TGFβ1), as well as the osteocatabolic markers crosslinked C-telopeptide of type-I-collagen (β-CTX) and serum band 5 tartrate-resistant acid phosphatase (TRAP5b), during the healing of fractures that have a low level of bone mineral density (BMD) compared with fractures that have a normal BMD. Between March 2007 and February 2009, 30 patients aged older than 50 years who suffered a metaphyseal fracture were included in our study. BMDs were verified by dual energy Xray absorptiometry (DXEA) scans. The levels of BTMs were examined over an 8-week period. Osteoanabolic BAP levels in those with low levels of BMD were significantly different from the BAP levels in those with normal BMD. BAP levels in the former group increased constantly, whereas the latter group showed an initial strong decrease in BAP followed by slowly rising values. Osteocatabolic β-CTX increased in the bone of the normal BMD group constantly, whereas these levels decreased significantly in the bone of the group with low BMD from the first week. TRAP5b was significantly reduced in the low level BMD group. With this work, we conduct first insights into the molecular biology of the fracture healing process in patients with low levels of BMD that explains the mechanism of its fracture healing. The results may be one reason for the reduced healing qualities in bones with low BMD. PMID:24788647

  8. Field fracturing multi-sites project. Annual technical progress report, July 28, 1993--July 31, 1994

    SciTech Connect

    Not Available

    1995-02-01

    The objective of the Field Fracturing Multi-Sites Project (M-Site) is to conduct experiments to definitively determine hydraulic fracture dimensions using remote well and treatment well diagnostic techniques. In addition, experiments will be conducted to provide data which will resolve significant unknowns with regard to hydraulic fracture modeling, fluid fracture rheology and fracture treatment design. These experiments will be supported by a well-characterized subsurface environment, as well as surface facilities and equipment that are conducive to acquiring high-quality data. The goal is to develop a fully characterized, tight reservoir-typical, field-scale hydraulic-fracturing test site.

  9. MULTI-PHASE FRACTURE-MATRIX INTERACTIONS UNDER STRESS CHANGES

    SciTech Connect

    A.S. Grader; D. Elsworth; P.M. Halleck; F. Alvarado; A. Alajmi; Z. Karpyn; N. Mohammed; S. Al-Enezi

    2005-06-15

    quantify the distribution of apertures and the nature of the asperities. Low resolution images of fluids in a sample with a shear fracture were performed and they provide the confidence that flow patterns and saturations could be determined in the future. A series of water imbibition tests were conducted in which water was injected into a fracture and its migration into the matrix was monitored with CT and DR x-ray techniques. The objective is to understand the impact of the fracture, its topology and occupancy on the nature of mass transfer between the matrix and the fracture. Counter-current imbibition next to the fracture was observed and quantified, including the influence of formation layering.

  10. MULTI-PHASE FRACTURE-MATRIX INTERACTIONS UNDER STRESS CHANGES

    SciTech Connect

    A.S. Grader; D. Elsworth; P.M. Halleck; F. Alvarado; A. Alajmi; Z. Karpyn; N. Mohammed; S. Al-Enezi

    2005-06-15

    quantify the distribution of apertures and the nature of the asperities. Low resolution images of fluids in a sample with a shear fracture were performed and they provide the confidence that flow patterns and saturations could be determined in the future. A series of water imbibition tests were conducted in which water was injected into a fracture and its migration into the matrix was monitored with CT and DR x-ray techniques. The objective is to understand the impact of the fracture, its topology and occupancy on the nature of mass transfer between the matrix and the fracture. Counter-current imbibition next to the fracture was observed and quantified, including the influence of formation layering.

  11. Epidemiology of clavicle fractures.

    PubMed

    Postacchini, Franco; Gumina, Stefano; De Santis, Pierfrancesco; Albo, Francesco

    2002-01-01

    An epidemiologic study of 535 isolated clavicle fractures treated in a hospital of a large metropolis during an 11-year period was performed. Data regarding patient's age and sex, side involved, mechanism of injury, and season in which the fracture occurred were obtained from the clinical records. Radiographic classification was performed with the Allman system. Clavicle fractures represented 2.6% of all fractures and 44% of those in the shoulder girdle. Most patients were men (68%), and the left side was involved in 61% of cases. Fractures of the middle third of the clavicle, which were the most common (81%), were displaced in 48% of cases and comminuted in 19%. Fractures of the medial third were the least common (2%). The prevalence of midclavicular fractures was found to decrease progressively with age, starting from the first decade of life when they represented 88.2% of all clavicle fractures and were undisplaced in 55.5% of cases. In adults, the incidence of displaced fractures, independent of location, was higher than that of undisplaced fractures. Traffic accidents were the most common cause of the injury. In the period under study, the incidence of fractures showed no significant change over time and no seasonal variation. PMID:12378163

  12. Fluid-driven multiple fracture growth from a permeable bedding plane intersected by an ascending hydraulic fracture

    NASA Astrophysics Data System (ADS)

    Zhang, Xi; Jeffrey, Robert G.

    2012-12-01

    In bedded sedimentary rocks, the energy for spontaneous growth of multiple vertical fractures from a bedding plane may be provided by an overpressurized sublayer fracture that connects a fluid source to the bedding plane. In this paper, using our coupled deformation and flow model, we study the processes and mechanisms involved in the formation and interaction of closely space fractures from preexisting flaws or starter fractures located along the bedding plane. Fracture growth from multiple flaws can be convergent, parallel or divergent, depending on the factors like contrasts in moduli and far-field stresses, flaw sizes and locations, and initial bed conductivity, fluid viscosity, and injection rate, as well as time. The results presented here have been obtained for conditions where fluid viscous dissipation is dominant, in contrast to other results available in literature based on uniform pressure assumption equivalent to use of an inviscid fluid. It is demonstrated that the earlier a hydraulic fracture starts to extend, the more likely it is to become the primary fracture in a system of closely spaced fractures. The fracture closest to the fluid source typically grows faster as a result of a higher pressure level because viscous dissipation results in a decrease in pressure with distance from the fluid source. But its development does not completely inhibit the growth of other hydraulic fractures. Simultaneous growth of closely spaced fractures is supported by the local stress and energetic analyses, and the fracture distance can be very small. Their length to spacing ratio is accordingly much larger than that predicted previously. Under certain circumstances, a longer and more permeable fracture may grow to a greater extent than a shorter fracture closer to the fluid source, which may grow toward and merge with the longer fracture to create fracture clusters adjacent to a bedding plane.

  13. Feasibility of a borehole VHF radar technique for fracture mapping

    SciTech Connect

    Chang, H.T.

    1984-01-01

    Experiments were conducted to establish the feasibility of a downhole high-frequency electromagnetic technique for location of fractures in the vicinity of boreholes. An existing flame-cut slot in granite was filled with salt water to simulate a brine-filled fracture. A transmitter consisting of a phased dual-dipole array arranged to provide a directional signal toward the fracture was installed in a borehole opposite the fracture. A receiver operated at 30 to 300 MHz was also located in the same borehole. The radar returns from the simulated fracture were detectable in boreholes located at distances of up to 12 meters from the fracture. These results indicate for the first time the feasibility of a downhole VHF radar for use in a single borehole for detection of fractures located away from the borehole.

  14. Modern Workflows for Fracture Rock Hydrogeology

    NASA Astrophysics Data System (ADS)

    Doe, T.

    2015-12-01

    Discrete Fracture Network (DFN) is a numerical simulation approach that represents a conducting fracture network using geologically realistic geometries and single-conductor hydraulic and transport properties. In terms of diffusion analogues, equivalent porous media derive from heat conduction in continuous media, while DFN simulation is more similar to electrical flow and diffusion in circuits with discrete pathways. DFN modeling grew out of pioneering work of David Snow in the late 1960s with additional impetus in the 1970's from the development of the development of stochastic approaches for describing of fracture geometric and hydrologic properties. Research in underground test facilities for radioactive waste disposal developed the necessary linkages between characterization technologies and simulation as well as bringing about a hybrid deterministic stochastic approach. Over the past 40 years DFN simulation and characterization methods have moved from the research environment into practical, commercial application. The key geologic, geophysical and hydrologic tools provide the required DFN inputs of conductive fracture intensity, orientation, and transmissivity. Flow logging either using downhole tool or by detailed packer testing identifies the locations of conducting features in boreholes, and image logging provides information on the geology and geometry of the conducting features. Multi-zone monitoring systems isolate the individual conductors, and with subsequent drilling and characterization perturbations help to recognize connectivity and compartmentalization in the fracture network. Tracer tests and core analysis provide critical information on the transport properties especially matrix diffusion unidentified conducting pathways. Well test analyses incorporating flow dimension boundary effects provide further constraint on the conducting geometry of the fracture network.

  15. Mechanics of Hydraulic Fractures

    NASA Astrophysics Data System (ADS)

    Detournay, Emmanuel

    2016-01-01

    Hydraulic fractures represent a particular class of tensile fractures that propagate in solid media under pre-existing compressive stresses as a result of internal pressurization by an injected viscous fluid. The main application of engineered hydraulic fractures is the stimulation of oil and gas wells to increase production. Several physical processes affect the propagation of these fractures, including the flow of viscous fluid, creation of solid surfaces, and leak-off of fracturing fluid. The interplay and the competition between these processes lead to multiple length scales and timescales in the system, which reveal the shifting influence of the far-field stress, viscous dissipation, fracture energy, and leak-off as the fracture propagates.

  16. Proton Conductivity of Nafion/Ex-Situ Sulfonic Acid-Modified Stöber Silica Nanocomposite Membranes As a Function of Temperature, Silica Particles Size and Surface Modification

    PubMed Central

    Muriithi, Beatrice; Loy, Douglas A.

    2016-01-01

    The introduction of sulfonic acid modified silica in Nafion nanocomposite membranes is a good method of improving the Nafion performance at high temperature and low relative humidity. Sulfonic acid-modified silica is bifunctional, with silica phase expected to offer an improvement in membranes hydration while sulfonic groups enhance proton conductivity. However, as discussed in this paper, this may not always be the case. Proton conductivity enhancement of Nafion nanocomposite membranes is very dependent on silica particle size, sometimes depending on experimental conditions, and by surface modification. In this study, Sulfonated Preconcentrated Nafion Stober Silica composites (SPNSS) were prepared by modification of Stober silica particles with mercaptopropyltriethoxysilane, dispersing the particles into a preconcentrated solution of Nafion, then casting the membranes. The mercapto groups were oxidized to sulfonic acids by heating the membranes in 10 wt % hydrogen peroxide for 1 h. At 80 °C and 100% relative humidity, a 20%–30% enhancement of proton conductivity was only observed when sulfonic acid modified particle less than 50 nm in diameter were used. At 120 °C, and 100% humidity, proton conductivity increased by 22%–42% with sulfonated particles with small particles showing the greatest enhancement. At 120 °C and 50% humidity, the sulfonated particles are less efficient at keeping the membranes hydrated, and the composites underperform Nafion and silica-Nafion nanocomposite membranes. PMID:26828525

  17. Proton Conductivity of Nafion/Ex-Situ Sulfonic Acid-Modified Stöber Silica Nanocomposite Membranes As a Function of Temperature, Silica Particles Size and Surface Modification.

    PubMed

    Muriithi, Beatrice; Loy, Douglas A

    2016-01-01

    The introduction of sulfonic acid modified silica in Nafion nanocomposite membranes is a good method of improving the Nafion performance at high temperature and low relative humidity. Sulfonic acid-modified silica is bifunctional, with silica phase expected to offer an improvement in membranes hydration while sulfonic groups enhance proton conductivity. However, as discussed in this paper, this may not always be the case. Proton conductivity enhancement of Nafion nanocomposite membranes is very dependent on silica particle size, sometimes depending on experimental conditions, and by surface modification. In this study, Sulfonated Preconcentrated Nafion Stober Silica composites (SPNSS) were prepared by modification of Stober silica particles with mercaptopropyltriethoxysilane, dispersing the particles into a preconcentrated solution of Nafion, then casting the membranes. The mercapto groups were oxidized to sulfonic acids by heating the membranes in 10 wt % hydrogen peroxide for 1 h. At 80 °C and 100% relative humidity, a 20%-30% enhancement of proton conductivity was only observed when sulfonic acid modified particle less than 50 nm in diameter were used. At 120 °C, and 100% humidity, proton conductivity increased by 22%-42% with sulfonated particles with small particles showing the greatest enhancement. At 120 °C and 50% humidity, the sulfonated particles are less efficient at keeping the membranes hydrated, and the composites underperform Nafion and silica-Nafion nanocomposite membranes. PMID:26828525

  18. Fractal Analysis of Permeability of Unsaturated Fractured Rocks

    PubMed Central

    Jiang, Guoping; Shi, Wei; Huang, Lili

    2013-01-01

    A physical conceptual model for water retention in fractured rocks is derived while taking into account the effect of pore size distribution and tortuosity of capillaries. The formula of calculating relative hydraulic conductivity of fractured rock is given based on fractal theory. It is an issue to choose an appropriate capillary pressure-saturation curve in the research of unsaturated fractured mass. The geometric pattern of the fracture bulk is described based on the fractal distribution of tortuosity. The resulting water content expression is then used to estimate the unsaturated hydraulic conductivity of the fractured medium based on the well-known model of Burdine. It is found that for large enough ranges of fracture apertures the new constitutive model converges to the empirical Brooks-Corey model. PMID:23690746

  19. Particle laden fluids in hydraulic fracturing

    NASA Astrophysics Data System (ADS)

    Lecampion, Brice

    2015-11-01

    The aim of hydraulic fracturing is to create a highly conductive pathway in the reservoir formation of interest. This is typically achieved by ``propping'' the created fracture with solid particles (i.e. proppant) in order to prevent complete closure of the created fracture due to in-situ stresses when pumping stops. The placement of proppant is therefore the main goal of any fracturing treatment. It involves a number of interesting fluid dynamics problem (suspensions flow with settling, complex rheologies of the base fluid, effect of the fracture roughness etc.). In this talk, we will review the different class of fluids used to achieve proppant placement in fracture particularly focusing on their widely varied rheological properties. We will also discuss the different flow regimes that are typically encountered during a hydraulic fracturing job. In particular, we will notably present in details how recent advances in our understanding of dense suspensions flow can improve predictions of proppant placement in the Stokesian regime. Second author: Dmtiry Garagash, Dalhousie University.

  20. A semi-analytical model for the flow behavior of naturally fractured formations with multi-scale fracture networks

    NASA Astrophysics Data System (ADS)

    Jia, Pin; Cheng, Linsong; Huang, Shijun; Wu, Yonghui

    2016-06-01

    This paper presents a semi-analytical model for the flow behavior of naturally fractured formations with multi-scale fracture networks. The model dynamically couples an analytical dual-porosity model with a numerical discrete fracture model. The small-scale fractures with the matrix are idealized as a dual-porosity continuum and an analytical flow solution is derived based on source functions in Laplace domain. The large-scale fractures are represented explicitly as the major fluid conduits and the flow is numerically modeled, also in Laplace domain. This approach allows us to include finer details of the fracture network characteristics while keeping the computational work manageable. For example, the large-scale fracture network may have complex geometry and varying conductivity, and the computations can be done at predetermined, discrete times, without any grids in the dual-porosity continuum. The validation of the semi-analytical model is demonstrated in comparison to the solution of ECLIPSE reservoir simulator. The simulation is fast, gridless and enables rapid model setup. On the basis of the model, we provide detailed analysis of the flow behavior of a horizontal production well in fractured reservoir with multi-scale fracture networks. The study has shown that the system may exhibit six flow regimes: large-scale fracture network linear flow, bilinear flow, small-scale fracture network linear flow, pseudosteady-state flow, interporosity flow and pseudoradial flow. During the first four flow periods, the large-scale fracture network behaves as if it only drains in the small-scale fracture network; that is, the effect of the matrix is negligibly small. The characteristics of the bilinear flow and the small-scale fracture network linear flow are predominantly determined by the dimensionless large-scale fracture conductivity. And low dimensionless fracture conductivity will generate large pressure drops in the large-scale fractures surrounding the wellbore. With

  1. Modeling of Interaction of Hydraulic Fractures in Complex Fracture Networks

    NASA Astrophysics Data System (ADS)

    Kresse, O. 2; Wu, R.; Weng, X.; Gu, H.; Cohen, C.

    2011-12-01

    A recently developed unconventional fracture model (UFM) is able to simulate complex fracture network propagation in a formation with pre-existing natural fractures. Multiple fracture branches can propagate at the same time and intersect/cross each other. Each open fracture exerts additional stresses on the surrounding rock and adjacent fractures, which is often referred to as "stress shadow" effect. The stress shadow can cause significant restriction of fracture width, leading to greater risk of proppant screenout. It can also alter the fracture propagation path and drastically affect fracture network patterns. It is hence critical to properly model the fracture interaction in a complex fracture model. A method for computing the stress shadow in a complex hydraulic fracture network is presented. The method is based on an enhanced 2D Displacement Discontinuity Method (DDM) with correction for finite fracture height. The computed stress field is compared to 3D numerical simulation in a few simple examples and shows the method provides a good approximation for the 3D fracture problem. This stress shadow calculation is incorporated in the UFM. The results for simple cases of two fractures are presented that show the fractures can either attract or expel each other depending on their initial relative positions, and compares favorably with an independent 2D non-planar hydraulic fracture model. Additional examples of both planar and complex fractures propagating from multiple perforation clusters are presented, showing that fracture interaction controls the fracture dimension and propagation pattern. In a formation with no or small stress anisotropy, fracture interaction can lead to dramatic divergence of the fractures as they tend to repel each other. However, when stress anisotropy is large, the fracture propagation direction is dominated by the stress field and fracture turning due to fracture interaction is limited. However, stress shadowing still has a strong effect

  2. Optimization of flow modeling in fractured media with discrete fracture network via percolation theory

    NASA Astrophysics Data System (ADS)

    Donado-Garzon, L. D.; Pardo, Y.

    2013-12-01

    Fractured media are very heterogeneous systems where occur complex physical and chemical processes to model. One of the possible approaches to conceptualize this type of massifs is the Discrete Fracture Network (DFN). Donado et al., modeled flow and transport in a granitic batholith based on this approach and found good fitting with hydraulic and tracer tests, but the computational cost was excessive due to a gigantic amount of elements to model. We present in this work a methodology based on percolation theory for reducing the number of elements and in consequence, to reduce the bandwidth of the conductance matrix and the execution time of each network. DFN poses as an excellent representation of all the set of fractures of the media, but not all the fractures of the media are part of the conductive network. Percolation theory is used to identify which nodes or fractures are not conductive, based on the occupation probability or percolation threshold. In a fractured system, connectivity determines the flow pattern in the fractured rock mass. This volume of fluid is driven through connection paths formed by the fractures, when the permeability of the rock is negligible compared to the fractures. In a population of distributed fractures, each of this that has no intersection with any connected fracture do not contribute to generate a flow field. This algorithm also permits us to erase these elements however they are water conducting and hence, refine even more the backbone of the network. We used 100 different generations of DFN that were optimized in this study using percolation theory. In each of the networks calibrate hydrodynamic parameters as hydraulic conductivity and specific storage coefficient, for each of the five families of fractures, yielding a total of 10 parameters to estimate, at each generation. Since the effects of the distribution of fault orientation changes the value of the percolation threshold, but not the universal laws of classical

  3. Characterizing Reactive Flow Paths in Fractured Cement

    NASA Astrophysics Data System (ADS)

    Wenning, Q. C.; Huerta, N. J.; Hesse, M. A.; Bryant, S. L.

    2011-12-01

    Geologic carbon sequestration can be a viable method for reducing anthropogenic CO2 flux into the atmosphere. However, the technology must be economically feasible and pose acceptable risk to stakeholders. One key risk is CO2 leakage out of the storage reservoir. Potential driving forces for leakage are the overpressure due to CO2 injection and the buoyancy of free phase CO2. Potential hazards of leakage are contamination of Underground Sources of Drinking Water or the atmosphere and would be deemed an unacceptable risk. Wells potentially provide a fast path for leakage from the reservoir. While the well's cement casing is reactive with CO2 and CO2-saturated brine, the low cement matrix permeability and slow diffusion rate make it unlikely that CO2 will escape through a properly constructed wellbore. However, highly permeable fractures with micrometer scale apertures can occur in cement casings. Reactions that occur in the flow in these fractures can either be self-limiting or self-enhancing. Therefore, understanding the reactive flow is critical to understanding of leakage evolution through these fractures. The goal of our work is to characterize the modification of the flow paths in the fracture due to reaction with acidic brine. With this aim we have characterized both the initial flow path of un-reactive flow and the final flow path after introduction of low-pH acid along the same fracture. Class H cement cores 3-6 cm in length and 2.5 cm diameter are created and a single natural and unique fracture is produced in each core using the Brazilian method. Our experimental fluid is injected at a constant rate into the cement core housed in a Hassler Cell under confining pressure. A solution of red dye and deionized water is pumped through the fracture to stain the un-reactive flow paths. Deionized water is then pumped through the core to limit diffusion of the dye into non-flowing portions of the fracture. After staining the initial flow path, low pH water due to

  4. Fracture corridors in carbonates

    NASA Astrophysics Data System (ADS)

    Chatelée, Sébastien; Lamarche, Juliette; Gauthier, Bertrand D. M.

    2015-04-01

    Among fractures, Fracture Corridors (FC) are anomalous structures made of highly persistent fracture clusters having a strong effect on multi-phase fluid flow in the subsurface. While mechanical and geological conditions for diffuse fracture systems are well constrained, FC genetic conditions remain a matter of questioning. FC can be localized in larger structures such as folds and fault zones but recent studies suggest that a large amount of fractures and FC also arise as distributed in the host rock and formed in tabular layers during burial with early rock mechanical differentiation. In addition, while the mechanical stratigraphy is of prime importance for fracture stratigraphy, it is still unknown which factor prevails on FC genesis among the local versus regional stress-state, the host rock mechanical stratigraphy or the sedimentary facies. We present a study of fractures in a 400×300 m wide quarry (Calvisson, SE France) dug in homogeneous marly limestones of Hauterivian age. The quarry exhibits diffuse fractures as well as 16 FC. The aim of this study is to reveal the genetics factor for FC development, their global geometry and internal morphologic variations, but also to clear the impact of fracture corridors on diffuse fracture. For that, we measured >2500 fractures (strike, dip, spacing, filling, aperture, etc.) and studied microstructures in 80 thin sections. We calculated fracture density and acquired LiDAR data with >90 million points with a resolution of 4 to 15mm. Diffuse fractures are organized as two perpendicular sets, a main set NE-SW-trending and minor set NW-SE-trending. The FC have the same trend, but the NW-SE trend prevail on the NE-SW one. The LiDAR acquisition allows to visualize the 3D lateral continuity with corridors with a minimal extension of 30m. We distinguish 4 internal morphologic types in FC, depending on fracture morphology, occurrence of breccia and number of zones. The types may occur in a single FC with a lateral transition

  5. Cryogenic Fracturing: Laboratory Visualization Experiments and Numerical Simulations Using Peridynamics

    NASA Astrophysics Data System (ADS)

    Martin-Short, R.; Edmiston, J. K.

    2015-12-01

    Typical hydraulic fracturing operations involve the use of a large quantity of water, which can be problematic for several reasons including possible formation (permeability) damage, disposal of waste water, and the use of precious local water resource. An alternate reservoir permeability enhancing technology not requiring water is cryogenic fracturing. This method induces controlled fracturing of rock formations by thermal shock and has potentially important applications in the geothermal and hydrocarbon industries. In this process, cryogenic fluid—such as liquid nitrogen—is injected into the subsurface, causing fracturing due to thermal gradients. These fractures may improve the formation permeability relative to that achievable by hydraulic fracturing alone. We conducted combined laboratory visualization and numerical simulations studies of thermal-shock-induced fracture initiation and propagation resulting from liquid nitrogen injection in rock and analog materials. The experiment used transparent soda-lime glass cubes to facilitate real-time visualization of fracture growth and the fracture network geometry. In this contribution, we report the effect of overall temperature difference between cryogenic fluid and solid material on the produced fracture network, by pre-heating the glass cubes to several temperatures and injecting liquid nitrogen. Temperatures are monitored at several points by thermocouple and the fracture evolution is captured visually by camera. The experiment was modeled using a customized, thermoelastic, fracture-capable numerical simulation code based on peridynamics. The performance of the numerical code was validated by the results of the laboratory experiments, and then the code was used to study the different factors affecting a cryogenic fracturing operation, including the evolution of residual stresses and constitutive relationships for material failure. In complex rock such as shale, understanding the process of cryogenic

  6. Numerical Simulation Study on the Hydraulic Behavior in Closed Fractures

    NASA Astrophysics Data System (ADS)

    Zhang, C.; Shu, L.; Wen, Z.; Wu, G.; Zhang, X.; Hu, B. X.

    2015-12-01

    As the main repositories for groundwater in karst systems, fractures involve the movement and storage of groundwater. Fundamentally, Navier-Stokes (NS) Equations is used to describe flow in fractures. However, due to the complexity of Navier-Stokes Equations, it is rarely applied to solve fracture flow problems. Thus, based on some simplifications, Stokes equations, Reynolds equations and Cubic Law (CL) are derived to describe fracture flow. The validity of the three simplified equations were extensively studies. Among the three simplified equations of NS, CL is the simplest and used to describe flow in open, smooth and paralleled fractures. In the previous work, most researchers focused on the open fractures. But it's the closed fractures exist widely in the field not the open fractures. The objective of this paper aims to check the validity of CL in closed fractures with different apertures and widths of fracture. After comparing the experimental results and simulations results from the COMSOL Multiphysics (FEM), this software was applied to solve the 3D or 2D NS equations in the closed fractures. The results obtained from NS simulation results and calculation results from CL were compared to indicate the degree of the validity of CL in application. A critical velocity was proposed to illustrate the validity of CL in closed fractures. Furthermore, the impacts of aperture size, width of fracture size, and velocity magnitude on both the hydraulic conductivity and velocity profile were also analyzed. The results showed the CL was capable of describing flow in closed fractures when the velocity was less than the critical velocity varying from 0.02 to 30.08cm/s. The ratio of NS results and CL results was between 0.9 and 2, with velocity varying from 0 to 40cm/s. The discrepancy between NS equation and CL increased with Reynolds number, increased with aperture size and decreased with width of fracture.

  7. Stress fractures in athletes.

    PubMed

    Hulkko, A; Orava, S

    1987-06-01

    During the 14-year period of 1971-1985, 368 stress fractures in 324 athletes were treated. The series contained 268 fractures in males and 100 fractures in females; 32 fractures occurred in children (less than 16 years), 117 in adolescents (16-19 years), and 219 in adults. Forty-six fractures were incurred by athletes at an international level, 274 by athletes at a national or district level and 48 by recreational athletes. Of the total cases, 72% occurred to runners and a further 12% to athletes in other sports after running exercises. The distribution of the stress fractures by site was: tibia 182, metatarsal bones 73, fibula 44, big toe sesamoid bones 15, femoral shaft 14, femoral neck 9, tarsal navicular 9, pelvis 7, olecranon 5 and other bones 10. Of the total fractures, 342 were treated conservatively and 26 fractures required surgical treatment. The operative indication was dislocation in 5 cases and delayed union/nonunion in 21 cases. The sites most often affected by delayed union were: anterior midtibia, sesamoid bones of the big toe, base of the fifth metatarsal, olecranon, and tarsal navicular. The athletes at an international level experienced the greatest risk of multiple separate fractures, protracted healing, or fractures requiring surgery. PMID:3623785

  8. A Hierarchical Approach to Fracture Mechanics

    NASA Technical Reports Server (NTRS)

    Saether, Erik; Taasan, Shlomo

    2004-01-01

    Recent research conducted under NASA LaRC's Creativity and Innovation Program has led to the development of an initial approach for a hierarchical fracture mechanics. This methodology unites failure mechanisms occurring at different length scales and provides a framework for a physics-based theory of fracture. At the nanoscale, parametric molecular dynamic simulations are used to compute the energy associated with atomic level failure mechanisms. This information is used in a mesoscale percolation model of defect coalescence to obtain statistics of fracture paths and energies through Monte Carlo simulations. The mathematical structure of predicted crack paths is described using concepts of fractal geometry. The non-integer fractal dimension relates geometric and energy measures between meso- and macroscales. For illustration, a fractal-based continuum strain energy release rate is derived for inter- and transgranular fracture in polycrystalline metals.

  9. Denosumab for the prevention of osteoporotic fractures in post-menopausal women: a NICE single technology appraisal.

    PubMed

    Scotland, Graham; Waugh, Norman; Royle, Pamela; McNamee, Paul; Henderson, Rob; Hollick, Rosemary

    2011-11-01

    costs. Utility weights were used to adjust time spent in fracture states, allowing QALYs to be estimated. The base-case analysis was conducted for women aged 70 years with a T-score of -2.5 or less and no prior fracture, and women aged 70 years with a T-score of -2.5 or less with a prior fragility fracture. Subgroup analyses based on T-score and independent clinical risk factors were also undertaken. Applying a willingness-to-pay (WTP) threshold of £30 000 per QALY, the manufacturer's results suggested that denosumab would offer a cost-effective alternative to all treatment comparators for the primary and secondary prevention of fractures. The ERG was concerned about an assumption that denosumab would be administered in general practice at the average cost of two standard GP visits a year. As a result, the ERG requested some further sensitivity analysis and undertook some further modelling, applying an assumption that denosumab would be provided primarily in secondary care. This modification altered the cost effectiveness of denosumab versus 'no treatment' (in women with no prior fragility fracture) and zoledronic acid. The NICE Appraisal Committee concluded that, as a treatment option for the prevention of osteoporotic fractures, denosumab should be recommended only in post-menopausal women at increased risk of fracture who cannot comply with the special instructions for administering oral bisphosphonates, or have an intolerance of, or contraindication to, those treatments. For primary prevention, the Appraisal Committee also stipulated specific levels of fracture risk at which denosumab is recommended. PMID:21854080

  10. Bifocal mandibular fractures: which should be treated first?

    PubMed

    Dell' Aversana Orabona, Giovanni; Iaconetta, Giorgio; Abbate, Vincenzo; Califano, Luigi

    2012-11-01

    Fractures of the mandible have been reported to account between 40% and 62% of all facial fractures. Most surveys show that just under 50% are isolated, the same amount are doubly fractured. This study aims to clarify, according to our experience, the correct surgical sequence which should be followed in order to treat bifocal mandibular fractures. From January 2004 to January 2009, we have conducted a retrospective study on a sample of patients operated on in our department because of bifocal mandibular fractures. We include only those cases in which the jaw was fractured in 2 places, in particular patients who suffer a fracture in tooth-bearing areas (symphysis, parasymphysis, and anterior body) and also contralaterally in non-tooth-bearing areas (posterior body, angle, ramus, and condyle). The sample was divided into 2 groups based on the fracture sequence of reduction. At 1-year follow-up, the group of patients who received first the tooth-bearing fractured areas treatment, followed by treatment of non-tooth-bearing fractured area on bifocal mandibular fracture, showed less postoperative complications and reduced surgical time and costs. It is recommended from this study that reduction of the tooth-bearing fragment be prior to that of the tooth-free fragment for the bifocal mandible. PMID:23147333

  11. Two-Dimensional Heat Transfer in a Heterogeneous Fracture Network

    NASA Astrophysics Data System (ADS)

    Gisladottir, V. R.; Roubinet, D.; Tartakovsky, D. M.

    2015-12-01

    Geothermal energy harvesting requires extraction and injection of geothermal fluid. Doing so in an optimal way requires a quantitative understanding of site-specific heat transfer between geothermal fluid and the ambient rock. We develop a heat transfer particle-tracking approach to model that interaction. Fracture-network models of heat transfer in fractured rock explicitly account for the presence of individual fractures, ambient rock matrix, and fracture-matrix interfaces. Computational domains of such models span the meter scale, whereas fracture apertures are on the millimeter scale. The computations needed to model these multi-scale phenomenon can be prohibitively expensive, even for methods using nonuniform meshes. Our approach appreciably decreases the computational costs. Current particle-tracking methods usually assume both infinite matrix and one-dimensional (1D) heat transfer in the matrix blocks. They rely on 1D analytical solutions for heat transfer in a single fracture, which can lead to large predictive errors. Our two-dimensional (2D) heat transfer simulation algorithm is mesh-free and takes into account both longitudinal and transversal heat conduction in the matrix. It uses a probabilistic model to transfer particle to the appropriate neighboring fracture unless it returns to the fracture of origin or remains in the matrix. We use this approach to look at the impact of a fracture-network topology (e.g. the importance of smaller scale fractures), as well as the matrix block distribution on the heat transport in heterogeneous fractured rocks.

  12. Comments on the paper: 'Optical reflectance, optical refractive index and optical conductivity measurements of nonlinear optics for L-aspartic acid nickel chloride single crystal'

    NASA Astrophysics Data System (ADS)

    Srinivasan, Bikshandarkoil R.; Naik, Suvidha G.; Dhavskar, Kiran T.

    2016-02-01

    We argue that the 'L-aspartic acid nickel chloride' crystal reported by the authors of the title paper (Optics Communications, 291 (2013) 304-308) is actually the well-known diaqua(L-aspartato)nickel(II) hydrate crystal.

  13. Streaming potential modeling in fractured rock: Insights into the identification of hydraulically active fractures

    NASA Astrophysics Data System (ADS)

    Roubinet, D.; Linde, N.; Jougnot, D.; Irving, J.

    2016-05-01

    Numerous field experiments suggest that the self-potential (SP) geophysical method may allow for the detection of hydraulically active fractures and provide information about fracture properties. However, a lack of suitable numerical tools for modeling streaming potentials in fractured media prevents quantitative interpretation and limits our understanding of how the SP method can be used in this regard. To address this issue, we present a highly efficient two-dimensional discrete-dual-porosity approach for solving the fluid flow and associated self-potential problems in fractured rock. Our approach is specifically designed for complex fracture networks that cannot be investigated using standard numerical methods. We then simulate SP signals associated with pumping conditions for a number of examples to show that (i) accounting for matrix fluid flow is essential for accurate SP modeling and (ii) the sensitivity of SP to hydraulically active fractures is intimately linked with fracture-matrix fluid interactions. This implies that fractures associated with strong SP amplitudes are likely to be hydraulically conductive, attracting fluid flow from the surrounding matrix.

  14. Field fracturing multi-sites project. Annual report, August 1, 1995--July 31, 1996

    SciTech Connect

    1996-12-31

    The objective of the Field Fracturing Multi-Sites Project (M-Site) is to conduct experiments to definitively determine hydraulic fracture dimensions using remote well and treatment well diagnostic techniques. In addition, experiments are to be conducted to provide data that will resolve significant unknowns with regard to hydraulic fracture modeling, fracture fluid rheology and fracture treatment design. These experiments will be supported by a well-characterized subsurface environment, as well as surface facilities and equipment conducive to acquiring high-quality data. The primary Project goal is to develop a fully characterized, tight reservoir-typical, field-scale hydraulic fracturing test site to diagnose, characterize, and test hydraulic fracturing technology and performance. It is anticipated that the research work being conducted by the multi-disciplinary team of GRI and DOE contractors will lead to the development of a commercial fracture mapping tool/service.

  15. The influence of naturally-occurring organic acids on model estimates of lakewater acidification using the model of acidification of groundwater in catchments (MAGIC). Summary of research conducted during year 1

    SciTech Connect

    Sullivan, T.J.; Eilers, J.M.; Cosby, B.J.; Driscoll, C.T.; Hemond, H.F.; Charles, D.F.; Norton, S.A.

    1993-03-05

    A project for the US Department of Energy, entitled ``Incorporation of an organic acid representation into MAGIC (Model of Acidification of Groundwater in Catchments) and Testing of the Revised Model UsingIndependent Data Sources`` was initiated by E&S Environmental Chemistry, Inc. in March, 1992. Major components of the project include: improving the MAGIC model by incorporating a rigorous organic acid representation, based on empirical data and geochemical considerations, and testing the revised model using data from paleolimnological hindcasts of preindustrial chemistry for 33 Adirondack Mountain lakes, and the results of whole-catchment artificial acidification projects in Maine and Norway. The ongoing research in this project involves development of an organic acid representation to be incorporated into the MAGIC modeland testing of the improved model using three independent data sources. The research during Year 1 has included conducting two workshops to agree on an approach for the organic acid modeling, developing the organic subroutine and incorporating it into MAGIC (Task 1), conducing MAGIC hindcasts for Adirondack lakes and comparing the results with paleolimnological reconstructions (Task 2), and conducting site visits to the manipulation project sites in Maine and Norway. The purpose of this report is to provide a summary of the work that has been conducted on this project during Year 1. Tasks 1 and 2 have now been completed.

  16. The exploration of making acidproof fracturing proppants using red mud.

    PubMed

    Tian, Xiaorang; Wu, Bolin; Li, Jian

    2008-12-30

    In this study, the exploration of making acidproof fracturing proppants using red mud was carried out. The main raw materials are red mud and the refractory waste. During the exploration, three methods were explored to enhance the acid resistance of the samples of the fracturing proppants. Eventually, fracturing proppants with good acid resistance were produced using red mud, the refractory waste, barium carbonate and plasticizer. The acid solubility of the samples of the acidproof fracturing proppants was less than 4.5% which reached the demands of The Petroleum and Gas Industrial Standards of China (SY/T5108-2006). The results show that adding barium carbonate to the raw materials can decrease the acid solubility of the samples effectively. The main reason is the monoclinic celsian-BaAl2Si2O8 formed in sintering process which can protect the other compositions of the acidproof fracturing proppants to prevent them from erosion by acid. The exploration shows that it is probable to produce fracturing proppants with good acid resistance using red mud. PMID:18434003

  17. [Comparative biological value of the proteins comprising the products for the tube and regular feeding of patients with mandibular fractures].

    PubMed

    Kholodov, S V; Vitollo, A S; Kalamkarova, O M; Rud'ko, V F; Vysotskiĭ, V G

    1988-01-01

    A comparative clinical evaluation was made of the biological effectiveness of protein components in the composition of three types of diet for patients with fractures of the mandible who had received "Ensure" (USA), a product for complete tube feeding; an experimental sample developed at the Institute of Nutrition, Academy of Medical Sciences of the USSR; and a routine clinical diet. The biological effectiveness of the proteins was estimated by some anthropometric and biochemical parameters as well as on the basis of nitrogenous metabolism in the patients. It has been established that the protein content in the routine clinical diets does not meet the high requirements in amino acids of patients with fracture of the mandible. In this respect the products for tube and dietotherapy have proved to be effective and completely provide the need of such patients in essential amino acids that has been evidenced by the results of the investigations conducted. PMID:3146160

  18. [Trochanteric femoral fractures].

    PubMed

    Douša, P; Čech, O; Weissinger, M; Džupa, V

    2013-01-01

    At the present time proximal femoral fractures account for 30% of all fractures referred to hospitals for treatment. Our population is ageing, the proportion of patients with post-menopausal or senile osteoporosis is increasing and therefore the number of proximal femoral fractures requiring urgent treatment is growing too. In the age category of 50 years and older, the incidence of these fractures has increased exponentially. Our department serves as a trauma centre for half of Prague and part of the Central Bohemia Region with a population of 1 150 000. Prague in particular has a high number of elderly citizens. Our experience is based on extensive clinical data obtained from the Register of Proximal Femoral Fractures established in 1997. During 14 years, 4280 patients, 3112 women and 1168 men, were admitted to our department for treatment of proximal femoral fractures. All patients were followed up until healing or development of complications. In the group under study, 82% were patients older than 70 years; 72% of those requiring surgery were in their seventies and eighties. Men were significantly younger than women (p<0.001) and represented 30% of the group. The fractures were 2.3-times more frequent in women than in men. In the category under 60 years, men significantly outnumbered women (p<0.001). The patients with pertrochanteric fractures were, on the average, eight years older than the patients with intertrochanteric fractures, which is a significant difference (p<0.001). The mortality rate within a year of injury was about 30%. Trochanteric fractures accounted for 54.7% and femoral neck fractures for 45.3% of all fractures. The inter-annual increase was 5.9%, with more trochanteric than femoral neck fractures. There was a non-significant decrease in intertrochanteric (AO 31-A3) fractures. On the other hand, the number of pertrochanteric (AO 31-A1+2) fractures increased significantly (p<0.001). A total of 1 394 fractures were treated with a proximal

  19. Growth, children, and fractures.

    PubMed

    Jones, Graeme

    2004-09-01

    Fractures in childhood have long been considered an unavoidable consequence of growth. Studies in recent years have documented the epidemiology of these very common fractures and have also documented considerable variation by fracture type and from country to country. There have also been a number of studies aimed at identifying risk factors particularly for the most common distal forearm fracture. These studies have consistently associated bone mineral density with these fractures. Other possible risk factors include obesity, physical inactivity, sports, cola beverages, calcium intake, risk taking, and coordination. While prospective studies are required to confirm these risk factors, accumulating evidence now suggests that a substantial proportion of fractures in children are preventable. PMID:16036086

  20. Remote sensing of subsurface fractures in the Otway Basin, South Australia

    NASA Astrophysics Data System (ADS)

    Bailey, Adam; King, Rosalind; Holford, Simon; Sage, Joshua; Backe, Guillaume; Hand, Martin

    2014-08-01

    Naturally occurring fractures were remotely detected in a 3-D seismic volume from the Penola Trough in South Australia's Otway Basin and validated through an integrated approach. Identified in image logs are 508 fractures and 523 stress indicators, showing maximum horizontal stress orientation in the Penola Trough is 127°N. Two fracture types were identified: (1) 268 electrically conductive (potentially open to fluid flow) fractures with mean NW-SE strikes and (2) 239 electrically resistive (closed to fluid flow) fractures with mean E-W strikes. Core from Jacaranda Ridge-1 shows that open fractures are rarer than what image logs indicate, due to the presence of fracture-filling siderite, an electrically conductive cement which may cause fractures to appear hydraulically conductive in image logs. The majority of fractures detected is favorably oriented for reactivation under in situ stresses, although it is demonstrated that fracture fills primarily control which fractures are open. Seismic attributes calculated from the 3-D Balnaves/Haselgrove survey are mapped to the Pretty Hill Formation to enhance observations of structural fabrics, showing linear discontinuities likely representing faults and fractures. Discontinuity orientations are consistent with natural fracture orientations identified in image logs, striking E-W and NW-SE, limited to zones around larger faults. However, it is unlikely that a large proportion of these fractures are open given observations of core and image logs, limiting possible fracture connectivity and therefore significant secondary permeability in the Penola Trough. The integrated methodology presented herein provides an effective workflow for remote detection of subsurface fractures and determining if electrically conductive fractures are also hydraulically conductive.

  1. Investigation of post hydraulic fracturing well cleanup physics in the Cana Woodford Shale

    NASA Astrophysics Data System (ADS)

    Lu, Rong

    Hydraulic fracturing was first carried out in the 1940s and has gained popularity in current development of unconventional resources. Flowing back the fracturing fluids is critical to a frac job, and determining well cleanup characteristics using the flowback data can help improve frac design. It has become increasingly important as a result of the unique flowback profiles observed in some shale gas plays due to the unconventional formation characteristics. Computer simulation is an efficient and effective way to tackle the problem. History matching can help reveal some mechanisms existent in the cleanup process. The Fracturing, Acidizing, Stimulation Technology (FAST) Consortium at Colorado School of Mines previously developed a numerical model for investigating the hydraulic fracturing process, cleanup, and relevant physics. It is a three-dimensional, gas-water, coupled fracture propagation-fluid flow simulator, which has the capability to handle commonly present damage mechanisms. The overall goal of this research effort is to validate the model on real data and to investigate the dominant physics in well cleanup for the Cana Field, which produces from the Woodford Shale in Oklahoma. To achieve this goal, first the early time delayed gas production was explained and modeled, and a simulation framework was established that included all three relevant damage mechanisms for a slickwater fractured well. Next, a series of sensitivity analysis of well cleanup to major reservoir, fracture, and operational variables was conducted; five of the Cana wells' initial flowback data were history matched, specifically the first thirty days' gas and water producing rates. Reservoir matrix permeability, net pressure, Young's modulus, and formation pressure gradient were found to have an impact on the gas producing curve's shape, in different ways. Some moderately good matches were achieved, with the outcome of some unknown reservoir information being proposed using the

  2. Fracture tooth fragment reattachment

    PubMed Central

    Maitin, Nitin; Maitin, Shipra Nangalia; Rastogi, Khushboo; Bhushan, Rajarshi

    2013-01-01

    Coronal fractures of the anterior teeth are a common form of dental trauma and its sequelae may impair the establishment and accomplishment of an adequate treatment plan. Among the various treatment options, reattachment of a crown fragment is a conservative treatment that should be considered for crown fractures of anterior teeth. This clinical case reports the management of two coronal tooth fracture cases that were successfully treated using tooth fragment reattachment using glass-fibre-reinforced composite post. PMID:23853012

  3. Prevention and treatment of senile osteoporosis and hip fractures.

    PubMed

    Duque, G; Demontiero, O; Troen, B R

    2009-02-01

    Osteoporosis is a major health issue worldwide, with significant economic consequences and adverse impacts on the quality of life. Hip fractures are the most devastating complication of osteoporosis, are likely to increase exponentially with an increasingly aged population, are associated with high recurrence rate, and lead to significant morbidity and mortality. This review discusses the prevalence and impact of hip fractures, the assessment of fracture risk, fall prevention, and treatment of osteoporosis with emphasis on evidence for hip fracture reduction among the various agents currently available. The aim is to provide recommendations to optimize hip fracture prevention and treatment. Ample evidence exists in the literature of many other risk factors independent from bone mineral density that increase fracture risk. These clinical risk factors have been validated in large cohorts and are incorporated into clinical tools that are invaluable in treatment decisions. In addition, strategies to prevent or reduce falls are integral to comprehensive osteoporosis management. Vitamin D combined with calcium has a role in primary prevention. Alendronate, residronate, strontium and zoledronic acid have proven efficacy in primary and secondary hip fracture prevention. An aggressive approach to investigate, assess and manage an individual's fracture risk and fall risk is paramount to reduce the high morbidity and mortality associated with hip fractures. The choice of therapy should be determined by the patient's calculated fracture risk and efficacy of the potential treatment, including long term compliance associated with the agent of choice. PMID:19277006

  4. Electrical Conductivity.

    ERIC Educational Resources Information Center

    Allen, Philip B.

    1979-01-01

    Examines Drude's classical (1900) theory of electrical conduction, details the objections to and successes of the 1900 theory, and investigates the Quantum (1928) theory of conduction, reviewing its successes and limitations. (BT)

  5. Pathological fractures in children

    PubMed Central

    De Mattos, C. B. R.; Binitie, O.; Dormans, J. P.

    2012-01-01

    Pathological fractures in children can occur as a result of a variety of conditions, ranging from metabolic diseases and infection to tumours. Fractures through benign and malignant bone tumours should be recognised and managed appropriately by the treating orthopaedic surgeon. The most common benign bone tumours that cause pathological fractures in children are unicameral bone cysts, aneurysmal bone cysts, non-ossifying fibromas and fibrous dysplasia. Although pathological fractures through a primary bone malignancy are rare, these should be recognised quickly in order to achieve better outcomes. A thorough history, physical examination and review of plain radiographs are crucial to determine the cause and guide treatment. In most benign cases the fracture will heal and the lesion can be addressed at the time of the fracture, or after the fracture is healed. A step-wise and multidisciplinary approach is necessary in caring for paediatric patients with malignancies. Pathological fractures do not have to be treated by amputation; these fractures can heal and limb salvage can be performed when indicated. PMID:23610658

  6. Fracture detection logging tool

    DOEpatents

    Benzing, William M.

    1992-06-09

    A method and apparatus by which fractured rock formations are identified and their orientation may be determined includes two orthogonal motion sensors which are used in conjunction with a downhole orbital vibrator. The downhole vibrator includes a device for orienting the sensors. The output of the sensors is displayed as a lissajou figure. The shape of the figure changes when a subsurface fracture is encountered in the borehole. The apparatus and method identifies fractures rock formations and enables the azimuthal orientation of the fractures to be determined.

  7. Capitellar and Trochlear Fractures.

    PubMed

    Carroll, Michael J; Athwal, George S; King, Graham J W; Faber, Kenneth J

    2015-11-01

    Fractures of the capitellum and trochlea account for a small proportion of elbow trauma. Clinicians need to be vigilant in their assessment as they are commonly associated with other injuries about the elbow. To optimize outcomes, the goals of management include a stable, anatomic reduction and early range of motion. Closed reduction of noncomminuted fractures may be successful but requires close follow-up. Open reduction and internal fixation is the preferred management of displaced capitellum-trochlear fractures. Elbow stiffness is the most commonly reported complication in operatively treated fractures. Arthroscopic-assisted reduction and internal fixation and arthroplasty are evolving management options. PMID:26498550

  8. Triaxial coreflood study of the hydraulic fracturing of Utica Shale

    NASA Astrophysics Data System (ADS)

    Carey, J. W.; Frash, L.; Viswanathan, H. S.

    2015-12-01

    One of the central questions in unconventional oil and gas production research is the cause of limited recovery of hydrocarbon. There are many hypotheses including: 1) inadequate penetration of fractures within the stimulated volume; 2) limited proppant delivery; 3) multiphase flow phenomena that blocks hydrocarbon migration; etc. Underlying any solution to this problem must be an understanding of the hydrologic properties of hydraulically fractured shale. In this study, we conduct triaxial coreflood experiments using a gasket sealing mechanism to characterize hydraulic fracture development and permeability of Utica Shale samples. Our approach also includes fracture propagation with proppants. The triaxial coreflood experiments were conducted with an integrated x-ray tomography system that allows direct observation of fracture development using x-ray video radiography and x-ray computed tomography at elevated pressure. A semi-circular, fracture initiation notch was cut into an end-face of the cylindrical samples (1"-diameter with lengths from 0.375 to 1"). The notch was aligned parallel with the x-ray beam to allow video radiography of fracture growth as a function of injection pressure. The proppants included tungsten powder that provided good x-ray contrast for tracing proppant delivery and distribution within the fracture system. Fractures were propagated at injection pressures in excess of the confining pressure and permeability measurements were made in samples where the fractures propagated through the length of the sample, ideally without penetrating the sample sides. Following fracture development, permeability was characterized as a function of hydrostatic pressure and injection pressure. X-ray video radioadiography was used to study changes in fracture aperture in relation to permeability and proppant embedment. X-ray tomography was collected at steady-state conditions to fully characterize fracture geometry and proppant distribution.

  9. Long term infiltration and tracer transport in fractured rocks: Field observations and model analyses

    NASA Astrophysics Data System (ADS)

    Lu, Guoping; Liu, Hui-Hai; Salve, Rohit

    2011-01-01

    SummaryThis paper presents modeling analyses of long term infiltration and tracer tests in fractured tuffs at Yucca Mountain, NV, USA. The experiments were conducted on a 20 m thick tuff section in a flyover formed by two exploratory tunnels. The infiltration test last for 870 days. Both measured infiltration and seepage show significant temporal and spatial variations. The tracer test used inorganic tracers (I -, Br -, F -) and organic tracers (fluorobenzoic acids) released 559 days after the infiltration test started. Leaching from dry salts from fracture walls was found to have affected tracer breakthroughs. The unsaturated flow was evaluated by optimizing 45 parameter values in a three-dimensional model, which accounts for fracture-matrix interaction and heterogeneous hydraulic properties in a column-based scheme. The field data are valuable asset to evaluate the modeling approaches for fractured rocks and the relative importance of the matrix diffusion process. Results show that matrix diffusion is an important process for transport, and that effective matrix-diffusion coefficients at the field-scale are larger than those at the laboratory-scale for the solutes.

  10. Pterygoid Plate Fractures: Not Limited to Le Fort Fractures.

    PubMed

    Garg, Ravi K; Alsheik, Nila H; Afifi, Ahmed M; Gentry, Lindell R

    2015-09-01

    Pterygoid plate fractures are often described in the setting of Le Fort fractures. The goal of this study was to define other craniofacial fracture patterns causing injury to the pterygoid plates. A retrospective review of computed tomography (CT) scans obtained on craniofacial trauma patients over a 5-year period revealed 209 patients with pterygoid plate fractures. Pterygoid plate fractures in 78 patients (37.3%) were unrelated to Le Fort fractures. Common causes included sphenotemporal buttress fractures in 26 patients (33.3%), temporal bone fractures in 18 patients (23.1%), zygomaticomaxillary complex fractures in 17 patients (21.8%), and displaced mandible fractures in 14 patients (17.9%). These findings indicate that approximately one third of pterygoid plate fractures do not result from Le Fort pattern injuries and that the craniofacial surgeon should have a broad differential for causes of pterygoid plate fractures when reviewing trauma imaging. PMID:26147022

  11. Influence of piezometer construction on groundwater sampling in fractured rock.

    PubMed

    Kozuskanich, J; Novakowski, K S; Anderson, B C

    2012-01-01

    A numerical model for groundwater flow and solute transport was employed to examine the influence of the screen and sandpack on the collection of a representative geochemical sample from a piezometer monitoring well installation in a discretely fractured bedrock aquifer. The optimization of screen and sandpack combinations was explored for the potential to reduce purging times and volumes in practice. Simulations accounted for the location of the fractures along the well screen, fracture aperture, screen length, and the pumping rate. The variability in the required purging times (t(99)-the time required to achieve 99% fractional contribution from the formation to pump discharge) can be explained by: (1) the relative hydraulic conductivities of the components of the system (fracture, sandpack, and screen), (2) the truncation of the flow field from the fracture to the screen by the upper and/or lower boundary of the sandpack of the flow field from another fracture, and (3) time-dependent drawdown. During pumping, only a portion of the sandpack may actually become hydraulically active. The optimal configuration (shortest purging time) is achieved when the ratios of the screen, sandpack, and fracture hydraulic conductivities are close to 1:1:1. More importantly, the role of the fracture hydraulic conductivity in the ratios is not as crucial to reducing t(99) as having the hydraulic conductivities of the screen and sandpack as similar as possible. This study provides a better understanding of well dynamics during pumping for the purpose of obtaining representative groundwater samples. PMID:21797851

  12. Proton-conducting membrane based on epoxy resin-poly(vinyl alcohol)-sulfosuccinic acid blend and its nanocomposite with sulfonated multiwall carbon nanotubes for fuel-cell application

    NASA Astrophysics Data System (ADS)

    Kakati, Nitul; Das, Gautam; Yoon, Young Soo

    2016-01-01

    A blend of poly(vinyl alcohol) (PVA) with diglycidyl ether of bisphenol-A (DGB) in the presence of sulfosuccinic acid (SSA) was investigated as hydrolytically-stable proton-conducting membrane. The PVA modification was carried out by varying the DGB:SSA ratio (20:20, 10:20, and 5:20). A nanocomposite of the blend (20:20) was prepared with sulfonated multiwall carbon nanotubes (viz., 1, 3 and 5 wt%). The water uptake behavior and the proton conductivity of the prepared membranes were evaluated. The ionic conductivity of the membranes and the water uptake behavior depended on the s-MWCNT and the DGB contents. The ionic conductivity showed an enhancement for the blend and for the nanocomposite membrane as compared to the pristine polymer.

  13. Gaseous detonation-driven fracture of tubes

    NASA Astrophysics Data System (ADS)

    Chao, Tong Wa

    load. Both non-fracturing linear elastic simulations and elastoplastic simulations with fracture were conducted on three-dimensional models. The simulated fracture was compared directly with an experiment with the same conditions. The overall qualitative fracture behavior was captured by the simulation. The forward and backward cracks were observed to branch in both the experiment and simulation.

  14. First European Report of Social Wasps Trapped in Response to Acetic acid, Isobutanol, 2-Methyl-2-propanol, and Heptyl butyrate in Tests Conducted in Hungary

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Five species of social wasps were captured in trapping tests in Hungary that evaluated the attractiveness of acetic acid, isobutanol, 2-methyl-2-propanol, and heptyl butyrate to social wasps. Both Vespula vulgaris (L.) and Vespula germanica (Fabr.), were captured in traps baited with isobutanol, t...

  15. Radionuclide transport in fractured granite interface zones

    NASA Astrophysics Data System (ADS)

    Hu, Q. H.; Möri, A.

    In situ radionuclide migration experiments, followed by excavation and sample characterization, were conducted in a water-conducting shear zone at the Grimsel Test Site (GTS) in Switzerland to study migration paths of radionuclides in fractured granite. In this work, a micro-scale mapping technique was applied by interfacing laser ablation sampling with inductively coupled plasma-mass spectrometry (LA-ICP-MS) to detect the small scale (micron-range) distribution of actinides in the interface zones between fractures and the granitic rock matrix. Long-lived 234U, 235U, and 237Np were detected in flow channels, as well as in the diffusion accessible rock matrix, using the sensitive, feature-based mapping of the LA-ICP-MS technique. The retarded actinides are mainly located at the fracture walls and in the fine grained fracture filling material as well as within the immediately adjacent wallrock. The water-conducting fracture studied in this work is bounded on one side by mylonite and the other by granitic matrix regions. Actinides studied in this work did not penetrate into the mylonite side as much as into the granite matrix, most likely due to the lower porosity, the enhanced sorption capacity and the disturbed diffusion paths of the mylonite region itself. Overall, the maximum penetration depth detected with this technique for 237Np and uranium isotopes over the field experimental time scale of about 60 days was about 10 mm in the granitic matrix, illustrating the importance of matrix diffusion in retarding radionuclide transport from the advective fractures. Laboratory tests and numerical modelling of radionuclide diffusion into granitic matrix was conducted to complement and help interpret the field results.

  16. Experimental assessment of the sealing effectiveness of rock fracture grouting

    SciTech Connect

    Schaffer, A.; Daemen, J.J.K.

    1987-03-01

    The objective of this investigation is to determine the effectiveness of cement grouts as sealants of fractures in rock. Laboratory experiments have been conducted on seven 15-cm granite cubes containing saw cuts, three 23-cm diameter andesite cores containing induced tension cracks, and one 15-cm diameter marble core containing a natural fracture. Prior to grouting, the hydraulic conductivity of the fractures is determined under a range of normal stresses, applied in loading and unloading cycles, from 0 to 14 MPa (2000 psi). Grout is injected through an axial borehole, at a pressure of 1.2 to 8.3 MPa (180 to 1200 psi), pressure selected to provide a likely groutable fracture aperture, while the fracture is stressed at a constant normal stress. The fracture permeability is measured after grouting. Flow tests on the ungrouted samples confirm the inverse relation between normal stress and fracture permeability. The equivalent aperture determined by these tests is a reliable indicator of groutability. Postgrouting permeability measurements as performed here, and frequently in practice, can be misleading, since incomplete grouting of fractures can result in major apparent reductions in permeability. The apparent permeability reduction is caused by grouting of a small area of a highly preferential flowpath directly adjacent to the hole used for grouting and for permeability testing. Experimental results confirm claims in the literature that ordinary portland cement inadequately penetrates fine fractures.

  17. TIBIAL SHAFT FRACTURES

    PubMed Central

    Kojima, Kodi Edson; Ferreira, Ramon Venzon

    2015-01-01

    The long-bone fractures occur most frequently in the tibial shaft. Adequate treatment of such fractures avoids consolidation failure, skewed consolidation and reoperation. To classify these fractures, the AO/OTA classification method is still used, but it is worthwhile getting to know the Ellis classification method, which also includes assessment of soft-tissue injuries. There is often an association with compartmental syndrome, and early diagnosis can be achieved through evaluating clinical parameters and constant clinical monitoring. Once the diagnosis has been made, fasciotomy should be performed. It is always difficult to assess consolidation, but the RUST method may help in this. Radiography is assessed in two projections, and points are scored for the presence of the fracture line and a visible bone callus. Today, the dogma of six hours for cleaning the exposed fracture is under discussion. It is considered that an early start to intravenous antibiotic therapy and the lesion severity are very important. The question of early or late closure of the lesion in an exposed fracture has gone through several phases: sometimes early closure has been indicated and sometimes late closure. Currently, whenever possible, early closure of the lesion is recommended, since this diminishes the risk of infection. Milling of the canal when the intramedullary nail is introduced is still a controversial subject. Despite strong personal positions in favor of milling, studies have shown that there may be some advantage in relation to closed fractures, but not in exposed fractures. PMID:27026999

  18. Rib fracture - aftercare

    MedlinePlus

    A rib fracture is a crack or break in one or more of your rib bones. Your ribs are the round, flat bones in your chest ... A rib fracture can be very painful because your ribs move when you breathe, cough, and move your upper ...

  19. The Role of Fibular Fixation in Distal Tibial Fractures

    PubMed Central

    Antin, S.M.; Akkimaradi, R.C.; Policepatil, Prasad; Naikawadi, Girish.

    2016-01-01

    Introduction Lower tibial extra-articular fractures of lower tibial extra-articular bone, treated with Minimally Invasive Percutaneous plate osteosynthesis (MIPPO) may have certain advantages, though the modiality is technically demanding. Aim To assess the results of distal tibial fractures treated with minimally invasive plate osteosynthesis utilizing precontoured dital medial tibial locking plates without fibular fracture fixation. Material and Methods The study was conducted during the period from june 2009 to june 2011. A series of 30 patients (22 men and 8 women) with concurrent distal tibia and fibula fractures who underwent minimally plate osteosynthesis utilizing precontoured distal tibial medial locking plates without fibular fracture fixation have been reviewed after surgery. 14 fractures were type A1, 6 type A2, and 4 type A3. Open Grade II fracture were 4 and Open Grade IIIA fracture is2. Results The mean follow-up duration was 2 years. The mean time to bone union was 20 weeks. No patient had shortening, hardware breakdown, or deep-seated infection. Out of 30 patients, 24 had excellent results, 6 had good results. Four patients had palpable screws, two patient had blisters which subsidized with conservative treatment. This minimally invasive technique for treatment of distal tibial fractures proved to be a feasible and worthwhile method of stabilization. Conclusion It appears from our study that fibula fixation is not required in non-syndesmotic distal metaphyseal extra articular fractures when fixed by locking plate using minimal invasive techniques. PMID:27190908

  20. Laboratory testing of cement grouting of fractures in welded tuff

    SciTech Connect

    Sharpe, C.J.; Daemen, J.J.

    1991-03-01

    Fractures in the rock mass surrounding a repository and its shafts, access drifts, emplacement rooms and holes, and exploratory or in-situ testing holes, may provide preferential flowpaths for the flow of groundwater or air, potentially containing radionuclides. Such cracks may have to be sealed. The likelihood that extensive or at least local grouting will be required as part of repository sealing has been noted in numerous publications addressing high level waste repository closing. The objective of this work is to determine the effectiveness of fracture sealing (grouting) in welded tuff. Experimental work includes measurement of intact and fracture permeability under various normal stresses and injection pressures. Grout is injected into the fractures. The effectiveness of grouting is evaluated in terms of grout penetration and permeability reduction, compared prior to and after grouting. Analysis of the results include the effect of normal stress, injection pressure, fracture roughness, grout rheology, grout bonding, and the radial extent of grout penetration. Laboratory experiments have been performed on seventeen tuff cylinders with three types of fractures: (1) tension induced cracks, (2) natural fractures, and (3) sawcuts. Prior to grouting, the hydraulic conductivity of the intact rock and of the fractures is measured under a range of normal stresses. The surface topography of the fracture is mapped, and the results are used to determine aperture distributions across the fractures. 72 refs., 76 figs., 25 tabs.

  1. Characterization of fracture networks for fluid flow analysis

    SciTech Connect

    Long, J.C.S.; Billaux, D.; Hestir, K.; Majer, E.L.; Peterson, J.; Karasaki, K.; Nihei, K.; Gentier, S.; Cox, L.

    1989-06-01

    The analysis of fluid flow through fractured rocks is difficult because the only way to assign hydraulic parameters to fractures is to perform hydraulic tests. However, the interpretation of such tests, or ''inversion'' of the data, requires at least that we know the geometric pattern formed by the fractures. Combining a statistical approach with geophysical data may be extremely helpful in defining the fracture geometry. Cross-hole geophysics, either seismic or radar, can provide tomograms which are pixel maps of the velocity or attenuation anomalies in the rock. These anomalies are often due to fracture zones. Therefore, tomograms can be used to identify fracture zones and provide information about the structure within the fracture zones. This structural information can be used as the basis for simulating the degree of fracturing within the zones. Well tests can then be used to further refine the model. Because the fracture network is only partially connected, the resulting geometry of the flow paths may have fractal properties. We are studying the behavior of well tests under such geometry. Through understanding of this behavior, it may be possible to use inverse techniques to refine the a priori assignment of fractures and their conductances such that we obtain the best fit to a series of well test results simultaneously. The methodology described here is under development and currently being applied to several field sites. 4 refs., 14 figs.

  2. The feasibility of ranking material fracture toughness by ultrasonic attenuation measurements

    NASA Technical Reports Server (NTRS)

    Vary, A.

    1975-01-01

    A preliminary study was conducted to assess the feasibility of ultrasonically ranking material fracture toughness. Specimens of two grades of maraging steel for which fracture toughness values were measured were subjected to ultrasonic probing. The slope of the attenuation coefficient versus frequency curve was empirically correlated with the plane strain fracture toughness value for each grade of steel.

  3. The feasibility of ranking material fracture toughness by ultrasonic attenuation measurements

    NASA Technical Reports Server (NTRS)

    Vary, A.

    1975-01-01

    A preliminary study was conducted to assess the feasibility of ultrasonically ranking material fracture toughness. Specimens of two grades of maraging steel for which fracture toughness values were measured were subjected to ultrasonic probing. The slope of the attenuation coefficient vs frequency curve was empirically correlated with the plane strain fracture toughness value for each grade of steel.

  4. A 3D POM-MOF composite based on Ni(ΙΙ) ion and 2,2‧-bipyridyl-3,3‧-dicarboxylic acid: Crystal structure and proton conductivity

    NASA Astrophysics Data System (ADS)

    Wei, Meilin; Wang, Xiaoxiang; Sun, Jingjing; Duan, Xianying

    2013-06-01

    We have succeeded in constructing a 3D POM-MOF, {H[Ni(Hbpdc)(H2O)2]2[PW12O40]·8H2O}n (H2bpdc=2,2'-bipyridyl-3,3'-dicarboxylic acid), by the controllable self-assembly of H2bpdc, Keggin-anions and Ni2+ ions based on the electrostatic and coordination interactions. Interestingly, Hbpdc- as polydentate organic ligands and Keggin-anion as polydentate inorganic ligands are covalently linked transition-metal nickel at the same time. The title complex represents a new example of introducing the metal N-heterocyclic multi-carboxylic acid frameworks into POMs chemistry. Based on Keggin-anions being immobilized as part of the metal N-heterocyclic multi-carboxylic acid framework, the title complex realizes four approaches in the 1D hydrophilic channel used to engender proton conductivity in MOFs. Its water adsorption isotherm at room temperature and pressure shows that the water content in it was 31 cm3 g-1 at the maximum allowable humidity, corresponding to 3.7 water molecules per unit formula. It exhibits good proton conductivities (10-4-10-3 S cm-1) at 100 °C in the relative humidity range 35-98%. The corresponding activation energy (Ea) of conductivity was estimated to be 1.01 eV.

  5. Dynamic fracture mechanics

    NASA Technical Reports Server (NTRS)

    Kobayashi, A. S.; Ramulu, M.

    1985-01-01

    Dynamic fracture and crack propagation concepts for ductile materials are reviewed. The equations for calculating dynamic stress integrity and the dynamic energy release rate in order to study dynamic crack propagation are provided. The stress intensity factor versus crack velocity relation is investigated. The uses of optical experimental techniques and finite element methods for fracture analyses are described. The fracture criteria for a rapidly propagating crack under mixed mode conditions are discussed; crack extension and fracture criteria under combined tension and shear loading are based on maximum circumferential stress or energy criteria such as strain energy density. The development and use of a Dugdale model and finite element models to represent crack and fracture dynamics are examined.

  6. Transphyseal Distal Humerus Fracture.

    PubMed

    Abzug, Joshua; Ho, Christine Ann; Ritzman, Todd F; Brighton, Brian

    2016-01-01

    Transphyseal distal humerus fractures typically occur in children younger than 3 years secondary to birth trauma, nonaccidental trauma, or a fall from a small height. Prompt and accurate diagnosis of a transphyseal distal humerus fracture is crucial for a successful outcome. Recognizing that the forearm is not aligned with the humerus on plain radiographs may aid in the diagnosis of a transphyseal distal humerus fracture. Surgical management is most commonly performed with the aid of an arthrogram. Closed reduction and percutaneous pinning techniques similar to those used for supracondylar humerus fractures are employed. Cubitus varus caused by a malunion, osteonecrosis of the medial condyle, or growth arrest is the most common complication encountered in the treatment of transphyseal distal humerus fractures. A corrective lateral closing wedge osteotomy can be performed to restore a nearly normal carrying angle. PMID:27049206

  7. Apparent capitellar fractures.

    PubMed

    Ring, David

    2007-11-01

    Isolated capitellar fractures are rare but are identified as such, even when they are more complex, because the displaced capitellar fracture is usually the most obvious and identifiable radiographic finding and because teaching has traditionally underemphasized the involvement of the trochlea in such fractures. The author prefers the term 'apparent capitellar fractures' and draws on his experience to explain why he favors three-dimensional CT for depicting fracture detail. This article discusses treatment options, emphasizing open reduction and internal fixation to restore the native elbow. Operative techniques, including extensile lateral exposure and olecranon osteotomy; fixation techniques; and elbow arthroplasty, are described. Complications, such as ulnar neuropathy and infection, are also covered. PMID:18054674

  8. Hydraulic fracturing of jointed formations

    SciTech Connect

    Murphy, H.D.; Fehler, M.C.

    1986-01-01

    Measured by volume, North America's largest hydraulic fracturing operations have been conducted at Fenton Hill, New Mexico to create geothermal energy reservoirs. In the largest operation 21,000 m/sup 3/ of water were injected into jointed granitic rock at a depth of 3.5 km. Microearthquakes induced by this injection were measured with geophones placed in five wells drilled into, or very close, to the reservoir, as well as 11 surface seismometers. The large volume of rock over which the microearthquakes were distributed indicates a mechanism of hydraulic stimulation which is at odds with conventional fracturing theory, which predicts failure along a plane which is perpendicular to the least compressive earth stress. A coupled rock mechanics/fluid flow model provides much of the explanation. Shear slippage along pre-existing joints in the rock is more easily induced than conventional tensile failure, particularly when the difference between minimum and maximum earth stresses is large and the joints are oriented at angles between 30 and 60 degrees to the principal earth stresses, and a low viscosity fluid like water is injected. Shear slippage results in local redistribution of stresses, which allows a branching, or dendritic, stimulation pattern to evolve, in agreement with the patterns of microearthquake locations. These results are qualitatively similar to the controversial process known as ''Kiel'' fracturing, in which sequential injections and shut-ins are repeated to create dendritic fractures for enhanced oil and gas recovery. However, we believe that the explanation is shear slippage of pre-existing joints and stress redistribution, not proppant bridging and fluid blocking as suggested by Kiel. 15 refs., 10 figs.

  9. Biomechanics of frontal skull fracture.

    PubMed

    Delye, Hans; Verschueren, Peter; Depreitere, Bart; Verpoest, Ignaas; Berckmans, Daniel; Vander Sloten, Jos; Van Der Perre, Georges; Goffin, Jan

    2007-10-01

    The purpose of the present study was to investigate whether an energy failure level applies to the skull fracture mechanics in unembalmed post-mortem human heads under dynamic frontal loading conditions. A double-pendulum model was used to conduct frontal impact tests on specimens from 18 unembalmed post-mortem human subjects. The specimens were isolated at the occipital condyle level, and pre-test computed tomography images were obtained. The specimens were rigidly attached to an aluminum pendulum in an upside down position and obtained a single degree of freedom, allowing motion in the plane of impact. A steel pendulum delivered the impact and was fitted with a flat-surfaced, cylindrical aluminum impactor, which distributed the load to a force sensor. The relative displacement between the two pendulums was used as a measure for the deformation of the specimen in the plane of impact. Three impact velocity conditions were created: low (3.60+/-0.23 m/sec), intermediate (5.21+/-0.04 m/sec), and high (6.95+/-0.04 m/sec) velocity. Computed tomography and dissection techniques were used to detect pathology. If no fracture was detected, repeated tests on the same specimen were performed with higher impact energy until fracture occurred. Peak force, displacement and energy variables were used to describe the biomechanics. Our data suggests the existence of an energy failure level in the range of 22-24 J for dynamic frontal loading of an intact unembalmed head, allowed to move with one degree of freedom. Further experiments, however, are necessary to confirm that this is a definitive energy criterion for skull fracture following impact. PMID:17970621

  10. CHARACTERIZATION OF FRACTURED BEDROCK FOR STEAM INJECTION

    EPA Science Inventory

    The most difficult setting in which to conduct groundwater remediation is that where chlorinated solvents have penetrated fractured bedrock. To demonstrate the potential viability of steam injection as a means of groundwater clean-up in this type of environment, steam will be in...

  11. Application of microseismic technology to hydraulic fracture diagnostics: GRI/DOE Field Fracturing Multi-Sites Project

    SciTech Connect

    Wilmer, R.; Warpinski, N.R.; Wright, T.B.; Branagan, P.T.; Fix, J.E.

    1995-06-01

    The objective of the Field Fracturing Multi-Sites Project (M-Site) is to conduct field experiments and analyze data that will result in definitive determinations of hydraulic fracture dimensions using remote well and treatment well diagnostic techniques. In addition, experiments will be conducted to provide data that will resolve significant unknowns with regard to hydraulic fracture modeling, fracture fluid rheology and fracture treatment design. These experiments will be supported by a well-characterized subsurface environment as well as surface facilities and equipment conducive to acquiring high-quality data. It is anticipated that the project`s research advancements will provide a foundation for a fracture diagnostic service industry and hydraulic fracture optimization based on measured fracture response. The M-Site Project is jointly sponsored by the Gas Research Institute (GRI) and the US Department of Energy (DOE). The site developed for M-Site hydraulic fracture experimentation is the former DOE Multiwell Experiment (MWX) site located near Rifle, Colorado. The MWX project drilled three closely-spaced wells (MWX-1, MWX-2 and MWX-3) which were the basis for extensive reservoir analyses and tight gas sand characterizations in the blanket and lenticular sandstone bodies of the Mesaverde Group. The research results and background knowledge gained from the MWX project are directly applicable to research in the current M-Site Project.

  12. A fractographic study of the edge-sliding mode in fracture toughness testing

    NASA Technical Reports Server (NTRS)

    Jones, D. L.; Chisholm, D. B.

    1976-01-01

    A fractographic study of Mode II fracture surfaces has been conducted for the purpose of identifying the microstructural mechanisms responsible for fracture in the edge-sliding mode. A compact shear (CS) specimen was employed to generate the fracture surfaces and also to establish Mode II fracture toughness values for Ti-6Al-4V, A533-B steel, and several aluminum alloys. In all tests, one of the two edge cracks sustained complete Mode II fracture while the other exhibited only a limited amount of subcritical crack growth. Mode II fracture surfaces, which were unique in appearance, have been examined by optical and scanning electron microscopy. It was determined that shear (or parabolic) microvoid coalescence was the dominant mechanism for Mode II fracture. It was also established that most of the surface abrasions were created by the relative sliding of the fracture surfaces during unstable fracture rather than the crack initiation process.

  13. The development of in situ fracture toughness evaluation techniques in hydrogen environment

    SciTech Connect

    Wang, Jy-An John; Ren, Fei; Tan, Ting; Liu, Ken C

    2014-01-01

    Fracture behavior and fracture toughness are of great interest regarding reliability of hydrogen pipelines and storage tanks, however, many conventional fracture testing techniques are difficult to be realized under the presence of hydrogen, in addition to the inherited specimen size effect. Thus it is desired to develop novel in situ fracture toughness evaluation techniques to study the fracture behavior of structural materials in hydrogen environments. In this study, a torsional fixture was developed to utilize an emerging fracture testing technique, Spiral Notch Torsion Test (SNTT). The in situ testing results indicated that the exposure to H2 significantly reduces the fracture toughness of 4340 high strength steels by up to 50 percent. Furthermore, SNTT tests conducted in air demonstrated a significant fracture toughness reduction in samples subject to simulated welding heat treatment using Gleeble, which illustrated the effect of welding on the fracture toughness of this material.

  14. Discrete fracture simulations of the hydrogeology at Koongarra, Northern Territory, Australia

    SciTech Connect

    Smoot, J.L.

    1992-04-01

    The US Department of Energy is studying the Alligator Rivers Natural Analogue Project site at Koongarra, Northern Territory, Australia to investigate and simulate radionuclide migration in fractured rocks. Discrete fracture simulations were conducted within a cubic volume (180-m edge length) of fractured Cahill Formation schist oriented with one major axis parallel to the trend of the Koongarra Fault. Five hundred fractures are simulated within this domain. The fractures have a mean orientation parallel to the idealized plane of the Koongarra Fault dipping 55{degrees} SE. Simple flow modeling of this fracture network was conducted by assigning constant head boundaries to upgradient and downgradient vertical faces of the cube, which trend parallel to the fault. No-flow boundaries were assigned to all other faces. The fracture network allows hydraulic communication across the block, in spite of relatively low fracture density across the block.

  15. Fractures and stresses in Bone Spring sandstones

    SciTech Connect

    Lorenz, J.C.; Warpinski, N.R.; Sattler, A.R.; Northrop, D.A.

    1990-09-01

    This project is a collaboration between Sandia National Laboratories and Harvey E. Yates Company being conducted under the auspices of the Oil Recovery Technology Partnership. The project seeks to apply perspectives related to the effects of natural fractures, stress, and sedimentology to the simulation and production of low-permeability gas reservoirs to low-permeability oil reservoirs as typified by the Bone Spring sandstones of the Permian Basin, southeast New Mexico. This report presents the results and analysis obtained in 1989 from 233 ft of oriented core, comprehensive suite of logs, various in situ stress measurements, and detailed well tests conducted in conjunction with the drilling of two development wells. Natural fractures were observed in core and logs in the interbed carbonates, but there was no direct evidence of fractures in the sandstones. However, production tests of the sandstones indicated permeabilities and behavior typical of a dual porosity reservoir. A general northeast trend for the maximum principal horizontal stress was observed in an elastic strain recovery measurements and in strikes of drilling-induced fractures; this direction is subparallel to the principal fracture trend observed in the interbed carbonates. Many of the results presented are believed to be new information for the Bone Spring sandstones. 57 figs., 18 tabs.

  16. Uncertainty Analysis of Simulated Hydraulic Fracturing

    NASA Astrophysics Data System (ADS)

    Chen, M.; Sun, Y.; Fu, P.; Carrigan, C. R.; Lu, Z.

    2012-12-01

    Artificial hydraulic fracturing is being used widely to stimulate production of oil, natural gas, and geothermal reservoirs with low natural permeability. Optimization of field design and operation is limited by the incomplete characterization of the reservoir, as well as the complexity of hydrological and geomechanical processes that control the fracturing. Thus, there are a variety of uncertainties associated with the pre-existing fracture distribution, rock mechanics, and hydraulic-fracture engineering that require evaluation of their impact on the optimized design. In this study, a multiple-stage scheme was employed to evaluate the uncertainty. We first define the ranges and distributions of 11 input parameters that characterize the natural fracture topology, in situ stress, geomechanical behavior of the rock matrix and joint interfaces, and pumping operation, to cover a wide spectrum of potential conditions expected for a natural reservoir. These parameters were then sampled 1,000 times in an 11-dimensional parameter space constrained by the specified ranges using the Latin-hypercube method. These 1,000 parameter sets were fed into the fracture simulators, and the outputs were used to construct three designed objective functions, i.e. fracture density, opened fracture length and area density. Using PSUADE, three response surfaces (11-dimensional) of the objective functions were developed and global sensitivity was analyzed to identify the most sensitive parameters for the objective functions representing fracture connectivity, which are critical for sweep efficiency of the recovery process. The second-stage high resolution response surfaces were constructed with dimension reduced to the number of the most sensitive parameters. An additional response surface with respect to the objective function of the fractal dimension for fracture distributions was constructed in this stage. Based on these response surfaces, comprehensive uncertainty analyses were conducted

  17. The Complex Relation between Bisphosphonate Adherence and Fracture Reduction

    PubMed Central

    Patrick, Amanda R.; Brookhart, M. Alan; Losina, Elena; Schousboe, John T.; Cadarette, Suzanne M.; Mogun, Helen; Solomon, Daniel H.

    2010-01-01

    Context: Real-world adherence to bisphosphonate therapy is poor. Consistent data support a relation between medication adherence and fracture reduction, but relatively little attention has been paid to the effect of the method used to measure adherence on this relation or on the relation between adherence and specific fracture types. Objective: Our objective was to assess the relation between bisphosphonate adherence and the risk of hip, vertebral, distal forearm, and any fracture using different measures of adherence. Design: We conducted a cohort study using administrative claims data. Adherence was assessed in sequential 60-d periods. In models incorporating time-varying measures of adherence, the adjusted relation between adherence and fracture was examined using several methods for calculating the proportion of days covered (PDC). Patients: Patients included community-dwelling elderly enrolled in a Pennsylvania pharmaceutical assistance program and Medicare initiating an oral bisphosphonate for osteoporosis. Main Outcome Measures: Risk of hip, vertebral, distal forearm, and any osteoporotic fracture was assessed. Results: Fractures occurred at a rate of 43 per 1000 person-years among the 19,987 patients meeting study eligibility criteria. There was an inverse relation between adherence and fracture rate for all adherence measures and fracture types, excluding distal forearm fractures. High (80–100%) cumulative PDC was associated with a 22% reduction in overall fracture rate, a 23% reduction in hip fracture rate, and 26% reduction in vertebral fracture rate. Conclusions: We found a consistent relation between adherence with osteoporosis treatment and fracture reduction, regardless of method for measuring PDC. The similarity in results across adherence measures is likely due to the high correlation between them. PMID:20444916

  18. Fracture Risk among Nursing Home Residents Initiating Antipsychotic Medications

    PubMed Central

    Rigler, Sally K.; Shireman, Theresa I.; Cook-Wiens, Galen J.; Ellerbeck, Edward F.; Whittle, Jeffrey C.; Mehr, David R.; Mahnken, Jonathan D.

    2013-01-01

    Objectives to determine whether antipsychotic medication initiation is associated with subsequent fracture in nursing home residents, whether fracture rates differ between first-generation versus second-generation antipsychotic use, and whether fracture rates differ among users of haloperidol, risperidone, olanzapine, and quetiapine. Design time-to-event analyses were conducted in a retrospective cohort using linked Medicaid, Medicare, Minimum Data Set and Online Survey, Certification and Reporting data sets. Setting and Participants nursing home residents aged ≥ 65 years in CA, FL, MO, NJ and PA. Measurements fracture outcomes (any fracture; hip fracture) in first-versus second-generation antipsychotic users, and specifically among users of haloperidol, risperidone, olanzapine and quetiapine. Comparisons incorporated propensity scores that included patient-level variables (demographics, comorbidity, diagnoses, weight, fall history, concomitant medications, cognitive performance, physical function, aggressivebehavior) and facility-level variables (nursing home size, ownership factors, staffing levels). Results Among 8,262 subjects (within 4,131 pairs), 4.3% suffered any fracture during observation with 1% having a hip fracture during an average follow up period of 93 ± 71 days; range 1 to 293 days). Antipsychotic initiation was associated with any fracture (hazard ratio (HR) 1.39, p=0.004) and with hip fracture (HR 1.76, p=0.024). The highest risk was found for hip fracture when antipsychotic use was adjusted for dose(HR=2.96; p=0.008). However, no differences in time-to-fracture were found in first-versus second-generation agents or across competing individual drugs. Conclusion Antipsychotic initiation is associated with fracture in nursing home residents, but risk does not differ across commonly used antipsychotics. PMID:23590366

  19. Fractured reservoir discrete feature network technologies. Final report, March 7, 1996 to September 30, 1998

    SciTech Connect

    Dershowitz, William S.; Einstein, Herbert H.; LaPoint, Paul R.; Eiben, Thorsten; Wadleigh, Eugene; Ivanova, Violeta

    1998-12-01

    This report summarizes research conducted for the Fractured Reservoir Discrete Feature Network Technologies Project. The five areas studied are development of hierarchical fracture models; fractured reservoir compartmentalization, block size, and tributary volume analysis; development and demonstration of fractured reservoir discrete feature data analysis tools; development of tools for data integration and reservoir simulation through application of discrete feature network technologies for tertiary oil production; quantitative evaluation of the economic value of this analysis approach.

  20. Calcium plus vitamin D supplementation and risk of fractures: An updated meta analysis from the National Osteoporosis Foundation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Background: Calcium plus vitamin D supplementation has been widely recommended to prevent osteoporosis and subsequent fractures; however, considerable controversy exists regarding the association of such supplementation and fracture risk.Purpose: To conduct a meta analysis of randomized controlled t...

  1. Understanding Hydraulic Fracture Stimulations in Oil-Gas Developments Using Microseismicity (M<0)

    NASA Astrophysics Data System (ADS)

    Urbancic, T.; Baig, A. M.

    2011-12-01

    effectiveness of different stimulation programs, and define the "effective fracture zone" associated with the stimulation. Knowledge of the effective fracture zone can then be used to estimate the Stimulated Reservoir Area (SRA) or Volume (SRV) associated with the treatment program and enable enhanced calculations of productivity. Using Hudson plots, changes in fracture behaviour from an opening dominated, fracture-extension regime to an ineffective closure-dominant regime, can identify Points of Diminishing Returns (PDR) as temporal points where continued stimulation of the reservoir with the same pumping regime will no longer extend the fracture network. Understanding when a fracture stage reaches a PDR enables engineers to adjust treatment plans to re-initiate fracture extension, achieve better proppant distribution or design future fracture networks to realize higher conductivity. This ability to integrate microseismic analysis with knowledge of the fracture treatment program serves as an invaluable tool for engineers who are trying to design and perform optimal fracture stimulations.

  2. Urokinase plasminogen activator gene deficiency inhibits fracture cartilage remodeling.

    PubMed

    Popa, Nicoleta L; Wergedal, Jon E; Lau, K-H William; Mohan, Subburaman; Rundle, Charles H

    2014-03-01

    Urokinase plasminogen activator (uPA) regulates a proteolytic cascade of extracellular matrix degradation that functions in tissue development and tissue repair. The development and remodeling of the skeletal extracellular matrix during wound healing suggests that uPA might regulate bone development and repair. To determine whether uPA functions regulate bone development and repair, we examined the basal skeletal phenotype and endochondral bone fracture repair in uPA-deficient mice. The skeletal phenotype of uPA knockout mice was compared with that of control mice under basal conditions by dual-energy X-ray absorptiometry and micro-CT analysis, and during femur fracture repair by micro-CT and histological examination of the fracture callus. No effects of uPA gene deficiency were observed in the basal skeletal phenotype of the whole body or the femur. However, uPA gene deficiency resulted in increased fracture callus cartilage abundance during femur fracture repair at 14 days healing. The increase in cartilage corresponded to reduced tartrate-resistant acid phosphatase (TRAP) staining for osteoclasts in the uPA knockout fracture callus at this time, consistent with impaired osteoclast-mediated remodeling of the fracture cartilage. CD31 staining was reduced in the knockout fracture tissues at this time, suggesting that angiogenesis was also reduced. Osteoclasts also colocalized with CD31 expression in the endothelial cells of the fracture tissues during callus remodeling. These results indicate that uPA promotes remodeling of the fracture cartilage by osteoclasts that are associated with angiogenesis and suggest that uPA promotes angiogenesis and remodeling of the fracture cartilage at this time of bone fracture repair. PMID:23700285

  3. Mixed-Mode Fracture Behavior and Related Surface Topography Feature of a Typical Sandstone

    NASA Astrophysics Data System (ADS)

    Ren, L.; Xie, L. Z.; Xie, H. P.; Ai, T.; He, B.

    2016-08-01

    The geo-mechanical properties of reservoirs, especially the morphology of the rock surface and the fracture properties of rocks, are of great importance in the modeling and simulation of hydraulic processes. To better understand these fundamental issues, five groups of mixed-mode fracture tests were conducted on sandstone using edge-cracked semi-circular bend specimens. Accordingly, the fracture loads, growth paths and fracture surfaces for different initial mixities of the mixed-mode loadings from pure mode I to pure mode II were then determined. A surface topography measurement for each rough fracture surface was conducted using a laser profilometer, and the fractal properties of these surfaces were then investigated. The fracture path evolution mechanism was also investigated via optical microscopy. Moreover, the mixed-mode fracture strength envelope and the crack propagation trajectories of sandstone were theoretically modeled using three widely accepted fracture criteria (i.e., the MTS, MSED and MERR criterions). The published test results in Hasanpour and Choupani (World Acad Sci Eng Tech 41:764-769, 2008) for limestone were also theoretically investigated to further examine the effectiveness of the above fracture criteria. However, none of these criteria could accurately predict the fracture envelopes of both sandstone and limestone. To better estimate the fracture strength of mixed-mode fractures, an empirical maximum tensile stress (EMTS) criterion was proposed and found to achieve good agreement with the test results. Finally, a uniformly pressurized fracture model was simulated for low pressurization rates using this criterion.

  4. Fracture mechanics: 26. volume

    SciTech Connect

    Reuter, W.G.; Underwood, J.H.; Newman, J.C. Jr.

    1995-12-31

    The original objective of these symposia was to promote technical interchange between researchers from the US and worldwide in the field of fracture. This objective was recently expanded to promote technical interchange between researchers in the field of fatigue and fracture. The symposium began with the Swedlow Memorial Lecture entitled ``Patterns and Perspectives in Applied Fracture Mechanics.`` The remaining 42 papers are divided into the following topical sections: Constraint crack initiation; Constraint crack growth; Weldments; Engineered materials; Subcritical crack growth; Dynamic loading; and Applications. Papers within the scope of the Energy Data Base have been processed separately.

  5. Conduct disorder

    MedlinePlus

    Disruptive behavior - child; Impulse control problem - child ... Conduct disorder has been linked to: Child abuse Drug or alcohol abuse in the parents Family conflicts Genetic defects Poverty The diagnosis is more common among boys. It is ...

  6. Electrical Conductivity.

    ERIC Educational Resources Information Center

    Hershey, David R.; Sand, Susan

    1993-01-01

    Explains how electrical conductivity (EC) can be used to measure ion concentration in solutions. Describes instrumentation for the measurement, temperature dependence and EC, and the EC of common substances. (PR)

  7. Effect of Internal Aperture Variability on Tracer Transport in Large Discrete Fracture Networks (DFN)

    NASA Astrophysics Data System (ADS)

    Makedonska, N.; Painter, S. L.; Hyman, J.; Karra, S.; Gable, C. W.; Viswanathan, H. S.

    2015-12-01

    Aperture variability within individual fractures is usually neglected in modeling flow and transport through fractured media. Typically, individual fractures are assumed to be homogeneous. However, in reality, individual fractures are heterogeneous, which may affect flow and transport in fractured media. The relative importance of including in-fracture variability in flow and transport modeling has been under debate for a long time. Previous studies have shown flow channeling on an individual fracture with internal variability, where the fracture is considered isolated from the rest of the fracture network. Although these studies yield some clear insights into the process, the boundary conditions are impractical for field-scale networks, where the realistic boundary conditions are determined by fracture connections in the network. Therefore, flow in a single fracture is controlled not only by in-fracture variability but also by boundary conditions. In order to address the question of the importance of in-fracture variability, the internal heterogeneity of every individual fracture is incorporated into a three-dimensional fracture network, represented by a composition of intersecting fractures. The new DFN simulation capability, dfnWorks, is used to generate a kilometer scale DFNs similar to the Forsmark, Sweden site. In our DFN model, the in-fracture aperture variability is scattered over each cell of the computational mesh along the fracture, representing by a stationary Gaussian random field with various correlation lengths. The Lagrangian particle tracking is conducted in multiple DFN realizations and the flow-dependent Lagrangian parameters, non-reacting travel time, τ, and cumulative reactivity parameter, β, are obtained along particles streamlines. It is shown that early particle travel times are more sensitive to in-fracture aperture variability than tails of travel time distributions, where no significant effect of the aperture variations and spatial

  8. Ionically conductive thin polymer films prepared by plasma polymerization; Preparation and characterization of ultrathin films having fixed sulfonic acid groups with only one mobile species

    SciTech Connect

    Ogumi, Z.; Uchimoto, Y.; Takehara, Z. ); Foulkes, F.R. . Dept. of Chemical Engineering and Applied Chemistry)

    1990-01-01

    Ultrathin solid polymer electrolyte membranes containing sulfonic ester groups were prepared by polymerization of methyl benzenesulfonate and octamethylcyclotetrasiloxane in a glow discharge plasma. The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treatment with lithium iodide. Hybridization of this plasma polymer containing the lithium sulfonate groups with poly(ethylene oxide) (average Mw 300) resulted in the formation of a single lithium ion conductive film. The hybrid polymer electrolyte films were about 1 {mu}m thick, pinhole-free, adherent to various substrates, and showed ionic conductivities at 60{degrees}C of the order of 10{sup {minus} 6} S cm{sup {minus} 1} (10{sup 2} {Omega} cm{sup 2} resistance per unit area of as-prepared solid polymer electrolyte). This material shows promise for electrochemical applications such as all solid-state lithium batteries, sensors, and electrochemical display devices.

  9. Mechanical Coal-Face Fracturer

    NASA Technical Reports Server (NTRS)

    Collins, E. R., Jr.

    1984-01-01

    Radial points on proposed drill bit take advantage of natural fracture planes of coal. Radial fracture points retracted during drilling and impacted by piston to fracture coal once drilling halts. Group of bits attached to array of pneumatic drivers to fracture large areas of coal face.

  10. Biomechanical failure of metacarpal fracture resorbable plate fixation.

    PubMed

    Lionelli, Gerald T; Korentager, Richard A

    2002-08-01

    Metacarpal fractures are a relatively common hand injury that may require operative intervention to ensure adequate reduction and stabilization. The use of permanent hardware, although acceptable, may lead to complications and an increased number of surgical procedures. The use of resorbable hardware such as poly-L-lactic acid and polyglycolic acid copolymer plates and screws may circumvent some of these complications. In vitro studies have demonstrated that the biomechanical characteristics of these resorbable plates may provide the rigid fixation necessary to allow for union of metacarpal fractures in vivo. However, limited clinical data are available regarding the success of their use in this application. The authors present what they believe is the first reported case of the failure of a poly-L-lactic acid and polyglycolic acid copolymer miniplate after use in the fixation of a metacarpal shaft fracture. PMID:12187350

  11. A 3D POM–MOF composite based on Ni(ΙΙ) ion and 2,2´-bipyridyl-3,3´-dicarboxylic acid: Crystal structure and proton conductivity

    SciTech Connect

    Wei, Meilin; Wang, Xiaoxiang; Sun, Jingjing; Duan, Xianying

    2013-06-01

    We have succeeded in constructing a 3D POM–MOF, (H[Ni(Hbpdc)(H₂O)₂]₂[PW₁₂O₄₀]·8H₂O)n (H₂bpdc=2,2´-bipyridyl-3,3´-dicarboxylic acid), by the controllable self-assembly of H₂bpdc, Keggin-anions and Ni²⁺ ions based on the electrostatic and coordination interactions. Interestingly, Hbpdc⁻ as polydentate organic ligands and Keggin-anion as polydentate inorganic ligands are covalently linked transition-metal nickel at the same time. The title complex represents a new example of introducing the metal N-heterocyclic multi-carboxylic acid frameworks into POMs chemistry. Based on Keggin-anions being immobilized as part of the metal N-heterocyclic multi-carboxylic acid framework, the title complex realizes four approaches in the 1D hydrophilic channel used to engender proton conductivity in MOFs. Its water adsorption isotherm at room temperature and pressure shows that the water content in it was 31 cm³ g⁻¹ at the maximum allowable humidity, corresponding to 3.7 water molecules per unit formula. It exhibits good proton conductivities (10⁻⁴–10⁻³ S cm⁻¹) at 100 °C in the relative humidity range 35–98%. The corresponding activation energy (E{sub a}) of conductivity was estimated to be 1.01 eV. - Graphical abstract: A POM–MOF composite constructed by Keggin-type polyanion, Ni²⁺ and H₂bpdc shows good proton conductivities of 10⁻⁴–10⁻³ S cm⁻¹ at 100 °C under 35–98% RH. - Highlights: • A POM–MOF was constructed by combining metal N-heterocyclic multi-carboxylic acid framework and Keggin anion. • It opens a pathway for design and synthesis of multifunctional hybrid materials based on two building units. • Three types of potential proton-carriers have been assembled in the 1D hydrophilic channels of the POM–MOF. • It achieved such proton conductivities as 10⁻⁴–10⁻³ S cm⁻¹ at 100 °C in the RH range 35–98%.

  12. Femur fracture repair - discharge

    MedlinePlus

    ... McCormack RG, Lopez CA. Commonly encountered fractures in sports medicine. In: Miller MD, Thompson SR, eds. DeLee and Drez's Orthopaedic Sports Medicine. 4th ed. Philadelphia, PA: Elsevier Saunders; 2015:chap ...

  13. Metatarsal stress fractures - aftercare

    MedlinePlus

    ... McCormack RG, Lopez CA. Commonly encountered fractures in sports medicine. In: Miller MD, Thompson SR, eds. DeLee and Drez's Orthopaedic Sports Medicine . 4th ed. Philadelphia, PA: Saunders Elsevier; 2014:chap. ...

  14. Clavicle Fracture (Broken Collarbone)

    MedlinePlus

    ... place and the fragments are severely out of alignment. A large bump over the fracture site may ... bone fragments are first repositioned into their normal alignment, and then held in place with special screws ...

  15. Sprains, Strains and Fractures

    MedlinePlus

    ... are useful for finding soft issue injuries (including torn ligaments) and stress fractures. Treatment will depend on ... weeks. Professional athletes may undergo surgery to repair torn ligaments. Oral anti-inflammatory medication, such as ibuprofen, ...

  16. Lisfranc (Midfoot) Fractures

    MedlinePlus

    ... broken or ligaments that support the midfoot are torn. The severity of the injury can vary from ... bones are broken (fractured) or the ligaments are torn (ruptured). Injuries can vary, from a simple injury ...

  17. Ankle fracture - aftercare

    MedlinePlus

    ... page: //medlineplus.gov/ency/patientinstructions/000548.htm Ankle fracture - aftercare To use the sharing features on this ... Sit with your foot elevated higher than your knee at least 4 times a day Apply an ...

  18. Fractures in medieval Scotland.

    PubMed

    MacLennan, W J

    2001-04-01

    The prevalence of fractures in medieval Scotland is assessed, particular attention being given to excavations of cemeteries beside three Carmelite cemeteries, at Aberdeen, Perth and Linlithgow, and another one at Whithorn Abbey. In the friaries the prevalence of fractures was 7.6% and in Whithorn it was 5.0%. These figures are comparable with an estimated prevalence of 7.2% for individuals between 0 and 65 years in present day Scotland. Males were more at risk of fractures than females, but a small group from both genders had been struck on the head by weapons. A study from a rural cemetery in England indicates that both male and female peasants had a much higher risk of fractures than their urban counterparts. PMID:11394343

  19. Suspensions in hydraulic fracturing

    SciTech Connect

    Shah, S.N.

    1996-12-31

    Suspensions or slurries are widely used in well stimulation and hydraulic fracturing processes to enhance the production of oil and gas from the underground hydrocarbon-bearing formation. The success of these processes depends significantly upon having a thorough understanding of the behavior of suspensions used. Therefore, the characterization of suspensions under realistic conditions, for their rheological and hydraulic properties, is very important. This chapter deals with the state-of-the-art hydraulic fracturing suspension technology. Specifically it deals with various types of suspensions used in well stimulation and fracturing processes, their rheological characterization and hydraulic properties, behavior of suspensions in horizontal wells, review of proppant settling velocity and proppant transport in the fracture, and presently available measurement techniques for suspensions and their merits. Future industry needs for better understanding of the complex behavior of suspensions are also addressed. 74 refs., 21 figs., 1 tab.

  20. Treating Tibia Fractures With Far Cortical Locking Implants.

    PubMed

    Rice, Christopher; Christensen, Thomas; Bottlang, Michael; Fitzpatrick, Dan; Kubiak, Erik

    2016-01-01

    Compared with conventional plating, the relatively new technology of far cortical locking (FCL) allows for more flexible fixation. Increased flexibility of FCL constructs is thought to better stimulate secondary osteosynthesis and lead to improved healing for certain fracture patterns. We conducted a study to compare healing rates and complications of tibial fractures treated with FCL or standard plating techniques. Twenty-two patients with fractures of the tibia (Orthopaedic Trauma Association 41ABC, 42C, 43C) were included in the study. Twelve tibia fractures were treated with FCL and 10 with standard plating (locking or nonlocking). Mean follow-up was 47 weeks in the FCL group and 41 weeks in the control group. The fracture healing rate was 92% in the FCL group and 100% in the control group (difference not statistically significant). Of note, there were 2 open fractures in the FCL group and 0 in the control group. The groups had similar complication rates. Our study data suggest FCL implants are not inferior to conventional plating techniques. Given that FCL-treated fractures tended to be more complex, the groups' similar fracture healing rates may indicate improved fracture healing with FCL technology, but this possibility requires further investigation. PMID:26991582

  1. Evaluation of borehole electromagnetic and seismic detection of fractures

    SciTech Connect

    Chang, H.T.; Suhler, S.A.; Owen, T.E.

    1984-02-01

    Experiments were conducted to establish the feasibility of downhole high-frequency techniques for location of fractures in the vicinity of boreholes. An existing flame-cut slot in granite was filled with salt water to simulate a brine-filled fracture. The first method used an electromagnetic wave at 30 to 300 MHz, vhf frequencies. A transmitter consisting of a phased dual-dipole array arranged to provide a directional signal toward the fracture was installed in a borehole opposite the fracture. A receiver was also located in the same borehole. The radar returns from the simulated fracture were detectable in boreholes located at distances of up to 12 meters from the fracture. These results indicate for the first time the feasibility of a downhole vhf radar for use in a single borehole for detection of fractures located away from the borehole. Similar experiments were also conducted using seismic waves at 4.5 to 6 KHz. The transmitter and the receiver in this case were located in separate boreholes. During this experiment, reflections from the slot were obtained only with the transducers oriented for shear wave illumination and detection. These results suggest that a high-frequency shear wave can also be used to detect fractures away from a borehole.

  2. Effect of Surface Wettability on Nonlinear Flow in a Rough-Walled Fracture

    NASA Astrophysics Data System (ADS)

    Lee, H.; Yeo, I.; Park, J.; Lee, K.

    2005-12-01

    The understanding of flow behavior in rock fractures is essential to the analysis of water flow, solute transport and DNAPL migration and remediation in rock fractures. DNAPL migration and remediation in rock fractures has been an emerging issue due to its serious contamination problem and the difficulty in dealing with DNAPL trapped in rock fractures. It has been reported that while DNAPL migrates through rock fractures, DNAPL may be trapped on rock surfaces due to variable apertures and dead-end fractures, and may also change the surface wettability of rock fractures from hydrophilic to hydrophobic. In this study, the effect of surface wettability on water flow in rock fractures has been investigated. A glass replica of a real rough-walled fracture was made, and the fracture surface was brushed with corn oil to make the fracture surface hydrophobic. The corn oil was wiped off with tissues many times, to eliminate the oil remnants on the surface. Flow tests were conducted on the oil-wet fracture surface. Then, the surface was completely washed out with the cleaning agents to make the fracture surface hydrophilic, which was confirmed through contact angle measurements. Flow tests were repeated for the water-wet fracture surface. Flow tests were also carried out for a parallel glass plate fracture over the same water- and oil-wet surface conditions as in the rough fracture. In the parallel plate fracture, the hydraulic aperture from the oil-wet surface was only two percent higher that that of the water-wet surface, which indicated that the initial aperture of the fracture might not decrease by the corn-oil coating. Both oil- and water-wet surfaces of the parallel plate showed a linear flow regime, up to Reynolds number of 400. In the case of the rough fracture, the hydraulic aperture of the oil-wet fracture surface was smaller than that of the water-wet fracture surface. For the water-wet fracture surface, the non-linear flow started at Reynolds number less than 30

  3. Hydraulic Fracture Propagation through Preexisting Discontinuity Monitored by Acoustic Emission and Ultrasonic Transmission

    NASA Astrophysics Data System (ADS)

    Stanchits, S.; Lund, J.; Surdi, A.; Edelman, E.; Whitney, N.; Eldredge, R.; Suarez-Rivera, R.

    2011-12-01

    Hydraulic fracturing is critical to enhance hydrocarbon production from ultra-low permeability unconventional reservoirs, and is the common completion methodology for tight formations around the world. Unfortunately, these reservoirs are often highly heterogeneous and their heterogeneity imparts a degree of geometrical complexity in hydraulic fractures that is poorly understood. Fracture complexity (e.g. branching) results in higher surface area and could be beneficial to production provided it remains conductive. Understanding the sources and consequences of fracture complexity is thus of high importance to completion and production operations. In this study we postulate that textural complexity in tight heterogeneous formations induces fracture complexity, and that the main sources of textural complexity are associated with veins, bed boundaries, lithologic contacts, and geologic interfaces. We thus study the effect of interfaces on hydraulic fracture propagation under laboratory conditions by Acoustic Emission (AE) and Ultrasonic Transmission (UT) monitoring techniques. The experiments were conducted on low permeability sandstone blocks of 279 x 279 x 381 mm length with saw cut discontinuities oriented orthogonally to the expected direction of fracture propagation. The rock is loaded in a poly-axial test frame to representative effective in-situ stress conditions of normal and deviatoric stress. Hydraulic fracturing was initiated by injection of silicon oil into a borehole drilled off center from the block. Acoustic emission (AE) events were continuously monitored during testing using nineteen P-wave sensors. Additional sensors were installed to periodically monitor ultrasonic transmission (UT) along various directions oblique and perpendicular to the fracture and the interface. The AE and UT data were recorded using a Vallen AMSY-6 system, with 16-bit amplitude resolution and 5 MHz sampling rate. Detailed analysis of AE localizations allowed us to identify

  4. Veining Failure and Hydraulic Fracturing in Shales

    NASA Astrophysics Data System (ADS)

    Mighani, S.; Sondergeld, C. H.; Rai, C. S.

    2014-12-01

    During the hydraulic fracturing, the pressurized fluid creates new fractures and reactivates existing natural fractures forming a highly conductive Stimulated Reservoir Volume (SRV) around the borehole. We extend the previous work on Lyons sandstone and pyrophyllite to anisotropic shale from the Wolfcamp formation. We divide the rock anisotropy into two groups: a) conventional and b) unconventional (shaly) anisotropy. X-ray Computed Tomography (CT), compressional velocity anisotropy, and SEM analysis are used to identify three causes of anisotropy: bedding planes, clay lamination, and calcite veins. Calcite vein is a subsequently filled with calcite bonded weakly to the matrix. Velocity anisotropy and visual observations demonstrate the calcite filled veins to be mostly subparallel to the fabric direction. Brazilian tests are carried out to observe the fracture initiation and propagation under tension. High speed photography (frame rate 300,000 frame/sec) was used to capture the failure. Strain gauges and Acoustic Emission (AE) sensors recorded the deformation leading up to and during failure. SEM imaging and surface profilometry were employed to study the post-failure fracture system and failed surface topology. Fracture permeability was measured as a function of effective stress. Brazilian tests on small disks containing a centered single vein revealed the shear strength of the veins. We interpret the strain data and number, frequency, and amplitude of AE events which are correlated well with the observed fracture process zone, surface roughness, and permeability. The unpropped fracture has enhanced permeability by two orders of magnitude. The observed anisotropic tensile failure seems to have a universal trend with a minimum strength occurring at 15o orientation with respect to the loading axis. The veins at 15o orientation with respect to the loading axis were easily activated at 30% of the original failure load. The measured strength of the vein is as low as 6

  5. Dynamic fracture toughness

    NASA Technical Reports Server (NTRS)

    Kobayashi, A. S.; Ramulu, M.; Dadkhah, M. S.; Yang, K.-H.; Kang, B. S. J.

    1986-01-01

    Dynamic fracture toughness versus crack velocity relations of Homalite-100, polycarbonate, hardened 4340 steel and reaction bonded silicon nitride are reviewed and discrepancies with published data and their probable causes are discussed. Data scatter in published data are attributed in part to the observed fluctuations in crack velocities. The results reaffirmed our previous conclusion that the dynamic fracture toughness versus crack velocity relation is specimen dependent and that the dynamic arrest stress intensity factor is not a unique material property.

  6. Relative permeability through fractures

    SciTech Connect

    Diomampo, Gracel, P.

    2001-08-01

    The mechanism of two-phase flow through fractures is of importance in understanding many geologic processes. Currently, two-phase flow through fractures is still poorly understood. In this study, nitrogen-water experiments were done on both smooth and rough parallel plates to determine the governing flow mechanism for fractures and the appropriate methodology for data analysis. The experiments were done using a glass plate to allow visualization of flow. Digital video recording allowed instantaneous measurement of pressure, flow rate and saturation. Saturation was computed using image analysis techniques. The experiments showed that gas and liquid phases flow through fractures in nonuniform separate channels. The localized channels change with time as each phase path undergoes continues breaking and reforming due to invasion of the other phase. The stability of the phase paths is dependent on liquid and gas flow rate ratio. This mechanism holds true for over a range of saturation for both smooth and rough fractures. In imbibition for rough-walled fractures, another mechanism similar to wave-like flow in pipes was also observed. The data from the experiments were analyzed using Darcy's law and using the concept of friction factor and equivalent Reynold's number for two-phase flow. For both smooth- and rough-walled fractures a clear relationship between relative permeability and saturation was seen. The calculated relative permeability curves follow Corey-type behavior and can be modeled using Honarpour expressions. The sum of the relative permeabilities is not equal one, indicating phase interference. The equivalent homogeneous single-phase approach did not give satisfactory representation of flow through fractures. The graphs of experimentally derived friction factor with the modified Reynolds number do not reveal a distinctive linear relationship.

  7. IPIRG programs - advances in pipe fracture technology

    SciTech Connect

    Wilkowski, G.; Olson, R.; Scott, P.

    1997-04-01

    This paper presents an overview of the advances made in fracture control technology as a result of the research performed in the International Piping Integrity Research Group (IPIRG) program. The findings from numerous experiments and supporting analyses conducted to investigate the behavior of circumferentially flawed piping and pipe systems subjected to high-rate loading typical of seismic events are summarized. Topics to be discussed include; (1) Seismic loading effects on material properties, (2) Piping system behavior under seismic loads, (3) Advances in elbow fracture evaluations, and (4) {open_quotes}Real{close_quotes} piping system response. The presentation for each topic will be illustrated with data and analytical results. In each case, the state-of-the-art in fracture mechanics prior to the first IPIRG program will be contrasted with the state-of-the-art at the completion of the IPIRG-2 program.

  8. Orthobiologics in the augmentation of osteoporotic fractures.

    PubMed

    Watson, J Tracy; Nicolaou, Daemeon A

    2015-02-01

    Many orthobiologic adjuvants are available and widely utilized for general skeletal restoration. Their use for the specific task of osteoporotic fracture augmentation is less well recognized. Common conductive materials are reviewed for their value in this patient population including the large group of allograft adjuvants categorically known as the demineralized bone matrices (DBMs). Another large group of alloplastic materials is also examined-the calcium phosphate and sulfate ceramics. Both of these materials, when used for the proper indications, demonstrate efficacy for these patients. The inductive properties of bone morphogenic proteins (BMPs) and platelet concentrates show no clear advantages for this group of patients. Systemic agents including bisphosphonates, receptor activator of nuclear factor κβ ligand (RANKL) inhibitors, and parathyroid hormone augmentation all demonstrate positive effects with this fracture cohort. Newer modalities, such as trace ion bioceramic augmentation, are also reviewed for their positive effects on osteoporotic fracture healing. PMID:25431160

  9. Thermodynamic transient behavior of a geothermal fracture

    SciTech Connect

    Ascencio, F.; Samaniego, F.; Cinco-Ley, H.; Rivera, J.

    1995-01-26

    This paper presents a space integrated zero dimensional model that describes the thermodynamic behavior of a geothermal fracture undergoing exploitation. The main assumptions involved are: fluid and energy entering the fracture come from the surrounding matrix, fracture of infinite conductivity, and that the steam and water phases are gravitationally segregated and in thermodynamic equilibrium. The nonlinear equations of mass and energy conservation are numerically solved. A sensitivity analysis on the main parameters that affect this problem was carried out. Water recharge is described by a linear infinite aquifer, and heat flow from the matrix to the fluid was also considered by means of a linear infinite system. The behavior of the system is clearly described for conditions of exploitation in the steam, in the water, or mixed completion in both steam and water zones.

  10. SIZE SCALING RELATIONSHIPS IN FRACTURE NETWORKS

    SciTech Connect

    Thomas H. Wilson

    2000-01-01

    The research conducted under DOE grant DE-FG26-98FT40385 provides a detailed assessment of size scaling issues in natural fracture and active fault networks that extend over scales from several tens of kilometers to less than a tenth of a meter. This study incorporates analysis of data obtained from several sources, including: natural fracture patterns photographed in the Appalachian field area, natural fracture patterns presented by other workers in the published literature, patterns of active faulting in Japan mapping at a scale of 1:100,000, and lineament patterns interpreted from satellite-based radar imagery obtained over the Appalachian field area. The complexity of these patterns is always found to vary with scale. In general,but not always, patterns become less complex with scale. This tendency may reverse as can be inferred from the complexity of high-resolution radar images (8 meter pixel size) which are characterized by patterns that are less complex than those observed over smaller areas on the ground surface. Model studies reveal that changes in the complexity of a fracture pattern can be associated with dominant spacings between the fractures comprising the pattern or roughly to the rock areas bounded by fractures of a certain scale. While the results do not offer a magic number (the fractal dimension) to characterize fracture networks at all scales, the modeling and analysis provide results that can be interpreted directly in terms of the physical properties of the natural fracture or active fault complex. These breaks roughly define the size of fracture bounded regions at different scales. The larger more extensive sets of fractures will intersect and enclose regions of a certain size, whereas smaller less extensive sets will do the same--i.e. subdivide the rock into even smaller regions. The interpretation varies depending on the number of sets that are present, but the scale breaks in the logN/logr plots serve as a guide to interpreting the

  11. Microbial processes in fractured rock environments

    NASA Astrophysics Data System (ADS)

    Kinner, Nancy E.; Eighmy, T. Taylor; Mills, M.; Coulburn, J.; Tisa, L.

    Little is known about the types and activities of microbes in fractured rock environments, but recent studies in a variety of bedrock formations have documented the presence of a diverse array of prokaryotes (Eubacteria and Archaea) and some protists. The prokaryotes appear to live in both diffusion-dominated microfractures and larger, more conductive open fractures. Some of the prokaryotes are associated with the surfaces of the host rock and mineral precipitates, while other planktonic forms are floating/moving in the groundwater filling the fractures. Studies indicate that the surface-associated and planktonic communities are distinct, and their importance in microbially mediated processes occurring in the bedrock environment may vary, depending on the availability of electron donors/acceptors and nutrients needed by the cells. In general, abundances of microbes are low compared with other environments, because of the paucity of these substances that are transported into the deeper subsurface where most bedrock occurs, unless there is significant pollution with an electron donor. To obtain a complete picture of the microbes present and their metabolic activity, it is usually necessary to sample formation water from specific fractures (versus open boreholes), and fracture surfaces (i.e., cores). Transport of the microbes through the major fracture pathways can be rapid, but may be quite limited in the microfractures. Very low abundances of small ( 2-3 μm) flagellated protists, which appear to prey upon planktonic bacteria, have been found in a bedrock aquifer. Much more research is needed to expand the understanding of all microbial processes in fractured rock environments.

  12. Laboratory Scale Hydraulic Fracture and Proppant Injection

    NASA Astrophysics Data System (ADS)

    Ingraham, M. D.; Rao, R. R.; Bolintineanu, D.; Lechman, J. B.; Bauer, S. J.; Quintana, E.

    2015-12-01

    A series of fracture and proppant injection tests have been conducted on Marcellus shale from an outcrop in Pennsylvania at the laboratory scale. The shale outcrop was recently exposed by new construction and shows little sign of weathering. Specimens 3 inches in diameter and nominally 6 inches long were cored (parallel to bedding) from blocks taken from the outcrop. A 3 inch hole was then cored down the center of the specimen and "cased" with 0.25 inch high pressure tubing, leaving 0.75 inches of space at the bottom of the borehole uncased. Specimens were then loaded under in an axisymmetric extension stress state and hydraulically fractured in order to generate the appropriate fracture orientation to represent the opening of a fracture in a typical long horizontal well, where fractures are "disks on a string." After fracture with water, while still under stress, a guar/proppant mixture was injected into the specimen to investigate the distribution of proppant in the fracture. Silicon carbide particles were used as proppant to assist in proppant visualization in microCT scans performed after the test was completed. Corresponding numerical analyses (using the finite element method) of the flow path and particle transport are underway, coupled with idealized flow experiments to validate the codes being used to model the particle transport. Some of the meshes being used were developed directly from CT scans. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2015-6111 A.

  13. Monitoring hydraulic fracturing with seismic emission volume

    NASA Astrophysics Data System (ADS)

    Niu, F.; Tang, Y.; Chen, H.; TAO, K.; Levander, A.

    2014-12-01

    Recent developments in horizontal drilling and hydraulic fracturing have made it possible to access the reservoirs that are not available for massive production in the past. Hydraulic fracturing is designed to enhance rock permeability and reservoir drainage through the creation of fracture networks. Microseismic monitoring has been proven to be an effective and valuable technology to image hydraulic fracture geometry. Based on data acquisition, seismic monitoring techniques have been divided into two categories: downhole and surface monitoring. Surface monitoring is challenging because of the extremely low signal-to-noise ratio of the raw data. We applied the techniques used in earthquake seismology and developed an integrated monitoring system for mapping hydraulic fractures. The system consists of 20 to 30 state-of-the-art broadband seismographs, which are generally about hundreds times more sensible than regular geophones. We have conducted two experiments in two basins with very different geology and formation mechanism in China. In each case, we observed clear microseismic events, which may correspond to the induced seismicity directly associated with fracturing and the triggered ones at pre-existing faults. However, the magnitude of these events is generally larger than magnitude -1, approximately one to two magnitudes larger than those detected by downhole instruments. Spectrum-frequency analysis of the continuous surface recordings indicated high seismic energy associated with injection stages. The seismic energy can be back-projected to a volume that surrounds each injection stage. Imaging seismic emission volume (SEV) appears to be an effective way to map the stimulated reservior volume, as well as natural fractures.

  14. Hybrid fracture and the transition from extension fracture to shear fracture.

    PubMed

    Ramsey, Jonathan M; Chester, Frederick M

    2004-03-01

    Fracture is a fundamental mechanism of material failure. Two basic types of brittle fractures are commonly observed in rock deformation experiments--extension (opening mode) fractures and shear fractures. For nearly half a century it has been hypothesized that extension and shear fractures represent end-members of a continuous spectrum of brittle fracture types. However, observations of transitional fractures that display both opening and shear modes (hybrids) in naturally deformed rock have often remained ambiguous, and a clear demonstration of hybrid fracture formation has not been provided by experiments. Here we present the results of triaxial extension experiments on Carrara marble that show a continuous transition from extension fracture to shear fracture with an increase in compressive stress. Hybrid fractures form under mixed tensile and compressive stress states at acute angles to the maximum principal compressive stress. Fracture angles are greater than those observed for extension fractures and less than those observed for shear fractures. Fracture surfaces also display a progressive change from an extension to shear fracture morphology. PMID:14999279

  15. FRACTURING FLUID CHARACTERIZATION FACILITY

    SciTech Connect

    Subhash Shah

    2000-08-01

    Hydraulic fracturing technology has been successfully applied for well stimulation of low and high permeability reservoirs for numerous years. Treatment optimization and improved economics have always been the key to the success and it is more so when the reservoirs under consideration are marginal. Fluids are widely used for the stimulation of wells. The Fracturing Fluid Characterization Facility (FFCF) has been established to provide the accurate prediction of the behavior of complex fracturing fluids under downhole conditions. The primary focus of the facility is to provide valuable insight into the various mechanisms that govern the flow of fracturing fluids and slurries through hydraulically created fractures. During the time between September 30, 1992, and March 31, 2000, the research efforts were devoted to the areas of fluid rheology, proppant transport, proppant flowback, dynamic fluid loss, perforation pressure losses, and frictional pressure losses. In this regard, a unique above-the-ground fracture simulator was designed and constructed at the FFCF, labeled ''The High Pressure Simulator'' (HPS). The FFCF is now available to industry for characterizing and understanding the behavior of complex fluid systems. To better reflect and encompass the broad spectrum of the petroleum industry, the FFCF now operates under a new name of ''The Well Construction Technology Center'' (WCTC). This report documents the summary of the activities performed during 1992-2000 at the FFCF.

  16. Treatment of Thoracolumbar Fracture

    PubMed Central

    Kim, Byung-Guk; Shin, Dong-Eun

    2015-01-01

    The most common fractures of the spine are associated with the thoracolumbar junction. The goals of treatment of thoracolumbar fracture are leading to early mobilization and rehabilitation by restoring mechanical stability of fracture and inducing neurologic recovery, thereby enabling patients to return to the workplace. However, it is still debatable about the treatment methods. Neurologic injury should be identified by thorough physical examination for motor and sensory nerve system in order to determine the appropriate treatment. The mechanical stability of fracture also should be evaluated by plain radiographs and computed tomography. In some cases, magnetic resonance imaging is required to evaluate soft tissue injury involving neurologic structure or posterior ligament complex. Based on these physical examinations and imaging studies, fracture stability is evaluated and it is determined whether to use the conservative or operative treatment. The development of instruments have led to more interests on the operative treatment which saves mobile segments without fusion and on instrumentation through minimal invasive approach in recent years. It is still controversial for the use of these treatments because there have not been verified evidences yet. However, the morbidity of patients can be decreased and good clinical and radiologic outcomes can be achieved if the recent operative treatments are used carefully considering the fracture pattern and the injury severity. PMID:25705347

  17. Towards improved 3D cross-borehole electrical resistivity imaging of discrete fracture networks

    NASA Astrophysics Data System (ADS)

    Robinson, J.; Slater, L. D.; Johnson, T. J.; Ntarlagiannis, D.; Lacombe, P.; Johnson, C. D.; Tiedeman, C. R.; Goode, D.; Day-Lewis, F. D.; Shapiro, A. M.; Lane, J. W.

    2012-12-01

    There is a need to better characterize discrete fractures in contaminated bedrock aquifers to determine the migration of injected remediation amendments away from boreholes. A synthetic cross-borehole electrical resistivity study was conducted assuming a discrete fracture model of an existing contaminated site with known fracture locations. Four boreholes and two discrete fracture zones, assumed to be the dominant electrical and hydraulically conductive pathways, were explicitly modeled within an unstructured tetrahedral finite-element mesh. To simulate field conditions, 5% random Gaussian noise was added to all synthetic datasets. We first evaluated different regularization constraints starting with an uninformed smoothness-constrained inversion, to which a priori information was incrementally added. We found major improvements when (1) smoothness regularization constraints were relaxed (or disconnected) along boreholes and fractures, (2) a homogeneous conductivity was assumed along boreholes, and (3) borehole conductivity constraints, which could be determined from a fluid specific-conductance log, were applied. We also evaluated the effect of including borehole packers on the fracture-zone model recovery. We found the estimated fracture-zone conductivities with the inclusion of packers were comparable to similar trials excluding the use of packers regardless of electrical potential changes. The misplacement of fracture regularization disconnects easily can be misinterpreted as actual fracture locations. Conductivities within misplaced disconnects were near the starting model value and removing smoothing between boreholes and assumed fracture locations helped in identifying incorrectly located fracture regularization disconnects. Model sensitivity structure improved when regularization disconnects were (1) applied along the boreholes and fracture zones, and (2) fracture-zone regularization disconnects were placed where actual fractures existed. A field study

  18. Hyponatremia and Fractures: Findings from the Osteoporotic Fractures in Men Study

    PubMed Central

    Jamal, Sophie A; Arampatzis, Spyridon; Harrison, Stephanie Litwack; Bucur, Roxana C; Ensrud, Kristine; Orwoll, Eric S; Bauer, Douglas C

    2015-01-01

    Hyponatremia may be a risk factor for fracture. To determine the relationship between hyponatremia and fracture we conducted cross-sectional and longitudinal analyses using data from the Osteoporotic Fractures in Men Study (MrOS). The MrOS study enrolled 5122 community dwelling men aged ≥ 65 years from six centers across the United States. We excluded men taking bisphosphonates, those with unknown medication history, those without serum sodium measures, or those with out of range assays for serum sodium. Serum sodium was measured at study entry. Subjects were followed for fractures (nonspine (including hip), hip, and incident and prevalent morphometric) for up to 9 years. We used cox proportional hazards models to analyze the association between serum sodium levels (<135mmol/L versus ≥135mmol/L) and risk of nonspine and hip fractures, with results presented as hazard ratios (HR) and 95% confidence intervals (CI). We examined the association between morphometric vertebral fractures and serum sodium using logistic regression models, presented as odds ratios (OR) and 95% CI. Hyponatremia was observed in 64 men (1.2% of the cohort). After adjusting for age, BMI, study center, and other covariates, we found that, compared to men with serum sodium ≥ 135mmol/L, those with serum sodium <135mmol/L, had an increased risk hip fracture (HR=3.04; 95% CI: 1.37 to 6.75), prevalent (OR=2.46; 95% CI: 1.22 to 4.95) and incident (OR=3.53; 95% CI: 1.35 to 9.19) morphometric spine fractures but not nonspine fractures (OR=1.44; 95% CI: 0.85 to 2.44). Adjusting for bone mineral density did not change our findings. Our data demonstrate that hyponatremia is associated with up to a doubling in the risk of hip and morphometric spine fractures, independent of BMD. Further studies, to determine how hyponatremia causes fractures and if correction of hyponatremia decreases fractures, are needed. PMID:25294595

  19. Fracturing fluids for low temperature wells

    SciTech Connect

    Montgomery, C.T.; Dollarhide, F.E.

    1980-01-01

    Highly viscous fluids are used to initiate and propagate fractures and to place proppant in the fractures during the hydraulic stimulation process. These fluids can cause damage to the conductivity of the induced fractures if they are not properly cleaned out after the fracturing treatment. The clean-up process is aided by the degradation of the polymers, and in low temperature wells the breakdown of the polymer must be chemically induced. This work presents data on a new fracturing fluid aimed specifically at stimulating low temperature and low pressure reservoirs. The system consists of a CO/sub 2/-energized, cross-linked hydroxypropyl guar fluid. The gel is degraded by a traditional breaker that is activated by a new, low temperature breaker activator. The fluid is effective in wells as cool as 60 F and with bhp as low as 100 psi and should be particularly applicable to the shallow gas wells in the Alberta Medicine Hat and high level Keg River areas.

  20. Computer Simulation of Fracture in Aerogels

    NASA Technical Reports Server (NTRS)

    Good, Brian S.

    2006-01-01

    Aerogels are of interest to the aerospace community primarily for their thermal properties, notably their low thermal conductivities. While the gels are typically fragile, recent advances in the application of conformal polymer layers to these gels has made them potentially useful as lightweight structural materials as well. In this work, we investigate the strength and fracture behavior of silica aerogels using a molecular statics-based computer simulation technique. The gels' structure is simulated via a Diffusion Limited Cluster Aggregation (DLCA) algorithm, which produces fractal structures representing experimentally observed aggregates of so-called secondary particles, themselves composed of amorphous silica primary particles an order of magnitude smaller. We have performed multi-length-scale simulations of fracture in silica aerogels, in which the interaction b e e n two secondary particles is assumed to be described by a Morse pair potential parameterized such that the potential range is much smaller than the secondary particle size. These Morse parameters are obtained by atomistic simulation of models of the experimentally-observed amorphous silica "bridges," with the fracture behavior of these bridges modeled via molecular statics using a Morse/Coulomb potential for silica. We consider the energetics of the fracture, and compare qualitative features of low-and high-density gel fracture.

  1. Analytical solutions of solute transport in a fracture-matrix system with different reaction rates for fracture and matrix

    NASA Astrophysics Data System (ADS)

    Zhu, Yonghui; Zhan, Hongbin; Jin, Menggui

    2016-08-01

    This study deals with the problem of reactive solute transport in a fracture-matrix system using both analytical and numerical modeling methods. The groundwater flow velocity in the fracture is assumed to be high enough (no less than 0.1 m/day) to ensure the advection-dominant transport in the fracture. The problem includes advection along the fracture, transverse diffusion in the matrix, with linear sorption as well as first-order reactions operative in both the fracture and the matrix. A constant-concentration boundary condition and a decay source boundary condition in the fracture are considered. With a constant-concentration source, we obtain closed-form analytical solutions that account for the transport without reaction as well as steady-state solutions with different first-order reactions in the two media. With a decay source, a semi-analytical solution is obtained. The analytical and semi-analytical solutions are in excellent agreement with the numerical simulation results obtained using COMSOL Multiphysics. Sensitivity analysis is conducted to assess the relative importance of matrix diffusion coefficient, fracture aperture, and matrix porosity. We conclude that the first-order reaction as well as the matrix diffusion in the fractured rock would decrease the solute peak concentration and shorten the penetration distance into the fracture. The solutions can be applied to assess the spatial-temporal distribution of concentrations in the fracture and the matrix as well as to assess the contaminant mass stored in the rock matrix. All of these are useful for designing remediation plans for contaminated fractured rocks or for risk assessment of contaminated fracture-matrix systems.

  2. Workflow Integrating Fracture Permeability Characterization and Multiphase Flow Modeling for CO2 Storage and Risk Assessments in Fractured Reservoirs

    NASA Astrophysics Data System (ADS)

    Jin, G.; Pashin, J. C.

    2014-12-01

    Ensuring safe and permanent storage of sequestered CO2in naturally fractured geological media is vital for the success of geologic storage projects. Critical needs exist to develop advanced techniques to characterize and model fluid transport in naturally fractured reservoirs and seals. We have developed a scale-independent 3-D stochastic fracture permeability characterization workflow that employs multiple discrete fracture network (DFN) realizations. The workflow deploys a multidirectional flux-based upwind weighting scheme that is capable of modeling multiphase flow in highly heterogeneous fractured media. The techniques employed herein show great promise for increasing the accuracy of capacity determinations and the prediction of pressure footprints associated with injected CO2 plumes. The proposed workflow has been conducted in a simulation study of flow transport and risk assessment of CO2 injection into a deep fractured saline formation using geological parameters from Knox Group carbonate and Red Mountain shale rocks in central Alabama. A 3-D fracture permeability map was generated from multiple realizations of DFN models. A multiphase flow model composed of supercritical CO2 and saline water was applied to simulate CO2 plume evolution during and after injection. Injection simulation reveals significant permeability anisotropy that favors development of northeast-elongate CO2 plumes. The spreading front of the CO2 plume shows strong viscous fingering effects. Post-injection simulation indicates significant lateral spreading of CO2 near the top of the fractured formations because of the buoyancy of injectate in rock matrix and strata-bound vertical fractures. Risk assessment shows that although pressure drops faster in the fractured formations than in those lacking fractures, lateral movement of CO2 along natural fractures necessitates that the injectate be confined by widespread seals with high integrity.

  3. Appropriate Conduct

    ERIC Educational Resources Information Center

    Di Lullo, Louis

    2004-01-01

    Many years ago when the author assumed the role of assistant principal for school climate, discipline, and attendance, he inherited many school policies and guidelines that were outdated, unfair, and without merit in the current school climate. Because the school conduct code had not been revised since the school opened in 1960, many of the…

  4. Conducting Meetings.

    ERIC Educational Resources Information Center

    United Tribes Educational Technical Center, Bismarck, ND.

    Written for anyone interested in what makes a meeting run smoothly (and what doesn't), the guide for conducting meetings is divided into the following sections: the chairperson (his/her responsibilities, preparing an agenda, organizing discussions); the meeting (quorums, discussions, points of order, and clarification); the motion (making the…

  5. Calculation Method and Distribution Characteristics of Fracture Hydraulic Aperture from Field Experiments in Fractured Granite Area

    NASA Astrophysics Data System (ADS)

    Cao, Yang-Bing; Feng, Xia-Ting; Yan, E.-Chuan; Chen, Gang; Lü, Fei-fei; Ji, Hui-bin; Song, Kuang-Yin

    2016-05-01

    Knowledge of the fracture hydraulic aperture and its relation to the mechanical aperture and normal stress is urgently needed in engineering construction and analytical research at the engineering field scale. A new method based on the in situ borehole camera measurement and borehole water-pressure test is proposed for the calculation of the fracture hydraulic aperture. This method comprises six steps. The first step is to obtain the equivalent hydraulic conductivity of the test section from borehole water-pressure tests. The second step is a tentative calculation to obtain the qualitative relation between the reduction coefficient and the mechanical aperture obtained from borehole camera measurements. The third step is to choose the preliminary reduction coefficient for obtaining the initial hydraulic aperture. The remaining three steps are to optimize, using the genetic algorithm, the hydraulic apertures of fractures with high uncertainty. The method is then applied to a fractured granite engineering area whose purpose is the construction of an underground water-sealed storage cavern for liquefied petroleum gas. The probability distribution characteristics of the hydraulic aperture, the relationship between the hydraulic aperture and the mechanical aperture, the hydraulic aperture and the normal stress, and the differences between altered fractures and fresh fractures are all analyzed. Based on the effects of the engineering applications, the method is proved to be feasible and reliable. More importantly, the results of the hydraulic aperture obtained in this paper are different from those results elicited from laboratory tests, and the reasons are discussed in the paper.

  6. Protection of 2-(3-Thienyl)ethanol with 3-Thienylacetic Acid and Hard Cross- Linked Conducting Films by Electropolymerization of the Ester

    NASA Technical Reports Server (NTRS)

    Leventis, Nicholas; Dass, Amala; Mulik, Sudir; Sotiriou-Leventis, Chariklia

    2005-01-01

    The ester (compound 1) of 2-(3-thienyl)ethanol (T-etOH) with 3-thienylacetic acid was synthesized as a monomer whose two thiophene groups could be electropolymerized independently, becoming members of different polymer chains in a highly-crosslinked highly-insoluble polymer. Indeed, 1 was electropolymerized successfully alone and together with 3-methylthiophene (3MeT). Films of poly(1) are hard (3H, as opposed to less than 6B for poly(3MeT)), and the close proximity of the polymeric strands creates pi-stacking interactions. The behavior of 1 suggests that by: (a) limiting the potential used for the oxidation of monomeric esters of T-etOH at the foot of their oxidation waves (less than 1.8 V vs. Ag/AgCl); and, (b) compensating for the decrease in the electrogenerated radical concentration by increasing the monomer concentration, practically all esters of T-etOH should be electropolymerizable. This was confirmed by durable film formation from the archetypical ester of T-etOH, the 2-(3-thienyl)ethyl acetate (T-etOAc), whose homo-electropolymerization is reported for the first time.

  7. Recent developments in analysis of crack propagation and fracture of practical materials

    NASA Technical Reports Server (NTRS)

    Hardrath, H. F.; Newman, J. C., Jr.; Elber, W.; Poe, C. C., Jr.

    1978-01-01

    Present U.S. Air Force and proposed U.S. civil airworthiness regulations are based on considerations of 'damage tolerance' in aircraft structures. Airworthiness is assured by demonstrating that damage that escapes one in a sequence of periodic inspections will not grow to critical size before the next inspection. The evaluations conducted employ fracture mechanics analyses. Problems arise because the features of fracture mechanics applications related to aircraft structures are more complex than the cases of fracture mechanics which have been mainly investigated. NASA has, therefore, conducted a variety of research tasks to extend the capabilities of fracture mechanics to deal with some of these complexities. The current stage of development of these capabilities is described. Attention is given to the limitations of linear elastic fracture mechanics, a two-parameter fracture criterion, aspects of fatigue crack propagation, and crack propagation and fracture in built-up structures.

  8. VITAL-Bone Health: rationale and design of two ancillary studies evaluating the effects of vitamin D and/or omega-3 fatty acid supplements on incident fractures and bone health outcomes in the VITamin D and OmegA-3 TriaL (VITAL)

    PubMed Central

    LeBoff, Meryl S.; Yue, Amy Y.; Copeland, Trisha; Cook, Nancy R.; Buring, Julie E.; Manson, JoAnn E.

    2015-01-01

    Rationale Although vitamin D is widely used to promote skeletal health, definitive data on benefits and risks of supplemental vitamin D alone on bone are lacking. Results from large, randomized controlled trials in the general population are sparse. Data on the effects of supplemental omega-3 fatty acids (FAs) on bone are also limited. Design The VITamin D and OmegA-3 TriaL (VITAL) is a double-blind, placebo-controlled trial assessing the role of vitamin D3 (2000 IU/d) and omega-3 FA (1 g/d) supplements in reducing risks of cancer and cardiovascular disease among U.S. men aged ≥50 and women aged ≥55. To comprehensively test effects of supplemental vitamin D and/or omega-3 FAs on skeletal health, the VITAL: Effects on Fractures ancillary study is determining the effects of these supplements on incident fractures among 25,875 participants enrolled in the parent trial. Study investigators adjudicate fractures through detailed review of medical records and radiological images (hip and femur). In a complementary ancillary, VITAL: Effects on Structure and Architecture is determining the effects of supplemental vitamin D and/or omega-3 FAs on bone with detailed phenotyping during in-person visits. Comprehensive assessments of bone density, turnover, structure/architecture, body composition, and physical performance are being performed at baseline and 2 years post-randomization. Conclusion Results from these studies will clarify the relationship between supplemental vitamin D and/or omega-3 FAs on bone health outcomes, and inform clinical care and public health guidelines on the use of supplemental vitamin D for the primary prevention of fractures in women and men. PMID:25623291

  9. Geothermal energy enhancement by thermal fracture. [REX (Rock Energy Extraction)

    SciTech Connect

    Demuth, R.B.; Harlow, F.H.

    1980-12-01

    A large, vertical, circular fracture created deep within hot rock is connected to the surface through two holes. The inlet provides a source of cold water and the outlet extracts heated water. Cooling of the rock produces thermal stresses that fracture the rock adjacent to the primary crack, thereby enhancing the heat extraction rate by means of convective transport. The properties of the thermal fracture network vary with position and time. The REX code for high-speed computer was written and used to study the coupled processes of primary-crack flow and lateral thermal fracture heat transport. Calculations for elapsed times of 100 y show that thermal fracture enhancement can double the heat extraction rate over the results from conduction alone. Long-term enhancement predictions depend on data from rock-mechanics studies, which the REX code is prepared to accept as they become available.

  10. [Delirium prevention and treatment in elderly hip fracture].

    PubMed

    Robles, María José; Formiga, Francesc; Vidán, M Teresa

    2014-04-22

    The fracture of the proximal femur or hip fracture in the elderly usually happens after a fall and carries a high morbidity and mortality. One of the most common complications during hospitalization for hip fracture is the onset of delirium or acute confusional state that in elderly patients has a negative impact on the hospital stay, and prognosis, worsening functional ability, cognitive status and mortality. Also the development of delirium during hospitalization increases health care costs. Strategies to prevent and treat delirium during hospitalization for hip fracture have been less studied. In this context, this paper aims to conduct a review of the literature on strategies that exist in the prevention and treatment of delirium in elderly patients with hip fracture. PMID:23790577

  11. Water infiltration and intermittent flow in rough-walled fractures

    SciTech Connect

    Su, G.

    1995-05-01

    Flow visualization experiments were conducted in transparent replicas of natural rough-walled fractures. The fracture was inclined to observe the interplay between capillary and gravity forces. Water was introduced into the fracture by a capillary siphon. Preferential flow paths were observed, where intermittent flow frequently occurred. The water infiltration experiments suggest that intermittent flow in fractures appears to be the rule rather than the exception. In order to investigate the mechanism causing intermittent flow in fractures, parallel plates with different apertures were assembled using lucite and glass. A medium-coarse-fine pore structure is believed to cause the intermittency in flow. Intermittent flow was successfully produced in the parallel plate experiments using the lucite plates. After several trials, intermittent flow was also produced in the glass plates.

  12. Geophysical characterization of fractured bedrock at Site 8, former Pease Air Force Base, Newington, New Hampshire

    USGS Publications Warehouse

    Mack, Thomas J.; Degnan, James R.

    2003-01-01

    Borehole-geophysical logs collected from eight wells and direct-current resistivity data from three survey lines were analyzed to characterize the fractured bedrock and identify transmissive fractures beneath the former Pease Air Force Base, Newington, N.H. The following logs were used: caliper, fluid temperature and conductivity, natural gamma radiation, electromagnetic conductivity, optical and acoustic televiewer, and heat-pulse flowmeter. The logs indicate several foliation and fracture trends in the bedrock. Two fracture-correlated lineaments trending 28? and 29?, identified with low-altitude aerial photography, are coincident with the dominant structural trend. The eight boreholes logged at Site 8 generally have few fractures and have yields ranging from 0 to 40 gallons per minute. The fractures that probably resulted in high well yields (20?40 gallons per minute) strike northeast-southwest or by the right hand rule, have an orientation of 215?, 47?, and 51?. Two-dimensional direct-current resistivity methods were used to collect detailed subsurface information about the overburden, bedrock-fracture zone depths, and apparent-dip directions. Analysis of data inversions from data collected with dipole-dipole and Schlumberger arrays indicated electrically conductive zones in the bedrock that are probably caused by fractured rock. These zones are coincident with extensions of fracture-correlated lineaments. The fracture-correlated lineaments and geophysical-survey results indicate a possible northeast-southwest anisotropy to the fractured rock.

  13. Modeling Electric Current Flow in 3D Fractured Media

    NASA Astrophysics Data System (ADS)

    Demirel, S.; Roubinet, D.; Irving, J.

    2014-12-01

    The study of fractured rocks is extremely important in a variety of research fields and applications such as hydrogeology, hydrocarbon extraction and long-term storage of toxic waste. As fractures are highly conductive structures in comparison to the surrounding rock, their presence can be either an advantage or a drawback. For hydrocarbon extraction, fractures allow for quick and easy access to the resource whereas for toxic waste storage their presence increases the risk of leakage and migration of pollutants. In both cases, the identification of fracture network characteristics is an essential step. Recently, we have developed an approach for modeling electric current flow in 2D fractured media. This approach is based on a discrete-dual-porosity model where fractures are represented explicitly, the matrix is coarsely discretized into blocks, and current flow exchange between the fractures and matrix is analytically evaluated at the fracture-scale and integrated at the block-scale [1]. Although this approach has shown much promise and has proven its efficiency for 2D simulations, its extension to 3D remains to be addressed. To this end, we assume that fractures can be represented as two-dimensional finite planes embedded in the surrounding matrix, and we express analytically the distribution of electric potential at the fracture scale. This fracture-scale expression takes into account the electric-current-flow exchange with the surrounding matrix and flow conservation is enforced at the fracture intersections. The fracture-matrix exchange is then integrated at the matrix-block scale where the electric current flow conservation at the block boundaries is formulated with a modified finite volume method. With the objective of providing a low-computational-cost modeling approach adapted to 3D simulations in fractured media, our model is (i) validated and compared to existing modeling approaches and, (ii) used to evaluate the impact of the presence of fractures on

  14. Measuring Changes in Fracture Aperture During Injection to Estimate Characteristics of Fractured Rock Near a Well

    NASA Astrophysics Data System (ADS)

    Schweisinger, T.; Murdoch, L.

    2002-12-01

    Fracture networks are critical to ground water flow, but details of the geometry of networks in the subsurface can be difficult to determine with currently available technology. Sheet fractures, or other flat-lying fractures, are an important component of fracture networks in crystalline rock. Using a televiewer, or other borehole geophysical technique, it is possible to determine the depth a sheet fracture intersects a borehole, but it is more difficult to determine the size of the fracture and its connectivity to other fractures in the network. The aperture of a sheet fracture will change in response to pressure changes during a hydraulic well test, and the amount that the aperture changes will depend on both the size of the crack and how it is connected to the network. We are developing a field test that measures changes in aperture during a well test to estimate fracture geometry. The test uses a borehole extensometer between straddle packers to measure changes in aperture, and transducers to measure pressure during and after a hydraulic well test conducted by injecting at a constant flow rate. In general, the fracture opens as pressure increases during injection, and closes as pressure decreases during recovery. A coupled model of deformation and fluid flow is inverted to estimate fracture parameters that best predict the records of aperture and pressure. Efforts toward developing this test have focused on designing and fabricating instrumentation for acquiring the field measurements, and deriving theoretical analyses for interpreting the results. The borehole extensometer consists of two retractable anchors separated by connecting rods attached to a submersible LVDT. The anchors are designed to lock themselves in place once actuated, thus minimizing creep over time. Another application for this device is to measure long-term changes in fracture aperture due to Earth tide or other effects, so it is important to reduce creep effects. The anchors are deployed on

  15. Comparing proton conductivity of polymer electrolytes by percent conducting volume

    SciTech Connect

    Kim, Yu Seung; Pivovar, Bryan

    2009-01-01

    Proton conductivity of sulfonated polymers plays a key role in polymer electrolyte membrane fuel cells. Mass based water uptake and ion exchange capacity of sulfonated polymers have been failed to correlating their proton conductivity. In this paper, we report a length scale parameter, percent conductivity volume, which is rather simply obtained from the chemical structure of polymer to compare proton conductivity of wholly aromatic sulfonated polymer perflurosulfonic acid. Morphology effect on proton conductivity at lower RH conditions is discussed using the percent conductivity volume parameter.

  16. Electrodeless conductivity.

    PubMed

    Light, T S; McHale, E J; Fletcher, K S

    1989-01-01

    Electrodeless conductivity is a technique for measuring the concentration of electrolytes in solution and utilizes a probe consisting of two toroids in close proximity, both of which are immersed in the solution. In special cases, the toroids may be mounted externally on insulated pipes carrying the solution. One toroid radiates an alternating electric field in the audiofrequency range and the other acts as a receiver to pick up the small current induced by the ions moving in a conducting loop of solution. Coatings which would foul contacting electrodes, such as suspensions, precipitates or oil, have little or no effect. Applications are chiefly to continuous measurement in the chemical processing industries, including pulp and paper, mining and heavy chemical production. The principles and practical details of the method are reviewed and cell-diameter, wall, and temperature effects are discussed. PMID:18964695

  17. Heat conduction

    SciTech Connect

    Lilley, D.G.

    1987-01-01

    Analytical and numerical methods, including both finite difference and finite element techniques, are presented with applications to heat conduction problems. Numerical and analytical methods are integrated throughout the text and a variety of complexities are thoroughly treated with many problems, solutions and computer programs. This book is presented as a fundamental course suitable for senior undergraduate and first year graduate students, with end-of-chapter problems and answers included. Sample case studies and suggested projects are included.

  18. Conduction apraxia.

    PubMed

    Ochipa, C; Rothi, L J; Heilman, K M

    1994-10-01

    A left hemisphere damaged patient with ideomotor apraxia is described, whose performance on pantomime to verbal command was superior to pantomime imitation. His reception of these same gestures (gesture naming) was spared. This syndrome has been named conduction apraxia. To account for this selective impaired performance on gesture imitation, a separation of the representations for gesture production and reception is proposed and a non-lexical gesture processing route for gesture imitation is suggested. PMID:7931387

  19. Fracture behavior across interfaces

    NASA Astrophysics Data System (ADS)

    Petrie, E. S.; Evans, J. P.; Jeppson, T. N.

    2011-12-01

    Faults and fracture networks at depth are important fluid pathways, especially in fine-grained, low permeability seal lithologies. Discontinues in sealing lithologies can create seal bypass systems, leading to the failure of CO2 geosequestration sites or hydrocarbon traps. We characterize the occurrence of and changes in discontinuity patterns and the associated changes in elastic moduli across sedimentologic interfaces to document the importance of these discontinuities for fluid management in the subsurface and potential for re-activation in high-pressure injection scenarios. We evaluate well-exposed, fine-grained, low-permeability Mesozoic and Paleozoic units that are seals of potential CO2 repositories on the Colorado Plateau and show evidence for open fractures and fluid flow in the subsurface. Field observations document changes in fracture distributions across lithologic boundaries allowing us to identify mechano-stratigraphic units and focus on the effect of lithologic interfaces on fracture distribution. An interface marks the boundary between facies in a seal and in this study the fractures are shown to deflect or arrest at the interface. In outcrop fracture intensity varies in from 1 to 18 fractures per meter and fracture apertures range from mm to cm. The mineralized fractures often have associated alteration halos along their boundaries; their general orientation follows that of discontinuities within the underlying reservoir facies or adjacent faults. The recognition of these changes in fracture distribution is important for forward modeling of fluid flow and risk management. Studying the occurrence of and changes in fracture patterns from outcrops and scaling it up for use in modeling at a field scale is difficult due to the lack of direct correlation between outcrop observations and subsurface data. Due to the size and amount of data needed to model fluid flow at the field scale the meso-scale (cm to m) variability of rock properties is often

  20. Effect of isolated fractures on accelerated flow in unsaturated porous rock

    USGS Publications Warehouse

    Su, G.W.; Nimmo, J.R.; Dragila, M.I.

    2003-01-01

    Fractures that begin and end in the unsaturated zone, or isolated fractures, have been ignored in previous studies because they were generally assumed to behave as capillary barriers and remain nonconductive. We conducted a series of experiments using Berea sandstone samples to examine the physical mechanisms controlling flow in a rock containing a single isolated fracture. The input fluxes and fracture orientation were varied in these experiments. Visualization experiments using dyed water in a thin vertical slab of rock were conducted to identify flow mechanisms occurring due to the presence of the isolated fracture. Two mechanisms occurred: (1) localized flow through the rock matrix in the vicinity of the isolated fracture and (2) pooling of water at the bottom of the fracture, indicating the occurrence of film flow along the isolated fracture wall. These mechanisms were observed at fracture angles of 20 and 60 degrees from the horizontal, but not at 90 degrees. Pooling along the bottom of the fracture was observed over a wider range of input fluxes for low-angled isolated fractures compared to high-angled ones. Measurements of matrix water pressures in the samples with the 20 and 60 degree fractures also demonstrated that preferential flow occurred through the matrix in the fracture vicinity, where higher pressures occurred in the regions where faster flow was observed in the visualization experiments. The pooling length at the terminus of a 20 degree isolated fracture was measured as a function of input flux. Calculations of the film flow rate along the fracture were made using these measurements and indicated that up to 22% of the flow occurred as film flow. These experiments, apparently the first to consider isolated fractures, demonstrate that such features can accelerate flow through the unsaturated zone and should be considered when developing conceptual models.

  1. Radionuclide Transport in Fracture-Granite Interface Zones

    SciTech Connect

    Hu, Q; Mori, A

    2007-09-12

    In situ radionuclide migration experiments, followed by excavation and sample characterization, were conducted in a water-conducting shear zone at the Grimsel Test Site (GTS) in Switzerland to study diffusion paths of radionuclides in fractured granite. In this work, we employed a micro-scale mapping technique that interfaces laser ablation sampling with inductively coupled plasma-mass spectrometry (LA/ICP-MS) to measure the fine-scale (micron-range) distribution of actinides ({sup 234}U, {sup 235}U, and {sup 237}Np) in the fracture-granite interface zones. Long-lived {sup 234}U, {sup 235}U, and {sup 237}Np were detected in flow channels, as well as in the adjacent rock matrix, using the sensitive, feature-based mapping of the LA/ICP-MS technique. The injected sorbing actinides are mainly located within the advective flowing fractures and the immediately adjacent regions. The water-conducting fracture studied in this work is bounded on one side by mylonite and the other by granitic matrix regions. These actinides did not penetrate into the mylonite side as much as the relatively higher-porosity granite matrix, most likely due to the low porosity, hydraulic conductivity, and diffusivity of the fracture wall (a thickness of about 0.4 mm separates the mylonite region from the fracture) and the mylonite region itself. Overall, the maximum penetration depth detected with this technique for the more diffusive {sup 237}Np over the field experimental time scale of about 60 days was about 10 mm in the granitic matrix, illustrating the importance of matrix diffusion in retarding radionuclide transport from the advective fractures. Laboratory tests and numerical modeling of radionuclide diffusion into granitic matrix was conducted to complement and help interpret the field results. Measured apparent diffusivity of multiple tracers in granite provided consistent predictions for radionuclide transport in the fractured granitic rock.

  2. Computed tomography of facial fractures.

    PubMed

    Furlow, Bryant

    2014-01-01

    Facial skeletal fractures are common, potentially serious, and frequently associated with other life-threatening conditions, such as traumatic brain injuries. Facial fractures can be simple or complex and sometimes involve serious complications. Computed tomography has revolutionized the rapid and precise assessment of craniofacial and neck fractures in patients with severe facial trauma. This article introduces readers to the epidemiology, skeletal anatomy and biomechanics, complications, and diagnostic imaging of facial fractures. In addition, this article describes efforts to develop and validate a quantitative scoring system for facial fracture severity and reviews treatment strategies for facial skeletal fractures. PMID:24806070

  3. Modification of ion transport in lipid bilayer membranes in the presence of 2,4-dichlorophenoxyacetic acid. II. Suppression of tetraphenylborate conductance and changes of interfacial potentials.

    PubMed Central

    Smejtek, P; Paulis-Illangasekare, M

    1979-01-01

    It has been shown that the blocking of negatively charged tetraphenylborate ion transport in phosphatidylcholine (PC)-cholesterol membranes by the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) is dominated by suppression of TPhB- diffusion across the membrane interior, rather than by the decrease of adsorption of TPhB- ions at the membrane surface. The blocking effect can be associated with the decrease of electric potential inside the membrane with respect to that of the aqueous medium, this decreases being proportional to the concentration of 2,4-D in the aqueous solution. It has been estimated that 25 - 30% of the total 2,4-D-induced change of the potential difference is between the plane of absorption of TPhB- and the aqueous solution, and the remaining fraction is between the membrane interior and the absorption plane. The results of this study support the dipolar hypothesis of 2,4-D action in lipid membranes. These conclusions are further supported by measurements changes of electric potential difference across air/water and air/lipid monolayer/water interfaces. It has been found that the electric potential of the nonpolar side of the interface decreases in the presence of neutral molecules of 2,4-D and that this effect becomes more prominent in presence of electrolyte. We have confirmed that PC-cholesterol monolayer cannot be considered as a model for half of the bilayer membrane because of the disagreement between the changes of the interfacial potential difference of PC-cholesterol monolayers and those determined from studied of transport of positive and negative ions across bilayer membranes. In contract, we have found close agreement between the 2,4-D-induced changes of electric potential of the lipid hydrocarbon region in glycerolmonooleate (GMO) membranes and GMO monolayers. We suggest that the action of 2,4-D in lipid membranes is not associated with the changes of orientation of dipoles of lipids constituting the membranes, but rather with a layer

  4. Modification of ion transport in lipid bilayer membranes in the presence of 2,4-dichlorophenoxyacetic acid. II. Suppression of tetraphenylborate conductance and changes of interfacial potentials.

    PubMed

    Smejtek, P; Paulis-Illangasekare, M

    1979-06-01

    It has been shown that the blocking of negatively charged tetraphenylborate ion transport in phosphatidylcholine (PC)-cholesterol membranes by the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) is dominated by suppression of TPhB- diffusion across the membrane interior, rather than by the decrease of adsorption of TPhB- ions at the membrane surface. The blocking effect can be associated with the decrease of electric potential inside the membrane with respect to that of the aqueous medium, this decreases being proportional to the concentration of 2,4-D in the aqueous solution. It has been estimated that 25 - 30% of the total 2,4-D-induced change of the potential difference is between the plane of absorption of TPhB- and the aqueous solution, and the remaining fraction is between the membrane interior and the absorption plane. The results of this study support the dipolar hypothesis of 2,4-D action in lipid membranes. These conclusions are further supported by measurements changes of electric potential difference across air/water and air/lipid monolayer/water interfaces. It has been found that the electric potential of the nonpolar side of the interface decreases in the presence of neutral molecules of 2,4-D and that this effect becomes more prominent in presence of electrolyte. We have confirmed that PC-cholesterol monolayer cannot be considered as a model for half of the bilayer membrane because of the disagreement between the changes of the interfacial potential difference of PC-cholesterol monolayers and those determined from studied of transport of positive and negative ions across bilayer membranes. In contract, we have found close agreement between the 2,4-D-induced changes of electric potential of the lipid hydrocarbon region in glycerolmonooleate (GMO) membranes and GMO monolayers. We suggest that the action of 2,4-D in lipid membranes is not associated with the changes of orientation of dipoles of lipids constituting the membranes, but rather with a layer

  5. Fracture-Flow-Enhanced Solute Diffusion into Fractured Rock

    SciTech Connect

    Wu, Yu-Shu; Ye, Ming; Sudicky, E.A.

    2007-12-15

    We propose a new conceptual model of fracture-flow-enhanced matrix diffusion, which correlates with fracture-flow velocity, i.e., matrix diffusion enhancement induced by rapid fluid flow within fractures. According to the boundary-layer or film theory, fracture flow enhanced matrix diffusion may dominate mass-transfer processes at fracture-matrix interfaces, because rapid flow along fractures results in large velocity and concentration gradients at and near fracture-matrix interfaces, enhancing matrix diffusion at matrix surfaces. In this paper, we present a new formulation of the conceptual model for enhanced fracture-matrix diffusion, and its implementation is discussed using existing analytical solutions and numerical models. In addition, we use the enhanced matrix diffusion concept to analyze laboratory experimental results from nonreactive and reactive tracer breakthrough tests, in an effort to validate the new conceptual model.

  6. Electrical and Magnetic Imaging of Proppants in Shallow Hydraulic Fractures

    NASA Astrophysics Data System (ADS)

    Denison, J. L. S.; Murdoch, L. C.; LaBrecque, D. J.; Slack, W. W.

    2015-12-01

    Hydraulic fracturing is an important tool to increase the productivity of wells used for oil and gas production, water resources, and environmental remediation. Currently there are relatively few tools available to monitor the distribution of proppants within a hydraulic fracture, or the propagation of the fracture itself. We have been developing techniques for monitoring hydraulic fractures by injecting electrically conductive, dielectric, or magnetically permeable proppants. We then use the resulting contrast with the enveloping rock to image the proppants using geophysical methods. Based on coupled laboratory and numerical modeling studies, three types of proppants were selected for field evaluation. Eight hydraulic fractures were created near Clemson, SC in May of 2015 by injecting specialized proppants at a depth of 1.5 m. The injections created shallow sub-horizontal fractures extending several meters from the injection point.Each cell had a dense array of electrodes and magnetic sensors on the surface and four shallow vertical electrode arrays that were used to obtain data before and after hydraulic fracturing. Net vertical displacement and transient tilts were also measured. Cores from 130 boreholes were used to characterize the general geometries, and trenching was used to characterize the forms of two of the fractures in detail. Hydraulic fracture geometries were estimated by inverting pre- and post-injection geophysical data. Data from cores and trenching show that the hydraulic fractures were saucer-shaped with a preferred propagation direction. The geophysical inversions generated images that were remarkably similar in form, size, and location to the ground truth from direct observation. Displacement and tilt data appear promising as a constraint on fracture geometry.

  7. Multi-Phase Fracture-Matrix Interactions Under Stress Changes

    SciTech Connect

    A.S. Grader; D. Elsworth; P.M. Halleck; F. Alvarao; A. Alajmi; Z. Karpyn; N. Mohammed; S. Al-Enezi

    2005-12-07

    The main objectives of this project are to quantify the changes in fracture porosity and multi-phase transport properties as a function of confining stress. These changes will be integrated into conceptual and numerical models that will improve our ability to predict and optimize fluid transport in fractured system. This report details our progress on: (a) developing the direct experimental measurements of fracture aperture and topology and fluid occupancy using high-resolution x-ray micro-tomography, (b) counter-current fluid transport between the matrix and the fracture, (c) studying the effect of confining stress on the distribution of fracture aperture and two-phase flow, and (d) characterization of shear fractures and their impact on multi-phase flow. The three-dimensional surface that describes the large-scale structure of the fracture in the porous medium can be determined using x-ray micro-tomography with significant accuracy. Several fractures have been scanned and the fracture aperture maps have been extracted. The success of the mapping of fracture aperture was followed by measuring the occupancy of the fracture by two immiscible phases, water and decane, and water and kerosene. The distribution of fracture aperture depends on the effective confining stress, on the nature of the rock, and the type and distribution of the asperities that keep the fracture open. Fracture apertures at different confining stresses were obtained by micro-tomography covering a range of about two thousand psig. Initial analysis of the data shows a significant aperture closure with increase in effective confining stress. Visual and detailed descriptions of the process are shown in the report. Both extensional and shear fractures have been considered. A series of water imbibition tests were conducted in which water was injected into a fracture and its migration into the matrix was monitored with CT and DR x-ray techniques. The objective was to understand the impact of the

  8. TIBIAL PLATEAU FRACTURES

    PubMed Central

    Júnior, Mauricio Kfuri; Fogagnolo, Fabrício; Bitar, Rogério Carneiro; Freitas, Rafael Lara; Salim, Rodrigo; Jansen Paccola, Cleber Antonio

    2015-01-01

    Tibial plateau fractures are joint lesions that require anatomical reduction of joint surface and functional restoration of mechanical axis of a lower limb. Patient profile, soft tissue conditions, presence of associated injuries and the available infrastructure for the treatment all contribute to the decision making about the best treatment for these fractures. High-energy fractures are usually approached in a staged manner respecting the principle of damage control, and are primarily targeted to maintain limb alignment while the resolution unfavorable soft tissue conditions is pending. Low-energy trauma can be managed on a singlestage basis, provided soft tissues are not an adverse factor, with open reduction and internal fixation. Stable fixation and early painless joint movement are related to a better prognosis. New developments as locked plates, bone replacements, intraoperative 3D imaging are promising and will certainly contribute for less invasive procedures and better outcomes. PMID:27077054

  9. Talar neck fractures.

    PubMed

    Berlet, G C; Lee, T H; Massa, E G

    2001-01-01

    Clinical management of talar neck fractures is complex and fraught with complications. As Gaius Julius Caesar stated: "The die is cast"; often the outcome of a talar neck fracture is determined at the time of injury. The authors believe, however, that better results can be achieved by following some simple guidelines. The authors advocate prompt and precise anatomic surgical reduction, preferring the medial approach with secondary anterolateral approach. Preservation of blood supply can be achieved by a thorough understanding of vascular pathways and efforts to stay within appropriate surgical intervals. The authors advocate bone grafting of medial neck comminution (if present) to prevent varus malalignment and rigid internal fixation to allow for joint mobilization postoperatively. These guidelines may seem simple, but when dealing with the complexity of talar neck fractures, the foot and ankle surgeon needs to focus and rely on easily grasped concepts to reduce poor outcomes. PMID:11465133

  10. DEM Particle Fracture Model

    SciTech Connect

    Zhang, Boning; Herbold, Eric B.; Homel, Michael A.; Regueiro, Richard A.

    2015-12-01

    An adaptive particle fracture model in poly-ellipsoidal Discrete Element Method is developed. The poly-ellipsoidal particle will break into several sub-poly-ellipsoids by Hoek-Brown fracture criterion based on continuum stress and the maximum tensile stress in contacts. Also Weibull theory is introduced to consider the statistics and size effects on particle strength. Finally, high strain-rate split Hopkinson pressure bar experiment of silica sand is simulated using this newly developed model. Comparisons with experiments show that our particle fracture model can capture the mechanical behavior of this experiment very well, both in stress-strain response and particle size redistribution. The effects of density and packings o the samples are also studied in numerical examples.

  11. Fracking, fracture, and permeability

    NASA Astrophysics Data System (ADS)

    Turcotte, D. L.; Norris, J.; Rundle, J. B.

    2013-12-01

    Injections of large volumes of water into tight shale reservoirs allows the extraction of oil and gas not previously accessible. This large volume 'super' fracking induces damage that allows the oil and/or gas to flow to an extraction well. The purpose of this paper is to provide a model for understanding super fracking. We assume that water is injected from a small spherical cavity into a homogeneous elastic medium. The high pressure of the injected water generates hoop stresses that reactivate natural fractures in the tight shales. These fractures migrate outward as water is added creating a spherical shell of damaged rock. The porosity associated with these fractures is equal to the water volume injected. We obtain an analytic expression for this volume. We apply our model to a typical tight shale reservoir and show that the predicted water volumes are in good agreement with the volumes used in super fracking.

  12. Geometrically Frustrated Fracture Mechanics

    NASA Astrophysics Data System (ADS)

    Mitchell, Noah; Koning, Vinzenz; Vitelli, Vincenzo; Irvine, William T. M.

    2015-03-01

    When a flat elastic sheet is forced to conform to a surface with Gaussian curvature, stresses arise in the sheet. The mismatch between initial and final metrics gives rise to new fracture behavior which cannot be achieved by boundary loading alone. Using experiments of PDMS sheets frustrated on 3D-printed surfaces and a linearized analytical model, we demonstrate the ability of curvature to govern the sheets' fracture phenomenology. In this talk, we first show that curvature can both stimulate and suppress fracture initiation, depending on the position and orientation of the initial slit. Secondly, we show that curvature can steer the path of a crack as it propagates through the material. Lastly, the curvature can arrest cracks which would otherwise continue to propagate.

  13. Strong Acid-Nonionic Surfactant Lyotropic Liquid-Crystalline Mesophases as Media for the Synthesis of Carbon Quantum Dots and Highly Proton Conducting Mesostructured Silica Thin Films and Monoliths.

    PubMed

    Olutaş, Elif B; Balcı, Fadime M; Dag, Ömer

    2015-09-22

    Lyotropic liquid-crystalline (LLC) materials are important in designing porous materials, and acids are as important in chemical synthesis. Combining these two important concepts will be highly beneficial to chemistry and material science. In this work, we show that a strong acid can be used as a solvent for the assembly of nonionic surfactants into various mesophases. Sulfuric acid (SA), 10-lauryl ether (C12E10), and a small amount of water form bicontinuous cubic (V1), 2D-hexagonal (H1), and micelle cubic (I1) mesophases with increasing SA/C12E10 mole ratio. A mixture of SA and C12E10 is fluidic but transforms to a highly ordered LLC mesophase by absorbing ambient water. The LLC mesophase displays high proton conductivity (1.5 to 19.0 mS/cm at room temperature) that increases with an increasing SA content up to 11 SA/C12E10 mole ratio, where the absorbed water is constant with respect to the SA amount but gradually increases from a 2.3 to 4.3 H2O/C12E10 mole ratio with increasing SA/C12E10 from 2 to 11, respectively. The mixture of SA and C12E10 slowly undergoes carbonization to produce carbon quantum dots (c-dots). The carbonization process can be controlled by simply controlling the water content of the media, and it can be almost halted by leaving the samples under ambient conditions, where the mixture slowly absorbs water to form photoluminescent c-dot-embedded mesophases. Over time the c-dots grow in size and increase in number, and the photoluminescence frequency gradually shifts to a lower frequency. The SA/C12E10 mesophase can also be used as a template to produce highly proton conducting mesostructured silica films and monoliths, as high as 19.3 mS/cm under ambient conditions. Aging the silica samples enhances the conductivity that can be even larger than for the LLC mesophase with the same amount of SA. The presence of silica has a positive effect on the proton conductivity of SA/C12E10 systems. PMID:26332603

  14. Conductivity Probe

    NASA Technical Reports Server (NTRS)

    2008-01-01

    The Thermal and Electrical Conductivity Probe (TECP) for NASA's Phoenix Mars Lander took measurements in Martian soil and in the air.

    The needles on the end of the instrument were inserted into the Martian soil, allowing TECP to measure the propagation of both thermal and electrical energy. TECP also measured the humidity in the surrounding air.

    The needles on the probe are 15 millimeters (0.6 inch) long.

    The Phoenix Mission is led by the University of Arizona, Tucson, on behalf of NASA. Project management of the mission is by NASA's Jet Propulsion Laboratory, Pasadena, Calif. Spacecraft development is by Lockheed Martin Space Systems, Denver.

  15. Physical model studies of dispersion in fracture systems

    SciTech Connect

    Hull, L.C.

    1985-04-01

    The purposes of the laboratory-scale fracture network experiments are to study mechanisms controlling solute transport under conditions of known fracture parameters, to evaluate injection-backflow test procedures under conditions of known reservoir parameters, and to acquire data for validation of numerical models. Validation of computer codes against laboratory data collected under controlled conditions provides reassurance that the codes deal with important processes in a realistic manner. Preliminary simulations of the dual-permeability physical model have been made using the FRACSL reservoir code. These simulations permit locating electrodes and piezometers in the most advantageous positions to record tracer migration and pressure response. Much of the physical modeling effort this year was oriented towards validating the particle tracking algorithm used in FRACSL, and developing a better theoretical understanding of transport processes in fractures. Experiments were conducted in single fractures and single fracture junctions, and data on tracer migration collected. The Prickett, Naymik, and Lonnquist Random Walk aquifer simulation program has been modfied to simulate flow in single fractures. The particle tracking algorithm was also used to simulate infinite parallel plates under conditions where analytical solutions to the transport equation could be derived. The first case is for zero diffusion in the fracture, and transport based on a parabolic velocity profile. The second case is for diffusion homogenizing the tracer solution across the fracture. The particle tracking algorithm matched both analytical solutions quite well, with the same grid for both simulations. 48 refs., 41 figs., 2 tabs.

  16. Direct observation of a sand-propped hydraulic fracture

    SciTech Connect

    Warpinski, N.R.; Tyler, L.D.; Vollendorf, W.C.; Northrop, D.A.

    1981-05-01

    An experiement has been conducted in which a sand-propped hydraulic fracture is created and then mined back to observe fracture behavior and proppant distribution. Three stages of different colored, different concentration sand transported by a water-based gel were injected into a volcanic ash fall tuff formation at a depth of 1400 ft near an existing tunnel complex. The resultant fracture was subsequently mined back for direct observation and photographed and mapped. This particular region was highly faulted and exhibited significant changes in in situ stress magnitudes across the faults; it is felt that this stress distribution resulted in very complex fracture behavior and growth processes. The fracture was bounded on one wing by a fault which was only a few feet from the wellbore. The fracture terminated on top at an unbonded bedding plane. Most of the injected volume of sand and fluid was forced downward, considerably below the elevation where the fracture was initiated. The different colors of sand were randomly distributed, although they were usually found in distinct layers, but this may have been due to the complex growth process. At different locations the fracture was found to have considerable variations in width; from several sand grains wide (1 cm) to devoid of sand altogether (2 to 3 mm average).

  17. Laboratory studies of radionuclide transport in fractured Climax granite

    SciTech Connect

    Failor, R.; Isherwood, D.; Raber, E.; Vandergraaf, T.

    1982-06-01

    This report documents our laboratory studies of radionuclide transport in fractured granite cores. To simulate natural conditions, our laboratory studies used naturally fractured cores and natural ground water from the Climax Granite Stock at the Nevada Test Site. For comparison, additional tests used artificially fractured granite cores or distilled water. Relative to the flow of tritiated water, {sup 85}Sr and /sup 95m/Tc showed little or no retardation, whereas {sup 137}Cs was retarded. After the transport runs the cores retained varying amounts of the injected radionuclides along the fracture. Autoradiography revealed some correlation between sorption and the fracture fill material. Strontium and cesium retention increased when the change was made from natural ground water to distilled water. Artificial fractures retained less {sup 137}Cs than most natural fractures. Estimated fracture apertures from 18 to 60 {mu}m and hydraulic conductivities from 1.7 to 26 x 10{sup -3} m/s were calculated from the core measurements.

  18. Evaluation of bone surrogates for indirect and direct ballistic fractures.

    PubMed

    Bir, Cynthia; Andrecovich, Chris; DeMaio, Marlene; Dougherty, Paul J

    2016-04-01

    The mechanism of injury for fractures to long bones has been studied for both direct ballistic loading as well as indirect. However, the majority of these studies have been conducted on both post-mortem human subjects (PMHS) and animal surrogates which have constraints in terms of storage, preparation and testing. The identification of a validated bone surrogate for use in forensic, medical and engineering testing would provide the ability to investigate ballistic loading without these constraints. Two specific bone surrogates, Sawbones and Synbone, were evaluated in comparison to PMHS for both direct and indirect ballistic loading. For the direct loading, the mean velocity to produce fracture was 121 ± 19 m/s for the PMHS, which was statistically different from the Sawbones (140 ± 7 m/s) and Synbone (146 ± 3 m/s). The average distance to fracture in the indirect loading was .70 cm for the PMHS. The Synbone had a statistically similar average distance to fracture (.61 cm, p=0.54) however the Sawbones average distance to fracture was statistically different (.41 cm, p<0.05). Fractures patterns were found to be comparable to the PMHS for tests conducted with Synbones, however the input parameters were slightly varied to produce similar results. The fractures patterns with the Sawbones were not found to be as comparable to the PMHS. An ideal bone surrogate for ballistic testing was not identified and future work is warranted. PMID:26867672

  19. Fractured Petroleum Reservoirs

    SciTech Connect

    Firoozabadi, Dr. Abbas

    2000-01-18

    In this report the results of experiments of water injection in fractured porous media comprising a number of water-wet matrix blocks are reported for the first time. The blocks experience an advancing fracture-water level (FWL). Immersion-type experiments are performed for comparison; the dominant recovery mechanism changed from co-current to counter-current imbibition when the boundary conditions changed from advancing FWL to immersion-type. Single block experiments of co-current and counter-current imbibition was performed and co-current imbibition leads to more efficient recovery was found.

  20. Adhesive fracture mechanics. [stress analysis for bond line interface

    NASA Technical Reports Server (NTRS)

    Bennett, S. J.; Devries, K. L.; Williams, M. L.

    1974-01-01

    In studies of fracture mechanics the adhesive fracture energy is regarded as a fundamental property of the adhesive system. It is pointed out that the value of the adhesive fracture energy depends on surface preparation, curing conditions, and absorbed monolayers. A test method reported makes use of a disk whose peripheral part is bonded to a substrate material. Pressure is injected into the unbonded central part of the disk. At a certain critical pressure value adhesive failure can be observed. A numerical stress analysis involving arbitrary geometries is conducted.

  1. Fractures of the coracoid process.

    PubMed

    Ogawa, K; Yoshida, A; Takahashi, M; Ui, M

    1997-01-01

    We reviewed 67 consecutive patients with fractures of the coracoid process, classifying them by the relationship between the fracture site and the coracoclavicular ligament. The 53 type-I fractures were behind the attachment of this ligament, and the 11 type-II fractures were anterior to it. The relationship of three fractures was uncertain. Type-I fractures were associated with a wide variety of shoulder injuries and consequent dissociation between the scapula and the clavicle. Treatment was usually by open reduction and fixation for type-I fractures and conservative methods for type-II. At follow-up of the 45 available patients, 87% had excellent results, with no significant differences between the operative and non-operative groups or between the type-I and type-II fractures. We consider that operative treatment should be reserved for patients with multiple shoulder injuries with severe disruption of the scapuloclavicular connection. PMID:9020438

  2. Progressive Fracture of Composite Structures

    NASA Technical Reports Server (NTRS)

    Chamis, Christos C.; Minnetyan, Levon

    2008-01-01

    A new approach is described for evaluating fracture in composite structures. This approach is independent of classical fracture mechanics parameters like fracture toughness. It relies on computational simulation and is programmed in a stand-alone integrated computer code. It is multiscale, multifunctional because it includes composite mechanics for the composite behavior and finite element analysis for predicting the structural response. It contains seven modules; layered composite mechanics (micro, macro, laminate), finite element, updating scheme, local fracture, global fracture, stress based failure modes, and fracture progression. The computer code is called CODSTRAN (Composite Durability Structural ANalysis). It is used in the present paper to evaluate the global fracture of four composite shell problems and one composite built-up structure. Results show that the composite shells and the built-up composite structure global fracture are enhanced when internal pressure is combined with shear loads.

  3. Compression fractures of the back

    MedlinePlus

    Compression fractures of the back are broken vertebrae. Vertebrae are the bones of the spine. ... bone from elsewhere Tumors that start in the spine, such as multiple myeloma Having many fractures of ...

  4. Bone fracture repair - series (image)

    MedlinePlus

    ... main treatment options for bone fractures are: Casting Open reduction, and internal fixation- this involves a surgery to repair the fracture-frequently, metal rods, screws or plates are used to repair the bone, and remain ...

  5. Fracture After Total Hip Replacement

    MedlinePlus

    ... er Total Hip Replacement cont. • Dislocation • Limb length inequality • Poor fracture healing • Repeat fracture • Lack of in- ... Surgeons (AAOS). To learn more about your orthopaedic health, please visit orthoinfo.org. Page ( 5 ) AAOS does ...

  6. Distal Radius Fracture (Broken Wrist)

    MedlinePlus

    ... choice depends on many factors, such as the nature of the fracture, your age and activity level, ... causing the cast to loosen. Depending on the nature of the fracture, your doctor may closely monitor ...

  7. Multiple mandibular fractures. Treatment outlines.

    PubMed

    Elia, Giovanni; Franco, Elena; Clauser, Luigi C

    2016-02-01

    Multiple mandibular comminuted fractures usually occur in high energy traumas. The authors describe the management and treatment of multiple mandibular fractures in a young patient after a suicide attempt. PMID:26862697

  8. Vertebroplasty for Spine Fracture Pain

    MedlinePlus

    MENU Return to Web version Vertebroplasty for Spine Fracture Pain Vertebroplasty for Spine Fracture Pain More than 40 million people in the United States have osteoporosis (a decrease in the amount ...

  9. Ankle Fractures Often Not Diagnosed

    MedlinePlus

    ... News, Videos & Podcasts » Articles » Text Size Print Bookmark Ankle Fractures Often Not Diagnosed Long-term Complications Result from Poor Recovery Mistaking an ankle fracture for an ankle sprain has serious consequences ...

  10. Stress fractures in young athletes.

    PubMed

    Orava, S; Jormakka, E; Hulkko, A

    1981-01-01

    In a series of 16 cases of stress fractures in 15-year-old and younger athletes 8 fractures occurred in boys and 8 in girls. There were no differences between the sexes in the athletes' training habits. Ten of the fractures were located at the tibia, seven at its upper third and three at the lower part of the bone. Three fractures were found in the fibula, in the metatarsal bones two stress fractures and in the femur one stress fracture. Most stress fractures were caused by endurance type sports. The daily training distances were not particularly high at the time of the onset of the symptoms. In most cases the diagnosis was based on a radiological evaluation. A sufficiently long pause from all athletic activity was enough treatment. Stress fractures in children are very uncommon. PMID:7295000

  11. Fracture propagation, pipe deformation study

    SciTech Connect

    Aloe, A.; Di Candia, A.; Bramante, M.

    1983-04-15

    Shear fracture propagation has become an important research subject connected with design aspects of gas pipelines. Difficulties involved in predicting safe service conditions from pure theoretical studies require 1:1 scale experiments. Through these tests, semiempirical design criteria was formulated where the minimum level of material quality, indicated by Charpy V energy in the ductile range, is determined as a function of pipe geometry and hoop stress. Disagreements exist among these criteria. Different arrest energy predictions at high hoop stresses and different effects ascribed to the thickness have called for further research in the field. Some interesting indications were obtained about shape and size of the plastic zone ahead of the propagating crack. Burst tests have been conducted and are discussed.

  12. Challenges and opportunities for fractured rock imaging using 3D cross-borehole electrical resistivity

    SciTech Connect

    Robinson, Judith; Johnson, Timothy C.; Slater, Lee D.

    2015-02-02

    There is an increasing need to characterize discrete fractures away from boreholes to better define fracture distributions and monitor solute transport. We performed a 3D evaluation of static and time-lapse cross-borehole electrical resistivity tomography (ERT) data sets from a limestone quarry in which flow and transport are controlled by a bedding-plane feature. Ten boreholes were discretized using an unstructured tetrahedral mesh, and 2D panel measurements were inverted for a 3D distribution of conductivity. We evaluated the benefits of 3D versus 2.5D inversion of ERT data in fractured rock while including the use of borehole regularization disconnects (BRDs) and borehole conductivity constraints. High-conductivity halos (inversion artifacts) surrounding boreholes were removed in static images when BRDs and borehole conductivity constraints were implemented. Furthermore, applying these constraints focused transient changes in conductivity resulting from solute transport on the bedding plane, providing a more physically reasonable model for conductivity changes associated with solute transport at this fractured rock site. Assuming bedding-plane continuity between fractures identified in borehole televiewer data, we discretized a planar region between six boreholes and applied a fracture regularization disconnect (FRD). Although the FRD appropriately focused conductivity changes on the bedding plane, the conductivity distribution within the discretized fracture was nonunique and dependent on the starting homogeneous model conductivity. Synthetic studies performed to better explain field observations showed that inaccurate electrode locations in boreholes resulted in low-conductivity halos surrounding borehole locations. These synthetic studies also showed that the recovery of the true conductivity within an FRD depended on the conductivity contrast between the host rock and fractures. Our findings revealed that the potential exists to improve imaging of fractured

  13. Rib fractures in coronary bypass patients: radionuclide detection

    SciTech Connect

    Greenwald, L.V.; Baisden, C.E.; Symbas, P.N.

    1983-08-01

    Sternal retraction can cause the first rib to be fractured posteriorly, injuring the brachial plexus. The authors conducted bone scans of 24 consecutive open-heart surgery patients and found an unexpectedly high number of rib fractures which in all but one case had not been seen on the chest radiograph. Bone scans are recommended whenever there is unexplained non-incisional pain in a patient who has undergone sternal retraction.

  14. Fracture analysis lowers expenses and raises production in Frontier

    SciTech Connect

    1995-08-01

    This report describes a fracturing treatment used for enhancing petroleum recovery in a tight sand in Wyoming. The treatment calls for a 30,000 gallon pad with linked fluid. The proppant goes into the hole in four stages starting at two pounds per gallon and increasing to four pounds per gallon and six pounds per gallon to finish at eight pounds per gallon. Afterwards, the fracture fluid flows back to the wellbore immediately which helps to reduce proppant settling and achieve conductivity.

  15. Dynamic Fracture Simulations of Explosively Loaded Cylinders

    SciTech Connect

    Arthur, Carly W.; Goto, D. M.

    2015-11-30

    This report documents the modeling results of high explosive experiments investigating dynamic fracture of steel (AerMet® 100 alloy) cylinders. The experiments were conducted at Lawrence Livermore National Laboratory (LLNL) during 2007 to 2008 [10]. A principal objective of this study was to gain an understanding of dynamic material failure through the analysis of hydrodynamic computer code simulations. Two-dimensional and three-dimensional computational cylinder models were analyzed using the ALE3D multi-physics computer code.

  16. New groups focus on hydraulic fracturing

    NASA Astrophysics Data System (ADS)

    Showstack, Randy

    2013-04-01

    The Scientific Advisory Board of the U.S. Environmental Protection Agency (EPA) has formed a 31-member expert panel to conduct a peer review of the agency's upcoming draft report on the potential effects of hydraulic fracturing on drinking water resources, EPA announced on 24 March. Panel members include experts in a number of areas, including petroleum/natural gas engineering, geology/geophysics, and waste water and drinking water treatment.

  17. Correlation of Hip Fracture with Other Fracture Types: Toward a Rational Composite Hip Fracture Endpoint

    PubMed Central

    Colón-Emeric, Cathleen; Pieper, Carl F.; Grubber, Janet; Van Scoyoc, Lynn; Schnell, Merritt L; Van Houtven, Courtney Harold; Pearson, Megan; Lafleur, Joanne; Lyles, Kenneth W.; Adler, Robert A.

    2016-01-01

    Purpose With ethical requirements to the enrollment of lower risk subjects, osteoporosis trials are underpowered to detect reduction in hip fractures. Different skeletal sites have different levels of fracture risk and response to treatment. We sought to identify fracture sites which cluster with hip fracture at higher than expected frequency; if these sites respond to treatment similarly, then a composite fracture endpoint could provide a better estimate of hip fracture reduction. Methods Cohort study using Veterans Affairs and Medicare administrative data. Male Veterans (n=5,036,536) aged 50-99 years receiving VA primary care between1999-2009 were included. Fractures were ascertained using ICD9 and CPT codes and classified by skeletal site. Pearson correlation coefficients, logistic regression and kappa statistics, were used to describe the correlation between each fracture type and hip fracture within individuals, without regards to the timing of the events. Results 595,579 (11.8%) men suffered 1 or more fractures and 179,597 (3.6%) suffered 2 or more fractures during the time under study. Of those with one or more fractures, rib was the most common site (29%), followed by spine (22%), hip (21%) and femur (20%). The fracture types most highly correlated with hip fracture were pelvic/acetabular (Pearson correlation coefficient 0.25, p<0.0001), femur (0.15, p<0.0001), and shoulder (0.11, p<0.0001). Conclusions Pelvic, acetabular, femur, and shoulder fractures cluster with hip fractures within individuals at greater than expected frequency. If we observe similar treatment risk reductions within that cluster, subsequent trials could consider use of a composite endpoint to better estimate hip fracture risk. PMID:26151123

  18. Low electrolytic conductivity standards

    SciTech Connect

    Wu, Y.C.; Berezansky, P.A.

    1995-09-01

    The monitoring and control of the quality of feedwater and boiler water are necessary for power plants. The generation of steam at high temperature and pressure requires that contaminants be strictly limited to very low levels to prevent corrosion and scaling. Standards of low electrolytic conductivity were developed to satisfy the demands of the US Navy and American industry for the measurement of high quality water. The criteria for the selection of appropriate solvent and solutes, based on the principles of equivalent conductivity and Onsager`s limiting law, are described. Dilute solutions of potassium chloride and benzoic acid in 30% n-propanol-water have been chosen as standards. The electrolytic conductivity of both sets of these solutions as a function of molality was determined. Solutions of potassium chloride and of benzoic acid are recommended for use as 5, 10, 15, 20, and 25 {micro}S/cm conductivity standards. Solutions prepared from potassium chloride in 30% n-propanol-water have been certified as Standard Reference Materials (SRMs). SRM 3198 and SRM 3199 are certified nominally at 5 and 15 {micro}S/cm, respectively, at 25.000 C.

  19. Statistical Physics of Fracture

    SciTech Connect

    Alava, Mikko; Nukala, Phani K; Zapperi, Stefano

    2006-05-01

    Disorder and long-range interactions are two of the key components that make material failure an interesting playfield for the application of statistical mechanics. The cornerstone in this respect has been lattice models of the fracture in which a network of elastic beams, bonds, or electrical fuses with random failure thresholds are subject to an increasing external load. These models describe on a qualitative level the failure processes of real, brittle, or quasi-brittle materials. This has been particularly important in solving the classical engineering problems of material strength: the size dependence of maximum stress and its sample-to-sample statistical fluctuations. At the same time, lattice models pose many new fundamental questions in statistical physics, such as the relation between fracture and phase transitions. Experimental results point out to the existence of an intriguing crackling noise in the acoustic emission and of self-affine fractals in the crack surface morphology. Recent advances in computer power have enabled considerable progress in the understanding of such models. Among these partly still controversial issues, are the scaling and size-effects in material strength and accumulated damage, the statistics of avalanches or bursts of microfailures, and the morphology of the crack surface. Here we present an overview of the results obtained with lattice models for fracture, highlighting the relations with statistical physics theories and more conventional fracture mechanics approaches.

  20. Fracture design modelling

    SciTech Connect

    Crichlow, H.B.; Crichlow, H.B.

    1980-02-07

    A design tool is discussed whereby the various components that enter the design process of a hydraulic fracturing job are combined to provide a realistic appraisal of a stimulation job in the field. An interactive computer model is used to solve the problem numerically to obtain the effects of various parameters on the overall behavior of the system.

  1. Tibia (Shinbone) Shaft Fractures

    MedlinePlus

    ... fractures in patients who are less healthy. • Early motion. Many doctors encourage leg motion early in the recovery period. For example, if ... will help you restore normal muscle strength, joint motion, and flexibility. AAOS does not endorse any treatments, ...

  2. Fracturing rigid materials.

    PubMed

    Bao, Zhaosheng; Hong, Jeong-Mo; Teran, Joseph; Fedkiw, Ronald

    2007-01-01

    We propose a novel approach to fracturing (and denting) brittle materials. To avoid the computational burden imposed by the stringent time step restrictions of explicit methods or with solving nonlinear systems of equations for implicit methods, we treat the material as a fully rigid body in the limit of infinite stiffness. In addition to a triangulated surface mesh and level set volume for collisions, each rigid body is outfitted with a tetrahedral mesh upon which finite element analysis can be carried out to provide a stress map for fracture criteria. We demonstrate that the commonly used stress criteria can lead to arbitrary fracture (especially for stiff materials) and instead propose the notion of a time averaged stress directly into the FEM analysis. When objects fracture, the virtual node algorithm provides new triangle and tetrahedral meshes in a straightforward and robust fashion. Although each new rigid body can be rasterized to obtain a new level set, small shards can be difficult to accurately resolve. Therefore, we propose a novel collision handling technique for treating both rigid bodies and rigid body thin shells represented by only a triangle mesh. PMID:17218752

  3. Fracture mechanics principles.

    PubMed

    Mecholsky, J J

    1995-03-01

    The principles of linear elastic fracture mechanics (LEFM) were developed in the 1950s by George Irwin (1957). This work was based on previous investigations of Griffith (1920) and Orowan (1944). Irwin (1957) demonstrated that a crack shape in a particular location with respect to the loading geometry had a stress intensity associated with it. He also demonstrated the equivalence between the stress intensity concept and the familiar Griffith criterion of failure. More importantly, he described the systematic and controlled evaluation of the toughness of a material. Toughness is defined as the resistance of a material to rapid crack propagation and can be characterized by one parameter, Kic. In contrast, the strength of a material is dependent on the size of the initiating crack present in that particular sample or component. The fracture toughness of a material is generally independent of the size of the initiating crack. The strength of any product is limited by the size of the cracks or defects during processing, production and handling. Thus, the application of fracture mechanics principles to dental biomaterials is invaluable in new material development, production control and failure analysis. This paper describes the most useful equations of fracture mechanics to be used in the failure analysis of dental biomaterials. PMID:8621030

  4. Increasing Metal Fracture Toughness

    NASA Technical Reports Server (NTRS)

    Lawing, P. L.; Wood, W. H.; Sandefur, P. G. J.

    1982-01-01

    In technique developed at Langley Research Center several thin sheets of metal are diffusion-brazed together in vacuum furnace to create thick piece of metal that retains much of fracture toughness of its thin components. Technique is expected to make many of high-strength stainless steels, not currently suitable, usable at cryogenic temperatures.

  5. Infiltration into Fractured Bedrock

    SciTech Connect

    Salve, Rohit; Ghezzehei, Teamrat A.; Jones, Robert

    2007-09-01

    One potential consequence of global climate change and rapid changes in land use is an increased risk of flooding. Proper understanding of floodwater infiltration thus becomes a crucial component of our preparedness to meet the environmental challenges of projected climate change. In this paper, we present the results of a long-term infiltration experiment performed on fractured ash flow tuff. Water was released from a 3 x 4 m{sup 2} infiltration plot (divided into 12 square subplots) with a head of {approx}0.04 m, over a period of {approx}800 days. This experiment revealed peculiar infiltration patterns not amenable to current infiltration models, which were originally developed for infiltration into soils over a short duration. In particular, we observed that in part of the infiltration plot, the infiltration rate abruptly increased a few weeks into the infiltration tests. We suggest that these anomalies result from increases in fracture permeability during infiltration, which may be caused by swelling of clay fillings and/or erosion of infill debris. Interaction of the infiltration water with subsurface natural cavities (lithophysal cavities) could also contribute to such anomalies. This paper provides a conceptual model that partly describes the observed infiltration patterns in fractured rock and highlights some of the pitfalls associated with direct extension of soil infiltration models to fractured rock over a long period.

  6. The role of in situ stress in determining hydraulic connectivity in a fractured rock aquifer (Australia)

    NASA Astrophysics Data System (ADS)

    Mortimer, Luke; Aydin, Adnan; Simmons, Craig T.; Heinson, Graham; Love, Andrew J.

    2011-11-01

    Fracture network connectivity is a spatially variable property that is difficult to quantify from standard hydrogeological datasets. This critical property is related to the distributions of fracture density, orientation, dimensions, intersections, apertures and roughness. These features that determine the inherent connectivity of a fracture network can be modified by secondary processes including weathering, uplift and unloading and other mechanisms that lead to fracture deformation in response to in situ stress. This study focussed on a fractured rock aquifer in the Clare Valley, South Australia, and found that fracture network connectivity could be discriminated from several geological, geophysical and hydrogeological field datasets at various scales including single well and local- to regional-scale data. Representative hydromechanical models of the field site were not only consistent with field observations but also highlighted the strong influence of in situ stress in determining the distribution of fracture hydraulic apertures and the formation of hydraulic chokes that impede fluid flow. The results of this multi-disciplinary investigation support the notion that the hydraulic conductivity of a fracture network is limited to the least hydraulically conductive interconnected fractures, which imposes a physical limit on the bulk hydraulic conductivity of a fractured rock aquifer.

  7. Mode II Interlaminar Fracture Toughness and Fatigue Characterization of a Graphite Epoxy Composite Material

    NASA Technical Reports Server (NTRS)

    O'Brien, T. Kevin; Johnston, William M.; Toland, Gregory J.

    2010-01-01

    Mode II interlaminar fracture toughness and delamination onset and growth characterization data were generated for IM7/8552 graphite epoxy composite materials from two suppliers for use in fracture mechanics analyses. Both the fracture toughness testing and the fatigue testing were conducted using the End-notched Flexure (ENF) test. The ENF test for mode II fracture toughness is currently under review by ASTM as a potential standard test method. This current draft ASTM protocol was used as a guide to conduct the tests on the IM7/8552 material. This report summarizes the test approach, methods, procedures and results of this characterization effort.

  8. Dense Nonaqueous-Phase Liquid Architecture in Fractured Bedrock: Implications for Treatment and Plume Longevity.

    PubMed

    Schaefer, Charles E; White, Erin B; Lavorgna, Graig M; Annable, Michael D

    2016-01-01

    Partitioning tracer testing was performed in discrete intervals within a fractured bedrock tetrachloroethene (PCE) dense nonaqueous-phase liquid (DNAPL) source area to assess the fracture flow field and DNAPL architecture. Results confirmed that the partitioning tracer testing was able to identify and quantify low levels of residual DNAPL along flow paths in hydraulically conductive fractures. DNAPL fracture saturations (Sn) ranged from undetectable to 0.007 (DNAPL volume/fracture volume). A comparison of the fracture flow field to the DNAPL distribution indicated that the highest value of Sn was observed in the least transmissive fracture (or fracture zone). Application of a simple ambient dissolution model showed that the DNAPL present in this low transmissivity zone would persist longer than the DNAPL present in more transmissive fractures and would persist for 200 years (in the absence of any degradation reactions). Assessment of PCE mass distribution between the rock matrix and fractures showed that, due to the presence of DNAPL, the rock matrix accounted for less than 10% of the total PCE mass. The evaluation of PCE concentration profiles in the rock matrix and the estimated diffusional flux from the rock matrix suggest that the elevated PCE groundwater concentrations observed in the fractures likely are due to the presence of the residual DNAPL sources and that removal of the residual DNAPL sources within the fractures would result in a significant decrease in dissolved PCE concentrations in the source area. PMID:26619000

  9. Role of geomechanically grown fractures on dispersive transport in heterogeneous geological formations.

    PubMed

    Nick, H M; Paluszny, A; Blunt, M J; Matthai, S K

    2011-11-01

    A second order in space accurate implicit scheme for time-dependent advection-dispersion equations and a discrete fracture propagation model are employed to model solute transport in porous media. We study the impact of the fractures on mass transport and dispersion. To model flow and transport, pressure and transport equations are integrated using a finite-element, node-centered finite-volume approach. Fracture geometries are incrementally developed from a random distributions of material flaws using an adoptive geomechanical finite-element model that also produces fracture aperture distributions. This quasistatic propagation assumes a linear elastic rock matrix, and crack propagation is governed by a subcritical crack growth failure criterion. Fracture propagation, intersection, and closure are handled geometrically. The flow and transport simulations are separately conducted for a range of fracture densities that are generated by the geomechanical finite-element model. These computations show that the most influential parameters for solute transport in fractured porous media are as follows: fracture density and fracture-matrix flux ratio that is influenced by matrix permeability. Using an equivalent fracture aperture size, computed on the basis of equivalent permeability of the system, we also obtain an acceptable prediction of the macrodispersion of poorly interconnected fracture networks. The results hold for fractures at relatively low density. PMID:22181492

  10. Fracture behaviour of functionally graded materials

    NASA Astrophysics Data System (ADS)

    Marur, Prabhakar R.

    in the graded zone, approaches the bimaterial crack behavior as the material gradient is increased. The mode-mixity is shown to be strongly dependent on the material gradient. Static and dynamic fracture tests are conducted on precracked specimens fabricated from homogenous, bimaterial and FGM. In the dynamic fracture study, complimentary finite element simulations are performed using the measured interaction forces as the traction boundary conditions. The measured dynamic strains and complex SIF data match favorably with the numerical results. The fracture test results show that, by joining two dissimilar materials with a graded zone, the strength of the resulting system has, at the minimum, the strength of the corresponding bimaterial.

  11. ADVANCED FRACTURING TECHNOLOGY FOR TIGHT GAS: AN EAST TEXAS FIELD DEMONSTRATION

    SciTech Connect

    Mukul M. Sharma

    2005-03-01

    The primary objective of this research was to improve completion and fracturing practices in gas reservoirs in marginal plays in the continental United States. The Bossier Play in East Texas, a very active tight gas play, was chosen as the site to develop and test the new strategies for completion and fracturing. Figure 1 provides a general location map for the Dowdy Ranch Field, where the wells involved in this study are located. The Bossier and other tight gas formations in the continental Unites States are marginal plays in that they become uneconomical at gas prices below $2.00 MCF. It was, therefore, imperative that completion and fracturing practices be optimized so that these gas wells remain economically attractive. The economic viability of this play is strongly dependent on the cost and effectiveness of the hydraulic fracturing used in its well completions. Water-fracs consisting of proppant pumped with un-gelled fluid is the type of stimulation used in many low permeability reservoirs in East Texas and throughout the United States. The use of low viscosity Newtonian fluids allows the creation of long narrow fractures in the reservoir, without the excessive height growth that is often seen with cross-linked fluids. These low viscosity fluids have poor proppant transport properties. Pressure transient tests run on several wells that have been water-fractured indicate a long effective fracture length with very low fracture conductivity even when large amounts of proppant are placed in the formation. A modification to the water-frac stimulation design was needed to transport proppant farther out into the fracture. This requires suspending the proppant until the fracture closes without generating excessive fracture height. A review of fracture diagnostic data collected from various wells in different areas (for conventional gel and water-fracs) suggests that effective propped lengths for the fracture treatments are sometimes significantly shorter than those

  12. Experimental and Numerical Analysis of Capillary Imbibition in Fractured Sandstone under Controlled Fracture Flow Conditions

    NASA Astrophysics Data System (ADS)

    Lee, C.; Karpyn, Z. T.

    2010-12-01

    Fractures serve as primary conduits and have great impact on the migration of injected fluid into fractured permeable media. Appropriate transport properties such as relative permeability and capillary pressures are essential for successful simulation and prediction of multi-phase flow in such systems. However, the lack of thorough understanding of the dynamics governing immiscible displacement in fractured media, limit our ability to properly represent their macroscopic transport properties. The present work is one component of a multi-variable analysis of factors affecting fracture-matrix imbibition, including injection rates, fluid properties, and fracture orientation. We conduct laboratory experiments to monitor spatial and temporal evolution of saturation distributions in fractured sandstone samples. Air-brine, kerosene-brine and mixed oil-brine were used as three different fluid pairs in separate sets of experiments. Results were then mimicked using an automated history matching approach to obtain representative relative permeability and capillary pressure curves to further investigate the interplay of gravity, capillary and viscous forces, on predictive simulation tests. Sensitive analyses, in combination with direct experimental observation, allowed us to explore the relative importance of injection flow rate, gravity effect, and fluid properties on the evolving imbibition front. High fracture flow rates favor faster recovery from the matrix, at the expense of higher pore volume injected, and generate a sharp saturation transition at the edge of the imbibing front. Water saturation in the imbibed zone remains constant at around 0.5 to 0.6, suggesting a dynamic equilibrium in the mobility of the fluid phases. Liquid-liquid and gas-liquid imbibition results show significant differences in the shape of the imbibing front, breakthrough time, and saturation profiles. Results from this work also assist in the identification of favorable conditions for cocurrent

  13. Fracture of articular cartilage.

    PubMed

    Chin-Purcell, M V; Lewis, J L

    1996-11-01

    Crack formation and propagation is a significant element of the degeneration process in articular cartilage. In order to understand this process, and separate the relative importance of structural overload and material failure, methods for measuring the fracture toughness of cartilage are needed. In this paper, two such methods are described and used to measure fracture properties of cartilage from the canine patella. A modified single edge notch (MSEN) specimen was used to measure J, and a trouser tear test was used to measure T, both measures of fracture toughness with units of kN/m. A pseudo-elastic modulus was also obtained from the MSEN test. Several potential error sources were examined, and results for the MSEN test compared with another method for measuring the fracture parameter for urethane rubber. Good agreement was found. The two test methods were used to measure properties of cartilage from the patellae of 12 canines: 4-9 specimens from each of 12 patellae, with 5 right-left pairs were tested. Values of J ranged from 0.14-1.2 kN/m. J values correlated with T and were an average of 1.7 times larger than T. A variety of failure responses was seen in the MSEN tests, consequently a grade of 0 to 3 was assigned to each test, where 0 represented a brittle-like crack with minimal opening and 3 represented plastic flow with no crack formation. The initial cracks in 12/82 specimens did not propagate and were assigned to grade 3. The method for reducing data in the MSEN test assumed pseudo-elastic response and could not be used for the grade 3 specimens. Stiffness did not correlate with J. Neither J nor T was statistically different between right-left pairs, but varied between animals. The test methods appear useful for providing a quantitative measure of fracture toughness for cartilage and other soft materials. PMID:8950659

  14. High viscosity acidic treating fluids and methods of forming and using the same

    SciTech Connect

    Harris, L.E.

    1982-02-02

    Acidizing and fracture acidizing procedures commonly are conducted in subterranean well formations to increase the recovery of hydrocarbons. High viscosity aqueous acid solutions prevent the acid from becoming prematurely spent and inactive and develops wider fractures so that live acid can be forced further into the formations. Acidic treating fluids are formed by combining a hydratable gelling agent capable of being cross-linked with metal ions and a zirconium cross-linking agent with an aqueous acid solution. When hydrated, the gelling agent increases the viscosity of the acid solution. The zirconium cross-linking agent cross-links the hydrated gelling agent thereby further increasing the viscosity and providing stability to the resulting viscous fluid. Hydratable gelling agents which are suitable for use are hydrophilic organic polymers having a high molecular weight and containing some carboxyl functionality whereby they can be cross-linked with metal ions. Examples of such polymers are substituted cellulose, substituted natural gums, acrylamides, methacrylamides, acrylates, methacrylates, maleic anhydrides, alkylvinyl ethers, vinyl alcohols and xanthan polymers. 14 claims.

  15. Site characterization in densely fractured dolomite: Comparison of methods

    USGS Publications Warehouse

    Muldoon, M.; Bradbury, K.R.

    2005-01-01

    One of the challenges in characterizing fractured-rock aquifers is determining whether the equivalent porous medium approximation is valid at the problem scale. Detailed hydrogeologic characterization completed at a small study site in a densely fractured dolomite has yielded an extensive data set that was used to evaluate the utility of the continuum and discrete-fracture approaches to aquifer characterization. There are two near-vertical sets of fractures at the site; near-horizontal bedding-plane partings constitute a third fracture set. Eighteen boreholes, including five coreholes, were drilled to a depth of ???10.6 m. Borehole geophysical logs revealed several laterally extensive horizontal fractures and dissolution zones. Flowmeter and short-interval packer testing identified which of these features were hydraulically important. A monitoring system, consisting of short-interval piezometers and multilevel samplers, was designed to monitor four horizontal fractures and two dissolution zones. The resulting network consisted of >70 sampling points and allowed detailed monitoring of head distributions in three dimensions. Comparison of distributions of hydraulic head - and hydraulic conductivity determined by these two approaches suggests that even in a densely fractured-carbonate aquifer, a characterization approach using traditional long-interval monitoring wells is inadequate to characterize ground water movement for the purposes of regulatory monitoring or site remediation. In addition, traditional multiwell pumping tests yield an average or bulk hydraulic conductivity that is not adequate for predicting rapid ground water travel times through the fracture network, and the pumping test response does not appear to be an adequate tool for assessing whether the porous medium approximation is valid. Copyright ?? 2005 National Ground Water Association.

  16. Site characterization in densely fractured dolomite: comparison of methods.

    PubMed

    Muldoon, Maureen; Bradbury, Ken R

    2005-01-01

    One of the challenges in characterizing fractured-rock aquifers is determining whether the equivalent porous medium approximation is valid at the problem scale. Detailed hydrogeologic characterization completed at a small study site in a densely fractured dolomite has yielded an extensive data set that was used to evaluate the utility of the continuum and discrete-fracture approaches to aquifer characterization. There are two near-vertical sets of fractures at the site; near-horizontal bedding-plane partings constitute a third fracture set. Eighteen boreholes, including five coreholes, were drilled to a depth of approximately 10.6 m. Borehole geophysical logs revealed several laterally extensive horizontal fractures and dissolution zones. Flowmeter and short-interval packer testing identified which of these features were hydraulically important. A monitoring system, consisting of short-interval piezometers and multilevel samplers, was designed to monitor four horizontal fractures and two dissolution zones. The resulting network consisted of >70 sampling points and allowed detailed monitoring of head distributions in three dimensions. Comparison of distributions of hydraulic head and hydraulic conductivity determined by these two approaches suggests that even in a densely fractured-carbonate aquifer, a characterization approach using traditional long-interval monitoring wells is inadequate to characterize ground water movement for the purposes of regulatory monitoring or site remediation. In addition, traditional multiwell pumping tests yield an average or bulk hydraulic conductivity that is not adequate for predicting rapid ground water travel times through the fracture network, and the pumping test response does not appear to be an adequate tool for assessing whether the porous medium approximation is valid. PMID:16324008

  17. Mandibular Fractures in Iraq: An Epidemiological Study

    PubMed Central

    Bede, Salwan

    2014-01-01

    The purpose of this study was to evaluate the epidemiological characteristics of the mandibular fractures relating to gender, age, the etiology of injury, and the rendered treatment modalities and complications. The data of the patients who sustained mandibular fractures were retrieved and were analyzed retrospectively, and based on these data a descriptive analysis was conducted. A total of 112 patients were included in this study; the most common cause was road traffic accidents (RTAs) followed by assaults and missile injuries. The most frequently involved age group was 11 to 20 years, treatment modalities included conservative, closed reduction and indirect fixation, and open reduction and internal fixation (ORIF) in 11.6, 79.5, and 8.9% of the cases, respectively. Most of the major complications were injury related. This study showed RTAs to be the most frequent cause followed by assaults, it also showed that a high percentage of assault victims were females mainly of low socioeconomic status. Another distinguishing feature in this study was the high incidence of missile injuries in the form of bullets and blasts. Closed reduction still has an important role in the treatment of fractures of mandible especially when the necessary equipments for ORIF are not readily available. A higher complication rate was observed in patients diagnosed with multiple and comminuted fractures as well as those caused by violence in the form of missile and assault injuries. PMID:25709754

  18. Fracture investigation in starch-based foods.

    PubMed

    Skamniotis, C G; Patel, Y; Charalambides, M N; Elliott, M

    2016-06-01

    The study of oral processing and specifically cutting of the food piece during mastication can lead towards optimization of products for humans or animals. Food materials are complex biocomposites with a highly nonlinear constitutive response. Their fracture properties have not been largely investigated, while the need for models capable of predicting food breakdown increases. In this study, the blade cutting and the essential work of fracture (EWF) methodologies assessed the fracture behaviour of starch-based pet food. Tensile tests revealed rate-dependent stiffness and stress softening effects, attributed to viscoplasticity and micro-cracking, respectively. Cutting data were collected for 5, 10 and 30 mm s(-1) sample feed rates, whereas the EWF tests were conducted at 1.7, 3.3 and 8.3 mm s(-1) crosshead speeds corresponding to average crack speeds of 4, 7 and 15 mm s(-1), respectively. A reasonable agreement was achieved between cutting and EWF, reporting 1.26, 1.78, 1.76 kJ m(-2) and 1.52, 1.37, 1.45 kJ m(-2) values, respectively, for the corresponding crack speeds. These toughness data were used in a novel numerical model simulating the 'first' bite mastication process. A viscoplastic material model is adopted for the food piece, combined with a damage law that enabled predicting fracture patterns in the product. PMID:27274805

  19. Naturally fractured tight gas reservoir detection optimization

    SciTech Connect

    1999-04-30

    In March, work continued on characterizing probabilities for determining natural fracturing associated with the GGRB for the Upper Cretaceous tight gas plays. Structural complexity, based on potential field data and remote sensing data was completed. A resource estimate for the Frontier and Mesa Verde play was also completed. Further, work was also conducted to determine threshold economics for the play based on limited current production in the plays in the Wamsutter Ridge area. These analyses culminated in a presentation at FETC on 24 March 1999 where quantified natural fracture domains, mapped on a partition basis, which establish ''sweet spot'' probability for natural fracturing, were reviewed. That presentation is reproduced here as Appendix 1. The work plan for the quarter of January 1, 1999--March 31, 1999 comprised five tasks: (1) Evaluation of the GGRB partitions for structural complexity that can be associated with natural fractures, (2) Continued resource analysis of the balance of the partitions to determine areas with higher relative gas richness, (3) Gas field studies, (4) Threshold resource economics to determine which partitions would be the most prospective, and (5) Examination of the area around the Table Rock 4H well.

  20. A review of fracture mechanics life technology

    NASA Technical Reports Server (NTRS)

    Thomas, J. M.; Besuner, P. M.; Harris, D. O.

    1985-01-01

    Current lifetime prediction technology for structural components subjected to cyclic loads was reviewed. The central objectives of the project were to report the current state of and recommend future development of fracture mechanics-based analytical tools for modeling and forecasting subcritical fatigue crack growth in structures. Of special interest to NASA was the ability to apply these tools to practical engineering problems and the developmental steps necessary to bring vital technologies to this stage. A survey of published literature and numerous discussions with experts in the field of fracture mechanics life technology were conducted. One of the key points made is that fracture mechanics analyses of crack growth often involve consideration of fatigue and fracture under extreme conditions. Therefore, inaccuracies in predicting component lifetime will be dominated by inaccuracies in environment and fatigue crack growth relations, stress intensity factor solutions, and methods used to model given loads and stresses. Suggestions made for reducing these inaccuracies include: development of improved models of subcritical crack growth, research efforts aimed at better characterizing residual and assembly stresses that can be introduced during fabrication, and more widespread and uniform use of the best existing methods.

  1. A review of fracture mechanics life technology

    NASA Technical Reports Server (NTRS)

    Besuner, P. M.; Harris, D. O.; Thomas, J. M.

    1986-01-01

    Lifetime prediction technology for structural components subjected to cyclic loads is examined. The central objectives of the project are: (1) to report the current state of the art, and (2) recommend future development of fracture mechanics-based analytical tools for modeling subcritical fatigue crack growth in structures. Of special interest is the ability to apply these tools to practical engineering problems and the developmental steps necessary to bring vital technologies to this stage. The authors conducted a survey of published literature and numerous discussions with experts in the field of fracture mechanics life technology. One of the key points made is that fracture mechanics analyses of crack growth often involve consideration of fatigue and fracture under extreme conditions. Therefore, inaccuracies in predicting component lifetime will be dominated by inaccuracies in environment and fatigue crack growth relations, stress intensity factor solutions, and methods used to model given loads and stresses. Suggestions made for reducing these inaccuracies include development of improved models of subcritical crack growth, research efforts aimed at better characterizing residual and assembly stresses that can be introduced during fabrication, and more widespread and uniform use of the best existing methods.

  2. Preventable mortality in geriatric hip fracture inpatients

    PubMed Central

    Tarrant, S. M.; Hardy, B. M.; Byth, P. L.; Brown, T. L.; Attia, J.; Balogh, Z. J.

    2014-01-01

    There is a high rate of mortality in elderly patients who sustain a fracture of the hip. We aimed to determine the rate of preventable mortality and errors during the management of these patients. A 12 month prospective study was performed on patients aged > 65 years who had sustained a fracture of the hip. This was conducted at a Level 1 Trauma Centre with no orthogeriatric service. A multidisciplinary review of the medical records by four specialists was performed to analyse errors of management and elements of preventable mortality. During 2011, there were 437 patients aged > 65 years admitted with a fracture of the hip (85 years (66 to 99)) and 20 died while in hospital (86.3 years (67 to 96)). A total of 152 errors were identified in the 80 individual reviews of the 20 deaths. A total of 99 errors (65%) were thought to have at least a moderate effect on death; 45 reviews considering death (57%) were thought to have potentially been preventable. Agreement between the panel of reviewers on the preventability of death was fair. A larger-scale assessment of preventable mortality in elderly patients who sustain a fracture of the hip is required. Multidisciplinary review panels could be considered as part of the quality assurance process in the management of these patients. Cite this article: Bone Joint J 2014;96-B:1178–84. PMID:25183587

  3. Conducting a thermal conductivity survey

    NASA Technical Reports Server (NTRS)

    Allen, P. B.

    1985-01-01

    A physically transparent approximate theory of phonon decay rates is presented starting from a pair potential model of the interatomic forces in an insulator or semiconductor. The theory applies in the classical regime and relates the 3-phonon decay rate to the third derivative of the pair potential. Phonon dispersion relations do not need to be calculated, as sum rules relate all the needed quantities directly to the pair potential. The Brillouin zone averaged phonon lifetime turns out to involve a dimensionless measure of the anharmonicity multiplied by an effective density of states for 3-phonon decay. Results are given for rare gas and alkali halide crystals. For rare gases, the results are in good agreement with more elaborate perturbation calculations. Comparison to experimental data on phonon linewidths and thermal conductivity are made.

  4. Chaotic dynamics in flow through unsaturated fractured media

    NASA Astrophysics Data System (ADS)

    Faybishenko, Boris

    Predictions of flow and transport within fractured rock in the vadose zone cannot be made without first characterizing the physics of unstable flow phenomena in unsaturated fractures. This paper introduces a new approach for studying complex flow processes in heterogeneous fractured media, using the methods of nonlinear dynamics and chaos--in particular reconstructing the system dynamics and calculating chaotic diagnostic parameters from time-series data. To demonstrate the application of chaotic analysis, this author analyzed the time-series pressure fluctuations from two water-air flow experiments conducted by Persoff and Pruess [Water Resour. Res. 31 (1995) 1175] in replicas of rough-walled rock fractures under controlled boundary conditions. This analysis showed that chaotic flow in fractures creates relaxational oscillations of liquid, gas, and capillary pressures. These pressure oscillations were used to calculate the diagnostic parameters of deterministic chaos, including correlation time, global embedding dimension, local embedding dimension, Lyapunov dimension, Lyapunov exponents, and correlation dimension. The results of the Persoff-Pruess experiments were then compared with the chaotic analysis of laboratory dripping-water experiments in fracture models and field-infiltration experiments in fractured basalt. This comparison allowed us to conjecture that intrinsic fracture flow and dripping, as well as extrinsic water dripping (from a fracture) subjected to a capillary-barrier effect, are deterministic-chaotic processes with a certain random component. The unsaturated fractured rock is a dynamic system that exhibits chaotic behavior because the flow processes are nonlinear, dissipative, and sensitive to initial conditions, with chaotic fluctuations generated by intrinsic properties of the system, not random external factors. Identifying a system as deterministically chaotic is important for developing appropriate short- and long-term prediction models

  5. Characterization of Fracture and Matrix Flow within Bedrock Aquifers

    NASA Astrophysics Data System (ADS)

    West, A. C.; Novakowski, K. S.

    2006-12-01

    This article describes new methods for the characterization of fractured bedrock aquifers and, via their application to a set of field data collected at Smithville, Ontario, Canada, provides new insight into the nature of fracture versus matrix flow in rock. Two complementary Maximum Likelihood methods are developed that provide log-normal parameter estimates from borehole measurements of interval transmissivities. The methods are tested using the Monte Carlo method based on interval transmissivities simulated from the properties of specified fracture populations. The first method was shown to estimate the transmissivity distribution of the most transmissive fractures from among the population at a user-specified scale (the inverse of the density of the Poisson Point Process assumed to describe their locations along the borehole), while the second method was shown to estimate sums of the transmissivities of the remaining fractures. The properties of the first method were shown to resolve certain difficulties resulting from the use of existing methods for both the analysis and design of fixed-interval length hydraulic testing programs, while the properties of the two complementary methods together provide tractable definitions for fracture versus matrix flow. Expressions for aquifer hydraulic conductivity and average linear groundwater velocity per unit hydraulic gradient are developed in terms of the fracture set scale parameter, the log-normal parameter estimates for the fractures transmissivity, and log-normal parameter estimates for the matrix interval transmissivity. Estimation accuracy for these important quantities is shown to be optimal for a moderately-heavy-tailed distribution for the fracture population transmissivities. It is pointed out that the job of drilling-geologists during core logging and analysts of hydraulic test data is one and the same. That is, to determine at what scale and with what physical properties such a fracture set exists.

  6. Static and fatigue fracture characteristics of rubber modified epoxy adhesives

    SciTech Connect

    Hosaka, Y.; Miyazaki, K.; Fujii, T.; Okubo, H.; Nejigaka, K.; Kurosawa, K.

    1993-12-31

    A conventional epoxy adhesive is modified with Closs-linked NBR-COOH to increase the fracture toughness. This paper presents the static and fatigue fracture characteristics of the rubber modified epoxy adhesives under Mode 1 loading. The fracture toughness under static loading is measured using Double Cantilever Beam (DCB) specimens. The energy release rate is used as a parameter of fracture toughness. Rubber contents are 2.8% and 5.5% in weight. Generally, toughened adhesives show relatively large plastic deformation ahead the crack tip. The crack extension is thought to be influenced by loading condition. Namely, monotonous loading up to the final failure gives the toughness which is different from the toughness obtained under loading-unloading condition. Therefore, two loading conditions are adopted under static loading in order to show the effect of loading history. Under cyclic loading, the fatigue crack velocity is measured with respect to number of loading cycles. The effect of rubber content on the fatigue crack growth is examined. The effect of adhesive thickness on both static and fatigue fracture also is examined. All tests are conducted at the laboratory condition at room temperature. Following conclusions are obtained from this study. The rubber modified adhesives show higher fracture toughness and fatigue resistance than unmodified one. Higher rubber content always show higher fracture toughness. The effect of rubber content on the fracture toughness is influenced by adhesive thickness. The observed fracture toughness increases with an increase of adhesive thickness while no effect of adherend thickness is found at the present condition. The stable crack extension force is higher than that at the crack starting moment. Rubber modification reduces the fatigue crack velocity. The fracture surface topology becomes different according to rubber content.

  7. Geomechanically Coupled Simulation of Flow in Fractured Reservoirs

    NASA Astrophysics Data System (ADS)

    Barton, C.; Moos, D.; Hartley, L.; Baxter, S.; Foulquier, L.; Holl, H.; Hogarth, R.

    2012-12-01

    Capturing the necessary and sufficient detail of reservoir hydraulics to accurately evaluate reservoir behavior remains a significant challenge to the exploitation and management of fracture-dominated geothermal reservoirs. In these low matrix permeability reservoirs, stimulation response is controlled largely by the properties of natural and induced fracture networks, which are in turn controlled by the in situ stresses, the fracture distribution and connectivity and the hydraulic behavior of the fractures. This complex interaction of fracture flow systems with the present-day stress field compounds the problem of developing an effective and efficient simulation to characterize, model and predict fractured reservoir performance. We discuss here a case study of the integration of geological, geophysical, geomechanical, and reservoir engineering data to characterize the in situ stresses, the natural fracture network and the controls on fracture permeability in geothermal reservoirs. A 3D geomechanical reservoir model includes constraints on stress magnitudes and orientations, and constraints on mechanical rock properties and the fractures themselves. Such a model is essential to understanding reservoir response to stimulation and production in low matrix permeability, fracture-dominated reservoirs. The geomechanical model for this study was developed using petrophysical, drilling, and wellbore image data along with direct well test measurements and was mapped to a 3D structural grid to facilitate coupled simulation of the fractured reservoir. Wellbore image and stimulation test data were used along with microseismic data acquired during the test to determine the reservoir fracture architecture and to provide control points for a realistic inter-connected discrete fracture network. As most fractures are stress-sensitive, their hydraulic conductivities will change with changes in bottomhole flowing and reservoir pressures, causing variations in production profiles

  8. Management of mandibular angle fracture.

    PubMed

    Braasch, Daniel Cameron; Abubaker, A Omar

    2013-11-01

    Fractures through the angle of the mandible are one of the most common facial fractures. The management of such fractures has been controversial, however. This controversy is related to the anatomic relations and complex biomechanical aspects of the mandibular angle. The debate has become even more heated since the evolution of rigid fixation and the ability to provide adequate stability of the fractured segments. This article provides an overview of the special anatomic and biomechanical features of the mandibular angle and their impact on the management of these fractures. PMID:24183373

  9. [Pathogenesis of atypical femoral fracture].

    PubMed

    Iwata, Ken; Mashiba, Tasuku

    2016-01-01

    We demonstrated microdamage accumulation in the fracture sites in the patients of subtrochanteric atypical femoral fracture with long term bisphosphonate therapy and of incomplete shaft fracture of lateral femoral bowing without bisphosphonate therapy. Based on these findings, pathogenesis of atypical femoral fracture is revealed stress fracture caused by accumulation of microdamages between distal to the lesser trochanter and proximal to the supracondylar flare in the femur in association with severely suppressed bone turnover and/or abnormal lower limb alignment, that causes stress concentration on the lateral side cortex of the femur. PMID:26728533

  10. Geomechanical Parameters in Fracturing Process of Layered Rocks

    NASA Astrophysics Data System (ADS)

    Mighani, S.; Sondergeld, C. H.; Rai, C. S.

    2013-12-01

    statistical analysis of microcracks formation inferred from SEM mosaics. The brittleness leads also to the dependence of failure on fabric dependent tensile strength. We observe twice as much Mode II fracturing (layer activation) at lower stress levels for Lyons sandstone. The rock microstructure, lamination, and brittleness control the break down pressure. They also influence the FPZ and laminations reactivation which affect the fracture conductivity and stimulated reservoir volume (SRV).

  11. Risk factors for fracture in adult kidney transplant recipients

    PubMed Central

    Naylor, Kyla L; Zou, Guangyong; Leslie, William D; Hodsman, Anthony B; Lam, Ngan N; McArthur, Eric; Fraser, Lisa-Ann; Knoll, Gregory A; Adachi, Jonathan D; Kim, S Joseph; Garg, Amit X

    2016-01-01

    AIM: To determine the general and transplant-specific risk factors for fractures in kidney transplant recipients. METHODS: We conducted a cohort study of all adults who received a kidney-only transplant (n = 2723) in Ontario, Canada between 2002 and 2009. We used multivariable Cox proportional hazards regression to determine general and transplant-specific risk factors for major fractures (proximal humerus, forearm, hip, and clinical vertebral). The final model was established using the backward elimination strategy, selecting risk factors with a P-value ≤ 0.2 and forcing recipient age and sex into the model. We also assessed risk factors for other fracture locations (excluding major fractures, and fractures involving the skull, hands or feet). RESULTS: There were 132 major fractures in the follow-up (8.1 fractures per 1000 person-years). General risk factors associated with a greater risk of major fracture were older recipient age [adjusted hazard ratio (aHR) per 5-year increase 1.11, 95%CI: 1.03-1.19] and female sex (aHR = 1.81, 95%CI: 1.28-2.57). Transplant-specific risk factors associated with a greater risk of fracture included older donor age (5-year increase) (aHR = 1.09, 95%CI: 1.02-1.17) and end-stage renal disease (ESRD) caused by diabetes (aHR = 1.72, 95%CI: 1.09-2.72) or cystic kidney disease (aHR = 1.73, 95%CI: 1.08-2.78) (compared to glomerulonephritis as the reference cause). Risk factors across the two fracture locations were not consistent (major fracture locations vs other). Specifically, general risk factors associated with an increased risk of other fractures were diabetes and a fall with hospitalization prior to transplantation, while length of time on dialysis, and renal vascular disease and other causes of ESRD were the transplant-specific risk factors associated with a greater risk of other fractures. CONCLUSION: Both general and transplant-specific risk factors were associated with a higher risk of fractures in kidney transplant

  12. Stimulation of large-conductance calcium-activated potassium channels inhibits neurogenic contraction of human bladder from patients with urinary symptoms and reverses acetic acid-induced bladder hyperactivity in rats.

    PubMed

    La Fuente, José M; Fernández, Argentina; Cuevas, Pedro; González-Corrochano, Rocío; Chen, Mao Xiang; Angulo, Javier

    2014-07-15

    We have analysed the effects of large-conductance calcium-activated potassium channel (BK) stimulation on neurogenic and myogenic contraction of human bladder from healthy subjects and patients with urinary symptoms and evaluated the efficacy of activating BK to relief bladder hyperactivity in rats. Bladder specimens were obtained from organ donors and from men with benign prostatic hyperplasia (BPH). Contractions elicited by electrical field stimulation (EFS) and carbachol (CCh) were evaluated in isolated bladder strips. in vivo cystometric recordings were obtained in anesthetized rats under control and acetic acid-induced hyperactive conditions. Neurogenic contractions of human bladder were potentiated by blockade of BK and small-conductance calcium-activated potassium channels (SK) but were unaffected by the blockade of intermediate calcium-activated potassium channels (IK). EFS-induced contractions were inhibited by BK stimulation with NS-8 or NS1619 or by SK/IK stimulation with NS309 (3µM). CCh-induced contractions were not modified by blockade or stimulation of BK, IK or SK. The anti-cholinergic agent, oxybutynin (0.3µM) inhibited either neurogenic or CCh-induced contractions. Neurogenic contractions of bladders from BPH patients were less sensitive to BK inhibition and more sensitive to BK activation than healthy bladders. The BK activator, NS-8 (5mg/kg; i.v.), reversed bladder hyperactivity induced by acetic acid in rats, while oxybutynin was ineffective. NS-8 did not significantly impact blood pressure or heart rate. BK stimulation specifically inhibits neurogenic contractions in patients with urinary symptoms and relieves bladder hyperactivity in vivo without compromising bladder contractile capacity or cardiovascular safety, supporting its potential therapeutic use for relieving bladder overactivity. PMID:24747752

  13. Fractured cement reactivity during CO2-rich brine leakage: Consequences on hydrodynamic and structural properties

    NASA Astrophysics Data System (ADS)

    abdelghafour, H.; Luquot, L.; Gouze, P.

    2013-12-01

    So far, cement alteration was principally studied experimentally using batch reactor (with static or renewed fluid). All exhibit similar carbonation mechanisms. The acidic solution, formed by the dissolution of the CO2 into the pore water or directly surrounding the cement sample, diffuses into the cement and induces dissolution reactions of the cement hydrates in particular portlandite and CSH. The calcium released by the dissolution of these calcium bearing phases combining with carbonate ions of the fluid forms calcium carbonates. The cement pH, initially around 13, falls to values where carbonate ion is the most dominant element (pH ~ 9), then CaCO3 phases can precipitate. These studies mainly associate carbonation process with a reduction of porosity and permeability. Indeed an increase of volume (about 10%) is expected during the formation of calcite from portlandite assuming a stoichiometric reaction. Here we investigated the cement alteration mechanisms in the frame of a controlled continuous renewal of CO2-rich fluid in a fracture. This situation is that expected when seepage is activated by the mechanical failure of the cement material that initially seals two layers of distinctly different pressure: the storage reservoir and the aquifer above the caprock, for instance. We study the effect of flow rates from quasi-static flow to higher flow rates for well-connected fractures. In the quasi-static case we observed an extensive conversion of portlandite (Ca(OH)2) to calcite in the vicinity of the fracture similar to that observed in the published batch experiments. Eventually, the fracture was almost totally healed. The experiments with constant flow revealed a different behavior triggered by the continuous renewing of the reactants and withdrawal of the reaction products. We showed that calcite precipitation is more efficient for low flow rate. With intermediate flow rate, we measured that permeability increases slowly at the beginning of the experiment and

  14. Particle-tracking simulations of anomalous transport in hierarchically fractured rocks

    NASA Astrophysics Data System (ADS)

    Roubinet, Delphine; de Dreuzy, Jean-Raynald; Tartakovsky, Daniel M.

    2013-01-01

    Complex topology of fracture networks and interactions between transport processes in a fracture and the ambient un-fractured rock (matrix) combine to render modeling solute transport in fractured media a challenge. Classical approaches rely on both strong assumptions of either limited or full diffusion of solutes in the matrix and simplified fracture configurations. We analyze fracture-matrix transport in two-dimensional Sierpinski lattice structures, which display a wide range of matrix block sizes. The analysis is conducted in several transport regimes that are limited by either diffusion or block sizes. Our simulation results can be used to validate the simplifying assumptions that underpin classical analytical solutions and to benchmark other numerical methods. They also demonstrate that both hydraulic and structural properties of fractured rocks control the residence time distribution.

  15. Density-surfactant-motivated removal of DNAPL trapped in dead-end fractures

    NASA Astrophysics Data System (ADS)

    Yeo, In Wook; Ji, Sung-Hoon; Lee, Kang-Kun

    2003-05-01

    Three kinds of experiments were conducted to test existing methods and develop an effective methodology for the remediation of DNAPL trapped in vertical dead-end fractures. A water-flushing method failed to remove TCE from vertical dead-end fractures where no fluid flow occurs. A water-flushing experiment implies that existing remediation methods, utilizing water-based remedial fluid such as surfactant-enhanced method, have difficulty in removing DNAPL trapped from the vertical downward dead-end fractures, because of no water flow through dead-end fractures, capillary, and gravity forces. Fluid denser than TCE was injected into the fracture network, but did not displace TCE from the vertical dead-end fractures. Based on the analysis of the experiments, the increase in the density of the dense fluid and the addition of surfactant to the dense fluid were suggested, and this composite dense fluid with surfactant effectively removed TCE from the vertical dead-end fractures.

  16. Transport in fractured porous solids

    NASA Astrophysics Data System (ADS)

    Mattisson, Charlotte; Knackstedt, Mark A.; Senden, Tim J.

    Laboratory measurements are made of the permeability and the resistivity of sintered porous media with disordered fractures over a wide range of matrix porosity. We discuss the preparation and characterisation of the samples. Approximating the topology of a rough fracture by a single discrete fracture can introduce large errors in the prediction of the permeability. We test the validity of empirical expressions relating permeability, resistivity and porosity for fractured samples. Resistivity correlations with porosity are independent of the presence of fractures. In contrast, permeability correlations show a strong dependence. Attempts to decouple the permeability of the fractured sample as a parallel sum of matrix and fracture permeability leads to large errors. The results indicate that transport in a medium with two distinct families of pathways cannot be described by a single-valued transport coefficient.

  17. Linear elastic fracture mechanics primer

    NASA Astrophysics Data System (ADS)

    Wilson, Christopher D.

    1992-07-01

    This primer is intended to remove the blackbox perception of fracture mechanics computer software by structural engineers. The fundamental concepts of linear elastic fracture mechanics are presented with emphasis on the practical application of fracture mechanics to real problems. Numerous rules of thumb are provided. Recommended texts for additional reading, and a discussion of the significance of fracture mechanics in structural design are given. Griffith's criterion for crack extension, Irwin's elastic stress field near the crack tip, and the influence of small-scale plasticity are discussed. Common stress intensities factor solutions and methods for determining them are included. Fracture toughness and subcritical crack growth are discussed. The application of fracture mechanics to damage tolerance and fracture control is discussed. Several example problems and a practice set of problems are given.

  18. Linear elastic fracture mechanics primer

    NASA Technical Reports Server (NTRS)

    Wilson, Christopher D.

    1992-01-01

    This primer is intended to remove the blackbox perception of fracture mechanics computer software by structural engineers. The fundamental concepts of linear elastic fracture mechanics are presented with emphasis on the practical application of fracture mechanics to real problems. Numerous rules of thumb are provided. Recommended texts for additional reading, and a discussion of the significance of fracture mechanics in structural design are given. Griffith's criterion for crack extension, Irwin's elastic stress field near the crack tip, and the influence of small-scale plasticity are discussed. Common stress intensities factor solutions and methods for determining them are included. Fracture toughness and subcritical crack growth are discussed. The application of fracture mechanics to damage tolerance and fracture control is discussed. Several example problems and a practice set of problems are given.

  19. Coupling Hydraulic Fracturing Propagation and Gas Well Performance for Simulation of Production in Unconventional Shale Gas Reservoirs

    NASA Astrophysics Data System (ADS)

    Wang, C.; Winterfeld, P. H.; Wu, Y. S.; Wang, Y.; Chen, D.; Yin, C.; Pan, Z.

    2014-12-01

    Hydraulic fracturing combined with horizontal drilling has made it possible to economically produce natural gas from unconventional shale gas reservoirs. An efficient methodology for evaluating hydraulic fracturing operation parameters, such as fluid and proppant properties, injection rates, and wellhead pressure, is essential for the evaluation and efficient design of these processes. Traditional numerical evaluation and optimization approaches are usually based on simulated fracture properties such as the fracture area. In our opinion, a methodology based on simulated production data is better, because production is the goal of hydraulic fracturing and we can calibrate this approach with production data that is already known. This numerical methodology requires a fully-coupled hydraulic fracture propagation and multi-phase flow model. In this paper, we present a general fully-coupled numerical framework to simulate hydraulic fracturing and post-fracture gas well performance. This three-dimensional, multi-phase simulator focuses on: (1) fracture width increase and fracture propagation that occurs as slurry is injected into the fracture, (2) erosion caused by fracture fluids and leakoff, (3) proppant subsidence and flowback, and (4) multi-phase fluid flow through various-scaled anisotropic natural and man-made fractures. Mathematical and numerical details on how to fully couple the fracture propagation and fluid flow parts are discussed. Hydraulic fracturing and production operation parameters, and properties of the reservoir, fluids, and proppants, are taken into account. The well may be horizontal, vertical, or deviated, as well as open-hole or cemented. The simulator is verified based on benchmarks from the literature and we show its application by simulating fracture network (hydraulic and natural fractures) propagation and production data history matching of a field in China. We also conduct a series of real-data modeling studies with different combinations of

  20. Fracture mechanics validity limits

    NASA Technical Reports Server (NTRS)

    Lambert, Dennis M.; Ernst, Hugo A.

    1994-01-01

    Fracture behavior is characteristics of a dramatic loss of strength compared to elastic deformation behavior. Fracture parameters have been developed and exhibit a range within which each is valid for predicting growth. Each is limited by the assumptions made in its development: all are defined within a specific context. For example, the stress intensity parameters, K, and the crack driving force, G, are derived using an assumption of linear elasticity. To use K or G, the zone of plasticity must be small as compared to the physical dimensions of the object being loaded. This insures an elastic response, and in this context, K and G will work well. Rice's J-integral has been used beyond the limits imposed on K and G. J requires an assumption of nonlinear elasticity, which is not characteristic of real material behavior, but is thought to be a reasonable approximation if unloading is kept to a minimum. As well, the constraint cannot change dramatically (typically, the crack extension is limited to ten-percent of the initial remaining ligament length). Rice, et al investigated the properties required of J-type parameters, J(sub x), and showed that the time rate, dJ(sub x)/dt, must not be a function of the crack extension rate, da/dt. Ernst devised the modified-J parameter, J(sub M), that meets this criterion. J(sub M) correlates fracture data to much higher crack growth than does J. Ultimately, a limit of the validity of J(sub M) is anticipated, and this has been estimated to be at a crack extension of about 40-percent of the initial remaining ligament length. None of the various parameters can be expected to describe fracture in an environment of gross plasticity, in which case the process is better described by deformation parameters, e.g., stress and strain. In the current study, various schemes to identify the onset of the plasticity-dominated behavior, i.e., the end of fracture mechanics validity, are presented. Each validity limit parameter is developed in

  1. An occult acetabular fracture preceding a femoral neck fracture.

    PubMed

    Lasanianos, Nikolaos; Kanakaris, Nikolaos; Giannoudis, Peter V

    2009-08-01

    This article describes the case of a 69-year-old patient with an occult acetabular fracture complicated by an ipsilateral femoral neck fracture occurring within 2 months. The acetabular fracture remained undiagnosed at examination due to insufficient clinical and radiographic data interpretation. The patient was assured of early mobilization that led to a fall and subsequent hip fracture. We focus on the potential reasons for the nondiagnosis of the acetabular fracture. Acetabular fractures in the elderly may occur after low-energy injuries. The lack of history of violent injury may lead to an incorrect diagnosis. Plain anteroposterior (AP) pelvis radiographs alone may prove an insufficient tool, especially in the hands of inexperienced personnel. As is characteristic, a retrospective review of the AP pelvis radiograph obtained after the first fall in our case revealed the undisplaced fracture of the anterior column that was missed initially. Combined fractures of the hip and the acetabulum are rarely described in the literature and are usually addressed by total hip arthroplasty (THA) alone. Similar fracture patterns that develop in 2 stages (2 injuries), as the 1 presented herein, are even more rare. The uniqueness of this combined fracture required a unique surgical treatment. The senior surgeon (P.V.G.) addressed the acetabular fracture separately to graft the anterior column fracture and facilitate union, as it was already 8 weeks old and the second fall had generated a further gap between the fragments. Stable fixation was felt appropriate prior to the THA. Thus, a double surgical approach was used. Six weeks postoperatively, the patient was able to perform full weight-bearing mobilization without an antalgic gait pattern. At 6-month follow-up, radiographs showed the metalwork to be in place with no displacement, and the fracture had progressed to union. PMID:19708620

  2. Borehole sampling of fracture populations - compensating for borehole sampling bias in crystalline bedrock aquifers, Mirror Lake, Grafton County, New Hampshire

    USGS Publications Warehouse

    McDonald, G.D.; Paillet, Frederick L.; Barton, C.C.; Johnson, C.D.

    1997-01-01

    The clustering of orientations of hydraulically conductive fractures in bedrock at the Mirror Lake, New Hampshire fractured rock study site was investigated by comparing the orientations of fracture populations in two subvertical borehole arrays with those mapped on four adjacent subvertical roadcuts. In the boreholes and the roadcuts, the orientation of fracture populations appears very similar after borehole data are compensated for undersampling of steeply dipping fractures. Compensated borehole and pavement fracture data indicate a northeast-striking population of fractures with varying dips concentrated near that of the local foliation in the adjacent rock. The data show no correlation between fracture density (fractures/linear meter) and distance from lithologic contacts in both the boreholes and the roadcuts. The population of water-producing borehole fractures is too small (28 out of 610 fractures) to yield meaningful orientation comparisons. However, the orientation of large aperture fractures (which contains all the producing fractures) contains two or three subsidiary clusters in orientation frequency that are not evident in stereographic projections of the entire population containing all aperture sizes. Further, these subsidiary orientation clusters do not coincide with the dominant (subhorizontal and subvertical) regional fracture orientations.

  3. Laboratory investigation on the effect of in situ stresses on hydraulic fracture containment

    SciTech Connect

    Warpinski, N. R.; Clark, J. A.; Schmidt, R. A.; Huddle, C. W.

    1981-01-01

    Laboratory experiments have been conducted to determine the effect of in situ stress variations on hydraulic fracture containment. Fractures were initiated in layered rock samples with prescribed stress variations, and fracture growth characteristics were determined as a function of stress levels. Stress contrasts of 2-3 MPa were found to be sufficient to restrict fracture growth in laboratory samples of Nevada tuff and Tennessee and Nugget sandstones. The required stress level was found not to depend on mechanical rock properties. However, permeability and the resultant pore pressure effects were found to be important. Tests conducted at bimaterial interfaces between Nugget and Tennessee sandstone show that the resultant stresses set up near the interface due to the applied overburden stress affect the fracture behavior in the same way as the applied confining stresses. These results provide a guideline for determining the in situ stress contrast necessary to contain a fracture in a field treatment.

  4. Multiple cervical spinous process fractures in a novice golf player.

    PubMed

    Kim, Sei-Yoon; Chung, Sang Ki; Kim, Dong-Yun

    2012-12-01

    Avulsion of spinous process, also called Clay-shoveler's fracture, is most prevalent among those engaged in hard physical labor. To the best of the author's knowledge, only one case of multiple spinous process fractures of the upper thoracic spine in a novice golfer has been reported. A 45-year-old female presented with intractable posterior neck pain. The patient experienced a sharp, sudden pain on the neck while swinging a golf club, immediately after the club head struck the ground. Dynamic cervical radiographic findings were C6 and C7 spinous process fractures. Magnetic resonance imaging revealed C6 and C7 spinous process fractures without spinal cord pathology. The patient was treated with pain medications and cervical bracing. The patient's pain gradually improved. The injury mechanism was speculated to be similar to Clay-shoveler's fracture. Lower cervical spinous process fractures can be associated with a golf swing. If the patient complains of long lasting neck pain and has a history of golf activity, further study should be conducted to rule out lower cervical spinous fracture. PMID:23346334

  5. Fracture behaviors of ceramic tissue scaffolds for load bearing applications

    NASA Astrophysics Data System (ADS)

    Entezari, Ali; Roohani-Esfahani, Seyed-Iman; Zhang, Zhongpu; Zreiqat, Hala; Dunstan, Colin R.; Li, Qing

    2016-07-01

    Healing large bone defects, especially in weight-bearing locations, remains a challenge using available synthetic ceramic scaffolds. Manufactured as a scaffold using 3D printing technology, Sr-HT-Gahnite at high porosity (66%) had demonstrated significantly improved compressive strength (53 ± 9 MPa) and toughness. Nevertheless, the main concern of ceramic scaffolds in general remains to be their inherent brittleness and low fracture strength in load bearing applications. Therefore, it is crucial to establish a robust numerical framework for predicting fracture strengths of such scaffolds. Since crack initiation and propagation plays a critical role on the fracture strength of ceramic structures, we employed extended finite element method (XFEM) to predict fracture behaviors of Sr-HT-Gahnite scaffolds. The correlation between experimental and numerical results proved the superiority of XFEM for quantifying fracture strength of scaffolds over conventional FEM. In addition to computer aided design (CAD) based modeling analyses, XFEM was conducted on micro-computed tomography (μCT) based models for fabricated scaffolds, which took into account the geometric variations induced by the fabrication process. Fracture strengths and crack paths predicted by the μCT-based XFEM analyses correlated well with relevant experimental results. The study provided an effective means for the prediction of fracture strength of porous ceramic structures, thereby facilitating design optimization of scaffolds.

  6. Measuring and Modeling Flow in Welded Fractured Tuffs

    SciTech Connect

    R. Salve; C. Doughty; J.S. Wang

    2001-10-03

    We have carried out a series of in situ liquid-release experiments in conjunction with a numerical modeling study to examine the effect of the rock matrix on liquid flow and transport occurring primarily through the fracture network. Field experiments were conducted in the highly fractured Topopah Spring welded tuff at a site accessed from the Exploratory Studies Facility (ESFS), an underground laboratory in the unsaturated zone at Yucca Mountain, Nevada. During the experiment, wetting-front movement, flow-field evolution, and drainage of fracture flow paths were evaluated. Modeling was used to aid in experimental design, predict experimental results, and study the physical processes accompanying liquid flow through unsaturated fractured welded tuff. Field experiments and modeling suggest that it may not be sufficient to conceptualize the fractured tuff as consisting of a single network of high-permeability fractures embedded in a low-permeability matrix. The need to include a secondary fracture network is demonstrated by comparison to the liquid flow observed in the field.

  7. Fracture behaviors of ceramic tissue scaffolds for load bearing applications

    PubMed Central

    Entezari, Ali; Roohani-Esfahani, Seyed-Iman; Zhang, Zhongpu; Zreiqat, Hala; Dunstan, Colin R.; Li, Qing

    2016-01-01

    Healing large bone defects, especially in weight-bearing locations, remains a challenge using available synthetic ceramic scaffolds. Manufactured as a scaffold using 3D printing technology, Sr-HT-Gahnite at high porosity (66%) had demonstrated significantly improved compressive strength (53 ± 9 MPa) and toughness. Nevertheless, the main concern of ceramic scaffolds in general remains to be their inherent brittleness and low fracture strength in load bearing applications. Therefore, it is crucial to establish a robust numerical framework for predicting fracture strengths of such scaffolds. Since crack initiation and propagation plays a critical role on the fracture strength of ceramic structures, we employed extended finite element method (XFEM) to predict fracture behaviors of Sr-HT-Gahnite scaffolds. The correlation between experimental and numerical results proved the superiority of XFEM for quantifying fracture strength of scaffolds over conventional FEM. In addition to computer aided design (CAD) based modeling analyses, XFEM was conducted on micro-computed tomography (μCT) based models for fabricated scaffolds, which took into account the geometric variations induced by the fabrication process. Fracture strengths and crack paths predicted by the μCT-based XFEM analyses correlated well with relevant experimental results. The study provided an effective means for the prediction of fracture strength of porous ceramic structures, thereby facilitating design optimization of scaffolds. PMID:27403936

  8. Risk factors and predictors of mortality for proximal humeral fractures

    PubMed Central

    Gooding, Benjamin WT; Manning, Paul A; Wallace, W Angus; Geoghegan, John M

    2014-01-01

    Background Risk factors for mortality after proximal humeral fracture, including socioeconomic status, are poorly defined. This retrospective review of prospectively collected data defines the epidemiology and predictors of mortality in association with proximal humeral fractures. Methods Patients who sustained proximal humeral fractures were identified from fragility fracture and trauma databases between May 2001 and September 2012. Results In total, 1880 patients with a mean age of 69 years and a male to female ratio of 2 : 3 were identified. Socioeconomic distribution is skewed towards the lowest and highest quintiles. Low-energy mechanisms caused 88% of fractures. Men sustain fractures when they are aged 10 years younger and via higher-energy mechanisms. In total, 536 patients (29%) died within the study period with a 1-year mortality of 9.8%, rising to 28.2% at 5 years. Female gender, increasing age, pathological fracture and increased number of co-morbidities were independent variables for increased mortality. Conclusions The present study, which was conducted over an 11-year period, is the first to combine the epidemiology and risk factors for mortality with socioeconomic rank. One-year mortality risk is twice that of the background matched population. Patient counselling with respect to increased mortality should be considered, especially in higher-risk elderly females with multiple co-morbidities.

  9. Fracture behaviors of ceramic tissue scaffolds for load bearing applications.

    PubMed

    Entezari, Ali; Roohani-Esfahani, Seyed-Iman; Zhang, Zhongpu; Zreiqat, Hala; Dunstan, Colin R; Li, Qing

    2016-01-01

    Healing large bone defects, especially in weight-bearing locations, remains a challenge using available synthetic ceramic scaffolds. Manufactured as a scaffold using 3D printing technology, Sr-HT-Gahnite at high porosity (66%) had demonstrated significantly improved compressive strength (53 ± 9 MPa) and toughness. Nevertheless, the main concern of ceramic scaffolds in general remains to be their inherent brittleness and low fracture strength in load bearing applications. Therefore, it is crucial to establish a robust numerical framework for predicting fracture strengths of such scaffolds. Since crack initiation and propagation plays a critical role on the fracture strength of ceramic structures, we employed extended finite element method (XFEM) to predict fracture behaviors of Sr-HT-Gahnite scaffolds. The correlation between experimental and numerical results proved the superiority of XFEM for quantifying fracture strength of scaffolds over conventional FEM. In addition to computer aided design (CAD) based modeling analyses, XFEM was conducted on micro-computed tomography (μCT) based models for fabricated scaffolds, which took into account the geometric variations induced by the fabrication process. Fracture strengths and crack paths predicted by the μCT-based XFEM analyses correlated well with relevant experimental results. The study provided an effective means for the prediction of fracture strength of porous ceramic structures, thereby facilitating design optimization of scaffolds. PMID:27403936

  10. Dynamic Fracture Behavior of Plastic-Bonded Explosives

    NASA Astrophysics Data System (ADS)

    Fu, Hua; Li, Jun-Ling; Tan, Duo-Wang; Ifp, Caep Team

    2011-06-01

    Plastic-Bonded Explosives (PBX) are used as important energetic materials in nuclear or conventional weapons. Arms Warhead in the service process and the ballistic phase, may experience complex process such as long pulse and higher loading, compresson, tension and reciprocating compression - tension, friction with the projectile shell, which would lead to explosive deformation and fracture.And the dynamic deformation and fracture behavior of PBX subsequently affect reaction characteristics and initiation mechanism in explosives, then having influence on explosives safety. The dynamic fracure behavior of PBX are generally complex and not well studied or understood. In this paper, the dynamic fracture of explosives are conducted using a Kolsky bar. The Brazilian test, also known as a indirect tensile test or splitting test, is chosen as the test method. Tensile strength under different strain rates are obtained using quartz crystal embedded in rod end. The dynamic deformation and fracture process are captured in real-time by high-speed digital camera, and the displacement and strain fields distribution before specimen fracture are obtained by digital correlation method. Considering the non-uniform microstructure of explosives,the dynamic fracture behavior of explosive are simulated by discrete element method, the simulation results can reproduce the deformation and fracture process in Brazilian test using a maximum tensile strain criterion.

  11. Effective transmissivity of two-dimensional fracture networks

    SciTech Connect

    Zimmerman, R.W.; Bodvarsson, G.S.

    1995-04-01

    Many of the sites that have been proposed as potential locations of underground radioactive waste repositories contain fractured rocks. For example, both the saturated and unsaturated zone at Yucca Mountain, Nevada, contains many hydrogeologic units that are extensively fractured. When modeling the hydrological behavior of these sites, for either the purpose of site characterization of performance assessment, computational grid-blocks are often used that contain large number of fractures. In order to treat these as equivalent continua, it is necessary to develop a procedure for relating the hydraulic properties of the individual fractures and he topology of the fracture network to the overall scale permeability. One aspect of this problem is that of determining the in situ hydraulic properties of the individual fractures. Another aspect is to reconstruct the three-dimensional geometry of the fracture network based on borehole or outcrop measurements. The final stage in the problem is that of taking a network of known geometry and determining it effective scale conductivity. The purpose of this paper is to describe a simple procedure for solving this latter problem,a nd to demonstrate it use in cases of both saturated and unsaturated flow. The TOUGH simulator was used.

  12. 3-D Mixed Mode Delamination Fracture Criteria - An Experimentalist's Perspective

    NASA Technical Reports Server (NTRS)

    Reeder, James R.

    2006-01-01

    Many delamination failure criteria based on fracture toughness have been suggested over the past few decades, but most only covered the region containing mode I and mode II components of loading because that is where toughness data existed. With new analysis tools, more 3D analyses are being conducted that capture a mode III component of loading. This has increased the need for a fracture criterion that incorporates mode III loading. The introduction of a pure mode III fracture toughness test has also produced data on which to base a full 3D fracture criterion. In this paper, a new framework for visualizing 3D fracture criteria is introduced. The common 2D power law fracture criterion was evaluated to produce unexpected predictions with the introduction of mode III and did not perform well in the critical high mode I region. Another 2D criterion that has been shown to model a wide range of materials well was used as the basis for a new 3D criterion. The new criterion is based on assumptions that the relationship between mode I and mode III toughness is similar to the relation between mode I and mode II and that a linear interpolation can be used between mode II and mode III. Until mixed-mode data exists with a mode III component of loading, 3D fracture criteria cannot be properly evaluated, but these assumptions seem reasonable.

  13. Fracturing results in diatomaceous earth formations, South Belridge Field, California

    SciTech Connect

    Strubhar, M.K.; Medin, W.L.

    1982-09-01

    Fracturing significantly increases light oil production rates at South Belridge making this an economically successful technique for exploitation of the Reef Ridge reservoir. No fracturing mechanics problems were encountered in any of the treatments. The loosely consolidated formations behaved mechanically much like brittle, elastic rocks. Net oil and gross production is typified by initial high rates and an early rapid decline. The major cause of this early rapid decline is the transient flow effect. This behavior is typical of low permeability oil and gas production. Fractures are vertical, as shown by gamma ray and temperature logs run following several treatments. The fractures grow slightly out of the perforated intervals (10 to 15 feet). Loss of fracture conductivity due to fines migration, scale deposition, and/or fracture healing (imbedment) is not a serious problem. Oil viscosity can vary as much as ten-fold. Some wells produce significant amounts of gas--100 to 200 MCFPD initially. The formation is primarily diatomaceous earth which is very fine particle size siliceous material composed of whole or fragmented diatom tests (skeletons). There is no evidence that clay swelling or dispersion is a problem. Field and laboratory data support this conclusion. Aqueous fracturing fluids were successfully used which confirmed laboratory tests on cores.

  14. Pelvic and acetabular fractures

    SciTech Connect

    Mears, D.C.; Rubash, H.E.

    1986-01-01

    This treatise focuses primarily on the clinical aspects of diagnosis and treatments of pelvic and acetabular fractures. However, considerable attention is also paid to the radiographic diagnosis of trauma and postoperative effects. The book begins with a succinct review of pelvic and acetabular anatomy and pelvic biomechanics. It continues with a radiographic classification of pelvic injury, which will represent the major source of the book's interest for radiologists. The remainder of the book is concerned with clinical management of pelvic and acetabular trauma, including preoperative planning, surgical approaches, techniques of reduction, internal fixation, eternal fixation, post-operative care, and late problems. Even throughout this later portion of the book there are extensive illustrations, including plain radiographs, computed tomographic (CT) scans, reconstructed three-dimensional CT scans, and schematic diagrams of diverse pelvic and acetabular fractures and the elementary surgical techniques for their repair.

  15. Vertebral fracture classification

    NASA Astrophysics Data System (ADS)

    de Bruijne, Marleen; Pettersen, Paola C.; Tankó, László B.; Nielsen, Mads

    2007-03-01

    A novel method for classification and quantification of vertebral fractures from X-ray images is presented. Using pairwise conditional shape models trained on a set of healthy spines, the most likely unfractured shape is estimated for each of the vertebrae in the image. The difference between the true shape and the reconstructed normal shape is an indicator for the shape abnormality. A statistical classification scheme with the two shapes as features is applied to detect, classify, and grade various types of deformities. In contrast with the current (semi-)quantitative grading strategies this method takes the full shape into account, it uses a patient-specific reference by combining population-based information on biological variation in vertebra shape and vertebra interrelations, and it provides a continuous measure of deformity. Good agreement with manual classification and grading is demonstrated on 204 lateral spine radiographs with in total 89 fractures.

  16. HUMERAL SHAFT FRACTURES

    PubMed Central

    Benegas, Eduardo; Ferreira Neto, Arnaldo Amado; Neto, Raul Bolliger; Santis Prada, Flavia de; Malavolta, Eduardo Angeli; Marchitto, Gustavo Oliveira

    2015-01-01

    Humeral shaft fractures (HSFs) represent 3% of the fractures of the locomotor apparatus, and the middle third of the shaft is the section most affected. In the majority of cases, it is treated using nonsurgical methods, but surgical indications in HSF cases are increasingly being adopted. The diversity of opinions makes it difficult to reach a consensus regarding the types of osteosynthesis, surgical technique and quantity and quality of synthesis materials that should be used. It would appear that specialists are far from reaching a consensus regarding the best method for surgical treatment of HSFs. We believe that less invasive methods, which favor relative stability, are the most appropriate methods, since the most feared complications are less frequent. PMID:27019833

  17. Probability of Hertzian fracture

    NASA Astrophysics Data System (ADS)

    Fischer-Cripps, A. C.; Collins, R. E.

    1994-04-01

    The indentation strength of brittle solids is traditionally characterized by Auerbach's law, which predicts a linear relationship between the load required to initiate a Hertzian cone crack and the radius of a spherical indentor. This paper reviews both the energy balance and flaw statisti