Science.gov

Sample records for acidic eo water

  1. Comparative Analysis of Dibutyric cAMP and Butyric Acid on the Differentiation of Human Eosinophilic Leukemia EoL-1 Cells

    PubMed Central

    2015-01-01

    Purification of enough numbers of circulating eosinophils is difficult because eosinophils account for less than 5% peripheral blood leukocytes. Human eosinophilic leukemia EoL-1 cells have been considered an in vitro source of eosinophils as they can differentiate into mature eosinophil-like cells when incubated with dibutyryl cAMP (dbcAMP) or butyric acid. In this study, the viability and phenotypic maturation of EoL-1 cells stimulated by either dbcAMP or butyric acid were comparatively analyzed. After treatment with 100 µM dbcAMP or 0.5 µM butyric acid, EoL-1 cells showed morphological signs of differentiation, although the number of nonviable EoL-1 cells was significantly increased following butyric acid treatment. Stimulation of EoL-1 cells with 0.5 µM butyric acid more effectively induced the expression of mature eosinophil markers than stimulation with dbcAMP. These results suggest that treatment of EoL-1 cells with 0.5 µM butyric acid for limited duration could be an effective strategy for inducing their differentiation. Considering that expression of CCR3 was not sufficient in EoL-1 cells stimulated with 0.5 µM butyric acid, treatment of the chemically stimulated EoL-1 cells with cytokines, which primarily support eosinophil maturation, would help to obtain differentiated EoL-1 cells with greater functional maturity. PMID:26770185

  2. Development of EOS-aided procedures for the determination of the water balance of hydrologic budget of a large watershed

    NASA Technical Reports Server (NTRS)

    Congalton, Russell G.; Thomas, Randall W.; Zinke, Paul J.

    1986-01-01

    Work focused on the acquisition of remotely sensed data for the 1985 to 1986 hydrogolic year; continuation of the field measurement program; continued acquisition and construction of passive microwave remote sensing instruments; a compilation of data necessary for an initial water balance computation; and participation with the EOS Simulataneity Team in reviewing the Feather River watershed as a possible site for a simultaneity experiment.

  3. EOS standards

    SciTech Connect

    Greeff, Carl W

    2011-01-12

    An approach to creating accurate EOS for pressure standards is described. Applications to Cu, Au, and Ta are shown. Extension of the method to high compressions using DFT is illustrated. Comparisons with modern functionals show promise.

  4. Photooxidative removal of the herbicide Acid Blue 9 in the presence of hydrogen peroxide: modeling of the reaction for evaluation of electrical energy per order (E EO).

    PubMed

    Khataee, Ali R; Khataee, Hamid R

    2008-09-01

    The present work deals with photooxidative removal of the herbicide, Acid Blue 9 (AB9), in water in the presence of hydrogen peroxide (H2O2) under UV light illumination (30 W). The influence of the basic operational parameters such as amount of H2O2, irradiation time and initial concentration of AB9 on the photodegradation efficiency of the herbicide was investigated. The degradation rate of AB9 was not appreciably high when the photolysis was carried out in the absence of H2O2 and it was negligible in the absence of UV light. The photooxidative removal of the herbicide was found to follow pseudo-first-order kinetic, and hence the figure-of-merit electrical energy per order (E Eo) was considered appropriate for estimating the electrical energy efficiency. A mathematical relation between the apparent reaction rate constant and H2O2 used was applied for prediction of the electricity consumption in the photooxidative removal of AB9. The results indicated that this kinetic model, based on the initial rates of degradation, provided good prediction of the E Eo values for a variety of conditions. The results also indicated that the UV/H2O2 process was appropriate as the effective treatment method for removal of AB9 from the contaminated wastewater. PMID:18803110

  5. The EOS Aura Mission

    NASA Technical Reports Server (NTRS)

    Schoeberl, Mark R.; Douglass, A. R.; Hilsenrath, E.; Luce, M.; Barnett, J.; Beer, R.; Waters, J.; Gille, J.; Levelt, P. F.; DeCola, P.; Einaudi, Franco (Technical Monitor)

    2001-01-01

    The EOS Aura Mission is designed to make comprehensive chemical measurements of the troposphere and stratosphere. In addition the mission will make measurements of important climate variables such as aerosols, and upper tropospheric water vapor and ozone. Aura will launch in late 2003 and will fly 15 minutes behind EOS Aqua in a polar sun synchronous ascending node orbit with a 1:30 pm equator crossing time.

  6. EOS Directory

    NASA Technical Reports Server (NTRS)

    1994-01-01

    This Earth Observing System (EOS) directory is divided into two main sections: white and yellow pages. The white pages list alphabetically the names and addresses -- including e-mail, phone, and fax when available -- of all individuals involved with EOS, from graduate students to panel members to program management and more. The yellow pages list the names, affiliation, and phone number of participants divided by project management, program management, individual project participants, interdisciplinary investigations (listed alphabetically by PI), the Science Executive Committee, various panels, platforms, working groups, fellowships, and contractors.

  7. EOS workstation

    NASA Technical Reports Server (NTRS)

    Leberl, Franz; Karspeck, Milan; Millot, Michel; Maurice, Kelly; Jackson, Matt

    1992-01-01

    This final report summarizes the work done from mid-1989 until January 1992 to develop a prototype set of tools for the analysis of EOS-type images. Such images are characterized by great multiplicity and quantity. A single 'snapshot' of EOS-type imagery may contain several hundred component images so that on a particular pixel, one finds multiple gray values. A prototype EOS-sensor, AVIRIS, has 224 gray values at each pixel. The work focused on the ability to utilize very large images and continuously roam through those images, zoom and be able to hold more than one black and white or color image, for example for stereo viewing or for image comparisons. A second focus was the utilization of so-called 'image cubes', where multiple images need to be co-registered and then jointly analyzed, viewed, and manipulated. The target computer platform that was selected was a high-performance graphics superworkstation, Stardent 3000. This particular platform offered many particular graphics tools such as the Application Visualization System (AVS) or Dore, but it missed availability of commercial third-party software for relational data bases, image processing, etc. The project was able to cope with these limitations and a phase-3 activity is currently being negotiated to port the software and enhance it for use with a novel graphics superworkstation to be introduced into the market in the Spring of 1993.

  8. Integrated Use Of MERIS And Other EO Data For Water Quality And Red Tide Monitoring Along United Arab Emirates Coasts

    NASA Astrophysics Data System (ADS)

    Ceriola, G.; Avgikou, V.; Manunta, P.

    2013-12-01

    Coastal zones host a large percentage of global population and economical and productive activities and are in need of a constant monitoring. The C-wams project is focused at implementing a suite EO services targeting two growing sectors: Waste Water Treatment and Desalination plants. The coast of the United Arab Emirates (UAE) hosts some of the largest desalination plants in the world and their operation can affect and be affected by the status of the WQ near the coast: the local phenomenon known as Red Tide caused increasing damages in the last 4 years. Some actors are involved in this respect in the Persian gulf, among them the Environment Agency of Abu Dhabi (EAD). In UAE an historical study-case is being performed aimed at identifying Red Tide events using MERIS images, integrating them with other medium and higher resolution data. The present work describes its scenario and the preliminary results obtained.

  9. Remote sensing of water vapor in the near IR from EOS/MODIS

    NASA Technical Reports Server (NTRS)

    Kaufman, Yoram J.; Gao, Bo-Cai

    1992-01-01

    Consideration is given to the selection of spectral channels in the near-infrared IR which are to be employed for the derivation of total column water vapor using the MODIS instrument on the NASA's Earth Observing System. Data obtained show that the three near-IR water vapor channels on the MODIS instrument enable remote sensing of the total column water vapor with an absolute accuracy of +/- 13 percent. An absolute accuracy of +/-7 percent can be obtained if additional MODIS channels are used to decrease the effect of uncertainty in the spectral reflectance of the surface, subpixel clouds, haze, and temperature profile on the derived water vapor.

  10. Chinese Lakes Behaviors In The Framework Of Meteorology And Water Management Practices: EO Based Monitoring Lessons

    NASA Astrophysics Data System (ADS)

    Yesou, Herve; Huber, Claire; Huang, Shifeng; Lai, Xijun; Daillet-Rochette, Sylviane

    2013-12-01

    Yangtze reaches, particularly on the middle and lower ones as the human population, few hundred millions of inhabitants downstream of 3 gorges dam, depend directly on the services that wetlands provide: regulating services such as flood storage; provisioning services such as fishing, and being biodiversity holders. The two largest fresh water lakes, Poyang and Dongting Lakes, which are very valuable ecosystems in term of biodiversity maintain but also threaded by epidemics, are the core of the monitored area since 2000. This monitoring based on medium and high resolution at a high temporal frequency, ie ca 10 days has allowed characterizing trends on an intra and interring annual basis. A key result is the apparent increase of years with water default since the mid 2000, ie near one year every two years. Results of the dynamic analysis of water height and water surfaces can be now analyzed in term of climatic variations and human activities. Obtained results shown that the meteorology, ie rainfall, at Yangtze's basin scale rather than lakes' basin scale, has a significant impact on water resources. In addition, and this for the first time, the effects management mode of the 3 Gorges reservoir, ie infilling of the reservoir rapidly in October at the beginning of the dry period followed by a slow release of the stocked water appears to reinforce the trends observed in recent drought years.

  11. WebGasEOS

    2005-10-01

    WebGasEOS provides quick, user-friendly access to real gas physical properties. Using the real gas properties modules of the TOUGH-Fx project, WebGasEOS allows any user, though a web- based application, to define a multicornponent system, specify temperature and pressure, select an equation of state, and compute volumetric, thermodynamic, and fluid properties. Additional functions allow the inclusion of gaseous or liquid water, with or without added salts. The user may choose the format of the results, performmore » repeat calculations or calculations over a range of temperature and pressure, or vary compositions by simply changing form parameters, The application is publicly available on the internet and can be used at any time by anyone with a standards-compliant web browser.« less

  12. Moisture Fluxes Derived from EOS Aqua Satellite Data for the North Water Polynya Over 2003-2009

    NASA Technical Reports Server (NTRS)

    Boisvert, Linette N.; Markus, Thorsten; Parkinson, Claire L.; Vihma, Timo

    2012-01-01

    Satellite data were applied to calculate the moisture flux from the North Water polynya during a series of events spanning 2003-2009. The fluxes were calculated using bulk aerodynamic formulas with the stability effects according to the Monin-Obukhov similarity theory. Input parameters were taken from three sources: air relative humidity, air temperature, and surface temperature from the Atmospheric Infrared Sounder (AIRS) onboard NASA's Earth Observing System (EOS) Aqua satellite, sea ice concentration from the Advanced Microwave Scanning Radiometer (AMSR-E, also onboard Aqua), and wind speed from the ECMWF ERA-Interim reanalysis. Our results show the progression of the moisture fluxes from the polynya during each event, as well as their atmospheric effects after the polynya has closed up. These results were compared to results from studies on other polynyas, and fall within one standard deviation of the moisture flux estimates from these studies. Although the estimated moisture fluxes over the entire study region from AIRS are smaller in magnitude than ERA-Interim, they are more accurate due to improved temperature and relative humidity profiles and ice concentration estimates over the polynya. Error estimates were calculated to be 5.56 x10(exp -3) g/sq. m/ s, only 25% of the total moisture flux, thus suggesting that AIRS and AMSR-E can be used with confidence to study smaller scale features in the Arctic sea ice pack and can capture their atmospheric effects. These findings bode well for larger-scale studies of moisture fluxes over the entire Arctic Ocean and the thinning ice pack.

  13. EOS mapping accuracy study

    NASA Technical Reports Server (NTRS)

    Forrest, R. B.; Eppes, T. A.; Ouellette, R. J.

    1973-01-01

    Studies were performed to evaluate various image positioning methods for possible use in the earth observatory satellite (EOS) program and other earth resource imaging satellite programs. The primary goal is the generation of geometrically corrected and registered images, positioned with respect to the earth's surface. The EOS sensors which were considered were the thematic mapper, the return beam vidicon camera, and the high resolution pointable imager. The image positioning methods evaluated consisted of various combinations of satellite data and ground control points. It was concluded that EOS attitude control system design must be considered as a part of the image positioning problem for EOS, along with image sensor design and ground image processing system design. Study results show that, with suitable efficiency for ground control point selection and matching activities during data processing, extensive reliance should be placed on use of ground control points for positioning the images obtained from EOS and similar programs.

  14. Use of EO-1 Advanced Land Imager (ALI) multispectral image data and real-time field sampling for water quality mapping in the Hirfanlı Dam Lake, Turkey.

    PubMed

    Kavurmacı, Murat; Ekercin, Semih; Altaş, Levent; Kurmaç, Yakup

    2013-08-01

    This paper focuses on the evaluation of water quality variations in Hirfanlı Water Reservoir, which is one of the most important water resources in Turkey, through EO-1 (Earth Observing-1) Advanced Land Imager (ALI) multispectral data and real-time field sampling. The study was materialized in 20 different sampling points during the overpass of the EO-1 ALI sensor over the study area. A multi-linear regression technique was used to explore the relationships between radiometrically corrected EO-1 ALI image data and water quality parameters: chlorophyll a, turbidity, and suspended solids. The retrieved and verified results show that the measured and estimated values of water quality parameters are in good agreement (R (2) >0.93). The resulting thematic maps derived from EO-1 multispectral data for chlorophyll a, turbidity, and suspended solids show the spatial distribution of the water quality parameters. The results indicate that the reservoir has average nutrient values. Furthermore, chlorophyll a, turbidity, and suspended solids values increased at the upstream reservoir and shallow coast of the Hirfanlı Water Reservoir. PMID:23423869

  15. EOS-WEBSTER

    EPA Science Inventory

    The mission of EOS-WEBSTER (Earth, Oceans, and Space - WEB-based System for Terrestrial Environmental Reasearch) is to make data and information products and services concerning terrestrial, ecological and hydrological processesavailable to the Earth System Science community and...

  16. Physically-based Methods for the Estimation of Crop Water Requirements from E.O. Optical Data

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The estimation of evapotranspiration (ET) represent the basic information for the evaluation of crop water requirements. A widely used method to compute ET is based on the so-called "crop coefficient" (Kc), defined as the ratio of total evapotranspiration by reference evapotranspiration ET0. The val...

  17. EOS Aura Mission Status

    NASA Technical Reports Server (NTRS)

    Guit, William J.

    2015-01-01

    This PowerPoint presentation will discuss EOS Aura mission and spacecraft subsystem summary, recent and planned activities, inclination adjust maneuvers, propellant usage lifetime estimate. Eric Moyer, ESMO Deputy Project Manager-Technical (code 428) has reviewed and approved the slides on April 30, 2015.

  18. Eos visible imagers

    NASA Technical Reports Server (NTRS)

    Barnes, W. L.

    1990-01-01

    Some of the proposed Earth Observing System (Eos) optical imagers are examined. These imagers include: moderate resolution imaging spectrometer (MODIS); geoscience laser ranging system (GLRS); high resolution imaging spectrometer (HIRIS); the intermediate thermal infrared spectrometer (ITIR); multi-angle imaging spectrometer (MISR); earth observing scanning polarimeter (EOSP); and the lightening imaging sensor (LIS).

  19. The 1991 EOS reference handbook

    NASA Technical Reports Server (NTRS)

    Dokken, David (Editor)

    1991-01-01

    The following topics are covered: (1) The Global Change Research Program; (2) The Earth Observing System (EOS) goal and objectives; (3) primary EOS mission requirements; (4) EOS science; (5) EOS Data and Information System (EOSDIS) architecture; (6) data policy; (7) international cooperation; (8) plans and status; (9) the role of the National Oceanic and Atmospheric Administration; (10) The Global Fellowship Program; (11) management of EOS; (12) mission elements; (13) EOS instruments; (14) interdisciplinary science investigations; (15) points of contact; and (16) acronyms and abbreviations.

  20. ACIDIC DEPOSITION AND CISTERN DRINKING WATER SUPPLIES

    EPA Science Inventory

    The Water quality charecteristics, including the trace element Cd, cu, Pb, and Zn, in rainwater cistern supplies representing an area receiving acidic deposition were compared to cistern water chemistry in a control area that does not receive a significant input of acidic deposit...

  1. Sulfuric Acid and Water: Paradoxes of Dilution

    ERIC Educational Resources Information Center

    Leenson, I. A.

    2004-01-01

    On equilibrium properties of aqueous solutions of sulfuric acid, Julius Thomsen has marked that the heat evolved on diluting liquid sulfuric acid with water is a continuous function of the water used, and excluded absolutely the acceptance of definite hydrates as existing in the solution. Information about thermochemical measurement, a discussion…

  2. Archiving tools for EOS

    NASA Astrophysics Data System (ADS)

    Sindrilaru, Elvin-Alin; Peters, Andreas-Joachim; Duellmann, Dirk

    2015-12-01

    Archiving data to tape is a critical operation for any storage system, especially for the EOS system at CERN which holds production data for all major LHC experiments. Each collaboration has an allocated quota it can use at any given time therefore, a mechanism for archiving "stale" data is needed so that storage space is reclaimed for online analysis operations. The archiving tool that we propose for EOS aims to provide a robust client interface for moving data between EOS and CASTOR (tape backed storage system) while enforcing best practices when it comes to data integrity and verification. All data transfers are done using a third-party copy mechanism which ensures point-to- point communication between the source and destination, thus providing maximum aggregate throughput. Using ZMQ message-passing paradigm and a process-based approach enabled us to achieve optimal utilisation of the resources and a stateless architecture which can easily be tuned during operation. The modular design and the implementation done in a high-level language like Python, has enabled us to easily extended the code base to address new demands like offering full and incremental backup capabilities.

  3. Incorporation of stratospheric acids into water ice

    NASA Technical Reports Server (NTRS)

    Elliott, Scott; Turco, Richard P.; Toon, Owen B.; Hamill, Patrick

    1990-01-01

    Hydrochloric and hydrofluoric acids are absorbed within the water ice lattice at mole fractions maximizing below 0.00001 and 0.0001 in a variety of solid impurity studies. The absorption mechanism may be substitutional or interstitial, leading in either case to a weak permeation of stratospheric ices by the acids at equilibrium. Impurities could also inhabit grain boundaries, and the acid content of atmospheric ice crystals will then depend on details of their surface and internal microstructures. Limited evidence indicates similar properties for the absorption of HNO3. Water ice lattices saturated with acid cannot be a significant local reservoir for HCl in the polar stratosphere.

  4. Acidity of Strong Acids in Water and Dimethyl Sulfoxide.

    PubMed

    Trummal, Aleksander; Lipping, Lauri; Kaljurand, Ivari; Koppel, Ilmar A; Leito, Ivo

    2016-05-26

    Careful analysis and comparison of the available acidity data of HCl, HBr, HI, HClO4, and CF3SO3H in water, dimethyl sulfoxide (DMSO), and gas-phase has been carried out. The data include experimental and computational pKa and gas-phase acidity data from the literature, as well as high-level computations using different approaches (including the W1 theory) carried out in this work. As a result of the analysis, for every acid in every medium, a recommended acidity value is presented. In some cases, the currently accepted pKa values were revised by more than 10 orders of magnitude. PMID:27115918

  5. Simulation of acid water movement in canals

    NASA Astrophysics Data System (ADS)

    Van Truong, To; Tat Dac, Nguyen; Ngoc Phienc, Huynh

    1996-05-01

    An attempt to tackle the problem of the propagation of acid water in canals is described, and a mathematical model to simulate the acid water movement is developed, in which the jurbanite equilibrium is found to prevail. The processes of settling owing to sedimentation, precipitation and redissolution have been considered in the modelling. Data available from Tan Thanh, in the Plain of Reeds of the Mekong Delta in Viet Nam, are used as a case study.

  6. EOS Terra Validation Program

    NASA Technical Reports Server (NTRS)

    Starr, David

    1999-01-01

    The EOS Terra mission will be launched in July 1999. This mission has great relevance to the atmospheric radiation community and global change issues. Terra instruments include ASTER, CERES, MISR, MODIS and MOPITT. In addition to the fundamental radiance data sets, numerous global science data products will be generated, including various Earth radiation budget, cloud and aerosol parameters, as well as land surface, terrestrial ecology, ocean color, and atmospheric chemistry parameters. Significant investments have been made in on-board calibration to ensure the quality of the radiance observations. A key component of the Terra mission is the validation of the science data products. This is essential for a mission focused on global change issues and the underlying processes. The Terra algorithms have been subject to extensive pre-launch testing with field data whenever possible. Intensive efforts will be made to validate the Terra data products after launch. These include validation of instrument calibration (vicarious calibration) experiments, instrument and cross-platform comparisons, routine collection of high quality correlative data from ground-based networks, such as AERONET, and intensive sites, such as the SGP ARM site, as well as a variety field experiments, cruises, etc. Airborne simulator instruments have been developed for the field experiment and underflight activities including the MODIS Airborne Simulator (MAS), AirMISR, MASTER (MODIS-ASTER), and MOPITT-A. All are integrated on the NASA ER-2, though low altitude platforms are more typically used for MASTER. MATR is an additional sensor used for MOPITT algorithm development and validation. The intensive validation activities planned for the first year of the Terra mission will be described with emphasis on derived geophysical parameters of most relevance to the atmospheric radiation community. Detailed information about the EOS Terra validation Program can be found on the EOS Validation program

  7. Base-acid hybrid water electrolysis.

    PubMed

    Chen, Long; Dong, Xiaoli; Wang, Fei; Wang, Yonggang; Xia, Yongyao

    2016-02-21

    A base-acid hybrid electrolytic system with a low onset voltage of 0.78 V for water electrolysis was developed by using a ceramic Li-ion exchange membrane to separate the oxygen-evolving reaction (OER) in a basic electrolyte solution containing the Li-ion and hydrogen-evolving reaction (HER) in an acidic electrolyte solution. PMID:26804323

  8. The EOS Aura Mission

    NASA Technical Reports Server (NTRS)

    Schoebert, Mark R.; Douglass, A. R.; Hilsenrath, E.; Bhartia, P. K.; Barnett, J.; Gille, J.; Beer, R.; Gunson, M.; Waters, J.; Levelt, P. F.

    2004-01-01

    The Earth Observing System (EOS) Aura satellite is scheduled to launch in the second quarter of 2004. The Aura mission is designed to attack three science questions: (1) Is the ozone layer recovering as expected? (2) What are the sources and processes that control tropospheric pollutants? (3) What is the quantitative impact of constituents on climate change? Aura will answer these questions by globally measuring a comprehensive set of trace gases and aerosols at high vertical and horizontal resolution. Fig. 1 shows the Aura spacecraft and its four instruments.

  9. Bacterial Cyanuric Acid Hydrolase for Water Treatment.

    PubMed

    Yeom, Sujin; Mutlu, Baris R; Aksan, Alptekin; Wackett, Lawrence P

    2015-10-01

    Di- and trichloroisocyanuric acids are widely used as water disinfection agents, but cyanuric acid accumulates with repeated additions and must be removed to maintain free hypochlorite for disinfection. This study describes the development of methods for using a cyanuric acid-degrading enzyme contained within nonliving cells that were encapsulated within a porous silica matrix. Initially, three different bacterial cyanuric acid hydrolases were compared: TrzD from Acidovorax citrulli strain 12227, AtzD from Pseudomonas sp. strain ADP, and CAH from Moorella thermoacetica ATCC 39073. Each enzyme was expressed recombinantly in Escherichia coli and tested for cyanuric acid hydrolase activity using freely suspended or encapsulated cell formats. Cyanuric acid hydrolase activities differed by only a 2-fold range when comparing across the different enzymes with a given format. A practical water filtration system is most likely to be used with nonviable cells, and all cells were rendered nonviable by heat treatment at 70°C for 1 h. Only the CAH enzyme from the thermophile M. thermoacetica retained significant activity under those conditions, and so it was tested in a flowthrough system simulating a bioreactive pool filter. Starting with a cyanuric acid concentration of 10,000 μM, more than 70% of the cyanuric acid was degraded in 24 h, it was completely removed in 72 h, and a respike of 10,000 μM cyanuric acid a week later showed identical biodegradation kinetics. An experiment conducted with water obtained from municipal swimming pools showed the efficacy of the process, although cyanuric acid degradation rates decreased by 50% in the presence of 4.5 ppm hypochlorite. In total, these experiments demonstrated significant robustness of cyanuric acid hydrolase and the silica bead materials in remediation. PMID:26187963

  10. Bacterial Cyanuric Acid Hydrolase for Water Treatment

    PubMed Central

    Yeom, Sujin; Mutlu, Baris R.; Aksan, Alptekin

    2015-01-01

    Di- and trichloroisocyanuric acids are widely used as water disinfection agents, but cyanuric acid accumulates with repeated additions and must be removed to maintain free hypochlorite for disinfection. This study describes the development of methods for using a cyanuric acid-degrading enzyme contained within nonliving cells that were encapsulated within a porous silica matrix. Initially, three different bacterial cyanuric acid hydrolases were compared: TrzD from Acidovorax citrulli strain 12227, AtzD from Pseudomonas sp. strain ADP, and CAH from Moorella thermoacetica ATCC 39073. Each enzyme was expressed recombinantly in Escherichia coli and tested for cyanuric acid hydrolase activity using freely suspended or encapsulated cell formats. Cyanuric acid hydrolase activities differed by only a 2-fold range when comparing across the different enzymes with a given format. A practical water filtration system is most likely to be used with nonviable cells, and all cells were rendered nonviable by heat treatment at 70°C for 1 h. Only the CAH enzyme from the thermophile M. thermoacetica retained significant activity under those conditions, and so it was tested in a flowthrough system simulating a bioreactive pool filter. Starting with a cyanuric acid concentration of 10,000 μM, more than 70% of the cyanuric acid was degraded in 24 h, it was completely removed in 72 h, and a respike of 10,000 μM cyanuric acid a week later showed identical biodegradation kinetics. An experiment conducted with water obtained from municipal swimming pools showed the efficacy of the process, although cyanuric acid degradation rates decreased by 50% in the presence of 4.5 ppm hypochlorite. In total, these experiments demonstrated significant robustness of cyanuric acid hydrolase and the silica bead materials in remediation. PMID:26187963

  11. Eos Chaos Rocks

    NASA Technical Reports Server (NTRS)

    2006-01-01

    11 January 2006 This Mars Global Surveyor (MGS) Mars Orbiter Camera (MOC) image shows light-toned, layered rock outcrops in Eos Chaos, located near the east end of the Valles Marineris trough system. The outcrops occur in the form of a distinct, circular butte (upper half of image) and a high slope (lower half of image). The rocks might be sedimentary rocks, similar to those found elsewhere exposed in the Valles Marineris system and the chaotic terrain to the east of the region.

    Location near: 12.9oS, 49.5oW Image width: 3 km (1.9 mi) Illumination from: lower left Season: Southern Summer

  12. HDF-EOS Dump Tools

    NASA Astrophysics Data System (ADS)

    Prasad, U.; Rahabi, A.

    2001-05-01

    The following utilities developed for HDF-EOS format data dump are of special use for Earth science data for NASA's Earth Observation System (EOS). This poster demonstrates their use and application. The first four tools take HDF-EOS data files as input. HDF-EOS Metadata Dumper - metadmp Metadata dumper extracts metadata from EOS data granules. It operates by simply copying blocks of metadata from the file to the standard output. It does not process the metadata in any way. Since all metadata in EOS granules is encoded in the Object Description Language (ODL), the output of metadmp will be in the form of complete ODL statements. EOS data granules may contain up to three different sets of metadata (Core, Archive, and Structural Metadata). HDF-EOS Contents Dumper - heosls Heosls dumper displays the contents of HDF-EOS files. This utility provides detailed information on the POINT, SWATH, and GRID data sets. in the files. For example: it will list, the Geo-location fields, Data fields and objects. HDF-EOS ASCII Dumper - asciidmp The ASCII dump utility extracts fields from EOS data granules into plain ASCII text. The output from asciidmp should be easily human readable. With minor editing, asciidmp's output can be made ingestible by any application with ASCII import capabilities. HDF-EOS Binary Dumper - bindmp The binary dumper utility dumps HDF-EOS objects in binary format. This is useful for feeding the output of it into existing program, which does not understand HDF, for example: custom software and COTS products. HDF-EOS User Friendly Metadata - UFM The UFM utility tool is useful for viewing ECS metadata. UFM takes an EOSDIS ODL metadata file and produces an HTML report of the metadata for display using a web browser. HDF-EOS METCHECK - METCHECK METCHECK can be invoked from either Unix or Dos environment with a set of command line options that a user might use to direct the tool inputs and output . METCHECK validates the inventory metadata in (.met file) using The

  13. Acidities of Water and Methanol in Aqueous Solution and DMSO

    ERIC Educational Resources Information Center

    Gao, Daqing

    2009-01-01

    The relative acidities of water and methanol have been a nagging issue. In gas phase, methanol is more acidic than water by 36.0 kJ/mol; however, in aqueous solution, the acidities of methanol and water are almost identical. The acidity of an acid in solution is determined by both the intrinsic gas-phase ionization Gibbs energy and the solvent…

  14. Acid mine water aeration and treatment system

    DOEpatents

    Ackman, Terry E.; Place, John M.

    1987-01-01

    An in-line system is provided for treating acid mine drainage which basically comprises the combination of a jet pump (or pumps) and a static mixer. The jet pump entrains air into the acid waste water using a Venturi effect so as to provide aeration of the waste water while further aeration is provided by the helical vanes of the static mixer. A neutralizing agent is injected into the suction chamber of the jet pump and the static mixer is formed by plural sections offset by 90 degrees.

  15. Robotic servicing of EOS instruments

    NASA Technical Reports Server (NTRS)

    Razzaghi, Andrea I.; Juberts, Maris

    1990-01-01

    This paper addresses robotic servicing of the Earth Observing Satellite (EOS) instruments. The goals of implementing a robotic servicing system on EOS would be to maintain the instruments throughout the required mission life and minimize life-cycle costs. To address robot servicing, an initial design concept has been developed which will be applied to a representative EOS instrument. This instrument will be used as a model for determining the most practical level of servicing of its parts, and how to design these parts for robot servicing. Using this representative EOS instrument as a model, a generic design scheme will be developed that can be applied to all EOS instruments. The first task is to determine how to identify which parts must be designed for robot servicing. Next, the requirements imposed on the instruments and the servicing robot when designing for robot serviceability must be examined.

  16. Determination of benzoic acid, chlorobenzoic acids and chlorendic acid in water

    SciTech Connect

    Dietz, E.A.; Cortellucci, N.J.; Singley, K.F. )

    1993-01-01

    To characterize and conduct treatment studies of a landfill leachate an analysis procedure was required to determine concentrations of benzoic acid, the three isomers of chlorobenzoic acid and chlorendic acid. The title compounds were isolated from acidified (pH 1) water by extraction with methyl t-butyl ether. Analytes were concentrated by back-extracting the ether with 0.1 N sodium hydroxide which was separated and acidified. This solution was analyzed by C[sub 18] reversed-phase HPLC with water/acetonitrile/acetic acid eluent and UV detection at 222 nm. The method has detection limits of 200 [mu]g/L for chlorendic acid and 100 [mu]g/L for benzoic acid and each isomer of chlorobenzoic acid. Validation studies with water which was fortified with the analytes at concentrations ranging from one to ten times detection limits resulted in average recoveries of >95%.

  17. Eos Chasma Landslides

    NASA Technical Reports Server (NTRS)

    2005-01-01

    [figure removed for brevity, see original site]

    This VIS image shows several landslides within Eos Chasma. Many very large landslides have occurred within different portions of Valles Marineris. Note where the northern wall has failed in a upside-down bowl shape, releasing the material that formed the landslide deposit.

    Image information: VIS instrument. Latitude -8, Longitude 318.6 East (41.4 West). 19 meter/pixel resolution.

    Note: this THEMIS visual image has not been radiometrically nor geometrically calibrated for this preliminary release. An empirical correction has been performed to remove instrumental effects. A linear shift has been applied in the cross-track and down-track direction to approximate spacecraft and planetary motion. Fully calibrated and geometrically projected images will be released through the Planetary Data System in accordance with Project policies at a later time.

    NASA's Jet Propulsion Laboratory manages the 2001 Mars Odyssey mission for NASA's Office of Space Science, Washington, D.C. The Thermal Emission Imaging System (THEMIS) was developed by Arizona State University, Tempe, in collaboration with Raytheon Santa Barbara Remote Sensing. The THEMIS investigation is led by Dr. Philip Christensen at Arizona State University. Lockheed Martin Astronautics, Denver, is the prime contractor for the Odyssey project, and developed and built the orbiter. Mission operations are conducted jointly from Lockheed Martin and from JPL, a division of the California Institute of Technology in Pasadena.

  18. Water and UV degradable lactic acid polymers

    SciTech Connect

    Bonsignore, P.V.; Coleman, R.D.

    1990-06-26

    A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene and polyethylane glycols (PVB 6/22/90), propylene and and polypropylene (PVB 6/22/90) glycols, P-dioxanone, 1, 5 dioxepan-2-one, 1,4 -oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2% by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

  19. Water and UV degradable lactic acid polymers

    DOEpatents

    Bonsignore, P.V.; Coleman, R.D.

    1994-11-01

    A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer were selected from the class consisting of ethylene and polyethylene glycols, propylene and polypropylene glycols, P-dioxanone, 1,5 dioxepan-2-one, 1,4 -oxathialan-2-one, 1,4-dioxide and mixtures. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide where the high molecular weight polyethylene oxide is present in the range of from about 2% by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures to an agricultural site is also disclosed.

  20. Water and UV degradable lactic acid polymers

    DOEpatents

    Bonsignore, P.V.; Coleman, R.D.

    1996-10-08

    A water and UV light degradable copolymer is described made from monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene glycol, propylene glycol, P-dioxanone, 1,5 dioxepan-2-one, 1,4-oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2 by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

  1. Water and UV degradable lactic acid polymers

    DOEpatents

    Bonsignore, Patrick V.; Coleman, Robert D.

    1996-01-01

    A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene glycol, propylene glycol, P-dioxanone, 1,5 dioxepan-2-one, 1,4-oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2 by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

  2. Water and UV degradable lactic acid polymers

    DOEpatents

    Bonsignore, Patrick V.; Coleman, Robert D.

    1994-01-01

    A water and UV light degradable copolymer of monomers of lactic acid and a modifying monomer selected from the class consisting of ethylene and polyethylene glycols, propylene and polypropylene glycols, P-dioxanone, 1,5 dioxepan-2-one, 1,4 -oxathialan-2-one, 1,4-dioxide and mixtures thereof. These copolymers are useful for waste disposal and agricultural purposes. Also disclosed is a water degradable blend of polylactic acid or modified polylactic acid and high molecular weight polyethylene oxide wherein the high molecular weight polyethylene oxide is present in the range of from about 2% by weight to about 50% by weight, suitable for films. A method of applying an active material selected from the class of seeds, seedlings, pesticides, herbicides, fertilizers and mixtures thereof to an agricultural site is also disclosed.

  3. A watershed model to integrate EO data

    NASA Astrophysics Data System (ADS)

    Jauch, Eduardo; Chambel-Leitao, Pedro; Carina, Almeida; Brito, David; Cherif, Ines; Alexandridis, Thomas; Neves, Ramiro

    2013-04-01

    MOHID LAND is a open source watershed model developed by MARETEC and is part of the MOHID Framework. It integrates four mediums (or compartments): porous media, surface, rivers and atmosphere. The movement of water between these mediums are based on mass and momentum balance equations. The atmosphere medium is not explicity simulated. Instead, it's used as boundary condition to the model through meteorological properties: precipitation, solar radiation, wind speed/direction, relative humidity and air temperature. The surface medium includes the overland runoff and vegetation growth processes and is simulated using a 2D grid. The porous media includes both the unsaturated (soil) and saturated zones (aquifer) and is simulated using a 3D grid. The river flow is simulated through a 1D drainage network. All these mediums are linked through evapotranspiration and flow exchanges (infiltration, river-soil growndwater flow, surface-river overland flow). Besides the water movement, it is also possible to simulate water quality processes and solute/sediment transport. Model setup include the definition of the geometry and the properties of each one of its compartments. After the setup of the model, the only continuous input data that MOHID LAND requires are the atmosphere properties (boundary conditions) that can be provided as timeseries or spacial data. MOHID LAND has been adapted the last 4 years under FP7 and ESA projects to integrate Earth Observation (EO) data, both variable in time and in space. EO data can be used to calibrate/validate or as input/assimilation data to the model. The currently EO data used include LULC (Land Use Land Cover) maps, LAI (Leaf Area Index) maps, EVTP (Evapotranspiration) maps and SWC (Soil Water Content) maps. Model results are improved by the EO data, but the advantage of this integration is that the model can still run without the EO data. This means that model do not stop due to unavailability of EO data and can run on a forecast mode

  4. EOS Terra Validation Program

    NASA Technical Reports Server (NTRS)

    Starr, David

    2000-01-01

    The EOS Terra mission will be launched in July 1999. This mission has great relevance to the atmospheric radiation community and global change issues. Terra instruments include Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), Clouds and Earth's Radiant Energy System (CERES), Multi-Angle Imaging Spectroradiometer (MISR), Moderate Resolution Imaging Spectroradiometer (MODIS) and Measurements of Pollution in the Troposphere (MOPITT). In addition to the fundamental radiance data sets, numerous global science data products will be generated, including various Earth radiation budget, cloud and aerosol parameters, as well as land surface, terrestrial ecology, ocean color, and atmospheric chemistry parameters. Significant investments have been made in on-board calibration to ensure the quality of the radiance observations. A key component of the Terra mission is the validation of the science data products. This is essential for a mission focused on global change issues and the underlying processes. The Terra algorithms have been subject to extensive pre-launch testing with field data whenever possible. Intensive efforts will be made to validate the Terra data products after launch. These include validation of instrument calibration (vicarious calibration) experiments, instrument and cross-platform comparisons, routine collection of high quality correlative data from ground-based networks, such as AERONET, and intensive sites, such as the SGP ARM site, as well as a variety field experiments, cruises, etc. Airborne simulator instruments have been developed for the field experiment and underflight activities including the MODIS Airborne Simulator (MAS) AirMISR, MASTER (MODIS-ASTER), and MOPITT-A. All are integrated on the NASA ER-2 though low altitude platforms are more typically used for MASTER. MATR is an additional sensor used for MOPITT algorithm development and validation. The intensive validation activities planned for the first year of the Terra

  5. Complete EOS for PBX 9502

    SciTech Connect

    Menikoff, Ralph S

    2009-10-08

    PBX 9502 is an insensitive plastic-bonded explosive based on triamino-trinitrobenzene (TATB). A complete equation of state (EOS) is constructed for unreacted PBX 9502 suitable for reactive burn models, i.e., high pressure regime in which material strength is unimportant. The PBX EOS is composed of two parts: a complete EOS for TATB and a porosity model which allows for variations in the initial PBX density. The TATB EOS is based on a cold curve and a thermal model for lattice vibrations. The heat capacity, and hence thermal model, is determined by the vibrational spectrum from Raman scattering. The cold curve is calibrated to diamond anvil cell data for isothermal compression using a two-piece Keane fitting form. Hugoniot data for PBX 9502 is used as a consistency check.

  6. Acidic deposition and surface water chemistry

    NASA Astrophysics Data System (ADS)

    Church, M. R.

    A pair of back-to-back (morning and afternoon) hydrology sessions, held December 10, 1987, at the AGU Fall Meeting in San Francisco, Calif., covered “Predicting the Effects of Acidic Deposition on Surface Water Chemistry.” The combined sessions included four invited papers, 12 contributed papers, and a panel discussion at its conclusion. The gathering dealt with questions on a variety of aspects of modeling the effects of acidic deposition on surface water chemistry.Contributed papers included discussions on the representation of processes in models as well as limiting assumptions in model application (V. S. Tripathi et al., Oak Ridge National Laboratory, Oak Ridge, Tenn., and E. C. Krug, Illinois State Water Survey, Champaign), along with problems in estimating depositional inputs to catchments and thus inputs to be used in the simulation of catchment response (M. M. Reddy et al., U.S. Geological Survey, Lakewood, Colo.; and E. A. McBean, University of Waterloo, Waterloo, Canada). L. A. Baker et al. (University of Minnesota, Minneapolis) dealt with the problem of modeling seepage lake systems, an exceedingly important portion of the aquatic resources in Florida and parts of the upper U.S. Midwest. J. A. Hau and Y. Eckstein (Kent State University, Kent, Ohio) considered equilibrium modeling of two northern Ohio watersheds that receive very different loads of acidic deposition but are highly similar in other respects.

  7. Factors controlling water movement in acid spoils

    SciTech Connect

    Evangelou, V.P.; Grove, J.H.; Phillips, R.E.

    1982-12-01

    The rate of water movement through toxic spoils plays a major role in reclamation. The toxic chemical constituents found in spoils need to be leached beyond the six inch depth (the usual depth of lime incorporation) since they can easily move upward during periods of high evapotranspiration. The rate of water infiltration plays a role in effective utilization of rain water, and conversely, the amount of surface runoff dictates the degree of surface erosion. Underground water quality may be affected by rates of water movement through a toxic spoil zone. Factors that control water movement through acid spoils were investigated through the use of a column one meter long and 8.0 cm in internal diameter. The maximum hydraulic conductivity was observed in the upper portion of the column where minimum salt buildup occurred. The hydraulic conductivity in this region was 0.5 cm/hr. In the middle portion of the column where a salty (14.0 mmhos/cm) solution was encountered, the hydraulic conductivity was 0.08 cm/hr. In the lower portion of the column where the maximum salt buildup took place (16.8 mmhos/cm), the hydraulic conductivity was found to be 0.03 cm/hr. Similar results were obtained with a small column experiment using calcite and dolomite as different lime sources. The hydraulic conductivity in the dolomitic small column remained relatively unchanged with time and salt depletion.

  8. HDF-EOS 5 Validator

    NASA Technical Reports Server (NTRS)

    Ullman, Richard; Bane, Bob; Yang, Jingli

    2008-01-01

    A computer program partly automates the task of determining whether an HDF-EOS 5 file is valid in that it conforms to specifications for such characteristics as attribute names, dimensionality of data products, and ranges of legal data values. ["HDF-EOS" and variants thereof are defined in "Converting EOS Data From HDF-EOS to netCDF" (GSC-15007-1), which is the first of several preceding articles in this issue of NASA Tech Briefs.] Previously, validity of a file was determined in a tedious and error-prone process in which a person examined human-readable dumps of data-file-format information. The present software helps a user to encode the specifications for an HDFEOS 5 file, and then inspects the file for conformity with the specifications: First, the user writes the specifications in Extensible Markup Language (XML) by use of a document type definition (DTD) that is part of the program. Next, the portion of the program (denoted the validator) that performs the inspection is executed, using, as inputs, the specifications in XML and the HDF-EOS 5 file to be validated. Finally, the user examines the output of the validator.

  9. HDF-EOS Web Server

    NASA Technical Reports Server (NTRS)

    Ullman, Richard; Bane, Bob; Yang, Jingli

    2008-01-01

    A shell script has been written as a means of automatically making HDF-EOS-formatted data sets available via the World Wide Web. ("HDF-EOS" and variants thereof are defined in the first of the two immediately preceding articles.) The shell script chains together some software tools developed by the Data Usability Group at Goddard Space Flight Center to perform the following actions: Extract metadata in Object Definition Language (ODL) from an HDF-EOS file, Convert the metadata from ODL to Extensible Markup Language (XML), Reformat the XML metadata into human-readable Hypertext Markup Language (HTML), Publish the HTML metadata and the original HDF-EOS file to a Web server and an Open-source Project for a Network Data Access Protocol (OPeN-DAP) server computer, and Reformat the XML metadata and submit the resulting file to the EOS Clearinghouse, which is a Web-based metadata clearinghouse that facilitates searching for, and exchange of, Earth-Science data.

  10. Acid gas extraction of pyridine from water

    SciTech Connect

    Laitinen, A.; Kaunisto, J.

    2000-01-01

    Pyridine was extracted from aqueous solutions initially containing 5 or 15 wt % pyridine by using liquid or supercritical carbon dioxide at 10 MPa as a solvent in a mechanically agitated countercurrent extraction column. The lowest pyridine concentration in the raffinate was 0.06 wt %, whereas the pyridine concentration in the extract was 86--94 wt %. From the initial amount of pyridine, 96--99% was transferred from the feed stream to the extract by using relatively small solvent-to-feed ratios of 2.8--4.6 (kg of solvent/kg of feed). The measured distribution coefficients for the water/pyridine/carbon dioxide system ranged from 0.3 to 1 (weight units), depending on the initial pyridine concentration in water. Carbon dioxide is a particularly suitable solvent for the extraction of pyridine from concentrated aqueous solutions. The efficiency may be the result of an acid-base interaction between weakly basic pyridine solute and weakly acidic carbon dioxide solvent in an aqueous environment.

  11. Lidar instruments proposed for Eos

    NASA Technical Reports Server (NTRS)

    Grant, William B.; Browell, Edward V.

    1990-01-01

    Lidar, an acronym for light detection and ranging, represents a class of instruments that utilize lasers to send probe beams into the atmosphere or onto the surface of the Earth and detect the backscattered return in order to measure properties of the atmosphere or surface. The associated technology has matured to the point where two lidar facilities, Geodynamics Laser Ranging System (GLRS), and Laser Atmospheric Wind Sensor (LAWS) were accepted for Phase 2 studies for Eos. A third lidar facility Laser Atmospheric Sounder and Altimeter (LASA), with the lidar experiment EAGLE (Eos Atmospheric Global Lidar Experiment) was proposed for Eos. The generic lidar system has a number of components. They include controlling electronics, laser transmitters, collimating optics, a receiving telescope, spectral filters, detectors, signal chain electronics, and a data system. Lidar systems that measure atmospheric constituents or meteorological parameters record the signal versus time as the beam propagates through the atmosphere. The backscatter arises from molecular (Rayleigh) and aerosol (Mie) scattering, while attenuation arises from molecular and aerosol scattering and absorption. Lidar systems that measure distance to the Earth's surface or retroreflectors in a ranging mode record signals with high temporal resolution over a short time period. The overall characteristics and measurements objectives of the three lidar systems proposed for Eos are given.

  12. The EducEO project

    NASA Astrophysics Data System (ADS)

    Fritz, Steffen; Dias, Eduardo; Zeug, Guenther; Vescovi, Fabio; See, Linda; Sturn, Tobias; McCallum, Ian; Stammes, Piet; Snik, Frans; Hendriks, Elise

    2015-04-01

    The ESA funded EducEO project is aimed at demonstrating the potential of citizen science and crowdsourcing for Earth Observation (EO), where citizen science and crowdsourcing refer to the involvement of citizens in tasks such as data collection. The potential for using citizens in the calibration and validation of satellite imagery through in-situ measurements and image recognition is largely untapped. The EducEO project will aim to achieve good integration with networks such as GLOBE (primary and secondary education) and COST (higher education) to involve students in four different applications that will be piloted as part of the EducEO project. The presentation will provide a brief overview and initial results of these applications, which include: the iSpex tool for measuring air pollution using an iPhone; a game to classify cropland and deforested areas from high resolution satellite imagery; an application to monitor areas of forest change using radar data from Sentinel-1; and the collection of in-situ yield and production data from both farmers (using high-tech farming equipment) and students. In particular initial results and future potential of the serious game on land cover and forest change monitoring will be discussed.

  13. INFLUENCE OF AQUEOUS ALUMINUM AND ORGANIC ACIDS ON MEASUREMENT OF ACID NEUTRALIZING CAPACITY IN SURFACE WATERS

    EPA Science Inventory

    Acid neutralizing capacity (ANC) is used to quantify the acid-base status of surface waters. Acidic waters have bean defined as having ANC values less than zero, and acidification is often quantified by decreases in ANC. Measured and calculated values of ANC generally agree, exce...

  14. EOS

    Atmospheric Science Data Center

    2012-11-30

    ... program is NASA's contribution to the United States Global Change Research Program (USGCRP). The purpose of this program is "to assess the ... condition, understand its processes, predict its future state, and find ways to ensure that the collective actions of humanity on the ...

  15. Hdf-Eos in Matlab(r)

    NASA Astrophysics Data System (ADS)

    Comer, R. P.; Lawton, C.; Yale, M. M.

    2001-05-01

    Since 1998, MATLAB has supported HDF-EOS, the Earth Observing System (EOS) extension to the Hierarchical Data Format (HDF). MATLAB users can access, process, or view HDF-EOS data sets or to construct new HDF-EOS products. They can work interactively or use MATLAB as a high-level programming language, and use the MATLAB Image Processing or Mapping Toolboxes. MATLAB 6.0, released in November 2000, incorporates the latest HDF 4 (Version 4.1r3) and HDF-EOS (Version 2.5v1) libraries. MATLAB provides a family of functions that parallel the C and Fortran application programmer interfaces (APIs) provided by the NCSA HDF and NASA HDF-EOS libraries. These functions enable full access to HDF-EOS data sets, via either interactive exploration or MATLAB programs (M-files). HDF and HDF-EOS data files can be read into or written from a MATLAB workspace. API-level functions in MATLAB include HDFPT, HDFSW, and HDFGD for interfaces to HDF-EOS point, swath, or grid objects, respectively. Both high level functions and a graphical user interface (GUI) are planned for future releases. Prototypes of high level functions (HDFINFO and HDFREAD) have already been developed and successfully demonstrated on HDF-EOS data sets from the Moderate Resolution Imaging Spectroradiometer (MODIS) on board NASA's Terra (EOS AM-1) satellite and HDF data sets from Landsat 7. (R)MATLAB is a registered trademark of The MathWorks, Inc.

  16. Earth Observing System (EOS) advanced altimetry

    NASA Technical Reports Server (NTRS)

    Parsons, C. L.; Walsh, E. J.

    1988-01-01

    In the post-TOPEX era, satellite radar altimeters will be developed with the capability of measuring the earth's surface topography over a wide swath of coverage, rather than just at the satellite's nadir. The identification of potential spacecraft flight missions in the future was studied. The best opportunity was found to be the Earth Observing System (EOS). It is felt that an instrument system that has a broad appeal to the earth sciences community stands a much better chance of being selected as an EOS instrument. Consequently, the Topography and Rain Radar Imager (TARRI) will be proposed as a system that has the capability to profile the Earth's topography regardless of the surface type. The horizontal and height resolutions of interest are obviously significantly different over land, ice, and water; but, the use of radar to provide an all-weather observation capability is applicable to the whole earth. The scientific guidance for the design and development of this instrument and the eventual scientific utilization of the data produced by the TARRI will be provided by seven science teams. The teams are formed around scientific disciplines and are titled: Geology/Geophysics, Hydrology/Rain, Oceanography, Ice/Snow, Geodesy/Orbit/Attitude, Cartography, and Surface Properties/Techniques.

  17. Earth Observing System (EOS) advanced altimetry

    NASA Astrophysics Data System (ADS)

    Parsons, C. L.; Walsh, E. J.

    In the post-TOPEX era, satellite radar altimeters will be developed with the capability of measuring the earth's surface topography over a wide swath of coverage, rather than just at the satellite's nadir. The identification of potential spacecraft flight missions in the future was studied. The best opportunity was found to be the Earth Observing System (EOS). It is felt that an instrument system that has a broad appeal to the earth sciences community stands a much better chance of being selected as an EOS instrument. Consequently, the Topography and Rain Radar Imager (TARRI) will be proposed as a system that has the capability to profile the Earth's topography regardless of the surface type. The horizontal and height resolutions of interest are obviously significantly different over land, ice, and water; but, the use of radar to provide an all-weather observation capability is applicable to the whole earth. The scientific guidance for the design and development of this instrument and the eventual scientific utilization of the data produced by the TARRI will be provided by seven science teams. The teams are formed around scientific disciplines and are titled: Geology/Geophysics, Hydrology/Rain, Oceanography, Ice/Snow, Geodesy/Orbit/Attitude, Cartography, and Surface Properties/Techniques.

  18. HDF-EOS 2 and HDF-EOS 5 Compatibility Library

    NASA Technical Reports Server (NTRS)

    Ullman, Richard; Bane, Bob; Yang, Jingli

    2008-01-01

    The HDF-EOS 2 and HDF-EOS 5 Compatibility Library contains C-language functions that provide uniform access to HDF-EOS 2 and HDF-EOS 5 files through one set of application programming interface (API) calls. ("HDFEOS 2" and "HDF-EOS 5" are defined in the immediately preceding article.) Without this library, differences between the APIs of HDF-EOS 2 and HDF-EOS 5 would necessitate writing of different programs to cover HDF-EOS 2 and HDF-EOS 5. The API associated with this library is denoted "he25." For nearly every HDF-EOS 5 API call, there is a corresponding he25 API call. If a file in question is in the HDF-EOS 5 format, the code reverts to the corresponding HDF-EOS 5 call; if the file is in the HDF-EOS 2 format, the code translates the arguments to HDF-EOS 2 equivalents (if necessary), calls the HDFEOS 2 call, and retranslates the results back to HDF-EOS 5 (if necessary).

  19. Water Resource Monitoring Based on EO Data: Gained Experience After 10 Years of Dragon Programme over the Yangtze Middle Reaches: From ERS 1 to Sentinel 1 and from MERIS to HJ1 and Pleiades

    NASA Astrophysics Data System (ADS)

    Yesou, Herve; Huber, Claire; Huang, Shifeng; Studer, Mathais; Lai, Xijun; Chen, Xiaoling; Daillet, Sylviane

    2014-11-01

    Water resources monitoring from space is an application of remote sensing under full development, with arriving satellite such as the Sentinels, and of course the development of inland applications of altimetry and the future mission as SWOT. Since 10 years within the framework of the DRAGON ESA MOST programme, a monitoring of Chines major fresh water lakes, Poyang and Dongting lakes on Yangtze reaches, is realized exploiting large source of EO data. Thanks to EO data archive exploitation, the covered period starts in 2000 up to 2014, over these two core lakes, whereas, since a 2012, a similar approach is carried over the small lakes of Anhui Province. A key question is how to access to convenient satellite data with sufficient resource to insure a high temporal frequency, ie ideally with about 10 days of revisit. An opportunistic approach was followed in order to insure this data access thanks to a large ESA support, accessing Envisat and ESA TPM, as well Chinese data. From 2004 to April 2012, ENVISAT Medium resolution products, MERIS and ASAR WSM data, were the core of the monitoring system. Since the lost of Envisat, the data exploited moved from MR to HR (20-30 m), thanks to the access to large volume of HJ1 images in 2012 and 2014, as well as coverage CSK data (30m) thanks agreement with ASI. The assimilation of these data is a fine preparation for the future exploitation of Sentinel1 and 2 dataset. Furthermore a first Sentinel data have been exploited, less than 45 after satellite launch. In addition on most sensitive areas, such as the Poyang Lake natural Reserve (Jiangxi Pr) and Shenjing Lake (Anhui Prov.) a unique set of VHR data, Pleiades, Kompsat, have been exploited. The expect strategy for the coming months and years will be in a first period, the jointly exploitation of Sentinel 1 data if the Chinese areas are rapidly integrated within the Sentinel 1 acquisition scheme, jointly with the Chinese HJ1AB data. In a second time HJ1AB data would be

  20. Review of selected oceanic EM/EO scattering problems

    NASA Astrophysics Data System (ADS)

    Haller, Merrick C.

    2010-02-01

    Electromagnetic and electro-optical (EM/EO) propagation and scattering in the ocean is of interest for a wide range of science problems. For example, the biological productivity of ocean waters through photochemical processes is governed by the vertical attenuation of solar radiation. Also, EO scattering theory is the primary basis for determining biogeochemical parameters (e.g. phytoplankton, suspended sediments, and dissolved matter) from the water leaving optical radiance. In addition, EO scattering from suspended sediments and bubbles is the limiting factor for active lidar systems used to map the sea bottom. This work will review specific applications of EO/EM scattering theory with regard to the influence of bubbles and droplets on remote sensing in the nearshore ocean. The current state of understanding concerning models and applications for optical scattering from bubbles in the water column as well as microwave scattering from water droplets produced by breaking waves at the ocean surface will be discussed as well as future research directions.

  1. The selection of narrow wavebands for optimizing water quality monitoring on the rivers of Tucuman using hyperspectral remote sensor data (EO1)

    NASA Astrophysics Data System (ADS)

    Rios, V.; Rios, E.; Guyot, E.; Zelaya, D.; Lepen, F.; Padilla, P.; Soria, F.

    Remote sensing data were successfully used to estimate spatial and temporal variation of optical water quality parameters such as chlorophyll a, turbidity and Total Suspended Solids (TSS) on the Rivers of Tucumán. Relationships between optical water quality parameters and one or two broad wavebands were determined. An attempt was made to utilize portions of the electromagnetic spectrum, which minimize the effects of atmospheric anomalies, in turn normalizing the spectrally additive constants in all wavebands. Because this assumption was not met for turbidity, a first derivative constants in all wavebands. Because this assumption was not met for turbidity, a first derivative approach was used. The derivative reflectance is an alternative and theoretically more robust relationship between the water quality parameter and adjacent wavebands. The ratio of wavebands 705 and 672 were highly correlated with chlorophyll a, and the first derivative of wavebands 700 and 675 were highly correlated with turbidity. These correlations made it possible to estimate the concentration of chlorophyll a and level of turbidity in portions of Tucumán Rivers where only hyperspectral data were taken. Maps of the relative distributions of chlorophyll a and turbidity were created from the hyperspectral images of the rivers.

  2. Peracetic acid: A new biocide for industrial water applications

    SciTech Connect

    Kramer, J.F.

    1997-12-01

    Peracetic acid is rapidly cidal at low concentrations against a broad spectrum of microorganisms, including gram-positive and gram-negative bacteria, yeasts, molds, and algae under a wide variety of conditions. It is also effective against anaerobic and spore forming bacteria. Peracetic acid is effective at killing biofilm microorganisms at low concentrations and short contact times. Unlike a number of other biocides, the biocidal activity of peracetic acid is not affected by pH or water hardness and biocidal activity is retained even in the presence of organic matter. For these reasons, peracetic acid is well suited as a biocide in industrial cooling water and papermaking systems. Peracetic acid is compatible with additives commonly used in these systems. Although peracetic acid is a potent biocide, it is unique in that it does not produce toxic byproducts and its decomposition products, acetic acid, water and oxygen, are innocuous and environmentally acceptable.

  3. Seasonal spectral dynamics and carbon fluxes at core EOS sites using EO-1 Hyperion images

    NASA Astrophysics Data System (ADS)

    Lagomasino, D.; Campbell, P.; Price, R. M.

    2010-12-01

    Fluxes of water and carbon into the atmosphere are critical components in order to monitor and predict climate change. Spatial heterogeneity and seasonal changes in vegetation contribute to ambiguities in regional and global CO2 and water cycle dynamics. Satellite remote sensing is essential for monitoring the spatial and temporal dynamics of various vegetation types for the purposes of determining carbon and water fluxes. Satellite data from the EO-1 Hyperion sensor was acquired for five Earth Observing Satellite (EOS) sites, Mongu (Zambia, Africa), Konza Prairie (Kansas, USA), Duke Forest (North Carolina, USA), Barrow (Alaska, USA) and Sevilleta (New Mexico, USA). Each EOS site represented a distinct vegetative ecosystem type; hardwood forest, grassland, evergreen forest, lichens, and shrubland/grassland respectively. Satellite data was atmospherically corrected using the Atmosphere CORrection Now (ACORN) model and subsequently, the spectral reflectance data was extracted in the vicinity of existing flux towers. The EO-1 Hyperion sensor proved advantageous because of its high and continuous spectral resolution (10 nm intervals from 355 to 2578 nm wavelengths). The high spectral resolution allowed us calculate biophysical indices based on specific wavelengths in the electromagnetic spectrum that are associated with alterations in foliar chemistry and plant membrane structure (i.e., vegetation stress) brought upon by many environmental factors. Previous studies have focused on relationships within a specific site or vegetation community. This study however, incorporated many sites with different vegetation types and various geographic locations throughout the world. Monitoring the fluctuations in vegetation stress with contemporaneous environmental conditions and carbon flux measurements from each site will provide better insight into water and carbon flux dynamics in many different biomes. Noticeable spectral signatures were identified based on site specific

  4. Acoustic properties of organic acid mixtures in water

    NASA Technical Reports Server (NTRS)

    Macavei, I.; Petrisor, V.; Auslaender, D.

    1974-01-01

    The variation of the rate of propagation of ultrasounds in organic acid mixtures in water points to structural changes caused by interactions that take place under conditions of thermal agitation, at different acid concentrations. At the same time, a difference is found in the changes in velocity as a function of the length of the carbon chain of the acids in the mixture as a result of their effect on the groups of water molecules associated by hydrogen bonds.

  5. Effect of Acids on Water Vapor Uptake by Pyrogenic Silica

    PubMed

    Bogdan; Kulmala

    1997-07-01

    Effect of gaseous HCl and HNO3 on the water vapor uptake by pyrogenic silica was studied at different relative humidities (RH) for pure water and different compositions of binary and ternary vapor mixtures. Experiments showed that the ability of silica to uptake water strongly depends on RH and on the type of acids and their concentration in the vapor mixtures. At low acid concentration in the binary mixtures the influence of acids is probably small. Water uptake by silica does not change monotonically with acid concentration: at first it decreases and then starts to grow. However, the presence of acids promotes water uptake, and the effect is very significant at low RH. HCl seems to be more effective acid to enhance water uptake than HNO3 . In the case of ternary mixtures the adsorbed weight of water is a bit larger than that adsorbed from the binary mixtures. Acids are accumulated by silica surface, and the accumulation is larger for nitric acid. PMID:9241208

  6. It Security and EO Systems

    NASA Astrophysics Data System (ADS)

    Burnett, M.

    2010-12-01

    One topic that is beginning to influence the systems that support these goals is that of Information Technology (IT) Security. Unsecure systems are vulnerable to increasing attacks and other negative consequences; sponsoring agencies are correspondingly responding with more refined policies and more stringent security requirements. These affect how EO systems can meet the goals of data and service interoperability and harmonization through open access, transformation and visualization services. Contemporary systems, including the vision of a system-of-systems (such as GEOSS, the Global Earth Observation System of Systems), utilize technologies that support a distributed, global, net-centric environment. These types of systems have a high reliance on the open systems, web services, shared infrastructure and data standards. The broader IT industry has developed and used these technologies in their business and mission critical systems for many years. Unfortunately, the IT industry, and their customers have learned the importance of protecting their assets and resources (computing and information) as they have been forced to respond to an ever increasing number and more complex illegitimate “attackers”. This presentation will offer an overview of work done by the CEOS WGISS organization in summarizing security threats, the challenges to responding to them and capturing the current state of the practice within the EO community.

  7. Peracetic acid: A new biocide for industrial water applications

    SciTech Connect

    Kramer, J.F.

    1997-08-01

    Peracetic acid is rapidly cidal at low concentrations against a broad spectrum of microorganisms, including gram-positive and gram-negative bacteria, yeasts, molds, and algae under a wide variety of conditions. It is also effective against anaerobic and spore-forming bacteria. Peracetic acid is effective at killing biofilm microorganisms at low concentrations and short contact times. Unlike a number of other biocides, the biocidal activity of peracetic acid is not affected by pH or water hardness and is retained even in the presence of organic matter. For these reasons, peracetic acid is well-suited as a biocide in industrial cooling water and paper-making systems. It is also compatible with additives commonly used in these systems. Although peracetic acid is a potent biocide, it is unique in that it does not produce toxic byproducts and its decomposition products (acetic acid, water, and oxygen) are innocuous and environmentally acceptable.

  8. Subcritical Water Extraction of Amino Acids from Atacama Desert Soils

    NASA Technical Reports Server (NTRS)

    Amashukeli, Xenia; Pelletier, Christine C.; Kirby, James P.; Grunthaner, Frank J.

    2007-01-01

    Amino acids are considered organic molecular indicators in the search for extant and extinct life in the Solar System. Extraction of these molecules from a particulate solid matrix, such as Martian regolith, will be critical to their in situ detection and analysis. The goals of this study were to optimize a laboratory amino acid extraction protocol by quantitatively measuring the yields of extracted amino acids as a function of liquid water temperature and sample extraction time and to compare the results to the standard HCl vapor- phase hydrolysis yields for the same soil samples. Soil samples from the Yungay region of the Atacama Desert ( Martian regolith analog) were collected during a field study in the summer of 2005. The amino acids ( alanine, aspartic acid, glutamic acid, glycine, serine, and valine) chosen for analysis were present in the samples at concentrations of 1 - 70 parts- per- billion. Subcritical water extraction efficiency was examined over the temperature range of 30 - 325 degrees C, at pressures of 17.2 or 20.0 MPa, and for water- sample contact equilibration times of 0 - 30 min. None of the amino acids were extracted in detectable amounts at 30 degrees C ( at 17.2 MPa), suggesting that amino acids are too strongly bound by the soil matrix to be extracted at such a low temperature. Between 150 degrees C and 250 degrees C ( at 17.2 MPa), the extraction efficiencies of glycine, alanine, and valine were observed to increase with increasing water temperature, consistent with higher solubility at higher temperatures, perhaps due to the decreasing dielectric constant of water. Amino acids were not detected in extracts collected at 325 degrees C ( at 20.0 MPa), probably due to amino acid decomposition at this temperature. The optimal subcritical water extraction conditions for these amino acids from Atacama Desert soils were achieved at 200 degrees C, 17.2 MPa, and a water- sample contact equilibration time of 10 min.

  9. Water and formic acid aggregates: a molecular dynamics study.

    PubMed

    Vardanega, Delphine; Picaud, Sylvain

    2014-09-14

    Water adsorption around a formic acid aggregate has been studied by means of molecular dynamics simulations in a large temperature range including tropospheric conditions. Systems of different water contents have been considered and a large number of simulations has allowed us to determine the behavior of the corresponding binary formic acid-water systems as a function of temperature and humidity. The results clearly evidence a threshold temperature below which the system consists of water molecules adsorbed on a large formic acid grain. Above this temperature, formation of liquid-like mixed aggregates is obtained. This threshold temperature depends on the water content and may influence the ability of formic acid grains to act as cloud condensation nuclei in the Troposphere. PMID:25217941

  10. The EOS TPC analysis shell

    SciTech Connect

    Olson, D.L.

    1991-03-01

    Key features of the general purpose event-based-data analysis shell (TAS) for the EOS TPC at LBL are described including the code development/code management procedures used. The architecture is designed with a view towards a distributed and multi-processing environment. TAS is interfaced seamlessly with the CERN PAW program and provides a consistent environment for both on-line and off-line analysis. The data model used is relational tables and the data structure definitions are maintained in a commercial database (INFORMIX). The interface for analysis modules is specified and enhances group participation in the development process. The use of commercial database as a data dictionary for both the table definitions and parameters used in the TAS kernel is extremely useful and productive. 6 refs., 4 figs.

  11. Earth Observing System (EOS) Advanced Microwave Sounding Unit-A2 (EOS/AMSU-A): EOS Software Test Report

    NASA Technical Reports Server (NTRS)

    1998-01-01

    This document describes the results of the formal qualification test (FQT)/ Demonstration conducted on September 10, and 14, 1998 for the EOS AMSU-A2 instrument. The purpose of the report is to relate the results of the functional performance and interface tests of the software. This is the final submittal of the EOS/AMSU-A Software Test report.

  12. Benzoic Acid and Chlorobenzoic Acids: Thermodynamic Study of the Pure Compounds and Binary Mixtures With Water.

    PubMed

    Reschke, Thomas; Zherikova, Kseniya V; Verevkin, Sergey P; Held, Christoph

    2016-03-01

    Benzoic acid is a model compound for drug substances in pharmaceutical research. Process design requires information about thermodynamic phase behavior of benzoic acid and its mixtures with water and organic solvents. This work addresses phase equilibria that determine stability and solubility. In this work, Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) was used to model the phase behavior of aqueous and organic solutions containing benzoic acid and chlorobenzoic acids. Absolute vapor pressures of benzoic acid and 2-, 3-, and 4-chlorobenzoic acid from literature and from our own measurements were used to determine pure-component PC-SAFT parameters. Two binary interaction parameters between water and/or benzoic acid were used to model vapor-liquid and liquid-liquid equilibria of water and/or benzoic acid between 280 and 413 K. The PC-SAFT parameters and 1 binary interaction parameter were used to model aqueous solubility of the chlorobenzoic acids. Additionally, solubility of benzoic acid in organic solvents was predicted without using binary parameters. All results showed that pure-component parameters for benzoic acid and for the chlorobenzoic acids allowed for satisfying modeling phase equilibria. The modeling approach established in this work is a further step to screen solubility and to predict the whole phase region of mixtures containing pharmaceuticals. PMID:26886302

  13. Factors affecting response of surface waters to acidic deposition

    SciTech Connect

    Turner, R.S.; Johnson, D.W.; Elwood, J.W.; Van Winkle, W.; Clapp, R.B.; Reuss, J.O.

    1986-04-01

    Knowledge of watershed hydrology and of the biogeochemical reactions and elemental pools and fluxes occurring in watersheds can be used to classify the response of watersheds and surface waters to acidic deposition. A conceptual mosel is presented for classifying watersheds into those for which (1) surface water chemistry will change rapidly with deposition quality (direct response) (2) surface water chemistry will change only slowly over time (delayed response), and (3) surface water chemistry will not change significantly, even with continued acidic deposition (capacity-protected). Techniques and data available for classification of all watersheds in a region into these categories are discussed.

  14. Adsorption of humic acids and trace metals in natural waters

    NASA Technical Reports Server (NTRS)

    Leung, W. H.

    1982-01-01

    Studies concerning the interactions between suspended hydrous iron oxide and dissolved humic acids and trace metals are reported. As a major component of dissolved organic matters and its readiness for adsorption at the solid/water interface, humic acids may play a very important role in the organometallic geochemistry of suspended sediments and in determining the fate and distribution of trace metals, pesticides and anions in natural water systems. Most of the solid phases in natural waters contain oxides and hydroxides. The most simple promising theory to describe the interactions of hydrous iron oxide interface is the surface complex formation model. In this model, the adsorptions of humic acids on hydrous iron oxide may be interpreted as complex formation of the organic bases (humic acid oxyanions) with surface Fe ions. Measurements on adsorptions were made in both fresh water and seawater. Attempts have been made to fit our data to Langmuir adsorption isotherm. Adsorption equilibrium constants were determined.

  15. Maleic acid solvation in mixed water-ethanol solvents

    NASA Astrophysics Data System (ADS)

    Usacheva, T. R.; Kuz'mina, I. A.; Sharnin, V. A.; Tukumova, I. R.

    2012-04-01

    Heat effects of maleic acid dissolution in mixed water-ethanol solvents at 298.15 K are determined by means of calorimetry. A rise in exothermicity of maleic acid solvation is observed upon changes in the solvent copmosition in the direction of H2O → EtOH, the minimum being at ˜0.2 mol fraction of EtOH.

  16. Does predation risk influence habitat use by northern redbelly dace Phoxinus eos at different spatial scales?

    PubMed

    Dupuch, A; Magnan, P; Bertolo, A; Dill, L M; Proulx, M

    2009-05-01

    This study investigated the relationship between spatial variations in predation risk and abundance of northern redbelly dace Phoxinus eos at both macroscale (littoral v. pelagic zones) and microscale (structured v. open water habitats in the littoral zone) of Canadian Shield lakes. Minnow traps were placed in both structured and open water habitats in the littoral zone of 13 Canadian Shield lakes, and estimates of the relative predation risk of P. eos in both the pelagic and the littoral zones were obtained from tethering experiments. Results showed that (1) the mean abundance of P. eos in the littoral zone was positively correlated with the relative predation risk in the pelagic zone, (2) P. eos preferentially used structured over open water habitats in the littoral zone and (3) this preference was not related to the relative predation risk in the littoral zone but decreased as the relative predation risk increased in the pelagic zone. At the lake level, these results support the hypothesis that P. eos enter the littoral zone to avoid pelagic piscivores. At the littoral zone level, the results do not necessarily contradict the widely accepted view that P. eos preferentially use structured over open habitats to reduce their predation risk, but suggest that flexibility in antipredator tactics (e.g. shelter use v. shoaling) could explain the spatial distribution of P. eos between structured and open water habitats. PMID:20735640

  17. Eosinophilic Esophagitis (EE) or (EoE)

    MedlinePlus

    ... Environmental allergies to substances such as dust mites, animals, pollen and molds can play a role in EoE. For some patients, it may seem like their EoE is worse during pollen seasons. Allergy testing for these common environmental allergies is often part ...

  18. Converting from XML to HDF-EOS

    NASA Technical Reports Server (NTRS)

    Ullman, Richard; Bane, Bob; Yang, Jingli

    2008-01-01

    A computer program recreates an HDF-EOS file from an Extensible Markup Language (XML) representation of the contents of that file. This program is one of two programs written to enable testing of the schemas described in the immediately preceding article to determine whether the schemas capture all details of HDF-EOS files.

  19. Using EO-1 Hyperion to Simulate HyspIRI Products for a Coniferous Forest: The Fraction of PAR Absorbed by Chlorophyll (fAPAR(sub chl)) and Leaf Water Content (LWC)

    NASA Technical Reports Server (NTRS)

    Zhang, Qingyuan; Middleton, Elizabeth M.; Gao, Bo-Cai; Cheng, Yen-Ben

    2011-01-01

    This study presents development of prototype products for terrestrial ecosystems in preparation for the future imaging spectrometer planned for the Hyperspectral Infrared Imager (HyspIRI) mission. We present a successful demonstration example in a coniferous forest of two product prototypes: fraction of photosynthetic active radiation (PAR) absorbed by chlorophyll of a canopy (fAPAR(sub chl)) and leaf water content (LWC), for future HyspIRI implementation at 60 m spatial resolution. For this, we used existing 30 m resolution imaging spectrometer data available from the Earth Observing One (EO-1) Hyperion satellite to simulate and prototype the level one radiometrically corrected radiance (L1R) images expected from the HyspIRI visible through shortwave infrared spectrometer. The HyspIRI-like images were atmospherically corrected to obtain surface reflectance, and spectrally resampled to produce 60 m reflectance images for wavelength regions that were comparable to all seven of the MODerate resolution Imaging Spectroradiometer (MODIS) land bands. Thus, we developed MODIS-like surface reflectance in seven spectral bands at the HyspIRI-like spatial scale, which was utilized to derive fAPARchl and LWC with a coupled canopy-leaf radiative transfer model (PROSAIL2) for the coniferous forest[1]. With this study, we provide additional evidence that the fAPARchl product is more realistic for describing the physiologically active canopy than the traditional fAPAR parameter for the whole canopy (fAPAR(sub canopy)), and thus should replace it in ecosystem process models to reduce uncertainties in terrestrial carbon cycle studies and ecosystem studies.

  20. Using EO-1 Hyperion to Simulate HyspIRI Products for a Coniferous Forest: The Fraction of PAR Absorbed by Chlorophyll (fAPAR(sub chl)) and Leaf Water Content(LWC)

    NASA Technical Reports Server (NTRS)

    Zhang, Qingyuan; Middleton, Elizabeth M.; Gao, Bo-Cai; Cheng, Yen-Ben

    2012-01-01

    This paper presents development of prototype products for terrestrial ecosystems in preparation for the future imaging spectrometer planned for the Hyperspectral Infrared Imager (HyspIRI) mission. We present a successful demonstration example in a coniferous forest of two product prototypes: fraction of photosynthetically active radiation (PAR) absorbed by chlorophyll of a canopy (fAPARchl) and leaf water content (LWC), for future HyspIRI implementation at 60-m spatial resolution. For this, we used existing 30-m resolution imaging spectrometer data available from the Earth Observing One (EO-1) Hyperion satellite to simulate and prototype the level one radiometrically corrected radiance (L1R) images expected from the HyspIRI visible through shortwave infrared spectrometer. The HyspIRIlike images were atmospherically corrected to obtain surface reflectance and spectrally resampled to produce 60-m reflectance images for wavelength regions that were comparable to all seven of the MODerate resolution Imaging Spectroradiometer (MODIS) land bands. Thus, we developed MODIS-like surface reflectance in seven spectral bands at the HyspIRI-like spatial scale, which was utilized to derive fAPARchl and LWC with a coupled canopy-leaf radiative transfer model (PROSAIL2) for the coniferous forest. With this paper, we provide additional evidence that the fAPARchl product is more realistic in describing the physiologically active canopy than the traditional fAPAR parameter for the whole canopy (fAPARcanopy), and thus, it should replace it in ecosystem process models to reduce uncertainties in terrestrial carbon cycle and ecosystem studies.

  1. A theoretical study on ascorbic acid dissociation in water clusters.

    PubMed

    Demianenko, Eugeniy; Ilchenko, Mykola; Grebenyuk, Anatoliy; Lobanov, Victor; Tsendra, Oksana

    2014-03-01

    Dissociation of ascorbic acid in water has been studied by using a cluster model. It was examined by density functional theory (DFT) with the В3LYP, M06, and wB97XD functionals and a 6-311++G(d,p) basis set. The thermodynamic and kinetic characteristics of proton transfer from ascorbic acid molecule to water clusters were calculated as well as the equilibrium constants (pK a ) for the related processes. The used functionals in the DFT method together with continuum solvent models provided results close to the experimental data for the dissociation constant of ascorbic acid in aqueous solution. PMID:24567154

  2. NEUROXOTOXICITY PRODUCED BY DIBROMOACETIC ACID IN DRINKING WATER OF RATS.

    EPA Science Inventory

    The Safe Drinking Water Act requires that EPA consider noncancer endpoints for the assessment of adverse human health effects of disinfection byproducts (DBPs). Dibromoacetic acid (DBA) is one of many DBPs produced by the chlorination of drinking water. Its chlorinated analog, ...

  3. PROBABLE EFFECTS OF ACID PRECIPITATION ON PENNSYLVANIA WATERS

    EPA Science Inventory

    The purpose of this project was to search for and identify any trends in water chemistry and fish communities in Pennsylvania waters which would indicate that acid precipitation was affecting them adversely. No new data collection was to be included. Five existing data bases, inc...

  4. EFFECTS OF ACID RAIN ON WATER SUPPLIES IN THE NORTHEAST

    EPA Science Inventory

    Results of the first study concerning the impact of acid precipitation on drinking water are reported in terms of health effects in humans as measured by the U.S. Environmental Protection Agency maximum contaminant levels. The study focused on sampling surface water and groundwat...

  5. Virucidal effect of chlorinated water containing cyanuric acid.

    PubMed Central

    Yamashita, T.; Sakae, K.; Ishihara, Y.; Isomura, S.; Inoue, H.

    1988-01-01

    The inhibitory influence of cyanuric acid on the virucidal effect of chlorine was studied. The time required for 99.9% inactivation of ten enteroviruses and two adenoviruses by 0.5 mg/l free available chlorine at pH 7.0 and 25 degrees C was prolonged approximately 4.8-28.8 times by the addition of 30 mg/l cyanuric acid. Comparative inactivation of poliovirus 1 by free available chlorine with or without cyanuric acid revealed the following. The inactivation rate by 1.5 mg/l free available chlorine with 30 mg/l cyanuric acid or by 0.5 mg/l free available chlorine with 1 mg/l cyanuric acid was slower than by 0.5 mg/l free available chlorine alone. Temperature and pH did not affect the inhibitory influence of cyanuric acid on the disinfectant action of chlorine. In the swimming-pool and tap water, cyanuric acid delayed the virucidal effect of chlorine as much as in the 'clean' condition of chlorine-buffered distilled water. The available chlorine value should be increased to 1.5 mg/l when cyanuric acid is used in swimming-pool water. PMID:2850940

  6. Adsorption of oleic acid at sillimanite/water interface.

    PubMed

    Kumar, T V Vijaya; Prabhakar, S; Raju, G Bhaskar

    2002-03-15

    The interaction of oleic acid at sillimanite-water interface was studied by adsorption, FT-IR, and zeta potential measurements. The isoelectric point (IEP) of sillimanite obtained at pH 8.0 was found to shift in the presence of oleic acid. This shift in IEP was attributed to chemisorption of oleic acid on sillimanite. Adsorption experiments were conducted at pH 8.0, where the sillimanite surface is neutral. The adsorption isotherm exhibited a plateau around 5 micromol/m2 that correspond to a monolayer formation. Adsorption of oleic acid on sillimanite, alumina, and aluminum hydroxide was studied by FT-IR. Chemisorption of oleic acid on the above substrates was confirmed by FT-IR studies. Hydroxylation of mineral surface was found to be essential for the adsorption of oleic acid molecules. These surface hydroxyl sites were observed to facilitate deprotonation of oleic acid and its subsequent adsorption. Thus protons from oleic acid react with surface hydroxyl groups and form water molecules. Based on the experimental results, the mechanism of oleic acid adsorption on mineral substrate was proposed. Free energy of adsorption was estimated using the Stern-Graham equation for a sillimanite-oleate system. PMID:16290466

  7. Amino Acid Synthesis in a Supercritical Carbon Dioxide - Water System

    PubMed Central

    Fujioka, Kouki; Futamura, Yasuhiro; Shiohara, Tomoo; Hoshino, Akiyoshi; Kanaya, Fumihide; Manome, Yoshinobu; Yamamoto, Kenji

    2009-01-01

    Mars is a CO2-abundant planet, whereas early Earth is thought to be also CO2-abundant. In addition, water was also discovered on Mars in 2008. From the facts and theory, we assumed that soda fountains were present on both planets, and this affected amino acid synthesis. Here, using a supercritical CO2/liquid H2O (10:1) system which mimicked crust soda fountains, we demonstrate production of amino acids from hydroxylamine (nitrogen source) and keto acids (oxylic acid sources). In this research, several amino acids were detected with an amino acid analyzer. Moreover, alanine polymers were detected with LC-MS. Our research lights up a new pathway in the study of life’s origin. PMID:19582225

  8. Acetic acid oxidation and hydrolysis in supercritical water

    SciTech Connect

    Meyer, J.C.; Marrone, P.A.; Tester, J.W.

    1995-09-01

    Acetic acid (CH{sub 3}COOH) hydrolysis and oxidation in supercritical water were examined from 425--600 C and 246 bar at reactor residence times of 4.4 to 9.8 s. Over the range of conditions studied, acetic acid oxidation was globally 0.72 {+-} 0.15 order in acetic acid and 0.27 {+-} 0.15 order in oxygen to a 95% confidence level, with an activation energy of 168 {+-} 21 kJ/mol, a preexponential factor of 10{sup 9.9{+-}1.7}, and an induction time of about 1.5 s at 525 C. Isothermal kinetic measurements at 550 C over the range 160 to 263 bar indicated that pressure or density did not affect the rate of acetic acid oxidation as much as was previously observed in the oxidation of hydrogen or carbon monoxide in supercritical water. Major products of acetic acid oxidation in supercritical water are carbon dioxide, carbon monoxide, methane, and hydrogen. Trace amounts of propenoic acid were occasionally detected. Hydrolysis or hydrothermolysis in the absence of oxygen resulted in approximately 35% conversion of acetic acid at 600 C, 246 bar, and 8-s reactor residence time. Regression of the limited hydrolysis runs assuming a reaction rate first-order in organic gave a global rate expression with a preexponential factor of 10{sup 4.4{+-}1.1} and an activation energy of 94 {+-} 17 kJ/mol.

  9. Vector Data Model: A New Model of HDF-EOS to Support GIS Applications in EOS

    NASA Astrophysics Data System (ADS)

    Chi, E.; Edmonds, R d

    2001-05-01

    NASA's Earth Science Data Information System (ESDIS) project has an active program of research and development of systems for the storage and management of Earth science data for Earth Observation System (EOS) mission, a key program of NASA Earth Science Enterprise. EOS has adopted an extension of the Hierarchical Data Format (HDF) as the format of choice for standard product distribution. Three new EOS specific datatypes - point, swath and grid - have been defined within the HDF framework. The enhanced data format is named HDF-EOS. Geographic Information Systems (GIS) are used by Earth scientists in EOS data product generation, visualization, and analysis. There are two major data types in GIS applications, raster and vector. The current HDF-EOS handles only raster type in the swath data model. The vector data model is identified and developed as a new HDFEOS format to meet the requirements of scientists working with EOS data products in vector format. The vector model is designed using a topological data structure, which defines the spatial relationships among points, lines, and polygons. The three major topological concepts that the vector model adopts are: a) lines connect to each other at nodes (connectivity), b) lines that connect to surround an area define a polygon (area definition), and c) lines have direction and left and right sides (contiguity). The vector model is implemented in HDF by mapping the conceptual model to HDF internal data models and structures, viz. Vdata, Vgroup, and their associated attribute structures. The point, line, and polygon geometry and attribute data are stored in similar tables. Further, the vector model utilizes the structure and product metadata, which characterize the HDF-EOS. Both types of metadata are stored as attributes in HDF-EOS files, and are encoded in text format by using Object Description Language (ODL) and stored as global attributes in HDF-EOS files. EOS has developed a series of routines for storing

  10. EOS calculations for hydrothermal diamond anvil cell operation.

    PubMed

    Presser, Volker; Heiss, Martin; Nickel, Klaus G

    2008-08-01

    The hydrothermal diamond anvil cell (HDAC) is an excellent tool for high-temperature, high-pressure (hydrothermal) experiments. For an accurate determination of pressure induced by a certain temperature in an isochoric sample chamber volume, an equation of state (EOS) of water can be used instead of direct measurement. This paper reviews the theoretic background and provides all needed equations for the application of EOS of water to HDAC experiments summarizing state-of-the-art knowledge and incorporating up-to-date thermodynamic data. The p-T conditions determined using the IAPWS-95 formulation for the thermodynamic properties of ordinary water are in agreement with values obtained from direct methods or other established EOS formulations. In particular, (1) the calculation of density through the (a) melting point or (b) homogenization method along with determining (2) pressure as a function of density and temperature or (3) density as a function of pressure and temperature is explained. As a new aspect in the context of HDAC operations, the critical influence of nucleation and a strategy to overcome this problem are discussed. Furthermore, we have derived new polynomial equations, which allow the direct calculation of the fluid phase's density from the melting temperature. These are implemented in a spreadsheet program, which is freely available for interested users. PMID:19044377

  11. Aluminum in acidic surface waters: chemistry, transport, and effects.

    PubMed Central

    Driscoll, C T

    1985-01-01

    Ecologically significant concentrations of Al have been reported in surface waters draining "acid-sensitive" watersheds that are receiving elevated inputs of acidic deposition. It has been hypothesized that mineral acids from atmospheric deposition have remobilized Al previously precipitated within the soil during soil development. This Al is then thought to be transported to adjacent surface waters. Dissolved mononuclear Al occurs as aquo Al, as well as OH-, F-, SO4(2-), and organic complexes. Although past investigations have often ignored non-hydroxide complexes of Al, it appears that organic and F complexes are the predominant forms of Al in dilute (low ionic strength) acidic surface waters. The concentration of inorganic forms of Al increases exponentially with decreases in solution pH. This response is similar to the theoretical pH dependent solubility of Al mineral phases. The concentration of organic forms of Al, however, is strongly correlated with variations in organic carbon concentration of surface waters rather than pH. Elevated concentrations of Al in dilute acidic waters are of interest because: Al is an important pH buffer; Al may influence the cycling of important elements like P, organic carbon, and trace metals; and Al is potentially toxic to aquatic organisms. An understanding of the aqueous speciation of Al is essential for an evaluation of these processes. PMID:3935428

  12. EOS ASTER thermal infrared band vicarious calibration

    NASA Technical Reports Server (NTRS)

    Palluconi, F.; Tonooka, H.; Hook, S.; Abtahi, A.; Alley, R.; Thompson, T.; Hoover, G.; Zadourian, S.

    2001-01-01

    Calibration of the 5 EOS ASTER instrument emission bands (90 m pixels at surface) is being checked during the operational life of the mission using field measurements simultaneous with the image acquisition.

  13. Vacuum Energy, EoS, and the Gluon Condensate at Finite Baryon Density in QCD

    SciTech Connect

    Zhitnitsky, Ariel R.

    2007-02-27

    The Equation of States (EoS) plays the crucial role in all studies of neutron star properties. Still, a microscopical understanding of EoS remains largely an unresolved problem. We use 2-color QCD as a model to study the dependence of vacuum energy (gluon condensate in QCD) as function of chemical potential {mu} << {lambda}QCD where we find very strong and unexpected dependence on {mu}. We present the arguments suggesting that similar behavior may occur in 3-color QCD in the color superconducting phases. Such a study may be of importance for analysis of EoS when phenomenologically relevant parameters (within such models as MIT Bag model or NJL model) are fixed at zero density while the region of study lies at much higher densities not available for terrestrial tests.

  14. Building EOS capability for Malaysia - the options

    NASA Astrophysics Data System (ADS)

    Subari, M. D.; Hassan, A.

    2014-06-01

    Earth observation satellite (EOS) is currently a major tool to monitor earth dynamics and increase human understanding of earth surface process. Since the early 80s, Malaysia has been using EOS images for various applications, such as weather forecasting, land use mapping, agriculture, environment monitoring and others. Until now, all EOS images were obtained from foreign satellite systems. Realising on the strategic need of having its own capability, Malaysia embarked into EOS development programs in the early 90s. Starting with TiungSAT-1, a micro-satellite carrying small camera, then followed by RazakSAT, a small satellite carrying 2.5 m panchromatic (PAN) medium-aperture-camera, the current satellite program development, the RazakSAT-2, designed to carry a 1.0 m high resolution PAN and 4.0m multi-spectral camera, would become a strategic initiative of the government in developing and accelerating the nation's capability in the area of satellite technology and its application. Would this effort continue until all needs of the remote sensing community being fulfilled by its own EOS? This paper will analyze the intention of the Malaysian government through its National Space Policy and other related policy documents, and proposes some policy options on this. Key factors to be considered are specific data need of the EOS community, data availability and the more subjective political motivations such as national pride.

  15. New class of hybrid EoS and Bayesian M - R data analysis

    NASA Astrophysics Data System (ADS)

    Alvarez-Castillo, D.; Ayriyan, A.; Benic, S.; Blaschke, D.; Grigorian, H.; Typel, S.

    2016-03-01

    We explore systematically a new class of two-phase equations of state (EoS) for hybrid stars that is characterized by three main features: 1) stiffening of the nuclear EoS at supersaturation densities due to quark exchange effects (Pauli blocking) between hadrons, modelled by an excluded volume correction; 2) stiffening of the quark matter EoS at high densities due to multiquark interactions; and 3) possibility for a strong first-order phase transition with an early onset and large density jump. The third feature results from a Maxwell construction for the possible transition from the nuclear to a quark matter phase and its properties depend on the two parameters used for 1) and 2), respectively. Varying these two parameters, one obtains a class of hybrid EoS that yields solutions of the Tolman-Oppenheimer-Volkoff (TOV) equations for sequences of hadronic and hybrid stars in the mass-radius diagram which cover the full range of patterns according to the Alford-Han-Prakash classification following which a hybrid star branch can be either absent, connected or disconnected with the hadronic one. The latter case often includes a tiny connected branch. The disconnected hybrid star branch, also called "third family", corresponds to high-mass twin stars characterized by the same gravitational mass but different radii. We perform a Bayesian analysis and demonstrate that the observation of such a pair of high-mass twin stars would have a sufficient discriminating power to favor hybrid EoS with a strong first-order phase transition over alternative EoS.

  16. Diaromatic sulphur-containing 'naphthenic' acids in process waters.

    PubMed

    West, Charles E; Scarlett, Alan G; Tonkin, Andrew; O'Carroll-Fitzpatrick, Devon; Pureveen, Jos; Tegelaar, Erik; Gieleciak, Rafal; Hager, Darcy; Petersen, Karina; Tollefsen, Knut-Erik; Rowland, Steven J

    2014-03-15

    Polar organic compounds found in industrial process waters, particularly those originating from biodegraded petroleum residues, include 'naphthenic acids' (NA). Some NA have been shown to have acute toxicity to fish and also to produce sub-lethal effects. Whilst some of these toxic effects are produced by identifiable carboxylic acids, acids such as sulphur-containing acids, which have been detected, but not yet identified, may produce others. Therefore, in the present study, the sulphur-containing acids in oil sands process water were studied. A fraction (ca 12% by weight of the total NA containing ca 1.5% weight sulphur) was obtained by elution of methylated NA through an argentation solid phase extraction column with diethyl ether. This was examined by multidimensional comprehensive gas chromatography-mass spectrometry (GCxGC-MS) in both nominal and high resolution mass accuracy modes and by GCxGC-sulphur chemiluminescence detection (GCxGC-SCD). Interpretation of the mass spectra and retention behaviour of methyl esters of several synthesised sulphur acids and the unknowns allowed delimitation of the structures, but not complete identification. Diaromatic sulphur-containing alkanoic acids were suggested. Computer modelling of the toxicities of some of the possible acids suggested they would have similar toxicities to one another and to dehydroabietic acid. However, the sulphur-rich fraction was not toxic or estrogenic to trout hepatocytes, suggesting the concentrations of sulphur acids in this sample were too low to produce any such effects in vitro. Further samples should probably be examined for these compounds. PMID:24252453

  17. Water and acid soluble trace metals in atmospheric particles

    NASA Technical Reports Server (NTRS)

    Lindberg, S. E.; Harriss, R. C.

    1983-01-01

    Continental aerosols are collected above a deciduous forest in eastern Tennessee and subjected to selective extractions to determine the water-soluble and acid-leachable concentrations of Cd, Mn, Pb, and Zn. The combined contributions of these metals to the total aerosol mass is 0.5 percent, with approximately 70 percent of this attributable to Pb alone. A substantial fraction (approximately 50 percent or more) of the acid-leachable metals is soluble in distilled water. In general, this water-soluble fraction increases with decreasing particle size and with increasing frequency of atmospheric water vapor saturation during the sampling period. The pattern of relative solubilities (Zn being greater than Mn, which is approximately equal to Cd, which is greater than Pb) is found to be similar to the general order of the thermodynamic solubilities of the most probable salts of these elements in continental aerosols with mixed fossil fuel and soil sources.

  18. NEUTRALIZATION OF ACIDIC GROUND WATER NEAR GLOBE, ARIZONA.

    USGS Publications Warehouse

    Eychaner, James H.; Stollenwerk, Kenneth G.

    1985-01-01

    Highly acidic contaminated water is moving through a shallow aquifer and interacting with streams near Globe, Arizona. Dissolved concentrations reach 3,000 mg/L iron, 150 mg/L copper, and 16,400 mg/L total dissloved solids; pH is as low as 3. 6. Samples from 16 PVC-cased observation wells include uncontaminated, contaminated, transition, and neutralized waters. Chemical reaction with sediments and mixing with uncontaminated water neutralizes the acidic water. The reactions form a transition zone where gypsum replaces calcite and most metals precipitate. Ferric hydroxide also precipitates if sufficient oxygen is available. Abundant gypsum crystals and ferric hydroxide coatings have been recovered from well cuttings. Large sulfate concentrations produce sulfate complexes with many metals that inhibit removal of metals from solution.

  19. Occurrence of perfluoroalkyl acids in environmental waters in Vietnam.

    PubMed

    Duong, Hanh Thi; Kadokami, Kiwao; Shirasaka, Hanako; Hidaka, Rento; Chau, Hong Thi Cam; Kong, Lingxiao; Nguyen, Trung Quang; Nguyen, Thao Thanh

    2015-03-01

    This is the first nationwide study of perfluoroalkyl acids (PFAAs) in environmental waters in Vietnam. Twenty-eight river water and 22 groundwater samples collected in four major cities and 14 river water samples from the Red River were screened to investigate the occurrence and sources of 16 PFAAs. Perfluorooctane sulfonic acid (PFOS), perfluorooctanoic acid (PFOA), and perfluorononanoic acid (PFNA) were the most prevalent of 11 detected PFAAs with maximum concentrations in urban river water of 5.3, 18 and 0.93ngL(-1), respectively, and in groundwater of 8.2, 4.5 and 0.45ngL(-1), respectively. PFAAs in the Red River water were detected at low levels. PFAA concentrations in river water were higher in the rainy season than in the dry season, possibly due to storm water runoff, a common phenomenon in Southeast Asian countries. The highest concentrations of PFAAs in river water were observed in samples from highly populated and industrialized areas, perhaps sourced from sewage. The PFAA concentrations observed were similar to those in other Southeast Asian countries, but lower than in developed nations. From the composition profiles of PFAAs, industrial products containing PFAAs imported from China and Japan might be one of the major sources of PFAAs in the Vietnamese aquatic environment. According to the health-based values and advisory issued by the United States Environmental Protection Agency (USEPA), the concentrations of detected PFAAs in this study do not pose an immediate health risk to humans and aquatic organisms. PMID:25496738

  20. Relationship of CDC group EO-2 and psychrobacter immobilis.

    PubMed Central

    Hudson, M J; Hollis, D G; Weaver, R E; Galvis, C G

    1987-01-01

    Thirty strains of microorganisms previously classified in the CDC group EO-2 were studied to determine the relationship of this group and the recently proposed Psychrobacter immobilis. Results of transformation studies indicated that 9 of the 30 studied strains should be reclassified as P. immobilis. While transformation studies should be used to identify the Psychrobacter genus definitively, some presumptive characteristics useful in differentiating the CDC group EO-2 and P. immobilis were observed. The Psychrobacter genus, compared with the CDC group EO-2, grew well at 25 degrees C, lightly or not at all at 35 degrees C, and not at all at 42 degrees C, grew in nutrient broth without NaCl and with only one exception grew in 6% NaCl, usually did not produce acid from adonitol, dextrin, fructose, or D-mannitol, did not demonstrate the O-shaped cellular morphology, and usually possessed an odor resembling that noted from a phenylethyl alcohol blood agar plate. PMID:3667912

  1. Activity of Microorganisms in Acid Mine Water I. Influence of Acid Water on Aerobic Heterotrophs of a Normal Stream

    PubMed Central

    Tuttle, Jon H.; Randles, C. I.; Dugan, P. R.

    1968-01-01

    Comparison of microbial content of acid-contaminated and nonacid-contaminated streams from the same geographical area indicated that nonacid streams contained relatively low numbers of acid-tolerant heterotrophic microorganisms. The acid-tolerant aerobes survived when acid entered the stream and actually increased in number to about 2 × 103 per ml until the pH approached 3.0. The organisms then represented the heterotrophic aerobic microflora of the streams comprised of a mixture of mine drainage and nonacid water. A stream which was entirely acid drainage did not have a similar microflora. Most gram-positive aerobic and anaerobic bacteria died out very rapidly in acidic water, and they comprised a very small percentage of the microbial population of the streams examined. Iron- and sulfur-oxidizing autotrophic bacteria were present wherever mine water entered a stream system. The sulfur-oxidizing bacteria predominated over iron oxidizers. Ecological data from the field were verified by laboratory experiments designed to simulate stream conditions. PMID:5650063

  2. Extremely acid Permian lakes and ground waters in North America

    USGS Publications Warehouse

    Benison, K.C.; Goldstein, R.H.; Wopenka, B.; Burruss, R.C.; Pasteris, J.D.

    1998-01-01

    Evaporites hosted by red beds (red shales and sandstones), some 275-265 million years old, extend over a large area of the North American mid- continent. They were deposited in non-marine saline lakes, pans and mud- flats, settings that are typically assumed to have been alkaline. Here we use laser Raman microprobe analyses of fluid inclusions trapped in halites from these Permian deposits to argue for the existence of highly acidic (pH < 1) lakes and ground waters. These extremely acidic systems may have extended over an area of 200,000 km2. Modern analogues of such systems may be natural acid lake and groundwater systems (pH ~2-4) in southern Australia. Both the ancient and modern acid systems are characterized by closed drainage, arid climate, low acid-neutralizing capacity, and the oxidation of minerals such as pyrite to generate acidity. The discovery of widespread ancient acid lake and groundwater systems demands a re-evaluation of reconstructions of surface conditions of the past, and further investigations of the geochemistry and ecology of acid systems in general.

  3. Transformation of acidic poorly water soluble drugs into ionic liquids.

    PubMed

    Balk, Anja; Wiest, Johannes; Widmer, Toni; Galli, Bruno; Holzgrabe, Ulrike; Meinel, Lorenz

    2015-08-01

    Poor water solubility of active pharmaceutical ingredients (API) is a major challenge in drug development impairing bioavailability and therapeutic benefit. This study is addressing the possibility to tailor pharmaceutical and physical properties of APIs by transforming these into tetrabutylphosphonium (TBP) salts, including the generation of ionic liquids (IL). Therefore, poorly water soluble acidic APIs (Diclofenac, Ibuprofen, Ketoprofen, Naproxen, Sulfadiazine, Sulfamethoxazole, and Tolbutamide) were converted into TBP ILs or low melting salts and compared to the corresponding sodium salts. Free acids and TBP salts were characterized by NMR and IR spectroscopy, DSC and XRPD, DVS and dissolution rate measurements, release profiles, and saturation concentration measurements. TBP salts had lower melting points and glass transition temperatures and dissolution rates were improved up to a factor of 1000 as compared to the corresponding free acid. An increase in dissolution rates was at the expense of increased hygroscopicity. In conclusion, the creation of TBP ionic liquids or solid salts from APIs is a valuable concept addressing dissolution and solubility challenges of poorly water soluble acidic compounds. The data suggested that tailor-made counterions may substantially expand the formulation scientist's armamentarium to meet challenges of poorly water soluble drugs. PMID:25976317

  4. Disinfection of water in recirculating aquaculture systems with peracetic acid

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Peracetic acid (PAA) has become a favoured alternative to chlorination in the disinfection of municipal waste water in recent years. It is also commonly used in the food industry as a disinfectant. Based on PAA concentration, the disulfide linkage in enzymes and proteins of microorganisms can be bro...

  5. Biodegradable water absorbent synthesized from bacterial poly(amino acid)s.

    PubMed

    Kunioka, Masao

    2004-03-15

    Biodegradable hydrogels prepared by gamma-irradiation from microbial poly(amino acid)s have been studied. pH-Sensitive hydrogels were prepared by the gamma-irradiation of poly(gamma-glutamic acid) (PGA) produced by Bacillus subtilis and poly(epsilon-lysine) (PL) produced by Streptomyces albulus in aqueous solutions. When the gamma-irradiation dose was 19 kGy or more, and the concentration of PGA in water was 2 wt.-% or more, transparent hydrogels could be produced. For the 19 kGy dose, the produced hydrogel was very weak, however, the specific water content (wt. of absorbed water/wt. of dry hydrogel) of this PGA hydrogel was approximately 3,500. The specific water content decreased to 200, increasing when the gamma-irradiation dose was over 100 kGy. Under acid conditions or upon the addition of electrolytes, the PGA hydrogels shrunk. The PGA hydrogel was pH-sensitive and the change in the volume of the hydrogel depended on the pH value outside the hydrogel in the swelling medium. This PGA hydrogel was hydrodegradable and biodegradable. A new novel purifier reagent (coagulant), made from the PGA hydrogels, for contaminated turbid water has been found and developed by Japanese companies. A very small amount of this coagulant (only 2 ppm in turbid water) with poly(aluminum chloride) can be used for the purification of turbid water. A PL aqueous solution also can change into a hydrogel by gamma-irradiation. The specific water content of the PL hydrogel ranged from 20 to 160 depending on the preparation conditions. Under acid conditions, the PL hydrogel swelled because of the ionic repulsion of the protonated amino groups in the PL molecules. The rate of enzymatic degradation of the respective PL hydrogels by a neutral protease was much faster than the rate of simple hydrolytic degradation. PMID:15468223

  6. Natural acidity of waters in podzolized soils and potential impacts from acid precipitation

    SciTech Connect

    Stednick, J.D.; Johnson, D.W.

    1982-01-01

    Nutrient movements through sites in southeast Alaska and Washington were documented to determine net changes in chemical composition of precipitation water as it passed through a forest soil and became stream flow. These sites were not subject to acid precipitation (rainfall pH 5.8 to 7.2), yet soil water was acidified to 4.2 by natural organic acid forming processes in the podzol soils. Organic acids precipitated in the subsoils, allowing a pH increase. Stream water pH ranged from 6.5 to 7.2 indicating a natural buffering capacity that may exceed any additional acid input from acid rain. Precipitation composition was dominated by magnesium, sodium, and chloride due to the proximity of the ocean at the southeast Alaska site. Anionic constituents of the precipitation were dominated by bicarbonate at the Washington site. Soil podzolization processes concurrently increased solution color and iron concentrations in the litter and surface horizons leachates. The anion flux through the soil profile was dominated by chloride and sulfate at the southwast Alaska site, whereas at the Washington site anion flux appeared to be dominated by organic acids. Electroneutrality calculations indicated a cation deficit for the southeast Alaska site. 10 references, 2 tables.

  7. Troubled skies, troubled waters: the story of acid rain

    SciTech Connect

    Luoma, J.R.

    1984-01-01

    Ecosystems of the canoe waters and wilderness in the northern border of Minnesota and Ontario appear, despite their seeming isolation, to be affected by industrial pollution and acid rain. This book describes the history and ecology of the area, the efforts by the author and local residents to halt destructive development, and evidence from air pollution studies that pollution is taking its toll in an area of particular sensitivity to acid precipitation. The author traces the evolution of awareness about the problem to the political response of concerned environmental groups. A highly personal account, the book begins and ends with observations and impressions during the author's canoe trips.

  8. Mitigation of acid deposition: Liming of surface waters. Final report

    SciTech Connect

    Bartoshesky, J.; Price, R.; DeMuro, J.

    1989-05-01

    In recent years acid deposition has become a serious concern internationally. Scientific literature has documented the acidification of numerous lakes and streams in North America and Scandinavia resulting in the depletion or total loss of fisheries and other aquatic biota. Liming represents the only common corrective practice aimed specifically at remediating an affected acid receptor. This report reviews a range of liming technologies and liming materials, as well as the effect of surface-water liming on water quality and aquatic biota. As background to the liming discussion, the hydrologic cycle and the factors that make surface waters sensitive to acid deposition are also discussed. Finally, a brief review of some of the liming projects that have been conducted, or are currently in operation is presented, giving special emphasis to mitigation efforts in Maryland. Liming has been effectively used to counteract surface-water acidification in parts of Scandinavia, Canada, and the U.S. To date, liming has generally been shown to improve physical and chemical conditions and enhance the biological recovery of aquatic ecosystems affected by acidification.

  9. The EOS data and information system

    NASA Technical Reports Server (NTRS)

    Ramapriyan, H. K.

    1990-01-01

    The Earth Observing System (EOS) is proposed as a 1991 new initiative by NASA as part of the Mission to Planet Earth. One of the key components of the EOS program is the EOS Data and Information System (EOSDIS). Two independent Phase B studies of EOSDIS were conducted from January 1989 through April 1990. Some of the key challenges faced by EOSDIS are: satisfying the data and information needs of a diverse multidisciplinary scientific community integrating product generation algorithms for over two dozen instruments, keeping up with an orbital average data rate of over 50 Mb/sec and assuring prompt generation of standard products, reprocessing data as product generation algorithms change, and storing, and managing information about tens of Petabytes of data over the 15-year life of the mission.

  10. EOS distributed planning and scheduling prototype

    NASA Astrophysics Data System (ADS)

    Hull, Larry G.; Peters, Stephen F.; Davis, Randy

    Some of the more significant lessons learned during the development of the Earth Observing System (EOS) Distributed Planning and Scheduling Prototype are presented. The need for a central scheduler is not demonstrated. A mapping of scheduling and conflict-resolution responsibility across the nodes of the EOS distributed scheduling system is developed and shown to be both feasible and appropriate. Complex instrument scheduling is mostly accomplished at the ICC/IST (instrument control center/instrumental support terminal) with 'slidable' flexibility for slews and some kinds of calibrations resolved at the EOS Operations Center (EOC). All nodes have full visibility interinstrument contention for resource and environmental rights, e.g., vibration, thermal, and electromagnetic. The EOC assigns, by activity, initial action responsibility for conflict resolution to a node which is party to the conflict. Most interinstrument conflicts are resolved by the ICCs and ISTs during an intermediate scheduling phase while the EOC is negotiating a TDRS schedule with the NCC.

  11. ASY-EOS experiment at GSI

    NASA Astrophysics Data System (ADS)

    Russotto, P.; Acosta, L.; Adamczyk, M.; Al-Ajlan, A.; Al-Garawi, M.; Al-Homaidhi, S.; Amorini, F.; Auditore, L.; Aumann, T.; Ayyad, Y.; Baran, V.; Basrak, Z.; Benlliure, J.; Boiano, C.; Boisjoli, C.; Boretzky, K.; Brzychczyk, J.; Budzanowski, A.; Cardella, G.; Cammarata, P.; Cavallaro, S.; Chajecki, Z.; Chartier, M.; Chbihi, A.; Colonna, M.; Czech, B.; De Filippo, E.; Di Toro, M.; Famiano, M.; Le Fevre, A.; Gašsparić, A.; Geraci, E.; Grassi, L.; Greco, V.; Guazzoni, C.; Guazzoni, P.; Heil, M.; Heilborn, L.; Introzzi, R.; Isobe, T.; Kezzar, K.; Kiš, M.; Kupny, S.; Kurz, N.; La Guidara, E.; Lanzalone, G.; Lasko, P.; Leifels, Y.; Lemmon, R.; Li, Q.; Lombardo, I.; Loria, D.; Lukasik, J.; Lynch, W. G.; Marini, P.; Matthews, Z.; May, L.; Minniti, T.; Mostazo, M.; Pagano, A.; Papa, M.; Pawlowski, P.; Petrovici, M.; Pirrone, S.; Politi, G.; Porto, F.; Reifarth, R.; Reisdorf, W.; Riccio, F.; Rizzo, F.; Rosato, E.; Rossi, D.; Santoro, S.; Simon, H.; Skwirczynska, I.; Sosin, Z.; Trautmann, W.; Trifirò, A.; Trimarchi, M.; Tsang, B.; Veselsky, M.; Verde, G.; Vigilante, M.; Wieloch, A.; Wigg, P.; Wilczynski, J.; Wolter, H. H.; Wu, P.; Yennello, S.; Zambon, P.; Zetta, L.; Zoric, M.

    2012-07-01

    The elliptic-flow ratio of neutrons with respect to protons in reactions of neutron rich Heavy-Ion at intermediate energies has been recently proposed as an observable sensitive to the strength of the symmetry term in the nuclear equation of state (EOS) at supra-saturation densities. The recent results obtained from the existing FOPI/LAND data for 197Au+197Au collisions at 400 MeV/nucleon in comparison with the UrQMD model allowed a first estimate of the symmetry term of the EOS but suffer from a considerable statistical uncertainty. In order to obtain an improved data set for Au+Au collisions and to extend the study to other systems, a new experiment was carried out at the GSI laboratory by the ASY-EOS collaboration in May 2011.

  12. EOS distributed planning and scheduling prototype

    NASA Technical Reports Server (NTRS)

    Hull, Larry G.; Peters, Stephen F.; Davis, Randy

    1993-01-01

    Some of the more significant lessons learned during the development of the Earth Observing System (EOS) Distributed Planning and Scheduling Prototype are presented. The need for a central scheduler is not demonstrated. A mapping of scheduling and conflict-resolution responsibility across the nodes of the EOS distributed scheduling system is developed and shown to be both feasible and appropriate. Complex instrument scheduling is mostly accomplished at the ICC/IST (instrument control center/instrumental support terminal) with 'slidable' flexibility for slews and some kinds of calibrations resolved at the EOS Operations Center (EOC). All nodes have full visibility interinstrument contention for resource and environmental rights, e.g., vibration, thermal, and electromagnetic. The EOC assigns, by activity, initial action responsibility for conflict resolution to a node which is party to the conflict. Most interinstrument conflicts are resolved by the ICCs and ISTs during an intermediate scheduling phase while the EOC is negotiating a TDRS schedule with the NCC.

  13. EO-1 Prototyping for Environmental Applications

    NASA Astrophysics Data System (ADS)

    Campbell, P. K.; Middleton, E.; Ungar, S.; Zhang, Q.; Ong, L.; Huemmrich, K. F.

    2009-12-01

    The Earth Observing One (EO-1) Mission, launched in November, 2000 as part of NASA’s New Millennium Program, is in it’s eight year of operation. From the start it was recognized that a key criteria for evaluating the EO-1 technology and outlining future Earth science mission needs is the ability of the technology to characterize terrestrial surface state and processes. EO-1 is participating in a broad range of investigations, demonstrating the utility of imaging spectroscopy in applications relating to forestry, agriculture, species discrimination, invasive species, desertification, land-use, vulcanization, fire management, homeland security, natural and anthropogenic hazards and disaster assessments and has provided characterization for a variety of instruments on EOS platforms. By generating a high spectral and spatial resolution data set for the corral reefs and islands, it is contributing for realizing the goals of the National Decadal survey and providing an excellent platform for testing strategies to be employed in the HyspIRI mission. The EO1 Mission Science Office (MSO) is developing tools and prototypes for new science products, addressing the HyspIRI goals to assess vegetation status and health and provide vegetation spectral bio-indicators and biophysical parameters such as LAI and fAPAR at <100 m spatial resolution. These are being used to resolve variability in heterogeneous areas (e.g. agriculture, narrow shapes, urban and developed lands) and for managed ecosystems less than 10 km2. A set of invariable reference targets (e.g. sun, moon, deserts, Antarctica) are being characterised to allow cross-calibration of current and future EO sensors, comparison of land products generated by multiple sensors and retroactive processing of time series data. Such products are needed to develop Science Requirements for the next generation of hyperspectral satellite sensors and to address global societal needs.

  14. Natural acidity of waters in podzolized soils and potential impacts from acid precipitation

    SciTech Connect

    Stednick, J.D.; Johnson, D.W.

    1982-01-01

    Nutrient movements through sites in southeast Alaska and Washington were documented to determine net changes in chemical composition of precipitation water as it passed through a forest soil and became stream-flow. These sites were not subject to acid precipitation (rainfall pH 5.8 to 7.2), yet soil water was acidified to 4.2 by natural organic acid-forming processes in the podzol soils. Organic acids precipitated in the subsoils, allowing a pH increase. Streamwater pH ranged from 6.5 to 7.2 indicating a natural buffering capacity that may exceed any additional acid input from acid rain. Precipitation composition was dominated by calcium, magnesium, sodium, and chloride due to the proximity of the ocean at the southeast Alaska site. Anionic constituents of the precipitation were dominated by bicarbonate at the Washington site. Soil podzolization processes concurrently increased solution color and iron concentrations in the litter and surface horizons leachates. The anion flux through the soil profile was dominated by chloride and sulfate at the southeast Alaska site, whereas at the Washington site anion flux appeared to be dominated by organic acids. Electroneutrality calculations indicated a cation deficit for the southeast Alaska site.

  15. Early-EOS data and information system

    NASA Technical Reports Server (NTRS)

    Ludwig, George H.; Hunolt, Gregory W.

    1991-01-01

    NASA's Earth Observing System (EOS), an integral part of the U.S. Global Change Research Program, will provide simultaneous observations from a suite of instruments in low-earth orbit. The EOS Data and Information System (EOSDIS) will handle the data from those instruments, as well as provide access to observations and related information from other earth science missions. The Early-EOSDIS Program will provide initial improved support for global change research by building upon present capabilities and data, and will establish a working prototype EOSDIS for selected archiving, distribution, and information management functions by mid-1994.

  16. EOS Laser Atmosphere Wind Sounder (LAWS) investigation

    NASA Technical Reports Server (NTRS)

    Emmitt, George D.

    1991-01-01

    The related activities of the contract are outlined for the first year. These include: (1) attend team member meetings; (2) support EOS Project with science related activities; (3) prepare and Execution Phase plan; and (4) support LAWS and EOSDIS related work. Attached to the report is an appendix, 'LAWS Algorithm Development and Evaluation Laboratory (LADEL)'. Also attached is a copy of a proposal to the NASA EOS for 'LAWS Sampling Strategies and Wind Computation Algorithms -- Storm-Top Divergence Studies. Volume I: Investigation and Technical Plan, Data Plan, Computer Facilities Plan, Management Plan.'

  17. Compressive sensing in the EO/IR.

    PubMed

    Gehm, M E; Brady, D J

    2015-03-10

    We investigate the utility of compressive sensing (CS) to electro-optic and infrared (EO/IR) applications. We introduce the field through a discussion of historical antecedents and the development of the modern CS framework. Basic economic arguments (in the broadest sense) are presented regarding the applicability of CS to the EO/IR and used to draw conclusions regarding application areas where CS would be most viable. A number of experimental success stories are presented to demonstrate the overall feasibility of the approaches, and we conclude with a discussion of open challenges to practical adoption of CS methods. PMID:25968399

  18. Sulfur geochemistry of hydrothermal waters in Yellowstone National Park: IV Acid-sulfate waters

    USGS Publications Warehouse

    Kirk, Nordstrom D.; Blaine, McCleskey R.; Ball, J.W.

    2009-01-01

    Many waters sampled in Yellowstone National Park, both high-temperature (30-94 ??C) and low-temperature (0-30 ??C), are acid-sulfate type with pH values of 1-5. Sulfuric acid is the dominant component, especially as pH values decrease below 3, and it forms from the oxidation of elemental S whose origin is H2S in hot gases derived from boiling of hydrothermal waters at depth. Four determinations of pH were obtained: (1) field pH at field temperature, (2) laboratory pH at laboratory temperature, (3) pH based on acidity titration, and (4) pH based on charge imbalance (at both laboratory and field temperatures). Laboratory pH, charge imbalance pH (at laboratory temperature), and acidity pH were in close agreement for pH ??10%, a selection process was used to compare acidity, laboratory, and charge balance pH to arrive at the best estimate. Differences between laboratory and field pH can be explained based on Fe oxidation, H2S or S2O3 oxidation, CO2 degassing, and the temperature-dependence of pK2 for H2SO4. Charge imbalances are shown to be dependent on a speciation model for pH values 350 mg/L Cl) decrease as the Cl- concentration increases from boiling which appears inconsistent with the hypothesis of H2S oxidation as a source of hydrothermal SO4. This trend is consistent with the alternate hypothesis of anhydrite solubility equilibrium. Acid-sulfate water analyses are occasionally high in As, Hg, and NH3 concentrations but in contrast to acid mine waters they are low to below detection in Cu, Zn, Cd, and Pb concentrations. Even concentrations of SO4, Fe, and Al are much lower in thermal waters than acid mine waters of the same pH. This difference in water chemistry may explain why certain species of fly larvae live comfortably in Yellowstone's acid waters but have not been observed in acid rock drainage of the same pH.

  19. Liquid structure of acetic acid-water and trifluoroacetic acid-water mixtures studied by large-angle X-ray scattering and NMR.

    PubMed

    Takamuku, Toshiyuki; Kyoshoin, Yasuhiro; Noguchi, Hiroshi; Kusano, Shoji; Yamaguchi, Toshio

    2007-08-01

    The structures of acetic acid (AA), trifluoroacetic acid (TFA), and their aqueous mixtures over the entire range of acid mole fraction xA have been investigated by using large-angle X-ray scattering (LAXS) and NMR techniques. The results from the LAXS experiments have shown that acetic acid molecules mainly form a chain structure via hydrogen bonding in the pure liquid. In acetic acid-water mixtures hydrogen bonds of acetic acid-water and water-water gradually increase with decreasing xA, while the chain structure of acetic acid molecules is moderately ruptured. Hydrogen bonds among water molecules are remarkably formed in acetic acid-water mixtures at xAwater clusters eventually predominate in the mixtures at xAwater mixtures O...O hydrogen bonds among water molecules gradually increase when xA decreases, and hydrogen bonds among water molecules are significantly formed in the mixtures at xAacid and TFA molecules for acetic acid-water and TFA-water mixtures have indicated strong relationships between a structural change of the mixtures and the acid mole fraction. On the basis of both LAXS and NMR results, the structural changes of acetic acid-water and TFA-water mixtures with decreasing acid mole fraction and the effects of fluorination of the methyl group on the structure are discussed at the molecular level. PMID:17628099

  20. Advances in the hydrogeochemistry and microbiology of acid mine waters

    USGS Publications Warehouse

    Nordstrom, D. Kirk

    2000-01-01

    The last decade has witnessed a plethora of research related to the hydrogeochemistry and microbiology of acid mine waters and associated tailings and waste-rock waters. Numerous books, reviews, technical papers, and proceedings have been published that examine the complex bio-geochemical process of sulfide mineral oxidation, develop and apply geochemical models to site characterization, and characterize the microbial ecology of these environments. This review summarizes many of these recent works, and provides references for those investigating this field. Comparisons of measured versus calculated Eh and measured versus calculated pH for water samples from several field sites demonstrate the reliability of some current geochemical models for aqueous speciation and mass balances. Geochemical models are not, however, used to predict accurately time-dependent processes but to improve our understanding of these systems and to constrain possible processes that contribute to actual or potential water quality issues. Microbiological studies are demonstrating that there is much we have yet to learn about the types of different microorganisms and their function and ecology in mine-waste environments. A broad diversity of green algae, bacteria, archaea, yeasts, and fungi are encountered in acid mine waters, and a better understanding of their ecology and function may potentially enhance remediation possibilities as well as our understanding of the evolution of life.

  1. OCCURRENCE OF IODO-ACID AND IODO-THM DBPS IN U. S. CHLORAMINATED DRINKING WATERS

    EPA Science Inventory

    Iodo-acids were recently identified for the first time as DBPs in drinking water disinfected with chloramines. The iodo-acids identified included iodoacetic acid (IAA), bromoiodoacetic acid, (E)-3-bromo-3-iodo-propenoic acid, (Z)-3-bromo-3-iodo-propenoic acid, and (E)-2-iodo-3...

  2. Leveraging abscisic acid receptors for efficient water use in Arabidopsis

    PubMed Central

    Yang, Zhenyu; Liu, Jinghui; Tischer, Stefanie V.; Christmann, Alexander; Windisch, Wilhelm; Schnyder, Hans; Grill, Erwin

    2016-01-01

    Plant growth requires the influx of atmospheric CO2 through stomatal pores, and this carbon uptake for photosynthesis is inherently associated with a large efflux of water vapor. Under water deficit, plants reduce transpiration and are able to improve carbon for water exchange leading to higher water use efficiency (WUE). Whether increased WUE can be achieved without trade-offs in plant growth is debated. The signals mediating the WUE response under water deficit are not fully elucidated but involve the phytohormone abscisic acid (ABA). ABA is perceived by a family of related receptors known to mediate acclimation responses and to reduce transpiration. We now show that enhanced stimulation of ABA signaling via distinct ABA receptors can result in plants constitutively growing at high WUE in the model species Arabidopsis. WUE was assessed by three independent approaches involving gravimetric analyses, 13C discrimination studies of shoots and derived cellulose fractions, and by gas exchange measurements of whole plants and individual leaves. Plants expressing the ABA receptors RCAR6/PYL12 combined up to 40% increased WUE with high growth rates, i.e., are water productive. Water productivity was associated with maintenance of net carbon assimilation by compensatory increases of leaf CO2 gradients, thereby sustaining biomass acquisition. Leaf surface temperatures and growth potentials of plants growing under well-watered conditions were found to be reliable indicators for water productivity. The study shows that ABA receptors can be explored to generate more plant biomass per water transpired, which is a prime goal for a more sustainable water use in agriculture. PMID:27247417

  3. Leveraging abscisic acid receptors for efficient water use in Arabidopsis.

    PubMed

    Yang, Zhenyu; Liu, Jinghui; Tischer, Stefanie V; Christmann, Alexander; Windisch, Wilhelm; Schnyder, Hans; Grill, Erwin

    2016-06-14

    Plant growth requires the influx of atmospheric CO2 through stomatal pores, and this carbon uptake for photosynthesis is inherently associated with a large efflux of water vapor. Under water deficit, plants reduce transpiration and are able to improve carbon for water exchange leading to higher water use efficiency (WUE). Whether increased WUE can be achieved without trade-offs in plant growth is debated. The signals mediating the WUE response under water deficit are not fully elucidated but involve the phytohormone abscisic acid (ABA). ABA is perceived by a family of related receptors known to mediate acclimation responses and to reduce transpiration. We now show that enhanced stimulation of ABA signaling via distinct ABA receptors can result in plants constitutively growing at high WUE in the model species Arabidopsis WUE was assessed by three independent approaches involving gravimetric analyses, (13)C discrimination studies of shoots and derived cellulose fractions, and by gas exchange measurements of whole plants and individual leaves. Plants expressing the ABA receptors RCAR6/PYL12 combined up to 40% increased WUE with high growth rates, i.e., are water productive. Water productivity was associated with maintenance of net carbon assimilation by compensatory increases of leaf CO2 gradients, thereby sustaining biomass acquisition. Leaf surface temperatures and growth potentials of plants growing under well-watered conditions were found to be reliable indicators for water productivity. The study shows that ABA receptors can be explored to generate more plant biomass per water transpired, which is a prime goal for a more sustainable water use in agriculture. PMID:27247417

  4. Evaluation of water treatment sludge for ameliorating acid mine waste.

    PubMed

    Van Rensburg, L; Morgenthal, T L

    2003-01-01

    This study investigated the liming effect of water treatment sludge on acid mine spoils. The study was conducted with sludge from a water purification plant along the Vaal River catchments in South Africa. The optimum application rate for liming acid spoils and the speed and depth with which the sludge reacted with the mine waste were investigated. Chemical analysis indicated that the sludge is suitable as a liming agent because of its alkaline pH (8.08), high bicarbonate concentration (183.03 mg L(-1)), and low salinity (electrical conductivity = 76 mS m(-1)). The high cation exchange capacity of 15.47 cmol(c) kg(-1) and elevated nitrate concentration (73.16 mg L(-1)) also increase its value as an ameliorative material. The soluble concentrations for manganese, aluminum, lead, and selenium were high at a pH of 5 although only selenium (0.83 mg L(-1)) warranted some concern. According to experimental results, the application of 10 Mg ha(-1) of sludge to acid gold tailings increased the leach water pH from 4.5 to more than 7.5 and also increased the medium pH from 2.4 to 7.5. The addition of sludge further reduced the solubility of iron, manganese, copper, and zinc in the ameliorated gold tailings, but increased the electrical conductivity. The liming tempo was highest in the coal discard profile that had a coarse particle size distribution and took the longest to move through the gold tailings that had a fine particle size distribution. Results from this study indicate that the water treatment sludge investigated is suitable as a liming agent for rehabilitation of acid mine waste. PMID:14535306

  5. Removal of coagulant aluminum from water treatment residuals by acid.

    PubMed

    Okuda, Tetsuji; Nishijima, Wataru; Sugimoto, Mayo; Saka, Naoyuki; Nakai, Satoshi; Tanabe, Kazuyasu; Ito, Junki; Takenaka, Kenji; Okada, Mitsumasa

    2014-09-01

    Sediment sludge during coagulation and sedimentation in drinking water treatment is called "water treatment residuals (WTR)". Polyaluminum chloride (PAC) is mainly used as a coagulant in Japan. The recycling of WTR has been desired; one method for its reuse is as plowed soil. However, WTR reuse in this way is inhibited by the aluminum from the added PAC, because of its high adsorption capacity for phosphate and other fertilizer components. The removal of such aluminum from WTR would therefore be advantageous for its reuse as plowed soil; this research clarified the effect of acid washing on aluminum removal from WTR and on plant growth in the treated soil. The percentage of aluminum removal from raw WTR by sulphuric acid solution was around 90% at pH 3, the percentage decreasing to 40% in the case of a sun-dried sample. The maximum phosphate adsorption capacity was decreased and the available phosphorus was increased by acid washing, with 90% of aluminum removal. The enhancement of Japanese mustard spinach growth and the increased in plant uptake of phosphates following acid washing were observed. PMID:24835954

  6. Tactical E-O Reconnaissance Results

    NASA Astrophysics Data System (ADS)

    Lawson, William E.

    1987-02-01

    Through several series of demonstration flights, all recorded on magnetic tape, a wide range of electro-optical camera capabilities has been displayed. Significant insight has been made possible relative to the attributes, as well as difficiencies, of tactical EO technology.

  7. Data links for the EOS TPC

    SciTech Connect

    Bieser, F.; Jones, R.; McParland, C.

    1990-10-01

    We report on the design and performance of high speed data links and slower configuration control links used between the EOS TPC detector and the data processing electronics. Data rates of 5MBytes/s/link are maintained over 30m with optical isolation. Pedestal subtraction, hit detection, and data reordering are performed online. 3 refs., 1 fig.

  8. The EOS Data and Information System (EOSDIS)

    NASA Technical Reports Server (NTRS)

    Dozier, J.

    1992-01-01

    The Earth Observing System (EOS) is the centerpiece of NASA's Mission to Planet Earth initiative. It is a pivotal part of the U.S. Global Change Research Program and hence of the international effort to understand global change and the increasing demands of human activity. EOS consists of a space-based observing system, a Data and Information System (EOSDIS) and a scientific research program. The space component consists of two series of polar-orbiting spacecraft, the first scheduled for launch in 1998, that will collect data for 15 years. EOS is completing its conceptual design phase and is preparing to enter the design phase with the selection and construction of the instruments for the first platform. EOSDIS will allow researchers to quickly and easily access data about the Earth system. Development of EOSDIS has already begun; it will support research and analysis with existing data. Geophysical and biological products will be created from the satellite data to be used to a broad range of the scientific community. NASA has also committed to providing smaller missions - called Earth Probes - dedicated to near-term observations of specific Earth processes. The scientific research program was initiated in 1990, with funding for 28 interdisciplinary teams, to begin development of models that will use EOS data and define the data requirements from the instruments, nine facility instruments and their science teams, 23 instrument investigations and definition studies for a synthetic-aperture radar.

  9. EOS Data Products Handbook. Volume 2

    NASA Technical Reports Server (NTRS)

    Parkinson, Claire L. (Editor); Greenstone, Reynold (Editor); Closs, James (Technical Monitor)

    2000-01-01

    The EOS Data Products Handbook provides brief descriptions of the data products that will be produced from a range of missions of the Earth Observing System (EOS) and associated projects. Volume 1, originally published in 1997, covers the Tropical Rainfall Measuring Mission (TRMM), the Terra mission (formerly named EOS AM-1), and the Data Assimilation System, while this volume, Volume 2, covers the Active Cavity Radiometer Irradiance Monitor Satellite (ACRIMSAT), Aqua, Jason-1, Landsat 7, Meteor 3M/Stratospheric Aerosol and Gas Experiment III (SAGE III). the Quick Scatterometer (QuikScat), the Quick Total Ozone Mapping Spectrometer (Quik-TOMS), and the Vegetation Canopy Lidar (VCL) missions. Volume 2 follows closely the format of Volume 1, providing a list of products and an introduction and overview descriptions of the instruments and data processing, all introductory to the core of the book, which presents the individual data product descriptions, organized into 11 topical chapters. The product descriptions are followed by five appendices, which provide contact information for the EOS data centers that will be archiving and distributing the data sets, contact information for the science points of contact for the data products, references, acronyms and abbreviations, and a data products index.

  10. Perfluorooctane sulphonate and perfluorooctanoic acid in drinking and environmental waters.

    PubMed

    Rumsby, Paul C; McLaughlin, Clare L; Hall, Tom

    2009-10-13

    Perfluorooctane sulphonate (PFOS) and perfluorooctanoic acid (PFOA) are chemicals that have been used for many years as surfactants in a variety of industrial and consumer products. Owing to their persistent, bioaccumulative and toxic (PBT) characteristics, PFOS has been phased out by its principal producer and the use of PFOA has been reduced. This PBT potential and a number of pollution incidents have led in recent years to an increase in studies surveying the concentrations of PFOS and PFOA in environmental waters worldwide. This paper reviews the results of these studies, as well as the monitoring that was conducted after the pollution incidents. The results of surveys suggest that PFOS and PFOA are found in environmental waters worldwide at low levels. In general, these levels are below health-based values set by international authoritative bodies for drinking water. There have been limited measurements of these chemicals in drinking water, but again these are below health-based values, except in some cases following pollution incidents. Monitoring studies suggested that where PFOS and PFOA were detected, they were at similar levels in both source and drinking water, suggesting that drinking water treatment does not remove these chemicals. However, new data show that PFOS and PFOA are effectively removed by granular activated carbon absorbers in practice. Further research is required on the newer perfluorinated chemicals that appear to be safer, but their degradation products have not as yet been fully studied. PMID:19736236

  11. Vapor-liquid equilibria for nitric acid-water and plutonium nitrate-nitric acid-water solutions

    SciTech Connect

    Maimoni, A.

    1980-01-01

    The liquid-vapor equilibrium data for nitric acid and nitric acid-plutnonium nitrate-water solutions were examined to develop correlations covering the range of conditions encountered in nuclear fuel reprocessing. The scanty available data for plutonium nitrate solutions are of poor quality but allow an order of magnitude estimate to be made. A formal thermodynamic analysis was attempted initially but was not successful due to the poor quality of the data as well as the complex chemical equilibria involved in the nitric acid and in the plutonium nitrate solutions. Thus, while there was no difficulty in correlating activity coefficients for nitric acid solutions over relatively narrow temperature ranges, attempts to extend the correlations over the range 25/sup 0/C to the boiling point were not successful. The available data were then analyzed using empirical correlations from which normal boiling points and relative volatilities can be obtained over the concentration ranges 0 to 700 g/l Pu, 0 to 13 M nitric acid. Activity coefficients are required, however, if estimates of individual component vapor pressures are needed. The required ternary activity coefficients can be approximated from the correlations.

  12. Computed phase diagrams for the system: Sodium hydroxide-uric acid-hydrochloric acid-water

    NASA Astrophysics Data System (ADS)

    Brown, W. E.; Gregory, T. M.; Füredi-Milhofer, H.

    1987-07-01

    Renal stone formation is made complex by the variety of solid phases that are formed, by the number of components in the aqueous phase, and by the multiplicity of ionic dissociation and association processes that are involved. In the present work we apply phase diagrams calculated by the use of equilibrium constants from the ternary system sodium hydroxide-uric acid-water to simplify and make more rigorous the understanding of the factors governing dissolution and precipitation of uric acid (anhydrous and dihydrate) and sodium urate monohydrate. The system is then examined in terms of four components. Finally, procedures are described for fluids containing more than four components. The isotherms, singular points, and fields of supersaturation and undersaturation are shown in various forms of phase diagrams. This system has two notable features: (1) in the coordinates -log[H 2U] versus -log[NaOH], the solubility isotherms for anhydrous uric acid and uric acid dihydrate approximate straight lines with slopes equal to +1 over a wide range of concentrations. As a result, substantial quantities of sodium acid urate monohydrate can precipitate from solution or dissolve without changing the degree of saturation of uric acid significantly. (2) The solubility isotherm for NaHU·H 2O has a deltoid shape with the low-pH branch having a slope of infinity. As a result of the vertical slope of this isotherm, substantial quantities of uric acid can dissolve or precipitate without changing the degree of saturation of sodium acid urate monohydrate significantly. The H 2U-NaOH singular point has a pH of 6.87 at 310 K in the ternary system.

  13. The general class of Bianchi cosmological models with varying EoS parameter

    NASA Astrophysics Data System (ADS)

    Chaubey, R.; Shukla, A. K.

    2015-03-01

    This paper deals with the general class of Bianchi cosmological models with varying equation of state (EoS) parameter. We have discussed three different types of physically viable cosmological solutions of average scale factor by using a special law for deceleration parameter which is linear in time with a negative slope. The exact solutions to the corresponding field equations are obtained for three different physical viable cosmologies. The EoS parameter for deceleration parameter as well as dark energy is found to be the time varying function. We have using the latest observational data to draw a qualitative picture of the evaluation of the universe. In our constructed model, the equation of state parameter of dark energy is obtained as time varying and it is evolving with negative sign which is consistent with recent observation. We also shows that, at the early stage, the equation of state (EoS) parameter ( γ) is positive i.e. the universe was matter dominated but at large time, the universe evolving with negative values i.e. the present epoch. All physical parameters are calculated and discussed in each physical viable cosmological model.

  14. Mammalian Cell Cytotoxicity and Genotoxicity of the Haloacetic Acids, A Major Class of Drinking Water Disinfection By-Products

    EPA Science Inventory

    The haloacetic acids (HAAs) are disinfection by-products (DBPs) that are formed during the disinfection of drinking water, wastewaters and recreational pool waters. Currently, five HAAs [bromoacetic acid (BAA), dibromoacetic acid (DBAA), chloroacetic acid (CAA), dichloroacetic ac...

  15. 2016 Mission Operations Working Group: Earth Observing-1 (EO-1)

    NASA Technical Reports Server (NTRS)

    Frye, Stuart

    2016-01-01

    EO-1 Mission Status for the Constellation Mission Operations Working Group to discuss the EO-1 flight systems, mission enhancements, debris avoidance maneuver, orbital information, 5-year outlook, and new ground stations.

  16. DC diaphragm discharge in water solutions of selected organic acids

    NASA Astrophysics Data System (ADS)

    Vyhnankova, Edita J.; Hammer, Malte U.; Reuter, Stephan; Krcma, Frantisek

    2015-07-01

    Effect of four simple organic acids water solution on a DC diaphragm discharge was studied. Efficiency of the discharge was quantified by the hydrogen peroxide production determined by UV-VIS spectrometry of a H2O2 complex formed with specific titanium reagent. Automatic titration was used to study the pH behaviour after the plasma treatment. Optical emission spectroscopy overview spectra were recorded and detailed spectra of OH band and Hβ line were used to calculate the rotational temperature and comparison of the line profile (reflecting electron concentration) in the acid solutions. Contribution to the topical issue "The 14th International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XIV)", edited by Nicolas Gherardi, Ronny Brandenburg and Lars Stollenwark

  17. Water transport in water-in-oil-in-water liquid emulsion membrane system for the separation of lactic acid

    SciTech Connect

    Mok, Y.S.; Lee, W.K. )

    1994-03-01

    Liquid emulsion membranes (LEMs) were applied to the separation of lactic acid from an aqueous feed phase, and water transport (swelling) was investigated during the separation. Considering that as lactic acid was extracted into the internal stripping phase, osmotic pressure difference across the membrane was varied, the water transfer coefficient was evaluated. The water transfer coefficient was larger at higher carrier concentration and initial lactic acid concentration, which means that emulsion swelling can also be mediated by solute/carrier complexes although it is, in general, osmotically induced. The appropriate LEM formulation was given for separation and concentration of lactic acid. If both separation and concentration are desired, evidently emulsion swelling should be considered in conjunction with the transport rate of lactic acid. It was observed that the separated solute concentration in the internal phase was lowered due to swelling during the operation. Nevertheless, lactic acid could be concentrated in the internal phase more than 6 times in specific conditions, indicating that as the volume ratio of external phase to internal phase is increased, a still higher concentration in the internal phase can be obtained. 22 refs., 10 figs., 4 tabs.

  18. Acid-base chemistry of frustrated water at protein interfaces.

    PubMed

    Fernández, Ariel

    2016-01-01

    Water molecules at a protein interface are often frustrated in hydrogen-bonding opportunities due to subnanoscale confinement. As shown, this condition makes them behave as a general base that may titrate side-chain ammonium and guanidinium cations. Frustration-based chemistry is captured by a quantum mechanical treatment of proton transference and shown to remove same-charge uncompensated anticontacts at the interface found in the crystallographic record and in other spectroscopic information on the aqueous interface. Such observations are untenable within classical arguments, as hydronium is a stronger acid than ammonium or guanidinium. Frustration enables a directed Grotthuss mechanism for proton transference stabilizing same-charge anticontacts. PMID:26762189

  19. Terpolymers of ethyl acrylate/methacrylic acid/unsaturated acid ester of alcohols and acids as anti-settling agents in coal water slurries

    SciTech Connect

    Savoly, A.; Villa, J.L.; Grinstein, R.H.; Nachfolger, S.J.

    1988-05-17

    This patent describes a pumpable stabilized coal water slurry, having a coal content of at least about 50% by weight wherein at least 80% of the coal particles are about 200 mesh or finer, containing from about 0.01% to about 1% by weight of the slurry of a water soluble terpolymer of ethylacrylate (A), metacrylic acid (B) and a third monomer (C) selected from the group consisting of an unsaturated carboxylic acid ester of an alcohol and an ethoxylated carboxylic acid. The unsaturated carboxylic acid is a mono- or di- basic unsaturated carboxylic acid of 3 to 10 carbon atoms selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, fumaric acid, and maleic acid.

  20. Thermal properties of phosphoric acid-doped polybenzimidazole membranes in water and methanol-water mixtures

    NASA Astrophysics Data System (ADS)

    Nores-Pondal, Federico J.; Buera, M. Pilar; Corti, Horacio R.

    The thermal properties of phosphoric acid-doped poly[2-2‧-(m-phenylene)-5-5‧ bi-benzimidazole] (PBI) and poly[2,5-benzimidazole] (ABPBI) membranes, ionomeric materials with promising properties to be used as electrolytes in direct methanol and in high temperature polymer electrolyte membrane (PEM) fuel cells, were studied by means of differential scanning calorimetry (DSC) technique in the temperature range from -145 °C to 200 °C. The DSC scans of samples equilibrated in water at different relative humidities (RH) and in liquid water-methanol mixtures were analyzed in relation to glass transition, water crystallization/melting and solvent desorption in different temperature regions. The thermal relaxation observed in the very low temperature region could be ascribed to the glass transition of the H 3PO 4-H 2O mixture confined in the polymeric matrix. After cooling the samples up to -145 °C, frozen water was detected in PBI and ABPBI at different RH, although at 100% RH less amount of water had crystallized than that observed in Nafion membranes under the same conditions. Even more important is the fact that the freezing degree of water is much lower in ABPBI membranes equilibrated in liquid water-methanol mixtures than that observed for PBI and, in a previous study, for Nafion. Thus, apart from other well known properties, acid-doped ABPBI emerges as an excellent ionomer for applications in direct methanol fuel cells working in cold environments.

  1. Millard coffin is appointed Eos Tectonophysics editor

    NASA Astrophysics Data System (ADS)

    Millard F. Coffin, of the University of Texas Institute for Geophysics (UTIG), has been named the Tectonophysics Editor of Eos for a term extending through 1998. He succeeds Louise Kellogg of the University of California-Davis.Recently, Coffin completed a term as associate editor for the solid Earth section of the Journal of Geophysical Research, and is looking forward to the move from a monthly to a weekly publication. His goal is are to serve the entire tectonophysics community, encompassing marine, terrestrial, and planetary research, through timely and frequent news items, a vigorous idea and results forum, and occasional review articles. He believes that the communication among field workers, experimentalists, and modelers afforded by Eos will benefit tectonophysicists strongly as well as effectively convey tectonophysics results to a broader audience.

  2. Novel EO/IR sensor technologies

    NASA Astrophysics Data System (ADS)

    Lewis, Keith

    2011-10-01

    The requirements for advanced EO/IR sensor technologies are discussed in the context of evolving military operations, with significant emphasis on the development of new sensing technologies to meet the challenges posed by asymmetric threats. The Electro-Magnetic Remote Sensing (EMRS DTC) was established in 2003 to provide a centre of excellence in sensor research and development, supporting new capabilities in key military areas such as precision attack, battlespace manoeuvre and information superiority. In the area of advanced electro-optic technology, the DTC has supported work on discriminative imaging, advanced detectors, laser components/technologies, and novel optical techniques. This paper provides a summary of some of the EO/IR technologies explored by the DTC.

  3. Strange particle measurements from the EOS TPC

    SciTech Connect

    Justice, M.

    1995-02-01

    A high statistics sample of {Lambda}`s produced in 2 GeV/nucleon {sup 5}8Ni + {sup nat}Cu collisions has been obtained with the EOS Time Projection Chamber at the Bevalac. The coverage of the EOS TPC is essentially 100% for y > y{sub cm} and extends down to P{sub T} = 0 where interesting effects such as collective radial expansion may be important. In addition, the detection of a majority of the charged particles in the TPC, along with the presence of directed flow for protons and heavier fragments at this beam energy, allows for the correlation of A production with respect to the event reaction plane. Our preliminary analysis indicates the first observation of a sidewards flow signature for A`s. Comparisons with the cascade code ARC are made.

  4. Inactivation of H1N1 viruses exposed to acidic ozone water

    NASA Astrophysics Data System (ADS)

    Uhm, Han S.; Lee, Kwang H.; Seong, Baik L.

    2009-10-01

    The inactivation of H1N1 viruses upon exposure to acidic ozone water was investigated using chicken allantoic fluids of different dilutions, pH values, and initial ozone concentrations. The inactivation effect of the acidic ozone water was found to be stronger than the inactivation effect of the ozone water combined with the degree of acidity, indicating a synergic effect of acidity on ozone decay in water. It is also shown that acidic ozone water with a pH value of 4 or less is very effective means of virus inactivation if provided in conjunction with an ozone concentration of 20 mg/l or higher.

  5. 76 FR 31892 - Retrospective Review Under E.O. 13563

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-06-02

    ... ADMINISTRATION 20 CFR Chapter III Retrospective Review Under E.O. 13563 AGENCY: Social Security Administration. ACTION: Request for information. SUMMARY: In accordance with Executive Order (E.O.) 13563, ``Improving... . SUPPLEMENTARY INFORMATION: On January 18, 2011, the President issued E.O. 13563, ``Improving Regulation...

  6. New Editors, Editorial Advisory Board for Eos

    NASA Astrophysics Data System (ADS)

    Richman, Barbara T.

    2010-11-01

    Eos has two new editors and, with this issue, a revitalized Editorial Advisory Board. Christina M. S. Cohen, of the California Institute of Technology, is the new editor for space sciences. She succeeds Manuel Grande, who had served since 2006. Carol A. Stein, of the University of Illinois at Chicago, is the new editor for solid Earth. She succeeds John W. Geissman, who has been solid Earth editor since 2001; he will continue through the end of 2010.

  7. Radar E-O image fusion

    NASA Technical Reports Server (NTRS)

    Oneil, William F.

    1993-01-01

    The fusion of radar and electro-optic (E-O) sensor images presents unique challenges. The two sensors measure different properties of the real three-dimensional (3-D) world. Forming the sensor outputs into a common format does not mask these differences. In this paper, the conditions under which fusion of the two sensor signals is possible are explored. The program currently planned to investigate this problem is briefly discussed.

  8. The EOS CERES Global Cloud Mask

    NASA Technical Reports Server (NTRS)

    Berendes, T. A.; Welch, R. M.; Trepte, Q.; Schaaf, C.; Baum, B. A.

    1996-01-01

    To detect long-term climate trends, it is essential to produce long-term and consistent data sets from a variety of different satellite platforms. With current global cloud climatology data sets, such as the International Satellite Cloud Climatology Experiment (ISCCP) or CLAVR (Clouds from Advanced Very High Resolution Radiometer), one of the first processing steps is to determine whether an imager pixel is obstructed between the satellite and the surface, i.e., determine a cloud 'mask.' A cloud mask is essential to studies monitoring changes over ocean, land, or snow-covered surfaces. As part of the Earth Observing System (EOS) program, a series of platforms will be flown beginning in 1997 with the Tropical Rainfall Measurement Mission (TRMM) and subsequently the EOS-AM and EOS-PM platforms in following years. The cloud imager on TRMM is the Visible/Infrared Sensor (VIRS), while the Moderate Resolution Imaging Spectroradiometer (MODIS) is the imager on the EOS platforms. To be useful for long term studies, a cloud masking algorithm should produce consistent results between existing (AVHRR) data, and future VIRS and MODIS data. The present work outlines both existing and proposed approaches to detecting cloud using multispectral narrowband radiance data. Clouds generally are characterized by higher albedos and lower temperatures than the underlying surface. However, there are numerous conditions when this characterization is inappropriate, most notably over snow and ice of the cloud types, cirrus, stratocumulus and cumulus are the most difficult to detect. Other problems arise when analyzing data from sun-glint areas over oceans or lakes over deserts or over regions containing numerous fires and smoke. The cloud mask effort builds upon operational experience of several groups that will now be discussed.

  9. Autonomous Science on the EO-1 Mission

    NASA Technical Reports Server (NTRS)

    Chien, S.; Sherwood, R.; Tran, D.; Castano, R.; Cichy, B.; Davies, A.; Rabideau, G.; Tang, N.; Burl, M.; Mandl, D.; Frye, S.; Hengemihle, J.; Agostino, J. D.; Bote, R.; Trout, B.; Shulman, S.; Ungar, S.; Gaasbeck, J. Van; Boyer, D.; Griffin, M.; Burke, H.; Greeley, R.; Doggett, T.; Williams, K.; Baker, V.

    2003-01-01

    In mid-2003, we will fly software to detect science events that will drive autonomous scene selectionon board the New Millennium Earth Observing 1 (EO-1) spacecraft. This software will demonstrate the potential for future space missions to use onboard decision-making to detect science events and respond autonomously to capture short-lived science events and to downlink only the highest value science data.

  10. The UARS and EOS Microwave Limb Sounder (MLS) Experiments.

    NASA Astrophysics Data System (ADS)

    Waters, J. W.; Read, W. G.; Froidevaux, L.; Jarnot, R. F.; Cofield, R. E.; Flower, D. A.; Lau, G. K.; Pickett, H. M.; Santee, M. L.; Wu, D. L.; Boyles, M. A.; Burke, J. R.; Lay, R. R.; Loo, M. S.; Livesey, N. J.; Lungu, T. A.; Manney, G. L.; Nakamura, L. L.;  Perun, V. S.;  Ridenoure, B. P.;  Shippony, Z.;  Siegel, P. H.;  Thurstans, R. P.;  Harwood, R. S.;  Pumphrey, H. C.;  Filipiak, M. J.

    1999-01-01

    The Microwave Limb Sounder (MLS) experiments obtain measurements of atmospheric composition, temperature, and pressure by observations of millimeter- and submillimeter-wavelength thermal emission as the instrument field of view is scanned through the atmospheric limb. Features of the measurement technique include the ability to measure many atmospheric gases as well as temperature and pressure, to obtain measurements even in the presence of dense aerosol and cirrus, and to provide near-global coverage on a daily basis at all times of day and night from an orbiting platform. The composition measurements are relatively insensitive to uncertainties in atmospheric temperature. An accurate spectroscopic database is available, and the instrument calibration is also very accurate and stable. The first MLS experiment in space, launched on the (NASA) Upper Atmosphere Research Satellite (UARS) in September 1991, was designed primarily to measure stratospheric profiles of ClO, O3, H2O, and atmospheric pressure as a vertical reference. Global measurement of ClO, the predominant radical in chlorine destruction of ozone, was an especially important objective of UARS MLS. All objectives of UARS MLS have been accomplished and additional geophysical products beyond those for which the experiment was designed have been obtained, including measurement of upper-tropospheric water vapor, which is important for climate change studies. A follow-on MLS experiment is being developed for NASA's Earth Observing System (EOS) and is scheduled to be launched on the EOS CHEMISTRY platform in late 2002. EOS MLS is designed for many stratospheric measurements, including HOx radicals, which could not be measured by UARS because adequate technology was not available, and better and more extensive upper-tropospheric and lower-stratospheric measurements.

  11. Silicon Isotope Fractionation During Acid Water-Igneous Rock Interaction

    NASA Astrophysics Data System (ADS)

    van den Boorn, S. H.; van Bergen, M. J.; Vroon, P. Z.

    2007-12-01

    Silica enrichment by metasomatic/hydrothermal alteration is a widespread phenomenon in crustal environments where acid fluids interact with silicate rocks. High-sulfidation epithermal ore deposits and acid-leached residues at hot-spring settings are among the best known examples. Acid alteration acting on basalts has also been invoked to explain the relatively high silica contents of the surface of Mars. We have analyzed basaltic-andesitic lavas from the Kawah Ijen volcanic complex (East Java, Indonesia) that were altered by interaction with highly acid (pH~1) sulfate-chloride water of its crater lake and seepage stream. Quantitative removal of major elements during this interaction has led to relative increase in SiO2 contents. Our silicon isotope data, obtained by HR-MC-ICPMS and reported relative to the NIST RM8546 (=NBS28) standard, show a systematic increase in &δ&&30Si from -0.2‰ (±0.3, 2sd) for unaltered andesites and basalts to +1.5‰ (±0.3, 2sd) for the most altered/silicified rocks. These results demonstrate that silicification induced by pervasive acid alteration is accompanied by significant Si isotope fractionation, so that alterered products become isotopically heavier than the precursor rocks. Despite the observed enrichment in SiO2, the rocks have experienced an overall net loss of silicon upon alteration, if Nb is considered as perfectly immobile. The observed &δ&&30Si values of the alteration products appeared to correlate well with the inferred amounts of silicon loss. These findings would suggest that &28Si is preferentially leached during water-rock interaction, implying that dissolved silica in the ambient lake and stream water is isotopically light. However, layered opaline lake sediments, that are believed to represent precipitates from the silica-saturated water show a conspicuous &30Si-enrichment (+1.2 ± 0.2‰). Because anorganic precipitation is known to discriminate against the heavy isotope (e.g. Basile- Doelsch et al., 2006

  12. Biosignatures in Fe- and As-rich acidic water

    NASA Astrophysics Data System (ADS)

    Casiot, C.; Bruneel, O.; Donard, O.; Morin, G.; Leblanc, M.; Personné, C.; Elbaz-Poulichet, F.

    2003-04-01

    The acid waters (pH 2.5-3.5) originating from the Carnoulès mine tailings contain elevated dissolved concentrations of arsenite (As(III)) (50-350 mg.l-1) and ferrous iron (Fe(II)) (˜2000 mg.l-1). In such extreme conditions, a number of microorganisms mainly bacteria can grow and influence water chemistry. In the acidic creek of Carnoulès, twenty to sixty percent of the arsenite initially present in water is removed from the aqueous phase within the first 30 m of the creek, as a result of its precipitation with iron. The precipitates contain 20% As around bacteria-made structures. Isotopic measurements revealed an important isotopic fractionation of iron in the stromatolites, which are enriched in 54Fe compared to the primary ore material. This enrichment may be related to the biologically-mediated oxidation of Fe(II) and subsequent immobilisation of Fe(III) by the bacteria of the Carnoulès creek. XANES analysis of sediments and stromatolite samples showed the formation of As(III)-rich compounds, tooeleite, a rare ferric arsenite sulfate oxy-hydroxide mineral and amorphous mixed As(III)/As(V)-Fe(III) oxyhydroxide compounds. These As(III)-rich compounds are dominant during the wet season; ex-situ experiments showed that the formation of these compounds may be related to the activity of bacterial strains of Acidithiobacillus ferrooxidans that oxidize Fe(II) but not As(III). In contrast, amorphous As(V)-Fe(III) oxy-hydroxides dominate in the sediments during the dry season; they originate from both biotic and abiotic oxidation of As(III). Different strains of As-oxidizing bacteria were isolated from the Carnoulès creek water and identified as strains of the genus Thiomonas.

  13. Keto-Enol Tautomerizations Catalyzed by Water and Carboxylic Acids

    NASA Astrophysics Data System (ADS)

    da Silva, G.

    2009-12-01

    The ability of weakly-bound complexes to influence the kinetics of gas phase reactions, particularly in atmospheric chemistry, has long been speculated. This study uses quantum chemistry and statistical reaction rate theory to identify that bound water molecules can significantly reduce barriers to intramolecular hydrogen shift reactions, via a double-hydrogen-shift mechanism. The bound water molecule directly participates in the hydrogen shift reaction, exchanging a H atom with its counterpart. For the vinyl alcohol to acetaldehyde keto-enol tautomerization this mechanism cuts the reaction barrier approximately in half, reducing it by over 30 kcal mol-1. In contrast, while a non-participatory ‘bystander’ water molecule also reduces the hydrogen shift barrier, it is only by around 3 kcal/mol. When a carboxylic acid replaces water in the double-hydrogen-shift mechanism the barrier to keto-enol tautomerization is decimated, reduced to less than 6 kcal/mol (around 15 kcal/mol in the reverse direction). This results from reduced strain in the hydrogen shift transition state, and achieves enol lifetimes in the troposphere that become short on relevant timescales. Rapid enol to ketone isomerizations are currently required to explain the oxidation products of isoprene. The wider significance of rapid hydrogen shift reactions in atmospherically relevant molecules and radicals is also explored.

  14. Superheated water extraction of glycyrrhizic acid from licorice root.

    PubMed

    Shabkhiz, Mohammad A; Eikani, Mohammad H; Bashiri Sadr, Zeinolabedin; Golmohammad, Fereshteh

    2016-11-01

    Superheated water extraction (SWE) has become an interesting green extraction method for different classes of compounds. In this study, SWE was used to extract glycyrrhizic acid (GA) from licorice root. Response surface methodology (RSM) was applied to evaluate and optimize the extraction conditions. The influence of operating conditions such as water temperature (100, 120 and 140°C) and solvent flow rates (1, 3 and 5mL/min) were investigated at 0.5mm mean particle size and 20bar pressure. Separation and identification of the glycyrrhizic acid, as the main component, was carried out by the RP-HPLC method. The best operating conditions for the SWE of licorice were determined to be 100°C temperature,15mL/min flow rate and 120min extraction time. The results showed that the amount of the obtained GA was relatively higher using SWE (54.760mg/g) than the Soxhlet method (28.760mg/g) and ultrasonic extraction (18.240mg/g). PMID:27211663

  15. Bridging EO Research, Operations and Collaborative Learning

    NASA Astrophysics Data System (ADS)

    Scarth, Peter

    2016-04-01

    Building flexible and responsive processing and delivery systems is key to getting EO information used by researchers, policy agents and the public. There are typically three distinct processes we tackle to get product uptake: undertake research, operationalise the validated research, and deliver information and garner feedback in an appropriate way. In many cases however, the gaps between these process elements are large and lead to poor outcomes. Good research may be "lost" and not adopted, there may be resistance to uptake by government or NGOs of significantly better operational products based on EO data, and lack of accessibility means that there is no use of interactive science outputs to improve cross disciplinary science or to start a dialog with citizens. So one of the the most important tasks, if we wish to have broad uptake of EO information and accelerate further research, is to link these processes together in a formal but flexible way. One of the ways to operationalize research output is by building a platform that can take research code and scale it across much larger areas. In remote sensing, this is typically a system that has access to current and historical corrected imagery with a processing pipeline built over the top. To reduce the demand on high level scientific programmers and allowing cross disciplinary researchers to hack and play and refine, this pipeline needs to be easy to use, collaborative and link to existing tools to encourage code experimentation and reuse. It is also critical to have efficient, tight integration with information delivery and extension components so that the science relevant to your user is available quickly and efficiently. The rapid expansion of open data licensing has helped this process, but building top-down web portals and tools without flexibility and regard for end user needs has limited the use of EO information in many areas. This research reports on the operalization of a scale independent time series

  16. Phase Structure Transition and Properties of Salt-Free Phosphoric Acid/Non-ionic Surfactants in Water.

    PubMed

    Wang, Lihuan; Zhao, Wenrong; Dong, Renhao; Hao, Jingcheng

    2016-08-23

    Precise control of phase structure transition for the synthesis of multi-dimensional soft materials is a fascinating target in amphiphilic molecule self-assembly. Here, we demonstrate a spontaneous formation of a closely packed lamellar phase consisting of uni- and multi-lamellar vesicles through the incorporation of a small amount of an extractant, di(2-ethylhexyl)phosphoric acid (DEHPA), into the highly swollen, planar lamellar phase of a non-ionic tetraethylene glycol monododecyl ether (C12EO4) surfactant in water. It is figured out that the introduction of negative membrane charges results in the electrostatic repulsion among the lamellae, which suppresses the Helfrich undulation and induces a phase structure transition from planar lamellae to closely packed vesicles. Our results provide important insight into amphiphilic molecule self-assembly, where additives and pH can satisfy the opportunities for the precise tuning of the lamellar structures, which makes a way for the development of lamellar soft materials. PMID:27490998

  17. Organic acids in cloud water and rainwater at a mountain site in acid rain areas of South China.

    PubMed

    Sun, Xiao; Wang, Yan; Li, Haiyan; Yang, Xueqiao; Sun, Lei; Wang, Xinfeng; Wang, Tao; Wang, Wenxing

    2016-05-01

    To investigate the chemical characteristics of organic acids and to identify their source, cloud water and rainwater samples were collected at Mount Lu, a mountain site located in the acid rain-affected area of south China, from August to September of 2011 and March to May of 2012. The volume-weighted mean (VWM) concentration of organic acids in cloud water was 38.42 μeq/L, ranging from 7.45 to 111.46 μeq/L, contributing to 2.50 % of acidity. In rainwater samples, organic acid concentrations varied from 12.39 to 68.97 μeq/L (VWM of 33.39 μeq/L). Organic acids contributed significant acidity to rainwater, with a value of 17.66 %. Formic acid, acetic acid, and oxalic acid were the most common organic acids in both cloud water and rainwater. Organic acids had an obviously higher concentration in summer than in spring in cloud water, whereas there was much less discrimination in rainwater between the two seasons. The contribution of organic acids to acidity was lower during summer than during spring in both cloud water (2.20 % in summer vs 2.83 % in spring) and rainwater (12.24 % in summer vs 19.89 % in spring). The formic-to-acetic acid ratio (F/A) showed that organic acids were dominated by primary emissions in 71.31 % of the cloud water samples and whole rainwater samples. Positive matrix factorization (PMF) analysis determined four factors as the sources of organic acids in cloud water, including biogenic emissions (61.8 %), anthropogenic emissions (15.28 %), marine emissions (15.07 %) and soil emissions (7.85 %). The findings from this study imply an indispensable role of organic acids in wet deposition, but organic acids may have a limited capacity to increase ecological risks in local environments. PMID:26841776

  18. Tracking the morphology of fulvic acids during water uptake

    NASA Astrophysics Data System (ADS)

    Zelenay, Veronika; Krepelova, Adela; Rudich, Yinon; Huthwelker, Thomas; Ammann, Markus

    2010-05-01

    Atmospheric humic like substances (HULIS) denote a range of oxidized, polyfunctional organic aerosol components widespread in the atmosphere, which show similar extraction behaviour on exchange columns as humic substances. Stemming from oxidation of primary gas phase and particulate organics, from e.g. biomass burning events, the HULIS constitute to a major fraction of the water soluble organic aerosol components in the atmosphere. Highly oxidized organic compounds play an important role in atmospheric processes like cloud formation or modification. Important factors therein are their hygroscopic properties and their microstructure, which influences their optical properties. HULIS somewhat resemble humic substances from terrestrial and aquatic sources, which consist mainly of carboxylic, aromatic and phenolic moieties assembled into hydrogen and van der Waals bonded supermolecular structures. Hence, the Suwannee River fulvic acid (SRFA), a chemically well characterized fulvic acid obtained from the International Humic Substances Society, was used to obtain combined data on hygroscopic properties and microstructural evolution during water uptake. The measurements were performed using x-ray absorption spectroscopy (NEXAFS, near edge x-ray absorption fine structure) in combination with an x-ray microscope (STXM, scanning x-ray transmission microscope) with a spatial resolution of about 30 nm. The measurements were performed at the PolLux beamline (SLS, Paul Scherrer Institut). The NEXAFS spectroscopy provides the possibility to map important chemical functional groups of carbon (as the one mentioned above) and oxygen atoms, and also to quantify the amount of carbon and oxygen atoms. To follow the submicron structure during water uptake a new device - a microreactor - was developed for the STXM. Using this reactor, the samples could be kept in a microenvironment with controlled temperature and humidity from 0 to 95 %. The samples were deposited either as droplets with

  19. Microbial Dissimilatory Sulfur Cycle in Acid Mine Water

    PubMed Central

    Tuttle, Jon H.; Dugan, Patrick R.; Macmillan, Carol B.; Randles, Chester I.

    1969-01-01

    Ferric, sulfate, and hydrogen ions are produced from pyritic minerals associated with coal as a result of autotrophic bacterial metabolism. Water carrying these ions accumulated behind a porous dam composed of wood dust originating at a log-cutting mill. As water seeped through the porous dam, it was enriched in organic nutrients which then supported growth and metabolism of heterotrophic bacteria in the water downstream from the dam. The heterotrophic microflora within and below the sawdust dam included dissimilatory sulfate-reducing anaerobic bacteria which reduce sulfate to sulfide. The sulfide produced caused the chemical reduction of ferric to ferrous ion, and black FeS precipitate was deposited on the pond bottom. A net increase in the pH of the lower pond water was observed when compared to the upper pond water. Microbial activity in the wood dust was demonstrated, and a sequence of cellulose degradation processes was inferred on the basis of sugar accumulation in mixed cultures in the laboratory, ultimately yielding fermentation products which serve as nutrients for sulfate-reducing bacteria. Some of the microorganisms were isolated and characterized. The biochemical and growth characteristics of pure culture isolates were generally consistent with observed reactions in the acidic environment, with the exception of sulfate-reducing bacteria. Mixed cultures which contained sulfate-reducing bacteria reduced sulfate at pH 3.0 in the laboratory with sawdust as the only nutrient. Pure cultures of sulfate-reducing bacteria isolated from the mixed cultures did not reduce sulfate below pH 5.5. PMID:5773013

  20. Arachidonic Acid and Eicosapentaenoic Acid Metabolism in Juvenile Atlantic Salmon as Affected by Water Temperature

    PubMed Central

    Norambuena, Fernando; Morais, Sofia; Emery, James A.; Turchini, Giovanni M.

    2015-01-01

    Salmons raised in aquaculture farms around the world are increasingly subjected to sub-optimal environmental conditions, such as high water temperatures during summer seasons. Aerobic scope increases and lipid metabolism changes are known plasticity responses of fish for a better acclimation to high water temperature. The present study aimed at investigating the effect of high water temperature on the regulation of fatty acid metabolism in juvenile Atlantic salmon fed different dietary ARA/EPA ratios (arachidonic acid, 20:4n-6/ eicosapentaenoic acid, 20:5n-3), with particular focus on apparent in vivo enzyme activities and gene expression of lipid metabolism pathways. Three experimental diets were formulated to be identical, except for the ratio EPA/ARA, and fed to triplicate groups of Atlantic salmon (Salmo salar) kept either at 10°C or 20°C. Results showed that fatty acid metabolic utilisation, and likely also their dietary requirements for optimal performance, can be affected by changes in their relative levels and by environmental temperature in Atlantic salmon. Thus, the increase in temperature, independently from dietary treatment, had a significant effect on the β-oxidation of a fatty acid including EPA, as observed by the apparent in vivo enzyme activity and mRNA expression of pparα -transcription factor in lipid metabolism, including β-oxidation genes- and cpt1 -key enzyme responsible for the movement of LC-PUFA from the cytosol into the mitochondria for β-oxidation-, were both increased at the higher water temperature. An interesting interaction was observed in the transcription and in vivo enzyme activity of Δ5fad–time-limiting enzyme in the biosynthesis pathway of EPA and ARA. Such, at lower temperature, the highest mRNA expression and enzyme activity was recorded in fish with limited supply of dietary EPA, whereas at higher temperature these were recorded in fish with limited ARA supply. In consideration that fish at higher water temperature

  1. Visualization, Analysis and Subsetting Tools for EOS Aura Data Products in HDF-EOS5

    NASA Technical Reports Server (NTRS)

    Johnson, J.; Ahmad, S.; Gopalan, A.; Smith, P.; Leptoukh, G.; Kempler, S.

    2004-01-01

    Aura data products are among the first to use the new version 5 of the Hierarchical Data Format for the Earth Observing System, or HDF-EOS5. This presentation discusses the common HDF-EOS5 file layout that is adopted for most of the EOS Aura standard data products. Details of the various tools that can be used to access, visualize and subset these data will also be provided. Aura, the NASA Earth Observing System's atmospheric chemistry mission, was successfully launched July 15, 2004. The Aura spacecraft includes four instruments: the High Resolution Dynamics Limb Sounder (HIRDLS), the Microwave Limb Sounder (MLS), the Ozone Monitoring Instrument (OMI), and the Tropospheric Emission Spectrometer (TES). Data from the HIRDLS, MLS and OMI will be archived at the NASA Goddard Earth Sciences (GES) Distributed Active Archive Center (DAAC), while TES data will be archived at the NASA Langley Research Center DAAC. For more information see http://daac.gsfc.nasa.gov/.

  2. Water ICE: Ion Exclusion Chromatography of Very Weak Acids with a Pure Water Eluent.

    PubMed

    Liao, Hongzhu; Shelor, C Phillip; Dasgupta, Purnendu K

    2016-05-01

    Separation of ions or ionizable compounds with pure water as eluent and detecting them in a simple fashion has been an elusive goal. It has been known for some time that carbonic acid can be separated from strong acids by ion chromatography in the exclusion mode (ICE) using only water as the eluent. The practice of water ICE was shown feasible for very weak acids like silicate and borate with a dedicated element specific detector like an inductively coupled plasma mass spectrometer (ICPMS), but this is rarely practical in most laboratories. Direct conductometric detection is possible for H2CO3 but because of its weak nature, not especially sensitive; complex multistep ion exchange methods do not markedly improve this LOD. It will clearly be impractical in acids that are weaker still. By using a permeative amine introduction device (PAID, Anal. Chem. 2016 , 88 , 2198 - 2204 ) as a conductometric developing agent, we demonstrate that a variety of weak acids (silicate, borate, arsenite, cyanide, carbonate, and sulfide) cannot only be separated on an ion exclusion column, they can be sensitively detected (LODs 0.2-0.4 μM). We observe that the elution order is essentially the same as that on a nonfunctionalized poly(styrene-divinylbenzene) column using 1-10% acetonitrile as eluent and follows the reverse order of the polar surface area (PSA) of the analyte molecules. PSA values have been widely used to predict biological transport of pharmaceuticals across a membrane but never to predict chromatographic behavior. We demonstrate the application of the technique by measuring the silicate and borate depth profiles in the Pacific Ocean; the silicate results show an excellent match with results from a reference laboratory. PMID:27075932

  3. Point Response Characteristics for the CERES/EOS-PM, FM3 & FM4 instruments.

    NASA Technical Reports Server (NTRS)

    Paden, Jack; Smith, G. Louis; Lee, Robert B., III; Pandey, Dhirendra K.; Priestley, Kory J.; Thomas, Susan; Wilson, Robert S.

    1999-01-01

    This paper describes the point source functions (PSF s) of the Clouds and the Earth s Radiant Energy System (CERES,) Earth Observing System (EOS,) afternoon platform (PM,) Flight Model 3 (FM3,) and Flight Model 4 (FM4) scanning instruments. The PSF (also known as the Point Response Function, or PRF) is vital to the accurate geo-location of the remotely sensed radiance measurements acquired by the instrument. This paper compares the characteristics of the FM3 and FM4 instruments with the earlier Proto Flight Model (PFM) on the Tropical Rainfall Measuring Mission (TRMM) platform, and the FM1 and FM2 Models on the EOS morning orbiting (AM) platform, which has recently been renamed "Terra". All of the PSF s were found to be quite comparable, and the previously noted "spreading" characteristic of the window (water vapor) channel PSF is analyzed Keywords: PSF, PRF, CERES, TRMM, EOS, Earth Radiation Budget

  4. OCCURRENCE OF IODO-ACID AND IODO-THM DISINFECTION BY-PRODUCTS IN DRINKING WATER

    EPA Science Inventory

    As part of a recent Nationwide Disinfection By-product (DBP) Occurrence Study, iodo-acids were identified for the first time as DBPs in drinking water disinfected with chloramines. The iodo-acids identified included iodoacetic acid, bromoiodoacetic acid, (E)-3-bromo-3-iodo- prope...

  5. OCCURRENCE AND TOXICITY OF IODO-ACID DISINFECTION BY-PRODUCTS IN CHLORAMINATED DRINKING WATER

    EPA Science Inventory

    As part of a recent Nationwide Disinfection By-Product (DBP) Occurrence Study, iodo-acids were identified for the first time as DBPs in drinking water disinfected with chloramines. The iodo-acids identified included iodoacetic acid (IAA), bromoiodoacetic acid, (E)-3-bromo-3-iodo...

  6. OCCURRENCE AND TOXICITY OF IODO-ACID AND IODO-THM DBPS IN CHLORAMINATED DRINKING WATER

    EPA Science Inventory

    As part of a recent Nationwide Disinfection By-Product (DBP) Occurrence Study, iodo-acids were identified for the first time as DBPs in drinking water disinfected with chloramines. The iodo-acids identified included iodoacetic acid, bromoiodoacetic acid, (E)-3-bromo-3-iodo-prope...

  7. Bigplate: an oblique angle explosive EOS test

    SciTech Connect

    Anderson, S; Avara, R; Fried, L; Janzen, J; McGuire, E; Souers, P C; Wu, B

    1998-04-16

    Bigplate is an advanced explosive equation of state (EOS) test. It consists of a point detonator driving a large disc (100 mm radius) of explosive, which pushes a 0.5 mm thick copper or tantalum plate. The plate is observed by a five-beam Fabry-Perot interferometer, which has beams at 0, 10, 20,40 and 80 mm on the plate. A short Fabry gives the jump-off to high accuracy; a long Fabry runs out to I0-15 microsec. A detailed error analysis is given, with the final velocity measurements considered good to ±0.066 mm/microsec. Jump-offs are measured to 0.01-0.02 microsec. Spall is seen in all shots, which creates a time delay on both the first and second velocity plateaus. A 0.1 microsec delay in jump-off of unknown origin is also seen at 80 mm. In order of decreasing explosive ideality, the explosives tired have been LX-14, LX-04 and LX-17. To partially negate the time delays, the data and code runs are overlaid at each radial position between the first and second plateaus. Traditional JWL's model LX-14 and LX-04 within accuracy, but not so for LX-17. The spall may be partly modeled using the pmin model but high resolution zoning is required. At longer times, spall does not appear to affect the explosive energetics. Because it includes diagonal zone crossing, Bigplate occupies a location between simple plate and cylinder tests and truly complex geometries. Hence, an EOS that fails Bigplate is not likely to move on to more complex issues. Bigplate is an excellent test bed for radically new EOS's, and the initial LX-17 runs done with Equilibrium and KINETIC CHEETAH are promising.

  8. Shear rigidity of spread stearic acid monolayers on water

    SciTech Connect

    Abraham, B.M.; Ketterson, J.B.; Miyano, K.; Kueny, A.

    1981-01-01

    The effect of Al/sup 3 +/, Fe/sup 3 +/, Ca/sup 2 +/, and Mg/sup 2 +/ ions and of pH on the two-dimensional shear modulus of stearic acid spread on a water substrate was determined. A large shear modulus was displayed by the films when the subphase contained Al/sup 3 +/ and Fe/sup 3 +/ ions at the self buffered pH. With Fe/sup 3 +/ dissolved in the subphase, the film displayed a viscous relaxation when strained but no residual stress was observed. No effect was observed with the Ca/sup 2 +/ or Mg/sup 2 +/. Reducing the pH value in the subphase with the trivalent ions caused the shear modulus to disappear. The observations are interpreted in terms of hydrogen bonding.

  9. [Study advance on haloacetic acids in drinking water].

    PubMed

    Ye, Bi-Xiong; Wang, Wu-Yi; Yang, Lin-Sheng; Wang, Yong-Hua

    2006-05-01

    Haloacetic acids (HAAs) in drinking water have attracted more and more attention of researchers due to their higher potential combination of chlorine, their carcinogenic and mutagenic effects and higher carcinogenic. The formation mechanism, analytical methods, the effects of many factors on HAAs formation such as precursor types, chlorine doses, pH, temperature, bromide, reaction time and seasonal change, toxicological character and the minimizing technology of HAAs in resent studies about HAAs are discussed in details in this paper. Further researches are still needed to clarify the formation mechanism of HAAs and find a feasible minimizing technology. New concerns including toxicological characters that correlate with human and other HAAs exposure routes besides oral ingestion (i.e., inhalation and dermal adsorption) should be put forward. PMID:16921773

  10. Engineering crassulacean acid metabolism to improve water-use efficiency

    PubMed Central

    Borland, Anne M.; Hartwell, James; Weston, David J.; Schlauch, Karen A.; Tschaplinski, Timothy J.; Tuskan, Gerald A.; Yang, Xiaohan; Cushman, John C.

    2014-01-01

    Climatic extremes threaten agricultural sustainability worldwide. One approach to increase plant water-use efficiency is to introduce crassulacean acid metabolism (CAM) into C3 crops. Such a task requires comprehensive systems-level understanding of the enzymatic and regulatory pathways underpinning this temporal CO2 pump. Here, we review the progress that has been made in achieving this goal. Given that CAM arose through multiple independent evolutionary origins, comparative transcriptomics and genomics of taxonomically diverse CAM species are being used to define the genetic ‘parts list’ required to operate the core CAM functional modules of nocturnal carboxylation, daytime decarboxylation, and inverse stomatal regulation. Engineered CAM offers the potential to sustain plant productivity for food, feed, fiber, and biofuel production in hotter and drier climates. PMID:24559590

  11. Engineering crassulacean acid metabolism to improve water-use efficiency.

    PubMed

    Borland, Anne M; Hartwell, James; Weston, David J; Schlauch, Karen A; Tschaplinski, Timothy J; Tuskan, Gerald A; Yang, Xiaohan; Cushman, John C

    2014-05-01

    Climatic extremes threaten agricultural sustainability worldwide. One approach to increase plant water-use efficiency (WUE) is to introduce crassulacean acid metabolism (CAM) into C3 crops. Such a task requires comprehensive systems-level understanding of the enzymatic and regulatory pathways underpinning this temporal CO2 pump. Here we review the progress that has been made in achieving this goal. Given that CAM arose through multiple independent evolutionary origins, comparative transcriptomics and genomics of taxonomically diverse CAM species are being used to define the genetic 'parts list' required to operate the core CAM functional modules of nocturnal carboxylation, diurnal decarboxylation, and inverse stomatal regulation. Engineered CAM offers the potential to sustain plant productivity for food, feed, fiber, and biofuel production in hotter and drier climates. PMID:24559590

  12. EOS image data processing system definition study

    NASA Technical Reports Server (NTRS)

    Gilbert, J.; Honikman, T.; Mcmahon, E.; Miller, E.; Pietrzak, L.; Yorsz, W.

    1973-01-01

    The Image Processing System (IPS) requirements and configuration are defined for NASA-sponsored advanced technology Earth Observatory System (EOS). The scope included investigation and definition of IPS operational, functional, and product requirements considering overall system constraints and interfaces (sensor, etc.) The scope also included investigation of the technical feasibility and definition of a point design reflecting system requirements. The design phase required a survey of present and projected technology related to general and special-purpose processors, high-density digital tape recorders, and image recorders.

  13. Share Your Opinion With Other Eos Readers

    NASA Astrophysics Data System (ADS)

    Narasimhan, T. N.

    2006-11-01

    Earlier this year, Robert Kitchen (Eos, 87(24), 235, 2006) drew attention to declining interest in Earth science education in public schools. The reason for a lack of interest in teaching Earth sciences in public schools may involve more than just the attitudes of parents who may wish for their children a better preparation for advanced placement courses later on. Part of the problem may lie with our present mind-set that technology can solve all the world's problems, from poverty, to better health, and to prosperity.

  14. Study on the kinetics and transformation products of salicylic acid in water via ozonation.

    PubMed

    Hu, Ruikang; Zhang, Lifeng; Hu, Jiangyong

    2016-06-01

    As salicylic acid is one of widely used pharmaceuticals, its residue has been found in various environmental water systems e.g. wastewater, surface water, treated water and drinking water. It has been reported that salicylic acid can be efficiently removed by advanced oxidation processes, but there are few studies on its transformation products and ozonation mechanisms during ozonation process. The objective of this study is to characterize the transformation products, investigate the degradation mechanisms at different pH, and propose the ozonation pathways of salicylic acid. The results showed that the rate of degradation was about 10 times higher at acidic condition than that at alkaline condition in the first 1 min when 1 mg L(-1) of ozone solution was added into 1 mg L(-1) of salicylic acid solution. It was proposed that ozone direct oxidation mechanism dominates at acidic condition, while indirect OH radical mechanism dominates at alkaline condition. A two stages pseudo-first order reaction was proposed at different pH conditions. Various hydroxylation products, carbonyl compounds and carboxylic acids, such as 2,5-dihydroxylbenzoic acid, 2,3-dihydroxylbenzoic acid, catechol, formaldehyde, glyoxal, acetaldehyde, maleic acid, acetic acid and oxalic acid etc. were identified as ozonation transformation products. In addition, acrylic acid was identified, for the first time, as ozonation transformation products through high resolution liquid chromatography-time of flight mass spectrometer. The information demonstrated in this study will help us to better understand the possible effects of ozonation products on the water quality. The degradation pathways of salicylic acid by ozonation in water sample were proposed. As both O3 and OH radical were important in the reactions, the degradation pathways of salicylic acid by ozonation in water sample were proposed at acidic and basic conditions. To our knowledge, there was no integrated study reported on the ozonation of

  15. Alicyclobacillus fodiniaquatilis sp. nov., isolated from acid mine water.

    PubMed

    Zhang, Bo; Wu, Yu-Fan; Song, Jin-Long; Huang, Zhong-Sheng; Wang, Bao-Jun; Liu, Shuang-Jiang; Jiang, Cheng-Ying

    2015-12-01

    Two novel, Gram-stain-variable, moderately thermophilic, acidophilic, rod-shaped, endospore-forming bacteria, G45-16T and G45-17, were isolated from acid mine water of Zijin copper mine in Fujian Province, China. Phylogenetic analysis of 16S rRNA gene sequences showed that they were closely related to Alicyclobacillus acidoterrestris ATCC 49025T with sequence similarities of 96.8 %. Cells grew aerobically at 20-45 °C (optimum, 40 °C), at pH 2.5-5.5(optimum, pH 3.5) and in the presence of 0-4.0 % (w/v) NaCl. Strains contained MK-7 as the major menaquinone and the major cellular fatty acids were ω-cyclohexane C19 : 0 and ω-cyclohexane C17 : 0. The DNA G+C content was 51.3 and 49.8 mol% (Tm) for G45-16T and G45-17, respectively. On the basis of phenotypic, chemotaxonomic and phylogenetic comparisons with their relatives and DNA-DNA relatedness values, it is concluded that strains G45-16T and G45-17 represent a novel species within the genus Alicyclobacillus, for which the name Alicyclobacillus fodiniaquatilis sp. nov. is proposed; the type strain is G45-16T(=CGMCC 1.15049T=NBRC 111483T). PMID:26476812

  16. Halogenated methanesulfonic acids: A new class of organic micropollutants in the water cycle.

    PubMed

    Zahn, Daniel; Frömel, Tobias; Knepper, Thomas P

    2016-09-15

    Mobile and persistent organic micropollutants may impact raw and drinking waters and are thus of concern for human health. To identify such possible substances of concern nineteen water samples from five European countries (France, Switzerland, The Netherlands, Spain and Germany) and different compartments of the water cycle (urban effluent, surface water, ground water and drinking water) were enriched with mixed-mode solid phase extraction. Hydrophilic interaction liquid chromatography - high resolution mass spectrometry non-target screening of these samples led to the detection and structural elucidation of seven novel organic micropollutants. One structure could already be confirmed by a reference standard (trifluoromethanesulfonic acid) and six were tentatively identified based on experimental evidence (chloromethanesulfonic acid, dichloromethanesulfonic acid, trichloromethanesulfonic acid, bromomethanesulfonic acid, dibromomethanesulfonic acid and bromochloromethanesulfonic acid). Approximated concentrations for these substances show that trifluoromethanesulfonic acid, a chemical registered under the European Union regulation REACH with a production volume of more than 100 t/a, is able to spread along the water cycle and may be present in concentrations up to the μg/L range. Chlorinated and brominated methanesulfonic acids were predominantly detected together which indicates a common source and first experimental evidence points towards water disinfection as a potential origin. Halogenated methanesulfonic acids were detected in drinking waters and thus may be new substances of concern. PMID:27267477

  17. The coagulation characteristics of humic acid by using acid-soluble chitosan, water-soluble chitosan, and chitosan coagulant mixtures.

    PubMed

    Chen, Chih-Yu; Wu, Chung-Yu; Chung, Ying-Chien

    2015-01-01

    Chitosan is a potential substitute for traditional aluminium salts in water treatment systems. This study compared the characteristics of humic acid (HA) removal by using acid-soluble chitosan, water-soluble chitosan, and coagulant mixtures of chitosan with aluminium sulphate (alum) or polyaluminium chloride (PACl). In addition, we evaluated their respective coagulation efficiencies at various coagulant concentrations, pH values, turbidities, and hardness levels. Furthermore, we determined the size and settling velocity of flocs formed by these coagulants to identify the major factors affecting HA coagulation. The coagulation efficiency of acid- and water-soluble chitosan for 15 mg/l of HA was 74.4% and 87.5%, respectively. The optimal coagulation range of water-soluble chitosan (9-20 mg/l) was broader than that of acid-soluble chitosan (4-8 mg/l). Notably, acid-soluble chitosan/PACl and water-soluble chitosan/alum coagulant mixtures exhibited a higher coagulation efficiency for HA than for PACl or alum alone. Furthermore, these coagulant mixtures yielded an acceptable floc settling velocity and savings in both installation and operational expenses. Based on these results, we confidently assert that coagulant mixtures with a 1:1 mass ratio of acid-soluble chitosan/PACl and water-soluble chitosan/alum provide a substantially more cost-effective alternative to using chitosan alone for removing HA from water. PMID:25362971

  18. Amino Acid and Protein Metabolism in Bermuda Grass During Water Stress 12

    PubMed Central

    Barnett, N. M.; Naylor, A. W.

    1966-01-01

    The ability of Arizona Common and Coastal Bermuda grass [Cynodon dactylon (L.) Pers.] to synthesize amino acids and proteins during water stress was investigated. Amino acids were continually synthesized during the water stress treatments, but protein synthesis was inhibited and protein levels decreased. Water stress induced a 10- to 100-fold accumulation of free proline in shoots and a 2- to 6-fold accumulation of free asparagine, both of which are characteristic responses of water-stressed plants. Valine levels increased, and glutamic acid and alanine levels decreased. 14C labeling experiments showed that free proline turns over more slowly than any other free amino acid during water stress. This proline is readily synthesized and accumulated from glutamic acid. It is suggested that during water stress free proline functions as a storage compound. No significant differences were found in the amino acid and protein metabolism of the 2 varieties of Bermuda grass. PMID:16656387

  19. Water-enhanced solubility of carboxylic acids in organic solvents and its applications to extraction processes

    SciTech Connect

    Starr, J.N.; King, C.J.

    1991-11-01

    The solubilities of carboxylic acids in certain organic solvents increase remarkably with an increasing amount of water in the organic phase. This phenomenon leads to a novel extract regeneration process in which the co-extracted water is selectively removed from an extract, and the carboxylic acid precipitates. This approach is potentially advantageous compared to other regeneration processes because it removes a minor component of the extract in order to achieve a large recovery of acid from the extract. Carboxylic acids of interest include adipic acid, fumaric acid, and succinic acid because of their low to moderate solubilities in organic solvents. Solvents were screened for an increase in acid solubility with increased water concentration in the organic phase. Most Lewis-base solvents were found to exhibit this increased solubility phenomena. Solvents that have a carbonyl functional group showed a very large increase in acid solubility. 71 refs., 52 figs., 38 tabs.

  20. Morphology of nitric acid and water ice films

    NASA Technical Reports Server (NTRS)

    Keyser, Leon F.; Leu, Ming-Taun

    1993-01-01

    Ice films have been used to simulate stratospheric cloud surfaces in order to obtain laboratory data on solubilities and heterogeneous reaction rates. In the present study, environmental scanning electron microscopy (ESEM) is used to study thin films of both water ice and nitric acid ice near the composition of the trihydrate. The ices are formed by vapor deposition onto aluminum or borosilicate-glass substrates cooled to about 200 K. Micrographs are recorded during the deposition process and during subsequent annealing at higher temperatures. The results show that the ice films are composed of loosely consolidated granules, which range from about 1 to 20 microns in size at temperatures between 197 and 235 K. Cubic water ice is sometimes observed at 200 K, which converts to the hexagonal form at slightly higher temperatures. The loose packing of the granules confirms the high porosities of these films obtained from separate bulk porosity measurements. Average surface areas calculated from the observed granule sizes range from about 0.2 to 1 sq m/g and agree with surface areas obtained by gas-adsorption (BET) analysis of annealed ice films. For unannealed films, the BET areas are about an order of magnitude higher than the ESEM results, implying that the unannealed ices contain microporosity which is lost during the annealing process.

  1. Converting EOS Data from HDF-EOS to netCDF

    NASA Technical Reports Server (NTRS)

    Ullman, Richard; Bame. Bob; Yang, Jingli

    2008-01-01

    A C-language computer program accepts, as input, a set of scientific data and metadata from an Earth Observing System (EOS) satellite and converts the set from (1) the format in which it was created and delivered to (2) another format for processing and exchange of data on Earth.

  2. New RADIOM algorithm using inverse EOS

    NASA Astrophysics Data System (ADS)

    Busquet, Michel; Sokolov, Igor; Klapisch, Marcel

    2012-10-01

    The RADIOM model, [1-2], allows one to implement non-LTE atomic physics with a very low extra CPU cost. Although originally heuristic, RADIOM has been physically justified [3] and some accounting for auto-ionization has been included [2]. RADIOM defines an ionization temperature Tz derived from electronic density and actual electronic temperature Te. LTE databases are then queried for properties at Tz and NLTE values are derived from them. Some hydro-codes (like FAST at NRL, Ramis' MULTI, or the CRASH code at U.Mich) use inverse EOS starting from the total internal energy Etot and returning the temperature. In the NLTE case, inverse EOS requires to solve implicit relations between Te, Tz, and Etot. We shall describe these relations and an efficient solver successively implemented in some of our codes. [4pt] [1] M. Busquet, Radiation dependent ionization model for laser-created plasmas, Ph. Fluids B 5, 4191 (1993).[0pt] [2] M. Busquet, D. Colombant, M. Klapisch, D. Fyfe, J. Gardner. Improvements to the RADIOM non-LTE model, HEDP 5, 270 (2009).[0pt] [3] M.Busquet, Onset of pseudo-thermal equilibrium within configurations and super-configurations, JQSRT 99, 131 (2006)

  3. Designing an EOS chip with SDP

    NASA Astrophysics Data System (ADS)

    Wang, Peng; Jin, Depeng; Zeng, Lieguang

    2004-05-01

    As is known, Ethernet has gained great popularity in LAN (local area network). Meanwhile, SDH/SONET is the backbone of today"s communication networks. Then, how to exchange information between Ethernets located in different regions over SDH/SONET is becoming a hotspot. This paper provides a single chip solution of Ethernet transmission over SDH/SONET (EOS), which supports up to thirty-two 10/100Mbit/s Ethernet ports or four 1000Mbit/s Ethernet ports over 2.5Gbit/s SDH/SONET. On designing of this EOS chip, we also present a packet loss policy called SDP (Selective Dropping Policy) to perform flow control, which can actively select packets to drop as the packet buffer overflows. Up to now, we have developed two policies of SDP: LPF (Longest Packet First) and LSPF (Least Significant Packet First). Simulation results show that with LPF, the average packet loss rate (PLR) of the overall system can be cut down significantly without increasing the buffer storage, and with LSPF, the packets of the least important group will be discarded discriminately in the case of overflow to lower average PLRs of other groups. Moreover, SDP can cooperate with Ethernet's Backpressure Mechanism fairly well and be implemented easily on chip.

  4. Realtime Decision Making on EO-1 Using Onboard Science Analysis

    NASA Technical Reports Server (NTRS)

    Sherwood, Robert; Chien, Steve; Davies, Ashley; Mandl, Dan; Frye, Stu

    2004-01-01

    Recent autonomy experiments conducted on Earth Observing 1 (EO-1) using the Autonomous Sciencecraft Experiment (ASE) flight software has been used to classify key features in hyperspectral images captured by EO-1. Furthermore, analysis is performed by this software onboard EO-1 and then used to modify the operational plan without interaction from the ground. This paper will outline the overall operations concept and provide some details and examples of the onboard science processing, science analysis, and replanning.

  5. Temperature dependence of hydrogen-bond dynamics in acetic acid-water solutions.

    PubMed

    D'Amico, Francesco; Bencivenga, Filippo; Gessini, Alessandro; Masciovecchio, Claudio

    2010-08-19

    An inelastic UV scattering experiment has been carried out on acetic acid-water solutions as a function of temperature and concentration. The analysis of experimental data indicates the presence of a crossover temperature (T(c) approximately 325 +/- 10 K). Above T(c), the energy of hydrogen bonds responsible for water-acetic acid and acetic acid-acetic acid interactions is strongly reduced. This leads to a reduction in the average number of water molecule interacting with acetic acid, as well as to a lower number of acetic acid clusters. The latter behavior can be mainly ascribed to a temperature change in the activation energy of carboxylic groups of acetic acid. These results may be also relevant to better understand the folding mechanism in protein-water solutions. PMID:20701390

  6. Analysis of fluorotelomer alcohols, fluorotelomer acids, and short- and long-chain perfluorinated acids in water and biota.

    PubMed

    Taniyasu, Sachi; Kannan, Kurunthachalam; So, Man Ka; Gulkowska, Anna; Sinclair, Ewan; Okazawa, Tsuyoshi; Yamashita, Nobuyoshi

    2005-11-01

    Fluorotelomer alcohols and fluorotelomer acids have been proposed as a source of the perfluorinated carboxylic acids found in remote marine locations. To examine the sources and fate of perfluorinated acids in the environment, a method to determine a wide range of poly- and perfluorinated acids in environmental and biological matrices is needed. In this study, a method has been developed to measure a suite of neutral and acidic fluorochemicals including, fluorotelomer alcohols, fluorotelomer acids, and short- and long-chain perfluorinated acids, in water and biological samples. The method involves solid-phase extraction with weak anion exchange (WAX) cartridges, followed by sequential elution with sodium acetate buffer, methanol, and 0.1% NH4OH in methanol. For biological samples, prior to solid-phase extraction, tissues are digested in 0.5N potassium hydroxide/methanol, diluted in water, and passed through the WAX cartridge. Neutral compounds and telomer alcohols are separated from other poly- and perfluorinated acids. The method is robust (i.e., capable of measuring neutral and acidic compounds), and can be applied for the analysis of a range of poly- and perfluorinated acids, including telomer alcohols, telomer acids, perfluoroalkylcarboxylates, and perfluoroalkylsulfonates in water and biota. With the use of high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS), a method detection limit in the range of several tens to hundreds of parts-per-quadrillion (pg/L) in water and at a few tens to hundreds of parts-per-trillion (pg/g) levels in biological matrices can be achieved. PMID:16233874

  7. Inactivation of bacteria on surfaces by sprayed slightly acidic hypochlorous acid water: in vitro experiments.

    PubMed

    Hakim, Hakimullah; Alam, Md Shahin; Sangsriratanakul, Natthanan; Nakajima, Katsuhiro; Kitazawa, Minori; Ota, Mari; Toyofuku, Chiharu; Yamada, Masashi; Thammakarn, Chanathip; Shoham, Dany; Takehara, Kazuaki

    2016-08-01

    The capacity of slightly acidic hypochlorous acid water (SAHW), in both liquid and spray form, to inactivate bacteria was evaluated as a potential candidate for biosecurity enhancement in poultry production. SAHW (containing 50 or 100 ppm chlorine, pH 6) was able to inactivate Escherichia coli and Salmonella Infantis in liquid to below detectable levels (≤2.6 log10 CFU/ml) within 5 sec of exposure. In addition, SAHW antibacterial capacity was evaluated by spraying it using a nebulizer into a box containing these bacteria, which were present on the surfaces of glass plates and rayon sheets. SAHW was able to inactivate both bacterial species on the glass plates (dry condition) and rayon sheets within 5 min spraying and 5 min contact times, with the exception of 50 ppm SAHW on the rayon sheets. Furthermore, a corrosivity test determined that SAHW does not corrode metallic objects, even at the longest exposure times (83 days). Our findings demonstrate that SAHW is a good candidate for biosecurity enhancement in the poultry industry. Spraying it on the surfaces of objects, eggshells, egg incubators and transport cages could reduce the chances of contamination and disease transmission. These results augment previous findings demonstrating the competence of SAHW as an anti-viral disinfectant. PMID:27052464

  8. Inactivation of bacteria on surfaces by sprayed slightly acidic hypochlorous acid water: in vitro experiments

    PubMed Central

    HAKIM, Hakimullah; ALAM, Md. Shahin; SANGSRIRATANAKUL, Natthanan; NAKAJIMA, Katsuhiro; KITAZAWA, Minori; OTA, Mari; TOYOFUKU, Chiharu; YAMADA, Masashi; THAMMAKARN, Chanathip; SHOHAM, Dany; TAKEHARA, Kazuaki

    2016-01-01

    The capacity of slightly acidic hypochlorous acid water (SAHW), in both liquid and spray form, to inactivate bacteria was evaluated as a potential candidate for biosecurity enhancement in poultry production. SAHW (containing 50 or 100 ppm chlorine, pH 6) was able to inactivate Escherichia coli and Salmonella Infantis in liquid to below detectable levels (≤2.6 log10 CFU/ml) within 5 sec of exposure. In addition, SAHW antibacterial capacity was evaluated by spraying it using a nebulizer into a box containing these bacteria, which were present on the surfaces of glass plates and rayon sheets. SAHW was able to inactivate both bacterial species on the glass plates (dry condition) and rayon sheets within 5 min spraying and 5 min contact times, with the exception of 50 ppm SAHW on the rayon sheets. Furthermore, a corrosivity test determined that SAHW does not corrode metallic objects, even at the longest exposure times (83 days). Our findings demonstrate that SAHW is a good candidate for biosecurity enhancement in the poultry industry. Spraying it on the surfaces of objects, eggshells, egg incubators and transport cages could reduce the chances of contamination and disease transmission. These results augment previous findings demonstrating the competence of SAHW as an anti-viral disinfectant. PMID:27052464

  9. The ASY-EOS Experiment at GSI

    NASA Astrophysics Data System (ADS)

    Russotto, P.; Chartier, M.; Cozma, M. D.; De Filippo, E.; Le Fèvre, A.; Gannon, S.; Gašparić, I.; Kiš, M.; Kupny, S.; Leifels, Y.; Lemmon, R. C.; Li, Q.; Łukasik, J.; Marini, P.; Pawłowski, P.; Trautmann, W.; Acosta, L.; Adamczyk, M.; Al-Ajlan, A.; Al-Garawi, M.; Al-Homaidhi, S.; Amorini, F.; Auditore, L.; Aumann, T.; Ayyad, Y.; Baran, V.; Basrak, Z.; Bassini, R.; Benlliure, J.; Boiano, C.; Boisjoli, M.; Boretzky, K.; Brzychczyk, J.; Budzanowski, A.; Cardella, G.; Cammarata, P.; Chajecki, Z.; Chbihi, A.; Colonna, M.; Czech, B.; Di Toro, M.; Famiano, M.; Greco, V.; Grassi, L.; Guazzoni, C.; Guazzoni, P.; Heil, M.; Heilborn, L.; Introzzi, R.; Isobe, T.; Kezzar, K.; Krasznahorkay, A.; Kurz, N.; La Guidara, E.; Lanzalone, G.; Lasko, P.; Lombardo, I.; Lynch, W. G.; Matthews, Z.; May, L.; Minniti, T.; Mostazo, M.; Pagano, A.; Papa, M.; Pirrone, S.; Pleskac, R.; Politi, G.; Porto, F.; Reifarth, R.; Reisdorf, W.; Riccio, F.; Rizzo, F.; Rosato, E.; Rossi, D.; Santoro, S.; Simon, H.; Skwirczynska, I.; Sosin, Z.; Stuhl, L.; Trifirò, A.; Trimarchi, M.; Tsang, M. B.; Verde, G.; Veselsky, M.; Vigilante, M.; Wieloch, A.; Wigg, P.; Wolter, H. H.; Wu, P.; Yennello, S.; Zambon, P.; Zetta, L.; Zoric, M.

    2016-05-01

    The elliptic-flow ratio of neutrons with respect to protons or light complex particles in reactions of heavy ions at pre-relativistic energies has been proposed as an observable sensitive to the strength of the symmetry term of the nuclear equation of state at supra-saturation densities. In the ASY-EOS experiment at the GSI laboratory, flows of neutrons and light charged particles were measured for 197Au+197Au collisions at 400 MeV/nucleon. Flow results obtained for the Au+Au system, in comparison with predictions of the UrQMD transport model, confirm the moderately soft to linear density dependence of the symmetry energy deduced from the earlier FOPI-LAND data.

  10. EO system concepts in the littoral

    NASA Astrophysics Data System (ADS)

    Schwering, Piet B. W.; van den Broek, Sebastiaan P.; van Iersel, Miranda

    2007-04-01

    In recent years, operations executed by naval forces have taken place at many different locations. At present, operations against international terrorism and asymmetric warfare in coastal environments are of major concern. In these scenarios, the threat caused by pirates on-board of small surface targets, such as jetskis and fast inshore attack crafts, is increasing. In the littoral environment, the understanding of its complexity and the efficient use of the limited reaction time, are essential for successful operations. Present-day electro-optical sensor suites, also incorporating Infrared Search and Track systems, can be used for varying tasks as detection, classification and identification. By means of passive electro-optical systems, infrared and visible light sensors, improved situational awareness can be achieved. For long range capability, elevated sensor masts and flying platforms are ideally suited for the surveillance task and improve situational awareness. A primary issue is how to incorporate new electro-optical technology and signal processing into the new sensor concepts, to improve system performance. It is essential to derive accurate information from the high spatial-resolution imagery created by the EO sensors. As electro-optical sensors do not have all-weather capability, the performance degradation in adverse scenarios must be understood, in order to support the operational use of adaptive sensor management techniques. In this paper we discuss the approach taken at TNO in the design and assessment of system concepts for future IRST development. An overview of our maritime programme in future IRST and EO system concepts including signal processing is presented.

  11. GDAL Enhancements for Interoperability with EOS Data

    NASA Astrophysics Data System (ADS)

    Tisdale, M.; Mathews, T. J.; Tisdale, B.; Sun, M.; Yang, C. P.; Lee, H.; Habermann, T.

    2015-12-01

    Historically, Earth Observing Satellite (EOS) data products have been difficult to consume by GIS tools, weather commercial or open-source. This has resulted in a reduced acceptance of these data products by GIS and general user communities. Common problems and challenges experienced by these data users include difficulty when: Consuming data products from NASA Distributed Active Archive Centers (DAACs) that pre-date modern application software with commercial and open-source geospatial tools; Identifying an initial approach for developing a framework and plug-ins that interpret non-compliant data; Defining a methodology that is extensible across NASA Earth Observing System Data and Information System (EOSDIS), scientific communities, and GIS communities by enabling other data centers to construct their own plug-ins and adjust specific data products; and Promoting greater use of NASA Data and new analysis utilizing GIS tools. To address these challenges and to make EOS data products more accessible and interpretable by GIS applications, a collaborative approach has been taken that includes the NASA Langley Atmospheric Science Data Center (ASDC), Esri, George Mason University (GMU), and the Hierarchical Data Format (HDF) Group to create a framework and plugins to be applied to Geospatial Data Abstraction Library (GDAL). This framework and its plugins offer advantages of extensibility within NASA EOSDIS, permitting other data centers to construct their own plugins necessary to adjust their data products. In this session findings related to the framework and the development of GDAL plugins will be reviewed. Specifically, this session will offer a workshop to review documentation and training materials that have been generated for the purpose of guiding other NASA DAACs through the process of constructing plug-ins consistent with the framework as well as a review of the certification process by which the plugins can be independently verified as properly converting the

  12. Isotopic geochemistry of acid thermal waters and volcanic gases from Zaō volcano in Japan

    NASA Astrophysics Data System (ADS)

    Kiyosu, Yasuhiro; Kurahashi, Makoto

    1984-08-01

    The chemical composition and D/H, {18O }/{16O } and {34S }/{32S } ratios have been determined for the acid hot waters and volcanic gases discharging from Zaō volcano in Japan. The thermal springs in Zaō volcano issue acid sulfate-chloride type waters (Zaō) and acid sulfate type waters (Kamoshika). Gases emitted at Kamoshika fumaroles are rich in CO 2, SO 2 and N 2, exclusive of H 2O. Chloride concentrations and oxygen isotope data indicate that the Zaō thermal waters issue a fluid mixture from an acid thermal reservoir and meteoric waters from shallow aquifers. The waters in the Zaō volcanic system have slight isotopic shifts from the respective local meteoric values. The isotopic evidence indicates that most of the water in the system is meteoric in origin. Sulfates in Zaō acid sulfate-chloride waters with δ34S values of around +15‰, are enriched in 34S compared to Zaō H 2S, while the acid sulfate waters at Kamoshika contain supergene light sulfate ( δ 34S = ˜ + 4‰ ) derived from volcanic sulfur dioxide from the volcanic exhalations. The sulfur species in Zaō acid waters are lighter in δ34S than those of other volcanic areas, reflecting the difference in total pressure.

  13. The geochemical model of neutral and acidic thermal water in the Tatun Volcano Group, Taiwan

    NASA Astrophysics Data System (ADS)

    Tsai, Y.; Kuo, C.; Liu, C.

    2013-12-01

    The geochemical model can provide a quantitative method for water-rock interaction and understand the processes of neutralization of initially acidic water. The Tatun Volcano Group (TVG) is one of the Quaternary volcanoes of northern Taiwan. In the Southern Sulfur River of the TVG, it has neutral and acidic thermal water that can provide good materials for modeling the flow path of acidic and neutral thermal water. This study collects 7 thermal springs and identifies into two types, which are neutral and acidic thermal water. The host rock of neutral thermal water has fresh andesitic rock and is weak fumaroles, and the field observations of acidic thermal waters have been alternated andesitic rock and strong degassing fumaroles. The Geochemist's Workbench software (GWB) can model the processes of neutralization of initially acidic water. Furthermore, this study will collect the meteoric water, thermal springs, and country rock along the Southern Sulfur River and use the GWB software to model the processes of neutralization of initially acidic water in the Southern Sulfur River in the future.

  14. Advanced water-cooled phosphoric acid fuel cell development

    SciTech Connect

    Not Available

    1992-09-01

    This program was conducted to improve the performance and minimize the cost of existing water-cooled phosphoric acid fuel cell stacks for electric utility and on-site applications. The goals for the electric utility stack technology were a power density of at least 175 watts per square foot over a 40,000-hour useful life and a projected one-of-a-kind, full-scale manufactured cost of less than $400 per kilowatt. The program adapted the existing on-site Configuration-B cell design to electric utility operating conditions and introduced additional new design features. Task 1 consisted of the conceptual design of a full-scale electric utility cell stack that meets program objectives. The conceptual design was updated to incorporate the results of material and process developments in Tasks 2 and 3, as well as results of stack tests conducted in Task 6. Tasks 2 and 3 developed the materials and processes required to fabricate the components that meet the program objectives. The design of the small area and 10-ft{sup 2} stacks was conducted in Task 4. Fabrication and assembly of the short stacks were conducted in Task 5 and subsequent tests were conducted in Task 6. The management and reporting functions of Task 7 provided DOE/METC with program visibility through required documentation and program reviews. This report describes the cell design and development effort that was conducted to demonstrate, by subscale stack test, the technical achievements made toward the above program objectives.

  15. Pre-sedation and transport of Rhamdia quelen in water containing essential oil of Lippia alba: metabolic and physiological responses.

    PubMed

    Becker, Alexssandro G; Parodi, Thaylise V; Zeppenfeld, Carla C; Salbego, Joseânia; Cunha, Mauro A; Heldwein, Clarissa G; Loro, Vania L; Heinzmann, Berta M; Baldisserotto, Bernardo

    2016-02-01

    The effects of transporting silver catfish (Rhamdia quelen) for 6 h in plastic bags containing 0 (control), 30 or 40 µL/L of essential oil (EO) from Lippia alba leaves were investigated. Prior to transport, the fish in the two experimental groups were sedated with 200 µL/L of EO for 3 min. After transport, dissolved oxygen, carbon dioxide, alkalinity, water hardness, pH, temperature and un-ionized ammonia levels in the transport water did not differ significantly among the groups. However, total ammonia nitrogen levels and net Na(+), Cl(-) and K(+) effluxes were significantly lower in the groups transported with EO of L. alba than those in the control group. PvO2, PvCO2 and HCO3(-) were higher after transporting fish in 40 µL/L of EO of L. alba, but there were no significant differences between groups regarding blood pH or hematocrit. Cortisol levels were significantly higher in fish transported in 30 µL/L of EO of L. alba compared to those of the control group. The metabolic parameters (glycogen, lactate, total amino acid, total ammonia and total protein) showed different responses after adding EO to the transport water. In conclusion, while the EO of L. alba is recommended for fish transport in the conditions tested in the present study because it was effective in reducing waterborne total ammonia levels and net ion loss, the higher hepatic oxidative stress in this species with the same EO concentrations reported by a previous study led us to conclude that the 10-20 µL/L concentration range of EO and lack of pre-sedation before transport are more effective. PMID:26297516

  16. Supernova constraints on neutrino oscillation and EoS for proto-neutron star

    NASA Astrophysics Data System (ADS)

    Kajino, T.; Aoki, W.; Cheoun, M.-K.; Hayakawa, T.; Hidaka, J.; Hirai, Y.; Mathews, G. J.; Nakamura, K.; Shibagaki, S.; Suzuki, T.

    2014-05-01

    Core-collapse supernovae eject huge amount of flux of energetic neutrinos which affect explosive nucleosynthesis of rare isotopes like 7Li, 11B, 92Nb, 138La and Ta and r-process elements. Several isotopes depend strongly on the neutrino flavor oscillation due to the Mikheyev-Smirnov-Wolfenstein (MSW) effect. We here discuss how to determine the neutrino temperatures and propose a method to determine still unknown neutrino oscillation parameters, mass hierarchy and θ13, simultaneously. Combining the recent experimental constraints on θ13 with isotopic ratios of the light elements discovered in presolar grains from the Murchison meteorite, we show that our method suggests at a marginal preference for an inverted neutrino mass hierarchy. We also discuss supernova relic neutrinos that may indicate the softness of the equation of state (EoS) of nuclear matter as well as adiabatic conditions of the neutrino oscillation.

  17. Supernova constraints on neutrino oscillation and EoS for proto-neutron star

    SciTech Connect

    Kajino, T.; Aoki, W.; Cheoun, M.-K.; Hayakawa, T.; Hidaka, J.; Hirai, Y.; Shibagaki, S.; Mathews, G. J.; Nakamura, K.; Suzuki, T.

    2014-05-02

    Core-collapse supernovae eject huge amount of flux of energetic neutrinos which affect explosive nucleosynthesis of rare isotopes like {sup 7}Li, {sup 11}B, {sup 92}Nb, {sup 138}La and Ta and r-process elements. Several isotopes depend strongly on the neutrino flavor oscillation due to the Mikheyev-Smirnov-Wolfenstein (MSW) effect. We here discuss how to determine the neutrino temperatures and propose a method to determine still unknown neutrino oscillation parameters, mass hierarchy and θ{sub 13}, simultaneously. Combining the recent experimental constraints on θ{sub 13} with isotopic ratios of the light elements discovered in presolar grains from the Murchison meteorite, we show that our method suggests at a marginal preference for an inverted neutrino mass hierarchy. We also discuss supernova relic neutrinos that may indicate the softness of the equation of state (EoS) of nuclear matter as well as adiabatic conditions of the neutrino oscillation.

  18. Extraction of amino acids from soils and sediments with superheated water

    NASA Technical Reports Server (NTRS)

    Cheng, C. N.; Ponnamperuma, C.

    1974-01-01

    A method of extraction for amino acids from soils and sediments involving superheated water has been investigated. About 75-97 per cent of the amino acids contained in four soils of a soil profile from Illinois were extracted by this method. Deep penetration of water into soil aggregates and partial hydrolysis of peptide bonds during this extraction by water at high temperature are likely mechanisms responsible for the release of amino acids from samples. This extraction method does not require subsequent desalting treatments when analyses are carried out with an ion-exchange amino acid analyzer.

  19. Lipase-catalyzed acidolysis of menhaden oil with conjugated linoleic acid: effect of water content.

    PubMed

    Torres, Carlos F; Hill, Charles G

    2002-06-01

    The effect of the water content on the lipase-catalyzed (Candida rugosa) interesterification (acidolysis) of menhaden oil with conjugated linoleic acid was studied for amounts of added water ranging from 0-4% (w/w). The rate of the acidolysis reaction increased with increasing water content, but the corresponding percentage of n-3 fatty acids liberated also increased. The implications of water content for minimization of the release of n-3 fatty acid residues while maximizing incorporation of CLA are discussed. PMID:12115120

  20. Study of an Acid-Free Technique for the Preparation of Glycyrrhetinic Acid from Ammonium Glycyrrhizinate in Subcritical Water.

    PubMed

    Lekar, Anna V; Borisenko, Sergey N; Vetrova, Elena V; Filonova, Olga V; Maksimenko, Elena V; Borisenko, Nikolai I; Minkin, Vladimir I

    2015-11-01

    The aim of this work was to study an application of a previously developed expedient acid-free technique for the preparation of glycyrrhetinic acid from ammonium glycyrrhizinate that requires no use of acids and toxic organic solvents. Subcritical water that serves as a reactant and a solvent was used in order to obtain glycyrrhetinic acid in good yields starting from ammonium glycyrrhizinate. It has been shown that variation of only one parameter of the process (temperature) allows alteration to thecomposition of the hydrolysis products. A new method was used for the synthesis of glycyrrhetinic acid (glycyrrhizic acid aglycone) and its monoglycoside. HPLC combined with mass spectrometry and NMR spectroscopy were used to determine the quantitative and qualitative compositions of the obtained products. The method developed for the production of glycyrrhetinic acid in subcritical water is environmentally friendly and faster than conventional hydrolysis methods that use acids and-expensive and toxic organic solvents. The proposed technique has a potential for the future development of inexpensive and environmentally friendly technologies for production of new pharmaceutical plant-based substances. PMID:26749800

  1. The development of the EOS data and information system

    NASA Technical Reports Server (NTRS)

    Taylor, Thomas D.; Ramapriyan, H. K.; Dozier, Jeffrey C.

    1991-01-01

    The architecture of the Earth Observing System (EOS), a major component of NASA's contribution to the U.S. Global Change Research Program, is described with emphasis on its development strategy. It is noted that the EOS is comprised of a scientific research program, a space measurement system, and an EOS Data and Information System (EOSDIS). Details are presented concerning the EOS program and its candidate instruments. Major components of EOS include Version 0 (V0) built on existing Distributed Active Archive Centers (DAACs), the EOSDIS core system (ECS), DAAC-unique functions, science computing facilities (SCF), and independent verification validation of the ECS. Requirements for EODIS are also reviewed noting that, among other requirements, it must keep up with an orbital average data rate of more than 30 Mbps as well as store, distribute, and manage information about tens of Petabytes of data during and after the 15-year mission.

  2. Biological Properties of Acidic Cosmetic Water from Seawater

    PubMed Central

    Liao, Wei-Ting; Huang, Tsi-Shu; Chiu, Chien-Chih; Pan, Jian-Liang; Liang, Shih-Shin; Chen, Bing-Hung; Chen, Shi-Hui; Liu, Po-Len; Wang, Hui-Chun; Wen, Zhi-Hong; Wang, Hui-Min; Hsiao, Shu-Wen

    2012-01-01

    This current work was to investigate the biological effects of acidic cosmetic water (ACW) on various biological assays. ACW was isolated from seawater and demonstrated several bio-functions at various concentration ranges. ACW showed a satisfactory effect against Staphylococcus aureus, which reduced 90% of bacterial growth after a 5-second exposure. We used cultured human peripheral blood mononuclear cells (PBMCs) to test the properties of ACW in inflammatory cytokine release, and it did not induce inflammatory cytokine release from un-stimulated, normal PBMCs. However, ACW was able to inhibit bacterial lipopolysaccharide (LPS)-induced inflammatory cytokine TNF-α released from PBMCs, showing an anti-inflammation potential. Furthermore, ACW did not stimulate the rat basophilic leukemia cell (RBL-2H3) related allergy response on de-granulation. Our data presented ACW with a strong anti-oxidative ability in a superoxide anion radical scavenging assay. In mass spectrometry information, magnesium and zinc ions demonstrated bio-functional detections for anti-inflammation as well as other metal ions such as potassium and calcium were observed. ACW also had minor tyrosinase and melanin decreasing activities in human epidermal melanocytes (HEMn-MP) without apparent cytotoxicity. In addition, the cell proliferation assay illustrated anti-growth and anti-migration effects of ACW on human skin melanoma cells (A375.S2) indicating that it exerted the anti-cancer potential against skin cancer. The results obtained from biological assays showed that ACW possessed multiple bioactivities, including anti-microorganism, anti-inflammation, allergy-free, antioxidant, anti-melanin and anticancer properties. To our knowledge, this was the first report presenting these bioactivities on ACW. PMID:22754342

  3. EOS ground data systems: A description and interface overview

    NASA Technical Reports Server (NTRS)

    Smith, Gene

    1993-01-01

    The Earth Observing System (EOS) is planned as a space-based measurement system, earth-science research program, and data and information system (EOSDIS). It will consist of several high data rate spacecraft with multiple earth sensing instruments which provide investigators with a thorough, longterm view of the earth's environment. Up to seven spacecraft may be supported at once, either in operational, checkout, or testing phases; and the average data rate from the EOS satellites in orbit at any one time is expected to be from 18 to 60 Mbps. Providing the data processing and flight operations support for EOS will be the EOSDIS Core System (ECS). The ECS will command and control the spacecraft; process and store the EOS data; provide access to the data for years; and support researchers. The data processing aspects of the ECS consist of a collection of Distributed Active Archive Centers (DAAC's) which perform the product generation, data archive and distribution, and information management services. Flight operations aspects will be provided by the EOS Operations Center, by instrument control centers, and by widely distributed instrument support terminals. The communications and system management aspects will be provided by the EOSDIS Science Network and the System Management Center. In addition to the EOS satellite data, other data sets from earlier earth science missions are also to be added to designated DAAC's. Other ground data systems which will provide support to EOS for acquiring, transporting, processing, and distributing the transformed spacecraft data are currently being defined or are being upgraded for the EOS era. These systems include the Space Network consisting of the Tracking and Data Relay Satellite System (TDRSS), the TDRSS Ground Terminals, and the Network Control Center as well as the night Dynamics Facility, the EOS Data and Operations System, and EOS Communications. This paper briefly describes data handling by the ECS, the support data

  4. OCCURRENCE OF IODO-ACID AND IODO-THM DISINFECTION BY-PRODUCTS IN CHLORAMINATED DRINKING WATER

    EPA Science Inventory

    Iodo-acids were recently identified for the first time as DBPs in drinking water disinfected with chloramines. The iodo-acids identified included iodoacetic acid (IAA), bromoiodoacetic acid, (E)-3-bromo-3-iodo-propenoic acid, (Z)-3-bromo-3-iodo-propenoic acid, and (E)-2-iodo-3...

  5. Phase equilibria and distribution constants of metal ions in diantipyryl alkane-organic acid-hydrochloric acid-water systems

    NASA Astrophysics Data System (ADS)

    Degtev, M. I.; Popova, O. N.; Yuminova, A. A.

    2014-08-01

    The ability of antipyrine and its derivatives (diantipyryl alkanes) to form separating systems in the presence of salicylic (sulfosalicylic) acid and hydrochloric acid and water is studied. The optimum volume of the organic phase, the composition of complexes, and the mechanism for the distribution of metal ions are determined, depending on the concentrations of the main components and the salting-out agent. The complex distribution and extraction constants are calculated.

  6. Isolation of organic acids from large volumes of water by adsorption chromatography

    USGS Publications Warehouse

    Aiken, George R.

    1984-01-01

    The concentrations of dissolved organic carbon from most natural waters ranges from 1 to 20 milligrams carbon per liter, of which approximately 75 percent are organic acids. These acids can be chromatographically fractionated into hydrophobic organic acids, such as humic substances, and hydrophilic organic acids. To effectively study any of these organic acids, they must be isolated from other organic and inorganic species, and concentrated. Usually, large volumes of water must be processed to obtain sufficient quantities of material, and adsorption chromatography on synthetic, macroporous resins has proven to be a particularly effective method for this purpose. The use of the nonionic Amberlite XAD-8 and Amberlite XAD-4 resins and the anion exchange resin Duolite A-7 for isolating and concentrating organic acids from water is presented.

  7. Water Stress Responses of Tomato Mutants Impaired in Hormone Biosynthesis Reveal Abscisic Acid, Jasmonic Acid and Salicylic Acid Interactions.

    PubMed

    Muñoz-Espinoza, Valeria A; López-Climent, María F; Casaretto, José A; Gómez-Cadenas, Aurelio

    2015-01-01

    To investigate the putative crosstalk between JA and ABA in Solanum lycopersicum plants in response to drought, suppressor of prosystemin-mediated responses2 (spr2, JA-deficient) and flacca (flc, ABA-deficient) mutants together with the naphthalene/salicylate hydroxylase (NahG) transgenic (SA-deficient) line were used. Hormone profiling and gene expression of key enzymes in ABA, JA and SA biosynthesis were analyzed during early stages of drought. ABA accumulation was comparable in spr2 and wild type (WT) plants whereas expression of 9-cis-epoxycarotenoid dioxygenase 1 (NCED1) and NCED2 was different, implying a compensation mechanism between NCED genes and an organ-specific regulation of NCED1 expression. JA levels and 12-oxo-phytodienoic acid reductase 3 (OPR3) expression in flc plants suggest that ABA regulates the induction of the OPR3 gene in roots. By contrast, ABA treatment to flc plants leads to a reduction of JA and SA contents. Furthermore, different pattern of SA accumulation (and expression of isochorismate synthase and phenylalanine ammonia lyase 1) was observed between WT seedlings and mutants, suggesting that SA plays an important role on the early response of tomato plants to drought and also that JA and ABA modulate its biosynthesis. Finally, hormone profiling in spr2 and NahG plants indicate a crosstalk between JA and SA that could enhance tolerance of tomato to water stress. PMID:26635826

  8. Water Stress Responses of Tomato Mutants Impaired in Hormone Biosynthesis Reveal Abscisic Acid, Jasmonic Acid and Salicylic Acid Interactions

    PubMed Central

    Muñoz-Espinoza, Valeria A.; López-Climent, María F.; Casaretto, José A.; Gómez-Cadenas, Aurelio

    2015-01-01

    To investigate the putative crosstalk between JA and ABA in Solanum lycopersicum plants in response to drought, suppressor of prosystemin-mediated responses2 (spr2, JA-deficient) and flacca (flc, ABA-deficient) mutants together with the naphthalene/salicylate hydroxylase (NahG) transgenic (SA-deficient) line were used. Hormone profiling and gene expression of key enzymes in ABA, JA and SA biosynthesis were analyzed during early stages of drought. ABA accumulation was comparable in spr2 and wild type (WT) plants whereas expression of 9-cis-epoxycarotenoid dioxygenase 1 (NCED1) and NCED2 was different, implying a compensation mechanism between NCED genes and an organ-specific regulation of NCED1 expression. JA levels and 12-oxo-phytodienoic acid reductase 3 (OPR3) expression in flc plants suggest that ABA regulates the induction of the OPR3 gene in roots. By contrast, ABA treatment to flc plants leads to a reduction of JA and SA contents. Furthermore, different pattern of SA accumulation (and expression of isochorismate synthase and phenylalanine ammonia lyase 1) was observed between WT seedlings and mutants, suggesting that SA plays an important role on the early response of tomato plants to drought and also that JA and ABA modulate its biosynthesis. Finally, hormone profiling in spr2 and NahG plants indicate a crosstalk between JA and SA that could enhance tolerance of tomato to water stress. PMID:26635826

  9. Acid deposition and the acidification of soils and waters

    SciTech Connect

    Reuss, J.O.; Johnson, D.W.

    1985-01-01

    A conceptual model of acid deposition is presented consistent with established physicochemical principles and the bulk of available information. The authors seek to provide insight into probable long-term effects of acid deposition; a testable hypotheses; plus design and interpretation of the research. (PSB)

  10. Integrating new Storage Technologies into EOS

    NASA Astrophysics Data System (ADS)

    Peters, Andreas J.; van der Ster, Dan C.; Rocha, Joaquim; Lensing, Paul

    2015-12-01

    The EOS[1] storage software was designed to cover CERN disk-only storage use cases in the medium-term trading scalability against latency. To cover and prepare for long-term requirements the CERN IT data and storage services group (DSS) is actively conducting R&D and open source contributions to experiment with a next generation storage software based on CEPH[3] and ethernet enabled disk drives. CEPH provides a scale-out object storage system RADOS and additionally various optional high-level services like S3 gateway, RADOS block devices and a POSIX compliant file system CephFS. The acquisition of CEPH by Redhat underlines the promising role of CEPH as the open source storage platform of the future. CERN IT is running a CEPH service in the context of OpenStack on a moderate scale of 1 PB replicated storage. Building a 100+PB storage system based on CEPH will require software and hardware tuning. It is of capital importance to demonstrate the feasibility and possibly iron out bottlenecks and blocking issues beforehand. The main idea behind this R&D is to leverage and contribute to existing building blocks in the CEPH storage stack and implement a few CERN specific requirements in a thin, customisable storage layer. A second research topic is the integration of ethernet enabled disks. This paper introduces various ongoing open source developments, their status and applicability.

  11. Version 3 Products from EOS MLS

    NASA Astrophysics Data System (ADS)

    Cuddy, D.

    2009-12-01

    In early August of 2009, Earth Observing System (EOS) Microwave Limb Sounder (MLS) began production with a newer version (Version 3) of Level 1 and Level 2 software. Over the next year, MLS intends to reprocess all of the mission data with these newer algorithms. Version 3 of MLS algorithms includes minor updates to Level 1 software; improvements in our Level 2 data products; and the addition of a new data product ¬ CH3Cl. Updates to Level 1 include redefining the Galactic Core for the instrument field of view. Improvements in Level 2 include O3 at higher vertical resolution with twice the resolution through the troposphere and a useful product at 260 hPa; H2O with removal of a kink at 2.3 hPa; CO with a reduced high bias; ClO with a reduced negative bias; HCl with the removal of various kinks; and HCN with a useful range from 100hPa to 10 hPa. For every product we make it easier to exclude heights and geographic locations where the quality is known to be poor. Version 3 metadata employs eXtensible Markup Language (XML) format replacing the old Object Definition Language (ODL) format. The Goddard Earth Sciences Data and Information Services Center (GES-DISC) archives and distributes these products to the users.

  12. Processing EOS MLS Level-2 Data

    NASA Technical Reports Server (NTRS)

    Snyder, W. Van; Wu, Dong; Read, William; Jiang, Jonathan; Wagner, Paul; Livesey, Nathaniel; Schwartz, Michael; Filipiak, Mark; Pumphrey, Hugh; Shippony, Zvi

    2006-01-01

    A computer program performs level-2 processing of thermal-microwave-radiance data from observations of the limb of the Earth by the Earth Observing System (EOS) Microwave Limb Sounder (MLS). The purpose of the processing is to estimate the composition and temperature of the atmosphere versus altitude from .8 to .90 km. "Level-2" as used here is a specialists f term signifying both vertical profiles of geophysical parameters along the measurement track of the instrument and processing performed by this or other software to generate such profiles. Designed to be flexible, the program is controlled via a configuration file that defines all aspects of processing, including contents of state and measurement vectors, configurations of forward models, measurement and calibration data to be read, and the manner of inverting the models to obtain the desired estimates. The program can operate in a parallel form in which one instance of the program acts a master, coordinating the work of multiple slave instances on a cluster of computers, each slave operating on a portion of the data. Optionally, the configuration file can be made to instruct the software to produce files of simulated radiances based on state vectors formed from sets of geophysical data-product files taken as input.

  13. Concentration and fractionation of hydrophobic organic acid constituents from natural waters by liquid chromatography

    USGS Publications Warehouse

    Thurman, E.M.; Malcolm, R.L.

    1979-01-01

    A scheme is presented which used adsorption chromatography with pH gradient elution and size-exclusion chromatography to concentrate and separate hydrophobic organic acids from water. A review of chromatographic processes involved in the flow scheme is also presented. Organic analytes which appear in each aqueous fraction are quantified by dissolved organic carbon analysis. Hydrophobic organic acids in a water sample are concentrated on a porous acrylic resin. These acids usually constitute approximately 30-50 percent of the dissolved organic carbon in an unpolluted water sample and are eluted with an aqueous eluent (dilute base). The concentrate is then passed through a column of polyacryloylmorpholine gel, which separates the acids into high- and low-molecular-weight fractions. The high- and low-molecular-weight eluates are reconcentrated by adsorption chromatography, then are eluted with a pH gradient into strong acids (predominately carboxylic acids) and weak acids (predominately phenolic compounds). For standard compounds and samples of unpolluted waters, the scheme fractionates humic substances into strong and weak acid fractions that are separated from the low molecular weight acids. A new method utilizing conductivity is also presented to estimate the acidic components in the methanol fraction.

  14. Matrix Isolation IR Spectroscopy of 1:1 Complexes of Acetic Acid and Trihaloacetic Acids with Water and Benzene

    NASA Astrophysics Data System (ADS)

    Banerjee, Pujarini; Chakraborty, Tapas

    2015-06-01

    A comparative study of infrared spectral effects for 1:1 complex formation of acetic acid (AA), trifluoroacetic acid (TFAA) and trichloroacetic acid (TFAA) with water and benzene has been carried out under a matrix isolation environment. Despite the large difference in aqueous phase acidities of the three acids, the measured νb{OH}stretching frequencies of the monomers of the three molecules are found to be almost same, and in agreement with gas phase electronic structure calculations. Intrinsic acidities are expressed only in the presence of the proton acceptors, water or benzene. Although electronic structure calculations predict distinct νb{OH} red-shifts for all three acids, the measured spectral features for TCAA and TFAA in this range do not allow unambiguous assignments for the 1:1 complex. On the other hand, the spectral changes in the νb{C=O} region are more systematic, and the observed changes are consistent with predictions of theory. Components of overall binding energy of each complex have been obtained from energy decomposition analysis, which allows determination of the relative contributions of various physical forces towards overall stability of the complexes, and the details will be discussed in the talk.

  15. Cold water fish gelatin modification by a natural phenolic cross-linker (ferulic acid and caffeic acid)

    PubMed Central

    Araghi, Maryam; Moslehi, Zeinab; Mohammadi Nafchi, Abdorreza; Mostahsan, Amir; Salamat, Nima; Daraei Garmakhany, Amir

    2015-01-01

    Nowadays use of edible films and coatings is increasing due to their biodegradability and environment friendly properties. Fish gelatin obtained from fish skin wastage can be used as an appropriate protein compound for replacing pork gelatin to produce edible film. In this study films were prepared by combination of fish gelatin and different concentration (0%, 1%, 3%, and 5%) of two phenolic compounds (caffeic acid and ferulic acid). The film was prepared at pH > 10 and temperature of 60˚c under continuous injection of O2 and addition of the plasticizer sorbitol/glycerol. Results showed that solubility, oxygen permeability, and water vapor permeability were decreased for caffeic acid and the highest effect was observed at concentration of 5%. Solubility had a linear relationship with concentration of phenolic compound in film containing ferulic acid, however, no significant change was observed in vapor and O2 permeability. A comparison between two phenolic compounds showed that caffeic acid had the highest effect in decreasing solubility, water vapor permeability, and oxygen permeability. Caffeic acid is more effective phenolic compound compared with Ferulic acid that can increase safety of biodegradable packaging by improving their barrier and physicochemical properties. PMID:26405523

  16. Oxidation reaction of high molecular weight carboxylic acids in supercritical water.

    PubMed

    Jin, Fangming; Moriya, Takehiko; Enomoto, Heiji

    2003-07-15

    Stearic acid, being a model compound of high molecular weight carboxylic acids, was oxidized in a batch reactor by changing the oxygen supply with an insufficient oxygen supply at a constant reaction time at 420 degrees C. On the basis of the intermediate products identified by GC/MS, NMR, and HPLC analyses and the free-radical reaction mechanism, the oxidation pathways of high molecular weight carboxylic acids in supercritical water are discussed. The reaction of carboxylic acids in supercritical water proceeds with the consecutive oxidation of higher molecular weight carboxylic acids to lower molecular weight carboxylic acids through several major pathways. The attack of the hydroxyl radical occurs not only at the carbons in alpha-, beta-, gamma-positions to a --COOH group but also at the carbons ((omega-1)-carbon and/or omega-carbon) far in the alkyl chain from a --COOH group, which may lead to the formation of dicarboxylic acids. PMID:12901673

  17. Surface rheology and foaming properties of sodium oleate and C12(EO)6 aqueous solutions.

    PubMed

    Beneventi, Davide; Pugh, Robert J; Carré, Bruno; Gandini, Alessandro

    2003-12-01

    The dynamic surface tension (DST) and the surface viscoelastic modulus of sodium oleate aqueous solutions at different concentrations were measured using an image analysis tensiometer based on the oscillating bubble technique. The diffusion coefficient of oleate moieties was calculated from DST measurements and the surface viscoelastic modulus using the Langmuir-Szyszkowski and the diffusion-controlled adsorption models. The viscoelastic moduli obtained from model calculations were compared with the corresponding experimental values. The diffusion coefficient of C(12)(EO)(6) in water and the parameters of the Langmuir-Szyszkowski adsorption isotherm were taken from the literature and used to calculate the surface viscoelastic modulus of its aqueous solutions at different concentrations. The foaming properties of both C(12)(EO)(6) and sodium oleate solutions, viz., the foam conductance and the water volume fraction in the foam, were measured using a commercial Foamscan device. Foaming experiments with C(12)(EO)(6) and sodium oleate solutions were carried out either under static conditions; i.e., the foam conductance and the water volume fraction were measured as a function of time after the generation of a fixed volume of foam, or under dynamic conditions; i.e., the foam conductance and the water volume fraction were measured during foam formation. The variations in the foam permeability as a function of surfactant concentration were related to the viscoelastic properties of the air/water interface and to the presence of micelles in the foam films. With foams in which the water volume fraction was higher than 0.05, the foam electrical conduction could be described using a simple parallel resistor model and their conductance measurements were related to the foam water volume fraction. The results related to water drainage under static conditions were used to interpret water drainage under dynamic conditions. Preliminary conjectures on the influence of foam

  18. EOS7CA Version 1.0: TOUGH2 Module for Gas Migration in Shallow Subsurface Porous Media Systems

    2015-06-22

    EOS7CA is a TOUGH2 module for mixtures of a non-condensible gas (NCG) and air (with or without a gas tracer), an aqueous phase, and water vapor. The user can select the NCG as being CO2, N2, or CH4. EOS7CA uses a cubic equation of state with a multiphase version of Darcy’s Law to model flow and transport of gas and aqueous phase mixtures over a range of pressures and temperatures appropriate to shallow subsurface porousmore » media systems. The limitation to shallow systems arises from the use of Henry’s Law for gas solubility which is appropriate for low pressures but begins to over-predict solubility starting at pressures greater than approximately 1 MPa (10 bar). The components modeled in EOS7CA are water, brine, NCG, gas tracer, air, and optional heat.« less

  19. EOS7CA Version 1.0: TOUGH2 Module for Gas Migration in Shallow Subsurface Porous Media Systems

    SciTech Connect

    Oldenburg, Curtis M.

    2015-06-22

    EOS7CA is a TOUGH2 module for mixtures of a non-condensible gas (NCG) and air (with or without a gas tracer), an aqueous phase, and water vapor. The user can select the NCG as being CO2, N2, or CH4. EOS7CA uses a cubic equation of state with a multiphase version of Darcy’s Law to model flow and transport of gas and aqueous phase mixtures over a range of pressures and temperatures appropriate to shallow subsurface porous media systems. The limitation to shallow systems arises from the use of Henry’s Law for gas solubility which is appropriate for low pressures but begins to over-predict solubility starting at pressures greater than approximately 1 MPa (10 bar). The components modeled in EOS7CA are water, brine, NCG, gas tracer, air, and optional heat.

  20. 76 FR 15859 - Reducing Regulatory Burden; Retrospective Review under E.O. 13563

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-22

    ... Chapters 5 and 61 Reducing Regulatory Burden; Retrospective Review under E.O. 13563 AGENCY: Office of... Executive Order (EO) 13563, ``Improving Regulation and Regulatory Review.'' E.O. 132563 was signed...

  1. PHOTOLYSIS RATES OF (2,4,5-TRICHLOROPHENOXY)ACETIC ACID AND 4-AMINO-3,5,6-TRICHLOROPICOLINIC ACID IN NATURAL WATERS

    EPA Science Inventory

    Photoreactions of (2,45-trichlorophenoxy) acetic acid (2,4,5-T) and 4-amino-3,5,6-trichloropicolinic acid (picloram) were studied in distilled water, natural water samples, fulvic acid solutions, and solutions containing iron (III) and/or hydrogen peroxide to determine the effect...

  2. Assessment of nanofiltration and reverse osmosis potentialities to recover metals, sulfuric acid, and recycled water from acid gold mining effluent.

    PubMed

    Ricci, Bárbara C; Ferreira, Carolina D; Marques, Larissa S; Martins, Sofia S; Amaral, Míriam C S

    2016-01-01

    This work assessed the potential of nanofiltration (NF) and reverse osmosis (RO) to treat acid streams contaminated with metals, such as effluent from the pressure oxidation process (POX) used in refractory gold ore processing. NF and RO were evaluated in terms of rejections of sulfuric acid and metals. Regarding NF, high sulfuric acid permeation (∼100%), was observed, while metals were retained with high efficiencies (∼90%), whereas RO led to high acid rejections (<88%) when conducted in pH values higher than 1. Thus, sequential use of NF and RO was proved to be a promising treatment for sulfuric acid solutions contaminated by metals, such as POX effluent. In this context, a purified acid stream could be recovered in NF permeate, which could be further concentrated in RO. Recovered acid stream could be reused in the gold ore processing or commercialized. A metal-enriched stream could be also recovered in NF retentate and transferred to a subsequent metal recovery stage. In addition, considering the high acid rejection obtained through the proposed system, RO permeate could be used as recycling water. PMID:27438241

  3. Effect of Lactic Acid Etching on Bonding Effectiveness of Orthodontic Bracket after Water Storage

    PubMed Central

    Alsulaimani, Fahad F.

    2014-01-01

    Objective. To determine the effect of lactic acid at various concentrations on the shear bond strength of orthodontic brackets bonded with the resin adhesive system before and after water storage. Materials and Methods. Hundred extracted human premolars were divided into 5 treatment groups and etched for 30 seconds with one of the following agents: lactic acid solution with (A) 10%, (B) 20%, (C) 30%, and (D) 50%; group E, 37% phosphoric acid (control). Metal brackets were bonded using a Transbond XT. Bonding effectiveness was assessed by shear bond strength after 24 hours and 6 months of water storage at 37°C. The data were analyzed with 2-way analysis of variance and Tukey's Honestly Significant Difference (HSD) test (α = .001). Results. Lactic acid concentration and water storage resulted in significant differences for brackets bond strength (P < .001). 20% lactic acid had significantly higher mean bond strength values (SD) for all conditions: 24 hours [12.2 (.7) MPa] and 6 months [10.1 (.6) MPa] of water storage. 37% phosphoric acid had intermediate bond strength values for all conditions: 24 hours [8.2 (.6) MPa] and 6 months [6.2 (.6) MPa] of water storage. Also, there were differences in bond strength between storage time, with a reduction in values from 24 hours and 6 months for all experimental groups (P < .001). Conclusion. Lactic acid could be used in place of phosphoric acid as an enamel etchant for bonding of orthodontic brackets. PMID:25006465

  4. Acid generation upon thermal concentration of natural water: The critical water content and the effects of ionic composition

    NASA Astrophysics Data System (ADS)

    Pulvirenti, April L.; Needham, Karen M.; Adel-Hadadi, Mohamad A.; Marks, Charles R.; Gorman, Jeffrey A.; Shettel, Donald L.; Barkatt, Aaron

    2009-10-01

    Thermal evaporation of a variety of simulated pore waters from the region of Yucca Mountain, Nevada, produced acidic liquids and gases during the final stages of evaporation. Several simulated pore waters were prepared and then thermally distilled in order to collect and analyze fractions of the evolved vapor. In some cases, distillates collected towards the end of the distillation were highly acidic; in other cases the pH of the distillate remained comparatively unchanged during the course of the distillation. The results suggest that the pH values of the later fractions are determined by the initial composition of the water. Acid production stems from the hydrolysis of magnesium ions, especially at near dryness. Near the end of the distillation, magnesium nitrate and magnesium chloride begin to lose water of hydration, greatly accelerating their thermal decomposition to form acid. Acid formation is promoted further when precipitated calcium carbonate is removed. Specifically, calcium chloride-rich pore waters containing moderate (10-20 ppm) levels of magnesium and nitrate and low levels of bicarbonate produced mixtures of nitric and hydrochloric acid, resulting in a precipitous drop in pH to values of 1 or lower after about 95% of the original volume was distilled. Waters with either low or moderate magnesium content coupled with high levels of bicarbonate produced slightly basic fractions (pH 7-9). If calcium was present in excess of bicarbonate, waters containing moderate levels of magnesium produced acid even in the presence of bicarbonate, due to the precipitation of calcium carbonate. Other salts such as halite and anhydrite promote the segregation of acidic vapors from residual basic solids. The concomitant release of wet acid gas has implications for the integrity of the alloys under consideration for containers at the Yucca Mountain nuclear waste repository. Condensed acid gases at very low pH, especially mixtures of nitric and hydrochloric acid, are

  5. Acid generation upon thermal concentration of natural water: the critical water content and the effects of ionic composition.

    PubMed

    Pulvirenti, April L; Needham, Karen M; Adel-Hadadi, Mohamad A; Marks, Charles R; Gorman, Jeffrey A; Shettel, Donald L; Barkatt, Aaron

    2009-10-13

    Thermal evaporation of a variety of simulated pore waters from the region of Yucca Mountain, Nevada, produced acidic liquids and gases during the final stages of evaporation. Several simulated pore waters were prepared and then thermally distilled in order to collect and analyze fractions of the evolved vapor. In some cases, distillates collected towards the end of the distillation were highly acidic; in other cases the pH of the distillate remained comparatively unchanged during the course of the distillation. The results suggest that the pH values of the later fractions are determined by the initial composition of the water. Acid production stems from the hydrolysis of magnesium ions, especially at near dryness. Near the end of the distillation, magnesium nitrate and magnesium chloride begin to lose water of hydration, greatly accelerating their thermal decomposition to form acid. Acid formation is promoted further when precipitated calcium carbonate is removed. Specifically, calcium chloride-rich pore waters containing moderate (10-20 ppm) levels of magnesium and nitrate and low levels of bicarbonate produced mixtures of nitric and hydrochloric acid, resulting in a precipitous drop in pH to values of 1 or lower after about 95% of the original volume was distilled. Waters with either low or moderate magnesium content coupled with high levels of bicarbonate produced slightly basic fractions (pH 7-9). If calcium was present in excess of bicarbonate, waters containing moderate levels of magnesium produced acid even in the presence of bicarbonate, due to the precipitation of calcium carbonate. Other salts such as halite and anhydrite promote the segregation of acidic vapors from residual basic solids. The concomitant release of wet acid gas has implications for the integrity of the alloys under consideration for containers at the Yucca Mountain nuclear waste repository. Condensed acid gases at very low pH, especially mixtures of nitric and hydrochloric acid, are

  6. Eos, Koronis, and Maria Family Asteroids: Infrared (JHK) Photometry

    NASA Technical Reports Server (NTRS)

    Veeder, Glenn J.; Matson, Dennis L.; Owensby, Pamela D.; Gradie, Jonathan C.; Bell, Jeffrey F.; Tedesco, Edward F.

    1995-01-01

    Infrared photometry at 1.2, 1.6, and 2.2 micrometer (JHK) is reported for 56 asteroids in the Eos, Koronis and, Maria dynamical families. These data are consistent with similar surface composition for all of the asteroids of each family. The infrared colors within each family cluster in the region observed for the S taxonomic class, but Eos asteroids may belong to a separable K class. Asteroid 243 Ida, which was observed by the Galileo spacecraft, is a typical member of the Koronis family. The average infrared colors of the Maria family are slightly redder than those of the Eos and Koronis families.

  7. EOS production on the Space Station. [Electrophoresis Operations/Space

    NASA Technical Reports Server (NTRS)

    Runge, F. C.; Gleason, M.

    1986-01-01

    The paper discusses a conceptual integration of the equipment for EOS (Electrophoresis Operations/Space) on the Space Station in the early 1990s. Electrophoresis is a fluid-constituent separation technique which uses forces created by an electrical field. Aspects covered include EOS equipment and operations, and Space Station installations involving a pressurized module, a resupply module, utility provisions and umbilicals and crew involvement. Accommodation feasibility is generally established, and interfaces are defined. Space Station production of EOS-derived pharmaceuticals will constitute a significant increase in capability compared to precursor flights on the Shuttle in the 1980s.

  8. EOS-AM1 Nickel Hydrogen Cell

    NASA Technical Reports Server (NTRS)

    Bennett, Charles W.; Keys, Denney J.; Rao, Gopalakrishna M.; Wannemacher, Hari E.; Vaidyanathan, Harry

    1997-01-01

    This paper reports the interim results of the Earth Observing System AM-1 project (EOS-AM-1) nickel hydrogen cell life test being conducted under contract to National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC) at the Lockheed Martin Missile and Space (LMMS) facility in East Windsor, NJ; and at COMSAT Labs., Clarksburg, MD. The purpose of die tests is to verify that the EOS-AM-1 cell design can meet five years of real-time Low Earth Orbit (LEO) cycling. The tests include both real-time LEO and accelerated stress tests. At LMMS, the first real-time LEO simulated 99 minute orbital cycle started on February 7, 1994 and the test has been running continuously since that time, with 18,202 LEO cycles completed as of September 1, 1997. Each cycle consists of a 64 minute charge (VT at 1.507 volts per cell, 1.06 C/D ratio, followed by 0.6 ampere trickle charge) and a 35 minute constant power discharge at 177 watts (22.5% DOD). At COMSAT, the accelerated stress test consists of 90 minute orbital cycles at 60% DOD with a 30 minute discharge at 60 amperes and a 60 minute charge at 40 amperes (VT at 1.54 volts per cell to 1.09 C/D ratio, followed by 0.6 ampere trickle charge). The real-time LEO life test battery consists of seven, 50AH (nameplate rating) Eagle-Picher, Inc. (EPI) Mantech cells manufactured into three, 3-cell pack assemblies (there are two place holder cells that are not part of the life test electrical circuit). The test pack is configured to simulate the conductive thermal design of the spacecraft battery, including: conductive aluminum sleeves, 3-cell pack aluminum baseplate, and honeycomb panel all mounted to a liquid (-5 C) cold plate. The entire assembly is located in a thermal chamber operating at +30 C. The accelerated stress test unit consists of five cells mounted in machined aluminum test sleeves and is operating at +10 C. The real-time LEO life test battery has met all performance requirements through the first 18

  9. Monte Carlo simulations of the pressure dependence of the water-acid gas interfacial tensions.

    PubMed

    Biscay, F; Ghoufi, A; Lachet, V; Malfreyt, P

    2009-10-29

    We report two-phase Monte Carlo (MC) simulations of the binary water-acid gas mixtures at high temperature and high pressure. Simulations are performed in the Np(N)AT ensemble in order to reproduce the pressure dependence of the interfacial tensions of the water-CO(2) and water-H(2)S mixtures. The interfacial tension of the binary water-CO(2) mixture is determined from 5 to 45 MPa along the isotherm T = 383 K. Water-H(2)S interfacial tensions are computed along one supercritical isotherm (T = 393 K) in a pressure range of 1-15 MPa. The temperature and pressure conditions investigated here by the MC simulations are typical of the geological storage conditions of these acid gases. The coexisting densities and the compositions of the water-rich and acid-gas-rich phases are compared with experiments and with data calculated from Gibbs ensemble Monte Carlo (GEMC) simulations. PMID:19803493

  10. Model for a surface film of fatty acids on rain water and aerosol particles

    NASA Astrophysics Data System (ADS)

    Seidl, Winfried

    Organic compounds with polar groups can form films on the water surface which lower the surface tension and may hinder the transport of water vapor and trace gases through the interface. A model is presented which describes in detail surface films formed by fatty acids. The model has been applied to measured concentrations of fatty acids on rain water and atmospheric aerosol particles. In most cases only a diluted film has been calculated which does not affect their physical and chemical properties. The exception was a clean region in the western USA, where the fatty acid concentrations are sufficiently high to form a dense film on atmospheric aerosol particles. An algorithm for the identification of the sources of fatty acids was developed. It showed leaf abrasion or biomass burning as a major source of fatty acids in the western USA.

  11. A molecular dynamics study of water mass accommodation on condensed phase water coated by fatty acid monolayers

    NASA Astrophysics Data System (ADS)

    Takahama, S.; Russell, L. M.

    2011-01-01

    As the water uptake by particles and clouds influences the radiative balance of the Earth, it is desirable to understand the mechanisms and parameters, which regulate water uptake in these colloidal particles. In this work, molecular dynamics simulations were used to simulate scattering or accommodation of water vapor molecules impinging on a slab of water and slabs of water coated by monomolecular amphiphile films: octanoic acid (C8) at surface densities of 29 and 18 Å2 per molecule and myristic acid (C14) at 29 Å2 per molecule. The mass accommodation coefficient of near unity on a pure water slab is in agreement with values estimated using similar scattering simulations using other potentials for water. The addition of surface-active organic molecules in quantities corresponding to less than 1% of mass in a typical cloud droplet are predicted to reduce this mass accommodation coefficient by 70-100% in similar types of scattering simulations. The mass accommodation coefficient decreased monotonically with projected surface coverage of the hydrocarbon backbones, although the accommodation mechanisms differed by packing density and type of organic molecule. The mechanisms of interaction of the impinging water vapor molecules with the simulated organic films are discussed in the context of their chemical characteristics and physical structures (e.g., fatty acid chain orientation).

  12. Negative pH and extremely acidic mine waters from Iron Mountain, California

    USGS Publications Warehouse

    Nordstrom, D.K.; Alpers, C.N.; Ptacek, C.J.; Blowes, D.W.

    2000-01-01

    Extremely acidic mine waters with pH values as low as -3.6, total dissolved metal concentrations as high as 200 g/L, and sulfate concentrations as high as 760 g/L, have been encountered underground in the Richmond Mine at Iron Mountain, CA. These are the most acidic waters known. The pH measurements were obtained by using the Pitzer method to define pH for calibration of glass membrane electrodes. The calibration of pH below 0.5 with glass membrane electrodes becomes strongly nonlinear but is reproducible to a pH as low as -4. Numerous efflorescent minerals were found forming from these acid waters. These extreme acid waters were formed primarily by pyrite oxidation and concentration by evaporation with minor effects from aqueous ferrous iron oxidation and efflorescent mineral formation.

  13. Solid/liquid phase diagram of the ammonium sulfate/succinic acid/water system.

    PubMed

    Pearson, Christian S; Beyer, Keith D

    2015-05-14

    We have studied the low-temperature phase diagram and water activities of the ammonium sulfate/succinic acid/water system using differential scanning calorimetry and infrared spectroscopy of thin films. Using the results from our experiments, we have mapped the solid/liquid ternary phase diagram, determined the water activities based on the freezing point depression, and determined the ice/succinic acid phase boundary as well as the ternary eutectic composition and temperature. We also compared our results to the predictions of the extended AIM aerosol thermodynamics model (E-AIM) and found good agreement for the ice melting points in the ice primary phase field of this system; however, differences were found with respect to succinic acid solubility temperatures. We also compared the results of this study with those of previous studies that we have published on ammonium sulfate/dicarboxylic acid/water systems. PMID:25431860

  14. IDENTIFICATION OF NEW BROMINATED ACIDS IN DRINKING WATER

    EPA Science Inventory

    Since chloroform was identified as the first disinfection by-product (DBP) in drinking water, there has been more than 25 years of research on DBPs. Despite these efforts, more than 50% of the total organic halide (TOX) formed in chlorinated drinking water remains unknown. Ther...

  15. XML DTD and Schemas for HDF-EOS

    NASA Technical Reports Server (NTRS)

    Ullman, Richard; Yang, Jingli

    2008-01-01

    An Extensible Markup Language (XML) document type definition (DTD) standard for the structure and contents of HDF-EOS files and their contents, and an equivalent standard in the form of schemas, have been developed.

  16. Boric acid equilibria in near-critical and supercritical water

    SciTech Connect

    Wofford, W.T.; Gloyna, E.F.; Johnston, K.P.

    1998-05-01

    Greater knowledge of acid-base equilibria is crucial to understanding the chemistry of hydrothermal processes including oxidation of organics, corrosion, catalysis, hydrolysis reactions, crystal growth and formation, precipitation of metal complexes and steam power cycles. The pH values of aqueous solutions of boric acid and KOH were measured with the optical indicator 2-naphthol at temperatures from 300 to 380 C. The equilibrium constant K{sub b}{sup {minus}1} for the reaction B(OH){sub 3} + OH{sup {minus}} = B(OH){sub 4}{sup {minus}} was determined from the pH measurements and correlated with a modified Born model. The titration curve for the addition of HCl to sodium borate exhibits strong acid-strong base behavior even at 350 C and 24.1 MPa. At these conditions, aqueous solutions of sodium borate buffer the pH at 9.6 {+-} 0.25.

  17. Reactions Between Water Soluble Organic Acids and Nitrates in Atmospheric Aerosols: Recycling of Nitric Acid and Formation of Organic Salts

    SciTech Connect

    Wang, Bingbing; Laskin, Alexander

    2014-03-25

    Atmospheric particles often include a complex mixture of nitrate and secondary organic materials accumulated within the same individual particles. Nitrate as an important inorganic component can be chemically formed in the atmosphere. For instance, formation of sodium nitrate (NaNO3) and calcium nitrate Ca(NO3)2 when nitrogen oxide and nitric acid (HNO3) species react with sea salt and calcite, respectively. Organic acids contribute a significant fraction of photochemically formed secondary organics that can condense on the preexisting nitrate-containing particles. Here, we present a systematic microanalysis study on chemical composition of laboratory generated particles composed of water soluble organic acids and nitrates (i.e. NaNO3 and Ca(NO3)2) investigated using computer controlled scanning electron microscopy with energy dispersive analysis of X-rays (CCSEM/EDX) and Fourier transform infrared micro-spectroscopy (micro-FTIR). The results show that water-soluble organic acids can react with nitrates releasing gaseous HNO3 during dehydration process. These reactions are attributed to acid displacement of nitrate with weak organic acids driven by the evaporation of HNO3 into gas phase due to its relatively high volatility. The reactions result in significant nitrate depletion and formation of organic salts in mixed organic acids/nitrate particles that in turn may affect their physical and chemical properties relevant to atmospheric environment and climate. Airborne nitrate concentrations are estimated by thermodynamic calculations corresponding to various nitrate depletions in selected organic acids of atmospheric relevance. The results indicate a potential mechanism of HNO3 recycling, which may further affect concentrations of gas- and aerosol-phase species in the atmosphere and the heterogeneous reaction chemistry between them.

  18. Dissociation constants of phosphoric acid in dimethylformamide-water mixtures at 298.15 K

    NASA Astrophysics Data System (ADS)

    Safonova, L. P.; Fadeeva, Yu. A.; Pryakhin, A. A.

    2009-10-01

    The dissociation constants of phosphoric acid (p K 1 and p K 2) in water-dimethylformamide (DMFA) mixtures (0-0.65 mole fractions of DMFA) were determined at 298.15 K by potentiometric titration. The extrapolation of these data to pure DMFA and the comparative calculation method were used to estimate the dissociation constants of the acid in DMFA.

  19. ACIDIC EPISODES AND SURFACE WATER CHEMISTRY: A COMPARISON OF NORTHEAST AND SOUTHEAST STUDY SITES

    EPA Science Inventory

    Much of the emphasis in the National Acid Precipitation Assessment Program (NAPAP) has been on historical or longterm trends in surface water acidification. Short-term acidic episodes, however, also might have significant adverse effects on aquatic ecosystems. The U.S. EPA is pre...

  20. Production of acid water in a lead-zinc mine, Coeur d'Alene, Idaho

    NASA Astrophysics Data System (ADS)

    Wai, C. M.; Reece, D. E.; Trexler, B. D.; Ralston, D. R.; Williams, R. E.

    1980-05-01

    The Bunker Hill Mine in Idaho's Coeur d'Alene mining district produces approximately 10 m3/minute of acid water containing high concentrations of heavy metals. Field and laboratory studies indicate that much of the acid water is produced in a single ore body in the upper part of the mine. The ore of this body contains mainly sphalerite, galena, and pyrite in a siderite-quartz gangue. Ground water recharges this ore body through a near-vertical zone of high permeability, which is the result of mining by the caving technique. Ore samples from the caving area contained oxidized forms of iron and produced acid in a laboratory leaching test. Leaching experiments with several ore samples from the mine also indicated that the ratio of pyrite to calcite in the samples strongly controlled the resultant pH values. Oxidation of pyrite to sulfuric acid and compounds of iron is apparently responsible for the production of acid water in the mine. In contrast, dissolution of calcite in water results in a basic solution, with pH around 8.3, that can neutralize the acid produced by the oxidation process. Methods for prevention of acid mine drainage in this and other similar mines are noted.

  1. Physiological effects of sublethal levels of acid water on three species of fishes

    SciTech Connect

    Pegg, W.J.

    1984-01-01

    Static toxicity tests revealed the need to assess the effect of acid mine water using some procedure that would gradually increase the concentration of acidity over a period of time. A relatively long-term (2-5 days) experiment involving the devlopment of a sublethal acid treatment gradient was chosen as potentially being the most representative of natural environments which are periodically subjected to changing inputs from coal mine drainage. Since respiratory change is an indication of physiological stress, the measurement of oxygen consumption rate was chosen as the major variable representing the effect of acid waters on fishes. Bluegill sunfish Lepomes macrochirus Rafinesque, pumpkinseed sunfish, Lepomis gibbosus (Linnaeus), and brown bullhead, Ictalurus nebulosus (LeSueur) were collected from the Monongahela River and backwater areas in the region of Morgantown, West Virginia. The sublethal acid water treatments decreased the oxygen consumption rates for brown bullhead and bluegill sunfish, while increasing the oxygen consumption rate for pumpkinseed sunfish. Further, the rhythms of the oxygen consumption rates were generally modified in both frequency and amplitude as a result of exposure to acid water. Acid water treatments also caused negative phase shifts in oxygen consumption rate for brown bullhead sand bluegill sunfish, while positive phase shifts occurred for pumpkinseed sunfish.

  2. THEOS: The1st Thailand EO System and

    NASA Astrophysics Data System (ADS)

    Peanvijarnpong, Chanchai

    Thailand has engaged in remote sensing satellite technological and scientific development many years since early 1980s. Thailand Landsat Station was established as a regional center of data processing and dissemination for Thai scientists for data applications. Over the years, GISTDA and Thai user community have been gaining technical experience and expertise in satellite data applications around the country such natural resources and environmental management, forest inventory, forest change detections, soil mapping, land-use and land cover mapping, crop type mapping, coastal shrimp farming, flood zone mapping, base mapping, water and drought management. The Government of Thailand realizes that remote sensing satellite technology is an important mechanism for social and economic development of the country. So the 1st Thailand Earth Observation System (THEOS) development program was approved by the Government since 2003. THEOS system is sub-synchronous satellite orbiting around the earth at 822 km. altitude same as SPOT satellites. It carries two imaging instruments; 2-m Panchromatic telescope with 22 km. swath width and 15-m resolution camera with four-multi-spectral band and 90-km swath wide. THEOS is scheduled to launch around March 2008. A number of technological and scientific activities has been implementing for Thailand and international scientific user community. Therefore THEOS is strong endorsement from the Government of Thailand on the value of remote sensing technology. This paper presents Thailand EO activities including THEOS System and its plans.

  3. Toward a complete EOS data and information system

    NASA Technical Reports Server (NTRS)

    Chase, Robert R. P.

    1989-01-01

    Based on NASA EOS data panel analyses, an architectural concept is described in terms of elemental composition, top-level functions, and external and internal interfaces. This concept has been evaluated through the use of realistic user-generated scenarios consistent with existing plans for the 1990s and the Space Station. Developmental approaches for the requisite EOS data and information system are presented and a hybrid methodology for implementing this system is discussed.

  4. ASE Floodwater Classifier Development for EO-1 Hyperion Imagery

    NASA Technical Reports Server (NTRS)

    Ip, Felipe; Dohm, J. M.; Baker, V. R.; Doggett, T.; Davies, A. G.; Castano, B.; Chien, S.; Cichy, B.; Greeley, R.; Sherwood, R.

    2004-01-01

    The objective of this investigation is to develop a prototype floodwater detection algorithm for Hyperion imagery. It will be run autonomously onboard the EO-1 spacecraft under the Autonomous Sciencecraft Experiment (ASE). This effort resulted in the development of two classifiers for floodwater, one of several classifier types that have been developed and will be uploaded to EO-1 in early 2004 in order to detect change related to transient processes such as volcanism, flooding, and ice formation and retreat.

  5. A comparison of neutralization efficiency of chemicals with respect to acidic Kopili River water

    NASA Astrophysics Data System (ADS)

    Kapil, Nibedita; Bhattacharyya, Krishna G.

    2016-02-01

    Among all the renewable sources of energy, hydropower is the most potential source which is economical, non-polluting and eco-friendly. The efficiency of hydropower plant in the long run depends on many factors like water and sediment quality. Erosive and corrosive wear of machine parts like turbine is a complex phenomenon. The problem becomes more acute if the hydroenvironment is acidic in nature. The wear and tear due to corrosion/erosion caused by acid mine drainage (AMD) from coal mines reduces the efficiency and the life of the equipments. In this work, neutralization of the acidic water of the Kopili River, Assam, India was investigated using a number of basic chemicals and quantitatively estimating their effectiveness and actual requirement. The acidic water of the river, used as the cooling water, has been found responsible for damaging the equipments of the Kopili Hydro Electric Power Project (KHEP), Assam/Meghalaya, India by reducing the life of all metallic parts through corrosion. In this work, use is made of a number of basic materials like calcium carbonate, calcium hydroxide, calcium oxide, sodium carbonate, sodium hydroxide, and ammonia to examine their neutralization efficiency with respect to the acidic water and it was found that quick lime or raw lime (CaO) has the highest neutralization capacity. Suggestions have been made for meeting the problem of acidity of the river water.

  6. Water chemical ionization mass spectrometry of aldehydes, ketones esters, and carboxylic acids

    SciTech Connect

    Hawthorne, S.B.; Miller, D.J.

    1986-11-01

    Chemical ionization mass spectrometry (CI) of aliphatic and aromatic carbonyl compounds using water as the reagent gas provides intense pseudomolecular ions and class-specific fragmentation patterns that can be used to identify aliphatic aldehydes, ketones, carboxylic acids, and esters. The length of ester acyl and alkyl groups can easily be determined on the basis of loss of alcohols from the protonated parent. Water CI provides for an approximately 200:1 selectivity of carbonyl species over alkanes. No reagent ions are detected above 55 amu, allowing species as small as acetone, propanal, acetic acid, and methyl formate to be identified. When deuterate water was used as the reagent, only the carboxylic acids and ..beta..-diketones showed significant H/D exchange. The use of water CI to identify carbonyl compounds in a wastewater from the supercritical water extraction of lignite coal, in lemon oil, and in whiskey volatiles is discussed.

  7. Strategising for the future Indian EO programme

    NASA Astrophysics Data System (ADS)

    Rao, Mukund; Jayaraman, V.; Kalyanraman, S.; Joseph, George; Navalgund, R. R.; Kasturirangan, K.

    2002-07-01

    The Indian Earth Observations Program, over the past three decades, has been mainly driven by the national need of natural resources management, infrastructure development, environment monitoring and disaster management support. With an array of seven Indian Remote Sensing Satellites (IRS), national development support has been supported, through a well-knit institutional framework of a National Natural Resources Management System (NNRMS), a wide variety of applications developed as an inter-agency effort over the past 20 years. Now, the capacity of the programme has been extended into the global arena and IRS is providing operational data services to the global user community. The future Earth Observation Systems will have to take into consideration the aspects related to the commercialisation and standardisation of programmes world-over; transitioning into a business environment; data continuity and the need to monitor processes rather than events. Technological changes are also going to re-define many of the concepts of observation from space and issues like spatial resolution, spectral resolution and temporal resolution may no more be a concern for observation systems. ISRO is presently defining a strategy for the Indian EO Programme that will chart the progress with a vision for the next 25 years. Based on a thorough analysis, the observation needs of the future are planned and presently systems design and implementation are underway. The Need Analysis has been done keeping in mind the Global change applications; Mapping and Cartographic applications; Natural Resources and Environmental management applications etc. Issues related to defining the space and data acquisition as a national "public good", costing of data products and services and evolving a commercial remote sensing policy have been addressed for providing the overall thrust of the Indian Earth Observations program. The paper discusses the strategy adopted for assessing the future user requirements

  8. PHOTOLYSIS OF COPPER(II)-AMINO ACID COMPLEXES IN WATER

    EPA Science Inventory

    Kinetics of the photolysis of Cu2+-amino acid complexes were investigated under sunlight or monochromatic radiation. nder sunlight (latitude 40 degrees N) in the absence of dioxygen, the mean half-lives estimated for the photoreduction of the bis-Cu2+ complexes (CuL2) at pH 8.0 a...

  9. Fulvic Acid Mediated Photolysis of Ibuprofen in Water.

    EPA Science Inventory

    Photolysis of the nonsteroidal anti-inflammatory drug ibuprofen was studied in solutions of fulvic acid (FA) isolated from Pony Lake, Antarctica; Suwannee River, GA, USA; and Old Woman Creek, OH, USA. At an initial concentration of 10 µM ibuprofen degrades by direct photolysis...

  10. Advanced water-cooled phosphoric acid fuel cell development

    SciTech Connect

    Not Available

    1990-01-01

    Fabrication of repeat parts for the small area short stack is nearing completion and assembly activities are being initiated. Electrolyte reservoir plates (ERPs) were completed and processed into integral separator plates, and acid fill of parts was initiated. Fabrication of electrodes was also completed, including catalyzation and applications of seals and matrices.

  11. Use of O and S Isotopes to Define Sources of Water and Sulfate in Acid Mine Drainage Waters

    NASA Astrophysics Data System (ADS)

    Earnest, D.

    2001-12-01

    Coal mining in Maryland, West Virginia, Pennsylvania, and other states has resulted in acid mine drainage problems in rivers throughout the region. The underground workings at the Kempton Mine have been abandoned since the 1950's, and the water filling these mines is discharged at a rate of 6,000,000 gallons per day into the headwaters of the Potomac River. This water has an average pH of 3.0 and an average dissolved load of 1 g/L. Evaluation of the mitigation options requires identification of water and acidity sources. We are using isotopic compositions of mine drainage waters to define hydrologic sources, flow paths, and acid sources. Water samples were taken monthly of mine water and other local sources. Oxygen isotope analyses are conducted on these samples. Seasonal variations in δ ^{18}O composition of mine drainage would suggest significant rapid meteoric input. Little or no variation in \\delta18O composition would suggest that mine drainage is derived primarily from groundwater sources or that the residence time in the mine is long. Sulfate precipitated as barite from these samples is analyzed for δ ^{34}S and \\delta18O. There is significantly more sulfate in the mine drainage waters than there is iron. The isotopic signature is used to determine whether the sulfur source is pyritic or organic. Sulfate δ 18O data are used to distinguish between sub-aerial and sub-aqueous oxidation of sulfur.

  12. Development of anti-scale poly(aspartic acid-citric acid) dual polymer systems for water treatment.

    PubMed

    Nayunigari, Mithil Kumar; Gupta, Sanjay Kumar; Kokkarachedu, Varaprasad; Kanny, K; Bux, F

    2014-01-01

    The formation of calcium sulphate and calcium carbonate scale poses major problems in heat exchangers and water cooling systems, thereby affecting the performance of these types of equipment. In order to inhibit these scale formations, new types of biodegradable water soluble single polymer and dual poly(aspartic acid-citric acid) polymers were developed and tested. The effectiveness of single polymer and four different compositions of poly aspartic acid and citric acid dual polymer systems as scale inhibitors were evaluated. Details of the synthesis, thermal stability, scale inhibition and the morphological characterization of single and dual polymers are presented in this scientific paper. It was found that the calcium sulphate scale inhibition rate was in the range 76.06-91.45%, while the calcium carbonate scale inhibition rate observed was in the range 23.37-30.0% at 65-70 °C. The finding suggests that the water soluble dual polymers are very effective in sulphate scale inhibition in comparison of calcium carbonate scale inhibition. PMID:25189837

  13. Rare earth element partitioning between hydrous ferric oxides and acid mine water during iron oxidation

    USGS Publications Warehouse

    Verplanck, P.L.; Nordstrom, D.K.; Taylor, H.E.; Kimball, B.A.

    2004-01-01

    Ferrous iron rapidly oxidizes to Fe (III) and precipitates as hydrous Fe (III) oxides in acid mine waters. This study examines the effect of Fe precipitation on the rare earth element (REE) geochemistry of acid mine waters to determine the pH range over which REEs behave conservatively and the range over which attenuation and fractionation occur. Two field studies were designed to investigate REE attenuation during Fe oxidation in acidic, alpine surface waters. To complement these field studies, a suite of six acid mine waters with a pH range from 1.6 to 6.1 were collected and allowed to oxidize in the laboratory at ambient conditions to determine the partitioning of REEs during Fe oxidation and precipitation. Results from field experiments document that even with substantial Fe oxidation, the REEs remain dissolved in acid, sulfate waters with pH below 5.1. Between pH 5.1 and 6.6 the REEs partitioned to the solid phases in the water column, and heavy REEs were preferentially removed compared to light REEs. Laboratory experiments corroborated field data with the most solid-phase partitioning occurring in the waters with the highest pH. ?? 2004 Elsevier Ltd. All rights reserved.

  14. Field and Laboratory Studies of Reactions between Atmospheric Water Soluble Organic Acids and Inorganic Particles

    SciTech Connect

    Wang, Bingbing; Kelly, Stephen T.; Sellon, Rachel E.; Shilling, John E.; Tivanski, Alexei V.; Moffet, Ryan C.; Gilles, Mary K.; Laskin, Alexander

    2013-06-25

    Atmospheric inorganic particles undergo complex heterogeneous reactions that change their physicochemical properties. Depletion of chloride in sea salt particles was reported in previous field studies and was attributed to the acid displacement of chlorides with inorganic acids, such as nitric and sulfuric acids [1-2]. Recently, we showed that NaCl can react with water soluble organic acids (WSOA) and release gaseous hydrochloric acid (HCl) resulting in formation of organic salts [3]. A similar mechanism is also applicable to mixed WSOA/nitrate particles where multi-phase reactions are driven by the volatility of nitric acid. Furthermore, secondary organic material, which is a complex mixture of carboxylic acids, exhibits the same reactivity towards chlorides and nitrates. Here, we present a systematic study of reactions between atmospheric relevant WSOA, SOM, and inorganic salts including NaCl, NaNO3, and Ca(NO3)2 using complementary micro-spectroscopy analysis.

  15. Chemical dynamics of acidity and heavy metals in a mine water-polluted soil during decontamination using clean water.

    PubMed

    Chen, A; Lin, C; Lu, W; Ma, Y; Bai, Y; Chen, H; Li, J

    2010-03-15

    A column leaching experiment was conducted to investigate the chemical dynamics of the percolating water and washed soil during decontamination of an acidic mine water-polluted soil. The results show that leaching of the contaminated soil with clean water rapidly reduced soluble acidity and ion concentrations in the soils. However, only <20% of the total actual acidity in the soil column was eliminated after 30 leaching cycles. It is likely that the stored acidity continues to be released to the percolating water over a long period of time. During the column leaching, dissolved Cu and Pb were rapidly leached out, followed by mobilization of colloidal Cu and Pb from the exchangeable and the oxide-bound fractions as a result of reduced ionic strength in the soil solution. The soluble Fe contained in the soil was rare, probably because the soil pH was not sufficiently low; marked mobility of colloidal Fe took place after the ionic strength of the percolating water was weakened and the mobilized Fe was mainly derived from iron oxides. In contrast with Cu, Pb and Fe, the concentration of leachate Zn and Mn showed a continuously decreasing trend during the entire period of the experiment. PMID:19913356

  16. General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2.

    PubMed

    Hu, Peng; Ben-David, Yehoshoa; Milstein, David

    2016-05-18

    An atom-economical and environmentally friendly method to transform amino alcohols to amino acid salts using just basic water, without the need of pre-protection or added oxidant, catalyzed by a ruthenium pincer complex, is developed. Water is the solvent, the source of the oxygen atom of the carboxylic acid group, and the actual oxidant, with liberation of dihydrogen. Many important and useful natural and unnatural amino acid salts can be produced in excellent yields by applying this new method. PMID:27139983

  17. NASA's Earth Observing System (EOS): Observing the Atmosphere, Land, Oceans, and Ice from Space

    NASA Technical Reports Server (NTRS)

    King, Michael D.

    2005-01-01

    The Earth Observing System (EOS) is a space-based observing system comprised of a series of satellite sensors by whch scientists can monitor the Earth, a Data and Information System (EOSDIS) enabling researchers worldwide to access the satellite data, and an interdisciplinary science research program to interpret the satellite data. During this year, the last of the first series of EOS missions, Aura, was launched. Aura is designed exclusively to conduct research on the composition, chemistry, and dynamics of the Earth's upper and lower atmosphere, employing multiple instruments on a single spacecraft. Aura is the third in a series of major Earth observing satellites to study the environment and climate change and is part of NASA's Earth Science Enterprise. The first and second missions, Terra and Aqua, are designed to study the land, oceans, atmospheric constituents (aerosols, clouds, temperature, and water vapor), and the Earth's radiation budget. The other seven EOS spacecraft include satellites to study (i) land cover & land use change, (ii) solar irradiance and solar spectral variation, (iii) ice volume, (iv) ocean processes (vector wind and sea surface topography), and (v) vertical variations of clouds, water vapor, and aerosols up to and including the stratosphere. Aura's chemistry measurements will also follow up on measurements that began with NASA's Upper Atmosphere Research Satellite and continue the record of satellite ozone data collected from the TOMS missions. In this presentation I will describe how scientists are using EOS data to examine the health of the earth's atmosphere, including atmospheric chemistry, aerosol properties, and cloud properties, with a special look at the latest earth observing mission, Aura.

  18. NASA's Earth Observing System (EOS): Observing the Atmosphere, Land, Oceans, and Ice from Space

    NASA Technical Reports Server (NTRS)

    King, Michael D.

    2004-01-01

    The Earth Observing System (EOS) is a space-based observing system comprised of a series of satellite sensors by which scientists can monitor the Earth, a Data and Information System (EOSDIS) enabling researchers worldwide to access the satellite data, and an interdisciplinary science research program to interpret the satellite data. During this year, the last of the first series of EOS missions, Aura, was launched. Aura is designed exclusively to conduct research on the composition, chemistry, and dynamics of the Earth's upper and lower atmosphere, employing multiple instruments on a single spacecraft. Aura is the third in a series of major Earth observing satellites to study the environment and climate change and is part of NASA's Earth Science Enterprise. The first and second missions, Terra and Aqua, are designed to study the land, oceans, atmospheric constituents (aerosols, clouds, temperature, and water vapor), and the Earth's radiation budget. The other seven EOS spacecraft include satellites to study (i) land cover & land use change, (ii) solar irradiance and solar spectral variation, (iii) ice volume, (iv) ocean processes (vector wind and sea surface topography), and (v) vertical variations of clouds, water vapor, and aerosols up to and including the stratosphere. Aura's chemistry measurements will also follow up on measurements that began with NASA's Upper Atmosphere Research Satellite and continue the record of satellite ozone data collected from the TOMS missions. In this presentation I will describe how scientists are using EOS data to examine the health of the earth's atmosphere, including atmospheric chemistry, aerosol properties, and cloud properties, with a special but not exclusive look at the latest earth observing mission, Aura.

  19. Potential health implications for acid precipitation, corrosion, and metals contamination of drinking water.

    PubMed Central

    Sharpe, W E; DeWalle, D R

    1985-01-01

    Potential health effects of drinking water quality changes caused by acid precipitation are presented. Several different types of water supply are discussed and their roles in modifying acid rain impacts on drinking water are explained. Sources of metals contamination in surface water supplies are enumerated. The authors present some results from their research into acid rain impacts on roof-catchment cisterns, small surface water supplies, and lead mobilization in acid soils. A good correlation was obtained between cistern water corrosivity as measured by the Ryznar Index (RI) values and standing tapwater copper concentrations. However, lead concentrations in tapwater did not correlate well with cistern water RI. A modified linear regression model that accounted for Ryznar Index change during storage in vinyl-lined cisterns was used to predict the Ryznar Index value at a copper concentration of 1000 micrograms/L. The predicted RI was greater than the RI of precipitation with a pH of 5.3, indicating that anthropogenically acidified precipitation may result in cistern tapwater copper concentrations in excess of the 1000 micrograms/L suggested drinking water limit. Good correlations between tapwater Ryznar Index and tapwater copper and lead concentrations were not obtained for the small surface water supply. Aluminum concentrations in reservoir water were similar to those in stream source water. Limited data were also presented that indicated lead was present in acid forest soil leachate and streams draining such soils in relatively small concentrations. Where appropriate, recommendations for future research are included with the discussions of research results. PMID:4076096

  20. Radiation modification of water absorption of cassava starch by acrylic acid/acrylamide

    NASA Astrophysics Data System (ADS)

    Kiatkamjornwong, Suda; Chomsaksakul, Wararuk; Sonsuk, Manit

    2000-10-01

    Graft copolymerizations of acrylamide and/or acrylic acid onto cassava starch by a simultaneous irradiation technique using gamma-rays as the initiator were studied with regard to various parameters of importance: the monomer-to-cassava starch ratio, total dose (kGy), dose rate (kGy h -1), acrylamide-to-acrylic acid ratio, and the addition of nitric acid and maleic acid as the additives. Grafting parameters were determined in relation to the water absorption of the saponified graft copolymer. The water absorption of the saponified graft copolymer in salt and buffer solutions of different ionic strengths was also measured, from which the superabsorbent properties are found to be pH sensitive. The starch graft copolymers of acrylamide and acrylic acid give higher water absorption than the starch graft copolymers of either acrylamide or acrylic acid alone. The porosity of the saponified starch graft copolymers prepared by the acrylamide/acrylic acid ratios of 70:30 and 50:50 was much higher than the porosity of copolymers in terms of fine networks. Ionic strength and multi-oxidation states of the saline and buffer solutions markedly decreased the water absorption of the saponified cassava starch grafted superabsorbent polymers.

  1. TECHNIQUES AND METHODS FOR THE DETERMINATION OF HALOACETIC ACIDS IN POTABLE WATER

    EPA Science Inventory

    Haloethanoic (haloacetic) acids (HAAs) are formed as disinfection byproducts (DBPs) during the chlorination of natural water to make it fit for consumption. Sundry analytical techniques have been applied in order to determine the concentrations of the HAAs in potable water suppli...

  2. Numbers of bacteria recovered from broiler carcasses and chiller water treated with hypochlorous and carbonic acids

    Technology Transfer Automated Retrieval System (TEKTRAN)

    A study was conducted to determine the effects of treating poultry chiller water with a mixture of hypochlorous and carbonic acids. Broiler carcasses and chiller water were obtained from a commercial processing facility which had recently installed a TOMCO Pathogen Management SystemJ to recycle wat...

  3. MUTAGENICITY AND DISINFECTION BY-PRODUCTS IN SURFACE DRINKING WATER DISINFECTED WITH PERACETIC ACID

    EPA Science Inventory

    The aims of this research were to study the influence of peracetic acid (PAA) on the formation of mutagens in surface waters used for human consumption and to assess its potential application for the disinfection of drinking water. The results obtained using PAA were compared to ...

  4. The mechanism of hydrothermal hydrolysis for glycyrrhizic acid into glycyrrhetinic acid and glycyrrhetinic acid 3-O-mono-β-D-glucuronide in subcritical water.

    PubMed

    Fan, Rui; Li, Nan; Xu, Honggao; Xiang, Jun; Wang, Lei; Gao, Yanxiang

    2016-01-01

    To improve the bioactivity and sweetness properties of glycyrrhizic acid (GL), the hydrothermal hydrolysis of GL into glycyrrhetinic acid (GA) and glycyrrhetinic acid 3-O-mono-β-D-glucuronide (GAMG) in subcritical water was investigated. The effects of temperature, time and their interaction on the conversion ratios were analyzed and the reactions were elaborated with kinetics and thermodynamics. The results showed that GL hydrothermal hydrolysis was significantly (P < 0.05) affected by reaction time and temperature, as well as their interaction, and could be fitted into first-order kinetics. The thermodynamic analysis indicated that the hydrolysis of GL was endergonic and non-spontaneous. The hydrolytic pathways were composed of complex consecutive and parallel reactions. It was concluded that subcritical water may be a potential medium for producing GAMG and GA. PMID:26213056

  5. Process for removal of ammonia and acid gases from contaminated waters

    DOEpatents

    King, C.J.; Mackenzie, P.D.

    1982-09-03

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  6. Process for removal of ammonia and acid gases from contaminated waters

    DOEpatents

    King, C. Judson; MacKenzie, Patricia D.

    1985-01-01

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  7. Influence of Sodium Carbonate on Decomposition of Formic Acid by Discharge inside Bubble in Water

    NASA Astrophysics Data System (ADS)

    Iwabuchi, Masashi; Takahashi, Katsuyuki; Takaki, Koichi; Satta, Naoya

    2015-09-01

    An influence of sodium carbonate on decomposition of formic acid by discharge inside bubble in water was investigated. Oxygen or argon gases were injected into the water through a vertically positioned glass tube, in which the high-voltage wire electrode was placed to generate plasmas at low applied voltage. The concentration of formic acid was determined by ion chromatography. In the case of addition of sodium carbonate, the pH value increased with decomposition of the formic acid. In the case of oxygen injection, the increase of pH value contributed to improve an efficiency of the formic acid decomposition because the reaction rate of ozone and formic acid increased with increasing pH value. In the case of argon injection, the decomposition rate was not affected by the pH value owing to the high rate constants for loss of hydroxyl radicals.

  8. Water-dispersible ascorbic-acid-coated magnetite nanoparticles for contrast enhancement in MRI

    NASA Astrophysics Data System (ADS)

    Sreeja, V.; Jayaprabha, K. N.; Joy, P. A.

    2015-04-01

    Superparamagnetic iron oxide nanoparticles of size ~5 nm surface functionalized with ascorbic acid (vitamin C) form a stable dispersion in water with a hydrodynamic size of ~30 nm. The anti-oxidant property of ascorbic acid is retained after capping, as evidenced from the capability of converting methylene blue to its reduced leuco form. NMR relaxivity studies show that the ascorbic-acid-coated superparamagnetic iron oxide aqueous nanofluid is suitable as a contrast enhancement agent for MRI applications, coupled with the excellent biocompatibility and medicinal values of ascorbic acid.

  9. Structure of bound water and refinement of acid metmyoglobin

    SciTech Connect

    Raghaven, N.V.; Schoenborn, B.P.

    1982-06-01

    The structure of myoglobin has been determined by x-ray diffraction for the acidmet, deoxy, and the oxy forms. Neutron diffraction work, done in this laboratory, has demonstrated that hydrogen and deuterium positions can be located. In addition to the localization of H and D, neutron diffraction provides a unique method for studying the water structure because of the strong scattering ability of D/sub 2/O. The scattering factor of deuterium is nearly twice as large as that of hydrogen, and it increases the visibility of water molecules in Fourier maps, so that in a neutron map a water molecule appears about three times as strong as in an equivalent electron-density map. (DT)

  10. Phase diagrams and water activities of aqueous ammonium salts of malonic acid.

    PubMed

    Beyer, Keith D; Richardson, Michael; Reusch, Breanna

    2011-04-14

    Malonic acid has been observed in the free troposphere and as a component of tropospheric aerosol, among other dicarboxylic acids. These aerosols can uptake ammonia, which partially or completely neutralizes the acids. Therefore, the impact of ammoniated dicarboxylic acids on the phases that can exist in aerosols at atmospheric temperatures needs investigation. To that end, the low temperature, solid/liquid phase diagrams of ammonium hydrogen malonate/water, ammonium malonate/water, and triammonium hydrogen malonate/water have been investigated with differential scanning calorimetry and infrared spectroscopy of thin films. Results show that the order of increasing solubility is triammonium hydrogen malonate, ammonium hydrogen malonate, malonic acid, and ammonium malonate. We have also determined a hydrate may form in the ammonium malonate system and decompose below 240 K. We report water activities at the ice melting points for each system up to the respective eutectic concentrations, and find for a given mole fraction of water, increasing ammonium content leads to decreasing water activity coefficients. PMID:21428389

  11. State of water in perfluorosulfonic acid membranes studied by microwave dielectric relaxation spectroscopy

    NASA Astrophysics Data System (ADS)

    Lu, Zijie

    The physical state of water in perfluosulfonic acid membranes (e.g., Nafion 117 and Flemion SH150) has been studied by the water sorption isotherms, DSC, 2H NMR, and microwave dielectric relaxation spectroscopy. Different water states have been discriminated in these membranes: (1) the first few water molecules upon absorption from water vapor (lambda ˜ 3, where lambda denotes the number of water molecules per sulfonic acid group) are tightly bound to the sulfonic acid group to form the first hydration water; (2) beyond this water content, water molecules form the second hydration layer of the sulfonic acid group. The amount of this water increases with water content, but reaches a constant value at higher water contents. The microwave DRS measurements showed a relaxation time of about 30 ps for this type of water; (3) the free water, locating at the center of the ion cluster regions where the ion-water interaction is negligible, is present when lambda ≥ 6. The free water, with relaxation time tau ≈ 8 ps at 25°C, shows the characteristic dynamics of bulk water; and (4) finally, as water content increases further, water molecules start to be associated with the perfluorinated side chains and even with the fluorocarbon backbone. A much longer relaxation time, tau ≈ 90 ps, is observed for this part of water due to the hydrophobic confinement by the polymer. Microwave DRS measurements showed markedly different dynamics, i.e., negligible activation enthalpy and large negative activation entropy, for the dielectric relaxation of this type of water. The presence of the hydrophobically confined water is found to correspond to the clustering of water and to the appearance of the freezing water in these membranes. The equivalent weight (EW) of the PSA membrane has been found to have considerable influence on the dielectric response of the membranes. Flemion SH150, which has an EW value of 909, shows higher static permittivity than Nafion 117, which has an EW of 1100

  12. Formation of Carbonic Acid in Impact of CO2 on Ice and Water.

    PubMed

    Hirshberg, Barak; Gerber, R Benny

    2016-08-01

    A new mode of formation is proposed for carbonic acid in the atmosphere. It involves impact of vibrationally excited gas-phase CO2 molecules on water or ice particles. This is a first mechanism that supports formation on ice as well as on liquid water surfaces. Results of ab initio molecular dynamics simulations are presented on collisions of CO2 with (H2O)n clusters (n = 1, 4, 8, 12). Efficient formation of carbonic acid is seen with product lifetimes exceeding 100 ps. The reaction is feasible even for collision of CO2 with a single water molecule but in a different mechanism than for larger clusters. For clusters, the transition state shows charge separation into H3O(+)···HCO3(-), which transforms into neutral carbonic acid as the product, hydrated by the remaining waters. Possible atmospheric implications of the results are discussed. PMID:27420400

  13. Short chain aliphatic acid anions in oil field waters and their contribution to the measured alkalinity

    USGS Publications Warehouse

    Willey, L.M.; Kharaka, Y.K.; Presser, T.S.; Rapp, J.B.; Barnes, I.

    1975-01-01

    High alkalinity values found in some formation waters from Kettleman North Dome oil field are due chiefly to acetate and propionate ions, with some contribution from higher molecular weight organic acid ions. Some of these waters contain no detectable bicarbonate alkalinity. For waters such as these, high supersaturation with respect to calcite will be incorrectly indicated by thermodynamic calculations based upon carbonate concentrations inferred from traditional alkalinity measurements. ?? 1975.

  14. EOS Reference Handbook 1999: A Guide to NASA's Earth Science Enterprise and the Earth Observing System

    NASA Technical Reports Server (NTRS)

    King, M. D. (Editor); Greenstone, R. (Editor)

    2000-01-01

    The content of this handbook includes Earth Science Enterprise; The Earth Observing System; EOS Data and Information System (EOSDIS); Data and Information Policy; Pathfinder Data Sets; Earth Science Information Partners and the Working Prototype-Federation; EOS Data Quality: Calibration and Validation; Education Programs; International Cooperation; Interagency Coordination; Mission Elements; EOS Instruments; EOS Interdisciplinary Science Investigations; and Points-of-Contact.

  15. The effect of acid drinking water on rumen protozoa in the blesbok (Damaliscus dorcas phillipsi).

    PubMed

    Booyse, D G; Dehority, B A; Myburgh, J G

    2015-01-01

    Rumen contents were collected from ten adult female blesbok, five from a mine area with only acid drinking water available and five from a control group consuming normal, non-polluted drinking water. The mean concentration of total protozoa in the normal water group was almost double that in the acid drinking water group, 24.9 x 10(3) versus 14.7 x 10(3). Percent of Entodinium was higher and Diplodinium lower in those animals drinking the acid water. The number of different protozoa species present in animals from both locations was fairly similar. Diplodinium bubalidis, Ostracodinium gracile and Diplodinium consors were present in the highest percentage in the normal water group, 18.8, 18.4 and 17.7 %, respectively. The same three species, plus Entodinium dubardi, were also highest in the acid water group, O. gracile, 21.3 %; D. consors, 12.6 %; E. dubardi, 11.4 % and D. bubalidis, 10.3 %. Seventeen species of protozoa found in this study were a new host record for the blesbok, bringing the total number of species reported from the blesbok to 29. PMID:26701455

  16. Development of a method for environmentally friendly chemical peptide synthesis in water using water-dispersible amino acid nanoparticles

    PubMed Central

    2011-01-01

    Due to the vast importance of peptides in biological processes, there is an escalating need for synthetic peptides to be used in a wide variety of applications. However, the consumption of organic solvent is extremely large in chemical peptide syntheses because of the multiple condensation steps in organic solvents. That is, the current synthesis method is not environmentally friendly. From the viewpoint of green sustainable chemistry, we focused on developing an organic solvent-free synthetic method using water, an environmentally friendly solvent. Here we described in-water synthesis technology using water-dispersible protected amino acids. PMID:21867548

  17. Determination of water-soluble forms of oxalic and formic acids in soils by ion chromatography

    NASA Astrophysics Data System (ADS)

    Karicheva, E.; Guseva, N.; Kambalina, M.

    2016-03-01

    Carboxylic acids (CA) play an important role in the chemical composition origin of soils and migration of elements. The content of these acids and their salts is one of the important characteristics for agrochemical, ecological, ameliorative and hygienic assessment of soils. The aim of the article is to determine water-soluble forms of same carboxylic acids — (oxalic and formic acids) in soils by ion chromatography with gradient elution. For the separation and determination of water-soluble carboxylic acids we used reagent-free gradient elution ion-exchange chromatography ICS-2000 (Dionex, USA), the model solutions of oxalate and formate ions, and leachates from soils of the Kola Peninsula. The optimal gradient program was established for separation and detection of oxalate and formate ions in water solutions by ion chromatography. A stability indicating method was developed for the simultaneous determination of water-soluble organic acids in soils. The method has shown high detection limits such as 0.03 mg/L for oxalate ion and 0.02 mg/L for formate ion. High signal reproducibility was achieved in wide range of intensities which correspond to the following ion concentrations: from 0.04 mg/g to 10 mg/L (formate), from 0.1 mg/g to 25 mg/L (oxalate). The concentration of formate and oxalate ions in soil samples is from 0.04 to 0.9 mg/L and 0.45 to 17 mg/L respectively.

  18. EOS-WEBSTER - Providing Satellite Imagery for Everyone

    NASA Astrophysics Data System (ADS)

    Schloss, A. L.; Moore, B.; Braswell, R.; Hurtt, G.; Armstrong, W.; Blaha, D.; Carmell, T.; Freuder, R.; Routhier, M.; Spencer, S.

    2002-12-01

    The University of New Hampshire's WEB-based System for Terrestrial Ecosystem Research (EOS-WEBSTER) distributes a special collection of data and imagery products for the Earth Science community. This collection includes satellite imagery from several sensors including the MODIS instrument aboard TERRA. Our services have been designed so that different types of users can access and use only the data that they want. Users can search EOS-WEBSTER's collections, create spatial and temporal subsets, and order data in ASCII or binary formats. We have developed a suite of MODIS products covering Amazonia. These products serve the Large Scale Biosphere-Atmosphere Project in Amazonia (LBA), a joint project of the Brazilian government and NASA. Products include 8-day reflectances (MOD09A1), daily fire potential (MOD14A1), and 16-day NDVIs (MOD13Q1), starting in January 2001. EOS-WEBSTER takes care of obtaining the 14 MODIS tiles that cover Amazonia and stitching them together into a seamless regional coverage. Users can cookie-cut the regional data into smaller areas of interest, such as a field site, a political boundary, or a watershed, then choose an output format such as GrADS and retrieve their order by ftp or on CD-ROM. EOS-WEBSTER delivers MODIS to users whether or not they can manipulate the HDF-EOS format. These regional data sets were developed in cooperation with Eros Data Center to facilitate use of MODIS products by the LBA community. Other products and regions can be developed for other user communities if there is enough interest. Please contact us at support@eos-webster.sr.unh.edu for more information. MODIS is only one of a variety of imagery products available from EOS-WEBSTER. Other platforms include Landsat, SPOT-VEGETATION and IKONOS. We provide Landsat imagery data access to educators by supporting the Forest Watch program, an educational project that includes K-12 teachers and students in UNH research activities that assess the state-of-health of local

  19. Characterization of water reservoirs affected by acid mine drainage: geochemical, mineralogical, and biological (diatoms) properties of the water.

    PubMed

    Valente, T; Rivera, M J; Almeida, S F P; Delgado, C; Gomes, P; Grande, J A; de la Torre, M L; Santisteban, M

    2016-04-01

    This work presents a combination of geochemical, mineralogical, and biological data obtained in water reservoirs located in one of the most paradigmatic mining regions, suffering from acid mine drainage (AMD) problems: the Iberian Pyrite Belt (IPB). Four water reservoirs located in the Spanish sector of the IBP, storing water for different purposes, were selected to achieve an environmental classification based on the effects of AMD: two mining dams (Gossan and Águas Ácidas), a reservoir for industrial use (Sancho), and one with water used for human supply (Andévalo). The results indicated that the four reservoirs are subject to the effect of metallic loads from polluted rivers, although with different levels: Águas Ácidas > Gossan > Sancho ≥ Andévalo. In accordance, epipsammic diatom communities have differences in the respective composition and dominant taxa. The dominant diatoms in each reservoir indicated acid water: Pinnularia acidophila and Pinnularia aljustrelica were found in the most acidic dams (Gossan and Águas Ácidas, with pH <3), Pinnularia subcapitata in Sancho (pH 2.48-5.82), and Eunotia exigua in Andévalo (pH 2.34-6.15). PMID:26032451

  20. Electrocatalytic hydrogen evolution in acidic water with molecular cobalt tetraazamacrocycles.

    PubMed

    McCrory, Charles C L; Uyeda, Christopher; Peters, Jonas C

    2012-02-15

    A series of water-soluble molecular cobalt complexes of tetraazamacrocyclic ligands are reported for the electrocatalytic production of H(2) from pH 2.2 aqueous solutions. The comparative data reported for this family of complexes shed light on their relative efficiencies for hydrogen evolution in water. Rotating disk electrode voltammetry data are presented for each of the complexes discussed, as are data concerning their respective pH-dependent electrocatalytic activity. In particular, two diimine-dioxime complexes were identified as exhibiting catalytic onset at comparatively low overpotentials relative to other reported homogeneous cobalt and nickel electrocatalysts in aqueous solution. These complexes are stable at pH 2.2 and produce hydrogen with high Faradaic efficiency in bulk electrolysis experiments over time intervals ranging from 2 to 24 h. PMID:22280515

  1. Steroidal aromatic 'naphthenic acids' in oil sands process-affected water: structural comparisons with environmental estrogens.

    PubMed

    Rowland, Steven J; West, Charles E; Jones, David; Scarlett, Alan G; Frank, Richard A; Hewitt, L Mark

    2011-11-15

    The large volumes, acute toxicity, estrogenicity, and antiandrogenicity of process-affected waters accruing in tailings ponds from the operations of the Alberta oil sands industries pose a significant task for environmental reclamation. Synchronous fluorescence spectra (SFS) suggest that oil sands process-affected water (OSPW) may contain aromatic carboxylic acids, which are among the potentially environmentally important toxicants, but no such acids have yet been identified, limiting interpretations of the results of estrogenicity and other assays. Here we show that multidimensional comprehensive gas chromatography-mass spectrometry (GCxGC-MS) of methyl esters of acids in an OSPW sample produces mass spectra consistent with their assignment as C(19) and C(20) C-ring monoaromatic hydroxy steroid acids, D-ring opened hydroxy and nonhydroxy polyhydrophenanthroic acids with one aromatic and two alicyclic rings and A-ring opened steroidal keto acids. High resolution MS data support the assignment of several of the so-called 'O3' species. When fractions of distilled, esterified, OSPW acid-extractable organics were examined, the putative aromatics were mainly present in a high boiling fraction; when examined by argentation thin layer chromatography, some were present in a fraction with a retardation factor between that of the methyl esters of synthetic monoalicyclic and monoaromatic acids. Ultraviolet absorption spectra of these fractions indicated the presence of benzenoid moieties. SFS of model octahydro- and tetrahydrophenanthroic acids produced emissions at the characteristic excitation wavelengths observed in some OSPW extracts, consistent with the postulations from ultraviolet spectroscopy and mass spectrometry data. We suggest the acids originate from extensive biodegradation of C-ring monoaromatic steroid hydrocarbons and offer a means of differentiating residues at different biodegradation stages in tailings ponds. Structural similarities with estrone and

  2. Evaluation of the Goulden Large-Sample Extractor for acidic compounds in natural waters

    SciTech Connect

    Headley, J.V.; Dickson, L.C.; Swyngedouw, C.; Crosley, B.; Whitley, G.

    1996-11-01

    The Goulden Large-Sample Extractor has received extensive use for monitoring and surveillance surveys of natural waters impacted by pulp and paper mills and agricultural runoff water. However, there are concerns about whether this sampler, which was originally developed for extractions of hydrophobic polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and other organochlorines, is suitable for sampling polar acidic compounds. The sampler was evaluated for recovery of surrogates for resin acids, fatty acids, herbicide acids, and chlorophenols from natural waters. Performance tests conducted in this work indicated that three surrogate compounds with K{sub p} (C{sub DCM}/C{sub water pH 2}) values from 16,700 to 1,260 were extracted from pH 2-adjusted 20-L water samples with an average recovery of 83.6%. The surrogate compounds with K{sub p} values less than 1,000 were extracted with significantly lower recoveries. The variability ranged from 10 to 36% relative standard deviation. Specific performance criteria (percent recoveries {+-} standard deviation, number of determinations in parentheses) observed for the surrogates 2,4,6-tribromophenol, heptadecanoic acid, O-methylpodocarpic acid, dichlorophenylacetic acid, and 4-bromophenol were 89.5 {+-} 24.0 (17), 82.8 {+-} 21.7 (18), 78.4 {+-} 14.8 (18), 41.9 {+-} 8.5 (16), and 22.1 {+-} 8.1 (19), respectively. Low recoveries of the 4-bromophenol surrogate may be due in part to side reactions with diazomethane. As a result, 4-bromophenol is not recommended as a surrogate. These values can be used to provide guidelines for acceptable surrogate recoveries and validation of extractions of polar acidic compounds.

  3. Insights on How NASA's Earth Observing System (EOS) Monitors Our World Environment

    NASA Technical Reports Server (NTRS)

    King, Michael D.

    2000-01-01

    The Earth Observing System (EOS) is a space-based observing system comprised of a series of satellite sensors by which scientists can monitor the Earth, a Data and Information System (EOSDIS) enabling researchers worldwide to access the satellite data, and an interdisciplinary science research program to interpret the satellite data. During this year, four EOS science missions were launched, representing observations of (1) total solar irradiance, (2) Earth radiation budget, (3) land cover and land use change, (4) ocean processes (vector wind, sea surface temperature, and ocean color), (5) atmospheric processes (aerosol and cloud properties, water vapor, and temperature and moisture profiles), and (6) tropospheric chemistry. In succeeding years many more satellites will be launched that will contribute immeasurably to our understanding of the Earth's environment. In this presentation I will describe how scientists are using EOS data to examine land use and natural hazards, environmental air quality, including dust storms over the world's deserts, cloud and radiation properties, sea surface temperature, and winds over the ocean.

  4. Electric Dipole Moments of Nanosolvated Acid Molecules in Water Clusters

    NASA Astrophysics Data System (ADS)

    Guggemos, Nicholas; Slavíček, Petr; Kresin, Vitaly V.

    2015-01-01

    The electric dipole moments of (H2O)nDCl (n =3 - 9 ) clusters have been measured by the beam-deflection method. Reflecting the (dynamical) charge distribution within the system, the dipole moment contributes information about the microscopic structure of nanoscale solvation. The addition of a DCl molecule to a water cluster results in a strongly enhanced susceptibility. There is evidence for a noticeable rise in the dipole moment occurring at n ≈5 - 6 . This size is consistent with predictions for the onset of ionic dissociation. Additionally, a molecular-dynamics model suggests that even with a nominally bound impurity an enhanced dipole moment can arise due to the thermal and zero-point motion of the proton and the water molecules. The experimental measurements and the calculations draw attention to the importance of fluctuations in defining the polarity of water-based nanoclusters and generally to the essential role played by motional effects in determining the response of fluxional nanoscale systems under realistic conditions.

  5. Dynamics of supercooled water in a biological model system of the amino acid L-lysine.

    PubMed

    Cerveny, Silvina; Swenson, Jan

    2014-10-28

    The dynamics of supercooled water in aqueous solutions of the single amino acid L-lysine has been studied by broadband dielectric spectroscopy. The chosen biological system is unique in the sense that the water content is high enough to fully dissolve the amino acid, but low enough to avoid crystallisation to ice at any temperature. This is not possible to achieve for proteins or other larger biomolecules, where either hydrated samples without ice or solutions with large quantities of ice, or a cryoprotectant sugar, have to be studied at low temperatures. Thus, it is a key finding to be able to study water and biomolecular dynamics in a non-crystallized and biologically realistic solution at supercooled temperatures. Here, we focus on the water dynamics in this unique biological solution of L-lysine and water. We show that this unique system also gives rise to unique water dynamics, since, for the first time, a continuation of a cooperative (α-like) water relaxation is observed after a crossover to a more local β-like water relaxation has occurred with decreasing temperature. This implies that the supercooled water in the biological solution shows a twofold relaxation behaviour, with one relaxation identical to the main relaxation of water in hard confinements and one relaxation almost identical to the main water relaxation in ordinary aqueous solutions. PMID:25224819

  6. The Integration, Testing and Flight of the EO-1 GPS

    NASA Technical Reports Server (NTRS)

    Quinn, David A.; Sanneman, Paul A.; Shulman, Seth E.; Sager, Jennifer A.

    2001-01-01

    The Global Positioning System has long been hailed as the wave of the future for autonomous on-board navigation of low Earth orbiting spacecraft despite the fact that relatively few spacecraft have actually employed it for this purpose. While several missions operated out of the Goddard Space Flight Center have flown GPS receivers on board, the New Millenium Program (NMP) Earth Orbiting-1 (EO-1) spacecraft is the first to employ GPS for active, autonomous on-board navigation. Since EO-1 was designed to employ GPS as its primary source of the navigation ephemeris, special care had to be taken during the integration phase of spacecraft construction to assure proper performance. This paper is a discussion of that process: a brief overview of how the GPS works, how it fits into the design of the EO-1 Attitude Control System (ACS), the steps taken to integrate the system into the EO-1 spacecraft, the ultimate on-orbit performance during launch and early operations of the EO-1 mission and the performance of the on-board GPS ephemeris versus the ground based ephemeris. Conclusions will include a discussion of the lessons learned.

  7. (abstract) The EOS SAR Mission: A New Approach

    NASA Technical Reports Server (NTRS)

    Way, JoBea

    1993-01-01

    The goal of the Earth Orbiting System Synthetic Aperture Radar (EOS SAR) program is to help develop the modeling and observational capabilities to predict and monitor terrestrial and oceanic processes that are either causing global change or resulting from global change. Specifically, the EOS SAR will provide important geophysical products to the EOS data set to improve our understanding of the state and functioning of the Earth system. The strategy for the EOS SAR program is to define the instrument requirements based on required input to geophysical algorithms, provide the processing capability and algorithms to generate such products on the required spatial (global) and temporal (3-5 days) scales, and to provide the spaceborne instrumentation with international partnerships. Initially this partnership has been with Germany; currently we are exploring broader international partnerships. A MultiSAR approach to the EOS SAR which includes a number of SARs provided by Japan, ESA, Germany, Canada, and the US in synergistic orbits could be used to attain a truly global monitoring capability using multifrequency polarimetric signatures. These concepts and several options for mission scenarios will be presented.

  8. Exponential 6 parameterization for the JCZ3-EOS

    SciTech Connect

    McGee, B.C.; Hobbs, M.L.; Baer, M.R.

    1998-07-01

    A database has been created for use with the Jacobs-Cowperthwaite-Zwisler-3 equation-of-state (JCZ3-EOS) to determine thermochemical equilibrium for detonation and expansion states of energetic materials. The JCZ3-EOS uses the exponential 6 intermolecular potential function to describe interactions between molecules. All product species are characterized by r*, the radius of the minimum pair potential energy, and {var_epsilon}/k, the well depth energy normalized by Boltzmann`s constant. These parameters constitute the JCZS (S for Sandia) EOS database describing 750 gases (including all the gases in the JANNAF tables), and have been obtained by using Lennard-Jones potential parameters, a corresponding states theory, pure liquid shock Hugoniot data, and fit values using an empirical EOS. This database can be used with the CHEETAH 1.40 or CHEETAH 2.0 interface to the TIGER computer program that predicts the equilibrium state of gas- and condensed-phase product species. The large JCZS-EOS database permits intermolecular potential based equilibrium calculations of energetic materials with complex elemental composition.

  9. The Role of Organic Acids in the Acid-Base Status of Surface Waters at Bickford Watershed, Massachusetts

    NASA Astrophysics Data System (ADS)

    Eshleman, K. N.; Hemond, H. F.

    1985-10-01

    An experimental field study of the alkalinity and major ion budgets of Bickford watershed in central Massachusetts indicates that organic acid production by the ecosystem contributes measurably to surface water acidification. Applying the concepts of alkalinity, electroneutrality of solutions, and mass balance, organic acids were found to comprise 20% of all strong acid sources on one subcatchment annually, a value half as large as the measured bulk mineral acid deposition. Inorganic cation to anion ratios in Provencial Brook varied between 1.0 in winter and 1.6 during summer, suggesting the presence of up to 100 μeq/L of unmeasured charge from organic anions during the growing season. Base titrations and ultraviolet photooxidation experiments confirmed the existence of low pKa (3.5-5.0) acidic functional groups. A positive linear relationship between dissolved organic carbon (DOC) and anion deficit for a group of surface and groundwater samples indicates the DOC contains about 7.5 meq carboxylic groups per gram C. Biological factors related to both upland and wetland carbon metabolism apparently control this natural acidification phenomenon, which has not been documented on other watersheds in the northeastern United States for which annual alkalinity budgets have been determined.

  10. Water evaporation rates across hydrophobic acid monolayers at equilibrium spreading pressure.

    PubMed

    Tsuji, Minami; Nakahara, Hiromichi; Moroi, Yoshikiyo; Shibata, Osamu

    2008-02-15

    The effect of alkanoic acid [CH(3)(CH(2))(n-2)COOH; HCn] and perfluoroalkanoic acid [CF(3)(CF(2))(n-2)COOH; FCn] monolayers on the water evaporation rate was investigated by thermogravimetry tracing the decrease in amount of water with time. The evaporation rate from the surface covered by a monolayer was measured as a function of temperature and hydrophobic chain length of the acids, where the monolayer was under an equilibrium spreading pressure. From thermal behavior of the crystallized acids, their solid states are C-type in crystalline state over the temperature range from 298.2 to 323.2 K. The dry air was flowed through a furnace tube of a thermogravimetry apparatus at the flow rate of 80 mL min(-1), where the evaporation rate becomes almost constant irrespective of the flow rate. The temperature dependence of the evaporation rate was analyzed kinetically to evaluate the activation energy and thermodynamics values for the activated complex, which demonstrated that these values were almost the same for both alkanoic acids and perfluoroalkanoic acids, although the effect of perfluoroalkanoic acids on the evaporation rate was smaller than that of corresponding hydrogenated fatty acids. The difference in the evaporation rate between FCn and HCn was examined by atomic force microscopy (AFM), Brewster angle microscopy (BAM), surface potential (DeltaV) at equilibrium spreading pressure, and Langmuir curve (pi-A isotherm), and their results were consistent and supported the difference. PMID:18048050

  11. Characterization of biodegradation intermediates of nonionic surfactants by MALDI-MS. 2. Oxidative biodegradation profiles of uniform octylphenol polyethoxylate in 18O-labeled water.

    PubMed

    Sato, Hiroaki; Shibata, Atsushi; Wang, Yang; Yoshikawa, Hiromichi; Tamura, Hiroto

    2003-01-01

    This paper reports the characterization of the biodegradation intermediates of octylphenol octaethoxylate (OP(8)EO) by means of matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS). The biodegradation test study was carried out in a pure culture (Pseudomonas putida S-5) under aerobic conditions using OP(8)EO as the sole carbon source and (18)O-labeled water as an incubation medium. In the MALDI-MS spectra of biodegraded samples, a series of OP(n)EO molecules with n = 2-8 EO units and their corresponding carboxylic acid products (OP(n)EC) were observed. The use of purified OP(8)EO enabled one to distinguish the shortened OPEO molecules as biodegradation intermediates. Furthermore, the formation of OP(8)EC (the oxidized product of OP(8)EO) supported the notion that terminal oxidation is a step in the biodegradation process. When biodegradation study was carried out in (18)O-labeled water, incorporation of (18)O atoms into the carboxyl group was observed for OPEC, while no incorporation was observed for the shortened OPEO products. These results could provide some rationale to the biodegradation mechanism of alkylphenol polyethoxylates. PMID:12523845

  12. OCCURRENCE OF IODO-ACID AND IODO-THM DISINFECTION BY-PRODUCTS IN CHLORAMINATED DRINKING WATER

    EPA Science Inventory

    As part of a recent Nationwide Disinfection By-Product (DBP) Occurrence Study, iodo-acids were identified for the first time as DBPs in drinking water disinfected with chloramines. The iodo-acids identified included iodoacetic acid, bromoiodoacetic acid, (E)-3-bromo-3-iodo-prope...

  13. Soil water samplers in ion balance studies on acidic forest soils

    SciTech Connect

    Rasmussen, L.; Joergensen, P.; Kruse, S.

    1986-04-01

    During the last years an increasing consciousness has appeared of the injurious effects of acid rain on the forest ecosystems both in Europe and North America. At several localities ion balance studies have been implemented in order to evaluate the impact of the atmospheric deposition of acidic substances and heavy metals on the forest ecosystem. In many localities the leaching of material to the ground water or output from the ecosystem has to be determined by means of tensiometer measurements and soil water sampling. Many different soil water samplers are available on the market and they show useful applicability under the given circumstances. But in many cases soil water samples taken with different equipment give incommensurable results leading to differing explanations of the effects of acid precipitation on elements and their cycling in the ecosystem. The purpose of the present study is twofold. Firstly, the sorption characteristics of different types of soil water samplers are examined under acidic soil conditions both by installation in the field and by laboratory experiments. Secondly, a new method is introduced for current and constant soil water sampling under varying soil suctions in the unsaturated zone.

  14. Impact of several water-miscible organic solvents on sorption of benzoic acid by soil

    SciTech Connect

    Lee, L.S.; Rao, P.S.C.

    1996-05-01

    Sorption of benzoic acid by a surface soil was measured from several binary mixtures of water and various organic cosolvents spanning a wide range in solvent properties. For all solvents investigated, the addition to an aqueous solution resulted in an increase in solubility and an alkaline shift in the conditional ionization constant (pK{sub a}{sup c}) of benzoic acid. Sorption data were assessed using a cosolvency model that incorporated speciation of the organic acid as determined by the pK{sub a}{sup c} and soil-solution pH. The model provided reasonable predictions of the sorption trends observed from acetone/water, acetonitrile/ water, and 1,4-dioxane/water solutions. However, enhanced sorption observed from DMSO/water solutions was not well described by the cosolvency model similar to what was previously observed for the sorption of carboxylic acids from methanol/water solutions. The relative importance of cosolvent properties and various solvent-specific mechanisms is discussed. Hydrogen bonding along with preferential solvation are hypothesized as the primary mechanisms responsible for the observed deviations from the model. 36 refs., 5 figs., 1 tab.

  15. Atmospheric photochemistry at a fatty acid-coated air-water interface.

    PubMed

    Rossignol, Stéphanie; Tinel, Liselotte; Bianco, Angelica; Passananti, Monica; Brigante, Marcello; Donaldson, D James; George, Christian

    2016-08-12

    Although fatty acids are believed to be photochemically inert in the actinic region, complex volatile organic compounds are produced during illumination of an air-water interface coated solely with a monolayer of carboxylic acid. When aqueous solutions containing nonanoic acid (NA) at bulk concentrations that give rise to just over a monolayer of NA coverage are illuminated with actinic radiation, saturated and unsaturated aldehydes are seen in the gas phase, and more highly oxygenated products appear in the aqueous phase. This chemistry is probably initiated by triplet-state NA molecules excited by direct absorption of actinic light at the water surface. Because fatty acids-covered interfaces are ubiquitous in the environment, such photochemical processing will have a substantial impact on local ozone and particle formation. PMID:27516601

  16. Communication: Physical origins of ionization potential shifts in mixed carboxylic acids and water complexes

    NASA Astrophysics Data System (ADS)

    Gu, Quanli; Tang, Zhen; Su, Peifeng; Wu, Wei; Yang, Zhijun; Trindle, Carl O.; Knee, Joseph L.

    2016-08-01

    The ionization potential (IP) of the aromatic alpha hydroxy carboxylic acid, 9-hydroxy-9-fluorene carboxylic acid (9HFCA), is shifted by complexation with hydrogen bonding ligands such as water and formic acid. Generalized Kohn-Sham energy decomposition analysis decomposes the intermolecular binding energies into a frozen energy term, polarization, correlation, and/or dispersion energy terms, as well as terms of geometric relaxation and zero point energy. We observe that in each dimer the attractive polarization always increases upon ionization, enhancing binding in the cation and shifting the IP toward the red. For 9HFCA—H2O, a substantial decrease of the repulsive frozen energy in cation further shifts the IP toward red. For 9HFCA—HCOOH, the increase of the frozen energy actually occurs in the cation and shifts the IP toward blue. Consistent with the experimental measurements, our analysis provides new, non-intuitive perspectives on multiple hydrogen bonds interactions in carboxylic acids and water complexes.

  17. CERNBox + EOS: end-user storage for science

    NASA Astrophysics Data System (ADS)

    Mascetti, L.; Gonzalez Labrador, H.; Lamanna, M.; Mościcki, JT; Peters, AJ

    2015-12-01

    CERNBox is a cloud synchronisation service for end-users: it allows syncing and sharing files on all major mobile and desktop platforms (Linux, Windows, MacOSX, Android, iOS) aiming to provide offline availability to any data stored in the CERN EOS infrastructure. The successful beta phase of the service confirmed the high demand in the community for an easily accessible cloud storage solution such as CERNBox. Integration of the CERNBox service with the EOS storage back-end is the next step towards providing “sync and share” capabilities for scientific and engineering use-cases. In this report we will present lessons learnt in offering the CERNBox service, key technical aspects of CERNBox/EOS integration and new, emerging usage possibilities. The latter includes the ongoing integration of “sync and share” capabilities with the LHC data analysis tools and transfer services.

  18. Reference MWA EoR Power Spectrum analysis

    NASA Astrophysics Data System (ADS)

    Hazelton, Bryna; Pober, Jonathan; Beardsley, Adam; Morales, Miguel F.; Sullivan, Ian S.; MWA Collaboration

    2015-01-01

    Observations of the Epoch of Reionization using redshifted 21cm HI emission promise to provide sensitive new cosmological constraints in the next few years. The current generation of HI EoR telescopes are targeting a statistical detection of the EoR in the power spectrum of the 21cm emission. The principal challenge lies in extracting the faint cosmological signal in the face of bright foregrounds and instrumental systematics that threaten to overwhelm it.We present the UW EoR power spectrum code, the reference code for the MWA and the first power spectrum analysis to analytically propagate the error bars through the full data analysis pipeline. We demonstrate the sensitivity of the power spectrum as a diagnostic tool for identifying subtle systematics and show power spectra of the first season of MWA observations.

  19. Effect of sewage sludge on formation of acidic ground water at a reclaimed coal mine

    USGS Publications Warehouse

    Cravotta, C.A., III

    1998-01-01

    Data on rock, ground water, vadose water, and vadose gas chemistry were collected for two years after sewage sludge was applied at a reclaimed surface coal mine in Pennsylvania to determine if surface-applied sludge is an effective barrier to oxygen influx, contributes metals and nutrients to ground water, and promotes the acidification of ground water. Acidity, sulfate, and metals concentrations were elevated in the ground water (6- to 21-m depth) from spoil relative to unmined rock because of active oxidation of pyrite and dissolution of aluminosilicate, carbonate, and Mn-Fe-oxide minerals in the spoil. Concentrations of acidity, sulfate, metals (Fe, Mn, Al, Cd, Cu, Cr, Ni, Zn), and nitrate, and abundances of iron-oxidizing bacteria were elevated in the ground water from sludge-treated spoil relative to untreated spoil having a similar mineral composition; however, gaseous and dissolved oxygen concentrations did not differ between the treatments. Abundances of iron-oxidizing bacteria in the ground water samples were positively correlated with concentrations of ammonia, nitrate, acidity, metals, and sulfate. Concentrations of metals in vadose water samples (<5-m depth) from sludge-treated spoil (pH 5.9) were not elevated relative to untreated spoil (pH 4.4). In contrast, concentrations of nitrate were elevated in vadose water samples from sludge-treated spoil, frequently exceeding 10 mg/L. Downgradient decreases in nitrate to less than 3 mg/L and increases in sulfate concentrations in underlying ground water could result from oxidation of pyrite by nitrate. Thus, sewage sludge added to pyritic spoil can increase the growth of iron-oxidizing bacteria, the oxidation of pyrite, and the acidification of ground water. Nevertheless, the overall effects on ground water chemistry from the sludge were small and probably short-lived relative to the effects from mining only.

  20. EOS7C Version 1.0 TOUGH2 Module for Carbon Dioxide or Nitrogen in Natural Gas

    2008-01-11

    EOS7C is a TOUGH2 module for multicomponent gas mixtures in the systems methane-carbon dioxide (CH{sub 4}-CO{sub 2}) or methane-nitrogen (CH{sub 4}-N{sub 2}) with or without an aqueous phase and H{sub 2}O vapor. EOS7C uses a cubic equation of state and an accurate solubility formulation along with a multiphase Darcy's Law to model flow and transport of gas and aqueous phase mixtures over a wide range of pressures and temperatures appropriate to subsurface geologic carbon sequestrationmore » sites and natural gas reservoirs. EOS7C models supercritical CO{sub 2{ and subcritical CO{sub 2} as a non-condensible gas, hence EOS7C does not model the transitions to liquid or solid CO{sub 2} conditions. The components modeled in EOS7C are water, brine, non-condensible gas, gas tracer, methane, and optional heat. The non-condensible gas (NCG) can be selected by the user to be CO{sub 2} or N{sub 2}. The real gas properties module has options for Peng-Robinson, Redlich-Kwong, or Soave-Redlich-Kwong equations of state to calculate gas mixture density, enthalpy departure, and viscosity. Partitioning of the NCG and CH{sub 4} between the aqueous and gas phases is calculated using a very accurate chemical equilibrium approach. Transport of the gaseous and dissolved components is by advection and Fickian molecular diffusion. EOS7C is written in FORTAN77.« less

  1. Nanoscale Distribution of Sulfonic Acid Groups Determines Structure and Binding of Water in Nafion Membranes.

    PubMed

    Ling, Xiao; Bonn, Mischa; Parekh, Sapun H; Domke, Katrin F

    2016-03-14

    The connection between the nanoscale structure of two chemically equivalent, yet morphologically distinct Nafion fuel-cell membranes and their macroscopic chemical properties is demonstrated. Quantification of the chemical interactions between water and Nafion reveals that extruded membranes have smaller water channels with a reduced sulfonic acid head group density compared to dispersion-cast membranes. As a result, a disproportionally large amount of non-bulk water molecules exists in extruded membranes, which also exhibit larger proton conductivity and larger water mobility compared to cast membranes. The differences in the physicochemical properties of the membranes, that is, the chemical constitution of the water channels and the local water structure, and the accompanying differences in macroscopic water and proton transport suggest that the chemistry of nanoscale channels is an important, yet largely overlooked parameter that influences the functionality of fuel-cell membranes. PMID:26895211

  2. Mission operations concepts for Earth Observing System (EOS)

    NASA Technical Reports Server (NTRS)

    Kelly, Angelita C.; Taylor, Thomas D.; Hawkins, Frederick J.

    1991-01-01

    Mission operation concepts are described which are being used to evaluate and influence space and ground system designs and architectures with the goal of achieving successful, efficient, and cost-effective Earth Observing System (EOS) operations. Emphasis is given to the general characteristics and concepts developed for the EOS Space Measurement System, which uses a new series of polar-orbiting observatories. Data rates are given for various instruments. Some of the operations concepts which require a total system view are also examined, including command operations, data processing, data accountability, data archival, prelaunch testing and readiness, launch, performance monitoring and assessment, contingency operations, flight software maintenance, and security.

  3. Musculoskeletal imaging in progress: the EOS imaging system.

    PubMed

    Wybier, Marc; Bossard, Philippe

    2013-05-01

    The EOS 2D/3D radio-imaging device (Biospace med, France) can disclose a digital radiographic image of bones with a very low radiation dose. This in turn allows in obtaining a single image of a large field of view, as wide as the full skeleton. The simultaneous capturing of spatially paired AP and lateral X-ray images is also a specificity of EOS imaging, which further provides secondary 3D (volumic) reformation of skeletal images. The main indications of this new imaging technology are assessment and follow-up of balance disorders of the spine and of the lower limbs. PMID:23177915

  4. Earth Observation Training and Education with ESA LearnEO!

    NASA Astrophysics Data System (ADS)

    Byfield, Valborg; Mathieu, Pierre-Philippe; Dobson, Malcolm; Rosmorduc, Vinca; Del Frate, Fabio; Banks, Chris; Picchiani, Matteo

    2013-04-01

    For society to benefit fully from its investment in Earth observation, EO data must be accessible and familiar to a global community of users who have the skills, knowledge and understanding to use the observations appropriately in their work. Achieving this requires considerable education effort. LearnEO! (www.learn-eo.org) is a new ESA education project that contributes towards making this a reality. LearnEO! has two main aims: to develop new training resources that use data from sensors on ESA satellites to explore a variety of environmental topics, and to stimulate and support members of the EO and education communities who may be willing to develop and share new education resources in the future. The project builds on the UNESCO Bilko project, which currently supplies free software, tutorials, and example data to users in 175 countries. Most of these users are in academic education or research, but the training resources are also of interest to a growing number of professionals in government, NGOs and private enterprise. Typical users are not remote sensing experts, but see satellite data as one of many observational tools. They want an easy, low-cost means to process, display and analyse data from different satellite sensors as part of their work in environmental research, monitoring and policy development. Many of the software improvements and training materials developed in LearnEO! are in response to requests from this user community. The LearnEO! tutorial and peer-reviewed lessons are designed to teach satellite data processing and analysis skills at different levels, from beginner to advanced - where advanced lessons requires some previous experience with Earth observation techniques. The materials are aimed at students and professionals in various branches of Earth sciences who have not yet specialised in specific EO technologies. The lessons are suitable for self-study, university courses at undergraduate to MSc level, or for continued professional

  5. Centaurus A galaxy, type EO peculiar elliptical, also radio source

    NASA Technical Reports Server (NTRS)

    2002-01-01

    Centaurus A galaxy, type EO peculiar elliptical, also radio source. CTIO 4-meter telescope, 1975. NGC 5128, a Type EO peculiar elliptical galaxy in the constellation Centaurus. This galaxy is one of the most luminous and massive galaxies known and is a strong source of both radio and X-ray radiation. Current theories suggest that the nucleus is experiencing giant explosions involving millions of stars and that the dark band across the galactic disk is material being ejected outward. Cerro Toloto 4-meter telescope photo. Photo credit: National Optical Astronomy Observatories

  6. Effects of Water Stress on the Organic Acid and Carbohydrate Compositions of Cotton Plants

    PubMed Central

    Timpa, Judy D.; Burke, John J.; Quisenberry, Jerry E.; Wendt, Charles W.

    1986-01-01

    Two photoperiodic cotton (Gossypium hirsutum L.) strains (T185 and T466) which had been empirically selected because of poor performance and two strains (T25 and T256) selected because of enhanced performance under field water stress were evaluated for stress-induced changes in their organic acids and carbohydrates. Profiles and quantitation of organic acids and carbohydrates from aqueous extractions of cotton leaf tissue were determined by high performance liquid chromatography. In all cases, the water-stressed plants showed two to five times greater amounts of organic acids and carbohydrates over the values determined for the irrigated samples. Under stress, sucrose accumulation was observed in wilting strains (poor performers) probably related to rate of translocation out of the leaf. The most dramatic response to water stress was the accumulation of citric acid in strains T25 and T256 as compared to T185 and T466. Citric/malic acid ratios for both the irrigated and water-stressed samples of T25 and T256 were twice those of T185 and T466. PMID:16665100

  7. Sulfuric acid speleogenesis (SAS) close to the water table: Examples from southern France, Austria, and Sicily

    NASA Astrophysics Data System (ADS)

    De Waele, Jo; Audra, Philippe; Madonia, Giuliana; Vattano, Marco; Plan, Lukas; D'Angeli, Ilenia M.; Bigot, Jean-Yves; Anoux, Catherine; Nobécourt, Jean-Claude

    2016-01-01

    Caves formed by rising sulfuric waters have been described from all over the world in a wide variety of climate settings, from arid regions to mid-latitude and alpine areas. H2S is generally formed at depth by reduction of sulfates in the presence of hydrocarbons and is transported in solution through the deep aquifers. In tectonically disturbed areas major fractures eventually allow these H2S-bearing fluids to rise to the surface where oxidation processes can become active producing sulfuric acid. This extremely strong acid reacts with the carbonate bedrock creating caves, some of which are among the largest and most spectacular in the world. Production of sulfuric acid mostly occurs at or close to the water table but also in subaerial conditions in moisture films and droplets in the cave environment. These caves are generated at or immediately above the water table, where condensation-corrosion processes are dominant, creating a set of characteristic meso- and micromorphologies. Due to their close connection to the base level, these caves can also precisely record past hydrological and geomorphological settings. Certain authigenic cave minerals, produced during the sulfuric acid speleogenesis (SAS) phase, allow determination of the exact timing of speleogenesis. This paper deals with the morphological, geochemical and mineralogical description of four very typical sulfuric acid water table caves in Europe: the Grotte du Chat in the southern French Alps, the Acqua Fitusa Cave in Sicily (Italy), and the Bad Deutsch Altenburg and Kraushöhle caves in Austria.

  8. Enzyme-linked immunosorbent assay (ELISA) for the anthropogenic marker isolithocholic acid in water.

    PubMed

    Baldofski, Stefanie; Hoffmann, Holger; Lehmann, Andreas; Breitfeld, Stefan; Garbe, Leif-Alexander; Schneider, Rudolf J

    2016-11-01

    Bile acids are promising chemical markers to assess the pollution of water samples with fecal material. This study describes the optimization and validation of a direct competitive enzyme-linked immunosorbent assay for the bile acid isolithocholic acid (ILA). The quantification range of the optimized assay was between 0.09 and 15 μg/L. The assay was applied to environmental water samples. Most studies until now were focused on bile acid fractions in the particulate phase of water samples. In order to avoid tedious sample preparation, we undertook to evaluate the dynamics and significance of ILA levels in the aqueous phase. Very low concentrations in tap and surface water samples made a pre-concentration step necessary for this matrix as well as for wastewater treatment plant (WWTP) effluent. Mean recoveries for spiked water samples were between 97% and 109% for tap water and WWTP influent samples and between 102% and 136% for WWTP effluent samples. 90th percentiles of intra-plate and inter-plate coefficients of variation were below 10% for influents and below 20% for effluents and surface water. ILA concentrations were quantified in the range of 33-72 μg/L in influent, 21-49 ng/L in effluent and 18-48 ng/L in surface water samples. During wastewater treatment the ILA levels were reduced by more than 99%. ILA concentrations of influents determined by ELISA and LC-MS/MS were in good agreement. However, findings in LC-ELISA experiments suggest that the true ILA levels in concentrated samples are lower due to interfering effects of matrix compounds and/or cross-reactants. Yet, the ELISA will be a valuable tool for the performance check and comparison of WWTPs and the localization of fecal matter input into surface waters. PMID:27544648

  9. Determination of boron in produced water using the carminic acid assay.

    PubMed

    Floquet, Cedric F A; Sieben, Vincent J; MacKay, Bruce A; Mostowfi, Farshid

    2016-04-01

    Using the carminic acid assay, we determined the concentration of boron in oilfield waters. We investigated the effect of high concentrations of salts and dissolved metals on the assay performance. The influence of temperature, development time, reagent concentration, and water volume was studied. Ten produced and flowback water samples of different origins were measured, and the method was successfully validated against ICP-MS measurements. In water-stressed regions, produced water is a potential source of fresh water for irrigation, industrial applications, or consumption. Therefore, boron concentration must be determined and controlled to match the envisaged waste water reuse. Fast, precise, and onsite measurements are needed to minimize errors introduced by sample transportation to laboratories. We found that the optimum conditions for our application were a 5:1 mixing volume ratio (reagent to sample), a 1 g L(-1) carminic acid concentration in 99.99% sulfuric acid, and a 30 min reaction time at ambient temperature (20 °C to 23 °C). Absorption values were best measured at 610 nm and 630 nm and baseline corrected at 865 nm. Under these conditions, the sensitivity of the assay to boron was maximized while its cross-sensitivity to dissolved titanium, iron, barium and zirconium was minimized, alleviating the need for masking agents and extraction methods. PMID:26838405

  10. Palladium-catalyzed cross-coupling reactions of aryl boronic acids with aryl halides in water.

    PubMed

    Wang, Shaoyan; Zhang, Zhiqiang; Hu, Zhizhi; Wang, Yue; Lei, Peng; Chi, Haijun

    2009-01-01

    An efficient Suzuki cross-coupling reaction using a variety of aryl halides in neat water was developed. The Pd-catalyzed reaction between aryl bromides or chlorides and phenyl boronic acids was compatible with various functional groups and affords biphenyls in good to excellent yields without requirement of organic cosolvents. The air stability and solubility in water of the palladium-phosphinous acid complexes were considered to facilitate operation of the coupling reaction and product isolation. The reaction conditions including Pd catalyst selection, temperature, base and catalyst recoverability were also investigated. PMID:25084408

  11. Efficient Route to Highly Water-Soluble Aromatic Cyclic Hydroxamic Acid Ligands

    SciTech Connect

    Seitz, Michael; Raymond, Kenneth N.

    2008-02-06

    2-Hydroxyisoquinolin-1-one (1,2-HOIQO) is a new member of the important class of aromatic cyclic hydroxamic acid ligands which are widely used in metal sequestering applications and metal chelating therapy. The first general approach for the introduction of substituents at the aromatic ring of the chelating moiety is presented. As a useful derivative, the highly water-soluble sulfonic acid has been synthesized by an efficient route that allows general access to 1,2-HOQIO 3-carboxlic acid amides, which are the most relevant for applications.

  12. One pot, rapid and efficient synthesis of water dispersible gold nanoparticles using alpha-amino acids

    NASA Astrophysics Data System (ADS)

    Wangoo, Nishima; Kaur, Sarabjit; Bajaj, Manish; Jain, D. V. S.; Sharma, Rohit K.

    2014-10-01

    A detailed study on the synthesis of spherical and monodispersed gold nanoparticles (AuNPs) using all of the 20 naturally occurring α-amino acids has been reported. The synthesized nanoparticles have been further characterized using various techniques such as absorbance spectroscopy, transmission electron microscopy, dynamic light scattering and nuclear magnetic resonance. Size control of the nanoparticles has been achieved by varying the ratio of the gold ion to the amino acid. These monodispersed water soluble AuNPs synthesized using non-toxic, naturally occurring α-amino acids as reducing and capping/stabilizing agents serve as a remarkable example of green chemistry.

  13. Microgravity Compatible Reagentless Instrumentation for Detection of Dissolved Organic Acids and Alcohols in Potable Water

    NASA Technical Reports Server (NTRS)

    Akse, James R.; Jan, Darrell L. (Technical Monitor)

    2002-01-01

    The Organic Acid and Alcohol Monitor (OAAM) program has resulted in the successful development of a computer controlled prototype analyzer capable of accurately determining aqueous organic acids and primary alcohol concentrations over a large dynamic range with high sensitivity. Formic, acetic, and propionic acid were accurately determined at concentrations as low as 5 to 10 micrograms/L in under 20 minutes, or as high as 10 to 20 mg/L in under 30 minutes. Methanol, ethanol, and propanol were determined at concentrations as low as 20 to 100 micrograms/L, or as high as 10 mg/L in under 30 minutes. Importantly for space based application, the OAAM requires no reagents or hazardous chemicals to perform these analyses needing only power, water, and CO2 free purge gas. The OAAM utilized two membrane processes to segregate organic acids from interfering ions. The organic acid concentration was then determined based upon the conductiometric signal. Separation of individual organic acids was accomplished using a chromatographic column. Alcohols are determined in a similar manner after conversion to organic acids by sequential biocatalytic and catalytic oxidation steps. The OAAM was designed to allow the early diagnosis of under performing or failing sub-systems within the Water Recovery System (WRS) baselined for the International Space Station (ISS). To achieve this goal, several new technologies were developed over the course of the OAAM program.

  14. Performance of the Goulden large volume sampler for acidic compounds in natural waters

    SciTech Connect

    Headley, J.; Dickson, L.; Swyngedouw, C.; Crosley, D.; Whitley, G.

    1995-12-31

    The Goulden large volume sampler (LVX) has received extensive use for monitoring and surveillance surveys of natural waters impacted by pulp and paper mills, and agricultural run-off water. Despite this use, there is a lack of performance criteria for acidic contaminants, There are concerns about whether this sampler which was originally developed for extractions of OCs, PCBs and PAHs, was suitable for sampling polar acidic compounds. Performance tests conducted in this work, indicated that with the exception of 4-bromophenol and dichlorophenylacetic acid, surrogate compounds were recovered from pH 2 adjusted samples (20 1) at approximately 80 {+-} 15--35% recovery. Although these recoveries were comparable to values attainable for neutral pesticides, the standard deviations were up to four times greater than values reported for neutral compounds, for concentrations of analytes at low ppt levels. Specific performance criteria (percent recoveries where the number of determinations are given in parenthesis) observed for the proposed surrogates heptadecanoic acid, dichlorophenylacetic acid, 4-bromophenol, o-methylpodocarpic acid and 2,4,6-tribromophenol were: 86.6(19) {+-} 26.8; 46.1(18) {+-} 14.5; 31.6(19) {+-} 24.1; 78.4(18) {+-} 14.7; and95.2(18) {+-} 33.6 respectively. These values can be used to provide guidelines for acceptable surrogate recoveries, and validation of extractions of acidic polar compounds.

  15. Diamonds in the rough: identification of individual napthenic acids in oil sands process water

    SciTech Connect

    Rowland, Steven J.; Scarlett, Alan G.; Jones, David; West, Charles E. ); Frank, Richard A.

    2011-03-10

    Expansion of the oil sands industry of Canada has seen a concomitant increase in the amount of process water produced and stored in large lagoons known as tailings ponds. Concerns have been raised, particularly about the toxic complex mixtures of water-soluble naphthenic acids (NA) in the process water. To date, no individual NA have been identified, despite numerous attempts, and while the toxicity of broad classes of acids is of interest, toxicity is often structure-specific, so identification of individual acids may also be very important. The chromatographic resolution and mass spectral identification of some individual NA from oil sands process water is described. The authors concluded that the presence of tricyclic diamondoid acids, never before even considered as NA, suggests an unprecedented degree of biodegradation of some of the oil in the oil sands. The identifications reported should now be followed by quantitative studies, and these used to direct toxicity assays of relevant NA and the method used to identify further NA to establish which, or whether all NA, are toxic. The two-dimensional comprehensive gas chromatography-mass spectrometry method described may also be important for helping to better focus reclamation/remediation strategies for NA as well as in facilitating the identification of the sources of NA in contaminated surface waters (auth)

  16. REE speciation in low-temperature acidic waters and the competitive effects of aluminum

    USGS Publications Warehouse

    Gimeno, Serrano M.J.; Auque, Sanz L.F.; Nordstrom, D.K.

    2000-01-01

    The effect of simultaneous competitive speciation of dissolved rare earth elements (REEs) in acidic waters (pH 3.3 to 5.2) has been evaluated by applying the PHREEQE code to the speciation of water analyses from Spain, Brazil, USA, and Canada. The main ions that might affect REE are Al3+, F-, SO42-, and PO43-. Fluoride, normally a significant complexer of REEs, is strongly associated with Al3+ in acid waters and consequently has little influence on REEs. The inclusion of aluminum concentrations in speciation calculations for acidic waters is essential for reliable speciation of REEs. Phosphate concentrations are too low (10-4 to 10-7 m) to affect REE speciation. Consequently, SO42- is the only important complexing ligand for REEs under these conditions. According to Millero [Millero, F.J., 1992. Stability constants for the formation of rare earth inorganic complexes as a function of ionic strength. Geochim. Cosmochim. Acta, 56, 3123-3132], the lanthanide sulfate stability constants are nearly constant with increasing atomic number so that no REE fractionation would be anticipated from aqueous complexation in acidic waters. Hence, REE enrichments or depletions must arise from mass transfer reactions. (C) 2000 Elsevier Science B.V. All rights reserved.

  17. Water uptake of internally mixed ammonium sulfate and dicarboxylic acid particles probed by infrared spectroscopy

    NASA Astrophysics Data System (ADS)

    Miñambres, Lorena; Méndez, Estíbaliz; Sánchez, María N.; Castaño, Fernando; Basterretxea, Francisco J.

    2013-05-01

    Tropospheric aerosols are usually mixtures of inorganic and organic compounds in variable proportions, and the relative amount of organic fraction can influence the hygroscopic properties of the particles. Infrared spectra of submicrometer internally mixed dry particles of ammonium sulfate (AS) with various dicarboxylic acids (oxalic, malonic, maleic, glutaric and pimelic) have been measured in an aerosol flow tube at several solute mass ratios. The spectra show a notable broadening in the bandwidth of sulfate ion ν3 vibrational band near 1115 cm-1 with respect to pure AS. We attribute these perturbations, that are biggest at AS/organic acid mass ratio near unity, to intermolecular interactions between inorganic ions and organic acid molecules in the internally mixed solids. The water uptake behavior of internally mixed particles has been measured by recording the infrared integrated absorbance of liquid water as a function of relative humidity (RH). The amount of water present in the particles prior to deliquescence correlates partially with the water solubilities of the dicarboxylic acids, and also with the relative magnitudes of intermolecular interactions in the internally mixed dry solids. Phase change of ammonium sulfate in the internally mixed particles with RH has been spectrally monitored, and it is shown that water uptaken before full deliquescence produces structural changes in the particles that are revealed by their vibrational spectra.

  18. Segregation of acid plume pixels from background water pixels, signatures of background water and dispersed acid plumes, and implications for calculation of iron concentration in dense plumes

    NASA Technical Reports Server (NTRS)

    Bahn, G. S.

    1978-01-01

    Two files of data, obtained with a modular multiband scanner, for an acid waste dump into ocean water, were analyzed intensively. Signatures were derived for background water at different levels of effective sunlight intensity, and for different iron concentrations in the dispersed plume from the dump. The effect of increased sunlight intensity on the calculated iron concentration was found to be relatively important at low iron concentrations and relatively unimportant at high values of iron concentration in dispersed plumes. It was concluded that the basic equation for iron concentration is not applicable to dense plumes, particularly because lower values are indicated at the very core of the plume, than in the surrounding sheath, whereas radiances increase consistently from background water to dispersed plume to inner sheath to innermost core. It was likewise concluded that in the dense plume the iron concentration would probably best be measured by the higher wave length radiances, although the suitable relationship remains unknown.

  19. Effect of boric acid supplementation of ostrich water on the expression of Foxn1 in thymus.

    PubMed

    Xiao, Ke; Ansari, Abdur Rahman; Rehman, Zia Ur; Khaliq, Haseeb; Song, Hui; Tang, Juan; Wang, Jing; Wang, Wei; Sun, Peng-Peng; Zhong, Juming; Peng, Ke-Mei

    2015-11-01

    Foxn1 is essential for thymus development. The relationship between boric acid and thymus development, optimal dose of boric acid in ostrich diets, and the effects of boric acid on the expression of Foxn1 were investigated in the present study. Thirty healthy ostriches were randomly divided into six groups: Group I, II, III, IV, V, VI, and supplemented with boric acid at the concentration of 0 mg/L, 40 mg/L, 80 mg/L, 160 mg/L, 320 mg/L, 640 mg/L, respectively. The histological changes in thymus were observed by HE staining, and the expression of Foxn1 analyzed by immunohistochemistry and western blot. TUNEL method was used to label the apoptotic cells. Ostrich Foxn1 was sequenced by Race method. The results were as following: Apoptosis in ostrich thymus was closely related with boric acid concentrations. Low boric acid concentration inhibited apoptosis in thymus, but high boric acid concentration promoted apoptosis. Foxn1-positive cells were mainly distributed in thymic medulla and rarely in cortex. Foxn1 is closely related to thymus growth and development. The nucleotide sequence and the encoded protein of Foxn1 were 2736 bases and 654 amino acids in length. It is highly conserved as compared with other species. These results demonstrated that the appropriate boric acid supplementation in water would produce positive effects on the growth development of ostrich thymus by promoting Foxn1 expression, especially at 80 mg/L, and the microstructure of the thymus of ostrich fed 80 mg/L boric acid was well developed. The supplementation of high dose boron (>320 mg/L) damaged the microstructure of thymus and inhibited the immune function by inhibiting Foxn1 expression, particularly at 640 mg/L. The optimal dose of boric acid supplementation in ostrich diets is 80 mg/L boric acid. The genomic full-length of African ostrich Foxn1 was cloned for the first time in the study. PMID:25665795

  20. Monthly variations of haloacetic acids in drinking water by GC/MS

    SciTech Connect

    Benoit, F.M.; Williams, D.T.; LeBel, G.L.

    1995-12-31

    In a national survey of 53 drinking water plants in Canada, haloacetic acids (HAA) were identified as major disinfection by-products (DBPs) and were found in all the chlorinated drinking water supplies examined. The HAA levels were observed to vary with season (summer and winter), water treatment practice (chlorination, chloramination and ozonation) and distance from the treatment plant. In an effort to understand better the dynamics of HAA formation, three drinking water plants that used different disinfectant combinations (chlorine - chlorine, chlorine chloramine and ozone - chlorine) were studied each month (over a period of I year, 1994) at five locations within each supply system. Three HAA (mono-(MCAA), di-(DCAA) and tri-(TCAA) chloroacetic acids) were monitored in the present study, however, MCAA were consistently found at lower levels than DCAA and TCAA; only the DCAA and TCAA results are presented here.

  1. Impacts on water quality and biota from natural acid rock drainage in Colorado's Lake Creek watershed

    USGS Publications Warehouse

    Bird, D.A.; Sares, Matthew A.; Policky, Greg A.; Schmidt, Travis S.; Church, Stanley E.

    2006-01-01

    Colorado's Lake Creek watershed hosts natural acid rock drainage that significantly impacts surface water, streambed sediment, and aquatic life. The source of the ARD is a group of iron-rich springs that emerge from intensely hydrothermally altered, unexploited, low-grade porphyry copper mineralization in the Grizzly Peak Caldera. Source water chemistry includes pH of 2.5 and dissolved metal concentrations of up to 277 mg/L aluminum, 498 mg/L iron, and 10 mg/L copper. From the hydrothermally altered area downstream for 27 kilometers to Twin Lakes Reservoir, metal concentrations in streambed sediment are elevated and the watershed experiences locally severe adverse impacts to aquatic life due to the acidic, metal-laden water. The water and sediment quality of Twin Lakes Reservoir is sufficiently improved that the reservoir supports a trout fishery, and remnants of upstream ARD are negligible.

  2. Chemical disinfection of combined sewer overflow waters using performic acid or peracetic acids.

    PubMed

    Chhetri, Ravi Kumar; Thornberg, Dines; Berner, Jesper; Gramstad, Robin; Öjstedt, Ulrik; Sharma, Anitha Kumari; Andersen, Henrik Rasmus

    2014-08-15

    We investigated the possibility of applying performic acid (PFA) and peracetic acid (PAA) for disinfection of combined sewer overflow (CSO) in existing CSO management infrastructures. The disinfection power of PFA and PAA towards Escherichia coli (E. coli) and Enterococcus was studied in batch-scale and pre-field experiments. In the batch-scale experiment, 2.5 mg L(-1) PAA removed approximately 4 log unit of E. coli and Enterococcus from CSO with a 360 min contact time. The removal of E. coli and Enterococcus from CSO was always around or above 3 log units using 2-4 mg L(-1) PFA; with a 20 min contact time in both batch-scale and pre-field experiments. There was no toxicological effect measured by Vibrio fischeri when CSO was disinfected with PFA; a slight toxic effect was observed on CSO disinfected with PAA. When the design for PFA based disinfection was applied to CSO collected from an authentic event, the disinfection efficiencies were confirmed and degradation rates were slightly higher than predicted in simulated CSO. PMID:24918873

  3. Binding of water, oil, and bile acids to dietary fibers of the cellan type.

    PubMed

    Dongowski, G; Ehwald, R

    1999-01-01

    Dietary fibers (DF) of the "cellan" type (consisting mainly or exclusively of undestroyed cells) were prepared as ethanol-dried materials from apple, cabbage, sugar-beet, soybean hulls, wheat bran, and suspension cultures of Chenopodium album L. and investigated with respect to their interactions with water, water-oil dispersions, bile acids, and oil. Water binding and retention capacities were found to be especially high in cellans obtained from thin-walled raw material. Water damp sorption by dry cellans, when analyzed according to the GAB and BET equations, shows a considerable fraction of monolayer water. At a water activity of 0.98, the cell and capillary spaces outside the walls remained in the air-filled state but the cell wall pores are filled with water. When the water content of a concentrated aqueous cellan suspension was equal to or below the water binding capacity, its rheological behavior was found to be of pseudoplastic nature. At a given dry weight concentration, yield stress and viscosity of such concentrated suspensions were highest for cellans with the highest water binding capacity. Dry cellan particles absorbed fatty oils without swelling but swell in a detergent-stabilized oil/water emulsion with a similar liquid absorption capacity as in water. In contrast to the dry or alkane-saturated cell wall, the hydrated wall is not permeable to oils in the absence of a detergent. Oil droplets may be entrapped within the cells, yielding a stable dispersion of oil in water. As DF of the cellan type absorb bile acids, preferentially glycoconjugates, from diluted solutions, they may have a potential to decrease the serum cholesterol level. PMID:10194401

  4. n3- polyunsaturated Fat Acid Content of Some Edible Fish from Bahrain Waters

    NASA Astrophysics Data System (ADS)

    Al-Arrayedu, F. H.; Al Maskati, H. A.; Abdullah, F. J.

    1999-08-01

    This study was performed to determine the content of n3- polyunsaturated fatty acids in 10 fish species that are commonly consumed in Bahrain in addition to the main commercial shrimp species. White sardinella, which is a plankton feeder, had the highest content of n3- polyunsaturated fatty acids. It had the highest value of eicosapentaenoic acid (146.5 ± 20 mg 100 g-1) and linolenic acid (98.9±f 100 g-1) and the second highest value of docosahexaenoic acid at (133.7 ± 22 mg 100 g-1). Spanish mackerel which feeds mainly on sardinella was second with eicosapentaenoc acid at 55 ± 5.4 mg 100 g-1, docosahexaenoic acid at 161 ± 19.8 mg 100 g-1, linolenic acid at 16.4 mg 100 g-1 and docosapentaenoic acid at 25 ± 1.9 mg 100 g-1. Rabbitfish, the most popular edible fish in Bahrain which feeds mainly on benthic algae had the third highest content of n3- polyunsaturated fatty acids with eicosapentaenoic acid at 37.5 ± 3.9 mg 100 g-1, docosahexaenoic acid at 76 ± 6.7 mg 100 g-1, and docosapentaenoic acid at 85.8 ± 10 mg 100 g-1. The other fish and crustacean species studied were Arabian carpet shark, doublebar bream, grouper, gray grunt, golden travally, keeled mullet, spangled emperor and shrimp. The study explores the transfer of n3- polyunsaturated fatty acids through the food webs of the examined fish. It is apparent, generally, that plankton feeders displayed the highest content of n3- polyunsaturated fatty acids followed by seaweed and algae grazers, with benthic carnivores feeding on invertebrates displaying the poorest content. The values reported here, however, are much lower than those reported for fish available in American markets and in Mediterranean fish. Warm water temperature and high salinity which lead to lowering of the density of phytoplankton and phytoplankton content of n3- polyunsaturated fatty acids are suggested as the reason for the observed low values of n3- polyunsaturated fatty acids in Bahrain fish.

  5. Machine learning and hurdle models for improving regional predictions of stream water acid neutralizing capacity

    NASA Astrophysics Data System (ADS)

    Povak, Nicholas A.; Hessburg, Paul F.; Reynolds, Keith M.; Sullivan, Timothy J.; McDonnell, Todd C.; Salter, R. Brion

    2013-06-01

    In many industrialized regions of the world, atmospherically deposited sulfur derived from industrial, nonpoint air pollution sources reduces stream water quality and results in acidic conditions that threaten aquatic resources. Accurate maps of predicted stream water acidity are an essential aid to managers who must identify acid-sensitive streams, potentially affected biota, and create resource protection strategies. In this study, we developed correlative models to predict the acid neutralizing capacity (ANC) of streams across the southern Appalachian Mountain region, USA. Models were developed using stream water chemistry data from 933 sampled locations and continuous maps of pertinent environmental and climatic predictors. Environmental predictors were averaged across the upslope contributing area for each sampled stream location and submitted to both statistical and machine-learning regression models. Predictor variables represented key aspects of the contributing geology, soils, climate, topography, and acidic deposition. To reduce model error rates, we employed hurdle modeling to screen out well-buffered sites and predict continuous ANC for the remainder of the stream network. Models predicted acid-sensitive streams in forested watersheds with small contributing areas, siliceous lithologies, cool and moist environments, low clay content soils, and moderate or higher dry sulfur deposition. Our results confirmed findings from other studies and further identified several influential climatic variables and variable interactions. Model predictions indicated that one quarter of the total stream network was sensitive to additional sulfur inputs (i.e., ANC < 100 µeq L-1), while <10% displayed much lower ANC (<50 µeq L-1). These methods may be readily adapted in other regions to assess stream water quality and potential biotic sensitivity to acidic inputs.

  6. Impact of treatment processes on the removal of perfluoroalkyl acids from the drinking water production chain.

    PubMed

    Eschauzier, Christian; Beerendonk, Erwin; Scholte-Veenendaal, Petra; De Voogt, Pim

    2012-02-01

    The behavior of polyfluoralkyl acids (PFAAs) from intake (raw source water) to finished drinking water was assessed by taking samples from influent and effluent of the several treatment steps used in a drinking water production chain. These consisted of intake, coagulation, rapid sand filtration, dune passage, aeration, rapid sand filtration, ozonation, pellet softening, granular activated carbon (GAC) filtration, slow sand filtration, and finished drinking water. In the intake water taken from the Lek canal (a tributary of the river Rhine), the most abundant PFAA were PFBA (perfluorobutanoic acid), PFBS (perfluorobutane sulfonate), PFOS (perfluorooctane sulfonate), and PFOA (perfluorooctanoic acid). During treatment, longer chain PFAA such as PFNA (perfluorononanoic acid) and PFOS were readily removed by the GAC treatment step and their GAC effluent concentrations were reduced to levels below the limits of quantitation (LOQ) (0.23 and 0.24 ng/L for PFOS and PFNA, respectively). However, more hydrophilic shorter chain PFAA (especially PFBA and PFBS) were not removed by GAC and their concentrations remained constant through treatment. A decreasing removal capacity of the GAC was observed with increasing carbon loading and with decreasing carbon chain length of the PFAAs. This study shows that none of the treatment steps, including softening processes, are effective for PFAA removal, except for GAC filtration. GAC can effectively remove certain PFAA from the drinking water cycle.The enrichment of branched PFOS and PFOA isomers relative to non branched isomers during GAC filtration was observed during treatment. The finished water contained 26 and 19 ng/L of PFBA and PFBS. Other PFAAs were present in concentrations below 4.2 ng/L The concentrations of PFAA observed in finished waters are no reason for concern for human health as margins to existing guidelines are sufficiently large. PMID:22201258

  7. Regional characters of cloud water chemistry over severe acid rain areas of China

    SciTech Connect

    Zhilai Shen; Hui Xiao; Hengchi Lei; Meiyuan Huang

    1996-12-31

    The results and discussion are presented of measurements of cloud water chemistry made over severe add rain areas, such as Chongqing, Chengdu, Guiyang, Guangzhou, Nanchang, and Changsha in China from 1985 to 1993. Analyses indicate that acid cloud water is widespread in these areas, the range of cloud water pH is large within an area, the highest acidity is not over big city, and the difference of average values of pH is not obvious in different areas. In some areas, for example Chongqing, the annual variation of average pH is large. The range of average of total ion concentrations of cloud water is also large and the maximum is six more than minimum. The relationship between the acidity and ion concentration of cloud water is unlinear. The chemistry parameters of cloud water exhibit an obvious region character in Southwest China (Chongqing, Chengdu and Guiyang) SO4= is a dominant anion and SO4=/NO3- is more than 8, Ca++ and NH4+ are the main cation, Ca++/NH4+>1 (in the remaining areas, Ca++/NH4+<1), the cloud water acidity is higher than that of ground rain, indicating that there is an acidification process below cloud. In South China (Guangzhou and Guiyang) NO3 is same important as SO4= and SO4=/NO3- is about 1. In Central China (Nanchang and Changsha) the total ion concentration is highest on comparison with other areas and the value is more than that of ground rainwater, meaning probably that there is an influence of cloud microphysical process on cloud water and rainwater chemistry.

  8. Selective Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate

    SciTech Connect

    Yantasee, Wassana; Fryxell, Glen E.; Addleman, Raymond S.; Wiacek, Robert J.; Koonsiripaiboon, View; Pattamakomsan, Kanda; Sukwarotwat, Vichaya; Xu, Jide; Raymond, Kenneth N.

    2009-09-15

    The increased demand for the lanthanides in commercial products result in increased production of lanthanide containing ores, increasing public exposure to the lanthanides, both from various commercial products and from production wastes/effluents. This work investigates lanthanide (La, Ce, Pr, Nd, Eu, Gd, Lu) binding properties of self-assembled monolayers on mesoporous silica supports (SAMMS®) that were functionalized with diphosphonic acid (DiPhos), acetamide phosphonic acid (AcPhos), propionamide phosphonic acid (ProPhos), and 1-hydroxy-2-pyridinone (1,2-HOPO) from natural waters (river, ground, and sea waters), acid solutions (to mimic certain industrial process streams), and dialysate and compares their performance to a high surface area activated carbon. The properties include sorption affinity, capacity, and sorption kinetics. Stability and regenerability of SAMMS materials were also investigated. Going from the acid side over to the alkaline side, the AcPhos- and DiPhos-SAMMS maintain their outstanding affinity for lanthanides, which enable the use of the materials in the systems where the pH may fluctuate. While the activated carbon is as effective as 1,2-HOPO-SAMMS for capturing lanthanides in natural (alkaline) waters, it has no affinity in acid solutions (pH 2.4) and low affinity in carbonate-rich dialysate. Over 99% of 100 ug/L of Gd in dialysate was removed by the ProPhos-SAMMS after ten minutes. SAMMS can be regenerated with an acid wash (0.5 M HCl) without losing the binding properties, for a number of regeneration cycles. In acid solutions, PhoPhos- and 1,2-HOPO-SAMMS have differing affinity along the lanthanide series, suggesting their potential for chromatographic lanthanide separations. Thus, SAMMS materials have a great potential to be used as sorbents in large scale treatment of lanthanides, lanthanide separation prior to analytical instruments, and sorbent dialyzers for lanthanide clearances.

  9. Ultraspectral Infrared Measurements from the Atmospheric Infrared Sounder (AIRS) on the EOS Aqua Spacecraft

    NASA Technical Reports Server (NTRS)

    Pagano, Thomas

    2003-01-01

    Aqua measures the Earth's water cycle, energy fluxes, vegetation and temperatures. The Atmospheric Infrared Sounder (AIRS), Advanced Microwave Sounding Unit (AMSU) and Humidity Sounder for Brazil (HSB) were launched on the EOS Aqua spacecraft in May 2002. AIRS has had good radiometric and spectral sensitivity, stability, and accuracy and is suitable for climate studies. Temperature products compare well with radiosondes and models over the limited test range (|LAT| less than 40 degrees). Early trace gas products demonstrate the potential of AIRS. NASA is developing the next generation of hyperspectral IR imagers. JPL is ready to participate with US government agencies and US industry to transfer AIRS technology and science experience.

  10. The Stratospheric Aerosol and Gas Experiment III instrument proposed for EOS - A conceptual design

    NASA Technical Reports Server (NTRS)

    Mauldin, L. E.; Mccormick, M. P.; Zawodny, J. M.; Mcmaster, L. R.; Chu, W. P.; Gustafson, J. C.; Maddrea, G. L.

    1989-01-01

    This paper describes the Stratospheric Aerosol and Gas Experiment III (SAGE III) instrument proposed for the Earth Observing System (EOS), which is designed to monitor the vertical distribution of stratospheric aerosols, ozone, water vapor, nitrogen dioxide, and temperature by measuring the extinction and scattering of solar radiation in the 03 to 1.6 micron range through the atmosphere. The SAGE III employs proven concepts which have evolved from the SAM II, SAGE, and SAGE II programs. The launch is scheduled for the summer of 1996. The SAGE II block diagram is included.

  11. Disulfuric acid dissociated by two water molecules: ab initio and density functional theory calculations.

    PubMed

    Kim, Seong Kyu; Lee, Han Myoung; Kim, Kwang S

    2015-11-21

    We have studied geometries, energies and vibrational spectra of disulfuric acid (H2S2O7) and its anion (HS2O7(-)) hydrated by a few water molecules, using density functional theory (M062X) and ab initio theory (SCS-MP2 and CCSD(T)). The most noteworthy result is found in H2S2O7(H2O)2 in which the lowest energy conformer shows deprotonated H2S2O7. Thus, H2S2O7 requires only two water molecules, the fewest number of water molecules for deprotonation among various hydrated monomeric acids reported so far. Even the second deprotonation of the first deprotonated species HS2O7(-) needs only four water molecules. The deprotonation is supported by vibration spectra, in which acid O-H stretching peaks disappear and specific three O-H stretching peaks for H3O(+) (eigen structure) appear. We have also kept track of variations in several geometrical parameters, atomic charges, and hybrid orbital characters upon addition of water. As the number of water molecules added increases, the S-O bond weakens in the case of H2S2O7, but strengthens in the case of HS2O7(-). It implies that the decomposition leading to H2SO4 and SO3 hardly occurs prior to the 2nd deprotonation at low temperatures. PMID:26400266

  12. Mission Operations of EO-1 with Onboard Autonomy

    NASA Technical Reports Server (NTRS)

    Tran, Daniel Q.

    2006-01-01

    Space mission operations are extremely labor and knowledge-intensive and are driven by the ground and flight systems. Inclusion of an autonomy capability can have dramatic effects on mission operations. We describe the prior, labor and knowledge intensive mission operations flow for the Earth Observing-1 (EO-1) spacecraft as well as the new autonomous operations as part of the Autonomous Sciencecraft Experiment.

  13. Potential commercial uses of EOS remote sensing products

    NASA Technical Reports Server (NTRS)

    Thompson, Leslie L.

    1991-01-01

    The instrument complement of the Earth Observing System (EOS) satellite system will generate data sets with potential interest to a variety of users who are now just beginning to develop geographic information systems tailored to their special applications and/or jurisdictions. Other users may be looking for a unique product that enhances competitive position. The generally distributed products from EOS will require additional value added processing to derive the unique products desired by specific users. Entrepreneurs have an opportunity to create these proprietary level 4 products from the EOS data sets. Specific instruments or collections of instruments could provide information for crop futures trading, mineral exploration, television and printed medium news products, regional and local government land management and planning, digital map directories, products for third world users, ocean fishing fleet probability of harvest forecasts, and other areas not even imagined at this time. The projected level 3 product are examined that will be available at launch from EOS instruments and commercial uses of the data after value added processing is estimated.

  14. EOS Operations Systems: EDOS Implemented Changes to Reduce Operations Costs

    NASA Technical Reports Server (NTRS)

    Cordier, Guy R.; Gomez-Rosa, Carlos; McLemore, Bruce D.

    2007-01-01

    The authors describe in this paper the progress achieved to-date with the reengineering of the Earth Observing System (EOS) Data and Operations System (EDOS), the experience gained in the process and the ensuing reduction of ground systems operations costs. The reengineering effort included a major methodology change, applying to an existing schedule driven system, a data-driven system approach.

  15. Scaling the Pipe: NASA EOS Terra Data Systems at 10

    NASA Technical Reports Server (NTRS)

    Wolfe, Robert E.; Ramapriyan, Hampapuram K.

    2010-01-01

    Standard products from the five sensors on NASA's Earth Observing System's (EOS) Terra satellite are being used world-wide for earth science research and applications. This paper describes the evolution of the Terra data systems over the last decade in which the distributed systems that produce, archive and distribute high quality Terra data products were scaled by two orders of magnitude.

  16. EOS Aura and Future Satellite Studies of the Ozone Layer

    NASA Technical Reports Server (NTRS)

    Schoeberl, Mark R.

    2007-01-01

    The EOS Aura mission, launched in 2004, provides a comprehensive assessment of the stratospheric dynamics and chemistry. This talk will focus on results from Aura including the chemistry of polar ozone depletion. The data from Aura can be directly linked to UARS data to produce long term trends in stratospheric trace gases.

  17. Mission Status at Aura Science Team MOWG Meeting: EOS Aura

    NASA Technical Reports Server (NTRS)

    Fisher, Dominic

    2016-01-01

    Presentation at the 24797-16 Earth Observing System (EOS) Aura Science Team Meeting (Mission Operations Work Group (MOWG)) at Rotterdam, Netherlands August 29, 2016. Presentation topics include mission summary, spacecraft subsystems summary, recent and planned activities, spacecraft anomalies, data capture, propellant usage and lifetime estimates, spacecraft maneuvers and ground track history, mission highlights and past spacecraft anomalies and reliability estimates.

  18. Enhanced modeling and simulation of EO/IR sensor systems

    NASA Astrophysics Data System (ADS)

    Hixson, Jonathan G.; Miller, Brian; May, Christopher

    2015-05-01

    The testing and evaluation process developed by the Night Vision and Electronic Sensors Directorate (NVESD) Modeling and Simulation Division (MSD) provides end to end systems evaluation, testing, and training of EO/IR sensors. By combining NV-LabCap, the Night Vision Integrated Performance Model (NV-IPM), One Semi-Automated Forces (OneSAF) input sensor file generation, and the Night Vision Image Generator (NVIG) capabilities, NVESD provides confidence to the M&S community that EO/IR sensor developmental and operational testing and evaluation are accurately represented throughout the lifecycle of an EO/IR system. This new process allows for both theoretical and actual sensor testing. A sensor can be theoretically designed in NV-IPM, modeled in NV-IPM, and then seamlessly input into the wargames for operational analysis. After theoretical design, prototype sensors can be measured by using NV-LabCap, then modeled in NV-IPM and input into wargames for further evaluation. The measurement process to high fidelity modeling and simulation can then be repeated again and again throughout the entire life cycle of an EO/IR sensor as needed, to include LRIP, full rate production, and even after Depot Level Maintenance. This is a prototypical example of how an engineering level model and higher level simulations can share models to mutual benefit.

  19. Downlink Probability Density Functions for EOS-McMurdo Sound

    NASA Technical Reports Server (NTRS)

    Christopher, P.; Jackson, A. H.

    1996-01-01

    The visibility times and communication link dynamics for the Earth Observations Satellite (EOS)-McMurdo Sound direct downlinks have been studied. The 16 day EOS periodicity may be shown with the Goddard Trajectory Determination System (GTDS) and the entire 16 day period should be simulated for representative link statistics. We desire many attributes of the downlink, however, and a faster orbital determination method is desirable. We use the method of osculating elements for speed and accuracy in simulating the EOS orbit. The accuracy of the method of osculating elements is demonstrated by closely reproducing the observed 16 day Landsat periodicity. An autocorrelation function method is used to show the correlation spike at 16 days. The entire 16 day record of passes over McMurdo Sound is then used to generate statistics for innage time, outage time, elevation angle, antenna angle rates, and propagation loss. The levation angle probability density function is compared with 1967 analytic approximation which has been used for medium to high altitude satellites. One practical result of this comparison is seen to be the rare occurrence of zenith passes. The new result is functionally different than the earlier result, with a heavy emphasis on low elevation angles. EOS is one of a large class of sun synchronous satellites which may be downlinked to McMurdo Sound. We examine delay statistics for an entire group of sun synchronous satellites ranging from 400 km to 1000 km altitude. Outage probability density function results are presented three dimensionally.

  20. Synthesis of water soluble glycosides of pentacyclic dihydroxytriterpene carboxylic acids as inhibitors of α-glucosidase.

    PubMed

    Xu, Jiancong; Nie, Xuliang; Hong, Yanping; Jiang, Yan; Wu, Guoqiang; Yin, Xiaoli; Wang, Chunrong; Wang, Xiaoqiang

    2016-04-01

    A series of compounds were synthesized by glycosylation of maslinic acid (MA) and corosolic acid (CA) with monosaccharides and disaccharides, and the structures of the derivatives were elucidated by standard spectroscopic methods including (1)H NMR, (13)C NMR and HRMS. The α-glucosidase inhibitory activities of all the novel compounds were evaluated in vitro. The solubility and inhibitory activity of α-glucosidase assays showed that the bis-disaccharide glycosides of triterpene acids possessed higher water solubility and α-glucosidase inhibitory activities than the bis-monosaccharide glycosides. Among these compounds, maslinic acid bis-lactoside (8e, IC50 = 684 µM) and corosolic acid bis-lactoside (9e, IC50 = 428 µM) had the best water solubility, and 9e exhibited a better inhibitory activity than acarbose (IC50 = 478 µM). However, most of glycosylated derivatives possessed lower inhibitory activities than the parent compounds, although their water solubility was enhanced obviously. Moreover, the kinetic inhibition studies indicated that 9e was a non-competitive inhibitor, and structure-activity relationships of the derivatives are also discussed. PMID:26974355

  1. Water solubility enhancement of some organic pollutants and pesticides by dissolved humic and fulvic acids

    USGS Publications Warehouse

    Chiou, C.T.; Malcolm, R.L.; Brinton, T.I.; Kile, D.E.

    1986-01-01

    Water solubility enhancements by dissolved humic and fulvic acids from soil and aquatic origins and by synthetic organic polymers have been determined for selected organic pollutants and pesticides (p,p???-DDT, 2,4,5,2???,5???-PCB, 2,4,4???-PCB, 1,2,3-trichlorobenzene, and lindane). Significant solubility enhancements of relatively water-insoluble solutes by dissolved organic matter (DOM) of soil and aquatic origins may be described in terms of a partition-like interaction of the the solutes with the microscopic organic environment of the high-molecular-weight DOM species; the apparent solute solubilities increase linearly with DOM concentration and show no competitive effect between solutes. With a given DOM sample, the solute partition coefficient (Kdom) increases with a decrease of solute solubility (Sw) or with an increase of the solute's octanol-water partition coefficient (Kow). The Kdom values of solutes with soil-derived humic acid are approximately 4 times greater than with soil fulvic acid and 5-7 times greater than with aquatic humic and fulvic acids. The effectiveness of DOM in enhancing solute solubility appears to be largely controlled by the DOM molecular size and polarity. The relative inability of high-molecular-weight poly(acrylic acids) to enhance solute solubility is attributed to their high polarities and extended chain structures that do not permit the formation of a sizable intramolecular nonpolar environment.

  2. A computer program for geochemical analysis of acid-rain and other low-ionic-strength, acidic waters

    USGS Publications Warehouse

    Johnsson, P.A.; Lord, D.G.

    1987-01-01

    ARCHEM, a computer program written in FORTRAN 77, is designed primarily for use in the routine geochemical interpretation of low-ionic-strength, acidic waters. On the basis of chemical analyses of the water, and either laboratory or field determinations of pH, temperature, and dissolved oxygen, the program calculates the equilibrium distribution of major inorganic aqueous species and of inorganic aluminum complexes. The concentration of the organic anion is estimated from the dissolved organic concentration. Ionic ferrous iron is calculated from the dissolved oxygen concentration. Ionic balances and comparisons of computed with measured specific conductances are performed as checks on the analytical accuracy of chemical analyses. ARCHEM may be tailored easily to fit different sampling protocols, and may be run on multiple sample analyses. (Author 's abstract)

  3. EOS imaging versus current radiography: A health technology assessment study

    PubMed Central

    Mahboub-Ahari, Alireza; Hajebrahimi, Sakineh; Yusefi, Mahmoud; Velayati, Ashraf

    2016-01-01

    Background: EOS is a 2D/3D muscle skeletal diagnostic imaging system. The device has been developed to produce a high quality 2D, full body radiographs in standing, sitting and squatting positions. Three dimensional images can be reconstructed via sterEOS software. This Health Technology Assessment study aimed to investigate efficacy, effectiveness and cost-effectiveness of new emerged EOS imaging system in comparison with conventional x-ray radiographic techniques. Methods: All cost and outcome data were assessed from Iran's Ministry of Health Perspective. Data for clinical effectiveness was extracted using a rigorous systematic review. As clinical outcomes the rate of x-ray emission and related quality of life were compared with Computed Radiography (CR) and Digital Radiography (DR). Standard costing method was conducted to find related direct medical costs. In order to examine robustness of the calculated Incremental Cost Effectiveness Ratios (ICERs) we used two-way sensitivity analysis. GDP Per capita of Islamic Republic of Iran (2012) adopted as cost-effectiveness threshold. Results: Review of related literature highlighted the lack of rigorous evidence for clinical outcomes. Ultra low dose EOS imaging device is known as a safe intervention because of FDA, CE and CSA certificates. The rate of emitted X-ray was 2 to 18 fold lower for EOS compared to the conventional techniques (p<0.001). The Incremental Cost Effectiveness Ratio for EOS relative to CR calculated $50706 in baseline analysis (the first scenario) and $50714, $9446 respectively for the second and third scenarios. Considering the value of neither $42146 as upper limit, nor the first neither the second scenario could pass the cost-effectiveness threshold for Iran. Conclusion: EOS imaging technique might not be considered as a cost-effective intervention in routine practice of health system, especially within in-patient wards. Scenario analysis shows that, only in an optimum condition such as lower

  4. Recent disruption of an asteroid from the Eos family

    NASA Astrophysics Data System (ADS)

    Novaković, B.; Tsirvoulis, G.

    2014-07-01

    A key difficulty with searching for partially differentiated asteroids arises from the fact that a crust covers the exterior of the body, and, consequently, should hide the melted interior. This motivates an alternative approach of examining members of asteroid families, i.e., fragments of single large bodies, many of which were in the size regime capable of igneous differentiation, that have been disrupted by catastrophic collisions. Such families could provide a stratigraphic cross section across the interior of the parent asteroid [1]. With more than 10,000 known members, the Eos dynamical family is one of the most numerous and earliest recognized asteroid families [2]. Interestingly, the estimated ˜220-km-diameter parent body [3] is well within the size range capable of differentiation. Thus, existing family members should contain fragments of the deep interior. The Eos family has the highest diversity of taxonomic classes than any other known family [4]. Many members are of K spectral type, which is uncommon outside the family, and is similar to the spectra of CV, CK, CO, and CR carbonaceous chondrites [5]. This diversity leads to the suggestion that the Eos parent body was partially differentiated [4,6]. Thus, the Eos family may not only be a remnant of a partially differentiated parent body, but it could be the source of the CV-CK meteorite group. Here we report the discovery of a young subfamily of the Eos asteroid family. It may help understanding the mineralogical nature of the Eos asteroid family and of its parent body. By applying the hierarchical clustering method [7], we find an extremely compact 16-body cluster within the borders of the Eos family. We name the cluster (6733) 1992 EF, after its largest member. The statistical significance of this new cluster is estimated to be above 99%, indicating that its members share a common origin. All members of the cluster are found to be dynamically stable over long timescales. Backward numerical orbital

  5. Glucansucrases from lactic acid bacteria which produce water-insoluble polysaccharides from sucrose

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Dextrans and related glucans produced from sucrose by lactic acid bacteria have been studied for many years and are used in numerous commercial applications and products. Most of these glucans are water-soluble, except for a few notable exceptions from cariogenic Streptococcus spp. and a very small ...

  6. DISTRIBUTION OF HYDROPHOBIC IONOGENIC ORGANIC COMPOUNDS BETWEEN OCTANOL AND WATER: ORGANIC ACIDS

    EPA Science Inventory

    The octanol-water distributions of 10 environmentally significant organic acid compounds were determined as a function of aqueous-phase salt concentration (0.05-0.2 M LiCl, NaCl, KCl, CaCl2, or MgCl2) and pH. he compounds were pentachlorophenol 2,3,4,5-tetrachlorophenol, (2,4,5-t...

  7. Linking Laboratory Experiences to the Real World: The Extraction of Octylphenoxyacetic Acid from Water

    ERIC Educational Resources Information Center

    Loyo-Rosales, Jorge E.; Torrents, Alba; Rosales-Rivera, Georgina C.; Rice, Clifford C.

    2006-01-01

    Several chemical concepts to the extraction of a water pollutant OPC (octylphenoxyacetic acid) is presented. As an introduction to the laboratory experiment, a discussion on endocrine disrupters is conducted to familiarize the student with the background of the experiment and to explain the need for the extraction and quantitation of the OPC which…

  8. EFFECT OF SOIL PROCESSES ON THE ACIDIFICATION OF WATER BY ACID DEPOSITION

    EPA Science Inventory

    The mechanism whereby acid deposition can cause acidification of surface waters via equilibrium processes in soil solution was investigated using chemical equilibrium models. These models show that for soils with low to moderately low exchangeable bases the soil solution pH is on...

  9. REPRODUCTIVE AND GENOMIC EFFECTS IN TESTES FROM MICE EXPOSED TO THE WATER DISINFECTANT BYPRODUCT BROMOCHLOROACETIC ACID

    EPA Science Inventory

    ABSTRACT

    A byproduct of drinking water disinfection, bromochloroacetic acid (BCA), acts as a reproductive toxicant in rats. To determine if BCA produces similar reproductive toxicity in mice, juvenile and adult C57BL/6 males were exposed to 0, 8, 24, 72 or 216 mg/kg of BC...

  10. Sulfuric acid and hot water treatments enhance ex vitro and in vitro germination of Hibiscus seed

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Seeds of Hibiscus dasycalyx S. F. Blake & Shiller, a federally listed candidate endangered species and native to North America, and two variants of Hibiscus acetosella Welw. ex. Hiern were scarified using sulfuric acid and hot water. The effects of the scarification methods on in vitro and ex vitro ...

  11. PREDICTING THE PRECIPITATION OF ACID AND DIRECT DYES IN NATURAL WATERS

    EPA Science Inventory

    A simple screening test was used to determine whether acid and direct dyes precipitate at calcium concentrations typical of hard waters in the Southeastern Piedmont region of the United States. f 52 dyes tested, only three direct dyes (Direct Black 19, Direct Black 22, and Direct...

  12. VAPOR PRESSURE AND MELTING BEHAVIOR OF SULFURIC ACID-WATER SYSTEMS

    EPA Science Inventory

    An experimental apparatus was designed and constructed to use high vacuum and mass spectrometric techniques to determine total and partial vapor pressures above bulk liquid samples in the temperature range between -65C and 25C. Observations on the sulfuric acid-water system revea...

  13. LABORATORY EVALUATION OF ZERO-VALENT IRON TO TREAT WATER IMPACTED BY ACID MINE DRAINAGE

    EPA Science Inventory

    This study examines the applicability and limitations of granular zero-valent iron for the treatment of water impacted by mine wastes. Rates of acid neutralization and of metal (Cu, Cd, Ni, Zn, Hg, Al, and Mn) and metalloid (As) uptake were determined in batch systems using simu...

  14. Multifunctional water-soluble molecular capsules based on p-phosphonic acid calix[5]arene.

    PubMed

    Martin, Adam D; Boulos, Ramiz A; Hubble, Lee J; Hartlieb, Karel J; Raston, Colin L

    2011-07-14

    p-Phosphonic acid calix[5]arene forms molecular capsules in water based on two of the molecules, which can be loaded with carboplatin using intense shearing, and attached to single wall carbon nano-tubes. Spin coating of the capsules onto a substrate affords 2 nm fibres of stacked calixarenes, with the self-assembly understood using molecular modelling. PMID:21637889

  15. Direct injection analysis of fatty and resin acids in papermaking process waters by HPLC/MS.

    PubMed

    Valto, Piia; Knuutinen, Juha; Alén, Raimo

    2011-04-01

    A novel HPLC-atmospheric pressure chemical ionization/MS (HPLC-APCI/MS) method was developed for the rapid analysis of selected fatty and resin acids typically present in papermaking process waters. A mixture of palmitic, stearic, oleic, linolenic, and dehydroabietic acids was separated by a commercial HPLC column (a modified stationary C(18) phase) using gradient elution with methanol/0.15% formic acid (pH 2.5) as a mobile phase. The internal standard (myristic acid) method was used to calculate the correlation coefficients and in the quantitation of the results. In the thorough quality parameters measurement, a mixture of these model acids in aqueous media as well as in six different paper machine process waters was quantitatively determined. The measured quality parameters, such as selectivity, linearity, precision, and accuracy, clearly indicated that, compared with traditional gas chromatographic techniques, the simple method developed provided a faster chromatographic analysis with almost real-time monitoring of these acids. PMID:21360668

  16. Degradation of caffeic acid in subcritical water and online HPLC-DPPH assay of degradation products.

    PubMed

    Khuwijitjaru, Pramote; Suaylam, Boonyanuch; Adachi, Shuji

    2014-02-26

    Caffeic acid was subjected to degradation under subcritical water conditions within 160-240 °C and at a constant pressure of 5 MPa in a continuous tubular reactor. Caffeic acid degraded quickly at these temperatures; the main products identified by liquid chromatography-diode array detection/mass spectrometry were hydroxytyrosol, protocatechuic aldehyde, and 4-vinylcatechol. The reaction rates for the degradation of caffeic acid and the formation of products were evaluated. Online high-performance liquid chromatography/2,2-diphenyl-1-picryhydrazyl assay was used to determine the antioxidant activity of each product in the solution. It was found that the overall antioxidant activity of the treated solution did not change during the degradation process. This study showed a potential of formation of antioxidants from natural phenolic compounds under these subcritical water conditions, and this may lead to a discovering of novel antioxidants compounds during the extraction by this technique. PMID:24483598

  17. Acid precipitation: Effects on fresh water ecosystems. (Latest citations from the Life Sciences Collection database). Published Search

    SciTech Connect

    Not Available

    1993-05-01

    The bibliography contains citations concerning the effects of acidification on fresh water ecosystems. Algae and diatom distribution, survival and reproduction rates of specific fish species under acid lake conditions, and tolerance to stress caused by acidic conditions in fresh water ecosystems are studied. Effects of water pH on trace metal toxicity to fresh water organisms are briefly considered. Control and reduction of acidification are excluded from this bibliography. (Contains 250 citations and includes a subject term index and title list.)

  18. Oxidation and hydrolysis of lactic acid in near-critical water

    SciTech Connect

    Li, L.; Vallejo, D.; Gloyna, E.F.; Portela, J.R.

    1999-07-01

    Hydrothermal reactions (oxidation and hydrolysis) involving lactic acid (LA) were studied at temperatures ranging from 300 to 400 C and a nominal pressure of 27.6 MPa. Kinetic models were developed with respect to concentrations of LA and total organic carbon (TOC), respectively. On the basis of identified liquid and gaseous products, pathways for hydrothermal reactions involving lactic acid were proposed. Acetic acid and acetaldehyde were confirmed as the major liquid intermediates for oxidation and hydrolysis reactions, respectively. Carbon monoxide and methane were identified as the major gaseous byproducts from these reactions. These results demonstrate the potential of completely oxidizing, as well as converting, lactic acid into other organic products, in high-temperature water.

  19. Sequential Washing with Electrolyzed Alkaline and Acidic Water Effectively Removes Pathogens from Metal Surfaces

    PubMed Central

    Nakano, Yuichiro; Akamatsu, Norihiko; Mori, Tsuyoshi; Sano, Kazunori; Satoh, Katsuya; Nagayasu, Takeshi; Miyoshi, Yoshiaki; Sugio, Tomomi; Sakai, Hideyuki; Sakae, Eiji; Ichimiya, Kazuko; Hamada, Masahisa; Nakayama, Takehisa; Fujita, Yuhzo; Yanagihara, Katsunori; Nishida, Noriyuki

    2016-01-01

    Removal of pathogenic organisms from reprocessed surgical instruments is essential to prevent iatrogenic infections. Some bacteria can make persistent biofilms on medical devices. Contamination of non-disposable equipment with prions also represents a serious risk to surgical patients. Efficient disinfection of prions from endoscopes and other instruments such as high-resolution cameras remains problematic because these instruments do not tolerate aggressive chemical or heat treatments. Herein, we develop a new washing system that uses both the alkaline and acidic water produced by electrolysis. Electrolyzed acidic water, containing HCl and HOCl as active substances, has been reported to be an effective disinfectant. A 0.15% NaCl solution was electrolyzed and used immediately to wash bio-contaminated stainless steel model systems with alkaline water (pH 11.9) with sonication, and then with acidic water (pH 2.7) without sonication. Two bacterial species (Staphylococcus aureus and Pseudomonas aeruginosa) and a fungus (Candida albicans) were effectively removed or inactivated by the washing process. In addition, this process effectively removed or inactivated prions from the stainless steel surfaces. This washing system will be potentially useful for the disinfection of clinical devices such as neuroendoscopes because electrolyzed water is gentle to both patients and equipment and is environmentally sound. PMID:27223116

  20. Metabolic activity and symbiotic interactions of lactic acid bacteria and yeasts isolated from water kefir.

    PubMed

    Stadie, Jasmin; Gulitz, Anna; Ehrmann, Matthias A; Vogel, Rudi F

    2013-09-01

    Water kefir is a mildly sour and alcoholic drink fermented by a stable microbial multispecies community. With its high sugar content and low amino acid concentration water kefir medium represents a demanding habitat. In this ecological niche only well adapted microorganisms which are fit to the consortium are able to grow and mutually provide essential nutrients. The synergism between main representatives of water kefir yeasts and lactobacilli was studied in a co-culture model system. Co-cultivation of yeasts and lactobacilli in water kefir medium significantly increased cell yield of all interaction partners, delineating the interaction of these water kefir isolates as mutualism. The support of Zygotorulaspora (Z.) florentina was due to the acidification of the medium by the lactobacilli, whereas lactobacilli are improved in growth by the disposal of essential nutrients produced by yeasts. The trophic interaction between Lactobacillus (Lb.) hordei and yeasts is constituted by the release of amino acids and Vitamin B6 from yeasts, whereas Lb. nagelii is supported in growth by their production of amino acids. The interaction of Z. florentina and Lb. nagelii was further examined to reveal that co-cultivation induced the yeast to release arginine, which was essential for Lb. nagelii. PMID:23664259

  1. Sequential Washing with Electrolyzed Alkaline and Acidic Water Effectively Removes Pathogens from Metal Surfaces.

    PubMed

    Nakano, Yuichiro; Akamatsu, Norihiko; Mori, Tsuyoshi; Sano, Kazunori; Satoh, Katsuya; Nagayasu, Takeshi; Miyoshi, Yoshiaki; Sugio, Tomomi; Sakai, Hideyuki; Sakae, Eiji; Ichimiya, Kazuko; Hamada, Masahisa; Nakayama, Takehisa; Fujita, Yuhzo; Yanagihara, Katsunori; Nishida, Noriyuki

    2016-01-01

    Removal of pathogenic organisms from reprocessed surgical instruments is essential to prevent iatrogenic infections. Some bacteria can make persistent biofilms on medical devices. Contamination of non-disposable equipment with prions also represents a serious risk to surgical patients. Efficient disinfection of prions from endoscopes and other instruments such as high-resolution cameras remains problematic because these instruments do not tolerate aggressive chemical or heat treatments. Herein, we develop a new washing system that uses both the alkaline and acidic water produced by electrolysis. Electrolyzed acidic water, containing HCl and HOCl as active substances, has been reported to be an effective disinfectant. A 0.15% NaCl solution was electrolyzed and used immediately to wash bio-contaminated stainless steel model systems with alkaline water (pH 11.9) with sonication, and then with acidic water (pH 2.7) without sonication. Two bacterial species (Staphylococcus aureus and Pseudomonas aeruginosa) and a fungus (Candida albicans) were effectively removed or inactivated by the washing process. In addition, this process effectively removed or inactivated prions from the stainless steel surfaces. This washing system will be potentially useful for the disinfection of clinical devices such as neuroendoscopes because electrolyzed water is gentle to both patients and equipment and is environmentally sound. PMID:27223116

  2. Inhibition of nitrobenzene adsorption by water cluster formation at acidic oxygen functional groups on activated carbon.

    PubMed

    Kato, Yuichi; Machida, Motoi; Tatsumoto, Hideki

    2008-06-15

    The inhibition effect of nitrobenzene adsorption by water clusters formed at the acidic groups on activated carbon was examined in aqueous and n-hexane solution. The activated carbon was oxidized with nitric acid to introduce CO complexes and then outgassed in helium flow at 1273 K to remove them completely without changing the structural properties of the carbon as a reference adsorbent. The amounts of acidic functional groups were determined by applying Boehm titration. A relative humidity of 95% was used to adsorb water onto the carbon surface. Strong adsorption of water onto the oxidized carbon can be observed by thermogravimetric analysis. The adsorption kinetic rate was estimated to be controlled by diffusion from the kinetic analysis. Significant decline in both capacity and kinetic rate for nitrobenzene adsorption onto the oxidized carbon was also observed in n-hexane solution by preadsorption of water to the carbon surface, whereas it was not detected for the outgassed carbons. These results might reveal that water molecules forming clusters at the CO complexes inhibited the entrance of nitrobenzene into the interparticles of the carbon. PMID:18440013

  3. ANN modeling of water consumption in the lead-acid batteries

    NASA Astrophysics Data System (ADS)

    Karimi, Mohammad Ali; Karami, Hassan; Mahdipour, Maryam

    Due to importance of the quantity of water loss in the life cycle of lead-acid batteries, water consumption tests were performed on 72 lead-acid batteries with low antimony grid alloy at different charge voltages and temperatures. Weight loss of batteries was measured during a period of 10 days. The behavior of batteries in different charge voltages and temperatures were modeled by artificial neural networks (ANNs) using MATLAB 7 media. Four temperatures were used in the training set, out of which three were used in prediction set and one in validation set. The network was trained by training and prediction data sets, and then was used for predicting water consumption in all three temperatures of prediction set. Finally, the network obtained was verified while being used in predicting water loss in defined temperatures of validation set. To achieve a better evaluation of the model ability, three models with different validation temperatures were used (model 1 = 50 °C, model 2 = 60 °C and model 3 = 70 °C). There was a good agreement between predicted and experimental results at prediction and validation sets for all the models. Mean prediction errors in modeling charge voltage-temperature-time behavior in the water consumption quantity for models 1-3 were below 0.99%, 0.03%, and 0.76%, respectively. The model can be simply used by inexpert operators working in lead-acid battery industry.

  4. Concepts For An EO Land Convoy Mission

    NASA Astrophysics Data System (ADS)

    Cutter, M. A.; Eves, S.; Remedios, J.; Humpage, N.; Hall, D.; Regan, A.

    2013-12-01

    ESA are undertaking three studies investigating possible synergistic satellite missions flying in formation with the operational Copernicus Sentinel missions and/or the METOP satellites. These three studies are focussed on:- a) ocean and ice b) land c) atmosphere Surrey Satellite Technology Ltd (SSTL), the University of Leicester and Astrium Ltd are undertaking the second of these studies into the synergetic observation by missions flying in formation with European operational missions, focusing on the land theme. The aim of the study is to identify and develop, (through systematic analysis), potential innovative Earth science objectives and novel applications and services that could be made possible by flying additional satellites, (possibly of small-class type), in constellation or formation with one or more already deployed or firmly planned European operational missions, with an emphasis on the Sentinel missions, but without excluding other possibilities. In the long-term, the project aims at stimulating the development of novel, (smaller), mission concepts in Europe that may exploit new and existing European operational capacity in order to address in a cost effective manner new scientific objectives and applications. One possible route of exploitation would be via the proposed Small Mission Initiative (SMI) that may be initiated under the ESA Earth Explorer Observation Programme (EOEP). The following ESA science priority areas have been highlighted during the study [1]:- - The water cycle - The carbon cycle - Terrestrial ecosystems - Biodiversity - Land use and land use cover - Human population dynamics The study team have identified the science gaps that might be addressed by a "convoy" mission flying with the Copernicus Sentinel satellites, identified the candidate mission concepts and provided recommendations regarding the most promising concepts from a list of candidates. These recommendations provided the basis of a selection process performed by ESA

  5. Rigorous theoretical constraint on constant negative EoS parameter and its effect for the late Universe

    NASA Astrophysics Data System (ADS)

    Burgazli, Alvina; Eingorn, Maxim; Zhuk, Alexander

    2015-03-01

    In this paper, we consider the Universe at the late stage of its evolution and deep inside the cell of uniformity. At these scales, the Universe is filled with inhomogeneously distributed discrete structures (galaxies, groups and clusters of galaxies). Supposing that the Universe contains also the cosmological constant and a perfect fluid with a negative constant equation of state (EoS) parameter (e.g., quintessence, phantom or frustrated network of topological defects), we investigate scalar perturbations of the Friedmann-Robertson-Walker metrics due to inhomogeneities. Our analysis shows that, to be compatible with the theory of scalar perturbations, this perfect fluid, first, should be clustered and, second, should have the EoS parameter . In particular, this value corresponds to the frustrated network of cosmic strings. Therefore, the frustrated network of domain walls with is ruled out. A perfect fluid with neither accelerates nor decelerates the Universe. We also obtain the equation for the nonrelativistic gravitational potential created by a system of inhomogeneities. Due to the perfect fluid with , the physically reasonable solutions take place for flat, open and closed Universes. This perfect fluid is concentrated around the inhomogeneities and results in screening of the gravitational potential.

  6. Eosinophilic Esophagitis in Children and Adolescents with Abdominal Pain: Comparison with EoE-Dysphagia and Functional Abdominal Pain

    PubMed Central

    Gorla, Kiranmai; Gupta, Sandeep

    2016-01-01

    Aim. Compare EoE-AP with EoE-D for clinical, endoscopy (EGD), histology and outcomes and also with FAP-N. Method. Symptoms, physical findings, EGD, histology, symptom scores, and treatments were recorded for the three groups. Cluster analysis was done. Results. Dysphagia and abdominal pain were different in numbers but not statistically significant between EoE-AP and EoE-D. EGD, linear furrows, white exudates were more in the EoE-D and both combined were significant (p < 0.05). EoE-D, peak and mean eosinophils (p  0.06) and eosinophilic micro abscesses (p  0.001) were higher. Follow-Up. Based on single symptom, EoE-AP had 30% (p  0.25) improvement, EoE-D 86% (p < 0.001) and similar with composite score (p  0.57 and <0.001, resp.). Patients who had follow-up, EGD: 42.8% with EoE-AP and 77.8% with EoE-D, showed single symptom improvement and the eosinophil count fell from 38.5/34.6 (peak and mean) to 31.2/30.4 (p  0.70) and from 43.6/40.8 to 25.2/22.8 (p < 0.001), respectively. FAP-N patients had similar symptom improvement like EoE-D. Cluster Analysis. EoE-AP and FAP-N were similar in clinical features and response to treatment, but EoE-D was distinctly different from EoE-AP and FAP-N. Conclusion. Our study demonstrates that EoE-AP and EoE-D have different histology and outcomes. In addition, EoE-AP has clinical features similar to the FAP-N group. PMID:27610357

  7. Stimulation of water injection wells in the Los Angeles basin using sodium hypochlorite and mineral acids

    SciTech Connect

    Clementz, D.M.; Patterson, D.E.; Aseltine, R.J.; Young, R.E.

    1982-01-01

    A comprehensive stimulation program was developed to improve the injectivity and vertical coverage of water injection wells in the East Beverly Hills Hills and San Vicente Fields. In recent years the wells had low to zero injectivity and very limited vertical distribution of injected water as a result of formation damage, sand face plugging, and perforation blockage. A stimulaiton strategy was developed which sequentially removed this damage. It began with redesigning the central water plant to provide clean injection brine. The casing was mechanically cleaned. Near-wellbore solids were dissolved or loosened using hydrochloric acid and/or sodium hypochlorite (bleach); then, removed from the well by reverse circulating and suction washing. Remaining damage was treated with hydrochloric/hydrofluoric acid and bleach using circulation wash and selective squeeze techniques. Two- to three-fold improvements in injectivity after stimulation were common. Vertical distribution was typically improved from an initial 0-30% coverage to 85-95% after stimulation. 10 refs.

  8. Amino acids and proteins at ZnO-water interfaces in molecular dynamics simulations.

    PubMed

    Nawrocki, Grzegorz; Cieplak, Marek

    2013-08-28

    We determine potentials of the mean force for interactions of amino acids with four common surfaces of ZnO in aqueous solutions. The method involves all-atom molecular dynamics simulations combined with the umbrella sampling technique. The profiled nature of the density of water with the strongly adsorbed first layer affects the approach of amino acids to the surface and generates either repulsion or weak binding. The largest binding energy is found for tyrosine interacting with the surface in which the Zn ions are at the top. It is equal to 7 kJ mol(-1) which is comparable to that of the hydrogen bonds in a protein. This makes the adsorption of amino acids onto the ZnO surface much weaker than onto the well studied surface of gold. Under vacuum, binding energies are more than 40 times stronger (for one of the surfaces). The precise manner in which water molecules interact with a given surface influences the binding energies in a way that depends on the surface. Among the four considered surfaces the one with Zn at the top is recognized as binding almost all amino acids with an average binding energy of 2.60 kJ mol(-1). Another (O at the top) is non-binding for most amino acids. For binding situations the average energy is 0.66 kJ mol(-1). The remaining two surfaces bind nearly as many amino acids as they do not and the average binding energies are 1.46 and 1.22 kJ mol(-1). For all of the surfaces the binding energies vary between amino acids significantly: the dispersion in the range of 68-154% of the mean. A small protein is shown to adsorb onto ZnO only intermittently and with only a small deformation. Various adsorption events lead to different patterns in mobilities of amino acids within the protein. PMID:23836065

  9. Defluoridation of water using dicarboxylic acids mediated chitosan-polyaniline/zirconium biopolymeric complex.

    PubMed

    Muthu Prabhu, Subbaiah; Meenakshi, Sankaran

    2016-04-01

    The present investigation describes the preparation of hydrogen bonded chitosan-polyaniline/zirconium biopolymeric matrix by grafting method under dicarboxylic acid medium for the removal of fluoride, first time. Herein, the dicarboxylic acids, oxalic acid, malonic acid, succinic acid were used as medium. The synthesized complex was characterized by usual analytical techniques like FTIR, XRD, SEM and EDAX analysis. From the batch equilibrium experiments, the maximum defluoridation capacity (DC) was found to be 8.713 mg/g at room temperature with the minimum contact time of 24 min at 100mg of the sorbent dosage. The temperature study results of adsorption kinetics showed the adsorption behavior could be better described by the pseudo-second-order equation than pseudo-first-order kinetic model. The adsorption isotherm was well fitted by the Freundlich equation rather than Langmuir and D-R isotherms. The mechanism of fluoride removal was ligand exchange at neutral pH and electrostatic attraction at acidic pH of the medium. Regeneration studies were carried out to identify the best regenerant which makes the process cost-effective. Conclusions of this work demonstrate the potential applicability of the dicarboxylic acid mediated chitosan-polyaniline/zirconium complex as an effective adsorbent for fluoride removal from water. PMID:26706844

  10. Optimization of dilute acid pretreatment of water hyacinth biomass for enzymatic hydrolysis and ethanol production

    PubMed Central

    Idrees, Muhammad; Adnan, Ahmad; Sheikh, Shahzad; Qureshic, Fahim Ashraf

    2013-01-01

    The present study was conducted for the optimization of pretreatment process that was used for enzymatic hydrolysis of lignocellulosic biomass (Water Hyacinth, WH), which is a renewable resource for the production of bioethanol with decentralized availability. Response surface methodology has been employed for the optimization of temperature (oC), time (hr) and different concentrations of maleic acid (MA), sulfuric acid (SA) and phosphoric acid (PA) that seemed to be significant variables with P < 0.05. High F and R2 values and low P-value for hydrolysis yield indicated the model predictability. The pretreated biomass producing 39.96 g/l, 39.86 g/l and 37.9 g/l of reducing sugars during enzymatic hydrolysis with yield 79.93, 78.71 and 75.9 % from PA, MA and SA treated respectively. The order of catalytic effectiveness for hydrolysis yield was found to be phosphoric acid > maleic acid > sulfuric acid. Mixture of sugars was obtained during dilute acid pretreatment with glucose being the most prominent sugar while pure glucose was obtained during enzymatic hydrolysis. The resulting sugars, obtained during enzymatic hydrolysis were finally fermented to ethanol, with yield 0.484 g/g of reducing sugars which is 95 % of theoretical yield (0.51 g/g glucose) by using commercial baker's yeast (Sacchromyces cerveasiae). PMID:26417215

  11. Interaction of cinnamic acid derivatives with β-cyclodextrin in water: experimental and molecular modeling studies.

    PubMed

    Liu, Benguo; Zeng, Jie; Chen, Chen; Liu, Yonglan; Ma, Hanjun; Mo, Haizhen; Liang, Guizhao

    2016-03-01

    Cyclodextrins (CDs) can be used to improve the solubility and stability of cinnamic acid derivatives (CAs). However, there was no detailed report about understanding the effects of the substituent groups in the benzene ring on the inclusion behavior between CAs and CDs in aqueous solution. Here, the interaction of β-CD with CAs, including caffeic acid, ferulic acid, and p-coumaric acid, in water was investigated by phase-solubility method, UV, fluorescence, and (1)H NMR spectroscopy, together with ONIOM (our Own N-layer Integrated Orbital molecular Mechanics)-based QM/MM (Quantum Mechanics/Molecular Mechanics) calculations. Experimental results demonstrated that CAs could form 1:1 stoichiometric inclusion complex with β-CD by non-covalent bonds, and that the maximum apparent stability constants were found in caffeic acid (176M(-1)) followed by p-coumaric acid (160M(-1)) and ferulic acid (133M(-1)). Moreover, our calculations reasonably illustrated the binding orientations of β-CD with CAs determined by experimental observations. PMID:26471667

  12. Radiation grafting of acrylic and methacrylic acid to cellulose fibers to impart high water sorbency

    SciTech Connect

    Zahran, A.H.; Williams, J.L.; Stannett, V.T.

    1980-04-01

    Acrylic and methacrylic acids have been directly grafted to rayon and cotton using the preirradiation technique with /sup 60/ Co gamma rays. The rate of grafting increased with increasing temperature and monomer concentration, as did the final degree of grafting. The amount and rate of grafting also increased with the total irradiation dose but tended to level off at higher doses, in agreement with the leveling off of the radical content reported previously. Methacrylic acid grafted more and faster than acrylic acid to both rayon and cotton. Methacrylic acid grafted more with rayon than cotton, but acrylic acid gave somewhat similar yields with both fibers. The water abosrbency of the grafted fibers depended strongly on their posttreatment. Decrystallizing with 70% zinc chloride or with hot sodium hydroxidy developed supersorbency. The two treatments in succession, respectively, gave the highest values. Metacrylic acid brought about less sorbency than the corrsponding acrylic acid grafts. Useful levels of grafting and supersorbency could be readily and practically achieved by the methods described.

  13. Aircraft observations of water-soluble dicarboxylic acids in the aerosols over China

    NASA Astrophysics Data System (ADS)

    Zhang, Yan-Lin; Kawamura, Kimitaka; Qing Fu, Ping; Boreddy, Suresh K. R.; Watanabe, Tomomi; Hatakeyama, Shiro; Takami, Akinori; Wang, Wei

    2016-05-01

    Vertical profiles of dicarboxylic acids, related organic compounds and secondary organic aerosol (SOA) tracer compounds in particle phase have not yet been simultaneously explored in East Asia, although there is growing evidence that aqueous-phase oxidation of volatile organic compounds may be responsible for the elevated organic aerosols (OA) in the troposphere. Here, we found consistently good correlation of oxalic acid, the most abundant individual organic compounds in aerosols globally, with its precursors as well as biogenic-derived SOA compounds in Chinese tropospheric aerosols by aircraft measurements. Anthropogenically derived dicarboxylic acids (i.e., C5 and C6 diacids) at high altitudes were 4-20 times higher than those from surface measurements and even occasionally dominant over oxalic acid at altitudes higher than 2 km, which is in contrast to the predominance of oxalic acid previously reported globally including the tropospheric and surface aerosols. This indicates an enhancement of tropospheric SOA formation from anthropogenic precursors. Furthermore, oxalic acid-to-sulfate ratio maximized at altitudes of ˜ 2 km, explaining aqueous-phase SOA production that was supported by good correlations with predicted liquid water content, organic carbon and biogenic SOA tracers. These results demonstrate that elevated oxalic acid and related SOA compounds from both the anthropogenic and biogenic sources may substantially contribute to tropospheric OA burden over polluted regions of China, implying aerosol-associated climate effects and intercontinental transport.

  14. Uptake of Gas-Phase Nitric Acid by Water-Ice Surfaces

    NASA Astrophysics Data System (ADS)

    Ullerstam, M.; Abbatt, J. P.

    2004-05-01

    Nitric acid is a widespread molecule found in the atmosphere. It is mainly removed from the troposphere by wet or dry deposition. In colder regions such as the upper troposphere and tropopause where cirrus clouds are formed nitric acid can also be scavenged by cirrus ice particles. The uptake of gas-phase nitric acid by water-ice films has been re-examined with a coated-wall flow tube coupled to a chemical-ionization mass spectrometer (CIMS) at 228K. Previous flow tube studies of this system have shown little dependence of the uptake over the partial pressure regime studied. In these studies the initial, short-term uptake has been the focus and the long term uptake has not been quantified. In this experimental setup it was possible to study the uptake of nitric acid at lower partial pressures resulting in a more atmospherically appropriate determination of the adsorption isotherm and the long term uptake has also been addressed. Measurement of the initial uptake coefficient representing a lower limit will also be presented. Finally, possible burial of nitric acid into the bulk of the ice during continuous growth of the ice film has been studied. In the atmosphere ice particles will be subject to cycles of evaporation and condensation which could cause the nitric acid to be encapsulated into the particle, especially since the major part of the adsorption has been proven to be irreversible. This could enhance the ice particles capacity of scavenging nitric acid.

  15. Reactive Iron deposition and ground water inflow control neutralization processes in acidic mine lakes

    NASA Astrophysics Data System (ADS)

    Blodau, C.

    2002-12-01

    The controls on the internal neutralization of highly acidified waters by iron sulphide accumulation are yet poorly understood. To elucidate the influence of ground water inflow on neutralization processes, inventories of solid phase iron and sulphur, pore water profiles and rates of ferrous iron and sulphate production and consumption were analyzed in different areas of an acidic mine lake. Ground water inflow had previously been determined by ground water modelling and chamber measurements (Knoll et al., 1999). The investigated sediments adjacent to mine tailings, which were subject to the inflow of groundwater (10-30 L d-1 m-2), were richer in dissolved ferrous iron iron (30 vs. 5 mmol L-1) and sulphate (30 vs. 10 mmol L-1) and showed higher pH values (6 vs. 4) than the sediments in areas of the lake not being influenced by groundwater inflow. Sediments adjacent to the mine tailings also showed higher rates of sulphate reduction and iron sulphide accumulation (Fig. 1). From these data it is suggested that neutralization processes in iron rich, acidic mine lakes neutralization processes primarily occur in areas influenced by the inflow of acid mine groundwater. These waters usually have considerably higher pH values than the surface waters in the lakes due to buffering processes in the tailings. The seepage of this water through the sediment might thus lead to higher pH values and thus to a higher thermodynamic competitiveness of sulfate reduction vs. iron reduction (Blodau and Peiffer 2002). This causes increased neutralization rates. These findings have consequences for remediation measures in highly acidic lakes. In areas influenced by the inflow of mine drainage increases in carbon availability, for example by the deposition of particulate organic matter, should enhance iron sulphide formation rates, whereas in other areas increases in carbon availability would only result in enhanced rates of iron reduction without a lasting gain in alkalinity. Blodau, C

  16. Tribromopyrrole, brominated acids, and other disinfection byproducts produced by disinfection of drinking water rich in bromide.

    PubMed

    Richardson, Susan D; Thruston, Alfred D; Rav-Acha, Chaim; Groisman, Ludmila; Popilevsky, Inna; Juraev, Olga; Glezer, Victor; McKague, A Bruce; Plewa, Michael J; Wagner, Elizabeth D

    2003-09-01

    Using gas chromatography/mass spectrometry (GC/MS), we investigated the formation of disinfection byproducts (DBPs) from high bromide waters (2 mg/L) treated with chlorine or chlorine dioxide used in combination with chlorine and chloramines. This study represents the first comprehensive investigation of DBPs formed by chlorine dioxide under high bromide conditions. Drinking water from full-scale treatment plants in Israel was studied, along with source water (Sea of Galilee) treated under carefully controlled laboratory conditions. Select DBPs (trihalomethanes, haloacetic acids, aldehydes, chlorite, chlorate, and bromate) were quantified. Many of the DBPs identified have not been previously reported, and several of the identifications were confirmed through the analysis of authentic standards. Elevated bromide levels in the source water caused a significant shift in speciation to bromine-containing DBPs; bromoform and dibromoacetic acid were the dominant DBPs observed, with very few chlorine-containing compounds found. Iodo-trihalomethanes were also identified, as well as a number of new brominated carboxylic acids and 2,3,5-tribromopyrrole, which represents the first time a halogenated pyrrole has been reported as a DBP. Most of the bromine-containing DBPs were formed during pre-chlorination at the initial reservoir, and were not formed by chlorine dioxide itself. An exception wasthe iodo-THMs, which appeared to be formed by a combination of chlorine dioxide with chloramines or chlorine (either added deliberately or as an impurity in the chlorine dioxide). A separate laboratory study was also conducted to quantitatively determine the contribution of fulvic acids and humic acids (from isolated natural organic matter in the Sea of Galilee) as precursor material to several of the DBPs identified. Results showed that fulvic acid plays a greater role in the formation of THMs, haloacetic acids, and aldehydes, but 2,3,5-tribromopyrrole was produced primarily from humic

  17. Do cytostatic drugs reach drinking water? The case of mycophenolic acid.

    PubMed

    Franquet-Griell, Helena; Ventura, Francesc; Boleda, M Rosa; Lacorte, Silvia

    2016-01-01

    Mycophenolic acid (MPA) has been identified as a new river contaminant according to its wide use and high predicted concentration. The aim of this study was to monitor the impact of MPA in a drinking water treatment plant (DWTP) that collects water downstream Llobregat River (NE Spain) in a highly densified urban area. During a one week survey MPA was recurrently detected in the DWTP intake (17-56.2 ng L(-1)). The presence of this compound in river water was associated to its widespread consumption (>2 tons in 2012 in Catalonia), high excretion rates and low degradability. The fate of MPA in waters at each treatment step of the DWTP was analyzed and complete removal was observed after pretreatment with chlorine dioxide. So far, MPA has not been described as water contaminant and its presence associated with its consumption in anticancer treatments is of relevance to highlight the importance of monitoring this compound. PMID:26552545

  18. Equilibrium phase diagrams and water absorption properties of aqueous mixtures of malonic acid and inorganic salts.

    NASA Astrophysics Data System (ADS)

    Salcedo, D.; Salgado-Olea, G.

    2006-12-01

    Tropospheric aerosols are usually complex mixtures of inorganic and organic components. Although the thermodynamic properties of inorganic aerosols have been widely studied, the effect of organics on such properties is still under discussion. Solubility in water, water activity of aqueous solutions, deliquescence relative humidity (DRH), eutonic composition, and eutonic DRH were determined for bulk mixtures of malonic acid with ammonium sulfate, ammonium bisulfate, and ammonium nitrate at 25oC over the full range of composition (from 0 wt% to the solubility limit of the mixture components). The data was used to construct equilibrium phase diagrams, which show the phase of the mixtures as a function of total composition, dry mixture composition, water content, and ambient relative humidity. Measured water activity of liquid solutions was compared with an extended Zdanovskii-Stokes-Robinson (ZSR) expression, which then was used to predict water absorption of the mixtures.

  19. Systematic review of the association between dietary acid load, alkaline water and cancer

    PubMed Central

    Fenton, Tanis R; Huang, Tian

    2016-01-01

    Objectives To evaluate the evidence for a causal relationship between dietary acid/alkaline and alkaline water for the aetiology and treatment of cancer. Design A systematic review was conducted on published and grey literature separately for randomised intervention and observational studies with either varying acid–base dietary intakes and/or alkaline water with any cancer outcome or for cancer treatment. Outcome measures Incidence of cancer and outcomes of cancer treatment. Results 8278 citations were identified, and 252 abstracts were reviewed; 1 study met the inclusion criteria and was included in this systematic review. No randomised trials were located. No studies were located that examined dietary acid or alkaline or alkaline water for cancer treatment. The included study was a cohort study with a low risk of bias. This study revealed no association between the diet acid load with bladder cancer (OR=1.15: 95% CI 0.86 to 1.55, p=0.36). No association was found even among long-term smokers (OR=1.72: 95% CI 0.96 to 3.10, p=0.08). Conclusions Despite the promotion of the alkaline diet and alkaline water by the media and salespeople, there is almost no actual research to either support or disprove these ideas. This systematic review of the literature revealed a lack of evidence for or against diet acid load and/or alkaline water for the initiation or treatment of cancer. Promotion of alkaline diet and alkaline water to the public for cancer prevention or treatment is not justified. PMID:27297008

  20. State Agency Applications of EOS Data in Texas

    NASA Astrophysics Data System (ADS)

    Wells, G. L.

    2001-05-01

    Texas offers a good model for the introduction of remotely sensed data products into the daily operations of state agencies by virtue of its large size and population. The diversity of the Texas landscape coupled with the long distances traveled to perform site inspections place special burdens on the land resource agencies responsible for monitoring crop conditions, water availability, environmental hazards and other natural resource issues. To assist these agencies, the Texas Synergy team has adopted a two-phase approach that incorporates framework geospatial data products designed for the broad user community with remote sensing applications developed for user-specific analyses. A key element to the success of the effort is the development of remote sensing products within a Texas Reference Frame that corresponds to the components of the high-resolution National Spatial Data Infrastructure developed by the state, such as 1-meter CIR digital orthophotographs, digital elevation models, and vector layers for hypsography, hydrography, soils, transportation and boundaries. Users accustomed to working with NSDI products can easily begin to include recently-collected EOS data presented within the same reference frame. Examples of statewide data products made available through the Texas Synergy project are AVHRR NDVI and MODIS imagery, Landsat 7 ETM+ scenes and SPOT 10-meter panchromatic image tiles. Delivery of the products involves a number of mechanisms from CD distribution to Internet FTP downloads, but increasingly relies upon Internet map services, such as ESRI's ArcIMS. Beyond release of the base imagery products, the Texas Synergy team has worked with the Texas Parks and Wildlife Department, Texas Soil and Water Conservation Board, Texas Department of Agriculture, Texas Water Development Board, National Park Service and USDA Natural Resources Conservation Service on a wide range of data applications. Throughout 1999-2000, the magnitude of drought conditions was

  1. EFFECTS OF SULFURIC ACID RAIN ON MAJOR CATION AND SULFATE CONCENTRATIONS OF WATER PERCOLATING THROUGH TWO MODEL HARDWOOD FORESTS

    EPA Science Inventory

    Acid precipitation falls on vast areas of forested land, including most of the eastern deciduous forest of the United States. Forest productivity, ground-water quality, and surface waters might all be affected. To document and quantify ecosystem response to the onset of acid prec...

  2. Interaction of acid mine drainage with waters and sediments of West Squaw Creek in the West Shasta Mining District, California

    USGS Publications Warehouse

    Filipek, L.H.; Kirk, Nordstrom D.; Ficklin, W.H.

    1987-01-01

    Acid mine drainage has acidified large volumes of water and added high concentrations of dissolved heavy metals to West Squaw Creek, a California stream draining igneous rocks of low acid-neutralizing capacity. During mixing of the acid sulfate stream waters in the South Fork of West Squaw Creek with an almost equal volume of dilute uncontaminated water, Cu, Zn, Mn, and Al remained in solution rather than precipitating or adsorbing on solid phases. Changes in the concentration of these generally conservative metals could be used to determine relative flow volumes of acid tributaries and the main stream. An amorphous orange precipitate (probably ferric hydroxides or a mixture of ferric hydroxides and jarosite) was ubiquitous in the acid stream beds and was intimately associated with algae at the most acid sites. Relative sorption of cations decreased with decreasing water pH. However, arsenic was almost completely scavenged from solution within a short distance from the sulfide sources.

  3. Respiration of aquatic insect larvae (ephemeroptera, plecoptera) in acid mine water

    SciTech Connect

    Doherty, F.G.; Hummon, W.D.

    1980-09-01

    Ecotoxicology (Truhaut 1975) is the study of the harmful effects of natural substances and artificial pollutants experienced by organisms in the environment. The degree of response exhibited by an organism toward the presence of noxious substances can often be determined by monitoring a physiological parameter. One such parameter is respiration. The majority of studies dealing with the biological impact of acid mine drainage have been ecological surveys. No studies have been reported which deal with the physiological response of an organism to acid mine water other than acute toxicities of the various components expected in an effluent stream (Bell and Nebeker 1969; Kimmel and Hales 1973; Warnick and Bell 1969). These studies did not consider possible synergistic effects between individual components of acid mine water or the mode of action of pollutants involved. The work we report was undertaken to determine whether the toxic mode of action of an acid water effluent involves any aspect of the respiratory processes in three species of aquatic insect larvae. Although respirometry can be valuable in detecting signs of metabolic involvement, one must be aware that it is not a technique for the identification of specific toxic mechanisms.

  4. Effects of Solution Hydrodynamics on Corrosion Inhibition of Steel by Citric Acid in Cooling Water

    NASA Astrophysics Data System (ADS)

    Ashassi-Sorkhabi, H.; Asghari, E.; Mohammadi, M.

    2014-08-01

    Corrosion is a major problem in cooling water systems, which is often controlled using corrosion inhibitors. Solution hydrodynamics is one of the factors affecting corrosion inhibition of metals in these systems. The present work focuses on the study of the combined effects of citric acid concentration (as a green corrosion inhibitor) and fluid flow on corrosion of steel in simulated cooling water. Electrochemical techniques including Tafel polarization and electrochemical impedance spectroscopy were used for corrosion studies. Laminar flow was simulated using a rotating disk electrode. The effects of solution hydrodynamics on inhibition performance of citric acid were discussed. The citric acid showed low inhibition performance in quiescent solution; however, when the electrode rotated at 200 rpm, inhibition efficiency increased remarkably. It was attributed mainly to the acceleration of inhibitor mass transport toward metal surface. The efficiencies were then decreased at higher rotation speeds due to enhanced wall shear stresses on metal surface and separation of adsorbed inhibitor molecules. This article is first part of authors' attempts in designing green inhibitor formulations for industrial cooling water. Citric acid showed acceptable corrosion inhibition in low rotation rates; thus, it can be used as a green additive to the corrosion inhibitor formulations.

  5. Chemical constituents: water-soluble vitamins, free amino acids and sugar profile from Ganoderma adspersum.

    PubMed

    Kıvrak, İbrahim

    2015-01-01

    Ganoderma adspersum presents a rigid fruiting body owing to chitin content and having a small quantity of water or moisture. The utility of bioactive constituent of the mushroom can only be available by extraction for human usage. In this study, carbohydrate, water-soluble vitamin compositions and amino acid contents were determined in G. adspersum mushroom. The composition in individual sugars was determined by HPLC-RID, mannitol (13.04 g/100 g) and trehalose (10.27 g/100 g) being the most abundant sugars. The examination of water-soluble vitamins and free amino acid composition was determined by UPLC-ESI-MS/MS. Essential amino acid constituted 67.79% of total amino acid, which is well worth the attention with regard to researchers and consumers. In addition, G. adspersum, which is also significantly rich in B group vitamins and vitamin C, can provide a wide range of notable applications in the pharmaceutics, cosmetics, food and dietary supplement industries. G. adspersum revealed its value for pharmacy and nutrition fields. PMID:25169839

  6. Assembly of acid-functionalized single-walled carbon nanotubes at oil/water interfaces.

    PubMed

    Feng, Tao; Hoagland, David A; Russell, Thomas P

    2014-02-01

    The efficient segregation of water-soluble, acid-functionalized, single-walled carbon nanotubes (SWCNTs) at the oil/water interface was induced by dissolving low-molecular-weight amine-terminated polystyrene (PS-NH2) in the oil phase. Salt-bridge interactions between carboxylic acid groups of SWCNTs and amine groups of PS drove the assembly of SWCNTs at the interface, monitored by pendant drop tensiometry and laser scanning confocal microscopy. The impact of PS end-group functionality, PS and SWCNT concentrations, and the degree of SWCNT acid modification on the interfacial activity was assessed, and a sharp drop in interfacial tension was observed above a critical SWCNT concentration. Interfacial tensions were low enough to support stable oil/water emulsions. Further experiments, including potentiometric titrations and the replacement of SWCNTs by other carboxyl-containing species, demonstrated that the interfacial tension drop reflects the loss of SWCNT charge as the pH falls near/below the intrinsic carboxyl dissociation constant; species lacking multivalent carboxylic acid groups are inactive. The trapped SWCNTs appear to be neither ordered nor oriented. PMID:24443769

  7. Photon and Water Mediated Sulfur Oxide and Acid Chemistry in the Atmosphere of Venus

    NASA Astrophysics Data System (ADS)

    Kroll, Jay A.; Vaida, Veronica

    2014-06-01

    Sulfur compounds have been observed in the atmospheres of a number of planetary bodies in our solar system including Venus, Earth, Mars, Io, Europa, and Callisto. The global cloud cover on Venus located at an altitude between 50 and 80 kilometers is composed primarily of sulfuric acid (H_2SO_4) and water. Planetary photochemical models have attempted to explain observations of sulfuric acid and sulfur oxides with significant discrepancies remaining between models and observation. In particular, high SO_2 mixing ratios are observed above 90 km which exceed model predictions by orders of magnitude. Work recently done in the Vaida lab has shown red light can drive photochemistry through overtone pumping for acids like H_2SO_4 and has been successful in explaining much of the sulfur chemistry in Earth's atmosphere. Water can have a number of interesting effects such as catalysis, suppression, and anti-catalysis of thermal and photochemical processes. We investigate the role of water complexes in the hydration of sulfur oxides and dehydration of sulfur acids and present spectroscopic studies to document such effects. We investigate these reactions using FTIR and UV/Vis spectroscopy and will report on our findings.

  8. Acidic electrolyzed water efficiently improves the flavour of persimmon (Diospyros kaki L. cv. Mopan) wine.

    PubMed

    Zhu, Wanqi; Zhu, Baoqing; Li, Yao; Zhang, Yanyan; Zhang, Bolin; Fan, Junfeng

    2016-04-15

    The ability of acidic (AcW) and alkaline electrolyzed waters (AlW) to improve the flavour of persimmon (Diospyros kaki L.) wine was evaluated. Wines made with AcW (WAcW) were significantly better than wines made with AlW or pure water (PW) in aroma, taste, and colour. Volatile analysis showed that WAcW has high alcohol and ester contents, including 2-phenylethanol, isopentanol, isobutanol, ethyl dodecanoate, phenethyl acetate, and butanedioic acid diethyl ester. The total amino acid content of persimmon slurry soaked with AcW reached 531.2 mg/l, which was much higher than those of the slurries soaked in AlW (381.3 mg/l) and PW (182.7 mg/l). The composition of major amino acids in the AcW-soaked slurry may contribute to the strong ester flavour of WAcW. This is the first report to suggest that electrolyzed functional water (EFW) can be used to improve wine flavour, leading to the possible use of EFW in food processing. PMID:26616934

  9. Ground-water quality, water year 1995, and statistical analysis of ground-water-quality data, water years 1994-95, at the Chromic Acid Pit site, US Army Air Defense Artillery Center and Fort Bliss, El Paso, Texas

    USGS Publications Warehouse

    Abeyta, Cynthia G.; Roybal, R.G.

    1996-01-01

    The Chromic Acid Pit site is an inactive waste disposal site that is regulated by the Resource Conservation and Recovery Act of 1976. The 2.2-cubic-yard cement-lined pit was operated from 1980 to 1983 by a contractor to the U.S. Army Air Defense Artillery Center and Fort Bliss. The pit, located on the Fort Bliss military reservation in El Paso, Texas, was used for disposal and evaporation of chromic acid waste generated from chrome plating operations. The site was closed in 1989, and the Texas Natural Resources Conservation Commission issued permit number HW-50296 (U.S. Environmental Protection Agency number TX4213720101), which approved and implemented post-closure care for the Chromic Acid Pit site. In accordance with an approved post-closure plan, the U.S. Geological Survey is cooperating with the U.S. Army in monitoring and evaluating ground-water quality at the site. One upgradient ground-water monitoring well (MW1) and two downgradient ground-water monitoring wells (MW2 and MW3), installed adjacent to the chromic acid pit, are monitored on a quarterly basis. Ground-water sampling of these wells by the U.S. Geological Survey began in December 1993. The ground-water level, measured in a production well located approximately 1,700 feet southeast of the Chromic Acid Pit site, has declined about 29.43 feet from 1982 to 1995. Depth to water at the Chromic Acid Pit site in September 1995 was 284.2 to 286.5 feet below land surface; ground-water flow at the water table is assumed to be toward the southeast. Ground-water samples collected from monitoring wells at the Chromic Acid Pit site during water year 1995 contained dissolved- solids concentrations of 481 to 516 milligrams per liter. Total chromium concentrations detected above the laboratory reporting limit ranged from 0.0061 to 0.030 milligram per liter; dissolved chromium concentrations ranged from 0.0040 to 0.010 milligram per liter. Nitrate as nitrogen concentrations ranged from 2.1 to 2.8 milligrams per

  10. Architecture analysis for European Long-Term Archiving EO systems

    NASA Astrophysics Data System (ADS)

    Garcia Gil, I.; Perez Moreno, R.; Perez Navarro, O.; Leone, R.

    2012-04-01

    Over the last ten years there has been a strongly increased need for access to historical Earth Observation (EO) data series, mainly for long term science and environmental monitoring applications. As the contents of EO space data archives increases from a few years duration to a period of decades their scientific values increases dramatically. The main objective of this Long Term Data Preservation(LTDP) initiative is to guarantee the long term preservation of the data from all EO ESA and Third Parties ESA managed missions, while also ensuring their accessibility and usability, as part of a joint and cooperative approach in Europe aimed at preserving the EO European data from member states' missions. To allow the maximum value to be extracted from the data, it is well recognized that there is a need to preserve this data without time limitations, while keeping all archived data accessible and exploitable. This will be even more of a challenge in the coming years, as the large number of upcoming Earth Observation missions will lead to a major increase in the available volume of EO data The LTDP Impact Analysis and Architecture Definition project (for simplicity known as LTDP-IMPACTS) aims to define and consolidate the architecture of European Long-Term Archiving EO systems, especially in the context of ESA PDGS. To do this, we shall perform a complete assessment of the impacts of implementing the guidelines from the LTDP initiative. This assessment will be over all timescales, short, middle and long-term, and must take into account all systems involved, from the point of view of "System of System" (SoS), and their data flows, data sets and their related operational policies for LTDP implementation The LTDP guidelines, and the standards adopted as a result, will have various impacts on the legacy and future long term archiving systems, the systems used to access them, and on the overall operational concept. This will particularly apply to the ESA PDGS environment

  11. Water O-H stretching Raman signature for strong acid monitoring via multivariate analysis.

    PubMed

    Casella, Amanda J; Levitskaia, Tatiana G; Peterson, James M; Bryan, Samuel A

    2013-04-16

    A distinct need exists for real time information on an acid concentration of industrial aqueous streams. Acid strength affects efficiency and selectivity of many separation processes, including nuclear fuel reprocessing. Despite the seeming simplicity of the problem, no practical solution has been offered yet, particularly for the large-scale schemes involving toxic streams such as highly radioactive nuclear wastes. The classic potentiometric technique is not amiable for online measurements due to the requirements of frequent calibration/maintenance and poor long-term stability in aggressive chemical and radiation environments. Therefore, an alternative analytical method is needed. In this work, the potential of using Raman spectroscopic measurements for online monitoring of strong acid concentration in solutions relevant to dissolved used nuclear fuel was investigated. The Raman water signature was monitored for solution systems containing nitric and hydrochloric acids and their sodium salts of systematically varied composition, ionic strength, and temperature. The trivalent neodymium ion simulated the presence of multivalent f metals. The gaussian deconvolution analysis was used to interpret observed effects of the solution nature on the Raman water O-H stretching spectrum. The generated Raman spectroscopic database was used to develop predictive multivariate regression models for the quantification of the acid and other solution components, as well as selected physicochemical properties. This method was validated using independent experiments conducted in a flow solvent extraction system. PMID:23472939

  12. 76 FR 15224 - Reducing Regulatory Burden; Retrospective Review Under E.O. 13563

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-03-21

    ...: E.O. 13653, 76 FR 3821, Jan. 21, 2011; E.O. 12866, 58 FR 51735, Oct. 4, 1993. Dated: March 15, 2011... how the Department can foster, promote, and develop the welfare of the wage earners, job seekers,...

  13. 76 FR 10526 - Reducing Regulatory Burden; Retrospective Review Under E.O. 13563

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-02-25

    ...? Please identify specific regulations and guidance that are good candidates for a plain language re-write.... Authority: E.O. 13653, 76 FR 3821, Jan. 21, 2011; E.O. 12866, 58 FR 51735, Oct. 4, 1993. Dated: February...

  14. EO-199, a specific antagonist of antiarrhythmic drugs: Assessment by binding experiments and in vivo studies

    SciTech Connect

    Oppenheimer, E.; Harel, G.; Lipinsky, D.; Sarne, Y. )

    1991-01-01

    EO-199, a demethylated analog of the novel class I antiarrhythmic drug EO-122 was found to antagonize the antiarrhythmic activity of EO-122 and that of procainamide (Class I{sub A}). EO-199 did not block significantly the activity of a class I{sub B} antiarrhythmic agent, lidocaine. EO-199 also displaced the specific binding of ({sup 3}H)EO-122 to rate heart membranes similarly to procainamide whereas lidocaine did not. The correlation between binding experiments and pharmacological effects points to a possible subclassification of these drugs; the two chemical analogs EO-199 and EO-122, as well as procainamide (I{sub A}) but not lidocaine (I{sub B}), compete at the same site or the same state of the sodium channel. The availability of a specific antagonist might be useful for studying the mechanism of action of antiarrhythmic drugs as well as an antidote in cases of antiarrhythmics overdose intoxication.

  15. Effects of acid mine drainage on water, sediment and associated benthic macroinvertebrate communities

    SciTech Connect

    Rutherford, L.G.; Cherry, D.S.; Dobbs, M.G.; Cairns, J. Jr.; Zipper, C.E.

    1995-12-31

    The toxic constituents of abandoned mined land (AML) discharges (acidic pH, heavy metals, total suspended solids) are extremely toxic to aquatic life . Studies were undertaken to ascertain environmental impacts to the upper Powell River, Lee and Wise Counties, Va. These impacts included disruptions in physical water quality, sediment quality, altered benthic macroinvertebrate assemblages, and toxicity of the water column and sediments from short-term impairment bioassays, and the potential to bioaccumulate selected metals (Al, Fe, Mn, P, Zn, Cu, Mg, S, Ni, Cd) by periphyton and resident bivalves. Water chemistry and macroinvertebrate assemblages were collected at upstream control, just below acid mine drainage and other downstream sites. Selected trace metal concentrations (Al, Fe, Mn, P, Zn, Cu, Mg, S, Ni, Cd) were determined for water, sediment and resident bivalves using ICP-AES. Acidic pH ranged from 2.15--3.3 at three AML-influenced seeps and varied from 6.4--8.0 at reference stations. At one AML-influenced creek, acidic pH conditions worsened from summer to fall and eradicated aquatic life throughout a 1.5 km stretch of that creek as it flowed into another creek. An additional dilution of 3.4 km in the second creek was needed to nearly neutralize the acidic pH problem. Conductivity (umhos/cm) ranged from 32--278 at reference sites and from 245--4,180 at AML-impact sites. Benthic macroinvertebrate abundance and taxon richness were essentially eliminated in the seeps or reached numbers of 1 -3 taxa totaling < 10 organisms relative to reference areas where richness values were 12--17 and comprised 300--977 organisms. Concentrations of Fe, Al, Mg and Cu and Zn were highest in the environmentally stressed stations of low pH and high conductivity relative to the reference stations. Iron was, by far, the element in highest concentration followed by Al and Mg.

  16. Remediation and selective recovery of metals from acidic mine waters using novel modular bioreactors.

    PubMed

    Hedrich, Sabrina; Johnson, D Barrie

    2014-10-21

    Mine waters are widely regarded as environmental pollutants, but are also potential sources of valuable metals. Water draining the Maurliden mine (Sweden) is highly acidic (pH 2.3) and rich in zinc (∼ 460 mg L(-1)) and iron (∼ 400 mg L(-1)), and contains smaller concentrations (0.3-49 mg L(-1)) of other transition metals and arsenic. We have developed novel techniques that promote the concurrent amelioration of acidic waste waters and selective recovery of metals, and have used these systems to treat synthetic Maurliden mine water in the laboratory. The two major metals present were removed via controlled biomineralization: zinc as ZnS in a sulfidogenic bioreactor, and iron as schwertmannite by microbial iron oxidation and precipitation of ferric iron. A small proportion (∼ 11%) of the schwertmannite produced was used to remove arsenic as the initial step in the process, and other chalcophilic metals (copper, cadmium and cobalt) were removed (as sulfides) in the stage 1 metal sulfide precipitation reactor. Results from this work have demonstrated that modular biomineralization units can be effective at processing complex mine waters and generating metal products that may be recycled. The economic and environmental benefits of using an integrated biological approach for treating metal-rich mine waters is discussed. PMID:25251612

  17. The removal of kaolinite suspensions by acid-soluble and water-soluble chitosans.

    PubMed

    Chung, Ying-Chien; Wu, Li-Chun; Chen, Chih-Yu

    2013-01-01

    Chitosan is a potential substitute for traditional aluminium salts in water treatment systems. This research compared the coagulant performance of acid-soluble chitosan with water-soluble chitosan and with coagulant mixtures of chitosan and aluminium sulfate (alum). We also assessed the coagulant performance of chitosan and poly-aluminium chloride (PAC) to remove kaolinite from turbid water. In addition, we evaluated their respective coagulation efficiencies under different coagulant concentrations, degrees of turbidity (NTU) and pH levels. Furthermore, we determined the size and settling velocity of flocs formed by these coagulants in order to illustrate major factors affecting kaolinite coagulation. The optimal concentrations of acid- versus water- soluble chitosan required to remove kaolinite from a 300 NTU suspension were 4.0 and 10.0 mg/l, respectively-with individual efficiencies of 79.3 and 92.4%, in that order. Optimum concentrations ofwater-soluble chitosan demonstrated a broader range than that of acid-soluble chitosan. In addition, it is of note that chitosan/alum and chitosan/PAC water-soluble coagulant mixtures demonstrated much wider ranges of optimal concentrations for turbidity reduction than either alum or PAC alone. Moreover, our water-soluble chitosan coagulant mixtures produced denser floc with elevated settling velocities that favour cost savings relevant to both installation and operational expenses. Based on our observations of these noteworthy performances, we confidently propose that a coagulant mixture with a 1:1 mass ratio of chitosan and alum presents a remarkably more cost-effective alternative to the use of chitosan alone in water treatment systems. PMID:23530342

  18. Assessing the capability of EOS sensors in measuring ocean-atmosphere moisture exchange

    NASA Technical Reports Server (NTRS)

    Liu, W. T.

    1985-01-01

    As part of the Science Synergism Studies to identify interdisciplinary Scientific studies, which could be addressed by the Environmental Observing System (EOS), the techniques being developed to measure ocean-atmosphere moisture exchanges using satellite sensors were evaluated. Studies required to use sensors proposed for EOS were examined. A method has been developed to compute the moisture flux using the wind speed, sea surface temperature, and preciptable water measured by satellite sensors. It relies on a statistical model which predicts surface-level humidity from precipitable water. The Scanning Multichannel Microwave Radiometer (SMMR) measures all 3 parameters and was found to be sensitive to the annual cycle and large interannual variations such as the 1982 to 1983 El Nino. There are systematic differences between geophysical parameters measured by Nimbus/SMMR and in situ measurements. After quadratic trends and crosstalks were removed from the parameters through multivariate regressions, the latent heat fluxes computed from SMMR agree with those computed from ship reports to within 30 W/sq m. The poor quality of ship reports may be the cause of a portion of this scatter. Similar results are found using SEASAT/SMMR data. When the scatterometer winds were used instead of the SMMR winds, the difference between the satellite fluxes and the ship fluxes was reduced.

  19. Heterogeneous chemical reaction of chlorine nitrate and water on sulfuric-acid surfaces at room temperature

    NASA Astrophysics Data System (ADS)

    Rossi, Michel J.; Malhotra, Ripudaman; Golden, David M.

    1987-02-01

    It has been demonstrated that the reaction between gaseous chlorine nitrate and water on room temperature liquid sulfuric acid (95.6%) surfaces yields hypochlorous acid in the gas phase. First-order loss rate constants for chlorine nitrate (equivalent to a value of the sticking coefficient γ = 3.2 × 10-4) have been determined. This value is five orders-of-magnitude greater than reported values on similar areas of more inert surfaces. Application of results of this type to stratospheric models must await ongoing studies at lower temperatures.

  20. Recovery of Zn from acid mine water and electric arc furnace dust in an integrated process.

    PubMed

    Carranza, Francisco; Romero, Rafael; Mazuelos, Alfonso; Iglesias, Nieves

    2016-01-01

    In this paper, the purification of acid mine water and the treatment of electric arc furnace dust (EAFD) are integrated into one process with the aim of recovering the Zn content of both effluent and waste. Zinc recovery can reduce the cost of their environmental management: purified acid mine water is discharged after removing all metals; EAFD ceases to be hazardous waste; and Zn is valorised. The process consists of the recovery of Zn as zinc oxide and its purification into commercial products. First, EAFD is leached with acid water and the dissolved metals are selectively precipitated as hydroxides. After EADF leaching, ferrous iron is bio-oxidized and Fe and Al are then precipitated; in the following stage, Cu, Ni, Co and Cd are cemented and finally Zn is precipitated as ZnO. In order to purify water that finally is discharged to a river, lime is used as the neutralizing agent, which results in a precipitate of mainly gypsum, MnO, and ZnO. From the impure zinc oxide produced, various alternatives for the attainment of commercial products, such as basic zinc carbonate and electrolytic zinc, are studied in this work. PMID:26433358

  1. Development and operation of a hybrid acid-alkaline advanced water electrolysis cell

    NASA Astrophysics Data System (ADS)

    Teschke, O.; Zwanziger, M.

    A hybrid acid-alkaline water electrolysis cell has been developed for hydrogen production. The cell is based on the use of an acidic solution at the cathode and a basic solution at the anode to reduce the minimum theoretical voltage for water decomposition from the thermoneutral potential of 1.47 V to close to 1.4 V at 25 C and 1 atm. The pH differential is maintained by the removal of OH ions from the cathode section and water removal from the anode section, which can be driven by heat energy. A practical cell has been built using a solid polymer electrolyte in which, however, the cathodic compartment is not acidic but neutral. Tests with a platinum black cathode catalyst and a platinum-iridium anode catalyst have resulted in steady-state water hydrolysis at an applied voltage of 0.9 V, and a V-I diagram with a considerably lower slope than that of a conventional cell has been obtained at 90 C.

  2. Changes in water quality following tidal inundation of coastal lowland acid sulfate soil landscapes

    NASA Astrophysics Data System (ADS)

    Johnston, Scott G.; Bush, Richard T.; Sullivan, Leigh A.; Burton, Edward D.; Smith, Douglas; Martens, Michelle A.; McElnea, Angus E.; Ahern, R., , Col; Powell, Bernard; Stephens, Luisa P.; Wilbraham, Steve T.; van Heel, Simon

    2009-01-01

    This study examines the remediation of surface water quality in a severely degraded coastal acid sulfate soil landscape. The remediation strategy consisted of partial restoration of marine tidal exchange within estuarine creeks and incremental tidal inundation of acidified soils, plus strategic liming of drainage waters. Time-series water quality and climatic data collected over 5 years were analysed to assess changes in water quality due to this remediation strategy. A time-weighted rainfall function (TWR) was generated from daily rainfall data to integrate the effects of antecedent rainfall on shallow groundwater levels in a way that was relevant to acid export dynamics. Significant increases in mean pH were evident over time at multiple monitoring sites. Regression analysis at multiple sites revealed a temporal progression of change in significant relationships between mean daily electrical conductivity (EC) vs. mean daily pH, and TWR vs. mean daily pH. These data demonstrate a substantial decrease over time in the magnitude of creek acidification per given quantity of antecedent rainfall. Data also show considerable increase in soil pH (2-3 units) in formerly acidified areas subject to tidal inundation. This coincides with a decrease in soil pe, indicating stronger reducing conditions. These observations suggest a fundamental shift has occurred in sediment geochemistry in favour of proton-consuming reductive processes. Combined, these data highlight the potential effectiveness of marine tidal inundation as a landscape-scale acid sulfate soil remediation strategy.

  3. Elemental and spectroscopic characterization of fractions of an acidic extract of oil sands process water.

    PubMed

    Jones, D; Scarlett, A G; West, C E; Frank, R A; Gieleciak, R; Hager, D; Pureveen, J; Tegelaar, E; Rowland, S J

    2013-11-01

    'Naphthenic acids' (NAs) in petroleum produced water and oil sands process water (OSPW), have been implicated in toxicological effects. However, many are not well characterized. A method for fractionation of NAs of an OSPW was used herein and a multi-method characterization of the fractions conducted. The unfractionated OSPW acidic extract was characterized by elemental analysis, electrospray ionization-Orbitrap-mass spectrometry (ESI-MS), and an esterified extract by Fourier Transform infrared (FTIR) and ultraviolet-visible (UV) absorption spectroscopy and by comprehensive multidimensional gas chromatography-MS (GCxGC-MS). Methyl esters were fractionated by argentation solid phase extraction (Ag(+) SPE) and fractions eluting with: hexane; diethyl ether: hexane and diethyl ether, examined. Each was weighed, examined by elemental analysis, FTIR, UV, GC-MS and GCxGC-MS (both nominal and high resolution MS). The ether fraction, containing sulfur, was also examined by GCxGC-sulfur chemiluminescence detection (GCxGC-SCD). The major ions detected by ESI-MS in the OSPW extract were assigned to alicyclic and aromatic 'O2' acids; sulfur was also present. Components recovered by Ag(+) SPE were also methyl esters of alicyclic and aromatic acids; these contained little sulfur or nitrogen. FTIR spectra showed that hydroxy acids and sulfoxides were absent or minor. UV spectra, along with the C/H ratio, further confirmed the aromaticity of the hexane:ether eluate. The more minor ether eluate contained further aromatics and 1.5% sulfur. FTIR spectra indicated free carboxylic acids, in addition to esters. Four major sulfur compounds were detected by GCxGC-SCD. GCxGC-high resolution MS indicated these were methyl esters of C18 S-containing, diaromatics with ≥C3 carboxylic acid side chains. PMID:23856466

  4. Selective removal of lanthanides from natural waters, acidic streams and dialysate.

    PubMed

    Yantasee, Wassana; Fryxell, Glen E; Addleman, R Shane; Wiacek, Robert J; Koonsiripaiboon, View; Pattamakomsan, Kanda; Sukwarotwat, Vichaya; Xu, Jide; Raymond, Kenneth N

    2009-09-15

    The increased demand for the lanthanides in commercial products result in increased production of lanthanide containing ores, which increases public exposure to the lanthanides, both from various commercial products and from production wastes/effluents. This work investigates lanthanide (La, Ce, Pr, Nd, Eu, Gd and Lu) binding properties of self-assembled monolayers on mesoporous silica supports (SAMMS), that were functionalized with diphosphonic acid (DiPhos), acetamide phosphonic acid (AcPhos), propionamide phosphonic acid (Prop-Phos), and 1-hydroxy-2-pyridinone (1,2-HOPO), from natural waters (river, ground and sea waters), acid solutions (to mimic certain industrial process streams), and dialysate. The affinity, capacity, and kinetics of the lanthanide sorption, as well as regenerability of SAMMS materials were investigated. Going from the acid side over to the alkaline side, the AcPhos- and DiPhos-SAMMS maintain their outstanding affinity for lanthanides, which enable the use of the materials in the systems where the pH may fluctuate. In acid solutions, Prop-Phos- and 1,2-HOPO-SAMMS have differing affinity along the lanthanide series, suggesting their use in chromatographic lanthanide separation. Over 95% of 100 microg/L of Gd in dialysate was removed by the Prop-Phos-SAMMS after 1 min and 99% over 10 min. SAMMS can be regenerated with an acid wash (0.5M HCl) without losing the binding properties. Thus, they have a great potential to be used as in large-scale treatment of lanthanides, lanthanide separation prior to analytical instruments, and in sorbent dialyzers for treatment of acute lanthanide poisoning. PMID:19345006

  5. Selective removal of lanthanides from natural waters, acidic streams and dialysate

    PubMed Central

    Yantasee, Wassana; Fryxell, Glen E.; Addleman, R. Shane; Wiacek, Robert J.; Koonsiripaiboon, View; Pattamakomsan, Kanda; Sukwarotwat, Vichaya; Xu, Jide; Raymond, Kenneth N.

    2009-01-01

    The increased demand for the lanthanides in commercial products result in increased production of lanthanide containing ores, which increases public exposure to the lanthanides, both from various commercial products and from production wastes/effluents. This work investigates lanthanide (La, Ce, Pr, Nd, Eu, Gd and Lu) binding properties of self-assembled monolayers on mesoporous silica supports (SAMMS™), that were functionalized with diphosphonic acid (DiPhos), acetamide phosphonic acid (AcPhos), propionamide phosphonic acid (Prop-Phos), and 1-hydroxy-2-pyridinone (1,2-HOPO), from natural waters (river, ground and sea waters), acid solutions (to mimic certain industrial process streams), and dialysate. The affinity, capacity, and kinetics of the lanthanide sorption, as well as regenerability of SAMMS materials were investigated. Going from the acid side over to the alkaline side, the AcPhos- and DiPhos-SAMMS maintain their outstanding affinity for lanthanides, which enable the use of the materials in the systems where the pH may fluctuate. In acid solutions, Prop-Phos- and 1,2-HOPO-SAMMS have differing affinity along the lanthanide series, suggesting their use in chromatographic lanthanide separation. Over 95% of 100 µg/L of Gd in dialysate was removed by the Prop-Phos-SAMMS after 1 min and 99% over 10 min. SAMMS can be regenerated with an acid wash (0.5 M HCl) without losing the binding properties. Thus, they have a great potential to be used as in large-scale treatment of lanthanides, lanthanide separation prior to analytical instruments, and in sorbent dialyzers for treatment of acute lanthanide poisoning. PMID:19345006

  6. Presence and sources of anthropogenic perfluoroalkyl acids in high-consumption tap-water based beverages.

    PubMed

    Eschauzier, Christian; Hoppe, Maria; Schlummer, Martin; de Voogt, Pim

    2013-01-01

    This study investigates the presence and sources of perfluorinated alkyl acids (PFAAs) in tap water and corresponding tap-water based beverages such as coffee and cola collected in the city of Amsterdam, The Netherlands. Exposure pathways studies have shown that low concentrations of PFAA in tap water already may pose a high contribution to daily human exposure. Tap water samples (n=4) had higher concentrations of PFAAs than the corresponding post-mixed cola (n=4). The lower PFAA levels in the cola were attributed to the pre-treatment of tap water in the mixing machines and dilution with cola syrup. In coffee samples from a coffee machine perfluorooctanoic acid (PFOA) at 4 ng L(-1) was the dominating analyte (n=12). The concentrations of PFHpA, PFOA and non branched PFOS were found to be significantly higher in manually (self) brewed coffee than in the corresponding tap water (n=4). The contribution from short-chain PFAA analogs could not be quantified due to low recoveries. Leaching experiments at different temperatures were performed with fluoropolymers-containing tubes to investigate the potential of leaching from tubes used in beverage preparation (n=16). Fluoropolymer tubes showed leaching of PFAAs at high (80°C) temperature but its relevance for contamination of beverages in practice is small. The specific contribution from perfluoropolymer tubing inside the beverage preparation machines could not be assessed since no information was available from the manufacturers. The present study shows that although different beverage preparation processes possibly affect the concentrations of PFAAs encountered in the final consumed product, the water used for preparation remains the most important source of PFAAs. This in turn has implications for areas where drinking water is contaminated. Tap-water based beverages will possibly be an additional source of human exposure to PFAAs and need to be considered in exposure modeling. PMID:22939265

  7. Southern Africa Validation of NASA's Earth Observing System (SAVE EOS)

    NASA Technical Reports Server (NTRS)

    Privette, Jeffrey L.

    2000-01-01

    Southern Africa Validation of EOS (SAVE) is 4-year, multidisciplinary effort to validate operational and experimental products from Terra-the flagship satellite of NASA's Earth Observing System (EOS). At test sites from Zambia to South Africa, we are measuring soil, vegetation and atmospheric parameters over a range of ecosystems for comparison with products from Terra, Landsat 7, AVHRR and SeaWiFS. The data are also employed to parameterize and improve vegetation process models. Fixed-point and mobile "transect" sampling are used to collect the ground data. These are extrapolated over larger areas with fine-resolution multispectral imagery. We describe the sites, infrastructure, and measurement strategies developed underSAVE, as well as initial results from our participation in the first Intensive Field Campaign of SAFARI 2000. We also describe SAVE's role in the Kalahari Transect Campaign (February/March 2000) in Zambia and Botswana.

  8. Explosive Products EOS: Adjustment for detonation speed and energy release

    SciTech Connect

    Menikoff, Ralph

    2014-09-05

    Propagating detonation waves exhibit a curvature effect in which the detonation speed decreases with increasing front curvature. The curvature effect is due to the width of the wave profile. Numerically, the wave profile depends on resolution. With coarse resolution, the wave width is too large and results in a curvature effect that is too large. Consequently, the detonation speed decreases as the cell size is increased. We propose a modification to the products equation of state (EOS) to compensate for the effect of numerical resolution; i.e., to increase the CJ pressure in order that a simulation propagates a detonation wave with a speed that is on average correct. The EOS modification also adjusts the release isentrope to correct the energy release.

  9. Enhancement to Hitran to Support the NASA EOS Program

    NASA Technical Reports Server (NTRS)

    Kirby, Kate P.; Rothman, Laurence S.

    1998-01-01

    The HITRAN molecular database has been enhanced with the object of providing improved capabilities for the EOS program scientists. HITRAN itself is the database of high-resolution line parameters of gaseous species expected to be observed by the EOS program in its remote sensing activities. The database is part of a larger compilation that includes IR cross-sections, aerosol indices of refraction, and software for filtering and plotting portions of the database. These properties have also been improved. The software has been advanced in order to work on multiple platforms. Besides the delivery of the compilation on CD-ROM, the effort has been directed toward making timely access of data and software on the world wide web.

  10. Wysession begins term as Eos Section Editor for Seismology

    NASA Astrophysics Data System (ADS)

    Wysession, Michael

    In mid-April, Michael Wysession, an associate professor in the Department of Earth and Planetary Sciences at Washington University, embarked on a 3-year term as section editor of Eos for seismology. Wysession brings to the position a strong background in research and teaching. Below are a few remarks from Wysession.“I recently became the new seismology editor for Eos. I look forward to presenting the many exciting areas of seismological research to the entire geophysical community. I have taught at Washington University since obtaining my Ph.D. at Northwestern University in 1991. My interest in seismology began during my undergraduate years at Brown University (Sc.B., 1984), but my experience as an educator began after I graduated and taught high school math and physics in Staten Island, N.Y.

  11. Enhancement to HITRAN to Support the NASA EOS Program

    NASA Technical Reports Server (NTRS)

    Kirby, Kate P.; Rothman, Laurence S.

    1999-01-01

    The HITRAN molecular database has been enhanced with the object of providing improved capabilities for the EOS program scientists. HITRAN itself is the database of high-resolution line parameters of gaseous species expected to be observed by the EOS program in its remote sensing activities. The database is part of a larger compilation that includes IR cross-sections, aerosol indices of refraction, and software for filtering and plotting portions of the database. These properties have also been improved. The software has been advanced in order to work on multiple platforms. Besides the delivery of the compilation on CD-ROM, the effort has been directed toward making timely access of data and software on the world wide web.

  12. EOS of a material mixture in pressure equilibrium

    SciTech Connect

    Charles W. Cranfill

    2000-01-01

    A procedure is presented for calculating the equation of state (EOS) of a material mixture whose constituents are in pressure equilibrium but not necessarily in temperature equilibrium. A Newton-Raphson iteration is performed to determine the constituent partial volumes and energies that give equal partial pressures subject to the constraints that the total volume and energy of the mixture are specified. During each iteration, the changes in EOS quantities are chosen to be fixed (but arbitrary) linear combinations of their temperature-equilibrium and isentropic values, so those two extremes can be reproduced as special cases. The changes in the constituent partial volumes and energies are limited to prevent the Newton-Raphson iteration from diverging.

  13. An Overview of the EOS Data Dissemination Systems

    NASA Technical Reports Server (NTRS)

    Ramapriyan, H.K.; Pfister, Robin; Weinstein, Beth

    2008-01-01

    The Earth Observing System Data and Information System (EOSDIS) is the primary data system serving the broad-scope of NASA s Earth Observing System (EOS) program and a significant portion of the "heritage" Earth science data. EOSDIS was designed to support the Earth sciences within NASA s Science Mission Directorate (previously the Earth Science Enterprise (ESE) and Mission to Planet Earth). The EOS Program was NASA s contribution to the United States Global Change Research Program (USGCRP) enacted by Congress in 1990 as part of the Global Change Act. ESE s objective was to launch a series of missions to help answer fundamental global change questions such as "How is Earth changing?" and "What are the consequences for life on Earth?" resulting support of this objective, EOSDIS distributes a wide variety of data to a diverse community.

  14. Carboxymethylcellulose Obtained by Ethanol/Water Organosolv Process Under Acid Conditions

    NASA Astrophysics Data System (ADS)

    Ruzene, Denise S.; Gonçalves, Adilson R.; Teixeira, José A.; Pessoa de Amorim, Maria T.

    Sugar cane bagasse pulps were obtained by ethanol/water organosolv process under acid and alkaline conditions. The best condition of acid pulping for the sugarcane bagasse was 0.02 mol/L sulfuric acid at 160°C, for 1h, whereas the best condition for alkaline pulping was 5% sodium hydroxide (base pulp) at 160°C, for 3h. For the residual lignin removal, the acid and alkaline pulps were submitted to a chemical bleaching using sodium chlorite. Pulps under acid and alkaline conditions bleached with sodium chlorite presented viscosities of 3.6 and 7.8 mPas, respectively, and μ-kappa numbers of 1.1 and 2.4, respectively. The pulp under acid condition, bleached with sodium chlorite was used to obtain carboxymethylcellulose (CMC). CMC yield was 35% (pulp based), showing mass gain after the carboxymethylation reaction corresponding to 23.6% of substitution or 0.70 groups-CH2COONa per unit of glucose residue. The infrared spectra showed the CMC characteristic bands and by the infrared technique it was possible to obtain a substitution degree (0.63), similar to the substitution degree calculated by mass gain (0.70).

  15. Earth Observatory Satellite (EOS) Definition Phase Report, Volume 1

    NASA Technical Reports Server (NTRS)

    1971-01-01

    System definition studies were conducted of the Earth Observatory Satellite (EOS). The studies show that the concept of an Earth Observatory Satellite in a near-earth, sun-synchronous orbit would make a unique contribution to the goals of a coordinated program for acquisition of data for environmental research with applications to earth resource inventory and management. The technical details for the proposed development of sensors, spacecraft, and a ground data processing system are presented.

  16. Management approach recommendations. Earth Observatory Satellite system definition study (EOS)

    NASA Technical Reports Server (NTRS)

    1974-01-01

    Management analyses and tradeoffs were performed to determine the most cost effective management approach for the Earth Observatory Satellite (EOS) Phase C/D. The basic objectives of the management approach are identified. Some of the subjects considered are as follows: (1) contract startup phase, (2) project management control system, (3) configuration management, (4) quality control and reliability engineering requirements, and (5) the parts procurement program.

  17. Earth Observing System (EOS) real-time onboard orbit determination

    NASA Technical Reports Server (NTRS)

    Folta, David C.; Muller, Ron

    1993-01-01

    The paper describes the TDRSS Onboard Navigation System (TONS) selected by NASA/GSFC for the EOS-AM1 spacecraft as the baseline navigation system for real-time onboard orbit determination. Particular attention is given to the TONS algorithms and environmental models, the general design considerations, the algorithm implementation, and the required hardware. Results are presented of the covariance analysis for the nominal onboard and instrument requirements.

  18. Regional relationships between geomorphic/hydrologic parameters and surface water chemistry relative to acidic deposition

    SciTech Connect

    Rochelle, B.P.; Liff, C.I.; Campbell, W.G.; Cassell, D.L.; Church, M.R.

    1989-01-01

    The authors determined geomorphic and hydrologic parameters for 144 forested, lake watersheds in the Northeast (NE) of the United States based primarily on measurements from topographic maps. These parameters were used to test for relationships with selected surface water chemistry relevant to acidic deposition. Analyses were conducted on regional and subregional scales delineated based on soils, land use, physiography, total sulfur deposition and statistical clustering of selected geomorphic/hydrologic parameters. Significant relationships were found among the geomorphic/hydrologic parameters and the surface water chemistry for the NE. Elevation had the most significant relationship with surface water chemistry, particularly in the mountainous areas of the NE. Other factors occurring consistently as significant predictors of surface water chemistry were maximum relief, relief ratio, runoff, and estimates of basin elongation. Results suggest that elevational parameters might be surrogates for other watershed characteristics, such as soils or spatial deposition patterns.

  19. Removal of carbamazepine and clofibric acid from water using double templates-molecularly imprinted polymers.

    PubMed

    Dai, Chao-meng; Zhang, Juan; Zhang, Ya-lei; Zhou, Xue-fei; Duan, Yan-ping; Liu, Shu-guang

    2013-08-01

    A novel double templates-molecularly imprinted polymer (MIP) was prepared by precipitation polymerization using carbamazepine (CBZ) and clofibric acid (CA) as the double templates molecular and 2-vinylpyridine as functional monomer. The equilibrium data of MIP was well described by the Freundlich isotherm model. Two kinetic models were adopted to describe the experimental data, and the pseudo second-order model well-described adsorption of CBZ and CA on the MIP. Adsorption experimental results showed that the MIP had good selectivity and adsorption capacity for CBZ and CA in the presence of competitive compounds compared with non-imprinted polymer, commercial powdered activated carbon, and C18 adsorbents. The feasibility of removing CBZ and CA from water by the MIP was demonstrated using tap water, lake water, and river water. PMID:23436062

  20. Abscisic Acid Elicits the Water-Stress Response in Root Hairs of Arabidopsis thaliana1

    PubMed Central

    Schnall, Jennifer A.; Quatrano, Ralph S.

    1992-01-01

    Water stress has been shown to cause root hairs to become short and bulbous. Because abscisic acid (ABA) mediates a variety of water-stress responses, we investigated the response of Arabidopsis thaliana root hairs to ABA. When wild-type root hairs were treated with ABA, they exhibited the water-stress response. The Arabidopsis mutants abi1 and abi2, which are insensitive to ABA at the seedling stage, did not display the root hair response. These data suggest that ABA may mediate the response of root hairs to water stress. The drought response of root hairs resulting in an inhibition of tip growth will provide an easy screen to select mutations that are insensitive to ABA and/or involved in tip growth. Images Figure 1 PMID:16652949

  1. Preserving ground water samples with hydrochloric acid does not result in the formation of chloroform

    USGS Publications Warehouse

    Squillace, Paul J.; Pankow, James F.; Barbash, Jack E.; Price, Curtis V.; Zogorski, John S.

    1999-01-01

    Water samples collected for the determination of volatile organic compounds (VOCs) are often preserved with hydrochloric acid (HCl) to inhibit the biotransformation of the analytes of interest until the chemical analyses can he performed. However, it is theoretically possible that residual free chlorine in the HCl can react with dissolved organic carbon (DOC) to form chloroform via the haloform reaction. Analyses of 1501 ground water samples preserved with HCl from the U.S. Geological Survey's National Water-Quality Assessment Program indicate that chloroform was the most commonly detected VOC among 60 VOCs monitored. The DOC concentrations were not significantly larger in samples with detectable chloroform than in those with no delectable chloroform, nor was there any correlation between the concentrations of chloroform and DOC. Furthermore, chloroform was detected more frequently in shallow ground water in urban areas (28.5% of the wells sampled) than in agricultural areas (1.6% of the wells sampled), which indicates that its detection was more related to urban land-use activities than to sample acidification. These data provide strong evidence that acidification with HCl does not lead to the production of significant amounts of chloroform in ground water samples. To verify these results, an acidification study was designed to measure the concentrations of all trihalomethanes (THMs) that can form as a result of HCl preservation in ground water samples and to determine if ascorbic acid (C6H8O6) could inhibit this reaction if it did occur. This study showed that no THMs were formed as a result of HCl acidification, and that ascorbic acid had no discernible effect on the concentrations of THMs measured.

  2. EOS7C-ECBM Version 1.0

    2012-11-14

    EOS7C is an equation of state module for the TOUGH2 program for CO2 or N2 in Methane (CH4) Reservoirs. In the present work, additions have been made to the EOS7C Version 1.0 module to include the Enhanced Coal Bed Methane (ECBM) modifications developed by Webb (2003). In addition, the Dusty Gas Model for gas-phase diffusion (Webb 2001) has been included. The ECBM modification to the EOS7C equation of state incorporate the extended Langmuir isothem formore » sorbing gases, including the change in porosity associated with the sorbed gas mass. Comparison to hand calculations for pure gas and binary mixture shows very good agreement. Application to a CO2 well injection problem by Law et al. (2002). The Dusty Model modification add options to calculate gas diffusion using the Dusty-Gas Model including separate and coupled approaches. Comparison to low-permeability pure gas diffusion data shows excellent agreement. The results from the DGM are compared to the Fick's Law behavior for diffusion across a capillary fringe. The differences between the models are small due to the relatively high permeability (10-11 m2) of the problem.« less

  3. EOS7C-ECBM Version 1.0

    SciTech Connect

    2012-11-14

    EOS7C is an equation of state module for the TOUGH2 program for CO2 or N2 in Methane (CH4) Reservoirs. In the present work, additions have been made to the EOS7C Version 1.0 module to include the Enhanced Coal Bed Methane (ECBM) modifications developed by Webb (2003). In addition, the Dusty Gas Model for gas-phase diffusion (Webb 2001) has been included. The ECBM modification to the EOS7C equation of state incorporate the extended Langmuir isothem for sorbing gases, including the change in porosity associated with the sorbed gas mass. Comparison to hand calculations for pure gas and binary mixture shows very good agreement. Application to a CO2 well injection problem by Law et al. (2002). The Dusty Model modification add options to calculate gas diffusion using the Dusty-Gas Model including separate and coupled approaches. Comparison to low-permeability pure gas diffusion data shows excellent agreement. The results from the DGM are compared to the Fick's Law behavior for diffusion across a capillary fringe. The differences between the models are small due to the relatively high permeability (10-11 m2) of the problem.

  4. On designing of LCAS over VCAT for an EOS chip

    NASA Astrophysics Data System (ADS)

    Wang, Peng; Jin, Depeng; Zeng, Lieguang

    2005-02-01

    Ethernet over SDH/SONET (EOS), which connects different Ethernets through the existing SDH/SONET infrastructure, is a promising data transmission technology in today"s networks, for it successfully combines the simplicity and affordability of Ethernet with the resilience and scalability of SDH/SONET. Virtual Concatenation (VCAT) is one of the key technologies in EOS, which provides the capability to transmit and receive over several noncontiguous parallel Virtual Container (VC) fragments as a single flow and drastically improves efficiency of over 33 percent against standard concatenations. Link capacity adjustment scheme (LCAS) over VCAT signaling scheme further enhances VCAT to tune bandwidth dynamically at the requests of network management system without disturbing the existing traffic. In addition, the scheme will automatically decrease the capacity if some member of VCAT experiences a failure in the network, and increase the capacity when the network fault is repaired. In this paper, our design of LCAS over VCAT within an EOS chip is provided, which supports four Virtual Concatenation Groups (VCG) to adjust their bandwidth simultaneously. The block diagrams of the total design for LCAS over VCAT are also provided and several open problems that we encountered during implementation and their corresponding solutions are discussed in focus. Thoroughly functional simulations and FPGA verifications have been done to the design to prove its validity. Finally, we have the design synthesized with Synopsys"s Design Compiler, which reveals that the whole design is realizable in ASICs.

  5. Observations of Active Volcanoes Using the EO-1 Satellite

    NASA Astrophysics Data System (ADS)

    Flynn, L. P.; Harris, A. J.; Wright, R.; Oppenheimer, C.; Geschwind, L. R.; Donegan, S.; Garbeil, H.

    2001-12-01

    Previous satellite observations of active volcanoes have been hampered by instruments that are primarily designed to measure surface reflectance of the Earth's vegetation. Sensors detecting radiation in the near-IR and IR are frequently saturated by highly radiant active volcanic features. Two satellite instruments, Hyperion and the Advanced Land Imager (ALI) on the Earth Observing -1 (EO-1) offer a means to circumvent saturation issues. Hyperion is a hyperspectral instrument that collects data in 242 narrow spectral bands between 0.4 and 2.5 microns and produces images that are 7.5 km x 100 km. For each 30m x 30m pixel, accurate atmospheric corrections and multiple component thermal models for lava flows can be generated. ALI is a Landsat-like instrument having 10 spectral bands at 0.4 - 2.35 microns. One of these, the 1.2 micron band, is sensitive to high temperature thermal anomalies such as overturning lava lakes and open lava channels. ALI also has a 10-m panchromtic band that allows for greater detailed mapping of volcanic features. ALI and Hyperion analyses for Erta Ale (Ethiopia), Mt. Etna (Sicily), Santiaguito (Guatemala), Popocatepetl (Mexico), and Mayon (Philippines) will be presented. While distribution of these data sets is limited to the EO-1 Science Team, the future of NASA's high spatial resolution terrestrial observation program will likely be based on a hybrid of these EO-1 sensors.

  6. Development of a PPT for the EO-1 Spacecraft

    NASA Technical Reports Server (NTRS)

    Benson, Scott W.; Arrington, Lynn A.; Hoskins, W. Andrew; Meckel, Nicole J.

    2000-01-01

    A Pulsed Plasma Thruster (PPT) has been developed for use in a technology demonstration flight experiment on the Earth Observing 1 (EO-1) New Millennium Program mission. The thruster replaces the spacecraft pitch axis momentum wheel for control and momentum management during an experiment of a minimum three-day duration. The EO-1 PPT configuration is a combination of new technology and design heritage from similar systems flown in the 1970's and 1980's. Acceptance testing of the protoflight unit has validated readiness for flight, and integration with the spacecraft, including initial combined testing, has been completed. The thruster provides a range of capability from 90 microN-sec impulse bit at 650 sec specific impulse for 12 W input power, through 860 microN-sec impulse bit at 1400 see specific impulse for 70 W input power. Development of this thruster reinitiates technology research and development and re-establishes an industry base for production of flight hardware. This paper reviews the EO-1 PPT development, including technology selection, design and fabrication, acceptance testing, and initial spacecraft integration and test.

  7. Effects of excess pantothenic acid administration on the other water-soluble vitamin metabolisms in rats.

    PubMed

    Shibata, Katsumi; Takahashi, Chisato; Fukuwatari, Tsutomu; Sasaki, Ryuzo

    2005-12-01

    To acquire the data concerning the tolerable upper intake level which prevents health problems from an excessive intake of pantothenic acid, an animal experiment was done. Rats of the Wistar strain (male, 3 wk old) were fed on a diet which contains 0%, 0.0016% (control group), 1%, or 3% calcium pantothenate for 29 d. The amount of weight increase, the food intake, and the organ weights were measured, as well as the pantothenic acid contents in urine, the liver and blood. Moreover, to learn the influence of excessive pantothenic acid on other water-soluble vitamin metabolism, thiamin, riboflavin, a vitamin B6 catabolite, the niacin catabolites, and ascorbic acid in urine were measured. As for the 3% addition group, enlargement of the testis, diarrhea, and hair damage were observed, and the amount of weight increase and the food intake were less than those of the control group. However, abnormality was not seen in the 1% addition group. The amount of pantothenic acid in urine, the liver, and blood showed a high correlation with intake level of pantothenic acid. It was only for 4-pyridoxic acid, a vitamin B6 catabolite, in urine that a remarkable difference was observed against the control group. Moreover, the (2-Py+4-Py)/MNA excretion ratio for these metabolites of the nicotinamide also indicated a low value in the 3% pantothenic acid group. As for the calcium pantothenate, it was found that the 3% level in the diet was the lowest-observed-adverse-effect-level (LOAEL) and the 1% level was the no-observed-adverse-effect-level (NOAEL). PMID:16521696

  8. Aerosol Disinfection Capacity of Slightly Acidic Hypochlorous Acid Water Towards Newcastle Disease Virus in the Air: An In Vivo Experiment.

    PubMed

    Hakim, Hakimullah; Thammakarn, Chanathip; Suguro, Atsushi; Ishida, Yuki; Nakajima, Katsuhiro; Kitazawa, Minori; Takehara, Kazuaki

    2015-12-01

    Existence of bioaerosol contaminants in farms and outbreaks of some infectious organisms with the ability of transmission by air increase the need for enhancement of biosecurity, especially for the application of aerosol disinfectants. Here we selected slightly acidic hypochlorous acid water (SAHW) as a candidate and evaluated its virucidal efficacy toward a virus in the air. Three-day-old conventional chicks were challenged with 25 doses of Newcastle disease live vaccine (B1 strain) by spray with nebulizer (particle size <3 μm in diameter), while at the same time reverse osmosis water as the control and SAHW containing 50 or 100 parts per million (ppm) free available chlorine in pH 6 were sprayed on the treated chicks with other nebulizers. Exposed chicks were kept in separated cages in an isolator and observed for clinical signs. Oropharyngeal swab samples were collected from 2 to 5 days postexposure from each chick, and then the samples were titrated with primary chicken kidney cells to detect the virus. Cytopathic effects were observed, and a hemagglutination test was performed to confirm the result at 5 days postinoculation. Clinical signs (sneezing) were recorded, and the virus was isolated from the control and 50 ppm treatment groups, while no clinical signs were observed in and no virus was isolated from the 100 ppm treatment group. The virulent Newcastle disease virus (NDV) strain Sato, too, was immediately inactivated by SAHW containing 50 ppm chlorine in the aqueous phase. These data suggest that SAHW containing 100 ppm chlorine can be used for aerosol disinfection of NDV in farms. PMID:26629621

  9. Selective removal of transition metals from acidic mine waters by novel consortia of acidophilic sulfidogenic bacteria

    PubMed Central

    Ňancucheo, Ivan; Johnson, D. Barrie

    2012-01-01

    Summary Two continuous‐flow bench‐scale bioreactor systems populated by mixed communities of acidophilic sulfate‐reducing bacteria were constructed and tested for their abilities to promote the selective precipitation of transition metals (as sulfides) present in synthetic mine waters, using glycerol as electron donor. The objective with the first system (selective precipitation of copper from acidic mine water containing a variety of soluble metals) was achieved by maintaining a bioreactor pH of ∼2.2–2.5. The second system was fed with acidic (pH 2.5) synthetic mine water containing 3 mM of both zinc and ferrous iron, and varying concentrations (0.5–30 mM) of aluminium. Selective precipitation of zinc sulfide was possible by operating the bioreactor at pH 4.0 and supplementing the synthetic mine water with 4 mM glycerol. Analysis of the microbial populations in the bioreactors showed that they changed with varying operational parameters, and novel acidophilic bacteria (including one sulfidogen) were isolated from the bioreactors. The acidophilic sulfidogenic bioreactors provided ‘proof of principle’ that segregation of metals present in mine waters is possible using simple online systems within which controlled pH conditions are maintained. The modular units are versatile and robust, and involve minimum engineering complexity. PMID:21895996

  10. Pervaporation separation of ethanol-water mixtures using polyacrylic acid composite membranes

    DOEpatents

    Neidlinger, H.H.

    1985-05-07

    Synthetic, organic, polymeric membranes were prepared from polyacrylic acid salts for use with pervaporation apparatus in the separation of ehthanol-water mixtures. The polymeric material was prepared in dilute aqueous solution and coated onto a polysulfone support film, from which excess polymeric material was subsequently removed. Cross-links were then generated by limited exposure to toluene-2,4-diisocyanata solution, after which the prepared membrane was heat-cured. The resulting membrane structure showed selectivity in permeating water over a wide range of feed concentrations. 4 tabs.

  11. Corrected fluorescence spectra of fulvic acids isolated from soil and water

    SciTech Connect

    Ewald, M.; Belin, C.; Berger, P.; Weber, J.H.

    1983-08-01

    The fluorescence of humic matter is a ubiquitous phenomenon that occurs for isolated soil and aquatic matter and for natural water samples. This property is used to compare humic substances, but uncorrected emission spectra can be especially misleading for spectra taken on different instruments. This paper details the corrections of emission fluorescence spectra of well-characterized fulvic acids isolated from soil and a fresh-water river. The corrections significantly modify the uncorrected spectra. This effect demonstrates the need for emission spectra corrections before comparing the fluorescence properties of diverse humic matter samples.

  12. Limitations in the use of commercial humic acids in water and soil research

    USGS Publications Warehouse

    Malcolm, R.L.; MacCarthy, P.

    1986-01-01

    Seven samples of commercial "humic acids", purchased from five different suppliers, were studied, and their characteristics were compared with humic and fulvic acids isolated from streams, soils, peat, leonardite, and a dopplerite sample. Cross-polarization and magic-angle spinning 13C NMR spectroscopy clearly shows pronounced differences between the commercial materials and all other samples. Elemental and infrared spectroscopic data do not show such clear-cut differences but can be used as supportive evidence, with the 13C NMR data, to substantiate the above distinctions. As a result of these differences and due to the general lack of information relating to the source, method of isolation, or other pretreatment of the commercial materials, these commercial products are not considered to be appropriate for use as analogues of true soil and water humic substances, in experiments designed to evaluate the nature and reactivity of humic substances in natural waters and soils.

  13. A classical reactive potential for molecular clusters of sulphuric acid and water

    NASA Astrophysics Data System (ADS)

    Stinson, Jake L.; Kathmann, Shawn M.; Ford, Ian J.

    2016-01-01

    We present a two-state empirical valence bond (EVB) potential describing interactions between sulphuric acid and water molecules and designed to model proton transfer between them within a classical dynamical framework. The potential has been developed in order to study the properties of molecular clusters of these species, which are thought to be relevant to atmospheric aerosol nucleation. The particle swarm optimisation method has been used to fit the parameters of the EVB model to density functional theory (DFT) calculations. Features of the parametrised model and DFT data are compared and found to be in satisfactory agreement. In particular, it is found that a single sulphuric acid molecule will donate a proton when clustered with four water molecules at 300 K and that this threshold is temperature dependent.

  14. Effect of pressure on the dissociation constant of boric acid in water and seawater

    NASA Astrophysics Data System (ADS)

    Millero, Frank J.; Ward, Gary K.; Surdo, Antonio Lo; Huang, Fen

    2012-01-01

    The sound speeds of boric acid and sodium borate in water and 0.725 m NaCl have been measured from 0 to 50 °C and to near 1 molal. These results have been used to determine the partial molal adiabatic compressibilities of B(OH) 3 and NaB(OH) 4. The partial molal volumes, v¯(i), and compressibilities, κ¯(i), have been used to estimate the changes in the volume (Δ V) and compressibility (Δ κ) for the dissociation of boric acid in water and average seawater (0.725 m NaCl, SA ˜ 35 g/kg) B(OH)3+H2O=H++B(OH)4- where

  15. Limitations in the use of commercial humic acids in water and soil research

    SciTech Connect

    Malcolm, R.L.; MacCarthy, P.

    1986-09-01

    Seven samples of commercial humic acids, purchased from five different suppliers, were studied, and their characteristics were compared with humic and fulvic acids isolated from streams, soils, peat, leonardite, and a dopplerite sample. Cross-polarization and magic-angle spinning /sup 13/C NMR spectroscopy clearly shows pronounced differences between the commercial materials and all other samples. Elemental and infrared spectroscopic data do not show such clear-cut differences but can be used as supportive evidence, with the /sup 13/C NMR data, to substantiate the above distinctions. As a result of these differences and due to the general lack of information relating to the source, method of isolation, or other pretreatment of the commercial materials, these commercial products are not considered to be appropriate for use as analogues of true soil and water humic substances, in experiments designed to evaluate the nature and reactivity of humic substances in natural waters and soils.

  16. Hydrogen production by water electrolysis using tetra-alkyl-ammonium-sulfonic acid ionic liquid electrolytes

    NASA Astrophysics Data System (ADS)

    Fiegenbaum, Fernanda; Martini, Emilse M.; de Souza, Michèle O.; Becker, Márcia R.; de Souza, Roberto F.

    2013-12-01

    Triethylammonium-propanesulfonic acid tetrafluoroborate (TEA-PS·BF4) is used as an electrolyte in the water electrolysis. The electrolysis of water with this ionic conductor produces high current densities with high efficiencies, even at room temperatures. A system using TEA-PS·BF4 in an electrochemical cell with platinum electrodes has current densities (i) up to 1.77 A cm-2 and efficiencies between 93 and 99% in temperatures ranging from 25 °C to 80 °C. The activation energy observed with TEA-PS·BF4 is ca. 9.3 kJ mol-1, a low value that can be explained by the facilitation of proton transport in the organised aqueous ionic liquid media. The unexpectedly high efficiency of this system is discussed by taking into account the high conductivities associated with the Brönsted and Lewis acidity characteristics associated with these ionic conductive materials.

  17. An active ingredient of Cat's Claw water extracts identification and efficacy of quinic acid.

    PubMed

    Sheng, Yezhou; Akesson, Christina; Holmgren, Kristin; Bryngelsson, Carl; Giamapa, Vincent; Pero, Ronald W

    2005-01-15

    Historic medicinal practice has defined Cat's Claw, also known as Una de Gato or Uncaria tomentosa, as an effective treatment for several health disorders including chronic inflammation, gastrointestinal dysfunction such as ulcers, tumors and infections. The efficacy of Cat's Claw was originally believed, as early as the 1960s, to be due to the presence of oxindole alkaloids. However, more recently water-soluble Cat's Claw extracts were shown not to contain significant amounts of alkaloids (<0.05%), and yet still were shown to be very efficacious. Here we characterize the active ingredients of a water-soluble Cat's Claw extract called C-Med-100 as inhibiting cell growth without cell death thus providing enhanced opportunities for DNA repair, and the consequences thereof, such as immune stimulation, anti-inflammation and cancer prevention. The active ingredients were chemically defined as quinic acid esters and could also be shown to be bioactive in vivo as quinic acid. PMID:15619581

  18. Pervaporation of Water from Aqueous Sulfuric Acid at Elevated Temperatures Using Nafion® Membranes

    SciTech Connect

    Christopher J. Orme; Frederick F. Stewart

    2009-01-01

    The concentration of sulfuric acid by pervaporation has been studied using Nafion-112® and Nafion-117® membranes, which have been characterized in terms of flux, permeability, and selectivity at 100 ºC and 120 ºC. Feed concentrations investigated ranged from 40 to over 80 weight percent. In general, water fluxes ranged from 100-8000 g/m2h, depending on feed acid concentration and separations factors as high as 104 were observed. Membrane stability was probed using Dynamic Mechanical Analysis that revealed some embrittlement of the membranes during use. Further studies showed that the embrittlement was due to an interaction with the acid and was not induced by the operating temperature.

  19. Tandem Catalytic Depolymerization of Lignin by Water-Tolerant Lewis Acids and Rhodium Complexes.

    PubMed

    Jastrzebski, Robin; Constant, Sandra; Lancefield, Christopher S; Westwood, Nicholas J; Weckhuysen, Bert M; Bruijnincx, Pieter C A

    2016-08-23

    Lignin is an attractive renewable feedstock for aromatic bulk and fine chemicals production, provided that suitable depolymerization procedures are developed. Here, we describe a tandem catalysis strategy for ether linkage cleavage within lignin, involving ether hydrolysis by water-tolerant Lewis acids followed by aldehyde decarbonylation by a Rh complex. In situ decarbonylation of the reactive aldehydes limits loss of monomers by recondensation, a major issue in acid-catalyzed lignin depolymerization. Rate of hydrolysis and decarbonylation were matched using lignin model compounds, allowing the method to be successfully applied to softwood, hardwood, and herbaceous dioxasolv lignins, as well as poplar sawdust, to give the anticipated decarbonylation products and, rather surprisingly, 4-(1-propenyl)phenols. Promisingly, product selectivity can be tuned by variation of the Lewis-acid strength and lignin source. PMID:27440544

  20. The Partitioning of Acetic, Formic, and Phosphoric Acids Between Liquid Water and Steam

    SciTech Connect

    Gruszkiewicz, M.S.; Marshall, S.L.; Palmer, D.A.; Simonson, J.M.

    1999-06-22

    The chemical carryover of impurities and treatment chemicals from the boiler to the steam phase, and ultimately to the low-pressure turbine and condenser, can be quantified based on laboratory experiments preformed over ranges of temperature, pH, and composition. The two major assumptions are that thermodynamic equilibrium is maintained and no deposition, adsorption or decomposition occurs. The most recent results on acetic, formic and phosphoric acids are presented with consideration of the effects of hydrolysis and dimerization reactions. Complications arising from thermal decomposition of the organic acids are discussed. The partitioning constants for these acids and other solutes measured in this program have been incorporated into a simple thermodynamic computer code that calculates the effect of chemical and mechanical carryover on the composition of the condensate formed to varying extents in the water/steam cycle.

  1. Water Relations, Diurnal Acidity Changes, and Productivity of a Cultivated Cactus, Opuntia ficus-indica1

    PubMed Central

    Acevedo, Edmundo; Badilla, Ignacio; Nobel, Park S.

    1983-01-01

    Physiological responses of the Crassulacean acid metabolism (CAM) plant Opuntia ficus-indica (Cactaceae) were studied on a commercial plantation in central Chile. Young cladodes (flattened stems) and flower buds exhibited daytime stomatal opening, whereas mature cladodes and fruit exhibited the nocturnal stomatal opening characteristic of CAM plants. Severe water stress suppressed the nocturnal stomatal opening by mature cladodes, but their high water vapor conductance occurring near dawn was not affected. Nocturnal acidity increases were not as sensitive to water stress as was the nocturnal stomatal opening. The magnitude of the nocturnal acidity increases depended on the total daily photosynthetically active radiation (PAR), being 90% PAR-saturated at 27 moles per square meter per day for a mean nighttime air temperature of 5°C and at 20 moles per square meter per day for 18°C. Inasmuch as the PAR received on unshaded vertical surfaces averaged about 21 moles per square meter per day, nocturnal acidity increases by the cladodes were on the verge of being PAR-limited in the field. The net assimilation rate, which was positive throughout the year, annually averaged 3.4 grams per square meter per day for 1.0- and 2.0-year-old plants. Plants that were 5.4 years old had 7.2 square meters of cladode surface area (both sides) and an annual dry weight productivity of 13 megagrams (metric tons) per hectare per year when their ground cover was 32%. This substantial productivity for a CAM plant was accompanied by the highest nocturnal acidity increase so far observed in the field, 0.78 mole H+ per square meter. PMID:16663084

  2. Study of the sequential conversion of citric to itaconic to methacrylic acid in near-critical and supercritical water

    SciTech Connect

    Carlsson, M.; Habenicht, C.; Kam, L.C.; Antal, M.J. Jr. ); Bian, N.; Cunningham, R.J.; Jones, M. Jr. . Dept. of Chemistry)

    1994-08-01

    Between 200 and 400 million lb of citric acid are produced annually in the USA by fermentation of molasses and other sugars using the microorganism Aspergillus niger. A lesser quantity of itaconic acid is manufactured by a similar technology using Aspergillus terreus. The recovery of citric acid from its fermentation broth via calcium salt precipitation is a costly, highly complex, sophisticated operation. USDOE estimates the cost of dry citric acid produced from a new plant to be about $0.59/lb, whereas the estimated cost of wet citric acid (in its fermentation broth) from a new plant is about $0.19/lb and from an old plant is about $0.15/lb. Citric acid rapidly reacts in hot (250 C), compressed (34.5 MPa) liquid water to form itaconic and citraconic acids with a combined selectivity that exceeds 90%. At higher temperatures (360 C), in the absence and presence of NaOH, itaconic acid decarboxylates to form methacrylic acid. The yield of methacrylic acid depends on the temperature, pH, and buffer strength of the medium, reaching a maximum of about 70% (by mole) of the itaconic acid feed. Conditions which favor the production of methacrylic acid also lead to the formation of its hydration product: hydroxyisobutyric acid. Under optimum conditions the combined yield of methacrylic acid and hydroxyisobutyric acid from itaconic acid exceeds 80%. Results are consistent with well-established dehydration and decarboxylation mechanisms.

  3. Competition between Displacement and Dissociation of a Strong Acid Compared to a Weak Acid Adsorbed on Silica Particle Surfaces: The Role of Adsorbed Water.

    PubMed

    Fang, Yuan; Tang, Mingjin; Grassian, Vicki H

    2016-06-16

    The adsorption of nitric (HNO3) and formic (HCOOH) acids on silica particle surfaces and the effect of adsorbed water have been investigated at 296 K using transmission FTIR spectroscopy. Under dry conditions, both nitric and formic acids adsorb reversibly on silica. Additionally, the FTIR spectra show that both of these molecules remain in the protonated form. At elevated relative humidities (RH), adsorbed water competes both for surface adsorption sites with these acids as well as promotes their dissociation to hydronium ions and the corresponding anions. Compared to HNO3, the extent of dissociation is much smaller for HCOOH, very likely because it is a weaker acid. This study provides valuable insights into the interaction of HNO3 and HCOOH with silica surface on the molecular level and further reveals the complex roles of surface-adsorbed water in atmospheric heterogeneous chemistry of mineral dust particles-many of these containing silica. PMID:27220375

  4. Anion-exchange separation techniques with methanol-water solutions of hydrochloric and nitric acids.

    PubMed

    Morrow, R J

    1966-09-01

    Mixed methanol-water systems were shown to be of use in the analysis of samples containing 500-mg amounts of metallic impurities for rare earths and actinides. Detailed study of the hydrochloric acid-methanol system led to improved separation of einsteinium and californium from americium and curium as well as to lanthanideactinide separations. Comparisons of elution orders are also drawn between these systems and the corresponding lithium salt systems, with emphasis on ion-hydration theories. PMID:18960002

  5. Chemical synthesis of lactic acid from cellulose catalysed by lead(II) ions in water.

    PubMed

    Wang, Yanliang; Deng, Weiping; Wang, Binju; Zhang, Qinghong; Wan, Xiaoyue; Tang, Zhenchen; Wang, Ye; Zhu, Chun; Cao, Zexing; Wang, Guichang; Wan, Huilin

    2013-01-01

    The direct transformation of cellulose, which is the main component of lignocellulosic biomass, into building-block chemicals is the key to establishing biomass-based sustainable chemical processes. Only limited successes have been achieved for such transformations under mild conditions. Here we report the simple and efficient chemocatalytic conversion of cellulose in water in the presence of dilute lead(II) ions, into lactic acid, which is a high-value chemical used for the production of fine chemicals and biodegradable plastics. The lactic acid yield from microcrystalline cellulose and several lignocellulose-based raw biomasses is >60% at 463 K. Both theoretical and experimental studies suggest that lead(II) in combination with water catalyses a series of cascading steps for lactic acid formation, including the isomerization of glucose formed via the hydrolysis of cellulose into fructose, the selective cleavage of the C3-C4 bond of fructose to trioses and the selective conversion of trioses into lactic acid. PMID:23846730

  6. Communication: Physical origins of ionization potential shifts in mixed carboxylic acids and water complexes.

    PubMed

    Gu, Quanli; Tang, Zhen; Su, Peifeng; Wu, Wei; Yang, Zhijun; Trindle, Carl O; Knee, Joseph L

    2016-08-01

    The ionization potential (IP) of the aromatic alpha hydroxy carboxylic acid, 9-hydroxy-9-fluorene carboxylic acid (9HFCA), is shifted by complexation with hydrogen bonding ligands such as water and formic acid. Generalized Kohn-Sham energy decomposition analysis decomposes the intermolecular binding energies into a frozen energy term, polarization, correlation, and/or dispersion energy terms, as well as terms of geometric relaxation and zero point energy. We observe that in each dimer the attractive polarization always increases upon ionization, enhancing binding in the cation and shifting the IP toward the red. For 9HFCA-H2O, a substantial decrease of the repulsive frozen energy in cation further shifts the IP toward red. For 9HFCA-HCOOH, the increase of the frozen energy actually occurs in the cation and shifts the IP toward blue. Consistent with the experimental measurements, our analysis provides new, non-intuitive perspectives on multiple hydrogen bonds interactions in carboxylic acids and water complexes. PMID:27497532

  7. Impacts of Sulfate Seed Acidity and Water Content on Isoprene Secondary Organic Aerosol Formation.

    PubMed

    Wong, Jenny P S; Lee, Alex K Y; Abbatt, Jonathan P D

    2015-11-17

    The effects of particle-phase water and the acidity of pre-existing sulfate seed particles on the formation of isoprene secondary organic aerosol (SOA) was investigated. SOA was generated from the photo-oxidation of isoprene in a flow tube reactor at 70% relative humidity (RH) and room temperature in the presence of three different sulfate seeds (effloresced and deliquesced ammonium sulfate and ammonium bisulfate) under low NOx conditions. High OH exposure conditions lead to little isoprene epoxydiol (IEPOX) SOA being generated. The primary result is that particle-phase water had the largest effect on the amount of SOA formed, with 60% more SOA formation occurring with deliquesced ammonium sulfate seeds as compared to that on effloresced ones. The additional organic material was highly oxidized. Although the amount of SOA formed did not exhibit a dependence on the range of seed particle acidity examined, perhaps because of the low amount of IEPOX SOA, the levels of high-molecular-weight material increased with acidity. While the uptake of organics was partially reversible under drying, the results nevertheless indicate that particle-phase water enhanced the amount of organic aerosol material formed and that the RH cycling of sulfate particles may mediate the extent of isoprene SOA formation in the atmosphere. PMID:26460477

  8. Electrical resistance response of polyaniline films to water, ethanol, and nitric acid solution

    NASA Astrophysics Data System (ADS)

    Yin, Hong-Xing; Li, Meng-Meng; Yang, H.; Long, Yun-Ze; Sun, Xin

    2010-08-01

    This paper reports on electrical resistance vs. aging time for the response of polyaniline films under exposure to water, ethanol and nitric acid (HNO3) solution. Camphor sulfonic acid-doped polyaniline films were prepared by a “doping-dedoping-redoping" method, the morphology and microstructures of the films were characterized by a scanning electron microscope and an x-ray diffractometer, the electrical resistance was measured by a four-probe method. It was found that a lower amount of water molecules infiltrating the film can decrease the film's resistance possibly due to an enhancement of charge carrier transfer between polyaniline chains, whereas excessive water molecules can swell inter-chain distances and result in a quick increase of resistance. The resistance of the film under exposure to ethanol increases and becomes much larger than the original value. However, HNO3 solution can decrease the film's resistance sharply possibly owing to doping effect of protonic acid. These results can help to understand the conduction mechanism in polyaniline films, and also indicate that the films have potential application in chemical sensors.

  9. Matrix isolation infrared and ab initio study of the hydrogen bonding between formic acid and water

    NASA Astrophysics Data System (ADS)

    George, Lisa; Sander, Wolfram

    2004-11-01

    The infrared spectra of the formic acid-water complexes isolated in argon matrices are reported. Both supersonic jet expansion and a conventional effusive source followed by trapping in solid argon at 10 K are used to obtain the matrices. The experimental IR spectra are compared to the data obtained from high level ab initio (MP2) and DFT (B3LYP) calculations with 6-311++G(d,p) and aug-cc-pVTZ basis sets. The complex formation results in red shifts in the CO and OH stretching vibrations and a blue shift in the CO stretching vibration of formic acid. The OH stretching modes of water also exhibit pronounced red shifts. Both the MP2 and B3LYP calculations located three minima corresponding to cyclic HCOOH⋯H 2O complexes with two hydrogen bond interactions. The binding energies are -10.3, -5.1, and -3.5 kcal mol -1, respectively, for the three complexes at the MP2/ aug-cc-pVTZ level, corrected for the basis set superposition error (BSSE) using the Boys-Bernardi counterpoise scheme. Comparison of the calculated frequencies of the three complexes with the matrix IR spectrum reveals that the lowest energy complex is formed. In addition, a complex of formic acid with two water molecules is observed.

  10. VizieR Online Data Catalog: Neutron-star matter unified EoS FORTRAN codes (Potekhin+, 2013)

    NASA Astrophysics Data System (ADS)

    Potekhin, A. Y.; Fantina, A. F.; Chamel, N.; Pearson, J. M.; Goriely, S.

    2013-09-01

    The FORTRAN codes implement the formulae for the unified EoSs of neutron-star matter BSk19, BSk20, and BSk21, supplemented with codes for masses and radii of static neutron stars, number fractions of particles, nuclear size and shape parameters, and effective masses of nucleons. Detailed descriptions of all subroutines are given by comment lines in the files (4 data files).

  11. A novel strategy for NQO1 (NAD(P)H:quinone oxidoreductase, EC 1.6.99.2) mediated therapy of bladder cancer based on the pharmacological properties of EO9

    PubMed Central

    Choudry, G A; Stewart, P A Hamilton; Double, J A; Krul, M R L; Naylor, B; Flannigan, G M; Shah, T K; Brown, J E; Phillips, R M

    2001-01-01

    The indolequinone EO9 demonstrated good preclinical activity but failed to show clinical efficacy against a range of tumours following intravenous drug administration. A significant factor in EO9's failure in the clinic has been attributed to its rapid pharmacokinetic elimination resulting in poor drug delivery to tumours. Intravesical administration of EO9 would circumvent the problem of drug delivery to tumours and the principal objective of this study is to determine whether or not bladder tumours have elevated levels of the enzyme NQO1 (NAD(P)H:quinone oxidoreductase) which plays a key role in activating EO9 under aerobic conditions. Elevated NQO1 levels in human bladder tumour tissue exist in a subset of patients as measured by both immunohistochemical and enzymatic assays. In a panel of human tumour cell lines, EO9 is selectively toxic towards NQO1 rich cell lines under aerobic conditions and potency can be enhanced by reducing extracellular pH. These studies suggest that a subset of bladder cancer patients exist whose tumours possess the appropriate biochemical machinery required to activate EO9. Administration of EO9 in an acidic vehicle could be employed to reduce possible systemic toxicity as any drug absorbed into the blood stream would become relatively inactive due to an increase in pH. © 2001 Cancer Research Campaign   http://www.bjcancer.com PMID:11710826

  12. Is the habitation of acidic-water sanctuaries by galaxiid fish facilitated by natural organic matter modification of sodium metabolism?

    PubMed

    Glover, Chris N; Donovan, Katherine A; Hill, Jonathan V

    2012-01-01

    Acidic waters of New Zealand's West Coast are hypothesized to be a refuge for native galaxiid fish, allowing them to escape predation from acid-sensitive invasive salmonid species. To determine the mechanisms by which galaxiids tolerate low pH, we investigated sodium metabolism in inanga Galaxias maculatus in response to water pH, short-term acclimation to acidic waters, the presence and source of natural organic matter (NOM), and fish life history. Contrary to expectation, inanga were physiologically sensitive to acid exposure, displaying inhibited sodium influx and exacerbated sodium efflux. Short-term (144 h) acclimation to acid did not modify this effect, and NOM did not exert a protective effect on sodium metabolism at low pH. Inanga sourced from naturally acidic West Coast waters did, however, display a sodium influx capacity (J(max)) that was significantly elevated when compared with that of fish collected from neutral waters. All inanga, independent of source, exhibited exceptionally high sodium uptake affinities (18-40 μM) relative to previously studied freshwater teleosts. Although inanga displayed relatively poor physiological tolerance to acidic waters, their high sodium influx affinity coupled with their occupation of near-coastal waters with elevated sodium levels may permit habitation of low-pH freshwaters. PMID:22902374

  13. Update - The Earth Observing System (EOS) forward and return link data processing and communications services

    NASA Technical Reports Server (NTRS)

    Ramapriyan, H. K.; Kelly, A. C.; Smith, G. A.

    1992-01-01

    An overview is presented of the EOS ground support services in order to identify interfaces to and drivers of the data processing and communication systems. Generic system requirements are compared with those specifically needed for EOS, including processing requirements for forward link and return link data. Communications requirements for transporting the forward link data from the EOS Operations Center and for the transfer of level zero data to the EOS Data and Information System (EOSDIS) Distributed Active Archive Centers are specified. The forward and return link processing requirements of the EOS instruments from the international partners are also addressed. The overall context of EOSDIS in the Mission to Planet Earth Program is addressed.

  14. Impact of acid mine drainages on surficial waters of an abandoned mining site.

    PubMed

    García-Lorenzo, M L; Marimón, J; Navarro-Hervás, M C; Pérez-Sirvent, C; Martínez-Sánchez, M J; Molina-Ruiz, José

    2016-04-01

    Weathering of sulphide minerals produces a great variety of efflorescences of soluble sulphate salts. These minerals play an important role for environmental pollution, since they can be either a sink or a source for acidity and trace elements. This paper aims to characterise surface waters affected by mining activities in the Sierra Minera of Cartagena-La Union (SE, Spain). Water samples were analysed for trace metals (Zn, Cd, Pb, Cu, As and Fe), major ions (Na(+), K(+), Ca(2+) and Mg(2+)) and anions (F(-), Cl(-), NO3 (-), CO3 (2-), SO4 (2-)) concentrations and were submitted to an "evaporation-precipitation" experiment that consisted in identifying the salts resulting from the evaporation of the water aliquots sampled onsite. Mineralogy of the salts was studied using X-ray diffraction and compared with the results of calculations using VISUAL MINTEQ. The study area is heavily polluted as a result of historical mining and processing activities that has produced large amount of wastes characterised by a high trace elements content, acidic pH and containing minerals resulting from the supergene alteration of the raw materials. The mineralogical study of the efflorescences obtained from waters shows that magnesium, zinc, iron and aluminium sulphates predominate in the acid mine drainage precipitates. Minerals of the hexahydrite group have been quantified together with minerals of the rozenite group, alunogen and other phases such as coquimbite and copiapite. Calcium sulphates correspond exclusively to gypsum. In a semiarid climate, such as that of the study area, these minerals contribute to understand the response of the system to episodic rainfall events. MINTEQ model could be used for the analysis of waters affected by mining activities but simulation of evaporation gives more realistic results considering that MINTEQ does not consider soluble hydrated salts. PMID:26347422

  15. Water-lactose behavior as a function of concentration and presence of lactic acid in lactose model systems.

    PubMed

    Wijayasinghe, Rangani; Vasiljevic, Todor; Chandrapala, Jayani

    2015-12-01

    The presence of high amounts of lactic acid in acid whey restricts its ability to be further processed because lactose appears to remain in its amorphous form. A systematic study is lacking in this regard especially during the concentration step. Hence, the main aim of the study was to establish the structure and behavior of water molecules surrounding lactose in the presence of 1% (wt/wt) lactic acid at a concentration up to 50% (wt/wt). Furthermore, the crystallization nature of freeze-dried lactose with or without lactic acid was established using differential scanning calorimetry and Fourier transform infrared spectroscopy. Two mechanisms were proposed to describe the behavior of water molecules around lactose molecules during the concentration of pure lactose and lactose solutions with lactic acid. Pure lactose solution exhibited a water evaporation enthalpy of ~679 J·g(-1), whereas lactose+ lactic acid solution resulted in ~965 J·g(-1) at a 50% (wt/wt) concentration. This indicates a greater energy requirement for water removal around lactose in the presence of lactic acid. Higher crystallization temperatures were observed with the presence of lactic acid, indicating a delay in crystallization. Furthermore, less crystalline lactose (~12%) was obtained in the presence of lactic acid, indicating high amorphous nature compared with pure lactose where ~50% crystallinity was obtained. The Fourier transform infrared spectra revealed that the strong hydration layer consisting lactic acid and H3O(+) ions surrounded lactose molecules via strong H bonds, which restricted water mobility, induced a change in structure of lactose, or both, creating unfavorable conditions for lactose crystallization. Thus, partial or complete removal of lactic acid from acid whey may be the first step toward improving the ability of acid whey to be processed. PMID:26476948

  16. The influence of acidic mine and spoil drainage on water quality in the mid-Wales area.

    PubMed

    Fuge, R; Laidlaw, I M; Perkins, W T; Rogers, K P

    1991-06-01

    The many abandoned base metal mines of the mid-Wales ore field are sources of extensive pollution. Some of the mineralised veins contain large amounts of pyrite and marcasite and oxidative weathering of these produces sulphuric acid resulting in very acidic mine drainage waters. In addition, the spoil tips associated with these mines can contain abundant iron sulphides. Drainage waters from these sources have pH values as low as 2.6 and are heavily contaminated with metals such as Al, Zn, Cd and Ni.Two of the main rivers of the area, the Rheidol and Ystwyth, intercept heavily contaminated acidic drainage which has a marked effect on water quality. The Rheidol contains over 100 μg L(-1) Zn for 16 km downstream of the acid water influx. This level is over three times the recommended EEC limit for Zn in salmonoid waters of low hardness. PMID:24202839

  17. Persistent Water-Nitric Acid Condensate with Saturation Water Vapor Pressure Greater than That of Hexagonal Ice.

    PubMed

    Gao, Ru-Shan; Gierczak, Tomasz; Thornberry, Troy D; Rollins, Andrew W; Burkholder, James B; Telg, Hagen; Voigt, Christiane; Peter, Thomas; Fahey, David W

    2016-03-10

    A laboratory chilled mirror hygrometer (CMH), exposed to an airstream containing water vapor (H2O) and nitric acid (HNO3), has been used to demonstrate the existence of a persistent water-nitric acid condensate that has a saturation H2O vapor pressure greater than that of hexagonal ice (Ih). The condensate was routinely formed on the mirror by removing HNO3 from the airstream following the formation of an initial condensate on the mirror that resembled nitric acid trihydrate (NAT). Typical conditions for the formation of the persistent condensate were a H2O mixing ratio greater than 18 ppm, pressure of 128 hPa, and mirror temperature between 202 and 216 K. In steady-state operation, a CMH maintains a condensate of constant optical diffusivity on a mirror through control of only the mirror temperature. Maintaining the persistent condensate on the mirror required that the mirror temperature be below the H2O saturation temperature with respect to Ih by as much as 3 K, corresponding to up to 63% H2O supersaturation with respect to Ih. The condensate was observed to persist in steady state for up to 16 h. Compositional analysis of the condensate confirmed the co-condensation of H2O and HNO3 and thereby strongly supports the conclusion that the Ih supersaturation is due to residual HNO3 in the condensate. Although the exact structure or stoichiometry of the condensate could not be determined, other known stable phases of HNO3 and H2O are excluded as possible condensates. This persistent condensate, if it also forms in the upper tropical troposphere, might explain some of the high Ih supersaturations in cirrus and contrails that have been reported in the tropical tropopause region. PMID:26447682

  18. Compartmentalization of amino acids in surfactant aggregates - Partitioning between water and aqueous micellar sodium dodecanoate and between hexane and dodecylammonium propionate trapped water in hexane

    NASA Technical Reports Server (NTRS)

    Fendler, J. H.; Nome, F.; Nagyvary, J.

    1975-01-01

    The partitioning of amino acids (glycine, alanine, leucine, phenylalanine, histidine, aspartic acid, glutamic acid, lysine, isoleucine, threonine, serine, valine, proline, arginine) in aqueous and nonaqueous micellar systems was studied experimentally. Partitioning from neat hexane into dodecylammonium propionate trapped water in hexane was found to be dependent on both electrostatic and hydrophobic interactions, which implies that the interior of dodecylammonium propionate aggregates is negatively charged and is capable of hydrogen bonding in addition to providing a hydrophobic environment. Unitary free energies of transfer of amino acid side chains from hexane to water were determined and solubilities of amino acids in neat hexane substantiated the amino acid hydrophobicity scale. The relevance of the experiments to prebiotic chemistry was examined.

  19. Relative Order of Sulfuric Acid, Bisulfate, Hydronium, and Cations at the Air-Water Interface.

    PubMed

    Hua, Wei; Verreault, Dominique; Allen, Heather C

    2015-11-01

    Sulfuric acid (H2SO4), bisulfate (HSO4(-)), and sulfate (SO4(2-)) are among the most abundant species in tropospheric and stratospheric aerosols due to high levels of atmospheric SO2 emitted from biomass burning and volcanic eruptions. The air/aqueous interfaces of sulfuric acid and bisulfate solutions play key roles in heterogeneous reactions, acid rain, radiative balance, and polar stratospheric cloud nucleation. Molecular-level knowledge about the interfacial distribution of these inorganic species and their perturbation of water organization facilitates a better understanding of the reactivity and growth of atmospheric aerosols and of the aerosol surface charge, thus shedding light on topics of air pollution, climate change, and thundercloud electrification. Here, the air/aqueous interface of NaHSO4, NH4HSO4, and Mg(HSO4)2 salt solutions as well as H2SO4 and HCl acid solutions are investigated by means of vibrational sum frequency generation (VSFG) and heterodyne-detected (HD) VSFG spectroscopy. VSFG spectra of all acid solutions show higher SFG response in the OH-bonded region relative to neat water, with 1.1 M H2SO4 being more enhanced than 1.1 M HCl. In addition, VSFG spectra of bisulfate salt solutions highly resemble that of the dilute H2SO4 solution (0.26 M) at a comparable pH. HD-VSFG (Im χ((2))) spectra of acid and bisulfate salt solutions further reveal that hydrogen-bonded water molecules are oriented preferentially toward the bulk liquid phase. General agreement between Im χ((2)) spectra of 1.1 M H2SO4 and 1.1 M HCl acid solutions indicate that HSO4(-) ions have a similar surface preference as that of chloride (Cl(-)) ions. By comparing the direction and magnitude of the electric fields arising from the interfacial ion distributions and the concentration of each species, the most reasonable relative surface preference that can be deduced from a simplified model follows the order H3O(+) > HSO4(-) > Na(+), NH4(+), Mg(2+) > SO4(2-). Interestingly

  20. Detecting and Simulating Urban-induced Climate Changes via EOS observations and NCAR Community Land Model

    NASA Astrophysics Data System (ADS)

    Jin, M.; Peters-Lidard, C.

    2003-12-01

    Advanced EOS observations provide us an unique opportunity to detect and simulate urban induced climate changes. Using 5km EOS MODIS-observed skin temperature, land cover, albedo, emissivity, LAI, aerosol optical depth, and cloud properties, we examine the surface-atmosphere interactions and urban heat island effects from selected big cities (New York, Beijing, Phoenix, and Houston) to global coverage. These analyses address physical processes modified by urban constructions as well as the general features of urban climate. We find the largest urban impacts in terms of temperature are observed over 30-60N, where most cities are located. In addition, urban regions overall decrease surface albedo by 3-5% and decrease surface emissivity by 1-2%. Focusing on Houston, we develop an urban scheme and couple it into NCAR Community Land Model (CLM-urban) to simulate urban climate. CLM-urban can improve the simulation of water and energy cycles over Houston with the use of observed LAI, albedo and emissivity, as well as urban thermal properties.

  1. Diurnal change in trees as observed by optical and microwave sensors - The EOS Synergism Study

    NASA Technical Reports Server (NTRS)

    Way, Jobea; Mcdonald, Kyle; Paris, Jack; Dobson, Myron C.; Ulaby, Fawwaz T.; Weber, James A.; Ustin, Susan L.; Vanderbilt, Vern C.; Kasischke, Eric S.

    1991-01-01

    The EOS (Earth Observing System) Synergism Study examined the temporal variability of the optical and microwave backscatter due to diurnal change in canopy properties of interest to ecosystem modelers. The experiment was designed to address diurnal changes in canopy water status that relate to transpiration. Multispectral optical and multifrequency, multipolarization microwave measurements were acquired using boom-truck-based systems over a two-week period. Sensor and canopy properties were collected around the clock. The canopy studied was a walnut orchard in the San Joaquin Valley of California. The results demonstrate a large diurnal variation in the dielectric properties of the tree that in turn produces significant diurnal changes in the microwave backscatter. The results suggest that permanently orbiting spaceborne sensors such as those on EOS should be placed in orbits that are optimized for the individual sensor and need not be tied together by a tight simultaneity requirement on the order of minutes to hours for the purpose of monitoring ecosystem properties.

  2. Estimating canopy chlorophyll and nitrogen concentration of rice from EO-1 Hyperion data

    NASA Astrophysics Data System (ADS)

    Chen, Junying; Tian, Qingjiu

    2006-09-01

    In this study, investigation was designed to find an effective method for estimating chlorophyll and nitrogen concentration in the canopies of rice from hyperspectral EO-1 Hyperion image. Continuum-removal analysis enables the isolation of absorption features and minimizes the background influence, thus absorption features stand out. We applied stepwise regression analysis and absorption feature analysis to the field measured foliage and canopy continuum-removed spectra. The results showed that the continuum-removed spectra from the whole range could be broke down into four isolated wavelength ranges and the first wavelength range was centered at 670nm. The area of the wavelength range centered at 670nm based on the BNC spectra was strongly correlated with the chlorophyll and nitrogen concentration. It was validated by EO-1 Hyperion image data, the results showed that the multiple correlation coefficients (R2) between the area of the wavelength range centered at 670nm based on the BNC image spectra and chlorophyll and nitrogen concentration were 0.485 and 0.783 separately. Then the estimation equations were applied to the rice pixels of image which were recognized through Normalized Difference Vegetation Index (NDVI), Land Surface Water Index (LSWI) and Enhanced Vegetation Index (EVI). Thus the chlorophyll and nitrogen concentration distribution maps were obtained. The values in the maps were quite consistent with those of field measurements.

  3. Initial Scientific Assessment of the EOS Data and Information System (EOSDIS)

    NASA Technical Reports Server (NTRS)

    1989-01-01

    Crucial to the success of the Earth Observing System (Eos) is the Eos Data and Information System (EosDIS). The goals of Eos depend not only on its instruments and science investigations, but also on how well EosDlS helps scientists integrate reliable, large-scale data sets of geophysical and biological measurements made from Eos data, and on how successfully Eos scientists interact with other investigations in Earth System Science. Current progress in the use of remote sensing for science is hampered by requirements that the scientist understand in detail the instrument, the electromagnetic properties of the surface, and a suite of arcane tape formats, and by the immaturity of some of the techniques for estimating geophysical and biological variables from remote sensing data. These shortcomings must be transcended if remote sensing data are to be used by a much wider population of scientists who study environmental change at regional and global scales.

  4. /sup 14/C-incorporation into sugars and organic acids of water-stressed maize leaves

    SciTech Connect

    Becker, T.; Fock, H.

    1986-04-01

    The incorporation of /sup 14/C into sugars and some organic acids of maize leaves has been studied in relation to the leaf water potential by feeding /sup 14/CO/sub 2/ (370 ppm) for 1,2 and 4 min during steady state photosynthesis at 25/sup 0/C (PAR = 800 ..mu..mol m/sup -2/s/sup -1/). The relative specific radioactivity (RSA) of the sugars was low (0.2% after 4 min) at -0.62 MPa (control) and decreased by about 50% when psi dropped to -0.95 MPa. The authors conclude that the low rate of photosynthetic sugar synthesis in maize leaves decreased during water stress. The RSA of malate was extremely low at -0.62 MPa (0.02%). This result may be the consequence of the large pool size of malate in maize leaves. The authors presume that there are two malate pools present in maize leaves, a small metabolic pool and a larger storage pool. The RSA of malate decreased during the stress period. This is consistent with the decline in net CO/sub 2/ uptake during water stress. The pool sizes of citrate and isocitrate increased when psi dropped to -0.95 MPa. As practically no radioactivity was detected in these organic acids, they conclude that these compounds are synthesized from unlabelled precursors during water stress.

  5. Environmentally Optimised Sprayer (EOS)--A software application for comprehensive assessment of environmental safety features of sprayers.

    PubMed

    Doruchowski, Grzegorz; Balsari, Paolo; Gil, Emilio; Marucco, Paolo; Roettele, Manfred; Wehmann, Hans-Joachim

    2014-06-01

    Despite technological progress in pesticide application equipment, chemical crop protection continues to contribute to environmental pollution. Water is at risk of contamination with pesticides from point and diffuse sources and could be reduced to a great extent with a better sprayer design. The sprayer manufacturers and pesticide applicators need to take more responsibility for the prevention of water pollution and therefore they have to make environmentally responsible decisions at different stages, from designing to servicing sprayers. The objective of the presented work was to develop an interactive application that would support decisions made by sprayer manufacturers during the production process, and by pesticide applicators when selecting and operating the sprayers. The EOS (Environmentally Optimised Sprayer) is an application evaluating the risk mitigation potential of sprayers based on their technological features, within five risk areas, representing sources of pollution: (i) Inside Contamination; (ii) Outside Contamination; (iii) Filling; (iv) Spray Loss & Drift; (v) Remnants. The evaluator completes the EOS questionnaire by checking for the technical solutions identified in the evaluated sprayer and the result reflects the sprayer quality in terms of potential environmental risk mitigation. The EOS tool also proved its awareness raising facility and educative value when used during training activities and university courses. PMID:24651055

  6. Surface retrievals from Hyperion EO1 using a new, fast, 1D-Var based retrieval code

    NASA Astrophysics Data System (ADS)

    Thelen, Jean-Claude; Havemann, Stephan; Wong, Gerald

    2015-05-01

    We have developed a new algorithm for the simultaneous retrieval of the atmospheric profiles (temperature, humidity, ozone and aerosol) and the surface reflectance from hyperspectral radiance measurements obtained from air/space-borne, hyperspectral imagers such as Hyperion EO-1. The new scheme, proposed here, consists of a fast radiative transfer code, based on empirical orthogonal functions (EOFs), in conjunction with a 1D-Var retrieval scheme. The inclusion of an 'exact' scattering code based on spherical harmonics, allows for an accurate treatment of Rayleigh scattering and scattering by aerosols, water droplets and ice-crystals, thus making it possible to also retrieve cloud and aerosol optical properties, although here we will concentrate on non-cloudy scenes. We successfully tested this new approach using hyperspectral images taken by Hyperion EO-1, an experimental pushbroom imaging spectrometer operated by NASA.

  7. Adsorption dynamics of L-glutamic acid copolymers at a heptane/water interface.

    PubMed

    Beverung, C J; Radke, C J; Blanch, H W

    1998-02-16

    Random copolymers of glutamic acid (glu-ala, glu-leu, glu-phe, glu-tyr) were employed to investigate the relationship between side chain structure and peptide charge on adsorption behavior at an oil/water boundary. Adsorption of a series of glutamate copolymers at a heptane/water interface was examined by the dynamic pendant-drop method to determine interfacial tension. Incorporation of leucine or phenylalanine into a glutamate copolymer results in greater tension reduction than incorporation of alanine or tyrosine. These effects are amplified at pH values near the isoelectric point of glutamate, where macroscopic adsorbed films of glu-leu and glu-phe exhibit gel-like properties in response to interfacial area compression. Differences in interfacial tension behavior of glu-tyr and glu-phe indicate the importance of the tyrosine p-hydroxyl group on adsorption and aggregation at the oil/water interface. PMID:9540205

  8. Water dispersible polytetrafluoroethylene microparticles prepared by grafting of poly(acrylic acid)

    NASA Astrophysics Data System (ADS)

    Yang, Changqiao; Xu, Lu; Zeng, Hongyan; Tang, Zhongfeng; Zhong, Lei; Wu, Guozhong

    2014-10-01

    Due to the hydrophobic nature and high gravimetric density, it is very difficult to obtain water dispersible polytetrafluoroethylene (PTFE) powder. In this work, hydrophilic PTFE microparticles were successfully prepared by grafting of poly(acrylic acid) onto PTFE micropowder via a pre-irradiation method. The as-obtained hydrophilic PTFE microparticles were analyzed by FT-IR, 1H NMR, CA, SEM and TGA. After neutralization by sodium hydroxide, the water contact angle decreased from 145.69° for pristine PTFE to 63.38° for PTFE-g-NaAA. The obtained micropowder can be easily dispersed in water to form a dispersion with very high stability. Furthermore, the presence of grafted PAA shows no obvious influence on degradation temperature of PTFE backbones.

  9. A systematic method for studying the spatial distribution of water molecules around nucleic acid bases.

    PubMed Central

    Schneider, B; Cohen, D M; Schleifer, L; Srinivasan, A R; Olson, W K; Berman, H M

    1993-01-01

    A new method to analyze the distribution of water molecules around the bases in DNA is presented. This method relies on the notion of a "hydrated building block," which represents the joint observed hydration around all bases of a particular type, in structures of a particular conformation type. The hydrated building blocks were constructed using atomic coordinates from 40 structures contained in the Nucleic Acid Database. Pseudoelectron densities were calculated for water molecules in each hydrated building block using standard crystallographic procedures. The electron densities were fitted to obtain "average building blocks," which represent bases with waters only at average or probable positions. Both types of building blocks were used to construct models of hydrated DNA oligomers. The essential features of the solvent structure around d(CGCGAATTCGCG)2 in the B form and d(CGCGCG)2 in the Z form were reproduced. Images FIGURE 4 FIGURE 5 PMID:8312469

  10. Formation of formic acid and organic peroxides in the ozonolysis of ethene with added water vapour

    NASA Astrophysics Data System (ADS)

    Horie, Osamu; Neeb, Peter; Limbach, Stefan; Moortgat, Geert K.

    1994-07-01

    Ozonolysis of C2H4 was carried out in a 580 l glass reaction vessel at 1-5 ppm reactant concentrations, with added water vapour. Under dry conditions ([H2O]0 = 0.5 ppm), HCHO, CO, CO2, (CHO)2O (formic acid anhydride), H2O2, and CH3OOH were identified as the reaction products. Under wet conditions ([H2O]0 = 2 × 104 ppm), HCOOH yields approaching ca. 20% of the converted C2H4, were observed, while no (CHO)2O was formed. Hydroxymethyl hydroperoxide, HOCH2OOH, was observed as the major peroxide, and found to be formed only in the presence of water vapour. Direct reactions of H2O vapour with the excited CH2OO* radicals and with stabilized CH2OO radicals are postulated to explain the formation of HCOOH and HOCH2OOH in the presence of water vapour, respectively.

  11. Recovery of water and acid from leach solutions using direct contact membrane distillation.

    PubMed

    Kesieme, Uchenna K; Milne, Nicholas; Cheng, Chu Yong; Aral, Hal; Duke, Mikel

    2014-01-01

    This paper describes for the first time the use of direct contact membrane distillation (DCMD) for acid and water recovery from a real leach solution generated by a hydrometallurgical plant. The leach solutions considered contained H2SO4 or HCl. In all tests the temperature of the feed solution was kept at 60 °C. The test work showed that fluxes were within the range of 18-33 kg/m(2)/h and 15-35 kg/m(2)/h for the H2SO4 and HCl systems, respectively. In the H2SO4 leach system, the final concentration of free acid in the sample solution increased on the concentrate side of the DCMD system from 1.04 M up to 4.60 M. The sulfate separation efficiency was over 99.9% and overall water recovery exceeded 80%. In the HCl leach system, HCl vapour passed through the membrane from the feed side to the permeate. The concentration of HCl captured in the permeate was about 1.10 M leaving behind only 0.41 M in the feed from the initial concentration of 2.13 M. In all the experiments, salt rejection was >99.9%. DCMD is clearly viable for high recovery of high quality water and concentrated H2SO4 from spent sulfuric acid leach solution where solvent extraction could then be applied to recover the sulfuric acid and metals. While HCl can be recovered for reuse using only DCMD. PMID:24569289

  12. New method for the direct determination of dissolved Fe(III) concentration in acid mine waters

    USGS Publications Warehouse

    To, T.B.; Nordstrom, D.K.; Cunningham, K.M.; Ball, J.W.; McCleskey, R.B.

    1999-01-01

    A new method for direct determination of dissolved Fe(III) in acid mine water has been developed. In most present methods, Fe(III) is determined by computing the difference between total dissolved Fe and dissolved Fe(II). For acid mine waters, frequently Fe(II) >> Fe(III); thus, accuracy and precision are considerably improved by determining Fe(III) concentration directly. The new method utilizes two selective ligands to stabilize Fe(III) and Fe(II), thereby preventing changes in Fe reduction-oxidation distribution. Complexed Fe(II) is cleanly removed using a silica-based, reversed-phase adsorbent, yielding excellent isolation of the Fe(III) complex. Iron(III) concentration is measured colorimetrically or by graphite furnace atomic absorption spectrometry (GFAAS). The method requires inexpensive commercial reagents and simple procedures that can be used in the field. Calcium(II), Ni(II), Pb(II), AI(III), Zn(II), and Cd(II) cause insignificant colorimetric interferences for most acid mine waters. Waters containing >20 mg of Cu/L could cause a colorimetric interference and should be measured by GFAAS. Cobalt(II) and Cr(III) interfere if their molar ratios to Fe(III) exceed 24 and 5, respectively. Iron(II) interferes when its concentration exceeds the capacity of the complexing ligand (14 mg/L). Because of the GFAAS elemental specificity, only Fe(II) is a potential interferent in the GFAAS technique. The method detection limit is 2 ??g/L (40 nM) using GFAAS and 20 ??g/L (0.4 ??M) by colorimetry.A new method for direct determination of dissolved Fe(III) in acid mine water has been developed. In most present methods, Fe(III) is determined by computing the difference between total dissolved Fe and dissolved Fe(II). For acid mine waters, frequently Fe(II)???Fe(III); thus, accuracy and precision are considerably improved by determining Fe(III) concentration directly. The new method utilizes two selective ligands to stabilize Fe(III) and Fe(II), thereby preventing changes

  13. Effects of iron on arsenic speciation and redox chemistry in acid mine water

    USGS Publications Warehouse

    Bednar, A.J.; Garbarino, J.R.; Ranville, J.F.; Wildeman, T.R.

    2005-01-01

    Concern about arsenic is increasing throughout the world, including areas of the United States. Elevated levels of arsenic above current drinking-water regulations in ground and surface water can be the result of purely natural phenomena, but often are due to anthropogenic activities, such as mining and agriculture. The current study correlates arsenic speciation in acid mine drainage and mining-influenced water with the important water-chemistry properties Eh, pH, and iron(III) concentration. The results show that arsenic speciation is generally in equilibrium with iron chemistry in low pH AMD, which is often not the case in other natural-water matrices. High pH mine waters and groundwater do not always hold to the redox predictions as well as low pH AMD samples. The oxidation and precipitation of oxyhydroxides deplete iron from some systems, and also affect arsenite and arsenate concentrations through sorption processes. ?? 2004 Elsevier B.V. All rights reserved.

  14. Estimates of cloud water deposition at Mountain Acid Deposition Program sites in the Appalachian Mountains.

    PubMed

    Baumgardner, Ralph E; Isil, Selma S; Lavery, Thomas F; Rogers, Christopher M; Mohnen, Volker A

    2003-03-01

    Cloud water deposition was estimated at three high-elevation sites in the Appalachian Mountains of the eastern United States (Whiteface Mountain, NY; Whitetop Mountain, VA; and Clingman's Dome, TN) from 1994 through 1999 as part of the Mountain Acid Deposition Program (MADPro). This paper provides a summary of cloud water chemistry, cloud liquid water content, cloud frequency, estimates of cloud water deposition of sulfur and nitrogen species, and estimates of total deposition of sulfur and nitrogen at these sites. Other cloud studies in the Appalachians and their comparison to MADPro are also summarized. Whiteface Mountain exhibited the lowest mean and median concentrations of sulfur and nitrogen ions in cloud water, while Clingman's Dome exhibited the highest mean and median concentrations. This geographic gradient is partly an effect of the different meteorological conditions experienced at northern versus southern sites in addition to the difference in pollution content of air masses reaching the sites. All sites measured seasonal cloud water deposition rates of SO4(2-) greater than 50 kg/ha and NO3(-) rates of greater than 25 kg/ha. These high-elevation sites experienced additional deposition loading of SO4(2-) and NO3(-) on the order of 6-20 times greater compared with lower elevation Clean Air Status and Trends Network (CASTNet) sites. Approximately 80-90% of this extra loading is from cloud deposition. PMID:12661689

  15. Seasonal and longitudinal distributions of atmospheric water-soluble dicarboxylic acids, oxocarboxylic acids, and α-dicarbonyls over the North Pacific

    NASA Astrophysics Data System (ADS)

    Bikkina, Srinivas; Kawamura, Kimitaka; Imanishi, Katsuya; Boreddy, S. K. R.; Nojiri, Yukihiro

    2015-05-01

    In order to assess the seasonal variability of atmospheric abundances of dicarboxylic acids, oxocarboxylic acids, and α-dicarbonyls over the North Pacific and Sea of Japan, aerosol samples were collected along the longitudinal transacts during six cruises between Canada and Japan. The back trajectory analyses indicate that aerosol samples collected in winter and spring are influenced by the East Asian outflow, whereas summer and fall samples are associated with the pristine maritime air masses. Molecular distributions of water-soluble organics in winter and spring samples show the predominance of oxalic acid (C2) followed by succinic (C4) and malonic acids (C3). In contrast, summer and fall marine aerosols are characterized by the predominance of C3 over C4. Concentrations of dicarboxylic acids were higher over the Sea of Japan than the North Pacific. With a lack of continental outflow, higher concentrations during early summer are ascribed to atmospheric oxidation of organic precursors associated with high biological activity in the North Pacific. This interpretation is further supported by the high abundances of azelaic acid, which is a photochemical oxidation product of biogenic unsaturated fatty acids, over the Bering Sea in early summer when surface waters are characterized by high biological productivity. We found higher ratios of oxalic acid to pyruvic and glyoxylic acids (C2/Pyr and C2/ωC2) and glyoxal and methylglyoxal (C2/Gly and C2/MeGly) in summer and fall than in winter and spring, suggesting a production of C2 from the aqueous-phase oxidation of oceanic isoprene. In this study, dicarboxylic acids account for 0.7-38% of water-soluble organic carbon.

  16. Determination of some aliphatic carboxylic acids in anaerobic digestion process waters by ion-exclusion chromatography with conductimetric detection on a weakly acidic cation-exchange resin column.

    PubMed

    Ito, Kazuaki; Takayama, Yohichi; Ikedo, Mikaru; Mori, Masanobu; Taoda, Hiroshi; Xu, Qun; Hu, Wenzhi; Sunahara, Hiroshi; Hayashi, Tsuneo; Sato, Shinji; Hirokawa, Takeshi; Tanaka, Kazuhiko

    2004-06-11

    The determination of seven aliphatic carboxylic acids, formic, acetic, propionic, isobutyric, n-butyric, isovaleric and n-valeric acids in anaerobic digestion process waters was examined using ion-exclusion chromatography with conductimetric detection. The analysis of these biologically important carboxylic acids is necessary as a measure for evaluating and controlling the process. The ion-exclusion chromatography system employed consisted of polymethacrylate-based weakly acidic cation-exchange resin columns (TSKgel OApak-A or TSKgel Super IC-A/C). weakly acidic eluent (benzoic acid), and conductimetric detection. Particle size and cation-exchange capacity were 5 microm and 0.1 meq./ml for TSKgel OApak-A and 3 microm and 0.2 meq./ml for TSKgel Super IC-A/C, respectively. A dilute eluent (1.0-2.0 mM) of benzoic acid was effective for the high resolution and highly conductimetric detection of the carboxylic acids. The good separation of isobutyric and n-butyric acids was performed using the TSKgel Super IC-A/C column (150 mm x 6.0 mm i.d. x 2). The simple and good chromatograms were obtained by the optimized ion-exclusion chromatography conditions for real samples from mesophilic anaerobic digestors, thus the aliphatic carboxylic acids were successfully determined without any interferences. PMID:15250416

  17. Fuzzy Ce-I(ec, eo) and Fuzzy Completely Ce-I(rc, eo) Functions via Fuzzy e-Open Sets

    PubMed Central

    Kamala, K.

    2016-01-01

    We introduced the notions of fuzzy Ce-I(ec, eo) functions and fuzzy completely Ce-I(rc, eo) functions via fuzzy e-open sets. Some properties and several characterization of these types of functions are investigated. PMID:27051858

  18. Fuzzy C e -I(ec, eo) and Fuzzy Completely C e -I(rc, eo) Functions via Fuzzy e-Open Sets.

    PubMed

    Seenivasan, V; Kamala, K

    2016-01-01

    We introduced the notions of fuzzy C e -I(ec, eo) functions and fuzzy completely C e -I(rc, eo) functions via fuzzy e-open sets. Some properties and several characterization of these types of functions are investigated. PMID:27051858

  19. DEVELOPMENT AND VALIDATION OF AN ACID MINE DRAINAGE TREATMENT PROCESS FOR SOURCE WATER

    SciTech Connect

    Lane, Ann

    2015-12-31

    Throughout Northern Appalachia and surrounding regions, hundreds of abandoned mine sites exist which frequently are the source of Acid Mine Drainage (AMD). AMD typically contains metal ions in solution with sulfate ions which have been leached from the mine. These large volumes of water, if treated to a minimum standard, may be of use in Hydraulic Fracturing (HF) or other industrial processes. This project’s focus is to evaluate an AMD water treatment technology for the purpose of providing treated AMD as an alternative source of water for HF operations. The HydroFlex™ technology allows the conversion of a previous environmental liability into an asset while reducing stress on potable water sources. The technology achieves greater than 95% water recovery, while removing sulfate to concentrations below 100 mg/L and common metals (e.g., iron and aluminum) below 1 mg/L. The project is intended to demonstrate the capability of the process to provide AMD as alternative source water for HF operations. The second budget period of the project has been completed during which Battelle conducted two individual test campaigns in the field. The first test campaign demonstrated the ability of the HydroFlex system to remove sulfate to levels below 100 mg/L, meeting the requirements indicated by industry stakeholders for use of the treated AMD as source water. The second test campaign consisted of a series of focused confirmatory tests aimed at gathering additional data to refine the economic projections for the process. Throughout the project, regular communications were held with a group of project stakeholders to ensure alignment of the project objectives with industry requirements. Finally, the process byproduct generated by the HydroFlex process was evaluated for the treatment of produced water against commercial treatment chemicals. It was found that the process byproduct achieved similar results for produced water treatment as the chemicals currently in use. Further

  20. Nanometer-Scale Water-Soluble Macrocycles from Nanometer-Sized Amino Acids

    PubMed Central

    Gothard, Chris M.

    2009-01-01

    This paper introduces the unnatural amino acids m-Abc2K and o-Abc2K as nanometersized building blocks for the creation of water-soluble macrocycles with well-defined shapes. m-Abc2K and o-Abc2K are homologues of the nanometer-sized amino acid Abc2K, which we recently introduced for the synthesis of water-soluble molecular rods of precise length. [J. Am. Chem. Soc. 2007, 129, 7272]. Abc2K is linear (180°), m-Abc2K creates a 120° angle, and o-Abc2K creates a 60° angle. m-Abc2K and o-Abc2K are derivatives of 3’-amino-[1,1’-biphenyl]-4-carboxylic acid and 2’-amino-[1,1’-biphenyl]-4-carboxylic acid, with two propyloxyammonium side chains for water solubility. m-Abc2K and o-Abc2K are prepared as Fmoc-protected derivatives Fmoc-m-Abc2K(Boc)-OH (1a) and Fmoc-o-Abc2K(Boc)-OH (1b). These derivatives can be used alone or in conjunction with Fmoc-Abc2K(Boc)-OH (1c) as ordinary amino acids in Fmoc-based solid-phase peptide synthesis. Building blocks 1a–c were used to synthesize macrocyclic “triangles” 9a–c, “parallelograms” 10a,b, and hexagonal “rings” 11a–d. The macrocycles range from a trimer to a dodecamer, with ring sizes from 24 to 114 atoms, and are 1–4 nm in size. Molecular modeling studies suggest that all the macrocycles except 10b should have well-defined triangle, parallelogram, and ring shapes if all of the amide linkages are trans and the ortho-alkoxy substituents are intramolecularly hydrogen bonded to the amide NH groups. The macrocycles have good water solubility and are readily characterized by standard analytical techniques, such as RP-HPLC, ESI-MS, and NMR spectroscopy. 1H and 13C NMR studies suggest that the macrocycles adopt conformations with all trans-amide linkages in CD3OD, that the “triangles” and “parallelograms” maintain these conformations in D2O, and that the “rings” collapse to form conformations with cis-amide linkages in D2O. PMID:20020731

  1. Temporal variability in urinary levels of drinking water disinfection byproducts dichloroacetic acid and trichloroacetic acid among men

    SciTech Connect

    Wang, Yi-Xin; Zeng, Qiang; Wang, Le; Huang, Yue-Hui; Lu, Zhi-Wei; Wang, Peng; He, Meng-Jie; Huang, Xin; Lu, Wen-Qing

    2014-11-15

    Urinary haloacetic acids (HAAs), such as dichloroacetic acid (DCAA) and trichloroacetic acid (TCAA), have been suggested as potential biomarkers of exposure to drinking water disinfection byproducts (DBPs). However, variable exposure to and the short elimination half-lives of these biomarkers can result in considerable variability in urinary measurements, leading to exposure misclassification. Here we examined the variability of DCAA and TCAA levels in the urine among eleven men who provided urine samples on 8 days over 3 months. The urinary concentrations of DCAA and TCAA were measured by gas chromatography coupled with electron capture detection. We calculated the intraclass correlation coefficients (ICCs) to characterize the within-person and between-person variances and computed the sensitivity and specificity to assess how well single or multiple urine collections accurately determined personal 3-month average DCAA and TCAA levels. The within-person variance was much higher than the between-person variance for all three sample types (spot, first morning, and 24-h urine samples) for DCAA (ICC=0.08–0.37) and TCAA (ICC=0.09–0.23), regardless of the sampling interval. A single-spot urinary sample predicted high (top 33%) 3-month average DCAA and TCAA levels with high specificity (0.79 and 0.78, respectively) but relatively low sensitivity (0.47 and 0.50, respectively). Collecting two or three urine samples from each participant improved the classification. The poor reproducibility of the measured urinary DCAA and TCAA concentrations indicate that a single measurement may not accurately reflect individual long-term exposure. Collection of multiple urine samples from one person is an option for reducing exposure classification errors in studies exploring the effects of DBP exposure on reproductive health. - Highlights: • We evaluated the variability of DCAA and TCAA levels in the urine among men. • Urinary DCAA and TCAA levels varied greatly over a 3-month

  2. Analysis of southeastern Canada lake-water chemistry data in relation to acidic deposition

    SciTech Connect

    Olson, R.J.; Cook, R.B.; Ross-Todd, B.M.; Beauchamp, J.J.

    1990-05-01

    Lake-water chemistry data were obtained for lakes in southeastern Canada to study relationships between atmospheric deposition and acid-base chemistry as part of the National Acid Precipitation Assessment Program State of Science and Technology reports. Quality assurance checks were made to ensure that the data used were of sufficient quality and were comparable to data from the United States. Ninety-eight percent of the 8506 sampled lakes had pH, ANC, and SO{sub 4}{sup 2 {minus}} data and were used in our analyses. Of these, we created a subset of 4017 lakes having data for more variable (Ca{sup 2+}, Mg{sup 2+}, Na{sup +}, K{sup +}, DOC, and conductivity) to analyze potential sources of lake-water acidity. The objectives of this work were to determine the geographical extent and number of potentially affected systems and to infer causes of acidification based on ion ratios. 35 refs., 28 figs., 12 tabs.

  3. Limitation of fluorescence spectrophotometry in the measurement of naphthenic acids in oil sands process water.

    PubMed

    Lu, Weibing; Ewanchuk, Andrea; Perez-Estrada, Leonidas; Sego, Dave; Ulrich, Ania

    2013-01-01

    Fluorescence spectrophotometry has been proposed as a quick screening technique for the measurement of naphthenic acids (NAs). To evaluate the feasibility of this application, the fluorescence emission spectra of NAs extracted from three oil sands process water sources were compared with that of commercial NAs. The NAs resulting from the bitumen extraction process cannot be differentiated because of the similarity of the fluorescence spectra. Separation of the fluorescent species in NAs using high performance liquid chromatography with fluorescence detector proved unsuccessful. The acidic fraction of NAs is fluorescent but the basic fraction of NAs is not fluorescent, implying that aromatic acids in NAs give rise to the fluorescent signals. The concentrations of NAs in oil sands process water were measured by Fourier transform infrared spectroscopy (FTIR), fluorescence spectrophotometry and ultra high performance liquid chromatography-time of flight/mass spectrometry (UPLC-TOF/MS). Commercial Merichem and Kodak NAs are the best standards to use when measuring NAs concentration with FTIR and fluorescence spectrophotometry. In addition, the NAs concentrations measured by fluorescence spectrophotometry are about 30 times higher than those measured by FTIR and UPLC-TOF/MS. The findings in this study underscore the limitation of fluorescence spectrophotometry in the measurement of NAs. PMID:23379948

  4. Bidirectional Interaction of Alanine with Sulfuric Acid in the Presence of Water and the Atmospheric Implication.

    PubMed

    Wang, Chun-Yu; Ma, Yan; Chen, Jiao; Jiang, Shuai; Liu, Yi-Rong; Wen, Hui; Feng, Ya-Juan; Hong, Yu; Huang, Teng; Huang, Wei

    2016-04-21

    Amino acids are recognized as important components of atmospheric aerosols, which impact on the Earth's climate directly and indirectly. However, much remains unknown about the initial events of nucleation. In this work, the interaction of alanine [NH2CH(CH3)COOH or Ala], one of the most abundant amino acids in the atmosphere, with sulfuric acid (SA) and water (W) has been investigated at the M06-2X/6-311++G(3df, 3pd) level of theory. We have studied thermodynamics of the hydrated (Ala)(SA) core system with up to four water molecules. We found that Ala, with one amino group and one carboxyl group, can interact with H2SO4 and H2O in two directions and that it has a high cluster stabilizing effect similar to that of ammonia, which is one of the key nucleation precursor. The corresponding Gibbs free energies of the (Ala)(SA)(W)n (n = 0-4) clusters formation at 298.15 K predicted that Ala can contribute to the stabilization of small binary clusters. Our results showed that the hydrate distribution is temperature-dependent and that a higher humidity and temperature can contribute to the formation of hydrated clusters. PMID:26997115

  5. Extreme carbon dioxide concentrations in acidic pit lakes provoked by water/rock interaction.

    PubMed

    Sánchez-España, Javier; Boehrer, Bertram; Yusta, Iñaki

    2014-04-15

    We quantify the gas pressure and concentration of a gas-charged acidic pit lake in SW Spain. We measured total dissolved gas pressure, carbon dioxide (CO2) concentration, major ion concentration, isotopic composition of dissolved inorganic carbon (δ(13)C(DIC)), and other physicochemical parameters. CO2 is the dominant dissolved gas in this lake and results mainly from carbonate dissolution during the interaction of acidic water with wall rocks, followed by diffusive and advective transport through the water column. The δ(13)C(DIC) values suggest that the biological contribution is comparatively small. Maximum CO2 concentrations higher than 0.1 M (∼5000 mg/L) have been measured, which are only comparable to those found in volcanic crater lakes. The corresponding gas pressures of CO2 alone (pCO2 ∼3.6 bar) imply 60% saturation relative to local pressure at 50 m depth. High CO2 concentrations have been observed in other pit lakes of the region. We recommend gas-specific monitoring in acidic pit lakes and, if necessary, the design of feasible degassing strategies. PMID:24628479

  6. The effect of zeolite treatment by acids on sodium adsorption ratio of coal seam gas water.

    PubMed

    Wang, Xiaoyu; Ozdemir, Orhan; Hampton, Marc A; Nguyen, Anh V; Do, Duong D

    2012-10-15

    Many coal seam gas (CSG) waters contain a sodium ion concentration which is too high relative to calcium and magnesium ions for environment acceptance. Natural zeolites can be used as a cheap and effective method to control sodium adsorption ratio (SAR, which is a measure of the relative preponderance of sodium to calcium and magnesium) due to its high cation exchange capacity. In this study, a natural zeolite from Queensland was examined for its potential to treat CSG water to remove sodium ions to lower SAR and reduce the pH value. The results demonstrate that acid activated zeolite at 30%wt solid ratio can reduce the sodium content from 563.0 to 182.7 ppm; the pH from 8.74 to 6.95; and SAR from 70.3 to 18.5. Based on the results of the batch experiments, the sodium adsorption capacity of the acid-treated zeolite is three times greater than that of the untreated zeolite. Both the untreated and acid-treated zeolite samples were characterized using zeta potential, surface characterization, DTA/TG and particle size distribution in order to explain their adsorption behaviours. PMID:22841594

  7. Ruthenium-Catalyzed Oxidative Homocoupling of Arylboronic Acids in Water: Ligand Tuned Reactivity and Mechanistic Study.

    PubMed

    Tyagi, Deepika; Binnani, Chinky; Rai, Rohit K; Dwivedi, Ambikesh D; Gupta, Kavita; Li, Pei-Zhou; Zhao, Yanli; Singh, Sanjay K

    2016-06-20

    Molecular catalysts based on water-soluble arene-Ru(II) complexes ([Ru]-1-[Ru]-5) containing aniline (L1), 2-methylaniline (L2), 2,6-dimethylaniline (L3), 4-methylaniline (L4), and 4-chloroaniline (L5) were designed for the homocoupling of arylboronic acids in water. These complexes were fully characterized by (1)H, (13)C NMR, mass spectrometry, and elemental analyses. Structural geometry for two of the representative arene-Ru(II) complexes [Ru]-3 and [Ru]-4 was established by single-crystal X-ray diffraction studies. Our studies showed that the selectivity toward biaryls products is influenced by the position and the electronic behavior of various substituents of aniline ligand coordinated to ruthenium. Extensive investigations using (1)H NMR, (19)F NMR, and mass spectral studies provided insights into the mechanistic pathway of homocoupling of arylboronic acids, where the identification of important organometallic intermediates, such as σ-aryl/di(σ-aryl) coordinated arene-Ru(II) species, suggested that the reaction proceeds through the formation of crucial di(σ-aryl)-Ru intermediates by the interaction of arylboronic acid with Ru-catalyst to yield biaryl products. PMID:27276384

  8. Mobility of acid-treated carbon nanotubes in water-saturated porous media.

    PubMed

    Peng, X J; Du, C J; Liang, Z; Wang, J; Luan, Z K; Li, W J

    2011-01-01

    The production, use, and disposal of nanomaterials may inevitably lead to their appearance in water. With the development of new industries around nanomaterials, it seems necessary to be concerned about the transport of nanomaterials in the environment. In this paper, the transport of acid-treated carbon nanotubes (CNTs) in porous media was investigated. Before the mobility investigation, the stability of acid-treated CNT dispersions was studied using ultraviolet-visible spectra and it was indicated that, under the chemical conditions employed in this work, there was no apparent aggregation. The mobility investigation showed that transport of acid-treated CNTs increased with treatment time due to increase in particle zeta potential. Carbon nanotubes treated with nitric acid for 2, 6, and 12 h possessed measured zeta potentials of -30.0, -43.0, and -48.5 mV, respectively. Utilizing clean-bed filtration theory, we showed that acid-treated CNTs have the potential to migrate 3.28, 5.67, and 7.69 m in saturated glass beads, respectively. We showed that solution ionic strength and pH have important effects on the mobility of acid-treated CNTs. Increasing the pH from 6.0 to 7.9 resulted in an increase in migration potential from 2.96 to 10.86 m. Increasing the ionic strength from 0.005 to 0.020 M resulted in a decrease in CNT migration potential from 5.67 to 1.42 m. PMID:22031583

  9. EOS MLS Level 1B Data Processing Software. Version 3

    NASA Technical Reports Server (NTRS)

    Perun, Vincent S.; Jarnot, Robert F.; Wagner, Paul A.; Cofield, Richard E., IV; Nguyen, Honghanh T.; Vuu, Christina

    2011-01-01

    This software is an improvement on Version 2, which was described in EOS MLS Level 1B Data Processing, Version 2.2, NASA Tech Briefs, Vol. 33, No. 5 (May 2009), p. 34. It accepts the EOS MLS Level 0 science/engineering data, and the EOS Aura spacecraft ephemeris/attitude data, and produces calibrated instrument radiances and associated engineering and diagnostic data. This version makes the code more robust, improves calibration, provides more diagnostics outputs, defines the Galactic core more finely, and fixes the equator crossing. The Level 1 processing software manages several different tasks. It qualifies each data quantity using instrument configuration and checksum data, as well as data transmission quality flags. Statistical tests are applied for data quality and reasonableness. The instrument engineering data (e.g., voltages, currents, temperatures, and encoder angles) is calibrated by the software, and the filter channel space reference measurements are interpolated onto the times of each limb measurement with the interpolates being differenced from the measurements. Filter channel calibration target measurements are interpolated onto the times of each limb measurement, and are used to compute radiometric gain. The total signal power is determined and analyzed by each digital autocorrelator spectrometer (DACS) during each data integration. The software converts each DACS data integration from an autocorrelation measurement in the time domain into a spectral measurement in the frequency domain, and estimates separately the spectrally, smoothly varying and spectrally averaged components of the limb port signal arising from antenna emission and scattering effects. Limb radiances are also calibrated.

  10. Science Requirements Document for OMI-EOS. 2

    NASA Technical Reports Server (NTRS)

    Levelt, P. F.; vanderA, R.; Bhartia, P. K.; Boersma, F.; Brinksma, E.; Carpay, J.; Chance, K.; deHaan, J.; Hilsenrath, E.; Isaksen, I.

    2000-01-01

    A Dutch-Finnish scientific and industrial consortium is supplying the Ozone Monitoring Instrument (OMI) for Earth Observing System-Aura (EOS-Aura). EOS-Aura is the next NASA mission to study the Earth's atmosphere extensively, and successor to the highly successful UARS (Upper Atmospheric Research Satellite) mission. The 'Science Requirements Document for OMI-EOS' presents an overview of the Aura and OMI mission objectives. It describes how OMI fits into the Aura mission and it reviews the synergy with the other instruments onboard Aura to fulfill the mission. This evolves in the Scientific Requirements for OMI (Chapter 3), stating which trace gases have to be measured with what necessary accuracy, in order for OMI to meet Aura's objectives. The most important data product of OMI, the ozone vertical column, densities shall have a better accuracy and an improved global coverage than the predecessor instruments TOMS (Total Ozone Monitoring Spectrometer) and GOME (Global Ozone Monitoring Experiment), which is a.o. achieved by a better signal to noise ratio, improved calibration and a wide field-of-view. Moreover, in order to meet its role on Aura, OMI shall measure trace gases, such as NO2, OClO, BrO, HCHO and SO2, aerosols, cloud top height and cloud coverage. Improved accuracy, better coverage, and finer ground grid than has been done in the past are goals for OMI. After the scientific requirements are defined, three sets of subordinate requirements are derived. These are: the algorithm requirements, i.e. what do the algorithms need in order to meet the scientific requirements; the instrument and calibration requirements, i.e. what has to be measured and how accurately in order to provide the quality of data necessary for deriving the data products; and the validation requirements, i.e. a strategy of how the OMI program will assure that its data products are valid in the atmosphere, at least to the required accuracy.

  11. Bile acids and pH values in total feces and in fecal water from habitually omnivorous and vegetarian subjects.

    PubMed

    van Faassen, A; Hazen, M J; van den Brandt, P A; van den Bogaard, A E; Hermus, R J; Janknegt, R A

    1993-12-01

    Twenty habitually omnivorous subjects and 19 habitually lactoovovegetarian subjects aged 59-65 y collected feces during 4 consecutive days. The concentrations of bile acids in total feces did not differ between the omnivores and vegetarians, but the bile acid concentrations in fecal water were significantly lower in the vegetarians. The concentration of the colorectal cancer-predicting bile acid deoxycholic acid in fecal water was explained by the intake of saturated fat and the daily fecal wet weight (r2 = 0.50). Fecal pH did not differ between the omnivores and vegetarians. This variable was significantly (P < 0.05) explained by the intake of calcium (r2 = 0.30); 24-h fecal wet weight and defecation frequency were significantly higher in the vegetarians. In conclusion, our vegetarian subjects had a lower concentration of deoxycholic acid in fecal water, higher fecal wet weight, and higher defecation frequency than the omnivorous subjects. PMID:8249879

  12. Earth Observatory Satellite system definition study. Report no. 3: Design/cost tradeoff studies. Appendix A: EOS program WBS dictionary. Appendix B: EOS mission functional analysis

    NASA Technical Reports Server (NTRS)

    1974-01-01

    The work breakdown structure (WBS) dictionary for the Earth Observatory Satellite (EOS) is defined. The various elements of the EOS program are examined to include the aggregate of hardware, computer software, services, and data required to develop, produce, test, support, and operate the space vehicle and the companion ground data management system. A functional analysis of the EOS mission is developed. The operations for three typical EOS missions, Delta, Titan, and Shuttle launched are considered. The functions were determined for the top program elements, and the mission operations, function 2.0, was expanded to level one functions. Selection of ten level one functions for further analysis to level two and three functions were based on concern for the EOS operations and associated interfaces.

  13. Autonomous Sciencecraft Experiment (ASE) Operations on EO-1 in 2004

    NASA Technical Reports Server (NTRS)

    Davies, A. G.; Baker, V.; Castano, R.; Chien, S.; Cichy, B.; Doggett, T.; Dohm, J. M.; Greeley, R.; Lee, R.; Sherwood, R.

    2004-01-01

    The Autonomous Sciencecraft Experiment (ASE) has been selected for flight demonstration by NASAs New Millennium Program (NMP) as part of the Space Technology 6 (ST6) mission. NASA has identified the development of an autonomously operating spacecraft as a necessity for an expanded program of missions exploring the Solar System. The versatile ASE spacecraft command and control software, image formation software, and science processing software will be uploaded to the Earth Observer 1 (EO-1) spacecraft in early 2004 to detect surface modification related to volcanism, ice formation and retreat, and flooding.

  14. EOS attitude determination and next generation star tracker enhancements

    NASA Technical Reports Server (NTRS)

    Kudva, P.; Throckmorton, A.

    1993-01-01

    The pointing knowledge required for the Earth Observing System (EOS) AM mission is at the limit of the current generation of star trackers, with little margin. Techniques for improving the performance of existing star trackers are explored, with performance sensitivities developed for each alternative. These are extended to define the most significant performance enhancements for a next generation star tracker. Since attitude determination studies tend to be computationally intensive, an approach for using a simpler one degree of freedom formulation is contrasted with a full three degree of freedom formulation. Additionally, covariance analysis results are compared with time domain simulation performance results.

  15. EOS radiometer concepts for soil moisture remote sensing

    NASA Technical Reports Server (NTRS)

    Carr, J.

    1986-01-01

    Preliminary work with aperture synthesis concepts for EOS is reported. The effects of nonvanishing bandwidths on image reconstruction in aperture synthesis system was studied. It is found that nonvanishing bandwidths introduce errors in off-axis pixels when naive Fourier processing is used. The net effect is for bandwidth to limit sensor field-of-view. To quantify this effect a computer program was written which is documented. Example runs are included which illustrate the resultant radiometric errors and effective fields-of-view for a plausible simple sensor.

  16. Reduction of bacteria on spinach, lettuce, and surfaces in food service areas using neutral electrolyzed oxidizing water.

    PubMed

    Guentzel, Jane L; Liang Lam, Kang; Callan, Michael A; Emmons, Stuart A; Dunham, Valgene L

    2008-02-01

    Food safety issues and increases in food borne illnesses have promulgated the development of new sanitation methods to eliminate pathogenic organisms on foods and surfaces in food service areas. Electrolyzed oxidizing water (EO water) shows promise as an environmentally friendly broad spectrum microbial decontamination agent. EO water is generated by the passage of a dilute salt solution ( approximately 1% NaCl) through an electrochemical cell. This electrolytic process converts chloride ions and water molecules into chlorine oxidants (Cl(2), HOCl/ClO(-)). At a near-neutral pH (pH 6.3-6.5), the predominant chemical species is the highly biocidal hypochlorous acid species (HOCl) with the oxidation reduction potential (ORP) of the solution ranging from 800 to 900mV. The biocidal activity of near-neutral EO water was evaluated at 25 degrees C using pure cultures of Escherichia coli, Salmonella typhimurium, Staphylococcus aureus, Listeria monocytogenes, and Enterococcus faecalis. Treatment of these organisms, in pure culture, with EO water at concentrations of 20, 50, 100, and 120ppm total residual chlorine (TRC) and 10min of contact time resulted in 100% inactivation of all five organisms (reduction of 6.1-6.7log(10)CFU/mL). Spray treatment of surfaces in food service areas with EO water containing 278-310ppm TRC (pH 6.38) resulted in a 79-100% reduction of microbial growth. Dip (10min) treatment of spinach at 100 and 120ppm TRC resulted in a 4.0-5.0log(10)CFU/mL reduction of bacterial counts for all organisms tested. Dipping (10min) of lettuce at 100 and 120ppm TRC reduced bacterial counts of E. coli by 0.24-0.25log(10)CFU/mL and reduced all other organisms by 2.43-3.81log(10)CFU/mL. PMID:17993375

  17. CHRONIC EXPOSURE TO DIBROMOACETIC ACID, A WATER DISINFECTION BY-PRODUCT, DIMINISHES PRIMORDIAL FOLLICLES IN THE RABBIT

    EPA Science Inventory

    Exposure to dibromoacetic acid (DBA), a commonly occurring water disinfection by-product, has detrimental effects on spermatogenesis and fertility in rats and rabbits. Despite indications of important reproductive consequences of DBA exposure in males, reproductive sequelae follo...

  18. Acid-rain related reconnaissance of water, rock, soil, and sediment chemistry in the Adirondacks during Fall, 1981

    SciTech Connect

    Not Available

    1981-01-01

    This study suggests strongly that inorganic chemical processes, with sulfate and nitrate input from atmospheric deposition and the absence of buffering from carbonate rock, cannot simply account for either the pH or the aluminum concentrations observed in Adirondack surface waters. Instead, organic acids originating from water flow through organic soil layers and wetlands are indicated as possible causes of increased acidity and aluminum concentrations. There are also indications that sulfides in bedrock and the sulfur utilized by vegetation may be important surface-water sulfate sources. Further, in part of the Adirondacks, weathering of calcium-containing non-carbonate aluminosilicate bedrock apparently keeps surface water from reaching ''critical'' acidity levels. Also, appreciable concentrations of heavy metals and persistent insecticides associated with the organic material in some soils and sediments. If mobilized into the food chain, these materials could be causing adverse ecological effects usually attributed to acid precipitation. Recommendations are included for further studies. 13 figs., 29 tabs. (PSB)

  19. 11-Aminoundecanoic acid: a versatile unit for the generation of low molecular weight gelators for water and organic solvents.

    PubMed

    D'Aléo, Anthony; Pozzo, Jean-Luc; Fages, Frédéric; Schmutz, Marc; Mieden-Gundert, Gudrun; Vögtle, Fritz; Caplar, Vesna; Zinic, Mladen

    2004-01-21

    The use of 11-aminoundecanoic acid as a synthetic building-block allows the systematic preparation of (oligo)amide organogelators-including chiral ones-which display remarkable gelation properties in organic solvents and water. PMID:14737543

  20. Removal of dissolved humic acid from water by photocatalytic oxidation using a silver orthophosphate semiconductor

    SciTech Connect

    Hatakeyama, Keisuke; Okuda, Masukazu; Kuki, Takahiro; Esaka, Takao

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ► The photocatalytic property of a silver orthophosphate (Ag{sub 3}PO{sub 4}) was investigated for humic acid degradation. ► The Ag{sub 3}PO{sub 4} shows high photocatalytic activity under visible light. ► The photocatalytic activity was greatly improved by employing the precipitation method. -- Abstract: In order to remove dissolved organic matter such as humic acid from water, a silver orthophosphate (Ag{sub 3}PO{sub 4}) was newly employed as a heterogeneous photocatalyst. Here, Ag{sub 3}PO{sub 4} was prepared by simple ion-exchange and precipitation methods, and the physico-chemical properties were characterized by X-ray diffraction, ultraviolet–visible diffuse reflectance spectroscopy, scanning electron microscopy, particle distribution measurements and Brunauer–Emmett–Teller (BET) analysis. The degradation of humic acid was faster over Ag{sub 3}PO{sub 4} catalyst than over conventional TiO{sub 2} (P-25). The total photocatalytic properties were improved by employing not an ion-exchange method but a precipitation method; humic acid degradation was performed with a removal ratio of dissolved organic carbon of 75% under visible light (λ = 451 nm) for 2-h irradiation.