Science.gov

Sample records for active hydrothermal processes

  1. Hydrothermal Processes

    NASA Astrophysics Data System (ADS)

    German, C. R.; von Damm, K. L.

    2003-12-01

    species escape from the seafloor in high abundance. When they do, the buoyancy of the high-temperature fluids carries them hundreds of meters up into the overlying water column as they mix and eventually form nonbuoyant plumes containing a wide variety of both dissolved chemicals and freshly precipitated mineral phases. The processes active within these dispersing hydrothermal plumes play a major role in determining the net impact of hydrothermal circulation upon the oceans and marine geochemistry.

  2. Hydrothermal Processing

    SciTech Connect

    Elliott, Douglas C.

    2011-03-11

    This chapter is a contribution to a book on Thermochemical Conversion of Biomass being edited by Prof. Robert Brown of Iowa State University. It describes both hydrothermal liquefaction and hydrothermal gasification of biomass to fuels.

  3. Enceladus: Starting Hydrothermal Activity

    NASA Technical Reports Server (NTRS)

    Matson, D. L.; Castillo-Rogez, J. C.; Johnson, T. V.; Lunine, J. I.; Davies, A. G.

    2011-01-01

    We describe a process for starting the hydrothermal activity in Enceladus' South Polar Region. The process takes advantage of fissures that reach the water table, about 1 kilometer below the surface. Filling these fissures with fresh ocean water initiates a flow of water up from an ocean that can be self-sustaining. In this hypothesis the heat to sustain the thermal anomalies and the plumes comes from a slightly warm ocean at depth. The heat is brought to the surface by water that circulates up, through the crust and then returns to the ocean.

  4. Hydrothermal activity in Tertiary Icelandic crust: Implication for cooling processes along slow-spreading mid-ocean ridges

    NASA Astrophysics Data System (ADS)

    Pałgan, D.; Devey, C. W.; Yeo, I. A.

    2015-12-01

    Known hydrothermal activity along the Mid-Atlantic Ridge is mostly high-temperature venting, controlled by volcano-tectonic processes confined to ridge axes and neotectonic zones ~15km wide on each side of the axis (e.g. TAG or Snake Pit). However, extensive exploration and discoveries of new hydrothermal fields in off-axis regions (e.g. Lost City, MAR) show that hydrothermalism may, in some areas, be dominated by off-axis venting. Little is known about nature of such systems, including whether low-temperature "diffuse" venting dominates rather than high-temperature black-smokers. This is particularly interesting since such systems may transport up to 90% of the hydrothermal heat to the oceans. In this study we use Icelandic hot springs as onshore analogues for off-shore hydrothermal activity along the MAR to better understand volcano-tectonic controls on their occurrence, along with processes supporting fluid circulation. Iceland is a unique laboratory to study how new oceanic crust cools and suggests that old crust may not be as inactive as previously thought. Our results show that Tertiary (>3.3 Myr) crust of Iceland (Westfjords) has widespread low-temperature hydrothermal activity. Lack of tectonism (indicated by lack of seismicity), along with field research suggest that faults in Westfjords are no longer active and that once sealed, can no longer support hydrothermal circulation, i.e. none of the hot springs in the area occur along faults. Instead, dyke margins provide open and permeable fluid migration pathways. Furthermore, we suggest that the Reykjanes Ridge (south of Iceland) may be similar to Westfjords with hydrothermalism dominated by off-axis venting. Using bathymetric data we infer dyke positions and suggest potential sites for future exploration located away from neotectonic zone. We also emphasise the importance of biological observations in seeking for low-temperature hydrothermal activity, since chemical or optical methods are not sufficient.

  5. Hydrothermal processes at seafloor spreading centers,

    SciTech Connect

    Rona, P.A.; Bostrom, K.; Laubier, L.; Smith, K.L.

    1983-01-01

    This book examines research on the description and interpretation of hydrothermal and associated phenomena at seafloor spreading centers. An interdisciplinary overview of the subject is presented, including geological, geophysical, geochemical, and biological discoveries. The implications of the discoveries for understanding the earth's heat transfer, geochemical mass balances and cycles, mineralization, and biological adaptation are discussed. Topics considered include geologic setting (e.g., the four dimensions of the spreading axis, geological processes of the mid-ocean ridge), hydrothermal convection (e.g., oxygen and hydrogen isotope studies, the basic physics of water penetration into hot rock), Iceland and oceanic ridges (e.g., chemical evidence from Icelandic geothermal systems, the physical environment of hydrothermal systems), mass balances and cycles (e.g., reduced gases and bacteria in hydrothermal fluids, the effects of hydrothermal activity on sedimentary organic matter), ferromanganese deposits, hydrothermal mineralization, and the biology of hydrothermal vents.

  6. Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

    USGS Publications Warehouse

    Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.

    2009-01-01

    Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confi ning pressure causes fluids to fl ash to steam, resulting in signifi cant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially signifi cant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identifi ed; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ??1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing

  7. Hydrothermal activity and subsurface soil complexity: implication for outgassing processes at Solfatara crater, Campi Flegrei caldera

    NASA Astrophysics Data System (ADS)

    Montanaro, Cristian; Mayer, Klaus; Scheu, Bettina; Isaia, Roberto; Mangiacapra, Annarita; Gresse, Marceau; Vandemeulebrouck, Jean; Moretti, Roberto; Dingwell, Donald B.

    2016-04-01

    The Solfatara area and its fumaroles are the main surface phenomena of the vigorous hydrothermal activity within the active Campi Flegrei caldera system. The existing fault system appears to have a major control on outgassing which in turn leads to a strong alteration of the volcanic products. Moreover the maar-nature of the crater, and its filling by more recent volcanic deposits, resulted in a complex fractured and multilayered cap to the rising gases. As a consequence the hydrothermal alteration differently affects the rocks within the crater, including pyroclastic fallout ash beds, pyroclastic density current deposits, breccias and lavas. The induced changes in both original microstructure and physical and mechanical properties of the rocks control the outgassing behavior. Here, we report results from a measurement survey conducted in July 2015, and aimed to characterize the in-situ physical (temperature, humidity) and mechanical (permeability, strength, stiffness) properties. The survey also included a mapping of the surficial hydrothermal features and their distributions. Chemical analyses and laboratory measurements (porosity, granulometry) of selected samples were additionally performed. Results show that the crater floor area comprises very different kinds of soils, from fine grained, thin laminated deposits around the two bubbling Fangaia mud pools, to crusted hummock formations along the SE and NE border of the crater. Dry and solid alunite-rich deposits are present in the western and southern part. Furthermore we observed evidences of a beginning of crust formation within the central part of the crater. A large range of surface temperatures, from boiling point to ambient temperature, were measured throughout the surveyed area. Outgassing occurs mainly along the crack system, which has also generated the crusted hummocks. Elsewhere the fluid circulation in the subsoil is favored by the presence of coarse and highly porous sulfur-hardened levels, whereas

  8. Arctic Ocean: hydrothermal activity on Gakkel Ridge.

    PubMed

    Jean-Baptiste, Philippe; Fourré, Elise

    2004-03-01

    In the hydrothermal circulation at mid-ocean ridges, sea water penetrates the fractured crust, becomes heated by its proximity to the hot magma, and returns to the sea floor as hot fluids enriched in various chemical elements. In contradiction to earlier results that predict diminishing hydrothermal activity with decreasing spreading rate, a survey of the ultra-slowly spreading Gakkel Ridge (Arctic Ocean) by Edmonds et al. and Michael et al. suggests that, instead of being rare, the hydrothermal activity is abundant--exceeding by at least a factor of two to three what would be expected by extrapolation from observation on faster spreading ridges. Here we use helium-3 (3He), a hydrothermal tracer, to show that this abundance of venting sites does not translate, as would be expected, into an anomalous hydrothermal 3He output from the ridge. Because of the wide implications of the submarine hydrothermal processes for mantle heat and mass fluxes to the ocean, these conflicting results call for clarification of the link between hydrothermal activity and crustal production at mid-ocean ridges.

  9. Active Volcanic and Hydrothermal Processes at NW Rota-1 Submarine Volcano: Mariana Volcanic Arc

    NASA Astrophysics Data System (ADS)

    Embley, R. W.; Baker, E. T.; Butterfield, D. A.; Chadwick, W. W.; de Ronde, C.; Dower, J.; Evans, L.; Hein, J.; Juniper, K.; Lebon, G.; Lupton, J. E.; Merle, S.; Metaxas, A.; Nakamura, K.; Resing, J. E.; Roe, K.; Stern, R.; Tunnicliffe, V.

    2004-12-01

    Dives with the remotely operated vehicle ROPOS in March/April 2004 documented a volcanic eruption at NW Rota-1, a submarine volcano of basaltic composition located at 14\\deg 36.0'N, 144\\deg 46.5'E lying 65 km northwest of Rota Island in the Commonwealth of the Northern Mariana Islands. The site was chosen as a dive target because of the of the high concentrations of H2S and alunite in the hydrothermal plume overlying its summit in February 2003. The summit of the volcano is composed of curvilinear volcanic ridge oriented NW-SE bounded by NE-SW trending normal faults. Lavas collected on the upper part of the edifice are primitive to moderately fractionated basalts (Mg# = 51-66). The eruptive activity is occurring within a small crater (Brimstone Pit) located on the upper south flank of the volcano at 550 m, about 30 m below the summit. The crater is approximately 15 m wide and at least 20 meters deep. The ROPOS's cameras observed billowing clouds of sulfur-rich fluid rising out of the crater, punctuated by frequent bursts of several minutes duration that entrained glassy volcanic ejecta up to at least 2 cm in diameter. ROPOS recorded a temperature of 38\\degC within the plume. The volcanic activity had substantial temporal variability on the scale of minutes. ROPOS was sometimes completely enveloped by the plume while on the rim of the crater, and its surfaces were coated with large sulfur droplets. Black glassy fragments were entrained in the plume up to least 50 m above the crater and deposits of this material were on ledges and tops of outcrops up to several hundred meters from Brimstone Pit. The pit crater fluids have an extremely high content of particulate sulfur and extremely acidic, with pH around 2.0. This strongly implicates magmatic degassing of SO2 and disproportionation into elemental S and sulfuric acid. Diffuse venting of clear fluids was also present on the summit of the volcano, with temperatures exceeding 100\\degC in volcaniclastic sands

  10. Antioxidant activities of crude extracts of fucoidan extracted from Sargassum glaucescens by a compressional-puffing-hydrothermal extraction process.

    PubMed

    Huang, Chun-Yung; Wu, Shu-Jing; Yang, Wen-Ning; Kuan, Ai-Wei; Chen, Cheng-Yo

    2016-04-15

    Fucoidan, a multifunctional marine polymer, is normally extracted from brown algae via extensive use of acid, solvent or high temperature water and a long reaction time. In present study, we developed a novel compressional-puffing-hydrothermal extraction (CPHE) process which primarily decomposes the cellular structure of algae and facilitates the release of fucoidan by hot water extraction. The CPHE process provides a number of advantages including simple procedure, reactant-saving, reduced pollution, and feasibility for continuous production. Sargassum glaucescens (SG) was utilized in this study, and the maximum extraction yield of polysaccharide was approximately 9.83 ± 0.11% (SG4). Thin layer chromatography (TLC), Fourier transform infrared (FTIR) analysis, and measurements of monosaccharide composition, fucose, sulfate, and uronic acid contents revealed that the extracted polysaccharide showed characteristics of fucoidan. All extracts exhibited antioxidant activities, and thus, further exploration of these extracts as potential natural and safe antioxidant agents is warranted.

  11. Antioxidant activities of crude extracts of fucoidan extracted from Sargassum glaucescens by a compressional-puffing-hydrothermal extraction process.

    PubMed

    Huang, Chun-Yung; Wu, Shu-Jing; Yang, Wen-Ning; Kuan, Ai-Wei; Chen, Cheng-Yo

    2016-04-15

    Fucoidan, a multifunctional marine polymer, is normally extracted from brown algae via extensive use of acid, solvent or high temperature water and a long reaction time. In present study, we developed a novel compressional-puffing-hydrothermal extraction (CPHE) process which primarily decomposes the cellular structure of algae and facilitates the release of fucoidan by hot water extraction. The CPHE process provides a number of advantages including simple procedure, reactant-saving, reduced pollution, and feasibility for continuous production. Sargassum glaucescens (SG) was utilized in this study, and the maximum extraction yield of polysaccharide was approximately 9.83 ± 0.11% (SG4). Thin layer chromatography (TLC), Fourier transform infrared (FTIR) analysis, and measurements of monosaccharide composition, fucose, sulfate, and uronic acid contents revealed that the extracted polysaccharide showed characteristics of fucoidan. All extracts exhibited antioxidant activities, and thus, further exploration of these extracts as potential natural and safe antioxidant agents is warranted. PMID:26675848

  12. Microbial bio-mineralization processes in hydrothermal travertine: the case study of two active travertine systems (Tuscany, Italy).

    NASA Astrophysics Data System (ADS)

    Barilaro, Federica; Bontognali, Tomaso R. R.; Mc Kenzie, Judith A.; Vasconcelos, Crisogono

    2015-04-01

    Modern hydrothermal travertine deposits, occurring today at Bagni San Filippo (Radicofani Basin) and at Bagni di Saturnia (Albegna Valley) in Tuscany, Central Italy, have been investigated with the main purpose to improve the understanding of the processes that control calcium carbonate precipitation in hydrothermal-spring settings. Present-day thermal activity at Bagni di Saturnia is characterized by a 37.5°C thermal spring with a rate of about 800 l/s, with a pH of ca. 6.4. Thermal water discharges at Bagni San Filippo reach a rate of 20 litres per second at a maximum temperature of 50°C and a pH of ca. 7. The springs expel water enriched in H2S-CO2-SO42- and HCO3- and divalent cations (Ca and Mg). In the studied areas, travertine precipitation occurs in association with living microbial mats and biofilms, composed of a heterogeneous community of green algae, filamentous cyanobacteria and other types of prokaryotes, anoxygenic photosynthetic bacteria and heterotrophic heat-tolerant bacteria, with a variable amount of extracellular polymeric substances (EPS). Nine categories of fabric types, dominantly calcite and aragonite in composition, showing a wide range of macro- and micro-porosity, have been identified. High magnification analysis of dendritic and laminated boundstone, crystalline crust cementstone, raft boundstone, coated bubble boundstone, micrite mudstone and coated reed boundstone fabric types, suggests that precipitation occurs in association with organic matter. Diatoms, cyanobacteria filaments and other bacteria are then associated with the EPS and often appear totally or partially entombed (passively or actively) in it. Organic extracellular polymeric substances (EPS) and often the external surface of cyanobacterial sheaths are the location where the calcite minerals nucleate and grow. Precipitation begins with organomineral nano-globules consisting of nanometre-size, from sub-spherical to globular-like, raised structures (5 to 80 nm diameter

  13. Mineral elements, lipoxygenase activity, and antioxidant capacity of okara as a byproduct in hydrothermal processing of soy milk.

    PubMed

    Stanojevic, Sladjana P; Barac, Miroljub B; Pesic, Mirjana B; Zilic, Sladjana M; Kresovic, Mirjana M; Vucelic-Radovic, Biljana V

    2014-09-10

    Minerals and antioxidative capacity of raw okara that was obtained as a byproduct from six soybean varieties during hydrothermal cooking (HTC) of soy milk were assessed. Lipoxygenase (Lox), an enzyme deteriorating the sensory characteristics of okara, was also investigated. All genotypes had very similar concentrations of Lox (4.32-5.62%). Compared to raw soybeans, the applied HTC significantly reduced Lox content in okara (0.54-0.19%) and lowered its activity to 0.004-0.007 μmol g(-1) min (-1). Correlation between the content of Lox in soybeans and that in okara (r = 0.21;p < 0.05) was not registered. This indicates that the content of this enzyme in okara depended much more on the technological process than on soybean genotype. Very strong correlation (r = 0.99; p < 0.05) between okara Lox content and its activity was found. The most abundant minerals in raw okara were potassium (1.04-1.21 g/100g), phosphorus (0.45-0.50 g/100 g), calcium (0.26-0.39 g/100 g), and iron (5.45-10.95 mg/100 g). A very high antioxidant capacity (19.06-29.36 mmol Trolox kg(-1)) contributes to the nutritional value of raw okara. PMID:25167333

  14. Experimental constraints on hydrothermal activities in Enceladus

    NASA Astrophysics Data System (ADS)

    Sekine, Y.; Shibuya, T.; Suzuki, K.; Kuwatani, T.

    2012-12-01

    One of the most remarkable findings by the Cassini-Huygens mission is perhaps water-rich plumes erupting from the south-pole region of Enceladus [1]. Given such geological activity and the detection of sodium salts in the plume, the interior of Enceladus is highly likely to contain an interior ocean interacting with the rock core [2]. A primary question regarding astrobiology and planetary science is whether Enceladus has (or had) hydrothermal activities in the interior ocean. Because N2 might be formed by thermal dissociation of primordial NH3 [3], the presence of N2 in the plume may be a possible indicator for the presence of hydrothermal activities in Enceladus. However, the Cassini UVIS revealed that the plumes do not contain large amounts of N2 [4]. Although these observations may not support the presence of hydrothermal activities, whether NH3 dissociation proceeds strongly depends on the kinetics of hydrothermal reactions and interactions with the rock components, which remain largely unknown. Furthermore, the Cassini CDA recently showed that small amounts of SiO2 might have been included in the plume dusts [5]. Formation of amorphous SiO2 usually occurs when high-temperature and/or high-pH solution with high concentrations of dissolved SiO2 cools and/or is neutralized. Thus, the presence of SiO2 in the plume dusts may suggest the presence of a temperature and/or pH gradient in the ocean. However, no laboratory experiments have investigated what processes control pH and SiO2 concentrations in hydrothermal fluids possibly existing in Enceladus. Here, we show the results of laboratory experiments simulating hydrothermal systems on Enceladus. As the initial conditions, we used both aqueous solution of high concentrations (0.01-2%) of NH3 and NaHCO3 and powdered olivine as an analog for the rock components. Our experimental results show that formation of N2 from NH3 is kinetically and thermodynamically inhibited even under high temperature conditions (< 400

  15. Ongoing hydrothermal activities within Enceladus.

    PubMed

    Hsu, Hsiang-Wen; Postberg, Frank; Sekine, Yasuhito; Shibuya, Takazo; Kempf, Sascha; Horányi, Mihály; Juhász, Antal; Altobelli, Nicolas; Suzuki, Katsuhiko; Masaki, Yuka; Kuwatani, Tatsu; Tachibana, Shogo; Sirono, Sin-iti; Moragas-Klostermeyer, Georg; Srama, Ralf

    2015-03-12

    Detection of sodium-salt-rich ice grains emitted from the plume of the Saturnian moon Enceladus suggests that the grains formed as frozen droplets from a liquid water reservoir that is, or has been, in contact with rock. Gravitational field measurements suggest a regional south polar subsurface ocean of about 10 kilometres thickness located beneath an ice crust 30 to 40 kilometres thick. These findings imply rock-water interactions in regions surrounding the core of Enceladus. The resulting chemical 'footprints' are expected to be preserved in the liquid and subsequently transported upwards to the near-surface plume sources, where they eventually would be ejected and could be measured by a spacecraft. Here we report an analysis of silicon-rich, nanometre-sized dust particles (so-called stream particles) that stand out from the water-ice-dominated objects characteristic of Saturn. We interpret these grains as nanometre-sized SiO2 (silica) particles, initially embedded in icy grains emitted from Enceladus' subsurface waters and released by sputter erosion in Saturn's E ring. The composition and the limited size range (2 to 8 nanometres in radius) of stream particles indicate ongoing high-temperature (>90 °C) hydrothermal reactions associated with global-scale geothermal activity that quickly transports hydrothermal products from the ocean floor at a depth of at least 40 kilometres up to the plume of Enceladus. PMID:25762281

  16. Ongoing hydrothermal activities within Enceladus.

    PubMed

    Hsu, Hsiang-Wen; Postberg, Frank; Sekine, Yasuhito; Shibuya, Takazo; Kempf, Sascha; Horányi, Mihály; Juhász, Antal; Altobelli, Nicolas; Suzuki, Katsuhiko; Masaki, Yuka; Kuwatani, Tatsu; Tachibana, Shogo; Sirono, Sin-iti; Moragas-Klostermeyer, Georg; Srama, Ralf

    2015-03-12

    Detection of sodium-salt-rich ice grains emitted from the plume of the Saturnian moon Enceladus suggests that the grains formed as frozen droplets from a liquid water reservoir that is, or has been, in contact with rock. Gravitational field measurements suggest a regional south polar subsurface ocean of about 10 kilometres thickness located beneath an ice crust 30 to 40 kilometres thick. These findings imply rock-water interactions in regions surrounding the core of Enceladus. The resulting chemical 'footprints' are expected to be preserved in the liquid and subsequently transported upwards to the near-surface plume sources, where they eventually would be ejected and could be measured by a spacecraft. Here we report an analysis of silicon-rich, nanometre-sized dust particles (so-called stream particles) that stand out from the water-ice-dominated objects characteristic of Saturn. We interpret these grains as nanometre-sized SiO2 (silica) particles, initially embedded in icy grains emitted from Enceladus' subsurface waters and released by sputter erosion in Saturn's E ring. The composition and the limited size range (2 to 8 nanometres in radius) of stream particles indicate ongoing high-temperature (>90 °C) hydrothermal reactions associated with global-scale geothermal activity that quickly transports hydrothermal products from the ocean floor at a depth of at least 40 kilometres up to the plume of Enceladus.

  17. Catastrophic volcanic collapse: relation to hydrothermal processes.

    PubMed

    López, D L; Williams, S N

    1993-06-18

    Catastrophic volcanic collapse, without precursory magmatic activity, is characteristic of many volcanic disasters. The extent and locations of hydrothermal discharges at Nevado del Ruiz volcano, Colombia, suggest that at many volcanoes collapse may result from the interactions between hydrothermal fluids and the volcanic edifice. Rock dissolution and hydrothermal mineral alteration, combined with physical triggers such as earth-quakes, can produce volcanic collapse. Hot spring water compositions, residence times, and flow paths through faults were used to model potential collapse at Ruiz. Caldera dimensions, deposits, and alteration mineral volumes are consistent with parameters observed at other volcanoes.

  18. Microbial processing of carbon in hydrothermal systems (Invited)

    NASA Astrophysics Data System (ADS)

    LaRowe, D.; Amend, J. P.

    2013-12-01

    Microorganisms are known to be active in hydrothermal systems. They catalyze reactions that consume and produce carbon compounds as a result of their efforts to gain energy, grow and replace biomass. However, the rates of these processes, as well as the size of the active component of microbial populations, are poorly constrained in hydrothermal environments. In order to better characterize biogeochemical processes in these settings, a quantitative relationship between rates of microbial catalysis, energy supply and demand and population size is presented. Within this formulation, rates of biomass change are determined as a function of the proportion of catabolic power that is converted into biomass - either new microorganisms or the replacement of existing cell components - and the amount of energy that is required to synthesize biomass. The constraints that hydrothermal conditions place on power supply and demand are explicitly taken into account. The chemical composition, including the concentrations of organic compounds, of diffuse and focused flow hydrothermal fluids, hydrothermally influenced sediment pore water and fluids from the oceanic lithosphere are used in conjunction with cell count data and the model described above to constrain the rates of microbial processes that influence the carbon cycle in the Juan de Fuca hydrothermal system.

  19. Synthesis of large surface area nano-sized BiVO{sub 4} by an EDTA-modified hydrothermal process and its enhanced visible photocatalytic activity

    SciTech Connect

    Sun Wanting; Xie Mingzheng; Jing Liqiang; Luan Yunbo; Fu Honggang

    2011-11-15

    In this work, monoclinic scheelite-type BiVO{sub 4} nanoparticle with large surface area has been successfully synthesized, using Bi(NO{sub 3}){sub 3} and NH{sub 4}VO{sub 3} as raw materials, through a hydrothermal process in the presence of ethylene diamine tetraacetic acid (EDTA). It is demonstrated that the nanoparticle size of as-prepared BiVO{sub 4} becomes small by decreasing hydrothermal temperature, shortening hydrothermal reaction time and increasing EDTA amount used. The resulting BiVO{sub 4} nanoparticle with large surface area exhibits a good photocatalytic performance for degrading phenol solution as a model organic pollutant under visible illumination. The key of this method is the chelating role of EDTA group in the synthetic process that it can greatly control the concentration of Bi{sup 3+}, leading to the growth inhibition of BiVO{sub 4} crystallite. The work provides a route for the synthesis of Bi-containing nano-sized composite oxides with large surface area. - Graphical abstract: High visible active nano-sized BiVO{sub 4} photocatalyst with large surface area is successfully synthesized, which is attributed to the chelating role of EDTA group inhibiting the growth of BiVO{sub 4} crystallites. Highlights: > Monoclinic scheelite-type BiVO{sub 4} nanoparticle with large surface area has been synthesized by a hydrothermal process. > Key of this method is the chelating role of EDTA group inhibiting the growth of BiVO{sub 4} crystallites. > Resulting nano-sized BiVO{sub 4} exhibits a good photocatalytic activity for degrading phenol under visible illumination.

  20. Hydrothermal processing of Hanford tank wastes: Process modeling and control

    SciTech Connect

    Currier, R.P.

    1994-10-01

    In the Los Alamos National Laboratory (LANL) hydrothermal process, waste streams are first pressurized and heated as they pass through a continuous flow tubular reactor vessel. The waste is maintained at reaction temperature of 300--550 C where organic destruction and sludge reformation occur. This report documents LANL activities in process modeling and control undertaken in FY94 to support hydrothermal process development. Key issues discussed include non-ideal flow patterns (e.g. axial dispersion) and their effect on reactor performance, the use and interpretation of inert tracer experiments, and the use of computational fluid mechanics to evaluate novel hydrothermal reactor designs. In addition, the effects of axial dispersion (and simplifications to rate expressions) on the estimated kinetic parameters are explored by non-linear regression to experimental data. Safety-related calculations are reported which estimate the explosion limits of effluent gases and the fate of hydrogen as it passes through the reactor. Development and numerical solution of a generalized one-dimensional mathematical model is also summarized. The difficulties encountered in using commercially available software to correlate the behavior of high temperature, high pressure aqueous electrolyte mixtures are summarized. Finally, details of the control system and experiments conducted to empirically determine the system response are reported.

  1. Hydrothermal processing of radioactive combustible waste

    SciTech Connect

    Worl, L.A.; Buelow, S.J.; Harradine, D.; Le, L.; Padilla, D.D.; Roberts, J.H.

    1998-09-01

    Hydrothermal processing has been demonstrated for the treatment of radioactive combustible materials for the US Department of Energy. A hydrothermal processing system was designed, built and tested for operation in a plutonium glovebox. Presented here are results from the study of the hydrothermal oxidation of plutonium and americium contaminated organic wastes. Experiments show the destruction of the organic component to CO{sub 2} and H{sub 2}O, with 30 wt.% H{sub 2}O{sub 2} as an oxidant, at 540 C and 46.2 MPa. The majority of the actinide component forms insoluble products that are easily separated by filtration. A titanium liner in the reactor and heat exchanger provide corrosion resistance for the oxidation of chlorinated organics. The treatment of solid material is accomplished by particle size reduction and the addition of a viscosity enhancing agent to generate a homogeneous pumpable mixture.

  2. Introduction to Atlantic Hydrothermal Activity

    NASA Astrophysics Data System (ADS)

    Rona, Peter A.; Thompson, Geoffrey

    1993-06-01

    Seafloor hydrothermal research has advanced rapidly from local to global scope through a sequence of discoveries. Hydrothermal research at seafloor spreading centers began in the mid-1960s with the discovery of hot metalliferous brines and sediments ponded in deeps along the slow spreading (half rate 1 cm yr-1) axis of the Red Sea [Chamock, 1964; Miller, 1964; Swallow and Crease, 1965; Miller et al., 1966; Hunt et al., 1967; Bischoff, 1969]. At the same time a hydrothermal metalliferous component was identified in sediments of the East Pacific Rise [Skomyakova, 1965; Arrhenins and Bonatti, 1965; Boström and Peterson, 1966]. Geophysicists recognized that heat flow measurements at spreading centers could only be explained by convective cooling of the crust with circulating seawater [Elder, 1967; Lister, 1972].

  3. Effects of process parameters on hydrothermal carbonization

    NASA Astrophysics Data System (ADS)

    Uddin, Md. Helal

    In recent years there has been increased research activity in renewable energy, especially upgrading widely available lignicellulosic biomass, in a bid to counter the increasing environmental concerns related with the use of fossil fuels. Hydrothermal carbonization (HTC), also known as wet torrefaction or hot water pretreatment, is a process for pretreatment of diverse lignocellulosic biomass feedstocks, where biomass is treated under subcritical water conditions in short contact time to produce high-value products. The products of this process are: a solid mass characterized as biochar/biocoal/biocarbon, which is homogeneous, energy dense, and hydrophobic; a liquid stream composed of five and six carbon sugars, various organic acids, and 5-HMF; and a gaseous stream, mainly CO2. A number of process parameters are considered important for the extensive application of the HTC process. Primarily, reaction temperature determines the characteristics of the products. In the solid product, the oxygen carbon ratio decreases with increasing reaction temperature and as a result, HTC biochar has the similar characteristics to low rank coal. However, liquid and gaseous stream compositions are largely correlated with the residence time. Biomass particle size can also limit the reaction kinetics due to the mass transfer effect. Recycling of process water can help to minimize the utility consumption and reduce the waste treatment cost as a result of less environmental impact. Loblolly pine was treated in hot compressed water at 200 °C, 230 °C, and 260 °C with 5:1 water:biomass mass ratio to investigate the effects of process parameters on HTC. The solid product were characterized by their mass yields, higher heating values (HHV), and equilibrium moisture content (EMC), while the liquid were characterized by their total organic carbon content and pH value.

  4. Hydrothermal alkali metal recovery process

    DOEpatents

    Wolfs, Denise Y.; Clavenna, Le Roy R.; Eakman, James M.; Kalina, Theodore

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  5. Hydrothermal processes at seafloor spreading centers,

    SciTech Connect

    Sleep, N.H.

    1983-01-01

    This chapter discusses the initial entry of hydrothermal seawater into deep levels of the oceanic crust, the effectiveness of hydrothermal circulation in cooling the crust, the geometry of hydrothermal circulation, the relationship between the hydrothermal circulation and the magma chamber, the reaction of the oceanic crust with the seawater, and the identification of the hydrothermal fluid which alters a rock sample. Topics considered include the crack front, observation relevant to the crack front, the limitations of the crack front hypothesis, the observed pattern of hydrothermal alteration, the nature of the hydrothermal fluid, the physics of large scale convection, and convection through crack zones. Knowledge of hydrothermal circulation at the ridge axis is based on sampling of the hydrothermal fluid, indirect geophysical measurements of the oceanic crust, and studies of rocks which are believed to have undergone hydrothermal alteration at the ridge axis. Includes 2 drawings.

  6. Hydrothermal processes at Mount Rainier, Washington

    SciTech Connect

    Frank, D.G.

    1985-01-01

    Field studies and thermal-infrared mapping at Mount Rainier indicate areas of active hydrothermal alteration where excess surface heat flux is about 9 megawatts. Three representative settings include: (1) An extensive area (greater than 12,000 m/sup 2/) of heated ground and slightly acidic boiling-point fumaroles at 76-82/sup 0/C at East and West Craters on the volcano's summit; (2) A small area (less than 500 m/sup 2/) of heated ground and sub-boiling-point fumaroles at 55-60/sup 0/C on the upper flank at Disappointment Cleaver, and other probably similar areas at Willis Wall, Sunset Amphitheater, and the South Tahoma and Kautz headwalls; (3) Sulfate and carbon dioxide enriched thermal springs at 9-24/sup 0/C on the lower flank of the volcano in valley walls beside the Winthrop and Paradise Glaciers. In addition, chloride- and carbon dioxide-enriched thermal springs issue from thin sediments that overlie Tertiary rocks at, or somewhat beyond, the base of the volcanic edifice in valley bottoms of the Nisqually and Ohanapecosh Rivers where maximum spring temperatures are 19-25/sup 0/C, respectively, and where extensive travertine deposits have developed. The heat flow, distribution of thermal activity, and nature of alteration products indicate that a narrow, central hydrothermal system exists within Mount Rainier forming steam-heated snowmelt at the summit craters and localized leakage of steam-heated fluids within 2 kilometers of the summit. The lateral extent of the hydrothermal system is limited in that only sparse, neutral sulfate-enriched thermal water issues from the lower flank of the cone. Simulations of geochemical mass transfer suggest that the thermal springs may be derived from an acid sulfate-chloride parent fluid which has been neutralized by reaction with andesite and highly diluted with shallow ground water.

  7. Anaerobic digestion of post-hydrothermal liquefaction wastewater for improved energy efficiency of hydrothermal bioenergy processes.

    PubMed

    Zhou, Yan; Schideman, Lance; Zheng, Mingxia; Martin-Ryals, Ana; Li, Peng; Tommaso, Giovana; Zhang, Yuanhui

    2015-01-01

    Hydrothermal liquefaction (HTL) is a promising process for converting wet biomass and organic wastes into bio-crude oil. It also produces an aqueous product referred to as post-hydrothermal liquefaction wastewater (PHWW) containing up to 40% of the original feedstock carbon, which reduces the overall energy efficiency of the HTL process. This study investigated the feasibility of using anaerobic digestion (AD) to treat PHWW, with the aid of activated carbon. Results showed that successful AD occurred at relatively low concentrations of PHWW (≤ 6.7%), producing a biogas yield of 0.5 ml/mg CODremoved, and ∼53% energy recovery efficiency. Higher concentrations of PHWW (≥13.3%) had an inhibitory effect on the AD process, as indicated by delayed, slower, or no biogas production. Activated carbon was shown to effectively mitigate this inhibitory effect by enhancing biogas production and allowing digestion to proceed at higher PHWW concentrations (up to 33.3%), likely due to sequestering toxic organic compounds. The addition of activated carbon also increased the net energy recovery efficiency of AD with a relatively high concentration of PHWW (33.3%), taking into account the energy for producing activated carbon. These results suggest that AD is a feasible approach to treat PHWW, and to improve the energy efficiency of the HTL processes. PMID:26676001

  8. Anaerobic digestion of post-hydrothermal liquefaction wastewater for improved energy efficiency of hydrothermal bioenergy processes.

    PubMed

    Zhou, Yan; Schideman, Lance; Zheng, Mingxia; Martin-Ryals, Ana; Li, Peng; Tommaso, Giovana; Zhang, Yuanhui

    2015-01-01

    Hydrothermal liquefaction (HTL) is a promising process for converting wet biomass and organic wastes into bio-crude oil. It also produces an aqueous product referred to as post-hydrothermal liquefaction wastewater (PHWW) containing up to 40% of the original feedstock carbon, which reduces the overall energy efficiency of the HTL process. This study investigated the feasibility of using anaerobic digestion (AD) to treat PHWW, with the aid of activated carbon. Results showed that successful AD occurred at relatively low concentrations of PHWW (≤ 6.7%), producing a biogas yield of 0.5 ml/mg CODremoved, and ∼53% energy recovery efficiency. Higher concentrations of PHWW (≥13.3%) had an inhibitory effect on the AD process, as indicated by delayed, slower, or no biogas production. Activated carbon was shown to effectively mitigate this inhibitory effect by enhancing biogas production and allowing digestion to proceed at higher PHWW concentrations (up to 33.3%), likely due to sequestering toxic organic compounds. The addition of activated carbon also increased the net energy recovery efficiency of AD with a relatively high concentration of PHWW (33.3%), taking into account the energy for producing activated carbon. These results suggest that AD is a feasible approach to treat PHWW, and to improve the energy efficiency of the HTL processes.

  9. Hydrothermal Activity in the Northern Guaymas Basin

    NASA Astrophysics Data System (ADS)

    Berndt, C.; Hensen, C.; Mortera-Gutierrez, C. A.; Sarkar, S.; Geilert, S.; Schmidt, M.; Liebetrau, V.; Kipfer, R.; Scholz, F.; Doll, M.; Muff, S.; Karstens, J.; Böttner, C.; Chi, W. C.; Moser, M.; Behrendt, R.; Fiskal, A.; Evans, T.; Planke, S.; Lizarralde, D.; Lever, M. A.

    2015-12-01

    Rift-related magmatism in the Guaymas Basin, Gulf of California induces hydrothermal activity within the basin sediments. Mobilized fluids migrate to the seafloor where they are emitted into the water column changing ocean chemistry and fuelling chemosynthetic ecosystems. New seismic and geochemical data from the northern rift arm of the Guaymas Basin document the variety of fluid expulsion phenomena from large-scale subsurface sediment mobilization related to contact metamorphosis to focused small-scale structures. The geochemical composition of emitted fluids depends largely on the age of the fluid escape structures with respect to the underlying intrusions. Whereas, old structures are dominated by methane emission, young vent sites are characterized by hot fluids that carry a wide range of minerals in solution. The overall high geothermal gradient within the basin (mainly between 160 and 260 °C/km) leads to a thin gas hydrate stability zone. Thus, deep hydrothermal fluid advection affects the gas hydrate system and makes it more dynamic than in colder sedimentary basins.

  10. Hydrothermal processing of new fly ash cement

    SciTech Connect

    Jiang, W.; Roy, D.M. )

    1992-04-01

    The recent Mount Pinatubo volcanic eruption in the Philippines, in which at least 268 people died, shows that volcanic eruptions can be highly destructive. The eruption shot ash and debris over the countryside; six towns near the volcano faced a high risk of devastating mudslides, and nearly 2000 U.S. service members and their families were evacuated from two nearby military bases. However, this paper reports that not all the consequences of volcanic eruptions are bad. Under hydrothermal conditions, volcanic ash can be transformed into zeolitic tuff and, eventually, into clay minerals that constitute agricultural soils. The Materials Research Laboratory (MRL) has recently used some artificial pozzolanas (fly ash) that when mixed with lime, under hydrothermal conditions, also produced a new type of cementitious material. This was categorized as a new fly ash cement. The formation of a new hydrothermally treated wood-fiber-reinforced composite has also been demonstrated. It is apparent, however, that with respect to concerns about detailed knowledge of the reactivity of calcium silicate-based materials under hydrothermal conditions, the application of the technology far outweighs the understanding of the underlying principles of reactivity. It would seem that an understanding of reactions on the molecular level is just beginning, and that work on hydrothermal reactions is still a potentially lucrative area of research.

  11. Hydrothermal and tectonic activity in northern Yellowstone Lake, Wyoming

    USGS Publications Warehouse

    Johnson, S.Y.; Stephenson, W.J.; Morgan, L.A.; Shanks, Wayne C.; Pierce, K.L.

    2003-01-01

    Yellowstone National Park is the site of one of the world's largest calderas. The abundance of geothermal and tectonic activity in and around the caldera, including historic uplift and subsidence, makes it necessary to understand active geologic processes and their associated hazards. To that end, we here use an extensive grid of high-resolution seismic reflection profiles (???450 km) to document hydrothermal and tectonic features and deposits in northern Yellowstone Lake. Sublacustrine geothermal features in northern Yellowstone Lake include two of the largest known hydrothermal explosion craters, Mary Bay and Elliott's. Mary Bay explosion breccia is distributed uniformly around the crater, whereas Elliott's crater breccia has an asymmetric distribution and forms a distinctive, ???2-km-long, hummocky lobe on the lake floor. Hydrothermal vents and low-relief domes are abundant on the lake floor; their greatest abundance is in and near explosion craters and along linear fissures. Domed areas on the lake floor that are relatively unbreached (by vents) are considered the most likely sites of future large hydrothermal explosions. Four submerged shoreline terraces along the margins of northern Yellowstone Lake add to the Holocene record or postglacial lake-level fluctuations attributed to "heavy breathing" of the Yellowstone magma reservoir and associated geothermal system. The Lake Hotel fault cuts through northwestern Yellowstone Lake and represents part of a 25-km-long distributed extensional deformation zone. Three postglacial ruptures indicate a slip rate of ???0.27 to 0.34 mm/yr. The largest (3.0 m slip) and most recent event occurred in the past ???2100 yr. Although high heat flow in the crust limits the rupture area of this fault zone, future earthquakes of magnitude ???5.3 to 6.5 are possible. Earthquakes and hydrothermal explosions have probably triggered landslides, common features around the lake margins. Few high-resolution seismic reflection surveys have

  12. Hydrothermal Activity on ultraslow Spreading Ridge: new hydrothermal fields found on the Southwest Indian ridge

    NASA Astrophysics Data System (ADS)

    Tao, C.; Li, H.; Deng, X.; Lei, J.; Wang, Y.; Zhang, K.; Zhou, J.; Liu, W.

    2014-12-01

    Ultraslow spreading ridge makes up about 25% of global mid-ocean ridge length. Previous studies believed that hydrothermal activity is not widespread on the ultraslow spreading ridge owing to lower magma supply. Southwest Indian ridge (SWIR) with the spreading rate between 1.2cm/a to 1.4cm/a, represents the ultraslow spreading ridge. In 2007, Chinese Cruise (CC) 19th discovered the Dragon Flag deposit (DFD) on the SWIR, which is the first active hydrothermal field found on the ultraslow spreading ridge. In recent years, over 10 hydrothermal fields have been found on the SWIR between Indomed and Gallieni transform faults by the Chinese team. Tao et al. (2012) implied that the segment sections with excess heat from enhanced magmatism and suitable crustal permeability along slow and ultraslow ridges might be the most promising areas for searching for hydrothermal activities. In 2014, CC 30thdiscovered five hydrothermal fields and several hydrothermal anomalies on the SWIR. Dragon Horn Area (DHA). The DHA is located on the southern of segment 27 SWIR, with an area of about 400 km2. The geophysical studies indicated that the DHA belongs to the oceanic core complex (OCC), which is widespread on the slow spreading ridges (Zhao et al., 2013). The rocks, such as gabbro, serpentinized peridotite, and consolidated carbonate were collected in the DHA, which provide the direct evidence with the existence of the OCC. However, all rock samples gathered by three TV-grab stations are basalts on the top of the OCC. A hydrothermal anomaly area, centered at 49.66°E,37.80° S with a range of several kms, is detected in the DHA. It is probably comprised of several hydrothermal fields and controlled by a NW fault. New discovery of hydrothermal fields. From January to April 2014, five hydrothermal fields were discovered on the SWIR between 48°E to 50°E during the leg 2&3 of the CC 30th, which are the Su Causeway field (48.6°E, 38.1°S), Bai Causeway field (48.8°E, 37.9 °S), Dragon

  13. Magma to Microbe: Modeling Hydrothermal Processes at Ocean Spreading Centers

    NASA Astrophysics Data System (ADS)

    Lowell, Robert P.; Seewald, Jeffrey S.; Metaxas, Anna; Perfit, Michael R.

    Hydrothermal systems at oceanic spreading centers reflect the complex interactions among transport, cooling and crystallization of magma, fluid circulation in the crust, tectonic processes, water-rock interaction, and the utilization of hydrothermal fluids as a metabolic energy source by microbial and macro-biological ecosystems. The development of mathematical and numerical models that address these complex linkages is a fundamental part the RIDGE 2000 program that attempts to quantify and model the transfer of heat and chemicals from "mantle to microbes" at oceanic ridges. This volume presents the first "state of the art" picture of model development in this context. The most outstanding feature of this volume is its emphasis on mathematical and numerical modeling of a broad array of hydrothermal processes associated with oceanic spreading centers. By examining the state of model development in one volume, both cross-fertilization of ideas and integration across the disparate disciplines that study seafloor hydrothermal systems is facilitated. Students and scientists with an interest in oceanic spreading centers in general and more specifically in ridge hydrothermal processes will find this volume to be an up-to-date and indispensable resource.

  14. The Trans-Atlantic Geotraverse hydrothermal field: A hydrothermal system on an active detachment fault

    NASA Astrophysics Data System (ADS)

    Humphris, Susan E.; Tivey, Margaret K.; Tivey, Maurice A.

    2015-11-01

    Over the last ten years, geophysical studies have revealed that the Trans-Atlantic Geotraverse (TAG) hydrothermal field (26°08‧N on the Mid-Atlantic Ridge) is located on the hanging wall of an active detachment fault. This is particularly important in light of the recognition that detachment faulting accounts for crustal accretion/extension along a significant portion of the Mid-Atlantic Ridge, and that the majority of confirmed vent sites on this slow-spreading ridge are hosted on detachment faults. The TAG hydrothermal field is one of the largest sites of high-temperature hydrothermal activity and mineralization found to date on the seafloor, and is comprised of active and relict deposits in different stages of evolution. The episodic nature of hydrothermal activity over the last 140 ka provides strong evidence that the complex shape and geological structure of the active detachment fault system exerts first order, but poorly understood, influences on the hydrothermal circulation patterns, fluid chemistry, and mineral deposition. While hydrothermal circulation extracts heat from a deep source region, the location of the source region at TAG is unknown. Hydrothermal upflow is likely focused along the relatively permeable detachment fault interface at depth, and then the high temperature fluids leave the low-angle portion of the detachment fault and rise vertically through the highly fissured hanging wall to the seafloor. The presence of abundant anhydrite in the cone on the summit of the TAG active mound and in veins in the crust beneath provides evidence for a fluid circulation system that entrains significant amounts of seawater into the shallow parts of the mound and stockwork. Given the importance of detachment faulting for crustal extension at slow spreading ridges, the fundamental question that still needs to be addressed is: How do detachment fault systems, and the structure at depth associated with these systems (e.g., presence of plutons and/or high

  15. Geophysical Constraints On Enceladus' Hydrothermal Activity

    NASA Astrophysics Data System (ADS)

    Matson, D.; Castillo, J. C.; Johnson, T. V.; Lunine, J. I.; Davies, A. G.

    2011-12-01

    Cassini-Huygens discovered many eruptive plumes and a heat flow of about 15 GW [1] in the South Polar Region of Enceladus. The plume material is believed to come from an ocean [2]. We have modeled the heat and chemicals as coming to the surface via the circulation of relatively warm ocean water [3]. The major challenge for our work is to explain how circulation of water can be maintained in the very cold crust. The upper boundary condition is relatively simple. Where seawater contacts surface ice the temperature is ~-2 C. Also, under the right conditions, tidally induced fissures in the surface ice can fill with water that freezes, producing new ice. The lower boundary temperature is difficult to characterize precisely. The ocean is several degrees warmer than the ice. Consequently there will be some melting at the bottom of the crust. The melt water is less dense than seawater and floats on it. As a result, an ice-ocean interface layer is formed. This layer is stable against Rayleigh-Bénard convection. The layer regulates the rate at which heat is transferred and the temperature at which melt water is produced through temperature and salinity gradients. Currents in the ocean below and other variables influence the extent and shape of the interface layer. A somewhat similar interface layer (thermal gradient only) has been discussed and modeled for Europa [4] and many of those considerations apply to Enceladus. In the Europa case a layer thickness of ~200 m was suggested and that should be roughly what one might also expect for Enceladus. We demonstrate that it is feasible to keep this hydrothermal activity going over the long-term, as long as it is powered by a deep source of heat whose origin is still to be determined. This work was conducted at the Jet Propulsion Laboratory, California Institute of Technology, under contract with NASA. Copyright 2011 Caltech.

  16. Interactions Between Serpentinization, Hydrothermal Activity and Microbial Community at the Lost City Hydrothermal Field

    NASA Astrophysics Data System (ADS)

    Delacour, A.; Frueh-Green, G. L.; Bernasconi, S. M.; Schaeffer, P.; Frank, M.; Gutjahr, M.; Kelley, D. S.

    2008-12-01

    Seafloor investigations of slow- and ultraslow-spreading ridges have reported many occurrences of exposed mantle peridotites and gabbroic rocks on the ocean floor. Along the Mid-Atlantic Ridge, these uplifted portions of oceanic crust host high-temperature black smoker-type hydrothermal systems (e.g., Rainbow, Logatchev, Saldanha), and the more distinct low-temperature Lost City Hydrothermal Field (LCHF). Built on a southern terrace of the Atlantis Massif, the LCHF is composed of carbonate-brucite chimneys that vent alkaline and low-temperature (40-90°C) hydrothermal fluids. These fluids are related to serpentinization of mantle peridotites, which together with minor gabbroic intrusions form the basement of the LCHF. Long-lived hydrothermal activity at Lost City led to extensive seawater-rock interaction in the basement rocks, as indicated by seawater-like Sr- and mantle to unradiogenic Nd-isotope compositions of the serpentinites. These high fluid fluxes in the southern part of the massif influenced the conditions of serpentinization and have obliterated the early chemical signatures in the serpentinites, especially those of carbon and sulfur. Compared to reducing conditions commonly formed during the first stages of serpentinization, serpentinization at Lost City is characterized by relatively oxidizing conditions resulting in a predominance of magnetite, the mobilization/dissolution and oxidation of igneous sulfides to secondary pyrite, and the incorporation of seawater sulfate, all leading to high bulk-rock S-isotope compositions. The Lost City hydrothermal fluids contain high concentrations in methane, hydrogen, and low-molecular weight hydrocarbons considered as being produced abiotically. In contrast, organic compounds in the serpentinites are dominated by the occurrences of isoprenoids (pristane, phytane, and squalane), polycyclic compounds (hopanes and steranes), and higher abundances of C16 to C20 n-alkanes indicative of a marine organic input. We

  17. Hydrothermal carbonization of animal manures: Processes and energetics

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Hydrothermal carbonization (HTC) is an emerging technology for thermochemically converting biomass and waste materials into value-added carbonaceous char called hydrochar. HTC is well suited to manage wet feedstocks streams because pre-drying prior to processing is not required as with gasification...

  18. Fast preparation of Bi{sub 2}GeO{sub 5} nanoflakes via a microwave-hydrothermal process and enhanced photocatalytic activity after loading with Ag nanoparticles

    SciTech Connect

    Li, Zhao-Qian; Lin, Xin-Shan; Zhang, Lei; Chen, Xue-Tai; Xue, Zi-Ling

    2012-09-15

    Highlights: ► Bi{sub 2}GeO{sub 5} nanoflakes were successfully synthesized via a microwave-assisted solution-phase approach. ► Ag nanoparticles were deposited on the Bi{sub 2}GeO{sub 5} nanoflakes by a photoreduction procedure. ► Catalytic activity of the Ag/Bi{sub 2}GeO{sub 5} nanocomposite in the photo-degradation of rhodamine B (RhB) was much higher than that of pure Bi{sub 2}GeO{sub 5}. -- Abstract: In this work, a facile and rapid microwave-assisted hydrothermal route has been developed to prepare Bi{sub 2}GeO{sub 5} nanoflakes. Ag nanoparticles were subsequently deposited on the Bi{sub 2}GeO{sub 5} nanoflakes by a photoreduction procedure. The phases and morphologies of the products were characterized by powder X-ray diffraction (XRD), X-ray photoelectron spectrum (XPS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and UV–vis diffuse reflectance spectroscopy. Photocatalytic experiments indicate that such Ag/Bi{sub 2}GeO{sub 5} nanocomposite possesses higher photocatalytic activity for RhB degradation under UV light irradiation in comparison to pure Bi{sub 2}GeO{sub 5}. The amount of Ag in the nanocomposite affects the catalytic activity, and 3 wt% Ag showed the highest photodegradation efficiency. Moreover, the catalyst remains active after four consecutive tests. The present study provides a new strategy to design composite materials with enhanced photocatalytic activity.

  19. Remotely Triggered Seismicity in Volcanic and Hydrothermal Environments - Which Processes?

    NASA Astrophysics Data System (ADS)

    Hill, D. P.

    2001-12-01

    The abrupt increase in seismicity rates at sites throughout much of the western United States immediately following the 1992 M=7.4 Landers earthquake provided compelling evidence that large regional earthquakes can trigger local earthquake activity at sites many source dimensions removed from the mainshock epicenter. Remotely triggered seismicity has since been documented for a number of other large earthquakes including the 1999 M=7.1 Hector Mine earthquake. Well-documented instances of remotely triggered seismicity are largely confined to transtensional or extensional tectonic regimes with a large fraction of these closely associated with hydrothermal and/or young volcanic systems. In the case of Long Valley caldera in eastern California, which responded to both the Landers and Hector Mines earthquakes, the triggered seismicity appears to be secondary to a larger, aseismic deformation transient. Because this is the only remotely triggered site with continuous deformation monitoring, however, it remains unclear whether a deformation transient is fundamental component of the remote triggering process. Fluids, either aqueous or magmatic, play a central role in most models for the triggering process in hydrothermal and/or young magmatic systems. These models span a range of intriguing (and sometimes counter-intuitive) physical processes including pressure increases associated with advective overpressure and rectified diffusion in bubbly fluids, hydraulic surges resulting from rupturing of compartments of super-hydrostatic fluids in the brittle-plastic transition zone, hydraulic pumping of near-surface pore fluids by surface waves, disruption of fine sediment accumulations (dams) in confined aquifers, local stress changes in the brittle crust associated with relaxation or mobilization of a partially crystallized magma body. All appeal to the dynamic stresses from the mainshock triggering a non-linear response in a crustal volume that is in some sense in a near

  20. Influence of hydrothermal alteration on phreatic eruption processes in Solfatara (Campi Flegrei)

    NASA Astrophysics Data System (ADS)

    Mayer, K.; Scheu, B.; Montanaro, C.; Isaia, R.; Dingwell, D. B.

    2014-12-01

    The strong hydrothermal activity exhibited at Campi Flegrei by the Solfatara and Pisciarelli fumaroles points to a significant risk for phreatic eruptions in this densely populated area. Phreatic eruptions, triggered by various processes are hardly predictable in occurrence time and size. Despite their hazard potential, these eruptions, as well as the influence of hydrothermal alteration on their likelihood, magnitude and style, have so far been largely overlooked in experimental volcanology. The physical properties and the mechanical behavior of volcanic rocks are highly dependent on their original magmatic microstructure and on any eventual alteration of those microstructures due to hydrothermal reactions. We have therefore investigated the potential effects of hydrothermal alteration on rock microstructure and, as a consequence, on fragmentation dynamics. Rock samples from the vicinity of the Solfatara fumaroles have been characterized 1) geochemically (X-ray fluorescence, X-ray diffraction), 2) physically (density, porosity, permeability and elastic wave velocity) and 3) mechanically (uniaxial compressive strength, tensile strength). We have investigated the effects of hydrothermal alteration on fragmentation processes using a shock-tube apparatus, operating with Argon gas, water vapor and superheated water at temperatures up to 400°C and maximum pressures of 20 MPa. The three different energy sources within the pores initiating fragmentation, have been investigated: overpressure by 1) Argon gas; or 2) water vapor and due to 3) steam flashing of water. Fragmentation speed, fragmentation efficiency and fragmented particle ejection velocity were measured. Our results indicate, that steam flashing provides the highest energy - resulting in increased particle ejection velocity and higher fragmentation efficiency. Based on our results, we aim to constrain the influence of hydrothermal alteration on the dynamics of phreatic explosions and the effect on the amount of

  1. Hydrothermal Mineralization Along the Volcanically Active Mariana Arc

    NASA Astrophysics Data System (ADS)

    de Ronde, C. E.; Hein, J. R.; Embley, R. W.; Stern, R. J.

    2004-12-01

    In March and April, 2004, ROPOS ROV dives took place from the R/V T.G. Thompson along the volcanically active Mariana arc to ground truth CTD data collected a year earlier that indicated hydrothermal activity. Dives took place on seven volcanoes, six of which showed hydrothermal activity. We present data on samples collected from NW Rota-1 (14° , 36'N, 144° , 46'E), E. Diamante (15° , 56'N, 145° , 41'E), and NW Eifuku (21° , 29'N, 144° , 03'E), the three sites most studied. All the hydrothermal systems found are associated with volcano summits, or with resurgent domes inside a caldera. Brimstone vent at NW Rota-1 provided a dramatic display of thick, bellowing, yellow plumes that contained ash and molten sulfur. This site occurs at 500 m water depth and clearly shows closely associated magmatic-hydrothermal discharge. Sulfur was the dominant hydrothermal mineral deposited around the vent and occurs as spheres in the surrounding volcaniclastic sediment, fracture fill and veins, and massive deposits. The Black Forest vent field at E Diamante consists of a sulfide-sulfate chimney system developed at about 650 m water depth. This is the only mature system discovered and consists of numerous tall (up to 9 m) chimneys. The measured fluid temperature of 240° C produces boiling at the depth of the vents. The chimneys and mounds are composed of varying amounts of pyrite, sphalerite, chalcopyrite, barite, and anhydrite. Hydrothermal Mn oxides occur on the surface of inactive chimneys. This mineralogy contrasts with the other two systems, which deposit sulfur as the dominant hydrothermal product. The Cu-Zn-Fe-Ba mineralization is perhaps largely controlled by water/rock interaction. A unique hydrothermal field (Champagne field) was found at NW Eifuku where liquid CO2 is discharging from focused- and diffuse-flow vents at 1600 m water depth. The focused-flow vents consist of small chimneys and mounds up to a meter high that are composed of sulfur and yet to be

  2. Hydrothermal alkali metal catalyst recovery process

    DOEpatents

    Eakman, James M.; Clavenna, LeRoy R.

    1979-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles primarily in the form of water soluble alkali metal formates by treating the particles with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of added carbon monoxide. During the treating process the water insoluble alkali metal compounds comprising the insoluble alkali metal residues are converted into water soluble alkali metal formates. The resultant aqueous solution containing water soluble alkali metal formates is then separated from the treated particles and any insoluble materials formed during the treatment process, and recycled to the gasification process where the alkali metal formates serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. This process permits increased recovery of alkali metal constituents, thereby decreasing the overall cost of the gasification process by reducing the amount of makeup alkali metal compounds necessary.

  3. Hydrothermal reservoir beneath Taal Volcano (Philippines): Implications to volcanic activity

    NASA Astrophysics Data System (ADS)

    Nagao, T.; Alanis, P. B.; Yamaya, Y.; Takeuchi, A.; Bornas, M. V.; Cordon, J. M.; Puertollano, J.; Clarito, C. J.; Hashimoto, T.; Mogi, T.; Sasai, Y.

    2012-12-01

    Taal Volcano is one of the most active volcanoes in the Philippines. The first recorded eruption was in 1573. Since then it has erupted 33 times resulting in thousands of casualties and large damages to property. In 1995, it was declared as one of the 15 Decade Volcanoes. Beginning in the early 1990s it has experienced several phases of abnormal activity, including seismic swarms, episodes of ground deformation, ground fissuring and hydrothermal activities, which continues up to the present. However, it has been noted that past historical eruptions of Taal Volcano may be divided into 2 distinct cycles, depending on the location of the eruption center, either at Main Crater or at the flanks. Between 1572-1645, eruptions occurred at the Main Crater, in 1707 to 1731, they occurred at the flanks. In 1749, eruptions moved back to the Main Crater until 1911. During the 1965 and until the end of the 1977 eruptions, eruptive activity once again shifted to the flanks. As part of the PHIVOLCS-JICA-SATREPS Project magnetotelluric and audio-magnetotelluric surveys were conducted on Volcano Island in March 2011 and March 2012. Two-dimensional (2-D) inversion and 3-D forward modeling reveals a prominent and large zone of relatively high resistivity between 1 to 4 kilometers beneath the volcano almost directly beneath the Main Crater, surrounded by zones of relatively low resistivity. This anomalous zone of high resistivity is hypothesized to be a large hydrothermal reservoir filled with volcanic fluids. The presence of this large hydrothermal reservoir could be related to past activities of Taal Volcano. In particular we believe that the catastrophic explosion described during the 1911 eruption was the result of the hydrothermal reservoir collapsing. During the cycle of Main Crater eruptions, this hydrothermal reservoir is depleted, while during a cycle of flank eruptions this reservoir is replenished with hydrothermal fluids.

  4. The Sasquatch Hydrothermal Field: Linkages Between Seismic Activity, Hydrothermal Flow, and Geology

    NASA Astrophysics Data System (ADS)

    Glickson, D. A.; Kelley, D. S.; Delaney, J. R.

    2006-12-01

    The Sasquatch Hydrothermal Field is the most northern known vent field along the central Endeavour Segment of the Juan de Fuca Ridge, located 6 km north of the Main Endeavour Field (MEF) near 47° 59.8'N, 129° 4.0'W. It was discovered in 2000, after two large earthquake swarms in June 1999 and January 2000 caused increased venting temperatures in the MEF and significant changes in volatile composition along the entire axis [Johnson et al., 2000; Lilley et al., 2003; Proskurowski et al., 2004]. From 2004-2006, Sasquatch and the surrounding axial valley were comprehensively mapped with SM2000 multibeam sonar system and Imagenex scanning sonar at a resolution of 1-5 m. These data were combined with visual imagery from Alvin and ROV dives to define the eruptive, hydrothermal, and tectonic characteristics of the field and distal areas. Based on multibeam sonar results, bathymetric relief of the segment near Sasquatch is subdued. The broad axial valley is split by a central high that rises 30-40 m above the surrounding seafloor. Simple pattern analysis of the valley shows two fundamentally different regions, distinguished by low and high local variance. Areas of low variance correspond to a collapse/drainback landscape characterized by ropy sheet flow, basalt pillars, and bathtub rings capped by intact and drained lobate flows. Areas of high variance generally correspond to three types of ridge structures: 1) faulted basalt ridges composed of truncated pillow basalt, rare massive flows, and widespread pillow talus; 2) constructional basalt ridges composed of intact pillow flow fronts; and 3) extinct sulfide ridges covered by varying amounts of sulfide talus and oxidized hydrothermal sediment. Sasquatch is located in a depression among truncated pillow ridges, and is comprised of ~10, 1-6 m high, fragile sulfide chimneys that vent fluids up to 289°C. The active field extends only ~25 x 25 m, although a linear, N-S trending ridge of nearly continuous extinct sulfide

  5. Hydrothermal Activity and Volcanism on the Southern Mid-Atlantic Ridge

    NASA Astrophysics Data System (ADS)

    Haase, K. M.; Scientific Party, M.

    2005-12-01

    In April 2005 four recently discovered different hydrothermal fields on the slow-spreading Mid-Atlantic Ridge (MAR) south of the Equator were studied and sampled using a remotely operated vehicle (ROV) during cruise METEOR 64/1. Three of these hydrothermally active fields (called Turtle Pits, Red Lion, and Wideawake) occur at about 3000 m water depth in the centre of a MAR segment at 4° 48'S which appears to be volcanically very active. The youngest lava flow partly covers the low-temperature, diffuse flow Wideawake mussel field and is thus probably only a few years old. The high-temperature Turtle Pits hydrothermal field with four active vent structures lies some 300 m west of the diffuse vent field and is characterized by boiling fluids with temperatures close to 400° C. The mineral assemblage recovered from inactive hydrothermal mounds includes massive magnetite+hematite+sulfate and differs from that of the presently active vents and indicates more oxidizing conditions during the earlier activity. The vent fluids at Turtle Pits contain relatively high contents of hydrogen which may have formed during iron oxidation processes when basaltic magmas crystallized. The high fluid temperatures, the change to more reducing conditions, and the relatively high hydrogen contents in the fluids are most likely due to the ascent of magmas from the mantle that fed the very recent eruption. The high-temperature Red Lion hydrothermal field lies some 2 km north of the Turtle Pits field and consists of at least four active black smokers surrounded by several inactive sulfide mounds. The composition of the Red Lion fluids differs significantly from the Turtle Pits fluids, possibly owing largely to a difference in the temperature of the two systems. The fourth hydrothermally active field on the southern MAR, the Liliput field, was discovered near 9° 33'S in a water depth of 1500 m and consists of several low-temperature vents. A shallow hydrothermal plume in the water column

  6. Chemical reaction path modeling of hydrothermal processes on Mars: Preliminary results

    NASA Technical Reports Server (NTRS)

    Plumlee, Geoffrey S.; Ridley, W. Ian

    1992-01-01

    Hydrothermal processes are thought to have had significant roles in the development of surficial mineralogies and morphological features on Mars. For example, a significant proportion of the Martian soil could consist of the erosional products of hydrothermally altered impact melt sheets. In this model, impact-driven, vapor-dominated hydrothermal systems hydrothermally altered the surrounding rocks and transported volatiles such as S and Cl to the surface. Further support for impact-driven hydrothermal alteration on Mars was provided by studies of the Ries crater, Germany, where suevite deposits were extensively altered to montmorillonite clays by inferred low-temperature (100-130 C) hydrothermal fluids. It was also suggested that surface outflow from both impact-driven and volcano-driven hydrothermal systems could generate the valley networks, thereby eliminating the need for an early warm wet climate. We use computer-driven chemical reaction path calculation to model chemical processes which were likely associated with postulated Martian hydrothermal systems.

  7. Active and relict sea-floor hydrothermal mineralization at the TAG hydrothermal field, Mid-Atlantic Ridge

    SciTech Connect

    Rona, P.A. . Atlantic Oceanographic and Meteorological Labs.); Hannington, M.D. ); Raman, C.V. ); Thompson, G.; Tivey, M.K.; Humphris, S.E. ); Lalou, C. . Lab. CNRS-CEA); Petersen, S. Aachen Univ. of Technology )

    1993-12-01

    The TAG hydrothermal field is a site of major active and inactive volcanic-hosted hydrothermal mineralization in the rift valley of the slow-spreading Mid-Atlantic Ridge at 26[degree]N. The axial high is the principal locus of present magmatic intrusions. The TAG field contains three main areas of present and past hydrothermal activity: (1) an actively venting high-temperature sulfide mound; (2) two former high-temperature vent areas; (3) a zone of low-temperature venting and precipitation of Fe and Mn oxide deposits. The volcanic centers occur at the intersections between ridge axis-parallel normal faults and projected axis-transverse transfer faults. The intersections of these active fault systems may act as conduits both for magmatic intrusions from sources beneath the axial high that build the volcanic centers and for hydrothermal upwelling that taps the heat sources. Radiometric dating of sulfide samples and manganese crusts in the hydrothermal zones and dating of sediments intercalated with pillow lava flows in the volcanic center adjacent to the active sulfide mound indicate multiple episodes of hydrothermal activity throughout the field driven by heat supplied by episodic intrusions over a period of at least 140 [times] 10[sup 3] yr. The sulfide deposits are built by juxtaposition and superposition during relatively long residence times near episodic axial heat sources counterbalanced by mass wasting in the tectonically active rift valley of the slow-spreading oceanic ridge. Hydrothermal reworking of a relict hydrothermal zone by high-temperature hydrothermal episodes has recrystallized sulfides and concentrated the first visible primary gold reported in a deposit at an oceanic ridge.

  8. Hydrothermal activity at the Arctic mid-ocean ridges

    NASA Astrophysics Data System (ADS)

    Pedersen, Rolf B.; Thorseth, Ingunn H.; Nygård, Tor Eivind; Lilley, Marvin D.; Kelley, Deborah S.

    Over the last 10 years, hydrothermal activity has been shown to be abundant at the ultraslow spreading Arctic Mid-Ocean Ridges (AMOR). Approximately 20 active and extinct vent sites have been located either at the seafloor, as seawater anomalies, or by dredge sampling hydrothermal deposits. Decreasing spreading rates and decreasing influence of the Icelandic hot spot toward the north along the AMOR result in a north-south change from a shallow and magmatically robust to a deep and magmatically starved ridge system. This contrast gives rise to large variability in the ridge geology and in the nature of the associated hydrothermal systems. The known vent sites at the southern part of the ridge system are either low-temperature or white smoker fields. At the deep, northern parts of the ridge system, a large black smoker field has been located, and seawater anomalies and sulfide deposits suggest that black smoker-type venting is common. Several of these fields may be peridotite-hosted. The hydrothermal activity at parts of the AMOR exceeds by a factor of 2 to 3 what would be expected by extrapolating from observations on faster spreading ridges. Higher fracture/fault area relative to the magma volume extracted seems a likely explanation for this. Many of the vent fields at the AMOR are associated with axial volcanic ridges. Strong focusing of magma toward these ridges, deep rifting of the ridges, and subsequent formation of long-lived detachment faults that are rooted below the ridges may be the major geodynamic mechanisms causing the unexpectedly high hydrothermal activity.

  9. Hydrothermal Processing of Macroalgal Feedstocks in Continuous-Flow Reactors

    SciTech Connect

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Roesijadi, Guri; Zacher, Alan H.; Magnuson, Jon K.

    2014-02-03

    Wet macroalgal slurries have been converted into a biocrude by hydrothermal liquefaction (HTL) in a bench-scale continuous-flow reactor system. Carbon conversion to a gravity-separable oil product of 58.8% was accomplished at relatively low temperature (350 °C) in a pressurized (subcritical liquid water) environment (20 MPa) when using feedstock slurries with a 21.7% concentration of dry solids. As opposed to earlier work in batch reactors reported by others, direct oil recovery was achieved without the use of a solvent, and biomass trace mineral components were removed by processing steps so that they did not cause processing difficulties. In addition, catalytic hydrothermal gasification (CHG) was effectively applied for HTL byproduct water cleanup and fuel gas production from water-soluble organics. Conversion of 99.2% of the carbon left in the aqueous phase was demonstrated. Finally, as a result, high conversion of macroalgae to liquid and gas fuel products was found with low levels of residual organic contamination in byproduct water. Both process steps were accomplished in continuous-flow reactor systems such that design data for process scale-up was generated.

  10. Hydrothermal liquefaction of biomass: Developments from batch to continuous process

    SciTech Connect

    Elliott, Douglas C.; Biller, Patrick; Ross, Andrew; Schmidt, Andrew J.; Jones, Susanne B.

    2015-02-01

    This review describes the recent results in hydrothermal liquefaction (HTL) of biomass in continuous-flow processing systems. Although much has been published about batch reactor tests of biomass HTL, there is only limited information yet available on continuous-flow tests, which can provide a more reasonable basis for process design and scale-up for commercialization. High-moisture biomass feedstocks are the most likely to be used in HTL. These materials are described and results of their processing are discussed. Engineered systems for HTL are described however they are of limited size and do not yet approach a demonstration scale of operation. With the results available process models have been developed and mass and energy balances determined. From these models process costs have been calculated and provide some optimism as to the commercial likelihood of the technology.

  11. Hydrothermal liquefaction of biomass: developments from batch to continuous process.

    PubMed

    Elliott, Douglas C; Biller, Patrick; Ross, Andrew B; Schmidt, Andrew J; Jones, Susanne B

    2015-02-01

    This review describes the recent results in hydrothermal liquefaction (HTL) of biomass in continuous-flow processing systems. Although much has been published about batch reactor tests of biomass HTL, there is only limited information yet available on continuous-flow tests, which can provide a more reasonable basis for process design and scale-up for commercialization. High-moisture biomass feedstocks are the most likely to be used in HTL. These materials are described and results of their processing are discussed. Engineered systems for HTL are described; however, they are of limited size and do not yet approach a demonstration scale of operation. With the results available, process models have been developed, and mass and energy balances determined. From these models, process costs have been calculated and provide some optimism as to the commercial likelihood of the technology.

  12. Influence of process water quality on hydrothermal carbonization of cellulose.

    PubMed

    Lu, Xiaowei; Flora, Joseph R V; Berge, Nicole D

    2014-02-01

    Hydrothermal carbonization (HTC) is a thermal conversion process that has been shown to be environmentally and energetically advantageous for the conversion of wet feedstocks. Supplemental moisture, usually in the form of pure water, is added during carbonization to achieve feedstock submersion. To improve process sustainability, it is important to consider alternative supplemental moisture sources. Liquid waste streams may be ideal alternative liquid source candidates. Experiments were conducted to systematically evaluate how changes in pH, ionic strength, and organic carbon content of the initial process water influences cellulose carbonization. Results from the experiments conducted evaluating the influence of process water quality on carbonization indicate that changes in initial water quality do influence time-dependent carbonization product composition and yields. These results also suggest that using municipal and industrial wastewaters, with the exception of streams with high CaCl2 concentrations, may impart little influence on final carbonization products/yields.

  13. Serpentinization-assisted deformation processes and characterization of hydrothermal fluxes at mid-ocean ridges

    NASA Astrophysics Data System (ADS)

    Genc, Gence

    Seafloor hydrothermal systems play a significantly important role in Earth’s energy and geochemical budgets and support the existence and development of complex biological ecosystems by providing nutrient and energy to microbial and macrafaunal ecosystems through geochemical fluxes. Heat output and fluid flow are key parameters which characterize hydrothermal systems at oceanic spreading centers by constraining models of hydrothermal circulation. Although integrated measurements of heat flux in plumes are critically important as well, quantification of heat flux at discrete sources (vent orifices versus patches of seafloor shimmering diffuse flow) from direct measurements is particularly essential for examining the partitioning of heat flow into focused and diffuse components of venting and determining geochemical fluxes from these two modes of flow. Hydrothermal heat output also constrains the permeability of young oceanic crust and thickness of the conductive boundary layer that separates magmatic heat source from overlying hydrothermal circulation. This dissertation will be fundamentally focused on three main inter-connected topics: (1) the design and development of direct high- or low-temperature heat flow measuring devices for hydrothermal systems, (2) the collection of new heat output results on four cruises between 2008 and 2010 at several distinct hydrothermal sites along mid-ocean ridges (MORs) to estimate total heat output from individual vent structures such as Dante, Hulk or the whole vent field (e.g., Main Endeavour Vent Field (MEF)), the partitioning between focused and diffuse hydrothermal venting in MEF, and determination of initial estimates of geochemical flux from diffuse hydrothermal fluids which may be influenced by the activity in subsurface biosphere and finally (3) the deformation and uplift associated with serpentinization at MORs and subduction zones. Despite extensive efforts spent for the last couple of decades on heat flow measurement

  14. Hydrothermal regimes of the dry active layer

    NASA Astrophysics Data System (ADS)

    Ishikawa, Mamoru; Zhang, Yinsheng; Kadota, Tsutomu; Ohata, Tetsuo

    2006-04-01

    Evaporation and condensation in the soil column clearly influence year-round nonconductive heat transfer dynamics in the dry active layer underlying semiarid permafrost regions. We deduced this from heat flux components quantified using state-of-the-art micrometeorological data sets obtained in dry and moist summers and in winters with various snow cover depths. Vapor moves easily through large pores, some of which connect to the atmosphere, allowing (1) considerable active layer warming driven by pipe-like snowmelt infiltration, and (2) direct vapor linkage between atmosphere and deeper soils. Because of strong adhesive forces, water in the dry active layer evaporates with great difficulty. The fraction of latent heat to total soil heat storage ranged from 26 to 45% in dry and moist summers, respectively. These values are not negligible, despite being smaller than those of arctic wet active layer, in which only freezing and thawing were considered.

  15. Refractory Organic Compounds in Enceladus' Ice Grains and Hydrothermal Activity

    NASA Astrophysics Data System (ADS)

    Postberg, F.; Khawaja, N.; Hsu, H. W.; Sekine, Y.; Shibuya, T.

    2015-12-01

    Cassini's Cosmic Dust Analyzer (CDA) generates time-of-flight mass spectra of individual grains impinging on the instruments target-plate. Following the analysis of salt rich ice grains emitted by Enceladus that indicated a salt-water ocean in contact with the moon's rocky core [1,2] a recent CDA analysis of nano-phase silica particles pointed at hydrothermal activity at the moon's rock/water interface [3]. The results imply temperatures above 80 - 90°C and alkaline pH values around 10 reminiscent of alkaline hydrothermal vents on Earth like the Lost City Hydrothermal Field. In this context the compositional analysis of organic components in CDA mass spectra of the ejected ice grains is of particular relevance. A multitude of volatile organic species has already been identified in the gas component of the plume [4]. As expected, we find more complex organic molecules in ice grains than in the gas indicating aromatic species, amines, and carbonyl group species. The composition of organic-bearing ice grains displays a great diversity indicating a variety of different organic species in varying concentrations. Recent spatially resolved CDA in situ measurements inside Enceladus' plume indicate that these organic compounds are especially frequent in 'young' ice grains that have just been ejected by high velocity jets. We investigate the implications of our findings with respect to ice grain formation at the water surface and inside the icy vents. We constrain the generation of organic compounds at the rock/water interface in the light of hydrothermal activity and the potential for the formation of life precursor molecules in Enceladus' ocean. Ref:[1] Postberg et al., Nature 459, 1098-1101 (2009). [2] Postberg et al., Nature 474, 620-622 (2011). [3]. Hsu, Postberg, Sekine et al., Nature, 519, 207-210 (2015). [4] Waite et al., Nature 460, 487-490 (2009).

  16. Processing of Microalgae: Acoustic Cavitation and Hydrothermal Conversion

    NASA Astrophysics Data System (ADS)

    Greenly, Justin Michael

    The production of energy dense fuels from renewable algal biomass feedstocks -- if sustainably developed at a sufficiently large scale -- may reduce the consumption of petroleum from fossil fuels and provide many environmental benefits. Achieving economic feasibility has several technical engineering challenges that arise from dilute concentration of growing algae in aqueous media, small cell sizes, and durable cell walls. For microalgae to be a sustainable source of biofuels and co-products, efficient fractionation and conversion of the cellular contents is necessary. Research was carried out to address two processing options for efficient microalgae biofuel production: 1. Ultrasonic cavitation for cell disruption and 2. Hydrothermal conversion of a model algal triglyceride. 1. Ultrasonic cell disruption, which relies on cavitating bubbles in the suspension to produce damaging shock waves, was investigated experimentally over a range of concentrations and species types. A few seconds of high intensity sonication at fixed frequency yielded significant cell disruption, even for the more durable cells. At longer exposure times, effectiveness was seen to decline and was attributed, using acoustic measurements, to ultrasonic power attenuation in the ensuing cloud of cavitating bubbles. Processing at higher cell concentrations slowed cell disintegration marginally, but increased the effectiveness of dissipating ultrasonic energy. A theoretical study effectively predicted optimal conditions for a variety of parameters that were inaccessible in this experimental investigation. In that study, single bubble collapse was modeled to identify operating conditions that would increase cavitation, and thus cell disruption. Simulations were conducted by varying frequency and pressure amplitude of the ultrasound wave, and initial bubble size. The simulation results indicated that low frequency, high sound wave amplitudes, and small initial bubble size generate the highest shock

  17. An authoritative global database for active submarine hydrothermal vent fields

    NASA Astrophysics Data System (ADS)

    Beaulieu, Stace E.; Baker, Edward T.; German, Christopher R.; Maffei, Andrew

    2013-11-01

    The InterRidge Vents Database is available online as the authoritative reference for locations of active submarine hydrothermal vent fields. Here we describe the revision of the database to an open source content management system and conduct a meta-analysis of the global distribution of known active vent fields. The number of known active vent fields has almost doubled in the past decade (521 as of year 2009), with about half visually confirmed and others inferred active from physical and chemical clues. Although previously known mainly from mid-ocean ridges (MORs), active vent fields at MORs now comprise only half of the total known, with about a quarter each now known at volcanic arcs and back-arc spreading centers. Discoveries in arc and back-arc settings resulted in an increase in known vent fields within exclusive economic zones, consequently reducing the proportion known in high seas to one third. The increase in known vent fields reflects a number of factors, including increased national and commercial interests in seafloor hydrothermal deposits as mineral resources. The purpose of the database now extends beyond academic research and education and into marine policy and management, with at least 18% of known vent fields in areas granted or pending applications for mineral prospecting and 8% in marine protected areas.

  18. Post-drilling hydrothermal vent and associated biological activities seen through artificial hydrothermal vents in the Iheya North field, Okinawa Trough

    NASA Astrophysics Data System (ADS)

    Takai, K.; Kawagucci, S.; Miyazaki, J.; Watsuji, T.; Ishibashi, J.; Yamamoto, H.; Nozaki, T.; Kashiwabara, T.; Shibuya, T.

    2012-12-01

    In 2010, IODP Expedition 331 was conducted in the Iheya North Field, the Okinawa Trough and drilled several sites in hydrothermally active subseafloor. In addition, during the IODP Expedition 331, four new hydrothermal vents were created. These post-drilling artificial hydrothermal vents provide excellent opportunities to investigate the physical, chemical and microbiological characteristics of the previously unexplored subseafloor hydrothermal fluid reservoirs, and to monitor and estimate how the anthropogenic drilling behaviors affect the deep-sea hydrothermal vent ecosystem. We were very much interested in the difference of hydrothermal fluid chemistry between the natural hydrothermal vents and the artificial hydrothermal vents. The IODP porewater chemistry of the cores pointed to the density-driven stratification of the phase-separated hydrothermal fluids and the natural vent fluids were likely derived only from the shallower vapor-enriched phases. However, the artificial hydrothermal vents had deeper fluid sources in the subseafloor hydrothermal fluid reservoirs composed of vapor-lost (Cl-enriched) phases. The fluids from the artificial hydrothermal vents were sampled by ROV at 5, 12 and 18 months after the IODP expedition. The artificial hydrothermal vent fluids were slightly enriched with Cl as compared to the natural hydrothermal vent fluids. Thus, the artificial hydrothermal vents successfully entrained the previously unexplored subseafloor hydrothermal fluids. The newly created hydrothermal vents also hosted the very quickly grown, enormous chimney structures, of which mineral compositions were highly variable among the vents. However, the quickly grown C0016B and C0016D vent chimneys were found to be typical Kuroko ore even though the chimney growth rates in the artificial vents were extremely faster than those in the natural vents. In addition, the IODP drilling operation not only created new hydrothermal vents by deep drilling but also induced the

  19. Tuning photoluminescence of organic rubrene nanoparticles through a hydrothermal process

    PubMed Central

    2011-01-01

    Light-emitting 5,6,11,12-tetraphenylnaphthacene (rubrene) nanoparticles (NPs) prepared by a reprecipitation method were treated hydrothermally. The diameters of hydrothermally treated rubrene NPs were changed from 100 nm to 2 μm, depending on hydrothermal temperature. Photoluminescence (PL) characteristics of rubrene NPs varied with hydrothermal temperatures. Luminescence of pristine rubrene NPs was yellow-orange, and it changed to blue as the hydrothermal temperature increased to 180°C. The light-emitting color distribution of the NPs was confirmed using confocal laser spectrum microscope. As the hydrothermal temperature increased from 110°C to 160°C, the blue light emission at 464 to approximately 516 nm from filtered-down NPs was enhanced by H-type aggregation. Filtered-up rubrene NPs treated at 170°C and 180°C exhibited blue luminescence due to the decrease of intermolecular excimer densities with the rapid increase in size. Variations in PL of hydrothermally treated rubrene NPs resulted from different size distributions of the NPs. PMID:21711925

  20. The study of active submarine volcanoes and hydrothermal vents in the Southernmost Part of Okinawa Trough

    NASA Astrophysics Data System (ADS)

    Lee, Y.; Tsai, C.; Lee, C.

    2004-12-01

    The study area is located in the Southernmost Part of Okinawa Trough (SPOT), which is a back-arc basin formed by extension of Eurasian plate. Previous research indicated two extensional stages in SPOT area. Many normal-fault structures were come into existence during both extensional processes. The SPOT is presently in an activity tectonic episode. Therefore, the area becomes a frequent earthquake and abundant magmatism. The purpose of this study is to discuss which relationship between tectonics, submarine volcanoes and hydrothermal vents in SPOT area. The investigations are continued from 1998 to 2004, we have found at least twelve active hydrothermal vents in study area. Compare the locations hydrothermal vents with fault systems, we find both of them have highly correlated. We can distinguish them into two shapes, pyramidal shape and non-pyramidal shape. According to plumes height, we are able to divide these vents into two groups near east longitude 122.5° . East of this longitude, the hydrothermal plumes are more powerful and west of it are the weaker. This is closely related to the present extensional axis (N80° E) of the southern part of the Okinawa Trough. This can be explained the reason of why the more powerful vents coming out of the east group. The east group is associated with the present back-arc spreading system. West of 122.5° , the spreading system are in a primary stage. The andesitic volcanic island, the Turtle Island, is a result of N60° E extensional tectonism with a lot of faults. Besides the pyramidal shape, this can be proved indirectly. The vents located in the west side were occurred from previous extensional faults and are weaker than the eastern. Therefore, we suggest that if last the extension keeps going on, the hydrothermal vents located at the west side of the longitude 122.5° will be intensified.

  1. Subaerial and sublacustrine hydrothermal activity at Lake Rotomahana

    NASA Astrophysics Data System (ADS)

    Stucker, Valerie K.; de Ronde, Cornel E. J.; Scott, Bradley J.; Wilson, Nathaniel J.; Walker, Sharon L.; Lupton, John E.

    2016-03-01

    Lake Rotomahana is a crater lake in the Okataina Volcanic Centre (New Zealand) that was significantly modified by the 1886 Tarawera Rift eruption. The lake is host to numerous sublacustrine hydrothermal vents. Water column studies were conducted in 2011 and 2014 along with sampling of lake shore hot springs and crater lakes in Waimangu Valley to complement magnetic, seismic, bathymetric and heat flux surveys. Helium concentrations below 50 m depth are higher in 2014 compared to 2011 and represent some of the highest concentrations measured, at 6 × 10- 7 ccSTP/g, with an end-member 3He/4He value of 7.1 RA. The high concentrations of helium, when coupled with pH anomalies due to high dissolved CO2 content, suggest the dominant chemical input to the lake is derived from magmatic degassing of an underlying magma. The lake shore hot spring waters show differences in source temperatures using a Na-K geothermometer, with inferred reservoir temperatures ranging between 197 and 232 °C. Water δ18O and δD values show isotopic enrichment due to evaporation of a steam heated pool with samples from nearby Waimangu Valley having the greatest enrichment. Results from this study confirm both pre-1886 eruption hydrothermal sites and newly created post-eruption sites are both still active.

  2. Destruction of nitrates, organics, and ferrocyanides by hydrothermal processing

    SciTech Connect

    Robinson, J.M.; Foy, B.R.; Dell`Orco, P.C.; Anderson, G.; Archuleta, F.; Atencio, J.; Breshears, D.; Brewer, R.; Eaton, H.; McFarland, R.; McInroy, R.; Reynolds, T.; Sedillo, M.; Wilmanns, E.; Buelow, S.J.

    1993-03-01

    This work targets the remediation of the aqueous mixed wastes stored in the underground tanks at the Department of Energy site in Hanford, Washington via hydrothermal processing. The feasibility of destroying the nitrate, organic, and ferrocyanide components of the wastes under supercritical and near critical conditions (623 {degree}K to 873{degree}K, 22.1 MPa to 103.4 MPa) is addressed. A novel method was developed for determining the solubility of nitrate salts in supercritical water solutions at pressures ranging from 24.8 MPa to 30.3 MPa (3600 psi to 4400 psi) and temperatures from 723 {degree}K to 798 {degree}K. Sodium nitrate solubilities ranged from 293 mg/kg at 24.8 MPa and 798 {degree}K to 1963 mg/kg at 30.3 MPa and 723{degree}K. Solubility was found to vary directly with pressure, and inversely with temperature. An empirical relationship was developed for the estimation of sodium nitrate solubility at water densities between 0.08 and 0.16 kg/L and temperatures between 723{degree}K and 798{degree}K. A small volume batch reactor equipped with optical diagnostics was used to monitor the phase behavior of a diluted variant of a tank 101-SY simulant. Preliminary results suggest that a single phase is formed at 83 MPa at 773 {degree}K.

  3. Destruction of nitrates, organics, and ferrocyanides by hydrothermal processing

    SciTech Connect

    Robinson, J.M.; Foy, B.R.; Dell'Orco, P.C.; Anderson, G.; Archuleta, F.; Atencio, J.; Breshears, D.; Brewer, R.; Eaton, H.; McFarland, R.; McInroy, R.; Reynolds, T.; Sedillo, M.; Wilmanns, E.; Buelow, S.J.

    1993-01-01

    This work targets the remediation of the aqueous mixed wastes stored in the underground tanks at the Department of Energy site in Hanford, Washington via hydrothermal processing. The feasibility of destroying the nitrate, organic, and ferrocyanide components of the wastes under supercritical and near critical conditions (623 [degree]K to 873[degree]K, 22.1 MPa to 103.4 MPa) is addressed. A novel method was developed for determining the solubility of nitrate salts in supercritical water solutions at pressures ranging from 24.8 MPa to 30.3 MPa (3600 psi to 4400 psi) and temperatures from 723 [degree]K to 798 [degree]K. Sodium nitrate solubilities ranged from 293 mg/kg at 24.8 MPa and 798 [degree]K to 1963 mg/kg at 30.3 MPa and 723[degree]K. Solubility was found to vary directly with pressure, and inversely with temperature. An empirical relationship was developed for the estimation of sodium nitrate solubility at water densities between 0.08 and 0.16 kg/L and temperatures between 723[degree]K and 798[degree]K. A small volume batch reactor equipped with optical diagnostics was used to monitor the phase behavior of a diluted variant of a tank 101-SY simulant. Preliminary results suggest that a single phase is formed at 83 MPa at 773 [degree]K.

  4. Seafloor Hydrothermal Activity in the Southern Gulf of California

    NASA Astrophysics Data System (ADS)

    Paduan, J. B.; Clague, D. A.; Caress, D. W.; Lundsten, L.; Zierenberg, R. A.; Troni, G.; Wheat, C. G.; Spelz, R. M.

    2015-12-01

    Active hydrothermal venting was previously unknown between Guaymas Basin and 21°N on the East Pacific Rise. MBARI AUV surveys and ROV dives in 2012 and 2015 discovered 7 hydrothermal vent sites with diverse and varied vent communities within that gap. One field in the Pescadero Basin vents clear shimmering fluids at 3685 m depth and four vigorous black smoker fields and several extinct chimney fields are between 2225 and 2400 m depth on the Alarcón Rise. Low-temperature vent sites are present on both of the Pescadero and Tamayo Transforms. The chimneys were discovered in 1-m resolution AUV bathymetric data, with some indicated to be active based on temperature anomalies in the AUV CTD data and confirmed during later ROV dives. The low-temperature vent sites on the transform faults were found on ROV dives while exploring young lava flows and sediment hills uplifted by sill intrusions. Pescadero Basin is a deep extensional basin in the southern Gulf. The smooth, subtly faulted floor is filled with at least 150 m of sediment, as determined from sub-bottom profiles collected by the AUV. Three large chimneys (named Auka by our Mexican collaborators) and several broad mounds are located on the SW margin of the basin. Temperatures to 290°C were measured, the fluids are clear, neutral pH, and contain elevated Na. The chimneys are delicate, white, predominantly Ca-carbonate; barite, sparse sulfides, and some aromatic hydrocarbons are also present. Three active vent fields (Ja Sít, Pericú, and Meyibó) at Alarcón Rise are located near the eruptive fissure of an extensive young sheet flow. The fourth field (Tzab-ek) is 1.1 km NW of the axis on older pillow lavas. The largest chimneys are in the Tzab-ek field: 31 and 33 m tall, with flanges and upside-down waterfalls. They rise from a sulfide mound, suggesting a long-lived hydrothermal system, in contrast to the near-axis fields where the chimneys grow directly on basalt. The Alarcón chimneys are Zn and Cu-rich sulfides

  5. Seafloor Hydrothermal Activity at the Galapagos Triple Junction, East Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Li, H.; Yu, Z.; Zhang, G.; Tao, C.; Chen, S.

    2014-12-01

    Since the first discovery of black smokers on the Gaplapgaos spreading center, over 500 hydrothermal sites have been confirmed on the mid-ocean ridge, arc and back-arc settings (Beaulieu et al., 2013). However, the hydrothermal activity at triple-junction has not received much attention. Consequently, there are outstanding questions regarding the features of the hydrothermal system, and the effect of the hydrothermal circulation on the tectonic activity of the triple-junction. In 2009, the Chinese Dayang Cruise 21 discovered the Precious Stone field (PSF) on the Dietz Semount at the southern flank of the Galapagos triple junction (GTJ). Most studies of the GTJ focus on the topographictectonic and stresssimulation, which suggest that the GTJ had complex evoluation(Smith et al., 2011, 2013; Mitchell et al., 2011,Schouten et al., 2012). Water anomay were clear detected and samples of hydrothermal deposit and rocks were collected by TV-Grab (Figure.1). This study aims to understand the geological features of the PSF related hydrothermal activity. Hydrothermal mineralization Three types of sedimentary hydrothermal deposits representing three different hydrothermal activity stages (Figure 1)are confirmed in the PSF: 1) sediments with native sulfur and pyrite clasts(Type I), 2) Fe—Mn oxides (Type II), and 3) clay minerals mainlynontronite(Type III). Type II sedimentsprecipitate early and the source comprises of clasts of distal hydrothermal plume. The nontronite-rich sediments propably derive from the low-temperature alteration of Fe—Mn oxides. Type 1 sediments are found on the active hydrothermal venting field. Hydrothermal plume Water anomaly were detected at the southewestern PSF. We observed widespreadsedimentary hydrothermal depositsin the western PSF, but no water anomaly. According to the results of five water anomaly dectection lines, we predicted the existence of three hydrothermal vents in the PSF. Seafloor type inversion Multi-beam backscatter data were

  6. Searching for evidence of hydrothermal activity at Apollinaris Mons, Mars

    USGS Publications Warehouse

    El Maarry, M.R.; Dohm, J.M.; Marzo, G.A.; Fergason, R.; Goetz, W.; Heggy, E.; Pack, A.; Markiewicz, W.J.

    2012-01-01

    A multidisciplinary approach involving various remote sensing instruments is used to investigate Apollinaris Mons, a prominent volcano on Mars, as well as the surrounding plains for signs of prolonged hydrologic and volcanic, and possibly hydrothermal activity. The main findings include (1) evidence from laser altimetry indicating the large thickness (1.5-2. km at some locations) of the fan deposits draping the southern flank contrary to previous estimates, coupled with possible layering which point to a significant emplacement phase at Apollinaris Mons, (2) corroboration of Robinson et al. (Robinson, M.S., Mouginis-Mark, P.J., Zimbelman, J.R., Wu, S.S.C., Ablin, K.K., Howington-Kraus, A.E. [1993]. Icarus 104, 301-323) hypothesis regarding the formation of incised valleys on the western flanks by density current erosion which would indicate magma-water interaction or, alternatively, volatile-rich magmas early in the volcano's history, (3) mounds of diverse geometric shapes, many of which display summit depressions and occur among faults and fractures, possibly marking venting, (4) strong indicators on the flanks of the volcano for lahar events, and possibly, a caldera lake, (5) ubiquitous presence of impact craters displaying fluidized ejecta in both shield-forming (flank and caldera) materials and materials that surround the volcano that are indicative of water-rich target materials at the time of impact, (6) long-term complex association in time among shield-forming materials and Medusae Fossae Formation.The findings point to a site of extensive volcanic and hydrologic activity with possibly a period of magma-water interaction and hydrothermal activity. Finally, we propose that the mound structures around Apollinaris should be prime targets for further in situ exploration and search for possible exobiological signatures. ?? 2011 Elsevier Inc..

  7. Searching for evidence of hydrothermal activity at Apollinaris Mons, Mars

    USGS Publications Warehouse

    El Maarry, M. Ramy; Dohm, James M.; Marzo, Giuseppe A.; Fergason, Robin; Goetz, Walter; Heggy, Essam; Pack, Andreas; Markiewicz, Wojciech J.

    2012-01-01

    A multidisciplinary approach involving various remote sensing instruments is used to investigate Apollinaris Mons, a prominent volcano on Mars, as well as the surrounding plains for signs of prolonged hydrologic and volcanic, and possibly hydrothermal activity. The main findings include (1) evidence from laser altimetry indicating the large thickness (1.5–2 km at some locations) of the fan deposits draping the southern flank contrary to previous estimates, coupled with possible layering which point to a significant emplacement phase at Apollinaris Mons, (2) corroboration of Robinson et al. (Robinson, M.S., Mouginis-Mark, P.J., Zimbelman, J.R., Wu, S.S.C., Ablin, K.K., Howington-Kraus, A.E. [1993]. Icarus 104, 301–323) hypothesis regarding the formation of incised valleys on the western flanks by density current erosion which would indicate magma–water interaction or, alternatively, volatile-rich magmas early in the volcano’s history, (3) mounds of diverse geometric shapes, many of which display summit depressions and occur among faults and fractures, possibly marking venting, (4) strong indicators on the flanks of the volcano for lahar events, and possibly, a caldera lake, (5) ubiquitous presence of impact craters displaying fluidized ejecta in both shield-forming (flank and caldera) materials and materials that surround the volcano that are indicative of water-rich target materials at the time of impact, (6) long-term complex association in time among shield-forming materials and Medusae Fossae Formation. The findings point to a site of extensive volcanic and hydrologic activity with possibly a period of magma–water interaction and hydrothermal activity. Finally, we propose that the mound structures around Apollinaris should be prime targets for further in situ exploration and search for possible exobiological signatures.

  8. Silica nanoparticles in E ring ice grains as an indicator for hydrothermal activities at Enceladus

    NASA Astrophysics Data System (ADS)

    Postberg, F.; Hsu, H. W.; Sekine, Y.

    2013-09-01

    Since 2004 the Cosmic Dust Analyser (CDA) on board the Cassini spacecraft detects nano-meter sized dust particles, so called stream particles, in the Saturnian system. Recently it has been shown that they are released from E ring ice grains in which they were previously embedded [1]. As a consequence the nanograins must have been generated at Saturns active moon Enceladus which feeds the E ring by its spectacular jets of vapour and ice grains. Liquid water below the moons icy crust is known to be the dominant source of these jets [2, 3]. New results from CDA presented here indicate that stream particles actually are nano-silica grains. The most prominent geological process which produces nano-phase silica are hydrothermal rock-water interactions. This process has recently been intensely studied for hydrothermal systems on Earth [e.g. 4, 5]. The measured concentration, composition and size range observed at in the Saturnian system precisely matches a hydrothermal synthesis origin. Thus, we propose nano-colloidal silica to be present at mMol concentrations in Enceladus' subsurface waters. We were able to reproduce the proposed hydrothermal serpentinisation processes in a geochemical long term experiment in the laboratory. As there are no alternative formation scenarios which are in agreement with the CDA observations our results indicate ongoing rock-water interactions inside Enceladus at temperatures clearly exceeding 100°C. We discuss implications for Enceladus geochemistry, like salinity, possible ranges of temperature and pH, as well as the mineral composition of the Enceladian rock core.

  9. Chemical properties and hydrothermal processes on the first two directly sampled deep-sea eruptions (Invited)

    NASA Astrophysics Data System (ADS)

    Butterfield, D. A.; Resing, J. A.; Roe, K. K.; Christensen, M.; Embley, R. W.; Lupton, J. E.; Chadwick, W.

    2009-12-01

    To understand the effects of deep-sea volcanic eruptions on oceanic chemistry, on the ecology of hydrothermal vent communities, on microbial communities in the sub-seafloor biosphere, and on the alteration of oceanic lithosphere requires direct observation and sampling of active eruption sites. Known mid-ocean ridge eruptions have so far been too brief to observe and sample, but a nearly continuous eruption at NW Rota-1 submarine volcano in the Mariana arc (2004-2009) and a potentially long-term eruption at West Mata volcano in the NE Lau Basin (detected Nov. 2008) have provided unprecedented access to magma degassing and rapid water-rock reaction processes that may typify active submarine arc volcanism. How closely this resembles the hydrothermal processes associated with mid-ocean ridge volcanism remains to be seen. NW Rota-1 has a significantly higher output of a free gas phase, but based on initial observations of fluid chemistry and venting types, NW Rota-1 and W Mata have much in common. Active hydrothermal venting was found within a depth horizon encompassing the top 100 meters of the summit peak on both volcanoes (520 m at Rota; 1200 m at Mata). The dominant particulate and chemical plumes originate at active volcanic vents. The hydrothermal chemistry of these volcanic vents is dominated by the condensation of magmatic sulfur dioxide gas, its dissolution into seawater, and subsequent acid attack on volcanic rock. Disproportionation of SO2 to elemental sulfur, H2S, and sulfuric acid occurs. Percolation of hot, acidic fluids through volcaniclastic deposits results in rapid uptake of iron, aluminum, and other metals into solution. Chemical compositions and models indicate that continued water/rock reaction, cooling, and sub-surface mixing with seawater result in rising pH and precipitation of sulfur, alunite, anhydrite, iron sulfides, and iron oxyhydroxides (in order of increasing pH and decreasing temperature). Venting fluids sampled directly out of the

  10. A fluorescein tracer release experiment in the hydrothermally active crater of Vailulu'u volcano, Samoa

    NASA Astrophysics Data System (ADS)

    Hart, S. R.; Staudigel, H.; Workman, R.; Koppers, A. A. P.; Girard, A. P.

    2003-08-01

    On 3 April 2001, a 20 kg point source of fluorescein dye was released 30 m above the bottom of the active summit caldera of Vailulu'u submarine volcano, Samoa. Vailulu'u crater is 2000 m wide and at water depths of 600-1000 m, with the bottom 200 m completely enclosed; it thus provides an ideal site to study the hydrodynamics of an active hydrothermal system. The magmatically driven hydrothermal system in the crater is currently exporting massive amounts of particulates, manganese, and helium. The dispersal of the dye was tracked for 4 days with a fluorimeter in tow-yo mode from the U.S. Coast Guard icebreaker Polar Sea. Lateral dispersion of the dye ranged from 80 to 500 m d-1; vertical dispersion had two components: a diapycnal diffusivity component averaging 21 cm2 s-1, and an advective component averaging 0.025 cm s-1. These measurements constrain the mass export of water from the crater during this period to be 8-1.3+4.6 × 107 m3 d-1, which leads to a "turnover" time for water in the crater of ˜3.2 days. Coupled with temperature data from CTD profiles and Mn analyses of water samples, the power output from the crater is 610-100+350 MW, and the manganese export flux is ˜240 kg d-1. The Mn/Heat ratio of 4.7 ng J-1 is significantly lower than ratios characteristic of hot smokers and diffuse hydrothermal flows on mid-ocean ridges and points to phase separation processes in this relatively shallow hydrothermal system.

  11. IODP Expedition 331: Strong and Expansive Subseafloor Hydrothermal Activities in the Okinawa Trough

    NASA Astrophysics Data System (ADS)

    Takai, K.; Mottl, M. J.; Nielsen, S. H. H.; IODP Expedition 331 Scientists, the

    2012-04-01

    Integrated Ocean Drilling Program (IODP) Expedition 331 drilled into the Iheya North hydrothermal system in the middle Okinawa Trough in order to investigate active subseafloor microbial ecosystems and their physical and chemical settings. We drilled five sites during Expedition 331 using special guide bases at three holes for reentry, casing, and capping, including installation of a steel mesh platform with valve controls for postcruise sampling of fluids. At Site C0016, drilling at the base of the North Big Chimney (NBC) mound yielded low recovery, but core included the first Kuroko-type black ore ever recovered from the modern subseafloor. The other four sites yielded interbedded hemipelagic and strongly pumiceous volcaniclastic sediment, along with volcanogenic breccias that are variably hydrothermally altered and mineralized. At most sites, analyses of interstitial water and headspace gas yielded complex patterns with depth and lateral distance of only a few meters. Documented processes included formation of brines and vapor-rich fluids by phase separation and segregation, uptake of Mg and Na by alteration minerals in exchange for Ca, leaching of K at high temperature and uptake at low temperature, anhydrite precipitation, potential microbial oxidation of organic matter and anaerobic oxidation of methane utilizing sulfate, and methanogenesis. Shipboard analyses have found evidence for microbial activity in sediments within the upper 10-30 m below seafloor (mbsf) where temperatures were relatively low, but little evidence in the deeper hydrothermally altered zones and hydrothermal fluid regime. doi:10.2204/iodp.sd.13.03.2011

  12. Hydrothermal synthesis and photocatalytic activity of zinc oxide hollow spheres.

    PubMed

    Yu, Jiaguo; Yu, Xiaoxiao

    2008-07-01

    ZnO hollow spheres with porous crystalline shells were one-pot fabricated by hydrothermal treatment of glucose/ZnCl2 mixtures at 180 degrees C for 24 h, and then calcined at different temperatures for 4 h. The as-prepared samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption-desorption isotherms. The photocatalytic activity of the as-prepared samples was evaluated by photocatalytic decolorization of Rhodamine B aqueous solution at ambient temperature. The results indicated that the average crystallite size, shell thickness, specific surface areas, pore structures, and photocatalytic activity of ZnO hollow spheres could be controlled by varying the molar ratio of glucose to zinc ions (R). With increasing R, the photocatalytic activity increases and reaches a maximum value at R = 15, which can be attributed to the combined effects of several factors such as specific surface area, the porous structure and the crystallite size. Further results show that hollow spheres can be more readily separated from the slurry system by filtration or sedimentation after photocatalytic reaction and reused than conventional powder photocatalyst. After many recycles for the photodegradation of RhB, the catalyst does not exhibit any great loss in activity, confirming ZnO hollow spheres is stability and not photocorroded. The prepared ZnO hollow spheres are also of great interest in solar cell, catalysis, separation technology, biomedical engineering, and nanotechnology.

  13. Nanohydroxyapatite coating on a titanium-niobium alloy by a hydrothermal process.

    PubMed

    Xiong, Jianyu; Li, Yuncang; Hodgson, Peter D; Wen, Cui'e

    2010-04-01

    A novel one-step hydrothermal coating process was used to produce nanohydroxyapatite (nano-HA) coating on a titanium-niobium (TiNb) alloy substrate in a newly designed solution containing calcium and phosphate ions. The morphology of the coating was studied using scanning electron microscopy. The phase identification of the coating was carried out using X-ray diffraction, attenuated total reflectance Fourier transform infrared spectroscopy and transmission electron microscopy. The reaction between the surface of TiNb alloy and the solution during the hydrothermal process was studied by X-ray photoelectron spectroscopy. Results show that the coating formed on the surface of TiNb alloy was composed of nano-HA particles. During the hydrothermal process, TiO(2) and Nb(2)O(5) formed on the TiNb alloy surface and hydrated to Ti(OH)(4) and Nb(OH)(5), respectively. Calcium phosphate nucleated and grew into a layer of nano-HA particles on the surface of TiNb alloy under the hydrothermal conditions. The crystallinity of the nano-HA coating was improved with the increase in hydrothermal treatment temperature and time duration. Nano-HA coating with good crystallinity was produced on the TiNb alloy via the hydrothermal process at a temperature of 200 degrees C for 12 h.

  14. Modeling hydrothermal processes at ocean spreading centers: Magma to microbe—An overview

    NASA Astrophysics Data System (ADS)

    Lowell, Robert P.; Seewald, Jeffrey S.; Metaxas, Anna; Perfit, Michael R.

    Hydrothermal processes at oceanic spreading centers encompass a number of highly interconnected processes ranging from the transport of mantle melts beneath spreading centers to the evolution of ocean chemistry and Earth's climate. This volume, which stems from a RIDGE Theoretical Institute held at Mammoth Lakes, California in June 2006, contains papers that address the complex connections among magmatic heat supply, crustal formation, seismicity, and hydrothermal circulation as well as the complex linkages among hydrothermal circulation, vent chemistry, carbon cycling, and microbial and macrofaunal ecosystems. The last paper in this volume explores the connection between hydrothermal venting and the chemical evolution of the oceans during the Phanerozoic. From reading these papers, one should recognize the wide variety of modeling approaches used and the uneven state of model development within various subdisciplines. Models of hydrothermal circulation and vent chemistry tend to be more quantitative, whereas models of carbon cycling and biological processes tend to be more conceptual. Although many of the complex linkages among the subdisciplines are understood at a conceptual level, considerable effort must be undertaken to develop integrated quantitative models of hydrothermal processes at oceanic spreading centers.

  15. Nanohydroxyapatite coating on a titanium-niobium alloy by a hydrothermal process.

    PubMed

    Xiong, Jianyu; Li, Yuncang; Hodgson, Peter D; Wen, Cui'e

    2010-04-01

    A novel one-step hydrothermal coating process was used to produce nanohydroxyapatite (nano-HA) coating on a titanium-niobium (TiNb) alloy substrate in a newly designed solution containing calcium and phosphate ions. The morphology of the coating was studied using scanning electron microscopy. The phase identification of the coating was carried out using X-ray diffraction, attenuated total reflectance Fourier transform infrared spectroscopy and transmission electron microscopy. The reaction between the surface of TiNb alloy and the solution during the hydrothermal process was studied by X-ray photoelectron spectroscopy. Results show that the coating formed on the surface of TiNb alloy was composed of nano-HA particles. During the hydrothermal process, TiO(2) and Nb(2)O(5) formed on the TiNb alloy surface and hydrated to Ti(OH)(4) and Nb(OH)(5), respectively. Calcium phosphate nucleated and grew into a layer of nano-HA particles on the surface of TiNb alloy under the hydrothermal conditions. The crystallinity of the nano-HA coating was improved with the increase in hydrothermal treatment temperature and time duration. Nano-HA coating with good crystallinity was produced on the TiNb alloy via the hydrothermal process at a temperature of 200 degrees C for 12 h. PMID:19836001

  16. Lessons from studies of impact crater hydrothermal processes in terrestrial analogs and their implications for impact craters on Mars

    NASA Astrophysics Data System (ADS)

    Newsom, H. E.

    2011-12-01

    Studying hydrothermal processes in terrestrial impact craters as martian analogs has sometimes been fraught with objections, including the Earth's greater abundance of water, the neutral instead of acidic aqueous environments and the composition of the targets. Although recent discoveries have dispelled many objections, some misconceptions remain. For example, the relevance of the Chicxulub crater as a martian analog is sometimes questioned because the target was covered with sediments, including carbonates and sulfates. However the impactites at the Yaxcopoil-1 drill site are derived from the underlying silicate basement. Comparisons can also be difficult because of scale issues, as many terrestrial craters with evidence of hydrothermal activity, e.g. Lonar, Haughton, Ries etc., are smaller than the Martian craters with phyllosilicate signatures (Ehlmann et al., 2010). Summarizing, the results of many studies of terrestrial craters show that: 1) Most terrestrial craters larger than 1.8 km diameter have at least some evidence of aqueous or hydrothermal processes in the form of alteration minerals (e.g., Naumov, 2005). 2) Impact melts in crater fill and ejecta blankets provide heat that can produce hydrothermal alteration if water is available (Newsom, 1980). 3) The uplifted geothermal gradient can be as important a heat source as shock effects. 4) Mineralogical evidence for high-temperature fluids (> 350 oC) is present in the central uplift of the Manson structure, and in the ejecta from the Chicxulub impact, where precipitation of phyllosilicates from hydrothermal fluids has also been described (Newsom et al., 2010). 5) Impact deposits begin hot, but have an extended cooling period during which alteration phases can back react to low temperature phases with corresponding stable isotope signatures. 5) Hydrothermal fluids can travel long distances from their sources (e.g., Chicxulub, Yaxcopoil site) and are often localized to faults or porous breccias (e.g. Sudbury

  17. Geochemical studies on the biodiversity and hydrothermal activity; mineralogy, chemistry, and age determination of hydrothermal chimney collected from Suiyo seamount, Izu-Bonin arc

    NASA Astrophysics Data System (ADS)

    Noguchi, T.; Oomori, T.; Taira, N.; Takada, J.; Urabe, T.

    2004-12-01

    Hydrothermal chimney structure has the steep environmental gradients of temperature, redox potential, pH and chemical concentration, which will provide diverse microhabitats for microbial communities (K.Takai et al. 2001, Hermie J.M. Harmsen et al. 1997). It is important for detailed understanding of the biodiversity to determine the chimney structural environment. Suiyo seamount is located 28.57° N, 140.66° E, where is suitable to compare with the Mid-ocean ridge hydrothermal field, because of few influence of terrestrial sediment. It was reported that the magma chamber below the seamount was very shallow ( ˜1 km), and high temperature hydrothermal fluid chamber was underlying just below the seafloor sealed with anhydrite and barite. Chimney samples used in this study were collected by Dive 1222-1225 of SHINKAI 2000 (JAMSTEC) in 2000. We measured the chemical composition with neutron activation analysis (NAA) and X-ray fluorescence analysis (XRF), mineral composition with X-ray diffraction analysis (XRD), and the precipitation age measurements ( ˜200 years) of these chimneys with γ -ray spectrometry (210Pb/Pb method, 228Th/228Ra method, and 210Pb/226Ra method). The mineral composition of the Suiyo seamount chimney were contained barite (BaSO4), sphalerite ((Zn,Fe)S), pyrite (FeS2), and chalcopyrite (CuFeS2) as a major mineral constituents. The chemical composition shows that gold contents in the chimney collected from Suiyo seamount were much higher (maximum 166 ppm) than other hydrothermal field. The chronological study showed that the precipitation ages of sulfide chimney samples (ranged in 37.2-79.6 years before 2002 by 210Pb/Pb method) were older than barite chimney ((ranged in 2.9-8.2 years before 2002 by 228Th/228Ra method). We will discuss about the process of chimney formation, the temporal variation of the past hydrothermal activity and the difference from other submarine hydrothermal fields (EPR, MAR, Okinawa trough, Loihi seamount).

  18. Investigations on Bi25FeO40 powders synthesized by hydrothermal and combustion-like processes

    NASA Astrophysics Data System (ADS)

    Köferstein, Roberto; Buttlar, Toni; Ebbinghaus, Stefan G.

    2014-09-01

    The syntheses of phase-pure and stoichiometric iron sillenite (Bi25FeO40) powders by a hydrothermal (at ambient pressure) and a combustion-like process are described. Phase-pure samples were obtained in the hydrothermal reaction at 100 °C (1), whereas the combustion-like process leads to pure Bi25FeO40 after calcination at 750 °C for 2 h (2a). The activation energy of the crystallite growth process of hydrothermally synthesized Bi25FeO40 was calculated as 48(9) kJ mol-1. The peritectic point was determined as 797(1) °C. The optical band gaps of the samples are between 2.70(7) eV and 2.81(6) eV. Temperature and field-depending magnetization measurements (5-300 K) show a paramagnetic behaviour with a Curie constant of 55.66×10-6 m3 K mol-1 for sample 1 and C=57.82×10-6 m3 K mol-1 for sample 2a resulting in magnetic moments of μmag=5.95(8) μB mol-1 and μmag=6.07(4) μB mol-1. The influence of amorphous iron-oxide as a result of non-stoichiometric Bi/Fe ratios in hydrothermal syntheses on the magnetic behaviour was additionally investigated.

  19. Diversity of hydrothermal processes and different types of epithermal deposits

    NASA Astrophysics Data System (ADS)

    Sidorov, A. A.; Volkov, A. V.

    2016-05-01

    It is shown that classical epithermal deposits with hydrothermal explosions, brecciated and framework-lamellar (including agate-like) structures, and well-developed bonanzas are usually pre-porphyry in origin. This inference seems to be important for development of the genetic model of a porphyry-epithermal ore-forming system as well as for exploration of gold-silver deposits and assessment of their potential.

  20. 30,000 years of hydrothermal activity at the lost city vent field.

    PubMed

    Früh-Green, Gretchen L; Kelley, Deborah S; Bernasconi, Stefano M; Karson, Jeffrey A; Ludwig, Kristin A; Butterfield, David A; Boschi, Chiara; Proskurowski, Giora

    2003-07-25

    Strontium, carbon, and oxygen isotope data and radiocarbon ages document at least 30,000 years of hydrothermal activity driven by serpentinization reactions at Lost City. Serpentinization beneath this off-axis field is estimated to occur at a minimum rate of 1.2 x 10(-4) cubic kilometers per year. The access of seawater to relatively cool, fresh peridotite, coupled with faulting, volumetric expansion, and mass wasting processes, are crucial to sustain such systems. The amount of heat produced by serpentinization of peridotite massifs, typical of slow and ultraslow spreading environments, has the potential to drive Lost City-type systems for hundreds of thousands, possibly millions, of years.

  1. Microbial Activity and Volatile Fluxes in Seafloor Hydrothermal Systems

    NASA Astrophysics Data System (ADS)

    Corrigan, R. S.; Lowell, R. P.

    2013-12-01

    Understanding geographically and biologically the production or utilization of volatile chemical species such as CO2, CH4, and H2 is crucial not only for understanding hydrothermal processes but also for understanding life processes in the oceanic crust. To estimate the microbial effect on the transport of these volatiles, we consider a double-loop single pass model as shown in Figure 1 to estimate the mass fluxes shown. We then use a simple mixing formulation: C4Q4 = C3 (Q1 -Q3)+ C2Q2, where C2 is the concentration of the chemical in seawater, C3 is the average concentration of the chemical in high temperature focused flow, C4 is the expected concentration of the chemical as a result of mixing, and the relevant mass flows are as shown in Figure 1. Finally, we compare the calculated values of CO2, CH4, and H2 in diffuse flow fluids to those observed. The required data are available for both the Main Endeavour Field on the Juan de Fuca Ridge and the East Pacific Rise 9°50' N systems. In both cases we find that, although individual diffuse flow sites have observed concentrations of some elements that are greater than average, the average concentration of these volatiles is smaller in all cases than the concentration that would be expected from simple mixing. This indicates that subsurface microbes are net utilizers of these chemical constituents at the Main Endeavour Field and at EPR 9°50' N on the vent field scale. Figure 1. Schematic of a 'double-loop' single-pass model above a convecting, crystallizing, replenished AMC (not to scale). Heat transfer from the vigorously convecting, cooling, and replenished AMC across the conductive boundary layer δ drives the overlying hydrothermal system. The deep circulation represented by mass flux Q1 and black smoker temperature T3 induces shallow circulation noted by Q2. Some black smoker fluid mixes with seawater resulting in diffuse discharge Q4, T4, while the direct black smoker mass flux with temperature T3 is reduced

  2. Effects of hydrothermal alteration on Pb in the active PACMANUS hydrothermal field, ODP Leg 193, Manus Basin, Papua New Guinea: A LA-ICP-MS study

    NASA Astrophysics Data System (ADS)

    Beaudoin, Yannick; Scott, Steven D.; Gorton, Michael P.; Zajacz, Zoltan; Halter, Werner

    2007-09-01

    The conventional model of leaching volcanic rocks as a source of metals in a seafloor hydrothermal systems has been tested by examining the behavior of Pb and other trace elements during hydrothermal alteration. ODP Leg 193 drill sites 1188 (Snowcap) and 1189 (Roman Ruins) on Pual Ridge in the eastern Manus Basin offshore eastern Papua New Guinea provide a unique three-dimensional window into an active back-arc hydrothermal system. We investigate by means of a LA-ICP-MS microbeam technique the capacity of Pb to be leached from a host volcanic rock exposed to various types and intensities of alteration. Our results are in general agreement with previous studies that utilized bulk analytical techniques but provide a more detailed explanation of the processes. Fresh representative dacitic lavas from the Pual Ridge have an average whole rock Pb content of 5.2 ppm, an average interstitial glass Pb content of 5.6 ppm and an average plagioclase Pb content of 1.0 ppm. Altered matrix samples have highly variable Pb values ranging from 0 to 52.4 ppm. High Pb values in altered samples are associated with a low temperature chlorite and clay mineral assemblage, in some cases overprinted by a high temperature (up to 350 °C) silica-rich "bleaching" alteration. Only the most highly altered matrix samples have REE patterns that differ from the fresh Pual Ridge dacite. This may represent either different lava histories or alteration characteristics that have affected normally immobile REEs. Altered samples with the highest Pb values have similar REE patterns to those of the local unaltered lavas. They are compositionally similar to typical Pual Ridge dacites indicating a genetic relationship between the main regional volcanic suite and the subseafloor hydrothermally altered, Pb-enriched material. Relative loss/gain for Pb between the analyzed altered samples and a calculated precursor show a maximum relative gain of 901%. Samples with relative Pb gain from both drill sites are

  3. Microwave hydrothermal synthesis of AgInS{sub 2} with visible light photocatalytic activity

    SciTech Connect

    Zhang, Wenjuan; Li, Danzhen; Chen, Zhixin; Sun, Meng; Li, Wenjuan; Lin, Qiang; Fu, Xianzhi

    2011-07-15

    Highlights: {yields} AgInS{sub 2} nanoparticles were synthesized by a microwave hydrothermal method. {yields} This method involves no organic solvents, catalysts, or surfactants. {yields} AgInS{sub 2} showed higher activity for photocatalytic degradation MO than TiO{sub 2-x}N{sub x}. {yields} Holes, O{sub 2}{center_dot}{sup -}, and H{sub 2}O{sub 2} played an important role in the photocatalytic process. -- Abstract: AgInS{sub 2} nanoparticles with superior visible light photocatalytic activity were successfully synthesized by a microwave hydrothermal method. This method is a highly efficient and rapid route that involves no organic solvents, catalysts, or surfactants. The photocatalytic activity of AgInS{sub 2} nanoparticles was investigated through the degradation of dyes under visible light irradiation. Compared with TiO{sub 2-x}N{sub x}, AgInS{sub 2} has exhibited a superior activity for photocatalytic degradation MO under the same condition. The experiment results showed that superoxide radicals (O{sub 2}{center_dot}{sup -}), hydrogen peroxides (H{sub 2}O{sub 2}) and holes (h{sup +}) were the mainly active species for the degradation of organic pollutants over AgInS{sub 2}. Through the determination of flat band potential, the energy band structure of the sample was obtained. A possible mechanism for the degradation of organic pollutant over AgInS{sub 2} was proposed.

  4. Hydrothermal mineralogy and fluid inclusions chemistry to understand the roots of active geothermal systems

    NASA Astrophysics Data System (ADS)

    Chambefort, I. S.; Dilles, J. H.; Heinrich, C.

    2013-12-01

    An integrated study to link magmatic textures, magmatic mineral compositions, hydrothermal alteration zoning, hydrothermal mineral chemistry, and fluid inclusion compositions has been undertaken to link an intrusive complex and its degassing alteration halo with their surface equivalent in an active geothermal system. Ngatamariki geothermal system, New Zealand, presents a unique feature in the Taupo Volcanic Zone (TVZ). Drilling intercepted an intrusive complex with a high temperature alteration halo similarly to what is observed in magmatic-derived ore deposits. Thus it presents the perfect opportunity to study the magmatic-hydrothermal transition of the TVZ by characterizing the nature of the deep magmatic fluids link to the heat source of the world known geothermal fields. The record of magmatic-hydrothermal fluid-rock interactions preserved at Ngatamariki may be analogous of processes presently occurring at depth beneath TVZ geothermal systems. The intrusive complex consists of over 5 km3 of tonalite, diorite, basalt and aplitic dykes. Evidence of undercooling subsolidus magmatic textures such as myrmekite and skeletal overgrowth are commonly observed and often linked to volatile loss. The fluids released during the crystallization of the intrusive complex are interpreted to be at the origin of the surrounding high temperature alteration halo. Advanced argillic to potassic alteration and high temperature acidic assemblage is associated with high-temperature quartz veining at depth and vuggy silica at the paleo-surface. Major element compositions of the white micas associated with the high temperature halo show a transition from, muscovite to phengite, muscovitic illite away from the intrusion, with a transition to pyrophyllite and/ or topaz, and andalusite characteristic of more acidic conditions. Abundant high-density (up to 59 wt% NaCl eq and homogenization temperatures of 550 degree Celsius and above) coexist with low-density vapor fluid inclusions. This

  5. Hydrothermal fluid-mineral interactions within volcanic sediment layer revealed by shallow drilling in active seafloor hydrothermal fields in the mid-Okinawa

    NASA Astrophysics Data System (ADS)

    Ishibashi, J.; Miyoshi, Y.; Tanaka, K.; Omori, E.; Takahashi, Y.; Furuzawa, Y.; Yamanaka, T.; Kawagucci, S.; Yoshizumi, R.; Urabe, T.

    2012-12-01

    TAIGA11 Expedition of R/V Hakurei-maru No.2 was conducted in June, 2011 to study subseafloor environment below active hydrothermal fields using a shallow drilling system (called as Benthic Multi-coring System, BMS). Three active hydrothermal fields at Iheya North Knoll (27 47'N, 126 54'E), at Izena Hole Jade site (27 16'N, 127 05'E) and at Izena Hole Hakurei site (27 15'N, 127 04'E) were selected as exploration targets, to focus on a hydrothermal fluid circulation system that develops in sediment consists of volcaniclastic and hemipelagic materials. In this presentation, we will report mineralogy of hydrothermal precipitates and altered clay minerals together with geochemistry of pore fluids, to discuss hydrothermal interactions beneath an active hydrothermal field. In the Iheya North Knoll hydrothermal field, the BMS drilling successfully attained to 453 cmbsf at the station 200 meters apart from the central mound area. The obtained core consisted almost entirely of grayish white altered mud that was identified as kaolinite by XRD. Pore fluid from the corresponding depth showed enrichment in major cations (Na, K, Ca and Mg) and Cl, which may be explained as a result of involvement of water into the kaolinite. Since kaolinite is considered as stable in rather acidic environment, its abundant occurrence beneath the seafloor would be attributed to a unique hydrothermal interaction. A possible scenario is intrusion of the vapor-rich hydrothermal component that has experienced phase separation. In the Jade hydrothermal fields in the Izena Hole, the BMS drilling successfully attained to 529 cmbsf at the marginal part of a hydrothermal field. The obtained core comprised grayish white hydrothermal altered mud below 370 cmbsf. Occurrence of native sulphur is also identified. Unfortunately, pore fluid could not be extracted from the intense alteration layer. In the Hakurei hydrothermal fields in the Izena Hole, the BMS drilling successfully attained to 610 cmbsf near one of

  6. Post-Impact Hydrothermal Activity at the Haughton Impact Structure, Devon Island, Nunavut, Canada

    NASA Technical Reports Server (NTRS)

    Osinski, G. R.; Spray, J. G.; Bunch, T. E.; Grieve, R. A. F.; Schutt, J. W.; Lee, P.

    2000-01-01

    Evidence for impact-generated hydrothermal activity is reported from the Haughton crater, Canada. Two distinct settings have been found: (1) pipe structures with marcasite, pyrite and minor chalcopyrite; (2) cavity and fracture fillings with marcasite predominant.

  7. Ultramafic-hosted Hydrothermal Systems at Mid-Ocean Ridges: Serpentinization, Chloritization and Geochemical Controls on Mass-Transfer Processes

    NASA Astrophysics Data System (ADS)

    Seyfried, W. E.; Pester, N. J.; Ding, K.

    2012-12-01

    Recent studies of seafloor hydrothermal systems associated with the slow spreading Mid-Atlantic Ridge have provided a wealth of information on the complex interplay between tectonic and magmatic processes that ultimately govern the chemical and physical evolution of these systems. The Lost City hydrothermal field (LCHF)(30°N) and the Rainbow hydrothermal system (36°N), for example, provide contrasting styles of heat and mass transfer that result in very different constraints on the composition of hydrothermal fluids. Hydrothermal fluids were sampled and analyzed during a series of ROV (Jason II) supported dives in 2008 to these and related vent sites along the northern MAR. In addition to deployment of conventional vent fluid sampling devices, in-situ chemical sensor systems were also used to better constrain pH and redox reactions. The general characteristics of the Lost City hydrothermal field, which is offset approximately 15km from the MAR owing to tectonic effects imposed by the emplacement of the Atlantis Massif, have been extensively reviewed in recent years. Vent fluids issuing from this peridotite-hosted system reveal temperatures of approximately 90-100°C, high concentrations of dissolved hydrogen and methane, and pH measured (25°C) values that exceed 10. The relatively low vent fluid temperatures notwithstanding, phase equilibria constraints imposed by dissolved Ca and sulfate suggest temperatures of approximately 200°C at depth, below the seafloor. New data for dissolved silica indicate a hydrothermal "root zone" lacking brucite, but where fluid chemistry and pH is buffered by serpentine-diopside-fluid equilibria. Consistent with previously published strontium and boron isotope measurements, data reported here for trace alkali elements (Cs, Rb, Li) indicate high fluid/rock mass ratios. Variably low dissolved Fe concentrations are broadly consistent with constraints imposed by magnetite-fluid equilibria at the high measured dissolved H2

  8. Beryllium 10 in hydrothermal vent deposits from the East Pacific Ridges: Role of sediments in the hydrothermal processes

    SciTech Connect

    Valette-Silver, J.N.; Tera, F.; Klein, J.; Middleton, R.

    1987-10-10

    Beryllium 10 concentrations were determined for 31 handpicked hydrothermal sulfides, six oxyhydroxides, seven basalts, and five sediments collected from the hydrothermally active areas of the East Pacific ridges. The samples includes specimens from the East Pacific Rise (EPR) at 21 /sup 0/N and 13 /sup 0/N, the Galapagos Rift, the Guaymas Basin, and the Gorda and the Juan de Fuca ridges. Additional samples from massive sulfides associated with the Oman ophiolites were studied. In all samples, we obtained values ranging from 0.04 x 10/sup 6/ atoms/g to 125 x 10/sup 6/ atoms/g, with the lowest values being very close to our blank (0.015 x 10/sup 6/ atoms/g). The data show systematic variations with sample location and type. The /sup 10/Be concentrations measured for the mid-ocean basalts are of the order of 0.3 x 10/sup 6/ atoms/g and reach 3800 x 10/sup 6/ atoms/g for the pelagic deep-sea sediments collected near the EPR 21 /sup 0/N. Based on their /sup 10/Be concentrations, we can clearly distinguish two categories of sulfides: sulfides containing low /sup 10/Be concentration (<10 /sup 6/ atoms/g) sitting directly on the mid-ocean basalt (EPR of Juan de Fuca), and sulfides with high /sup 10/Be concentration (>10/sup 6/ atoms/g) located atop of a thick pile of young sediments (Guaymas Basin or Gorda Ridge).

  9. Subaqueous cryptodome eruption, hydrothermal activity and related seafloor morphologies on the andesitic North Su volcano

    NASA Astrophysics Data System (ADS)

    Thal, Janis; Tivey, Maurice; Yoerger, Dana R.; Bach, Wolfgang

    2016-09-01

    North Su is a double-peaked active andesite submarine volcano located in the eastern Manus Basin of the Bismarck Sea that reaches a depth of 1154 m. It hosts a vigorous and varied hydrothermal system with black and white smoker vents along with several areas of diffuse venting and deposits of native sulfur. Geologic mapping based on ROV observations from 2006 and 2011 combined with morphologic features identified from repeated bathymetric surveys in 2002 and 2011 documents the emplacement of a volcanic cryptodome between 2006 and 2011. We use our observations and rock analyses to interpret an eruption scenario where highly viscous, crystal-rich andesitic magma erupted slowly into the water-saturated, gravel-dominated slope of North Su. An intense fragmentation process produced abundant blocky clasts of a heterogeneous magma (olivine crystals within a rhyolitic groundmass) that only rarely breached through the clastic cover onto the seafloor. Phreatic and phreatomagmatic explosions beneath the seafloor cause mixing of juvenile and pre-existing lithic clasts and produce a volcaniclastic deposit. This volcaniclastic deposit consists of blocky, non-altered clasts next, variably (1-100%) altered clasts, hydrothermal precipitates and crystal fragments. The usually applied parameters to identify juvenile subaqueous lava fragments, i.e. fluidal shape or chilled margin, were not applicable to distinguish between pre-existing non-altered clasts and juvenile clasts. This deposit is updomed during further injection of magma and mechanical disruption. Gas-propelled turbulent clast-recycling causes clasts to develop variably rounded shapes. An abundance of blocky clasts and the lack of clasts typical for the contact of liquid lava with water is interpreted to be the result of a cooled, high-viscosity, crystal-rich magma that failed as a brittle solid upon stress. The high viscosity allows the lava to form blocky and short lobes. The pervasive volcaniclastic cover on North Su is

  10. Water under Hydrothermal, Supercritical, and High Pressure Conditions as Key to Developing Green Processes and New Technologies

    NASA Astrophysics Data System (ADS)

    Smith, Richard L.

    2010-11-01

    In this work, an overview of research and activity in the hydrothermal and supercritical fields is given. Properties and characteristics of water are reviewed in relation to separations, materials, and chemical conversion processes. Examples that are discussed include biomass fractionation, natural product extraction, material formation, biomass oxidation, biomass conversions, waste treatment, flames, and hydrocarbon upgrading. In the field of chromatography, water under hydrothermal conditions can be used to replace many organic solvents. As a solvent for separation processes, hot water can be used to achieve rapid and efficient fractionation of biomass or isolation of chemical compounds. In the field of materials, water in its supercritical state can be used to synthesize practical materials and to develop processes with low environmental burden. In the field of chemical processing, water can be used under oxidizing conditions to generate clean and renewable energy and to reduce the number of chemical steps for producing chemical products. A few other technological applications such as flames and hydrocarbon upgrading will be discussed. Water under hydrothermal, supercritical and high pressure conditions has many favorable properties that allow the development of green chemical processes and new technologies.

  11. New evidence for persistent impact-generated hydrothermal activity in the Miocene Ries impact structure, Germany

    NASA Astrophysics Data System (ADS)

    Arp, Gernot; Kolepka, Claudia; Simon, Klaus; Karius, Volker; Nolte, Nicole; Hansen, Bent T.

    2013-12-01

    The extent of impact-generated hydrothermal activity in the 24 km sized Ries impact structure has been controversially discussed. To date, mineralogical and isotopic investigations point to a restriction of hydrothermal activity to the impact-melt bearing breccias, specifically the crater-fill suevite. Here, we present new petrographic, geochemical, and isotopic data of postimpact carbonate deposits, which indicate a hydrothermal activity more extended than previously assumed. Specifically, carbonates of the Erbisberg, a spring mound located upon the inner crystalline ring of the crater, show travertine facies types not seen in any of the previously investigated sublacustrine soda lake spring mounds of the Ries basin. In particular, the streamer carbonates, which result from the encrustation of microbial filaments in subaerial spring effluents between 60 and 70 °C, are characteristic of a hydrothermal origin. While much of the primary geochemical and isotopic signatures in the mound carbonates have been obliterated by diagenesis, a postimpact calcite vein from brecciated gneiss of the subsurface crater floor revealed a flat rare earth element pattern with a clear positive Eu anomaly, indicating a hydrothermal fluid convection in the crater basement. Finally, the strontium isotope stratigraphic correlation of the travertine mound with the crater basin succession suggests a hydrothermal activity for about 250,000 yr after the impact, which would be much longer than previously assumed.

  12. Removal of copper and cadmium from aqueous solution using switchgrass biochar produced via hydrothermal carbonization process.

    PubMed

    Regmi, Pusker; Garcia Moscoso, Jose Luis; Kumar, Sandeep; Cao, Xiaoyan; Mao, Jingdong; Schafran, Gary

    2012-10-30

    Biochar produced from switchgrass via hydrothermal carbonization (HTC) was used as a sorbent for the removal of copper and cadmium from aqueous solution. The cold activation process using KOH at room temperature was developed to enhance the porous structure and sorption properties of the HTC biochar. The sorption efficiency of HTC biochar and alkali activated HTC biochar (HTCB) for removing copper and cadmium from aqueous solution were compared with commercially available powdered activated carbon (PAC). The present batch adsorption study describes the effects of solution pH, biochar dose, and contact time on copper and cadmium removal efficiency from single metal ion aqueous solutions. The activated HTCB exhibited a higher adsorption potential for copper and cadmium than HTC biochar and PAC. Experiments conducted with an initial metal concentration of 40 mg/L at pH 5.0 and contact time of 24 h resulted in close to 100% copper and cadmium removal by activated HTCB at 2 g/L, far greater than what was observed for HTC biochar (16% and 5.6%) and PAC (4% and 7.7%). The adsorption capacities of activated HTCB for cadmium removal were 34 mg/g (0.313 mmol/g) and copper removal was 31 mg/g (0.503 mmol/g). PMID:22687632

  13. Hydrothermal activity at slow-spreading ridges: variability and importance of magmatic controls

    NASA Astrophysics Data System (ADS)

    Escartin, Javier

    2016-04-01

    Hydrothermal activity along mid-ocean ridge axes is ubiquitous, associated with mass, chemical, and heat exchanges between the deep lithosphere and the overlying envelopes, and sustaining chemiosynthetic ecosystems at the seafloor. Compared with hydrothermal fields at fast-spreading ridges, those at slow spreading ones show a large variability as their location and nature is controlled or influenced by several parameters that are inter-related: a) tectonic setting, ranging from 'volcanic systems' (along the rift valley floor, volcanic ridges, seamounts), to 'tectonic' ones (rift-bounding faults, oceanic detachment faults); b) the nature of the host rock, owing to compositional heterogeneity of slow-spreading lithosphere (basalt, gabbro, peridotite); c) the type of heat source (magmatic bodies at depth, hot lithosphere, serpentinization reactions); d) and the associated temperature of outflow fluids (high- vs.- low temperature venting and their relative proportion). A systematic review of the distribution and characteristics of hydrothermal fields along the slow-spreading Mid-Atlantic Ridge suggests that long-lived hydrothermal activity is concentrated either at oceanic detachment faults, or along volcanic segments with evidence of robust magma supply to the axis. A detailed study of the magmatically robust Lucky Strike segment suggests that all present and past hydrothermal activity is found at the center of the segment. The association of these fields to central volcanos, and the absence of indicators of hydrothermal activity along the remaining of the ridge segment, suggests that long-lived hydrothermal activity in these volcanic systems is maintained by the enhanced melt supply and the associated magma chamber(s) required to build these volcanic edifices. In this setting, hydrothermal outflow zones at the seafloor are systematically controlled by faults, indicating that hydrothermal fluids in the shallow crust exploit permeable fault zones to circulate. While

  14. Hydrothermal processing of BaTiO{sub 3}/polymer films

    SciTech Connect

    Slamovich, E.B.; Aksay, I.A.

    1994-12-31

    Hydrothermally derived films of BaTiO{sub 3} were fabricated by reacting thin layers of titanium organometallic liquid precursors in aqueous solutions containing Ba(OH){sub 2} and having a high pH. Cubic submicron polycrystalline films of BaTiO{sub 3} (thickness {approx} 1 {mu}m) were formed at 70 C. Low concentrations of block copolymers of polybutadiene and polystyrene were incorporated into the liquid precursor to prevent precursor film cracking. Higher polymer concentrations allowed fabrication of polymer/ceramic composite films by virtue of the low temperature used in hydrothermal processing.

  15. A review on hydrothermal pre-treatment technologies and environmental profiles of algal biomass processing.

    PubMed

    Patel, Bhavish; Guo, Miao; Izadpanah, Arash; Shah, Nilay; Hellgardt, Klaus

    2016-01-01

    The need for efficient and clean biomass conversion technologies has propelled Hydrothermal (HT) processing as a promising treatment option for biofuel production. This manuscript discussed its application for pre-treatment of microalgae biomass to solid (biochar), liquid (biocrude and biodiesel) and gaseous (hydrogen and methane) products via Hydrothermal Carbonisation (HTC), Hydrothermal Liquefaction (HTL) and Supercritical Water Gasification (SCWG) as well as the utility of HT water as an extraction medium and HT Hydrotreatment (HDT) of algal biocrude. In addition, the Solar Energy Retained in Fuel (SERF) using HT technologies is calculated and compared with benchmark biofuel. Lastly, the Life Cycle Assessment (LCA) discusses the limitation of the current state of art as well as introduction to new potential input categories to obtain a detailed environmental profile. PMID:26514623

  16. A review on hydrothermal pre-treatment technologies and environmental profiles of algal biomass processing.

    PubMed

    Patel, Bhavish; Guo, Miao; Izadpanah, Arash; Shah, Nilay; Hellgardt, Klaus

    2016-01-01

    The need for efficient and clean biomass conversion technologies has propelled Hydrothermal (HT) processing as a promising treatment option for biofuel production. This manuscript discussed its application for pre-treatment of microalgae biomass to solid (biochar), liquid (biocrude and biodiesel) and gaseous (hydrogen and methane) products via Hydrothermal Carbonisation (HTC), Hydrothermal Liquefaction (HTL) and Supercritical Water Gasification (SCWG) as well as the utility of HT water as an extraction medium and HT Hydrotreatment (HDT) of algal biocrude. In addition, the Solar Energy Retained in Fuel (SERF) using HT technologies is calculated and compared with benchmark biofuel. Lastly, the Life Cycle Assessment (LCA) discusses the limitation of the current state of art as well as introduction to new potential input categories to obtain a detailed environmental profile.

  17. Effects of pH and temperature on photocatalytic activity of PbTiO3 synthesized by hydrothermal method

    NASA Astrophysics Data System (ADS)

    Li, Yongyu; Sun, Haijie; Wang, Ning; Fang, Wenxue; Li, Zhongjun

    2014-11-01

    PbTiO3 photocatalyst was synthesized successfully by facile hydrothermal method. The effects of the hydrothermal reaction temperatures and the pH values of the systems on the photocatalytic activities of PbTiO3 were investigated in detail. The photocatalytic activities of samples were evaluated by the degradation of methyl orange (MO) aqueous solution under simulated solar irradiation. The as-obtained PbTiO3 sample exhibits anisotropical growth along the (0 0 1) plane, and its photocatalytic activity is about 3 times higher than that of PbTiO3 prepared by precipitation method. Moreover, the as-prepared PbTiO3 has high stability during photocatalytic oxidation process, and does not cause secondary pollution.

  18. Discovery of Active Hydrothermal Sites Along the Mariana Volcanic Arc, Western Pacific Ocean

    NASA Astrophysics Data System (ADS)

    Baker, E. T.; Embley, R. W.; Resing, J. A.; Lupton, J. E.; Massoth, G. J.; de Ronde, C. E.; Nakamura, K.; Walker, S. L.

    2003-12-01

    Some 20,000 km of volcanic arcs, roughly one-third the total length of the global midocean ridge (MOR) system, rim the western Pacific Ocean. But compared to 25 years of hydrothermal investigations along MORs, exploration of similar activity on the estimated 600 submarine arc volcanoes is only beginning. In February 2003, as part of the Submarine Ring of Fire project funded by NOAA's Ocean Exploration Program, we made the first systematic survey of hydrothermal activity along the 1270-km-long Mariana intraoceanic volcanic arc, which lies almost entirely within the US EEZ. Prior fieldwork had documented active (but low-temperature) hydrothermal discharge on only three volcanoes: Kasuga 2, Kasuga 3, and Esmeralda Bank. During the cruise, we conducted 70 CTD operations over more than 50 individual volcanoes from 13° N to 23° N, plus a continuous CTD survey along 75 km of the back-arc spreading center (13° 15'N to 13° 41'N) adjacent to the southern end of the arc. We found evidence for active hydrothermal venting at 11 submarine volcanoes with summit (or caldera floor) depths ranging from 50 to 1550 m. Two additional sites were identified on the back-arc spreading center. Ongoing analyses of collected water samples could increase these totals. Our results confirmed continuing hydrothermal activity at Kasuga 2 (but not Kasuga 3) and Esmeralda Bank, in addition to newly discovered sites on nine other volcanoes. Many of these sites produce intense and widely dispersed plumes indicative of vigorous, high-temperature discharge. The volcanoes with active hydrothermal systems are about equally divided between those with and without summit calderas. The addition of the Marianas data greatly improves our view of hydrothermal sources along arcs. The 20,000 km of Pacific arcs can be divided between 6380 km of intraoceanic (i.e., mostly submarine) arcs and 13,880 km of island (i.e., mostly subaerial) arcs. At present, ˜15% of the total length of Pacific arcs has been surveyed

  19. Various-scale controls of complex subduction dynamics on magmatic-hydrothermal processes in eastern Mediterranean

    NASA Astrophysics Data System (ADS)

    Menant, Armel; Jolivet, Laurent; Sternai, Pietro; Ducoux, Maxime; Augier, Romain; Rabillard, Aurélien; Gerya, Taras; Guillou-Frottier, Laurent

    2014-05-01

    In subduction environment, magmatic-hydrothermal processes, responsible for the emplacement of magmatic bodies and related mineralization, are strongly controlled by slab dynamics. This 3D dynamics is often complex, resulting notably in spatial evolution through time of mineralization and magmatism types and in fast kinematic changes at the surface. Study at different scales of the distribution of these magmatic and hydrothermal products is useful to better constrain subduction dynamics. This work is focused on the eastern Mediterranean, where the complex dynamics of the Tethyan active margin since the upper Cretaceous is still largely debated. We propose new kinematic reconstructions of the region also showing the distribution of magmatic products and mineralization in space and time. Three main periods have thus been identified with a general southward migration of magmatic and ore bodies. (1) From late Cretaceous to lower Paleocene, calc-alkaline magmatism and porphyry Cu deposits emplaced notably in the Balkans, along a long linear cordillera. (2) From late Paleocene to Eocene, a barren period occurred while the Pelagonian microcontinent was buried within the subduction zone. (3) Since the Oligocene, Au-rich deposits and related K-rich magmatism emplaced in the Rhodopes, the Aegean and western Anatolian extensional domains in response to fast slab retreat and related mantle flow inducing the partial melting of the lithospheric mantle or the base of the upper crust where Au was previously stored. The emplacement at shallow level of this mineralization was largely controlled by large-scale structures that drained the magmatic-hydrothermal fluids. In the Cyclades for instance, field studies show that Au-rich but also base metal-rich ore deposits are syn-extensional and spatially related to large-scale detachment systems (e.g. on Tinos, Mykonos, Serifos islands), which are recognized as subduction-related structures. These results highlight the importance at

  20. 30,000 years of hydrothermal activity at the lost city vent field.

    PubMed

    Früh-Green, Gretchen L; Kelley, Deborah S; Bernasconi, Stefano M; Karson, Jeffrey A; Ludwig, Kristin A; Butterfield, David A; Boschi, Chiara; Proskurowski, Giora

    2003-07-25

    Strontium, carbon, and oxygen isotope data and radiocarbon ages document at least 30,000 years of hydrothermal activity driven by serpentinization reactions at Lost City. Serpentinization beneath this off-axis field is estimated to occur at a minimum rate of 1.2 x 10(-4) cubic kilometers per year. The access of seawater to relatively cool, fresh peridotite, coupled with faulting, volumetric expansion, and mass wasting processes, are crucial to sustain such systems. The amount of heat produced by serpentinization of peridotite massifs, typical of slow and ultraslow spreading environments, has the potential to drive Lost City-type systems for hundreds of thousands, possibly millions, of years. PMID:12881565

  1. Synthesis of pyrite FeS2 nanorods by simple hydrothermal method and its photocatalytic activity

    NASA Astrophysics Data System (ADS)

    Morales-Gallardo, M. V.; Ayala, A. M.; Pal, Mou; Cortes Jacome, M. A.; Toledo Antonio, J. A.; Mathews, N. R.

    2016-09-01

    In this work, FeS2 nanorods were synthetized by hydrothermal method. The advantages of our process were the high yield, simplicity and reproducibility. The material was studied in detail using different experimental tools such as XRD, SEM, HRTEM, EDXS, XPS, Raman, and UV-vis reflectance. XRD pattern and Raman data revealed good crystalline quality for the as synthesized pyrite FeS2. SEM analysis displayed the rod-like morphologies of FeS2 which seemed to grow radially from a center giving a flower-like appearance. From TEM images the approximate length and diameter of nano-rods were determined as 275 and 15 nm respectively. The material showed excellent photocatalytic activity which was assessed from the degradation of the methlyene blue.

  2. Amino acids assisted hydrothermal synthesis of hierarchically structured ZnO with enhanced photocatalytic activities

    NASA Astrophysics Data System (ADS)

    Guo, Yanxia; Lin, Siwen; Li, Xuan; Liu, Yuping

    2016-10-01

    Novel hierarchically structured ZnO, including rose-like, dandelion-like and flower-like, have been synthesized through a simple hydrothermal process using different amino acids (glutamine, histidine and glycine) as structure-directing agents and urea as deposition agent, followed by subsequent calcination. Amino acids played a crucial role in the formation of hierarchically structured ZnO, and different amino acids could induce different exquisite shapes and assembly ways, as well as more oxygen defects. The prepared hierarchically structured ZnO exhibited excellent photocatalytic activities for the photodegradation of Rhodamine B, which was associated with their special hierarchical structures, large BET surface area and the existence of more oxygen defects. Amino acid-assisted growth mechanism of hierarchically structured ZnO was also discussed.

  3. High-pressure homogenization associated hydrothermal process of palygorskite for enhanced adsorption of Methylene blue

    NASA Astrophysics Data System (ADS)

    Zhang, Zhifang; Wang, Wenbo; Wang, Aiqin

    2015-02-01

    Palygorskite (PAL) was modified by a high-pressure homogenization assisted hydrothermal process. The effects of modification on the morphology, structure and physicochemical properties of PAL were systematically investigated by Field-emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), Fourier transform infrared spectrometry (FTIR), Brunauer-Emmett-Teller (BET) analysis, X-ray diffraction (XRD) and Zeta potential analysis techniques, and the adsorption properties were systematically evaluated using Methylene blue (MB) as the model dye. The results revealed that the crystal bundles were disaggregated and the PAL nanorods became more even after treated via associated high-pressure homogenization and hydrothermal process, and the crystal bundles were dispersed as nanorods. The intrinsic crystal structure of PAL was remained after hydrothermal treatment, and the pore size calculated by the BET method was increased. The adsorption properties of PAL for MB were evidently improved (from 119 mg/g to 171 mg/g) after modification, and the dispersion of PAL before hydrothermal reaction is favorable to the adsorption. The desorption evaluation confirms that the modified PAL has stronger affinity with MB, which is benefit to fabricate a stable organic-inorganic hybrid pigment.

  4. Present-day submarine hydrothermal activity in the Taupo-Rotorua Zone (Bay of Plenty, New Zealand)

    SciTech Connect

    Osipenko, A.B.; Egorov, Yu.O.; Fazlullin, S.M.; Gavrilenko, G.M.; Shul`kin, V.I.; Chertkova, L.V.

    1994-09-01

    We made detailed descriptions of the structure and material composition of sedimentary and water columns in the vicinity of active submarine hydrothermal activity in the southern part of the Bay of Plenty (North Island, New Zealand). Geophysical methods revealed that the hydrothermal system is confined to a tectonically distinct zone with a sedimentary cover characterized by complex structure. Chemical and mineralogical investigations confirmed that the activity of underwater vents exerts no substantial regional influence on the composition and features of ore mineralization in these formations. It is shown that essentially hydrothermal formations distinguishable within areas of otherwise monotypic sediments directly coincide with zones of hydrothermal discharge in the ocean floor. The absence of pronounced hydrothermal anomalies, together with the presence of {open_quotes}tongues{close_quotes} of anomalous concentrations of water-soluble gases suggests that the discharges are primarily hydrothermal in character.

  5. The magmatic- and hydrothermal-dominated fumarolic system at the Active Crater of Lascar volcano, northern Chile

    NASA Astrophysics Data System (ADS)

    Tassi, F.; Aguilera, F.; Vaselli, O.; Medina, E.; Tedesco, D.; Delgado Huertas, A.; Poreda, R.; Kojima, S.

    2009-03-01

    Low-to-high temperature fumaroles discharging from the Active Crater of Lascar volcano (northern Chile) have been collected in November 2002, May 2005 and October 2006 for chemical and isotopic analysis to provide the first geochemical survey on the magmatic-hydrothermal system of this active volcano. Chemical and isotopic gas composition shows direct addition of high-temperature fluids from magmatic degassing, mainly testified by the very high contents of SO2, HCl and HF (up to 87,800, 29,500 and 2,900 μmol/mol) and the high R/Ra values (up to 7.29). Contributions from a hydrothermal source, mainly in gas discharges of the Active Crater rim, has also been detected. Significant variations in fluid chemistry, mainly consisting of a general decrease of magmatic-related compounds, i.e. SO2, have affected the fumarolic system during the period of observation, indicating an increase of the influence of the hydrothermal system surrounding the ascending deep fluids. The chemical composition of Active Crater fumaroles has been used to build up a geochemical model describing the main processes that regulate the fluid circulation system of Lascar volcano to be utilized in volcanic surveillance.

  6. Investigations on Bi{sub 25}FeO{sub 40} powders synthesized by hydrothermal and combustion-like processes

    SciTech Connect

    Köferstein, Roberto Buttlar, Toni; Ebbinghaus, Stefan G.

    2014-09-15

    The syntheses of phase-pure and stoichiometric iron sillenite (Bi{sub 25}FeO{sub 40}) powders by a hydrothermal (at ambient pressure) and a combustion-like process are described. Phase-pure samples were obtained in the hydrothermal reaction at 100 °C (1), whereas the combustion-like process leads to pure Bi{sub 25}FeO{sub 40} after calcination at 750 °C for 2 h (2a). The activation energy of the crystallite growth process of hydrothermally synthesized Bi{sub 25}FeO{sub 40} was calculated as 48(9) kJ mol{sup −1}. The peritectic point was determined as 797(1) °C. The optical band gaps of the samples are between 2.70(7) eV and 2.81(6) eV. Temperature and field-depending magnetization measurements (5−300 K) show a paramagnetic behaviour with a Curie constant of 55.66×10{sup −6} m{sup 3} K mol{sup −1} for sample 1 and C=57.82×10{sup −6} m{sup 3} K mol{sup −1} for sample 2a resulting in magnetic moments of µ{sub mag}=5.95(8) µ{sub B} mol{sup −1} and µ{sub mag}=6.07(4) µ{sub B} mol{sup −1}. The influence of amorphous iron-oxide as a result of non-stoichiometric Bi/Fe ratios in hydrothermal syntheses on the magnetic behaviour was additionally investigated. - Graphical abstract: Bi{sub 25}FeO{sub 40} powders were prepared by a hydrothermal method and a combustion process. The optical band gaps and the peritectic point were determined. The magnetic behaviour was investigated depending on the synthesis and the initial Bi/Fe ratios. The influence of amorphous iron-oxide on the magnetic properties was examined. - Highlights: • Two simple syntheses routes for stoichiometric Bi{sub 25}FeO{sub 40} powders using starch as polymerization agent. • Monitoring the phase evolution and crystallite growth kinetics during the syntheses. • Determination of the optical band gap and melting point. • Investigations of the magnetic behaviour of Bi{sub 25}FeO{sub 40} powders. • Influence of amorphous iron oxide and a non-stoichiometric Bi/Fe ratio on the

  7. Trace element behavior in hydrothermal experiments: Implications for fluid processes at shallow depths in subduction zones

    NASA Astrophysics Data System (ADS)

    You, C.-F.; Castillo, P. R.; Gieskes, J. M.; Chan, L. H.; Spivack, A. J.

    1996-05-01

    Chemical evaluation of fluids affected during progressive water-sediment interactions provides critical information regarding the role of slab dehydration and/or crustal recycling in subduction zones. To place some constraints on geochemical processes during sediment subduction, reactions between décollement sediments and synthetic NaCl-CaCl 2 solutions at 25-350°C and 800 bar were monitored in laboratory hydrothermal experiments using an autoclave apparatus. This is the first attempt in a single set of experiments to investigate the relative mobilities of many subduction zone volatiles and trace elements but, because of difficulties in conducting hydrothermal experiments on sediments at high P-T conditions, the experiments could only be designed for a shallow (˜ 10 km) depth. The experimental results demonstrate mobilization of volatiles (B and NH 4) and incompatible elements (As, Be, Cs, Li, Pb, Rb) in hydrothermal fluids at relatively low temperatures (˜ 300°C). In addition, a limited fractionation of light from heavy rare earth elements (REEs) occurs under hydrothermal conditions. On the other hand, the high field strength elements (HFSEs) Cr, Hf, Nb, Ta, Ti, and Zr are not mobile in the reacted fluids. The observed behavior of volatiles and trace elements in hydrothermal fluids is similar to the observed enrichment in As, B, Cs, Li, Pb, Rb, and light REEs and depletion in HFSEs in arc magmas relative to magmas derived directly from the upper mantle. Thus, our work suggests a link between relative mobilities of trace elements in hydrothermal fluids and deep arc magma generation in subduction zones. The experimental results are highly consistent with the proposal that the addition of subduction zone hydrous fluids to the subarc mantle, which has been depleted by previous melting events, can produce the unique characteristics of arc magmas. Moreover, the results suggest that deeply subducted sediments may no longer have the composition necessary to generate

  8. Characteristics of hydrothermal sedimentation process in the Yanchang Formation, south Ordos Basin, China: Evidence from element geochemistry

    NASA Astrophysics Data System (ADS)

    He, Cong; Ji, Liming; Wu, Yuandong; Su, Ao; Zhang, Mingzhen

    2016-11-01

    Hydrothermal sedimentation occurred in the Triassic Yanchang Formation, Ordos Basin, China. However, their macroscopic features at the scale of the stratum and hydrothermal sources still lack correlational research. This paper performed element geochemical study on a large number of core samples collected from the Yanchang Formation of a new drilling well located in the south Ordos Basin. The SiO2/(K2O + Na2O) vs. MnO/TiO2 crossplot and Fe vs. Mn vs. (Cu + Co + Ni) × 10 ternary diagram demonstrate that the Yanchang stratum in the study area has, in general, hydrothermal components. The Al/(Al + Fe + Mn) and (Fe + Mn)/Ti ratios of the core samples range from 0.34 to 0.84 and 4.81 to 50.54, averaging 0.66 and 10.67, respectively, indicating that the stratum is a set of atypical hydrothermal sedimentation with much terrigenous input. Data analysis shows that the hydrothermal source in the study area was from the deep North Qinling Orogen around the south margin of the basin, where some active tectonic and volcanic activities took place, rather than from the relatively stable internal basin. Early Indosinian movement and volcanic activities activated basement faults around the southern margin of the basin, providing vents for the deep hydrothermal fluid upwelling. The hydrothermal indicators suggest that the study area experienced 4 episodes of relatively stronger hydrothermal activity, namely during the Chang 10, Chang 9-1, Chang 7-3 and Chang 6-2 periods. We also propose a new hydrothermal sedimentation model of hydrothermal fluids overflowing from basin margin faults, for the Yanchang Formation, which is reported here for the first time.

  9. Enhanced performance of wearable piezoelectric nanogenerator fabricated by two-step hydrothermal process

    SciTech Connect

    Qiu, Yu; Lei, Jixue; Yin, Bing; Zhang, Heqiu; Ji, Jiuyu; Hu, Lizhong; Bian, Jiming; Liu, Yanhong; Zhao, Yu; Luo, Yingmin

    2014-03-17

    A simple two-step hydrothermal process was proposed for enhancing the performance of the nanogenerator on flexible and wearable terylene-fabric substrate. With this method, a significant enhancement in output voltage of the nanogenerator from ∼10 mV to 7 V was achieved, comparing with the one by conventional one-step process. In addition, another advantage with the devices synthesized by two-step hydrothermal process was that their output voltages are only sensitive to strain rather than strain rate. The devices with a high output voltage have the ability to power common electric devices and will have important applications in flexible electronics and wearable devices.

  10. Catalytic Hydrothermal Gasification

    SciTech Connect

    Elliott, Douglas C.

    2015-05-31

    The term “hydrothermal” used here refers to the processing of biomass in water slurries at elevated temperature and pressure to facilitate the chemical conversion of the organic structures in biomass into useful fuels. The process is meant to provide a means for treating wet biomass materials without drying and to access ionic reaction conditions by maintaining a liquid water processing medium. Typical hydrothermal processing conditions are 523-647K of temperature and operating pressures from 4-22 MPa of pressure. The temperature is sufficient to initiate pyrolytic mechanisms in the biopolymers while the pressure is sufficient to maintain a liquid water processing phase. Hydrothermal gasification is accomplished at the upper end of the process temperature range. It can be considered an extension of the hydrothermal liquefaction mechanisms that begin at the lowest hydrothermal conditions with subsequent decomposition of biopolymer fragments formed in liquefaction to smaller molecules and eventually to gas. Typically, hydrothermal gasification requires an active catalyst to accomplish reasonable rates of gas formation from biomass.

  11. Low-temperature hydrothermal synthesis of BiFeO{sub 3} microcrystals and their visible-light photocatalytic activity

    SciTech Connect

    Wei, Jie; Zhang, Chao; Xu, Zhuo

    2012-11-15

    Highlights: ► Urea-assisted hydrothermal synthesis of pure BiFeO{sub 3} at 120 °C was reported. ► Possible formation mechanism of pure phase BiFeO{sub 3} at low temperature was illuminated. ► BiFeO{sub 3} microcrystals exhibited efficient visible-light photocatalytic activity. -- Abstract: Pure BiFeO{sub 3} (BFO) microcrystals were synthesized at the temperature as low as 120 °C via a urea-assisted hydrothermal process. The crystal structure, morphology and photocatalytic property of BFO microcrystals were investigated. The analysis reveals that the hydrolysis of urea in the hydrothermal process plays a key role in the synthesis of pure phase BFO microcrystals. FE-SEM and TEM results show that these BFO microcrystals present a nearly spherical microstructure, and specially exhibit superstructures consisting of large amounts of small particles with the size of 100–150 nm by further observation. Moreover, these BFO microcrystals exhibit efficient photocatalytic activity under visible-light irradiation, suggesting their promising applications as photocatalysts and related fields.

  12. ESR dating of submarine hydrothermal activities using barite in sulfide deposition

    NASA Astrophysics Data System (ADS)

    Toyoda, S.; Fujiwara, T.; Ishibashi, J.; Isono, Y.; Uchida, A.; Takamasa, A.; Nakai, S.

    2012-12-01

    The temporal change of submarine hydrothermal activities has been an important issue in the aspect of the evolution of hydrothermal systems which is related with ore formation (Urabe, 1995) and biological systems sustained by the chemical species arising from hydrothermal activities (Macdonald et al., 1980). Determining the ages of the hydrothermal deposit will provide essential information on such studies. Dating methods using disequilibrium between radioisotopes such as U-Th method (e.g. You and Bickle, 1998), 226}Ra-{210Pb and 228}Ra-{228Th method (e.g. Noguchi et al., 2011) have been applied to date submarine hydrothermal deposits. ESR (electron spin resonance) dating method is commonly applied to fossil teeth, shells, and quartz of Quaternay period where the natural accumulated dose is obtained from the intensities of the ESR signals which are created by natural radiation. The natural dose is divided by the dose rate to the mineral/sample to deduce the age. Okumura et al., (2010) made the first practical application of ESR (electron spin resonance) dating technique to a sample of submarine hydrothermal barite (BaSO4) to obtain preliminary ages, where Kasuya et al. (1991) first pointed out that barite can be used for ESR dating. Knowing that ESR dating of barite is promising, in this paper, we will present how we have investigated each factor that contributes ESR dating of barite in submarine hydrothermal sulfide deposition. (1) The best ESR condition for measuring the SO3- signal in barite is with the microwave power of 1mW and modulation amplitude of 0.1mT. (2) As results of heating experiments, the signal was found to be stable for the dating age range of several thousands. (3) 226Ra replacing Ba in barite is the source of the radiation. The amount of radioactive elements in sulfide mineral surrounding barite is negligible. (4) The external radiation from the sea water is negligible even in the submarine hydrothermal area where the radiation level is much

  13. Production of monosaccharides from napier grass by hydrothermal process with phosphoric acid.

    PubMed

    Takata, Eri; Tsutsumi, Ken; Tsutsumi, Yuji; Tabata, Kenji

    2013-09-01

    The production of monosaccharides from napier grass was investigated in the presence of acid catalysts using the hydrothermal process. When the napier grass was treated with 3 wt.% phosphoric acid at 160°C for 15min, the xylose yield reached 10.3 wt.%, corresponding to 72.0% of the xylan in it, whereas glucose was hardly obtained. A combined process was then conducted using an 85 wt.% phosphoric acid treatment at 60 °C for 1h followed by a hydrothermal treatment with 3 wt.% phosphoric acid. In the initial treatment with concentrated phosphoric acid the most of xylan was hydrolyzed to xylose, and the crystalline cellulose was converted to its amorphous form. The hydrolysis of cellulose to glucose was significantly enhanced during the following hydrothermal process with 3 wt.% phosphoric acid at 200 °C for 8 min. Consequently, 77.2% yield of xylose and 50.0% yield of glucose were obtained from the combined process.

  14. Facile fabrication of superhydrophobic surfaces on wood substrates via a one-step hydrothermal process

    NASA Astrophysics Data System (ADS)

    Liu, Ming; Qing, Yan; Wu, Yiqiang; Liang, Jin; Luo, Sha

    2015-03-01

    Superhydrophobic nanocomposite surfaces were successfully fabricated on wood substrates via a one-step hydrothermal process. The morphology of the nanocomposite surfaces was characterized using scanning electron microscopy (SEM), and the elemental composition was determined via energy-dispersive X-ray spectrometry (EDS), X-ray diffraction (XRD) analysis, and Fourier transform infrared (FTIR) spectroscopy. The results indicated that the crystallization of the anatase phase of TiO2 was prevented because of the presence of vinyltriethoxysilane [VTES, CH2CHSi(OC2H5)3] during the hydrothermal process. In addition, the nanocomposite contained Ti/Si particles with diameters ranging from 50 to 100 nm that thoroughly covered the wood substrate. Furthermore, the roughness coupled with the presence of low surface free energy groups led to superhydrophobicity; the static water contact angle (WCA) was as high as 153°, and the sliding angle was very low.

  15. Silica nanoparticles as indicator of hydrothermal activities at Enceladus ocean floor

    NASA Astrophysics Data System (ADS)

    Postberg, F.; Hsu, S.; Sekine, Y.; Kempf, S.; Juhasz, A.; Horanyi, M.; Moragas-Klostermeyer, G.; Srama, R.

    2013-12-01

    Silica nanoparticles as indicator of hydrothermal activities at Enceladus ocean floor F. Postberg, H.-W. Hsu, Y. Sekine, S. Kempf, A. Juhasz, M. Horanyi, G. Moragas-Klostermeyer, R. Srama Silica serves as a unique indicator of hydrothermal activities on Earth as well as on Mars. Here we report the Cassini Cosmic Dust Analyser (CDA) observation of nanosilica particles from the Saturnian system. Based on their interaction with the solar wind electromagnetic fields, these charged nanosilica particles, so-called stream particles, are found to be originated in Saturn's E ring, indicating Enceladus being their ultimate source. CDA stream particle mass spectra reveal a metal-free but silicon-rich composition that is only plausible for nearly pure silica particles. The size range derived from our measurements confines the size of these particles to a radius of 2 - 8 nm. The unique properties of nano-grains with the observed composition and size are a well-known phenomenon on Earth and their formation requires specific hydrothermal rock-water interactions. The observation of Saturnian nanosilica particles thus serves as an evidence of hydrothermal activities at the interface of Enceladus subsurface ocean and its rocky core. Considering plasma erosion as the major mechanism of releasing embedded nanosilica particles from their carriers, the much larger E ring ice grains, our dynamical model and CDA observation provide a lower limit on the average nanosilica concentration in E ring grains. Together with dedicated hydrothermal experiments (Sekine at al., 2013) this can be translated into constraints on the hydrothermal activities on Enceladus. Measurements and experiments both point at dissolved silica concentrations at the ocean floor in the order of 1 - 3 mMol. The hydrothermal reactions likely take place with a pristine, chondritic rock composition at temperature higher than 130°C (Sekine at al. 2013). Colloidal nano-silica forms upon supersaturation during cooling of the

  16. Microwave-hydrothermal process for the synthesis of rutile

    SciTech Connect

    Baldassari, Sara; Komarneni, Sridhar . E-mail: komarneni@psu.edu; Mariani, Emilia; Villa, Carla

    2005-11-03

    The synthesis of pure rutile titanium dioxide is not an easy achievement, as the crystallization process generally leads to mixtures of two or even three phases; moreover the synthetic processes normally used by industry require harsh reaction conditions. We carried out the synthesis of titanium dioxide from an aqueous titanium tetrachloride solution under microwave irradiation in the reaction time range of 5-120 min. We mostly obtained mixtures of rutile and anatase, but obtained single-phase rutile after a 2-h treatment at 160 deg. C; transmission electron micrographs revealed well-dispersed spherical nanoparticles. We also investigated the effects of dilution and addition of a dispersant (polyvinylpyrrolidone) on phase crystallization and particle shape.

  17. Cavitational Hydrothermal Oxidation: A New Remediation Process - Final Report

    SciTech Connect

    Suslick, K. S.

    2001-07-05

    During the past year, we have continued to make substantial scientific progress on our understanding of cavitation phenomena in aqueous media and applications of cavitation to remediation processes. Our efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions.

  18. Hydrothermal changes related to earthquake activity at Mud Volcano, Yellowstone National Park, Wyoming

    SciTech Connect

    Pitt, A.M.; Hutchinson, R.A.

    1982-04-10

    The Mud Volcano hydrothermal area in Yellowstone National Park is near the intersection of a 20-km-long zone of northeast trending normal faults with the eastern resurgent dome within the 600,000-year-odd Yellowstone caldera. Recent crustal uplift along the northeast trending axis of the caldera is at a maximum (700 mm since 1923) near the Mud Volcano area. From 1973 through April 1978, less than 10 earthquakes (largest M 2.4) were located within 3 km of the Mud Volcano area. In May 1978, earthquakes began occurring beneath the hydrothermal area at depths of 1 to 5 km. The seismic activity continued until the end of November with intense swarms (100 events per hour) occurring on October 23 and November 7. The largest event (M 3.1) occured on November 14 and at least 8 events were M 2.5 or larger. In December 1978, heat flux in the Mud Volcano hydrothermal features began increasing along a 2-km-long northeast trending zone. Existing mud cauldrons became more active, new mud cauldrons and fumeroles were formed, and vegetation (primarily lodgepole pine) was killed by increased soil temperature. The increase in heat flux continued through July 1979 then gradually declined, reaching the early 1978 level by June 1980. The spatial and temporal association of earthquakes and increased hydrothermal activity at Mud Volcano suggests that the seismic activity expanded preexisting fracture systems, premitting increased fluid flow from depths of several kilometers.

  19. Exploring an active hydrothermal system - An analogue study from the Swiss Alps

    NASA Astrophysics Data System (ADS)

    Egli, Daniel; Herwegh, Marco; Berger, Alfons; Baron, Ludovic

    2016-04-01

    Understanding the detailed flow paths in hydrothermal reservoirs is crucial for successful exploration of naturally porous and permeable rock masses for energy production. However, due to the common inaccessibility of active hydrothermal systems of suitable depth, e.g. in the northern Alpine foreland of the European Alps, direct observations are normally impossible and the knowledge about such systems is still insufficient. For that reason, a known fault-bound hydrothermal system in the crystalline basement of the Aar Massif serves as an analogue for potential geothermal reservoirs in the deep crystalline subsurface of the northern Alpine foreland. During summer 2015, a 125 m hole has been drilled across this active hydrothermal zone on the Grimsel Pass for in-situ characterization of its structural, petrophysical, mechanical as well as geophysical parameters. With this information, this project aims at improving the knowledge of natural hydrothermal systems as a potentially exploitable energy source. The investigated system is characterized by a central breccia zone surrounded by different types of cataclasites and localized high strain zones. The surrounding includes different altered and deformed granitoid host rocks. In this study, we focus on the ductile and brittle deformation (shear zones, fractures, joints) that provides the main fluid pathways. Their spatial distribution around a central water-bearing breccia zone as well as their continuity and permeability provide constraints on the water flow paths in such structurally controlled hydrothermal systems. The aim will be the connection of detailed structural data with petrophysical parameters such as porosities and permeabilities. The drillcore shows the high variability of deformation structures and related fluid pathways at different scales (millimeter-decameter) demonstrating the urgent need for an improved understanding of the link between mechanical evolution, associated deformation structures as well

  20. Optimization of hydrothermal pretreatment of lignocellulosic biomass in the bioethanol production process.

    PubMed

    Nitsos, Christos K; Matis, Konstantinos A; Triantafyllidis, Kostas S

    2013-01-01

    The natural resistance to enzymatic deconstruction exhibited by lignocellulosic materials has designated pretreatment as a key step in the biological conversion of biomass to ethanol. Hydrothermal pretreatment in pure water represents a challenging approach because it is a method with low operational costs and does not involve the use of organic solvents, difficult to handle chemicals, and "external" liquid or solid catalysts. In the present work, a systematic study has been performed to optimize the hydrothermal treatment of lignocellulosic biomass (beech wood) with the aim of maximizing the enzymatic digestibility of cellulose in the treated solids and obtaining a liquid side product that could also be utilized for the production of ethanol or valuable chemicals. Hydrothermal treatment experiments were conducted in a batch-mode, high-pressure reactor under autogeneous pressure at varying temperature (130-220 °C) and time (15-180 min) regimes, and at a liquid-to-solid ratio (LSR) of 15. The intensification of the process was expressed by the severity factor, log R(o). The major changes induced in the solid biomass were the dissolution/removal of hemicellulose to the process liquid and the partial removal and relocation of lignin on the external surface of biomass particles in the form of recondensed droplets. The above structural changes led to a 2.5-fold increase in surface area and total pore volume of the pretreated biomass solids. The enzymatic hydrolysis of cellulose to glucose increased from less than 7 wt% for the parent biomass to as high as 70 wt% for the treated solids. Maximum xylan recovery (60 wt%) in the hydrothermal process liquid was observed at about 80 wt% hemicellulose removal; this was accomplished by moderate treatment severities (log R(o)=3.8-4.1). At higher severities (log R(o)=4.7), xylose degradation products, mainly furfural and formic acid, were the predominant chemicals formed. PMID:23180649

  1. Assessing microbial processes in deep-sea hydrothermal systems by incubation at in situ temperature and pressure

    NASA Astrophysics Data System (ADS)

    McNichol, Jesse; Sylva, Sean P.; Thomas, François; Taylor, Craig D.; Sievert, Stefan M.; Seewald, Jeffrey S.

    2016-09-01

    At deep-sea hydrothermal vents, a large source of potential chemical energy is created when reducing vent fluid and oxidizing seawater mix. In this environment, chemolithoautotrophic microbes catalyze exergonic redox reactions which in turn provide the energy needed to fuel their growth and the fixation of CO2 into biomass. In addition to producing new organic matter, this process also consumes compounds contained both in vent fluid and entrained seawater (e.g. H2, NO3-). Despite their biogeochemical importance, such reactions have remained difficult to quantify due to methodological limitations. To address this knowledge gap, this study reports a novel application of isobaric gas-tight fluid samplers for conducting incubations of hydrothermal vent fluids at in situ temperature and pressure. Eighteen ~24 h incubations were carried out, representing seven distinct conditions that examine amendments consisting of different electron donors and acceptors. Microbial activity was observed in all treatments, and time series chemical measurements showed that activity was limited by electron acceptor supply, confirming predictions based on geochemical data. Also consistent with these predictions, the presence of nitrate increased rates of hydrogen consumption and yielded ammonium as a product of nitrate respiration. The stoichiometry of predicted redox reactions was also determined, revealing that the sulfur and nitrogen cycles are incompletely understood at deep-sea vents, and likely involve unknown intermediate redox species. Finally, the measured rates of redox processes were either equal to or far greater than what has been reported in previous studies where in situ conditions were not maintained. In addition to providing insights into deep-sea hydrothermal vent biogeochemistry, the methods described herein also offer a practical approach for the incubation of any deep-sea pelagic sample under in situ conditions.

  2. Hydrothermal activity in the Northwest Lau Backarc Basin: Evidence from water column measurements

    NASA Astrophysics Data System (ADS)

    Lupton, J. E.; Arculus, R. J.; Resing, J.; Massoth, G. J.; Greene, R. R.; Evans, L. J.; Buck, N.

    2012-05-01

    The Northwest Lau Backarc Basin, consisting of the Northwest Lau Spreading Center (NWLSC) and the Rochambeau Rifts (RR), is unique in having elevated 3He/4He ratios (up to 28 Ra) in the erupted lavas, clearly indicating a hot spot or ocean island basalt (OIB)-type signature. This OIB-type helium signature does not appear in any other part of the Lau Basin. Water column plume surveys conducted in 2008 and 2010 identified several sites of active hydrothermal discharge along the NWLSC-RR and showed that the incidence of hydrothermal activity is high, consistent with the high spreading rate of ˜100 mm/year. Hydrocasts into the Central Caldera and Southern Caldera of the NWLSC detected elevated3He/4He (δ3He = 55% and 100%, respectively), trace metals (TMn, TFe), and suspended particles, indicating localized hydrothermal venting at these two sites. Hydrocasts along the northern rift zone of the NWLSC also had excess δ3He, TMn, and suspended particles suggesting additional sites of hydrothermal activity. The RR are dominated by Lobster Caldera, a large volcano with four radiating rift zones. Hydrocasts into Lobster Caldera in 2008 detected high δ3He (up to 239%) and suspended particle and TMn signals, indicating active venting within the caldera. A repeat survey of Lobster in 2010 confirmed the site was still active two years later. Plumes at Lobster Caldera and Central Caldera have end-member3He/4He ratios of 19 Ra and 11 Ra, respectively, confirming that hot spot-type helium is also present in the hydrothermal fluids.

  3. Preparation of tourmaline nano-particles through a hydrothermal process and its infrared emission properties.

    PubMed

    Xue, Gang; Han, Chao; Liang, Jinsheng; Wang, Saifei; Zhao, Chaoyue

    2014-05-01

    Tourmaline nano-particles were successfully prepared via a hydrothermal process using HCl as an additive. The reaction temperature (T) and the concentration of HCI (C(HCl)) had effects on the size and morphology of the tourmaline nano-particles. The optimum reaction condition was that: T = 180 degrees C and C(HCl) = 0.1 mol/l. The obtained nano-particles were spherical with the diameter of 48 nm. The far-infrared emissivity of the product was 0.923. The formation mechnism of the tourmaline nano-particles might come from the corrosion of grain boundary between the tourmaline crystals in acidic hydrothermal conditions and then the asymmetric contraction of the crystals. PMID:24734669

  4. Preparation of tourmaline nano-particles through a hydrothermal process and its infrared emission properties.

    PubMed

    Xue, Gang; Han, Chao; Liang, Jinsheng; Wang, Saifei; Zhao, Chaoyue

    2014-05-01

    Tourmaline nano-particles were successfully prepared via a hydrothermal process using HCl as an additive. The reaction temperature (T) and the concentration of HCI (C(HCl)) had effects on the size and morphology of the tourmaline nano-particles. The optimum reaction condition was that: T = 180 degrees C and C(HCl) = 0.1 mol/l. The obtained nano-particles were spherical with the diameter of 48 nm. The far-infrared emissivity of the product was 0.923. The formation mechnism of the tourmaline nano-particles might come from the corrosion of grain boundary between the tourmaline crystals in acidic hydrothermal conditions and then the asymmetric contraction of the crystals.

  5. Hydrothermal activity recorded in post Noachian-aged impact craters on Mars

    NASA Astrophysics Data System (ADS)

    Turner, Stuart M. R.; Bridges, John C.; Grebby, Stephen; Ehlmann, Bethany L.

    2016-04-01

    Hydrothermal systems have previously been reported in ancient Noachian and Hesperian-aged craters on Mars using CRISM but not in Amazonian-aged impact craters. However, the nakhlite meteorites do provide evidence of Amazonian hydrothermal activity. This study uses CRISM data of 144 impact craters of ≥7 km diameter and 14 smaller craters (3-7 km diameter) within terrain mapped as Amazonian to search for minerals that may have formed as a result of impact-induced hydrothermal alteration or show excavation of ancient altered crust. No evidence indicating the presence of hydrated minerals was found in the 3-7 km impact craters. Hydrated minerals were identified in three complex impact craters, located at 52.42°N, 39.86°E in the Ismenius Lacus quadrangle, at 8.93°N, 141.28°E in Elysium, and within the previously studied Stokes crater. These three craters have diameters 20 km, 62 km, and 51 km. The locations of the hydrated mineral outcrops and their associated morphology indicate that two of these three impact craters—the unnamed Ismenius Lacus Crater and Stokes Crater—possibly hosted impact-induced hydrothermal systems, as they contain alteration assemblages on their central uplifts that are not apparent in their ejecta. Chlorite and Fe serpentine are identified within alluvial fans in the central uplift and rim of the Ismenius Lacus crater, whereas Stokes crater contains a host of Fe/Mg/Al phyllosilicates. However, excavation origin cannot be precluded. Our work suggests that impact-induced hydrothermalism was rare in the Amazonian and/or that impact-induced hydrothermal alteration was not sufficiently pervasive or spatially widespread for detection by CRISM.

  6. Advanced Seismic Studies of the Endeavour Ridge: Understanding the Interplay among Magmatic, Hydrothermal, and Tectonic Processes at Mid-Ocean Ridges

    NASA Astrophysics Data System (ADS)

    Arnoux, G. M.; VanderBeek, B. P.; Morgan, J. V.; Hooft, E. E. E.; Toomey, D. R.; Wilcock, W. S. D.; Warner, M.

    2014-12-01

    At mid-ocean ridges magmatic, hydrothermal, and tectonic processes are linked. Understanding their interactions requires mapping magmatic systems and tectonic structures, as well as their relationship to hydrothermal circulation. Three-dimensional seismic images of the crust can be used to infer the size, shape, and location of magma reservoirs, in addition to the structure of the thermal boundary layer that connects magmatic and hydrothermal processes. Travel time tomography has often been used to study these processes, however, the spatial resolution of travel time tomography is limited. Three-dimensional full waveform inversion (FWI) is a state-of-the art seismic method developed for use in the oil industry to obtain high-resolution models of the velocity structure. The primary advantage of FWI is that it has the potential to resolve subsurface structures on the order of half the seismic wavelength—a significant improvement on conventional travel time tomography. Here, we apply anisotropic FWI to data collected on the Endeavour segment of the Juan de Fuca Ridge. Starting models for anisotropic P-wave velocity were obtained by travel time tomography [Weekly et al., 2014]. During FWI, the isotropic velocity model is updated and anisotropy is held constant. We have recovered low-velocity zones approximately 2-3 km beneath the ridge axis that likely correspond to a segmented magma-rich body and are in concert with those previously resolved using multi-channel seismic reflection methods. The segmented crustal magma body underlies all five known high-temperature hydrothermal vent fields along the Endeavour segment. A high-velocity zone, shallower than the observed low-velocity zones, underlies the southernmost hydrothermal vent field. This may be indicative of waning hydrothermal activity in which minerals are crystallizing beneath the vent field. Our FWI study of the Endeavour Ridge will provide the most detailed three-dimensional images of the crustal structure to

  7. Plume indications from hydrothermal activity on Kawio Barat Submarine Volcano, Sangihe Talaud Sea, North Sulawesi, Indonesia

    NASA Astrophysics Data System (ADS)

    Makarim, S.; Baker, E. T.; Walker, S. L.; Wirasantosa, S.; Permana, H.; Sulistiyo, B.; Shank, T. M.; Holden, J. F.; Butterfield, D.; Ramdhan, M.; Adi, R.; Marzuki, M. I.

    2010-12-01

    Kawio Barat submarine volcano has formed in response to the active tectonic conditions in Sangihe Talaud, an area that lies in the subduction zone between the Molucca Sea Plate and Celebes Sea Plate. Submarine volcanic activity in the western Sangihe volcanic arc is controlled by the west-dipping Molucca Sea Plate as it subducts beneath the Sangihe Arc. A secondary faulting system on Kawio Barat is in a northwest - southeast direction, and creates a network of deep cracks that facilitate hydrothermal discharge in this area. Hydrothermal activity on Kawio Barat was first discovered by joint Indonesia/Australian cruises in 2003. In 2010, as part of the joint US/Indonesian INDEX-SATAL expedition, we conducted CTD casts that confirmed continuing activity. Hydrothermal plumes were detected by light -scattering (LSS) and oxidation-reduction potential (ORP) sensors on the CTD package. LSS anomalies were found between 1600-1900 m, with delta NTU levels of 0.020-0.040. ORP anomalies coincident with the LSS anomalies indicate strong concentrations of reduced species such as H2S and Fe, confirming the hydrothermal origin of the plumes. Images of hydrothermal vents on Kawio Barat Submarine volcano, recorded by high- definition underwater cameras on the ROV “Little Hercules” operated from the NOAA ship Okeanos Explorer, confirmed the presence and sources of the detected vent plumes in the northern and southwest part of the summit in 1800-1900 m depth. In southwest part of this summit chimney, drips of molten sulfur were observed in the proximity of microbal staining.

  8. Metagenome and Metatranscriptome Revealed a Highly Active and Intensive Sulfur Cycle in an Oil-Immersed Hydrothermal Chimney in Guaymas Basin.

    PubMed

    He, Ying; Feng, Xiaoyuan; Fang, Jing; Zhang, Yu; Xiao, Xiang

    2015-01-01

    The hydrothermal vent system is a typical chemosynthetic ecosystem in which microorganisms play essential roles in the geobiochemical cycling. Although it has been well-recognized that the inorganic sulfur compounds are abundant and actively converted through chemosynthetic pathways, the sulfur budget in a hydrothermal vent is poorly characterized due to the complexity of microbial sulfur cycling resulting from the numerous parties involved in the processes. In this study, we performed an integrated metagenomic and metatranscriptomic analysis on a chimney sample from Guaymas Basin to achieve a comprehensive study of each sulfur metabolic pathway and its hosting microorganisms and constructed the microbial sulfur cycle that occurs in the site. Our results clearly illustrated the stratified sulfur oxidation and sulfate reduction at the chimney wall. Besides, sulfur metabolizing is closely interacting with carbon cycles, especially the hydrocarbon degradation process in Guaymas Basin. This work supports that the internal sulfur cycling is intensive and the net sulfur budget is low in the hydrothermal ecosystem.

  9. Submarine Hydrothermal Activity on the Aeolian Arc: New Evidence from Helium Isotopes

    NASA Astrophysics Data System (ADS)

    Lupton, J.; de Ronde, C.; Baker, E.; Sprovieri, M.; Bruno, P.; Italiano, F.; Walker, S.; Faure, K.; Leybourne, M.; Britten, K.; Greene, R.

    2008-12-01

    In November 2007 we conducted a water-column and seafloor mapping study of the submarine volcanoes of the Aeolian Arc in the southern Tyrrhenian Sea aboard the R/V Urania. A total of 26 CTD casts were completed, 13 vertical casts and 13 tows. In addition to in situ measurements of temperature, conductivity, pressure and suspended particles, we also collected discrete samples for helium isotopes, methane, and trace metals. The helium isotope ratio, which is known to be an unambiguous indicator of hydrothermal input, showed a clear excess above background at 5 out of the 10 submarine volcanoes surveyed. We found the strongest helium anomaly over Marsili seamount, where the 3He/4He ratio reached maximum values of δ3He = 23% at 610 m depth compared with background values of ~7%. We also found smaller but distinct δ3He anomalies over Enerato, Eolo, Palinuro, and Secca del Capo. We interpret these results as indicating the presence of hydrothermal activity on these 5 seamounts. Hydrothermal venting has been documented at subsea vents offshore of the islands of Panarea, Stromboli, and Vulcano (Dando et al., 1999; Di Roberto et al., 2008), and hydrothermal deposits have been sampled on many of the submarine volcanoes of the Aeolian Arc (Dekov and Savelli, 2004). However, as far as we know this is the first evidence of present day hydrothermal activity on Marsili, Enerato, and Eolo. Samples collected over Filicudi, Glabro, Lamentini, Sisifo, and Alcioni had δ3He very close to the regional background values, suggesting either absence of or very weak hydrothermal activity on these seamounts. Helium isotope measurements from the background hydrocasts positioned between the volcanoes revealed the presence of an excess in 3He throughout the SE Tyrrhenian Sea. These background profiles reach a consistent maximum of about δ3He = 11% at 2300 m depth. Historical helium profiles collected in the central and northern Tyrrhenian Sea in 1987 and 1997 do not show this deep 3He

  10. Mineralogy, paragenesis and textures associated with metasomatic- hydrothermal processes, Qatruyeh area, Sanandaj- Sirjan zone, SW Iran

    NASA Astrophysics Data System (ADS)

    Asadi, S.; Rajabzadeh, M. A.

    2009-04-01

    The Qatruyeh area is located at about 40 Km northeastern of Neyriz region, in the eastern edge of the high P- Low T metamorphic Zagros orogenic belt. The studied area principally includes outcrops of green schist facies metamorphic rocks that are thrusted over the Neotethyan ophiolites. Hydrothermal activities occurred episodically in the Mesozoic era . The textural relationships, mineral assemblages and X- Ray diffractions have recognized two different stages of hydrothermal alteration during mineralization. The Mineralization was largely controlled by striking faults and host rock layers. Three different types of magnetite are distinguished in microscopic investigation. The First is euhedral to subhedral, partly replacement by martite with exsolved ilmenites. The Second reveals myrmekite like textures and the last type includes layered magnetite. All of the types are related to replacement textures such as psedomorphism, widening of a fracture filling, irregulare or vermicular intergrowths, islands of unreplaced host rock, cusp or caries, nonmatching walls or borders of a fracture and rims of one mineral penetrating another along its crystallographic direction. X- Ray analyses indicate oxide minerals (Magnetite, Hematite, Maghemite, Specularite, Goethite, Limonite and Ilmenite), Silicate minerals (Tourmaline-shorl and dravite-, Epidote, Chlorite, Actinolite, Titanite, Paragonite, Talc, Muscovite and Quartz), Carbonate minerals (Siderite and Malachite) and Sulfide minerals (Pyrite and Chalcopyrite-minor-) as major phases. The mineral paragenesis and textures show two different stages of metasomatic- hydrothermal alteration. The first stage alteration (Sodic- Calsic) accompanying with mineral paragenesis of Magnetite+ Tourmaline+ Titanite+ Paragonite and the second stage of alteration (Solfidation- Oxidation) follows with Magnetite+ Hematite+ Quartz

  11. Highly effective removal of Methylene Blue using functionalized attapulgite via hydrothermal process.

    PubMed

    Zhang, Zhifang; Wang, Wenbo; Wang, Aiqin

    2015-07-01

    Attapulgite (APT) has been frequently used for the adsorptive removal of dyes from aqueous solution owing to its unique one-dimensional nanoscale structure and low-cost, abundant, eco-friendly advantages. In this work, APT was functionalized under mild hydrothermal condition using chloroacetic acid (CA) with COOH functional groups to improve its adsorption properties. The effect of hydrothermal modification on the microstructure and physicochemical features of APT was investigated by Fourier transform infrared spectroscopy, X-ray diffraction and Field-emission scanning electron microscopy analyses. The effects of hydrothermal reaction parameters on the adsorption properties of modified APT were intensively investigated. It was revealed that the rearrangement of crystal structure and the surface functionalization of APT with COOH groups cause the surprising increase of adsorption capability for Methylene Blue (MB). The removal ratio of raw APT for MB is only 59.52%, while modified APT could almost completely remove MB in the 200 mg/L of MB solution with a removal ratio of 99.8%. The adsorption kinetics fitted pseudo second-order kinetic model, and the adsorption isotherm could be described with Langmuir isotherm model very well. The hydrogen-bonding interaction, electrostatic attraction and chemical association are the main driving force for the adsorption process.

  12. Hydrothermal and tectonic processes recorded in fault rocks from the upper oceanic crust

    NASA Astrophysics Data System (ADS)

    Browne, C. M.; Hayman, N. W.

    2011-12-01

    Faulting and fracturing along mid-ocean ridges play a crucial role in hydrothermal systems and the mechanical behavior of the oceanic crust. Fault and fracture systems resulting from explosive hydrothermal events may differ in permeability and mechanical strength from those that accommodate axial extension. To explore the potential differences, images and samples have been investigated from a range of spreading environments, including the Hess and Pito Deep rifts in East Pacific Rise-spread crust, the SMARK area (22°N) on the Mid Atlantic Ridge, the Troodos Ophiolite, and the Icelandic rift system. These exposures of lavas and dikes contain fault-zone units with contrasting lithologic and mechanical properties and geochemical compositions. To further understand the deformation mechanisms of ocean crustal faulting, image analysis of the fault-zone units from micro- to meso-scales provides a quantitative assessment of grain size, orientation, and fracture density. A key measure is the Particle Size Distribution (PSD), found in continental fault rocks to be a power-law probability function distribution reflecting incremental grain fracture. However, the PSDs of ocean crustal fault rocks are not power law, suggesting a departure from continental fault-zone deformation patterns. Controls on PSD in ocean crustal fault rocks include the initial fracture development in otherwise massive basalts, importance of fluid-rock interaction, and distinctive tectonic strain and stress conditions for seafloor spreading. Here it is further suggested that structures resulting from intense hydrothermal activity may result from different brittle deformation mechanisms (and thereby have different PSDs and SPOs) than those resulting from dominantly tectonic strain. Identifying these different mechanisms of ocean crustal fault-zone deformation establishes length scales, grain-scale deformation mechanisms, the geologic record of fluid-rock interaction, and could lead to in situ constraints

  13. System and process for efficient separation of biocrudes and water in a hydrothermal liquefaction system

    DOEpatents

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Oyler, James R.; Rotness, Jr, Leslie J.; Schmidt, Andrew J.; Zacher, Alan H.

    2016-08-02

    A system and process are described for clean separation of biocrudes and water by-products from hydrothermal liquefaction (HTL) product mixtures of organic and biomass-containing feedstocks at elevated temperatures and pressures. Inorganic compound solids are removed prior to separation of biocrude and water by-product fractions to minimize formation of emulsions that impede separation. Separation may be performed at higher temperatures that reduce heat loss and need to cool product mixtures to ambient. The present invention thus achieves separation efficiencies not achieved in conventional HTL processing.

  14. Microwave-assisted hydrothermal synthesis of Cu/Cu2O hollow spheres with enhanced photocatalytic and gas sensing activities at room temperature.

    PubMed

    Zou, Xinwei; Fan, Huiqing; Tian, Yuming; Zhang, Mingang; Yan, Xiaoyan

    2015-05-01

    Cu/Cu2O nano-heterostructure hollow spheres with a submicron diameter (200-500 nm) were prepared by a microwave-assisted hydrothermal method using Cu(OAc)2·H2O, PVP and ascorbic acid solution as the precursors. The morphology of the products could evolve with the hydrothermal time from solid spheres to thick-shell hollow spheres, then to thin-shell hollow spheres, and finally to nanoparticles. Moreover, the content of Cu in the products could be controlled by adjusting the hydrothermal time. The spontaneous forming of the hollow structure spheres was found to result from the Ostwald ripening effect during the low temperature (100 °C) hydrothermal reaction process. The photocatalytic degradation activities on MO under visible-light irradiation and the gas sensing activities toward the oxidizing NO2 gas of different Cu/Cu2O nano-heterostructure hollow spheres were investigated. As a result, the Cu/Cu2O nano-heterostructure hollow spheres obtained at the hydrothermal time of 30 min, with a rough/porous thin-shell structure and a Cu content of about 10.5 wt%, exhibited the best photocatalytic and gas sensing performances compared with others.

  15. Antimicrobial Activity of Marine Bacterial Symbionts Retrieved from Shallow Water Hydrothermal Vents.

    PubMed

    Eythorsdottir, Arnheidur; Omarsdottir, Sesselja; Einarsson, Hjorleifur

    2016-06-01

    Marine sponges and other sessile macro-organisms were collected at a shallow water hydrothermal site in Eyjafjörður, Iceland. Bacteria were isolated from the organisms using selective media for actinomycetes, and the isolates were screened for antimicrobial activity. A total of 111 isolates revealed antimicrobial activity displaying different antimicrobial patterns which indicates production of various compounds. Known test strains were grown in the presence of ethyl acetate extracts from one selected isolate, and a clear growth inhibition of Staphylococcus aureus was observed down to 0.1 % extract concentration in the medium. Identification of isolates shows different species of Actinobacteria with Streptomyces sp. playing the largest role, but also members of Bacilli, Alphaproteobacteria and Gammaproteobacteria. Sponges have an excellent record regarding production of bioactive compounds, often involving microbial symbionts. At the hydrothermal vents, however, the majority of active isolates originated from other invertebrates such as sea anemones or algae. The results indicate that antimicrobial assays involving isolates in full growth can detect activity not visible by other methods. The macro-organisms inhabiting the Eyjafjörður hydrothermal vent area host diverse microbial species in the phylum Actinobacteria with antimicrobial activity, and the compounds responsible for the activity will be subject to further research. PMID:27147438

  16. Antimicrobial Activity of Marine Bacterial Symbionts Retrieved from Shallow Water Hydrothermal Vents.

    PubMed

    Eythorsdottir, Arnheidur; Omarsdottir, Sesselja; Einarsson, Hjorleifur

    2016-06-01

    Marine sponges and other sessile macro-organisms were collected at a shallow water hydrothermal site in Eyjafjörður, Iceland. Bacteria were isolated from the organisms using selective media for actinomycetes, and the isolates were screened for antimicrobial activity. A total of 111 isolates revealed antimicrobial activity displaying different antimicrobial patterns which indicates production of various compounds. Known test strains were grown in the presence of ethyl acetate extracts from one selected isolate, and a clear growth inhibition of Staphylococcus aureus was observed down to 0.1 % extract concentration in the medium. Identification of isolates shows different species of Actinobacteria with Streptomyces sp. playing the largest role, but also members of Bacilli, Alphaproteobacteria and Gammaproteobacteria. Sponges have an excellent record regarding production of bioactive compounds, often involving microbial symbionts. At the hydrothermal vents, however, the majority of active isolates originated from other invertebrates such as sea anemones or algae. The results indicate that antimicrobial assays involving isolates in full growth can detect activity not visible by other methods. The macro-organisms inhabiting the Eyjafjörður hydrothermal vent area host diverse microbial species in the phylum Actinobacteria with antimicrobial activity, and the compounds responsible for the activity will be subject to further research.

  17. Lake-floor sediment texture and composition of a hydrothermally-active, volcanic lake, Lake Rotomahana

    NASA Astrophysics Data System (ADS)

    Pittari, A.; Muir, S. L.; Hendy, C. H.

    2016-03-01

    Young volcanic lakes undergo a transition from rapid, post-eruptive accumulation of volcaniclastic sediment to slower pelagic settling under stable lake conditions, and may also be influenced by sublacustrine hydrothermal systems. Lake Rotomahana is a young (129 year-old), hydrothermally-active, volcanic lake formed after the 1886 Tarawera eruption, and provides a unique insight into the early evolution of volcanic lake systems. Lake-bottom sediment cores, 20-46 cm in length, were taken along a transect across the lake and characterised with respect to stratigraphy, facies characteristics (i.e., grain size, componentry) and pore water silica concentrations. The sediments generally comprise two widespread facies: (i) a lower facies of light grey to grey, very fine lacustrine silt derived from the unconsolidated pyroclastic deposits that mantled the catchment area immediately after the eruption, which were rapidly reworked and redeposited into the lake basin; and (ii) an upper facies of dark, fine-sandy diatomaceous silt, that settled from the pelagic zone of the physically stable lake. Adjacent to sublacustrine hydrothermal vents, the upper dark facies is absent, and the upper part of the light grey to grey silt is replaced by a third localised facies comprised of hydrothermally altered pale yellow to yellowish brown, laminated silt with surface iron-rich encrustations. Microspheres, which are thought to be composed of amorphous silica, although some may be halloysite, have precipitated from pore water onto sediment grains, and are associated with a decrease in pore water silicon concentration. Lake Rotomahana is an example of a recently-stabilised volcanic lake, with respect to sedimentation, that shows signs of early sediment silicification in the presence of hydrothermal activity.

  18. Anomalous quartz from the Roter Kamm impact crater, Namibia - Evidence for post-impact hydrothermal activity?

    NASA Technical Reports Server (NTRS)

    Koeberl, Christian; Fredriksson, Kurt; Goetzinger, Michael; Reimold, Wolf Uwe

    1989-01-01

    Quartz pebbles from the Roter Kamm impact crater (the Namib Desert, SWA/Namibia) were examined for evidence of impact-induced hydrothermal activity, using results from microprobe analyses, neutron activation analyses, transmission IR spectroscopy, and X-ray diffractometry. It was found that the pebbles consisted of pure quartz, which contains three different types of fluid inclusions. These were identified as primary inclusions (5-10 microns) that record the formation conditions of the quartz, very small (less than 1 micron) secondary inclusions associated with the grain boundaries, and late inclusions of irregular size. It is concluded that the quartz and the primary inclusions may provide evidence for a postimpact phase of extensive hydrothermal activity, generated by the residual heat from the kinetic energy of the impact.

  19. East Pacific rise at 21°N: the volcanic, tectonic, and hydrothermal processes of the central axis

    USGS Publications Warehouse

    Ballard, Richard D.; Francheteau, Jean; Juteau, Tierre; Rangan, Claude; Normark, William

    1981-01-01

    Photographs obtained by the ANGUS survey system at 21°N reveal many similarities to the geological processes delineated at other spreading centers and in particular those observed in the Galapagos Rift at 86°W. The region of recent volcanism is restricted to a narrow zone (Zone 1) approximately 1 km wide. This suggests that the width of the magma chamber feeding these flows is also narrow at the top. Variations in sediment cover are used to subdivide the flows within Zone 1 into three sheet-flow/pillow-flow pairs. The youngest pair appears to have erupted form a linear fissure 8 km long running parallel to the valley axis. This fissure is part of a larger en echelon pattern of eruptive fissures. Active hydrothermal vents associated with the youngest flows are situated directly above the apparent eruptive fissure. The high (350°C) temperature for some of the fluids exiting from the vents suggests a highly restricted circulation system involving, at times, little to no mixing with cold seawater. The lava terrain in the remainder of Zone 1 and bordering regions is characterized by extensive fracturing, further suggesting a narrow upper dimension to the magma chamber and also that subsurface hydrothermal deposition of massive sulfides may lead to a reduction in the mixing processes.

  20. Hydrothermal Synthesis and Processing of Barium Titanate Nanoparticles Embedded in Polymer Films.

    PubMed

    Toomey, Michael D; Gao, Kai; Mendis, Gamini P; Slamovich, Elliott B; Howarter, John A

    2015-12-30

    Barium titanate nanoparticles embedded in flexible polymer films were synthesized using hydrothermal processing methods. The resulting films were characterized with respect to material composition, size distribution of nanoparticles, and spatial location of particles within the polymer film. Synthesis conditions were varied based on the mechanical properties of the polymer films, ratio of polymer to barium titanate precursors, and length of aging time between initial formulations of the solution to final processing of nanoparticles. Block copolymers of poly(styrene-co-maleic anhydride) (SMAh) were used to spatially separate titanium precursors based on specific chemical interactions with the maleic anhydride moiety. However, the glassy nature of this copolymer restricted mobility of the titanium precursors during hydrothermal processing. The addition of rubbery butadiene moieties, through mixing of the SMAh with poly(styrene-butadiene-styrene) (SBS) copolymer, increased the nanoparticle dispersion as a result of greater diffusivity of the titanium precursor via higher mobility of the polymer matrix. Additionally, an aminosilane was used as a means to retard cross-linking in polymer-metalorganic solutions, as the titanium precursor molecules were shown to react and form networks prior to hydrothermal processing. By adding small amounts of competing aminosilane, excessive cross-linking was prevented without significantly impacting the quality and composition of the final barium titanate nanoparticles. X-ray diffraction and X-ray photoelectron spectroscopy were used to verify nanoparticle compositions. Particle sizes within the polymer films were measured to be 108 ± 5 nm, 100 ± 6 nm, and 60 ± 5 nm under different synthetic conditions using electron microscopy. Flexibility of the films was assessed through measurement of the glass transition temperature using dynamic mechanical analysis. Dielectric permittivity was measured using an impedance analyzer.

  1. Significant role of climatic trends on hydrothermal activity Coso Hot Springs, California

    SciTech Connect

    Lofgren, B.E. )

    1990-05-01

    The hydrothermal features of Coso Hot Springs have attracted visitors for 130 yr and scientific investigators for two decades. In 1978, anticipating effects of major geothermal developments nearby, the Naval Weapons Center (NWC) initiated a comprehensive monitoring program at a dozen hydrothermal sites in the Coso Hot Springs area. Nine years of monitoring preceded power production in the nearby Coso geothermal field in July 1987. During this period, steam was rising from numerous vents and gently boiling mud pots. Local rainfall caused increased boiling activity in several mud pots, with some overflowing during wet periods. Then in August 1988, a year after geothermal power production began major changes in hot spring activity commenced. Small mud pots and steamers started to grow and coalesce. In March 1989, mud-pot activity became more violent. Many buried wells failed causing surface activity in other areas to diminish. During ensuing months, large mud cones developed and much of the steam and boiling water occurred in a few major pots. Because the abrupt changes in hydrothermal activity followed so closely after nearby geothermal production began, the obvious cause has been attributed to geothermal developments. Studies of NWC baseline monitoring data indicate, however, that no effects of geothermal developments have been felt in the hot springs area. Rainfall and barometric effects account for most of the fluctuations in records of the past decade. Early accounts and field evidence suggest similar changes have occurred in the past.

  2. Hydrothermal-Assisted Cold Sintering Process: A New Guidance for Low-Temperature Ceramic Sintering.

    PubMed

    Guo, Hanzheng; Guo, Jing; Baker, Amanda; Randall, Clive A

    2016-08-17

    Sintering is a thermal treatment process that is generally applied to achieve dense bulk solids from particulate materials below the melting temperature. Conventional sintering of polycrystalline ceramics is prevalently performed at quite high temperatures, normally up to 1000 to 1200 °C for most ceramic materials, typically 50% to 75% of the melting temperatures. Here we present a new sintering route to achieve dense ceramics at extraordinarily low temperatures. This method is basically modified from the cold sintering process (CSP) we developed very recently by specifically incorporating the hydrothermal precursor solutions into the particles. BaTiO3 nano polycrystalline ceramics are exemplified for demonstration due to their technological importance and normally high processing temperature under conventional sintering routes. The presented technique could also be extended to a much broader range of material systems than previously demonstrated via a hydrothermal synthesis using water or volatile solutions. Such a methodology is of significant importance, because it provides a chemical roadmap for cost-effective inorganic processing that can enable broad practical applications. PMID:27468626

  3. Process Development for Hydrothermal Liquefaction of Algae Feedstocks in a Continuous-Flow Reactor

    SciTech Connect

    Elliott, Douglas C.; Hart, Todd R.; Schmidt, Andrew J.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.; Albrecht, Karl O.; Hallen, Richard T.; Holladay, Johnathan E.

    2013-10-01

    Wet algae slurries can be converted into an upgradeable biocrude by hydrothermal liquefaction (HTL). High levels of carbon conversion to gravity-separable biocrude product were accomplished at relatively low temperature (350 °C) in a continuous-flow, pressurized (sub-critical liquid water) environment (20 MPa). As opposed to earlier work in batch reactors reported by others, direct oil recovery was achieved without the use of a solvent and biomass trace components were removed by processing steps so that they did not cause process difficulties. High conversions were obtained even with high slurry concentrations of up to 35 wt% of dry solids. Catalytic hydrotreating was effectively applied for hydrodeoxygenation, hydrodenitrogenation, and hydrodesulfurization of the biocrude to form liquid hydrocarbon fuel. Catalytic hydrothermal gasification was effectively applied for HTL byproduct water cleanup and fuel gas production from water soluble organics, allowing the water to be considered for recycle of nutrients to the algae growth ponds. As a result, high conversion of algae to liquid hydrocarbon and gas products was found with low levels of organic contamination in the byproduct water. All three process steps were accomplished in bench-scale, continuous-flow reactor systems such that design data for process scale-up was generated.

  4. Hg Isotopic Compositions of Chimneys and Pelagic Sediments at Active Submarine Hydrothermal Field in the Okinawa Trough, Japan

    NASA Astrophysics Data System (ADS)

    Takeuchi, A.; Marumo, K.; Tomiyasu, T.; Yamamoto, M.; Komuro, K.

    2012-12-01

    Mercury (Hg) is a globally distributed and highly toxic pollutant in the environment. It is known that a submarine hydrothermal activity is one of the natural processes to emit Hg to marine environment. In order to estimate the degree to which the Hg found in the marine environment is from anthropogenic versus natural sources, it is important to characterize the Hg from the hydrothermal vents. Samples of chimneys and a ~20 cm sediment core, collected by a deep-sea remotely operated vehicle, from Iheya North hydrothermal field in Okinawa Trough, Japan, were analyzed for Hg concentrations and Hg isotopic compositions. Total Hg concentrations of chimneys range between 8.2 and 16.9 mg/kg, whereas seafloor sediment total Hg concentrations are from 3.8 to 34.8 mg/kg. Approximately 0.4 to 1.1 μg/kg of monomethyl Hg (MMHg) was detected in the top 6 cm sediment cores. Hg isotopic compositions (δ202Hg) of chimneys are between -0.30 and -0.96 ‰, whereas δ202Hg values of sediment samples range from -0.85 to -1.60 ‰. Neither chimneys nor sediment samples exhibit the significant mass independent fractionations in Hg isotopes (Δ201Hg > ± 0.10). The chimney δ202Hg values are slightly higher than the δ202Hg values of sediments. This may indicate that the heavier Hg isotopes tend to be incorporated with mercury-bearing sulfides in chimneys, and the lighter isotopes tend to be remained in the hydrothermal fluid and distributed in the surrounding sediments. Also, the sediment samples from the upper portion of cores demonstrate approximately 0.4 - 0.5 ‰ lower δ202Hg values than those from the lower part. This isotopic fractionation may be resulted from a demethylated process of MMHg by microbes. Several studies have previously demonstrated the rapid demethylation of MMHg by microbes in Hg-contaminated aquatic sediments, and range of the isotopic fractionation is similar to that of the experimentally determined isotopic fractionation of MMHg by bacterial reduction

  5. Hydrothermal activity along the slow-spreading Lucky Strike ridge segment (Mid-Atlantic Ridge): Distribution, heatflux, and geological controls

    NASA Astrophysics Data System (ADS)

    Escartin, J.; Barreyre, T.; Cannat, M.; Garcia, R.; Gracias, N.; Deschamps, A.; Salocchi, A.; Sarradin, P.-M.; Ballu, V.

    2015-12-01

    We have reviewed available visual information from the seafloor, and recently acquired microbathymetry for several traverses across the Lucky Strike segment, to evaluate the distribution of hydrothermal activity. We have identified a new on-axis site with diffuse flow, Ewan, and an active vent structure ∼1.2 km from the axis, Capelinhos. These sites are minor relative to the Main field, and our total heatflux estimate for all active sites (200-1200 MW) is only slightly higher than previously published estimates. We also identify fossil sites W of the main Lucky Strike field. A circular feature ∼200 m in diameter located on the flanks of a rifted off-axis central volcano is likely a large and inactive hydrothermal edifice, named Grunnus. We find no indicator of focused hydrothermal activity elsewhere along the segment, suggesting that the enhanced melt supply and the associated melt lenses, required to form central volcanoes, also sustain hydrothermal circulation to form and maintain large and long-lived hydrothermal fields. Hydrothermal discharge to the seafloor occurs along fault traces, suggesting focusing of hydrothermal circulation in the shallow crust along permeable fault zones.

  6. Seafloor hydrothermal activity and spreading rates: the Eocene carbon dioxide greenhouse revisted.

    PubMed

    Kasting, J F; Richardson, S M

    1985-01-01

    A suggestion has been made that enhanced rates of hydrothermal activity during the Eocene could have caused a global warming by adding calcium to the ocean and pumping CO2 into the atmosphere (Owen and Rea, 1984). This phenomenon was purported to be consistent with the predictions of the CO2 geochemical cycle model of Berner, Lasaga and Garrels (1983) (henceforth BLAG). In fact, however, the BLAG model predicts only a weak connection between hydrothermal activity and atmospheric CO2 levels. By contrast, it predicts a strong correlation between seafloor spreading rates and pCO2, since the release rate of CO2 from carbonate metamorphism is assumed to be proportional to the mean spreading rate. The Ecocene warming can be conveniently explained if the BLAG model is extended by assuming that the rate of carbonate metamorphism is also proportional to the total length of the midocean ridges from which the spreading originates.

  7. Seafloor hydrothermal activity and spreading rates: the Eocene carbon dioxide greenhouse revisted

    NASA Technical Reports Server (NTRS)

    Kasting, J. F.; Richardson, S. M.

    1985-01-01

    A suggestion has been made that enhanced rates of hydrothermal activity during the Eocene could have caused a global warming by adding calcium to the ocean and pumping CO2 into the atmosphere (Owen and Rea, 1984). This phenomenon was purported to be consistent with the predictions of the CO2 geochemical cycle model of Berner, Lasaga and Garrels (1983) (henceforth BLAG). In fact, however, the BLAG model predicts only a weak connection between hydrothermal activity and atmospheric CO2 levels. By contrast, it predicts a strong correlation between seafloor spreading rates and pCO2, since the release rate of CO2 from carbonate metamorphism is assumed to be proportional to the mean spreading rate. The Ecocene warming can be conveniently explained if the BLAG model is extended by assuming that the rate of carbonate metamorphism is also proportional to the total length of the midocean ridges from which the spreading originates.

  8. Seafloor hydrothermal activity and spreading rates - The Eocene carbon dioxide greenhouse revisited

    NASA Technical Reports Server (NTRS)

    Kasting, J. F.; Richardson, S. M.

    1985-01-01

    A suggestion has been made that enhanced rates of hydrothermal activity during the Eocene could have caused a global warming by adding calcium to the ocean and pumping CO2 into the atmosphere (Owen and Rea, 1984). This phenomenon was purported to be consistent with the predictions of the CO2 geochemical cycle model of Berner, Lasaga and Garrels (1983) (henceforth BLAG). In fact, however, the BLAG model predicts only a weak connection between hydrothermal activity and atmospheric CO2 levels. By contrast, it predicts a strong correlation between seafloor spreading rates and pCO2, since the release rate of CO2 from carbonate metamorphism is assumed to be proportional to the mean spreading rate. The Eocene warming can be conveniently explained if the BLAG model is extended by assuming that the rate of carbonate metamorphism is also proportional to the total length of the midocean ridges from which the spreading originates.

  9. Seafloor hydrothermal activity and spreading rates: the Eocene carbon dioxide greenhouse revisted.

    PubMed

    Kasting, J F; Richardson, S M

    1985-01-01

    A suggestion has been made that enhanced rates of hydrothermal activity during the Eocene could have caused a global warming by adding calcium to the ocean and pumping CO2 into the atmosphere (Owen and Rea, 1984). This phenomenon was purported to be consistent with the predictions of the CO2 geochemical cycle model of Berner, Lasaga and Garrels (1983) (henceforth BLAG). In fact, however, the BLAG model predicts only a weak connection between hydrothermal activity and atmospheric CO2 levels. By contrast, it predicts a strong correlation between seafloor spreading rates and pCO2, since the release rate of CO2 from carbonate metamorphism is assumed to be proportional to the mean spreading rate. The Ecocene warming can be conveniently explained if the BLAG model is extended by assuming that the rate of carbonate metamorphism is also proportional to the total length of the midocean ridges from which the spreading originates. PMID:11539654

  10. CONDENSED MATTER: STRUCTURE, MECHANICAL AND THERMAL PROPERTIES: CuO Nanosheets Synthesized by Hydrothermal Process

    NASA Astrophysics Data System (ADS)

    Jiang, Zhi-Ang; Chen, Jiang-Tao; Wang, Jun; Zhuo, Ren-Fu; Yan, De; Zhang, Fei; Yan, Peng-Xun

    2009-08-01

    CuO nanosheets are synthesized by oxidation of commercial Cu substrates through the hydrothermal process at 150°C. The as-synthesized nanosheets are characterized by powder x-ray diffraction, transmission electron microscopy, selected area electron diffraction and x-ray photoelectron spectroscopy. For comparison, Cu substrates are also oxidized without NaOH added in precursor solution. The results show that the morphology of CuO could be controlled by NaOH, which demonstrates that NaOH can serve as a cosolvent and modifier in the reaction system. The possible mechanism of the growth of CuO nanosheets is also discussed.

  11. A geophysical multi-parametric analysis of hydrothermal activity at Dallol, Ethiopia

    NASA Astrophysics Data System (ADS)

    Carniel, Roberto; Jolis, Ester Muñoz; Jones, Josh

    2010-12-01

    During December 2003, three seismic stations were installed close to the hornitos of the hydrothermal system at Dallol, complemented by radiometer and infrasonic measurements. A combined geophysical data set was collected for about three days. During this period thermal, seismic and acoustic records indicate the presence of two regimes characterized by a different energy distribution in frequency. Few volcano-tectonic events appear superimposed to the continuous hydrothermal tremor. The continuous data indicate variable shallow processes most likely related with variations in temperature and degassing processes within the shallow geothermal system. This alternation of low and high regimes shows significant similarities with other volcanic systems of different nature, although at Dallol the transition is more evident in the thermal than in the seismic and acoustic data.

  12. Hydrothermal activity along the slow-spreading Lucky Strike ridge segment (Mid-Atlantic Ridge): Distribution, heatflux, and geological controls

    NASA Astrophysics Data System (ADS)

    Escartin, J.; Barreyre, T.; Cannat, M.; Garcia, R.; Gracias, N.; Deschamps, A.; Salocchi, A.; Sarradin, P. M.; Ballu, V.

    2015-12-01

    We have reviewed available visual information from the seafloor, and recently acquired microbathymetry for several traverses across the Lucky Strike segment to evaluate the distribution of hydrothermal activity. The Lucky Strike segment hosts three active hydrothermal fields: Capelinhos, Ewan, and the known Main Lucky Strike Hydrothermal Field (MLSHF). Capelinhos is located 1.3 km E of the axis and the MLSHF, and consists of a ~20 m sulfide mound with black smoker vents. Ewan is located ~1.8 km south from the MLSHF along the axial graben, and displays only diffuse flow along and around scarps of collapse structures associated with fault scarps. At the MLSHF we have identified an inactive site, thus broadening the extent of this field. Heat flux estimates from these new sites are relatively low and correspond to ~10% of the heat flux estimated for the Main field, with an integrated heatflux of 200-1200 MW. Overall, most of the flux (up to 80-90%) is associated with diffuse outflow, with the Ewan site showing solely diffuse flow and Capelinhos mostly focused flow. Microbathymetry also reveals a large, off-axis (~2.4 km) hydrothermal field, similar to the TAG mound in size, on the flanks of a rifted volcano. The association of these fields to a central volcano, and the absence of indicators of hydrothermal activity along the ridge segment, suggest that sustained hydrothermal activity is maintained by the enhanced melt supply and the associated magma chamber(s) required to build central volcanoes. Hydrothermal outflow zones at the seafloor are systematically controlled by faults, indicating that hydrothermal circulation in the shallow crust exploits permeable fault zones. Central volcanoes are thus associated with long-lived hydrothermal activity, and these sites may play a major role in the distribution and biogeography of vent communities.

  13. Macrobenthos community structure and trophic relationships within active and inactive Pacific hydrothermal sediments

    NASA Astrophysics Data System (ADS)

    Levin, Lisa A.; Mendoza, Guillermo F.; Konotchick, Talina; Lee, Raymond

    2009-09-01

    Hydrothermal fluids passing through sediments create a habitat hypothesized to influence the community structure of infaunal macrobenthos. Here we characterize the density, biomass, species composition, diversity, distributions, lifestyle, and nutritional sources of macroinfauna in hydrothermal sediments in NE and SW Pacific settings, and draw comparisons in search of faunal attributes characteristic of this habitat. There is increasing likelihood that seafloor massive sulfide deposits, associated with active and inactive hydrothermal venting, will be mined commercially. This creates a growing imperative for a more thorough understanding of the structure, dynamics, and resilience of the associated sediment faunas, and has stimulated the research presented here. Macrobenthic assemblages were studied at Manus Basin (1430-1634 m, Papua New Guinea [PNG]) as a function of location (South Su vs. Solwara 1), and hydrothermal activity (active vs. inactive), and at Middle Valley (2406-2411 m, near Juan de Fuca Ridge) as a function of habitat (active clam bed, microbial mat, hot mud, inactive background sediment). The studies conducted in PNG formed part of the environmental impact assessment work for the Solwara 1 Project of Nautilus Minerals Niugini Limited. We hypothesized that hydrothermally active sites should support (a) higher densities and biomass, (b) greater dominance and lower diversity, (c) a higher fraction of deposit feeders, and (d) greater isotopic evidence for chemosynthetic food sources than inactive sites. Manus Basin macrofauna generally had low density (<1000 ind. m -2) and low biomass (0.1-1.07 g m -2), except for the South Su active site, which had higher density (3494 ind. m -2) and biomass (11.94 g m -2), greater dominance (R1D=76%), lower diversity and more spatial (between-core) homogeneity than the Solwara 1 and South Su inactive sites. Dominant taxa at Manus Basin were Spionidae ( Prionospio sp.) in active sediments, and tanaids and deposit

  14. Cu-SSZ-39, an active and hydrothermally stable catalyst for the selective catalytic reduction of NOx.

    PubMed

    Moliner, Manuel; Franch, Cristina; Palomares, Eduardo; Grill, Marie; Corma, Avelino

    2012-08-25

    A Cu-exchanged SSZ-39 zeolite has been synthesized and tested for the selective catalytic reduction (SCR) of NOx. This material shows an excellent catalytic activity, and most importantly, an extraordinary hydrothermal stability.

  15. Elaboration of a video processing platform to analyze the temporal dynamics of hydrothermal ecosystems

    NASA Astrophysics Data System (ADS)

    Aron, M.; Sarrazin, J.; Sarradin, P.; Mercier, G.

    2010-12-01

    Located on oceanic ridges, hydrothermal ecosystems are characterized by strong physicochemical gradients and the presence of a unique fauna, sustained by microbial chemosynthesis. Several studies have shown that the spatial distribution and composition of vent faunal assemblages were strongly correlated to geological, physical and chemical processes at different spatial and temporal scales, but almost no data are available on the temporal dynamics of these peculiar ecosystems. The objective of our research is to develop a video processing platform to automatically extract the biological, physical and geological data from video imagery in order to study the dynamics of the fauna and its habitat in hydrothermal ecosystems. The video data was acquired from the Tempo-mini module deployed at 100m depth in the Saanich inlet (BC, Canada) and connected to the VENUS cable observatory (http://www.venus.uvic.ca/). This submarine color video-camera acquired four months of video footage, representing 487944 images of typical benthic habitat. A first manual extraction of the data allowed us to identify the key data available on a small subset of the video sequences. The objective of the new processing tool is to automatically extract these key data on the whole dataset, using unsupervized or lightly supervized image processing technique adapted to the specificity of submarines images. Firstly, all the moving objects in the video frames were segmented and labelled, allowing us to use statistical methods to process very large datasets. Secondly, computer vision techniques were used in order to get metric and 3D information from the images. For example, the speed of the moving objects and the image surface area were computed. The method implies the calibration of the camera with a calibration target, i.e. computing the projective geometric properties of the camera and the scene. Lastly, the developed tools will be integrated in a user-friendly processing platform that will be used

  16. Hydrothermally processed 1D hydroxyapatite: Mechanism of formation and biocompatibility studies.

    PubMed

    Stojanović, Zoran S; Ignjatović, Nenad; Wu, Victoria; Žunič, Vojka; Veselinović, Ljiljana; Škapin, Srečo; Miljković, Miroslav; Uskoković, Vuk; Uskoković, Dragan

    2016-11-01

    Recent developments in bone tissue engineering have led to an increased interest in one-dimensional (1D) hydroxyapatite (HA) nano- and micro-structures such as wires, ribbons and tubes. They have been proposed for use as cell substrates, reinforcing phases in composites and carriers for biologically active substances. Here we demonstrate the synthesis of 1D HA structures using an optimized, urea-assisted, high-yield hydrothermal batch process. The one-pot process, yielding HA structures composed of bundles of ribbons and wires, was typified by the simultaneous occurrence of a multitude of intermediate reactions, failing to meet the uniformity criteria over particle morphology and size. To overcome these issues, the preparation procedure was divided to two stages: dicalcium phosphate platelets synthesized in the first step were used as a precursor for the synthesis of 1D HA in the second stage. Despite the elongated particle morphologies, both the precursor and the final product exhibited excellent biocompatibility and caused no reduction of viability when tested against osteoblastic MC3T3-E1 cells in 2D culture up to the concentration of 2.6mg/cm(2). X-ray powder diffraction combined with a range of electron microscopies and laser diffraction analyses was used to elucidate the formation mechanism and the microstructure of the final particles. The two-step synthesis involved a more direct transformation of DCP to 1D HA with the average diameter of 37nm and the aspect ratio exceeding 100:1. The comparison of crystalline domain sizes along different crystallographic directions showed no signs of significant anisotropy, while indicating that individual nanowires are ordered in bundles in the b crystallographic direction of the P63/m space group of HA. Intermediate processes, e.g., dehydration of dicalcium phosphate, are critical for the formation of 1D HA alongside other key aspects of this phase transformation, it must be investigated in more detail in the continuous

  17. Hydrothermally processed 1D hydroxyapatite: Mechanism of formation and biocompatibility studies.

    PubMed

    Stojanović, Zoran S; Ignjatović, Nenad; Wu, Victoria; Žunič, Vojka; Veselinović, Ljiljana; Škapin, Srečo; Miljković, Miroslav; Uskoković, Vuk; Uskoković, Dragan

    2016-11-01

    Recent developments in bone tissue engineering have led to an increased interest in one-dimensional (1D) hydroxyapatite (HA) nano- and micro-structures such as wires, ribbons and tubes. They have been proposed for use as cell substrates, reinforcing phases in composites and carriers for biologically active substances. Here we demonstrate the synthesis of 1D HA structures using an optimized, urea-assisted, high-yield hydrothermal batch process. The one-pot process, yielding HA structures composed of bundles of ribbons and wires, was typified by the simultaneous occurrence of a multitude of intermediate reactions, failing to meet the uniformity criteria over particle morphology and size. To overcome these issues, the preparation procedure was divided to two stages: dicalcium phosphate platelets synthesized in the first step were used as a precursor for the synthesis of 1D HA in the second stage. Despite the elongated particle morphologies, both the precursor and the final product exhibited excellent biocompatibility and caused no reduction of viability when tested against osteoblastic MC3T3-E1 cells in 2D culture up to the concentration of 2.6mg/cm(2). X-ray powder diffraction combined with a range of electron microscopies and laser diffraction analyses was used to elucidate the formation mechanism and the microstructure of the final particles. The two-step synthesis involved a more direct transformation of DCP to 1D HA with the average diameter of 37nm and the aspect ratio exceeding 100:1. The comparison of crystalline domain sizes along different crystallographic directions showed no signs of significant anisotropy, while indicating that individual nanowires are ordered in bundles in the b crystallographic direction of the P63/m space group of HA. Intermediate processes, e.g., dehydration of dicalcium phosphate, are critical for the formation of 1D HA alongside other key aspects of this phase transformation, it must be investigated in more detail in the continuous

  18. Meteorite organics in planetary environments: hydrothermal release, surface activity, and microbial utilization.

    PubMed

    Mautner, M N; Leonard, R L; Deamer, D W

    1995-01-01

    Up to 50% of the organics in the Murchison meteorite, possibly including some of the polymer, is released in high temperature and pressure aqueous environments, to 350 degrees C and 250 bar, that simulate submarine volcanic, hydrothermal or impact-induced conditions. Meteorite organics of prebiotic significance, such as nonanoic acid, glycine, and pyrene survive the hydrothermal conditions. The released material is surface active with surface pressures up to 19.8 x 10(-3) N m-1, and exhibits an extended surface tension isotherm which suggests a mixture of amphiphilic components. One component, nonanoic acid, is shown to form vesicles. The materials extracted under mild conditions, at 120 degrees C, are nutrients for the humic acid bacterium Pseudomonas maltophilia and efficient nutrients for the oligotroph Flavobacterium oryzihabitans, demonstrating the capability of microorganisms to metabolize extraterrestrial organics.

  19. Meteorite organics in planetary environments: hydrothermal release, surface activity, and microbial utilization.

    PubMed

    Mautner, M N; Leonard, R L; Deamer, D W

    1995-01-01

    Up to 50% of the organics in the Murchison meteorite, possibly including some of the polymer, is released in high temperature and pressure aqueous environments, to 350 degrees C and 250 bar, that simulate submarine volcanic, hydrothermal or impact-induced conditions. Meteorite organics of prebiotic significance, such as nonanoic acid, glycine, and pyrene survive the hydrothermal conditions. The released material is surface active with surface pressures up to 19.8 x 10(-3) N m-1, and exhibits an extended surface tension isotherm which suggests a mixture of amphiphilic components. One component, nonanoic acid, is shown to form vesicles. The materials extracted under mild conditions, at 120 degrees C, are nutrients for the humic acid bacterium Pseudomonas maltophilia and efficient nutrients for the oligotroph Flavobacterium oryzihabitans, demonstrating the capability of microorganisms to metabolize extraterrestrial organics. PMID:11538427

  20. Meteorite organics in planetary environments: hydrothermal release, surface activity, and microbial utilization

    NASA Astrophysics Data System (ADS)

    Mautner, Michael N.; Leonard, Robert L.; Deamer, David W.

    1995-02-01

    Up to 50% of the organics in the Murchison meteorite, possibly including some of the polymer, is released in high temperature and pressure aqueous environments, to 350°C and 250 bar, that simulate submarine volcanic, hydrothermal or impact-induced conditions. Meteorite organics of prebiotic significance, such as nonanoic acid, glycine, and pyrene survive the hydrothermal conditions. The released material is surface active with surface pressures up to 19.8 × 10 -3 N m -1, and exhibits an extended surface tension isotherm which suggests a mixture of amphiphilic components. One component, nonanoic acid, is shown to form vesicles. The materials extracted under mild conditions, at 120°C, are nutrients for the humic acid bacterium Pseudomonas maltophilia and efficient nutrients for the oligotroph Flavobacterium oryzihabitans, demonstrating the capability of micro-organisms to metabolize extraterrestrial organics.

  1. Meteorite organics in planetary environments: hydrothermal release, surface activity, and microbial utilization

    NASA Technical Reports Server (NTRS)

    Mautner, M. N.; Leonard, R. L.; Deamer, D. W.

    1995-01-01

    Up to 50% of the organics in the Murchison meteorite, possibly including some of the polymer, is released in high temperature and pressure aqueous environments, to 350 degrees C and 250 bar, that simulate submarine volcanic, hydrothermal or impact-induced conditions. Meteorite organics of prebiotic significance, such as nonanoic acid, glycine, and pyrene survive the hydrothermal conditions. The released material is surface active with surface pressures up to 19.8 x 10(-3) N m-1, and exhibits an extended surface tension isotherm which suggests a mixture of amphiphilic components. One component, nonanoic acid, is shown to form vesicles. The materials extracted under mild conditions, at 120 degrees C, are nutrients for the humic acid bacterium Pseudomonas maltophilia and efficient nutrients for the oligotroph Flavobacterium oryzihabitans, demonstrating the capability of microorganisms to metabolize extraterrestrial organics.

  2. Fermentation of cellulosic hydrolysates obtained by enzymatic saccharification of sugarcane bagasse pretreated by hydrothermal processing.

    PubMed

    Silva, Vinícius F N; Arruda, Priscila V; Felipe, Maria G A; Gonçalves, Adilson R; Rocha, George J M

    2011-07-01

    This work aims to evaluate the fermentability of cellulosic hydrolysates obtained by enzymatic saccharification of sugarcane bagasse pretreated by hydrothermal processing using Candida guilliermondii FTI 20037 yeast. The inoculum was obtained from yeast culture in a medium containing glucose as a carbon source supplemented with rice bran extract, CaCl(2)·2H(2)O and (NH(4))(2)SO(4) in 50 mL Erlenmeyer flasks, containing 20 mL of medium, initial 5.5 pH under agitation of an orbital shaker (200 rpm) at 30°C for 24 h. The cellulosic hydrolysates, prior to being used as a fermentation medium, were autoclaved for 15 min at 0.5 atm and supplemented with the same nutrients employed for the inoculum, except the glucose, using the same conditions for the inoculum, but with a period of 48 h. Preliminary results showed the highest consumption of glucose (97%) for all the hydrolysates, at 28 h of fermentation. The highest concentration of ethanol (20.5 g/L) was found in the procedure of sugarcane bagasse pretreated by hydrothermal processing (195°C/10 min in 20 L reactor) and delignificated with NaOH 1.0% (w/v), 100°C, 1 h in 500 mL stainless steel ampoules immersed in an oil bath.

  3. Hydrothermal processing of hydroxyapatite nanoparticles—A Taguchi experimental design approach

    NASA Astrophysics Data System (ADS)

    Sadat-Shojai, Mehdi; Khorasani, Mohammad-Taghi; Jamshidi, Ahmad

    2012-12-01

    Chemical precipitation followed by hydrothermal processing is conventionally employed in the laboratory-scale synthesis of hydroxyapatite (HAp) and extensive information on its processing conditions has therefore been provided in literature. However, the knowledge about the influence of some operating parameters, especially those important for a large-scale production, is yet insufficient. A specific approach based on a Taguchi orthogonal array was therefore used to evaluate these parameters and to optimize them for a more effective synthesis. This approach allowed us to systematically determine the correlation between the operating factors and the powder quality. Analysis of signal-to-noise ratios revealed the great influence of temperature and pH on the characteristic of powder. Additionally, the injection rate of one reagent into another was found to be the most important operating factor affecting the stoichiometric ratio of powders. As-prepared powders were also studied for their in-vitro bioactivity. The SEM images showed the accumulation of a new apatite-like phase on surface of the powder along with an interesting morphological change after a 45-day incubation of powder in SBF, indicating a promising bioactivity. Some results also showed the capability of simple hydrothermal method for the synthesis of a lamellar structure without the help of any templating system.

  4. [Impact of hydrothermal process on the dewaterability and degrease performance of restaurant garbage].

    PubMed

    Ren, Lian-hail; Nie, Yong-feng; Liu, Jian-guo; Jin, Yi-ying

    2006-09-01

    In order to ameliorate the dewaterability and degrease performance of restaurant garbage, and to improve the treatment effect, a complete trail series with 2 factors on 5 levels was implemented. The 2 factors were temperature and retention time respectively as the main influencing factors of hydrothermal process. By means of analyzing the variation of the resistance, dewatering rate and floatable oil content of the treated restaurant garbage, and constructing the solid grease extracting kinetics, the mechanism of impact of hydrothermal process on the dewaterability and degrease performance of restaurant garbage was studied. It showed that the dewaterability of the product decreases at the beginning, after heating for 40min, it begins to increase. Moreover, it increases more quickly as temperature increases. The optimal dewaterability of the treated garbage appears at 180 degrees C and heating for 100 minutes. As temperature rises and heating time increases, the degrease performance is improved. Furthermore, this trend becomes more remarkably as temperature increases. When the temperature and retention time reach 160 degrees C and 80 minutes respectively, most of the solid grease in the garbage is extracted out to become floatable oil which can be separated and recovered readily. Subsequently, the amount of floatable oil begins to decrease since chemical reactions such as the partial hydrolysis of the oil take place. Additionally, the extraction of solid grease from interior accords with first-order reaction dynamic model. PMID:17117654

  5. Carbon Isotope Systematics in Mineral-Catalyzed Hydrothermal Organic Synthesis Processes at High Temperature and Pressures

    NASA Technical Reports Server (NTRS)

    Fu, Qi; Socki, R. A.; Niles, Paul B.

    2011-01-01

    Observation of methane in the Martian atmosphere has been reported by different detection techniques. Reduction of CO2 and/or CO during serpentization by mineral surface catalyzed Fischer-Tropsch Type (FTT) synthesis may be one possible process responsible for methane generation on Mars. With the evidence a recent study has discovered for serpentinization in deeply buried carbon rich sediments, and more showing extensive water-rock interaction in Martian history, it seems likely that abiotic methane generation via serpentinization reactions may have been common on Mars. Experiments involving mineral-catalyzed hydrothermal organic synthesis processes were conducted at 750 C and 5.5 Kbars. Alkanes, alcohols and carboxylic acids were identified as organic compounds. No "isotopic reversal" of delta C-13 values was observed for alkanes or carboxylic acids, suggesting a different reaction pathway than polymerization. Alcohols were proposed as intermediaries formed on mineral surfaces at experimental conditions. Carbon isotope data were used in this study to unravel the reaction pathways of abiotic formation of organic compounds in hydrothermal systems at high temperatures and pressures. They are instrumental in constraining the origin and evolution history of organic compounds on Mars and other planets.

  6. Hydrothermal processing of duckweed: effect of reaction conditions on product distribution and composition.

    PubMed

    Duan, Peigao; Chang, Zhoufan; Xu, Yuping; Bai, Xiujun; Wang, Feng; Zhang, Lei

    2013-05-01

    Influences of operating conditions such as temperature (270-380 °C), time (10-120 min), reactor loading (0.5-5.5 g), and K2CO3 loading (0-50 wt.%) on the product (e.g. crude bio-oil, water soluble, gas and solid residue) distribution from the hydrothermal processing of duckweed were determined. Of the four variables, temperature and K2CO3 loading were always the most influential factors to the relative amount of each component. The presence of K2CO3 is unfavorable for the production of bio-oil and gas. Hydrothermal processing duckweed produces a bio-oil that is enriched in carbon and hydrogen and has reduced levels of O compared with the original duckweed feedstock. The higher heating values of the bio-oil were estimated within the range of 32-36 MJ/kg. Major bio-oil constituents include ketones and their alkylated derivatives, alcohols, heterocyclic nitrogen-containing compounds, saturated fatty acids and hydrocarbons. The gaseous products were mainly CO2 and H2, with lesser amounts of CH4 and CO.

  7. [Impact of hydrothermal process on the dewaterability and degrease performance of restaurant garbage].

    PubMed

    Ren, Lian-hail; Nie, Yong-feng; Liu, Jian-guo; Jin, Yi-ying

    2006-09-01

    In order to ameliorate the dewaterability and degrease performance of restaurant garbage, and to improve the treatment effect, a complete trail series with 2 factors on 5 levels was implemented. The 2 factors were temperature and retention time respectively as the main influencing factors of hydrothermal process. By means of analyzing the variation of the resistance, dewatering rate and floatable oil content of the treated restaurant garbage, and constructing the solid grease extracting kinetics, the mechanism of impact of hydrothermal process on the dewaterability and degrease performance of restaurant garbage was studied. It showed that the dewaterability of the product decreases at the beginning, after heating for 40min, it begins to increase. Moreover, it increases more quickly as temperature increases. The optimal dewaterability of the treated garbage appears at 180 degrees C and heating for 100 minutes. As temperature rises and heating time increases, the degrease performance is improved. Furthermore, this trend becomes more remarkably as temperature increases. When the temperature and retention time reach 160 degrees C and 80 minutes respectively, most of the solid grease in the garbage is extracted out to become floatable oil which can be separated and recovered readily. Subsequently, the amount of floatable oil begins to decrease since chemical reactions such as the partial hydrolysis of the oil take place. Additionally, the extraction of solid grease from interior accords with first-order reaction dynamic model.

  8. Fabrication of hollow mesoporous NiO hexagonal microspheres via hydrothermal process in ionic liquid

    SciTech Connect

    Zhao, Jinbo; Wu, Lili; Zou, Ke

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Ni(OH){sub 2} precursors were synthesized in ionic liquid and water solution by hydrothermal method. Black-Right-Pointing-Pointer NiO hollow microspheres were prepared by thermal treatment of Ni(OH){sub 2} precursors. Black-Right-Pointing-Pointer NiO hollow microspheres were self-assembled by mesoporous cubic and hexagonal nanocrystals with high specific surface area. Black-Right-Pointing-Pointer The mesoporous structure is stable at 773 K. Black-Right-Pointing-Pointer The ionic liquid absorbed on the O-terminate surface of the crystals to form hydrogen bond and played key roles in determining the final shape of the NiO novel microstructure. -- Abstract: The novel NiO hexagonal hollow microspheres have been successfully prepared by annealing Ni(OH){sub 2}, which was synthesized via an ionic liquid-assisted hydrothermal method. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), N{sub 2} adsorption-desorption and Fourier transform infrared spectrometer (FTIR). The results show that the hollow NiO microstructures are self-organized by mesoporous cubic and hexagonal nanocrystals. The mesoporous structure possessed good thermal stability and high specific surface area (ca. 83 m{sup 2}/g). The ionic liquid 1-butyl-3methylimidazolium tetrafluoroborate ([Bmim][BF{sub 4}]) was found to play a key role in controlling the morphology of NiO microstructures during the hydrothermal process. The special hollow mesoporous architectures will have potential applications in many fields, such as catalysts, absorbents, sensors, drug-delivery carriers, acoustic insulators and supercapacitors.

  9. Electrical Resistivity Monitoring of an Active Hydrothermal Degassing Area at Solfatara, Phlegrean Fields.

    NASA Astrophysics Data System (ADS)

    Vandemeulebrouck, J.; Byrdina, S.; Grangeon, J.; Lebourg, T.; Bascou, P.; Mangiacapra, A.

    2015-12-01

    Campi Flegrei caldera (CFc) is an active volcanic complex covering a ~100 km² densely populated area in the western part of Naples (Italy) that is presently showing clear signs of unrest. Solfatara volcano, a tuff cone crater formed ~4000 yrs B.P. ago by phreato-magmatic eruptions represents the main degassing outflow of CFc. Magmatic gases which are exsolved from a ~8 km deep magmatic reservoir mix at 4 km depth with meteoric hydrothermal fluids then reach the surface in the Solfatara area. These hydrothermal and magmatic gases, mainly H2O and CO2, are released through both diffuse degassing structures and fumaroles. In the frame of the MedSuv (Mediterranean Supervolcanoes) FP7 european project , we are performing a time-lapse electrical resistivity monitoring of an active degassing area of Solfatara. Using a 500-m-long cable and 48 electrodes, an electrical resistivity tomography (ERT) is performed on a two-day basis since May 2013. The time-lapse inversion of the ERT gives an image of the temporal variations of resistivity up to 100 m depth that can be compared with the variations of ground deformation, CO2 flux, soil temperature and seismic ambient noise. Resistivity variations can originate from fluid composition, gas ratio and temperature. For example, the abrupt change of resistivity that was observed mid-2014 during a period of uplift and gas flux increase, could be associated with the rise of hydrothermal fluids.

  10. Phylogenetic diversity of sulfate-reducing prokaryotes in active deep-sea hydrothermal vent chimney structures.

    PubMed

    Nakagawa, Tatsunori; Nakagawa, Satoshi; Inagaki, Fumio; Takai, Ken; Horikoshi, Koki

    2004-03-19

    The phylogenetic diversity of sulfate-reducing prokaryotes occurring in active deep-sea hydrothermal vent chimney structures was characterized based on the deduced amino acid sequence analysis of the polymerase chain reaction-amplified dissimilatory sulfite reductase (DSR) gene. The DSR genes were successfully amplified from microbial assemblages of the chimney structures, derived from three geographically and geologically distinct deep-sea hydrothermal systems in the Central Indian Ridge (CIR), in the Izu-Bonin Arc (IBA), and the Okinawa Trough (OT), respectively. Phylogenetic analysis revealed seven major phylogenetic groups. More than half of the clones from the CIR chimney structure were related to DSR amino acid sequences of the hyperthermophilic archaeal members of the genus Archaeoglobus, and those of environmental DSR clones within the class Thermodesulfobacteria. From the OT chimney structure, a different group was obtained, which comprised a novel, deep lineage associated with the DSRs of the thermophilic sulfate-reducing bacterium Thermodesulfovibrio. Most of the DSR clones from the IBA chimney structure were phylogenetically associated with the delta-proteobacterial sulfate-reducing bacteria represented by the genus Desulfobulbus. Sequence analysis of DSR clones demonstrated a diverse sulfate-reducing prokaryotic community in the active deep-sea hydrothermal chimney structures.

  11. A comparison of product yields and inorganic content in process streams following thermal hydrolysis and hydrothermal processing of microalgae, manure and digestate.

    PubMed

    Ekpo, U; Ross, A B; Camargo-Valero, M A; Williams, P T

    2016-01-01

    Thermal hydrolysis and hydrothermal processing show promise for converting biomass into higher energy density fuels. Both approaches facilitate the extraction of inorganics into the aqueous product. This study compares the behaviour of microalgae, digestate, swine and chicken manure by thermal hydrolysis and hydrothermal processing at increasing process severity. Thermal hydrolysis was performed at 170°C, hydrothermal carbonisation (HTC) was performed at 250°C, hydrothermal liquefaction (HTL) was performed at 350°C and supercritical water gasification (SCWG) was performed at 500°C. The level of nitrogen, phosphorus and potassium in the product streams was measured for each feedstock. Nitrogen is present in the aqueous phase as organic-N and NH3-N. The proportion of organic-N is higher at lower temperatures. Extraction of phosphorus is linked to the presence of inorganics such as Ca, Mg and Fe in the feedstock. Microalgae and chicken manure release phosphorus more easily than other feedstocks.

  12. A comparison of product yields and inorganic content in process streams following thermal hydrolysis and hydrothermal processing of microalgae, manure and digestate.

    PubMed

    Ekpo, U; Ross, A B; Camargo-Valero, M A; Williams, P T

    2016-01-01

    Thermal hydrolysis and hydrothermal processing show promise for converting biomass into higher energy density fuels. Both approaches facilitate the extraction of inorganics into the aqueous product. This study compares the behaviour of microalgae, digestate, swine and chicken manure by thermal hydrolysis and hydrothermal processing at increasing process severity. Thermal hydrolysis was performed at 170°C, hydrothermal carbonisation (HTC) was performed at 250°C, hydrothermal liquefaction (HTL) was performed at 350°C and supercritical water gasification (SCWG) was performed at 500°C. The level of nitrogen, phosphorus and potassium in the product streams was measured for each feedstock. Nitrogen is present in the aqueous phase as organic-N and NH3-N. The proportion of organic-N is higher at lower temperatures. Extraction of phosphorus is linked to the presence of inorganics such as Ca, Mg and Fe in the feedstock. Microalgae and chicken manure release phosphorus more easily than other feedstocks. PMID:26615335

  13. Phases' characteristics of poultry litter hydrothermal carbonization under a range of process parameters.

    PubMed

    Mau, Vivian; Quance, Julie; Posmanik, Roy; Gross, Amit

    2016-11-01

    The aim of this work was to study the hydrothermal carbonization of poultry litter under a range of process parameters. Experiments were conducted to investigate the effect of HTC of poultry litter under a range of operational parameters (temperature, reaction time, and solids concentration) on the formation and characteristics of its phases. Results showed production of a hydrochar with caloric value of 24.4MJ/kg, similar to sub-bituminous coal. The gaseous phase consisted mainly of CO2. However, significant amounts of H2S dictate the need for (further) treatment. The process also produced an aqueous phase with chemical characteristics suggesting its possible use as a liquid fertilizer. Temperature had the most significant effect on processes and product formation. Solids concentration was not a significant factor once dilution effects were considered. PMID:27544913

  14. The Third Dimension of an Active Back-arc Hydrothermal System: ODP Leg 193 at PACMANUS

    NASA Astrophysics Data System (ADS)

    Binns, R.; Barriga, F.; Miller, D.

    2001-12-01

    This first sub-seafloor examination of an active hydrothermal system hosted by felsic volcanics, at a convergent margin, obtained drill core from a high-T "smoker" site (penetrated to sim200 mbsf) and a low-T site of diffuse venting (~400mbsf). We aimed to delineate the lateral and vertical variability in mineralisation and alteration patterns, so as to understand links between volcanological, structural and hydrothermal phenomena and the sources of fluids, and to establish the nature and extent of microbial activity within the system. Technological breakthroughs included deployment of a new hard-rock re-entry system, and direct comparison in a hardrock environment of structural images obtained by wireline methods and logging-while-drilling. The PACMANUS hydrothermal site, at the 1700m-deep crest of a 500m-high layered sequence of dacitic lavas, is notable for baritic massive sulfide chimneys rich in Cu, Zn, Au and Ag. Below an extensive cap 5-40m thick of fresh dacite-rhyodacite, we found unexpectedly pervasive hydrothermal alteration of vesicular and flow-banded precursors, accompanied by variably intense fracturing and anhydrite-pyrite veining. Within what appears one major hydrothermal event affecting the entire drilled sequence, there is much overprinting and repetition of distinctly allochemical argillaceous (illite-chlorite), acid-sulfate (pyrophyllite-anhydrite) and siliceous assemblages. The alteration profiles include a transition from metastable cristobalite to quartz at depth, and are similar under low-T and high-T vent sites but are vertically condensed in a manner suggesting higher thermal gradients beneath the latter. The altered rocks are surprisingly porous (average 25%). Retention of intergranular pore spaces and open vesicles at depth implies elevated hydrothermal pressures, whereas evidence from fluid inclusions and hydrothermal brecciation denotes local or sporadic phase separation. A maximum measured temperature of 313 degC measured 8 days

  15. Mineralogical and chemical characteristics of newer dolerite dyke around Keonjhar, Orissa: Implication for hydrothermal activity in subduction zone setting

    NASA Astrophysics Data System (ADS)

    Sengupta, Piyali; Ray, Arijit; Pramanik, Sayantani

    2014-06-01

    The newer dolerite dykes around Keonjhar within the Singbhum Granite occur in NE-SW, NW-SE and NNE-SSW trends. The mafic dykes of the present study exhibit several mineralogical changes like clouding of plagioclase feldspars, bastitisation of orthopyroxene, and development of fibrous amphibole (tremolite-actinolite) from clinopyroxene, which are all considered products of hydrothermal alterations. This alteration involves addition and subtraction of certain elements. Graphical analyses with Alteration index and elemental abundances show that elements like Rb, Ba, Th, La and K have been added during the alteration process, whereas elements like Sc, Cr, Co, Ni, Si, Al, Fe, Mg and Ca have been removed. It is observed that in spite of such chemical alteration, correlation between major and trace elements, characteristic of petrogenetic process, is still preserved. This might reflect systematic Alteration (addition or subtraction) of elements without disturbing the original element to element correlation. It has also been established by earlier workers that the evolution of newer dolerite had occurred in an arc-back arc setting which may also be true for newer dolerites of the present study. This is evident from plots of pyroxene composition and whole rock composition of newer dolerite samples in different tectonic discrimination diagrams using immobile elements. The newer dolerite dykes of the Keonjhar area may thus be considered to represent an example of hydrothermal activity on mafic rocks in an arc setting.

  16. Volcanic and Hydrothermal Activity of the North Su Volcano: New Insights from Repeated Bathymetric Surveys and ROV Observations

    NASA Astrophysics Data System (ADS)

    Thal, J.; Bach, W.; Tivey, M.; Yoerger, D.

    2013-12-01

    Bathymetric data from cruises in 2002, 2006, and 2011 were combined and compared to determine the evolution of volcanic activity, seafloor structures, erosional features and to identify and document the distribution of hydrothermal vents on North Su volcano, SuSu Knolls, eastern Manus Basin (Papua New Guinea). Geologic mapping based on ROV observations from 2006 (WHOI Jason-2) and 2011 (MARUM Quest-4000) combined with repeated bathymetric surveys from 2002 and 2011 are used to identify morphologic features on the slopes of North Su and to track temporal changes. ROV MARUM Quest-4000 bathymetry was used to develop a 10 m grid of the top of North Su to precisely depict recent changes. In 2006, the south slope of North Su was steeply sloped and featured numerous white smoker vents discharging acid sulfate waters. These vents were covered by several tens of meters of sand- to gravel-sized volcanic material in 2011. The growth of this new cone changed the bathymetry of the south flank of North Su up to ~50 m and emplaced ~0.014 km3 of clastic volcanic material. This material is primarily comprised of fractured altered dacite and massive fresh dacite as well as crystals of opx, cpx, olivine and plagioclase. There is no evidence for pyroclastic fragmentation, so we hypothesize that the fragmentation is likely related to hydrothermal explosions. Hydrothermal activity varies over a short (~50 m) lateral distance from 'flashing' black smokers to acidic white smoker vents. Within 2 weeks of observation time in 2011, the white smoker vents varied markedly in activity suggesting a highly episodic hydrothermal system. Based on ROV video recordings, we identified steeply sloping (up to 30°) slopes exposing pillars and walls of hydrothermal cemented volcaniclastic material representing former fluid upflow zones. These features show that hydrothermal activity has increased slope stability as hydrothermal cementation has prevented slope collapse. Additionally, in some places

  17. The production of glucose from corn stalk using hydrothermal process with pre-treatment ultrasound assisted alkaline

    NASA Astrophysics Data System (ADS)

    Yolanda, Dora; Prasutiyo, Indry; Trisanti, P. N.; Sumarno

    2015-12-01

    The production of glucose from corn stalk by using subcritical hydrothermal technology is studied in this work. Ultrasound-assisted alkaline delignification methods are used as pre-treatment. The corn stalk powder were pretreated with ultrasound-assisted alkaline (NaOH 2% w/w, solid to liquid ratio 1:22 w/v) at room temperature and 30 minutes. After pre-treatment, solid residue and liquid fractions are separated by filtration. Pretreated solids are further submitted to hydrothermal process for glucose production. Hydrothermal process was carried out at 100 Bar and 120°C in various times. The solid product was characterized by SEM and XRD. And liquid product was analysis using DNS method to determine percentage of glucose. From XRD analysis showed that crystallinity of material was lower than delignification product.

  18. Extensive and Diverse Submarine Volcanism and Hydrothermal Activity in the NE Lau Basin

    NASA Astrophysics Data System (ADS)

    Embley, R. W.; Merle, S. G.; Lupton, J. E.; Resing, J.; Baker, E. T.; Lilley, M. D.; Arculus, R. J.; Crowhurst, P. V.

    2009-12-01

    The northeast Lau basin, the NE “corner” of the Tonga subduction zone, has an unusual concentration of young submarine volcanism and hydrothermal activity. The area is bounded on the west by overlapping spreading centers opening at rates up to 120 mm/yr, on the north by the E-W trending Tonga trench and on the east by the Tofua arc front. From the south, the Fonualei rift spreading center (FRSC) overlaps with the southern rift of The Mangatolo triple junction spreading center (MTJSC). The northern arm of the MTJSC overlaps with the northeast Lau spreading center (NELSC). Surveys of the area with an EM300 sonar system in November 2008 show high backscatter over the 10-20 km wide neovolcanic zones of the FRSC, MTJSC and NELSC. High backscatter is also associated with: (1) a 10-km diameter, hydrothermally active, volcanic caldera/cone (Volcano “O”) lying between the NELSC and the northern Tofua arc front; (2) a rift zone extending north from volcano “O” and intersecting the NELSC near the Tonga trench; and (3) a series of volcanoes constructed along SW-NE trending crustal tears in the northernmost backarc near the east-west portion of the Tonga Trench. Two eruptions were detected in November 2008 during hydrothermal plume surveys of the area. Subsequent dives with the remotely operated vehicle Jason 2 in May 2009 revealed that the southern NELSC eruption was a short-lived, primarily effusive eruption. The second eruption was detected on the summit of the largest SW-NE trending volcano (West Mata) and was ongoing when Jason 2 arrived on site more than 6 months later. It was producing both pillow lavas and abundant volcaniclastic debris streams that have a characteristic appearance on the sonar backscatter map. There is also an unusual series of lava flows emanating from ridges and scarps between Volcano “O” and West Mata. These flows contain drained-out lava ponds up to 2 km in diameter. The apparent high level of volcanic activity in the NE Lau basin

  19. Response to"Analysis of the Treatment, by the U.S. Department of Energy, of the FEP Hydrothermal Activity in the Yucca Mountain Performance Assessment" by Yuri Dublyansky

    SciTech Connect

    Houseworth, J.E.; Hardin, E.

    2008-11-17

    This paper presents a rebuttal to Dublyansky (2007), which misrepresents technical issues associated with hydrothermal activity at the proposed Yucca Mountain nuclear waste repository and their importance to the long-term performance of the repository. In this paper, questions associated with hydrothermal activity are reviewed and the justification for exclusion of hydrothermal activity from performance assessment is presented. The hypothesis that hydrothermal upwelling into the present-day unsaturated zone has occurred at Yucca Mountain is refuted by the unambiguous evidence that secondary minerals and fluid inclusions in the unsaturated zone formed in an unsaturated environment from downward percolating meteoric waters. The thermal history at Yucca Mountain, inferred from fluid inclusion and isotopic data, is explained in terms of the tectonic extensional environment and associated silicic magmatism. The waning of tectonic extension over millions of years has led to the present-day heat flux in the Yucca Mountain region that is below average for the Great Basin. The long time scales of tectonic processes are such that any effects of a resumption of extension or silicic magmatism on hydrothermal activity at Yucca Mountain over the 10,000-year regulatory period would be negligible. The conclusion that hydrothermal activity was incorrectly excluded from performance assessment as asserted in Dublyansky (2007) is contradicted by the available technical and regulatory information.

  20. Investigating the active hydrothermal field of Kolumbo Volcano using CTD profiling

    NASA Astrophysics Data System (ADS)

    Eleni Christopoulou, Maria; Mertzimekis, Theo; Nomikou, Paraskevi; Papanikolaou, Dimitrios; Carey, Steve

    2014-05-01

    The submarine Kolumbo volcano NE of Santorini Island and the unique active hydrothermal vent field on its crater field (depth ~ 500 m) have been recently explored in multiple cruises aboard E/V Nautilus. ROV explorations showed the existence of extensive vent activity and almost completely absence of vent-specific macrofauna. Gas discharges have been found to be 99%-rich in CO2, which is sequestered at the bottom of the crater due to a special combination of physicochemical and geomorphological factors. The dynamic conditions existing along the water column in the crater have been studied in detail by means of temperature, salinity and conductivity depth profiles for the first time. CTD sensors aboard the ROV Hercules were employed to record anomalies in those parameters in an attempt to investigate several active and inactive vent locations. Temporal CTD monitoring inside and outside of the crater was carried out over a period of two years. Direct comparison between the vent field and locations outside the main cone, where no hydrothermal activity is known to exist, showed completely different characteristics. CTD profiles above the active vent field (NNE side) are correlated to Kolumbo's cone morphology. The profiles suggest the existence of four distinct zones of physicochemical properties in the water column. The layer directly above the chimneys exhibit gas discharges highly enriched in CO2. Continuous gas motoring is essential to identify the onset of geological hazards in the region.

  1. [Effect of sodium carbonate assisted hydrothermal process on heavy metals stabilization in medical waste incinerator fly ash].

    PubMed

    Jin, Jian; Li, Xiao-dong; Chi, Yong; Yan, Jian-hua

    2010-04-01

    A sodium carbonate assisted hydrothermal process was induced to stabilize the fly ash from medical waste incinerator. The results showed that sodium carbonate assisted hydrothermal process reduced the heavy metals leachability of fly ash, and the heavy metal waste water from the process would not be a secondary pollution. The leachability of heavy metals studied in this paper were Cd 1.97 mg/L, Cr 1.56 mg/L, Cu 2.56 mg/L, Mn 17.30 mg/L, Ni 1.65 mg/L, Pb 1.56 mg/L and Zn 189.00 mg/L, and after hydrothermal process with the optimal experimental condition (Na2CO3/fly ash dosage = 5/20, reaction time = 8 h, L/S ratio = 10/1) the leachability reduced to < 0.02 mg/L for Cd, Cr, Cu, Mn, Ni, Pb, and 0.05 mg/L for Zn, according to GB 5085.3-2007. Meanwhile, the concentrations of heavy metals in effluent after hydrothermal process were less than 0.8 mg/L. The heavy metals leachability and concentration in effluent reduced with prolonged reaction time. Prolonged aging can affect the leachability of metals as solids become more crystalline, and heavy metals transferred inside of crystalline. The mechanism of heavy metal stabilization can be concluded to the co precipitation and adsorption effect of aluminosilicates formation, crystallization and aging process.

  2. Hydrothermal carbonization of biomass from landscape management - Influence of process parameters on soil properties of hydrochars.

    PubMed

    Röhrdanz, Michael; Rebling, Tammo; Ohlert, Jan; Jasper, Jan; Greve, Thomas; Buchwald, Rainer; von Frieling, Petra; Wark, Michael

    2016-05-15

    Besides pyrolysis the technology of hydrothermal carbonization (HTC) is tested to produce hydrochars for soil improvement. The chemical and physical properties of the hydrochars mainly depend on the feedstock and the process parameters reaction time and process temperature. Systematic investigations on the influences of these process parameters on soil properties of hydrochars like water holding capacity (WHC) and cation exchange capacity (CEC) are missing. In this study, a rush-rich biomass was carbonized within defined HTC process conditions under variation of reaction time and process temperature to produce hydrochars. Analysis of WHC, CEC, the elemental composition and Fourier-transform infrared spectroscopy (FT-IR) were performed to evaluate the influence of HTC process conditions on the pedological hydrochar properties. The results indicated that at increasing reaction severity (reaction time and process temperature) WHC and CEC decreased as well as the elemental O/C ratio. The decrease of WHC and CEC is based on the decrease of the hydrochar surface polarity. However, even the lowest WHC and CEC of investigated hydrochars still exceeded those of pure quartz sand by factors of 5-10. An application of hydrochars produced at severe HTC conditions could improve WHC and CEC of sandy soils. This has to be investigated in further studies. PMID:26974240

  3. Tide-related variability of TAG hydrothermal activity observed by deep-sea monitoring system and OBSH

    NASA Astrophysics Data System (ADS)

    Fujioka, Kantaro; Kobayashi, Kazuo; Kato, Kazuhiro; Aoki, Misumi; Mitsuzawa, Kyohiko; Kinoshita, Masataka; Nishizawa, Azusa

    1997-12-01

    Hydrothermal activities were monitored by an ocean bottom seismometer with hydrophone (OBSH) and a composite measuring system (Manatee) including CTD, current meter, transmission meter and cameras at a small depression on the TAG hydrothermal mound in the Mid-Atlantic Ridge. Low-frequency pressure pulses detected by the hydrophone with semi-diurnal periodicity seem to correspond to cycles of hydrothermal upflow from a small and short-lived smoker vent close to the observing site. The peaks of pressure pulses are synchronous with the maximum gradient of areal strain decrease due to tidal load release. Microearthquakes with very near epicenters occur sporadically and do not appear to be directly correlatable to hydrothermal venting. Temporal variations in bottom water temperature also have semi-diurnal periodicity but are more complicated than the pressure events. Temperatures may be affected both by upwelling of hot water and by lateral flow of the bottom current changing its directions with ocean tide.

  4. Surface Defects Control for ZnO Nanorods Synthesized Through a Gas-Assisted Hydrothermal Process

    NASA Astrophysics Data System (ADS)

    Zhao, Limin; Shu, Changhua; Jia, Zhengfeng; Wang, Changzheng

    2016-08-01

    Oxygen vacancies in crystal have an important impact on the electronic properties of zinc oxide (ZnO). In this paper, ZnO nanorods with rich oxygen vacancies were prepared through a novel gas-assisted hydrothermal growth process. X-ray diffraction data showed that single-phase ZnO with the wurtzite crystal structure was obtained and the crystallite size decreased as the reaction atmosphere pressure increased. The oxygen vacancies of ZnO were confirmed using x-ray photoelectron spectroscopy and photoluminescence spectroscopy. The results showed that the concentration of oxygen vacancies could be regulated by both the atmosphere pressure and the atmosphere properties. The oxygen vacancies in ZnO samples were reduced when the pressure increase in the hydrogen reaction environment (reducing atmosphere) and the oxygen vacancies in ZnO samples were increased when the pressure increased in the oxygen reaction environment (oxidizing atmosphere).

  5. Effects of processing conditions on biocrude yields from fast hydrothermal liquefaction of microalgae.

    PubMed

    Faeth, Julia L; Savage, Phillip E

    2016-04-01

    This study investigated the effects of algae species, reaction time, and reactor loading on the biocrude yield from fast hydrothermal liquefaction (HTL) of microalgae. Fast HTL reaction times were always less than 2 min and employed rapid heating and nonisothermal conditions. The highest biocrude yield obtained was 67±5 wt.% (dry basis). With all other process variables fixed, increasing the reaction time in a 600 °C sand bath by 15 s increments led to a rapid increase in biocrude yield between 15 and 45 s. At longer times, the biocrude yield decreased. Low reactor loadings generally gave higher biocrude yields than did higher loadings. The low reactor loadings may facilitate biocrude production by facilitating cell rupture and/or increasing the effective concentration of algal cells in the hot, compressed water in the reactor. PMID:26879204

  6. Effects of processing conditions on biocrude yields from fast hydrothermal liquefaction of microalgae.

    PubMed

    Faeth, Julia L; Savage, Phillip E

    2016-04-01

    This study investigated the effects of algae species, reaction time, and reactor loading on the biocrude yield from fast hydrothermal liquefaction (HTL) of microalgae. Fast HTL reaction times were always less than 2 min and employed rapid heating and nonisothermal conditions. The highest biocrude yield obtained was 67±5 wt.% (dry basis). With all other process variables fixed, increasing the reaction time in a 600 °C sand bath by 15 s increments led to a rapid increase in biocrude yield between 15 and 45 s. At longer times, the biocrude yield decreased. Low reactor loadings generally gave higher biocrude yields than did higher loadings. The low reactor loadings may facilitate biocrude production by facilitating cell rupture and/or increasing the effective concentration of algal cells in the hot, compressed water in the reactor.

  7. Hydrothermally processed TiO2 nanowire electrodes with antireflective and electrochromic properties.

    PubMed

    Chen, Jing-Zhi; Ko, Wen-Yin; Yen, Yin-Cheng; Chen, Po-Hung; Lin, Kuan-Jiuh

    2012-08-28

    Dual functionalities of antireflective and electrochromic properties-based anatase TiO(2) nanowire devices with a high-porosity cross-linked geometry directly grown onto transparent conductive glass was achieved for the first time through a simple one-step hydrothermal process under mild alkali conditions. Devices fashioned from these TiO(2) nanowires were found to display enhanced optical transparency in the visible range, better color contrast, and faster color-switching time in comparison to devices made from nanoparticles. These improvements can be attributed to the low refractive index and high porosity of the TiO(2) nanowires and their larger accessible surface area for Li(+) intercalation and deintercalation, leading to enhanced capabilities for transparent electrochromic smart windows. PMID:22757633

  8. Mineralogical and geochemical evidence for hydrothermal activity at the west wall of 12°50′N core complex (Mid-Atlantic ridge): a new ultramafic-hosted seafloor hydrothermal deposit?

    USGS Publications Warehouse

    Dekov, Vesselin; Boycheva, Tanya; Halenius, Ulf; Billstrom, Kjell; Kamenov, George D.; Shanks, Wayne C.; Stummeyer, Jens

    2011-01-01

    Dredging along the west wall of the core complex at 12°50′N Mid-Atlantic Ridge sampled a number of black oxyhydroxide crusts and breccias cemented by black and dark brown oxyhydroxide matrix. Black crusts found on top of basalt clasts (rubble) are mainly composed of Mn-oxides (birnessite, 10-Å manganates) with thin films of nontronite and X-ray amorphous FeOOH on their surfaces. Their chemical composition (low trace- and rare earth-element contents, high Li and Ag concentrations, rare earth element distribution patterns with negative both Ce and Eu anomalies), Sr–Nd–Pb-isotope systematic and O-isotope data suggest low-temperature (~ 20 °C) hydrothermal deposition from a diffuse vent area on the seafloor. Mineralogical, petrographic and geochemical investigations of the breccias showed the rock clasts were hydrothermally altered fragments of MORBs. Despite the substantial mineralogical changes caused by the alteration the Sr–Nd–Pb-isotope ratios have not been significantly affected by this process. The basalt clasts are cemented by dark brown and black matrix. Dark brown cement exhibits geochemical features (very low trace- and rare earth- element contents, high U concentration, rare earth element distribution pattern with high positive Eu anomaly) and Nd–Pb-isotope systematics (similar to that of MORB) suggesting that the precursor was a primary, high-temperature Fe-sulfide, which was eventually altered to goethite at ambient seawater conditions. The data presented in this work points towards the possible existence of high- and low-temperature hydrothermal activity at the west wall of the core complex at 12°50′N Mid-Atlantic Ridge. Tectonic setting at the site implies that the proposed hydrothermal field is possibly ultramafic-hosted.

  9. Evolution of magmatic and hydrothermal activity in the western Arctic and North Atlantic regions

    NASA Astrophysics Data System (ADS)

    Sorokhtin, N. O.; Lobkovsky, L. I.; Novikov, G. V.; Kozlov, E. E.; Bogdanova, O. Yu.; Nikiforov, S. L.

    2016-07-01

    This paper discusses the geodynamic evolution of the lithosphere in the Arctic region during the Phaneorozic and its polyphase lithotectonic reorganization. Spatiotemporal patterns of the mosaic junction of lithospheric plates of different age are presented for the Caledonian-Hercynian stage and for the Cenozoic evolution of the North Atlantic and Arctic oceanic basins. Special attention is given to the intersections of fault systems with different kinematics, which control the manifestation of peculiar magmatism and the formation of numerous mineral deposits. It is shown that the hydrothermal activity of the region is related to the ocean opening in the Eocene and is confined to the mid-ocean ridge.

  10. Tunable ZnO spheres with high anti-biofilm and antibacterial activity via a simple green hydrothermal route.

    PubMed

    Patrinoiu, Greta; Calderón-Moreno, José Maria; Chifiriuc, Carmen Mariana; Saviuc, Crina; Birjega, Ruxandra; Carp, Oana

    2016-01-15

    A family of distinct ZnO morphologies - hollow, compartmented, core-shell and full solid ZnO spheres, dispersed or interconnected - is obtained by a simple hydrothermal route, in the presence of the starch biopolymer. The zinc-carbonaceous precursors were characterized by infrared spectroscopy, thermal analysis and scanning electron microscopy, while the ZnO spheres, obtained after the thermal processing, were investigated by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, UV-VIS spectroscopy, photoluminescence measurements, antimicrobial, anti-biofilm and flow cytometry tests. The formation mechanism proposed for this versatile synthesis route is based on the gelling ability of amylose, one of the starch template constituents, responsible for the effective embedding of zinc cations into starch prior to its hydrothermal carbonization. The simple variation of the raw materials concentration dictates the type of ZnO spheres. The micro-sized ZnO spheres exhibit high antibacterial and anti-biofilm activity against Gram-positive (Staphylococcus aureus, Bacillus subtilis) and Gram-negative (Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa) reference and methicillin resistant clinical strains especially for Gram-negative biofilms (P. aeruginosa), demonstrating great potential for new ZnO anti-biofilm formulations. PMID:26433479

  11. Discovery of hydrothermally active and extinct talc mounds on the Mid-Cayman Rise

    NASA Astrophysics Data System (ADS)

    Hodgkinson, M.; Murton, B. J.; Roberts, S.

    2013-12-01

    Since 1977, hydrothermal vents have been the subject of intense scientific interest due to their role in cooling the oceanic crust and global geochemical cycles. Until now, two types of hydrothermal system have been identified: one, driven by magmatic heat extruding ';black smoker' fluids; and another, involving serpentinisation of ultramafic rocks and the precipitation of carbonate/brucite chimneys. Here, we present details of a new, off-axis type of hydrothermal system consisting of mounds of predominately botryoidal talc (a magnesium-silicate) with accessory silica and copper sulphides, and chimneys exhaling fluids of moderate temperature and pH. Discovered on the Mid-Cayman Rise (MCR) in 2010, the Von Damm Vent Field (VDVF) features a NNW-ESE-trending line of four overlapping cones, the largest of which is 75 m high by 150 m in diameter. The VDVF is hosted in the gabbroic footwall of the Mount Dent Oceanic Core Complex (MDOCC), which includes serpentinised peridotite at depth. The largest cone vents clear fluids from two main orifices at its summit, with primary temperatures of 215°C. Elsewhere, both focussed and diffuse flow areas emit fluids with temperatures of up to 150°C. The surrounding ~1 m thick pelagic sediment contains abundant pockmarks that emit methane-rich fluids at temperatures of less than 10°C. During the return to the MCR in early 2013, several other talc mounds were discovered within a kilometre of the active VDVF. These inactive mounds also comprise an assemblage of botryoidal talc, silica, disseminated sulphides (including chalcopyrite) and sulphates. One of these mounds (Mystic Mount) is double the volume of the active VDVF. The unique dominance of talc as the major mineral forming the hydrothermal structures indicates unusual vent fluid compositions that are able to carry both copper (at high-temperatures) and precipitate magnesium silicate. Thermodynamic modelling indicates that talc precipitates on mixing a moderately acidic, silica

  12. Key Factors Influencing Rates of Heterotrophic Sulfate Reduction in Active Seafloor Hydrothermal Massive Sulfide Deposits.

    PubMed

    Frank, Kiana L; Rogers, Karyn L; Rogers, Daniel R; Johnston, David T; Girguis, Peter R

    2015-01-01

    Hydrothermal vents are thermally and geochemically dynamic habitats, and the organisms therein are subject to steep gradients in temperature and chemistry. To date, the influence of these environmental dynamics on microbial sulfate reduction has not been well constrained. Here, via multivariate experiments, we evaluate the effects of key environmental variables (temperature, pH, H2S, [Formula: see text], DOC) on sulfate reduction rates and metabolic energy yields in material recovered from a hydrothermal flange from the Grotto edifice in the Main Endeavor Field, Juan de Fuca Ridge. Sulfate reduction was measured in batch reactions across a range of physico-chemical conditions. Temperature and pH were the strongest stimuli, and maximum sulfate reduction rates were observed at 50°C and pH 6, suggesting that the in situ community of sulfate-reducing organisms in Grotto flanges may be most active in a slightly acidic and moderate thermal/chemical regime. At pH 4, sulfate reduction rates increased with sulfide concentrations most likely due to the mitigation of metal toxicity. While substrate concentrations also influenced sulfate reduction rates, energy-rich conditions muted the effect of metabolic energetics on sulfate reduction rates. We posit that variability in sulfate reduction rates reflect the response of the active microbial consortia to environmental constraints on in situ microbial physiology, toxicity, and the type and extent of energy limitation. These experiments help to constrain models of the spatial contribution of heterotrophic sulfate reduction within the complex gradients inherent to seafloor hydrothermal deposits.

  13. Key Factors Influencing Rates of Heterotrophic Sulfate Reduction in Active Seafloor Hydrothermal Massive Sulfide Deposits

    PubMed Central

    Frank, Kiana L.; Rogers, Karyn L.; Rogers, Daniel R.; Johnston, David T.; Girguis, Peter R.

    2015-01-01

    Hydrothermal vents are thermally and geochemically dynamic habitats, and the organisms therein are subject to steep gradients in temperature and chemistry. To date, the influence of these environmental dynamics on microbial sulfate reduction has not been well constrained. Here, via multivariate experiments, we evaluate the effects of key environmental variables (temperature, pH, H2S, SO42−, DOC) on sulfate reduction rates and metabolic energy yields in material recovered from a hydrothermal flange from the Grotto edifice in the Main Endeavor Field, Juan de Fuca Ridge. Sulfate reduction was measured in batch reactions across a range of physico-chemical conditions. Temperature and pH were the strongest stimuli, and maximum sulfate reduction rates were observed at 50°C and pH 6, suggesting that the in situ community of sulfate-reducing organisms in Grotto flanges may be most active in a slightly acidic and moderate thermal/chemical regime. At pH 4, sulfate reduction rates increased with sulfide concentrations most likely due to the mitigation of metal toxicity. While substrate concentrations also influenced sulfate reduction rates, energy-rich conditions muted the effect of metabolic energetics on sulfate reduction rates. We posit that variability in sulfate reduction rates reflect the response of the active microbial consortia to environmental constraints on in situ microbial physiology, toxicity, and the type and extent of energy limitation. These experiments help to constrain models of the spatial contribution of heterotrophic sulfate reduction within the complex gradients inherent to seafloor hydrothermal deposits. PMID:26733984

  14. Key Factors Influencing Rates of Heterotrophic Sulfate Reduction in Active Seafloor Hydrothermal Massive Sulfide Deposits.

    PubMed

    Frank, Kiana L; Rogers, Karyn L; Rogers, Daniel R; Johnston, David T; Girguis, Peter R

    2015-01-01

    Hydrothermal vents are thermally and geochemically dynamic habitats, and the organisms therein are subject to steep gradients in temperature and chemistry. To date, the influence of these environmental dynamics on microbial sulfate reduction has not been well constrained. Here, via multivariate experiments, we evaluate the effects of key environmental variables (temperature, pH, H2S, [Formula: see text], DOC) on sulfate reduction rates and metabolic energy yields in material recovered from a hydrothermal flange from the Grotto edifice in the Main Endeavor Field, Juan de Fuca Ridge. Sulfate reduction was measured in batch reactions across a range of physico-chemical conditions. Temperature and pH were the strongest stimuli, and maximum sulfate reduction rates were observed at 50°C and pH 6, suggesting that the in situ community of sulfate-reducing organisms in Grotto flanges may be most active in a slightly acidic and moderate thermal/chemical regime. At pH 4, sulfate reduction rates increased with sulfide concentrations most likely due to the mitigation of metal toxicity. While substrate concentrations also influenced sulfate reduction rates, energy-rich conditions muted the effect of metabolic energetics on sulfate reduction rates. We posit that variability in sulfate reduction rates reflect the response of the active microbial consortia to environmental constraints on in situ microbial physiology, toxicity, and the type and extent of energy limitation. These experiments help to constrain models of the spatial contribution of heterotrophic sulfate reduction within the complex gradients inherent to seafloor hydrothermal deposits. PMID:26733984

  15. Structural elucidation of sorghum lignins from an integrated biorefinery process based on hydrothermal and alkaline treatments.

    PubMed

    Sun, Shao-Long; Wen, Jia-Long; Ma, Ming-Guo; Sun, Run-Cang

    2014-08-13

    An integrated process based on hydrothermal pretreatment (HTP) (i.e., 110-230 °C, 0.5-2.0 h) and alkaline post-treatment (2% NaOH at 90 °C for 2.0 h) has been performed for the production of xylooligosaccharide, lignin, and digestible substrate from sweet sorghum stems. The yield, purity, dissociation mechanisms, structural features, and structural transformations of alkali lignins obtained from the integrated process were investigated. It was found that the HTP process facilitated the subsequent alkaline delignification, releasing lignin with the highest yield (79.3%) and purity from the HTP residue obtained at 190 °C for 0.5 h. All of the results indicated that the cleavage of the β-O-4 linkages and degradation of β-β and β-5 linkages occurred under the harsh HTP conditions. Depolymerization and condensation reactions simultaneously occurred at higher temperatures (≥ 170 °C). Moreover, the thermostability of lignin was positively related to its molecular weight, but was also affected by the inherent structures, such as β-O-4 linkages and condensed units. These findings will enhance the understanding of structural transformations of the lignins during the integrated process and maximize the potential utilizations of the lignins in a current biorefinery process.

  16. Fundamental chemistry and thermodynamics of hydrothermal oxidation processes. 1998 annual progress report

    SciTech Connect

    Simonson, J.M.; Mesmer, R.E.; Blencoe, J.G.; Cummings, P.T.; Chialvo, A.A.

    1998-06-01

    'The objective of this research program is to provide fundamental scientific information on the physical and chemical properties of solutes in aqueous solutions at high temperatures needed to assess and enhance the applicability of hydrothermal oxidation (HTO) to the remediation of DOE hazardous and mixed wastes. Potential limitations to the use of HTO technology include formation of deposits (scale) from precipitation of inorganic solutes in the waste, corrosion arising from formation of strong acids on oxidation of some organic compounds (e.g., chlorinated hydrocarbons), and unknown effects of fluid density and phase behavior at high temperatures. Focus areas for this project include measurements of the solubility and speciation of actinides and surrogates in model HTO process streams at high temperatures, and the experimental and theoretical development of equations of state for aqueous mixtures under HTO process conditions ranging above the critical temperature of water. A predictive level of understanding of the chemical and physical properties of HTO process streams is being developed through molecular-level simulations of aqueous solutions at high temperatures. Advances in fundamental understanding of phase behavior, density, and solute speciation at high temperatures and pressures contribute directly to the ultimate applicability of this process for the treatment of DOE hazardous and mixed wastes. Research in this project has been divided into individual tasks, with each contributing to a unified understanding of HTO processing problems related to the treatment of DOE wastes. This report summarizes progress attained after slightly less than two years of this three-year project.'

  17. Hydrothermal gasification of waste biomass: process design and life cycle asessment.

    PubMed

    Luterbacher, Jeremy S; Fröling, Morgan; Vogel, Frederic; Maréchal, François; Tester, Jefferson W

    2009-03-01

    A process evaluation methodology is presented that incorporates flowsheet mass and energy balance modeling, heat and power integration, and life cycle assessment Environmental impacts are determined by characterizing and weighting (using CO2 equivalents, Eco-indicator 99, and Eco-scarcity) the flowsheet and inventory modeling results. The methodology is applied to a waste biomass to synthetic natural gas (SNG) conversion process involving a catalytic hydrothermal gasification step. Several scenarios are constructed for different Swiss biomass feedstocks and different scales depending on logistical choices: large-scale (155 MW(SNG)) and small-scale (5.2 MW(SNG)) scenarios for a manure feedstock and one scenario (35.6 MW(SNG))for a wood feedstock. Process modeling shows that 62% of the manure's lower heating value (LHV) is converted to SNG and 71% of wood's LHV is converted to SNG. Life cycle modeling shows that, for all processes, about 10% of fossil energy use is imbedded in the produced renewable SNG. Converting manure and replacing it, as a fertilizer, with the process mineral byproduct leads to reduced N20 emissions and an improved environmental performance such as global warming potential: -0.6 kg(CO2eq)/MJ(SNG) vs. -0.02 kg(CO2eq)/MJ(SNG) for wood scenarios.

  18. Living with the Heat. Submarine Ring of Fire--Grades 5-6. Hydrothermal Vent Ecology.

    ERIC Educational Resources Information Center

    National Oceanic and Atmospheric Administration (DOC), Rockville, MD.

    This activity is designed to teach about hydrothermal vent ecology. Students are expected to describe how hydrothermal vents are formed and characterize the physical conditions at these sites, explain chemosynthesis and contrast this process with photosynthesis, identify autotrophic bacteria as the basis for food webs in hydrothermal vent…

  19. Xenopumice erupted on 15 October 2011 offshore of El Hierro (Canary Islands): a subvolcanic snapshot of magmatic, hydrothermal and pyrometamorphic processes

    NASA Astrophysics Data System (ADS)

    Del Moro, S.; Di Roberto, A.; Meletlidis, S.; Pompilio, M.; Bertagnini, A.; Agostini, S.; Ridolfi, F.; Renzulli, A.

    2015-06-01

    On 15 October 2011, a submarine eruption offshore of El Hierro Island gave rise to floating volcanic products, known as xenopumices, i.e., pumiceous xenoliths partly mingled and coated with the juvenile basanitic magma. Over the last few years, no consensus in the scientific community in explaining the origin of these products has been reached. In order to better understand the formation of xenopumice, we present a textural, mineralogical, and geochemical study of the possible magmatic, hydrothermal, and pyrometamorphic processes, which usually operate in the plumbing systems of active volcanoes. We carried out a comprehensive SEM investigation and Sr-Nd-Pb isotope analyses on some samples representative of three different xenopumice facies. All the data were compared with previous studies, new data for El Hierro extrusives and a literature dataset of Canary Islands igneous and sedimentary rocks. In the investigated xenopumices, we emphasize the presence of restitic magmatic phases as well as crystallization of minerals (mainly olivine + pyroxene + magnetite aggregates) as pseudomorphs after pre-existing mafic phenocrysts, providing evidence of pyrometamorphism induced by the high-T juvenile basanitic magma. In addition, we identify veins consisting of zircon + REE-oxides + mullite associated with Si-rich glass and hydrothermal quartz, which indicate the fundamental role played by hydrothermal fluid circulation in the xenopumice protolith. The petrological data agree with a pre-syneruptive formation of the xenopumice, when El Hierro basanite magma intruded hydrothermally altered trachyandesite to trachyte rocks and triggered local partial melting. Therefore, the El Hierro xenopumice represents a snapshot of the transient processes at the magma-wall rock interface, which normally occurs in the feeding system of active volcanoes.

  20. Distribution of Hydrothermal Activity at the Lau ISS: Possible Controlling Parameters

    NASA Astrophysics Data System (ADS)

    Martinez, F.; Baker, E. T.; Resing, J. A.; Edwards, M. H.; Walker, S. L.; Buck, N.

    2008-12-01

    Seismic tomographic studies of intermediate to fast spreading rate mid-ocean ridges (MORs) interpret zones of rapid crustal cooling a few (3-4) km off axis surrounding the axial seismic low velocity zone (LVZ). These zones of rapid cooling also broadly correlate with the initiation and growth of large abyssal hill faults. The close association of both high thermal gradients and development of fault permeability at crustal scales suggests the hypothesis that these areas may be favorable locations for off-axis high temperature hydrothermal activity. In March-May 2008 on R/V Kilo Moana we conducted a near-bottom sidescan sonar and oceanographic survey along the Eastern Lau Spreading Center (ELSC) and Valu Fa Ridge (VFR) in the Lau back-arc basin to map the distribution of hydrothermal activity within this region. The survey utilized the deep-towed DSL120A (IMI120) sonar, an array of miniature autonomous plume recorders (MAPRs) attached to the tow cable and tethered beneath the sonar's depressor weight, an in situ chemical scanner (VISA) and 23 CTD hydrocasts (see Baker et al., this session). At the ELSC the survey spanned ~100 x 10 km area encompassing the ABE, Tow Cam and Kilo Moana vent fields with ~ 1 km spaced lines overall and ~500 m spaced lines in the area of the ABE vent field. On the VFR the survey spanned a distance of ~100 km along axis by ~5 km across axis with 700 m spaced lines encompassing the Vai Lili, Mariner and Tui Malila vent sites. Initial results identified particle plumes, indicative of high temperature venting, only within about a km of the ridge axis at the ELSC and VFR with possible diffuse venting indicated by MAPR oxidation-reduction potential (ORP) measurements at flank sites at VFR. The expanded sonar coverage better defines the volcano-tectonic context of the hydrothermal signals and previously mapped vent sites. Initial results suggest, however, no high-T venting more than about 1 km from the ridge axis, an apparently negative test of

  1. Green synthesis of silver nanoparticles in aloe vera plant extract prepared by a hydrothermal method and their synergistic antibacterial activity

    PubMed Central

    Phromviyo, Nutthakritta; Boueroy, Parichart; Chompoosor, Apiwat

    2016-01-01

    Background There is worldwide interest in silver nanoparticles (AgNPs) synthesized by various chemical reactions for use in applications exploiting their antibacterial activity, even though these processes exhibit a broad range of toxicity in vertebrates and invertebrates alike. To avoid the chemical toxicity, biosynthesis (green synthesis) of metal nanoparticles is proposed as a cost-effective and environmental friendly alternative. Aloe vera leaf extract is a medicinal agent with multiple properties including an antibacterial effect. Moreover the constituents of aloe vera leaves include lignin, hemicellulose, and pectins which can be used in the reduction of silver ions to produce as AgNPs@aloe vera (AgNPs@AV) with antibacterial activity. Methods AgNPs were prepared by an eco-friendly hydrothermal method using an aloe vera plant extract solution as both a reducing and stabilizing agent. AgNPs@AV were characterized using XRD and SEM. Additionally, an agar well diffusion method was used to screen for antimicrobial activity. MIC and MBC were used to correlate the concentration of AgNPs@AV its bactericidal effect. SEM was used to investigate bacterial inactivation. Then the toxicity with human cells was investigated using an MTT assay. Results The synthesized AgNPs were crystalline with sizes of 70.70 ± 22-192.02 ± 53 nm as revealed using XRD and SEM. The sizes of AgNPs can be varied through alteration of times and temperatures used in their synthesis. These AgNPs were investigated for potential use as an antibacterial agent to inhibit pathogenic bacteria. Their antibacterial activity was tested on S. epidermidis and P. aeruginosa. The results showed that AgNPs had a high antibacterial which depended on their synthesis conditions, particularly when processed at 100 oC for 6 h and 200 oC for 12 h. The cytotoxicity of AgNPs was determined using human PBMCs revealing no obvious cytotoxicity. These results indicated that AgNPs@AV can be effectively utilized in

  2. Aqueous Volatiles in Hydrothermal fluids from the Main Endeavour Vent Field: Temporal Variability Following Earthquake Activity

    NASA Astrophysics Data System (ADS)

    Seewald, J. S.; Cruse, A. M.; Saccocia, P. J.

    2001-12-01

    Volatile species play a critical role in a broad spectrum of physical, chemical, and biological processes associated with hydrothermal circulation at oceanic spreading centers. Earthquake activity at the Main Endeavour vent field, northern Juan de Fuca Ridge in June 1999 [1] provided and opportunity to assess factors that regulate the flux of volatile species from the oceanic crust to the water column following a rapid change in subsurface reaction zone conditions. High temperature vent fluids were collected in gas-tight samplers at the Main Endeavour field in September 1999, approximately four months after the earthquakes, and again in July 2000, and were analyzed for the abundance of aqueous volatile and non-volatile species. Measured concentrations of aqueous H2, H2S, and CO2 increased substantially in September 1999 relative to pre-earthquake values [2,3], and subsequently decreased in July 2000, while aqueous Cl concentrations initially decreased in 1999 and subsequently increased in 2000. Concentrations of Cl in all fluids were depleted relative to seawater values. Aqueous CH4 and NH3 concentrations decreased in both the 1999 and 2000 samples relative to pre- earthquake values. Variations in Cl concentration of Endeavour fluids reflect varying degrees of phase separation under near critical temperature and pressure conditions. Because volatile species efficiently partition into the vapor phase, variations in their abundance as a function of Cl concentration can be used to constrain conditions of phase separation and fluid-rock interaction. For example, concentrations of volatile species that are not readily incorporated into minerals (CH4 and NH3) correlated weakly with Cl suggesting phase separation was occurring under supercritical conditions after the earthquake activity. In contrast, compositional data for fluids prior to the earthquakes indicate a strong negative correlation between these species and Cl suggesting phase separation under subcritical

  3. Sulfur Isotope Chemistry of the Uzon Caldera Active Hydrothermal System, Kamchatka, Far-East Russia

    NASA Astrophysics Data System (ADS)

    Hollingsworth, E. R.; Crowe, D. E.

    2006-05-01

    The Uzon Caldera is an actively precipitating As-Sb-Au epithermal system located on the Kamchatka Peninsula of Far-East Russia. Present at the surface of the caldera is a remarkable diversity of thermal fluid types discharging within the geothermal fields. These fluids have subsequently produced a broad array of S- bearing alteration minerals both within and around pools, hotsprings, mudpots, and fumaroles. Using the δD/δ18O/δ34S and dissolved ion chemistry of the thermal fluids, three types were distinguished as follows: 1) an acid sulfate type with δD/δ18O/δ34S values ranging between -74.66‰ to -100.33‰, - 2.30‰ to -9.57‰, and -0.3‰ to 0.3‰ respectively with sulfate being the dominant anion ranging between 504ppm and 3439ppm 2) an alkali chloride type with δD/δ18O/δ34S values ranging between -97.22‰ to -104.37‰, - 8.8‰ to -11.43‰ respectively with chloride being the dominant anion ranging between 1090ppm to 2405ppm, and 3) a dilute type resulting from the mixture of the alkali-chloride endmember with the cold meteoric waters present at the surface subsequently generating δD/δ18O/δ34S values ranging between -82.00‰ to -119.34‰, -6.02‰ to -15.76‰, and +1.9‰ to +13.5‰ with dissolved ion concentrations falling along a mixing line between the two endmember components. The interpretations made from the presence of these three fluid types were used in conjunction with the δ34S of the S-bearing alteration minerals from within and around the various water and gas sources (values ranging between -1.94‰ to +5.7‰ and -5.19‰ to +1.6‰ respectively) to construct a sulfur evolution model for the Uzon's hydrothermal system. Results of the model show the chemical and isotopic processes responsible for the speciation and isotopic signature of the S-bearing phases collected at the surface (both aqueous and mineral) are not only dictated by the geologic processes at depth, but are also influenced by microbiological processes at the

  4. Synthesis of ZnO nanorod–nanosheet composite via facile hydrothermal method and their photocatalytic activities under visible-light irradiation

    SciTech Connect

    Tan, Wai Kian; Abdul Razak, Khairunisak; Lockman, Zainovia; Kawamura, Go; Muto, Hiroyuki; Matsuda, Atsunori

    2014-03-15

    ZnO composite films consisting of ZnO nanorods and nanosheets were prepared by low-temperature hydrothermal processing at 80 °C on seeded glass substrates. The seed layer was coated on glass substrates by sol–gel dip-coating and pre-heated at 300 °C for 10 min prior to hydrothermal growth. The size of the grain formed after pre-heat treatment was ∼40 nm. A preferred orientation seed layer at the c-axis was obtained, which promoted vertical growth of the ZnO nanorod arrays and formation of the ZnO nanosheets. X-ray diffraction patterns and high-resolution transmission electron microscope (HR-TEM) images confirmed that the ZnO nanorods and nanosheets consist of single crystalline and polycrystalline structures, respectively. Room temperature photoluminescence spectra of the ZnO nanorod–nanosheet composite films exhibited band-edge ultraviolet (UV) and visible emission (blue and green) indicating the formation of ZnO crystals with good crystallinity and are supported by Raman scattering results. The formation of one-dimensional (1D) ZnO nanorod arrays and two-dimensional (2D) ZnO nanosheet films using seeded substrates in a single low-temperature hydrothermal step would be beneficial for realization of device applications that utilize substrates with limited temperature stability. The ZnO nanorods and nanosheets composite structure demonstrated higher photocatalytic activity during degradation of aqueous methylene blue under visible-light irradiation. -- Graphical abstract: Schematic illustration of ZnO nanorod–nanosheet composite structure formation by hydrothermal at low-temperature of 80 °C against time. Highlights: • Novel simultaneous formation of ZnO nanorods and nanosheets composite structure. • Facile single hydrothermal step formation at low-temperature. • Photoluminescence showed ultraviolet and visible emission. • Feasible application on substrates with low temperature stability. • Improved photocatalytic activity under visible

  5. Enhanced hydrothermal activity along the East Pacific Rise during the last two glacial terminations

    NASA Astrophysics Data System (ADS)

    Lund, D. C.; Asimow, P. D.; Farley, K. A.

    2015-12-01

    Mid-ocean ridge magmatism is driven by seafloor spreading and decompression melting of the upper mantle. Scaling estimates [1-2] and model results [3-4] indicate that glacial-interglacial changes in sea level should modulate melt production at mid-ocean ridges, an idea that has been confirmed with detailed surveys of ridge bathymetry [4-5]. The nature and timing of associated changes in hydrothermal activity have remained unknown, however, precluding a clear understanding of whether ridge magmatism can act as a negative feedback on ice sheet size. Here we present multiple records of hydrothermal sedimentation spanning 1300 km of the East Pacific Rise (EPR). At each location, the flux of Fe, Mn, and As increased beginning at ~25 kyr BP, reached maximum values by 15 kyr BP, and then decreased into the Holocene. Lateral sediment focusing is an unlikely explanation given the similar signal in multiple cores and the lack of evidence for anomalous horizontal transport in 3He-based focusing factors. Coherent variations in Fe, Mn, and As suggest that diagenetic overprinting is not the primary driver of the down core signal. Elevated metal fluxes also occur during Termination II. The time series of hydrothermal sedimentation bear a strong resemblance to a record of seafloor bathymetry from 17ºS [5], suggesting that both have a common driver. The simplest explanation is glacial-interglacial variations in sea level, which apparently modulates sub-ridge melting, seafloor bathymetry, and hydrothermal activity at the EPR. Our results imply that geothermal heat flux from ridges increases during the last two glacial terminations, which should act to erode the deep ocean stratification, enhance the abyssal circulation, and transmit excess heat to the Southern Ocean, thereby setting the stage for deglaciation. [1] Lund and Asimow (2008) AGU Fall Meeting, Abstract #PP11D-08. [2] Huybers and Langmuir (2009) Earth and Planetary Science Letters 286, 479-491. [3] Lund and Asimow (2011

  6. Ore-bearing hydrothermal metasomatic processes in the Elbrus volcanic center, the northern Caucasus, Russia

    NASA Astrophysics Data System (ADS)

    Gurbanov, A. G.; Bogatikov, O. A.; Dokuchaev, A. Ya.; Gazeev, V. M.; Abramov, S. S.; Groznova, E. O.; Shevchenko, A. V.

    2008-06-01

    Precaldera, caldera, and postcaldera cycles are recognized in the geological evolution of the Pleistocene-Holocene Elbrus volcanic center (EVC). During the caldera cycle, the magmatic activity was not intense, whereas hydrothermal metasomatic alteration of rocks was vigorous and extensive. The Kyukyurtli and Irik ore-magmatic systems have been revealed in the EVC, with the former being regarded as the more promising one. The ore mineralization in rocks of the caldera cycle comprises occurrences of magnetite, ilmenite, pyrite and pyrrhotite (including Ni-Co varieties), arsenopyrite, chalcopyrite, millerite, galena, and finely dispersed particles of native copper. Pyrite and pyrrhotite from volcanics of the caldera cycle and dacite of the Kyukyurtli extrusion are similar in composition and differ from these minerals of the postcaldera cycle, where pyrite and pyrrhotite are often enriched in Cu, Co, and Ni and millerite is noted as well. The composition of ore minerals indicates that the hydrothermal metasomatic alteration related to the evolution of the Kyukyurtli hydrothermal system was superimposed on rocks of the caldera cycle, whereas the late mineralization in rocks of the postcaldera cycle developed autonomously. The homogenization temperature of fluid inclusions in quartz and carbonate from crosscutting veinlets in the apical portion of the Kyukyurtli extrusion is 140-170°C and in quartz from geyserite, 120-150°C. The temperature of formation of the chalcopyrite-pyrite-pyrrhotite assemblage calculated using mineral geothermometers is 156 and 275°C in dacite from the middle and lower portions of the Malka lava flow and 190°C in dacite of the Kyukyurtli extrusion. The hydrothermal solutions that participated in metasomatic alteration of rocks pertaining to the Kyukyurtli ore-magmatic system (KOMS) and formed both secondary quartzite and geyserite were enriched in fluorine, as evidenced from the occurrence of F-bearing minerals-zharchikhite, ralstonite,

  7. Extensive hydrothermal activity revealed by multi-tracer survey in the Wallis and Futuna region (SW Pacific)

    NASA Astrophysics Data System (ADS)

    Konn, C.; Fourré, E.; Jean-Baptiste, P.; Donval, J. P.; Guyader, V.; Birot, D.; Alix, A. S.; Gaillot, A.; Perez, F.; Dapoigny, A.; Pelleter, E.; Resing, J. A.; Charlou, J. L.; Fouquet, Y.

    2016-10-01

    The study area is close to the Wallis and Futuna Islands in the French EEZ. It exists on the western boundary of the fastest tectonic area in the world at the junction of the Lau and North-Fiji basins. At this place, the unstable back-arc accommodates the plate motion in three ways: (i) the north Fiji transform fault, (ii) numerous unstable spreading ridges, and (iii) large areas of recent volcanic activity. This instability creates bountiful opportunity for hydrothermal discharge to occur. Based on geochemical (CH4, TDM, 3He) and geophysical (nephelometry) tracer surveys: (1) no hydrothermal activity could be found on the Futuna Spreading Centre (FSC) which sets the western limit of hydrothermal activity; (2) four distinct hydrothermal active areas were identified: Kulo Lasi Caldera, Amanaki Volcano, Fatu Kapa and Tasi Tulo areas; (3) extensive and diverse hydrothermal manifestations were observed and especially a 2D distribution of the sources. At Kulo Lasi, our data and especially tracer ratios (CH4/3He 50×106 and CH4/TDM 4.5) reveal a transient CH4 input, with elevated levels of CH4 measured in 2010, that had vanished in 2011, most likely caused by an eruptive magmatic event. By contrast at Amanaki, vertical tracer profiles and tracer ratios point to typical seawater/basalt interactions. Fatu Kapa is characterised by a substantial spatial variability of the hydrothermal water column anomalies, most likely due to widespread focused and diffuse hydrothermal discharge in the area. In the Tasi Tulo zone, the hydrothermal signal is characterised by a total lack of turbidity, although other tracer anomalies are in the same range as in nearby Fatu Kapa. The background data set revealed the presence of a Mn and 3He chronic plume due to the extensive and cumulative venting over the entire area. To that respect, we believe that the joined domain composed of our active area and the nearby active area discovered in the East by Lupton et al. (2012) highly contribute to the

  8. Mass transfer constraints on the chemical evolution of an active hydrothermal system, Valles caldera, New Mexico

    USGS Publications Warehouse

    White, A.F.; Chuma, N.J.; Goff, F.

    1992-01-01

    Partial equilibrium conditions occur between fluids and secondary minerals in the Valles hydrothermal system, contained principally in the Tertiary rhyolitic Bandelier Tuff. The mass transfer processes are governed by reactive phase compositions, surface areas, water-rock ratios, reaction rates, and fluid residence times. Experimental dissolution of the vitric phase of the tuff was congruent with respect to Cl in the solid and produced reaction rates which obeyed a general Arrhenius release rate between 250 and 300??C. The 18O differences between reacted and unreacted rock and fluids, and mass balances calculations involving Cl in the glass phase, produced comparable water-rock ratios of unity, confirming the importance of irreversible reaction of the vitric tuff. A fluid residence time of approximately 2 ?? 103 years, determined from fluid reservoir volume and discharge rates, is less than 0.2% of the total age of the hydrothermal system and denotes a geochemically and isotopically open system. Mass transfer calculations generally replicated observed reservoir pH, Pco2, and PO2 conditions, cation concentrations, and the secondary mineral assemblage between 250 and 300??C. The only extraneous component required to maintain observed calcite saturation and high Pco2 pressures was carbon presumably derived from underlying Paleozoic limestones. Phase rule constraints indicate that Cl was the only incompatible aqueous component not controlled by mineral equilibrium. Concentrations of Cl in the reservoir directly reflect mass transport rates as evidenced by correlations between anomalously high Cl concentrations in the fluids and tuff in the Valles caldera relative to other hydrothermal systems in rhyolitic rocks. ?? 1992.

  9. Heat Source for Active Venting at the Lost City Hydrothermal Field

    NASA Astrophysics Data System (ADS)

    Smith, J. E.; Germanovich, L. N.; Lowell, R. P.

    2014-12-01

    Located at the inside corner high of the Mid-Atlantic Ridge (MAR), 30°N and the Atlantis Transform Fault (ATF), the Atlantis Massif has been uplifted over the past ~2 my. The Southern Ridge of this massif hosts the Lost City Hydrothermal Field (LCHF), an off-axis hydrothermal vent field with carbonate chimney ages surpassing 120,000 yrs. The fluids discharging at LCHF carry geochemical signals that show a direct interaction with serpentinites. However, mineralogical evidence suggests that peridotite hydration began early in the formation of oceanic core complexes and previous modeling results indicate that serpentinization is unlikely to generate the heat necessary to maintain current levels of discharge at LCHF. This work develops a model for the LCHF venting based on the evidence of tectonic strain, detachment faulting, serpentinization, and convective fluid flow. We constrain fluid flow at the LCHF by vent geochemistry, vent temperature, seismically inferred faulting, and expected geothermal gradient ≈100°C/km. Present understanding of tectonic processes at the intersection of MAR and ATF suggests that unroofing of the footwall and crustal flexing of the massif induced normal faults, which run parallel to the MAR, throughout the Southern Ridge. In the absence of the evidence of magmatism, we test the feasibility of the geothermal gradient to cause fluid circulation in the high-permeability, sub-vertical fault zone. Fluid circulation in the fault zone is complemented by the bulk porous flow driven through the Southern Ridge by the lateral temperature gradient between the cold water on the steep face along the ATF side and the hot interior of the massif. In this scenario, the high pH hydrothermal fluids pass through the serpentinized zone before discharging as both high-temperature focused flow (40°-91°C) and low-temperature (≈15°C) diffuse flow at the LCHF.

  10. Removal of strontium and transuranics from Hanford waste via hydrothermal processing -- FY 1994/95 test results

    SciTech Connect

    Orth, R.J.; Schmidt, A.J.; Elmore, M.R.; Hart, T.R.; Neuenschwander, G.G.; Gano, S.R.; Lehmann, R.W.; Momont, J.A.

    1995-09-01

    Under the Tank Waste Remediation System (TWRS) Pretreatment Technology Development Project, Pacific Northwest Laboratory (PNL) is evaluating and developing organic destruction technologies that may be incorporated into the Initial Pretreatment Module (IPM) to treat Hanford tank waste. Organic (and ferrocyanide) destruction removes the compounds responsible for waste safety issues, and conditions the supernatant for low-level waste disposal by removing compounds that may be responsible for promoting strontium and transuranic (TRU) components solubility. Destruction or defunctionalization of complexing organics in tank wastes eliminates organic species that can reduce the efficiency of radionuclide (E.g., {sup 90}Sr) separation processes, such as ion exchange, solvent extraction, and precipitation. The technologies being evaluated and tested for organic destruction are low-temperature hydrothermal processing (HTP) and wet air oxidation (WAO). Four activities are described: Batch HTP/WAO testing with Actual Tank Waste (Section 3.0), Batch HTP Testing with Simulant (Section 4.0), Batch WAO testing with Simulant (Section 5.0), and Continuous Bench-scale WAO Testing with Simulant (Section 6.0). For each of these activities, the objectives, test approach, results, status, and direction of future investigations are discussed. The background and history of the HTP/WAO technology is summarized below. Conclusions and Recommendations are provided in Section 2.0. A continuous HTP off-gas safety evaluation conducted in FY 1994 is included as Appendix A.

  11. Effect of hydrothermal processing on total polyphenolics and antioxidant potential of underutilized leafy vegetables, Boerhaavia diffusa and Portulaca oleracea

    PubMed Central

    Nagarani, Gunasekaran; Abirami, Arumugam; Nikitha, Prasad; Siddhuraju, Perumal

    2014-01-01

    Objective To investigate the effect of different processing methods on antioxidant properties of acetone extract of aerial parts from Boerhaavia diffusa and Portulaca oleracea. Methods The total phenolic and flavonoid contents were determined by Folin-Ciocalteau and aluminum chloride method, respectively. FRAP, metal chelating activity, DPPH, ABTS, nitric oxide, hydroxyl and superoxide radical scavenging activities, carotene/linoleic acid bleaching activity were used for the determination of antioxidant capacity. Results The total phenolics in Boerhaavia diffusa (82.79-162.80 mg GAE/g extract) were found to be higher when compared to that of Portulaca oleracea (22.94-10.02 mg GAE/g extract). Hydrothermal processing enhanced the level of inhibition on synthetic radicals such as DPPH (3 439-309 549 mmol TE/g extract) and ABTS (17 808-53 818 mmol TE/g extract) as well as biologically relevant radicals such as superoxide anion (70%-90%) and nitric oxide (49%-57%). In addition, boiling of the vegetables were found to be maximum capacity of FRAP (6 404.95 mmol Fe (II)/g extract) and metal chelating activity (1.53 mg EDTA/g extract) than the respective raw samples. Conclusions The present investigation suggests that the processing enhance the functionality and improves the availability of bioactive substances of these vegetables. In addition, they also exhibited more potent antioxidant activity. Therefore these natural weeds from the crop land ecosystem could be suggested as cost effective indigenous green vegetables for human diet and potential feed resources for animals. Further extensive studies on role and importance of those weeds in sustaining the agro biodiversity are also needed. PMID:25183131

  12. Hydrothermal synthesis of Graphene-TiO2 nanowire with an enhanced photocatalytic activity

    NASA Astrophysics Data System (ADS)

    Wu, Huitong; Fan, Jun; Yang, Yuhao; Liu, Enzhou; Hu, Xiaoyun; Ma, Yongning; Fan, Xiao; Tang, Chunni

    2015-07-01

    The hydrothermal method was used to synthesize TiO2 nanowire (NW) and then fabricate graphene-TiO2 nanowire nanocomposite (GNW). Graphene oxide (GO) was prepared via improved Hummers'method. GO reduction to graphene and hybridization between NW and graphene by forming chemical bonding. The as-prepared composites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), transmission electron microscopy (TEM), and ultraviolet visible (UV-Vis) diffuse reflectance spectra. The photocatalytic activity was evaluated by the photodegradation of methylene blue (MB). The prepared GNW nanocomposite has superior photocatalytic activity in the degradation test, showing an impressive photocatalytic enhancement over NW. At the same time, in comparison with Graphene-TiO2 nanoparticle (NP) nanocomposite (GNP), GNW have a better activity which because NW have more uniform dispersion on graphene with less agglomeration.

  13. High-resolution water column survey to identify active sublacustrine hydrothermal discharge zones within Lake Rotomahana, North Island, New Zealand

    NASA Astrophysics Data System (ADS)

    Walker, Sharon L.; de Ronde, Cornel E. J.; Fornari, Daniel; Tivey, Maurice A.; Stucker, Valerie K.

    2016-03-01

    Autonomous underwater vehicles were used to conduct a high-resolution water column survey of Lake Rotomahana using temperature, pH, turbidity, and oxidation-reduction potential (ORP) to identify active hydrothermal discharge zones within the lake. Five areas with active sublacustrine venting were identified: (1) the area of the historic Pink Terraces; (2) adjacent to the western shoreline subaerial "Steaming Cliffs," boiling springs and geyser; (3) along the northern shoreline to the east of the Pink Terrace site; (4) the newly discovered Patiti hydrothermal system along the south margin of the 1886 Tarawera eruption rift zone; and (5) a location in the east basin (northeast of Patiti Island). The Pink Terrace hydrothermal system was active prior to the 1886 eruption of Mount Tarawera, but venting along the western shoreline, in the east basin, and the Patiti hydrothermal system appear to have been initiated in the aftermath of the eruption, similar to Waimangu Valley to the southwest. Different combinations of turbidity, pH anomalies (both positive and negative), and ORP responses suggest vent fluid compositions vary over short distances within the lake. The seasonal period of stratification limits vertical transport of heat to the surface layer and the hypolimnion temperature of Lake Rotomahana consequently increases with an average warming rate of ~ 0.010 °C/day due to both convective hydrothermal discharge and conductive geothermal heating. A sudden temperature increase occurred during our 2011 survey and was likely the response to an earthquake swarm just 11 days prior.

  14. Activity and hydrothermal stability of CeO₂-ZrO₂-WO₃ for the selective catalytic reduction of NOx with NH₃.

    PubMed

    Song, Zhongxian; Ning, Ping; Zhang, Qiulin; Li, Hao; Zhang, Jinhui; Wang, Yancai; Liu, Xin; Huang, Zhenzhen

    2016-04-01

    A series of CeO2-ZrO2-WO3 (CZW) catalysts prepared by a hydrothermal synthesis method showed excellent catalytic activity for selective catalytic reduction (SCR) of NO with NH3 over a wide temperature of 150-550°C. The effect of hydrothermal treatment of CZW catalysts on SCR activity was investigated in the presence of 10% H2O. The fresh catalyst showed above 90% NOx conversion at 201-459°C, which is applicable to diesel exhaust NOx purification (200-440°C). The SCR activity results indicated that hydrothermal aging decreased the SCR activity of CZW at low temperatures (below 300°C), while the activity was notably enhanced at high temperature (above 450°C). The aged CZW catalyst (hydrothermal aging at 700°C for 8 hr) showed almost 80% NOx conversion at 229-550°C, while the V2O5-WO3/TiO2 catalyst presented above 80% NOx conversion at 308-370°C. The effect of structural changes, acidity, and redox properties of CZW on the SCR activity was investigated. The results indicated that the excellent hydrothermal stability of CZW was mainly due to the CeO2-ZrO2 solid solution, amorphous WO3 phase and optimal acidity. In addition, the formation of WO3 clusters increased in size as the hydrothermal aging temperature increased, resulting in the collapse of structure, which could further affect the acidity and redox properties.

  15. Hydrothermal activity on near-arc sections of back-arc ridges: Results from the Mariana Trough and Lau Basin

    NASA Astrophysics Data System (ADS)

    Baker, Edward T.; Massoth, Gary J.; Nakamura, Ko-Ichi; Embley, Robert W.; de Ronde, Cornel E. J.; Arculus, Richard J.

    2005-09-01

    The spatial density of hydrothermal venting is strongly correlated with spreading rate on mid-ocean ridges (with the interesting exception of hot spot-affected ridges), evidently because spreading rate is a reliable proxy for the magma budget. This correlation remains untested on spreading ridges in back-arc basins, where the magma budget may be complicated by subduction-induced variations of the melt supply. To address this uncertainty, we conducted hydrothermal plume surveys along slow-spreading (40-60 mm/yr) and arc-proximal (10-60 km distant) sections of the southern Mariana Trough and the Valu Fa Ridge (Lau Basin). On both sections we found multiple plumes overlying ˜15-20% of the total length of each section, a coverage comparable to mid-ocean ridges spreading at similar rates. These conditions contrast with earlier reported results from the two nearest-arc segments of a faster spreading (60-70 mm/yr) back-arc ridge, the East Scotia Ridge, which approaches no closer than 100 km to its arc. There, hydrothermal venting is relatively scarce (˜5% plume coverage) and the ridge characteristics are distinctly slow-spreading: small central volcanic highs bookended by deep median valleys, and axial melt lenses restricted to the volcanic highs. Two factors may contribute to an unexpectedly low hydrothermal budget on these East Scotia Ridge segments: they may lie too far from the adjacent arc to benefit from near-arc sources of melt supply, and subduction-aided migration of mantle from the Bouvet hot spot may reduce hydrothermal circulation by local crustal warming and thickening, analogous to the Reykjanes Ridge. Thus the pattern among these three ridge sections appears to mirror the larger global pattern defined by mid-ocean ridges: a well-defined trend of spreading rate versus hydrothermal activity on most ridge sections, plus a subset of ridge sections where unusual melt delivery conditions diminish the expected hydrothermal activity.

  16. Early Solar System hydrothermal activity in chondritic asteroids on 1-10-year timescales.

    PubMed

    Dyl, Kathryn A; Bischoff, Addi; Ziegler, Karen; Young, Edward D; Wimmer, Karl; Bland, Phil A

    2012-11-01

    Chondritic meteorites are considered the most primitive remnants of planetesimals from the early Solar System. As undifferentiated objects, they also display widespread evidence of water-rock interaction on the parent body. Understanding this history has implications for the formation of planetary bodies, the delivery of water to the inner Solar System, and the formation of prebiotic molecules. The timescales of water-rock reactions in these early objects, however, are largely unknown. Here, we report evidence for short-lived water-rock reactions in the highly metamorphosed ordinary chondrite breccia Villalbeto de la Peña (L6). An exotic clast (d = 2cm) has coexisting variations in feldspar composition and oxygen isotope ratios that can only result from hydrothermal conditions. The profiles were modeled at T = 800 °C and P(H(2)O) = 1 bar using modified grain-boundary diffusion parameters for oxygen self-diffusion and reaction rates of NaSiCa(-1)Al(-1) exchange in a fumarole. The geochemical data are consistent with hydrothermal activity on the parent body lasting only 1-10 y. This result has wide-ranging implications for the geological history of chondritic asteroids.

  17. Early Solar System hydrothermal activity in chondritic asteroids on 1–10-year timescales

    PubMed Central

    Dyl, Kathryn A.; Bischoff, Addi; Ziegler, Karen; Young, Edward D.; Wimmer, Karl; Bland, Phil A.

    2012-01-01

    Chondritic meteorites are considered the most primitive remnants of planetesimals from the early Solar System. As undifferentiated objects, they also display widespread evidence of water–rock interaction on the parent body. Understanding this history has implications for the formation of planetary bodies, the delivery of water to the inner Solar System, and the formation of prebiotic molecules. The timescales of water–rock reactions in these early objects, however, are largely unknown. Here, we report evidence for short-lived water–rock reactions in the highly metamorphosed ordinary chondrite breccia Villalbeto de la Peña (L6). An exotic clast (d = 2cm) has coexisting variations in feldspar composition and oxygen isotope ratios that can only result from hydrothermal conditions. The profiles were modeled at T = 800 °C and P(H2O) = 1 bar using modified grain-boundary diffusion parameters for oxygen self-diffusion and reaction rates of NaSiCa-1Al-1 exchange in a fumarole. The geochemical data are consistent with hydrothermal activity on the parent body lasting only 1–10 y. This result has wide-ranging implications for the geological history of chondritic asteroids. PMID:23093668

  18. Bioactive proteins and energy value of okara as a byproduct in hydrothermal processing of soy milk.

    PubMed

    Stanojevic, Sladjana P; Barac, Miroljub B; Pesic, Mirjana B; Jankovic, Vanja S; Vucelic-Radovic, Biljana V

    2013-09-25

    The nutritional properties of raw okara obtained as a byproduct from six soybean varieties during hydrothermal cooking (HTC) of soy milk were assessed. The composition and residual activity (rTIA) of trypsin inhibitors (TIs), contents of lectin, proteins, fats, and carbohydrates, and energy values (EV) were correlated with the respective physicochemical properties of soybean and okara. Kunitz (KTI) and Bowman-Birk (BBI) TIs both comprised okara rTIA. TIs content was higher in okara (5.19-14.40%) than in soybean (3.10-12.17%), which additionally enriched okara by cysteine. Contents of KTI (r = 1.00;p < 0.05) and BBI (r = 0.89;p < 0.05) as well as BBI monomeric (r = 0.89;p < 0.05) and polymeric forms (r = 0.95;p < 0.05) in okara and in soybean were strongly correlated. Low urease index activity indicated that okara was heated adequately to inactivate antinutritional factors. The proximate composition of raw okara, advantageous rTIA, and a very low EV (2.74-3.78 kJ/g) qualify this byproduct for potential application in food preparation as a functional ingredient in dietary products. PMID:23978042

  19. A large hydrothermal reservoir beneath Taal Volcano (Philippines) revealed by magnetotelluric observations and its implications to the volcanic activity.

    PubMed

    Alanis, Paul K B; Yamaya, Yusuke; Takeuchi, Akihiro; Sasai, Yoichi; Okada, Yoshihiro; Nagao, Toshiyasu

    2013-01-01

    Taal Volcano is one of the most active volcanoes in the Philippines. The magnetotelluric 3D forward analyses indicate the existence of a large high resistivity anomaly (∼100 Ω·m) with a volume of at least 3 km×3 km×3 km, which is capped by a conductive layer (∼10 Ω·m), beneath the Main Crater. This high resistivity anomaly is hypothesized to be a large hydrothermal reservoir, consisting of the aggregate of interconnected cracks in rigid and dense host rocks, which are filled with hydrothermal fluids coming from a magma batch below the reservoir. The hydrothermal fluids are considered partly in gas phase and liquid phase. The presence of such a large hydrothermal reservoir and the stagnant magma below may have influences on the volcano's activity. Two possibilities are presented. First, the 30 January 1911 explosion event was a magmatic hydrothermal eruption rather than a base-surge associated with a phreato-magmatic eruption. Second, the earlier proposed four eruption series may be better interpreted by two cycles, each consisting of series of summit and flank eruptions. PMID:24126286

  20. A large hydrothermal reservoir beneath Taal Volcano (Philippines) revealed by magnetotelluric observations and its implications to the volcanic activity

    PubMed Central

    ALANIS, Paul K. B.; YAMAYA, Yusuke; TAKEUCHI, Akihiro; SASAI, Yoichi; OKADA, Yoshihiro; NAGAO, Toshiyasu

    2013-01-01

    Taal Volcano is one of the most active volcanoes in the Philippines. The magnetotelluric 3D forward analyses indicate the existence of a large high resistivity anomaly (∼100 Ω·m) with a volume of at least 3 km × 3 km × 3 km, which is capped by a conductive layer (∼10 Ω·m), beneath the Main Crater. This high resistivity anomaly is hypothesized to be a large hydrothermal reservoir, consisting of the aggregate of interconnected cracks in rigid and dense host rocks, which are filled with hydrothermal fluids coming from a magma batch below the reservoir. The hydrothermal fluids are considered partly in gas phase and liquid phase. The presence of such a large hydrothermal reservoir and the stagnant magma below may have influences on the volcano’s activity. Two possibilities are presented. First, the 30 January 1911 explosion event was a magmatic hydrothermal eruption rather than a base-surge associated with a phreato-magmatic eruption. Second, the earlier proposed four eruption series may be better interpreted by two cycles, each consisting of series of summit and flank eruptions. PMID:24126286

  1. A large hydrothermal reservoir beneath Taal Volcano (Philippines) revealed by magnetotelluric observations and its implications to the volcanic activity.

    PubMed

    Alanis, Paul K B; Yamaya, Yusuke; Takeuchi, Akihiro; Sasai, Yoichi; Okada, Yoshihiro; Nagao, Toshiyasu

    2013-01-01

    Taal Volcano is one of the most active volcanoes in the Philippines. The magnetotelluric 3D forward analyses indicate the existence of a large high resistivity anomaly (∼100 Ω·m) with a volume of at least 3 km×3 km×3 km, which is capped by a conductive layer (∼10 Ω·m), beneath the Main Crater. This high resistivity anomaly is hypothesized to be a large hydrothermal reservoir, consisting of the aggregate of interconnected cracks in rigid and dense host rocks, which are filled with hydrothermal fluids coming from a magma batch below the reservoir. The hydrothermal fluids are considered partly in gas phase and liquid phase. The presence of such a large hydrothermal reservoir and the stagnant magma below may have influences on the volcano's activity. Two possibilities are presented. First, the 30 January 1911 explosion event was a magmatic hydrothermal eruption rather than a base-surge associated with a phreato-magmatic eruption. Second, the earlier proposed four eruption series may be better interpreted by two cycles, each consisting of series of summit and flank eruptions.

  2. Dynamics of the Yellowstone hydrothermal system

    USGS Publications Warehouse

    Hurwitz, Shaul; Lowenstern, Jacob B.

    2014-01-01

    The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.

  3. New insights into hydrothermal vent processes in the unique shallow-submarine arc-volcano, Kolumbo (Santorini), Greece

    PubMed Central

    Kilias, Stephanos P.; Nomikou, Paraskevi; Papanikolaou, Dimitrios; Polymenakou, Paraskevi N.; Godelitsas, Athanasios; Argyraki, Ariadne; Carey, Steven; Gamaletsos, Platon; Mertzimekis, Theo J.; Stathopoulou, Eleni; Goettlicher, Joerg; Steininger, Ralph; Betzelou, Konstantina; Livanos, Isidoros; Christakis, Christos; Bell, Katherine Croff; Scoullos, Michael

    2013-01-01

    We report on integrated geomorphological, mineralogical, geochemical and biological investigations of the hydrothermal vent field located on the floor of the density-stratified acidic (pH ~ 5) crater of the Kolumbo shallow-submarine arc-volcano, near Santorini. Kolumbo features rare geodynamic setting at convergent boundaries, where arc-volcanism and seafloor hydrothermal activity are occurring in thinned continental crust. Special focus is given to unique enrichments of polymetallic spires in Sb and Tl (±Hg, As, Au, Ag, Zn) indicating a new hybrid seafloor analogue of epithermal-to-volcanic-hosted-massive-sulphide deposits. Iron microbial-mat analyses reveal dominating ferrihydrite-type phases, and high-proportion of microbial sequences akin to "Nitrosopumilus maritimus", a mesophilic Thaumarchaeota strain capable of chemoautotrophic growth on hydrothermal ammonia and CO2. Our findings highlight that acidic shallow-submarine hydrothermal vents nourish marine ecosystems in which nitrifying Archaea are important and suggest ferrihydrite-type Fe3+-(hydrated)-oxyhydroxides in associated low-temperature iron mats are formed by anaerobic Fe2+-oxidation, dependent on microbially produced nitrate. PMID:23939372

  4. New insights into hydrothermal vent processes in the unique shallow-submarine arc-volcano, Kolumbo (Santorini), Greece.

    PubMed

    Kilias, Stephanos P; Nomikou, Paraskevi; Papanikolaou, Dimitrios; Polymenakou, Paraskevi N; Godelitsas, Athanasios; Argyraki, Ariadne; Carey, Steven; Gamaletsos, Platon; Mertzimekis, Theo J; Stathopoulou, Eleni; Goettlicher, Joerg; Steininger, Ralph; Betzelou, Konstantina; Livanos, Isidoros; Christakis, Christos; Bell, Katherine Croff; Scoullos, Michael

    2013-01-01

    We report on integrated geomorphological, mineralogical, geochemical and biological investigations of the hydrothermal vent field located on the floor of the density-stratified acidic (pH ~ 5) crater of the Kolumbo shallow-submarine arc-volcano, near Santorini. Kolumbo features rare geodynamic setting at convergent boundaries, where arc-volcanism and seafloor hydrothermal activity are occurring in thinned continental crust. Special focus is given to unique enrichments of polymetallic spires in Sb and Tl (±Hg, As, Au, Ag, Zn) indicating a new hybrid seafloor analogue of epithermal-to-volcanic-hosted-massive-sulphide deposits. Iron microbial-mat analyses reveal dominating ferrihydrite-type phases, and high-proportion of microbial sequences akin to "Nitrosopumilus maritimus", a mesophilic Thaumarchaeota strain capable of chemoautotrophic growth on hydrothermal ammonia and CO2. Our findings highlight that acidic shallow-submarine hydrothermal vents nourish marine ecosystems in which nitrifying Archaea are important and suggest ferrihydrite-type Fe(3+)-(hydrated)-oxyhydroxides in associated low-temperature iron mats are formed by anaerobic Fe(2+)-oxidation, dependent on microbially produced nitrate.

  5. New insights into hydrothermal vent processes in the unique shallow-submarine arc-volcano, Kolumbo (Santorini), Greece.

    PubMed

    Kilias, Stephanos P; Nomikou, Paraskevi; Papanikolaou, Dimitrios; Polymenakou, Paraskevi N; Godelitsas, Athanasios; Argyraki, Ariadne; Carey, Steven; Gamaletsos, Platon; Mertzimekis, Theo J; Stathopoulou, Eleni; Goettlicher, Joerg; Steininger, Ralph; Betzelou, Konstantina; Livanos, Isidoros; Christakis, Christos; Bell, Katherine Croff; Scoullos, Michael

    2013-01-01

    We report on integrated geomorphological, mineralogical, geochemical and biological investigations of the hydrothermal vent field located on the floor of the density-stratified acidic (pH ~ 5) crater of the Kolumbo shallow-submarine arc-volcano, near Santorini. Kolumbo features rare geodynamic setting at convergent boundaries, where arc-volcanism and seafloor hydrothermal activity are occurring in thinned continental crust. Special focus is given to unique enrichments of polymetallic spires in Sb and Tl (±Hg, As, Au, Ag, Zn) indicating a new hybrid seafloor analogue of epithermal-to-volcanic-hosted-massive-sulphide deposits. Iron microbial-mat analyses reveal dominating ferrihydrite-type phases, and high-proportion of microbial sequences akin to "Nitrosopumilus maritimus", a mesophilic Thaumarchaeota strain capable of chemoautotrophic growth on hydrothermal ammonia and CO2. Our findings highlight that acidic shallow-submarine hydrothermal vents nourish marine ecosystems in which nitrifying Archaea are important and suggest ferrihydrite-type Fe(3+)-(hydrated)-oxyhydroxides in associated low-temperature iron mats are formed by anaerobic Fe(2+)-oxidation, dependent on microbially produced nitrate. PMID:23939372

  6. Fabrication of carbon/SiO2 composites from the hydrothermal carbonization process of polysaccharide and their adsorption performance.

    PubMed

    Li, Yinhui; Li, Kunyu; Su, Min; Ren, Yanmei; Li, Ying; Chen, Jianxin; Li, Liang

    2016-11-20

    In this work, carbon/SiO2 composites, using amylose and tetraethyl orthosilicate (TEOS) as raw materials, were successfully prepared by a facial hydrothermal carbonization process. The carbon/SiO2 composites were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), Energy Dispersive Spectroscopy (EDS), transmission electron microscope (TEM), N2 adsorption and Thermogravimetric (TG) analysis. The composites, which were made up of amorphous SiO2 and amorphous carbon, were found to have hierarchical porous structures. The mass ratios of amylose and SiO2 and the hydrothermal carbonization time had significant effects on the morphology of the composites, which had three shapes including monodispersed spheres, porous pieces and the nano-fibers combined with nano-spheres structures. The adsorption performance of the composites was studied using Pb(2+) as simulated contaminants from water. When the mass ratio of amylose and SiO2 was 9/1, the hydrothermal time was 30h and the hydrothermal temperature was 180°C, the adsorption capacity of the composites achieved to 52mg/g. Experimental data show that adsorption kinetics of the carbon/SiO2 composites can be fitted well by the Elovich model, while the isothermal data can be perfectly described by the Langmuir adsorption model and Freundlich adsorption model. The maximum adsorption capacity of the carbon/SiO2 composites is 56.18mgg(-1). PMID:27561502

  7. Fabrication of carbon/SiO2 composites from the hydrothermal carbonization process of polysaccharide and their adsorption performance.

    PubMed

    Li, Yinhui; Li, Kunyu; Su, Min; Ren, Yanmei; Li, Ying; Chen, Jianxin; Li, Liang

    2016-11-20

    In this work, carbon/SiO2 composites, using amylose and tetraethyl orthosilicate (TEOS) as raw materials, were successfully prepared by a facial hydrothermal carbonization process. The carbon/SiO2 composites were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), Energy Dispersive Spectroscopy (EDS), transmission electron microscope (TEM), N2 adsorption and Thermogravimetric (TG) analysis. The composites, which were made up of amorphous SiO2 and amorphous carbon, were found to have hierarchical porous structures. The mass ratios of amylose and SiO2 and the hydrothermal carbonization time had significant effects on the morphology of the composites, which had three shapes including monodispersed spheres, porous pieces and the nano-fibers combined with nano-spheres structures. The adsorption performance of the composites was studied using Pb(2+) as simulated contaminants from water. When the mass ratio of amylose and SiO2 was 9/1, the hydrothermal time was 30h and the hydrothermal temperature was 180°C, the adsorption capacity of the composites achieved to 52mg/g. Experimental data show that adsorption kinetics of the carbon/SiO2 composites can be fitted well by the Elovich model, while the isothermal data can be perfectly described by the Langmuir adsorption model and Freundlich adsorption model. The maximum adsorption capacity of the carbon/SiO2 composites is 56.18mgg(-1).

  8. Life cycle assessment of microalgae to biofuel: Thermochemical processing through hydrothermal liquefaction or pyrolysis

    NASA Astrophysics Data System (ADS)

    Bennion, Edward P.

    Microalgae are currently being investigated as a renewable transportation fuel feedstock based on various advantages that include high annual yields, utilization of poor quality land, does not compete with food, and can be integrated with various waste streams. This study focuses on directly assessing the impact of two different thermochemical conversion technologies on the microalgae-to-biofuel process through life cycle assessment. A system boundary of a "well to pump" (WTP) is defined and includes sub-process models of the growth, dewatering, thermochemical bio-oil recovery, bio-oil stabilization, conversion to renewable diesel, and transport to the pump. Models were validated with experimental and literature data and are representative of an industrial-scale microalgae-to-biofuel process. Two different thermochemical bio-oil conversion systems are modeled and compared on a systems level, hydrothermal liquefaction (HTL) and pyrolysis. The environmental impact of the two pathways were quantified on the metrics of net energy ratio (NER), defined here as energy consumed over energy produced, and greenhouse gas (GHG) emissions. Results for WTP biofuel production through the HTL pathway were determined to be 1.23 for the NER and GHG emissions of -11.4 g CO2 eq (MJ renewable diesel)-1. WTP biofuel production through the pyrolysis pathway results in a NER of 2.27 and GHG emissions of 210 g CO2 eq (MJ renewable diesel)-1. The large environmental impact associated with the pyrolysis pathway is attributed to feedstock drying requirements and combustion of co-products to improve system energetics. Discussion focuses on a detailed breakdown of the overall process energetics and GHGs, impact of modeling at laboratory-scale compared to industrial-scale, environmental impact sensitivity to engineering systems input parameters for future focused research and development, and a comparison of results to literature.

  9. Hydrothermally Processed Photosensitive Field-Effect Transistor Based on ZnO Nanorod Networks

    NASA Astrophysics Data System (ADS)

    Kumar, Ashish; Bhargava, Kshitij; Dixit, Tejendra; Palani, I. A.; Singh, Vipul

    2016-11-01

    Formation of a stable, reproducible zinc oxide (ZnO) nanorod-network-based photosensitive field-effect transistor using a hydrothermal process at low temperature has been demonstrated. K2Cr2O7 additive was used to improve adhesion and facilitate growth of the ZnO nanorod network over the SiO2/Si substrate. Transistor characteristics obtained in the dark resemble those of the n-channel-mode field-effect transistor (FET). The devices showed I on/ I off ratio above 8 × 102 under dark condition, field-effect mobility of 4.49 cm2 V-1 s-1, and threshold voltage of -12 V. Further, under ultraviolet (UV) illumination, the FET exhibited sensitivity of 2.7 × 102 in off-state (-10 V) versus 1.4 in on-state (+9.7 V) of operation. FETs based on such nanorod networks showed good photoresponse, which is attributed to the large surface area of the nanorod network. The growth temperature for ZnO nanorod networks was kept at 110°C, enabling a low-temperature, cost-effective, simple approach for high-performance ZnO-based FETs for large-scale production. The role of network interfaces in the FET performance is also discussed.

  10. Hydrothermally Processed Photosensitive Field-Effect Transistor Based on ZnO Nanorod Networks

    NASA Astrophysics Data System (ADS)

    Kumar, Ashish; Bhargava, Kshitij; Dixit, Tejendra; Palani, I. A.; Singh, Vipul

    2016-07-01

    Formation of a stable, reproducible zinc oxide (ZnO) nanorod-network-based photosensitive field-effect transistor using a hydrothermal process at low temperature has been demonstrated. K2Cr2O7 additive was used to improve adhesion and facilitate growth of the ZnO nanorod network over the SiO2/Si substrate. Transistor characteristics obtained in the dark resemble those of the n-channel-mode field-effect transistor (FET). The devices showed I on/I off ratio above 8 × 102 under dark condition, field-effect mobility of 4.49 cm2 V-1 s-1, and threshold voltage of -12 V. Further, under ultraviolet (UV) illumination, the FET exhibited sensitivity of 2.7 × 102 in off-state (-10 V) versus 1.4 in on-state (+9.7 V) of operation. FETs based on such nanorod networks showed good photoresponse, which is attributed to the large surface area of the nanorod network. The growth temperature for ZnO nanorod networks was kept at 110°C, enabling a low-temperature, cost-effective, simple approach for high-performance ZnO-based FETs for large-scale production. The role of network interfaces in the FET performance is also discussed.

  11. Hydrothermal Processes and Mobile Element Transport in Martian Impact Craters - Evidence from Terrestrial Analogue Craters

    NASA Technical Reports Server (NTRS)

    Newsom, H. E.; Nelson, M. J.; Shearer, C. K.; Dressler, B. L.

    2005-01-01

    Hydrothermal alteration and chemical transport involving impact craters probably occurred on Mars throughout its history. Our studies of alteration products and mobile element transport in ejecta blanket and drill core samples from impact craters show that these processes may have contributed to the surface composition of Mars. Recent work on the Chicxulub Yaxcopoil-1 drill core has provided important information on the relative mobility of many elements that may be relevant to Mars. The Chicxulub impact structure in the Yucatan Peninsula of Mexico and offshore in the Gulf of Mexico is one of the largest impact craters identified on the Earth, has a diameter of 180-200 km, and is associated with the mass extinctions at the K/T boundary. The Yax-1 hole was drilled in 2001 and 2002 on the Yaxcopoil hacienda near Merida on the Yucatan Peninsula. Yax-1 is located just outside of the transient cavity, which explains some of the unusual characteristics of the core stratigraphy. No typical impact melt sheet was encountered in the hole and most of the Yax-1 impactites are breccias. In particular, the impact melt and breccias are only 100 m thick which is surprising taking into account the considerably thicker breccia accumulations towards the center of the structure and farther outside the transient crater encountered by other drill holes.

  12. Controllable synthesis of ultrathin vanadium oxide nanobelts via an EDTA-mediated hydrothermal process

    NASA Astrophysics Data System (ADS)

    Yu-Xiang, Qin; Cheng, Liu; Wei-Wei, Xie; Meng-Yang, Cui

    2016-02-01

    Ultrathin VO2 nanobelts with rough alignment features are prepared on the induction layer-coated substrates by an ethylenediaminetetraacetic acid (EDTA)-mediated hydrothermal process. EDTA acts as a chelating reagent and capping agent to facilitate the one-dimensional (1D) preferential growth of ultrathin VO2 nanobelts with high crystallinities and good uniformities. The annealed induction layer and concentration of EDTA are found to play crucial roles in the formation of aligned and ultrathin nanobelts. Variation in EDTA concentration can change the VO2 morphology of ultrathin nanobelts into that of thick nanoplates. Mild annealing of ultrathin VO2 nanobelts at 350 °C in air results in the formation of V2O5 nanobelts with a nearly unchanged ultrathin structure. The nucleation and growth mechanism involved in the formations of nanobelts and nanoplates are proposed. The ethanol gas sensing properties of the V2O5 nanobelt networks-based sensor are investigated in a temperature range from 100 °C to 300 °C over ethanol concentrations ranging from 3 ppm to 500 ppm. The results indicate that the V2O5 nanobelt network sensor exhibits high sensitivity, good reversibility, and fast response-recovery characteristics with an optimal working temperature of 250 °C. Project supported by the National Natural Science Foundation of China (Grant Nos. 61274074, 61271070, and 61574100).

  13. Enhanced East Pacific Rise hydrothermal activity during the last two glacial terminations

    NASA Astrophysics Data System (ADS)

    Lund, D. C.; Asimow, P. D.; Farley, K. A.; Rooney, T. O.; Seeley, E.; Jackson, E. W.; Durham, Z. M.

    2016-01-01

    Mid-ocean ridge magmatism is driven by seafloor spreading and decompression melting of the upper mantle. Melt production is apparently modulated by glacial-interglacial changes in sea level, raising the possibility that magmatic flux acts as a negative feedback on ice-sheet size. The timing of melt variability is poorly constrained, however, precluding a clear link between ridge magmatism and Pleistocene climate transitions. Here we present well-dated sedimentary records from the East Pacific Rise that show evidence of enhanced hydrothermal activity during the last two glacial terminations. We suggest that glacial maxima and lowering of sea level caused anomalous melting in the upper mantle and that the subsequent magmatic anomalies promoted deglaciation through the release of mantle heat and carbon at mid-ocean ridges.

  14. ESR dating of barite in sulphide deposits formed by the sea-floor hydrothermal activities.

    PubMed

    Toyoda, Shin; Fujiwara, Taisei; Uchida, Ai; Ishibashi, Jun-ichiro; Nakai, Shun'ichi; Takamasa, Asako

    2014-06-01

    Barite is a mineral newly found to be practically useful for electron spin resonance (ESR) dating of sulphide deposits formed by the sea-floor hydrothermal activities. The recent studies for the properties of the ESR dating signal in barite are summarised in the present paper as well as the formulas for corrections for accurate dose-rate estimation are developed including the dose-rate conversion factors, shape correction for gamma-ray dose and decay of (226)Ra. Although development of the techniques for ESR dating of barite has been completed, further comparative studies with other dating techniques such as U-Th and (226)Ra-(210)Pb dating are necessary for the technique to be widely used.

  15. Enhanced East Pacific Rise hydrothermal activity during the last two glacial terminations.

    PubMed

    Lund, D C; Asimow, P D; Farley, K A; Rooney, T O; Seeley, E; Jackson, E W; Durham, Z M

    2016-01-29

    Mid-ocean ridge magmatism is driven by seafloor spreading and decompression melting of the upper mantle. Melt production is apparently modulated by glacial-interglacial changes in sea level, raising the possibility that magmatic flux acts as a negative feedback on ice-sheet size. The timing of melt variability is poorly constrained, however, precluding a clear link between ridge magmatism and Pleistocene climate transitions. Here we present well-dated sedimentary records from the East Pacific Rise that show evidence of enhanced hydrothermal activity during the last two glacial terminations. We suggest that glacial maxima and lowering of sea level caused anomalous melting in the upper mantle and that the subsequent magmatic anomalies promoted deglaciation through the release of mantle heat and carbon at mid-ocean ridges. PMID:26823422

  16. Dramatic activity of mixed-phase TiO2 photocatalyst synthesized by hydrothermal method

    NASA Astrophysics Data System (ADS)

    Li, Huiquan; Xu, Bolian; Fan, Yining

    2013-02-01

    The mixed-phase TiO2 photocatalysts with different anatase/rutile/brookite ratios and high specific surface area (157-218 m2/g) were prepared by hydrothermal method at 100 °C and the effect of rutile content in TiO2 on the BET surface area, light absorption and separation efficiency of photogenerated charge carriers was studied and correlated to the photocatalytic activity of TiO2. Rutile content increased from 0% to 100% by increasing the amount of TiCl4 in aqueous phase and the initial pH value of reaction solution played an important role in the phase composition of TiO2. The photocatalytic mechanism of mixed-phase TiO2 was discussed.

  17. Enhanced East Pacific Rise hydrothermal activity during the last two glacial terminations.

    PubMed

    Lund, D C; Asimow, P D; Farley, K A; Rooney, T O; Seeley, E; Jackson, E W; Durham, Z M

    2016-01-29

    Mid-ocean ridge magmatism is driven by seafloor spreading and decompression melting of the upper mantle. Melt production is apparently modulated by glacial-interglacial changes in sea level, raising the possibility that magmatic flux acts as a negative feedback on ice-sheet size. The timing of melt variability is poorly constrained, however, precluding a clear link between ridge magmatism and Pleistocene climate transitions. Here we present well-dated sedimentary records from the East Pacific Rise that show evidence of enhanced hydrothermal activity during the last two glacial terminations. We suggest that glacial maxima and lowering of sea level caused anomalous melting in the upper mantle and that the subsequent magmatic anomalies promoted deglaciation through the release of mantle heat and carbon at mid-ocean ridges.

  18. Hydrothermal processing of Hanford tank waste. Organic destruction technology development task annual report -- FY 1993

    SciTech Connect

    Orth, R.J.; Schmidt, A.J.; Zacher, A.H.

    1993-09-01

    Low-temperature hydrothermal processing (HTP) is a thermal-chemical autogenous processing method that can be used to destroy organics and ferrocyanide in Hanford tank waste at temperatures from 250 C to 400 C. With HTP, organics react with oxidants, such as nitrite and nitrate, already present in the waste. Ferrocyanides and free cyanide will hydrolyze at similar temperatures and may also react with nitrates or other oxidants in the waste. No air or oxygen or additional chemicals need to be added to the autogenous HTP system. However, enhanced kinetics may be realized by air addition, and, if desired, chemical reductants can be added to the system to facilitate complete nitrate/nitrate destruction. Tank waste can be processed in a plug-flow, tubular reactor, or a continuous-stirred tank reactor system designed to accommodate the temperature, pressure, gas generation, and heat release associated with decomposition of the reactive species. The work described in this annual report was conducted in FY 1993 for the Organic Destruction Technology Development Task of Hanford`s Tank Waste Remediation System (TWRS). This task is part of an overall program to develop organic destruction technologies originally funded by TWRS to meet tank safety and waste form disposal criteria and condition the feed for further pretreatment. During FY 1993 the project completed seven experimental test plans, a 30-hr pilot-scale continuous run, over 200 hr of continuous bench-scale HTP testing, and 20 batch HTP tests; two contracts were established with commercial vendors, and a commercial laboratory reactor was procured and installed in a glovebox for HTP testing with actual Hanford tank waste.

  19. Diffuse flow hydrothermal manganese mineralization along the active Mariana and southern Izu-Bonin arc system, western Pacific

    NASA Astrophysics Data System (ADS)

    Hein, James R.; Schulz, Marjorie S.; Dunham, Rachel E.; Stern, Robert J.; Bloomer, Sherman H.

    2008-08-01

    Abundant ferromanganese oxides were collected along 1200 km of the active Izu-Bonin-Mariana arc system. Chemical compositions and mineralogy show that samples were collected from two deposit types: Fe-Mn crusts of mixed hydrogenetic/hydrothermal origin and hydrothermal Mn oxide deposits; this paper addresses only the second type. Mn oxides cement volcaniclastic and biogenic sandstone and breccia layers (Mn sandstone) and form discrete dense stratabound layers along bedding planes and within beds (stratabound Mn). The Mn oxide was deposited within coarse-grained sediments from diffuse flow systems where precipitation occurred below the seafloor. Deposits were exposed at the seabed by faulting, mass wasting, and erosion. Scanning electron microscopy and microprobe analyses indicate the presence of both amorphous and crystalline 10 Å and 7 Å manganate minerals, the fundamental chemical difference being high water contents in the amorphous Mn oxides. Alternation of amorphous and crystalline laminae occurs in many samples, which likely resulted from initial rapid precipitation of amorphous Mn oxides from waxing pulses of hydrothermal fluids followed by precipitation of slow forming crystallites during waning stages. The chemical composition is characteristic of a hydrothermal origin including strong fractionation between Fe (mean 0.9 wt %) and Mn (mean 48 wt %) for the stratabound Mn, generally low trace metal contents, and very low rare earth element and platinum group element contents. However, Mo, Cd, Zn, Cu, Ni, and Co occur in high concentrations in some samples and may be good indicator elements for proximity to the heat source or to massive sulfide deposits. For the Mn sandstones, Fe (mean 8.4%) and Mn (12.4%) are not significantly fractionated because of high Fe contents in the volcaniclastic material. However, the proportion of hydrothermal Fe (nondetrital Fe) to total Fe is remarkably constant (49-58%) for all the sample groups, regardless of the degree of

  20. Diffuse flow hydrothermal manganese mineralization along the active Mariana and southern Izu-Bonin arc system, western Pacific

    USGS Publications Warehouse

    Hein, J.R.; Schulz, M.S.; Dunham, R.E.; Stern, R.J.; Bloomer, S.H.

    2008-01-01

    Abundant ferromanganese oxides were collected along 1200 km of the active Izu-Bonin-Mariana arc system. Chemical compositions and mineralogy show that samples were collected from two deposit types: Fe-Mn crusts of mixed hydrogenetic/hydrothermal origin and hydrothermal Mn oxide deposits; this paper addresses only the second type. Mn oxides cement volcaniclastic and biogenic sandstone and breccia layers (Mn sandstone) and form discrete dense stratabound layers along bedding planes and within beds (stratabound Mn). The Mn oxide was deposited within coarse-grained sediments from diffuse flow systems where precipitation occurred below the seafloor. Deposits were exposed at the seabed by faulting, mass wasting, and erosion. Scanning electron microscopy and microprobe analyses indicate the presence of both amorphous and crystalline 10 ?? and 7 ?? manganate minerals, the fundamental chemical difference being high water contents in the amorphous Mn oxides. Alternation of amorphous and crystalline laminae occurs in many samples, which likely resulted from initial rapid precipitation of amorphous Mn oxides from waxing pulses of hydrothermal fluids followed by precipitation of slow forming crystallites during waning stages. The chemical composition is characteristic of a hydrothermal origin including strong fractionation between Fe (mean 0.9 wt %) and Mn (mean 48 wt %) for the stratabound Mn, generally low trace metal contents, and very low rare earth element and platinum group element contents. However, Mo, Cd, Zn, Cu, Ni, and Co occur in high concentrations in some samples and may be good indicator elements for proximity to the heat source or to massive sulfide deposits. For the Mn sandstones, Fe (mean-8.4%) and Mn (12.4%) are not significantly fractionated because of high Fe contents in the volcaniclastic material. However, the proportion of hydrothermal Fe (nondetrital Fe) to total Fe is remarkably constant (49-58%) for all the sample groups, regardless of the degree of

  1. The reductive supercritical hydrothermal process, a novel synthesis method for cobalt nanoparticles: synthesis and investigation on the reaction mechanism.

    PubMed

    Seong, Gimyeong; Adschiri, Tadafumi

    2014-07-28

    Highly crystalline cobalt nanoparticles with low surface oxidation were synthesized by the reductive supercritical hydrothermal process in the temperature range from 340 to 420 °C. Under these reaction conditions, hydrogen generated from formic acid decomposition is maximally soluble in water, enabling the effective reduction of cobalt ions and cobalt oxide. The reaction mechanism was investigated by kinetic analysis on the formation of cobalt nanoparticles. This analysis assumed the first order irreversible reaction and two different types of shrinking core models (chemical reaction and inter-diffusion dominated). According to the proposed reaction mechanism, cobalt monoxide is probably formed at the early reaction stage, where insufficient H2 is available, or under high temperature conditions. Moreover, cobalt monoxide influences the entire reaction rate. Thus, suppressing the formation and growth of cobalt monoxide is of primary importance in the optimal synthesis of cobalt nanoparticles by the reductive supercritical hydrothermal process.

  2. Diversity of Active Seafloor Hydrothermal Mineralization in the Manus Back-Arc Basin, Papua New Guinea

    NASA Astrophysics Data System (ADS)

    Gena, K.; Chiba, H.

    2004-12-01

    sulfidation mineralization is considered to be a product of magmatic degassing and is a typical example of an acid-sulphate type of hydrothermal activity developing on the seafloor.

  3. METEORIC-HYDROTHERMAL SYSTEMS.

    USGS Publications Warehouse

    Criss, Robert E.; Taylor, Hugh P.

    1986-01-01

    This paper summarizes the salient characteristics of meteoric-hydrothermal systems, emphasing the isotopic systematics. Discussions of permeable-medium fluid dynamics and the geology and geochemistry of modern geothermal systems are also provided, because they are essential to any understanding of hydrothermal circulation. The main focus of the paper is on regions of ancient meteoric-hydrothermal activity, which give us information about the presently inaccessible, deep-level parts of modern geothermal systems. It is shown oxygen and hydrogen isotopes provide a powerful method to discover and map fossil hydrothermal systems and to investigate diverse associated aspects of rock alteration and ore deposition.

  4. The effect of stirring in the hydrothermal process to convert the mixed municipal solid waste into uniform solid fuel

    NASA Astrophysics Data System (ADS)

    Prawisudha, P.; Mu'min, G. F.; Yoshikawa, K.; Pasek, A. D.

    2016-06-01

    An innovative waste treatment technology has been developed in Indonesia to treat the mixed municipal solid waste into a solid fuel by employing the hydrothermal process. A mixture of organic and plastic waste was treated in a 2.5 L reactor using saturated steam in the temperature range of 120 to 180 °C. Two modes of operation were employed to achieve two different goals, i.e. without stirring (NS mode) and with stirring (WS mode). It was observed that both modes resulted in increasing density of product up to twofold of the raw MSW. In NS mode, the processed mixed MSW was converted into two different products; however, in WS mode the bulky plastic was converted into small granules, producing a uniform product. The results suggest that by hydrothermal treatment, the organic fibers in the organic parts are trapped into the plastic, and the stirring breaks the bulky plastics, producing uniform granules suitable as solid fuel. Therefore, the stirring during the hydrothermal process can be a solution to treat the MSW as it is, without any separation, to produce a clean and renewable energy source.

  5. Using noble gases measured in spring discharge to trace hydrothermal processes in the Norris Geyser Basin, Yellowstone National Park, U.S.A.

    USGS Publications Warehouse

    Gardner, W.P.; Susong, D.D.; Solomon, D.K.; Heasler, H.P.

    2010-01-01

    Dissolved noble gas concentrations in springs are used to investigate boiling of hydrothermal water and mixing of hydrothermal and shallow cool water in the Norris Geyser Basin area. Noble gas concentrations in water are modeled for single stage and continuous steam removal. Limitations on boiling using noble gas concentrations are then used to estimate the isotopic effect of boiling on hydrothermal water, allowing the isotopic composition of the parent hydrothermal water to be determined from that measured in spring. In neutral chloride springs of the Norris Geyser Basin, steam loss since the last addition of noble gas charged water is less than 30% of the total hydrothermal discharge, which results in an isotopic shift due to boiling of ?? 2.5% ??D. Noble gas concentrations in water rapidly and predictably change in dual phase systems, making them invaluable tracers of gas-liquid interaction in hydrothermal systems. By combining traditional tracers of hydrothermal flow such as deuterium with dissolved noble gas measurements, more complex hydrothermal processes can be interpreted. ?? 2010 Elsevier B.V.

  6. Fundamental chemistry and thermodynamics of hydrothermal oxidation processes. 1997 annual progress report

    SciTech Connect

    Simonson, J.M.; Mesmer, R.E.; Blencoe, J.G.; Cummings, P.T.; Chialvo, A.A.

    1997-09-01

    'The objective of this research program is to provide fundamental scientific information on the physical and chemical properties of solutes in aqueous solutions at high temperatures needed to assess and improve the applicability of hydrothermal oxidation (HTO) to the remediation of US Department of Energy (DOE) hazardous and mixed wastes. Investigators in two divisions at Oak Ridge National Laboratory (Chemical and Analytical Sciences, and Chemical Technology) and at the University of Tennessee are focused on the solubility and speciation of actinides and surrogates in model HTO process streams at high temperatures, on the experimental and theoretical development of equations of state for aqueous mixtures containing noncondensible gases under HTO process conditions ranging above the critical temperature of water, and on achieving a predictive level of understanding of the chemical and physical properties of HTO process streams through molecular-level simulations of aqueous solutions at high temperatures. Specific tasks in these three efforts over the past year include measurements of solubility and identification of stable solid phases for UO{sub 3} in aqueous carbonate solutions at temperatures above 100 C, measurements of fluid-phase coexistence boundaries and densities of mixtures in (H{sub 2}O + N{sub 2} + CO{sub 2}) mixtures at high temperatures and pressures, and molecular dynamics simulations of water and aqueous solutions addressing the speciation of simple ionic solutes and the structure of water and aqueous solutions as functions of temperature and density. Research in this project has been divided into individual tasks, each addressing a particular scientific question and each contributing to a unified understanding of HTO processing problems related to the treatment of DOE hazardous and mixed wastes. The three primary tasks are (1) the determination of solubilities of inorganic compounds including actinides and surrogates to determine their likely fate

  7. Age, Episodicity and Migration of Hydrothermal Activity within the Axial Valley, Endeavour Segment, Juan de Fuca Ridge

    NASA Astrophysics Data System (ADS)

    Jamieson, J. W.; Hannington, M. D.; Kelley, D. S.; Clague, D. A.; Holden, J. F.; Tivey, M. K.; Delaney, J. R.

    2011-12-01

    Hydrothermal sulfide deposits record the history of high-temperature venting along the Endeavour Segment. Active venting is currently located within five discreet vent fields, with minor diffuse venting occurring between the fields. However, inactive and/or extinct sulfide structures are found throughout the entire axial valley of the ridge segment, suggesting that hydrothermal activity has been more vigorous in the past or focused venting has migrated with time. Here, we present age constraints from U-series dating of 44 sulfide samples collected by manned submersible from between the Mothra Field in the south to Sasquatch in the north. Samples are dated using 226Ra/Ba ratios from hydrothermal barite that precipitates along with the sulfide minerals. Most samples have been collected from within or near the active vent fields. Fifteen samples from the Main Endeavour Field (MEF) show a spectrum of ages from present to 2,430 years old, indicating that this field has been continuously active for at least ~2,400 years. MEF appears to be oldest currently active field. This minimum value for the age of hydrothermal activity also provides a minimum age of the axial valley itself. Ages from thirteen samples from the High-Rise Field indicate continuous venting for at least the past ~1,250 years. These age data are used in conjunction with age constraints of the volcanic flows to develop an integrated volcanic, hydrothermal and tectonic history of the Endeavour Segment. The total volume of hydrothermal sulfide within the axial valley, determined from high-resolution bathymetry, is used in conjunction with the age constraints of the sulfide material to determine the mass accumulation rates of sulfide along the Endeavour Segment. These data can be used to calibrate the efficiency of sulfide deposition from the hydrothermal vents, and provide a time-integrated history of heat, fluid and chemical fluxes at the ridge-segment scale. The comparison of time-integrated rates with

  8. Metaproteomic Analysis of a Chemosynthetic Hydrothermal Vent Community Reveals Insights into Key-Metabolic Processes

    NASA Astrophysics Data System (ADS)

    Steen, I.; Stokke, R.; Lanzen, A.; Pedersen, R.; Øvreås, L.; Urich, T.

    2010-12-01

    In 2005 researchers at the Centre for Geobiology, University of Bergen, Norway, discovered two active vent fields at the southwestern Mohns Ridge in the Norwegian-Greenland Sea. The fields harbours both low-temperature iron deposits and high-temperature white smoker vents. Distinct microbial mats were abundantly present and located in close vicinity to the hydrothermal vent sites. Characteristics of the mat environment were steep physical and chemical gradients with temperatures ranging from 10°C in the top layer to 90°C at 10 cm bsf and high concentrations of hydrogen sulfide and methane. The work presented here focus on the In situ community activities, and is part of an integrated strategy combining metagenomics, metatranscriptomics and metaproteomics to in-depth characterise these newly discovered hydrothermal vent communities. Extracted proteins were separated via SDS-PAGE. Peptides extracted after In-gel tryptic digest was injected into an Ultimate 3000 nanoLC system connected to a linear quadropole ion trap-orbitrap (LTQ-Orbitrap XL) mass spectrometer equipped with a nanoelectrospray ion source. A custom database of open reading frames (ORFs) from the combined metatranscriptome and metagenome datasets was implemented and searched against using Mascot 2.2; the IRMa tool box [1] was used in peptide validation. Validated ORFs were subjected to a Blastp search against Refseq with an E-value cut-off of 0.001. A total of 1097 proteins with ≥ 2 peptides were identified of which 921 gave a hit against Refseq, containing 519 unique proteins. Key enzymes of the sulfur oxidation pathway (sox) were found, which were taxonomically affiliated to Epsilonproteobacteria. In addition, this group actively expressed hydrogenases and membrane proteins involved in aerobic and anaerobic respiratory chains. Enzymes of dissimilatory sulfate-reduction (APS-reductase, AprAB and DsrA2) were found with closest hit to members of the Deltaproteobacteria. These findings indicate an

  9. Transportability Class of Americium in K Basin Sludge under Ambient and Hydrothermal Processing Conditions

    SciTech Connect

    Delegard, Calvin H.; Schmitt, Bruce E.; Schmidt, Andrew J.

    2006-08-01

    data is derived spent nuclear fuel corroded within the K Basins at 10-15?C. The STP process will place water-laden sludges from the K Basin in process vessels at {approx}150-180 C. Therefore, published studies with other irradiated (uranium oxide) fuel were examined. From these studies, the affinity of plutonium and americium for uranium in irradiated UO2 also was demonstrated at hydrothermal conditions (150 C anoxic liquid water) approaching those proposed for the STP process and even for hydrothermal conditions outside of the STP operating envelope (e.g., 150 C oxic and 100 C oxic and anoxic liquid water). In summary, by demonstrating that the chemical and physical behavior of 241Am in the sludge matrix is similar to that of the predominant species (uranium and for the plutonium from which it originates), a technical basis is provided for using the slow uptake transportability factor for 241Am that is currently used for plutonium and uranium oxides. The change from moderate to slow uptake for 241Am could reduce the overall analyzed dose consequences for the STP by more than 30%.

  10. The hydrophysical evidence for hydrothermal activity intensification in the subtropical MAR in summer, 2002

    NASA Astrophysics Data System (ADS)

    Aleynik, D. L.

    2003-04-01

    The adequate evaluations of heat and matter flux on the ocean - bottom boundary are required as for determination of the overall ocean thermal budget, so for the expected climate transformations. The hydrophysical measurements were obtained by rosette equipped with CTD, nephelometer, pinger and 30-liter bottles, which were deployed from R/V “Ak. M. Keldysh” in a tow-yo regime. The data were supplemented by visual and instrumental observations from submersibles “MIR”. These results at six hydrothermal vent sites of MAR from 23.3 to 37.3 deg. N were compared with data of similar surveys, fulfilled during previous decade. The hydrothermal matter influx irregularity leads to fluctuations in the parameters of the neutral buoyant plumes above five sites (Snake Pit, TAG, Broken Spur, Lucky Strike and Rainbow). The absence of the plume above the Lost City was detected. In July, 2002, northeastern-more off the most active field Rainbow the sizes of the neutral plume again (as well as during the RRS “Discovery” expedition in 1997) increased in three times (up to 6-7 kms along SW-NE line and more than 4 kms across) in contrast to the data of detail survey in autumn, 1999. Now this plume covers the whole peak of Rainbow axial Ridge. The waters contained in this rift valley (160 cubic kms) are remarkably more heated than ambient ocean waters (at depth 2650 m the difference is near 0.5 deg. C). The author thanks crews of R/V “AMK” and submersibles “MIR” for their help in measurements.

  11. Hydrothermal Activity on the Mid-Cayman Rise: ROV Jason sampling and site characterization at the Von Damm and Piccard hydrothermal fields

    NASA Astrophysics Data System (ADS)

    German, C. R.

    2012-12-01

    In January 2012 our multi-national and multi-disciplinary team conducted a series of 10 ROV Jason dives to conduct first detailed and systematic sampling of the Mid Cayman Rise hydrothermal systems at the Von Damm and Piccard hydrothermal fields. At Von Damm, hydrothermal venting is focused at and around a large conical structure that is approximately 120 m in diameter and rises at least 80m from the surrounding, largely sedimented seafloor. Clear fluids emitted from multiple sites around the flanks of the mound fall in the temperature range 110-130°C and fall on a common mixing line with hotter (>200°C) clear fluids emitted from an 8m tall spire at the summit which show clear evidence of ultramafic influence. Outcrop close to the vent-site is rare and the cone itself appear to consist of clay minerals derived from highly altered host rock. The dominant fauna at the summit of Von Damm are a new species of chemosynthetic shrimp but elsewhere the site also hosts two distinct species of chemosynthetic tube worm as well as at least one species of gastropod. The adjacent Piccard site, at ~5000m depth comprises 7 distinct sulfide mounds, 3 of which are currently active: Beebe Vents, Beebe Woods and Beebe Sea. Beebe Vents consists of 5 vigorous black smoker chimneys with maximum temperatures in the range 400-403°C while at Beebe Woods a more highly colonized thicket of up to 8m tall chimneys includes predominantly beehive diffusers with rare black smokers emitting fluids up to 353°C. Beebe Sea a diffuse site emitting fluids at 38°C Tmax, is the largest of the currently active mounds and immediately abuts a tall (8m) rift that strikes NE-SW bisecting the host Axial Volcanic Ridge. The fauna at Piccard are less diverse than at Von Damm and, predominantly, comprise the same species of MCR shrimp, a distinct gastropod species and abundant anemones.

  12. Distribution, activity and function of short-chain alkane degrading phylotypes in hydrothermal vent sediments

    NASA Astrophysics Data System (ADS)

    Adams, M. M.; Joye, S. B.; Hoarfrost, A.; Girguis, P. R.

    2012-12-01

    Global geochemical analyses suggest that C2-C4 short chain alkanes are a common component of the utilizable carbon pool in deep-sea sediments worldwide and have been found in diverse ecosystems. From a thermodynamic standpoint, the anaerobic microbial oxidation of these aliphatic hydrocarbons is more energetically yielding than the anaerobic oxidation of methane (AOM). Therefore, the preferential degradation of these hydrocarbons may compete with AOM for the use of oxidants such as sulfate, or other potential oxidants. Such processes could influence the fate of methane in the deep-sea. Sulfate-reducing bacteria (SRB) from hydrocarbon seep sediments of the Gulf of Mexico and Guaymas Basin have previously been enriched that anaerobically oxidize short chain alkanes to generate CO2 with the preferential utilization of 12C-enriched alkanes (Kniemeyer et al. 2007). Different temperature regimens along with multiple substrates were tested and a pure culture (deemed BuS5) was isolated from mesophilic enrichments with propane or n-butane as the sole carbon source. Through comparative sequence analysis, strain BuS5 was determined to cluster with the metabolically diverse Desulfosarcina / Desulfococcus cluster, which also contains the SRB found in consortia with anaerobic, methane-oxidizing archaea in seep sediments. Enrichments from a terrestrial, low temperature sulfidic hydrocarbon seep also corroborated that propane degradation occurred with most bacterial phylotypes surveyed belonging to the Deltaproteobacteria, particularly Desulfobacteraceae (Savage et al. 2011). To date, no microbes capable of ethane oxidation or anaerobic C2-C4 alkane oxidation at thermophilic temperature have been isolated. The sediment-covered, hydrothermal vent systems found at Middle Valley (Juan de Fuca Ridge, eastern Pacific Ocean) are a prime environment for investigating mesophilic to thermophilic anaerobic oxidation of short-chain alkanes, given the elevated temperatures and dissolved

  13. Topographic control of a dispersing hydrothermal plume

    NASA Astrophysics Data System (ADS)

    German, C. R.; Richards, K. J.; Rudnicki, M. D.; Lam, M. M.; Charlou, J. L.; Flame Scientific Party

    1998-03-01

    Deep-sea hydrothermal vents represent a major source of heat and chemicals to the oceans and support endemic chemosynthetic biological communities. To fully understand the impact of hydrothermal activity upon the oceans, however, requires investigation of both the physical and the biogeochemical processes which are active in hydrothermal plumes and which serve to determine the net hydrothermal flux to the oceans. We have recently conducted a detailed multidisciplinary study of the lateral dispersion of the hydrothermal plume emitted from the Rainbow vent site near 36°15'N, Mid-Atlantic Ridge. Combining velocity measurements from a lowered ADCP, optical back scatter measurements from a deep-tow CTD and methane measurements from bottle samples we are able, for the first time in the Atlantic, to trace a neutrally buoyant plume for a distance of over 50 km. The path of the plume is seen to be heavily controlled by the local topography with a general northeast movement of water. Both particle and methane concentrations decrease downstream over the length of the observed plume. The dataset provides an excellent opportunity to study the mixing and biogeochemical processes active in a hydrothermal plume and estimate fluxes of biogeochemical constituents.

  14. Cinnabar, arsenian pyrite and thallium-enrichment in active shallow submarine hydrothermal vents at Paleochori Bay, Milos Island, Greece

    NASA Astrophysics Data System (ADS)

    Kati, Marianna; Voudouris, Panagiotis; Valsami-Jones, Eugenia; Magganas, Andreas; Baltatzis, Emmanouil; Kanellopoulos, Christos; Mavrogonatos, Constantinos

    2015-04-01

    We herein report the discovery of active cinnabar-depositing hydrothermal vents in a submarine setting at Paleochori Bay, within the offshore southeastern extension of the Milos Island Geothermal Field, South Aegean Active Volcanic Arc. Active, low temperature (up to 115 °C) hydrothermal venting through volcaniclastic material has led to a varied assemblage of sulfide and alteration mineral phases in an area of approximately 1 km2. Our samples recovered from Paleochori Bay are hydrothermal edifices composed of volcaniclastic detrital material cemented by pyrite, or pure sulfide (mainly massive pyrite) mounts. Besides pyrite and minor marcasite, the hydrothermal minerals include cinnabar, amorphous silica, hydrous ferric oxides, carbonates (aragonite and calcite), alunite-jarosite solid solution and Sr-rich barite. Among others, growth textures, sieve-textured pyrite associated with barite, alunite-jarosite solid solution and hydrous ferric oxides rims colloform-banded pyrite layers. Overgrowths of arsenian pyrite layers (up to 3.2 wt. % As and/or up to 1.1 wt. % Mn) onto As-free pyrite indicate fluctuation in As content of the hydrothermal fluid. Mercury, in the form of cinnabar, occurs in up to 5 μm grains within arsenian pyrite layers, usually forming distinct cinnabar-enriched micro-layers. Hydrothermal Sr-rich barite (barite-celestine solid solution), pseudocubic alunite-jarosite solid solution and Mn- and Sr-enriched carbonates occur in various amounts and closely associated with pyrite and/or hydrous ferric oxides. Thallium-bearing sulfides and/or sulfosalts were not detected during our study; however, hydrous ferric oxides show thallium content of up to 0.5 wt. % Tl. The following scenarios may have played a role in pyrite precipitation at Paleochori: (a) H2S originally dissolved in the deep fluid but separated upon boiling could have reacted with oxygenated seawater under production of sulphuric acid, thus causing leaching and dissolution of primary iron

  15. Deep-Sea Magnetics on Active and Fossil Hydrothermal Sites: a Tool to Detect and Characterize Submarine Ore Deposits

    NASA Astrophysics Data System (ADS)

    Dyment, J.; Szitkar, F.; Fouquet, Y.; Choi, Y.

    2011-12-01

    Since the first discoveries of hydrothermal sites at mid-ocean ridges in the 70s, international efforts in the deep seafloor exploration have unravelled a wide variety of hydrothermal sites in terms of geological settings, physical parameters, and biological communities as well. Such efforts, coordinated in the InterRidge program since 1992, are becoming even more important when the increasing need in metals for developing economies makes the exploitation of metal sulfides accumulated at deep-sea hydrothermal sites a realistic target. The usual method to find hydrothermal sites is to detect the associated chemical plumes enriched in manganese, methane, hydrogen, helium 3, in the water column. How efficient it has been proven, such a method is limited to the search for active hydrothermal vents. Active vents, however, are not the best places for mining the seafloor, because (1) they host massive sulfides deposits in the making and may not represent the largest accumulation; (2) they are still very hot and would rapidly damage the mining tools; and, last but not the least, (3) they host fragile and precious ecosystem that could be dramatically affected by mining operations. Methods to find fossil hydrothermal sites (i.e. colder and devoid of specific ecosystems) include systematic rock sampling - a very tedious endeavour - and high resolution, near seafloor geophysical surveys. Existing magnetic surveys on basalt-hosted, peridotite-hosted and sediment-hosted sites revealed different types of signatures, which reflect the magnetizations of the host rock and the ore deposit, among others. Basalt-hosted sites exhibit negative magnetic anomalies, i.e. a deficit of magnetization, due to thermal demagnetization and hydrothermal alteration of the highly magnetic basalt, whereas both peridotite-hosted and sediment-hosted sites show positive anomalies, i.e. an excess of magnetization, clearly associated with the ore deposit. Results from recent cruises Serpentine (R

  16. High-temperature hydrothermal synthesis of crystalline mesoporous TiO2 with superior photo catalytic activities

    NASA Astrophysics Data System (ADS)

    Liu, Fujian; Liu, Chun-Lin; Hu, Baowei; Kong, Wei-Ping; Qi, Chen-Ze

    2012-07-01

    Mesoporous titanium dioxide with crystalline mesopore walls (M-TiO2-ns) have been successfully synthesized through the self-assembly of poly 4-Vinylpyridine template and tetrabutyl titanate precursor based on their complex bond interaction under high temperature (180 °C) hydrothermal conditions. X-ray diffraction shows that M-TiO2-ns have highly crystalline mesopore walls with anatase phase characters; N2 sorption-desorption isotherms, SEM and TEM images show that M-TiO2-ns have high BET surface areas (85 and 120 m2/g, respectively), large pore volumes (0.32 and 0.34 cm3/g, respectively) and crystalline mesopore walls, which exhibit monolithic morphology with crystal sizes around 3-5 μm. Interestingly, M-TiO2-ns exhibit much higher catalytic activities and good recyclability in both induced reduction of decabromodiphenyl and oxidation of Rhodamine B under UV light than those of nonporous crystalline TiO2 and M-TiO2 templated by hydrocarbon surfactant of F127, which is even comparable with that of commercial P25. Combination of the unique characters such as crystallinity, stable mesostructure, large BET surface areas and superior photo catalytic activities make M-TiO2-ns a kind of potentially important material for removing of organic pollutions in environment through green photo irradiation processes.

  17. Low Temperature Hydrothermal Synthesis of Visible-Light-Activated I-Doped TiO2 for Improved Dye Degradation.

    PubMed

    Wang, Dongting; Li, Jianwen; Zhou, Guangsheng; Wang, Wenxu; Zhang, Xianxi; Pan, Xu

    2016-06-01

    Iodine doped TiO2 with different iodine/Ti molar ratios has been firstly synthesized with a low temperature hydrothermal route and has been studied systematically in photocatalysis under visible light condition. The resulting iodine doped TiO2 were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (TEM), diffuse reflectance spectrum (DRS), and X-ray photoelectron spectroscopy (XPS). The photocatalytic performance investigations were conducted by means of the degradation of Rhodamine B (RhB) under the visible light irradiation in aqueous solution. Under an optimized I/Ti doping ratio of 10 mol%, the photocatalytic performance is greatly better, with degradation efficiency of 95%, which is almost double that of pure TiO2. The superior photocatalytic activity of iodine-doped TiO2 could be mainly attributed to extended visible light absorption originated from the formation of continuous states existed in the band gap of the doped TiO2 introduced by iodine. Active oxygen species, that is, *OH and O2-, were evidenced to be involved in the degradation process and a possible mechanism was also proposed.

  18. Low Temperature Hydrothermal Synthesis of Visible-Light-Activated I-Doped TiO2 for Improved Dye Degradation.

    PubMed

    Wang, Dongting; Li, Jianwen; Zhou, Guangsheng; Wang, Wenxu; Zhang, Xianxi; Pan, Xu

    2016-06-01

    Iodine doped TiO2 with different iodine/Ti molar ratios has been firstly synthesized with a low temperature hydrothermal route and has been studied systematically in photocatalysis under visible light condition. The resulting iodine doped TiO2 were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (TEM), diffuse reflectance spectrum (DRS), and X-ray photoelectron spectroscopy (XPS). The photocatalytic performance investigations were conducted by means of the degradation of Rhodamine B (RhB) under the visible light irradiation in aqueous solution. Under an optimized I/Ti doping ratio of 10 mol%, the photocatalytic performance is greatly better, with degradation efficiency of 95%, which is almost double that of pure TiO2. The superior photocatalytic activity of iodine-doped TiO2 could be mainly attributed to extended visible light absorption originated from the formation of continuous states existed in the band gap of the doped TiO2 introduced by iodine. Active oxygen species, that is, *OH and O2-, were evidenced to be involved in the degradation process and a possible mechanism was also proposed. PMID:27427614

  19. Hydrothermal synthesis of ZTO/graphene nanocomposite with excellent photocatalytic activity under visible light irradiation.

    PubMed

    Ben Ali, Monaam; Yolcu, Haci Hasan; Elhouichet, Habib; Sieber, Brigitte; Addad, Ahmed; Boussekey, Luc; Moreau, Myriam; Férid, Mokhtar; Szunerits, Sabine; Boukherroub, Rabah

    2016-07-01

    A facile and efficient one-step hydrothermal approach for the synthesis of Zn2SnO4 nanoparticles/reduced graphene oxide (ZTO/rGO) nanocomposites using zinc acetate, tin chloride and graphene oxide (GO) as precursors, and sodium hydroxide as reducing agent has been developed. This approach allows simultaneous reduction of GO and growth of spinel ZTO nanoparticles (NPs) on the rGO sheets. The morphology and microstructure characterizations of ZTO/rGO nanocomposites revealed that this method leads to close interfacial contact of ZTO NPs and rGO and efficient dispersion of ZTO NPs on the surface of rGO sheets. The photocatalytic activity of the ZTO/rGO nanocomposite was investigated for the reduction of rhodamine B under visible light irradiation. Compared to pure ZTO NPs, ZTO/rGO nanocomposite exhibited superior photocatalytic activity with a full degradation of rhodamine B within 15min. The enhanced photocatalytic performance of ZTO/rGO was mainly attributed to excellent electron trapping and effective adsorption properties of rGO.

  20. Anomalous quartz from the Roter Kamm impact crater, Namibia: Evidence for post-impact hydrothermal activity

    SciTech Connect

    Koeberl, C. Univ. of Vienna ); Fredriksson, K. ); Goetzinger, M. ); Reimold, W.U. )

    1989-08-01

    Centimeter-sized quartz pebbles have been found on the rim of the Roter Kamm impact crater. The Roter Kamm crater has a diameter of about 2.5 km and is situated in the Namib Desert, SWA/Namibia. Because of the sand coverage, impact products are exposed exclusively in the form of ejecta on the crater rim. The quartz pebbles were found close to the main deposits of the impact breccias and show signs of wind abrasion. Thin sections revealed that the pebbles consist of individual quartz domains that are up to 1 mm in size. Under crossed nicols (polarized light), all individual domains show extinction almost simultaneously within {plus minus}2{degree}, which is a rare phenomenon. Microprobe studies, neutron activation analyses, and X-ray diffractometry confirmed that the material consists of pure quartz. The quartz contains three different types of fluid inclusions: primary inclusions that record the formation conditions of the quartz, very small (<1 {mu}m) secondary inclusions associated with the grain boundaries, and late inclusions of irregular size. Freezing point depression measurements of the primary inclusions indicate fluid salinities between 18.3 and 19.6 wt% NaCl. Homogenization temperatures (T{sub h}) for the primary inclusions range from 165 to 250{degree}C. The quartz and the primary inclusions may provide evidence for a post-impact phase of extensive hydrothermal activity, generated by the residual heat from the kinetic energy of the impact.

  1. Hydrothermal synthesis of ZTO/graphene nanocomposite with excellent photocatalytic activity under visible light irradiation.

    PubMed

    Ben Ali, Monaam; Yolcu, Haci Hasan; Elhouichet, Habib; Sieber, Brigitte; Addad, Ahmed; Boussekey, Luc; Moreau, Myriam; Férid, Mokhtar; Szunerits, Sabine; Boukherroub, Rabah

    2016-07-01

    A facile and efficient one-step hydrothermal approach for the synthesis of Zn2SnO4 nanoparticles/reduced graphene oxide (ZTO/rGO) nanocomposites using zinc acetate, tin chloride and graphene oxide (GO) as precursors, and sodium hydroxide as reducing agent has been developed. This approach allows simultaneous reduction of GO and growth of spinel ZTO nanoparticles (NPs) on the rGO sheets. The morphology and microstructure characterizations of ZTO/rGO nanocomposites revealed that this method leads to close interfacial contact of ZTO NPs and rGO and efficient dispersion of ZTO NPs on the surface of rGO sheets. The photocatalytic activity of the ZTO/rGO nanocomposite was investigated for the reduction of rhodamine B under visible light irradiation. Compared to pure ZTO NPs, ZTO/rGO nanocomposite exhibited superior photocatalytic activity with a full degradation of rhodamine B within 15min. The enhanced photocatalytic performance of ZTO/rGO was mainly attributed to excellent electron trapping and effective adsorption properties of rGO. PMID:27054768

  2. Characteristics of Hydrothermal Mineralization in Ultraslow Spreading Ridges

    NASA Astrophysics Data System (ADS)

    Zhou, H.; Yang, Q.; Ji, F.; Dick, H. J.

    2014-12-01

    Hydrothermal activity is a major component of the processes that shape the composition and structure of the ocean crust, providing a major pathway for the exchange of heat and elements between the Earth's crust and oceans, and a locus for intense biological activity on the seafloor and underlying crust. In other hand, the structure and composition of hydrothermal systems are the result of complex interactions between heat sources, fluids, wall rocks, tectonic controls and even biological processes. Ultraslow spreading ridges, including the Southwest Indian Ridge, the Gakkel Ridge, are most remarkable end member in plate-boundary structures (Dick et al., 2003), featured with extensive tectonic amagmatic spreading and frequent exposure of peridotite and gabbro. With intensive surveys in last decades, it is suggested that ultraslow ridges are several times more effective than faster-spreading ridges in sustaining hydrothermal activities. This increased efficiency could attributed to deep mining of heat and even exothermic serpentinisation (Baker et al., 2004). Distinct from in faster spreading ridges, one characteristics of hydrothermal mineralization on seafloor in ultraslow spreading ridges, including the active Dragon Flag hydrothermal field at 49.6 degree of the Southwest Indian Ridge, is abundant and pervasive distribution of lower temperature precipitated minerals ( such as Fe-silica or silica, Mn (Fe) oxides, sepiolite, pyrite, marcasite etc. ) in hydrothermal fields. Structures formed by lower temperature activities in active and dead hydrothermal fields are also obviously. High temperature precipitated minerals such as chalcopyrite etc. are rare or very limited in hydrothermal chimneys. Distribution of diverse low temperature hydrothermal activities is consistence with the deep heating mechanisms and hydrothermal circulations in the complex background of ultraslow spreading tectonics. Meanwhile, deeper and larger mineralization at certain locations along the

  3. Hydrodynamic modeling of magmatic-hydrothermal activity at submarine arc volcanoes, with implications for ore formation

    NASA Astrophysics Data System (ADS)

    Gruen, Gillian; Weis, Philipp; Driesner, Thomas; Heinrich, Christoph A.; de Ronde, Cornel E. J.

    2014-10-01

    Subduction-related magmas have higher volatile contents than mid-ocean ridge basalts, which affects the dynamics of associated submarine hydrothermal systems. Interaction of saline magmatic fluids with convecting seawater may enhance ore metal deposition near the seafloor, making active submarine arcs a preferred modern analogue for understanding ancient massive sulfide deposits. We have constructed a quantitative hydrological model for sub-seafloor fluid flow based on observations at Brothers volcano, southern Kermadec arc, New Zealand. Numerical simulations of multi-phase hydrosaline fluid flow were performed on a two-dimensional cross-section cutting through the NW Caldera and the Upper Cone sites, two regions of active venting at the Brothers volcanic edifice, with the former hosting sulfide mineralization. Our aim is to explore the flow paths of saline magmatic fluids released from a crystallizing magma body at depth and their interaction with seawater circulating through the crust. The model includes a 3×2 km sized magma chamber emplaced at ∼2.5 km beneath the seafloor connected to the permeable cone via a ∼200 m wide feeder dike. During the simulation, a magmatic fluid was temporarily injected from the top of the cooling magma chamber into the overlying convection system, assuming hydrostatic conditions and a static permeability distribution. The simulations predict a succession of hydrologic regimes in the subsurface of Brothers volcano, which can explain some of the present-day hydrothermal observations. We find that sub-seafloor phase separation, inferred from observed vent fluid salinities, and the temperatures of venting at Brothers volcano can only be achieved by input of a saline magmatic fluid at depth, consistent with chemical and isotopic data. In general, our simulations show that the transport of heat, water, and salt from magmatic and seawater sources is partly decoupled. Expulsion of magmatic heat and volatiles occurs within the first few

  4. Vent fluid chemistry of the Rainbow hydrothermal system (36°N, MAR): Phase equilibria and in situ pH controls on subseafloor alteration processes

    NASA Astrophysics Data System (ADS)

    Seyfried, W. E., Jr.; Pester, Nicholas J.; Ding, Kang; Rough, Mikaella

    2011-03-01

    The Rainbow hydrothermal field is located at 36°13.8'N-33°54.15'W at 2300 m depth on the western flank of a non-volcanic ridge between the South AMAR and AMAR segments of the Mid-Atlantic Ridge. The hydrothermal field consists of 10-15 active chimneys that emit high-temperature (˜365 °C) fluid. In July 2008, vent fluids were sampled during cruise KNOX18RR, providing a rich dataset that extends in time information on subseafloor chemical and physical processes controlling vent fluid chemistry at Rainbow. Data suggest that the Mg concentration of the hydrothermal end-member is not zero, but rather 1.5-2 mmol/kg. This surprising result may be caused by a combination of factors including moderately low dissolved silica, low pH, and elevated chloride of the hydrothermal fluid. Combining end-member Mg data with analogous data for dissolved Fe, Si, Al, Ca, and H 2, permits calculation of mineral saturation states for minerals thought appropriate for ultramafic-hosted hydrothermal systems at temperatures and pressures in keeping with constraints imposed by field observations. These data indicate that chlorite solid solution, talc, and magnetite achieve saturation in Rainbow vent fluid at a similar pH (T,P) (400 °C, 500 bar) of approximately 4.95, while higher pH values are indicated for serpentine, suggesting that serpentine may not coexist with the former assemblage at depth at Rainbow. The high Fe/Mg ratio of the Rainbow vent fluid notwithstanding, the mole fraction of clinochlore and chamosite components of chlorite solid solution at depth are predicted to be 0.78 and 0.22, respectively. In situ pH measurements made at Rainbow vents are in good agreement with pH (T,P) values estimated from mineral solubility calculations, when the in situ pH data are adjusted for temperature and pressure. Calculations further indicate that pH (T,P) and dissolved H 2 are extremely sensitive to changes in dissolved silica owing to constraints imposed by chlorite solid solution

  5. Seawater bicarbonate removal during hydrothermal circulation

    NASA Astrophysics Data System (ADS)

    Proskurowski, G. K.; Seewald, J.; Sylva, S. P.; Reeves, E.; Lilley, M. D.

    2013-12-01

    High temperature fluids sampled at hydrothermal vents represent a complex alteration product of water-rock reactions on a multi-component mixture of source fluids. Sources to high-temperature hydrothermal samples include the 'original' seawater present in the recharge limb of circulation, magmatically influenced fluids added at depth as well as any seawater entrained during sampling. High-temperature hydrothermal fluids are typically enriched in magmatic volatiles, with CO2 the dominant species, characterized by concentrations of 10's-100's of mmol/kg (1, 2). Typically, the high concentration of CO2 relative to background seawater bicarbonate concentrations (~2.3 mmol/kg) obscures a full analysis of the fate of seawater bicarbonate during high-temperature hydrothermal circulation. Here we present data from a suite of samples collected over the past 15 years from high-temperature hydrothermal vents at 9N, Endeavour, Lau Basin, and the MAR that have endmember CO2 concentrations less than 10 mmol/kg. Using stable and radiocarbon isotope measurements these samples provide a unique opportunity to examine the balance between 'original' seawater bicarbonate and CO2 added from magmatic sources. Multiple lines of evidence from multiple hydrothermal settings consistently points to the removal of ~80% of the 'original' 2.3 mmol/kg seawater bicarbonate. Assuming that this removal occurs in the low-temperature, 'recharge' limb of hydrothermal circulation, this removal process is widely occurring and has important contributions to the global carbon cycle over geologic time. 1. Lilley MD, Butterfield DA, Lupton JE, & Olson EJ (2003) Magmatic events can produce rapid changes in hydrothermal vent chemistry. Nature 422(6934):878-881. 2. Seewald J, Cruse A, & Saccocia P (2003) Aqueous volatiles in hydrothermal fluids from the Main Endeavour Field, northern Juan de Fuca Ridge: temporal variability following earthquake activity. Earth and Planetary Science Letters 216(4):575-590.

  6. State of the hydrothermal activity of Soufrière of Guadeloupe volcano inferred by VLF surveys

    NASA Astrophysics Data System (ADS)

    Zlotnicki, J.; Vargemezis, G.; Mille, A.; Bruère, F.; Hammouya, G.

    2006-04-01

    La Soufrière (1467 m) is the active island arc volcano of Guadeloupe Island in the Lesser Antilles arc. Its historical eruptions are more or less violent phreatic outbursts the last of which, in 1976-1977, led to the evacuation of nearly 70 000 persons. The subsurface structure of the volcano consists of calderas, craters, and avalanche amphitheatres nested within the composite pile of eruptive products. Since the last magmatic eruption, dated ca. 1440 AD, the four phreatic eruptions have developed radial fractures on Soufrière dome favouring the development of a huge active hydrothermal system emphasized by a tropical environment. After the eruptions, the thermal state and the stable ground water flow are completely disorganised during several years during which the slow mineralization of rocks is becoming again preponderant. Sealing of fractures and decay of rocks permeability act as a cap for upward thermal transfers. Therefore Soufrière dome operates as a valve, resealing the hydrothermal system underlying the volcano thus providing over pressurization that could lead to the next phreatic eruption. In 1992 new small seismic swarms have appeared. Several of them are recorded every year while the emission of acid gas slowly increases. In order to recognise the superficial electrical resistive and conductive zones (less than 100 m depth) as well as the cavities on Soufrière volcano, we have made Very Low Frequency (VLF) surveys in 2000. Electrical conductive zones are clearly associated with major radial faults starting from the summit in which the hydrothermal activity takes place. In the continuation of these active hydrothermal fractures hot springs are located down slope. Conversely some of the resistive zones are associated with inactive clayed and sealed or opened faults. The distribution of the conductive zones allows detailing the state of the superficial part of the hydrothermal system of La Soufrière. The distribution of vertical clayed zones

  7. Acid-Base Behavior in Hydrothermal Processing of Wastes - Final Report

    SciTech Connect

    Johnston, K.; Rossky, P.

    2000-12-01

    A major obstacle to development of hydrothermal oxidation technology has been a lack of scientific knowledge of chemistry in hydrothermal solution above 350 C, particularly acid-base behavior, and transport phenomena, which is needed to understand corrosion, metal-ion complexation, and salt precipitation and recovery. Our objective has been to provide this knowledge with in situ UV-visible spectroscopic measurements and fully molecular computer simulation. Our recent development of relatively stable organic UV-visible pH indicators for supercritical water oxidation offers the opportunity to characterize buffers and to monitor acid-base titrations. These results have important implications for understanding reaction pathways and yields for decomposition of wastes in supercritical water.

  8. Agricultural residue valorization using a hydrothermal process for second generation bioethanol and oligosaccharides production.

    PubMed

    Vargas, Fátima; Domínguez, Elena; Vila, Carlos; Rodríguez, Alejandro; Garrote, Gil

    2015-09-01

    In the present work, the hydrothermal valorization of an abundant agricultural residue has been studied in order to look for high added value applications by means of hydrothermal pretreatment followed by fed-batch simultaneous saccharification and fermentation, to obtain oligomers and sugars from autohydrolysis liquors and bioethanol from the solid phase. Non-isothermal autohydrolysis was applied to barley straw, leading to a solid phase with about a 90% of glucan and lignin and a liquid phase with up to 168 g kg(-1) raw material valuable hemicellulose-derived compounds. The solid phase showed a high enzymatic susceptibility (up to 95%). It was employed in the optimization study of the fed-batch simultaneous saccharification and fermentation, carried out at high solids loading, led up to 52 g ethanol/L (6.5% v/v).

  9. Discovery of sublacustrine hydrothermal activity and associated massive sulfides and hydrocarbons in the north Tanganyika trough, East African Rift

    SciTech Connect

    Tiercelin, J.J.; Mondeguer, A. ); Thouin, C. ); Kalala, T. )

    1989-11-01

    Massive sulfides and carbonate mineral deposits associated with sublacustrine thermal springs were recently discovered along the Zaire side of the north Tanganyika trough, western branch of the East African Rift. This hydrothermal activity, investigated by scuba diving at a maximum depth of 20 m, is located at the intersection of major north-south normal faults and northwest-southeast faults belonging to the Tanganyika-Rukwa-Malawi (TRM) strike-slip fault zone. The preliminary results presented here come from analyses of sulfide deposits, hydrothermal fluids, and associated hydrocarbons that result from geothermal activity in this part of the East African Rift filled by a thick pile of sediment, the north Tanganyika trough.

  10. In vitro evaluation of H2O2 hydrothermal treatment of aged titanium surface to enhance biofunctional activity.

    PubMed

    Yoneyama, Yuya; Matsuno, Tomonori; Hashimoto, Yoshiya; Satoh, Tazuko

    2013-01-01

    Surface modification of titanium has been extensively investigated in implant science and technology in an effort to improve its osteoconductivity. The rate of protein adsorption on titanium surfaces is known to vary depending on the chemistry, structure, morphology, and titanium-specific biological aging of the surface. It is thus desirable to modify smooth titanium surfaces of miniimplants used as orthodontic anchors immediately prior to use. In this study, we have developed a simple surface modification of titanium alloy that improves its biofunctional activity. The surface of a Ti-6Al-4V disk was modified by applying 3% H(2)O(2) hydrothermal treatment using an autoclave. A nanostructured porous network TiO(2) was observed on the treated surface. Treated surfaces exhibited higher hydrophilicity, protein adsorption, and cell proliferation than untreated surfaces. 3% H(2)O(2) hydrothermal treatment is thought to provide biofunctional activity for aged titanium surface.

  11. Synthesis and electrochemical performance of Ti3C2Tx with hydrothermal process

    NASA Astrophysics Data System (ADS)

    Wang, Libo; Zhang, Heng; Wang, Bo; Shen, Changjie; Zhang, Chuanxiang; Hu, Qianku; Zhou, Aiguo; Liu, Baozhong

    2016-09-01

    In this study, a simple hydrothermal method has been developed to prepare Ti3C2Tx from Ti3AlC2 as a high-performance electrode material for supercapacitors. This method is environmentally friendly and has a low level of danger. The morphology and structure of the Ti3C2Tx can be controlled by hydrothermal reaction time, temperature and NH4F amounts. The prepared Ti3C2Tx was characterized by X-ray diffraction, field emission scanning electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and Brunauer-Emmet-Teller. The results show that the prepared Ti3C2Tx is terminated by O, OH, and F groups. The electrochemical properties of the Ti3C2Tx sample exhibit specific capacitance up to 141 Fcm-3 in 3 M KOH aqueous electrolyte, and even after 1000 cycles, no significant degradation of the volumetric capacitance was observed. These results indicate that the Ti3C2Tx material prepared by this hydrothermal method can be used in high performance supercapacitors.

  12. Synthesis and electrochemical performance of Ti3C2Tx with hydrothermal process

    NASA Astrophysics Data System (ADS)

    Wang, Libo; Zhang, Heng; Wang, Bo; Shen, Changjie; Zhang, Chuanxiang; Hu, Qianku; Zhou, Aiguo; Liu, Baozhong

    2016-08-01

    In this study, a simple hydrothermal method has been developed to prepare Ti3C2Tx from Ti3AlC2 as a high-performance electrode material for supercapacitors. This method is environmentally friendly and has a low level of danger. The morphology and structure of the Ti3C2Tx can be controlled by hydrothermal reaction time, temperature and NH4F amounts. The prepared Ti3C2Tx was characterized by X-ray diffraction, field emission scanning electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and Brunauer-Emmet-Teller. The results show that the prepared Ti3C2Tx is terminated by O, OH, and F groups. The electrochemical properties of the Ti3C2Tx sample exhibit specific capacitance up to 141 Fcm-3 in 3 M KOH aqueous electrolyte, and even after 1000 cycles, no significant degradation of the volumetric capacitance was observed. These results indicate that the Ti3C2Tx material prepared by this hydrothermal method can be used in high performance supercapacitors. [Figure not available: see fulltext.

  13. Processes and interactions in macrofaunal assemblages at hydrothermal vents: A modeling perspective

    NASA Astrophysics Data System (ADS)

    Shea, Katriona; Metaxas, Anna; Young, Curtis R.; Fisher, Charles R.

    Our understanding of the biological assemblages at hydrothermal vents is growing rapidly, in part facilitated by the coupling of experimental and observational methods with theoretical modeling efforts. We review theoretical approaches in four main areas and link them to empirical studies of the biology of hydrothermal vent systems. First, we describe models of dispersal of vent organisms within and among vent sites. These models fall broadly into two categories: those based on larval biology and currents that predict dispersal capabilities from a source, and those using genetic data to address historical genetic links between populations. Then we discuss models for individual and population growth at a location and give examples from work in a biologically similar deep-sea environment: cold seeps. Third, we address how these two aspects can be integrated using models that couple dispersal and demography. Last, we summarize existing modeling approaches for community succession in other types of habitats, and outline the conceptual models and the sorts of data that currently exist for hydrothermal vent communities. Throughout, we also examine the use of models in improving experimental design.

  14. Permeability Reduction in Passively Degassing Seawater-dominated Volcanic-hydrothermal systems: Processes and Perils on Raoul Island, Kermadecs (NZ)

    NASA Astrophysics Data System (ADS)

    Christenson, B. W.; Reyes, A. G.

    2014-12-01

    The 2006 eruption from Raoul Island occurred apparently in response to local tectonic swarm activity, but without any precursory indication of volcanic unrest within the hydrothermal system on the island. The eruption released some 200 T of SO2, implicating the involvement of a deep magmatic vapor input into the system during/prior to the event. In the absence of any recognized juvenile material in the eruption products, previous explanations for this eruptive event focused on this vapor being a driving force for the eruption. In 2004, at least 80 T/d of CO2 was escaping from the hydrothermal system, but mainly through areas that did not correspond to the 2006 eruption vents. The lack of a pre-eruptive hydrothermal system response related to the seismic event in 2006 can be explained by the presence of a hydrothermal mineralogic seal in the vent area of the volcano. Evidence for the existence of such a seal was found in eruption deposits in the form of massive fracture fillings of aragonite, calcite and anhydrite. Fluid inclusion homogenization temperatures in these phases range from ca. 140 °C to 220 °C which, for pure water indicate boiling point depths of between 40 and 230 m assuming a cold hydrostatic pressure constraint. Elevated pressures behind this seal are consistent with the occurrence of CO2 clathrates in some inclusion fluids, indicating CO2 concentrations approaching 1 molal in the parent fluids. Reactive transport modeling of magmatic volatile inputs into what is effectively a seawater-dominated hydrothermal system provide valuable insights into seal formation. Carbonate mineral phases ultimately come to saturation along this flow path, but we suggest that focused deposition of the observed massive carbonate seal is facilitated by near-surface boiling of these CO2-enriched altered seawaters, leading to large degrees of supersaturation which are required for the formation of aragonite. As the seal grew and permeability declined, pore pressures

  15. Integrated Geoscience Studies in the Greater Yellowstone Area - Volcanic, Tectonic, and Hydrothermal Processes in the Yellowstone Geoecosystem

    USGS Publications Warehouse

    Morgan, Lisa A.

    2007-01-01

    Yellowstone National Park, rimmed by a crescent of older mountainous terrain, has at its core the Quaternary Yellowstone Plateau, an undulating landscape shaped by forces of volcanism, tectonism, and later glaciation. Its spectacular hydrothermal systems cap this landscape. From 1997 through 2003, the United States Geological Survey Mineral Resources Program conducted a multidisciplinary project of Yellowstone National Park entitled Integrated Geoscience Studies of the Greater Yellowstone Area, building on a 130-year foundation of extensive field studies (including the Hayden survey of 1871, the Hague surveys of the 1880s through 1896, the studies of Iddings, Allen, and Day during the 1920s, and NASA-supported studies starting in the 1970s - now summarized in USGS Professional Paper 729 A through G) in this geologically dynamic terrain. The project applied a broad range of scientific disciplines and state-of-the-art technologies targeted to improve stewardship of the unique natural resources of Yellowstone and enable the National Park Service to effectively manage resources, protect park visitors from geologic hazards, and better educate the public on geologic processes and resources. This project combined a variety of data sets in characterizing the surficial and subsurface chemistry, mineralogy, geology, geophysics, and hydrothermal systems in various parts of the park. The sixteen chapters presented herein in USGS Professional Paper 1717, Integrated Geoscience Studies in the Greater Yellowstone Area - Volcanic, Tectonic, and Hydrothermal Processes in the Yellowstone Geoecosystem, can be divided into four major topical areas: (1) geologic studies, (2) Yellowstone Lake studies, (3) geochemical studies, and (4) geophysical studies. The geologic studies include a paper by Ken Pierce and others on the influence of the Yellowstone hotspot on landscape formation, the ecological effects of the hotspot, and the human experience and human geography of the greater

  16. The giant Carlin gold province: a protracted interplay of orogenic, basinal, and hydrothermal processes above a lithospheric boundary

    NASA Astrophysics Data System (ADS)

    Emsbo, Poul; Groves, David I.; Hofstra, Albert H.; Bierlein, Frank P.

    2006-09-01

    Northern Nevada hosts the only province that contains multiple world-class Carlin-type gold deposits. The first-order control on the uniqueness of this province is its anomalous far back-arc tectonic setting over the rifted North American paleocontinental margin that separates Precambrian from Phanerozoic subcontinental lithospheric mantle. Globally, most other significant gold provinces form in volcanic arcs and accreted terranes proximal to convergent margins. In northern Nevada, periodic reactivation of basement faults along this margin focused and amplified subsequent geological events. Early basement faults localized Devonian synsedimentary extension and normal faulting. These controlled the geometry of the Devonian sedimentary basin architecture and focused the discharge of basinal brines that deposited syngenetic gold along the basin margins. Inversion of these basins and faults during subsequent contraction produced the complex elongate structural culminations that characterize the anomalous mineral deposit “trends.” Subsequently, these features localized repeated episodes of shallow magmatic and hydrothermal activity that also deposited some gold. During a pulse of Eocene extension, these faults focused advection of Carlin-type fluids, which had the opportunity to leach gold from gold-enriched sequences and deposit it in reactive miogeoclinal host rocks below the hydrologic seal at the Roberts Mountain thrust contact. Hence, the vast endowment of the Carlin province resulted from the conjunction of spatially superposed events localized by long-lived basement structures in a highly anomalous tectonic setting, rather than by the sole operation of special magmatic or fluid-related processes. An important indicator of the longevity of this basement control is the superposition of different gold deposit types (e.g., Sedex, porphyry, Carlin-type, epithermal, and hot spring deposits) that formed repeatedly between the Devonian and Miocene time along the

  17. Geochemistry of Phosphorus and Nitrogen in Volcanic Rocks Altered by Submarine Hydrothermal Activities at the Suiyo Seamount in Japan

    NASA Astrophysics Data System (ADS)

    Noda, M.; Kakegawa, T.; Naraoka, H.; Marumo, K.; Urabe, T.

    2002-12-01

    Phosphorus and nitrogen are essential major elements for all microorganisms. In order to understand the ecological conditions of subvent microorganisms and thermophilic microorganisms on ocean floor, it is necessary to understand the behavior of bio-essential elements not only in hydrothermal fluids but also in the subvent environment. Nine sites of hydrothermal discharging area were drilled in the Suiyo volcanic caldera, Izu-Ogasawara (Bonin) island-arc, western Pacific. Approximately 2 to 10 m deep drill core samples were recovered in the last two years. Chemical compositions and hydrothermal mineral assemblages in the drilled core samples were determined by XRF, ICP-MS, and XRD. Morphology of phosphorous-bearing minerals and their chemistry were examined by electron microprobe. Nitrogen isotopes were measured by the EA-IRMS system. Primary igneous-rock texture (such as euhedral plagioclase phenocryst) is found in the less altered rocks. They often associated with montmorillonite. Highly altered rocks are divided into two groups. First group is characterized by extensive (up to 90%) replacement of primary igneous mineral assemblage by chlorite, mica and sulfide. Second group is cemented with large amounts of sulfates with sulfide (mainly pyrite). It is found in a few drill core sections that hydrothermal hydrous silicate minerals change with depth from montmorillonite to chlorite and mica through mixed layer of chlorite/montmorillonite. This may suggest the more extensive and higher temperature alteration in deeper zones in a certain area. Electron microprobe analyses and bulk chemical composition indicate that the depletion of phosphorous in altered rocks (below 0.1 wt%) but enrichment of phosphorous in sulfide zones. This suggests that phosphorous was easily dissolved from igneous rocks by hydrothermal process, but readily precipitated with sulfides. The reason for co-precipitation of phosphates with sulfides is not certain, but such co-precipitation mechanism

  18. Behavior of nuclear waste elements during hydrothermal alteration of glassy rhyolite in an active geothermal system: Yellowstone National Park, Wyoming

    SciTech Connect

    Sturchio, N.C.; Seitz, M.G.

    1984-12-31

    The behavior of a group of nuclear waste elements (U, Th, Sr, Zr, Sb, Cs, Ba, and Sm) during hydrothermal alteration of glassy rhyolite is investigated through detailed geochemical analyses of whole rocks, glass and mineral separates, and thermal waters. Significant mobility of U, Sr, Sb, Cs, and Ba is found, and the role of sorption processes in their observed behavior is identified. Th, Zr, and Sm are relatively immobile, except on a microscopic scale. 9 references, 2 figures, 2 tables.

  19. Hydrothermal REE and Zr Ore Forming Processes in Peralkaline Granitic Systems

    NASA Astrophysics Data System (ADS)

    Gysi, A. P.

    2015-12-01

    Anorogenic peralkaline igneous systems display extreme enrichment of REE and Zr with a hydrothermal overprint leading to post-magmatic metal mobilization. Strange Lake in Canada, for example, is a mid-Proterozoic peralkaline granitic intrusion and host to a world-class REE-Zr deposit with >50 Mt ore (>1.5 wt.% REE and >3 wt.% Zr). In contrast to porphyry systems, peralkaline systems are poorly understood and hydrothermal metal mobilization models are only in the early stage of their development. This is partly due to the paucity of thermodynamic data for REE-bearing minerals and aqueous species, and the complexity of the hydrothermal fluids (enrichment of F, P and Cl), which make it difficult to develop thermodynamic models of metal partitioning. This study aims to show the link between alteration stages and metal mobilization using Strange Lake as a natural laboratory and combine these observations with numerical modeling. Four types of alteration were recognized at Strange Lake: i) alkali (i.e. K and Na) metasomatism related to interaction with NaCl-bearing orthomagmatic fluids, ii) acidic alteration by HCl-HF-bearing fluids originating from the pegmatites followed by iii) aegirinization of the border of the pegmatites and surrounding granites and by iv) pervasive Ca-F-metasomatism. The acidic alteration accounts for most of the hydrothermal metal mobilization in and outward from the pegmatites, whereas the Ca-F-metasomatism led to metal deposition and resulted from interaction of an acidic F-rich fluid with a Ca-bearing fluid. Numerical simulations of fluid-rock reactions with saline HCl-HF-bearing fluids at 400 °C to 250 °C indicate that temperature, availability of F/Cl and pH limit the mobility of Zr and REE. Fluids with pH <2 led to the formation of quartz and fluorite in the core of the pegmatites and to an increase in the stability of REE chloride species favorable for REE mobilization. The mobilization of Zr was favored at low temperature with the

  20. Nitrogen-doped graphene/ZnSe nanocomposites: hydrothermal synthesis and their enhanced electrochemical and photocatalytic activities.

    PubMed

    Chen, Ping; Xiao, Tian-Yuan; Li, Hui-Hui; Yang, Jing-Jing; Wang, Zheng; Yao, Hong-Bin; Yu, Shu-Hong

    2012-01-24

    Nitrogen-doped graphene (GN) has great potential applications in many fields because doping with nitrogen can alter the electrical properties of graphene. It is still a challenge to develop a convenient method for synthesis of GN sheets. In this paper, we first report the synthesis of a nitrogen-doped graphene/ZnSe nanocomposite (GN-ZnSe) by a one-pot hydrothermal process at low temperature using graphene oxide nanosheets and [ZnSe](DETA)(0.5) nanobelts as precursors. ZnSe nanorods composed of ZnSe nanoparticles were found to deposit on the surface of the GN sheets. The results demonstrated that [ZnSe](DETA)(0.5) nanobelts were used not only as the source of ZnSe nanoparticles but also as the nitrogen source. Interestingly, it was found that the as-prepared nanocomposites exhibit remarkably enhanced electrochemical performance for oxygen reduction reaction and photocatalytic activities for the bleaching of methyl orange dye under visible-light irradiation. This facile and catalyst-free approach for depositing ZnSe nanoparticles onto the graphene sheets may provide an alternative way for preparation of other nanocomposites based on GN sheets under mild conditions, which show their potential applications in wastewater treatment, fuel cells, energy storage, nanodevices, and so on. PMID:22136425

  1. Synthesis of flower- and rod-like nickel sulfide nanostructures by an organic-free hydrothermal process

    SciTech Connect

    Pan Qingtao; Huang Kai; Ni Shibing; Yang Feng; He Deyan

    2008-06-03

    Well-crystalline flower- and rod-like NiS nanostructures have been synthesized by an organic-free hydrothermal process at a low temperature of 200 deg. C. X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) were employed to characterize the as-synthesized NiS nanostructures. The effects of temperature and reaction time on the morphology have been also investigated. The two-step flake-cracking mechanism for the formation of flower- and rod-like NiS nanostructures was discussed. The products were also investigated by photoluminescence (PL) spectroscopy.

  2. Hydrothermal carbonization and torrefaction of grape pomace: a comparative evaluation.

    PubMed

    Pala, Mehmet; Kantarli, Ismail Cem; Buyukisik, Hasan Baha; Yanik, Jale

    2014-06-01

    Grape pomace was treated by hydrothermal carbonization (sub-critical water, 175-275°C) and torrefaction (nitrogen atmosphere, 250 and 300°C), with mass yield of solid product (char) ranging between 47% and 78%, and energy densification ratio to 1.42-1.15 of the original feedstock. The chars were characterised with respect to their fuel properties, morphological and structural properties and combustion characteristics. The hydrothermal carbonization produced the char with greater energy density than torrefaction. The chars from torrefaction were found to be more aromatic in nature than that from hydrothermal carbonization. Hydrothermal carbonization process produced the char having high combustion reactivity. Most interesting was the finding that aqueous phase from hydrothermal carbonization had antioxidant activity. The results obtained in this study showed that HTC appears to be promising process for a winery waste having high moisture content.

  3. Microearthquakes at the active Trans-Atlantic Geotraverse (TAG) hydrothermal mound, Mid-Atlantic Ridge, 26°08'N

    NASA Astrophysics Data System (ADS)

    Pontbriand, C.; Reves-Sohn, R. A.

    2010-12-01

    A small 200 m aperture network of five ocean bottom seismometers around the periphery the active TAG hydrothermal mound on the Mid-Atlantic Ridge (26°08’N) detected microearthquake events that may be associated with the subsurface hydraulics of the massive hydrothermal deposit. Seismic data were sampled at 100 Hz for a period of eight months spanning June, 2003 to February, 2004, during which time 24,191 locatable events were detected. Microearthquake hypocenters are concentrated within a 300 m radius of the sulfide mound in the top 250 m of crust, and exhibit a conical shape with the deepest events beneath the mound center. Event rates are steady at 180 events per day at the beginning of the study period and decline slightly to 116 events per day after whale calls elevate background noise levels about 2/3 of the way through the deployment. The mean local magnitude of events is -1.2 with a range of -2.9≦ML≦0.3. We suggest that events may be largely due to hydraulic fracturing of clogged flow conduits in the mineral deposit, which provides the possibility of using the microearthquake data to constrain subsurface flow parameters and the permeability structure of the active TAG deposit. Figure: A bathymetric map of the TAG area depicts a small aperture network of 5 ocean bottom seismometers (white triangles) around the periphery of the active TAG hydrothermal mound. High resolution bathymetry is from Roman and Singh, 2005.

  4. SeaVOICE: Sea-going Experiments to Test Potential Linkages among Sea Level Change, Ocean Ridge Volcanism, and Hydrothermal Activity.

    NASA Astrophysics Data System (ADS)

    Langmuir, C. H.; Carbotte, S. M.; Huybers, P. J.; McManus, J. F.; Mukhopadhyay, S.; Winckler, G.; Boulahanis, B.; Costa, K.; Ferguson, D.; Katz, R. F.; Li, Y.; Middleton, J. L.

    2015-12-01

    Changes in sea level influence the pressure of the solid Earth over entire ocean basins. While the absolute changes in sea level caused by glacial cycles are small relative to ocean depths, the temporal variations in sea level can lead to pressure changes of similar order to mantle upwelling rates, with the potential to significantly perturb short term rates of melt production at ocean ridges (Huybers and Langmuir, EPSL, 2009). Such changes could then lead to fluctuations in crustal thickness, magma composition and hydrothermal activity. To investigate possible relationships between glacial cycles and ocean ridge processes, we carried out an 18 day cruise of mapping and sediment coring to the Cleft Segment of the Juan de Fuca ridge. High resolution bathymetry was obtained on the west side of the ridge axis to beyond 1Ma to test whether abyssal hill fabric shows periodicities consistent with glacial cycles. Nine successful piston cores up to 7.6m in length provide a sedimentary record back to more than 600kyr to test for spatial and temporal variations in hydrothermal activity. Oxygen isotope stratigraphy on these cores is systematic and provides good age constraints. Short cores near the ridge axis provide a record of the current trace of hydrothermal activity in youngest sediments. Several of the cores impacted basement and recovered a basement sample. Above basement, basaltic glass shards were recovered in the bottom meter of sediment, raising the possibility of temporal records of basalt chemical compositions using the age constraints the sediments provide. The glass samples provide a unique and new perspective on ridge volcanism, since previous off-axis samples were restricted to dredging old fault scarps. Cores can be taken anywhere, raising the potential for global time series studies of ridge volcanism. The coupled bathymetry, sediment geochemistry and magmatic glass compositions hold the promise of a definitive advance in our understanding of the

  5. Recent uplift and hydrothermal activity at Tangkuban Parahu volcano, west Java, Indonesia

    USGS Publications Warehouse

    Dvorak, J.; Matahelumual, J.; Okamura, A.T.; Said, H.; Casadevall, T.J.; Mulyadi, D.

    1990-01-01

    Tangkuban Parahu is an active stratovolcano located 17 km north of the city of Bandung in the province west Java, Indonesia. All historical eruptive activity at this volcano has been confined to a complex of explosive summit craters. About a dozen eruptions-mostly phreatic events- and 15 other periods of unrest, indicated by earthquakes or increased thermal activity, have been noted since 1829. The last magmatic eruption occurred in 1910. In late 1983, several small phreatic explosions originated from one of the summit craters. More recently, increased hydrothermal and earthquake activity occurred from late 1985 through 1986. Tilt measurements, using a spirit-level technique, have been made every few months since February 1981 in the summit region and along the south and east flanks of the volcano. Measurements made in the summit region indicated uplift since the start of these measurements through at least 1986. From 1981 to 1983, the average tilt rate at the edges of the summit craters was 40-50 microradians per year. After the 1983 phreatic activity, the tilt rate decreased by about a factor of five. Trilateration surveys across the summit craters and on the east flank of the volcano were conducted in 1983 and 1986. Most line length changes measured during this three-year period did not exceed the expected uncertainty of the technique (4 ppm). The lack of measurable horizontal strain across the summit craters seems to contradict the several years of tilt measurements. Using a point source of dilation in an elastic half-space to model tilt measurements, the pressure center at Tangkuban Parahu is located about 1.5 km beneath the southern part of the summit craters. This is beneath the epicentral area of an earthquake swarm that occurred in late 1983. The average rate in the volume of uplift from 1981 to 1983 was 3 million m3 per year; from 1983 to 1986 it averaged about 0.4 million m3 per year. Possible causes for this uplift are increased pressure within a very

  6. Linking microbial ultrastructure and physiology to iron depositional processes in deep sea hydrothermal environments

    NASA Astrophysics Data System (ADS)

    Chan, C. S.; Fleming, E. J.; Emerson, D.; Edwards, K. J.

    2008-12-01

    Clara S. Chan, Emily Fleming, David Emerson, Katrina J. Edwards Iron microbial mats have been discovered in a variety of deep-sea hydrothermal environments and are increasingly being recognized as more seafloor is explored. The predominant structures found in many of these mats are iron oxyhydroxide-rich filaments. One of the most common structures is a helical stalk bearing a resemblance to the twisted stalk of the terrestrial iron-oxidizing microbe, Gallionella ferruginea. While Gallionella has not been detected in, or isolated from, these mats microaerophilic iron-oxidizing, a stalk- forming bacterium, Mariprofundus ferrooxydans (PV-1 and related strains) has been isolated from mats at the Loihi seamount in Hawaii (Emerson et al. 2007, PLoS One 2(8): e667). Fossilized aggregates of iron filaments have been observed in the rock record (e.g. Little et al. 2004, Geomicrobiol. J. 21:415), and may represent ancient versions of these microbial mats. If this is shown to be true, such filaments would represent one of the few microfossil morphologies that can be linked to a specific microbial metabolism. We have used a combination of test tube culturing, microslide culturing, time lapse microscopy, and electron microscopy to study Mariprofundus stalk morphology and genesis and link these details to physiological responses to environmental chemistry. The goals include determining specific attributes of stalk morphology that can be used to determine the biogenicity of putative iron microfossils, and interpret the conditions of the depositional environment. Light microscopic observation of microslide cultures over the course of several days allowed for determination of bacterial response to developing oxygen and Fe(II) gradients. Once gradients have been established, given an abundant supply of oxygen, cells congregate in a band perpendicular to the gradient and stalks are formed, growing in the direction of increasing oxygen (and decreasing Fe) concentration. This

  7. Investigating microbial colonization in actively forming hydrothermal deposits using thermocouple arrays

    NASA Astrophysics Data System (ADS)

    Tivey, M. K.; Reysenbach, A. L.; Hirsch, M.; Steinberg, J.; Flores, G. E.

    2010-12-01

    Investigations of microbial colonization of very young hydrothermal deposits were carried out in 2009 at hydrothermal vents in the Lau Basin (SW Pacific), and in Guaymas Basin, Gulf of California, with a test deployment at the Rainbow vent field on the Mid-Atlantic Ridge in 2008. Our method entailed razing active chimneys and placing arrays of temperature probes (8 titanium-encased probes with their tips placed within a titanium cage) over the active flow. The chimneys that grew back through each array, encasing the temperature probe tips, were recovered after 2 to 15 days, along with temperature records. Molecular phylogenetic methods are being used to reveal the members of the microbial communities that developed in each chimney of known age and thermal history. A total of 15 array deployments were made at 10 vents in 6 different vent fields. Similar morphology beehives (with porous fine-grained interiors and steep temperature gradients across the outermost more-consolidated “wall”) formed at 2 of the 3 vents in Guaymas Basin (in 2 and 5 days at one vent and 3 and 15 days at a second), and at one vent each in the Kilo Moana (in 3 days), Tahi Moana (in 2.5 days), and Tui Malila (in 3 and 8 days) vent fields in the Lau Basin. In contrast, open conduit, thin walled chimneys grew within arrays at the Mariner vent field, Lau Basin, at 3 different vents (in 3 days at one vent, in 3 and 11 days at a second vent, and in 13 days at a third vent). A lower temperature (<280C) diffuser/spire with a filamentous biofilm formed in 15 days in an array at a hydrocarbon-rich vent in the Guaymas Basin. A similar biofilm formed after 6 days within an array placed earlier at this same vent, with little mineralization. Preliminary diversity data from the 6 and 15 day Guaymas deployments show an increased diversity of bacteria with time with initial colonizers being primarily sulfur-oxidizing Epsilonproteobacteria, with members of the Aquificales and Deltaproteobacteria appearing

  8. Implications of the Iceland Deep Drilling Project for improving understanding of hydrothermal processes at slow spreading mid-ocean ridges

    NASA Astrophysics Data System (ADS)

    Elders, Wilfred A.; Friðleifsson, Guðmundur Ómar

    The Iceland Deep Drilling Project (IDDP) is investigating producing geothermal energy from magma-hydrothermal systems at supercritical conditions. This requires drilling to depths of 4 to 5 km where temperatures should be in the range of 450-600°C or higher. Modeling studies suggest producing superheated steam from supercritical temperatures >450°C could increase power output tenfold relative to steam produced from a 300°C reservoir. The first IDDP well was drilled at Krafla within a volcanic caldera in the active rift zone of NE Iceland. At the end of June 2009, drilling was terminated at only 2100 m depth when a >900°C rhyolitic magma flowed into the drill hole. The well was completed with a casing cemented a few meters above the magma. Depending on the result of a planned flow test, there is the possibility of creating the world's hottest "Engineered Geothermal System" by injecting water in a nearby well to produce superheated steam from the magma. An advantage of such a strategy would be that the acidic gases likely to be given off by the magma could be neutralized by injecting suitably treated water. Two new wells, ˜4 km deep, are planned to be drilled during 2010-2012 at the Hengill and the Reykjanes geothermal fields in SW Iceland to explore for supercritical zones. The Reykjanes geothermal system produces hydrothermally modified seawater. This presents an ideal situation to study a high-temperature magma-hydrothermal system at depth analogous to those responsible for the black smokers at submarine divergent plate margins.

  9. Synthesis of kalsilite from microcline powder by an alkali-hydrothermal process

    NASA Astrophysics Data System (ADS)

    Su, Shuang-qing; Ma, Hong-wen; Yang, Jing; Zhang, Pan; Luo, Zheng

    2014-08-01

    The properties of aluminosilicate kalsilite have attracted the interest of researchers in chemical synthesis, ceramic industry, biofuels, etc. In this study, kalsilite was hydrothermally synthesized from microcline powder in a KOH solution. The microcline powder, rich in potassium, aluminum, and silicon, was collected from Mountain Changling in Northwestern China. The effects of temperature, time, and KOH concentration on the decomposition of microcline were investigated. The kalsilite and intermediate products were characterized by means of wet chemistry analysis, X-ray Diffraction (XRD), infrared spectrometry (IR), 29Si magic angle spinning nuclear magnetic resonance (29Si MAS NMR), 27Al MAS NMR, and scanning electron microscope (SEM). With increasing temperature, the microcline powder transforms into a metastable KAlSiO4 polymorph before transforming further into pure kalsilite. A mixture of both kalsilite and metastable KAlSiO4 polymorph is obtained when the hydrothermal reaction is carried out within 2 h; but after 2 h, kalsilite is the predominant product. The concentration of KOH, which needs to be larger than 4.3 M, is an important parameter influencing the synthesis of kalsilite.

  10. Significance of the 1982-2014 Campi Flegrei seismicity: Preexisting structures, hydrothermal processes, and hazard assessment

    NASA Astrophysics Data System (ADS)

    Di Luccio, F.; Pino, N. A.; Piscini, A.; Ventura, G.

    2015-09-01

    We find that the double-difference relocated seismicity, which occurred over the last 30 years at Campi Flegrei, was triggered by the uprising of fluids preferentially concentrated along onshore and offshore NW striking preexisting caldera faults. Focal volumes of the 2005-2014 seismicity do not overlap that of the 1982-1984 period, when a major uplift of 1.8 m occurred in the central sector of the caldera. This indicates a transition from an elastic to a plastic behavior due to fluid saturation and heating of the rocks in the hydrothermal reservoir. The 2012-2014 deeper earthquakes are located in a low VP/VS zone at the western boundary of the hydrothermal reservoir, where a volume increase from a magmatic body at 3.5 km depth has been recognized. The progressive rheological change from elastic to plastic in the upper 4 km of the crust implies that a slow upward migration of magma may not necessarily be preceded by earthquakes or swarms.

  11. Making a black shale shine: the interaction of hydrothermal fluids and diagenetic processes

    NASA Astrophysics Data System (ADS)

    Gleeson, Sarah; Magnall, Joe; Reynolds, Merilie

    2016-04-01

    Hydrothermal fluids are important agents of mass and thermal transfer in the upper crust. This is exemplified by shale-hosted massive sulphide deposits (SHMS), which are anomalous accumulations of Zn and Pb sulphides (± barite) in sedimentary basins created by hydrothermal fluids. These deposits occur in passive margin settings and, typically, there is no direct evidence of magmatic input. Recent studies of Paleozoic deposits in the North American Cordillera (MacMillan Pass and Red Dog Districts) have shown that the deposits are formed in a sub-seafloor setting, where the potential for thermal and chemical gradients is high. Mineralization is characterized by the replacement and displacement of unconsolidated, partially lithified and lithified biosiliceous mudstones (± carbonates), and commonly the sulphide mineralization post-dates, and replaces, bedded barite units in the sediments. The Red Dog District (Alaska, USA) contain some of the largest Zn-Pb deposits ever discovered. The host-rocks are dominantly carbonaceous mudstones, with carbonate units and some radiolarites. The ore forms massive sulphide bodies that replace pyritized mudstones, barite and carbonate units. Lithological and textural relationships provide evidence that much of the ore formed in bioturbated, biosiliceous zones that may have had high primary porosity and/or permeability. Sediment permeability may have been further modified by aging of the silica rich sediments and the dissolution/replacement of carbonate and barite beds. At the Tom and Jason deposits (MacMillan Pass, Yukon) the fault-controlled hydrothermal upflow zone is uniquely preserved as an unequivocal vent complex. Here, the metal bearing fluids are hot (300°C), low salinity (6 wt% NaCl equiv.) and acidic (pH < 4.5). These fluids were initially in thermal and chemical disequilibrium with a partially lithified organic rich host-rock but cooled rapidly during fluid rock interaction and the input of diagenetic pore fluids

  12. Intertidal rocky shore seaweed communities subject to the influence of shallow water hydrothermal activity in São Miguel (Azores, Portugal)

    NASA Astrophysics Data System (ADS)

    Wallenstein, Francisco M.; Couto, Ruben P.; Torrão, Daniel F.; Neto, Ana I.; Rodrigues, Armindo S.; Wilkinson, Martin

    2013-09-01

    The volcanic origin of the Azores archipelago (Portugal) gives rise to active deep sea and shallow water hydrothermal activity that affects benthic communities. Intertidal seaweed surveys were conducted at two shores affected by intense shallow water hydrothermal vents. Water temperature, acidity and salinity were monitored. Seaweed communities were found to be species poor and have a disproportionally larger number of filamentous early successional species on shores that are subject to the effect of hot and acidic freshwater of volcanic origin. There is an ecological resemblance between hydrothermally affected seaweed communities in the Azores and those affected by acid mine drainage in the UK, thus indicating that hydrothermalism can be a useful scenario for pollution studies under conditions of ocean warming and acidification.

  13. Chlorine isotope and Cl-Br fractionation in fluids of Poás volcano (Costa Rica): Insight into an active volcanic-hydrothermal system

    NASA Astrophysics Data System (ADS)

    Rodríguez, Alejandro; Eggenkamp, H. G. M.; Martínez-Cruz, María; van Bergen, Manfred J.

    2016-10-01

    Halogen-rich volcanic fluids issued at the surface carry information on properties and processes operating in shallow hydrothermal systems. This paper reports a long-term record of Cl-Br concentrations and δ37Cl signatures of lake water and fumaroles from the active crater of Poás volcano (Costa Rica), where surface expressions of magmatic-hydrothermal activity have shown substantial periodic changes over the last decades. Both the hyperacid water of its crater lake (Laguna Caliente) and subaerial fumaroles show significant temporal variability in Cl-Br concentrations, Br/Cl ratios and δ37Cl, reflecting variations in the mode and magnitude of volatile transfer. The δ37Cl signatures of the lake, covering the period 1985-2012, show fluctuations between + 0.02 ± 0.06‰ and + 1.15 ± 0.09‰. Condensate samples from adjacent fumaroles on the southern shore, collected during the interval (2010-2012) with strong changes in gas temperature (107-763°C), display a much larger range from - 0.43 ± 0.09‰ to + 14.09 ± 0.08‰. Most of the variations in Cl isotope, Br/Cl and concentration signals can be attributed to interaction between magma-derived gas and liquid water in the volcanic-hydrothermal system below the crater. The δ37Cl were lowest and closest to magmatic values in (1) fumarolic gas that experienced little or no interaction with subsurface water and followed a relatively dry pathway, and (2) water that captured the bulk of magmatic halogen output so that no phase separation could induce fractionation. In contrast, elevated δ37Cl can be explained by partial scavenging and fractionation during subsurface gas-liquid interaction. Hence, strong Cl isotope fractionation leading to very high δ37Cl in Poás' fumaroles indicates that they followed a wet pathway. Highest δ37Cl values in the lake water were found mostly in periods when it received a significant input from subaqueous fumaroles or when high temperatures and low pH caused HCl evaporation. It is

  14. Geochemical constraints on the diversity and activity of H2 -oxidizing microorganisms in diffuse hydrothermal fluids from a basalt- and an ultramafic-hosted vent.

    PubMed

    Perner, Mirjam; Petersen, Jillian M; Zielinski, Frank; Gennerich, Hans-Hermann; Seifert, Richard

    2010-10-01

    Mixing processes of reduced hydrothermal fluids with oxygenated seawater and fluid-rock reactions contribute to the chemical signatures of diffuse venting and likely determine the geochemical constraints on microbial life. We examined the influence of fluid chemistry on microbial diversity and activity by sampling diffuse fluids emanating through mussel beds at two contrasting hydrothermal vents. The H(2) concentration was very low at the basalt-hosted Clueless site, and mixing models suggest O(2) availability throughout much of the habitat. In contrast, effluents from the ultramafic-hosted Quest site were considerably enriched in H(2) , while O(2) is likely limited to the mussel layer. Only two different hydrogenase genes were identified in clone libraries from the H(2) -poor Clueless fluids, but these fluids exhibited the highest H(2) uptake rates in H(2) -spiked incubations (oxic conditions, at 18 °C). In contrast, a phylogenetically diverse H(2) -oxidizing potential was associated with distinct thermal conditions in the H(2) -rich Quest fluids, but under oxic conditions, H(2) uptake rates were extremely low. Significant stimulation of CO(2) fixation rates by H(2) addition was solely illustrated in Quest incubations (P-value <0.02), but only in conjunction with anoxic conditions (at 18 °C). We conclude that the factors contributing toward differences in the diversity and activity of H(2) oxidizers at these sites include H(2) and O(2) availability.

  15. Co3O4-reduced graphene oxide nanocomposite synthesized by microwave-assisted hydrothermal process for Li-ion batteries

    NASA Astrophysics Data System (ADS)

    Park, Sang-Hoon; Kim, Hyun-Kyung; Roh, Kwang Chul; Kim, Kwang-Bum

    2015-03-01

    A nanocomposite of Co3O4 and reduced graphene oxide (Co3O4-rGO) was successfully synthesized as an anode material for lithium-ion batteries by a one-pot microwave-assisted hydrothermal process. In the nanocomposite, Co3O4 nanoparticles with narrow size distribution in the range of 10-30 nm uniformly decorated the surface of rGO, indicating that rGO could act as a two-dimensional template for the heterogeneous precipitation of Co3O4 nanoparticles. To investigate the effect of mass ratios of Co3O4 and rGO on the electrochemical properties, the Co3O4 loading in the nanocomposite was controlled during the microwave-assisted hydrothermal synthesis. The resulting nanocomposite electrode exhibited high electrochemical performance in terms of specific capacity and cyclability, indicating that rGO served as an efficient template material to provide a highly conducting and buffering network for Co3O4 nanoparticles. [Figure not available: see fulltext.

  16. The effect of solution chemistry on the preparation of MgAl{sub 2}O{sub 4} by hydrothermal-assisted sol-gel processing

    SciTech Connect

    Amini, M.M. . E-mail: m-pouramini@cc.sbu.ac.ir; Mirzaee, M.; Sepanj, N.

    2007-03-22

    Preparation of magnesium aluminate spinel powder by hydrothermal-assisted sol-gel processing from MgAl{sub 2}(OCH{sub 2}CH{sub 2}OR){sub 8}, R=CH{sub 3} (1), CH{sub 2}CH{sub 2}OCH{sub 3} (2), MgAl{sub 2}[OCH(CH{sub 3}){sub 2}]{sub 8} (3) and MgAl{sub 2}(O- {sup s}Bu){sub 8} (4) in toluene and parent alcohol has been investigated. Coordination status of aluminum atom in precursors was determined by {sup 27}Al NMR and correlation between coordination number of aluminum and development of spinel phase in hydrothermal-assisted sol-gel processing has been studied. The gels obtained from hydrothermal-assisted hydrolysis of magnesium-aluminum alkoxides that contain six-coordinated aluminum atoms in solution (1 and 2) after calcination at 700 deg. C resulted in the formation of pure spinel phase, whereas in similar hydrolysis and calcination processes of precursors that contain four-coordinated aluminum (3 and 4) spinel phase forms along with some Al{sub 2}O{sub 3} and MgO. Selected powders obtained from hydrothermal-assisted sol-gel processing were characterized by thermal analysis (TGA/DSC), X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). Results indicate that the coordination status of aluminum in the precursor is very crucial for the formation of pure phase spinel. The morphology of prepared spinels was studied by SEM and the results showed that the solvent in hydrothermal-assisted sol-gel processing has a marked effect on the morphology of the resulting MgAl{sub 2}O{sub 4}. In hydrothermal-assisted sol-gel processing of aluminum-magnesium alkoxides in hydrophobic solvent, spherical particles are formed, while in the parent alcohol, non-spherical powders are formed.

  17. Observations of Flatfish "Spas" From Three Hydrothermally Active Seamounts in the Mariana Arc

    NASA Astrophysics Data System (ADS)

    Dower, J.; Tunnicliffe, V.; Tyler, J.; Juniper, K.; Stevens, C.; Kouris, A.; Takano, B.

    2006-12-01

    During a cruise to the Mariana Islands in spring 2004, dense aggregations of small flatfish were recorded from areas of diffuse flow on two hydrothermally active seamounts known as Kasuga-2 and Daikoku. This is quite novel, as flatfish are not known to be part of vent faunas elsewhere. Based on a single specimen, it was determined to be a new species of tonguefish in the genus Symphurus, and is currently under description. In October 2005, we returned to the Mariana Arc and collected about 60 specimens from Kasuga-2, Daikoku, and a third site, Nikko Seamount. Interestingly, the Nikko specimens were about twice as large as the flatfish from Kasuga-2 and Daikoku. Current molecular work (using the Barcode of Life Data System) will determine the relationship among these populations, and verify whether they are the same species. Under the microscope, the sandy sediments from the flatfish habitat were found to be full of tiny nematodes and polychaete worms. Our current hypothesis is that the fish are feeding on both and, thus, are ultimately supported by chemosynthesis, since the worms likely feed on bacteria in the sediments. However, during our most recent cruise in May 2006, we also observed several instances in which dead (or nearly dead) mid-water fish and shrimp fell out of the water column onto the bottom, after which they were almost immediately fed upon by the flatfish. This suggests that there may also be an additional energy subsidy to the seamount benthos from the water column. We hypothesize that sulfite (or some other toxic chemical) in the plume overlying these active volcanoes either kills or anesthetizes small pelagics that get advected over the seamount summit while feeding in near-surface waters at night. Stable isotope and lipid analysis of samples from these "fish spas" are currently underway to establish trophic relationships. We hope to use otolith microstructure analyses to quantify individual growth trajectories and population age structure of

  18. Realization of single-termination SrTiO{sub 3} (100) surfaces by a microwave-induced hydrothermal process

    SciTech Connect

    Velasco-Davalos, Ivan; Thomas, Reji; Ruediger, Andreas

    2013-11-11

    A microwave-induced hydrothermal etching of SrTiO{sub 3} (100) single crystal surfaces in deionized water and subsequent annealing in oxygen atmosphere results in single-terminated and atomically flat terraces for pure and niobium-doped substrates as confirmed through one unit-cell step height and uniform phase by atomic force microscopy. This process that requires 3 min of moderate microwave radiation completely avoids the use of hydrofluoric acid (HF) and related point defects due to fluorine in the crystal surface. The advantages of a safe, inexpensive, and environmentally neutral process hold promise to replace the existing standard protocol for substrate preparation based on buffered HF.

  19. Characterization of products from hydrothermal carbonization of orange pomace including anaerobic digestibility of process liquor.

    PubMed

    Erdogan, Ezgi; Atila, Buse; Mumme, Jan; Reza, M Toufiq; Toptas, Asli; Elibol, Murat; Yanik, Jale

    2015-11-01

    In this study, the effect of the temperature and reaction time on hydrothermal carbonization (HTC) of orange pomace was investigated. In addition, a set of anaerobic batch tests were performed to determine the resulting biogas and methane potential of the spent liquor. Hydrochar yields followed a decreasing trend with the increasing temperature, whereas reaction time had no considerably effect on the yield. The evolution of the H/C and O/C atomic ratios from the raw material to the hydrochars suggested that dehydration reactions prevail during HTC. The hydrochars tended to become enriched in Ca, Mg and P minerals by increasing HTC temperature. The heavy metal contents in hydrochars were found below limits and no PAH compound was detected. Anaerobic digestion tests showed that the aqueous phase from HTC can be used as feedstocks for biogas production. PMID:26226579

  20. Algal biofuels from urban wastewaters: maximizing biomass yield using nutrients recycled from hydrothermal processing of biomass.

    PubMed

    Selvaratnam, T; Pegallapati, A K; Reddy, H; Kanapathipillai, N; Nirmalakhandan, N; Deng, S; Lammers, P J

    2015-04-01

    Recent studies have proposed algal cultivation in urban wastewaters for the dual purpose of waste treatment and bioenergy production from the resulting biomass. This study proposes an enhancement to this approach that integrates cultivation of an acidophilic strain, Galdieria sulphuraria 5587.1, in a closed photobioreactor (PBR); hydrothermal liquefaction (HTL) of the wet algal biomass; and recirculation of the nutrient-rich aqueous product (AP) of HTL to the PBR to achieve higher biomass productivity than that could be achieved with raw wastewater. The premise is that recycling nutrients in the AP can maintain optimal C, N and P levels in the PBR to maximize biomass growth to increase energy returns. Growth studies on the test species validated growth on AP derived from HTL at temperatures from 180 to 300°C. Doubling N and P concentrations over normal levels in wastewater resulted in biomass productivity gains of 20-25% while N and P removal rates also doubled.

  1. Controllable growth of dendrite-like CuO nanostructures by ethylene glycol assisted hydrothermal process

    SciTech Connect

    Zhang Hui; Li Shenzhong; Ma Xiangyang; Yang Deren

    2008-05-06

    The dendrite-like CuO nanostructures, consisting of a rod-like main stem and some rod-like sub-branches, have been synthesized by a simple ethylene glycol (EG) assisted hydrothermal method. The X-ray diffraction (XRD) and the selected area electron diffraction (SAED) patterns indicate that the dendrite-like CuO nanostructures are of monoclinic phase and the individual branch of CuO is single crystalline in nature. The effects of the growth conditions such as temperature and pH value on the morphology and structures of CuO have also been investigated. It is indicated that different temperature and pH value result in the morphology and structure evolution of CuO. Moreover, a possible mechanism for the morphology and structures evolution of CuO has been primarily presented.

  2. Hydrothermal carbonisation of sewage sludge: effect of process conditions on product characteristics and methane production.

    PubMed

    Danso-Boateng, E; Shama, G; Wheatley, A D; Martin, S J; Holdich, R G

    2015-02-01

    Hydrothermal carbonisation of primary sewage sludge was carried out using a batch reactor. The effect of temperature and reaction time on the characteristics of solid (hydrochar), liquid and gas products, and the conditions leading to optimal hydrochar characteristics were investigated. The amount of carbon retained in hydrochars decreased as temperature and time increased with carbon retentions of 64-77% at 140 and 160°C, and 50-62% at 180 and 200°C. Increasing temperature and treatment time increased the energy content of the hydrochar from 17 to 19 MJ/kg but reduced its energy yield from 88% to 68%. Maillard reaction products were identified in the liquid fractions following carbonisations at 180 and 200°C. Theoretical estimates of the methane yields resulting from the anaerobic digestion of the liquid by-products are also presented and optimal reaction conditions to maximise these identified.

  3. Crustal flushing and its relationship to magnetic and hydrothermal processes on the East Pacific Rise crest

    NASA Technical Reports Server (NTRS)

    Wright, Dawn J.; Haymon, Rachel M.; Fornari, Daniel J.

    1995-01-01

    The deep-towed Argo I optical/acoustical vehicle and a geographic information system (GIS) have been used to establish the abundance, widths, and spatial distribution of fissures, as well as the relative age distribution of lavas along the narrow (less than 500 m wide) axial zone of the East Pacific Rise (EPR) from 9 deg 12 min to 9 deg 54 min N. On a second-order scale (approximately 78 km long), wider but less numerous fissures are found in the northern portion of the survey area; this changes to narrower, more abundant fissures in the south. A profile of the cumulative width added by fissures to the axial zone exhibits minima in three areas along strike (near 9 deg 49 min, 9 deg 35 min, and 9 deg 15 min N), where the most recent eruptions have occurred above sites of magmatic injection from the upper mantle, filling and covering older fissures. On a fourth-order scale (5-15 km long) the mean density of fissuring on a given segment is greater where relative axial lava age is greater. Fissure density also correlates with hydrothermal vent abundance and type. Increased cracking toward segment tips is observed at the second-order scale, whereas fourth-order segments tend to be more cracked in the middle. Cracking on a fourth-order scale may be driven by the propagation of dikes, rather than by the far-field plate stresses. The above relations constrain the model of Haymon et al. (1991) in which individual fourth-order segments are in different phases of a volcanic-hydrothermal-tectonic cycle.

  4. The giant Carlin gold province: A protracted interplay of orogenic, basinal, and hydrothermal processes above a lithospheric boundary

    USGS Publications Warehouse

    Emsbo, P.; Groves, D.I.; Hofstra, A.H.; Bierlein, F.P.

    2006-01-01

    Northern Nevada hosts the only province that contains multiple world-class Carlin-type gold deposits. The first-order control on the uniqueness of this province is its anomalous far back-arc tectonic setting over the rifted North American paleocontinental margin that separates Precambrian from Phanerozoic subcontinental lithospheric mantle. Globally, most other significant gold provinces form in volcanic arcs and accreted terranes proximal to convergent margins. In northern Nevada, periodic reactivation of basement faults along this margin focused and amplified subsequent geological events. Early basement faults localized Devonian synsedimentary extension and normal faulting. These controlled the geometry of the Devonian sedimentary basin architecture and focused the discharge of basinal brines that deposited syngenetic gold along the basin margins. Inversion of these basins and faults during subsequent contraction produced the complex elongate structural culminations that characterize the anomalous mineral deposit "trends." Subsequently, these features localized repeated episodes of shallow magmatic and hydrothermal activity that also deposited some gold. During a pulse of Eocene extension, these faults focused advection of Carlin-type fluids, which had the opportunity to leach gold from gold-enriched sequences and deposit it in reactive miogeoclinal host rocks below the hydrologic seal at the Roberts Mountain thrust contact. Hence, the vast endowment of the Carlin province resulted from the conjunction of spatially superposed events localized by long-lived basement structures in a highly anomalous tectonic setting, rather than by the sole operation of special magmatic or fluid-related processes. An important indicator of the longevity of this basement control is the superposition of different gold deposit types (e.g., Sedex, porphyry, Carlin-type, epithermal, and hot spring deposits) that formed repeatedly between the Devonian and Miocene time along the trends

  5. General one-pot template-free hydrothermal method to metal oxide hollow spheres and their photocatalytic activities and lithium storage properties.

    PubMed

    Li, Di; Qin, Qing; Duan, Xiaochuan; Yang, Jiaqin; Guo, Wei; Zheng, Wenjun

    2013-09-25

    A general and facile one-pot template-free hydrothermal strategy has been developed to synthesize various metal oxide (TiO2, SnO2 and α-Fe2O3) hollow spheres with unified morphologies. The formation of hollow structure involves a trifluoroacetic acid (TFA)-assisted Ostwald ripening process. Photocatalytic activities of the as-prepared TiO2 product are evaluated by the photodegradation of Rhodamine B (RhB), which the TiO2 hollow spheres obtained from 450 °C thermal treatment exhibit higher photocatalytic activity than Degussa P25. In addition, electrochemical measurements demonstrate that all of the as-prepared metal oxides hollow spheres have the potential applications in lithium-ion battery. We have a great expectation that this synthesis strategy can afford a new universal route for functional metal oxide hollow materials preparation without using template.

  6. A study of starch gelatinisation behaviour in hydrothermally-processed plant food tissues and implications for in vitro digestibility.

    PubMed

    Edwards, Cathrina H; Warren, Frederick J; Campbell, Grant M; Gaisford, Simon; Royall, Paul G; Butterworth, Peter J; Ellis, Peter R

    2015-12-01

    The aim of this study was to investigate the role of the plant food matrix in influencing the extent of starch gelatinisation during hydrothermal processing, and its implications for starch digestibility. Differential scanning calorimetry (DSC) was used to provide a detailed examination of the gelatinisation behaviour of five distinct size fractions (diameters <0.21 to 2.58 mm) of milled chickpea and durum wheat. Gelatinisation parameters were obtained from the DSC thermograms and concomitant microscopy analyses were performed. The estimated terminal extent of gelatinisation (TEG) was compared with our previously published data for in vitro starch digestibility of the same food materials. We observed clear differences in the gelatinisation behaviour of matched size-fractions of chickpeas and durum wheat. In chickpea materials, the TEG values (34-100%) were inversely related to particle size, whereas in durum wheat, no size-dependent limitations on TEG were observed. The TEG values were completely consistent with the extent of starch amylolysis in all size fractions of both durum wheat and chickpea. Microstructural analysis following hydrothermal processing confirmed the presence of some partially gelatinised birefringent starch within intact chickpea cells. Birefringent starch granules were not present in any of the processed fractions of durum wheat. The differences in gelatinisation behaviour of these plant species seem to reflect the individual cell wall properties of these materials. These findings demonstrate the applicability of DSC to real food materials to provide insight into the mechanisms by which the food matrix (particularly the plant cell walls) influences gelatinisation, and consequently, starch amylolysis.

  7. Stratigraphic development and hydrothermal activity in the central western Cascade Range, Oregon

    SciTech Connect

    Cummings, M.L.; Bull, M.K. ); Pollock, J.M. ); Thompson, G.D. )

    1990-11-10

    Two volcanic sequences bounded by erosional unconformities compose the stratigraphy of the North Santiam mining district, Western Cascade Range, Oregon. Diorite, grandodiorite, and leucocratic quartz porphyry dikes, stocks, and sills intrude the breccias, flows, and tuffs of a volcanic center in the older Sardine Formation. Tourmaline-bearing breccia pipes are associated with the porphyritic granodiorite intrusions. An erosional unconformity separates the Sardine Formation from the overlying Elk Lake formation. The alteration patterns in the two formations are consistent with the development of hydrothermal systems during the eruption of each formation. However, the development of the two hydrothermal systems is separated by a period of erosion of the older volcanic pile. Early formation of mineralization that resembles porphyry copper deposits occurred within the Sardine Formation, and later, after eruption of the Elk Lake formation, epithermal veins and alteration developed along faults, fractures, and the margins of dikes in the Sardine Formation.

  8. Coupled RNA-SIP and metatranscriptomics of active chemolithoautotrophic communities at a deep-sea hydrothermal vent.

    PubMed

    Fortunato, Caroline S; Huber, Julie A

    2016-08-01

    The chemolithoautotrophic microbial community of the rocky subseafloor potentially provides a large amount of organic carbon to the deep ocean, yet our understanding of the activity and metabolic complexity of subseafloor organisms remains poorly described. A combination of metagenomic, metatranscriptomic, and RNA stable isotope probing (RNA-SIP) analyses were used to identify the metabolic potential, expression patterns, and active autotrophic bacteria and archaea and their pathways present in low-temperature hydrothermal fluids from Axial Seamount, an active submarine volcano. Metagenomic and metatranscriptomic results showed the presence of genes and transcripts for sulfur, hydrogen, and ammonium oxidation, oxygen respiration, denitrification, and methanogenesis, as well as multiple carbon fixation pathways. In RNA-SIP experiments across a range of temperatures under reducing conditions, the enriched (13)C fractions showed differences in taxonomic and functional diversity. At 30 °C and 55 °C, Epsilonproteobacteria were dominant, oxidizing hydrogen and primarily reducing nitrate. Methanogenic archaea were also present at 55 °C, and were the only autotrophs present at 80 °C. Correspondingly, the predominant CO2 fixation pathways changed from the reductive tricarboxylic acid (rTCA) cycle to the reductive acetyl-CoA pathway with increasing temperature. By coupling RNA-SIP with meta-omics, this study demonstrates the presence and activity of distinct chemolithoautotrophic communities across a thermal gradient of a deep-sea hydrothermal vent. PMID:26872039

  9. Coupled RNA-SIP and metatranscriptomics of active chemolithoautotrophic communities at a deep-sea hydrothermal vent

    PubMed Central

    Fortunato, Caroline S; Huber, Julie A

    2016-01-01

    The chemolithoautotrophic microbial community of the rocky subseafloor potentially provides a large amount of organic carbon to the deep ocean, yet our understanding of the activity and metabolic complexity of subseafloor organisms remains poorly described. A combination of metagenomic, metatranscriptomic, and RNA stable isotope probing (RNA-SIP) analyses were used to identify the metabolic potential, expression patterns, and active autotrophic bacteria and archaea and their pathways present in low-temperature hydrothermal fluids from Axial Seamount, an active submarine volcano. Metagenomic and metatranscriptomic results showed the presence of genes and transcripts for sulfur, hydrogen, and ammonium oxidation, oxygen respiration, denitrification, and methanogenesis, as well as multiple carbon fixation pathways. In RNA-SIP experiments across a range of temperatures under reducing conditions, the enriched 13C fractions showed differences in taxonomic and functional diversity. At 30 °C and 55 °C, Epsilonproteobacteria were dominant, oxidizing hydrogen and primarily reducing nitrate. Methanogenic archaea were also present at 55 °C, and were the only autotrophs present at 80 °C. Correspondingly, the predominant CO2 fixation pathways changed from the reductive tricarboxylic acid (rTCA) cycle to the reductive acetyl-CoA pathway with increasing temperature. By coupling RNA-SIP with meta-omics, this study demonstrates the presence and activity of distinct chemolithoautotrophic communities across a thermal gradient of a deep-sea hydrothermal vent. PMID:26872039

  10. Hydrothermal mineralization at seafloor spreading centers

    NASA Astrophysics Data System (ADS)

    Rona, Peter A.

    1984-01-01

    The recent recognition that metallic mineral deposits are concentrated by hydrothermal processes at seafloor spreading centers constitutes a scientific breakthrough that opens active sites at seafloor spreading centers as natural laboratories to investigate ore-forming processes of such economically useful deposits as massive sulfides in volcanogenic rocks on land, and that enhances the metallic mineral potential of oceanic crust covering two-thirds of the Earth both beneath ocean basins and exposed on land in ophiolite belts. This paper reviews our knowledge of processes of hydrothermal mineralization and the occurrence and distribution of hydrothermal mineral deposits at the global oceanic ridge-rift system. Sub-seafloor hydrothermal convection involving circulation of seawater through fractured rocks of oceanic crust driven by heat supplied by generation of new lithosphere is nearly ubiquitous at seafloor spreading centers. However, ore-forming hydrothermal systems are extremely localized where conditions of anomalously high thermal gradients and permeability increase hydrothermal activity from the ubiquitous low-intensity background level (⩽ 200°C) to high-intensity characterized by high temperatures ( > 200-c.400°C), and a rate and volume of flow sufficient to sustain chemical reactions that produce acid, reducing, metal-rich primary hydrothermal solutions. A series of mineral phases with sulfides and oxides as high- and low-temperature end members, respectively, are precipitated along the upwelling limb and in the discharge zone of single-phase systems as a function of increasing admixture of normal seawater. The occurrence of hydrothermal mineral deposits is considered in terms of spatial and temporal frames of reference. Spatial frames of reference comprise structural features along-axis (linear sections that are the loci of seafloor spreading alternating with transform faults) and perpendicular to axis (axial zone of volcanic extrusion and marginal

  11. Photocatalytic activity of BiFeO{sub 3} nanoparticles synthesized through hydrothermal method

    SciTech Connect

    Dhanalakshmi, Radhalayam; Muneeswaran, M.; Vanga, Pradeep Reddy; Ashok, M.; Giridharan, N. V.

    2015-06-24

    Multiferroic BiFeO{sub 3} (BFO) nanoparticles (Nps) were synthesized using hydrothermal method. From the X-Ray diffraction analysis (XRD), the synthesized Nps were found to having rhombohedral structure with R3c space group confirmed by Rietveld analysis. Fourier transform infrared spectroscopy (FTIR) analysis was carried out to identify the chemical bonds present in the BFO Nps. Photocatalytic properties of synthesized Nps were studied for the degradation of Methylene Blue (MB) dye under visible light of 150W.

  12. Field Trip Guide to Serpentinite, Silica-Carbonate Alteration, and Related Hydrothermal Activity in the Clear Lake Region, California

    SciTech Connect

    Fraser Goff; George Guthrie

    1999-06-01

    This guide is designed to familiarize scientists with the geology, structure, alteration, and fluids typical of California serpentinites for purposes of carbon dioxide sequestration (Lackner et al., 1995). Goff et al. (1997) and Goff and Lackner (1998) describe the geology and geochemistry of some of the serpentinites from this area. Mechanisms of silica-carbonate alteration were outlined by Barnes et al. (1973). Donnelly-Nolan et al. (1993) most recently reviewed relations between regional hydrothermal alteration and Quarternary volcanic activity. Stanley et al. (1998) summarized geophysical characteristics of the region.

  13. Hydrothermal processes for Tm 3+ -doped GdV O 4 nanocrystalline morphologies and their photoluminescence properties

    NASA Astrophysics Data System (ADS)

    Calderón-Villajos, R.; Zaldo, C.; Cascales, C.

    Controlled reaction conditions in simple, template-free hydrothermal processes yield pure tetragonal zircon-type I 41 / amd TmGdV O4 nanocrystals with well-defined specific morphologies and sizes. Nitrate reagents under mild conditions (180 ∘C, pH=7, autogenous pressure) produce from square, hexagon and lozenge nanocrystals with sides starting in 20 nm, to porous spindles, nanotubes, nanorods and nanobelts depending of the reaction times. They exhibit photoluminescence in ˜1.95 μm similar to bulk single crystals. For the lowest Tm3+ concentration (0.2 % mol) in GdV O4 measured 3H4 and 3F4 fluorescence lifetimes τ are very near to their radiative values, τrad.

  14. Prebiotic activation processes.

    NASA Technical Reports Server (NTRS)

    Lohrmann, R.; Orgel, L. E.

    1973-01-01

    Questions regarding the combination of amino acids and ribonucleotides to polypeptides and polynucleotides are investigated. Each of the reactions considered occurs in the solid state in plausible prebiotic conditions. Together they provide the basis for a unified scheme of amino acid and nucleotide activation. Urea, imidazole and Mg(++) are essential catalytic components of the reaction mixtures. However, these compounds could probably be replaced by other organic molecules.

  15. Carbon Isotopes of Alkanes in Hydrothermal Abiotic Organic Synthesis Processes at High Temperatures and Pressures: An Experimental Study

    NASA Technical Reports Server (NTRS)

    Fu, Qi; Socki, Richard A.; Niles, Paul B.

    2010-01-01

    Observation of methane in the Martian atmosphere has been reported by different detection techniques [1-4]. With more evidence showing extensive water-rock interaction in Martian history [5-7], abiotic formation by Fischer-Tropsch Type (FTT) synthesis during serpentization reactions may be one possible process responsible for methane generation on Mars [8, 9]. While the experimental studies performed to date leave little doubt that chemical reactions exist for the abiotic synthesis of organic compounds by mineral surface-catalyzed reactions [10-12], little is known about the reaction pathways by which CO2 and/or CO are reduced under hydrothermal conditions. Carbon and hydrogen isotope measurements of alkanes have been used as an effective tool to constrain the origin and reaction pathways of hydrocarbon formation. Alkanes generated by thermal breakdown of high molecular weight organic compounds have carbon and hydrogen isotopic signatures completely distinct from those formed abiotically [13-15]. Recent experimental studies, however, showed that different abiogenic hydrocarbon formation processes (e.g., polymerization vs. depolymerization) may have different carbon and hydrogen isotopic patterns [16]. Results from previous experiments studying decomposition of higher molecular weight organic compounds (lignite) also suggested that pressure could be a crucial factor affecting fractionation of carbon isotopes [17]. Under high pressure conditions, no experimental data are available describing fractionation of carbon isotope during mineral catalyzed FTT synthesis. Thus, hydrothermal experiments present an excellent opportunity to provide the requisite carbon isotope data. Such data can also be used to identify reaction pathways of abiotic organic synthesis under experimental conditions.

  16. Effect of calcination temperature on the photocatalytic reduction and oxidation processes of hydrothermally synthesized titania nanotubes.

    SciTech Connect

    Viayan, B.; Dimitrijevic, N. M.; Rajh, T.; Gray, K.; Northwestern Univ.

    2010-08-05

    Titania nanotubes having diameters 8 to 12 nm and lengths of 50-300 nm were prepared using a hydrothermal method. Further, the titania nanotubes were calcined over the temperature range 200-800 C in order to enhance their photocatalytic properties by altering their morphology. The calcined titania nanotubes were characterized by using X-ray diffraction and surface area analysis and their morphological features were studied by scanning and transmission electron microscopy. Nanotubes calcined at 400 C showed the maximum extent of photocatalyitc reduction of carbon dioxide to methane, whereas samples calcined at 600 C produced maximum photocatalytic oxidation of acetaldehyde. Electron paramagnetic resonance (EPR) spectroscopy was used to interrogate the effects of nanotube structure on the charge separation and trapping as a function of calcination temperature. EPR results indicated that undercoordinated titania sites are associated with maximum CO{sub 2} reduction occurring in nanotubes calcined at 400 C. Despite the collapse of the nantube structure to form nanorods and the concomitant loss of surface area, the enhanced charge separation associated with increased crystallinity promoted high rates of oxidation of acetaldehyde in titania materials calcined at 600 C. These results illustrate that calcination temperature allows us to tune the morphological and surface features of the titania nanostructures for particular photocatalytic reactions.

  17. Hydrothermal processes at Gusev Crater: An evaluation of Paso Robles class soils

    USGS Publications Warehouse

    Yen, A. S.; Morris, R.V.; Clark, B. C.; Gellert, Ralf; Knudson, A.T.; Squyres, S.; Mittlefehldt, D. W.; Ming, D. W.; Arvidson, R.; McCoy, T.; Schmidt, M.; Hurowitz, J.; Li, R.; Johnson, J. R.

    2008-01-01

    The Mars Exploration Rover Spirit analyzed multiple occurrences of sulfur-rich, light-toned soils along its traverse within Gusev Crater. These hydrated deposits are not readily apparent in images of undisturbed soil but are present at shallow depths and were exposed by the actions of the rover wheels. Referred to as 'Paso Robles' class soils, they are dominated by ferric iron sulfates, silica, and Mg-sulfates. Ca-sulfates, Ca-phosphates, and other minor phases are also indicated in certain specific samples. The chemical compositions are highly variable over both centimeter-scale distances and between the widely separated exposures, but they clearly reflect the elemental signatures of nearby rocks. The quantity of typical basaltic soil mixed into the light-toned materials prior to excavation by the rover wheels is minimal, suggesting negligible reworking of the deposits after their initial formation. The mineralogy, geochemistry, variability, association with local compositions, and geologic setting of the deposits suggest that Paso Robles class soils likely formed as hydrothermal and famarolic condensates derived from magma degassing and/ or oxidative alteration of crustal iron sulfide deposits. Their occurrence as unconsolidated, near-surface soils permits, though does not require, an age that is significantly younger than that of the surrounding rocks. Copyright 2008 by the American Geophysical Union.

  18. Utilization of recovered nitrogen from hydrothermal carbonization process by Arthrospira platensis.

    PubMed

    Yao, Changhong; Pan, Yanfei; Lu, Hongbin; Wu, Peichun; Meng, Yingying; Cao, Xupeng; Xue, Song

    2016-07-01

    In the context of sustainable cultivation of microalgae, the present study focused on the use of nitrogen from the hot-water extracted biomass residue of Arthrospira platensis by hydrothermal carbonization (HTC) and the sequential cultivation of the same alga with the HTC aqueous phase (AP). Nearly 90% of the nitrogen recovered from HTC into AP was in the organic form. Under nitrogen-limited condition with HTCAP as nitrogen source the yield and content of carbohydrate were enhanced by 21% and 15% respectively compared with that under the same nitrogen level provided by NaNO3, which entitled HTCAP for the substitution of conventional nitrate. In the same way pilot-scale cultivation of A. platensis in raceway ponds outdoors demonstrated that carbohydrate content of 43.8% DW and productivity of 10.3g/m(2)/d was achieved. Notably 54% of organic nitrogen in the HTCAP could be recycled by cultivation of pre-nitrogen starved A. platensis as seeds under nitrogen limitation. PMID:27070286

  19. Optical properties of Mn-doped ZnS semiconductor nanoclusters synthesized by a hydrothermal process

    NASA Astrophysics Data System (ADS)

    Hoa, Tran Thi Quynh; The, Ngo Duc; McVitie, Stephen; Nam, Nguyen Hoang; Vu, Le Van; Canh, Ta Dinh; Long, Nguyen Ngoc

    2011-01-01

    Undoped and Mn-doped ZnS nanoclusters have been synthesized by a hydrothermal approach. Various samples of the ZnS:Mn with 0.5, 1, 3, 10 and 20 at.% Mn dopant have been prepared and characterized using X-ray diffraction, energy-dispersive analysis of X-ray, high resolution electron microscopy, UV-vis diffusion reflection, photoluminescence (PL) and photoluminescence excitation (PLE) measurements. All the prepared ZnS nanoclusters possess cubic sphalerite crystal structure with lattice constant a = 5.408 ± 0.011 Ǻ. The PL spectra of Mn-doped ZnS nanoclusters at room temperature exhibit both the 495 nm blue defect-related emission and the 587 nm orange Mn2+ emission. Furthermore, the blue emission is dominant at low temperatures; meanwhile the orange emission is dominant at room temperature. The Mn2+ ion-related PL can be excited both at energies near the band-edge of ZnS host (the UV region) and at energies corresponding to the Mn2+ ion own excited states (the visible region). An energy schema for the Mn-doped ZnS nanoclusters is proposed to interpret the photoluminescence behaviour.

  20. Large-scale synthesis of nickel sulfide micro/nanorods via a hydrothermal process

    NASA Astrophysics Data System (ADS)

    Yin, Peng-fei; Han, Xiang-yu; Zhou, Chao; Xia, Chuan-hui; Hu, Chun-lian; Sun, Li-li

    2015-07-01

    Rhombohedral-phase NiS micro/nanorods were synthesized on a large scale through a hydrothermal method using NiCl2·6H2O and thiourea crystals as starting precursors. Recrystallized thiourea was observed to play an important role in the formation of micro/nanosized rods and flower-like structures. The molar ratio and reaction temperature of the precursors influenced the morphology and phase of NiS products. Pure rhombohedral NiS micro/nanorods were obtained on a large scale when the molar ratio between NiCl2·6H2O and thiourea crystals was fixed at 2:1, and the mixture was heated at 250°C for 5 h. Flower-like NiS nanostructures were formed when the molar ratio between NiCl2·6H2O and thiourea crystals was maintained at 1:1. The Raman and Fourier-transform infrared (FTIR) spectra of the as-prepared rhombohedral NiS micro/nanorods were collected, and their magnetic properties were investigated. The results showed that the FTIR absorption peaks of the as-prepared product are located at 634 cm-1 and their Raman peaks are located at 216 and 289 cm-1; the as-prepared NiS micro/nanorods exhibited weak ferromagnetic behavior due to the size effect.

  1. The 1997 phreatic eruption of Akita-Yakeyama volcano, northeast Japan: Insight into the hydrothermal processes

    NASA Astrophysics Data System (ADS)

    Nogami, K.; Hirabayashi, J.; Ohba, T.; Yoshiike, Y.

    2000-04-01

    A small-scale steam explosion occurred on Karanuma crater on the summit of Akita-Yakeyama volcano on August 16, 1997 after a dormancy of 46 years. Chemical compositions of the fumarolic gases at the summit and hot spring waters around the volcano were monitored before the eruption.Obvious changes in the composition and outlet temperatures of the fumarolic gases were not detected, neither before nor after the 1997 eruption. Hydrogen and oxygen isotopic ratios of the gas condensates and hot-spring waters at the Yunuma crater indicated that a hydrothermal reservoir, where the fumarolic gases separated from the hot-spring waters at 150circC, existed in a shallow place beneath the crater.Smectite, kaolinite and pyrophyllite were identified in the clay fraction of the volcanic ejecta. Although pyrophyllite should have been formed at about 1~km beneath the summit, it was not directly derived from the deep zone during the 1997 eruption but had been ejected by previous eruptions. The Cl/S values of the water leachates of the ejecta were about 0.7, which indicated that the volcanic gas which caused the eruption was rich in HCl. However, the fumarolic gases and the water samples collected from the summit area contained little chloride. The source of the water-soluble chloride might be high-temperature magmatic gases that have been estimated as the source of Cl-SO4 type thermal water. Such magmatic gases might have caused the 1997 eruption.

  2. Towards the kinetics of diagenetic overprint processes deduced from laboratory-based hydrothermal alteration of modern Arctica islandica shell material

    NASA Astrophysics Data System (ADS)

    Casella, Laura A.; Griesshaber, Erika; Mavromatis, Vasileios; Dietzel, Martin; Immenhauser, Adrian; Schmahl, Wolfgang W.

    2016-04-01

    Benthic and nektonic marine biogenic carbonate archives represent the foundation of numerous studies aiming at paleo-environment reconstructions. However, living organisms are not in thermodynamic equilibrium as they form local chemical environments for physiologic processes such as biological mineralization of their hard tissues. This disequilibrium is not sustained after death and all biological tissues are altered by equilibration with the surrounding environment: diagenesis. To understand transformation during diagenesis we performed laboratory-based hydrothermal alteration experiments on Arctica islandica shells at four different temperatures between 100 °C and 175 °C treated in simulated meteoric and burial waters, respectively. We investigated, relative to unaltered shells, the kinetics of Arctica islandica bioaragonite to calcite transition as well as microstructural- and nanostructural characteristics of the altered shells with X-ray diffraction, micro-Raman, high-resolution SEM and EBSD. At hydrothermal treatment at 100 °C bioaragonite - although metastable at 1 bar - does not transform to calcite, even in meteoric fluids and over a time period of 28 days. We noted a drastic recrystallization from the initial fine-grained fractal microstructure and pronounced axial texture to a new and still fine-grained microstructure with an almost randomized orientation distribution. At 175 °C the transformation to coarse-grained calcite is complete after 8 days. Calcite formation starts after a passive incubation period of 4 days; after 6 days the aragonite is almost completely transformed. In solutions simulating meteoric water the grain size of the newly formed calcite reaches 100-150 μm, while in burial fluids the calcite reaches sizes in the 1mm range during 28 days of alteration. Phase transformation proceeds where the hydrothermal fluid is in contact with the aragonite: at shell surfaces, around pores and in growth lines. Our observations lead us to the

  3. Process Design and Economics for the Conversion of Algal Biomass to Hydrocarbons: Whole Algae Hydrothermal Liquefaction and Upgrading

    SciTech Connect

    Jones, Susanne B.; Zhu, Yunhua; Anderson, Daniel B.; Hallen, Richard T.; Elliott, Douglas C.; Schmidt, Andrew J.; Albrecht, Karl O.; Hart, Todd R.; Butcher, Mark G.; Drennan, Corinne; Snowden-Swan, Lesley J.; Davis, Ryan; Kinchin, Christopher

    2014-03-20

    This report provides a preliminary analysis of the costs associated with converting whole wet algal biomass into primarily diesel fuel. Hydrothermal liquefaction converts the whole algae into an oil that is then hydrotreated and distilled. The secondary aqueous product containing significant organic material is converted to a medium btu gas via catalytic hydrothermal gasification.

  4. Contrasting hydrological processes of meteoric water incursion during magmatic-hydrothermal ore deposition: An oxygen isotope study by ion microprobe

    NASA Astrophysics Data System (ADS)

    Fekete, Szandra; Weis, Philipp; Driesner, Thomas; Bouvier, Anne-Sophie; Baumgartner, Lukas; Heinrich, Christoph A.

    2016-10-01

    Meteoric water convection has long been recognized as an efficient means to cool magmatic intrusions in the Earth's upper crust. This interplay between magmatic and hydrothermal activity thus exerts a primary control on the structure and evolution of volcanic, geothermal and ore-forming systems. Incursion of meteoric water into magmatic-hydrothermal systems has been linked to tin ore deposition in granitic plutons. In contrast, evidence from porphyry copper ore deposits suggests that crystallizing subvolcanic magma bodies are only affected by meteoric water incursion in peripheral zones and during late post-ore stages. We apply high-resolution secondary ion mass spectrometry (SIMS) to analyze oxygen isotope ratios of individual growth zones in vein quartz crystals, imaged by cathodo-luminescence microscopy (SEM-CL). Existing microthermometric information from fluid inclusions enables calculation of the oxygen isotope composition of the fluid from which the quartz precipitated, constraining the relative timing of meteoric water input into these two different settings. Our results confirm that incursion of meteoric water directly contributes to cooling of shallow granitic plutons and plays a key role in concurrent tin mineralization. By contrast, data from two porphyry copper deposits suggest that downward circulating meteoric water is counteracted by up-flowing hot magmatic fluids. Our data show that porphyry copper ore deposition occurs close to a magmatic-meteoric water interface, rather than in a purely magmatic fluid plume, confirming recent hydrological modeling. On a larger scale, the expulsion of magmatic fluids against the meteoric water interface can shield plutons from rapid convective cooling, which may aid the build-up of large magma chambers required for porphyry copper ore formation.

  5. Fluids in early stage hydrothermal alteration of high-sulfidation epithermal systems: A view from the Vulcano active hydrothermal system (Aeolian Island, Italy)

    NASA Astrophysics Data System (ADS)

    Boyce, Adrian J.; Fulignati, Paolo; Sbrana, Alessandro; Fallick, Anthony E.

    2007-10-01

    High-sulfidation (HS) epithermal systems have elements in common with passively degassing volcanoes associated with high T, acid fumarole fields or acid crater lakes. They are considered to form in two stages, the first of which involves advanced argillic alteration resulting from intense, strongly acidic fluid-rock interaction. The La Fossa hydrothermal system (Vulcano Island) represents a classic example of such an active HS system and can be considered as a modern analogue of this early stage of alteration, resulting in a core of intense silicic (90-95% pure SiO 2) alteration surrounded by alunitic alteration zones. This paper focuses on a geochemical and stable isotope study of the surficial alteration facies of Vulcano - particularly the horizon characterized by strong silicic alteration - and on deep seated xenoliths ejected during the last eruption of La Fossa volcano (1888-90) that can be considered as representative of fragments of the deep conduit system of La Fossa volcano. Using directly measured temperatures at the sites of sampling, we have calculated fluid composition in isotopic equilibrium with the alteration products. The large range of measured silica δ18O (12.3 to 29‰) reflects the wide range of formation temperatures (80-240 °C). The fluid compositions calculated for intense silicic alteration vary from - 0.9 to + 6.5‰. These are significantly heavier than local meteoric water (- 6‰), and are consistent with derivation from the condensation of high-temperature fumarolic gases, dominated by magmatic fluids and rich in acid gases (SO 2, H 2S, HCl, HF), into shallow groundwaters of meteoric origin, with dynamically variable ratios of fumarolic steam/meteoric water. The calculated δ18O and δD of water in equilibrium with alunite also suggest the mixing of magmatic and meteoric waters for the fluids involved in the genesis of advanced argillic alteration facies. The calculated δ18O of water in equilibrium with hedenbergitic clinopyroxene

  6. Submarine hydrothermal activity along the mid-Kermadec Arc, New Zealand: Large-scale effects on venting

    NASA Astrophysics Data System (ADS)

    de Ronde, C. E. J.; Baker, E. T.; Massoth, G. J.; Lupton, J. E.; Wright, I. C.; Sparks, R. J.; Bannister, S. C.; Reyners, M. E.; Walker, S. L.; Greene, R. R.; Ishibashi, J.; Faure, K.; Resing, J. A.; Lebon, G. T.

    2007-07-01

    The 2,500-km Kermadec-Tonga arc is the longest submarine arc on the planet. Here, we report on the second of a series of cruises designed to investigate large-scale controls on active hydrothermal venting on this arc. The 2002 NZAPLUME II cruise surveyed 12 submarine volcanic centers along ~580 km of the middle Kermadec arc (MKA), extending a 1999 cruise that surveyed 260 km of the southern Kermadec arc (SKA). Average spacing between volcanic centers increases northward from 30 km on backarc crust along the SKA, to 45 km on backarc crust along the southern MKA, to 58 km where the MKA joins the Kermadec Ridge. Volcanic cones dominate in the backarc, and calderas dominate the Kermadec Ridge. The incidence of venting is higher along the MKA (83%, 10 of 12 volcanic centers) than the SKA (67%, 8 of 12), but the relative intensity of venting, as given by plume thickness, areal extent, and concentration of dissolved gases and ionic species, is generally weaker in the MKA. This pattern may reflect subduction of the ~17-km-thick oceanic Hikurangi Plateau beneath the SKA. Subduction of this basaltic mass should greatly increase fluid loss from the downgoing slab, initiating extensive melting in the upper mantle wedge and invigorating the hydrothermal systems of the SKA. Conversely, volcanic centers in the southern MKA are starved of magma replenishment and so their hydrothermal systems are waning. Farther north, where the MKA centers merge with the Kermadec Ridge, fewer but larger magma bodies accumulate in the thicker (older) crust, ensuring more widely separated, caldera-dominated volcanic centers.

  7. A reduced crustal magnetization zone near the first observed active hydrothermal vent field on the Southwest Indian Ridge

    NASA Astrophysics Data System (ADS)

    Zhu, Jian; Lin, Jian; Chen, Yongshun J.; Tao, Chunhui; German, Christopher R.; Yoerger, Dana R.; Tivey, Maurice A.

    2010-09-01

    Inversion of near-bottom magnetic data reveals a well-defined low crustal magnetization zone (LMZ) near a local topographic high (37°47‧S, 49°39‧E) on the ultraslow-spreading Southwest Indian Ridge (SWIR). The magnetic data were collected by the autonomous underwater vehicle ABE on board R/V DaYangYiHao in February-March 2007. The first active hydrothermal vent field observed on the SWIR is located in Area A within and adjacent to the LMZ at the local topographic high, implying that this LMZ may be the result of hydrothermal alteration of magnetic minerals. The maximum reduction in crustal magnetization is 3 A/M. The spatial extent of the LMZ is estimated to be at least 6.7 × 104 m2, which is larger than that of the LMZs at the TAG vent field on the Mid-Atlantic Ridge (MAR), as well as the Relict Field, Bastille, Dante-Grotto, and New Field vent-sites on the Juan de Fuca Ridge (JdF). The calculated magnetic moment, i.e., the product of the spatial extent and amplitude of crustal magnetization reduction is at least -3 × 107 Am2 for the LMZ on the SWIR, while that for the TAG field on the MAR is -8 × 107 Am2 and that for the four individual vent fields on the JdF range from -5 × 107 to -3 × 107 Am2. Together these results indicate that crustal demagnetization is a common feature of basalt-hosted hydrothermal vent fields at mid-ocean ridges of all spreading rates. Furthermore, the crustal demagnetization of the Area A on the ultraslow-spreading SWIR is comparable in strength to that of the TAG area on the slow-spreading MAR.

  8. Massive sulfide deposits and hydrothermal solutions: incremental reaction modeling of mineral precipitation and sulfur isotopic evolution

    SciTech Connect

    Janecky, D.R.

    1986-01-01

    Incremental reaction path modeling of chemical and sulfur isotopic reactions occurring in active hydrothermal vents on the seafloor, in combination with chemical and petrographic data from sulfide samples from the seafloor and massive sulfide ore deposits, allows a detailed examination of the processes involved. This paper presents theoretical models of reactions of two types: (1) adiabatic mixing between hydrothermal solution and seawater, and (2) reaction of hydrothermal solution with sulfide deposit materials. In addition, reaction of hydrothermal solution with sulfide deposit minerals and basalt in feeder zones is discussed.

  9. Fluids in the lithosphere: The dimensions of rheological and hydrothermal processes

    SciTech Connect

    Kerrich, R.K. . Dept. of Geological Sciences)

    1992-01-01

    The lithosphere contains approximately the same mass of water, in the form of pore fluids and hydrates, as the hydrosphere and there is a continuous exchange of volatiles between these reservoirs at a rate of Ca 10[sup 16]/ga. Fluids influence the rheological behavior of the lithosphere over 16 orders of magnitude, from the scale of intracrystalline bonding to the dimensions of entire plates. Pore fluid pressure is one of the major controls on the depth of the seismic-aseismic transition, and at least one major class of ore deposit, namely mesothermal gold, forms dominantly at this rheological transition as a result of fluid pressure fluctuations. A single metallogenic province of this type involves advection of ca 10[sup 18] g of hydrothermal fluid through the seismic-aseismic transition. Sibson and coworkers model of seismic pumping is well established. A major unresolved question, however, is whether surface waters that infiltrate to depth under hydrostatic pressure, become valved off, raised to lithostatic pressure, and discharge, in a cyclic pattern; or alternatively, whether deep crustal fluid reservoirs at lithostatic pressure intermittently breach the seismic-aseismic transition. Another fundamental problem is the depth to which surface fluids penetrate the crust. In the Canadian Shield, tectonic pumping of fluids to depths of 12 km has occurred episodically at 2.6, 2.2, 1.8, 1.1 and 0.5 Ga, involving ca 10[sup 4] km[sup 3] H[sub 2]O per event, during tectonic and/or thermal events, principally along reactivated Archean structures. It is becoming increasingly clear that fluids not only govern rheological behavior, but may also reset radiogenic isotope systems well below the conventional blocking temperature, by solution-reprecipitation, resulting in reversed apparent blocking ages where T(K-Ar) > T(Rb-Sr)>T(Sm-Nd).

  10. Timing and duration of hydrothermal activity at the Los Bronces porphyry cluster: an update

    NASA Astrophysics Data System (ADS)

    Deckart, K.; Silva, W.; Spröhnle, C.; Vela, I.

    2014-06-01

    New geochronological data from the Los Bronces cluster of the Río Blanco-Los Bronces mega-porphyry Cu-Mo district establish a wide range of magmatism, hydrothermal alteration, and mineralization ages, both in terms of areal extent and time. The northern El Plomo and southernmost Los Piches exploration areas contain the oldest barren porphyritic intrusions with U-Pb ages of 10.8 ± 0.1 Ma and 13.4 ± 0.1 Ma, respectively. A hypabyssal barren intrusion adjacent northwesterly to the main pit area yields a slightly younger age of 10.2 ± 0.3 Ma (San Manuel sector, U-Pb), whereas in the Los Bronces (LB) open-pit area, the present day mineral extraction zone, porphyries range from 8.49 to 6.02 Ma (U-Pb). Hydrothermal biotite and sericite ages are up to 0.5 Ma younger but consistent with the cooling of the corresponding intrusion events of each area. Two quartz-molybdenite B-type veins from the LB open pit have Re-Os molybdenite ages of 5.65 ± 0.03 Ma and 5.35 ± 0.03 Ma consistent with published data for the contiguous Río Blanco cluster. The San Manuel exploration area within the Los Bronces cluster, located about 1.5-2 km southeast of the open-pit extraction zone, shows both the oldest hydrothermal biotite (7.70 ± 0.07 Ma; 40Ar/39Ar) and breccia cement molybdenite ages (8.36 ± 0.06 Ma; Re-Os) registered in the entire Río Blanco-Los Bronces district. These are also older than those reported from the El Teniente porphyry Cu(-Mo) deposit, suggesting that mineralization in the late Miocene to early Pliocene porphyry belt of Central Chile commenced 2 Ma before the previously accepted age of 6.3 Ma.

  11. Stable isotope geochemistry of clay minerals from fossil and active hydrothermal systems, southwestern Hokkaido, Japan

    SciTech Connect

    Marumo, Katsumi; Longstaffe, F.J.; Matsubaya, Osamu

    1995-06-01

    Miocene submarine to Quaternary terrestrial volcanism in southwestern Hokkaido, Japan, is associated with hydrothermal clay alteration and mineralization, including Kuroko-type deposits at Kagenosawa (14.2 Ma, Cu > Zn, Pb > Au) and Minamishiraoi (12.5 Ma, Ba > Zn, Pb, Cu), vein-style at Noboribetsu ({le} 1.8 Ma). The {delta}D and {delta}{sup 18}O values of mica (sericite), mica-smectite, chlorite, chlorite-smectite, nacrite, dickite, kaolinite, and smectite were used to deduce the type(s) of hydrothermal fluid at each locality. Calculated compositions for Minamishiraoi and Kagenosawa fluids suggest that seawater was dominant, but some mixing with magmatic water is also indicated, particularly for the polymetallic Kagenosawa deposit. Hydrothermal fluids at Date, Chitose, and the Noboribetsu geothermal area were dominated by meteoric water. The {delta}D and {delta}{sup 18}O values of modern hot-spring waters at Noboribetsu closely parallel fluid compositions calculated for the clay alteration at Date, Chitose, and Noboribetsu. In vacuo TG patterns of other smectitic clays suggested gradual loss of hydroxyl-groups beginning near 200{degrees}C, rather than the more typical distinct separation between interlayer water at <200{degrees}C and hydroxyl-groups at >400{degrees}C. This behaviour constrains the maximum temperature that can be used for in vacuo preheating. Furthermore, shifts to lower {delta}D values (by as much as 19{per_thousand}) were obtained when this smectite was dispersed in low-D water for three weeks, perhaps indicating isotopic exchange. However, with appropriate care, {delta}D values obtained by conventional procedures (including preheating to {le}200{degrees}C) normally reproduced natural compositions of the smectitic clays with acceptable accuracy and precision.

  12. Enhanced Visible-Light Photocatalytic Activity of C/Ce-Codoped ZnO Nanoellipsoids Synthesized by Hydrothermal Method

    NASA Astrophysics Data System (ADS)

    Ha, Luu Thi Viet; Dai, Luu Minh; Nhiem, Dao Ngoc; Van Cuong, Nguyen

    2016-08-01

    C/Ce-codoped ZnO nanomaterial has been synthesized by a hydrothermal method and its physical properties and characterization investigated using thermogravimetric and differential thermal analysis (TG-DTA), x-ray diffraction (XRD) analysis, Fourier-transform infrared (FTIR) spectroscopy, energy-dispersive x-ray (EDX) spectroscopy, UV-Vis diffuse reflectance spectroscopy, and scanning electron microscopy (SEM). The photocatalytic activity of the nanomaterial was examined using methylene blue as organic dye under visible-light source. The results show that the C/Ce-codoped ZnO nanomaterial exhibited higher photocatalytic activity under visible-light irradiation compared with undoped ZnO, Ce-doped ZnO or C-doped ZnO nanomaterials. Such enhancement of the photocatalytic activity of C/Ce-codoped ZnO under visible-light irradiation suggests that these nanoparticles might have good applications in optoelectronics and wastewater treatment.

  13. Calibrated Hydrothermal Parameters, Barrow, Alaska, 2013

    DOE Data Explorer

    Atchley, Adam; Painter, Scott; Harp, Dylan; Coon, Ethan; Wilson, Cathy; Liljedahl, Anna; Romanovsky, Vladimir

    2015-01-29

    A model-observation-experiment process (ModEx) is used to generate three 1D models of characteristic micro-topographical land-formations, which are capable of simulating present active thaw layer (ALT) from current climate conditions. Each column was used in a coupled calibration to identify moss, peat and mineral soil hydrothermal properties to be used in up-scaled simulations. Observational soil temperature data from a tundra site located near Barrow, AK (Area C) is used to calibrate thermal properties of moss, peat, and sandy loam soil to be used in the multiphysics Advanced Terrestrial Simulator (ATS) models. Simulation results are a list of calibrated hydrothermal parameters for moss, peat, and mineral soil hydrothermal parameters.

  14. Geochemistry of hydrothermal plume in the Suiyo Seamount Caldera.

    NASA Astrophysics Data System (ADS)

    Shitashima, K.; Maeda, Y.

    2002-12-01

    Chemical compounds of the hot basalt origin are discharged into the deep ocean via hydrothermal plume by the deep-sea hydrothermal activity. The hydrothermal plume is widely diffused to the ocean by mixing with ambient seawater. Chemical reactions and interactions with microorganisms in the diffusion process of the hydrothermal plume are important to comprehend the oceanic geochemical cycles. Recently, it has been clarified that the variation of hydrothermal activity is greatly controlled in the tidal current. Not only geochemical observation but also physical observation, such as water current measurement, are necessary for the understanding of the deep-sea hydrothermal systems including the behavior of hydrothermal plume. In order to observe the diffusion process of hydrothermal plumes, sampling and chemical mapping of the hydrothermal plume and measurement of water current were carried out at the Suiyo Seamount Caldera during research cruises under the ?Archaean Park? project funded by MEXT. The three-dimensional acoustic current meters were moored at the height of 13m and 125m above the bottom in the Suiyo Seamount Caldera. At the 13m height, average water current speed and current direction were 10.46 cm/second and 228.1 degrees, respectively, and maximum water current speed was over 40.46 cm/second. On the other hand, average water current speed and current direction at the 125m height were 3.87 cm/second and 57.8 degrees, respectively. The strong water current of the southwest direction in 24 hours periods existed near bottom of the caldera. In addition, downward current and water temperature depreciation were observed, when there was the strong current in 24 hours periods. These results suggest that the low-temperature ocean water around the Suiyo Seamount flows toward the bottom of caldera periodically. The mini CTDT-RMS mounted twelve 1.2L Niskin bottles and the in-situ pH sensor were installed on the ROV or manned submersible. The hydrothermal plume

  15. Hydrothermal activity on the southern Mid-Atlantic Ridge: Tectonically- and volcanically-controlled venting at 4 5°S

    NASA Astrophysics Data System (ADS)

    German, C. R.; Bennett, S. A.; Connelly, D. P.; Evans, A. J.; Murton, B. J.; Parson, L. M.; Prien, R. D.; Ramirez-Llodra, E.; Jakuba, M.; Shank, T. M.; Yoerger, D. R.; Baker, E. T.; Walker, S. L.; Nakamura, K.

    2008-09-01

    We report results from an investigation of the geologic processes controlling hydrothermal activity along the previously-unstudied southern Mid-Atlantic Ridge (3-7°S). Our study employed the NOC (UK) deep-tow sidescan sonar instrument, TOBI, in concert with the WHOI (USA) autonomous underwater vehicle, ABE, to collect information concerning hydrothermal plume distributions in the water column co-registered with geologic investigations of the underlying seafloor. Two areas of high-temperature hydrothermal venting were identified. The first was situated in a non-transform discontinuity (NTD) between two adjacent second-order ridge-segments near 4°02'S, distant from any neovolcanic activity. This geologic setting is very similar to that of the ultramafic-hosted and tectonically-controlled Rainbow vent-site on the northern Mid-Atlantic Ridge. The second site was located at 4°48'S at the axial-summit centre of a second-order ridge-segment. There, high-temperature venting is hosted in an ˜ 18 km 2 area of young lava flows which in some cases are observed to have flowed over and engulfed pre-existing chemosynthetic vent-fauna. In both appearance and extent, these lava flows are directly reminiscent of those emplaced in Winter 2005-06 at the East Pacific Rise, 9°50'N and reference to global seismic catalogues reveals that a swarm of large (M 4.6-5.6) seismic events was centred on the 5°S segment over a ˜ 24 h period in late June 2002, perhaps indicating the precise timing of this volcanic eruptive episode. Temperature measurements at one of the vents found directly adjacent to the fresh lava flows at 5°S MAR (Turtle Pits) have subsequently revealed vent-fluids that are actively phase separating under conditions very close to the Critical Point for seawater, at ˜ 3000 m depth and 407 °C: the hottest vent-fluids yet reported from anywhere along the global ridge crest.

  16. Conversion of tomato-peel waste into solid fuel by hydrothermal carbonization: Influence of the processing variables.

    PubMed

    Sabio, E; Álvarez-Murillo, A; Román, S; Ledesma, B

    2016-01-01

    In this work, the influence of the variables temperature, residence time, and biomass/water ratio on the hydrothermal carbonization (HTC) of tomato peel was investigated. The implementation of a Design of Experiments - Response Surface Methodology approach allowed to identify the importance of each variable, as well as their interactions, in both the reactivity (solid yield) and energy densification (increase in higher heating value). The HTC residence time and specially temperature had a major effect on the process, increasing the solid yield and promoting energy densification. Ratio had a minor effect although under certain temperature and time conditions, it was a decisive parameter. Solid yields in the range 27.6% and 87.7% with corresponding high heating values 23.6-34.6 MJ kg(-1) were obtained. From the statistical processing of the experimental data obtained pseudo-second order models were developed. It was proven that these approaches envisaged the hydrochar final characteristics successfully. From the elemental analysis and the FTIR spectra, it was possible to investigate the HTC pathway, which was defined as a combination of several processes; considering dehydration and decarboxylation reactions and especially lignin depolimerization reactions, which lead to the formation of monomeric radicals. Moreover, the surface morphology of selected hydrochars by Scanning Electron Microscopy (SEM) showed the original structure scaffold, with minor changes between hydrochars prepared under different conditions.

  17. Muon dynamic radiography of density changes induced by hydrothermal activity at the La Soufrière of Guadeloupe volcano

    PubMed Central

    Jourde, Kevin; Gibert, Dominique; Marteau, Jacques; de Bremond d’Ars, Jean; Komorowski, Jean-Christophe

    2016-01-01

    Imaging geological structures through cosmic muon radiography is a newly developed technique which shows a great potential in volcanology. Here we demonstrate that muon radiography permits to detect and characterize mass movements in shallow hydrothermal systems of low-energy active volcanoes like the La Soufrière lava dome. We present an experiment conducted on this volcano during the Summer 2014 and bring evidence that very important density changes occurred in three domains of the lava dome. Depending on their position and on the medium porosity the volumes of these domains vary from 1 × 106 m3 to 7 × 106 m3. However, the total mass budget remains approximately constant : two domains show a mass loss (Δm∈ [−0.8;−0.4] × 109 kg) and the third one a mass gain (Δm∈ [1.5; 2.5] × 109 kg). We attribute the negative mass changes to the formation of steam in shallow hydrothermal reservoir previously partly filled with liquid water. This coincides with the emergence of new fumaroles on top of the volcano. The positive mass change is synchronized with the negative mass changes indicating that liquid water probably flowed from the two reservoirs invaded by steam toward the third reservoir. PMID:27629497

  18. Muon dynamic radiography of density changes induced by hydrothermal activity at the La Soufrière of Guadeloupe volcano.

    PubMed

    Jourde, Kevin; Gibert, Dominique; Marteau, Jacques; de Bremond d'Ars, Jean; Komorowski, Jean-Christophe

    2016-01-01

    Imaging geological structures through cosmic muon radiography is a newly developed technique which shows a great potential in volcanology. Here we demonstrate that muon radiography permits to detect and characterize mass movements in shallow hydrothermal systems of low-energy active volcanoes like the La Soufrière lava dome. We present an experiment conducted on this volcano during the Summer 2014 and bring evidence that very important density changes occurred in three domains of the lava dome. Depending on their position and on the medium porosity the volumes of these domains vary from 1 × 10(6) m(3) to 7 × 10(6) m(3). However, the total mass budget remains approximately constant : two domains show a mass loss (Δm∈ [-0.8;-0.4] × 10(9) kg) and the third one a mass gain (Δm∈ [1.5; 2.5] × 10(9) kg). We attribute the negative mass changes to the formation of steam in shallow hydrothermal reservoir previously partly filled with liquid water. This coincides with the emergence of new fumaroles on top of the volcano. The positive mass change is synchronized with the negative mass changes indicating that liquid water probably flowed from the two reservoirs invaded by steam toward the third reservoir. PMID:27629497

  19. Muon dynamic radiography of density changes induced by hydrothermal activity at the La Soufrière of Guadeloupe volcano.

    PubMed

    Jourde, Kevin; Gibert, Dominique; Marteau, Jacques; de Bremond d'Ars, Jean; Komorowski, Jean-Christophe

    2016-09-15

    Imaging geological structures through cosmic muon radiography is a newly developed technique which shows a great potential in volcanology. Here we demonstrate that muon radiography permits to detect and characterize mass movements in shallow hydrothermal systems of low-energy active volcanoes like the La Soufrière lava dome. We present an experiment conducted on this volcano during the Summer 2014 and bring evidence that very important density changes occurred in three domains of the lava dome. Depending on their position and on the medium porosity the volumes of these domains vary from 1 × 10(6) m(3) to 7 × 10(6) m(3). However, the total mass budget remains approximately constant : two domains show a mass loss (Δm∈ [-0.8;-0.4] × 10(9) kg) and the third one a mass gain (Δm∈ [1.5; 2.5] × 10(9) kg). We attribute the negative mass changes to the formation of steam in shallow hydrothermal reservoir previously partly filled with liquid water. This coincides with the emergence of new fumaroles on top of the volcano. The positive mass change is synchronized with the negative mass changes indicating that liquid water probably flowed from the two reservoirs invaded by steam toward the third reservoir.

  20. Muon dynamic radiography of density changes induced by hydrothermal activity at the La Soufrière of Guadeloupe volcano

    NASA Astrophysics Data System (ADS)

    Jourde, Kevin; Gibert, Dominique; Marteau, Jacques; de Bremond D’Ars, Jean; Komorowski, Jean-Christophe

    2016-09-01

    Imaging geological structures through cosmic muon radiography is a newly developed technique which shows a great potential in volcanology. Here we demonstrate that muon radiography permits to detect and characterize mass movements in shallow hydrothermal systems of low-energy active volcanoes like the La Soufrière lava dome. We present an experiment conducted on this volcano during the Summer 2014 and bring evidence that very important density changes occurred in three domains of the lava dome. Depending on their position and on the medium porosity the volumes of these domains vary from 1 × 106 m3 to 7 × 106 m3. However, the total mass budget remains approximately constant : two domains show a mass loss (Δm∈ [‑0.8‑0.4] × 109 kg) and the third one a mass gain (Δm∈ [1.5; 2.5] × 109 kg). We attribute the negative mass changes to the formation of steam in shallow hydrothermal reservoir previously partly filled with liquid water. This coincides with the emergence of new fumaroles on top of the volcano. The positive mass change is synchronized with the negative mass changes indicating that liquid water probably flowed from the two reservoirs invaded by steam toward the third reservoir.

  1. Hydrothermal mineralization at seafloor spreading centers

    NASA Astrophysics Data System (ADS)

    Rona, Peter A.

    1984-01-01

    The recent recognition that metallic mineral deposits are concentrated by hydrothermal processes at seafloor spreading centers constitutes a scientific breakthrough that opens active sites at seafloor spreading centers as natural laboratories to investigate ore-forming processes of such economically useful deposits as massive sulfides in volcanogenic rocks on land, and that enhances the metallic mineral potential of oceanic crust covering two-thirds of the Earth both beneath ocean basins and exposed on land in ophiolite belts. This paper reviews our knowledge of processes of hydrothermal mineralization and the occurrence and distribution of hydrothermal mineral deposits at the global oceanic ridge-rift system. Sub-seafloor hydrothermal convection involving circulation of seawater through fractured rocks of oceanic crust driven by heat supplied by generation of new lithosphere is nearly ubiquitous at seafloor spreading centers. However, ore-forming hydrothermal systems are extremely localized where conditions of anomalously high thermal gradients and permeability increase hydrothermal activity from the ubiquitous low-intensity background level (⩽ 200°C) to high-intensity characterized by high temperatures ( > 200-c.400°C), and a rate and volume of flow sufficient to sustain chemical reactions that produce acid, reducing, metal-rich primary hydrothermal solutions. A series of mineral phases with sulfides and oxides as high- and low-temperature end members, respectively, are precipitated along the upwelling limb and in the discharge zone of single-phase systems as a function of increasing admixture of normal seawater. The occurrence of hydrothermal mineral deposits is considered in terms of spatial and temporal frames of reference. Spatial frames of reference comprise structural features along-axis (linear sections that are the loci of seafloor spreading alternating with transform faults) and perpendicular to axis (axial zone of volcanic extrusion and marginal

  2. A national drilling program to study the roots of active hydrothermal systems related to young magmatic intrusions

    SciTech Connect

    Not Available

    1984-01-01

    The importance of studies of active hydrothermal-magma systems as part of a national continental scientific drilling program has been emphasized in numerous workshops and symposia. The present report, prepared by the Panel on Thermal Regimes of the Continental Scientific Drilling Committee, both reinforces and expands on earlier recommendations. The US Geodynamics Committee 1979 report of the Los Almos workshop, Continental Scientific Drilling Program, placed major emphasis on maximizing the scientific value of current and planned drilling by industry and government, supplementing these efforts with holes drilled solely for scientific purposes. Although the present report notes the importance of opportunities for scientific investigations that may be added on to current, mission-oriented drilling activities, the Panel on Thermal Regimes recognizes that such opportunities are limited and thus focused its study on holes dedicated to broad scientific objectives. 16 refs., 2 figs., 4 tabs.

  3. Geochemistry of fluid phases and sediments: Relevance to hydrothermal circulation in Middle Valley, ODP Legs 139 and 169

    USGS Publications Warehouse

    Gieskes, J.M.; Simoneit, B.R.T.; Shanks, Wayne C.; Goodfellow, W.D.; James, R.H.; Baker, P.A.; Ishibashi, J.-I.

    2002-01-01

    Geochemical and isotopic studies of pore fluids and solid phases recovered from the Dead Dog and Bent Hill hydrothermal sites in Middle Valley (Ocean Drilling Program Leg 169) have been compared with similar data obtained previously from these sites during Ocean Drilling Program Leg 139. Although generally the hydrothermal systems reflect non-steady state conditions, the data allow an assessment of the history of the hydrothermal processes. Sediment K/A1 ratios as well as the distribution of anhydrite in the sediments suggest that the Dead Dog hydrothermal field has been, and still is, active. In contrast, similar data in the Bent Hill hydrothermal field indicate a waning of hydrothermal activity. Pore fluid and hydrothermal vent data in the Dead Dog hydrothermal field are similar in nature to the data collected during ODP Leg 139. In the area of the Bent Hill sulfide deposit, however, the pore water data indicate that recent wholesale flushing of the sediment column with relatively unaltered seawater has obliterated a previous record of hydrothermal activity in the pore fluids. Data from the deepest part of Hole 1035A in the Bent Hill locality show the presence of hydrothermal fluids at greater depths in this area. This suggests the origin of the hydrothermal fluids found to be emanating from Hole 1035F, which constitutes one of the first man made hydrothermal vents in the Middle Valley hydrothermal system. Similarly, CORKed Hole 858G, because of seal failures, has acted as a hydrothermal vent, with sulfide deposits forming inside the CORK. ?? 2002 Elsevier Science Ltd. All rights reserved.

  4. Hydrothermal fluids circulation and travertine deposition in an active tectonic setting: Insights from the Kamara geothermal area (western Anatolia, Turkey)

    NASA Astrophysics Data System (ADS)

    Brogi, Andrea; Alçiçek, M. Cihat; Yalçıner, Cahit Çağlar; Capezzuoli, Enrico; Liotta, Domenico; Meccheri, Marco; Rimondi, Valentina; Ruggieri, Giovanni; Gandin, Anna; Boschi, Chiara; Büyüksaraç, Aydin; Alçiçek, Hülya; Bülbül, Ali; Baykara, Mehmet Oruç; Shen, Chuan-Chou

    2016-06-01

    Coexistence of thermal springs, travertine deposits and tectonic activity is a recurring feature for most geothermal areas. Although such a certainty, their relationships are debated mainly addressing on the role of the tectonic activity in triggering and controlling fluids flow and travertine deposition. In this paper, we present the results of an integrated study carried out in a geothermal area located in western Anatolia (Turkey), nearby the well-known Pamukkale area (Denizli Basin). Our study focused on the relationships among hydrothermal fluids circulation, travertine deposition and tectonic activity, with particular emphasis on the role of faults in controlling fluids upwelling, thermal springs location and deposition of travertine masses. New field mapping and structural/kinematics analyses allowed us to recognize two main faults systems (NW- and NE-trending), framed in the Neogene-Quaternary extensional tectonic evolution of western Anatolia. A geo-radar (GPR) prospection was also provided in a key-area, permitting us to reconstruct a buried fault zone and its relationships with the development of a fissure-ridge travertine deposit (Kamara fissure-ridge). The integration among structural and geophysical studies, fluids inclusion, geochemical, isotopic data and 230 Th/238 U radiometric age determination on travertine deposits, depict the characteristics of the geothermal fluids and their pathway, up to the surface. Hydrological and seismological data have been also taken in account to investigate the relation between local seismicity and fluid upwelling. As a main conclusion we found strict relationships among tectonic activity, earthquakes occurrence, and variation of the physical/chemical features of the hydrothermal fluids, presently exploited at depth, or flowing out in thermal springs. In the same way, we underline the tectonic role in controlling the travertine deposition, making travertine (mainly banded travertine) a useful proxy to reconstruct the

  5. River solute fluxes reflecting active hydrothermal chemical weathering of the Yellowstone Plateau Volcanic Field, USA

    USGS Publications Warehouse

    Hurwitz, S.; Evans, William C.; Lowenstern, J. B.

    2010-01-01

    In the past few decades numerous studies have quantified the load of dissolved solids in large rivers to determine chemical weathering rates in orogenic belts and volcanic areas, mainly motivated by the notion that over timescales greater than ~100kyr, silicate hydrolysis may be the dominant sink for atmospheric CO2, thus creating a feedback between climate and weathering. Here, we report the results of a detailed study during water year 2007 (October 1, 2006 to September 30, 2007) in the major rivers of the Yellowstone Plateau Volcanic Field (YPVF) which hosts Earth's largest "restless" caldera and over 10,000 thermal features. The chemical compositions of rivers that drain thermal areas in the YPVF differ significantly from the compositions of rivers that drain non-thermal areas. There are large seasonal variations in river chemistry and solute flux, which increases with increasing water discharge. The river chemistry and discharge data collected periodically over an entire year allow us to constrain the annual solute fluxes and to distinguish between low-temperature weathering and hydrothermal flux components. The TDS flux from Yellowstone Caldera in water year 2007 was 93t/km2/year. Extensive magma degassing and hydrothermal interaction with rocks accounts for at least 82% of this TDS flux, 83% of the cation flux and 72% of the HCO3- flux. The low-temperature chemical weathering rate (17t/km2/year), calculated on the assumption that all the Cl- is of thermal origin, could include a component from low-temperature hydrolysis reactions induced by CO2 ascending from depth rather than by atmospheric CO2. Although this uncertainty remains, the calculated low-temperature weathering rate of the young rhyolitic rocks in the Yellowstone Caldera is comparable to the world average of large watersheds that drain also more soluble carbonates and evaporates but is slightly lower than calculated rates in other, less-silicic volcanic regions. Long-term average fluxes at

  6. Effects of hydrothermal processes on antioxidants in brown, purple and red bran whole grain rice (Oryza sativa L.).

    PubMed

    Min, Byungrok; McClung, Anna; Chen, Ming-Hsuan

    2014-09-15

    The impacts of parboiling and wet-cooking, alone and in combination, on the concentrations of lipophilic antioxidants (vitamin E and γ-oryzanol), soluble (including proanthocyanidins and anthocyanins) and cell wall-bound phenolics, and antioxidant capacities in whole grain rice from six cultivars having different bran colours were investigated. Parboiling rough and brown rice increased the concentrations of lipophilic antioxidants in whole grain rice but decreased the concentrations of total phenolics and antioxidant capacities found in the soluble fraction. After hydrothermal processing of purple bran rice, the retention of extractable anthocyanins was low, but was high for simple phenolics. For proanthocyanidins found in red bran rice, the extractable oligomers with a degree of polymerization (DP) less than 4, increased up to 6-fold; while for oligomers with DP⩾4 and polymers, there was a significant decrease that was positively correlated with the DP and the temperature of the processing methods. The presence of hulls helped to retain water-soluble antioxidants during parboiling.

  7. Production of acetic acid by hydrothermal two-step process of vegetable wastes for use as a road deicer

    NASA Astrophysics Data System (ADS)

    Jin, F.; Watanabe, Y.; Kishita, A.; Enomoto, H.; Kishida, H.

    2008-07-01

    This study aimed to produce acetic acid from vegetable wastes by a new hydrothermal two-step process. A continuous flow reaction system with a maximum treatment capacity of 2 kg/h of dry biomass developed by us was used. Five kinds of vegetables of carrots, white radish, chinese cabbage, cabbage and potato were selected as the representation of vegetable wastes. First, batch experiments with the selected vegetables were performed under the condition of 300°C, 1 min for the first step, and 300°C, 1 min and 70% oxygen supply for the second step, which is the optimum condition for producing acetic acid in the case of using starch as test material. The highest yields of acetic acid from five vegetables were almost the same as those obtained from starch. Subsequently, similar the highest yield of acetic acid and experimental conditions from vegetables were also obtained successfully using the continuous flow reaction system. These results should be useful for developing an industrial scale process.

  8. Evidence of hydrothermal activity on Marsili Seamount, Tyrrhenian Basin. Technical report

    SciTech Connect

    Uchupi, E.; Ballard, R.D.

    1989-01-01

    In this paper we describe the finding of what appears to be an extensive hydrothermal mineral deposit on the crest of Marsili Seamount in the Tyrrhenian Basin, western Mediterranean Sea. The deposit on the seamount was discovered during a study of the geology of the Tyrrhenian Basin with the Argo video system (HARRIS and BALLARD, 1986) aboard the R.V. Starella during June 1988. Mounted on the vehicle were three Silicon Intensified target (SIT) cameras, a digital charge Couple Device (CCD) camera and a 35 mm camera with a 16 mm lens. The site was revisited in mid August aboard the R.V. Knorr during a cruise to test the dynamic position system on the Knorr.

  9. Geological framework of an active hydrothermal site in the North Fiji Basin: Starmer cruise of the submersible Nautile

    SciTech Connect

    Auzende, J. )

    1990-06-01

    During the summer of 1989 the French submersible Nautile carried out a diving cruise on the North Fiji Basin ridge axis in the frame of the Starmer French-Japanese joint project. The diving sites were selected using the Seapso 3, Kaiyo 87, and Kaiyo 88 cruises Seabeam surveys. They are located around 17{degree}S in the axial graben at the northern end of the N15 ridge. The axis consists of an 18 km wide, N15 elongated dome cut by a 2 km wide axial graben. The elevation of the dome with respect to adjacent oceanic floor is 500-600 m. It culminates at less than 1,900 m, which is higher than a normal oceanic ridge. The axial graben width (2 km) is also unusual compared to oceanic ridge with intermediate spreading rates such as the EPR at 21{degree}N. Six Nautile dives have been devoted to the detailed exploration of the axial graben between 16{degree}58'S and 17{degree}00'S in order to locate the hydrothermal vents in the inferred most active part of the axial graben. A structural map has been established on the basis of dive observation. Between 17{degree}S and 16{degree}58'S, the axis shows a succession of N15-trending horsts and grabens paralleling the main orientation of the ridge. Two main lateral grabens and a central graben can be recognized. The central graben shows remarkably constant width (200 m) and depth (2,000 m). It is bounded by two small horsts, few tens of meters wide. Observed tectonic features include N15 normal fault scarps and abundant open fissures with the same direction. The whole area is dusted with sediments indicating that volcanism was not active recently. Evidence of recent hydrothermal activity such as oxide staining, dead munch, dead chimney is abundant all along the central graben.

  10. Geological setting of hydrothermal activity at 12°50'N on the East Pacific Rise: A submersible study

    NASA Astrophysics Data System (ADS)

    Ballard, R. D.; Hekinian, Roger; Francheteau, Jean

    1984-07-01

    A detailed submersible investigation of a 20-km segment of the East Pacific Rise near 12°50'N between the Orozco and Clipperton fracture zones has resulted in the localization of 24 active hydrothermal vent fields and over 80 sites of sulfide accumulations. The active vents range from low-temperature vents characterized by exotic benthic communities to high-temperature "black smokers" and the deposition of polymetallic sulfides. The study is based upon a combination of fine scale topography obtained using the SEABEAM sonar system on N/O "Jean Charcot", camera lowerings along the axis using the RAIE vehicle, and 32 dives by the submersible "Cyana" operating from N/O "Le Suroit". The observations made between the Orozco and Clipperton fracture zones show topographic highs situated along the strike of the accreting plate segment separated by a small ridge offset at 11°49'N. This offset divides this portion of the ridge into two separate spreading segments each of which has a primary topographic high along strike. Secondary highs are associated with each segment of the ridge separated by either small offsets (or relay zones) or in some cases, zones where spreading centers overlap. Dives made on the tops of both primary highs (12°50'N and 11°30'N) confirm the presence inferred from previous surface work of high-temperature vent fields while one reconnaissance dive (14°20'N) near the Orozco fracture zone/ridge axis intersection reveals the absence of any hydrothermal activity in the present or recent past. The vast majority of vent fields investigated were found at the topographic high near 12°50'N, are associated with the most recent period of volcanism, and are confined to lava ponds situated within the axial graben.

  11. Tectonic Windows Reveal Off-axis Volcanic and Hydrothermal Activity and Along-strike Variations in Eruption Effusion Rates

    NASA Astrophysics Data System (ADS)

    MacDonald, K. C.

    2005-12-01

    Alvin transects of faulted escarpments 50-500m high provide tectonic windows to investigate the top 500m of oceanic crustal structure and lava stratigraphy. The Alvin archives were used to review dives from the East Pacific Rise, the Mid-Atlantic Ridge, the Juan de Fuca Ridge, the Blanco Trough, Cayman Trough and the Galapagos Spreading Center. A spreading rate dependence in lava morphology based solely on areal coverage(Bonatti and Harrison, 1988) was confirmed in scarp transects: mostly pillow lavas at slow spreading rates and sheet flows/lobate flows at faster spreading rates. More interestingly; there is a systematic variation within first, second and third order segments on intermediate and fast-spreading centers such that sheet/lobate flows dominate at segment centers and pillow flows and lava domes are more common at segment ends. This confirms earlier studies which were based on areal coverage (White et al, 2000, 2002, Soule et al 2005). This suggests higher eruption effusion rates and perhaps higher magma pressure and lower magma viscosity at segment centers relative to segment ends. This has important implications for the relationship between segmentation, magma supply, volcanism and hydrothermal activity (Haymon and White 2005). A conundrum remains; based on areal photographic surveys, why are pillow lavas so much more common off-axis than on-axis for intermediate to fast-spreading ridges? If there is an eruption cycle in which sheeted and lobate flows dominate early on, and pillow lavas dominate the waning stages of eruption (e.g. Ballard et al 1979), then more pillow lavas should be seen on axis than are seen on-axis in either areal or transect data. Another explanation is that pillow lavas off-axis are primarily produced by off-axis eruptions (except near segment ends, they may also occur as the pillowed terminations of channeled sheet and lobate flows; the association with channels will make this obvious.) Off-axis volcanism is also indicated by a

  12. Observation of hydrothermal flows with acoustic video camera

    NASA Astrophysics Data System (ADS)

    Mochizuki, M.; Asada, A.; Tamaki, K.; Scientific Team Of Yk09-13 Leg 1

    2010-12-01

    To evaluate hydrothermal discharging and its diffusion process along the ocean ridge is necessary for understanding balance of mass and flux in the ocean, ecosystem around hydrothermal fields and so on. However, it has been difficult for us to measure hydrothermal activities without disturbance caused by observation platform ( submersible, ROV, AUV ). We wanted to have some observational method to observe hydrothermal discharging behavior as it was. DIDSON (Dual-Frequency IDentification SONar) is acoustic lens-based sonar. It has sufficiently high resolution and rapid refresh rate that it can substitute for optical system in turbid or dark water where optical systems fail. DIDSON operates at two frequencies, 1.8MHz or 1.1MHz, and forms 96 beams spaced 0.3° apart or 48 beams spaced 0.6° apart respectively. It images out to 12m at 1.8MHz and 40m at 1.1MHz. The transmit and receive beams are formed with acoustic lenses with rectangular apertures and made of polymethylpentene plastic and FC-70 liquid. This physical beam forming allows DIDSON to consume only 30W of power. DIDSON updates its image between 20 to 1 frames/s depending on the operating frequency and the maximum range imaged. It communicates its host using Ethernet. Institute of Industrial Science, University of Tokyo ( IIS ) has understood DIDSON’s superior performance and tried to find new method for utilization of it. The observation systems that IIS has ever developed based on DIDSON are waterside surveillance system, automatic measurement system for fish length, automatic system for fish counting, diagnosis system for deterioration of underwater structure and so on. A next challenge is to develop an observation method based on DIDSON for hydrothermal discharging from seafloor vent. We expected DIDSON to reveal whole image of hydrothermal plume as well as detail inside the plume. In October 2009, we conducted seafloor reconnaissance using a manned deep-sea submersible Shinkai6500 in Central Indian

  13. Influence of pH on hydrothermal treatment of swine manure: Impact on extraction of nitrogen and phosphorus in process water.

    PubMed

    Ekpo, U; Ross, A B; Camargo-Valero, M A; Fletcher, L A

    2016-08-01

    This study investigates the influence of pH on extraction of nitrogen and phosphorus from swine manure following hydrothermal treatment. Conditions include thermal hydrolysis (TH) at 120°C and 170°C, and hydrothermal carbonisation (HTC) at 200°C and 250°C in either water alone or in the presence of 0.1M NaOH, H2SO4, CH3COOH or HCOOH. Phosphorus extraction is pH and temperature dependent and is enhanced under acidic conditions. The highest level of phosphorus is extracted using H2SO4 reaching 94% at 170°C. The phosphorus is largely retained in the residue for all other conditions. The extraction of nitrogen is not as significantly influenced by pH, although the maximum N extraction is achieved using H2SO4. A significant level of organic-N is extracted into the process waters following hydrothermal treatment. The results indicate that operating hydrothermal treatment in the presence of acidic additives has benefits in terms of improving the extraction of phosphorus and nitrogen.

  14. Influence of pH on hydrothermal treatment of swine manure: Impact on extraction of nitrogen and phosphorus in process water.

    PubMed

    Ekpo, U; Ross, A B; Camargo-Valero, M A; Fletcher, L A

    2016-08-01

    This study investigates the influence of pH on extraction of nitrogen and phosphorus from swine manure following hydrothermal treatment. Conditions include thermal hydrolysis (TH) at 120°C and 170°C, and hydrothermal carbonisation (HTC) at 200°C and 250°C in either water alone or in the presence of 0.1M NaOH, H2SO4, CH3COOH or HCOOH. Phosphorus extraction is pH and temperature dependent and is enhanced under acidic conditions. The highest level of phosphorus is extracted using H2SO4 reaching 94% at 170°C. The phosphorus is largely retained in the residue for all other conditions. The extraction of nitrogen is not as significantly influenced by pH, although the maximum N extraction is achieved using H2SO4. A significant level of organic-N is extracted into the process waters following hydrothermal treatment. The results indicate that operating hydrothermal treatment in the presence of acidic additives has benefits in terms of improving the extraction of phosphorus and nitrogen. PMID:27187568

  15. Influence of hydrothermal processes on changes of volcanic rocks (data of physical modelling)

    NASA Astrophysics Data System (ADS)

    Shanina, V. V.; Bychkov, A. Y.

    2009-04-01

    Due to active development of geothermal energy, in middle of the last century have begun papers devoted to experiments, directed on study of transformations of minerals [4] and rocks [1, 2, 5] under action of geothermal processes. But any researcher did not estimate thus change of their physical and physico-mechanical properties. The purpose of job - to study character and dynamics changes of volcanic rocks (to simulate conditions of geothermal transformations). Tasks: creation of the whole series of experiments in autoclavs at various temperatures, pressure and composition of solutions, preparation of samples, study of chemical and mineral composition, structure and properties of rocks and solutions before and after experiments. In 2006 the first similar experiments were begun [3]. Researched rocks basalts, hyaloclasites and obsidian, selected from Iceland and tuffs Payzhetka Geothermal Field, Southern Kamchatka, Russia. Were used autoclavs, consisting from titanic of an alloy ВТ-8, volume 116-119 мл, in each of which was located from 2 up to 4 samples of rocks of the investigated structure and properties. The heating was made in OVEN ТРМ-10 with accuracy + 1 °С, the constancy of temperature was supervised by thermocouples. 15 experiences (temperature 200, 300 and 450 °С; pressure 16, 86 and 1000 bars accordingly now are carried out; 4 solutions (1 alkaline and 3 acid); duration 14, 15, 30 and 60 days). All four groups of the investigated rocks appreciablly react under geothermal influence. The changes are observed in colour of samples (brighten in acid solutions), their microstructure, that for basalts is visible only in raster electronic microscope, and in education of new mineral phases, is especially active in a acid solution, the X-Ray analysis (has executed by Dr. Krupskaya V.V., apparatuses - DRON- UM1) has shown, that 94,2 % is smectite, 3,5 % - kaolinite, 1,2 % - crisrobalite, 1,1 % - diopside (?), in others pores fills chlorite, and in an

  16. Influence of hydrothermal processes on changes of volcanic rocks (data of physical modelling)

    NASA Astrophysics Data System (ADS)

    Shanina, V. V.; Bychkov, A. Y.

    2009-04-01

    Due to active development of geothermal energy, in middle of the last century have begun papers devoted to experiments, directed on study of transformations of minerals [4] and rocks [1, 2, 5] under action of geothermal processes. But any researcher did not estimate thus change of their physical and physico-mechanical properties. The purpose of job - to study character and dynamics changes of volcanic rocks (to simulate conditions of geothermal transformations). Tasks: creation of the whole series of experiments in autoclavs at various temperatures, pressure and composition of solutions, preparation of samples, study of chemical and mineral composition, structure and properties of rocks and solutions before and after experiments. In 2006 the first similar experiments were begun [3]. Researched rocks basalts, hyaloclasites and obsidian, selected from Iceland and tuffs Payzhetka Geothermal Field, Southern Kamchatka, Russia. Were used autoclavs, consisting from titanic of an alloy ВТ-8, volume 116-119 мл, in each of which was located from 2 up to 4 samples of rocks of the investigated structure and properties. The heating was made in OVEN ТРМ-10 with accuracy + 1 °С, the constancy of temperature was supervised by thermocouples. 15 experiences (temperature 200, 300 and 450 °С; pressure 16, 86 and 1000 bars accordingly now are carried out; 4 solutions (1 alkaline and 3 acid); duration 14, 15, 30 and 60 days). All four groups of the investigated rocks appreciablly react under geothermal influence. The changes are observed in colour of samples (brighten in acid solutions), their microstructure, that for basalts is visible only in raster electronic microscope, and in education of new mineral phases, is especially active in a acid solution, the X-Ray analysis (has executed by Dr. Krupskaya V.V., apparatuses - DRON- UM1) has shown, that 94,2 % is smectite, 3,5 % - kaolinite, 1,2 % - crisrobalite, 1,1 % - diopside (?), in others pores fills chlorite, and in an

  17. Discovery of Nascent Vents and Recent Colonization Associated with(Re)activated Hydrothermal Vent Fields by the GALREX 2011 Expedition on the Galápagos Rift

    NASA Astrophysics Data System (ADS)

    Shank, T. M.; Holden, J. F.; Herrera, S.; Munro, C.; Muric, T.; Lin, J.; Stuart, L.

    2011-12-01

    GALREX 2011 was a NOAA OER telepresence cruise that explored the diverse habitats and geologic settings of the deep Galápagos region. The expedition made12 Little Hercules ROV dives in July 2011.Abundant corals and a strong depth zonation of species (including deepwater coral communities) were found near 500 m depth on Paramount Seamount, likely influenced by past low sea level states, wave-cut terrace processes, and the historical presence of shallow reef structures. At fresh lava flows with associated (flocculent) hydrothermal venting near 88° W, now known as Uka Pacha and Pegasus Vent Fields, rocks were coated with white microbial mat and lacked sessile fauna, with few mobile fauna (e.g., bythograeid crabs, alvinocarid shrimp, polynoid worms, zoarcid fish, and dirivultid copepods). This suggests a recent creation of hydrothermal habitats through volcanic eruptions and/or diking events, which may have taken place over a 15 km span separating the two vent fields. The Rosebud vent field at 86°W was not observed and may have been covered with lava since last visited in 2005. A hydrothermal vent field near 86°W was discovered that is one of the largest vent fields known on the Rift (120m by 40m). Low-temperature vent habitats were colonized by low numbers of tubeworms including Riftia, Oasisia, and a potential Tevnia species (the latter not previously observed on the Galapagos Rift). Patches of tubeworms were observed with individuals less than 2cm in length, and the relatively few large Riftia had tube lengths near 70cm long. Large numbers of small (< 3cm long) bathymodiolin mussels lined cracks and crevices throughout the active part of the field. Live clams, at least four species of gastropod limpets, three species of polynoid polychaetes, juvenile and adult alvinocarid shrimp, actinostolid anemones, and white microbial communities were observed on the underside and vertical surfaces of basalt rock surfaces. There were at least 13 species of vent-endemic fauna

  18. Tectonic, magmatic, and hydrothermal processes imaged by high-resolution seismicity beneath the fast-spreading East Pacific Rise (Invited)

    NASA Astrophysics Data System (ADS)

    Waldhauser, F.; Tolstoy, M.

    2010-12-01

    Cross-correlation and double-difference earthquake relocation methods have produced hypocenter locations with unprecedented resolution at many different scales and locations. The new locations typically image fine-scale seismogenic structures that help address important seismological and plate tectonic questions. In this paper we present results from a worldwide unique data set of more than 300,000 micro-earthquakes recorded at a dense OBS array (4x4 km) located on the fast-spreading East Pacific Rise at 9°50’ N. The array captured the build up of seismicity leading to a sea floor eruption in January 2006. We focus on improved relocations of ~16,000 earthquakes recorded during the first deployment between October 2003 and April 2004. An initial double-difference analysis using only analyst picks revealed the general structure of an along-axis oriented hydrothermal circulation cell, with an inferred down-flow zone near a 4th-order axial discontinuity and a cracking front overlying the axial magma chamber (AMC). To gain further insight into the detailed structure and kinematics of this divergent plate boundary we have increased the precision in event location by including cross-correlation delay times and improving relocation procedures that harness the high event density. We find that the majority of events within the down flow pipe represent frictional slip on short faults caused by regional tectonic stresses and thermal contraction as the cold sea water enters the hot crust. Along the eastern side of the ridge axis, just above the AMC at ~1.4 km depth, we observe repeated shear failure along well defined steeply east dipping structures. Composite first motion focal mechanisms for these strongly correlated events indicate reverse motion, suggesting that slip on these faults is caused by AMC inflation and associated injection of magma into a narrow sill. A broader sill appears to have formed at the bottom of the upflow zone beneath the active hydrothermal vents

  19. Mineralogical and strontium isotopic record of hydrothermal processes in the lower ocean crust at and near the East Pacific Rise

    NASA Astrophysics Data System (ADS)

    Kirchner, Timo M.; Gillis, Kathryn M.

    2012-07-01

    Tectonic exposures of upper plutonics (>800 m) that are part of a contiguous section of young East Pacific Rise (EPR) crust at the Hess Deep Rift provide the first regional-scale constraints on hydrothermal processes in the upper plutonic crust formed at a fast-spreading ridge. Submersible-collected samples recovered over a 4-km-wide region show that the sheeted dike complex is largely underlain by a 150- to 200-m-thick gabbro unit, followed by a more primitive gabbronorite unit. Gabbroic samples are variably altered by pervasive fluid flow along fracture networks to amphibole-dominated assemblages. The gabbroic rocks are significantly less altered (average 11% hydrous phases) than the overlying sheeted dike complex (average 24%), and the percentage of hydrous alteration diminishes with depth. Incipient, pervasive fluid flow occurred at amphibolite facies conditions (average 720°C), with slightly higher temperatures in the lower 500 m of the section. The extent of subsequent lower-temperature alteration is generally low and regionally variable. The gabbroic samples are slightly elevated in 87Sr/86Sr relative to fresh rock values (0.7024) and less enriched than the overlying sheeted dike complex. 87Sr/86Sr for the pervasively altered gabbroic samples ranges from 0.70244 to 0.70273 (mean 0.70257), tonalites is 0.7038, and pyroxene hornfels ranges from 0.70259 to 0.70271. 87Sr/86Sr does not vary with depth, and there is a strong positive correlation with the percentage of hydrous phases. Strontium contents of igneous and hydrothermal minerals, combined with bulk rock 87Sr/86Sr, indicate that Sr-isotopic exchange is largely controlled by the uptake of fluid 87Sr/86Sr in hydrous minerals and does not require Sr gain or loss. The minimum, time-integrated fluid-rock ratio for the sheeted dike complex and upper plutonics is 0.55-0.66, and the fluid flux calculated by mass balance is ~2.1 to 2.5 × 106 kg m-2, 30-60% higher than fluid fluxes calculated in the same manner

  20. Hydrothermal treatment coupled with mechanical expression at increased temperature for excess sludge dewatering: influence of operating conditions and the process energetics.

    PubMed

    Wang, Liping; Zhang, Lei; Li, Aimin

    2014-11-15

    Dewatering is very important for excess sludge treatment and disposal. Hydrothermal treatment coupled with mechanical expression is a novel technology, in which a conventional pressure dewatering is combined with hydrothermal effect to realize an improved liquid/solids separation with low energy consumption. In this study, the process was performed by way of that the excess sludge was hydrothermally treated first and then the mechanical expression was employed immediately at increased temperature in two separate cells respectively. The results demonstrated that the mechanical expression employed at increased temperature showed a significant advantage than that at room temperature, given a further reduction of 19-47% of the moisture content. The dewatering process at room temperature was mostly depended on the effect of mechanical expression. Hydrothermal process, more importantly than mechanical effect at increased temperatures, seemed to govern the extent to which the dewatering process occurred. The dewatering began to show a positive effect when the temperature was exceeded the threshold temperature (between 120 and 150 °C). The residence time of 30 min promoted a substantial conversion in the sludge surface properties. After dewatering at temperatures of 180-210 °C, the moisture content decreased from 52 to 20% and the corresponding total water removal as filtrate was between 81 and 93%. It was observed that the moisture content of filter cake correlated with surface charge (Rp = -0.93, p < 0.05) and relative hydrophobicity (Rp = -0.99, p < 0.05). The calculated energy balance suggested that no additional external energy input is needed to support the dewatering process for excess sludge. The dewatering process needs an obviously lower energy input compared to thermal drying and electro-dewatering to produce a higher solids content cake.

  1. Formation and morphology of Zn(2)Ti(3)O(8) powders using hydrothermal process without dispersant agent or mineralizer.

    PubMed

    Wang, Cheng-Li; Hwang, Weng-Sing; Chang, Kuo-Ming; Ko, Horng-Huey; Hsi, Chi-Shiung; Huang, Hong-Hsin; Wang, Moo-Chin

    2011-01-28

    Synthesis of Zn(2)Ti(3)O(8) powders for attenuating UVA using TiCl(4), Zn(NO(3))(2)·6H(2)O and NH(4)OH as precursor materials by hydrothermal process has been investigated. The X-ray diffractometry (XRD) results show the phases of ZnO, anatase TiO(2) and Zn(2)Ti(3)O(8) coexisted when the zinc titanate powders were calcined at 600 °C for 1 h. When calcined at 900 °C for 1 h, the XRD results reveal the existence of ZnO, Zn(2)TiO(4), rutile TiO(2) and ZnTiO(3). Scanning electron microscope (SEM) observations show extensive large agglomeration in the samples. Transmission electron microscope (TEM) and electron diffraction (ED) examination results indicate that ZnTiO(3) crystallites formed with a size of about 5 nm on the matrix of plate-like ZnO when calcined at 700 °C for 1 h. The calcination samples have acceptable absorbance at a wavelength of 400 nm, indicating that the zinc titanate precursor powders calcined at 700 °C for 1 h can be used as an UVA-attenuating agent.

  2. Formation and Morphology of Zn2Ti3O8 Powders Using Hydrothermal Process without Dispersant Agent or Mineralizer

    PubMed Central

    Wang, Cheng-Li; Hwang, Weng-Sing; Chang, Kuo-Ming; Ko, Horng-Huey; Hsi, Chi-Shiung; Huang, Hong-Hsin; Wang, Moo-Chin

    2011-01-01

    Synthesis of Zn2Ti3O8 powders for attenuating UVA using TiCl4, Zn(NO3)2·6H2O and NH4OH as precursor materials by hydrothermal process has been investigated. The X-ray diffractometry (XRD) results show the phases of ZnO, anatase TiO2 and Zn2Ti3O8 coexisted when the zinc titanate powders were calcined at 600 °C for 1 h. When calcined at 900 °C for 1 h, the XRD results reveal the existence of ZnO, Zn2TiO4, rutile TiO2 and ZnTiO3. Scanning electron microscope (SEM) observations show extensive large agglomeration in the samples. Transmission electron microscope (TEM) and electron diffraction (ED) examination results indicate that ZnTiO3 crystallites formed with a size of about 5 nm on the matrix of plate-like ZnO when calcined at 700 °C for 1 h. The calcination samples have acceptable absorbance at a wavelength of 400 nm, indicating that the zinc titanate precursor powders calcined at 700 °C for 1 h can be used as an UVA-attenuating agent. PMID:21541035

  3. An in situ vapour phase hydrothermal surface doping approach for fabrication of high performance Co3O4 electrocatalysts with an exceptionally high S-doped active surface.

    PubMed

    Tan, Zhijin; Liu, Porun; Zhang, Haimin; Wang, Yun; Al-Mamun, Mohammad; Yang, Hua Gui; Wang, Dan; Tang, Zhiyong; Zhao, Huijun

    2015-04-01

    A facile in situ vapour phase hydrothermal (VPH) surface doping approach has been developed for fabrication of high performance S-doped Co3O4 electrocatalysts with an unprecedentedly high surface S content (>47%). The demonstrated VPH doping approach could be useful for enrichment of surface active sites for other metal oxide electrocatalysts. PMID:25714902

  4. Quantification of diagenetic overprint processes deduced from fossil carbonate shells and laboratory-based hydrothermal alteration experiments

    NASA Astrophysics Data System (ADS)

    Griesshaber, Erika; Casella, Laura; Mavromatis, Vasileios; Dietzel, Martin; Immenhauser, Adrian; Schmahl, Wolfgang

    2016-04-01

    Benthic and nektonic marine biogenic carbonate archives represent the foundation of numerous studies aiming at reconstructions of past climate dynamics and environmental change. However, living organisms are not in thermodynamic equilibrium and create local chemical environments where physiologic processes such as biomineralization takes place. After the death of the organism the former physiologic disequilibrium conditions are not sustained any more and all biological tissues are altered by equilibration according to the surrounding environment: diagenesis. With increasing diagenetic alteration, the biogenic structure and fingerprint fades away and is replaced by inorganic features. Thus, recrystallization of organism-specific microstructure is a clear indicator for diagenetic overprint. Microstructural data, which mirror recrystallization, are of great value for interpreting geochemical proxies for paleo-environment reconstruction. Despite more than a century of research dealing with carbonate diagenesis, many of the controlling processes and factors are only understood in a qualitative manner. One of the main issues is that diagenetically altered carbonates are usually present as the product of a complex preceding diagenetic pathway with an unknown number of intermediate steps. In this contribution we present and discuss laboratory based alteration experiments with the aim to investigate time-series data sets in a controlled manner. We conducted hydrothermal alteration experiments with modern Arctica islandica (bivalvia) and Notosaria nigricans (brachiopoda) in order to mimic diagenetic overprint. We explore first the potential of electron backscattered diffraction (EBSD) measurements together with statistical data evaluation as a tool to quantify diagenetic alteration of carbonate skeletons. Subsequently, we compare microstructural patterns obtained from experimentally altered shell material with those of fossil specimens that have undergone variable degrees of

  5. Microwave assisted hydrothermal synthesis of Ag/AgCl/WO{sub 3} photocatalyst and its photocatalytic activity under simulated solar light

    SciTech Connect

    Adhikari, Rajesh; Gyawali, Gobinda; Sekino, Tohru; Wohn Lee, Soo

    2013-01-15

    Simulated solar light responsive Ag/AgCl/WO{sub 3} composite photocatalyst was synthesized by microwave assisted hydrothermal process. The synthesized powders were characterized by X-Ray Diffraction (XRD) spectroscopy, X-Ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), Diffuse Reflectance Spectroscopy (UV-Vis DRS), and BET surface area analyzer to investigate the crystal structure, morphology, chemical composition, optical properties and surface area of the composite photocatalyst. This photocatalyst exhibited higher photocatalytic activity for the degradation of rhodamine B under simulated solar light irradiation. Dye degradation efficiency of composite photocatalyst was found to be increased significantly as compared to that of the commercial WO{sub 3} nanopowder. Increase in photocatalytic activity of the photocatalyst was explained on the basis of surface plasmon resonance (SPR) effect caused by the silver nanoparticles present in the composite photocatalyst. Highlights: Black-Right-Pointing-Pointer Successful synthesis of Ag/AgCl/WO{sub 3} nanocomposite. Black-Right-Pointing-Pointer Photocatalytic experiment was performed under simulated solar light. Black-Right-Pointing-Pointer Nanocomposite photocatalyst was very active as compared to WO{sub 3} commercial powder. Black-Right-Pointing-Pointer SPR effect due to Ag nanoparticles enhanced the photocatalytic activity.

  6. Dynamics of active magmatic and hydrothermal systems at Taal Volcano, Philippines, from continuous GPS measurements

    NASA Astrophysics Data System (ADS)

    Bartel, Beth A.; Hamburger, Michael W.; Meertens, Chuck M.; Lowry, Anthony R.; Corpuz, Ernesto

    2003-10-01

    A dense network of continuous single- and dual-frequency GPS receivers at Taal Volcano, Philippines, reveals four major stages of volcanogenic deformation: deflation, from installation in June 1998 to December 1998; inflation, from January to March 1999; deflation, from April 1999 to February 2000; and inflation, from February to November 2000. The largest displacements occurred during the February-November 2000 period of inflation, which was characterized by ˜120 mm of uplift of the center of Volcano Island relative to the northern caldera rim at average rates up to 216 mm/yr. Deformation sources were modeled using a constrained least squares inversion algorithm. The source of 1999 deflation and inflation in 2000 were modeled as contractional and dilatational Mogi point sources centered at 4.2 and 5.2 km depth, respectively, beneath Volcano Island. The locations of the inflationary and deflationary sources are indistinguishable within the 95% confidence estimates. Modeling using a running 4-month time window from June 1999 to March 2001 reveals little evidence for source migration. We suggest that the two periods of inflation observed at Taal result from episodic intrusions of magma into a shallow reservoir centered beneath Volcano Island. Subsequent deflation may result from exsolution of magmatic fluids and/or gases into an overlying, unconfined hydrothermal system.

  7. Distributions and contents of the organic carbon and major heavy metals in aquatic environment surrounding the active submarine hydrothermal vent in the Northwestern Pacific

    NASA Astrophysics Data System (ADS)

    Lee, S.; Iizasa, K.; Shimoda, G.

    2009-12-01

    Since seafloor massive sulfides (SMSs) were firstly found in the central Red Sea in the middle of 20 century, many SMSs have been reported in the settings of oceanic ridges and island arcs. Although seafloor mining of SMSs is likely to be realized in the near future, there are some concerns on hydrothermal biota and ambient environments after seafloor mining. As biota and ambient environments will be affected by the mining of SMSs in direct, researches on the aquatic environment surrounding submarine hydrothermal vents are strongly needed. Because submarine hydrothermal activities are not stable and their life times are relatively short, it is conceivable that the aquatic environments in the hydrothermal field are different from the other site. Therefore, the regular and the long term monitoring in the aquatic environment of the hydrothermal field be strongly required for the more exact and detailed knowledge about the submarine hydrothermal environment. The distributions and the contents of organic carbon and major heavy metals in the seawater columns around hydrothermal fields will be discussed in the present study. In recent, the submarine hydrothermal activities are presumed as one of the factors causing the seasonal fluctuation in concentration of the total organic carbon in the subtropical Northwestern Pacific, but the practical demonstration about this was not carried out yet. The discussion about the distributions and the contents of major heavy metals in the seawater columns around hydrothermal fields will help to understanding of the diffusion through the plume discharged from hydrothermal vents to ambient environments. The samples were collected at and around the hydrothermal fields of the Bayonnaise Knoll caldera on the back-arc rift and the Myojin Knoll and Myojinsho in the Izu-Ogasawara arc, and the Izena cauldron in Okinawa Trough, during at summer in 2008 and 2009 throughout the HT08 cruise by Hakurei-maru and KT09-12 cruise by Tansei-maru. Seawater

  8. Microwave-assisted hydrothermal synthesis of marigold-like ZnIn2S4 microspheres and their visible light photocatalytic activity

    NASA Astrophysics Data System (ADS)

    Chen, Zhixin; Li, Danzhen; Xiao, Guangcan; He, Yunhui; Xu, Yi-Jun

    2012-02-01

    Marigold-like ZnIn2S4 microspheres were synthesized by a microwave-assisted hydrothermal method with the temperature ranging from 80 to 195 °C. X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen sorption analysis, UV-visible spectroscopy, scanning electron microscopy and transmission electron microscopy were used to characterize the products. It was found that the crystallographic structure and optical property of the products synthesized at different temperatures were almost the same. The degradation of methyl orange (MO) under the visible light irradiation has been used as a probe reaction to investigate the photocatalytic activity of as-prepared ZnIn2S4, which shows that the ZnIn2S4 sample synthesized at 195 °C shows the best photocatalytic activity for MO degradation. In addition, the photocatalytic activities of all the samples prepared by the microwave-assisted hydrothermal method are better than those prepared by a normal hydrothermal method, which could be attributed to the formation of more defect sites during the microwave-assisted hydrothermal treatment.

  9. Characterization of Active Hydrothermal Fluid Discharge and Recharge Zones in the Endeavour Axial Valley, Juan de Fuca Ridge

    NASA Astrophysics Data System (ADS)

    Salmi, M.; Hutnak, M.; Hearn, C.; Tivey, M.; Bjorklund, T.; Johnson, H. P.

    2012-12-01

    Sites where warm hydrothermal fluid vents at mid-ocean spreading centers are important for understanding a wide range of critical oceanic processes, but discharge zones represent a very limited portion of crustal fluid circulation pathways. Mapping the distribution of both fluid recharge and discharge sites within the axial valley provides wider insight into the larger scale features of hydrothermal circulation. Our 2011 survey consisted of 180 conductive heat flow stations within the Endeavour axial valley in roughly a 400 m by 1000 m grid, extending across the entire axial valley from the outer flank of the western boundary ridge to the eastern wall. Data acquisition used thermal blankets which measured conductive heat flow without requiring substantial sediment cover. A surprising result from this survey was zones of high heat flow extending across-strike, from the summit of the west valley wall across the entire axial valley floor. This trend was correlated with anomalously low seafloor magnetization from a near-bottom survey with the ROV JASON. Unexpectedly, over half of the axial valley floor was anomalously low at <50 mW m-2, while a small portion of the sites within the 'warm zone' had heat flow values >1 W m-2. The areas of extremely low heat flow values are interpreted as being directly influenced by recharge zones. Based on MCS estimates of partial melt depth below the axial valley and the assumption of no fluid advection, the purely conductive heat flow for this region should be on the order of 1 W m-2.The observation that conductive heat flux is suppressed over large portions of the axial valley floor suggests that heat transfer within the crustal sub-surface fluid reservoir is widespread, and impacts a large portion of our survey area. The largely bi-modal distribution of high and low conductive heat flow, coupled with geophysical and video observations, suggest current Endeavour axial valley crustal fluid circulation models need to be re-evaluated.

  10. MoMar-Demo at Lucky Strike. A near-real time multidisciplinary observatory of hydrothermal processes and ecosystems at the Mid-Atlantic Ridge

    NASA Astrophysics Data System (ADS)

    Cannat, M.; Sarradin, P.; Blandin, J.; Escartin, J.; Colaco, A.; MoMAR-Demo Scientific Party : Aron Michael, Aumont Virginie, Baillard Christian, Ballu Valérie, Barreyre Thibaut, Blandin Jérôme, Blin Alexandre, Boulart Cédric, Cannat Mathilde, Carval Thierry, Castillo Alain, Chavagnac Valérie, Coail Jean Yves, Colaço Ana, Corela Carlos, Courrier Christophe, Crawford Wayne, Cuvelier Daphné, Daniel Romuald, Dausse Denis, Escartin Javier, Fabrice Fontaine, Gabsi Taoufik, Gayet Nicolas, Guyader Gérard, Lallier François, Lecomte Benoit, Legrand Julien, Lino Silva, Miranda Miguel, Mitard Emmelyne, Pichavant Pascal, Pot Olivier, Reverdin Gilles, Rommevaux Céline, Sarradin Pierre Marie, Sarrazin Jozée, Tanguy Virginie, Villinger Heinrich, Zbinden Magali

    2011-12-01

    The MoMAR "Monitoring the Mid-Atlantic Ridge" project was initiated by InterRidge in 1998 to study the environmental instability resulting from active mid-ocean-ridge processes at hydrothermal vent fields south of the Azores. It then developped into a component of the ESONET (European Seafloor Observatory Network) and EMSO (European Multidisciplinary Subsea Observatory) programs, which coordinate eulerian observatory initiatives in the seas around Europe. MoMAR experiments have started in 2006 and address two main questions : What are the feedbacks between volcanism, deformation, seismicity, and hydrothermalism at a slow spreading mid-ocean ridge? and How does the hydrothermal ecosystem couple with these sub-seabed processes? The MoMAR-Demo project started in 2010 with partial support from ESONET. It has been implemented so far by 2 cruises of the RV Pourquoi Pas ? during which we successfully deployed (in 2010), and upgraded (in 2011) a near-realtime buoyed observatory system. The system comprises two Sea Monitoring Nodes (SeaMoN) at the seafloor, which are acoustically linked to a surface relay buoy (BoRel), ensuring satellite communication to a land base station in Brest (France). One SeaMoN node connects to a 3-components seismometer and an hydrophone for seismic event detection, and two pressure probes for geodetic measurements, and the other SeaMoN node connects to a video camera, a dissolved-iron analyzer, and an optode (oxygen and temperature probe) for ecological time studies. The BOREL transmission buoy is equiped with GPS (geodetic experiment and buoy location) and meteo station. Data and/or status signals from these sensors are transmitted every 6 hours, and put on line in compliance with the ESONET-EMSO data policy (temporary access through http://www.ifremer.fr/WC2en/allEulerianNetworks). The MoMAR-Demo system also allows for interactive connections and changes of data transmission rates on demand. It is nested in arrays of autonomous sensors (OBSs

  11. Near-bottom water column anomalies associated with active hydrothermal venting at Aeolian arc volcanoes, Tyrrhenian Sea, Italy

    NASA Astrophysics Data System (ADS)

    Walker, S. L.; Carey, S.; Bell, K. L.; Baker, E. T.; Faure, K.; Rosi, M.; Marani, M.; Nomikou, P.

    2012-12-01

    Hydrothermal deposits such as metalliferous sediments, Fe-Mn crusts, and massive sulfides are common on the submarine volcanoes of the Aeolian arc (Tyrrhenian Sea, Italy), but the extent and style of active hydrothermal venting is less well known. A systematic water column survey in 2007 found helium isotope ratios indicative of active venting at 6 of the 9 submarine volcanoes surveyed plus the Marsili back-arc spreading center (Lupton et al., 2011). Other plume indicators, such as turbidity and temperature anomalies were weak or not detected. In September 2011, we conducted five ROV Hercules dives at Eolo, Enarete, and Palinuro volcanoes during an E/V Nautilus expedition. Additionally, two dives explored the Casoni seamount on the southern flank of Stromboli where a dredge returned apparently warm lava in 2002 (Gamberi, 2006). Four PMEL MAPRs, with temperature, optical backscatter (particles), and oxidation-reduction potential (ORP) sensors, were arrayed along the lowermost 50 m of the Hercules/Argus cable during the dives to assess the relationship between seafloor observations and water column anomalies. Active venting was observed at each of the volcanoes visited. Particle anomalies were weak or absent, consistent with the 2007 CTD surveys, but ORP anomalies were common. Venting at Eolo volcano was characterized by small, localized patches of yellow-orange bacteria; living tubeworms were observed at one location. ORP anomalies (-1 to -22 mv) were measured at several locations, primarily along the walls of the crescent-shaped collapse area (or possible caldera) east of the Eolo summit. At Enarete volcano, we found venting fluids with temperatures up to 5°C above ambient as well as small, fragile iron-oxide chimneys. The most intense ORP anomaly (-140 mv) occurred at a depth of about 495 m on the southeast side of the volcano, with smaller anomalies (-10 to -20 mv) more common as the ROV moved upslope to the summit. At Palinuro volcano, multiple dives located

  12. Hydrothermal iron flux variability following rapid sea level changes

    NASA Astrophysics Data System (ADS)

    Middleton, Jennifer L.; Langmuir, Charles H.; Mukhopadhyay, Sujoy; McManus, Jerry F.; Mitrovica, Jerry X.

    2016-04-01

    Sea level changes associated with Pleistocene glacial cycles have been hypothesized to modulate melt production and hydrothermal activity at ocean ridges, yet little is known about fluctuations in hydrothermal circulation on time scales longer than a few millennia. We present a high-resolution record of hydrothermal activity over the past 50 ka using elemental flux data from a new sediment core from the Mir zone of the TAG hydrothermal field at 26°N on the Mid-Atlantic Ridge. Mir sediments reveal sixfold to eightfold increases in hydrothermal iron and copper deposition during the Last Glacial Maximum, followed by a rapid decline during the sea level rise associated with deglaciation. Our results, along with previous observations from Pacific and Atlantic spreading centers, indicate that rapid sea level changes influence hydrothermal output on mid-ocean ridges. Thus, climate variability may discretize volcanic processing of the solid Earth on millennial time scales and subsequently stimulate variability in biogeochemical interactions with volcanic systems.

  13. Adsorption of crystal violet with diatomite earth&carbon by a modification of hydrothermal carbonization process.

    PubMed

    Zhang, Yanzhuo; Li, Jun; Chen, Guanghui; Bian, Wei; Lu, Yun; Li, Wenjing; Zheng, Zhaoming; Cheng, Xiaojie

    2016-01-01

    The high colority and difficulty of decolorization are the most important tasks on printing and dyeing wastewater. This study investigates the ability of diatomite earth&carbon (DE&C) as an adsorbent to removal crystal violet (CV) from aqueous solutions. Fourier transform infrared spectroscopy results indicate the importance of functional groups during the adsorption of CV. The obtained N2 adsorption-desorption isotherm values accord with well IUPAC type II. Our calculations determined a surface area of 73.15 m(2) g(-1) for DE&C and an average pore diameter of 10.56 nm. Equilibrium data of the adsorption process fitted very well to the Langmuir model (R(2) > 0.99). The results of kinetics study showed that the pseudo-second-order model fitted to the experimental data well. The thermodynamic parameters were also evaluated. ΔH° <0, ΔS° > 0 and ΔG° < 0 demonstrated that the adsorption process was spontaneous and exothermic for dye. Furthermore the positive value of ΔS° reflected good affinity of the CV dye. PMID:27003089

  14. Adsorption of crystal violet with diatomite earth&carbon by a modification of hydrothermal carbonization process.

    PubMed

    Zhang, Yanzhuo; Li, Jun; Chen, Guanghui; Bian, Wei; Lu, Yun; Li, Wenjing; Zheng, Zhaoming; Cheng, Xiaojie

    2016-01-01

    The high colority and difficulty of decolorization are the most important tasks on printing and dyeing wastewater. This study investigates the ability of diatomite earth&carbon (DE&C) as an adsorbent to removal crystal violet (CV) from aqueous solutions. Fourier transform infrared spectroscopy results indicate the importance of functional groups during the adsorption of CV. The obtained N2 adsorption-desorption isotherm values accord with well IUPAC type II. Our calculations determined a surface area of 73.15 m(2) g(-1) for DE&C and an average pore diameter of 10.56 nm. Equilibrium data of the adsorption process fitted very well to the Langmuir model (R(2) > 0.99). The results of kinetics study showed that the pseudo-second-order model fitted to the experimental data well. The thermodynamic parameters were also evaluated. ΔH° <0, ΔS° > 0 and ΔG° < 0 demonstrated that the adsorption process was spontaneous and exothermic for dye. Furthermore the positive value of ΔS° reflected good affinity of the CV dye.

  15. Hydrothermal ore-forming processes in the light of studies in rock- buffered systems: II. Some general geologic applications

    USGS Publications Warehouse

    Hemley, J.J.; Hunt, J.P.

    1992-01-01

    The experimental metal solubilities for rock-buffered hydrothermal systems provide important insights into the acquisition, transport, and deposition of metals in real hydrothermal systems that produced base metal ore deposits. Water-rock reactions that determine pH, together with total chloride and changes in temperature and fluid pressure, play significant roles in controlling the solubility of metals and determining where metals are fixed to form ore deposits. Deposition of metals in hydrothermal systems occurs where changes such as cooling, pH increase due to rock alteration, boiling, or fluid mixing cause the aqueous metal concentration to exceed saturation. Metal zoning results from deposition occurring at successive saturation surfaces. Zoning is not a reflection simply of relative solubility but of the manner of intersection of transport concentration paths with those surfaces. Saturation surfaces will tend to migrate outward and inward in prograde and retrograde time, respectively, controlled by either temperature or chemical variables. -from Authors

  16. Crater lake and post-eruption hydrothermal activity, El Chichón Volcano, Mexico

    USGS Publications Warehouse

    Casadevall, Thomas J.; de la Cruz-Reyna, Servando; Rose, William I.; Bagley, Susan; Finnegan, David L.; Zoller, William H.

    1984-01-01

    Explosive eruptions of Volcán El Chichón in Chiapas, Mexico on March 28 and April 3–4, 1982 removed 0.2 km3 of rock to form a 1-km-wide 300-m-deep summit crater. By late April 1982 a lake had begun to form on the crater floor, and by November 1982 it attained a maximum surface area of 1.4 × 105 m2 and a volume of 5 × 106 m3. Accumulation of 4–5 m of rainfall between July and October 1982 largely formed the lake. In January 1983, temperatures of fumaroles on the crater floor and lower crater walls ranged from 98 to 115°C; by October 1983 the maximum temperature of fumarole emissions was 99°C. In January 1983 fumarole gas emissions were greater than 99 vol. % H2O with traces of CO2, SO2, and H2S. The water of the lake was a hot (T = 52–58°C), acidic (pH = 0.5), dilute solution (34,046 mg L−1 dissolved solids; Cl/S = 20.5). Sediment from the lake contains the same silicate minerals as the rocks of the 1982 pyroclastic deposits, together with less than 1% of elemental sulfur. The composition and temperature of the lake water is attributed to: (1) solution of fumarole emissions; (2) reaction of lake water with hot rocks beneath the lake level; (3) sediments washed into the lake from the crater walls; (4) hydrothermal fluids leaching sediments and formational waters in sedimentary rocks of the basement; (5) evaporation; and (6) precipitation.

  17. Cavitational hydrothermal oxidation: A new remediation process. Annual progress report, September 1996--August 1997

    SciTech Connect

    Suslick, K.S.

    1997-11-21

    'During the past year, the authors have continued to make substantial scientific progress on the understanding of cavitation phenomena in aqueous media and applications of cavitation to remediation processes. The efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions. In order to gain further understanding of the conditions present during cavitation, the author has continued his studies of sonoluminescence. He has made recent breakthroughs in the use of emission spectroscopy for temperature and pressure measurement of cavitation events, which he expects to publish shortly. He has been able to measure for the first time the temperature of cavitation in water during multi-bubble cavitation in the presence of aromatic hydrocarbons. The emission from excited states of C{sub 2} in water gives temperatures that are consistent with adiabatic compressional heating, with maximum temperatures of 4,300 K. Prior measurements of cavitation temperatures in low vapor pressure nonaqueous media gave somewhat higher temperatures of 5,000 K. This work lays permanently to rest exotic mechanisms for cavitational chemistry, at least for cavitation fields.'

  18. Cavitational hydrothermal oxidation: A new remediation process. 1998 annual progress report

    SciTech Connect

    Suslick, K.S.

    1998-06-01

    'The primary goal is to develop a quantitative understanding of cavitation phenomena in aqueous media and the development of applications of cavitation to remediation processes. Efforts have focused on three separate areas: sonoluminescence as a probe of conditions created during cavitational collapse in aqueous media, the use of cavitation for remediation of contaminated water, and an addition of the use of ultrasound in the synthesis of novel heterogeneous catalysts for hydrodehalogenation of halocarbons under mild conditions. This report summarizes work after one year of a three year project. In order to gain further understanding of the conditions present during cavitation, the author has continued his studies of sonoluminescence. He has made recent breakthroughs in the use of emission spectroscopy for temperature and pressure measurement of cavitation events, which he expects to publish shortly. He has been able to measure for the first time the temperature of cavitation in water during multi-bubble cavitation in the presence of aromatic hydrocarbons. The emission from excited states of C{sub 2} in water gives temperatures that are consistent with adiabatic compressional heating, with maximum temperatures of 4,300 K. Prior measurements of cavitation temperatures in low vapor pressure nonaqueous media gave somewhat higher temperatures of 5,000 K. This work lays permanently to rest exotic mechanisms for cavitational chemistry, at least for cavitation fields.'

  19. Preparation of briquettes from the Golden Horn bottom sediments by hydro-thermal agglomeration process.

    PubMed

    Celik, Ozlem; Elbeyli, iffet Yakar

    2004-04-01

    The Golden Horn (GH) sediments, which consist mainly of clay, organic substances and heavy metals, are formed with the contribution of industrial and domestic wastes released in the Golden Horn Estuary. On account of their mineralogical and chemical composition, these sediments may be regarded as a suitable raw material for briquette production. In this study, the utilization of GH dredged bottom sediments was investigated for preparation of briquettes. Dried GH sediments were mixed with lime and sand in different percentages, moulded at various squeezing pressures and hardened under several steam pressure values by autoclaving. The briquettes produced through these different process conditions were tested for compressive strength according to the Turkish standards (TS705). It was found that variations in compressive strength were dependent on the amount of lime (Ca(OH)2) and sand (SiO2) added. Results show that the compressive strength increased with increasing lime and decreasing sand in the mixtures prepared for briquettes. It is concluded that briquettes with a compressive strength value of 294 kgf cm(-2) can be produced. This allows the GH sediments to be taken into account as a raw material in brick production, as far as compressive strength requirements are concerned. This possibility may represent an important way either for reducing environmental pollution or for recycling waste materials in industrial applications.

  20. Deep Crustal Magma Conduits, Diabase Internal Structure, and Coupled Hydrothermal Processes in Mesozoic Basins of Eastern North America

    NASA Astrophysics Data System (ADS)

    Ryan, M. P.; Ingerov, A.; Daniels, D. L.; Carr, P. M.; Elliott, G.; Fox, L.; Pierce, H. A.; Sutphin, D. M.

    2004-05-01

    Gettysburg basin has been interpreted from wavelength-filtered aeromagnetic data processing. Lopoliths may be solitary, intersecting, or ``nested'' in concentrically-arranged groups. Collectively, the Gettysburg basin is intruded by some 8 major diabase complexes. Contemporary compartmentalization and fracture flow. Relatively low permeability diabase (10-17}hydrothermal processes. Finite element simulations of hydrothermal flow around and through diabase-compartmentalized basins define the geometric relations promoting subsurface fluid flow and include the roles played by sheets, lopoliths, and en-echelon--arranged dike complexes in regulating aqueous fluid leakage across basins.

  1. Comparative study of photocatalytic activities of hydrothermally grown ZnO nanorod on Si(001) wafer and FTO glass substrates.

    PubMed

    Jeon, Eun Hee; Yang, Sena; Kim, Yeonwoo; Kim, Namdong; Shin, Hyun-Joon; Baik, Jaeyoon; Kim, Hyun Sung; Lee, Hangil

    2015-12-01

    ZnO nanorods have been grown on Si(001) wafer and fluorine-doped tin oxide (FTO) glass substrates for 1 and 4 h with the hydrothermal methods. The morphologies and photocatalytic activities of the ZnO nanorods were found to depend on the substrates. We investigated their properties by using spectroscopic analysis and demonstrated that the shape of nanorod and the ratios of external defects can be controlled by varying the substrates. Our experiments revealed that the nanorods grown on Si(001) have a single-crystalline wurtzite structure with (002) facets and that the number of surface oxygen defects increases with their length as the growth time increases. The nanorods grown on Si(001) have different facets, in particular wider (002) facets, and a higher ratio of the oxygen defect than the nanorods on FTO glass substrate. Moreover, the photocatalytic activities with respect to 2-aminothiophenol (2-ATP) of these nanorods were investigated with high-resolution photoemission spectroscopy (HRPES). We demonstrated that their photocatalytic activity is influenced by the ratios of surface oxygen defects, which varies with the substrate surface.

  2. Comparative study of photocatalytic activities of hydrothermally grown ZnO nanorod on Si(001) wafer and FTO glass substrates

    NASA Astrophysics Data System (ADS)

    Jeon, Eun Hee; Yang, Sena; Kim, Yeonwoo; Kim, Namdong; Shin, Hyun-Joon; Baik, Jaeyoon; Kim, Hyun Sung; Lee, Hangil

    2015-09-01

    ZnO nanorods have been grown on Si(001) wafer and fluorine-doped tin oxide (FTO) glass substrates for 1 and 4 h with the hydrothermal methods. The morphologies and photocatalytic activities of the ZnO nanorods were found to depend on the substrates. We investigated their properties by using spectroscopic analysis and demonstrated that the shape of nanorod and the ratios of external defects can be controlled by varying the substrates. Our experiments revealed that the nanorods grown on Si(001) have a single-crystalline wurtzite structure with (002) facets and that the number of surface oxygen defects increases with their length as the growth time increases. The nanorods grown on Si(001) have different facets, in particular wider (002) facets, and a higher ratio of the oxygen defect than the nanorods on FTO glass substrate. Moreover, the photocatalytic activities with respect to 2-aminothiophenol (2-ATP) of these nanorods were investigated with high-resolution photoemission spectroscopy (HRPES). We demonstrated that their photocatalytic activity is influenced by the ratios of surface oxygen defects, which varies with the substrate surface.

  3. Production of xylitol and tetrahydrofurfuryl alcohol from xylan in napier grass by a hydrothermal process with phosphorus oxoacids followed by aqueous phase hydrogenation.

    PubMed

    Takata, Eri; Tsuruoka, Tatsushi; Tsutsumi, Ken; Tsutsumi, Yuji; Tabata, Kenji

    2014-09-01

    The production of xylitol and tetrahydrofurfuryl alcohol (THFA) from napier grass was studied using two steps: a hydrothermal process with phosphorus oxoacids followed by aqueous phase hydrogenation with Pd/C. Xylose obtained from the napier grass by the hydrothermal treatment with 3.0 wt% phosphorous acid was subsequently converted into xylitol at 51.6% yield of the xylan in napier grass by hydrogenation with 5.0 wt% Pd/C. The furfural produced from napier grass with a 3.0 wt% phosphoric acid treatment was also directly subjected to the hydrogenation as a hydrolysate to yield 41.4% THFA based on the xylan in napier grass. The yields of xylitol and THFA obtained by hydrogenation using the napier grass hydrolysate containing xylose or furfural were almost the same as those of hydrogenation using commercial materials. To our knowledge, this is the first report on the production of THFA in high yield by hydrogenation directly from biomass hydrolysate.

  4. Comparative phylogeography among hydrothermal vent species along the East Pacific Rise reveals vicariant processes and population expansion in the South.

    PubMed

    Plouviez, S; Shank, T M; Faure, B; Daguin-Thiebaut, C; Viard, F; Lallier, F H; Jollivet, D

    2009-09-01

    The use of sequence polymorphism from individual mitochondrial genes to infer past demography has recently proved controversial because of the recurrence of selective sweeps acting over genes and the need for unlinked multilocus data sets. However, comparative analyses using several species for one gene and/or multiple genes for one species can serve as a test for potential selective effects and clarify our understanding of historical demographic effects. This study compares nucleotide polymorphisms in mitochondrial cytochrome oxidase I across seven deep-sea hydrothermal vent species that live along the volcanically active East Pacific Rise. Approximate Bayesian Computation (ABC) method, developed to trace shared vicariant events across species pairs, indicates the occurrence of two across species divergence times, and suggests that the present geographical patterns of genetic differentiation may be explained by two periods of significant population isolation. The oldest period dates back 11.6 Ma and is associated with the vent limpet Lepetodrilus elevatus, while the most recent period of isolation is 1.3 Ma, which apparently affected all species examined and coincides with a transition zone across the equator. Moreover, significant negative Tajima's D and star-like networks were observed for all southern lineages, suggesting that these lineages experienced a concomitant demographic and geographical expansion about 100 000-300 000 generations ago. This expansion may have initiated from a wave of range expansions during the secondary colonization of new sites along the Southern East Pacific Rise (founder effects below the equator) or recurrent bottleneck events because of the increase of eruptive phases associated with the higher spreading rates of the ridge in this region.

  5. Elucidating some issues regarding the synthesis of superparamagnetic-like single crystalline micrometric Fe3O4 during the hydrothermal process

    NASA Astrophysics Data System (ADS)

    Kiss, Mihaela Luminita; Chirita, Marius; Mihaila, Alexandru Ionut Chirita; Beljung, Corina Ana; Niznansky, Daniel; Savii, Cecilia

    2015-12-01

    By hydrothermal decomposition of the Fe-EDTA complex, at 230°C, after 38 h of high -pressure treatment time, magnetite octahedrons with micrometric dimensions (15-45 µm) were obtained. Unusual and notable for these crystallites is the very small hysteresis surface, indicating a superparamagnetic-like behavior at micrometer scale, which means that the agglomeration of these crystallites is avoided after the removal of the magnetic field. This behavior can be correlated with a low level of imperfections in magnetite octahedrons, involving a low level of internal stresses, which leads to coercivity decreasing. The large dispersion in the crystallite axes is consistent with low remanence. We assumed that these attributes are related to the hydrothermal crystal growth process. To elucidate some issues regarding the magnetite crystallites development during the hydrothermal process, a careful observation of occurring intermediate phases by optical and SEM microscopy has been performed. Also the purity of the ferrous carbonate/magnetite mixture was analyzed by FTIR and Mössbauer spectroscopy

  6. Numerical Modeling of Thermal-Geochemical Processes in the Hydrothermal System of Pantelleria Island, Italy

    NASA Astrophysics Data System (ADS)

    Bellani, S.; Gherardi, F.

    2009-12-01

    The island of Pantelleria, located in the Sicily Channel, Central Mediterranean, (about 100 km from Sicily and 70 km from Tunisia), represents the emergent part of a quiescent Quaternary volcano. It has been affected by an intense recent volcano-tectonic activity. The rocks outcropping on the island are mainly lavas and pyroclastic deposits, mostly represented by pantellerites and trachytes. Surface geothermal manifestations are diffused in Pantelleria, with fumaroles, mofettes and hot springs with temperatures up to 98 °C. Since the 60s’, a number of pre-feasibility studies was carried out on the island, which underwent an extensive geothermal exploration during the early 90s’. The results of the exploration revealed a very promising zone in the southern part of the island, where the main geothermal manifestations are concentrated. Temperatures above 250°C were measured in exploratory drillings down to 1100 m b.g.l. (well PPT1). The intrusion of pure seawater likely occurs throughout the island, and deep geothermal reservoir recharge appears to be predominantly of marine origin, though contributions from meteoric water are also possible. A conceptual model of the system has been set up on the basis of a wide set of geological, geophysical and geochemical data obtained during the surveys. The TOUGHREACT simulator was used for the water-rock reaction simulations. A plug-flow model has been used to perform non-isothermal calculations. Boundary thermal conditions have been calibrated according to heat flow measurements and well temperature data. Water-rock interactions have been evaluated in successive steps. First, the saturation states of minerals of sampled geothermal fluids were computed at reservoir temperatures to determine the mineral phases which would likely be dissolving or precipitating. The composition of “synthetic”, nearly-equilibrated waters likely occurring at depth within the reservoir has been then numerically reconstructed. Next, the

  7. Preliminary results of trace elements mobility in soils and plants from the active hydrothermal area of Nisyros island (Greece)

    NASA Astrophysics Data System (ADS)

    Daskalopoulou, Kyriaki; Calabrese, Sergio; Milazzo, Silvia; Brusca, Lorenzo; D'Alessandro, Walter; Kyriakopoulos, Konstantinos; Tassi, Franco; Parello, Francesco

    2014-05-01

    Trace elements, i.e. chemical constituents of rocks with concentration <1000 ppm, play a structural role in the organisms and use proteins as a carrier to their target site. Their toxicity depends on their concentration, speciation and reactions with other elements. In volcanic environments, significant amounts of trace elements discharged from gas emissions, contribute to produce air particulate. Nisyros Island is a stratovolcano located at the South Aegean active Volcanic Arc. Intense hydrothermal activity characterise the Lakki caldera. In particular, the fumaroles located in the craters of Stefanos, Kaminakia, Lofos Dome and the area comprising Phlegeton, Polyvotes Micros and Polyvotes Megalos discharge hydrothermal fluids rich in H2O (91- 99%), SO2 and H2S. Their temperatures are almost 100o C and H2S is highly abundant accounting for 8-26 % of the released dry gas phase. On June 2013, during a multidisciplinary field trip on Nisyros island, 39 samples of top soils and 31 of endemic plants (Cistus Creticus and Salvifolius and Erica Arborea and Manipuliflora) were collected in the caldera area, with the aim to investigate the distribution of concentrations of trace elements related to the contribution of deep originated fluids. Moreover, one sample of plant and soil was collected outside the caldera as local background, for comparison. All the soil samples were powdered avoiding metal contamination and they were extracted twice, using HNO3 + HCl for one extraction (closed microwave digestion) and ultrapure de- ionized water for the other one (leaching extraction). The leaves of plants were gently isolated, dried and powdered for acid microwave extraction (HNO3 + H2O2). All the solutions were analysed for major and trace elements contents by using ionic chromatography (IC) and inductively plasma spectrometry (ICP-MS and ICP-OES). The preliminary results showed high enrichment of many trace elements both in plant and soils respect to the local background, in

  8. Aqueous volatiles in hydrothermal fluids from the Main Endeavour Field, northern Juan de Fuca Ridge: temporal variability following earthquake activity

    NASA Astrophysics Data System (ADS)

    Seewald, Jeffrey; Cruse, Anna; Saccocia, Peter

    2003-12-01

    The Main Endeavour Field, northern Juan de Fuca Ridge, experienced intense seismic activity in June 1999. Hydrothermal vent fluids were collected from sulfide structures in September 1999 and July 2000 and analyzed for the abundance of H2, H2S, CH4, CO2, NH3, Mg and Cl to document temporal and spatial changes following the earthquakes. Dissolved concentrations of CO2, H2, and H2S increased dramatically in the September 1999 samples relative to pre-earthquake abundances, and subsequently decreased during the following year. In contrast, dissolved NH3 and CH4 concentrations in 1999 and 2000 were similar to or less than pre-earthquake values. Aqueous Cl abundances showed large decreases immediately following the earthquakes followed by increases to near pre-earthquake values. The abundances of volatile species at the Main Endeavour Field were characterized by strong inverse correlations with chlorinity. Phase separation can account for 20-50% enrichments of CO2, CH4, and NH3 in low-chlorinity fluids, while temperature- and pressure-dependent fluid-mineral equilibria at near-critical conditions are responsible for order of magnitude greater enrichments in dissolved H2S and H2. The systematic variation of dissolved gas concentrations with chlorinity likely reflects mixing of a low-chlorinity volatile-enriched vapor generated by supercritical phase separation with a cooler gas-poor hydrothermal fluid of seawater chlorinity. Decreased abundances of sediment-derived NH3 and CH4 in 1999 indicate an earthquake-induced change in subsurface hydrology. Elevated CO2 abundances in vent fluids collected in September 1999 provide evidence that supports a magmatic origin for the earthquakes. Temperature-salinity relationships are consistent with intrusion of a shallow dike and suggest that the earthquakes were associated with movement of magma beneath the ridge crest. These data demonstrate the large and rapid response of chemical fluxes at mid-ocean ridges to magmatic activity and

  9. Drill core-based facies reconstruction of a deep-marine felsic volcano hosting an active hydrothermal system (Pual Ridge, Papau New Guinea, ODP Leg 193)

    NASA Astrophysics Data System (ADS)

    Paulick, H.; Vanko, D. A.; Yeats, C. J.

    2004-02-01

    Pual Ridge is a deep-marine, felsic volcanic edifice in the eastern Manus back-arc basin (Papua New Guinea) with an estimated volume of ˜6 to 9 km 3. It is 1-1.5 km wide, 20 km long and rises 500-600 m above the surrounding ocean floor. The active PACMANUS hydrothermal field on the crest of Pual Ridge at 1640-1690 m below sea level was the target of Ocean Drilling Program Leg 193. Variably altered dacite lavas have been recovered from the subsurface of a low-T discharge site (Snowcap) and a high-T black smoker site (Roman Ruins) reaching a maximum depth of 380 m below seafloor (mbsf). Volcanic facies interpretation of these cores is difficult due to incomplete recovery and widespread pseudoclastic textures generated by fracturing and multi-phase, incomplete fluid-dacite interaction. However, distinction of genuine volcaniclastic facies and facies with alteration-related clastic appearance is important in order to define paleo-seafloor positions within the volcanic stratigraphy, that may be prospective for massive sulfide mineralization. This has been accomplished using remnant primary characteristics indicative of transportation such as polymictic composition, grading or textural evidence for differential movement of individual clasts. Three phases of volcanic activity can be distinguished and a proximal facies association dominated by coherent facies of dacite lavas exists below Snowcap. At Roman Ruins, a medial facies association consists of lava flows with about equal proportions of coherent and volcaniclastic facies. Endogenous growth was an important process during lava flow emplacement and groundmass textures such as perlite, flow banding and spherulites indicate that cooling rates were variable, locally allowing for high-temperature devitrification. A tube pumice breccia unit is interpreted as the resedimented facies of a quench fragmented, highly vesicular dacite lava carapace. Sulfide accumulations in the subsurface are restricted to Roman Ruins

  10. Multiple episodes of hydrothermal activity and epithermal mineralization in the southwestern Nevada volcanic field and their relations to magmatic activity, volcanism and regional extension

    SciTech Connect

    Weiss, S.I.; Noble, D.C.; Jackson, M.C.

    1994-12-31

    Volcanic rocks of middle Miocene age and underlying pre-Mesozoic sedimentary rocks host widely distributed zones of hydrothermal alteration and epithermal precious metal, fluorite and mercury deposits within and peripheral to major volcanic and intrusive centers of the southwestern Nevada volcanic field (SWNVF) in southern Nevada, near the southwestern margin of the Great Basin of the western United States. Radiometric ages indicate that episodes of hydrothermal activity mainly coincided with and closely followed major magmatic pulses during the development of the field and together spanned more than 4.5 m.y. Rocks of the SWNVF consist largely of rhyolitic ash-flow sheets and intercalated silicic lava domes, flows and near-vent pyroclastic deposits erupted between 15.2 and 10 Ma from vent areas in the vicinity of the Timber Mountain calderas, and between about 9.5 and 7 Ma from the outlying Black Mountain and Stonewall Mountain centers. Three magmatic stages can be recognized: the main magmatic stage, Mountain magmatic stage (11.7 to 10.0 Ma), and the late magmatic stage (9.4 to 7.5 Ma).

  11. Career management: an active process.

    PubMed

    Mackowiak, J; Eckel, F M

    1985-03-01

    The self-assessment, goal-setting, and career-planning techniques of career management are discussed, and the organization's role in career management is discussed. Career management is a planned process, initiated and carried out by an individual with the assistance of others. Because work and nonwork activities are so interrelated, career and life management planning can maximize a pharmacist's personal success. The career- and life-management process begins with the development of a personal definition of success. A self-assessment must be made of one's values, needs, interests, and activities. The next step of the process involves setting goals and establishing a plan or strategy to achieve them. Establishing a career path requires researching alternate career goals. Career competencies are identified that can increase an employee's chances of success. The employer shares the responsibility for career development through coaching, job structuring, and keeping the employee aware of constraints. Through the integration of the roles of the individual and the organization in the career-management process, employees can optimize their contribution to an organization. Pharmacists can successfully manage their careers by applying the techniques of self-assessment, goal setting, and career planning. PMID:3985018

  12. Template-free synthesis of ZnWO{sub 4} powders via hydrothermal process in a wide pH range

    SciTech Connect

    Hojamberdiev, Mirabbos; Zhu, Gangqiang; Xu, Yunhua

    2010-12-15

    ZnWO{sub 4} powders with different morphologies were fabricated through a template-free hydrothermal method at 180 {sup o}C for 8 h in a wide pH range. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-visible and luminescence spectrophotometers were applied to study the effects of pH values on crystallinity, morphology, optical and luminescence properties. The XRD results showed that the WO{sub 3} + ZnWO{sub 4}, ZnWO{sub 4}, and ZnO phases could form after hydrothermal processing at 180 {sup o}C for 8 h with the pH values of 1, 3-11, and 13, respectively. The SEM and TEM observation revealed that the morphological transformation of ZnWO{sub 4} powders occurred with an increase in pH values as follows: star anise-, peony-, and desert rose-like microstructures and soya bean- and rod-like nanostructures. The highest luminescence intensity was found to be in sample consisting of star anise-like crystallites among all the samples due to the presence of larger particles with high crystallinity resulted from the favorable pH under the current hydrothermal conditions.

  13. The Timber Mountain magmato-thermal event: An intense widespread culmination of magmatic and hydrothermal activity at the southwestern Nevada volcanic field

    SciTech Connect

    Jackson, M.R. Jr.

    1988-05-01

    Eruption of the Rainier Mesa and Ammonia Tanks Members Timber Mountain Tuff at about 11.5 and 11.3 Ma, respectively, resulted in formation of the timber Mountain (TM) caldera; new K-Ar ages show that volcanism within and around the TM caldera continued for about 1 m.y. after collapse. Some TM age magmatic activity took place west and southeast of the TM caldera in the Beatty -- Bullfrog Hills and Shoshone Mountain areas, suggesting that volcanic activity at the TM caldera was an intense expression of an areally extensive magmatic system active from about 11.5 to 10Ma. Epithermal Au-Ag, Hg and fluorite mineralization and hydrothermal alteration are found in both within and surrounding the Timber Mountain -- Oasis Valley caldera complex. New K-Ar ages date this hydrothermal activity between about 13 and 10 Ma, largely between about 11.5 and 10 Ma, suggesting a genetic relation of hydrothermal activity to the TM magmatic system.

  14. Activity of antioxidant enzymes in response to atmospheric pressure induced physiological stress in deep-sea hydrothermal vent mussel Bathymodiolus azoricus.

    PubMed

    Martins, Inês; Romão, Célia V; Goulart, Joana; Cerqueira, Teresa; Santos, Ricardo S; Bettencourt, Raul

    2016-03-01

    Deep sea hydrothermal Bathymodiolus azoricus mussels from Portuguese EEZ Menez Gwen hydrothermal field possess the remarkable ability to overcome decompression and survive successfully at atmospheric pressure conditions. We investigated the potential use of antioxidant defense enzymes in mussel B. azoricus as biomarkers of oxidative stress induced by long term acclimatization to atmospheric pressure conditions. Mussels collected at Menez Gwen hydrothermal field were acclimatized for two weeks in three distinct conditions suitable of promoting physiological stress, (i) in plain seawater for concomitant endosymbiont bacteria loss, (ii) in plain seawater under metal iron exposure, (iii) constant bubbling methane and pumped sulfide for endosymbiont bacteria survival. The enzymatic activities of superoxide dismutase (SOD), catalase (CAT), and iron storage proteins in addition to electrophoretic profiles were examined in vent mussel gills and digestive gland. Gills showed approximately 3 times more SOD specific activity than digestive glands. On the other hand, digestive glands showed approximately 6 times more CAT specific activity than gills. Iron storage proteins were identified in gill extracts from all experimental conditions mussels. However, in digestive gland extracts only fresh collected mussels and after 2 weeks in FeSO4 showed the presence of iron storage proteins. The differences between SOD, CAT specific activities and the presence of iron storage proteins in the examined tissues reflect dissimilar metabolic and antioxidant activities, as a result of tissue specificities and acclimatization conditions influences on the organism. PMID:26790096

  15. On the Interaction of a Vigorous Hydrothermal System with an Active Magma Chamber: The Puna Magma Chamber, Kilauea East Rift, Hawaii

    NASA Astrophysics Data System (ADS)

    Gregory, R. T.; Marsh, B. D.; Teplow, W.; Fournelle, J.

    2009-12-01

    The extent of the interaction between hydrothermal systems and active magma chambers has long been of fundamental interest to the development of ore deposits, cooling of magma chambers, and dehydration of the subducting lithosphere. As volatiles build up in the residual magma in the trailing edge of magmatic solidification fronts, is it possible that volatiles are transferred from the active magma to the hydrothermal system and vice versa? Does the external fracture front associated with vigorous hydrothermal systems sometimes propagate into the solidification front, facilitating volatile exchange? Or is the magma always sealed at temperatures above some critical level related to rock strength and overpressure? The degree of hydrothermal interaction in igneous systems is generally gauged in post mortem studies of δ18O and δD, where it has been assumed that a fracture front develops about the magma collapsing inward with cooling. H.P. Taylor and D. Norton's (1979; J. Petrol.)seminal work inferred that rocks are sealed with approach to the solidus and there is little to no direct interaction with external volatiles in the active magma. In active lava lakes a fracture front develops in response to thermal contraction of the newly formed rock once the temperature drops to ~950°C (Peck and Kinoshita,1976;USGS PP935A); rainfall driven hydrothermal systems flash to steam near the 100 °C isotherm in the solidified lake and have little effect on the cooling history (Peck et al., 1977; AJS). Lava lakes are fully degassed magmas and until the recent discovery of the Puna Magma Chamber (Teplow et al., 2008; AGU) no active magma was known at sufficiently great pressure to contain original volatiles. During the course of routine drilling of an injection well at the Puna Geothermal Venture (PGV) well-field, Big Island, Hawaii, a 75-meter interval of diorite containing brown glass inclusions was penetrated at a depth of 2415 m, continued drilling to 2488 m encountered a melt

  16. Linking geology, fluid chemistry, and microbial activity of basalt- and ultramafic-hosted deep-sea hydrothermal vent environments.

    PubMed

    Perner, M; Hansen, M; Seifert, R; Strauss, H; Koschinsky, A; Petersen, S

    2013-07-01

    Hydrothermal fluids passing through basaltic rocks along mid-ocean ridges are known to be enriched in sulfide, while those circulating through ultramafic mantle rocks are typically elevated in hydrogen. Therefore, it has been estimated that the maximum energy in basalt-hosted systems is available through sulfide oxidation and in ultramafic-hosted systems through hydrogen oxidation. Furthermore, thermodynamic models suggest that the greatest biomass potential arises from sulfide oxidation in basalt-hosted and from hydrogen oxidation in ultramafic-hosted systems. We tested these predictions by measuring biological sulfide and hydrogen removal and subsequent autotrophic CO2 fixation in chemically distinct hydrothermal fluids from basalt-hosted and ultramafic-hosted vents. We found a large potential of microbial hydrogen oxidation in naturally hydrogen-rich (ultramafic-hosted) but also in naturally hydrogen-poor (basalt-hosted) hydrothermal fluids. Moreover, hydrogen oxidation-based primary production proved to be highly attractive under our incubation conditions regardless whether hydrothermal fluids from ultramafic-hosted or basalt-hosted sites were used. Site-specific hydrogen and sulfide availability alone did not appear to determine whether hydrogen or sulfide oxidation provides the energy for primary production by the free-living microbes in the tested hydrothermal fluids. This suggests that more complex features (e.g., a combination of oxygen, temperature, biological interactions) may play a role for determining which energy source is preferably used in chemically distinct hydrothermal vent biotopes.

  17. Identification and activity of acetate-assimilating bacteria in diffuse fluids venting from two deep-sea hydrothermal systems.

    PubMed

    Winkel, Matthias; Pjevac, Petra; Kleiner, Manuel; Littmann, Sten; Meyerdierks, Anke; Amann, Rudolf; Mußmann, Marc

    2014-12-01

    Diffuse hydrothermal fluids often contain organic compounds such as hydrocarbons, lipids, and organic acids. Microorganisms consuming these compounds at hydrothermal sites are so far only known from cultivation-dependent studies. To identify potential heterotrophs without prior cultivation, we combined microbial community analysis with short-term incubations using (13)C-labeled acetate at two distinct hydrothermal systems. We followed cell growth and assimilation of (13)C into single cells by nanoSIMS combined with fluorescence in situ hybridization (FISH). In 55 °C-fluids from the Menez Gwen hydrothermal system/Mid-Atlantic Ridge, a novel epsilonproteobacterial group accounted for nearly all assimilation of acetate, representing the first aerobic acetate-consuming member of the Nautiliales. In contrast, Gammaproteobacteria dominated the (13) C-acetate assimilation in incubations of 37 °C-fluids from the back-arc hydrothermal system in the Manus Basin/Papua New Guinea. Here, 16S rRNA gene sequences were mostly related to mesophilic Marinobacter, reflecting the high content of seawater in these fluids. The rapid growth of microorganisms upon acetate addition suggests that acetate consumers in diffuse fluids are copiotrophic opportunists, which quickly exploit their energy sources, whenever available under the spatially and temporally highly fluctuating conditions. Our data provide first insights into the heterotrophic microbial community, catalyzing an under-investigated part of microbial carbon cycling at hydrothermal vents.

  18. Targeting organic molecules in hydrothermal environments on Mars

    NASA Astrophysics Data System (ADS)

    Parnell, J.; Bowden, S. A.; Lindgren, P.; Wilson, R.; Cooper, J. M.

    2008-09-01

    . Discharging fluids will also precipitate minerals due to drop in temperature and pressure, and colonising organisms are likely to become entrained by the minerals. Attempts to find evidence of microbial activity related to hydrothermal systems in the geological record have therefore been focussed on hydrothermal mineral precipitates. Organic matter is found in hydrothermal precipitates back into the Precambrian [6]. Fig. 1 Settings for organic matter in hydrothermal systems. Surface discharge could be in subaerial or subaqueous environment. Application of SERS Studies using conventional laser Raman instruments have made a good case for application of this type of spectroscopy to planetary exploration. The detection of pigments sited in microbial matter in a range of samples from extreme environments (e.g. [7]) has supported development of the technique for space exploration generally, and Mars exploration in particular [8]. A major advantage of conventional Raman spectroscopy is that it can be applied to simultaneous characterization of bond types in both organic and inorganic materials. Surface-Enhanced Raman Spectroscopy (SERS) increases the sensitivity by several orders of magnitude, and overcomes the problems created by natural fluorescence [9]. SERS is achieved by adsorbing the target analyte onto the surface of a metal. We are combining the additional sample processing necessary for SERS with sample preparation in a microfluidic format (including extraction and sample concentration). The final result will be a very rapid assay, capable of detecting ppb concentrations of certain organic analytes. This approach was tested at a site in Iceland, where young/active hydrothermal systems are focussed in a rift environment. Sulphur species are prevalent, in a range of oxidation states, including sulphates, sulphides and native sulphur. Thus they are a useful model for systems that might exist on Mars, where sulphur species are widespread and therefore likely to be incorporated

  19. Microwave-assisted hydrothermal synthesis of marigold-like ZnIn{sub 2}S{sub 4} microspheres and their visible light photocatalytic activity

    SciTech Connect

    Chen Zhixin; Li Danzhen; Xiao Guangcan; He Yunhui; Xu Yijun

    2012-02-15

    Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a microwave-assisted hydrothermal method with the temperature ranging from 80 to 195 Degree-Sign C. X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen sorption analysis, UV-visible spectroscopy, scanning electron microscopy and transmission electron microscopy were used to characterize the products. It was found that the crystallographic structure and optical property of the products synthesized at different temperatures were almost the same. The degradation of methyl orange (MO) under the visible light irradiation has been used as a probe reaction to investigate the photocatalytic activity of as-prepared ZnIn{sub 2}S{sub 4}, which shows that the ZnIn{sub 2}S{sub 4} sample synthesized at 195 Degree-Sign C shows the best photocatalytic activity for MO degradation. In addition, the photocatalytic activities of all the samples prepared by the microwave-assisted hydrothermal method are better than those prepared by a normal hydrothermal method, which could be attributed to the formation of more defect sites during the microwave-assisted hydrothermal treatment. - Graphical abstract: Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a fast microwave-assisted hydrothermal method at 80-195 Degree-Sign C with a very short reaction time of 10 min. The as-prepared ZnIn{sub 2}S{sub 4} sample can be used as visible light photocatalyst for degradation of organic dyes. Highlights: Black-Right-Pointing-Pointer ZnIn{sub 2}S{sub 4} microspheres were synthesized by microwave-assisted hydrothermal method. Black-Right-Pointing-Pointer The crystal structure and optical property of the products were almost the same. Black-Right-Pointing-Pointer Increment of the temperature renders high surface area due to the bubbling effect. Black-Right-Pointing-Pointer The ZnIn{sub 2}S{sub 4} synthesized at 195 Degree-Sign C shows the best visible catalytic activity for MO.

  20. Identification and characterization of the active hydrothermal deposits in Okinawa Trough, SW Japan: Estimates from logging-while-drilling

    NASA Astrophysics Data System (ADS)

    Saito, S.; Sanada, Y.; Moe, K.; Kido, Y. N.; Hamada, Y.; Kumagai, H.; Nozaki, T.; Takai, K.; Suzuki, K.

    2015-12-01

    A scientific drilling expedition was conducted at an active hydrothermal field on the Iheya-North Knoll by D/V Chikyu in 2014 (Expedition 907) as a part of "Next-generation Technology for Ocean Resources Survey" of the Cross-ministerial Strategic Innovation Promotion Program. During the expedition logging while drilling (LWD) was deployed to constrain the area of the fluid reservoir beneath seafloor followed by three coring holes down to 150 meter below the seafloor (mbsf). The LWD system is composed of arcVISION for resistivity and natural gamma ray measurement and TeleScope for real-time transmission of drilling parameters and arcVISION data. Five sites (C9011-15) at the Iheya-North Original Site and one site (C9016) at Aki Site were drilled with LWD. At C9012 and C9016, the arcVISION detected temperature anomaly up to 84℃ at 234 mbsf and up to 39℃ at 80 mbsf, respectively. The temperature quickly increases at that depth and it would reflect the existence of high-temperature heat source along borehole. Due to the continuous fluid circulation during drilling, the measured temperature does not indicate in-situ temperature, but it reflects the heat disturbed by the cold circulated water instead. High quality resistivity and natural gamma ray data were acquired at six sites. The log curves at Site C9016 show characteristic response; the natural gamma ray log exhibits extremely high radiation (>500 gAPI) at 7-13 and 23-31 mbsf (Zone A). In the underlying interval of 31-40 mbsf, the resistivity log exhibits extremely low value (<0.2 ohm-m) (Zone B). Then the resistivity log exhibits higher value (~10 ohm-m) and the natural gamma ray log shows very low radiation (<50 gAPI) at the interval of 41-48 mbsf (Zone C). The log characteristics in Zone A, B, and C can be interpreted as a series of K-rich alteration zone, sulfide zone, and low-K hard (silicified) sediments, respectively. The LWD-based lithological interpretation was confirmed by the following core description

  1. The Lassen hydrothermal system

    USGS Publications Warehouse

    Ingebritsen, Steven E.; Bergfeld, Deborah; Clor, Laura; Evans, William C.

    2016-01-01

    The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 °C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 ± 10 kg/s of steam (~115 MW) and 23 ± 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km3/Ma, and the ongoing rates of heat and magmatic CO2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4–5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km2, the average conductive heat flux over that area is >25 W/m2, and the conductive-boundary length <50 m. Observational records of hydrothermal discharge are likely too short to document long-term transients, whether they are intrinsic to the system or owe to various geologic events such as the eruption of Lassen Peak at 27 ka, deglaciation beginning ~18 ka, the eruptions of Chaos Crags at 1.1 ka, or the minor 1914–1917 eruption at the summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009–present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.

  2. The Biogeochemistry of Sulfur in Hydrothermal Systems

    NASA Technical Reports Server (NTRS)

    Schulte, Mitchell; Rogers, K. L.; DeVincenzi, Donald L. (Technical Monitor)

    2001-01-01

    The incorporation of sulfur into many biomolecules likely dates back to the development of the earliest metabolic strategies. Sulfur is common in enzymes and co-enzymes and is an indispensable structural component in many peptides and proteins. Early metabolism may have been heavily influenced by the abundance of sulfide minerals in hydrothermal systems. The incorporation of sulfur into many biomolecules likely dates back to the development of the earliest metabolic strategies. Sulfur is common in enzymes and co-enzymes and is an indispensable structural component in many peptides and proteins. Early metabolism may have been heavily influenced by the abundance of sulfide minerals in hydrothermal systems. Understanding how sulfur became prevalent in biochemical processes and many biomolecules requires knowledge of the reaction properties of sulfur-bearing compounds. We have previously estimated thermodynamic data for thiols, the simplest organic sulfur compounds, at elevated temperatures and pressures. If life began in hydrothermal environments, it is especially important to understand reactions at elevated temperatures among sulfur-bearing compounds and other organic molecules essential for the origin and persistence of life. Here we examine reactions that may have formed amino acids with thiols as reaction intermediates in hypothetical early Earth hydrothermal environments. (There are two amino acids, cysteine and methionine, that contain sulfur.) Our calculations suggest that significant amounts of some amino acids were produced in early Earth hydrothermal fluids, given reasonable concentrations H2, NH3, H2S and CO. For example, preliminary results indicate that glycine activities as high as 1 mmol can be reached in these systems at 100 C. Alanine formation from propanethiol is also a favorable reaction. On the other hand, the calculated equilibrium log activities of cysteine and serine from propanethiol are -21 and -19, respectively, at 100 C. These results

  3. Detection of active hydrothermal vent fields in the Pescadero Basin and on the Alarcon Rise using AUV multibeam and CTD data

    NASA Astrophysics Data System (ADS)

    Caress, D. W.; Troni, G.; Clague, D. A.; Paduan, J. B.; Martin, J. F.; Thomas, H. J.; Thompson, D.; Conlin, D.; Martin, E. J.; meneses-Quiroz, E.; Nieves-Cardoso, C.; Angel Santa Rosa del Rio, M.

    2015-12-01

    The MBARI AUV D. Allan B. collected high resolution bathymetry, sidescan, and subbottom profiles along the neovolcanic zone of the Alarcon Rise and across the southern Pescadero Basin during 2012 and 2015 MBARI expeditions to the Gulf of California (GOC). The combination of high resolution multibeam bathymetry and seawater temperature data has proven effective in identifying active high temperature vent fields, as validated by inspection and sampling during ROV dives. The AUV carries a 200 kHz multibeam sonar, 110 kHz chirp sidescan sonar, a 1-6 kHz chirp subbottom profiler, and a conductivity, temperature and depth (CTD) sensor for ~17-hour duration missions. Flying at 5.4 km/hr at 50 m altitude, the processed AUV bathymetry has a 0.1 m vertical precision and a 1 m lateral resolution. Chimneys taller than 1.5 m are sufficiently distinctive to allow provisional identification. The CTD temperature data have a nominal 0.002°C accuracy. Following calculation of potential temperature and correcting for average local variation of potential temperature with depth, anomalies greater than 0.05 °C can be reliably identified using a spike detection filter. MBARI AUV mapping surveys are typically planned using a 150 m survey line spacing, so the CTD data may be collected as much as 75 m away from any vent plume source. Five active high temperature vent fields were discovered in the southern GOC, with the Auka Field in the southern Pescadero Basin, and the Ja Sít, Pericú, Meyibó, and Tzab-ek Fields along the Alarcon Rise. In all five cases, hydrothermal vent chimneys are readily identifiable in the multibeam bathymetry, and temperature anomalies are observed above background variability. Other apparent hydrothermal chimneys were observed in the bathmetry that did not exhibit water temperature anomalies; most of these were visited during ROV dives and confirmed to be inactive sites. The maximum water column anomalies are 0.13°C observed above the Meyibó field and 0.25

  4. NaF-assisted hydrothermal synthesis of Ti-doped hematite nanocubes with enhanced photoelectrochemical activity for water splitting

    NASA Astrophysics Data System (ADS)

    Zheng, Chong; Zhu, Zezhou; Wang, Sibo; Hou, Yidong

    2015-12-01

    Ti-doped α-Fe2O3 nanocubes on FTO substrate was prepared by hydrothermal deposition β-FeOOH onto FTO glass with a solution of FeCl3, TiOCl2 and NaF, followed by an appropriate annealing. In comparison to Ti-doped α-Fe2O3 nanorods Ti-doped α-Fe2O3 nanocubes showed an enhanced photoelectrochemical activity for water splitting, with a remarkable IPCE of 25.2% at 340 nm at the potential of 1.23 V vs. RHE. The hematite films were studied in detail by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, UV-vis absorption spectroscopy and electrochemical impedance spectroscopy. On the basis of the obtained results, the improved performance of Ti-doped α-Fe2O3 nanocubes can be ascribed to the porous structure, good electrical conductivity and fast charge transportation of hematite.

  5. Ultrasonically assisted hydrothermal synthesis of activated carbon-HKUST-1-MOF hybrid for efficient simultaneous ultrasound-assisted removal of ternary organic dyes and antibacterial investigation: Taguchi optimization.

    PubMed

    Azad, F Nasiri; Ghaedi, M; Dashtian, K; Hajati, S; Pezeshkpour, V

    2016-07-01

    Activated carbon (AC) composite with HKUST-1 metal organic framework (AC-HKUST-1 MOF) was prepared by ultrasonically assisted hydrothermal method and characterized by FTIR, SEM and XRD analysis and laterally was applied for the simultaneous ultrasound-assisted removal of crystal violet (CV), disulfine blue (DSB) and quinoline yellow (QY) dyes in their ternary solution. In addition, this material, was screened in vitro for their antibacterial actively against Methicillin-resistant Staphylococcus aureus (MRSA) and Pseudomonas aeruginosa (PAO1) bacteria. In dyes removal process, the effects of important variables such as initial concentration of dyes, adsorbent mass, pH and sonication time on adsorption process optimized by Taguchi approach. Optimum values of 4, 0.02 g, 4 min, 10 mg L(-1) were obtained for pH, AC-HKUST-1 MOF mass, sonication time and the concentration of each dye, respectively. At the optimized condition, the removal percentages of CV, DSB and QY were found to be 99.76%, 91.10%, and 90.75%, respectively, with desirability of 0.989. Kinetics of adsorption processes follow pseudo-second-order model. The Langmuir model as best method with high applicability for representation of experimental data, while maximum mono layer adsorption capacity for CV, DSB and QY on AC-HKUST-1 estimated to be 133.33, 129.87 and 65.37 mg g(-1) which significantly were higher than HKUST-1 as sole material with Qm to equate 59.45, 57.14 and 38.80 mg g(-1), respectively.

  6. Visible light induced bactericidal and photocatalytic activity of hydrothermally synthesized BiVO4 nano-octahedrals.

    PubMed

    Sharma, Rishabh; Uma; Singh, Sonal; Verma, Ajit; Khanuja, Manika

    2016-09-01

    In the present work, monoclinic bismuth vanadate (m-BiVO4) nanostructures have been synthesized via simple hydrothermal method and employed for visible light driven antimicrobial and photocatalytic activity. Morphology (octahedral) and size (200-300nm) of the m-BiVO4 are studied using transmission electron microscopy (TEM). The crystal structure of m-BiVO4 (monoclinic scheelite structure) is confirmed by high resolution-TEM (HRTEM) and X-ray diffraction (XRD) studies. The band gap of m-BiVO4 was estimated to be ca. 2.42eV through Kubelka-Munk function F(R∞) using diffuse reflectance spectroscopy (DRS). Antimicrobial action of m-BiVO4 is anticipated by (i) shake flask method, (ii) MTT [3-(4,5-Dimethylthiazol-2-Yl)-2,5-Diphenyltetrazolium Bromide] assay for cytotoxicity. SEM analysis has been carried on Escherichia coli (E.coli) before and after treatment with nanostructure materials to reveal the mechanism underlying the antimicrobial action. Antimicrobial activity is studied as a function of m-BiVO4 concentration viz. 20, 40, 60 and 80ppm. The bacterial growth is decreased 80% to 96%, with the increase in m-BiVO4 concentration from 20ppm to 80ppm, respectively, in 2h. Photocatalytic activity and rate kinetics of m-BiVO4 nanostructures have been studied as a function of time on methylene blue (MB) dye degradation which is one of the waste products of textile industries and responsible for water pollution. PMID:27394009

  7. The chemistry of hydrothermal magnetite: a review

    USGS Publications Warehouse

    Nadoll, Patrick; Angerer, Thomas; Mauk, Jeffrey L.; French, David; Walshe, John

    2014-01-01

    Magnetite (Fe3O4) is a well-recognized petrogenetic indicator and is a common accessory mineral in many ore deposits and their host rocks. Recent years have seen an increased interest in the use of hydrothermal magnetite for provenance studies and as a pathfinder for mineral exploration. A number of studies have investigated how specific formation conditions are reflected in the composition of the respective magnetite. Two fundamental questions underlie these efforts — (i) How can the composition of igneous and, more importantly, hydrothermal magnetite be used to discriminate mineralized areas from barren host rocks, and (ii) how can this assist exploration geologists to target ore deposits at greater and greater distances from the main mineralization? Similar to igneous magnetite, the most important factors that govern compositional variations in hydrothermal magnetite are (A) temperature, (B) fluid composition — element availability, (C) oxygen and sulfur fugacity, (D) silicate and sulfide activity, (E) host rock buffering, (F) re-equilibration processes, and (G) intrinsic crystallographic controls such as ionic radius and charge balance. We discuss how specific formation conditions are reflected in the composition of magnetite and review studies that investigate the chemistry of hydrothermal and igneous magnetite from various mineral deposits and their host rocks. Furthermore, we discuss the redox-related alteration of magnetite (martitization and mushketovitization) and mineral inclusions in magnetite and their effect on chemical analyses. Our database includes published and previously unpublished magnetite minor and trace element data for magnetite from (1) banded iron formations (BIF) and related high-grade iron ore deposits in Western Australia, India, and Brazil, (2) Ag–Pb–Zn veins of the Coeur d'Alene district, United States, (3) porphyry Cu–(Au)–(Mo) deposits and associated (4) calcic and magnesian skarn deposits in the southwestern United

  8. Discovery of new hydrothermal activity and chemosynthetic fauna on the Central Indian Ridge at 18°-20° S.

    PubMed

    Nakamura, Kentaro; Watanabe, Hiromi; Miyazaki, Junichi; Takai, Ken; Kawagucci, Shinsuke; Noguchi, Takuro; Nemoto, Suguru; Watsuji, Tomo-o; Matsuzaki, Takuya; Shibuya, Takazo; Okamura, Kei; Mochizuki, Masashi; Orihashi, Yuji; Ura, Tamaki; Asada, Akira; Marie, Daniel; Koonjul, Meera; Singh, Manvendra; Beedessee, Girish; Bhikajee, Mitrasen; Tamaki, Kensaku

    2012-01-01

    Indian Ocean hydrothermal vents are believed to represent a novel biogeographic province, and are host to many novel genera and families of animals, potentially indigenous to Indian Ocean hydrothermal systems. In particular, since its discovery in 2001, much attention has been paid to a so-called 'scaly-foot' gastropod because of its unique iron-sulfide-coated dermal sclerites and the chemosynthetic symbioses in its various tissues. Despite increasing interest in the faunal assemblages at Indian Ocean hydrothermal vents, only two hydrothermal vent fields have been investigated in the Indian Ocean. Here we report two newly discovered hydrothermal vent fields, the Dodo and Solitaire fields, which are located in the Central Indian Ridge (CIR) segments 16 and 15, respectively. Chemosynthetic faunal communities at the Dodo field are emaciated in size and composition. In contrast, at the Solitaire field, we observed faunal communities that potentially contained almost all genera found at CIR hydrothermal environments to date, and even identified previously unreported taxa. Moreover, a new morphotype of 'scaly-foot' gastropod has been found at the Solitaire field. The newly discovered 'scaly-foot' gastropod has similar morphological and anatomical features to the previously reported type that inhabits the Kairei field, and both types of 'scaly-foot' gastropods genetically belong to the same species according to analyses of their COI gene and nuclear SSU rRNA gene sequences. However, the new morphotype completely lacks an iron-sulfide coating on the sclerites, which had been believed to be a novel feature restricted to 'scaly-foot' gastropods. Our new findings at the two newly discovered hydrothermal vent sites provide important insights into the biodiversity and biogeography of vent-endemic ecosystems in the Indian Ocean. PMID:22431990

  9. Evidence for Hesperian Impact-Induced Hydrothermalism on Mars

    NASA Technical Reports Server (NTRS)

    Marzo, Giuseppe A.; Davila, Alfonso F.; Tornabene, Livio L.; Dohm, James M.; Fairen, Alberto G.; Gross, Christoph; Kneissl, Thomas; Bishop, Janice L.; Roush, Ted L.; McKay, Chris P.

    2010-01-01

    Several hydrated silicate deposits on Mars are observed within craters and are interpreted as excavated Noachian material. Toro crater (71.8 deg E, 17.0 deg N), located on the northern edge of the Syrtis Major Volcanic Plains, shows spectral and morphologic evidence of impact-induced hydrothermal activity. Spectroscopic observations were used to identify extensive hydrated silicate deposits, including prehnite, chlorites, smectites, and opaline material, a suite of phases that frequently results from hydrothermal alteration in terrestrial craters and also expected on Mars from geochemical modeling of hydrothermal environments. When combined with altimetry and high-resolution imaging data, these deposits appear associated predominantly with the central uplift and with portions of the northern part of the crater floor. Detailed geologic mapping of these deposits reveals geomorphic features that are consistent with hydrothermal activity that followed the impact event, including vent-like and conical mound structures, and a complex network of tectonic structures caused by fluid interactions such as fractures and joints. The crater age has been calculated from the cumulative crater size-frequency distributions and is found to be Early Hesperian. The evidence presented here provides support for impact-induced hydrothermal activity in Toro crater, that extends phyllosilicate formation processes beyond the Noachian era.

  10. Morphology-dependent photocatalytic activity of octahedral anatase particles prepared by ultrasonication-hydrothermal reaction of titanates

    NASA Astrophysics Data System (ADS)

    Wei, Zhishun; Kowalska, Ewa; Verrett, Jonathan; Colbeau-Justin, Christophe; Remita, Hynd; Ohtani, Bunsho

    2015-07-01

    Octahedral anatase particles (OAPs) were prepared by an ultrasonication (US)-hydrothermal (HT) reaction of partially proton-exchanged potassium titanate nanowires (TNWs). The structural/physical properties of OAP-containing samples, including specific surface area, crystallinity, crystallite size, particle aspect ratio, composition and total OAP content, were analyzed. Photocatalytic activities of samples were measured under irradiation (>290 nm) for oxidative decomposition of acetic acid (CO2 system) and dehydrogenation of methanol (H2 system) under aerobic and deaerated conditions, respectively. Total density of electron traps (ETs) was measured by double-beam photoacoustic spectroscopy (DB-PAS). Mobility and lifetime of charge carriers (electrons) were investigated by the time-resolved microwave conductivity (TRMC) method. The effects of synthesis parameters, i.e., HT duration, HT temperature and US duration, on properties and photocatalytic activities of final products were examined in detail. The sample prepared with 1 h US duration and 6 h HT duration at 433 K using 267 mg of TNWs in 80 mL of Milli-Q water exhibited the highest photocatalytic activity. It was found that change in HT duration or HT temperature while keeping the other conditions the same resulted in changes in all properties and photocatalytic activity. On the other hand, duration of US treatment, before HT reaction, influenced the morphology of both the reagent (by TNWs breaking) and final products (change in total OAP content); samples prepared with various US durations exhibited almost the same structural/physical properties evaluated in this study but were different in morphology and photocatalytic activity. This enabled clarification of the correlation between morphology and photocatalytic activity, i.e., the higher the total OAP content was, the higher was the level of photocatalytic activity, especially in the CO2 system. Although the decay after maximum TRMC signal intensity (Imax) was

  11. Distribution of buried hydrothermal alteration deduced from high-resolution magnetic surveys in Yellowstone National Park

    NASA Astrophysics Data System (ADS)

    Bouligand, Claire; Glen, Jonathan M. G.; Blakely, Richard J.

    2014-04-01

    Yellowstone National Park (YNP) displays numerous and extensive hydrothermal features. Although hydrothermal alteration in YNP has been extensively studied, the volume, geometry, and type of rock alteration at depth remain poorly constrained. In this study, we use high-resolution airborne and ground magnetic surveys and measurements of remanent and induced magnetization of field and drill core samples to provide constraints on the geometry of hydrothermal alteration within the subsurface of three thermal areas in YNP (Firehole River, Smoke Jumper Hot Springs, and Norris Geyser Basin). We observe that hydrothermal zones from both liquid- and vapor-dominated systems coincide with magnetic lows observed in aeromagnetic surveys and with a decrease of the amplitude of short-wavelength anomalies seen in ground magnetic surveys. This suggests a strong demagnetization of both the shallow and deep substratum within these areas associated with the removal of magnetic minerals by hydrothermal alteration processes. Such demagnetization is confirmed by measurements of rock samples from hydrothermal areas which display significantly decreased total magnetization. A pronounced negative anomaly is observed over the Lone Star Geyser and suggests a significant demagnetization of the substratum associated with areas displaying large-scale fluid flow. The ground and airborne magnetic surveys are used to evaluate the distribution of magnetization in the subsurface. This study shows that significant demagnetization occurs over a thickness of at least a few hundred meters in hydrothermal areas at YNP and that the maximum degree or maximum thickness of demagnetization correlates closely with the location of hydrothermal activity and mapped alteration.

  12. NeMO-Net: A System for Near Real-Time Remote Sensing of Hydrothermal and Biological Activity in the Caldera of an Active Submarine Volcano

    NASA Astrophysics Data System (ADS)

    Hammond, S. R.; Butterfield, D.; Embley, R. W.; Meinig, C.; Stalin, S.

    2001-12-01

    In July of 2000, a camera and three temperature sensors were placed on the seafloor near a hydrothermal vent located in the caldera of an active submarine volcano. The volcano's summit lies at a depth of about 1500 m and is located at 46° N, 130° W, approximately 250 nautical miles off the Oregon coast. The volcano is the site of a long-term interdisciplinary study focused in part on discovering relationships between submarine volcanic and hydrothermal activity and a microbial biosphere which exists beneath the sea floor within the volcano's summit caldera. NeMO-Net utilizes an acoustic modem to communicate with a surface mooring anchored nearby. The mooring, in turn, is linked from the ocean surface to the Pacific Marine Environmental Laboratory by means of satellite systems. A unique feature of NeMO-Net is that it enables shore-based investigators to interrogate and command the system to perform specific tasks, the results of which are then reported back typically within several minutes . In the initial year-long deployment, photographic images, along with hourly readings from the three temperature probes, were available on a website which was updated every 24 hours. During the year, the camera documented a dynamic vent biological community as well as water temperature variations due to the influence of tides, and possibly with changing vent fluid temperatures The NeMO-Net system is under continuing development with particular emphasis on linking it to multiple sea floor instruments including near-real-time chemical and water samplers. Near-future plans also call for NeMO Net to be linked to a resident sea floor AUV.

  13. Vapor Discharges On Nevado Del Ruiz During The Recent Activity: Clues On The Composition Of The Deep Hydrothermal System And Its Effects On Thermal Springs

    NASA Astrophysics Data System (ADS)

    Inguaggiato, S.; Federico, C.; Chacon, Z.; Londono, J. M.; Alzate, D. M.; Gil, E.

    2015-12-01

    The Nevado del ruiz volcano (NdR, 5321m asl), one of the most active in Colombia, threatens about 600,000 people. The existence of an ice cap and several streams channeling in some main rivers increase the risk of lahars and mudflows in case of unrest, as occurred during the November 1985 eruption, which caused 20,000 casualties. The involvement of the local hydrothermal system has also produced in the past phreatic and phreatomagmatic activity, as in 1985 and 1989. After more than 7 years of relative stability, since 2010, the still ongoing phase of unrest has produced two small eruption in 2012, and still maintains in high levels of seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and streamwater, located at 2600-5000 m asl, analyzed for water chemistry and stable isotopes. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated the mass rate of steam discharging in the different steam-heated springs. The composition of the hottest thermal spring (Botero Londoño) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250°C and low salinity (Cl ~1500 mg/l), which suggest a chiefly meteoric origin, as also confirmed by the isotope composition retrieved for the hydrothermal water. The vapour discharged at the steam vent "Nereidas" (3600 m asl) is hypothesised to be separated from a high-temperature hyrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, as well as its pH and fO2. The vapour feeding Nereidas would separate from a byphasic hydrothermal system characterised by the follow parameters: t= 315°C, P=19 MPa, NaCl= 15 %, CO2 = 9%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, we obtain pH=2, fO2 fixed by FeO-Fe2O3 buffer, and [Cl]=12000 mg/l. Changes

  14. Hydrothermal alteration, ore fluid characteristics, and gold depositional processes along a trondhjemite-komatiite contact at Tarmoola, Western Australia

    USGS Publications Warehouse

    Duuring, P.; Hagemann, S.G.; Cassidy, K.F.; Johnson, C.A.

    2004-01-01

    Tarmoola is a structurally controlled Archean orogenic gold deposit hosted in greenschist facies metamorphosed komatiite and trondhjemite in the Leonora district of the Eastern Goldfields province, Yilgarn craton. High-grade (>1 g/t Au) orebodies are located in komatiite wall rock adjacent to the eastern and northeastern margins of the asymmetrical, north-south-striking, Tarmoola trondhjemite intrusion. Gold-bearing veins post-date trondhjemite emplacement (ca. 2700 Ma), quartz diorite dikes (ca. 2667 Ma), and regional greenschist facies metamorphism. Textures and crosscutting relationships in gold-bearing veins indicate two stages of hydrothermal fluid infiltration associated with a single gold-related hydrothermal event: a volumetrically dominant, but gold-poor, stage I fluid and a gold-rich stage II fluid. Gold-bearing veins contain stage I milky quartz and pyrite that are overprinted by stage II quartz-ankerite-muscovite-chalcopyrite-sphalerite-galena-gold-tellurides ?? albite ?? chlorite ?? fuchsite ?? epidote ?? scheelite. Stage I hydrothermal alteration assemblages are different in trondhjemite and komatiite due to contrasting reactions between a common ore fluid and disparate wall-rock chemistry. Stage II fluid-wall rock interaction was minor compared to stage I and is indicated by the overprinting of stage I mineral assemblages by stage II microveins. Wall-rock alteration proximal to veins in trondhjemite is characterized by replacement of igneous plagioclase, amphibole, biotite, and metamorphic chlorite by hydrothermal quartz, muscovite, ankerite, calcite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold, whereas in proximal alteration in komatiite, metamorphic chlorite and talc are replaced by ankerite, quartz, muscovite, albite, chlorite, fuchsite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold. The stage II fluid was enriched in H2O, CO2, Si, Ca, K, Na, S, Au, Ag, Cu, Pb, W, Bi, As, Mo, Zn, and Te. Based on fluid inclusion

  15. Trace elements in magnetite from massive iron oxide-apatite deposits indicate a combined formation by igneous and magmatic-hydrothermal processes

    NASA Astrophysics Data System (ADS)

    Knipping, Jaayke L.; Bilenker, Laura D.; Simon, Adam C.; Reich, Martin; Barra, Fernando; Deditius, Artur P.; Wälle, Markus; Heinrich, Christoph A.; Holtz, François; Munizaga, Rodrigo

    2015-12-01

    during ascent along regional-scale transcurrent faults promotes continued growth of the magmatic magnetite microlites from the Fe-rich magmatic-hydrothermal fluid, which manifests in magnetite rims that have trace element abundances consistent with growth from a magmatic-hydrothermal fluid. Mass balance calculations indicate that this process can leach and transport sufficient Fe from a magmatic source to form large IOA deposits such as Los Colorados. Furthermore, published experimental data demonstrate that a saline magmatic-hydrothermal ore fluid will scavenge significant quantities of metals such as Cu and Au from a silicate melt, and when combined with solubility data for Fe, Cu and Au, it is plausible that the magmatic-hydrothermal ore fluid that continues to ascend from the IOA depositional environment can retain sufficient concentrations of these metals to form iron oxide copper-gold (IOCG) deposits at lateral and/or stratigraphically higher levels in the crust. Notably, this study provides a new discrimination diagram to identify magnetite from Kiruna-type deposits and to distinguish them from IOCG, porphyry and Fe-Ti-V/P deposits, based on low Cr (<100 ppm) and high V (>500 ppm) concentrations.

  16. Synthesis of nanostructured and microstructured ZnO and Zn(OH)2 on activated carbon cloth by hydrothermal and microwave-assisted chemical bath deposition methods

    NASA Astrophysics Data System (ADS)

    Mosayebi, Elham; Azizian, Saeid; Hajian, Ali

    2015-05-01

    Nanostructured and microstructured ZnO and Zn(OH)2 loaded on activated carbon cloth were synthesized by microwave-assisted chemical bath deposition and hydrothermal methods. By hydrothermal method the deposited sample on carbon fiber is pure ZnO with dandelion-like nanostructures. By microwave-assisted chemical bath method the structure and composition of deposited sample depends on solution pH. At pH = 9.8 the deposited sample on carbon fiber is pure ZnO with flower-like microstructure; but at pH = 10.8 the sample is a mixture of ZnO and Zn(OH)2 with flower-like and rhombic microstructures, respectively. The mechanism of crystal grow by microwave-assisted chemical bath method was investigated by SEM method at both pH.

  17. Acoustic stratigraphy and hydrothermal activity within Epi Submarine Caldera, Vanuatu, New Hebrides Arc

    USGS Publications Warehouse

    Greene, H. Gary; Exon, N.F.

    1988-01-01

    Geological and geophysical surveys of active submarine volcanoes offshore and southeast of Epi Island, Vanuatu, New Hebrides Arc, have delineated details of the structure and acoustic stratigraphy of three volcanic cones. These submarine cones, named Epia, Epib, and Epic, are aligned east-west and spaced 3.5 km apart on the rim of a submerged caldera. At least three acoustic sequences, of presumed Quaternary age, can be identified on single-channel seismic-reflection profiles. Rocks dredged from these cones include basalt, dacite, and cognate gabbroic inclusions with magmatic affinities similar to those of the Karua (an active submarine volcano off the southeastern tip of Epi) lavas. ?? 1988 Springer-Verlag New York Inc.

  18. Current California legislative and regulatory activity impacting geothermal hydrothermal commercialization: a monitoring report. Report No. 1017

    SciTech Connect

    Not Available

    1980-01-20

    Four key geothermal-impacting bills presently before the California legislature are described. Two deal with state financial backing for geothermal projects. The third relates to the use of the state's share of the BLM geothermal revenues and the fourth to the protection of sensitive hot springs. The current regulatory activities of the California Energy Commission, the California Division of Oil and Gas, and the counties are discussed. (MHR)

  19. Geology and hydrothermal evolution of the Mothra Hydrothermal Field, Endeavour Segment, Juan de Fuca Ridge

    NASA Astrophysics Data System (ADS)

    Glickson, Deborah A.; Kelley, Deborah S.; Delaney, John R.

    2007-06-01

    Detailed characterization of the Mothra Hydrothermal Field, the most southern and spatially extensive field on the Endeavour Segment of the Juan de Fuca Ridge, provides new insights into its geologic and hydrothermal development. Meter-scale bathymetry, side-scan sonar imagery, and direct dive observations show that Mothra is composed of six actively venting sulfide clusters spaced 40-200 m apart. Chimneys within each cluster have similar morphology and venting characteristics, and all clusters host a combination of active and extinct sulfide structures. Black smoker chimneys venting fluids above 300°C are rare, while more common lower-temperature, diffusely venting chimneys support dense colonies of macrofauna and bacterial mat. Hydrothermal sediment and extinct sulfide debris cover 10-15 m of the seafloor surrounding each vent cluster, obscuring the underlying basaltic substrate of light to moderately sedimented pillow, lobate, sheet, and chaotic flows, basalt talus, and collapse terrain. Extinct sulfide chimneys and debris between the clusters indicate that hydrothermal flow was once more widespread and that it has shifted spatially over time. The most prominent structural features in the axial valley at Mothra are regional (020°) trending faults and fissures and north-south trending collapse basins. The location of actively venting clusters within the field is controlled by (1) localization of fluid upflow along the western boundary fault zone, and diversion of these fluids by antithetic faults to feed vent clusters near the western valley wall, and (2) tapping of residual magmatic heat in the central part of the axial valley, which drives flow beneath vent clusters directly adjacent to the collapse basins 70-90 m east of the western valley wall. These processes form the basis for a model of axial valley and hydrothermal system development at Mothra, in which the field is initiated by an eruptive-diking episode and sustained through intense microseismicity

  20. Double, double, (but mostly) toil, and trouble: A multidisciplinary approach to quantify the permeability of an active volcanic hydrothermal system (Whakaari volcano, New Zealand)

    NASA Astrophysics Data System (ADS)

    Heap, Michael; Kennedy, Ben; Farquharson, Jamie; Ashworth, James; Mayer, Klaus; Letham-Brake, Mark; Reuschlé, Thierry; Gilg, Albert; Scheu, Betty; Lavallée, Yan; Siratovich, Paul; Cole, Jim; Jolly, Art; Dingwell, Donald

    2016-04-01

    Our multidisciplinary approach, which combines field techniques and traditional laboratory methods, aims to better understand the permeability of an active volcanic hydrothermal system, a vital prerequisite for understanding and modelling the behaviour of hydrothermal systems worldwide. Whakaari volcano (an active stratovolcano located 48 km off New Zealand's North Island) hosts an open, highly reactive hydrothermal system (hot springs and mud pools, fumaroles, acid streams and lakes) and represents an ideal natural laboratory to undertake such a study. We first gained an appreciation of the different lithologies at Whakaari and (where possible) their lateral and vertical extent through reconnaissance by land, sea, and air. Due to the variable nature of these altered lithologies (mainly lavas and tuffs), we measured porosity-permeability for in excess of a hundred rock hand samples using field techniques. We also measured the permeability of recent, unconsolidated deposits using a field soil permeameter. Our field measurements were then groundtruthed on a subset of these samples (~40-50) using traditional laboratory techniques: helium pycnometry and measurements of permeability using a benchtop permeameter, including measurements under increasing confining pressure (i.e., depth). In all, our measurements highlight that the porosity of the materials at Whakaari can vary from ~0.01 to ~0.6, and permeability can vary by eight orders of magnitude. However, our data show no discernable trend between porosity and permeability. A combination of macroscopic and microscopic observations, chemistry (XRF), mineralogy (XRD), and mercury porosimetry highlight that the absence of a robust porosity-permeability relationship is the product of an insane variability in alteration and microstructure (pore size, particle size, pore connectivity, presence/absence of microcracks, layering, amongst others). While our systematic study offers the most complete porosity-permeability dataset

  1. Chemosynthetic microbial activity at Mid-Atlantic Ridge hydrothermal vent sites

    NASA Astrophysics Data System (ADS)

    Wirsen, Carl O.; Jannasch, Holger W.; Molyneaux, Stephen J.

    1993-06-01

    Chemosynthetic production of microbial biomass, determined by 14CO2 fixation and enzymatic (RuBisCo) activity, at the Mid-Atlantic Ridge (MAR) 23° and 26°N vent sites was found in various niches: warm water emissions, loosely rock-attached flocculent material, dense morphologically diverse bacterial mats covering the surfaces of polymetal sulfide deposits, and filamentous microbes on the carapaces of shrimp (Rimicaris exoculata). The bacterial mats on polymetal sulfide surfaces contained unicellular and filamentous bacteria which appeared to use as their chemolithotrophic electron or energy source either dissolved reduced minerals from vent emissions, mainly sulfur compounds, or solid metal sulfide deposits, mainly pyrite. Moderately thermophilic Chemosynthetic activity was observed in carbon dioxide fixation experiments and in enrichments, but no thermophilic aerobic sulfur oxidizers could be isolated. Both obligate and facultative chemoautotrophs growing at mesophilic temperatures were isolated from all chemosynthetically active surface scrapings. The obligate autotrophs could oxidize sterilized MAR natural sulfide deposits as well as technical pyrite at near neutral pH, in addition to dissolved reduced sulfur compounds. While the grazing by shrimp on the surface mats of MAR metal sulfide deposits was observed and deemed important, the animals' primary occurrence in dense swarms near vent emissions suggests that they were feeding at these sites, where conditions for Chemosynthetic growth of their filamentous microbial epiflora were optimal. The data show that the transformation of geothermal energy at the massive polymetal sulfide deposits of the MAR is based on the lithoautotrophic oxidation of soluble sulfides and pyrites into microbial biomass.

  2. Luminescence characteristics of impurities-activated ZnS nanocrystals prepared in microemulsion with hydrothermal treatment

    NASA Astrophysics Data System (ADS)

    Xu, S. J.; Chua, S. J.; Liu, B.; Gan, L. M.; Chew, C. H.; Xu, G. Q.

    1998-07-01

    Cu-, Eu-, or Mn-doped ZnS nanocrystalline phosphors were prepared at room temperature using a chemical synthesis method. Transmission electron microscopy observation shows that the size of the ZnS clusters is in the 3-18 nm range. New luminescence characteristics such as strong and stable visible-light emissions with different colors were observed from the doped ZnS nanocrystals at room temperature. These results strongly suggest that impurities, especially transition metals and rare-earth metals-activated ZnS nanoclusters form a new class of luminescent materials.

  3. A discussion of 'Anomalous quartz from the Roter Kamm impact crater, Namibia - Evidence for post-impact hydrothermal activity?'

    NASA Technical Reports Server (NTRS)

    Roedder, Edwin

    1990-01-01

    This paper presents arguments against the statement made by Koeberl et al. (1989) to the effect that various differences between the quartz of the three quartz pebbles from the Roter Kamm impact crater (Namibia) and the quartz of the pegmatites present in the basement rocks of this crater can be best interpreted as evidence that the pebbles were formed (or 'recrystallized') by a post-impact hydrothermal system. Arguments are presented that suggest that the three quartz pebbles are, most likely, fragments of a preimpact vein quartz of hydrothermal origin.

  4. A case study of impact-induced hydrothermal activity: The Haughton impact structure, Devon Island, Canadian High Arctic

    NASA Astrophysics Data System (ADS)

    Osinski, Gordon R.; Lee, Pascal; Parnell, John; Spray, John G.; Baron, Martin

    2005-12-01

    The well-preserved state and excellent exposure at the 39 Ma Haughton impact structure, 23 km in diameter, allows a clearer picture to be made of the nature and distribution of hydrothermal deposits within mid-size complex impact craters. A moderate- to low-temperature hydrothermal system was generated at Haughton by the interaction of groundwaters with the hot impact melt breccias that filled the interior of the crater. Four distinct settings and styles of hydrothermal mineralization are recognized at Haughton: a) vugs and veins within the impact melt breccias, with an increase in intensity of alteration towards the base; b) cementation of brecciated lithologies in the interior of the central uplift; c) intense veining around the heavily faulted and fractured outer margin of the central uplift; and d) hydrothermal pipe structures or gossans and mineralization along fault surfaces around the faulted crater rim. Each setting is associated with a different suite of hydrothermal minerals that were deposited at different stages in the development of the hydrothermal system. Minor, early quartz precipitation in the impact melt breccias was followed by the deposition of calcite and marcasite within cavities and fractures, plus minor celestite, barite, and fluorite. This occurred at temperatures of at least 200 °C and down to ˜100-120 °C. Hydrothermal circulation through the faulted crater rim with the deposition of calcite, quartz, marcasite, and pyrite, occurred at similar temperatures. Quartz mineralization within breccias of the interior of the central uplift occurred in two distinct episodes (˜250 down to ˜90 °C, and <60 °C). With continued cooling (<90 °C), calcite and quartz were precipitated in vugs and veins within the impact melt breccias. Calcite veining around the outer margin of the central uplift occurred at temperatures of ˜150 °C down to <60 °C. Mobilization of hydrocarbons from the country rocks occurred during formation of the higher

  5. Reduced graphene oxide supported platinum nanocubes composites: one-pot hydrothermal synthesis and enhanced catalytic activity

    NASA Astrophysics Data System (ADS)

    Li, Fumin; Gao, Xueqing; Xue, Qi; Li, Shuni; Chen, Yu; Lee, Jong-Min

    2015-02-01

    Reduced graphene oxide (rGO) supported platinum nanocubes (Pt-NCs) composites (Pt-NCs/rGO) were synthesized successfully by a water-based co-chemical reduction method, in which polyallylamine hydrochloride acted as a multi-functional molecule for the functionalization of graphene oxide, anchorage of PtII precursor, and control of Pt crystal facets. The morphology, structure, composition, and catalytic property of Pt-NCs/rGO composites were characterized in detail by various spectroscopic techniques. Transmission electron microscopy images showed well-defined Pt-NCs with an average size of 9 nm uniformly distributed on the rGO surface. The as-prepared Pt-NCs/rGO composites had excellent colloidal stability in the aqueous solution, and exhibited superior catalytic activity towards the hydrogenation reduction of nitro groups compared to commercial Pt black. The improved catalytic activity originated from the abundant exposed Pt{100} facets of Pt-NCs, excellent dispersion of Pt-NCs on the rGO surface, and synergistic effect between Pt-NCs and rGO.

  6. Lead recovery from scrap cathode ray tube funnel glass by hydrothermal sulphidisation.

    PubMed

    Yuan, Wenyi; Meng, Wen; Li, Jinhui; Zhang, Chenglong; Song, Qingbin; Bai, Jianfeng; Wang, Jingwei; Li, Yingshun

    2015-10-01

    This research focused on the application of the hydrothermal sulphidisation method to separate lead from scrap cathode ray tube funnel glass. Prior to hydrothermal treatment, the cathode ray tube funnel glass was pretreated by mechanical activation. Under hydrothermal conditions, hydroxyl ions (OH(-)) were generated through an ion exchange reaction between metal ions in mechanically activated funnel glass and water, to accelerate sulphur disproportionation; no additional alkaline compound was needed. Lead contained in funnel glass was converted to lead sulphide with high efficiency. Temperature had a significant effect on the sulphidisation rate of lead in funnel glass, which increased from 25% to 90% as the temperature increased from 100 °C to 300 °C. A sulphidisation rate of 100% was achieved at a duration of 8 h at 300 °C. This process of mechanical activation and hydrothermal sulphidisation is efficient and promising for the treatment of leaded glass.

  7. Parallel Activation in Bilingual Phonological Processing

    ERIC Educational Resources Information Center

    Lee, Su-Yeon

    2011-01-01

    In bilingual language processing, the parallel activation hypothesis suggests that bilinguals activate their two languages simultaneously during language processing. Support for the parallel activation mainly comes from studies of lexical (word-form) processing, with relatively less attention to phonological (sound) processing. According to…

  8. The latest on hydrothermal activity on Enceladus from Cassini and Laboratory work

    NASA Astrophysics Data System (ADS)

    Postberg, F.; Hsu, H. W.; Sekine, Y.; Shibuya, T.

    2015-10-01

    Various observations from the Cassini spacecraft [1,2,3], suggest the existence of subsurface water beneath the south polar region of Saturn's geologically active icy moon Enceladus. They provide information on the composition and physical conditions of water reservoirs occurring at shallow depth from which the plumes emerge [1,2,4], and about the dimensions of the south polar ocean beneath the ice crust at a depth of about 50km [3]. However, constraints on the physical and chemical conditions at the interface of the rocky core and the deep ocean are sparse. We report in situ measurements of tiny grains, so called stream particles, by Cassini's Cosmic Dust Analyser (CDA) in the Saturnian system. CDA data shows that these nano-particles are composed of silica that were initially embedded in larger μm-sized icy grains emitted from Enceladus subsurface waters and released by sputter erosion in Saturn's E ring. Comprehensive long- term laboratory experiments and model calculations were carried out to investigate the reaction conditions at the bottom of Enceladus' ocean.

  9. Subsurface geology, ancient hydrothermal systems and crater excavation processes beneath Lake Rotomahana: Evidence from lithic clasts of the 1886 AD Rotomahana Pyroclastics

    NASA Astrophysics Data System (ADS)

    Pittari, A.; Briggs, R. M.; Bowyer, D. A.

    2016-03-01

    The craters associated with the 1886 AD phreatomagmatic Rotomahana eruption, Okataina Volcanic Centre, New Zealand, and the near-vent geology are now hidden beneath Lake Rotomahana and its post-eruptive sediment fill. Lithic clasts from the near-vent lithic lapilli ash deposits of the Rotomahana Pyroclastics are used in this study to trace geological and geothermal conditions before the eruption, as well as vent excavation dynamics. Near-vent deposit characteristics were described in the field, representative lithic clasts were documented petrographically, and unaltered clasts were analysed for major and trace element compositions. The majority of the lithic clasts were rhyolites with subordinate ignimbrites and hydrothermally altered clasts, and trace siltstone and silicified clasts. The rhyolites were classified into four petrographic groups according to phenocryst content and assemblage and were more diverse with respect to geochemical compositions. Most of the rhyolite lithics in the Rotomahana Pyroclastics did not match the rhyolite domes exposed subaerially around the lake, but did have affinities with the pre-Matahina caldera Wairua Rhyolite, and potentially other older non-exposed domes. Ignimbrites most likely correlated either to the Matahina ignimbrite or older non-exposed units. Hydrothermally altered rhyolite and ignimbrite lithic clasts are common and suggest that there has been a long-lived hydrothermal system in this sector, possibly dating back to early activity of the Okataina Volcanic Centre. The diversity in lithic types indicate a spatial variation in country rock lithology and strength, which probably contributed to the vent position and morphology along the Rotomahana fissure.

  10. From nanocorals to nanorods to nanoflowers nanoarchitecture for efficient dye-sensitized solar cells at relatively low film thickness: All Hydrothermal Process

    PubMed Central

    Mali, Sawanta S.; Betty, Chirayath A.; Bhosale, Popatrao N.; Patil, Pramod S.; Hong, Chang Kook

    2014-01-01

    Simple and low temperature hydrothermal process is employed to synthesize exotic nanostructures of TiO2. The nanostructures are obtained merely by changing the nature of the precursors and processing parameters. The chloride and isopropoxide salts of titanium are used to grow high quality thin films comprising anatase nanocorals, rutile nanorods and rutile nanoflowers respectively. A novel route of addition of room temperature ionic liquid (RTIL) is used to synthesize hitherto unexplored nano-morphologies. The Bronsted Acidic Ionic Liquid [BAIL] 0.01 M, 1: 3-ethoxycarbonylethyl-1-methyl-imidazolium chloride [CMIM][HSO4] RTIL directed growth of TiO2 flowers with bunch of aligned nanorods are obtained. The structural, optical and morphological properties of hydrothermally grown TiO2 samples are studied with the different characterization techniques. The influence of these exotic nano-morphologies on the performance of dye sensitized solar cells (DSSCs) is investigated in detail. It is found that [CMIM][HSO4] can facilitate the formation of novel nanoflower morphology with uniform, dense, and collectively aligned in regular petal like oriented TiO2 nanorods and hence improves the dye adsorption and the photovoltaic performance of DSSCs, typically in short-circuit photocurrent and power conversion efficiency. A best power conversion efficiency of 6.63% has been achieved on a DSSC based on nanoflowers (TNF) film obtained from a [CMIM][HSO4] solution. PMID:24975849

  11. Novel synthesis of well-dispersed crystalline SnO2 nanoparticles by water-in-oil microemulsion-assisted hydrothermal process.

    PubMed

    Chen, Deliang; Gao, Lian

    2004-11-01

    Well-dispersed crystalline tin dioxide (SnO2) nanoparticles were synthesized by a novel and simple water-in-oil (w/o) microemulsion-assisted hydrothermal process, using low-cost tin chloride as the starting material. The typical quaternary microemulsions of cetyltrimethylammonium bromide (CTAB)/n-pentanol/n-hexane/water were used as space-confined microreactors for the nucleation, growth, and crystallization of SnO2 nanoparticles under hydrothermal conditions. The techniques of XRD, TEM, HRTEM, SAED, EDS, FTIR, XPS, and N2 adsorption measurement were used to characterize the compositions and structures of obtained samples. The results show that the SnO2 nanoparticles have high specific areas (107-169 m2 g(-1)), small particle sizes (ca. 3.0 nm), high crystallinity, and narrow size distributions. The well-dispersed, uniform, and well-crystallized powders with microporous texture are favorable for gas-sensing applications. The as-developed microemulsion-assisted in situ crystallizing process can be extended to prepare other oxide, metal, and sulfide nanoparticles.

  12. Modeled temperatures and fluid source distributions for the Mexican subduction zone: Effects of hydrothermal circulation and implications for plate boundary seismic processes

    NASA Astrophysics Data System (ADS)

    Perry, Matthew; Spinelli, Glenn A.; Wada, Ikuko; He, Jiangheng

    2016-02-01

    In subduction zones, spatial variations in pore fluid pressure are hypothesized to control the sliding behavior of the plate boundary fault. The pressure-temperature paths for subducting material control the distributions of dehydration reactions, a primary control on the pore fluid pressure distribution. Thus, constraining subduction zone temperatures are required to understand the seismic processes along the plate interface. We present thermal models for three margin-perpendicular transects in the Mexican subduction zone. We examine the potential thermal effects of vigorous fluid circulation in a high-permeability aquifer within the basaltic basement of the oceanic crust and compare the results with models that invoke extremely high pore fluid pressures to reduce frictional heating along the megathrust. We combine thermal model results with petrological models to determine the spatial distribution of fluid release from the subducting slab and compare dewatering locations with the locations of seismicity, nonvolcanic tremor, slow-slip events, and low-frequency earthquakes. Simulations including hydrothermal circulation are most consistent with surface heat flux measurements. Hydrothermal circulation has a maximum cooling effect of 180°C. Hydrothermally cooled crust carries water deeper into the subduction zone; fluid release distributions in these models are most consistent with existing geophysical data. Our models predict focused fluid release, which could generate overpressures, coincident with an observed ultraslow layer (USL) and a region of nonvolcanic tremor. Landward of USLs, a downdip decrease in fluid source magnitude could result in the dissipation in overpressure in the oceanic crust without requiring a downdip increase in fault zone permeability, as posited in previous studies.

  13. Molecular Diversity and Activity of Methanogens in the Subseafloor at Deep-Sea Hydrothermal Vents of the Pacific Ocean (Invited)

    NASA Astrophysics Data System (ADS)

    Huber, J. A.; Merkel, A.; Holden, J. F.; Lilley, M. D.; Butterfield, D. A.

    2009-12-01

    Methanogenesis is thought to represent one of the most ancient metabolic pathways on Earth, and methanogens may serve as important primary producers in warm crustal habitats at deep-sea hydrothermal vents. Many of these obligate chemolithoautotrophs depend solely on geochemically-derived energy and carbon sources and grow at high temperatures under strictly anaerobic conditions. A combined geochemical and microbiological approach was used to determine the distribution and molecular diversity of methanogens in low temperature diffuse vent fluids from the Endeavour Segment R2K ISS site, as well as Axial Seamount and volcanoes of the Mariana Arc. Geochemical data from hot and adjacent warm diffuse vent fluids provided chemical indicators to guide sample selection for detailed polymerase chain reaction (PCR)-based analysis of the key enzyme for methane formation, methyl-coenzyme M reductase (mcrA), as well as archaeal 16S rRNA genes. At most Endeavour vent sites, hydrogen concentrations were too low to support hydrogenotrophic methanogensis directly and only one diffuse site, Easter Island, had a positive signal for the mcrA gene. These sequences were most closely related to members of the order Methanococcales, as well as anaerobic methane oxidizers (ANME-1). The presence of ANME, which are rarely found in non-sedimented marine environments, is another line of evidence supporting the occurrence of buried sediments at Endeavour. At Axial, a number of diffuse vents have strong chemical indicators of methanogenesis. Methanogenic communities were detected at 3 sites on the southeast side of the caldera: the northern end of the 1998 lava flow, the International District, and on the pre-1987 lava flow. Time series work at Marker 113 showed that in 4 different years over the last 6 years methanogenic communities are active and abundant, suggesting a stable anaerobic, warm subseafloor habitat. Results show that members of the order Methanococcales dominate at this site

  14. Evidence for Long-Time Scale ( > 103 years) Changes in Hydrothermal Activity Induced By Seismic Events

    NASA Astrophysics Data System (ADS)

    Person, M. A.; Howald, T.; Campbell, A.; Hofstra, A.; Lueth, V.; Sweetkind, D. S.; Gable, C. W.; Luijendijk, E.; Crossey, L. J.; Karlstrom, K. E.; Kelley, S.; Phillips, F. M.

    2014-12-01

    The typical approach to assess climate change impacts on water resources systems is based on a vertical integration/coupling of models: GCM models are run to project future precipitations and temperatures, which are then downscaled and used as inputs to hydrologic models whose outputs are processed by water systems models. From a decision-making point of view, this top-down vertical approach presents some challenges. For example, since the range of uncertainty that can be explored with GCM is limited, researchers are relying on ensembles to enlarge the spread, making the modeling approach even more demanding in terms of computation time and resource. When a particular water system must be analyzed, the question is to know whether this computationally intensive vertical approach is necessary in the first place or if we could extrapolate projections available in neighboring systems to feed the water system model? This would be equivalent to a horizontal approach. The proposed study addresses this question by comparing the performance of a water resource system under future climate conditions using the vertical and horizontal approaches. The methodology is illustrated with the hydropower system of the Gatineau River Basin in Quebec, Canada. Vertically obtained hydrologic projections available in those river basins are extrapolated and used as inputs to a stochastic multireservoir optimization model. Two different extrapolation techniques are tested. The first one simply relies on the ratios between the drainage areas. The second exploits the covariance structure found in historical flow data throughout the region. The analysis of the simulation results reveals that the annual and weekly energy productions of the system derived from the horizontal approach are statistically equivalent to those obtained with the vertical one, regardless of the extrapolation technique used.

  15. Shallow submarine hydrothermal activity with significant contribution of magmatic water producing talc chimneys in the Wakamiko Crater of Kagoshima Bay, southern Kyushu, Japan

    NASA Astrophysics Data System (ADS)

    Yamanaka, Toshiro; Maeto, Kotaro; Akashi, Hironori; Ishibashi, Jun-Ichiro; Miyoshi, Youko; Okamura, Kei; Noguchi, Takuroh; Kuwahara, Yoshihiro; Toki, Tomohiro; Tsunogai, Urumu; Ura, Tamaki; Nakatani, Takeshi; Maki, Toshihiro; Kubokawa, Kaoru; Chiba, Hitoshi

    2013-05-01

    Active hydrothermal venting from shallow seafloor (200-m depth) with talc chimneys has been discovered at the Wakamiko Crater floor in the Aira Caldera, southern Kyushu, Japan. The major chemical composition of the fluids suggests that the fluids are supplied from a single reservoir. The fluid is characterized by a low chloride concentration, low δD value, and a high δ18O value, suggesting that the endmember hydrothermal fluid is a mixture of seawater and andesitic water and possibly contribution of meteoric water and/or phase separation. Such noticeable magmatic input may be supported by high helium isotopic ratio (6.77 RA) of fumarolic gas discharging from the crater. Silica and alkaline geothermometers indicate that the fluid-rock interaction in the reservoir occurs in the temperature range of 230 to 250 °C. The high alkalinity and high ammonium and dissolved organic matter concentrations in the fluid indicate interaction of the fluid with organic matter in sedimentary layers. At least three hydrothermal vents have been observed in the crater. Two of these have similar cone-shaped chimneys. The chimneys have a unique mineralogy and consist dominantly of talc (kerolite and hydrated talc) with lesser amounts of carbonate (dolomite and magnesite), anhydrite, amorphous silica, and stibnite. The precipitation temperature estimated from δ18O values of talc was almost consistent with the observed fluid temperature. Geochemical modeling calculations also support the formation of talc and carbonate upon mixing of the endmember hydrothermal fluid with seawater and suggest that the talc chimneys are currently growing from venting fluid.

  16. Hydrothermal alteration of surficial rocks at Solfatara (Campi Flegrei): Petrophysical properties and implications for phreatic eruption processes

    NASA Astrophysics Data System (ADS)

    Mayer, Klaus; Scheu, Bettina; Montanaro, Cristian; Yilmaz, Tim I.; Isaia, Roberto; Aßbichler, Donjá; Dingwell, Donald B.

    2016-06-01

    Solfatara crater is located within the Campi Flegrei caldera to the west of Naples (Italy). It is one of the largest fumarolic manifestations known, and the rocks hosting the hydrothermal system are affected by intense hydrothermal alteration. Alteration can result in changes of degassing behavior, and in the formation of a cap rock thereby increasing the probability of phreatic eruptions. Here, we investigate the effects of alunitic (solfataric) alteration on the mineralogy, the physical properties (porosity, density, permeability) and the mechanical properties (strength) of the rocks involved, as well as its influence on fragmentation and ejection behavior. Our results show that the pristine mineralogy of deposits from the vicinity of the Solfatara cryptodome and from Pisciarelli is almost completely replaced by amorphous silica and alunite. The differences in the degree of alteration among the samples series are reflected in the investigated properties and behavior as well as in the analysis of the experimentally generated particles. Alunitic alteration increases porosity and permeability, whereas it reduces density, elastic wave velocity and strength leading to higher fragmentation and ejection speeds for the sample series examined in this study. Our results also show that alteration results in the generation of a high fraction of fines (particle sizes < 10 μm) during fragmentation, mainly composed of alunite crystals. Due to their potential for inducing chronic disease, dispersion of such material should represent a serious health hazard on a local scale and the evaluation of precautions should be considered.

  17. Transport and deposition processes of the hydrothermal blast of the 6 August 2012 Te Maari eruption, Mt. Tongariro

    NASA Astrophysics Data System (ADS)

    Breard, E. C. P.; Lube, G.; Cronin, S. J.; Valentine, G. A.

    2015-11-01

    The 2012 eruption of Tongariro volcano (New Zealand) produced highly mobile, low-temperature, blast-derived pyroclastic density currents after partial collapse of the western flank of the Upper Te Maari crater. Despite a low volume (340,000 m3), the flows traveled up to 2.5 km from source, covering a total area of 6.1 km2. Along one of the blast axes, freshly exposed, proximal-to-distal sedimentary structures and grain-size data suggest emplacement of the fining upward tripartite depositional sequence (massive, stratified, and laminated) under a dilute and strongly longitudinally zoned turbulent density current. While the zoning formed in the deposit in the first 1500 m of runout, the current progressively waned to the extent where it transported a nearly homogenous grain-size mixture at the liftoff position. Our data indicate that after the passage of an erosive flow front, massive unit A was deposited under a rapid-suspension sedimentation regime. Unit B was deposited under a traction-dominated regime generated by a subsequent portion of the flow moving at lower velocities and with lower sediment transport capacity than the portion depositing unit A. The final and slowest flow zone deposited the finest particles under weakly tractive conditions. Transport and emplacement dynamics inferred in this study show strong similarities between hydrothermal explosions, magmatic blasts, and high-energy dilute PDCs. The common occurrence of hydrothermal fields on volcanic flanks points to this hazard being an under-appreciated one at stratovolcanoes worldwide.

  18. Hydrothermal liquefaction of freshwater and marine algal biomass: A novel approach to produce distillate fuel fractions through blending and co-processing of biocrude with petrocrude.

    PubMed

    Lavanya, Melcureraj; Meenakshisundaram, Arunachalam; Renganathan, Sahadevan; Chinnasamy, Senthil; Lewis, David Milton; Nallasivam, Jaganathan; Bhaskar, Sailendra

    2016-03-01

    Biocrude was produced from Tetraselmis sp. - a marine alga and Arthrospira platensis - a fresh water alga using hydrothermal liquefaction (HTL) process. Considering the constraints in cultivating algae for replacing 100% petrocrude, this study evaluated the option of blending and co-processing algal biocrude with petrocrude. Biocrudes obtained from algal strains cultivated in fresh water and sea water were blended with petrocrude at 10% concentration and the characteristics were studied using FT-IR and CNS SIMDIST. True Boiling Point (TBP) distillation was carried out to assess yields and properties of distillates of blended biocrudes. Biocrudes obtained from both algae were light crudes and the blended crudes recorded distillate yields of 76-77 wt%. The yield of light naphtha fraction of biocrude blends was 29-30%; whereas the yield of diesel fraction was about 18%. This study proposes blending and co-processing of algal biocrude with petrocrude to produce drop-in biofuels. PMID:26735877

  19. Hydrothermal liquefaction of freshwater and marine algal biomass: A novel approach to produce distillate fuel fractions through blending and co-processing of biocrude with petrocrude.

    PubMed

    Lavanya, Melcureraj; Meenakshisundaram, Arunachalam; Renganathan, Sahadevan; Chinnasamy, Senthil; Lewis, David Milton; Nallasivam, Jaganathan; Bhaskar, Sailendra

    2016-03-01

    Biocrude was produced from Tetraselmis sp. - a marine alga and Arthrospira platensis - a fresh water alga using hydrothermal liquefaction (HTL) process. Considering the constraints in cultivating algae for replacing 100% petrocrude, this study evaluated the option of blending and co-processing algal biocrude with petrocrude. Biocrudes obtained from algal strains cultivated in fresh water and sea water were blended with petrocrude at 10% concentration and the characteristics were studied using FT-IR and CNS SIMDIST. True Boiling Point (TBP) distillation was carried out to assess yields and properties of distillates of blended biocrudes. Biocrudes obtained from both algae were light crudes and the blended crudes recorded distillate yields of 76-77 wt%. The yield of light naphtha fraction of biocrude blends was 29-30%; whereas the yield of diesel fraction was about 18%. This study proposes blending and co-processing of algal biocrude with petrocrude to produce drop-in biofuels.

  20. Hydrothermal systems and volcano geochemistry

    USGS Publications Warehouse

    Fournier, R.O.

    2007-01-01

    The upward intrusion of magma from deeper to shallower levels beneath volcanoes obviously plays an important role in their surface deformation. This chapter will examine less obvious roles that hydrothermal processes might play in volcanic deformation. Emphasis will be placed on the effect that the transition from brittle to plastic behavior of rocks is likely to have on magma degassing and hydrothermal processes, and on the likely chemical variations in brine and gas compositions that occur as a result of movement of aqueous-rich fluids from plastic into brittle rock at different depths. To a great extent, the model of hydrothermal processes in sub-volcanic systems that is presented here is inferential, based in part on information obtained from deep drilling for geothermal resources, and in part on the study of ore deposits that are thought to have formed in volcanic and shallow plutonic environments.

  1. Variability in the microbial communities and hydrothermal fluid chemistry at the newly discovered Mariner hydrothermal field, southern Lau Basin

    NASA Astrophysics Data System (ADS)

    Takai, Ken; Nunoura, Takuro; Ishibashi, Jun-Ichiro; Lupton, John; Suzuki, Ryohei; Hamasaki, Hiroshi; Ueno, Yuichiro; Kawagucci, Shinsuke; Gamo, Toshitaka; Suzuki, Yohey; Hirayama, Hisako; Horikoshi, Koki

    2008-06-01

    A newly discovered hydrothermal field called the Mariner field on the Valu Fa Ridge in the southern Lau Basin was explored and characterized with geochemical and microbiological analyses. The hydrothermal fluid discharging from the most vigorous vent (Snow Chimney, maximum discharge temperature 365°C) was boiling at the seafloor at a depth of 1908 m, and two distinct end-member hydrothermal fluids were identified. The fluid chemistry of the typical Cl-enriched and Cl-depleted hydrothermal fluids was analyzed, as was the mineralogy of the host chimney structures. The variability in the fluid chemistry was potentially controlled by the subseafloor phase-separation (vapor loss process) and the microbial community activities. Microbial community structures in three chimney structures were investigated using culture-dependent and -independent techniques. The small subunit (SSU) rRNA gene clone analysis revealed that both bacterial and archaeal rRNA gene communities on the chimney surfaces differed among three chimneys. Cultivation analysis demonstrated significant variation in the culturability of various microbial components among the chimneys, particularly of thermophilic H2-oxidizing (and S-oxidizing) chemolithoautotrophs such as the genera Aquifex and Persephonella. The physical and chemical environments of chimney surface habitats are still unresolved and do not directly extrapolate the environments of possible subseafloor habitats. However, the variability in microbial community found in the chimneys also provides an insight into the different biogeochemical interactions potentially affected by the phase separation of the hydrothermal fluids in the subseafloor hydrothermal habitats. In addition, comparison with other deep-sea hydrothermal systems revealed that the Mariner field microbial communities have unusual characteristics.

  2. Geochemical constraints on chemolithoautotrophic reactions in hydrothermal systems

    NASA Technical Reports Server (NTRS)

    Shock, Everett L.; Mccollom, Thomas; Schulte, Mithell D.

    1995-01-01

    Thermodynamic calculations provide the means to quantify the chemical disequilibrium inherent in the mixing of reduced hydrothermal fluids with seawater. The chemical energy available for metabolic processes in these environments can be evaluated by taking into account the pressure and temperature dependence of the apparent standard Gibbs free energies of reactions in the S-H2-H2O system together with geochemical constraints on pH, activities of aqueous sulfur species and fugacities of H2 and/or O2. Using present-day mixing of hydrothermal fluids and seawater as a starting point, it is shown that each mole of H2S entering seawater from hydrothermal fluids represents about 200,000 calories of chemical energy for metabolic systems able to catalyze H2S oxidation. Extrapolating to the early Earth, which was likely to have had an atmosphere more reduced than at present, shows that this chemical energy may have been a factor of two or so less. Nevertheless, mixing of hydrothermal fluids with seawater would have been an abundant source of chemical energy, and an inevitable consequence of the presence of an ocean on an initially hot Earth. The amount of energy available was more than enough for organic synthesis from CO2 or CO, and/or polymer formation, indicating that the vicinity of hydrothermal systems at the sea floor was an ideal location for the emergence of the first chemolithoautotrophic metabolic systems.

  3. Comparison of 14C ages of hydrothermal petroleums

    USGS Publications Warehouse

    Simoneit, B.R.T.; Kvenvolden, K.A.

    1994-01-01

    In order to set limits on the time frame of formation of hydrothermal petroleum, we have obtained 14C ages on samples from three diverse regions; Gulf of California (Guaymas Basin), Northeast Pacific Ocean (Escanaba Trough and Middle Valley), and the East African Rift (Tanganyika Trough). The results date the source of carbon and therefore provide maximum ages for the formation and emplacement of the hydrothermal petroleums. The youngest petroleum occurs iin the Souther Trough of Guaymas Basin (3200-6600 yr, mean 4692 yr); in the Northern Trough the petroleum is slightly older (7400 yr). Significantly older hydrothermal petroleum occurs in Escanaba Trough (17,000 yr) and Middle Valley (29,000 yr). A continental example from the East African Rift has an age of 25,000 yr, comparable to the ages observed in the oceanic samples from the Northeast Pacific Ocean. These ages affirm that hydrothermal petroleum formation is a very rapid process and took place some time between the latest Pleistocene and the present in these active hydrothermal systems. ?? 1994.

  4. Three-dimensional sea-urchin-like hierarchical TiO{sub 2} microspheres synthesized by a one-pot hydrothermal method and their enhanced photocatalytic activity

    SciTech Connect

    Zhou, Yi; Huang, Yan; Li, Dang; He, Wenhong

    2013-07-15

    Graphical abstract: SEM images of the samples synthesized at different hydrothermal temperatures for 8 h: (a) 75; (b) 100; (c) 120; and (d) 140°C, followed by calcination at 450 °C for 2 h. Highlights: ► Effects of calcination temperature on the phase transformation were studied. ► Effects of hydrothermal temperature and time on the morphology growth were studied. ► A two-stage reaction mechanism for the formation was presented. ► The photocatalytic activity was evaluated under sunlight irradiation. ► Effects of calcination temperature on the photocatalytic activity were studied. - Abstract: Novel three-dimensional sea-urchin-like hierarchical TiO{sub 2} superstructures were synthesized on a Ti plate in a mixture of H{sub 2}O{sub 2} and NaOH aqueous solution by a facile one-pot hydrothermal method at a low temperature, followed by protonation and calcination. The results of series of electron microscopy characterizations suggested that the hierarchical TiO{sub 2} superstructures consisted of numerous one-dimensional nanostructures. The microspheres were approximately 2–4 μm in diameter, and the one-dimensional TiO{sub 2} nanostructures were up to 600–700 nm long. A two-stage reaction mechanism, i.e., initial growth and then assembly, was proposed for the formation of these architectures. The three-dimensional sea-urchin-like hierarchical TiO{sub 2} microstructures showed excellent photocatalytic activity for the degradation of Rhodamine B aqueous solution under sunlight irradiation, which was attributed to the special three-dimensional hierarchical superstructure, and increased number of surface active sites. This novel superstructure has promising use in practical aqueous purification.

  5. Lithium manganese oxide (LiMn2O4) nanoparticles synthesized by hydrothermal method as adsorbent of lithium recovery process from geothermal fluid of Lumpur Sidoarjo

    NASA Astrophysics Data System (ADS)

    Noerochim, Lukman; Sapputra, Gede Panca Ady; Widodo, Amien

    2016-04-01

    Lumpur Sidoarjo is one of geothermal fluid types which has a great potential as source of lithium. Adsorption method with Lithium Manganese Oxide (LiMn2O4) as an adsorbent has been chosen for lithium recovery process due to low production cost and environmental friendly. LiMn2O4 was synthesized by hydrothermal method at 200 °C for 24 hrs, 48 hrs, and 72 hrs. As prepared LiMn2O4 powder is treated by acid treatment with 0.5 M HCl solution for 24 hrs. XRD test result reveals that all of as-prepared samples are indexed as spinel structure of LiMn2O4 (JCPDS card no 35-0782) with no impurity peaks detected. SEM images show that LiMn2O4 has nanoparticles morphology with particle size around 25 nm. The highest adsorption efficiency of adsorbent is obtained by sample hydrothermal for 72 hrs with 42.76%.

  6. Hydrothermal Liquefaction of Biomass

    SciTech Connect

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international collaboration with

  7. High-Temperature Hydrothermal Vent Field of Kolumbo Submarine Volcano, Aegean Sea: Site of Active Kuroko-Type Mineralization

    NASA Astrophysics Data System (ADS)

    Sigurdsson, H.; Carey, S.; Alexandri, M.; Vougioukalakis, G.; Croff, K.; Roman, C.; Sakellariou, D.; Anagnostou, C.; Rousakis, G.; Ioakim, C.; Gogou, A.; Ballas, D.; Misaridis, T.; Nomikou, P.

    2006-12-01

    Kolumbo submarine volcano is located 7 km north-east of the island of Santorini in the Hellenic arc (Greece), and comprises one of about twenty submarine cones in a NE-trending rift zone. Kolumbo erupted explosively in 1649-50AD, causing 70 fatalities on Santorini. Kolumbo's crater is 1700 m in diameter, with a crater rim at 10 m below sea level and crater floor at depth of 505 m. Recent marine geological investigations, using ROVs, reveal a very active high-temperature hydrothermal vent field in the northeastern part of the Kolumbo crater floor, about 25,000 m2. Vent chimneys up to 4 m high are vigorously emitting colorless gas plumes up to 10 m high in the water column. Temperatures up to 220oC are recorded in vent fluids. Some vents are in crater- like depressions, containing debris from collapsed extinct chimneys. The entire crater floor of Kolumbo is mantled by a reddish-orange bacterial mat, and bacterial filaments of a variety of colors cling to chimneys in dense clusters. Glassy tunicates and anemones are common in lower-temperature environments on the crater floor. Most chimneys show a high porosity, with a central conduit surrounded by an open and very permeable framework of sulfides and sulfates, aiding fluid flow through the chimney walls. In the sulfate-rich samples, blades of euhedral barite and anhydrite crystals coat the outside of the chimney wall, and layers of barite alternate with sulfide in the interior. The dominant sulfides are pyrite, sphalerite, wurtzite, marcasite and galena. Crusts on extinct and lower-temperature chimneys are composed of amorphous silica, goethite and halite. Sulfur isotope composition of sulfates is virtually at sea water values, whereas the sulfides are more depleted. Elevated levels of copper, gold and silver are observed in bulk composition of chimney samples. Both the structural setting, character of the vent field and sulfide/sulfate mineralogy and geochemistry indicate on-going Kuroko-type mineralization in the

  8. Isotopic signatures associated with growth and metabolic activities of chemosynthetic nitrate-reducing microbes from deep-sea hydrothermal vents

    NASA Astrophysics Data System (ADS)

    Perez-Rodriguez, I. M.; Foustoukos, D.; Fogel, M. L.; Sievert, S. M.

    2013-12-01

    Epsilonproteobacteria and Aquificaceae have been identified as dominant members of microbial communities at deep-sea hydrothermal vents. Cultured representatives from these two groups appear to be mostly genetically wired to perform chemosynthesis at moderate-to-high temperatures (45 - 80oC) under anaerobic and sulfidic conditions. In this study we used Caminibacter mediatlanticus and Thermovibrio ammonificans as model organisms to constrain physiological parameters associated with dissimilatory nitrate reduction to ammonium (DNRA) in deep-sea vent Epsilonproteobacteria and Aquificaceae. We postulate that nitrate-based metabolic processes are of relevance for understanding primary production as well as nitrate mobilization in deep-sea vents. By constraining growth and respiration rates during DNRA, we observed that C. mediatlanticus achieved higher cell densities than T. ammonificans while exhibiting similar growth rates. DNRA kinetic rate constants and cell-specific nitrate reduction rates (csNRR) obtained from our data showed that within similar time frames T. ammonificans used 2.5 to 3 times as much nitrate than C. mediatlanticus and it did so ~3 times faster. However, the increased consumption of nitrate in T. ammonificans did not translate into higher growth yield. This is suggestive of either differential efficiencies in energy generating pathways or differential organic matter production (cell biomass versus extracellular organic material) associated with DNRA in these microorganisms. Nitrogen isotope fractionation for nitrate was similar for both organisms, with discrimination factors of ~ -5 to -6‰ for C. mediatlanticus and ~ -7 to -8‰ for T. ammonificans. Similar experiments performed under high hydrostatic pressure conditions (50 and 200 bar) showed that changes in pressure greatly affected both growth rates and DNRA kinetic rate constants in both microorganisms, however, δ15N discrimination factors for nitrate were not affected. This study provides

  9. Impact-induced hydrothermal activity within the Haughton impact structure, arctic Canada: generation of a transient, warm, wet oasis