Fungal colonization of an Ordovician impact-induced hydrothermal system
Ivarsson, Magnus; Broman, Curt; Sturkell, Erik; Ormö, Jens; Siljeström, Sandra; van Zuilen, Mark; Bengtson, Stefan
2013-01-01
Impacts are common geologic features on the terrestrial planets throughout the solar system, and on at least Earth and Mars impacts have induced hydrothermal convection. Impact-generated hydrothermal systems have been suggested to possess the same life supporting capability as hydrothermal systems associated with volcanic activity. However, evidence of fossil microbial colonization in impact-generated hydrothermal systems is scarce in the literature. Here we report of fossilized microorganisms in association with cavity-grown hydrothermal minerals from the 458 Ma Lockne impact structure, Sweden. Based on morphological characteristics the fossilized microorganisms are interpreted as fungi. We further infer the kerogenization of the microfossils, and thus the life span of the fungi, to be contemporaneous with the hydrothermal activity and migration of hydrocarbons in the system. Our results from the Lockne impact structure show that hydrothermal systems associated with impact structures can support colonization by microbial life. PMID:24336641
Fungal colonization of an Ordovician impact-induced hydrothermal system
NASA Astrophysics Data System (ADS)
Ivarsson, Magnus; Broman, Curt; Sturkell, Erik; Ormö, Jens; Siljeström, Sandra; van Zuilen, Mark; Bengtson, Stefan
2013-12-01
Impacts are common geologic features on the terrestrial planets throughout the solar system, and on at least Earth and Mars impacts have induced hydrothermal convection. Impact-generated hydrothermal systems have been suggested to possess the same life supporting capability as hydrothermal systems associated with volcanic activity. However, evidence of fossil microbial colonization in impact-generated hydrothermal systems is scarce in the literature. Here we report of fossilized microorganisms in association with cavity-grown hydrothermal minerals from the 458 Ma Lockne impact structure, Sweden. Based on morphological characteristics the fossilized microorganisms are interpreted as fungi. We further infer the kerogenization of the microfossils, and thus the life span of the fungi, to be contemporaneous with the hydrothermal activity and migration of hydrocarbons in the system. Our results from the Lockne impact structure show that hydrothermal systems associated with impact structures can support colonization by microbial life.
Fungal colonization of an Ordovician impact-induced hydrothermal system.
Ivarsson, Magnus; Broman, Curt; Sturkell, Erik; Ormö, Jens; Siljeström, Sandra; van Zuilen, Mark; Bengtson, Stefan
2013-12-16
Impacts are common geologic features on the terrestrial planets throughout the solar system, and on at least Earth and Mars impacts have induced hydrothermal convection. Impact-generated hydrothermal systems have been suggested to possess the same life supporting capability as hydrothermal systems associated with volcanic activity. However, evidence of fossil microbial colonization in impact-generated hydrothermal systems is scarce in the literature. Here we report of fossilized microorganisms in association with cavity-grown hydrothermal minerals from the 458 Ma Lockne impact structure, Sweden. Based on morphological characteristics the fossilized microorganisms are interpreted as fungi. We further infer the kerogenization of the microfossils, and thus the life span of the fungi, to be contemporaneous with the hydrothermal activity and migration of hydrocarbons in the system. Our results from the Lockne impact structure show that hydrothermal systems associated with impact structures can support colonization by microbial life.
Hydrothermal activity at slow-spreading ridges: variability and importance of magmatic controls
NASA Astrophysics Data System (ADS)
Escartin, Javier
2016-04-01
Hydrothermal activity along mid-ocean ridge axes is ubiquitous, associated with mass, chemical, and heat exchanges between the deep lithosphere and the overlying envelopes, and sustaining chemiosynthetic ecosystems at the seafloor. Compared with hydrothermal fields at fast-spreading ridges, those at slow spreading ones show a large variability as their location and nature is controlled or influenced by several parameters that are inter-related: a) tectonic setting, ranging from 'volcanic systems' (along the rift valley floor, volcanic ridges, seamounts), to 'tectonic' ones (rift-bounding faults, oceanic detachment faults); b) the nature of the host rock, owing to compositional heterogeneity of slow-spreading lithosphere (basalt, gabbro, peridotite); c) the type of heat source (magmatic bodies at depth, hot lithosphere, serpentinization reactions); d) and the associated temperature of outflow fluids (high- vs.- low temperature venting and their relative proportion). A systematic review of the distribution and characteristics of hydrothermal fields along the slow-spreading Mid-Atlantic Ridge suggests that long-lived hydrothermal activity is concentrated either at oceanic detachment faults, or along volcanic segments with evidence of robust magma supply to the axis. A detailed study of the magmatically robust Lucky Strike segment suggests that all present and past hydrothermal activity is found at the center of the segment. The association of these fields to central volcanos, and the absence of indicators of hydrothermal activity along the remaining of the ridge segment, suggests that long-lived hydrothermal activity in these volcanic systems is maintained by the enhanced melt supply and the associated magma chamber(s) required to build these volcanic edifices. In this setting, hydrothermal outflow zones at the seafloor are systematically controlled by faults, indicating that hydrothermal fluids in the shallow crust exploit permeable fault zones to circulate. While less studied, similar hydrothermal systems are found elsewhere associated to other central volcanoes along the ridge axis (e.g., Menez Gwenn at the Mid-Atlantic Ridge and Soria Mornia or Troll Wall at the Arctic Ridges). Long-lived hydrothermal activity plays an important role in controlling the thermal structure of the lithosphere and its accretion at and near-axis, and also determining the distribution and biogeography of vent communities. Along slow-spreading segments, long-lived hydrothermal activity can be provided both by volcanic systems (e.g., Lucky Strike) and tectonic systems (oceanic detachment faults). While magmatic and hydrothermal activity is relatively well understood now in volcanic systems (e.g., Lucky Strike), tectonic systems (oceanic detachment faults) require further integrated studies to constrain the links between long-lived localization of deformation along oceanic detachment faults, hydrothermal activity, and origin and nature of off-axis heat sources animating hydrothermal circulation.
Organic matter in hydrothermal metal ores and hydrothermal fluids
Orem, W.H.; Spiker, E. C.; Kotra, R.K.
1990-01-01
Massive polymetallic sulfides are currently being deposited around active submarine hydrothermal vents associated with spreading centers. Chemoautolithotrophic bacteria are responsible for the high production of organic matter also associated with modern submarine hydrothermal activity. Thus, there is a significant potential for organic matter/metal interactions in these systems. We have studied modern and ancient hydrothermal metal ores and modern hydrothermal fluids in order to establish the amounts and origin of the organic matter associated with the metal ores. Twenty-six samples from modern and ancient hydrothermal systems were surveyed for their total organic C contents. Organic C values ranged from 0.01% to nearly 4.0% in these samples. Metal ores from modern and ancient sediment-covered hydrothermal systems had higher organic C values than those from modern and ancient hydrothermal systems lacking appreciable sedimentary cover. One massive pyrite sample from the Galapagos spreading center (3% organic C) had stable isotope values of -27.4% (??13C) and 2.1% (??15N), similar to those in benthic siphonophors from active vents and distinct from seep sea sedimentary organic matter. This result coupled with other analyses (e.g. 13C NMR, pyrolysis/GC, SEM) of this and other samples suggests that much of the organic matter may originate from chemoautolithotrophic bacteria at the vents. However, the organic matter in hydrothermal metal ores from sediment covered vents probably arises from complex sedimentary organic matter by hydrothermal pyrolysis. The dissolved organic C concentrations of hydrothermal fluids from one site (Juan de Fuca Ridge) were found to be the same as that of background seawater. This result may indicate that dissolved organic C is effectively scavenged from hydrothermal fluids by biological activity or by co-precipitation with metal ores. ?? 1990.
NASA Astrophysics Data System (ADS)
Taran, Yuri; Tassi, Franco; Varekamp, Johan; Inguaggiato, Salvatore; Kalacheva, Elena
2017-10-01
Many volcanoes at any tectonic settings host hydrothermal systems. Volcano-hydrothermal systems (VHS) are result of interaction of the upper part of plumbing systems of active volcanoes with crust, hydrosphere and atmosphere. They are heated by magma, fed by magmatic fluids and meteoric (sea) water, transport and re-distribute magmatic and crustal material. VHS are sensitive to the activity of a host volcano. VHS may have specific features depending on the regional and local tectonic, geologic and geographic settings. The studies reported in this volume help to illustrate the diversity of the approaches and investigations that are being conducting at different volcano-hydrothermal systems over the world and the results of which will be of important value in furthering our understanding of the complex array of the processes accompanying hydrothermal activity of volcanoes. About 60 papers were submitted to a special session of "Volcano-Hydrothermal Systems" at the 2015 fall meeting of the American Geophysical Union. The papers in this special issue of the Journal of Volcanology and Geothermal Research were originally presented at that session.
Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.
2009-01-01
Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confi ning pressure causes fluids to fl ash to steam, resulting in signifi cant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially signifi cant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identifi ed; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ??1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing and vein-fi lling; and (5) areal dimensions of many large hydrothermal explosion craters in Yellowstone are similar to those of its active geyser basins and thermal areas. For Yellowstone, our knowledge of hydrothermal craters and ejecta is generally limited to after the Yellowstone Plateau emerged from beneath a late Pleistocene icecap that was roughly a kilometer thick. Large hydrothermal explosions may have occurred earlier as indicated by multiple episodes of cementation and brecciation commonly observed in hydrothermal ejecta clasts. Critical components for large, explosive hydrothermal systems include a watersaturated system at or near boiling temperatures and an interconnected system of well-developed joints and fractures along which hydrothermal fluids flow. Active deformation of the Yellowstone caldera, active faulting and moderate local seismicity, high heat flow, rapid changes in climate, and regional stresses are factors that have strong infl uences on the type of hydrothermal system developed. Ascending hydrothermal fluids flow along fractures that have developed in response to active caldera deformation and along edges of low-permeability rhyolitic lava flows. Alteration of the area affected, self-sealing leading to development of a caprock for the hydrothermal system, and dissolution of silica-rich rocks are additional factors that may constrain the distribution and development of hydrothermal fields. A partial lowpermeability layer that acts as a cap to the hydrothermal system may produce some over-pressurization, thought to be small in most systems. Any abrupt drop in pressure initiates steam fl ashing and is rapidly transmitted through interconnected fractures that result in a series of multiple large-scale explosions contributing to the excavation of a larger explosion crater. Similarities between the size and dimensions of large hydrothermal explosion craters and thermal fields in Yellowstone may indicate that catastrophic events which result in l
Gieskes, J.M.; Simoneit, B.R.T.; Shanks, Wayne C.; Goodfellow, W.D.; James, R.H.; Baker, P.A.; Ishibashi, J.-I.
2002-01-01
Geochemical and isotopic studies of pore fluids and solid phases recovered from the Dead Dog and Bent Hill hydrothermal sites in Middle Valley (Ocean Drilling Program Leg 169) have been compared with similar data obtained previously from these sites during Ocean Drilling Program Leg 139. Although generally the hydrothermal systems reflect non-steady state conditions, the data allow an assessment of the history of the hydrothermal processes. Sediment K/A1 ratios as well as the distribution of anhydrite in the sediments suggest that the Dead Dog hydrothermal field has been, and still is, active. In contrast, similar data in the Bent Hill hydrothermal field indicate a waning of hydrothermal activity. Pore fluid and hydrothermal vent data in the Dead Dog hydrothermal field are similar in nature to the data collected during ODP Leg 139. In the area of the Bent Hill sulfide deposit, however, the pore water data indicate that recent wholesale flushing of the sediment column with relatively unaltered seawater has obliterated a previous record of hydrothermal activity in the pore fluids. Data from the deepest part of Hole 1035A in the Bent Hill locality show the presence of hydrothermal fluids at greater depths in this area. This suggests the origin of the hydrothermal fluids found to be emanating from Hole 1035F, which constitutes one of the first man made hydrothermal vents in the Middle Valley hydrothermal system. Similarly, CORKed Hole 858G, because of seal failures, has acted as a hydrothermal vent, with sulfide deposits forming inside the CORK. ?? 2002 Elsevier Science Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Han, C.; Wu, G.; Qin, H.; Wang, Z.
2012-12-01
Investigation of active hydrothermal mound as well as non-active massive sulfide mound are studied recently. However, there is still lack of in-situ detection method for the non-active massive sulfide mound. Even though Transient ElectroMagnetic (TEM) and Electric Self-potential (SP) methods are good, they both are labour, time and money cost work. We proposed a new multiparameter chemical sensor method to study the seafloor active hydrothermal mound as well as non-active massive sulfide mound. This sensor integrates Eh, S2- ions concentration and pH electrochemical electrodes together, and could found chemical change caused by the active hydrothermal vent, even weak chemical abnormalities by non-active massive sulfide hydrothermal mound which MARP and CTD sometimes cannot detect. In 2012, the 1st Leg of the Chinese 26th cruise, the multiparameter chemical sensor was carried out with the deepsea camera system over the Carlsberg Ridge in Indian Ocean by R/V DAYANGYIHAO. It was shown small Eh and S2- ions concentration abnormal around a site at Northwest Indian ridge. This site was also evidenced by the TV grab. In the 2nd Leg of the same cruise in June, this chemical sensor was carried out with TEM and SP survey system. The chemical abnormalities are matched very well with both TEM and SP survey results. The results show that the multiparameter chemical sensor method not only can detect active hydrothermal mound, but also can find the non-active massive sulfide hydrothermal mound.
Impact Crater Hydrothermal Niches for Life on Mars: Question of Scale
NASA Technical Reports Server (NTRS)
Pope, K. O.; Ames, D. E.; Kieffer, S. W.; Ocampo, A. C.
2000-01-01
A major focus in the search for fossil life on Mars is on ancient hydrothermal deposits. Nevertheless, remote sensing efforts have not found mineral assemblages characteristic of hydrothermal activity. Future remote sensing work, including missions with higher spatial resolution, may detect localized hydrothermal deposits, but it is possible that dust mantles will prohibit detection from orbit and lander missions will be required. In anticipation of such missions, it is critical to develop a strategy for selecting potential hydrothermal sites on Mars. Such a strategy is being developed for volcanogenic hydrothermal systems, and a similar strategy is needed for impact hydrothermal systems.
Dynamics of the Yellowstone hydrothermal system
Hurwitz, Shaul; Lowenstern, Jacob B.
2014-01-01
The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.
Water column imaging on hydrothermal vent in Central Indian Ridge
NASA Astrophysics Data System (ADS)
Koh, J.; Park, Y.
2017-12-01
Water column imaging with Multibeam echosounder systems (MBES) is recently becoming of increasing interest for oceanographic studies. Especially gas bubbles and hot water exposed from hydrothermal vents make acoustic impedance anomalies in cold seawater, water column imaging is very useful for the researchers who want to detect some kinds of hydrothermal activity. We conducted a hydrothermal exploration program, called "INVENT17", using the MBES system, KONGBERG EM122 (12kHz, 1°×1°), mounted on R/V ISABU and we deployed other equipments including video guided hydraulic grab, tow-yo CTD and general CTD with MAPR (Miniature Autonomous Plume Recorder) in 2017. First, to evaluate its capabilities of detection of hydrothermal vent, the surveys using the MBES were conducted at the Solitaire Field, previously identified hydrothermal area of the Central Indian Ridge. The bathymetric data obtained from MBES provided information about detailed morphology of seafloor, but we were not able to achieve the information from the water column imaging data. But the clue of existence of active hydrothermal vent was detected through the values of ΔNTU, dEh/dt, and OPR gained from MAPR, the data means that the hydrothermal activity affects 100m from the seafloor. It could be the reason that we can't find the hydrothermal activity because the range resolution of water column imaging is pretty rough so that the size of 100m-scaled activity has low possibility to distinguish from seafloor. The other reason is there are no sufficient objects to cause strong scattering like as CO2 bubbles or droplets unlike in the mid-Okinawa Trough. And this suggests that can be a important standard to identify properties of hydrothermal vent sites depending on the presence of scattering objects in water mass. To justify this, we should perform more chemical analysis of hot water emanating from hydrothermal vent and collected several bottles of water sample to do that.
A biographical memoir of Donald Edward White
Muffler, L. J. Patrick
2016-01-01
Donald E. White was a leading scientist for the U.S. Geological Survey, where his career was devoted almost entirely to the study of hydrothermal processes in the Earth’s crust, from the dual perspectives of active geothermal systems and of extinct hydrothermal systems now represented only by ore deposits and alteration patterns. White was devoted to analyzing the mechanisms by which ore-forming metals are concentrated, transported, and deposited. His early work on antimony deposits and on mercury transport led to the understanding that these elements, as well as some precious metals, were concentrated in hydrothermal convection systems characterized by dilute chloride waters of predominantly meteoric origin. He concluded, on the other hand, that base metals required more concentrated brines, as was impressively confirmed in the early 1960s by the discovery of the metal-rich fluids of the Salton Sea geothermal system and subsequently by the recognition of sulfide-depositing hydrothermal systems on the sea floor. His studies of active hot-spring systems elucidated the principles of geyser activity and provided the scientific foundation for research programs aimed at the understanding of geothermal systems throughout the world.
The hydrothermal evolution of the Kawerau geothermal system, New Zealand
NASA Astrophysics Data System (ADS)
Milicich, S. D.; Chambefort, I.; Wilson, C. J. N.; Charlier, B. L. A.; Tepley, F. J.
2018-03-01
Hydrothermal alteration zoning and processes provide insights into the evolution of heat source(s) and fluid compositions associated with geothermal systems. Traditional petrological techniques, combined with hydrothermal alteration studies, stable isotope analyses and geochronology can resolve the nature of the fluids involved in hydrothermal processes and their changes through time. We report here new findings along with previous unpublished works on alteration patterns, fluid inclusion measurements and stable isotope data to provide insights into the thermal and chemical evolution of the Kawerau geothermal system, New Zealand. These data indicate the presence of two hydrothermal events that can be coupled with chronological data. The earlier period of hydrothermal activity was initiated at 400 ka, with the heat driving the hydrothermal system inferred to be from the magmatic system that gave rise to rhyolite lavas and sills of the Caxton Formation. Isotopic data fingerprint fluids attributed to this event as meteoric, indicating that the magma primarily served as a heat source driving fluid circulation, and was not releasing magmatic fluids in sufficient quantity to affect the rock mineralogy and thus inferred fluid compositions. The modern Kawerau system was initiated at 16 ka with hydrothermal eruptions linked to shallow intrusion of magma at the onset of activity that gave rise to the Putauaki andesite cone. Likely associated with this later event was a pulse of magmatic CO2, resulting in large-scale deposition of hydrothermal calcite enriched in 18O. Meteoric water-dominated fluids subsequently overwhelmed the magmatic fluids associated with this 18O-rich signature, and both the fluid inclusion microthermometry and stable isotope data reflect a change to the present-day fluid chemistry of low salinity, meteoric-dominated waters.
Microbial processing of carbon in hydrothermal systems (Invited)
NASA Astrophysics Data System (ADS)
LaRowe, D.; Amend, J. P.
2013-12-01
Microorganisms are known to be active in hydrothermal systems. They catalyze reactions that consume and produce carbon compounds as a result of their efforts to gain energy, grow and replace biomass. However, the rates of these processes, as well as the size of the active component of microbial populations, are poorly constrained in hydrothermal environments. In order to better characterize biogeochemical processes in these settings, a quantitative relationship between rates of microbial catalysis, energy supply and demand and population size is presented. Within this formulation, rates of biomass change are determined as a function of the proportion of catabolic power that is converted into biomass - either new microorganisms or the replacement of existing cell components - and the amount of energy that is required to synthesize biomass. The constraints that hydrothermal conditions place on power supply and demand are explicitly taken into account. The chemical composition, including the concentrations of organic compounds, of diffuse and focused flow hydrothermal fluids, hydrothermally influenced sediment pore water and fluids from the oceanic lithosphere are used in conjunction with cell count data and the model described above to constrain the rates of microbial processes that influence the carbon cycle in the Juan de Fuca hydrothermal system.
600 kyr of Hydrothermal Activity on the Cleft Segment of the Juan de Fuca Ridge
NASA Astrophysics Data System (ADS)
Middleton, J. L.; Mukhopadhyay, S.; Langmuir, C. H.; Costa, K.; McManus, J. F.; Katz, R. F.; Huybers, P. J.; Winckler, G.; Li, Y.
2017-12-01
Pressure fluctuations caused by glacially driven variations in sea level may modulate magmatic and hydrothermal output at submarine volcanic centers, with falling sea level driving increased volcanic activity. In turn, glacially paced changes in submarine volcanism could induce globally synchronous variations in the delivery of bioavailable iron and CO2 from mid-ocean ridges and thus provide solid-Earth feedbacks into the climate system. While evaluation of submarine volcanic output on orbital-timescales is technically challenging, near-ridge sediment cores hosting hydrothermal plume precipitates provide continuous, spatially integrated, and datable records to investigate the long-term behavior of hydrothermal systems. We will present new sedimentary records of hydrothermal variability spanning the past 600 kyr on the Cleft Segment of the Juan de Fuca Ridge in the Northeast Pacific. As an intermediate spreading-rate ridge, the Juan de Fuca Ridge is hypothesized to be particularly sensitive to sea level forcing at the Milankovitch frequencies of Pleistocene glacial cycles. Thus, the new records can be used to examine the connection between sea level and hydrothermal activity over multiple glacial cycles. Hydrothermal input is determined from iron and copper, with a titanium-based correction for lithogenic contributions. Sedimentary fluxes are then constrained using excess thorium-230 and extraterrestrial helium-3 as constant flux proxies. Preliminary results indicate 10-fold changes in hydrothermal iron and copper fluxes over the past 600 kyr and suggest a quasiperiodic variability in hydrothermal deposition on 100 to 120 kyr cycles. Comparison of the Juan de Fuca record with model predictions for an intermediate spreading ridge forced by Pleistocene glacial cycles finds frequent coincidence between predicted positive anomalies in magmatic output and observed peaks in hydrothermal deposition. This work encourages the continued exploration of the relationship between glacial cycles and submarine volcanic activity.
NASA Technical Reports Server (NTRS)
Fu, Qi; Socki, Richard A.; Niles, Paul B.; Romanek, Christopher; Datta, Saugata; Darnell, Mike
2012-01-01
Hydrothermal systems on Earth are active centers in the crust where organic molecules can be synthesized biotically or abiotically under a wide range of physical and chemical conditions [1-3]. Not only are volatile species (CO, CO2, H2, and hydrocarbons) a reflection of deep-seated hydrothermal alteration processes, but they also form an important component of biological systems. Studying carbon-bearing fluids from hydrothermal systems is of specific importance to understanding (bio-)geochemical processes within these systems. With recent detection of methane in the martian atmosphere [4-7] and the possibility of its hydrothermal origin [8, 9], understanding the formation mechanisms of methane may provide constraints on the history of the martian aqueous environments and climate.
Characteristics of Hydrothermal Mineralization in Ultraslow Spreading Ridges
NASA Astrophysics Data System (ADS)
Zhou, H.; Yang, Q.; Ji, F.; Dick, H. J.
2014-12-01
Hydrothermal activity is a major component of the processes that shape the composition and structure of the ocean crust, providing a major pathway for the exchange of heat and elements between the Earth's crust and oceans, and a locus for intense biological activity on the seafloor and underlying crust. In other hand, the structure and composition of hydrothermal systems are the result of complex interactions between heat sources, fluids, wall rocks, tectonic controls and even biological processes. Ultraslow spreading ridges, including the Southwest Indian Ridge, the Gakkel Ridge, are most remarkable end member in plate-boundary structures (Dick et al., 2003), featured with extensive tectonic amagmatic spreading and frequent exposure of peridotite and gabbro. With intensive surveys in last decades, it is suggested that ultraslow ridges are several times more effective than faster-spreading ridges in sustaining hydrothermal activities. This increased efficiency could attributed to deep mining of heat and even exothermic serpentinisation (Baker et al., 2004). Distinct from in faster spreading ridges, one characteristics of hydrothermal mineralization on seafloor in ultraslow spreading ridges, including the active Dragon Flag hydrothermal field at 49.6 degree of the Southwest Indian Ridge, is abundant and pervasive distribution of lower temperature precipitated minerals ( such as Fe-silica or silica, Mn (Fe) oxides, sepiolite, pyrite, marcasite etc. ) in hydrothermal fields. Structures formed by lower temperature activities in active and dead hydrothermal fields are also obviously. High temperature precipitated minerals such as chalcopyrite etc. are rare or very limited in hydrothermal chimneys. Distribution of diverse low temperature hydrothermal activities is consistence with the deep heating mechanisms and hydrothermal circulations in the complex background of ultraslow spreading tectonics. Meanwhile, deeper and larger mineralization at certain locations along the ultraslow spreading ridges is also presumable.
Schrenk, Matthew O; Kelley, Deborah S; Bolton, Sheryl A; Baross, John A
2004-10-01
The recently discovered Lost City Hydrothermal Field (LCHF) represents a new type of submarine hydrothermal system driven primarily by exothermic serpentinization reactions in ultramafic oceanic crust. Highly reducing, alkaline hydrothermal environments at the LCHF produce considerable quantities of hydrogen, methane and organic molecules through chemo- and biosynthetic reactions. Here, we report the first analyses of microbial communities inhabiting carbonate chimneys awash in warm, high pH fluids at the LCHF and the predominance of a single group of methane-metabolizing Archaea. The predominant phylotype, related to the Methanosarcinales, formed tens of micrometre-thick biofilms in regions adjacent to hydrothermal flow. Exterior portions of active structures harboured a diverse microbial community composed primarily of filamentous Eubacteria that resembled sulphide-oxidizing species. Inactive samples, away from regions of hydrothermal flow, contained phylotypes related to pelagic microorganisms. The abundance of organisms linked to the volatile chemistry at the LCHF hints that similar metabolic processes may operate in the subseafloor. These results expand the range of known geological settings that support biological activity to include submarine hydrothermal systems that are not dependent upon magmatic heat sources.
Ishibashi, J.-I.; Sato, M.; Sano, Y.; Wakita, H.; Gamo, T.; Shanks, Wayne C.
2002-01-01
Ocean Drilling Program (ODP) Leg 169, which was conducted in 1996 provided an opportunity to study the gas geochemistry in the deeper part of the sediment-rich hydrothermal system in Escanaba Trough. Gas void samples obtained from the core liner were analyzed and their results were compared with analytical data of vent fluid samples collected by a submersible dive program in 1988. The gas geochemistry of the pore fluids consisted mostly of a hydrothermal component and was basically the same as that of the vent fluids. The He isotope ratios (R/RA = 5.6-6.6) indicated a significant mantle He contribution and the C isotopic compositions of the hydrocarbons [??13C(CH4) = -43???, ??13C(C2H6) = -20???] were characterized as a thermogenic origin caused by hydrothermal activity. On the other hand, the pore fluids in sedimentary layers away from the hydrothermal fields showed profiles which reflected lateral migration of the hydrothermal hydrocarbons and abundant biogenic CH4. Helium and C isotope systematics were shown to represent a hydrothermal component and useful as indicators for their distribution beneath the seafloor. Similarities in He and hydrocarbon signatures to that of the Escanaba Trough hydrothermal system were found in some terrestrial natural gases, which suggested that seafloor hydrothermal activity in sediment-rich environments would be one of the possible petroleum hydrocarbon generation scenarios in unconventional geological settings. ?? 2002 Elsevier Science Ltd. All rights reserved.
Sulfide geochronlogy along the Southwest Indian Ridge
NASA Astrophysics Data System (ADS)
Yang, W.; Tao, C.; Li, H.; Liang, J.; Liao, S.
2017-12-01
Dragon Flag and Duanqiao hydrothermal field is located between the Indomed and Gallieni fracture zones in the ultraslow-spreading Southwest Indian Ridge (SWIR). Ten subsamples from active and inactive vents of Dragon Flag hydrothermal field and twenty-eight subsamples from Duanqiao hydrothermal field were dated using the 230Th/238U method. Four main episodes of hydrothermal activity of Duanqiao were determined according to the restricted results: 68.9-84.3, 43.9-48.4, 25.3-34.8, and 0.7-17.3 kyrs. Hydrothermal activity of Duanqiao probably started about 84.3 (±0.5) kyrs ago and ceased about 0.737 (±0.023) kyrs ago. And sulfide samples from the nearby Dragon Flag filed at the same time and the results show that the ages of most sulfides from Dragon Flag field range from 1.496(±0.176) to 5.416 (±0.116) kyrs with the oldest age estimated at 15.997 (±0.155) kyrs Münch et al. (2001) reconstructed the evolution history of Mt. Jourdanne hydrothermal field. The age dating results indicate activity in two episodes, at 70-40 and 27-13 kyrs. The hydrothermal activity in Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. The massive sulfides are younger than the sulfides from other hydrothermal fields such as Rainbow, Sonne and Ashadze-2. All these results suggest that hydrothermal activity of Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. Mt. Jourdanne is situated on an axial volcanic ridge which has both volcanic and tectonic activity. This is necessary to develop the heat source and pathways for the fluid convection, which enables the hydrothermal circulation. Hydrothermal activity in Dragon Flag Field is located next to the detachment fault termination. The detachment fault system provides a pathway for hydrothermal convection. Such style of heat source can contribute to continuous hydrothermal activity for over 1000 years. Duanqiao field is located near the central volcano and there is a hot mantle and/or fertile melt beneath Duanqiao field. The crust thickness is 9.5 km, suggesting the existence of AMC (Axial Magma Chamber) which provides magma source to the field (Li et al. 2015; Mendel et al. 2003). The periodic hydrothermal activity at Duanqiao may be related to the heat source provided by the local interaction of magmatism and tectonism.
NASA Astrophysics Data System (ADS)
Barreyre, Thibaut; Escartin, Javier; Cannat, Mathilde; Garcia, Rafael; Science Party, Momar'08; Science Party, Bathyluck'09
2010-05-01
The Lucky Strike hydrothermal site, located South of the Azores along the Mid-Atlantic Ridge, is one of the largest and best-known active hydrothermal fields along the ridge system. This site within the MoMAR area is also the target for the installation in 2010 of a pilot deep-sea observatory with direct telemetry to land, to be part of the European Seafloor Observatory Network (ESONET). The Lucky Strike hydrothermal site has seen extensive high-resolution, near-bottom geophysical surveys in 1996 (Lustre'96), 2006 (Momareto06), 2008 (MOMAR08) and 2009 (Bathyluck09). Vertically acquired black-and-white electronic still camera images have been projected and georeferenced to obtain 3 image mosaics covering the zone of active venting, extending ~ 700x800 m2, and with full image resolution (~10 mm pixels). These data allow us to study how hydrothermal outflow is structured, including the relationships between the zones of active high-temperature venting, areas of diffuse outflow, and the geological structure (nature of the substrate, faults and fissures, sediments, etc.). Hydrothermal outflow is systematically associated with bacterial mats that are easily identified in the imagery, allowing us to study temporal variability at two different scales. Over the 13-year period we can potentially track changes in both the geometry and intensity of hydrothermal activity throughout the system; our preliminary study of the Eiffel Tower, White Castle and Mt Segur indicate that activity has been sustained in recent times, with small changes in the detailed geometry of the diffuse outflow and its intensity. At longer times scales (hundreds to 1000 years?) imagery also shows evidence of areas of venting that are no longer active, often associated with the active structures. In combination with the high-resolution bathymetry, the imagery data thus allow us to characterize the shallow structure of hydrothermal outflow at depth, the structural and volcanic control, and ultimately quantify the heat flux associates with this hydrothermal outflow. Image mosaics are also key for the installation of instrumentation required by temporal studies, and for the infrastructure of the ESONET pilot seafloor observatory. This type of survey techniques and studies can also be extended to other areas of interest, such as hydrothermal fields, cold seeps, etc.
Vein networks in hydrothermal systems provide constraints for the monitoring of active volcanoes.
Cucci, Luigi; Di Luccio, Francesca; Esposito, Alessandra; Ventura, Guido
2017-03-10
Vein networks affect the hydrothermal systems of many volcanoes, and variations in their arrangement may precede hydrothermal and volcanic eruptions. However, the long-term evolution of vein networks is often unknown because data are lacking. We analyze two gypsum-filled vein networks affecting the hydrothermal field of the active Lipari volcanic Island (Italy) to reconstruct the dynamics of the hydrothermal processes. The older network (E1) consists of sub-vertical, N-S striking veins; the younger network (E2) consists of veins without a preferred strike and dip. E2 veins have larger aperture/length, fracture density, dilatancy, and finite extension than E1. The fluid overpressure of E2 is larger than that of E1 veins, whereas the hydraulic conductance is lower. The larger number of fracture intersections in E2 slows down the fluid movement, and favors fluid interference effects and pressurization. Depths of the E1 and E2 hydrothermal sources are 0.8 km and 4.6 km, respectively. The decrease in the fluid flux, depth of the hydrothermal source, and the pressurization increase in E2 are likely associated to a magma reservoir. The decrease of fluid discharge in hydrothermal fields may reflect pressurization at depth potentially preceding hydrothermal explosions. This has significant implications for the long-term monitoring strategy of volcanoes.
NASA Astrophysics Data System (ADS)
Bolós, X.; Cifuentes-Nava, G.; Macias, J. L.; Sosa-Ceballos, G.; García-Tenorio, F.; Albor, M., III; Juarez, M.; Gamez, V.
2017-12-01
Hydrothermal activity in volcanic calderas is the consequence of energy transfer between deep magmatic chambers and subsurface layers saturated in water. This hydrothermal system is generated by convection of the groundwater supplied by meteoric water recharged and the ascent of hot volcanic gasses exsolved from deep magma reservoirs. Calderas are heterogeneous geological structures that due to their formation and evolution produced a complex stratigraphy. All of these heterogeneities can be affected by deformation and also by the presence of fractures and faults which constitute the main pathways whereby hydrothermal fluids can move easily through the surface as spring discharges and fumarolic activity. Geophysical methods have been used in the last decades to investigate the relationship between structural geology and hydrothermal systems in different volcanic areas around the world. In this work, we have focused on the role of subsurface structures to understand and localize the pathways of fluids related to the hydrothermal system of the Cerritos Colorados geothermal field. We focused in the central area of the caldera (P12 well and Cerritos Colorados graben), where active hydrothermal activity is evidenced by fumaroles, thermal anomalies, CO2 diffuse emission, and sulfur precipitation. We have applied a self-potential method (SP) that combined with temperature measurements that allowed to identify the main infiltration and ascending fluid zones in the area, and their specific surface temperature coinciding with fumarolic activity. From this data we an applied Electrical Resistivity Tomography (ERT) survey in two selected places. One ERT profile (1.2 km in length) was located in the P12 well area. A 3D resistivity model used with the equatorial method was carried out on the Cerritos Colorados graben area. Combining the results of the SP, TºC, and ERT data with a detailed structural map we identified the main degassing zones (i.e. fumaroles) that correspond to higher permeability zones located along normal and strike-slip faults. In conclusion, a strong structural control of the surface manifestation of these hydrothermal systems is deduced from our new data. Then, our results emphasize the importance of old structural boundaries that are controlled by intra-caldera tectonic structures.
NASA Astrophysics Data System (ADS)
Weis, Philipp; Driesner, Thomas; Scott, Samuel; Lecumberri-Sanchez, Pilar
2016-04-01
Heat and mass transport in hydrothermal systems associated with upper crustal magmatic intrusions can result in resources with large economic potential (Kesler, 1994). Active hydrothermal systems can form high-enthalpy geothermal reservoirs with the possibility for renewable energy production. Fossil continental or submarine hydrothermal systems may have formed ore deposits at variable crustal depths, which can be mined near today's surface with an economic profit. In both cases, only the right combination of first-order geologic and hydrologic controls may lead to the formation of a significant resource. To foster exploration for these hydrothermal georesources, we need to improve our understanding of subsurface fluxes of mass and energy by combining numerical process modelling, observations at both active and fossil systems, as well as knowledge of fluid and rock properties and their interactions in natural systems. The presentation will highlight the role of non-linear fluid properties, phase separation, salt precipitation, fluid mixing, permeability structure, hydraulic fracturing and the transition from brittle to ductile rock behavior as major geologic and hydrologic controls on the formation of high-enthalpy and supercritical geothermal resources (Scott et al., 2015), and magmatic-hydrothermal mineral resources, such as porphyry copper, massive sulfide and epithermal gold deposits (Lecumberri-Sanchez et al., 2015; Weis, 2015). References: Kesler, S. E., 1994: Mineral Resources, economics and the environment, New York, McMillan, 391. Lecumberri-Sanchez, P., Steele-MacInnis, M., Weis, P., Driesner, T., Bodnar, R.J. (2015): Salt precipitation in magmatic-hydrothermal systems associated with upper crustal plutons. Geology, v. 43, p. 1063-1066, doi:10.1130/G37163.1 Scott, S., Driesner, T., Weis, P. (2015): Geologic controls on supercritical geothermal resources above magmatic intrusions. Nature Communications, 6:7837 doi: 10.1038/ncomms8837 Weis, P. (2015): The dynamic interplay between saline fluid flow and rock permeability in magmatic-hydrothermal systems. Geofluids, 15, 350-371.
NASA Astrophysics Data System (ADS)
Coussement, C.; Gente, P.; Rolet, J.; Tiercelin, J.-J.; Wafula, M.; Buku, S.
1994-10-01
The two branches of the East African Rift system include numerous hydrothermal fields, which are closely related to the present fault motion and to volcanic and seismic activity. In this study structural data from Pemba and Cape Banza hydrothermal fields (western branch, North Tanganyika, Zaire) are discussed in terms of neotectonic phenomena. Different types of records, such as fieldwork (onshore and underwater) and LANDSAT and SPOT imagery, are used to explain structural controls on active and fossil hydrothermal systems and their significance. The Pemba site is located at the intersection of 000-020°-trending normal faults belonging to the Uvira Border Fault System and a 120-130°-trending transtensional fault zone and is an area of high seismicity, with events of relatively large magnitude ( Ms < 6.5). The Cape Banza site occurs at the northern end of the Ubawari Peninsula horst. It is bounded by two fault systems trending 015° and is characterized seismically by events of small magnitude ( Ms < 4). The hydrothermal area itself is tectonically controlled by structures striking 170-180° and 080°. The analysis of both hydrothermal areas demonstrates the rejuvenation of older Proterozoic structures during Recent rift faulting and the location of the hydrothermal activity at the junctions of submeridian and transverse faults. The fault motion is compatible with a regional direction of extension of 090-110°. The Cape Banza and Pemba hydrothermal fields may testify to magma chambers existing below the junctions of the faults. They appear to form at structural nodes and may represent a future volcanic province. Together with the four surface volcanic provinces existing along the western branch, they possibly indicate an incipient rift segmentation related to 'valley-valley' or 'transverse fault-valley' junctions, contrasting with the spacing of the volcanoes measured in the eastern branch. These spacings appear to express the different elastic thicknesses between the eastern and western branches of the East African Rift system, perhaps related to a difference in stage of evolution of the two branches.
NASA Astrophysics Data System (ADS)
Takai, K.; Inagaki, F.; Nakamura, K.; Suzuki, K.; Kumagai, H.
2005-12-01
Deep-sea hydrothermal system has been recognized one of the most plausible places for origin of life in this planet. This hypothesis has been supported by evidences from multidisciplinary scientific fields. In geology, it has been demonstrated that the potentially most ancient microbial fossils are retrieved from the paleoenvironment, that might be related with deep-sea hydrothermal systems in the Archean. Chemical reactions suggesting prebiotic chemical evolution (synthesis of amino acids, nucleic acids and hydrocarbon, and polymerization of these molecules) are observed under the simulated physical and chemical conditions of the deep-sea hydrothermal vents in the laboratory. In addition, phylogenetic analyses of all the lives in this planet have clearly revealed that hyperthermophiles inhabiting deep-sea hydrothermal systems represent the deepest lineage of the life. Supposed that the Archean deep-sea hydrothermal system hosted the origin of life, what was the first life? We are pursuing the energy metabolism of our last universal common ancestor (LUCA) and the environmental settings hosting the LUCA. It is definitely expected that the genesis of LUCA occurred at high temperatures of locally organics-rich microenvironment around deep-sea hydrothermal field and the first energy metabolism depended on fermentation of simple amino acids, organic acids and sugars. However, these organics were immediately consumed by the hyperthermophilic LUCA activity. Inheritance of the LUCA needed to evolve the energy and carbon acquisitions to more stable and efficient mode. Chemolithoautotrophy might be the best because a plenty of reductive gas components were always provided by the hydrothermal activity. Hyperthermophilic chemolithoautotrophs could serve as the primary producers and could foster the heterotrophic fellows. This was the genesis of the last universal common ancestral (LUCA) community of life. We hypothesize that the LUCA community was metabolically approximated to hyperthermophilic subsurface lithoautotrophic microbial ecosystem (HyperSLiME) currently discovered beneath the Central Indian Ridge hydrothermal field. The environmental settings for the occurrence of HyperSLiME are now being characterized and an important linkage among the occurrence of HyperSLiME, extraordinary amount of hydrogen in the hydrothermal fluids and ultramfics-hosted hydrothermal systems is proposed. This ultramafics-hydrothermalism-hydrogen-HyperSLiME (UltraH3) linkage is very likely a key for the genesis of the LUCA community. We would like to discuss the possible UltraH3 linkage in the Archean earth. In addition, we would like to discuss which of modern deep-sea hydrothermal systems is the most plausible proxy for the Archean LUCA habitats.
Anatomy of Old Faithful From Subsurface Seismic Imaging of the Yellowstone Upper Geyser Basin
NASA Astrophysics Data System (ADS)
Wu, Sin-Mei; Ward, Kevin M.; Farrell, Jamie; Lin, Fan-Chi; Karplus, Marianne; Smith, Robert B.
2017-10-01
The Upper Geyser Basin in Yellowstone National Park contains one of the highest concentrations of hydrothermal features on Earth including the iconic Old Faithful geyser. Although this system has been the focus of many geological, geochemical, and geophysical studies for decades, the shallow (<200 m) subsurface structure remains poorly characterized. To investigate the detailed subsurface geologic structure including the hydrothermal plumbing of the Upper Geyser Basin, we deployed an array of densely spaced three-component nodal seismographs in November of 2015. In this study, we extract Rayleigh wave seismic signals between 1 and 10 Hz utilizing nondiffusive seismic waves excited by nearby active hydrothermal features with the following results: (1) imaging the shallow subsurface structure by utilizing stationary hydrothermal activity as a seismic source, (2) characterizing how local geologic conditions control the formation and location of the Old Faithful hydrothermal system, and (3) resolving a relatively shallow (10-60 m) and large reservoir located 100 m southwest of Old Faithful geyser.
NASA Astrophysics Data System (ADS)
Fujioka, Kantaro; Kobayashi, Kazuo; Kato, Kazuhiro; Aoki, Misumi; Mitsuzawa, Kyohiko; Kinoshita, Masataka; Nishizawa, Azusa
1997-12-01
Hydrothermal activities were monitored by an ocean bottom seismometer with hydrophone (OBSH) and a composite measuring system (Manatee) including CTD, current meter, transmission meter and cameras at a small depression on the TAG hydrothermal mound in the Mid-Atlantic Ridge. Low-frequency pressure pulses detected by the hydrophone with semi-diurnal periodicity seem to correspond to cycles of hydrothermal upflow from a small and short-lived smoker vent close to the observing site. The peaks of pressure pulses are synchronous with the maximum gradient of areal strain decrease due to tidal load release. Microearthquakes with very near epicenters occur sporadically and do not appear to be directly correlatable to hydrothermal venting. Temporal variations in bottom water temperature also have semi-diurnal periodicity but are more complicated than the pressure events. Temperatures may be affected both by upwelling of hot water and by lateral flow of the bottom current changing its directions with ocean tide.
NASA Astrophysics Data System (ADS)
Tao, W.; Tao, C.; Li, H.; Zhaocai, W.; Jinhui, Z.; Qinzhu, C.; Shili, L.
2014-12-01
Mid-ocean ridges, largely present far from the continental plates, are characterized by complex geological structures and numerous hydrothermal systems with complex controlling factors. Exploring seafloor sulfide resources for industrial and scientific applications is a challenge. With the advent of geophysical surveys for seabed investigation, near-bottom magnetic prospecting, which yields shallow geological structure, is an efficient method for investigating active and inactive hydrothermal fields and for researching the structure of hydrothermal systems (Tivey et al., 1993, 1996;German et al., 2008). We collected near-bottom magnetic data in the Longqi hydrothermal area, located in the southwest Indian ridge (49.6° E; Zhu et al., 2010; Tao et al., 2014), using the autonomous benthic explorer, an autonomous underwater vehicle, during the second leg of the Chinese cruise DY115-19 on board R/V DaYangYiHao. Based on the results of the intensity of the spatial differential vector method (Seaman et al., 1993), we outline the hydrothermal alternation zone. By building models, we subsequently infer a fault along the discovered hydrothermal vents; this fault line may be connected to a detachment fault (Zhao et al., 2013). In addition, we discuss the channels of the hydrothermal circulation system (Figure 1), and presume that heat was conducted to the sea subsurface by the detachment fault; the aqueous fluid that infiltrated the fault is heated and conveyed to the seafloor, promoting the circulation of the hydrothermal system.
Simulating Electrochemistry of Hydrothermal Vents on Enceladus and Other Ocean Worlds
NASA Astrophysics Data System (ADS)
Barge, L. M.; Krause, F. C.; Jones, J. P.; Billings, K.; Sobron, P.
2017-12-01
Gradients generated in hydrothermal systems provide a significant source of free energy for chemosynthetic life, and may play a role in present-day habitability on ocean worlds such as Enceladus that are thought to host hydrothermal activity. Hydrothermal vents are similar in some ways to typical fuel cell devices: redox/pH gradients between seawater and hydrothermal fluid are analogous to the oxidant and fuel reservoirs; conductive natural mineral deposits are analogous to electrodes; and, in hydrothermal chimneys, the porous chimney wall can function as a separator or ion-exchange membrane. Electrochemistry, founded on quantitative study of redox and other chemical disequilibria as well as the chemistry of interfaces, is uniquely suited to studying these systems. We have performed electrochemical studies to better understand the catalytic potential of seafloor minerals and vent chimneys, using samples from a black smoker vent chimney as an initial demonstration. Fuel cell experiments with electrodes made from black smoker chimney material accurately simulated the redox reactions that occur in a geological setting with this particular catalyst. Similar methods with other geo-catalysts (natural or synthetic) could be utilized to test which redox reactions or metabolisms could be driven in other hydrothermal systems, including putative vent systems on other worlds.
NASA Astrophysics Data System (ADS)
Stucker, Valerie K.; Walker, Sharon L.; de Ronde, Cornel E. J.; Caratori Tontini, Fabio; Tsuchida, Shinji
2017-10-01
The Hinepuia volcanic center is made up of two distinct edifices aligned northwest to southeast, with an active cone complex in the SE. Hinepuia is one of several active volcanoes in the northern segment of the Kermadec arc. Regional magnetic data show no evidence for large-scale hydrothermal alteration at Hinepuia, yet plume data confirm present-day hydrothermal discharge, suggesting that the hydrothermal system may be too young to have altered the host rocks with respect to measurable changes in magnetic signal. Gravity data are consistent with crustal thinning and shallow mantle under the volcanic center. Following the discovery of hydrothermal plumes over Hinepuia, the submersible Shinkai 6500 was used to explore the SE cone and sample hydrothermal fluids. The chemistry of hydrothermal fluids from submarine arc and backarc volcanoes is typically dominated by water-rock interactions and/or magmatic degassing. Chemical analyses of vent fluids show that Hinepuia does not quite fit either traditional model. Moreover, the Hinepuia samples fall between those typically ascribed to both end-member fluid types when plotted on a K-Mg-SO4 ternary diagram. Due to evidence of strong degassing, abundant native sulfur deposition, and H2S presence, the vent sampled at Hinepuia is ultimately classified as a magmatic-hydrothermal system with a water-rock influence. This vent is releasing water vapor and magmatic volatiles with a notable lack of salinity due to subcritical boiling and phase separation. Magmatic-hydrothermal fluid chemistry appears to be controlled by a combination of gas flux, phase separation processes, and volcano evolution and/or distance from the magma source.
NASA Astrophysics Data System (ADS)
Cigolini, Corrado; Laiolo, Marco; Coppola, Diego
2017-04-01
The behavior of fluids in hydrothermal systems is critical in volcano monitoring and geothermal prospecting. Analyzing the time series of radon emissions on active volcanoes is strategic for detecting and interpreting precursory signals of changes in volcanic activity, eventually leading to eruptions. Radon is a radioactive gas generated from the decay of U bearing rocks, soils and magmas. Although radon has been regarded as a potential precursor of earthquakes, radon anomalies appear to be better suited to forecast volcanic eruptions since we know where paroxysms may occur and we can follow the evolution of volcanic activity. Radon mapping at active volcanoes is also a reliable tool to assess diffuse and concentrated degassing as well as efficiently detecting earthquake-volcano interactions. Systematic radon monitoring has been shown to be a key factor for evaluating the rise of volcanic and hydrothermal fluids. In fact, the decay properties of radon, the duration of radon anomalies together with sampling rates may be cross-checked with the chemistry of hydrothermal fluids (and their transport properties) to constrain fluids ascent rates and to infer the permeability and porosity of rocks in sectors surrounding the active conduits. We hereby further discuss the data of radon surveys and monitoring at Somma-Vesuvius, Stromboli and La Soufrière (Guadeloupe, Lesser Antilles). The integrated analysis of seismic and geochemical data, including radon emissions, may be successfully used in testing temperature distributions and variations of porosity and permeability in volcanic hydrothermal systems and can be used as a proxy to analyze geothermal reservoirs.
NASA Astrophysics Data System (ADS)
Gregory, R. T.; Marsh, B. D.; Teplow, W.; Fournelle, J.
2009-12-01
The extent of the interaction between hydrothermal systems and active magma chambers has long been of fundamental interest to the development of ore deposits, cooling of magma chambers, and dehydration of the subducting lithosphere. As volatiles build up in the residual magma in the trailing edge of magmatic solidification fronts, is it possible that volatiles are transferred from the active magma to the hydrothermal system and vice versa? Does the external fracture front associated with vigorous hydrothermal systems sometimes propagate into the solidification front, facilitating volatile exchange? Or is the magma always sealed at temperatures above some critical level related to rock strength and overpressure? The degree of hydrothermal interaction in igneous systems is generally gauged in post mortem studies of δ18O and δD, where it has been assumed that a fracture front develops about the magma collapsing inward with cooling. H.P. Taylor and D. Norton's (1979; J. Petrol.)seminal work inferred that rocks are sealed with approach to the solidus and there is little to no direct interaction with external volatiles in the active magma. In active lava lakes a fracture front develops in response to thermal contraction of the newly formed rock once the temperature drops to ~950°C (Peck and Kinoshita,1976;USGS PP935A); rainfall driven hydrothermal systems flash to steam near the 100 °C isotherm in the solidified lake and have little effect on the cooling history (Peck et al., 1977; AJS). Lava lakes are fully degassed magmas and until the recent discovery of the Puna Magma Chamber (Teplow et al., 2008; AGU) no active magma was known at sufficiently great pressure to contain original volatiles. During the course of routine drilling of an injection well at the Puna Geothermal Venture (PGV) well-field, Big Island, Hawaii, a 75-meter interval of diorite containing brown glass inclusions was penetrated at a depth of 2415 m, continued drilling to 2488 m encountered a melt of dacitic composition of ~67 wt.% SiO2. The melt flowed up the borehole, quenched, and was repeatedly re-drilled over a depth interval of ~8 m, producing several kilograms of clear, colorless vitric cuttings. The melt is of low crystallinity, vesicle-free, at a minimum temperature of ~865°C, and with an apparent viscosity of ~106.5 Pa-s. The magma is separated from the deepest hydrothermal regime at 356°C by 526 m of sealed rock. Heat flux from the magma into the overlying geothermal reservoir at ~2784 mW/m2 is an order of magnitude greater than that for mid-ocean ridges. Typical Hawaiian basalt contains ~0.25 wt.% water. The dacite melt contains ~2.44 wt.% water, and is of normal magmatic δ18O (5.4 ‰) and δD (-61.8‰), which is in contrast to the surrounding hydrothermal waters. A similar preliminary analysis of the water content in the altered basalt just outside the sealed zone shows it to heavily hydrated (~4.94 wt.%) and altered by the hydrothermal field. This suggests that volatile under-saturated magmas are sealed with respect to hydrothermal fields and deeper systems may be even more strongly sealed.
Asymmetrical hydrothermal system below Merapi volcano imaged by geophysical data.
NASA Astrophysics Data System (ADS)
Byrdina, Svetlana; Friedel, Sven; Budi-Santoso, Agus; Suryanto, Wiwit; Suhari, Aldjarishy; Vandemeulebrouck, Jean; Rizal, Mohhamed H.; Grandis, Hendra
2017-04-01
A high-resolution image of the hydrothermal system of Merapi volcano is obtained using electrical resistivity tomography (ERT), self-potential, and CO2 flux mappings. The ERT inversions identify two distinct low-resistivity bodies, at the base of the south flank and in the summit area, that represent likely two parts of an interconnected hydrothermal system. In the summit area, the extension of the hydrothermal system is clearly limited by the main geological structures which are actual and ancient craters. A sharp resistivity contrast at ancient crater rim Pasar-Bubar separates a conductive hydrothermal system (20 - 50 Ωm) from the resistive andesite lava flows and pyroclastic deposits (2000 - 50 000 Ωm). High diffuse CO2 degassing (with a median value of 400g m -2 d -1) is observed in a narrow vicinity of the active crater rim and close to the Pasar-Bubar. The existence of preferential fluid circulation along this ancient crater rim is also evidenced by self-potential data. The total CO2 degassing across the accessible summit area with a surface of 1.4 · 10 5 m 2 is around 20 td -1. Before the 2010 eruption, Toutain et al. (2009) estimated a higher value of the total diffuse degassing from the summit area (about 200 - 230 td -1). This drop in the diffuse degassing can be related to the decrease in the magmatic activity, to the change of the summit morphology or to a combination of these factors. On the south flank of Merapi, the resistivity model shows spectacular stratification. While surficial recent andesite lava flows are characterized by resistivity exceeding 100 000 Ωm, resistivity as low as 10 Ωm has been encountered at a depth of 200 m at the base of the south flank and was interpreted as a presence of the hydrothermal system. We suggest that a sandwich-like structure of stratified pyroclastic deposits on the flanks of Merapi screen and separate the flow of hydrothermal fluids with the degassing occurring mostly through the fractured crater rims, while the liquid water flows down to the base of the volcanic dome. Our ERT results suggest the existence of a peripheral hydrothermal system below the south and west flanks in agreement with previous electromagnetic studies. In contrast, no evidence of hydrothermal system is found below the north flank, where the resistivity values are too high to be assigned to a hydrothermal system, at least to the ERT investigation depth. A probable cause of this asymmetry could be a non-axial location of the magmatic heat source. Such non-axial location of the magmatic source relative to the edifice is suggested by the shift of the volcanic activity to the south as proposed in the geological model by Camus et al, (2000). In addition, the hypocenters of seismic events located by Budi-Santoso et al, (2013) seem to be distributed to the SW from the active crater suggesting that the magma conduits and likely, the magmatic source, are shifted to the SW with respect to the actual crater.
Origin of Abiotic Methane in Submarine Hydrothermal Systems
NASA Astrophysics Data System (ADS)
Seewald, J. S.; German, C. R.; Grozeva, N. G.; Klein, F.; McDermott, J. M.; Ono, S.; Reeves, E. P.; Wang, D. T.
2018-05-01
Results of recent investigations into the chemical and isotopic composition of actively venting submarine hydrothermal fluids and volatile species trapped in fluid inclusions will be discussed in the context of processes responsible for abiotic CH4 formation.
NASA Astrophysics Data System (ADS)
Rubin, K. H.; Chadwick, W. C.; Embley, R. W.; Butterfield, D. A.
2018-05-01
Newly-discovered extensive explosive deep sea volcanism produces distinct stratovolcano structures and physical rock characteristics, and host primarily diffuse flow hydrothermal activity, unlike focused flow systems at effusive submarine volcanoes.
Hydrothermal systems in small ocean planets.
Vance, Steve; Harnmeijer, Jelte; Kimura, Jun; Hussmann, Hauke; Demartin, Brian; Brown, J Michael
2007-12-01
We examine means for driving hydrothermal activity in extraterrestrial oceans on planets and satellites of less than one Earth mass, with implications for sustaining a low level of biological activity over geological timescales. Assuming ocean planets have olivine-dominated lithospheres, a model for cooling-induced thermal cracking shows how variation in planet size and internal thermal energy may drive variation in the dominant type of hydrothermal system-for example, high or low temperature system or chemically driven system. As radiogenic heating diminishes over time, progressive exposure of new rock continues to the current epoch. Where fluid-rock interactions propagate slowly into a deep brittle layer, thermal energy from serpentinization may be the primary cause of hydrothermal activity in small ocean planets. We show that the time-varying hydrostatic head of a tidally forced ice shell may drive hydrothermal fluid flow through the seafloor, which can generate moderate but potentially important heat through viscous interaction with the matrix of porous seafloor rock. Considering all presently known potential ocean planets-Mars, a number of icy satellites, Pluto, and other trans-neptunian objects-and applying Earth-like material properties and cooling rates, we find depths of circulation are more than an order of magnitude greater than in Earth. In Europa and Enceladus, tidal flexing may drive hydrothermal circulation and, in Europa, may generate heat on the same order as present-day radiogenic heat flux at Earth's surface. In all objects, progressive serpentinization generates heat on a globally averaged basis at a fraction of a percent of present-day radiogenic heating and hydrogen is produced at rates between 10(9) and 10(10) molecules cm(2) s(1).
NASA Astrophysics Data System (ADS)
Yamaya, Y.; Alanis, P. K. B.; Takeuchi, A.; Cordon, J. M.; Mogi, T.; Hashimoto, T.; Sasai, Y.; Nagao, T.
2013-07-01
Taal Volcano, located in the southwestern part of Luzon Island, Philippines, has frequently experienced catastrophic eruptions from both the Main Crater on Volcano Island and flank eruptions. These eruptions have been magmatic, phreatomagmatic, and hydrothermal, with the latter implying the existence of a large-scale hydrothermal system beneath the volcano. We conducted an electrical resistivity survey using the magnetotelluric method in order to identify the location and geometry of the hydrothermal reservoir and sealing cap rock. Two-dimensional inversion using the observed data indicates four similar resistivity sections. The structure at shallow depths corresponds to volcanic deposits and an aquifer. Below 1 km, the structure features a relatively resistive zone beneath the main crater surrounded by a conductive shell. We interpreted these to be a large hydrothermal reservoir with an impermeable cap rock sealing it. Recent ground deformation detected by GPS measurements suggests that the hydrothermal reservoir is active. The interpreted cap rock thins just beneath the main crater and could easily be destroyed by an imbalance in the hydrothermal system. We conclude that this hydrothermal reservoir plays a significant role in driving catastrophic eruptions that begin with a hydrothermal explosion at the main crater.
NASA Astrophysics Data System (ADS)
Morgan, K.; Ort, M. H.; Di Muro, A.; Parnell, R. A.; Huff, W. D.
2017-12-01
Piton de la Fournaise (PdF) is an active basaltic volcano on La Réunion island. The Bellecombe Tephra was deposited from at least three unusually explosive eruptions between 3000-5000 ka. The Bellecombe eruptions were interpreted recently to have been due to rapid depressurization of the hydrothermal system when a deep fracture opened after lateral, seaward-directed sliding of the eastern flank, late in a large effusive eruption. This project tests this hypothesis by physically, mineralogically, and chemically characterizing the Bellecombe Tephra to look for evidence of the involvement of the PdF hydrothermal system in the eruptions and understand where the eruptions initiated. The Bellecombe tephra consists of three units separated by incipient soils. Both the Upper and Lower Bellecombe deposits are mostly medium to very fine ash. Lower Bellecombe deposits, from the first two eruptions, are mostly beds of glassy ash containing minor lithic grains and olivine crystals. Hydrothermal minerals, mostly smectite, are present in a few Lower Bellecombe beds. Since these minerals are only present in some beds, the smectite formed before deposition rather than as a product of surficial alteration. The Upper Bellecombe deposits record a third eruption and vary between clast-supported crystal- and lithic-rich lapilli beds and ash beds with abundant ash pellets. The crystals are mostly olivine, with lesser pyroxene and plagioclase and sparse hydrothermal quartz. Gabbro and oceanite clasts are abundant and trachytic pumice rare in these deposits. Hydrothermal minerals are common in most Upper Bellecombe beds. The presence of smectite in some of the Lower Bellecombe beds suggests these deposits came from a system below 200 ºC. Clays in the Upper Bellecombe beds - smectite and mixed layer R0 illite/smectite - imply a system at 40-140 ºC. The hydrothermal system was involved, but might not have been the primary impetus for these eruptions, since hydrothermal minerals are not present in all of the beds, but we find no evidence of high temperatures. The lower Bellecombe vent was near the active summit whereas the Upper Bellecombe vent was from a previously more active area, and this may be reflected in the temperatures of the hydrothermal system. The abundant olivine crystals confirm a relation to a large effusive oceanite eruption.
NASA Astrophysics Data System (ADS)
Brothelande, E.; Lénat, J.-F.; Chaput, M.; Gailler, L.; Finizola, A.; Dumont, S.; Peltier, A.; Bachèlery, P.; Barde-Cabusson, S.; Byrdina, S.; Menny, P.; Colonge, J.; Douillet, G. A.; Letort, J.; Letourneur, L.; Merle, O.; Di Gangi, F.; Nakedau, D.; Garaebiti, E.
2016-08-01
In this contribution, we focus on one of the most active resurgences on Earth, that of the Yenkahe dome in the Siwi caldera (Tanna Island, Vanuatu), which is associated with the persistently active Yasur volcano. Gravity and magnetic surveys have been carried out over the past few years in the area, as well as electrical methods including electrical resistivity tomography (ERT), time domain electro-magnetics (TDEM) and self-potential (SP). These investigations were completed by thermometry, CO2 soil gas measurements, field observations and sampling. This multi-method approach allows geological structures within the caldera to be identified, as well as associated hydrothermal features. The global structure of the caldera is deduced from gravity data, which shows the caldera rim as a high density structure. Large lava fields, emplaced before and after the onset of resurgence, are evidenced by combined gravity, magnetic and resistivity signals. In the middle of the caldera, the Yenkahe dome apparently results from a combination of volcanic and tectonic events, showing that lava extrusion and resurgence have been operating simultaneously or alternately during the Siwi caldera post-collapse history. There is a clear distinction between the western and eastern parts of the dome. The western part is older and records the growth of an initial volcanic cone and the formation of a small caldera. This small caldera (paleo-Yasur caldera), partially filled with lava flows, is the present-day focus of volcanic activity and associated fluid circulation and alteration. The eastern part of the dome is presumably younger, and is characterized by intense, extensive hydrothermal alteration and activity. Its northern part is covered by lava flow piles and exhibits a shallow hydrothermal zone in ERT. The southern part has hydrothermal alteration and activity extending at least down to the base of the resurgent dome. This part of the dome is built up of low cohesion rock and is thus potentially prone to gravitational landslides. Lastly, while self-potential and temperature data suggest that widespread hydrothermal circulation occurs throughout almost all of the caldera, and possibly beyond, the most active parts of this hydrothermal system are associated with the dome. The presence of this active hydrothermal system is the clearest indicator that these methods can provide of a potential shallow magmatic body underneath the dome.
NASA Astrophysics Data System (ADS)
Zierenberg, R. A.; Fowler, A. P.; Schiffman, P.; Fridleifsson, G. Ó.; Elders, W. A.
2017-12-01
The Iceland Deep Drilling Project well IDDP-2, drilled to 4,659 m in the Reykjanes geothermal system, the on-land extension of the Mid Atlantic Ridge, SW Iceland. Drill core was recovered, for the first time, from a seawater-recharged, basalt-hosted hydrothermal system at supercritical conditions. The well has not yet been allowed to heat to in situ conditions, but temperature and pressure of 426º C and 340 bar was measured at 4500 m depth prior to the final coring runs. Spot drill cores were recovered between drilling depths of 3648.00 m and 4657.58 m. Analysis of the core is on-going, but we present the following initial observations. The cored material comes from a basaltic sheeted dike complex in the brittle-ductile transition zone. Felsic (plagiogranite) segregation veins are present in minor amounts in dikes recovered below 4300 m. Most core is pervasively altered to hornblende + plagioclase, but shows only minor changes in major and minor element composition. The deepest samples record the transition from the magmatic regime to the presently active hydrothermal system. Diabase near dike margins has been locally recrystallized to granoblastic-textured orthopyroxene-clinopyroxe-plagioclase hornfels. High temperature hydrothermal alteration includes calcic plagioclase (up to An100) and aluminous hornblende (up to 11 Wt. % Al2O3) locally intergrown with hydrothermal biotite, clinopyroxene, orthopyroxene and/or olivine. Hydrothermal olivine is iron-rich (Mg # 59-64) compared to expected values for igneous olivine. Biotite phenocrysts in felsic segregation veins have higher Cl and Fe compared to hydrothermal biotites. Orthopyroxene-clinopyroxene pairs in partially altered quench dike margins give temperature of 955° to 1067° C. Orthopyroxene-clinopyroxene pairs from hornfels and hydrothermal veins and replacements give temperature ranging from 774° to 888° C. Downhole fluid sampling is planned following thermal equilibration of the drill hole. Previous work has suggested that the Reykjanes geothermal system has been active since the last glaciation, 10ka. No shallow melt bodies have been detected on the Reykjanes Peninsula suggesting that hydrothermal circulation typical of black smoker systems can be sustained with out a magmatic heat source.
Mathematical Models of Seafloor Hydrothermal Systems Driven by Serpentinization of Peridotite
NASA Astrophysics Data System (ADS)
Lowell, R. P.; Rona, P. A.; Germanovich, L. N.
2001-12-01
Most seafloor hydrothermal systems are driven by heat transfer from subsurface magma bodies. At slow spreading ridges of the Atlantic and Indian oceans, however, magma supply is low; and tectonic activity brings mantle rocks to shallow depths in the crust. Then, the heat of formation released upon serpentinization of peridotite provides the energy source for hydrothermal circulation. This latter class of system has been relatively unstudied, but recent discoveries of peridotite-hosted hydrothermal systems along the Mid-Atlantic Ridge suggest that such systems may play an important role in geochemical cycling and biogeochemical processes. The likelihood that peridotite-hosted hydrothermal systems was more prevalent during the Archean further suggests that such systems may have played a role in the origin of life. We present the first mathematical models of seafloor hydrothermal systems driven by heat released upon serpentinization of peridotite. We assume seawater circulates through a major crack network in the host-peridotite and that cooling of the host-rock leads to the formation of microcracks through which the fluid infiltrates. Reaction of the fluid in microcracks with the host rock results in serpentinization and the heat released upon serpentinization is transported to the seafloor by the fluid circulating in the main crack network. The temperature and heat output of the resulting hydrothermal system is a function of the main network permeability and the rate at which the serpentinization reaction proceeds via diffusion and propagation of the microcracks. Although the temperature of such a system can be quite variable, vent temperatures between 10° C and 100° C are likely for typical crustal parameters.
Hydrothermal activity lowers trophic diversity in Antarctic hydrothermal sediments
NASA Astrophysics Data System (ADS)
Bell, James B.; Reid, William D. K.; Pearce, David A.; Glover, Adrian G.; Sweeting, Christopher J.; Newton, Jason; Woulds, Clare
2017-12-01
Hydrothermal sediments are those in which hydrothermal fluid is discharged through sediments and are one of the least studied deep-sea ecosystems. We present a combination of microbial and biochemical data to assess trophodynamics between and within hydrothermal and background areas of the Bransfield Strait (1050-1647 m of depth). Microbial composition, biomass, and fatty acid signatures varied widely between and within hydrothermally active and background sites, providing evidence of diverse metabolic activity. Several species had different feeding strategies and trophic positions between hydrothermally active and inactive areas, and the stable isotope values of consumers were not consistent with feeding morphology. Niche area and the diversity of microbial fatty acids was lowest at the most hydrothermally active site, reflecting trends in species diversity. Faunal uptake of chemosynthetically produced organics was relatively limited but was detected at both hydrothermal and non-hydrothermal sites, potentially suggesting that hydrothermal activity can affect trophodynamics over a much wider area than previously thought.
Hydrothermal deposition on the Juan de Fuca Ridge over multiple glacial-interglacial cycles
NASA Astrophysics Data System (ADS)
Costa, Kassandra M.; McManus, Jerry F.; Middleton, Jennifer L.; Langmuir, Charles H.; Huybers, Peter J.; Winckler, Gisela; Mukhopadhyay, Sujoy
2017-12-01
Hydrothermal systems play an important role in modern marine chemistry, but little is known about how they may have varied on 100,000 year timescales. Here we present high-resolution records of non-lithogenic metal fluxes within sediment cores covering the last 500,000 years of hydrothermal deposition on the flanks of the Juan de Fuca Ridge. Six adjacent, gridded cores were analyzed by x-ray fluorescence for Fe, Mn, and Cu concentrations, corrected for lithogenic inputs with Ti, and normalized to excess initial 230Th to generate non-lithogenic metal flux records that provide the longest orbitally resolved reconstructions of hydrothermal activity currently available. Fe fluxes vary with global sea level over the last two glacial cycles, suggesting higher hydrothermal deposition during interglacial periods. The observed negative relationship between Fe and Mn indicates variable sediment redox conditions and diagenetic remobilization of sedimentary Mn over time. Thus, Mn fluxes may not be a reliable indicator for hydrothermal activity in the Juan de Fuca Ridge sediment cores. Cu fluxes show substantial high-frequency variability that may be linked to changes in vent temperature related to increased magmatic production during glacial periods. Deglacial hydrothermal peaks on the Juan de Fuca Ridge are consistent with previously published records from the Mid-Atlantic Ridge and the East Pacific Rise. Moreover, on the Juan de Fuca Ridge, the deglacial peaks in hydrothermal activity are followed by relatively high hydrothermal fluxes throughout the ensuing interglacial periods relative to the previous glacial period.
State of the hydrothermal activity of Soufrière of Guadeloupe volcano inferred by VLF surveys
NASA Astrophysics Data System (ADS)
Zlotnicki, J.; Vargemezis, G.; Mille, A.; Bruère, F.; Hammouya, G.
2006-04-01
La Soufrière (1467 m) is the active island arc volcano of Guadeloupe Island in the Lesser Antilles arc. Its historical eruptions are more or less violent phreatic outbursts the last of which, in 1976-1977, led to the evacuation of nearly 70 000 persons. The subsurface structure of the volcano consists of calderas, craters, and avalanche amphitheatres nested within the composite pile of eruptive products. Since the last magmatic eruption, dated ca. 1440 AD, the four phreatic eruptions have developed radial fractures on Soufrière dome favouring the development of a huge active hydrothermal system emphasized by a tropical environment. After the eruptions, the thermal state and the stable ground water flow are completely disorganised during several years during which the slow mineralization of rocks is becoming again preponderant. Sealing of fractures and decay of rocks permeability act as a cap for upward thermal transfers. Therefore Soufrière dome operates as a valve, resealing the hydrothermal system underlying the volcano thus providing over pressurization that could lead to the next phreatic eruption. In 1992 new small seismic swarms have appeared. Several of them are recorded every year while the emission of acid gas slowly increases. In order to recognise the superficial electrical resistive and conductive zones (less than 100 m depth) as well as the cavities on Soufrière volcano, we have made Very Low Frequency (VLF) surveys in 2000. Electrical conductive zones are clearly associated with major radial faults starting from the summit in which the hydrothermal activity takes place. In the continuation of these active hydrothermal fractures hot springs are located down slope. Conversely some of the resistive zones are associated with inactive clayed and sealed or opened faults. The distribution of the conductive zones allows detailing the state of the superficial part of the hydrothermal system of La Soufrière. The distribution of vertical clayed zones associated with major faults supposes Soufrière dome constituted of more or less consolidated blocks joined side by side and lying on the hydrothermally floor of crater Amic.
Volcano-hydrothermal system and activity of Sirung volcano (Pantar Island, Indonesia)
NASA Astrophysics Data System (ADS)
Caudron, Corentin; Bernard, Alain; Murphy, Sam; Inguaggiato, Salvatore; Gunawan, Hendra
2018-05-01
Sirung is a frequently active volcano located in the remote parts of Western Timor (Indonesia). Sirung has a crater with several hydrothermal features including a crater lake. We present a timeseries of satellite images of the lake and chemical and isotope data from the hyperacid hydrothermal system. The fluids sampled in the crater present the typical features of hyperacidic systems with high TDS, low pH and δ34SHSO4-δ34SS0 among the highest for such lakes. The cations concentrations are predominantly controlled by the precipitation of alunite, jarosite, silica phases, native sulfur and pyrite which dominate the shallow portions of the hydrothermal system. These minerals may control shallow sealing processes thought to trigger phreatic eruptions elsewhere. Sparse Mg/Cl and SO4/Cl ratios and lake parameters derived from satellite images suggest gradual increase in heat and gas flux, most likely SO2-rich, prior to the 2012 phreatic eruption. An acidic river was sampled 8 km far from the crater and is genetically linked with the fluids rising toward the active crater. This river would therefore be a relevant target for future remote monitoring purposes. Finally, several wells and springs largely exceeded the World Health Organization toxicity limits in total arsenic and fluoride.
NASA Astrophysics Data System (ADS)
Xu, G.; Bemis, K. G.
2014-12-01
Seafloor hydrothermal systems feature intricate interconnections among oceanic, geological, hydrothermal, and biological processes. The advent of the NEPTUNE observatory operated by Ocean Networks Canada at the Endeavour Segment, Juan de Fuca Ridge enables scientists to study these interconnections through multidisciplinary, continuous, real-time observations. The multidisciplinary observatory instruments deployed at the Grotto Mound, a major study site of the NEPTUNE observatory, makes it a perfect place to study the response of a seafloor hydrothermal system to geological and oceanic processes. In this study, we use the multidisciplinary datasets recorded by the NEPTUNE Observatory instruments as observational tools to demonstrate two different aspects of the response of hydrothermal activity at the Grotto Mound to geological and oceanic processes. First, we investigate a recent increase in venting temperature and heat flux at Grotto observed by the Benthic and Resistivity Sensors (BARS) and the Cabled Observatory Vent Imaging Sonar (COVIS) respectively. This event started in Mar 2014 and is still evolving by the time of writing this abstract. An initial interpretation in light of the seismic data recorded by a neighboring ocean bottom seismometer on the NEPTUNE observatory suggests the temperature and heat flux increase is probably triggered by local seismic activities. Comparison of the observations with the results of a 1-D mathematical model simulation of hydrothermal sub-seafloor circulation elucidates the potential mechanisms underlying hydrothermal response to local earthquakes. Second, we observe significant tidal oscillations in the venting temperature time series recorded by BARS and the acoustic imaging of hydrothermal plumes by COVIS, which is evidence for hydrothermal response to ocean tides and currents. We interpret the tidal oscillations of venting temperature as a result of tidal loading on a poroelastic medium. We then invoke poroelastic theories to estimate the crustal permeability, a fundamental property of subsurface hydrothermal circulation, from the phase shift of the tidal oscillations of venting temperature relative to ambient ocean tides. These results together shed light on the influences of seismic and oceanic processes on a seafloor hydrothermal system.
NASA Astrophysics Data System (ADS)
Medialdea, T.; Somoza, L.; González, F. J.; Vázquez, J. T.; de Ignacio, C.; Sumino, H.; Sánchez-Guillamón, O.; Orihashi, Y.; León, R.; Palomino, D.
2017-08-01
New seismic profiles, bathymetric data, and sediment-rock sampling document for the first time the discovery of hydrothermal vent complexes and volcanic cones at 4800-5200 m depth related to recent volcanic and intrusive activity in an unexplored area of the Canary Basin (Eastern Atlantic Ocean, 500 km west of the Canary Islands). A complex of sill intrusions is imaged on seismic profiles showing saucer-shaped, parallel, or inclined geometries. Three main types of structures are related to these intrusions. Type I consists of cone-shaped depressions developed above inclined sills interpreted as hydrothermal vents. Type II is the most abundant and is represented by isolated or clustered hydrothermal domes bounded by faults rooted at the tips of saucer-shaped sills. Domes are interpreted as seabed expressions of reservoirs of CH4 and CO2-rich fluids formed by degassing and contact metamorphism of organic-rich sediments around sill intrusions. Type III are hydrothermal-volcanic complexes originated above stratified or branched inclined sills connected by a chimney to the seabed volcanic edifice. Parallel sills sourced from the magmatic chimney formed also domes surrounding the volcanic cones. Core and dredges revealed that these volcanoes, which must be among the deepest in the world, are constituted by OIB-type, basanites with an outer ring of blue-green hydrothermal Al-rich smectite muds. Magmatic activity is dated, based on lava samples, at 0.78 ± 0.05 and 1.61 ± 0.09 Ma (K/Ar methods) and on tephra layers within cores at 25-237 ky. The Subvent hydrothermal-volcanic complex constitutes the first modern system reported in deep water oceanic basins related to intraplate hotspot activity.
First Evidence of Epithermal Gold Occurrences in the SE Afar Rift, Republic of Djibouti
NASA Astrophysics Data System (ADS)
Moussa, Nima; Fouquet, Yves; Caminiti, Antoine Marie; Le Gall, Bernard; Rolet, Joel; Bohn, Marcel; Etoubleau, Joel; Delacourt, Christophe; Jalludin, Mohamed
2010-05-01
The Republic of Djibouti, located at the SE part of the Afar volcanic Triangle, is characterized by intense tectonic and bimodal volcanic activity, and is emplaced over an earlier magmatic rift system, as old as 25-30 Ma. Each magmatic event is accompanied by hydrothermal activity. Few works have been so far published on hydrothermal mineralization in the Afar area. Mineralization generally occur as veins and are mainly associated with acidic volcanic intrusions along the fractures at the edges of grabens established during the last 4 Ma. Eighty samples from hydrothermal quartz ± carbonate veins and breccias were studied on 9 different sites representative of 4 main volcanic events ranging in age from early Miocene up to Present. Gold was found in excess of 200 ppb in 30% of the samples. Mineralogical analyses based on optical reflected light microscopy, X-Ray diffractometry, X-Ray fluorescence, inductively coupled plasma mass spectroscopy and electron microprobe, led us to identify two types of gold mineralization (i) native gold, electrum, hessite and sulfides (chalcopyrite, pyrite, bornite, ± sphalerite, and galena) in massive quartz breccias and banded chalcedony, (ii) gold, electrum, hematite, magnetite, trace minerals (argentite) and adularia in banded chalcedony. Another group without gold is characterized by quartz, pyrite ± goethite. Secondary minerals are characterized by goethite, native silver and native copper. Arsenic is enriched in pyrite in samples with a high gold content. The bimodal volcanism, the occurrence of adularia, the native gold and electrum in banded silica veins, are classically observed in neutral epithermal systems. The discovery of this type of mineralization in a recent-active continental rift system supplies new insights about hydrothermal processes associated with volcanic activity in a spreading context. Keywords: Republic of Djibouti, Afar Triangle, Hydrothermal, Epithermal system, Gold
Fracture distribution and porosity in a fault-bound hydrothermal system (Grimsel Pass, Swiss Alps)
NASA Astrophysics Data System (ADS)
Egli, Daniel; Küng, Sulamith; Baumann, Rahel; Berger, Alfons; Baron, Ludovic; Herwegh, Marco
2017-04-01
The spatial distribution, orientation and continuity of brittle and ductile structures strongly control fluid pathways in a rock mass by joining existing pores and creating new pore space (fractures, joints) but can also act as seals to fluid flow (e.g. ductile shear zones, clay-rich fault gouges). In long-lived hydrothermal systems, permeability and the related fluid flow paths are therefore dynamic in space and time. Understanding the evolution and behaviour of naturally porous and permeable rock masses is critical for the successful exploration and sustainable exploitation of hydrothermal systems and can advance methods for planning and implementation of enhanced geothermal systems. This study focuses on an active fault-bound hydrothermal system in the crystalline basement of the Aar Massif (hydrothermal field Grimsel Pass, Swiss Alps) that has been exhumed from few kilometres depth and which documents at least 3 Ma of hydrothermal activity. The explored rock unit of the Aar massif is part of the External Crystalline Massifs that hosts a multitude of thermal springs on its southern border in the Swiss Rhône valley and furthermore represents the exhumed equivalent of potentially exploitable geothermal reservoirs in the deep crystalline subsurface of the northern Alpine foreland basin. This study combines structural data collected from a 125 m long drillhole across the hydrothermal zone, the corresponding drill core and surface mapping. Different methods are applied to estimate the porosity and the structural evolution with regard to porosity, permeability and fracture distribution. Analyses are carried out from the micrometre to decametre scale with main focus on the flow path evolution with time. This includes a large variety of porosity-types including fracture-porosity with up to cm-sized aperture down to grain-scale porosity. Main rock types are granitoid host rocks, mylonites, paleo-breccia and recent breccias. The porosity of the host rock as well as the cemented paleo-hydrothermal breccia is typically very low with values <1%. The high volume of mineralized fractures in the paleo-breccia indicates high porosity in former times, which is today closed by newly developed cements. The preservation of such paleo-breccias allow the investigation of contrasts between the fossil porosity/permeability and the present day active flow path, which is defined by fracture porosity that generally follows the regional deformation pattern and forms a wide network of interconnected fractures of variable orientation.
NASA Astrophysics Data System (ADS)
Fujii, Masakazu; Okino, Kyoko; Sato, Taichi; Sato, Hiroshi; Nakamura, Kentaro
2016-05-01
High-resolution vector magnetic measurements were performed on an inactive ultramafic-hosted hydrothermal vent field, called Yokoniwa Hydrothermal Field (YHF), using a deep-sea manned submersible Shinkai6500 and an autonomous underwater vehicle r2D4. The YHF has developed at a non-transform offset massif of the Central Indian Ridge. Dead chimneys were widely observed around the YHF along with a very weak venting of low-temperature fluids so that hydrothermal activity of the YHF was almost finished. The distribution of crustal magnetization from the magnetic anomaly revealed that the YHF is associated with enhanced magnetization, as seen at the ultramafic-hosted Rainbow and Ashadze-1 hydrothermal sites of the Mid-Atlantic Ridge. The results of rock magnetic analysis on seafloor rock samples (including basalt, dolerite, gabbro, serpentinized peridotite, and hydrothermal sulfide) showed that only highly serpentinized peridotite carries high magnetic susceptibility and that the natural remanent magnetization intensity can explain the high magnetization of Yokoniwa. These observations reflect abundant and strongly magnetized magnetite grains within the highly serpentinized peridotite. Comparisons with the Rainbow and Ashadze-1 suggest that in ultramafic-hosted hydrothermal systems, strongly magnetized magnetite and pyrrhotite form during the progression of hydrothermal alteration of peridotite. After the completion of serpentinization and production of hydrogen, pyrrhotites convert into pyrite or nonmagnetic iron sulfides, which considerably reduces their levels of magnetization. Our results revealed origins of the magnetic high and the development of subsurface chemical processes in ultramafic-hosted hydrothermal systems. Furthermore, the results highlight the use of near-seafloor magnetic field measurements as a powerful tool for detecting and characterizing seafloor hydrothermal systems.
Impact-generated Hydrothermal Activity at the Chicxulub Crater
NASA Astrophysics Data System (ADS)
Kring, D. A.; Zurcher, L.; Abramov, O.
2007-05-01
Borehole samples recovered from PEMEX exploration boreholes and an ICDP scientific borehole indicate the Chicxulub impact event generated hydrothermal alteration throughout a large volume of the Maya Block beneath the crater floor and extending across the bulk of the ~180 km diameter crater. The first indications of hydrothermal alteration were observed in the crater discovery samples from the Yucatan-6 borehole and manifest itself in the form of anhydrite and quartz veins. Continuous core from the Yaxcopoil-1 borehole reveal a more complex and temporally extensive alteration sequence: following a brief period at high temperatures, impact- melt-bearing polymict breccias and a thin, underlying unit of impact melt were subjected to metasomatism, producing alkali feldspar, sphene, apatite, and magnetite. As the system continued to cool, smectite-series phyllosilicates appeared. A saline solution was involved. Stable isotopes suggest the fluid was dominated by a basinal brine created mostly from existing groundwater of the Yucatan Peninsula, although contributions from down-welling water also occurred in some parts of the system. Numerical modeling of the hydrothermal system suggests circulation occurred for 1.5 to 2.3 Myr, depending on the permeability of the system. Our understanding of the hydrothermal system, however, is still crude. Additional core recovery projects, particularly into the central melt sheet, are needed to better evaluate the extent and duration of hydrothermal alteration.
NASA Astrophysics Data System (ADS)
Braddock, Mathilde; Biggs, Juliet; Watson, Iain M.; Hutchison, William; Pyle, David M.; Mather, Tamsin A.
2017-07-01
Fumaroles are the surface manifestation of hydrothermal circulation and can be influenced by magmatic, hydrothermal, hydrological and tectonic processes. This study investigates the temporal changes in fumarole temperatures and spatial extent on Aluto, a restless volcano in the Main Ethiopian Rift (MER), in order to better understand the controls on fluid circulation and the interaction between the magmatic and hydrothermal systems. Thermal infrared (TIR) satellite images, acquired by the Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) over the period of 2004 to 2016, are used to generate time series of the fumarole temperatures and areas. The thermal anomalies identified in the ASTER images coincide with known fumaroles with temperatures > 80 °C and are located on or close to fault structures, which provide a pathway for the rising fluids. Most of the fumaroles, including those along the major zone of hydrothermal upwelling, the Artu Jawe Fault Zone, have pixel-integrated temperature variations of only 2 ± 1.5 °C. The exception are the Bobesa fumaroles located on a hypothesised caldera ring fault which show pixel-integrated temperature changes of up to 9 °C consistent with a delayed response of the hydrothermal system to precipitation. We conclude that fumaroles along major faults are strongly coupled to the magmatic-hydrothermal system and are relatively stable with time, whereas those along shallower structures close to the rift flank are more strongly influenced by seasonal variations in groundwater flow. The use of remote sensing data to monitor the thermal activity of Aluto provides an important contribution towards understanding the behaviour of this actively deforming volcano. This method could be used at other volcanoes around the world for monitoring and geothermal exploration.
NASA Astrophysics Data System (ADS)
Tanaka, A.; Abe, G.; Yamaguchi, K. E.
2014-12-01
Recent studies have shown that submarine hydrothermal system supports diverse microbial life. Bio-essential metals supporting such microbial communities were released from basalts by high-temperature water-rock interaction in deeper part of the oceanic crust and carried by submarine fluid flow. Its total quantity in global hydrothermal settings has been estimated to be on the order of ~1019 g/yr, which is surprisingly on the same order of the total river flows (Urabe et al., 2011). Therefore, it is important to explore how submarine river system works, i.e., to understand mechanism and extent of elemental transport, which should lead to understanding of the roles of hydrothermal circulation in oceanic crust in controlling elemental budget in the global ocean and geochemical conditions to support deep hot biosphere. We performed REE analysis of marine sediments influenced by submarine hydrothermal activity in Mid-Okinawa Trough. The sediment samples used in this study are from IODP site at Iheya North region and JADE site at Izena region. The samples show alternation between volcanic and clastic sediments. Hydrothermal fluids of this area contain elevated concentrations of volatile components such as H2, CO2, CH4, NH4+, and H2S, supporting diverse chemoautotrophic microbial community (Nakagawa et al., 2005). The purpose of this study is to examine the effect of hydrothermal activity on the REE signature of the sediments. Chondrite-normalized REE patterns of the samples show relative enrichment of light over heavy REEs, weak positive Ce anomalies, and variable degrees of negative Eu anomalies. The REE patterns suggest the sediments source was mainly basalt, suggesting insignificant input of continental materials. Negative Eu anomalies found in the IODP site become more pronounced with increasing depth, suggesting progressive increase of hydrothermal alteration where Eu was reductively dissolved into fluids by decomposition of feldspars. Contrary, at the JADE site, magnitude of negative Eu anomalies was variable independent of the sediment depth. This suggests changes in the redox conditions, most likely due to occasional invasions of O2-bearing seawater into sediments. Different regimes of hydrothermal fluid flows govern the chemical environments of marine sediments in active hydrothermal areas.
de Moor, J Maarten; Aiuppa, A; Avard, G; Wehrmann, H; Dunbar, N; Muller, C; Tamburello, G; Giudice, G; Liuzzo, M; Moretti, R; Conde, V; Galle, B
2016-08-01
Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San José. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high-frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO 2 -rich gas (CO 2 /S total > 4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2 weeks before eruptions, which are accompanied by shallowly derived sulfur-rich magmatic gas emissions. Degassing modeling suggests that the deep magmatic reservoir is ~8-10 km deep, whereas the shallow magmatic gas source is at ~3-5 km. Two cycles of degassing and eruption are observed, each attributed to pulses of magma ascending through the deep reservoir to shallow crustal levels. The magmatic degassing signals were overprinted by a fluid contribution from the shallow hydrothermal system, modifying the gas compositions, contributing volatiles to the emissions, and reflecting complex processes of scrubbing, displacement, and volatilization. H 2 S/SO 2 varies over 2 orders of magnitude through the monitoring period and demonstrates that the first eruptive episode involved hydrothermal gases, whereas the second did not. Massive degassing (>3000 T/d SO 2 and H 2 S/SO 2 > 1) followed, suggesting boiling off of the hydrothermal system. The gas emissions show a remarkable shift to purely magmatic composition (H 2 S/SO 2 < 0.05) during the second eruptive period, reflecting the depletion of the hydrothermal system or the establishment of high-temperature conduits bypassing remnant hydrothermal reservoirs, and the transition from phreatic to phreatomagmatic eruptive activity.
Aiuppa, A.; Avard, G.; Wehrmann, H.; Dunbar, N.; Muller, C.; Tamburello, G.; Giudice, G.; Liuzzo, M.; Moretti, R.; Conde, V.; Galle, B.
2016-01-01
Abstract Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San José. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high‐frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO2‐rich gas (CO2/Stotal > 4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2 weeks before eruptions, which are accompanied by shallowly derived sulfur‐rich magmatic gas emissions. Degassing modeling suggests that the deep magmatic reservoir is ~8–10 km deep, whereas the shallow magmatic gas source is at ~3–5 km. Two cycles of degassing and eruption are observed, each attributed to pulses of magma ascending through the deep reservoir to shallow crustal levels. The magmatic degassing signals were overprinted by a fluid contribution from the shallow hydrothermal system, modifying the gas compositions, contributing volatiles to the emissions, and reflecting complex processes of scrubbing, displacement, and volatilization. H2S/SO2 varies over 2 orders of magnitude through the monitoring period and demonstrates that the first eruptive episode involved hydrothermal gases, whereas the second did not. Massive degassing (>3000 T/d SO2 and H2S/SO2 > 1) followed, suggesting boiling off of the hydrothermal system. The gas emissions show a remarkable shift to purely magmatic composition (H2S/SO2 < 0.05) during the second eruptive period, reflecting the depletion of the hydrothermal system or the establishment of high‐temperature conduits bypassing remnant hydrothermal reservoirs, and the transition from phreatic to phreatomagmatic eruptive activity. PMID:27774371
NASA Astrophysics Data System (ADS)
de Moor, J. Maarten; Aiuppa, A.; Avard, G.; Wehrmann, H.; Dunbar, N.; Muller, C.; Tamburello, G.; Giudice, G.; Liuzzo, M.; Moretti, R.; Conde, V.; Galle, B.
2016-08-01
Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San José. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high-frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO2-rich gas (CO2/Stotal > 4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2 weeks before eruptions, which are accompanied by shallowly derived sulfur-rich magmatic gas emissions. Degassing modeling suggests that the deep magmatic reservoir is 8-10 km deep, whereas the shallow magmatic gas source is at 3-5 km. Two cycles of degassing and eruption are observed, each attributed to pulses of magma ascending through the deep reservoir to shallow crustal levels. The magmatic degassing signals were overprinted by a fluid contribution from the shallow hydrothermal system, modifying the gas compositions, contributing volatiles to the emissions, and reflecting complex processes of scrubbing, displacement, and volatilization. H2S/SO2 varies over 2 orders of magnitude through the monitoring period and demonstrates that the first eruptive episode involved hydrothermal gases, whereas the second did not. Massive degassing (>3000 T/d SO2 and H2S/SO2 > 1) followed, suggesting boiling off of the hydrothermal system. The gas emissions show a remarkable shift to purely magmatic composition (H2S/SO2 < 0.05) during the second eruptive period, reflecting the depletion of the hydrothermal system or the establishment of high-temperature conduits bypassing remnant hydrothermal reservoirs, and the transition from phreatic to phreatomagmatic eruptive activity.
NASA Astrophysics Data System (ADS)
Ludwig, K. A.; Kelley, D. S.; Butterfield, D. A.; Nelson, B. K.; Karson, J. A.
2003-12-01
The Lost City Hydrothermal Field (LCHF), at 30° N near the Mid-Atlantic Ridge, is an off-axis, low temperature, high-pH, ultramafic-hosted vent system. Within the field, carbonate chimneys tower up to 60 m above the seafloor, making them the tallest vent structures known. The chemistry of the vent structures and fluids at the LCHF is controlled by reactions between seawater and ultramafic rocks beneath the Atlantis massif. Mixing of warm alkaline vent fluids with seawater causes precipitation of calcium carbonate and growth of the edifaces, which range from tall, graceful pinnacles to fragile flanges and colloform deposits. Geochemical and petrological analyses of the carbonate rocks reveal distinct differences between the active and extinct structures. Actively venting chimneys and flanges are extremely porous, friable formations composed predominantly of aragonite and brucite. These structures provide important niches for well-developed microbial communities that thrive on and within the chimney walls. Some of the active chimneys may also contain the mineral ikaite, an unstable, hydrated form of calcium carbonate. TIMS and ICP-MS analyses of the carbonate chimneys show that the most active chimneys have low Sr isotope values and that they are low in trace metals (e.g., Mn, Ti, Pb). Active structures emit high-pH, low-Mg fluids at 40-90° C. The fluids also have low Sr values, indicating circulation of hydrothermal solutions through the serpentinite bedrock beneath the field. In contrast to the active structures, extinct chimneys are less porous, are well lithified, and they are composed predominantly of calcite that yields Sr isotopes near seawater values. Prolonged lower temperature seawater-hydrothermal fluid interaction within the chimneys results in the conversion of aragonite to calcite and in the enrichment of some trace metals (e.g., Mn, Ti, Co, Zn). It also promotes the incorporation of foraminifera within the outer, cemented walls of the carbonate structures. The Lost City system represents a novel natural laboratory for observing hydrothermal and biological activity in a system controlled by moderate temperature serpentinization reactions. The LCHF is the only vent field of its kind known to date; however, it is likely not unique along the global mid-ocean ridge spreading network.
NASA Astrophysics Data System (ADS)
Rosas-Carbajal, M.; Marteau, J.; Tramontini, M.; de Bremond d Ars, J.; Le Gonidec, Y.; Carlus, B.; Ianigro, J. C.; Deroussi, S.; Komorowski, J. C.; Gibert, D.
2017-12-01
Muon imaging has recently emerged as a powerful method to complement standard geophysical tools in the study of the Earth's subsurface. Muon measurements yield a radiography of the average density along the muon path, allowing to image large volumes of a geological body from a single observation point. Long-term measurements allow to infer density changes by tracking the associated variations in the muon flux. In the context of volcanic hydrothermal systems, this approach helps to characterize zones of steam formation, condensation, water infiltration and storage. We present results of imaging the La Soufrière de Guadeloupe dome and shallow active hydrothermal system with a network of muon telescopes viewing the dome from different positions around its base. First, we jointly invert the muon radiographies of the different telescopes with gravity data to obtain a three-dimensional density model of the lava dome. The model reveals an extended low density region where the hydrothermal system is most active. We then analyze the dynamics of the hydrothermal system from long-term measurements (more than 2 years of almost non-interrupted acquisition) with 5 simultaneous muon telescopes. We identify a periodicity of 1-2 months in the density increase/decrease in the most active zones below fumaroles and acid boiling ponds. Our simultaneous-muon telescope strategy provides constraints on the three-dimensional location of the density changes and an improved quantification of the associated mass flux changes. We compare the temporal trends acquired by the different muon telescopes to time-series of rainfall on the summit recharge area as well as to ground temperature profiles in the vicinity of thermal anomalies and high-discharge summit fumaroles.
de Wit, Maarten J.; Furnes, Harald
2016-01-01
Estimates of ocean temperatures on Earth 3.5 billion years ago (Ga) range between 26° and 85°C. We present new data from 3.47- to 3.43-Ga volcanic rocks and cherts in South Africa suggesting that these temperatures reflect mixing of hot hydrothermal fluids with cold marine and terrestrial waters. We describe fossil hydrothermal pipes that formed at ~200°C on the sea floor >2 km below sea level. This ocean floor was uplifted tectonically to sea level where a subaerial hydrothermal system was active at 30° to 270°C. We also describe shallow-water glacial diamictites and diagenetic sulfate mineral growth in abyssal muds. These new observations reveal that both hydrothermal systems operated in relatively cold environments and that Earth’s surface temperatures in the early Archean were similar to those in more recent times. PMID:26933677
NASA Astrophysics Data System (ADS)
Federico, Cinzia; Inguaggiato, Salvatore; Chacón, Zoraida; Londoño, John Makario; Gil, Edwing; Alzate, Diego
2017-10-01
The Nevado del Ruiz volcano is considered one of the most active volcanoes in Colombia, which can potentially threaten approximately 600,000 inhabitants. The existence of a glacier and several streams channelling in some main rivers, flowing downslope, increases the risk for the population living on the flank of the volcano in case of unrest, because of the generation of lahars and mudflows. Indeed, during the November 1985 subplinian eruption, a lahar generated by the sudden melting of the glacier killed twenty thousand people in the town of Armero. Moreover, the involvement of the local hydrothermal system has produced in the past phreatic and phreatomagmatic activity, as occurred in 1989. Therefore, the physico-chemical conditions of the hydrothermal system as well as its contribution to the shallow thermal groundwater and freshwater in terms of enthalpy and chemicals require a close monitoring. The phase of unrest occurred since 2010 and culminated with an eruption in 2012, after several years of relative stability, still maintains a moderate alert, as required by the high seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and stream water, located at 2600-5000 m of elevation on the slope of Nevado del Ruiz, analyzed for water chemistry and stable isotopes. Some of these waters are typically steam-heated (low pH and high sulfate content) by the vapour probably separating from a zoned hydrothermal system. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated the mass rate of hydrothermal steam discharging in the different springs. The composition of the hottest thermal spring (Botero Londono) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250 °C and low salinity (Cl 1500 mg/l), which suggest, along with the retrieved isotope composition, a chiefly meteoric origin. The vapour discharged at the steam vent "Nereidas" (3600 m asl) is hypothesized to be separated from a high-temperature hydrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, as well as its pH and fO2. The vapour feeding Nereidas would separate from a biphasic hydrothermal system characterized by the following parameters: t = 315 °C, P = 15 MPa, NaCl = 10 wt%, CO2 = 5 wt%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, pH would approach the value of 1.5 while fO2 would correspond to the FeO-Fe2O3 buffer. Chlorine content is estimated at 10,300 mg/l. Changes in the magmatic input into the hydrothermal system could modify its degree of vapourization and/or P-T-X conditions, thus inducing corresponding variations in vapour discharges and thermal waters. These findings, paralleled by contemporary measurements of water flow rates, could give significant clues on risk evaluation.
Identifying bubble collapse in a hydrothermal system using hidden Markov models
Dawson, P.B.; Benitez, M.C.; Lowenstern, J. B.; Chouet, B.A.
2012-01-01
Beginning in July 2003 and lasting through September 2003, the Norris Geyser Basin in Yellowstone National Park exhibited an unusual increase in ground temperature and hydrothermal activity. Using hidden Markov model theory, we identify over five million high-frequency (>15Hz) seismic events observed at a temporary seismic station deployed in the basin in response to the increase in hydrothermal activity. The source of these seismic events is constrained to within ???100 m of the station, and produced ???3500-5500 events per hour with mean durations of ???0.35-0.45s. The seismic event rate, air temperature, hydrologic temperatures, and surficial water flow of the geyser basin exhibited a marked diurnal pattern that was closely associated with solar thermal radiance. We interpret the source of the seismicity to be due to the collapse of small steam bubbles in the hydrothermal system, with the rate of collapse being controlled by surficial temperatures and daytime evaporation rates. copyright 2012 by the American Geophysical Union.
Identifying bubble collapse in a hydrothermal system using hiddden Markov models
Dawson, Phillip B.; Benitez, M.C.; Lowenstern, Jacob B.; Chouet, Bernard A.
2012-01-01
Beginning in July 2003 and lasting through September 2003, the Norris Geyser Basin in Yellowstone National Park exhibited an unusual increase in ground temperature and hydrothermal activity. Using hidden Markov model theory, we identify over five million high-frequency (>15 Hz) seismic events observed at a temporary seismic station deployed in the basin in response to the increase in hydrothermal activity. The source of these seismic events is constrained to within ~100 m of the station, and produced ~3500–5500 events per hour with mean durations of ~0.35–0.45 s. The seismic event rate, air temperature, hydrologic temperatures, and surficial water flow of the geyser basin exhibited a marked diurnal pattern that was closely associated with solar thermal radiance. We interpret the source of the seismicity to be due to the collapse of small steam bubbles in the hydrothermal system, with the rate of collapse being controlled by surficial temperatures and daytime evaporation rates.
Shanks, Wayne C.
2001-01-01
The recognition of abundant and widespread hydrothermal activity and associated unique life-forms on the ocean floor is one of the great scientific discoveries of the latter half of the twentieth century. Studies of seafloor hydrothermal processes have led to revolutions in understanding fluid convection and the cooling of the ocean crust, the chemical and isotopic mass balance of the oceans, the origin of stratiform and statabound massive-sulfide ore-deposits, the origin of greenstones and serpentinites, and the potential importance of the subseafloor biosphere. Stable isotope geochemistry has been a critical and definitive tool from the very beginning of the modern era of seafloor exploration.
Gomez-Saez, Gonzalo V; Pop Ristova, Petra; Sievert, Stefan M; Elvert, Marcus; Hinrichs, Kai-Uwe; Bühring, Solveig I
2017-01-01
The unique geochemistry of marine shallow-water hydrothermal systems promotes the establishment of diverse microbial communities with a range of metabolic pathways. In contrast to deep-sea vents, shallow-water vents not only support chemosynthesis, but also phototrophic primary production due to the availability of light. However, comprehensive studies targeting the predominant biogeochemical processes are rare, and consequently a holistic understanding of the functioning of these ecosystems is currently lacking. To this end, we combined stable isotope probing of lipid biomarkers with an analysis of the bacterial communities to investigate if chemoautotrophy, in parallel to photoautotrophy, plays an important role in autotrophic carbon fixation and to identify the key players. The study was carried out at a marine shallow-water hydrothermal system located at 5 m water depth off Dominica Island (Lesser Antilles), characterized by up to 55°C warm hydrothermal fluids that contain high amounts of dissolved Fe 2+ . Analysis of the bacterial diversity revealed Anaerolineae of the Chloroflexi as the most abundant bacterial class. Furthermore, the presence of key players involved in iron cycling generally known from deep-sea hydrothermal vents (e.g., Zetaproteobacteria and Geothermobacter ), supported the importance of iron-driven redox processes in this hydrothermal system. Uptake of 13 C-bicarbonate into bacterial fatty acids under light and dark conditions revealed active photo- and chemoautotrophic communities, with chemoautotrophy accounting for up to 65% of the observed autotrophic carbon fixation. Relatively increased 13 C-incorporation in the dark allowed the classification of ai C 15:0 , C 15:0 , and i C 16:0 as potential lipid biomarkers for bacterial chemoautotrophy in this ecosystem. Highest total 13 C-incorporation into fatty acids took place at the sediment surface, but chemosynthesis was found to be active down to 8 cm sediment depth. In conclusion, this study highlights the relative importance of chemoautotrophy compared to photoautotrophy in a shallow-water hydrothermal system, emphasizing chemosynthesis as a prominent process for biomass production in marine coastal environments influenced by hydrothermalism.
Gomez-Saez, Gonzalo V.; Pop Ristova, Petra; Sievert, Stefan M.; Elvert, Marcus; Hinrichs, Kai-Uwe; Bühring, Solveig I.
2017-01-01
The unique geochemistry of marine shallow-water hydrothermal systems promotes the establishment of diverse microbial communities with a range of metabolic pathways. In contrast to deep-sea vents, shallow-water vents not only support chemosynthesis, but also phototrophic primary production due to the availability of light. However, comprehensive studies targeting the predominant biogeochemical processes are rare, and consequently a holistic understanding of the functioning of these ecosystems is currently lacking. To this end, we combined stable isotope probing of lipid biomarkers with an analysis of the bacterial communities to investigate if chemoautotrophy, in parallel to photoautotrophy, plays an important role in autotrophic carbon fixation and to identify the key players. The study was carried out at a marine shallow-water hydrothermal system located at 5 m water depth off Dominica Island (Lesser Antilles), characterized by up to 55°C warm hydrothermal fluids that contain high amounts of dissolved Fe2+. Analysis of the bacterial diversity revealed Anaerolineae of the Chloroflexi as the most abundant bacterial class. Furthermore, the presence of key players involved in iron cycling generally known from deep-sea hydrothermal vents (e.g., Zetaproteobacteria and Geothermobacter), supported the importance of iron-driven redox processes in this hydrothermal system. Uptake of 13C-bicarbonate into bacterial fatty acids under light and dark conditions revealed active photo- and chemoautotrophic communities, with chemoautotrophy accounting for up to 65% of the observed autotrophic carbon fixation. Relatively increased 13C-incorporation in the dark allowed the classification of aiC15:0, C15:0, and iC16:0 as potential lipid biomarkers for bacterial chemoautotrophy in this ecosystem. Highest total 13C-incorporation into fatty acids took place at the sediment surface, but chemosynthesis was found to be active down to 8 cm sediment depth. In conclusion, this study highlights the relative importance of chemoautotrophy compared to photoautotrophy in a shallow-water hydrothermal system, emphasizing chemosynthesis as a prominent process for biomass production in marine coastal environments influenced by hydrothermalism. PMID:28484442
The role of magmas in the formation of hydrothermal ore deposits
Hedenquist, Jeffrey W.; Lowenstern, Jacob B.
1994-01-01
Magmatic fluids, both vapour and hypersaline liquid, are a primary source of many components in hydrothermal ore deposits formed in volcanic arcs. These components, including metals and their ligands, become concentrated in magmas in various ways from various sources, including subducted oceanic crust. Leaching of rocks also contributes components to the hydrothermal fluid—a process enhanced where acid magmatic vapours are absorbed by deeply circulating meteoric waters. Advances in understanding the hydrothermal systems that formed these ore deposits have come from the study of their active equivalents, represented at the surface by hot springs and volcanic fumaroles.
Bayraktarov, Elisa; Price, Roy E.; Ferdelman, Timothy G.; Finster, Kai
2013-01-01
Microbial sulfate reduction (SR) is a dominant process of organic matter mineralization in sulfate-rich anoxic environments at neutral pH. Recent studies have demonstrated SR in low pH environments, but investigations on the microbial activity at variable pH and CO2 partial pressure are still lacking. In this study, the effect of pH and pCO2 on microbial activity was investigated by incubation experiments with radioactive 35S targeting SR in sediments from the shallow-sea hydrothermal vent system of Milos, Greece, where pH is naturally decreased by CO2 release. Sediments differed in their physicochemical characteristics with distance from the main site of fluid discharge. Adjacent to the vent site (T ~40–75°C, pH ~5), maximal sulfate reduction rates (SRR) were observed between pH 5 and 6. SR in hydrothermally influenced sediments decreased at neutral pH. Sediments unaffected by hydrothermal venting (T ~26°C, pH ~8) expressed the highest SRR between pH 6 and 7. Further experiments investigating the effect of pCO2 on SR revealed a steep decrease in activity when the partial pressure increased from 2 to 3 bar. Findings suggest that sulfate reducing microbial communities associated with hydrothermal vent system are adapted to low pH and high CO2, while communities at control sites required a higher pH for optimal activity. PMID:23658555
Bayraktarov, Elisa; Price, Roy E; Ferdelman, Timothy G; Finster, Kai
2013-01-01
Microbial sulfate reduction (SR) is a dominant process of organic matter mineralization in sulfate-rich anoxic environments at neutral pH. Recent studies have demonstrated SR in low pH environments, but investigations on the microbial activity at variable pH and CO2 partial pressure are still lacking. In this study, the effect of pH and pCO2 on microbial activity was investigated by incubation experiments with radioactive (35)S targeting SR in sediments from the shallow-sea hydrothermal vent system of Milos, Greece, where pH is naturally decreased by CO2 release. Sediments differed in their physicochemical characteristics with distance from the main site of fluid discharge. Adjacent to the vent site (T ~40-75°C, pH ~5), maximal sulfate reduction rates (SRR) were observed between pH 5 and 6. SR in hydrothermally influenced sediments decreased at neutral pH. Sediments unaffected by hydrothermal venting (T ~26°C, pH ~8) expressed the highest SRR between pH 6 and 7. Further experiments investigating the effect of pCO2 on SR revealed a steep decrease in activity when the partial pressure increased from 2 to 3 bar. Findings suggest that sulfate reducing microbial communities associated with hydrothermal vent system are adapted to low pH and high CO2, while communities at control sites required a higher pH for optimal activity.
NASA Astrophysics Data System (ADS)
Konn, C.; Fourré, E.; Jean-Baptiste, P.; Donval, J. P.; Guyader, V.; Birot, D.; Alix, A. S.; Gaillot, A.; Perez, F.; Dapoigny, A.; Pelleter, E.; Resing, J. A.; Charlou, J. L.; Fouquet, Y.
2016-10-01
The study area is close to the Wallis and Futuna Islands in the French EEZ. It exists on the western boundary of the fastest tectonic area in the world at the junction of the Lau and North-Fiji basins. At this place, the unstable back-arc accommodates the plate motion in three ways: (i) the north Fiji transform fault, (ii) numerous unstable spreading ridges, and (iii) large areas of recent volcanic activity. This instability creates bountiful opportunity for hydrothermal discharge to occur. Based on geochemical (CH4, TDM, 3He) and geophysical (nephelometry) tracer surveys: (1) no hydrothermal activity could be found on the Futuna Spreading Centre (FSC) which sets the western limit of hydrothermal activity; (2) four distinct hydrothermal active areas were identified: Kulo Lasi Caldera, Amanaki Volcano, Fatu Kapa and Tasi Tulo areas; (3) extensive and diverse hydrothermal manifestations were observed and especially a 2D distribution of the sources. At Kulo Lasi, our data and especially tracer ratios (CH4/3He 50×106 and CH4/TDM 4.5) reveal a transient CH4 input, with elevated levels of CH4 measured in 2010, that had vanished in 2011, most likely caused by an eruptive magmatic event. By contrast at Amanaki, vertical tracer profiles and tracer ratios point to typical seawater/basalt interactions. Fatu Kapa is characterised by a substantial spatial variability of the hydrothermal water column anomalies, most likely due to widespread focused and diffuse hydrothermal discharge in the area. In the Tasi Tulo zone, the hydrothermal signal is characterised by a total lack of turbidity, although other tracer anomalies are in the same range as in nearby Fatu Kapa. The background data set revealed the presence of a Mn and 3He chronic plume due to the extensive and cumulative venting over the entire area. To that respect, we believe that the joined domain composed of our active area and the nearby active area discovered in the East by Lupton et al. (2012) highly contribute to the extensive Tonga-Fiji plume and which thus may not originate from a sole source near the Samoa. Our results also emphasize and support the idea that back-arc hydrothermal systems have a significant input to the regional and global ocean and maybe more important than their MOR analogues.
NASA Astrophysics Data System (ADS)
Hahm, Doshik; Baker, Edward T.; Siek Rhee, Tae; Won, Yong-Jin; Resing, Joseph A.; Lupton, John E.; Lee, Won-Kyung; Kim, Minjeong; Park, Sung-Hyun
2015-09-01
The Australian-Antarctic Ridge (AAR) is one of the largest unexplored regions of the global mid-ocean ridge system. Here, we report a multiyear effort to locate and characterize hydrothermal activity on two first-order segments of the AAR: KR1 and KR2. To locate vent sites on each segment, we used profiles collected by Miniature Autonomous Plume Recorders on rock corers during R/V Araon cruises in March and December of 2011. Optical and oxidation-reduction-potential anomalies indicate multiple active sites on both segments. Seven profiles on KR2 found 3 sites, each separated by ˜25 km. Forty profiles on KR1 identified 17 sites, some within a few kilometer of each other. The spatial density of hydrothermal activity along KR1 and KR2 (plume incidence of 0.34) is consistent with the global trend for a spreading rate of ˜70 mm/yr. The densest area of hydrothermal activity, named "Mujin," occurred along the 20 km-long inflated section near the segment center of KR1. Continuous plume surveys conducted in January-February of 2013 on R/V Araon found CH4/3He (1 - 15 × 106) and CH4/Mn (0.01-0.5) ratios in the plume samples, consistent with a basaltic-hosted system and typical of ridges with intermediate spreading rates. Additionally, some of the plume samples exhibited slightly higher ratios of H2/3He and Fe/Mn than others, suggesting that those plumes are supported by a younger hydrothermal system that may have experienced a recent eruption. The Mujin-field was populated by Kiwa crabs and seven-armed Paulasterias starfish previously recorded on the East Scotia Ridge, raising the possibility of circum-Antarctic biogeographic connections of vent fauna.
Geochemical constraints on chemolithoautotrophic reactions in hydrothermal systems
NASA Astrophysics Data System (ADS)
Shock, Everett L.; McCollom, Thomas; Schulte, Mitchell D.
1995-06-01
Thermodynamic calculations provide the means to quantify the chemical disequilibrium inherent in the mixing of redeuced hydrothermal fluids with seawater. The chemical energy available for metabolic processes in these environments can be evaluated by taking into account the pressure and temperature dependence of the apparent standard Gibbs free energies of reactions in the S-H2-H2O system together with geochemical constraints on pH, activities of aqueous sulfur species and fugacities of H2 and/or O2. Using present-day mixing of hydrothermal fluids and seawater as a starting point, it is shown that each mole of H2S entering seawater from hydrothermal fluids represents about 200,000 calories of chemical energy for metabolic systems able to catalyze H2S oxidation. Extrapolating to the early Earth, which was likely to have had an atmosphere more reduced than at present, shows that this chemical energy may have been a factor of two or so less. Nevertheless, mixing of hydrothermal fluids with seawater would have been an abundant source of chemical energy, and an inevitable consequence of the presence of an ocean on an initially hot Earth. The amount of energy available was more than enough for organic synthesis from CO2 or CO, and/or polymer formation, indicating that the vicinity of hydrothermal systems at the sea floor was an ideal location for the emergence of the first chemolithoautotrophic metabolic systems.
Geochemical constraints on chemolithoautotrophic reactions in hydrothermal systems
NASA Technical Reports Server (NTRS)
Shock, Everett L.; Mccollom, Thomas; Schulte, Mithell D.
1995-01-01
Thermodynamic calculations provide the means to quantify the chemical disequilibrium inherent in the mixing of reduced hydrothermal fluids with seawater. The chemical energy available for metabolic processes in these environments can be evaluated by taking into account the pressure and temperature dependence of the apparent standard Gibbs free energies of reactions in the S-H2-H2O system together with geochemical constraints on pH, activities of aqueous sulfur species and fugacities of H2 and/or O2. Using present-day mixing of hydrothermal fluids and seawater as a starting point, it is shown that each mole of H2S entering seawater from hydrothermal fluids represents about 200,000 calories of chemical energy for metabolic systems able to catalyze H2S oxidation. Extrapolating to the early Earth, which was likely to have had an atmosphere more reduced than at present, shows that this chemical energy may have been a factor of two or so less. Nevertheless, mixing of hydrothermal fluids with seawater would have been an abundant source of chemical energy, and an inevitable consequence of the presence of an ocean on an initially hot Earth. The amount of energy available was more than enough for organic synthesis from CO2 or CO, and/or polymer formation, indicating that the vicinity of hydrothermal systems at the sea floor was an ideal location for the emergence of the first chemolithoautotrophic metabolic systems.
The Third Dimension of an Active Back-arc Hydrothermal System: ODP Leg 193 at PACMANUS
NASA Astrophysics Data System (ADS)
Binns, R.; Barriga, F.; Miller, D.
2001-12-01
This first sub-seafloor examination of an active hydrothermal system hosted by felsic volcanics, at a convergent margin, obtained drill core from a high-T "smoker" site (penetrated to sim200 mbsf) and a low-T site of diffuse venting (~400mbsf). We aimed to delineate the lateral and vertical variability in mineralisation and alteration patterns, so as to understand links between volcanological, structural and hydrothermal phenomena and the sources of fluids, and to establish the nature and extent of microbial activity within the system. Technological breakthroughs included deployment of a new hard-rock re-entry system, and direct comparison in a hardrock environment of structural images obtained by wireline methods and logging-while-drilling. The PACMANUS hydrothermal site, at the 1700m-deep crest of a 500m-high layered sequence of dacitic lavas, is notable for baritic massive sulfide chimneys rich in Cu, Zn, Au and Ag. Below an extensive cap 5-40m thick of fresh dacite-rhyodacite, we found unexpectedly pervasive hydrothermal alteration of vesicular and flow-banded precursors, accompanied by variably intense fracturing and anhydrite-pyrite veining. Within what appears one major hydrothermal event affecting the entire drilled sequence, there is much overprinting and repetition of distinctly allochemical argillaceous (illite-chlorite), acid-sulfate (pyrophyllite-anhydrite) and siliceous assemblages. The alteration profiles include a transition from metastable cristobalite to quartz at depth, and are similar under low-T and high-T vent sites but are vertically condensed in a manner suggesting higher thermal gradients beneath the latter. The altered rocks are surprisingly porous (average 25%). Retention of intergranular pore spaces and open vesicles at depth implies elevated hydrothermal pressures, whereas evidence from fluid inclusions and hydrothermal brecciation denotes local or sporadic phase separation. A maximum measured temperature of 313 degC measured 8 days after drilling (360 mbsf at the diffuse venting site), if indicative of thermal gradient, suggests the presence of a very shallow ( ~1.5 km below seafloor) magmatic heat source. While isotopic characteristics of anhydrite suggest an irregularly varying component of magmatic fluid, the abundance of this mineral implies a substantial role for circulating seawater within the subsurface hydrothermal system. Other than the near-ubiquitous, fine grained disseminated pyrite in altered rocks, we found little sulfide mineralisation. Pyritic vein networks and breccias are extensive in the rapidly penetrated, but poorly recovered, interval down to 120 mbsf within our "high-T end-member" hole spudded on a mound surmounted by active (280 degC) chimneys. Anhydrite and open cavities possibly dominate this interval, from which a possible example of subhalative semi-massive sulfide containing chalcopyrite and some sphalerite was recovered near 30 mbsf. At the low-T and high-T vent sites respectively, anaerobic microbes were recorded by direct counting at depths down to 99 and 78 mbsf, and in 90 degC cultivation experiments at 69-107 and 99-129 mbsf. >http://www-odp.tamu.edu/publications/prelim/193
DOE Office of Scientific and Technical Information (OSTI.GOV)
Moore, R.B.; Trusdell, F.A.
1993-08-01
This paper summarizes studies of the structure, stratigraphy, petrology, drill holes, eruption frequency, and volcanic and seismic hazards of Kilauea volcano. All the volcano is discussed, but the focus is on its lower east rift zone (LERZ) because active exploration for geothermal energy is concentrated in that area. Kilauea probably has several separate hydrothermal-convection systems that develop in response to the dynamic behavior of the volcano and the influx of abundant meteoric water. Important features of some of these hydrothermal-convection systems are known through studies of surface geology and drill holes. Observations of eruptions during the past two centuries, detailedmore » geologic mapping, radiocarbon dating, and paleomagnetic secular-variation studies indicate that Kilauea has erupted frequently from its summit and two radial rift zones during Quaternary time. Petrologic studies have established that Kilauea erupts only tholeiitic basalt. Extensive ash deposits at Kilauea's summit and on its LERZ record locally violent, but temporary, disruptions of local hydrothermal-convection systems during the interaction of water or steam with magma. Recent drill holes on the LERZ provide data on the temperatures of the hydrothermal-convection systems, intensity of dike intrusion, porosity and permeability, and an increasing amount of hydrothermal alteration with depth. The prehistoric and historic record of volcanic and seismic activity indicates that magma will continue to be supplied to deep and shallow reservoirs beneath Kilauea's summit and rift zones and that the volcano will be affected by eruptions and earthquakes for many thousands of years. 71 refs., 2 figs.« less
Moore, R.B.; Trusdell, F.A.
1993-01-01
This paper summarizes studies of the structure, stratigraphy, petrology, drill holes, eruption frequency, and volcanic and seismic hazards of Kilauea volcano. All the volcano is discussed, but the focus is on its lower cast rift zone (LERZ) because active exploration for geothermal energy is concentrated in that area. Kilauea probably has several separate hydrothermal-convection systems that develop in response to the dynamic behavior of the volcano and the influx of abundant meteoric water. Important features of some of these hydrothermal-convection systems are known through studies of surface geology and drill holes. Observations of eruptions during the past two centuries, detailed geologic mapping, radiocarbon dating, and paleomagnetic secular-variation studies indicate that Kilauea has erupted frequently from its summit and two radial rift zones during Quaternary time. Petrologic studies have established that Kilauea erupts only tholeiitic basalt. Extensive ash deposits at Kilauea's summit and on its LERZ record locally violent, but temporary, disruptions of local hydrothermal-convection systems during the interaction of water or steam with magma. Recent drill holes on the LERZ provide data on the temperatures of the hydrothermal-convection systems, intensity of dike intrusion, porosity and permeability, and an increasing amount of hydrothermal alteration with depth. The prehistoric and historic record of volcanic and seismic activity indicates that magma will continue to be supplied to deep and shallow reservoirs beneath Kilauea's summit and rift zones and that the volcano will be affected by eruptions and earthquakes for many thousands of years. ?? 1993.
Yang, Liyang; Zhuang, Wan-E; Chen, Chen-Tung Arthur; Wang, Bing-Jye; Kuo, Fu-Wen
2017-03-15
The submarine hydrothermal systems are extreme environments where active cycling of dissolved organic matter (DOM) may occur. However, little is known about the optical properties and bioavailability of hydrothermal DOM, which could provide valuable insights into its transformation processes and biogeochemical reactivity. The quantity, quality, and bioavailability of DOM were investigated for four very different hydrothermal vents east of Taiwan, using dissolved organic carbon (DOC), absorption spectroscopy, and fluorescence excitation-emission matrices-parallel factor analysis (EEM-PARAFAC). The DOC and absorption coefficient a 280 were both lower in the two hydrothermal vents off the Orchid Island and on the Green Island than in the surrounding seawater and the two vents off the Kueishantao Island, indicating effective removals of DOM in the former two hydrothermal systems owing to possible adsorption/co-precipitation and thermal degradation respectively. The four hydrothermal DOM showed notable differences in the absorption spectral slope S 275-295 , humification index HIX, biological index BIX, EEM spectra, and the relative distributions of seven PARAFAC components. The results demonstrated a high diversity of chemical composition and transformation history of DOM under contrasting hydrothermal conditions. The little change in the hydrothermal DOC after 28-day microbial incubations indicated a low bioavailability of the bulk DOM, and different PARAFAC components showed contrasting bioavailability. The results have profound implications for understanding the biogeochemical cycling and environmental effects of hydrothermal DOM in the marine environments. Copyright © 2017 Elsevier Ltd. All rights reserved.
Winkel, Matthias; Pjevac, Petra; Kleiner, Manuel; Littmann, Sten; Meyerdierks, Anke; Amann, Rudolf; Mußmann, Marc
2014-12-01
Diffuse hydrothermal fluids often contain organic compounds such as hydrocarbons, lipids, and organic acids. Microorganisms consuming these compounds at hydrothermal sites are so far only known from cultivation-dependent studies. To identify potential heterotrophs without prior cultivation, we combined microbial community analysis with short-term incubations using (13)C-labeled acetate at two distinct hydrothermal systems. We followed cell growth and assimilation of (13)C into single cells by nanoSIMS combined with fluorescence in situ hybridization (FISH). In 55 °C-fluids from the Menez Gwen hydrothermal system/Mid-Atlantic Ridge, a novel epsilonproteobacterial group accounted for nearly all assimilation of acetate, representing the first aerobic acetate-consuming member of the Nautiliales. In contrast, Gammaproteobacteria dominated the (13) C-acetate assimilation in incubations of 37 °C-fluids from the back-arc hydrothermal system in the Manus Basin/Papua New Guinea. Here, 16S rRNA gene sequences were mostly related to mesophilic Marinobacter, reflecting the high content of seawater in these fluids. The rapid growth of microorganisms upon acetate addition suggests that acetate consumers in diffuse fluids are copiotrophic opportunists, which quickly exploit their energy sources, whenever available under the spatially and temporally highly fluctuating conditions. Our data provide first insights into the heterotrophic microbial community, catalyzing an under-investigated part of microbial carbon cycling at hydrothermal vents. © 2014 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.
Sorey, M.L.; Suemnicht, G.A.; Sturchio, N.C.; Nordquist, G.A.
1991-01-01
Data collected since 1985 from test drilling, fluid sampling, and geologic and geophysical investigations provide a clearer definition of the hydrothermal system in Long Valley caldera than was previously available. This information confirms the existence of high-temperature (> 200??C) reservoirs within the volcanic fill in parts of the west moat. These reservoirs contain fluids which are chemically similar to thermal fluids encountered in the central and eastern parts of the caldera. The roots of the present-day hydrothermal system (the source reservoir, principal zones of upflow, and the magmatic heat source) most likely occur within metamorphic basement rocks beneath the western part of the caldera. Geothermometer-temperature estimates for the source reservoir range from 214 to 248??C. Zones of upflow of hot water could exist beneath the plateau of moat rhyolite located west of the resurgent dome or beneath Mammoth Mountain. Lateral flow of thermal water away from such upflow zones through reservoirs in the Bishop Tuff and early rhyolite accounts for temperature reversals encountered in most existing wells. Dating of hot-spring deposits from active and inactive thermal areas confirms previous interpretations of the evolution of hydrothermal activity that suggest two periods of extensive hot-spring discharge, one peaking about 300 ka and another extending from about 40 ka to the present. The onset of hydrothermal activity around 40 ka coincides with the initiation of rhyolitic volcanism along the Mono-Inyo Craters volcanic chain that extends beneath the caldera's west moat. ?? 1991.
NASA Astrophysics Data System (ADS)
Syverson, D. D.; Scheuermann, P.; Pester, N. J.; Higgins, J. A.; Seyfried, W. E., Jr.
2016-12-01
The elemental and isotopic mass balance of Ca and Sr between seawater and basalt at mid-ocean ridge (MOR) hydrothermal systems is an integrated reflection of the various physiochemical processes, which induce chemical exchange, in the subseafloor. Specifically, the processes of anhydrite precipitation and recrystallization are recognized to be important controls on governing the Ca and Sr elemental and isotope compositions of high temperature vent fluids, however, few experimental data exist to constrain these geochemical effects. Thus, to better understand the associated Sr/Ca partitioning and Ca isotope fractionation and rate of exchange between anhydrite and dissolved constituents, anhydrite precipitation and recrystallization experiments were performed at 175, 250, and 350°C and 500 bar at chemical conditions indicative of active MOR hydrothermal systems. The experimental data suggest that upon entrainment of seawater into MOR hydrothermal systems, anhydrite will precipitate rapidly and discriminate against the heavy isotopes of Ca (Δ44/40Ca(Anh-Fluid) = -0.68 - -0.25 ‰), whereas Sr/Ca partitioning depends on the saturation state of the evolving hydrothermal fluid with respect to anhydrite at each PTX (KD(Anh-Fluid) = 1.24 - 0.55). Coupling experimental constraints with the temperature gradient inferred for high temperature MOR hydrothermal systems in the oceanic crust, data suggest that the Ca isotope and Sr elemental composition of anhydrite formed near the seafloor will be influenced by disequilibrium effects, while, at higher temperatures further into the oceanic crust, anhydrite will be representative of equilibrium Sr/Ca partitioning and Ca isotope fractionation conditions. These experimental observations are consistent with analyzed Sr/Ca and Ca isotope compositions of anhydrites and vent fluids sampled from modern MOR hydrothermal systems1,2 and can be used to further constrain the geochemical effects of hydrothermal circulation in the oceanic crust throughout Earth's history. 1 Tivey, M. K. Generation of Seafloor Hydrothermal Deposits. Oceanography 20, 50-66 (2007).2 Amini, M. et al. Calcium isotope (δ44/40Ca) fractionation along hydrothermal pathways, Logatchev field (Mid-Atlantic Ridge, 14°45'N). Geochimica et Cosmochimica Acta 72, 4107-4122 (2008).
The Biogeochemistry of Sulfur in Hydrothermal Systems
NASA Technical Reports Server (NTRS)
Schulte, Mitchell; Rogers, K. L.; DeVincenzi, Donald L. (Technical Monitor)
2001-01-01
The incorporation of sulfur into many biomolecules likely dates back to the development of the earliest metabolic strategies. Sulfur is common in enzymes and co-enzymes and is an indispensable structural component in many peptides and proteins. Early metabolism may have been heavily influenced by the abundance of sulfide minerals in hydrothermal systems. The incorporation of sulfur into many biomolecules likely dates back to the development of the earliest metabolic strategies. Sulfur is common in enzymes and co-enzymes and is an indispensable structural component in many peptides and proteins. Early metabolism may have been heavily influenced by the abundance of sulfide minerals in hydrothermal systems. Understanding how sulfur became prevalent in biochemical processes and many biomolecules requires knowledge of the reaction properties of sulfur-bearing compounds. We have previously estimated thermodynamic data for thiols, the simplest organic sulfur compounds, at elevated temperatures and pressures. If life began in hydrothermal environments, it is especially important to understand reactions at elevated temperatures among sulfur-bearing compounds and other organic molecules essential for the origin and persistence of life. Here we examine reactions that may have formed amino acids with thiols as reaction intermediates in hypothetical early Earth hydrothermal environments. (There are two amino acids, cysteine and methionine, that contain sulfur.) Our calculations suggest that significant amounts of some amino acids were produced in early Earth hydrothermal fluids, given reasonable concentrations H2, NH3, H2S and CO. For example, preliminary results indicate that glycine activities as high as 1 mmol can be reached in these systems at 100 C. Alanine formation from propanethiol is also a favorable reaction. On the other hand, the calculated equilibrium log activities of cysteine and serine from propanethiol are -21 and -19, respectively, at 100 C. These results indicate that while amino acid formation with thiols as intermediates is favored in some cases, other mechanisms may have been necessary to produce significant amounts of other amino acids. Coupled with our previous results for thiols, these studies imply that sulfur may have been easily incorporated into the organic geochemistry of early Earth hydrothermal systems, leading to its widespread use in biomolecules. Formation of more complex biomolecules in hydrothermal systems may have required sulfur-bearing organic compounds as reaction intermediates.
NASA Astrophysics Data System (ADS)
Maucourant, Samuel; Giammanco, Salvatore; Greco, Filippo; Dorizon, Sophie; Del Negro, Ciro
2014-06-01
A multidisciplinary approach integrating self-potential, soil temperature, heat flux, CO2 efflux and gravity gradiometry signals was used to investigate a relatively small fissure-related hydrothermal system near the summit of Mt. Etna volcano (Italy). Measurements were performed through two different surveys carried out at the beginning and at the end of July 2009, right after the end of the long-lived 2008-2009 flank eruption and in coincidence with an increase in diffuse flank degassing related to a reactivation of the volcano, leading to the opening of a new summit vent (NSEC). The main goal was to use a multidisciplinary approach to the detection of hidden fractures in an area of evident near-surface hydrothermal activity. Despite the different methodologies used and the different geometry of the sampling grid between the surveys, all parameters concurred in confirming that the study area is crossed by faults related with the main fracture systems of the south flank of the volcano, where a continuous hydrothermal circulation is established. Results also highlighted that hydrothermal activity in this area changed both in space and in time. These changes were a clear response to variations in the magmatic system, notably to migration of magma at various depth within the main feeder system of the volcano. The results suggest that this specific area, initially chosen as the optimal test-site for the proposed approach, can be useful in order to get information on the potential reactivation of the summit craters of Mt. Etna.
The Lassen hydrothermal system
Ingebritsen, Steven E.; Bergfeld, Deborah; Clor, Laura; Evans, William C.
2016-01-01
The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 °C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 ± 10 kg/s of steam (~115 MW) and 23 ± 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km3/Ma, and the ongoing rates of heat and magmatic CO2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4–5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km2, the average conductive heat flux over that area is >25 W/m2, and the conductive-boundary length <50 m. Observational records of hydrothermal discharge are likely too short to document long-term transients, whether they are intrinsic to the system or owe to various geologic events such as the eruption of Lassen Peak at 27 ka, deglaciation beginning ~18 ka, the eruptions of Chaos Crags at 1.1 ka, or the minor 1914–1917 eruption at the summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009–present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.
Experimental constraints on hydrothermal activities in Enceladus
NASA Astrophysics Data System (ADS)
Sekine, Y.; Shibuya, T.; Suzuki, K.; Kuwatani, T.
2012-12-01
One of the most remarkable findings by the Cassini-Huygens mission is perhaps water-rich plumes erupting from the south-pole region of Enceladus [1]. Given such geological activity and the detection of sodium salts in the plume, the interior of Enceladus is highly likely to contain an interior ocean interacting with the rock core [2]. A primary question regarding astrobiology and planetary science is whether Enceladus has (or had) hydrothermal activities in the interior ocean. Because N2 might be formed by thermal dissociation of primordial NH3 [3], the presence of N2 in the plume may be a possible indicator for the presence of hydrothermal activities in Enceladus. However, the Cassini UVIS revealed that the plumes do not contain large amounts of N2 [4]. Although these observations may not support the presence of hydrothermal activities, whether NH3 dissociation proceeds strongly depends on the kinetics of hydrothermal reactions and interactions with the rock components, which remain largely unknown. Furthermore, the Cassini CDA recently showed that small amounts of SiO2 might have been included in the plume dusts [5]. Formation of amorphous SiO2 usually occurs when high-temperature and/or high-pH solution with high concentrations of dissolved SiO2 cools and/or is neutralized. Thus, the presence of SiO2 in the plume dusts may suggest the presence of a temperature and/or pH gradient in the ocean. However, no laboratory experiments have investigated what processes control pH and SiO2 concentrations in hydrothermal fluids possibly existing in Enceladus. Here, we show the results of laboratory experiments simulating hydrothermal systems on Enceladus. As the initial conditions, we used both aqueous solution of high concentrations (0.01-2%) of NH3 and NaHCO3 and powdered olivine as an analog for the rock components. Our experimental results show that formation of N2 from NH3 is kinetically and thermodynamically inhibited even under high temperature conditions (< 400°C). This is because NH3 decomposition proceeds inefficiently due to efficient H2 production via serpentinization. Our experimental results also suggest that SiO2 concentration dissolved in hydrothermal fluids simulating Enceladus' condition would be buffered by the serpentine-brucite system. The presence of NH3 in the hydrothermal conditions keeps pH of the solution high (pH 9-11). We suggest that under such conditions, SiO2 concentrations in the fluids would be 0.1 mmol/L or less for temperature < 350°C. Given the SiO2 solubility of 1-10 mmol/L at 0°C and pH 9-11, direct formation of amorphous SiO2 would not occur in Enceladus' hydrothermal systems. To produce amorphous SiO2, large-scale hydrothermal activities and subsequent concentration of dissolved SiO2 in the ocean (due to freezing and/or evaporation of liquid water) would be required, which is consistent with high concentrations of radiogenic Ar and sodium salts in the plume [2, 6]. [1] Porco et al., Science 311, 1393 (2006). [2] Postberg et al., Nature 459, 1098 (2009). [3] Matson et al., Icarus 187, 569 (2007). [4] Hansen t al., Geophs. Res. Lett. 38, L11202 (2011). [5] Hsu et al., EOS Trans. AGU, (2010). [6] Waite et al., Nature 460, 487 (2009).
NASA Astrophysics Data System (ADS)
Johannessen, Karen C.; Vander Roost, Jan; Dahle, Håkon; Dundas, Siv H.; Pedersen, Rolf B.; Thorseth, Ingunn H.
2017-04-01
Diffuse low-temperature hydrothermal vents on the seafloor host neutrophilic microaerophilic Fe-oxidizing bacteria that utilize the Fe(II) supplied by hydrothermal fluids and produce intricate twisted and branching extracellular stalks. The growth behavior of Fe-oxidizing bacteria in strongly opposing gradients of Fe(II) and O2 have been thoroughly investigated in laboratory settings to assess whether extracellular stalks and aligned biomineralized fabrics may serve as biosignatures of Fe-oxidizing bacteria and indications of palaeo-redox conditions in the rock record. However, the processes controlling the growth of biogenic Fe-oxyhydroxide deposits in natural, modern hydrothermal systems are still not well constrained. In this study, we aimed to establish how variations in the texture of stratified hydrothermal Fe-oxyhydroxide deposits are linked to the physicochemical conditions of the hydrothermal environment. We conducted 16S rRNA gene analyses, microscopy and geochemical analyses of laminated siliceous Fe-mounds from the Jan Mayen Vent Fields at the Arctic Mid-Ocean Ridge. Chemical analyses of low- and high-temperature hydrothermal fluids were performed to characterize the hydrothermal system in which the Fe-deposits form. Our results reveal synchronous inter-laminar variations in texture and major and trace element geochemistry. The Fe-deposits are composed of alternating porous laminae of mineralized twisted stalks and branching tubes, Mn-rich horizons with abundant detrital sediment, domal internal cavities and thin P- and REE-enriched lamina characterized by networks of ≪1 μm wide fibers. Zetaproteobacteria constitute one third of the microbial community in the surface layer of actively forming mounds, indicating that microbial Fe-oxidation is contributing to mound accretion. We suggest that Mn-oxide precipitation and detrital sediment accumulation take place during periodically low hydrothermal fluid discharge conditions. The elevated concentrations of P and REE in distinct laminae suggest Fe-cycling and accumulation of diagenetic species at depth in the deposits during hydrothermal quiescence and co-precipitation of these species with Fe-oxyhydroxides at the mound surface with reinitiated hydrothermal discharge. The origin of the low-temperature hydrothermal source fluid and the Fe-deposits are evident by low LREE/HREE ratios and negative Eu-anomalies, which clearly differ from the LREE and Eu enrichment of nearby high-temperature white smoker venting fluids. Our study demonstrates that hydrothermal fluctuations exert the primary control on the formation of laminae and the activity of Fe-oxidizing bacteria in marine hydrothermal Fe-deposits and indicates that REE-patterns may be used to distinguish high-temperature plume fallout and biomineralized low-temperature Fe-deposits in the rock record.
The Activity of Trace Metals in Aqueous Systems and the Effect of Corrosion Control Inhibitors
1975-10-01
corrosion product on metallic zinc 49 Uncombined slilica as quartz or cristobalite forms by the hydrothermal alteration of solid zilicates or by direct... hydrothermally . The com- position of the solids are dependent on temperature and pressure as well as on the relative concentrations of the dissolved...of the few anhydrous simple silicates formed hydrotherm - ally. The sodium silicates, Na2SiO 3 and BNa 2Si205, are somewhat soluble in high temperature
NASA Astrophysics Data System (ADS)
Inguaggiato, S.; Federico, C.; Chacon, Z.; Londono, J. M.; Alzate, D. M.; Gil, E.
2015-12-01
The Nevado del ruiz volcano (NdR, 5321m asl), one of the most active in Colombia, threatens about 600,000 people. The existence of an ice cap and several streams channeling in some main rivers increase the risk of lahars and mudflows in case of unrest, as occurred during the November 1985 eruption, which caused 20,000 casualties. The involvement of the local hydrothermal system has also produced in the past phreatic and phreatomagmatic activity, as in 1985 and 1989. After more than 7 years of relative stability, since 2010, the still ongoing phase of unrest has produced two small eruption in 2012, and still maintains in high levels of seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and streamwater, located at 2600-5000 m asl, analyzed for water chemistry and stable isotopes. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated the mass rate of steam discharging in the different steam-heated springs. The composition of the hottest thermal spring (Botero Londoño) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250°C and low salinity (Cl ~1500 mg/l), which suggest a chiefly meteoric origin, as also confirmed by the isotope composition retrieved for the hydrothermal water. The vapour discharged at the steam vent "Nereidas" (3600 m asl) is hypothesised to be separated from a high-temperature hyrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, as well as its pH and fO2. The vapour feeding Nereidas would separate from a byphasic hydrothermal system characterised by the follow parameters: t= 315°C, P=19 MPa, NaCl= 15 %, CO2 = 9%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, we obtain pH=2, fO2 fixed by FeO-Fe2O3 buffer, and [Cl]=12000 mg/l. Changes in the magmatic input into the hydrothermal system could modify its degree of vaporization and/or P-T-X conditions, thus inducing corresponding variations in vapour discharges and thermal waters. These findings, paralleled by contemporary measurements of water flow rates, could give significant clues on risk evaluation at NdR.
Hydrothermal mineralization at seafloor spreading centers
NASA Astrophysics Data System (ADS)
Rona, Peter A.
1984-01-01
The recent recognition that metallic mineral deposits are concentrated by hydrothermal processes at seafloor spreading centers constitutes a scientific breakthrough that opens active sites at seafloor spreading centers as natural laboratories to investigate ore-forming processes of such economically useful deposits as massive sulfides in volcanogenic rocks on land, and that enhances the metallic mineral potential of oceanic crust covering two-thirds of the Earth both beneath ocean basins and exposed on land in ophiolite belts. This paper reviews our knowledge of processes of hydrothermal mineralization and the occurrence and distribution of hydrothermal mineral deposits at the global oceanic ridge-rift system. Sub-seafloor hydrothermal convection involving circulation of seawater through fractured rocks of oceanic crust driven by heat supplied by generation of new lithosphere is nearly ubiquitous at seafloor spreading centers. However, ore-forming hydrothermal systems are extremely localized where conditions of anomalously high thermal gradients and permeability increase hydrothermal activity from the ubiquitous low-intensity background level (⩽ 200°C) to high-intensity characterized by high temperatures ( > 200-c.400°C), and a rate and volume of flow sufficient to sustain chemical reactions that produce acid, reducing, metal-rich primary hydrothermal solutions. A series of mineral phases with sulfides and oxides as high- and low-temperature end members, respectively, are precipitated along the upwelling limb and in the discharge zone of single-phase systems as a function of increasing admixture of normal seawater. The occurrence of hydrothermal mineral deposits is considered in terms of spatial and temporal frames of reference. Spatial frames of reference comprise structural features along-axis (linear sections that are the loci of seafloor spreading alternating with transform faults) and perpendicular to axis (axial zone of volcanic extrusion and marginal zones of active extension) common to all spreading centers, regional tectonic setting determined by stage (early, advanced), and rate (slow, intermediate-to-fast) of opening of an ocean basin about a spreading center, and local tectonic sub-setting that incorporates anomalous structural and thermal conditions conducive to mineral concentration (thermal gradient, permeability, system geometry, leaky versus tight hydrothermal systems). Temporal frames of reference comprise the relation between mineral concentration and timing of regional plutonic, volcanic and tectonic cycles and of episodic local physical and chemical events (transient stress, fluctuating heat transfer, intrusion-extrusion, fracturing, sealing, etc.). Types of hydrothermal deposits are not uniquely associated with specific tectonic settings and subsettings. Similar types of hydrothermal deposits may occur in different tectonic settings as a consequence of convergence of physical and chemical processes of concentration. Local tectonic sub-settings with conditions conducive to hydrothermal mineralization at slow-spreading centers (half rate ≤ 2cm y -1; length c. 28,000 km), characterized by an estimated average convective heat transfer of 15.1·10 8 cal. cm -2, deep-level ( > 3 km), relative narrow (< 5 km wide at base) magma chambers, and high topographic relief (1-5 km) are: (1) basins along linear sections of the axial zone of volcanic extrusion near transform faults at an early stage of opening, represented by a large stratiform sulfide deposit (estimated 32.5·10 6 metric tons) of the Atlantis II Deep of the Red Sea; (2) the wall along linear sections of the rift valley in the marginal zone of active extension at an advanced stage of opening, represented by encrustations and layered deposits of manganese and iron oxides, hydroxides and silicates inferred to be underlain by stockwork sulfides at the TAG Hydrothermal Field at latitude 26°C on the Mid-Atlantic Ridge; (3) transform faults, especially those with large ridge-ridge offset ( > 30 km), at an advanced stage of opening, represented by stockwork sulfides exposed in the walls of equatorial fracture zones of the Atlantic Ocean and Indian Ocean; (4) the axial zone of volcanic extrusion at an advanced stage of opening. Local tectonic sub-settings with conditions conducive to hydrothermal mineralization at intermediate- to fast-spreading centers (half rate > 2cm y -1; length c. 22,000 km) characterized by an estimated average convective heat transfer of 11.5·10 8 cal. cm -2, relatively wide (up to 20 km at base), shallow-level (c. 1-3 km) magma chambers, and low topographic relief (< 1 km), are: (1) basins along linear sections of the axial zone of volcanic extrusion at an early stage of opening, represented by massive sulfide deposits of the Guaymas Basin of the Gulf of California; (2) the axial zone of volcanic extrusion at an advanced stage of opening, represented by individually small (c. 1·10 3 metric tons), massive sulfide mounds surmounted by chimneys of the East Pacific Rise at latitude 21°N; (3) the marginal zone of active extension at an advanced stage of opening represented by a large, massive sulfide deposit (preliminary tentative estimate c.10·10 6 metric tons) at a double-rifted section of the Galapagos Spreading Center; (4) transform faults, especially those with large ridge-ridge offset ( > 50 km) represented by manganese encrustations in a transform fault at the Galapagos Spreading Center; (5) volcanic seamounts related to persistent hot spots at spreading centers, represented by oxide and sulfide deposits on seamounts off the axis of the East Pacific Rise; (6) portions of spreading centers with anomalous configurations such as multiple, bent or extended rifts, represented by massive sulfide deposits at a double-rifted section of the Galapagos Spreading Center, suggesting the operation of a thermal-structural feedback mechanism indicative of the presence of hydrothermal mineralization; (7) discrete spreading centers in back-arc basins represented by hydrothermal deposits at sites in marginal seas of the western Pacific. Ore-forming processes appear to be least efficient in the axial zone of volcanic extrusion of oceanic ridges at an advanced stage of opening irrespective of spreading rate, where tight hydrothermal systems dissipate a major portion of contained metals by precipitation and dispersion in particulate form from "black smokers" that discharge into the water column. Ore-forming processes appear to be most efficient at sites in basins at linear sections of the axial zone of volcanic extrusion near transform faults during an early stage of opening, and at marginal zones of active extension along linear sections of a spreading center during an advanced stage of opening, irrespective of spreading rate, where both tight and leaky hydrothermal systems may conserve their contained metals to concentrate large sulfide deposits. Resemblances in mineralization between stockwork sulfides at seafloor spreading centers and porphyry copper-type deposits in volcanogenic rocks on land suggest the possibility for the occurrence of large tonnage, low-grade porphyry copper-like deposits concentrated by leaky hydrothermal systems at spreading centers. Systematic application of composite exploration procedures is leading to the discovery of numerous additional deposits. It is inferred from the limited data base available that the occurrence of hydrothermal mineral deposits is more frequent at intermediate-to-fast-than at slow-spreading centers, but the potential for the accumulation of large hydrothermal mineral deposits is greater at slow-spreading centers. Current knowledge of the distribution of hydrothermal mineral deposits at seafloor spreading centers is limited to about 55 sites at this early stage of exploration. Estimates of the distribution of either fields of hydrothermal mineral deposits or high-intensity ore-forming hydrothermal systems at seafloor spreading centers, deduced from various considerations, range from one such occurrence between 15 and 265 km along slow-spreading centers, and 1 and 100 km along intermediate- to fast-spreading centers. However, the distribution of sizable deposits will remain sporadic owing to the special structural and thermal conditions necessary to sustain and to retain high-intensity ore-forming hydrothermal systems.
Gaunt, H. Elizabeth; Bernard, Benjamin; Hidalgo, Silvana; Proano, Antonio; Wright, Heather M.; Mothes, Patricia; Criollo, Evelyn; Kueppers, Ulrich
2016-01-01
Forecasting future activity and performing hazard assessments during the reactivation of volcanoes remain great challenges for the volcanological community. On August 14, 2015 Cotopaxi volcano erupted for the first time in 73 years after approximately four months of precursory activity, which included an increase in seismicity, gas emissions, and minor ground deformation. Here we discuss the use of near real-time petrological monitoring of ash samples as a complementary aid to geophysical monitoring, in order to infer eruption dynamics and evaluate possible future eruptive activity at Cotopaxi. Twenty ash samples were collected between August 14 and November 23, 2015 from a monitoring site on the west flank of the volcano. These samples contain a range of grain types that we classified as: hydrothermal/altered, lithic, juvenile, and free crystals. The relative proportions of theses grains evolved as the eruption progressed, with increasing amounts of juvenile material and a decrease in hydrothermally altered material. In samples from the initial explosion, juvenile grains are glassy, microlite-poor and contain hydrothermal minerals (opal and alunite). The rising magma came in contact with the hydrothermal system under confinement, causing hydro-magmatic explosions that cleared the upper part of the plumbing system. Subsequently, the magmatic column produced a thermal aureole in the conduit and dried out the hydrothermal system, allowing for dry eruptions. Magma ascent rates were low enough to allow for efficient outgassing and microlite growth. Constant supply of magma from below caused quasi-continuous disruption of the uppermost magma volume through a combination of shear-deformation and gas expansion. The combination of increasing crystallinity of juvenile grains, and high measured SO2 flux indicate decreasing integrated magma ascent rates and clearing of the hydrothermal system along transport pathways in a system open to gas loss. The near real-time monitoring of ash samples combined with traditional geophysical monitoring techniques during the reawakening of Cotopaxi allowed us to gain a much clearer understanding of events than when using traditional geophysical monitoring alone.
NASA Astrophysics Data System (ADS)
Brazelton, W. J.; Mehta, M. P.; Baross, J. A.
2010-04-01
DNA sequencing and metabolic activity measurements show that lateral gene transfer promotes phenotypic diversity in single-species archaeal biofilms attached to hydrothermal chimneys. This system may be a useful model for early cellular evolution.
The hydrothermal system associated with the Kilauea East Rift Zone, Hawaii
DOE Office of Scientific and Technical Information (OSTI.GOV)
Thomas, D.M.; Conrad, M.E.
1997-12-31
During the last twenty years drilling and fluid production on the Kilauea East Rift Zone (KERZ) has shown that an active hydrothermal system is associated with much of the rift. Well logging and fluid geochemistry indicate that reservoir temperatures exceed 360 C but are highly variable. Although neither well testing nor pressure decline data have clearly demonstrated the lateral limits of the reservoir, divergent fluid compositions over short distances suggest that the larger hydrothermal system is strongly compartmentalized across the rift zone. The chemical compositions of production fluids indicate that recharge is derived from ocean water and meteoric recharge andmore » isotopic data suggest that the latter may be derived from subsurface inflow from the flanks of Mauna Loa.« less
Caldera unrest driven by CO2-induced drying of the deep hydrothermal system.
Moretti, R; Troise, C; Sarno, F; De Natale, G
2018-05-29
Interpreting volcanic unrest is a highly challenging and non-unique problem at calderas, since large hydrothermal systems may either hide or amplify the dynamics of buried magma(s). Here we use the exceptional ground displacement and geochemical datasets from the actively degassing Campi Flegrei caldera (Southern Italy) to show that ambiguities disappear when the thermal evolution of the deep hydrothermal system is accurately tracked. By using temperatures from the CO 2 -CH 4 exchange of 13 C and thermodynamic analysis of gas ascending in the crust, we demonstrate that after the last 1982-84 crisis the deep hydrothermal system evolved through supercritical conditions under the continuous isenthalpic inflow of hot CO 2 -rich gases released from the deep (~8 km) magma reservoir of regional size. This resulted in the drying of the base of the hot hydrothermal system, no more buffered along the liquid-vapour equilibrium, and excludes any shallow arrival of new magma, whose abundant steam degassing due to decompression would have restored liquid-vapour equilibrium. The consequent CO 2 -infiltration and progressive heating of the surrounding deforming rock volume cause the build-up of pore pressure in aquifers, and generate the striking temporal symmetry that characterizes the ongoing uplift and the post-1984 subsidence, both originated by the same but reversed deformation mechanism.
NASA Astrophysics Data System (ADS)
Thal, J.; Bach, W.; Tivey, M.; Yoerger, D.
2013-12-01
Bathymetric data from cruises in 2002, 2006, and 2011 were combined and compared to determine the evolution of volcanic activity, seafloor structures, erosional features and to identify and document the distribution of hydrothermal vents on North Su volcano, SuSu Knolls, eastern Manus Basin (Papua New Guinea). Geologic mapping based on ROV observations from 2006 (WHOI Jason-2) and 2011 (MARUM Quest-4000) combined with repeated bathymetric surveys from 2002 and 2011 are used to identify morphologic features on the slopes of North Su and to track temporal changes. ROV MARUM Quest-4000 bathymetry was used to develop a 10 m grid of the top of North Su to precisely depict recent changes. In 2006, the south slope of North Su was steeply sloped and featured numerous white smoker vents discharging acid sulfate waters. These vents were covered by several tens of meters of sand- to gravel-sized volcanic material in 2011. The growth of this new cone changed the bathymetry of the south flank of North Su up to ~50 m and emplaced ~0.014 km3 of clastic volcanic material. This material is primarily comprised of fractured altered dacite and massive fresh dacite as well as crystals of opx, cpx, olivine and plagioclase. There is no evidence for pyroclastic fragmentation, so we hypothesize that the fragmentation is likely related to hydrothermal explosions. Hydrothermal activity varies over a short (~50 m) lateral distance from 'flashing' black smokers to acidic white smoker vents. Within 2 weeks of observation time in 2011, the white smoker vents varied markedly in activity suggesting a highly episodic hydrothermal system. Based on ROV video recordings, we identified steeply sloping (up to 30°) slopes exposing pillars and walls of hydrothermal cemented volcaniclastic material representing former fluid upflow zones. These features show that hydrothermal activity has increased slope stability as hydrothermal cementation has prevented slope collapse. Additionally, in some places, hydrothermal crusts cover loose volcaniclastic material on the steep slopes and stabilize them.
Geologic evolution of the Lost City Hydrothermal Field
NASA Astrophysics Data System (ADS)
Denny, Alden R.; Kelley, Deborah S.; Früh-Green, Gretchen L.
2016-02-01
The Lost City Hydrothermal Field (LCHF) is a novel serpentinite-hosted vent field located on the Atlantis Massif southern wall. Results of 2 m resolution bathymetry, side scan, and video and still imagery, integrated with direct submersible observations provide the first high-resolution geologic map of the LCHF. These data form the foundation for an evolutionary model for the vent system over the past >120,000 years. The field is located on a down-dropped bench 70 m below the summit of the massif. The bench is capped by breccia and pelagic carbonate deposits underlain by variably deformed and altered serpentinite and gabbroic rocks. Hydrothermal activity is focused at the 60 m tall, 100 m across, massive carbonate edifice "Poseidon," which is venting 91°C fluid. Hydrothermal activity declines south and west of the Poseidon complex and dies off completely at distances greater than 200 m. East of Poseidon, the most recent stage of hydrothermal flow is characterized by egress of diffuse fluids from narrow fissures within a low-angle, anastomosing mylonite zone. South of the area of current hydrothermal activity, there is evidence of two discrete previously unrecognized relict fields. Active venting sites defined by carbonate-filled fissures that cut the carbonate cap rock at the summit of the massif mark the present-day northernmost extent of venting. These spatial relationships reflect multiple stages of field development, the northward migration of venting over time, and the likely development of a nascent field at the massif summit.
Learning about hydrothermal volcanic activity by modeling induced geophysical changes
NASA Astrophysics Data System (ADS)
Currenti, Gilda M.; Napoli, Rosalba
2017-05-01
Motivated by ongoing efforts to understand the nature and the energy potential of geothermal resources, we devise a coupled numerical model (hydrological, thermal, mechanical), which may help in the characterization and monitoring of hydrothermal systems through computational experiments. Hydrothermal areas in volcanic regions arise from a unique combination of geological and hydrological features which regulate the movement of fluids in the vicinity of magmatic sources capable of generating large quantities of steam and hot water. Numerical simulations help in understanding and characterizing rock-fluid interaction processes and the geophysical observations associated with them. Our aim is the quantification of the response of different geophysical observables (i.e. deformation, gravity and magnetic field) to hydrothermal activity on the basis of a sound geological framework (e.g. distribution and pathways of the flows, the presence of fractured zones, caprock). A detailed comprehension and quantification of the evolution and dynamics of the geothermal systems and the definition of their internal state through a geophysical modeling approach are essential to identify the key parameters for which the geothermal system may fulfill the requirements to be exploited as a source of energy. For the sake of illustration only, the numerical computations are focused on a conceptual model of the hydrothermal system of Vulcano Island by simulating a generic 1-year unrest and estimating different geophysical changes. We solved (i) the mass and energy balance equations of flow in porous media for temperature, pressure and density changes, (ii) the elastostatic equation for the deformation field and (iii) the Poisson’s equations for gravity and magnetic potential fields. Under the model assumptions, a generic unrest of 1-year engenders on the ground surface low amplitude changes in the investigated geophysical observables, that are, however, above the accuracies of the modern state-of-the-art instruments. Devising multidisciplinary and easy-to-use computational experiments enable us to learn how the hydrothermal system responds to un unrest and which fingerprints it may leave in the geophysical signals.
Geophysical image of the hydrothermal system of Merapi volcano
NASA Astrophysics Data System (ADS)
Byrdina, S.; Friedel, S.; Vandemeulebrouck, J.; Budi-Santoso, A.; Suhari; Suryanto, W.; Rizal, M. H.; Winata, E.; Kusdaryanto
2017-01-01
We present an image of the hydrothermal system of Merapi volcano based on results from electrical resistivity tomography (ERT), self-potential, and CO2 flux mappings. The ERT models identify two distinct low-resistivity bodies interpreted as two parts of a probably interconnected hydrothermal system: at the base of the south flank and in the summit area. In the summit area, a sharp resistivity contrast at ancient crater rim Pasar-Bubar separates a conductive hydrothermal system (20-50 Ω m) from the resistive andesite lava flows and pyroclastic deposits (2000-50,000 Ω m). The existence of preferential fluid circulation along this ancient crater rim is also evidenced by self-potential data. The significative diffuse CO2 degassing (with a median value of 400 g m-2 d-1) is observed in a narrow vicinity of the active crater rim and close to the ancient rim of Pasar-Bubar. The total CO2 degassing across the accessible summital area with a surface of 1.4 ṡ 105 m2 is around 20 t d-1. Before the 2010 eruption, Toutain et al. (2009) estimated a higher value of the total diffuse degassing from the summit area (about 200-230 t d-1). This drop in the diffuse degassing from the summit area can be related to the decrease in the magmatic activity, to the change of the summit morphology, to the approximations used by Toutain et al. (2009), or, more likely, to a combination of these factors. On the south flank of Merapi, the resistivity model shows spectacular stratification. While surficial recent andesite lava flows are characterized by resistivity exceeding 100,000 Ω m, resistivity as low as 10 Ω m has been encountered at a depth of 200 m at the base of the south flank and was interpreted as a presence of the hydrothermal system. No evidence of the hydrothermal system is found on the basis of the north flank at the same depth. This asymmetry might be caused by the asymmetry of the heat supply source of Merapi whose activity is moving south or/and to the asymmetry in topography caused by the presence of Merbabu volcano in the north. On the basis of our results we suggest that stratified pyroclastic deposits on the south flank of Merapi screen and separate the flow of hydrothermal fluids with the gaseous part rising through the crater rims, while the liquid part is flowing downwards to the base of the edifice.
NASA Astrophysics Data System (ADS)
Heap, Michael J.; Kennedy, Ben M.; Farquharson, Jamie I.; Ashworth, James; Mayer, Klaus; Letham-Brake, Mark; Reuschlé, Thierry; Gilg, H. Albert; Scheu, Bettina; Lavallée, Yan; Siratovich, Paul; Cole, Jim; Jolly, Arthur D.; Baud, Patrick; Dingwell, Donald B.
2017-02-01
Our multidisciplinary study aims to better understand the permeability of active volcanic hydrothermal systems, a vital prerequisite for modelling and understanding their behaviour and evolution. Whakaari/White Island volcano (an active stratovolcano at the north-eastern end of the Taupo Volcanic Zone of New Zealand) hosts a highly reactive hydrothermal system and represents an ideal natural laboratory to undertake such a study. We first gained an appreciation of the different lithologies at Whakaari and (where possible) their lateral and vertical extent through reconnaissance by land, sea, and air. The main crater, filled with tephra deposits, is shielded by a volcanic amphitheatre comprising interbedded lavas, lava breccias, and tuffs. We deployed field techniques to measure the permeability and density/porosity of (1) > 100 hand-sized sample blocks and (2) layered unlithified deposits in eight purpose-dug trenches. Our field measurements were then groundtruthed using traditional laboratory techniques on almost 150 samples. Our measurements highlight that the porosity of the materials at Whakaari varies from ∼ 0.01 to ∼ 0.7 and permeability varies by eight orders of magnitude (from ∼ 10-19 to ∼ 10-11 m2). The wide range in physical and hydraulic properties is the result of the numerous lithologies and their varied microstructures and alteration intensities, as exposed by a combination of macroscopic and microscopic (scanning electron microscopy) observations, quantitative mineralogical studies (X-ray powder diffraction), and mercury porosimetry. An understanding of the spatial distribution of lithology and alteration style/intensity is therefore important to decipher fluid flow within the Whakaari volcanic hydrothermal system. We align our field observations and porosity/permeability measurements to construct a schematic cross section of Whakaari that highlights the salient findings of our study. Taken together, the alteration typical of a volcanic hydrothermal system can result in increases (due to alteration-induced dissolution and fracturing) and decreases (due to hydrothermal precipitation) to permeability. Importantly, a decrease in permeability-be it due to fracture sealing in lava, pore-filling alunite precipitation in tuff, near-vent cementation by sulphur, and/or well-sorted layers of fine ash-can result in pore pressure augmentation. An increase in pore pressure could result in ground deformation, seismicity, jeopardise the stability of the volcanic slopes, and/or drive the wide variety of eruptions observed at Whakaari. Our systematic study offers the most complete porosity-permeability dataset for a volcanic hydrothermal system to date. These new data will inform and support modelling, unrest monitoring, and eruption characterisation at Whakaari and other hydrothermally modified volcanic systems worldwide.
NASA Astrophysics Data System (ADS)
Fontaine, F.; Peltier, A.; Kowalski, P.; Di Muro, A.; Villeneuve, N.; Ferrazzini, V.; Staudacher, T.
2017-12-01
Piton de la Fournaise, located on La Réunion Island in the South East Indian Ocean, is one of the most active basaltic volcanoes (hotspot) of the world with a mean eruption frequency <6 months over the last 20 years. The central dome of the shield is thought to host an active hydrothermal system evidenced by self-potential techniques early in the 90's and mining heat from a magmatic source located about 2-2.5 km below the summit. Surface manifestations of this activity such as fumeroles or hot grounds have however never been observed before 2007 when deep magma withdrawal from the magmatic horizon during the "eruption of the century" (>100×106 m3) on the island, led to the formation of a 400-m-deep, 1000-m-large, funnel-shaped summit caldera. Since then, the floor and inner flanks of this summit depression hosting hot grounds and active fumaroles, are monitored using an infra-red camera device permanently installed on the caldera rim.This thermal dataset constitutes the first opportunity to understand the structure and dynamics of the hydrothermal system and its ability to relay deep-seated heat and mass perturbations. We present in this communication an overview of this thermal datasets focusing on ground/fumaroles temperature evolution during volcanic crisis and rest periods and analyzing correlations with the other permanently acquired data such as the temporal evolution of gas geochemistry (CO2, SO2, H2S), ground deformation and micro-seismic activity. We finally propose a conceptual model of fluid flow architecture within the edifice which paves the way for future quantitative models of hydrothermal heat and mass transfers.
Izawa, M R M; Banerjee, Neil R; Osinski, G R; Flemming, R L; Parnell, J; Cockell, C S
2011-01-01
Meteorite impacts are among the very few processes common to all planetary bodies with solid surfaces. Among the effects of impact on water-bearing targets is the formation of post-impact hydrothermal systems and associated mineral deposits. The Haughton impact structure (Devon Island, Nunavut, Canada, 75.2 °N, 89.5 °W) hosts a variety of hydrothermal mineral deposits that preserve assemblages of primary hydrothermal minerals commonly associated with secondary oxidative/hydrous weathering products. Hydrothermal mineral deposits at Haughton include intra-breccia calcite-marcasite vugs, small intra-breccia calcite or quartz vugs, intra-breccia gypsum megacryst vugs, hydrothermal pipe structures and associated surface "gossans," banded Fe-oxyhydroxide deposits, and calcite and quartz veins and coatings in shattered target rocks. Of particular importance are sulfide-rich deposits and their associated assemblage of weathering products. Hydrothermal mineral assemblages were characterized structurally, texturally, and geochemically with X-ray diffraction, micro X-ray diffraction, optical and electron microscopy, and inductively coupled plasma atomic emission spectroscopy. Primary sulfides (marcasite and pyrite) are commonly associated with alteration minerals, including jarosite (K,Na,H(3)O)Fe(3)(SO(4))(2)(OH)(6), rozenite FeSO(4)·4(H(2)O), copiapite (Fe,Mg)Fe(4)(SO(4))(6)(OH)(2)·20(H(2)O), fibroferrite Fe(SO(4))(OH)·5(H(2)O), melanterite FeSO(4)·7(H(2)O), szomolnokite FeSO(4)·H(2)O, goethite α-FeO(OH), lepidocrocite γ-FeO(OH) and ferrihydrite Fe(2)O(3)·0.5(H(2)O). These alteration assemblages are consistent with geochemical conditions that were locally very different from the predominantly circumneutral, carbonate-buffered environment at Haughton. Mineral assemblages associated with primary hydrothermal activity, and the weathering products of such deposits, provide constraints on possible microbial activity in the post-impact environment. The initial period of active hydrothermal circulation produced primary mineral assemblages, including Fe sulfides, and was succeeded by a period dominated by oxidation and low-temperature hydration of primary minerals by surface waters. Active hydrothermal circulation can enable the rapid delivery of nutrients to microbes. Nutrient availability following the cessation of hydrothermal circulation is likely more restricted; therefore, the biological importance of chemical energy from hydrothermal mineral deposits increases with time. Weathering of primary hydrothermal deposits and dissolution and reprecipitation of mobile weathering products also create many potential habitats for endolithic microbes. They also provide a mechanism that may preserve biological materials, potentially over geological timescales. © Mary Ann Liebert, Inc.
Hydrothermal monitoring in a quiescent volcanic arc: Cascade Range, northwestern United States
Ingebritsen, S.E.; Randolph-Flagg, N. G.; Gelwick, K.D.; Lundstrom, E.A.; Crankshaw, I.M.; Murveit, A.M.; Schmidt, M.E.; Bergfeld, D.; Spicer, K.R.; Tucker, D.S.; Mariner, R.H.; Evans, William C.
2014-01-01
Ongoing (1996–present) volcanic unrest near South Sister, Oregon, is accompanied by a striking set of hydrothermal anomalies, including elevated temperatures, elevated major ion concentrations, and 3He/4He ratios as large as 8.6 RA in slightly thermal springs. These observations prompted the US Geological Survey to begin a systematic hydrothermal-monitoring effort encompassing 25 sites and 10 of the highest-risk volcanoes in the Cascade volcanic arc, from Mount Baker near the Canadian border to Lassen Peak in northern California. A concerted effort was made to develop hourly, multiyear records of temperature and/or hydrothermal solute flux, suitable for retrospective comparison with other continuous geophysical monitoring data. Targets included summit fumarole groups and springs/streams that show clear evidence of magmatic influence in the form of high 3He/4He ratios and/or anomalous fluxes of magmatic CO2 or heat. As of 2009–2012, summit fumarole temperatures in the Cascade Range were generally near or below the local pure water boiling point; the maximum observed superheat was 3 during periods of hourly record. Hydrothermal responses to these small seismic stimuli were generally undetectable or ambiguous. Evaluation of multiyear to multidecadal trends indicates that whereas the hydrothermal system at Mount St. Helens is still fast-evolving in response to the 1980–present eruptive cycle, there is no clear evidence of ongoing long-term trends in hydrothermal activity at other Cascade Range volcanoes that have been active or restless during the past century (Baker, South Sister, and Lassen). Experience gained during the Cascade Range hydrothermal-monitoring experiment informs ongoing efforts to capture entire unrest cycles at more active but generally less accessible volcanoes such as those in the Aleutian arc.
NASA Astrophysics Data System (ADS)
Kalacheva, E.; Taran, Y.; Voloshina, E.; Kotenko, T.; Tarasov, K.
2017-12-01
More than 30 active volcanoes with historical eruptions are known on 20 main islands composing the Kuril Arc. Eight islands - Paramushir, Shiashkotan, Rasshua, Ushishir, Ketoy, Urup, Iturup and Kunashir - are characterized by hydrothermal activity, complementary to the fumarole activity in the craters and volcano slopes. At Paramushir, Shiashkotan, Iturup and Kunashir most of thermal manifestations are acidic to ultra-acidic hot springs associated with hydrothermal aquifers inside volcano edifices. The most powerful of them is the ultra-acid hydrothermal system of Ebeko volcano (Paramushir island) with more than 80 t/day of the chloride output and pH of springs of 1.5. At the summit part of the Ebeko volcano there are 12 thermal fields with the total thermal area exceeding 1 km2. The measured temperatures of fumaroles are from 98º C to 500ºC. Another type of hydrothermal activity are the wide spread coastal hot and neutral springs situated as a rule within the tide zone. Four groups of this type of thermal manifestation were found on the western shore of Shiashkotan island. It have Na-Ca-Cl-SO4 composition with temperatures 50-80°C and TDS 7-8 g/L. Coastal neutral springs were found also on Russhua, Uturup and Kunashir islands. Ushishir volcano-hydrothermal system in the middle of the arc is formed by the absorption of magmatic gases by seawater. In the crater of the Pallas cone (Ketoy island) there is a small Glazok lake with acid SO4 water and pH=2.4, TDS=2g/L, T=12oC. Ketoy volcano on the same island hosts a high temperature hydrothermal system with unusual boiling Ca-Na-SO4 neutral springs and steam vents. Mendeleev and Golovnin volcanoes on Kunashir Island are the southernmost of the Kuril arc. Mendeleev edifice is a centre of a large thermal area with many manifestations of different types including steam vents, acid springs and neutral coastal springs. In a 4.2x4 km wide caldera of Golovnin volcano there are two lakes with acid Cl-SO4 water and numerous thermal vents around and on the bottom of the lakes and outside the caldera, along the coast of the Sea of Okhotsk. In this report we present new data on the chemical (major and trace elements) and isotopic (H, O) composition of thermal fluids and gases from thermal manifestations obtained during the field campaign in 2015-2017. This work is supported by the RSF grant #15-17-20011.
Dekov, V.M.; Cuadros, J.; Shanks, Wayne C.; Koski, R.A.
2008-01-01
Talc, kerolite-smectite, smectite, chlorite-smectite and chlorite samples from sediments, chimneys and massive sulfides from six seafloor hydrothermal areas have been analyzed for mineralogy, chemistry and oxygen isotopes. Samples are from both peridotite- and basalt-hosted hydrothermal systems, and basaltic systems include sediment-free and sediment-covered sites. Mg-phyllosilicates at seafloor hydrothermal sites have previously been described as talc, stevensite or saponite. In contrast, new data show tri-octahedral Mg-phyllosilicates ranging from pure talc and Fe-rich talc, through kerolite-rich kerolite-smectite to smectite-rich kerolite-smectite and tri-octahedral smectite. The most common occurrence is mixed-layer kerolite-smectite, which shows an almost complete interstratification series with 5 to 85% smectitic layers. The smectite interstratified with kerolite is mostly tri-octahedral. The degree of crystal perfection of the clay sequence decreases generally from talc to kerolite-smectite with lower crystalline perfection as the proportion of smectite layers in kerolite-smectite increases. Our studies do not support any dependence of the precipitated minerals on the type/subtype of hydrothermal system. Oxygen isotope geothermometry demonstrates that talc and kerolite-smectite precipitated in chimneys, massive sulfide mounds, at the sediment surface and in open cracks in the sediment near seafloor are high-temperature (> 250????C) phases that are most probably the result of focused fluid discharge. The other end-member of this tri-octahedral Mg-phyllosilicate sequence, smectite, is a moderate-temperature (200-250????C) phase forming deep within the sediment (??? 0.8??m). Chlorite and chlorite-smectite, which constitute the alteration sediment matrix around the hydrothermal mounds, are lower-temperature (150-200????C) phases produced by diffuse fluid discharge through the sediment around the hydrothermal conduits. In addition to temperature, other two controls on the precipitation of this sequence are the silica activity and Mg/Al ratio (i.e. the degree of mixing of seawater with hydrothermal fluid). Higher silica activity favors the formation of talc relative to tri-octahedral smectite. Vent structures and sedimentary cover preclude complete mixing of hydrothermal fluid and ambient seawater, resulting in lower Mg/Al ratios in the interior parts of the chimneys and deeper in the sediment which leads to the precipitation of phyllosilicates with lower Mg contents. Talc and kerolite-smectite have very low trace- and rare earth element contents. Some exhibit a negative or flat Eu anomaly, which suggests Eu depletion in the original hydrothermal fluid. Such Eu depletion could be caused by precipitation of anhydrite or barite (sinks for Eu2+) deeper in the system. REE abundances and distribution patterns indicate that chlorite and chlorite-smectite are hydrothermal alteration products of the background turbiditic sediment. ?? 2007 Elsevier B.V. All rights reserved.
Electrochemistry of Prebiotic Early Earth Hydrothermal Chimney Systems
NASA Astrophysics Data System (ADS)
Hermis, N.; Barge, L. M.; Chin, K. B.; LeBlanc, G.; Cameron, R.
2017-12-01
Hydrothermal chimneys are self-organizing chemical garden precipitates generated from geochemical disequilibria within sea-vent environments, and have been proposed as a possible setting for the emergence of life because they contain mineral catalysts and transect ambient pH / Eh / chemical gradients [1]. We simulated the growth of hydrothermal chimneys in early Earth vent systems by using different hydrothermal simulants such as sodium sulfide (optionally doped with organic molecules) which were injected into an early Earth ocean simulant containing dissolved ferrous iron, nickel, and bicarbonate [2]. Chimneys on the early Earth would have constituted flow-through reactors, likely containing Fe/Ni-sulfide catalysts that could have driven proto-metabolic electrochemical reactions. The electrochemical activity of the chimney system was characterized non-invasively by placing electrodes at different locations across the chimney wall and in the ocean to analyze the bulk properties of surface charge potential in the chimney / ocean / hydrothermal fluid system. We performed in-situ characterization of the chimney using electrochemical impedance spectroscopy (EIS) which allowed us to observe the changes in physio-chemical behavior of the system through electrical spectra of capacitance and impedance over a wide range of frequencies during the metal sulfide chimney growth. The electrochemical properties of hydrothermal chimneys in natural systems persist due to the disequilibria maintained between the ocean and hydrothermal fluid. When the injection in our experiment (analogous to fluid flow in a vent) stopped, we observed a corresponding decline in open circuit voltage across the chimney wall, though the impedance of the precipitate remained lor. Further work is needed to characterize the electrochemistry of simulated chimney systems by controlling response factors such as electrode geometry and environmental conditions, in order to simulate electrochemical reactions that may have occurred in similar systems on the early Earth. [1] Russell, MJ et al. 2014. Astrobiology,14, 4, 308-343. [2] Barge, LM et al. (2015) Journal of Visualized Experiments, 105, DOI: 10.3791/53015.
Microbiology of ancient and modern hydrothermal systems.
Reysenbach, A L; Cady, S L
2001-02-01
Hydrothermal systems have prevailed throughout geological history on earth, and ancient ARCHAEAN hydrothermal deposits could provide clues to understanding earth's earliest biosphere. Modern hydrothermal systems support a plethora of microorganisms and macroorganisms, and provide good comparisons for paleontological interpretation of ancient hydrothermal systems. However, all of the microfossils associated with ancient hydrothermal deposits reported to date are filamentous, and limited STABLE ISOTOPE analysis suggests that these microfossils were probably autotrophs. Therefore, the morphology and mode of carbon metabolism are attributes of microorganisms from modern hydrothermal systems that provide valuable information for interpreting the geological record using morphological and isotopic signatures.
A Blind Hydrothermal System in an Ocean Island Environment: Humu'ula Saddle, Hawaii Island
NASA Astrophysics Data System (ADS)
Thomas, D. M.; Wallin, E.; Lautze, N. C.; Lienert, B. R.; Pierce, H. A.
2014-12-01
A recently drilled groundwater investigation borehole, drilled to a depth of 1760 m in the Humu'ula Saddle of Hawaii Island, encountered an unexpectedly high temperature gradient of more than 160 ̊C/km. Although prior MT surveys across the region identified conductive formations of modest extent in the region, there were few surface manifestations of geologic structures likely to host a geothermal system and no evidence of an active, extensive hydrothermal system. Cores recovered from the borehole showed the presence of intrusive formations and moderate hydrothermal alteration at depth with progressive infilling of fractures and vesicles with depth and temperature. Independent modeling of gravity data (Flinders et al., 2013) suggests the presence of a broad intrusive complex within the region that is consistent with the borehole's confirmation of a high-elevation (~1400 m amsl) regional water table. A subsequent MT survey covering much of the western Saddle region has confirmed the presence of highly conductive conditions, consistent with thermal activity, to depths of 4 km and greater. Light stable isotope data for the borehole fluids indicate that the regional water table is derived from recharge from the upper elevations of Mauna Kea; major element chemistry indicates that formation temperatures exceed 200 ̊C. A conceptual model of the hydrothermal system, along with isotopic and fluid chemistry of the thermal fluids will be presented.
NASA Astrophysics Data System (ADS)
Moretti, Roberto; De Natale, Giuseppe; Troise, Claudia
2017-03-01
Volcanic unrest at calderas involves complex interaction between magma, hydrothermal fluids, and crustal stress and strain. Campi Flegrei caldera (CFc), located in the Naples (Italy) area and characterized by the highest volcanic risk on Earth for the extreme urbanization, undergoes unrest phenomena involving several meters of uplift and intense shallow microseismicity since several decades. Despite unrest episodes display in the last decade only moderate ground deformation and seismicity, current interpretations of geochemical data point to a highly pressurized hydrothermal system. We show that at CFc, the usual assumption of vapor-liquid coexistence in the fumarole plumes leads to largely overestimated hydrothermal pressures and, accordingly, interpretations of elevated unrest. By relaxing unconstrained geochemical assumptions, we infer an alternative model yielding better agreement between geophysical and geochemical observations. The model reconciles discrepancies between what observed (1) for two decades since the 1982-1984 large unrest, when shallow magma was supplying heat and fluids to the hydrothermal system, and (2) in the last decade. Compared to the 1980's unrest, the post-2005 phenomena are characterized by much lower aquifers overpressure and magmatic involvement, as indicated by geophysical data and despite large changes in geochemical indicators. Our interpretation points out a model in which shallow sills, intruded during 1969-1984, have completely cooled, so that fumarole emissions are affected now by deeper, CO2-richer, magmatic gases producing the modest heating and overpressure of the hydrothermal system. Our results have important implications on the short-term eruption hazard assessment and on the best strategies for monitoring and interpreting geochemical data.
Manganese Oxidizing Bacteria in Guaymas Basin Hydrothermal Fluids, Sediments, and Plumes
NASA Astrophysics Data System (ADS)
Dick, G. J.; Tebo, B. M.
2002-12-01
The active seafloor hydrothermal system at Guaymas Basin in the Gulf of California is unique in that spreading centers are covered with thick sediments, and hydrothermal fluids are injected into a semi-enclosed basin. This hydrothermal activity is the source of a large input of dissolved manganese [Mn(II)] into Guaymas Basin, and the presence of a large standing stock of particulate manganese in this basin has been taken as evidence for a short residence time of dissolved Mn(II) with respect to oxidation, suggestive of bacterial catalysis. During a recent Atlantis/Alvin expedition (R/V Atlantis Cruise #7, Leg 11, Jim Cowen Chief Scientist), large amounts of particulate manganese oxides were again observed in Guaymas Basin hydrothermal plumes. The goal of the work presented here was to identify bacteria involved in the oxidation of Mn(II) in Guaymas Basin, and to determine what molecular mechanisms drive this process. Culture-based methods were employed to isolate Mn(II)-oxidizing bacteria from Guaymas Basin hydrothermal fluids, sediments, and plumes, and numerous Mn(II)-oxidizing bacteria were identified based on the formation of orange, brown, or black manganese oxides on bacterial colonies on agar plates. The Mn(II)-oxidizing bacteria were able to grow at temperatures from 12 to 50°C, and a selection of the isolates were chosen for phylogenetic (16S rRNA genes) and microscopic characterization. Endospore-forming Bacillus species accounted for many of the Mn(II)-oxidizing isolates obtained from both hydrothermal sediments and plumes, while members of the alpha- and gamma-proteobacteria were also found. Mn(II)-oxidizing enzymes from previously characterized Bacillus spores are known to be active at temperatures greater than 50°C. The presence of Mn(II)-oxidizing spores - some of which are capable of growing at elevated temperatures - in hydrothermal fluids and sediments at Guaymas Basin suggests that Mn(II) oxidation may be occurring immediately or very soon after hydrothermal fluids emerge from the seafloor.
ESR dating of submarine hydrothermal activities using barite in sulfide deposition
NASA Astrophysics Data System (ADS)
Toyoda, S.; Fujiwara, T.; Ishibashi, J.; Isono, Y.; Uchida, A.; Takamasa, A.; Nakai, S.
2012-12-01
The temporal change of submarine hydrothermal activities has been an important issue in the aspect of the evolution of hydrothermal systems which is related with ore formation (Urabe, 1995) and biological systems sustained by the chemical species arising from hydrothermal activities (Macdonald et al., 1980). Determining the ages of the hydrothermal deposit will provide essential information on such studies. Dating methods using disequilibrium between radioisotopes such as U-Th method (e.g. You and Bickle, 1998), 226}Ra-{210Pb and 228}Ra-{228Th method (e.g. Noguchi et al., 2011) have been applied to date submarine hydrothermal deposits. ESR (electron spin resonance) dating method is commonly applied to fossil teeth, shells, and quartz of Quaternay period where the natural accumulated dose is obtained from the intensities of the ESR signals which are created by natural radiation. The natural dose is divided by the dose rate to the mineral/sample to deduce the age. Okumura et al., (2010) made the first practical application of ESR (electron spin resonance) dating technique to a sample of submarine hydrothermal barite (BaSO4) to obtain preliminary ages, where Kasuya et al. (1991) first pointed out that barite can be used for ESR dating. Knowing that ESR dating of barite is promising, in this paper, we will present how we have investigated each factor that contributes ESR dating of barite in submarine hydrothermal sulfide deposition. (1) The best ESR condition for measuring the SO3- signal in barite is with the microwave power of 1mW and modulation amplitude of 0.1mT. (2) As results of heating experiments, the signal was found to be stable for the dating age range of several thousands. (3) 226Ra replacing Ba in barite is the source of the radiation. The amount of radioactive elements in sulfide mineral surrounding barite is negligible. (4) The external radiation from the sea water is negligible even in the submarine hydrothermal area where the radiation level is much higher than usual sea water. (5) The decay of 226Ra has to be considered. (6) Major terms of dose rate are the internal alpha dose rate and the external beta and gamma dose rates. (7) The alpha effectiveness, the ratio of forming the radical by internal alpha particles to by beta and gamma rays, was obtained to be 0.043±0.018. (8) The shape of the chimney sample should be considered for gamma ray dose. Examples of dating results for submarine hydrothermal deposits from South Mariana and Okinawa Trough will be presented.
Koski, Randolph A.; Lamons, Roberta C.; Dumoulin, Julie A.; Bouse, Robin M.
1993-01-01
The Island Mountain deposit, an anomalous massive sulfide in the Central belt of the Franciscan subduction complex, northern California Coast Ranges, formed during hydrothermal activity in a sediment-dominated paleo-sea-floor environment. Although the base of the massive sulfide is juxtaposed against a 500-m-wide melange band, its gradational upper contact within a coherent sequence of sandstone, siltstone, and mudstone indicates that hydrothermal activity was concurrent with turbidite deposition. Accumulations of sulfide breccia and clastic sulfide were produced by mass wasting of the sulfide mound prior to burial by turbidites. The bulk composition of sulfide samples (pyrrhotite rich; high Cu, As, and Au contents; radiogenic Pb isotope ratios) is consistent with a hydrothermal system dominated by fluid-sediment interaction. On the basis of a comparison with possible contemporary tectonic analogues at the southern Gorda Ridge and the Chile margin triple junction, we propose that massive sulfide mineralization in the Central belt of the Franciscan complex resulted from hydrothermal activity at a late Mesozoic sediment-covered ridge axis prior to collision with the North American plate.
NASA Astrophysics Data System (ADS)
Koski, Randolph A.; Lamons, Roberta C.; Dumoulin, Julie A.; Bouse, Robin M.
1993-02-01
The Island Mountain deposit, an anomalous massive sulfide in the Central belt of the Franciscan subduction complex, northern California Coast Ranges, formed during hydrothermal activity in a sediment-dominated paleo-sea-floor environment. Although the base of the massive sulfide is juxtaposed against a 500-m-wide melange band, its gradational upper contact within a coherent sequence of sandstone, siltstone, and mudstone indicates that hydrothermal activity was concurrent with turbidite deposition. Accumulations of sulfide breccia and clastic sulfide were produced by mass wasting of the sulfide mound prior to burial by turbidites. The bulk composition of sulfide samples (pyrrhotite rich; high Cu, As, and Au contents; radiogenic Pb isotope ratios) is consistent with a hydrothermal system dominated by fluid-sediment interaction. On the basis of a comparison with possible contemporary tectonic analogues at the southern Gorda Ridge and the Chile margin triple junction, we propose that massive sulfide mineralization in the Central belt of the Franciscan complex resulted from hydrothermal activity at a late Mesozoic sediment-covered ridge axis prior to collision with the North American plate.
NASA Astrophysics Data System (ADS)
Onyeali, M. M. C.; Joseph, E. P.; Frey, H. M.
2017-12-01
Dominica has an abundance of volcanic activity, with nine potentially active volcanoes, many of which have highly active volcanic-hydrothermal systems. The waters are predominantly acid-sulphate in character (SO4=100-4200 mg/L, pH≤4), and likely formed because of dilution of acidic gases in near surface oxygenated groundwater. The waters are of primarily meteoric origin, but are likely affected by evaporation effects at/near the surface, with δ18O ranging from -1.75 to 10.67‰, and δD from -6.1 to 14.5‰. With updated water chemistry and isotopic data from five hydrothermal areas (Boiling Lake, Valley of Desolation, Sulphur Springs, Wotten Waven, Cold Soufriere) for the period 2014 to 2017, we will re-evaluate the characteristics of these systems, which were last reported in 2011. We will present updated reservoir temperatures using a variety of geothermometers and provide insight into water-rock interactions taking place in the reservoirs. Recent changes in chemistry of the waters have indicated that while the origin of the hydrothermal systems are still dominantly meteoric (δ18O = -3 to 8‰ and δD = -5 to 18‰), surface evaporation effects and variable amounts of mixing with shallow ground waters play an important role. Fumaroles appear to reflect a deeper source contribution as compared to thermal waters with differences in acidity, temperature, TDS, δ18O, and δD observed. The general composition of the waters for most of the hydrothermal systems studied indicate no significant changes, with the exception of the Boiling Lake, which experienced a draining event in November 2016 which lasted for 6 weeks. Decreases in temperature, pH, Na, K, and Cl were seen post draining, while SO4 remained relatively low (66 ppm), but showed a small increase. The chemistry of the Boiling Lake appears to show significant changes in response to changes in the groundwater system. Changes in the groundwater system at the lake observed during the 2004/2005 draining, which lasted for 6 months, were attributed to strain release from a nearby regional seismic event. Based on the changes observed during the recent draining events, there are likely other factors affecting the ground water system at the Boiling Lake. Of particular note is the drastic change in SO4 concentrations in the Boiling Lake, which went from 1830 ppm in 2003 to <100 ppm presently.
NASA Astrophysics Data System (ADS)
Catchpole, Honza; Kouzmanov, Kalin; Bendezú, Aldo; Ovtcharova, Maria; Spikings, Richard; Stein, Holly; Fontboté, Lluís
2015-12-01
The Morococha district in central Peru is characterised by economically important Cordilleran polymetallic (Zn-Pb-Ag-Cu) vein and replacement bodies and the large Toromocho porphyry Cu-Mo deposit in its centre. U-Pb, Re-Os, and 40Ar/39Ar geochronology data for various porphyry-related hydrothermal mineralisation styles record a 3.5-Ma multi-stage history of magmatic-hydrothermal activity in the district. In the late Miocene, three individual magmatic-hydrothermal centres were active: the Codiciada, Toromocho, and Ticlio centres, each separated in time and space. The Codiciada centre is the oldest magmatic-hydrothermal system in the district and consists of a composite porphyry stock associated with anhydrous skarn and quartz-molybdenite veins. The hydrothermal events are recorded by a titanite U-Pb age at 9.3 ± 0.2 Ma and a molybdenite Re-Os age at 9.26 ± 0.03 Ma. These ages are indistinguishable from zircon U-Pb ages for porphyry intrusions of the composite stock and indicate a time span of 0.2 Ma for magmatic-hydrothermal activity. The small Ticlio magmatic-hydrothermal centre in the west of the district has a maximum duration of 0.3 Ma, ranging from porphyry emplacement to porphyry mineralisation at 8.04 ± 0.14 Ma (40Ar/39Ar muscovite cooling age). The Toromocho magmatic-hydrothermal centre has a minimum of five recorded porphyry intrusions that span a total of 1.3 Ma and is responsible for the formation of the giant Toromocho Cu-Mo deposit. At least two hydrothermal pulses are identified. Post-dating a first pulse of molybdenite mineralisation, wide-spread hydrous skarn covers an area of over 6 km2 and is recorded by five 40Ar/39Ar cooling ages at 7.2-6.8 Ma. These ages mark the end of the slowly cooling and long-lived Toromocho magmatic-hydrothermal centre soon after last magmatic activity at 7.26 ± 0.02 Ma. District-wide (50 km2) Cordilleran base metal vein and replacement bodies post-date the youngest recorded porphyry mineralisation event at Toromocho by more than 0.5 Ma. Polymetallic veins (5.78 ± 0.10 and 5.72 ± 0.18 Ma; 40Ar/39Ar ages) and the Manto Italia polymetallic replacement bodies (6.23 ± 0.12 and 6.0 ± 0.2 Ma; 40Ar/39Ar ages) are interpreted to have been formed by a single hydrothermal pulse. Hydrothermal activity ceased after the formation of the base metal vein and replacement bodies. Overlapping monazite U-Pb (8.26 ± 0.18 Ma) and muscovite 40Ar/39Ar ages (8.1 ± 0.5 Ma) from the early base metal stage of one Cordilleran vein sample in the Sulfurosa area provide evidence that a discrete hydrothermal pulse was responsible for polymetallic vein formation 2.6 Ma prior to the district-wide polymetallic veins. These ages pre-date those of Toromocho porphyry Cu-Mo formation and show that Zn-Pb-Ag-Cu mineralisation formed during several discrete magmatic-hydrothermal pulses in the same district.
Morgan, L.A.; Shanks, Wayne C.; Lovalvo, D.A.; Johnson, S.Y.; Stephenson, W.J.; Pierce, K.L.; Harlan, S.S.; Finn, C.A.; Lee, G.; Webring, M.; Schulze, B.; Duhn, J.; Sweeney, R.; Balistrieri, L.
2003-01-01
Discoveries from multi-beam sonar mapping and seismic reflection surveys of the northern, central, and West Thumb basins of Yellowstone Lake provide new insight into the extent of post-collapse volcanism and active hydrothermal processes occurring in a large lake environment above a large magma chamber. Yellowstone Lake has an irregular bottom covered with dozens of features directly related to hydrothermal, tectonic, volcanic, and sedimentary processes. Detailed bathymetric, seismic reflection, and magnetic evidence reveals that rhyolitic lava flows underlie much of Yellowstone Lake and exert fundamental control on lake bathymetry and localization of hydrothermal activity. Many previously unknown features have been identified and include over 250 hydrothermal vents, several very large (>500 m diameter) hydrothermal explosion craters, many small hydrothermal vent craters (???1-200 m diameter), domed lacustrine sediments related to hydrothermal activity, elongate fissures cutting post-glacial sediments, siliceous hydrothermal spire structures, sublacustrine landslide deposits, submerged former shorelines, and a recently active graben. Sampling and observations with a submersible remotely operated vehicle confirm and extend our understanding of the identified features. Faults, fissures, hydrothermally inflated domal structures, hydrothermal explosion craters, and sublacustrine landslides constitute potentially significant geologic hazards. Toxic elements derived from hydrothermal processes also may significantly affect the Yellowstone ecosystem. Published by Elsevier Science B.V.
Cunningham, Charles G.; Steven, Thomas A.; Campbell, David L.; Naeser, Charles W.; Pitkin, James A.; Duval, Joseph S.
1984-01-01
The report outlines the complex history of igneous activity and associated alteration and mineralization in the western Tushar Mountains, Utah and pointss out implciations for minerals exploration. The area has been subjected to recurrent episodes of igneous intrusion, hydrothermal alteration, and mineralization, and the mineral-resource potential of the different mineralized areas is directly related to local geologic history. The mineral commodities to be expected vary from one hydrothermal system to another, and from one depth to another within any given system. Uranium and molybdenum seem likely to have the greatest economic potential, although significant concentrations of gold may also exist.
30,000 years of hydrothermal activity at the lost city vent field.
Früh-Green, Gretchen L; Kelley, Deborah S; Bernasconi, Stefano M; Karson, Jeffrey A; Ludwig, Kristin A; Butterfield, David A; Boschi, Chiara; Proskurowski, Giora
2003-07-25
Strontium, carbon, and oxygen isotope data and radiocarbon ages document at least 30,000 years of hydrothermal activity driven by serpentinization reactions at Lost City. Serpentinization beneath this off-axis field is estimated to occur at a minimum rate of 1.2 x 10(-4) cubic kilometers per year. The access of seawater to relatively cool, fresh peridotite, coupled with faulting, volumetric expansion, and mass wasting processes, are crucial to sustain such systems. The amount of heat produced by serpentinization of peridotite massifs, typical of slow and ultraslow spreading environments, has the potential to drive Lost City-type systems for hundreds of thousands, possibly millions, of years.
Tabakaeva, O V; Kalenik, T K; Tabakaev, A V
2015-01-01
Products of technological and biotechnological modification (acid and enzymatic hydrolyzates and hydrothermal extracts) of the holothurian Cucumariajaponica from the Far East region are the complex multicomponent systems containing biologically active agents of a sea origin that has to provide them biological activity. The research objective consisted in quantitative studying of anti-radical properties of acid, enzymatic hydrolyzates and hydrothermal extracts from soft fabrics of a holothurian from the Far East region (Cucumaria japonica) and their influence on oxidation of lipids in fat emulsion products. The reaction with stable free 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical was used as a model system. Radical relating activity of hydrolyzates and extracts from Cucumaria japonica varied over a wide range from 48 to 78%. The maximum radical binding activity was noted for acid hydrolyzates. The activity of the hydrolyzate from a nimbus and feelers of Cucumaria japonica was comparable with activity of ionol. It has been defined that levels of manifestation of anti-radical activity depended on a way of technological and biotechnological processing of raw materials. Studying of fractional composition of melanoidins of hydrolyzates and extracts from Cucumaria japonica established that they can be divided into fractions--with molecular masses about 10,000 and 1000 Da. The maximum content of melanoidins has been defined in fraction weighing about 1000 Da. Introduction of acid, enzymatic hydrolyzates and hydrothermal extracts from Cucumaria japonica in the composition of oil-fat emulsion systems allowed to slow down processes of lipid oxidation and triglyceride hydrolysis in mayonnaise. Introduction of hydrolyzates and hydrothermal extracts from Cucumaria japonica in an oil-fat emulsion product allowed to reduce peroxide value by 22-45%, acid value by 12-35% on the 90th days of storage. Acid hydrolysates of Cucumaria Japonica most significantly reduce the rate of oxidation and hydrolysis.
The Interplay Between Saline Fluid Flow and Dynamic Permeability in Magmatic-Hydrothermal Systems
NASA Astrophysics Data System (ADS)
Weis, P.
2014-12-01
Magmatic-hydrothermal ore deposits document the interplay between saline fluid flow and rock permeability. Numerical simulations of multi-phase flow of variably miscible, compressible H20-NaCl fluids in concert with a dynamic permeability model can reproduce characteristics of porphyry copper and epithermal gold systems. This dynamic permeability model incorporates depth-dependent permeability profiles characteristic for tectonically active crust as well as pressure- and temperature-dependent relationships describing hydraulic fracturing and the transition from brittle to ductile rock behavior. In response to focused expulsion of magmatic fluids from a crystallizing upper crustal magma chamber, the hydrothermal system self-organizes into a hydrological divide, separating an inner part dominated by ascending magmatic fluids under near-lithostatic pressures from a surrounding outer part dominated by convection of colder meteoric fluids under near-hydrostatic pressures. This hydrological divide also provides a mechanism to transport magmatic salt through the crust, and prevents the hydrothermal system to become "clogged" by precipitation of solid halite due to depressurization of saline, high-temperature magmatic fluids. The same physical processes at similar permeability ranges, crustal depths and flow rates are relevant for a number of active systems, including geothermal resources and excess degassing at volcanos. The simulations further suggest that the described mechanism can separate the base of free convection in high-enthalpy geothermal systems from the magma chamber as a driving heat source by several kilometers in the vertical direction in tectonic settings with hydrous magmatism. This hydrology would be in contrast to settings with anhydrous magmatism, where the base of the geothermal systems may be closer to the magma chamber.
Tectonic and magmatic controls on hydrothermal activity in the Woodlark Basin
NASA Astrophysics Data System (ADS)
Laurila, T. E.; Petersen, S.; Devey, C. W.; Baker, E. T.; Augustin, N.; Hannington, M. D.
2012-09-01
The Woodlark Basin is one of the rare places on earth where the transition from continental breakup to seafloor spreading can be observed. The potential juxtaposition of continental rocks, a large magmatic heat source, crustal-scale faulting, and hydrothermal circulation has made the Woodlark Basin a prime target for seafloor mineral exploration. However, over the past 20 years, only two locations of active hydrothermalism had been found. In 2009 we surveyed 435 km of the spreading axis for the presence of hydrothermal plumes. Only one additional plume was found, bringing the total number of plumes known over 520 km of ridge axis to only 3, much less than at ridges with similar spreading rates globally. Particularly the western half of the basin (280 km of axis) is apparently devoid of high temperature plumes despite having thick crust and a presumably high magmatic budget. This paucity of hydrothermal activity may be related to the peculiar tectonic setting at Woodlark, where repeated ridge jumps and a re-location of the rotation pole both lead to axial magmatism being more widely distributed than at many other, more mature and stable mid-ocean ridges. These factors could inhibit the development of both a stable magmatic heat source and the deeply penetrating faults needed to create long-lived hydrothermal systems. We conclude that large seafloor massive sulfide deposits, potential targets for seafloor mineral exploration, will probably not be present along the spreading axis of the Woodlark Basin, especially in its younger, western portion.
NASA Astrophysics Data System (ADS)
Morales, Sergio; Alarcón, Alex; Basualto, Daniel; Bengoa, Cintia; Bertín, Daniel; Cardona, Carlos; Córdova, Maria; Franco, Luis; Gil, Fernando; Hernandez, Erasmo; Lara, Luis; Lazo, Jonathan; Mardones, Cristian; Medina, Roxana; Peña, Paola; Quijada, Jonathan; San Martín, Juan; Valderrama, Oscar
2015-04-01
Copahue Volcano (COPV), in Southern Andes of Chile, is an andesitic-basaltic stratovolcano, which is located on the western margin of Caviahue Caldera. The COPV have a NE-trending fissure with 9 aligned vents, being El Agrio the main currently active vent, with ca. 400 m in diameter. The COPV is placed into an extensive hydrothermal system which has modulated its recent 2012-2014 eruptive activity, with small phreatic to phreatomagmatic eruptions and isolated weak strombolian episodes and formation of crater lakes inside the main crater. Since 2012, the Southern Andes Volcano Observatory (OVDAS) carried out the real-time monitoring with seismic broadband stations, GPS, infrasound sensors and webcams. In this work, we report pre, sin, and post-eruptive seismic activity of the last two main eruptions (Dec, 2012 and Oct, 2014) both with different seismic precursors and superficial activity, showing the second one a particularly appearance of seismic quiescence episodes preceding explosive activity, as an indicator of interaction between magmatic-hydrothermal systems. The first episode, in late 2012, was characterized by a low frequency (0.3-0.4 Hz and 1.0-1.5 Hz) continuous tremor which increased gradually from background noise level amplitude to values of reduced displacement (DR), close to 50 cm2 at the peak of the eruption, reaching an eruptive column of ~1.5 km height. After few months of recording low energy seismicity, a sequence of low frequency, repetitive and low energy seismic events arose, with a frequency of occurrence up to 300 events/hour. Also, the VLP earthquakes were added to the record probably associated with magma intrusion into a deep magmatic chamber during all stages of eruptive process, joined to the record of VT seismicity during the same period, which is located throughout the Caviahue Caldera area. Both kind of seismic patterns were again recorded in October 2014, being the precursor of the new eruptive cycle at this time as well as the deformation of the volcanic edifice detected by GPS network. In this new eruptive process, the record of tremor was followed by particular seismic quiescence, as precursors of explosive activity which evolved from low acoustic energy signals toward more energetic signals with impulsive first arrivals and strong attenuation, joined to night incandescence in the main vent without evident juvenile material ejected, which could be associated to the temporal depression of the hydrothermal system located in the volcano system. The recent eruptive episode at Copahue Volcano is a good example of the complex temporal evolution of the interaction between magmatic and hydrothermal systems.
Back-Projection Imaging of extended, diffuse seismic sources in volcanic and hydrothermal systems
NASA Astrophysics Data System (ADS)
Kelly, C. L.; Lawrence, J. F.; Beroza, G. C.
2017-12-01
Volcanic and hydrothermal systems exhibit a wide range of seismicity that is directly linked to fluid and volatile activity in the subsurface and that can be indicative of imminent hazardous activity. Seismograms recorded near volcanic and hydrothermal systems typically contain "noisy" records, but in fact, these complex signals are generated by many overlapping low-magnitude displacements and pressure changes at depth. Unfortunately, excluding times of high-magnitude eruptive activity that typically occur infrequently relative to the length of a system's entire eruption cycle, these signals often have very low signal-to-noise ratios and are difficult to identify and study using established seismic analysis techniques (i.e. phase-picking, template matching). Arrays of short-period and broadband seismic sensors are proven tools for monitoring short- and long-term changes in volcanic and hydrothermal systems. Time-reversal techniques (i.e. back-projection) that are improved by additional seismic observations have been successfully applied to locating volcano-seismic sources recorded by dense sensor arrays. We present results from a new computationally efficient back-projection method that allows us to image the evolution of extended, diffuse sources of volcanic and hydrothermal seismicity. We correlate short time-window seismograms from receiver-pairs to find coherent signals and propagate them back in time to potential source locations in a 3D subsurface model. The strength of coherent seismic signal associated with any potential source-receiver-receiver geometry is equal to the correlation of the short time-windows of seismic records at appropriate time lags as determined by the velocity structure and ray paths. We stack (sum) all short time-window correlations from all receiver-pairs to determine the cumulative coherence of signals at each potential source location. Through stacking, coherent signals from extended and/or repeating sources of short-period energy radiation interfere constructively while background noise signals interfere destructively, such that the most likely source locations of the observed seismicity are illuminated. We compile results to analyze changes in the distribution and prevalence of these sources throughout a systems entire eruptive cycle.
NASA Astrophysics Data System (ADS)
Pintoro, A.; Ambarita, H.; Nur, T. B.; Napitupulu, F. H.
2018-02-01
Indonesia has a high potential energy resources from geothermal activities. Base on the report of Asian Development Bank and World Bank, the estimated of Indonesian hydrothermal geothermal resource considered to be the largest among the world. If it’s can be utilized to produce the electric power, it’s can contribute to increasing the electrification rates in Indonesia. In this study, an experimental studied of electric power generation, utilizing the Organic Rankine Cycle (ORC) system to convert the low level heat of hydrothermal as an energy source. The temperature of hydrothermal was modelled as hot water from water boiler which has a temperature range from 60 °C - 100 °C to heat up the organic working fluid of ORC system. The system can generated 1,337.7 watts of electricity when operated using R134A with hot water inlet temperature of 100 °C. Changing system working fluid to R245fa, the net power obtained increase to 1,908.9 watts with the same heat source condition. This study showed that the ORC system can be implemented to utilize low temperature heat source of hydrothermal in Indonesia.
NASA Astrophysics Data System (ADS)
Seki, Kaori; Kanda, Wataru; Tanbo, Toshiya; Ohba, Takeshi; Ogawa, Yasuo; Takakura, Shinichi; Nogami, Kenji; Ushioda, Masashi; Suzuki, Atsushi; Saito, Zenshiro; Matsunaga, Yasuo
2016-10-01
This study clarifies the hydrothermal system of Jigokudani Valley near Mt. Tateyama volcano in Japan by using a combination of audio-frequency magnetotelluric (AMT) survey and hot-spring water analysis in order to assess the potential of future phreatic eruptions in the area. Repeated phreatic eruptions in the area about 40,000 years ago produced the current valley morphology, which is now an active solfatara field dotted with hot springs and fumaroles indicative of a well-developed hydrothermal system. The three-dimensional (3D) resistivity structure of the hydrothermal system was modeled by using the results of an AMT survey conducted at 25 locations across the valley in 2013-2014. The model suggests the presence of a near-surface highly conductive layer of < 50 m in thickness across the entire valley, which is interpreted as a cap rock layer. Immediately below the cap rock is a relatively resistive body interpreted as a gas reservoir. Field measurements of temperature, pH, and electrical conductivity (EC) were taken at various hot springs across the valley, and 12 samples of hot-spring waters were analyzed for major ion chemistry and H2O isotopic ratios. All hot-spring waters had low pH and could be categorized into three types on the basis of the Cl-/SO 42 - concentration ratio, with all falling largely on a mixing line between magmatic fluids and local meteoric water (LMW). The geochemical analysis suggests that the hydrothermal system includes a two-phase zone of vapor-liquid. A comparison of the resistivity structure and the geochemically inferred structure suggests that a hydrothermal reservoir is present at a depth of approximately 500 m, from which hot-spring water differentiates into the three observed types. The two-phase zone appears to be located immediately beneath the cap rock structure. These findings suggest that the hydrothermal system of Jigokudani Valley exhibits a number of factors that could trigger a future phreatic eruption.
NASA Astrophysics Data System (ADS)
Fontaine, F. J.; Cannat, M.; Escartin, J.; Crawford, W. C.; Singh, S. C.
2012-12-01
The modalities and efficiency of hydrothermal heat evacuation at mid-ocean ridges (25% of the global heat loss) are controlled by the lithosphere thermal and permeability structures for which we had robust constraints only for fast/intermediate spreading axis until the last past few years during which integrated geophysical, geological and geochemical studies focused on some hydrothermal sites at slow-spreading ridges. At the Lucky Strike vent field of the mid-atlantic ridge - a hydrothermal complex composed of high-temperature (maximum T=340°C), smoker-like vents and associated diffuse flow and extracting a few hundreds MW from the oceanic lithosphere - a seafloor observatory which installation started in 2005 highlights local interactions between hydrothermal, tectonic and magmatic processes. Detailed geophysical and geological investigations stress the role of the local axial fault system on localizing high- and low-temperature ventings around the faulted rim of a paleo lava lake. Microseismic studies bring constraints on the subseafloor hydrology and suggest an along-axis flow pattern, with a privileged recharge area located about a kilometer north off the active discharges. Seismic reflection studies image a central magma chamber fueling the hydrothermal sites and also reveal its along-axis depth variations likely influencing hydrothermal cell organization and flow focusing. Such linkages among hydrothermal dynamics, heat source and crustal permeability geometries usually lack quantitative constraints at mid-ocean ridges in general, and the Lucky Strike segment settings offers a unique opportunity to couple high-resolution geophysical data to hydrodynamic model. Here we develop a series of original two- and three-dimensional numerical and physical models of hydrothermal activity, tailored to this slow-spreading environment. Our results highlight physical linkages among magmatism, tectonics and crustal hydrology stressing the key role of faulting and magma chamber roof-topology in focusing fluid flow at the center of the Lucky Strike segment. They also help identifying some causes of variations in the modalities of hydrothermal heat extraction along the global ridge network.
Leal-Acosta, María Luisa; Shumilin, Evgueni; Mirlean, Nicolai; Delgadillo-Hinojosa, Francisco; Sánchez-Rodríguez, Ignacio
2013-02-01
The influence of hydrothermal venting activity on arsenic (As) and mercury (Hg) accumulation was investigated in the shallow-water marine ecosystem of Concepcion Bay in the western Gulf of California. Geochemical data indicate that the marine shallow-water hydrothermal system of the Mapachitos site is a source of As and Hg for the water, sediment and algae collected along a transect moving across the western region of the bay. Although a small proportion of As and Hg precipitates close to the hydrothermal vent, both elements remain largely in the dissolved fraction, spreading a long distance from the source. The brown seaweed Sargassum sinicola thriving near the area of hydrothermal venting accumulates large quantities of As (above 600 mg kg (-1)), surpassing its typical concentration in the genus Sargassum by an order of magnitude. In contrast to As, the seaweed does not significantly accumulate Hg.
NASA Astrophysics Data System (ADS)
Neveu, Marc Francois Laurent
Finding habitable worlds is a key driver of solar system exploration. Many solar system missions seek environments providing liquid water, energy, and nutrients, the three ingredients necessary to sustain life. Such environments include hydrothermal systems, spatially-confined systems where hot aqueous fluid circulates through rock by convection. I sought to characterize hydrothermal microbial communities, collected in hot spring sediments and mats at Yellowstone National Park, USA, by measuring their bulk elemental composition. To do so, one must minimize the contribution of non-biological material to the samples analyzed. I demonstrate that this can be achieved using a separation method that takes advantage of the density contrast between cells and sediment and preserves cellular elemental contents. Using this method, I show that in spite of the tremendous physical, chemical, and taxonomic diversity of Yellowstone hot springs, the composition of microorganisms there is surprisingly ordinary. This suggests the existence of a stoichiometric envelope common to all life as we know it. Thus, future planetary investigations could use elemental fingerprints to assess the astrobiological potential of hydrothermal settings beyond Earth. Indeed, hydrothermal activity may be widespread in the solar system. Most solar system worlds larger than 200 km in radius are dwarf planets, likely composed of an icy, cometary mantle surrounding a rocky, chondritic core. I enhance a dwarf planet evolution code, including the effects of core fracturing and hydrothermal circulation, to demonstrate that dwarf planets likely have undergone extensive water-rock interaction. This supports observations of aqueous products on their surfaces. I simulate the alteration of chondritic rock by pure water or cometary fluid to show that aqueous alteration feeds back on geophysical evolution: it modifies the fluid antifreeze content, affecting its persistence over geological timescales; and the distribution of radionuclides, whose decay is a chief heat source on dwarf planets. Interaction products can be observed if transported to the surface. I simulate numerically how cryovolcanic transport is enabled by primordial and hydrothermal volatile exsolution. Cryovolcanism seems plausible on dwarf planets in light of images recently returned by spacecrafts. Thus, these coupled geophysical-geochemical models provide a comprehensive picture of dwarf planet evolution, processes, and habitability.
NASA Astrophysics Data System (ADS)
Roedder, Edwin
1990-11-01
This paper presents arguments against the statement made by Koeberl et al. (1989) to the effect that various differences between the quartz of the three quartz pebbles from the Roter Kamm impact crater (Namibia) and the quartz of the pegmatites present in the basement rocks of this crater can be best interpreted as evidence that the pebbles were formed (or 'recrystallized') by a post-impact hydrothermal system. Arguments are presented that suggest that the three quartz pebbles are, most likely, fragments of a preimpact vein quartz of hydrothermal origin.
NASA Technical Reports Server (NTRS)
Socki, Richard A.; Niles, Paul B.; Gibson, Everett K., Jr.; Romanek, Christopher S.; Zhang, Chuanlun L.; Bissada, Kadry K.
2008-01-01
The recent detection of methane in the Martian atmosphere and the possibility that its origin could be attributed to biological activity, have highlighted the importance of understanding the mechanisms of methane formation and its usefulness as a biomarker. Much debate has centered on the source of the methane in hydrothermal fluids, whether it is formed biologically by microorganisms, diagenetically through the decomposition of sedimentary organic matter, or inorganically via reduction of CO2 at high temperatures. Ongoing research has now shown that much of the methane present in sea-floor hydrothermal systems is probably formed through inorganic CO2 reduction processes at very high temperatures (greater than 400 C). Experimental results have indicated that methane might form inorganically at temperatures lower still, however these results remain controversial. Currently, methane in continental hydrothermal systems is thought to be formed mainly through the breakdown of sedimentary organic matter and carbon isotope equilibrium between CO2 and CH4 is thought to be rarely present if at all. Based on isotopic measurements of CO2 and CH4 in two continental hydrothermal systems, we suggest that carbon isotope equilibration exists at temperatures as low as 155 C. This would indicate that methane is forming through abiotic CO2 reduction at lower temperatures than previously thought and could bolster arguments for an abiotic origin of the methane detected in the martian atmosphere.
NASA Astrophysics Data System (ADS)
Morgan, L. A.; Shanks, W. C.; Lovalvo, D. A.; Johnson, S. Y.; Stephenson, W. J.; Pierce, K. L.; Harlan, S. S.; Finn, C. A.; Lee, G.; Webring, M.; Schulze, B.; Dühn, J.; Sweeney, R.; Balistrieri, L.
2003-04-01
'No portion of the American continent is perhaps so rich in wonders as the Yellow Stone' (F.V. Hayden, September 2, 1874) Discoveries from multi-beam sonar mapping and seismic reflection surveys of the northern, central, and West Thumb basins of Yellowstone Lake provide new insight into the extent of post-collapse volcanism and active hydrothermal processes occurring in a large lake environment above a large magma chamber. Yellowstone Lake has an irregular bottom covered with dozens of features directly related to hydrothermal, tectonic, volcanic, and sedimentary processes. Detailed bathymetric, seismic reflection, and magnetic evidence reveals that rhyolitic lava flows underlie much of Yellowstone Lake and exert fundamental control on lake bathymetry and localization of hydrothermal activity. Many previously unknown features have been identified and include over 250 hydrothermal vents, several very large (>500 m diameter) hydrothermal explosion craters, many small hydrothermal vent craters (˜1-200 m diameter), domed lacustrine sediments related to hydrothermal activity, elongate fissures cutting post-glacial sediments, siliceous hydrothermal spire structures, sublacustrine landslide deposits, submerged former shorelines, and a recently active graben. Sampling and observations with a submersible remotely operated vehicle confirm and extend our understanding of the identified features. Faults, fissures, hydrothermally inflated domal structures, hydrothermal explosion craters, and sublacustrine landslides constitute potentially significant geologic hazards. Toxic elements derived from hydrothermal processes also may significantly affect the Yellowstone ecosystem.
Bell, James B; Woulds, Clare; Oevelen, Dick van
2017-09-20
Hydrothermal vents are highly dynamic ecosystems and are unusually energy rich in the deep-sea. In situ hydrothermal-based productivity combined with sinking photosynthetic organic matter in a soft-sediment setting creates geochemically diverse environments, which remain poorly studied. Here, we use comprehensive set of new and existing field observations to develop a quantitative ecosystem model of a deep-sea chemosynthetic ecosystem from the most southerly hydrothermal vent system known. We find evidence of chemosynthetic production supplementing the metazoan food web both at vent sites and elsewhere in the Bransfield Strait. Endosymbiont-bearing fauna were very important in supporting the transfer of chemosynthetic carbon into the food web, particularly to higher trophic levels. Chemosynthetic production occurred at all sites to varying degrees but was generally only a small component of the total organic matter inputs to the food web, even in the most hydrothermally active areas, owing in part to a low and patchy density of vent-endemic fauna. Differences between relative abundance of faunal functional groups, resulting from environmental variability, were clear drivers of differences in biogeochemical cycling and resulted in substantially different carbon processing patterns between habitats.
Dating of barite and anhydrite in sea-floor hydrothermal deposits in the Okinawa Trough
NASA Astrophysics Data System (ADS)
Taisei, F.; Toyoda, S.; Uchida, A.; Ishibashi, J. I.; Totsuka, S.; Shimada, K.; Nakai, S.
2016-12-01
Dating of submarine hydrothermal activities has been an important issue in the aspect of the ore formation (Urabe, 1995) and biological systems sustained by the chemical species arising from hydrothermal activities (Macdonald et al., 1980). For this purpose, dating methods using radioactive disequilibrium such as U-Th method (e.g. You and Bickle, 1998) for sulfide, 226Ra-210Pb and 228Ra-228Th (e.g. Noguchi et al., 2011), Ra/Ba, and ESR (Electron Spin Resonance) methods for barite (Okumura et al., 2010) have been employed. In this study, firstly, we will report the first successful dating results on anhydrite using 226Ra-210Pb and 228Ra-228Th methods. The anhydrite samples were taken from the Daiyon-Yonaguni knoll field and the Hatoma knoll field and the Iheya North Knoll field of the Okinawa Trough by research cruises operated by JAMSTEC. The anhydrite crystals were physically scratched out of the samples. 226Ra, 228Ra and daughter nuclei were measured in the same samples for the ESR method by the low background gamma ray spectrometry. From the activity ratios, disequilibrium ages were obtained to be about 7.3 years by 226Ra-210Pb method, and to be 0.6-2.5 years by 228Ra-228Th method. Secondly, the ESR ages of barite taken from hydrothermal areas in the Okinawa trough range from 4.1 to 16000 years, filling the age gap of the maximum age, 150 years, of 226Ra-210Pb method and the minimum age, several thousand years of U-Th method, being the most appropriate age range to discuss the evolution of the hydrothermal systems. Interestingly, the 226Ra-210Pb and 228Ra-228Th ages for the same samples are the same or younger than the ESR ages. As for the latter samples, the reason has already been discussed (Uchida et al., 2015) as the deposits had been formed by two or more hydrothermal events. In the present paper, the disequilibrium and ESR ages will be simulated with these multiple hydrothermal events so that the differences in the ages are explained.
Modeling microbial reaction rates in a submarine hydrothermal vent chimney wall
NASA Astrophysics Data System (ADS)
LaRowe, Douglas E.; Dale, Andrew W.; Aguilera, David R.; L'Heureux, Ivan; Amend, Jan P.; Regnier, Pierre
2014-01-01
The fluids emanating from active submarine hydrothermal vent chimneys provide a window into subseafloor processes and, through mixing with seawater, are responsible for steep thermal and compositional gradients that provide the energetic basis for diverse biological communities. Although several models have been developed to better understand the dynamic interplay of seawater, hydrothermal fluid, minerals and microorganisms inside chimney walls, none provide a fully integrated approach to quantifying the biogeochemistry of these hydrothermal systems. In an effort to remedy this, a fully coupled biogeochemical reaction-transport model of a hydrothermal vent chimney has been developed that explicitly quantifies the rates of microbial catalysis while taking into account geochemical processes such as fluid flow, solute transport and oxidation-reduction reactions associated with fluid mixing as a function of temperature. The metabolisms included in the reaction network are methanogenesis, aerobic oxidation of hydrogen, sulfide and methane and sulfate reduction by hydrogen and methane. Model results indicate that microbial catalysis is generally fastest in the hottest habitable portion of the vent chimney (77-102 °C), and methane and sulfide oxidation peak near the seawater-side of the chimney. The fastest metabolisms are aerobic oxidation of H2 and sulfide and reduction of sulfate by H2 with maximum rates of 140, 900 and 800 pmol cm-3 d-1, respectively. The maximum rate of hydrogenotrophic methanogenesis is just under 0.03 pmol cm-3 d-1, the slowest of the metabolisms considered. Due to thermodynamic inhibition, there is no anaerobic oxidation of methane by sulfate (AOM). These simulations are consistent with vent chimney metabolic activity inferred from phylogenetic data reported in the literature. The model developed here provides a quantitative approach to describing the rates of biogeochemical transformations in hydrothermal systems and can be used to constrain the role of microbial activity in the deep subsurface.
Larson, Peter B.; Phillips, Allison; John, David A.; Cosca, Michael A.; Pritchard, Chad; Andersen, Allen; Manion, Jennifer
2009-01-01
Erosion in the Grand Canyon of the Yellowstone River, Yellowstone Caldera (640 ka), Wyoming, has exposed a cross section of older hydrothermal alteration in the canyon walls. The altered outcrops of the post-collapse tuff of Sulphur Creek (480 ka) extend from the canyon rim to more than 300 m beneath it. The hydrothermal minerals are zoned, with an advanced argillic alteration consisting of an association of quartz (opal) + kaolinite ± alunite ± dickite, and an argillic or potassic alteration association with quartz + illite ± adularia. Disseminated fine-grained pyrite or marcasite is ubiquitous in both alteration types. These alteration associations are characteristic products of shallow volcanic epithermal environments. The contact between the two alteration types is about 100 m beneath the rim. By analogy to other active geothermal systems including active hydrothermal springs in the Yellowstone Caldera, the transition from kaolinite to illite occurred at temperatures in the range 150 to 170 °C. An 40Ar/39Ar age on alunite of 154,000 ± 16,000 years suggests that hydrothermal activity has been ongoing since at least that time. A northwest-trending linear array of extinct and active hot spring centers in the Sevenmile Hole area implies a deeper structural control for the upflowing hydrothermal fluids. We interpret this deeper structure to be the Yellowstone Caldera ring fault that is covered by the younger tuff of Sulphur Creek. The Sevenmile Hole altered area lies at the eastern end of a band of hydrothermal centers that may mark the buried extension of the Yellowstone Caldera ring fault across the northern part of the Caldera.
NASA Astrophysics Data System (ADS)
Keith, Manuel; Haase, Karsten M.; Klemd, Reiner; Smith, Daniel J.; Schwarz-Schampera, Ulrich; Bach, Wolfgang
2018-05-01
Most magmatic-hydrothermal Cu deposits are genetically linked to arc magmas. However, most continental or oceanic arc magmas are barren, and hence new methods have to be developed to distinguish between barren and mineralised arc systems. Source composition, melting conditions, the timing of S saturation and an initial chalcophile element-enrichment represent important parameters that control the potential of a subduction setting to host an economically valuable deposit. Brothers volcano in the Kermadec island arc is one of the best-studied examples of arc-related submarine magmatic-hydrothermal activity. This study, for the first time, compares the chemical and mineralogical composition of the Brothers seafloor massive sulphides and the associated dacitic to rhyolitic lavas that host the hydrothermal system. Incompatible trace element ratios, such as La/Sm and Ce/Pb, indicate that the basaltic melts from L'Esperance volcano may represent a parental analogue to the more evolved Brothers lavas. Copper-rich magmatic sulphides (Cu > 2 wt%) identified in fresh volcanic glass and phenocryst phases, such as clinopyroxene, plagioclase and Fe-Ti oxide suggest that the surrounding lavas that host the Brothers hydrothermal system represent a potential Cu source for the sulphide ores at the seafloor. Thermodynamic calculations reveal that the Brothers melts reached volatile saturation during their evolution. Melt inclusion data and the occurrence of sulphides along vesicle margins indicate that an exsolving volatile phase extracted Cu from the silicate melt and probably contributed it to the overlying hydrothermal system. Hence, the formation of the Cu-rich seafloor massive sulphides (up to 35.6 wt%) is probably due to the contribution of Cu from a bimodal source including wall rock leaching and magmatic degassing, in a mineralisation style that is hybrid between Cyprus-type volcanic-hosted massive sulphide and subaerial epithermal-porphyry deposits.
NASA Astrophysics Data System (ADS)
Tao, C.; Liang, J.; Zhang, H.; Li, H.; Egorov, I. V.; Liao, S.
2016-12-01
The Dragon Horn Area (49.7°E), is located at the west end of the EW trending Segment 28 of Southwest Indian Ridge between Indomed and Gallieni FZ. The segment is characterized by highly asymmetric topography. The northern flank is deeper and develops typical parallel linear fault escarpments. Meanwhile, the southern flank, where the Dragon Horn lies, is shallower and bears corrugations. The indicative corrugated surface which extends some 5×5 km was interpreted to be of Dragon Flag OCC origin (Zhao et al., 2013). Neo-volcanic ridge extends along the middle of the rifted valley and is bounded by two non-transform offsets to the east and west. Our investigations revealed 6 hydrothermal fields/anomalies in this area, including 2 confirmed sulfide fields, 1 carbonate field, and 3 inferred hydrothermal anomalies based on methane and turbidity data from 2016 AUV survey. Longqi-1(Dragon Flag) vent system lies to the northwest edge of Dragon Flag OCC. It is one of the largest hydrothermal venting systems along Mid-Ocean Ridges, with maximum temperature at vent site DFF6 of 'M zone' up to 379.3 °C (Tao et al, 2016). Massive sulfides (49.73 °E, 37.78 °S) were sampled 10 km east to Longqi-1, representing independent hydrothermal activities controlled by respective local structures. According to geological mapping and interpretation, both sulfide fields are located on the hanging wall of the Dragon Flag OCC detachment. Combined with the inferred hydrothermal anomaly to the east of the massive sulfide site, we suppose that they are controlled by different fault phases during the detachment of oceanic core complex. Moreover, consolidated carbonate sediments were widely observed and sampled on the corrugated surface and its west side, they are proposed to be precipitated during the serpentinization of ultramafic rocks, representing low-temperature hydrothermal process. These hydrothermal activities, distributed within 20km, may be controlled by the same Dragon Flag OCC. Acknowledgement This work was supported by National Basic Research Program of China (973 Program) under contract No. 2012CB417305, China Ocean Mineral Resources R & D Association "Twelfth Five-Year" Major Program under contract No. DY125-11-R-01 and DY125-11-R-05
Geologic field-trip guide to the volcanic and hydrothermal landscape of the Yellowstone Plateau
Morgan Morzel, Lisa Ann; Shanks, W. C. Pat; Lowenstern, Jacob B.; Farrell, Jamie M.; Robinson, Joel E.
2017-11-20
Yellowstone National Park, a nearly 9,000 km2 (~3,468 mi2) area, was preserved in 1872 as the world’s first national park for its unique, extraordinary, and magnificent natural features. Rimmed by a crescent of older mountainous terrain, Yellowstone National Park has at its core the Quaternary Yellowstone Plateau, an undulating landscape shaped by forces of late Cenozoic explosive and effusive volcanism, on-going tectonism, glaciation, and hydrothermal activity. The Yellowstone Caldera is the centerpiece of the Yellowstone Plateau. The Yellowstone Plateau lies at the most northeastern front of the 17-Ma Yellowstone hot spot track, one of the few places on Earth where time-transgressive processes on continental crust can be observed in the volcanic and tectonic (faulting and uplift) record at the rate and direction predicted by plate motion. Over six days, this field trip presents an intensive overview into volcanism, tectonism, and hydrothermal activity on the Yellowstone Plateau (fig. 1). Field stops are linked directly to conceptual models related to monitoring of the various volcanic, geochemical, hydrothermal, and tectonic aspects of the greater Yellowstone system. Recent interest in young and possible future volcanism at Yellowstone as well as new discoveries and synthesis of previous studies, (for example, tomographic, deformation, gas, aeromagnetic, bathymetric, and seismic surveys), provide a framework in which to discuss volcanic, hydrothermal, and seismic activity in this dynamic region.
NASA Astrophysics Data System (ADS)
Yumao, Pang; Xunhua, Zhang; Guolin, Xiao; Luning, Shang; Xingwei, Guo; Zhenhe, Wen
2018-04-01
Various igneous complexes were identified in multi-channel seismic reflection profiles from the South Yellow Sea Basin. It is not rare that magmatic intrusions in sedimentary basins cause strong thermal perturbations and hydrothermal activities. Some intrusion-related hydrothermal vent complexes have been identified and they are considered to originate from the deep sedimentary contact aureole around igneous intrusions and terminate in upper vents structures, and are linked by a vertical conduit system. The upper vent complexes are usually eye-shaped, dome-shaped, fault-related, crater-shaped or pock-shaped in seismic profiles. A schematic model was proposed to illustrate the structures of different types of hydrothermal vent complexes. A conceptual conduit model composed of an upper pipe-like part and a lower branching part was also derived. Hydrothermal vent complexes mainly developed during the Middle-Late Cretaceous, which is coeval with, or shortly after the intrusion. The back-arc basin evolution of the area which is related to the subduction of the Paleo-Pacific plate during the Mesozoic-Cenozoic may be the principal factor for voluminous igneous complexes and vent complexes in this area. It is significant to study the characteristics of igneous complexes and related hydrothermal vent complexes, which will have implications for the future study of this area.
White, Donald Edward; Hutchinson, Roderick A.; Keith, Terry E.C.
1988-01-01
Norris Geyser Basin, normally shortened to Norris Basin, is adjacent to the north rim of the Yellowstone caldera at the common intersection of the caldera rim and the Norris-Mammoth Corridor, a zone of faults, volcanic vents, and thermal activity that strikes north from the caldera rim to Mammoth Hot Springs. An east-west fault zone terminates the Gallatin Range at its southern end and extends from Hebgen Lake, west of the park, to Norris Basin. No local evidence exists at the surface in Norris Basin for the two oldest Yellowstone volcanic caldera cycles (~2.0 and 1.3 m.y.B.P.). The third and youngest cycle formed the Yellowstone caldera, which erupted the 600,000-year-old Lava Creek Tuff. No evidence is preserved of hydrothermal activity near Norris Basin during the first 300,000.years after the caldera collapse. Glaciation probably removed most of the early evidence, but erratics of hot-spring sinter that had been converted diagenetically to extremely hard, resistant chalcedonic sinter are present as cobbles in and on some moraines and till from the last two glacial stages, here correlated with the early and late stages of the Pinedale glaciation <150,000 years B.P.). Indirect evidence for the oldest hydrothermal system at Norris Basin indicates an age probably older than both stages of Pinedale glaciation. Stream deposits consisting mainly of rounded quartz phenocrysts of the Lava Creek Tuff were subaerial, perhaps in part windblown and redeposited by streams. A few small rounded pebbles are interpreted as chalcedonic sinter of a still older cycle. None of these are precisely dated but are unlikely to be more than 150,000 to 200,000 years old. ...Most studies of active hydrothermal areas have noted chemical differences in fluids and alteration products but have given little attention to differences and models to explain evolution in types. This report, in contrast, emphasizes the kinds of changes in vents and their changing chemical types of waters and then provides models for explaining these differences. Norris Basin is probably not an independent volcanic-hydrothermal system. The basin and nearby acid-leached areas (from oxidation of H2S-enriched vapor) are best considered as parts of the same system, extending from Norris Basin to Roaring Mountain and possibly to Mammoth. If so, are they parts of a single large system centered within the Yellowstone caldera, or are Norris Basin and the nearby altered areas both parts of one or more young independent corridor systems confined, at least in the shallow crust, to the Norris-Mammoth Corridor? Tentatively, we favor the latter relation, probably having evolved in the past ~300,000 years. A model for large, long-lived, volcanic-hydrothermal activity is also suggested, involving all of the crust and upper mantle and using much recent geophysical data bearing on crust-mantle interrelations. Our model for large systems is much superior to previous suggestions for explaining continuing hydrothermal activity over hundreds of thousands of years, but is less attractive for the smaller nonhomogenized volcanic system actually favored here for the Norris-Mammoth Corridor.
NASA Astrophysics Data System (ADS)
Dickey, K.; Holbrook, W. S.; Finn, C.; Auken, E.; Carr, B.; Sims, K. W. W.; Bedrosian, P.; Lowenstern, J. B.; Hurwitz, S.; Pedersen, J. B. B.
2017-12-01
Yellowstone National Park hosts over 10,000 thermal features (e.g. geysers, fumaroles, mud pots, and hot springs), yet little is known about the circulation depth of meteoric water feeding these features, nor the lithological and structural bounds on the pathways that guide deep, hot fluids to the surface. Previous near-surface geophysical studies have been effective in imaging shallow hydrothermal pathways in some areas of the park, but these methods are difficult to conduct over the large areas needed to characterize entire hydrothermal systems. Transient electromagnetic (TEM) soundings and 2D direct current (DC) resistivity profiles show that hydrothermal fluids at active sites have a higher electrical conductivity than the surrounding hydrothermally inactive areas. For that reason, airborne TEM is an effective method to characterize large areas and identify hydrothermally active and inactive zones using electrical conductivity. Aeromagnetic data have been useful in mapping faults that localize hot springs, making the integration of aeromagnetic and EM data effective for structurally characterizing fluid pathways. Here we present the preliminary results from an airborne transient electromagnetic (TEM) and magnetic survey acquired jointly by the U.S. Geological Survey (USGS) and the University of Wyoming (UW) in November 2016. We integrate the EM and magnetic data for the purpose of edge detection of rhyolite flow boundaries as well as source depth of hydrothermal features. The maximum horizontal gradient technique applied on magnetic data is a useful tool that used to estimate source depth as well as indicate faults and fractures. The integration of EM with magnetics allows us to distinguish hydrothermally altered fault systems that guide fluids in the subsurface. We have used preliminary 2D inversions of EM from Aarhus Workbench to delineate rhyolite flow edges in the upper 300-600 meters and cross-checked those boundaries with the aeromagnetic map.
Diverse styles of submarine venting on the ultraslow spreading Mid-Cayman Rise
German, C. R.; Bowen, A.; Coleman, M. L.; Honig, D. L.; Huber, J. A.; Jakuba, M. V.; Kinsey, J. C.; Kurz, M. D.; Leroy, S.; McDermott, J. M.; de Lépinay, B. Mercier; Nakamura, K.; Seewald, J. S.; Smith, J. L.; Sylva, S. P.; Van Dover, C. L.; Whitcomb, L. L.; Yoerger, D. R.
2010-01-01
Thirty years after the first discovery of high-temperature submarine venting, the vast majority of the global mid-ocean ridge remains unexplored for hydrothermal activity. Of particular interest are the world’s ultraslow spreading ridges that were the last to be demonstrated to host high-temperature venting but may host systems particularly relevant to prebiotic chemistry and the origins of life. Here we report evidence for previously unknown, diverse, and very deep hydrothermal vents along the ∼110 km long, ultraslow spreading Mid-Cayman Rise (MCR). Our data indicate that the MCR hosts at least three discrete hydrothermal sites, each representing a different type of water-rock interaction, including both mafic and ultramafic systems and, at ∼5,000 m, the deepest known hydrothermal vent. Although submarine hydrothermal circulation, in which seawater percolates through and reacts with host lithologies, occurs on all mid-ocean ridges, the diversity of vent types identified here and their relative geographic isolation make the MCR unique in the oceans. These new sites offer prospects for an expanded range of vent-fluid compositions, varieties of abiotic organic chemical synthesis and extremophile microorganisms, and unparalleled faunal biodiversity—all in close proximity. PMID:20660317
Hydrothermal systems as environments for the emergence of life
NASA Technical Reports Server (NTRS)
Shock, E. L.
1996-01-01
Analysis of the chemical disequilibrium provided by the mixing of hydrothermal fluids and seawater in present-day systems indicates that organic synthesis from CO2 or carbonic acid is thermodynamically favoured in the conditions in which hyperthermophilic microorganisms are known to live. These organisms lower the Gibbs free energy of the chemical mixture by synthesizing many of the components of their cells. Primary productivity is enormous in hydrothermal systems because it depends only on catalysis of thermodynamically favourable, exergonic reactions. It follows that hydrothermal systems may be the most favourable environments for life on Earth. This fact makes hydrothermal systems logical candidates for the location of the emergence of life, a speculation that is supported by genetic evidence that modern hyperthermophilic organisms are closer to a common ancestor than any other forms of life. The presence of hydrothermal systems on the early Earth would correspond to the presence of liquid water. Evidence that hydrothermal systems existed early in the history of Mars raises the possibility that life may have emerged on Mars as well. Redox reactions between water and rock establish the potential for organic synthesis in and around hydrothermal systems. Therefore, the single most important parameter for modelling the geochemical emergence of life on the early Earth or Mars is the composition of the rock which hosts the hydrothermal system.
,; Foley, Duncan; Fournier, Robert O.; Heasler, Henry P.; Hinckley, Bern; Ingebritsen, Steven E.; Lowenstern, Jacob B.; Susong, David D.
2014-01-01
There are many documented examples at YNP and elsewhere where human infrastructure and natural thermal features have negatively affected each other. Unless action is taken, human conflicts with the Old Faithful hydrothermal system are likely to increase over the coming years. This is partly because of the increase in park visitation over the past decades, but also because the interval between eruptions of Old Faithful has increased, lengthening the time spent (and services needed) for each visitor at Old Faithful. To avoid an increase in visitor impacts, the National Park Service should consider 2 alternate strategies to accommodate people, vehicles, and services in the Upper Geyser Basin, such as shuttle services from staging (parking and dining) areas with little or no recent hydrothermal activity. We further suggest that YNP consider a zone system to guide maintenance and development of infrastructure in the immediate Old Faithful area. A “red” zone includes hydrothermally active land where new development is discouraged and existing infrastructure is modified with great care. An outer “green” zone represents areas where cooler temperatures and less hydrothermal flow are thought to exist, and where development and maintenance could proceed as occurs elsewhere in the park. An intermediate “yellow” zone would require preliminary assessment of subsurface temperatures and gas concentrations to assess suitability for infrastructure development. The panel recommends that YNP management follow the lead of the National Park System Advisory Board Science Committee (2012) by applying the “precautionary principle” when making decisions regarding the interaction of hydrothermal phenomena and park infrastructure in the Old Faithful area and other thermal areas within YNP.
Klein, Frieder; Humphris, Susan E; Guo, Weifu; Schubotz, Florence; Schwarzenbach, Esther M; Orsi, William D
2015-09-29
Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support deep chemolithoautotrophic life in the hydrated oceanic mantle (i.e., serpentinite). However, geosphere-biosphere interactions in serpentinite-hosted subseafloor mixing zones remain poorly constrained. Here we examine fossil microbial communities and fluid mixing processes in the subseafloor of a Cretaceous Lost City-type hydrothermal system at the magma-poor passive Iberia Margin (Ocean Drilling Program Leg 149, Hole 897D). Brucite-calcite mineral assemblages precipitated from mixed fluids ca. 65 m below the Cretaceous paleo-seafloor at temperatures of 31.7 ± 4.3 °C within steep chemical gradients between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity. Dense microbial colonies are fossilized in brucite-calcite veins that are strongly enriched in organic carbon (up to 0.5 wt.% of the total carbon) but depleted in (13)C (δ(13)C(TOC) = -19.4‰). We detected a combination of bacterial diether lipid biomarkers, archaeol, and archaeal tetraethers analogous to those found in carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin, possibly before the onset of seafloor spreading. Lost City-type serpentinization systems have been discovered at midocean ridges, in forearc settings of subduction zones, and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments.
Klein, Frieder; Humphris, Susan E.; Guo, Weifu; Schubotz, Florence; Schwarzenbach, Esther M.; Orsi, William D.
2015-01-01
Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support deep chemolithoautotrophic life in the hydrated oceanic mantle (i.e., serpentinite). However, geosphere-biosphere interactions in serpentinite-hosted subseafloor mixing zones remain poorly constrained. Here we examine fossil microbial communities and fluid mixing processes in the subseafloor of a Cretaceous Lost City-type hydrothermal system at the magma-poor passive Iberia Margin (Ocean Drilling Program Leg 149, Hole 897D). Brucite−calcite mineral assemblages precipitated from mixed fluids ca. 65 m below the Cretaceous paleo-seafloor at temperatures of 31.7 ± 4.3 °C within steep chemical gradients between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity. Dense microbial colonies are fossilized in brucite−calcite veins that are strongly enriched in organic carbon (up to 0.5 wt.% of the total carbon) but depleted in 13C (δ13CTOC = −19.4‰). We detected a combination of bacterial diether lipid biomarkers, archaeol, and archaeal tetraethers analogous to those found in carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin, possibly before the onset of seafloor spreading. Lost City-type serpentinization systems have been discovered at midocean ridges, in forearc settings of subduction zones, and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments. PMID:26324888
NASA Astrophysics Data System (ADS)
Wang, Long; Yu, Min; Liu, Yan; Liu, Jiwen; Wu, Yonghua; Li, Li; Liu, Jihua; Wang, Min; Zhang, Xiao-Hua
2018-04-01
As an ideal place to study back-arc basins and hydrothermal eco-system, Okinawa Trough has attracted the interests of scientists for decades. However, there are still no in-depth studies targeting the bacterial community of the seafloor sediments and hydrothermal deposits in Okinawa Trough. In the present study, we reported the bacterial community of the surface deposits of a newly found hydrothermal field in the southern Okinawa Trough, and the horizontal and vertical variation of bacterial communities in the sediments of the northern Okinawa Trough. The hydrothermal deposits had a relatively high 16S rRNA gene abundance but low bacterial richness and diversity. Epsilonproteobacteria and Bacteroidetes were predominant in hydrothermal deposits whereas Deltaproteobacteria, Gammaproteobacteria and Chloroflexi were abundant across all samples. The bacterial distribution in the seafloor of Okinawa Trough was significantly correlated to the content of total nitrogen, and had consistent relationship with total carbon. Gradual changes of sulfur-oxidizing bacteria were found with the distance away from hydrothermal fields, while the hydrothermal activity did not influence the distribution of the major clades of sulfate-reducing bacteria. Higher abundance of the sulfur cycle related genes (aprA and dsrB), and lower abundance of the bacterial ammonia-oxidizing related gene (amoA) were quantified in hydrothermal deposits. In addition, the present study also compared the inter-field variation of Epsilonproteobacteria among multi-types of hydrothermal vents, revealing that the proportion and diversity of this clade were quite various.
Mobility of rare earth element in hydrothermal process and weathering product: a review
NASA Astrophysics Data System (ADS)
Lintjewas, L.; Setiawan, I.
2018-02-01
The Rare Earth Element (REE), consists of La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Lu, Ho, Er, Tm, Yb, are important elements to be used as raw materials of advanced technology such as semiconductors, magnets, and lasers. The research of REE in Indonesia has not been done. Several researches were conducted on granitic rocks and weathering product such as Bangka, Sibolga, West Kalimantan, West Sulawesi and Papua. REE can be formed by hydrothermal processes such as Bayan Obo, South China. The REE study on active hydrothermal system (geothermal) in this case also has the potential to produce mineral deposits. The purpose of this review paper is to know the mobility of REE on hydrothermal process and weathering products. Mobility of REE in the hydrothermal process can change the distribution patterns and REE content such as Ce, Eu, La, Lu, Nd, Sm, and Y. Another process besides the hydrothermal is weathering process. REE mobility is influenced by weathering products, where the REE will experience residual and secondary enrichment processes in heavier minerals.
Hydrothermal Petroleum in Active Continental Rift: Lake Chapala, Western Mexico, Initial Results.
NASA Astrophysics Data System (ADS)
Zarate-del Valle, P. F.; Simoneit, B. R.; Ramirez-Sanchez, H. U.
2003-12-01
Lake Chapala in western Mexico is located partially in the Citala Rift, which belongs to the well-known neotectonic Jalisco continental triple junction. The region is characterized by active volcanism (Ceboruco, Volcan de Fuego), tectonic (1995 earthquake, M=8, 40-50 mm to SW) and hydrothermal (San Juan Cosala & Villa Corona spas and La Calera sinter deposit) activities. Hydrothermal petroleum has been described in active continental rift (East African Rift) and marine spreading zones (Guaymas Basin, Gulf of California). In 1868 the Mexican local press reported that manifestations of bitumen were appearing in front of the Columba Cap on the mid south shore of Lake Chapala. This bitumen is linked to the lake bottom and when the water level decreases sufficiently it is possible to access these tar bodies as islands. Because of these manifestations the Mexican oil company (PEMEX) drilled an exploration well (2,348m) at Tizapan El Alto without success. Hydrothermal activity is evident in the tar island zone as three in-shore thermal springs (26.8 m depth, 48.5° C, pH 7.8 and oriented N-S). The preliminary analyses by GC-MS of the tar from these islands indicate hydrothermal petroleum derived from lake sedimentary organic matter, generated at low temperatures (150° -200° C). The tars contain no n-alkanes, no PAH or other aromatics, but a major UCM of branched and cyclic hydrocarbons and mature biomarkers derived from lacustrine biota. The biomarkers consist of mainly 17α (H),21β (H)-hopanes ranging from C27 to C34 (no C28), gammacerane, tricyclic terpanes (C20-C26), carotane and its cracking products, and drimanes (C14-C16). The biomarker composition indicates an organic matter source from bacteria and algae, typical of lacustrine ecosystems. 14C dating of samples from two tar islands yielded ages exceeding 40 kyrs, i.e., old carbon from hydrothermal/tectonic remobilization of bitumen from deeper horizons to the surface. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be included as a target in exploration for future energy resources in such regions.
Hein, J.R.; Schulz, M.S.; Dunham, R.E.; Stern, R.J.; Bloomer, S.H.
2008-01-01
Abundant ferromanganese oxides were collected along 1200 km of the active Izu-Bonin-Mariana arc system. Chemical compositions and mineralogy show that samples were collected from two deposit types: Fe-Mn crusts of mixed hydrogenetic/hydrothermal origin and hydrothermal Mn oxide deposits; this paper addresses only the second type. Mn oxides cement volcaniclastic and biogenic sandstone and breccia layers (Mn sandstone) and form discrete dense stratabound layers along bedding planes and within beds (stratabound Mn). The Mn oxide was deposited within coarse-grained sediments from diffuse flow systems where precipitation occurred below the seafloor. Deposits were exposed at the seabed by faulting, mass wasting, and erosion. Scanning electron microscopy and microprobe analyses indicate the presence of both amorphous and crystalline 10 ?? and 7 ?? manganate minerals, the fundamental chemical difference being high water contents in the amorphous Mn oxides. Alternation of amorphous and crystalline laminae occurs in many samples, which likely resulted from initial rapid precipitation of amorphous Mn oxides from waxing pulses of hydrothermal fluids followed by precipitation of slow forming crystallites during waning stages. The chemical composition is characteristic of a hydrothermal origin including strong fractionation between Fe (mean 0.9 wt %) and Mn (mean 48 wt %) for the stratabound Mn, generally low trace metal contents, and very low rare earth element and platinum group element contents. However, Mo, Cd, Zn, Cu, Ni, and Co occur in high concentrations in some samples and may be good indicator elements for proximity to the heat source or to massive sulfide deposits. For the Mn sandstones, Fe (mean-8.4%) and Mn (12.4%) are not significantly fractionated because of high Fe contents in the volcaniclastic material. However, the proportion of hydrothermal Fe (nondetrital Fe) to total Fe is remarkably constant (49-58%) for all the sample groups, regardless of the degree of Mn mineralization. Factor analyses indicate various mixtures of two dominant components: hydrothermal Mn oxide for the stratabound Mn and detrital aluminosilicate for the Mn-cemented sandstone; and two minor components, hydrothermal Fe oxyhydroxide and biocarbonate/biosilica. Our conceptual model shows that Mn mineralization was produced by hydrothermal convection cells within arc volcanoes and sedimentary prisms that occur along, the flanks and within calderas. The main source of hydrothermal fluid was seawater that penetrated through fractures, faults, and permeable volcanic edifices. The fluids were heated by magma, enriched in metals by leaching of basement rocks and sediments, and mixed with magmatic fluids and gases. Dikes and sills may have been another source of heat that drove small-scale circulation within sedimentary prisms. Copyright 2008 by the American Geophysical Union.
NASA Astrophysics Data System (ADS)
Hein, James R.; Schulz, Marjorie S.; Dunham, Rachel E.; Stern, Robert J.; Bloomer, Sherman H.
2008-08-01
Abundant ferromanganese oxides were collected along 1200 km of the active Izu-Bonin-Mariana arc system. Chemical compositions and mineralogy show that samples were collected from two deposit types: Fe-Mn crusts of mixed hydrogenetic/hydrothermal origin and hydrothermal Mn oxide deposits; this paper addresses only the second type. Mn oxides cement volcaniclastic and biogenic sandstone and breccia layers (Mn sandstone) and form discrete dense stratabound layers along bedding planes and within beds (stratabound Mn). The Mn oxide was deposited within coarse-grained sediments from diffuse flow systems where precipitation occurred below the seafloor. Deposits were exposed at the seabed by faulting, mass wasting, and erosion. Scanning electron microscopy and microprobe analyses indicate the presence of both amorphous and crystalline 10 Å and 7 Å manganate minerals, the fundamental chemical difference being high water contents in the amorphous Mn oxides. Alternation of amorphous and crystalline laminae occurs in many samples, which likely resulted from initial rapid precipitation of amorphous Mn oxides from waxing pulses of hydrothermal fluids followed by precipitation of slow forming crystallites during waning stages. The chemical composition is characteristic of a hydrothermal origin including strong fractionation between Fe (mean 0.9 wt %) and Mn (mean 48 wt %) for the stratabound Mn, generally low trace metal contents, and very low rare earth element and platinum group element contents. However, Mo, Cd, Zn, Cu, Ni, and Co occur in high concentrations in some samples and may be good indicator elements for proximity to the heat source or to massive sulfide deposits. For the Mn sandstones, Fe (mean 8.4%) and Mn (12.4%) are not significantly fractionated because of high Fe contents in the volcaniclastic material. However, the proportion of hydrothermal Fe (nondetrital Fe) to total Fe is remarkably constant (49-58%) for all the sample groups, regardless of the degree of Mn mineralization. Factor analyses indicate various mixtures of two dominant components: hydrothermal Mn oxide for the stratabound Mn and detrital aluminosilicate for the Mn-cemented sandstone; and two minor components, hydrothermal Fe oxyhydroxide and biocarbonate/biosilica. Our conceptual model shows that Mn mineralization was produced by hydrothermal convection cells within arc volcanoes and sedimentary prisms that occur along the flanks and within calderas. The main source of hydrothermal fluid was seawater that penetrated through fractures, faults, and permeable volcanic edifices. The fluids were heated by magma, enriched in metals by leaching of basement rocks and sediments, and mixed with magmatic fluids and gases. Dikes and sills may have been another source of heat that drove small-scale circulation within sedimentary prisms.
Evidence for organic synthesis in high temperature aqueous media - facts and prognosis
NASA Technical Reports Server (NTRS)
Simoneit, Bernd R. T.
1995-01-01
Hydrothermal systems are common along the active tectonic areas of the earth. Potential sites being studied for organic matter alteration and possible organic synthesis are spreading ridges, off-axis systems, back-arc activity, hot spots, volcanism, and subduction. Organic matter alteration, primarily reductive and generally from immature organic detritus, occurs in these high temperature and rapid fluid flow hydrothermal regimes. Hot circulating water (temperature range - warm to greater than 400 C) is responsible for these molecular alterations, expulsion and migration. Compounds that are obviously synthesized are minor components because they are generally masked by the pyrolysis products formed from contemporary natural organic precursors. The reactivity of organic compounds in hot water (200-350 C) has been studied in autoclaves, and supercritical water as a medium for chemistry has also been evaluated. This high temperature aqueous organic chemistry and the strong reducing conditions of the natural systems suggest this as an important route to produce organic compounds on the primitive earth. Thus a better understanding of the potential syntheses of organic compounds in hydrothermal systems will require investigations of the chemistry of condensation, autocatalysis, catalysis and hydrolysis reactions in aqueous mineral buffered systems over a range of temperatures from warm to greater than 400 C.
Extensive hydrothermal activity in the NE Lau basin revealed by ROV dives
NASA Astrophysics Data System (ADS)
Embley, R. W.; Resing, J. A.; Tebo, B.; Baker, E. T.; Butterfield, D. A.; Chadwick, B.; Davis, R.; de Ronde, C. E. J.; Lilley, M. D.; Lupton, J. E.; Merle, S. G.; Rubin, K. H.; Shank, T. M.; Walker, S. L.; Arculus, R. J.; Bobbitt, A. M.; Buck, N. J.; Caratori Tontini, F.; Crowhurst, P. V.; Mitchell, E.; Olson, E. J.; Ratmeyer, V.; Richards, S.; Roe, K. K.; Kenner-Chavis, P.; Martinez-Lyons, A.; Sheehan, C.; Brian, R.
2014-12-01
Dives with the QUEST 4000 ROV (Remotely Operated Vehicle) in September 2012 discovered nine hydrothermal sites in the arc and rear-arc region of the NE Lau Basin in 1150 m to 2630 m depth. These sites, originally detected by water column and seafloor surveys conducted in 2008-2011, include: (1) a paired sulfur-rich/black smoker field on the summit of a tectonically deformed magmatic arc volcano (Niua), (2) fracture-controlled black smoker venting on several small en echelon seamounts (north Matas) that lie between the magmatic arc and the backarc spreading center and (3) a magmatic degassing site on the summit of a dacite cone within a large (~12 km diameter) caldera volcano (Niuatahi). Dives at West Mata Seamount, which was undergoing strombolian volcanic activity and effusive rift-zone eruptions from 2008 to 2010, revealed a dormant volcanic phase in September 2012, with continued low-temperature diffuse venting. The high-temperature venting is likely driven by magmatic heat indicative of underlying partial melt zones and/or melt pockets distributed through the region. The occurrence of the youngest known boninite eruptions on the Mata volcanoes is consistent with subduction fluid flux melting extending into the rear-arc zone. Extension related to the transition from subduction to strike-slip motion of the northern Tonga Arc over the active Subduction-Transform Edge Propagator (STEP) fault probably contributes to the enhanced volcanism/hydrothermal activity in the NE Lau Basin. Chemosynthetic ecosystems at these sites range from mostly motile, lower diversity ecosystems at the eruptive/magmatically-degassing sites to higher diversity ecosystems with less mobile faunal components at the black-smoker systems. The wide range of fluid chemistry, water depth and geologic settings of the hydrothermal systems in this area provides an intriguing template to study the interaction of hydrothermal fluid chemistry, chemosynthetic habitats and their geologic underpinning within an arc/backarc setting.
Hyperactive hydrothermal activity in the NE Lau basin revealed by ROV dives
NASA Astrophysics Data System (ADS)
Embley, R. W.; Resing, J. A.; Tebo, B.; Baker, E. T.; Butterfield, D. A.; Chadwick, B.; Davis, R.; de Ronde, C. E.; Lilley, M. D.; Lupton, J. E.; Merle, S. G.; Rubin, K. H.; Shank, T. M.; Walker, S. L.; Arculus, R. J.; Bobbitt, A. M.; Buck, N.; Caratori Tontini, F.; Crowhurst, P. V.; Mitchell, E.; Olson, E. J.; Ratmeyer, V.; Richards, S.; Roe, K. K.; Keener, P.; Martinez Lyons, A.; Sheehan, C.; Brian, R.
2013-12-01
Dives with the QUEST 4000 ROV (Remotely Operated Vehicle) in September 2012 discovered nine hydrothermal sites in the arc and rear-arc region of the NE Lau Basin in 1150 m to 2630 m depth. These sites, originally detected by water column and seafloor surveys conducted in 2008-2011, include: (1) a paired sulfur-rich/black smoker field on the summit of a tectonically deformed magmatic arc volcano (Niua), (2) fracture-controlled black smoker venting on several small en echelon seamounts (north Matas) that lie between the magmatic arc and the backarc spreading center and (3) a magmatic degassing site on the summit of a dacite cone within a large (~12 km diameter) caldera volcano (Niuatahi). Dives at West Mata Seamount, which was undergoing strombolian volcanic activity and effusive rift-zone eruptions from 2008 to 2010, revealed a dormant volcanic phase in September 2012, with continued low-temperature diffuse venting. The high-temperature venting is likely driven by magmatic heat indicative of underlying partial melt zones and/or melt pockets distributed through the region. The occurrence of the youngest known boninite eruptions on the Mata volcanoes is consistent with subduction fluid flux melting extending into the rear-arc zone. Extension related to the transition from subduction to strike-slip motion of the northern Tonga Arc over the active Subduction-Transform Edge Propagator (STEP) fault probably contributes to the enhanced volcanism/hydrothermal activity in the NE Lau Basin. Chemosynthetic ecosystems at these sites range from mostly motile, lower diversity ecosystems at the eruptive/magmatically-degassing sites to higher diversity ecosystems with less mobile faunal components at the black-smoker systems. The wide range of fluid chemistry, water depth and geologic settings of the hydrothermal systems in this area provides an intriguing template to study the interaction of hydrothermal fluid chemistry, chemosynthetic habitats and their geologic underpinning within an arc/backarc setting.
NASA Astrophysics Data System (ADS)
Henri, P. A.; Rommevaux, C.; Lesongeur, F.; Emerson, D.; Leleu, T.; Chavagnac, V.
2015-12-01
Iron-oxidizing bacteria becomes increasingly described in different geological settings from volcanically active seamounts, coastal waters, to diffuse hydrothermal vents near seafloor spreading centers [Emerson et al., 2010]. They have been mostly identified and described in Pacific Ocean, and have been only recently found in hydrothermal systems associated to slow spreading center of the Mid-Atlantic Ridge (MAR) [Scott et al., 2015]. During the MoMARSAT'13 cruise at Lucky Strike hydrothermal field (MAR), a new hydrothermal site was discovered at about 1.5 km eastward from the lava lake and from the main hydrothermal vents. This active venting site, named Capelinhos, is therefore the most distant from the volcano, features many chimneys, both focused and diffuses. The hydrothermal end-member fluids from Capelinhos are different from those of the other sites of Lucky Strike, showing the highest content of iron (Fe/Mn≈3.96) and the lowest chlorinity (270 mmol/l) [Leleu et al., 2015]. Most of the chimneys exhibit rust-color surfaces and bacterial mats near diffuse flows. During the MoMARSAT'15 cruise, an active chimney, a small inactive one, and rust-color bacterial mat near diffuse flow were sampled at Capelinhos. Observations by SEM of the hydrothermal samples revealed the presence of iron oxides in an assemblage of tubular "sheaths", assembled "stalks", helical "stalks" and amorphous aggregates. These features are similar to those described from the Loihi iron-mats deposits and argue for the occurrence of iron-oxidizing bacteria. Cultures under micro-aerobic and neutral pH conditions allowed us to isolate strains from the small inactive chimney. Pyrosequencing of the 16S rRNA gene of the isolates and environmental samples will soon be performed, which should confirm the presence of iron-oxidizing bacteria and reveal the organization of bacterial communities in this original and newly discovered hydrothermal site of the slow spreading Mid-Atlantic Ridge. Emerson, D., et al. (2010), Annu Rev Microbiol, 64(1), 561-583. Leleu, T., et al. (2015), Fluid geochemistry of the Capelinhos Vent Site. A key to understand the Lucky Strike hydrothermal vent field (37°N, MAR), AGU fall meeting Abstract, San Francisco, USA. Scott, J. J.,et al. (2015), PLoS ONE, 10(3), e0119284.
NASA Astrophysics Data System (ADS)
McDermott, J. M.; Seewald, J.; German, C. R.; Sylva, S. P.
2013-12-01
The generation of organic compounds in vent fluids has been of interest since the discovery of seafloor hydrothermal systems, due to implications for the sustenance of present-day microbial populations and their potential role in the origin of life on early Earth. Possible sources of organic compounds in hydrothermal systems include microbial production, thermogenic degradation of organic material, and abiotic synthesis. Abiotic organic synthesis reactions may occur during active circulation of seawater-derived fluids through the oceanic crust or within olivine-hosted fluid inclusions containing carbon-rich magmatic volatiles. H2-rich end-member fluids at the Von Damm vent field on the Mid-Cayman Rise, where fluid temperatures reach 226°C, provide an exciting opportunity to examine the extent of abiotic carbon transformations in a highly reducing system. Our results indicate multiple sources of carbon compounds in vent fluids at Von Damm. An ultramafic-influenced hydrothermal system located on the Mount Dent oceanic core complex at 2350 m depth, Von Damm vent fluids contain H2, CH4, and C2+ hydrocarbons in high abundance relative to basalt-hosted vent fields, and in similar abundance to other ultramafic-hosted systems, such as Rainbow and Lost City. The CO2 content and isotopic composition in end-member fluids are virtually identical to bottom seawater, suggesting that seawater DIC is unchanged during hydrothermal circulation of seawater-derived fluids. Accordingly, end-member CH4 that is present in slightly greater abundance than CO2 cannot be generated from reduction of aqueous CO2 during hydrothermal circulation. We postulate that CH4 and C2+ hydrocarbons that are abundantly present in Von Damm vent fluids reflect leaching of fluids from carbon- and H2-rich fluid inclusions hosted in plutonic rocks. Geochemical modeling of carbon speciation in the Von Damm fluids suggests that the relative abundances of CH4, C2+ hydrocarbons, and CO2 are consistent with thermodynamic equilibrium at higher temperatures and more reducing conditions than those observed in the Von Damm vent fluids. These findings are consistent with a scenario in which n-alkanes form abiotically within a high-H2, carbon-rich olivine-hosted fluid inclusion, and are subsequently liberated and transported to the seafloor during hydrothermal alteration of the lower crustal rocks exposed at the Mount Dent oceanic core complex. Mixed fluids at Von Damm show depletions in CO2 and H2, relative to conservative mixing. Multiple S isotope measurements indicate that the H2 sink cannot be attributed to sulfate reduction. Thermodynamic constraints indicate that high-H2 conditions support the active formation of formate via reduction of dissolved CO2 during hydrothermal circulation - a process that has also been described at the Lost City vent field - and could account for the concurrent depletions in CO2 and H2. The transformation of inorganic carbon to organic compounds via two distinct pathways in modern seafloor hydrothermal vents validates theoretical and experimental conceptual models regarding processes occurring in the crust and during hydrothermal circulation, and is relevant to supporting life in vent ecosystems.
NASA Astrophysics Data System (ADS)
Kleine, B. I.; Stefansson, A.; Halldorsson, S. A.; Martin, W.; Barnes, J.; Jónasson, K.; Franzson, H.
2016-12-01
Magma often encounters groundwater (meteoric or seawater derived) when intruded into the crust. Magma-groundwater interactions result in the formation of hydrothermal fluids which can lead to contact metamorphism and elemental transport in the country rock. In fact, magma-hydrothermal fluid interaction (rather than magma-magmatic fluid interaction) may lead to classic contact metamorphic reactions. In order to explore the importance of hydrothermal fluid during contact metamorphism we use stable isotopes (δD, δ18O, δ30Si) from both active and extinct magma chambers and hydrothermal systems from across Iceland. Quartz grains from various hydrothermal systems, from crustal xenoliths from the Askja central volcano and from the Hafnarfjall pluton, as well as quartz grains associated with low-T zeolites were analysed for δ18O and δ30Si in-situ using SIMS. Whole rock material of these samples was analysed for δD values using a TCEA coupled to an IRMS. Our results indicate that low-T quartz (<150°C) are dominated by negative δ30Si values whereas positive δ30Si values prevail in quartz precipitated at higher T (>300°C). Combining the results from the analyses of δ18O and δD allows further division of samples into (i) seawater and/or rock dominated and (ii) meteoric water dominated hydrothermal systems. In order to isolate the effects of fluid-rock interaction, fluid source and formation temperature at the magma-groundwater contact, δD, δ18O and δ30Si values of rocks and fluids were modeled using the PHREEQC software. Comparison of analytical and model results shows that the isotopic compositions are influenced by multiple processes. In some cases, groundwater penetrates the contact zone and causes alteration at >400°C by groundwater-magma heat interaction. Other cases document "baked" contact zones without groundwater. Our analyses and modeling demonstrates that groundwater flow and permeability are crucial in setting the style of contact metamorphism around high T intrusions.
NASA Astrophysics Data System (ADS)
Bühring, Solveig I.; Amend, Jan P.; Gómez Sáez, Gonzalo V.; Häusler, Stefan; Hinrichs, Kai-Uwe; Pichler, Thomas; Pop Ristova, Petra; Price, Roy E.; Santi, Ioulia; Sollich, Miriam
2014-05-01
The shallow water hydrothermal vents off Milos Island, Greece, discharge hot, slightly acidic, reduced fluids into colder, slightly alkaline, oxygenated seawater. Gradients in temperature, pH, and geochemistry are established as the two fluids mix, leading to the formation of various microbial microniches. In contrast to deep-sea hydrothermal systems, the availability of sun light allows for a combination of photo- and chemotrophic carbon fixation. Despite the comparably easy accessibility of shallow water hydrothermal systems, little is known about their microbial diversity and functioning. We present data from a shallow hydrothermal system off Milos Island, one of the most hydrothermally active regions in the Mediterranean Sea. The physico-chemical changes from ambient seafloor to hydrothermal area were investigated and documented by in situ microsensor profiling of temperature, pH, total reduced sulfur and dissolved oxygen alongside porewater geochemistry. The spatial microbial diversity was determined using a combination of gene- and lipid-based approaches, whereas microbial functioning was assessed by stable isotope probing experiments targeting lipid biomarkers. In situ microprofiles indicated an extreme environment with steep gradients, offering a variety of microniches for metabolically diverse microbial communities. We sampled a transect along a hydrothermal patch, following an increase in sediment surface temperature from background to 90°C, including five sampling points up to 20 cm sediment depth. Investigation of the bacterial diversity using ARISA revealed differences in the community structure along the geochemical gradients, with the least similarity between the ambient and highly hydrothermally impacted sites. Furthermore, using multivariate statistical analyses it was shown that variations in the community structure could be attributed to differences in the sediment geochemistry and especially the sulfide content, and only indirectly to shifts in temperature. Results from intact polar lipid analyses were consistent with the ARISA data and clearly differentiated those samples located close to the vent from those found in less affected areas. Changes from phospho- and betaine lipids within the top layer of the unaffected area to glyco- and ornithine lipids in the hydrothermally influenced sediment layers reflected a change from photoautotrophic algae to a bacteria-dominated community as predominant lipid sources. A clear dominance of archaeal lipids indicated archaea as key players in the deeper, hotter layers of the hydrothermal sediment. We performed stable isotope probing experiments with 13C-bicarbonate in the dark to investigate if chemolithotrophy, as opposed to phototrophy, plays any significant role for carbon fixation in shallow vent systems. Different amendments revealed that not only chemolithotrophy represents an important pathway for carbon fixation in these ecosystems, but that diverse ways of dark CO2 fixation exist, with hydrogen being the most effective electron donor under high temperature conditions.
Structural features related to the volcanic gases in Southern Okinawa Trough
NASA Astrophysics Data System (ADS)
Wang, H. F.; Hsu, S. K.; Tsia, C. H.; Chen, S. C.; Wu, M. F.
2016-12-01
The Okinawa Trough is a rifted back-arc basin, heavily sedimented and formed in an intracontinental rift zone behind the Ryukyu trench-arc system. The Southern Okinawa Trough (SOT) east of Taiwan is the place where post-collisional extension happened. The collision moved southwestward and the Ryukyu trench-arc extension westward, Arc volcanism is dominant in the Northern Ryukyu volcanic arc and back-arc volcanism in the Southern Okinawa Trough. Marine geophysical data including side-scan sonar (SSS), sub-bottom profiler (SBP) and echo sounder system (EK60) data are used in this study. Active fluid activities out of seafloor are obvious from various images observed on these data, such as gas plumes. These hydrothermal vents have been located at a water depth of 1400 m. Our preliminary results show that gas seepage structures appear in the location where is a week zone, such as a normal fault in the slope. The hydrothermal activity within the Okinawa Trough is associated with volcanism located in rift zones in the Southern Okinawa Trough. However, the origin of the submarine hydrothermal fluids within the Okinawa Trough is diverse with contributions from volcanic, sedimentary and magmatic sources, needed further investigations.
Chemical reaction path modeling of hydrothermal processes on Mars: Preliminary results
NASA Technical Reports Server (NTRS)
Plumlee, Geoffrey S.; Ridley, W. Ian
1992-01-01
Hydrothermal processes are thought to have had significant roles in the development of surficial mineralogies and morphological features on Mars. For example, a significant proportion of the Martian soil could consist of the erosional products of hydrothermally altered impact melt sheets. In this model, impact-driven, vapor-dominated hydrothermal systems hydrothermally altered the surrounding rocks and transported volatiles such as S and Cl to the surface. Further support for impact-driven hydrothermal alteration on Mars was provided by studies of the Ries crater, Germany, where suevite deposits were extensively altered to montmorillonite clays by inferred low-temperature (100-130 C) hydrothermal fluids. It was also suggested that surface outflow from both impact-driven and volcano-driven hydrothermal systems could generate the valley networks, thereby eliminating the need for an early warm wet climate. We use computer-driven chemical reaction path calculation to model chemical processes which were likely associated with postulated Martian hydrothermal systems.
Pathways for abiotic organic synthesis at submarine hydrothermal fields.
McDermott, Jill M; Seewald, Jeffrey S; German, Christopher R; Sylva, Sean P
2015-06-23
Arguments for an abiotic origin of low-molecular weight organic compounds in deep-sea hot springs are compelling owing to implications for the sustenance of deep biosphere microbial communities and their potential role in the origin of life. Theory predicts that warm H2-rich fluids, like those emanating from serpentinizing hydrothermal systems, create a favorable thermodynamic drive for the abiotic generation of organic compounds from inorganic precursors. Here, we constrain two distinct reaction pathways for abiotic organic synthesis in the natural environment at the Von Damm hydrothermal field and delineate spatially where inorganic carbon is converted into bioavailable reduced carbon. We reveal that carbon transformation reactions in a single system can progress over hours, days, and up to thousands of years. Previous studies have suggested that CH4 and higher hydrocarbons in ultramafic hydrothermal systems were dependent on H2 generation during active serpentinization. Rather, our results indicate that CH4 found in vent fluids is formed in H2-rich fluid inclusions, and higher n-alkanes may likely be derived from the same source. This finding implies that, in contrast with current paradigms, these compounds may form independently of actively circulating serpentinizing fluids in ultramafic-influenced systems. Conversely, widespread production of formate by ΣCO2 reduction at Von Damm occurs rapidly during shallow subsurface mixing of the same fluids, which may support anaerobic methanogenesis. Our finding of abiogenic formate in deep-sea hot springs has significant implications for microbial life strategies in the present-day deep biosphere as well as early life on Earth and beyond.
Pathways for abiotic organic synthesis at submarine hydrothermal fields
McDermott, Jill M.; Seewald, Jeffrey S.; German, Christopher R.; Sylva, Sean P.
2015-01-01
Arguments for an abiotic origin of low-molecular weight organic compounds in deep-sea hot springs are compelling owing to implications for the sustenance of deep biosphere microbial communities and their potential role in the origin of life. Theory predicts that warm H2-rich fluids, like those emanating from serpentinizing hydrothermal systems, create a favorable thermodynamic drive for the abiotic generation of organic compounds from inorganic precursors. Here, we constrain two distinct reaction pathways for abiotic organic synthesis in the natural environment at the Von Damm hydrothermal field and delineate spatially where inorganic carbon is converted into bioavailable reduced carbon. We reveal that carbon transformation reactions in a single system can progress over hours, days, and up to thousands of years. Previous studies have suggested that CH4 and higher hydrocarbons in ultramafic hydrothermal systems were dependent on H2 generation during active serpentinization. Rather, our results indicate that CH4 found in vent fluids is formed in H2-rich fluid inclusions, and higher n-alkanes may likely be derived from the same source. This finding implies that, in contrast with current paradigms, these compounds may form independently of actively circulating serpentinizing fluids in ultramafic-influenced systems. Conversely, widespread production of formate by ΣCO2 reduction at Von Damm occurs rapidly during shallow subsurface mixing of the same fluids, which may support anaerobic methanogenesis. Our finding of abiogenic formate in deep-sea hot springs has significant implications for microbial life strategies in the present-day deep biosphere as well as early life on Earth and beyond. PMID:26056279
van de Flierdt, T.; Frank, M.; Halliday, A.N.; Hein, J.R.; Hattendorf, B.; Gunther, D.; Kubik, P.W.
2004-01-01
Secular variations in the Pb isotopic composition of a mixed hydrogenous-hydrothermal ferromanganese crust from the Bauer Basin in the eastern Equatorial Pacific provide clear evidence for changes in hydrothermal contributions during the past 7 Myr. The nearby Galapagos Rise spreading center provided a strong hydrothermal flux prior to 6.5 Ma. After 6.5 Ma, the Pb became stepwise more radiogenic and more similar to Equatorial Pacific seawater, reflecting the westward shift of spreading to the presently active East Pacific Rise (EPR). A second, previously unrecognized enhanced hydrothermal period occurred between 4.4 and 2.9 Ma, which reflects either off-axis hydrothermal activity in the Bauer Basin or a late-stage pulse of hydrothermal Pb from the then active, but waning Galapagos Rise spreading center. Hafnium isotope time-series of the same mixed hydrogenous-hydrothermal crust show invariant values over the past 7 Myr. Hafnium isotope ratios, as well as Nd isotope ratios obtained for this crust, are identical to that of hydrogenous Equatorial Pacific deep water crusts and clearly indicate that hydrothermal Hf, similar to Nd, does not travel far from submarine vents. Therefore, we suggest that hydrothermal Hf fluxes do not contribute significantly to the global marine Hf budget. ?? 2004 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Chiodini, Giovanni; Cardellini, Carlo; Lamberti, María Clara; Agusto, Mariano; Caselli, Alberto; Liccioli, Caterina; Tamburello, Giancarlo; Tassi, Franco; Vaselli, Orlando; Caliro, Stefano
2015-10-01
The north-western sector of Caviahue caldera (Argentina), close to the active volcanic system of Copahue, is characterized by the presence of several hydrothermal sites that host numerous fumarolic emissions, anomalous soil diffuse degassing of CO2 and hot soils. In March 2014, measurements of soil CO2 fluxes in 5 of these sites (namely, Las Máquinas, Las Maquinitas I, Las Maquinitas II, Anfiteatro, and Termas de Copahue) allowed an estimation that 165 t of deeply derived CO2 is daily released. The gas source is likely related to a relatively shallow geothermal reservoir containing a single vapor phase as also suggested by both the geochemical data from the 3 deep wells drilled in the 1980s and gas geoindicators applied to the fumarolic discharges. Gas equilibria within the H-C-O gas system indicate the presence of a large, probably unique, single phase vapor zone at 200-210 °C feeding the hydrothermal manifestations of Las Máquinas, Las Maquinitas I and II and Termas de Copahue. A natural thermal release of 107 MW was computed by using CO2 as a tracer of the original vapor phase. The magmatic signature of the incondensable fumarolic gases, the wide expanse of the hydrothermal areas and the remarkable high amount of gas and heat released by fluid expulsion seem to be compatible with an active magmatic intrusion beneath this portion of the Caviahue caldera.
NASA Astrophysics Data System (ADS)
Pearce, R.; Mitchell, T. M.; Moorkamp, M.; Araya, J.; Cembrano, J. M.; Yanez, G. A.; Hammond, J. O. S.
2017-12-01
At convergent plate boundaries, volcanic orogeny is largely controlled by major thrust fault systems that act as magmatic and hydrothermal fluid conduits through the crust. In the south-central Andes, the volcanically and seismically active Tinguiririca and Planchon-Peteroa volcanoes are considered to be tectonically related to the major El Fierro thrust fault system. These large scale reverse faults are characterized by 500 - 1000m wide hydrothermally altered fault cores, which possess a distinct conductive signature relative to surrounding lithology. In order to establish the subsurface architecture of these fault systems, such conductivity contrasts can be detected using the magnetotelluric method. In this study, LEMI fluxgate-magnetometer long-period and Metronix broadband MT data were collected at 21 sites in a 40km2 survey grid that surrounds this fault system and associated volcanic complexes. Multi-remote referencing techniques is used together with robust processing to obtain reliable impedance estimates between 100 Hz and 1,000s. Our preliminary inversion results provide evidence of structures within the 10 - 20 km depth range that are attributed to this fault system. Further inversions will be conducted to determine the approximate depth extent of these features, and ultimately provide constraints for future geophysical studies aimed to deduce the role of these faults in volcanic orogeny and hydrothermal fluid migration processes in this region of the Andes.
NASA Astrophysics Data System (ADS)
Klein, F.; Humphris, S. E.; Guo, W.; Schubotz, F.; Schwarzenbach, E. M.; Orsi, W.
2015-12-01
Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support autotrophic microorganisms in the hydrated oceanic mantle (serpentinite). Despite the potentially significant implications for the distribution of microbial life on Earth and other water-bearing planetary bodies, our understanding of such environments remains elusive. In the present study we examined fossilized microbial communities and fluid mixing processes in the subseafloor of a Cretaceous 'Lost City'-type hydrothermal system at the passive Iberia Margin (ODP Leg 149, Hole 897D). Brucite and calcite co-precipitated from mixed fluids ca. 65m below the Cretaceous palaeo-seafloor at temperatures of 32±4°C within steep chemical gradients (fO2, pH, CH4, SO4, ΣCO2, etc) between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity within the oceanic basement. Dense microbial colonies are fossilized in brucite-calcite veins that are strongly enriched in organic carbon but depleted in 13C. We detected a combination of bacterial diether lipid biomarkers, archaeol and archaeal tetraethers analogous to those found in brucite-carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin during the Cretaceous, possibly before the onset of seafloor spreading in the Atlantic. 'Lost City'-type serpentinization systems have been discovered at mid-ocean ridges, in forearc settings of subduction zones and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments as demonstrated in the present study. Because equivalent systems have likely existed throughout most of Earth's history, fluid mixing may have provided the substrates and energy to support a unique subseafloor community of microorganisms over geological timescales.
NASA Astrophysics Data System (ADS)
Klein, F.; Humphris, S. E.; Guo, W.; Schubotz, F.; Schwarzenbach, E. M.; Orsi, W.
2014-12-01
Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support autotrophic microorganisms in the hydrated oceanic mantle (serpentinite). Despite the potentially significant implications for the distribution of microbial life on Earth and other water-bearing planetary bodies, our understanding of such environments remains elusive. In the present study we examined fossilized microbial communities and fluid mixing processes in the subseafloor of a Cretaceous 'Lost City'-type hydrothermal system at the passive Iberia Margin (ODP Leg 149, Hole 897D). Brucite and calcite co-precipitated from mixed fluids ca. 65m below the Cretaceous palaeo-seafloor at temperatures of 32±4°C within steep chemical gradients (fO2, pH, CH4, SO4, ΣCO2, etc) between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity within the oceanic basement. Dense microbial colonies are fossilized in brucite-calcite veins that are strongly enriched in organic carbon but depleted in 13C. We detected a combination of bacterial diether lipid biomarkers, archaeol and archaeal tetraethers analogous to those found in brucite-carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin during the Cretaceous, possibly before the onset of seafloor spreading in the Atlantic. 'Lost City'-type serpentinization systems have been discovered at mid-ocean ridges, in forearc settings of subduction zones and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments as demonstrated in the present study. Because equivalent systems have likely existed throughout most of Earth's history, fluid mixing may have provided the substrates and energy to support a unique subseafloor community of microorganisms over geological timescales.
Hydrothermal Solute Flux from Ebeko Volcanic Center, Paramushir, Kuril Islands
NASA Astrophysics Data System (ADS)
Taran, Y.; Kalacheva, E.; Kotenko, T.; Chaplygin, I.
2014-12-01
Ebeko volcano on the northern part of Paramushir Island, Northern Kurils, is characterized by frequent phreatic eruptions, a strong low-temperature fumarolic activity at the summit and was the object of comprehensive volcanological and geochemical studies during the last half a century. The volcanic center is composed of several Pleistocene volcanic structures aadjacent to Ebeko and hosts a hydrothermal system with a high outflow rate of hot SO4-Cl acidic water (Upper Yurieva springs) with the current maximum temperature of ~85oC, pH 1.3 and TDS ~ 10 g/L. All discharging thermal waters are drained by the Yurieva River to the Sea of Okhotsk. The hot springs have been changing in time, generally decreasing their activity from near boiling in 1960s, with TDS ~ 20 g/L and the presence of a small steaming field at the upper part of the ~ 700 m long discharging area, to a much lower discharge rate of main vents, lower temperature and the absence of the steaming ground. The spring chemistry did not react to the Ebeko volcanic activity (14 strong phreato-magmatic events during the last 60 years).The total measured outputs of chloride and sulfur from the system last time (2006-2010) were estimated on average as 730 g/s and 980 g/s, respectively, which corresponds to the equivalent fluxes of 64 t/d of HCl and 169 t/d of SO2. These values are higher than the fumarolic volatile output from Ebeko. The estimated discharge rate of hot (85oC) water from the system with ~ 3500 ppm of chloride is about 0.3 m3/s which is much higher than the thermal water discharge from El Chichon or Copahue volcano-hydrothermal systems and among the highest hot water natural outputs ever measured for a volcano-hydrothermal system. We also report the chemical composition (major and ~ 60 trace elements including REE) of water from the main hot spring vents and the Yurieva river mouth.
230Th/238U dating of hydrothermal sulfides from Duanqiao hydrothermal field, Southwest Indian Ridge
NASA Astrophysics Data System (ADS)
Yang, Weifang; Tao, Chunhui; Li, Huaiming; Liang, Jin; Liao, Shili; Long, Jiangping; Ma, Zhibang; Wang, Lisheng
2017-06-01
Duanqiao hydrothermal field is located between the Indomed and Gallieni fracture zones at the central volcano, at 50°28'E in the ultraslow-spreading Southwest Indian Ridge (SWIR). Twenty-eight subsamples from a relict chimney and massive sulfides were dated using the 230Th/238U method. Four main episodes of hydrothermal activity were determined according to the restricted results: 68.9-84.3, 43.9-48.4, 25.3-34.8, and 0.7-17.3 kyrs. Hydrothermal activity of Duanqiao probably started about 84.3 (±0.5) kyrs ago and ceased about 0.737 (±0.023) kyrs ago. The periodic character of hydrothermal activity may be related to the heat source provided by the interaction of local magmatism and tectonism. The estimated mean growth rate of the sulfide chimney is <0.02 mm/yr. This study is the first to estimate the growth rate of chimneys in the SWIR. The maximum age of the relict chimney in Duanqiao hydrothermal filed is close to that of the chimneys from Mt. Jourdanne (70 kyrs). The hydrothermal activity in Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. The massive sulfides are younger than the sulfides from other hydrothermal fields such as Rainbow, Sonne and Ashadze-2. The preliminarily estimated reserves of sulfide ores of Duanqiao are approximately 0.5-2.9 million tons.
NASA Astrophysics Data System (ADS)
Finizola, A.; Ricci, T.; Deiana, R.; Cabusson, S. Barde; Rossi, M.; Praticelli, N.; Giocoli, A.; Romano, G.; Delcher, E.; Suski, B.; Revil, A.; Menny, P.; Di Gangi, F.; Letort, J.; Peltier, A.; Villasante-Marcos, V.; Douillet, G.; Avard, G.; Lelli, M.
2010-09-01
On March 15th 2007 a paroxysmal explosion occurred at the Stromboli volcano. This event generated a large amount of products, mostly lithic blocks, some of which impacted the ground as far as down to 200 m a.s.l., about 1.5 km far away from the active vents. Two days after the explosion, a new vapour emission was discovered on the north-eastern flank of the volcanic edifice, at 560 m a.s.l., just above the area called "Nel Cannestrà". This new vapour emission was due to a block impact. In order to investigate the block impact area to understand the appearance of the vapour emission, we conducted on May 2008 a multidisciplinary study involving Electrical Resistivity Tomography (ERT), Ground Penetrating Radar (GPR), Self-Potential (SP), CO 2 soil diffuse degassing and soil temperature surveys. This complementary data set revealed the presence of an anomalous conductive body, probably related to a shallow hydrothermal level, at about 10-15 m depth, more or less parallel to the topography. It is the first time that such a hydrothermal fluid flow, with a temperature close to the water boiling point (76 °C) has been evidenced at Stromboli at this low elevation on the flank of the edifice. The ERT results suggest a possible link between (1) the main central hydrothermal system of Stromboli, located just above the plumbing system feeding the active vents, with a maximum of subsurface soil temperature close to 90 °C and limited by the NeoStromboli summit crater boundary and (2) the investigated area of Nel Cannestrà, at ~ 500 m a.s.l., a buried eruptive fissure active 9 ka ago. In parallel, SP and CO 2 soil diffuse degassing measurements suggest in this sector at slightly lower elevation from the block impact crater a magmatic and hydrothermal fluid rising system along the N41° regional fault. A complementary ERT profile, on May 2009, carried out from the NeoStromboli crater boundary down to the block impact crater displayed a flank fluid flow apparently connected to a deeper system. The concept of shallow hydrothermal level have been compared to similar ERT results recently obtained on Mount Etna and La Fossa cone of Vulcano. This information needs to be taken into account in general fluid flow models on volcanoes. In particular, peripheral thermal waters (as those bordering the north-eastern coast of Stromboli) could be contaminated by hydrothermal and magmatic fluids coming from regional faults but also from the summit.
NASA Astrophysics Data System (ADS)
Nowacki, Andy; Wilks, Matthew; Kendall, J.-Michael; Biggs, Juliet; Ayele, Atalay
2018-05-01
Geothermal resources are frequently associated with silicic calderas which show evidence of geologically-recent activity. Hence development of geothermal sites requires both an understanding of the hydrothermal system of these volcanoes, as well as the deeper magmatic processes which drive them. Here we use shear wave splitting to investigate the hydrothermal system at the silicic peralkaline volcano Aluto in the Main Ethiopian Rift, which has experienced repeated uplift and subsidence since at least 2004. We make over 370 robust observations of splitting, showing that anisotropy is confined mainly to the top ∼3 km of the volcanic edifice. We find up to 10% shear wave anisotropy (SWA) is present with a maximum centred at the geothermal reservoir. Fast shear wave orientations away from the reservoir align NNE-SSW, parallel to the present-day minimum compressive stress. Orientations on the edifice, however, are rotated NE-SW in a manner we predict from field observations of faults at the surface, providing fluid pressures are sufficient to hold two fracture sets open. These fracture sets may be due to the repeated deformation experienced at Aluto and initiated in caldera formation. We therefore attribute the observed anisotropy to aligned cracks held open by over-pressurised gas-rich fluids within and above the reservoir. This study demonstrates that shear wave splitting can be used to map the extent and style of fracturing in volcanic hydrothermal systems. It also lends support to the hypothesis that deformation at Aluto arises from variations of fluid pressures in the hydrothermal system. These constraints will be crucial for future characterisation of other volcanic and geothermal systems, in rift systems and elsewhere.
A novel hydrogen oxidizer amidst the sulfur-oxidizing Thiomicrospira lineage
Hansen, Moritz; Perner, Mirjam
2015-01-01
Thiomicrospira species are ubiquitously found in various marine environments and appear particularly common in hydrothermal vent systems. Members of this lineage are commonly classified as sulfur-oxidizing chemolithoautotrophs. Although sequencing of Thiomicrospira crunogena's genome has revealed genes that encode enzymes for hydrogen uptake activity and for hydrogenase maturation and assembly, hydrogen uptake ability has so far not been reported for any Thiomicrospira species. We isolated a Thiomicrospira species (SP-41) from a deep sea hydrothermal vent and demonstrated that it can oxidize hydrogen. We show in vivo hydrogen consumption, hydrogen uptake activity in partially purified protein extracts and transcript abundance of hydrogenases during different growth stages. The ability of this strain to oxidize hydrogen opens up new perspectives with respect to the physiology of Thiomicrospira species that have been detected in hydrothermal vents and that have so far been exclusively associated with sulfur oxidation. PMID:25226028
U-Th isotopic systematics and ages of carbonate chimneys at the Lost City Hydrothermal Field
NASA Astrophysics Data System (ADS)
Ludwig, K. A.; Shen, C.; Kelley, D. S.; Cheng, H.; Edwards, R.
2009-12-01
The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th isotopic systematics of hydrothermal fluids and the 230Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples with <15 mmol/kg Mg, 232Th concentration is 0.11 to 0.13 pg/g and surrounding seawater concentration average is 0.133 ± 0.016 pg/g. The 230Th/232Th atomic ratios of the vent fluids range from 1 ± 10 to 26 ± 4 ×10-6 and are less than those of seawater. Chimney U is seawater-derived and 238U concentrations range from 1-10 μg/g and the mean chimney corrected initial δ234U is 146.9 ± 0.5, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate thorium concentrations range broadly from 0.035-125 ng/g and 230Th/232Th atomic ratios vary from near seawater values of 43 ± 8 × 10-6 up to 530 ± 25 × 10-3. Chimney ages range from 18 ± 6 yrs to 122 ± 12 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.
Edmonds, H N; Michael, P J; Baker, E T; Connelly, D P; Snow, J E; Langmuir, C H; Dick, H J B; Mühe, R; German, C R; Graham, D W
2003-01-16
Submarine hydrothermal venting along mid-ocean ridges is an important contributor to ridge thermal structure, and the global distribution of such vents has implications for heat and mass fluxes from the Earth's crust and mantle and for the biogeography of vent-endemic organisms. Previous studies have predicted that the incidence of hydrothermal venting would be extremely low on ultraslow-spreading ridges (ridges with full spreading rates <2 cm x yr(-1)-which make up 25 per cent of the global ridge length), and that such vent systems would be hosted in ultramafic in addition to volcanic rocks. Here we present evidence for active hydrothermal venting on the Gakkel ridge, which is the slowest spreading (0.6-1.3 cm x yr(-1)) and least explored mid-ocean ridge. On the basis of water column profiles of light scattering, temperature and manganese concentration along 1,100 km of the rift valley, we identify hydrothermal plumes dispersing from at least nine to twelve discrete vent sites. Our discovery of such abundant venting, and its apparent localization near volcanic centres, requires a reassessment of the geologic conditions that control hydrothermal circulation on ultraslow-spreading ridges.
NASA Astrophysics Data System (ADS)
Zhang, J.
2016-12-01
There is a high temperature hydrothermal activity area in the western plateau of Sichuan. More than 200 hot springs points have been found in the region, including 11 hot spring water temperature above local boiling point. Most of these distribute along Jinshajjiang fracture, Dege-Xiangcheng fracture, Ganzi-Litang fracture as well as Xianshuihe fracture, and form three high-temperature hydrothermal activity strips in the NW-SE direction. Using gravity, magnetic, seismic and helium isotope data, this paper analyzed the crust-mantle heat flow structure, crustal heat source distribution and water heating system. The results show that the geothermal activity mainly controlled by the "hot" crust. The ratio of crustal heat flow and surface heat flow is higher than 60%. In the high temperature hydrothermal activities area, there is lower S wave velocity zone with Vs<3.2 km/s in 15 30 km depth in middle and lower crust. Basing on the S wave velocity inversion temperature of crust-mantle, it has been found that there is a high temperature layer with 850 1000 ° in 20 40 km depth. It is the main heat source of high temperature hydrothermal activity area of western Sichuan. Our argument is that atmospheric precipitation, surface water infiltrated along the fault fracture into the crustal deep, heating by crustal hot source, and circulation to surface become high temperature hot water. Geothermal water mainly reserve in the Triassic strata of the containing water good carbonate rocks, and in the intrusive granite which is along the fault zone. The thermal energy of Surface heat thermal activities mainly comes from the high-temperature hot source which is located in the middle and lower crust. Being in the deep crustal fracture, the groundwater infiltrated to the deep crust and absorbed heat, then, quickly got back to the surface and formed high hot springs.
NASA Astrophysics Data System (ADS)
Takahashi, Kosuke; Takakura, Shinichi; Matsushima, Nobuo; Fujii, Ikuko
2018-01-01
Hydrothermal activity at Meakandake volcano, Japan, from 2004 to 2014 was investigated by using long-term geomagnetic field observations and audio-frequency magnetotelluric (AMT) surveys. The total intensity of the geomagnetic field has been measured around the summit crater Ponmachineshiri since 1992 by Kakioka Magnetic Observatory. We reanalyzed an 11-year dataset of the geomagnetic total intensity distribution and used it to estimate the thermomagnetic source models responsible for the surface geomagnetic changes during four time periods (2004-2006, 2006-2008, 2008-2009 and 2013-2014). The modeled sources suggest that the first two periods correspond to a cooling phase after a phreatic eruption in 1998, the third one to a heating phase associated with a phreatic eruption in 2008, and the last one to a heating phase accompanying minor internal activity in 2013. All of the thermomagnetic sources were beneath a location on the south side of Ponmachineshiri crater. In addition, we conducted AMT surveys in 2013 and 2014 at Meakandake and constructed a two-dimensional model of the electrical resistivity structure across the volcano. Combined, the resistivity information and thermomagnetic models revealed that the demagnetization source associated with the 2008 eruptive activity, causing a change in magnetic moment about 30 to 50 times greater than the other sources, was located about 1000 m beneath Ponmachineshiri crater, within or below a zone of high conductivity (a few ohm meters), whereas the other three sources were near each other and above this zone. We interpret the conductive zone as either a hydrothermal reservoir or an impermeable clay-rich layer acting as a seal above the hydrothermal reservoir. Along with other geophysical observations, our models suggest that the 2008 phreatic eruption was triggered by a rapid influx of heat into the hydrothermal reservoir through fluid-rich fractures developed during recent seismic swarms. The hydrothermal reservoir remained hot after the 2008 eruption, and heat was sporadically transported upward through its low permeability ceiling.
NASA Astrophysics Data System (ADS)
Gonzales, Katherine; Finizola, Anthony; Lénat, Jean-François; Macedo, Orlando; Ramos, Domingo; Thouret, Jean-Claude; Fournier, Nicolas; Cruz, Vicentina; Pistre, Karine
2014-04-01
Ubinas volcano, the historically most active volcano in Peru straddles a low-relief high plateau and the flank of a steep valley. A multidisciplinary geophysical study has been performed to investigate the internal structure and the fluids flow within the edifice. We conducted 10 self-potential (SP) radial (from summit to base) profiles, 15 audio magnetotelluric (AMT) soundings on the west flank and a detailed survey of SP and soil temperature measurements on the summit caldera floor. The typical “V” shape of the SP radial profiles has been interpreted as the result of a hydrothermal zone superimposed on a hydrogeological zone in the upper parts of the edifice, and depicts a sub-circular SP positive anomaly, about 6 km in diameter. The latter is centred on the summit, and is characterised by a larger extension on the western flank located on the low-relief high plateau. The AMT resistivity model shows the presence of a conductive body beneath the summit at a depth comparable to that of the bottom of the inner south crater in the present-day caldera, where intense hydrothermal manifestations occur. The lack of SP and temperature anomalies on the present caldera floor suggests a self-sealed hydrothermal system, where the inner south crater acts as a pressure release valve. Although no resistivity data exists on the eastern flank, we presume, based on the asymmetry of the basement topography, and the amplitude of SP anomalies on the east flank, which are approximately five fold that on the west flank, that gravitational flow of hydrothermal fluids may occur towards the deep valley of Ubinas. This hypothesis, supported by the presence of hot springs and faults on the eastern foot of the edifice, reinforces the idea that a large part of the southeast flank of the Ubinas volcano may be altered by hydrothermal activity and will tend to be less stable. One of the major findings that stems from this study is that the slope of the basement on which a volcano has grown plays a major role in the geometry of the hydrothermal systems. Another case of asymmetrical composite cone edifice, built on a steep topography, is observed on El Misti volcano (situated 70 km west of Ubinas), which exhibits a similar SP pattern. These types of edifices have a high potential of spreading and sliding along the slope owing to the thicker accumulation of low cohesion and hydrothermally altered volcanic products.
NASA Astrophysics Data System (ADS)
Chiodini, G.; Vilardo, G.; Augusti, V.; Granieri, D.; Caliro, S.; Minopoli, C.; Terranova, C.
2007-12-01
A permanent automatic infrared (IR) station was installed at Solfatara crater, the most active zone of Campi Flegrei caldera. After a positive in situ calibration of the IR camera, we analyze 2175 thermal IR images of the same scene from 2004 to 2007. The scene includes a portion of the steam heated hot soils of Solfatara. The experiment was initiated to detect and quantify temperature changes of the shallow thermal structure of a quiescent volcano such as Solfatara over long periods. Ambient temperature is the main parameter affecting IR temperatures, while air humidity and rain control image quality. A geometric correction of the images was necessary to remove the effects of slow movement of the camera. After a suitable correction the images give a reliable and detailed picture of the temperature changes, over the period October 2004 to January 2007, which suggests that origin of the changes were linked to anthropogenic activity, vegetation growth, and the increase of the flux of hydrothermal fluids in the area of the hottest fumaroles. Two positive temperature anomalies were registered after the occurrence of two seismic swarms which affected the hydrothermal system of Solfatara in October 2005 and October 2006. It is worth noting that these signs were detected in a system characterized by a low level of activity with respect to systems affected by real volcanic crisis where more spectacular results will be expected. Results of the experiment show that this kind of monitoring system can be a suitable tool for volcanic surveillance.
Organic synthesis during fluid mixing in hydrothermal systems
NASA Astrophysics Data System (ADS)
Shock, Everett L.; Schulte, Mitchell D.
1998-12-01
Hydrothermal circulation can lead to fluid mixing on any planet with liquid water and a source of heat. Aqueous fluids with differing compositions, especially different oxidation states, are likely to be far from thermodynamic equilibrium when they mix, and provide a source of free energy that can drive organic synthesis from CO2 and H2, and/or supply a source of geochemical energy to chemolithoautotrophic organisms. Results are presented that quantify the potential for organic synthesis during unbuffered fluid mixing in present submarine hydrothermal systems, as well as hypothetical systems that may have existed on the early Earth and Mars. Dissolved hydrogen, present in submarine hydrothermal fluids owing to the high-temperature reduction of H2O as seawater reacts with oceanic crustal rocks, provides the reduction potential and the thermodynamic drive for organic synthesis from CO2 (or bicarbonate) as hydrothermal fluids mix with seawater. The potential for organic synthesis is a strong function of the H2 content of the hydrothermal fluid, which is, in turn, a function of the prevailing oxidation state controlled by the composition of the rock that hosts the hydrothermal system. Hydrothermal fluids with initial oxidation states at or below those set by the fayalite-magnetite-quartz mineral assemblage show the greatest potential for driving organic synthesis. These calculations show that it is thermodynamically possible for 100% of the carbon in the mixed fluid to be reduced to a mixture of carboxylic acids, alcohols, and ketones in the range 250-50°C as cold seawater mixes with the hydrothermal fluid. As the temperature drops, larger organic molecules are favored, which implies that fluid mixing could drive the geochemical equivalent of a metabolic system. This enormous reduction potential probably drives a large portion of the primary productivity around present seafloor hydrothermal vents and would have been present in hydrothermal systems on the early Earth or Mars. The single largest control on the potential for organic synthesis is the composition of the rock that hosts the hydrothermal system.
NASA Astrophysics Data System (ADS)
John, D. A.; Breit, G. N.; Sisson, T. W.; Vallance, J. W.; Rye, R. O.
2005-12-01
Mount Rainier is the result of episodic stages of edifice growth during periods of high eruptive activity and edifice destruction during periods of relative magmatic quiescence over the past 500 kyr. Edifice destruction occurred both by slow erosion and by catastrophic collapses, some of which were strongly influenced by hydrothermal alteration. Several large-volume Holocene debris-flow deposits contain abundant clasts of hydrothermally altered rocks, most notably the 4-km3 clay-rich Osceola Mudflow which formed by collapse of the northeast side and upper 1000+ m of the edifice about 5600 ya and flowed >120 km downstream into Puget Sound. Mineral assemblages and stable isotope data of hydrothermal alteration products in Holocene debris-flow deposits indicate formation in distinct hydrothermal environments, including magmatic-hydrothermal, steam-heated (including a large fumarolic component), magmatic steam (including a possible fumarolic component), and supergene. The Osceola Mudflow and phreatic components of coeval tephras contain the highest-temperature and inferred most deeply formed alteration minerals; assemblages include magmatic-hydrothermal quartz-alunite, quartz-topaz, quartz-pyrophyllite and quartz-illite (all +pyrite), in addition to steam-heated opal-alunite-kaolinite and abundant smectite-pyrite. In contrast, the Paradise lahar, which formed by a collapse of the surficial upper south side of the edifice, contains only steam-heated assemblages including those formed largely above the water table from condensation of fumarolic vapor (opal-alunite-jarosite). Younger debris-flow deposits on the west side of the volcano (Round Pass lahar and Electron Mudflow) contain only smectite-pyrite alteration, whereas an early 20th century rock avalanche on Tahoma Glacier also contains magmatic-hydrothermal alteration that is exposed in the avalanche headwall of Sunset Amphitheater. Mineralogy and isotopic composition of the alteration phases, geologic and geophysical data, as well as analog fossil hydrothermal systems in volcanoes elsewhere, constrain hydrothermal alteration geometry on the pre-Osceola-collapse edifice of Mount Rainier. Relatively narrow zones of acid magmatic-hydrothermal alteration in the central core of the volcano grade to more widely distributed smectite-pyrite alteration farther out on the upper flanks, capped by steam-heated alteration with a large component of alteration resulting from condensation of fumarolic vapor above the water table. Alteration was polygenetic in zones formed episodically, and was strongly controlled by fluxes of heat and magmatic fluid and by local permeability.
Heat flux from magmatic hydrothermal systems related to availability of fluid recharge
Harvey, M. C.; Rowland, J.V.; Chiodini, G.; Rissmann, C.F.; Bloomberg, S.; Hernandez, P.A.; Mazot, A.; Viveiros, F.; Werner, Cynthia A.
2015-01-01
Magmatic hydrothermal systems are of increasing interest as a renewable energy source. Surface heat flux indicates system resource potential, and can be inferred from soil CO2 flux measurements and fumarole gas chemistry. Here we compile and reanalyze results from previous CO2 flux surveys worldwide to compare heat flux from a variety of magma-hydrothermal areas. We infer that availability of water to recharge magmatic hydrothermal systems is correlated with heat flux. Recharge availability is in turn governed by permeability, structure, lithology, rainfall, topography, and perhaps unsurprisingly, proximity to a large supply of water such as the ocean. The relationship between recharge and heat flux interpreted by this study is consistent with recent numerical modeling that relates hydrothermal system heat output to rainfall catchment area. This result highlights the importance of recharge as a consideration when evaluating hydrothermal systems for electricity generation, and the utility of CO2 flux as a resource evaluation tool.
Hydrothermal plume anomalies over the southwest Indian ridge: magmatic control
NASA Astrophysics Data System (ADS)
Yue, X.; Li, H.; Tao, C.; Ren, J.; Zhou, J.; Chen, J.; Chen, S.; Wang, Y.
2017-12-01
Here we firstly reported the extensive survey results of the hydrothermal activity along the ultra-slow spreading southwest Indian ridge (SWIR). The study area is located at segment 27, between the Indomed and Gallieni transform faults, SWIR. The seismic crustal thickness reaches 9.5km in this segment (Li et al., 2015), which is much thicker than normal crustal. The anomaly thickened crust could be affected by the Crozet hotspot or highly focused melt delivery from the mantle. The Duanqiao hydrothermal field was reported at the ridge valley of the segment by Tao et al (2009). The Deep-towed Hydrothermal Detection System (DHDS) was used to collect information related with hydrothermal activity, like temperature, turbidity, oxidation-reduction potential (ORP) and seabed types. There are 15 survey lines at the interval of 2 to 3 km which are occupied about 1300 km2 in segment 27. After processing the raw data, including wiping out random noise points, 5-points moving average processing and subtracting the ambient, we got anomalous Nephelometric Turbidity Units values (ΔNTU). And dE/dt was used to identify the ORP anomalous as the raw data is easily influenced by electrode potentials drifting (Baker et al., 2016). According to the results of water column turbidity and ORP distributions, we confirmed three hydrothermal anomaly fields named A1, A2 and A3. The three fields are all located in the western part of the segment. The A1 field lies on the ridge valley, west side of Duanqiao field. The A2 and A3 field lie on the northern and southern of the ridge valley, respectively. We propose that recent magmatic activity probably focus on the western part of segment 27.And the extensive distribution of hydrothermal plume in the segment is the result of the discrete magma intrusion. References Baker E T, et al. How many vent fields? New estimates of vent field populations on ocean ridges from precise mapping of hydrothermal discharge locations. EPSL, 2016, 449:186-196. Li J, et al. Seismic observation of an extremely magmatic accretion at the ultraslow spreading Southwest Indian Ridge. GRL, 2015, 42:2656-2663. Tao C, Wu G, Ni J, et al. New hydrothermal fields found along the SWIR during the Legs 5-7 of the Chinese DY115-20 Expedition. AGU 2009.
Aqueous geochemistry of the Thermopolis hydrothermal system, southern Bighorn Basin, Wyoming, U.S.A.
Kaszuba, John P.; Sims, Kenneth W.W.; Pluda, Allison R.
2014-06-01
The Thermopolis hydrothermal system is located in the southern portion of the Bighorn Basin, in and around the town of Thermopolis, Wyoming. It is the largest hydrothermal system in Wyoming outside of Yellowstone National Park. The system includes hot springs, travertine deposits, and thermal wells; published models for the hydrothermal system propose the Owl Creek Mountains as the recharge zone, simple conductive heating at depth, and resurfacing of thermal waters up the Thermopolis Anticline.
Exopolysaccharides Isolated from Hydrothermal Vent Bacteria Can Modulate the Complement System
Courtois, Anthony; Berthou, Christian; Guézennec, Jean
2014-01-01
The complement system is involved in the defence against bacterial infection, or in the elimination of tumour cells. However, disturbances in this system contributes to the pathogenesis of various inflammatory diseases. The efficiency of therapeutic anti-tumour antibodies is enhanced when the complement system is stimulated. In contrast, cancer cells are able to inhibit the complement system and thus proliferate. Some marine molecules are currently being developed as new drugs for use in humans. Among them, known exopolyssacharides (EPSs) generally originate from fungi, but few studies have been performed on bacterial EPSs and even fewer on EPSs extracted from deep-sea hydrothermal vent microbes. For use in humans, these high molecular weight EPSs must be depolymerised. Furthermore, the over-sulphation of EPSs can modify their biological activity. The aim of this study was to investigate the immunodulation of the complement system by either native or over-sulphated low molecular weight EPSs isolated from vent bacteria in order to find pro or anti-activators of complement. PMID:24736648
Discovery of a black smoker vent field and vent fauna at the Arctic Mid-Ocean Ridge
Pedersen, Rolf B.; Rapp, Hans Tore; Thorseth, Ingunn H.; Lilley, Marvin D.; Barriga, Fernando J. A. S.; Baumberger, Tamara; Flesland, Kristin; Fonseca, Rita; Früh-Green, Gretchen L.; Jorgensen, Steffen L.
2010-01-01
The Arctic Mid-Ocean Ridge (AMOR) represents one of the most slow-spreading ridge systems on Earth. Previous attempts to locate hydrothermal vent fields and unravel the nature of venting, as well as the provenance of vent fauna at this northern and insular termination of the global ridge system, have been unsuccessful. Here, we report the first discovery of a black smoker vent field at the AMOR. The field is located on the crest of an axial volcanic ridge (AVR) and is associated with an unusually large hydrothermal deposit, which documents that extensive venting and long-lived hydrothermal systems exist at ultraslow-spreading ridges, despite their strongly reduced volcanic activity. The vent field hosts a distinct vent fauna that differs from the fauna to the south along the Mid-Atlantic Ridge. The novel vent fauna seems to have developed by local specialization and by migration of fauna from cold seeps and the Pacific. PMID:21119639
Stratigraphic development and hydrothermal activity in the central western Cascade Range, Oregon
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cummings, M.L.; Bull, M.K.; Pollock, J.M.
1990-11-10
Two volcanic sequences bounded by erosional unconformities compose the stratigraphy of the North Santiam mining district, Western Cascade Range, Oregon. Diorite, grandodiorite, and leucocratic quartz porphyry dikes, stocks, and sills intrude the breccias, flows, and tuffs of a volcanic center in the older Sardine Formation. Tourmaline-bearing breccia pipes are associated with the porphyritic granodiorite intrusions. An erosional unconformity separates the Sardine Formation from the overlying Elk Lake formation. The alteration patterns in the two formations are consistent with the development of hydrothermal systems during the eruption of each formation. However, the development of the two hydrothermal systems is separated bymore » a period of erosion of the older volcanic pile. Early formation of mineralization that resembles porphyry copper deposits occurred within the Sardine Formation, and later, after eruption of the Elk Lake formation, epithermal veins and alteration developed along faults, fractures, and the margins of dikes in the Sardine Formation.« less
NASA Astrophysics Data System (ADS)
Costa, I. A.; Barriga, F. J.; Fouquet, Y.
2014-12-01
Siliceous hydrothermal breccias were sampled in two Mid-Atlantic Ridge active sites: Lucky Strike and Menez Gwen. These hydrothermal fields are located in the border of the Azorean plateau, southwest of the Azores islands where the alteration processes affecting basaltic rocks are prominent (Costa et al., 2003). The hydrothermal breccias are genetically related with the circulation of low temperature hydrothermal fluids in diffuse vents. The groundmass of these breccias precipitates from the fluid and consolidates the clastic fragments mostly composed of basalt. The main sources are the surrounding volcanic hills. Breccias are found near hydrothermal vents and may play an important role in the protection of subseafloor hydrothermal deposits forming an impermeable cap due to the high content in siliceous material. The amorphous silica tends to precipitate when the fluid is conductively cooled as proposed by Fouquet et al. (1998) after Fournier (1983). The process evolves gradually from an initial stage where we have just the fragments and circulating seawater. The ascending hydrothermal fluid mixes with seawater, which favours the precipitation of the sulphide components. Sealing of the initially loose fragments begins, the temperature rises below this crust, and the processes of mixing fluid circulation and conductive cooling are simultaneous. At this stage the fluid becomes oversaturated with respect to amorphous silica. This form of silica can precipitate in the open spaces of the porous sulphides and seal the system. Normally this can happen at low temperatures. At this stage the hydrothermal breccia is formed creating a progressively less permeable, eventually impermeable cap rock at the surface. Once the fluid is trapped under this impermeable layer, conductive cooling is enhanced and mixing with seawater is restricted, making the precipitation of amorphous silica more efficient. Since the first discovery and description of recent mineralized submarine hydrothermal deposits, comparison with ancient volcanic massive sulphide deposits is appropriate. The proposed model can explain some of the processes taking place in the early phase of formation of old deposits where equivalent siliceous material is found in the hanging wall of the ore bodies (e.g. Barriga and Fyfe, 1988).
Geologic setting of the Snake Pit hydrothermal site: An active vent field on the Mid-Atlantic Ridge
NASA Astrophysics Data System (ADS)
Karson, Jeffrey A.; Brown, Jennifer R.
1988-03-01
The Snake Pit Hydrothermal Site lies on the axis of the Mid-Atlantic Ridge at 23°22' N latitude, about 30 km south of the Kane Transform Intersection. Active ‘black smoker’ vents and a surrounding field of hydrothermal sediment occur at the crest of a laterally extensive neovolcanic ridge. It is one of the first active hydrothermal vent fields to be found on a slow-spreading ridge axis and despite significant differences in its geologic setting from those of the East Pacific Rise, has many similarities to its fast-spreading counterparts. Although preliminary reports have documented many interesting aspects of these vents and their surroundings, new data collected from the manned submersible ALVIN and the deep-towed ANGUS camera system define the regional tectonic setting as well as the local geologic environment of this fascinating area. The Snake Pit vents are located on a local peak of a volcanic constructional ridge at a depth of 3450 m, 700 800 m deeper than vents known from the East Pacific Rise, Galapagos, or Juan de Fuca spreading centers. The vent field is at least 600 m long and up to 200 m wide and is covered by a thick blanket of greenish to yellow-orange hydrothermal sediment. Both active and extinct vents are perched along the crests of steep-sided sulfide mounds that reach heights of over 40 m. High-temperature (350° C) fluids are vented from black smoker chimneys and low-temperature (226° C) fluids seep from sulphide domes and subordinate anhydrite constructions. Water temperatures, flow rates, fluid chemistries, and mineralization are strikingly similar to vents of faster spreading ridge crests; however, a somewhat distinct fauna inhabit the area.
Berndt, M.E.; Seal, R.R.; Shanks, Wayne C.; Seyfried, W.E.
1996-01-01
Hydrogen isotope fractionation factors were measured for coexisting brines and vapors formed by phase separation of NaCl/H2O fluids at temperatures ranging from 399-450??C and pressures from 277-397 bars. It was found that brines are depleted in D compared to coexisting vapors at all conditions studied. The magnitude of hydrogen isotope fractionation is dependent on the relative amounts of Cl in the two phases and can be empirically correlated to pressure using the following relationship: 1000 ln ??(vap-brine) = 2.54(??0.83) + 2.87(??0.69) x log (??P), where ??(vap-brine) is the fractionation factor and ??P is a pressure term representing distance from the critical curve in the NaCl/H2O system. The effect of phase separation on hydrogen isotope distribution in subseafloor hydrothermal systems depends on a number of factors, including whether phase separation is induced by heating at depth or by decompression of hydrothermal fluids ascending to the seafloor. Phase separation in most subseafloor systems appears to be a simple process driven by heating of seawater to conditions within the two-phase region, followed by segregation and entrainment of brine or vapor into a seawater dominated system. Resulting vent fluids exhibit large ranges in Cl concentration with no measurable effect on ??D. Possible exceptions to this include hydrothermal fluids venting at Axial and 9??N on the East Pacific Rise. High ??D values of low Cl fluids venting at Axial are consistent with phase separation taking place at relatively shallow levels in the oceanic crust while negative ??D values in some low Cl fluids venting at 9??N suggest involvement of a magmatic fluid component or phase separation of D-depleted brines derived during previous hydrothermal activity.
Chemical environments of submarine hydrothermal systems
NASA Technical Reports Server (NTRS)
Shock, Everett L.
1992-01-01
Perhaps because black-smoker chimneys make tremendous subjects for magazine covers, the proposal that submarine hydrothermal systems were involved in the origin of life has caused many investigators to focus on the eye-catching hydrothermal vents. In much the same way that tourists rush to watch the spectacular eruptions of Old Faithful geyser with little regard for the hydrology of the Yellowstone basin, attention is focused on the spectacular, high-temperature hydrothermal vents to the near exclusion of the enormous underlying hydrothermal systems. Nevertheless, the magnitude and complexity of geologic structures, heat flow, and hydrologic parameters which characterize the geyser basins at Yellowstone also characterize submarine hydrothermal systems. However, in the submarine systems the scale can be considerably more vast. Like Old Faithful, submarine hydrothermal vents have a spectacular quality, but they are only one fascinating aspect of enormous geologic systems operating at seafloor spreading centers throughout all of the ocean basins. A critical study of the possible role of hydrothermal processes in the origin of life should include the full spectrum of probable environments. The goals of this chapter are to synthesize diverse information about the inorganic geochemistry of submarine hydrothermal systems, assemble a description of the fundamental physical and chemical attributes of these systems, and consider the implications of high-temperature, fluid-driven processes for organic synthesis. Information about submarine hydrothermal systems comes from many directions. Measurements made directly on venting fluids provide useful, but remarkably limited, clues about processes operating at depth. The oceanic crust has been drilled to approximately 2.0 km depth providing many other pieces of information, but drilling technology has not allowed the bore holes and core samples to reach the maximum depths to which aqueous fluids circulate in oceanic crust. Such determinations rely on studies of pieces of deep oceanic crust uplifted by tectonic forces such as along the Southwest Indian Ridge, or more complete sections of oceanic crust called ophiolite sequences which are presently exposed on continents owing to tectonic emplacement. Much of what is thought to happen in submarine hydrothermal systems is inferred from studies of ophiolite sequences, and especially from the better-exposed ophiolites in Oman, Cyprus and North America. The focus of much that follows is on a few general features: pressure, temperature, oxidation states, fluid composition and mineral alteration, because these features will control whether organic synthesis can occur in hydrothermal systems.
First evidence of epithermal gold occurrences in the SE Afar Rift, Republic of Djibouti
NASA Astrophysics Data System (ADS)
Moussa, N.; Fouquet, Y.; Le Gall, B.; Caminiti, A. M.; Rolet, J.; Bohn, M.; Etoubleau, J.; Delacourt, C.; Jalludin, M.
2012-06-01
The geology of the Republic of Djibouti, in the SE Afar Triangle, is characterized by intense tectonic and bimodal volcanic activity that began as early as 25-30 Ma. Each magmatic event was accompanied by hydrothermal activity. Mineralization generally occurs as gold-silver bearing chalcedony veins and is associated with felsic volcanism. Eighty samples from mineralized hydrothermal chalcedony, quartz ± carbonate veins and breccias were studied from ten sites representing four major volcanic events that range in age from early Miocene to the present. The most recent veins are controlled by fractures at the edges of grabens established during the last 4 Myr. Gold in excess of 200 ppb is present in 30% of the samples, with values up to 16 ppm. Mineralogical compositions allowed us to identify different types of mineralization corresponding to different depths in the hydrothermal system: (1) surface and subsurface mineralization characterized by carbonate chimneys, gypsum, silica cap and quartz ± carbonate veins that are depleted in metals and Au; (2) shallow banded chalcedony ± adularia veins related to boiling that contain up to 16 ppm Au, occurring as native gold and electrum with pyrite, and tetradymite; (3) quartz veins with sulfides, and (4) epidote alteration in the deepest hydrothermal zones. Samples in which pyrite is enriched in As tend to have a high Au content. The association with bimodal volcanism, the occurrence of adularia and the native Au and electrum in banded chalcedony veins are typical of epithermal systems and confirm that this type of mineralization can occur in a young intracontinental rift system.
Takai, Ken; Oida, Hanako; Suzuki, Yohey; Hirayama, Hisako; Nakagawa, Satoshi; Nunoura, Takuro; Inagaki, Fumio; Nealson, Kenneth H; Horikoshi, Koki
2004-04-01
Distribution profiles of marine crenarchaeota group I in the vicinity of deep-sea hydrothermal systems were mapped with culture-independent molecular techniques. Planktonic samples were obtained from the waters surrounding two geographically and geologically distinct hydrothermal systems, and the abundance of marine crenarchaeota group I was examined by 16S ribosomal DNA clone analysis, quantitative PCR, and whole-cell fluorescence in situ hybridization. A much higher proportion of marine crenarchaeota group I within the microbial community was detected in deep-sea hydrothermal environments than in normal deep and surface seawaters. The highest proportion was always obtained from the ambient seawater adjacent to hydrothermal emissions and chimneys but not from the hydrothermal plumes. These profiles were markedly different from the profiles of epsilon-Proteobacteria, which are abundant in the low temperatures of deep-sea hydrothermal environments.
Hydrothermal circulation at Mount St. Helens determined by self-potential measurements
Bedrosian, P.A.; Unsworth, M.J.; Johnston, M.J.S.
2007-01-01
The distribution of hydrothermal circulation within active volcanoes is of importance in identifying regions of hydrothermal alteration which may in turn control explosivity, slope stability and sector collapse. Self-potential measurements, indicative of fluid circulation, were made within the crater of Mount St. Helens in 2000 and 2001. A strong dipolar anomaly in the self-potential field was detected on the north face of the 1980-86 lava dome. This anomaly reaches a value of negative one volt on the lower flanks of the dome and reverses sign toward the dome summit. The anomaly pattern is believed to result from a combination of thermoelectric, electrokinetic, and fluid disruption effects within and surrounding the dome. Heat supplied from a cooling dacite magma very likely drives a shallow hydrothermal convection cell within the dome. The temporal stability of the SP field, low surface recharge rate, and magmatic component to fumarole condensates and thermal waters suggest the hydrothermal system is maintained by water vapor exsolved from the magma and modulated on short time scales by surface recharge. ?? 2006 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Del Moro, S.; Di Roberto, A.; Meletlidis, S.; Pompilio, M.; Bertagnini, A.; Agostini, S.; Ridolfi, F.; Renzulli, A.
2015-06-01
On 15 October 2011, a submarine eruption offshore of El Hierro Island gave rise to floating volcanic products, known as xenopumices, i.e., pumiceous xenoliths partly mingled and coated with the juvenile basanitic magma. Over the last few years, no consensus in the scientific community in explaining the origin of these products has been reached. In order to better understand the formation of xenopumice, we present a textural, mineralogical, and geochemical study of the possible magmatic, hydrothermal, and pyrometamorphic processes, which usually operate in the plumbing systems of active volcanoes. We carried out a comprehensive SEM investigation and Sr-Nd-Pb isotope analyses on some samples representative of three different xenopumice facies. All the data were compared with previous studies, new data for El Hierro extrusives and a literature dataset of Canary Islands igneous and sedimentary rocks. In the investigated xenopumices, we emphasize the presence of restitic magmatic phases as well as crystallization of minerals (mainly olivine + pyroxene + magnetite aggregates) as pseudomorphs after pre-existing mafic phenocrysts, providing evidence of pyrometamorphism induced by the high-T juvenile basanitic magma. In addition, we identify veins consisting of zircon + REE-oxides + mullite associated with Si-rich glass and hydrothermal quartz, which indicate the fundamental role played by hydrothermal fluid circulation in the xenopumice protolith. The petrological data agree with a pre-syneruptive formation of the xenopumice, when El Hierro basanite magma intruded hydrothermally altered trachyandesite to trachyte rocks and triggered local partial melting. Therefore, the El Hierro xenopumice represents a snapshot of the transient processes at the magma-wall rock interface, which normally occurs in the feeding system of active volcanoes.
Isotope and fluid inclusion studies of geological and hydrothermal processes, northern Peru
DOE Office of Scientific and Technical Information (OSTI.GOV)
MacFarlane, A.W.; Prol-Ledesma, R.M.; Conrad, M.E.
1994-07-01
Mineralization in the Hualgayoc district of northern Peru occurs in altered Miocene felsic intrusions and in mid-Cretaceous platform sedimentary rocks of the Goyllarisquizga, Inca, and Chulec formations. The ores occur both as stratiform and stratabound pyritiferous base-metal deposits (mantos), and as steeply dipping, sedimentary and intrusive rock-hosted base-metal veins. Igneous rocks in the district are affected by propylytic, sericitic-argillic, sericitic, potassic, and acid-sulfate alteration. K-Ar and Rb-Sr dating and geological evidence indicate multiple stages of intrusive activity and hydrothermal alteration, including close spatial emplacement of two or more separate Miocene magmatic-hydrothermal systems. K-Ar dates on sericite, hydrothermal biotite, and alunitemore » indicate that the most important hydrothermal episodes in the district took place {approx}13.24 and 12.4 Ma. Other K-Ar dates on altered rocks in the district may reflect various amounts of resetting by the emplacement of the 9.05 {+-} 0.2 Ma Hualgayoc rhyodacite. A five-point Rb-Sr isochron for the San Miguel intrusion at Cerro Coymolache yields an age of 45 {+-} 3.4 Ma, which indicates much earlier magmatic activity in this area than recognized previously. Fluid inclusion and paragenetic studies reveal a clear temporal evolution of fluid temperature and chemistry in the San Agustin area at Hualgayoc. Gradually, ore formation shifted to precipitation of vein minerals in the brittle fractures as the mantos became less permeable and were sealed off. Vein formation continued from progressively cooler and more diluted fluids (down to {approx}150{degrees}C and 4.3 wt% NaCl equivalent) as the system waned. No evidence for phase separation is observed in the fluids until the very last paragenetic stage, which contributed no economic mineralization. 53 refs., 15 figs., 7 tabs.« less
The Plumbing System Feeding the Lusi Eruption Revealed by Ambient Noise Tomography
NASA Astrophysics Data System (ADS)
Fallahi, Mohammad Javad; Obermann, Anne; Lupi, Matteo; Karyono, Karyono; Mazzini, Adriano
2017-10-01
Lusi is a sediment-hosted hydrothermal system featuring clastic-dominated geyser-like eruption behavior in East Java, Indonesia. We use 10 months of ambient seismic noise cross correlations from 30 temporary seismic stations to obtain a 3-D model of shear wave velocity anomalies beneath Lusi, the neighboring Arjuno-Welirang volcanic complex, and the Watukosek fault system connecting the two. Our work reveals a hydrothermal plume, rooted at a minimum 6 km depth that reaches the surface at the Lusi site. Furthermore, the inversion shows that this vertical anomaly is connected to the adjacent volcanic complex through a narrow ( 3 km wide) low velocity corridor slicing the survey area at a depth of 4-6 km. The NE-SW direction of this elongated zone matches the strike of the Watukosek fault system. Distinct magmatic chambers are also inferred below the active volcanoes. The large-scale tomography features an exceptional example of a subsurface connection between a volcanic complex and a solitary erupting hydrothermal system hosted in a hydrocarbon-rich back-arc sedimentary basin. These results are consistent with a scenario where deep-seated fluids (e.g., magmas and released hydrothermal fluids) flow along a region of enhanced transmissivity (i.e., the Watukosek fault system damage zone) from the volcanic arc toward the back arc basin where Lusi resides. The triggered metamorphic reactions occurring at depth in the organic-rich sediments generated significant overpressure and fluid upwelling that is today released at the spectacular Lusi eruption site.
NASA Astrophysics Data System (ADS)
Inguaggiato, Salvatore; Mazzini, Adriano; Vita, Fabio; Sciarra, Alessandra
2016-04-01
The Java Island is characterized by an intense volcanic activity with more then 100 active volcanoes. Moreover, this island is also known by the presence of many mud volcanoes and hydrothermal springs. In particular, in the 2006 several sudden hot mud eruptions, with fluids around 100° C, occurred in the NE side of the island resulting in a prominent eruption named Lusi (contraction of Lumpur Sidoarjo) located along the major Watukosek strike-slip fault zone. The Watukosek fault system, strikes from the Arjuno-Welirang volcanic complex, intersects Lusi and extends towards the NE of the Java island. Conversely of the normal mud eruptions (cold fluids emitted in a short time period of few days), the Lusi eruption was characterized by a persistent effusive hot fluids emissions for a long-time period of, so far, nearly a decade. Moreover, the isotopic composition of emitted gases like Helium showed a clear magmatic origin. For this reasons we decided to investigate the near Arjuno-Welirang complex located on the same strike-slip fault. Arjuno-Welirang is a twin strato-volcano system located in the East of Java along the Watukosek fault, at about 25 km SW respect to the Lusi volcano system. It features two main peaks: Arjuno (3339 masl) and Welirang (3156 masl). The last recorded eruptive activity took place in August 1950 from the flanks of Kawah Plupuh and in October 1950 from the NW part of the Gunung Welirang. This strato-volcano is characterized by a S-rich area, with high T-vent fumarole at least up to 220° C (and likely higher), located mainly in the Welirang crater. In addition, several hot springs vent from the flanks of the volcano, indicate the presence of a large hydrothermal system. During July 2015, in the framework of the Lusi Lab project (ERC grant n° 308126), we carried out a geochemical field campaign on the Arjuno-Welirang volcano hydrothermal system area, sampling water and dissolved gases from the thermal and cold springs located on the flanks of the volcano and from two high-T fumaroles located on the summit area of Welirang. Hydrothermal springs reveal temperatures up to 53° C and pH between 6.2 and 8.2. The hydrothermal springs show a volatile content (mainly CO2 and He) that is several order of magnitude higher than the Air Saturated Waters values (ASW) indicating a strong gas/water interaction processes between waters of meteoric origin and deep volatiles of volcanic origin. The hydrothermal springs have dissolved helium isotopic values with clear magmatic signature (R/Ra around 7) that is remarkably close to the helium isotope values from the fumaroles (R/Ra= 7.30). The isotopic composition of helium measured in the fluids emitted from the Lusi mud-volcano around 6.5R/Ra is very similar to the Welirang volcanic fluids indicating the presence of magmatic gases in the Lusi emitted fluids. While the isotopic composition of waters in the Welirang and Lusi fluids are markedly different suggesting a different origin and/or recharge areas for these two hydrothermal systems. These data support the hypothesis that the presence of volcanic gases could have triggered and conveyed the hot and persistent mud fluids emissions of Lusi volcano.
Hydrothermal and tectonic activity in northern Yellowstone Lake, Wyoming
Johnson, S.Y.; Stephenson, W.J.; Morgan, L.A.; Shanks, Wayne C.; Pierce, K.L.
2003-01-01
Yellowstone National Park is the site of one of the world's largest calderas. The abundance of geothermal and tectonic activity in and around the caldera, including historic uplift and subsidence, makes it necessary to understand active geologic processes and their associated hazards. To that end, we here use an extensive grid of high-resolution seismic reflection profiles (???450 km) to document hydrothermal and tectonic features and deposits in northern Yellowstone Lake. Sublacustrine geothermal features in northern Yellowstone Lake include two of the largest known hydrothermal explosion craters, Mary Bay and Elliott's. Mary Bay explosion breccia is distributed uniformly around the crater, whereas Elliott's crater breccia has an asymmetric distribution and forms a distinctive, ???2-km-long, hummocky lobe on the lake floor. Hydrothermal vents and low-relief domes are abundant on the lake floor; their greatest abundance is in and near explosion craters and along linear fissures. Domed areas on the lake floor that are relatively unbreached (by vents) are considered the most likely sites of future large hydrothermal explosions. Four submerged shoreline terraces along the margins of northern Yellowstone Lake add to the Holocene record or postglacial lake-level fluctuations attributed to "heavy breathing" of the Yellowstone magma reservoir and associated geothermal system. The Lake Hotel fault cuts through northwestern Yellowstone Lake and represents part of a 25-km-long distributed extensional deformation zone. Three postglacial ruptures indicate a slip rate of ???0.27 to 0.34 mm/yr. The largest (3.0 m slip) and most recent event occurred in the past ???2100 yr. Although high heat flow in the crust limits the rupture area of this fault zone, future earthquakes of magnitude ???5.3 to 6.5 are possible. Earthquakes and hydrothermal explosions have probably triggered landslides, common features around the lake margins. Few high-resolution seismic reflection surveys have been conducted in lakes in active volcanic areas. Our data reveal active geothermal features with unprecedented resolution and provide important analogues for recognition of comparable features and potential hazards in other subaqueous geothermal environments.
Magnetic exploration of a low-temperature ultramafic-hosted hydrothermal site (Lost City, 30°N, MAR)
NASA Astrophysics Data System (ADS)
Szitkar, Florent; Tivey, Maurice A.; Kelley, Deborah S.; Karson, Jeffrey A.; Früh-Green, Gretchen L.; Denny, Alden R.
2017-03-01
A 2003 high-resolution magnetic survey conducted by the Autonomous Underwater Vehicle ABE over the low-temperature, ultramafic-hosted hydrothermal field Lost City reveals a weak positive magnetic anomaly. This observation is in direct contrast to recent observations of strong positive magnetic anomalies documented over the high-temperature ultramafic-hosted hydrothermal vents fields Rainbow and Ashadze, which indicates that temperature may control the production of magnetization at these sites. The Lost City survey provides a unique opportunity to study a field that is, to date, one of a kind, and is an end member of ultramafic-hosted hydrothermal systems. Our results highlight the key contribution of temperature on magnetite production resulting from serpentinization reactions. Whereas high temperature promotes significant production and partitioning of iron into magnetite, low temperature favors iron partitioning into various alteration phases, resulting in a magnetite-poor rock. Moreover, the distribution of magnetic anomalies confirms results of a previous geological survey indicating the progressive migration of hydrothermal activity upslope. These discoveries contribute to the results of 25 yrs of magnetic exploration of a wide range of hydrothermal sites, from low- to high-temperature and from basalt- to ultramafic-hosted, and thereby validate using high-resolution magnetics as a crucial parameter for locating and characterizing hydrothermal sites hosting unique chemosynthetic-based ecosystems and potentially mineral-rich deposits.
Near-Seafloor Magnetic Exploration of Submarine Hydrothermal Systems in the Kermadec Arc
NASA Astrophysics Data System (ADS)
Caratori Tontini, F.; de Ronde, C. E. J.; Tivey, M.; Kinsey, J. C.
2014-12-01
Magnetic data can provide important information about hydrothermal systems because hydrothermal alteration can drastically reduce the magnetization of the host volcanic rocks. Near-seafloor data (≤70 m altitude) are required to map hydrothermal systems in detail; Autonomous Underwater Vehicles (AUVs) are the ideal platform to provide this level of resolution. Here, we show the results of high-resolution magnetic surveys by the ABE and Sentry AUVs for selected submarine volcanoes of the Kermadec arc. 3-D magnetization models derived from the inversion of magnetic data, when combined with high resolution seafloor bathymetry derived from multibeam surveys, provide important constraints on the subseafloor geometry of hydrothermal upflow zones and the structural control on the development of seafloor hydrothermal vent sites as well as being a tool for the discovery of previously unknown hydrothermal sites. Significant differences exist between the magnetic expressions of hydrothermal sites at caldera volcanoes ("donut" pattern) and cones ("Swiss cheese" pattern), respectively. Subseafloor 3-D magnetization models also highlight structural differences between focused and diffuse vent sites.
Heavy metals from Kueishantao shallow-sea hydrothermal vents, offshore northeast Taiwan
NASA Astrophysics Data System (ADS)
Chen, Xue-Gang; Lyu, Shuang-Shuang; Garbe-Schönberg, Dieter; Lebrato, Mario; Li, Xiaohu; Zhang, Hai-Yan; Zhang, Ping-Ping; Chen, Chen-Tung Arthur; Ye, Ying
2018-04-01
Shallow water hydrothermal vents are a source of heavy metals leading to their accumulation in marine organisms that manage to live under extreme environmental conditions. This is the case at Kueishantao (KST) shallow-sea vents system offshore northeast Taiwan, where the heavy metal distribution in vent fluids and ambient seawater is poorly understood. This shallow vent is an excellent natural laboratory to understand how heavy and volatile metals behave in the nearby water column and ecosystem. Here, we investigated the submarine venting of heavy metals from KST field and its impact on ambient surface seawater. The total heavy metal concentrations in the vent fluids and vertical plumes were 1-3 orders of magnitude higher than the overlying seawater values. When compared with deep-sea hydrothermal systems, the estimated KST end-member fluids exhibited much lower concentrations of transition metals (e.g., Fe and Mn) but comparable concentrations of toxic metals such as Pb and As. This may be attributed to the lower temperature of the KST reaction zone and transporting fluids. Most of the heavy metals (Fe, Mn, As, Y, and Ba) in the plumes and seawater mainly originated from hydrothermal venting, while Cd and Pb were largely contributed by external sources such as contaminated waters (anthropogenic origin). The spatial distribution of heavy metals in the surface seawater indicated that seafloor venting impacts ambient seawater. The measurable influence of KST hydrothermal activity, however, was quite localized and limited to an area of < 1 km2. The estimated annual fluxes of heavy metals emanating from the yellow KST hydrothermal vent were: 430-2600 kg Fe, 24-145 kg Mn, 5-32 kg Ba, 10-60 kg As, 0.3-1.9 kg Cd, and 2-10 kg Pb. This study provides important data on heavy metals from a shallow-sea hydrothermal field, and it helps to better understand the environmental impact of submarine shallow hydrothermal venting.
NASA Astrophysics Data System (ADS)
Arnulf, A. F.; Harding, A. J.; Kent, G. M.
2016-12-01
The Endeavour segment is a 90 km-long, medium-spreading-rate, oceanic spreading center located on the northern Juan de Fuca ridge (JDFR). The central part of this segment forms a 25-km-long volcanic high that hosts five of the most hydrothermally active vent fields on the MOR system, namely (from north to south): Sasquatch, Salty Dawg, High Rise, Main Endeavour and Mothra. Mass, heat and chemical fluxes associated to vigorous hydrothermal venting are large, however the geometry of the fluid circulation system through the oceanic crust remains almost completely undefined. To produce high-resolution velocity/reflectivity structures along the axis of the Endeavour segment, here, we combined a synthetic ocean bottom experiment (SOBE), 2-D traveltime tomography, 2D elastic full waveform and reverse time migration (RTM). We present velocity and reflectivity sections along Endeavour segment at unprecedented spatial resolutions. We clearly image a set of independent, geometrically complex, elongated low-velocity regions linking the top of the magma chamber at depth to the hydrothermal vent fields on the seafloor. We interpret these narrow pipe-like units as focused regions of hydrothermal fluid up-flow, where acidic and corrosive fluids form pipe-like alteration zones as previously observed in Cyprus ophiolites. Furthermore, the amplitude of these low-velocity channels is shown to be highly variable, with the strongest velocity drops observed at Main Endeavour, Mothra and Salty Dawg hydrothermal vent fields, possibly suggesting more mature hydrothermal cells. Interestingly, the near-seafloor structure beneath those three sites is very similar and highlights a sharp lateral transition in velocity (north to south). On the other hand, the High-Rise hydrothermal vent field is characterized by several lower amplitudes up-flow zones and relatively slow near-surface velocities. Last, Sasquatch vent field is located in an area of high near-surface velocities and is not characterized by an obvious low-velocity up-flow region, in good agreement with an extinct vent field.
NASA Astrophysics Data System (ADS)
Lazo, Jonathan; Basualto, Daniel; Bengoa, Cintia; Cardona, Carlos; Franco, Luis; Gil-Cruz, Fernando; Hernández, Erasmo; Lara, Luis; Lundgren, Paul; Medina, Roxana; Morales, Sergio; Peña, Paola; Quijada, Jonathan; Samsonov, Sergey; San Martin, Juan; Valderrama, Oscar
2015-04-01
Temporal and spatial variations of b-value have been interpreted as regional stress changes on active tectonic zones or magma ascent and/or hydrothermal fluids mobilization that could affect to active volcanic arc. Increasing of fluids pressure, medium heterogeneities or temperature changes would be the cause of these variations. The Copahue volcano is a shield strato-volcano that has been edified on the western margin of the Caviahue Caldera, located in the international border between Chile and Argentina, which contain an important geothermic field and is located at a horse-tail structure of the Liquiñe-Ofqui Fault Zone. The pre-fracture nature of its basement, as well as an extensive geothermic field, would be producing very complex conditions to fluids movement that could be exploring to use the 'b' value of the recorded seismicity between 2012 and 2014. Based in the database of VT seismic events, we used 2.073 events to calculate the b-value to obtain the 2D and 3D distribution maps. Results showed two anomalous zones: the first one located 9 Km to NE of the active crater, 3-6 Km depth, with high b-values (>1.2) that is associated with a very high production rate of small earthquakes that could suggest a brittle zone, located in the active geothermal field. The second zone, showed a low b-values (~ 0.7), located to east of the volcano edifice at <3 Km depth, associated to a zone where were generated larger magnitude events, suggesting a zone with more stress accumulation that well correlated with the deformation center detected by InSAR measurements. This zone could be interpreted as the magmatic source that interacts with the shallow hydrothermal system. Thus, in a very complex setting as a volcano sitting on top of a geothermal system, the b-value offers a tool to understand the distribution of the seismic sources and hence a physical constrain for the coupled magmatic/hydrothermal system.
Fractures, Faults, and Hydrothermal Systems of Puna, Hawaii, and Montserrat, Lesser Antilles
NASA Astrophysics Data System (ADS)
Kenedi, Catherine Lewis
The focus of this work is to use geologic and geophysical methods to better understand the faults and fracture systems at Puna, in southeastern Hawaii, and southern Montserrat, in the Lesser Antilles. The particular interest is understanding and locating the deep fracture networks that are necessary for fluid circulation in hydrothermal systems. The dissertation first presents a study in which identification of large scale faulting places Montserrat into a tectonic context. Then follow studies of Puna and Montserrat that focus on faults and fractures of the deep hydrothermal systems. The first chapter consists of the results of the SEA-CALIPSO experiment seismic reflection data, recorded on a 48 channel streamer with the active source as a 2600 in3 airgun. This chapter discusses volcaniclastic debris fans off the east coast of Montserrat and faults off the west coast. The work places Montserrat in a transtensional environment (influenced by oblique subduction) as well as in a complex local stress regime. One conclusion is that the stress regime is inconsistent with the larger arc due to the influence of local magmatism and stress. The second chapter is a seismic study of the Puna hydrothermal system (PHS) along the Kilauea Lower East Rift Zone. The PHS occurs at a left step in the rift, where a fracture network has been formed between fault segments. It is a productive geothermal field, extracting steam and reinjecting cooled, condensed fluids. A network of eight borehole seismometers recorded >6000 earthquakes. Most of the earthquakes are very small (< M.2), and shallow (1-3 km depth), likely the result of hydrothermal fluid reinjection. Deeper earthquakes occur along the rift as well as along the south-dipping fault plane that originates from the rift zone. Seismic methods applied to the PHS data set, after the initial recording, picking, and locating earthquakes, include a tomographic inversion of the P-wave first arrival data. This model indicates a high seismic velocity under the field that is thought to be an intrusion and the heat source of the hydrothermal system. A shear wave splitting study suggested the PHS fracture system is largely oriented rift-parallel with some orthogonal fractures. Shear wave splitting data also were used in a tomographic inversion for fracture density. The fracture density is high in the PHS, which indicates high permeability and potential for extensive fluid circulation. This has been confirmed by high fluid flow and energy generation. The high fracture density is consistent with the interpretation of a transfer zone between the rift segments where a fracture mesh would be expected. In Puna the transfer zone is a relay ramp. The results from the PHS are used as an example to examine the proposed hydrothermal system at St. George's Hill, Montserrat. In southern Montserrat, hot springs and fumaroles suggest a deep hydrothermal system heated by local magmatism. A magnetotelluric study obtained resistivity data that suggest focused alteration under southeastern Montserrat that is likely to be along fault segments. Several faults intersect under SGH, making it the probable center of the hydrothermal system. At Puna, and also Krafla, Iceland, where faults interact is an area of increased permeability, acting as a model to be applied to southern Montserrat. The conclusion is that in both Puna and Montserrat large faults interact to produce local areas of stress transfer that lead to fracturing and permeable networks; these networks allow for high-temperature hydrothermal circulation.
Whakaari (White Island volcano, New Zealand): Magma-hydrothermal laboratory
NASA Astrophysics Data System (ADS)
Lavallee, Yan; Heap, Michael J.; Reuschle, Thierry; Mayer, Klaus; Scheu, Bettina; Gilg, H. Albert; Kennedy, Ben M.; Letham-Brake, Mark; Jolly, Arthur; Dingwell, Donald B.
2015-04-01
Whakaari, active andesitic stratovolcano of the Taupo Volcanic Zone (New Zealand), hosts an open, highly reactive hydrothermal system in the amphitheatre of an earlier sector collapse. Its recent volcanic activity is primarily characterized by sequences of steam-driven (phreatic) and phreatomagmatic explosive eruptions, although a lava dome briefly extruded in 2012. The volcano provides a natural laboratory for the study of aggressive fluids on the permeability of the hydrothermal system, on phreatomagmatic volcanism as well as on the volcano edifice structural stability. Here, we present a holistic experimental dataset on the reservoir rocks properties (mineralogy, permeability, seismic velocity) and their response to changes in stress (strength, deformation mechanisms, fragmentation) and temperature (mineralogical breakdown). We show that the advance degree of alteration in the system, nearly replaced all the original rock-forming minerals. This alteration has produced generally weak rocks, which, when subjected to a differential stress, can undergo transition from a dilatant response (brittle) to a compactant response with a mere confining pressure of about 15-20 MPa (corresponding to depth of about 1 km). Thermal stressing experiments reveal that the alteration phases breakdown at 500 °C (alunite) and 700 °C (dehydrated alum and sulphur), generating much weakened skeletal rocks, deteriorated by a mass loss of 20 wt.%, resulting in an increase in porosity and permeability of about 15 vol.% and an order of magnitude, respectively. Novel thermal stressing tests at high-heating rates (<1000 K/min) suggest that the onset of this mineralogical debilitation is pushed to higher temperatures with heating rates, carrying implication for the stability of the reservoir rocks and explosions during magma movement at variable rates in the upper edifice. Rock strength imposes an important control on the stability of volcanic edifices and of the hydrothermal reservoir rocks, especially when considering the high potential energy stored as fluids in these porous rocks. Recent unrest at Whakaari has resulted in the near sudden generation of phreatomagmatic activity. Here, we complete our experimental description of these rocks by discussing the result of rapid decompression experiments on the rocks stoked with supercritical fluids. The results constrain the violence of these steam-driven events and highlight the predisposition of thermally unstable rocks in hydrothermal system to undergo sudden phreatic eruptions.
Diverse styles of submarine venting on the ultra-slow spreading Mid-Cayman Rise (Invited)
NASA Astrophysics Data System (ADS)
German, C. R.; Bowen, A.; Coleman, M. L.; Honig, D. L.; Huber, J. A.; Jakuba, M.; Kinsey, J. C.; Kurz, M. D.; Leroy, S.; McDermott, J.; Mercier de Lepinay, B. F.; Nakamura, K.; Seewald, J.; Smith, J.; Sylva, S.; van Dover, C. L.; Whitcomb, L. L.; Yoerger, D. R.
2010-12-01
Thirty years after the first discovery of high-temperature submarine venting, the vast majority of the global Mid Ocean Ridge remains unexplored for hydrothermal activity. Of particular interest are the world’s ultra-slow spreading ridges which were the last to be demonstrated to host high-temperature venting, but may host systems particularly relevant to pre-biotic chemistry and the origins of life. Here we report first evidence for diverse and very deep hydrothermal vents along the ~110 km long, ultra-slow spreading Mid-Cayman Rise collected using a combination of CTD-rosette operations and dives of the Hybrid Remotely Operated Vehicle (HROV) Nereus in 2009 followed by shore based work-up of samples for geochemical and microbiological analyses. Our data indicate that the Mid-Cayman Rise hosts at least three discrete hydrothermal sites, each representing a different type of water-rock interaction, including both mafic and ultra-mafic systems and, at ~5000 m, the deepest known hydrothermal vent. Although submarine hydrothermal circulation, in which seawater percolates through and reacts with host lithologies, occurs on all mid-ocean ridges, the diversity of vent-types identified here and their relative geographic isolation make the Mid-Cayman Rise unique in the oceans. These new sites offer prospects for: an expanded range of vent-fluid compositions; varieties of abiotic organic chemical synthesis and extremophile microorganisms; and unparalleled faunal biodiversity - all in close proximity.
NASA Astrophysics Data System (ADS)
Gomila, Rodrigo; Arancibia, Gloria; Mitchell, Thomas M.; Cembrano, Jose M.; Faulkner, Daniel R.
2016-02-01
Understanding fault zone permeability and its spatial distribution allows the assessment of fluid-migration leading to precipitation of hydrothermal minerals. This work is aimed at unraveling the conditions and distribution of fluid transport properties in fault zones based on hydrothermally filled microfractures, which reflect the ''frozen-in'' instantaneous advective hydrothermal activity and record palaeopermeability conditions of the fault-fracture system. We studied the Jorgillo Fault, an exposed 20 km long, left-lateral strike-slip fault, which juxtaposes Jurassic gabbro against metadiorite belonging to the Atacama Fault System in northern Chile. Tracings of microfracture networks of 19 oriented thin sections from a 400 m long transect across the main fault trace was carried out to estimate the hydraulic properties of the low-strain fault damagezone, adjacent to the high-strain fault core, by assuming penny-shaped microfractures of constant radius and aperture within an anisotropic fracture system. Palaeopermeability values of 9.1*10-11 to 3.2*10-13 m2 in the gabbro and of 5.0*10-10 to 1.2*10-13 m2 in the metadiorite were determined, both decreasing perpendicularly away from the fault core. Fracture porosity values range from 40.00% to 0.28%. The Jorgillo Fault has acted as a left-lateral dilational fault-bend, generating large-scale dilation sites north of the JF during co-seismic activity.
NASA Astrophysics Data System (ADS)
Rouxel, Olivier; Toner, Brandy; Germain, Yoan; Glazer, Brian
2018-01-01
Low-temperature hydrothermal vents, such as those encountered at Loihi Seamount, harbor abundant microbial communities and provide ideal systems to test hypotheses on biotic versus abiotic formation of hydrous ferric oxide (FeOx) deposits at the seafloor. Hydrothermal activity at Loihi Seamount produces abundant microbial mats associated with rust-colored FeOx deposits and variably encrusted with Mn-oxyhydroxides. Here, we applied Fe isotope systematics together with major and trace element geochemistry to study the formation mechanisms and preservation of such mineralized microbial mats. Iron isotope composition of warm (<60 °C), Fe-rich and H2S-depleted hydrothermal fluids yielded δ56Fe values near +0.1‰, indistinguishable from basalt values. Suspended particles in the vent fluids and FeOx deposits recovered nearby active vents yielded systematically positive δ56Fe values. The enrichment in heavy Fe isotopes between +1.05‰ and +1.43‰ relative to Fe(II) in vent fluids suggest partial oxidation of Fe(II) during mixing of the hydrothermal fluid with seawater. By comparing the results with experimentally determined Fe isotope fractionation factors, we determined that less than 20% of Fe(II) is oxidized within active microbial mats, although this number may reach 80% in aged or less active deposits. These results are consistent with Fe(II) oxidation mediated by microbial processes considering the expected slow kinetics of abiotic Fe oxidation in low oxygen bottom water at Loihi Seamount. In contrast, FeOx deposits recovered at extinct sites have distinctly negative Fe-isotope values down to -1.77‰ together with significant enrichment in Mn and occurrence of negative Ce anomalies. These results are best explained by the near-complete oxidation of an isotopically light Fe(II) source produced during the waning stage of hydrothermal activity under more oxidizing conditions. Light Fe isotope values of FeOx are therefore generated by subsurface precipitation of isotopically heavy Fe-oxides rather than by the activity of dissimilatory Fe reduction in the subsurface. Overall, Fe-isotope compositions of microbial mats at Loihi Seamount display a remarkable range between -1.2‰ and +1.6‰ which indicate that Fe isotope compositions of hydrothermal Fe-oxide precipitates are particularly sensitive to local environmental conditions where they form, and are less sensitive to abiotic versus biotic origins. It follows that FeOx deposits at Loihi Seamount provides important modern analogues for ancient seafloor Fe-rich deposits allowing for testing hypotheses about the biogeochemical cycling of Fe isotopes on early Earth.
An authoritative global database for active submarine hydrothermal vent fields
NASA Astrophysics Data System (ADS)
Beaulieu, Stace E.; Baker, Edward T.; German, Christopher R.; Maffei, Andrew
2013-11-01
The InterRidge Vents Database is available online as the authoritative reference for locations of active submarine hydrothermal vent fields. Here we describe the revision of the database to an open source content management system and conduct a meta-analysis of the global distribution of known active vent fields. The number of known active vent fields has almost doubled in the past decade (521 as of year 2009), with about half visually confirmed and others inferred active from physical and chemical clues. Although previously known mainly from mid-ocean ridges (MORs), active vent fields at MORs now comprise only half of the total known, with about a quarter each now known at volcanic arcs and back-arc spreading centers. Discoveries in arc and back-arc settings resulted in an increase in known vent fields within exclusive economic zones, consequently reducing the proportion known in high seas to one third. The increase in known vent fields reflects a number of factors, including increased national and commercial interests in seafloor hydrothermal deposits as mineral resources. The purpose of the database now extends beyond academic research and education and into marine policy and management, with at least 18% of known vent fields in areas granted or pending applications for mineral prospecting and 8% in marine protected areas.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jia, Li-Ping; Zhang, Qiang; State Key Laboratory of Pollution Control and Resource Reuse
Graphical abstract: Lanthanide ions doped bare earth rare earth fluoride nanocrystals are synthesized by hydrothermal technology and characterized. The down/up-conversion luminescence of them are discussed. - Highlights: • Mixed hydrothermal system H{sub 2}O–OA (EDA)–O-A(LO-A) is used for synthesis. • Barium rare earth fluoride nanocrystals are synthesized comprehensively. • Luminescence for down-conversion and up-conversion are obtained for these systems. - Abstract: Mixed hydrothermal system H{sub 2}O–OA (EDA)–O-A(LO-A) is developed to synthesize barium rare earth fluorides nanocrystals (OA = oleylamine, EDA = ethylenediamine, O-A = oleic acid and LO-A = linoleic acid). They are presented as BaREF{sub 5} (RE = Ce, Pr,more » Nd, Eu, Gd, Tb, Dy, Y, Tm, Lu) and Ba{sub 2}REF{sub 7} (RE = La, Sm, Ho, Er, Yb). The influence of reaction parameters (rare earth species, hydrothermal system and temperature) is checked on the phase and shape evolution of the fluoride nanocrystals. It is found that reaction time and temperature of these nanocrystals using EDA (180 °C, 6 h) is lower than those of them using OA (220 °C, 10 h). The photoluminescence properties of these fluorides activated by some rare earth ions (Nd{sup 3+}, Eu{sup 3+}, Tb{sup 3+}) are studied, and especially up-conversion luminescence of the four fluoride nanocrystal systems (Ba{sub 2}LaF{sub 7}:Yb, Tm(Er), Ba{sub 2}REF{sub 7}:Yb, Tm(Er) (RE = Gd, Y, Lu)) is observed.« less
NASA Astrophysics Data System (ADS)
Miller, Craig A.; Currenti, Gilda; Hamling, Ian; Williams-Jones, Glyn
2018-05-01
Fluid transfer and ground deformation at hydrothermal systems occur both as a precursor to, or as a result of, an eruption. Typically studies focus on pre-eruption changes to understand the likelihood of unrest leading to eruption; however, monitoring post-eruption changes is important for tracking the return of the system towards background activity. Here we describe processes occurring in a hydrothermal system following the 2012 eruption of Upper Te Maari crater on Mt Tongariro, New Zealand, from observations of microgravity change and deformation. Our aim is to assess the post-eruption recovery of the system, to provide a baseline for long-term monitoring. Residual microgravity anomalies of up to 92 ± 11 μGal per year are accompanied by up to 0.037 ± 0.01 m subsidence. We model microgravity changes using analytic solutions to determine the most likely geometry and source location. A multiobjective inversion tests whether the gravity change models are consistent with the observed deformation. We conclude that the source of subsidence is separate from the location of mass addition. From this unusual combination of observations, we develop a conceptual model of fluid transfer within a condensate layer, occurring in response to eruption-driven pressure changes. We find that depressurisation drives the evacuation of pore fluid, either exiting the system completely as vapour through newly created vents and fumaroles, or migrating to shallower levels where it accumulates in empty pore space, resulting in positive gravity changes. Evacuated pores then collapse, causing subsidence. In addition we find that significant mass addition occurs from influx of meteoric fluids through the fractured hydrothermal seal. Long-term combined microgravity and deformation monitoring will allow us to track the resealing and re-pressurisation of the hydrothermal system and assess what hazard it presents to thousands of hikers who annually traverse the volcano, within 2 km of the eruption site.
Frouin, Eléonore; Bes, Méline; Ollivier, Bernard; Quéméneur, Marianne; Postec, Anne; Debroas, Didier; Armougom, Fabrice; Erauso, Gaël
2018-01-01
The Bay of Prony, South of New Caledonia, represents a unique serpentinite-hosted hydrothermal field due to its coastal situation. It harbors both submarine and intertidal active sites, discharging hydrogen- and methane-rich alkaline fluids of low salinity and mild temperature through porous carbonate edifices. In this study, we have extensively investigated the bacterial and archaeal communities inhabiting the hydrothermal chimneys from one intertidal and three submarine sites by 16S rRNA gene amplicon sequencing. We show that the bacterial community of the intertidal site is clearly distinct from that of the submarine sites with species distribution patterns driven by only a few abundant populations, affiliated to the Chloroflexi and Proteobacteria phyla. In contrast, the distribution of archaeal taxa seems less site-dependent, as exemplified by the co-occurrence, in both submarine and intertidal sites, of two dominant phylotypes of Methanosarcinales previously thought to be restricted to serpentinizing systems, either marine (Lost City Hydrothermal Field) or terrestrial (The Cedars ultrabasic springs). Over 70% of the phylotypes were rare and included, among others, all those affiliated to candidate divisions. We finally compared the distribution of bacterial and archaeal phylotypes of Prony Hydrothermal Field with those of five previously studied serpentinizing systems of geographically distant sites. Although sensu stricto no core microbial community was identified, a few uncultivated lineages, notably within the archaeal order Methanosarcinales and the bacterial class Dehalococcoidia (the candidate division MSBL5) were exclusively found in a few serpentinizing systems while other operational taxonomic units belonging to the orders Clostridiales, Thermoanaerobacterales , or the genus Hydrogenophaga , were abundantly distributed in several sites. These lineages may represent taxonomic signatures of serpentinizing ecosystems. These findings extend our current knowledge of the microbial diversity inhabiting serpentinizing systems and their biogeography.
NASA Astrophysics Data System (ADS)
German, C. R.; von Damm, K. L.
2003-12-01
What is Hydrothermal Circulation?Hydrothermal circulation occurs when seawater percolates downward through fractured ocean crust along the volcanic mid-ocean ridge (MOR) system. The seawater is first heated and then undergoes chemical modification through reaction with the host rock as it continues downward, reaching maximum temperatures that can exceed 400 °C. At these temperatures the fluids become extremely buoyant and rise rapidly back to the seafloor where they are expelled into the overlying water column. Seafloor hydrothermal circulation plays a significant role in the cycling of energy and mass between the solid earth and the oceans; the first identification of submarine hydrothermal venting and their accompanying chemosynthetically based communities in the late 1970s remains one of the most exciting discoveries in modern science. The existence of some form of hydrothermal circulation had been predicted almost as soon as the significance of ridges themselves was first recognized, with the emergence of plate tectonic theory. Magma wells up from the Earth's interior along "spreading centers" or "MORs" to produce fresh ocean crust at a rate of ˜20 km3 yr-1, forming new seafloor at a rate of ˜3.3 km2 yr-1 (Parsons, 1981; White et al., 1992). The young oceanic lithosphere formed in this way cools as it moves away from the ridge crest. Although much of this cooling occurs by upward conduction of heat through the lithosphere, early heat-flow studies quickly established that a significant proportion of the total heat flux must also occur via some additional convective process (Figure 1), i.e., through circulation of cold seawater within the upper ocean crust (Anderson and Silbeck, 1981). (2K)Figure 1. Oceanic heat flow versus age of ocean crust. Data from the Pacific, Atlantic, and Indian oceans, averaged over 2 Ma intervals (circles) depart from the theoretical cooling curve (solid line) indicating convective cooling of young ocean crust by circulating seawater (after C. A. Stein and S. Stein, 1994). The first geochemical evidence for the existence of hydrothermal vents on the ocean floor came in the mid-1960s when investigations in the Red Sea revealed deep basins filled with hot, salty water (40-60 °C) and underlain by thick layers of metal-rich sediment (Degens and Ross, 1969). Because the Red Sea represents a young, rifting, ocean basin it was speculated that the phenomena observed there might also prevail along other young MOR spreading centers. An analysis of core-top sediments from throughout the world's oceans ( Figure 2) revealed that such metalliferous sediments did, indeed, appear to be concentrated along the newly recognized global ridge crest (Boström et al., 1969). Another early indication of hydrothermal activity came from the detection of plumes of excess 3He in the Pacific Ocean Basin (Clarke et al., 1969) - notably the >2,000 km wide section in the South Pacific ( Lupton and Craig, 1981) - because 3He present in the deep ocean could only be sourced through some form of active degassing of the Earth's interior, at the seafloor. (62K)Figure 2. Global map of the (Al+Fe+Mn):Al ratio for surficial marine sediments. Highest ratios mimic the trend of the global MOR axis (after Boström et al., 1969). One area where early heat-flow studies suggested hydrothermal activity was likely to occur was along the Galapagos Spreading Center in the eastern equatorial Pacific Ocean (Anderson and Hobart, 1976). In 1977, scientists diving at this location found hydrothermal fluids discharging chemically altered seawater from young volcanic seafloor at elevated temperatures up to 17 °C ( Edmond et al., 1979). Two years later, the first high-temperature (380±30 °C) vent fluids were found at 21° N on the East Pacific Rise (EPR) (Spiess et al., 1980) - with fluid compositions remarkably close to those predicted from the lower-temperature Galapagos findings ( Edmond et al., 1979). Since that time, hydrothermal activity has been found at more than 40 locations throughout the Pacific, North Atlantic, and Indian Oceans (e.g., Van Dover et al., 2002) with further evidence - from characteristic chemical anomalies in the ocean water column - of its occurrence in even the most remote and slowly spreading ocean basins ( Figure 3), from the polar seas of the Southern Ocean (German et al., 2000; Klinkhammer et al., 2001) to the extremes of the ice-covered Arctic ( Edmonds et al., 2003). (61K)Figure 3. Schematic map of the global ridge crest showing the major ridge sections along which active hydrothermal vents have already been found (red circles) or are known to exist from the detection of characteristic chemical signals in the overlying water column (orange circles). Full details of all known hydrothermally active sites and plume signals are maintained at the InterRidge web-site: http://triton.ori.u-tokyo.ac.jp/~intridge/wg-gdha.htm The most spectacular manifestation of seafloor hydrothermal circulation is, without doubt, the high-temperature (>400 °C) "black smokers" that expel fluids from the seafloor along all parts of the global ocean ridge crest. In addition to being visually compelling, vent fluids also exhibit important enrichments and depletions when compared to ambient seawater. Many of the dissolved chemicals released from the Earth's interior during venting precipitate upon mixing with the cold, overlying seawater, generating thick columns of black metal-sulfide and oxide mineral-rich smoke - hence the colloquial name for these vents: "black smokers" (Figure 4). In spite of their common appearance, high-temperature hydrothermal vent fluids actually exhibit a wide range of temperatures and chemical compositions, which are determined by subsurface reaction conditions. Despite their spectacular appearance, however, high-temperature vents may only represent a small fraction - perhaps as little as 10% - of the total hydrothermal heat flux close to ridge axes. A range of studies - most notably along the Juan de Fuca Ridge (JdFR) in the NE Pacific Ocean (Rona and Trivett, 1992; Schultz et al., 1992; Ginster et al., 1994) have suggested that, instead, axial hydrothermal circulation may be dominated by much lower-temperature diffuse flow exiting the seafloor at temperatures comparable to those first observed at the Galapagos vent sites in 1977. The relative importance of high- and low-temperature hydrothermal circulation to overall ocean chemistry remains a topic of active debate. (141K)Figure 4. (a) Photograph of a "black smoker" hydrothermal vent emitting hot (>400 °C) fluid at a depth of 2,834 m into the base of the oceanic water column at the Brandon vent site, southern EPR. The vent is instrumented with a recording temperature probe. (b) Diffuse flow hydrothermal fluids have temperatures that are generally <35 °C and, therefore, may host animal communities. This diffuse flow site at a depth of 2,500 m on the EPR at 9°50' N is populated by Riftia tubeworms, mussels, crabs, and other organisms. While most studies of seafloor hydrothermal systems have focused on the currently active plate boundary (˜0-1 Ma crust), pooled heat-flow data from throughout the world's ocean basins (Figure 1) indicate that convective heat loss from the oceanic lithosphere actually continues in crust from 0-65 Ma in age ( Stein et al., 1995). Indeed, most recent estimates would indicate that hydrothermal circulation through this older (1-65 Ma) section, termed "flank fluxes," may be responsible for some 70% or more of the total hydrothermal heat loss associated with spreading-plate boundaries - either in the form of warm (20-65 °C) altered seawater, or as cooler water, which is only much more subtly chemically altered ( Mottl, 2003).When considering the impact of hydrothermal circulation upon the chemical composition of the oceans and their underlying sediments, however, attention returns - for many elements - to the high-temperature "black smoker" systems. Only here do many species escape from the seafloor in high abundance. When they do, the buoyancy of the high-temperature fluids carries them hundreds of meters up into the overlying water column as they mix and eventually form nonbuoyant plumes containing a wide variety of both dissolved chemicals and freshly precipitated mineral phases. The processes active within these dispersing hydrothermal plumes play a major role in determining the net impact of hydrothermal circulation upon the oceans and marine geochemistry.
U-Th systematics and 230Th ages of carbonate chimneys at the Lost City Hydrothermal Field
NASA Astrophysics Data System (ADS)
Ludwig, Kristin A.; Shen, Chuan-Chou; Kelley, Deborah S.; Cheng, Hai; Edwards, R. Lawrence
2011-04-01
The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th systematics of hydrothermal fluids and the 230Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples containing only 2-21% ambient seawater (1.1-11 mmol/kg Mg), Th concentration is 0.11-0.13 pg/g and surrounding seawater concentrations average 0.133 ± 0.016 pg/g. The 230Th/ 232Th atomic ratios of the vent fluids range from 1 (±10) × 10 -6 to 11 (±5) × 10 -6, are less than those of seawater, and indicate that the vent fluids may contribute a minor amount of non-radiogenic 230Th to the LCHF carbonate chimney deposits. Chimney 238U concentrations range from 1 to 10 μg/g and the average chimney corrected initial δ 234U is 147.2 ± 0.8, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate 232Th concentrations range broadly from 0.0038 ± 0.0003 to 125 ± 16 ng/g and 230Th/ 232Th atomic ratios vary from near seawater values of 43 (±8) × 10 -6 up to 530 (±25) × 10 -3. Chimney ages, corrected for initial 230Th, range from 17 ± 6 yrs to 120 ± 13 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.
A seismological perspective of the shallow magma and hydrothermal systems under Kilauea Caldera
NASA Astrophysics Data System (ADS)
Chouet, B. A.; Dawson, P. B.
2011-12-01
The past 20 years have seen great strides in our understanding of Kilauea Volcano, in large part due to technological developments and improvements in seismological instrumentation, which now allow the surface effects of subterranean volcanic processes to be imaged in unprecedented detail. High-resolution tomography provided an image of 3D velocity anomalies down to a scale of a few hundred meters, providing indirect evidence for the presence of reservoirs under the summit region of Kilauea. A sharper image of a shallow hydrothermal reservoir under Kilauea Caldera was obtained from frequency-slowness analyses of long-period (LP) seismicity recorded on three small-aperture seismic antennas deployed in the summit caldera. Located within the top 500 m below the caldera floor and extending ~0.6 km and ~1 km in the east-west and north-south directions, this hydrothermal reservoir broadly overlaps the east wall of the Halemaumau pit crater. Further evidence of hydrothermal processes within this zone was obtained from a study of a well-recorded LP event, indicating a source mechanism consistent with the resonance of a horizontal steam-filled crack at a depth of ~150 m near the eastern rim of Halemaumau. Recurring very-long-period (VLP) signals originating in the repeated activation of a compact source region near sea level immediately beneath this hydrothermal reservoir have allowed a gradually emerging view of the shallowest segment of the magma transport pathway under the caldera. Further elaboration of our image of the magma pathway structure, made possible through detailed modeling of VLP signals accompanying degassing activity at a new vent formed in Halemaumau in March 2008, points to a dominant dike segment in the form of a nearly vertical east-trending dike. The inferred dike features a ~20° clockwise rotation in strike under the east edge of Halemaumau, where it intersects a sub-vertical north-striking dike. The triple junction made by the intersection of the west and east branches of the east-trending dike with the north-striking dike provides a natural locus for strong localized elastic coupling of pressure and momentum changes induced by shallow degassing bursts. This juncture offers a ready explanation for the observed temporal stability of the VLP source location. Radial semblance analyses of VLP seismic energy in near real time, supplemented with spectral analyses and Hidden Markov Model (HMM) pattern recognition of degassing bursts provide valuable tools for monitoring the evolution of this active magmatic system and its interaction with the perched hydrothermal system.
Giovannelli, Donato; d'Errico, Giuseppe; Manini, Elena; Yakimov, Michail; Vetriani, Costantino
2013-01-01
Studies of shallow-water hydrothermal vents have been lagging behind their deep-sea counterparts. Hence, the importance of these systems and their contribution to the local and regional diversity and biogeochemistry is unclear. This study analyzes the bacterial community along a transect at the shallow-water hydrothermal vent system of Milos island, Greece. The abundance and biomass of the prokaryotic community is comparable to areas not affected by hydrothermal activity and was, on average, 1.34 × 10(8) cells g(-1). The abundance, biomass and diversity of the prokaryotic community increased with the distance from the center of the vent and appeared to be controlled by the temperature gradient rather than the trophic conditions. The retrieved 16S rRNA gene fragments matched sequences from a variety of geothermal environments, although the average similarity was low (94%), revealing previously undiscovered taxa. Epsilonproteobacteria constituted the majority of the population along the transect, with an average contribution to the total diversity of 60%. The larger cluster of 16S rRNA gene sequences was related to chemolithoautotrophic Sulfurovum spp., an Epsilonproteobacterium so far detected only at deep-sea hydrothermal vents. The presence of previously unknown lineages of Epsilonproteobacteria could be related to the abundance of organic matter in these systems, which may support alternative metabolic strategies to chemolithoautotrophy. The relative contribution of Gammaproteobacteria to the Milos microbial community increased along the transect as the distance from the center of the vent increased. Further attempts to isolate key species from these ecosystems will be critical to shed light on their evolution and ecology.
Giovannelli, Donato; d'Errico, Giuseppe; Manini, Elena; Yakimov, Michail; Vetriani, Costantino
2013-01-01
Studies of shallow-water hydrothermal vents have been lagging behind their deep-sea counterparts. Hence, the importance of these systems and their contribution to the local and regional diversity and biogeochemistry is unclear. This study analyzes the bacterial community along a transect at the shallow-water hydrothermal vent system of Milos island, Greece. The abundance and biomass of the prokaryotic community is comparable to areas not affected by hydrothermal activity and was, on average, 1.34 × 108 cells g−1. The abundance, biomass and diversity of the prokaryotic community increased with the distance from the center of the vent and appeared to be controlled by the temperature gradient rather than the trophic conditions. The retrieved 16S rRNA gene fragments matched sequences from a variety of geothermal environments, although the average similarity was low (94%), revealing previously undiscovered taxa. Epsilonproteobacteria constituted the majority of the population along the transect, with an average contribution to the total diversity of 60%. The larger cluster of 16S rRNA gene sequences was related to chemolithoautotrophic Sulfurovum spp., an Epsilonproteobacterium so far detected only at deep-sea hydrothermal vents. The presence of previously unknown lineages of Epsilonproteobacteria could be related to the abundance of organic matter in these systems, which may support alternative metabolic strategies to chemolithoautotrophy. The relative contribution of Gammaproteobacteria to the Milos microbial community increased along the transect as the distance from the center of the vent increased. Further attempts to isolate key species from these ecosystems will be critical to shed light on their evolution and ecology. PMID:23847607
Major off-axis hydrothermal activity on the northern Gorda Ridge
Rona, Peter A.; Denlinger, Roger P.; Fisk, M. R.; Howard, K. J.; Taghon, G. L.; Klitgord, Kim D.; McClain, James S.; McMurray, G. R.; Wiltshire, J. C.
1990-01-01
The first hydrothermal field on the northern Gorda Ridge, the Sea Cliff hydrothermal field, was discovered and geologic controls of hydrothermal activity in the rift valley were investigated on a dive series using the DSV Sea Cliff. The Sea Cliff hydrothermal field was discovered where predicted at the intersection of axis-oblique and axis-parallel faults at the south end of a linear ridge at mid-depth (2700 m) on the east wall. Preliminary mapping and sampling of the field reveal: a setting nested on nearly sediment-free fault blocks 300 m above the rift valley floor 2.6 km from the axis; a spectrum of venting types from seeps to black smokers; high conductive heat flow estimated to be equivalent to the convective flux of multiple black smokers through areas of the sea floor sealed by a caprock of elastic breccia primarily derived from basalt with siliceous cement and barite pore fillings; and a vent biota with Juan de Fuca Ridge affinites. These findings demonstrate the importance of off-axis hydrothermal activity and the role of the intersection of tectonic lineations in controlling hydrothermal sites at sea-floor spreading centers.
NASA Astrophysics Data System (ADS)
Boulart, Cédric; Briais, Anne; Chavagnac, Valérie; Révillon, Sidonie; Ceuleneer, Georges; Donval, Jean-Pierre; Guyader, Vivien; Barrere, Fabienne; Ferreira, Nicolas; Hanan, Barry; Hémond, Christophe; Macleod, Sarah; Maia, Marcia; Maillard, Agnès.; Merkuryev, Sergey; Park, Sung-Hyun; Ruellan, Etienne; Schohn, Alexandre; Watson, Sally; Yang, Yun-Seok
2017-07-01
Using a combined approach of seafloor mapping, MAPR and CTD survey, we report evidence for active hydrothermal venting along the 130°-140°E section of the poorly-known South-East Indian Ridge (SEIR) from the Australia-Antarctic Discordance (AAD) to the George V Fracture Zone (FZ). Along the latter, we report Eh and CH4 anomalies in the water column above a serpentinite massif, which unambiguously testify for ultramafic-related fluid flow. This is the first time that such circulation is observed on an intermediate-spreading ridge. The ridge axis itself is characterized by numerous off-axis volcanoes, suggesting a high magma supply. The water column survey indicates the presence of at least ten distinct hydrothermal plumes along the axis. The CH4:Mn ratios of the plumes vary from 0.37 to 0.65 denoting different underlying processes, from typical basalt-hosted to ultramafic-hosted high-temperature hydrothermal circulation. Our data suggest that the change of mantle temperature along the SEIR not only regulates the magma supply, but also the hydrothermal activity. The distribution of hydrothermal plumes from a ridge segment to another implies secondary controls such as the presence of fractures and faults along the axis or in the axial discontinuities. We conclude from these results that hydrothermal activity along the SEIR is controlled by magmatic processes at the regional scale and by the tectonics at the segment scale, which influences the type of hydrothermal circulation and leads to various chemical compositions. Such variety may impact global biogeochemical cycles, especially in the Southern Ocean where hydrothermal venting might be the only source of nutrients.
Living with the Heat. Submarine Ring of Fire--Grades 5-6. Hydrothermal Vent Ecology.
ERIC Educational Resources Information Center
National Oceanic and Atmospheric Administration (DOC), Rockville, MD.
This activity is designed to teach about hydrothermal vent ecology. Students are expected to describe how hydrothermal vents are formed and characterize the physical conditions at these sites, explain chemosynthesis and contrast this process with photosynthesis, identify autotrophic bacteria as the basis for food webs in hydrothermal vent…
Rediscovery and Exploration of Magic Mountain, Explorer Ridge, NE Pacific
NASA Astrophysics Data System (ADS)
Embley, R. W.
2002-12-01
A two-part exploration program at Explorer Ridge, the northernmost spreading segment of the NE Pacific spreading centers, was conducted in two phases during June to August of 2002. A robust hydrothermal system (Magic Mountain) was found in this area in the early 1980s by the Canadian PISCES IV submersible, but its dimensions and geologic relationships were not well determined due to limited dives and poor navigation. The first part of the 2002 exploration program utilized an EM300 multibeam sonar on T. G. Thompson, the autonomous vehicle ABE, and a CTD/rosette system to map the seafloor and conduct hydrothermal plume surveys. While ABE conducted detailed surveys in the area where the most intense hydrothermal plume was found on the initial CTD survey, the T. G. Thompson conducted additional multibeam surveys, CTD casts and CTD tow-yos on the other second order segments up to 60 km away. This increased the efficiency of the expedition by at least 30%. After 12 days on site, a multibeam map was completed of the entire segment, the spatial distribution and character of the hydrothermal plumes were mapped out and a section of seafloor measuring 2 x 5.5 km was mapped in detail with ABE. The ABE used two sonar systems, a previously proven Imagenex pencil beam sonar, and, for the first time, a multibeam sonar (SM2000). In addition to the high-resolution bathymetry (1 m grid-cell size resolution for the SM2000), ABE collected temperature, optical backscatter, eH redox potential, and magnetic field data. Using the CTD and ABE data, a major hydrothermal system was easily located on the seafloor during the second part of the exploration program using the ROPOS remotely operated vehicle. The Magic Mountain hydrothermal system is located almost entirely on the eastern constructional shoulder of the ridge eastward of the rim of the eastern boundary fault of the axial valley. This is in contrast to most other hydrothermal systems on intermediate rate spreading ridges, which are either centered within the neovolcanic zone or associated with a boundary fault. The active venting occurs over at least 400 m along axis and is mostly concentrated in clusters of high temperature chimneys, each about 50 m in diameter. Two of these clusters have a basal sulfide mound. There is obvious structural control of many of the vents - many lie along or in line with distinct fissures or small faults and the entire field appears to have developed within a shallow graben formed on the ridge flank. Most of the chimneys consist of relatively friable sulfates (barite/anhydrite) that vent clear fluid at up to about 290°C. Several larger active chimneys consist primarily of sulfide minerals that emit gray smoke with temperatures as high as 312§ C. Biologic communities were primarily associated with the more stable sulfide structures. The mixture of proven technology used from a capable surface vessel during the 2002 Explorer Ridge program, including a cutting edge deep AUV and a large ROV, provided the tools to explore a little-known site at a full range of scales in a short amount of time and collect invaluable samples for research. These initial data sets from the 2002 exploration program set the stage for more detailed studies of this unique hydrothermal system in the future.
Modeling Hydrothermal Activity on Enceladus
NASA Astrophysics Data System (ADS)
Stamper, T., Jr.; Farough, A.
2017-12-01
Cassini's mass spectrometer data and gravitational field measurements imply water-rock interactions around the porous core of Enceladus. Using such data we characterize global heat and fluid transport properties of the core and model the ongoing hydrothermal activity on Enceladus. We assume that within the global ocean beneath the surface ice, seawater percolates downward into the core where it is heated and rises to the oceanfloor where it emanates in the form of diffuse discharge. We utilize the data from Hsu et al., [2015] with models of diffuse flow in seafloor hydrothermal systems by Lowell et al., [2015] to characterize the global heat transport properties of the Enceladus's core. Based on direct observations the gravitational acceleration (g) is calculated 0.123 m s-2. We assume fluid's density (ρ) is 103 kg m-3 and the specific heat of the fluid (cf) is 4000 Jkg-1 °C-1. From these values effective thermal diffusivity (a*) is calculated as 10-6 m2 s-1. We also assume the coefficient of thermal expansion of fluid (αf) and the kinematic viscosity of fluid (ν) to be 10-4 °C-1 and 10-6 m2 s-1 respectively. The estimated Rayleigh number (Ra) ranges between 0.11-2468.0, for core porosity (φ) of 5-15%, permeability (k) between 10-12-10-8 m2 and temperature between 90-200 °C and the depth of fluid circulation of 100 m. High values of Rayleigh number, cause vigorous convection within the core of Enceladus. Numerical modeling of reactive transport in multicomponent, multiphase systems is required to obtain a full understanding of the characteristics and evolution of the hydrothermal system on Enceladus, but simple scaling laws can provide insight into the physics of water-rock interactions.
NASA Astrophysics Data System (ADS)
Minami, H.; Ohara, Y.
2017-09-01
High-resolution geophysical mapping was conducted from an autonomous underwater vehicle on the flank of Daisan-Kume Knoll in the Ryukyu Arc, southwest of Japan. 1 m resolution bathymetry identified 264 spires, 173 large mounds and 268 small mounds within a depression that is up to 1600 m wide and up to 60 m deep, at water depths between 1330 and 1470 m. Hydrothermal venting is strongly inferred from the observation of plumes in sidescan sonar imagery and positive temperature anomalies over the spires and mounds. This field, named the Gondou Field, has a giant mound G1 with a diameter of 280 m and a height of 80 m. Mound G1 has distinctive summit ridges composed of multiple spires where acoustic plumes with temperature anomalies up to 1.12°C are observed, indicative of high-temperature venting. Other than mound G1, a number of active large mounds more than 30 m wide and spires over 10-22 m tall are common and they concentrate in the central and southern areas of the field, suggesting that these areas are the center of present hydrothermal activity. Acoustic plumes imaged by side-scan sonar at the Gondou Field are different in character from bubble plumes imaged in other hydrothermal fields in the Ryukyu Arc. The plumes are diffused and deflected as they rise through the water column and have a shape consistent with black smokers.
NASA Astrophysics Data System (ADS)
Ishibashi, J.; Suzuki, R.; Hamasaki, H.; Yamanaka, T.; Chiba, H.; Tsunogai, U.; Ijiri, A.; Nakagawa, S.; Nunoura, T.; Takai, K.; Kinoshita, M.; Ashi, J.
2007-12-01
The newly developed ROV NSS (Navigable Sampling System) enabled pin-point piston core sampling from the active hydrothermal field. In the Iheya North hydrothermal field in the mid-Okinawa Trough (27°47.5'N, 126°53.8'E, depth = 1000m), animal colonies are observed not only around the central mound structure (named as NBC) which discharges vigrously high temperature (T=311°C) clear fluid, but also as Calyptogena colony at 200m east from the NBC mound and as tube-worm colony at 250m southeast from the NBC mound. During Leg 3 of KY05-14 cruise (R/V Kaiyo of JAMSTEC) in Jan. 2005, fourn piston cores were successfully recovered with length from 65cm to 250cm. Surface sediments from the Calyptogena colony and the tube-worm colony were revealed as mainly composed of pumiceous sediment. Pore fluids from the Calyptogena Field showed unusual chemistry characterized as very low salinity (Cl=420mM), low Mg concentration, significantly lower Na/Cl ratio than seawater and high methane concentration, which suggests contribution of a vapor-rich hydrothermal component migrating within the pumice layer from the activity center. Moreover, decrease of SO4 accompanied by increase of alkalinity is notable even less than one meter depth below the seafloor. In situ sulfate reduction in the surface sediment caused by entrainment of the hydrothermal component would be a source of hydrogen sulfide that supports Calyptogena colony.
Along-arc distribution of 3He/4He and 87Sr/86Sr in thermal fluids of the Kuril Island arc (Russia)
NASA Astrophysics Data System (ADS)
Taran, Y.; Kalacheva, E.; Bujakajte, M.; Inguaggiato, S.
2017-12-01
The Kuril Island arc in the NW Pacific extends for 1200 km from the Kamchatka Peninsula to Hokkaido Islandand separates the margin Sea of Okhotsk from the Pacific Ocean. Among 40 active volcanoes at least 7 are characterized by strong and high-temperature fumarolic activity, 1 to 3 volcanoes are erupting right now, and many of active and dormant volcanoes host hydrothermal systems. We report our data on hydrochemistry and isotopic composition of He and Sr from fumarolic and hydrothermal discharges sampled along the arc, from Ebeko volcano on Paramushir Island to Golovnin volcano on Kunashir Island. The data were obtained during the field campaign in 2015-2017. Most of hydrothermal systems of Kuril Islands discharge acid-to-ultra acid SO4-Cl and Cl-SO4 waters and steam-heated SO4 waters. On some islands, like Shiashkotan, northern Kurils, coastal hot springs can be found issuing Na-Cl waters mixed with seawater. Mature Na-Cl waters are known only on southern big islands Iturup and Kunashir. The distribution of 3He/4He in hydrothermal and fumarolic gases along the arc is very uniform with 3He/4He values close to the MORB value of 8Ra where Ra is atmospheric ratio (1.4 x 10-6). The northernmost Ebeko volcano discharges fumaroles with 3He/4He up to 7.9Ra, and bubbling gas in the nearest hot springs up to 7.6Ra. Such high 3He/4He values with a maximum of 8.3Ra in fumaroles of the Pallas Peak in the middle of the arc were measured in all thermal manifestations of the arc (fumaroles, hydrothermal steam vents and bubbling gases) up to the southernmost Kunashir Island, where volcanic and hydrothermal gases are characterized by significantly lower values of 5.5Ra at Mendeleev volcano and 3.5Ra at Golovnin volcano. Isotopic ratio of the dissolved Sr as a rule corresponds to the 87Sr/86Sr values of the host rocks and only in the coastal hot springs demonstrates partial mixing with seawater. There is also a general consistence of 87Sr/86Sr in springs and 3He/4He in gases. This study was supported by the Russian Science Foundation grant # 15-17-20011.
Recent crustal subsidence at Yellowstone Caldera, Wyoming
Dzurisin, D.; Savage, J.C.; Fournier, R.O.
1990-01-01
Following a period of net uplift at an average rate of 15??1 mm/year from 1923 to 1984, the east-central floor of Yellowstone Caldera stopped rising during 1984-1985 and then subsided 25??7 mm during 1985-1986 and an additional 35??7 mm during 1986-1987. The average horizontal strain rates in the northeast part of the caldera for the period from 1984 to 1987 were: {Mathematical expression}1 = 0.10 ?? 0.09 ??strain/year oriented N33?? E??9?? and {Mathematical expression}2 = 0.20 ?? 0.09 ??strain/year oriented N57?? W??9?? (extension reckoned positive). A best-fit elastic model of the 1985-1987 vertical and horizontal displacements in the eastern part of the caldera suggests deflation of a horizontal tabular body located 10??5 km beneath Le Hardys Rapids, i.e., within a deep hydrothermal system or within an underlying body of partly molten rhyolite. Two end-member models each explain most aspects of historical unrest at Yellowstone, including the recent reversal from uplift to subsidence. Both involve crystallization of an amount of rhyolitic magma that is compatible with the thermal energy requirements of Yellowstone's vigorous hydrothermal system. In the first model, injection of basalt near the base of the rhyolitic system is the primary cause of uplift. Higher in the magmatic system, rhyolite crystallizes and releases all of its magmatic volatiles into the shallow hydrothermal system. Uplift stops and subsidence starts whenever the supply rate of basalt is less than the subsidence rate produced by crystallization of rhyolite and associated fluid loss. In the second model, uplift is caused primarily by pressurization of the deep hydrothermal system by magmatic gas and brine that are released during crystallization of rhyolite and them trapped at lithostatic pressure beneath an impermeable self-sealed zone. Subsidence occurs during episodic hydrofracturing and injection of pore fluid from the deep lithostatic-pressure zone into a shallow hydrostatic-pressure zone. Heat input from basaltic intrusions is required to maintain Yellowstone's silicic magmatic system and shallow hydrothermal system over time scales longer than about 105 years, but for the historical time period crystallization of rhyolite can account for most aspects of unrest at Yellowstone, including seismicity, uplift, subsidence, and hydrothermal activity. ?? 1990 Springer-Verlag.
NASA Astrophysics Data System (ADS)
Goutham, Cilaveni; Kandula, Kumara Raja; Raavi, Sai Santhosh Kumar; Asthana, Saket
2018-04-01
Nanocrystalline Pr3+ substituted NBT was synthesized using hydrothermal technique. Pr3+ modifies the ferroelectric NBT optically active and enhances the electrical properties with small structural changes. Aiming to the development of the bottom up optoelectronic devices this optimized nanoscale Na0.5Bi0.5-xPrxTiO3(x = 0.005) compound is synthesized hydrothermally. X-ray diffraction pattern shows that the system is stabilized in the Rhombohedral (space groupR3c) phase indicating the local strain inhomogeneity. PE loop shows that there is a decrement in the Ec value compared with compounds synthesized using conventional methods. The strong red emission assigned to prominent transition of the Pr3+ ions at 610nm was observed along with weak blue-green emission, indicating the potential use of the system. Energy transfer from host system to Pr3+ ions is responsible for red emission while blue green emission is due to quenching of 3P0 induced by intervalence charge transfer state.
NASA Astrophysics Data System (ADS)
Keim, Maximilian F.; Walter, Benjamin F.; Neumann, Udo; Kreissl, Stefan; Bayerl, Richard; Markl, Gregor
2018-03-01
The silver-copper sulfide mineralization associated with the fluorite-barite vein system at the Clara deposit in SW Germany shows large scale vertical zoning. Low to moderate silver contents prevail in the upper 350 m, whereas high silver contents occur in the subsequent 450 m of the currently known vein system. This change in Ag tenor is related to conspicuous mineralogical changes with depth. A detailed petrographic and fluid inclusion study identifies evidence for five subsequent hydrothermal and one alteration stage—all contributing to mineralogical diversity. The vertical Ag zoning, however, is attributed only to the first of these stages. During this first stage, increasing oxidation of ascending hydrothermal fluids (90-160 °C, 24.2-26.7 wt% NaCl+CaCl2) led to the formation of high-Ag tetrahedrite-tennantite in the lower parts and basically Ag-free enargite in the upper parts of the vein system. The subsequent hydrothermal stage led to significant mineralogical changes, but inherited the pre-existing Ag zonation. In this second hydrothermal stage, which was related to fluids similar in composition to those of the first stage (70-125 °C, 23.1-26.5 wt% NaCl+CaCl2), dissolution of high Ag-tetrahedrite-tennantite resulted in the formation of complex Ag-sulfosalts together with moderately Ag-bearing tetrahedrite-tennantite and chalcopyrite. The first two stages were formed by fluid mixing of a sedimentary and a hot basement fluid. The influx of fluids with high Ag, Bi and Pb activity during stage 3 and 5 resulted in the local replacement of earlier Ag-sulfosalts by galena and Ag-(Bi)-sulfosalts. The fourth stage is marked by partial dissolution of sulfides and sulfosalts by a late, hot, undiluted basement fluid (250 °C, 18.7-20.9 wt% NaCl+CaCl2) precipitating fluorite, barite and quartz. Finally, supergene alteration lead to the dissolution of silver-bearing phases and the precipitation of acanthite and native silver. The study illustrates, how metal tenor and mineralogy are decoupled in vertically extensive, polyphase hydrothermal vein systems. This may be pertinent to similarly zoned polymetallic vein systems.
NASA Astrophysics Data System (ADS)
Qi, Jihong; Xu, Mo; An, Chenjiao; Zhang, Yunhui; Zhang, Qiang
2017-04-01
The Xianshuihe Fault with frequent earthquakes activities is the regional deep fault in China. The Moxi Fault is the southern part of the Xianshuihe Fault, where the strong activities of geothermal water could bring abundant information of deep crust. In this article, some typical geothermal springs were collected along the Moxi fault from Kangding to Shimian. Using the the Na-K-Mg equilibrium diagram, it explains the state of water-rock equilibrium, and estimates the reservoir temperature basing appropriate geothermometers. Basing on the relationship between the enthalpy and chlorine concentration of geothermal water, it analyze the mixing progress of thermal water with shallow groundwater. Moreover, the responses of variation of geothermal water to the solid tides are considered to study the hydrothermal activities of this fault. The Guanding in Kangding are considered as the center of the geothermal system, and the hydrothermal activities decrease southward extending. Geothermal water maybe is heated by the deep heat source of the Himalayan granites, while the springs in the south area perform the mixture with thermal water in the sub-reservoir of the Permian crystalline limestone. It improves the research of hydrothermal activities in the Moxi Fault, meanwhile using the variation of geothermal water maybe become a important method to study the environment of deep earth in the future.
Models of magma-aquifer interactions and their implications for hazard assessment
NASA Astrophysics Data System (ADS)
Strehlow, Karen; Gottsmann, Jo; Tumi Gudmundsson, Magnús
2014-05-01
Interactions of magmatic and hydrological systems are manifold, complex and poorly understood. On the one side they bear a significant hazard potential in the form of phreatic explosions or by causing "dry" effusive eruptions to turn into explosive phreatomagmatic events. On the other side, they can equally serve to reduce volcanic risk, as resulting geophysical signals can help to forecast eruptions. It is therefore necessary to put efforts towards answering some outstanding questions regarding magma - aquifer interactions. Our research addresses these problems from two sides. Firstly, aquifers respond to magmatic activity and they can also become agents of unrest themselves. Therefore, monitoring the hydrology can provide a valuable window into subsurface processes in volcanic areas. Changes in temperature and strain conditions, seismic excitation or the injection of magmatic fluids into hydrothermal systems are just a few of the proposed processes induced by magmatic activity that affect the local hydrology. Interpretations of unrest signals as groundwater responses are described for many volcanoes and include changes in water table levels, changes in temperature or composition of hydrothermal waters and pore pressure-induced ground deformation. Volcano observatories can track these hydrological effects for example with potential field investigations or the monitoring of wells. To fully utilise these indicators as monitoring and forecasting tools, however, it is necessary to improve our understanding of the ongoing mechanisms. Our hydrogeophysical study uses finite element analysis to quantitatively test proposed mechanisms of aquifer excitation and the resultant geophysical signals. Secondly, volcanic activity is influenced by the presence of groundwater, including phreatomagmatic and phreatic eruptions. We focus here on phreatic explosions at hydrothermal systems. At least two of these impulsive events occurred in 2013: In August at the Icelandic volcano Kverkfjöll and in October on White Island, New Zealand. The latter is only one example of these natural attractions that are visited by thousands of tourists every year. Additionally, these systems are increasingly used for energy generation. Phreatic explosions pose a serious risk to people and infrastructure nearby, and they are hard to predict. To improve risk assessment in hydrothermal areas, we assessed historical records and literature with regard to the frequency and mechanisms of hydrothermal explosions. Complemented by numerical models this study wants to answer the question: What determines the change of a safe to a dangerous behaviour of the system, i.e. the change from silent degassing to explosions? Our project aims to widen our knowledge base on the complex coupling of magmatic and hydrological systems, which provides further insight into the subsurface processes at volcanic systems and will aid future risk assessment and eruption forecasting.
NASA Astrophysics Data System (ADS)
de Ronde, C. E. J.; Walker, S. L.; Caratori Tontini, F.; Baker, E. T.; Embley, R. W.; Yoerger, D.
2014-12-01
The application of Autonomous Underwater Vehicles (AUVs) in the search for, and characterization of, seafloor hydrothermal systems associated with arc volcanoes has provided important information at a scale relevant to the study of these systems. That is, 1-2 m resolution bathymetric mapping of the seafloor, when combined with high-resolution magnetic and water column measurements, enables the discharge of hydrothermal vent fluids to be coupled with geological and structural features, and inferred upflow zones. Optimum altitude for the AUVs is ~70 m ensuring high resolution coverage of the area, maximum exposure to hydrothermal venting, and efficency of survey. The Brothers caldera and Clark cone volcanoes of the Kermadec arc have been surveyed by ABE and Sentry. At Brothers, bathymetric mapping shows complex features on the caldera walls including embayment's, ridges extending orthogonal to the walls and the location of a dominant ring fault. Water column measurements made by light scattering, temperature, ORP and pH sensors confirmed the location of the known vent fields on the NW caldera wall and atop the two cones, and discovered a new field on the West caldera wall. Evidence for diffuse discharge was also seen on the rim of the NW caldera wall; conversely, there was little evidence for discharge over an inferred ancient vent site on the SE caldera wall. Magnetic measurements show a strong correlation between the boundaries of vent fields determined by water column measurements and observed from manned submersible and towed camera surveys, and donut-shaped zones of magnetic 'lows' that are focused along ring faults. A magnetic low was also observed to cover the SE caldera site. Similar surveys over the NW edifice of Clark volcano also show a strong correlation between active hydrothermal venting and magnetic lows. Here, the survey revealed a pattern resembling Swiss cheese of magnetic lows, indicating more widespread permeability. Moreover, the magnetic survey showed evidence for a highly magnetized ring structure ~350 m below the volcano summit considered to represent a buried (by continued growth of the cone) caldera rim. Zones of magnetic lows located inside the inferred caldera that are not associated with present-day venting are consistent with an earlier stage of hydrothermal activity.
NASA Astrophysics Data System (ADS)
Lyle, Mitchell; Leinen, Margaret; Owen, Robert M.; Rea, David K.
1987-06-01
Commonly it is assumed that the intensity of mid-ocean ridge hydrothermal activity should correlate with spreading rate, since high spreading rates are an indication of large subcrustal heat sources needed for intense hydrothermal activity. We have tested this hypothesis by modeling the deposition of hydrothermal precipitates from cores from Deep Sea Drilling Project Leg 92, taken on the west flank of the East Pacific Rise at 19°S. Although spreading rates at the East Pacific Rise and its predecessor, the Mendoza Rise, have varied by only 50% in the last 30 million years, we found certain episodes, at about 25, 18, 14, and 9 million years ago, of hydrothermal manganese deposition as much as a factor of 20 higher than equivalent Holocene accumulation. These eposides do not correlate with spreading rate changes and instead seem to occur at times of major tectonic reorganizations. We propose that ridge jumps and changes of ridge orientation may substantially increase hydrothermal activity by fracturing the ocean crust and providing seawater access to deep-seated heat sources.
NASA Astrophysics Data System (ADS)
Masaki, Y.; Kinoshita, M.; Yamamoto, H.; Nakajima, R.; Kumagai, H.; Takai, K.
2014-12-01
Iheya-North hydrothermal field situated in the middle Okinawa trough backarc basin is one of the largest ongoing Kuroko deposits in the world. Active chimneys as well as diffuse ventings (maximum fluid temperature 311 °C) have been located and studied in detail through various geological and geophysical surveys. To clarify the spatial scale of the hydrothermal circulation system, intensive heat flow measurements were carried out and ~100 heat flow data in and around the field from 2002 to 2014. In 2010, Integrated Ocean Drilling Program (IODP) Expedition 331 was carried out, and subbottom temperature data were obtained around the hydrothermal sites. During the JAMSTEC R/V Kaiyo cruise, KY14-01 in 2014, Iheya-North "Natsu" and "Aki" hydrothermal fields were newly found. The Iheya-Noth "Natsu" and "Aki" sites are located 1.2 km and 2.6 km south from the Iheya-North original site, respectively, and the maximum venting fluid temperature was 317 °C. We obtained one heat flow data at the "Aki" site. The value was 17 W/m2. Currently, the relationship between these hydrothermal sites are not well known. Three distinct zones are identified by heat flow values within 3 km from the active hydrothermal field. They are high-heat flow zone (>1 W/m2; HHZ), moderate-heat-flow zone (1-0.1 W/m2; MHZ); and low-heat-flow zone (<0.1 W/m2; LHZ). With increasing distance east of the HHZ, heat flow gradually decreases towards MHZ and LHZ. In the LHZ, temperature at 37m below the seafloor (mbsf) was 6 °C, that is consistent with the surface low heat flow suggesting the recharge of seawater. However, between 70 and 90 mbsf, the coarser sediments were cored, and temperature increased from 25 °C to 40°C. The temperature was 905°C at 151 mbsf, which was measured with thermoseal strips. The low thermal gradient in the upper 40 m suggests downward fluid flow. We infer that a hydrothermal circulation in the scale of ~1.5 km horizontal vs. ~a few hundred meters vertical.
Fluid flow and water-rock interaction in the East Rift Zone of Kilauea Volcano, Hawaii
NASA Astrophysics Data System (ADS)
Conrad, Mark E.; Thomas, Donald M.; Flexser, Steven; Vennemann, Torsten W.
1997-07-01
The East Rift Zone of Kilauea Volcano in Hawaii represents a major area of geothermal activity. Fluid inclusion and stable isotope analyses of secondary hydrothermal minerals in core samples from three scientific observation holes (SOH) drilled into the rift zone indicate that the geothermal system is dominated by meteoric waters to depths of as much as 1500 m below sea level. Calculated δ18O and δD values for fluids on the north side of the rift zone indicate that the deep meteoric fluids may be derived from precipitation on the upper slopes of Mauna Loa Volcano. In the interior of the rift zone, recharge is dominated by seawater mixed with local meteoric water. Water/rock ratios in the rift area are approximately 2, but strongly 18O-enriched fluids in the deeper parts of the SOH-2 and SOH-4 drill holes (on the north side of the rift) indicate that the fluids underwent extensive interaction with rocks prior to reaching this part of the rift zone. Marine carbonates at the subaerial to submarine transition (between 1700 and 1780 m depth) in SOH-4 have not fully equilibrated with the fluids, suggesting that the onset of hydrothermal activity in this area was relatively recent (<2000 years). This may represent increased volcanic activity along the rift after the end of the Ai La'au phase of eruptive activity at the Kilauea summit approximately 1000 years ago, or it may reflect progressive evolution of the hydrothermal system in response to southward migration of intrusive activity within the rift.
Putative fossil life in a hydrothermal system of the Dellen impact structure, Sweden
NASA Astrophysics Data System (ADS)
Lindgren, Paula; Ivarsson, Magnus; Neubeck, Anna; Broman, Curt; Henkel, Herbert; Holm, Nils G.
2010-07-01
Impact-generated hydrothermal systems are commonly proposed as good candidates for hosting primitive life on early Earth and Mars. However, evidence of fossil microbial colonization in impact-generated hydrothermal systems is rarely reported in the literature. Here we present the occurrence of putative fossil microorganisms in a hydrothermal system of the 89 Ma Dellen impact structure, Sweden. We found the putative fossilized microorganisms hosted in a fine-grained matrix of hydrothermal alteration minerals set in interlinked fractures of an impact breccia. The putative fossils appear as semi-straight to twirled filaments, with a thickness of 1-2 μm, and a length between 10 and 100 μm. They have an internal structure with segmentation, and branching of filaments occurs frequently. Their composition varies between an outer and an inner layer of a filament, where the inner layer is more iron rich. Our results indicate that hydrothermal systems in impact craters could potentially be capable of supporting microbial life. This could have played an important role for the evolution of life on early Earth and Mars.
Trace metal-rich Quaternary hydrothermal manganese oxide and barite deposit, Milos Island, Greece
Hein, J.R.; Stamatakis, G.; Dowling, J.S.
2000-01-01
The Cape Vani Mn oxide and barite deposit on Milos Island offers an excellent opportunity to study the three-dimensional characteristics of a shallow-water hydrothermal system. Milos Island is part of the active Aegean volcanic arc. A 1 km long basin located between two dacitic domes in northwest Milos is filled with a 35-50 m thick section of Quaternary volcaniclastic and pyroclastic rocks capped by reef limestone that were hydrothermally mineralized by Mn oxides and barite. Manganese occurs as thin layers, as cement of sandstone and as metasomatic replacement of the limestone, including abundant fossil shells. Manganese minerals include chiefly δ-MnO2, pyrolusite and ramsdellite. The MnO contents for single beds range up to 60%. The Mn oxide deposits are rich in Pb (to 3.4%), BaO (to 3.1%), Zn (to 0.8%), As (to 0.3%), Sb (to 0.2%) and Ag (to 10 ppm). Strontium isotopic compositions of the Mn oxide deposits and sulphur isotopic compositions of the associated barite show that the mineralizing fluids were predominantly sea water. The Mn oxide deposit formed in close geographical proximity to sulphide-sulphate-Au-Ag deposits and the two deposit types probably formed from the same hydrothermal system. Precipitation of Mn oxide took place at shallow burial depths and was promoted by the mixing of modified sea water (hydrothermal fluid) from which the sulphides precipitated at depth and sea water that penetrated along faults and fractures in the Cape Vani volcaniclastic and tuff deposits. The hydrothermal fluid was formed from predominantly sea water that was enriched in metals leached from the basement and overlying volcanogenic rocks. The hydrothermal fluids were driven by convection sustained by heat from cooling magma chambers. Barite was deposited throughout the time of Mn oxide mineralization, which occurred in at least two episodes. Manganese mineralization occurred by both focused and diffuse flow, the fluids mineralizing the beds of greatest porosity and filling dilatational fractures along with barite.
White, A.F.; Chuma, N.J.; Goff, F.
1992-01-01
Partial equilibrium conditions occur between fluids and secondary minerals in the Valles hydrothermal system, contained principally in the Tertiary rhyolitic Bandelier Tuff. The mass transfer processes are governed by reactive phase compositions, surface areas, water-rock ratios, reaction rates, and fluid residence times. Experimental dissolution of the vitric phase of the tuff was congruent with respect to Cl in the solid and produced reaction rates which obeyed a general Arrhenius release rate between 250 and 300??C. The 18O differences between reacted and unreacted rock and fluids, and mass balances calculations involving Cl in the glass phase, produced comparable water-rock ratios of unity, confirming the importance of irreversible reaction of the vitric tuff. A fluid residence time of approximately 2 ?? 103 years, determined from fluid reservoir volume and discharge rates, is less than 0.2% of the total age of the hydrothermal system and denotes a geochemically and isotopically open system. Mass transfer calculations generally replicated observed reservoir pH, Pco2, and PO2 conditions, cation concentrations, and the secondary mineral assemblage between 250 and 300??C. The only extraneous component required to maintain observed calcite saturation and high Pco2 pressures was carbon presumably derived from underlying Paleozoic limestones. Phase rule constraints indicate that Cl was the only incompatible aqueous component not controlled by mineral equilibrium. Concentrations of Cl in the reservoir directly reflect mass transport rates as evidenced by correlations between anomalously high Cl concentrations in the fluids and tuff in the Valles caldera relative to other hydrothermal systems in rhyolitic rocks. ?? 1992.
NASA Astrophysics Data System (ADS)
Roquer, T.; Arancibia, G.; Rowland, J. V.; Iturrieta, P. C.; Morata, D.; Cembrano, J. M.
2017-12-01
Paleofluid-transporting systems can be recognized as meshes of fracture-filled veins in eroded zones of extinct hydrothermal systems. Here we conducted meso-microstructural analysis and mechanical modeling from two exhumed exposures of the faults governing regional tectonics of the Southern Andes: the Liquiñe-Ofqui Fault System (LOFS) and the Andean Transverse Faults (ATF). A total of 107 fractures in both exposures were analyzed. The ATF specific segment shows two tectonic solutions that can be modeled as Andersonian and non-Andersonian tectonic regimes: (1) shear (mode II/III) failure occurs at differential stresses > 28 MPa and fluid pressures < 40-80% lithostatic in the Andersonian regime; and (2) sporadic hybrid extensional + shear (modes I + II/III) failure occurs at differential stresses < 20 MPa and anomalously high fluid pressures > 85-98% lithostatic in the non-Andersonian regime. Additionally, the LOFS exposure cyclically fails in extension (mode I) or extension + shear (modes I + II/III) in the Andersonian regime, at differential stresses < 28 MPa and fluid pressures > 40-80% lithostatic. In areas of spatial interaction between ATF and LOFS, these conditions might favor: (1) the storage of overpressured fluids in hydrothermal systems associated with the ATF faults, and (2) continuous fluid flow through vertical conduits in the LOFS faults. These observations suggest that such intersections are highly probable locations for concentrated hydrothermal activity, which must be taken into consideration for further geothermal exploration. ACKNOWLEDGEMENTS. PhD CONICYT grants, Centro de Excelencia en Geotermia de los Andes (CEGA-FONDAP/CONICYT Project #15090013), FONDECYT Project #1130030 and Project CONICYT REDES #140036.
NASA Astrophysics Data System (ADS)
Ucciani, G.; Beauducel, F.; Bouin, M. P.; Nercessian, A.
2015-12-01
La Soufrière is one of the many hazardous volcanoes in the inner arc of Lesser Antilles. Located South of Basse-Terre island, it is the only active volcano of the Guadeloupe archipelago. Since the last significant magmatic eruption in 1535 AD, the activity has been exculsively phreatic. Since 1992 and the abrupt renewal of seismic and fumarollic activities, the Guadeloupe Volcanological and Seismological Observatory (OVSG-IPGP) has recorded a progressive increasing of seismicity and degassing that led scientists and authorities to set the alert level ``Vigilance'' and hold it until today. According to the recent geophysical, geochemical and geological studies, the current volcanic activity of la Soufrière volcano seems to be exclusively associated to the hydrothermal system, while the link with seismic activity is still poorly studied. In this context of possible pre-eruptive unrest, we investigated the spatial and temporal variations of the seismicity recorded between 1981 and 2013. From a consistent seismological framework coupling spectral, statistical, signal processing, clustering, and inverse problems methods, we demonstrate that this seismicity is largely generated by shallow hydrothermal fluid sources located in a complex plumbing system. Spatial variations of Vp/Vs ratio and B-value in seismogenic structures allow us to document three main seismic zones associated to : (1) migration of magmatic gas, (2) the storage and mixing of underground water and gas and (3) the shallow migration of hydrothermal fluids in high fractured and heterogeneous system. Waveform analysis revealed a low number of significant families consistent with fracturing process, and the temporal evolution of multiplet activities highlighted several variations associated with surface manifestations and brutal dynamic changes after major local tectonic earthquakes of Les Saintes (21 November 2004, Mw=6.3), its main aftershock (14 February 2005, Mw=5.7) and the last major earthquake of la Martinique (29 November 2007, Mw=7.4).
Element fluxes from Copahue Volcano, Argentina
NASA Astrophysics Data System (ADS)
Varekamp, J. C.
2003-12-01
Copahue volcano in Argentina has an active volcano-magmatic hydrothermal system that emits fluids with pH=0.3 that feed a river system. River flux measurements and analytical data provide element flux data from 1997 to 2003, which includes the eruptive period of July to December 2000. The fluids have up to 6.5 percent sulfate, 1 percent Cl and ppm levels of B, As, Cu, Zn and Pb. The hydrothermal system acts as a perfect scrubber for magmatic gases during the periods of passive degassing, although the dissolved magmatic gases are modified through water rock interaction and mineral precipitation. The magmatic SO2 disproportionates into sulfate and liquid elemental sulfur at about 300 C; the sulfate is discharged with the fluids, whereas the liquid sulfur is temporarily retained in the reservoir but ejected during phreatic and hydrothermal eruptions. The intrusion and chemical attack of new magma in the hydrothermal reservoir in early 2000 was indicated by strongly increased Mg concentrations and Mg fluxes, and higher Mg/Cl and Mg/K values. The hydrothermal discharge has acidified a large glacial lake (0.5 km3) to pH=2 and the lake effluents acidify the exiting river. Even more than 100 km downstream, the effects of acid pulses from the lake are evident from red coated boulders and fish die-offs. The river-bound sulfate fluxes from the system range from 70 to 200 kilotonnes/year. The equivalent SO2 output of the whole volcanic system ranges from 150 to 500 tonnes/day, which includes the fraction of native sulfur that formed inside the mountain but does not include the release of SO2 into the atmosphere during the eruptions. Trace element fluxes of the river will be scaled up and compared with global element fluxes from meteoric river waters (subterranean volcanic weathering versus watershed weathering).
Gardner, W.P.; Susong, D.D.; Solomon, D.K.; Heasler, H.P.
2010-01-01
Dissolved noble gas concentrations in springs are used to investigate boiling of hydrothermal water and mixing of hydrothermal and shallow cool water in the Norris Geyser Basin area. Noble gas concentrations in water are modeled for single stage and continuous steam removal. Limitations on boiling using noble gas concentrations are then used to estimate the isotopic effect of boiling on hydrothermal water, allowing the isotopic composition of the parent hydrothermal water to be determined from that measured in spring. In neutral chloride springs of the Norris Geyser Basin, steam loss since the last addition of noble gas charged water is less than 30% of the total hydrothermal discharge, which results in an isotopic shift due to boiling of ?? 2.5% ??D. Noble gas concentrations in water rapidly and predictably change in dual phase systems, making them invaluable tracers of gas-liquid interaction in hydrothermal systems. By combining traditional tracers of hydrothermal flow such as deuterium with dissolved noble gas measurements, more complex hydrothermal processes can be interpreted. ?? 2010 Elsevier B.V.
Nakamura, Kentaro; Watanabe, Hiromi; Miyazaki, Junichi; Takai, Ken; Kawagucci, Shinsuke; Noguchi, Takuro; Nemoto, Suguru; Watsuji, Tomo-o; Matsuzaki, Takuya; Shibuya, Takazo; Okamura, Kei; Mochizuki, Masashi; Orihashi, Yuji; Ura, Tamaki; Asada, Akira; Marie, Daniel; Koonjul, Meera; Singh, Manvendra; Beedessee, Girish; Bhikajee, Mitrasen; Tamaki, Kensaku
2012-01-01
Indian Ocean hydrothermal vents are believed to represent a novel biogeographic province, and are host to many novel genera and families of animals, potentially indigenous to Indian Ocean hydrothermal systems. In particular, since its discovery in 2001, much attention has been paid to a so-called ‘scaly-foot’ gastropod because of its unique iron-sulfide-coated dermal sclerites and the chemosynthetic symbioses in its various tissues. Despite increasing interest in the faunal assemblages at Indian Ocean hydrothermal vents, only two hydrothermal vent fields have been investigated in the Indian Ocean. Here we report two newly discovered hydrothermal vent fields, the Dodo and Solitaire fields, which are located in the Central Indian Ridge (CIR) segments 16 and 15, respectively. Chemosynthetic faunal communities at the Dodo field are emaciated in size and composition. In contrast, at the Solitaire field, we observed faunal communities that potentially contained almost all genera found at CIR hydrothermal environments to date, and even identified previously unreported taxa. Moreover, a new morphotype of ‘scaly-foot’ gastropod has been found at the Solitaire field. The newly discovered ‘scaly-foot’ gastropod has similar morphological and anatomical features to the previously reported type that inhabits the Kairei field, and both types of ‘scaly-foot’ gastropods genetically belong to the same species according to analyses of their COI gene and nuclear SSU rRNA gene sequences. However, the new morphotype completely lacks an iron-sulfide coating on the sclerites, which had been believed to be a novel feature restricted to ‘scaly-foot’ gastropods. Our new findings at the two newly discovered hydrothermal vent sites provide important insights into the biodiversity and biogeography of vent-endemic ecosystems in the Indian Ocean. PMID:22431990
Chemical environments of submarine hydrothermal systems. [supporting abiogenetic theory
NASA Technical Reports Server (NTRS)
Shock, Everett L.
1992-01-01
The paper synthesizes diverse information about the inorganic geochemistry of submarine hydrothermal systems, provides a description of the fundamental physical and chemical properties of these systems, and examines the implications of high-temperature, fluid-driven processes for organic synthesis. Emphasis is on a few general features, i.e., pressure, temperature, oxidation states, fluid composition, and mineral alteration, because these features will control whether organic synthesis can occur in hydrothermal systems.
Yanagawa, Katsunori; Ijiri, Akira; Breuker, Anja; Sakai, Sanae; Miyoshi, Youko; Kawagucci, Shinsuke; Noguchi, Takuroh; Hirai, Miho; Schippers, Axel; Ishibashi, Jun-ichiro; Takaki, Yoshihiro; Sunamura, Michinari; Urabe, Tetsuro; Nunoura, Takuro; Takai, Ken
2017-01-01
Subseafloor microbes beneath active hydrothermal vents are thought to live near the upper temperature limit for life on Earth. We drilled and cored the Iheya North hydrothermal field in the Mid-Okinawa Trough, and examined the phylogenetic compositions and the products of metabolic functions of sub-vent microbial communities. We detected microbial cells, metabolic activities and molecular signatures only in the shallow sediments down to 15.8 m below the seafloor at a moderately distant drilling site from the active hydrothermal vents (450 m). At the drilling site, the profiles of methane and sulfate concentrations and the δ13C and δD isotopic compositions of methane suggested the laterally flowing hydrothermal fluids and the in situ microbial anaerobic methane oxidation. In situ measurements during the drilling constrain the current bottom temperature of the microbially habitable zone to ~45 °C. However, in the past, higher temperatures of 106–198 °C were possible at the depth, as estimated from geochemical thermometry on hydrothermally altered clay minerals. The 16S rRNA gene phylotypes found in the deepest habitable zone are related to those of thermophiles, although sequences typical of known hyperthermophilic microbes were absent from the entire core. Overall our results shed new light on the distribution and composition of the boundary microbial community close to the high-temperature limit for habitability in the subseafloor environment of a hydrothermal field. PMID:27754478
Yanagawa, Katsunori; Ijiri, Akira; Breuker, Anja; Sakai, Sanae; Miyoshi, Youko; Kawagucci, Shinsuke; Noguchi, Takuroh; Hirai, Miho; Schippers, Axel; Ishibashi, Jun-Ichiro; Takaki, Yoshihiro; Sunamura, Michinari; Urabe, Tetsuro; Nunoura, Takuro; Takai, Ken
2017-02-01
Subseafloor microbes beneath active hydrothermal vents are thought to live near the upper temperature limit for life on Earth. We drilled and cored the Iheya North hydrothermal field in the Mid-Okinawa Trough, and examined the phylogenetic compositions and the products of metabolic functions of sub-vent microbial communities. We detected microbial cells, metabolic activities and molecular signatures only in the shallow sediments down to 15.8 m below the seafloor at a moderately distant drilling site from the active hydrothermal vents (450 m). At the drilling site, the profiles of methane and sulfate concentrations and the δ 13 C and δD isotopic compositions of methane suggested the laterally flowing hydrothermal fluids and the in situ microbial anaerobic methane oxidation. In situ measurements during the drilling constrain the current bottom temperature of the microbially habitable zone to ~45 °C. However, in the past, higher temperatures of 106-198 °C were possible at the depth, as estimated from geochemical thermometry on hydrothermally altered clay minerals. The 16S rRNA gene phylotypes found in the deepest habitable zone are related to those of thermophiles, although sequences typical of known hyperthermophilic microbes were absent from the entire core. Overall our results shed new light on the distribution and composition of the boundary microbial community close to the high-temperature limit for habitability in the subseafloor environment of a hydrothermal field.
NASA Astrophysics Data System (ADS)
Gresse, Marceau; Vandemeulebrouck, Jean; Byrdina, Svetlana; Chiodini, Giovanni; Revil, André; Johnson, Timothy C.; Ricci, Tullio; Vilardo, Giuseppe; Mangiacapra, Annarita; Lebourg, Thomas; Grangeon, Jacques; Bascou, Pascale; Metral, Laurent
2017-11-01
The Solfatara volcano is the main degassing area of the Campi Flegrei caldera, characterized by 60 years of unrest. Assessing such renewal activity is a challenging task because hydrothermal interactions with magmatic gases remain poorly understood. In this study, we decipher the complex structure of the shallow Solfatara hydrothermal system by performing the first 3-D, high-resolution, electrical resistivity tomography of the volcano. The 3-D resistivity model was obtained from the inversion of 43,432 resistance measurements performed on an area of 0.68 km2. The proposed interpretation of the multiphase hydrothermal structures is based on the resistivity model, a high-resolution infrared surface temperature image, and 1,136 soil CO2 flux measurements. In addition, we realized 27 soil cation exchange capacity and pH measurements demonstrating a negligible contribution of surface conductivity to the shallow bulk electrical conductivity. Hence, we show that the resistivity changes are mainly controlled by fluid content and temperature. The high-resolution tomograms identify for the first time the structure of the gas-dominated reservoir at 60 m depth that feeds the Bocca Grande fumarole through a 10 m thick channel. In addition, the resistivity model reveals a channel-like conductive structure where the liquid produced by steam condensation around the main fumaroles flows down to the Fangaia area within a buried fault. The model delineates the emplacement of the main geological structures: Mount Olibano, Solfatara cryptodome, and tephra deposits. It also reveals the anatomy of the hydrothermal system, especially two liquid-dominated plumes, the Fangaia mud pool and the Pisciarelli fumarole, respectively.
Houghton, J.L.; Shanks, Wayne C.; Seyfried, W.E.
2004-01-01
The Bent Hill massive sulfide deposit and ODP Mound deposit in Middle Valley at the northernmost end of the Juan de Fuca Ridge are two of the largest modern seafloor hydrothermal deposits yet explored. Trace metal concentrations of sulfide minerals, determined by laser-ablation ICP-MS, were used in conjunction with mineral paragenetic studies and thermodynamic calculations to deduce the history of fluid-mineral reactions during sulfide deposition. Detailed analyses of the distribution of metals in sulfides indicate significant shifts in the physical and chemical conditions responsible for the trace element variability observed in these sulfide deposits. Trace elements (Mn, Co, Ni, As, Se, Ag, Cd, Sb, Pb, and Bi) analyzed in a representative suite of 10 thin sections from these deposits suggest differences in conditions and processes of hydrothermal alteration resulting in mass transfer of metals from the center of the deposits to the margins. Enrichments of some trace metals (Pb, Sb, Cd, Ag) in sphalerite at the margins of the deposits are best explained by dissolution/reprecipitation processes consistent with secondary remineralization. Results of reaction-path models clarify mechanisms of mass transfer during remineralization of sulfide deposits due to mixing of hydrothermal fluids with seawater. Model results are consistent with patterns of observed mineral paragenesis and help to identify conditions (pH, redox, temperature) that may be responsible for variations in trace metal concentrations in primary and secondary minerals. Differences in trace metal distributions throughout a single deposit and between nearby deposits at Middle Valley can be linked to the history of metal mobilization within this active hydrothermal system that may have broad implications for sulfide ore formation in other sedimented and unsedimented ridge systems. ?? 2004 Elsevier Ltd.
NASA Astrophysics Data System (ADS)
Cocchi, L.; Plunkett, S.; Augustin, N.; Petersen, S.
2013-12-01
In this paper we present the preliminary results of new near bottom magnetic datasets collected during the recent POS442 cruise using the autonomous underwater vehicle (AUV) Abyss. The Southern Tyrrhenian basin is characterized by deep seafloor interspersed with huge volcanic seamounts (e.g Vavilov and Marsili and those associated to the Aeolian volcanic arc), which were formed during eastward roll back of the Apennine subduction system. These submarine edifices often are affected by significant hydrothermal activity and associated mineral deposits such as those observed at Marsili, Palinuro and Panarea. The western part of the Palinuro volcanic complex is characterized by a half rim of a caldera-like structure and hosts hydrothermal barite-pyrite deposits. Until recently, the full extent of the hydrothermal system remained poorly defined, as exploration has been limited to a few specific sites. In November 2012, a set of high resolution near seafloor geophysical surveys were carried out using GEOMAR's AUV Abyss to attempt to better define the hydrothermal mineralization at Palinuro. Five AUV dives were performed, mapping a total area of 3.7 km2 over the western part of Palinuro. Geomar's Abyss AUV (a Remus6000 class vehicle) was equipped with an Applied Physics Systems flux gate magnetometer, writing to a stand alone data logger, powered by the AUV's main batteries. The 5 dives were performed within the same area but with different primary geophysical sensors (multibeam, sidescan sonar, subbottom profiler), survey altitudes above seafloor (100m, 40m) and line spacing (150m, 100m, 20m). Magnetic data was collect on all five dives. At the beginning of each dive, the AUV performed a set of calibration manoeuvres, involving a 360 degree heading variation, a set of three upwards/downwards pitches, and three port and starboard yaws. This magnetic data reveals the magnetization features of the seafloor in unprecedented detail, highlighting a complex pattern mostly due to extensive hydrothermal alteration. In particular, the strongest hydrothermal alteration related magnetic anomaly appears to be centred on a NNE-SSW fault zone located along the eastern margin of the caldera rims. Multibeam and sidescan sonar co-collected in this area by the AUV have delineated a previously unknown large hydrothermal chimney field and likely sulphide mounds, which extend along and within the caldera rim. Near bottom investigation confirms prior interpretation of extensive hydrothermal alteration being responsible of local magnetization lows previously inferred by ship-borne magnetic investigation. Usually, magnetic anomalies due to hydrothermal alteration are spatially limited, and are slightly detectable from ship borne surveys. The results of this magnetic survey demonstrate how near bottom mapping can significantly improve the resolution of the magnetic anomalies associated with hydrothermal deposits, facilitating a more detailed interpretation for geological modelling.
Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.
2017-09-12
A combined hydrothermal liquefaction (HTL) and catalytic hydrothermal gasification (CHG) system and process are described that convert various biomass-containing sources into separable bio-oils and aqueous effluents that contain residual organics. Bio-oils may be converted to useful bio-based fuels and other chemical feedstocks. Residual organics in HTL aqueous effluents may be gasified and converted into medium-BTU product gases and directly used for process heating or to provide energy.
Tang, Kai; Zhang, Yao; Lin, Dan; Han, Yu; Chen, Chen-Tung A; Wang, Deli; Lin, Yu-Shih; Sun, Jia; Zheng, Qiang; Jiao, Nianzhi
2018-01-01
Shallow-sea hydrothermal systems experience continuous fluctuations of physicochemical conditions due to seawater influx which generates variable habitats, affecting the phylogenetic composition and metabolic potential of microbial communities. Until recently, studies of submarine hydrothermal communities have focused primarily on chemolithoautotrophic organisms, however, there have been limited studies on heterotrophic bacteria. Here, fluorescence in situ hybridization, high throughput 16S rRNA gene amplicon sequencing, and functional metagenomes were used to assess microbial communities from the shallow-sea hydrothermal system off Kueishantao Island, Taiwan. The results showed that the shallow-sea hydrothermal system harbored not only autotrophic bacteria but abundant heterotrophic bacteria. The potential for marker genes sulfur oxidation and carbon fixation were detected in the metagenome datasets, suggesting a role for sulfur and carbon cycling in the shallow-sea hydrothermal system. Furthermore, the presence of diverse genes that encode transporters, glycoside hydrolases, and peptidase indicates the genetic potential for heterotrophic utilization of organic substrates. A total of 408 cultivable heterotrophic bacteria were isolated, in which the taxonomic families typically associated with oligotrophy, copiotrophy, and phototrophy were frequently found. The cultivation-independent and -dependent analyses performed herein show that Alphaproteobacteria and Gammaproteobacteria represent the dominant heterotrophs in the investigated shallow-sea hydrothermal system. Genomic and physiological characterization of a novel strain P5 obtained in this study, belonging to the genus Rhodovulum within Alphaproteobacteria, provides an example of heterotrophic bacteria with major functional capacity presented in the metagenome datasets. Collectively, in addition to autotrophic bacteria, the shallow-sea hydrothermal system also harbors many heterotrophic bacteria with versatile genetic potential to adapt to the unique environmental conditions.
Characterization of Magma-Driven Hydrothermal Systems at Oceanic Spreading Centers
NASA Astrophysics Data System (ADS)
Farough, A.; Lowell, R. P.; Corrigan, R.
2012-12-01
Fluid circulation in high-temperature hydrothermal systems involves complex water-rock chemical reactions and phase separation. Numerical modeling of reactive transport in multi-component, multiphase systems is required to obtain a full understanding of the characteristics and evolution of hydrothermal vent systems. We use a single-pass parameterized model of high-temperature hydrothermal circulation at oceanic spreading centers constrained by observational parameters such as vent temperature, heat output, and vent field area, together with surface area and depth of the sub-axial magma chamber, to deduce fundamental hydrothermal parameters such as mass flow rate, bulk permeability, conductive boundary layer thickness at the base of the system, magma replenishment rate, and residence time in the discharge zone. All of these key subsurface characteristics are known for fewer than 10 sites out of 300 known hydrothermal systems. The principal limitations of this approach stem from the uncertainty in heat output and vent field area. For systems where data are available on partitioning of heat and chemical output between focused and diffuse flow, we determined the fraction of high-temperature vent fluid incorporated into diffuse flow using a two-limb single pass model. For EPR 9°50` N and ASHES, the diffuse flow temperatures calculated assuming conservative mixing are nearly equal to the observed temperatures indicating that approximately 80%-90% of the hydrothermal heat output occurs as high-temperature flow derived from magmatic heat even though most of the heat output appears as low-temperature diffuse discharge. For the Main Endeavour Field and Lucky Strike, diffuse flow fluids show significant conductive cooling and heating respectively. Finally, we calculate the transport of various geochemical constituents in focused and diffuse flow at the vent field scale and compare the results with estimates of geochemical transports from the Rainbow hydrothermal field where diffuse flow is absent.
Tang, Kai; Zhang, Yao; Lin, Dan; Han, Yu; Chen, Chen-Tung A.; Wang, Deli; Lin, Yu-Shih; Sun, Jia; Zheng, Qiang; Jiao, Nianzhi
2018-01-01
Shallow-sea hydrothermal systems experience continuous fluctuations of physicochemical conditions due to seawater influx which generates variable habitats, affecting the phylogenetic composition and metabolic potential of microbial communities. Until recently, studies of submarine hydrothermal communities have focused primarily on chemolithoautotrophic organisms, however, there have been limited studies on heterotrophic bacteria. Here, fluorescence in situ hybridization, high throughput 16S rRNA gene amplicon sequencing, and functional metagenomes were used to assess microbial communities from the shallow-sea hydrothermal system off Kueishantao Island, Taiwan. The results showed that the shallow-sea hydrothermal system harbored not only autotrophic bacteria but abundant heterotrophic bacteria. The potential for marker genes sulfur oxidation and carbon fixation were detected in the metagenome datasets, suggesting a role for sulfur and carbon cycling in the shallow-sea hydrothermal system. Furthermore, the presence of diverse genes that encode transporters, glycoside hydrolases, and peptidase indicates the genetic potential for heterotrophic utilization of organic substrates. A total of 408 cultivable heterotrophic bacteria were isolated, in which the taxonomic families typically associated with oligotrophy, copiotrophy, and phototrophy were frequently found. The cultivation-independent and -dependent analyses performed herein show that Alphaproteobacteria and Gammaproteobacteria represent the dominant heterotrophs in the investigated shallow-sea hydrothermal system. Genomic and physiological characterization of a novel strain P5 obtained in this study, belonging to the genus Rhodovulum within Alphaproteobacteria, provides an example of heterotrophic bacteria with major functional capacity presented in the metagenome datasets. Collectively, in addition to autotrophic bacteria, the shallow-sea hydrothermal system also harbors many heterotrophic bacteria with versatile genetic potential to adapt to the unique environmental conditions. PMID:29527196
Phreatic activity and hydrothermal alteration in the Valley of Desolation, Dominica, Lesser Antilles
NASA Astrophysics Data System (ADS)
Mayer, Klaus; Scheu, Bettina; Yilmaz, Tim I.; Montanaro, Cristian; Albert Gilg, H.; Rott, Stefanie; Joseph, Erouscilla P.; Dingwell, Donald B.
2017-12-01
Phreatic eruptions are possibly the most dramatic surface expressions of hydrothermal activity, and they remain poorly understood. The near absence of precursory signals makes phreatic eruptions unpredictable with respect to both time and magnitude. The Valley of Desolation (VoD), Dominica, located close to the Boiling Lake, the second largest high-temperature volcanic crater lake in the world, hosts vigorous hydrothermal activity with hot springs, mud pools, fumaroles, and steaming ground. A phreatic or phreatomagmatic eruption from this site is considered to be the most likely scenario for future volcanic activity on Dominica. Yet there is little information regarding the trigger mechanisms and eruption processes of explosive events at this active hydrothermal center, and only a very small number of studies have investigated hydrothermal activity in the VoD. We therefore conducted two field campaigns in the VoD to map hydrothermal activity and its surficial phenomena. We also investigated alteration processes and their effects on degassing and phreatic eruption processes. We collected in situ petrophysical properties of clay-rich unconsolidated samples, and together with consolidated rock samples, we investigated the range of supergene and hydrothermal alteration in the laboratory. In addition, we performed rapid decompression experiments on unconsolidated soil samples. Our results show that alteration leads to an increasing abundance of clay minerals and a decrease in both strength and permeability of the rocks. In the immediate vicinity of degassing acid-sulfate fluids, advanced argillic alteration yields a mineral zoning which is influenced by meteoric water. The water-saturated basal zone is dominated by kaolinite run 0whereas alunite formation is favored at and above the groundwater table where atmospheric oxidation of H2S to H2SO4 occurs (e.g., steam-heated alteration). Alteration effects may in turn inhibit degassing at the surface, increasing the potential for pressurization in the subsurface and thus lead to phreatic eruptions. Rapid decompression experiments, together with ballistic trajectory calculations, constrain estimates of the conditions prior to the 1997 small-scale phreatic event in the VoD. The results presented here may serve as a contribution to the understanding of the hazard potential of ongoing hydrothermal activity within the VoD. On a broader perspective, our results will help evaluate hydrothermal activity in similar areas worldwide which might also have the potential for phreatic eruptions, for instance Poas (Costa Rica) or Tongariro and Waimangu (New Zealand).
NASA Astrophysics Data System (ADS)
Canet, Carles; Trillaud, Frederic; Prol-Ledesma, Rosa María; González-Hernández, Galia; Peláez, Berenice; Hernández-Cruz, Berenice; Sánchez-Córdova, María M.
2015-10-01
Acoculco is a geothermal prospective area hosted by a volcanic caldera complex in the eastern Trans-Mexican Volcanic Belt. Surface manifestations are scarce and consist of gas discharges (CO2-rich) and acid-sulfate springs of low temperature, whereas hydrothermal explosive activity is profusely manifested by meter-scale craters and mounds of hydrothermal debris and breccias. Silicic alteration extends for several square kilometers around the zone with gas manifestations and explosive features, affecting surficial volcanic rocks, primarily tuffs and breccias. In the subsurface, an argillic alteration zone (ammonium illite) extends down to a depth of ∼ 600 m, and underneath it a propylitic zone (epidote-calcite-chlorite) occurs down to ∼ 1000 m. Thermal logs from an exploratory borehole (EAC-1, drilled in 1995 down to 1810 m) showed a conductive heat transfer regime under high geothermal gradient (∼ 140 °C/1000 m). In contrast, the thermal profile established from temperatures of homogenization of fluid inclusions-measured on core samples from the same drill hole-suggests that convection occurred in the past through the upper ~ 1400 m of the geothermal system. A drop in permeability due to the precipitation of alteration minerals would have triggered the cessation of the convective heat transfer regime to give place to a conductive one. With the purpose of determining when the transition of heat transfer regime occurred, we developed a 1D model that simulates the time-depth distribution of temperature. According to our numerical simulations, this transition happened ca. 7000 years ago; this date is very recent compared to the lifespan of the geothermal system. In addition, radiocarbon chronology indicates that the hydrothermal explosive activity postdates the end of the convective heat transfer regime, having dated at least three explosive events, at 4867-5295, 1049-1417 and 543-709 y cal. BP. Therefore, hydrothermal explosions arise from the self-sealing of the Acoculco geothermal system, involving a natural hazard that could affect future geothermal-power infrastructure.
NASA Astrophysics Data System (ADS)
Chen, Zhixin; Li, Danzhen; Xiao, Guangcan; He, Yunhui; Xu, Yi-Jun
2012-02-01
Marigold-like ZnIn2S4 microspheres were synthesized by a microwave-assisted hydrothermal method with the temperature ranging from 80 to 195 °C. X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen sorption analysis, UV-visible spectroscopy, scanning electron microscopy and transmission electron microscopy were used to characterize the products. It was found that the crystallographic structure and optical property of the products synthesized at different temperatures were almost the same. The degradation of methyl orange (MO) under the visible light irradiation has been used as a probe reaction to investigate the photocatalytic activity of as-prepared ZnIn2S4, which shows that the ZnIn2S4 sample synthesized at 195 °C shows the best photocatalytic activity for MO degradation. In addition, the photocatalytic activities of all the samples prepared by the microwave-assisted hydrothermal method are better than those prepared by a normal hydrothermal method, which could be attributed to the formation of more defect sites during the microwave-assisted hydrothermal treatment.
NASA Astrophysics Data System (ADS)
Iizasa, Kokichi; Asada, Akira; Mizuno, Katsunori; Katase, Fuyuki; Lee, Sangkyun; Kojima, Mitsuhiro; Ogawa, Nobuhiro
2018-04-01
Sulfide deposits with extremely high Au concentrations (up to 275 ppm; avg. 102 ppm, n = 15), high Au/Ag ratios (0.24, n = 15), and low Cu/(Cu + Zn) ratios (0.03, n = 15) were discovered in 2015 in active hydrothermal fields at a water depth of 760 m in a basalt-dominated submarine caldera in the Izu-Ogasawara frontal arc, Japan. Native gold grains occur in massive sulfide fragments, concretions, and metalliferous sediments from a sulfide mound (40 m across and 20 m high) with up to 30-m-high black smoker chimneys. Tiny native gold grains up to 14 μm in diameter are mainly present in sulfide fallouts from chimney orifices and plumes. Larger native gold grains up to 150 μm long occur mostly as discrete particles and/or with amorphous silica and sulfides. The larger gold grains are interpreted to represent direct precipitation from Au-bearing hydrothermal fluids circulating in and/or beneath the unconsolidated sulfide mound deposits. Sulfur isotope compositions from a limited number of sulfide separates (n = 4) range from 4.3 to 5.8‰ δ34S, similar to the quaternary volcanic rocks of the arc. Barite separates have values of 22.2 and 23.1‰, close to modern seawater values, and indicate probable seawater sulfate origin. The Cu, Zn, and Pb concentrations in bulk samples of sulfide-rich rocks are similar to those of volcanogenic massive sulfides formed in continental crustal environments. The gold is interpreted to have formed by low-temperature hydrothermal activity, perhaps genetically different from systems with documented magmatic contributions or from seafloor hydrothermal systems in other island arc settings. Its presence suggests that basalt-dominated submarine calderas situated on relatively thick continental crust in an intraoceanic arc setting such as the Higashi-Aogashima knoll caldera may be perspective for gold mineralization.
Tempo of magma degassing and the genesis of porphyry copper deposits.
Chelle-Michou, Cyril; Rottier, Bertrand; Caricchi, Luca; Simpson, Guy
2017-01-12
Porphyry deposits are copper-rich orebodies formed by precipitation of metal sulphides from hydrothermal fluids released from magmatic intrusions that cooled at depth within the Earth's crust. Finding new porphyry deposits is essential because they are our largest source of copper and they also contain other strategic metals including gold and molybdenum. However, the discovery of giant porphyry deposits is hindered by a lack of understanding of the factors governing their size. Here, we use thermal modelling and statistical simulations to quantify the tempo and the chemistry of fluids released from cooling magmatic systems. We confirm that typical arc magmas produce fluids similar in composition to those that form porphyry deposits and conclude that the volume and duration of magmatic activity exert a first order control on the endowment (total mass of deposited copper) of economic porphyry copper deposits. Therefore, initial magma enrichment in copper and sulphur, although adding to the metallogenic potential, is not necessary to form a giant deposit. Our results link the respective durations of magmatic and hydrothermal activity from well-known large to supergiant deposits to their metal endowment. This novel approach can readily be implemented as an additional exploration tool that can help assess the economic potential of magmatic-hydrothermal systems.
Tempo of magma degassing and the genesis of porphyry copper deposits
Chelle-Michou, Cyril; Rottier, Bertrand; Caricchi, Luca; Simpson, Guy
2017-01-01
Porphyry deposits are copper-rich orebodies formed by precipitation of metal sulphides from hydrothermal fluids released from magmatic intrusions that cooled at depth within the Earth’s crust. Finding new porphyry deposits is essential because they are our largest source of copper and they also contain other strategic metals including gold and molybdenum. However, the discovery of giant porphyry deposits is hindered by a lack of understanding of the factors governing their size. Here, we use thermal modelling and statistical simulations to quantify the tempo and the chemistry of fluids released from cooling magmatic systems. We confirm that typical arc magmas produce fluids similar in composition to those that form porphyry deposits and conclude that the volume and duration of magmatic activity exert a first order control on the endowment (total mass of deposited copper) of economic porphyry copper deposits. Therefore, initial magma enrichment in copper and sulphur, although adding to the metallogenic potential, is not necessary to form a giant deposit. Our results link the respective durations of magmatic and hydrothermal activity from well-known large to supergiant deposits to their metal endowment. This novel approach can readily be implemented as an additional exploration tool that can help assess the economic potential of magmatic-hydrothermal systems. PMID:28079160
Mineralized iron oxidizing bacteria from hydrothermal vents: targeting biosignatures on Mars
NASA Astrophysics Data System (ADS)
Leveille, R. J.
2010-12-01
Putative hydrothermal systems have been identified on Mars based on orbital imagery and rover-based analyses. Based on Earth analogs, hydrothermal systems on Mars would be highly attractive for their potential for preserving organic and inorganic biosignatures. For example, iron oxidizing bacteria are ubiquitous in marine and terrestrial hydrothermal systems, where they often display distinctive cell morphologies and are commonly encrusted by minerals, especially bacteriogenic iron oxides and silica. Microfossils of iron oxidizing bacteria have been found in ancient Si-Fe deposits and iron oxidation may be an ancient and widespread metabolic pathway. In order to investigate mineralized iron oxidizing bacteria as a biosignature, we have examined samples collected from extinct hydrothermal vents along Explorer Ridge, NE Pacific Ocean. In addition, microaerophilic iron oxidizing bacteria, isolated from active Pacific hydrothermal vents, were grown in a Fe-enriched seawater medium at constant pH (6.5) and O2 concentration (5%) in a controlled bioreactor system. Samples and experimental products were examined with a combination of variable-pressure and field-emission scanning electron microscopy (SEM), in some cases by preparing samples with a focused ion beam (FIB) milling system. Light-toned seafloor samples display abundant filamentous forms resembling, in both size and shape (1-5 microns in diameter and up to several microns in length), the twisted stalks of Gallionella and the elongated filaments of Leptothrix. Some samples consist entirely of low-density masses of silica (>90% Si) encrusted filamentous forms. The presence of unmineralized filamentous matter rich in C and Fe suggests that these are the remains of iron oxidizing bacteria. Mineralized filaments sectioned by FIB show variable internal material within semi-hollow, tubular-like features. Silica encrustations also show pseudo-concentric growth bands. In the bioreactor runs, abundant microbial growth and formation of an iron oxyhydroxide precipitate, either in direct association with the cells or within the growth medium, were observed. Preliminary analyses suggest that these precipitates are different from abiotic precipitates. Continuing work includes high-resolution TEM observations of cultured organisms and biogenic iron minerals, Raman and reflectance spectroscopy of precipitates, examination of seafloor incubation experiments, and bioreactor silicification experiments in order to better understand the Fe-Si fossilization process. Microaerophilic iron oxidation could have existed on the early Earth in environments containing small amounts of oxygen produced either by locally-concentrated photosynthetic microorganisms (e.g., cyanobacteria) or by chemical reactions. By analogy, similar subsurface or near-surface microaerophilic environments could have existed on Mars in the past, including in low-temperature hydrothermal systems. The distinctive morphologies and Fe-Si mineralization patterns of iron oxidizing bacteria could be a useful biosignature to search for on Mars. Deposits and features similar to those described here could be identified on Mars with existing technologies, and thus hydrothermal systems represent an attractive target for future surface and sample return missions.
NASA Astrophysics Data System (ADS)
Maussen, Katharine; Villacorte, Edgardo; Rebadulla, Ryan R.; Maximo, Raymond Patrick; Debaille, Vinciane; Bornas, Ma. Antonia; Bernard, Alain
2018-02-01
Taal volcano (Luzon Island, Philippines) has last erupted in 1977 but has known some periods of increased activity, characterised by seismic swarms, ground deformation, increased carbon dioxide flux and in some cases temperature anomalies and the opening of fissures. We studied major, trace element and sulphur and strontium isotopic composition of Taal lake waters and hot springs over a period of 25 years to investigate the geochemical evolution of Taal volcano's hydrothermal system and its response to volcanic unrest. Long-term evolution of Main Crater Lake (MCL) composition shows a slow but consistent decrease of acidity, SO4, Mg, Fe and Al concentrations and a trend from light to heavy sulphate, consistent with a general decrease of volcanic gases dissolving in the hydrothermal system. Na, K and Cl concentrations remain constant indicating a non-volcanic origin for these elements. Sulphate and strontium isotopic data suggest this neutral chloride-rich component represents input of geothermal water into Taal hydrothermal system. A significant deviation from the long-term baseline can be seen in two samples from 1995. That year, pH dropped from 2.6 to 2.2, F, Si and Fe concentrations increased and Na, K and Cl concentrations decreased. Sulphate was depleted in 34S and temperature was 4 °C above baseline level at the time of sampling. We attribute these changes to the shallow intrusion of a degassing magma body during the unrest in 1991-1994. More recent unrest periods have not caused significant changes in the geochemistry of Taal hydrothermal waters and are therefore unlikely to have been triggered by shallow magma intrusion. A more likely cause for these events is thus pressurisation of the hydrothermal reservoir by increasing degassing from a stagnant magma reservoir. Our study indicates that new magmatic intrusions that might lead to the next eruption of Taal volcano are expected to change the geochemistry of MCL in the same way as in 1994-1995, with the most notable effects being changes in temperature, pH, F and Si concentrations.
NASA Astrophysics Data System (ADS)
Kissling, W. M.; Villamor, P.; Ellis, S. M.; Rae, A.
2018-05-01
Present-day geothermal activity on the margins of the Ngakuru graben and evidence of fossil hydrothermal activity in the central graben suggest that a graben-wide system of permeable intersecting faults acts as the principal conduit for fluid flow to the surface. We have developed numerical models of fluid and heat flow in a regional-scale 2-D cross-section of the Ngakuru Graben. The models incorporate simplified representations of two 'end-member' fault architectures (one symmetric at depth, the other highly asymmetric) which are consistent with the surface locations and dips of the Ngakuru graben faults. The models are used to explore controls on buoyancy-driven convective fluid flow which could explain the differences between the past and present hydrothermal systems associated with these faults. The models show that the surface flows from the faults are strongly controlled by the fault permeability, the fault system architecture and the location of the heat source with respect to the faults in the graben. In particular, fault intersections at depth allow exchange of fluid between faults, and the location of the heat source on the footwall of normal faults can facilitate upflow along those faults. These controls give rise to two distinct fluid flow regimes in the fault network. The first, a regular flow regime, is characterised by a nearly unchanging pattern of fluid flow vectors within the fault network as the fault permeability evolves. In the second, complex flow regime, the surface flows depend strongly on fault permeability, and can fluctuate in an erratic manner. The direction of flow within faults can reverse in both regimes as fault permeability changes. Both flow regimes provide insights into the differences between the present-day and fossil geothermal systems in the Ngakuru graben. Hydrothermal upflow along the Paeroa fault seems to have occurred, possibly continuously, for tens of thousands of years, while upflow in other faults in the graben has switched on and off during the same period. An asymmetric graben architecture with the Paeroa being the major boundary fault will facilitate the predominant upflow along this fault. Upflow on the axial faults is more difficult to explain with this modelling. It occurs most easily with an asymmetric graben architecture and heat sources close to the graben axis (which could be associated with remnant heat from recent eruptions from Okataina Volcanic Centre). Temporal changes in upflow can also be associated with acceleration and deceleration of fault activity if this is considered a proxy for fault permeability. Other explanations for temporal variations in hydrothermal activity not explored here are different permeability on different faults, and different permeability along fault strike.
Porosity evolution in Icelandic hydrothermal systems
NASA Astrophysics Data System (ADS)
Thien, B.; Kosakowski, G.; Kulik, D. A.
2014-12-01
Mineralogical alteration of reservoir rocks, driven by fluid circulation in natural or enhanced hydrothermal systems, is likely to influence the long-term performance of geothermal power generation. A key factor is the change of porosity due to dissolution of primary minerals and precipitation of secondary phases. Porosity changes will affect fluid circulation and solute transport, which, in turn, influence mineralogical alteration. This study is part of the Sinergia COTHERM project (COmbined hydrological, geochemical and geophysical modeling of geotTHERMal systems, grant number CRSII2_141843/1) that is an integrative research project aimed at improving our understanding of the sub-surface processes in magmatically-driven natural geothermal systems. These are typically high enthalphy systems where a magmatic pluton is located at a few kilometers depth. These shallow plutons increase the geothermal gradient and trigger the circulation of hydrothermal waters with a steam cap forming at shallow depth. Field observations suggest that active and fossil Icelandic hydrothermal systems are built from a superposition of completely altered and completely unaltered layers. With help of 1D and 2D reactive transport models (OpenGeoSys-GEM code), we investigate the reasons for this finding, by studying the mineralogical evolution of protoliths with different initial porosities at different temperatures and pressures, different leaching water composition and gas content, and different porosity geometries (i.e. porous medium versus fractured medium). From this study, we believe that the initial porosity of protoliths and volume changes due to their transformation into secondary minerals are key factors to explain the different alteration extents observed in field studies. We also discuss how precipitation and dissolution kinetics can influence the alteration time scales.
Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi
2012-01-01
To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan’s coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH4) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan. PMID:22970260
Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi
2012-01-01
To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4)) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4) was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4) concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.
Lead recovery from scrap cathode ray tube funnel glass by hydrothermal sulphidisation.
Yuan, Wenyi; Meng, Wen; Li, Jinhui; Zhang, Chenglong; Song, Qingbin; Bai, Jianfeng; Wang, Jingwei; Li, Yingshun
2015-10-01
This research focused on the application of the hydrothermal sulphidisation method to separate lead from scrap cathode ray tube funnel glass. Prior to hydrothermal treatment, the cathode ray tube funnel glass was pretreated by mechanical activation. Under hydrothermal conditions, hydroxyl ions (OH(-)) were generated through an ion exchange reaction between metal ions in mechanically activated funnel glass and water, to accelerate sulphur disproportionation; no additional alkaline compound was needed. Lead contained in funnel glass was converted to lead sulphide with high efficiency. Temperature had a significant effect on the sulphidisation rate of lead in funnel glass, which increased from 25% to 90% as the temperature increased from 100 °C to 300 °C. A sulphidisation rate of 100% was achieved at a duration of 8 h at 300 °C. This process of mechanical activation and hydrothermal sulphidisation is efficient and promising for the treatment of leaded glass. © The Author(s) 2015.
NASA Astrophysics Data System (ADS)
Gillis, Kathryn M.; Thompson, Geoffrey
1993-12-01
An extensive suite of hydrothermally altered rocks were recovered by Alvin and dredging along the MARK [Mid-Atlantic Ridge, south of the Kane Fracture Zone (23 24°N)] where detachment faulting has provided a window into the crustal component of hydrothermal systems. Rocks of basaltic composition are altered to two assemblages with these characteristics: (i) type I: albitic plagioclase (An02 10)+mixed-layer smectite/chlorite or chlorite±actinolite±quartz±sphene, <10% of the clinopyroxene is altered, and there is no trace metal mobility; (ii) type II: plagioclase (An10 30)+amphibole (actinolite-magnesio-hornblende) +chlorite+sphene, >20% of the clinopyroxene is altered, and Cu and Zn are leached. The geochemical signature of these alteration types reflects the relative proportion and composition of secondary minerals, and the degree of alteration of primary phases, and does not show simple predictive relationships. Element mobilities indicate that both alteration types formed at low water/rock ratios. The MARK assemblages are typical of the greenschist and transition to the amphibolite facies, and represent two distinct, albeit overlapping, temperature regimes: type I-180 to 300°C and type II-250 to 450°C. By analogy with DSDP/ODP Hole 504B and many ophiolites, the MARK metabasalts were altered within the downwelling limb of a hydrothermal cell and type I and II samples formed in the upper and lower portions of the sheeted like complex, respectively. Episodic magmatic and hydrothermal events at slow-spreading ridges suggest that these observed mineral assemblages represent the cumulative effects of more than one hydrothermal event. Groundmass and vein assemblages in the MARK metabasalts indicate either that alteration conditions did not change during successive hydrothermal events or that these assemblages record only the highest temperature event. Lack of retrograde reactions or overprinting of lower temperature assemblages (e.g., zeolites) suggests that there is a continuum in alteration conditions while crustal segments remain in the ridge axis environment. The type II samples may be representative of the reaction zone where compositions of hydrothermal fluids actively venting at the seafloor today become fixed. This prediction necessitates interaction between hydrothermal fluids and intersertal glass and/or mafic phases, in addition to plagioclase, in order to produce the observed range in vented fluid pH.
NASA Astrophysics Data System (ADS)
Chen, Xue-Gang; Lyu, Shuang-Shuang; Zhang, Ping-Ping; Yu, Ming-Zhen; Chen, Chen-Tung Arthur; Chen, Yun-Jie; Li, Xiaohu; Jin, Aimin; Zhang, Hai-Yan; Duan, Wei; Ye, Ying
2018-03-01
The chemical compositions of gas discharges from the Kueishantao (KST) hydrothermal field changed dramatically from 2000 to 2014. In this study, we established a gas mixing model for the KST gases. The N2, Ar, and CO2 contents were mixed from a magmatic endmember with CO2 of about 990 mmol/mol, a hydrothermal and an atmospheric endmember enriched in N2 and Ar. More than 71% KST gas components were mantle-derived/magmatic. The calculated endmember N2/Ar ratio and Ar contents of the hydrothermal endmember (percolated fluid) are about 140 and 5.28-5.52 mmol/mol, respectively. This relatively elevated N2/Ar ratio was probably caused by the thermogenic addition of N2. The log(CH4/CO2) values of the KST gas samples correlate well with the mixing temperature that estimated from the mixing ratio between the percolated fluid and the magmatic endmember. It is indicated that the KST CH4 and CO2 may have attained chemical equilibrium. The temporal variations of the KST gas compositions are determined by the mixing ratio, which is dependent on the magmatic activity underneath the KST field. With the decreasing of magmatic activity since 2005, the proportion of the hydrothermal endmember increased, along with the increasing of N2, Ar, and CH4 contents. This study proposed an effective model to quantitatively assess the sources of gas components discharged from submarine hydrothermal vents. In addition, it is suggested that the mixing between a magmatic and a hydrothermal endmember may play an important role in the concentrations of CO2 and CH4 in hydrothermal gas discharges.
Alanis, Paul K B; Yamaya, Yusuke; Takeuchi, Akihiro; Sasai, Yoichi; Okada, Yoshihiro; Nagao, Toshiyasu
2013-01-01
Taal Volcano is one of the most active volcanoes in the Philippines. The magnetotelluric 3D forward analyses indicate the existence of a large high resistivity anomaly (∼100 Ω·m) with a volume of at least 3 km×3 km×3 km, which is capped by a conductive layer (∼10 Ω·m), beneath the Main Crater. This high resistivity anomaly is hypothesized to be a large hydrothermal reservoir, consisting of the aggregate of interconnected cracks in rigid and dense host rocks, which are filled with hydrothermal fluids coming from a magma batch below the reservoir. The hydrothermal fluids are considered partly in gas phase and liquid phase. The presence of such a large hydrothermal reservoir and the stagnant magma below may have influences on the volcano's activity. Two possibilities are presented. First, the 30 January 1911 explosion event was a magmatic hydrothermal eruption rather than a base-surge associated with a phreato-magmatic eruption. Second, the earlier proposed four eruption series may be better interpreted by two cycles, each consisting of series of summit and flank eruptions.
ALANIS, Paul K. B.; YAMAYA, Yusuke; TAKEUCHI, Akihiro; SASAI, Yoichi; OKADA, Yoshihiro; NAGAO, Toshiyasu
2013-01-01
Taal Volcano is one of the most active volcanoes in the Philippines. The magnetotelluric 3D forward analyses indicate the existence of a large high resistivity anomaly (∼100 Ω·m) with a volume of at least 3 km × 3 km × 3 km, which is capped by a conductive layer (∼10 Ω·m), beneath the Main Crater. This high resistivity anomaly is hypothesized to be a large hydrothermal reservoir, consisting of the aggregate of interconnected cracks in rigid and dense host rocks, which are filled with hydrothermal fluids coming from a magma batch below the reservoir. The hydrothermal fluids are considered partly in gas phase and liquid phase. The presence of such a large hydrothermal reservoir and the stagnant magma below may have influences on the volcano’s activity. Two possibilities are presented. First, the 30 January 1911 explosion event was a magmatic hydrothermal eruption rather than a base-surge associated with a phreato-magmatic eruption. Second, the earlier proposed four eruption series may be better interpreted by two cycles, each consisting of series of summit and flank eruptions. PMID:24126286
Urabe, T; Baker, E T; Ishibashi, J; Feely, R A; Marumo, K; Massoth, G J; Maruyama, A; Shitashima, K; Okamura, K; Lupton, J E; Sonoda, A; Yamazaki, T; Aoki, M; Gendron, J; Greene, R; Kaiho, Y; Kisimoto, K; Lebon, G; Matsumoto, T; Nakamura, K; Nishizawa, A; Okano, O; Paradis, G; Roe, K; Shibata, T; Tennant, D; Vance, T; Walker, S L; Yabuki, T; Ytow, N
1995-08-25
A survey of hydrothermal activity along the superfast-spreading (approximately 150 millimeters per year) East Pacific Rise shows that hydrothermal plumes overlay approximately 60 percent of the ridge crest between 13 degrees 50' and 18 degrees 40'S, a plume abundance nearly twice that known from any other rige portion of comparable length. Plumes were most abundant where the axial cross section is inflated and an axial magma chamber is present. Plumes with high ratios of volatile ((3)He, CH(4), and H(2)S) to nonvolatile (Mn and Fe) species marked where hydrothermal circulation has been perturbed by recent magmatic activity. The high proportion of volatile-rich plumes observed implies that such episodes are more frequent here than on slower spreading ridges.
Soil-plant-microbial relations in hydrothermally altered soils of Northern California
USDA-ARS?s Scientific Manuscript database
Soils developed on relict hydrothermally altered soils throughout the Western United States present unique opportunities to study the role of geology on above and belowground biotic activity and composition. Soil and vegetation samples were taken at three unaltered andesite and three hydrothermally ...
NASA Astrophysics Data System (ADS)
Montanaro, Cristian; Mayer, Klaus; Isaia, Roberto; Gresse, Marceau; Scheu, Bettina; Yilmaz, Tim I.; Vandemeulebrouck, Jean; Ricci, Tullio; Dingwell, Donald B.
2017-12-01
The Solfatara area and its fumaroles are the main surface expression of the vigorous hydrothermal activity within the active Campi Flegrei caldera system. At depth, a range of volcanic and structural processes dictate the actual state of the hydrothermal system below the crater. The presence of a large variety of volcanic products at shallow depth (including pyroclastic fallout ash beds, pyroclastic density current deposits, breccias, and lavas), and the existence of a maar-related fault system appears to exert major controls on the degassing and alteration behavior. Adding further to the complexity of this environment, variations in permeability and porosity, due to subsoil lithology and alteration effects, may further influence fluid flow towards the surface. Here, we report results from a field campaign conducted in July 2015 that was designed to characterize the in situ physical (temperature, humidity) and mechanical (permeability, strength, stiffness) properties of the Solfatara crater subsoil. The survey also included a mapping of the surficial hydrothermal features and their distributions. Finally, laboratory measurements (porosity, granulometry) of selected samples were performed. Our results enable the discrimination of four main subsoils around the crater: (1) the Fangaia domain located in a topographic low in the southwestern sector, (2) the silica flat domain on the western altered side, (3) the new crust domain in the central area, and (4) the crusted hummocks domain that dominates the north, east, and south parts. These domains are surrounded by encrusted areas, reworked material, and vegetated soil. The distribution of these heterogeneous subsoils suggests that their formation is mostly related to (i) the presence of the Fangaia domain within the crater and (ii) a system of ring faults bordering it. The subsoils show an alternation between very high and very low permeabilities, a fact which seems to affect both the temperature distribution and surficial degassing. A large range of surface temperatures (from 25 up to 95 °C) has been measured across these surfaces, with the hottest spot corresponding to the mud pools, the area of new crust formation, and the crusted hummocks. In the subsoil, the distribution of temperature is more complex and controlled by the presence of coarser, and more permeable, sandy/pebbly levels. These act as preferential pathways for hot hydrothermal fluid circulation. In contrast, low permeability, fine-grained levels act as thermal insulators that remain relatively cold and hinder fluid escape to the surface. Hot gases reach the surface predominantly along (vertical) fractures. When this occurs, mound-like structures can be formed by a cracking and healing process associated with significant degassing. It is anticipated that the results presented here may contribute to an improved understanding of the hazard potential associated with the ongoing hydrothermal activity within the Solfatara crater. At this site the permeability of the near-surface environment and its changes in space and time can affect the spatial and temporal distribution of gas and heat emission. Particularly, in areas where reduction in permeability occurs, it can produce pore pressure augmentation that may result in explosive events.
Li, Meng; Jain, Sunit; Dick, Gregory J
2016-01-01
Microbial chemosynthesis within deep-sea hydrothermal vent plumes is a regionally important source of organic carbon to the deep ocean. Although chemolithoautotrophs within hydrothermal plumes have attracted much attention, a gap remains in understanding the fate of organic carbon produced via chemosynthesis. In the present study, we conducted shotgun metagenomic and metatranscriptomic sequencing on samples from deep-sea hydrothermal vent plumes and surrounding background seawaters at Guaymas Basin (GB) in the Gulf of California. De novo assembly of metagenomic reads and binning by tetranucleotide signatures using emergent self-organizing maps (ESOM) revealed 66 partial and nearly complete bacterial genomes. These bacterial genomes belong to 10 different phyla: Actinobacteria, Bacteroidetes, Chloroflexi, Deferribacteres, Firmicutes, Gemmatimonadetes, Nitrospirae, Planctomycetes, Proteobacteria, Verrucomicrobia. Although several major transcriptionally active bacterial groups (Methylococcaceae, Methylomicrobium, SUP05, and SAR324) displayed methanotrophic and chemolithoautotrophic metabolisms, most other bacterial groups contain genes encoding extracellular peptidases and carbohydrate metabolizing enzymes with significantly higher transcripts in the plume than in background, indicating they are involved in degrading organic carbon derived from hydrothermal chemosynthesis. Among the most abundant and active heterotrophic bacteria in deep-sea hydrothermal plumes are Planctomycetes, which accounted for seven genomes with distinct functional and transcriptional activities. The Gemmatimonadetes and Verrucomicrobia also had abundant transcripts involved in organic carbon utilization. These results extend our knowledge of heterotrophic metabolism of bacterial communities in deep-sea hydrothermal plumes.
Li, Meng; Jain, Sunit; Dick, Gregory J.
2016-01-01
Microbial chemosynthesis within deep-sea hydrothermal vent plumes is a regionally important source of organic carbon to the deep ocean. Although chemolithoautotrophs within hydrothermal plumes have attracted much attention, a gap remains in understanding the fate of organic carbon produced via chemosynthesis. In the present study, we conducted shotgun metagenomic and metatranscriptomic sequencing on samples from deep-sea hydrothermal vent plumes and surrounding background seawaters at Guaymas Basin (GB) in the Gulf of California. De novo assembly of metagenomic reads and binning by tetranucleotide signatures using emergent self-organizing maps (ESOM) revealed 66 partial and nearly complete bacterial genomes. These bacterial genomes belong to 10 different phyla: Actinobacteria, Bacteroidetes, Chloroflexi, Deferribacteres, Firmicutes, Gemmatimonadetes, Nitrospirae, Planctomycetes, Proteobacteria, Verrucomicrobia. Although several major transcriptionally active bacterial groups (Methylococcaceae, Methylomicrobium, SUP05, and SAR324) displayed methanotrophic and chemolithoautotrophic metabolisms, most other bacterial groups contain genes encoding extracellular peptidases and carbohydrate metabolizing enzymes with significantly higher transcripts in the plume than in background, indicating they are involved in degrading organic carbon derived from hydrothermal chemosynthesis. Among the most abundant and active heterotrophic bacteria in deep-sea hydrothermal plumes are Planctomycetes, which accounted for seven genomes with distinct functional and transcriptional activities. The Gemmatimonadetes and Verrucomicrobia also had abundant transcripts involved in organic carbon utilization. These results extend our knowledge of heterotrophic metabolism of bacterial communities in deep-sea hydrothermal plumes. PMID:27512389
Pop Ristova, Petra; Pichler, Thomas; Friedrich, Michael W; Bühring, Solveig I
2017-01-01
Shallow-water hydrothermal systems represent extreme environments with unique biogeochemistry and high biological productivity, at which autotrophic microorganisms use both light and chemical energy for the production of biomass. Microbial communities of these ecosystems are metabolically diverse and possess the capacity to transform a large range of chemical compounds. Yet, little is known about their diversity or factors shaping their structure or how they compare to coastal sediments not impacted by hydrothermalism. To this end, we have used automated ribosomal intergenic spacer analysis (ARISA) and high-throughput Illumina sequencing combined with porewater geochemical analysis to investigate microbial communities along geochemical gradients in two shallow-water hydrothermal systems off the island of Dominica (Lesser Antilles). At both sites, venting of hydrothermal fluids substantially altered the porewater geochemistry by enriching it with silica, iron and dissolved inorganic carbon, resulting in island-like habitats with distinct biogeochemistry. The magnitude of fluid flow and difference in sediment grain size, which impedes mixing of the fluids with seawater, were correlated with the observed differences in the porewater geochemistry between the two sites. Concomitantly, individual sites harbored microbial communities with a significantly different community structure. These differences could be statistically linked to variations in the porewater geochemistry and the hydrothermal fluids. The two shallow-water hydrothermal systems of Dominica harbored bacterial communities with high taxonomical and metabolic diversity, predominated by heterotrophic microorganisms associated with the Gammaproteobacterial genera Pseudomonas and Pseudoalteromonas , indicating the importance of heterotrophic processes. Overall, this study shows that shallow-water hydrothermal systems contribute substantially to the biogeochemical heterogeneity and bacterial diversity of coastal sediments.
The physical hydrogeology of ore deposits
Ingebritsen, Steven E.; Appold, M.S.
2012-01-01
Hydrothermal ore deposits represent a convergence of fluid flow, thermal energy, and solute flux that is hydrogeologically unusual. From the hydrogeologic perspective, hydrothermal ore deposition represents a complex coupled-flow problem—sufficiently complex that physically rigorous description of the coupled thermal (T), hydraulic (H), mechanical (M), and chemical (C) processes (THMC modeling) continues to challenge our computational ability. Though research into these coupled behaviors has found only a limited subset to be quantitatively tractable, it has yielded valuable insights into the workings of hydrothermal systems in a wide range of geologic environments including sedimentary, metamorphic, and magmatic. Examples of these insights include the quantification of likely driving mechanisms, rates and paths of fluid flow, ore-mineral precipitation mechanisms, longevity of hydrothermal systems, mechanisms by which hydrothermal fluids acquire their temperature and composition, and the controlling influence of permeability and other rock properties on hydrothermal fluid behavior. In this communication we review some of the fundamental theory needed to characterize the physical hydrogeology of hydrothermal systems and discuss how this theory has been applied in studies of Mississippi Valley-type, tabular uranium, porphyry, epithermal, and mid-ocean ridge ore-forming systems. A key limitation in the computational state-of-the-art is the inability to describe fluid flow and transport fully in the many ore systems that show evidence of repeated shear or tensional failure with associated dynamic variations in permeability. However, we discuss global-scale compilations that suggest some numerical constraints on both mean and dynamically enhanced crustal permeability. Principles of physical hydrogeology can be powerful tools for investigating hydrothermal ore formation and are becoming increasingly accessible with ongoing advances in modeling software.
Pop Ristova, Petra; Pichler, Thomas; Friedrich, Michael W.; Bühring, Solveig I.
2017-01-01
Shallow-water hydrothermal systems represent extreme environments with unique biogeochemistry and high biological productivity, at which autotrophic microorganisms use both light and chemical energy for the production of biomass. Microbial communities of these ecosystems are metabolically diverse and possess the capacity to transform a large range of chemical compounds. Yet, little is known about their diversity or factors shaping their structure or how they compare to coastal sediments not impacted by hydrothermalism. To this end, we have used automated ribosomal intergenic spacer analysis (ARISA) and high-throughput Illumina sequencing combined with porewater geochemical analysis to investigate microbial communities along geochemical gradients in two shallow-water hydrothermal systems off the island of Dominica (Lesser Antilles). At both sites, venting of hydrothermal fluids substantially altered the porewater geochemistry by enriching it with silica, iron and dissolved inorganic carbon, resulting in island-like habitats with distinct biogeochemistry. The magnitude of fluid flow and difference in sediment grain size, which impedes mixing of the fluids with seawater, were correlated with the observed differences in the porewater geochemistry between the two sites. Concomitantly, individual sites harbored microbial communities with a significantly different community structure. These differences could be statistically linked to variations in the porewater geochemistry and the hydrothermal fluids. The two shallow-water hydrothermal systems of Dominica harbored bacterial communities with high taxonomical and metabolic diversity, predominated by heterotrophic microorganisms associated with the Gammaproteobacterial genera Pseudomonas and Pseudoalteromonas, indicating the importance of heterotrophic processes. Overall, this study shows that shallow-water hydrothermal systems contribute substantially to the biogeochemical heterogeneity and bacterial diversity of coastal sediments. PMID:29255454
NASA Astrophysics Data System (ADS)
McConachy, T. F.; Ballard, R. D.; Mottl, M. J.; von Herzen, R. P.
1986-04-01
A hydrothermal vent field, here called the Feather Duster site, occurs on the eastern marginal high near the edge of a narrow (95-m) and shallow (15 20-m) axial graben, within an area dominated by sheet flows and collapse features. The sheet flows are intermediate in relative age between younger fluid-flow lavas on the floor of the axial graben and older pillow (constructional) lavas on the marginal highs. Hydrothermal activity occurs in two zones within a 65 by 45 m area. The main zone is located where a fissure system and sulfide-sulfate chimneys vent warm (9 47 °C) and hot (347 °C) hydrothermal fluids. Here, two mounds of massive sulfide totaling about 200 t are forming. One occurs at the base of a 3-m-high scarp which is the wall of a drained lava lake; the other is perched on top of the scarp. *Present address: Department of Geology, University of Toronto, Toronto, Ontario, Canada M5S 1A1
Rusk, B.G.; Lowers, H.A.; Reed, M.H.
2008-01-01
High-resolution electron microprobe maps show the distribution of Ti, Al, Ca, K, and Fe among quartz growth zones revealed by scanning electron microscope-cathodoluminescence (SEM-CL) from 12 hydrothermal ore deposits formed between ???100 and e1750 ??C. The maps clearly show the relationships between trace elements and CL intensity in quartz. Among all samples, no single trace element consistently correlates with variations in CL intensity. However in vein quartz from five porphyry-Cu (Mo-Au) deposits, CL intensity always correlates positively with Ti concentrations, suggesting that Ti is a CL activator in quartz formed at >400 ??C. Ti concentrations in most rutile-bearing vein quartz from porphyry copper deposits indicate reasonable formation temperatures of 2000 ppm, but in high-temperature quartz, Al concentrations are consistently in the range of several hundred ppm. Aluminum concentrations in quartz refl ect the Al solubility in hydrothermal fluids, which is strongly dependent on pH. Aluminum concentrations in quartz therefore reflect fluctuations in pH that may drive metal-sulfide precipitation in hydrothermal systems. ?? 2008 The Geological Society of America.
Peptide synthesis in early earth hydrothermal systems
Lemke, K.H.; Rosenbauer, R.J.; Bird, D.K.
2009-01-01
We report here results from experiments and thermodynamic calculations that demonstrate a rapid, temperature-enhanced synthesis of oligopeptides from the condensation of aqueous glycine. Experiments were conducted in custom-made hydrothermal reactors, and organic compounds were characterized with ultraviolet-visible procedures. A comparison of peptide yields at 260??C with those obtained at more moderate temperatures (160??C) gives evidence of a significant (13 kJ ?? mol-1) exergonic shift. In contrast to previous hydrothermal studies, we demonstrate that peptide synthesis is favored in hydrothermal fluids and that rates of peptide hydrolysis are controlled by the stability of the parent amino acid, with a critical dependence on reactor surface composition. From our study, we predict that rapid recycling of product peptides from cool into near-supercritical fluids in mid-ocean ridge hydrothermal systems will enhance peptide chain elongation. It is anticipated that the abundant hydrothermal systems on early Earth could have provided a substantial source of biomolecules required for the origin of life. Astrobiology 9, 141-146. ?? 2009 Mary Ann Liebert, Inc. 2009.
Thermohydrodynamic model: Hydrothermal system, shallowly seated magma chamber
NASA Astrophysics Data System (ADS)
Kiryukhin, A. V.
1985-02-01
The results of numerical modeling of heat exchange in the Hawaiian geothermal reservoir demonstrate the possibility of appearance of a hydrothermal system over a magma chamber. This matter was investigated in hydrothermal system. The equations for the conservation of mass and energy are discussed. Two possible variants of interaction between the magma chamber and the hydrothermal system were computated stationary dry magma chamber and dry magma chamber changing volume in dependence on the discharge of magma and taking into account heat exchange with the surrounding rocks. It is shown that the thermal supplying of the hydrothermal system can be ensured by the extraction of heat from a magma chamber which lies at a depth of 3 km and is melted out due to receipt of 40 cubic km of basalt melt with a temperature of 1,300 C. The initial data correspond with computations made with the model to the temperature values in the geothermal reservoir and a natural heat transfer comparable with the actually observed values.
Lack of Microbial Diversity in an Extreme Mars Analog Setting: Poás Volcano, Costa Rica.
Hynek, Brian M; Rogers, Karyn L; Antunovich, Monique; Avard, Geoffroy; Alvarado, Guillermo E
2018-04-24
The Poás volcano in Costa Rica has been studied as a Mars geochemical analog environment, since both the style of hydrothermal alteration present and the alteration mineralogy are consistent with Mars' relict hydrothermal systems. The site hosts an active volcano, with high-temperature fumaroles (up to 980°C) and an ultra-acidic lake. This lake, Laguna Caliente, is one of the most dynamic environments on Earth, with frequent phreatic eruptions, temperatures ranging from near-ambient to almost boiling, a pH range of -1 to 1.5, and a wide range of chemistries and redox potential. Martian acid-sulfate hydrothermal systems were likely similarly dynamic and equally challenging to life. The microbiology existing within Laguna Caliente was characterized for the first time, with sampling taking place in November, 2013. The diversity of the microbial community was surveyed via extraction of environmental DNA from fluid and sediment samples followed by Illumina sequencing of the 16S rRNA gene. The microbial diversity was limited to a single species of the bacterial genus Acidiphilium. This organism likely gets its energy from oxidation of reduced sulfur in the lake, including elemental sulfur. Given Mars' propensity for sulfur and acid-sulfate environments, this type of organism is of significant interest to the search for past or present life on the Red Planet. Key Words: Mars astrobiology-Acid-sulfate hydrothermal systems-Extremophiles-Acidic-High temperature-Acidiphilium bacteria. Astrobiology 18, xxx-xxx.
High-pressure hydrogen respiration in hydrothermal vent samples from the deep biosphere
NASA Astrophysics Data System (ADS)
Morgan-Smith, D.; Schrenk, M. O.
2013-12-01
Cultivation of organisms from the deep biosphere has met with many challenges, chief among them the ability to replicate this extreme environment in a laboratory setting. The maintenance of in situ pressure levels, carbon sources, and gas concentrations are important, intertwined factors which may all affect the growth of subsurface microorganisms. Hydrogen in particular is of great importance in hydrothermal systems, but in situ hydrogen concentrations are largely disregarded in attempts to culture from these sites. Using modified Hungate-type culture tubes (Bowles et al. 2011) within pressure-retaining vessels, which allow for the dissolution of higher concentrations of gas than is possible with other culturing methods, we have incubated hydrothermal chimney and hydrothermally-altered rock samples from the Lost City and Mid-Cayman Rise hydrothermal vent fields. Hydrogen concentrations up to 15 mmol/kg have been reported from Lost City (Kelley et al. 2005), but data are not yet available from the recently-discovered Mid-Cayman site, and the elevated concentration of 30 mmol/kg is being used in all incubations. We are using a variety of media types to enrich for various metabolic pathways including iron and sulfur reduction under anoxic or microaerophilic conditions. Incubations are being carried out at atmospheric (0.1 MPa), in situ (9, 23, or 50 MPa, depending on site), and elevated (50 MPa) pressure levels. Microbial cell concentrations, taxonomic diversity, and metabolic activities are being monitored during the course of these experiments. These experiments will provide insight into the relationships between microbial activities, pressure, and gas concentrations typical of deep biosphere environments. Results will inform further culturing studies from both fresh and archived samples. References cited: Bowles, M.W., Samarkin, V.A., Joye, S.B. 2011. Improved measurement of microbial activity in deep-sea sediments at in situ pressure and methane concentration. Limnology and Oceanography Methods 9:499-506 Kelley, D.S., Karson, J.A., Früh-Green, G.L., Yoerger, D.R., Shank, T.M., et al. 2005. A Serpentinite-Hosted Ecosystem: The Lost City Hydrothermal Field. Science 307:1428-1434
Volcano-ice interaction as a microbial habitat on Earth and Mars.
Cousins, Claire R; Crawford, Ian A
2011-09-01
Volcano-ice interaction has been a widespread geological process on Earth that continues to occur to the present day. The interaction between volcanic activity and ice can generate substantial quantities of liquid water, together with steep thermal and geochemical gradients typical of hydrothermal systems. Environments available for microbial colonization within glaciovolcanic systems are wide-ranging and include the basaltic lava edifice, subglacial caldera meltwater lakes, glacier caves, and subsurface hydrothermal systems. There is widespread evidence of putative volcano-ice interaction on Mars throughout its history and at a range of latitudes. Therefore, it is possible that life on Mars may have exploited these habitats, much in the same way as has been observed on Earth. The sedimentary and mineralogical deposits resulting from volcano-ice interaction have the potential to preserve evidence of any indigenous microbial populations. These include jökulhlaup (subglacial outflow) sedimentary deposits, hydrothermal mineral deposits, basaltic lava flows, and subglacial lacustrine deposits. Here, we briefly review the evidence for volcano-ice interactions on Mars and discuss the geomicrobiology of volcano-ice habitats on Earth. In addition, we explore the potential for the detection of these environments on Mars and any biosignatures these deposits may contain.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lopez-Ruiz, Juan A.; Cooper, Alan R.; Li, Guosheng
Common ketonization catalysts such as ZrO2, CeO2, CexZryOz, and TiO2-based catalysts have been reported to lose surface area, undergo phase-transformation, and lose catalytic activity when utilized in the condensed aqueous phase. In this work, we synthesized and tested a series of LaxZryOz mixed metal oxides with different La:Zr atomic ratios with the goal of enhancing the catalytic activity and stability for the ketonization of acetic acid in condensed aqueous media at 568 K. We synthesized a hydrothermally stable LaxZryOz mixed-metal oxide catalyst with enhanced ketonization activities 360 and 40 times more active than La2O3 and ZrO2, respectively. Catalyst characterization techniquesmore » suggest that the formation of a hydrothermally stable catalyst which is isomorphic with tetragonal-ZrO2 under hydrothermal reaction conditions.« less
NASA Astrophysics Data System (ADS)
Stucker, V. K.; Tivey, M.; Lupton, J. E.; Walker, S. L.; Fornari, D. J.; de Ronde, C. E. J.
2014-12-01
Lake Rotomahana (North Island, New Zealand) is a crater lake with prominent hydrothermal venting. Water column studies were conducted in 2011 and 2014 to complement magnetic, seismic, bathymetric and heat flux surveys, respectively. Results from the heat flow survey indicate that Lake Rotomahana is getting warmer relative to historic measurements, with individual stations within the lake releasing heat in excess of 60 Watts/m2. Helium sources are found at the lake floor at depths of ~50 meters and ~100m. Helium concentrations below 50 m depth have increased with high statistical significance over the three years between surveys and represent some of the highest concentrations ever measured at 6x107 ccSTP/g with an end-member 3He/4He value of 7.1 Ra. Hydrothermal activity comprises a significant portion of the inputs to Lake Rotomahana, as evidenced by δD and δ18O values, as well as ratios of conservative elements such as boron and chloride. Waters collected from lakeshore hot springs show geographic differences in geothermal source temperature using a Na-K geothermometer, with inferred reservoir temperatures ranging from 200 to 230°C. Lake Rotomahana was in part the focus of the 1886 Tarawera eruption; our results show both pre-eruption hydrothermal sites and newly created post-eruption sites are active and should be monitored for continued changes.
New insights into the Kawah Ijen hydrothermal system from geophysical data
Caudron, Corentin; Mauri, G.; Williams-Jones, Glyn; Lecocq, Thomas; Syahbana, Devy Kamil; de Plaen, Raphael; Peiffer, Loic; Bernard, Alain; Saracco, Ginette
2017-01-01
Volcanoes with crater lakes and/or extensive hydrothermal systems pose significant challenges with respect to monitoring and forecasting eruptions, but they also provide new opportunities to enhance our understanding of magmatic–hydrothermal processes. Their lakes and hydrothermal systems serve as reservoirs for magmatic heat and fluid emissions, filtering and delaying the surface expressions of magmatic unrest and eruption, yet they also enable sampling and monitoring of geochemical tracers. Here, we describe the outcomes of a highly focused international experimental campaign and workshop carried out at Kawah Ijen volcano, Indonesia, in September 2014, designed to answer fundamental questions about how to improve monitoring and eruption forecasting at wet volcanoes.
NASA Astrophysics Data System (ADS)
Shao, H.; Yang, S.; Teng, F. Z.; Cai, D.; Humphris, S. E.
2016-12-01
Chlorite is a common alteration product during water-rock reactions in seafloor hydrothermal systems. This chlorite is commonly characterized by high concentrations of magnesium. However, the source of the Mg and its behavior during hydrothermal alteration have yet to be clarified. Mg isotopes have been used in recent years to investigate a variety of geological processes, including low temperature weathering and metamorphism processes, and Mg cycling in sediments. In this study, we investigate the source of Mg and its behavior in chlorite-rich sediments collected during IODP Expedition 331 from the active hydrothermal Iheya North Knoll field in the middle Okinawa Trough — an intra-continental rift in continental crust. This area is characterized by hemipelagic muds with interbedded thick layers of felsic pumiceous volcanic material. Based on mineralogical, geochemical, and isotopic data, we have previously suggested that the chlorite-rich sediments resulted from hydrothermal alteration of the pumiceous layers at temperatures of 220-300°C. Prior to Mg isotope analysis, all selected samples were pretreated with 1N HCl in order to remove carbonates and other unstable minerals, and measurements were made on both the residues (mainly chlorite) and leachates, as well as on bulk samples. The residues are expected to show higher δ26Mg than the leachates reflecting the Mg isotopic signature of the pumiceous material precursor and provide insight into the behavior of Mg isotopes during the high-temperature hydrothermal processes.
NASA Astrophysics Data System (ADS)
Araoka, Daisuke; Nishio, Yoshiro; Gamo, Toshitaka; Yamaoka, Kyoko; Kawahata, Hodaka
2016-10-01
The Li concentration and isotopic composition (δ7Li) in submarine vent fluids are important for oceanic Li budget and potentially useful for investigating hydrothermal systems deep under the seafloor because hydrothermal vent fluids are highly enriched in Li relative to seawater. Although Li isotopic geochemistry has been studied at mid-ocean-ridge (MOR) hydrothermal sites, in arc and back-arc settings Li isotopic composition has not been systematically investigated. Here we determined the δ7Li and 87Sr/86Sr values of 11 end-member fluids from 5 arc and back-arc hydrothermal systems in the western Pacific and examined Li behavior during high-temperature water-rock interactions in different geological settings. In sediment-starved hydrothermal systems (Manus Basin, Izu-Bonin Arc, Mariana Trough, and North Fiji Basin), the Li concentrations (0.23-1.30 mmol/kg) and δ7Li values (+4.3‰ to +7.2‰) of the end-member fluids are explained mainly by dissolution-precipitation model during high-temperature seawater-rock interactions at steady state. Low Li concentrations are attributable to temperature-related apportioning of Li in rock into the fluid phase and phase separation process. Small variation in Li among MOR sites is probably caused by low-temperature alteration process by diffusive hydrothermal fluids under the seafloor. In contrast, the highest Li concentrations (3.40-5.98 mmol/kg) and lowest δ7Li values (+1.6‰ to +2.4‰) of end-member fluids from the Okinawa Trough demonstrate that the Li is predominantly derived from marine sediments. The variation of Li in sediment-hosted sites can be explained by the differences in degree of hydrothermal fluid-sediment interactions associated with the thickness of the marine sediment overlying these hydrothermal sites.
Zimbelman, D.R.; Rye, R.O.; Landis, G.P.
2000-01-01
The edifice of Mount Rainier, an active stratovolcano, has episodically collapsed leading to major debris flows. The largest debris flows are related to argillically altered rock which leave areas of the edifice prone to failure. The argillic alteration results from the neutralization of acidic magmatic gases that condense in a meteoric water hydrothermal system fed by the melting of a thick mantle of glacial ice. Two craters atop a 2000-year-old cone on the summit of the volcano contain the world's largest volcanic ice-cave system. In the spring of 1997 two active fumaroles (T=62°C) in the caves were sampled for stable isotopic, gas, and geochemical studies. Stable isotope data on fumarole condensates show significant excess deuterium with calculated δD and δ18O values (−234 and −33.2‰, respectively) for the vapor that are consistent with an origin as secondary steam from a shallow water table which has been heated by underlying magmatic–hydrothermal steam. Between 1982 and 1997, δD of the fumarole vapor may have decreased by 30‰. The compositions of fumarole gases vary in time and space but typically consist of air components slightly modified by their solubilities in water and additions of CO2 and CH4. The elevated CO2 contents δ13CCO2 = -11.8±0.7‰, with spikes of over 10,000 ppm, require the episodic addition of magmatic components into the underlying hydrothermal system. Although only traces of H2S were detected in the fumaroles, most notably in a sample which had an air δ13CCO2 signature (−8.8‰), incrustations around a dormant vent containing small amounts of acid sulfate minerals (natroalunite, minamiite, and woodhouseite) indicate higher H2S (or possibly SO2) concentrations in past fumarolic gases. Condensate samples from fumaroles are very dilute, slightly acidic, and enriched in elements observed in the much higher temperature fumaroles at Mount St. Helens (K and Na up to the ppm level; metals such as Al, Pb, Zn Fe and Mn up to the ppb level and volatiles such as Cl, S, and F up to the ppb level). The data indicate that the hydrothermal system in the edifice at Mount Rainier consists of meteoric water reservoirs, which receive gas and steam from an underlying magmatic system. At present the magmatic system is largely flooded by the meteoric water system. However, magmatic components have episodically vented at the surface as witnessed by the mineralogy of incrustations around inactive vents and gas compositions in the active fumaroles. The composition of fumarole gases during magmatic degassing is distinct and, if sustained, could be lethal. The extent to which hydrothermal alteration is currently occurring at depth, and its possible influence on future edifice collapse, may be determined with the aid of on site analyses of fumarole gases and seismic monitoring in the ice caves.
Teske, Andreas; de Beer, Dirk; McKay, Luke J.; Tivey, Margaret K.; Biddle, Jennifer F.; Hoer, Daniel; Lloyd, Karen G.; Lever, Mark A.; Røy, Hans; Albert, Daniel B.; Mendlovitz, Howard P.; MacGregor, Barbara J.
2016-01-01
The hydrothermal mats, mounds, and chimneys of the southern Guaymas Basin are the surface expression of complex subsurface hydrothermal circulation patterns. In this overview, we document the most frequently visited features of this hydrothermal area with photographs, temperature measurements, and selected geochemical data; many of these distinct habitats await characterization of their microbial communities and activities. Microprofiler deployments on microbial mats and hydrothermal sediments show their steep geochemical and thermal gradients at millimeter-scale vertical resolution. Mapping these hydrothermal features and sampling locations within the southern Guaymas Basin suggest linkages to underlying shallow sills and heat flow gradients. Recognizing the inherent spatial limitations of much current Guaymas Basin sampling calls for comprehensive surveys of the wider spreading region. PMID:26925032
Hydrothermal reservoir beneath Taal Volcano (Philippines): Implications to volcanic activity
NASA Astrophysics Data System (ADS)
Nagao, T.; Alanis, P. B.; Yamaya, Y.; Takeuchi, A.; Bornas, M. V.; Cordon, J. M.; Puertollano, J.; Clarito, C. J.; Hashimoto, T.; Mogi, T.; Sasai, Y.
2012-12-01
Taal Volcano is one of the most active volcanoes in the Philippines. The first recorded eruption was in 1573. Since then it has erupted 33 times resulting in thousands of casualties and large damages to property. In 1995, it was declared as one of the 15 Decade Volcanoes. Beginning in the early 1990s it has experienced several phases of abnormal activity, including seismic swarms, episodes of ground deformation, ground fissuring and hydrothermal activities, which continues up to the present. However, it has been noted that past historical eruptions of Taal Volcano may be divided into 2 distinct cycles, depending on the location of the eruption center, either at Main Crater or at the flanks. Between 1572-1645, eruptions occurred at the Main Crater, in 1707 to 1731, they occurred at the flanks. In 1749, eruptions moved back to the Main Crater until 1911. During the 1965 and until the end of the 1977 eruptions, eruptive activity once again shifted to the flanks. As part of the PHIVOLCS-JICA-SATREPS Project magnetotelluric and audio-magnetotelluric surveys were conducted on Volcano Island in March 2011 and March 2012. Two-dimensional (2-D) inversion and 3-D forward modeling reveals a prominent and large zone of relatively high resistivity between 1 to 4 kilometers beneath the volcano almost directly beneath the Main Crater, surrounded by zones of relatively low resistivity. This anomalous zone of high resistivity is hypothesized to be a large hydrothermal reservoir filled with volcanic fluids. The presence of this large hydrothermal reservoir could be related to past activities of Taal Volcano. In particular we believe that the catastrophic explosion described during the 1911 eruption was the result of the hydrothermal reservoir collapsing. During the cycle of Main Crater eruptions, this hydrothermal reservoir is depleted, while during a cycle of flank eruptions this reservoir is replenished with hydrothermal fluids.
NASA Astrophysics Data System (ADS)
Shinohara, Hiroshi; Geshi, Nobuo; Yokoo, Akihiko; Ohkura, Takahiro; Terada, Akihiko
2018-03-01
A hot and acid crater lake is located in the Nakadake crater, Aso volcano, Japan. The volume of water in the lake decreases with increasing activity, drying out prior to the magmatic eruptions. Salt-rich materials of various shapes were observed, falling from the volcanic plume during the active periods. In May 2011, salt flakes fell from the gas plume emitted from an intense fumarole when the acid crater lake was almost dry. The chemical composition of these salt flakes was similar to those of the salts formed by the drying of the crater lake waters, suggesting that they originated from the crater lake water. The salt flakes are likely formed by the drying up of the crater lake water droplets sprayed into the plume by the fumarolic gas jet. In late 2014, the crater lake dried completely, followed by the magmatic eruptions with continuous ash eruptions and intermittent Strombolian explosions. Spherical hollow salt shells were observed on several occasions during and shortly after the weak ash eruptions. The chemical composition of the salt shells was similar to the salts formed by the drying of the crater lake water. The hollow structure of the shells suggests that they were formed by the heating of hydrothermal solution droplets suspended by a mixed stream of gas and ash in the plume. The salt shells suggest the existence of a hydrothermal system beneath the crater floor, even during the course of magmatic eruptions. Instability of the magmatic-hydrothermal interface can cause phreatomagmatic explosions, which often occur at the end of the eruptive phase of this volcano.
1998-04-01
Kido •Solution Flow System for Hydrothermal -Electrochemical Synthesis : New Opportunities for Multilayered Oxide Films 639 VI. Suchanek, T...FLOW SYSTEM FOR HYDROTHERMAL -ELECTROCHEMICAL SYNTHESIS : NEW OPPORTUNITIES FOR MULTTLAYERED OXIDE FILMS W. SUCHANEK, T. WATANABE, B. SAKURAI, M...ABSTRACT A solution flow system for hydrothermal -electrochemical synthesis has been constructed in our laboratory. This equipment can operate at 20
NASA Astrophysics Data System (ADS)
Holbrook, W. S.; Carr, B.; Pasquet, S.; Sims, K. W. W.; Dickey, K.
2016-12-01
Despite the prominence of Yellowstone as the world's most active hydrothermal province, relatively little is known about the plumbing systems that link deeper hydrothermal fluids to the charismatic hot springs, geysers and mud pots at the surface. We present the results of a multi-method, multi-scale geophysical investigation of the Obsidian Pool Thermal Area (OPTA) in Yellowstone National Park. OPTA hosts acid-sulfate hot springs and mud pots with relatively low pH. We present the results of seismic refraction, electrical resistivity, time-domain EM (TEM), soil conductivity meter (EMI), and GPR data acquired in July 2016. There is a strong contrast in physical properties in the upper 50 m of the subsurface between the low-lying hydrothermal area and surrounding hills: the hydrothermal area has much lower seismic velocities ( 1 km/s vs 3 km/s) and electrical resistivity ( 20 ohm-m vs 300 ohm-m). A prominent zone of very low resistivity (<10 ohm-m) exists at about 20 m depth beneath all hydrothermal features. Poisson's ratio, calculated from P-wave refraction tomography and surface wave inversions, shows low values beneath the "frying pan," where gas is emerging in small fumaroles, suggesting that Poisson's ratio is an effective "gas detector" in hydrothermal areas. Near-surface resistivity mapped from EMI shows a strong correlation with hydrothermal areas previously mapped by heat flow, with areas of high heat flow generally having low resistivity near the surface. Two exceptions are (1) the "frying pan," which shows a central area of high resistivity (corresponding to escaping gas) surrounding by a halo of low resistivity, and (2) a broad area of low resistivity connecting the hydrothermal centers to the lake, which may be clay deposits. TEM data penetrate up to 200 m in depth and suggest that a reservoir of hydrothermal fluids may underlie the entire area, including beneath the forested hills, at depths greater than 100 m, but that they rise toward the surface in a 100-m-wide area just west of the frying pan. Our results show that synoptic, multi-scale geophysical measurements can place important constraints on the subsurface pathways of hydrothermal waters and gas.
Geophysical characterization of an active hydrothermal shear zone in granitic rocks
NASA Astrophysics Data System (ADS)
Zahner, Tobias; Baron, Ludovic; Holliger, Klaus; Egli, Daniel
2016-04-01
Hydrothermally active faults and shear zones in the crystalline massifs of the central Alps are currently of particular interest because of their potential similarities and analogies with planned deep petrothermal reservoirs in the Alpine foreland. In order to better understand such hydrothermal systems, a near-vertical, hydrothermally active shear zone embedded in low-permeability granitic rocks has been drilled. This borehole is located on the Grimsel Pass in the central Swiss Alps, has an inclination of 24 degrees with regard to the vertical, and crosses the targeted shear zone between about 82 and 86 meters depth. The borehole has been fully cored and a comprehensive suite of geophysical logging data has been acquired. The latter comprises multi-frequency sonic, ground-penetrating radar, resistivity, self-potential, gamma-gamma, neutron-neutron, optical televiewer, and caliper log data. In addition to this, we have also performed a surface-to-borehole vertical seismic profiling experiment. The televiewer data and the retrieved core samples show a marked increase of the fracture density in the target region, which also finds its expression in rather pronounced and distinct signatures in all other log data. Preliminary results point towards a close correspondence between the ground-penetrating radar and the neutron-neutron log data, which opens the perspective of constraining the effective fracture porosity at vastly differing scales. There is also remarkably good agreement between the sonic log and the vertical seismic profiling data, which may allow for assessing the permeability of the probed fracture network by interpreting these data in a poroelastic context.
NASA Astrophysics Data System (ADS)
Liegler, A.; Bakkar Hindeleh, H.; Deering, C. D.; Fentress, S. E.
2015-12-01
Volcanic gas emissions are a key component for monitoring volcanic activity, magmatic input of volatiles to the atmosphere and the assessment of geothermal potential in volcanic regions. Diffuse soil degassing has been shown to represent a major part of volcanic gas emissions. However, this type of gas emission has not yet been quantified in the Guanacaste province of Costa Rica; a region of the country with several large, active or dormant volcanoes. We conducted the first study of diffuse CO2 degassing at Rincón de la Vieja and Miravalles volcanoes, both located in Guanacaste. Diffuse degassing was measured using the accumulation chamber method to quantify CO2 flux in regions where hydrothermal surface features indicate anomalous activity. The total diffuse carbon dioxide flux estimated at Miravalles in two areas, together roughly 2 km2 in size, was 135 t/day and in several areas at Rincón de la Vieja a minimum of 4 t/day. Comparatively low flux values and a very local concentration (few m2) of CO2 flux were observed at the active Rincón de la Vieja volcano, compared to the dormant Miravalles volcano, where significant soil flux was found over extended areas, not only around vents. Our assessment of the origin of these differences leads to two possibilities depending on if the surface features on the two volcanoes are fed by a common hydrothermal system or two separate ones. In the former case, the different intensity of diffuse CO2 flux could indicate a different degassing behavior and stronger concentration of gas emissions at the active vent areas at Rincon de la Vieja. In the latter case, where the hydrothermal systems are not linked, the amount of CO2 degassed through the flanks of the volcanoes could indicate that different physical and chemical conditions are governing the degassing of the two systems.
NASA Astrophysics Data System (ADS)
Dai, Changchao; Wan, Jiafeng; Yang, Juan; Qu, Shanshan; Jin, Tieyu; Ma, Fangwei; Shao, Jinqiu
2018-06-01
In this work, argy wormwood-based porous carbon electrode materials for high-performance supercapacitors are prepared through H3PO4 solution hydrothermal carbonization and subsequent KOH activation. The obtained carbon has a specific surface area (SSA) of 927 m2 g-1, a total pore volume of 0.56 cm3 g-1, and a high oxygen (9.38%) content. In three-electrode system, it exhibits specific capacitance of 344 F g-1 at 1 A g-1. Moreover, the symmetric supercapacitor shows an excellent rate capability of 87% retention from 1 A g-1 to 10 A g-1, and a good cycling performance with 91.6% retention over 5000 cycles in 6 M KOH. Therefore, the sample activated by H3PO4 & KOH exhibits an excellent future in energy storage.
NASA Astrophysics Data System (ADS)
Barge, Laurie
2016-07-01
Planetary water-rock interfaces generate energy in the form of redox, pH, and thermal gradients, and these disequilibria are particularly focused in hydrothermal vent systems where the reducing, heated hydrothermal fluid feeds back into the more oxidizing ocean. Alkaline hydrothermal vents have been proposed as a likely location for the origin of life on the early Earth due to various factors: including the hydrothermal pH / Eh gradients that resemble the ubiquitous electrical / proton gradients in biology, the catalytic hydrothermal precipitates that resemble inorganic catalysts in enzymes, and the presence of electron donors and acceptors in hydrothermal systems (e.g. H2 + CH4 and CO2) that are thought to have been utilized in the earliest metabolisms. Of particular importance for the emergence of metabolism are the mineral "chimneys" that precipitate at the vent fluid / seawater interface. Hydrothermal chimneys are flow-through chemical reactors that form porous and permeable inorganic membranes transecting geochemical gradients; in some ways similar to biological membranes that transect proton / ion gradients and harness these disequilibria to drive metabolism. These emergent chimney structures in the far-from-equilibrium system of the alkaline vent have many properties of interest to the origin of life that can be simulated in the laboratory: for example, they can generate electrical energy and drive redox reactions, and produce catalytic minerals (in particular the metal sulfides and iron oxyhydroxides - "green rust") that can facilitate chemical reactions towards proto-metabolic cycles and biosynthesis. Many of the factors prompting interest in alkaline hydrothermal vents on Earth may also have been present on early Mars, or even presently within icy worlds such as Europa or Enceladus - thus, understanding the disequilibria and resulting prebiotic chemistry in these systems can be of great use in assessing the potential for other environments in the Solar System where life could have emerged.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zou, Yunling; College of Science, Civil Aviation University of China, Tianjin 300300; Tan, Xin
Highlights: • Flower-like brookite TiO{sub 2} structures were prepared by hydrothermal method. • PVP not only acted as a dispersant but also stabilized the layered structure. • The resulted brookite TiO{sub 2} showed high photocatalytic activity under UV irradiation. - Abstract: Flower-like brookite TiO{sub 2} nanostructures were controllable prepared by a one-step hydrothermal method by changing experimental conditions, such as hydrothermal temperature, reaction time and the amount of polyvinylpyrrolidone. The photocatalytic activities of the samples were investigated by degradation of methylene blue (MB) in aqueous solution under UV light irradiation. It was found that the formation of brookite TiO{sub 2}more » nanostructures with various morphologies could be well controlled by the adjustment of hydrothermal temperature, reaction time and the amount of surfactant, and the morphology of the products changed from spindle-like structures to flower-like structures with the increase of hydrothermal temperature, reaction time and the amount of surfactant. The photocatalytic tests indicate that the flower-like brookite TiO{sub 2} nanostructures shows high photocatalytic activity in degradation of methylene blue (MB) under UV light irradiation. The formation mechanism of flower-like brookite TiO{sub 2} nanostructures was also discussed in detail based on the above investigations.« less
NASA Astrophysics Data System (ADS)
Wilson, D. J.; Peirce, C.; Hobbs, R. W.; Gregory, E. P. M.; Zhang, L.
2016-12-01
Geophysical studies of crustal structure at a diverse range of ridges have provided evidence that the balance between spreading rate and magma supply determines whether spreading predominantly occurs by magmatic accretion of new oceanic crust or through tectonic stretching of the whole lithosphere. Asymmetric spreading, patterns of on- and off-axis volcanism, the evolution of oceanic core complexes and the distribution of hydrothermal systems all indicate that the process of spreading is not constant over geologically short timescales. The structure of the resulting crust reflects this complexity in origin. Studies along flow-lines across ridges spreading at intermediate rates suggest variations in topographic style and crustal structure have periodically occurred, controlled by the interplay between magmatic accretion and tectonic stretching, and coupled to the degree of hydrothermal activity. Seismic reflection images and tomographic models derived from wide-angle seismic data have enabled a detailed examination of the oceanic crust that formed at the fast-to-intermediate-spreading (36 mm yr-1) Costa Rica Rift over the last 6 Ma, to look for any temporal variation in basement topography, upper crust (layer 2) P-wave velocity/density structure and crustal thickness. Coincident marine gravity and magnetic data not only allow us to test the validity of the final velocity-density model but also review variability in half-spreading rate, respectively. Collectively our analyses allow us to investigate the timescale and cyclicity of crustal structure variations and, having determined the spreading rate over time, consider how this may reflect changes in magma supply and/or hydrothermal activity at the Costa Rica Rift, using borehole 504B as the ground-truth. This research is part of a major, interdisciplinary NERC-funded collaboration entitled: Oceanographic and Seismic Characterisation of heat dissipation and alteration by hydrothermal fluids at an Axial Ridge (OSCAR).
Optimization of Large-Scale Daily Hydrothermal System Operations With Multiple Objectives
NASA Astrophysics Data System (ADS)
Wang, Jian; Cheng, Chuntian; Shen, Jianjian; Cao, Rui; Yeh, William W.-G.
2018-04-01
This paper proposes a practical procedure for optimizing the daily operation of a large-scale hydrothermal system. The overall procedure optimizes a monthly model over a period of 1 year and a daily model over a period of up to 1 month. The outputs from the monthly model are used as inputs and boundary conditions for the daily model. The models iterate and update when new information becomes available. The monthly hydrothermal model uses nonlinear programing (NLP) to minimize fuel costs, while maximizing hydropower production. The daily model consists of a hydro model, a thermal model, and a combined hydrothermal model. The hydro model and thermal model generate the initial feasible solutions for the hydrothermal model. The two competing objectives considered in the daily hydrothermal model are minimizing fuel costs and minimizing thermal emissions. We use the constraint method to develop the trade-off curve (Pareto front) between these two objectives. We apply the proposed methodology on the Yunnan hydrothermal system in China. The system consists of 163 individual hydropower plants with an installed capacity of 48,477 MW and 11 individual thermal plants with an installed capacity of 12,400 MW. We use historical operational records to verify the correctness of the model and to test the robustness of the methodology. The results demonstrate the practicability and validity of the proposed procedure.
Basin scale permeability and thermal evolution of a magmatic hydrothermal system
NASA Astrophysics Data System (ADS)
Taron, J.; Hickman, S. H.; Ingebritsen, S.; Williams, C.
2013-12-01
Large-scale hydrothermal systems are potentially valuable energy resources and are of general scientific interest due to extreme conditions of stress, temperature, and reactive chemistry that can act to modify crustal rheology and composition. With many proposed sites for Enhanced Geothermal Systems (EGS) located on the margins of large-scale hydrothermal systems, understanding the temporal evolution of these systems contributes to site selection, characterization and design of EGS. This understanding is also needed to address the long-term sustainability of EGS once they are created. Many important insights into heat and mass transfer within natural hydrothermal systems can be obtained through hydrothermal modeling assuming that stress and permeability structure do not evolve over time. However, this is not fully representative of natural systems, where the effects of thermo-elastic stress changes, chemical fluid-rock interactions, and rock failure on fluid flow and thermal evolution can be significant. The quantitative importance of an evolving permeability field within the overall behavior of a large-scale hydrothermal system is somewhat untested, and providing such a parametric understanding is one of the goals of this study. We explore the thermal evolution of a sedimentary basin hydrothermal system following the emplacement of a magma body. The Salton Sea geothermal field and its associated magmatic system in southern California is utilized as a general backdrop to define the initial state. Working within the general framework of the open-source scientific computing initiative OpenGeoSys (www.opengeosys.org), we introduce full treatment of thermodynamic properties at the extreme conditions following magma emplacement. This treatment utilizes a combination of standard Galerkin and control-volume finite elements to balance fluid mass, mechanical deformation, and thermal energy with consideration of local thermal non-equilibrium (LTNE) between fluids and solids. Permeability is allowed to evolve under several constitutive models tailored to both porous media and fractures, considering the influence of both mechanical stress and diagenesis. In this first analysis, a relatively simple mechanical model is used; complexity will be added incrementally to represent specific characteristics of the Salton Sea hydrothermal field.
NASA Astrophysics Data System (ADS)
Byrdina, Svetlana; Revil, André; Gunawan, Hendra; Saing, Ugan B.; Grandis, Hendra
2017-07-01
Papandayan volcano in West Java, Indonesia, is characterized by intense hydrothermal activities manifested by numerous fumaroles at three craters or kawah, i.e. Mas, Manuk and Baru. The latter was created after November 2002 phreatic eruption. Since 2011, numerous volcano-tectonic B events are encountered and the volcano was set on alert status on several occasions. The purpose of the present study is to delineate the structure of the summital hydrothermal system from Self-Potential (SP), soil temperature and gas concentrations in the soil (CO2, SO2 and H2S) data. This combination of geophysical and geochemical methods allows identification of the weak permeable zones serving as preferential pathways for hydrothermal circulation and potential candidates to future landslides or flank collapses. This study is an on-going collaborative research project and we plan to conduct electrical resistivity tomography (ERT) and also Induced-Polarization (IP) surveys. Additional data would allow the 3D imaging of the studied area. The IP parameters will be used to characterise and to quantify the degree of alteration of the volcanic rocks as has been shown very recently in the laboratory studies. There are also rocks and soil samples that will undergo laboratory analyses at ISTerre for IP and complex resistivity parameters at the sample scale that will help to interpret the survey results.
Validation of the BASALT model for simulating off-axis hydrothermal circulation in oceanic crust
NASA Astrophysics Data System (ADS)
Farahat, Navah X.; Archer, David; Abbot, Dorian S.
2017-08-01
Fluid recharge and discharge between the deep ocean and the porous upper layer of off-axis oceanic crust tends to concentrate in small volumes of rock, such as seamounts and fractures, that are unimpeded by low-permeability sediments. Basement structure, sediment burial, heat flow, and other regional characteristics of off-axis hydrothermal systems appear to produce considerable diversity of circulation behaviors. Circulation of seawater and seawater-derived fluids controls the extent of fluid-rock interaction, resulting in significant geochemical impacts. However, the primary regional characteristics that control how seawater is distributed within upper oceanic crust are still poorly understood. In this paper we present the details of the two-dimensional (2-D) BASALT (Basement Activity Simulated At Low Temperatures) numerical model of heat and fluid transport in an off-axis hydrothermal system. This model is designed to simulate a wide range of conditions in order to explore the dominant controls on circulation. We validate the BASALT model's ability to reproduce observations by configuring it to represent a thoroughly studied transect of the Juan de Fuca Ridge eastern flank. The results demonstrate that including series of narrow, ridge-parallel fractures as subgrid features produces a realistic circulation scenario at the validation site. In future projects, a full reactive transport version of the validated BASALT model will be used to explore geochemical fluxes in a variety of off-axis hydrothermal environments.
Entropy production in a box: Analysis of instabilities in confined hydrothermal systems
NASA Astrophysics Data System (ADS)
Börsing, N.; Wellmann, J. F.; Niederau, J.; Regenauer-Lieb, K.
2017-09-01
We evaluate if the concept of thermal entropy production can be used as a measure to characterize hydrothermal convection in a confined porous medium as a valuable, thermodynamically motivated addition to the standard Rayleigh number analysis. Entropy production has been used widely in the field of mechanical and chemical engineering as a way to characterize the thermodynamic state and irreversibility of an investigated system. Pioneering studies have since adapted these concepts to natural systems, and we apply this measure here to investigate the specific case of hydrothermal convection in a "box-shaped" confined porous medium, as a simplified analog for, e.g., hydrothermal convection in deep geothermal aquifers. We perform various detailed numerical experiments to assess the response of the convective system to changing boundary conditions or domain aspect ratios, and then determine the resulting entropy production for each experiment. In systems close to the critical Rayleigh number, we derive results that are in accordance to the analytically derived predictions. At higher Rayleigh numbers, however, we observe multiple possible convection modes, and the analysis of the integrated entropy production reveals distinct curves of entropy production that provide an insight into the hydrothermal behavior in the system, both for cases of homogeneous materials, as well as for heterogeneous spatial material distributions. We conclude that the average thermal entropy production characterizes the internal behavior of hydrothermal systems with a meaningful thermodynamic measure, and we expect that it can be useful for the investigation of convection systems in many similar hydrogeological and geophysical settings.
NASA Astrophysics Data System (ADS)
Rejas, J. G.; Martínez-Frías, J.; Bonatti, J.; Martínez, R.; Marchamalo, M.
2012-07-01
The aim of this work is the comparative study of the presence of hydrothermal alteration materials in the Turrialba volcano (Costa Rica) in relation with computed spectral anomalies from multitemporal and multisensor data adquired in spectral ranges of the visible (VIS), short wave infrared (SWIR) and thermal infrared (TIR). We used for this purposes hyperspectral and multispectral images from the HyMAP and MASTER airborne sensors, and ASTER and Hyperion scenes in a period between 2002 and 2010. Field radiometry was applied in order to remove the atmospheric contribution in an empirical line method. HyMAP and MASTER images were georeferenced directly thanks to positioning and orientation data that were measured at the same time in the acquisition campaign from an inertial system based on GPS/IMU. These two important steps were allowed the identification of spectral diagnostic bands of hydrothermal alteration minerals and the accuracy spatial correlation. Enviromental impact of the volcano activity has been studied through different vegetation indexes and soil patterns. Have been mapped hydrothermal materials in the crater of the volcano, in fact currently active, and their surrounding carrying out a principal components analysis differentiated for a high and low absorption bands to characterize accumulations of kaolinite, illite, alunite and kaolinite+smectite, delimitating zones with the presence of these minerals. Spectral anomalies have been calculated on a comparative study of methods pixel and subpixel focused in thermal bands fused with high-resolution images. Results are presented as an approach based on expert whose main interest lies in the automated identification of patterns of hydrothermal altered materials without prior knowledge or poor information on the area.
Hydrothermal activity in the Lau back-arc basin: Sulfides and water chemistry
DOE Office of Scientific and Technical Information (OSTI.GOV)
Fouquet, Y.; Charlou, J.L.; Donval, J.P.
1991-04-01
The submersible Nautile completed 22 dives during the Nautilau cruise (R/V Nadir, April 17-May 10, 1989) for a detailed investigation of the southern Lau basin near Tonga. The objective of the scientific team from France, Germany, and Tonga was to understand the process of sea-floor ore formation associated with hydrothermal circulation along the Valu Fa back-arc ridge behind the Tonga-Kermadec trench. The four diving areas, between lat21{degree}25'S and 22{degree}40'S in water{approximately}2000 m deep, were selected on the basis of results from cruises of the R/V Jean Charcot and R/V Sonne. The Nadir cruise provided proof of hydrothermal activity-in all formore » areas, over more than 100 km-as indicated by the widespread occurence of hydrothermal deposits and by heat flow, conductivity, and temperature measurements near the sea bottom. The most spectacular findings were high-temperature white and black smokers and associated fauna and ore deposits. Hydrothermal water chemistry and sulfide composition data presented here indicate that this hydrothermal field is very different from the hydrothermal fields in oceanic ridges. This difference is seen in water chemistry of the hydrothermal fluid (pH=2 and high metal content) and the chemical composition of sulfides (enrichment in Ba, As, and Pb).« less
Isotopic constraints on ice age fluids in active geothermal systems: Reykjanes, Iceland
NASA Astrophysics Data System (ADS)
Pope, Emily C.; Bird, Dennis K.; Arnórsson, Stefán; Fridriksson, Thráinn; Elders, Wilfred A.; Fridleifsson, Gudmundur Ó.
2009-08-01
The Reykjanes geothermal system is located on the landward extension of the Mid-Atlantic Ridge in southwest Iceland, and provides an on-land proxy to high-temperature hydrothermal systems of oceanic spreading centers. Previous studies of elemental composition and salinity have shown that Reykjanes geothermal fluids are likely hydrothermally modified seawater. However, δD values of these fluids are as low as -23‰, which is indicative of a meteoric water component. Here we constrain the origin of Reykjanes hydrothermal solutions by analysis of hydrogen and oxygen isotope compositions of hydrothermal epidote from geothermal drillholes at depths between 1 and 3 km. δDEPIDOTE values from wells RN-8, -9, -10 and -17 collectively range from -60 to -78‰, and δ18OEPIDOTE in these wells are between -3.0 and 2.3‰. The δD values of epidote generally increase along a NE trend through the geothermal field, whereas δ18O values generally decrease, suggesting a southwest to northeast migration of the geothermal upflow zone with time that is consistent with present-day temperatures and observed hydrothermal mineral zones. For comparative analysis, the meteoric-water dominated Nesjavellir and Krafla geothermal systems, which have a δDFLUID of ˜ -79‰ and -89‰, respectively, show δDEPIDOTE values of -115‰ and -125‰. In contrast, δDEPIDOTE from the mixed meteoric-seawater Svartsengi geothermal system is -68‰; comparable to δDEPIDOTE from well RN-10 at Reykjanes. Stable isotope compositions of geothermal fluids in isotopic equilibrium with the epidotes at Reykjanes are computed using published temperature dependent hydrogen and oxygen isotope fractionation curves for epidote-water, measured isotope composition of the epidotes and temperatures approximated from the boiling point curve with depth. Calculated δD and δ18O of geothermal fluids are less than 0‰, suggesting that fluids of meteoric or glacial origin are a significant component of the geothermal solutions. Additionally, δDFLUID values in equilibrium with geothermal epidote are lower than those of modern-day fluids, whereas calculated δ18OFLUID values are within range of the observed fluid isotope composition. We propose that modern δDEPIDOTE and δDFLUID values are the result of diffusional exchange between hydrous alteration minerals that precipitated from glacially-derived fluids early in the evolution of the Reykjanes system and modern seawater-derived geothermal fluids. A simplified model of isotope exchange in the Reykjanes geothermal system, in which the average starting δDROCK value is -125‰ and the water to rock mass ratio is 0.25, predicts a δDFLUID composition within 1‰ of average measured values. This model resolves the discrepancy between fluid salinity and isotope composition of Reykjanes geothermal fluids, explains the observed disequilibrium between modern fluids and hydrothermal epidote, and suggests that rock-fluid interaction is the dominant control over the evolution of fluid isotope composition in the hydrothermal system.
NASA Astrophysics Data System (ADS)
Barriga, F. J.; Fonseca, R.; Dias, S.; Cruz, I.; Carvalho, C.; Relvas, J. M.; Pedersen, R.
2010-12-01
The Loki’s Castle hydrothermal vent field was discovered in the summer of 2008 during a cruise led by the Centre of Geobiology of the University of Bergen, integrated in the H2Deep Project (Eurocores, ESF; see Pedersen et al., 2010, AGU Fall Meeting, Session OS26). Fresh volcanic glasses analyzed by EPMA are basalts. The vent site is composed of several active, over 10 m tall chimneys, producing up to 320 C fluid, at the top of a very large sulfide mound (estimated diameter 200 m). Mineralogy: The main sulfide assemblage in chimneys consists of sphalerite (Sp), pyrite (Py) and pyrrhotite, with lesser chalcopyrite (Ccp). Sulphide-poor selected samples collected at the base of chimneys are mostly composed of anhydrite (Anh), gypsum and talc (Tlc). Association of quartz, anhydrite, gypsum and barite were also found in some of the samples. The sulphide-poor samples from the base of the chimneys denote seawater interaction with the hydrothermal fluid and consequent decrease in temperature, precipitating sulfates. Sphalerite compositions are Zn(0.61-0.70)Fe(0.39-0.30)S. The variations in Fe content are consistent with those of hot, reduced hydrothermal fluids. The observed sulfide assemblage is consistent with the temperature of 320C measured in Loki’s Castle vents. Compositional zonation in sphalerites suggests different pulses of activity of the hydrothermal system, with higher contents of Zn in the center of the crystals. Geochemistry: Here we report preliminary data part of a major analytical task of sequential extraction of metals from sediments in the vicinity of Loki’s Castle, in an attempt to detect correlations with microbial populations and/or subseafloor mineralized intervals. The abundances of Cu, Pb, Ni, Cr, Zn, Fe, Mn and Co in sediments were determined by aqua regia extraction on subsamples from 7 gravity cores. Several anomalous intervals were sampled, in which Cu<707ppm, Ni shows many weak peaks (<50ppm), Cr shows 6 peaks (<121ppm), Zn shows 4 well-defined peaks (<234ppm). Fe varies up to ~9% and Mn, not surprisingly, is enriched in the upper few centimeters of each core. Co shows hardly any peaks. The various metals show variable degrees of intercorrelation. Cores GC6 and GC7, both located ~25 km to the SW of Loki’s Castle, contain the most anomalous intervals. Some intervals contain clusters of anomalous values of most analyzed metals, in others the anomalies are scattered vertically through both cores. The variations in metal contents along the GC6 and GC7 cores indicate oscillation in hydrothermal activity during sediment formation, suggesting different pulses of activity of the hydrothermal field. These two cores also reveal an enrichment in Mn in the upper layers, which could indicate either oxyhydroxide precipitation directly under the seafloor, due to the gradual mixing of the hydrothermal plumes with seawater (cooler and more oxidizing). Collectively, these data suggest both layered and cross-cutting metal-enriched intervals. The latter may correspond to hydrothermal upflow of mineralized solutions through the sediments.
Aquilina, Alfred; Connelly, Douglas P.; Copley, Jon T.; Green, Darryl R. H.; Hawkes, Jeffrey A.; Hepburn, Laura E.; Huvenne, Veerle A. I.; Marsh, Leigh; Mills, Rachel A.; Tyler, Paul A.
2013-01-01
In the austral summer of 2011 we undertook an investigation of three volcanic highs in the Central Bransfield Basin, Antarctica, in search of hydrothermal activity and associated fauna to assess changes since previous surveys and to evaluate the extent of hydrothermalism in this basin. At Hook Ridge, a submarine volcanic edifice at the eastern end of the basin, anomalies in water column redox potential (Eh) were detected close to the seafloor, unaccompanied by temperature or turbidity anomalies, indicating low-temperature hydrothermal discharge. Seepage was manifested as shimmering water emanating from the sediment and from mineralised structures on the seafloor; recognisable vent endemic fauna were not observed. Pore fluids extracted from Hook Ridge sediment were depleted in chloride, sulfate and magnesium by up to 8% relative to seawater, enriched in lithium, boron and calcium, and had a distinct strontium isotope composition (87Sr/86Sr = 0.708776 at core base) compared with modern seawater (87Sr/86Sr ≈0.70918), indicating advection of hydrothermal fluid through sediment at this site. Biogeochemical zonation of redox active species implies significant moderation of the hydrothermal fluid with in situ diagenetic processes. At Middle Sister, the central ridge of the Three Sisters complex located about 100 km southwest of Hook Ridge, small water column Eh anomalies were detected but visual observations of the seafloor and pore fluid profiles provided no evidence of active hydrothermal circulation. At The Axe, located about 50 km southwest of Three Sisters, no water column anomalies in Eh, temperature or turbidity were detected. These observations demonstrate that the temperature anomalies observed in previous surveys are episodic features, and suggest that hydrothermal circulation in the Bransfield Strait is ephemeral in nature and therefore may not support vent biota. PMID:23359806
NASA Astrophysics Data System (ADS)
Sultana, Saima; Rafiuddin; Khan, Mohammad Zain; Umar, Khalid; Ahmed, Arham S.; Shahadat, Mohammad
2015-10-01
The present paper reports development of SnO2-SrO based nanocomposites using facile hydrothermal and sol-gel method. Nanocomposites were characterized on the basis of X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Studies (EDS), Transmission Electron Microscopy (TEM), Fourier Transform Infrared (FTIR), Thermal Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) techniques. The materials were explored for the photocatalytic activity regarding the treatment of organic pollutants viz-azo-dye, pesticide and drug. In addition, a comparative study was performed in term of particle size using hydrothermal and sol-gel route. It was observed that hydrothermal route showed an improved particle size, which affects the photocatalytic activity, porosity and crystalline nature of the nanocomposite. Further, kinetic and thermodynamic parameters were also calculated for the photodegradation experiments. It was found that the rate of photodegradation reaction followed the pseudo-first order kinetics and the highest rate was observed for azo-dye while it was lowest for the drug. A negative values of the Gibbs free energy (ΔG) show that the photodegradation proceeds with a net decrease in free energy of the system. The results of photodegradation of dye, pesticide and drug indicate that nanocomposites of SnO2-SrO can be effectively applied for the treatment of organic pollutants.
NASA Astrophysics Data System (ADS)
Aihara, Y.; Kiyokawa, S.; Ito, T.; Ikehara, M.; Yamaguchi, K. E.; Horie, K.; Sakamoto, R.; Miki, T.
2013-12-01
Stratigraphic transition of black chert to iron-rich sedimentary rocks above volcanic sequences with hydrothermal systems is common and characteristic feature of Archean greenstone belts. The 3.2 Ga Dixon Island Formation, exposed along the northern coast of Dixon Island located in the coastal Pilbara terrane, Western Australia, is one of such units and the focus of our study. We introduce field occurrence and lithology of the Dixon Island Formation that preserves features of paleohydrohermal environment in the Mesoarchean ocean. The Dixon Island Formation is composed of the following three members (in ascending order): Komatiite-Rhyolite Tuff, Black Chert, and Varicolored Chert members (Kiyokawa and Taira, 1998). Here we focus on the Komatiite-Rholite Tuff member. It preserves two cycles of highly altered komatiite lavas and well-stratified rhyolite tuff. Komatiite lavas include dendritic crystals of chrome spinel and ghosts of spinifex, euhedral and sheet-like olivines and pyroxenes. These rocks are now composed of granular microcrystalline quartz with chromian muscovite, chrome spinel and chrorite that formed by intense silicification. Its upper part contains hydrothermal veining and alteration (i.e., many vein swarms composed of veins of quartz and organic carbon-rich black chert). Most black chert veins intrude vertically into overlying layers, and contain barite, pyrite, monazite and clay minerals which were least affected by silicificatio. Based on the cross-cutting relationship seen in the outcrops, we recognized two generations of black chert veins (type 1 and type 2 veins; Kiyokawa et al., 2006). Type 1 veins are mainly composed of carbonaceous peloids in a microcrystalline quartz matrix. Euhedral and xenocrystic tourmaline are found only in Type1 veins. Type 2 veins are organic carbon-poor and contain fragments of black chert and siliceous volcanic breccia (Kiyokawa et al., 2006). Intense silicification of komatiitic volcaniclastics and lava, enriched in Si and K and depleted in Mg, occurred earlier than the formation of black chert veins and probably during sedimentation of the overlying Black Chert member. Petrographycally, tourmaline in Type1 veins formed by hydrothermal processes and can be used to infer physicochemical conditions of the hydrothermal activity. Fragmentation of black chert and volcanic rocks within Type 2 veins was probably due to high pressure caused by hydrothermal activity.
Magmatic Intrusions and a Hydrothermal Origin for Fluvial Valleys on Mars
NASA Technical Reports Server (NTRS)
Gulick, Virginia C
1998-01-01
Numerical models of Martian hydrothermal systems demonstrate that systems associated with magmatic intrusions greater than several hundred cubic kilometers can provide sufficient groundwater outflow to form the observed fluvial valleys, if subsurface permeability exceeds about 1.0 darcy. Groundwater outflow increases with increasing intrusion volume and subsurface permeability and is relatively insensitive to intrusion depth and subsurface porosity within the range considered here. Hydrothermally-derived fluids can melt through 1 to 2 km thick ice-rich permafrost layers in several thousand years. Hydrothermal systems thus provide a viable alternative to rainfall for providing surface water for valley formation. This mechanism can form fluvial valleys not only during the postulated early warm, wet climatic epoch, but also during more recent epochs when atmospheric conditions did not favor atmospheric cycling of water. The clustered distribution of the valley networks on a given geologic surface or terrain unit of Mars may also be more compatible with localized, hydrothermally-driven groundwater outflow than regional rainfall. Hydrothermal centers on Mars may have provided appropriate environments for the initiation of life or final oases for the long-term persistence of life.
Effect of Hydrothermal Alteration on Rock Properties in Active Geothermal Setting
NASA Astrophysics Data System (ADS)
Mikisek, P.; Bignall, G.; Sepulveda, F.; Sass, I.
2012-04-01
Hydrothermal alteration records the physical-chemical changes of rock and mineral phases caused by the interaction of hot fluids and wall rock, which can impact effective permeability, porosity, thermal parameters, rock strength and other rock properties. In this project, an experimental approach has been used to investigate the effects of hydrothermal alteration on rock properties. A rock property database of contrastingly altered rock types and intensities has been established. The database details horizontal and vertical permeability, porosity, density, thermal conductivity and thermal heat capacity for ~300 drill core samples from wells THM12, THM13, THM14, THM17, THM18, THM22 and TH18 in the Wairakei-Tauhara geothermal system (New Zealand), which has been compared with observed hydrothermal alteration type, rank and intensity obtained from XRD analysis and optical microscopy. Samples were selected from clay-altered tuff and intercalated siltstones of the Huka Falls Formation, which acts as a cap rock at Wairakei-Tauhara, and tuffaceous sandstones of the Waiora Formation, which is a primary reservoir-hosting unit for lateral and vertical fluid flows in the geothermal system. The Huka Falls Formation exhibits argillic-type alteration of varying intensity, while underlying Waiora Formations exhibits argillic- and propylithic-type alteration. We plan to use a tempered triaxial test cell at hydrothermal temperatures (up to 200°C) and pressures typical of geothermal conditions, to simulate hot (thermal) fluid percolation through the rock matrix of an inferred "reservoir". Compressibility data will be obtained under a range of operating (simulation reservoir) conditions, in a series of multiple week to month-long experiments that will monitor change in permeability and rock strength accompanying advancing hydrothermal alteration intensity caused by the hot brine interacting with the rock matrix. We suggest, our work will provide new baseline information concerning fluid-rock interaction processes in geothermal reservoirs, and their effects on rock properties, that will aid improved understanding of the evolution of high-temperature geothermal systems, provide constraints to parameterization of reservoir models and assist future well planning and design through prediction of rock properties in the context of drilling strategies.
Nordstrom, D. Kirk; Guo, Qinghai; McCleskey, R. Blaine
2014-01-01
Explanations for the lack of acid geothermal springs in Tibet are inferred from a comprehensive hydrochemical comparison of Tibetan geothermal waters with those discharged from Yellowstone (USA) and two active volcanic areas, Nevado del Ruiz (Colombia) and Miravalles (Costa Rica) where acid springs are widely distributed and diversified in terms of geochemical characteristic and origin. For the hydrothermal areas investigated in this study, there appears to be a relationship between the depths of magma chambers and the occurrence of acid, chloride-rich springs formed via direct magmatic fluid absorption. Nevado del Ruiz and Miravalles with magma at or very close to the surface (less than 1–2 km) exhibit very acidic waters containing HCl and H2SO4. In contrast, the Tibetan hydrothermal systems, represented by Yangbajain, usually have fairly deep-seated magma chambers so that the released acid fluids are much more likely to be fully neutralized during transport to the surface. The absence of steam-heated acid waters in Tibet, however, may be primarily due to the lack of a confining layer (like young impermeable lavas at Yellowstone) to separate geothermal steam from underlying neutral chloride waters and the possible scenario that the deep geothermal fluids below Tibet carry less H2S than those below Yellowstone.
NASA Astrophysics Data System (ADS)
Guo, Qinghai; Kirk Nordstrom, D.; Blaine McCleskey, R.
2014-11-01
Explanations for the lack of acid geothermal springs in Tibet are inferred from a comprehensive hydrochemical comparison of Tibetan geothermal waters with those discharged from Yellowstone (USA) and two active volcanic areas, Nevado del Ruiz (Colombia) and Miravalles (Costa Rica) where acid springs are widely distributed and diversified in terms of geochemical characteristic and origin. For the hydrothermal areas investigated in this study, there appears to be a relationship between the depths of magma chambers and the occurrence of acid, chloride-rich springs formed via direct magmatic fluid absorption. Nevado del Ruiz and Miravalles with magma at or very close to the surface (less than 1-2 km) exhibit very acidic waters containing HCl and H2SO4. In contrast, the Tibetan hydrothermal systems, represented by Yangbajain, usually have fairly deep-seated magma chambers so that the released acid fluids are much more likely to be fully neutralized during transport to the surface. The absence of steam-heated acid waters in Tibet, however, may be primarily due to the lack of a confining layer (like young impermeable lavas at Yellowstone) to separate geothermal steam from underlying neutral chloride waters and the possible scenario that the deep geothermal fluids below Tibet carry less H2S than those below Yellowstone.
Organic Biomarker Preservation in Silica-Rich Hydrothermal Systems with Implications to Mars
NASA Astrophysics Data System (ADS)
Jahnke, L. L.; Parenteau, M. N.; Farmer, J. D.
2016-05-01
Microbial community structure and preservation of organic matter in siliceous hydrothermal environments is a critical issue given the discovery of hydrothermal vents and silica on Mars. Here we discuss preservation of cyanobacterial biomarker lipid.
Destruction of Energetic Materials in Supercritical Water
2002-06-25
PHASE BEHAVIOR UNDER HYDROTHERMAL PROCESSING CONDITIONS...172 E. MODELING TOOLS FOR SOLVATION FREE ENERGIES IN HYDROTHERMAL SYSTEMS...potential equations of state of hydrothermal solutions. Figure 25 shows a schematic of the transient grating experiment. In this experiment, two laser
NASA Astrophysics Data System (ADS)
Pałgan, Dominik; Devey, Colin W.; Yeo, Isobel A.
2017-12-01
Current estimates indicate that the number of high-temperature vents (one of the primary pathways for the heat extraction from the Earth's mantle) - at least 1 per 100 km of axial length - scales with spreading rate and should scale with crustal thickness. But up to present, shallow ridge axes underlain by thick crust show anomalously low incidences of high-temperature activity. Here we compare the Reykjanes Ridge, an abnormally shallow ridge with thick crust and only one high-temperature vent known over 900 km axial length, to the adjacent subaerial Reykjanes Peninsula (RP), which is characterized by high-temperature geothermal sites confined to four volcanic systems transected by fissure swarms with young (Holocene) volcanic activity, multiple faults, cracks and fissures, and continuous seismic activity. New high-resolution bathymetry (gridded at 60 m) of the Reykjanes Ridge between 62°30‧N and 63°30‧N shows seven Axial Volcanic Ridges (AVR) that, based on their morphology, geometry and tectonic regime, are analogues for the volcanic systems and fissure swarms on land. We investigate in detail the volcano-tectonic features of all mapped AVRs and show that they do not fit with the previously suggested 4-stage evolution model for AVR construction. Instead, we suggest that AVR morphology reflects the robust or weak melt supply to the system and two (or more) eruption mechanisms may co-exist on one AVR (in contrast to 4-stage evolution model). Our interpretations indicate that, unlike on the Reykjanes Peninsula, faults on and around AVRs do not cluster in orientation domains but all are subparallel to the overall strike of AVRs (orthogonal to spreading direction). High abundance of seamounts shows that the region centered at 62°47‧N and 25°04‧W (between AVR-5 and -6) is volcanically robust while the highest fault density implies that AVR-1 and southern part of AVR-6 rather undergo period of melt starvation. Based on our observations and interpretations we expect all of the AVRs on Reykjanes Ridge to be hydrothermally active but morphological and hydrographic settings of this ridge may cause hydrothermal plumes to be quickly dispersed and diluted due to exposure to strong bottom currents. Therefore, combined CTD and autonomous vehicles surveys are probably the most efficient methods for hydrothermal exploration along the Reykjanes Ridge.
NASA Astrophysics Data System (ADS)
Crone, T. J.; Kinsey, J. C.; Mittelstaedt, E. L.
2017-12-01
Hydrothermal venting at mid-ocean ridges influences ocean chemistry, the thermal and chemical structure of the oceanic crust, and the evolution of unique and diverse autolithotrophically-supported ecosystems. Axially-hosted hydrothermal systems are responsible for 20-25% of the total heat flux out of Earth's interior, and likely play a large role in local as well as global biogeochemical cycles. Despite the importance of these systems, only a few studies have attempted to constrain the volume and heat flux of an entire hydrothermal vent field. In July of 2014 we used the Sentry autonomous underwater vehicle (AUV) to survey the water column over the ASHES hydrothermal vent field which is located within the caldera of Axial Seamount, an active submarine volcano located on the Juan de Fuca Ridge. To estimate the total heat and mass flux from this vent field, we equipped Sentry with a Nortek acoustic Doppler velocimeter (ADV), an inertial measurement unit (IMU), two acoustic Doppler current profilers (ADCPs), and two SBE3 temperature probes, allowing us to obtain precise measurements of fluid temperature and water velocity. The survey was designed using a control volume approach in which Sentry was pre-programmed to survey a 150-m-square centered over the vent field flying a grid pattern with 5-m track line spacing followed by a survey of the perimeter. This pattern was repeated multiple times during several 10-h dives at different altitudes, including 10, 20, 40, and 60 m above the seafloor, and during one 40-h survey at an altitude of 10 m. During the 40-h survey, the pattern was repeated nine times allowing us to obtain observations over several tidal cycles. Water velocity data obtained with Sentry were corrected for platform motion and then combined with the temperature measurements to estimate heat flux. The analysis of these data will likely provide the most accurate and highest resolution heat and mass flux estimates at a seafloor hydrothermal field to date.
Lipid biomarker and microbial community of 49.6°E hydrothermal field at Southwest Indian Ocean Ridge
NASA Astrophysics Data System (ADS)
Lei, J.; Chu, F.; Yu, X.; Li, X.; Tao, C.
2012-12-01
In 2007, Chinese Research Cruises Discovered the First Active Hydrothermal Vent Field at the Ultraslow Spreading Southwest Indian Ridge. This study intent to get composition, evolution and origin information of lipid compounds in SWIR, and recognize the style of lipid biomarkers which have obviously indicative significance for community structure.Soluble organic matter were extracted from geological samples (including chimney sulfide, oxide, around hydrothermal vents) in Southwest Indian Ridge (SWIR), and divided into hydrocarbon, fatty acid component by column chromatography. GC, GC-MS, HPLC-MS were applied for composition and abundance analysis. Lipid in hydrothermal sulfide contains obvious isoprenoidal hydrocarbon biomarkers (Sq, IS40) and GDGTs (m/z=653) that associated with methanogenic archaea which belongs to Euryarchaeota, and iso /anti-iso fatty acid (iC15:0, aiC15:0, iC17:0, aiC17:0)which may originated from sulfate reducing bacteria (SRB).Lipids extracted from hydrothermal oxide lack isoprenoidal hydrocarbon, and Ph/C18 (0.57) is much lower than sulfide (1.22). Fatty acid compound of oxide include abundant saturated fatty (C16:0, C18:0) acid and mono-unsaturated fatty acids (C16:1n7, C18:1n7), but much less iso/anti-iso was detected. Lipid composition of hydrothermal oxide showed that archaea activity was seldom in hydrothermal oxide, and sulfur-oxidizing bacteria was the main microbial community.Study of Jaeschke (2010) showed that high temperature hydrothermal venting encompassed different microbial community from low temperature hydrothermal venting. Our study showed that in different stage of hydrothermal, microbial community structure may be distinct.
DIAPHANE: muon tomography applied to volcanoes, civil engineering, archaelogy
NASA Astrophysics Data System (ADS)
Marteau, J.; de Bremond d'Ars, J.; Gibert, D.; Jourde, K.; Ianigro, J.-C.; Carlus, B.
2017-02-01
Muography techniques applied to geological structures greatly improved in the past ten years. Recent applications demonstrate the interest of the method not only to perform structural imaging but also to monitor the dynamics of inner movements like magma ascent inside volcanoes or density variations in hydrothermal systems. Muography time-resolution has been studied thanks to dedicated experiments, e.g. in a water tower tank. This paper presents the activities of the DIAPHANE collaboration between particle- and geo-physicists and the most recent results obtained in the field of volcanology, with a focus on the main target, the Soufrière of Guadeloupe active volcano. Special emphasis is given on the monitoring of the dome's inner volumes opacity variations, that could be ascribed to the hydrothermal system dynamics (vaporization of inner liquid water in coincidence with the appearance of new fumaroles at the summit). I also briefly present results obtained in the fields of civil engineering (study of urban underground tunnels) and archaelogy (greek tumulus scanning).
Stable isotope geochemistry of fumaroles: an insight into volcanic surveillance
NASA Astrophysics Data System (ADS)
Panichi, C.; La Ruffa, G.
2001-12-01
In active volcanic environments magmatic water may accumulate in the volcanic-hosted geothermal systems, or, more rarely may reach the surface along deep fractures inside the volcano crater. Knowledge of magmatic contribution to emerging fluids in volcanic active areas is critical to understanding the chemical evolution of the magma, the conditions in which it exists in the crust, and the mechanisms by which it erupts in the crust. The source of volatiles (especially water) is also of interest when eruptions are driven by the expansion of hydrothermal fluids against atmospheric pressure, without the involvement of fresh magma ('hydrothermal' or 'phreatomagmatic' eruptions). In both cases the occurrence of volcanic and/or phreatic activities is likely to be preceded by substantial isotopic and chemical changes in the crater fumarolic systems. H and O isotopic composition of condensed water from crater fumaroles appear to be able to give strong evidence for the existence of magmatic waters in the high-temperature manifestations of the volcanic systems. Isotopic data and specific hydrological models from seven different volcanic systems (Galeras Volcano, Colombia, Kilauea Volcano, Hawaii, Kudryvy Volcano, Kuril volcanic arc, Mt St Helens, USA; Guagua Pichincha, Ecuador; Vulcano island, Italy; the Aegean Volcanic Arc, Greece) are discussed in order to highlight the possibility to use those isotopic parameters in the assessment of the environmental risks of an active volcanic area.
NASA Astrophysics Data System (ADS)
Finn, C. A.; Deszcz-Pan, M.; Horton, R.; Breit, G.; John, D.
2007-12-01
High resolution helicopter-borne magnetic and electromagnetic (EM) data flown over the rugged, ice-covered, highly magnetic and mostly resistive volcanoes of Mount Rainier, Mount Adams and Mount Baker, along with rock property measurements, reveal the distribution of alteration, water and hydrothermal fluids that are essential to evaluating volcanic landslide hazards and understanding hydrothermal systems. Hydrothermally altered rocks, particularly if water saturated, can weaken stratovolcanoes, thereby increasing the potential for catastrophic sector collapses that can lead to far-traveled, destructive debris flows. Intense hydrothermal alteration significantly reduces the magnetization and resistivity of volcanic rock resulting in clear recognition of altered rock by helicopter magnetic and EM measurements. Magnetic and EM data, combined with geological mapping and rock property measurements, indicate the presence of appreciable thicknesses of hydrothermally altered rock west of the modern summit of Mount Rainier in the Sunset Amphitheater region, in the central core of Mount Adams north of the summit, and in much of the central cone of Mount Baker. We identify the Sunset Amphitheater region and steep cliffs at the western edge of the central altered zone at Mount Adams as likely sources for future debris flows. In addition, the EM data identified water-saturated rocks in the upper 100-200 m of the three volcanoes. The water-saturated zone could extend deeper, but is beyond the detection limits of the EM data. Water in hydrothermal fluids reacts with the volcanic rock to produce clay minerals. The formation of clay minerals and presence of free water reduces the effective stress, thereby increasing the potential for slope failure, and acts, with entrained melting ice, as a lubricant to transform debris avalanches into lahars. Therefore, knowing the distribution of water is also important for hazard assessments. Finally, modeling requires extremely low resistivities (< 20 ohm-m) that laboratory electrical resistivity measurements indicate are most easily explained by sulfuric acid solutions permeating altered rocks. The acid is the result of oxidation of magmatic H2S to sulfuric acid and highlights the continued alteration of volcanoes during periods of relative quiescence. Our results demonstrate that high resolution geophysical and geological observations can yield unprecedented views of the three-dimensional distribution of altered rock and shallow pore water and hydrothermal fluids within active stratovolcanoes.
NASA Astrophysics Data System (ADS)
Venturi, Stefania; Tassi, Franco; Fazi, Stefano; Vaselli, Orlando; Crognale, Simona; Rossetti, Simona; Cabassi, Jacopo; Capecchiacci, Francesco
2017-04-01
Soils in volcanic and hydrothermal areas are affected by anomalously high concentrations of gases released from the deep reservoirs, which consists of both inorganic (mainly CO2 and H2S) and organic (volatile organic compounds; VOCs) species. VOCs in volcanic and hydrothermal fluids are mainly composed of saturated and unsaturated hydrocarbons (alkanes, aromatics, alkenes, and cyclics), with variable concentrations of O- and S-bearing compounds and halocarbons, depending on the physicochemical conditions at depth. VOCs in interstitial soil gases and fumarolic emissions from four volcanic and hydrothermal systems in the Mediterranean area (Solfatara Crater, Poggio dell'Olivo and Cava dei Selci, in Italy, and Nisyros Island, in Greece) evidenced clear compositional differences, suggesting that their behavior is strongly affected by secondary processes occurring at shallow depths and likely controlled by microbial activity. Long-chain saturated hydrocarbons were significantly depleted in interstitial soil gases with respect to those from fumarolic discharges, whereas enrichments in O-bearing compounds (e.g. aldehydes, ketones), DMSO2 and cyclics were commonly observed. Benzene was recalcitrant to degradation processes, whereas methylated aromatics were relatively instable. The chemical and isotopic (δ13C in CO2 and CH4) composition of soil gases collected along vertical profiles down to 50 cm depth at both Solfatara Crater and Poggio dell'Olivo (Italy) showed evidences of relevant oxidation processes in the soil, confirming that microbial activity likely plays a major role in modifying the composition of deep-derived VOCs. Despite their harsh conditions, being typically characterized by high temperatures, low pH, and high toxic gases and metal contents, the variety of habitats characterizing volcanic and hydrothermal environments offers ideal biomes to extremophilic microbes, whose metabolic activity can consume and/or produce VOCs. In the Solfatara Crater, microbial diversity was assessed by new generation sequencing (NGS) of 16S rDNA. Microbiological analyses of samples collected from selected vertical profiles in the soil, where temperatures were up to 60 °C, revealed total prokaryotic abundances ranging from 7.23×106 to 439×106 cell/g WW. The highest abundances were recorded in sites affected by the highest and the lowest CO2 (3,350 and 110 gm-2day-1, respectively) and CH4 (0.059 and 0.00021 gm-2day-1, respectively) soil fluxes, and H2S concentrations ranging from 0.05 to 1.9 mmol/mol. The composition of both archaeal and bacterial communities showed remarkable changes depending on the sampling site, the most abundant phyla being represented by Proteobacteria, Firmicutes, Actinobacteria and Euryarchaeota at the highest inputs of hydrothermal fluids, corresponding to VOCs concentrations up to 898 nmol/mol (mainly alkanes and aromatics). Conversely, Proteobacteria, Acidobacteria, Firmicutes, Chloroflexi and Thaumarchaeota dominated in those sites where low gas fluxes and VOCs contents (≤300 nmol/mol; mainly alkanes and O-bearing species) were recognized. The intimate relation between microbial distribution and hydrothermal gas concentrations and gas fluxes demonstrated the critical interplay between soil gases and microorganisms, remarking the potential biodegradation efficiency at extremely high VOCs concentrations in the soil.
NASA Astrophysics Data System (ADS)
Malligavathy, M.; Iyyapushpam, S.; Nishanthi, S. T.; Padiyan, D. Pathinettam
2018-04-01
TiO2 nanoparticles were synthesised by hydrothermal method. The degree of crystallinity and phase purity were confirmed from the Raman spectra and X-ray diffraction. By increasing the hydrothermal temperature, crystallinity and AC conductivity of the TiO2 nanoparticles increase. Nitrogen adsorption-desorption measurements confirmed that the samples were mesoporous with an average pore diameter of 4.4-7.45 nm. Photocatalytic activity of TiO2 nanoparticles was evaluated and the sample hydrothermally treated at 160°C has the highest photocatalytic activity. In gas sensing measurements, sensitivity increases as a function of concentration and the response to ethanol vapour was better compared to other gases for the sample synthesised at 160°C.
Geological model of supercritical geothermal reservoir related to subduction system
NASA Astrophysics Data System (ADS)
Tsuchiya, Noriyoshi
2017-04-01
Following the Great East Japan Earthquake and the accident at the Fukushima Daiichi Nuclear power station on 3.11 (11th March) 2011, geothermal energy came to be considered one of the most promising sources of renewable energy for the future in Japan. The temperatures of geothermal fields operating in Japan range from 200 to 300 °C (average 250 °C), and the depths range from 1000 to 2000 m (average 1500 m). In conventional geothermal reservoirs, the mechanical behavior of the rocks is presumed to be brittle, and convection of the hydrothermal fluid through existing network is the main method of circulation in the reservoir. In order to minimize induced seismicity, a rock mass that is "beyond brittle" is one possible candidate, because the rock mechanics of "beyond brittle" material is one of plastic deformation rather than brittle failure. Supercritical geothermal resources could be evaluated in terms of present volcanic activities, thermal structure, dimension of hydrothermal circulation, properties of fracture system, depth of heat source, depth of brittle factures zone, dimension of geothermal reservoir. On the basis of the GIS, potential of supercritical geothermal resources could be characterized into the following four categories. 1. Promising: surface manifestation d shallow high temperature, 2 Probability: high geothermal gradient, 3 Possibility: Aseismic zone which indicates an existence of melt, 4 Potential : low velocity zone which indicates magma input. Base on geophysical data for geothermal reservoirs, we have propose adequate tectonic model of development of the supercritical geothermal reservoirs. To understand the geological model of a supercritical geothermal reservoir, granite-porphyry system, which had been formed in subduction zone, was investigated as a natural analog of the supercritical geothermal energy system. Quartz veins, hydrothermal breccia veins, and glassy veins are observed in a granitic body. The glassy veins formed at 500-550 °C under lithostatic pressures, and then pressures dropped drastically. The solubility of silica also dropped, resulting in formation of quartz veins under a hydrostatic pressure regime. Connections between the lithostatic and hydrostatic pressure regimes were key to the formation of the hydrothermal breccia veins, and the granite-porphyry system provides useful information for creation of fracture clouds in supercritical geothermal reservoirs. A granite-porphyry system, associated with hydrothermal activity and mineralization, provides a suitable natural analog for studying a deep-seated geothermal reservoir where stockwork fracture systems are created in the presence of supercritical geothermal fluids. I describe fracture networks and their formation mechanisms using petrology and fluid inclusion studies in order to understand this "beyond brittle" supercritical geothermal reservoir, and a geological model for "Beyond Brittle" and "Supercritical" geothermal reservoir in the subduction zone were was revealed.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Chen Zhixin, E-mail: czx@fzu.edu.cn; Analysis and Test Center, Fuzhou University, Fuzhou 350002; Li Danzhen
Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a microwave-assisted hydrothermal method with the temperature ranging from 80 to 195 Degree-Sign C. X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen sorption analysis, UV-visible spectroscopy, scanning electron microscopy and transmission electron microscopy were used to characterize the products. It was found that the crystallographic structure and optical property of the products synthesized at different temperatures were almost the same. The degradation of methyl orange (MO) under the visible light irradiation has been used as a probe reaction to investigate the photocatalytic activity of as-prepared ZnIn{sub 2}S{sub 4}, which shows that the ZnIn{sub 2}S{submore » 4} sample synthesized at 195 Degree-Sign C shows the best photocatalytic activity for MO degradation. In addition, the photocatalytic activities of all the samples prepared by the microwave-assisted hydrothermal method are better than those prepared by a normal hydrothermal method, which could be attributed to the formation of more defect sites during the microwave-assisted hydrothermal treatment. - Graphical abstract: Marigold-like ZnIn{sub 2}S{sub 4} microspheres were synthesized by a fast microwave-assisted hydrothermal method at 80-195 Degree-Sign C with a very short reaction time of 10 min. The as-prepared ZnIn{sub 2}S{sub 4} sample can be used as visible light photocatalyst for degradation of organic dyes. Highlights: Black-Right-Pointing-Pointer ZnIn{sub 2}S{sub 4} microspheres were synthesized by microwave-assisted hydrothermal method. Black-Right-Pointing-Pointer The crystal structure and optical property of the products were almost the same. Black-Right-Pointing-Pointer Increment of the temperature renders high surface area due to the bubbling effect. Black-Right-Pointing-Pointer The ZnIn{sub 2}S{sub 4} synthesized at 195 Degree-Sign C shows the best visible catalytic activity for MO.« less
Discovery of hydrothermally active and extinct talc mounds on the Mid-Cayman Rise
NASA Astrophysics Data System (ADS)
Hodgkinson, M.; Murton, B. J.; Roberts, S.
2013-12-01
Since 1977, hydrothermal vents have been the subject of intense scientific interest due to their role in cooling the oceanic crust and global geochemical cycles. Until now, two types of hydrothermal system have been identified: one, driven by magmatic heat extruding ';black smoker' fluids; and another, involving serpentinisation of ultramafic rocks and the precipitation of carbonate/brucite chimneys. Here, we present details of a new, off-axis type of hydrothermal system consisting of mounds of predominately botryoidal talc (a magnesium-silicate) with accessory silica and copper sulphides, and chimneys exhaling fluids of moderate temperature and pH. Discovered on the Mid-Cayman Rise (MCR) in 2010, the Von Damm Vent Field (VDVF) features a NNW-ESE-trending line of four overlapping cones, the largest of which is 75 m high by 150 m in diameter. The VDVF is hosted in the gabbroic footwall of the Mount Dent Oceanic Core Complex (MDOCC), which includes serpentinised peridotite at depth. The largest cone vents clear fluids from two main orifices at its summit, with primary temperatures of 215°C. Elsewhere, both focussed and diffuse flow areas emit fluids with temperatures of up to 150°C. The surrounding ~1 m thick pelagic sediment contains abundant pockmarks that emit methane-rich fluids at temperatures of less than 10°C. During the return to the MCR in early 2013, several other talc mounds were discovered within a kilometre of the active VDVF. These inactive mounds also comprise an assemblage of botryoidal talc, silica, disseminated sulphides (including chalcopyrite) and sulphates. One of these mounds (Mystic Mount) is double the volume of the active VDVF. The unique dominance of talc as the major mineral forming the hydrothermal structures indicates unusual vent fluid compositions that are able to carry both copper (at high-temperatures) and precipitate magnesium silicate. Thermodynamic modelling indicates that talc precipitates on mixing a moderately acidic, silica rich fluid (e.g. the primary VDVF fluids) with only 2% of seawater. At lower pH (e.g. typical ';black smoker' fluids), the ratio jumps to over 90% while at high pH (e.g. ';Lost City' fluids) brucite and carbonate dominate. Estimates using recently measured vent temperatures and fluid fluxes indicate a heat flux of ~800 MW for the active VDVF. Assuming the primary vent fluid has remained largely unchanged, the VDVF could have grown in under 1000 years and Mystic Mount in ~2000 years. Both the hydrothermal mounds and faults in the surrounding gabbro share a NNW-ESE orientation that is consistent with a brittle structural control imposed by the flexural curvature of the MDOCC in response to the uplift of the lower oceanic crust along a low-angle detachment fault. We propose that these flexural faults provide pathways for fluids to ingress deep into the MDOCC where they react with both mafic rocks (producing high-temperature, low pH, sulphide and copper-bearing fluids), peridotites and carbonates (increasing the pH) resulting in a moderate pH, silica-rich fluid that precipitates talc on mixing with seawater. The presence of further, inactive, talc mounds within 1 km of the VDVF indicates hydrothermal activity on OCCs has been widespread and represents a significant but hitherto overlooked mechanism of crustal heat loss and chemical interaction with the ocean at slow-spreading ridges.
Petrology of the 1995/2000 Magma of Copahue, Argentina
NASA Astrophysics Data System (ADS)
Goss, A.; Varekamp, J. C.
2001-05-01
Phreatomagmatic eruptions of Copahue in July/August,1995 and July/August 2000 produced mixed juvenile clasts, silica-rich debris from the hydrothermal system, and magmatic scoria with 88 percent SiO2. These high-SiO2 clasts carry an as yet unidentified (crystobalite?), euhedral silica phase in great abundance, which is riddled with tan, primary melt inclusions. The mixed clasts have bands of mafic material with small euhedral olivine, clinopyroxene, and plagioclase that are mixed with an intermediate magma with coarser, resorbed phenocrysts of olivine, plagioclase, clino- and ortho- pyroxene, and rare occurrences of the silica phase. These ejecta are intimate mixtures of a relatively felsic magma similar to Pleistocene Copahue lavas and a mafic basaltic andesite, with minor contributions of a magma contaminated with silica-rich hydrothermal wallrock material. Two-pyroxene geothermometry indicates crystallization temperatures of 1020 deg - 1045 deg C. Glass inclusions (59-63 percent SiO2) in plagioclase and olivine crystals yield very low volatile contents in the melt (0.4-1.5 percent H2O). The 1995/2000 magmas resided at shallow level and degassed into the active volcano-hydrothermal system which discharges acid fluids into the Copahue crater lake and hot springs. More mafic magma intruded this shallow batch and the mixture rose into the hydrothermal system and assimilated siliceous wall rock. A Ti-diffusion profile in a magnetite crystal suggests that the period between magma mixing and eruption was on the order of 4-10 weeks, and the temperature difference between resident and intruding magma was about 50-60 oC.
Hydrothermal exploration and astrobiology: oases for life in distant oceans?
NASA Astrophysics Data System (ADS)
German, Christopher R.
2004-04-01
High-temperature submarine hydrothermal fields on Earth's mid-ocean ridges play host to exotic ecosystems with fauna previously unknown to science. Because these systems draw significant energy from chemosynthesis rather than photosynthesis, it has been postulated that the study of such systems could have relevance to the origins of life and, hence, astrobiology. A major flaw to that argument, however, is that modern basalt-hosted submarine vents are too oxidizing and lack the abundant free hydrogen required to drive abiotic organic synthesis and/or the energy yielding reactions that the most primitive anaerobic thermophiles isolated from submarine vent-sites apparently require. Here, however, the progress over the past decade in which systematic search strategies have been used to identify previously overlooked venting on the slow-spreading Mid-Atlantic Ridge and the ultra-slow spreading Arctic and SW Indian Ridges is described. Preliminary identification of fault-controlled venting in a number of these sites has led to the discovery of at least two high-temperature hydrothermal fields hosted in ultramafic rocks which emit complex organic molecules in their greater than 360 °C vent-fluids. Whether these concentrations represent de novo organic synthesis within the hydrothermal cell remains open to debate but it is probable that many more such sites exist throughout the Atlantic, Arctic and SW Indian Oceans. One particularly intriguing example is the Gakkel Ridge, which crosses the floor of the Arctic Ocean. On-going collaborations between oceanographers and astrobiologists are actively seeking to develop a new class of free-swimming autonomous underwater vehicle, equipped with appropriate chemical sensors, to conduct long-range missions that will seek out, locate and investigate new sites of hydrothermal venting at the bottom of this, and other, ice-covered oceans.
NASA Astrophysics Data System (ADS)
Saito, S.; Yamada, Y.; Sanada, Y.; Kido, Y. N.; Hamada, Y.; Shiraishi, K.; Hsiung, K. H.; Tsuji, T.; Eng, C.; Maeda, L.; Kumagai, H.; Nozaki, T.; Ishibashi, J. I.
2017-12-01
A scientific drilling expedition, CK16-01 was conducted by D/V Chikyu in an active hydrothermal field on the Iheya-North Knoll in Okinawa Trough in February-March, 2016 as a part of "Next-generation Technology for Ocean Resources Survey" of the Cross-ministerial Strategic Innovation Promotion Program (SIP). During the expedition logging while drilling (LWD) was deployed to uncover the architecture of modern hydrothermal deposits near the seafloor. A downhole sequence of fracture network (stock-work) was discovered by high resolution resistivity images at Site C9023 in the southern part of the knoll. More than 500 structural features were extracted from the borehole images down to 188 meter below the seafloor. Quantitative image analyses were performed and three types of conductive fractures were identified and classified as Generation 1 (G1), Generation 2 (G2), and Generation 3 (G3) based on the crossing or cutting relationship. The average thickness of fractures decrease with generation from G1 (78 mm), G2 (57 mm), to G3 (45 mm). G1 is developed in the entire interval, whereas G2 and G3 are commonly observed in the intervals of lower gamma ray and high resistivity ( 10 ohm-m) at 77-125 m and 167-186 m where sulfide minerals hosted in silicified rocks were observed in recovered core samples. Low angle fractures (<30°) are typically developed in the interval at 120 -125 m, suggesting possible lateral hydrothermal conduits. The quantitative analysis of fracture network based on borehole images shows the detailed formation process of stock-work in the basal part of modern hydrothermal system.
NASA Astrophysics Data System (ADS)
German, C. R.; Connelly, D. P.; Prien, R. D.; Yoerger, D.; Jakuba, M.; Bradley, A.; Shank, T. J.; Edmonds, H. N.; Langmuir, C. H.
2004-12-01
Less than one quarter of the global ridge-crest has yet received even cursory investigation for the presence or absence of hydrothermal activity. To improve exploration efficiency, particularly at high latitudes, new methodologies independent of tethered vehicles are required. To that end, we have begun the use of in situ chemical sensors allied to the increasing capabilities of autonomous underwater vehicles. Here, we present first results from our most recent efforts aboard the second R2K cruise to the Lau Basin (C.Langmuir, PI; Autumn 2004) to (a) map non-buoyant hydrothermal plumes, (b) intercept buoyant hydrothermal plumes and (c) locate and image novel hydrothermal fields on the seafloor. The AUV used for this work is ABE and the sensors deployed are direct extensions of the in situ Fe/Mn sensor deployed previously on SOC's AUTOSUB to investigate seasonally-reducing waters in Loch Etive, NW Scotland. Each in situ instrument comprises an electronics package that contains a tattletale control system with a flash memory card for on-board logging and a chemical manifold, consisting of a series of valves, pumps and a colorimetric cell. Analysis of iron is enabled by the determination of the coloured complex formed between iron II and ferrozine, manganese uses the colour change of PAN in the presence of reduced manganese. The system includes capacity for switching between sample, blank and two on-board samples for "in flight" calibrations with blanks and standards held in medical bags, outside of the pressure-balanced manifold, to attain in situ water-column temperatures. An in-line filter prevents large particle clogging and detection limits for both iron II and manganese II are ca.2nM.
Inactivation of Escherichia coli Endotoxin by Soft Hydrothermal Processing▿
Miyamoto, Toru; Okano, Shinya; Kasai, Noriyuki
2009-01-01
Bacterial endotoxins, also known as lipopolysaccharides, are a fever-producing by-product of gram-negative bacteria commonly known as pyrogens. It is essential to remove endotoxins from parenteral preparations since they have multiple injurious biological activities. Because of their strong heat resistance (e.g., requiring dry-heat sterilization at 250°C for 30 min) and the formation of various supramolecular aggregates, depyrogenation is more difficult than sterilization. We report here that soft hydrothermal processing, which has many advantages in safety and cost efficiency, is sufficient to assure complete depyrogenation by the inactivation of endotoxins. The endotoxin concentration in a sample was measured by using a chromogenic limulus method with an endotoxin-specific limulus reagent. The endotoxin concentration was calculated from a standard curve obtained using a serial dilution of a standard solution. We show that endotoxins were completely inactivated by soft hydrothermal processing at 130°C for 60 min or at 140°C for 30 min in the presence of a high steam saturation ratio or with a flow system. Moreover, it is easy to remove endotoxins from water by soft hydrothermal processing similarly at 130°C for 60 min or at 140°C for 30 min, without any requirement for ultrafiltration, nonselective adsorption with a hydrophobic adsorbent, or an anion exchanger. These findings indicate that soft hydrothermal processing, applied in the presence of a high steam saturation ratio or with a flow system, can inactivate endotoxins and may be useful for the depyrogenation of parenterals, including end products and medical devices that cannot be exposed to the high temperatures of dry heat treatments. PMID:19502435
The Marine Biogeochemistry of Zinc Isotopes
2007-06-01
hydrothermal fluids and minerals, cultured marine phytoplankton, natural plankton, and seawater. By measuring Zn isotopes in a diverse array of...variations were discovered in hydrothermal fluids and minerals, with hydrothermal fluids ranging in 6 66Zn from 0.02 %o to +0.93 %o, and chimney minerals...drives much of the Zn isotope fractionation in hydrothermal systems. In cultured diatoms, a relationship was discovered between Zn transport by
Chemical and isotopic characteristics of geothermal fluids from Sulphur Springs, Saint Lucia
NASA Astrophysics Data System (ADS)
Joseph, Erouscilla P.; Fournier, Nicolas; Lindsay, Jan M.; Robertson, Richard; Beckles, Denise M.
2013-03-01
Sulphur Springs is a vigorous, geothermal field associated with the active Soufrière Volcanic Centre in southern Saint Lucia, Lesser Antilles island arc. The 'Sulphur Springs Park' is an important tourist attraction (touted as the 'world's only drive-through volcano') with some of the hot pools being developed into recreational pools. Some 200,000 people visit the park each year. Since 2001, the hydrothermal fluids of Sulphur Springs have been sampled as part of an integrated volcanic monitoring programme for the island. Gas and water samples were analysed to characterise the geochemistry of the hydrothermal system, and to assess the equilibrium state and subsurface temperatures of the reservoir. This has also enabled us, for the first time, to establish baseline data for future geochemical monitoring. The gases are of typical arc-type composition, with N2 excess and low He and Ar content. The dry gas composition is dominated by CO2 (ranging from 601-993 mmol/mol), with deeper magmatic sourced H2S-rich vapour undergoing boiling and redox changes in the geothermal reservoir to emerge with a hydrothermal signature in the fumarolic gases. Fluid contributions from magmatic degassing are also evident, mainly from the moderate to high contents of HCl and deeply-sourced H2S gas, respectively. Sulphur Springs hydrothermal waters have acid-sulphate type compositions (SO4 = 78-4008 mg/L; pH = 3-7), and are of primarily meteoric origin which have been affected by evaporation processes based on the enrichment in both δ18O and δD (δ18O = - 1 to 15‰ and δD = - 9 to 14‰ respectively) in relation to the global meteoric water line (GMWL). These waters are steam-heated water typically formed by absorption of H2S-rich gases in the near surface oxygenated groundwaters. Reservoir temperatures calculated from the evaluation of gas equilibria in the CO2-CH4-H2 system reveal higher temperatures (190 to 300 °C) than those derived from quartz geothermometry (95 to 169 °C), which appeared to be affected by dilution with meteoric waters. Generally, no significant variations in fluid geochemistry of the hydrothermal system were observed between 2001 and 2006, and we propose that there were no changes in the state of volcanic activity during this period.
Insight from Genomics on Biogeochemical Cycles in a Shallow-Sea Hydrothermal System
NASA Astrophysics Data System (ADS)
Lu, G. S.; Amend, J.
2015-12-01
Shallow-sea hydrothermal ecosystems are dynamic, high-energy systems influenced by sunlight and geothermal activity. They provide accessible opportunities for investigating thermophilic microbial biogeochemical cycles. In this study, we report biogeochemical data from a shallow-sea hydrothermal system offshore Paleochori Bay, Milos, Greece, which is characterized by a central vent covered by white microbial mats with hydrothermally influenced sediments extending into nearby sea grass area. Geochemical analysis and deep sequencing provide high-resolution information on the geochemical patterns, microbial diversity and metabolic potential in a two-meter transect. The venting fluid is elevated in temperature (~70oC), low in pH (~4), and enriched in reduced species. The geochemical pattern shows that the profile is affected by not only seawater dilution but also microbial regulation. The microbial community in the deepest section of vent core (10-12 cm) is largely dominated by thermophilic archaea, including a methanogen and a recently described Crenarcheon. Mid-core (6-8 cm), the microbial community in the venting area switches to the hydrogen utilizer Aquificae. Near the sediment-water interface, anaerobic Firmicutes and Actinobacteria dominate, both of which are commonly associated with subsurface and hydrothermal sites. All other samples are dominated by diverse Proteobacteria. The sulfate profile is strongly correlated with the population size of delta- and episilon-proteobactia. The dramatic decrease in concentrations of As and Mn in pore fluids as a function of distance from the vent suggests that in addition to seawater dilution, microorganisms are likely transforming these and other ions through a combination of detoxification and catabolism. In addition, high concentrations of dissolved Fe are only measurable in the shallow sea grass area, suggesting that iron-transforming microorganisms are controlling Fe mobility, and promoting biomineralization. Taken together, these samples represent the effects of submarine venting on sediment microbial communities both vertically and horizontally in the predicted fluid flow path, and will provide a detailed investigation of genetic potential for biogeochemical cycling at Paleochori Bay.
NASA Astrophysics Data System (ADS)
Wang, Peng; Chen, Xiaohong; Shen, Licheng; Wu, Kunyu; Huang, Mingzhi; Xiao, Qiong
2016-06-01
Mapamyum geothermal field (MGF) in western Tibet is one of largest geothermal areas characterized by the occurrence of hydrothermal explosions on the Tibetan Plateau. The geochemical properties of hydrothermal water in the MGF system were investigated to trace the origin of the solutes and to determine the equilibrium temperatures of the feeding reservoir. The study results show that the geochemistry of hydrothermal waters in the MGF system is mainly of the Na-HCO3 type. The chemical components of hydrothermal waters are mainly derived from the minerals in the host rocks (e.g., K-feldspar, albite, Ca-montmorillonite, and Mg-montmorillonite). The hydrothermal waters are slightly supersaturated or undersaturated with respect to aragonite, calcite, dolomite, chalcedony and quartz (saturation indices close to 0), but are highly undersaturated with respect to gypsum and anhydrite (saturation indices < 0). Mixing models and Na-K-Mg ternary diagrams show that strong mixing between cold meteoric water and deeply-seated thermal fluids occurred during the upward flowing process. δD and δ18O data confirm that the meteoric water acts as the water source of the geothermal waters. An 220 °C equilibrated reservoir temperature of hydrothermal spring waters was calculated via both the Na-K-Mg ternary diagrams and the cationic chemical geothermometers. The logpCO2 of hydrothermal waters in the MGF system ranges from - 2.59 to - 0.57 and δ13C of the total dissolved inorganic carbon ranges from - 5.53‰ to - 0.94‰, suggesting that the carrier CO2 in hydrothermal water are mainly of a magmatic or metamorphic CO2 origin.
NASA Astrophysics Data System (ADS)
Smith, C. N.; Kesler, S. E.; Blum, J. D.; Rytuba, J. J.
2007-12-01
We present here the first study of the isotopic composition of Hg in rocks, ore deposits, and active hydrothermal systems from the California Coast Ranges, one of Earth's largest Hg-depositing systems. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of Hg deposits, hot-spring deposits that form at shallow depths (<300 m) and silica-carbonate deposits that extend to greater depths (200 to 1000 m), as well as active springs and geothermal systems that release Hg to the present surface. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of Hg than volcanic rocks of the Clear Lake Volcanic Field. Mean Hg isotope compositions for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate Hg deposits have similar average isotopic compositions that are indistinguishable from averages for the three rock units, although δ202Hg values for the Hg deposits have a greater variance than the country rocks. Precipitates from dilute spring and saline thermal waters in the area have similarly large variance and a mean δ202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate there is little or no isotopic fractionation during release of Hg from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of Hg in deposits, especially in their uppermost parts. Boiling of hydrothermal fluids is likely the most important process causing of the observed Hg isotope fractionation. This should result in the release of Hg with low δ202Hg values into the atmosphere from the top of these hydrothermal systems and a consequent enrichment in heavy Hg isotopes in the upper crust through time.
Using fumarolic inert gas composition to investigate magma dynamics at Campi Flegrei (Italy)
NASA Astrophysics Data System (ADS)
Chiodini, G.; Caliro, S.; Paonita, A.; Cardellini, C.
2013-12-01
Since 2000 the Campi Flegrei caldera sited in Neapolitan area (Italy), has showed signs of reactivation, marked by ground uplift, seismic activity, compositional variations of fumarolic effluents from La Solfatara, an increase of the fumarolic activity as well as of soil CO2 fluxes. Comparing long time series of geochemical signals with ground deformation and seismicity, we show that these changes are at least partially caused by repeated injections of magmatic fluid into the hydrothermal system. The frequency of these degassing episodes has increased in the last years, causing pulsed uplift episodes and swarms of low magnitude earthquakes. We focus here in the inert gas species (CO2-He-Ar-N2) of Solfatara fumaroles which displayed in the time spectacular and persistent variation trends affecting all the monitored vents. The observed variations, which include a continuous decrease of both N2/He and N2/CO2 ratios since 1985, paralleled by an increase of He/CO2, can not be explained neither with changes in processes of boiling-condensation in the local hydrothermal system nor with changes in the mixing proportions between a magmatic vapour and hydrothermal fluids. Consequently we investigated the possibility that the trends of inert gas species are governed by changes in the conditions controlling magma degassing at depth. We applied a magma degassing model, with the most recent updates for inert gas solubilities, after to have included petrologic constraints from the ranges of melt composition and reservoir pressure at Campi Flegrei. The model simulations for mafic melts (trachybasalt and shoshonite) show a surprising agreement with the measured data. Both decompressive degassing of an ascending magma and mixing between magmatic fluids exsolved at various levels along the ascent path can explain the long-time geochemical changes. Our work highlights that, in caldera systems where the presence of hydrothermal aquifers commonly masks the magmatic signature of reactive volatiles, inert gases are the preferred species to achieve information on the dynamics and structure of the magma plumbing systems.
NASA Astrophysics Data System (ADS)
Baker, Edward T.; Walker, Sharon L.; Resing, Joseph A.; Chadwick, William W.; Merle, Susan G.; Anderson, Melissa O.; Butterfield, David A.; Buck, Nathan J.; Michael, Susanna
2017-11-01
Back-arc spreading centers (BASCs) form a distinct class of ocean spreading ridges distinguished by steep along-axis gradients in spreading rate and by additional magma supplied through subduction. These characteristics can affect the population and distribution of hydrothermal activity on BASCs compared to mid-ocean ridges (MORs). To investigate this hypothesis, we comprehensively explored 600 km of the southern half of the Mariana BASC. We used water column mapping and seafloor imaging to identify 19 active vent sites, an increase of 13 over the current listing in the InterRidge Database (IRDB), on the bathymetric highs of 7 of the 11 segments. We identified both high and low (i.e., characterized by a weak or negligible particle plume) temperature discharge occurring on segment types spanning dominantly magmatic to dominantly tectonic. Active sites are concentrated on the two southernmost segments, where distance to the adjacent arc is shortest (<40 km), spreading rate is highest (>48 mm/yr), and tectonic extension is pervasive. Re-examination of hydrothermal data from other BASCs supports the generalization that hydrothermal site density increases on segments <90 km from an adjacent arc. Although exploration quality varies greatly among BASCs, present data suggest that, for a given spreading rate, the mean spatial density of hydrothermal activity varies little between MORs and BASCs. The present global database, however, may be misleading. On both BASCs and MORs, the spatial density of hydrothermal sites mapped by high-quality water-column surveys is 2-7 times greater than predicted by the existing IRDB trend of site density versus spreading rate.
Sphalerite is a geochemical catalyst for carbon−hydrogen bond activation
Shipp, Jessie A.; Gould, Ian R.; Shock, Everett L.; Williams, Lynda B.; Hartnett, Hilairy E.
2014-01-01
Reactions among minerals and organic compounds in hydrothermal systems are critical components of the Earth’s deep carbon cycle, provide energy for the deep biosphere, and may have implications for the origins of life. However, there is limited information as to how specific minerals influence the reactivity of organic compounds. Here we demonstrate mineral catalysis of the most fundamental component of an organic reaction: the breaking and making of a covalent bond. In the absence of mineral, hydrothermal reaction of cis- and trans-1,2-dimethylcyclohexane is extremely slow and generates many products. In the presence of sphalerite (ZnS), however, the reaction rate increases dramatically and one major product is formed: the corresponding stereoisomer. Isotope studies show that the sphalerite acts as a highly specific heterogeneous catalyst for activation of a single carbon−hydrogen bond in the dimethylcyclohexanes. PMID:25071186
Sphalerite is a geochemical catalyst for carbon-hydrogen bond activation.
Shipp, Jessie A; Gould, Ian R; Shock, Everett L; Williams, Lynda B; Hartnett, Hilairy E
2014-08-12
Reactions among minerals and organic compounds in hydrothermal systems are critical components of the Earth's deep carbon cycle, provide energy for the deep biosphere, and may have implications for the origins of life. However, there is limited information as to how specific minerals influence the reactivity of organic compounds. Here we demonstrate mineral catalysis of the most fundamental component of an organic reaction: the breaking and making of a covalent bond. In the absence of mineral, hydrothermal reaction of cis- and trans-1,2-dimethylcyclohexane is extremely slow and generates many products. In the presence of sphalerite (ZnS), however, the reaction rate increases dramatically and one major product is formed: the corresponding stereoisomer. Isotope studies show that the sphalerite acts as a highly specific heterogeneous catalyst for activation of a single carbon-hydrogen bond in the dimethylcyclohexanes.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Katoh, Yutai; Koyanagi, Takaaki; Kiggans Jr, James O.
2016-06-30
Hydrothermal corrosion of four types of the silicon carbide (SiC) to SiC plate joints were investigated under PWR and BWR relevant chemical conditions without irradiation. The joints were formed by metal diffusion bonding using molybdenum or titanium interlayer, reaction sintering using Ti-Si-C system, and SiC nanopowder sintering. Most of the formed joints withstood the corrosion tests for five weeks. The recession of the SiC substrates was limited. Based on the recession rate of the bonding layers, it was concluded that all the joints except for the molybdenum diffusion bond are promising under the reducing activity environments. The SiC nanopowder sinteredmore » joint was the most corrosion tolerant under the oxidizing activity environment among the four joints.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Aggarwal, J.K.; Palmer, M.R.
Boron isotope ratios have been determined in a variety of different geothermal waters from hydrothermal systems across Iceland. Isotope ratios from the high temperature meteoric water recharged systems reflect the isotope ratio of the host rocks without any apparent fractionation. Seawater recharged geothermal systems exhibit more positive {delta}{sup 11}B values than the meteoric water recharged geothermal systems. Water/rock ratios can be assessed from boron isotope ratios in the saline hydrothermal systems. Low temperature hydrothermal systems also exhibit more positive {delta}{sup 11}B than the high temperature systems, indicating fractionation of boron due to adsorption of the lighter isotope onto secondary minerals.more » Fractionation of boron in carbonate deposits may indicate the level of equilibrium attained within the systems.« less
Thermodynamics of Strecker synthesis in hydrothermal systems
NASA Technical Reports Server (NTRS)
Schulte, Mitchell; Shock, Everett
1995-01-01
Submarine hydrothermal systems on the early Earth may have been the sites from which life emerged. The potential for Strecker synthesis to produce biomolecules (amino and hydroxy acids) from starting compounds (ketones, aldehydes, HCN and ammonia) in such environments is evaluated quantitatively using thermodynamic data and parameters for the revised Helgeson-Kirkham-Flowers (HKF) equation of state. Although there is an overwhelming thermodynamic drive to form biomolecules by the Strecker synthesis at hydrothermal conditions, the availability and concentration of starting compounds limit the efficiency and productivity of Strecker reactions. Mechanisms for concentrating reactant compounds could help overcome this problem, but other mechanisms for production of biomolecules may have been required to produce the required compounds on the early Earth. Geochemical constraints imposed by hydrothermal systems provide important clues for determining the potential of these and other systems as sites for the emergence of life.
A simulation of the hydrothermal response to the Chesapeake Bay bolide impact
Sanford, W.E.
2005-01-01
Groundwater more saline than seawater has been discovered in the tsunami breccia of the Chesapeake Bay impact Crater. One hypothesis for the origin of this brine is that it may be a liquid residual following steam separation in a hydrothermal system that evolved following the impact. Initial scoping calculations have demonstrated that it is feasible such a residual brine could have remained in the crater for the 35 million years since impact. Numerical simulations have been conducted using the code HYDROTHERM to test whether or not conditions were suitable in the millennia following the impact for the development of a steam phase in the hydrothermal system. Hydraulic and thermal parameters were estimated for the bedrock underlying the crater and the tsunami breccia that fills the crater. Simulations at three different breccia permeabilities suggest that the type of hydrothermal system that might have developed would have been very sensitive to the permeability. A relatively low breccia permeability (1 ?? 10-16 m2) results in a system partitioned into a shallow water phase and a deeper superheated steam phase. A moderate breccia permeability (1 ?? 10-15 m2 ) results in a system with regionally extensive multiphase conditions. A relatively high breccia permeability (1 ?? 10-14 m2 ) results in a system dominated by warm-water convection cells. The permeability of the crater breccia could have had any of these values at given depths and times during the hydrothermal system evolution as the sediments compacted. The simulations were not able to take into account transient permeability conditions, or equations of state that account for the salt content of seawater. Results suggest, however, that it is likely that steam conditions existed at some time in the system following impact, providing additional evidence that is consistent with a hydrothermal origin for the crater brine. ?? Blackwell Publishing Ltd.
NASA Astrophysics Data System (ADS)
Tivey, M.; Bach, W.; Tivey, M.; Seewald, J.; Craddock, P.; Rouxel, O.; Yoerger, D.; Yeats, C.; McConachy, T.; Quigley, M.; Vanko, D.
2006-12-01
In August 2006, hydrothermal activity within the eastern Manus Basin north of Papua New Guinea was investigated using a combination of mapping (SeaBeam from the R/V Melville, near-bottom multi-beam sonar and magnetometer from AUV ABE and ROV Jason-2) and sampling (fluids and solids using ROV Jason-2). Objectives included identifying tectonic/geologic settings, examining interactions of seawater with felsic rocks that constitute the high silica end-member in the range of basement compositions, determining the extent of volatile magmatic inputs into these systems, and examining the evolution of hydrothermal activity through time. At the PACMANUS (Papua New Guinea Australia Canada Manus) area five previously discovered vent fields were mapped and sampled, and a new very active field, Fenway, was located south of the Satanic Mills field. The core of the Fenway field is a 40 m diameter two-tiered mound. A large black smoker complex venting boiling (356C, 172 bar) fluids forms the upper tier, with the lower tier composed of sulfide debris, massive anhydrite-sulfide deposits, and anhydrite sand. At the DESMOS Caldera hyaloclastites and extensive patches of bleached and stained substrate were mapped and sampled, as were diffuse (72C) and focused (119C) acidic fluids with a pH (25C) of 1.0; no sulfide deposits were observed in the area. At the North Su vent field within the SuSu Knolls area even lower pH fluids were sampled (see Seewald et al., this session). Hydrothermal activity includes venting of white sulfur-rich fluids through cracks and sediments, formation of native sulfur flanges, diffuse venting through spires, and black smoker activity (324C). Anhydrite cement is also present. The abundance of massive anhydrite at Fenway and presence of anhydrite cement at North Su is consistent with significant local entrainment and heating of seawater. The extremely low pH (less than 2) of some vent fluids supports previous hypotheses that fluids in this area contain significant input of magmatic volatiles (e.g., Gamo et al. 1997, Geology 25). During the cruise, 104 black, gray, and clear fluids were sampled using gas-tight and major samplers, and 198 vent sulfide deposit, 83 altered substrate, and 43 fresh lava samples were recovered. Geophysical maps and geochemical data for solids and fluids will be used to determine the styles of mixing and reaction occurring beneath the vent fields, estimate subsurface mineral deposition, and investigate the extent to which input of magmatic fluids is occurring within each system.
NASA Technical Reports Server (NTRS)
Leif, Roald N.
1993-01-01
High temperature alteration of sedimentary organic matter associated with marine hydrothermal systems involves complex physical and chemical processes that are not easily measured in most natural systems. Many of these processes can be evaluated indirectly by examining the geochemistry of the hydrothermal system in the laboratory. In this investigation, an experimental organic geochemical approach to studying pyrolysis of sedimentary organic matter is applied to the hydrothermal system in the Guaymas Basin, Gulf of California. A general survey of hydrothermal oils and extractable organic matter (bitumen) in hydrothermally altered sediments identified several homologous series of alkanones associated with a high temperature hydrothermal origin. The alkanones range in carbon number from C11 to C30 with no carbon number preference. Alkan-2-ones are in highest concentrations, with lower amounts of 3-, 4-, 5- (and higher) homologs. The alkanones appear to be pyrolysis products synthesized under extreme hydrothermal conditions. Hydrous pyrolysis and confinement pyrolysis experiments were performed to simulate thermally enhanced diagenetic and catagenetic changes in the immature sedimentary organic matter. The extent of alteration was measured by monitoring the n-alkanes, acyclic isoprenoids, steroid and triterpenoid biomarkers, polycyclic aromatic hydrocarbons and alkanones. The results were compared to bitumen extracts from sediments which have been naturally altered by a sill intrusion and accompanied hydrothermal fluid flow. These pyrolysis experiments duplicated many of the organic matter transformations observed in the natural system. Full hopane and sterane maturation occurred after 48 hr in experiments at 330 deg C with low water/rock mass ratios (0.29). A variety of radical and ionic reactions are responsible for the organic compound conversions which occur under extreme hydrothermal conditions. Short duration pyrolysis experiments revealed that a portion of the hydrocarbons generated from kerogen was observed to go through alkene intermediates, and the rate of alkene isomerization was influenced by the ionic strength and catalytic mineral phases. Confinement of the organic pyrolysate to the bulk sediment accelerated the rates of the biomarker epimerization reactions, suggesting that these reactions are influenced strongly by the association of the inorganic matrix, and that the relative rates of some ionic and radical reactions can be influenced by the water/rock ratio during the pyrolysis experiments.
Coupled cycling of Fe and organic carbon in submarine hydrothermal systems: Modelling approach
NASA Astrophysics Data System (ADS)
Legendre, Louis; German, Christopher R.; Sander, Sylvia G.; Niquil, Nathalie
2014-05-01
It has been recently proposed that hydrothermal plumes may be a significant source of dissolved Fe to the oceans. In order to assess this proposal, we investigated the fate of dissolved Fe released from hydrothermal systems to the overlying ocean using an approach that combined modelling and field values. We based our work on a consensus conceptual model developed by members of SCOR-InterRidge Working Group 135. The model was both complex enough to capture the main processes of dissolved Fe released from hydrothermal systems and chemical transformation in the hydrothermal plume, and simple enough to be parameterized with existing field data. It included the following flows: Fe, water and heat in the high temperature vent fluids, in the fluids diffusing around the vent, and in the entrained seawater in the buoyant plume; Fe precipitation in polymetallic sulphides near the vent; transport of Fe in the non-buoyant plume, and both its precipitation in particles onto the sea bottom away from the vent and dissolution into deep-sea waters. In other words, there were three Fe input flows into the buoyant hydrothermal plume (vent-fluids; entrained diffuse flow; entrained seawater) and three Fe output flows (sedimentation from the buoyant plume as polymetallic sulfides; sedimentation from the non-buoyant plume in particulate form; export to the deep ocean in dissolved or nanoparticulate form). The output flows balanced the input flows. We transformed the conceptual model into equations, and parameterized these with field data. To do so, we assumed that all hydrothermal systems, globally, can be represented by the circumstances that prevail at the EPR 9°50'N hydrothermal field, although we knew this assumption not to be accurate. We nevertheless achieved, by following this approach, two important goals, i.e. we could assemble into a coherent framework, for the first time, several discrete data sets acquired independently over decades of field work, and we could obtain model results that were consistent with recent field observations. We used our model to explore scenarios of Fe emissions and transformations under various constraints. The modelling exercises indicated that the provision of significant amounts of dissolved Fe to the oceans by hydrothermal plumes was consistent with realistic model parameters. This supported the proposition that hydrothermal systems play significant roles in the global biogeochemical Fe cycle.
Geological Model of Supercritical Geothermal Reservoir on the Top of the Magma Chamber
NASA Astrophysics Data System (ADS)
Tsuchiya, N.
2017-12-01
We are conducting supercritical geothermal project, and deep drilling project named as "JBBP: Japan Beyond Brittle Project" The temperatures of geothermal fields operating in Japan range from 200 to 300 °C (average 250 °C), and the depths range from 1000 to 2000 m (average 1500 m). In conventional geothermal reservoirs, the mechanical behavior of the rocks is presumed to be brittle, and convection of the hydrothermal fluid through existing network is the main method of circulation in the reservoir. In order to minimize induced seismicity, a rock mass that is "beyond brittle" is one possible candidate, because the rock mechanics of "beyond brittle" material is one of plastic deformation rather than brittle failure. To understand the geological model of a supercritical geothermal reservoir, granite-porphyry system, which had been formed in subduction zone, was investigated as a natural analog of the supercritical geothermal energy system. Quartz veins, hydrothermal breccia veins, and glassy veins are observed in a granitic body. The glassy veins formed at 500-550 °C under lithostatic pressures, and then pressures dropped drastically. The solubility of silica also dropped, resulting in formation of quartz veins under a hydrostatic pressure regime. Connections between the lithostatic and hydrostatic pressure regimes were key to the formation of the hydrothermal breccia veins, and the granite-porphyry system provides useful information for creation of fracture clouds in supercritical geothermal reservoirs. A granite-porphyry system, associated with hydrothermal activity and mineralization, provides a suitable natural analog for studying a deep-seated geothermal reservoir where stockwork fracture systems are created in the presence of supercritical geothermal fluids. I describe fracture networks and their formation mechanisms using petrology and fluid inclusion studies in order to understand this "beyond brittle" supercritical geothermal reservoir, and a geological model for "Beyond Brittle" and "Supercritical" geothermal reservoir, which is located at the top of magma chamber of granite-porphyry system, will be revealed.
NASA Astrophysics Data System (ADS)
Luan, Z.; Ma, X.; Yan, J.; Zhang, X.; Zheng, C.; Sun, D.
2016-12-01
High-resolution topography can help us deeply understand the seabed and related geological processes (e.g. hydrothermal/cold spring systems) in the deep sea areas. However, such studies are rare in China due to the limit of deep-sea detection technology. Here, we report the advances of the application of ROV in China and the newly measured high-resolution topographical data in PACMANUS and DESMOS hydrothermal fields. In June 2015, the ROV "FAXIAN" with a multibeam system (Kongsberg EM2040) was deployed to measure the topography of PACMANUS and DESMOS hydrothermal fields in the Manus basin. A composite positioning system on the ROV provided long baseline (LBL) navigation and positioning during measurements, giving a high positioning accuracy (better than 0.5m). The raw bathymetric data obtained were processed using CARIS HIPS (version 8.1). Based on the high-resolution data, we can describe the topographical details of the PACMANUS and DESMOS hydrothermal fields. High-resolution terrain clearly shows the detailed characters of the topography in the PACMANUS hydrothermal field, and some cones are corresponding to the pre discovered hydrothermal points and volcanic area. Most hydrothermal points in the PACMANUS hydrothermal field mainly developed on the steep slopes with a gradient exceeding 30 °. In contrast, the DESMOS field is a caldera that is approximately 250 m deep in the center with an E-W diameter of approximately1 km and a N-S diameter of approximately 2 km. The seafloor is much steeper on the inner side of the circular fracture. Two highlands occur in the northern and the southern flanks of the caldera. Video record indicated that pillow lava, sulfide talus, breccia, anhydrite, outcrops, and sediment all appeared in the DESMOS field. This is the first time for the ROV "FAXIAN" to be used in near-bottom topography measurements in the hydrothermal fields, opening a window of deep-sea researches in China.
NASA Astrophysics Data System (ADS)
Berardi, Gabriele; Lucci, Federico; Cozzupoli, Domenico; Pizzino, Luca; Cantucci, Barbara; Quattrocchi, Fedora
2010-05-01
In this early stage of the work we present a preliminary study of hydrothermal mineralizations found in Verzino locality, Crotone Basin, Southern Appennines, (Calabria, Italy). Both geochemical and petrographic investigations were developed with the aim of understanding the genesis of the sulfide-sulfate associations present in the "Argille Marnose del Ponda" formation, deepening their relationship with fluids circulation. These mineralizations have been recognized only in two "Calanchi" morphostructures - Badlands like morphology developed by the differential erosional pattern of the "Argille Marnose del Ponda" fm. - and constituting the northwestern flank of a little valley evolved in the Miocene sedimentary sequence from "Conglomerato di S.Nicola" fm. to "Evaporiti Superiori" fm. The mineralizations are distributed along isooriented centimetric veins (with mean direction of N120) and in nodules diffused close to the veins. These hydrothermal mineralizations are constituted by an associations of Pyrite spherical nodules (millimetric to centimetric in radius with occurrences of well developed octahedral habit single crystals), sulphate crystals (Gypsum, Jarosite, NatroJarosite), Oxides (Goethite mainly), millimetric veins of Barite and micrometric Ankerite specimens. The data (mineral habits, semiquantitative compositions and x-Ray spectra), obtained by an integration of S.E.M and XRD investigations, permit us, at the current stage of the study, to hypothesize a possible hydrothermal origin (whose temperature range estimate needs further investigations) for the sulfide-sulfate mineral phases. At the moment, we exclude their primary or secondary sedimentary provenance. The comparison of our results with the previous scientific literature focused on hydrothermal sulfide-sulfate systems (Vinogradov and Stephanov, 1964; Kostov, 1968; Plummer 1971; Boles, 1978; Ferrini and Moretti 1998) allows us to propose a possible "thermal window" ranging in the interval 50°C-230°C, characterizing an exalative-ephitermal facies condition for the genesis of the here presented mineralizations. The supposed hydrothermal genesis, together with the localization and oriented distribution of the vein/nodule systems, suggest a strong control on the fluid circulation by the very local fault systems characterizing the tectonic of the investigated area. A very close relationship between faults and fluids in Calabria region has been recently claimed by Italiano et al (2010); the presence of thermal and sulphur-rich ground-waters farther south and west of the study area (Belvedere di Spinello, Verzino, Casabona and Cotronei), strongly supports our inferences. The study area (and in general the Crotone basin) has suffered two destructive earthquakes in 1638 and 1832, with an estimated magnitude of 6.5-6.8. Moreover, recent paleoseismological studies (Galli and Bosi, 2003; Galli et al., 2008) re-evaluated the seismic hazard of the area, by detecting some historical strong earthquakes along previously unknown fault systems. This work, with the reported results on mineral associations developed by important fluid/fault interactions, highlights the role and the timing of both localized stress and pore pressures cycles in an active tectonic setting, and may represent a new interpretation key and a clue reference for a deeper understanding of a not well known italian seismic area characterized, at least, by the presence of three regional active master faults: the Marchesato Fault, the Lakes fault the Cerenzia-San Nicola-Strongoli Line. Geochemical and isotopic analyses on mineralizations, host rock and spring fluids are in progress to better define and understand the local hydrothermal system and to propose a model of time and control of the tectonic on the fluid circulation.
High-resolution aeromagnetic mapping of volcanic terrain, Yellowstone National Park
Finn, C.A.; Morgan, L.A.
2002-01-01
High-resolution aeromagnetic data acquired over Yellowstone National Park (YNP) show contrasting patterns reflecting differences in rock composition, types and degree of alteration, and crustal structures that mirror the variable geology of the Yellowstone Plateau. The older, Eocene, Absaroka Volcanic Supergroup, a series of mostly altered, andesitic volcanic and volcaniclastic rocks partially exposed in mountains on the eastern margin of YNP, produces high-amplitude, positive magnetic anomalies, strongly contrasting with the less magnetic, younger, latest Cenozoic, Yellowstone Plateau Group, primarily a series of fresh and variably altered rhyolitic rocks covering most of YNP. The Yellowstone caldera is the centerpiece of the Yellowstone Plateau; part of its boundary can be identified on the aeromagnetic map as a series of discontinuous, negative magnetic anomalies that reflect faults or zones along which extensive hydrothermal alteration is localized. The large-volume rhyolitic ignimbrite deposits of the 0.63-Ma Lava Creek Tuff and the 2.1-Ma Huckleberry Ridge Tuff, which are prominent lithologies peripheral to the Yellowstone caldera, produce insignificant magnetic signatures. A zone of moderate amplitude positive anomalies coincides with the mapped extent of several post-caldera rhyolitic lavas. Linear magnetic anomalies reflect the rectilinear fault systems characteristic of resurgent domes in the center of the caldera. Peripheral to the caldera, the high-resolution aeromagnetic map clearly delineates flow unit boundaries of pre- and post-caldera basalt flows, which occur stratigraphically below the post-caldera rhyolitic lavas and are not exposed extensively at the surface. All of the hot spring and geyser basins, such as Norris, Upper and Lower Geyser Basins, West Thumb, and Gibbon, are associated with negative magnetic anomalies, reflecting hydrothermal alteration that has destroyed the magnetic susceptibility of minerals in the volcanic rocks. Within Yellowstone Lake, which is mostly within the Yellowstone caldera, aeromagnetic lows also are associated with known hydrothermal activity in the lake. Many of the magnetic lows extend beyond the areas of alteration and hot springs, suggesting a more extensive currently active or fossil hydrothermal system than is currently mapped. Steep magnetic gradients, suggesting faults or fractures, bound the magnetic lows. This implies that fractures localize the hot springs. Magnetic gradient trends reflect the mapped Basin and Range structural trends of north and northwest, as well as northeasterly trends that parallel the regional trend of the Snake River Plain and the track of the Yellowstone hot spot which follow the Precambrian structural grain. These trends are found both at small scales such as in hydrothermal basins and at more regional fault scales, which suggests that the regional stress field and reactivated older structures may exert some control on localization of hydrothermal activity. ?? 2002 Elsevier Science B.V. All rights reserved.
Catastrophic volcanic collapse: relation to hydrothermal processes.
López, D L; Williams, S N
1993-06-18
Catastrophic volcanic collapse, without precursory magmatic activity, is characteristic of many volcanic disasters. The extent and locations of hydrothermal discharges at Nevado del Ruiz volcano, Colombia, suggest that at many volcanoes collapse may result from the interactions between hydrothermal fluids and the volcanic edifice. Rock dissolution and hydrothermal mineral alteration, combined with physical triggers such as earth-quakes, can produce volcanic collapse. Hot spring water compositions, residence times, and flow paths through faults were used to model potential collapse at Ruiz. Caldera dimensions, deposits, and alteration mineral volumes are consistent with parameters observed at other volcanoes.
Multi-Sensor Mapping of Diffuse Degassing of C-O-H Compounds in Terrestrial Hydrothermal Systems
NASA Astrophysics Data System (ADS)
Schwandner, F. M.; Shock, E. L.
2004-12-01
In-situ single-sensor detection and mapping of diffuse degassing phenomena in hydrothermal and volcanic areas can be used to elucidate subsurface tectonic structures, assess emission rates, and to monitor emission variability (Williams 1985; Chiodini et al. 1996, Werner et al., 2003). More than one technique has been deployed to measure several gas species simultaneously (e.g., Crenshaw et al. 1982), and correlations of one gas species (usually CO2) with physical parameters like heat flux (Brombach et al., 2001), or with one other gas species (Rn, He) have been demonstrated (Barberi & Carapezza 1994; Williams-Jones et al., 2000). Recently, correlations of multiple gas species with one another were reported (Schwandner et al., 2004), leading to the possibility of quantitative mapping of subsurface hydrothermal chemical processes by simultaneous measurement of reaction partners and products that continuously and diffusely degas. In the present study, we joined a fully-quantitative multi-sensor instrument (Draeger Multiwarn II) to a modified accumulation-chamber sensing method (Chiodini et al., 1996) and measured diffuse degassing of CH4, H2, CO2, CO, and H2S. In this approach, each batch of gas that is recirculated through the detector is simultaneously analyzed by all sensors. To test this approach we chose two magmatically influenced, hydrothermally active areas at Yellowstone National Park (USA): Sylvan Springs and the Greater Obsidian Pool Area. The area near Obsidian Pool was previously studied during a diffuse CO2 degassing campaign (Werner & Brantley, 2004). Preliminary results show that elevated reduced gas emissions appear to be most prominent near hydrothermal pools, whereas CO2-dominated degassing anomalies highlight subsurface tectonic structures. This multimodal distribution allows us to distinguish deep degassing sources (CO2 anomalies) from shallow localized hydrothermal processes (reduced gas anomalies). The results permit us to positively identify and partially map a previously-inferred active lineament in the Obsidian Pool area. In addition, reduced gas data are yielding areal ratio distributions of CO/CO2, H2/CH4, and CO/CH4, that may be indicative of reactions such as the catalytic hydrogenation of CO2 (Sabatier-Process) and of CO (Fischer-Tropsch-Process) within the shallow hydrothermal system. Barberi & Carapezza (1994). Bull. Volcanol. 56(5): 335-342. Brombach, et al. (2001). Geophys. Res. Lett. 28(1): 69-72. Crenshaw et al. (1982). Nature 300: 345-346. Chiodini et al. (1996). Bull. Volcanol. 58(1): 41-50. Schwandner et al. (2004). JGR D 109: D04301, doi:10.1029/2003JD003890. Werner & Brantley (2004) JGR B 105: 10,831-10,846. Werner et al. (2003). Earth Planet. Sci. Lett. 210: 561-577. Williams (1985). Science 229(4713): 551-553. Williams-Jones et al. (2000). Bull. Volcanol. 62: 130-142.
Hydrothermal Processing of Base Camp Solid Wastes To Allow Onsite Recycling
2008-09-01
ER D C/ CE R L TR -0 8 -1 3 Hydrothermal Processing of Base Camp Solid Wastes To Allow Onsite Recycling Gary L. Gerdes, Deborah...release; distribution is unlimited. ERDC/CERL TR-08-13 September 2008 Hydrothermal Processing of Base Camp Solid Wastes To Allow Onsite Recycling...a technology to process domestic solid waste using a unique hydrothermal system. The process was successfully demonstrated at Forts Benning and
Tassi, Franco; Montegrossi, Giordano; Capecchiacci, Francesco; Vaselli, Orlando
2010-03-31
The composition of non-methane organic volatile compounds (VOCs) determined in 139 thermal gas discharges from 18 different geothermal and volcanic systems in Italy and Latin America, consists of C(2)-C(20) species pertaining to the alkanes, alkenes, aromatics and O-, S- and N-bearing classes of compounds. Thiophenes and mono-aromatics, especially the methylated species, are strongly enriched in fluids emissions related to hydrothermal systems. Addition of hydrogen sulphide to dienes and electrophilic methylation involving halogenated radicals may be invoked for the formation of these species. On the contrary, the formation of furans, with the only exception of C(4)H(8)O, seems to be favoured at oxidizing conditions and relatively high temperatures, although mechanisms similar to those hypothesized for the production of thiophenes can be suggested. Such thermodynamic features are typical of fluid reservoirs feeding high-temperature thermal discharges of volcanoes characterised by strong degassing activity, which are likely affected by conspicuous contribution from a magmatic source. The composition of heteroaromatics in fluids naturally discharged from active volcanoes and geothermal areas can then be considered largely dependent on the interplay between hydrothermal vs. magmatic contributions. This implies that they can be used as useful geochemical tools to be successfully applied in both volcanic monitoring and geothermal prospection.
Tassi, Franco; Montegrossi, Giordano; Capecchiacci, Francesco; Vaselli, Orlando
2010-01-01
The composition of non-methane organic volatile compounds (VOCs) determined in 139 thermal gas discharges from 18 different geothermal and volcanic systems in Italy and Latin America, consists of C2–C20 species pertaining to the alkanes, alkenes, aromatics and O-, S- and N-bearing classes of compounds. Thiophenes and mono-aromatics, especially the methylated species, are strongly enriched in fluids emissions related to hydrothermal systems. Addition of hydrogen sulphide to dienes and electrophilic methylation involving halogenated radicals may be invoked for the formation of these species. On the contrary, the formation of furans, with the only exception of C4H8O, seems to be favoured at oxidizing conditions and relatively high temperatures, although mechanisms similar to those hypothesized for the production of thiophenes can be suggested. Such thermodynamic features are typical of fluid reservoirs feeding high-temperature thermal discharges of volcanoes characterised by strong degassing activity, which are likely affected by conspicuous contribution from a magmatic source. The composition of heteroaromatics in fluids naturally discharged from active volcanoes and geothermal areas can then be considered largely dependent on the interplay between hydrothermal vs. magmatic contributions. This implies that they can be used as useful geochemical tools to be successfully applied in both volcanic monitoring and geothermal prospection. PMID:20480029
Sekine, Yasuhito; Shibuya, Takazo; Postberg, Frank; Hsu, Hsiang-Wen; Suzuki, Katsuhiko; Masaki, Yuka; Kuwatani, Tatsu; Mori, Megumi; Hong, Peng K.; Yoshizaki, Motoko; Tachibana, Shogo; Sirono, Sin-iti
2015-01-01
It has been suggested that Saturn's moon Enceladus possesses a subsurface ocean. The recent discovery of silica nanoparticles derived from Enceladus shows the presence of ongoing hydrothermal reactions in the interior. Here, we report results from detailed laboratory experiments to constrain the reaction conditions. To sustain the formation of silica nanoparticles, the composition of Enceladus' core needs to be similar to that of carbonaceous chondrites. We show that the presence of hydrothermal reactions would be consistent with NH3- and CO2-rich plume compositions. We suggest that high reaction temperatures (>50 °C) are required to form silica nanoparticles whether Enceladus' ocean is chemically open or closed to the icy crust. Such high temperatures imply either that Enceladus formed shortly after the formation of the solar system or that the current activity was triggered by a recent heating event. Under the required conditions, hydrogen production would proceed efficiently, which could provide chemical energy for chemoautotrophic life. PMID:26506464
Sekine, Yasuhito; Shibuya, Takazo; Postberg, Frank; Hsu, Hsiang-Wen; Suzuki, Katsuhiko; Masaki, Yuka; Kuwatani, Tatsu; Mori, Megumi; Hong, Peng K; Yoshizaki, Motoko; Tachibana, Shogo; Sirono, Sin-iti
2015-10-27
It has been suggested that Saturn's moon Enceladus possesses a subsurface ocean. The recent discovery of silica nanoparticles derived from Enceladus shows the presence of ongoing hydrothermal reactions in the interior. Here, we report results from detailed laboratory experiments to constrain the reaction conditions. To sustain the formation of silica nanoparticles, the composition of Enceladus' core needs to be similar to that of carbonaceous chondrites. We show that the presence of hydrothermal reactions would be consistent with NH3- and CO2-rich plume compositions. We suggest that high reaction temperatures (>50 °C) are required to form silica nanoparticles whether Enceladus' ocean is chemically open or closed to the icy crust. Such high temperatures imply either that Enceladus formed shortly after the formation of the solar system or that the current activity was triggered by a recent heating event. Under the required conditions, hydrogen production would proceed efficiently, which could provide chemical energy for chemoautotrophic life.
Effect of Hydrothermal Treatment on Structural and Catalytic Properties of [CTA]-MCM-41 Silica.
Zapelini, Iago W; Silva, Laura L; Cardoso, Dilson
2018-05-21
The [CTA]-MCM-41 hybrid silica is a useful and simply prepared heterogeneous basic catalyst for the transesterification reaction. Here, the effect of hydrothermal treatment during catalyst preparation was investigated, with the aim of improving the structural stability of this catalyst during the reaction. It was observed that the hydrothermal step led to the formation of a material with a higher degree of organization and a greater wall thickness, which improved its structural stability. However, the catalyst prepared using this treatment presented lower catalytic activity, due to the presence of fewer active sites.
NASA Astrophysics Data System (ADS)
Tassi, Franco; Capaccioni, Bruno; Vaselli, Orlando
2014-05-01
The November 2002 submarine gas blast at Panarea Island (Sicily, southern Italy) was an unexpected reactivation event able to locally affect this hydrothermal-magmatic system whose the youngest eruptive products were dated at 20,000 ± 2000 years BP. The presence of magmatic gases (SO2 and HF) in the fumarolic gas discharges after the violent exhalative event was indicative of a magmatic input that temporary displaced the hydrothermal system. A few months later these acidic gases were indeed not detected in any of the studied fumaroles. Nevertheless, new geochemical data obtained by periodical sampling up to June 2013 suggest that the chemical-physical conditions of the hydrothermal-magmatic system at Panarea were not completely restored with respect to the geochemical data obtained in the early nineties. Thus, the 2002 gas burst has unequivocally caused a permanent modification to the fluid circulation system feeding the submarine fumaroles. In addition, strong compositional differences were observed by the 46 gases collected in 2012-2013 from submarine fumaroles located in different sites of the studied area, allowing to distinguish three different groups of fumaroles: A) H2- and CO-rich gases, which also show relatively low Ar concentrations, B) H2S-rich gases, having variable CO/CH4 ratios, and C) Ar-rich gases, having relatively low H2 concentrations. Gases from group A are distributed along NW- and NE-trending fault systems, whereas those of groups B and C discharge at increasing distance from the intersection of the two fault systems, indicating a spatial and compositional control by the local tectonic setting. The H2/CO ratios of groups A and B gases are significantly lower than those measured prior to 2012. This would imply an increase of gas pressure at depth, possibly caused by continuous addition of gas and energy from the magmatic source to the hydrothermal reservoir. Continuation of this process may lead to the occurrence of gas burst events in the next future, a hypothesis that is supported by the strong ongoing degassing activity at the surface notwithstanding a decrease of temperatures at depth. A geochemical, seismological and ground deformation monitoring of the Panarea submarine fumarolic field is highly recommended to obtain precursory signals of new strong degassing phenomena.
NASA Astrophysics Data System (ADS)
Ji, Fuwu; Zhou, Huaiyang; Yang, Qunhui; Gao, Hang; Wang, Hu; Lilley, Marvin D.
2017-04-01
The Longqi hydrothermal field at 49.6°E on the Southwest Indian Ridge was the first active hydrothermal field found at a bare-rock ultra-slow spreading mid-ocean ridge. Here we report the chemistry of the hydrothermal fluids, for the first time, that were collected from the S zone and the M zone of the Longqi field by gas-tight isobaric samplers by the HOV "Jiaolong" diving cruise in January 2015. According to H2, CH4 and other chemical data of the vent fluid, we suggest that the basement rock at the Longqi field is dominantly mafic. This is consistent with the observation that the host rock of the active Longqi Hydrothermal field is dominated by extensively distributed basaltic rock. It was very interesting to detect simultaneously discharging brine and vapor caused by phase separation at vents DFF6, DFF20, and DFF5 respectively, in a distance of about 400 m. Based on the end-member fluid chemistry and distance between the vents, we propose that there is a single fluid source at the Longqi field. The fluid branches while rising to the seafloor, and two of the branches reach S zone and M zone and phase separate at similar conditions of about 28-30.2 MPa and 400.6-408.3 °C before they discharge from the vents. The end-member fluid compositions of these vents are comparable with or within the range of variation of known global seafloor hydrothermal fluid chemical data from fast, intermediate and slow spreading ridges, which confirms that the spreading rate is not the key factor that directly controls hydrothermal fluid chemistry. The composition of basement rock, water-rock interaction and phase separation are the major factors that control the composition of the vent fluids in the Longqi field.
NASA Astrophysics Data System (ADS)
Kitada, K.; Kasaya, T.; Iwamoto, H.; Nogi, Y.
2017-12-01
The Okinawa Trough is an active back-arc basin formed by the rifting associated with extension of the continental margin behind the Ryukyu trench. New hydrothermal sites were recently discovered off Kumejima Island in the Mid-Okinawa Trough and the hydrothermal mineral deposits were identified by seafloor surveys and rock samplings by ROV (e.g., JOGMEC, 2015). In order to characterize the sub-seafloor structures and the spatial distribution of the magmatic activity around the sites, we conducted the dense magnetic, gravity and bathymetric surveys with a line spacing of 0.5 nmi aboard the R/Vs Yokosuka and Kairei, operated by the Japan Agency for Marine-Earth Science and Technology (JAMSTEC) in 2016. The geophysical data collected during the previous cruises in the area by JAMSTEC were additionally used for this study. Magnetic anomaly was calculated by subtracting the IGRF model and the magnetization intensity was estimated by the method of Parker and Huestis (1974). Free-air gravity anomaly was calculated with subtracting the normal gravity field and with corrections of the drift and of the Eötvös effect. Bouguer gravity anomaly was calculated based on the method of Parker (1972). The magnetization intensity and the Bouguer gravity anomaly reveal three characteristics of the hydrothermal area off Kumejima Island: 1) The distribution of magnetization around the hydrothermal sites shows two different types of sub-seafloor magnetic features. One is corresponded to the submarine knolls with a relatively high magnetization of 4 A/M. The other is an ENE-WSW trending magnetization distribution with relatively high and low intensities, which is consistent with the trend of the bathymetric lineament. These features are considered to be formed by magmatism associated with submarine volcanoes and back-arc rifting. 2) The reduced magnetization zone corresponding to the hydrothermal area probably attributes to hydrothermal alteration of the host rock. 3) The hydrothermal site is located on the area where the Bouguer gravity anomaly is steeply changed from 10 to 30 mGal, suggesting that the hydrothermal activity can be related to the change in crustal thickness associated with back-arc rifting.
Identifying Martian Hydrothermal Sites: Geological Investigation Utilizing Multiple Datasets
NASA Technical Reports Server (NTRS)
Dohm, J. M.; Baker, V. R.; Anderson, R. C.; Scott, D. H.; Rice, J. W., Jr.; Hare, T. M.
2000-01-01
Comprehensive geological investigations of martian landscapes that may have been modified by magmatic-driven hydrothermal activity, utilizing multiple datasets, will yield prime target sites for future hydrological, mineralogical, and biological investigations.
NASA Astrophysics Data System (ADS)
Norini, G.; Groppelli, G.; Sulpizio, R.; Carrasco-Núñez, G.; Dávila-Harris, P.; Pellicioli, C.; Zucca, F.; De Franco, R.
2015-08-01
The Los Humeros Volcanic Complex (LHVC) is an important geothermal target in the Trans-Mexican Volcanic Belt. Understanding the structure of the LHVC and its influence on the occurrence of thermal anomalies and hydrothermal fluids is important to get insights into the interplay between the volcano-tectonic setting and the characteristics of the geothermal resources in the area. In this study, we present a structural analysis of the LHVC, focused on Quaternary tectonic and volcano-tectonic features, including the areal distribution of monogenetic volcanic centers. Morphostructural analysis and structural field mapping revealed the geometry, kinematics and dynamics of the structural features in the study area. Also, thermal infrared remote sensing analysis has been applied to the LHVC for the first time, to map the main endogenous thermal anomalies. These data are integrated with newly proposed Unconformity Bounded Stratigraphic Units, to evaluate the implications for the structural behavior of the caldera complex and geothermal field. The LHVC is characterized by a multistage formation, with at least two major episodes of caldera collapse: Los Humeros Caldera (460 ka) and Los Potreros Caldera (100 ka). The study suggests that the geometry of the first collapse recalls a trap-door structure and impinges on a thick volcanic succession (10.5-1.55 Ma), now hosting the geothermal reservoir. The main ring-faults of the two calderas are buried and sealed by the widespread post-calderas volcanic products, and for this reason they probably do not have enough permeability to be the main conveyers of the hydrothermal fluid circulation. An active, previously unrecognized fault system of volcano-tectonic origin has been identified inside the Los Potreros Caldera. This fault system is the main geothermal target, probably originated by active resurgence of the caldera floor. The active fault system defines three distinct structural sectors in the caldera floor, where the occurrence of hydrothermal fluids is controlled by fault-induced secondary permeability. The resurgence of the caldera floor could be induced by an inferred magmatic intrusion, representing the heat source of the geothermal system and feeding the simultaneous monogenetic volcanic activity around the deforming area. The operation of the geothermal field and the plans for further exploration should focus on, both, the active resurgence fault system and the new endogenous thermal anomalies mapped outside the known boundaries of the geothermal field.
Monitoring diffuse volcanic degassing during volcanic unrests: the case of Campi Flegrei (Italy).
Cardellini, C; Chiodini, G; Frondini, F; Avino, R; Bagnato, E; Caliro, S; Lelli, M; Rosiello, A
2017-07-28
In volcanoes with active hydrothermal systems, diffuse CO 2 degassing may constitute the primary mode of volcanic degassing. The monitoring of CO 2 emissions can provide important clues in understanding the evolution of volcanic activity especially at calderas where the interpretation of unrest signals is often complex. Here, we report eighteen years of CO 2 fluxes from the soil at Solfatara of Pozzuoli, located in the restless Campi Flegrei caldera. The entire dataset, one of the largest of diffuse CO 2 degassing ever produced, is made available for the scientific community. We show that, from 2003 to 2016, the area releasing deep-sourced CO 2 tripled its extent. This expansion was accompanied by an increase of the background CO 2 flux, over most of the surveyed area (1.4 km 2 ), with increased contributions from non-biogenic source. Concurrently, the amount of diffusively released CO 2 increased up to values typical of persistently degassing active volcanoes (up to 3000 t d -1 ). These variations are consistent with the increase in the flux of magmatic fluids injected into the hydrothermal system, which cause pressure increase and, in turn, condensation within the vapor plume feeding the Solfatara emission.
NASA Astrophysics Data System (ADS)
Tassi, F.; Liccioli, C.; Agusto, M.; Chiodini, G.; Vaselli, O.; Calabrese, S.; Pecoraino, G.; Tempesti, L.; Caponi, C.; Fiebig, J.; Caliro, S.; Caselli, A.
2016-12-01
The Domuyo volcanic complex (Neuquén Province, Argentina) hosts one of the most promising geothermal systems of Patagonia, giving rise to thermal manifestations discharging hot and Cl--rich fluids. This study reports a complete geochemical dataset of gas and water samples collected in three years (2013, 2014 and 2015) from the main fluid discharges of this area. The chemical and isotopic composition (δD-H2O and δ18O-H2O) of waters indicates that rainwater and snow melting are the primary recharge of a hydrothermal reservoir located at relative shallow depth (400-600 m) possibly connected to a second deeper (2-3 km) reservoir. Reactive magmatic gases are completely scrubbed by the hydrothermal aquifer(s), whereas interaction of meteoric waters at the surface causes a significant air contamination and dilution of the fluid discharges located along the creeks at the foothill of the Cerro Domuyo edifice. Thermal discharges located at relatively high altitude ( 3150 m a.s.l.), namely Bramadora, are less affected by this process, as also shown by their relatively high R/Ra values (up to 6.91) pointing to the occurrence of an actively degassing magma batch located at an unknown depth. Gas and solute geothermometry suggests equilibrium temperatures up to 220-240 °C likely referred to the shallower hydrothermal reservoir. These results, confirming the promising indications of the preliminary surveys carried out in the 1980‧s, provide useful information for a reliable estimation of the geothermal potential of this extinct volcanic system, although a detailed geophysical measurements is required for the correct estimation of depth and dimensions of the fluid reservoir(s).
Specific mineral associations of hydrothermal shale (South Kamchatka)
NASA Astrophysics Data System (ADS)
Rychagov, S. N.; Sergeeva, A. V.; Chernov, M. S.
2017-11-01
The sequence of hydrothermal shale from the East Pauzhet thermal field within the Pauzhet hydrothermal system (South Kamchatka) was studied in detail. It was established that the formation of shale resulted from argillization of an andesitic lava flow under the influence of an acidic sulfate vapor condensate. The horizons with radically different compositions and physical properties compared to those of the overlying homogeneous plastic shale were distinguished at the base of the sequence. These horizons are characterized by high (up to two orders of magnitude in comparison with average values in hydrothermal shale) concentrations of F, P, Na, Mg, K, Ca, Sc, Ti, V, Cr, Cu, and Zn. We suggested a geological-geochemical model, according to which a deep metal-bearing chloride-hydrocarbonate solution infiltrated into the permeable zone formed at the root of the andesitic lava flow beneath plastic shale at a certain stage of evolution of the hydrothermal system.
Seafloor doming driven by degassing processes unveils sprouting volcanism in coastal areas.
Passaro, Salvatore; Tamburrino, Stella; Vallefuoco, Mattia; Tassi, Franco; Vaselli, Orlando; Giannini, Luciano; Chiodini, Giovanni; Caliro, Stefano; Sacchi, Marco; Rizzo, Andrea Luca; Ventura, Guido
2016-03-01
We report evidences of active seabed doming and gas discharge few kilometers offshore from the Naples harbor (Italy). Pockmarks, mounds, and craters characterize the seabed. These morphologies represent the top of shallow crustal structures including pagodas, faults and folds affecting the present-day seabed. They record upraise, pressurization, and release of He and CO2 from mantle melts and decarbonation reactions of crustal rocks. These gases are likely similar to those that feed the hydrothermal systems of the Ischia, Campi Flegrei and Somma-Vesuvius active volcanoes, suggesting the occurrence of a mantle source variously mixed to crustal fluids beneath the Gulf of Naples. The seafloor swelling and breaching by gas upraising and pressurization processes require overpressures in the order of 2-3 MPa. Seabed doming, faulting, and gas discharge are manifestations of non-volcanic unrests potentially preluding submarine eruptions and/or hydrothermal explosions.
Seafloor doming driven by degassing processes unveils sprouting volcanism in coastal areas
Passaro, Salvatore; Tamburrino, Stella; Vallefuoco, Mattia; Tassi, Franco; Vaselli, Orlando; Giannini, Luciano; Chiodini, Giovanni; Caliro, Stefano; Sacchi, Marco; Rizzo, Andrea Luca; Ventura, Guido
2016-01-01
We report evidences of active seabed doming and gas discharge few kilometers offshore from the Naples harbor (Italy). Pockmarks, mounds, and craters characterize the seabed. These morphologies represent the top of shallow crustal structures including pagodas, faults and folds affecting the present-day seabed. They record upraise, pressurization, and release of He and CO2 from mantle melts and decarbonation reactions of crustal rocks. These gases are likely similar to those that feed the hydrothermal systems of the Ischia, Campi Flegrei and Somma-Vesuvius active volcanoes, suggesting the occurrence of a mantle source variously mixed to crustal fluids beneath the Gulf of Naples. The seafloor swelling and breaching by gas upraising and pressurization processes require overpressures in the order of 2–3 MPa. Seabed doming, faulting, and gas discharge are manifestations of non-volcanic unrests potentially preluding submarine eruptions and/or hydrothermal explosions. PMID:26925957
Differentiating biotic from abiotic methane genesis in hydrothermally active planetary surfaces
Oze, Christopher; Jones, L. Camille; Goldsmith, Jonas I.; Rosenbauer, Robert J.
2012-01-01
Molecular hydrogen (H2) is derived from the hydrothermal alteration of olivine-rich planetary crust. Abiotic and biotic processes consume H2 to produce methane (CH4); however, the extent of either process is unknown. Here, we assess the temporal dependence and limit of abiotic CH4 related to the presence and formation of mineral catalysts during olivine hydrolysis (i.e., serpentinization) at 200 °C and 0.03 gigapascal. Results indicate that the rate of CH4 production increases to a maximum value related to magnetite catalyzation. By identifying the dynamics of CH4 production, we kinetically model how the H2 to CH4 ratio may be used to assess the origin of CH4 in deep subsurface serpentinization systems on Earth and Mars. Based on our model and available field data, low H2/CH4 ratios (less than approximately 40) indicate that life is likely present and active. PMID:22679287
Differentiating biotic from abiotic methane genesis in hydrothermally active planetary surfaces.
Oze, Christopher; Jones, L Camille; Goldsmith, Jonas I; Rosenbauer, Robert J
2012-06-19
Molecular hydrogen (H(2)) is derived from the hydrothermal alteration of olivine-rich planetary crust. Abiotic and biotic processes consume H(2) to produce methane (CH(4)); however, the extent of either process is unknown. Here, we assess the temporal dependence and limit of abiotic CH(4) related to the presence and formation of mineral catalysts during olivine hydrolysis (i.e., serpentinization) at 200 °C and 0.03 gigapascal. Results indicate that the rate of CH(4) production increases to a maximum value related to magnetite catalyzation. By identifying the dynamics of CH(4) production, we kinetically model how the H(2) to CH(4) ratio may be used to assess the origin of CH(4) in deep subsurface serpentinization systems on Earth and Mars. Based on our model and available field data, low H(2)/CH(4) ratios (less than approximately 40) indicate that life is likely present and active.
Martian Magmatic-Driven Hydrothermal Sites: Potential Sources of Energy, Water, and Life
NASA Technical Reports Server (NTRS)
Anderson, R. C.; Dohm, J. M.; Baker, V. R.; Ferris, J. C.; Hare, T. M.; Tanaka, K. L.; Klemaszewski, J. E.; Skinner, J. A.; Scott, D. H.
2000-01-01
Magmatic-driven processes and impact events dominate the geologic record of Mars. Such recorded geologic activity coupled with significant evidence of past and present-day water/ice, above and below the martian surface, indicate that hydrothermal environments certainly existed in the past and may exist today. The identification of such environments, especially long-lived magmatic-driven hydrothermal environments, provides NASA with significant target sites for future sample return missions, since they (1) could favor the development and sustenance of life, (2) may comprise a large variety of exotic mineral assemblages, and (3) could potentially contain water/ice reservoirs for future Mars-related human activities. If life developed on Mars, the fossil record would presumably be at its greatest concentration and diversity in environments where long-term energy sources and water coexisted such as at sites where long-lived, magmatic-driven hydrothermal activity occurred. These assertions are supported by terrestrial analogs. Small, single-celled creatures (prokaryotes) are vitally important in the evolution of the Earth; these prokaryotes are environmentally tough and tolerant of environmental extremes of pH, temperature, salinity, and anoxic conditions found around hydrothermal vents. In addition, there is a great ability for bacteria to survive long periods of geologic time in extreme conditions, including high temperature hydrogen sulfide and sulfur erupted from Mount St. Helens volcano. Our team of investigators is conducting a geological investigation using multiple mission-derived datasets (e.g., existing geologic map data, MOC imagery, MOLA, TES image data, geophysical data, etc.) to identify prime target sites of hydrothermal activity for future hydrological, mineralogical, and biological investigations. The identification of these sites will enhance the probability of success for future missions to Mars.
Exploration Method Development for hydrothermal plume hunting by XCTD
NASA Astrophysics Data System (ADS)
Kitagawa, Y.; Ikeda, M.; Kadoshima, K.; Koizumi, Y.; Nakano, J.; Asakawa, E.; Sumi, T.
2017-12-01
J-MARES (Research and Development Partnership for Next Generation Technology of Marine Resources Survey, JAPAN) has been designing a low-cost and high-efficiency exploration system for seafloor hydrothermal massive sulfide deposits in "Cross-ministerial Strategic Innovation Promotion Program (SIP)" granted by the Cabinet Office, Government of Japan since 2014. We proposed hydrothermal plume hunting by XCTD (eXpendables Conductivity, Temperature and Depth). We applied this method to an area of interest more than 100km x 100km over Okinawa Trough, including some known seafloor massive sulfide deposits. Generally, hydrothermal plume exploration has been by ship mounted with MBES (Multi Beam Echo Sounder) or AUV with sound anomaly observation. However, these methods have to charter the sophisticated ship costly. On the other hand, throw-in type water quality meters (eg. XCTD and XBT) can be low-cost and easily operable. Moreover, that can make a quick look at seawater temperature and conductivity even in rough waters.Firstly, we confirmed XCTD probes position on the seafloor by ROV mounted deep-sea high vision camera. As a result of the test, probes swept downstream about 40 m in horizontal distance from throwing positions with about 1,600m in water depth. Following the previous test results, we had performed to the next test that confirmed detection range of hydrothermal plume at the chimney of North Mound in Izena Cauldron, so we had caught anomaly of seawater temperature and conductivity successfully which could be possibly derived from hydrothermal activities. Although averaged seawater temperature at a depth of 1500 m or more was about 3.95 degrees C, near the chimney was about 4.93 degrees C. The temperature anomalies originated from the hydrothermal plumes could be distributed at most 30m in horizontal distance and became smaller away from the chimney. Moreover, temperature anomaly mass of sea water tended to move upward in depth with distance away from the chimney.
Hydroxyl defects and conversion thermodynamics and kinetics of hydrothermal barium titanate
NASA Astrophysics Data System (ADS)
Atakan, Vahit
The main objectives of this study are to investigate the possibility of hydrothermal conversion of carboxylate based solid-state precursors to BaTiO3 and to characterize residual H or commonly referred as hydroxyls, which are common defects in hydrothermally synthesized ceramic oxides. Neutron scattering techniques, prompt gamma activation analysis (PGAA) and neutron powder diffraction (NPD) were selected as the main tools for characterization of residual H due to high interaction capability of neutrons with H. Residual H was classified as surface and lattice H. Total H content was measured by PGAA and surface H was measured by Karl Fischer Titration (KFT). NPD was used for estimating lattice H. It was found that 75% of the residual H was in the lattice. Even though more than half of the residual H was removed at low temperatures like 200°C, it was tough to remove H completely even at 1200°C. Residual H caused expansion in the unit cell and presence of lattice H was compensated by Ti vacancies. Yield diagrams were generated depending on a thermodynamic model to theoretically verify that hydrothermal conversion of carboxylate based solid-state precursors to BaTiO3 is possible. Theoretical results were then verified experimentally. It was found that BaC2O 4 and TiO2, and BaTiO(C2O4)2 can be successfully converted to BaTiO3 under hydrothermal conditions. However, BaCO3 and TiO2 precursors were not fully converted. Among barium oxalate and titania, and barium titanly oxalate (BTO) systems, conversion of BTO was more favorable in terms of reaction temperature and KOH concentration. BTO can be hydrothermally converted to BaTiO3 at temperatures as low as room temperature. Further studies on hydrothermal conversion of BTO showed that, reaction time can be reduced from 12 h to less than 5 seconds under atmospheric pressure at ˜103°C.
NASA Astrophysics Data System (ADS)
Nishizawa, Manabu; Miyazaki, Junichi; Makabe, Akiko; Koba, Keisuke; Takai, Ken
2014-08-01
Hyperthermophilic hydrogenotrophic methanogens are considered to be one of the most predominant primary producers in hydrogen (H2)-abundant hydrothermal environments in the present-day ocean and throughout the history of the Earth. However, the nitrogen sources supporting the development of microbial communities in hydrothermal environments remain poorly understood. We have investigated, for the first time, methanogenic archaea commonly found in deep-sea hydrothermal environments to understand their physiological properties (growth kinetics, energetics, and metal requirements) and isotopic characteristics during the fixation of dinitrogen (N2), which is an abundant but less-bioavailable compound in hydrothermal fluids. Culture experiments showed that Methanocaldococcus strain (Mc 1-85N) (Topt = 85 °C) and Methanothermococcus strain (Mt 5-55N) (Topt = 55 °C) assimilated N2 and ammonium, but not nitrate. Previous phylogenetic studies have predicted that the Methanocaldococcus and Methanothermococcus lineages have nitrogenases, key enzymes for N2 fixation, with biochemically uncharacterised active site metal cofactors. We showed that Mt 5-55N required molybdenum for the nitrogenase to function, implying a molybdenum-bearing cofactor in the strain. Molybdenum also stimulated diazotrophic (i.e., N2-fixing) growth of Mc 1-85N, though further experiments are required to test whether the strain contains a molybdenum-dependent nitrogenase. Importantly, Mc 1-85N exhibited an apparently lower requirement of and higher tolerance to molybdenum and iron than Mt 5-55N. Furthermore, both strains produced more 15N-depleted biomass (-4‰ relative to N2) than that previously reported for diazotrophic photosynthetic prokaryotes. These results demonstrate that diazotrophic hyperthermophilic methanogens can be broadly distributed in seafloor and subseafloor hydrothermal environments, where the availability of transition metals is variable and where organic carbon, organic nitrogen, and ammonium are generally scarce. The emergence and function of diazotrophy, coupled with methanogenesis, in the early Earth is also consistent with the nitrogen isotopic records of 3.5 billion-year-old hydrothermal deposits.
ESR dating of barite in sea-floor hydrothermal sulfide deposits at Okinawa Trough
NASA Astrophysics Data System (ADS)
Fujiwara, T.; Toyoda, S.; Uchida, A.; Ishibashi, J.; Nakai, S.; Takamasa, A.
2013-12-01
The temporal change of submarine hydrothermal activities has been an important issue in the aspect of the evolution of hydrothermal systems which is related with ore formation and biological systems sustained by the chemical species arising from hydrothermal activities (Macdonald et al., 1980). With this aspect, Okumura et al. (2010) made the first practical application of ESR (electron spin resonance) dating technique to a sample of submarine hydrothermal barite to obtain preliminary ages, while Kasuya et al. (1991) first pointed out that barite can be used for ESR dating. ESR is a method to observe radicals having unpaired electrons. As natural radiation creates unpaired electrons in minerals, the age is deduced by dividing the natural radiation dose (obtained from the amount of unpaired electrons) by the dose rate which is estimated by the amount of environmental radioactive elements. The samples were taken by the research cruises, NT12-10 and NT11-20 and NT12-06 operated by JAMSTEC from Hatoma, Yoron, Izena, North Iheya, and Yonaguni IV Knolls of Okinawa Trough. The blocks of sulfide deposits were cut into pieces, and about 2.0g was crushed. The samples were soaked in 12M hydrochloric acid, left for approximately 24 hours. Then, 13M nitric acid was added. Finally, after rinsing in distilled water, the sample was filtered and dried. Impurities were removed by handpicking. A X-ray diffraction study was made to confirm that the grains are pure barite. After γ-ray irradiation at Takasaki Advanced Radiation Research Institute, Japan Atomic Energy Agency, they were measured at room temperature with an ESR spectrometer (JES-PX2300) with a microwave power of 1mW, and the magnetic field modulation amplitude of 0.1mT. The equivalent natural radiation doses were obtained from the increase of ESR signal intensity of SO3- by irradiation. The bulk Ra concentration was measured by the low background pure Ge gamma ray spectrometer. Assuming that Ra is populated only in barite, the dose rate was calculated with the alpha effectiveness of 0.043 (Toyoda et al., 2012), where the decay of Ra (a half life of 1600 years) was also taken into account. The dating results indicate that the ages are, Yron Knoll < Hatoma Knoll ≒ North Iheya Knoll < Izena Knoll. This order of ages is consistent with the development of the hydrothermal vent ecosystem estimated by observed landscape.. The results of U-Th dating for these samples will also be presented.
NASA Astrophysics Data System (ADS)
Shi, Z.; Wang, G.
2017-12-01
Understanding the geochemical and geothermal characteristic of the hydrothermal systems provide useful information in appropriate evaluating the geothermal potential in this area. In this paper, we investigate the chemical and isotopic composition of thermal water in an underexploited geothermal belt, Yidun-Litang area, in eastern Tibetan Plateau geothermal belt. 24 hot springs from the Yidun and Litang area were collected and analyzed. The chemical facies of the hot springs are mainly Na-HCO3 type water. Water-rock interaction, cation exchange are the dominant hydrogeochemical processes in the hydrothermal evolution. All the hot springs show long-time water-rock interaction and significant 18O shift occurred in the Yindun area. Tritium data indicate the long-time water-rock interaction time in the hydrothermal system. According to the isotope and geochemical data, the hydrothermal systems in Yidun and Litang area may share a common deep parent geothermal liquid but receive different sources of meteoric precipitation and undergone different geochemical processes. The Yidun area have relative high reservoir equilibrium temperature (up to 230 °C) while the reservoir temperature at Litang area is relative low (up to 128 °C).
The hydrothermal exploration system on the 'Qianlong2' AUV
NASA Astrophysics Data System (ADS)
Tao, W.; Tao, C.; Jinhui, Z.; Cai, L.; Guoyin, Z.
2016-12-01
ABSTRACT: Qianlong2, is a fully Autonomous Underwater Vehicle (AUV) designed for submarine resources research, especially for polymetallic sulphides, and the survey depths of is up to 4500 m. Qianlong2 had successfully explored hydrothermal vent field on the Southwest Indian Ridge (SWIR), and collected conductance, temperature and depth (CTD), turbidity, and Oxidation-Reduction Potential (ORP) data. It also had mapped precise topography by high resolution side scan sonar (HRBSSS) during every dive; and obtained photographs of sulfide deposits during some dives. Here, we detailedly described the implementation of investigation, data administration, and fast mapping of hydrothermal exploration system by Qianlong2. Giving a description of how to remove the platform magnetic interference by using magnetic data during Qianlong2 spin. Based on comprehensive hydrochemical anomalies, we get a rapid method for finding the localization of hydrothermal vents. Taking one dive as an example, we systemically showed the process about how to analyse hydrothermal survey data and acquire the location results of hydrothermal vents. Considering that this method is effective and can be used in other deep-submergence assets such as human occupied vehicles (HOVs) and remotely operated vehicles (ROVs) during further studies. Finally, we discussed how to promote and optimize the installation and application of those sensors and how to improve Qianlong2's autonomy of investigation.
NASA Astrophysics Data System (ADS)
German, C. R.
2012-12-01
In January 2012 our multi-national and multi-disciplinary team conducted a series of 10 ROV Jason dives to conduct first detailed and systematic sampling of the Mid Cayman Rise hydrothermal systems at the Von Damm and Piccard hydrothermal fields. At Von Damm, hydrothermal venting is focused at and around a large conical structure that is approximately 120 m in diameter and rises at least 80m from the surrounding, largely sedimented seafloor. Clear fluids emitted from multiple sites around the flanks of the mound fall in the temperature range 110-130°C and fall on a common mixing line with hotter (>200°C) clear fluids emitted from an 8m tall spire at the summit which show clear evidence of ultramafic influence. Outcrop close to the vent-site is rare and the cone itself appear to consist of clay minerals derived from highly altered host rock. The dominant fauna at the summit of Von Damm are a new species of chemosynthetic shrimp but elsewhere the site also hosts two distinct species of chemosynthetic tube worm as well as at least one species of gastropod. The adjacent Piccard site, at ~5000m depth comprises 7 distinct sulfide mounds, 3 of which are currently active: Beebe Vents, Beebe Woods and Beebe Sea. Beebe Vents consists of 5 vigorous black smoker chimneys with maximum temperatures in the range 400-403°C while at Beebe Woods a more highly colonized thicket of up to 8m tall chimneys includes predominantly beehive diffusers with rare black smokers emitting fluids up to 353°C. Beebe Sea a diffuse site emitting fluids at 38°C Tmax, is the largest of the currently active mounds and immediately abuts a tall (8m) rift that strikes NE-SW bisecting the host Axial Volcanic Ridge. The fauna at Piccard are less diverse than at Von Damm and, predominantly, comprise the same species of MCR shrimp, a distinct gastropod species and abundant anemones.
NASA Astrophysics Data System (ADS)
Daud, Yunus; Rosid, Syamsu; Fahmi, Fikri; Yunus, Faris Maulana; Muflihendri, Reza
2018-02-01
Ijen geothermal area is high-temperature geothermal system located in Bondowoso regency, East Java. It is categorized as caldera-hosted geothermal system which is covered by quaternary andesitic volcanic rocks with steep topography at the surrounding. Several surface thermal manifestations are found, such as altered rocks near Mt. Kukusan and a group of Blawan hotsprings in the northern part of the caldera. Geomagnetic survey was conducted at 72 stations which is distributed inside the caldera to delineate the existence of hydrothermal activity. Magnetic anomaly was obtained by reducing total magnetic measured on the field by IGRF and diurnal variation. Reduction to pole (RTP) method was applied with geomagnetic inclination of about -32°. In general, the result shows that high magnetic anomaly is distributed at the boundary of study area, while low magnetic anomaly is observed in the centre. The low anomaly indicates demagnetized rock that probably caused by hydrothermal activity. It has a good correlation with surface alteration observed close to Mt. Kukusan as well as high temperature reservoir drilled in the centre of caldera. Accordingly, the low magnetic anomaly also presents the possibility of geothermal reservoir in Ijen geothermal area.
Monitoring diffuse volcanic degassing during volcanic unrests: the case of Campi Flegrei (Italy)
NASA Astrophysics Data System (ADS)
Cardellini, Carlo; Chiodini, Giovanni; Avino, Rosario; Bagnato, Emanuela; Caliro, Stefano; Frondini, Francesco; Lelli, Matteo; Rosiello, Angelo
2017-04-01
Hydrothermal activity at Solfatara of Pozzuoli (Campi Flegrei caldera, Italy) results on a large area of hot soils, diffuse CO2 degassing and numerous fumaroles, releasing at the surface large amounts of gasses and thermal energy. Solfatara is one of the first sites of the world where the techniques for measuring and interpreting soil CO2 diffuse degassing were developed during 1990's and, more recently, it has become a sort of natural laboratory for testing new types of measurements of the CO2 fluxes from hydrothermal sites. The results of 30 diffuse CO2 flux surveys performed at Solfatara from 1998 to 2016 are presented and discussed. CO2 soil fluxes were measured over an area of about 1.2 1.2 km including the Solfatara crater and the hydrothermal site of Pisciarelli using the accumulation chamber technique. Each survey consisted in a number of CO2 flux measurements varying from 372 to 583 resulting in a total of 13158 measurements. This data set is one of the largest dataset ever made in the world on a single degassing volcanic-hydrothermal system. It is particularly relevant in the frame of volcanological sciences because it was acquired during a long period of unrest at Campi Flegrei caldera and because Solfatara release an amount of CO2 comparable to that released by medium-large volcanic plumes. Statistical and geostatistical elaborations of CO2 flux data allowed to characterise the sources of soil diffuse degassing, to define the extent of the area interested by the release of hydrothermal CO2 (Solfatara DDS) and to quantify the total amount of released CO2. During the last eighteen years relevant variations affected Solfatara degassing, and in particular the "background" CO2 emission , the extent of DDS and the total CO2 output, that may reflect variations in the subterraneous gas plume feeding the Solfatara and Pisciarelli emissions. In fact, the most relevant variations in Solfatara diffuse degassing well correlates with steam condensation and temperature increase affecting the Solfatara system resulting from repeated inputs of magmatic fluids into the hydrothermal systems as suggested by Chiodini et al., (2015; 2016; 2017) and show a long-term increase on the amount of released CO2 that accompanies the ongoing unrest of Campi Flegrei caldera.
NASA Astrophysics Data System (ADS)
Ramírez-Leiva, A.; Sánchez-Murillo, R.; Martínez-Cruz, M.; Calderón, H.; Esquivel-Hernández, G.; Delgado, V.; Birkel, C.; Gazel, E.; Alvarado, G. E.; Soulsby, C.
2017-10-01
The Central America volcanic front provides a unique opportunity to study hydrothermal inputs and their interaction and mixing with modern meteoric waters. The objectives of this study were to: a) characterize the isotopic composition (δ18O, δ2H, d-excess, and lc-excess) of hydrothermal/volcanic systems, b) analyze the influence of kinetic fractionation and meteoric water inputs in the isotopic composition of hydrothermal waters, and c) estimate the 'andesitic water' contribution (recycled subduction fluids) within the volcanic front of Nicaragua and Costa Rica. Hydrothermal evaporation lines are described as: δ2H = 4.7·δ18O - 13.0 (Costa Rica) and δ2H = 2.7·δ18O - 31.6 (Nicaragua). These regressions are significantly (p < 0.001) deviated from their respective meteoric water lines: δ2H = 7.6·δ18O + 7.4 (Costa Rica) and δ2H = 7.4·δ18O + 5.2 (Nicaragua). The greater rainfall inputs in Costa Rica with respect to Nicaragua, resulted in the attenuation of the evaporative effect as observed in the strong bimodal distribution of the hydrothermal waters, which can be divided in fluids: a) isotopically-close to meteoric conditions and b) isotopically-altered by the interaction with recycled subduction fluids and kinetic fractionation. The latter is clearly depicted in the significantly (p < 0.001) low d-excess and lc-excess median values between Costa Rica (+ 5.10‰, - 5.25‰) and Nicaragua (- 2.42‰, - 10.65‰), respectively. Poor correlations between δ18O/δ2H and the elevation gradient emphasize that the contribution of recycled subduction fluids and subsequent surface kinetic fractionation are the main drivers of the isotopic departure from the orographic distillation trend captured in the rainfall isoscapes. End-member mixing calculations resulted in a significant difference (p < 0.001) between the mean 'andesitic water' contribution to the hydrothermal systems of 15.3 ± 10.8 (%, ± 1σ) (Nicaragua) and 19.7 ± 10.3 (%, ± 1σ) (Costa Rica). The spectrum of 'andesitic water' contribution largely reflects the degree of mixing with isotopically 'pre-shifted' recycled subduction fluids. The latter is supported by previous strong evidence of mantle-derived N2/He contributions across the volcanic front of Nicaragua and Costa Rica.
Reconstructing the Vulcano Island evolution from 3D modeling of magnetic signatures
NASA Astrophysics Data System (ADS)
Napoli, Rosalba; Currenti, Gilda
2016-06-01
High-resolution ground and marine magnetic data are exploited for a detailed definition of a 3D model of the Vulcano Island volcanic complex. The resulting 3D magnetic imaging, obtained by 3-D inverse modeling technique, has delivered useful constraints both to reconstruct the Vulcano Island evolution and to be used as input data for volcanic hazard assessment models. Our results constrained the depth and geometry of the main geo-structural features revealing more subsurface volcanic structures than exposed ones and allowing to elucidate the relationships between them. The recognition of two different magnetization sectors, approximatively coincident with the structural depressions of Piano caldera, in the southern half of the island, and La Fossa caldera at the north, suggests a complex structural and volcanic evolution. Magnetic highs identified across the southern half of the island reflect the main crystallized feeding systems, intrusions and buried vents, whose NNW-SSE preferential alignment highlights the role of the NNW-SSE Tindari-Letojanni regional system from the initial activity of the submarine edifice, to the more recent activity of the Vulcano complex. The low magnetization area, in the middle part of the island may result from hydrothermally altered rocks. Their presence not only in the central part of the volcano edifice but also in other peripheral areas, is a sign of a more diffuse historical hydrothermal activity than in present days. Moreover, the high magnetization heterogeneity within the upper flanks of La Fossa cone edifice is an imprint of a composite distribution of unaltered and altered rocks with different mechanical properties, which poses in this area a high risk level for failure processes especially during volcanic or hydrothermal crisis.
The potential hydrothermal systems unexplored in the Southwest Indian Ocean
NASA Astrophysics Data System (ADS)
Suo, Yanhui; Li, Sanzhong; Li, Xiyao; Zhang, Zhen; Ding, Dong
2017-06-01
Deep-sea hydrothermal vents possess complex ecosystems and abundant metallic mineral deposits valuable to human being. On-axial vents along tectonic plate boundaries have achieved prominent results and obtained huge resources, while nearly 90% of the global mid-ocean ridge and the majority of the off-axial vents buried by thick oceanic sediments within plates remain as relatively undiscovered domains. Based on previous detailed investigations, hydrothermal vents have been mapped along five sections along the Southwest Indian Ridge (SWIR) with different bathymetry, spreading rates, and gravity features, two at the western end (10°-16°E Section B and 16°-25°E Section C) and three at the eastern end (49°-52°E Section D, 52°-61°E Section E and 61°-70°E Section F). Hydrothermal vents along the Sections B, C, E and F with thin oceanic crust are hosted by ultramafic rocks under tectonic-controlled magmatic-starved settings, and hydrothermal vents along the Section D are associated with exceed magmatism. Limited coverage of investigations is provided along the 35°-47°E SWIR (between Marion and Indomed fracture zones) and a lot of research has been done around the Bouvet Island, while no hydrothermal vents has been reported. Analyzing bathymetry, gravity and geochemical data, magmatism settings are favourable for the occurrence of hydrothermal systems along these two sections. An off-axial hydrothermal system in the southern flank of the SWIR that exhibits ultra-thin oceanic crust associated with an oceanic continental transition is postulated to exist along the 100-Ma slow-spreading isochron in the Enderby Basin. A discrete, denser enriched or less depleted mantle beneath the Antarctic Plate is an alternative explanation for the large scale thin oceanic crust concentrated on the southern flank of the SWIR.
NASA Technical Reports Server (NTRS)
McCollom, T. M.; Simoneit, B. R.; Shock, E. L.
1999-01-01
Polycyclic aromatic hydrocarbons (PAH) are found at high concentrations in thermally altered organic matter and hydrothermally generated petroleum from sediment-covered seafloor hydro-thermal systems. To better understand the factors controlling the occurrence of PAH in thermally altered environments, the reactivities of two PAH, phenanthrene and anthracene, were investigated in hydrothermal experiments. The compounds were heated with water at 330 degrees C in sealed reaction vessels for durations ranging from 1 to 17 days. Iron oxide and sulfide minerals, formic acid, or sodium for-mate were included in some experiments to vary conditions within the reaction vessel. Phenanthrene was unreactive both in water alone and in the presence of minerals for up to 17 days, while anthracene was partially hydrogenated (5-10%) to di- and tetrahydroanthracene. In the presence of 6-21 vol % formic acid, both phenanthrene and anthracene reacted extensively to form hydrogenated and minor methylated derivatives, with the degree of hydrogenation and methylation increasing with the amount of formic acid. Phenanthrene was slightly hydrogenated in sodium formate solutions. The hydrogenation reactions could be readily reversed; heating a mixture of polysaturated phenanthrenes resulted in extensive dehydrogenation (aromatization) after 3 days at 330 degrees C. While the experiments demonstrate that reaction pathways for the hydrogenation of PAH under hydrothermal conditions exist, the reactions apparently require higher concentrations of H2 than are typical of geologic settings. The experiments provide additional evidence that PAH may be generated in hydrothermal systems from progressive aromatization and dealkylation of biologically derived polycyclic precursors such as steroids and terpenoids. Furthermore, the results indicate that PAH initially present in sediments or formed within hydrothermal systems are resistant to further thermal degradation during hydrothermal alteration.
Groundwater flow processes and mixing in active volcanic systems: the case of Guadalajara (Mexico)
NASA Astrophysics Data System (ADS)
Hernández-Antonio, A.; Mahlknecht, J.; Tamez-Meléndez, C.; Ramos-Leal, J.; Ramírez-Orozco, A.; Parra, R.; Ornelas-Soto, N.; Eastoe, C. J.
2015-09-01
Groundwater chemistry and isotopic data from 40 production wells in the Atemajac and Toluquilla valleys, located in and around the Guadalajara metropolitan area, were determined to develop a conceptual model of groundwater flow processes and mixing. Stable water isotopes (δ2H, δ18O) were used to trace hydrological processes and tritium (3H) to evaluate the relative contribution of modern water in samples. Multivariate analysis including cluster analysis and principal component analysis were used to elucidate distribution patterns of constituents and factors controlling groundwater chemistry. Based on this analysis, groundwater was classified into four groups: cold groundwater, hydrothermal groundwater, polluted groundwater and mixed groundwater. Cold groundwater is characterized by low temperature, salinity, and Cl and Na concentrations and is predominantly of Na-HCO3-type. It originates as recharge at "La Primavera" caldera and is found predominantly in wells in the upper Atemajac Valley. Hydrothermal groundwater is characterized by high salinity, temperature, Cl, Na and HCO3, and the presence of minor elements such as Li, Mn and F. It is a mixed-HCO3 type found in wells from Toluquilla Valley and represents regional flow circulation through basaltic and andesitic rocks. Polluted groundwater is characterized by elevated nitrate and sulfate concentrations and is usually derived from urban water cycling and subordinately from agricultural return flow. Mixed groundwaters between cold and hydrothermal components are predominantly found in the lower Atemajac Valley. Twenty-seven groundwater samples contain at least a small fraction of modern water. The application of a multivariate mixing model allowed the mixing proportions of hydrothermal fluids, polluted waters and cold groundwater in sampled water to be evaluated. This study will help local water authorities to identify and dimension groundwater contamination, and act accordingly. It may be broadly applicable to other active volcanic systems on Earth.
NASA Astrophysics Data System (ADS)
Tang, Xianchun; Zhang, Jian; Pang, Zhonghe; Hu, Shengbiao; Tian, Jiao; Bao, Shujing
2017-10-01
The eastern Tibetan Plateau geothermal belt (ETGB), which is located in 98-102°E, 28-32°N, belongs to the eastern part of the Mediterranean-Himalayan geothermal belt. Recently, about 248 natural hot springs have been found in the ETGB. > 60% of these springs have temperatures of > 40 °C, and 11 springs have temperature above the local water boiling point. Using the helium isotopic data, gravity, magnetic and seismic data, we analyzed the thermal structure and the relationship between hydrothermal activity and geothermal dynamics of the ETGB. Results show that: (1) the 248 springs can be divided into three geothermal fields: Kangding-Luhuo geothermal field (KGF), Litang-Ganzi geothermal field (LGF) and Batang-Xiangcheng geothermal field (BGF). The BGF and LGF have hot crust and warm mantle, and are characterized by the higher heat flux (66.26 mW/m2), and higher ratios of crust-derived heat flux to total flux (47.46-60.62%). The KGF has cool crust and hot mantle, and is characterized by the higher heat flux and lower Qc/Qm; (2) there is a relatively 4-6 m higher gravimetric geoid anomaly dome which is corresponding with the ETGB. And in hydrothermal activity areas of the BGF and LGF, there is a northwest - southeast-trending tensile stress area and the upper-middle crust uplift area; (3) an abnormal layer exists in the middle-lower crust at a depth of 13-30 km beneath the ETGB, and this layer is 8-10 km thick and is characterized by lower velocity (Vp < 5.8 km/s, Vs < 3.2 km/s), high Poisson's ratio (> 2.5), high conductivity ( 10 Ω·m) and high temperature (850-1000 °C). Finally, based on the heat source and geological and geophysical background, we propose Kangding-type and Batang-type hydrothermal system models in the ETGB.
NASA Astrophysics Data System (ADS)
Kurniati, M.; Nurhayati, D.; Maddu, A.
2017-03-01
The important part of fuel cell is the gas diffusion layer who made from carbon based material porous and conductive. The main goal of this research is to obtain carbon material from sugarcane bagasse with hydrothermal carbonization and chemical-physics activation. There were two step methods in this research. The first step was sample preparation which consisted of prepare the materials, hydrothermal carbonization and chemical-physics activation. The second one was analyze character of carbon using EDS, SEM, XRD, and LCR meter. The amount of carbon in sugarcane bagasse-carbon was about 85%-91.47% with pore morphology that already form. The degree of crystallinity of sugarcane bagasse carbon was about 13.06%-20.89%, leaving the remain as the amorphous phase. Electrical conductivity was about 5.36 x 10-2 Sm-1 - 1.11 Sm-1. Sugarcane bagasse-carbon has porous characteristic with electrical conductivity property as semiconductor. Sugarcane bagasse-carbon with hydrothermal carbonization potentially can be used as based material for fuel cell if only time of hydrothermal carbonization hold is increased.
NASA Astrophysics Data System (ADS)
Tanaka, Ryo; Hashimoto, Takeshi; Matsushima, Nobuo; Ishido, Tsuneo
2018-05-01
We investigate a volcanic hydrothermal system using numerical simulations, focusing on change in crater temperature. Both increases and decreases in crater temperature have been observed before phreatic eruptions. We follow the system's response for up to a decade after hydrothermal fluid flux from the deep part of the system is increased and permeability is reduced at a certain depth in a conduit. Our numerical simulations demonstrate that: (1) changes in crater temperature are controlled by the magnitude of the increase in hydrothermal fluid flux and the degree of permeability reduction; (2) significant increases in hydrothermal flux with decreases in permeability induce substantial pressure changes in shallow depths in the edifice and decreases in crater temperature; (3) the location of maximum pressure change differs between the mechanisms. The results of this study imply that it is difficult to predict eruptions by crater temperature change alone. One should be as wary of large eruptions when crater temperature decreases as when crater temperature increases. It is possible to clarify the implications of changes in crater temperature with simultaneous observation of ground deformation.[Figure not available: see fulltext.
NASA Astrophysics Data System (ADS)
Buskop, J.; Joseph, E. P.; Inguaggiato, S.; Varekamp, J. C.; Ku, T.
2017-12-01
The major goals of volcano hydrothermal monitoring are to obtain information on temperature, origin, and changes in chemical composition of volcanic fluids. This data contributes to the baseline geochemical monitoring of volcanic activity and informs on potential volcanic hazards to which the public may be exposed. The origins of hydrothermal fluids are diverse and can be magmatic, crustal and atmospheric. Studies of isotopes, inert gases, and thermodynamic calculations help elucidate the origin in each case and determine provenance of volatiles and a re-evaluation of reservoir temperatures. Sulphur isotope ratio (δ34S) for H2S leached from rock is <0 ‰, of magmatic origin = 0‰ and of marine origin >0 ‰. Low δ15N (-7.3 ‰) is indicative of low sediment addition to source magmas, while high δ15N (+2.1 ‰) indicates greater sediment contribution in magma formation. Baseline monitoring of hydrothermal gases of Dominica for the period 2000 - 2006 show compositions typical of those found in arc-type settings, with N2 excess and low amounts of He and Ar. The dry gas is dominated by CO2 (ranging from 492 to 993 mmol/mol), and has a hydrothermal signature with hydrogen sulphide as the main sulphurous gas. Over the past decade, Dominica has experienced volcanic and tectonic seismicity and a sudden draining episode at the Boiling Lake in November 2016. This study evaluates data obtained in 2017 on gas composition from five (5) hydrothermal areas across the island (Valley of Desolation, Sulphur Spring, Watten Waven, Galion and Penville cold Soufriere) to determine temporal and spatial deviations from baseline geochemical conditions. This study also presents new data, obtained in 2017, on sulphur and nitrogen isotopes to evaluate contributions from various source components. Preliminary results show high CH4/CO2 ratios for gases from Sulphur Springs and Galion, indicative of a significant hydrothermal contribution to these fluids. However, high helium isotope compositions of 7.02 R/Ra signify a clear magmatic origin. This is consistent with the previously established baseline chemistry of the hydrothermal systems on Dominica.
Campbell, Barbara J; Polson, Shawn W; Zeigler Allen, Lisa; Williamson, Shannon J; Lee, Charles K; Wommack, K Eric; Cary, S Craig
2013-01-01
Hydrothermal vents differ both in surface input and subsurface geochemistry. The effects of these differences on their microbial communities are not clear. Here, we investigated both alpha and beta diversity of diffuse flow-associated microbial communities emanating from vents at a basalt-based hydrothermal system along the East Pacific Rise (EPR) and a sediment-based hydrothermal system, Guaymas Basin. Both Bacteria and Archaea were targeted using high throughput 16S rRNA gene pyrosequencing analyses. A unique aspect of this study was the use of a universal set of 16S rRNA gene primers to characterize total and diffuse flow-specific microbial communities from varied deep-sea hydrothermal environments. Both surrounding seawater and diffuse flow water samples contained large numbers of Marine Group I (MGI) Thaumarchaea and Gammaproteobacteria taxa previously observed in deep-sea systems. However, these taxa were geographically distinct and segregated according to type of spreading center. Diffuse flow microbial community profiles were highly differentiated. In particular, EPR dominant diffuse flow taxa were most closely associated with chemolithoautotrophs, and off axis water was dominated by heterotrophic-related taxa, whereas the opposite was true for Guaymas Basin. The diversity and richness of diffuse flow-specific microbial communities were strongly correlated to the relative abundance of Epsilonproteobacteria, proximity to macrofauna, and hydrothermal system type. Archaeal diversity was higher than or equivalent to bacterial diversity in about one third of the samples. Most diffuse flow-specific communities were dominated by OTUs associated with Epsilonproteobacteria, but many of the Guaymas Basin diffuse flow samples were dominated by either OTUs within the Planctomycetes or hyperthermophilic Archaea. This study emphasizes the unique microbial communities associated with geochemically and geographically distinct hydrothermal diffuse flow environments.
Campbell, Barbara J.; Polson, Shawn W.; Zeigler Allen, Lisa; Williamson, Shannon J.; Lee, Charles K.; Wommack, K. Eric; Cary, S. Craig
2013-01-01
Hydrothermal vents differ both in surface input and subsurface geochemistry. The effects of these differences on their microbial communities are not clear. Here, we investigated both alpha and beta diversity of diffuse flow-associated microbial communities emanating from vents at a basalt-based hydrothermal system along the East Pacific Rise (EPR) and a sediment-based hydrothermal system, Guaymas Basin. Both Bacteria and Archaea were targeted using high throughput 16S rRNA gene pyrosequencing analyses. A unique aspect of this study was the use of a universal set of 16S rRNA gene primers to characterize total and diffuse flow-specific microbial communities from varied deep-sea hydrothermal environments. Both surrounding seawater and diffuse flow water samples contained large numbers of Marine Group I (MGI) Thaumarchaea and Gammaproteobacteria taxa previously observed in deep-sea systems. However, these taxa were geographically distinct and segregated according to type of spreading center. Diffuse flow microbial community profiles were highly differentiated. In particular, EPR dominant diffuse flow taxa were most closely associated with chemolithoautotrophs, and off axis water was dominated by heterotrophic-related taxa, whereas the opposite was true for Guaymas Basin. The diversity and richness of diffuse flow-specific microbial communities were strongly correlated to the relative abundance of Epsilonproteobacteria, proximity to macrofauna, and hydrothermal system type. Archaeal diversity was higher than or equivalent to bacterial diversity in about one third of the samples. Most diffuse flow-specific communities were dominated by OTUs associated with Epsilonproteobacteria, but many of the Guaymas Basin diffuse flow samples were dominated by either OTUs within the Planctomycetes or hyperthermophilic Archaea. This study emphasizes the unique microbial communities associated with geochemically and geographically distinct hydrothermal diffuse flow environments. PMID:23898323
NASA Astrophysics Data System (ADS)
Ueda, Hisahiro; Shibuya, Takazo; Sawaki, Yusuke; Saitoh, Masafumi; Takai, Ken; Maruyama, Shigenori
2016-12-01
To understand the chemical nature of hydrothermal fluids in the komatiite-hosted seafloor hydrothermal system in the Hadean, we conducted two hydrothermal serpentinization experiments involving synthetic komatiite and a CO2-rich acidic NaCl fluid at 250 and 350 °C, 500 bars. During the experiments, the komatiites were strongly carbonated to yield iron-rich dolomite (3-9 wt.% FeO) at 250 °C and calcite (<0.8 wt.% FeO) at 350 °C, respectively. The carbonation of komatiites suppressed H2 generation in the fluids. The steady-state H2 concentrations in the fluid were approximately 0.024 and 2.9 mmol/kg at 250 and 350 °C, respectively. This correlation between the Fe content in carbonate mineral and the H2 concentration in the fluid suggests that the incorporation of ferrous iron into the carbonate mineral probably limited magnetite formation and consequent generation of hydrogen during the serpentinization of komatiites. The H2 concentration of the fluid at 350 °C corresponds to that of modern H2-rich seafloor hydrothermal systems, such as the Kairei hydrothermal field, where hydrogenotrophic methanogens dominate in the prosperous microbial ecosystem. Accordingly, the high-temperature serpentinization of komatiite would provide the H2-rich hydrothermal environments that were necessary for the emergence and early evolution of life in the Hadean ocean. In contrast, H2-rich fluids may not have been generated by serpentinization at temperatures below 250 °C because carbonate minerals become more stable with decreasing temperature in the komatiite-H2O-CO2 system.
NASA Astrophysics Data System (ADS)
Lu, G. S.; Amend, J.; LaRowe, D.
2017-12-01
Chemolithoautotrophic microorganisms are important primary producers in hydrothermal environments. The potential catabolic energy sources that thermophilic chemolithoautotrophs can take advantage of can be quantified by combining analytical geochemical data and thermodynamic calculations. This approach explicitly considers how microbial communities are shaped by environmental conditions such as temperature, pressure, pH and the concentrations of electron donors and acceptors. In this study, we have calculated the Gibbs free energy available from 730 redox reactions in 30 terrestrial, shallow-sea, and deep-sea hydrothermal venting systems around the world (326 geochemical data sets) to better determine the relationship between microbial physiology and environment. The reactions with NO2-, O2, MnO2 and NO3- as terminal electron acceptors yield 5-20 kJ/mol e- more energy in terrestrial and shallow-sea hydrothermal systems than in deep-sea hydrothermal settings. However, reactions in which As5+, S0, FeS2 and SO42- as electron acceptors are more favorable by 5-30 kJ/mol e- in deep-sea hydrothermal systems than in the other two types of hydrothermal systems. The most exergonic reactions were predominantly NO2-, O2, MnO2 and NO3- reduction or Fe2+, pyrite, CO and CH4 oxidation. In contrast, reduction of N2, CO, and CO2 or oxidation of N2, Mn2+, and NO2-, though still often exergonic, yielded significantly less energy. Our results provide a comprehensive view of the distribution of energy supplies from redox reactions in high-temperature ecosystems on a global scale. Furthermore, the bioenergetic modeling carried out in this study can be used to test physiological predictions made from metagenomic and proteomic data sets, explore in situ biogeochemical interactions, predict possible but yet-to-be observed metabolisms and guide cultivation efforts.
Mars, John L.
2013-01-01
Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) data and Interactive Data Language (IDL) logical operator algorithms were used to map hydrothermally altered rocks in the central and southern parts of the Basin and Range province of the United States. The hydrothermally altered rocks mapped in this study include (1) hydrothermal silica-rich rocks (hydrous quartz, chalcedony, opal, and amorphous silica), (2) propylitic rocks (calcite-dolomite and epidote-chlorite mapped as separate mineral groups), (3) argillic rocks (alunite-pyrophyllite-kaolinite), and (4) phyllic rocks (sericite-muscovite). A series of hydrothermal alteration maps, which identify the potential locations of hydrothermal silica-rich, propylitic, argillic, and phyllic rocks on Landsat Thematic Mapper (TM) band 7 orthorectified images, and geographic information systems shape files of hydrothermal alteration units are provided in this study.
Hydrothermal pretreatment of palm oil empty fruit bunch
NASA Astrophysics Data System (ADS)
Simanungkalit, Sabar Pangihutan; Mansur, Dieni; Nurhakim, Boby; Agustin, Astrid; Rinaldi, Nino; Muryanto, Fitriady, Muhammad Ariffudin
2017-01-01
Hydrothermal pretreatment methods in 2nd generation bioethanol production more profitable to be developed, since the conventional pretreatment, by using acids or alkalis, is associated with the serious economic and environmental constraints. The current studies investigate hydrothermal pretreatment of palm oil empty fruit bunch (EFB) in a batch tube reactor system with temperature and time range from 160 to 240 C and 15 to 30 min, respectively. The EFB were grinded and separated into 3 different particles sizes i.e. 10 mesh, 18 mesh and 40 mesh, prior to hydrothermal pretreatment. Solid yield and pH of the treated EFB slurries changed over treatment severities. The chemical composition of EFB was greatly affected by the hydrothermal pretreatment especially hemicellulose which decreased at higher severity factor as determined by HPLC. Both partial removal of hemicellulose and migration of lignin during hydrothermal pretreatment caused negatively affect for enzymatic hydrolysis. This studies provided important factors for maximizing hydrothermal pretreatment of EFB.
The Growth of Berlinite (AlPO4) Single Crystals.
1980-03-01
Solubility of AlPO 4 18 6. Solubility Data of Jahn and Kordes on AlPO4 19 7. AlPO 4 Seed Crystal 23 8. Tem-Pres Hydrothermal Research Unit 25 9...Since the vapor pressure of water rises rapidly with temperature, a closed hydrothermal system was used. In a seeded hydrothermal growth process, the...to investigate the hydrothermal growth of Berlinite (AlPO4 ) to determine the optimum growth conditions for large high quality crystals. Over thirty
NASA Astrophysics Data System (ADS)
Roulleau, Emilie; Bravo, Francisco; Pinti, Daniele L.; Barde-Cabusson, Stéphanie; Pizarro, Marcela; Tardani, Daniele; Muñoz, Carlos; Sanchez, Juan; Sano, Yuji; Takahata, Naoto; de la Cal, Federico; Esteban, Carlos; Morata, Diego
2017-07-01
Natural geothermal systems are limited areas characterized by anomalously high heat flow caused by recent tectonic or magmatic activity. The heat source at depth is the result of the emplacement of magma bodies, controlled by the regional volcano-tectonic setting. In contrast, at a local scale a well-developed fault-fracture network favors the development of hydrothermal cells, and promotes the vertical advection of fluids and heat. The Southern Volcanic Zone (SVZ), straddling Chile and Argentina, has an important, yet unexplored and undeveloped geothermal potential. Studies on the lithological and tectonic controls of the hydrothermal circulation are therefore important for a correct assessment of the geothermal potential of the region. Here, new and dense self-potential (SP), soil CO2 and temperature (T) measurements, and helium isotope data measured in fumaroles and thermal springs from the geothermal area located in the north-eastern flank of the Copahue volcanic edifice, within the Caviahue Caldera (the Caviahue-Copahue Volcanic Complex - CCVC) are presented. Our results allowed to the constraint of the structural origin of the active thermal areas and the understanding of the evolution of the geothermal system. NE-striking faults in the area, characterized by a combination of SP, CO2, and T maxima and high 3He/4He ratios (up to 8.16 ± 0.21Ra, whereas atmospheric Ra is 1.382 × 10- 6), promote the formation of vertical permeability preferential pathways for fluid circulation. WNW-striking faults represent low-permeability pathways for hydrothermal fluid ascent, but promote infiltration of meteoric water at shallow depths, which dilute the hydrothermal input. The region is scattered with SP, CO2, and T minima, representing self-sealed zones characterized by impermeable altered rocks at depth, which create local barriers for fluid ascent. The NE-striking faults seem to be associated with the upflowing zones of the geothermal system, where the boiling process produces a high vapor-dominated zone close to the surface, whereas the WNW-striking faults could act as a boundary of the Copahue geothermal area to the south.
Hydrothermal systems on Mars: an assessment of present evidence
NASA Technical Reports Server (NTRS)
Farmer, J. D.
1996-01-01
Hydrothermal processes have been suggested to explain a number of observations for Mars, including D/H ratios of water extracted from Martian meteorites, as a means for removing CO2 from the Martian atmosphere and sequestering it in the crust as carbonates, and as a possible origin for iron oxide-rich spectral units on the floors of some rifted basins (chasmata). There are numerous examples of Martian channels formed by discharges of subsurface water near potential magmatic heat sources, and hydrothermal processes have also been proposed as a mechanism for aquifer recharge needed to sustain long term erosion of sapping channels. The following geological settings have been identified as targets for ancient hydrothermal systems on Mars: channels located along the margins of impact crater melt sheets and on the slopes of ancient volcanoes; chaotic and fretted terranes where shallow subsurface heat sources are thought to have interacted with ground ice; and the floors of calderas and rifted basins (e.g. chasmata). On Earth, such geological environments are often a locus for hydrothermal mineralization. But we presently lack the mineralogical information needed for a definitive evaluation of hypotheses. A preferred tool for identifying minerals by remote sensing methods on Earth is high spatial resolution, hyperspectral, near-infrared spectroscopy, a technique that has been extensively developed by mineral explorationists. Future efforts to explore Mars for ancient hydrothermal systems would benefit from the application of methods developed by the mining industry to look for similar deposits on Earth. But Earth-based exploration models must be adapted to account for the large differences in the climatic and geological history of Mars. For example, it is likely that the early surface environment of Mars was cool, perhaps consistently below freezing, with the shallow portions of hydrothermal systems being dominated by magma-cryosphere interactions. Given the smaller gravitational field, declining atmospheric pressure, and widespread, permeable megaregolith on Mars, volatile outgassing and magmatic cooling would have been more effective than on Earth. Thus, hydrothermal systems are likely to have had much lower average surface temperatures than comparable geological settings on Earth. The likely predominance of basaltic crust on Mars suggests that hydrothermal fluids and associated deposits should be enriched in Fe, Mg, Si and Ca, with surficial deposits being dominated by lower temperature, mixed iron oxide and carbonate mineralogies.
Hydrothermal systems on Mars: an assessment of present evidence.
Farmer, J D
1996-01-01
Hydrothermal processes have been suggested to explain a number of observations for Mars, including D/H ratios of water extracted from Martian meteorites, as a means for removing CO2 from the Martian atmosphere and sequestering it in the crust as carbonates, and as a possible origin for iron oxide-rich spectral units on the floors of some rifted basins (chasmata). There are numerous examples of Martian channels formed by discharges of subsurface water near potential magmatic heat sources, and hydrothermal processes have also been proposed as a mechanism for aquifer recharge needed to sustain long term erosion of sapping channels. The following geological settings have been identified as targets for ancient hydrothermal systems on Mars: channels located along the margins of impact crater melt sheets and on the slopes of ancient volcanoes; chaotic and fretted terranes where shallow subsurface heat sources are thought to have interacted with ground ice; and the floors of calderas and rifted basins (e.g. chasmata). On Earth, such geological environments are often a locus for hydrothermal mineralization. But we presently lack the mineralogical information needed for a definitive evaluation of hypotheses. A preferred tool for identifying minerals by remote sensing methods on Earth is high spatial resolution, hyperspectral, near-infrared spectroscopy, a technique that has been extensively developed by mineral explorationists. Future efforts to explore Mars for ancient hydrothermal systems would benefit from the application of methods developed by the mining industry to look for similar deposits on Earth. But Earth-based exploration models must be adapted to account for the large differences in the climatic and geological history of Mars. For example, it is likely that the early surface environment of Mars was cool, perhaps consistently below freezing, with the shallow portions of hydrothermal systems being dominated by magma-cryosphere interactions. Given the smaller gravitational field, declining atmospheric pressure, and widespread, permeable megaregolith on Mars, volatile outgassing and magmatic cooling would have been more effective than on Earth. Thus, hydrothermal systems are likely to have had much lower average surface temperatures than comparable geological settings on Earth. The likely predominance of basaltic crust on Mars suggests that hydrothermal fluids and associated deposits should be enriched in Fe, Mg, Si and Ca, with surficial deposits being dominated by lower temperature, mixed iron oxide and carbonate mineralogies.
NASA Astrophysics Data System (ADS)
Canales, J. P.; Dunn, R. A.; Sohn, R. A.; Horning, G.; Arai, R.; Paulatto, M.
2015-12-01
Most of our understanding of hydrothermal systems and the nature of their heat sources comes from models and observations at fast and intermediate spreading ridges. In these settings, hydrothermal systems are mainly located within the axial zone of a spreading segment, hosted in basaltic rock, and primarily driven by heat extracted from crystallization of crustal melt sills. In contrast, hydrothermal systems at slow-spreading ridges like the Mid-Atlantic Ridge (MAR) show a great variety of venting styles and host-rock lithology, and are located in diverse tectonic settings like axial volcanic ridges, non-transform discontinuities (NTDs), the foot of ridge valley walls, and off-axis inside corner highs. Among MAR systems, the Rainbow hydrothermal field (RHF) stands out as an end-member of this diversity: an ultramafic-hosted system emitting H2 and CH4-rich fluids at high temperatures and high flow rates, which suggests a magmatic heat source despite the lack of evidence for recent volcanism and its location within an NTD with presumably low magma budget. We present 2D multichannel seismic reflection images across the Rainbow massif from the NSF-funded MARINER multidisciplinary geophysical study that reveal, for the first time, the magmatic system driving hydrothermal circulation in an ultramafic setting. Data were acquired in 2013 onboard the RV M. Langseth with an 8-km-long hydrophone streamer. The images have been obtained from pre-stack depth migrations using a regional 3D P-wave velocity model from a coincident controlled-source seismic tomography experiment using ocean bottom seismometers. Our images show a complex magmatic system centered beneath the RHF occupying an areal extent of ~3.7x6 km2, with partially molten sills ranging in depth between ~3.4 km and ~6.9 km below the seafloor. Our data also image high-amplitude dipping reflections within the massif coincident with strong lateral velocity gradients that may arise from detachment fault planes, lithological contacts, and/or alteration boundaries. Our results are an important step towards understanding the interactions of detachment faulting, magmatic intrusion, and hydrothermal circulation.
NASA Astrophysics Data System (ADS)
Ruiz Chancho, M.; Pichler, T.; Amend, J. P.; Akerman, N. H.
2011-12-01
Arsenic, although toxic, is used as an energy source by certain microbes, some of which can catalyse the reduction of arsenate by using different electron donors, while others oxidize arsenite with oxygen or nitrate as electron acceptors. The marine shallow-water hydrothermal system in Tutum Bay, Ambitle Island, Papua New Guinea is ideal for investigating the metabolism of microbes involved in arsenic cycling, because there hydrothermal vents discharge fluids with arsenite concentrations as high as 950 μg/L. Vent fluids are hot (˜100°C), slightly acidic (pH˜6) and reducing. Upon mixing with colder and oxygen-rich seawater the fluid chemistry changes rapidly within a few meters from the hydrothermal source. The objective of this work was to study arsenic metabolism due to microbial activity in Tutum Bay. Sediments collected at 7.5 and 30 m along a transect beginning at a hydrothermal vent were used as inocula in the microbial culturing experiments. Media were designed using chemical analyses of the hydrothermal fluids. Following culture experiments, arsenic species identification and quantification were performed for the growth media with HPLC-ICP(HR)MS, using anion exchange and reversed phase chromatography. Quality control included mass balance calculations and spiking experiments. A fast reduction of arsenate to arsenite was observed in the first 24 hours leading to the conclusion that the microbial communities were capable of reducing arsenic. However, mass balance calculations revealed that more than 30% of the arsenic had been transformed to one or more unknown species, which could not be detected by ion exchange chromatography. The addition of peroxide combined with reversed phase chromatography revealed the presence of several unknown species. Following the addition of peroxide some of the unknown species were identified to be thio-arsenic compounds, because they were oxidized to their oxo-analogues. Nevertheless, a significant fraction of unknown arsenic species could not be identified and remain to be studied further with the help of molecular mass spectrometric techniques. At this time it can be concluded that the metabolic processes involving arsenic in Tutum Bay's microbial communities are complex but that arsenic definitely plays an important role.
Vertical Cable Seismic Survey for Hydrothermal Deposit
NASA Astrophysics Data System (ADS)
Asakawa, E.; Murakami, F.; Sekino, Y.; Okamoto, T.; Ishikawa, K.; Tsukahara, H.; Shimura, T.
2012-04-01
The vertical cable seismic is one of the reflection seismic methods. It uses hydrophone arrays vertically moored from the seafloor to record acoustic waves generated by surface, deep-towed or ocean bottom sources. Analyzing the reflections from the sub-seabed, we could look into the subsurface structure. This type of survey is generally called VCS (Vertical Cable Seismic). Because VCS is an efficient high-resolution 3D seismic survey method for a spatially-bounded area, we proposed the method for the hydrothermal deposit survey tool development program that the Ministry of Education, Culture, Sports, Science and Technology (MEXT) started in 2009. We are now developing a VCS system, including not only data acquisition hardware but data processing and analysis technique. Our first experiment of VCS surveys has been carried out in Lake Biwa, JAPAN in November 2009 for a feasibility study. Prestack depth migration is applied to the 3D VCS data to obtain a high quality 3D depth volume. Based on the results from the feasibility study, we have developed two autonomous recording VCS systems. After we carried out a trial experiment in the actual ocean at a water depth of about 400m and we carried out the second VCS survey at Iheya Knoll with a deep-towed source. In this survey, we could establish the procedures for the deployment/recovery of the system and could examine the locations and the fluctuations of the vertical cables at a water depth of around 1000m. The acquired VCS data clearly shows the reflections from the sub-seafloor. Through the experiment, we could confirm that our VCS system works well even in the severe circumstances around the locations of seafloor hydrothermal deposits. We have, however, also confirmed that the uncertainty in the locations of the source and of the hydrophones could lower the quality of subsurface image. It is, therefore, strongly necessary to develop a total survey system that assures a accurate positioning and a deployment techniques. We have carried out two field surveys in FY2011. One is a 3D survey with a boomer for a high-resolution surface source and the other one for an actual field survey in the Izena Cauldron an active hydrothermal area in the Okinawa Trough. Through these surveys, the VCS will become a practical exploration tool for the exploration of seafloor hydrothermal deposits.
Drieberg, Susan L.; Hagemann, Steffen G.; Huston, David L.; Landis, Gary; Ryan, Chris G.; Van Achterbergh, Esmé; Vennemann, Torsten
2013-01-01
The ~3240 Ma Panorama volcanic-hosted massive sulfide (VHMS) district is unusual for its high degree of exposure and low degree of postdepositional modification. In addition to typical seafloor VHMS deposits, this district contains greisen- and vein-hosted Mo-Cu-Zn-Sn mineral occurrences that are contemporaneous with VHMS orebodies and are hosted by the Strelley granite complex, which also drove VHMS circulation. Hence the Panorama district is a natural laboratory to investigate the role of magmatic-hydrothermal fluids in VHMS hydrothermal systems. Regional and proximal high-temperature alteration zones in volcanic rocks underlying the VHMS deposits are dominated by chlorite-quartz ± albite assemblages, with lesser low-temperature sericite-quartz ± K-feldspar assemblages. These assemblages are typical of VHMS hydrothermal systems. In contrast, the alteration assemblages associated with granite-hosted greisens and veins include quartz-topaz-muscovite-fluorite and quartz-muscovite (sericite)-chlorite-ankerite. These vein systems generally do not extend into the overlying volcanic pile. Fluid inclusion and stable isotope studies suggest that the greisens were produced by high-temperature (~590°C), high-salinity (38–56 wt % NaCl equiv) fluids with high densities (>1.3 g/cm3) and high δ18O (9.3 ± 0.6‰). These fluids are compatible with the measured characteristics of magmatic fluids evolved from the Strelley granite complex. In contrast, fluids in the volcanic pile (including the VHMS ore-forming fluids) were of lower temperature (90°–270°C), lower salinity (5.0–11.2 wt % NaCl equiv), with lower densities (0.88–1.01 g/cm3) and lower δ18O (−0.8 ± 2.6‰). These fluids are compatible with evolved Paleoarchean seawater. Fluids that formed the quartz-chalcopyrite-sphalerite-cassiterite veins, which are present within the granite complex near the contact with the volcanic pile, were intermediate in temperature and isotopic composition between the greisen and volcanic pile fluids (T = 240°–315°C; δ18O = 4.3 ± 1.5‰) and are interpreted to indicate mixing between the two end-member fluids. Evidence of mixing between evolved seawater and magmatic-hydrothermal fluid within the granite complex, together with the lack of evidence for a magmatic component in fluids from the volcanic pile, suggest partitioning of magmatic-hydrothermal from evolved seawater hydrothermal systems in the Panorama VHMS system. This separation is interpreted to result from either the swamping of a relatively small magmatic-hydro-thermal system by evolved seawater or density contrasts precluding movement of magmatic-hydrothermal fluids into the volcanic pile. Variability in the salinity of fluids in the volcanic pile, combined with evidence for mixing of low- and high-salinity fluids in the massive sulfide lens, is interpreted to indicate that phase separation occurred within the Panorama hydrothermal system. Although we consider this phase separation to have most likely occurred at depth within the system, as has been documented in modern VHMS systems, the data do not allow the location of the inferred phase separation to be determined.
Impact of hydrothermalism on the ocean iron cycle
Resing, Joseph
2016-01-01
As the iron supplied from hydrothermalism is ultimately ventilated in the iron-limited Southern Ocean, it plays an important role in the ocean biological carbon pump. We deploy a set of focused sensitivity experiments with a state of the art global model of the ocean to examine the processes that regulate the lifetime of hydrothermal iron and the role of different ridge systems in governing the hydrothermal impact on the Southern Ocean biological carbon pump. Using GEOTRACES section data, we find that stabilization of hydrothermal iron is important in some, but not all regions. The impact on the Southern Ocean biological carbon pump is dominated by poorly explored southern ridge systems, highlighting the need for future exploration in this region. We find inter-basin differences in the isopycnal layer onto which hydrothermal Fe is supplied between the Atlantic and Pacific basins, which when combined with the inter-basin contrasts in oxidation kinetics suggests a muted influence of Atlantic ridges on the Southern Ocean biological carbon pump. Ultimately, we present a range of processes, operating at distinct scales, that must be better constrained to improve our understanding of how hydrothermalism affects the ocean cycling of iron and carbon. This article is part of the themed issue ‘Biological and climatic impacts of ocean trace element chemistry’. PMID:29035256
Impact of hydrothermalism on the ocean iron cycle.
Tagliabue, Alessandro; Resing, Joseph
2016-11-28
As the iron supplied from hydrothermalism is ultimately ventilated in the iron-limited Southern Ocean, it plays an important role in the ocean biological carbon pump. We deploy a set of focused sensitivity experiments with a state of the art global model of the ocean to examine the processes that regulate the lifetime of hydrothermal iron and the role of different ridge systems in governing the hydrothermal impact on the Southern Ocean biological carbon pump. Using GEOTRACES section data, we find that stabilization of hydrothermal iron is important in some, but not all regions. The impact on the Southern Ocean biological carbon pump is dominated by poorly explored southern ridge systems, highlighting the need for future exploration in this region. We find inter-basin differences in the isopycnal layer onto which hydrothermal Fe is supplied between the Atlantic and Pacific basins, which when combined with the inter-basin contrasts in oxidation kinetics suggests a muted influence of Atlantic ridges on the Southern Ocean biological carbon pump. Ultimately, we present a range of processes, operating at distinct scales, that must be better constrained to improve our understanding of how hydrothermalism affects the ocean cycling of iron and carbon.This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'. © 2016 The Author(s).
McCollom, Thomas M
2007-12-01
Numerical models are employed to investigate sources of chemical energy for autotrophic microbial metabolism that develop during mixing of oxidized seawater with strongly reduced fluids discharged from ultramafic-hosted hydrothermal systems on the seafloor. Hydrothermal fluids in these systems are highly enriched in H(2) and CH(4) as a result of alteration of ultramafic rocks (serpentinization) in the subsurface. Based on the availability of chemical energy sources, inferences are made about the likely metabolic diversity, relative abundance, and spatial distribution of microorganisms within ultramafic-hosted systems. Metabolic reactions involving H(2) and CH(4), particularly hydrogen oxidation, methanotrophy, sulfate reduction, and methanogenesis, represent the predominant sources of chemical energy during fluid mixing. Owing to chemical gradients that develop from fluid mixing, aerobic metabolisms are likely to predominate in low-temperature environments (<20-30 degrees C), while anaerobes will dominate higher-temperature environments. Overall, aerobic metabolic reactions can supply up to approximately 7 kJ of energy per kilogram of hydrothermal fluid, while anaerobic metabolic reactions can supply about 1 kJ, which is sufficient to support a maximum of approximately 120 mg (dry weight) of primary biomass production by aerobic organisms and approximately 20-30 mg biomass by anaerobes. The results indicate that ultramafic-hosted systems are capable of supplying about twice as much chemical energy as analogous deep-sea hydrothermal systems hosted in basaltic rocks.
NASA Technical Reports Server (NTRS)
Treiman, Allan H.; Amundsen, Hans E. F.; Blake, David F.; Bunch, Ted
2002-01-01
Carbonate minerals in the ancient Martian meteorite ALH84001 are the only known solid phases that bear witness to the processing of volatile and biologically critical compounds (CO2, H2O) on early Mars. Similar carbonates have been found in xenoliths and their host basalts from Quaternary volcanic centers in northern Spitsbergen (Norway). These carbonates were deposited by hot (i.e., hydrothermal) waters associated with the volcanic activity. By analogy with the Spitsbergen carbonates, the ALH84001 carbonates were probably also deposited by hot water. Hydrothermal activity was probably common and widespread on Early Mars, which featured abundant basaltic rocks, water as ice or liquid, and heat from volcanos and asteroid impacts. On Earth, descendants of the earliest life forms still prefer hydrothermal environments, which are now shown to have been present on early Mars.
An Assessment of Magma-Hydrothermal Heat Output at the Costa Rica Rift
NASA Astrophysics Data System (ADS)
Lowell, R. P.; Morales Maqueda, M. A.; Banyte, D.; Zhang, L.; Tong, V.; Hobbs, R. W.; Harris, R. N.
2016-12-01
A joint geophysical/physical oceanographic investigation of the Costa Rica Ridge as part of the OSCAR (Oceanographic and Seismic Characterization of heat dissipation and alteration by hydrothermal fluids at an Axial Ridge) research program enables us to estimate hydrothermal heat output and its likely link to a sub-axial magma lens (AML). In December 2014, a number of tow-yo casts were made along and near the ridge axis where seismic reflection data collected in 1994 showed the presence of seismic reflector interpreted to be an AML at a depth of about 2800 m below the seafloor. A decline in beam transmission in a ≈ 200 m thick region located approximately 800 to 900 meters above the seafloor indicated the presence of a hydrothermal plume. CTD data collected above the ridge yielded a weighted average buoyancy frequency of approximately 19.3 x 10-8 s-2. Assuming a mean hydrothermal vent temperature of 350°C, buoyant plume theory yields a heat output between 400 and 600 MW. Application of the single-pass modeling approach to the hydrothermal system, yields an estimated mass flow between 210 and 337 kg/s, and the mean product of crustal permeability x discharge area ranges between 6 and 10 x 10-9 m4. A multichannel seismic profile collected in 2015 indicates the presence of a reflector 5 km along-axis and < 100 m wide, in approximately the same location as the 1994 survey, suggesting that magma-driven hydrothermal heat output may have exhibited stability on a decadal time scale. The relatively small size of the inferred AML, when coupled to the heat output estimate and the single-pass model, suggests that the conductive boundary layer at the top the AML is 2m thick and that the AML must be frequently replenished to maintain stable heat output. Assuming the hydrothermal system is driven by magmatic latent heat, a 100 m thick AML could have powered a 100 MW hydrothermal system for 20 years, while inputting 5 x 107 m3 of melt into the axis. These results indicate hydrothermal heat output at the Costa Rica Ridge is time-varying.
Drill-back studies examine fractured, heated rock
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wollenberg, H.A.; Flexser, S.; Myer, L.R.
1990-01-01
To investigate the effects of heating on the mineralogical, geochemical, and mechanical properties of rock by high-level radioactive waste, cores are being examined from holes penetrating locations where electric heaters simulated the presence of a waste canister, and from holes penetration natural hydrothermal systems. Results to date indicate the localized mobility and deposition of uranium in an open fracture in heated granitic rock, the mobility of U in a breccia zone in an active hydrothermal system in tuff, and the presence of U in relatively high concentration in fracture-lining material in tuff. Mechanical -- property studies indicate that differences inmore » compressional- and shear-wave parameters between heated and less heated rock can be attributed to differences in the density of microcracks. Emphasis has shifted from initial studies of granitic rock at Stripa, Sweden to current investigations of welded tuff at the Nevada Test Site. 7 refs., 8 figs.« less
The chemical and hydrologic structure of Poas volcano, Costa Rica
Rowe, G.L.; Brantley, S.L.; Fernandez, J.F.; Borgia, A.
1995-01-01
Comparison of the chemical characteristics of spring and river water draining the flanks of Poas Volcano, Costa Rica indicates that acid chloride sulfate springs of the northwestern flank of the volcano are derived by leakage and mixing of acid brines formed in the summit hydrothermal system with dilute flank groundwater. Acid chloride sulfate waters of the Rio Agrio drainage basin on the northwestern flank are the only waters on Poas that are affected by leakage of acid brines from the summit hydrothermal system. Acid sulfate waters found on the northwestern flank are produced by the interaction of surface and shallow groundwater with dry and wet acid deposition of SO2 and H2SO4 aerosols, respectively. The acid deposition is caused by a plume of acid gases that is released by a shallow magma body located beneath the active crater of Poas. -from Authors
Secondary mineral growth in fractures in the Miravalles geothermal system, Costa Rica
DOE Office of Scientific and Technical Information (OSTI.GOV)
Rochelle, C.A.; Milodowski, A.E.; Savage, D.
1989-01-01
A mineralogical, fluid-chemical, and theoretical study of hydrothermal alteration in veins from drillcore from the Miravalles geothermal field, Costa Rica has revealed a complex history of mineral-fluid reaction which may be used to characterize changes in temperature and fluid composition with time. Mineralogical and mineral-chemical data are consistent with hydrothermal alteration in the temperature range 200{sup 0}-270{sup 0}C, with deeper portions of the system having undergone temperatures in excess of 300{sup 0}C. Thermodynamic calculations suggest that the observed alteration assemblage is not equilibrium with current well fluids, unless estimates of reservoir pH are incorrect. Fe-Al zoning of prehnite and epidotemore » in veins is consistent with rapid, isothermal fluctuations in fluid composition at current reservoir temperatures, and may be due to changes in volatile content of the fluid due to tectonic activity.« less
NASA Astrophysics Data System (ADS)
Liu, Y.; Tao, C.; Cai, L.; Qiu, L.
2016-12-01
We developed a long-period seismic monitoring experiment near the active Longqi hydrothermal vent from January to April during the Chinese cruise DY115-34 in 2014. During the 102-day experiment, more than 2,000 seismic signals recorded by a single Ocean bottom Seismometer with Hydrophone (OBS/H) are associated with tectonic activity and magma migration in the hydrothermal field. We classified these signals into four typical classes based on their time-frequency characteristics: 1. more than1800 volcano-tectonic microearthquakes (VTMs) with clear onset of P and S phases, Ts-Tp delay time less than 2 s and small local magnitude; 2. 3 regional earthquakes used to determinate sensor orientation; 3. about a hundred short duration events (SDEs) whose have several narrow peaks in frequency range and high amplitude with an exponential decaying coda in seismograms; 4. several special acoustic signals that have the similar feature in waveform recorded by seismometers and hydrophone, with uncertain of generated by biological or geological activity. Analysis of signals based on its feature: First, located the 1549 VTMs with high signal to noise ratio (SNR) by the single station location (SSL) method based on polarization analysis, the results shows that hypocenters mainly beneath the axial valley ridge (AVR) and extended to upper mantle with depth of 15 km, it indicates magma is still active now beneath the AVR in the Longqi field. Second, activities of earthquakes have a certain rule, during the first 6 days, there is an active period with 21.6 events per day, After a long quiet period of 78 days (3.4 events per day), a larger scale and a longer duration of the earthquakes activity is coming with 79.7 events per day. This reflects the law of intermittent magmatic and hydrothermal activity in the Longqi field. Moreover, complex frequencies characteristics of SDEs ascribed to clusters of some monochromatic waves around different frequencies suggest that SDEs are the combination of harmonic wave resonated in full-filled pipes and cracks associated with fluid driven. Above all, we make a conclusion that the Longqi hydrothermal field is in the stage of magmatism in the magmato-tectonic cycle, with intense magmatic and hydrothermal activity intermittently follow certain rules.
Geochemistry of pyrite and chalcopyrite from an active black smoker in 49.6°E Southwest Indian Ridge
NASA Astrophysics Data System (ADS)
Yuan, Bo; Yang, Yaomin; Yu, Hongjun; Zhao, Yuexia; Ding, Qingfeng; Yang, Jichao; Tang, Xin
2017-06-01
Active hydrothermal chimneys, as the product of submarine hydrothermal activity, can be used to determine the fluid evolution and formation process of potential volcanic-hosted massive sulfide deposits. A hard-won specimen from an active hydrothermal chimney was collected in the 49.6°E ultraslow-spreading Southwest Indian Ridge (SWIR) field through a television-guided grab. A geochemical study of prominent sulfide (e.g., pyrite and chalcopyrite) included in this sample was performed using laser ablation inductively coupled plasma mass spectroscopy. The early sulfides produced at low temperature are of disseminated fine-grained anhedral morphology, whereas the late ones with massive, coarse euhedral features precipitated in a high-temperature setting. The systematic variations in the contents of minor and trace elements are apparently related to the crystallization sequence, as well as to texture. Micro-disseminated anhedral sulfides rich in Pb, As, Ni, Ba, Mn, Mo, U, and V were formed during the initial chimney wall growth, whereas those rich in Sn, Se, and Co with massive, coarse euhedral morphology were formed within the late metallogenic stage. The hydrothermal fluid composition has experienced a great change during the chimney growth. Such a conclusion is consistent with that indicated by using principal component analysis, which is a powerful statistical analysis method widely used to project multidimensional datasets (e.g., element contents in different mineral phases) into a few directions. This distribution pattern points to crystallographic controls on minor and trace element uptake during chimney growth, occurring with concomitant variations in the fluid composition evolutionary history. In this pyrite-chalcopyrite-bearing active hydrothermal chimney at the SWIR, the metal concentration and precipitation of sulfides largely occurred at the seafloor as a result of mixing between the upwelling hot hydrothermal fluid and cold seawater. Over the course of mixing, significant variations in metal solubility were caused by changes in temperature, pH, and redox conditions in the parental fluid phase.
A seismic network to investigate the sedimentary hosted hydrothermal Lusi system
NASA Astrophysics Data System (ADS)
Javad Fallahi, Mohammad; Mazzini, Adriano; Lupi, Matteo; Obermann, Anne; Karyono, Karyono
2016-04-01
The 29th of May 2006 marked the beginning of the sedimentary hosted hydrothermal Lusi system. During the last 10 years we witnessed numerous alterations of the Lusi system behavior that coincide with the frequent seismic and volcanic activity occurring in the region. In order to monitor the effect that the seismicity and the activity of the volcanic arc have on Lusi, we deployed a ad hoc seismic network. This temporary network consist of 10 broadband and 21 short period stations and is currently operating around the Arjuno-Welirang volcanic complex, along the Watukosek fault system and around Lusi, in the East Java basin since January 2015. We exploit this dataset to investigate surface wave and shear wave velocity structure of the upper-crust beneath the Arjuno-Welirang-Lusi complex in the framework of the Lusi Lab project (ERC grant n° 308126). Rayleigh and Love waves travelling between each station-pair are extracted by cross-correlating long time series of ambient noise data recorded at the stations. Group and phase velocity dispersion curves are obtained by time-frequency analysis of cross-correlation functions, and are tomographically inverted to provide 2D velocity maps corresponding to different sampling depths. 3D shear wave velocity structure is then acquired by inverting the group velocity maps.
NASA Technical Reports Server (NTRS)
Behar, Alberto; Matthews, Jaret; Venkateswaran, Kasthuri; Bruckner, James; Basic, Goran; So, Edmond; Rivadeneyra, Cesar
2005-01-01
This paper provides a physical description of the current system, as well as a summary of the preliminary tests conducted in 2005: a pressure chamber test, a dive test in a 30 foot dive pool, and a dive operation at a hydrothermal vent off the northern coast of Iceland.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Yusa, Y.; Ohsawa, S.; Kitaoka, K.
The central part of Kyushu Island, southwest Japan, is located at the junction of the Southwest Japan Arc and the Ryukyu Arc, where a graben (Beppu-Shimabara Graben) has been formed by the rifting tectonic movement. There are many Quaternary volcanoes and active geo- and hydro-thermal fields within the Graben. The Beppu hydrothermal system extends around the Tsurumi-Garandake volcanoes at the eastern end of the Graben. This report will deal with the hydrothermal system beneath the volcanoes specially focusing on Garandake. Modest or violent fumarolic activities are visible near the summit of Garandake (1045 m in height). The total water(steam) outputmore » is 1.4 kg/s and its heat output 3.8 MW, while the heat output from the ground surface of 5.5 x 10{sup 4} m{sup 2} is 19.5 MW estimated by a heat balance analysis based on infrared radiation measurements (Yuhara et al., 1987). Thus the main process of heat discharge from Garandake, totally 23.3 MW, is the radiation from the ground surface. The geothermal gradient observed in a well drilled near the summit indicates that the large heat output is caused by some special process different from conduction because the heat flow by conduction is estimated to be 0.03 MW, which is very small compared with the observed output. Allis and Yusa (1989) suggested that a two-phase flow system is developed in Garandake. The two-phase flow, steam rising and water failing, acts as a heat pipe, by which a large quantity of (latent) heat can be transported upwards. Applying the theory of two-phase flow (Yusa and Oishi, 1989) to the Garandake system, the upflow rate of steam is estimated to be 10.3 kg/s at 100{degrees}C; the temperature near the ground surface, A part of rising steam (1.4 kg/s) flows out through fumaroles, and the remnant condenses to flow downwards. If the system is vapor-dominated, the intrinsic permeability at the shallow part should be about 1 darcy.« less
Phosphatase activities as biosignatures of extant life
NASA Astrophysics Data System (ADS)
Kobayashi, K.; Itoh, Y.; Edazawa, Y.; Moroi, A.; Takano, Y.
It has been recognized that terrestrial biosphere expands to such extreme environments as deep subsurface lithosphere high temperature hot springs and stratosphere Possible extraterrestrial biospheres in Mars Europa and Titan are being discussed Many biosignatures or biomarkers have been proposed to detect microbial activities in such extreme environments Phosphate esters are essential for the terrestrial life since they are constituents of nucleic acids and cell mebranes Thus all the terrestrial organisms have phosphatases that are enzymes catalyzing hydrolysis of phosphate esters We analyzed phosphatase activities in the samples obtained in extreme environments such as submarine hydrothermal systems and discussed whether they can be used as biosignatures for extant life Core samples and chimney samples were collected at the Suiyo Seamount Izu-Bonin Arc the Pacific Ocean in 2001 and 2002 and in South Mariana hydrothermal systems the Pacific Oceanas in 2003 both in a part of the Archaean Park Project Phosphatase activity in solid rock samples was measured spectrometrically by using 25 mM p-nitrophenyl phosphate pH 8 0 or pH 6 5 as a substrate as follows Pulverized samples were incuvated with substrate solution for an hour and then production rate of p-nitrophenol was calculated with absorbance at 410 nm Phosphatase activity in extracts was measured fluorometrically by using 4-methylumberyferryl phosphate as a substrate Concentration of amino acids and their enantiomeric ratio were determined by HPLC after HF digestion of the
Electron microscopy study of microbial mat in the North Fiji basin hydrothermal vent
NASA Astrophysics Data System (ADS)
Park, H.; Kim, J. W.; Lee, J. W.
2017-12-01
Hydrothermal vent systems consisting of hydrothermal vent, hydrothermal sediment and microbial mat are widely spread around the ocean, particularly spreading axis, continental margin and back-arc basin. Scientists have perceived that the hydrothermal systems, which reflect the primeval earth environment, are one of the best places to reveal the origin of life and extensive biogeochemical process of microbe-mineral interaction. In the present study multiline of analytical methods (X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM)) were utilized to investigate the mineralogy/chemistry of microbe-mineral interaction in hydrothermal microbial mat. Microbial mat samples were recovered by Canadian scientific submersible ROPOS on South Pacific North Fiji basin KIOST hydrothermal vent expedition 1602. XRD analysis showed that red-colored microbial mat contains Fe-oxides and Fe-oxyhydroxides. Various morphologies of minerals in the red-colored microbial mat observed by SEM are mainly showed sheath shaped, resembled with Leptothrix microbial structure, stalks shaped, similar with Marioprofundus microbial structure and globule shaped microbial structures. They are also detected with DNA analysis. The cross sectional observation of microbial structures encrusted with Fe-oxide and Fe-oxyhydroxide at a nano scale by Transmission Electron Microscopy (TEM) and Focused Ion Beam (FIB) technique was developed to verify the structural/biogeochemical properties in the microbe-mineral interaction. Systematic nano-scale measurements on the biomineralization in the microbial mat leads the understandings of biogeochemical environments around the hydrothermal vent.
Hemley, J.J.; Hunt, J.P.
1992-01-01
The experimental metal solubilities for rock-buffered hydrothermal systems provide important insights into the acquisition, transport, and deposition of metals in real hydrothermal systems that produced base metal ore deposits. Water-rock reactions that determine pH, together with total chloride and changes in temperature and fluid pressure, play significant roles in controlling the solubility of metals and determining where metals are fixed to form ore deposits. Deposition of metals in hydrothermal systems occurs where changes such as cooling, pH increase due to rock alteration, boiling, or fluid mixing cause the aqueous metal concentration to exceed saturation. Metal zoning results from deposition occurring at successive saturation surfaces. Zoning is not a reflection simply of relative solubility but of the manner of intersection of transport concentration paths with those surfaces. Saturation surfaces will tend to migrate outward and inward in prograde and retrograde time, respectively, controlled by either temperature or chemical variables. -from Authors
Criss, R.E.; Ekren, E.B.; Hardyman, R.F.
1984-01-01
The largest fossil hydrothermal system occupying a 4500 km2 area in central Idaho is revealed by delta 18O studies. The remains of this meteoric-hydrothermal system are preserved within a sharply bounded, 15 km wide, 70-km-diameter annulus of low delta 18O rock (+2.0 to -8.8per mille) termed the Castro ring zone. The zone is centred on a less depleted (+4.5) core zone consisting of granitic rocks of the Castro pluton. This 700-km2 Eocene subvolcanic batholith has intruded, domed, and hydrothermally metamorphosed a thick sequence of Challis Volcanics, the stratigraphically low rocks in the 2000-km2 Van Horn Peak and the 1000-km2 Thunder Mountain cauldron complexes being most strongly altered. Less extreme 18O depletions occur in the youngest major ash-flow sheets of these complexes, indicating a vertical 18O gradient. Water/rock ratios of geothermal systems are surprisingly insensitive to the circulation scale.-L.-di H.
NASA Astrophysics Data System (ADS)
Boulart, C.; Chavagnac, V.; Briais, A.; Revillon, S.; Donval, J. P.; Guyader, V.
2015-12-01
We report on the first evidence for hydrothermal activity along the intermediate-spreading South-East Indian Ridge (SEIR) between Australia and Antarctica (128°E-140°E), discovered during the STORM cruise of R/V L'Atalante. This section of the SEIR is located east of the low-magma Australian-Antarctic Discordance (AAD), where the ridge has the morphology of a slow-spreading mid-ocean ridge despite its intermediate spreading rate of 75 mm/yr. The axial depth decreases eastward, reflecting an eastward increase in magma budget.Using in-situ geochemical tracers based on optical backscatter, temperature, redox potential sensor and in situ mass spectrometer (ISMS) anomalies, we establish the existence of several distinct hydrothermal plumes within the water column along the 500 nautical miles ridge section. At one site, the combination of near-bottom temperature anomalies of 0.1°C together with strong dissolved methane and dissolved carbon dioxide anomalies revealed by the ISMS provides the precise location of an active vent in the Deep Southern Indian Ocean off Tasmania. Hydrothermal venting along the 128°E-140°E section of the SEIR appears to be significant, an observation consistent with the global link between spreading rate and plume occurrence (Baker and German, 2004). Moreover, the plume incidence increases westward and, in the eastern part, hydrothermal venting seems to be less significant, suggesting a possible influence of the high magma budget, as observed in mid-ocean ridge sections affected by hotspots. Future investigation will focus on the direct identification of venting sources and the study of hydrothermal circulation within the specific settings of the AAD. The observation of new venting sites at the frontier between Pacific and Indian Oceans may also provide new insights on the biogeography (diversity and distribution) of hydrothermal fauna. Baker, E. T., and C. R. German (2004), On the global distribution of hydrothermal vent fields, in Mid-Ocean Ridges: Hydrothermal Interactions
NASA Astrophysics Data System (ADS)
Hasenclever, Jörg; Rüpke, Lars; Theissen-Krah, Sonja; Morgan, Jason
2016-04-01
We use 3-D numerical models of hydrothermal fluid flow to assess the magnitude and spatial distribution of hydrothermal mass and energy fluxes within the upper and lower oceanic crust. A better understanding of the hydrothermal flow pattern (e.g. predominantly on-axis above the axial melt lens vs. predominantly off-axis and ridge-perpendicular over the entire crustal thickness) is essential for quantifying the volume of oceanic crust exposed to high-temperature fluid flow and the associated leaching and redistribution of economically interesting metals. The initial setup of all 3-D models is based on our previous 2-D studies (Theissen-Krah et al., 2011), in which we have coupled numerical models for crustal accretion and hydrothermal fluid flow. One result of these 2-D calculations is a crustal permeability field that leads to a thermal structure in the crust that matches seismic tomography data at the East Pacific Rise. Our reference 3-D model for hydrothermal flow at fast-spreading ridges predicts the existence of a hybrid hydrothermal system (Hasenclever et al., 2014) with two interacting flow components that are controlled by different physical mechanisms. Shallow on-axis flow structures develop owing to the thermodynamic properties of water, whereas deeper off-axis flow is strongly shaped by crustal permeability, particularly the brittle-ductile transition. About ˜60% of the discharging fluid mass is replenished on-axis by warm (up to 300oC) recharge flow surrounding the hot thermal plumes. The remaining ˜40%, however, occurs as colder and broader recharge up to several kilometres away from the ridge axis that feeds hot (500-700oC) deep off-axis flow in the lower crust towards the ridge. Both flow components merge above the melt lens to feed ridge-centred vent sites. In a suite of 3-D model calculations we vary the isotropic crustal permeability to quantify its influence on on-axis vs. off-axis hydrothermal fluxes as well as on along-axis hydrothermal activity. We also explore the effect of anisotropic permeability that is likely to be a feature of the diking region above the melt lens where the repeated emplacement of meter-size dikes should lead to higher permeability in vertical and along-ridge direction and to lower permeability across the ridge. We further study the effect of along-ridge depth-variations of the axial melt lens on the distribution of hydrothermal vent sites.
Age and origin of base and precious metal veins of the Coeur d'Alene mining district, Idaho
Fleck, R.J.; Criss, R.E.; Eaton, G.F.; Cleland, R.W.; Wavra, C.S.; Bond, W.D.
2002-01-01
Ore-bearing quartz-carbonate veins of the Coeur d'Alene mining district yield 87Sr/86Sr ratios of 0.74 to >1.60 for low Rb/Sr, carbonate gangue minerals, similar to current ranges measured in Middle Proterozoic, high Rb/Sr rocks of the Belt Supergroup. Stable isotope and fluid inclusion studies establish a genetic relationship between vein formation and metamorphic-hydrothermal systems of the region. These extraordinary 87Sr/86Sr ratios require accumulation of radiogenic 87Sr in a high Rb/Sr system over an extended period prior to incorporation of Sr into the hydrothermal veins. Evaluation of the age and composition of potential sources of highly radiogenic Sr indicates that the ore-bearing veins of the Coeur d'Alene district formed during the Cretaceous from components scavenged from rocks of the Belt Supergroup, the primary host rocks of the district. Proterozoic Pb isotope ratios observed in galena from many Coeur d'Alene veins were established when Pb separated from uranium during deposition or diagenesis of the Belt Supergroup at 1400 to 1500 Ma, possibly as disseminated syngenetic deposits. K-Ar and Rb-Sr apparent ages and ??18O values of Belt Supergroup rocks decrease from the Coeur d'Alene district toward the Idaho and Kaniksu batholiths, approximately normal to the trends of metamorphic isograds, fold axes, foliation, and the major reverse faults of the district. Isoclinal folding, thrust faulting, high-temperature metamorphism, granitic plutonism, and regional-scale metamorphic-hydrothermal activity is documented in the region between 140 and 45 Ma, representing the only such combination of events in the Coeur d'Alene region subsequent to about 1300 Ma. The Sr and oxygen results and geologic evidence favor formation of the ore-bearing carbonate veins by fluids related to a complex metamorphic-hydrothermal system during the Cretaceous. Pb with Proterozoic isotopic compositions was probably mobilized and incorporated like other metals into the hydrothermal veins during this event. The ore-bearing veins were sheared and displaced during early Tertiary northwest-trending dextral strike-slip faulting along the Osburn fault and related structures of the Lewis and Clark line.
Vailulu'u Seamount, Samoa: Life and Death at the Edge of An Active Submarine Volcano
NASA Astrophysics Data System (ADS)
Vailulu'U Research Group, T.
2005-12-01
Exploration of Vailulu'u seamount (14°13'S; 169°04'W) by manned submersible, ROV, and surface ship revealed a new, 300m tall volcano that has grown in the summit crater in less than four years. This shows that Vailulu'u's eruption behavior is at this stage not predictable and continued growth could allow Vailulu'u to breach sea level within decades Several types of hydrothermal vents fill Vailulu'u crater with particulates that reduce visibility to less than a few meters in some regions. Hydrothermal solutions mix with seawater that enters the crater from its breaches to produce distinct biological habitats. Low temperature hydrothermal vents can produce Fe-oxide chimneys or up to one meter-thick microbial mats. Higher temperature vents (85°C) produce low salinity acidic fluids containing buoyant droplets of immiscible CO2. Low temperature hydrothermal vents at Nafanua summit (708m depth) support a thriving population of eels (Dysommia rusosa). The areas around the high temperature vents and the moat and remaining crater around the new volcano is almost devoid of any macroscopic life and is littered with fish, and mollusk carcasses that apparently died from exposure to hydrothermal fluid components in deeper crater waters. Acid- tolerant polychaetes adapt to this environment and feed near and on these carcasses. Vailulu'u presents a natural laboratory for the study of how seamounts and their volcanic systems interact with the hydrosphere to produce distinct biological habitats, and how marine life can adapt to these conditions or be trapped in a toxic volcanic system that leads to mass mortality. The Vailulu'u research team: Hubert Staudigel, Samantha Allen, Brad Bailey, Ed Baker, Sandra Brooke, Ryan Delaney, Blake English, Lisa Haucke, Stan Hart, John Helly, Ian Hudson, Matt Jackson, Daniel Jones, Alison Koleszar, Anthony Koppers, Jasper Konter, Laurent Montesi, Adele Pile, Ray Lee, Scott Mcbride, Julie Rumrill, Daniel Staudigel, Brad Tebo, Alexis Templeton, Rhea Workman, Craig Young, Robert Zierenberg.
The vent microbiome: patterns and drivers
NASA Astrophysics Data System (ADS)
Pachiadaki, M.
2015-12-01
Microbial processes within deep-sea hydrothermal vents affect the global biogeochemical cycles. Still, there are significant gaps in our understanding of the microbiology and the biogeochemistry of deep-sea hydrothermal systems. Vents differ in temperature, host rock composition and fluid chemistry; factors that are hypothesized to shape the distribution of the microbial communities, their metabolic capabilities and their activities. Using large-scale single cell genomics, we obtained insights into the genomic content of several linkages of a diffuse flow vent. The genomes show high metabolic versatility. Sulfur oxidation appears to be predominant but there is the potential of using a variety of e- donors and acceptors to obtain energy. To further assess the ecological importance of the vent auto- and heterotrophs, the global biogeography of the analyzed lineages will be investigated by fragment recruitment of metagenomes produced from the same site as well as other hydrothermal systems. Metatranscriptomic and metaproteomic data will be integrated to examine the expression of the predominant metabolic pathways and thus the main energy sources driving chemoautotrophic production. The comparative analysis of the key players and associated pathways among various vent sites that differ in physicochemical characteristics is anticipated to decipher the patterns and drivers of the global dispersion and the local diversification of the vent microbiome.
First hydrothermal active vent discovered on the Galapagos Microplate
NASA Astrophysics Data System (ADS)
Tao, C.; Li, H.; Wu, G.; Su, X.; Zhang, G.; Chinese DY115-21 Leg 3 Scientific Party
2011-12-01
The Galapagos Microplate (GM) lies on the western Gaplapagos Spreading Center (GSC), representing one of the classic Ridge-Ridge-Ridge (R-R-R) plate boundaries of the Nazca, Cocos, and Pacific plates. The presence of the 'black smoke' and hydrothermal vent community were firstly confirmed on the GSC. Lots of hydrothermal fields were discovered on the center and eastern GSC, while the western GSC has not been well investigated. During 17th Oct. to 9th Nov. 2009, the 3rd leg of Chinese DY115-21 cruise with R/V Dayangyihao has been launched along 2°N-5°S near equatorial East Pacific Rise (EPR). Two new hydrothermal fields were confirmed. One is named 'Precious Stone Mountain', which is the first hydrothermal field on the GM. The other is found at 101.47°W, 0.84°S EPR. The 'Precious Stone Mountain' hydrothermal field (at 101.49°W, 1.22°N) is located at an off-axial seamount on the southern GM boundary, with a depth from 1,450 to 1,700m. Hydrothermal fluids emitting from the fissures and hydrothermal fauna were captured by deep-tow video. Few mineral clasts of pyrite and chalcopyrite were separated from one sediment sample, but no sulfide chimney was found yet. Hydrothermal fauna such as alive mussels, crabs, shrimps, tubeworms, giant clams, as well as rock samples were collected by TV-Grab. The study of the seafloor classification with Simrad EM120 multi-beam echosounder has been conducted on the 'Precious Stone Mountain' hydrothermal field. The result indicates that seafloor materials around the hydrothermal field can be characterized into three types, such as the fresh lava, hydrothermal sediment, and altered rock.
NASA Astrophysics Data System (ADS)
Levin, Lisa A.; Mendoza, Guillermo F.; Konotchick, Talina; Lee, Raymond
2009-09-01
Hydrothermal fluids passing through sediments create a habitat hypothesized to influence the community structure of infaunal macrobenthos. Here we characterize the density, biomass, species composition, diversity, distributions, lifestyle, and nutritional sources of macroinfauna in hydrothermal sediments in NE and SW Pacific settings, and draw comparisons in search of faunal attributes characteristic of this habitat. There is increasing likelihood that seafloor massive sulfide deposits, associated with active and inactive hydrothermal venting, will be mined commercially. This creates a growing imperative for a more thorough understanding of the structure, dynamics, and resilience of the associated sediment faunas, and has stimulated the research presented here. Macrobenthic assemblages were studied at Manus Basin (1430-1634 m, Papua New Guinea [PNG]) as a function of location (South Su vs. Solwara 1), and hydrothermal activity (active vs. inactive), and at Middle Valley (2406-2411 m, near Juan de Fuca Ridge) as a function of habitat (active clam bed, microbial mat, hot mud, inactive background sediment). The studies conducted in PNG formed part of the environmental impact assessment work for the Solwara 1 Project of Nautilus Minerals Niugini Limited. We hypothesized that hydrothermally active sites should support (a) higher densities and biomass, (b) greater dominance and lower diversity, (c) a higher fraction of deposit feeders, and (d) greater isotopic evidence for chemosynthetic food sources than inactive sites. Manus Basin macrofauna generally had low density (<1000 ind. m -2) and low biomass (0.1-1.07 g m -2), except for the South Su active site, which had higher density (3494 ind. m -2) and biomass (11.94 g m -2), greater dominance (R1D=76%), lower diversity and more spatial (between-core) homogeneity than the Solwara 1 and South Su inactive sites. Dominant taxa at Manus Basin were Spionidae ( Prionospio sp.) in active sediments, and tanaids and deposit-feeding nuculanoid bivalves in active and inactive sediments. At Middle Valley, hot mud sediments supported few animals (1011 ind m -2) and low biomass (1.34 g m -2), while active clam bed sediments supported a high-density (19,984 ind m -2), high-biomass (4.46 g m -2), low-diversity assemblage comprised of largely orbiniid and syllid polychaetes. Microbial mat sediments had the most diverse assemblage (mainly orbiniid, syllid, dorvilleid, and ampharetid polychaetes) with intermediate densities (8191 ind m -2) and high biomass (4.23 g m -2). Fauna at both Manus Basin active sites had heavy δ 13C signatures (-17‰ to -13‰) indicative of chemosynthetic, TCA-cycle microbes at the base of the food chain. In contrast, photosynthesis and sulfide oxidation appear to fuel most of the fauna at Manus Basin inactive sites (δ 13C=-29‰ to -20‰) and Middle Valley active clam beds and microbial mats (δ 13C=-36‰ to -20‰). The two hydrothermal regions, located at opposite ends of the Pacific Ocean, supported different habitats, sharing few taxa at the generic or family level, but both exhibited elevated infaunal density and high dominance at selected sites. Subsurface-deposit feeding and bacterivory were prevalent feeding modes. Both the Manus Basin and Middle Valley assemblages exhibit significant within-region heterogeneity, apparently conferred by variations in hydrothermal activity and associated biogenic habitats.
Lipid synthesis under hydrothermal conditions by Fischer-Tropsch-type reactions
NASA Technical Reports Server (NTRS)
McCollom, T. M.; Ritter, G.; Simoneit, B. R.
1999-01-01
Ever since their discovery in the late 1970's, mid-ocean-ridge hydrothermal systems have received a great deal of attention as a possible site for the origin of life on Earth (and environments analogous to mid-ocean-ridge hydrothermal systems are postulated to have been sites where life could have originated or Mars and elsewhere as well). Because no modern-day terrestrial hydrothermal systems are free from the influence of organic compounds derived from biologic processes, laboratory experiments provide the best opportunity for confirmation of the potential for organic synthesis in hydrothermal systems. Here we report on the formation of lipid compounds during Fischer-Tropsch-type synthesis from aqueous solutions of formic acid or oxalic acid. Optimum synthesis occurs in stainless steel vessels by heating at 175 degrees C for 2-3 days and produces lipid compounds ranging from C2 to > C35 which consist of n-alkanols, n-alkanoic acids, n-alkenes, n-alkanes and alkanones. The precursor carbon sources used are either formic acid or oxalic acid, which disproportionate to H2, CO2 and probably CO. Both carbon sources yield the same lipid classes with essentially the same ranges of compounds. The synthesis reactions were confirmed by using 13C labeled precursor acids.
Lipid Synthesis Under Hydrothermal Conditions by Fischer- Tropsch-Type Reactions
NASA Astrophysics Data System (ADS)
McCollom, Thomas M.; Ritter, Gilles; Simoneit, Bernd R. T.
1999-03-01
Ever since their discovery in the late 1970's, mid-ocean-ridge hydrothermal systems have received a great deal of attention as a possible site for the origin of life on Earth (and environments analogous to mid-ocean-ridge hydrothermal systems are postulated to have been sites where life could have originated on Mars and elsewhere as well). Because no modern-day terrestrial hydrothermal systems are free from the influence of organic compounds derived from biologic processes, laboratory experiments provide the best opportunity for confirmation of the potential for organic synthesis in hydrothermal systems. Here we report on the formation of lipid compounds during Fischer-Tropsch-type synthesis from aqueous solutions of formic acid or oxalic acid. Optimum synthesis occurs in stainless steel vessels by heating at 175 °C for 2-3 days and produces lipid compounds ranging from C2 to >C35 which consist of n-alkanols, n- alkanoic acids, n-alkenes, n-alkanes and alkanones. The precursor carbon sources used are either formic acid or oxalic acid, which disproportionate to H2, CO2 and probably CO. Both carbon sources yield the same lipid classes with essentially the same ranges of compounds. The synthesis reactions were confirmed by using 13C labeled precursor acids.
Lipid synthesis under hydrothermal conditions by Fischer-Tropsch-type reactions.
McCollom, T M; Ritter, G; Simoneit, B R
1999-03-01
Ever since their discovery in the late 1970's, mid-ocean-ridge hydrothermal systems have received a great deal of attention as a possible site for the origin of life on Earth (and environments analogous to mid-ocean-ridge hydrothermal systems are postulated to have been sites where life could have originated or Mars and elsewhere as well). Because no modern-day terrestrial hydrothermal systems are free from the influence of organic compounds derived from biologic processes, laboratory experiments provide the best opportunity for confirmation of the potential for organic synthesis in hydrothermal systems. Here we report on the formation of lipid compounds during Fischer-Tropsch-type synthesis from aqueous solutions of formic acid or oxalic acid. Optimum synthesis occurs in stainless steel vessels by heating at 175 degrees C for 2-3 days and produces lipid compounds ranging from C2 to > C35 which consist of n-alkanols, n-alkanoic acids, n-alkenes, n-alkanes and alkanones. The precursor carbon sources used are either formic acid or oxalic acid, which disproportionate to H2, CO2 and probably CO. Both carbon sources yield the same lipid classes with essentially the same ranges of compounds. The synthesis reactions were confirmed by using 13C labeled precursor acids.
NASA Astrophysics Data System (ADS)
Plum, Christoph; Pradillon, Florence; Fujiwara, Yoshihiro; Sarrazin, Jozée
2017-03-01
The few existing studies on deep-sea hydrothermal vent copepods indicate low connectivity with surrounding environments and reveal high endemism among vents. However, the finding of non-endemic copepod species in association with engineer species at different reduced ecosystems poses questions about the dispersal of copepods and the colonization of hydrothermal vents as well as their ecological connectivity. The objective of this study is to understand copepod colonization patterns at a hydrothermal vent site in response to environmental factors such as temperature and fluid flow as well as the presence of different types of substrata. To address this objective, an in situ experiment was deployed using both organic (woods, pig bones) and inorganic (slates) substrata along a gradient of hydrothermal activity at the Lucky Strike vent field (Eiffel Tower, Mid-Atlantic Ridge). The substrata were deployed in 2011 during the MoMARSAT cruise and were recovered after two years in 2013. Overall, copepod density showed significant differences between substrata types, but was similar among different hydrothermal activity regimes. Highest densities were observed on woods at sites with moderate or low fluid input, whereas bones were the most densely colonized substrata at the 2 sites with higher hydrothermal influence. Although differences in copepod diversity were not significant, the observed trends revealed overall increasing diversity with decreasing temperature and fluid input. Slates showed highest diversity compared to the organic substrata. Temperature and fluid input had a significant influence on copepod community composition, resulting in higher similarity among stations with relatively high and low fluid inputs, respectively. While vent-specialists such as dirivultids and the tegastid Smacigastes micheli dominated substrata at high vent activity, the experiment demonstrated increasing abundance and dominance of non-vent taxa with decreasing temperature and fluid input. Effects of the substratum type on community composition were not significant, although at sites with moderate or low fluid input, woods exhibited distinctive communities with high densities and relative abundance of the taxon Nitocrella sp. In conclusion, copepod colonization and species composition were mainly influenced by hydrothermal fluid input and temperature rather than the type of substratum. The outcome of this study provides fundamental knowledge to better understand copepod colonization at hydrothermal vents.
YELLOWSTONE MAGMATIC-HYDROTHERMAL SYSTEM, U. S. A.
Fournier, R.O.; Pitt, A.M.; ,
1985-01-01
At Yellowstone National Park, the deep permeability and fluid circulation are probably controlled and maintained by repeated brittle fracture of rocks in response to local and regional stress. Focal depths of earthquakes beneath the Yellowstone caldera suggest that the transition from brittle fracture to quasi-plastic flow takes place at about 3 to 4 km. The maximum temperature likely to be attained by the hydrothermal system is 350 to 450 degree C, the convective thermal output is about 5. 5 multiplied by 10**9 watts, and the minimum average thermal flux is about 1800 mW/m**2 throughout 2,500 km**2. The average thermal gradient between the heat source and the convecting hydrothermal system must be at least 700 to 1000 degree C/km. Crystallization and partial cooling of about 0. 082 km**3 of basalt or 0. 10 km**3 of rhyolite annually could furnish the heat discharged in the hot-spring system. The Yellowstone magmatic-hydrothermal system as a whole appears to be cooling down, in spite of a relatively large rate of inflation of the Yellowstone caldera.
NASA Astrophysics Data System (ADS)
Wang, Shujie; Li, Huaiming; Zhai, Shikui; Yu, Zenghui; Cai, Zongwei
2017-12-01
In this study, geochemical compositions of elements in sulfide samples collected from the Deyin-1 hydrothermal field near the 15°S southern Mid-Atlantic Ridge (SMAR) were analyzed by the X-ray fluorescence spectrometry (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to examine the enrichment regulations of ore-forming elements and hydrothermal mineralization. These sulfide precipitates can be classified macroscopically into three types: Fe-rich sulfide, Fe-Cu-rich sulfide and Fe-Zn-rich sulfide, and are characterized by the enrichment of base metal elements along with a sequence of Fe>Zn>Cu. Compared with sulfides from other hydrothermal fields on MAR, Zn concentrations of sulfides in the research area are significantly high, while Cu concentrations are relatively low. For all major, trace or rare-earth elements (REE), their concentrations and related characteristic parameters exhibit significant variations (up to one or two orders of magnitude), which indicates the sulfides from different hydrothermal vents or even a same station were formed at different stages of hydrothermal mineralization, and suggests the variations of chemical compositions of the hydrothermal fluid with respect to time. The hydrothermal temperatures of sulfides precipitation decreased gradually from station TVG10 (st.TVG10) to st.TVG12, and to st.TVG11, indicating that the precipitation of hydrothermal sulfides is subjected to conditions changed from high temperature to low temperature, and that the hydrothermal activity of study area was at the late stage of a general trend of evolution from strong to weak. The abnormally low concentrations of REE in sulfides and their similar chondrite-normalized REE patterns show that REEs in all sulfides were derived from a same source, but underwent different processes of migration or enrichment, or sulfides were formed at different stages of hydrothermal mineralization. The sulfides collected from the active hydrothermal vent were mainly attributed to precipitating directly from the hydrothermal fluid, while those collected from the extinct hydrothermal chimney might have already been altered by the seawater. Generally, ore-forming elements in the sulfides can be divided into three groups: Fe-based element group, Cu-based element group and Zn-based element group. The first group includes Fe, Mn, Cr, Mo, Sn, Rb and bio-enriching elements, such as P and Si, reflecting the similar characteristics to Fe in the study area. And the second group contains Cu, W, Co, Se, Te and Bi, suggesting the similar behavior with Cu. Moreover, the third group includes Zn, Hf, Hg, Cd, Ta, Ga, Pb, As, Ag, Ni and Sb, which indicates the geochemical characteristics of most dispersed trace elements controlled by Zn-bearing minerals to some extent.
Mapping advanced argillic alteration at Cuprite, Nevada, using imaging spectroscopy
Swayze, Gregg A.; Clark, Roger N.; Goetz, Alexander F.H.; Livo, K. Eric; Breit, George N.; Kruse, Fred A.; Sutley, Stephen J.; Snee, Lawrence W.; Lowers, Heather A.; Post, James L.; Stoffregen, Roger E.; Ashley, Roger P.
2014-01-01
Mineral maps based on Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were used to study late Miocene advanced argillic alteration at Cuprite, Nevada. Distributions of Fe-bearing minerals, clays, micas, sulfates, and carbonates were mapped using the Tetracorder spectral-shape matching system. The Al content of white micas increases toward altered areas and near intrusive rocks. Alunite composition varies from pure K to intimate mixtures of Na-K endmembers with subpixel occurrences of huangite, the Ca analogue of alunite. Intimately mixed Na-K alunite marks areas of relatively lower alteration temperature, whereas co-occurring Na-alunite and dickite may delineate relict hydrothermal conduits. The presence of dickite, halloysite, and well-ordered kaolinite, but absence of disordered kaolinite, is consistent with acidic conditions during hydrothermal alteration. Partial lichen cover on opal spectrally mimics chalcedony, limiting its detection to lichen-free areas. Pods of buddingtonite are remnants of initial quartz-adularia-smectite alteration. Thus, spectral maps provide a synoptic view of the surface mineralogy, and define a previously unrecognized early steam-heated hydrothermal event.Faulting and episodes of hydrothermal alteration at Cuprite were intimately linked to upper plate movements above the Silver Peak-Lone Mountain detachment and growth, collapse, and resurgence of the nearby Stonewall Mountain volcanic complex between 8 and 5 Ma. Isotopic dating indicates that hydrothermal activity started at least by 7.61 Ma and ended by about 6.2 Ma. Spectral and stable isotope data suggest that Cuprite is a late Miocene low-sulfidation adularia-sericite type hot spring deposit overprinted by late-stage, steam-heated advanced argillic alteration formed along the margin of the Stonewall Mountain caldera.
Mineralogical and chemical characteristics of some natural jarosites
Desborough, G.A.; Smith, K.S.; Lowers, H.A.; Swayze, G.A.; Hammarstrom, J.M.; Diehl, S.F.; Leinz, R.W.; Driscoll, R.L.
2010-01-01
This paper presents a detailed study of the mineralogical, microscopic, thermal, and spectral characteristics of jarosite and natrojarosite minerals. Systematic mineralogic and chemical examination of a suite of 32 natural stoichiometric jarosite and natrojarosite samples from diverse supergene and hydrothermal environments indicates that there is only limited solid solution between Na and K at low temperatures, which suggests the presence of a solvus in the jarosite-natrojarosite system at temperatures below about 140 ??C. The samples examined in this study consist of either end members or coexisting end-member pairs of jarosite and natrojarosite. Quantitative electron-probe microanalysis data for several natural hydrothermal samples show only end-member compositions for individual grains or zones, and no detectable alkali-site deficiencies, which indicates that there is no hydronium substitution within the analytical uncertainty of the method. In addition, there is no evidence of Fe deficiencies in the natural hydrothermal samples. Hydronium-bearing jarosite was detected in only one relatively young supergene sample suggesting that terrestrial hydronium-bearing jarosites generally are unstable over geologic timescales. Unit-cell parameters of the 20 natural stoichiometric jarosites and 12 natural stoichiometric natrojarosites examined in this study have distinct and narrow ranges in the a- and c-cell dimensions. There is no overlap of these parameters at the 1?? level for the two end-member compositions. Several hydrothermal samples consist of fine-scale (2-10 ??m) intimate intergrowths of jarosite and natrojarosite, which could have resulted from solid-state diffusion segregation or growth zoning due to variations in the Na/K activity ratio of hydrothermal solutions.
NASA Technical Reports Server (NTRS)
Harrison, Keith P.; Grimm, Robert E.
2002-01-01
Models of hydrothermal groundwater circulation can quantify limits to the role of hydrothermal activity in Martian crustal processes. We present here the results of numerical simulations of convection in a porous medium due to the presence of a hot intruded magma chamber. The parameter space includes magma chamber depth, volume, aspect ratio, and host rock permeability and porosity. A primary goal of the models is the computation of surface discharge. Discharge increases approximately linearly with chamber volume, decreases weakly with depth (at low geothermal gradients), and is maximized for equant-shaped chambers. Discharge increases linearly with permeability until limited by the energy available from the intrusion. Changes in the average porosity are balanced by changes in flow velocity and therefore have little effect. Water/rock ratios of approximately 0.1, obtained by other workers from models based on the mineralogy of the Shergotty meteorite, imply minimum permeabilities of 10(exp -16) sq m2 during hydrothermal alteration. If substantial vapor volumes are required for soil alteration, the permeability must exceed 10(exp -15) sq m. The principal application of our model is to test the viability of hydrothermal circulation as the primary process responsible for the broad spatial correlation of Martian valley networks with magnetic anomalies. For host rock permeabilities as low as 10(exp -17) sq m and intrusion volumes as low as 50 cu km, the total discharge due to intrusions building that part of the southern highlands crust associated with magnetic anomalies spans a comparable range as the inferred discharge from the overlying valley networks.
Li, Hongzhong; Zhai, Mingguo; Zhang, Lianchang; Gao, Le; Yang, Zhijun; Zhou, Yongzhang; He, Junguo; Liang, Jin; Zhou, Liuyu; Voudouris, Panagiotis Ch
2014-01-01
Marine siliceous rocks are widely distributed in the central orogenic belt (COB) of China and have a close connection to the geological evolution and metallogenesis. They display periodic distributions from Mesoproterozoic to Jurassic with positive peaks in the Mesoproterozoic, Cambrian--Ordovician, and Carboniferous--Permian and their deposition is enhanced by the tensional geological settings. The compressional regimes during the Jinning, Caledonian, Hercynian, Indosinian, and Yanshanian orogenies resulted in sudden descent in their distribution. The siliceous rocks of the Bafangshan-Erlihe ore deposit include authigenic quartz, syn-depositional metal sulphides, and scattered carbonate minerals. Their SiO2 content (71.08-95.30%), Ba (42.45-503.0 ppm), and ΣREE (3.28-19.75 ppm) suggest a hydrothermal sedimentation origin. As evidenced by the Al/(Al + Fe + Mn), Sc/Th, (La/Yb) N, and (La/Ce) N ratios and δCe values, the studied siliceous rocks were deposited in a marginal sea basin of a limited ocean. We suggest that the Bafangshan-Erlihe area experienced high- and low-temperature stages of hydrothermal activities. The hydrothermal sediments of the former stage include metal sulphides and silica, while the latter was mainly composed of silica. Despite the hydrothermal sedimentation of the siliceous rocks, minor terrigenous input, magmatism, and biological activity partly contributed to geochemical features deviating from the typical hydrothermal characteristics.
Li, Hongzhong; Zhai, Mingguo; Zhang, Lianchang; Gao, Le; Yang, Zhijun; Zhou, Yongzhang; He, Junguo; Liang, Jin; Zhou, Liuyu; Voudouris, Panagiotis Ch.
2014-01-01
Marine siliceous rocks are widely distributed in the central orogenic belt (COB) of China and have a close connection to the geological evolution and metallogenesis. They display periodic distributions from Mesoproterozoic to Jurassic with positive peaks in the Mesoproterozoic, Cambrian—Ordovician, and Carboniferous—Permian and their deposition is enhanced by the tensional geological settings. The compressional regimes during the Jinning, Caledonian, Hercynian, Indosinian, and Yanshanian orogenies resulted in sudden descent in their distribution. The siliceous rocks of the Bafangshan-Erlihe ore deposit include authigenic quartz, syn-depositional metal sulphides, and scattered carbonate minerals. Their SiO2 content (71.08–95.30%), Ba (42.45–503.0 ppm), and ΣREE (3.28–19.75 ppm) suggest a hydrothermal sedimentation origin. As evidenced by the Al/(Al + Fe + Mn), Sc/Th, (La/Yb)N, and (La/Ce)N ratios and δCe values, the studied siliceous rocks were deposited in a marginal sea basin of a limited ocean. We suggest that the Bafangshan-Erlihe area experienced high- and low-temperature stages of hydrothermal activities. The hydrothermal sediments of the former stage include metal sulphides and silica, while the latter was mainly composed of silica. Despite the hydrothermal sedimentation of the siliceous rocks, minor terrigenous input, magmatism, and biological activity partly contributed to geochemical features deviating from the typical hydrothermal characteristics. PMID:25140349
NASA Astrophysics Data System (ADS)
Tao, Chunhui; Chen, Sheng; Baker, Edward T.; Li, Huaiming; Liang, Jin; Liao, Shili; Chen, Yongshun John; Deng, Xianming; Zhang, Guoyin; Gu, Chunhua; Wu, Jialin
2017-06-01
Seafloor hydrothermal polymetallic sulfide deposits are a new type of resource, with great potential economic value and good prospect development. This paper discusses turbidity, oxidation-reduction potential, and temperature anomalies of hydrothermal plumes from the Zouyu-1 and Zouyu-2 hydrothermal fields on the southern Mid-Atlantic Ridge. We use the known location of these vent fields and plume data collected in multiple years (2009, 2011, 2013) to demonstrate how real-time plume exploration can be used to locate active vent fields, and thus associated sulfide deposits. Turbidity anomalies can be detected 10 s of km from an active source, but the location precision is no better than a few kilometers because fine-grained particles are quasi-conservative over periods of many days. Temperature and oxidation-reduction potential anomalies provide location precision of a few hundred meters. Temperature anomalies are generally weak and difficult to reliably detect, except by chance encounters of a buoyant plume. Oxidation-reduction potential is highly sensitive (nmol concentrations of reduced hydrothermal chemicals) to discharges of all temperatures and responds immediately to a plume encounter. Real-time surveys using continuous tows of turbidity and oxidation-reduction potential sensors offer the most efficient and precise surface ship exploration presently possible.
Post-impact hydrothermal system geochemistry and mineralogy: Rochechouart impact structure, France.
NASA Astrophysics Data System (ADS)
Simpson, Sarah
2014-05-01
Hypervelocity impacts generate extreme temperatures and pressures in target rocks and may permanently alter them. The process of cratering is at the forefront of research involving the study of the evolution and origin of life, both on Mars and Earth, as conditions may be favourable for hydrothermal systems to form. Of the 170 known impact structures on Earth, over one-third are known to contain fossil hydrothermal systems [1]. The introduction of water to a system, when coupled with even small amounts of heat, has the potential to completely alter the target or host rock geochemistry. Often, the mineral assemblages produced in these environments are unique, and are useful indicators of post-impact conditions. The Rochechouart impact structure in South-Central France is dated to 201 ± 2 Ma into a primarily granitic target [2]. Much of the original morphological features have been eroded and very little of the allochthonous impactites remain. This has, however, allowed researchers to study the shock effects on the lower and central areas of the structure, as well as any subsequent hydrothermal activity. Previous work has focused on detailed classification of the target and autochthonous and allochthonous impactites [3, 4], identification of the projectile [5], and dating the structure using Ar-isotope techniques [2]. Authors have also noted geochemical evidence of K-metasomatism, which is pronounced throughout all lithologies as enrichment in K2O and depletion in CaO and Na2O [3, 4, 5]. This indicates a pervasive hydrothermal system, whose effects throughout the structure have yet to be studied in detail, particularly in those parts at and below the transient floor. The purpose of this study is to classify the mineralogical and geochemical effects of the hydrothermal system. Samples were collected via permission from the Réserve Naturelle de l'Astroblème de Rochechouart-Chassenon [6]. Sample selection was based on the presence of secondary mineralization in hand sample and prepared for SEM/EDS and Raman analysis using the facilities available through the University of Glasgow. Oxygen and sulphur stable isotope work will begin in February at the SUERC facility in East Kilbride, Scotland. Carbonate and sulphide mineral veining is restricted to below the transient crater floor, cross cutting brecciated basement rocks and pseudotachylites Melt-bearing lithologies display heavy argillization, particularly in the melt-rich, vesicular lithologies. Vesicles are lined with sulphates, sulphides and Fe and Ti oxides, and fractured granitic basement has been locally sericitized, particularly in samples containing mineral veins. In altered melt-rich impactites, there is an accumulation of REE's around the periphery of vesicles. Further results from this study will be used to constrain the conditions of the hydrothermal system, particularly temperature and chemistry of fluids, and levels of alteration with respect to location within the structure. As geologic processes and conditions are similar on the Martian surface to those on Earth, findings from this and similar studies may be used as analogues for impact hydrothermal systems on Mars [7]. [1] Osinski, G. R. and Tornabene, L. L. (2013) Icarus 224, 347-363 [2] Schmeider, M. et al. (2010) Meteoritics & Planetary Science 45, Nr 8, 1225-1242 [3] Lambert, P., (1977) Earth and Planetary Science Letters, 3, 258-268 [4] Lambert, P., (2010) The Geological Society of America Special Paper 465 [5] Tagle, R. and Schmitt, R. T., (2009) Geochimica et Cosmochimica Acta 73, 4891-4906 [6] Réserve Naturelle de l'Astroblème de Rochechouart-Chassenon, CCPM Mairie-Place-du-Chateau, 87600, Rochechouart, France [7] Schwenzer, S.P. et al., (2012) Earth and Planetary Science Letters 335-336, 9-17
Microbial community structure across fluid gradients in the Juan de Fuca Ridge hydrothermal system.
Anderson, Rika E; Beltrán, Mónica Torres; Hallam, Steven J; Baross, John A
2013-02-01
Physical and chemical gradients are dominant factors in shaping hydrothermal vent microbial ecology, where archaeal and bacterial habitats encompass a range between hot, reduced hydrothermal fluid and cold, oxidized seawater. To determine the impact of these fluid gradients on microbial communities inhabiting these systems, we surveyed bacterial and archaeal community structure among and between hydrothermal plumes, diffuse flow fluids, and background seawater in several hydrothermal vent sites on the Juan de Fuca Ridge using 16S rRNA gene diversity screening (clone libraries and terminal restriction length polymorphisms) and quantitative polymerase chain reaction methods. Community structure was similar between hydrothermal plumes and background seawater, where a number of taxa usually associated with low-oxygen zones were observed, whereas high-temperature diffuse fluids exhibited a distinct phylogenetic profile. SUP05 and Arctic96BD-19 sulfur-oxidizing bacteria were prevalent in all three mixing regimes where they exhibited overlapping but not identical abundance patterns. Taken together, these results indicate conserved patterns of redox-driven niche partitioning between hydrothermal mixing regimes and microbial communities associated with sinking particles and oxygen-deficient waters. Moreover, the prevalence of SUP05 and Arctic96BD-19 in plume and diffuse flow fluids indicates a more cosmopolitan role for these groups in the ecology and biogeochemistry of the dark ocean. © 2012 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Stewart, C. L.; Schrenk, M.
2017-12-01
Ultramafic-hosted hydrothermal systems associated with slow-spreading mid ocean ridges emit copious amounts of hydrogen and methane into the deep-sea, generated through a process known as serpentinization. Hydrothermal plumes carrying the reduced products of water-rock interaction dissipate and mix with deep seawater, and potentially harbor microbial communities adapted to these conditions. Methane and hydrogen enriched hydrothermal plumes were sampled from 3 sites near the Atlantis Massif (30°N, Mid Atlantic Ridge) during IODP Expedition 357 and used to initiate cultivation experiments targeting methanotrophic and hydrogenotrophic microorganisms. One set of experiments incubated the cultures at in situ hydrostatic pressures and gas concentrations resulting in the enrichment of gammaproteobacterial assemblages, including Marinobacter spp. That may be involved in hydrocarbon degradation. A second set of experiments pursued the anaerobic enrichment of microbial communities on solid media, resulting in the enrichment of alphaproteobacteria related to Ruegeria. The most prodigious growth in both case occurred in methane-enriched media, which may play a role as both an energy and carbon source. Ongoing work is evaluating the physiological characteristics of these isolates, including their metabolic outputs under different physical-chemical conditions. In addition to providing novel isolates from hydrothermal habitats near the Lost City Hydrothermal Field, these experiments will provide insight into the ecology of microbial communities from serpentinization influenced hydrothermal systems that may aid in future exploration of these sites.
NASA Astrophysics Data System (ADS)
Hanamuro, T.; Umeda, K.; Maeda, K.
2008-12-01
Although there is no known evidence of volcanism during the Pliocene nor the Quaternary in the Kii Peninsula, it has long been recognized to host several hot springs with discharge temperatures greater than 60°C. In addition, numerous small-scale vein-type metal deposits are distributed around the southern part of the peninsula, with a heat source thought to be the Middle Miocene acidic magmatism associated with Kumano Acidic Rocks. The results of the TL (Thermoluminescence), FT (Fission Track) and K-Ar dating of altered rocks from these hot spring areas showed that the vein-type ore deposits and their surrounding altered rocks experienced high temperature hydrothermal alteration related to acidic magmatism in the Middle Miocene, whereas relatively low temperature alteration has occurred since the Pliocene in the Hongu and Totsukawa hot spring areas [Hanamuro et al., 2008]. Chemical and isotope data were obtained for fluid inclusions trapped in hydrothermal minerals in the peripheral parts of the high-temperature hot springs and in vein-type ore deposits. The hot spring inclusions indicate temperatures reached ~100°C with salinities of about 2 wt % (NaCl equiv.). In contrast, the inclusions in the vein-type deposits are characterized by high temperature fluids (>260°C) with high salinity (>5 wt %). The 3He/4He ratios of the hot spring inclusions have relatively high values, generally in agreement with those of the present-day hydrothermal fluids, indicating a significant contribution by deep source gases (i.e., mantle helium). These results suggest that the amagmatic hydrothermal system related to high-temperature hot springs in the southern Kii Peninsula have formed since the Pliocene and were caused by high temperature fluids with a lower crust provenance, presumably supplied from the subducting slab of the Philippine Sea Plate (PHS) [Umeda et al., 2006]. After a hiatus of about 4 Ma, the PHS resumed subduction beneath the SW Japan Arc at around 6 Ma [Kamata and Kodama, 1994]. This indicates that the present-day plate system for the SW Japan arc formed at around 6 Ma and continues to the present day. Although we lack definitive information on the age of hydrothermal alteration, it seems reasonable to infer that the amagmatic hydrothermal activity since about 6 Ma in the southern Kii Peninsula has occurred in a manner synchronous with the present-day plate system of the SW Japan Arc. Reference Hanamuro et al. (2008): Japanese Magazine of Mineralogical and Petrological Sciences, 37, 27-38 (in Japanese with English Abstract). Kamata and Kodama (1994): Journal of Geophysical Research, 233, 69-81. Umeda et al. (2006): Journal of Volcanology and Geothermal Research, 149, 47-61.
Normark, W.R.
1986-01-01
The submersible Alvin was used to investigate 3 active hydrothermal discharge sites along the S Juan de Fuca Ridge in September 1984. The hydrothermal zones occur within a 10-30m-deep, 30-50m-wide cleft marking the center of the axial valley. This cleft is the eruptive locus for the axial valley. The hydrothermal vents coincide with the main eruptive vents along the cleft. Each hydrothermal zone has multiple discharge sites extending as much as 500m along the cleft. Sulfide deposits occur as clusters (15-100m2 area) of small chimneys (= or <2m high) and as individual and clustered fields of large, branched chimneys (= or <10m high). Recovered sulfide samples are predominantly the tops of chimneys and spires and typically contain more than 80% sphalerite and wurtzite with minor pyrrhotite, pyrite, marcasite, isocubanite, chalcopyrite, anhydrite, anhydrite, and amorphous silica. The associated hydrothermal fluids have the highest chlorinity of any reported to date.-Authors
Steven, Thomas A.
1984-01-01
PART A: Igneous activity in the Marysvale volcanic field of western Utah can be separated into many episodes of extrusion, intrusion, and hydrothermal activity. The rocks of the western Tushar Mountains, near the western part of the volcanic field, include intermediate-composition, calc-alkalic volcanic rocks erupted from scattered volcanoes in Oligocene through earliest Miocene time and related monzonitic intrusions emplaced 24-23 m.y. ago. Beginning 22-21 m.y. ago and extending through much of the later Cenozoic, a bimodal basalt-rhyolite assemblage was erupted widely throughout the volcanic field. Only volcanic and intrusive rocks belonging to the rhyolitic end member of this bimodal assemblage are present in the western Tushar Mountains; most of these rocks either fill the Mount Belknap caldera (19 m.y. old) or are part of the rhyolite of Gillies Hill (9---8 m.y. old). Episodic hydrothermal activity altered and mineralized rocks at many places in the western Tushar Mountains during Miocene time. The earliest activity took place in and adjacent to monzonitic calcalkalic intrusions emplaced in the vicinity of Indian Creek and Cork Ridge. These rocks were widely propylitized, and gold-bearing quartz-pyrite-carbonate veins formed in local fractures. Hydrothermal activity associated with the Mount Belknap caldera mobilized and redeposited uranium contained in the caldera-fill rocks and formed primary concentrations of lithophile elements (including molybdenum and uranium) in the vicinity of intrusive bodies. Hydrothermal activity associated with the rhyolite of Gillies Hill altered and mineralized rocks at several places along the fault zone that marks the western margin of the Tushar Mountains; the zoned alunite and gold deposits at Sheep Rock, the gold deposit at the Sunday Mine, and an alunite deposit near Indian Creek were thus produced. Resetting of isotopic ages suggests that another center of hydrothermally altered rocks associated with a buried pluton about 16 m.y. old may exist near Indian Creek just west of the Mount Belknap caldera. Geophysical evidence confirms the probability of a buried pluton near Indian Creek, and also indicates that another buried pluton probably exists beneath the 9-m.y.-old mineralized area at Sheep Rock. The mineral potential of the different hydrothermal systems, and the types of minerals deposited probably vary considerably from one period of mineralization to another and from one depth environment to another within a given system. PART B: The Big John caldera, on the western flank of the Tushar Mountains in the Marysvale volcanic field in west-central Utah, formed 23-22 m.y. ago in response to ash-flow eruptions of the Delano Peak Tuff Member of the Bullion Canyon Volcanics. These eruptions were near the end of the period of Oligocene-early Miocene calc-alkalic igneous activity that built a broad volcanic plateau in this part of Utah. About 22 m.y. ago, the composition of rocks erupted changed to a bimodal assemblage of mafic and silicic volcanics that was erupted episodically through the remainder of Cenozoic time. The alkali rhyolites are uranium rich in part, and are associated with all the known uranium deposits in the Marysvale volcanic field. The Big John caldera was a broad drained basin whose floor was covered by a layer of stream gravels when ash flows from the western source area of the Mount Belknap Volcanics filled the caldera with the Joe Lott Tuff Member about 19 m.y. ago. Devitrified and zeolitized rocks in the caldera fill have lost one-quarter to one-half of the uranium contained in the original magma. This mobilized uranium probably moved into the hydrologic regime, and some may have been redeposited in stream gravels underlying the Joe Lott within the caldera, or in gravels filling the original drainage channel that extended south from the caldera.
Decline of a Hydrothermal Vent Field - Escanaba Trough 12 Years Later
NASA Astrophysics Data System (ADS)
Zierenberg, R. A.; Clague, D. A.; Davis, A. S.; Lilley, M. D.; McClain, J. S.; Olson, E. S.; Ross, S. L.; Von Damm, K. L.
2001-12-01
Hydrothermal venting was discovered in Escanaba Trough, the southern sediment-covered portion of the Gorda Ridge, in 1988. Large pyrrhotite-rich massive sulfide mounds are abundant at each of the volcanic/intrusive centers that have been investigated in Escanaba Trough, but the only area of known hydrothermal venting is the NESCA site along the ridge axis at 41\\deg N. Hydrothermal fluids venting at 217\\deg C and 108\\deg C were sampled in 1988 on two sulfide mounds separated by about 275 m. The end-member fluid compositions were indistinguishable within analytical errors. Several sulfide mounds were observed in 1988 which had diffusely venting low temperature (< 20\\deg C) fluids that supported extensive vent communities dominated by fields of Ridgia. Nine holes were drilled in the NESCA area in 1996 on ODP Leg 169, including Hole 1036I that penetrated to basaltic basement at 405 m below sea floor (mbsf). Surveys of the area using the drill string camera located only one area of active venting at the same mound where 217\\deg C vent fluids were sampled from two active vents in 1988. Drill hole 1036A was spudded between the two active vents on this sulfide mound (approximately 4 and 8 m away) and penetrated to 115 mbsf. The NESCA site was revisited in 2000 using MBARI's R/V Western Flyer and ROV Tiburon. The hydrothermal vents appeared essentially identical to observations made from the drill string camera in 1996 despite the presence of a drill hole within meters of the two vents. The maximum vent temperature measured in 2000 was 212\\deg C. Fluid samples have major element and isotopic compositions very similar to those collected in 1988. The vent fluids have higher methane ( ~19 mmol/kg) than those from the geologically similar Middle Valley vent field, but lower values than those at Guaymas Basin. Drill hole 1036A was weakly venting, but the diffuse hydrothermal fluids could not be sampled with the equipment available. The walls of the drill hole were colonized by palm worms, limpets, and snails. Four other drill holes showed no hydrothermal flow nor visible evidence of down hole recharge. Mapping with Tiburon confirmed that the extent of hydrothermal venting at NESCA decreased dramatically since 1988. Formerly extensive colonies of Ridgia had vanished leaving no trace of their presence. Although hydrothermal venting has collapsed to a single mound, the temperature and composition of the fluids remained nearly unchanged. This is curious given that sediment pore fluids analyzed on Leg 169 included both high salinity and low salinity components of phase separated hydrothermal fluids in the shallow subsurface indicating that the hydrothermal field must have had a relatively recent (relative to the rate of pore fluid diffusion) high temperature history. Hydrothermal fluids presently venting at this site must be derived from an essentially homogeneous, approximately 215\\degC fluid reservoir that has declined in its fluid output on a decadal scale, but has not undergone significant changes in temperature and composition. Venting at the seafloor does not seem to have been affected by drilling in the hydrothermal field.
Pjevac, Petra; Meier, Dimitri V.; Markert, Stephanie; Hentschker, Christian; Schweder, Thomas; Becher, Dörte; Gruber-Vodicka, Harald R.; Richter, Michael; Bach, Wolfgang; Amann, Rudolf; Meyerdierks, Anke
2018-01-01
At hydrothermal vent sites, chimneys consisting of sulfides, sulfates, and oxides are formed upon contact of reduced hydrothermal fluids with oxygenated seawater. The walls and surfaces of these chimneys are an important habitat for vent-associated microorganisms. We used community proteogenomics to investigate and compare the composition, metabolic potential and relative in situ protein abundance of microbial communities colonizing two actively venting hydrothermal chimneys from the Manus Basin back-arc spreading center (Papua New Guinea). We identified overlaps in the in situ functional profiles of both chimneys, despite differences in microbial community composition and venting regime. Carbon fixation on both chimneys seems to have been primarily mediated through the reverse tricarboxylic acid cycle and fueled by sulfur-oxidation, while the abundant metabolic potential for hydrogen oxidation and carbon fixation via the Calvin–Benson–Bassham cycle was hardly utilized. Notably, the highly diverse microbial community colonizing the analyzed black smoker chimney had a highly redundant metabolic potential. In contrast, the considerably less diverse community colonizing the diffusely venting chimney displayed a higher metabolic versatility. An increased diversity on the phylogenetic level is thus not directly linked to an increased metabolic diversity in microbial communities that colonize hydrothermal chimneys. PMID:29696004
Constrained circulation at Endeavour ridge facilitates colonization by vent larvae.
Thomson, Richard E; Mihály, Steven F; Rabinovich, Alexander B; McDuff, Russell E; Veirs, Scott R; Stahr, Frederick R
2003-07-31
Understanding how larvae from extant hydrothermal vent fields colonize neighbouring regions of the mid-ocean ridge system remains a major challenge in oceanic research. Among the factors considered important in the recruitment of deep-sea larvae are metabolic lifespan, the connectivity of the seafloor topography, and the characteristics of the currents. Here we use current velocity measurements from Endeavour ridge to examine the role of topographically constrained circulation on larval transport along-ridge. We show that the dominant tidal and wind-generated currents in the region are strongly attenuated within the rift valley that splits the ridge crest, and that hydrothermal plumes rising from vent fields in the valley drive a steady near-bottom inflow within the valley. Extrapolation of these findings suggests that the suppression of oscillatory currents within rift valleys of mid-ocean ridges shields larvae from cross-axis dispersal into the inhospitable deep ocean. This effect, augmented by plume-driven circulation within rift valleys having active hydrothermal venting, helps retain larvae near their source. Larvae are then exported preferentially down-ridge during regional flow events that intermittently over-ride the currents within the valley.
Brown, Adrian; Walter, Malcolm; Cudahy, Thomas
2004-01-01
Rover missions to the rocky bodies of the Solar System and especially to Mars require lightweight, portable instruments that use minimal power, require no sample preparation, and provide suitably diagnostic mineralogical information to an Earth-based exploration team. Short-wave infrared (SWIR) spectroscopic instruments such as the Portable Infrared Mineral Analyser (PIMA, Integrated Spectronics Pty Ltd., Baulkham Hills, NSW, Australia) fulfill all these requirements. We describe an investigation of a possible Mars analogue site using a PIMA instrument. A survey was carried out on the Strelley Pool Chert, an outcrop of stromatolitic, silicified Archean carbonate and clastic succession in the Pilbara Craton, interpreted as being modified by hydrothermal processes. The results of this study demonstrate the capability of SWIR techniques to add significantly to the geological interpretation of such hydrothermally altered outcrops. Minerals identified include dolomite, white micas such as illite-muscovite, and chlorite. In addition, the detection of pyrophyllite in a bleached and altered unit directly beneath the succession suggests acidic, sulfur-rich hydrothermal activity may have interacted with the silicified sediments of the Strelley Pool Chert.
In-situ Eh sensor measurement and calibration: application to seafloor observatories
NASA Astrophysics Data System (ADS)
Ding, K.; Seyfried, W. E.; Tan, C.
2013-12-01
Eh measurement is often used with manned submersible and AUV assets as an effective way to detect and locate seafloor hydrothermal activity. Eh can be fundamentally and sensitively linked to dissolved H 2 , which, in turn, serves as a key constraint on subseafloor redox reactions. Moreover, Eh is now being increasingly relied on for event detection and process monitoring efforts intrinsic to cabled seafloor observatories. Due to seawater interaction with electrochemical components fundamental to the operation of the Eh sensor, however, the quality and reliability of the measurements are often compromised by signal drift, especially when the sensor is used for long term deployment. To solve this problem, a calibration protocol was developed and added to our previously constructed pH 'calibrator'. Thus, the integrated electrochemical system now permits the combined in-situ measurement and calibration of pH and Eh of seafloor hydrothermal fluids. Key aspects of the design for this calibration system are: (1) the sensing electrodes can be kept preserved in fluid of known pH, Eh and NaCl concentration prior to use, thereby preventing deterioration of electrode response characteristics by chemical and biological activity; (2) the system consists of valves and pumps for flow control, and therefore can be operated remotely with power from the seafloor cabled observatory, or as a stand-alone device, using battery power for shorter-term deployments. In both cases, standardization with on-board fluids of known redox, pH, and NaCl activity can be activated at any time, providing enhanced reliability (3) the current development is aimed at deep sea environments, cold seeps, and hydrothermal diffuse flow fluids at the temperatures up to 100°C and depths up to 4500 m. The in-situ operation is especially well-suited for use with cabled observatory for real time intervention and event response owing to enabled power supply and two way communications. Field tests have been conducted extensively during one Alvin cruise at EPR 9°N, and one Jason-II cruise at MAR (Lost city, 30°N). In addition to these submersible deployments, profile measurements using ship wench system were made from the sea-surface to depths to more than 3000 m. The remote operation tests were carried out with a direct connection though MARS seafloor cabled observatory at the depth of 880 m for a period of more than two months. During these deployments, the standard solutions with O2 concentration of room saturation matched with seawater salinity and know pH values were used. The results indicate the effectiveness of these concepts and design for conducting in-situ calibration enhanced Eh measurement and monitoring covering the operational conditions from normal seawater with relatively oxidizing environment to reducing condition in low temperature hydrothermal diffuse systems. The results and detailed discussion will be presented in this presentation.
Sylvan, Jason B.; Toner, Brandy M.; Edwards, Katrina J.
2012-01-01
ABSTRACT Hydrothermal chimneys are a globally dispersed habitat on the seafloor associated with mid-ocean ridge (MOR) spreading centers. Active, hot, venting sulfide structures from MORs have been examined for microbial diversity and ecology since their discovery in the mid-1970s, and recent work has also begun to explore the microbiology of inactive sulfides—structures that persist for decades to millennia and form moderate to massive deposits at and below the seafloor. Here we used tag pyrosequencing of the V6 region of the 16S rRNA and full-length 16S rRNA sequencing on inactive hydrothermal sulfide chimney samples from 9°N on the East Pacific Rise to learn their bacterial composition, metabolic potential, and succession from venting to nonventing (inactive) regimes. Alpha-, beta-, delta-, and gammaproteobacteria and members of the phylum Bacteroidetes dominate all inactive sulfides. Greater than 26% of the V6 tags obtained are closely related to lineages involved in sulfur, nitrogen, iron, and methane cycling. Epsilonproteobacteria represent <4% of the V6 tags recovered from inactive sulfides and 15% of the full-length clones, despite their high abundance in active chimneys. Members of the phylum Aquificae, which are common in active vents, were absent from both the V6 tags and full-length 16S rRNA data sets. In both analyses, the proportions of alphaproteobacteria, betaproteobacteria, and members of the phylum Bacteroidetes were greater than those found on active hydrothermal sulfides. These shifts in bacterial population structure on inactive chimneys reveal ecological succession following cessation of venting and also imply a potential shift in microbial activity and metabolic guilds on hydrothermal sulfides, the dominant biome that results from seafloor venting. PMID:22275502
NASA Astrophysics Data System (ADS)
Whitley, S. Z.; Mittelstaedt, E. L.
2016-02-01
During expedition NA054 of the E/V Nautilus from 18 September to 9 October 2014 and as part of the TREET (Transforming Remotely Conducted Research through Ethnography, Education, and Rapidly Evolving Technologies) project, a series of photographic surveys along the shoulder of the Kick'em Jenny volcano were performed under direction of a remote research team located at the University of Rhode Island Inner Space Center. The primary goal of these surveys was to map the distribution and extent of active and extinct hydrothermal activity along a large collapse scar surrounding the current edifice of the Kick'em Jenny volcano. Photomosaic surveys cover a area of 3000 m2 and reveal extensive basalt alteration with areas of active diffuse hydrothermal outflow. The spatial extents of orange-colored alteration and white, bacterial mats, taken to indicate active outflow, are quantified using both manual identification and an automated, supervised classification scheme. Both methods find that alteration covers 7-8% and active outflow 1-3% of the survey region. It is unclear if the observed hydrothermal fluids are part of the fluid circulation network of the nearby Kick'em Jenny volcano or if a separate heat source is driving this flow. To test these two endmember cases, we use a 2D, finite-difference, marker-in-cell code to simulate hydrothermal circulation of a single-phase fluid within the oceanic crust. Parameters varied include the permeability structure (e.g., inclusion of a permeability barrier representing the collapse surface), the depth to the heat source beneath Kick'em Jenny, and the bathymetry. We will discuss results from the photomosaic analysis and our initial models.
Numerical Modeling of Multiphase Fluid Flow in Ore-Forming Hydrothermal Systems
NASA Astrophysics Data System (ADS)
Weis, P.; Driesner, T.; Coumou, D.; Heinrich, C. A.
2007-12-01
Two coexisting fluid phases - a variably saline liquid and a vapor phase - are ubiquitous in ore-forming and other hydrothermal systems. Understanding the dynamics of phase separation and the distinct physical and chemical evolution of the two fluids probably plays a key role in generating different ore deposit types, e.g. porphyry type, high and low sulfidation Cu-Mo-Au deposits. To this end, processes within hydrothermal systems have been studied with a refined numerical model describing fluid flow in transient porous media (CSP~5.0). The model is formulated on a mass, energy and momentum conserving finite-element-finite-volume (FEFV) scheme and is capable of simulating multiphase flow of NaCl-H20 fluids. Fluid properties are computed from an improved equation of state (SOWAT~2.0). It covers conditions with temperatures of up to 1000 degrees~C, pressures of up to 500 MPa, and fluid salinities of 0~to 100%~NaCl. In particular, the new set-up allows for a more accurate description of fluid phase separation during boiling of hydrothermal fluids into a vapor and a brine phase. The geometric flexibility of the FEFV-meshes allows for investigations of a large variety of geological settings, ranging from ore-forming processes in magmatic hydrothermal system to the dynamics of black smokers at mid-ocean ridges. Simulations demonstrated that hydrothermal convection patterns above cooling plutons are primarily controlled by the system-scale permeability structure. In porphyry systems, high fluid pressures develop in a stock rising from the magma chamber which can lead to rock failure and, eventually, an increase in permeability due to hydrofracturing. Comparisons of the thermal evolution as inferred from modeling studies with data from fluid inclusion studies of the Pb-Zn deposits of Madan, Bulgaria are in a strikingly good agreement. This indicates that cross-comparisons of field observations, analytical data and numerical simulations will become a powerful tool towards a more thorough understanding of hydrothermal fluid processes. One such attempt will incorporate geometric data of veins in the Bingham porphyry Cu-Mo-Au deposit into our numerical model. The presentation will introduce the numerical model and show examples and first results of the aforementioned applications.
Hydrothermal carbonization: modeling, final properties design and applications: a review
USDA-ARS?s Scientific Manuscript database
Active research on biomass hydrothermal carbonization (HTC) continues to demonstrate its advantages over other thermochemical processes, in particular the interesting benefits associated with carbonaceous solid products called hydrochar (HC). The areas of applications of HC range from biofuel to dop...
NASA Astrophysics Data System (ADS)
Woitischek, Julia; Dietzel, Martin; Inguaggiato, Claudio; Böttcher, Michael E.; Leis, Albrecht; Cruz, J. Virgílio; Gehre, Matthias
2017-10-01
This study focuses on the characterisation and origin of hydrothermal waters discharging from three main active volcanoes (Furnas, Fogo and Sete Cidades) at São Miguel, where 33 water with temperatures ranging between 13 and 97 °C, and 5 precipitate samples were collected. The developed conceptual model for this active hydrothermal system reveals that all waters can be classified by Na-HCO3, Na-Cl and Na-SO4 types and are of meteoric origin. This is confirmed by the stable hydrogen and oxygen isotope data that are positioned close to the local meteoric water line (- 4.1‰ ≤ δ18OH2O ≤ 5.2‰; - 17.6‰ ≤ δDH2O ≤ 20.4‰), except for the Na-Cl type water at Ferraria (Sete Cidades area), which is characterized by admixing of seawater. The stable isotope composition of São Miguel hydrothermal solutions (δ34SSO4 range from 21.3 to - 3.7; δ18OSO4 range between 0.5 and 10.5‰; δ13CTDIC = - 4.5 ± 3.2‰) indicate that waters are individually evolved by several processes: evaporation, uptake of volcanogenic sulphur and carbon dioxide, leaching of local volcanic rocks (driven by high CO2 contents and/or elevated temperature), and biological activity. Latter hydrochemical superimposition is displayed by stromatolitic structures in the precipitates at the given site. Dissolved REE data show similar pattern as local volcanic rocks. In particular the distinct Eu anomaly hints to preferential leaching of locally occurring trachyte. The strongly acidic Na-SO4 waters sampled in boiling pools at Fogo and Furnas Lake indicate high leaching levels and LREE depletion versus HREE compared with the volcanic local rock compositions. Depletion in LREE is most likely caused by its preferential removal compared to HREE by the co-precipitation with alunite.
The potential for prebiotic synthesis in hydrothermal systems. [Abstract only
NASA Technical Reports Server (NTRS)
Ferris, James P.
1994-01-01
Contemporary hydrothermal systems provide a reducing environment where organic compounds are formed and may react to generate the molecules used in the first living systems. The organic compounds percolate through mineral assemblages at a variety of temperatures so the proposed synthetic reactions are driven by heat and catalyzed by minerals (Ferris, 1992). Some examples of potential prebiotic reactions are discussed.
Hydrothermal impacts on trace element and isotope ocean biogeochemistry.
German, C R; Casciotti, K A; Dutay, J-C; Heimbürger, L E; Jenkins, W J; Measures, C I; Mills, R A; Obata, H; Schlitzer, R; Tagliabue, A; Turner, D R; Whitby, H
2016-11-28
Hydrothermal activity occurs in all ocean basins, releasing high concentrations of key trace elements and isotopes (TEIs) into the oceans. Importantly, the calculated rate of entrainment of the entire ocean volume through turbulently mixing buoyant hydrothermal plumes is so vigorous as to be comparable to that of deep-ocean thermohaline circulation. Consequently, biogeochemical processes active within deep-ocean hydrothermal plumes have long been known to have the potential to impact global-scale biogeochemical cycles. More recently, new results from GEOTRACES have revealed that plumes rich in dissolved Fe, an important micronutrient that is limiting to productivity in some areas, are widespread above mid-ocean ridges and extend out into the deep-ocean interior. While Fe is only one element among the full suite of TEIs of interest to GEOTRACES, these preliminary results are important because they illustrate how inputs from seafloor venting might impact the global biogeochemical budgets of many other TEIs. To determine the global impact of seafloor venting, however, requires two key questions to be addressed: (i) What processes are active close to vent sites that regulate the initial high-temperature hydrothermal fluxes for the full suite of TEIs that are dispersed through non-buoyant hydrothermal plumes? (ii) How do those processes vary, globally, in response to changing geologic settings at the seafloor and/or the geochemistry of the overlying ocean water? In this paper, we review key findings from recent work in this realm, highlight a series of key hypotheses arising from that research and propose a series of new GEOTRACES modelling, section and process studies that could be implemented, nationally and internationally, to address these issues.This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'. © 2015 The Authors.
Hydrothermal impacts on trace element and isotope ocean biogeochemistry
Dutay, J.-C.; Heimbürger, L. E.; Jenkins, W. J.; Measures, C. I.; Mills, R. A.; Obata, H.; Turner, D. R.; Whitby, H.
2016-01-01
Hydrothermal activity occurs in all ocean basins, releasing high concentrations of key trace elements and isotopes (TEIs) into the oceans. Importantly, the calculated rate of entrainment of the entire ocean volume through turbulently mixing buoyant hydrothermal plumes is so vigorous as to be comparable to that of deep-ocean thermohaline circulation. Consequently, biogeochemical processes active within deep-ocean hydrothermal plumes have long been known to have the potential to impact global-scale biogeochemical cycles. More recently, new results from GEOTRACES have revealed that plumes rich in dissolved Fe, an important micronutrient that is limiting to productivity in some areas, are widespread above mid-ocean ridges and extend out into the deep-ocean interior. While Fe is only one element among the full suite of TEIs of interest to GEOTRACES, these preliminary results are important because they illustrate how inputs from seafloor venting might impact the global biogeochemical budgets of many other TEIs. To determine the global impact of seafloor venting, however, requires two key questions to be addressed: (i) What processes are active close to vent sites that regulate the initial high-temperature hydrothermal fluxes for the full suite of TEIs that are dispersed through non-buoyant hydrothermal plumes? (ii) How do those processes vary, globally, in response to changing geologic settings at the seafloor and/or the geochemistry of the overlying ocean water? In this paper, we review key findings from recent work in this realm, highlight a series of key hypotheses arising from that research and propose a series of new GEOTRACES modelling, section and process studies that could be implemented, nationally and internationally, to address these issues. This article is part of the themed issue ‘Biological and climatic impacts of ocean trace element chemistry’. PMID:29035265
Ca and Sr Isotope Sytematics in Mid-Ocean Ridge Hydrothermal Fluids
NASA Astrophysics Data System (ADS)
Pester, N. J.; Syverson, D. D.; Higgins, J. A.; Seyfried, W. E., Jr.
2016-12-01
We report a comprehensive suite of Ca isotopic data (δ44/40Ca) from mid-ocean ridge hydrothermal fluids, standardized relative to seawater. Samples were acquired from 7 different vent fields on the EPR, JdFR and MAR during expeditions between 1999 and 2014. All endmember hydrothermal fluids (within analytical uncertainty) reflect an entirely MORB-dominated signal (-1.0 to -1.2 ‰). This rather uniform signal, despite variable fluid chemistries and a mixture of mafic to ultramafic host lithologies, is somewhat surprising given the noteworthy Ca concentrations in both the hydrothermal fluids and precursor seawater. One explanation for this observation involves the change in anhydrite (CaSO4) saturation with increasing temperature, and the molal concentration ratio of [Mg]:[Ca]:[SO4] in modern seawater of 53:10:28. The near quantitative removal of seawater Mg to silicate alteration phases, favorable at all temperatures, is largely charge balanced by exchange for basaltic Ca, and this process alone can account for the majority of the rock dominated δ44/40Casw signal. That these values are equivalent to MORB, however, suggests a high proportion of this Mg-Ca exchange occurs after seawater Ca precipitates as anhydrite in lower temperature (recharge) regimes of the hydrothermal system, aided by the low [Ca]/[SO4]. 87/86Sr ratios of hydrothermal fluids exhibit a seawater signal of 20 to 30% and Sr is therefore not quantitatively removed during incipient anhydrite formation. Strontium mobility in hydrothermal systems is still poorly understood, but the offset between the Ca and Sr isotopic signatures is consistent with near-equilibrium partitioning of Sr into anhydrite observed in recent experiments. Such observations from modern MOR systems place important constraints on the role of hydrothermal fluxes in paleo-seawater evolution, such as feedbacks involving significant variability in [Mg]:[Ca]:[SO4] ratios of seawater suggested over much of the Phanerozoic.
Photo-induced self-cleaning and sterilizing activity of Sm3+ doped ZnO nanomaterials.
Saif, M; Hafez, H; Nabeel, A I
2013-01-01
Highly active samarium doped zinc oxide self-cleaning and biocidal surfaces (x mol% Sm(3+)/ZnO where x=0, 1, 2 and 4 mol%) with crystalline porous structures were synthesized by hydrothermal method. Sm(3+)/ZnO thin films were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive spectroscopic (EDS), UV-visible diffuse reflectance and fluorescence (FL) spectroscopy. The combination between doping and hydrothermal treatments significantly altered the morphology of ZnO into rod and plate-like nanoshapes structure and enhanced its absorption and emission of ultraviolet radiation. The photo-activity in term of quantitative determination of the active oxidative species (()OH) produced on the thin film surfaces was evaluated using fluorescent probe method. The results showed that, the hydrothermally treated 2.0 mol% Sm(3+)/ZnO film (S2) is the highly active one. The optical, structural, morphology and photo-activity properties of the highly active thin film (S2) make it promising surface for self-cleaning and sterilizing applications. Copyright © 2012 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Laiolo, M.; Coppola, D.; Barahona, F.; Benítez, J. E.; Cigolini, C.; Escobar, D.; Funes, R.; Gutierrez, E.; Henriquez, B.; Hernandez, A.; Montalvo, F.; Olmos, R.; Ripepe, M.; Finizola, A.
2017-06-01
On October 1st, 2005, Santa Ana volcano (El Salvador) underwent a VEI 3 phreatomagmatic eruption after approximately one century of rest. Casualties and damages to some of the local infrastructures and surrounding plantations were followed by the evacuation of the nearby communities. The analysis of MODIS (Moderate Resolution Imaging Spectroradiometer) infrared data reveals that the main explosion was preceded by a one-year-long thermal unrest, associated to the development of a fumaroles field, located at the western rim of the summit crater lake. By combining space-based thermal flux and ground-based measurements (seismicity, sulfur emissions and lake temperatures), we suggest that the activity observed at Santa Ana between 2004 and 2005 was driven by the gradual intrusion of an undegassed magma body at a very shallow depth. Magma injection induced thermal anomalies associated with sustained degassing from the fumaroles field and promoted the interaction between the magmatic-hydrothermal system and the overlying water table. This process culminated into the VEI 3 phreatomagmatic eruption of October 2005 that strongly modified the shallow structure of the crater area. The subsequent three-years-long activity resulted from self-sealing of the fracture system and by the opening of a new fracture network directly connecting the deeper hydrothermal system with the crater lake. Our results show that satellite-based thermal data allow us to detect the expansion of the high-temperature fumarolic field. This may precede an explosive eruption and/or a lava dome extrusion. In particular, we show that thermal records can be analyzed with other geochemical (i.e. SO2 emissions) and geophysical (seismicity) data to track a shallow magmatic intrusion interacting with the surrounding hydrothermal system. This provides a remarkable support for volcano monitoring and eruption forecasting, particularly in remote areas where permanent ground data acquisition is hazardous, expensive and difficult.
Ridley, W.I.; Perfit, M.R.; Josnasson, I.R.; Smith, M.F.
1994-01-01
The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85??49???W and 85??55???W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (< 10) conditions following a period of lower-temperature weathering of volcanics within the rift zone. The complex patterns of element enrichment and depletion and strontium isotope variations indicate mixing between pristine seawater and ascending hot fluids to produce a compositional spectrum of fluids. The precipitation of base-metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems. ?? 1994.
Astrobiology, Mars Exploration and Lassen Volcanic National Park
NASA Technical Reports Server (NTRS)
Des Marais, David J.
2015-01-01
The search for evidence of life beyond Earth illustrates how the charters of NASA and the National Park Service share common ground. The mission of NPS is to preserve unimpaired the natural and cultural resources of the National Park System for the enjoyment, education and inspiration of this and future generations. NASA's Astrobiology program seeks to understand the origins, evolution and distribution of life in the universe, and it abides by the principles of planetary stewardship, public outreach, and education. We cannot subject planetary exploration destinations to Earthly biological contamination both for ethical reasons and to preserve their scientific value for astrobiology. We respond to the public's interest in the mysteries of life and the cosmos by honoring their desire to participate in the process of discovery. We involve youth in order to motivate career choices in science and technology and to perpetuate space exploration. The search for evidence of past life on Mars illustrates how the missions of NASA and NPS can become synergistic. Volcanic activity occurs on all rocky planets in our Solar System and beyond, and it frequently interacts with water to create hydrothermal systems. On Earth these systems are oases for microbial life. The Mars Exploration Rover Spirit has found evidence of extinct hydrothermal system in Gusev crater, Mars. Lassen Volcanic National Park provides a pristine laboratory for investigating how microorganisms can both thrive and leave evidence of their former presence in hydrothermal systems. NASA scientists, NPS interpretation personnel and teachers can collaborate on field-oriented programs that enhance Mars mission planning, engage students and the public in science and technology, and emphasize the ethics of responsible exploration.
Calibrated Hydrothermal Parameters, Barrow, Alaska, 2013
Atchley, Adam; Painter, Scott; Harp, Dylan; Coon, Ethan; Wilson, Cathy; Liljedahl, Anna; Romanovsky, Vladimir
2015-01-29
A model-observation-experiment process (ModEx) is used to generate three 1D models of characteristic micro-topographical land-formations, which are capable of simulating present active thaw layer (ALT) from current climate conditions. Each column was used in a coupled calibration to identify moss, peat and mineral soil hydrothermal properties to be used in up-scaled simulations. Observational soil temperature data from a tundra site located near Barrow, AK (Area C) is used to calibrate thermal properties of moss, peat, and sandy loam soil to be used in the multiphysics Advanced Terrestrial Simulator (ATS) models. Simulation results are a list of calibrated hydrothermal parameters for moss, peat, and mineral soil hydrothermal parameters.
Zhou, Yan; Schideman, Lance; Zheng, Mingxia; Martin-Ryals, Ana; Li, Peng; Tommaso, Giovana; Zhang, Yuanhui
2015-01-01
Hydrothermal liquefaction (HTL) is a promising process for converting wet biomass and organic wastes into bio-crude oil. It also produces an aqueous product referred to as post-hydrothermal liquefaction wastewater (PHWW) containing up to 40% of the original feedstock carbon, which reduces the overall energy efficiency of the HTL process. This study investigated the feasibility of using anaerobic digestion (AD) to treat PHWW, with the aid of activated carbon. Results showed that successful AD occurred at relatively low concentrations of PHWW (≤ 6.7%), producing a biogas yield of 0.5 ml/mg CODremoved, and ∼53% energy recovery efficiency. Higher concentrations of PHWW (≥13.3%) had an inhibitory effect on the AD process, as indicated by delayed, slower, or no biogas production. Activated carbon was shown to effectively mitigate this inhibitory effect by enhancing biogas production and allowing digestion to proceed at higher PHWW concentrations (up to 33.3%), likely due to sequestering toxic organic compounds. The addition of activated carbon also increased the net energy recovery efficiency of AD with a relatively high concentration of PHWW (33.3%), taking into account the energy for producing activated carbon. These results suggest that AD is a feasible approach to treat PHWW, and to improve the energy efficiency of the HTL processes.
Emergence of Habitable Environments in Icy World Interiors
NASA Astrophysics Data System (ADS)
Neveu, Marc
2016-07-01
Finding habitable worlds is a key driver of solar system exploration. Many solar system missions seek environments providing liquid water, energy, and nutrients, the three ingredients necessary to sustain life [1]. Such environments include hydrothermal systems, spatially confined systems where hot aqueous fluid circulates through rock by convection. Hydrothermal activity may be widespread in the solar system. Most solar system worlds larger than 200 km in radius are icy moons and dwarf planets, likely composed of an icy, cometary mantle surrounding a rocky, chondritic core [2]. By improving an icy world evolution code [3] to include the effects of core fracturing and hydrothermal circulation, I show that several icy moons and dwarf planets likely have undergone extensive water-rock interaction [4,5]. This supports observations of aqueous products on their surfaces [6,7]. I simulated the alteration of chondritic rock [8] by pure water or fluid of cometary composition [9] to show that aqueous alteration feeds back on geophysical evolution: it modifies the fluid antifreeze content, affecting its persistence over geological timescales; and the distribution of radionuclides, whose decay is a chief heat source on dwarf planets [10]. Hydrothermal circulation also efficiently transports heat from the core into the ocean, thereby increasing ocean persistence [4]. Thus, these coupled geophysical-geochemical models provide a comprehensive picture of icy world evolution and the emergence of liquid environments in chemical disequilibrium with underlying rock in their interiors. Habitable settings also require a suitable supply of bioessential elements; but what constitutes "suitable"? I sought to quantify the bulk elemental composition of hydrothermal microbial communities, collected in hot spring sediments and mats at Yellowstone National Park, USA. To do so, one must minimize the contribution of non-biological material to the samples analyzed. This was achieved using a separation method that takes advantage of the density contrast between cells and sediment and preserves cellular elemental contents [11]. Using this method, I showed that in spite of the tremendous physical, chemical, and taxonomic diversity of Yellowstone hot springs, the composition of microorganisms there is surprisingly ordinary [12]. This suggests the existence of a stoichiometric envelope common to all life as we know it. Thus, future planetary investigations could use elemental fingerprints to assess the astrobiological potential of hydrothermal settings beyond Earth. References: [1] US National Research Council (2011)Vision & Voyages in the Decade 2013-2022. [2] Hussmann et al. (2006) Icarus 185, 258-273. [3] Desch et al. (2009) Icarus 202, 694-714. [4] Neveu et al. (2015) JGR 120, 123-154. [5] Neveu & Rhoden, in prep. [6] De Sanctis et al. (2015) Nature 528, 241-244. [7] Hsu et al. (2015) Nature 519, 207-210. [8] Wasson & Kallemeyn (1988) Phil Trans R Soc London A 325, 535-544. [9] Mumma & Charnley (2011) Annu Rev Astron Astrophys 49, 471. [10] Neveu et al., in revision. [11] Neveu et al. (2014) Limn Oceanogr 12, 519-529. [12] Neveu et al. (2016) Geobiology 14, 33-53.
NASA Astrophysics Data System (ADS)
Alam, M.
2010-12-01
The San José and Tupungatito volcanoes, located near Santiago (Chile), are the potential hazards, given their geological and historical record of explosive eruptions with pyroclastic flows, most recently in 1960 and 1987 respectively (Global Volcanism Program, Smithsonian Institution). What aggravates the potential risk of these very high (>5290m elevation) snow- and ice-covered volcanoes is their location at the source of relatively narrow mountain drainage systems that feed into the Maipo River, flowing through the southern outskirts of Santiago. Sector-collapse and debris-flow, as a result of volcano-ice/snow interaction, can form lahars causing immense destruction to the life and property in the Maipo Valley (Cajón del Maipo). These lahars can cause submergence and burial of vast downstream areas under several meters thick sediment, as in the case of 1980 eruption of Mount St. Helens, USA. In the event of a major eruption, Santiago city will be at peril, with all the drinking water supply installations either destroyed or contaminated to the extent of being abandoned. Besides, ash and tephra will halt the air traffic in the region, particularly in Santiago-Mendoza sector between Chile and Argentina. In a proposed research project (for which funding is awaited from CONICYT, Chile under its Initiation into Research Funding Competition), hydrothermal systems associated with the aforementioned volcanoes will be periodically studied to monitor these volcanoes, in order to develop a Systematics for using the peripheral hydrothermal manifestations, together with nearby surface water bodies, as means for monitoring the activities of the volcano(es). Basic premise of this proposal is to use the relationship between volcanic and hydrothermal activities. Although this association has been observed at many volcanic centers, no attempt has been made to use this relation effectively as a tool for monitoring the volcanoes. Before an eruption or even with increased solfataric activities, the geochemical signatures of the peripheral hydrothermal systems and nearby surface water bodies change significantly. These geochemical changes can be correlated and verified with the observed volcanic activities. Ground deformation of the volcanoes will be studied through Synthetic Aperture Radar (SAR) Interferometry (InSAR), while thermal infrared remote sensing will be used for monitoring thermal anomalies. The reason for choosing these remote methods over the conventional ground based on-site monitoring, is the difficulty in accessing the aforementioned volcanic centers and risk involved in carrying such instruments for frequent observations, as required for the proposed work. In fact, the idea of developing such a Systematics is because of the risk involved in ground based monitoring of these volcanoes. However, microgravity study, which is relatively easier and safer, will be done to validate the results of the remote sensing studies. The expected outcome of the proposed work will not only help in the mitigation of potential hazard of the aforementioned volcanoes, which are currently unmonitored for the reasons mentioned earlier; but will also serve as a model for monitoring remote and largely ‘inaccessible’ volcanoes elsewhere.
Phenols in hydrothermal petroleums and sediment bitumen from Guaymas Basin, Gulf of California
NASA Technical Reports Server (NTRS)
Simoneit, B. R.; Leif, R. N.; Ishiwatari, R.
1996-01-01
The aliphatic, aromatic and polar (NSO) fractions of seabed petroleums and sediment bitumen extracts from the Guaymas Basin hydrothermal system have been analyzed by gas chromatography and gas chromatography-mass spectrometry (free and silylated). The oils were collected from the interiors and exteriors of high temperature hydrothermal vents and represent hydrothermal pyrolyzates that have migrated to the seafloor by hydrothermal fluid circulation. The downcore sediments are representative of both thermally unaltered and thermally altered sediments. The survey has revealed the presence of oxygenated compounds in samples with a high degree of thermal maturity. Phenols are one class of oxygenated compounds found in these samples. A group of methyl-, dimethyl- and trimethyl-isoprenoidyl phenols (C27-C29) is present in all of the seabed NSO fractions, with the methyl- and dimethyl-isoprenoidyl phenols occurring as major components, and a trimethyl-isoprenoidyl phenol as a minor component. A homologous series of n-alkylphenols (C13-C33) has also been found in the seabed petroleums. These phenols are most likely derived from the hydrothermal alteration of sedimentary organic matter. The n-alkylphenols are probably synthesized under hydrothermal conditions, but the isoprenoidyl phenols are probably hydrothermal alteration products of natural product precursors. The suites of phenols do not appear to be useful tracers of high temperature hydrothermal processes.
Distribution of Hydrothermal Activity at the Lau ISS: Possible Controlling Parameters
NASA Astrophysics Data System (ADS)
Martinez, F.; Baker, E. T.; Resing, J. A.; Edwards, M. H.; Walker, S. L.; Buck, N.
2008-12-01
Seismic tomographic studies of intermediate to fast spreading rate mid-ocean ridges (MORs) interpret zones of rapid crustal cooling a few (3-4) km off axis surrounding the axial seismic low velocity zone (LVZ). These zones of rapid cooling also broadly correlate with the initiation and growth of large abyssal hill faults. The close association of both high thermal gradients and development of fault permeability at crustal scales suggests the hypothesis that these areas may be favorable locations for off-axis high temperature hydrothermal activity. In March-May 2008 on R/V Kilo Moana we conducted a near-bottom sidescan sonar and oceanographic survey along the Eastern Lau Spreading Center (ELSC) and Valu Fa Ridge (VFR) in the Lau back-arc basin to map the distribution of hydrothermal activity within this region. The survey utilized the deep-towed DSL120A (IMI120) sonar, an array of miniature autonomous plume recorders (MAPRs) attached to the tow cable and tethered beneath the sonar's depressor weight, an in situ chemical scanner (VISA) and 23 CTD hydrocasts (see Baker et al., this session). At the ELSC the survey spanned ~100 x 10 km area encompassing the ABE, Tow Cam and Kilo Moana vent fields with ~ 1 km spaced lines overall and ~500 m spaced lines in the area of the ABE vent field. On the VFR the survey spanned a distance of ~100 km along axis by ~5 km across axis with 700 m spaced lines encompassing the Vai Lili, Mariner and Tui Malila vent sites. Initial results identified particle plumes, indicative of high temperature venting, only within about a km of the ridge axis at the ELSC and VFR with possible diffuse venting indicated by MAPR oxidation-reduction potential (ORP) measurements at flank sites at VFR. The expanded sonar coverage better defines the volcano-tectonic context of the hydrothermal signals and previously mapped vent sites. Initial results suggest, however, no high-T venting more than about 1 km from the ridge axis, an apparently negative test of the above hypothesis. This may suggest that hydrothermal fluids are efficiently channeled to the axis even if cooling off-axis crustal regions. Alternatively, at the back-arc VFR/ELSC subduction controls on magmatic productivity may play an important role in modifying the usual relationships observed at MORs among spreading rate, seismic low velocity zone width, faulting, sedimentation and hydrothermal activity. For example, the fast spreading ELSC is magmatically deficient for its spreading rate, forms a deep faulted axial floor and has no continuous axial magma lens seismic reflector. This may lead to a narrower LVZ at the ELSC relative to MORs spreading at the same rate. At the intermediate rate and arc- proximal VFR excess magmatic productivity and volatile-rich volcanics form a peaked shallow axis, few flanking faults and a sediment drape of volcaniclastics from the ridge axis (and nearby arc volcanoes). These effects may act to suppress fault-related permeability on ridge flanks or may rapidly blanket ridge-flanking hydrothermal systems. Some of these issues may be further clarified when planned seismic tomographic and moored hydrophone studies are carried out beginning next year at the ELSC/VFR.
Hydrothermal systems and volcano geochemistry
Fournier, R.O.
2007-01-01
The upward intrusion of magma from deeper to shallower levels beneath volcanoes obviously plays an important role in their surface deformation. This chapter will examine less obvious roles that hydrothermal processes might play in volcanic deformation. Emphasis will be placed on the effect that the transition from brittle to plastic behavior of rocks is likely to have on magma degassing and hydrothermal processes, and on the likely chemical variations in brine and gas compositions that occur as a result of movement of aqueous-rich fluids from plastic into brittle rock at different depths. To a great extent, the model of hydrothermal processes in sub-volcanic systems that is presented here is inferential, based in part on information obtained from deep drilling for geothermal resources, and in part on the study of ore deposits that are thought to have formed in volcanic and shallow plutonic environments.
Availability of Heat to Drive Hydrothermal Systems in Large Martian Impact Craters
NASA Technical Reports Server (NTRS)
Thorsos, I. E.; Newsom, H. E.; Davies, A. G.
2001-01-01
The central uplift in large craters on Mars can provide a substantial source of heat, equivalent to heat produced by the impact melt sheet. The heat generated in large impacts could play a significant role in hydrothermal systems on Mars. Additional information is contained in the original extended abstract.
Numerical simulation of magmatic hydrothermal systems
Ingebritsen, S.E.; Geiger, S.; Hurwitz, S.; Driesner, T.
2010-01-01
The dynamic behavior of magmatic hydrothermal systems entails coupled and nonlinear multiphase flow, heat and solute transport, and deformation in highly heterogeneous media. Thus, quantitative analysis of these systems depends mainly on numerical solution of coupled partial differential equations and complementary equations of state (EOS). The past 2 decades have seen steady growth of computational power and the development of numerical models that have eliminated or minimized the need for various simplifying assumptions. Considerable heuristic insight has been gained from process-oriented numerical modeling. Recent modeling efforts employing relatively complete EOS and accurate transport calculations have revealed dynamic behavior that was damped by linearized, less accurate models, including fluid property control of hydrothermal plume temperatures and three-dimensional geometries. Other recent modeling results have further elucidated the controlling role of permeability structure and revealed the potential for significant hydrothermally driven deformation. Key areas for future reSearch include incorporation of accurate EOS for the complete H2O-NaCl-CO2 system, more realistic treatment of material heterogeneity in space and time, realistic description of large-scale relative permeability behavior, and intercode benchmarking comparisons. Copyright 2010 by the American Geophysical Union.
Peacock, Jared R.; Mangan, Margaret T.; McPhee, Darcy K.; Wannamaker, Phil E.
2016-01-01
Though shallow flow of hydrothermal fluids in Long Valley Caldera, California, has been well studied, neither the hydrothermal source reservoir nor heat source has been well characterized. Here a grid of magnetotelluric data were collected around the Long Valley volcanic system and modeled in 3-D. The preferred electrical resistivity model suggests that the source reservoir is a narrow east-west elongated body 4 km below the west moat. The heat source could be a zone of 2–5% partial melt 8 km below Deer Mountain. Additionally, a collection of hypersaline fluids, not connected to the shallow hydrothermal system, is found 3 km below the medial graben, which could originate from a zone of 5–10% partial melt 8 km below the south moat. Below Mammoth Mountain is a 3 km thick isolated body containing fluids and gases originating from an 8 km deep zone of 5–10% basaltic partial melt.
The energetics of organic synthesis inside and outside the cell
Amend, Jan P.; LaRowe, Douglas E.; McCollom, Thomas M.; Shock, Everett L.
2013-01-01
Thermodynamic modelling of organic synthesis has largely been focused on deep-sea hydrothermal systems. When seawater mixes with hydrothermal fluids, redox gradients are established that serve as potential energy sources for the formation of organic compounds and biomolecules from inorganic starting materials. This energetic drive, which varies substantially depending on the type of host rock, is present and available both for abiotic (outside the cell) and biotic (inside the cell) processes. Here, we review and interpret a library of theoretical studies that target organic synthesis energetics. The biogeochemical scenarios evaluated include those in present-day hydrothermal systems and in putative early Earth environments. It is consistently and repeatedly shown in these studies that the formation of relatively simple organic compounds and biomolecules can be energy-yielding (exergonic) at conditions that occur in hydrothermal systems. Expanding on our ability to calculate biomass synthesis energetics, we also present here a new approach for estimating the energetics of polymerization reactions, specifically those associated with polypeptide formation from the requisite amino acids. PMID:23754809
NASA Astrophysics Data System (ADS)
Rubin, Ken
1997-09-01
Recently, it has been reported that the element polonium degasses from mid-ocean ridge and seamount volcanoes during eruptions. Published and new observations on other volatile metal and metalloid elements can also be interpreted as indicating significant degassing of magmatic vapors during submarine eruptions. This process potentially plays an important role in the net transfer of chemical elements from erupting volcanoes to seawater in addition to that arising from sea floor hydrothermal systems. In this paper, a framework is constructed for predicting and assessing semiquantitatively the potential magnitude and chemical fingerprints in the water column of metal and metalloid degassing using (1) predictions from a summary of element volatilities during mafic subaerial volcanism worldwide and (2) limited data from submarine volcanic effusives. The latter include analyses of polonium and trace metals in near-volcano water masses sampled following a submarine eruption at Loihi seamount, Hawaii (1000 m bsl) in 1996. The element volatility predictions and observations show good agreement, considering the limited dataset. Some of the highest volatility main group and transition element enrichments in seawater over Loihi are predicted by the degassing mass transfer model I present. When expanded to cover all submarine volcanic activity, it is predicted that exit fluxes of these elements are up to 10 2-10 3 greater by degassing than by normal MOR hydrothermalism. In contrast, MOR exit fluxes of low volatility alkali and alkaline earth elements are likely 10 2-10 6 greater from hydrothermal inputs. Degassing inputs to the ocean are probably highly episodic, occurring almost entirely during eruptions; these are times of enhanced and abnormal hydrothermalism as well. Although major hydrothermal and degassing events may not be chemically recognizable in real water masses as wholly distinct entities, it is nevertheless possible to predict to what extent each process flavors the effluents of the other. Degassing at mid-ocean ridges may explain a variety of observations previously ascribed to complexities occurring during hydrothermal venting and/or fluid ascent in the buoyant hydrothermal plumes above ridges.
Structural controls on the emission of magmatic carbon dioxide gas, Long Valley Caldera, USA
NASA Astrophysics Data System (ADS)
Lucic, Gregor; Stix, John; Wing, Boswell
2015-04-01
We present a degassing study of Long Valley Caldera that explores the structural controls upon emissions of magmatic carbon dioxide gas. A total of 223 soil gas samples were collected and analyzed for stable carbon isotopes using a field-portable cavity ring-down spectrometer. This novel technique is flexible, accurate, and provides sampling feedback on a daily basis. Sampling sites included major and minor volcanic centers, regional throughgoing faults, caldera-related structures, zones of elevated seismicity, and zones of past and present hydrothermal activity. The classification of soil gases based on their δ13C and CO2 values reveals a mixing relationship among three end-members: atmospheric, biogenic, and magmatic. Signatures dominated by biogenic contributions (~4 vol %, -24‰) are found on the caldera floor, the interior of the resurgent dome, and areas associated with the Hilton Creek and Hartley Springs fault systems. With the introduction of the magmatic component (~100 vol %, -4.5‰), samples acquire mixing and hydrothermal signatures and are spatially associated with the central caldera and Mammoth Mountain. In particular, they are concentrated along the southern margin of the resurgent dome where the interplay between resurgence-related reverse faulting and a bend in the regional fault system has created a highly permeable fracture network, suitable for the formation of shallow hydrothermal systems. This contrasts with the south moat, where despite elevated seismicity, a thick sedimentary cover has formed an impermeable cap, inhibiting the ascent of fluids and gases to the surface.
Heat flow in relation to hydrothermal activity in the southern Black Rock Desert, Nevada
DOE Office of Scientific and Technical Information (OSTI.GOV)
Sass, J.H.; Zoback, M.L.; Galanis, S.P. Jr.
1979-01-01
As part of an investigation of the Gerlach NE KGRA (Known Geothermal Resource Area) a number of heat-flow measurements were made in playa sediments of the southern Black Rock Desert, northwestern Nevada. These data together with additional previously unpublished heat-flow values reveal a complex pattern of heat flow with values ranging between 1.0 to 5.0 HFU (40 to 100 mWm/sup -2/) outside of the hot springs area. The mean heat flow for the 13 reported sites in the southern Black Rock Desert is 1.8 +- 0.15 HFU (75 +- 6 mWm/sup -2/). The complexity of the pattern of heat flowmore » is believed to arise from hydrothermal circulation supporting the numerous hot springs throughout the region. The fact that the lowest observed heat flow occurs in the deepest part of the basin strongly suggests that fluid movement within the basin represents part of the recharge for the hydrothermal system. A thermal balance for the system incorporating both anomalous conductive heat loss and convective heat loss from the spring systems indicate a total energy loss of about 8.0 Mcal/sec or 34 megawatts over an estimated 1000 km/sup 2/ region. Consideration of this additional heat loss yields a mean regional heat flow of 2.5 + HFU (100 + mWm/sup -2/) and warrants inclusion of this region in the Battle Mountain heat-flow high (Lachenbruch and Sass, 1977, 1978).« less
Hydrothermal signature in the axial-sediments from the Carlsberg Ridge in the northwest Indian Ocean
NASA Astrophysics Data System (ADS)
Yu, Zenghui; Li, Huaiming; Li, Mengxing; Zhai, Shikui
2018-04-01
30 sediments grabbed from 24 sites between the equator and 10°N along the Carlsberg Ridge (CR) in the northwest Indian Ocean has been analyzed for bulk chemical compositions. Hydrothermal components in the sediments are identified and characterized. They mainly occur at 6.3°N as sulfide debris and at 3.6°N as both sulfide and high temperature water-rock interaction products. The enrichment of chalcophile elements such as Zn, Cu, Pb and the depletion of alkalis metals such as K and Rb are the typical features of hydrothermal components. High U/Fe, low (Nd/Yb)N and negative Ce anomaly infer the uptake of seawater in the hydrothermal deposits by oxidizing after deposition. However, the general enrichment of Mn in hydrothermal plumed-derived materials is not found in the sediments, which may indicate the limited diffusion of fluids or plumes, at least in the direction along the Carlsberg spreading center. The hydrothermal components show their similarity to the hydrothermal deposits from the Indian Ocean Ridge. At 3.6°N ultramafic rocks or gabbroic intrusions, may be involved in the hydrothermal system.
Ray, Jessica; Dondrup, Michael; Modha, Sejal; Steen, Ida Helene; Sandaa, Ruth-Anne; Clokie, Martha
2012-01-01
Viruses are ubiquitous in the oceans and critical components of marine microbial communities, regulating nutrient transfer to higher trophic levels or to the dissolved organic pool through lysis of host cells. Hydrothermal vent systems are oases of biological activity in the deep oceans, for which knowledge of biodiversity and its impact on global ocean biogeochemical cycling is still in its infancy. In order to gain biological insight into viral communities present in hydrothermal vent systems, we developed a method based on deep-sequencing of pulsed field gel electrophoretic bands representing key viral fractions present in seawater within and surrounding a hydrothermal plume derived from Loki's Castle vent field at the Arctic Mid-Ocean Ridge. The reduction in virus community complexity afforded by this novel approach enabled the near-complete reconstruction of a lambda-like phage genome from the virus fraction of the plume. Phylogenetic examination of distinct gene regions in this lambdoid phage genome unveiled diversity at loci encoding superinfection exclusion- and integrase-like proteins. This suggests the importance of fine-tuning lyosgenic conversion as a viral survival strategy, and provides insights into the nature of host-virus and virus-virus interactions, within hydrothermal plumes. By reducing the complexity of the viral community through targeted sequencing of prominent dsDNA viral fractions, this method has selectively mimicked virus dominance approaching that hitherto achieved only through culturing, thus enabling bioinformatic analysis to locate a lambdoid viral "needle" within the greater viral community "haystack". Such targeted analyses have great potential for accelerating the extraction of biological knowledge from diverse and poorly understood environmental viral communities.
NASA Astrophysics Data System (ADS)
Jourde, Kevin; Gibert, Dominique; Marteau, Jacques; de Bremond D'Ars, Jean; Komorowski, Jean-Christophe
2016-09-01
Imaging geological structures through cosmic muon radiography is a newly developed technique which shows a great potential in volcanology. Here we demonstrate that muon radiography permits to detect and characterize mass movements in shallow hydrothermal systems of low-energy active volcanoes like the La Soufrière lava dome. We present an experiment conducted on this volcano during the Summer 2014 and bring evidence that very important density changes occurred in three domains of the lava dome. Depending on their position and on the medium porosity the volumes of these domains vary from 1 × 106 m3 to 7 × 106 m3. However, the total mass budget remains approximately constant : two domains show a mass loss (Δm∈ [-0.8-0.4] × 109 kg) and the third one a mass gain (Δm∈ [1.5; 2.5] × 109 kg). We attribute the negative mass changes to the formation of steam in shallow hydrothermal reservoir previously partly filled with liquid water. This coincides with the emergence of new fumaroles on top of the volcano. The positive mass change is synchronized with the negative mass changes indicating that liquid water probably flowed from the two reservoirs invaded by steam toward the third reservoir.
Jourde, Kevin; Gibert, Dominique; Marteau, Jacques; de Bremond d’Ars, Jean; Komorowski, Jean-Christophe
2016-01-01
Imaging geological structures through cosmic muon radiography is a newly developed technique which shows a great potential in volcanology. Here we demonstrate that muon radiography permits to detect and characterize mass movements in shallow hydrothermal systems of low-energy active volcanoes like the La Soufrière lava dome. We present an experiment conducted on this volcano during the Summer 2014 and bring evidence that very important density changes occurred in three domains of the lava dome. Depending on their position and on the medium porosity the volumes of these domains vary from 1 × 106 m3 to 7 × 106 m3. However, the total mass budget remains approximately constant : two domains show a mass loss (Δm∈ [−0.8;−0.4] × 109 kg) and the third one a mass gain (Δm∈ [1.5; 2.5] × 109 kg). We attribute the negative mass changes to the formation of steam in shallow hydrothermal reservoir previously partly filled with liquid water. This coincides with the emergence of new fumaroles on top of the volcano. The positive mass change is synchronized with the negative mass changes indicating that liquid water probably flowed from the two reservoirs invaded by steam toward the third reservoir. PMID:27629497
Jourde, Kevin; Gibert, Dominique; Marteau, Jacques; de Bremond d'Ars, Jean; Komorowski, Jean-Christophe
2016-09-15
Imaging geological structures through cosmic muon radiography is a newly developed technique which shows a great potential in volcanology. Here we demonstrate that muon radiography permits to detect and characterize mass movements in shallow hydrothermal systems of low-energy active volcanoes like the La Soufrière lava dome. We present an experiment conducted on this volcano during the Summer 2014 and bring evidence that very important density changes occurred in three domains of the lava dome. Depending on their position and on the medium porosity the volumes of these domains vary from 1 × 10(6) m(3) to 7 × 10(6) m(3). However, the total mass budget remains approximately constant : two domains show a mass loss (Δm∈ [-0.8;-0.4] × 10(9) kg) and the third one a mass gain (Δm∈ [1.5; 2.5] × 10(9) kg). We attribute the negative mass changes to the formation of steam in shallow hydrothermal reservoir previously partly filled with liquid water. This coincides with the emergence of new fumaroles on top of the volcano. The positive mass change is synchronized with the negative mass changes indicating that liquid water probably flowed from the two reservoirs invaded by steam toward the third reservoir.
NASA Astrophysics Data System (ADS)
Wang, Zhengduo; Zhang, Li; Liu, Zhongwei; Sang, Lijun; Yang, Lizhen; Chen, Qiang
2017-06-01
In this paper, we report the combination of atomic layer deposition (ALD) with hydrothermal techniques to deposit ZnO on electrospun polyamide 6 (PA 6) nanofiber (NF) surface in the purpose of antibacterial application. The micro- and nanostructures of the hierarchical fibers are characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HRTEM), and scanning transmission electron microscopy (STEM). We find that NFs can grow into "water lily"- and "caterpillar"-like shapes, which depend on the number of ALD cycles and the hydrothermal reaction period. It is believed that the thickness of ZnO seed layer by ALD process and the period in hydrothermal reaction have the same importance in crystalline growth and hierarchical fiber formation. The tests of antibacterial activity demonstrate that the ZnO/PA 6 core-shell composite fabricated by the combination of ALD with hydrothermal are markedly efficient in suppressing bacteria survivorship.
Song, Sangho; Kim, Hyun Chan; Kim, Jung Woong; Kim, Debora
2017-01-01
Miniaturized accelerometers are necessary for evaluating the performance of small devices, such as haptics, robotics and simulators. In this study, we fabricated miniaturized accelerometers using well-aligned ZnO nanowires. The layer of ZnO nanowires is used for active piezoelectric layer of the accelerometer, and copper was chosen as a head mass. Seedless and refresh hydrothermal synthesis methods were conducted to grow ZnO nanowires on the copper substrate and the effect of ZnO nanowire length on the accelerometer performance was investigated. The refresh hydrothermal synthesis exhibits longer ZnO nanowires, 12 µm, than the seedless hydrothermal synthesis, 6 µm. Performance of the fabricated accelerometers was verified by comparing with a commercial accelerometer. The sensitivity of the fabricated accelerometer by the refresh hydrothermal synthesis is shown to be 37.7 pA g−1, which is about 30 times larger than the previous result. PMID:28989760
Hydrothermal Vents of Juan de Fuca Ridge
NASA Astrophysics Data System (ADS)
Stark, Joyce
As a member of REVEL (Research and Education: Volcanoes, Exploration and Life), I had an opportunity to participant in a scientific research cruise focused on the active volcanoes along the Juan de Fuca Ridge, the submarine spreading center off the Washington- Oregon-Canada coast. REVEL was sponsored by the National Science Foundation, University of Washington, Pennsylvania State University and the American Museum of Natural History. We studied the geological, chemical and biological processes associated with active hydrothermal systems and my research focused on the biological communities of the sulfide structures. We worked on board the Woods Hole Oceanographic Institution Vessel, R/V Atlantis and the submersible ALVIN was used to sample the "Black Smokers". As a member of the scientific party, I participated in collection and sorting of biological specimens from the vent communities, attended lectures by scientists, contributed to the cruise log website, maintained a journal and developed my own research project. It was my responsibility to bring this cutting-edge research back to the classroom.
NASA Astrophysics Data System (ADS)
Smith, Christopher N.; Kesler, Stephen E.; Blum, Joel D.; Rytuba, James J.
2008-05-01
We present here the first study of the isotopic composition of mercury in rocks, ore deposits, and active spring deposits from the California Coast Ranges, a part of Earth's crust with unusually extensive evidence of mercury mobility and enrichment. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of mercury deposits, hot-spring deposits that form at shallow depths (< 300 m) and silica-carbonate deposits that extend to depths of 1000 m. Active springs and geothermal areas continue to precipitate Hg and Au and are modern analogues to the fossil hydrothermal systems preserved in the ore deposits. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of mercury than volcanic rocks of the Clear Lake Volcanic Field. Mean mercury isotopic compositions ( δ202Hg) for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate mercury deposits have similar average mercury isotopic compositions that are indistinguishable from averages for the three rock units, although δ202Hg values for the mercury deposits have a greater variance than the country rocks. Precipitates from spring and geothermal waters in the area have similarly large variance and a mean δ202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate that there is little or no isotopic fractionation (< ± 0.5‰) during release of mercury from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of mercury in deposits, however, especially in their uppermost parts. Boiling of hydrothermal fluids, separation of a mercury-bearing CO 2 vapor or reduction and volatilization of Hg (0) in the near-surface environment are likely the most important processes causing the observed Hg isotope fractionation. This should result in the release of mercury with low δ202Hg values into the atmosphere from the top of these hydrothermal systems. Estimates of mass balance suggest that residual Hg reservoirs are not measurably enriched in heavy Hg isotopes as a result of this process because only a small amount of Hg (< 4%) leaves actively ore-forming systems.
Smith, C.N.; Kesler, S.E.; Blum, J.D.; Rytuba, J.J.
2008-01-01
We present here the first study of the isotopic composition of mercury in rocks, ore deposits, and active spring deposits from the California Coast Ranges, a part of Earth's crust with unusually extensive evidence of mercury mobility and enrichment. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of mercury deposits, hot-spring deposits that form at shallow depths (< 300??m) and silica-carbonate deposits that extend to depths of 1000??m. Active springs and geothermal areas continue to precipitate Hg and Au and are modern analogues to the fossil hydrothermal systems preserved in the ore deposits. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of mercury than volcanic rocks of the Clear Lake Volcanic Field. Mean mercury isotopic compositions (??202Hg) for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate mercury deposits have similar average mercury isotopic compositions that are indistinguishable from averages for the three rock units, although ??202Hg values for the mercury deposits have a greater variance than the country rocks. Precipitates from spring and geothermal waters in the area have similarly large variance and a mean ??202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate that there is little or no isotopic fractionation (< ?? 0.5???) during release of mercury from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of mercury in deposits, however, especially in their uppermost parts. Boiling of hydrothermal fluids, separation of a mercury-bearing CO2 vapor or reduction and volatilization of Hg(0) in the near-surface environment are likely the most important processes causing the observed Hg isotope fractionation. This should result in the release of mercury with low ??202Hg values into the atmosphere from the top of these hydrothermal systems. Estimates of mass balance suggest that residual Hg reservoirs are not measurably enriched in heavy Hg isotopes as a result of this process because only a small amount of Hg (< 4%) leaves actively ore-forming systems. ?? 2008 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Heuser, G.; Arancibia, G.; Veloso, E. A.; Reich, M.; Morales, H.
2017-12-01
The Fe-Cu paragenetic assemblages at the Cretaceous Dominga IOCG deposit in northern Chile (2082 Mt at 23% Fe, 0.07% Cu) show a spatial and genetic affinity with major structural systems in the district: the Early Structural System (ESS), El Tofo Structural System (ETSS) and Intermediate Structural System (ISS), developed under different tectonic regimes, from transtension (ESS) to transpression (ETSS, ISS). The ESS is a NE-ENE-trending right-lateral strike slip duplex related to the formation of biotite-magnetite mineralization in Fe-rich bands parallel to bedding (stage I), and magnetite-apatite-actinolite-quartz hydrothermal breccia (stage II). The ETSS is a NNE left-lateral fault breccia related to K-feldspar veins and anhydrite-chalcopyrite hydrothermal breccia (stage III). The ISS is a NW-WNW left lateral strike slip duplex composed of calcite veins (stage IV). However, an understanding of fault-driven fluid flow mechanisms and their impact on the studied Fe-Cu deposit is still lacking. We analyzed representative textures from veins and hydrothermal breccias of stages II, III and IV. Microstructural analysis was made in thin/polished sections normal and parallel to the vein wall using optical and scanning electron microscopy techniques. Stage II shows euhedral magnetite with ilmenite lamellae exsolution textures and intergrowths between magnetite and anhedral mosaic quartz. Hydrothermal breccias contain euhedral quartz with double-terminated crystal shapes and concentric growth zoning surrounded by plumose quartz. Stage III exhibits zoned K-feldspar veins, banded plumose quartz veins, and mosaic subhedral anhydrite. Stage IV is characterized by banded veins of plumose and rhombic calcite, and dilational jogs with rhombic calcite. The observed microtextures suggest slow cooling of high temperature Fe-Cu-rich fluid, suspension in aqueous fluid during crystal growth, and boiling. Despite the different tectonic regimes, the paleo-fluids at the Dominga IOCG deposit were emplaced under similar conditions during the main activity of each structural system, i.e., 1) development of veins related to fluid overpressure and 2) episodic boiling triggered by abrupt pressure drop. Acknowledgements: CONICYT Ph.D. Scholarship, Millennium Nucleus for Metal Tracing Along Subduction NC 130065.
Starting Conditions for Hydrothermal Systems Underneath Martian Craters: Hydrocode Modeling
NASA Technical Reports Server (NTRS)
Pierazzo, E.; Artemieva, N. A.; Ivanov, B. A.
2004-01-01
Mars is the most Earth-like of the Solar System s planets, and the first place to look for any sign of present or past extraterrestrial life. Its surface shows many features indicative of the presence of surface and sub-surface water, while impact cratering and volcanism have provided temporary and local surface heat sources throughout Mars geologic history. Impact craters are widely used ubiquitous indicators for the presence of sub-surface water or ice on Mars. In particular, the presence of significant amounts of ground ice or water would cause impact-induced hydrothermal alteration at Martian impact sites. The realization that hydrothermal systems are possible sites for the origin and early evolution of life on Earth has given rise to the hypothesis that hydrothermal systems may have had the same role on Mars. Rough estimates of the heat generated in impact events have been based on scaling relations, or thermal data based on terrestrial impacts on crystalline basements. Preliminary studies also suggest that melt sheets and target uplift are equally important heat sources for the development of a hydrothermal system, while its lifetime depends on the volume and cooling rate of the heat source, as well as the permeability of the host rocks. We present initial results of two-dimensional (2D) and three-dimensional (3D) simulations of impacts on Mars aimed at constraining the initial conditions for modeling the onset and evolution of a hydrothermal system on the red planet. Simulations of the early stages of impact cratering provide an estimate of the amount of shock melting and the pressure-temperature distribution in the target caused by various impacts on the Martian surface. Modeling of the late stage of crater collapse is necessary to characterize the final thermal state of the target, including crater uplift, and distribution of the heated target material (including the melt pool) and hot ejecta around the crater.
NASA Astrophysics Data System (ADS)
Hawkes, Jeffrey A.; Rossel, Pamela E.; Stubbins, Aron; Butterfield, David; Connelly, Douglas P.; Achterberg, Eric P.; Koschinsky, Andrea; Chavagnac, Valérie; Hansen, Christian T.; Bach, Wolfgang; Dittmar, Thorsten
2015-11-01
Oceanic dissolved organic carbon (DOC) is an important carbon pool, similar in magnitude to atmospheric CO2, but the fate of its oldest forms is not well understood. Hot hydrothermal circulation may facilitate the degradation of otherwise un-reactive dissolved organic matter, playing an important role in the long-term global carbon cycle. The oldest, most recalcitrant forms of DOC, which make up most of oceanic DOC, can be recovered by solid-phase extraction. Here we present measurements of solid-phase extractable DOC from samples collected between 2009 and 2013 at seven vent sites in the Atlantic, Pacific and Southern oceans, along with magnesium concentrations, a conservative tracer of water circulation through hydrothermal systems. We find that magnesium and solid-phase extractable DOC concentrations are correlated, suggesting that solid-phase extractable DOC is almost entirely lost from solution through mineralization or deposition during circulation through hydrothermal vents with fluid temperatures of 212-401 °C. In laboratory experiments, where we heated samples to 380 °C for four days, we found a similar removal efficiency. We conclude that thermal degradation alone can account for the loss of solid-phase extractable DOC in natural hydrothermal systems, and that its maximum lifetime is constrained by the timescale of hydrothermal cycling, at about 40 million years.
Hydrothermally Activated Graphene Fiber Fabrics for Textile Electrodes of Supercapacitors.
Li, Zheng; Huang, Tieqi; Gao, Weiwei; Xu, Zhen; Chang, Dan; Zhang, Chunxiao; Gao, Chao
2017-11-28
Carbon textiles are promising electrode materials for wearable energy storage devices owing to their conductive, flexible, and lightweight features. However, there still lacks a perfect choice for high-performance carbon textile electrodes with sufficient electrochemical activity. Graphene fiber fabrics (GFFs) are newly discovered carbon textiles, exhibiting various attractive properties, especially a large variability on the microstructure. Here we report the fabrication of hierarchical GFFs with significantly enlarged specific surface area using a hydrothermal activation strategy. By carefully optimize the activation process, the hydrothermally activated graphene fiber fabrics (HAGFFs) could achieve an areal capacitance of 1060 mF cm -2 in a very thin thickness (150 μm) and the capacitance is easily magnified by overlaying several layers of HAGFFs, even up to a record value of 7398 mF cm -2 . Meanwhile, a good rate capability and a long cycle life are also attained. As compared with other carbon textiles, including the commercial carbon fiber cloths, our HAGFFs present much better capacitive performance. Therefore, the mechanically stable, flexible, conductive, and highly active HAGFFs have provided an option for high-performance textile electrodes.
NASA Astrophysics Data System (ADS)
Kring, D. A.; Schmieder, M.; Tikoo, S.; Riller, U. P.; Simpson, S. L.; Osinski, G.; Cockell, C. S.; Coolen, M.; Gulick, S. P. S.; Morgan, J. V.
2017-12-01
Impact cratering, particularly large basin-size craters with diameters >100 km, have the potential to generate vast subsurface hydrothermal systems. There were dozens of such impacts during the Hadean and early Archean, some of which vaporized seas for brief periods of time, during which the safest niches for early life may have been in those subsurface hydrothermal systems. The Chicxulub crater can serve as a proxy for those events. New IODP-ICDP core recovered by Expedition 364 reveals a high-temperature (>300 degree C) system that may have persisted for more than 100,000 years. Of order 105 to 106 km3 of crust was structurally deformed, melted, and vaporized within about 10 minutes of the impact. The crust had to endure immense strain rates of 104/s to 106/s, up to 12 orders of magnitude greater than those associated with igneous and metamorphic processes. The outcome is a porous, permeable region that is a perfect host for hydrothermal circulation across the entire diameter of the crater to depths up to 5 or 6 km. The target rocks at Chicxulub are composed of an 3 km-thick carbonate platform sequence over a crystalline basement composed of igneous granite, granodiorite, and a few other intrusive components, such as dolerite, and metamorphic assemblages composed, in part, of gneiss and mica schist. Post-impact hydrothermal alteration includes Ca-Na- and K-metasomatism, pervasive hydration to produce layered silicates, and lower-temperature vug-filling zeolites as the system cycled from high temperatures to low temperatures. While the extent of granitic crust on early Earth is still debated and, thus, the direct application of those mineral reactions to the Hadean and early Archean can be debated, the thermal evolution of the system should be applicable to diverse crustal compositions. It is important to point out that pre-impact thermal conditions of Hadean and early Archean crust can affect the size of an impact basin and, in turn, the proportion of that basin that may experience hydrothermal conditions. The Chicxulub crater - as sampled by Expedition 364 - will provide the baseline needed to assess the spatial and temporal extent of Hadean and early Archean hydrothermal systems and their potential as crucibles for pre-biotic chemistry and the early evolution of microbial life.
Molybdenum isotope behaviour in groundwaters and terrestrial hydrothermal systems, Iceland
NASA Astrophysics Data System (ADS)
Neely, Rebecca A.; Gislason, Sigurdur R.; Ólafsson, Magnus; McCoy-West, Alex J.; Pearce, Christopher R.; Burton, Kevin W.
2018-03-01
Molybdenum (Mo) isotopes have proved useful in the reconstruction of paleoredox conditions. Their application generally relies upon a simplified model of ocean inputs in which rivers dominate Mo fluxes to the oceans and hydrothermal fluids are considered to be a minor contribution. To date, however, little attention has been paid to the extent of Mo isotope variation of hydrothermal waters, or to the potential effect of direct groundwater discharge to the oceans. Here we present Mo isotope data for two Icelandic groundwater systems (Mývatn and Þeistareykir) that are both influenced by hydrothermal processes. Relative to NIST 3134 = +0.25‰, the cold (<10 °C) groundwaters (δ98/95MoGROUNDWATER = -0.15‰ to +0.47‰; n = 13) show little, if any, fractionation from the host basalt (δ 98 / 95MoBASALT = +0.16‰ to -0.12‰) and are, on average, lighter than both global and Icelandic rivers. In contrast, waters that are hydrothermally influenced (>10 °C) possess isotopically heavy δ98/95MoHYDROTHERMAL values of +0.25‰ to +2.06‰ (n = 18) with the possibility that the high temperature endmembers are even heavier. Although the mechanisms driving this fractionation remain unresolved, the incongruent dissolution of the host basalt and both the dissolution and precipitation of sulfides are considered. Regardless of the processes driving these variations, the δ98Mo data presented in this study indicate that groundwater and hydrothermal waters have the potential to modify ocean budget calculations.
Functional Metagenomic Investigations of Microbial Communities in a Shallow-Sea Hydrothermal System
Tang, Kai; Liu, Keshao; Jiao, Nianzhi; Zhang, Yao; Chen, Chen-Tung Arthur
2013-01-01
Little is known about the functional capability of microbial communities in shallow-sea hydrothermal systems (water depth of <200 m). This study analyzed two high-throughput pyrosequencing metagenomic datasets from the vent and the surface water in the shallow-sea hydrothermal system offshore NE Taiwan. This system exhibited distinct geochemical parameters. Metagenomic data revealed that the vent and the surface water were predominated by Epsilonproteobacteria (Nautiliales-like organisms) and Gammaproteobacteria ( Thiomicrospira -like organisms), respectively. A significant difference in microbial carbon fixation and sulfur metabolism was found between the vent and the surface water. The chemoautotrophic microorganisms in the vent and in the surface water might possess the reverse tricarboxylic acid cycle and the Calvin−Bassham−Benson cycle for carbon fixation in response to carbon dioxide highly enriched in the environment, which is possibly fueled by geochemical energy with sulfur and hydrogen. Comparative analyses of metagenomes showed that the shallow-sea metagenomes contained some genes similar to those present in other extreme environments. This study may serve as a basis for deeply understanding the genetic network and functional capability of the microbial members of shallow-sea hydrothermal systems. PMID:23940820
Experimentally Testing Hydrothermal Vent Origin of Life on Enceladus and Other Icy/Ocean Worlds.
Barge, Laura M; White, Lauren M
2017-09-01
We review various laboratory strategies and methods that can be utilized to simulate prebiotic processes and origin of life in hydrothermal vent systems on icy/ocean worlds. Crucial steps that could be simulated in the laboratory include simulations of water-rock chemistry (e.g., serpentinization) to produce hydrothermal fluids, the types of mineral catalysts and energy gradients produced in vent interfaces where hydrothermal fluids interface with the surrounding seawater, and simulations of biologically relevant chemistry in flow-through gradient systems (i.e., far-from-equilibrium experiments). We describe some examples of experimental designs in detail, which are adaptable and could be used to test particular hypotheses about ocean world energetics or mineral/organic chemistry. Enceladus among the ocean worlds provides an ideal test case, since the pressure at the ocean floor is more easily simulated in the lab. Results for Enceladus could be extrapolated with further experiments and modeling to understand other ocean worlds. Key Words: Enceladus-Ocean worlds-Icy worlds-Hydrothermal vent-Iron sulfide-Gradient. Astrobiology 17, 820-833.
Hydrothermal contamination of public supply wells in Napa and Sonoma Valleys, California
Forrest, Matthew J.; Kulongoski, Justin T.; Edwards, Matthew S.; Farrar, Christopher D.; Belitz, Kenneth; Norris, Richard D.
2013-01-01
Groundwater chemistry and isotope data from 44 public supply wells in the Napa and Sonoma Valleys, California were determined to investigate mixing of relatively shallow groundwater with deeper hydrothermal fluids. Multivariate analyses including Cluster Analyses, Multidimensional Scaling (MDS), Principal Components Analyses (PCA), Analysis of Similarities (ANOSIM), and Similarity Percentage Analyses (SIMPER) were used to elucidate constituent distribution patterns, determine which constituents are significantly associated with these hydrothermal systems, and investigate hydrothermal contamination of local groundwater used for drinking water. Multivariate statistical analyses were essential to this study because traditional methods, such as mixing tests involving single species (e.g. Cl or SiO2) were incapable of quantifying component proportions due to mixing of multiple water types. Based on these analyses, water samples collected from the wells were broadly classified as fresh groundwater, saline waters, hydrothermal fluids, or mixed hydrothermal fluids/meteoric water wells. The Multivariate Mixing and Mass-balance (M3) model was applied in order to determine the proportion of hydrothermal fluids, saline water, and fresh groundwater in each sample. Major ions, isotopes, and physical parameters of the waters were used to characterize the hydrothermal fluids as Na–Cl type, with significant enrichment in the trace elements As, B, F and Li. Five of the wells from this study were classified as hydrothermal, 28 as fresh groundwater, two as saline water, and nine as mixed hydrothermal fluids/meteoric water wells. The M3 mixing-model results indicated that the nine mixed wells contained between 14% and 30% hydrothermal fluids. Further, the chemical analyses show that several of these mixed-water wells have concentrations of As, F and B that exceed drinking-water standards or notification levels due to contamination by hydrothermal fluids.
NASA Astrophysics Data System (ADS)
Yamasaki, T.; Takaya, Y.; Mukae, N.; Nagase, T.; Tindell, T.; Totsuka, S.; Uno, Y.; Yonezu, K.; Nozaki, T.; Ishibashi, J. I.; Kumagai, H.; Maeda, L.; Shipboard Scientist, C.
2016-12-01
The Okinawa Trough (OT) is a young and actively spreading back-arc basin, extending behind the Ryukyu arc-trench system in the southeastern margin of the East China Sea. The OT is believed to be in an initial rifting stage (starting from 6-9 Ma), prior to the normal/stable seafloor spreading which constitutes the main stage of back-arc basin formation. Two drilling cruises ‒ the IODP Exp. 331 and SIP CK14-04 D/V Chikyu Cruise (Exp. 907) in 2010 and 2014 ‒ were conducted at the Iheya North Knoll, middle OT. The Iheya North Knoll is a domal volcanic complex consisting of small volcanic bodies. On these cruises, pumiceous gravel and altered rhyolitic rocks, as well as hemi-pelagic sediments, hydrothermal clay and Kuroko-type ores, were recovered from the upper 200 m of the crust. From Feb. 11, 2016 to Mar. 17, 2016, the SIP CK16-01 (Exp. 908) D/V Chikyu cruise was conducted at Iheya North Knoll and the sediment-covered rifting center of the Iheya-Minor Ridge area, middle OT. The Iheya-Minor ridge area is also an active hydrothermal field, located 25 km southeast of the Iheya North Knoll. In this area, basaltic rocks are widely distributed, and drilling has confirmed that the basaltic materials continue to 120 m below the seafloor. From an igneous petrological point of view, the volcanic rocks in the Okinawa Trough are characterized by bimodal basaltic and rhyolitic compositions, with a compositional gap between SiO2 = 56-66 wt%. The origin of the rhyolitic rock has been interpreted as magmatic differentiation of basaltic magma. However, the existence of an active basalt-hosted hydrothermal field in the Iheya-Minor ridge area suggests the presence of hot basaltic rocks at a shallow position in the crust, and reaching recharged seawater at this depth. Furthermore, the composition of felsic rocks just after the compositional gap (SiO2 = 67 wt%) is very similar to that of the minimum melt of a granitic system, and experimental partial melt of hydrous basalt. Therefore, the contrast in the uppermost crustal composition between very close ( 25 km) areas can reasonably be explained by re-melting of hydrothermally-altered basaltic rocks and production of felsic magma at the upper crustal level, and direct eruption of basaltic magma at the seafloor.