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  1. ACTUAL-WASTE TESTS OF ENHANCED CHEMICAL CLEANING FOR RETRIEVAL OF SRS HLW SLUDGE TANK HEELS AND DECOMPOSITION OF OXALIC ACID

    SciTech Connect

    Martino, C.; King, W.; Ketusky, E.

    2012-01-12

    Savannah River National Laboratory conducted a series of tests on the Enhanced Chemical Cleaning (ECC) process using actual Savannah River Site waste material from Tanks 5F and 12H. Testing involved sludge dissolution with 2 wt% oxalic acid, the decomposition of the oxalates by ozonolysis (with and without the aid of ultraviolet light), the evaporation of water from the product, and tracking the concentrations of key components throughout the process. During ECC actual waste testing, the process was successful in decomposing oxalate to below the target levels without causing substantial physical or chemical changes in the product sludge.

  2. Actual-Waste Tests of Enhanced Chemical Cleaning for Retrieval of SRS HLW Sludge Tank Heels and Decomposition of Oxalic Acid - 12256

    SciTech Connect

    Martino, Christopher J.; King, William D.; Ketusky, Edward T.

    2012-07-01

    Savannah River National Laboratory conducted a series of tests on the Enhanced Chemical Cleaning (ECC) process using actual Savannah River Site waste material from Tanks 5F and 12H. Testing involved sludge dissolution with 2 wt% oxalic acid, the decomposition of the oxalates by ozonolysis (with and without the aid of ultraviolet light), the evaporation of water from the product, and tracking the concentrations of key components throughout the process. During ECC actual waste testing, the process was successful in decomposing oxalate to below the target levels without causing substantial physical or chemical changes in the product sludge. During ECC actual waste testing, the introduction of ozone was successful in decomposing oxalate to below the target levels. This testing did not identify physical or chemical changes in the ECC product sludge that would impact downstream processing. The results from these tests confirm observations made by AREVA NP during larger scale testing with waste simulants. This testing, however, had a decreased utilization of ozone, requiring approximately 5 moles of ozone per mole of oxalate decomposed. Decomposition of oxalates in sludge dissolved in 2 wt% OA to levels near 100 ppm oxalate using ECC process conditions required 8 to 12.5 hours without the aid of UV light and 4.5 to 8 hours with the aid of UV light. The pH and ORP were tracked during decomposition testing. Sludge components were tracked during OA decomposition, showing that most components have the highest soluble levels in the initial dissolved sludge and early decomposition samples and exhibit lower soluble levels as OA decomposition progresses. The Deposition Tank storage conditions that included pH adjustment to approximately 1 M free hydroxide tended to bring the soluble concentrations in the ECC product to nearly the same level for each test regardless of storage time, storage temperature, and contact with other tank sludge material. (authors)

  3. Comparison of simulants to actual neutralized current acid waste: process and product testing of three NCAW core samples from Tanks 101-AZ and 102-AZ

    SciTech Connect

    Morrey, E.V.; Tingey, J.M.; Elliott, M.L.

    1996-10-01

    A vitrification plant is planned to process the high-level waste (HLW) solids from Hanford Site tanks into canistered glass logs for disposal in a national repository. Programs were established within the Pacific Northwest Laboratory Vitrification Technology Development (PVTD) Project to test and model simulated waste to support design, feed processability, operations, permitting, safety, and waste-form qualification. Parallel testing with actual radioactive waste was performed on a laboratory-scale to confirm the validity of using simulants and glass property models developed from simulants. Laboratory-scale testing has been completed on three radioactive core samples from tanks 101-AZ and 102-AZ containing neutralized current acid waste (NCAW), which is one of the first waste types to be processed in the high-level waste vitrification plant under a privatization scenario. Properties of the radioactive waste measured during process and product testing were compared to simulant properties and model predictions to confirm the validity of simulant and glass property ,models work. This report includes results from the three NCAW core samples, comparable results from slurry and glass simulants, and comparisons to glass property model predictions.

  4. Comparison of simulants to actual neutralized current acid waste: Process and product testing of three NCAW core samples from Tanks 101-AZ and 102-AZ

    SciTech Connect

    Morrey, E.V.; Tingey, J.M.

    1996-04-01

    A vitrification plant is planned to process the high-level waste (HLW) solids from Hanford Site tanks into canistered glass logs for disposal in a national repository. Programs have been established within the Pacific Northwest Laboratory Vitrification Technology Development (PVTD) Project to test and model simulated waste to support design, feed processability, operations, permitting, safety, and waste-form qualification. Parallel testing with actual radioactive waste is being performed on a laboratory-scale to confirm the validity of using simulants and glass property models developed from simulants. Laboratory-scale testing has been completed on three radioactive core samples from tanks 101-AZ and 102-AZ containing neutralized current acid waste (NCAW), which is one of the first waste types to be processed in the high-level waste vitrification plant under a privatization scenario. Properties of the radioactive waste measured during process and product testing were compared to simulant properties and model predictions to confirm the validity of simulant and glass property models work. This report includes results from the three NCAW core samples, comparable results from slurry and glass simulants, and comparisons to glass property model predictions.

  5. FRACTIONAL CRYSTALLIZATION FLOWSHEET TESTS WITH ACTUAL TANK WASTE

    SciTech Connect

    HERTING, D.L.

    2007-04-13

    Laboratory-scale flowsheet tests of the fractional crystallization process were conducted with actual tank waste samples in a hot cell at the 2224 Laboratory. The process is designed to separate medium-curie liquid waste into a low-curie stream for feeding to supplemental treatment and a high-curie stream for double-shell tank storage. Separations criteria (for Cesium-137 sulfate and sodium) were exceeded in all three of the flowsheet tests that were performed.

  6. FRACTIONAL CRYSTALLIZATION FLOWSHEET TESTS WITH ACTUAL TANK WASTE

    SciTech Connect

    HERTING, D.L.

    2006-10-18

    Laboratory-scale flowsheet tests of the fractional crystallization process were conducted with actual tank waste samples in a hot cell at the 222-S Laboratory. The process is designed to separate medium-curie liquid waste into a low-curie stream for feeding to supplemental treatment and a high-curie stream for double-shell tank storage. Separations criteria (for Cs-137 sulfate, and sodium) were exceeded in all three of the flowsheet tests that were performed.

  7. Alternative Chemical Cleaning Methods for High Level Waste Tanks: Actual Waste Testing with SRS Tank 5F Sludge

    SciTech Connect

    King, William D.; Hay, Michael S.

    2016-08-30

    Solubility testing with actual High Level Waste tank sludge has been conducted in order to evaluate several alternative chemical cleaning technologies for the dissolution of sludge residuals remaining in the tanks after the exhaustion of mechanical cleaning and sludge sluicing efforts. Tests were conducted with archived Savannah River Site (SRS) radioactive sludge solids that had been retrieved from Tank 5F in order to determine the effectiveness of an optimized, dilute oxalic/nitric acid cleaning reagent toward dissolving the bulk non-radioactive waste components. Solubility tests were performed by direct sludge contact with the oxalic/nitric acid reagent and with sludge that had been pretreated and acidified with dilute nitric acid. For comparison purposes, separate samples were also contacted with pure, concentrated oxalic acid following current baseline tank chemical cleaning methods. One goal of testing with the optimized reagent was to compare the total amounts of oxalic acid and water required for sludge dissolution using the baseline and optimized cleaning methods. A second objective was to compare the two methods with regard to the dissolution of actinide species known to be drivers for SRS tank closure Performance Assessments (PA). Additionally, solubility tests were conducted with Tank 5 sludge using acidic and caustic permanganate-based methods focused on the “targeted” dissolution of actinide species.

  8. CHARACTERIZATION AND ACTUAL WASTE TEST WITH TANK 5F SAMPLES

    SciTech Connect

    Hay, M. S.; Crapse, K. P.; Fink, S. D.; Pareizs, J. M.

    2007-08-30

    The initial phase of bulk waste removal operations was recently completed in Tank 5F. Video inspection of the tank indicates several mounds of sludge still remain in the tank. Additionally, a mound of white solids was observed under Riser 5. In support of chemical cleaning and heel removal programs, samples of the sludge and the mound of white solids were obtained from the tank for characterization and testing. A core sample of the sludge and Super Snapper sample of the white solids were characterized. A supernate dip sample from Tank 7F was also characterized. A portion of the sludge was used in two tank cleaning tests using oxalic acid at 50 C and 75 C. The filtered oxalic acid from the tank cleaning tests was subsequently neutralized by addition to a simulated Tank 7F supernate. Solids and liquid samples from the tank cleaning test and neutralization test were characterized. A separate report documents the results of the gas generation from the tank cleaning test using oxalic acid and Tank 5F sludge. The characterization results for the Tank 5F sludge sample (FTF-05-06-55) appear quite good with respect to the tight precision of the sample replicates, good results for the glass standards, and minimal contamination found in the blanks and glass standards. The aqua regia and sodium peroxide fusion data also show good agreement between the two dissolution methods. Iron dominates the sludge composition with other major contributors being uranium, manganese, nickel, sodium, aluminum, and silicon. The low sodium value for the sludge reflects the absence of supernate present in the sample due to the core sampler employed for obtaining the sample. The XRD and CSEM results for the Super Snapper salt sample (i.e., white solids) from Tank 5F (FTF-05-07-1) indicate the material contains hydrated sodium carbonate and bicarbonate salts along with some aluminum hydroxide. These compounds likely precipitated from the supernate in the tank. A solubility test showed the material

  9. ACTUAL WASTE TESTING OF GYCOLATE IMPACTS ON THE SRS TANK FARM

    SciTech Connect

    Martino, C.

    2014-05-28

    Glycolic acid is being studied as a replacement for formic acid in the Defense Waste Processing Facility (DWPF) feed preparation process. After implementation, the recycle stream from DWPF back to the high-level waste Tank Farm will contain soluble sodium glycolate. Most of the potential impacts of glycolate in the Tank Farm were addressed via a literature review and simulant testing, but several outstanding issues remained. This report documents the actual-waste tests to determine the impacts of glycolate on storage and evaporation of Savannah River Site high-level waste. The objectives of this study are to address the following: Determine the extent to which sludge constituents (Pu, U, Fe, etc.) dissolve (the solubility of sludge constituents) in the glycolate-containing 2H-evaporator feed. Determine the impact of glycolate on the sorption of fissile (Pu, U, etc.) components onto sodium aluminosilicate solids. The first objective was accomplished through actual-waste testing using Tank 43H and 38H supernatant and Tank 51H sludge at Tank Farm storage conditions. The second objective was accomplished by contacting actual 2H-evaporator scale with the products from the testing for the first objective. There is no anticipated impact of up to 10 g/L of glycolate in DWPF recycle to the Tank Farm on tank waste component solubilities as investigated in this test. Most components were not influenced by glycolate during solubility tests, including major components such as aluminum, sodium, and most salt anions. There was potentially a slight increase in soluble iron with added glycolate, but the soluble iron concentration remained so low (on the order of 10 mg/L) as to not impact the iron to fissile ratio in sludge. Uranium and plutonium appear to have been supersaturated in 2H-evaporator feed solution mixture used for this testing. As a result, there was a reduction of soluble uranium and plutonium as a function of time. The change in soluble uranium concentration was

  10. Vacuum Drying of Actual Transuranic Waste from Hanford Tanks

    SciTech Connect

    Tingey, Joel M.

    2004-05-20

    Composites of sludge from Tanks 241-B-203, 241-T-203, 241 T 204, and 241-T-110 at the Hanford Site were prepared at the Hanford 222-S Laboratory from core samples retrieved from these tanks. These tank composites may not be representative of the entire contents of the tank but provide some indication of the properties of the waste within these underground storage tanks. The composite samples were diluted with water at the Radiochemical Processing Laboratory at Pacific Northwest National Laboratory to represent the slurries that are expected to be received from tank retrieval operations and processed to produce a final waste stream. The dilutions were vacuum dried at 60 C and 26 in. of mercury ({approx} 100 torr). Semi-quantitative measurements of stickiness and cohesive strength were made on these dilutions as a function of drying time. Mass loss as a function of drying time and total solids concentration of the initial dilution and at the conclusion of drying were also measured. Visual observations of the sludge were recorded throughout the drying process.

  11. Electrochemical destruction of organics and nitrates in simulated and actual radioactive Hanford tank waste

    SciTech Connect

    Elmore, M.R.; Lawrence, W.E.

    1996-09-01

    Pacific Northwest National Laboratory has conducted an evaluation of electrochemical processing for use in radioactive tank waste cleanup activities. An electrochemical organic destruction (ECOD) process was evaluated, with the main focus being the destruction of organic compounds (especially organic complexants of radionuclides) in simulated and actual radioactive Hanford tank wastes. A primary reason for destroying the organic species in the complexant concentrate tank waste is to decomplex/defunctionalize species that chelate radionuclides. the separations processes required to remove the radionuclides are much less efficient when chelators are present. A second objective, the destruction of nitrates and nitrites in the wastes, was also assessed. Organic compounds, nitrates, and nitrites may affect waste management and safety considerations, not only at Hanford but at other US Department of Energy sites that maintain high- level waste storage tanks.

  12. Characterization, Leaching, and Filtrations Testing of Ferrocyanide Tank sludge (Group 8) Actual Waste Composite

    SciTech Connect

    Fiskum, Sandra K.; Billing, Justin M.; Crum, J. V.; Daniel, Richard C.; Edwards, Matthew K.; Shimskey, Rick W.; Peterson, Reid A.; MacFarlan, Paul J.; Buck, Edgar C.; Draper, Kathryn E.; Kozelisky, Anne E.

    2009-02-28

    This is the final report in a series of eight reports defining characterization, leach, and filtration testing of a wide variety of Hanford tank waste sludges. The information generated from this series is intended to supplement the Waste Treatment and Immobilization Plant (WTP) project understanding of actual waste behaviors associated with tank waste sludge processing through the pretreatment portion of the WTP. The work described in this report presents information on a high-iron waste form, specifically the ferrocyanide tank waste sludge. Iron hydroxide has been shown to pose technical challenges during filtration processing; the ferrocyanide tank waste sludge represented a good source of the high-iron matrix to test the filtration processing.

  13. TESTING OF ENHANCED CHEMICAL CLEANING OF SRS ACTUAL WASTE TANK 5F AND TANK 12H SLUDGES

    SciTech Connect

    Martino, C.; King, W.

    2011-08-22

    Forty three of the High Level Waste (HLW) tanks at the Savannah River Site (SRS) have internal structures that hinder removal of the last approximately five thousand gallons of waste sludge solely by mechanical means. Chemical cleaning can be utilized to dissolve the sludge heel with oxalic acid (OA) and pump the material to a separate waste tank in preparation for final disposition. This dissolved sludge material is pH adjusted downstream of the dissolution process, precipitating the sludge components along with sodium oxalate solids. The large quantities of sodium oxalate and other metal oxalates formed impact downstream processes by requiring additional washing during sludge batch preparation and increase the amount of material that must be processed in the tank farm evaporator systems and the Saltstone Processing Facility. Enhanced Chemical Cleaning (ECC) was identified as a potential method for greatly reducing the impact of oxalate additions to the SRS Tank Farms without adding additional components to the waste that would extend processing or increase waste form volumes. In support of Savannah River Site (SRS) tank closure efforts, the Savannah River National Laboratory (SRNL) conducted Real Waste Testing (RWT) to evaluate an alternative to the baseline 8 wt. % OA chemical cleaning technology for tank sludge heel removal. The baseline OA technology results in the addition of significant volumes of oxalate salts to the SRS tank farm and there is insufficient space to accommodate the neutralized streams resulting from the treatment of the multiple remaining waste tanks requiring closure. ECC is a promising alternative to bulk OA cleaning, which utilizes a more dilute OA (nominally 2 wt. % at a pH of around 2) and an oxalate destruction technology. The technology is being adapted by AREVA from their decontamination technology for Nuclear Power Plant secondary side scale removal. This report contains results from the SRNL small scale testing of the ECC process

  14. BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE

    SciTech Connect

    Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

    2008-09-25

    Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The

  15. Laboratory Demonstration of the Pretreatment Process with Caustic and Oxidative Leaching Using Actual Hanford Tank Waste

    SciTech Connect

    Fiskum, Sandra K.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Shimskey, Rick W.; Snow, Lanee A.

    2009-01-01

    This report describes the bench-scale pretreatment processing of actual tank waste materials through the entire baseline WTP pretreatment flowsheet in an effort to demonstrate the efficacy of the defined leaching processes on actual Hanford tank waste sludge and the potential impacts on downstream pretreatment processing. The test material was a combination of reduction oxidation (REDOX) tank waste composited materials containing aluminum primarily in the form of boehmite and dissolved S saltcake containing Cr(III)-rich entrained solids. The pretreatment processing steps tested included • caustic leaching for Al removal • solids crossflow filtration through the cell unit filter (CUF) • stepwise solids washing using decreasing concentrations of sodium hydroxide with filtration through the CUF • oxidative leaching using sodium permanganate for removing Cr • solids filtration with the CUF • follow-on solids washing and filtration through the CUF • ion exchange processing for Cs removal • evaporation processing of waste stream recycle for volume reduction • combination of the evaporated product with dissolved saltcake. The effectiveness of each process step was evaluated by following the mass balance of key components (such as Al, B, Cd, Cr, Pu, Ni, Mn, and Fe), demonstrating component (Al, Cr, Cs) removal, demonstrating filterability by evaluating filter flux rates under various processing conditions (transmembrane pressure, crossflow velocities, wt% undissolved solids, and PSD) and filter fouling, and identifying potential issues for WTP. The filterability was reported separately (Shimskey et al. 2008) and is not repeated herein.

  16. FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION & COPRECIPITATION WITH ACTUAL TANK WASTE

    SciTech Connect

    WARRANT, R.W.

    2006-12-11

    Fractional crystallization is being considered as a pretreatment method to support supplemental treatment of retrieved single-shell tank (SST) saltcake waste at the Hanford Site. The goal of the fractional crystallization process is to optimize the separation of the radioactivity (radionuclides) from the saltcake waste and send it to the Waste Treatment and Immobilization Plant and send the bulk of the saltcake to the supplemental treatment plant (bulk vitrification). The primary factors that influence the separation efficiency are (1) solid/liquid separation efficiency, (2) contaminant inclusions, and (3) co-precipitation. This is a report of testing for factors (2) and (3) with actual tank waste samples. For the purposes of this report, contaminant inclusions are defined as the inclusion of supernatant, containing contaminating radionuclides, in a pocket within the precipitating saltcake crystals. Co-precipitation is defined as the simultaneous precipitation of a saltcake crystal with a contaminating radionuclide. These two factors were tested for various potential fractional crystallization product salts by spiking the composite tank waste samples (SST Early or SST Late, external letter CH2M-0600248, ''Preparation of Composite Tank Waste Samples for ME-21 Project'') with the desired target salt and then evaporating to precipitate that salt. SST Early represents the typical composition of dissolved saltcake early in the retrieval process, and SST Late represents the typical composition during the later stages of retrieval.

  17. PERFORMANCE TESTING OF THE NEXT-GENERATION CSSX SOLVENT WITH ACTUAL SRS TANK WASTE

    SciTech Connect

    Pierce, R.; Peters, T.; Crowder, M.; Fink, S.

    2011-11-01

    Efforts are underway to qualify the Next-Generation Solvent for the Caustic Side Solvent Extraction (CSSX) process. Researchers at multiple national laboratories have been involved in this effort. As part of the effort to qualify the solvent extraction system at the Savannah River Site (SRS), SRNL performed a number of tests at various scales. First, SRNL completed a series of batch equilibrium, or Extraction-Scrub-Strip (ESS), tests. These tests used {approx}30 mL of Next-Generation Solvent and either actual SRS tank waste, or waste simulant solutions. The results from these cesium mass transfer tests were used to predict solvent behavior under a number of conditions. At a larger scale, SRNL assembled 12 stages of 2-cm (diameter) centrifugal contactors. This rack of contactors is structurally similar to one tested in 2001 during the demonstration of the baseline CSSX process. Assembly and mechanical testing found no issues. SRNL performed a nonradiological test using 35 L of cesium-spiked caustic waste simulant and 39 L of actual tank waste. Test results are discussed; particularly those related to the effectiveness of extraction.

  18. REMOVING SLUDGE HEELS FROM SAVANNAH RIVER SITE WASTE TANKS BY OXALIC ACID DISSOLUTION

    SciTech Connect

    Poirier, M; David Herman, D; Fernando Fondeur, F; John Pareizs, J; Michael Hay, M; Bruce Wiersma, B; Kim Crapse, K; Thomas Peters, T; Samuel Fink, S; Donald Thaxton, D

    2009-03-01

    The Savannah River Site (SRS) will remove sludge as part of waste tank closure operations. Typically the bulk sludge is removed by mixing it with supernate to produce a slurry, and transporting the slurry to a downstream tank for processing. Experience shows that a residual heel may remain in the tank that cannot be removed by this conventional technique. In the past, SRS used oxalic acid solutions to disperse or dissolve the sludge heel to complete the waste removal. To better understand the actual conditions of oxalic acid cleaning of waste from carbon steel tanks, the authors developed and conducted an experimental program to determine its effectiveness in dissolving sludge, the hydrogen generation rate, the generation rate of other gases, the carbon steel corrosion rate, the impact of mixing on chemical cleaning, the impact of temperature, and the types of precipitates formed during the neutralization process. The test samples included actual SRS sludge and simulated SRS sludge. The authors performed the simulated waste tests at 25, 50, and 75 C by adding 8 wt % oxalic acid to the sludge over seven days. They conducted the actual waste tests at 50 and 75 C by adding 8 wt % oxalic acid to the sludge as a single batch. Following the testing, SRS conducted chemical cleaning with oxalic acid in two waste tanks. In Tank 5F, the oxalic acid (8 wt %) addition occurred over seven days, followed by inhibited water to ensure the tank contained enough liquid to operate the mixer pumps. The tank temperature during oxalic acid addition and dissolution was approximately 45 C. The authors analyzed samples from the chemical cleaning process and compared it with test data. The conclusions from the work are: (1) Oxalic acid addition proved effective in dissolving sludge heels in the simulant demonstration, the actual waste demonstration, and in SRS Tank 5F. (2) The oxalic acid dissolved {approx} 100% of the uranium, {approx} 100% of the iron, and {approx} 40% of the manganese

  19. Task Technical and Quality Assurance Plan for Determining Uranium and Plutonium Solubility in Actual Tank Waste Supernates

    SciTech Connect

    King, William D.

    2005-06-28

    Savannah River Site tank waste supernates contain small quantities of dissolved uranium and plutonium. Due to the large volume of supernates, significant quantities of dissolved uranium and plutonium are managed as part of waste transfers, evaporation and pretreatment at the Savannah River Site in tank farm operations, the Actinide Removal Project (ARP), and the Salt Waste Processing Facility (SWPF). Previous SRNL studies have investigated the effect of temperature and major supernate components on the solubility of uranium and plutonium. Based on these studies, equations were developed for the prediction of U and Pu solubility in tank waste supernates. The majority of the previous tests were conducted with simulated waste solutions. The current testing is intended to determine solubility in actual tank waste samples (as-received, diluted, and combinations of tank samples) as a function of composition and temperature. Results will be used to validate and build on the existing solubility equations.

  20. Modeling water retention of sludge simulants and actual saltcake tank wastes

    SciTech Connect

    Simmons, C.S.

    1996-07-01

    The Ferrocyanide Tanks Safety Program managed by Westinghouse hanford Company has been concerned with the potential combustion hazard of dry tank wastes containing ferrocyanide chemical in combination with nitrate salts. Pervious studies have shown that tank waste containing greater than 20 percent of weight as water could not be accidentally ignited. Moreover, a sustained combustion could not be propagated in such a wet waste even if it contained enough ferrocyanide to burn. Because moisture content is a key critical factor determining the safety of ferrocyanide-containing tank wastes, physical modeling was performed by Pacific Northwest National laboratory to evaluate the moisture-retaining behavior of typical tank wastes. The physical modeling reported here has quantified the mechanisms by which two main types of tank waste, sludge and saltcake, retain moisture in a tank profile under static conditions. Static conditions usually prevail after a tank profile has been stabilized by pumping out any excess interstitial liquid, which is not naturally retained by the waste as a result of physical forces such as capillarity.

  1. Physical Property and Rheological Testing of Actual Transuranic Waste from Hanford Single-Shell Tanks

    SciTech Connect

    Tingey, Joel M. ); Gao, Johnway ); Delegard, Calvin H. ); Bagaasen, Larry M. ); Wells, Beric E. )

    2003-08-25

    Composites of sludge from Hanford tanks 241-B-203 (B-203), 241-T-203 (T-203), 241-T-204 (T-204), and 241-T-110 (T-110) were prepared at the Hanford 222-S Laboratory and transferred to the Radiochemical Processing Laboratory at the Pacific Northwest National Laboratory (PNNL) for measurement of the composites' physical properties. These tank composites were prepared from core samples retieved from these tanks. These core samples may not be representative of the entire contents of the tank but provide some indication of the properties of the waste in these underground storage tanks. Dilutions in water were prepared from the composite samples. The measurements included paint filter tests, viscosity, shear strength, settling and centrifuging behavior, a qualitative test of stickiness, total solids concentration, and extrusion tests to estimate shear strength.

  2. DESTRUCTION OF TETRAPHENYLBORATE IN TANK 48H USING WET AIR OXIDATION BATCH BENCH SCALE AUTOCLAVE TESTING WITH ACTUAL RADIOACTIVE TANK 48H WASTE

    SciTech Connect

    Adu-Wusu, K; Paul Burket, P

    2009-03-31

    Wet Air Oxidation (WAO) is one of the two technologies being considered for the destruction of Tetraphenylborate (TPB) in Tank 48H. Batch bench-scale autoclave testing with radioactive (actual) Tank 48H waste is among the tests required in the WAO Technology Maturation Plan. The goal of the autoclave testing is to validate that the simulant being used for extensive WAO vendor testing adequately represents the Tank 48H waste. The test objective was to demonstrate comparable test results when running simulated waste and real waste under similar test conditions. Specifically: (1) Confirm the TPB destruction efficiency and rate (same reaction times) obtained from comparable simulant tests, (2) Determine the destruction efficiency of other organics including biphenyl, (3) Identify and quantify the reaction byproducts, and (4) Determine off-gas composition. Batch bench-scale stirred autoclave tests were conducted with simulated and actual Tank 48H wastes at SRNL. Experimental conditions were chosen based on continuous-flow pilot-scale simulant testing performed at Siemens Water Technologies Corporation (SWT) in Rothschild, Wisconsin. The following items were demonstrated as a result of this testing. (1) Tetraphenylborate was destroyed to below detection limits during the 1-hour reaction time at 280 C. Destruction efficiency of TPB was > 99.997%. (2) Other organics (TPB associated compounds), except biphenyl, were destroyed to below their respective detection limits. Biphenyl was partially destroyed in the process, mainly due to its propensity to reside in the vapor phase during the WAO reaction. Biphenyl is expected to be removed in the gas phase during the actual process, which is a continuous-flow system. (3) Reaction byproducts, remnants of MST, and the PUREX sludge, were characterized in this work. Radioactive species, such as Pu, Sr-90 and Cs-137 were quantified in the filtrate and slurry samples. Notably, Cs-137, boron and potassium were shown as soluble as a

  3. STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138

    SciTech Connect

    Burket, P

    2009-02-24

    This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

  4. Ion exchange removal of cesium from simulated and actual supernate from Hanford tanks 241-SY-101 and 241-SY-103

    SciTech Connect

    Brown, G.N.; Bontha, J.R.; Carlson, C.D.

    1995-09-01

    Pacific Northwest Laboratory (PNL), in conjunction with the Process Chemistry and Statistics Section of Westinghouse Hanford Company (WHC), conducted this study as part of the Supernatant Treatment Development Task for the Initial Pretreatment Module (IPM) Applied Engineering Project. The study assesses the performance of the CS-100 ion exchange material for removing cesium from simulated and actual alkaline supernate from Hanford tanks 241-SY-101 and 241-SY-103. The objective of these experiments is to compare the cesium ion exchange loading and elution profiles of actual and simulated wastes. Specific experimental objectives include (1) demonstration of decontamination factors (DF) for cesium removal, 92) verification of simulant performance, (3) investigation of waste/exchanger chemistry, and (4) determination of the radionuclide content of the regenerated CS-100 resin prior to disposal.

  5. Disinfection of septic tank and cesspool wastewater with peracetic acid.

    PubMed

    Heinonen-Tanski, Helvi; Savolainen, Ritva

    2003-08-01

    Wastewaters of private household septic tanks and cesspools have been treated with peracetic acid (1-2 g L(-1)). Adding 1 g L(-1) peracetic acid to wastewaters was easy and has been found to be effective in destroying enteric indicator microorganisms. The careful mixing of peracetic acid and wastewater was found to be important. Winter periods with frozen soil, ice and snow did not constitute extra problems. The bad smell of these wastewaters almost totally disappeared during the treatment. When wastewaters treated with peracetic acid were emptied into animal slurry tanks, hygienization still continued in the mixture of animal slurry and the wastewaters. These wastewaters could thus be released into agricultural soil without risk of microbiological pollution to groundwaters.

  6. Hydrogen gas filling into an actual tank at high pressure and optimization of its thermal characteristics

    NASA Astrophysics Data System (ADS)

    Khan, Md. Tawhidul Islam; Monde, Masanori; Setoguchi, Toshiaki

    2009-09-01

    Gas with high pressure is widely used at present as fuel storage mode for different hydrogen vehicles. Different types of materials are used for constructing these hydrogen pressure vessels. An aluminum lined vessel and typically carbon fiber reinforced plastic (CFRP) materials are commercially used in hydrogen vessels. An aluminum lined vessel is easy to construct and posses high thermal conductivity compared to other commercially available vessels. However, compared to CFRP lined vessel, it has low strength capacity and safety factors. Therefore, nowadays, CFRP lined vessels are becoming more popular in hydrogen vehicles. Moreover, CFRP lined vessel has an advantage of light weight. CFRP, although, has many desirable properties in reducing the weight and in increasing the strength, it is also necessary to keep the material temperature below 85 °C for maintaining stringent safety requirements. While filling process occurs, the temperature can be exceeded due to the compression works of the gas flow. Therefore, it is very important to optimize the hydrogen filling system to avoid the crossing of the critical limit of the temperature rise. Computer-aided simulation has been conducted to characterize the hydrogen filling to optimize the technique. Three types of hydrogen vessels with different volumes have been analyzed for optimizing the charging characteristics of hydrogen to test vessels. Gas temperatures are measured inside representative vessels in the supply reservoirs (H2 storages) and at the inlet to the test tank during filling.

  7. 46 CFR 153.1052 - Carriage of other cargoes in acid tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ..., hydrochloric acid, or phosphoric acid with out specific authorization from the Commandant (CG-ENG). ... 46 Shipping 5 2012-10-01 2012-10-01 false Carriage of other cargoes in acid tanks. 153.1052... Special Cargo Procedures § 153.1052 Carriage of other cargoes in acid tanks. No person shall load or carry...

  8. 46 CFR 153.1052 - Carriage of other cargoes in acid tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ..., hydrochloric acid, or phosphoric acid with out specific authorization from the Commandant (CG-ENG). ... 46 Shipping 5 2013-10-01 2013-10-01 false Carriage of other cargoes in acid tanks. 153.1052... Special Cargo Procedures § 153.1052 Carriage of other cargoes in acid tanks. No person shall load or carry...

  9. 46 CFR 153.1052 - Carriage of other cargoes in acid tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... Special Cargo Procedures § 153.1052 Carriage of other cargoes in acid tanks. No person shall load or carry other cargoes in a cargo containment system of a U.S. flag ship endorsed to carry sulfuric acid... 46 Shipping 5 2014-10-01 2014-10-01 false Carriage of other cargoes in acid tanks. 153.1052...

  10. 46 CFR 153.1052 - Carriage of other cargoes in acid tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... Special Cargo Procedures § 153.1052 Carriage of other cargoes in acid tanks. No person shall load or carry other cargoes in a cargo containment system of a U.S. flag ship endorsed to carry sulfuric acid... 46 Shipping 5 2011-10-01 2011-10-01 false Carriage of other cargoes in acid tanks. 153.1052...

  11. Organic Tank Safety Project: development of a method to measure the equilibrium water content of Hanford organic tank wastes and demonstration of method on actual waste

    SciTech Connect

    Scheele, R.D.; Bredt, P.R.; Sell, R.L.

    1996-09-01

    Some of Hanford`s underground waste storage tanks contain Organic- bearing high level wastes that are high priority safety issues because of potentially hazardous chemical reactions of organics with inorganic oxidants in these wastes such as nitrates and nitrites. To ensure continued safe storage of these wastes, Westinghouse Hanford Company has placed affected tanks on the Organic Watch List and manages them under special rules. Because water content has been identified as the most efficient agent for preventing a propagating reaction and is an integral part of the criteria developed to ensure continued safe storage of Hanford`s organic-bearing radioactive tank wastes, as part of the Organic Tank Safety Program the Pacific Northwest National Laboratory developed and demonstrated a simple and easily implemented procedure to determine the equilibrium water content of these potentially reactive wastes exposed to the range of water vapor pressures that might be experienced during the wastes` future storage. This work focused on the equilibrium water content and did not investigate the various factors such as @ ventilation, tank surface area, and waste porosity that control the rate that the waste would come into equilibrium, with either the average Hanford water partial pressure 5.5 torr or other possible water partial pressures.

  12. 31. Public Works Department Drawing 463M5 (1992), 'Replace Acid Tank ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    31. Public Works Department Drawing 463-M-5 (1992), 'Replace Acid Tank No. 3-Plan, Elevation, Details' - Mare Island Naval Shipyard, Acid Mixing Facility, California Avenue & E Street, Vallejo, Solano County, CA

  13. Tank 12H Acidic Chemical Cleaning Sample Analysis And Material Balance

    SciTech Connect

    Martino, C. J.; Reboul, S. H.; Wiersma, B. J.; Coleman, C. J.

    2013-11-08

    A process of Bulk Oxalic Acid (BOA) chemical cleaning was performed for Tank 12H during June and July of 2013 to remove all or a portion of the approximately 4400 gallon sludge heel. Three strikes of oxalic acid (nominally 4 wt% or 2 wt%) were used at 55°C and tank volumes of 96- to 140-thousand gallons. This report details the sample analysis of a scrape sample taken prior to BOA cleaning and dip samples taken during BOA cleaning. It also documents a rudimentary material balance for the Tank 12H cleaning results.

  14. Comparison of organic and inorganic ion exchangers for removal of cesium and strontium from simulated and actual Hanford 241-AW-101 DSSF tank waste

    SciTech Connect

    Brown, G.N.; Bray, L.A.; Carlson, C.D.

    1996-04-01

    A number of organic and inorganic exchangers are being developed and evaluated for cesium removal from Hanford tank wastes. The exchangers of interest that are investigated in this work include powdered (IONSIV{reg_sign} IE-910; referred to as IE-910) and engineered (IONSIV{reg_sign} IE-911; referred to as IE-911) forms of the crystalline silico-titanate (CST) inorganic sorbent developed by Sandia National Laboratories (SNL)/Texas A and M and prepared by UOP; a phenol-formaldehyde (CS-100) resin developed by Rohm and Haas; a resorcinol-formaldehyde (R-F) polymer developed at the Westinghouse Savannah River Company (WSRC) and produced by Boulder Scientific; an inorganic zeolite exchanger produced by UOP (IONSIV{reg_sign} TIE-96; referred to as TIE-96); an inorganic sodium titanate produced by Allied Signal/Texas A and M (NaTi); and a macrocyclic organic resin developed and produced by IBC Advanced Technologies (SuperLig{reg_sign} 644; referred to as SL-644). Several of these materials are still under development and may not be in the optimal form. The work described in this report involves the direct comparison of the ion exchange materials for the pretreatment of actual and simulated Hanford tank waste. Data on the performance of all of the exchangers with simulated and actual double shell slurry feed (DSSF) is included. The DSSF waste is a mixture of the supernate from tanks 101-AW (70%), 106-AP (20%) and 102-AP (10%). The comparative parameters include radionuclide removal efficiency under a variety of conditions and material properties (e.g., bed density and percent removable water). Cesium and strontium distribution (K{sub d}), lambda ({lambda} = K{sub d} {times} {rho}{sub b}), and decontamination factors (DF) are compared as a function of exchanger contact duration, solution composition (Na and Cs concentration), exchanger/waste phase ratio, and multiple sequential contacts.

  15. SAFETY EVALUATION OF OXALIC ACID WASTE RETRIEVAL IN SINGLE SHELL TANK (SST) 241-C-106

    SciTech Connect

    GOETZ, T.G.

    2003-07-21

    This report documents the safety evaluation of the process of retrieving sludge waste from single-shell tank 241-C-106 using oxalic acid. The results of the HAZOP, safety evaluation, and control allocation/decision are part of the report. This safety evaluation considers the use of oxalic acid to recover residual waste in single-shell tank (SST) 241-C-106. This is an activity not addressed in the current tank farm safety basis. This evaluation has five specific purposes: (1) Identifying the key configuration and operating assumptions needed to evaluate oxalic acid dissolution in SST 241-C-106. (2) Documenting the hazardous conditions identified during the oxalic acid dissolution hazard and operability study (HAZOP). (3) Documenting the comparison of the HAZOP results to the hazardous conditions and associated analyzed accident currently included in the safety basis, as documented in HNF-SD-WM-TI-764, ''Hazard Analysis Database Report''. (4) Documenting the evaluation of the oxalic acid dissolution activity with respect to Accident analyses described in HNF-SD-WM-SAR-067, ''Tank Farms Final Safety Analysis Report'' (FSAR). (5)Controls specified in HNF-SD-WM-TSR-006, ''Tank Farms Technical Safety Requirements'' (TSR). Documenting the process and results of control decisions as well as the applicability of preventive and/or mitigative controls to each oxalic acid addition hazardous condition.

  16. 46 CFR 153.1052 - Carriage of other cargoes in acid tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Carriage of other cargoes in acid tanks. 153.1052 Section 153.1052 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS... other cargoes in a cargo containment system of a U.S. flag ship endorsed to carry sulfuric acid...

  17. SAFETY EVALUATION OF OXALIC ACID WASTE RETRIEVAL IN SINGLE SHELL TANK (SST) 241-C-106

    SciTech Connect

    SHULTZ, M.V.

    2003-06-11

    This report documents the safety evaluation of the process of retrieving sludge waste from single-shell tank 241-C-106 using oxalic acid. The results of the HAZOP, safety evaluation, and control allocation/decision are part of the report. This safety evaluation considers the use of oxalic acid to recover residual waste in single-shell tank (SST) 241-C-106. This is an activity not addressed in the current tank farm safety basis. This evaluation has five specific purposes: (1) Identifying the key configuration and operating assumptions needed to evaluate oxalic acid dissolution in SST 241-C-106. (2) Documenting the hazardous conditions identified during the oxalic acid dissolution hazard and operability study (HAZOP). (3) Documenting the comparison of the HAZOP results to the hazardous conditions and associated analyzed accident currently included in the safety basis, as documented in HNF-SD-WM-TI-764, Hazard Analysis Database Report. (4) Documenting the evaluation of the oxalic acid dissolution activity with respect to: (A) Accident analyses described in HNF-SD-WM-SAR-067, Tank Farms Final Safety Analysis Report (FSAR), and (B) Controls specified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements (TSR). (5) Documenting the process and results of control decisions as well as the applicability of preventive and/or mitigative controls to each oxalic acid addition hazardous condition. This safety evaluation is not intended to be a request to authorize the activity. Authorization issues are addressed by the unreviewed safety question (USQ) evaluation process. This report constitutes an accident analysis.

  18. DEPOSITION TANK CORROSION TESTING FOR ENHANCED CHEMICAL CLEANING POST OXALIC ACID DESTRUCTION

    SciTech Connect

    Mickalonis, J.

    2011-08-29

    An Enhanced Chemical Cleaning (ECC) process is being developed to aid in the high level waste tank closure at the Savannah River Site. The ECC process uses an advanced oxidation process (AOP) to destroy the oxalic acid that is used to remove residual sludge from a waste tank prior to closure. The AOP process treats the dissolved sludge with ozone to decompose the oxalic acid through reactions with hydroxyl radicals. The effluent from this oxalic acid decomposition is to be sent to a Type III waste tank and may be corrosive to these tanks. As part of the hazardous simulant testing that was conducted at the ECC vendor location, corrosion testing was conducted to determine the general corrosion rate for the deposition tank and to assess the susceptibility to localized corrosion, especially pitting. Both of these factors impact the calculation of hydrogen gas generation and the structural integrity of the tanks, which are considered safety class functions. The testing consisted of immersion and electrochemical testing of A537 carbon steel, the material of construction of Type III tanks, and 304L stainless steel, the material of construction for transfer piping. Tests were conducted in solutions removed from the destruction loop of the prototype ECC set up. Hazardous simulants, which were manufactured at SRNL, were used as representative sludges for F-area and H-area waste tanks. Oxalic acid concentrations of 1 and 2.5% were used to dissolve the sludge as a feed to the ECC process. Test solutions included the uninhibited effluent, as well as the effluent treated for corrosion control. The corrosion control options included mixing with an inhibited supernate and the addition of hydroxide. Evaporation of the uninhibited effluent was also tested since it may have a positive impact on reducing corrosion. All corrosion testing was conducted at 50 C. The uninhibited effluent was found to increase the corrosion rate by an order of magnitude from less than 1 mil per year (mpy

  19. The effect of nitric acid exposure on Galileo spacecraft titanium alloy Ti-6Al-4V propellant tanks

    NASA Technical Reports Server (NTRS)

    Hsieh, Cheng; O'Donnell, Tim; Yavrouian, Andre

    1990-01-01

    The Ti-6Al-4V-constructed retropropulsion-module tanks of the Galileo spacecraft were purged with nitrogen tetroxide in order to wait out a major launch rescheduling; nitric acid is among the residual products of such an operation. A test program was conducted on representative samples to ascertain the fracture toughness and stress corrosion threshold of the tanks' material, in view of Space Shuttle safety and mission-reliability requirements. It was found that the tanks' structural integrity was not degraded by nitric acid exposure.

  20. DEVELOPING AN OPTIMIZED PROCESS STRATEGY FOR ACID CLEANING OF THE SAVANNAH RIVERSITE HLW TANKS

    SciTech Connect

    Ketusky, E

    2006-12-04

    At the Savannah River Site (SRS), there remains approximately 35 million gallons of High Level Waste (HLW) that was mostly created from Purex and SRS H-Area Modified (HM) nuclear fuel cycles. The waste is contained in approximately forty-nine tanks fabricated from commercially available carbon steel. In order to minimize general corrosion, the waste is maintained as very-alkaline solution. The very-alkaline chemistry has caused hydrated metal oxides to precipitate and form a sludge heel. Over the years, the sludge waste has aged, with some forming a hardened crust. To aid in the removal of the sludge heels from select tanks for closure the use of oxalic acid to dissolve the sludge is being investigated. Developing an optimized process strategy based on laboratory analyses would be prohibitively costly. This research, therefore, demonstrates that a chemical equilibrium based software program can be used to develop an optimized process strategy for oxalic acid cleaning of the HLW tanks based on estimating resultant chemistries, minimizing resultant oxalates sent to the evaporator, and minimizing resultant solids sent to the Defense Waste Processing Facility (DWPF).

  1. Factors affecting the numbers of expected viable lactic acid bacteria in inoculant applicator tanks.

    PubMed

    Windle, M C; Kung, L

    2016-11-01

    The application of correct numbers of viable microorganisms to forages at the time of ensiling is one of the most important factors affecting the probability of a beneficial effect from an inoculant. The objective of this study was to determine relationships between numbers of expected lactic acid bacteria (LAB) from silage inoculants in application tanks and various factors that might affect their viability. The pH and temperature of inoculant-water mixes were measured in applicator tanks (n=53) on farms in Wisconsin, Minnesota, South Dakota, and California during the corn harvest season of 2012. Samples were collected on-farm and plated on de Man, Rogosa, and Sharpe agar to enumerate LAB and establish the number of viable LAB (cfu/mL). Expected numbers of LAB were calculated from the minimum label guarantees for viable bacteria and mixing rates with water. In addition, the pH of the inoculant-water mixes at sampling, the ambient temperature at sampling, and the length of time that the samples had been in the tank were measured and obtained. The log difference between the measured and expected numbers of LAB was calculated and expressed as ΔM - E in log scale. Ambient temperature at sampling had no relationship with time in the tank or ΔM - E. Most (83%) of the inoculants had been mixed with water in the applicator tanks for <10h. For these samples, a negative linear correlation (R(2)=0.36) existed between time that the inoculant-water mixes were in the applicators tanks and ΔM - E. The pH of the inoculant-water mixes was also negatively correlated (R(2)=0.28) with time in the applicator tank, but pH was not related to ΔM - E. The temperatures of the inoculant-water mixtures were negatively correlated with ΔM - E (R(2)=0.39). Seven of 8 samples whose ΔM - E were at least -0.95 or more lower than expected (equivalent of about 1 or more log concentration less than expected) had water temperatures above 35°C. These data support our previous laboratory findings

  2. Removal of Cesium From Acidic Radioactive Tank Waste Using IONSIV IE-911 (CST)

    SciTech Connect

    Mann, Nicholas Robert; Todd, Terry Allen

    2004-10-01

    IONSIV IE-911, or the engineered form of crystalline silicotitanate (CST), manufactured by UOP Molecular Sieves, has been evaluated for the removal of cesium from Idaho National Engineering and Environmental Laboratory (INEEL) acidic radioactive tank waste. A series of batch contacts and column tests were performed by using three separate batches of CST. Batch contacts were performed to evaluate the concentration effects of nitric acid, sodium, and potassium ions on cesium sorption. Additional batch tests were performed to determine if americium, mercury, and plutonium would sorb onto IONSIV IE-911. An equilibrium isotherm was generated by using a concentrated tank waste simulant. Column tests using a 1.5 cm 3 column and flow rates of 3, 5, 10, 20, and 30 bed volumes (BV)/hr were performed to elucidate dynamic cesium sorption capacities and sorption kinetics. Additional experiments investigated the effect of CST batch and pretreatment on cesium sorption. The thermal stability of IONSIV IE-911 was evaluated by performing thermal gravimetric analysis/differential thermal analysis. Overall, IONSIV IE-911 was shown to be effective for cesium sorption from complex, highly acidic solutions; however, sorbent stability in these solutions may have a deleterious effect on cesium sorption.

  3. Molar Fraction of Oxalic Acid in Vapor Phase for Tank 241-C-106 Acid Dissolution Project

    SciTech Connect

    WHITE, M.A.

    2003-08-06

    The purpose of this calculation is to determine the molar fraction of oxalic acid in the vapor phase. This calculation will be used to assist the materials compatibility assessment for equipment that will be exposed to the oxalic acid vapor.

  4. SAVANNAH RIVER SITE TANK CLEANING: CORROSION RATE FOR ONE VERSUS EIGHT PERCENT OXALIC ACID SOLUTION

    SciTech Connect

    Ketusky, E.; Subramanian, K.

    2011-01-20

    Until recently, the use of oxalic acid for chemically cleaning the Savannah River Site (SRS) radioactive waste tanks focused on using concentrated 4 and 8-wt% solutions. Recent testing and research on applicable dissolution mechanisms have concluded that under appropriate conditions, dilute solutions of oxalic acid (i.e., 1-wt%) may be more effective. Based on the need to maximize cleaning effectiveness, coupled with the need to minimize downstream impacts, SRS is now developing plans for using a 1-wt% oxalic acid solution. A technology gap associated with using a 1-wt% oxalic acid solution was a dearth of suitable corrosion data. Assuming oxalic acid's passivation of carbon steel was proportional to the free oxalate concentration, the general corrosion rate (CR) from a 1-wt% solution may not be bound by those from 8-wt%. Therefore, after developing the test strategy and plan, the corrosion testing was performed. Starting with the envisioned process specific baseline solvent, a 1-wt% oxalic acid solution, with sludge (limited to Purex type sludge-simulant for this initial effort) at 75 C and agitated, the corrosion rate (CR) was determined from the measured weight loss of the exposed coupon. Environmental variations tested were: (a) Inclusion of sludge in the test vessel or assuming a pure oxalic acid solution; (b) acid solution temperature maintained at 75 or 45 C; and (c) agitation of the acid solution or stagnant. Application of select electrochemical testing (EC) explored the impact of each variation on the passivation mechanisms and confirmed the CR. The 1-wt% results were then compared to those from the 8-wt%. The immersion coupons showed that the maximum time averaged CR for a 1-wt% solution with sludge was less than 25-mils/yr for all conditions. For an agitated 8-wt% solution with sludge, the maximum time averaged CR was about 30-mils/yr at 50 C, and 86-mils/yr at 75 C. Both the 1-wt% and the 8-wt% testing demonstrated that if the sludge was removed from

  5. Comparison of organic and inorganic ion exchangers for removal of cesium and strontium from simulated and actual Hanford 241-AW-101 DSSF tank waste

    SciTech Connect

    Brown, G.N.; Bray, L.A.; Carlson, C.D.

    1996-01-01

    Pacific Northwest National Laboratory (Northwest National Laboratory) conducted this study as a joint effort between the ``Develop and Test Sorbents`` task for the Efficient Separations and Processing Cross-Cutting Program (ESP) and the ``Batch Testing of Crystalline Silico-Titanates (CSTs)`` subtask, which is part of the Northwest National Laboratory Tank Waste Remediation System (TWRS) Pretreatment Technology Development Project. The objective of the study is to investigate radionuclide uptake of the newly produced CST materials under a variety of solution conditions and to compare the results obtained for this material with those obtained for other commercial and experimental exchangers.

  6. Basic and Acidic Leaching of Sludge from Melton Valley Storage Tank W-25

    SciTech Connect

    Collins, J.L., Egan, B.Z., Beahm, E.C., Chase, C.W., Anderson, K.K.

    1997-10-01

    Bench-scale leaching tests were conducted with samples of tank waste sludge from the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to evaluate separation technology processes for use in concentrating the radionuclides and reducing the volume of waste for final disposal. This paper discusses the hot cell apparatus, the characterization of the sludge, the leaching methodology, and the results obtained from a variety of basic and acidic leaching tests of samples of sludge at ambient temperature. Basic leaching tests were also conducted at 75 and 95 deg C. The major alpha-,gamma., and beta-emitting radionuclides in the centrifuged, wet sludge solids were {sup 137}Cs, {sup 60}Co, {sup 154}Eu, {sup 241}Am, {sup 244}Cm {sup 90}Sr, Pu, U, and Th. The other major metals (in addition to the U and Th) and anions were Na, Ca, Al, K, Mg, NO{sub 3}{sup -},CO{sub 3}{sup 2-}, OH{sup -}, and O{sup 2-} organic carbon content was 3.0 +/- 1.0%. The pH was 13. A surprising result was that about 93% of the {sup 137}Cs in the centrifuged, wet sludge solids was bound in the solids and could not be solubilized by basic leaching at ambient temperature and 75 deg C. However, the solubility of the {sup 137}Cs was enhanced by heating the sludge to 95 deg C. In one of the tests,about 42% of the {sup 137}Cs was removed by leaching with 6.3 M NaOH at 95 deg C.Removing {sup 137}Cs from the W-25 sludge with nitric acid was a slow process. About 13% of the {sup 137}Cs was removed in 16 h with 3.0 M HNO{sub 3}. Only 22% of the {sup 137}Cs was removed in 117 h usi 6.0 M HNO{sub 3}. Successive leaching of sludge solids with 0.5 M, 3.0 M, 3.0 M; and 6.0 M HNO{sub 3} for a total mixing time of 558 h removed 84% of the {sup 137}Cs. The use of caustic leaching prior to HNO{sub 3} leaching, and the use of HF with HNO{sub 3} in acidic leaching, increased the rate of {sup 137}Cs dissolution. Gel formation proved to be one of the biggest problems associated with HNO{sub 3

  7. Actual ratios of triacylglycerol positional isomers consisting of saturated and highly unsaturated fatty acids in fishes and marine mammals.

    PubMed

    Gotoh, Naohiro; Matsumoto, Yumiko; Nagai, Toshiharu; Mizobe, Hoyo; Otake, Ikuko; Ichioka, Kenji; Kuroda, Ikuma; Watanabe, Hiroyuki; Noguchi, Noriko; Wada, Shun

    2011-07-15

    The distribution of fatty acid species at the (sn-1, 3) position or the (sn-2) position of triacylglycerol (TAG) in natural fats and oils has already been analysed by many researchers and several interesting results have been reported. However, most of these reports only focused on the distribution of fatty acids at the or positions in TAG, and did not take account of the combination of fatty acids in the TAG, i.e., the TAG positional isomers. In this study, the actual ratios of TAG positional isomer pairs, consisting of palmitic acid and highly unsaturated fatty acid (HUFA) such as DHA or EPA, in fish and marine mammals were investigated using a high-performance liquid chromatography/atmospheric pressure chemical ionisation-mass spectrometry (HPLC/APCI-MS) system equipped with tandem jointed non-endcapped polymeric ODS columns. The results show that for combinations of DHA or EPA with two palmitic acids in the TAG of marine mammals, binding was almost all at the α position. In contrast, binding of DHA or EPA was mainly at the β position in fish. The preferred DHA and EPA positions in TAG were the same in the same marine mammal or fish. The binding position tendency of HUFA in TAG positional isomers consisting of two HUFAs and one palmitic acid was the same as that for combinations of one HUFA and two palmitic acids. These results were interpreted as showing that the preferred fatty acid species of sn-glycerol-3-phosphate acyltransferase and 1-acyl-sn-glycerol-3-phosphate acyltransferase in marine mammals are different to those in fish and other animals, or that diacylglycerol acyltransferase in marine mammals favours 1,2-dipalmitoyl-sn-glycerol formed from 1,2-dipalmitoyl-sn-glycerol-3-phosphatidate if HUFA is the reaction substrate. Copyright © 2011 Elsevier Ltd. All rights reserved.

  8. Tanks and Tank Troops

    DTIC Science & Technology

    1982-03-01

    operational in the Bundeswehr. These include the well-known U.S. M113 APC, the HS-30 APC, developed by the Swiss company Hispano- Suiza , as well as the...powered by the Leyland L-60 engine, and the French AMX-30, powered by the Hispano- Suiza HS-110 engine. The new Japanese STB-6 tank (ඒ") is...of all foreign series-produced tank engines. A complete tank engine replacement can be performed in four hours. The Hispano- Suiza HS-110 engine

  9. Effect of acidity consumption/production on the pH of aeration tank during the biodegradation of acetic acid/epichlorohydrin.

    PubMed

    Yoon, Seong-Hoon; Kim, Hyung-Soo; Chung, Yun-Chul

    2002-06-01

    In order to elucidate the biologically driven pH fluctuation phenomena in industrial wastewater treatment, the contrary effects of acetic acid (AA) and epichlorohydrin (ECH) on the pH of aeration tank were investigated. Two simple equations were derived to estimate optimum neutralization pHs for the biological AA/ECH wastewater treatment, and the calculated optimum neutralization pHs were compared with experimental results. The pH in aeration tank was expected to fluctuate sharply with the smallest deviation of neutralization pH from the optimum value. However experimental results showed that real pH fluctuation is smaller than the theoretical one. It was considered that carbonate buffer in aqueous system relieves the pH fluctuation. The deviation between experimental and theoretical optimum neutralization pH could be mainly caused by volatility of AA and ECH. The deviation was larger with ECH wastewater of which volatility is larger than AA. Finally, this theory was successfully applied to the real petrochemical wastewater treatment. The pH of aeration tank was properly maintained when acidified wastewater (pH 3.4) was supplied.

  10. Characterization of the first core sample of neutralized current acid waste from double-shell tank 101-AZ

    SciTech Connect

    Peterson, M E; Scheele, R D; Tingey, J M

    1989-09-01

    In FY 1989, Westinghouse Hanford Company (WHC) successfully obtained four core samples (totaling seven segments) of neutralized current acid waste (NCAW) from double-shell tanks (DSTs) 101-AZ and 102-AZ. A segment was a 19-in.-long and 1-in.-diameter cylindrical sample of waste. A core sample consisted of enough 19-in.-long segments to obtain the waste of interest. Three core samples were obtained from DST 101-AZ and one core sample from DST 102-AZ. Two DST 101-AZ core samples consisted of two segments per core, and the third core sample consisted of only one segment. The third core consisted of the solids from the bottom of the tank and was used to determine the relative abrasiveness of this NCAW. The DST 102-AZ core sample consisted of two segments. The core samples were transported to the Pacific Northwest Laboratory (PNL), where the waste was extruded from its sampler and extensively characterized. A characterization plan was followed that simulated the processing of the NCAW samples through retrieval, pretreatment and vitrification process steps. Physical, rheological, chemical and radiochemical properties were measured throughout the process steps. The characterization of the first core sample from DST 101-AZ was completed, and the results are provided in this report. The results for the other core characterizations will be reported in future reports. 3 refs., 13 figs., 10 tabs.

  11. Nondeterministic computational fluid dynamics modeling of Escherichia coli inactivation by peracetic acid in municipal wastewater contact tanks.

    PubMed

    Santoro, Domenico; Crapulli, Ferdinando; Raisee, Mehrdad; Raspa, Giuseppe; Haas, Charles N

    2015-06-16

    Wastewater disinfection processes are typically designed according to heuristics derived from batch experiments in which the interaction among wastewater quality, reactor hydraulics, and inactivation kinetics is often neglected. In this paper, a computational fluid dynamics (CFD) study was conducted in a nondeterministic (ND) modeling framework to predict the Escherichia coli inactivation by peracetic acid (PAA) in municipal contact tanks fed by secondary settled wastewater effluent. The extent and variability associated with the observed inactivation kinetics were both satisfactorily predicted by the stochastic inactivation model at a 95% confidence level. Moreover, it was found that (a) the process variability induced by reactor hydraulics is negligible when compared to the one caused by inactivation kinetics, (b) the PAA dose required for meeting regulations is dictated equally by the fixed limit of the microbial concentration as well as its probability of occurrence, and (c) neglecting the probability of occurrence during process sizing could lead to an underestimation of the PAA dose required by as much as 100%. Finally, the ND-CFD model was used to generate sizing information in the form of probabilistic disinfection curves relating E. coli inactivation and probability of occurrence with the average PAA dose and PAA residual concentration at the outlet of the contact tank.

  12. Kinetic modeling and scale up of lipoic acid (LA) production from Saccharomyces cerevisiae in a stirred tank bioreactor.

    PubMed

    Jayakar, Shilpa S; Singhal, Rekha S

    2013-08-01

    Scale up studies for production of lipoic acid (LA) from Saccharomyces cerevisiae have been reported in this paper for the first time. LA production in batch mode was carried out in a stirred tank bioreactor at varying agitation and aeration with maximum LA production of 512 mg/L obtained at 350 rpm and 25 % dissolved oxygen in batch culture conditions. Thus, LA production increased from 352 mg/L in shake flask to 512 mg/L in batch mode in a 5 L stirred tank bioreactor. Biomass production under these conditions was mathematically explained using logistic equation and data obtained for LA production and substrate utilization were successfully fitted using Luedeking-Piret and Mercier's models. The kinetic studies showed LA production to be growth associated. Further enhancement of LA production was carried out using fed-batch (variable volume) and semi-continuous modes of fermentation. Semi-continuous fermentation with three feeding cycles of sucrose effectively increased the production of LA from 512 to 725 mg/L.

  13. Storage tank for cryogenic liquefied gas

    SciTech Connect

    Guilhem, J. R.

    1985-02-12

    The invention is related to a tank designed to contain a cryogenic liquefied gas and formed in addition to the main tank by two other tight walls. In the upper part of this tank an aperture duct connects the ceiling of the tank to the exterior of the tank, a holder supporting a device sensing in various areas wall temperatures of the tank, can be fitted into this aperture duct, a remote temperature sensor is actually hold by this support and is introduced into the tank. The invention finds an application as a means to easily localize leaking failures of the intermediate wall.

  14. Tank 241-AZ-101 tank characterization plan

    SciTech Connect

    Schreiber, R.D.

    1995-02-06

    The Defense Nuclear Facilities Safety Board has advised the DOE to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The Data Quality Objective (DQO) process was chosen as a tool to be used in the resolution of safety issues. As a result, A revision in the Federal Facilities Agreement and Consent Order (Tri-Party Agreement) milestone M-44 has been made, which states that ``A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process. Development of TCPs by the DQO process is intended to allow users to ensure their needs will be met and that resources are devoted to gaining only necessary information``. This document satisfies that requirement for Tank 241-AZ-101 (AZ-101) sampling activities. Tank AZ-101 is currently a non-Watch List tank, so the only DQOs applicable to this tank are the safety screening DQO and the compatibility DQO, as described below. The contents of Tank AZ-101, as of October 31, 1994, consisted of 3,630 kL (960 kgal) of dilute non-complexed waste and aging waste from PUREX (NCAW, neutralized current acid waste). Tank AZ-101 is expected to have two primary layers. The bottom layer is composed of 132 kL of sludge, and the top layer is composed of 3,500 kL of supernatant, with a total tank waste depth of approximately 8.87 meters.

  15. Integrated adsorptive technique for efficient recovery of m-cresol and m-toluidine from actual acidic and salty wastewater.

    PubMed

    Chen, Da; Liu, Fuqiang; Zong, Lidan; Sun, Xiaowen; Zhang, Xiaopeng; Zhu, Changqing; Tao, Xuewen; Li, Aimin

    2016-07-15

    An integrated adsorptive technique combining an m-cresol adsorption unit, an acid retardation unit and an m-toluidine adsorption unit in sequence was designed to recover m-cresol and m-toluidine from highly acidic and salty m-cresol manufacturing wastewater. In the first column packed with hypercrosslinked polymeric resin (NDA-99), most m-cresol was captured through π-π and hydrogen-bonding interactions as well as the salting-out effect, while m-toluidine was not absorbed due to protonation. To separate acid from salt, an acid retardation unit was introduced successively to adsorb sulfuric acid by strong base anion exchange resin (201×7). After the acid retardation unit and mild neutralization reaction, the last column filled with NDA-99 was applied to trap neutral m-toluidine from the salty effluent. Moreover, the eluent of the acid retardation unit was utilized as the regenerant to recover m-toluidine, and the recycled high-acidity and low-salinity solution of m-toluidine was directly used to produce m-cresol as the raw material. Therefore, the proposed method not only efficiently recycled m-cresol and m-toluidine, but also reduced the consumption of alkali dramatically (saving 0.1628t/t wastewater). These findings will inspire design of integrated adsorptive techniques for treating complex organic wastewater with high efficiency and low cost.

  16. Intake of Fish and Omega-3 (n-3) Fatty Acids: Effect on Humans During Actual and Simulated Weightlessness

    NASA Technical Reports Server (NTRS)

    Smith, S. M.; Pierson, D. L.; Mehta, S. K.; Zwart, S. R.

    2011-01-01

    Space flight has many negative effects on human physiology, including bone and muscle loss. Bone and muscle are two systems that are positively affected by dietary intake of fish and n-3 fatty acids. The mechanism is likely to be related to inhibition by n-3 fatty acids of inflammatory cytokines (such as TNF) and thus inhibition of downstream NF-kB activation. We have documented this effect in a 3-dimensional cell culture model, where NF-kB activation in osteoclasts was inhibited by eicosapentaenoic acid, an n-3 fatty acid. We have also indentified that NF-kB activation in peripheral blood mononuclear cells of Space Shuttle crews. We found that after Shuttle flights of 2 wk, expression of the protein p65 (evidence of NF-kB activation) was increased at landing (P less than 0.001). When evaluating the effects of n-3 fatty acid intake on bone breakdown after 60 d of bed rest (a weightlessness analog). We found that after 60 d of bed rest, greater intake of n-3 fatty acids was associated with less N-telopeptide excretion (Pearson r = -0.62, P less than 0.05). We also evaluated the relationship of fish intake and bone loss in astronauts after 4 to 6 mo missions on the International Space Station. Higher consumption of fish during flight was associated with higher bone mineral density (Pearson r = 0.46, P less than 0.05). Together, these findings provide evidence of the cellular mechanism by which n-3 fatty acids can inhibit bone loss, and preliminary human evidence of the potential for n-3 fatty acids to counteract bone loss associated with space flight. This study was supported by the NASA Human Research Program.

  17. Laboratory-Scale Column Testing Using IONSIV IE-911 for Removing Cesium from Acidic Tank Waste Simulant. 2: Determination of Cesium Exchange Capacity and Effective Mass Transfer Coefficient from a 500-cm3 Column Experiement

    SciTech Connect

    T.J. Tranter; R.D. Tillotson; T.A. Todd

    2005-04-01

    A semi-scale column test was performed using a commercial form of crystalline silicotitanate (CST) for removing radio-cesium from a surrogate acidic tank solution, which represents liquid waste stored at the Idaho National Engineering and Environmental Laboratory (INEEL). The engineered form of CST ion exchanger, known as IONSIVtmIE-911 (UOP, Mt. Laurel,NJ, USA), was tested in a 500-cm3 column to obtain a cesium breakthrough curve. The cesium exchange capacity of this column matched that obtained from previous testing with a 15-mc3 column. A numerical algorithm using implicit finite difference approximations was developed to solve the governing mass transport equations for the CST columns. An effective mass transfer coefficient was derived from solving these equations for previously reported 15 cm3 tests. The effective mass transfer coefficient was then used to predict the cesium breakthrough curve for the 500-cm3 column and compared to the experimental data reported in this paper. The calculated breakthrough curve showed excellent agreement with the data from the 500-cm3 column even though the interstitial velocity was a factor of two greater. Thus, this approach should provide a reasonable method for scale up to larger columns for treating actual tank waste.

  18. Intake of Fish and Omega-3 (N-3) Fatty Acid: Effect on Humans during Actual and Simulated Weightlessness

    NASA Technical Reports Server (NTRS)

    Smith, Scott M.; Mehta, Satish K.; Pierson, Duane L.; Zwart, Sara R.

    2009-01-01

    Space flight has many negative effects on human physiology, including bone and muscle loss. These are some of the systems on which intakes of fish and n-3 fatty acids have positive effects. These effects are likely to occur through inhibition of inflammatory cytokines (such as TNFalpha) and thus inhibition of downstream NF-KB activation. We documented this effect in a 3D cell culture model, where NF-KB activation in osteoclasts was inhibited by eicosapentaenoic acid, an n-3 fatty acid. We have extended these studies and report here (a) NF-KB expression in peripheral blood mononuclear cells of Space Shuttle crews on 2-wk missions, (b) the effects of n-3 fatty acid intake after 60 d of bed rest (a weightlessness analog), and (c) the effects of fish intake in astronauts after 4 to 6 mo on the International Space Station. After Shuttle flights of 2 wk, NFKB p65 expression at landing was increased (P less than 0.001). After 60 d of bed rest, higher intake of n-3 fatty acids was associated with less N-telopeptide excretion (Pearson r = -0.62, P less than 0.05). Higher consumption of fish during flight was associated with higher bone mineral density (Pearson r = -0.46, P less than 0.05). Together with our earlier findings, these data provide mechanistic cellular and preliminary human evidence of the potential for n-3 fatty acids to counteract bone loss associated with spaceflight. This study was supported by the NASA Human Research Program.

  19. Intake of Fish and Omega-3 (N-3) Fatty Acid: Effect on Humans during Actual and Simulated Weightlessness

    NASA Technical Reports Server (NTRS)

    Smith, Scott M.; Mehta, Satish K.; Pierson, Duane L.; Zwart, Sara R.

    2009-01-01

    Space flight has many negative effects on human physiology, including bone and muscle loss. These are some of the systems on which intakes of fish and n-3 fatty acids have positive effects. These effects are likely to occur through inhibition of inflammatory cytokines (such as TNFalpha) and thus inhibition of downstream NF-KB activation. We documented this effect in a 3D cell culture model, where NF-KB activation in osteoclasts was inhibited by eicosapentaenoic acid, an n-3 fatty acid. We have extended these studies and report here (a) NF-KB expression in peripheral blood mononuclear cells of Space Shuttle crews on 2-wk missions, (b) the effects of n-3 fatty acid intake after 60 d of bed rest (a weightlessness analog), and (c) the effects of fish intake in astronauts after 4 to 6 mo on the International Space Station. After Shuttle flights of 2 wk, NFKB p65 expression at landing was increased (P less than 0.001). After 60 d of bed rest, higher intake of n-3 fatty acids was associated with less N-telopeptide excretion (Pearson r = -0.62, P less than 0.05). Higher consumption of fish during flight was associated with higher bone mineral density (Pearson r = -0.46, P less than 0.05). Together with our earlier findings, these data provide mechanistic cellular and preliminary human evidence of the potential for n-3 fatty acids to counteract bone loss associated with spaceflight. This study was supported by the NASA Human Research Program.

  20. LEAD IMMOBILIZATION TECHNOLOGY UTILIZING POTASSIUM DEHYDROGEN PHOSPHATE AND ORGANIC ACID IN AN ACTUAL SHOOTING RANGE LEAD-CONTAMINATED SOIL

    NASA Astrophysics Data System (ADS)

    Yoshida, Takatoshi; Katoh, Masahiko; Sato, Takeshi

    This paper addressed potassium dehydrogen phosphate (KP) and acetic acid (OAc) amendments of neutral pH soil sampled from the lead contaminated soil in a shooting range to promote immobilization by modification of Pb speciation in solid and liquid phases. This study evaluated the amount of antimony leachability in the so il. The single KP application increased Pb and Sb leachabilitie s due to soil pH increase, wheres combined KP and OAc amendments decreased them in compar ison with the control. Sequential extraction analysis reveal ed that Pb residual fraction in KP amended soil increased to 72% than that in the control (5%). Th e residual fraction (82%) in KP an d OAc amended soil was higher than the single application of KP. This st udy indicated that combined appli catons of KP and OAc promoted Pb immobilization and suppressed Pb leachabilities.

  1. System Description for Tank 241-AZ-101 Waste Retrieval Data Acquisition System

    SciTech Connect

    ROMERO, S.G.

    2000-02-14

    The proposed activity provides the description of the Data Acquisition System for Tank 241-AZ-101. This description is documented in HNF-5572, Tank 241-AZ-101 Waste Retrieval Data Acquisition System (DAS). This activity supports the planned mixer pump tests for Tank 241-AZ-101. Tank 241-AZ-101 has been selected for the first full-scale demonstration of a mixer pump system. The tank currently holds over 960,000 gallons of neutralized current acid waste, including approximately 12.7 inches of settling solids (sludge) at the bottom of the tank. As described in Addendum 4 of the FSAR (LMHC 2000a), two 300 HP mixer pumps with associated measurement and monitoring equipment have been installed in Tank 241-AZ-101. The purpose of the Tank 241-AZ-101 retrieval system Data Acquisition System (DAS) is to provide monitoring and data acquisition of key parameters in order to confirm the effectiveness of the mixer pumps utilized for suspending solids in the tank. The suspension of solids in Tank 241-AZ-101 is necessary for pretreatment of the neutralized current acid waste and eventual disposal as glass via the Hanford Waste Vitrification Plant. HNF-5572 provides a basic description of the Tank 241-AZ-101 retrieval system DAS, including the field instrumentation and application software. The DAS is provided to fulfill requirements for data collection and monitoring. This document is not an operations procedure or is it intended to describe the mixing operation. This USQ screening provides evaluation of HNF-5572 (Revision 1) including the changes as documented on ECN 654001. The changes include (1) add information on historical trending and data backup, (2) modify DAS I/O list in Appendix E to reflect actual conditions in the field, and (3) delete IP address in Appendix F per Lockheed Martin Services, Inc. request.

  2. Think Tanks

    NASA Technical Reports Server (NTRS)

    2001-01-01

    A new inspection robot from Solex Robotics Systems was designed to eliminate hazardous inspections of petroleum and chemical storage tanks. The submersible robot, named Maverick, is used to inspect the bottoms of tanks, keeping the tanks operational during inspection. Maverick is able to provide services that will make manual tank inspections obsolete. While the inspection is conducted, Maverick's remote human operators remain safe outside of the tank. The risk to human health and life is now virtually eliminated. The risk to the environment is also minimal because there is a reduced chance of spillage from emptying and cleaning the tanks, where previously, tons of pollutants were released through the process of draining and refilling.

  3. 49 CFR 172.330 - Tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... DOT 107 tank cars only) Division 2.3 materials Formic acid Hydrocyanic acid, aqueous solutions Hydrofluoric acid, solution Hydrogen cyanide, stabilized (less than 3% water) Hydrogen fluoride, anhydrous... Hydrogen peroxide and peroxyacetic acid mixtures Nitric acid (other than red fuming) Phosphorus, amorphous...

  4. 49 CFR 172.330 - Tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... DOT 107 tank cars only) Division 2.3 materials Formic acid Hydrocyanic acid, aqueous solutions Hydrofluoric acid, solution Hydrogen cyanide, stabilized (less than 3% water) Hydrogen fluoride, anhydrous... Hydrogen peroxide and peroxyacetic acid mixtures Nitric acid (other than red fuming) Phosphorus, amorphous...

  5. 49 CFR 172.330 - Tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... DOT 107 tank cars only) Division 2.3 materials Formic acid Hydrocyanic acid, aqueous solutions Hydrofluoric acid, solution Hydrogen cyanide, stabilized (less than 3% water) Hydrogen fluoride, anhydrous... Hydrogen peroxide and peroxyacetic acid mixtures Nitric acid (other than red fuming) Phosphorus, amorphous...

  6. Uncoupled hydrogen and volatile fatty acids generation in a two-step biotechnological anaerobic process fed with actual site wastewater.

    PubMed

    Monti, Matilde; Scoma, Alberto; Martinez, Gonzalo; Bertin, Lorenzo; Fava, Fabio

    2015-05-25

    Among agro-wastes, olive mill wastewater (OMW) truly qualifies as a high impact organic residue due to its biochemical-rich composition and high annual production. In the present investigation, dephenolized OMW (OMWdeph) was employed as the feedstock for a biotechnological two-stage anaerobic process dedicated to the production of biohydrogen and volatile fatty acids (VFAs), respectively. To this end, two identically configured packed-bed biofilm reactors were operated sequentially. In the first, the hydraulic retention time was set to 1 day, whereas in the second it was equal to 5 days. The rationale was to decouple the hydrolysis of the organic macronutrients held by the OMWdeph, so as to quantitatively generate a biogas enriched in H2 (first stage aim), for the acidogenesis of the residual components left after hydrolysis, to then produce a highly concentrated mixture of VFAs (second stage aim). Results showed that the generation of H2 and VFAs was effectively split, with carbohydrates and lipids, respectively, being the main substrates of the two processes. About 250 ml H2 L(-1) day(-1) was produced, corresponding to a yield of 0.36 mol mol(-1) of consumed carbohydrates (expressed as glucose equivalents). The overall concentration of VFAs in the acidogenic process was 13.80 g COD L(-1), so that 2.76 g COD L(-1) day(-1) was obtained. Second generation biorefineries use a selected fraction of an organic waste to conduct a microbiologically-driven pathway towards the generation of one target molecule. With the proposed approach, a greater value of the waste was attained, since the multi-purpose two-stage process did not entail competition for substrates between the first and the second steps.

  7. SINDA/FLUINT Stratified Tank Modeling for Cryrogenic Propellant Tanks

    NASA Technical Reports Server (NTRS)

    Sakowski, Barbara

    2014-01-01

    A general purpose SINDA/FLUINT (S/F) stratified tank model was created to simulate self-pressurization and axial jet TVS; Stratified layers in the vapor and liquid are modeled using S/F lumps.; The stratified tank model was constructed to permit incorporating the following additional features:, Multiple or singular lumps in the liquid and vapor regions of the tank, Real gases (also mixtures) and compressible liquids, Venting, pressurizing, and draining, Condensation and evaporation/boiling, Wall heat transfer, Elliptical, cylindrical, and spherical tank geometries; Extensive user logic is used to allow detailed tailoring - Don't have to rebuilt everything from scratch!!; Most code input for a specific case is done through the Registers Data Block:, Lump volumes are determined through user input:; Geometric tank dimensions (height, width, etc); Liquid level could be input as either a volume percentage of fill level or actual liquid level height

  8. Composite Tank

    NASA Technical Reports Server (NTRS)

    DeLay, Thomas K. (Inventor)

    2000-01-01

    A composite tank for containing liquid oxygen and the method of making the same Wherein a water-soluble mandrel having ing the desired tank configuration and a cylindrical protuberance on at least one end is fitted with an inner boss conformance, to the configuration of the mandrel and in outer boss conforming to the configuration of the inner boss, the bosses each having a tubular portion for receiving the protuberance on the mandrel and a spherical portion. The mandrel and the bosses are first coated with a nickel coating. The mandrel is then wrapped with graphite fibers wetted with an epoxy resin and this resin is cured. A layer of insulating foam is then applied to the tank and cured. The insulating foam is machined to a desired concentration and a layer of aramid fibers wetted with a second epoxy resin is wrapped around the tank. The second resin is cured and the water soluble mandrel is washed from inside the tank.

  9. Actual ratios of triacylglycerol positional isomers and enantiomers comprising saturated fatty acids and highly unsaturated fatty acids in fishes and marine mammals.

    PubMed

    Nagai, Toshiharu; Matsumoto, Yumiko; Jiang, Yanying; Ishikawa, Keiko; Wakatabe, Tokuhisa; Mizobe, Hoyo; Yoshinaga, Kazuaki; Kojima, Koichi; Kuroda, Ikuma; Saito, Tadao; Beppu, Fumiaki; Gotoh, Naohiro

    2013-01-01

    It has been previously shown that the positional isomers of triacylglycerol (TAG) containing palmitic acid (P) and highly unsaturated fatty acids (HUFAs) such as DHA (D) and EPA (E) vary between fishes and marine mammals. However, it has not yet been understood why in marine mammals HUFAs are located only at the α position when two palmitic acid chains combine, and not in fishes. In order to gain further understanding of the biosynthetic pathways involved in the formation of these asymmetric TAGs, we investigated whether the HUFA in the TAG of marine mammals exists predominantly at the sn-1 or sn-3 position. We examined the TAG positional isomers and enantiomers in marine organisms in detail. As a result, while PDP and PEP were not detected, sn-PPD and sn-PPE were found in abundance in marine mammals. For fishes, on the other hand, PDP, PEP, sn-PPD, and sn-PPE were all identified. In the case of TAGs that contain two HUFAs and one palmitic acid, marine mammals were rich in DPD and EPE whereas fishes were rich in sn-PDD and sn-PEE.

  10. Tank 50H Tetraphenylborate Destruction Results

    SciTech Connect

    Peters, T.B.

    2003-10-03

    We conducted several scoping tests with both Tank 50H surrogate materials (KTPB and phenol) as well as with actual Tank 50H solids. These tests examined whether we could destroy the tetraphenylborate in the surrogates or actual Tank 50H material either by use of Fenton's Reagent or by hydrolysis (in Tank 50H conditions at a maximum temperature of 50 degrees C) under a range of conditions. The results of these tests showed that destruction of the solids occurred only under a minority of conditions. (1)Using Fenton's Reagent and KTPB as the Tank 50H surrogate, no reaction occurred at pH ranges greater than 9. (2)Using Fenton's Reagent and phenol as the Tank 50H surrogate, no reaction occurred at a pH of 14. (3)Using Fenton's Reagent and actual Tank 50H slurry, a reaction occurred at a pH of 9.5 in the presence of ECC additives. (4)Using Fenton's Reagent and actual Tank 50H slurry, after a thirty three day period, all attempts at hydrolysis (at pH 14) were too slow to be viable. This happened even in the case of higher temperature (50 degrees C) and added (100 ppm) copper. Tank 50H is scheduled to return to HLW Tank Farm service with capabilities of transferring and receiving salt supernate solutions to and from the Tank Farms and staging feed for the Saltstone Facility. Before returning Tank 50H to Tank Farm service as a non-organic tank, less than 5 kg of TPB must remain in Tank 50H. Recently, camera inspections in Tank 50H revealed two large mounds of solid material, one in the vicinity of the B5 Riser Transfer Pump and the other on the opposite side of the tank. Personnel sampled and analyzed this material to determine its composition. The sample analysis indicated presence of a significant quantity of organics in the solid material. This quantity of organic material exceeds the 5 kg limit for declaring only trace amounts of organic material remain in Tank 50H. Additionally, these large volumes of solids, calculated as approximately 61K gallons, present other

  11. CORROSION TESTING IN SIMULATED TANK SOLUTIONS

    SciTech Connect

    Hoffman, E.

    2010-12-09

    Three simulated waste solutions representing wastes from tanks SY-102 (high nitrate, modified to exceed guidance limits), AN-107, and AY-102 were supplied by PNNL. Out of the three solutions tested, both optical and electrochemical results show that carbon steel samples corroded much faster in SY-102 (high nitrate) than in the other two solutions with lower ratios of nitrate to nitrite. The effect of the surface preparation was not as strong as the effect of solution chemistry. In areas with pristine mill-scale surface, no corrosion occurred even in the SY-102 (high nitrate) solution, however, corrosion occurred in the areas where the mill-scale was damaged or flaked off due to machining. Localized corrosion in the form of pitting in the vapor space of tank walls is an ongoing challenge to overcome in maintaining the structural integrity of the liquid waste tanks at the Savannah River and Hanford Sites. It has been shown that the liquid waste condensate chemistry influences the amount of corrosion that occurs along the walls of the storage tanks. To minimize pitting corrosion, an effort is underway to gain an understanding of the pitting response in various simulated waste solutions. Electrochemical testing has been used as an accelerated tool in the investigation of pitting corrosion. While significant effort has been undertaken to evaluate the pitting susceptibility of carbon steel in various simulated waste solutions, additional effort is needed to evaluate the effect of liquid waste supernates from six Hanford Site tanks (AY-101, AY-102, AN-102, AN-107, SY-102 (high Cl{sup -}), and SY-102 (high nitrate)) on carbon steel. Solutions were formulated at PNNL to replicate tank conditions, and in the case of SY-102, exceed Cl{sup -} and NO{sub 3}{sup -} conditions, respectively, to provide a contrast between in and out of specification limits. The majority of previous testing has been performed on pristine polished samples. To evaluate the actual tank carbon steel

  12. Management practices, physically effective fiber, and ether extract are related to bulk tank milk de novo fatty acid concentration on Holstein dairy farms.

    PubMed

    Woolpert, M E; Dann, H M; Cotanch, K W; Melilli, C; Chase, L E; Grant, R J; Barbano, D M

    2017-04-05

    The objective of this study was to evaluate the relationship of management practices and dietary factors with de novo fatty acid concentration in bulk tank milk from commercial dairy farms milking Holstein cows. Farms were selected based on de novo fatty acid concentration during the 6 mo before the farm visit and were categorized as high de novo (HDN; 24.61 ± 0.75 g/100 g of fatty acids, mean ± standard deviation; n = 19) or low de novo (LDN; 23.10 ± 0.88 g/100 g of fatty acids; n = 20). Farms were visited once in February, March, or April 2015 and evaluated based on management and facility design known to affect cow behavior, physical and chemical characteristics of the diet, and ration formulation and forage analyses obtained from the farm's nutritionist. We observed no differences between HDN and LDN farms in farm size, time away from the pen for milking, days in milk, or body condition score. We detected no differences between HDN and LDN farms in milk fat or true protein yield; however, milk fat and protein content and de novo fatty acid yield per day were higher for HDN farms, as was gross income per unit of milk sold. High de novo farms tended to be more likely to deliver fresh feed twice versus once per day, have a freestall stocking density ≤110%, and provide ≥46 cm of feed bunk space per cow. We observed no detectable differences in forage quality or ration dry matter, crude protein, or starch content. However, ether extract was lower and physically effective neutral detergent fiber was higher for HDN farms. Feeding management, stocking density, dietary ether extract content, and the physical characteristics of the diet are related to de novo fatty acid, fat, and protein concentration in bulk tank milk from high-producing Holstein dairy farms.

  13. TESTING OF THE SPINTEK ROTARY MICROFILTER USING ACTUAL HANFORD WASTE SAMPLES

    SciTech Connect

    HUBER HJ

    2010-04-13

    The SpinTek rotary microfilter was tested on actual Hanford tank waste. The samples were a composite of archived Tank 241-AN-105 material and a sample representing single-shell tanks (SST). Simulants of the two samples have been used in non-rad test runs at the 222-S laboratory and at Savannah River National Laboratory (SRNL). The results of these studies are compared in this report. Two different nominal pore sizes for the sintered steel rotating disk filter were chosen: 0.5 and 0.1 {micro}m. The results suggest that the 0.5-{micro}m disk is preferable for Hanford tank waste for the following reasons: (1) The filtrate clarity is within the same range (<<4 ntu for both disks); (2) The filtrate flux is in general higher for the 0.5-{micro}m disk; and (3) The 0.1-{micro}m disk showed a higher likelihood of fouling. The filtrate flux of the actual tank samples is generally in the range of 20-30% compared to the equivalent non-rad tests. The AN-105 slurries performed at about twice the filtrate flux of the SST slurries. The reason for this difference has not been identified. Particle size distributions in both cases are very similar; comparison of the chemical composition is not conclusive. The sole hint towards what material was stuck in the filter pore holes came from the analysis of the dried flakes from the surface of the fouled 0.1-{micro}m disk. A cleaning approach developed by SRNL personnel to deal with fouled disks has been found adaptable when using actual Hanford samples. The use of 1 M nitric acid improved the filtrate flux by approximately two times; using the same simulants as in the non-rad test runs showed that the filtrate flux was restored to 1/2 of its original amount.

  14. ANALYSIS OF SAMPLES FROM TANK 6F CHEMICAL CLEANING

    SciTech Connect

    Poirier, M.; Fink, S.

    2010-02-02

    Savannah River Remediation (SRR) is preparing Tank 6F for closure. The first step in preparing the tank for closure is mechanical sludge removal. In mechanical sludge removal, personnel add liquid (e.g., inhibited water or supernate salt solution) to the tank to form a slurry. They mix the liquid and sludge with pumps, and transfer the slurry to another tank for further processing. Mechanical sludge removal effectively removes the bulk of the sludge from a tank, but is not able to remove all of the sludge. In Tank 6F, SRR estimated a sludge heel of 5,984 gallons remained after mechanical sludge removal. To remove this sludge heel, SRR performed chemical cleaning. The chemical cleaning included two oxalic acid strikes, a spray wash, and a water wash. SRR conducted the first oxalic acid strike as follows. Personnel added 110,830 gallons of 8 wt % oxalic acid to Tank 6F and mixed the contents of Tank 6F with two submersible mixer pumps (SMPs) for approximately four days. Following the mixing, they transferred 115,903 gallons of Tank 6F material to Tank 7F. The SMPs were operating when the transfer started and were shut down approximately five hours after the transfer started. SRR collected a sample of the liquid from Tank 6F and submitted it to SRNL for analysis. Mapping of the tank following the transfer indicated that 2,400 gallons of solids remained in the tank. SRR conducted the second oxalic acid strike as follows. Personnel added 28,881 gallons of 8 wt % oxalic acid to Tank 6F. Following the acid addition, they visually inspected the tank and transferred 32,247 gallons of Tank 6F material to Tank 7F. SRR collected a sample of the liquid from Tank 6F and submitted it to SRNL for analysis. Mapping of the tank following the transfer indicated that 3,248 gallons of solids remained in the tank. Following the oxalic acid strikes, SRR performed Spray Washing with oxalic acid to remove waste collected on internal structures, cooling coils, tank top internals, and tank

  15. Dual Tank Fuel System

    DOEpatents

    Wagner, Richard William; Burkhard, James Frank; Dauer, Kenneth John

    1999-11-16

    A dual tank fuel system has primary and secondary fuel tanks, with the primary tank including a filler pipe to receive fuel and a discharge line to deliver fuel to an engine, and with a balance pipe interconnecting the primary tank and the secondary tank. The balance pipe opens close to the bottom of each tank to direct fuel from the primary tank to the secondary tank as the primary tank is filled, and to direct fuel from the secondary tank to the primary tank as fuel is discharged from the primary tank through the discharge line. A vent line has branches connected to each tank to direct fuel vapor from the tanks as the tanks are filled, and to admit air to the tanks as fuel is delivered to the engine.

  16. Think Tank.

    ERIC Educational Resources Information Center

    Governick, Heather; Wellington, Thom

    1998-01-01

    Examines the options for upgrading, replacing, and removal or closure of underground storage tanks (UST). Reveals the diverse regulatory control involving USTs, the Environmental Protection Agency's interest in pursuing violators, and stresses the need for administrators to be knowledgeable about state and local agency definitions of regulated…

  17. Hydrolysis-acidogenesis of food waste in solid-liquid-separating continuous stirred tank reactor (SLS-CSTR) for volatile organic acid production.

    PubMed

    Karthikeyan, Obulisamy Parthiba; Selvam, Ammaiyappan; Wong, Jonathan W C

    2016-01-01

    The use of conventional continuous stirred tank reactor (CSTR) can affect the methane (CH4) recovery in a two-stage anaerobic digestion of food waste (FW) due to carbon short circuiting in the hydrolysis-acidogenesis (Hy-Aci) stage. In this research, we have designed and tested a solid-liquid-separating CSTR (SLS-CSTR) for effective Hy-Aci of FW. The working conditions were pH 6 and 9 (SLS-CSTR-1 and -2, respectively); temperature-37°C; agitation-300rpm; and organic loading rate (OLR)-2gVSL(-1)day(-1). The volatile fatty acids (VFA), enzyme activities and bacterial population (by qPCR) were determined as test parameters. Results showed that the Hy-Aci of FW at pH 9 produced ∼35% excess VFA as compared to that at pH 6, with acetic and butyric acids as major precursors, which correlated with the high enzyme activities and low lactic acid bacteria. The design provided efficient solid-liquid separation there by improved the organic acid yields from FW. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Distributions of 14 elements on 60 selected absorbers from two simulant solutions (acid-dissolved sludge and alkaline supernate) for Hanford HLW Tank 102-SY

    SciTech Connect

    Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.

    1993-10-01

    Sixty commercially available or experimental absorber materials were evaluated for partitioning high-level radioactive waste. These absorbers included cation and anion exchange resins, inorganic exchangers, composite absorbers, and a series of liquid extractants sorbed on porous support-beads. The distributions of 14 elements onto each absorber were measured from simulated solutions that represent acid-dissolved sludge and alkaline supernate solutions from Hanford high-level waste (HLW) Tank 102-SY. The selected elements, which represent fission products (Ce, Cs, Sr, Tc, and Y); actinides (U, Pu, and Am); and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr), were traced by radionuclides and assayed by gamma spectrometry. Distribution coefficients for each of the 1680 element/absorber/solution combinations were measured for dynamic contact periods of 30 min, 2 h, and 6 h to provide sorption kinetics information for the specified elements from these complex media. More than 5000 measured distribution coefficients are tabulated.

  19. Process chemistry for the pretreatment of Hanford tank wastes

    SciTech Connect

    Lumetta, G.J.; Swanson, J.L.; Barker, S.A.

    1992-08-01

    Current guidelines for disposing radioactive wastes stored in underground tanks at the US Department of Energy`s Hanford Site call for the vitrification of high-level waste in borosilicate glass and disposal of the glass canisters in a deep geologic repository. Low-level waste is to be cast in grout and disposed of on site in shallow burial vaults. Because of the high cost of vitrification and geologic disposal, methods are currently being developed to minimize the volume of high-level waste requiring disposal. Two approaches are being considered for pretreating radioactive tank sludges: (1) leaching of selected components from the sludge and (2) acid dissolution of the sludge followed by separation of key radionuclides. The leaching approach offers the advantage of simplicity, but the acid dissolution/radionuclide extraction approach has the potential to produce the least number of glass canisters. Four critical components (Cr, P, S, and Al) were leached from an actual Hanford tank waste-Plutonium Finishing Plant sludge. The Al, P, and S were removed from the sludge by digestion of the sludge with 0.1 M NaOH at 100{degrees}C. The Cr was leached by treating the sludge with alkaline KMnO{sub 4} at 100{degrees}C. Removing these four components from the sludge will dramatically lower the number of glass canisters required to dispose of this waste. The transuranic extraction (TRUEX) solvent extraction process has been demonstrated at a bench scale using an actual Hanford tank waste. The process, which involves extraction of the transuranic elements with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO), separated 99.9% of the transuranic elements from the bulk components of the waste. Several problems associated with the TRUEX processing of this waste have been addressed and solved.

  20. Tank 241-U-204 tank characterization plan

    SciTech Connect

    Bell, K.E.

    1995-03-23

    This document is the tank characterization plan for Tank 241-U-204 located in the 200 Area Tank Farm on the Hanford Reservation in Richland, Washington. This plan describes Data Quality Objectives (DQO) and presents historical information and scheduled sampling events for tank 241-U-204.

  1. Tank Insulation

    NASA Technical Reports Server (NTRS)

    1979-01-01

    For NASA's Apollo program, McDonnell Douglas Astronautics Company, Huntington Beach, California, developed and built the S-IVB, uppermost stage of the three-stage Saturn V moonbooster. An important part of the development task was fabrication of a tank to contain liquid hydrogen fuel for the stage's rocket engine. The liquid hydrogen had to be contained at the supercold temperature of 423 degrees below zero Fahrenheit. The tank had to be perfectly insulated to keep engine or solar heat from reaching the fuel; if the hydrogen were permitted to warm up, it would have boiled off, or converted to gaseous form, reducing the amount of fuel available to the engine. McDonnell Douglas' answer was a supereffective insulation called 3D, which consisted of a one-inch thickness of polyurethane foam reinforced in three dimensions with fiberglass threads. Over a 13-year development and construction period, the company built 30 tanks and never experienced a failure. Now, after years of additional development, an advanced version of 3D is finding application as part of a containment system for transporting Liquefied Natural Gas (LNG) by ship.

  2. Feed tank transfer requirements

    SciTech Connect

    Freeman-Pollard, J.R.

    1998-09-16

    This document presents a definition of tank turnover. Also, DOE and PC responsibilities; TWRS DST permitting requirements; TWRS Authorization Basis (AB) requirements; TWRS AP Tank Farm operational requirements; unreviewed safety question (USQ) requirements are presented for two cases (i.e., tank modifications occurring before tank turnover and tank modification occurring after tank turnover). Finally, records and reporting requirements, and documentation which will require revision in support of transferring a DST in AP Tank Farm to a privatization contractor are presented.

  3. Burkholderia heleia sp. nov., a nitrogen-fixing bacterium isolated from an aquatic plant, Eleocharis dulcis, that grows in highly acidic swamps in actual acid sulfate soil areas of Vietnam.

    PubMed

    Aizawa, Tomoko; Ve, Nguyen Bao; Nakajima, Mutsuyasu; Sunairi, Michio

    2010-05-01

    Nitrogen-fixing bacteria, strains SA41(T), SA42 and SA53, were isolated from an aquatic plant, Eleocharis dulcis, that grows in highly acidic swamps (pH 2-4) in actual acid sulfate soil areas of Vietnam. The isolates were Gram-negative, aerobic, non-spore-forming, rod-shaped bacteria, having a cell width of 0.6-0.7 microm and a length of 1.5-1.7 microm. They showed good growth between pH 3.0 and 7.0, and between 17 and 37 degrees C. The organisms contained ubiquinone Q-8 as the predominant isoprenoid quinone, and C(16 : 0), C(17 : 0) cyclo, C(18 : 1) omega7c and summed feature 3 (C(16 : 1) omega7c and/or iso-C(15 : 0) 2-OH) as major fatty acids. Their fatty acid profiles are similar to those reported for other Burkholderia species. The DNA G+C content of these strains was 64 mol%. On the basis of 16S rRNA gene sequence similarity, these strains were shown to belong to the genus Burkholderia. Although their calculated 16S rRNA gene sequence similarity values to Burkholderia silvatlantica, Burkholderia mimosarum, Burkholderia ferrariae and Burkholderia tropica were 98.5, 98.2, 98.0 and 97.0 %, respectively, the isolates formed a distinct group in phylogenetic trees, and the DNA-DNA relatedness values of strain SA41(T) to these species were 39, 41, 39 and 33 %, respectively. The results of physiological and biochemical tests, including whole-cell protein pattern analysis, allowed phenotypic differentiation of these strains from the published Burkholderia species. Therefore, strains SA41(T), SA42 and SA53 represent a novel species for which the name Burkholderia heleia sp. nov. is proposed. The type strain is SA41(T) (=NBRC 101817(T)=VTCC-D6-7(T)).

  4. Phase Chemistry of Tank Sludge Residual Components

    SciTech Connect

    J.L. Krumhansl

    2002-04-02

    The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate nearby groundwaters with radionuclides and RCRA metals. Performance assessment (PA) calculations must be carried out prior to closing the tanks. This requires developing radionuclide release models from the sludges so that the PA calculations can be based on credible source terms. These efforts continued to be hindered by uncertainties regarding the actual nature of the tank contents and the distribution of radionuclides among the various phases. In particular, it is of vital importance to know what radionuclides are associated with solid sludge components. Experimentation on actual tank sludges can be difficult, dangerous and prohibitively expensive. The research funded under this grant for the past three years was intended to provide a cost-effective method for developing the needed radionuclide release models using non-radioactive artificial sludges. Insights gained from this work will also have more immediate applications in understanding the processes responsible for heel development in the tanks and in developing effective technologies for removing wastes from the tanks.

  5. ACTUAL-WASTE TESTING OF ULTRAVIOLET LIGHT TO AUGMENT THE ENHANCED CHEMICAL CLEANING OF SRS SLUDGE

    SciTech Connect

    Martino, C.; King, W.; Ketusky, E.

    2012-07-10

    In support of Savannah River Site (SRS) tank closure efforts, the Savannah River National Laboratory (SRNL) conducted Real Waste Testing (RWT) to evaluate Enhanced Chemical Cleaning (ECC), an alternative to the baseline 8 wt% oxalic acid (OA) chemical cleaning technology for tank sludge heel removal. ECC utilizes a more dilute OA solution (2 wt%) and an oxalate destruction technology using ozonolysis with or without the application of ultraviolet (UV) light. SRNL conducted tests of the ECC process using actual SRS waste material from Tanks 5F and 12H. The previous phase of testing involved testing of all phases of the ECC process (sludge dissolution, OA decomposition, product evaporation, and deposition tank storage) but did not involve the use of UV light in OA decomposition. The new phase of testing documented in this report focused on the use of UV light to assist OA decomposition, but involved only the OA decomposition and deposition tank portions of the process. Compared with the previous testing at analogous conditions without UV light, OA decomposition with the use of UV light generally reduced time required to reach the target of <100 mg/L oxalate. This effect was the most pronounced during the initial part of the decomposition batches, when pH was <4. For the later stages of each OA decomposition batch, the increase in OA decomposition rate with use of the UV light appeared to be minimal. Testing of the deposition tank storage of the ECC product resulted in analogous soluble concentrations regardless of the use or non-use of UV light in the ECC reactor.

  6. STATUS OF CHEMICAL CLEANING OF WASTE TANKS AT THE SAVANNAH RIVER SITE F TANK FARM CLOSURE PROJECT - 9114

    SciTech Connect

    Thaxton, D; Geoff Clendenen, G; Willie Gordon, W; Samuel Fink, S; Michael Poirier, M

    2008-12-31

    Chemical Cleaning is currently in progress for Tanks 5 and 6 at the Savannah River Site. The Chemical Cleaning process is being utilized to remove the residual waste heel remaining after completion of Mechanical Sludge Removal. This work is required to prepare the tanks for closure. Tanks 5 and 6 are 1950s vintage carbon steel waste tanks that do not meet current containment standards. These tanks are 22.9 meters (75 feet) in diameter, 7.5 meters (24.5 feet) in height, and have a capacity of 2.84E+6 liters (750,000 gallons). Chemical Cleaning adds 8 wt % oxalic acid to the carbon steel tank to dissolve the remaining sludge heel. The resulting acidic waste solution is transferred to Tank 7 where it is pH adjusted to minimize corrosion of the carbon steel tank. The Chemical Cleaning flowsheet includes multiple strikes of acid in each tank. Acid is delivered by tanker truck and is added to the tanks through a hose assembly connected to a pipe penetration through the tank top. The flowsheet also includes spray washing with acid and water. This paper includes an overview of the configuration required for Chemical Cleaning, the planned flowsheet, and an overview of technical concerns associated with the process. In addition, the current status of the Chemical Cleaning process in Tanks 5 and 6, lessons learned from the execution of the process, and the path forward for completion of cleaning in Tanks 5 and 6 will also be discussed.

  7. CALCULATION OF THE EFFECT OF TANK 241-C-106 RETRIEVAL ON CHEMISTRY CONTROL OF TANK 241-AN-106

    SciTech Connect

    CAROTHERS, K.G.

    2003-05-30

    In preparation for the retrieval and transfer of the tank 241-C-106 sludge to double-shell tank storage, concentrated caustic (sodium hydroxide) needs to be added to the receiver, tank 241-AN-106, to ensure compliance with the AC 5.15, ''Corrosion Mitigation Program,'' chemistry control limits. The tank 241-C-106 sludge will be retrieved by dissolving the sludge using oxalic acid. The hydroxide content of AN-106 needs to be sufficient to neutralize the incoming acid waste stream.

  8. Management, nutrition, and lactation performance are related to bulk tank milk de novo fatty acid concentration on northeastern US dairy farms.

    PubMed

    Woolpert, M E; Dann, H M; Cotanch, K W; Melilli, C; Chase, L E; Grant, R J; Barbano, D M

    2016-10-01

    This study investigated the relationship of management practices, dietary characteristics, milk composition, and lactation performance with de novo fatty acid (FA) concentration in bulk tank milk from commercial dairy farms with Holstein, Jersey, and mixed-breed cows. It was hypothesized that farms with higher de novo milk FA concentrations would more commonly use management and nutrition practices known to optimize ruminal conditions that enhance de novo synthesis of milk FA. Farms (n=44) located in Vermont and northeastern New York were selected based on a history of high de novo (HDN; 26.18±0.94g/100g of FA; mean ± standard deviation) or low de novo (LDN; 24.19±1.22g/100g of FA) FA in bulk tank milk. Management practices were assessed during one visit to each farm in March or April, 2014. Total mixed ration samples were collected and analyzed for chemical composition using near infrared spectroscopy. We found no differences in days in milk at the farm level. Yield of milk fat, true protein, and de novo FA per cow per day were higher for HDN versus LDN farms. The HDN farms had lower freestall stocking density (cows/stall) than LDN farms. Additionally, tiestall feeding frequency was higher for HDN than LDN farms. No differences between HDN and LDN farms were detected for dietary dry matter, crude protein, neutral detergent fiber, starch, or percentage of forage in the diet. However, dietary ether extract was lower for HDN than LDN farms. This research indicates that overcrowded freestalls, reduced feeding frequency, and greater dietary ether extract content are associated with lower de novo FA synthesis and reduced milk fat and true protein yields on commercial dairy farms.

  9. 49 CFR 172.331 - Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. 172.331 Section 172.331 Transportation Other Regulations... packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. (a) Each...

  10. 49 CFR 172.331 - Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. 172.331 Section 172.331 Transportation Other Regulations... packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. (a) Each...

  11. 49 CFR 172.331 - Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 2 2014-10-01 2014-10-01 false Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. 172.331 Section 172.331 Transportation Other Regulations... packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. (a) Each...

  12. 49 CFR 172.331 - Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. 172.331 Section 172.331 Transportation Other Regulations... packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. (a) Each...

  13. 49 CFR 172.331 - Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false Bulk packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. 172.331 Section 172.331 Transportation Other Regulations... packagings other than portable tanks, cargo tanks, tank cars and multi-unit tank car tanks. (a) Each...

  14. Effects of organic loading rate on hydrogen and volatile fatty acid production and microbial community during acidogenic hydrogenesis in a continuous stirred tank reactor using molasses wastewater.

    PubMed

    Yun, J; Cho, K-S

    2016-12-01

    Microbial community associated with hydrogen production and volatile fatty acids (VFAs) accumulation was characterized in acidogenic hydrogenesis using molasses wastewater as a feedstock. Hydrogen and VFAs production were measured under an organic loading rate (OLR) from 19 to 35 g-COD l(-1)  day(-1) . The active microbial community was analysed using RNA-based massively parallel sequencing technique, and their correlation patterns were analysed using networking analysis. The continuous stirred tank reactor achieved stable hydrogen production at different OLR conditions, and the maximum hydrogen production rate (HPR) was 1·02 L-H2  l(-1)  day(-1) at 31·0 g-COD l(-1)  day(-1) . Butyrate (50%) and acetate (38%) positively increased with increase in OLR. Total VFA production stayed around 7135 mg l(-1) during the operation period. Although Clostridiales and Lactobacillales were relatively abundant, the HPR was positively associated with Pseudomonadaceae and Micrococcineae. Total VFA and acetate, butyrate and propionate concentrations were positively correlated with lactic acid bacteria (LAB) such as Bacillales, Sporolactobacillus and Lactobacillus. The close relationship between Pseudomonadaceae and Micrococcineae, and LAB play important roles for stable hydrogen and VFA production from molasses wastewater. Microbial information on hydrogen and VFA production can be useful to design and operate for acidogenic hydrogenesis using high strength molasses wastewater. © 2016 The Society for Applied Microbiology.

  15. Evaluation of coupons from Tank 50

    SciTech Connect

    Mickalonis, J.I.

    1995-09-01

    The coupons from the corrosion coupon rig (CCR) were removed from tank 50 after a ten-month exposure. The evaluation consisted of microscopic examination, weight losses, and pit depth measurements. The coupons were exposed in both the liquid waste and the air space above the waste. The corrosion in the air space was characterized by variable-depth degradation under adherent corrosion products. Corrosion degradation was not significant for coupons in the waste. The coupon areas exposed at the air-waste interface had pits; the deepest measuring 6 mils. These results provide cur-rent information on actual corrosion in the waste tank. Continued use of the CCR on tank 50 is recommended (i) to monitor pitting rates, (ii) to verify the low corrosion degradation of the tanks, and (iii) to complete the CCR development for future implementation in tanks 43 and 48.

  16. AX Tank Farm tank removal study

    SciTech Connect

    SKELLY, W.A.

    1999-02-24

    This report examines the feasibility of remediating ancillary equipment associated with the 241-AX Tank Farm at the Hanford Site. Ancillary equipment includes surface structures and equipment, process waste piping, ventilation components, wells, and pits, boxes, sumps, and tanks used to make waste transfers to/from the AX tanks and adjoining tank farms. Two remedial alternatives are considered: (1) excavation and removal of all ancillary equipment items, and (2) in-situ stabilization by grout filling, the 241-AX Tank Farm is being employed as a strawman in engineering studies evaluating clean and landfill closure options for Hanford single-shell tanks. This is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms.

  17. Tank 241-U-203: Tank Characterization Plan

    SciTech Connect

    Sathyanarayana, P.

    1995-03-27

    The revised Federal Facility Agreement and Consent Order states that a tank characterization plan will be developed for each double-shell tank and single-shell tank using the data quality objective process. The plans are intended to allow users and regulators to ensure their needs will be met and resources are devoted to gaining only necessary information. This document satisfies that requirement for Tank 241-U-203 sampling activities.

  18. Waste Tank Heel Chemical Cleaning Summary

    SciTech Connect

    Barnes, M.J.

    2003-12-02

    At the Savannah River Site in Aiken, South Carolina, there are approximately 40 million gallons of legacy High Level Waste stored in large capacity sub-surface tanks. Twelve of these tanks are single-containment, non-conforming tanks with leaks. These tanks were built in the 1950s. Some of these tanks contain sludge heels and are being considered for near-term removal efforts and vitrification. Currently, only mechanical methods (i.e., pumps) are used to remove the sludge waste with varying degrees of success. To provide for additional levels of removal, chemically-aided techniques are being considered. The objective of the was to collect and evaluate information available on chemical-based methods for removing residual solids from the Site's waste tanks. As part of this study, the team was requested to develop recommendations for chemical treatments to remove residual heels (primarily sludge). Ideally, one agent alone would be efficient at dissolving all residual tank heels and yet satisfy all safety and process concerns. No such chemical cleaning agent was found. The cleaning agents identified from the literature, included oxalic acid, a mixture of oxalic acid and citric acid, a combination of oxalic acid with hydrogen peroxide, nitric acid, formic acid, and organics. A criteria matrix for evaluating the various cleaning agents was developed. The results of the evaluation conclusively support oxalic acid as the cleaning agent of choice for the immediate future. Oxalic acid scored nearly double the next closest cleaning agent. Nitric acid, formic acid, and oxalic acid with hydrogen peroxide were all closely grouped for the next best choice. The mixture of oxalic acid and citric acid rated poorly. Organics rated even more poorly due to large uncertainties in performance and downstream impacts.

  19. 49 CFR 172.330 - Tank cars and multi-unit tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 2 2012-10-01 2012-10-01 false Tank cars and multi-unit tank car tanks. 172.330..., TRAINING REQUIREMENTS, AND SECURITY PLANS Marking § 172.330 Tank cars and multi-unit tank car tanks. (a... material— (1) In a tank car unless the following conditions are met: (i) The tank car must be marked...

  20. USE OF AN EQUILIBRIUM MODEL TO FORECAST DISSOLUTION EFFECTIVENESS, SAFETY IMPACTS, AND DOWNSTREAM PROCESSABILITY FROM OXALIC ACID AIDED SLUDGE REMOVAL IN SAVANNAH RIVER SITE HIGH LEVEL WASTE TANKS 1-15

    SciTech Connect

    KETUSKY, EDWARD

    2005-10-31

    This thesis details a graduate research effort written to fulfill the Magister of Technologiae in Chemical Engineering requirements at the University of South Africa. The research evaluates the ability of equilibrium based software to forecast dissolution, evaluate safety impacts, and determine downstream processability changes associated with using oxalic acid solutions to dissolve sludge heels in Savannah River Site High Level Waste (HLW) Tanks 1-15. First, a dissolution model is constructed and validated. Coupled with a model, a material balance determines the fate of hypothetical worst-case sludge in the treatment and neutralization tanks during each chemical adjustment. Although sludge is dissolved, after neutralization more is created within HLW. An energy balance determines overpressurization and overheating to be unlikely. Corrosion induced hydrogen may overwhelm the purge ventilation. Limiting the heel volume treated/acid added and processing the solids through vitrification is preferred and should not significantly increase the number of glass canisters.

  1. Thermally resistant polymers for fuel tank sealants

    NASA Technical Reports Server (NTRS)

    Webster, J. A.

    1972-01-01

    Conversion of fluorocarbon dicarboxylic acid to intermediates whose terminal functional groups permit polymerization is discussed. Resulting polymers are used as fuel tank sealers for jet fuels at elevated temperatures. Stability and fuel resistance of the prototype polymers is explained.

  2. AX Tank Farm tank removal study

    SciTech Connect

    SKELLY, W.A.

    1998-10-14

    This report considers the feasibility of exposing, demolishing, and removing underground storage tanks from the 241-AX Tank Farm at the Hanford Site. For the study, it was assumed that the tanks would each contain 360 ft{sup 3} of residual waste (corresponding to the one percent residual Inventory target cited in the Tri-Party Agreement) at the time of demolition. The 241-AX Tank Farm is being employed as a ''strawman'' in engineering studies evaluating clean and landfill closure options for Hanford single-shell tank farms. The report is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms.

  3. HANFORD TANK CLEANUP UPDATE

    SciTech Connect

    BERRIOCHOA MV

    2011-04-07

    Access to Hanford's single-shell radioactive waste storage tank C-107 was significantly improved when workers completed the cut of a 55-inch diameter hole in the top of the tank. The core and its associated cutting equipment were removed from the tank and encased in a plastic sleeve to prevent any potential spread of contamination. The larger tank opening allows use of a new more efficient robotic arm to complete tank retrieval.

  4. Tank 241-C-103 tank characterization plan

    SciTech Connect

    Schreiber, R.D.

    1994-10-06

    The data quality objective (DQO) process was chosen as a tool to be used to identify the sampling analytical needs for the resolution of safety issues. A Tank Characterization Plant (TCP) will be developed for each double shell tank (DST) and single-shell tank (SST) using the DQO process. There are four Watch list tank classifications (ferrocyanide, organic salts, hydrogen/flammable gas, and high heat load). These classifications cover the six safety issues related to public and worker health that have been associated with the Hanford Site underground storage tanks. These safety issues are as follows: ferrocyanide, flammable gas, organic, criticality, high heat, and vapor safety issues. Tank C-103 is one of the twenty tanks currently on the Organic Salts Watch List. This TCP will identify characterization objectives pertaining to sample collection, hot cell sample isolation, and laboratory analytical evaluation and reporting requirements in accordance with the appropriate DQO documents. In addition, the current contents and status of the tank are projected from historical information. The relevant safety issues that are of concern for tanks on the Organic Salts Watch List are: the potential for an exothermic reaction occurring from the flammable mixture of organic materials and nitrate/nitrite salts that could result in a release of radioactive material and the possibility that other safety issues may exist for the tank.

  5. Tank 241-AW-101 tank characterization plan

    SciTech Connect

    Sathyanarayana, P.

    1994-11-22

    The first section gives a summary of the available information for Tank AW-101. Included in the discussion are the process history and recent sampling events for the tank, as well as general information about the tank such as its age and the risers to be used for sampling. Tank 241-AW-101 is one of the 25 tanks on the Flammable Gas Watch List. To resolve the Flammable Gas safety issue, characterization of the tanks, including intrusive tank sampling, must be performed. Prior to sampling, however, the potential for the following scenarios must be evaluated: the potential for ignition of flammable gases such as hydrogen-air and/or hydrogen-nitrous oxide; and the potential for secondary ignition of organic-nitrate/nitrate mixtures in crust layer initiated by the burning of flammable gases or by a mechanical in-tank energy source. The characterization effort applicable to this Tank Characterization Plan is focused on the resolution of the crust burn flammable gas safety issue of Tank AW-101. To evaluate the potential for a crust burn of the waste material, calorimetry tests will be performed on the waste. Differential Scanning Calorimetry (DSC) will be used to determine whether an exothermic reaction exists.

  6. Neptunium Disposal to the Savannah River Site Tank Farm

    SciTech Connect

    Walker, D.D.

    2004-02-26

    Researchers investigated the neutralization of an acidic neptunium solution from a Savannah River Site (SRS) processing canyon and the properties of the resulting slurry to determine the feasibility of disposal in the SRS tank farm. The acidic solution displayed no properties that precluded the proposed disposal route. Neutralization of the acidic neptunium forms a 4 wt per cent slurry of precipitated metal hydroxides. The insoluble solids consist largely of iron (92 per cent) and neptunium hydroxides (2 per cent). The concentration of soluble neptunium remaining after neutralization equaled much less than previous solubility measurements predicted. Researchers used an apparatus similar to an Ostwald-type viscometer to estimate the consistency of the neptunium slurry with the solids present. The yield stress and consistency of the 4 wt per cent slurry will allow transfer through the tank farm, although concentration of the insoluble solids above 4 wt per cent may cause significant problems due to increased consistency and yield stress. The consistency of the 4 wt per cent slurry is 7.6 centipoise (cP) with a yield stress less than 1 Pascal (Pa). The neptunium slurry, when combined with actual washed radioactive sludge, slightly reduces the yield stress and consistency of the sludge and produces a combined slurry with acceptable rheological properties for vitrification.

  7. ANALYSIS OF SAMPLES FROM TANK 5F CHEMICAL CLEANING

    SciTech Connect

    Poirier, M.; Fink, S.

    2011-03-07

    The Savannah River Site (SRS) is preparing Tank 5F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning. SRS personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. The conclusions from this work are: (1) With the exception of iron, the dissolution of sludge components from Tank 5F agreed with results from the actual waste demonstration performed in 2007. The fraction of iron removed from Tank 5F by chemical cleaning was significantly less than the fraction removed in the SRNL demonstrations. The likely cause of this difference is the high pH following the first oxalic acid strike. (2) Most of the sludge mass remaining in the tank is iron and nickel. (3) The remaining sludge contains approximately 26 kg of barium, 37 kg of chromium, and 37 kg of mercury. (4) Most of the radioactivity remaining in the residual material is beta emitters and {sup 90}Sr. (5) The chemical cleaning removed more than {approx} 90% of the uranium isotopes and {sup 137}Cs. (6) The chemical cleaning removed {approx} 70% of the neptunium, {approx} 83% of the {sup 90}Sr, and {approx} 21% of the {sup 60}Co. (7) The chemical cleaning removed less than 10% of the plutonium, americium, and curium isotopes. (8) The chemical cleaning removed more than 90% of the aluminium, calcium, and sodium from the tank. (9) The cleaning operations removed 61% of lithium, 88% of non-radioactive strontium, and 65% of zirconium. The {sup 90}Sr and non-radioactive strontium were measured

  8. Tank characterization report: Tank 241-C-109

    SciTech Connect

    Simpson, B.C.; Borshiem, G.L.; Jensen, L.

    1993-09-01

    Single-shell tank 241-C-109 is a Hanford Site Ferrocyanide Watch List tank that was most recently sampled in September 1992. Analyses of materials obtained from tank 241-C-109 were conducted to support the resolution of the ferrocyanide unreviewed safety question (USQ) and to support Hanford Federal Facility Agreement and consent Order (Tri- Party Agreement) Milestone M-10-00. This report describes this analysis.

  9. Caustic-Side Solvent Extraction: Prediction of Cesium Extraction for Actual Wastes and Actual Waste Simulants

    SciTech Connect

    Delmau, L.H.; Haverlock, T.J.; Sloop, F.V., Jr.; Moyer, B.A.

    2003-02-01

    This report presents the work that followed the CSSX model development completed in FY2002. The developed cesium and potassium extraction model was based on extraction data obtained from simple aqueous media. It was tested to ensure the validity of the prediction for the cesium extraction from actual waste. Compositions of the actual tank waste were obtained from the Savannah River Site personnel and were used to prepare defined simulants and to predict cesium distribution ratios using the model. It was therefore possible to compare the cesium distribution ratios obtained from the actual waste, the simulant, and the predicted values. It was determined that the predicted values agree with the measured values for the simulants. Predicted values also agreed, with three exceptions, with measured values for the tank wastes. Discrepancies were attributed in part to the uncertainty in the cation/anion balance in the actual waste composition, but likely more so to the uncertainty in the potassium concentration in the waste, given the demonstrated large competing effect of this metal on cesium extraction. It was demonstrated that the upper limit for the potassium concentration in the feed ought to not exceed 0.05 M in order to maintain suitable cesium distribution ratios.

  10. The Course of Actualization

    ERIC Educational Resources Information Center

    De Smet, Hendrik

    2012-01-01

    Actualization is traditionally seen as the process following syntactic reanalysis whereby an item's new syntactic status manifests itself in new syntactic behavior. The process is gradual in that some new uses of the reanalyzed item appear earlier or more readily than others. This article accounts for the order in which new uses appear during…

  11. Tank evaluation system shielded annular tank application

    SciTech Connect

    Freier, D.A.

    1988-10-04

    TEST (Tank Evaluation SysTem) is a research project utilizing neutron interrogation techniques to analyze the content of nuclear poisons and moderators in tank shielding. TEST experiments were performed on an experimental SAT (Shielded Annular Tank) at the Rocky Flats Plant. The purpose of these experiments was threefold: (1) to assess TEST application to SATs, (2) to determine if Nuclear Safety inspection criteria could be met, and (3) to perform a preliminary calibration of TEST for SATs. Several experiments were performed, including measurements of 11 tank shielding configurations, source-simulated holdup experiments, analysis of three detector modes, resolution studies, and TEST scanner geometry experiments. 1 ref., 21 figs., 4 tabs.

  12. Acoustic imaging of underground storage tank wastes

    SciTech Connect

    Mech, S.J.

    1995-09-01

    Acoustics is a potential tool to determine the properties of high level wastes stored in Underground Storage Tanks. Some acoustic properties were successfully measured by a limited demonstration conducted in 114-TX. This accomplishment provides the basis for expanded efforts to qualify techniques which depend on the acoustic properties of tank wastes. This work is being sponsored by the Department of Energy under the Office of Science and Technology. In FY-1994, limited Tank Waste Remediation Systems EM-30 support was available at Hanford and Los Alamos National Laboratory. The Massachusetts Institute of Technology (MIT) and Earth Resources Laboratory (ERL) were engaged for analysis support, and Elohi Geophysics, Inc. for seismic testing services. Westinghouse-Hanford Company provided the testing and training, supplied the special engineering and safety analysis equipment and procedures, and provided the trained operators for the actual tank operations. On 11/9/94, limited in-tank tests were successfully conducted in tank 114-TX. This stabilized Single Shell Tank was reported as containing 16.8 feet of waste, the lower 6.28 feet of which contained interstitial liquid. Testing was conducted over the lower 12 feet, between two Liquid Observation Wells thirty feet apart. The ``quick-look`` data was reviewed on-site by MIT and Elohi.

  13. Haneş and Valea Vinului (Romania) closed mines Acid Mine Drainages (AMDs)--actual condition and passive treatment remediation proposal.

    PubMed

    Măicăneanu, Andrada; Bedelean, Horea; Ardelean, Marius; Burcă, Silvia; Stanca, Maria

    2013-10-01

    Acid Mine Drainages (AMDs) from Haneş and Valea Vinului (Romania) closed mines were considered for characterization and treatment using a local zeolitic volcanic tuff, ZVT, (Măcicaş, Cluj County, Romania). Water samples were collected from two locations, before and after discharging point in case of Haneş mine, and on three horizons in case of Valea Vinului mine. Physico-chemical (pH, total solid, heavy metal ions concentration) analyses showed that the environment is strongly affected by these AMD discharges even if the mines were closed years ago. Iron, manganese and zinc were the main pollutants identified in Haneş mine AMD, while zinc is the one mainly present in case of Valea Vinului AMD. A batch technique (no stirring) in which the ZVT was put in contact with the AMD sample was proposed as a passive remediation technique. ZVT successfully remove heavy metal ion from AMD. According to heavy metal ion concentrations, removal efficiencies are reaching 100%, varying as follows, Fe(2+)>Zn(2+)>Mn(2+). When the ZVT was compared with two cationic resins (strong, SAR and weak acid, WAR) the following series was depicted, SAR>ZVT>WAR. Copyright © 2013 Elsevier Ltd. All rights reserved.

  14. Tank Characterization Report for Single Shell Tank 241-C-104

    SciTech Connect

    ADAMS, M.R.

    2000-04-06

    Interprets information about the tank answering a series of six questions covering areas such as information drivers, tank history, tank comparisons, disposal implications, data quality and quantity, and unique aspects of the tank.

  15. Assemblies of Conformal Tanks

    NASA Technical Reports Server (NTRS)

    DeLay, Tom

    2009-01-01

    Assemblies of tanks having shapes that conform to each other and/or conform to other proximate objects have been investigated for use in storing fuels and oxidizers in small available spaces in upper stages of spacecraft. Such assemblies might also prove useful in aircraft, automobiles, boats, and other terrestrial vehicles in which space available for tanks is limited. The basic concept of using conformal tanks to maximize the utilization of limited space is not new in itself: for example, conformal tanks are used in some automobiles to store windshield -washer liquid and coolant that overflows from radiators. The novelty of the present development lies in the concept of an assembly of smaller conformal tanks, as distinguished from a single larger conformal tank. In an assembly of smaller tanks, it would be possible to store different liquids in different tanks. Even if the same liquid were stored in all the tanks, the assembly would offer an advantage by reducing the mechanical disturbance caused by sloshing of fuel in a single larger tank: indeed, the requirement to reduce sloshing is critical in some applications. The figure shows a prototype assembly of conformal tanks. Each tank was fabricated by (1) copper plating a wax tank mandrel to form a liner and (2) wrapping and curing layers of graphite/epoxy composite to form a shell supporting the liner. In this case, the conformal tank surfaces are flat ones where they come in contact with the adjacent tanks. A band of fibers around the outside binds the tanks together tightly in the assembly, which has a quasi-toroidal shape. For proper functioning, it would be necessary to maintain equal pressure in all the tanks.

  16. Rheology of Savannah River site tank 42 and tank 51 HLW radioactive sludges

    SciTech Connect

    Ha, B.C.; Bibler, N.E.

    1996-01-19

    Knowledge of the rheology of the radioactive sludge slurries at the Savannah River Site (SRS) is necessary in order to ensure that they can be retrieved from waste tanks and processed for final disposal. The high activity radioactive wastes stored as caustic slurries at SRS result from the neutralization of acid waste generated from production of nuclear defense materials. During storage, the wastes separate into a supernate layer and a sludge layer. In the Defense Waste Processing Facility (DWPF) at SRS, the radionuclides from the sludge and supernate will be immobilized into borosilicate glass for long term storage and eventual disposal. Before transferring the waste from a storage tank to the DWPF, a portion of the aluminum in the waste sludge will be dissolved and the sludge will be extensively washed to remove sodium. Tank 51 and Tank 42 radioactive sludges represent the first batch of HLW sludge to be processed in the DWPF. This paper presents results of rheology measurements of Tank 51 and Tank 42 at various solids concentrations. The rheologies of Tank 51 and Tank 42 radioactive slurries were measured remotely in the Shielded Cells Operations (SCO) at the Savannah River Technology Center (SRTC) using a modified Haake Rotovisco RV-12 with an M150 measuring drive unit and TI sensor system. Rheological properties of the Tank 51 and Tank 42 radioactive sludges were measured as a function of weight percent solids. The weight percent solids of Tank 42 sludge was 27, as received. Tank 51 sludge had already been washed. The weight percent solids were adjusted by dilution with water or by concentration through drying. At 12, 15, and 18 weight percent solids, the yield stresses of Tank 51 sludge were 5, 11, and 14 dynes/cm2, respectively. The apparent viscosities were 6, 10, and 12 centipoises at 300 sec-1 shear rate, respectively.

  17. Tank 241-SX-103 tank characterization plan

    SciTech Connect

    Homi, C.S.

    1995-03-08

    This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-SX-103.

  18. Tank 241-U-103 tank characterization plan

    SciTech Connect

    Carpenter, B.C.

    1995-01-24

    This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-U-103.

  19. Tank 241-T-107 tank characterization plan

    SciTech Connect

    Homi, C.S.

    1995-01-05

    This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, Oak Ridge National Laboratory, and PNL tank vapor program. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-T-107.

  20. Liquid rocket metal tanks and tank components

    NASA Technical Reports Server (NTRS)

    Wagner, W. A.; Keller, R. B. (Editor)

    1974-01-01

    Significant guidelines are presented for the successful design of aerospace tanks and tank components, such as expulsion devices, standpipes, and baffles. The state of the art is reviewed, and the design criteria are presented along with recommended practices. Design monographs are listed.

  1. SLUDGE BATCH 7 PREPARATION TANK 4 AND 12 CHARACTERIZATION

    SciTech Connect

    Bannochie, C.; Click, D.; Pareizs, J.

    2010-05-21

    Samples of PUREX sludge from Tank 4 and HM sludge from Tank 12 were characterized in preparation for Sludge Batch 7 (SB7) formulation in Tank 51. SRNL analyses on Tank 4 and Tank 12 were requested in separate Technical Assistance Requests (TAR). The Tank 4 samples were pulled on January 19, 2010 following slurry operations by F-Tank Farm. The Tank 12 samples were pulled on February 9, 2010 following slurry operations by H-Tank Farm. At the Savannah River National Laboratory (SRNL), two 200 mL dip samples of Tank 4 and two 200 mL dip samples of Tank 12 were received in the SRNL Shielded Cells. Each tank's samples were composited into clean 500 mL polyethylene storage bottles and weighed. The composited Tank 4 sample was 428.27 g and the composited Tank 12 sample was 502.15 g. As expected there are distinct compositional differences between Tank 4 and Tank 12 sludges. The Tank 12 slurry is much higher in Al, Hg, Mn, and Th, and much lower in Fe, Ni, S, and U than the Tank 4 slurry. The Tank 4 sludge definitely makes the more significant contribution of S to any sludge batch blend. This S, like that observed during SB6 washing, is best monitored by looking at the total S measured by digesting the sample and analyzing by inductively coupled plasma - atomic emission spectroscopy (ICPAES). Alternatively, one can measure the soluble S by ICP-AES and adjust the value upward by approximately 15% to have a pretty good estimate of the total S in the slurry. Soluble sulfate measurements by ion chromatography (IC) will be biased considerably lower than the actual total S, the difference being due to the non-sulfate soluble S and the undissolved S. Tank 12 sludge is enriched in U-235, and hence samples transferred into SRNL from the Tank Farm will need to be placed on the reportable special nuclear material inventory and tracked for total U per SRNL procedure requirements.

  2. Ammonia tank failure

    SciTech Connect

    Sweat, M.E.

    1983-04-01

    An ammonia tank failure at Hawkeye Chemical of Clinton, Iowa is discussed. The tank was a double-wall, 27,000 metric-ton tank built in 1968 and commissioned in December 1969. The paper presented covers the cause of the failure, repair, and procedural changes made to prevent recurrence of the failure. (JMT)

  3. Feed tank transfer requirements

    SciTech Connect

    Freeman-Pollard, J.R.

    1998-09-16

    This document presents a definition of tank turnover; DOE responsibilities; TWRS DST permitting requirements; TWRS Authorization Basis (AB) requirements; TWRS AP Tank Farm operational requirements; unreviewed safety question (USQ) requirements; records and reporting requirements, and documentation which will require revision in support of transferring a DST in AP Tank Farm to a privatization contractor for use during Phase 1B.

  4. 49 CFR 174.63 - Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... Packagings, cargo tanks, and multi-unit tank car tanks. 174.63 Section 174.63 Transportation Other....63 Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car..., Large Packaging, cargo tank, or multi-unit tank car tank) containing a hazardous material in...

  5. Total cyanide analysis of tank core samples: Analytical results and supporting investigations. Revision 1

    SciTech Connect

    Pool, K.H.

    1994-03-01

    The potential for a ferrocyanide explosion in Hanford site single-shelled waste storage tanks (SSTS) poses a serious safety concern. This potential danger developed in the 1950s when {sup 137}Cs was scavenged during the reprocessing of uranium recovery process waste by co-precipitating it along with sodium in nickel ferrocyanide salt. Sodium or potassium ferrocyanide and nickel sulfate were added to the liquid waste stored in SSTs. The tank storage space resulting from the scavenging process was subsequently used to store other waste types. Ferrocyanide salts in combinations with oxidizing agents, such as nitrate and nitrite, are known to explode when key parameters (temperature, water content, oxidant concentration, and fuel [cyanide]) are in place. Therefore, reliable total cyanide analysis data for actual SST materials are required to address the safety issue. Accepted cyanide analysis procedures do not yield reliable results for samples containing nickel ferrocyanide materials because the compounds are insoluble in acidic media. Analytical chemists at Pacific Northwest Laboratory (PNL) have developed a modified microdistillation procedure (see below) for analyzing total cyanide in waste tank matrices containing nickel ferrocyanide materials. Pacific Northwest Laboratory analyzed samples from Hanford Waste Tank 241-C-112 cores 34, 35, and 36 for total cyanide content using technical procedure PNL-ALO-285 {open_quotes}Total Cyanide by Remote Microdistillation and Agrentometric Titration,{close_quotes} Rev. 0. This report summarizes the results of these analyses along with supporting quality control data, and, in addition, summarizes the results of the test to check the efficacy of sodium nickel ferrocyanide solubilization from an actual core sample by aqueous EDTA/en to verify that nickel ferrocyanide compounds were quantitatively solubilized before actual distillation.

  6. Rethinking the Hanford Tank Waste Program

    SciTech Connect

    Parker, F. L.; Clark, D. E.; Morcos, N.

    2002-02-26

    The program to treat and dispose of the highly radioactive wastes stored in underground tanks at the U.S. Department of Energy's Hanford site has been studied. A strategy/management approach to achieve an acceptable (technically sound) end state for these wastes has been developed in this study. This approach is based on assessment of the actual risks and costs to the public, workers, and the environment associated with the wastes and storage tanks. Close attention should be given to the technical merits of available waste treatment and stabilization methodologies, and application of realistic risk reduction goals and methodologies to establish appropriate tank farm cleanup milestones. Increased research and development to reduce the mass of non-radioactive materials in the tanks requiring sophisticated treatment is highly desirable. The actual cleanup activities and milestones, while maintaining acceptable safety standards, could be more focused on a risk-to-benefit cost effectiveness, as agreed to by the involved stakeholders and in accordance with existing regulatory requirements. If existing safety standards can be maintained at significant cost savings under alternative plans but with a change in the Tri-Party Agreement (a regulatory requirement), those plans should be carried out. The proposed strategy would also take advantage of the lessons learned from the activities and efforts in the first phase of the two-phased cleanup of the Hanford waste tank farms.

  7. Tank 241-B-103 tank characterization plan

    SciTech Connect

    Carpenter, B.C.

    1995-01-23

    The Defense Nuclear Facilities Safety Board (DNFSB) has advised the US Department of Energy (DOE) to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The data quality objective (DQO) process was chosen as a tool to be used to identify sampling and analytical needs for the resolution of safety issues. As a result, a revision in the Federal Facility Agreement and Consent Order (Tri-Party Agreement or TPA) milestone M-44-00 has been made, which states that ``A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process... Development of TCPs by the DQO process is intended to allow users (e.g., Hanford Facility user groups, regulators) to ensure their needs will be met and that resources are devoted to gaining only necessary information.`` This document satisfies that requirement for Tank 241-B-103 (B-103) sampling activities. Tank B-103 was placed on the Organic Watch List in January 1991 due to review of TRAC data that predicts a TOC content of 3.3 dry weight percent. The tank was classified as an assumed leaker of approximately 30,280 liters (8,000 gallons) in 1978 and declared inactive. Tank B-103 is passively ventilated with interim stabilization and intrusion prevention measures completed in 1985.

  8. Selecting fuel storage tanks

    SciTech Connect

    Doherty, R. )

    1993-07-01

    Until the use of underground storage tanks (USTs) for fuel storage was mandated by the 1970 Uniform Fire Code, above-ground storage tanks (ASTs) were widely used. The tanks were relatively crude by today's standards so the technical superiority and fire protection afforded by use of underground tanks soon made USTs the system of choice for almost all uses. As a result, tens of thousands of tanks have been underground for more than 20 years, and at some point, many of them began leaking. Often, the first sign of these leaks appeared when groundwater became contaminated. The EPA responded to this major environmental problem by strictly regulating the use of below-ground tanks to store flammable liquids. These added regulations have had a severe effect on both service stations and private fueling. The removal of underground tanks and the removal and disposal of any contaminated soil is an extremely expensive proposition. Furthermore, new Uniform Fire Code regulations have added to the costs, imposing requirements for double-walled tanks, corrosion protection, electronic leak monitoring, and annual tank testing. These requirements, plus the financial responsibility requirements the EPA imposed on owners and users of below-ground tanks, led directly to a reconsideration of the use of above-ground tanks for some applications.

  9. Extraction of long-lived radionuclides from caustic Hanford tank waste supernatants

    SciTech Connect

    Chaiko, D.J.; Mertz, C.J.; Vojta, Y.

    1995-07-01

    A series of polymer-based extraction systems, based on the use of polyethylene glycols (PEGs) or polypropylene glycols (PPGs), was demonstrated to be capable of selective extraction and recovery of long-lived radionuclides, such as {sup 99}Tc and {sup 129}I, from Hanford SY-101 tank waste, neutralized current acid waste, and single-shell tank waste simulants. During the extraction process, anionic species like TcO{sub 4}{sup {minus}} and I{sup {minus}} are selectively transferred to the less dense PEG-rich aqueous phase. The partition coefficients for a wide range of inorganic cations and anions, such as sodium, potassium, aluminum, nitrate, nitrite, and carbonate, are all less than one. The partition coefficients for pertechnetate ranged from 12 to 50, depending on the choice of waste simulant and temperature. The partition coefficient for iodide was about 5, while that of iodate was about 0.25. Irradiation of the PEG phase with gamma-ray doses up to 20 Mrad had no detectable effect on the partition coefficients. The most selective extraction systems examined were those based on PPGs, which exhibited separation factors in excess of 3000 between TcO{sub 4}{sup {minus}} and NO{sub 3}{sup {minus}}/NO{sub 2}{sub {minus}}. An advantage of the PPG-based system is minimization of secondary waste production. These studies also highlighted the need for exercising great care in extrapolating the partitioning behavior with tank waste simulants to actual tank waste.

  10. ANALYSIS OF TURBULENT MIXING JETS IN LARGE SCALE TANK

    SciTech Connect

    Lee, S; Richard Dimenna, R; Robert Leishear, R; David Stefanko, D

    2007-03-28

    Flow evolution models were developed to evaluate the performance of the new advanced design mixer pump for sludge mixing and removal operations with high-velocity liquid jets in one of the large-scale Savannah River Site waste tanks, Tank 18. This paper describes the computational model, the flow measurements used to provide validation data in the region far from the jet nozzle, the extension of the computational results to real tank conditions through the use of existing sludge suspension data, and finally, the sludge removal results from actual Tank 18 operations. A computational fluid dynamics approach was used to simulate the sludge removal operations. The models employed a three-dimensional representation of the tank with a two-equation turbulence model. Both the computational approach and the models were validated with onsite test data reported here and literature data. The model was then extended to actual conditions in Tank 18 through a velocity criterion to predict the ability of the new pump design to suspend settled sludge. A qualitative comparison with sludge removal operations in Tank 18 showed a reasonably good comparison with final results subject to significant uncertainties in actual sludge properties.

  11. Tank 241-C-107 tank characterization plan

    SciTech Connect

    Schreiber, R.D.

    1995-02-06

    The Defense Nuclear Facilities Safety Board (DNFSB) has advised the US Department of Energy (DOE) to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The data quality objective (DQO) process was chosen as a tool to be used to identify sampling and analytical needs for the resolution of safety issues. As a result, a revision in the Federal Facility Agreement and Consent Order (Tri-Party Agreement or TPA) milestone M-44-00 has been made, which states that ``A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process... Development of TCPs by the DQO process is intended to allow users (e.g., Hanford Facility user groups, regulators) to ensure their needs will be met and that resources are devoted to gaining only necessary information.`` This document satisfies that requirement for the Tank 241-C-107 (C-107) sampling activities. Currently tank C-107 is categorized as a sound, low-heat load tank with partial isolation completed in December 1982. The tank is awaiting stabilization. Tank C-107 is expected to contain three primary layers of waste. The bottom layer should contain a mixture of the following wastes: ion exchange, concentrated phosphate waste from N-Reactor, Hanford Lab Operations, strontium semi-works, Battelle Northwest, 1C, TBP waste, cladding waste, and the hot semi-works. The middle layer should contain strontium recovery supernate. The upper layer should consist of non-complexed waste.

  12. Multifunctional Tanks for Spacecraft

    NASA Technical Reports Server (NTRS)

    Collins, David H.; Lewis, Joseph C.; MacNeal, Paul D.

    2006-01-01

    A document discusses multifunctional tanks as means to integrate additional structural and functional efficiencies into designs of spacecraft. Whereas spacecraft tanks are traditionally designed primarily to store fluids and only secondarily to provide other benefits, multifunctional tanks are designed to simultaneously provide multiple primary benefits. In addition to one or more chamber(s) for storage of fluids, a multifunctional tank could provide any or all of the following: a) Passageways for transferring the fluids; b) Part or all of the primary structure of a spacecraft; c) All or part of an enclosure; d) Mechanical interfaces to components, subsystems, and/or systems; e) Paths and surfaces for transferring heat; f)Shielding against space radiation; j) Shielding against electromagnetic interference; h) Electrically conductive paths and surfaces; and i) Shades and baffles to protect against sunlight and/or other undesired light. Many different multifunctional-tank designs are conceivable. The design of a particular tank can be tailored to the requirements for the spacecraft in which the tank is to be installed. For example, the walls of the tank can be flat or curved or have more complicated shapes, and the tank can include an internal structure for strengthening the tank and/or other uses.

  13. 49 CFR 174.63 - Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car tanks. 174.63 Section 174.63 Transportation Other....63 Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank...

  14. LH tank installation

    NASA Image and Video Library

    2011-07-25

    Stennis Space Center employees marked another construction milestone July 25 with installation of the 85,000-gallon liquid hydrogen tank atop the A-3 Test Stand. The 300-foot-tall stand is being built to test next-generation rocket engines that could carry humans into deep space once more. The liquid hydrogen tank and a 35,000-gallon liquid oxygen tank installed atop the steel structure earlier in June will provide fuel propellants for testing the engines.

  15. Tank overpressure: An uplifting experience

    SciTech Connect

    Morgenegg, E.E.

    1982-05-01

    One of the most common causes of tank damage is uplift. The paper discusses the sources and magnitude of pressure that causes tank uplift, repairs that can be performed on tanks that have lifted, and the prevention of tank uplift. Discussion and examples given are limited to tanks 70 feet or less in diameter.

  16. Hanford tanks initiative plan

    SciTech Connect

    McKinney, K.E.

    1997-07-01

    Abstract: The Hanford Tanks Initiative (HTI) is a five-year project resulting from the technical and financial partnership of the U.S. Department of Energy`s Office of Waste Management (EM-30) and Office of Science and Technology Development (EM-50). The HTI project accelerates activities to gain key technical, cost performance, and regulatory information on two high-level waste tanks. The HTI will provide a basis for design and regulatory decisions affecting the remainder of the Tank Waste Remediation System`s tank waste retrieval Program.

  17. Underground petroleum tanks

    SciTech Connect

    Not Available

    1990-07-01

    This book presents the results of a survey of 46 state underground storage tank program officials. The survey covers: Whether petroleum tank insurance (mandated by the EPA) is available in each state and whether category 3 and 4 owners can obtain it; state programs that help owners meet the financial responsibility and/or technical requirements of such insurance; and lending institutions' attitudes towards providing loans to storage tank owners. A survey of the number and terms of insurance policies offered to tank owners is also presented.

  18. 33 CFR Appendix A to Part 157 - Damage Assumptions, Hypothetical Outflows, and Cargo Tank Size and Arrangements

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Pt. 157, App. A Appendix A to Part 157... being the actual volume of one such tank (where they are of equal capacity) or the smaller of the two tanks (if they differ in capacity), adjacent to such space, multiplied by S i as defined below...

  19. WASHING AND DEMONSTRATION OF THE DWPF FLOWSHEET IN THE SRNL SHIELDED CELLS USING POST ALUMINUM DISSOLUTION TANK 51 SLUDGE SLURRY

    SciTech Connect

    Pareizs, J; Cj Bannochie, C; Damon Click, D; Erich Hansen, E; Dan Lambert, D; Michael Stone, M

    2008-04-28

    under-added. Although the sludge was rheologically thick throughout the SRAT and Slurry Mix Evaporator (SME) cycles, this may have been due to the under addition of acid. Aluminum dissolution did, however, impact analyses of the SRAT receipt material. Two methods for determining total base yielded significantly different results. The high hydroxide content and the relatively high soluble aluminum content of the washed post aluminum dissolution sludge likely contributed to this difference and the ultimate under addition of acid. It should be noted that the simulant used to provide input for the SRAT cycle was an inadequate representation of the waste in terms of acid demand, likely due to the differences in the form of aluminum and hydroxide in the simulant and actual waste. Based on the results of this task, it is recommended that: (1) Sludge settling and rheology during washing of the forthcoming Sludge Batch 5 qualification sample be monitored closely and communicated to the Tank Farm. (2) SRNL receive a sample of Tank 51 after all chemical additions have been made and prior to the final Sludge Batch 5 decant for rheological assessment. Rheology versus wt% insoluble solids will be performed to determine the maximum amount of decant prior to the Tank 51 to Tank 40 transfer. (3) As a result of the problem with measuring total base and subsequently under-calculating acid for the DWPF CPC processing of the post aluminum dissolution sludge; (4) Studies to develop understanding of how the sludge titrates (i.e., why different titration methods yield different results) should be performed. (5) Simulants that better match the properties of post aluminum dissolution sludge should be developed. (6) Work on developing an acid calculation less dependant on the total base measurement should be continued.

  20. Commercial Submersible Mixing Pump For SRS Tank Waste Removal - 15223

    SciTech Connect

    Hubbard, Mike; Herbert, James E.; Scheele, Patrick W.

    2015-01-12

    product lubricated canned motor pumps designed to fit within available risers and have significant agitation capabilities to suspend waste solids. Waste removal and closure of two tanks has been accomplished with agitation provided by 3 SMPs installed within the tanks. In 2012, a team was assembled to investigate alternative solids removal technologies to support waste removal for closing tanks. The goal of the team was to find a more cost effective approach that could be used to replace the current mixing pump technology. This team was unable to identify an alternative technology outside of mixing pumps to support waste agitation and removal from SRS waste tanks. However, the team did identify a potentially lower cost mixing pump compared to the baseline SLPs and SMPs. Rather than using the traditional procurement using an engineering specification, the team proposed to seek commercially available submersible mixer pumps (CSMP) as alternatives to SLPs and SMPs. SLPs and SMPs have a high procurement cost and the actual cost of moving pumps between tanks has shown to be significantly higher than the original estimates that justified the reuse of SMPs and SLPs. The team recommended procurement of “off-the-shelf” industry pumps which may be available for significant savings, but at an increased risk of failure and reduced operating life in the waste tank. The goal of the CSMP program is to obtain mixing pumps that could mix from bulk waste removal through tank closure and then be abandoned in place as part of tank closure. This paper will present the development, progress and relative advantages of the CSMP.

  1. Double-shell tank remaining useful life estimates

    SciTech Connect

    Anantatmula, R.P., Westinghouse Hanford

    1996-12-02

    The existing 28 double-shell tanks (DSTS) at Hanford are currently planned to continue operation through the year 2028 when disposal schedules show removal of waste. This schedule will place the DSTs in a service life window of 4O to 60 years depending on tank construction date and actual retirement date. This paper examines corrosion- related life-limiting conditions of DSTs and reports the results of remaining useful life models developed for estimating remaining tank life. Three models based on controllable parameters such as temperature, chemistry, and relative humidity are presented for estimates to the year in which a particular DST may receive a breach in the primary tank due to pitting in the liquid or vapor region. Pitting is believed to be the life-limiting condition for DSTs,however, the region of the most aggressive pitting (vapor space or liquid) requires further investigation. The results of the models presented suggest none of the existing DSTs should fail by through-wall pitting until well beyond scheduled retrieval in 2028. The estimates of tank breach years (the year in which a tank may be expected to breach the primary tank wall) range from 2056 for pitting corrosion in the liquid region of tank 104-AW to beyond the next millennium for several tanks in the vapor region.

  2. COOLING COIL EFFECTS ON BLENDING IN A PILOT SCALE TANK

    SciTech Connect

    Leishear, R.; Poirier, M.; Fowley, M.; Steeper, T.

    2010-08-26

    Blending, or mixing, processes in 1.3 million gallon nuclear waste tanks are complicated by the fact that miles of serpentine, vertical, cooling coils are installed in the tanks. As a step toward investigating blending interference due to coils in this type of tank, a 1/10.85 scale tank and pump model were constructed for pilot scale testing. A series of tests were performed in this scaled tank by adding blue dye to visualize blending, and by adding acid or base tracers to solution to quantify the time required to effectively blend the tank contents. The acid and base tests were monitored with pH probes, which were located in the pilot scale tank to ensure that representative samples were obtained. Using the probes, the hydronium ion concentration [H{sup +}] was measured to ensure that a uniform concentration was obtained throughout the tank. As a result of pilot scale testing, a significantly improved understanding of mixing, or blending, in nuclear waste tanks has been achieved. Evaluation of test data showed that cooling coils in the waste tank model increased pilot scale blending times by 200% in the recommended operating range, compared to previous theoretical estimates of a 10-50% increase. Below the planned operating range, pilot scale blending times were increased by as much as 700% in a tank with coils installed. One pump, rather than two or more, was shown to effectively blend the tank contents, and dual pump nozzles installed parallel to the tank wall were shown to provide optimal blending. In short, experimental results varied significantly from expectations.

  3. Stirring system for radioactive waste water storage tank

    SciTech Connect

    Ogata, Yoshimune; Nishizawa, Kunihide . Radioisotope Research Center)

    1999-07-01

    A stirring system for 100-m[sup 3] radioactive liquid waste tanks was constructed to unify radioactive concentrations in the tank. The stirring system is effective in certifying that the radioactive concentrations in the tanks are less than the legal limits before they are drained away as waste liquid. This system is composed of discharge units, pipe lines, and a controller. The performance of the system was assessed by comparing the calculated red ink and [sup 32]P concentrations with those monitored at six locations in the tanks. The concentration reached equilibrium after stirring 60 o 120 min with discharge units equipped with six fixed openings configured in differing directions. Residual chlorine in city water used for dilution occasionally bleached the red ink and reduced its concentration. The adsorption of [sup 32]P by slime on the walls of the tanks storing actual waste water lowered the equilibrium concentration.

  4. 49 CFR 179.401 - Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... to inner tanks for cryogenic liquid tank car tanks. 179.401 Section 179.401 Transportation Other..., DEPARTMENT OF TRANSPORTATION (CONTINUED) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank... requirements applicable to inner tanks for cryogenic liquid tank car tanks....

  5. High organic containing tanks: Assessing the hazard potential

    SciTech Connect

    Hill, R.C.P.; Babad, H.

    1991-09-01

    Eight Hanford Site tanks contain organic chemicals at concentrations believed to be greater than 10 mole percent sodium acetate equivalent mixed with the oxidizing salts sodium nitrate/sodium nitrite. Also, three of the hydrogen and ferrocyanide tanks appear on the organic tank list. Concentrations of organics that may be present in some tanks could cause an exothermic reaction given a sufficient driving force, such as high temperatures. However, the difference between ignition temperatures and actual tank temperatures measured is so large that the probability of such a reaction is considered very low. The consequences of the postulated reaction are about the same as the scenarios for an explosion in a burping'' hydrogen tank. Although work on this issue is just beginning, consideration of hazards associated with heating nitrate-nitrite mixtures containing organic materials is an integral part of both the hydrogen and ferrocyanide tank efforts. High concentrations of organic compounds have been inferred (from tank transfer, flow sheet records, and limited analytical data) in eight single-shell tanks. Many organic chemicals, if present in concentrations above 10 dry weight percent (sodium acetate equivalent), have the potential to react with nitrate-nitrites constituents at temperatures above 200{degree}C (392{degree}F) in an exothermic manner. The concentrations of organic materials in the listed single-shell tanks, and their chemical identity, is not accurately known at present. A tank sampling program has been planned to provide more information on the contents of these tanks and to serve as a basis for laboratory testing and safety evaluations. 2 refs., 1 fig., 2 tabs.

  6. Underground Tank Management.

    ERIC Educational Resources Information Center

    Bednar, Barbara A.

    1990-01-01

    The harm to human health and our environment caused by leaking underground storage tanks can be devastating. Schools can meet new federal waste management standards by instituting daily inventory monitoring, selecting a reliable volumetric testing company, locating and repairing leaks promptly, and removing and installing tanks appropriately. (MLH)

  7. Underground Tank Management.

    ERIC Educational Resources Information Center

    Bednar, Barbara A.

    1990-01-01

    The harm to human health and our environment caused by leaking underground storage tanks can be devastating. Schools can meet new federal waste management standards by instituting daily inventory monitoring, selecting a reliable volumetric testing company, locating and repairing leaks promptly, and removing and installing tanks appropriately. (MLH)

  8. Oxygen tank assemblies

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Structural design considerations for O2 tank shells and suspension systems of ground based storage and mobile tank systems are outlined. Safety factors, chemical compatibility, liquid slosh strength, and cryogenic temperature properties are summarized. Finally, costs, quality control measures, and long life characteristics are examined.

  9. Initial single-shell tank retrieval system tank selection

    SciTech Connect

    Grenard, C.E.

    1996-10-24

    The Hanford Federal Facility Agreement and Consent Order (also known as the Tri-Party Agreement), established several milestones associated with the Initial Single-Shell Tank Retrieval System (ISSTRS). It also established that the scope of ISSTRS is the retrieval of a complete tank farm or an equivalent number of tanks. This study selected the single- shell tanks to be included in the ISSTRS work scope. This study determined that the ISSTRS work scope should consist of four tanks located in the A, AX, and C, tank farms. One of the tanks (Tank 241-AX-103) will be a salt cake retrieval demonstration tank. The other three (Tanks 241 -A-1 02, 241 -C-1 03, and 241-C-105) are 100-series tanks containing high interim storage risk, high long-term hazard waste and are assumed not to be leaking.

  10. Stainless steel tanks

    SciTech Connect

    Hagen, T.

    1995-12-31

    There is currently no recognized code or standard for the design, fabrication and construction of atmospheric and low pressure stainless steel tanks. At the present time these tanks are being designed to individual specifications, manufacturers standards or utilizing other codes and standards that may not be entirely applicable. Recognizing the need, the American Petroleum Institute will be publishing a new appendix to the API STD 650 Standard which will cover stainless steel tanks. The new Appendix was put together by a Task Group of selected individuals from the API Subcommittee of Pressure Vessels and Tanks from the Committee on Refinery Equipment. This paper deals with the development and basis of the new appendix. The new appendix will provide a much needed standard to cover the material, design, fabrication, erection and testing requirements for vertical, cylindrical, austenitic stainless steel aboveground tanks in nonrefrigerated service.

  11. Rainwater tank drowning.

    PubMed

    Byard, Roger W

    2008-11-01

    Drowning remains a significant cause of accidental death in young children. The site of drowning varies among communities and is influenced by cultural and geographic factors, including the availability of particular water sources. The drowning deaths of a twin two-year-old brother and sister in a rainwater tank are reported to demonstrate specific issues that may arise. Ladders, vegetation and trellises may provide access to tanks and should be removed. Secure child-proof access points should also be installed, particularly on in-ground tanks (given the ready accessibility of the latter). As there has been a recent trend in Australia to install more domestic rainwater tanks, the number of childhood rainwater tank drownings and near-drownings will need to be monitored by forensic pathologists and child death review committees to ensure that this has not led to the introduction of a new hazard into the home environment.

  12. Tank characterization reference guide

    SciTech Connect

    De Lorenzo, D.S.; DiCenso, A.T.; Hiller, D.B.; Johnson, K.W.; Rutherford, J.H.; Smith, D.J.; Simpson, B.C.

    1994-09-01

    Characterization of the Hanford Site high-level waste storage tanks supports safety issue resolution; operations and maintenance requirements; and retrieval, pretreatment, vitrification, and disposal technology development. Technical, historical, and programmatic information about the waste tanks is often scattered among many sources, if it is documented at all. This Tank Characterization Reference Guide, therefore, serves as a common location for much of the generic tank information that is otherwise contained in many documents. The report is intended to be an introduction to the issues and history surrounding the generation, storage, and management of the liquid process wastes, and a presentation of the sampling, analysis, and modeling activities that support the current waste characterization. This report should provide a basis upon which those unfamiliar with the Hanford Site tank farms can start their research.

  13. Analysis of tank damage during the 1994 Northridge earthquake

    SciTech Connect

    Haroun, M.A.; Bhatia, H.

    1995-12-31

    The damage sustained by cylindrical liquid storage tanks during the 1994 Northridge earthquake is summarized. It included elephant foot buckling, anchor failure and roof-shell connection separation. A few of the important lessons learned, in particular, as related to the accuracy of code computations in predicting the actual behavior of these structures are outlined. A detailed case study is presented to illustrate the application of current seismic design standards to a damaged unanchored tank and to demonstrate the use of a state-of-the-art finite element analysis in assessing the seismic safety of the same tank.

  14. Results for the DWPF Slurry Mix Evaporator Condensate Tank, Off Gas Condensate Tank, And Recycle Collection Tank Samples

    SciTech Connect

    TERRI, FELLINGER

    2004-12-21

    The Defense Waste Processing Facility, DWPF, currently generates approximately 1.4 million gallons of recycle water per year during Sludge-Only operations. DWPF has minimized condensate generation to 1.4 million gallons by not operating the Steam Atomized Scrubbers, SASs, for the melter off gas system. By not operating the SASs, DWPF has reduced the total volume by approximately 800,000 gallons of condensate per year. Currently, the recycle stream is sent to back to the Tank Farm and processed through the 2H Evaporator system. To alleviate the load on the 2H Evaporator system, an acid evaporator design is being considered as an alternate processing and/or concentration method for the DWPF recycle stream. In order to support this alternate processing option, the DWPF has requested that the chemical and radionuclide compositions of the Off Gas Condensate Tank, OGCT, Slurry Mix Evaporator Condensate Tank, SMECT, Recycle Collection Tank, RCT, and the Decontamination Waste Treatment Tank, DWTT, be determined as a part of the process development work for the acid evaporator design. Samples have been retrieved from the OGCT, RCT, and SMECT and have been sent to the Savannah River National Laboratory, SRNL for this characterization. The DWTT samples have been recently shipped to SRNL. The results for the DWTT samples will be issued at later date.

  15. 49 CFR 179.201 - Individual specification requirements applicable to non-pressure tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... to non-pressure tank car tanks. 179.201 Section 179.201 Transportation Other Regulations Relating to... MATERIALS REGULATIONS SPECIFICATIONS FOR TANK CARS Specifications for Non-Pressure Tank Car Tanks (Classes... car tanks....

  16. Tank 241-U-202 tank characterization plan

    SciTech Connect

    Schreiber, R.D.

    1995-02-21

    This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, and WHC 222-S Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples for tank 241-U-202.

  17. Tank 241-U-201 tank characterization plan

    SciTech Connect

    Schreiber, R.D.

    1995-02-21

    This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, and WHC 22-S Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples for tank 241-U-201.

  18. Tank 241-SX-115 tank characterization plan

    SciTech Connect

    Sasaki, L.M.

    1995-04-24

    This document is a plan which serves as the contractual agreement between the Characterization Project, Sampling Operations, and WHC 222-S Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples for tank 241-SX-115.

  19. Tank 241-TY-104 Tank characterization plan

    SciTech Connect

    Schreiber, R.D.

    1995-02-15

    This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, and WHC 222-C Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples for tank 241-TY-104.

  20. Tank 241-BY-103 tank characterization plan

    SciTech Connect

    Carpenter, B.C.

    1994-10-21

    This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, WHC 222-S Laboratory, Oak Ridge National Laboratory, and PNL 329 Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of vapor samples from tank 241-BY-103.

  1. Welded polypropylene liners for large descaling tanks

    NASA Technical Reports Server (NTRS)

    Abel, H. P.

    1971-01-01

    Liners for nitric and hydrofluoric acid tanks show no sign of deterioration after 18 months of continuous use. Each side of each edge of the polypropylene sheets is chamfered, and sheets are welded from both sides with polypropylene filler rod and a special hot-air welding torch.

  2. ADM. Tanks: from left to right: fuel oil tank, fuel ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    ADM. Tanks: from left to right: fuel oil tank, fuel pump house (TAN-611), engine fuel tank, water pump house, water storage tank. Camera facing northwest. Not edge of shielding berm at left of view. Date: November 25, 1953. INEEL negative no. 9217 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  3. Pressurizer tank upper support

    DOEpatents

    Baker, Tod H.; Ott, Howard L.

    1994-01-01

    A pressurizer tank in a pressurized water nuclear reactor is mounted between structural walls of the reactor on a substructure of the reactor, the tank extending upwardly from the substructure. For bearing lateral loads such as seismic shocks, a girder substantially encircles the pressurizer tank at a space above the substructure and is coupled to the structural walls via opposed sway struts. Each sway strut is attached at one end to the girder and at an opposite end to one of the structural walls, and the sway struts are oriented substantially horizontally in pairs aligned substantially along tangents to the wall of the circular tank. Preferably, eight sway struts attach to the girder at 90.degree. intervals. A compartment encloses the pressurizer tank and forms the structural wall. The sway struts attach to corners of the compartment for maximum stiffness and load bearing capacity. A valve support frame carrying the relief/discharge piping and valves of an automatic depressurization arrangement is fixed to the girder, whereby lateral loads on the relief/discharge piping are coupled directly to the compartment rather than through any portion of the pressurizer tank. Thermal insulation for the valve support frame prevents thermal loading of the piping and valves. The girder is shimmed to define a gap for reducing thermal transfer, and the girder is free to move vertically relative to the compartment walls, for accommodating dimensional variation of the pressurizer tank with changes in temperature and pressure.

  4. Pressurizer tank upper support

    DOEpatents

    Baker, T.H.; Ott, H.L.

    1994-01-11

    A pressurizer tank in a pressurized water nuclear reactor is mounted between structural walls of the reactor on a substructure of the reactor, the tank extending upwardly from the substructure. For bearing lateral loads such as seismic shocks, a girder substantially encircles the pressurizer tank at a space above the substructure and is coupled to the structural walls via opposed sway struts. Each sway strut is attached at one end to the girder and at an opposite end to one of the structural walls, and the sway struts are oriented substantially horizontally in pairs aligned substantially along tangents to the wall of the circular tank. Preferably, eight sway struts attach to the girder at 90[degree] intervals. A compartment encloses the pressurizer tank and forms the structural wall. The sway struts attach to corners of the compartment for maximum stiffness and load bearing capacity. A valve support frame carrying the relief/discharge piping and valves of an automatic depressurization arrangement is fixed to the girder, whereby lateral loads on the relief/discharge piping are coupled directly to the compartment rather than through any portion of the pressurizer tank. Thermal insulation for the valve support frame prevents thermal loading of the piping and valves. The girder is shimmed to define a gap for reducing thermal transfer, and the girder is free to move vertically relative to the compartment walls, for accommodating dimensional variation of the pressurizer tank with changes in temperature and pressure. 10 figures.

  5. LOX tank installation

    NASA Image and Video Library

    2011-06-08

    Construction of the A-3 Test Stand at Stennis Space Center continued June 8 with installation of a 35,000-gallon liquid oxygen tank atop the steel structure. The stand is being built to test next-generation rocket engines that will carry humans into deep space once more. The LOX tank and a liquid hydrogen tank to be installed atop the stand later will provide propellants for testing the engines. The A-3 Test Stand is scheduled for completion and activation in 2013.

  6. Composition, preparation, and gas generation results from simulated wastes of Tank 241-SY-101

    SciTech Connect

    Bryan, S.A.; Pederson, L.R.

    1994-08-01

    This document reviews the preparation and composition of simulants that have been developed to mimic the wastes temporarily stored in Tank 241-SY-101 at Hanford. The kinetics and stoichiometry of gases that are generated using these simulants are also compared, considering the roles of hydroxide, chloride, and transition metal ions; the identities of organic constituents; and the effects of dilution, radiation, and temperature. Work described in this report was conducted for the Flammable Gas Safety Program at Pacific Northwest Laboratory, (a) whose purpose is to develop information that is necessary to mitigate potential safety hazards associated with waste tanks at the Hanford Site. The goal of this research and of related efforts at the Georgia Institute of Technology (GIT), Argonne National Laboratory (ANL), and Westinghouse Hanford Company (WHC) is to determine the thermal and thermal/radiolytic mechanisms by which flammable and other gases are produced in Hanford wastes, emphasizing those stored in Tank 241-SY-101. A variety of Tank 241-SY-101 simulants have been developed to date. The use of simulants in laboratory testing activities provides a number of advantages, including elimination of radiological risks to researchers, lower costs associated with experimentation, and the ability to systematically alter simulant compositions to study the chemical mechanisms of reactions responsible for gas generation. The earliest simulants contained the principal inorganic components of the actual waste and generally a single complexant such as N-(2-hydroxyethyl) ethylenediaminetriacetic acid (HEDTA) or ethylenediaminetriacetic acid (EDTA). Both homogeneous and heterogeneous compositional forms were developed. Aggressive core sampling and analysis activities conducted during Windows C and E provided information that was used to design new simulants that more accurately reflected major and minor inorganic components.

  7. 7. General Viewacid storage tank to east of building with ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    7. General View-acid storage tank to east of building with accumulation vats in foreground. - Mare Island Naval Shipyard, Battery Test Office & Storage Facility, California Avenue & E Street, Vallejo, Solano County, CA

  8. Cryogenic-storage-tank support

    NASA Technical Reports Server (NTRS)

    Wisdom, G. H.

    1980-01-01

    Support isolates tank from thermal and mechanical loading by environment. Design uses combination of well-known common mechanisms to isolate tank and allow for tank expansion and contraction due to temperature and pressure changes. Similar support method is used on nitrogen tanks.

  9. Hybrid Composite Cryogenic Tank Structure

    NASA Technical Reports Server (NTRS)

    DeLay, Thomas

    2011-01-01

    A hybrid lightweight composite tank has been created using specially designed materials and manufacturing processes. The tank is produced by using a hybrid structure consisting of at least two reinforced composite material systems. The inner composite layer comprises a distinct fiber and resin matrix suitable for cryogenic use that is a braided-sleeve (and/or a filamentwound layer) aramid fiber preform that is placed on a removable mandrel (outfitted with metallic end fittings) and is infused (vacuum-assisted resin transfer molded) with a polyurethane resin matrix with a high ductility at low temperatures. This inner layer is allowed to cure and is encapsulated with a filamentwound outer composite layer of a distinct fiber resin system. Both inner and outer layer are in intimate contact, and can also be cured at the same time. The outer layer is a material that performs well for low temperature pressure vessels, and it can rely on the inner layer to act as a liner to contain the fluids. The outer layer can be a variety of materials, but the best embodiment may be the use of a continuous tow of carbon fiber (T-1000 carbon, or others), or other high-strength fibers combined with a high ductility epoxy resin matrix, or a polyurethane matrix, which performs well at low temperatures. After curing, the mandrel can be removed from the outer layer. While the hybrid structure is not limited to two particular materials, a preferred version of the tank has been demonstrated on an actual test tank article cycled at high pressures with liquid nitrogen and liquid hydrogen, and the best version is an inner layer of PBO (poly-pphenylenebenzobisoxazole) fibers with a polyurethane matrix and an outer layer of T-1000 carbon with a high elongation epoxy matrix suitable for cryogenic temperatures. A polyurethane matrix has also been used for the outer layer. The construction method is ideal because the fiber and resin of the inner layer has a high strain to failure at cryogenic

  10. Tank 48 - Chemical Destruction

    SciTech Connect

    Simner, Steven P.; Aponte, Celia I.; Brass, Earl A.

    2013-01-09

    Small tank copper-catalyzed peroxide oxidation (CCPO) is a potentially viable technology to facilitate the destruction of tetraphenylborate (TPB) organic solids contained within the Tank 48H waste at the Savannah River Site (SRS). A maturation strategy was created that identified a number of near-term development activities required to determine the viability of the CCPO process, and subsequent disposition of the CCPO effluent. Critical activities included laboratory-scale validation of the process and identification of forward transfer paths for the CCPO effluent. The technical documentation and the successful application of the CCPO process on simulated Tank 48 waste confirm that the CCPO process is a viable process for the disposition of the Tank 48 contents.

  11. Waste tank sample transport

    SciTech Connect

    Field, J.G.; Mercado, M.S.; Smith, R.J.; Thornton, J.W.

    1994-08-01

    Since 1943, radioactive liquid waste has been stored in underground storage tanks at the Hanford Site in Richland, Washington. The waste was the result of chemical separation processes for the production of fissile defense materials. Associated with the current environmental cleanup mission, waste characterization and processing programs are requiring the extraction of samples from the tanks. Approved onsite packaging are in place and in use for transfers of samples from the tanks to onsite laboratories. Initiatives are under way to develop and procure packaging for sample shipments to offsite laboratories. This paper will provide a current status of the tank sample packaging used at the Hanford Site, as well as the project status for new packaging to be used for offsite shipments.

  12. 49 CFR 179.401 - Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... to inner tanks for cryogenic liquid tank car tanks. 179.401 Section 179.401 Transportation Other... TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid... requirements applicable to inner tanks for cryogenic liquid tank car tanks. ...

  13. TANK 5 SAMPLING

    SciTech Connect

    Vrettos, N; William Cheng, W; Thomas Nance, T

    2007-11-26

    Tank 5 at the Savannah River Site has been used to store high level waste and is currently undergoing waste removal processes in preparation for tank closure. Samples were taken from two locations to determine the contents in support of Documented Safety Analysis (DSA) development for chemical cleaning. These samples were obtained through the use of the Drop Core Sampler and the Snowbank Sampler developed by the Engineered Equipment & Systems (EES) group of the Savannah River National Laboratory (SRNL).

  14. 40 CFR 63.133 - Process wastewater provisions-wastewater tanks.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) of this section. (A) Actual emissions tests that use full-size or scale-model wastewater tanks that... barometric pressure, or (B) An engineering evaluation that the Administrator determines is an accurate method...) For any fixed roof tank and closed-vent system that is operated and maintained under negative...

  15. Methodology for completing Hanford 200 Area tank waste physical/chemical profile estimations

    SciTech Connect

    Kruger, A.A.

    1996-04-29

    The purpose of the Methodology for Completing Hanford 200 Area Tank Waste Physical/Chemical Profile Estimations is to capture the logic inherent to completing 200 Area waste tank physical and chemical profile estimates. Since there has been good correlation between the estimate profiles and actual conditions during sampling and sub-segment analysis, it is worthwhile to document the current estimate methodology.

  16. 40 CFR 63.133 - Process wastewater provisions-wastewater tanks.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) of this section. (A) Actual emissions tests that use full-size or scale-model wastewater tanks that... the stored liquid. (ix) A gasket, joint, lid, cover, or door has a crack or gap, or is broken. (2)...

  17. In-Tank Elutriation Test Report And Independent Assessment

    SciTech Connect

    Burns, H. H.; Adamson, D. J.; Qureshi, Z. H.; Steeper, T. J.

    2011-04-13

    elevations. Testing revealed that the most important variable was jet velocity which translates to a downstream fluid velocity in the vicinity of the suction tube which can suspend particles and potentially allow their removal from the tank. The optimum jet velocity in the vicinity of the sucti9on tube was between 1.5 and 2 ft/s (4-5 gpm). During testing at lower velocities a significant amount of slow-settling particles remained in the tank. At higher velocities a significant amount of fast-settling particles were elutriated from the tank. It should be noted that this range of velocities is appropriate for this particular geometry and particles. However, the principle of In-Tank Elutriation was proved. In-tank elutriation has the potential to save much money in tank closure. However, more work, both analytical and experimental, must be done before an improved version of the process could be applied to actual waste tanks. It is recommended that testing with more prototypic simulants be conducted. Also, scale-up criteria for elutriation and the resulting size of pilot scale test equipment require investigation during future research. In addition, it is recommended that the use of hydrocyclones be pursued in Phase 2 testing. Hydrocyclones are a precise and efficient separation tool that are frequently used in industry.

  18. Development of simulated tank wastes for the US Department of Energy's Underground Storage Tank Integrated Demonstration

    SciTech Connect

    Elmore, M.R.; Colton, N.G.; Jones, E.O.

    1992-08-01

    The purpose of the Underground Storage Tank Integrated Demonstration (USTID) is to identify and evaluate technologies that may be used to characterize, retrieve, treat, and dispose of hazardous and radioactive wastes contained in tanks on US Department of Energy sites. Simulated wastes are an essential component of the evaluation process because they provide controlled samples for technology assessment, and minimize costs and risks involved when working with radioactive wastes. Pacific Northwest Laboratory has developed a recipe to simulate Hanford single-shell tank, (SST) waste. The recipe is derived from existing process recipes, and elemental concentrations are based on characterization data from 18 SSTs. In this procedure, salt cake and metal oxide/hydroxide sludge are prepared individually, and mixed together at varying ratios depending on the specific tank, waste to be simulated or the test being conducted. Elemental and physical properties of the stimulant are comparable with analyzed tank samples, and chemical speciation in the simulant is being improved as speciation data for actual wastes become available. The nonradioactive chemical waste simulant described here is useful for testing technologies on a small scale.

  19. Candidate reagents and procedures for the dissolution of Hanford Site single-shell tank sludges

    SciTech Connect

    Schulz, W.W.; Kupfer, M.J.

    1991-10-01

    At least some of the waste in the 149 single-shell tanks (SST) at the US Department of Energy (DOE) Hanford Site will be retrieved, treated, and disposed of. Although the importance of devising efficient and cost-effective sludge dissolution procedures has long been recognized, a concerted bench-scale effort to devise and test such procedures with actual solids representative of those in Hanford Site SSTs has not been performed. Reagents that might be used, either individually or serially, to dissolve sludges include HNO{sub 3}, HNO{sub 3}-oxalic acid, and HNO{sub 3}-HF. This report consolidates and updates perspectives and recommendations concerning reagents and procedures for dissolving Hanford Site SST and selected double-shell tank (DST) sludges. The principal objectives of this report are as follows: (1) Compile and review existing experimental data on dissolution of actual Hanford Site SST and DST sludges. (2) Further inform Hanford Site engineers and scientists concerning the utility of combinations of thermally unstable complexants (TUCS) reagents and various reducing agents for dissolving SST and DST sludges. (This latter technology has recently been explored at the Argonne National Laboratory.) (3) Provide guidance in laying out a comprehensive experimental program to develop technology for dissolving all types of Hanford Site SST and DST sludges. 6 refs., 1 fig., 4 tabs.

  20. Identification of potential transuranic waste tanks at the Hanford Site

    SciTech Connect

    Colburn, R.P.

    1995-05-05

    The purpose of this document is to identify potential transuranic (TRU) material among the Hanford Site tank wastes for possible disposal at the Waste Isolation Pilot Plant (WIPP) as an alternative to disposal in the high-level waste (HLW) repository. Identification of such material is the initial task in a trade study suggested in WHC-EP-0786, Tank Waste Remediation System Decisions and Risk Assessment (Johnson 1994). The scope of this document is limited to the identification of those tanks that might be segregated from the HLW for disposal as TRU, and the bases for that selection. It is assumed that the tank waste will be washed to remove soluble inert material for disposal as low-level waste (LLW), and the washed residual solids will be vitrified for disposal. The actual recommendation of a disposal strategy for these materials will require a detailed cost/benefit analysis and is beyond the scope of this document.

  1. Stabilization of Mercury in High pH Tank Sludges

    SciTech Connect

    Spence, R.; Barton, J.

    2003-02-24

    DOE complex contains many tank sludges contaminated with mercury. The high pH of these tank sludges typically fails to stabilize the mercury, resulting in these radioactive wastes also being characteristically hazardous or mixed waste. The traditional treatment for soluble inorganic mercury species is precipitation as insoluble mercuric sulfide. Sulfide treatment and a commercial mercury-stabilizing product were tested on surrogate sludges at various alkaline pH values. Neither the sulfide nor the commercial product stabilized the mercury sufficiently at the high pH of the tank sludges to pass the Toxicity Characteristic Leach Procedure (TCLP) treatment standards of the Resource Conservation and Recovery Act (RCRA). The commercial product also failed to stabilize the mercury in samples of the actual tank sludges.

  2. Laboratory-Scale Column Testing Using IONSIV IE-911 for Removing Cesium from Acidic Tank Waste Simulant. 1: Cesium Exchange Capacity of a 15-cm3 Column and Dynamic Stability of the Exchange Media

    SciTech Connect

    T.J. Tranter; R.D. Tillotson; T.A. Todd

    2005-04-01

    Bench-scale column tests were performed using a commercial form of crystalline silicotitanate (CST) for removing radio-cesium from a surrogate acidic tank solution representative of liquid waste stored at the Idaho National Engineering and Environmental Laboratory (INEEL). An engineered form of CST ion exchanger, known as IONSIVtm IE-911 (UOP, Mt Laurel, NJ, USA), was tested in 15 cm3 columns at a flow rate of 5 bed volumes per hour. These experiments showed the ion exchange material to have reasonable selectivity and capacity for removing cesium from the complex chemical matrix of the solution. However, previous testing indicated that partial neutralization of the feed stream was necessary to increase the stability of the ion exchange media. Thus, in these studies, CST degradation was determined as a function of throughput in order to better assess the stability characteristics of the exchanger for potential future waste treatment applications. Results of these tests indicate that the degradation of the CST reaches a maximum very soon after the acidic feed is introduced to the column and then rapidly declines. Total dissolution of bed material did not exceed 3% under the experimental regime used.

  3. Optical Cryogenic Tank Level Sensor

    NASA Technical Reports Server (NTRS)

    Duffell, Amanda

    2005-01-01

    Cryogenic fluids play an important role in space transportation. Liquid oxygen and hydrogen are vital fuel components for liquid rocket engines. It is also difficult to accurately measure the liquid level in the cryogenic tanks containing the liquids. The current methods use thermocouple rakes, floats, or sonic meters to measure tank level. Thermocouples have problems examining the boundary between the boiling liquid and the gas inside the tanks. They are also slow to respond to temperature changes. Sonic meters need to be mounted inside the tank, but still above the liquid level. This causes problems for full tanks, or tanks that are being rotated to lie on their side.

  4. 131. NORTH PLANT TANK CHEMICAL STORAGE TANKS FROM GB MANUFACTURING ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    131. NORTH PLANT TANK CHEMICAL STORAGE TANKS FROM GB MANUFACTURING PLANT. VIEW TO SOUTHEAST. - Rocky Mountain Arsenal, Bounded by Ninety-sixth Avenue & Fifty-sixth Avenue, Buckley Road, Quebec Street & Colorado Highway 2, Commerce City, Adams County, CO

  5. Material selection for Multi-Function Waste Tank Facility tanks

    SciTech Connect

    Larrick, A.P.; Blackburn, L.D.; Brehm, W.F.; Carlos, W.C.; Hauptmann, J.P.; Danielson, M.J.; Westerman, R.E.; Divine, J.R.; Foster, G.M.

    1995-03-01

    This paper briefly summarizes the history of the materials selection for the US Department of Energy`s high-level waste carbon steel storage tanks. It also provides an evaluation of the materials for the construction of new tanks at the evaluation of the materials for the construction of new tanks at the Multi-Function Waste Tank Facility. The evaluation included a materials matrix that summarized the critical design, fabrication, construction, and corrosion resistance requirements: assessed. each requirement: and cataloged the advantages and disadvantages of each material. This evaluation is based on the mission of the Multi-Function Waste Tank Facility. On the basis of the compositions of the wastes stored in Hanford waste tanks, it is recommended that tanks for the Multi-Function Waste Tank Facility be constructed of ASME SA 515, Grade 70, carbon steel.

  6. Analysis of ammonium sulfate circulation tank failure -- Possible causes and their remediation

    SciTech Connect

    O`Hearn, R.J.

    1997-12-31

    Acme steel manufactures a liquid solution of ammonium sulphate by scrubbing the coke oven gas with a dilute solution of sulphuric acid. When the bath reaches a predetermined specific gravity, it is isolated from the system, neutralized with aqua ammonia, pumped to the shipping tanks, re-charged with water and acid, then placed back in service. To improve the ammonia removal efficiency, three circulation tanks are used in this system. In June 1996, the volume of two of the sulfate solution tanks in the ammonia removal plant were increased by two different pressure events. The first tank was damaged by pressure that was not relieved due to a plugged vent line. The second tank was damaged by a pressure event generated during the process of making ammonium sulfate. This paper will discuss the cause of the second tank`s failure, and the design solution to restart the operation of the plant.

  7. Composite overwrapped metallic tanks

    NASA Technical Reports Server (NTRS)

    Caudill, C. L.; Kirlin, R. L.

    1972-01-01

    Work is reported for fabricating and testing the fiberglass overwrapped titanium pressure vessel for cryogenic service. Difficulties encountered in the tank liner fabrication phase involved explosive forming, vacuum annealing, chemical milling and electron beam welding. While each of these processes and the nondestructive test methods employed are normally considered to be individually reliable, the combination of poor material together with fabrication and development reversals prevented the full achievement of the desired end results. Eight tanks plus a prototype and tool proofing article were produced. Six of the vessels failed during the hydrostatic sizing operation. One of the remaining tanks was hydrostatically pressurized to burst and the other was pressurized repeatedly at 75 F from 100 psi to the operating pressure until failure occurred. As a result, it is not possible to draw firm conclusions as to the true value of the design concept due to the problems encountered in the program.

  8. Fireman's Air Tanks

    NASA Technical Reports Server (NTRS)

    1976-01-01

    Together with NASA's Johnson Space Center, A-T-O Inc.'s Scott Aviation has developed light-weight firefighter's air tanks. New backpack system weighs only 20 pounds for 30 minute air supply, 13 pounds less than conventional firefighting tanks. They are pressurized at 4,500 psi, (twice current tanks). Made of aluminum liner wrapped by resin-impregnated glass fibers, eliminating corrosion as well as lightening the load. Redesigned face mask permits better vision. Warning device to tell fireman he is running out of air is personalized so it can't be heard by others reducing confusion in an already hectic environment. Structural Composites Inc., The Boeing Co., and Martin- Marietta Corp. have developed uses for this technology.

  9. Above- and underground storage tanks

    SciTech Connect

    Canning, K.; Kilbourne, A.

    1997-09-01

    Storage tanks are the primary means of storing liquid, fluid and gas products. Federal and state environmental regulations, as well as local building and fire codes, take into account leaks and spills, tank emissions, underground tank seepage and safety issues, and they define standards for tank manufacturers and owners. For specific regulatory information pertaining to your application, contact the local authorities having jurisdiction. Storage tanks listed within this product guide have been classified as underground or aboveground, with subcategories including modular, process and temporary tanks. Tank construction materials include aluminum, carbon steel, concrete, fiberglass-reinforced plastic (FRP) and stainless steel. A variety of accessories, including automatic tank gauging systems, level monitors, leak detectors, overfill protection and tank inspection systems, also are listed. Aboveground storage tanks (ASTs) have less than 10 percent of their tank volume and piping below ground. Available in both vertical and horizontal configurations, they can be either erected in the field or fabricated in a factory. Underground storage tanks (USTs) are primarily used to contain regulated substances; USTs have at least 10% of their tank volume and piping buried belowground. Common UST construction materials include carbon steel, coated steel, cathodically protected steel and FRP. USTs are required to have corrosion protection, spill and overfill prevention and control and release detection in place by December 1998.

  10. Waste Tank Organic Safety Program: Analytical methods development. Progress report, FY 1994

    SciTech Connect

    Campbell, J.A.; Clauss, S.A.; Grant, K.E.

    1994-09-01

    The objectives of this task are to develop and document extraction and analysis methods for organics in waste tanks, and to extend these methods to the analysis of actual core samples to support the Waste Tank organic Safety Program. This report documents progress at Pacific Northwest Laboratory (a) during FY 1994 on methods development, the analysis of waste from Tank 241-C-103 (Tank C-103) and T-111, and the transfer of documented, developed analytical methods to personnel in the Analytical Chemistry Laboratory (ACL) and 222-S laboratory. This report is intended as an annual report, not a completed work.

  11. Complex dynamic behavior in the bromate-oxalic acid-acetone-Mn(II) oscillating reaction in a continuous stirred tank reactor (CSTR)

    NASA Astrophysics Data System (ADS)

    Silva, Lucyane C.; Faria, Roberto B.

    2007-05-01

    The oscillating reaction bromate-oxalic acid-acetone-Mn(II)-sulfuric acid was observed for the first time in a CSTR at 20 °C. Depending on the bromate concentrations and flow rate, the system showed large amplitude oscillations, two kinds of mixed mode oscillations, quasiperiodicity and bursts of large amplitude oscillations, all mapped in a phase diagram. More complex behavior was favored at low bromate concentrations. The system without acetone was discovered to oscillate too, but the more complex patterns were not seen, indicating that acetone is implied in their formation.

  12. Tank depletion flow controller

    DOEpatents

    Georgeson, Melvin A.

    1976-10-26

    A flow control system includes two bubbler tubes installed at different levels within a tank containing such as radioactive liquid. As the tank is depleted, a differential pressure transmitter monitors pressure differences imparted by the two bubbler tubes at a remote, shielded location during uniform time intervals. At the end of each uniform interval, balance pots containing a dense liquid are valved together to equalize the pressures. The resulting sawtooth-shaped signal generated by the differential pressure transmitter is compared with a second sawtooth signal representing the desired flow rate during each time interval. Variations in the two signals are employed by a control instrument to regulate flow rate.

  13. TANK SPACE OPTIONS REPORT

    SciTech Connect

    WILLIS WL; AHRENDT MR

    2009-08-11

    Since this report was originally issued in 2001, several options proposed for increasing double-shell tank (DST) storage space were implemented or are in the process of implementation. Changes to the single-shell tank (SST) waste retrieval schedule, completion of DST space saving options, and the DST space saving options in progress have delayed the projected shortfall of DST storage space from the 2007-2011 to the 2018-2025 timeframe (ORP-11242, River Protection Project System Plan). This report reevaluates options from Rev. 0 and includes evaluations of new options for alleviating projected restrictions on SST waste retrieval beginning in 2018 because of the lack of DST storage space.

  14. 33 CFR 157.15 - Slop tanks in tank vessels.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) POLLUTION RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING... ballast water containing an oily mixture of 3 percent or more of the oil carrying capacity. Two percent... tank. (2) A new vessel of 70,000 tons DWT or more must have at least two slop tanks. (b) Capacity....

  15. 33 CFR 157.15 - Slop tanks in tank vessels.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) POLLUTION RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING... ballast water containing an oily mixture of 3 percent or more of the oil carrying capacity. Two percent... tank. (2) A new vessel of 70,000 tons DWT or more must have at least two slop tanks. (b) Capacity....

  16. 33 CFR 157.15 - Slop tanks in tank vessels.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) POLLUTION RULES FOR THE PROTECTION OF THE MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING... ballast water containing an oily mixture of 3 percent or more of the oil carrying capacity. Two percent... tank. (2) A new vessel of 70,000 tons DWT or more must have at least two slop tanks. (b) Capacity....

  17. Design criteria monograph for metal tanks and tank components

    NASA Technical Reports Server (NTRS)

    1975-01-01

    Significant elements in detail tank design are wall and end structures, weld joints at bulkhead and attachment junctures, and ports and access openings. Additional design considerations are influence and effect of fabrication processes on tank component design, and finally, testing and inspection that are required to establish confidence in tank design.

  18. Tank plan for tank 241-C-104 retrieval testing

    SciTech Connect

    HERTING, D.L.

    1999-05-21

    Tank 241-C-104 has been identified as one of the first tanks to be retrieved for high-level waste pretreatment and immobilization. Retrieval of the tank waste will require dilution. Laboratory tests are needed to determine the amount of dilution required for safe retrieval and transfer of feed. The proposed laboratory tests are described in this document.

  19. 46 CFR 153.266 - Tank linings.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... LIQUID, LIQUEFIED GAS, OR COMPRESSED GAS HAZARDOUS MATERIALS Design and Equipment Cargo Tanks § 153.266 Tank linings. A tank lining must be: (a) At least as elastic as the tank material; and (b) Applied or...

  20. Enhanced Waste Tank Level Model

    SciTech Connect

    Duignan, M.R.

    1999-06-24

    'With the increased sensitivity of waste-level measurements in the H-Area Tanks and with periods of isolation, when no mass transfer occurred for certain tanks, waste-level changes have been recorded with are unexplained.'

  1. Tanks Emissions for TRI Reporting

    EPA Pesticide Factsheets

    A presentation on overcoming the challenges of TRI reporting for and monitoring the hazardous air emissions from storage tanks, including a discussion on the most accurate and feasible methods of correctly reporting tank emissions to the TRI Program.

  2. Enhanced Waste Tank Level Model

    SciTech Connect

    Duignan, M.R.

    1999-06-24

    'With the increased sensitivity of waste-level measurements in the H-Area Tanks and with periods of isolation, when no mass transfer occurred for certain tanks, waste-level changes have been recorded with are unexplained.'

  3. The solubilities of significant organic compounds in HLW tanks upernate solutions - FY 1997 progress report

    SciTech Connect

    Barney, G.S.

    1997-09-16

    The solubilities of seven sodium salts of organic acids that are thought to exist in high-level waste at the Hanford Site were measured in tank supernatant simulant solutions during FY 1997. This solubility information will be used to determine if these organic salts could exist in solid phases (saltcake or sludges) in the waste where they might react violently with the nitrate or nitrite salts present in the tanks. The solubility of sodium acetate was measured in simulated waste supernate solutions at 25C, 30C, 40C, and 50C that were both unsaturated and saturated with sodium nitrate. Solubilities of sodium glycolate, citrate, ethylenediaminetetraacetate (EDTA), nitrilotriacetate (NTA), formate, and oxalate were measured in simulated waste supernate solutions that were saturated with sodium nitrate. In addition, solubilities of sodium EDTA, citrate, glycolate, and NTA were measured in a complex waste matrix. The organic compounds were selected because they are expected to exist in relatively high concentrations in the tanks. The solubilities of sodium glycolate citrate, EDTA, NTA, and formate were high over the temperature and sodium hydroxide concentration ranges expected in the tanks. The solubility of sodium oxalate in solutions saturated with sodium nitrate were quite low. The presence of additional sodium in the waste simulant solutions that were saturated with sodium nitrate slightly lowered the solubilities of each of the organic salts. Solubilities were, however, high enough to prevent solid sodium salts of all the organic acids from precipitating from tank supernate solutions, except for sodium oxalate. The total organic carbon concentrations (TOC) of actual tank supernates are generally much lower than the TOC ranges for the simulated supernate solutions saturated (at the solubility limit) with the organic salts. This is true even if all the dissolved carbon in a given tank supernate is due to only one of these soluble compounds (an unlikely situation

  4. Boehmite Actual Waste Dissolutions Studies

    SciTech Connect

    Snow, Lanee A.; Lumetta, Gregg J.; Fiskum, Sandra K.; Peterson, Reid A.

    2008-07-15

    The U.S. Department of Energy plans to vitrify approximately 60,000 metric tons of high-level waste (HLW) sludge from underground storage tanks at the Hanford Nuclear Reservation. To reduce the volume of HLW requiring treatment, a goal has been set to remove a significant quantity of the aluminum, which comprises nearly 70 percent of the sludge. Aluminum is found in the form of gibbsite, sodium aluminate and boehmite. Gibbsite and sodium aluminate can be easily dissolved by washing the waste stream with caustic. Boehmite, which comprises nearly half of the total aluminum, is more resistant to caustic dissolution and requires higher treatment temperatures and hydroxide concentrations. Samples were taken from four Hanford tanks and homogenized in order to give a sample that is representative of REDOX (Reduction Oxidation process for Pu recovery) sludge solids. Bench scale testing was performed on the homogenized waste to study the dissolution of boehmite. Dissolution was studied at three different hydroxide concentrations, with each concentration being run at three different temperatures. Samples were taken periodically over the 170 hour runs in order to determine leaching kinetics. Results of the dissolution studies and implications for the proposed processing of these wastes will be discussed.

  5. Fiscal year 1995 laboratory scale studies of Cs elution in Tank 8D-1 and sludge dissolution in tank 8D-2

    SciTech Connect

    Sills, J.A.; Patello, G.K.; Roberts, J.S.; Wiemers, K.D.; Elmore, M.R.; Richmond, W.G.; Russell, R.L.

    1996-04-01

    During Phase I of West Valley Demonstration project waste remediation, an estimated 95% of the zeolite currently in tank 8D-1 will be transferred to tank 8D-2, leaving behind residual Cs-loaded zeolite which will require treatment to remove the Cs. After phase I vitrification, tank 8D-2 will contain residual waste from PUREX and THOREX and spent Cs-loaded zeolite. The residual waste will require treatment. Oxalic acid has been proposed for eluting Cs from zeolite in tank 8D-1 and dissolving radionuclides in tank 8D-2. Laboratory tests were performed to determine optimum Cs elution and sludge dissolution conditions and to evaluate effects of multiple contacts, long-term contacts, presence of corrosion products, lack of agitation, temperature of tank contents, and oxalic acid concentration. Mild steel corrosion tests were also conducted.

  6. Soil load above Hanford waste storage tanks (2 volumes)

    SciTech Connect

    Pianka, E.W.

    1995-01-25

    This document is a compilation of work performed as part of the Dome Load Control Project in 1994. Section 2 contains the calculations of the weight of the soil over the tank dome for each of the 75-feet-diameter waste-storage tanks located at the Hanford Site. The chosen soil specific weight and soil depth measured at the apex of the dome crown are the same as those used in the primary analysis that qualified the design. Section 3 provides reference dimensions for each of the tank farm sites. The reference dimensions spatially orient the tanks and provide an outer diameter for each tank. Section 4 summarizes the available soil surface elevation data. It also provides examples of the calculations performed to establish the present soil elevation estimates. The survey data and other data sources from which the elevation data has been obtained are printed separately in Volume 2 of this Supporting Document. Section 5 contains tables that provide an overall summary of the present status of dome loads. Tables summarizing the load state corresponding to the soil depth and soil specific weight for the original qualification analysis, the gravity load requalification for soil depth and soil specific weight greater than the expected actual values, and a best estimate condition of soil depth and specific weight are presented for the Double-Shell Tanks. For the Single-Shell Tanks, only the original qualification analysis is available; thus, the tabulated results are for this case only. Section 6 provides a brief overview of past analysis and testing results that given an indication of the load capacity of the waste storage tanks that corresponds to a condition approaching ultimate failure of the tank. 31 refs.

  7. Development of a High Level Waste Tank Inspection System

    SciTech Connect

    Appel, D.K.; Loibl, M.W.; Meese, D.C.

    1995-03-21

    The Westinghouse Savannah River Technology Center was requested by it`s sister site, West Valley Nuclear Service (WVNS), to develop a remote inspection system to gather wall thickness readings of their High Level Waste Tanks. WVNS management chose to take a proactive approach to gain current information on two tanks t hat had been in service since the early 70`s. The tanks contain high level waste, are buried underground, and have only two access ports to an annular space between the tank and the secondary concrete vault. A specialized remote system was proposed to provide both a visual surveillance and ultrasonic thickness measurements of the tank walls. A magnetic wheeled crawler was the basis for the remote delivery system integrated with an off-the-shelf Ultrasonic Data Acquisition System. A development program was initiated for Savannah River Technology Center (SRTC) to design, fabricate, and test a remote system based on the Crawler. The system was completed and involved three crawlers to perform the needed tasks, an Ultrasonic Crawler, a Camera Crawler, and a Surface Prep Crawler. The crawlers were computer controlled so that their operation could be done remotely and their position on the wall could be tracked. The Ultrasonic Crawler controls were interfaced with ABB Amdata`s I-PC, Ultrasonic Data Acquisition System so that thickness mapping of the wall could be obtained. A second system was requested by Westinghouse Savannah River Company (WSRC), to perform just ultrasonic mapping on their similar Waste Storage Tanks; however, the system needed to be interfaced with the P-scan Ultrasonic Data Acquisition System. Both remote inspection systems were completed 9/94. Qualifications tests were conducted by WVNS prior to implementation on the actual tank and tank development was achieved 10/94. The second inspection system was deployed at WSRC 11/94 with success, and the system is now in continuous service inspecting the remaining high level waste tanks at WSRC.

  8. OXALATE MASS BALANCE DURING CHEMICAL CLEANING IN TANK 6F

    SciTech Connect

    Poirier, M.; Fink, S.

    2011-07-22

    The Savannah River Remediation (SRR) is preparing Tank 6F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning to determine whether the tank is ready for closure. SRR personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. Analysis of the anions showed the measured oxalate removed from Tank 6F to be approximately 50% of the amount added in the oxalic acid. To close the oxalate mass balance, the author collected solid samples, leached them with nitric acid, and measured the concentration of cations and anions in the leachate. Some conclusions from this work are: (1) Approximately 65% of the oxalate added as oxalic acid was removed with the decanted liquid. (2) Approximately 1% of the oxalate (added to the tank as oxalic acid) formed precipitates with compounds such as nickel, manganese, sodium, and iron (II), and was dissolved with nitric acid. (3) As much as 30% of the oxalate may have decomposed forming carbon dioxide. The balance does not fully account for all the oxalate added. The offset represents the combined uncertainty in the analyses and sampling.

  9. VOLUMETRIC TANK TESTING: AN OVERVIEW

    EPA Science Inventory

    This report summarizes the technical findings of an EPA study on volumetric tank testing. It describes the results of the EPA study, which evaluated the viability of volumetric tank tests as a means of detecting leaks in underground storage tanks. It explains the accuracy requi...

  10. VOLUMETRIC TANK TESTING: AN OVERVIEW

    EPA Science Inventory

    This report summarizes the technical findings of an EPA study on volumetric tank testing. The results of this study, which evaluated the viability of volumetric tank tests as a means of detecting leaks in underground storage tanks, are described. Also, the accuracy requirements s...

  11. Treatment of radioactive wastes from DOE underground storage tanks

    SciTech Connect

    Collins, J.L.; Egan, B.Z.; Spencer, B.B.; Chase, C.W.; Anderson, K.K.; Bell, J.T.

    1994-06-01

    Bench-scale batch tests have been conducted with sludge and supernate tank waste from the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to evaluate separation technology process for use in a comprehensive sludge processing flow sheet as a means of concentrating the radionuclides and reducing the volumes of storage tank waste at national sites for final disposal. This paper discusses the separation of the sludge solids and supernate, the basic washing of the sludge solids, the acidic dissolution of the sludge solids, and the removal of the radionuclides from the supernate.

  12. Plating Tank Control Software

    SciTech Connect

    Krafcik, John

    1998-03-01

    The Plating Tank Control Software is a graphical user interface that controls and records plating process conditions for plating in high aspect ratio channels that require use of low current and long times. The software is written for a Pentium II PC with an 8 channel data acquisition card, and the necessary shunt resistors for measuring currents in the millampere range.

  13. Hybrid Tank Technology

    NASA Technical Reports Server (NTRS)

    2004-01-01

    Researchers have accomplished great advances in pressure vessel technology by applying high-performance composite materials as an over-wrap to metal-lined pressure vessels. These composite over-wrapped pressure vessels (COPVs) are used in many areas, from air tanks for firefighters and compressed natural gas tanks for automobiles, to pressurant tanks for aerospace launch vehicles and propellant tanks for satellites and deep-space exploration vehicles. NASA and commercial industry are continually striving to find new ways to make high-performance pressure vessels safer and more reliable. While COPVs are much lighter than all-metal pressure vessels, the composite material, typically graphite fibers with an epoxy matrix resin, is vulnerable to impact damage. Carbon fiber is most frequently used for the high-performance COPV applications because of its high strength-to-weight characteristics. Other fibers have been used, but with limitations. For example, fiberglass is inexpensive but much heavier than carbon. Aramid fibers are impact resistant but have less strength than carbon and their performance tends to deteriorate.

  14. Tank bump consequence analysis

    SciTech Connect

    Board, B.D.

    1996-08-07

    The purpose of this document is to derive radiological and toxicological consequences for a tank bump event based on analysis performed using the GOTH computer model, to estimate the mitigative effect of pump and sluice pit cover blocks, and to discuss preventative measures.

  15. Tank bump consequence analysis

    SciTech Connect

    Board, B.D.

    1996-09-01

    The purpose of this document is to derive radiological and toxicological consequences for a tank bump event based on analysis performed using the GOTH computer model, to estimate the mitigative effect of pump and sluice pit cover blocks, and to discuss preventative measures.

  16. SLUDGE BATCH 7B QUALIFICATION ACTIVITIES WITH SRS TANK FARM SLUDGE

    SciTech Connect

    Pareizs, J.; Click, D.; Lambert, D.; Reboul, S.

    2011-11-16

    projected noble metals content for SB7b. Characterization was performed on the Tank 51 SB7b samples and SRNL performed DWPF simulations using the Tank 40 SB7b material. This report documents: (1) The preparation and characterization of the Tank 51 SB7b and Tank 40 SB7b samples. (2) The performance of a DWPF Chemical Process Cell (CPC) simulation using the SB7b Tank 40 sample. The simulation included a Sludge Receipt and Adjustment Tank (SRAT) cycle, where acid was added to the sludge to destroy nitrite and reduce mercury, and a Slurry Mix Evaporator (SME) cycle, where glass frit was added to the sludge in preparation for vitrification. The SME cycle also included replication of five canister decontamination additions and concentrations. Processing parameters were based on work with a nonradioactive simulant. (3) Vitrification of a portion of the SME product and characterization and durability testing (as measured by the Product Consistency Test (PCT)) of the resulting glass. (4) Rheology measurements of the SRAT receipt, SRAT product, and SME product. This program was controlled by a Task Technical and Quality Assurance Plan (TTQAP), and analyses were guided by an Analytical Study Plan. This work is Technical Baseline Research and Development (R&D) for the DWPF. It should be noted that much of the data in this document has been published in interoffice memoranda. The intent of this technical report is bring all of the SB7b related data together in a single permanent record and to discuss the overall aspects of SB7b processing.

  17. Thermally resistant polymers for fuel tank sealants

    NASA Technical Reports Server (NTRS)

    Webster, J. A.

    1973-01-01

    Imide-linked perfluoroalkylene ether polymers, that were developed for the high temperature fuel tank sealant application, are discussed. Modifications of polymer structure and properties were realized through use of a new aromatic dianhydride intermediate containing an ether-linked perfluoroalkylene segment. Tests of thermal, oxidative and hydrolytic stability, fuel resistance, and adhesion are discussed along with tensile strength and elongation results. Efforts to effect a low temperature condensation of amic acid prepolymer to form imide links inside are described.

  18. Tank System Integrated Model: A Cryogenic Tank Performance Prediction Program

    NASA Technical Reports Server (NTRS)

    Bolshinskiy, L. G.; Hedayat, A.; Hastings, L. J.; Sutherlin, S. G.; Schnell, A. R.; Moder, J. P.

    2017-01-01

    Accurate predictions of the thermodynamic state of the cryogenic propellants, pressurization rate, and performance of pressure control techniques in cryogenic tanks are required for development of cryogenic fluid long-duration storage technology and planning for future space exploration missions. This Technical Memorandum (TM) presents the analytical tool, Tank System Integrated Model (TankSIM), which can be used for modeling pressure control and predicting the behavior of cryogenic propellant for long-term storage for future space missions. Utilizing TankSIM, the following processes can be modeled: tank self-pressurization, boiloff, ullage venting, mixing, and condensation on the tank wall. This TM also includes comparisons of TankSIM program predictions with the test data andexamples of multiphase mission calculations.

  19. Linguistic Theory and Actual Language.

    ERIC Educational Resources Information Center

    Segerdahl, Par

    1995-01-01

    Examines Noam Chomsky's (1957) discussion of "grammaticalness" and the role of linguistics in the "correct" way of speaking and writing. It is argued that the concern of linguistics with the tools of grammar has resulted in confusion, with the tools becoming mixed up with the actual language, thereby becoming the central…

  20. Linguistic Theory and Actual Language.

    ERIC Educational Resources Information Center

    Segerdahl, Par

    1995-01-01

    Examines Noam Chomsky's (1957) discussion of "grammaticalness" and the role of linguistics in the "correct" way of speaking and writing. It is argued that the concern of linguistics with the tools of grammar has resulted in confusion, with the tools becoming mixed up with the actual language, thereby becoming the central…

  1. El Observatorio Gemini - Status actual

    NASA Astrophysics Data System (ADS)

    Levato, H.

    Se hace una breve descripción de la situación actual del Observatorio Gemini y de las últimas decisiones del Board para incrementar la eficiencia operativa. Se hace también una breve referencia al uso argentino del observatorio.

  2. 22. Public Works Department Drawing 461M9 (1931), 'Platform and Tanks ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    22. Public Works Department Drawing 461-M-9 (1931), 'Platform and Tanks For Acid and Distilled Water' - Mare Island Naval Shipyard, Acid Mixing Facility, California Avenue & E Street, Vallejo, Solano County, CA

  3. Tanks focus area. Annual report

    SciTech Connect

    Frey, J.

    1997-12-31

    The U.S. Department of Energy Office of Environmental Management is tasked with a major remediation project to treat and dispose of radioactive waste in hundreds of underground storage tanks. These tanks contain about 90,000,000 gallons of high-level and transuranic wastes. We have 68 known or assumed leaking tanks, that have allowed waste to migrate into the soil surrounding the tank. In some cases, the tank contents have reacted to form flammable gases, introducing additional safety risks. These tanks must be maintained in the safest possible condition until their eventual remediation to reduce the risk of waste migration and exposure to workers, the public, and the environment. Science and technology development for safer, more efficient, and cost-effective waste treatment methods will speed up progress toward the final remediation of these tanks. The DOE Office of Environmental Management established the Tanks Focus Area to serve as the DOE-EM`s technology development program for radioactive waste tank remediation in partnership with the Offices of Waste Management and Environmental Restoration. The Tanks Focus Area is responsible for leading, coordinating, and facilitating science and technology development to support remediation at DOE`s four major tank sites: the Hanford Site in Washington State, Idaho National Engineering and Environmental Laboratory in Idaho, Oak Ridge Reservation in Tennessee, and the Savannah River Site in South Carolina. The technical scope covers the major functions that comprise a complete tank remediation system: waste retrieval, waste pretreatment, waste immobilization, tank closure, and characterization of both the waste and tank. Safety is integrated across all the functions and is a key component of the Tanks Focus Area program.

  4. Tank characterization report for Single-Shell Tank T-102

    SciTech Connect

    Remund, K.M.; Hartley, S.A.; Toth, J.J.; Tingey, J.M.; Heasler, P.G.; Ryan, F.M.; Simpson, B.C.

    1994-09-01

    Tank 241-T-102 (hereafter referred to as T-102) is a 530,000 gallon single-shell waste tank located in the 200 West T Tank farm at the Hanford Site. In 1993, two cores were taken from this tank and analysis of the cores was conducted by Battelle`s 325-A Laboratory. Characterization of the waste in this tank was conducted to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-44-05. Tank T-102 was constructed in 1943 and put into service in 1945; it is the second tank in a cascade system with Tanks T-101 and T-103. During its process history, Tank T-102 received mostly Metal Waste (MW) from the Bismuth Phosphate Process and Coating Waste (CW) from the REDOX Process via the cascade from Tank T-101 and in transfers from Tank C-102. In 1956, the MW was removed from T-102 by pumping and sluicing`. This tank was declared inactive and retired from service in 1976. In 1981, intrusion prevention and stabilization measures were taken to isolate the waste in T-102. The tank presently contains approximately 121,100 liters (32,000 gallons) of liquid and sludge-like waste. Historically, there are no unreviewed safety issues associated with this tank and none were revealed after reviewing the data from the latest core sampling event in 1993. An extensive set of analytical measurements was performed on the core composites. The major constituents (>0.5 wt%) of the waste are water, aluminum, sodium, iron, and nitrate, ordered from the largest concentration to the smallest. The concentrations and inventories of these and other constituents are given. The results of the chemical analyses have been compared to the dangerous waste codes in the Washington Dangerous Waste Regulations (WAC 173-303).

  5. FY2003 Visual examination of In Tank and Tank annuli at 241-SY tank farm

    SciTech Connect

    AFTANAS, B.L.

    2003-07-08

    This report documents the completion of the FY 2003 in-tank and annulus video inspections for the 241-SY tank farms. Representative photos of observed anomalies, water-streaks, corrosion deposits, pitting, and in-tank strains on the 241-SY-101, 102 & 103

  6. 49 CFR 179.500 - Specification DOT-107A * * * * seamless steel tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Specification DOT-107A * * * * seamless steel tank...) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.500 Specification DOT-107A * * * * seamless steel tank car tanks....

  7. 49 CFR 179.500 - Specification DOT-107A * * * * seamless steel tank car tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Specification DOT-107A * * * * seamless steel tank...) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.500 Specification DOT-107A * * * * seamless steel tank car tanks....

  8. 49 CFR 179.500 - Specification DOT-107A * * * * seamless steel tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Specification DOT-107A * * * * seamless steel tank... REGULATIONS SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.500 Specification DOT-107A * * * * seamless steel tank car tanks....

  9. 49 CFR 179.500 - Specification DOT-107A * * * * seamless steel tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Specification DOT-107A * * * * seamless steel tank...) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.500 Specification DOT-107A * * * * seamless steel tank car tanks....

  10. 49 CFR 179.500 - Specification DOT-107A * * * * seamless steel tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Specification DOT-107A * * * * seamless steel tank...) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.500 Specification DOT-107A * * * * seamless steel tank car tanks....

  11. 49 CFR 179.301 - Individual specification requirements for multi-unit tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ...-unit tank car tanks. 179.301 Section 179.301 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Multi-Unit Tank Car Tanks (Classes DOT-106A and 110AW) § 179.301 Individual specification requirements for multi-unit tank car tanks. (a) In addition...

  12. 49 CFR 179.201 - Individual specification requirements applicable to non-pressure tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... to non-pressure tank car tanks. 179.201 Section 179.201 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Non-Pressure Tank Car Tanks (Classes DOT-111AW and 115AW) § 179.201 Individual specification requirements applicable to non-pressure tank car tanks....

  13. 49 CFR 179.201 - Individual specification requirements applicable to non-pressure tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... to non-pressure tank car tanks. 179.201 Section 179.201 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Non-Pressure Tank Car Tanks (Classes DOT-111AW and 115AW) § 179.201 Individual specification requirements applicable to non-pressure tank car tanks....

  14. 49 CFR 179.301 - Individual specification requirements for multi-unit tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ...-unit tank car tanks. 179.301 Section 179.301 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Multi-Unit Tank Car Tanks (Classes DOT-106A and 110AW) § 179.301 Individual specification requirements for multi-unit tank car tanks. (a) In addition...

  15. 49 CFR 179.400 - General specification applicable to cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... liquid tank car tanks. 179.400 Section 179.400 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400 General specification applicable to cryogenic liquid tank...

  16. 49 CFR 179.400 - General specification applicable to cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... liquid tank car tanks. 179.400 Section 179.400 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400 General specification applicable to cryogenic liquid tank...

  17. 49 CFR 179.101 - Individual specification requirements applicable to pressure tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... to pressure tank car tanks. 179.101 Section 179.101 Transportation Other Regulations Relating to... MATERIALS REGULATIONS SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT... tank car tanks. Editorial Note: At 66 FR 45186, Aug. 28, 2001, an amendment published amending a...

  18. 49 CFR 179.301 - Individual specification requirements for multi-unit tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ...-unit tank car tanks. 179.301 Section 179.301 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Multi-Unit Tank Car Tanks (Classes DOT-106A and 110AW) § 179.301 Individual specification requirements for multi-unit tank car tanks. (a) In addition...

  19. 49 CFR 179.201 - Individual specification requirements applicable to non-pressure tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... to non-pressure tank car tanks. 179.201 Section 179.201 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Non-Pressure Tank Car Tanks (Classes DOT-111AW and 115AW) § 179.201 Individual specification requirements applicable to non-pressure tank car tanks....

  20. 49 CFR 179.400 - General specification applicable to cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... liquid tank car tanks. 179.400 Section 179.400 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400 General specification applicable to cryogenic liquid tank...

  1. 49 CFR 179.301 - Individual specification requirements for multi-unit tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ...-unit tank car tanks. 179.301 Section 179.301 Transportation Other Regulations Relating to... MATERIALS REGULATIONS SPECIFICATIONS FOR TANK CARS Specifications for Multi-Unit Tank Car Tanks (Classes DOT-106A and 110AW) § 179.301 Individual specification requirements for multi-unit tank car tanks. (a)...

  2. AN ASSESSMENT OF THE SERVICE HISTORY AND CORROSION SUSCEPTIBILITY OF TYPE IV WASTE TANKS

    SciTech Connect

    Wiersma, B

    2008-09-18

    Type IV waste tanks were designed and built to store waste that does not require auxiliary cooling. Each Type IV tank is a single-shell tank constructed of a steel-lined pre-stressed concrete tank in the form of a vertical cylinder with a concrete domed roof. There are four such tanks in F-area, Tanks 17-20F, and four in H-Area, Tanks 21-24H. Leak sites were discovered in the liners for Tanks 19 and 20F in the 1980's. Although these leaks were visually observed, the investigation to determine the mechanism by which the leaks had occurred was not completed at that time. Therefore, a concern was raised that the same mechanism which caused the leak sites in the Tanks in F-area may also be operable in the H-Area tanks. Data from the construction of the tanks (i.e., certified mill test reports for the steel, no stress-relief), the service history (i.e., waste sample data, temperature data), laboratory tests on actual wastes and simulants (i.e., electrochemical testing), and the results of the visual inspections were reviewed. The following observations and conclusions were made: (1) Comparison of the compositional and microstructural features indicate that the A212 material utilized for construction of the H-Area tanks are far more resistant to SCC than the A285 materials used for construction of the F-Area tanks. (2) A review of the materials of construction, temperature history, service histories concluded that F-Area tanks likely failed by caustic stress corrosion cracking. (3) The environment in the F-Area tanks was more aggressive than that experienced by the H-Area tanks. (4) Based on a review of the service history, the H-Area tanks have not been exposed to an environment that would render the tanks susceptible to either nitrate stress corrosion cracking (i.e., the cause of failures in the Type I and II tanks) or caustic stress corrosion cracking. (5) Due to the very dilute and uninhibited solutions that have been stored in Tank 23H, vapor space corrosion has

  3. Storage tanks under earthquake loading

    SciTech Connect

    Rammerstorfer, F.G.; Scharf, K. ); Fisher, F.D. )

    1990-11-01

    This is a state-of-the-art review of various treatments of earthquake loaded liquid filled shells by the methods of earthquake engineering, fluid dynamics, structural and soil dynamics, as well as the theory of stability and computational mechanics. Different types of tanks and different possibilities of tank failure will be discussed. The authors will emphasize cylindrical above-ground liquid storage tanks with vertical axis. But many of the treatments are also valid for other tank configurations. For the calculation of the dynamically activated pressure due to an earthquake a fluid-structure-soil interaction problem must be solved. The review will describe the methods, proposed by different authors, to solve this interaction problem. To study the dynamic behavior of liquid storage tanks, one must distinguish between anchored and unanchored tanks. In the case of an anchored tank, the tank bottom edge is fixed to the foundation. If the tank is unanchored, partial lifting of the tank's bottom may occur, and a strongly nonlinear problem has to be solved. They will compare the various analytical and numerical models applicable to this problem, in combination with experimental data. An essential aim of this review is to give a summary of methods applicable as tools for an earthquake resistant design, which can be used by an engineer engaged in the construction of liquid storage tanks.

  4. Toxic chemical considerations for tank farm releases. Revision 1

    SciTech Connect

    Van Keuren, J.C.

    1995-11-01

    This document provides a method of determining the toxicological consequences of accidental releases from Hanford Tank Farms. A determination was made of the most restrictive toxic chemicals that are expected to be present in the tanks. Concentrations were estimated based on the maximum sample data for each analyte in all the tanks in the composite. Composite evaluated were liquids and solids from single shell tanks, double shell tanks, flammable gas watch list tanks, as well as all solids, all liquids, head space gases, and 241-C-106 solids. A sum of fractions of the health effects was computed for each composite for unit releases based emergency response planning guidelines (ERPGs). Where ERPGs were not available for chemical compounds of interest, surrogate guidelines were established. The calculation method in this report can be applied to actual release scenarios by multiplying the sum of fractions by the release rate for continuous releases, or the release amount for puff releases. Risk guidelines are met if the product is less than for equal to one.

  5. Precipitation of nitrate-cancrinite in Hanford Tank Sludge.

    PubMed

    Buck, E C; McNamara, B K

    2004-08-15

    The chemistry of underground storage tanks containing high-level waste at the Hanford Site in Washington State is an area of continued research interest. Thermodynamic models have predicted the formation of analcime and clinoptilolite in Hanford tanks, rather than cancrinite; however, these predictions were based on carbonate-cancrinite. We report the first observation of a nitrate-cancrinite [possibly Na8(K,Cs)(AlSiO4)6(NO3)2 x nH2O] extracted from a Hanford tank 241-AP-101 sample that was evaporated to 6, 8, and 10 M NaOH concentrations. The nitrate-cancrinite phase formed spherical aggregates (4 microm in diameter) that consisted of platy hexagonal crystals (approximately 0.2 microm thick). Cesium-137 was concentrated in these aluminosilicate structures. These phases possessed a morphology identical to that of nitrate-cancrinite synthesized using simulant tests of nonradioactive tank waste, supporting the contention that it is possible to develop nonradioactive artificial sludges. This investigation points to the continued importance of understanding the solubility of NO3-cancrinite and related phases. Knowledge of the detailed structure of actual phases in the tank waste helps with thermodynamic modeling of tank conditions and waste processing.

  6. Grout and glass performance in support of stabilization/solidification of ORNL tank sludges

    SciTech Connect

    Spence, R.D.; Mattus, C.H.; Mattus, A.J.

    1998-09-01

    Wastewater at Oak Ridge National Laboratory (ORNL) is collected, evaporated, and stored in the Melton Valley Storage Tanks (MVST) and Bethel Valley Evaporator Storage Tanks (BVEST) pending treatment for disposal. In addition, some sludges and supernatants also requiring treatment remain in two inactive tank systems: the gunite and associated tanks (GAAT) and the old hydrofracture (OHF) tank. The waste consists of two phases: sludge and supernatant. The sludges contain a high amount of radioactivity, and some are classified as TRU sludges. Some Resource Conservation and Recovery Act (RCRA) metal concentrations are high enough to be defined as RCRA hazardous; therefore, these sludges are presumed to be mixed TRU waste. Grouting and vitrification are currently two likely stabilization/solidification alternatives for mixed wastes. Grouting has been used to stabilize/solidify hazardous and low-level radioactive waste for decades. Vitrification has been developed as a high-level radioactive alternative for decades and has been under development recently as an alternative disposal technology for mixed waste. The objective of this project is to define an envelope, or operating window, for grout and glass formulations for ORNL tank sludges. Formulations will be defined for the average composition of each of the major tank farms (BVEST/MVST, GAAT, and OHF) and for an overall average composition of all tank farms. This objective is to be accomplished using surrogates of the tank sludges with hot testing of actual tank sludges to check the efficacy of the surrogates.

  7. TankSIM: A Cryogenic Tank Performance Prediction Program

    NASA Technical Reports Server (NTRS)

    Bolshinskiy, L. G.; Hedayat, A.; Hastings, L. J.; Moder, J. P.; Schnell, A. R.; Sutherlin, S. G.

    2015-01-01

    Accurate prediction of the thermodynamic state of the cryogenic propellants in launch vehicle tanks is necessary for mission planning and successful execution. Cryogenic propellant storage and transfer in space environments requires that tank pressure be controlled. The pressure rise rate is determined by the complex interaction of external heat leak, fluid temperature stratification, and interfacial heat and mass transfer. If the required storage duration of a space mission is longer than the period in which the tank pressure reaches its allowable maximum, an appropriate pressure control method must be applied. Therefore, predictions of the pressurization rate and performance of pressure control techniques in cryogenic tanks are required for development of cryogenic fluid long-duration storage technology and planning of future space exploration missions. This paper describes an analytical tool, Tank System Integrated Model (TankSIM), which can be used for modeling pressure control and predicting the behavior of cryogenic propellant for long-term storage for future space missions. It is written in the FORTRAN 90 language and can be compiled with any Visual FORTRAN compiler. A thermodynamic vent system (TVS) is used to achieve tank pressure control. Utilizing TankSIM, the following processes can be modeled: tank self-pressurization, boiloff, ullage venting, and mixing. Details of the TankSIM program and comparisons of its predictions with test data for liquid hydrogen and liquid methane will be presented in the final paper.

  8. Tank characterization data report: Tank 241-C-112

    SciTech Connect

    Simpson, B.C.; Borsheim, G.L.; Jensen, L.

    1993-04-01

    Tank 241-C-112 is a Hanford Site Ferrocyanide Watch List tank that was most recently sampled in March 1992. Analyses of materials obtained from tank 241-C-112 were conducted to support the resolution of the Ferrocyanide Unreviewed Safety Question (USQ) and to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-10-00. Analysis of core samples obtained from tank 241-C-112 strongly indicates that the fuel concentration in the tank waste will not support a propagating exothermic reaction. It is probable that tank 241-C-112 exceeds the 1,000 g-mol inventory criteria established for the Ferrocyanide USQ; however, extensive energetic analysis of the waste has determined a maximum exothermic value of -9 cal/g dry waste. This value is substantially below any levels of concern (-75 cal/g). In addition, an investigation of potential mechanisms to generate concentration levels of radionuclides high enough to be of concern was performed. No credible mechanism was postulated that could initiate the formation of such concentration levels in the tank. Tank 241-C-112 waste is a complex material made up primarily of water and inert salts. The insoluble solids are a mixture of phosphates, sulfates, and hydroxides in combination with aluminum, calcium, iron, nickel, and uranium. Disodium nickel ferrocyanide and sodium cesium nickel ferrocyanide probably exist in the tank; however, there appears to have been significant degradation of this material since the waste was initially settled in the tank.

  9. SPHERICAL RESORCINOL-FORMALDEHYDE PERFORMANCE TESTING WITH HANFORD TANK WASTE

    SciTech Connect

    Fiskum, Sandra K.; Arm, Stuart T.; Steele, Marilyn J.; Thorson, Murray R.

    2008-07-16

    The efficacy of a new spherically engineered form of resorcinol-formaldehyde (RF) resin was tested for cesium removal on two actual Hanford tank wastes. Small-scale processing was conducted according to the River Protection Project-Waste Treatment and Immobilization Plant flowsheet in a lead-lag column format. The RF resin processed 95 bed volumes (BVs) of high potassium-bearing waste (AP-101) and >200 BVs of a high complexant-bearing waste (AN-102) before reaching 50% cesium breakthrough. Elution with 0.5 M nitric acid was effective and complete after processing 16 BVs. Cesium and other analyte fractionations to the process stream effluent and eluate were evaluated. The RF resin resulted in very little metal and radionuclide fractionation, other than cesium, to the eluate. The spent resins were measured for most analytes relevant to land-disposal requirements. The actinide concentrations on the spent resins were <3% of the transuranic waste limit; the residual cesium concentrations were <4 mCi/kg; chromium was the only metal, regulated by the Resource Conservation Recovery Act, that was measured in quantities significant to land-disposal regulations.

  10. DEVELOPMENT OF ANSYS FINITE ELEMENT MODELS FOR SINGLE SHELL TANK (SST) & DOUBLE SHELL TANK (DST) TANKS

    SciTech Connect

    JULYK, L.J.; MACKEY, T.C.

    2003-06-19

    Summary report of ANSYS finite element models developed for dome load analysis of Hanford 100-series single-shell tanks and double-shell tanks. Document provides user interface for selecting proper tank model and changing of analysis parameters for tank specific analysis. Current dome load restrictions for the Hanford Site underground waste storage tanks are based on existing analyses of record (AOR) that evaluated the tanks for a specific set of design load conditions. However, greater flexibility is required in controlling dome loadings applied to the tanks due to day-to-day operations and waste retrieval activities. This requires the development of an analytical model with sufficient detail to evaluate various dome loading conditions not specifically addressed in the AOR.

  11. CHARACTERIZATION OF TANK 16H ANNULUS SAMPLES

    SciTech Connect

    Hay, M.; Reboul, S.

    2012-04-16

    The closure of Tank 16H will require removal of material from the annulus of the tank. Samples from Tank 16H annulus were characterized and tested to provide information to evaluate various alternatives for removing the annulus waste. The analysis found all four annulus samples to be composed mainly of Si, Na, and Al and lesser amounts of other elements. The XRD data indicate quartz (SiO{sub 2}) and sodium aluminum nitrate silicate hydrate (Na{sub 8}(Al{sub 6}Si{sub 6}O{sub 24})(NO{sub 3}){sub 2}.4H{sub 2}O) as the predominant crystalline mineral phases in the samples. The XRD data also indicate the presence of crystalline sodium nitrate, sodium nitrite, gibbsite, hydrated sodium bicarbonate, and muscovite. Based on the weight of solids remaining at the end of the test, the water leaching test results indicate approximately 20-35% of the solids dissolved after three contacts with an approximately 3:1 volume of water at 45 C. The chemical analysis of the leachates and the XRD results of the remaining solids indicate sodium salts of nitrate, nitrite, sulfate, and possibly carbonate/bicarbonate make up the majority of the dissolved material. The majority of these salts were dissolved in the first water contact and simply diluted with each subsequent water contact. The water leaching removed large amounts of the uranium in two of the samples and {approx}1/3 of the {sup 99}Tc from all four samples. Most of the other radionuclides analyzed showed low solubility in the water leaching test. The preliminary data on the oxalic acid leaching test indicate the three acid contacts at 45 C dissolved from {approx}34-47% of the solids. The somewhat higher dissolution found in the oxalic acid leaching test versus the water leaching test might be offset by the tendency of the oxalic acid solutions to take on a gel-like consistency. The filtered solids left behind after three oxalic acid contacts were sticky and formed large clumps after drying. These two observations could indicate

  12. Fuel Tank Technology

    DTIC Science & Technology

    1989-11-01

    do leur mise sous prossion. on a prdvu en at? ucturc dos garnitures do produit on mousse rigide (Kidgecol) pour assurer uine assiso continue do is...number of years. In the Royal Air Force in particular, repairing and resealing integral fuel tanks has always been difficult and has frequently...surface preparation and resealing . In each area we are continually improving both equipment and procedures in order to reduce aircraft downtime and

  13. Thermal and radiolytic gas generation from Tank 241-S-102 waste

    SciTech Connect

    King, C.M.; Pederson, L.R.; Bryan, S.A.

    1997-07-01

    This report summarizes progress in evaluating thermal and radiolytic rate parameters for flammable gas generation in Hanford single-shell tank wastes based on the results of laboratory tests using actual waste from Tank 241-S-102 (S-102). Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support Fluor Daniel Hanford (FDH) and its Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT) under subcontract to PNNL, using simulated wastes, and to studies being performed at Numatec Hanford Corporation (formerly Westinghouse Hanford Company) using actual wastes. The results of gas generation from Tank S-102 waste under thermal and radiolytic conditions are described in this report. The accurate measurement of gas generation rates in actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from Tank S-102, a waste tank listed as high priority by the Flammable Gas Safety Program due to its potential for flammable gas accumulation above the flammability limit.

  14. Benzene Generation Testing for Tank 48H Waste Disposition

    SciTech Connect

    Peters, T

    2005-05-13

    In support for the Aggregation option1, researchers performed a series of tests using actual Tank 48H slurries. The tests were designed to examine potential benzene generation issues if the Tank 48H slurry is disposed to Saltstone. Personnel used the archived Tank 48H sample (HTF-E-03-127, collected September 17, 2003) for the experiments. The tests included a series of three experiments (Tests A, B, and F) performed in duplicate, giving a total of six experiments. Test A used Tank 48H slurry mixed with {approx}20:1 with Defense Waste Processing Facility (DWPF) Recycle from Tanks 21H and 22H. Test B used Tank 48H slurry mixed with {approx}2.7:1 with DWPF Recycle from Tanks 21H and 22H, while Test F used Tank 48H slurry as-is. Tests A and B occurred at 45 C, while Test F occurred at 55 C. Over a period of 8 weeks, personnel collected samples for analysis, once per week. Each sample was tested with the in-cell gamma counter. The researchers noted a decline in the cesium activity in solution which is attributed to temperature dependence of the complex slurry equilibrium. Selected samples were sent to ADS for potassium, boron, and cesium analysis. The benzene generation rate was inferred from the TPB destruction which is indirectly measured by the in-growth of cesium, potassium or boron. The results of all the analyses reveal no discernible in-growth of radiocesium, potassium or boron, indicating no significant tetraphenylborate (TPB) decomposition in any of the experiments. From boron measurements, the inferred rate of TPB destruction remained less than 0.332 mg/(L-h) implying a maximum benzene generation rate of <0.325 mg/(L-h).

  15. HYDRAULICS AND MIXING EVALUATIONS FOR NT-21/41 TANKS

    SciTech Connect

    Lee, S.; Barnes, O.

    2014-11-17

    The hydraulic results demonstrate that pump head pressure of 20 psi recirculates about 5.6 liters/min flowrate through the existing 0.131-inch orifice when a valve connected to NT-41 is closed. In case of the valve open to NT-41, the solution flowrates to HB-Line tanks, NT-21 and NT-41, are found to be about 0.5 lpm and 5.2 lpm, respectively. The modeling calculations for the mixing operations of miscible fluids contained in the HB-Line tank NT-21 were performed by taking a three-dimensional Computational Fluid Dynamics (CFD) approach. The CFD modeling results were benchmarked against the literature results and the previous SRNL test results to validate the model. Final performance calculations were performed for the nominal case by using the validated model to quantify the mixing time for the HB-Line tank. The results demonstrate that when a pump recirculates a solution volume of 5.7 liters every minute out of the 72-liter tank contents containing two acid solutions of 2.7 M and 0 M concentrations (i.e., water), a minimum mixing time of 1.5 hours is adequate for the tank contents to get the tank contents adequately mixed. In addition, the sensitivity results for the tank contents of 8 M existing solution and 1.5 M incoming species show that the mixing time takes about 2 hours to get the solutions mixed.

  16. Preliminary safety criteria for organic watch list tanks at the Hanford site

    SciTech Connect

    Webb, A.B.; Stewart, J.L.; Turner, O.A.; Plys, M.G.; Malinovic, B.; Grigsby, J.M.; Camaioni, D.M.; Heasler, P.G.; Samuels, W.O.; Toth, J.J.

    1995-11-01

    Condensed-phase, rapid reactions of organic salts with nitrates/nitrites in Hanford High Level Radioactive Waste single-shell tanks could lead to structural failure of the tanks resulting in significant releases of radionuclides and toxic materials. This report establishes appropriate preliminary safety criteria to ensure that tank wastes will be maintained safe. These criteria show that if actual dry wastes contain less than 1.2 MJ/kg of reactants reaction energy or less 4.5 wt % of total organic carbon, then the waste will be safe and will not propagate if ignited. Waste moisture helps to retard reactions; when waste moisture exceeds 20 wt %, rapid reactions are prevented, regardless of organic carbon concentrations. Aging and degradation of waste materials has been considered to predict the types and amounts to organic compounds present in the waste. Using measurements of 3 waste phases (liquid, salt cake, and sludge) obtained from tank waste samples analyzed in the laboratory, analysis of variance (ANOVA) models were used to estimate waste states for unmeasured tanks. The preliminary safety criteria are based upon calorimetry and propagation testing of likely organic compounds which represent actual tank wastes. These included sodium salts of citrate, formate, acetate and hydroxyethylethylenediaminetricetate (HEDTA). Hot cell tests of actual tank wastes are planned for the future to confirm propagation tests performed in the laboratory. The effects of draining liquids from the tanks which would remove liquids and moisture were considered because reactive waste which is too dry may propagate. Evaporation effects which could remove moisture from the tanks were also calculated. The various ways that the waste could be heated or ignited by equipment failures or tank operations activities were considered and appropriate monitoring and controls were recommended.

  17. STATUS OF MECHANICAL SLUDGE REMOVAL AND COOLING COILS CLOSURE AT THE SAVANNAH RIVER SITE - F TANK FARM CLOSURE PROJECT - 9225

    SciTech Connect

    Jolly, R

    2009-01-06

    The Savannah River Site F-Tank Farm Closure project has successfully performed Mechanical Sludge Removal using the Waste on Wheels (WOW) system within two of its storage tanks. The Waste on Wheels (WOW) system is designed to be relatively mobile with the ability for many components to be redeployed to multiple tanks. It is primarily comprised of Submersible Mixer Pumps (SMPs), Submersible Transfer Pumps (STPs), and a mobile control room with a control panel and variable speed drives. These tanks, designated as Tank 6 and Tank 5 respectively, are Type I waste tanks located in F-Tank Farm (FTF) with a capacity of 2839 cubic meters (750,000 gallons) each. In addition, Type I tanks have 34 vertically oriented cooling coils and two horizontal cooling coil circuits along the tank floor. DOE intends to remove from service and operationally close Tank 5 and Tank 6 and other HLW tanks that do not meet current containment standards. After obtaining regulatory approval, the tanks and cooling coils will be isolated and filled with grout for long term stabilization. Mechanical Sludge Removal of the remaining sludge waste within Tank 6 removed {approx} 75% of the original 25,000 gallons in August 2007. Utilizing lessons learned from Tank 6, Tank 5 Mechanical Sludge Removal completed removal of {approx} 90% of the original 125 cubic meters (33,000 gallons) of sludge material in May 2008. The successful removal of sludge material meets the requirement of approximately 19 to 28 cubic meters (5,000 to 7,500 gallons) remaining prior to the Chemical Cleaning process. The Chemical Cleaning Process will utilize 8 wt% oxalic acid to dissolve the remaining sludge heel. The flow sheet for Chemical Cleaning planned a 20:1 volume ratio of acid to sludge for the first strike with mixing provided by the submersible mixer pumps. The subsequent strikes will utilize a 13:1 volume ratio of acid to sludge with no mixing. The results of the Chemical Cleaning Process are detailed in the 'Status of

  18. Tank characterization data report: Tank 241-C-112

    SciTech Connect

    Simpson, B.C.; Borsheim, G.L.; Jensen, L.

    1993-09-01

    Tank 241-C-112 is a Hanford Site Ferrocyanide Watch List tank that was most recently sampled in March 1992. Analyses of materials obtained from tank 241-C-112 were conducted to support the resolution of the Ferrocyanide Unreviewed Safety Question (USQ) and to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-10-00. Analysis of core samples obtained from tank 241-C-112 strongly indicates that the fuel concentration in the tank waste will not support a propagating exothermic reaction. Analysis of the process history of the tank as well as studies of simulants provided valuable information about the physical and chemical condition of the waste. This information, in combination with the analysis of the tank waste, sup ports the conclusion that an exothermic reaction in tank 241-C-112 is not plausible. Therefore, the contents of tank 241-C-112 present no imminent threat to the workers at the Hanford Site, the public, or the environment from its forrocyanide inventory. Because an exothermic reaction is not credible, the consequences of this accident scenario, as promulgated by the General Accounting Office, are not applicable.

  19. Tank characterization report for Single-Shell Tank B-111

    SciTech Connect

    Remund, K.M.; Tingey, J.M.; Heasler, P.G.; Toth, J.J.; Ryan, F.M.; Hartley, S.A.; Simpson, D.B.; Simpson, B.C.

    1994-09-01

    Tank 241-B-111 (hereafter referred to as B-111) is a 2,006,300 liter (530,000 gallon) single-shell waste tank located in the 200 East B tank farm at Hanford. Two cores were taken from this tank in 1991 and analysis of the cores was conducted by Battelle`s 325-A Laboratory in 1993. Characterization of the waste in this tank is being done to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-44-05. Tank B-111 was constructed in 1943 and put into service in 1945; it is the second tank in a cascade system with Tanks B-110 and B-112. During its process history, B-111 received mostly second-decontamination-cycle waste and fission products waste via the cascade from Tank B-110. This tank was retired from service in 1976, and in 1978 the tank was assumed to have leaked 30,300 liters (8,000 gallons). The tank was interim stabilized and interim isolated in 1985. The tank presently contains approximately 893,400 liters (236,000 gallons) of sludge-like waste and approximately 3,800 liters (1,000 gallons) of supernate. Historically, there are no unreviewed safety issues associated with this tank and none were revealed after reviewing the data from the latest core sampling event in 1991. An extensive set of analytical measurements was performed on the core composites. The major constituents (> 0.5 wt%) measured in the waste are water, sodium, nitrate, phosphate, nitrite, bismuth, iron, sulfate and silicon, ordered from largest concentration to the smallest. The concentrations and inventories of these and other constituents are given. Since Tanks B-110 and B-111 have similar process histories, their sampling results were compared. The results of the chemical analyses have been compared to the dangerous waste codes in the Washington Dangerous Waste Regulations (WAC 173-303). This assessment was conducted by comparing tank analyses against dangerous waste characteristics `D` waste codes; and against state waste codes.

  20. Laboratory stabilization/solidification of surrogate and actual mixed-waste sludge in glass and grout

    SciTech Connect

    Spence, R.D.; Gilliam, T.M.; Mattus, C.H.; Mattus, A.J.

    1998-03-03

    Grouting and vitrification are currently the most likely stabilization/solidification technologies for mixed wastes. Grouting has been used to stabilize and solidify hazardous and low-level waste for decades. Vitrification has long been developed as a high-level-waste alternative and has been under development recently as an alternative treatment technology for low-level mixed waste. Laboratory testing has been performed to develop grout and vitrification formulas for mixed-waste sludges currently stored in underground tanks at Oak Ridge National Laboratory (ORNL) and to compare these waste forms. Envelopes, or operating windows, for both grout and soda-lime-silica glass formulations for a surrogate sludge were developed. One formulation within each envelope was selected for testing the sensitivity of performance to variations ({+-}10 wt%) in the waste form composition and variations in the surrogate sludge composition over the range previously characterized in the sludges. In addition, one sludge sample of an actual mixed-waste tank was obtained, a surrogate was developed for this sludge sample, and grout and glass samples were prepared and tested in the laboratory using both surrogate and the actual sludge. The sensitivity testing of a surrogate tank sludge in selected glass and grout formulations is discussed in this paper, along with the hot-cell testing of an actual tank sludge sample.

  1. Tank Characterization Report for Double Shell Tank (DST) 241-AN-107

    SciTech Connect

    ADAMS, M.R.

    2000-03-23

    This report interprets information about the tank answering a series of six questions covering areas such as information drivers, tank history, tank comparisons, disposal implications, data quality and quantity, and unique aspects of the tank.

  2. Parametric evaluation of contoured aluminum diaphragm, positive expulsion tanks

    NASA Astrophysics Data System (ADS)

    Marvin, M.; Kammerer, H.; Gidley, J. T.

    1992-07-01

    Development and application of contoured aluminum diaphragm positive expulsion tanks has progressed to the stage where parametric trade studies can be performed confidently. These allow the investigation of the effect of parameters including: size/shape/pressure/wall thickness/overwrap usage, on weight, system volume constraints and other considerations. Both mathematically derived and empirically fit equations relating these parameters have been developed. The resulting graphs show the weight efficiency for graphite wrapped vs all metal tank shells in all but the smallest sizes and low pressures. They also show the penalty for departing from simple oblate spheroid shapes, a need sometimes dictated by system constraints. A comparison between the predicted and actual data from delivered tanks is also shown.

  3. Low temperature hydrothermal destruction of organics in Hanford tank wastes

    SciTech Connect

    Orth, R.J.; Elmore, M.R.; Zacher, A.H.; Neuenschwander, G.G.; Schmidt, A.J.; Jones, E.O.; Hart, T.R.; Poshusta, J.C.

    1994-08-01

    The objective of this work is to evaluate and develop a low temperature hydrothermal process (HTP) for the destruction of organics that are present wastes temporarily stored in underground tanks at the Hanford Site. Organic compounds contribute to tank waste safety issues, such as hydrogen generation. Some organic compounds act as complexants, promoting the solubility of radioactive constituents such as {sup 90}Sr and {sup 241}Am, which is undesirable for waste pretreatment processing. HTP is thermal-chemical autogenous processing method that is typically operated between 250{degrees}C and 375{degrees}C and approximately 200 atm. Testing with simulated tank waste, containing a variety of organics has been performed. The distribution of strontium, cesium and bulk metals between the supernatant and solid phases as a function of the total organic content of the waste simulant will be presented. Test results using simulant will be compared with similar tests conducted using actual radioactive waste.

  4. How People Actually Use Thermostats

    SciTech Connect

    Meier, Alan; Aragon, Cecilia; Hurwitz, Becky; Mujumdar, Dhawal; Peffer, Therese; Perry, Daniel; Pritoni, Marco

    2010-08-15

    Residential thermostats have been a key element in controlling heating and cooling systems for over sixty years. However, today's modern programmable thermostats (PTs) are complicated and difficult for users to understand, leading to errors in operation and wasted energy. Four separate tests of usability were conducted in preparation for a larger study. These tests included personal interviews, an on-line survey, photographing actual thermostat settings, and measurements of ability to accomplish four tasks related to effective use of a PT. The interviews revealed that many occupants used the PT as an on-off switch and most demonstrated little knowledge of how to operate it. The on-line survey found that 89% of the respondents rarely or never used the PT to set a weekday or weekend program. The photographic survey (in low income homes) found that only 30% of the PTs were actually programmed. In the usability test, we found that we could quantify the difference in usability of two PTs as measured in time to accomplish tasks. Users accomplished the tasks in consistently shorter times with the touchscreen unit than with buttons. None of these studies are representative of the entire population of users but, together, they illustrate the importance of improving user interfaces in PTs.

  5. 46 CFR 154.439 - Tank design.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Tank design. 154.439 Section 154.439 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type A § 154.439 Tank design. An independent tank type A must meet the deep tank standard of the...

  6. 46 CFR 154.439 - Tank design.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Tank design. 154.439 Section 154.439 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type A § 154.439 Tank design. An independent tank type A must meet the deep tank standard of the...

  7. 46 CFR 154.439 - Tank design.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Tank design. 154.439 Section 154.439 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type A § 154.439 Tank design. An independent tank type A must meet the deep tank standard of the...

  8. 49 CFR 238.423 - Fuel tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Fuel tanks. 238.423 Section 238.423 Transportation....423 Fuel tanks. (a) External fuel tanks. Each type of external fuel tank must be approved by FRA's Associate Administrator for Safety upon a showing that the fuel tank provides a level of safety at...

  9. 49 CFR 238.423 - Fuel tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Fuel tanks. 238.423 Section 238.423 Transportation....423 Fuel tanks. (a) External fuel tanks. Each type of external fuel tank must be approved by FRA's Associate Administrator for Safety upon a showing that the fuel tank provides a level of safety at...

  10. 49 CFR 238.423 - Fuel tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 4 2013-10-01 2013-10-01 false Fuel tanks. 238.423 Section 238.423 Transportation....423 Fuel tanks. (a) External fuel tanks. Each type of external fuel tank must be approved by FRA's Associate Administrator for Safety upon a showing that the fuel tank provides a level of safety at...

  11. 49 CFR 238.423 - Fuel tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 4 2011-10-01 2011-10-01 false Fuel tanks. 238.423 Section 238.423 Transportation....423 Fuel tanks. (a) External fuel tanks. Each type of external fuel tank must be approved by FRA's Associate Administrator for Safety upon a showing that the fuel tank provides a level of safety at...

  12. 49 CFR 238.423 - Fuel tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 4 2014-10-01 2014-10-01 false Fuel tanks. 238.423 Section 238.423 Transportation....423 Fuel tanks. (a) External fuel tanks. Each type of external fuel tank must be approved by FRA's Associate Administrator for Safety upon a showing that the fuel tank provides a level of safety at...

  13. 27 CFR 19.183 - Scale tanks.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Scale tanks. 19.183... Tank Requirements § 19.183 Scale tanks. (a) Except as otherwise provided in paragraph (b) of this..., the tank must be mounted on scales and the contents of the tank must be determined by weight. The...

  14. 27 CFR 19.183 - Scale tanks.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Scale tanks. 19.183... Tank Requirements § 19.183 Scale tanks. (a) Except as otherwise provided in paragraph (b) of this..., the tank must be mounted on scales and the contents of the tank must be determined by weight. The...

  15. 27 CFR 19.183 - Scale tanks.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Scale tanks. 19.183... Tank Requirements § 19.183 Scale tanks. (a) Except as otherwise provided in paragraph (b) of this..., the tank must be mounted on scales and the contents of the tank must be determined by weight. The...

  16. 27 CFR 19.183 - Scale tanks.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Scale tanks. 19.183... Tank Requirements § 19.183 Scale tanks. (a) Except as otherwise provided in paragraph (b) of this..., the tank must be mounted on scales and the contents of the tank must be determined by weight. The...

  17. 49 CFR 174.63 - Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 2 2014-10-01 2014-10-01 false Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car tanks. 174.63 Section 174.63 Transportation Other Regulations Relating to Transportation PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS...

  18. 49 CFR 174.63 - Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 2 2011-10-01 2011-10-01 false Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car tanks. 174.63 Section 174.63 Transportation Other Regulations Relating to Transportation PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS...

  19. 49 CFR 174.63 - Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 2 2013-10-01 2013-10-01 false Portable tanks, IM portable tanks, IBCs, Large Packagings, cargo tanks, and multi-unit tank car tanks. 174.63 Section 174.63 Transportation Other Regulations Relating to Transportation PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS...

  20. 46 CFR 154.420 - Tank design.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Integral Tanks § 154.420 Tank design. (a) The structure of an integral tank must meet the deep tank scantling standards.... (b) The structure of an integral tank must be designed and shown by calculation to withstand the...

  1. 14 CFR 25.1013 - Oil tanks.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... oil tank installation must meet the requirements of § 25.967. (b) Expansion space. Oil tank expansion... expansion space of not less than the greater of 10 percent of the tank capacity or 0.5 gallon, and each oil tank used with a turbine engine must have an expansion space of not less than 10 percent of the tank...

  2. 14 CFR 25.1013 - Oil tanks.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... oil tank installation must meet the requirements of § 25.967. (b) Expansion space. Oil tank expansion... expansion space of not less than the greater of 10 percent of the tank capacity or 0.5 gallon, and each oil tank used with a turbine engine must have an expansion space of not less than 10 percent of the tank...

  3. 14 CFR 23.1013 - Oil tanks.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil tanks. 23.1013 Section 23.1013... tanks. (a) Installation. Each oil tank must be installed to— (1) Meet the requirements of § 23.967 (a...) Expansion space. Oil tank expansion space must be provided so that— (1) Each oil tank used with...

  4. 27 CFR 25.35 - Tanks.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Tanks. 25.35 Section 25.35... TREASURY LIQUORS BEER Construction and Equipment Equipment § 25.35 Tanks. Each stationary tank, vat, cask... contents of tanks or containers in lieu of providing each tank or container with a measuring device....

  5. 49 CFR 230.116 - Oil tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Oil tanks. 230.116 Section 230.116 Transportation... Locomotive Tanks § 230.116 Oil tanks. The oil tanks on oil burning steam locomotives shall be maintained free... adjacent to the fuel supply tank or in another safe location; (b) Closes automatically when tripped...

  6. 46 CFR 154.439 - Tank design.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Tank design. 154.439 Section 154.439 Shipping COAST... Tank Type A § 154.439 Tank design. An independent tank type A must meet the deep tank standard of the...: (a) Withstand the internal pressure determined under § 154.407; (b) Withstand loads from...

  7. 46 CFR 154.439 - Tank design.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Tank design. 154.439 Section 154.439 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type A § 154.439 Tank design. An independent tank type A must meet the deep tank standard of...

  8. 46 CFR 154.420 - Tank design.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Integral Tanks § 154.420 Tank design. (a) The structure of an integral tank must meet the deep tank scantling standards.... (b) The structure of an integral tank must be designed and shown by calculation to withstand...

  9. 46 CFR 154.420 - Tank design.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Integral Tanks § 154.420 Tank design. (a) The structure of an integral tank must meet the deep tank scantling standards.... (b) The structure of an integral tank must be designed and shown by calculation to withstand...

  10. 46 CFR 154.420 - Tank design.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Integral Tanks § 154.420 Tank design. (a) The structure of an integral tank must meet the deep tank scantling standards.... (b) The structure of an integral tank must be designed and shown by calculation to withstand...

  11. 46 CFR 154.420 - Tank design.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Integral Tanks § 154.420 Tank design. (a) The structure of an integral tank must meet the deep tank scantling standards.... (b) The structure of an integral tank must be designed and shown by calculation to withstand...

  12. ENHANCED CHEMICAL CLEANING: A NEW PROCESS FOR CHEMICALLY CLEANING SAVANNAH RIVER WASTE TANKS

    SciTech Connect

    Ketusky, E; Neil Davis, N; Renee Spires, R

    2008-01-17

    The Savannah River Site (SRS) has 49 high level waste (HLW) tanks that must be emptied, cleaned, and closed as required by the Federal Facilities Agreement. The current method of chemical cleaning uses several hundred thousand gallons per tank of 8 weight percent (wt%) oxalic acid to partially dissolve and suspend residual waste and corrosion products such that the waste can be pumped out of the tank. This adds a significant quantity of sodium oxalate to the tanks and, if multiple tanks are cleaned, renders the waste incompatible with the downstream processing. Tank space is also insufficient to store this stream given the large number of tanks to be cleaned. Therefore, a search for a new cleaning process was initiated utilizing the TRIZ literature search approach, and Chemical Oxidation Reduction Decontamination--Ultraviolet (CORD-UV), a mature technology currently used for decontamination and cleaning of commercial nuclear reactor primary cooling water loops, was identified. CORD-UV utilizes oxalic acid for sludge dissolution, but then decomposes the oxalic acid to carbon dioxide and water by UV treatment outside the system being treated. This allows reprecipitation and subsequent deposition of the sludge into a selected container without adding significant volume to that container, and without adding any new chemicals that would impact downstream treatment processes. Bench top and demonstration loop measurements on SRS tank sludge stimulant demonstrated the feasibility of applying CORD-UV for enhanced chemical cleaning of SRS HLW tanks.

  13. Tank closure reducing grout

    SciTech Connect

    Caldwell, T.B.

    1997-04-18

    A reducing grout has been developed for closing high level waste tanks at the Savannah River Site in Aiken, South Carolina. The grout has a low redox potential, which minimizes the mobility of Sr{sup 90}, the radionuclide with the highest dose potential after closure. The grout also has a high pH which reduces the solubility of the plutonium isotopes. The grout has a high compressive strength and low permeability, which enhances its ability to limit the migration of contaminants after closure. The grout was designed and tested by Construction Technology Laboratories, Inc. Placement methods were developed by the Savannah River Site personnel.

  14. Improved Tank Testing Methods

    DTIC Science & Technology

    1980-01-01

    slowly. During the final tests, the tank is inspected for leaks and also signs of “distress” in the shell. All detected leaks are repaired. Manufacturers...capillary action. Penetrant inspection is widely used in the fabrication industries for the detection of There are two basic types of penetrants, one is a...4 in. of the leak to be detected . If the weld being inspected is wider than 1/4 in. two parallel passes must be made to ensure that all leaks are

  15. [High Pressure Gas Tanks

    NASA Technical Reports Server (NTRS)

    Quintana, Rolando

    2002-01-01

    Four high-pressure gas tanks, the basis of this study, were especially made by a private contractor and tested before being delivered to NASA Kennedy Space Center. In order to insure 100% reliability of each individual tank the staff at KSC decided to again submit the four tanks under more rigorous tests. These tests were conducted during a period from April 10 through May 8 at KSC. This application further validates the predictive safety model for accident prevention and system failure in the testing of four high-pressure gas tanks at Kennedy Space Center, called Continuous Hazard Tracking and Failure Prediction Methodology (CHTFPM). It is apparent from the variety of barriers available for a hazard control that some barriers will be more successful than others in providing protection. In order to complete the Barrier Analysis of the system, a Task Analysis and a Biomechanical Study were performed to establish the relationship between the degree of biomechanical non-conformities and the anomalies found within the system on particular joints of the body. This relationship was possible to obtain by conducting a Regression Analysis to the previously generated data. From the information derived the body segment with the lowest percentage of non-conformities was the neck flexion with 46.7%. Intense analysis of the system was conducted including Preliminary Hazard Analysis (PHA), Failure Mode and Effect Analysis (FMEA), and Barrier Analysis. These analyses resulted in the identification of occurrences of conditions, which may be becoming hazardous in the given system. These conditions, known as dendritics, may become hazards and could result in an accident, system malfunction, or unacceptable risk conditions. A total of 56 possible dendritics were identified. Work sampling was performed to observe the occurrence each dendritic. The out of control points generated from a Weighted c control chart along with a Pareto analysis indicate that the dendritics "Personnel not

  16. 33 CFR 157.208 - Dedicated Clean Ballast Tanks Operations Manual for foreign tank vessels: Submission.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 33 Navigation and Navigable Waters 2 2012-07-01 2012-07-01 false Dedicated Clean Ballast Tanks... MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels General § 157.208 Dedicated Clean Ballast Tanks Operations Manual for foreign tank...

  17. 33 CFR 157.208 - Dedicated Clean Ballast Tanks Operations Manual for foreign tank vessels: Submission.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 33 Navigation and Navigable Waters 2 2014-07-01 2014-07-01 false Dedicated Clean Ballast Tanks... MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels General § 157.208 Dedicated Clean Ballast Tanks Operations Manual for foreign tank...

  18. 33 CFR 157.208 - Dedicated Clean Ballast Tanks Operations Manual for foreign tank vessels: Submission.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 33 Navigation and Navigable Waters 2 2011-07-01 2011-07-01 false Dedicated Clean Ballast Tanks... MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels General § 157.208 Dedicated Clean Ballast Tanks Operations Manual for foreign tank...

  19. 33 CFR 157.208 - Dedicated Clean Ballast Tanks Operations Manual for foreign tank vessels: Submission.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 33 Navigation and Navigable Waters 2 2013-07-01 2013-07-01 false Dedicated Clean Ballast Tanks... MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels General § 157.208 Dedicated Clean Ballast Tanks Operations Manual for foreign tank...

  20. 33 CFR 157.208 - Dedicated Clean Ballast Tanks Operations Manual for foreign tank vessels: Submission.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Dedicated Clean Ballast Tanks... MARINE ENVIRONMENT RELATING TO TANK VESSELS CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels General § 157.208 Dedicated Clean Ballast Tanks Operations Manual for foreign tank...

  1. 46 CFR 153.250 - Double-bottom and deep tanks as cargo tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Double-bottom and deep tanks as cargo tanks. 153.250... Equipment Cargo Tanks § 153.250 Double-bottom and deep tanks as cargo tanks. Except in those cases in which Commandant (CG-522) specifically approves another arrangement, such as a double-bottom or deep tank as...

  2. 46 CFR 153.250 - Double-bottom and deep tanks as cargo tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Double-bottom and deep tanks as cargo tanks. 153.250... Equipment Cargo Tanks § 153.250 Double-bottom and deep tanks as cargo tanks. Except in those cases in which Commandant (CG-ENG) specifically approves another arrangement, such as a double-bottom or deep tank as...

  3. 46 CFR 153.250 - Double-bottom and deep tanks as cargo tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Double-bottom and deep tanks as cargo tanks. 153.250... Equipment Cargo Tanks § 153.250 Double-bottom and deep tanks as cargo tanks. Except in those cases in which Commandant (CG-ENG) specifically approves another arrangement, such as a double-bottom or deep tank as...

  4. 46 CFR 153.250 - Double-bottom and deep tanks as cargo tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Double-bottom and deep tanks as cargo tanks. 153.250... Equipment Cargo Tanks § 153.250 Double-bottom and deep tanks as cargo tanks. Except in those cases in which Commandant (CG-ENG) specifically approves another arrangement, such as a double-bottom or deep tank as...

  5. 49 CFR 179.102 - Special commodity requirements for pressure tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... car tanks. 179.102 Section 179.102 Transportation Other Regulations Relating to Transportation... REGULATIONS SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.102 Special commodity requirements for pressure tank car tanks. (a) In addition...

  6. 49 CFR 179.103 - Special requirements for class 114A * * * tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Special requirements for class 114A * * * tank car... SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.103 Special requirements for class 114A * * * tank car tanks. (a) In addition to the...

  7. 49 CFR 179.103 - Special requirements for class 114A * * * tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Special requirements for class 114A * * * tank car...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.103 Special requirements for class 114A * * * tank car tanks. (a) In addition to the...

  8. 27 CFR 24.229 - Tank car and tank truck requirements.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Tank car and tank truck... BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL WINE Spirits § 24.229 Tank car and tank truck requirements. Railroad tank cars and tank trucks used to transport spirits for use in wine production will be...

  9. 49 CFR 179.102 - Special commodity requirements for pressure tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... car tanks. 179.102 Section 179.102 Transportation Other Regulations Relating to Transportation...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.102 Special commodity requirements for pressure tank car tanks. (a) In addition to §§ 179.100...

  10. 49 CFR 179.100 - General specifications applicable to pressure tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... car tanks. 179.100 Section 179.100 Transportation Other Regulations Relating to Transportation...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.100 General specifications applicable to pressure tank car tanks....

  11. 49 CFR 179.103 - Special requirements for class 114A * * * tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Special requirements for class 114A * * * tank car...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.103 Special requirements for class 114A * * * tank car tanks. (a) In addition to the...

  12. 49 CFR 179.100 - General specifications applicable to pressure tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... car tanks. 179.100 Section 179.100 Transportation Other Regulations Relating to Transportation... REGULATIONS SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.100 General specifications applicable to pressure tank car tanks....

  13. 49 CFR 179.102 - Special commodity requirements for pressure tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... car tanks. 179.102 Section 179.102 Transportation Other Regulations Relating to Transportation...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.102 Special commodity requirements for pressure tank car tanks. (a) In addition to §§ 179.100...

  14. 49 CFR 179.101 - Individual specification requirements applicable to pressure tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... to pressure tank car tanks. 179.101 Section 179.101 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.101 Individual specification requirements applicable to pressure tank...

  15. 27 CFR 24.229 - Tank car and tank truck requirements.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Tank car and tank truck... BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Spirits § 24.229 Tank car and tank truck requirements. Railroad tank cars and tank trucks used to transport spirits for use in wine production will be...

  16. 27 CFR 24.229 - Tank car and tank truck requirements.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Tank car and tank truck... BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL WINE Spirits § 24.229 Tank car and tank truck requirements. Railroad tank cars and tank trucks used to transport spirits for use in wine production will be...

  17. 49 CFR 179.100 - General specifications applicable to pressure tank car tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... car tanks. 179.100 Section 179.100 Transportation Other Regulations Relating to Transportation...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.100 General specifications applicable to pressure tank car tanks....

  18. 49 CFR 179.101 - Individual specification requirements applicable to pressure tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... to pressure tank car tanks. 179.101 Section 179.101 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.101 Individual specification requirements applicable to pressure tank...

  19. 49 CFR 179.100 - General specifications applicable to pressure tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... car tanks. 179.100 Section 179.100 Transportation Other Regulations Relating to Transportation...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.100 General specifications applicable to pressure tank car tanks....

  20. 49 CFR 179.101 - Individual specification requirements applicable to pressure tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... to pressure tank car tanks. 179.101 Section 179.101 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.101 Individual specification requirements applicable to pressure tank...

  1. 27 CFR 27.174 - Tank cars and tank trucks to be sealed.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Tank cars and tank trucks... Tank cars and tank trucks to be sealed. Where a shipment of distilled spirits from customs custody to the distilled spirits plant is made in a tank car or tank truck, all openings affording access to...

  2. 27 CFR 27.174 - Tank cars and tank trucks to be sealed.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Tank cars and tank trucks... Tank cars and tank trucks to be sealed. Where a shipment of distilled spirits from customs custody to the distilled spirits plant is made in a tank car or tank truck, all openings affording access to...

  3. 49 CFR 179.101 - Individual specification requirements applicable to pressure tank car tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... to pressure tank car tanks. 179.101 Section 179.101 Transportation Other Regulations Relating to... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.101 Individual specification requirements applicable to pressure tank...

  4. 27 CFR 24.229 - Tank car and tank truck requirements.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Tank car and tank truck... BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Spirits § 24.229 Tank car and tank truck requirements. Railroad tank cars and tank trucks used to transport spirits for use in wine production will be...

  5. 49 CFR 179.100 - General specifications applicable to pressure tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... car tanks. 179.100 Section 179.100 Transportation Other Regulations Relating to Transportation...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.100 General specifications applicable to pressure tank car tanks....

  6. 49 CFR 179.102 - Special commodity requirements for pressure tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... car tanks. 179.102 Section 179.102 Transportation Other Regulations Relating to Transportation...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.102 Special commodity requirements for pressure tank car tanks. (a) In addition to §§ 179.100...

  7. 27 CFR 27.174 - Tank cars and tank trucks to be sealed.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Tank cars and tank trucks... Tank cars and tank trucks to be sealed. Where a shipment of distilled spirits from customs custody to the distilled spirits plant is made in a tank car or tank truck, all openings affording access to...

  8. 27 CFR 24.229 - Tank car and tank truck requirements.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Tank car and tank truck... BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Spirits § 24.229 Tank car and tank truck requirements. Railroad tank cars and tank trucks used to transport spirits for use in wine production will be...

  9. 49 CFR 179.103 - Special requirements for class 114A * * * tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Special requirements for class 114A * * * tank car...) SPECIFICATIONS FOR TANK CARS Specifications for Pressure Tank Car Tanks (Classes DOT-105, 109, 112, 114 and 120) § 179.103 Special requirements for class 114A * * * tank car tanks. (a) In addition to the...

  10. FRACTIONAL CRYSTALLIZATION OF HANFORD SINGLE SHELL TANK (SST) WASTES LABORATORY DEVELOPMENT

    SciTech Connect

    HERTING, D.L.

    2006-12-05

    Laboratory studies demonstrate that fractional crystallization is a viable process for separating Hanford medium-curie waste into high-curie and low-curie fractions. The product salt from the crystallization process qualifies as low-curie feed to a supplemental treatment system (e.g., bulk vitrification). The high-curie raffinate is returned to the double-shell tank system, eventually to be sent as feed to the Waste Treatment and Immobilization Plant. Process flowsheet tests were designed with the aid of thermodynamic chemical modeling. Laboratory equipment design and test procedures were developed using simulated tank waste samples. Proof-of-concept flowsheet tests were carried out in a shielded hot cell using actual tank waste samples. Data from both simulated waste tests and actual tank waste tests demonstrate that the process exceeded all of the separation criteria established for the program.

  11. Sludge batch 9 simulant runs using the nitric-glycolic acid flowsheet

    SciTech Connect

    Lambert, D. P.; Williams, M. S.; Brandenburg, C. H.; Luther, M. C.; Newell, J. D.; Woodham, W. H.

    2016-11-01

    Testing was completed to develop a Sludge Batch 9 (SB9) nitric-glycolic acid chemical process flowsheet for the Defense Waste Processing Facility’s (DWPF) Chemical Process Cell (CPC). CPC simulations were completed using SB9 sludge simulant, Strip Effluent Feed Tank (SEFT) simulant and Precipitate Reactor Feed Tank (PRFT) simulant. Ten sludge-only Sludge Receipt and Adjustment Tank (SRAT) cycles and four SRAT/Slurry Mix Evaporator (SME) cycles, and one actual SB9 sludge (SRAT/SME cycle) were completed. As has been demonstrated in over 100 simulations, the replacement of formic acid with glycolic acid virtually eliminates the CPC’s largest flammability hazards, hydrogen and ammonia. Recommended processing conditions are summarized in section 3.5.1. Testing demonstrated that the interim chemistry and Reduction/Oxidation (REDOX) equations are sufficient to predict the composition of DWPF SRAT product and SME product. Additional reports will finalize the chemistry and REDOX equations. Additional testing developed an antifoam strategy to minimize the hexamethyldisiloxane (HMDSO) peak at boiling, while controlling foam based on testing with simulant and actual waste. Implementation of the nitric-glycolic acid flowsheet in DWPF is recommended. This flowsheet not only eliminates the hydrogen and ammonia hazards but will lead to shorter processing times, higher elemental mercury recovery, and more concentrated SRAT and SME products. The steady pH profile is expected to provide flexibility in processing the high volume of strip effluent expected once the Salt Waste Processing Facility starts up.

  12. 39. DIABLO POWERHOUSE: GRAVITY LUBRICATING OIL TANKS. THESE TANKS ARE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    39. DIABLO POWERHOUSE: GRAVITY LUBRICATING OIL TANKS. THESE TANKS ARE LOCATED AT ROOF LEVEL AT THE NORTHEAST REAR CORNER OF DIABLO POWERHOUSE, 1989. - Skagit Power Development, Diablo Powerhouse, On Skagit River, 6.1 miles upstream from Newhalem, Newhalem, Whatcom County, WA

  13. Tank Waste Remediation System Tank Waste Analysis Plan. FY 1995

    SciTech Connect

    Haller, C.S.; Dove, T.H.

    1994-11-01

    This documents lays the groundwork for preparing the implementing the TWRS tank waste analysis planning and reporting for Fiscal Year 1995. This Tank Waste Characterization Plan meets the requirements specified in the Hanford Federal Facility Agreement and Consent Order, better known as the Tri-Party Agreement.

  14. 33 CFR 157.15 - Slop tanks in tank vessels.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... ballast water containing an oily mixture of 3 percent or more of the oil carrying capacity. Two percent... of oil, and the creation of an emulsion by the use of separate inlet and outlet connections; and (2... OIL IN BULK Design, Equipment, and Installation § 157.15 Slop tanks in tank vessels. (a) Number. A...

  15. 33 CFR 157.15 - Slop tanks in tank vessels.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... ballast water containing an oily mixture of 3 percent or more of the oil carrying capacity. Two percent... of oil, and the creation of an emulsion by the use of separate inlet and outlet connections; and (2... OIL IN BULK Design, Equipment, and Installation § 157.15 Slop tanks in tank vessels. (a) Number. A...

  16. Object choice and actual bisexuality.

    PubMed

    Limentani, A

    1976-01-01

    Actual bisexuality is to be distinguished from homosexuality in a latent state and from conscious bisexual fantasies. Contemporary social changes have caused an increased demand for help for those men and women capable of engaging in protracted heterosexual and homosexual relations. Among such people narcissistic and borderline states are common. Clinical material is presented in some detail. The author suggests that the condition is associated with a tendency to be caught up between the anaclitic and narcissistic types of object choice. The concurrent involvement with a male and female love object against a background of pseudogenitality creates the illusory appearance of two objects being involved, covering up the fact that there is splitting of the original love object together with severe preoedipal disturbance.

  17. Health effects of tank cleaners.

    PubMed

    Lillienberg, L; Högstedt, B; Järvholm, B; Nilson, L

    1992-06-01

    A total of 29 tank cleaners and 31 referent controls participated in the study. In most cases, the tank cleaners were employed in small companies, usually specialized subcontractors such as firms only working in refineries cleaning oil tanks and handling oil spills. The air concentrations of hydrocarbons (HCs) in tanks containing residuals from heavy fuel oil were generally low, unless the oil was still warm. Addition of light fuel oil to facilitate the cleaning of tanks containing viscous, heavy fuel oils resulted in total airborne HC levels of 1000-1500 mg/m3. High levels of HC were measured in tanks with low-boiling petroleum fractions (naphtha and light fuel oils) of 1000-2600 mg/m3 (maximum). Today, most cleaners use air-supplied respirators or air-purifying respirator cartridges inside tanks with petroleum products or other chemicals. The exception is small firms handling fuel oils for heating purposes where only 50% of the workers use protective equipment regularly; the other workers only occasionally use protective equipment even if the air concentrations of HC are high. Protective equipment is rarely used in small, domestic tanks. Measurements of heart rate showed that tank cleaning is, at times, a highly strenuous job. No differences between tank cleaners and controls were found with respect to spirometry, liver enzymes, or frequency of micronuclei. Acute intoxications were not frequently reported in this group. However, this investigation may underestimate the true risk, as it is a cross-sectional study that found that exposures were highly variable, both quantitatively and qualitatively. In many cases, the tank cleaners knew very little about the potential hazards or the proper use of protective equipment.(ABSTRACT TRUNCATED AT 250 WORDS)

  18. Progress in High-Level Waste Tank Cleaning at the Idaho National Environmental and Engineering Laboratory

    SciTech Connect

    Lockie, K. A.; McNaught, W. B.

    2002-02-26

    The Department of Energy Idaho Operations Office (DOE-ID) is making preparations to close two underground high-level waste (HLW) storage tanks at the Idaho National Engineering and Environmental Laboratory (INEEL) to meet Resource Conservation and Recovery Act (RCRA) regulations and Department of Energy (DOE) orders. Closure of these two tanks is scheduled for 2004 as the first phase in closure of the eleven 300,000 gallon tanks currently in service at the Idaho Nuclear Technology and Engineering Center (INTEC). Design, development, and deployment of a remotely operated tank cleaning system were completed in August 2001. The system incorporates many commercially available components, which have been adapted for application in cleaning high-level waste tanks. The system also uses existing waste transfer technology (steam-jets) to remove tank heel solids from the tank bottoms during the cleaning operations. By using this existing transfer system and commercially available equipment, the cost of developing custom designed cleaning equipment can be avoided. Remotely operated directional spray nozzles, automatic rotating wash balls, video monitoring equipment, decontamination spray-rings, and tank specific access interface devices have been integrated to provide a system that efficiently cleans tank walls and heel solids in an acidic, radioactive environment. This system is also compliant with operational and safety performance requirements at INTEC. Through the deployment of the tank cleaning system, the INEEL High Level Waste Program has demonstrated the capability to clean tanks to meet RCRA clean closure standards and DOE closure performance measures. The tank cleaning system deployed at the INTEC offers unique advantages over other approaches evaluated at the INEEL and throughout the DOE Complex. The system's ability to agitate and homogenize the tank heel sludge will simplify verification-sampling techniques and reduce the total quantity of samples required to

  19. C-106 tank process ventilation test

    SciTech Connect

    Bailey, J.W.

    1998-07-20

    Project W-320 Acceptance Test Report for tank 241-C-106, 296-C-006 Ventilation System Acceptance Test Procedure (ATP) HNF-SD-W320-012, C-106 Tank Process Ventilation Test, was an in depth test of the 296-C-006 ventilation system and ventilation support systems required to perform the sluicing of tank C-106. Systems involved included electrical, instrumentation, chiller and HVAC. Tests began at component level, moved to loop level, up to system level and finally to an integrated systems level test. One criteria was to perform the test with the least amount of risk from a radioactive contamination potential stand point. To accomplish this a temporary configuration was designed that would simulate operation of the systems, without being connected directly to the waste tank air space. This was done by blanking off ducting to the tank and connecting temporary ducting and an inlet air filter and housing to the recirculation system. This configuration would eventually become the possible cause of exceptions. During the performance of the test, there were points where the equipment did not function per the directions listed in the ATP. These events fell into several different categories. The first and easiest problems were field configurations that did not match the design documentation. This was corrected by modifying the field configuration to meet design documentation and reperforming the applicable sections of the ATP. A second type of problem encountered was associated with equipment which did not operate correctly, at which point an exception was written against the ATP, to be resolved later. A third type of problem was with equipment that actually operated correctly but the directions in the ATP were in error. These were corrected by generating an Engineering Change Notice (ECN) against the ATP. The ATP with corrected directions was then re-performed. A fourth type of problem was where the directions in the ATP were as the equipment should operate, but the design of

  20. Fluid manifold design for a solar energy storage tank

    NASA Technical Reports Server (NTRS)

    Humphries, W. R.; Hewitt, H. C.; Griggs, E. I.

    1975-01-01

    A design technique for a fluid manifold for use in a solar energy storage tank is given. This analytical treatment generalizes the fluid equations pertinent to manifold design, giving manifold pressures, velocities, and orifice pressure differentials in terms of appropriate fluid and manifold geometry parameters. Experimental results used to corroborate analytical predictions are presented. These data indicate that variations in discharge coefficients due to variations in orifices can cause deviations between analytical predictions and actual performance values.

  1. A Study of Elastomeric Materials for Tank Track Pads

    DTIC Science & Technology

    1978-06-01

    above equation into the form: a C TC1 + This is known as the Mooney - Rivlin Equation. However this still repre- sents only the first curvature of the...of the actual problem When a tank is in motion, the rubber track pads undergo shear and com- pressive deformations as they contact the ground surface...mechanical work is dissipated into heat resulting in the heat of the rubber pads. This is because the rubber pads are viscoelastic substances which during a

  2. Caustic Leaching of Sludges from Selected Hanford Tanks

    SciTech Connect

    Chase, C.W.; Egan, B.Z.; Spencer, B.B.

    1998-08-01

    The objective of this project was to measure the caustic dissolution behavior of sludge components from selected Hanford waste tank sludge samples under different conditions. The dissolution of aluminum, chromium, and other constituents of actual sludge samples in aqueous sodium hydroxide solution was evaluated using various values of temperature, sodium hydroxide concentration, volume of caustic solution per unit mass of sludge (liquid:solids ratio), and leaching time.

  3. Calcination/dissolution testing for Hanford Site tank wastes

    SciTech Connect

    Colby, S.A.; Delegard, C.H.; McLaughlin, D.F.; Danielson, M.J.

    1994-07-01

    Thermal treatment by calcination offers several benefits for the treatment of Hanford Site tank wastes, including the destruction of organics and ferrocyanides and an hydroxide fusion that permits the bulk of the mostly soluble nonradioactive constituents to be easily separated from the insoluble transuranic residue. Critical design parameters were tested, including: (1) calciner equipment design, (2) hydroxide fusion chemistry, and (3) equipment corrosion. A 2 gal/minute pilot plant processed a simulated Tank 101-SY waste and produced a free flowing 700 C molten calcine with an average calciner retention time of 20 minutes and >95% organic, nitrate, and nitrite destruction. Laboratory experiments using actual radioactive tank waste and the simulated waste pilot experiments indicate that 98 wt% of the calcine produced is soluble in water, leaving an insoluble transuranic fraction. All of the Hanford Site tank wastes can benefit from calcination/dissolution processing, contingent upon blending various tank waste types to ensure a target of 70 wt% sodium hydroxide/nitrate/nitrite fluxing agent. Finally, corrosion testing indicates that a jacketed nickel liner cooled to below 400 C would corrode <2 mil/year (0.05 mm/year) from molten calcine attack.

  4. Space shuttle external tank performance improvements: The challenge

    NASA Technical Reports Server (NTRS)

    Coldwater, H. R.; Foll, R. R.; Howell, G. J.; Dutton, J. A.

    1985-01-01

    The external tank (ET) has been actively involved in performance improvements since the inception of the space shuttle program, primarily by weight savings. Weight savings were realized on the first block of flight articles (standard weight tank). With a need for further performance improvements, the ET Program Office was requested to develop a program to reduce tank weight an additional 6000 lb and schedule delivery of the first lightweight ET (LWT) for June 1982. The weight savings program was accomplished by: (1) a unique approach to use of factors of safety; (2) design optimization; and (3) redesign of structures with large margins of safety which resulted in an actual weight savings of 7294 lb. Additional studies have identified further weight savings which are to be implemented at appropriate times in production flow. Examples are an improved thermal protection system for the LH2 tank aft dome and reduction of slosh baffles in the LO2 tank based on flight data. All performance improvements were compared and selected based on non-recurring and recurring cost and technical risk.

  5. Solitons in a wave tank

    NASA Astrophysics Data System (ADS)

    Olsen, M.; Smith, H.; Scott, A. C.

    1984-09-01

    A wave tank experiment (first described by the nineteenth-century engineer and naval architect John Scott Russell) relates a linear eigenvalue problem from elementary quantum mechanics to a striking feature of modern nonlinear wave theory: multiple generation of solitons. The tank experiment is intended for lecture demonstrations.

  6. 1990 waste tank inspection program

    SciTech Connect

    McNatt, F.G.

    1990-01-01

    Aqueous radioactive wastes from Savannah River Site separations processes are contained in large underground carbon steel tanks. Tank conditions are evaluated by inspection using periscopes, still photography, and video systems for visual imagery. Inspections made in 1990 are the subject of this report.

  7. 1990 waste tank inspection program

    SciTech Connect

    McNatt, F.G.

    1990-12-31

    Aqueous radioactive wastes from Savannah River Site separations processes are contained in large underground carbon steel tanks. Tank conditions are evaluated by inspection using periscopes, still photography, and video systems for visual imagery. Inspections made in 1990 are the subject of this report.

  8. Cesium Ion Exchange Using Tank 241-AN-104 Supernate

    SciTech Connect

    Adu-Wusu, K.

    2003-12-22

    The River Protection Project is to design and build a high level nuclear waste treatment facility. The waste treatment plant is to process millions of gallons of radioactive waste stored in tanks at the Hanford Site. The high level nuclear waste treatment process includes various unit operations, such as ultrafiltration, precipitation, evaporation, ion exchange, and vitrification. Ion exchange is identified as the optimal treatment method for removal of cesium-137 and Tc-99 from the waste. Extensive ion exchange testing was performed using small-scale columns with actual waste samples. The objectives of this study were to: demonstrate SuperLig 644 ion exchange performance and process steps for the removal of cesium from actual AN-104 tank waste; pretreat actual AN-104 tank waste to reduce the concentration of cesium-137 in the waste below LAW vitrification limit; produce and characterize cesium eluate solutions for use in eluate evaporation tests. The experiments consisted of batch contact and small-scale column tests. The batch contact tests measured sorption partition coefficients Kds. The Kds were used to predict the effective resin capacity. The small-scale column tests, which closely mimic plant conditions, generated loading and elution profile data used to determine whether removal targets and design requirements were met.

  9. Development of simulated tank wastes for the US Department of Energy`s Underground Storage Tank Integrated Demonstration

    SciTech Connect

    Elmore, M.R.; Colton, N.G.; Jones, E.O.

    1992-08-01

    The purpose of the Underground Storage Tank Integrated Demonstration (USTID) is to identify and evaluate technologies that may be used to characterize, retrieve, treat, and dispose of hazardous and radioactive wastes contained in tanks on US Department of Energy sites. Simulated wastes are an essential component of the evaluation process because they provide controlled samples for technology assessment, and minimize costs and risks involved when working with radioactive wastes. Pacific Northwest Laboratory has developed a recipe to simulate Hanford single-shell tank, (SST) waste. The recipe is derived from existing process recipes, and elemental concentrations are based on characterization data from 18 SSTs. In this procedure, salt cake and metal oxide/hydroxide sludge are prepared individually, and mixed together at varying ratios depending on the specific tank, waste to be simulated or the test being conducted. Elemental and physical properties of the stimulant are comparable with analyzed tank samples, and chemical speciation in the simulant is being improved as speciation data for actual wastes become available. The nonradioactive chemical waste simulant described here is useful for testing technologies on a small scale.

  10. Progress report on tube propagation testing of tank waste using the PRSST

    SciTech Connect

    Bechtold, D.B.

    1997-09-17

    The subject of this FY 1997 progress report is tube propagation tests of actual, dried tank waste to verify the contact temperature ignition (CTI) criterion for point-source ignition in the Hanford Site waste tanks. Testing is in support of the Organic Tanks Safety Project and will help resolve safety issues with waste containing organic constitutents. In FY 1997, improvements were made to the laboratory apparatus and procedures for conducting the testing, and the final testing strategy was formulated. The strategy lays out details of the tests to be performed, samples to be tested, and modes of reporting results.

  11. Evaluation of tank thermal expansion data in CALDEX

    SciTech Connect

    Suda, S. ); Weh, R. )

    1991-01-01

    A thermal expansion test involving a large annular input reprocessing tank was carried out as a part of the CALDEX Project at the TEKO test facility in Karlsruhe, FRG. The objective of this test was to investigate thermal expansion properties of the tank and effects on various pressure and level measurement instruments used in the determination of liquid volume. In the thermal expansion test, a weak nitric acid solution was heated internally to a temperature of 60{degrees}C by means of steam injection through the sparge ring. After heating, the annular tank took about one hour to thermally equilibrate, and it took another hour for the sparge ring and pulsator pipes to fill before thermal effects could be followed. The temperature at the end of the test, after tank and its contents had cooled undisturbed for fifty hours, was 29.9{degrees}C. Thirteen instrument readings were obtained during each measurement cycle of roughly 70 seconds for a total of over 2800 readings per instrument. Thermal expansion effects for the CALDEX annular tank were consistent with that reported for cylindrical tanks. Temperature variations effect each type of probe in a way that depends on the properties of the probe and the characteristics of the measurement system. 3 refs., 4 figs., 3 tabs.

  12. Actual ratio of triacylglycerol positional isomers in milk and cheese.

    PubMed

    Gotoh, Naohiro; Matsumoto, Yumiko; Nagai, Toshiharu; Mizobe, Hoyo; Yoshinaga, Kazuaki; Kojima, Koichi; Kuroda, Ikuma; Kitamura, Yohei; Shimizu, Takashi; Ishida, Hiroki; Wada, Shun

    2012-01-01

    Actual ratios of triacylglycerol (TAG) positional isomers in human, rat, and cow milk fat and cow, buffalo, goat, and sheep cheese fat were analyzed using HPLC-UV-atmospheric pressure chemical ionization-MS/MS system equipped with an octacosyl silylation column or polymeric ODS column. We substituted cheese fats for milk fats in parts of our study because milks from ruminants, with the exception of cows, are difficult to get in Japan. The actual ratio of β-PPC (the TAG consisting of two palmitic acids (P) and one capric acid (C), with the palmitic acid located at the β position) and β-PCP in human milk was different from those in ruminants, with more than half of the medium-chain fatty acids located at the β position even though other fats possessed it mainly at the α position. Palmitic acid was mainly located at the β position for human milk and rat milk; however, the location in ruminant cheese fat was mainly at the α position. The location of fatty acids is thought to be very important for infant nutrition. Particularly, the location of palmitic acid in case of human milk and of medium-chain fatty acids in case of ruminant milk was very characteristic and is considered to be very important to the fatty acids in milk fat.

  13. [Actual status of laparoscopic cholecystectomy].

    PubMed

    Chousleb Mizrahi, Elias; Chousleb Kalach, Alberto; Shuchleib Chaba, Samuel

    2004-08-01

    Since the first laparoscopic cholecystectomy in 1988, the management of gall-bladder disease has changed importantly. This technique was rapidly popularized in the U.S. as well as in Europe. Multiple studies have proved its feasibility, safeness and great advantages. Analyze usefulness and recent advances of endoscopic surgery in the management of gallbladder disease. We did a review of the recent medical literature to determine the actual status of laparoscopic cholecystectomy. Laparoscopic cholecystectomy is the most common surgical procedure performed in the digestive tract. During the year 2001, 1,100,000 cholecystectomies were done in the U.S., 85% were done laparoscopically. In Mexico cholecystectomy in government hospitals is done laparoscopically in 50% of the cases, while in private hospitals it reaches 90%. There are multiple prospective controlled studies showing superiority of laparoscopic cholecystectomy in times of recovery, costs, return to normal activity, pain, morbidity, esthetics among other advantages. Laparoscopic cholecystectomy is the gold standard for the treatment of the great majority of cases of gallbladder disease, nevertheless in developing countries open cholecystectomy is still done frequently.

  14. Engineering study of 50 miscellaneous inactive underground radioactive waste tanks located at the Hanford Site, Washington

    SciTech Connect

    Freeman-Pollard, J.R.

    1994-03-02

    This engineering study addresses 50 inactive underground radioactive waste tanks. The tanks were formerly used for the following functions associated with plutonium and uranium separations and waste management activities in the 200 East and 200 West Areas of the Hanford Site: settling solids prior to disposal of supernatant in cribs and a reverse well; neutralizing acidic process wastes prior to crib disposal; receipt and processing of single-shell tank (SST) waste for uranium recovery operations; catch tanks to collect water that intruded into diversion boxes and transfer pipeline encasements and any leakage that occurred during waste transfer operations; and waste handling and process experimentation. Most of these tanks have not been in use for many years. Several projects have, been planned and implemented since the 1970`s and through 1985 to remove waste and interim isolate or interim stabilize many of the tanks. Some tanks have been filled with grout within the past several years. Responsibility for final closure and/or remediation of these tanks is currently assigned to several programs including Tank Waste Remediation Systems (TWRS), Environmental Restoration and Remedial Action (ERRA), and Decommissioning and Resource Conservation and Recovery Act (RCRA) Closure (D&RCP). Some are under facility landlord responsibility for maintenance and surveillance (i.e. Plutonium Uranium Extraction [PUREX]). However, most of the tanks are not currently included in any active monitoring or surveillance program.

  15. Organic Tanks Safety Program: Waste aging studies

    SciTech Connect

    Camaioni, D.M.; Samuels, W.D.; Lenihan, B.D.; Clauss, S.A.; Wahl, K.L.; Campbell, J.A.

    1994-11-01

    The underground storage tanks at the Hanford Complex contain wastes generated from many years of plutonium production and recovery processes, and mixed wastes from radiological degradation processes. The chemical changes of the organic materials used in the extraction processes have a direct on several specific safety issues, including potential energy releases from these tanks. This report details the first year`s findings of a study charged with determining how thermal and radiological processes may change the composition of organic compounds disposed to the tank. Their approach relies on literature precedent, experiments with simulated waste, and studies of model reactions. During the past year, efforts have focused on the global reaction kinetics of a simulated waste exposed to {gamma} radiation, the reactions of organic radicals with nitrite ion, and the decomposition reactions of nitro compounds. In experiments with an organic tank non-radioactive simulant, the authors found that gas production is predominantly radiolytically induced. Concurrent with gas generation they observe the disappearance of EDTA, TBP, DBP and hexone. In the absence of radiolysis, the TBP readily saponifies in the basic medium, but decomposition of the other compounds required radiolysis. Key organic intermediates in the model are C-N bonded compounds such as oximes. As discussed in the report, oximes and nitro compounds decompose in strong base to yield aldehydes, ketones and carboxylic acids (from nitriles). Certain aldehydes can react in the absence of radiolysis to form H{sub 2}. Thus, if the pathways are correct, then organic compounds reacting via these pathways are oxidizing to lower energy content. 75 refs.

  16. Summary report for the tank tightness testing of underground storage tanks, Idaho National Engineering Laboratory

    SciTech Connect

    Not Available

    1990-03-01

    Between August 14, 1989, and August 26, 1989, 16 underground storage tanks were tank tightness tested for leaks as part of the Idaho National Engineering Laboratory tank management program. This report summarizes the results of these tank tightness tests, the modifications and repairs made to the tank systems, fuel transfer records, and any problems that affected the tank testing schedule. Of the 16 underground storage tanks tested, five failed the tank tightness test. Attempts were made to repair the tanks that failed the tank tightness test. Of those tanks, two were tested three times (one passed and one failed), and three were tested twice (two passed and one failed). The five failed tanks were removed and will be replaced with tanks that meet the Environmental Protection Agency regulations of underground storage tanks. 3 refs., 1 fig., 3 tabs.

  17. Supporting document for the Southeast Quadrant historical tank content estimate report for SY-tank farm

    SciTech Connect

    Brevick, C.H.; Gaddis, L.A.; Consort, S.D.

    1995-12-31

    Historical Tank Content Estimate of the Southeast Quadrant provides historical evaluations on a tank by tank basis of the radioactive mixed wastes stored in the underground double-shell tanks of the Hanford 200 East and West Areas. This report summarizes historical information such as waste history, temperature profiles, psychrometric data, tank integrity, inventory estimates and tank level history on a tank by tank basis. Tank Farm aerial photos and in-tank photos of each tank are provided. A brief description of instrumentation methods used for waste tank surveillance are included. Components of the data management effort, such as Waste Status and Transaction Record Summary, Tank Layer Model, Supernatant Mixing Model, Defined Waste Types, and Inventory Estimates which generate these tank content estimates, are also given in this report.

  18. Radio-Frequency Tank Eigenmode Sensor for Propellant Quantity Gauging

    NASA Technical Reports Server (NTRS)

    Zimmerli, Gregory A.; Buchanan, David A.; Follo, Jeffrey C.; Vaden, Karl R.; Wagner, James D.; Asipauskas, Marius; Herlacher, Michael D.

    2010-01-01

    Although there are several methods for determining liquid level in a tank, there are no proven methods to quickly gauge the amount of propellant in a tank while it is in low gravity or under low-settling thrust conditions where propellant sloshing is an issue. Having the ability to quickly and accurately gauge propellant tanks in low-gravity is an enabling technology that would allow a spacecraft crew or mission control to always know the amount of propellant onboard, thus increasing the chances for a successful mission. The Radio Frequency Mass Gauge (RFMG) technique measures the electromagnetic eigenmodes, or natural resonant frequencies, of a tank containing a dielectric fluid. The essential hardware components consist of an RF network analyzer that measures the reflected power from an antenna probe mounted internal to the tank. At a resonant frequency, there is a drop in the reflected power, and these inverted peaks in the reflected power spectrum are identified as the tank eigenmode frequencies using a peak-detection software algorithm. This information is passed to a pattern-matching algorithm, which compares the measured eigenmode frequencies with a database of simulated eigenmode frequencies at various fill levels. A best match between the simulated and measured frequency values occurs at some fill level, which is then reported as the gauged fill level. The database of simulated eigenmode frequencies is created by using RF simulation software to calculate the tank eigenmodes at various fill levels. The input to the simulations consists of a fairly high-fidelity tank model with proper dimensions and including internal tank hardware, the dielectric properties of the fluid, and a defined liquid/vapor interface. Because of small discrepancies between the model and actual hardware, the measured empty tank spectra and simulations are used to create a set of correction factors for each mode (typically in the range of 0.999 1.001), which effectively accounts for

  19. Tank-automotive robotics

    NASA Astrophysics Data System (ADS)

    Lane, Gerald R.

    1999-07-01

    To provide an overview of Tank-Automotive Robotics. The briefing will contain program overviews & inter-relationships and technology challenges of TARDEC managed unmanned and robotic ground vehicle programs. Specific emphasis will focus on technology developments/approaches to achieve semi- autonomous operation and inherent chassis mobility features. Programs to be discussed include: DemoIII Experimental Unmanned Vehicle (XUV), Tactical Mobile Robotics (TMR), Intelligent Mobility, Commanders Driver Testbed, Collision Avoidance, International Ground Robotics Competition (ICGRC). Specifically, the paper will discuss unique exterior/outdoor challenges facing the IGRC competing teams and the synergy created between the IGRC and ongoing DoD semi-autonomous Unmanned Ground Vehicle and DoT Intelligent Transportation System programs. Sensor and chassis approaches to meet the IGRC challenges and obstacles will be shown and discussed. Shortfalls in performance to meet the IGRC challenges will be identified.

  20. Insulated solar storage tanks

    SciTech Connect

    Eldighidy, S.M. )

    1991-01-01

    This paper presents the theoretical and experimental investigation of an insulated parallelepiped, outdoor solar, water-filled storage tank of size 1 m {times} 0.5 m {times} 0.3 m, that is made from galvanized iron. The absorption coefficient of the insulating material has been determined. The effects of plastic covers and insulation thickness on the water temperature and the energy gained or lost by water are investigated. Moreover, the effects of insulation thickness on the temperature profiles of the insulating material are discussed. The results show that the absorption coefficient decreases as the insulation thickness increases. Also, it is found that the glass wool insulation of 2.5 cm thickness has the best results compared with the other thicknesses (5 cm, 7.5 cm, and 10 cm) as far as the water temperature and the energy gained by water are concerned.

  1. TANK 7 CHARACTERIZATION AND WASHING STUDIES

    SciTech Connect

    Lambert, D.; Pareizs, J.; Click, D.

    2010-02-04

    A 3-L PUREX sludge sample from Tank 7 was characterized and then processed through a series of inhibited water washes to remove oxalate, sodium, and other soluble ions. Current plans use Tank 7 as one of the feed sources for Sludge Batch 7 (SB7). Tank 7 is high in oxalate due to the oxalic acid cleaning of the sludge heels from Tanks 5 and 6 and subsequent transfer to Tank 7. Ten decant and nine wash cycles were performed over a 47 day period at ambient temperature. Initially, seven decants and seven washes were completed based on preliminary estimates of the number of wash cycles required to remove the oxalate in the sludge. After reviewing the composition data, SRNL recommended the completion of 2 or 3 more decant/wash cycles to ensure all of the sodium oxalate had redissolved. In the first 7 washes, the slurry oxalate concentration was 12,300 mg/kg (69.6% oxalate removal compared to 96.1% removal of the other soluble ions). After all ten decants were complete, the slurry oxalate concentration was 3,080 mg/kg (89.2% oxalate removal compared to 99.0% of the other soluble ions). The rate of dissolution of oxalate increased significantly with subsequent washes until all of the sodium oxalate had been redissolved after seven decant/wash cycles. The measured oxalate concentrations agreed very well with LWO predictions for washing of the Tank 7 sample. Highlights of the analysis and washing of the Tank 7 sample include: (1) Sodium oxalate was detected in the as-received filtered solids. 95% of the oxalate was insoluble (undissolved) in the as-received slurry. (2) No sodium oxalate was detected in the post-wash filtered solids. (3) Sodium oxalate is the last soluble species that redissolves during washing with inhibited water. In order to significantly reduce the sodium oxalate concentration, the sludge must be highly washed, leaving the other soluble anions and cations (including sodium) very low in concentration. (4) The post-wash slurry had 1% of the soluble anions

  2. Exploration of the perceived and actual benefits of omega-3 fatty acids and the impact of FADS1 and FADS2 genetic information on dietary intake and blood levels of EPA and DHA.

    PubMed

    Roke, Kaitlin

    2017-03-01

    From a global health perspective, increased intake of omega-3 fatty acids (FAs), in particular eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA), are beneficial for human health. However, the consumption of EPA- and DHA-rich foods such as fatty fish is low in the Western diet. Therefore, finding new ways to motivate people to increase their consumption of omega-3 FAs is essential. To find effective ways to motivate individuals, understanding people's awareness of omega-3 FAs and how they obtain their knowledge about nutrition and health is critical. Consequently, we developed an online survey to assess awareness and self-reported intake of omega-3 FAs and supplements in young adults. EPA and DHA are also produced endogenously to a limited extent through a pathway regulated by fatty acid desaturase 1 and 2 (FADS1 and FADS2) genes. Of relevance, single nucleotide polymorphisms (SNPs) in the FADS genes influence levels of omega-3 FAs, where minor allele carriers have lower levels compared with major allele carriers. Accordingly, we conducted a clinical trial to investigate FA levels in response to dietary EPA and DHA supplementation in young adults stratified by SNPs in FADS1 and FADS2. The level of reported awareness of omega-3 terminology varied depending on an individual's field of study and thus providing all participants with the same set of nutrition information could be an effective tool to increase knowledge and motivate behaviour change. Additionally, the variation in FA levels in accordance to SNPs in FADS1 and FADS2 could be used to create tailored nutritional recommendations which may improve lifestyle habits. The results discovered in the first 2 studies regarding awareness of omega-3 FAs and genetic variation were subsequently used to design a nutrigenetics intervention in young adults. Individuals who received their FADS1 genetic information were more aware of different omega-3 FAs and reported fewer barriers to their consumption by the end of

  3. Tank farms hazards assessment

    SciTech Connect

    Broz, R.E.

    1994-09-30

    Hanford contractors are writing new facility specific emergency procedures in response to new and revised US Department of Energy (DOE) Orders on emergency preparedness. Emergency procedures are required for each Hanford facility that has the potential to exceed the criteria for the lowest level emergency, an Alert. The set includes: (1) a facility specific procedure on Recognition and Classification of Emergencies, (2) area procedures on Initial Emergency Response and, (3) an area procedure on Protective Action Guidance. The first steps in developing these procedures are to identify the hazards at each facility, identify the conditions that could release the hazardous material, and calculate the consequences of the releases. These steps are called a Hazards Assessment. The final product is a document that is similar in some respects to a Safety Analysis Report (SAR). The document could br produced in a month for a simple facility but could take much longer for a complex facility. Hanford has both types of facilities. A strategy has been adopted to permit completion of the first version of the new emergency procedures before all the facility hazards Assessments are complete. The procedures will initially be based on input from a task group for each facility. This strategy will but improved emergency procedures in place sooner and therefore enhance Hanford emergency preparedness. The purpose of this document is to summarize the applicable information contained within the Waste Tank Facility ``Interim Safety Basis Document, WHC-SD-WM-ISB-001`` as a resource, since the SARs covering Waste Tank Operations are not current in all cases. This hazards assessment serves to collect, organize, document and present the information utilized during the determination process.

  4. The actual goals of geoethics

    NASA Astrophysics Data System (ADS)

    Nemec, Vaclav

    2014-05-01

    The most actual goals of geoethics have been formulated as results of the International Conference on Geoethics (October 2013) held at the geoethics birth-place Pribram (Czech Republic): In the sphere of education and public enlightenment an appropriate needed minimum know how of Earth sciences should be intensively promoted together with cultivating ethical way of thinking and acting for the sustainable well-being of the society. The actual activities of the Intergovernmental Panel of Climate Changes are not sustainable with the existing knowledge of the Earth sciences (as presented in the results of the 33rd and 34th International Geological Congresses). This knowledge should be incorporated into any further work of the IPCC. In the sphere of legislation in a large international co-operation following steps are needed: - to re-formulate the term of a "false alarm" and its legal consequences, - to demand very consequently the needed evaluation of existing risks, - to solve problems of rights of individuals and minorities in cases of the optimum use of mineral resources and of the optimum protection of the local population against emergency dangers and disasters; common good (well-being) must be considered as the priority when solving ethical dilemmas. The precaution principle should be applied in any decision making process. Earth scientists presenting their expert opinions are not exempted from civil, administrative or even criminal liabilities. Details must be established by national law and jurisprudence. The well known case of the L'Aquila earthquake (2009) should serve as a serious warning because of the proven misuse of geoethics for protecting top Italian seismologists responsible and sentenced for their inadequate superficial behaviour causing lot of human victims. Another recent scandal with the Himalayan fossil fraud will be also documented. A support is needed for any effort to analyze and to disclose the problems of the deformation of the contemporary

  5. 49 CFR 180.519 - Periodic retest and inspection of tank cars other than single-unit tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Periodic retest and inspection of tank cars other... of Tank Cars § 180.519 Periodic retest and inspection of tank cars other than single-unit tank car... devices must be retested periodically as specified in Retest Table 1 of paragraph (b)(5) of this section...

  6. 49 CFR 180.519 - Periodic retest and inspection of tank cars other than single-unit tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Periodic retest and inspection of tank cars other... § 180.519 Periodic retest and inspection of tank cars other than single-unit tank car tanks. (a) General... periodically as specified in Retest Table 1 of paragraph (b)(5) of this section. Retests may be made at any...

  7. West Valley Tank 8D-1 and 8D-2 Inventory Estimation Methodology

    SciTech Connect

    O'Brien, Robert F.; Heasler, Patrick G.; Rowell, Laurene

    2001-07-20

    This report details work funded by the West Valley Support Project (WVSP) and the Tanks Focus Area Retrieval and Closure Program. The work was conducted by the Pacific Northwest National Laboratory (PNNL) and is in support of the West Valley Demonstration Project (WVDP). The WVDP site in New York was originally the site of a commercial nuclear fuel reprocessing plant. The high-level waste (HLW), approximately 2 million liters, produced during plutonium-uranium extraction (PUREX) and thorium extraction (THOREX) reprocessing campaigns at the plant and subsequent HLW preprocessing, was stored on site in three tanks identified as 8D-1, 8D-2, and 8D-4. Waste from the PUREX process was neutralized with NaOH for storage in a carbon steel tank designated as 8D-2. Neutralization resulted in a precipitated hydroxide sludge that settled to the bottom of the tank and was covered by a supernatant salt solution. The acidic THOREX waste, approximately 55,000 L, was first stored in a stainless steel tank (8D-4) and then added to the PUREX waste in Tank 8D-2. Supernatant decontamination, primarily cesium removal, was conducted by ion-exchange using in-tank columns suspended in Tank 8D-1. The cesium-loaded zeolite, resulting from the supernatant decontamination process, was dumped to the bottom of Tank 8D-1. Approximately 90% of the spent zeolite was transferred from Tank 8D-1 into Tank 8D-2 by the start of vitrification processing in June 1996. Periodically, the remaining spent zeolite contained in Tank 8D-1 is incrementally transferred to 8D-2. The combined waste in Tank 8D-2 continues to be processed through the Vitrification Facility into canisters for final repository disposal.

  8. Tank 241-U-103 tank characterization plan. Revision 1

    SciTech Connect

    Homi, C.S.

    1995-10-04

    This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-U-103.

  9. Tank vapor mitigation requirements for Hanford Tank Farms

    SciTech Connect

    Rakestraw, L.D.

    1994-11-15

    Westinghouse Hanford Company has contracted Los Alamos Technical Associates to listing of vapors and aerosols that are or may be emitted from the High Level Waste (HLW) tanks at Hanford. Mitigation requirements under Federal and State law, as well as DOE Orders, are included in the listing. The lists will be used to support permitting activities relative to tank farm ventilation system up-grades. This task is designated Task 108 under MJB-SWV-312057 and is an extension of efforts begun under Task 53 of Purchase Order MPB-SVV-03291 5 for Mechanical Engineering Support. The results of that task, which covered only thirty-nine tanks, are repeated here to provide a single source document for vapor mitigation requirements for all 177 HLW tanks.

  10. Tank characterization report for double shell tank 241-AP-104

    SciTech Connect

    Winkelman, W.D., Westinghouse Hanford

    1996-08-07

    This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-AP-104. This report supports the requirements of Tri-Party Agreement Milestone M-44-09.

  11. Tank characterization report for single shell tank 241-SX-108

    SciTech Connect

    Eggers, R.F., Westinghouse Hanford

    1996-07-11

    This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in tank 241-SX-108. This report supports the requirements of Tri-Party Agreement Milestone M-44-09.

  12. Tank characterization report for single shell tank 241-A-102

    SciTech Connect

    Jo, J., Westinghouse Hanford

    1996-07-29

    This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-A-102. This report supports the requirements of Tri-party Agreement Milestone M-44-09.

  13. Tank characterization report for single shell tank 241-S-107

    SciTech Connect

    Simpson, B.C.

    1996-09-19

    This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-S-107. This report supports the requirements of Tri- Party Agreement Milestone M-44-09.

  14. Chemical Characterization of an Envelope A Sample from Hanford Tank 241-AN-103

    SciTech Connect

    Hay, M.S.

    2000-08-23

    A whole tank composite sample from Hanford waste tank 241-AN-103 was received at the Savannah River Technology Center (SRTC) and chemically characterized. Prior to characterization the sample was diluted to {approximately}5 M sodium concentration. The filtered supernatant liquid, the total dried solids of the diluted sample, and the washed insoluble solids obtained from filtration of the diluted sample were analyzed. A mass balance calculation of the three fractions of the sample analyzed indicate the analytical results appear relatively self-consistent for major components of the sample. However, some inconsistency was observed between results where more than one method of determination was employed and for species present in low concentrations. A direct comparison to previous analyses of material from tank 241-AN-103 was not possible due to unavailability of data for diluted samples of tank 241-AN-103 whole tank composites. However, the analytical data for other types of samples from 241-AN-103 we re mathematically diluted and compare reasonably with the current results. Although the segments of the core samples used to prepare the sample received at SRTC were combined in an attempt to produce a whole tank composite, determination of how well the results of the current analysis represent the actual composition of the Hanford waste tank 241-AN-103 remains problematic due to the small sample size and the large size of the non-homogenized waste tank.

  15. Burst Pressure Failure of Titanium Tanks Damaged by Secondary Plumes from Hypervelocity Impacts on Aluminum Shields

    NASA Technical Reports Server (NTRS)

    Nahra, Henry; Ghosn, Louis; Christiansen, Eric; Davis, B. Alan; Keddy, Chris; Rodriquez, Karen; Miller, Joshua; Bohl, William

    2011-01-01

    Metallic pressure tanks used in space missions are inherently vulnerable to hypervelocity impacts from micrometeoroids and orbital debris; thereby knowledge of impact damage and its effect on the tank integrity is crucial to a spacecraft risk assessment. This paper describes tests that have been performed to assess the effects of hypervelocity impact (HVI) damage on Titanium alloy (Ti-6Al-4V) pressure vessels burst pressure and characteristics. The tests consisted of a pair of HVI impact tests on water-filled Ti-6Al-4V tanks (water being used as a surrogate to the actual propellant) and subsequent burst tests as well as a burst test on an undamaged control tank. The tanks were placed behind Aluminum (Al) shields and then each was impacted with a 7 km/s projectile. The resulting impact debris plumes partially penetrated the Ti-6Al-4V tank surfaces resulting in a distribution of craters. During the burst tests, the tank that failed at a lower burst pressure did appear to have the failure initiating at a crater site with observed spall cracks. A fracture mechanics analysis showed that the tanks failure at the impact location may have been due to a spall crack that formed upon impact of a fragmentation on the Titanium surface. This result was corroborated with a finite element analysis from calculated Von-Mises and hoop stresses.

  16. Ecodesign of Liquid Fuel Tanks

    NASA Astrophysics Data System (ADS)

    Gicevska, Jana; Bazbauers, Gatis; Repele, Mara

    2011-01-01

    The subject of the study is a 10 litre liquid fuel tank made of metal and used for fuel storage and transportation. The study dealt with separate life cycle stages of this product, compared environmental impacts of similar fuel tanks made of metal and plastic, as well as analysed the product's end-of-life cycle stage, studying the waste treatment and disposal scenarios. The aim of this study was to find opportunities for improvement and to develop proposals for the ecodesign of 10 litre liquid fuel tank.

  17. Early Warning and the Tank

    DTIC Science & Technology

    1989-06-01

    recharge the batteries. Naturally, this makes the tank more detectable. THE PEWS EARLY WARNING SYSTEM U.S. tank platoons currently have one Platoon... Early Warning System ( PEWS ) per platoon. These con- tain 10 seismic sensors which can be placed a kilometer or so foreward. A panel of lights indicates...BRL-.MR-3’E i" MEMORANDUM REPORT BRL-MR-3767 ’B𔃽BRL EARLY WARNING AND THE TANK FRED L. BUNN s IN JUN 16 1989 " JUNE 1989 APPROVED FOR PUBLIC RELEASE

  18. 5. West SideElevated Tank Structure with fume exhaust system and ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    5. West Side-Elevated Tank Structure with fume exhaust system and support structure in foreground. - Mare Island Naval Shipyard, Acid Mixing Facility, California Avenue & E Street, Vallejo, Solano County, CA

  19. Tank Waste Retrieval Lessons Learned at the Hanford Site

    SciTech Connect

    Dodd, R.A.

    2008-07-01

    approval of an exception to the waste retrieval criteria for a specific tank. Tank waste retrieval has been conducted at the Hanford Site over the last few decades using a method referred to as Past Practice Hydraulic Sluicing. Past Practice Hydraulic Sluicing employs large volumes of DST supernatant and water to dislodge, dissolve, mobilize, and retrieve tank waste. Concern over the leak integrity of SSTs resulted in the need for tank waste retrieval methods capable of using smaller volumes of liquid in a more controlled manner. Retrieval of SST waste in accordance with HFFACO requirements was initiated at the Hanford Site in April 2003. New and innovative tank waste retrieval methods that minimize and control the use of liquids are being implemented for the first time. These tank waste retrieval methods replace Past Practice Hydraulic Sluicing and employ modified sluicing, vacuum retrieval, and in-tank vehicle techniques. Waste retrieval has been completed in seven Hanford Site SSTs (C-106, C-103, C-201, C-202, C-203, C-204, and S-112) in accordance with HFFACO requirements. Three additional tanks are currently in the process of being retrieved (C-108, C-109 and S-102) Preparation for retrieval of two additional SSTs (C-104 and C-110) is ongoing with retrieval operations forecasted to start in calendar year 2008. Tank C-106 was retrieved to a residual waste volume of 470 ft{sup 3} using oxalic acid dissolution and modified sluicing. An Appendix H exception request for Tank C-106 is undergoing review. Tank C-103 was retrieved to a residual volume of 351 ft{sup 3} using a modified sluicing technology. This approach was successful at reaching the TPA limits for this tank of less than 360 ft{sup 3}and the limits of the technology. Tanks C-201, C-202, C-203, and C-204 are smaller (55,000 gallon) tanks and waste removal was completed in accordance with HFFACO requirements using a vacuum retrieval system. Residual waste volumes in each of these four tanks were less than 25 ft

  20. Stabilization of in-tank residual wastes and external-tank soil contamination for the tank focus area, Hanford tank initiative: Applications to the AX Tank Farm

    SciTech Connect

    Balsley, S.D.; Krumhansl, J.L.; Borns, D.J.; McKeen, R.G.

    1998-07-01

    A combined engineering and geochemistry approach is recommended for the stabilization of waste in decommissioned tanks and contaminated soils at the AX Tank Farm, Hanford, WA. A two-part strategy of desiccation and gettering is proposed for treatment of the in-tank residual wastes. Dry portland cement and/or fly ash are suggested as an effective and low-cost desiccant for wicking excess moisture from the upper waste layer. Getters work by either ion exchange or phase precipitation to reduce radionuclide concentrations in solution. The authors recommend the use of specific natural and man-made compounds, appropriately proportioned to the unique inventory of each tank. A filler design consisting of multilayered cementitous grout with interlayered sealant horizons should serve to maintain tank integrity and minimize fluid transport to the residual waste form. External tank soil contamination is best mitigated by placement of grouted skirts under and around each tank, together with installation of a cone-shaped permeable reactive barrier beneath the entire tank farm. Actinide release rates are calculated from four tank closure scenarios ranging from no action to a comprehensive stabilization treatment plan (desiccant/getters/grouting/RCRA cap). Although preliminary, these calculations indicate significant reductions in the potential for actinide transport as compared to the no-treatment option.

  1. 46 CFR 154.446 - Tank design.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 5 2014-10-01 2014-10-01 false Tank design. 154.446 Section 154.446 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type B § 154.446 Tank design. An independent tank type B must meet the calculations under § 154...

  2. 46 CFR 154.446 - Tank design.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 5 2012-10-01 2012-10-01 false Tank design. 154.446 Section 154.446 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type B § 154.446 Tank design. An independent tank type B must meet the calculations under § 154...

  3. 46 CFR 154.446 - Tank design.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 5 2013-10-01 2013-10-01 false Tank design. 154.446 Section 154.446 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type B § 154.446 Tank design. An independent tank type B must meet the calculations under § 154...

  4. 49 CFR 229.217 - Fuel tank.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 4 2011-10-01 2011-10-01 false Fuel tank. 229.217 Section 229.217 Transportation... TRANSPORTATION RAILROAD LOCOMOTIVE SAFETY STANDARDS Locomotive Crashworthiness Design Requirements § 229.217 Fuel tank. (a) External fuel tanks. Locomotives equipped with external fuel tanks shall, at a...

  5. 49 CFR 229.217 - Fuel tank.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Fuel tank. 229.217 Section 229.217 Transportation... TRANSPORTATION RAILROAD LOCOMOTIVE SAFETY STANDARDS Locomotive Crashworthiness Design Requirements § 229.217 Fuel tank. (a) External fuel tanks. Locomotives equipped with external fuel tanks shall, at a...

  6. 49 CFR 229.217 - Fuel tank.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 4 2014-10-01 2014-10-01 false Fuel tank. 229.217 Section 229.217 Transportation... TRANSPORTATION RAILROAD LOCOMOTIVE SAFETY STANDARDS Locomotive Crashworthiness Design Requirements § 229.217 Fuel tank. (a) External fuel tanks. Locomotives equipped with external fuel tanks shall, at a...

  7. 49 CFR 229.217 - Fuel tank.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 4 2010-10-01 2010-10-01 false Fuel tank. 229.217 Section 229.217 Transportation... TRANSPORTATION RAILROAD LOCOMOTIVE SAFETY STANDARDS Locomotive Crashworthiness Design Requirements § 229.217 Fuel tank. (a) External fuel tanks. Locomotives equipped with external fuel tanks shall, at a...

  8. 49 CFR 229.217 - Fuel tank.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 4 2013-10-01 2013-10-01 false Fuel tank. 229.217 Section 229.217 Transportation... TRANSPORTATION RAILROAD LOCOMOTIVE SAFETY STANDARDS Locomotive Crashworthiness Design Requirements § 229.217 Fuel tank. (a) External fuel tanks. Locomotives equipped with external fuel tanks shall, at a...

  9. 14 CFR 25.1013 - Oil tanks.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 1 2013-01-01 2013-01-01 false Oil tanks. 25.1013 Section 25.1013... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Oil System § 25.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 25.967. (b) Expansion space. Oil tank expansion...

  10. 46 CFR 64.29 - Tank saddles.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Tank saddles. 64.29 Section 64.29 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING MARINE PORTABLE TANKS AND CARGO HANDLING SYSTEMS Standards for an MPT § 64.29 Tank saddles. If a tank is not completely supported by a...

  11. 46 CFR 64.29 - Tank saddles.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Tank saddles. 64.29 Section 64.29 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING MARINE PORTABLE TANKS AND CARGO HANDLING SYSTEMS Standards for an MPT § 64.29 Tank saddles. If a tank is not completely supported by a...

  12. 14 CFR 29.1013 - Oil tanks.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... oil tank installation must meet the requirements of § 29.967. (b) Expansion space. Oil tank expansion space must be provided so that— (1) Each oil tank used with a reciprocating engine has an expansion... used with a turbine engine has an expansion space of not less than 10 percent of the tank capacity; (2...

  13. 14 CFR 29.1013 - Oil tanks.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... oil tank installation must meet the requirements of § 29.967. (b) Expansion space. Oil tank expansion space must be provided so that— (1) Each oil tank used with a reciprocating engine has an expansion... used with a turbine engine has an expansion space of not less than 10 percent of the tank capacity; (2...

  14. 14 CFR 23.1013 - Oil tanks.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ...) Expansion space. Oil tank expansion space must be provided so that— (1) Each oil tank used with a reciprocating engine has an expansion space of not less than the greater of 10 percent of the tank capacity or 0.5 gallon, and each oil tank used with a turbine engine has an expansion space of not less than 10...

  15. 14 CFR 29.1013 - Oil tanks.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 14 Aeronautics and Space 1 2013-01-01 2013-01-01 false Oil tanks. 29.1013 Section 29.1013... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Oil System § 29.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 29.967. (b) Expansion space. Oil tank...

  16. 49 CFR 230.116 - Oil tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 4 2012-10-01 2012-10-01 false Oil tanks. 230.116 Section 230.116 Transportation... Locomotive Tanks § 230.116 Oil tanks. The oil tanks on oil burning steam locomotives shall be maintained free from leaks. The oil supply pipe shall be equipped with a safety cut-off device that: (a) Is...

  17. 49 CFR 230.116 - Oil tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 4 2013-10-01 2013-10-01 false Oil tanks. 230.116 Section 230.116 Transportation... Locomotive Tanks § 230.116 Oil tanks. The oil tanks on oil burning steam locomotives shall be maintained free from leaks. The oil supply pipe shall be equipped with a safety cut-off device that: (a) Is...

  18. 49 CFR 230.116 - Oil tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 4 2014-10-01 2014-10-01 false Oil tanks. 230.116 Section 230.116 Transportation... Locomotive Tanks § 230.116 Oil tanks. The oil tanks on oil burning steam locomotives shall be maintained free from leaks. The oil supply pipe shall be equipped with a safety cut-off device that: (a) Is...

  19. 14 CFR 25.1013 - Oil tanks.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil tanks. 25.1013 Section 25.1013... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Oil System § 25.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 25.967. (b) Expansion space. Oil tank...

  20. 7 CFR 58.422 - Brine tank.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Brine tank. 58.422 Section 58.422 Agriculture....422 Brine tank. The brine tank shall be constructed of suitable non-toxic material and should be resistant to corrosion, pitting or flaking. The brine tank shall be operated so as to assure the brine...

  1. 46 CFR 64.29 - Tank saddles.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Tank saddles. 64.29 Section 64.29 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) MARINE ENGINEERING MARINE PORTABLE TANKS AND CARGO HANDLING SYSTEMS Standards for an MPT § 64.29 Tank saddles. If a tank is not completely supported by a...

  2. 14 CFR 29.1013 - Oil tanks.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Oil tanks. 29.1013 Section 29.1013... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Oil System § 29.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 29.967. (b) Expansion space. Oil tank...

  3. 7 CFR 58.218 - Surge tanks.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Surge tanks. 58.218 Section 58.218 Agriculture....218 Surge tanks. If surge tanks are used for hot milk, and temperatures of product including foam being held in the surge tank during processing, is not maintained at a minimum of 150 °F, then two...

  4. 27 CFR 24.167 - Tanks.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Tanks. 24.167 Section 24... TREASURY LIQUORS WINE Construction and Equipment § 24.167 Tanks. (a) General. All tanks on wine premises... the intended purpose. Each tank used for wine operations will be located, constructed, and equipped...

  5. 46 CFR 154.446 - Tank design.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Tank design. 154.446 Section 154.446 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS FOR... Tank Type B § 154.446 Tank design. An independent tank type B must meet the calculations under §...

  6. 7 CFR 58.320 - Brine tanks.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 3 2010-01-01 2010-01-01 false Brine tanks. 58.320 Section 58.320 Agriculture....320 Brine tanks. Brine tanks used for the treating of parchment liners shall be constructed of... liners. The tank should also be provided with a satisfactory drainage outlet....

  7. 49 CFR 179.10 - Tank mounting.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Tank mounting. 179.10 Section 179.10... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS REGULATIONS SPECIFICATIONS FOR TANK CARS General Design Requirements § 179.10 Tank mounting. (a) The manner in which tanks are attached to the...

  8. 46 CFR 154.446 - Tank design.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 5 2011-10-01 2011-10-01 false Tank design. 154.446 Section 154.446 Shipping COAST... SELF-PROPELLED VESSELS CARRYING BULK LIQUEFIED GASES Design, Construction and Equipment Independent Tank Type B § 154.446 Tank design. An independent tank type B must meet the calculations under §...

  9. 14 CFR 29.1013 - Oil tanks.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Oil System § 29.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 29.967. (b) Expansion space. Oil tank expansion... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Oil tanks. 29.1013 Section 29.1013...

  10. 14 CFR 25.1013 - Oil tanks.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... STANDARDS: TRANSPORT CATEGORY AIRPLANES Powerplant Oil System § 25.1013 Oil tanks. (a) Installation. Each oil tank installation must meet the requirements of § 25.967. (b) Expansion space. Oil tank expansion... 14 Aeronautics and Space 1 2011-01-01 2011-01-01 false Oil tanks. 25.1013 Section 25.1013...

  11. Double-shell tank emergency pumping guide

    SciTech Connect

    BROWN, M.H.

    1999-02-24

    This Double-Shell Tank Emergency Pumping Guide provides the preplanning necessary to expeditiously remove any waste that may leak from the primary tank to the secondary tank for Hanford's 28 DSTS. The strategy is described, applicable emergency procedures are referenced, and transfer routes and pumping equipment for each tank are identified.

  12. 49 CFR 179.400 - General specification applicable to cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... (CONTINUED) SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400 General specification applicable to cryogenic liquid tank car... 49 Transportation 3 2014-10-01 2014-10-01 false General specification applicable to...

  13. 27 CFR 24.230 - Examination of tank car or tank truck.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Examination of tank car or... TRADE BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL WINE Spirits § 24.230 Examination of tank car or tank truck. Upon arrival of a tank car or tank truck at the bonded wine premises, the proprietor...

  14. 27 CFR 24.230 - Examination of tank car or tank truck.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Examination of tank car or... TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Spirits § 24.230 Examination of tank car or tank truck. Upon arrival of a tank car or tank truck at the bonded wine premises, the proprietor...

  15. 27 CFR 24.230 - Examination of tank car or tank truck.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Examination of tank car or... TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Spirits § 24.230 Examination of tank car or tank truck. Upon arrival of a tank car or tank truck at the bonded wine premises, the proprietor...

  16. 27 CFR 24.230 - Examination of tank car or tank truck.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Examination of tank car or... TRADE BUREAU, DEPARTMENT OF THE TREASURY LIQUORS WINE Spirits § 24.230 Examination of tank car or tank truck. Upon arrival of a tank car or tank truck at the bonded wine premises, the proprietor...

  17. 27 CFR 24.230 - Examination of tank car or tank truck.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Examination of tank car or... TRADE BUREAU, DEPARTMENT OF THE TREASURY ALCOHOL WINE Spirits § 24.230 Examination of tank car or tank truck. Upon arrival of a tank car or tank truck at the bonded wine premises, the proprietor...

  18. ENHANCED CHEMICAL CLEANING OF SRS WASTE TANKS TO IMPROVE ACTINIDE SOLUBILITY

    SciTech Connect

    Rudisill, T.; Thompson, M.

    2011-09-20

    Processes for the removal of residual sludge from SRS waste tanks have historically used solutions containing up to 0.9 M oxalic acid to dissolve the remaining material following sludge removal. The selection of this process was based on a comparison of a number of studies performed to evaluate the dissolution of residual sludge. In contrast, the dissolution of the actinide mass, which represents a very small fraction of the waste, has not been extensively studied. The Pu, Np, and Am in the sludge is reported to be present as hydrated and crystalline oxides. To identify aqueous solutions which have the potential to increase the solubility of the actinides, the alkaline and mildly acidic test solutions shown below were selected as candidates for use in a series of solubility experiments. The efficiency of the solutions in solubilizing the actinides was evaluated using a simulated sludge prepared by neutralizing a HNO{sub 3} solution containing Pu, Np, and Am. The hydroxide concentration was adjusted to a 1.2 M excess and the solids were allowed to age for several weeks prior to starting the experiments. The sludge was washed with 0.01 M NaOH to prepare the solids for use. Following the addition of an equal portion of the solids to each test solution, the concentrations of Pu, Np, and Am were measured as a function of time over a 792 h (33 day) period to provide a direct comparison of the efficiency of each solution in solubilizing the actinide elements. Although the composition of the sludge was limited to the hydrated actinide oxides (and did not contain other components of demonstrated importance), the results of the study provides guidance for the selection of solutions which should be evaluated in subsequent tests with a more realistic surrogate sludge and actual tank waste.

  19. Weather in a Tank (Invited)

    NASA Astrophysics Data System (ADS)

    Illari, L.

    2013-12-01

    ';Weather in a Tank' is an approach to teaching atmospheres, oceans and climate which uses rotating laboratory demonstrations and associated curriculum materials. Originating at MIT, the approach has been further developed and expanded through collaborations with many Professors in universities across the country and around the world. The aim of the project is to offer instructors a repertoire of rotating tank experiments and a curriculum in fluid dynamics to better assist students in making connections between phenomena in the real world and basic principles of rotating fluid dynamics. The approach also provides a context for interactive experiments in which data is collected in real-time and then analyzed. In this presentation we will illustrate the ideas behind ';Weather in a Tank' by performing (if possible) some live laboratory experiments using rotating tanks of water, dyes and ice buckets, emphasizing the kind of quantitative approach we use in our teaching.

  20. Cryogenic storage tank thermal analysis

    NASA Technical Reports Server (NTRS)

    Wright, J. P.

    1976-01-01

    Parametric study discusses relationship between cryogenic boil-off and factors such as tank size, insulation thickness and performance, structural-support heat leaks and use of vapor-cooled shields. Data presented as series of nomographs and curves.

  1. Tank 48 Chemical Destruction - 13237

    SciTech Connect

    Simner, Steven P.; Aponte, Celia I.; Brass, Earl A.

    2013-07-01

    Small tank copper-catalyzed peroxide oxidation (CCPO) is a potentially viable technology to facilitate the destruction of tetraphenylborate (TPB) organic solids contained within the Tank 48H waste at the Savannah River Site (SRS). A maturation strategy was created that identified a number of near-term development activities required to determine the viability of the CCPO process, and subsequent disposition of the CCPO effluent. Critical activities included laboratory scale validation of the process and identification of forward transfer paths for the CCPO effluent. The technical documentation and the successful application of the CCPO process on simulated Tank 48 waste confirm that the CCPO process is a viable process for the disposition of the Tank 48 contents. (authors)

  2. Integral Radiator and Storage Tank

    NASA Technical Reports Server (NTRS)

    Burke, Kenneth A.; Miller, John R.; Jakupca, Ian; Sargi,Scott

    2007-01-01

    A simplified, lightweight system for dissipating heat of a regenerative fuel- cell system would include a heat pipe with its evaporator end placed at the heat source and its condenser end integrated into the wall of the regenerative fuel cell system gas-storage tanks. The tank walls act as heat-radiating surfaces for cooling the regenerative fuel cell system. The system was conceived for use in outer space, where radiation is the only physical mechanism available for transferring heat to the environment. The system could also be adapted for use on propellant tanks or other large-surface-area structures to convert them to space heat-radiating structures. Typically for a regenerative fuel cell system, the radiator is separate from the gas-storage tanks. By using each tank s surface as a heat-radiating surface, the need for a separate, potentially massive radiator structure is eliminated. In addition to the mass savings, overall volume is reduced because a more compact packaging scheme is possible. The underlying tank wall structure provides ample support for heat pipes that help to distribute the heat over the entire tank surface. The heat pipes are attached to the outer surface of each gas-storage tank by use of a high-thermal conductance, carbon-fiber composite-material wrap. Through proper choice of the composite layup, it is possible to exploit the high longitudinal conductivity of the carbon fibers (greater than the thermal conductivity of copper) to minimize the unevenness of the temperature distribution over the tank surface, thereby helping to maximize the overall heat-transfer efficiency. In a prototype of the system, the heat pipe and the composite wrap contribute an average mass of 340 g/sq m of radiator area. Lightweight space radiator panels have a mass of about 3,000 g/sq m of radiator area, so this technique saves almost 90 percent of the mass of separate radiator panels. In tests, the modified surface of the tank was found to have an emissivity of 0

  3. Toroidal Tank Development for Upper-stages

    NASA Technical Reports Server (NTRS)

    DeLay, Tom; Roberts, Keith

    2003-01-01

    The advantages, development, and fabrication of toroidal propellant tanks are profiled in this viewgraph presentation. Several images are included of independent research and development (IR&D) of toroidal propellant tanks at Marshall Space Flight Center (MSFC). Other images in the presentation give a brief overview of Thiokol conformal tank technology development. The presentation describes Thiokol's approach to continuous composite toroidal tank fabrication in detail. Images are shown of continuous and segmented toroidal tanks fabricated by Thiokol.

  4. Demonstration of the UNEX Process for the Simultaneous Separation of Cesium, Strontium, and the Actinides from Actual INEEL Sodium-Bearing Waste

    SciTech Connect

    Law, Jack Douglas; Herbst, Ronald Scott; Todd, Terry Allen; Romanovskiy, V.; Smirnov, I.; Babain, V.; Zaitsev, B.; Esimantovskiy, V.

    1999-11-01

    A universal solvent extraction (UNEX) process for the simultaneous separation of cesium, strontium, and the actinides from actual radioactive acidic tank waste was demonstrated at the Idaho National Engineering and Environmental Laboratory. The waste solution used in the countercurrent flowsheet demonstration was obtained from tank WM-185. The UNEX process uses a tertiary solvent containing 0.08 M chlorinated cobalt dicarbollide, 0.5% polyethylene glycol-400 (PEG-400), and 0.02 M diphenyl-N,N-dibutylcarbamoyl phosphine oxide (Ph2Bu2CMPO) in a diluent consisting of phenyltrifluoromethyl sulfone (FS-13). The countercurrent flowsheet demonstration was performed in a shielded cell facility using 24 stages of 2-cm diameter centrifugal contactors. Removal efficiencies of 99.4%, 99.995%, and 99.96% were obtained for 137Cs, 90Sr, and total alpha, respectively. This is sufficient to reduce the activities of 137Cs, 90Sr, and actinides in the WM-185 waste to below NRC Class A LLW requirements. Flooding and/or precipitate formation were not observed during testing. Significant amounts of the Zr (87%), Ba (>99%), Pb (98.8%), Fe (8%), Ca (10%), Mo (32%), and K (28%) were also removed from the feed with the universal solvent extraction flowsheet. 99Tc, Al, Hg, and Na were essentially inextractable (<1% extracted).

  5. Oxalate Mass Balance During Chemical Cleaning in Tank 5F

    SciTech Connect

    Poirier, M.; Fink, S.

    2011-07-08

    The Savannah River Site (SRS) is preparing Tank 5F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning to determine whether the tank is ready for closure. SRS personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. Analysis of the anions showed the measured oxalate removed from Tank 5F to be approximately 50% of the amount added in the oxalic acid. To close the oxalate mass balance, the author collected solid samples, leached them with nitric acid, and measured the concentration of cations and anions in the leachate.

  6. Multiple steady states in coupled flow tank reactors

    NASA Astrophysics Data System (ADS)

    Hunt, Katharine L. C.; Kottalam, J.; Hatlee, Michael D.; Ross, John

    1992-05-01

    Coupling between continuous-flow, stirred tank reactors (CSTR's), each having multiple steady states, can produce new steady states with different concentrations of the chemical species in each of the coupled tanks. In this work, we identify a kinetic potential ψ that governs the deterministic time evolution of coupled tank reactors, when the reaction mechanism permits a single-variable description of the states of the individual tanks; examples include the iodate-arsenous acid reaction, a cubic model suggested by Noyes, and two quintic models. Stable steady states correspond to minima of ψ, and unstable steady states to maxima or saddle points; marginally stable states typically correspond to saddle-node points. We illustrate the variation in ψ due to changes in the rate constant for external material intake (k0) and for exchange between tanks (kx). For fixed k0 values, we analyze the changes in numbers and types of steady states as kx increases from zero. We show that steady states disappear by pairwise coalescence; we also show that new steady states may appear with increasing kx, when the reaction mechanism is sufficiently complex. For fixed initial conditions, the steady state ultimately reached in a mixing experiment may depend on the exchange rate constant as a function of time, kx(t) : Adiabatic mixing is obtained in the limit of slow changes in kx(t) and instantaneous mixing in the limit as kx(t)→∞ while t remains small. Analyses based on the potential ψ predict the outcome of mixing experiments for arbitrary kx(t). We show by explicit counterexamples that a prior theory developed by Noyes does not correctly predict the instability points or the transitions between steady states of coupled tanks, to be expected in mixing experiments. We further show that the outcome of such experiments is not connected to the relative stability of steady states in individual tank reactors. We find that coupling may effectively stabilize the tanks. We provide

  7. Three-Dimensional Wave Interactions in a Baffled Ship Tank

    NASA Astrophysics Data System (ADS)

    Raad, Peter E.; Bidoae, Razvan

    1999-11-01

    The simulation of the general motion of a viscous fluid inside a baffled container is important for the design of tankers. A partially filled tank will adversely affect the stability of a ship. However, by the careful addition of baffles, the modified tank can actually improve the overall stability of the ship. The extent of the benefit will depend on the prevailing sea conditions. The general motion of the fluid inside a tank includes wave breaking and fluid-solid interactions, both of which are computationally challenging. The authors have developed a three-dimensional Eulerian-Lagrangian Marker and Micro Cell (ELMMC) method capable of simulating incompressible flow problems in which impact occurs between fluid fronts (as in wave breaking) as well as between a fluid front and solid (or porous) walls. In the ELMMC method, massless markers track the free surface in a Lagrangian manner. The primitive fluid flow variables are discretized on an Eulerian staggered grid. The instantaneous position of the surface markers defines the location of the free surface cells. The surface cells and their neighbors are subdivided into microcells in order to improve the tracking of the free surface and the treatment of the fluid-solid and fluid-fluid interactions. Animations of 3D solutions of general fluid motion inside a baffled tank will be presented along with selected corresponding experimental validations.

  8. Experimental characterization of jet static forces impacting waste tank components

    SciTech Connect

    Bamberger, J.A.; Bates, J.M. ); Waters, E.D. )

    1990-06-01

    Westinghouse Hanford Company plans to install mixer pumps in doubleshell waste tanks to mobilize and suspend settled sludge to allow eventual retrieval for treatment and permanent storage. The mixer pumps produce high momentum, horizontally directed jets that impact and mobilize the sludge and mix it into slurry for removal. There is concern that the force of the jet may damage tank internal components in its path. Scaled experiments were conducted to characterize the velocity profiles of the floor jet and to quantify the drag coefficients and impact forces for three tank components: radiation dry well, air lift circulator, and steam coil. Jet impact forces were measured on the scaled models at a 4 to 1 range of hydraulically scaled flow rates and a scaled range of distances between discharge nozzle and test component. The test were designed to provide hydraulic similarity between test conditions and expected actual waste tank conditions by using equal Reynolds number the jet maximum velocity impacted the test component. Forces measured on the models were used to calculate expected forces on the full scale components. Correlations of force on the test article versus distance from the nozzle were derived for the radiation dry well and air lift circulator based on the velocity correlation and drag parameter. The force data were also used to derive equivalent drag parameters which accounted for component shape factors including variation of jet impact area on the test article with distance from the nozzle. 8 refs., 44 figs., 42 tabs.

  9. 49 CFR 179.400-7 - Tank heads.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Tank heads. 179.400-7 Section 179.400-7... Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400-7 Tank heads. (a) Tank heads of the inner tank and outer jacket must be flanged and dished, or ellipsoidal. (b)...

  10. 49 CFR 179.400-7 - Tank heads.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Tank heads. 179.400-7 Section 179.400-7... Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400-7 Tank heads. (a) Tank heads of the inner tank and outer jacket must be flanged and dished, or ellipsoidal. (b)...

  11. 49 CFR 179.400-7 - Tank heads.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Tank heads. 179.400-7 Section 179.400-7... Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400-7 Tank heads. (a) Tank heads of the inner tank and outer jacket must be flanged and dished, or ellipsoidal. (b)...

  12. 49 CFR 179.400-7 - Tank heads.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 3 2014-10-01 2014-10-01 false Tank heads. 179.400-7 Section 179.400-7... Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400-7 Tank heads. (a) Tank heads of the inner tank and outer jacket must be flanged and dished, or ellipsoidal. (b)...

  13. 49 CFR 179.400-14 - Cleaning of inner tank.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400-14 Cleaning of inner tank. The interior of the inner tank and all connecting lines... 49 Transportation 2 2010-10-01 2010-10-01 false Cleaning of inner tank. 179.400-14 Section...

  14. 49 CFR 179.400-16 - Access to inner tank.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400-16 Access to inner tank. (a) The inner tank must be provided with a means of... 49 Transportation 2 2010-10-01 2010-10-01 false Access to inner tank. 179.400-16 Section...

  15. 49 CFR 173.315 - Compressed gases in cargo tanks and portable tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... conditions. In this case, except for UN portable tanks, each insulated tank must be covered by a sheet metal... sulfur dioxide optional portable tanks, one or more fusible plugs examined by the Bureau of...

  16. Stabilization of in-tank residual wastes and external-tank soil contamination for the tank focus area, Hanford Tank Initiative: Applications to the AX tank farm

    SciTech Connect

    Becker, D.L.

    1997-11-03

    This report investigates five technical areas for stabilization of decommissioned waste tanks and contaminated soils at the Hanford Site AX Farm. The investigations are part of a preliminary evacuation of end-state options for closure of the AX Tanks. The five technical areas investigated are: (1) emplacement of cementations grouts and/or other materials; (2) injection of chemicals into contaminated soils surrounding tanks (soil mixing); (3) emplacement of grout barriers under and around the tanks; (4) the explicit recognition that natural attenuation processes do occur; and (5) combined geochemical and hydrological modeling. Research topics are identified in support of key areas of technical uncertainty, in each of the five areas. Detailed cost-benefit analyses of the technologies are not provided. This investigation was conducted by Sandia National Laboratories, Albuquerque, New Mexico, during FY 1997 by tank Focus Area (EM-50) funding.

  17. ROBOTIC TANK INSPECTION END EFFECTOR

    SciTech Connect

    Rachel Landry

    1999-10-01

    The objective of this contract between Oceaneering Space Systems (OSS) and the Department of Energy (DOE) was to provide a tool for the DOE to inspect the inside tank walls of underground radioactive waste storage tanks in their tank farms. Some of these tanks are suspected to have leaks, but the harsh nature of the environment within the tanks precludes human inspection of tank walls. As a result of these conditions only a few inspection methods can fulfill this task. Of the methods available, OSS chose to pursue Alternating Current Field Measurement (ACFM), because it does not require clean surfaces for inspection, nor any contact with the Surface being inspected, and introduces no extra by-products in the inspection process (no coupling fluids or residues are left behind). The tool produced by OSS is the Robotic Tank Inspection End Effector (RTIEE), which is initially deployed on the tip of the Light Duty Utility Arm (LDUA). The RTEE combines ACFM with a color video camera for both electromagnetic and visual inspection The complete package consists of an end effector, its corresponding electronics and software, and a user's manual to guide the operator through an inspection. The system has both coarse and fine inspection modes and allows the user to catalog defects and suspected areas of leakage in a database for further examination, which may lead to emptying the tank for repair, decommissioning, etc.. The following is an updated report to OSS document OSS-21100-7002, which was submitted in 1995. During the course of the contract, two related subtasks arose, the Wall and Coating Thickness Sensor and the Vacuum Scarifying and Sampling Tool Assembly. The first of these subtasks was intended to evaluate the corrosion and wall thinning of 55-gallon steel drums. The second was retrieved and characterized the waste material trapped inside the annulus region of the underground tanks on the DOE's tank farms. While these subtasks were derived from the original intent of

  18. DEMONSTRATION OF THE GLYCOLIC-FORMIC FLOWSHEET IN THE SRNL SHIELDED CELLS USING ACTUAL WASTE

    SciTech Connect

    Lambert, D.; Pareizs, J.; Click, D.

    2011-11-07

    Glycolic acid was effective at dissolving many metals, including iron, during processing with simulants. Criticality constraints take credit for the insolubility of iron during processing to prevent criticality of fissile materials. Testing with actual waste was needed to determine the extent of iron and fissile isotope dissolution during Chemical Process Cell (CPC) processing. The Alternate Reductant Project was initiated by the Savannah River Remediation (SRR) Company to explore options for the replacement of the nitric-formic flowsheet used for the CPC at the Defense Waste Processing Facility (DWPF). The goals of the Alternate Reductant Project are to reduce CPC cycle time, increase mass throughput of the facility, and reduce operational hazards. In order to achieve these goals, several different reductants were considered during initial evaluations conducted by Savannah River National Laboratory (SRNL). After review of the reductants by SRR, SRNL, and Energy Solutions (ES) Vitreous State Laboratory (VSL), two flowsheets were further developed in parallel. The two flowsheet options included a nitric-formic-glycolic flowsheet, and a nitric-formic-sugar flowsheet. As of July 2011, SRNL and ES/VSL have completed the initial flowsheet development work for the nitric-formic-glycolic flowsheet and nitric-formic-sugar flowsheet, respectively. On July 12th and July 13th, SRR conducted a Systems Engineering Evaluation (SEE) to down select the alternate reductant flowsheet. The SEE team selected the Formic-Glycolic Flowsheet for further development. Two risks were identified in SEE for expedited research. The first risk is related to iron and plutonium solubility during the CPC process with respect to criticality. Currently, DWPF credits iron as a poison for the fissile components of the sludge. Due to the high iron solubility observed during the flowsheet demonstrations with simulants, it was necessary to determine if the plutonium in the radioactive sludge slurry

  19. ANNUAL RADIOACTIVE WASTE TANK INSPECTION PROGRAM 2009

    SciTech Connect

    West, B.; Waltz, R.

    2010-06-21

    Aqueous radioactive wastes from Savannah River Site (SRS) separations and vitrification processes are contained in large underground carbon steel tanks. Inspections made during 2009 to evaluate these vessels and other waste handling facilities along with evaluations based on data from previous inspections are the subject of this report. The 2009 inspection program revealed that the structural integrity and waste confinement capability of the Savannah River Site waste tanks were maintained. All inspections scheduled per LWO-LWE-2008-00423, HLW Tank Farm Inspection Plan for 2009, were completed. All Ultrasonic measurements (UT) performed in 2009 met the requirements of C-ESG-00006, In-Service Inspection Program for High Level Waste Tanks, Rev. 1, and WSRC-TR-2002-00061, Rev.4. UT inspections were performed on Tank 29 and the findings are documented in SRNL-STI-2009-00559, Tank Inspection NDE Results for Fiscal Year 2009, Waste Tank 29. Post chemical cleaning UT measurements were made in Tank 6 and the results are documented in SRNL-STI-2009-00560, Tank Inspection NDE Results Tank 6, Including Summary of Waste Removal Support Activities in Tanks 5 and 6. A total of 6669 photographs were made and 1276 visual and video inspections were performed during 2009. Twenty-Two new leaksites were identified in 2009. The locations of these leaksites are documented in C-ESR-G-00003, SRS High Level Waste Tank Leaksite Information, Rev.4. Fifteen leaksites at Tank 5 were documented during tank wall/annulus cleaning activities. Five leaksites at Tank 6 were documented during tank wall/annulus cleaning activities. Two new leaksites were identified at Tank 19 during waste removal activities. Previously documented leaksites were reactivated at Tanks 5 and 12 during waste removal activities. Also, a very small amount of additional leakage from a previously identified leaksite at Tank 14 was observed.

  20. Destruction of Ion-Exchange Resin In Waste From the HFIR, T1 and T2 Tanks Using Fenton's Reagent

    SciTech Connect

    Taylor, P.A.

    2002-11-06

    The use of Fenton's reagent (hydrogen peroxide and a ferrous iron catalyst) has been tested as a method for destroying ion-exchange resin in radioactive waste from three underground storage tanks at the Oak Ridge National Laboratory. The resin in these wastes must be destroyed before they can be transferred to the Melton Valley Storage Tanks (MVSTs) prior to solidification and disposal at the Waste Isolation Pilot Plant. The reaction with ion-exchange resin requires a dilute acidic solution (pH = 3 to 5) and moderate temperatures (T = 60 to 100 C). Laboratory-scale tests of the process have been successfully completed using both simulants and actual waste samples. The ion-exchange resin is oxidized to carbon dioxide and inorganic salts. The reaction rate is quite slow for temperatures below 70 C but increases almost linearly as the temperature of the slurry increases from 70 to 90 C. Pilot-scale tests have demonstrated the process using larger samples of actual waste slurries. A sample from the High Flux Isotope Reactor (HFIR) tank, containing 500 mL of settled solids (resin and inorganic sludge) in a total volume of 1800 mL, was successfully treated to meet MVST waste acceptance requirements in 9 h of processing time, using 1650 mL of 50 wt% hydrogen peroxide. A composite sample from the T1 and T2 tanks, which contained 1000 mL of settled solids in a total volume of 2000 mL required 8 h of treatment, using 1540 mL of 50 wt% peroxide, to meet waste acceptance requirements. Hydrogen peroxide reaction rates were 0.71 to 0.74 g H{sub 2}O{sub 2}/L/min, with very low (<2000 mg/L) concentrations of peroxide in the slurry. The reaction produces mostly carbon dioxide gas during the early part of the treatment, when organic carbon concentrations in the slurry are high, and then produces increasing amounts of oxygen as the organic carbon concentration drops. Small amounts (<3 vol%) of carbon monoxide are also generated. The off-gas from the pilot-scale tests, which was 81

  1. RECOMMENDATIONS FOR SAMPLING OF TANK 19 IN F TANK FARM

    SciTech Connect

    Harris, S.; Shine, G.

    2009-12-14

    Representative sampling is required for characterization of the residual material in Tank 19 prior to operational closure. Tank 19 is a Type IV underground waste storage tank located in the F-Tank Farm. It is a cylindrical-shaped, carbon steel tank with a diameter of 85 feet, a height of 34.25 feet, and a working capacity of 1.3 million gallons. Tank 19 was placed in service in 1961 and initially received a small amount of low heat waste from Tank 17. It then served as an evaporator concentrate (saltcake) receiver from February 1962 to September 1976. Tank 19 also received the spent zeolite ion exchange media from a cesium removal column that once operated in the Northeast riser of the tank to remove cesium from the evaporator overheads. Recent mechanical cleaning of the tank removed all mounds of material. Anticipating a low level of solids in the residual waste, Huff and Thaxton [2009] developed a plan to sample the waste during the final clean-up process while it would still be resident in sufficient quantities to support analytical determinations in four quadrants of the tank. Execution of the plan produced fewer solids than expected to support analytical determinations in all four quadrants. Huff and Thaxton [2009] then restructured the plan to characterize the residual separately in the North and the South regions: two 'hemispheres.' This document provides sampling recommendations to complete the characterization of the residual material on the tank bottom following the guidance in Huff and Thaxton [2009] to split the tank floor into a North and a South hemisphere. The number of samples is determined from a modification of the formula previously published in Edwards [2001] and the sample characterization data for previous sampling of Tank 19 described by Oji [2009]. The uncertainty is quantified by an upper 95% confidence limit (UCL95%) on each analyte's mean concentration in Tank 19. The procedure computes the uncertainty in analyte concentration as a

  2. Evaluation of tank waste transfers at 241-AW tank farm

    SciTech Connect

    Willis, W.L.

    1998-05-27

    A number of waste transfers are needed to process and feed waste to the private contractors in support of Phase 1 Privatization. Other waste transfers are needed to support the 242-A Evaporator, saltwell pumping, and other ongoing Tank Waste Remediation System (TWRS) operations. The purpose of this evaluation is to determine if existing or planned equipment and systems are capable of supporting the Privatization Mission of the Tank Farms and continuing operations through the end of Phase 1B Privatization Mission. Projects W-211 and W-314 have been established and will support the privatization effort. Equipment and system upgrades provided by these projects (W-211 and W-314) will also support other ongoing operations in the tank farms. It is recognized that these projects do not support the entire transfer schedule represented in the Tank Waste Remediation system Operation and Utilization Plan. Additionally, transfers surrounding the 241-AW farm must be considered. This evaluation is provided as information, which will help to define transfer paths required to complete the Waste Feed Delivery (WFD) mission. This document is not focused on changing a particular project, but it is realized that new project work in the 241-AW Tank Farm is required.

  3. Auxiliary resonant DC tank converter

    DOEpatents

    Peng, Fang Z.

    2000-01-01

    An auxiliary resonant dc tank (ARDCT) converter is provided for achieving soft-switching in a power converter. An ARDCT circuit is coupled directly across a dc bus to the inverter to generate a resonant dc bus voltage, including upper and lower resonant capacitors connected in series as a resonant leg, first and second dc tank capacitors connected in series as a tank leg, and an auxiliary resonant circuit comprising a series combination of a resonant inductor and a pair of auxiliary switching devices. The ARDCT circuit further includes first clamping means for holding the resonant dc bus voltage to the dc tank voltage of the tank leg, and second clamping means for clamping the resonant dc bus voltage to zero during a resonant period. The ARDCT circuit resonantly brings the dc bus voltage to zero in order to provide a zero-voltage switching opportunity for the inverter, then quickly rebounds the dc bus voltage back to the dc tank voltage after the inverter changes state. The auxiliary switching devices are turned on and off under zero-current conditions. The ARDCT circuit only absorbs ripples of the inverter dc bus current, thus having less current stress. In addition, since the ARDCT circuit is coupled in parallel with the dc power supply and the inverter for merely assisting soft-switching of the inverter without participating in real dc power transmission and power conversion, malfunction and failure of the tank circuit will not affect the functional operation of the inverter; thus a highly reliable converter system is expected.

  4. CHARACTERIZATION OF TANK 17 RESIDUAL WASTE

    SciTech Connect

    D'Entremont, P; Thomas Caldwell, T

    1997-09-22

    Plans are to close Tank 17, a type IV waste tank in the F-area Tank Farm, by filling it with pumpable backfills. Most of the waste was removed from the tank in the late 1980s, and the remainder of the waste was removed in a short spray washing campaign that began on 11 April 1997. More details on the planned closure can be found in the Closure Plan for the High-Level Waste (HLW) Tanks and the specific closure module for Tank 17. To show that closure of the tank is environmentally sound, a performance evaluation has been performed for Tank 17. The performance evaluation projected the concentration of contaminants at various locations and times after closure. This report documents the basis for the inventories of contaminants that were used in the Tank 17 performance evaluation.

  5. 241-AW Tank Farm Construction Extent of Condition Review for Tank Integrity

    SciTech Connect

    Barnes, Travis J.; Gunter, Jason R.; Reeploeg, Gretchen E.

    2013-11-19

    This report provides the results of an extent of condition construction history review for the 241-AW tank farm. The construction history of the 241-AW tank farm has been reviewed to identify issues similar to those experienced during tank AY-102 construction. Those issues and others impacting integrity are discussed based on information found in available construction records, using tank AY-102 as the comparison benchmark. In the 241-AW tank farm, the fourth double-shell tank farm constructed, similar issues as those with tank 241-AY-102 construction occured. The overall extent of similary and affect on 241-AW tank farm integrity is described herein.

  6. 241-AY-101 Tank Construction Extent of Condition Review for Tank Integrity

    SciTech Connect

    Barnes, Travis J.; Gunter, Jason R.

    2013-08-26

    This report provides the results of an extent of condition construction history review for tank 241-AY-101. The construction history of tank 241-AY-101 has been reviewed to identify issues similar to those experienced during tank AY-102 construction. Those issues and others impacting integrity are discussed based on information found in available construction records, using tank AY-102 as the comparison benchmark. In tank 241-AY-101, the second double-shell tank constructed, similar issues as those with tank 241-AY-102 construction reoccurred. The overall extent of similary and affect on tank 241-AY-101 integrity is described herein.

  7. 241-AP Tank Farm Construction Extent of Condition Review for Tank Integrity

    SciTech Connect

    Barnes, Travis J.; Gunter, Jason R.; Reeploeg, Gretchen E.

    2014-04-04

    This report provides the results of an extent of condition construction history review for the 241-AP tank farm. The construction history of the 241-AP tank farm has been reviewed to identify issues similar to those experienced during tank AY-102 construction. Those issues and others impacting integrity are discussed based on information found in available construction records, using tank AY-102 as the comparison benchmark. In the 241-AP tank farm, the sixth double-shell tank farm constructed, tank bottom flatness, refractory material quality, post-weld stress relieving, and primary tank bottom weld rejection were improved.

  8. Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

    2004-03-29

    In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

  9. Evaluation of Hanford Tank Supernatant Availability for Technetium Management Project Studies in FY16

    SciTech Connect

    Rapko, Brian M.

    2015-09-30

    This report examines the need for actual Hanford tank waste solutions to support tasks in the Technetium Management Program in fiscal year (FY) 2016. One key need is to identify both samples where a majority of the soluble technetium is present as pertechnetate and samples where it is not. The total amount of tank supernatant needed from any given tank waste supernatant was determined by polling the tasks leaders for their technology testing needs in FY16 and then arbitrarily ascribing a 10% process loss associated with consolidation and the Cs-137 removal needed to reduce the dose to a level suitable for testing in radiological fumehoods. These polling results identified a need for approximately 2.1 to 3.6 kg of any particular targeted Hanford tank waste supernatant.

  10. Modeling of Gaseous Oxygen Liquefaction Inside Mars Ascent Vehicle Propellant Tank

    NASA Technical Reports Server (NTRS)

    Wang, Xiao-Yen; Plachta, David

    2016-01-01

    The In-Situ production of propellants for Mars missions has been considered to utilize the Carbon dioxide (CO2) in Mars atmosphere to produce Oxygen using a high temperature solid oxide electrolyzer. The oxygen then needs to be cooled, liquefied, and stored to be available for propulsion and other end users. The storage period could be up to two years either in the actual Mars ascent propulsion tanks or in a separate tank. Recent investigations have demonstrated the feasibility of both achieving zero-boil-off and controlling the pressure of oxygen within a tank using high efficiency cryocoolers. A representative configuration of tube on tank liquefaction using cryocooler is shown in Fig. 1.

  11. LNG vapor mitigation by doubling tank-wall integrity. Topical report, September 1987-March 1989

    SciTech Connect

    Atallah, S.; Shah, J.N.

    1990-04-16

    A review of the results of numerous experimental studies on the crack arrest capabilities of 9% nickel-steels and the heat-affected zone has confirmed the excellent historical experience with these materials when used for LNG and other cryogenic liquid storage. In the absence of any actual unzippering tank wall failures involving 9% nickel-steels, the historical data can only suggest that the failure rate of such tanks is much less than 5 x 10(-4) per year. The capability of a second external 9% nickel-steel wall to withstand the asymmetric load and thermal shock resulting from a catastrophic failure of the inner wall was questioned. A concrete wall built around an existing LNG tank, buttressed by an earthen berm is one of several alternative means for reducing the extent of a vapor cloud should the existing tank fail. Guidelines for estimating the initial and annual costs of such a structure are given.

  12. Tank 241-C-105 tank characterization plan. Revision 1

    SciTech Connect

    Schreiber, R.D.

    1995-01-25

    The Defense Nuclear Facilities Safety Board has advised the DOE to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The data quality objective (DQO) process was chosen as a tool to be used to identify the sampling and analytical needs for the resolution of safety issues. Tank C-105 was on the Higher Heat Load Watch List. However, it is presently classified as a non-Watch List low heat load tank and is monitored weekly. This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, and WHC 222-S Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples from Tank 241-C-105.

  13. TANK48 CFD MODELING ANALYSIS

    SciTech Connect

    Lee, S.

    2011-05-17

    The process of recovering the waste in storage tanks at the Savannah River Site (SRS) typically requires mixing the contents of the tank to ensure uniformity of the discharge stream. Mixing is accomplished with one to four dual-nozzle slurry pumps located within the tank liquid. For the work, a Tank 48 simulation model with a maximum of four slurry pumps in operation has been developed to estimate flow patterns for efficient solid mixing. The modeling calculations were performed by using two modeling approaches. One approach is a single-phase Computational Fluid Dynamics (CFD) model to evaluate the flow patterns and qualitative mixing behaviors for a range of different modeling conditions since the model was previously benchmarked against the test results. The other is a two-phase CFD model to estimate solid concentrations in a quantitative way by solving the Eulerian governing equations for the continuous fluid and discrete solid phases over the entire fluid domain of Tank 48. The two-phase results should be considered as the preliminary scoping calculations since the model was not validated against the test results yet. A series of sensitivity calculations for different numbers of pumps and operating conditions has been performed to provide operational guidance for solids suspension and mixing in the tank. In the analysis, the pump was assumed to be stationary. Major solid obstructions including the pump housing, the pump columns, and the 82 inch central support column were included. The steady state and three-dimensional analyses with a two-equation turbulence model were performed with FLUENT{trademark} for the single-phase approach and CFX for the two-phase approach. Recommended operational guidance was developed assuming that local fluid velocity can be used as a measure of sludge suspension and spatial mixing under single-phase tank model. For quantitative analysis, a two-phase fluid-solid model was developed for the same modeling conditions as the single

  14. Lenders get break in EPA final rule on underground storage tanks

    SciTech Connect

    Seppa, N.

    1996-03-01

    EPA has issued a final rule that limits the liability of financial institutions and others that lead money based on properties with underground storage tanks (USTs). This article describes the reasoning behind the rule and the highpoints of the actual rule itself.

  15. Chemical research projects office fuel tank sealants review. [flight testing of fluorosilicone sealants

    NASA Technical Reports Server (NTRS)

    Rosser, R. W.; Parker, J. A.

    1974-01-01

    The status of high-temperature fuel tank sealants for military and potentially commercial supersonic aircraft is examined. The interrelationships of NASA's sealants program comprise synthesis and development of new fluoroether elastomers, sealant prediction studies, flight simulation and actual flight testing of best state-of-the-art fluorosilicone sealants. The technical accomplishments of these projects are reviewed.

  16. High speed machining of space shuttle external tank liquid hydrogen barrel panel

    NASA Technical Reports Server (NTRS)

    Hankins, J. D.

    1983-01-01

    Actual and projected optimum High Speed Machining data for producing shuttle external tank liquid hydrogen barrel panels of aluminum alloy 2219-T87 are reported. The data included various machining parameters; e.g., spindle speeds, cutting speed, table feed, chip load, metal removal rate, horsepower, cutting efficiency, cutter wear (lack of) and chip removal methods.

  17. TANK FARM CLOSURE - A NEW TWIST ON REGULATORY STRATEGIES FOR CLOSURE OF WASTE TANK RESIDUALS FOLLOWING NUREG

    SciTech Connect

    LEHMAN LL

    2008-01-23

    Waste from a number of single-shell tanks (SST) at the U.S. Department of Energy's (DOE) Hanford Site has been retrieved by CH2M HILL Hanford Group to fulfill the requirements of the 'Hanford Federal Facility Agreement and Consent Order (HFFACO) [1]. Laboratory analyses of the Hanford tank residual wastes have provided concentration data which will be used to determine waste classification and disposal options for tank residuals. The closure of tank farm facilities remains one of the most challenging activities faced by the DOE. This is due in part to the complicated regulatory structures that have developed. These regulatory structures are different at each of the DOE sites, making it difficult to apply lessons learned from one site to the next. During the past two years with the passage of the Section 3116 of the 'Ronald Reagan Defense Authorization Act of 2005' (NDAA) [2] some standardization has emerged for Savannah River Site and the Idaho National Laboratory tank residuals. Recently, with the issuance of 'NRC Staff Guidance for Activities Related to US. Department of Energy Waste Determinations' (NUREG-1854) [3] more explicit options may be considered for Hanford tank residuals than are presently available under DOE Orders. NUREG-1854, issued in August 2007, contains several key pieces of information that if utilized by the DOE in the tank closure process, could simplify waste classification and streamline the NRC review process by providing information to the NRC in their preferred format. Other provisions of this NUREG allow different methods to be applied in determining when waste retrieval is complete by incorporating actual project costs and health risks into the calculation of 'technically and economically practical'. Additionally, the NUREG requires a strong understanding of the uncertainties of the analyses, which given the desire of some NRC/DOE staff may increase the likelihood of using probabilistic approaches to uncertainty analysis. The purpose

  18. Tank Waste Disposal Program redefinition

    SciTech Connect

    Grygiel, M.L.; Augustine, C.A.; Cahill, M.A.; Garfield, J.S.; Johnson, M.E.; Kupfer, M.J.; Meyer, G.A.; Roecker, J.H.; Holton, L.K.; Hunter, V.L.; Triplett, M.B.

    1991-10-01

    The record of decision (ROD) (DOE 1988) on the Final Environmental Impact Statement, Hanford Defense High-Level, Transuranic and Tank Wastes, Hanford Site, Richland Washington identifies the method for disposal of double-shell tank waste and cesium and strontium capsules at the Hanford Site. The ROD also identifies the need for additional evaluations before a final decision is made on the disposal of single-shell tank waste. This document presents the results of systematic evaluation of the present technical circumstances, alternatives, and regulatory requirements in light of the values of the leaders and constitutents of the program. It recommends a three-phased approach for disposing of tank wastes. This approach allows mature technologies to be applied to the treatment of well-understood waste forms in the near term, while providing time for the development and deployment of successively more advanced pretreatment technologies. The advanced technologies will accelerate disposal by reducing the volume of waste to be vitrified. This document also recommends integration of the double-and single-shell tank waste disposal programs, provides a target schedule for implementation of the selected approach, and describes the essential elements of a program to be baselined in 1992.

  19. Lightweight Tanks for Storing Liquefied Natural Gas

    NASA Technical Reports Server (NTRS)

    DeLay, Tom

    2008-01-01

    Single-walled, jacketed aluminum tanks have been conceived for storing liquefied natural gas (LNG) in LNG-fueled motor vehicles. Heretofore, doublewall steel tanks with vacuum between the inner and outer walls have been used for storing LNG. In comparison with the vacuum- insulated steel tanks, the jacketed aluminum tanks weigh less and can be manufactured at lower cost. Costs of using the jacketed aluminum tanks are further reduced in that there is no need for the vacuum pumps heretofore needed to maintain vacuum in the vacuum-insulated tanks.

  20. Vacuum leak detection for double bottom tanks

    SciTech Connect

    Hagen, T.; Rials, R.

    1995-12-31

    Double bottom tanks offer strong leak detection advantages. By incorporating the use of vacuum detection between the two bottoms, the tank bottoms can be verified leak free after construction and during tank use. Utilizing vacuum leak detection requires special considerations. In 1992 a tank construction company built 10 tanks for an oil company in Ponca City, Oklahoma. Each of these tanks were built with a double bottom. This paper provides insight into the planning, construction and testing of this type of double bottom design.

  1. In-tank recirculating arsenic treatment system

    DOEpatents

    Brady, Patrick V [Albuquerque, NM; Dwyer, Brian P [Albuquerque, NM; Krumhansl, James L [Albuquerque, NM; Chwirka, Joseph D [Tijeras, NM

    2009-04-07

    A low-cost, water treatment system and method for reducing arsenic contamination in small community water storage tanks. Arsenic is removed by using a submersible pump, sitting at the bottom of the tank, which continuously recirculates (at a low flow rate) arsenic-contaminated water through an attached and enclosed filter bed containing arsenic-sorbing media. The pump and treatment column can be either placed inside the tank (In-Tank) by manually-lowering through an access hole, or attached to the outside of the tank (Out-of-Tank), for easy replacement of the sorption media.

  2. 46 CFR 98.30-7 - Materials authorized for transfer to and from a portable tank.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... point of 80 °F (27 °C) or less by open-cup test Benzene Gasoline Mixtures of Hydrochloric acid and hydrofluoric acid containing not more than 36 percent hydrochloric acid or 2 percent hydrofluoric acid 1 Methyl... portable tank conforming to the T Code “T1” specified in 49 CFR 172.102(c)(7)(i). (c) Sulfuric acid having...

  3. Racial Discrimination in Occupations; Perceived and Actual.

    ERIC Educational Resources Information Center

    Turner, Castellano B.; Turner, Barbara F.

    1981-01-01

    A study of perceived discrimination by race and by sex for each of 21 occupations was compared with actual percentages of Blacks in each field. The study suggested that: (1) perception of opportunity corresponded to actual structure of opportunity; and (2) both a change in the social structure and individual belief systems is needed to further…

  4. Storage tanks ASTs and USTs

    SciTech Connect

    Krause, D.E.; Lehmann, J.A.

    1995-12-31

    Risks of storage tank failure and ground contamination are just two of the problems facing storage tank owners and operators today. As governmental concern for public safety increases, so does the pressure on operators to implement the necessary changes to satisfy the new regulations within the specified time frame. There is a lot of legislation pending on aboveground storage tanks that will affect companies planning construction in the future. The paper presented here are being presented not only to cover pending legislation, but also prospective legislation. Besides the important regulatory issues, the technical program covers corrosion, leak detection and prevention, contingency planning, emergency response, asset preservation, design, construction, and maintenance. All paper have been processed separately for inclusion on the database.

  5. ICPP Tank Farm systems analysis

    SciTech Connect

    Palmer, W.B.; Beer, M.J.; Cukars, M.; Law, J.P.; Millet, C.B.; Murphy, J.A.; Nenni, J.A.; Park, C.V.; Pruitt, J.I.; Thiel, E.C.; Ward, F.S.; Woodard, J.

    1994-01-01

    During the early years (1950--1965) of Idaho Chemical Processing Plant (ICPP) operations, eleven, 300,000-gallon waste storage tanks were constructed. A project was in progress to replace these aging tanks; however, since fuel reprocessing has been curtailed at ICPP, it is not clear that the new tanks are required. The Department of Energy (DOE) requested a systems engineering evaluation to determine the need for the new tanks. Over 100 alternatives were identified during a facilitated team meeting using Value Engineering techniques. After eliminating any ideas which clearly could not meet the requirements, the remaining ideas were combined into nine basic cases with five sub cases. These fourteen cases were then carefully defined using two methods. First, each case was drawn graphically to show waste processing equipment interfaces and time constraints where they existed or were imposed. Second, each case was analyzed using a time-dependent computer simulation of ICPP waste management activities to determine schedule interactions, liquid storage requirements, and solid waste quantities. Based on the evaluation data, the team developed the following recommendations: Install and operate the high-level liquid waste evaporator; minimize liquid waste generation as much as possible within the constraints of required ICPP operational, safety, and environmental commitments; bring a Waste Immobilization Facility on line by 2008 or earlier; operate NWCF as required to alleviate the need for new tank farm capacity; maximize the concentration of Na and K in the calcine to minimize the final amount of waste requiring immobilization; avoid using Bin Set 7 for calcine storage, if possible, to reduce future calcine retrieval and D&D costs; and use WM-190 for liquid waste storage and one of the pillar and panel vaulted tanks as the spare.

  6. TANK SPACE ALTERNATIVES ANALYSIS REPORT

    SciTech Connect

    TURNER DA; KIRCH NW; WASHENFELDER DJ; SCHAUS PS; WODRICH DD; WIEGMAN SA

    2010-04-27

    This report addresses the projected shortfall of double-shell tank (DST) space starting in 2018. Using a multi-variant methodology, a total of eight new-term options and 17 long-term options for recovering DST space were evaluated. These include 11 options that were previously evaluated in RPP-7702, Tank Space Options Report (Rev. 1). Based on the results of this evaluation, two near-term and three long-term options have been identified as being sufficient to overcome the shortfall of DST space projected to occur between 2018 and 2025.

  7. Tank waste concentration mechanism study

    SciTech Connect

    Pan, L.C.; Johnson, L.J.

    1994-09-01

    This study determines whether the existing 242-A Evaporator should continue to be used to concentrate the Hanford Site radioactive liquid tank wastes or be replaced by an alternative waste concentration process. Using the same philosophy, the study also determines what the waste concentration mechanism should be for the future TWRS program. Excess water from liquid DST waste should be removed to reduce the volume of waste feed for pretreatment, immobilization, and to free up storage capacity in existing tanks to support interim stabilization of SSTS, terminal cleanout of excess facilities, and other site remediation activities.

  8. 49 CFR 179.401 - Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 3 2012-10-01 2012-10-01 false Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks. 179.401 Section 179.401 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED)...

  9. 49 CFR 179.401 - Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 3 2011-10-01 2011-10-01 false Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks. 179.401 Section 179.401 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED)...

  10. 49 CFR 179.401 - Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 3 2013-10-01 2013-10-01 false Individual specification requirements applicable to inner tanks for cryogenic liquid tank car tanks. 179.401 Section 179.401 Transportation Other Regulations Relating to Transportation (Continued) PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION (CONTINUED)...

  11. Tank Characterization Report for Single Shell Tank 241-U-103

    SciTech Connect

    ADAMS, M.R.

    2000-02-01

    This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-U-103. This report supports the requirements of the Tri-Party Agreement Milestone M-44-15B.

  12. Corrosion studies of carbon steel under impinging jets of simulated slurries of neutralized current acid waste (NCAW) and neutralized cladding removal waste (NCRW)

    SciTech Connect

    Smith, H.D.; Elmore, M.R.

    1992-01-01

    Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the Hanford Site call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank`s structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the actual NCRW and NCAW both chemically and physically. The tests simulated those conditions expected to exist in the respective double-shell tanks during waste retrieval operations. Results of both tests indicate that, because of the action of the mixer pump slurry jets, the waste retrieval operations proposed for NCAW and NCRW will moderately accelerate corrosion of the tank wall and floor. Based on the corrosion of initially unoxidized test specimens, and the removal of corrosion products from those specimens, the maximum time-averaged corrosion rates of carbon steel in both waste simulants for the length of the test was {approximately}4 mil/yr. The protective oxide layer that exists in each storage tank is expected to inhibit corrosion of the carbon steel.

  13. 33 CFR 157.220 - Dedicated clean ballast tanks: Standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels Design and Equipment § 157.220 Dedicated...). (b) Each tank under paragraph (a) of this section must be: (1) A wing tank; or (2) Any other...

  14. 33 CFR 157.220 - Dedicated clean ballast tanks: Standards.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels Design and Equipment § 157.220 Dedicated...). (b) Each tank under paragraph (a) of this section must be: (1) A wing tank; or (2) Any other...

  15. 33 CFR 157.220 - Dedicated clean ballast tanks: Standards.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels Design and Equipment § 157.220 Dedicated...). (b) Each tank under paragraph (a) of this section must be: (1) A wing tank; or (2) Any other...

  16. 33 CFR 157.220 - Dedicated clean ballast tanks: Standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... CARRYING OIL IN BULK Dedicated Clean Ballast Tanks on Tank Vessels Design and Equipment § 157.220 Dedicated...). (b) Each tank under paragraph (a) of this section must be: (1) A wing tank; or (2) Any other...

  17. Phase chemistry and radionuclide retention from simulated tank sludges

    SciTech Connect

    KRUMHANSL,JAMES L.; LIU,J.; ARTHUR,SARA E.; HUTCHERSON,SHEILA K.; QIAN,MORRIS; ANDERSON,HOWARD L.

    2000-05-19

    Decommissioning high level nuclear waste tanks will leave small amounts of residual sludge clinging to the walls and floor of the structures. The permissible amount of material left in the tanks depends on the radionuclide release characteristics of the sludge. At present, no systematic process exists for assessing how much of the remaining inventory will migrate, and which radioisotopes will remain relatively fixed. Working with actual sludges is both dangerous and prohibitively expensive. Consequently, methods were developed for preparing sludge simulants and doping them with nonradioactive surrogates for several radionuclides and RCRA metals of concern in actual sludges. The phase chemistry of these mixes was found to be a reasonable match for the main phases in actual sludges. Preliminary surrogate release characteristics for these sludges were assessed by lowering the ionic strength and pH of the sludges in the manner that would occur if normal groundwater gained access to a decommissioned tank. Most of the Se, Cs and Tc in the sludges will be released into the first pulse of groundwater passing through the sludge. A significant fraction of the other surrogates will be retained indefinitely by the sludges. This prolonged sequestration results from a combination coprecipitated and sorbed into or onto relatively insoluble phases such as apatite, hydrous oxides of Fe, Al, Bi and rare earth oxides and phosphates. The coprecipitated fraction cannot be released until the host phase dissolves or recrystallizes. The sorbed fraction can be released by ion exchange processes as the pore fluid chemistry changes. However, these releases can be predicted based on a knowledge of the fluid composition and the surface chemistry of the solids. In this regard, the behavior of the hydrous iron oxide component of most sludges will probably play a dominant role for many cationic radionuclides while the hydrous aluminum oxides may be more important in governing anion releases.

  18. Comparative safety analysis of LNG storage tanks

    SciTech Connect

    Fecht, B.A.; Gates, T.E.; Nelson, K.O.; Marr, G.D.

    1982-07-01

    LNG storage tank design and response to selected release scenarios were reviewed. The selection of the scenarios was based on an investigation of potential hazards as cited in the literature. A review of the structure of specific LNG storage facilities is given. Scenarios initially addressed included those that most likely emerge from the tank facility itself: conditions of overfill and overflow as related to liquid LNG content levels; over/underpressurization at respective tank vapor pressure boundaries; subsidence of bearing soil below tank foundations; and crack propagation in tank walls due to possible exposure of structural material to cryogenic temperatures. Additional scenarios addressed include those that result from external events: tornado induced winds and pressure drops; exterior tank missile impact with tornado winds and rotating machinery being the investigated mode of generation; thermal response due to adjacent fire conditions; and tank response due to intense seismic activity. Applicability of each scenario depended heavily on the specific tank configurations and material types selected. (PSB)

  19. 7 CFR 58.422 - Brine tank.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ....422 Brine tank. The brine tank shall be constructed of suitable non-toxic material and should be... clean, well circulated, and of the proper strength and temperature for the variety of cheese being made. ...

  20. Leaking Underground Storage Tank (LUST) Trust Fund

    EPA Pesticide Factsheets

    In 1986, Congress created the Leaking Underground Storage Tank (LUST) Trust Fund to address releases from federally regulated underground storage tanks (USTs) by amending Subtitle I of the Solid Waste Disposal Act.

  1. Hopkins works with tanks from the ARFTA

    NASA Image and Video Library

    2013-11-24

    ISS038-E-008289 (24 Nov. 2013) --- NASA astronaut Michael Hopkins, Expedition 38 flight engineer, works with tanks from the Advanced Recycle Filter Tank Assembly (ARFTA) in the Tranquility node of the International Space Station.

  2. Hopkins works with tanks from the ARFTA

    NASA Image and Video Library

    2013-11-24

    ISS038-E-008287 (24 Nov. 2013) --- NASA astronaut Michael Hopkins, Expedition 38 flight engineer, works with tanks from the Advanced Recycle Filter Tank Assembly (ARFTA) in the Tranquility node of the International Space Station.

  3. 27 CFR 24.167 - Tanks.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... wine operations not enclosed within a building or room will be enclosed within a secure fence unless the premises where the tank is located are enclosed by a fence or wall, or all tank openings are...

  4. Technical requirements specification for tank waste retrieval

    SciTech Connect

    Lamberd, D.L.

    1996-09-26

    This document provides the technical requirements specification for the retrieval of waste from the underground storage tanks at the Hanford Site. All activities covered by this scope are conducted in support of the Tank Waste Remediation System (TWRS) mission.

  5. Tank 241-U-106 vapor sampling and analysis tank characterization report

    SciTech Connect

    Huckaby, J.L.

    1995-05-31

    This report presents the details of the Hanford waste tank characterization study for tank 241-U-106. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected to determine the potential risks to tank farm workers due to fugitive emissions from the tank.

  6. 49 CFR 179.400 - General specification applicable to cryogenic liquid tank car tanks.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false General specification applicable to cryogenic... MATERIALS REGULATIONS SPECIFICATIONS FOR TANK CARS Specification for Cryogenic Liquid Tank Car Tanks and Seamless Steel Tanks (Classes DOT-113 and 107A) § 179.400 General specification applicable to cryogenic...

  7. Cathodic protection design for aboveground storage tanks

    SciTech Connect

    Koszewski, L.; Quincy, G.L.

    1995-12-31

    The application of cathodic protection for aboveground storage tank (AST) bottoms has been accomplished in a variety of approaches, with varying degrees of success. Recent State regulations, requiring corrosion protection for new tanks and secondary containment for double bottom tanks, have prompted new application techniques to be developed for AST cathodic protection. Improved design applications are now available to todays` tank owners and operators to provide effective long term cathodic protection.

  8. Filament-wound, fiberglass cryogenic tank supports

    NASA Technical Reports Server (NTRS)

    Carter, J. S.; Timberlake, T. E.

    1971-01-01

    The design, fabrication, and testing of filament-wound, fiberglass cryogenic tank supports for a LH2 tank, a LF2/FLOX tank and a CH4 tank. These supports consist of filament-wound fiberglass tubes with titanium end fittings. These units were satisfactorily tested at cryogenic temperatures, thereby offering a design that can be reliably and economically produced in large or small quantities. The basic design concept is applicable to any situation where strong, lightweight axial load members are desired.

  9. CHEMICAL SLUDGE HEEL REMOVAL AT THE SAVANNAH RIVER SITE F TANK FARM CLOSURE PROJECT 8183

    SciTech Connect

    Thaxton, D; Timothy Baughman, T

    2008-01-16

    Chemical Sludge Removal (CSR) is the final waste removal activity planned for some of the oldest nuclear waste tanks located at the Savannah River Site (SRS) in Aiken, SC. In 2008, CSR will be used to empty two of these waste tanks in preparation for final closure. The two waste tanks chosen to undergo this process have previously leaked small amounts of nuclear waste from the primary tank into an underground secondary containment pan. CSR involves adding aqueous oxalic acid to the waste tank in order to dissolve the remaining sludge heel. The resultant acidic waste solution is then pumped to another waste tank where it will be neutralized and then stored awaiting further processing. The waste tanks to be cleaned have a storage capacity of 2.84E+06 liters (750,000 gallons) and a target sludge heel volume of 1.89E+04 liters (5,000 gallons) or less for the initiation of CSR. The purpose of this paper is to describe the CSR process and to discuss the most significant technical issues associated with the development of CSR.

  10. Hanford Tanks Initiative fiscal year 1997 retrieval technology demonstrations

    SciTech Connect

    Berglin, E.J.

    1998-02-05

    The Hanford Tanks Initiative was established in 1996 to address a range of retrieval and closure issues associated with radioactive and hazardous waste stored in Hanford`s single shell tanks (SSTs). One of HTI`s retrieval goals is to ``Successfully demonstrate technology(s) that provide expanded capabilities beyond past practice sluicing and are extensible to retrieve waste from other SSTS.`` Specifically, HTI is to address ``Alternative technologies to past practice sluicing`` ... that can ... ``successfully remove the hard heel from a sluiced tank or to remove waste from a leaking SST`` (HTI Mission Analysis). During fiscal year 1997, the project contracted with seven commercial vendor teams to demonstrate retrieval technologies using waste simulants. These tests were conducted in two series: three integrated tests (IT) were completed in January 1997, and four more comprehensive Alternative Technology Retrieval Demonstrations (ARTD) were completed in July 1997. The goal of this testing was to address issues to minimize the risk, uncertainties, and ultimately the overall cost of removing waste from the SSTS. Retrieval technologies can be separated into three tracks based on how the tools would be deployed in the tank: globally (e.g., sluicing) or using vehicles or robotic manipulators. Accordingly, the HTI tests included an advanced sluicer (Track 1: global systems), two different vehicles (Track 2: vehicle based systems), and three unique manipulators (Track 3: arm-based systems), each deploying a wide range of dislodging tools and conveyance systems. Each industry team produced a system description as envisioned for actual retrieval and a list of issues that could prevent using the described system; defined the tests to resolve the issues; performed the test; and reported the results, lessons learned, and state of issue resolution. These test reports are cited in this document, listed in the reference section, and summarized in the appendices. This report

  11. RECOMMENDATIONS FOR SAMPLING OF TANK 18 IN F TANK FARM

    SciTech Connect

    Shine, G.

    2009-12-14

    Representative sampling is required for characterization of the residual floor material in Tank 18 prior to operational closure. Tank 18 is an 85-foot diameter, 34-foot high carbon steel tank with nominal operating volume of 1,300,000 gallons. It is a Type IV tank, and has been in service storing radioactive materials since 1959. Recent mechanical cleaning of the tank removed all mounds of material. Anticipating a low level of solids in the residual material, Huff and Thaxton [2009] developed a plan to sample the material during the final clean-up process while it would still be resident in sufficient quantities to support analytical determinations in four quadrants of the tank. Execution of the plan produced fewer solids than expected to support analytical determinations in all four quadrants. Huff and Thaxton [2009] then restructured the plan to characterize the residual floor material separately in the North and the South regions: two 'hemispheres.' This document provides sampling recommendations to complete the characterization of the residual material on the tank bottom following the guidance in Huff and Thaxton [2009] to split the tank floor into a North and a South hemisphere. The number of samples is determined from a modification of the formula previously published in Edwards [2001] and the sample characterization data for previous sampling of Tank 18 described by Oji [2009]. The uncertainty is quantified by an upper 95% confidence limit (UCL95%) on each analyte's mean concentration in Tank 18. The procedure computes the uncertainty in analyte concentration as a function of the number of samples, and the final number of samples is determined when the reduction in the uncertainty from an additional sample no longer has a practical impact on results. The characterization of the full suite of analytes in the North hemisphere is currently supported by a single Mantis rover sample obtained from a compact region near the center riser. A floor scrape sample was

  12. Decision analysis for continuous cover gas monitoring of Ferrocyanide Watch List tanks

    SciTech Connect

    Fowler, K.D.; Graves, R.D.

    1994-07-01

    This document pertains to underground waste storage tanks at the Hanford Site that have been identified to potentially contain a significant amount of ferrocyanide compounds. This document evaluates the need for continuously monitoring the headspace vapors in Ferrocyanide Watch List tanks to detect flammable gases or gases that could indicate the occurrence of a propagating ferrocyanide-nitrate/nitrite reaction. The results of modeling studies and gas monitoring, and sludge sample analyses of actual ferrocyanide tank wastes have indicated no need to continuously monitor the vapor spaces in ferrocyanide tanks. This conclusion is based in part on the following factors: (1) a study performance on waste aging suggests that the ferrocyanide has degraded in the tanks during the more than 35 years of storage; therefore, the ferrocyanide is not present in concentrations that could support an exothermic reaction, also, the moisture present in the waste is sufficient to preclude a self-sustaining (propagating) ferrocyanide-nitrate reaction; (2) evaluation of core sample results from Tank 241-C-109 and Tank 241-C-112 support laboratory studies showing that ferrocyanide has degraded and the fuel concentration in the tanks is considerably lower than postulated by flowsheet simulants; (3) no gases have been identified that would indicate the occurrence of a ferrocyanide nitrate/nitrite reaction; additionally, a self-sustaining ferrocyanide nitrate/nitrite reaction is not possible under current and future planned storage conditions. After reviewing the available information, it is evident that there would be little safety benefit from continuous in-tank vapor monitoring, and the time and commitment of operations schedule and equipment funds are not justified in the face of competing needs.

  13. Alternative Chemical Cleaning Methods for High Level Waste Tanks: Simulant Studies

    SciTech Connect

    Rudisill, T.; King, W.; Hay, M.; Jones, D.

    2015-11-19

    Solubility testing with simulated High Level Waste tank heel solids has been conducted in order to evaluate two alternative chemical cleaning technologies for the dissolution of sludge residuals remaining in the tanks after the exhaustion of mechanical cleaning and sludge washing efforts. Tests were conducted with non-radioactive pure phase metal reagents, binary mixtures of reagents, and a Savannah River Site PUREX heel simulant to determine the effectiveness of an optimized, dilute oxalic/nitric acid cleaning reagent and pure, dilute nitric acid toward dissolving the bulk non-radioactive waste components. A focus of this testing was on minimization of oxalic acid additions during tank cleaning. For comparison purposes, separate samples were also contacted with pure, concentrated oxalic acid which is the current baseline chemical cleaning reagent. In a separate study, solubility tests were conducted with radioactive tank heel simulants using acidic and caustic permanganate-based methods focused on the “targeted” dissolution of actinide species known to be drivers for Savannah River Site tank closure Performance Assessments. Permanganate-based cleaning methods were evaluated prior to and after oxalic acid contact.

  14. Tank 241-BY-112 vapor sampling and analysis tank characterization report

    SciTech Connect

    Huckaby, J.L.

    1995-05-31

    Tank 241-BY-112 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-112 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  15. Tank 241-BY-111 vapor sampling and analysis tank characterization report

    SciTech Connect

    Huckaby, J.L.

    1995-05-31

    Tank 241-BY-111 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-111 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  16. Tank 241-U-107 vapor sampling and analysis tank characterization report

    SciTech Connect

    Huckaby, J.L.

    1995-05-31

    Tank 241-U-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-U-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  17. Tank 241-BY-104 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect

    Huckaby, J.L.

    1995-05-31

    Tank 241-BY-104 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-104 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  18. Tank 241-TX-118 vapor sampling and analysis tank characterization report

    SciTech Connect

    Huckaby, J.L.

    1995-05-31

    Tank 241-TX-118 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-TX-118 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  19. Tank 241-BY-103 vapor sampling and analysis tank characterization report

    SciTech Connect

    Huckaby, J.L.

    1995-05-05

    Tank 241-BY-103 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-103 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}

  20. Tank 241-BY-107 vapor sampling and analysis tank characterization report. Revision 1

    SciTech Connect

    Huckaby, J.L.

    1995-05-31

    Tank 241-BY-107 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in {open_quotes}Program Plan for the Resolution of Tank Vapor Issues.{close_quotes} Tank 241-BY-107 was vapor sampled in accordance with {open_quotes}Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.{close_quotes}