Science.gov

Sample records for additional line broadening

  1. Charge Correlations in Plasma Line Broadening

    SciTech Connect

    Wrighton, Jeffrey M.; Dufty, James W.

    2008-10-22

    The traditional theory of plasma line broadening is re-examined to correct for phenom-enological assumptions regarding charge correlations. Conditions for static ions are assumed, and the ion microfield distribution is introduced without neglecting ion-electron correlations, and with a precise definition for the ion field at the radiator. Radiator and plasma subsystems are defined so as to make a second order calculation of electron broadening valid for the case of high Z radiators. The electron broadening operator is identified in terms of the fluctuation of the electron density at the radiator, averaged over the entire plasma constrained by a given value for the ion microfield.

  2. Line Broadening and the Solar Opacity Problem

    NASA Astrophysics Data System (ADS)

    Krief, M.; Feigel, A.; Gazit, D.

    2016-06-01

    The calculation of line widths constitutes theoretical and computational challenges in the calculation of opacities of hot, dense plasmas. Opacity models use line broadening approximations that are untested at stellar interior conditions. Moreover, calculations of atomic spectra of the Sun indicate a large discrepancy in the K-shell line widths between several atomic codes and the Opacity-Project (OP). In this work, the atomic code STAR is used to study the sensitivity of solar opacities to line broadening. Variations in the solar opacity profile due to an increase of the Stark widths resulting from discrepancies with OP, are compared, in light of the solar opacity problem, with the required opacity variations of the present day Sun, as imposed by helioseismic and neutrino observations. The resulting variation profile is much larger than the discrepancy between different atomic codes, agrees qualitatively with the missing opacity profile, recovers about half of the missing opacity nearby the convection boundary, and has a little effect in the internal regions. Since it is hard to estimate quantitatively the uncertainty in the Stark widths, we show that an increase of all line widths by a factor of about ˜100 recovers quantitatively the missing opacity. These results emphasize the possibility that photoexcitation processes are not modeled properly, and more specifically, highlight the need for a better theoretical characterization of the line broadening phenomena at stellar interior conditions, and of the uncertainty due to the way it is implemented by atomic codes.

  3. Pressure broadening of CO and OCS spectral lines

    NASA Astrophysics Data System (ADS)

    Bouanich, J.-P.; Blanquet, G.

    1988-09-01

    This paper reviews the principal features of two semiclassical impact theories of collisional line-broadening, Anderson (1949) and Tsao-Curnutte (1962) theory and the more recent theory of Robert and Bonamy (1979). These models are applied to the calculation of self-, N2-, O2- and CO2-broadened line widths of CO and of self-, O2-, and N2-broadened linewidths of OCS. In addition to the electrostatic interactions, two anisotropic potentials are considered: a simple one governing dispersion interaction and a more elaborate atom-atom interaction potential. Selected experimental values for broadening coefficients of CO and OCS at room temperature and around 200 K are compared with the theoretical values. Conclusions on the two theories and the intermolecular potentials used are drawn from this comparison.

  4. Spectral line broadening in magnetized black holes

    SciTech Connect

    Frolov, Valeri P.; Shoom, Andrey A.; Tzounis, Christos E-mail: ashoom@ualberta.ca

    2014-07-01

    We consider weakly magnetized non-rotating black holes. In the presence of a regular magnetic field the motion of charged particles in the vicinity of a black hole is modified. As a result, the position of the innermost stable circular orbit (ISCO) becomes closer to the horizon. When the Lorentz force is repulsive (directed from the black hole) the ISCO radius can reach the gravitational radius. In the process of accretion charged particles (ions) of the accreting matter can be accumulated near their ISCO, while neutral particles fall down to the black hole after they reach 6M radius. The sharp spectral line Fe α, emitted by iron ions at such orbits, is broadened when the emission is registered by a distant observer. In this paper we study this broadening effect and discuss how one can extract information concerning the strength of the magnetic field from the observed spectrum.

  5. Collision Broadening Of Line Spectrum In Sonoluminescence

    SciTech Connect

    Li Chaohui; An Yu

    2008-06-24

    The direct measurement of temperature inside a sonoluminescing bubble as it is at its flashing phase is almost impossible due to the smallness of the bubble and the short duration of the flashing. One may estimate the temperature through fitting the continuum spectrum of sonoluminescence by the black body radiation formula, or fitting the shape of atomic or molecular line spectrum (the different temperature, density and pressure result in the different shape of the line spectrum due to the effect of collision broadening). However, the temperature changes in a huge range at short duration as the bubble flashes, therefore, the observed spectra are some kind of average one, so are those fitted results. To evaluate the instantaneous temperature more accurately, we simulate the processes of the bubble motion and the thermodynamics inside the bubble, in which atomic or molecular line spectra with the collision broadening effect and the continuum spectra contributed from the processes of electron-atom bremsstrahlung, electron-ion bremsstrahlung and recombination radiation and radiative attachment of electrons to atoms and molecules are taken into account in calculating the light emission. If both the calculated continuum spectra and the shape of line spectra can well represent the experimental data, we may deduce that the calculation of the temperature, density and pressure is reliable and we indirectly evaluate those quantities inside the bubble. In the present calculation, the line spectra of OH radical at about 310 nm mixing the electron transition with the vibration and rotational bands are considered. The calculation qualitatively consists with the observation, and we expect that with the more precise bubble dynamics model instead of the uniform model employed in the present calculation we may improve the quantitative result.

  6. Wall-collision line broadening of molecular oxygen within nanoporous materials

    SciTech Connect

    Xu, Can T.; Lewander, Maerta; Andersson-Engels, Stefan; Svensson, Tomas; Svanberg, Sune; Adolfsson, Erik

    2011-10-15

    Wall-collision broadening of near-infrared absorption lines of molecular oxygen confined in nanoporous zirconia is studied by employing high-resolution diode-laser spectroscopy. The broadening is studied for pores of different sizes under a range of pressures, providing new insights on how wall collisions and intermolecular collisions influence the total spectroscopic line profile. The pressure series show that wall-collision broadening is relatively more prominent under reduced pressures, enabling sensitive means to probe pore sizes of porous materials. In addition, we show that the total wall-collision-broadened profile strongly deviates from a Voigt profile and that wall-collision broadening exhibits an additive-like behavior to the pressure and Doppler broadening.

  7. Critical tests of line broadening theories by precision measurements

    SciTech Connect

    Glenzer, S.H.

    1996-02-22

    The spectral line profiles of ionized emitters in plasmas play an important role in the calculation of opacity, for short-wavelength laser studies, and for the diagnostics of inertial confinement fusion plasmas. Sophisticated theoretical methods and modeling have been advanced and applied in recent years to calculate spectral line profiles in the limits where broadening by electron collisions or by ion microfield dominates. Here, the authors describe recent measurements of spectral line profiles of a z-pinch experiment employing precision plasma diagnostic techniques. In particular, the electron-collisional-broadened 2s--2p transitions in B{sub III} have been investigated because their line profiles provide an excellent test for electron-impact line shape theories and electron collision strength calculations. Although they find good agreement with semiclassical calculations, a factor of two discrepancy with the most elaborate quantum-mechanical five-state close coupling calculations is observed. They discuss the experimental error estimates of the various measured quantities and show that the observed discrepancy can not be explained by experimental shortcomings. They further discuss measurements of non-isolated spectral lines of some {Delta}n = 1 transitions in C{sub IV}--O{sub VI}. For these transitions ion broadening dominates. Excellent agreement for the whole line profile with line broadening calculations is obtained for all cases only when including ion dynamic effects. The latter are calculated using the frequency-fluctuation model and account for about 10--25% of the line width of the considered ions.

  8. Stark broadening of Kr UV spectral lines

    SciTech Connect

    Cirisan, M.; Djurovic, S.; Pelaez, R. J.; Aparicio, J. A.; Mar, S.

    2011-01-15

    This work reports new data for the Stark parameters of doubly ionized krypton spectral lines. Stark widths and shifts of Kr iii lines belonging to the UV region (245-300 nm) have been measured. A low-pressure pulsed arc, containing a mixture of 8% krypton and 92% helium, was used as a plasma source. Measured electron densities and electron temperatures were in the range (0.7-2.0)x10{sup 23} m{sup -3} and 16 000-20 000 K, respectively. Experimentally obtained data were compared to theoretical results calculated using simplified modified semiempirical formulas.

  9. OBSERVATIONAL EVIDENCE FOR A CORRELATION BETWEEN MACROTURBULENT BROADENING AND LINE-PROFILE VARIATIONS IN OB SUPERGIANTS

    SciTech Connect

    Simon-Diaz, S.; Herrero, A.; Castro, N.; Uytterhoeven, K.; Puls, J.

    2010-09-10

    The spectra of O and B supergiants (Sgs) are known to be affected by a significant form of extra line broadening (usually referred to as macroturbulence) in addition to that produced by stellar rotation. Recent analyses of high-resolution spectra have shown that the interpretation of this line broadening as a consequence of large-scale turbulent motions would imply highly supersonic velocity fields in photospheric regions, making this scenario quite improbable. Stellar oscillations have been proposed as a likely alternative explanation. As part of a long-term observational project, we are investigating the macroturbulent broadening in O and B Sgs and its possible connection with spectroscopic variability phenomena and stellar oscillations. In this Letter, we present the first encouraging results of our project, namely, firm observational evidence for a strong correlation between the extra broadening and photospheric line-profile variations in a sample of 13 Sgs with spectral types ranging from O9.5 to B8.

  10. Stark broadening of hydrogen lines in magnetic fusion plasmas

    NASA Astrophysics Data System (ADS)

    Rosato, J.; Godbert-Mouret, L.; Koubiti, M.; Marandet, Y.; Stamm, R.

    2017-03-01

    We report on a Stark line shape model for the diagnostic of tokamak edge plasmas. In specific scenarios, plasma discharges are carried out at high density regimes, sufficiently so that the spectral lines emitted by the neutral atoms present in the edge and in the divertor region are affected by the plasma microscopic electric field (Stark broadening). We present new line shape calculations, carried out for diagnostic purposes in the context of the MST1 (Medium Sized Tokamak) European campaign. The role of the magnetic field (Zeeman effect) on line spectra is discussed.

  11. Hydrogen Balmer Line Broadening in Solar and Stellar Flares

    NASA Astrophysics Data System (ADS)

    Kowalski, Adam F.; Allred, Joel C.; Uitenbroek, Han; Tremblay, Pier-Emmanuel; Brown, Stephen; Carlsson, Mats; Osten, Rachel A.; Wisniewski, John P.; Hawley, Suzanne L.

    2017-03-01

    The broadening of the hydrogen lines during flares is thought to result from increased charge (electron, proton) density in the flare chromosphere. However, disagreements between theory and modeling prescriptions have precluded an accurate diagnostic of the degree of ionization and compression resulting from flare heating in the chromosphere. To resolve this issue, we have incorporated the unified theory of electric pressure broadening of the hydrogen lines into the non-LTE radiative-transfer code RH. This broadening prescription produces a much more realistic spectrum of the quiescent, A0 star Vega compared to the analytic approximations used as a damping parameter in the Voigt profiles. We test recent radiative-hydrodynamic (RHD) simulations of the atmospheric response to high nonthermal electron beam fluxes with the new broadening prescription and find that the Balmer lines are overbroadened at the densest times in the simulations. Adding many simultaneously heated and cooling model loops as a “multithread” model improves the agreement with the observations. We revisit the three-component phenomenological flare model of the YZ CMi Megaflare using recent and new RHD models. The evolution of the broadening, line flux ratios, and continuum flux ratios are well-reproduced by a multithread model with high-flux nonthermal electron beam heating, an extended decay phase model, and a “hot spot” atmosphere heated by an ultrarelativistic electron beam with reasonable filling factors: ∼0.1%, 1%, and 0.1% of the visible stellar hemisphere, respectively. The new modeling motivates future work to understand the origin of the extended gradual phase emission.

  12. Non-thermal line-broadening in solar prominences

    NASA Astrophysics Data System (ADS)

    Stellmacher, G.; Wiehr, E.

    2015-09-01

    Aims: We show that the line broadening in quiescent solar prominences is mainly due to non-thermal velocities. Methods: We have simultaneously observed a wide range of optically thin lines in quiescent prominences, selected for bright and narrow Mg b emission without line satellites from macro-shifts. Results: We find a ratio of reduced widths, ΔλD/λ0, of Hγ and Hδ of 1.05 ± 0.03, which can hardly be attributed to saturation, since both are optically thin for the prominences observed: τγ ≤ 0.3, τδ ≤ 0.15. We confirm the ratio of reduced widths of He 4772 (triplet) and He 5015 (singlet) of 1.1 ± 0.05 at higher significance and detect a width ratio of Mg b2 and Mg 4571 (both from the triplet system) of 1.3 ± 0.1. Conclusions: The discrepant widths of lines from different atoms, and even from the same atom, cannot be represented by a unique pair [Tkin; Vnth]. Values of Tkin deduced from observed line radiances using models indicate low temperatures down to Tkin ≈ 5000 K. Non-thermal velocities, related to different physical states of the respective emitting prominence region, seem to be the most important line broadening mechanism.

  13. Curves of growth for van der Waals broadened spectral lines

    NASA Technical Reports Server (NTRS)

    Park, C.

    1980-01-01

    Curves of growth are evaluated for a spectral line broadened by the van der Waals interactions during collisions. The growth of the equivalent widths of such lines is shown to be dependent on the product of the perturber density and the 6/10 power of the van der Waals potential coefficient. When the parameter is small, the widths grow as the 1/2 power of the optical depth as they do for the Voigt profile: but when the parameter is large, they grow as 2/3 power and, hence, faster than the Voigt profile. An approximate analytical expression for the computed growth characteristics is given.

  14. Correction for inhomogeneous line broadening in spin labels, II

    NASA Astrophysics Data System (ADS)

    Bales, Barney L.

    Our methods to correct for inhomogeneous line broadening in the EPR of nitroxide spin labels are extended. Previously, knowledge of the hyperfine pattern of the nuclei responsible for the inhomogeneous broadening was necessary in order to carry out the corrections. This normally meant that either a separate NMR experiment or EPR spectral simulation was needed. Here a very simple method is developed, based upon measurement of four points on the experimental EPR spectrum itself, that allows one to carry out the correction procedure with precision rivaling that attained using NMR or spectral simulation. Two associated problems are solved: (1) the EPR signal strength is estimated without the need to carry out double integrations and (2) linewidth ratios, important in calculating rotational correlation times, are corrected. In all cases except one, the corrections are effected from the four measured points using only a hand-held programmable calculator. Experimental examples illustrate the methods and show them to be amazingly accurate.

  15. Standard line broadening impact theory for hydrogen including penetrating collisions

    NASA Astrophysics Data System (ADS)

    Alexiou, S.; Poquérusse, A.

    2005-10-01

    In recent years there has been significant interest in the emission spectra from high-density plasmas, as manifested by a number of experiments. At these high densities short range (small impact parameter) interactions become important and these cannot be adequately handled by the standard theory, whose predictions depend on some cutoffs, necessary to preserve unitarity, the long range approximation, and to ensure the validity of a semiclassical picture. Very recently, as a result of a debate concerning the broadening of isolated ion lines, the importance of penetration of bound electron wave functions by plasma electrons has been realized. By softening the interaction, penetration makes perturbative treatments more valid. The penetration effect has now been included analytically into the standard theory. It turns out that the integrations may be done in closed form in terms of the modified Bessel functions K0 and K1 . This work develops the new theory and applies it to experimental measurements.

  16. Comparing the line broadened quasilinear model to Vlasov code

    NASA Astrophysics Data System (ADS)

    Ghantous, K.; Berk, H. L.; Gorelenkov, N. N.

    2014-03-01

    The Line Broadened Quasilinear (LBQ) model is revisited to study its predicted saturation level as compared with predictions of a Vlasov solver BOT [Lilley et al., Phys. Rev. Lett. 102, 195003 (2009) and M. Lilley, BOT Manual. The parametric dependencies of the model are modified to achieve more accuracy compared to the results of the Vlasov solver both in regards to a mode amplitude's time evolution to a saturated state and its final steady state amplitude in the parameter space of the model's applicability. However, the regions of stability as predicted by LBQ model and BOT are found to significantly differ from each other. The solutions of the BOT simulations are found to have a larger region of instability than the LBQ simulations.

  17. Why Is Non-thermal Line Broadening of Lower Transition Region Lines Independent of Spatial Resolution?

    NASA Astrophysics Data System (ADS)

    De Pontieu, B.; Mcintosh, S. W.; Martínez-Sykora, J.; Peter, H.; Pereira, T. M. D.

    2014-12-01

    Spectral observations of the solar transition region (TR) and corona typically show broadening of the spectral lines beyond what is expected from thermal and instrumental broadening. The remaining non-thermal broadening is significant (10-30 km/s), correlated with the intensity, and has been attributed to waves, macro and micro turbulence, nanoflares, etc... Here we study spectra of the low TR Si IV 1403 Angstrom line obtained at high spatial and spectral resolution with the Interface Region Imaging Spectrograph (IRIS). We find that the large improvement in spatial resolution (0.33 arcsec) of IRIS compared to previous spectrographs (2 arcsec) does not resolve the non-thermal line broadening which remains at pre-IRIS levels of 20 km/s. This surprising invariance to spatial resolution indicates that the physical processes behind the non-thermal line broadening either occur along the line-of-sight (LOS) and/or on spatial scales (perpendicular to the LOS) smaller than 250 km. Both effects appear to play a role. Comparison with IRIS chromospheric observations shows that, in regions where the LOS is more parallel to the field, magneto-acoustic shocks driven from below impact the low TR leading to strong non-thermal line broadening from line-of-sight integration across the shock at the time of impact. This scenario is confirmed by advanced MHD simulations. In regions where the LOS is perpendicular to the field, the prevalence of small-scale twist is likely to play a significant role in explaining the invariance and the correlation with intensity.

  18. Measurements of air-broadened and nitrogen-broadened half-widths and shifts of ozone lines near 9 microns

    NASA Technical Reports Server (NTRS)

    Smith, M. A. H.; Rinsland, C. P.; Devi, Malathy V.; Benner, D. Chris; Thakur, K. B.

    1988-01-01

    Air- and nitrogen-broadened half-widths and line shifts at room temperature for more than 60 individual vibration-rotation transitions in the nu1 fundamental band of (O-16)3 and several transitions in the nu3 band were determined from infrared absorption spectra. These spectra were recorded at 0.005/cm resolution with a Fourier-transform spectrometer. A tunable-diode-laser spectrometer operating in the 1090-1150/cm region was also used to record data on oxygen-, nitrogen-, and air-broadened half-widths for selected individual transitions. The nitrogen- and air-broadened half-widths determined by these two different measurement techniques are consistent to within 4 percent. The results are in good agreement with other published measurements and calculations.

  19. An Experimental and Theoretical Study of Nitrogen-Broadened Acetylene Lines

    NASA Technical Reports Server (NTRS)

    Thibault, Franck; Martinez, Raul Z.; Bermejo, Dionisio; Ivanov, Sergey V.; Buzykin, Oleg G.; Ma, Qiancheng

    2014-01-01

    We present experimental nitrogen-broadening coefficients derived from Voigt profiles of isotropic Raman Q-lines measured in the 2 band of acetylene (C2H2) at 150 K and 298 K, and compare them to theoretical values obtained through calculations that were carried out specifically for this work. Namely, full classical calculations based on Gordon's approach, two kinds of semi-classical calculations based on Robert Bonamy method as well as full quantum dynamical calculations were performed. All the computations employed exactly the same ab initio potential energy surface for the C2H2N2 system which is, to our knowledge, the most realistic, accurate and up-to-date one. The resulting calculated collisional half-widths are in good agreement with the experimental ones only for the full classical and quantum dynamical methods. In addition, we have performed similar calculations for IR absorption lines and compared the results to bibliographic values. Results obtained with the full classical method are again in good agreement with the available room temperature experimental data. The quantum dynamical close-coupling calculations are too time consuming to provide a complete set of values and therefore have been performed only for the R(0) line of C2H2. The broadening coefficient obtained for this line at 173 K and 297 K also compares quite well with the available experimental data. The traditional Robert Bonamy semi-classical formalism, however, strongly overestimates the values of half-width for both Qand R-lines. The refined semi-classical Robert Bonamy method, first proposed for the calculations of pressure broadening coefficients of isotropic Raman lines, is also used for IR lines. By using this improved model that takes into account effects from line coupling, the calculated semi-classical widths are significantly reduced and closer to the measured ones.

  20. Line mixing in H broadening of the Na 3P-3D lines

    NASA Astrophysics Data System (ADS)

    Sanchez-Fortún Stoker, J.; Dickinson, A. S.

    2003-04-01

    Line mixing of the Na 3P-3D lines broadened by atomic hydrogen has been calculated in the impact approximation. The required S-matrix elements are calculated using a time-dependent close-coupling rectilinear-path approximation, the ab initio NaH potentials used by Leininger et al (2000 J. Phys. B: At. Mol. Opt. Phys. 33 1805) being employed. At energies of less than 25 000 cm-1, the real and imaginary parts of the mixing cross sections were found to be about 50 and about 25 times smaller, respectively, than the broadening coefficients, while at about 105 cm-1, the real and imaginary parts were found to be smaller in magnitude by factors of about 200 and 10, respectively. On thermally averaging the cross sections, the line-shape parameters leading to mixing were found to be 50-100 times smaller than the corresponding broadening coefficients for the isolated lines. For a number density of 1016 - 1017 cm-3 and temperature of 6000 K, the mixed and unmixed line shapes were found to deviate by less than 3% over the range of frequencies for which the application of the impact approximation was valid.

  1. Si 6142 and 6155 Å lines in stellar atmospheres: Stark broadening effect

    NASA Astrophysics Data System (ADS)

    Dimitrijević, M. S.; Popović, L. Č.; Ryabchikova, T.

    2002-07-01

    We study the influence of Stark broadening effect on Si I lines in the roAp 10 Aql star, where the lines are asymmetrical and shifted. First we have calculated Stark broadening parameters using by the semi-classical method for two Si I lines: 6142.48 Å and 6155.13 Å. We have adopted SYNTH code to include into account both Stark width and shift for these lines. From comparison of our calculation data with observations we found that Stark broadening plus stratification effect can explain the width and the asymmetry of the Si I lines in the atmosphere of roAp 10 Aql star.

  2. On the Stark Broadening of Single Ionized Argon Lines

    NASA Astrophysics Data System (ADS)

    Dimitrijević, M. S.; Truong-Bach

    1986-06-01

    Using a semi-classical formalism which includes Debye shielding, Stark broadening parameters of various components within the 4 s 2P - 4 p ´ 2P0 multiplet and the 4 p - 4 d (2P 0 - 2P, 2D0 - 2 P, 2D0 - 2D) supermutiplet of Ar II are computed. We show that when various components of a multiplet (supermultiplet or transition array) are broadened inequally by an embedded closelying perturbing level, use of a perturber param eter cut-off at the Debye length can restrain the calculated differences between Stark widths within the multiplet.

  3. A method for measuring magnetic fields in sunspots using Zeeman-broadened absorption lines

    NASA Astrophysics Data System (ADS)

    Oostra, Benjamin

    2017-04-01

    We present measurements of magnetic fields in several sunspots using high-resolution spectra obtained with the ESPARTACO spectrograph at the Universidad de los Andes, with the aim to explore experimental possibilities for students. Because the Zeeman line splitting is smaller than the line width, our work only observes broadened absorption lines. This broadening, however, can be measured and suitably modeled, giving realistic quantitative results.

  4. Line parameters for CO2 broadening in the ν2 band of HD16O

    NASA Astrophysics Data System (ADS)

    Devi, V. Malathy; Benner, D. Chris; Sung, Keeyoon; Crawford, Timothy J.; Gamache, Robert R.; Renaud, Candice L.; Smith, Mary Ann H.; Mantz, Arlan W.; Villanueva, Geronimo L.

    2017-01-01

    CO2-rich planetary atmospheres such as those of Mars and Venus require accurate knowledge of CO2 broadened HDO half-width coefficients and their temperature dependence exponents for reliable abundance determination. Although a few calculated line lists have recently been published on HDO-CO2 line shapes and their temperature dependences, laboratory measurements of those parameters are thus far non-existent. In this work, we report the first measurements of CO2-broadened half-width and pressure-shift coefficients and their temperature dependences for over 220 transitions in the ν2 band. First measurements of self-broadened half-width and self-shift coefficients at room temperature are also obtained for majority of these transitions. In addition, the first experimental determination of collisional line mixing has been reported for 11 transition pairs for HDO-CO2 and HDO-HDO systems. These results were obtained by analyzing ten high-resolution spectra of HDO and HDO-CO2 mixtures at various sample temperatures and pressures recorded with the Bruker IFS-125HR Fourier transform spectrometer at the Jet Propulsion Laboratory (JPL). Two coolable absorption cells with path lengths of 20.38 cm and 20.941 m were used to record the spectra. The various line parameters were retrieved by fitting all ten spectra simultaneously using a multispectrum nonlinear least squares fitting algorithm. The HDO transitions in the 1100-4100 cm-1 range were extracted from the HITRAN2012 database. For the ν2 and 2ν2 -ν2 bands there were 2245 and 435 transitions, respectively. Modified Complex Robert-Bonamy formalism (MCRB) calculations were made for the half-width coefficients, their temperature dependence and the pressure shift coefficients for the HDO-CO2 and HDO-HDO collision systems. MCRB calculations are compared with the measured values.

  5. Collisional broadening of CO2 IR lines. II. Calculations

    NASA Astrophysics Data System (ADS)

    Rosenmann, L.; Hartmann, J. M.; Perrin, M. Y.; Taine, J.

    1988-03-01

    The ability of available theoretical models in describing broadening mechanisms is tested for the CO2-O2, CO2-CO2, and CO2-N2 systems. It is shown that the Anderson-Tsao-Curnutte theory is inaccurate since short-range forces can contribute significantly to broadening. We use the approach of Robert and Bonamy, but the usual expansion of the atom-atom potential to the fourth order around the intermolecular distance appears insufficient at short distances for these particular systems. We propose a better representation of the radial dependence of the atom-atom potential, while keeping the previous analytical expression of the cross section. Satisfactory results are obtained for both the rotational quantum number dependence of room-temperature CO2-O2, CO2-CO2, and CO2-N2 half-widths and the evolution of CO2-N2 broadening with temperature. It is shown that the isotropic part of the potential involved in the trajectory calculation must be coherently deduced from the atom-atom interaction potential.

  6. Magnetic Turbulence and Line Broadening in Simulations of Lyman-Alpha Absorption

    NASA Astrophysics Data System (ADS)

    Gurvich, Alex; Burkhart, Blakesley K.; Bird, Simeon

    2016-01-01

    We use the Illustris cosmological AREPO simulations to study the effects of gas turbulence and magnetic fields on measurements from the Lyman-Alpha forest. We generate simulated Lyman-Alpha spectra and plot the distributions of Column Density (CDD) and Doppler Width (b) both by adhering to the canonical method of fitting Voigt profiles to absorption lines and by directly measuring the column density and equivalent widths from snapshot data .We investigate the effects of additional unresolved gas turbulence in Illustris by adding an additional broadening term to the line profiles to mimic turbulent broadening. When we do this, we find a measurable effect in the CDD and an offset in the mean of the b distribution corresponding to the additional turbulence. We also compare different MHD runs in AREPO we find that the CDD can measurably differentiate between magnetic seed field at redshifts as low as z=0.1, but we do not find that the b distribution is affected at a detectable level. Our work suggests that the effects of turbulence and magnetic fields from z=2-0.1 can potentially be measured with these diagnostics. This work was supported in part by the NSF REU and DoD ASSURE programs under NSF grant no. 1262851 and by the Smithsonian Institution.

  7. Experimental and Theoretical Studies of Pressure Broadened Alkali-Metal Atom Resonance Lines

    NASA Technical Reports Server (NTRS)

    Shindo, F.; Zhu, C.; Kirby, K.; Babb, J. F.

    2006-01-01

    We are carrying out a joint theoretical and experimental research program to study the broadening of alkali atom resonance lines due to collisions with helium and molecular hydrogen for applications to spectroscopic studies of brown dwarfs and extrasolar giant planets.

  8. Measurements of H2O-broadening coefficients of O2 A-band lines

    NASA Astrophysics Data System (ADS)

    Delahaye, T.; Landsheere, X.; Pangui, E.; Huet, F.; Hartmann, J.-M.; Tran, H.

    2016-11-01

    We report laboratory measurements of H2O-broadening coefficients of O2 absorption lines in the A-band near 13,000 cm-1. For this, four spectra of oxygen gas mixed with water vapor were recorded with a high resolution Fourier transform spectrometer for total pressures ranging from 125 to 175 Torr at 323 K, and a fifth at 175 Torr and 365 K. Broadening coefficients of 39 transitions (up to J″ = 21) were retrieved from the measured spectra through fits using Galatry line profiles. Values at room temperature (296 K) were then extrapolated and compared with previous determinations in the A-band and millimeter waves region. This enables to resolve some controversial issues related to the inconsistencies between these studies. Finally, comparing our results with the line broadening coefficients by dry air confirms that H2O-broadenings of oxygen lines are, on average, 10% larger than those by dry air.

  9. Gain and Raman line-broadening with graphene coated diamond-shape nano-antennas.

    PubMed

    Paraskevaidis, Charilaos; Kuykendall, Tevye; Melli, Mauro; Weber-Bargioni, Alexander; Schuck, P James; Schwartzberg, Adam; Dhuey, Scott; Cabrini, Stefano; Grebel, Haim

    2015-10-07

    Using Surface Enhanced Raman Scattering (SERS), we report on intensity-dependent broadening in graphene-deposited broad-band antennas. The antenna gain curve includes both the incident frequency and some of the scattered mode frequencies. By comparing antennas with various gaps and types (bow-tie vs. diamond-shape antennas) we make the case that the line broadening did not originate from strain, thermal or surface potential. Strain, if present, further shifts and broadens those Raman lines that are included within the antenna gain curve.

  10. The influence of Stark broadening on Cr II spectral line shapes in stellar atmospheres

    NASA Astrophysics Data System (ADS)

    Dimitrijević, M. S.; Ryabchikova, T.; Simić, Z.; Popović, L. Č.; Dačić, M.

    2007-07-01

    Aims:We consider the effect of Stark broadening on the shapes of Cr ii spectral lines observed in stellar atmospheres of the middle part of the main sequence. Methods: Stark broadening parameters were calculated by the semiclassical perturbation approach. For stellar spectra synthesis, the improved version synth3 of the code synth for synthetic spectrum calculations was used. Results: Stark broadening parameters for Cr ii spectral lines of seven multiplets belonging to 4s-4p transitions were calculated. New calculated Stark parameters were applied to the analysis of Cr ii line profiles observed in the spectrum of Cr-rich star HD 133792. Conclusions: We found that Stark broadening mechanism is very important and should be taken into account, especially in the study of Cr abundance stratification.

  11. Role of Lorentz-Stark broadening of hydrogen spectral lines in magnetized plasmas: Applications to magnetic fusion and solar physics

    NASA Astrophysics Data System (ADS)

    Oks, Eugene

    2015-05-01

    Broadening of hydrogen spectral lines in plasmas is an important diagnostic tool for many applications (here and below by "hydrogen atoms" and "hydrogen spectral lines" we mean atoms and spectral lines of hydrogen, deuterium, and tritium). In magnetized plasmas radiating hydrogen atoms moving with the velocity v across the magnetic field B experience a Lorentz electric field EL=v×B/c in addition to other electric fields. Since the velocity v has a distribution, so does the Lorentz field, thus making an additional contribution to the broadening of spectral lines. Compared to previous studies of this contribution, we cover the following new aspects. First, we consider the Lorentz-Doppler broadening of highly-excited hydrogen lines and produce new analytical results for arbitrary strength of the magnetic field B. We show for the first time that in the high-B case, the π-components of hydrogen lines are significantly suppressed compared to the σ-components. Second, we derive analytically Lorentz-broadened profiles of highly-excited hydrogen lines. We obtain expressions for the principal quantum number nmax of the last observable hydrogen line in the spectral series. These expressions differ very significantly from the corresponding Inglis-Teller result and constitute a new diagnostic method allowing to measure the product T1/2B, where T is the atomic temperature. Third, we consider magnetized plasmas containing a low-frequency electrostatic turbulence. This kind of turbulence causes anomalous transport phenomena (e.g., the anomalous resistivity) and is therefore very important to be diagnosed. We derive analytically distributions of the total electric field and the corresponding Stark profiles of hydrogen lines. We demonstrate that our findings lead to a significantly revised interpretation of the previous and future experimental data in magnetic fusion and the observational data in solar physics.

  12. Theoretical effect of various broadening parameters on ultraviolet line profiles

    NASA Technical Reports Server (NTRS)

    Peytremann, E.

    1972-01-01

    The relative importance of various damping parameters in ultraviolet lines under conditions of normal stellar atmospheres are studied. It is found that the damping by electron collisions is always much smaller than either the radiative or the classical damping, except for lines that arise from high excitation levels and do not therefore develop strong damping wings. A damping constant equal to 10 times the classical value is always much too large when compared to the more realistic (electron + radiative) damping.

  13. SUPERSONIC LINE BROADENING WITHIN YOUNG AND MASSIVE SUPER STAR CLUSTERS

    SciTech Connect

    Tenorio-Tagle, Guillermo; Silich, Sergiy; Wuensch, Richard; Munoz-Tunon, Casiana; Palous, Jan E-mail: richard@wunsch.c E-mail: cmt@ll.iac.e

    2010-01-10

    The origin of supersonic infrared and radio recombination nebular lines often detected in young and massive superstar clusters is discussed. We suggest that these arise from a collection of repressurizing shocks (RSs), acting effectively to re-establish pressure balance within the cluster volume and from the cluster wind which leads to an even broader although much weaker component. The supersonic lines here are shown to occur in clusters that undergo a bimodal hydrodynamic solution, that is within clusters that are above the threshold line in the mechanical luminosity or cluster mass versus the size of the cluster plane. A plethora of RSs is due to frequent and recurrent thermal instabilities that take place within the matter reinserted by stellar winds and supernovae. We show that the maximum speed of the RSs and of the cluster wind are both functions of the temperature reached at the stagnation radius. This temperature depends only on the cluster heating efficiency (eta). Based on our two-dimensional simulations we calculate the line profiles that result from several models and confirm our analytical predictions. From a comparison between the predicted and observed values of the half-width zero intensity of the two line components, we conclude that the thermalization efficiency in young super star clusters above the threshold line must be lower than 20%.

  14. N 2- and O 2-broadening coefficients of C 2H 2 IR lines

    NASA Astrophysics Data System (ADS)

    Bouanich, J. P.; Lambot, D.; Blanquet, G.; Walrand, J.

    1990-04-01

    Pressure-broadening parameters of six lines belonging to the ν5 band of C 2H 2 in collision with N 2 have been measured with a tunable diode-laser spectrometer in order to complete up to J = 33 our earlier measurements (D. Lambot, G. Blanquet, and J. P. Bouanich, J. Mol. Spectrosc.136, 86-92 (1989)) on the broadening of C 2H 2 by N 2 and O 2 at 297 K. These N 2- and O 2-broadening coefficients have been first calculated on the basis of the Anderson-Tsao-Curnutte theory; in this approach, we show that the short-range interactions which contribute significantly to the linewidths are not correctly treated. Next, we consider the improved semiclassical model proposed by Robert and Bonamy. The intermolecular potential consists in the addition of the atom-atom interaction model to the quadrupolar interactions. The limited radial spherical harmonics expansion of the atom-atom potential, from which expressions for the differential cross section were derived, appears to be quite insufficient at short intermolecular distances. Therefore, we use a more accurate representation of this potential, avoiding an inadequate truncation and keeping the analytic expressions obtained by Bonamy and Robert. In the calculations we take into account the contributions derived from the radial functions U000( r), U200( r), and U220( r), as well as from U400( r). A theoretical expression is obtained for the U400 contribution to the differential cross section. The results of the calculations arising from the exact radial expansion of the atom-atom potential appear to be significantly larger for high J lines than those arising from the truncated expansion. The latter results, which do not include adjustable atom-atom parameters, are in good agreement with experimental broadening coefficients for C 2H 2O 2 and in reasonable agreement (except at large J values) for C 2H 2N 2. It is also shown that the contributions to the linewidths derived from U400 are rather small for C 2H 2N 2 and more

  15. Broadening of the spectral lines of a buffer gas and target substance in laser ablation

    SciTech Connect

    Kask, Nikolai E; Michurin, Sergei V

    2012-11-30

    The broadening of discrete spectral lines from the plasma produced in the laser ablation of metal targets in a broad pressure range (10{sup 2} - 10{sup 7} Pa) of the ambient gas (Ar, He, H{sub 2}) was studied experimentally. The behaviour of spectral line broadening for the buffer gases was found to be significantly different from that for the atoms and ions of the target material. In comparison with target atoms, the atoms of buffer gases radiate from denser plasma layers, and their spectral line profiles are complex in shape. (interaction of laser radiation with matter. laser plasma)

  16. Absorption Spectra of Broadened Sodium Resonance Lines in Presence of Rare Gases

    SciTech Connect

    Chung, H-K; Shurgalin, M; Babb, J F

    2002-09-11

    The pressure broadening of alkali-metal lines is a fundamental problem with numerous applications. For example, the sodium resonance lines broadened by xenon are important in the production of broad spectra emitted in the HPS (High-Pressure Sodium) lamp and they potentially can be used for gas condition diagnostics. Broadened absorption lines of alkali-metal atoms are prominent in the optical spectra of brown dwarfs and understanding the broadening mechanism will help elucidate the chemical composition and atmospheric properties of those stars. The far-line wing spectra of sodium resonance lines broadened by rare gases are found to exhibit molecular characteristics such as satellites and hence the total absorption coefficients for vapors of Na atoms and perturbing rare gas atoms can be modeled as Na-RG (rare gas) molecular absorption spectra. In this work, using carefully chosen interatomic potentials for Na-RG molecules we carry out quantum-mechanical calculations for reduced absorption coefficients for vapors composed of Na-He, Na-Ar, and Na-Xe. Calculated spectra are compared to available experimental results and the agreement is good in the measured satellite positions and shapes.

  17. Variable rotational line broadening in the Be star Achernar

    NASA Astrophysics Data System (ADS)

    Rivinius, Th.; Baade, D.; Townsend, R. H. D.; Carciofi, A. C.; Štefl, S.

    2013-11-01

    Aims: The main theoretical problem for the formation of a Keplerian disk around Be stars is how angular momentum is supplied from the star to the disk, even more so since Be stars probably rotate somewhat subcritically. For instance, nonradial pulsation may transport angular momentum to the stellar surface until (part of) this excess supports the disk-formation/replenishment. The nearby Be star Achernar is presently building a new disk and offers an excellent opportunity to observe this process from relatively close-up. Methods: Spectra from various sources and epochs are scrutinized to identify the salient stellar parameters characterizing the disk life cycle as defined by Hα emission. The variable strength of the non-radial pulsation is confirmed, but does not affect the other results. Results: For the first time it is demonstrated that the photospheric line width does vary in a Be star, by as much as Δv sini ≲ 35 km s-1. However, unlike assumptions in which a photospheric spin-up accumulates during the diskless phase and then is released into the disk as it is fed, the apparent photospheric spin-up is positively correlated with the appearance of Hα line emission. The photospheric line widths and circumstellar emission increase together, and the apparent stellar rotation declines to the value at quiescence after the Hα line emission becomes undetectable. Based on observations collected at the European Southern Observatory at La Silla and Paranal, Chile, Prog. IDs: 62.H-0319, 64.H-0548, 072.C-0513, 073.C-0784, 074.C-0012, 073.D-0547, 076.C-0431, 077.D-0390, 077.D-0605, and the technical program IDs 60.A-9120 and 60.A-9036.Appendices are available in electronic form at http://www.aanda.org

  18. Pressure Broadening of the Cadmium 326.1 nm Line

    NASA Astrophysics Data System (ADS)

    Roston, G. D.; Helmi, M. S.

    2014-11-01

    The temperature dependence of the Cd line absorption profile at 326.1nm perturbed by inert gases (Xe, Kr, Ar, Ne and He) has been carefully studied over a wide spectral range in both blue and red wings using a high-resolution double-beam spectrometer. The atomic densities of inert gases (Ngas) and cadmium (NCd) was sufficient to study the wing of the Cd line at 326.1nm. The temperature dependence of the studied line profile was analyzed in the framework of the quasi-static theory. The van der Waals coefficient differences (ΔC60 and ΔC61) between the ground X0+ state and the two excited states A30+ and B31 were obtained from the near red wing profile using Kuhn's law. All the results of the well depths with their positions for the ground (X0+), and the excited (31, 30+) were determined. The obtained results are compared with the corresponding theoretical and experimental molecular beam experiments results.

  19. Study of ion line broadening in the Tormac discharge

    SciTech Connect

    Shaw, R.S.

    1980-07-01

    Tormac (Toroidal Magnetic Cusp) is a magnetic confinement plasma concept having absolute minimum-B geometry. Two versions of Tormac are considered here. Tormac T IV-c has a glass vessel of rectangular cross section, 0.5 m in diameter. The confinement field rises to approx. 4.5 kG in approx. 8.3 ..mu..sec. Tormac T V has a T-shaped glass vessel, 1 m in diameter, with a field of approx. 3 kG, rising in approx. 10 ..mu..sec. Gaussian HeII 4686 A spectral lines having full widths at half maximum over 2 A have been observed in both Tormac plasmas.

  20. Broadening and shift of the spectral lines of hydrogen atoms and silicon ions in laser plasma

    SciTech Connect

    Kask, N E; Leksina, E G; Michurin, S V; Fedorov, G M; Chopornyak, D B

    2015-06-30

    We report an experimental investigation of the broadening and shift of discrete lines in the plasma spectrum produced in the laser ablation of silicon in a broad pressure range (10{sup 2} – 10{sup 7} Pa) of the ambient gas (Ar, He, H{sub 2}). The broadening and line shifts are measured in relation to the distance from the target and initial gas pressure. The threshold nature of the resulting dependences is found to be related to the formation of virtual percolation clusters proceeding in the hot dense plasma. (laser plasma)

  1. Argon-broadened line parameters in the ν3 band of 12CH4.

    NASA Astrophysics Data System (ADS)

    Gabard, T.

    1997-02-01

    Prompted by improved measurements of collisional line shapes in the ν3 band P, Q and R branches of 12CH4, The author has performed semi-classical line broadening calculations for methane perturbed by argon. He has used the theoretical approach developed by Robert and Bonamy (1979) as an extension of the well-known Anderson-Tsao-Curnutte theory. The semi-classical theory as reformulated here is shown to fully account for the tetrahedral symmetry of methane type molecules. The variation of argon-broadened linewidth coefficients in the ν3 band of 12CH4 with the branch, J, symmetry and energy level fine structure is discussed.

  2. Improved electron collisional line broadening for low-temperature ions and neutrals in plasma modeling

    DOE PAGES

    Johns, H. M.; Kilcrease, D. P.; Colgan, J.; ...

    2015-09-29

    In this study, electron collisional broadening of observed spectral lines depends on plasma electron temperature and density. Including this effect in models of measured spectra is necessary to determine plasma conditions; however, computational limits make accurate line broadening treatments difficult to implement in large-scale plasma modeling efforts. In this paper, we report on improvements to the treatment of electron collisional line broadening and illustrate this with calculations using the Los Alamos ATOMIC code. We implement the Dimitrijevic and Konjevic modified semi-empirical model Dimitrijevic and Konjevic (1986 Astron. and Astrophy. 163 297 and 1987 Astron. Astrophys. 172 345), which we amendmore » by employing oscillator strengths from Hartree–Fock calculations. This line broadening model applies to near-neutral plasmas with electron temperatures of Te ~ 1 eV and electron densities of Ne ~1017 cm-3. We evaluate the D.K.-inspired model against the previous hydrogenic approach in ATOMIC through comparison to NIST-rated measurements for selected neutral and singly-ionized Ca, O, Fe, and Sn lines using both fine-structure and configuration-averaged oscillator strengths. The new D.K.-inspired model is significantly more accurate than the previous hydrogenic model and we find the use of configuration-averaged oscillator strengths a good approximation for applications such as LIBS (laser induced breakdown spectroscopy), for which we demonstrate the use of the D.K.-inspired model.« less

  3. Improved electron collisional line broadening for low-temperature ions and neutrals in plasma modeling

    SciTech Connect

    Johns, H. M.; Kilcrease, D. P.; Colgan, J.; Judge, E. J.; Barefield II, J. E.; Wiens, R. C.; Clegg, S. M.

    2015-09-29

    In this study, electron collisional broadening of observed spectral lines depends on plasma electron temperature and density. Including this effect in models of measured spectra is necessary to determine plasma conditions; however, computational limits make accurate line broadening treatments difficult to implement in large-scale plasma modeling efforts. In this paper, we report on improvements to the treatment of electron collisional line broadening and illustrate this with calculations using the Los Alamos ATOMIC code. We implement the Dimitrijevic and Konjevic modified semi-empirical model Dimitrijevic and Konjevic (1986 Astron. and Astrophy. 163 297 and 1987 Astron. Astrophys. 172 345), which we amend by employing oscillator strengths from Hartree–Fock calculations. This line broadening model applies to near-neutral plasmas with electron temperatures of Te ~ 1 eV and electron densities of Ne ~1017 cm-3. We evaluate the D.K.-inspired model against the previous hydrogenic approach in ATOMIC through comparison to NIST-rated measurements for selected neutral and singly-ionized Ca, O, Fe, and Sn lines using both fine-structure and configuration-averaged oscillator strengths. The new D.K.-inspired model is significantly more accurate than the previous hydrogenic model and we find the use of configuration-averaged oscillator strengths a good approximation for applications such as LIBS (laser induced breakdown spectroscopy), for which we demonstrate the use of the D.K.-inspired model.

  4. Line broadening interference for high-resolution nuclear magnetic resonance spectra under inhomogeneous magnetic fields

    SciTech Connect

    Wei, Zhiliang; Yang, Jian; Lin, Yanqin E-mail: chenz@xmu.edu.cn; Chen, Zhong E-mail: chenz@xmu.edu.cn; Chen, Youhe

    2015-04-07

    Nuclear magnetic resonance spectroscopy serves as an important tool for analyzing chemicals and biological metabolites. However, its performance is subject to the magnetic-field homogeneity. Under inhomogeneous fields, peaks are broadened to overlap each other, introducing difficulties for assignments. Here, we propose a method termed as line broadening interference (LBI) to provide high-resolution information under inhomogeneous magnetic fields by employing certain gradients in the indirect dimension to interfere the magnetic-field inhomogeneity. The conventional spectral-line broadening is thus interfered to be non-diagonal, avoiding the overlapping among adjacent resonances. Furthermore, an inhomogeneity correction algorithm is developed based on pattern recognition to recover the high-resolution information from LBI spectra. Theoretical deductions are performed to offer systematic and detailed analyses on the proposed method. Moreover, experiments are conducted to prove the feasibility of the proposed method for yielding high-resolution spectra in inhomogeneous magnetic fields.

  5. Line broadening interference for high-resolution nuclear magnetic resonance spectra under inhomogeneous magnetic fields.

    PubMed

    Wei, Zhiliang; Yang, Jian; Chen, Youhe; Lin, Yanqin; Chen, Zhong

    2015-04-07

    Nuclear magnetic resonance spectroscopy serves as an important tool for analyzing chemicals and biological metabolites. However, its performance is subject to the magnetic-field homogeneity. Under inhomogeneous fields, peaks are broadened to overlap each other, introducing difficulties for assignments. Here, we propose a method termed as line broadening interference (LBI) to provide high-resolution information under inhomogeneous magnetic fields by employing certain gradients in the indirect dimension to interfere the magnetic-field inhomogeneity. The conventional spectral-line broadening is thus interfered to be non-diagonal, avoiding the overlapping among adjacent resonances. Furthermore, an inhomogeneity correction algorithm is developed based on pattern recognition to recover the high-resolution information from LBI spectra. Theoretical deductions are performed to offer systematic and detailed analyses on the proposed method. Moreover, experiments are conducted to prove the feasibility of the proposed method for yielding high-resolution spectra in inhomogeneous magnetic fields.

  6. N2 pressure - broadened O3 line widths and strengths near 1129.4 cm-1

    NASA Technical Reports Server (NTRS)

    Copeland, G. E.; Majorana, L. N.; Harward, C. N.; Steinkamp, R. J.

    1982-01-01

    A Beer's Law experiment was performed with a tunable diode laser to find the N2 pressure broadening characteristics of a single 03 absorption line at 1129.426 cm for N2 pressures from 10 to 100 torr (O3 pressure = 3.16 torr). SO2 line positions were used for wavelength calibration. Line shapes were interatively fitted to a Lorentz function. Results were delta (HWHM in MHz) = 47.44 (+ or - 5.34) MHz + 1.730 (+ or - 0.088) MHz/torr *p(torr) with sigma = 0.9897. This intercept compares well with the Doppler O3 - O3 broadened (at 3.16 torr) width of 44.52 Hz. This result in a HWHM line width of 0.44 cm atm at 760 torr and 285 K. The line strengths integrated over delta nu = 0.55 cm were found to be N2 pressure dependent.

  7. Water absorption lines, 931-961 nm - Selected intensities, N2-collision-broadening coefficients, self-broadening coefficients, and pressure shifts in air

    NASA Technical Reports Server (NTRS)

    Giver, L. P.; Gentry, B.; Schwemmer, G.; Wilkerson, T. D.

    1982-01-01

    Intensities were measured for 97 lines of H2O vapor between 932 and 961 nm. The lines were selected for their potential usefulness for remote laser measurements of H2O vapor in the earth's atmosphere. The spectra were obtained with several different H2O vapor abundances and N2 broadening gas pressures; the spectral resolution was 0.046/cm FWHM. Measured H2O line intensities range from 7 x 10 to the -25th to 7 x 10 to the -22nd/cm per (molecules/sq cm). H2O self-broadening coefficients were measured for 13 of these strongest lines; the mean value was 0.5/cm per atm. N2-collision-broadening coefficients were measured for 73 lines, and the average was 0.11 cm per atm HWHM. Pressure shifts in air were determined for a sample of six lines between 948 and 950 nm; these lines shift to lower frequency by an amount comparable to 0.1 of the collision-broadened widths measured in air or N2. The measured intensities of many lines of 300-000 band are much larger than expected from prior computations, in some cases by over an order of magnitude. Coriolis interactions with the stronger 201-000 band appear to be the primary cause of the enhancement of these line intensities.

  8. Theoretical Studies of Laser-Induced Molecular Rate Processes: Topics in Line Broadening and Spectroscopy.

    DTIC Science & Technology

    1985-10-01

    GROUP SU. GRF. MOLECULAR RATE PROCESSES MOLECULAR DYNAMICS LASER-INDUCED LINE BROADENING THEORETICAL STUDIES SPECTROSCOPY 19. ABSI*ACT (Continue On...approaches half the band-gap energy. -q 14 This idea of using a laser to "charge" the surface region has fomed the basis of a semiclassical theory of charge

  9. Stark broadening of heavy metal spectral lines in atmospheres of chemically peculiar stars

    NASA Astrophysics Data System (ADS)

    Simić, Zoran

    2010-11-01

    Data on the Stark broadening of heavy metal spectral lines are of interest not only for laboratory but also for astrophysical plasma research as e.g. for stellar spectra analysis and synthesis. Here, we investigated theoretically the influence of collisions with charged particles on heavy metal spectral line profiles for Te I, Cr II, Mn II, Au II, Cu III, Zn III, Se III, In III and Sn III in spectra of A stars and white dwarfs. We applied semiclassical theory of Sahal-Bréchot since the most of published results in literature until now are determined using this method. When it can not be applied in an adequate way, due to the lack of reliable atomic data, we used modified semiempirical theory of Dimitrijević & Konjević, Dimitrijević & Kršljanin. Stark broadening parameters, widths and shifts, were obtained for spectral lines of neutral emitter Te I, singly charged emitters Cr II, Mn II and Au II and doubly charged emitters Cu III, Zn III, Se III, In III and Sn III. We considered as well the contributions of different collision processes to the total Stark width in comparison with Doppler one. In this case we obtained contributions for elastic, strong and inelastic collisions for upper and lower levels. For example, chromium lines are interesting due to their presence in stellar atmospheres, so that they give possibility to determine chromium abundance and investigate chromium stratification in stelar atmospheres and to be used for the diagnostics of stellar plasma and for more refined synthesis of stellar spectra. We consider the effect of Stark broadening on the shapes of Cr II spectral lines observed in the spectra of stars in the middle part of the main sequence. Stark broadening parameters were calculated by the semiclassical perturbation approach. For stellar spectra synthesis, the improved version SYNTH3 of the code SYNTH for synthetic spectrum calculations was used. Stark broadening parameters for Cr II spectral lines of seven multiplets belonging to 4s

  10. A mode-coupling theory of vibrational line broadening in near-critical fluids.

    PubMed

    Egorov, S A; Lawrence, C P; Skinner, J L

    2005-04-14

    We present a fully microscopic mode-coupling theory of near-critical line broadening. All the structural and dynamical input required by the theory is calculated directly from intermolecular potentials. We compute vibrational frequency time-correlation functions and line shapes as the critical point is approached along both the critical isochore and the liquid-gas coexistence curve. Theory is shown to be in good agreement with simulation.

  11. On spectral line Stark broadening parameters needed for stellar and laboratory plasma investigations.

    NASA Astrophysics Data System (ADS)

    Dimitrijević, M. S.

    1995-03-01

    This paper presents a review of semiclassical calculations of Stark broadening parameters and a comparison of different semiclassical procedures is discussed, as well as the agreement with critically selected experimental data and more sophisticated, close coupling calculations. Approximate methods for the calculation of Stark broadening parameters, useful especially in such astrophysical problems where large scale calculations and analyses must be performed and where a good average accuracy is expected, have also been discussed. The beginning and development of line shapes investigations in Yugoslavia has been described as well.

  12. Studies of Pressure-Broadening of Alkali Atom Resonance Lines for Modeling Atmospheres of Extrasolar Giant Planets and Brown Dwarfs

    NASA Technical Reports Server (NTRS)

    Kirby, Kate; Babb, J.; Yoshino, K.

    2004-01-01

    In L-dwarfs and T-dwarfs the resonance lines of sodium and potassium are so profoundly pressure-broadened that their wings extend several hundred nanometers from line center. With accurate knowledge of the line profiles as a function of temperature and pressure: such lines can prove to be valuable diagnostics of the atmospheres of such objects. We have initiated a joint program of theoretical and experimental research to study the line-broadening of alkali atom resonance lines due to collisions with species such as helium and molecular hydrogen. Although potassium and sodium are the alkali species of most interest in the atmospheres of cool brown dwarfs and extrasolar giant planets, some of our theoretical focus this year has involved the calculation of pressure-broadening of lithium resonance lines by He, as a test of a newly developed suite of computer codes. In addition, theoretical calculations have been carried out to determine the leading long range van der Waals coefficients for the interactions of ground and excited alkali metal atoms with helium atoms, to within a probable error of 2%. Such data is important in determining the behavior of the resonance line profiles in the far wings. Important progress has been made on the experimental aspects of the program since the arrival of a postdoctoral fellow in September. A new absorption cell has been designed, which incorporates a number of technical improvements over the previous cell, including a larger cell diameter to enhance the signal, and fittings which allow for easier cleaning, thereby significantly reducing the instrument down-time.

  13. Electron Broadening of Isolated Lines with Stationary Non-Equilibrium Level Populations

    SciTech Connect

    Iglesias, C A

    2005-01-12

    It is shown that a quantum kinetic theory approach to line broadening, extended to stationary non-equilibrium states, yields corrections to the standard electron impact widths of isolated lines that depend on the population of the radiator internal levels. A consistent classical limit from a general quantum treatment of the perturbing electrons also introduces corrections to the isolated line widths. Both effects are essential in preserving detailed-balance relations. Preliminary analysis indicates that these corrections may resolve existing discrepancies between theoretical and experimental widths of isolated lines. An experimental test of the results is proposed.

  14. He-broadening and shift coefficients of water vapor lines in infrared spectral region

    NASA Astrophysics Data System (ADS)

    Petrova, T. M.; Solodov, A. M.; Solodov, A. A.; Deichuli, V. M.; Starikov, V. I.

    2015-11-01

    The water vapor line broadening and shift coefficients in the ν1+ν2, ν2+ν3, ν1+ν3, 2ν3, 2ν1, 2ν2+ν3, and ν1+2ν2 vibrational bands induced by helium pressure were measured using a Bruker IFS 125HR spectrometer. The vibrational bands 2ν3 and ν1+2ν2 were investigated for the first time. The interaction potential used in the calculations of broadening and shift coefficients was chosen as the sum of pair potentials, which were modeled by the Lennard-Jones (6-12) potentials. The vibrational and rotational contributions to this potential were obtained by use of the intermolecular potential parameters and intramolecular parameters of H2O molecule. The calculated values of the broadening and shift coefficients were compared with the experimental data.

  15. Line intensities and collisional-broadening parameters for the nu4 and nu6 bands of carbonyl fluoride

    NASA Technical Reports Server (NTRS)

    May, Randy D.

    1992-01-01

    Line intensities, air- and self-broadening parameters have been measured for selected lines in the nu4 (1243/cm) and nu6 (774/cm) bands of carbonyl fluoride at 296 and 215 K using a tunable diode-laser spectrometer. Measured line intensities are in good agreement +/- 6 percent with recently reported values derived from rotational analyses of the nu4 and nu6 bands. The measured average air-broadening coefficient at 296 K also agrees well (+/- 5 percent) with N2-broadening coefficients determined from microwave studies, while the average self-broadening coefficient reported here is smaller than a previously reported value by 45 percent.

  16. Stark Broadening Of Heavy Metal Spectral Lines In Atmospheres Of Chemically Peculiar Stars

    NASA Astrophysics Data System (ADS)

    Simic, Z.

    2010-07-01

    Data on the Stark broadening of heavy metal spectral lines are of interest not only for laboratory but also for astrophysical plasma research as e.g. for stellar spectra analysis and synthesis. Here, we investigated theoretically the influence of collisions with charged particles on heavy metal spectral line profiles for Te I, Cr II, Mn II, Au II, Cu III, Zn III, Se III, In III and Sn III in spectra of A stars and white dwarfs. We applied semiclassical theory of Sahal-Bréchot since the most of published results in literature until now are determined using this method. When it can not be applied in an adequate way, due to the lack of reliable atomic data, we used modified semiempirical theory of Dimitrijevic & Konjevic, Dimitrijevic & Králjanin. Stark broadening parameters, widths and shifts, were obtained for spectral lines of neutral emitter Te I, singly charged emitters Cr II, Mn II and Au II and doubly charged emitters Cu III, Zn III, Se III, In III and Sn III. We considered as well the contributions of different collision processes to the total Stark width in comparison with Doppler one. In this case we obtained distributions for elastic, strong, inelastic collisions from upper and lower levels. For example, chromium lines are interesting due to their presence in stellar atmospheres, so that they give possibility to determine chromium abundance and investigate chromium stratification in stelar atmospheres and to be used for the diagnostics of stellar plasma and for more rafined synthesis of stellar spectra. We consider the effect of Stark broadening on the shapes of Cr II spectral lines observed in the spectra of stars in the middle part of the main sequence. Stark broadening parameters were calculated by the semic- lassical perturbation approach. For stellar spectra synthesis, the improved version SYNTH3 of the code SYNTH for synthetic spectrum calculations was used. Stark broadening parameters for Cr II spectral lines of seven multiplets belonging to 4s-4p

  17. Spectroscopic study of unique line broadening and inversion in low-pressure microwave generated water plasmas

    NASA Astrophysics Data System (ADS)

    Mills, R. L.; Ray, P. C.; Mayo, R. M.; Nansteel, M.; Dhandapani, B.; Phillips, J.

    2005-12-01

    It was demonstrated that low pressure (˜0.2 torr) water vapor plasmas generated in a 10 mm inner diameter quartz tube with an Evenson microwave cavity show at least two features that are not explained by conventional plasma models. First, significant (gt2.5Å) hydrogen Balmer alpha line broadening, of constant width, up to 5 cm from the microwave coupler was recorded. Only hydrogen, and not oxygen, showed significant line broadening. This feature, observed previously in hydrogen-containing mixed gas plasmas generated with high voltage dc and rf discharges, was explained by some researchers as resulting from acceleration of hydrogen ions near the cathode. This explanation cannot apply to the line broadening observed in the (electrodeless) microwave plasmas generated in this work, particularly at distances as great as 5 cm from the microwave coupler. Second, inversion of the line intensities of both the Lyman and Balmer series, again at distances up to 5 cm from the coupler, were observed. The line inversion suggests the existence of a hitherto unknown source of pumping of the optical power in plasmas. Finally, it is notable that other aspects of the plasma including the OH* rotational temperature and low electron concentrations are quite typical of plasmas of this type.

  18. X-Ray Diffraction Line Broadening: Modeling and Applications to High-Tc Superconductors

    PubMed Central

    Balzar, Davor

    1993-01-01

    A method to analyze powder-diffraction line broadening is proposed and applied to some novel high-Tc superconductors. Assuming that both size-broadened and strain-broadened profiles of the pure-specimen profile are described with a Voigt function, it is shown that the analysis of Fourier coefficients leads to the Warren-Averbach method of separation of size and strain contributions. The analysis of size coefficients shows that the “hook” effect occurs when the Cauchy content of the size-broadened profile is underestimated. The ratio of volume-weighted and surface-weighted domain sizes can change from ~1.31 for the minimum allowed Cauchy content to 2 when the size-broadened profile is given solely by a Cauchy function. If the distortion co-efficient is approximated by a harmonic term, mean-square strains decrease linearly with the increase of the averaging distance. The local strain is finite only in the case of pure-Gauss strain broadening because strains are then independent of averaging distance. Errors of root-mean-square strains as well as domain sizes were evaluated. The method was applied to two cubic structures with average volume-weighted domain sizes up to 3600 Å, as well as to tetragonal and orthorhombic (La-Sr)2CuO4, which exhibit weak line broadenings and highly overlapping reflections. Comparison with the integral-breadth methods is given. Reliability of the method is discussed in the case of a cluster of the overlapping peaks. The analysis of La2CuO4 and La1.85M0.15CuO4(M = Ca, Ba, Sr) high-Tc superconductors showed that microstrains and incoherently diffracting domain sizes are highly anisotropic. In the superconductors, stacking-fault probability increases with increasing Tc; microstrain decreases. In La2CuO4, different broadening of (h00) and (0k0) reflections is not caused by stacking faults; it might arise from lower crystallographic symmetiy. The analysis of Bi-Cu-O superconductors showed much higher strains in the [001] direction than in

  19. Stark broadening of halogen atom lines from (1 D) n p levels

    NASA Astrophysics Data System (ADS)

    Djurović, S.; Konjević, N.; Dimitrijević, M. S.

    1990-12-01

    We report results of a study of the Stark broadening of halogen atom lines from (1 D) n p levels. Wall stabilized arc is used as a plasma source. Electron densities 2.2 3.2×1022 m-3 are determined from the width of H α line and electron temperature 9300 10000 K from plasma composition data. The agreement with the results of simple semiclassical calculations is within the limits of the estimated errors of both experiment and theory. An explanation for the large discrepancy between theory and experiment detected for three BrI lines is offered.

  20. On the mode-coupling theory of vibrational line broadening in near-critical fluids.

    PubMed

    Lawrence, C P; Skinner, J L

    2004-05-08

    Molecular-dynamics simulations of a neat atomic fluid, coupled with a simple model for vibrational frequency perturbations, are used to investigate vibrational line broadening near the liquid-gas critical point. All features of our simulations are in qualitative agreement with recent Raman experiments on nitrogen. We also use our simulation results to assess the validity of the mode-coupling theories that have been used to analyze experiment. We find that the theoretical results are not in good agreement with simulation, both for the temperature dependence of the linewidth, and for the frequency time-correlation functions. However, the mode-coupling prediction that critical line broadening is due to the diverging correlation time of the frequency fluctuations is shown to be correct.

  1. Broadening and shift of Fe I lines perturbed by atomic hydrogen

    SciTech Connect

    Gomez, M.T.; Marmolino, C.; Roberti, R.; Severino, G.

    1987-01-01

    The broadening and shift parameters for a number of Fe I lines perturbed by atomic hydrogen are computed using the interatomic potential due to Hindmarsh et al (1967, 1970). It is also shown that the rms radius and the effective radius of the radiating atom, which determine the force constants in the interatomic potential, can be simply related to each other depending on the orbital quantum number of the atomic level.

  2. Broadening and Shifting of Atomic Strontium and Diatomic Bismuth Spectral Lines

    DTIC Science & Technology

    2003-05-01

    Lifetime in Sr,” Physical Review A, 13: 1269-70 (1976). BIB-2 23. Herzberg , Gerhard . Atomic Spectra and Atomic Structure. New York: Dover...Publications, Incorporated, 1944. 24. Herzberg , Gerhard . Molecular Spectra and Molecular Structure, Volume I: Spectra of Diatomic Molecules (2nd...the respective line broadening rates were measured. All spectroscopic constants in this table are gleaned from Herzberg [24]. The computations of

  3. Broadening, shifting, and line asymmetries in the 2<--0 band of CO and CO-N2: Experimental results and theoretical calculations

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, Adriana; Bouanich, J. P.; Benner, D. Chris; May, A. D.; Drummond, J. R.

    2000-07-01

    We have measured the room temperature, widths, pressure shifts, and line asymmetry coefficients for many transitions of the first overtone band of CO and CO perturbed by N2. The broadening coefficients were obtained with an accuracy of about 1%. The pure CO profiles have been fitted by a Voigt profile while the CO-N2 spectral profiles have been fitted with a Lorentz and an empirical line shape model (HCv) that blends together a hard collision model and a speed-dependent Lorentz profile. In addition to the Voigt, Lorentz, and HCv models, we have added a dispersion profile to account for weak line mixing. The line broadening and shift coefficients are compared to semiclassical calculations employing a variety of intermolecular interactions. The line asymmetry results are compared to line mixing calculations based on the energy corrected sudden (ECS) model. The results indicate that effects other than line mixing also contribute to the measured line asymmetry.

  4. Line centers, pressure shift, and pressure broadening of 1530-1560 nm hydrogen cyanide wavelength calibration lines

    SciTech Connect

    Swann, William C.; Gilbert, Sarah L.

    2005-08-01

    We have measured the line centers and pressure-induced shift and broadening of 25 lines in the 2{nu}{sub 3} rotational-vibrational band of hydrogen cyanide H{sup 13}C{sup 14}N. These lines can be used as wavelength references in the optical fiber communication wavelength division multiplexing C-band (approximately 1530-1565 nm). We find that the pressure shift varies with line number from +0.09 pm/kPa to -0.15 pm/kPa (approximately -1.5 to +2.5 MHz/Torr). The pressure broadening also varies with line number and is typically between 1 and 5.4 pm/kPa (17-90 MHz/Torr). We determined the line centers of 21 lines with an expanded uncertainty (2{sigma}) of 0.01 pm ({approx_equal}1 MHz), an improvement of more than 1 order of magnitude over previous line center measurements of this band. We also calculate the molecular constants for the band, yielding improved determination of the band origin frequency and the excited-state molecular constants.

  5. Electron Stark Broadening Database for Atomic N, O, and C Lines

    NASA Technical Reports Server (NTRS)

    Liu, Yen; Yao, Winifred M.; Wray, Alan A.; Carbon, Duane F.

    2012-01-01

    A database for efficiently computing the electron Stark broadening line widths for atomic N, O, and C lines is constructed. The line width is expressed in terms of the electron number density and electronatom scattering cross sections based on the Baranger impact theory. The state-to-state cross sections are computed using the semiclassical approximation, in which the atom is treated quantum mechanically whereas the motion of the free electron follows a classical trajectory. These state-to-state cross sections are calculated based on newly compiled line lists. Each atomic line list consists of a careful merger of NIST, Vanderbilt, and TOPbase line datasets from wavelength 50 nm to 50 micrometers covering the VUV to IR spectral regions. There are over 10,000 lines in each atomic line list. The widths for each line are computed at 13 electron temperatures between 1,000 K 50,000 K. A linear least squares method using a four-term fractional power series is then employed to obtain an analytical fit for each line-width variation as a function of the electron temperature. The maximum L2 error of the analytic fits for all lines in our line lists is about 5%.

  6. Pressure broadening coefficients for the 811.5nm Ar line and 811.3nm Kr line in rare gases

    NASA Astrophysics Data System (ADS)

    Ghildina, A. R.; Mikheyev, P. A.; Chernyshov, A. K.; Ufimtsev, N. I.; Azyazov, V. N.; Heaven, M. C.

    2017-01-01

    This paper describes systematic measurements of pressure broadening coefficients for argon and krypton lines in an RF (radio-frequency) discharge plasma sustained in a mixture of inert gases. Using tunable diode laser spectroscopy we obtained experimental data for pressure broadening of argon and krypton lines. Pressure broadening coefficients were determined for Ar+Ne and Kr+Ne and Kr+Ar. For krypton, the isotopic structure of the line was taken into account and an appropriate fitting function was used to determine pressure broadening coefficients for the natural mixture of isotopes. These data may be used for diagnostics of the active medium of optically pumped all-rare-gas lasers.

  7. VizieR Online Data Catalog: Stark broadening of H lines (Stehle 1995)

    NASA Astrophysics Data System (ADS)

    Stehle, C.

    1995-09-01

    Tables of Stark broadened hydrogen lines of the Lyman, Balmer and Paschen series are presented under the conditions of stellar envelopes. The formalism is based on the Model Microfield Method (MMM) (Brissaud and Frisch, Frisch and Brissaud 1971) for both the electronic and ionic contributions to the line shape. The range of temperatures is 10000 to 80000 K, and electronic densities between 3.2E+14 and 3.2E+16 cm-3. Lyman and Balmer results were published in A&AS 104, 509, whereas Paschen results were presented at the 1995 July Workshop in Vienna. (3 data files).

  8. Experimental and Theoretical He-BROADENED Line Parameters of Carbon Monoxide in the Fundamental Band

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, Adriana; Rosario, Hoimonti; Esteki, Koorosh; Latif, Shamria; Naseri, Hossein; Thibault, Franck; Devi, V. Malathy; Smith, Mary Ann H.; Mantz, Arlan

    2016-06-01

    We report experimental measurements and theoretical calculations for He-broadened Lorentz half-width coefficients and He- pressure-shift coefficients of 45 carbon monoxide transitions in the 1-0 band. The high-resolution spectra analyzed in this study were recorded over a range of sample temperatures between 296 and 80 K. The He-broadened line parameters and their temperature dependences were retrieved using a multispectrum nonlinear least squares analysis program. A previous analysis of these spectra used only the Voigt line shape. In the present study four line shape models were compared including Voigt, speed dependent Voigt, Rautian (to take into account confinement narrowing) and Rautian with speed dependence. The line mixing coefficients have been calculated using the Exponential Power Gap scaling law. We were unable to retrieve the temperature dependence of the line mixing coefficients. The current measurements and theoretical results are compared with other published results, where appropriate. A. W. Mantz et al., J. Molec. Structure 742 (2005) 99-110

  9. Using line broadening to determine the electron density in an argon surface-wave discharge at atmospheric pressure

    SciTech Connect

    Christova, M.; Christov, L.; Castanos-Martinez, E.; Moisan, M.; Dimitrijevic, M. S.

    2008-10-22

    Broadening due to collisions with charged particles (Stark broadening ) and neutral atoms, was determined for Ar I 522.1, 549.6 and 603.2 nm spectral lines from the spectral series 3p{sup 5}nd-3p{sup 5}4p, in order to evaluate the electron density in a surface-wave discharge at atmospheric pressure.

  10. Calculation of gain and luminescence spectra of quantum-cascade laser structures taking into account asymmetric emission line broadening

    SciTech Connect

    Ushakov, D V; Manak, I S; Kononenko, V K

    2010-05-26

    The energy levels, wave functions, and matrix elements of optical dipole transitions are calculated numerically for superlattice quantum-cascade structures. The effect of spectral broadening on the shape of emission spectra is estimated and semiphenomenological asymmetric profiles of emission line broadening are proposed. It is shown that the electroluminescence spectra well agree with the calculated spontaneous recombination spectra. (lasers)

  11. Model for interpreting Doppler broadened optical line emission measurements on axially symmetric plasma

    NASA Technical Reports Server (NTRS)

    Englert, G. W.; Patch, R. W.; Reinmann, J. J.

    1978-01-01

    A plasma model, previously developed to interpret neutral-particle analyzer measurements on E x B heating devices, is adapted to analyze Doppler broadened charge-exchange-neutral lines measured by an optical monochromator. Comparison of theoretical with experimental results indicates that azimuthal drift as well as cyclotron motion are quite influential in determining line shapes and widths, and thus important in temperature determination, even when the monochromator line of sight is intersecting the plasma axis of symmetry. At this central sighting position, however, results are quite insensitive to radial ion density distribution when time lag between the charge-exchange-excitation events and emission is neglected. Line shapes and widths obtained by sighting across chords of plasma at various distances from the plasma axis of symmetry indicate a strong dependence on time lag.

  12. Stark broadening of high-principal-quantum-number n-alpha lines of hydrogen.

    NASA Technical Reports Server (NTRS)

    Lasalle, T. R.; Nee, T.-J.; Griem, H. R.

    1973-01-01

    High n-alpha lines (transitions n + 1 to n) with quantum numbers n between 50 and 250 have been observed emanating from galactic H II regions where the electron density and temperature are about 1000/cu cm and 1 eV, respectively. High n-alpha lines have not previously been seen in the laboratory where fairly homogeneous plasmas may be produced and relatively precise measurements of electron densities and temperatures can be made. The present work describes experiments where the first members of the hydrogen line series with lower states n = 10, 11, 12, and 13 have been detected in a laboratory plasma. The width of the 12-alpha line at 88.7 microns could be measured and was consistent with calculated broadening from elastic electron collisions and quasi-static ion effects.

  13. Atom Resonance Lines for Modeling Atmosphere: Studies of Pressure-Broadening of Alkali Atom Resonance Lines for Modeling Atmospheres of Extrasolar Giant Planets and Brown Dwarfs

    NASA Technical Reports Server (NTRS)

    Hasan, Hashima (Technical Monitor); Kirby, K.; Babb, J.; Yoshino, K.

    2005-01-01

    We report on progress made in a joint program of theoretical and experimental research to study the line-broadening of alkali atom resonance lines due to collisions with species such as helium and molecular hydrogen. Accurate knowledge of the line profiles of Na and K as a function of temperature and pressure will allow such lines to serve as valuable diagnostics of the atmospheres of brown dwarfs and extra-solar giant planets. A new experimental apparatus has been designed, built and tested over the past year, and we are poised to begin collecting data on the first system of interest, the potassium resonance lines perturbed by collisions with helium. On the theoretical front, calculations of line-broadening due to sodium collisions with helium are nearly complete, using accurate molecular potential energy curves and transition moments just recently computed for this system. In addition we have completed calculations of the three relevant potential energy curves and associated transition moments for K - He, using the MOLPRO quantum chemistry codes. Currently, calculations of the potential surfaces describing K-H2 are in progress.

  14. Theoretical study of the Stark broadening for Mg IV spectral lines of astrophysical interest

    NASA Astrophysics Data System (ADS)

    de Andrés-García, I.; You, C.; Alonso-Medina, A.; Colón, C.

    2016-11-01

    Emission lines of Mg IV have been detected in the Far Ultraviolet Spectroscopic Explorer (FUSE) spectrum of LS V +46°21 star and in the Space Telescope Imaging Spectrograph (STIS) spectrum of BD +28°4211 star. This fact justifies our interest in providing spectroscopic parameters of Mg IV. Stark broadening parameters for 169 spectral lines of Mg IV have been calculated by using the Griem semi-empirical approach. The matrix elements used in these calculations has been determined from 13 configurations of Mg IV: 2s12p6, 2s22p4ns (n = 3-5), 2s22p4nd (n = 3-5) and 2s22p45g for even parity and 2s22p5, 2s22p4np (n = 3, 4) and 2s22p4nf (n = 4, 5) for odd parity. Our calculations were made by using the Cowan code. Data are presented for an electron density of 1017 cm-3 and temperatures T = 1.0-10.0 (104 K). Also we present calculated values of transition probabilities for 30 spectral lines and radiative lifetimes corresponding to its upper levels. These values were analysed using the data found in the literature. Theoretical trends of the Stark broadening parameters versus the temperature for several lines of astrophysical interest are presented.

  15. [Analysis of lorentzian line shape function broadened by non-sinusoidal wavelength modulation].

    PubMed

    Sun, You-Qun; Wang, Yun-Tao; Ruan, Chi; Xu, Song-Song

    2014-03-01

    In the present work, the Fourier analysis of Lorentzian line shape broadened by non-sinusoidal wavelength modulation was investigated, in which the third order and above harmonic items were ignored. The analytical expression of n-order Fourier coefficient was brought out, where a variable K named harmonic distortion to characterize the ratio of the second harmonic to the first harmonic was introduced. Numerical simulations based on the cases of K > 0.01 and K < 0.01 were carried out, and the result shows: non-sinusoidal modulation has little effect compared with the sinusoidal modulation when K value is less than 0.01, however, if K value is about 0.1 or higher, the center of the Fourier amplitude curve would deviate from the origin of coordinates. With the increase in the harmonic distortion, the deviation of the curve grows, and high order harmonics are more sensitive to the non-sinusoidal modulation compared with the low order harmonics. In addition, when harmonic distortion cannot be ignored, for example K > 0.01, the effect of different depths of modulation on the odd and even order harmonic amplitude curve is significant. And the numerical simulation shows there exists an optimum value of modulation depth which could minimize the impact of the harmonic distortion, and both large K value and small K value would cause a great error. The conclusion of this work could be applied in error analysis of wavelength modulation spectroscopy system And the results are helpful to deepening understanding of WMS and would be the important reference for some kind of frequency stabilization technology in laser instrument.

  16. Refinement of the semiclassical theory of the Stark broadening of hydrogen spectral lines in plasmas

    NASA Astrophysics Data System (ADS)

    Oks, Eugene

    2015-02-01

    Stark broadening (SB) of hydrogen, deuterium, and tritium lines (H-lines) is an important diagnostic tool for many applications. The most "user-friendly" are semiclassical theories of the SB of H-lines: their results can be expressed analytically in a relatively simple form for any H-line. The simplest semiclassical theory is the so-called Conventional Theory (CT), which is frequently referred to as Griem's theory. While by now there are several significantly more advanced semiclassical "non-CT" theories of the SB, Griem's CT is still used by a number of groups performing laboratory experiments or astrophysical observations for the comparison with their experimental or observational results. In the present study we engage unexplored capabilities of the CT for creating analytically a more accurate CT. First, we take into account that the perturbing electrons actually do not move as free particles: rather they move in a dipole potential V=·r/r3, where r is the radius-vector of the perturbing electrons and is the mean value of the radius vector of the atomic electron. Second, Griem's definition of the so-called Weisskopf radius was not quite accurate. Third, in his book of year 1974, Griem suggested changing so-called strong collision constant without changing the Weisskopf radius, while in reality the choices of the Weisskopf radius and of the strong collision constant are interrelated. We show that the above refinements of the CT increase the electron broadening - especially for warm dense plasmas emitting H-lines. By comparison with benchmark experiments concerning the Hα line we demonstrate that the effect of the ion dynamics (neglected in any CT) might be slightly smaller than previously thought, while the effect of the acceleration of perturbing electrons by the ion field in the vicinity of the radiating atom (neglected in any CT) might be greater than previously thought.

  17. The Broadening of Spectral Lines by Collisions with Neutral Hydrogen Atoms

    NASA Astrophysics Data System (ADS)

    Barklem, P. S.

    1998-10-01

    In this thesis the theory of collisional broadening by neutral hydrogen of Anstee and O'Mara (1991,1992,1995) for s-p and p-s transitions of neutrals is extended and applied to both p-d, d-p, d-f and f-d transitions of neutral atoms, and the broadening of transitions of ions. The interaction between a ground state hydrogen atom with a generic neutral atom, is considered using Rayleigh-Schrödinger perturbation theory. The usual second order expression for the interaction energy between the two atoms involves an infinite sum over virtual states of the two-atom system, and an energy denominator which is the energy debt incurred when the two atom system makes a transition from the state of interest to a virtual state. Unsöld (1927,1955) showed that the expression for the in teraction energy can be greatly simplified if the variable energy debt incurred in making a transition from the state of interest to a virtual state is replaced by a fixed debt Ep. Closure can then be used to complete the sum over the virtual states leading to an expression for the interaction energy in terms of diagonal matrix elements of V2 (where V is the electrostatic interaction between the two atoms), and Ep. This is commonly referred to as the Unsöld approximation. It is the most important approximation in the development of the treatment of spectral line broadening presented in this thesis. Expressions for the interaction energy between a ground state hydrogen atom and a generic neutral atom in both d- and f-states are presented. Adiabatic potential curves calculated from code written to compute these expressions are presented. For interactions of neutral atoms, the Unsöld value of Ep=-4/9 atomic units is used throughout. Code was written to compute line broadening cross-sections for p-d, d-p, d-f and f-d transitions of neutral atoms, using the semi-classical procedure of Roueff (1974) adapted for these transitions. Firstly, the dependence of cross-sections on regions of the potential

  18. Molecular dynamic simulations of N2-broadened methane line shapes and comparison with experiments

    NASA Astrophysics Data System (ADS)

    Le, Tuong; Doménech, José-Luis; Lepère, Muriel; Tran, Ha

    2017-03-01

    Absorption spectra of methane transitions broadened by nitrogen have been calculated for the first time using classical molecular dynamic simulations. For that, the time evolution of the auto-correlation function of the dipole moment vector, assumed along a C-H axis, was computed using an accurate site-site intermolecular potential for CH4-N2. Quaternion coordinates were used to treat the rotation of the molecules. A requantization procedure was applied to the classical rotation and spectra were then derived as the Fourier-Laplace transform of the auto-correlation function. These computed spectra were compared with experimental ones recorded with a tunable diode laser and a difference-frequency laser spectrometer. Specifically, nine isolated methane lines broadened by nitrogen, belonging to various vibrational bands and having rotational quantum numbers J from 0 to 9, were measured at room temperature and at several pressures from 20 to 945 mbar. Comparisons between measured and calculated spectra were made through their fits using the Voigt profile. The results show that ab initio calculated spectra reproduce with very high fidelity non-Voigt effects on the measurements and that classical molecular dynamic simulations can be used to predict spectral shapes of isolated lines of methane perturbed by nitrogen.

  19. Temperature dependences of self- and N2-broadened line-shape parameters in the ν3 and ν5 bands of 12CH3D: Measurements and calculations

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, A.; Malathy Devi, V.; Sutradhar, P.; Sinyakova, T.; Buldyreva, J.; Sung, K.; Smith, M. A. H.; Mantz, A. W.

    2016-07-01

    This paper presents the results of a spectroscopic line shape study of self- and nitrogen-broadened 12CH3D transitions in the ν3 and ν5 bands in the Triad region. We combined five pure gas spectra with eighteen spectra of lean mixtures of 12CH3D and nitrogen, all recorded with a Bruker IFS-125 HR Fourier transform spectrometer. The spectra have been analyzed simultaneously using a multispectrum nonlinear least squares fitting technique. N2-broadened line parameters for 184 transitions in the ν3 band and 205 transitions in the ν5 band were measured. In addition, line positions and line intensities were measured for 168 transitions in the ν3 band and 214 transitions in the ν5 band. We have observed 10 instances of weak line mixing corresponding to K″=3 A1 or A2 transitions. Comparisons were made for the N2-broadening coefficients and associated temperature exponents with corresponding values calculated using a semi-classical Robert Bonamy type formalism that involved an inter-molecular potential with terms corresponding to short- and long-range interactions, and exact classical molecular trajectories. The theoretical N2-broadened coefficients are overestimated for high J values, but are in good agreement with the experimental values for small and middle range J values.

  20. RELATIVISTIC BROADENING OF IRON EMISSION LINES IN A SAMPLE OF ACTIVE GALACTIC NUCLEI

    SciTech Connect

    Brenneman, Laura W.; Reynolds, Christopher S.

    2009-09-10

    We present a uniform X-ray spectral analysis of eight type-1 active galactic nuclei that have been previously observed with relativistically broadened iron emission lines. Utilizing data from the XMM-Newton European Photon Imaging Camera (EPIC-pn) we carefully model the spectral continuum, taking complex intrinsic absorption and emission into account. We then proceed to model the broad Fe K{alpha} feature in each source with two different accretion disk emission line codes, as well as a self-consistent, ionized accretion disk spectrum convolved with relativistic smearing from the inner disk. Comparing the results, we show that relativistic blurring of the disk emission is required to explain the spectrum in most sources, even when one models the full reflection spectrum from the photoionized disk.

  1. Plasma motions and non-thermal line broadening in flaring twisted coronal loops

    NASA Astrophysics Data System (ADS)

    Gordovskyy, M.; Kontar, E. P.; Browning, P. K.

    2016-05-01

    Context. Observation of coronal extreme ultra-violet (EUV) spectral lines sensitive to different temperatures offers an opportunity to evaluate the thermal structure and flows in flaring atmospheres. This, in turn, can be used to estimate the partitioning between the thermal and kinetic energies released in flares. Aims: Our aim is to forward-model large-scale (50-10 000 km) velocity distributions to interpret non-thermal broadening of different spectral EUV lines observed in flares. The developed models allow us to understand the origin of the observed spectral line shifts and broadening, and link these features to particular physical phenomena in flaring atmospheres. Methods: We use ideal magnetohydrodynamics (MHD) to derive unstable twisted magnetic fluxtube configurations in a gravitationally stratified atmosphere. The evolution of these twisted fluxtubes is followed using resistive MHD with anomalous resistivity depending on the local density and temperature. The model also takes thermal conduction and radiative losses in the continuum into account. The model allows us to evaluate average velocities and velocity dispersions, which would be interpreted as non-thermal velocities in observations, at different temperatures for different parts of the models. Results: Our models show qualitative and quantitative agreement with observations. Thus, the line-of-sight (LOS) velocity dispersions demonstrate substantial correlation with the temperature, increasing from about 20-30 km s-1 around 1 MK to about 200-400 km s-1 near 10-20 MK. The average LOS velocities also correlate with velocity dispersions, although they demonstrate a very strong scattering compared to the observations. We also note that near footpoints the velocity dispersions across the magnetic field are systematically lower than those along the field. We conclude that the correlation between the flow velocities, velocity dispersions, and temperatures are likely to indicate that the same heating

  2. - and Air-Broadened Line Shape Parameters of 12CH_4 : 4500-4620 CM-1

    NASA Astrophysics Data System (ADS)

    Devi, V. Malathy; Benner, D. Chris; Sung, Keeyoon; Brown, Linda; Crawford, Timothy J.; Smith, Mary Ann H.; Mantz, Arlan; Predoi-Cross, Adriana

    2014-06-01

    Accurate knowledge of spectral line shape parameters is important for infrared transmission and radiance calculations in the terrestrial atmosphere. We report the self- and air-broadened Lorentz widths, shifts and line mixing coefficients along with their temperature dependences for methane absorption lines in the 2.2 μm spectral region. For this, we obtained a series of high-resolution, high S/N spectra of 99.99% 12C-enriched samples of pure methane and its dilute mixtures in dry air at cold temperatures down to 150 K using the Bruker IFS 125HR Fourier transform spectrometer at JPL. The coolable absorption cell had an optical path of 20.38 cm and was specially built to reside inside the sample compartment of the Bruker FTS. The 13 spectra used in the analysis consisted of seven pure 12CH_4 spectra at pressures from 4.5 to 169 Torr and six air-broadened spectra with total sample pressures of 113-300 Torr and methane volume mixing ratios between 4 and 9.7%. These 13 spectra were fit simultaneously using the multispectrum least-squares fitting technique. The results will be compared to existing values reported in the literature. K. Sung, A. W. Mantz, L. R. Brown, et al., J. Mol. Spectrosc., 162 (2010) 124-134. D. C. Benner, C. P. Rinsland, V. Malathy Devi, M. A. H. Smith and D. Atkins, JQSRT, 53 (1995) 705-721. Research described in this paper was performed at Connecticut College, the College of William and Mary, NASA Langley Research Center and the Jet Propulsion Laboratory, California Institute of Technology, under contracts and cooperative agreements with the National Aeronautics and Space Administration.

  3. Calculations of H2O microwave line broadening in collisions with He atoms - Sensitivity to potential energy surfaces

    NASA Technical Reports Server (NTRS)

    Green, Sheldon; Defrees, D. J.; Mclean, A. D.

    1991-01-01

    Theoretical computations of broadening parameters are reported for three microwave lines of H2O in a bath of He atoms. The potential-energy surfaces employed are corrected for basis-set superposition error, and their reliability is checked by repeating the calculations with a different basis set for orbital expansion. The results are presented in extensive tables and discussed in detail. The corrections applied are shown to have a significant impact on the accuracy of the room-temperature broadenings determined: 8.9 sq A for the 22.2-GHz line, 11.8 sq A for the 183,3-GHz line, and 10.0 sq A for the 380.2-GHz line, in good agreement with published experimental data. The importance of collisional broadening for the atmospheric transmission of radiation and for remote-sensing applications is indicated.

  4. Line strength and self-broadening coefficient of the pure rotational S(1) quadrupole line in H2

    NASA Technical Reports Server (NTRS)

    Reuter, Dennis C.; Sirota, J. Marcos

    1994-01-01

    The absolute intensity, S(sub 1), and self-broadening coefficient, gamma(sub L), for H2 S(sub zero)(1) pure rotational line at 17.0348 micrometers (587.032 cm(exp -1)) have been measured for the first time using a tunable diode laser spectrometer with a resolution of approximately 1 x 10(exp -3) cm(exp -1). By fitting a Galatry line shape convolved with a 1 x 10(exp -3) cm(exp -1) Gaussian instrument profile to absorption profiles, for H2 pressures ranging from 0.34 to 1.30 atm, values of s(sub 1) = (7.0 +/- 0.4) x 10(exp -8) cm(exp -2) atm(exp -1) and gamma(sub L) = (1.73 +/- 0.12) x 10(exp -3) cm(exp -1) atm(exp -1) were obtained.

  5. Anomalous Doppler broadening caused by exothermic reactions: application to hydrogen Balmer lines

    NASA Astrophysics Data System (ADS)

    Loureiro, J.; Amorim, J.

    2011-08-01

    The three- and one-dimensional velocity distributions of a product species created by an exothermic reaction are calculated using the energy conservation, with the aim of evaluating the impact of such processes on the anomalous broadening of Doppler lines. The calculations are performed to the reaction H{2/+} + H2 → H{3/+} + H, in which according to Christoffersen (1964) an amount of 1.56 eV is transferred to the product species. It is shown that the deviations relatively to Maxwell-Boltzmann distributions are significant as the internal energy defect ΔE increases, even within energies lower than 1.56 eV, and hence the profiles of excited H∗ atoms, associated with the emission of hydrogen Balmer lines, created in the sequence of H( n = 1) produced by the above reaction are not of Gaussian-type. The profiles are markedly flatter and squarer than Gaussian distributions. The validity of the species temperature determined from the full width at half maximum (FWHM) of the lines, as well as the fit of the lines by multimodal Gaussian functions, is then analyzed.

  6. - and H_2-BROADENED Line Parameters of Carbon Monoxide in the First Overtone Band

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, Adriana; Esteki, Koorosh; Naseri, Hossein; Devi, V. Malathy; Smith, Mary Ann H.; Mantz, Arlan; Ivanov, Sergei V.

    2016-06-01

    In this study we have re-analyzed high-resolution spectra of pure CO and CO broadened by hydrogen recorded in the spectral range of the first overtone band. We have used four different line shapes in the multispectrum analysis (Voigt, speed dependent Voigt, Rautian, and Rautian with speed dependence) and compared the resulting line shape parameters. The line mixing coefficients have been calculated using the Exponential Power Gap and the Energy Corrected Sudden scaling laws. A classical approach was applied to calculate CO line widths in CO-H_2 and CO-CO collisions. The formulas of classical impact theory are used for calculation of dipole absorption half-widths along with exact 3D Hamilton equations for simulation of molecular motion. The calculations utilize Monte Carlo averaging over collision parameters and simple interaction potential (Tipping-Herman + electrostatic). Molecules are treated as rigid rotors. The dependences of CO half-widths on rotational quantum number J≤ 24 are computed and compared with measured data at room temperature. V. Malathy Devi et al., J. Mol. Spectrosc. 228 (2004) 580-592. R. G. Gordon, J. Chem. Phys. 44 (1966) 3083-3089; ibid., 45 (1966) 1649-1655. J.-P. Bouanich and A. Predoi-Cross, J. Molec. Structure 742 (2005) 183-190 A. Predoi-Cross, J.-P. Bouanich, D. Chris Benner, A. D. May, and J. R. Drummond, J. Chem. Phys. 113 (2000) 158-168

  7. Impact of broadened laser line-shape on retrievals of atmospheric species from lidar sounding absorption spectra.

    PubMed

    Chen, Jeffrey R; Numata, Kenji; Wu, Stewart T

    2015-02-09

    We examine the impact of broadened laser line-shape on retrievals of atmospheric species from lidar-sounding absorption spectra. The laser is assumed to be deterministically modulated into a stable, nearly top-hat frequency comb to suppress the stimulated Brillouin scattering, allowing over 10-fold pulse energy increase without adding measurement noise. Our model remains accurate by incorporating the laser line-shape factor into the effective optical depth. Retrieval errors arising from measurement noise and model bias are analyzed parametrically and numerically to provide deeper insight. The stable laser line-shape broadening minimally degrades the column-averaged retrieval, but can significantly degrade the multiple-layer retrievals.

  8. Water-vapor line broadening and shifting by air, nitrogen, oxygen, and argon in the 720-nm wavelength region

    NASA Technical Reports Server (NTRS)

    Grossmann, Benoist E.; Browell, Edward V.

    1989-01-01

    High-resolution spectroscopic measurements of H2O vapor in the 720-nm wavelength region were conducted to investigate the broadening and shifting of H2O lines by air, nitrogen, oxygen, and argon over a wide range of pressures and temperatures. For each of the buffer gases under study, a linear relationship was found between the widths and the shifts, with the broader lines having the smaller pressure shifts. The pressure shifts measured compared favorably with theoretical values reported by Bykov et al. (1988). The temperature-dependence exponents for air-broadening were found to be J-dependent, with the lower-J lines having the higher exponents.

  9. Broadening of the infrared absorption lines at reduced temperatures. II - Carbon monoxide in an atmosphere of carbon dioxide.

    NASA Technical Reports Server (NTRS)

    Tubbs, L. D.; Williams, D.

    1972-01-01

    The strengths of the rotational lines in the R branch of the CO fundamental have been determined at temperatures of 298, 202, and 132 K by means of a high-resolution spectrograph. The results can be used to determine line strengths at other temperatures by means of the Herman-Wallis relation or by considerations of the populations of the rotational levels in the ground vibrational state. Parameters describing the self-broadening and carbon dioxide broadening of CO lines have been determined at 298 and 202 K. The results are compared with other recent experimental and theoretical studies.

  10. Effect of collisional lines broadening and calibration functions in the pure rotational Raman lidar technique

    NASA Astrophysics Data System (ADS)

    Gerasimov, Vladislav V.; Zuev, Vladimir V.

    2016-10-01

    We present and examine two three-coefficient calibration functions to be used for the tropospheric temperature retrievals via the pure rotational Raman (PRR) lidar technique. These functions are the special cases of the general analytical calibration function in the PRR lidar technique. The general function special cases take into account the collisional (pressure) broadening of all individual atmospheric N2 and O2 PRR lines in varying degrees. We apply these two special cases to real lidar remote sensing data and compare nighttime temperature profiles retrieved using these calibration functions to the profiles retrieved using other known ones. The absolute statistical uncertainties of temperature retrieval are also given in an analytical form. Lidar measurements data, obtained in Tomsk (56.48° N, 85.05° E, Western Siberia, Russia) using the IMCES PRR lidar at λ = 354.67 nm on 1 April 2015, were used for the tropospheric temperature retrievals (3-12 km).

  11. Plasma density characterization at SPARC_LAB through Stark broadening of Hydrogen spectral lines

    NASA Astrophysics Data System (ADS)

    Filippi, F.; Anania, M. P.; Bellaveglia, M.; Biagioni, A.; Chiadroni, E.; Cianchi, A.; Di Giovenale, D.; Di Pirro, G.; Ferrario, M.; Mostacci, A.; Palumbo, L.; Pompili, R.; Shpakov, V.; Vaccarezza, C.; Villa, F.; Zigler, A.

    2016-09-01

    Plasma-based acceleration techniques are of great interest for future, compact accelerators due to their high accelerating gradient. Both particle-driven and laser-driven Plasma Wakefield Acceleration experiments are foreseen at the SPARC_LAB Test Facility (INFN National Laboratories of Frascati, Italy), with the aim to accelerate high-brightness electron beams. In order to optimize the efficiency of the acceleration in the plasma and preserve the quality of the accelerated beam, the knowledge of the plasma electron density is mandatory. The Stark broadening of the Hydrogen spectral lines is one of the candidates used to characterize plasma density. The implementation of this diagnostic for plasma-based experiments at SPARC_LAB is presented.

  12. WHY IS NON-THERMAL LINE BROADENING OF SPECTRAL LINES IN THE LOWER TRANSITION REGION OF THE SUN INDEPENDENT OF SPATIAL RESOLUTION?

    SciTech Connect

    De Pontieu, B.; Martinez-Sykora, J.; McIntosh, S.; Peter, H.; Pereira, T. M. D.

    2015-01-20

    Spectral observations of the solar transition region (TR) and corona show broadening of spectral lines beyond what is expected from thermal and instrumental broadening. The remaining non-thermal broadening is significant (5–30 km s{sup −1}) and correlated with intensity. Here we study spectra of the TR Si iv 1403 Å line obtained at high resolution with the Interface Region Imaging Spectrograph (IRIS). We find that the large improvement in spatial resolution (0.″33) of IRIS compared to previous spectrographs (2″) does not resolve the non-thermal line broadening which, in most regions, remains at pre-IRIS levels of about 20 km s{sup −1}. This invariance to spatial resolution indicates that the processes behind the broadening occur along the line-of-sight (LOS) and/or on spatial scales (perpendicular to the LOS) smaller than 250 km. Both effects appear to play a role. Comparison with IRIS chromospheric observations shows that, in regions where the LOS is more parallel to the field, magneto-acoustic shocks driven from below impact the TR and can lead to significant non-thermal line broadening. This scenario is supported by MHD simulations. While these do not show enough non-thermal line broadening, they do reproduce the long-known puzzling correlation between non-thermal line broadening and intensity. This correlation is caused by the shocks, but only if non-equilibrium ionization is taken into account. In regions where the LOS is more perpendicular to the field, the prevalence of small-scale twist is likely to play a significant role in explaining the invariance and correlation with intensity. (letters)

  13. Why is Non-Thermal Line Broadening of Spectral Lines in the Lower Transition Region of the Sun Independent of Spatial Resolution?

    NASA Astrophysics Data System (ADS)

    De Pontieu, B.; McIntosh, S.; Martinez-Sykora, J.; Peter, H.; Pereira, T. M. D.

    2015-01-01

    Spectral observations of the solar transition region (TR) and corona show broadening of spectral lines beyond what is expected from thermal and instrumental broadening. The remaining non-thermal broadening is significant (5-30 km s-1) and correlated with intensity. Here we study spectra of the TR Si iv 1403 Å line obtained at high resolution with the Interface Region Imaging Spectrograph (IRIS). We find that the large improvement in spatial resolution (0.″33) of IRIS compared to previous spectrographs (2″) does not resolve the non-thermal line broadening which, in most regions, remains at pre-IRIS levels of about 20 km s-1. This invariance to spatial resolution indicates that the processes behind the broadening occur along the line-of-sight (LOS) and/or on spatial scales (perpendicular to the LOS) smaller than 250 km. Both effects appear to play a role. Comparison with IRIS chromospheric observations shows that, in regions where the LOS is more parallel to the field, magneto-acoustic shocks driven from below impact the TR and can lead to significant non-thermal line broadening. This scenario is supported by MHD simulations. While these do not show enough non-thermal line broadening, they do reproduce the long-known puzzling correlation between non-thermal line broadening and intensity. This correlation is caused by the shocks, but only if non-equilibrium ionization is taken into account. In regions where the LOS is more perpendicular to the field, the prevalence of small-scale twist is likely to play a significant role in explaining the invariance and correlation with intensity.

  14. H2-,He-and CO2-line broadening coefficients and pressure shifts for the HITRAN database

    NASA Astrophysics Data System (ADS)

    Wilzewski, Jonas; Gordon, Iouli E.; Rothman, Laurence S.

    2014-06-01

    To increase the potential of the HITRAN database in astronomy, experimental and theoretical line broadening coefficients and line shifts of molecules of planetary interest broadened by H2,He,and CO2 have been assembled from available peer-reviewed sources. Since H2 and He are major constituents in the atmospheres of gas giants, and CO2 predominates in atmospheres of some rocky planets with volcanic activity, these spectroscopic data are important for studying planetary atmospheres. The collected data were used to create semi-empirical models for complete data sets from the microwave to the UV part of the spectrum of the studied molecules. The presented work will help identify the need for further investigations of broadening and shifting of spectral lines.

  15. Measurements of argon-, helium-, hydrogen-, and nitrogen-broadened widths of methane lines near 9000 per cm

    NASA Technical Reports Server (NTRS)

    Fox, Kenneth; Jennings, Donald E.; Stern, Elizabeth A.; Hubbard, Rob

    1988-01-01

    Pressure-broadened widths of rotational-vibrational lines in CH4 have been measured at very high spectral resolution in the R-branch of the 3nu3 overtone. The broadening gases were Ar, He, H2, and N2. Results are presented as averages for J-multiplets at ambient temperature. The overall values (per cm per atm) for these R-branch lines are 0.0651 (CH4-Ar), 0.0508 (CH4-He), 0.0728 (CH4-H2), and 0.0715 (CH4-N2).

  16. Measurement of multiplet intensities and noble gas-broadened line widths in the nu 3 fundamental of methane

    NASA Technical Reports Server (NTRS)

    Varanasi, P.; Pugh, L. A.; Bangaru, B. R. P.

    1974-01-01

    Presented integrated intensity data at 300 K for J multiplets between P(11) and R(11) in the nu-3 fundamental of C-12 methane are shown to be in good agreement with most previously published pertinent values. Also, line widths measured at 100 K, 130 K, 190 K, 250 K, and 300 K for R(0), R(1), and R(2) broadened by He, Ne, and Ar are presented, and the line-width temperature dependence is discussed for the three cases of broadening.

  17. Investigation of the collision line broadening problem as applicable to the NASA Optical Plume Anomaly Detection (OPAD) system, phase 1

    NASA Technical Reports Server (NTRS)

    Dean, Timothy C.; Ventrice, Carl A.

    1995-01-01

    As a final report for phase 1 of the project, the researchers are submitting to the Tennessee Tech Office of Research the following two papers (reprinted in this report): 'Collision Line Broadening Effects on Spectrometric Data from the Optical Plume Anomaly System (OPAD),' presented at the 30th AIAA/ASME/SAE/ASEE Joint Propulsion Conference, 27-29 June 1994, and 'Calculation of Collision Cross Sections for Atomic Line Broadening in the Plume of the Space Shuttle Main Engine (SSME),' presented at the IEEE Southeastcon '95, 26-29 March 1995. These papers fully state the problem and the progress made up to the end of NASA Fiscal Year 1994. The NASA OPAD system was devised to predict concentrations of anomalous species in the plume of the Space Shuttle Main Engine (SSME) through analysis of spectrometric data. The self absorption of the radiation of these plume anomalies is highly dependent on the line shape of the atomic transition of interest. The Collision Line Broadening paper discusses the methods used to predict line shapes of atomic transitions in the environment of a rocket plume. The Voigt profile is used as the line shape factor since both Doppler and collisional line broadening are significant. Methods used to determine the collisional cross sections are discussed and the results are given and compared with experimental data. These collisional cross sections are then incorporated into the current self absorbing radiative model and the predicted spectrum is compared to actual spectral data collected from the Stennis Space Center Diagnostic Test Facility rocket engine. The second paper included in this report investigates an analytical method for determining the cross sections for collision line broadening by molecular perturbers, using effective central force interaction potentials. These cross sections are determined for several atomic species with H2, one of the principal constituents of the SSME plume environment, and compared with experimental data.

  18. Investigation of the collision line broadening problem as applicable to the NASA Optical Plume Anomaly Detection (OPAD) system, phase 1

    NASA Astrophysics Data System (ADS)

    Dean, Timothy C.; Ventrice, Carl A.

    1995-05-01

    As a final report for phase 1 of the project, the researchers are submitting to the Tennessee Tech Office of Research the following two papers (reprinted in this report): 'Collision Line Broadening Effects on Spectrometric Data from the Optical Plume Anomaly System (OPAD),' presented at the 30th AIAA/ASME/SAE/ASEE Joint Propulsion Conference, 27-29 June 1994, and 'Calculation of Collision Cross Sections for Atomic Line Broadening in the Plume of the Space Shuttle Main Engine (SSME),' presented at the IEEE Southeastcon '95, 26-29 March 1995. These papers fully state the problem and the progress made up to the end of NASA Fiscal Year 1994. The NASA OPAD system was devised to predict concentrations of anomalous species in the plume of the Space Shuttle Main Engine (SSME) through analysis of spectrometric data. The self absorption of the radiation of these plume anomalies is highly dependent on the line shape of the atomic transition of interest. The Collision Line Broadening paper discusses the methods used to predict line shapes of atomic transitions in the environment of a rocket plume. The Voigt profile is used as the line shape factor since both Doppler and collisional line broadening are significant. Methods used to determine the collisional cross sections are discussed and the results are given and compared with experimental data. These collisional cross sections are then incorporated into the current self absorbing radiative model and the predicted spectrum is compared to actual spectral data collected from the Stennis Space Center Diagnostic Test Facility rocket engine. The second paper included in this report investigates an analytical method for determining the cross sections for collision line broadening by molecular perturbers, using effective central force interaction potentials. These cross sections are determined for several atomic species with H2, one of the principal constituents of the SSME plume environment, and compared with experimental data.

  19. Line formation in Be star circumstellar disks Shear broadening, shell absorption, stellar obscuration and rotational parameter

    NASA Astrophysics Data System (ADS)

    Hummel, W.; Vrancken, M.

    2000-07-01

    We improve the theory of Horne & Marsh on shear broadening in accretion disks of CVs and adapt it to Be star circumstellar disks. Stellar obscuration and shell absorption are taken into account in detail. It is shown that shell absorption is already present in those emission lines where the central depression does not drop below the stellar continuum. The model profiles are fitted to observed symmetric Hα net emission lines with low equivalent width. The derived disk radii range from Rd = 5.3 R_* to Rd = 18 R_* and the surface emissivity varies as ~ R-m with 1.6 < m < 3.5. The comparison between model profiles of rotational parameter j>(1)/(2) with the optically thick Hα profile of HR 5440 rules out the range of j>(1)/(2). This can be understood by the lack of velocity shear in the outer disk regions. We conclude that Keplerian rotation (j=(1)/(2)) is a valid approximation. Based on observations collected at the German-Spanish Astronomical Center (DSAZ), Calar Alto, operated by the Max-Plank-Institut für Astronomie Heidelberg jointly with the Spanish National Commission for Astronomy. Based on observations collected at the Observatoire de Haute-Provence (OHP), CNRS, France.

  20. Spectral anomalies of the light-induced drift effect caused by the velocity dependence of the collision broadening and shift of the absorption line

    NASA Astrophysics Data System (ADS)

    Parkhomenko, A. I.; Shalagin, Anatolii M.

    2013-02-01

    We have theoretically investigated the spectral features of the light-induced drift (LID) effect, arising due to the dependence of the collision broadening γ and shift Δ of the absorption line on the velocity of resonance particles, ν. It is shown that under certain conditions, account of this dependence can radically change the spectral shape of the LID signal, up to the appearance of additional zeros in the dependence of the drift velocity on the radiation frequency.

  1. Spectral anomalies of the light-induced drift effect caused by the velocity dependence of the collision broadening and shift of the absorption line

    SciTech Connect

    Parkhomenko, A I; Shalagin, Anatolii M

    2013-02-28

    We have theoretically investigated the spectral features of the light-induced drift (LID) effect, arising due to the dependence of the collision broadening {gamma} and shift {Delta} of the absorption line on the velocity of resonance particles, {nu}. It is shown that under certain conditions, account of this dependence can radically change the spectral shape of the LID signal, up to the appearance of additional zeros in the dependence of the drift velocity on the radiation frequency. (nonlinear optical phenomena)

  2. Determination of foreign broadening coefficients for Methane Lines Targeted by the Tunable Laser Spectrometer (TLS) on the Mars Curiosity Rover

    NASA Astrophysics Data System (ADS)

    Manne, Jagadeeshwari; Bui, Thinh Q.; Webster, Christopher R.

    2017-04-01

    Molecular line parameters of foreign- broadening by air, carbon dioxide, and helium gas have been experimentally determined for infrared ro-vibrational spectral lines of methane isotopologues (12CH4 and 13CH4) at 3057 cm-1 targeted by the Tunable Laser Spectrometer (TLS) in the Sample Analysis at Mars (SAM) instrument suite on the Mars Science Laboratory (MSL) Curiosity rover. From multi-spectrum analyses with the speed-dependent Voigt line profile with Rosenkrantz line-mixing, speed-dependence and line-mixing effects were quantified for methane spectra at total pressures up to 200 mbar. The fitted air-broadening coefficients deviated from 8-25% to those reported in the HITRAN-2012 database.

  3. Coherent population trapping resonances at lower atomic levels of Doppler broadened optical lines

    SciTech Connect

    Şahin, E; Hamid, R; Çelik, M; Özen, G; Izmailov, A Ch

    2014-11-30

    We have detected and analysed narrow high-contrast coherent population trapping (CPT) resonances, which are induced in absorption of a weak monochromatic probe light beam by counterpropagating two-frequency pump radiation in a cell with rarefied caesium vapour. The experimental investigations have been performed by the example of nonclosed three level Λ-systems formed by spectral components of the D{sub 2} line of caesium atoms. The applied method allows one to analyse features of the CPT phenomenon directly at a given low long-lived level of the selected Λ-system even in sufficiently complicated spectra of atomic gases with large Doppler broadening. We have established that CPT resonances in transmission of the probe beam exhibit not only a higher contrast but also a much lesser width in comparison with well- known CPT resonances in transmission of the corresponding two-frequency pump radiation. The results obtained can be used in selective photophysics, photochemistry and ultra-high resolution atomic (molecular) spectroscopy. (laser applications and other topics in quantum electronics)

  4. Observations of Relativistically Broadened Iron Kalpha Lines From Stellar Mass Black Holes

    NASA Astrophysics Data System (ADS)

    Tomsick, John

    2016-04-01

    The measurement of Doppler broadened and gravitationally redshifted iron emission lines from accreting black holes has been used to measure the inner radius of the optically thick disk (Rin). At high mass accretion rates, when the disk is at or close to the Innermost Stable Circular Orbit (ISCO), a determination of Rin provides a constraint on the spin of the black hole. Measuring Rin can also provide information about whether the disk is truncated or not, and this is especially important for understanding the relationship between the disk and the steady jet in the hard state. Over the past few years, the Nuclear Spectroscopic Telescope Array (NuSTAR) has provided improved measurements due to its combination of bandpass (3-79 keV), good energy resolution, and high throughput. In this presentation, we discuss NuSTAR results for a number of stellar mass black holes (e.g., Cyg X-1, GX 339-4, and GRS 1739-278). While these observations have been successful in obtaining measurements of Rin, the improved spectra have also provided extra information about the source geometry and the inner disk inclination, which we will discuss.

  5. MODIFICATION OF THE MOOG SPECTRAL SYNTHESIS CODES TO ACCOUNT FOR ZEEMAN BROADENING OF SPECTRAL LINES

    SciTech Connect

    Deen, Casey P.

    2013-09-15

    In an attempt to widen access to the study of magnetic fields in stellar astronomy, I present MOOGStokes, a version of the MOOG one-dimensional local thermodynamic equilibrium radiative transfer code, overhauled to incorporate a Stokes vector treatment of polarized radiation through a magnetic medium. MOOGStokes is a suite of three complementary programs, which together can synthesize the disk-averaged emergent spectrum of a star with a magnetic field. The first element (a pre-processing script called CounterPoint) calculates for a given magnetic field strength, wavelength shifts, and polarizations for the components of Zeeman-sensitive lines. The second element (a MOOG driver called SynStokes derived from the existing MOOG driver Synth) uses the list of Zeeman-shifted absorption lines together with the existing machinery of MOOG to synthesize the emergent spectrum at numerous locations across the stellar disk, accounting for stellar and magnetic field geometry. The third and final element (a post-processing script called DiskoBall) calculates the disk-averaged spectrum by weighting the individual emergent spectra by limb darkening and projected area, and applying the effects of Doppler broadening. All together, the MOOGStokes package allows users to synthesize emergent spectra of stars with magnetic fields in a familiar computational framework. MOOGStokes produces disk-averaged spectra for all Stokes vectors ( I, Q, U, V ), normalized by the continuum. MOOGStokes agrees well with the predictions of INVERS10 a polarized radiative transfer code with a long history of use in the study of stellar magnetic fields. In the non-magnetic limit, MOOGStokes also agrees with the predictions of the scalar version of MOOG.

  6. Modification of the MOOG Spectral Synthesis Codes to Account for Zeeman Broadening of Spectral Lines

    NASA Astrophysics Data System (ADS)

    Deen, Casey P.

    2013-09-01

    In an attempt to widen access to the study of magnetic fields in stellar astronomy, I present MOOGStokes, a version of the MOOG one-dimensional local thermodynamic equilibrium radiative transfer code, overhauled to incorporate a Stokes vector treatment of polarized radiation through a magnetic medium. MOOGStokes is a suite of three complementary programs, which together can synthesize the disk-averaged emergent spectrum of a star with a magnetic field. The first element (a pre-processing script called CounterPoint) calculates for a given magnetic field strength, wavelength shifts, and polarizations for the components of Zeeman-sensitive lines. The second element (a MOOG driver called SynStokes derived from the existing MOOG driver Synth) uses the list of Zeeman-shifted absorption lines together with the existing machinery of MOOG to synthesize the emergent spectrum at numerous locations across the stellar disk, accounting for stellar and magnetic field geometry. The third and final element (a post-processing script called DiskoBall) calculates the disk-averaged spectrum by weighting the individual emergent spectra by limb darkening and projected area, and applying the effects of Doppler broadening. All together, the MOOGStokes package allows users to synthesize emergent spectra of stars with magnetic fields in a familiar computational framework. MOOGStokes produces disk-averaged spectra for all Stokes vectors ( I, Q, U, V ), normalized by the continuum. MOOGStokes agrees well with the predictions of INVERS10 a polarized radiative transfer code with a long history of use in the study of stellar magnetic fields. In the non-magnetic limit, MOOGStokes also agrees with the predictions of the scalar version of MOOG.

  7. Temperature dependence of 13CH4 line shapes broadened by N2

    NASA Astrophysics Data System (ADS)

    Sung, K.; Mantz, A. M.; Brown, L. R.; Smith, M. H.; Benner, D. C.; Devi, V.; Crawford, T. J.

    2009-12-01

    In order to support remote sensing of Titan’s atmosphere, the temperature dependences for the 13CH4 nitrogen broadening and frequency shift coefficients were measured for several transitions from 1200 to 1400 cm-1 (8.33 to 7.14 μm) using a Fourier transform spectrometer (Bruker IFS-125HR) newly configured with a temperature stabilized cryogenic absorption cell at the Jet Propulsion Laboratory. The cryogenic cell is mounted on the cold finger of a closed cycle helium refrigerator, and the temperatures are monitored with Si diode sensors. The wedged ZnSe cell windows are vacuum sealed with crushed indium gaskets. The cell has an optical path of 24 cm and is suspended from the top cover of the evacuated sample compartment. It has demonstrated a temperature stability of better than ±0.01 K at all temperatures between 300 K and 90 K. To test the system performance, we first recorded 10 spectra of the ν4 band of 13CH4 broadened by nitrogen at 0.0056 cm-1 instrumental resolution (Resolving power = 232000) using a HgCdTe detector. The pressures of 13CH4+N2 mixtures ranged from 140 to 796 torr with the volume mixing ratios of 13CH4 varying between 0.001 and 0.012 at 296, 255, 225 and 180 K. Line shape parameters in the spectral region from 1200 to 1400 cm-1 were retrieved using the nonlinear least squares multispectrum technique1, fitting selected wavenumber intervals of all spectra simultaneously to determine temperature dependence. Preliminary results from the temperature dependence measurements at planetary and astrophysical temperatures are reported along with detailed discussion of the instrumental setup. This new spectroscopic capability at the Jet Propulsion Laboratory will enable future research in studies of planetary science and astrophysics2. 1 Benner DC, Rinsland CP, Devi VM, Smith MAH, Atkins D. A multispectrum nonlinear least squares fitting technique. JQSRT 53, 705 - 721 (1995). 2 The research at the Jet Propulsion Laboratory (JPL), California Institute

  8. Quasicontiguous frequency-fluctuation model for calculation of hydrogen and hydrogenlike Stark-broadened line shapes in plasmas.

    PubMed

    Stambulchik, E; Maron, Y

    2013-05-01

    We present an analytical method for the calculation of shapes of Stark-broadened spectral lines in plasmas, applicable to hydrogen and hydrogenlike transitions (including Rydberg ones) with Δn>1. The method is based on the recently suggested quasicontiguous approximation of the static Stark line shapes, while the dynamical effects are accounted for using the frequency-fluctuation-model approach. Comparisons with accurate computer simulations show excellent agreement.

  9. Broadening of fast-beam spectral lines due to diffraction at the entrance slit of a spectrometer.

    NASA Technical Reports Server (NTRS)

    Leavitt, J. A.; Stoner, J. O., Jr.

    1972-01-01

    Experimental and theoretical demonstration of the necessity to take into account the effects of diffraction at a spectrometer's entrance slit in adjusting the spectrometer for observation of fast-beam spectral lines under conditions of minimum linewidth. An approximate expression is obtained for the optimum entrance slit width to be used in order to avoid the pronounced broadening of the spectral lines that occurs for very narrow entrance slits.

  10. A line-broadening analysis model for the microstructural characterization of nanocrystalline materials from asymmetric x-ray diffraction peaks

    NASA Astrophysics Data System (ADS)

    Pantoja-Cortés, Juan; Sánchez-Bajo, Florentino; Ortiz, Angel L.

    2012-05-01

    Nanograin sizes and crystal lattice microstrains in nanocrystalline materials are typically evaluated from the broadening of their x-ray diffraction (XRD) peaks under the assumption of symmetrical diffraction profiles. Since this assumption is not entirely satisfactory, we formulate a line-broadening analysis model of a single peak that considers explicitly the XRD peak asymmetry. The model is a generalization of the variance method in which the shape of the XRD peaks is idealized through asymmetrical split pseudo-Voigt functions. The model is validated on two nanocrystalline powders.

  11. A line-broadening analysis model for the microstructural characterization of nanocrystalline materials from asymmetric x-ray diffraction peaks.

    PubMed

    Pantoja-Cortés, Juan; Sánchez-Bajo, Florentino; Ortiz, Angel L

    2012-05-30

    Nanograin sizes and crystal lattice microstrains in nanocrystalline materials are typically evaluated from the broadening of their x-ray diffraction (XRD) peaks under the assumption of symmetrical diffraction profiles. Since this assumption is not entirely satisfactory, we formulate a line-broadening analysis model of a single peak that considers explicitly the XRD peak asymmetry. The model is a generalization of the variance method in which the shape of the XRD peaks is idealized through asymmetrical split pseudo-Voigt functions. The model is validated on two nanocrystalline powders.

  12. Air- and Self-Broadened Half Widths, Pressure-Induced Shifts, and Line Mixing in the Nu(sub 2) Band of (12)CH4

    NASA Technical Reports Server (NTRS)

    Smith, M. A. H.; Benner, D. Chris; Pedroi-Cross, A.; Devi, V. Malathy

    2013-01-01

    Lorentz self- and air-broadened half width and pressure-induced shift coefficients and their dependences on temperature have been measured from laboratory absorption spectra for nearly 130 transitions in the nu(sub 2) band of (12)CH4. In addition line mixing coefficients (using the relaxation matrix element formalism) for both self- and airbroadening were experimentally determined for the first time for a small number of transitions in this band. Accurate line positions and absolute line intensities were also determined. These parameters were obtained by analyzing high-resolution (approx. 0.003 to 0.01 per cm) laboratory spectra of high-purity natural CH4 and air-broadened CH4 recorded at temperatures between 226 and 297 K using the McMath-Pierce Fourier transform spectrometer (FTS) located at the National Solar Observatory on Kitt Peak, Arizona. A multispectrum nonlinear least squares technique was used to fit short (5-15 per cm) spectral intervals in 24-29 spectra simultaneously. Parameters were determined for nu(sub 2) transitions up to J" = 16. The variations of the measured broadening and shift parameters with the rotational quantum number index and tetrahedral symmetry species are examined. The present results are also compared with previous measurements available in the literature.

  13. Theoretical and revisited experimentally retrieved He-broadened line parameters of carbon monoxide in the fundamental band

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, A.; Esteki, K.; Rozario, H.; Naseri, H.; Latif, S.; Thibault, F.; Malathy Devi, V.; Smith, M. A. H.; Mantz, A. W.

    2016-11-01

    We report revisited experimentally retrieved and theoretically calculated He-broadened Lorentz half-width coefficients and He- pressure-shift coefficients of 45 carbon monoxide transitions in the 1←0 band. The spectra analyzed in this study were recorded over a range of temperatures between 79 and 296 K. The He-broadened line parameters and their temperature dependences were retrieved using a multispectrum nonlinear least squares analysis program. The line shape models used in this study include Voigt, speed dependent Voigt, Rautian (to take into account confinement narrowing) and Rautian with speed dependence, all with an asymmetric component added to account for weak line mixing effects. We were unable to retrieve the temperature dependence of line mixing coefficients. A classical method was used to determine the He-narrowing parameters while quantum dynamical calculations were performed to determine He-broadening and He-pressure shifts coefficients at different temperatures. The line mixing coefficients were also derived from the exponential power gap law and the energy corrected sudden approximation. The current measurements and theoretical results are compared with other published results, where appropriate.

  14. Pulse-driven non-linear Alfvén waves and their role in the spectral line broadening

    NASA Astrophysics Data System (ADS)

    Chmielewski, P.; Srivastava, A. K.; Murawski, K.; Musielak, Z. E.

    2013-01-01

    We study the impulsively generated non-linear Alfvén waves in the solar atmosphere and describe their most likely role in the observed non-thermal broadening of some spectral lines in solar coronal holes. We solve numerically the time-dependent magnetohydrodynamic equations to find temporal signatures of large-amplitude Alfvén waves in the solar atmosphere model of open and expanding magnetic field configuration, with a realistic temperature distribution. We calculate the temporally and spatially averaged, instantaneous transversal velocity of non-linear Alfvén waves at different heights of the model atmosphere and estimate its contribution to the unresolved non-thermal motions caused by the waves. We find that the pulse-driven non-linear Alfvén waves with the amplitude Av = 50 km s- 1 are the most likely candidates for the non-thermal broadening of Si viii λ1445.75 Å line profiles in the polar coronal hole as reported by Banerjee et al. We also demonstrate that the Alfvén waves driven by comparatively smaller velocity pulse with amplitude Av = 25 km s- 1 may contribute to the spectral line width of the same line at various heights in coronal hole broadening. We conclude that the non-linear Alfvén waves excited impulsively in the lower solar atmosphere may be responsible for the observed spectral line broadening in polar coronal holes. This is an important result as it allows us to conclude that such large amplitude and pulse-driven Alfvén waves may indeed exist in solar coronal holes. The existence of these waves may impart the required momentum to accelerate the solar wind.

  15. Cavity ring-down spectroscopy of Doppler-broadened absorption line with sub-MHz absolute frequency accuracy.

    PubMed

    Cheng, C-F; Sun, Y R; Pan, H; Lu, Y; Li, X-F; Wang, J; Liu, A-W; Hu, S-M

    2012-04-23

    A continuous-wave cavity ring-down spectrometer has been built for precise determination of absolute frequencies of Doppler-broadened absorption lines. Using a thermo-stabilized Fabry-Pérot interferometer and Rb frequency references at the 780 nm and 795 nm, 0.1 - 0.6 MHz absolute frequency accuracy has been achieved in the 775-800 nm region. A water absorption line at 12579 cm(-1) is studied to test the performance of the spectrometer. The line position at zero-pressure limit is determined with an uncertainty of 0.3 MHz (relative accuracy of 0.8 × 10(-9)).

  16. Nonadiabatic theory of atomic line broadening: Redistribution calculations for Sr(/sup 1/Preverse arrow /sup 1/S)+Ar

    SciTech Connect

    Julienne, P.S.; Mies, F.H.

    1986-11-01

    The close-coupled theory of collisions in a radiation field is used to calculate the absorption profile for the Sr /sup 1/Preverse arrow/sup 1/S resonance line broadened by collisions with Ar. The calculations predict the polarization ratios of Sr /sup 1/P fluorescence following line wing excitation by either linear or circular polarized light. Ab initio calculations were used to obtain the ground and excited SrAr molecular-potential curves, which were adjusted to give improved agreement with experiment. The radiative-scattering theory gives a unified description of the absorption coefficient and polarization redistribution from the small detuning impact limit region to the far spectral wings. The cross sections for elastic and inelastic depolarizing collisions of Sr /sup 1/P/sub 1/+Ar were also calculated. The calculated absorption coefficient, impact-broadening rate, linear- and circular-polarization ratios, and depolarization rate coefficients are for the most part in good agreement with experiment.

  17. Thermal Line Shift and Broadening of Ho(3+) in Y3AI5O12 and Lu3AIO12

    NASA Technical Reports Server (NTRS)

    Snoke, Elizabeth R.; Armagan, Guzin; Grew, Gary W.; Barnes, Norman P.; Walsh, Brian M.

    1995-01-01

    The interaction between the active ion and the host lattice manifests itself in two distinct ways: the static interaction with the crystal field that causes the splitting of the free ion energy levels and the active interaction through the surrounding phonon system that produces temperature dependent characteristics in the optical spectrum of the ion (e.g. line broadening and line shift). The strength of the splitting depends heavily on the electronic configuration of the atom. The model give by McCumber and Sturge describes the thermal effects on line width and position above 77 K with Raman scattering of Debye model phonons. These processes predict a Lorentzian line shape. However, below 77 K the principal contributions are from crystal inhomogeneities that result in a Gaussian line shape. We have investigated the experimental Stark levels as well as the thermal effects on the line width and the position of trivalent holmium ions in both yttrium aluminum garnet, Y3Al5O12 (YAG) and lutetium aluminum garnet, Lu3Al5O12 (LuAG) crystals. We have compared the Stark levels of the (5)I(6) state, and the thermal line shift and broadening of an isolated transition (Z2 to X13) between the (5)I(8) and (5)I(6) stark levels in these crystals. This transition occurs in the near infrared region at approximately 1117 nm.

  18. Experimental air-broadened line parameters in the nu(2) band of CH3D

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, Adriana; Brawley-Tremblay, Shannon; Povey, Chad; Smith, Mary Ann H.

    2007-02-01

    In this study, we report the first experimental measurements of air-broadening and air-induced pressure-shift coefficients for approximately 378 transitions in the nu(2) fundamental band of CH3D. These results were obtained from analysis of 17 room-temperature laboratory absorption spectra recorded at 0.0056 cm(-1) resolution using the McMath-Pierce Fourier transform spectrometer located on Kitt Peak, Ariz. Three absorption cells with path lengths of 10.2, 25, and 150 cm were used to record the spectra. The total sample pressures ranged from 0.129 x 10(-2) to 52.855 x 10(-2) atm with CH3D volume mixing ratios of approximately 0.0109 in air. The spectra were analyzed using a multispectrum nonlinear least-squares fitting technique. We report measurements for air pressure-broadening coefficients for transitions with quantum numbers as high as J'' D 20 and K D 15, where K'' D K' equivalent to K (for a parallel band). The measured air-broadening coefficients range from 0.0205 to 0.0835 cm(-1)atm(-1) at 296 K. All the measured pressure-shift coefficients are negative and are found to vary from about -0.0005 to -0.0080 cm(-1) atm(-1) at the temperature of the spectra. We have examined the dependence of the measured broadening and shift parameters on the J'', and K quantum numbers and also developed empirical expressions to describe the broadening coefficients in terms of m (m D -J'', J'', and J'' + 1 in the P-Q-, (Q)Q-, and R-Q-branch, respectively) and K. On average, the empirical expressions reproduce the measured broadening coefficients to within 4.4%.

  19. Collisional Shift and Broadening of Iodine Spectral Lines in Air Near 543 nm

    NASA Technical Reports Server (NTRS)

    Fletcher, D. G.; McDaniel, J. C.

    1995-01-01

    The collisional processes that influence the absorption of monochromatic light by iodine in air have been investigated. Measurements were made in both a static cell and an underexpanded jet flow over the range of properties encountered in typical compressible-flow aerodynamic applications. Experimentally measured values of the collisional shift and broadening coefficients were 0.058 +/- 0.004 and 0.53 +/- 0.010 GHz K(exp 0.7)/torr, respectively. The measured shift value showed reasonable agreement with theoretical calculations based on Lindholm-Foley collisional theory for a simple dispersive potential. The measured collisional broadening showed less favorable agreement with the calculated value.

  20. Visual observations of macroscopic inhomogeneous broadening of the R1 line in ruby

    NASA Astrophysics Data System (ADS)

    Jessop, P. E.; Szabo, A.

    1980-09-01

    Observation of sharp spatial variations of the R1 fluorescence of ruby at 5 K resonantly excited by a 1-MHz-linewidth scanning cw dye laser indicates the presence of gross macroscopic strain broadening in Czochralski and Verneuil crystals. The implications of these results in several current studies are discussed.

  1. Broadening of CO2 lines in the 4.3 μm region by H2O

    NASA Astrophysics Data System (ADS)

    Delahaye, T.; Landsheere, X.; Pangui, E.; Huet, F.; Hartmann, J.-M.; Tran, H.

    2016-08-01

    Transmission spectra of CO2 highly diluted in water vapor have been recorded at 50 and 95 °C for four pressures between 0.02 and 0.1 atm using a high resolution Fourier Transform spectrometer. The collisional (Lorentz) widths of many lines of the ν3 band (and of some of the ν3 + ν2 - ν2 hot band) have been retrieved from each spectrum through fits using Voigt line shapes. Our result are about 4% lower than the values recommended in a previous study but they confirm the relative variations of the line broadening on the rotational quantum numbers. We also provide the first determination of H2O-induced line shifts of CO2 lines.

  2. Laser absorption spectroscopy of water vapor confined in nanoporous alumina: wall collision line broadening and gas diffusion dynamics.

    PubMed

    Svensson, Tomas; Lewander, Märta; Svanberg, Sune

    2010-08-02

    We demonstrate high-resolution tunable diode laser absorption spectroscopy (TDLAS) of water vapor confined in nanoporous alumina. Strong multiple light scattering results in long photon pathlengths (1 m through a 6 mm sample). We report on strong line broadening due to frequent wall collisions (gas-surface interactions). For the water vapor line at 935.685 nm, the HWHM of confined molecules are about 4.3 GHz as compared to 2.9 GHz for free molecules (atmospheric pressure). Gas diffusion is also investigated, and in contrast to molecular oxygen (that moves rapidly in and out of the alumina), the exchange of water vapor is found very slow.

  3. A far wing line shape theory and its application to the foreign-broadened water continuum absorption. III

    NASA Technical Reports Server (NTRS)

    Ma, Q.; Tipping, R. H.

    1992-01-01

    The far wing line shape theory developed previously and applied to the calculation of the continuum absorption of pure water vapor is extended to foreign-broadened continua. Explicit results are presented for H2O-N2 and H2O-CO2 in the frequency range from 0 to 10,000/cm. For H2O-N2 the positive and negative resonant frequency average line shape functions and absorption coefficients are computed for a number of temperatures between 296 and 430 K for comparison with available laboratory data. In general the agreement is very good.

  4. Temperature-Dependence of Air-Broadened Line Widths and Shifts in the nu3 Band of Ozone

    NASA Technical Reports Server (NTRS)

    Smith, Mary A. H.; Rinsland, Curtis P.; Devi, V. Malathy; Benner, D. Chris; Cox, A. M.

    2006-01-01

    The 9.6-micron bands of O3 are used by many remote-sensing experiments for retrievals of terrestrial atmospheric ozone concentration profiles. Line parameter errors can contribute significantly to the total errors in these retrievals, particularly for nadir-viewing. The McMath-Pierce Fourier transform spectrometer at the National Solar Observatory on Kitt Peak was used to record numerous high-resolution infrared absorption spectra of O3 broadened by various gases at temperatures between 160 and 300 K. Over 30 spectra were analyzed simultaneously using a multispectrum nonlinear least squares fitting technique to determine Lorentz air-broadening and pressure-induced shift coefficients along with their temperature dependences for selected transitions in the 3 fundamental band of (16)O3. We compare the present results with other measurements reported in the literature and with the ozone parameters on the 2000 and 2004 editions of the HITRAN database.

  5. Measurement and calculation of the Stark-broadening parameters for the resonance lines of singly ionized calcium and magnesium.

    NASA Technical Reports Server (NTRS)

    Jones, W. W.; Sanchez, A.; Greig, J. R.; Griem, H. R.

    1972-01-01

    The electron-impact-broadened profiles of the resonance lines of singly ionized calcium and magnesium have been measured using an electromagnetically driven shock tube and a rapid-scanning Fabry-Perot spectrometer. For an electron density of 10 to the 17th power per cu cm and a temperature of 19,000 K, we found the Lorentzian half-width of the Ca+ line to be 0.086 A plus or minus 10% and of the Mg+ line to be 0.044 A plus or minus 10%. Using the quantum-mechanical theory of Barnes and Peach and our semiclassical calculation for the calcium lines, we found that the temperature dependence of the theoretical curves is close to that measured, although both theories predict actual values which are somewhat large.

  6. Comments on alternative calculations of the broadening of spectral lines of neutral sodium by H-atom collisions

    NASA Astrophysics Data System (ADS)

    Barklem, P. S.; O'Mara, B. J.

    2001-12-01

    With the exception of the sodium D-lines, recent calculations of line broadening cross sections for several multiplets of sodium by Leininger et al (Leininger T, Gadéa F X and Dickinson A 2000 J. Phys. B: At. Mol. Opt. Phys. 33 1805) are in substantial disagreement with cross sections interpolated from the tables of Anstee and O'Mara (Anstee and O'Mara 1995 Mon. Not. R. Astron. Soc. 276 859) and Barklem and O'Mara (Barklem P S and O'Mara B J 1997 Mon. Not. R. Astron. Soc. 290 102). The discrepancy is as large as a factor of 3 for the 3p-4d multiplet. The two theories are tested by using the results of each to synthesize lines in the solar spectrum. It is found that generally the data from the theory of Anstee, Barklem and O'Mara produce the best match to the observed solar spectrum. It is found, using a simple model for reflection of the optical electron by the potential barrier between the two atoms, that the reflection coefficient is too large for avoided crossings with the upper states of subordinate lines to contribute to line broadening, supporting the neglect of avoided ionic crossings by Anstee, Barklem and O'Mara for these lines. The large discrepancies between the two sets of calculations is a result of an approximate treatment of avoided ionic crossings for these lines by Leininger et al (Leininger T, Gadéa F X and Dickinson A 2000 J. Phys. B: At. Mol. Opt. Phys. 33 1805).

  7. Line intensities and temperature-dependent line broadening coefficients of Q-branch transitions in the v2 band of ammonia near 10.4 μm

    NASA Astrophysics Data System (ADS)

    Sur, Ritobrata; Spearrin, R. Mitchell; Peng, Wen Y.; Strand, Christopher L.; Jeffries, Jay B.; Enns, Gregory M.; Hanson, Ronald K.

    2016-05-01

    We report measured line intensities and temperature-dependent broadening coefficients of NH3 with Ar, N2, O2, CO2, H2O, and NH3 for nine sQ(J,K) transitions in the ν2 fundamental band in the frequency range 961.5-967.5 cm-1. This spectral region was chosen due to the strong NH3 absorption strength and lack of spectral interference from H2O and CO2 for laser-based sensing applications. Spectroscopic parameters were determined by multi-line fitting using Voigt lineshapes of absorption spectra measured with two quantum cascade lasers in thermodynamically-controlled optical cells. The temperature dependence of broadening was measured over a range of temperatures between 300 and 600 K. These measurements aid the development of mid-infrared NH3 sensors for a broad range of gas mixtures and at elevated temperatures.

  8. Microscopic nature of inhomogeneous line broadening: Analysis of the excitation-line-narrowing spectra of Cf4+ in CeF4

    NASA Astrophysics Data System (ADS)

    Liu, G. K.; Huang, Jin; Beitz, James V.

    1993-11-01

    Optical transitions between 5f states of tetravalent californium ion doped (1 metal-atom %) into CeF4 exhibit unusually large inhomogeneous broadening. The nature of the inhomogeneous broadening in this system has been studied by using fluorescence line narrowing and excitation line narrowing (ELN). It is shown that the energy distributions of different electronic states of Cf4+ in this system are correlated. In the ELN experiments, reduced excitation linewidth was obtained when selectively monitoring fluorescence emission. A linear relation was observed between the excitation energies of crystal-field states of the G54' manifold and the fluorescence wavelength monitored across the inhomogeneous profile of a G56'-F76' transition. Analysis of these results by means of a microscopic theory proposed by Laird and Skinner [J. Chem. Phys. 90, 3880 (1989)] has provided insights into the structural properties of this disordered system.

  9. Stark broadening for diagnostics of the electron density in non-equilibrium plasma utilizing isotope hydrogen alpha lines

    SciTech Connect

    Yang, Lin; Tan, Xiaohua; Wan, Xiang; Chen, Lei; Jin, Dazhi; Qian, Muyang; Li, Gongping

    2014-04-28

    Two Stark broadening parameters including FWHM (full width at half maximum) and FWHA (full width at half area) of isotope hydrogen alpha lines are simultaneously introduced to determine the electron density of a pulsed vacuum arc jet. To estimate the gas temperature, the rotational temperature of the C{sub 2} Swan system is fit to 2500 ± 100 K. A modified Boltzmann-plot method with b{sub i}-factor is introduced to determine the modified electron temperature. The comparison between results of atomic and ionic lines indicates the jet is in partial local thermodynamic equilibrium and the electron temperature is close to 13 000 ± 400 K. Based on the computational results of Gig-Card calculation, a simple and precise interpolation algorithm for the discrete-points tables can be constructed to obtain the traditional n{sub e}-T{sub e} diagnostic maps of two Stark broadening parameters. The results from FWHA formula by the direct use of FWHM = FWHA and these from the diagnostic map are different. It can be attributed to the imprecise FWHA formula form and the deviation between FWHM and FWHA. The variation of the reduced mass pair due to the non-equilibrium effect contributes to the difference of the results derived from two hydrogen isotope alpha lines. Based on the Stark broadening analysis in this work, a corrected method is set up to determine n{sub e} of (1.10 ± 0.08) × 10{sup 21} m{sup −3}, the reference reduced mass μ{sub 0} pair of (3.30 ± 0.82 and 1.65 ± 0.41), and the ion kinetic temperature of 7900 ± 1800 K.

  10. Determination of ion temperatures from Zeeman broadened spectral lines in the edge of Tore Supra

    SciTech Connect

    Klepper, C.C.; Isler, R.C.; Tobin, S.J.; Hogan, J.T.; Hess, W.R.

    1994-09-01

    The authors have examined a {sup 3}P {yields} {sup 3}S multiplet of C III in Tore Supra in order to assess the possibility of determining the ion temperatures from transitions where the Zeeman effect cannot be neglected compared to the Doppler broadening. The preliminary studies lead them to believe that with good quality data the temperatures can be determined within about 20% in the 20--30 eV range and within about 50% in the neighborhood of 5 eV by fitting the entire multiplet rather than a semi-isolated feature, even though certain parameters important for the analysis, such as polarization effects of the optics, are not well characterized. In order to quantify these conclusions more precisely, future work will concentrate on developing numerical fitting routines and on examining the validity of the assumption that the distribution function for low ionization stages is Maxwellian.

  11. Shift and width measurements of the Stark-broadened ionized helium line at 1215 A

    NASA Technical Reports Server (NTRS)

    Van Zandt, J. R.; Adcock, J. C., Jr.; Griem, H. R.

    1976-01-01

    Time-resolved photoelectric measurements were made of the shifts of helium plasma lines at 1640 A and 1215 A and of the Stark profile of the 1215 A line, using an electromagnetic shock tube as a light source. These red shifts are consistent with a plasma polarization shift, where the interaction energy between the radiating ion and the perturbing plasma electrons corresponds to the Coulomb interaction near the excited state Bohr radius. No significant shifts were observed for the 1640 A line, while the 1215 A line underwent a red shift of about 0.5 A. The measured Stark width of the 1215 A line was 10-45% greater than the calculated width based on the measured width of the 4686 A line.

  12. Comparison of experimental and theoretical pressure-broadened atomic line shapes.

    NASA Technical Reports Server (NTRS)

    Atakan, A. K.; Jacobson, H. C.

    1972-01-01

    Line-structure calculations of the longer wavelength resonance line of cesium pressurized by argon are compared with experimental values over a range of perturber relative densities from 0.5 to 61. The main features of the line shapes are reproduced by the general pressures method using Lennard-Jones potentials. The calculations indicate that results are very sensitive to the potential parameters employed, but are not sensitive to changes in the temperature. The data are also compared with the method that makes the quasi-static approximation and with the high-pressure limit that leads to a Gaussian line profile. The former technique yields good agreement over the range of pressures where the approximation is warranted, and the latter appears to have several disadvantages.

  13. Pressure broadening and shift of K D1 and D2 lines in the presence of 3He and 21Ne

    NASA Astrophysics Data System (ADS)

    Li, Rujie; Li, Yang; Jiang, Liwei; Quan, Wei; Ding, Ming; Fang, Jiancheng

    2016-06-01

    Due to the collisions with alkali-metal atoms, the buffer gases used in spin-exchange optical pumping systems induce a broadening of spectral profiles and a shift in the resonance frequency. Here we report the pressure broadening and shift rates of K D 1 and D 2 lines in the presence of 21Ne for the first time and values for 3He have been reinvestigated by means of laser absorption spectroscopy. We have also examined the temperature dependence of these collisional effects in a range of 435-458 K. A comparison for the broadening and shift rates to those of other isotopes, 4He and 20Ne, is presented.

  14. Uncertainties Associated with Theoretically Calculated N2-Broadened Half-Widths of H2O Lines

    NASA Technical Reports Server (NTRS)

    Ma, Q.; Tipping, R. H.; Gamache, R. R.

    2010-01-01

    With different choices of the cut-offs used in theoretical calculations, we have carried out extensive numerical calculations of the N2-broadend Lorentzian half-widths of the H2O lines using the modified Robert-Bonamy formalism. Based on these results, we are able to thoroughly check for convergence. We find that, with the low-order cut-offs commonly used in the literature, one is able to obtain converged values only for lines with large half-widths. Conversely, for lines with small half-widths, much higher cut-offs are necessary to guarantee convergence. We also analyse the uncertainties associated with calculated half-widths, and these are correlated as above. In general, the smaller the half-widths, the poorer the convergence and the larger the uncertainty associated with them. For convenience, one can divide all H2O lines into three categories, large, intermediate, and small, according to their half-width values. One can use this division to judge whether the calculated half-widths are converged or not, based on the cut-offs used, and also to estimate how large their uncertainties are. We conclude that with the current Robert- Bonamy formalism, for lines in category lone can achieve the accuracy requirement set by HITRAN, whereas for lines in category 3, it 'is impossible to meet this goal.

  15. Precision considerations of classical and semiclassical methods used in collision line broadening calculations: Different linear molecules perturbed by argon

    NASA Astrophysics Data System (ADS)

    Ivanov, Sergey V.; Buzykin, Oleg G.

    2013-04-01

    The accuracies of the classical and semiclassical methods currently used in collisional spectral line broadening calculations of molecules are compared. The primary goal is to elucidate the validity of each particular method applied to linear molecules that have different rotational constants but which are perturbed by the same atom. Vibration-rotational electric dipole absorption spectra of CO2, C2H2, CO, HCl and HF molecules perturbed by an Ar atom are examined at room temperature. The most accurate vibrationally independent potential energy surfaces (PESs) are applied to all molecular pairs. The following theoretical approaches are involved in cross-examination: two classical schemes (exact C3D and C3Diso) and four semiclassical formalisms (NG—of Neilsen and Gordon, PA—peaking approximation, SGC—of Smith, Giraud and Cooper, and RB—of Robert and Bonamy). Identical “exact” isotropic trajectories, driven by only the isotropic part of the PES, are used in C3Diso and in all semiclassical calculations. The comparison is made with experimental data as well as with benchmark quantum dynamical results obtained in the same conditions within close coupling and coupled states schemes. Quantum results reproduced the experimental data excellently in all cases considered, which is as it should be if the interaction PES is accurate. An exact classical C3D approach displays good results for all molecules. By contrast, NG, PA and SGC semiclassical formalisms seriously underestimate line broadening for molecules with small rotational constants (CO2, C2H2 and, to a lesser extent, CO), mainly due to the use of isotropic trajectories in these schemes. The RB method strongly overestimates line broadening for the majority of values of the rotational quantum number J for all molecules studied. The only exception is the case of HF molecules at high J values, where PA, SGC and RB semiclassical schemes provide good results, coinciding well with quantum CC calculations for J>3

  16. Line-shape study of self-broadened O{sub 2} transitions measured by Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectroscopy

    SciTech Connect

    Wojtewicz, S.; Lisak, D.; Cygan, A.; Domyslawska, J.; Trawinski, R. S.; Ciurylo, R.

    2011-09-15

    We present high-sensitivity and high-spectral-resolution line-shape and line-intensity measurements of self-broadened O{sub 2} b {sup 1}{Sigma}{sub g}{sup +}(v=1)(leftarrow)X {sup 3}{Sigma}{sub g}{sup -}(v=0) band transitions measured using the Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectroscopy technique. We give collisional broadening parameters and take into account the line-narrowing effects described by Dicke narrowing or the speed dependence of collisional broadening. We compare line intensities measured with relative uncertainties below 0.4% to data available in the HITRAN spectroscopic database.

  17. The broadening of the calcium resonance line in a high-temperature helium atmosphere. [solar and white dwarf atmospheric studies

    NASA Technical Reports Server (NTRS)

    Driver, R. D.; Snider, J. L.

    1976-01-01

    The paper describes experimental measurements of the shape of the Ca I resonance line at 4227 A in a high-temperature helium atmosphere. A ballistic piston compressor was used to produce hot helium in the temperature range from 3000 to 7000 K and the number-density range from 2 to 4 by 10 to the 20th power per cu cm, which conditions approximate those postulated for the atmospheres of certain cool white-dwarf stars. The Boltzmann temperature of the calcium atoms was measured by the brightness-emissivity method, the absorption line shape was measured with a twelve-channel polychromator, and the helium kinetic temperature was calculated from the equation of an ideal gas. The observed deviation from thermodynamic equilibrium is illustrated. The value of the ratio of the damping constant to the helium number density at 5000 K is found to be 45 (+ or - 4) by 10 to the -22nd power A cu cm, or 4.7 (+ or - 0.4) by 10 to the -9th power rad/s cu cm. It is noted that no existing line-broadening calculation for the calcium-helium system is consistent with the present results. Recent studies of the 4227-A line in spectra of the sun and the white dwarf van Maanen 2 are discussed.

  18. Stark broadening of isolated lines from high-Z emitters in dense plasmas

    SciTech Connect

    Weisheit, J.C.; Pollock, E.L.

    1980-09-01

    The joint distribution of the electric microfield and its longitudinal derivative is required for the calculation of line profiles for the He-like ions in very dense plasmas. We used a molecular dynamics code to compute exact distributions in single- and multi-component plasmas, and then we investigated various analytical approximations to these results. We found that a simplified, two-nearest-neighbor scheme leads to surprisingly accurate distribution functions. Our results are illustrated by sample profiles for Ne/sup +8/ and Ar/sup +16/ resonance lines.

  19. The Broadening of Spectral Lines by Autoionization, Radiative Transitions, and Collisions.

    DTIC Science & Technology

    1980-10-22

    nnounced Justif icai ¢:c Distr -- / Av~a..’ ’ "Co~es fl/-i iii st THE BRAODENING OF SPECTRAL LINES BY AUTOIONIZATION, RADIATIVE TRANSITIONS, AND...of NY Physics Department Stony Brook, New York 11794 Meerut College Meerut, 250001 India Meyerhof, W.E. Department of Physics Stanford University

  20. The broadening of calcium II H and K lines by helium. [white dwarf atmosphere simulation

    NASA Technical Reports Server (NTRS)

    Hammond, G. L.

    1975-01-01

    Laboratory measurements of widths and shifts of the Ca II H and K lines have been made under conditions simulating those in the atmospheres of metallic-line white dwarfs, namely, densities of 10 to the 21st power helium atoms per cu cm and temperatures of 4500 to 6000 K. There are significant differences in the shifts and damping constants of the two fine-structure components. The impact theory is evidently applicable to the Ca II/He system under these conditions, and the observed damping constants are fortuitously close to the predictions of conventional Lindholm-Foley/van der Waals theory. The widths and shifts have also been analyzed in terms of Lennard-Jones potential theory.

  1. N2-, O2- and He-collision-induced broadening of sulfur dioxide ro-vibrational lines in the 9.2 μm atmospheric window

    NASA Astrophysics Data System (ADS)

    Tasinato, Nicola; Pietropolli Charmet, Andrea; Stoppa, Paolo; Giorgianni, Santi; Buffa, Giovanni

    2014-01-01

    Sulfur dioxide (SO2) is a molecule of considerable interest for both atmospheric chemistry and astrophysics. In the Earth's atmosphere, it enters in the sulfur cycle and it is ubiquitous present in polluted atmospheres, where it is responsible for acid rains. It is also of astrophysical and planetological importance, being present on Venus and in interstellar clouds. In this work the collisional broadening of a number of ν1 ro-vibrational lines of SO2 perturbed by N2, O2 and He are investigated at room temperature in the 9 μm atmospheric region by means of high resolution tunable diode laser (TDL) infrared spectroscopy. From N2- and O2-broadening coefficients, the broadening parameters of sulfur dioxide in air, useful for atmospheric applications, are derived as well. From the present measurements some conclusions on the quantum number dependence of the N2-, O2- and He-broadening coefficients are drawn. While the J dependence is weak for all the perturbers investigated, different trends with Ka are reported. N2-broadening coefficients show a slight decrease with increasing values of Ka, whereas O2 and He broadening cross sections first increase up to Ka″≈6 and then they keep a nearly constant value. A comparison and a brief discussion on the efficiency of self-, N2-, O2- and He-collisional dynamics are given. The data obtained represent a significant analysis on foreign broadening of SO2 useful for atmospheric remote sensing and astrophysical applications.

  2. Air-broadened Lorentz halfwidths and pressure-induced line shifts in the nu(4) band of C-13H4

    NASA Technical Reports Server (NTRS)

    Devi, V. Malathy; Benner, D. Chris; Rinsland, Curtis P.; Smith, Mary Ann H.

    1988-01-01

    Air-broadened halfwidths and pressure-induced line shifts in the nu(4) fundamental of C-13H4 were determined from spectra recorded at room temperature and at 0.01/cm resolution using a Fourier transform spectrometer. Halfwidths and pressure shifts were determined for over 180 transitions belonging to J-double prime values of less than or = to 16. Comparisons of air-broadened halfwidths and pressure-induced line shifts made for identical transitions in the nu(4) bands of C-12H4 and C-13H4 have shown that C-13H4 air-broadened halfwidths are about 5 percent smaller than the corresponding C-12H4 halfwidths, and the pressure shifts for C-13H4 lines are about 5-15 percent larger than those for C-12H4.

  3. Quantum-statistical T-matrix approach to line broadening of hydrogen in dense plasmas

    SciTech Connect

    Lorenzen, Sonja; Wierling, August; Roepke, Gerd; Reinholz, Heidi; Zammit, Mark C.; Fursa, Dmitry V.; Bray, Igor

    2010-10-29

    The electronic self-energy {Sigma}{sup e} is an important input in a quantum-statistical theory for spectral line profile calculations. It describes the influence of plasma electrons on bound state properties. In dense plasmas, the effect of strong, i.e. close, electron-emitter collisions can be considered by three-particle T-matrix diagrams. These digrams are approximated with the help of an effective two-particle T-matrix, which is obtained from convergent close-coupling calculations with Debye screening. A comparison with other theories is carried out for the 2p level of hydrogen at k{sub B}T = 1 eV and n{sub e} = 2{center_dot}10{sup 23} m{sup -3}, and results are given for n{sub e} = 1{center_dot}10{sup 25} m{sup -3}.

  4. Theoretical Studies of N2-broadened Half-widths of H2O Lines Involving High j States

    NASA Technical Reports Server (NTRS)

    Ma, Q.; Tipping, R. H.; Lavrentieva, N. N.

    2012-01-01

    Based on the properties of the energy levels and wave functions of H2O states, one can categorize H2O lines into individually defined groups such that within the same group, the energy levels and the wave functions associated with two paired lines have an identity property while those associated with different pairs have a similarity property. Meanwhile, by thoroughly analyzing processes used to calculate N2-broadened half-widths, it was found that the 'Fourier series' of W(sup a)(sub L(sub 1))(sub K(sub 1))(sub K(sub 1)) (t; j(sub f) T(sub f) and W(sup a)(sub L(sub 1))(sub K(sub 1))(sub K(sub 1)) (t; j(sub i) T(sub i), and a factor P(sub 222) (j(sub f) T(sub f) j(sub i) T(sub i)) are the key items in the Robert-Bonamy formalism to distinguish contributions to ReS2(r(sub c)) among different transitions of j(sub f) T(sub f) - j(sub i). However, these items are completely determined by the energy levels and the wave functions associated with their initial and final states and they must bear the latter's features as well. Thus, it becomes obvious that for two paired lines in the same group, their calculated half-widths must be almost identical and the values associated with different pairs must vary smoothly as their ji values vary. Thus, the pair identity and the smooth variation rules are established within individual groups of lines. One can use these rules to screen half-width data listed in HITRAN and to improve the data accuracies.

  5. Effect of buffer gases on broadening of the Iodine-127 resonance absorption line at a 633-nm He-Ne laser wavelength

    SciTech Connect

    Kireev, S.V.; Shnyrev, S.L.; Zaspa, Yu.P.

    1995-04-01

    Collisional broadening coefficients are measured for iodine-127 resonance absorption lines in several rare cases of atmospheric air and CO{sub 2}. The results obtained are used to determine the optimum pressure of a gaseous mixture in a measuring cell for detecting iodine-127 by a helium-neon (633 nm) laser-induced fluorescence technique of monitoring iodine in atmospheric air.

  6. Method of averaged energy differences of coupled states and other approaches for calculation line broadening parameters of HD16O transitions

    NASA Astrophysics Data System (ADS)

    Dudaryonok, A. S.; Voronin, B. A.; Lavrentieva, N. N.; Lugovskoy, A. A.; Starikov, V. I.

    2012-11-01

    Air-broadening coefficients of the water isotopologue HD16O up to J = 50 for P, Q and R branches calculated using different methods are presented. For partially labeled lines ("good" quantum numbers: J, symmetry and level number) we combined three methods for calculating half-widths: J-dependence and JJ'-dependence up to J=15 and averaging coefficients calculated using a previously developed semi-empirical method for high J (15-50). For lines with full assignments based on normal modes v1, v2, v3, Ka, Kc we used: (a) an analytical model (approximation) which depends on use of rotational quantum numbers J and Ka for both the upper and lower levels; and (b) a method based on the estimate of the averaged energy differences between coupled states. The comparison of calculated data with broadening coefficients from HITRAN-2008 and available experimental data is presented. The resulting broadening coefficients can be used to calculate spectra of water vapor with hundreds millions of weak lines with reasonable accuracy. The line list VTT [Voronin, Tennyson, Tolchenov, MNRAS, 2010], supporting programs, files for calculations of spectra HD16O and estimation of broadening coefficient are made freely available also in electronic form via http://www.exomol.com.

  7. Line parameters including temperature dependences of self- and air-broadened line shapes of 12C16O2: 1.6-μm region

    NASA Astrophysics Data System (ADS)

    Devi, V. Malathy; Benner, D. Chris; Sung, Keeyoon; Brown, Linda R.; Crawford, Timothy J.; Miller, Charles E.; Drouin, Brian J.; Payne, Vivienne H.; Yu, Shanshan; Smith, Mary Ann H.; Mantz, Arlan W.; Gamache, Robert R.

    2016-07-01

    Pressure-broadened line shapes in the 30013←00001 (ν1+4 ν20 +ν3) band of 12C16O2 at 6228 cm-1 are reanalyzed using new spectra recorded with sample temperatures down to 170 K. High resolution, high signal-to-noise (S/N) laboratory measurements of line shapes (Lorentz air- and self-broadened half-width coefficients, pressure-shift coefficients and off-diagonal relaxation matrix element coefficients) as a function of gas sample temperatures for various pressures and volume mixing ratios are presented. The spectra were recorded using two different Fourier transform spectrometers (FTS): (1) the McMath-Pierce FTS located at the National Solar Observatory on Kitt Peak, Arizona (and reported in Devi et al., J Mol Spectrosc 2007;245:52-80) and, (2) the Bruker IFS-125HR FTS at the Jet Propulsion Laboratory in Pasadena, California. The 19 spectra taken at Kitt Peak were all recorded near room temperature while the 27 Bruker spectra were acquired both at room temperature and colder temperatures (170-296 K). Various spectral resolutions (0.004-0.011 cm-1), absorption path lengths (2.46-121 m) and CO2 samples (natural and 12C-enriched) were included in the dataset. To maximize the accuracies of the various retrieved line parameters, a multispectrum nonlinear least squares spectrum fitting software program was used to adjust the ro-vibrational constants (G,B,D etc.) and intensity parameters (including Herman-Wallis terms) instead of directly measuring the individual line positions and intensities. To minimize systematic residuals, line mixing (via off-diagonal relaxation matrix elements) and quadratic speed dependence parameters were included in the analysis. Contributions from other weakly absorbing bands: the 30013←00001 and 30012←00001 bands of 13C16O2, the 30013←00001 band of 12C16O18O, hot bands 31113←01101 and 32212←02201 of 12C16O2, as well as the 40013←10001 and the 40014←10002 bands of 12C16O2, present within the fitted interval were also measured

  8. Tunable diode laser measurements of formaldehyde foreign-gas broadening parameters and line strengths in the 9-11-micron region

    NASA Technical Reports Server (NTRS)

    Nadler, Shachar; Reuter, Dennis C.; Daunt, Stephen J.

    1987-01-01

    A tunable diode laser spectrometer has been used to determine pressure broadening coefficients due to collision with the foreign gases air, H2, O2, and N2 in the nu4 and nu6 bands of H2CO between 9 and 11 microns. Absolute line strengths for twenty-eight transitions have also been determined. The broadening coefficients are very similar to theoretical literature values in the cases of air, N2, and O2. The H2-H2CO values are in good agreement with earlier experimental millimeter-wave results.

  9. Self- and N2-broadening of CH3Br ro-vibrational lines in the ν2 band: The J and K dependence

    NASA Astrophysics Data System (ADS)

    Boussetta, Z.; Kwabia Tchana, F.; Aroui, H.

    2015-02-01

    Methyl bromide (CH3Br) is the major source of inorganic bromine in the atmosphere and contributes significantly to ozone depletion. Indeed, CH3Br is dissociated by UV radiation, producing Br radicals that catalyze the destruction of ozone. In this paper, we report measured Lorentz self- and N2-broadening coefficients of CH3Br in the ν2 fundamental band using a mono-spectrum non-linear least squares fitting of Voigt profiles which appeared to properly model the observed molecular line shapes within the noise level. These measurements were made by analyzing 12 laboratory absorption spectra recorded at high resolution (0.005, 0.003 or 0.002 cm-1) using the Fourier transform spectrometer Bruker IF125HR located at the LISA facility in Créteil. The spectra were obtained at room temperature using a White-type multipass cell with an optical path of 0.849 m and various pressures. We have been able to determine the self- and N2-broadening coefficients of 948 ν2 transitions with quantum numbers as high as J = 49 and K = 10. The measured self-broadening coefficients range from 0.1542 to 0.4930 cm-1 atm-1 and the N2-broadening coefficients range from 0.0737 to 0.1284 cm-1 atm-1 at 295 K. The accuracy of the broadening coefficients measured in this work is between 4% and 8%, depending on the studied transition. Comparisons with measurements taken in the ν5 and ν6 bands of CH3Br did not show any clear vibrational dependence. The J and K dependences of the self- and N2-broadening coefficients have been observed and the rotational K dependence has been modeled using empirical polynomial expression. On average, the empirical expression reproduce the measured broadening coefficients to within 6%. The data obtained represent a significant contribution to the determination of broadening coefficients of CH3Br useful for atmospheric remote sensing and applications. Note: The assignment column gives the isotopologue (79 for CH379Br and 81 for CH381Br) for which the transition is

  10. Line parameters including temperature dependences of air- and self-broadened line shapes of 12C16O2: 2.06-μm region

    NASA Astrophysics Data System (ADS)

    Benner, D. Chris; Devi, V. Malathy; Sung, Keeyoon; Brown, Linda R.; Miller, Charles E.; Payne, Vivienne H.; Drouin, Brian J.; Yu, Shanshan; Crawford, Timothy J.; Mantz, Arlan W.; Smith, Mary Ann H.; Gamache, Robert R.

    2016-08-01

    This study reports the results from analyzing a number of high resolution, high signal-to-noise ratio (S/N) spectra in the 2.06-μm spectral region for pure CO2 and mixtures of CO2 in dry air. A multispectrum nonlinear least squares curve fitting technique has been used to retrieve the various spectral line parameters. The dataset includes 27 spectra: ten pure CO2, two 99% 13C-enriched CO2 and fifteen spectra of mixtures of 12C-enriched CO2 in dry air. The spectra were recorded at various gas sample temperatures between 170 and 297 K. The absorption path lengths range from 0.347 to 49 m. The sample pressures for the pure CO2 spectra varied from 1.1 to 594 Torr; for the two 13CO2 spectra the pressures were ∼10 and 146 Torr. For the air-broadened spectra, the pressures of the gas mixtures varied between 200 and 711 Torr with CO2 volume mixing ratios ranging from 0.014% to 0.203%. The multispectrum fitting technique was applied to fit simultaneously all these spectra to retrieve consistent set of line positions, intensities, and line shape parameters including their temperature dependences; for this, the Voigt line shape was modified to include line mixing (via the relaxation matrix formalism) and quadratic speed dependence. The new results are compared to select published values, including recent ab initio calculations. These results are required to retrieve the column averaged dry air mole fraction (XCO2) from space-based observations, such as the Orbiting Carbon Observatory-2 (OCO-2) satellite mission that NASA launched in July 2014.

  11. Measurements of argon broadened Lorentz width and pressure-induced line shift coefficients in the nu4 band of (C-12)H4

    NASA Technical Reports Server (NTRS)

    Rinsland, Curtis P.; Smith, Mary Ann H.; Devi, V. Malathy; Benner, D. Chris

    1989-01-01

    Room temperature argon broadened halfwidth and pressure-induced line shift coefficients have been determined for 118 transitions in the nu4 band of (C-12)H4 from analysis of high resolution laboratory absorption spectra recorded with the McMath Fourier transform spectrometer operated on Kitt Peak by the National Solar Observatory. Transitions up to J-double-prime = 12 have been measured using a nonlinear least-squares spectral fitting procedure. The variation of the measured halfwidth coefficients with symmetry type and rotational quantum number is very similar to that measured previously for N2 and air broadening, but the absolute values of the argon broadening coefficients are all smaller. On average, the ratio of the argon broadened halfwidth coefficient to the corresponding N2 broadened halfwidth coefficient is 0.877 + or - 0.017 (2 Sigma). More than 95 percent of the pressure-induced shifts are negative with values ranging from -0.0081 to +0.0055/cm atm. The pressure shifts in argon are nearly equal to corresponding values measured previously in N2 and air.

  12. GISH analysis of disomic Brassica napus-Crambe abyssinica chromosome addition lines produced by microspore culture from monosomic addition lines.

    PubMed

    Wang, Youping; Sonntag, Karin; Rudloff, Eicke; Wehling, Peter; Snowdon, Rod J

    2006-02-01

    Two Brassica napus-Crambe abyssinica monosomic addition lines (2n=39, AACC plus a single chromosome from C. abyssinca) were obtained from the F(2) progeny of the asymmetric somatic hybrid. The alien chromosome from C. abyssinca in the addition line was clearly distinguished by genomic in situ hybridization (GISH). Twenty-seven microspore-derived plants from the addition lines were obtained. Fourteen seedlings were determined to be diploid plants (2n=38) arising from spontaneous chromosome doubling, while 13 seedlings were confirmed as haploid plants. Doubled haploid plants produced after treatment with colchicine and two disomic chromosome addition lines (2n=40, AACC plus a single pair of homologous chromosomes from C. abyssinca) could again be identified by GISH analysis. The lines are potentially useful for molecular genetic analysis of novel C. abyssinica genes or alleles contributing to traits relevant for oilseed rape (B. napus) breeding.

  13. Spectral Line Parameters Including Temperature Dependences of Self- and Air-Broadening in the 2 (left arrow) 0 Band of CO at 2.3 micrometers

    NASA Technical Reports Server (NTRS)

    Devi, V. Malathy; Benner, D. Chris; Smith, M. A. H.; Mantz, A. W.; Sung, K.; Brown, L. R.; Predoi-Cross, A.

    2012-01-01

    Temperature dependences of pressure-broadened half-width and pressure-induced shift coefficients along with accurate positions and intensities have been determined for transitions in the 2<--0 band of C-12 O-16 from analyzing high-resolution and high signal-to-noise spectra recorded with two different Fourier transform spectrometers. A total of 28 spectra, 16 self-broadened and 12 air-broadened, recorded using high- purity (greater than or equal to 99.5% C-12-enriched) CO samples and CO diluted with dry air(research grade) at different temperatures and pressures, were analyzed simultaneously to maximize the accuracy of the retrieved parameters. The sample temperatures ranged from 150 to 298K and the total pressures varied between 5 and 700 Torr. A multispectrum nonlinear least squares spectrum fitting technique was used to adjust the rovibrational constants (G, B, D, etc.) and intensity parameters (including Herman-Wallis coefficients), rather than determining individual line positions and intensities. Self-and air-broadened Lorentz half-width coefficients, their temperature dependence exponents, self- and air-pressure-induced shift coefficients, their temperature dependences, self- and air-line mixing coefficients, their temperature dependences and speed dependence have been retrieved from the analysis. Speed-dependent line shapes with line mixing employing off-diagonal relaxation matrix element formalism were needed to minimize the fit residuals. This study presents a precise and complete set of spectral line parameters that consistently reproduce the spectrum of carbon monoxide over terrestrial atmospheric conditions.

  14. Line strength and collisional broadening coefficients of H2O at 2.7 μm for natural gas quality assurance applications

    NASA Astrophysics Data System (ADS)

    Anyangwe Nwaboh, Javis; Werhahn, Olav; Ebert, Volker

    2014-09-01

    We employed tunable diode laser absorption spectroscopy to measure the line strength, the methane (CH4), ethane (C2H6) and the propane (C3H8) broadening coefficients for the 523-422 H2O transition at 3619.61 cm-1. Water amount fractions generated by a stable and accurate humidity transfer standard, traceable to the SI units via the German national humidity standard, were used to calibrate the spectroscopic line strength measurements. We focus on the traceability of the measured line data to the SI and on uncertainty assessments following the guidelines of the Guide to the Expression of Uncertainty in Measurement. We determined the line strength to be (8.42 ± 0.07)×10-20 cm-1/(cm-2 molecule) corresponding to a relative uncertainty of ±0.8%. To the best of our knowledge, we report the first methane, ethane and propane broadening coefficients of (8.037 ± 0.056)×10-5 cm-1/hPa, (9.077 ± 0.064)×10-5 cm-1/hPa and (10.469 ± 0.073)×10-5 cm-1/hPa for the 523-422 H2O transition at 3619.61 cm-1, respectively. The relative combined uncertainties of the stated CH4, C2H6 and C3H8 broadening coefficients are in the ±0.7% range.

  15. Broadening and shifting of the methanol 119 {mu}m gain line of linear and circular polarization by collision with chiral molecules

    SciTech Connect

    J.S. Bakos; G. Djotyan; Zsuzsa Soerlei; J. Szigeti; D. K. Mansfield; J. Sarkozi

    2000-06-21

    Evidence of circular dichroism has been observed in the spectral properties of a gas of left-right symmetric molecules. This dichroism comes about as the result of collisions of the symmetric molecules with left-right asymmetric molecules introduced as a buffer gas. In this sense, the dichroism can be said to have been transferred from the chiral buffer molecules to the symmetric, non-chiral molecules of the background vapor. This transferred dichroism appears as broadening in the gain line of the symmetric molecule which is asymmetric with respect to the right or left handedness of a circularly polarized probe. The broadening of the 119 {mu}m line of the methanol molecule was observed using infrared-far infrared double resonance spectroscopy.

  16. THE RELATIONSHIP BETWEEN EXTREME ULTRAVIOLET NON-THERMAL LINE BROADENING AND HIGH-ENERGY PARTICLES DURING SOLAR FLARES

    SciTech Connect

    Kawate, T.; Imada, S.

    2013-10-01

    We have studied the relationship between the location of EUV non-thermal broadening and high-energy particles during large flares using the EUV Imaging Spectrometer on board Hinode, the Nobeyama Radio Polarimeter, the Nobeyama Radioheliograph, and the Atmospheric Imaging Assembly on board the Solar Dynamic Observatory. We have analyzed five large flare events that contain thermal-rich, intermediate, and thermal-poor flares classified by the definition discussed in the paper. We found that, in the case of thermal-rich flares, the non-thermal broadening of Fe XXIV occurred at the top of the flaring loop at the beginning of the flares. The source of 17 GHz microwaves is located at the footpoint of the flare loop. On the other hand, in the case of intermediate/thermal-poor flares, the non-thermal broadening of Fe XXIV occurred at the footpoint of the flare loop at the beginning of the flares. The source of 17 GHz microwaves is located at the top of the flaring loop. We discussed the difference between thermal-rich and intermediate/thermal-poor flares based on the spatial information of non-thermal broadening, which may provide clues that the presence of turbulence plays an important role in the pitch angle scattering of high-energy electrons.

  17. The Relationship between Extreme Ultraviolet Non-thermal Line Broadening and High-energy Particles during Solar Flares

    NASA Astrophysics Data System (ADS)

    Kawate, T.; Imada, S.

    2013-10-01

    We have studied the relationship between the location of EUV non-thermal broadening and high-energy particles during large flares using the EUV Imaging Spectrometer on board Hinode, the Nobeyama Radio Polarimeter, the Nobeyama Radioheliograph, and the Atmospheric Imaging Assembly on board the Solar Dynamic Observatory. We have analyzed five large flare events that contain thermal-rich, intermediate, and thermal-poor flares classified by the definition discussed in the paper. We found that, in the case of thermal-rich flares, the non-thermal broadening of Fe XXIV occurred at the top of the flaring loop at the beginning of the flares. The source of 17 GHz microwaves is located at the footpoint of the flare loop. On the other hand, in the case of intermediate/thermal-poor flares, the non-thermal broadening of Fe XXIV occurred at the footpoint of the flare loop at the beginning of the flares. The source of 17 GHz microwaves is located at the top of the flaring loop. We discussed the difference between thermal-rich and intermediate/thermal-poor flares based on the spatial information of non-thermal broadening, which may provide clues that the presence of turbulence plays an important role in the pitch angle scattering of high-energy electrons.

  18. Electron Density Measurements in the National Spherical Torus Experiment Detached Divertor Region Using Stark Broadening of Deuterium Infrared Paschen Emission Lines

    SciTech Connect

    Soukhanovskii, V A; Johnson, D W; Kaita, R; Roquemore, A L

    2007-04-27

    Spatially resolved measurements of deuterium Balmer and Paschen line emission have been performed in the divertor region of the National Spherical Torus Experiment using a commercial 0.5 m Czerny-Turner spectrometer. While the Balmer emission lines, Balmer and Paschen continua in the ultraviolet and visible regions have been extensively used for tokamak divertor plasma temperature and density measurements, the diagnostic potential of infrared Paschen lines has been largely overlooked. We analyze Stark broadening of the lines corresponding to 2-n and 3-m transitions with principle quantum numbers n = 7-12 and m = 10-12 using recent Model Microfield Method calculations (C. Stehle and R. Hutcheon, Astron. Astrophys. Supl. Ser. 140, 93 (1999)). Densities in the range (5-50) x 10{sup 19} m{sup -3} are obtained in the recombining inner divertor plasma in 2-6 MW NBI H-mode discharges. The measured Paschen line profiles show good sensitivity to Stark effects, and low sensitivity to instrumental and Doppler broadening. The lines are situated in the near-infrared wavelength domain, where optical signal extraction schemes for harsh nuclear environments are practically realizable, and where a recombining divertor plasma is optically thin. These properties make them an attractive recombining divertor density diagnostic for a burning plasma experiment.

  19. Broadening of the R(0) and P(2) Lines in the 13CO Fundamental by Helium Atoms from 300 K down to 12 K: Measurements and Comparison with Close-Coupling Calculations

    NASA Technical Reports Server (NTRS)

    Thibault, F.; Mantz, A. W.; Claveau, C.; Valentin, A.; Hurtmans, D.

    2007-01-01

    We present measurements of He-broadening parameters for the R(0) and O(2) lines in the fundamental band of 13CO at different temperatures between 12K and room temperature. The broadening parameters are determined, taking into account confinement narrowing, by simultaneous least-squares fitting of spectra recorded using a frequency stabilized diode laser spectrometer. The pressure broadening cross sections are deduced and compared to close-coupling calculations and earlier results obtained for rotational transitions of 12 CO.

  20. Line broadening of confined CO gas: from molecule-wall to molecule-molecule collisions with pressure.

    PubMed

    Hartmann, J-M; Boulet, C; Auwera, J Vander; El Hamzaoui, H; Capoen, B; Bouazaoui, M

    2014-02-14

    The infrared absorption in the fundamental band of CO gas confined in porous silica xerogel has been recorded at room temperature for pressures between about 5 and 920 hPa using a high resolution Fourier transform spectrometer. The widths of individual lines are determined from fits of measured spectra and compared with ab initio predictions obtained from requantized classical molecular dynamics simulations. Good agreement is obtained from the low pressure regime where the line shapes are governed by molecule-wall collisions to high pressures where the influence of molecule-molecule interactions dominates. These results, together with those obtained with a simple analytical model, indicate that both mechanisms contribute in a practically additive way to the observed linewidths. They also confirm that a single collision of a molecule with a wall changes its rotational state. These results are of interest for the determination of some characteristics of the opened porosity of porous materials through optical soundings.

  1. Temperature dependence of Lorentz air-broadening and pressure-shift coefficients of (12)CH4 lines in the 2.3-micron spectral region

    NASA Technical Reports Server (NTRS)

    Devi, V. Malathy; Benner, D. Chris; Smith, M. A. H.; Rinsland, C. P.

    1994-01-01

    High-resolution (0.01/cm) absorption spectra of lean mixtures of CH4 in dry air were recorded with the McMath-Pierce Fourier transform spectrometer (FTS) of the National Solar Observatory on Kitt Peak at various temperatures between 24 and -61 C. The spectra have been analyzed to determine the values at room temperature of pressure-broadened widths and pressure-induced shifts of more than 740 transitions. The temperature dependence of air-broadened widths and pressure-induced shifts was deduced for approx. 370 transitions in the nu(sub 1) + nu(sub 4), nu(sub 3) + nu(sub 4), and nu(sub 2) + nu(sub 3) bands of (12)CH4 located between 4118 and 4615/cm. These results were obtained by analyzing a total of 29 spectra simultaneously using a multi-spectral non-linear least-squares fitting technique. This new technique allowed the determination of correlated spectral line parameters (e.g. intensity and broadening coefficient) better than the procedure of averaging values obtained by fitting the spectra individually. This method also provided a direct determination of the uncertainties in the retrieved parameters due to random errors. For each band analysed in this study the dependence of the various spectral line parameters upon the tetrahedral symmetry species and the rotational quantum numbers of the transitions is also presented.

  2. Semi-classical H2-broadening coefficients of 12CH3D rovibrational lines and their temperature dependence for planetary atmosphere modeling

    NASA Astrophysics Data System (ADS)

    Sinyakova, T.; Buldyreva, J.

    2017-01-01

    Theoretical hydrogen-broadening coefficients and associated temperature exponents for 12CH3D (J, K) lines in parallel (ΔK = 0) bands are calculated by a semi-classical approach based on a rigorous consideration of the active molecule as a symmetric top, a model intermolecular potential comprising both short- and long-range interactions, and exact classical trajectories. The leading potential terms are shown to provide a realistic description of line broadening in comparison with scarce measurements available in the literature. The calculations performed for 296, 240 and 190 K are used to extract the line-width temperature-dependence exponents for the typical temperature range of atmospheric interest ∼200-300 K. Detailed P-Q-R-line lists are provided for large intervals of quantum numbers (0 ≤ J ≤ 20, 0 ≤ K ≤ J) requested for remote sensing of planetary atmospheres, in particular those of outer planets and their moons. With negligible vibrational dependence of CH3D line-widths and estimated as negligible their sub-branch dependence, these data can be also employed for perpendicular bands.

  3. Study of the effect of perturber mass on collisional broadening coefficients of lines in the ν3 band of CS2

    NASA Astrophysics Data System (ADS)

    Kongolo Tshikala, Pardaillan; Blanquet, Ghislain; Lepère, Muriel

    2012-05-01

    Using a tunable diode-laser spectrometer, we have recorded 28 lines in the fundamental ν3 band of carbon disulfide diluted in several rare gases: helium, neon and krypton. These lines are ranged from P(78) to R(72) and located in the spectral range 1514-1548 cm-1. The collisional half-widths of each line have been obtained by fitting to the experimental lineshape, a Voigt profile and also the models developed by Rautian and Sobel'man and by Galatry. These two more elaborate profiles take into account the narrowing due to the molecular confinement (Dicke effect). From these results and those previously obtained for CS2 + Ar, we have compared the collisional broadening coefficients of CS2 lines to put in evidence the effect of the perturber mass.

  4. Teaching and Learning Fraction Addition on Number Lines

    ERIC Educational Resources Information Center

    Izsak, Andrew; Tillema, Erik; Tunc-Pekkan, Zelha

    2008-01-01

    We present a case study of teaching and learning fraction addition on number lines in one sixth-grade classroom that used the Connected Mathematics Project Bits and Pieces II materials. Our main research questions were (1) What were the primary cognitive structures through which the teacher and students interpreted the lessons? and (2) Were the…

  5. Self-, N2-, O2-broadening coefficients and line parameters of HFC-32 for ν7 band and ground state transitions from infrared and microwave spectroscopy

    NASA Astrophysics Data System (ADS)

    Tasinato, Nicola; Turchetto, Arianna; Puzzarini, Cristina; Stoppa, Paolo; Pietropolli Charmet, Andrea; Giorgianni, Santi

    2014-09-01

    Hydrofluorocarbons have been used as replacement gases of chlorofluorocarbons, since the latter have been phased out by the Montreal Protocol due to their environmental hazardous ozone-depleting effects. This is also the case of difluoromethane (CH2F2, HFC-32), which nowadays is widely used in refrigerant mixtures together with CF3CH3, CF3CH2F, and CF3CHF2. Due to its commercial use, in the last years, the atmospheric concentration of HFC-32 has increased significantly. However, this molecule presents strong absorptions within the 8-12 μm atmospheric window, and hence it is a greenhouse gas which contributes to global warming. Although over the years several experimental and theoretical investigations dealt with the spectroscopic properties of CH2F2, up to now pressure broadening coefficients have never been determined. In the present work, the line-by-line parameters of CH2F2 are retrieved for either ground state or ν7 band transitions by means of microwave (MW) and infrared (IR) absorption spectroscopy, respectively. In particular, laboratory experiments are carried out on 9 pure rotational transitions of the ground state and 26 ro-vibrational transitions belonging to the ν7 band lying around 8.2 μm within the atmospheric region. Measurements are carried out at room temperature on self-perturbed CH2F2 as well as on CH2F2 perturbed by N2 and O2. The line shape analysis leads to the first determination of self-, N2-, O2-, and air-broadening coefficients, and also of line intensities (IR). Upon comparison, broadening coefficients of ground state transitions are larger than those of the ν7 band, and no clear dependence on the rotational quantum numbers can be reported. The obtained results represent basic information for the atmospheric modelling of this compound as well as for remote sensing applications.

  6. X-ray line broadening studies on aluminum nitride, titanium carbide and titanium diboride modified by high pressure shock loading

    SciTech Connect

    Morosin, B.; Graham, R.A.

    1983-01-01

    Powders of AlN, TiC and TiB/sub 2/ have been subjected to controlled shock loading with peak pressures in the samples between 14 to 27 GPa and preserved for post-shock study. Broadened x-ray diffraction peak profiles are analyzed by a simplified method and show increases in residual lattice strain and small decreases in crystallite size. Strain values range from 10/sup -5/ to 10/sup -4/ for TiB/sub 2/ and to values larger than 10/sup -3/ for TiC and AlN.

  7. Pressure broadening of the electric dipole and Raman lines of CO2 by argon: Stringent test of the classical impact theory at different temperatures on a benchmark system

    NASA Astrophysics Data System (ADS)

    Ivanov, Sergey V.; Buzykin, Oleg G.

    2016-12-01

    A classical approach is applied to calculate pressure broadening coefficients of CO2 vibration-rotational spectral lines perturbed by Ar. Three types of spectra are examined: electric dipole (infrared) absorption; isotropic and anisotropic Raman Q branches. Simple and explicit formulae of the classical impact theory are used along with exact 3D Hamilton equations for CO2-Ar molecular motion. The calculations utilize vibrationally independent most accurate ab initio potential energy surface (PES) of Hutson et al. expanded in Legendre polynomial series up to lmax = 24. New improved algorithm of classical rotational frequency selection is applied. The dependences of CO2 half-widths on rotational quantum number J up to J=100 are computed for the temperatures between 77 and 765 K and compared with available experimental data as well as with the results of fully quantum dynamical calculations performed on the same PES. To make the picture complete, the predictions of two independent variants of the semi-classical Robert-Bonamy formalism for dipole absorption lines are included. This method. however, has demonstrated poor accuracy almost for all temperatures. On the contrary, classical broadening coefficients are in excellent agreement both with measurements and with quantum results at all temperatures. The classical impact theory in its present variant is capable to produce quickly and accurately the pressure broadening coefficients of spectral lines of linear molecules for any J value (including high Js) using full-dimensional ab initio - based PES in the cases where other computational methods are either extremely time consuming (like the quantum close coupling method) or give erroneous results (like semi-classical methods).

  8. Spectroscopic measurements of SO(2) line parameters in the 9.2 mum atmospheric region and theoretical determination of self-broadening coefficients.

    PubMed

    Tasinato, Nicola; Charmet, Andrea Pietropolli; Stoppa, Paolo; Giorgianni, Santi; Buffa, Giovanni

    2010-01-28

    Sulfur dioxide is still the subject of numerous spectroscopic studies since it plays an active role in the chemistry of Earth's atmosphere and it is a molecule of proven astrophysical importance. In the present work we have determined the self-broadening and integrated absorption coefficients for several lines in the nu(1) band spectral region around 9.2 mum. Besides the parameters of the lines belonging to the nu(1) fundamental of (32)SO(2), also those for some rovibrational lines of the nu(1)+nu(2)-nu(2) hot band of the (32)SO(2) isotopologue and the nu(1) band of the (34)SO(2) isotopic species have been determined. The measurements have been carried out at 297 K using a tunable diode laser spectrometer. The self-broadening parameters have also been theoretically determined employing a semiclassical formalism based on the Anderson-Tsao-Curnutte approximation. The study has been completed with the determination of the vibrational cross sections of the three fundamental bands measured from the spectra recorded at a resolution of 0.2 cm(-1) using a Fourier transform infrared spectrometer.

  9. Spectroscopic Line Parameters of - and Hydrogen-Broadened 12C16O Transitions in the 3-0 Band from 6270 wn to 6402 wn.

    NASA Astrophysics Data System (ADS)

    Reed, Zachary; Hodges, Joseph T.

    2016-06-01

    We present helium- and hydrogen-broadened linewidths, pressure-induced shifts, and collisional narrowing coefficients for selected lines in the P- and R- branch of the second overtone (3-0) band of CO, spanning from 6270 wn to 6402 wn. The contribution of speed dependent effects and partial correlation between velocity-changing and dephasing collisions on the foreign broadened line shapes are also discussed. The data were obtained using the frequency-stabilized cavity ringdown spectroscopy technique. Spectra were collected at room temperature over a pressure range from 13.3 kPa to 100 kPa. The spectrum frequency axis is referenced via an optical frequency comb to a Cs clock, which provides pressure shifting values with uncertainties as low as 100 kHz/atm. The spectra exhibited signal-to-noise ratios as high as 20,000:1, which enables rigorous tests of theoretical line profiles through multi-spectrum least squares data analysis. The partially correlated, quadratic-speed-dependent Nelkin Ghatak profile gives a quality of fit mostly commensurate with the high spectrum signal-to-noise and minimizes structural residuals.

  10. The role of higher-multipolar and repulsive forces in the calculation of collision-broadened line-widths of linear molecules

    NASA Technical Reports Server (NTRS)

    Varanasi, P.; Sarangi, S.

    1974-01-01

    Collision-broadened line widths in CO-CO2 and CO-O2 collisions have been calculated by incorporating interactions due to octopoles and hexadecapoles and short-range repulsive interactions into Anderson's (1949) theory. It is shown how these higher-order interactions can be manipulated to yield good agreement with experimental data. A critical evaluation of this totally empirical manipulation suggests that a thorough revision of the theory is required for all but simple dipole-dipole interactions. In the process of the evaluation, the values of the multipole moments are discussed.

  11. Investigation of broadening and shift of vapour absorption lines of H{sub 2}{sup 16}O in the frequency range 7184 – 7186 cm{sup -1}

    SciTech Connect

    Nadezhdinskii, A I; Pereslavtseva, A A; Ponurovskii, Ya Ya

    2014-10-31

    We present the results of investigation of water vapour absorption spectra in the 7184 – 7186 cm{sup -1} range that is of particular interest from the viewpoint of possible application of the data obtained for monitoring water vapour in the Earth's stratosphere. The doublet of H{sub 2}{sup 16}O near ν = 7185.596 cm{sup -1} is analysed. The coefficients of broadening and shift of water vapour lines are found in the selected range in mixtures with buffer gases and compared to those obtained by other authors. (laser spectroscopy)

  12. Solid-state proton NMR of paramagnetic metal complexes: DANTE spin echoes for selective excitation in inhomogeneously broadened lines

    NASA Astrophysics Data System (ADS)

    Carnevale, Diego; Perez Linde, A. J.; Bauer, Gerald; Bodenhausen, Geoffrey

    2013-08-01

    The paramagnetic complex bis(oxazolinylphenyl)amine-Fe(III)Cl2 is investigated by means of solid-state proton NMR at 18.8 T (800 MHz) using magic-angle spinning at 65 kHz. Spin echoes that are excited and refocused by combs of rotor-synchronized pulses in the manner of 'Delays Alternating with Nutation for Tailored Excitation' (DANTE) allow one to characterize different chemical environments that severely overlap in conventional MAS spectra. Such sequences combine two apparently contradictory features: an overall bandwidth exceeding several MHz, and very selective irradiation of a few kHz within inhomogeneously broadened sidebands. The experimental hyperfine interactions correlate well with DFT calculations.

  13. Multispectrum Analysis of 12CH4 in the v4 Band: I. Air-Broadened Half Widths, Pressure-Induced Shifts, Temperature Dependences and Line Mixing

    NASA Technical Reports Server (NTRS)

    Smith, MaryAnn H.; Benner, D. Chris; Predoi-Cross, Adriana; Venkataraman, Malathy Devi

    2009-01-01

    Lorentz air-broadened half widths, pressure-induced shifts and their temperature dependences have been measured for over 430 transitions (allowed and forbidden) in the v4 band of (CH4)-12 over the temperature range 210 to 314 K. A multispectrum non linear least squares fitting technique was used to simultaneously fit a large number of high-resolution (0.006 to 0.01/cm) absorption spectra of pure methane and mixtures of methane diluted with dry air. Line mixing was detected for pairs of A-, E-, and F-species transitions in the P- and R-branch manifolds and quantified using the off-diagonal relaxation matrix elements formalism. The measured parameters are compared to air- and N2-broadened values reported in the literature for the v4 and other bands. The dependence of the various spectral line parameters upon the tetrahedral symmetry species and rotational quantum numbers of the transitions is discussed. All data used in the present work were recorded using the McMath-Pierce Fourier transform spectrometer located at the National Solar Observatory on Kitt Peak.

  14. Anomalous Broadening of Balmer H{sub {alpha}} Line in Aluminum and Copper Hollow Cathode Glow Discharges

    SciTech Connect

    Sisovic, N. M.; Majstorovic, G. Lj.; Konjevic, N.

    2008-10-22

    The presented results are concerned with the shape of Balmer alpha line emitted from a low pressure DC glow discharge with aluminum (Al) and copper (Cu) hollow cathode (HC) in pure H{sub 2} and Ar-H{sub 2} gas mixture. The analysis indicates that the line profile represents a convolution of Gaussian profiles resulting from different collision excitation processes.

  15. Broadening the Recruiting Market.

    ERIC Educational Resources Information Center

    Central All-Volunteer Force Task Force, Washington, DC.

    The purpose of the study is to broaden the enlisted recruiting market, especially for high school graduates and describe measures to complete or expedite actions initiated by ASD (M and RA) (Assistant Secretary of Defense Manpower and Reserve Affairs) and the military services and to take additional actions to enhance recruiting. (Author)

  16. ¹⁴N Quadrupole Resonance line broadening due to the earth magnetic field, occuring only in the case of an axially symmetric electric field gradient tensor.

    PubMed

    Aissani, Sarra; Guendouz, Laouès; Marande, Pierre-Louis; Canet, Daniel

    2015-01-01

    As demonstrated before, the application of a weak static B0 magnetic field (less than 10 G) may produce definite effects on the ¹⁴N Quadrupole Resonance line when the electric field gradient tensor at the nitrogen nucleus level is of axial symmetry. Here, we address more precisely the problem of the relative orientation of the two magnetic fields (the static field and the radio-frequency field of the pure NQR experiment). For a field of 6G, the evolution of the signal intensity, as a function of this relative orientation, is in very good agreement with the theoretical predictions. There is in particular an intensity loss by a factor of three when going from the parallel configuration to the perpendicular configuration. By contrast, when dealing with a very weak magnetic field (as the earth field, around 0.5 G), this effect drops to ca. 1.5 in the case Hexamethylenetetramine (HMT).This is explained by the fact that the Zeeman shift (due to the very weak magnetic field) becomes comparable to the natural line-width. The latter can therefore be determined by accounting for this competition. Still in the case of HMT, the estimated natural line-width is half the observed line-width. The extra broadening is thus attributed to earth magnetic field. The latter constitutes therefore the main cause of the difference between the natural transverse relaxation time (T₂) and the transverse relaxation time derived from the observed line-width (T₂(⁎)).

  17. Line Positions, Intensities, - and N_2-BROADENING Parameters in the ν_9 Band of Ethane (C_2H_6)

    NASA Astrophysics Data System (ADS)

    Rinsland, Curtis P.; Devi, V. Malathy; Benner, D. Chris; Sams, Robert L.; Blake, Thomas A.

    2009-06-01

    High-resolution infrared spectra of ethane have been recorded using the Bruker IFS 120 HR Fourier transform spectrometer (FTS) at the Pacific Northwest National Laboratory (PNNL), in Richland, Washington. Several spectra of pure ethane and ethane in N_2 mixtures were obtained with absorption paths of 20 cm and 3.2 m. Room temperature spectra were obtained in both 20 cm and 3.2 m paths while cold spectra were obtained using only the 20 cm path cell. The spectra were obtained at ˜0.0028 cm^{-1} resolution with sample pressures ranging from 0.3 to ˜36 torr for pure ethane and 11 to 180 torr in ethane-N_2 mixtures. The volume mixing ratios of ethane in the ethane-N_2 mixtures varied between 0.01 and 0.2. The gas temperatures varied from -66^°C to 24^°C. Positions, intensities, self- and N_2-broadening parameters were determined by processing 16 or 17 room temperature spectra using the multispectrum nonlinear least squares spectrum fitting technique. The results obtained for transitions in a few select ^PQ and ^RQ sub-bands will be reported at this time. D. Chris Benner, C.P. Rinsland, V. Malathy Devi, M.A.H. Smith, and D. Atkins, J. Quant. Spectrosc. Radiat. Transfer 53, 705-721 (1995)

  18. Air-Broadened Line Shapes in the 2ν_3 R Branch of ^{12}CH_4 Between 6014 and 6100 CM^{-1}

    NASA Astrophysics Data System (ADS)

    Devi, V. Malathy; Benner, D. Chris; Sung, K.; Brown, L. R.; Crawford, T. J.; Yu, Shanshan; Smith, M. A. H.; Mantz, A. W.

    2013-06-01

    Complete and accurate information on line shape parameters of 2ν_3 methane transitions for air broadening as a function of temperature is critical not only for the correct interpretation of the observed atmospheric spectra but also for the development of a reliable theoretical model. For this reason, we obtained a series of high-resolution, high S/N spectra of high-purity ^{12}CH_4 and ^{12}CH_4 broadened with dry air at temperatures in the 130 to 295 K range using the Bruker IFS 125HR Fourier transform spectrometer at JPL. Two absorption cells were used in the experiment, a White cell with path length of 13 m for room temperature spectra and a 21 m Herriott cell for cold sample spectra. The 15 spectra used in the analysis consisted of 3 low pressure (0.26 to 2.57 Torr) spectra with pure ^{12}CH_4 and 12 air-broadened spectra with total sample pressures of 79-805 Torr and volume mixing ratios of methane between 0.23 and 1%. A multispectrum least-squares fitting technique was employed to fit all 15 spectra simultaneously. Preliminary results for select R(J) manifolds will be presented. A. W. Mantz, K. Sung, L. R. Brown, et al., abstract submitted to this Symposium. D. C. Benner, C. P. Rinsland, V. Malathy Devi, M. A. H. Smith and D. Atkins, JQSRT {53} (1995) 705-721. Research described in this paper was performed at Connecticut College, the College of William and Mary, NASA Langley Research Center and the Jet Propulsion Laboratory, California Institute of Technology, under contracts and cooperative agreements with the National Aeronautics and Space Administration.

  19. Laser-induced line-narrowing effects in coupled Doppler-broadened transitions. II - Standing-wave features.

    NASA Technical Reports Server (NTRS)

    Feldman, B. J.; Feld, M. S.

    1972-01-01

    Previous theoretical results on the influence of a laser on the line shape of a coupled transition (laser-induced line narrowing) have been restricted to the case where the laser is detuned from the center of its atomic gain profile or is in the form of a traveling wave. The present paper extends these results to the case where the laser is an intense standing-wave field tunable to the center of its atomic gain profile (conditions for Lamb dip). A theoretical solution of the problem is developed, and a detailed discussion of line shapes and physical processes involved is included.

  20. Fouling control in seawater by on-line acid addition

    SciTech Connect

    Salvago, G.; Taccani, G.; Polimeni, R.; Fumagalli, G.; Picenoni, D.

    1996-11-01

    An experimental plant was set up containing once-through test lines supplied with seawater. The pH level of the seawater was maintained at 6.3 by the acids addition. Heat exchange monitoring equipment and channels exposing different metal specimens were installed on each of the lines. Observation by microscope and EDS analyses were carried out both on the specimen surfaces and on the cross section of the fouling after fracturing in liquid N{sub 2}. The results obtained show that: fouling must not be confused with its effects or simply with its biological components; acidifying seawater can prevent the resistance to heat exchange from increasing without impeding its biological activity. Observation by microscope of the fouling cross sections showed that in untreated seawater the foulings on stainless steel were composed of a continuous compact layer, covered by disorderly clusters. These compact layers were found to contain high quantities of corrosion products of the metals. Elements typical of corrosion products of ferrous materials (Fe, Mn) were also found on Pt, copper alloys and plastic materials. The addition of HCl or H{sub 2}SO{sub 4} to the seawater, to bring it to pH 6.3, reduces the amount of fouling adhering to the surfaces, prevents the development of the continuous layer containing iron and prevents significant increases in heat exchange resistance. The addition of CO{sub 2} can encourage the development of incoherent fibrous material with high Si content and low Fe content which is of little impediment to heat exchange. The addition of lactic acid can encourage both the abnormal development of biomass and the formation of several, separate, layers on stainless steel surfaces.

  1. The relaxation matrix for symmetric tops with inversion symmetry. I. Effects of line coupling on self-broadened ν1 and pure rotational bands of NH3

    NASA Astrophysics Data System (ADS)

    Ma, Q.; Boulet, C.

    2016-06-01

    The Robert-Bonamy formalism has been commonly used to calculate half-widths and shifts of spectral lines for decades. This formalism is based on several approximations. Among them, two have not been fully addressed: the isolated line approximation and the neglect of coupling between the translational and internal motions. Recently, we have shown that the isolated line approximation is not necessary in developing semi-classical line shape theories. Based on this progress, we have been able to develop a new formalism that enables not only to reduce uncertainties on calculated half-widths and shifts, but also to model line mixing effects on spectra starting from the knowledge of the intermolecular potential. In our previous studies, the new formalism had been applied to linear and asymmetric-top molecules. In the present study, the method has been extended to symmetric-top molecules with inversion symmetry. As expected, the inversion splitting induces a complete failure of the isolated line approximation. We have calculated the complex relaxation matrices of self-broadened NH3. The half-widths and shifts in the ν1 and the pure rotational bands are reported in the present paper. When compared with measurements, the calculated half-widths match the experimental data very well, since the inapplicable isolated line approximation has been removed. With respect to the shifts, only qualitative results are obtained and discussed. Calculated off-diagonal elements of the relaxation matrix and a comparison with the observed line mixing effects are reported in the companion paper (Paper II).

  2. The relaxation matrix for symmetric tops with inversion symmetry. I. Effects of line coupling on self-broadened ν1 and pure rotational bands of NH3.

    PubMed

    Ma, Q; Boulet, C

    2016-06-14

    The Robert-Bonamy formalism has been commonly used to calculate half-widths and shifts of spectral lines for decades. This formalism is based on several approximations. Among them, two have not been fully addressed: the isolated line approximation and the neglect of coupling between the translational and internal motions. Recently, we have shown that the isolated line approximation is not necessary in developing semi-classical line shape theories. Based on this progress, we have been able to develop a new formalism that enables not only to reduce uncertainties on calculated half-widths and shifts, but also to model line mixing effects on spectra starting from the knowledge of the intermolecular potential. In our previous studies, the new formalism had been applied to linear and asymmetric-top molecules. In the present study, the method has been extended to symmetric-top molecules with inversion symmetry. As expected, the inversion splitting induces a complete failure of the isolated line approximation. We have calculated the complex relaxation matrices of self-broadened NH3. The half-widths and shifts in the ν1 and the pure rotational bands are reported in the present paper. When compared with measurements, the calculated half-widths match the experimental data very well, since the inapplicable isolated line approximation has been removed. With respect to the shifts, only qualitative results are obtained and discussed. Calculated off-diagonal elements of the relaxation matrix and a comparison with the observed line mixing effects are reported in the companion paper (Paper II).

  3. Influence of velocity effects on the shape of N2 (and air) broadened H2O lines revisited with classical molecular dynamics simulations

    NASA Astrophysics Data System (ADS)

    Ngo, N. H.; Tran, H.; Gamache, R. R.; Bermejo, D.; Domenech, J.-L.

    2012-08-01

    The modeling of the shape of H2O lines perturbed by N2 (and air) using the Keilson-Storer (KS) kernel for collision-induced velocity changes is revisited with classical molecular dynamics simulations (CMDS). The latter have been performed for a large number of molecules starting from intermolecular-potential surfaces. Contrary to the assumption made in a previous study [H. Tran, D. Bermejo, J.-L. Domenech, P. Joubert, R. R. Gamache, and J.-M. Hartmann, J. Quant. Spectrosc. Radiat. Transf. 108, 126 (2007)], 10.1016/j.jqsrt.2007.03.009, the results of these CMDS show that the velocity-orientation and -modulus changes statistically occur at the same time scale. This validates the use of a single memory parameter in the Keilson-Storer kernel to describe both the velocity-orientation and -modulus changes. The CMDS results also show that velocity- and rotational state-changing collisions are statistically partially correlated. A partially correlated speed-dependent Keilson-Storer model has thus been used to describe the line-shape. For this, the velocity changes KS kernel parameters have been directly determined from CMDS, while the speed-dependent broadening and shifting coefficients have been calculated with a semi-classical approach. Comparisons between calculated spectra and measurements of several lines of H2O broadened by N2 (and air) in the ν3 and 2ν1 + ν2 + ν3 bands for a wide range of pressure show very satisfactory agreement. The evolution of non-Voigt effects from Doppler to collisional regimes is also presented and discussed.

  4. Influence of velocity effects on the shape of N2 (and air) broadened H2O lines revisited with classical molecular dynamics simulations.

    PubMed

    Ngo, N H; Tran, H; Gamache, R R; Bermejo, D; Domenech, J-L

    2012-08-14

    The modeling of the shape of H(2)O lines perturbed by N(2) (and air) using the Keilson-Storer (KS) kernel for collision-induced velocity changes is revisited with classical molecular dynamics simulations (CMDS). The latter have been performed for a large number of molecules starting from intermolecular-potential surfaces. Contrary to the assumption made in a previous study [H. Tran, D. Bermejo, J.-L. Domenech, P. Joubert, R. R. Gamache, and J.-M. Hartmann, J. Quant. Spectrosc. Radiat. Transf. 108, 126 (2007)], the results of these CMDS show that the velocity-orientation and -modulus changes statistically occur at the same time scale. This validates the use of a single memory parameter in the Keilson-Storer kernel to describe both the velocity-orientation and -modulus changes. The CMDS results also show that velocity- and rotational state-changing collisions are statistically partially correlated. A partially correlated speed-dependent Keilson-Storer model has thus been used to describe the line-shape. For this, the velocity changes KS kernel parameters have been directly determined from CMDS, while the speed-dependent broadening and shifting coefficients have been calculated with a semi-classical approach. Comparisons between calculated spectra and measurements of several lines of H(2)O broadened by N(2) (and air) in the ν(3) and 2ν(1) + ν(2) + ν(3) bands for a wide range of pressure show very satisfactory agreement. The evolution of non-Voigt effects from Doppler to collisional regimes is also presented and discussed.

  5. Experimental studies, line-shape analysis and semi-empirical calculations of broadening coefficients for CH335Cl-CO2 submillimeter transitions

    NASA Astrophysics Data System (ADS)

    Dudaryonok, A. S.; Lavrentieva, N. N.; Buldyreva, J.; Margulès, L.; Motiyenko, R. A.; Rohart, F.

    2014-09-01

    Rotational transitions in CH335Cl mixed with CO2 are recorded at 296 K and total pressures up to 0.6 Torr in the frequency interval 186-901 GHz (1.6-0.3 mm) for J=6→7, 10→11, 17→18, 22→23, 31→32, 33→34 and K=0-6, using the frequency-modulation spectrometer of the Laboratory PhLAM (Lille, France). These line-shapes are analyzed with the commonly used Voigt profile as well as with more refined Speed-Dependent Voigt and Galatry models accounting for the line narrowing induced, respectively, by the speed-dependence of the relaxation parameters and by velocity-changing collisions. Due to the high line intensities, the fitting procedure involves the full implementation of the Bee-Lambert law instead of its traditional linear approximation. The experimentally deduced J- and K-dependences of the pressure-broadening coefficients are further used to obtain the model parameters of a semi-empirical approach allowing massive calculations of line-shape parameters for enlarged ranges of rotational quantum numbers requested by spectroscopic databases.

  6. Line positions, pressure broadening and shift coefficients for the second overtone transitions of carbon monoxide in argon

    NASA Astrophysics Data System (ADS)

    Kowzan, G.; Stec, K.; Zaborowski, M.; Wójtewicz, S.; Cygan, A.; Lisak, D.; Masłowski, P.; Trawiński, R. S.

    2017-04-01

    Absolute positions and spectral line-shape parameters of carbon monoxide 0 → 3 band, P branch transitions are reported. The speed-dependent effects and the influence of velocity-changing collisions were taken into account in the fitted line-shape models. For the first time the values of pressure shift coefficients of CO in argon for this band were determined. The measurements were made with the Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectrometer, with the frequency axis linked through an optical frequency comb to the UTC(AOS) frequency reference based on a hydrogen maser. Achieved uncertainties of line positions are between 70 kHz and 420 kHz.

  7. Shift measurements of the stark-broadened ionized helium lines at 1640 and 1215 angstrom. Ph.D. Thesis

    NASA Technical Reports Server (NTRS)

    Vanzandt, J. R.

    1976-01-01

    Time-resolved measurements were made of the shifts of the ionized helium lines at 1,640 A (n = 3 approaches 2) and 1,215 A (n = 4 approaches 2), and of the Stark profile of the 1,215 A wavelength line. An electromagnetic shock tube was used as a light source. The plasma conditions corresponded to electron temperatures of approximately 3.5 eV and electron densities of 0.8 to 1.8 x 10 to the 17th power/cubic cm. The measured shifts fell between two previous estimates of plasma polarization shifts. The measured Stark width of the 1,215 A wavelength line was up to 30% greater than the theoretical width.

  8. TURBULENCE SPECTRA FROM DOPPLER-BROADENED SPECTRAL LINES: TESTS OF THE VELOCITY CHANNEL ANALYSIS AND VELOCITY COORDINATE SPECTRUM TECHNIQUES

    SciTech Connect

    Chepurnov, A.; Lazarian, A.

    2009-03-10

    Turbulent motions induce Doppler shifts of observable emission and absorption lines motivating studies of turbulence using precision spectroscopy. We provide numerical testing of the two most promising techniques, velocity channel analysis and velocity coordinate spectrum (VCS). We obtain an expression for the shot noise that the discretization of the numerical data entails and successfully test it. We show that the numerical resolution required for recovering the underlying turbulent spectrum from observations depend on the spectral index of velocity fluctuations, which makes low-resolution testing misleading. We demonstrate numerically that, when dealing with absorption lines, sampling of turbulence along just a dozen directions provides a high quality spectrum with the VCS technique.

  9. TESTING THE NO-HAIR THEOREM WITH OBSERVATIONS IN THE ELECTROMAGNETIC SPECTRUM. IV. RELATIVISTICALLY BROADENED IRON LINES

    SciTech Connect

    Johannsen, Tim; Psaltis, Dimitrios

    2013-08-10

    According to the no-hair theorem, astrophysical black holes are fully characterized by their masses and spins and are described by the Kerr metric. This theorem can be tested observationally by measuring (at least) three different multipole moments of the spacetimes of black holes. In this paper, we calculate the profiles of fluorescent iron lines emitted from the accretion flows around black hole candidates within a framework that allows us to perform the calculation as a function of its mass and spin as well as of a free parameter that measures potential deviations from the Kerr metric. We show that such deviations lead to line profiles that are significantly altered and may exhibit a modified flux ratio of the two peaks in their characteristic double-peaked shape. We also show that the disk inclination can be measured independently of the spin and the deviation parameter at low to intermediate inclination angles, as in the case of Kerr black holes. We estimate the precision that near-future X-ray missions such as Astro-H and ATHENA+ are required to achieve in order to resolve deviations from the Kerr metric in iron line profiles and show that constraints on such deviations will be strongest for rapidly spinning black holes. More generally, we show that measuring the line profile with a precision of {approx}5% at disk inclinations of 30 Degree-Sign or 60 Degree-Sign constrains the deviation parameter to order unity for values of the spin a {approx}> 0.5M.

  10. Gas temperature determination in an argon non-thermal plasma at atmospheric pressure from broadenings of atomic emission lines

    NASA Astrophysics Data System (ADS)

    Yubero, C.; Rodero, A.; Dimitrijevic, M. S.; Gamero, A.; García, M. C.

    2017-03-01

    In this work a new spectroscopic method, allowing gas temperature determination in argon non-thermal plasmas sustained at atmospheric pressure, is presented. The method is based on the measurements of selected pairs of argon atomic lines (Ar I 603.2 nm/Ar I 549.6 nm, Ar I 603.2 nm/Ar I 522.1 nm, Ar I 549.6 nm/Ar I 522.1 nm). For gas temperature determination using the proposed method, there is no need of knowing the electron density, neither making assumptions on the degree of thermodynamic equilibrium existing in the plasma. The values of the temperatures obtained using this method, have been compared with the rotational temperatures derived from the OH ro-vibrational bands, using both, the well-known Boltzmann-plot technique and the best fitting to simulated ro-vibrational bands. A very good agreement has been found.

  11. Spectral Line Shape Parameters for the ν_1, ν_2, and ν_3 Bands of Hdo: Self and CO_2 Broadened

    NASA Astrophysics Data System (ADS)

    Devi, V. Malathy; Benner, D. Chris; Sung, Keeyoon; Crawford, Timothy J.; Gamache, Robert R.; Renaud, Candice L.; Mantz, Arlan; Smith, Mary Ann H.; Villanueva, Geronimo L.

    2016-06-01

    To provide precise information relevant to Martian atmospheric remote sensing, high resolution high signal-to-noise ratio spectra of HDO in mixture with CO_2 were recorded in the ν_1, ν_2, and ν_3 fundamental bands between 2.7 and 7 μm regions. The spectra were obtained with the Bruker IFS-125HR Fourier transform spectrometer at the Jet Propulsion Laboratory along with two specially built coolable absorption cells with path lengths of 0.2038 m and 20.941 m at various sample gas temperatures (˜220 - 296 K), total sample pressures and volume mixing ratios. A multispectrum nonlinear least squares technique was applied to fit simultaneously all the spectra obtained. The measured line parameters include accurate line positions, intensities, self- and CO_2-broadened Lorentz halfwidth and pressure-shift coefficients, and temperature dependences of CO_2 broadened HDO halfwidth and pressure-shift coefficients. Line mixing coefficients using the relaxation matrix formalism and quadratic speed dependence parameters were also measured where appropriate. Example results for select transitions in each band will be presented and comparisons made to other measured/calculated values. K. Sung, A.W. Mantz, M.A.H. Smith, L.R. Brown, T.J. Crawford, V.M. Devi, D.C. Benner. J. Mol. Spectrosc. 162 (2010) 124-134. A.W. Mantz, K. Sung, T.J. Crawford, L.R. Brown, M.A.H. Smith, V.M. Devi, D.C. Benner, J. Mol. Spectrosc. 304 (2014) 12-24. D.C. Benner, C.P. Rinsland, V. Malathy Devi, M.A. H. Smith, and D. Atkins. JQSRT 53 (1995) 705-721. Research described in this paper are performed at the College of William and Mary, Jet Propulsion Laboratory, California Institute of Technology, Connecticut College, and NASA Langley Research Center under contracts and cooperative agreements with the National Aeronautics and Space Administration. RRG and CLR were supported by the National Science Foundation through Grant # AGS-1156862.

  12. Air-Broadened Line Parameters for the 2←0 Bands of 13C16O and 12C18O at 2.3 μm

    NASA Astrophysics Data System (ADS)

    Devi, V. Malathy; Benner, D. Chris; Smith, M. A. H.; Mantz, A. W.; Sung, K.; Brown, L. R.

    2012-06-01

    Air-broadened line shape parameters were determined for the first time in the 2←0 bands of 13C16O near 4166.8 cm-1 and 12C18O near 4159.0 cm-1. Spectra were recorded at 0.005 cm-1 resolution using a coolable absorption cell in the sample compartment of the Bruker IFS 125HR Fourier transform spectrometer at Jet Propulsion Laboratory. Gas temperatures and pressures ranged from 150 to 298 K and 20 to 700 Torr, respectively. Line parameters were determined by broad-band multispectrum least-squares fitting of the 4000-4360 cm-1 region in 16 spectra simultaneously; each set included 4 isotope-enriched pure sample scans and 12 air+CO samples (13CO or C18O, as appropriate). The air-broadened parameters measured were Lorentz half-width coefficients, their temperature dependence exponents; pressure-induced shift coefficients, their temperature dependences; and off-diagonal relaxation matrix elements. Speed dependence parameters were included to minimize the fit residuals. For both isotopologues the individual line positions and intensities were constrained to their theoretical relationships in order to obtain the rovibrational (G, B, D, and H) and band intensity parameters, including Herman-Wallis coefficients. The results for 13C16O and 12C18O are compared with those for the 12C16O 2←0 band and discussed. K. Sung, A. W. Mantz, M. A. H. Smith, et al., JMS 262 (2010) 122-134. D. C. Benner, C. P. Rinsland, V. Malathy Devi, M. A. H. Smith and D. A. Atkins, JQSRT 53 (1995) 705-721. V. Malathy Devi, D. C. Benner, L. R. Brown, C. E. Miller and R. A. Toth, JMS 242 (2007) 90-117. V. Malathy Devi, D. C. Benner, M. A. H. Smith, et al., JQSRT (2012) in press. Research described in this paper was performed at Connecticut College, the College of William and Mary, NASA Langley Research Center and the Jet Propulsion Laboratory, California Institute of Technology, under contracts and cooperative agreements with the National Aeronautics and Space Administration.

  13. Concentration dependence of the wings of a dipole-broadened magnetic resonance line in magnetically diluted lattices

    NASA Astrophysics Data System (ADS)

    Zobov, V. E.; Kucherov, M. M.

    2017-01-01

    The singularities of the time autocorrelation functions (ACFs) of magnetically diluted spin systems with dipole-dipole interaction (DDI), which determine the high-frequency asymptotics of autocorrelation functions and the wings of a magnetic resonance line, are studied. Using the self-consistent fluctuating local field approximation, nonlinear equations are derived for autocorrelation functions averaged over the independent random arrangement of spins (magnetic atoms) in a diamagnetic lattice with different spin concentrations. The equations take into account the specificity of the dipole-dipole interaction. First, due to its axial symmetry in a strong static magnetic field, the autocorrelation functions of longitudinal and transverse spin components are described by different equations. Second, the long-range type of the dipole-dipole interaction is taken into account by separating contributions into the local field from distant and near spins. The recurrent equations are obtained for the expansion coefficients of autocorrelation functions in power series in time. From them, the numerical value of the coordinate of the nearest singularity of the autocorrelation function is found on the imaginary time axis, which is equal to the radius of convergence of these expansions. It is shown that in the strong dilution case, the logarithmic concentration dependence of the coordinate of the singularity is observed, which is caused by the presence of a cluster of near spins whose fraction is small but contribution to the modulation frequency is large. As an example a silicon crystal with different 29Si concentrations in magnetic fields directed along three crystallographic axes is considered.

  14. XRD line-broadening characteristics of M-oxides (M = Mg, Mg-Al, Y, Fe) nanoparticles produced by coprecipitation method

    SciTech Connect

    Pratapa, S.; Susanti, L.; Insany, Y. A. S.; Alfiati, Z.; Hartono, B.; Mashuri,; Triwikantoro; Baqiya, M. A.; Purwaningsih, S.; Yahya, E.; Darminto; Taufiq, Ahmad; Fuad, Abdullah

    2010-10-24

    Simple coprecipitation method has been used to produce nanoparticles of MgO (magnesia), MgO{center_dot}Al{sub 2}O{sub 3}(spinel), Y{sub 2}O{sub 3}(yttria) and Fe{sub 3}O{sub 4}(ferrite). The raw materials were, in respective, magnesium powder, magnesium and aluminium powders, ytrria powder, and natural sand. The coprecipitation included the use of suitable acid and base to dissolve the powders or sand and to produce precipitates, as well as the use of water to wash and purify the precipitates, and drying at relatively low temperatures, namely lower than 100 deg. C, followed by heating at 450 deg. C, 750 deg. C, 600 deg. C and 200 deg. C to produce magnesia, spinel, yttria and ferrite nanopowders, respectively. X-ray diffractometry was used to characterise the purity and nanocrystallinity of the final powders. It was found qualitatively that the powders were of high purity. Further line-broadening analysis using single-line and Rietveld-based softwares was performed to reveal the nanocrystallinity of the powders. Different line breadth values were found for the powders, indicating different crystallite sizes. It was also found that, particularly for spinel and yttria, the diffraction peaks exhibited 'longer' tails, indicating broader crystallite size distribution. The average crystallite size for the powders ranged from 3 to 70 nm. The results could then be used as 'fingerprints' for nanocrystallinity using x-ray diffractometry. The XRD crystallite sizes for yttria and ferrite nanocrystals are in fair agreement with their counterparts from electron microscopy observation.

  15. Carbon-13 nuclear magnetic resonance spectroscopy of lipids: Differential line broadening due to cross-correlation effects as a probe of membrane structure

    SciTech Connect

    Oldfield, E.; Adebodun, F.; Chung, J.; Montez, B.; Ki Deok Park; Hongbiao Le; Phillips, B. )

    1991-11-19

    The authors have obtained proton-coupled carbon-13 nuclear magnetic resonance (NMR) spectra of a variety of lipid-water and lipid-drug-water systems, at 11.7 T, as a function of temperature, using the 'magic-angle' sample-spinning (MAS) NMR technique. The resulting spectra show a wide range of line shapes, due to interferences between dipole-dipole and dipole-chemical shielding anisotropy interactions. The differential line-broadening effects observed are particularly large for aromatic and olefinic (sp{sup 2}) carbon atom sites. Coupled spectra of the tricyclic antidepressants desipramine and imipramine, in 1,2-dimyristoyl-sn-glycero-3-phosphocholine-water mesophases, show well-resolved doublets having different line shapes for each of the four aromatic methine groups, due to selective averaging of the four C-H dipolar interactions due to rapid motion about the director (or drug C{sub 2}) axis. {sup 2}H NMR spectra of (2,4,6,8-{sup 2}H{sub 4})desipramine (and imipramine) in the same 1,2-dimyristoyl-sn-glycero-3-phosphocholine-water mesophase exhibit quadrupole splittings of {approximately}0-2 and {approximately}20 kHz, indicating an approximate magic-angle orientation of the C2-{sup 2}H({sup 1}H) and C8-{sup 2}H({sup 1}H) vectors with respect to an axis of motional averaging, in accord with the {sup 13}C NMR results. The good qualitative agreement between {sup 13}C and {sup 2}H NMR results suggests that useful orientational ({sup 2}H NMR like) information can be deduced from natural-abundance {sup 13}C NMR spectra of a variety of mobile solids.

  16. Diagnostic of the self-healing of metallized polypropylene film by modeling of the broadening emission lines of aluminum emitted by plasma discharge

    NASA Astrophysics Data System (ADS)

    Tortai, J.-H.; Bonifaci, N.; Denat, A.; Trassy, C.

    2005-03-01

    Metallized-film capacitors have the property, even under high continuous voltage, to self-heal i.e., to clear a defect in the dielectric. The self-healing process is a consequence of a transient arc discharge. It has been previously shown that during the discharge, due to Joule effect, the metal is vaporized until the arc extinguishes. The discharge duration has been found to be inversely proportional to the mechanical pressure applied on the layers of metallized films making up a capacitor. The aim of this study is to understand the physical processes involved in this spontaneous extinction of the arc discharge. Emission spectroscopy has been used to provide information about the physical properties (temperatures, electronic and neutral particles densities, etc.) of the plasma induces by a self-healing. An analysis, based on the broadenings and shifts of Al atomic lines, of the experimental light spectra obtained has shown that the self-healing process leads to the generation, from the vaporized metal, of a high-density and relatively weakly ionized aluminum plasma. The plasma density increases with the pressure applied on the film layers and, consequently, the density power needed to extend the plasma zone increases as well and the arc discharge goes out faster as experimentally observed.

  17. Line shape parameters of PH3 transitions in the Pentad near 4–5 μm: Self-broadened widths, shifts, line mixing and speed dependence

    SciTech Connect

    Malathy Devi, V.; Benner, D. C.; Kleiner, Isabelle; Sams, Robert L.; Fletcher, Leigh N.

    2014-08-01

    Accurate knowledge of spectroscopic line parameters of PH3 is important for remote sensing of the outer planets, especially Jupiter and Saturn. In a recent study, line positions and intensities for the Pentad bands of PH3 have been reported from analysis of high-resolution, high signal-to noise room-temperature spectra recorded with two Fourier transform spectrometers (2014) [1]. The results presented in this study were obtained during the analysis of positions and intensities, but here we focus on the measurements of spectral line shapes (e.g. widths, shifts, line mixing) for the 2ν4, ν2 + ν4, ν1 and ν3 bands. A multispectrum nonlinear least squares curve fitting technique employing a non-Voigt line shape to include line mixing and speed dependence of the Lorentz width was employed to fit the spectra simultaneously. The least squares fittings were performed on five room-temperature spectra recorded at various PH3 pressures (~2–50 Torr) with the Bruker IFS-125HR Fourier transform spectrometer (FTS) located at the Pacific Northwest National Laboratory (PNNL), in Richland, Washington. Over 840 Lorentz self-broadened half-width coefficients, 620 self-shift coefficients and 185 speed dependence parameters were measured. Line mixing was detected for transitions in the 2ν4, ν1 and ν3 bands, and their values were quantified for 10 A+A- pairs of transitions via off-diagonal relaxation matrix element formalism. The dependences of the measured half-width coefficients on the J and K rotational quanta of the transitions are discussed. The self-width coefficients for the ν1 and ν3 bands from this study are compared to the self-width coefficients for transitions with the same rotational quanta (J, K) reported for the Dyad (ν2 and ν4) bands. The measurements from present study should be useful for the

  18. H2, He, and CO2 line-broadening coefficients, pressure shifts and temperature-dependence exponents for the HITRAN database. Part 1: SO2, NH3, HF, HCl, OCS and C2H2

    NASA Astrophysics Data System (ADS)

    Wilzewski, Jonas S.; Gordon, Iouli E.; Kochanov, Roman V.; Hill, Christian; Rothman, Laurence S.

    2016-01-01

    To increase the potential for use of the HITRAN database in astronomy, experimental and theoretical line-broadening coefficients, line shifts and temperature-dependence exponents of molecules of planetary interest broadened by H2, He, and CO2 have been assembled from available peer-reviewed sources. The collected data were used to create semi-empirical models so that every HITRAN line of the studied molecules has corresponding parameters. Since H2 and He are major constituents in the atmospheres of gas giants, and CO2 predominates in atmospheres of some rocky planets with volcanic activity, these spectroscopic data are important for remote sensing studies of planetary atmospheres. In this paper we make the first step in assembling complete sets of these parameters, thereby creating datasets for SO2, NH3, HF, HCl, OCS and C2H2.

  19. Interpretation of magnetization transfer from inhomogeneously broadened lines (ihMT) in tissues as a dipolar order effect within motion restricted molecules.

    PubMed

    Varma, G; Girard, O M; Prevost, V H; Grant, A K; Duhamel, G; Alsop, D C

    2015-11-01

    Comparison of off-resonance saturation with single and dual frequency irradiation indicates a contribution of inhomogeneously broadened lines to magnetization transfer in tissues. This inhomogeneous magnetization transfer (ihMT) phenomenon can be exploited to produce images that highlight tissues containing myelin, in vivo. Here, a model for ihMT is described that includes dipolar order effects from magnetization associated with motion-restricted macromolecules. In this model, equal irradiation at positive and negative frequency offsets eliminates dipolar order and achieves greater saturation than irradiation at a single offset frequency using the same power. Fitting of mouse and human volunteer brain data at different irradiation powers and offset frequencies was performed to assess the relevance of the model and approximate tissue parameters. A key parameter in determining ihMT signal was found to be the relaxation time T1D associated with the dipolar order reservoir and the fraction f of the semi-solid, bound magnetization that possessed a nonzero T1D. Indeed, better fits of myelinated tissue were achieved when assuming f≠1. From such fits, estimated T1Ds of mice in the white matter, (34±14) ms, were much longer than in muscle, T1D=(1±1) ms and the average f from white matter volunteer data was 2.2 times greater than that in grey matter. The combination of f and longer T1Ds was primarily responsible for the much higher ihMT in myelinated tissues, and provided explanation for the species variation. This dipolar order ihMT model should help guide future research, pulse sequence optimization, and clinical applications.

  20. Spin exchange broadening of magnetic resonance lines in a high-sensitivity rotating K-Rb-21Ne co-magnetometer

    PubMed Central

    Chen, Yao; Quan, Wei; Zou, Sheng; Lu, Yan; Duan, Lihong; Li, Yang; Zhang, Hong; Ding, Ming; Fang, Jiancheng

    2016-01-01

    Atomic co-magnetometers can be utilized for high-precision angular velocity sensing or fundamental physics tests. The sensitivity of a co-magnetometer determines the angle random walk of an angular velocity sensor and the detection limit for a fundamental physics test. A high-sensitivity K-Rb-21Ne co-magnetometer, which is utilized for angular velocity sensing, is presented in this paper. A new type of spin relaxation of Rb atom spins, which can broaden the zero-field magnetic resonance lines of the co-magnetometer, is discovered. Further studies show that the spin relaxation of Rb atoms is caused by a high Rb electron magnetization field. With this discovery, the total relaxation rate of Rb atoms is optimized to improve the sensitivity of the co-magnetometer. Moreover, its sensitivity is optimized by suppressing various noises. Especially, to suppress laser-related noises, the co-magnetometer is designed such that the sensitive axis of the co-magnetometer can be fixed to the direction in which the projection input of the earth’s rotation is 0. This is called a rotating co-magnetometer. A magnetic field sensitivity of 1.0 fT/Hz−1/2@5 Hz, which is equal to an angular velocity sensitivity of 2.1 × 10−8 rad s−1 Hz−1/2@5 Hz, is demonstrated using a spherical vapour cell with a diameter of 14 mm. PMID:27830744

  1. Spin exchange broadening of magnetic resonance lines in a high-sensitivity rotating K-Rb-(21)Ne co-magnetometer.

    PubMed

    Chen, Yao; Quan, Wei; Zou, Sheng; Lu, Yan; Duan, Lihong; Li, Yang; Zhang, Hong; Ding, Ming; Fang, Jiancheng

    2016-11-10

    Atomic co-magnetometers can be utilized for high-precision angular velocity sensing or fundamental physics tests. The sensitivity of a co-magnetometer determines the angle random walk of an angular velocity sensor and the detection limit for a fundamental physics test. A high-sensitivity K-Rb-(21)Ne co-magnetometer, which is utilized for angular velocity sensing, is presented in this paper. A new type of spin relaxation of Rb atom spins, which can broaden the zero-field magnetic resonance lines of the co-magnetometer, is discovered. Further studies show that the spin relaxation of Rb atoms is caused by a high Rb electron magnetization field. With this discovery, the total relaxation rate of Rb atoms is optimized to improve the sensitivity of the co-magnetometer. Moreover, its sensitivity is optimized by suppressing various noises. Especially, to suppress laser-related noises, the co-magnetometer is designed such that the sensitive axis of the co-magnetometer can be fixed to the direction in which the projection input of the earth's rotation is 0. This is called a rotating co-magnetometer. A magnetic field sensitivity of 1.0 fT/Hz(-1/2)@5 Hz, which is equal to an angular velocity sensitivity of 2.1 × 10(-8) rad s(-1) Hz(-1/2)@5 Hz, is demonstrated using a spherical vapour cell with a diameter of 14 mm.

  2. Interpretation of magnetization transfer from inhomogeneously broadened lines (ihMT) in tissues as a dipolar order effect within motion restricted molecules

    NASA Astrophysics Data System (ADS)

    Varma, G.; Girard, O. M.; Prevost, V. H.; Grant, A. K.; Duhamel, G.; Alsop, D. C.

    2015-11-01

    Comparison of off-resonance saturation with single and dual frequency irradiation indicates a contribution of inhomogeneously broadened lines to magnetization transfer in tissues. This inhomogeneous magnetization transfer (ihMT) phenomenon can be exploited to produce images that highlight tissues containing myelin, in vivo. Here, a model for ihMT is described that includes dipolar order effects from magnetization associated with motion-restricted macromolecules. In this model, equal irradiation at positive and negative frequency offsets eliminates dipolar order and achieves greater saturation than irradiation at a single offset frequency using the same power. Fitting of mouse and human volunteer brain data at different irradiation powers and offset frequencies was performed to assess the relevance of the model and approximate tissue parameters. A key parameter in determining ihMT signal was found to be the relaxation time T1D associated with the dipolar order reservoir and the fraction f of the semi-solid, bound magnetization that possessed a nonzero T1D. Indeed, better fits of myelinated tissue were achieved when assuming f ≠ 1. From such fits, estimated T1Ds of mice in the white matter, (34 ± 14)ms, were much longer than in muscle, T1D = (1 ± 1)ms and the average f from white matter volunteer data was 2.2 times greater than that in grey matter. The combination of f and longer T1Ds was primarily responsible for the much higher ihMT in myelinated tissues, and provided explanation for the species variation. This dipolar order ihMT model should help guide future research, pulse sequence optimization, and clinical applications.

  3. Spin exchange broadening of magnetic resonance lines in a high-sensitivity rotating K-Rb-21Ne co-magnetometer

    NASA Astrophysics Data System (ADS)

    Chen, Yao; Quan, Wei; Zou, Sheng; Lu, Yan; Duan, Lihong; Li, Yang; Zhang, Hong; Ding, Ming; Fang, Jiancheng

    2016-11-01

    Atomic co-magnetometers can be utilized for high-precision angular velocity sensing or fundamental physics tests. The sensitivity of a co-magnetometer determines the angle random walk of an angular velocity sensor and the detection limit for a fundamental physics test. A high-sensitivity K-Rb-21Ne co-magnetometer, which is utilized for angular velocity sensing, is presented in this paper. A new type of spin relaxation of Rb atom spins, which can broaden the zero-field magnetic resonance lines of the co-magnetometer, is discovered. Further studies show that the spin relaxation of Rb atoms is caused by a high Rb electron magnetization field. With this discovery, the total relaxation rate of Rb atoms is optimized to improve the sensitivity of the co-magnetometer. Moreover, its sensitivity is optimized by suppressing various noises. Especially, to suppress laser-related noises, the co-magnetometer is designed such that the sensitive axis of the co-magnetometer can be fixed to the direction in which the projection input of the earth’s rotation is 0. This is called a rotating co-magnetometer. A magnetic field sensitivity of 1.0 fT/Hz‑1/2@5 Hz, which is equal to an angular velocity sensitivity of 2.1 × 10‑8 rad s‑1 Hz‑1/2@5 Hz, is demonstrated using a spherical vapour cell with a diameter of 14 mm.

  4. Multispectrum measurements of spectral line parameters including temperature dependences of N2- and self-broadened half-width coefficients in the region of the v9 band of 12C2H6

    SciTech Connect

    Malathy Devi, V.; Benner, D. C.; Rinsland, C.P.; Smith, M.A.H.; Sams, Robert L.; Blake, Thomas A.; Flaud, Jean Marie; Sung, Keeyoon; Brown, L.R.; Mantz, A. W.

    2010-11-01

    Ethane is a prominent contributor to the spectrum of Titan, particularly in the region of the v9 band at 12μm. A multispectrum nonlinear least squares fitting program was applied to laboratory spectra of ethane to measure accurate positions, absolute intensities, N2- and selfbroadened half- width coefficients and their temperature dependences for a large number transitions. These measurements include several pQ and rQ sub-bands (and other sub-bands such as pP, rR) in the v9 fundamental band of 12C2H6 centered near 822 cm-1. Positions were measured for 2958 transitions and intensities for 3771 transitions. N2- and self-broadened half-width coefficients were determined for over 1700 transitions while temperature dependence exponents were retrieved for over 1350 of those transitions. Of these, many measurements (mostly line positions and intensities) belong to the v9+v4-v4 hot band, v9+2v4-2v4 hot band, 13C12CH6 v9 band and unidentified transitions. Forty-three high resolution (0.0016-0.005 cm-1) infrared laboratory absorption spectra recorded at temperatures between 148 and 298 K were fitted simultaneously to retrieve these parameters. Forty-one of these spectra were obtained in the temperature range of 211-298 K using the Bruker IFS 120HR interferometer located at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington. Two additional spectra at 148 K were recorded using a new temperature stabilized cryogenic cell designed to work inside the sample compartment of the high resolution Bruker IFS 125HR interferometer of the Jet Propulsion Laboratory (JPL) in Pasadena California. The specialized cooling cell developed at Connecticut College and capable of achieving gas sample temperatures down to 70 K with a temperature stability and uniformity of better than ±0.05 K was employed to record the 148 K spectra. Constraints to intensity ratios, doublet separations, half-width coefficients and their temperature dependence exponents were required to

  5. Homogeneous and inhomogeneous broadenings and the Voigt line shapes in the phase-resolved and intensity sum-frequency generation vibrational spectroscopy

    SciTech Connect

    Chen, Shunli; Fu, Li; Gan, Wei; Wang, Hongfei

    2016-01-21

    In this report we show that the ability to measure the sub-1 cm-1 resolution phase-resolved and intensity high-resolution broadband sum frequency generation vibrational spectra (HR-BB-SFG-VS) of the –CN stretch vibration of the Langmuir-Blodgett (LB) monolayer of the 4-n-octyl-4’-cyanobiphenyl (8CB) on the z-cut α-quartz surface allows for the first time the direct comparison and understanding of the homogeneous and inhomogeneous broadenings in the imaginary and intensity SFG vibrational spectral lineshapes in detail. The difference of the full width at half maxima (FWHM) of the imaginary and intensity SFG-VS spectra of the same vibrational mode is the signature of the Voigt lineshape and it measures the relative contribution to the overall lineshape from the homogeneous and inhomogeneous broadenings in SFG vibrational spectra. From the phase-resolved and intensity spectra, we found that the FWHM of the 2238.00 ±0.02 cm-1 peak in the phase-resolved imaginary and intensity spectra is 19.2 ± 0.2 cm-1 and 21.6 ± 0.4 cm-1, respectively, for the –CN group of the 8CB LB monolayer on the z-cut α-quartz crystal surface. The FWHM width difference of 2.4 cm-1 agrees quantitatively with a Voigt lineshape with a homogeneous broadening half width of Γ = 5.29 ± 0.08 cm-1 and a inhomogeneous standard derivation width Δω = 5.42 ± 0.07 cm-1. These results shed new lights on the understanding and interpretation of the lineshapes of both the phase-resolved and the intensity SFG vibrational spectra, as well as other incoherent and coherent spectroscopic techniques in general.

  6. Broadening Transfer Opportunities

    ERIC Educational Resources Information Center

    Dearing, Bruce

    1975-01-01

    Broadened opportunity for transfer offers a potential for bolstering sagging enrollments, and increases capacities for accomodating the educational needs of a broader spectrum of a democratic society. (Author/KE)

  7. The recurrent PPP1CB mutation p.Pro49Arg in an additional Noonan-like syndrome individual: Broadening the clinical phenotype.

    PubMed

    Bertola, Débora; Yamamoto, Guilherme; Buscarilli, Michelle; Jorge, Alexander; Passos-Bueno, Maria Rita; Kim, Chong

    2017-03-01

    We report on a 12-year-old Brazilian boy with the p.Pro49Arg mutation in PPP1CB, a novel gene associated with RASopathies. This is the fifth individual described, and the fourth presenting the same variant, suggesting a mutational hotspot. Phenotypically, he also showed the same hair pattern-sparse, thin, and with slow growing-, similar to the typical ectodermal finding observed in Noonan syndrome-like disorder with loose anagen hair. Additionally, he presented craniosynostosis, a rare clinical finding in RASopathies. This report gives further support that this novel RASopathy-PPP1CB-related Noonan syndrome with loose anagen hair-shares great similarity to Noonan syndrome-like disorder with loose anagen hair, and expands the phenotypic spectrum by adding the cranial vault abnormality. © 2017 Wiley Periodicals, Inc.

  8. Pressure broadening of oxygen by water

    NASA Astrophysics Data System (ADS)

    Drouin, Brian J.; Payne, Vivienne; Oyafuso, Fabiano; Sung, Keeyoon; Mlawer, Eli

    2014-01-01

    A need for precise air-mass retrievals utilizing the near-infrared O2 A-band has motivated measurements of the water-broadening in oxygen. Experimental challenges have resulted in very little water broadened oxygen data. Existing water broadening data for the O2 A-band is of insufficient precision for application to the atmospheric data. Line shape theory suggests that approximate O2 pressure broadening parameters for one spectral region, such as the A-band, may be obtained from comparable spectral regions such as the O2 60 GHz Q-branch, which is also used prominently in remote sensing. We have measured precise O2-H2O broadening for the 60 GHz Q-branch and the pure-rotational transitions at room temperature with a Zeeman-modulated absorption cell using a frequency-multiplier spectrometer. Intercomparisons of these data and other O2 pressure broadening data sets confirm the expectation of only minor band-to-band scaling of pressure broadening. The measurement provides a basis for fundamental parameterization of retrieval codes for the long-wavelength atmospheric measured values. Finally, we demonstrate the use of these measurements for retrievals of air-mass via remote sensing of the oxygen A-band.

  9. The Relaxation Matrix for Symmetric Tops with Inversion Symmetry. I. Effects of Line Coupling on Self-Broadened v (sub 1) and Pure Rotational Bands of NH3

    NASA Technical Reports Server (NTRS)

    Ma, Q.; Boulet, C.

    2016-01-01

    The Robert-Bonamy formalism has been commonly used to calculate half-widths and shifts of spectral lines for decades. This formalism is based on several approximations. Among them, two have not been fully addressed: the isolated line approximation and the neglect of coupling between the translational and internal motions. Recently, we have shown that the isolated line approximation is not necessary in developing semi-classical line shape theories. Based on this progress, we have been able to develop a new formalism that enables not only to reduce uncertainties on calculated half-widths and shifts, but also to model line mixing effects on spectra starting from the knowledge of the intermolecular potential. In our previous studies, the new formalism had been applied to linear and asymmetric-top molecules. In the present study, the method has been extended to symmetric-top molecules with inversion symmetry. As expected, the inversion splitting induces a complete failure of the isolated line approximation. We have calculated the complex relaxation matrices of selfbroadened NH3. The half-widths and shifts in the ?1 and the pure rotational bands are reported in the present paper. When compared with measurements, the calculated half-widths match the experimental data very well, since the inapplicable isolated line approximation has been removed. With respect to the shifts, only qualitative results are obtained and discussed. Calculated off-diagonal elements of the relaxation matrix and a comparison with the observed line mixing effects are reported in the companion paper (Paper II).

  10. Comparison of Trajectory Models in Calculations of N2-broadened Half-widths and N2-induced Line Shifts for the Rotational Band of H2O-16 and Comparison with Measurements

    NASA Technical Reports Server (NTRS)

    Lamouroux, J.; Gamache, R. R.; Laraia, A. L.; Ma, Q.; Tipping, R. H.

    2012-01-01

    In this work, Complex Robert-Bonamy calculations of half-widths and line shifts were done for N2-broadening of water for 1639 transitions in the rotational band using two models for the trajectories. The first is a model correct to second order in time, the Robert-Bonamy parabolic approximation. The second is the solution of Hamilton's equations. Both models use the isotropic part of the atom-atom potential to determine the trajectories. The present calculations used an intermolecular potential expanded to 20th order to assure the convergence of the half-widths and line shifts. The aim of the study is to assess if the difference in the half-widths and line shifts determined from the two trajectory models is greater than the accuracy requirements of the spectroscopic and remote sensing communities. The results of the calculations are compared with measurements of the half-widths and line shifts. It is shown that the effects of the trajectory model greatly exceed the needs of current remote sensing measurements and that line shape parameters calculated using trajectories determined by solving Hamilton's equations agree better with measurement.

  11. Cytogenetic and molecular identification of three Triticum aestivum-Leymus racemosus translocation addition lines.

    PubMed

    Wang, Le; Yuan, Jianhua; Bie, Tongde; Zhou, Bo; Chen, Peidu

    2009-06-01

    Chromosome 2C from Aegilops cylindrica has the ability to induce chromosome breakage in common wheat (Tritivum aestivum). In the BC(1)F(3) generation of the T. aestivum cv. Chinese Spring and a hybrid between T. aestivum-Leymus racemosus Lr.7 addition line and T. aestivum-Ae. cylindrica 2C addition line, three disomic translocation addition lines (2n = 44) were selected by mitotic chromosome C-banding and genomic in situ hybridization. We further characterized these T. aestivum-L. racemosus translocation addition lines, NAU636, NAU637 and NAU638, by chromosome C-banding, in situ hybridization using the A- and D-genome-specific bacterial artificial chromosome (BAC) clones 676D4 and 9M13; plasmids pAs1 and pSc119.2, and 45S rDNA; as well as genomic DNA of L. racemosus as probes, in combination with double ditelosomic test cross and SSR marker analysis. The translocation chromosomes were designated as T3AS-Lr7S, T6BS-Lr7S, and T5DS-Lr7L. The translocation line T3AS-Lr7S was highly resistant to Fusarium head blight and will be useful germplasm for resistance breeding.

  12. Stark broadening effect and zirconium conflict problem

    NASA Astrophysics Data System (ADS)

    Dimitrijević, Milan S.; Popović, Luka Č.; Milovanović, Nenad

    2001-04-01

    Using the Modified Semiempirical Method we have calculated the electron-impact widths for four singly and doubly ionized zirconium UV lines of astrophysical importance. Using the SYNTH and ATLAS9 codes for stellar atmospheres similar to that of the HgMn star χ Lupi we have synthesized the line profiles and found equivalent widths for these lines. The influence of the Stark broadening effect on abundance determination and its contribution to the so-called ``zirconium conflict'' are discussed. .

  13. Broadening, Deepening, and Consolidating

    ERIC Educational Resources Information Center

    Cumming, Alister

    2004-01-01

    I encourage the editors of and contributors to "Language Assessment Quarterly" to continue, and to extend, three directions that are integral to the development of the field of language assessment: (a) to broaden the scope of inquiry and contexts that inform knowledge about language assessment; (b) to deepen the theoretical premises and…

  14. Spectral shapes of Ar-broadened HCl lines in the fundamental band by classical molecular dynamics simulations and comparison with experiments

    SciTech Connect

    Tran, H.; Domenech, J.-L.

    2014-08-14

    Spectral shapes of isolated lines of HCl perturbed by Ar are investigated for the first time using classical molecular dynamics simulations (CMDS). Using reliable intermolecular potentials taken from the literature, these CMDS provide the time evolution of the auto-correlation function of the dipole moment, whose Fourier-Laplace transform leads to the absorption spectrum. In order to test these calculations, room temperature spectra of various lines in the fundamental band of HCl diluted in Ar are measured, in a large pressure range, with a difference-frequency laser spectrometer. Comparisons between measured and calculated spectra show that the CMDS are able to predict the large Dicke narrowing effect on the shape of HCl lines and to satisfactorily reproduce the shapes of HCl spectra at different pressures and for various rotational quantum numbers.

  15. New developments in the theory of pressure-broadening and pressure-shifting of spectral lines of H2O: the complex Robert-Bonamy formalism.

    NASA Astrophysics Data System (ADS)

    Gamache, R. R.; Lynch, R.; Neshyba, S. P.

    1998-05-01

    Calculations of the halfwidth and line shift of water vapor perturbed by N2, O2, CO2 and H2 based on a complex implementation of the formalism of Robert and Bonamy are made. The potentials employ the leading terms of the electrostatic potential, a Lennard-Jones (6-12) atom-atom potential, and the induction and dispersion components of the isotropic potential. The dynamics of the collisions are correct to second order in time. The results are compared with measurements and very good agreement is observed for both halfwidths and line shifts. A new feature in this approach is that the real and imaginary components of the S matrix affect both the halfwidth and the line shift. It is shown here that the imaginary parts of the S matrix strongly affect the calculated halfwidths for some of the systems considered.

  16. SMM observations of gamma-ray transients. 3: A search for a broadened, redshifted positron annihilation line from the direction of the Galactic center

    NASA Technical Reports Server (NTRS)

    Harris, Michael J.; Share, Gerald H.; Leising, Mark D.

    1994-01-01

    We have searched for 1980-1988 Solar Maximum Mission gamma-ray spectrometer data for transient emission on timescales from hours to approximately 12 days of broad gamma-ray lines at energies approximately 400 keV, which were reported by the High Energy Astronomy Observatory (HEAO) 1 and SIGMA experiments from two sources lying toward the Galactic center. The lines have been interpreted as the product of the annihilation of positrons in pair plasmas surrounding the black hole candidate 1E 1740.7-2942 and the X-ray binary 1H 1822-371. Our results from a combined exposure of approximately 1.5 x 10(exp 7)s provide no convincing evidence for transient emission of this line on any timescale between approximately 9 hr and approximately 1 yr. Our 3 sigma upper limits on the line flux during approximately 12 day intervals are characteristically 4.8 x 10(exp -3) photon/sq cm/s, while for approximately 1 day intervals our 3 sigma upper limits are characteristically 4.9 x 10(exp -3) photon/sq cm/s. These results imply a duty cycle of less than 1.3% for the transient line measured from 1H 1822-371 during a approximately 3 week interval in 1977 by HEAO 1, and a duty cycle of less than or = 0.8% for the transient line detected in 1990 and 1992 from 1E 1740.7-2942 on approximately 1 day timescales by SIGMA.

  17. Spectral diagnostics based on Doppler-broadened H{sub α} line shape in a single element of a matrix source

    SciTech Connect

    Iordanova, S.; Pashov, A.

    2015-04-08

    The study is on optical emission spectroscopy diagnostics of a single element of a matrix source of negative hydrogen ions. The method developed for description of the hydrogen atoms behaviour is based on analysis of the Balmer H{sub α} line profile, and it can be readily applied to various low pressure hydrogen discharges. The present observations reveal the existence of thermal as well as of non-thermal fast hydrogen atoms in the discharge. For processing of the experimental data a line shape model, which accounts for details of the plasma kinetics and the fine structure of the Balmer lines is developed. The fit of this model to the recorded at different experimental conditions line shapes results in the temperature of the thermal atoms, the mean energy of the fast atoms, the ratio between the densities of these two group of atoms and the relative populations of the fine structure components of the n = 3 hydrogen state. The present study indicates that the reactions leading to production of fast atoms and the process of energy exchange between thermal and fast atoms may be important for the correct modeling of the plasma kinetics.

  18. Khα1,2 X-Ray Hypersatellite Line Broadening as a Signature of K-Shell Double Photoionization Followed by Outer-Shell Ionization and Excitation

    NASA Astrophysics Data System (ADS)

    Polasik, M.; Słabkowska, K.; Rzadkiewicz, J.; Kozioł, K.; Starosta, J.; Wiatrowska-Kozioł, E.; Dousse, J.-Cl.; Hoszowska, J.

    2011-08-01

    We propose a novel approach for the theoretical analysis of the photoinduced high-resolution Khα1,2 x-ray hypersatellite spectra, which allows us to obtain reliable values of lifetimes of the doubly K-shell ionized states and fundamental information about the relative role of K-shell double photoionization (DPI) mechanisms. It is demonstrated for the first time that the Khα1,2 hypersatellite natural line broadening observed for selected metal atoms with 20≤Z≤30 can be well reproduced quantitatively by taking into account the influences of the open-shell valence configuration (adopted from predictions of the band-structure method) and the outer-shell ionization and excitation following the DPI process.

  19. Temperature-dependent pressure broadened line shape measurements in the ν 1+ ν 3 band of acetylene using a diode laser referenced to a frequency comb

    NASA Astrophysics Data System (ADS)

    Cich, M. J.; McRaven, C. P.; Lopez, G. V.; Sears, T. J.; Hurtmans, D.; Mantz, A. W.

    2012-11-01

    Using an extended cavity diode laser referenced to a femtosecond frequency comb, the P(11) absorption line in the ν 1+ ν 3 combination band of the most abundant isotopologue of pure acetylene was studied at temperatures of 296, 240, 200, 175, 165, 160, 155, and 150 K to determine pressure-dependent line shape parameters at these temperatures. The laser emission profile, the instrumental resolution, is a Lorentz function characterized by a half width at half the maximum emission (HWHM) of 8.3×10-6 cm-1 (or 250 kHz) for these measurements. Six collision models were tested in fitting the experimental data: Voigt, speed-dependent Voigt, Rautian-Sobel'man, Galatry, and two Rautian-Galatry hybrid models (with and without speed-dependence). Only the speed-dependent Voigt model was able to fit the data to the experimental noise level at all temperatures and for pressures between 3 and nearly 360 torr. The variations of the speed-dependent Voigt profile line shape parameters with temperature were also characterized, and this model accurately reproduces the observations over their entire range of temperature and pressure.

  20. Model for Assembly Line Re-Balancing Considering Additional Capacity and Outsourcing to Face Demand Fluctuations

    NASA Astrophysics Data System (ADS)

    Samadhi, TMAA; Sumihartati, Atin

    2016-02-01

    The most critical stage in a garment industry is sewing process, because generally, it consists of a number of operations and a large number of sewing machines for each operation. Therefore, it requires a balancing method that can assign task to work station with balance workloads. Many studies on assembly line balancing assume a new assembly line, but in reality, due to demand fluctuation and demand increased a re-balancing is needed. To cope with those fluctuating demand changes, additional capacity can be carried out by investing in spare sewing machine and paying for sewing service through outsourcing. This study develops an assembly line balancing (ALB) model on existing line to cope with fluctuating demand change. Capacity redesign is decided if the fluctuation demand exceeds the available capacity through a combination of making investment on new machines and outsourcing while considering for minimizing the cost of idle capacity in the future. The objective of the model is to minimize the total cost of the line assembly that consists of operating costs, machine cost, adding capacity cost, losses cost due to idle capacity and outsourcing costs. The model develop is based on an integer programming model. The model is tested for a set of data of one year demand with the existing number of sewing machines of 41 units. The result shows that additional maximum capacity up to 76 units of machine required when there is an increase of 60% of the average demand, at the equal cost parameters..

  1. The STARK-B database VAMDC node: a repository for spectral line broadening and shifts due to collisions with charged particles

    NASA Astrophysics Data System (ADS)

    Sahal-Bréchot, S.; Dimitrijević, M. S.; Moreau, N.; Ben Nessib, N.

    2015-05-01

    Accurate spectroscopic diagnostics and modeling require the knowledge of numerous collisional line profiles. Access to such data via an online database has become indispensable. The STARK-B database is aimed at meeting these needs for widths and shifts of isolated lines of neutral and ionized elements due to electron and ion impacts. This database of the Paris Observatory is a result of scientific cooperation between S Sahal-Bréchot (LERMA) and M S Dimitrijević (AOB). Access to it is free, and it was opened online at the end of 2008. STARK-B is a node of the Virtual Atomic and Molecular Data Centre (VAMDC) and thus complies with VAMDC and Virtual Observatory standards. VAMDC is a European Union-funded collaboration among groups involved in the generation and use of interoperable atomic and molecular data. STARK-B now contains all our semiclassical-perturbation (SCP) calculated data for more than 123 neutral or ionized elements as published in international refereed journals. It is devoted to modeling and spectroscopic diagnostics of stellar atmospheres and envelopes, laboratory plasmas, laser equipment, and technological plasmas. Hence, the range of temperatures and densities covered by the tables is broad and depends on the ionization degree of the radiating atom. The modified semiempirical (MSE) results of calculations have begun to be implemented. In this paper, we highlight the key points of the method and the assumptions used in the calculations, which have lately been revisited. Then we present the database and its recent developments, as well as our ongoing work and our plans for the future.

  2. Additives

    NASA Technical Reports Server (NTRS)

    Smalheer, C. V.

    1973-01-01

    The chemistry of lubricant additives is discussed to show what the additives are chemically and what functions they perform in the lubrication of various kinds of equipment. Current theories regarding the mode of action of lubricant additives are presented. The additive groups discussed include the following: (1) detergents and dispersants, (2) corrosion inhibitors, (3) antioxidants, (4) viscosity index improvers, (5) pour point depressants, and (6) antifouling agents.

  3. Number line estimation and mental addition: examining the potential roles of language and education.

    PubMed

    Laski, Elida V; Yu, Qingyi

    2014-01-01

    This study investigated the relative importance of language and education to the development of numerical knowledge. Consistent with previous research suggesting that counting systems that transparently reflect the base-10 system facilitate an understanding of numerical concepts, Chinese and Chinese American kindergartners' and second graders' number line estimation (0-100 and 0-1000) was 1 to 2 years more advanced than that of American children tested in previous studies. However, Chinese children performed better than their Chinese American peers, who were fluent in Chinese but had been educated in America, at kindergarten on 0-100 number lines, at second grade on 0-1000 number lines, and at both time points on complex addition problems. Overall, the pattern of findings suggests that educational approach may have a greater influence on numerical development than the linguistic structure of the counting system. The findings also demonstrate that, despite generating accurate estimates of numerical magnitude on 0-100 number lines earlier, it still takes Chinese children approximately 2 years to demonstrate accurate estimates on 0-1000 number lines, which raises questions about how to promote the mapping of knowledge across numerical scales.

  4. Measurement of the Temperature Dependence of Line Mixing and Pressure Broadening Parameters between 296 and 90 K in the v3 band of 12CH4 and their Influence on Atmospheric Methane Retrievals

    NASA Technical Reports Server (NTRS)

    Mondelain, Didier; Payan, Sebastien; Deng, Wenping; Camy-Peyret, Claude; Hurtmans, Daniel; Mantz, Arlan W.

    2007-01-01

    We measured the temperature dependence of the nitrogen broadening, narrowing and line-mixing coefficients of four lines of the P9 manifold in the v3 band of 12CH4 for atmospheric purposes. The data were collected using our tunable diode laser (TDL) spectrometer with active wavenumber control coupled to a newly developed cold Herriott cell with a path length of 5.37 m and a temperature uniformity of better than 0.01 K along the cell. We recorded and analyzed spectra recorded at sample temperature between 90 K and room temperature. We have investigate the influence of our new results in the inversion model used to retrieve methane profiles from atmospheric spectra; our new results make it possible to retrieve significantly more precise methane profiles. The atmospheric spectra we utilized were obtained by several of us with a balloon-born Fourier Transform infrared experiment in a limb configuration. Differences up to 7% on the retrieved volume mixing ratio were found compared to an inversion model using only HITRAN04 spectroscopic parameters.

  5. abo-cross: Hydrogen broadening cross-section calculator

    NASA Astrophysics Data System (ADS)

    Barklem, P. S.; Anstee, S. D.; O'Mara, B. J.

    2015-07-01

    Line broadening cross sections for the broadening of spectral lines by collisions with neutral hydrogen atoms have been tabulated by Anstee & O'Mara (1995), Barklem & O'Mara (1997) and Barklem, O'Mara & Ross (1998) for s-p, p-s, p-d, d-p, d-f and f-d transitions. abo-cross, written in Fortran, interpolates in these tabulations to make these data more accessible to the end user. This code can be incorporated into existing spectrum synthesis programs or used it in a stand-alone mode to compute line broadening cross sections for specific transitions.

  6. Development and characterization of potato-Solanum brevidens chromosomal addition/substitution lines.

    PubMed

    Dong, F; Tek, A L; Frasca, A B L; McGrath, J M; Wielgus, S M; Helgeson, J P; Jiang, J

    2005-01-01

    Solanum brevidens is a wild diploid potato species possessing high levels of resistances to several major potato diseases. We previously developed fertile somatic hybrids between S. brevidens and the cultivated potato (Solanum tuberosum) in order to introgress disease resistances from this wild species into potato. A series of backcross progenies was developed from a hexaploid somatic hybrid A206. Using a combination of S. brevidens-specific randomly amplified polymorphic DNA (RAPD) markers and a sequential genomic in situ hybridization (GISH) and fluorescence in situ hybridization (FISH) technique, we identified all 12 S. brevidens chromosomes in the backcross progenies. Seven potato-S. brevidens monosomic chromosome addition lines (chromosomes 1, 3, 4, 5, 8, 9 and 10) and one monosomic substitution line (chromosome 6) were identified, and the remaining four S. brevidens chromosomes (2, 7, 11, and 12) were included in two other lines. These chromosomal addition/substitution stocks provide valuable tools for potato cytogenetic research, and can be used to introgress disease resistances from S. brevidens into potato.

  7. Line-broadened quasilinear burst model

    SciTech Connect

    Berk, H.L.; Breizman, B.N.; Wong, H.V.; Fitzpatrick, J.

    1995-07-01

    A quasilinear model is developed to produce realistic self-consistent saturation levels when modes do not overlap, and give self-consistent diffusion and wave evolution when modes do overlap. Both regimes give steady or pulsating behavior in weakly driven systems with classical relaxation and background dissipation present. An avalanche response is demonstrated: wave momentum release caused by the overlap of closely spaced modes can produce mode overlap of more widely spaced modes (a domino effect) or the growth of modes which would be stable in systems unaffected by the closely-spaced modes` diffusion. Detailed analysis and calculations are performed for the bump-on-tail instability, and extension of the method to more general problems is briefly discussed.

  8. Absolute intensities and foreign gas broadening coefficients of the 11(sub 1,10) from 11(sub 2,10) and 18(sub 0,18) from 18(sub 1,18) lines in the nu(sub 7) band of C2H4

    NASA Technical Reports Server (NTRS)

    Reuter, Dennis C.; Sirota, J. Marcos

    1993-01-01

    Absolute intensities and foreign gas broadening coefficients of the 18(sub 0,18) from 18(sub 1,18) and 11(sub 1,10) from 11(sub 2,10) transitions in the nu(sub 7) band of C2H4 near 948/cm have been measured at a spectral resolution of approximately 5 x 10(exp -4)/cm using tunable diode laser spectrometry. Ar, He, N2, O2 were used as the broadening gases. In order to determine the temperature dependence of the broadening coefficient, data were obtained at temperatures ranging from 150 to 296 K. The absolute intensity of the 5(sub 0,5) from 5(sub 1,5) transition was also found at 296 K. A band strength of 330 +/- 10/sq cm/atm was obtained from weighted averages of the individual line intensities and a rigid asymmetric top calculation.

  9. Method for decomposing observed line shapes resulting from multiple causes - Application to plasma charge-exchange-neutral spectra

    NASA Technical Reports Server (NTRS)

    Patch, R. W.

    1979-01-01

    A method is given for decomposing the widths of observed spectral lines resulting from unresolved line splitting, additive kinetic processes of different types, instrumental broadening (slit function), Doppler broadening, etc. all superimposed. The second moments are used as measures of the various widths involved. The method is not applicable if dispersion type (Lorentz) broadening occurs. Application is made to plasma charge-exchange-neutral spectra of hydrogen, deuterium, and helium.

  10. Comparative proteomic analysis of drug sodium iron chlorophyllin addition to Hep 3B cell line.

    PubMed

    Zhang, Jun; Wang, Wenhai; Yang, Fengying; Zhou, Xinwen; Jin, Hong; Yang, Peng-yuan

    2012-09-21

    The human hepatoma 3B cell line was chosen as an experimental model for in vitro test of drug screening. The drugs included chlorophyllin and its derivatives such as fluo-chlorophyllin, sodium copper chlorophyllin, and sodium iron chlorophyllin. The 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-tetrazolium bromide (MTT) method was used in this study to obtain the primary screening results. The results showed that sodium iron chlorophyllin had the best LC(50) value. Proteomic analysis was then performed for further investigation of the effect of sodium iron chlorophyllin addition to the Hep 3B cell line. The proteins identified from a total protein extract of Hep 3B before and after the drug addition were compared by two-dimensional-gel-electrophoresis. Then 32 three-fold differentially expressed proteins were successfully identified by MALDI-TOF-TOF-MS. There are 29 unique proteins among those identified proteins. These proteins include proliferating cell nuclear antigen (PCNA), T-complex protein, heterogeneous nuclear protein, nucleophosmin, heat shock protein A5 (HspA5) and peroxiredoxin. HspA5 is one of the proteins which are involved in protecting cancer cells against stress-induced apoptosis in cultured cells, protecting them against apoptosis through various mechanisms. Peroxiredoxin has anti-oxidant function and is related to cell proliferation, and signal transduction. It can protect the oxidation of other proteins. Peroxiredoxin has a close relationship with cancer and can eventually become a disease biomarker. This might help to develop a novel treatment method for carcinoma cancer.

  11. Corrigendum to "Line shape parameters measurement and computations for self-broadened carbon dioxide transitions in the 30012 ← 00001 and 30013 ← 00001 bands, line mixing, and speed dependence" [J. Mol. Spectrosc. 245 (2007) 34-51

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, A.; Unni, A. V.; Liu, W.; Schofield, I.; Holladay, C.; McKellar, A. R. W.; Hurtmans, D.

    2016-04-01

    The authors have been notified that there may be errors in the spectroscopic analysis presented in this published article. While the authors are re-analysing the spectra in a different approach, we would like to ask the readers to ignore the discussion of line parameters other than line positions. We would like to assure the readers that we are preparing follow-up manuscripts where we will compare our new results with those published earlier. These manuscripts will be submitted for publication in the same journal.

  12. Pressure broadening of atomic oxygen two-photon absorption laser induced fluorescence

    NASA Astrophysics Data System (ADS)

    Marinov, Daniil; Drag, Cyril; Blondel, Christophe; Guaitella, Olivier; Golda, Judith; Klarenaar, Bart; Engeln, Richard; Schulz-von der Gathen, Volker; Booth, Jean-Paul

    2016-12-01

    Atomic oxygen, considered to be a determining reactant in plasma applications at ambient pressure, is routinely detected by two-photon absorption laser induced fluorescence (TALIF). Here, pressure broadening of the (2p 4 3 P 2  →  3p 3 P J=0,1,2) two-photon transition in oxygen atoms was investigated using a high-resolution TALIF technique in normal and Doppler-free configurations. The pressure broadening coefficients determined were {γ{{\\text{O}2}}}   =  0.40  ±  0.08  cm-1/bar for oxygen molecules and {γ\\text{He}}   =  0.46  ±  0.03 cm-1/bar for helium atoms. These correspond to pressure broadening rate constants k\\text{PB}{{\\text{O}2}}   =  9 · 10-9 cm3 s-1 and k\\text{PB}\\text{He}   =  4 · 10-9 cm3 s-1, respectively. The well-known quenching rate constants of O(3p 3 P J ) by O2 and He are at least one order of magnitude smaller, which signifies that non-quenching collisions constitute the main line-broadening mechanism. In addition to providing new insights into collisional processes of oxygen atoms in electronically excited 3p 3 P J state, reported pressure broadening parameters are important for quantification of oxygen TALIF line profiles when both collisional and Doppler broadening mechanisms are important. Thus, the Doppler component (and hence the temperature of oxygen atoms) can be accurately determined from high resolution TALIF measurements in a broad range of conditions.

  13. Proteomic analysis of salt tolerance in sugar beet monosomic addition line M14.

    PubMed

    Yang, Le; Zhang, Yanjun; Zhu, Ning; Koh, Jin; Ma, Chunquan; Pan, Yu; Yu, Bing; Chen, Sixue; Li, Haiying

    2013-11-01

    Understanding the mechanisms of plant salinity tolerance can facilitate plant engineering for enhanced salt stress tolerance. Sugar beet monosomic addition line M14 obtained from the intercross between Beta vulgaris L. and Beta corolliflora Zoss exhibits tolerance to salt stress. Here we report the salt-responsive characteristics of the M14 plants under 0, 200, and 400 mM NaCl conditions using quantitative proteomics approaches. Proteins from control and the salt treated M14 plants were separated using 2D-DIGE. Eighty-six protein spots representing 67 unique proteins in leaves and 22 protein spots representing 22 unique proteins in roots were identified. In addition, iTRAQ LC-MS/MS was employed to identify and quantify differentially expressed proteins under salt stress. Seventy-five differentially expressed proteins in leaves and 43 differentially expressed proteins in roots were identified. The proteins were mainly involved in photosynthesis, energy, metabolism, protein folding and degradation, and stress and defense. Moreover, gene transcription data obtained from the same samples were compared to the corresponding protein data. Thirteen proteins in leaves and 12 in roots showed significant correlation in gene expression and protein levels. These results suggest the important processes for the M14 tolerance to salt stress include enhancement of photosynthesis and energy metabolism, accumulation of osmolyte and antioxidant enzymes, and regulation of methionine metabolism and ion uptake/exclusion.

  14. Second-order quadrupolar line shapes under molecular dynamics: An additional transition in the extremely fast regime.

    PubMed

    Hung, Ivan; Wu, Gang; Gan, Zhehong

    2016-12-10

    NMR spectroscopy is a powerful tool for probing molecular dynamics. For the classic case of two-site exchange, NMR spectra go through the transition from exchange broadening through coalescence and then motional narrowing as the exchange rate increases passing through the difference between the resonance frequencies of the two sites. For central-transition spectra of half-integer quadrupolar nuclei in solids, line shape change due to molecular dynamics occurs in two stages. The first stage occurs when the exchange rate is comparable to the second-order quadrupolar interaction. The second spectral transition comes at a faster exchange rate which approaches the Larmor frequency and generally reduces the isotropic quadrupolar shift. Such a two-stage transition phenomenon is unique to half-integer quadrupolar nuclei. A quantum mechanical formalism in full Liouville space is presented to explain the physical origin of the two-stage phenomenon and for use in spectral simulations. Variable-temperature (17)O NMR of solid NaNO3 in which the NO3(-) ion undergoes 3-fold jumps confirms the two-stage transition process. The spectra of NaNO3 acquired in the temperature range of 173-413K agree well with simulations using the quantum mechanical formalism. The rate constants for the 3-fold NO3(-) ion jumps span eight orders of magnitude (10(2)-10(10)s(-1)) covering both transitions of the dynamic (17)O line shape.

  15. EPA Proposes Additional Water Line Connections for Groundwater Contamination at Tinkham Garage Superfund Site in Londonderry, NH

    EPA Pesticide Factsheets

    The U.S. EPA in consultation with NHDES, is proposing additional connections to an existing water line for residents whose wells have been found to have contamination and whom live northeast section of the Tinkham Garage Superfund Site (Site).

  16. Evaluation of on-line chelant addition to PWR steam generators. Steam generator cleaning project

    SciTech Connect

    Tvedt, T.J.; Wallace, S.L.; Griffin, F. Jr.

    1983-09-01

    The investigation of chelating agents for continuous water treatment of secondary loops of PWR steam generators were conducted in two general areas: the study of the chemistry of chelating agents and the study of materials compatability with chelating agents. The thermostability of both EDTA and HEDTA metal chelates in All Volatile Treatment (AVT) water chemistry were shown to be greater than or equal to the thermostability of EDTA metal chelates in phosphate-sulfite water chemistry. HEDTA metal chelates were shown to have a much greater stability than EDTA metal chelates. Using samples taken from the EDTA metal chelate thermostability study and from the Commonwealth Research Corporation (CRC) model steam generators (MSG), EDTA decomposition products were determined. Active metal surfaces were shown to become passivated when exposed to EDTA and HEDTA concentrations as high as 0.1% w/w in AVT. Trace amounts of iron in the water were found to increase the rate of passivation. Material balance and visual inspection data from CRC model steam generators showed that metal was transported through and cleaned from the MSG's. The Inconel 600 tubes of the salt water fouled model steam generators experienced pitting corrosion. Results of this study demonstrates the feasibility of EDTA as an on-line water treatment additive to maintain nuclear steam generators in a clean condition.

  17. Broadening nanotechnology's impact on development

    NASA Astrophysics Data System (ADS)

    Beumer, Koen

    2016-05-01

    Discussions about nanotechnology and development focus on applications that directly address the needs of the world's poor. Nanotechnology can certainly make an impact in the fight against global poverty, but we need to broaden our imagination.

  18. Differing metabolic responses to salt stress in wheat-barley addition lines containing different 7H chromosomal fragments

    PubMed Central

    Gierczik, Krisztián; Hudák, Orsolya; Forgó, Péter; Pál, Magda; Türkösi, Edina; Kovács, Viktória; Dulai, Sándor; Majláth, Imre; Molnár, István; Janda, Tibor; Molnár-Láng, Márta

    2017-01-01

    Salinity-induced osmotic, ionic and oxidative stress responses were investigated on Asakaze/Manas wheat/barley addition lines 7H, 7HL and 7HS, together with their barley (salt-tolerant) and wheat (relatively salt-sensitive) parents. Growth, photosynthetic activity, chlorophyll degradation, proline, glycine betaine accumulation, sugar metabolism, Na+ and K+ uptake and transport processes and the role of polyamines and antioxidants were studied in young plants grown in hydroponic culture with or without salt treatment. Changes in plant growth and photosynthetic activity of plants demonstrated that the salt tolerance of the addition lines 7H and 7HL was similar to that of barley parent cv. Manas, while the sensitivity of the addition line 7HS was similar to that of the wheat parent cv. Asakaze. The Na accumulation in the roots and shoots did not differ between the addition lines and wheat parent. The activation of various genes related to Na uptake and transport was not correlated with the salt tolerance of the genotypes. These results indicated that the direct regulation of Na transport processes is not the main reason for the salt tolerance of these genotypes. Salt treatment induced a complex metabolic rearrangement in both the roots and shoots of all the genotypes. Elevated proline accumulation in the roots and enhanced sugar metabolism in the shoots were found to be important for salt tolerance in the 7H and 7HL addition lines and in barley cv. Manas. In wheat cv. Asakaze and the 7HS addition line the polyamine metabolism was activated. It seems that osmotic adjustment is a more important process in the improvement of salt tolerance in 7H addition lines than the direct regulation of Na transport processes or antioxidant defence. PMID:28328973

  19. Exact expression of the impact broadening operator for hydrogen Stark broadening

    NASA Astrophysics Data System (ADS)

    Gigosos, M. A.; González, M. Á.; Talin, B.; Calisti, A.

    2007-05-01

    Aims:Recent measurements on the Stark broadening of radio recombination lines show values and trends in disagreement with conventional theories. Different attemps to explain those disagreements have not been successfull for any of the employed theoretical models. In particular, the impact model that describes well the physical conditions at which the studied broadenings occur, shows a functional trend upon the principal quantum number of the studied transitions that does not correspond to the experimental observations. Methods: High values of the principal quantum number require computable formulas for the calculation of transition probabilities. Some of those expressions have been published, leading to approximate formulas on the dependence of the line width versus the principal quantum number of the upper level of the transition. Results: In this work an exact expression for the hydrogen Stark width in the frame of impact approximation is given.

  20. [Features of alloplasmic wheat-barley substitution and addition lines (Hordeum marinum subsp. gussoneanum)-triticum aestivum].

    PubMed

    Pershina, L A; Deviatkina, E P; Belova, L I; Trubacheeva, N V; Arbuzova, V S; Kravtsova, L A

    2009-10-01

    Two alloplasmic wheat-barley substitution lines were studied: a line replaced at three pairs of chromosomes 1Hmr((IB), 5Hmar(5D), and 7Hmar(7D), and the disomic-substituted line 7Hma(7D). The lines were constructed on the basis of individual plants from BCIF8- and BC2F6 progeny of barley-wheat hybrids (H. marinum subsp. gussoneanum Hudson (=H. geniculatum All.) (2n = 28) x T. aestivum L.) (2n = 42) (Pyrotrix 28), respectively. Moreover, the alloplasmic wheat-barley ditelosomic addition line 7HLma' isolated among plants from the BC1F6 progeny of a barley-wheat amphiploid was studied, which in this work corresponds to BC2F10 and BC2F11 progeny. It was ascertained that when grown in the field, these alloplasmic lines manifest stable self-fertility. Plants of the given lines are characterized by low height, shortened ears, the fewer number of stems and ears, and of spikelets in the ear, by decreased grain productivity and weight of 1000 grains, in comparison with the common wheat cultivar Pyrotrix 28. The inhibition of trait expression in alloplasmic wheat-barley substitution and addition lines may be connected not only with the influence of wild barley chromosomes functioning in the genotypic environment of common wheat, but also with the effect of the barley cytoplasm. The alloplasmic line with substitution of chromosomes 1Hmar(1B), 5Hmar(5D), and 7Hmar(7D) or the alloplasmic line 7HLmar with ditelosomic addition have, in comparison with the common wheat cultivar Pyrotrix 28, an increased grain protein content, which is explained by the effect of wild barley H. marinum subsp. gussoneanum chromosomes.

  1. Stark Broadening Parameters For White Dwarf Atmospheres Research

    NASA Astrophysics Data System (ADS)

    Larbi-Terzi, N.; Sahal-Brechot, S.; Nessib, N. B.; Dimitrijevic, M. S.

    2010-07-01

    Stark broadening parameters of C II lines were determined within 3d-nf series using semiclassical perturbation method. The atomic energy levels needed for calculations were taken from TOPBASE as well as the oscillator strengths, which were additionally calculated using the method of Bates and Damgaard. The both results were compared and only insignificant differences were found. Calculations were performed for plasma conditions relevant for atmospheres of DQ white dwarfs and for a new type of white dwarfs, with surface composed mostly of carbon, discovered in 2007 by Dufour et al. The aim of this work is to provide accurate C II Stark broadening data, which are crucial for this type of white dwarf atmosphere modellisation. Obtained results will be included in STARK-B database (http://stark-b.obspm.fr/), entering in the FP7 project of European Virtual Atomic and Molecular Data Center VAMDC aiming at building an interoperable e- Infrastructure for the exchange of atomic and molecular data (http://www.vamdc.org/).

  2. Stark broadening measurements in plasmas produced by laser ablation of hydrogen containing compounds

    NASA Astrophysics Data System (ADS)

    Burger, Miloš; Hermann, Jörg

    2016-08-01

    We present a method for the measurement of Stark broadening parameters of atomic and ionic spectral lines based on laser ablation of hydrogen containing compounds. Therefore, plume emission spectra, recorded with an echelle spectrometer coupled to a gated detector, were compared to the spectral radiance of a plasma in local thermal equilibrium. Producing material ablation with ultraviolet nanosecond laser pulses in argon at near atmospheric pressure, the recordings take advantage of the spatially uniform distributions of electron density and temperature within the ablated vapor. By changing the delay between laser pulse and detector gate, the electron density could be varied by more than two orders of magnitude while the temperature was altered in the range from 6,000 to 14,000 K. The Stark broadening parameters of transitions were derived from their simultaneous observation with the hydrogen Balmer alpha line. In addition, assuming a linear increase of Stark widths and shifts with electron density for non-hydrogenic lines, our measurements indicate a change of the Stark broadening-dependence of Hα over the considered electron density range. The presented results obtained for hydrated calcium sulfate (CaSO4ṡ2H2O) can be extended to any kind of hydrogen containing compounds.

  3. The IACOB project . III. New observational clues to understand macroturbulent broadening in massive O- and B-type stars

    NASA Astrophysics Data System (ADS)

    Simón-Díaz, S.; Godart, M.; Castro, N.; Herrero, A.; Aerts, C.; Puls, J.; Telting, J.; Grassitelli, L.

    2017-01-01

    Context. The term macroturbulent broadening is commonly used to refer to a certain type of non-rotational broadening affecting the spectral line profiles of O- and B-type stars. It has been proposed to be a spectroscopic signature of the presence of stellar oscillations; however, we still lack a definitive confirmation of this hypothesis. Aims: We aim to provide new empirical clues about macroturbulent spectral line broadening in O- and B-type stars to evaluate its physical origin. Methods: We used high-resolution spectra of 430 stars with spectral types in the range O4 - B9 (all luminosity classes) compiled in the framework of the IACOB project. We characterized the line broadening of adequate diagnostic metal lines using a combined Fourier transform and goodness-of-fit technique. We performed a quantitative spectroscopic analysis of the whole sample using automatic tools coupled with a huge grid of fastwind models to determine their effective temperatures and gravities. We also incorporated quantitative information about line asymmetries into our observational description of the characteristics of the line profiles, and performed a comparison of the shape and type of line-profile variability found in a small sample of O stars and B supergiants with still undefined pulsational properties and B main-sequence stars with variable line profiles owing to a well-identified type of stellar oscillations or to the presence of spots in the stellar surface. Results: We present a homogeneous and statistically significant overview of the (single snapshot) line-broadening properties of stars in the whole O and B star domain. We find empirical evidence of the existence of various types of non-rotational broadening agents acting in the realm of massive stars. Even though all these additional sources of line-broadening could be quoted and quantified as a macroturbulent broadening from a practical point of view, their physical origin can be different. Contrarily to the early- to

  4. Medical vest broadens treatment capability

    NASA Technical Reports Server (NTRS)

    Johnson, G. S.

    1970-01-01

    Universal sized vest, with specially tailored pockets designed to hold medical supplies, provides first aid/first care medical teams with broadened on-site capability. Vest is made of nylon, tough fibrous materials, and polyvinyl chloride. Design facilitates rapid donning, doffing, and adjustment.

  5. Microdissection and chromosome painting of the alien chromosome in an addition line of wheat-Thinopyrum intermedium

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The chromosome painting is an efficient tool for chromosome research. However, plant chromosome painting is relatively underdeveloped. In this study, chromosome painting was developed and used to identify alien chromosomes in TAi-27, a wheat-Thinopyrum intermedium addition line, and chromosomes of...

  6. Coherent Forward Broadening in Cold Atom Clouds

    NASA Astrophysics Data System (ADS)

    Sutherland, R. T.; Robicheaux, Francis

    2016-05-01

    It is shown that homogeneous line-broadening in a diffuse cold atom cloud is proportional to the resonant optical depth of the cloud. Further, it is demonstrated how the strong directionality of the coherent interactions causes the cloud's spectra to depend strongly on its shape, even when the cloud is held at constant densities. These two numerical observations can be predicted analytically by extending the single photon wavefunction model. Lastly, elongating a cloud along the line of laser propagation causes the excitation probability distribution to deviate from the exponential decay predicted by the Beer-Lambert law to the extent where the atoms in the back of the cloud are more excited than the atoms in the front. These calculations are conducted at low densities relevant to recent experiments. This work was supported by the National Science Foundation under Grant No. 1404419-PHY.

  7. Coherent forward broadening in cold atom clouds

    NASA Astrophysics Data System (ADS)

    Sutherland, R. T.; Robicheaux, F.

    2016-02-01

    It is shown that homogeneous line-broadening in a diffuse cold atom cloud is proportional to the resonant optical depth of the cloud. Furthermore, it is demonstrated how the strong directionality of the coherent interactions causes the cloud's spectra to depend strongly on its shape, even when the cloud is held at constant densities. These two numerical observations can be predicted analytically by extending the single-photon wave-function model. Lastly, elongating a cloud along the line of laser propagation causes the excitation probability distribution to deviate from the exponential decay predicted by the Beer-Lambert law to the extent where the atoms at the back of the cloud are more excited than the atoms at the front. These calculations are conducted at the low densities relevant to recent experiments.

  8. Spectral broadening in anatase titanium dioxide waveguides at telecommunication and near-visible wavelengths.

    PubMed

    Evans, Christopher C; Shtyrkova, Katia; Bradley, Jonathan D B; Reshef, Orad; Ippen, Erich; Mazur, Eric

    2013-07-29

    We observe spectral broadening of femtosecond pulses in single-mode anatase-titanium dioxide (TiO(2)) waveguides at telecommunication and near-visible wavelengths (1565 and 794 nm). By fitting our data to nonlinear pulse propagation simulations, we quantify nonlinear optical parameters around 1565 nm. Our fitting yields a nonlinear refractive index of 0.16 × 10(-18) m(2)/W, no two-photon absorption, and stimulated Raman scattering from the 144 cm(-1) Raman line of anatase with a gain coefficient of 6.6 × 10(-12) m/W. Additionally, we report on asymmetric spectral broadening around 794 nm. The wide wavelength applicability and negligible two-photon absorption of TiO(2) make it a promising material for integrated photonics.

  9. Broadening and shifting of the Raman Q branch of HD

    SciTech Connect

    Rosasco, G.J.; May, A.D.; Hurst, W.S.; Petway, L.B.; Smyth, K.C.

    1989-02-15

    The line broadening and shifting of the vibrational Q branch in pure HD has was measured for transitions J = 0 to 3 at room temperature over the density range 0.8 to 10.6 amagat. The shifting and broadening coefficients were determined with an uncertainty of + or - .0002/cm/amaget, which now provides a discriminating test for various semiclassical and quantal theoretical calculations. The line broadening coefficients are compared with linewidth data from other spectroscopic branches and with measurements of the rates of state-to-state rotational energy transfer. Use of an exponential gap law for the rates of rotational energy transfer allows estimates to be made of the contributions to the linewidths from rotationally inelastic, elastic vibrational dephasing, and elastic reorientation processes. This analysis suggests that rotational energy transfer occurs approximately 30% faster in v = 1 than in v = 0.

  10. Broadening and shifting of the Raman Q branch of HD

    SciTech Connect

    Rosasco, G.J.; May, A.D.; Hurst, W.S.; Petway, L.B.; Smyth, K.C.

    1989-02-15

    The line broadening and shifting of the vibrational Q branch in pure HD has been measured for transitions J = 0 to 3 at room temperature over the density range 0.8 to 10.6 amagat. The shifting and broadening coefficients have been determined with an uncertainty of +- 0.2 x 10/sup -3/ cm/sup -1/ /amagat, which now provides a discriminating test for various semiclassical and quantal theoretical calculations. The line broadening coefficients are compared with linewidth data from other spectroscopic branches and with measurements of the rates of state-to-state rotational energy transfer. Use of an exponential gap law for the rates of rotational energy transfer allows estimates to be made of the contributions to the linewidths from rotationally inelastic, elastic vibrational dephasing, and elastic reorientation processes. This analysis suggests that rotational energy transfer occurs approximately 30% faster in v = 1 than in v = 0.

  11. Molecular cytogenetic identification of a wheat-rye 1R addition line with multiple spikelets and resistance to powdery mildew.

    PubMed

    Yang, Wujuan; Wang, Changyou; Chen, Chunhuan; Wang, Yajuan; Zhang, Hong; Liu, Xinlun; Ji, Wanquan

    2016-04-01

    Alien addition lines are important for transferring useful genes from alien species into common wheat. Rye is an important and valuable gene resource for improving wheat disease resistance, yield, and environment adaptation. A new wheat-rye addition line, N9436B, was developed from the progeny of the cross of common wheat (Triticum aestivum L., 2n = 6x = 42, AABBDD) cultivar Shaanmai 611 and rye (Secale cereal L., 2n = 2x = 14, RR) accession Austrian rye. We characterized this new line by cytology, genomic in situ hybridization (GISH), fluorescence in situ hybridization (FISH), molecular markers, and disease resistance screening. N9436B was stable in morphology and cytology, with a chromosome composition of 2n = 42 + 2t = 22II. GISH investigations showed that this line contained two rye chromosomes. GISH, FISH, and molecular maker identification suggested that the introduced R chromosome and the missing wheat chromosome arms were 1R chromosome and 2DL chromosome arm, respectively. N9436B exhibited 30-37 spikelets per spike and a high level of resistance to powdery mildew (Blumeria graminis f. sp. tritici, Bgt) isolate E09 at the seedling stage. N9436B was cytologically stable, had the trait of multiple spikelets, and was resistant to powdery mildew; this line should thus be useful in wheat improvement.

  12. Experimental studies by complementary terahertz techniques and semi-classical calculations of N2- broadening coefficients of CH335Cl

    NASA Astrophysics Data System (ADS)

    Guinet, M.; Rohart, F.; Buldyreva, J.; Gupta, V.; Eliet, S.; Motiyenko, R. A.; Margulès, L.; Cuisset, A.; Hindle, F.; Mouret, G.

    2012-07-01

    Room-temperature N2-broadening coefficients of methyl chloride rotational lines are measured over a large interval of quantum numbers (6≤J≤50, 0≤K≤18) by a submillimeter frequency-multiplication chain (J≤31) and a terahertz photomixing continuous-wave spectrometer (J≥31). In order to check the accuracy of both techniques, the measurements of identical lines are compared for J=31. The pressure broadening coefficients are deduced from line fits using mainly a Voigt profile model. The excellent signal-to-noise ratio of the frequency-multiplication scheme highlights some speed dependence effect on the line shape. Theoretical values of these coefficients are calculated by a semi-classical approach with exact trajectories. An intermolecular potential including atom-atom interactions is used for the first time. It is shown that, contrary to the previous theoretical predictions, the contributions of short-range forces are important for all values of the rotational quantum numbers. Additional testing of modifications required in the semi-classical formalism for a correct application of the cumulant expansion is also performed. It is stated that the use of the cumulant average on the rotational states of the perturbing molecule leads, for high J and small K values, to slightly higher line-broadening coefficients, as expected for the relatively strong interacting CH3Cl-N2 system. The excellent agreement between the theoretical and the experimental results ensures the reliability of these data.

  13. Determination of Van der Waals broadening at temperatures of astrophysical interest.

    NASA Technical Reports Server (NTRS)

    Evans, J. M., Jr.; Cooper, J.

    1972-01-01

    Discussion of the results of experiments analyzing the widths of shock-excited emission lines at temperatures of about 5000 K. The width of two neutral silicon lines (4102 and 5948 A) were measured as broadened by argon, and the shift of one of these lines (4102 A) was determined. Likewise, the width one of the lines of cesium (4593 A) was measured as broadened by argon and neon. These data are compared with other experimental data to determine the temperature dependence of the broadening. Significant disagreements with simple theory are found, the experimental values of the widths being larger than the theoretical values by factors of 1.5-2.

  14. Implementation of on-the-fly doppler broadening in MCNP

    SciTech Connect

    Martin, W. R.; Wilderman, S.; Brown, F. B.; Yesilyurt, G.

    2013-07-01

    A new method to obtain Doppler broadened cross sections has been implemented into MCNP, removing the need to generate cross sections for isotopes at problem temperatures. When a neutron of energy E enters a material region that is at some temperature T, the cross sections for that material at temperature T are immediately obtained 'on-the-fly' (OTF) by interpolation using a high order functional expansion for the temperature dependence of the Doppler-broadened cross section for that isotope at the neutron energy E. The OTF cross sections agree with the NJOY-based cross sections for all neutron energies and all temperatures in the range specified by the user, e.g., 250 K - 3200 K. The OTF methodology has been successfully implemented into the MCNP Monte Carlo code and has been tested on several test problems by comparing MCNP with conventional ACE cross sections versus MCNP with OTF cross sections. The test problems include the Doppler defect reactivity benchmark suite and two full-core VHTR configurations, including one with multiphysics coupling using RELAP5-3D/ATHENA for the thermal-hydraulic analysis. The comparison has been excellent, verifying that the OTF libraries can be used in place of the conventional ACE libraries generated at problem temperatures. In addition, it has been found that the OTF methodology greatly reduces the complexity of the input for MCNP, resulting in an order of magnitude decrease in the number of input lines for full-core configurations. Finally, for full-core problems with multiphysics feedback, the memory required to store the cross section data is considerably reduced with OTF cross sections and the additional computational effort with OTF is modest, on the order of 10-15%. (authors)

  15. Extension of H-alpha/H-beta Photometry to Additional Luminosity Classes and Emission Line Objects

    NASA Astrophysics Data System (ADS)

    Hintz, Eric G.; Joner, Michael D.

    2017-01-01

    In Joner & Hintz (2015) they presented a fully calibrated H-alpha index based on spectroscopic observations of main sequence stars ranging from O9 to K2. In that work they provided relations between the H-alpha index, temperature, and equivalent width. In Didelon (1982) the relation between spectral type and equivalent width is examined with a clear difference between luminosity classes. In this poster we will present results from a spectroscopic examination of the H-alpha/H-beta relations. First we will examine the equivalent width as a function of luminosity class. Then we will examine the extension of the H-alpha system for application to emission line objects.We would like to acknowledge use of the Dominion Astrophysical Observatory 1.2-m Telescope.

  16. Single-layer and bilayer graphene superlattices: collimation, additional Dirac points and Dirac lines.

    PubMed

    Barbier, Michaël; Vasilopoulos, Panagiotis; Peeters, François M

    2010-12-13

    We review the energy spectrum and transport properties of several types of one-dimensional superlattices (SLs) on single-layer and bilayer graphene. In single-layer graphene, for certain SL parameters an electron beam incident on an SL is highly collimated. On the other hand, there are extra Dirac points generated for other SL parameters. Using rectangular barriers allows us to find analytical expressions for the location of new Dirac points in the spectrum and for the renormalization of the electron velocities. The influence of these extra Dirac points on the conductivity is investigated. In the limit of δ-function barriers, the transmission T through and conductance G of a finite number of barriers as well as the energy spectra of SLs are periodic functions of the dimensionless strength P of the barriers, Pδ(x) = V(x)/ħv(F), with v(F) the Fermi velocity. For a Kronig-Penney SL with alternating sign of the height of the barriers, the Dirac point becomes a Dirac line for P = π/2+nπ with n an integer. In bilayer graphene, with an appropriate bias applied to the barriers and wells, we show that several new types of SLs are produced and two of them are similar to type I and type II semiconductor SLs. Similar to single-layer graphene SLs, extra 'Dirac' points are found in bilayer graphene SLs. Non-ballistic transport is also considered.

  17. Hydrogen Stark broadening by different kinds of model microfields

    NASA Astrophysics Data System (ADS)

    Seidel, J.

    1980-07-01

    A new model microfield is defined (the theta process) which in conjunction with the kangaroo process, is used to demonstrate the effects of different model microfields on hydrogen line profiles. The differences in the statistical features of the models give an estimate of the uncertainties associated with the method of model microfields. Stark broadening of hydrogen Lyman lines by either electrons or ions is investigated specifically.

  18. Understanding Doppler Broadening of Gamma Rays

    SciTech Connect

    Rawool-Sullivan, Mohini; Sullivan, John P.

    2014-07-03

    Doppler-broadened gamma ray peaks are observed routinely in the collection and analysis of gamma-ray spectra. If not recognized and understood, the appearance of Doppler broadening can complicate the interpretation of a spectrum and the correct identification of the gamma ray-emitting material. We have conducted a study using a simulation code to demonstrate how Doppler broadening arises and provide a real-world example in which Doppler broadening is found. This report describes that study and its results.

  19. High-resolution TALIF measurements of atomic oxygen: determination of gas temperature and collisional broadening coefficients

    NASA Astrophysics Data System (ADS)

    Booth, Jean-Paul; Marinov, Daniil; Guaitella, Olivier; Drag, Cyril; Engeln, Richard; Golda, Judith; Schultz-von der Gathern, Volker

    2016-09-01

    Two-photon Absorption Laser-Induced Fluorescence (TALIF) is a well-established technique to measure relative (and with appropriate calibration techniques, absolute) densities of atoms in plasmas and flames. The excitation line profiles can provide additional information, but this is usually overlooked due to the mediocre spectral resolution of commercial pulsed dye laser systems. We have investigated O-atom TALIF excitation line profiles using a house-built narrow line-width pulsed UV laser system, based on pulsed Ti:Sa ring laser seeded by a cw infrared diode laser. The observed Doppler profiles allow unambiguous measurement of gas temperature with high precision in O2 and CO2 DC glow discharges. Sub-Doppler measurements, performed by reflecting the laser beam back through excitation zone, allow the pressure-broadened line shapes to be observed, both in a pure O2 DC discharge (up to 10 Torr pressure) and in an atmospheric pressure RF plasma jet in He/O2. Pressure broadening coefficients of the 3p3PJ state of O were determined for O2 and He bath gases, and were found to be an order of magnitude bigger than that predicted from the measured quenching rate. Work performed in the LABEX Plas@par project, with financial state aid (ANR-11-IDEX-0004-02 and ANR-13-BS09-0019).

  20. Gas Temperature Determination in Argon-Helium Plasma at Atmospheric Pressure using van der Waals Broadening

    SciTech Connect

    Munoz, Jose; Yubero, Cristina; Calzada, Maria Dolores; Dimitrijevic, Milan S.

    2008-10-22

    The use of the van der Waals broadening of Ar atomic lines to determine the gas temperature in Ar-He plasmas, taking into account both argon and helium atoms as perturbers, has been analyzed. The values of the gas temperature inferred from this broadening have been compared with those obtained from the spectra of the OH molecular species in the discharge.

  1. Chromosomal Localization of Genes Conferring Desirable Agronomic Traits from Wheat-Agropyron cristatum Disomic Addition Line 5113.

    PubMed

    Li, Qingfeng; Lu, Yuqing; Pan, Cuili; Yao, Miaomiao; Zhang, Jinpeng; Yang, Xinming; Liu, Weihua; Li, Xiuquan; Xi, Yajun; Li, Lihui

    2016-01-01

    Creation of wheat-alien disomic addition lines and localization of desirable genes on alien chromosomes are important for utilization of these genes in genetic improvement of common wheat. In this study, wheat-Agropyron cristatum derivative line 5113 was characterized by genomic in situ hybridization (GISH) and specific-locus amplified fragment sequencing (SLAF-seq), and was demonstrated to be a novel wheat-A. cristatum disomic 6P addition line. Compared with its parent Fukuhokomugi (Fukuho), 5113 displayed multiple elite agronomic traits, including higher uppermost internode/plant height ratio, larger flag leaf, longer spike length, elevated grain number per spike and spikelet number per spike, more kernel number in the middle spikelet, more fertile tiller number per plant, and enhanced resistance to powdery mildew and leaf rust. Genes conferring these elite traits were localized on the A. cristatum 6P chromosome by using SLAF-seq markers and biparental populations (F1, BC1F1 and BC1F2 populations) produced from the crosses between Fukuho and 5113. Taken together, chromosomal localization of these desirable genes will facilitate transferring of high-yield and high-resistance genes from A. cristatum into common wheat, and serve as the foundation for the utilization of 5113 in wheat breeding.

  2. Chromosomal Localization of Genes Conferring Desirable Agronomic Traits from Wheat-Agropyron cristatum Disomic Addition Line 5113

    PubMed Central

    Pan, Cuili; Yao, Miaomiao; Zhang, Jinpeng; Yang, Xinming; Liu, Weihua; Li, Xiuquan; Xi, Yajun; Li, Lihui

    2016-01-01

    Creation of wheat-alien disomic addition lines and localization of desirable genes on alien chromosomes are important for utilization of these genes in genetic improvement of common wheat. In this study, wheat-Agropyron cristatum derivative line 5113 was characterized by genomic in situ hybridization (GISH) and specific-locus amplified fragment sequencing (SLAF-seq), and was demonstrated to be a novel wheat-A. cristatum disomic 6P addition line. Compared with its parent Fukuhokomugi (Fukuho), 5113 displayed multiple elite agronomic traits, including higher uppermost internode/plant height ratio, larger flag leaf, longer spike length, elevated grain number per spike and spikelet number per spike, more kernel number in the middle spikelet, more fertile tiller number per plant, and enhanced resistance to powdery mildew and leaf rust. Genes conferring these elite traits were localized on the A. cristatum 6P chromosome by using SLAF-seq markers and biparental populations (F1, BC1F1 and BC1F2 populations) produced from the crosses between Fukuho and 5113. Taken together, chromosomal localization of these desirable genes will facilitate transferring of high-yield and high-resistance genes from A. cristatum into common wheat, and serve as the foundation for the utilization of 5113 in wheat breeding. PMID:27824906

  3. Effects of 946-nm thermal shift and broadening on Nd3+:YAG laser performance

    NASA Astrophysics Data System (ADS)

    Seyed Ebrahim, Pourmand; Ghasem, Rezaei

    2015-12-01

    Spectroscopic properties of flashlamp pumped Nd3+:YAG laser are studied as a function of temperature in a range from -30 °C to 60 °C. The spectral width and shift of quasi three-level 946.0-nm inter-Stark emission within the respective intermanifold transitions of 4F3/2 → 4I9/2 are investigated. The 946.0-nm line shifts toward the shorter wavelength and broadens. In addition, the threshold power and slope efficiency of the 946.0-nm laser line are quantified with temperature. The lower the temperature, the lower the threshold power is and the higher the slope efficiency of the 946.0-nm laser line is, thus the higher the laser output is. This phenomenon is attributed to the ion-phonon interaction and the thermal population in the ground state. Project supported by Estahban Branch, Islamic Azad University.

  4. Comparative proteomic analysis of apomictic monosomic addition line of Beta corolliflora and Beta vulgaris L. in sugar beet.

    PubMed

    Zhu, Hong; Bi, Ying-Dong; Yu, Li-Jie; Guo, De-Dong; Wang, Bai-Chen

    2009-11-01

    Apomixis refers to a process in which plants produce seed without fertilization through female syngamy that produces embryos genetically identical to the maternal parent. In sugar beet, interspecific hybrids between diploid Beta vulgaris and tetraploid Beta corolliflora were established and monosomic addition line M14 was selected because of the apomictic phenotype. By using two-dimensional electrophoresis gels we identified the proteins which were differently expressed between the M14 and B. vulgaris. A total of 27 protein spots which varied expressed between lines were isolated and successfully identified with MALDI-TOF MS. Among them five protein spots were found to be only presented in M14 and two protein spots only expressed in Beta. According to their functional annotations described in Swissprot database, these proteins were, respectively, involved in important biological pathways, such as cell division, functionally classified using the KEGG functional classification system. The result may be useful for us to better understand the genetic mechanism of apomixes.

  5. Infrared Spectra of N_2-BROADENED 13CH_4 at Titan Atmospheric Temperatures

    NASA Astrophysics Data System (ADS)

    Smith, M. A. H.; Sung, K.; Brown, L. R.; Crawford, T. J.; Mantz, A. W.; Devi, V. Malathy; Benner, D. Chris

    2010-06-01

    High-resolution spectra of the ν_4 fundamental band of 13CH_4 broadened by N_2 at temperatures relevant to the atmosphere of Titan (80 K to 296 K) have been recorded using new temperature-controlled absorption cells installed in the sample compartment of a Bruker (IFS-125HR) Fourier Transform spectrometer (FTS) at the Jet Propulsion Laboratory (JPL). Details of the cells and spectrometer performance have been discussed in the previous talk. Early analysis of these spectra using multispectrum fitting has determined half widths, pressure-induced shifts, line mixing parameters and their temperature dependences for R-branch transitions from R(0) through R(6). In addition to the initial R(2) study mentioned in the previous talk, the analysis for the other J-manifolds examined in detail whether or not the N_2-broadened half width coefficients follow the simple power-law temperature-dependence over the entire temperature range from 80 K to 296 K. The results are compared with other published measurements of N_2-broadened methane parameters at low temperatures. A. W. Mantz et al., Closed-cycle He-cooled absorption cells designed for a Bruker IFS-125HR: First results between 79 K and 297 K, this session. Research described in this paper was performed at Connecticut College, the College of William and Mary, NASA Langley Research Center and the Jet Propulsion Laboratory, California Institute of Technology, under contracts and cooperative agreements with the National Aeronautics and Space Administration.

  6. Wavefront holoscopy: application of digital in-line holography for the inspection of engraved marks in progressive addition lenses

    NASA Astrophysics Data System (ADS)

    Perucho, Beatriz; Micó, Vicente

    2014-01-01

    Progressive addition lenses (PALs) are engraved with permanent marks at standardized locations in order to guarantee correct centering and alignment throughout the manufacturing and mounting processes. Out of the production line, engraved marks provide useful information about the PAL as well as act as locator marks to re-ink again the removable marks. Even though those marks should be visible by simple visual inspection with the naked eye, engraving marks are often faint and weak, obscured by scratches, and partially occluded and difficult to recognize on tinted or antireflection-coated lenses. Here, we present an extremely simple optical device (named as wavefront holoscope) for visualization and characterization of permanent marks in PAL based on digital in-line holography. Essentially, a point source of coherent light illuminates the engraved mark placed just before a CCD camera that records a classical Gabor in-line hologram. The recorded hologram is then digitally processed to provide a set of high-contrast images of the engraved marks. Experimental results are presented showing the applicability of the proposed method as a new ophthalmic instrument for visualization and characterization of engraved marks in PALs.

  7. A study of Stark broadening for the diagnostic of runaway electrons in ITER

    NASA Astrophysics Data System (ADS)

    Rosato, J.; Pandya, S. P.; Logeais, Ch.; Meireni, M.; Hannachi, I.; Reichle, R.; Barnsley, R.; Marandet, Y.; Stamm, R.

    2017-03-01

    We investigate the Stark broadening of hydrogen lines in tokamak edge plasma conditions in the presence of a beam of relativistic "runaway" electrons. The possibility for a diagnostic involving passive spectroscopy is discussed.

  8. High resolution diode laser spectroscopy of H2O spectra broadened by nitrogen and noble gases

    NASA Astrophysics Data System (ADS)

    Kapitanov, Venedikt A.; Osipov, Konstantin Yu.; Protasevich, Alexander E.; Ponurovskiy, Yakov Ya.

    2014-11-01

    The absorption spectra of pure H2O with mixtures of broadening gases N2, Ar, Xe, He, Ar and air have been measured in 1.39 mμ spectral region by high resolution spectrometer based on diode laser (DFB NEL, Japan). For the processing of pure water spectra and it's mixtures with a different broadening gases in a wide pressure range we used a multispectrum fitting procedure developed at IAO. The program is based on a relatively simple Rautian-Sobel'man line profile and linear pressure dependence of the line profile parameters. H2O measured spectra bulk processing results in the retrieving of such line parameters: zero-pressure line center positions, intensities, self-broadening and self-shift coefficients of pure water, broadening and shift coefficients for other gases which are describes the experiment with the minimum residuals in a wide pressure range.

  9. Bandwidth broadening for stripline circulator

    NASA Astrophysics Data System (ADS)

    Chao, Hsien-Wen; Wu, Shi-Yao; Chang, Tsun-Hsu

    2017-02-01

    This work provides a detailed analysis and simulation to demonstrate how to broaden the operating bandwidth of a circulator. A double-Y junction circulator is designed, and the shape of the central stripline is optimized with the knowledge of a modified equation. The equation predicts two resonant conditions. The overlapping of the two resonant conditions jointly constitutes the broad bandwidth. The bias magnetic field is simulated and then used in full electromagnetic-wave simulation. The designed circulator was fabricated in the S-band for communication purpose. The measured results agree very well with simulation. The overall operation range is from 1643 to 2027 MHz with the insertion loss less than 0.35 dB, reflection, and isolation better than 20 dB. The mechanism will be discussed.

  10. Multigroup Free-atom Doppler-broadening Approximation. Experiment

    SciTech Connect

    Gray, Mark Girard

    2015-11-06

    The multigroup energy Doppler-broadening approximation agrees with continuous energy Dopplerbroadening generally to within ten percent for the total cross sections of 1H, 56Fe, and 235U at 250 lanl. Although this is probably not good enough for broadening from room temperature through the entire temperature range in production use, it is better than any interpolation scheme between temperatures proposed to date, and may be good enough for extrapolation from high temperatures. The method deserves further study since additional improvements are possible.

  11. Air-broadened linewidths of nitrous oxide: An improved calculation

    NASA Astrophysics Data System (ADS)

    Lacome, Nelly; Levy, Armand; Boulet, Christian

    1983-01-01

    The semiclassical theory developed by Robert and Bonamy was used to obtain the linewidths of N 2O broadened by itself, by N 2 and by O 2. The main features of the formalism are as follows: (a) The anisotropic potential is expressed by using, besides the quadrupole-quadrupole contribution, an atom-atom interaction model (without any adjustable parameter) which takes both long- and short-range forces into account. (b) The geometry of the collision is described through the so-called "equivalent" straight path, more appropriate than the usual one. (c) The matrix elements of the relaxation operator are computed by means of the linked-cluster theorem, so that the treatment remains nonperturbative and no resort to cutoff precedures is needed. In addition to being more realistic the present formalism has the advantage of making the computation tractable for complex molecular systems such as linear-linear ones. Careful comparison was made with the available experimental results. For self-broadened N 2O very satisfactory agreement is obtained both at 300 and 204 K. This is also the case for nitrogen broadening at room temperature. Regarding oxygen-broadened linewidths, very few experimental data exist. Anyway, the present results reveal substantial improvement as compared to the usual calculations based upon Anderson-Tsao-Curnutte model. From these results a predictive tabulation was obtained for the values of air-broadened N 2O linewidths at 300 and 204 K.

  12. Saturation effects and inhomogeneous broadening in Doppler-free degenerate four-wave mixing

    NASA Astrophysics Data System (ADS)

    Steel, D. G.; Lam, J. F.

    1981-12-01

    We have performed experiments to study the saturation properties of degenerate four-wave mixing (DFWM) in inhomogeneously broadened material. The experiments were performed on line-center in SF 6 using a CW CO 2 laser on the P16 line at 10.6 μm. Measured peak reflectivities of 1.7 x 10 -4 are in reasonable agreement with a simple two-level model. This model also appears to correctly account for the observed saturation effects. While the material is clearly inhomogeneously broadened, both the experimental and theoretical reflectivity scale as though the material was homogeneously broadened.

  13. [Simultaneous determination of 16 organic acids in feed additives by on-line enrichment and ion chromatography-mass spectrometry].

    PubMed

    Xiong, Zhiyu; Dong, Ying; Zhou, Hongbin; Yu, Yang; Li, Jing; Sun, Li

    2014-02-01

    A novel analytical method for simultaneous determination of sixteen organic acids by on-line enrichment and ion chromatography-mass spectrometry (IC-MS) was developed. Online enrichment and separation of the organic acids were performed by ion chromatography on a homemade enrichment column and a homemade separation column. The qualitative and quantitative analyses of the organic acids were performed by mass spectrometry in selected ion monitoring (SIM) mode on the basis of atmospheric pressure chemical ionization (APCI) source in negative mode. The sample of 200 microL was injected for the analysis, and the on-line enrichment time was 3 min. The sodium hydroxide solution was used as a gradient elution system. The two columns made it possible to have a low limit of detection due to the good enrichment and separation capability. The sixteen organic acids were separated completely within 30 min. All curves showed good linearity within the test concentration ranges. The limits of detection (LODs) were between 0.01 and 0.22 mg/L, and the average recoveries were between 70.6% and 110.8%. The relative standard deviations (RSDs) were less than 6.3%. The results indicate that this method is simple, rapid, sensitive and accurate for the determination of the organic acids in feed additives.

  14. The effect of dispersion on spectral broadening of incoherent continuous-wave light in optical fibers.

    PubMed

    Soh, Daniel B S; Koplow, Jeffrey P; Moore, Sean W; Schroder, Kevin L; Hsu, Wen L

    2010-10-11

    In addition to fiber nonlinearity, fiber dispersion plays a significant role in spectral broadening of incoherent continuous-wave light. In this paper we have performed a numerical analysis of spectral broadening of incoherent light based on a fully stochastic model. Under a wide range of operating conditions, these numerical simulations exhibit striking features such as damped oscillatory spectral broadening (during the initial stages of propagation), and eventual convergence to a stationary, steady state spectral distribution at sufficiently long propagation distances. In this study we analyze the important role of fiber dispersion in such phenomena. We also demonstrate an analytical rate equation expression for spectral broadening.

  15. Analysis of broadened Mössbauer spectra using simple mathematical functions. Analysis of broadened Mössbauer spectra

    NASA Astrophysics Data System (ADS)

    Cabral-Prieto, A.

    2014-01-01

    Simulated and experimental broadened Mössbauer spectra are analyzed using several distribution functions. The resolution Hesse and Rübartsch data are reproduced in order to analyze the origin of the oscillations appearing in the recovered distribution function. The lined triangular distribution is used and some of its properties are described. The no implicit nth-nomial distribution function is introduced, complementing the Window and Hesse and Rübartasch no implicit distribution functions. This new no implicit distribution function gives similar results of those of Window's method. In addition, the Window method has also been modified by inserting a smoothing factor λ C . For 0 < λ C < 1 a hyperfine distribution with low resolution may be obtained; for λ C > 1, the opposite is obtained. The Levenberg-Marquardt algorithm is used to solve the involved Fredholm integral equation rather than the typical second order regularized algorithm. From the extracted hyperfine field distribution functions of the Mössbauer spectra of the amorphous and crystallized Fe70Cr2Si5B16 magnetic alloy the short range atomic order for the amorphous state of this alloy can be inferred.

  16. Stark broadening data for stellar plasma research.

    NASA Astrophysics Data System (ADS)

    Dimitrijević, M. S.

    Results of an effort to provide to astrophysicists and physicists an as much as possible complete set of Stark broadening parameters needed for stellar opacity calculations, stellar atmosphere modelling, abundance determinations and diagnostics of different plasmas in astrophysics, physics and plasma technology, are presented. Stark broadening has been considered within the semiclassical perturbation, and the modified semiempirical approaches.

  17. Correction of Doppler-broadened Rayleigh backscattering effects in H2O dial measurements

    NASA Technical Reports Server (NTRS)

    Ansmann, A.; Bosenberg, J.

    1986-01-01

    A general method of solutions for treating effects of Doppler-broadened Rayleigh backscattering in H2O Differential Absorption Lidar (DIAL) measurements are described and discussed. Errors in vertical DIAL measuremtns caused by this laser line broadening effect can be very large and, therfore, this effect has to be accounted for accurately. To analyze and correct effects of Doppler-broadened Rayleigh backscattering in DIAL experiments, a generalized DIAL approximation was derived starting from a lidar equation, which includes Doppler broadening. To evaluate the accuracy of H2O DIAL measurements, computer simulations were performed. It was concluded that correction of Doppler broadened Rayleigh backscattering is possible with good accuracy in most cases of tropospheric H2O DIAL measurements, but great care has to be taken when layers with steep gradients of Mie backscattering like clouds or inversion layers are present.

  18. Experimental transition probabilities and Stark-broadening parameters of neutral and single ionized tin

    NASA Technical Reports Server (NTRS)

    Miller, M. H.; Roig, R. A.; Bengtson, R. D.

    1979-01-01

    Strengths and Stark-effect widths of the Sn I and Sn II lines prominent between 3200 and 7900 A are measured with a spectroscopic shock tube. Absolute strengths of 17 ionic lines are obtained with estimated (22-50)% accuracy and conform to appropriate quantum-mechanical sum rules. Relative transition probabilities for nine prominent neutral tin lines, normalized to radiative-lifetime data, are compared with other experiments and theoretical predictions. Parameters for Stark-effect broadening are measured over a range of plasma electron densities. Broadening data (with accuracies of 15-35%) for one neutral and ten ionic lines of tin are compared to theoretical predictions.

  19. Observation of Doppler broadening in β -delayed proton- γ decay

    DOE PAGES

    Schwartz, S. B.; Wrede, C.; Bennett, M. B.; ...

    2015-09-14

    Background: The Doppler broadening of gamma-ray peaks is due to nuclear recoil from beta-delayed nucleon emission can be used to measure the energies of the nucleons. This method has never been tested using beta-delayed proton emission or applied to a recoil heavier than A = 10. Purpose: To test and apply this Doppler broadening method using gamma-ray peaks from the P-26(beta p gamma)Al-25 decay sequence. Methods: A fast beam of P-26 was implanted into a planar Ge detector, which was used as a P-26 beta-decay trigger. The SeGA array of high-purity Ge detectors was used to detect gamma rays frommore » the P-26(beta p gamma)Al-25 decay sequence. Results: Radiative Doppler broadening in beta-delayed proton-gamma decay was observed for the first time. Moreover, the Doppler broadening analysis method was verified using the 1613-keV gamma-ray line for which the proton energies were previously known. The 1776-keV gamma ray de-exciting the 2720 keV Al-25 level was observed in P-26(beta p gamma)Al-25 decay for the first time and used to determine that the center-of-mass energy of the proton emission feeding the 2720-keV level is 5.1 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV, corresponding to a Si-26 excitation energy of 13.3 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV for the proton-emitting level. Conclusions: Finally, the Doppler broadening method has been demonstrated to provide practical measurements of the energies for beta-delayed nucleon emissions populating excited states of nuclear recoils at least as heavy as A = 25.« less

  20. Lines

    ERIC Educational Resources Information Center

    Mires, Peter B.

    2006-01-01

    National Geography Standards for the middle school years generally stress the teaching of latitude and longitude. There are many creative ways to explain the great grid that encircles our planet, but the author has found that students in his college-level geography courses especially enjoy human-interest stories associated with lines of latitude…

  1. A Global Fitting Approach For Doppler Broadening Thermometry

    NASA Astrophysics Data System (ADS)

    Amodio, Pasquale; Moretti, Luigi; De Vizia, Maria Domenica; Gianfrani, Livio

    2014-06-01

    Very recently, a spectroscopic determination of the Boltzmann constant, kB, has been performed at the Second University of Naples by means of a rather sophisticated implementation of Doppler Broadening Thermometry (DBT)1. Performed on a 18O-enriched water sample, at a wavelength of 1.39 µm, the experiment has provided a value for kB with a combined uncertainty of 24 parts over 106, which is the best result obtained so far, by using an optical method. In the spectral analysis procedure, the partially correlated speed-dependent hard-collision (pC-SDHC) model was adopted. The uncertainty budget has clearly revealed that the major contributions come from the statistical uncertainty (type A) and from the uncertainty associated to the line-shape model (type B)2. In the present work, we present the first results of a theoretical and numerical work aimed at reducing these uncertainty components. It is well known that molecular line shapes exhibit clear deviations from the time honoured Voigt profile. Even in the case of a well isolated spectral line, under the influence of binary collisions, in the Doppler regime, the shape can be quite complicated by the joint occurrence of velocity-change collisions and speed-dependent effects. The partially correlated speed-dependent Keilson-Storer profile (pC-SDKS) has been recently proposed as a very realistic model, capable of reproducing very accurately the absorption spectra for self-colliding water molecules, in the near infrared3. Unfortunately, the model is so complex that it cannot be implemented into a fitting routine for the analysis of experimental spectra. Therefore, we have developed a MATLAB code to simulate a variety of H218O spectra in thermodynamic conditions identical to the one of our DBT experiment, using the pC-SDKS model. The numerical calculations to determine such a profile have a very large computational cost, resulting from a very sophisticated iterative procedure. Hence, the numerically simulated spectra

  2. Pressure broadening calculations for OH in collisions with argon: Rotational, vibrational, and electronic transitions

    NASA Astrophysics Data System (ADS)

    Dagdigian, Paul J.

    2017-03-01

    Collisional parameters describing both the pressure-induced broadening and shifting of isolated lines in the spectrum of the hydroxyl radical in collisions with argon have been determined through quantum scattering calculations using accurate potential energy surfaces describing the OH(X2 Π , A2Σ+)-Ar interactions. These calculations have been carried for pure rotational, vibrational, and electronic transitions. The calculated pressure broadening coefficients are in good agreement with the available measurements in the microwave, infrared, and ultraviolet spectral regions. Computed pressure broadening coefficients as a function of temperature are reported for these three types of transitions.

  3. Determination of low pressure broadening and shift rates for K, Rb, and Cs collisions with rare gases from Anderson Tallman theory

    NASA Astrophysics Data System (ADS)

    Hager, Gordon D.; Rotondaro, Matthew D.; Perram, Glen P.

    2012-11-01

    A mathematical method is described to compute the pressure dependent spectrum of the D1 and D2 lines of atomic cesium in the presence of argon. The method is based on the Anderson Tallman unified theory of pressure broadening in which the spectrum is determined form the Fourier transform of the auto-correlation function. The method uses modified potential energy surfaces of the ground and excited states that correlate to the 2S1/2 ground state and the 2P1/2 and 2P3/2excited states at large inter-nuclear separation. These surfaces are used to form interaction difference potentials to determine the auto-correlation function. In addition to being able to compute pressure dependent spectra that exhibit symmetry and far wing structure the method also allows us to compute the low pressure shift and broadening rates of the Lorentzian line core.

  4. A theoretical and experimental study of pressure broadening of the oxygen A-band by helium

    SciTech Connect

    Grimminck, Dennis L. A. G.; Spiering, Frans R.; Janssen, Liesbeth M. C.; Avoird, Ad van der; Zande, Wim J. van der; Groenenboom, Gerrit C.

    2014-05-28

    The rotationally resolved magnetic dipole absorption spectrum of the oxygen A-band b{sup 1}Σ{sub g}{sup +}(v=0)←X{sup 3}Σ{sub g}{sup −}(v=0) perturbed by collisions with helium was studied theoretically using the impact approximation. To calculate the relaxation matrix, scattering calculations were performed on a newly computed helium-oxygen (b{sup 1}Σ{sub g}{sup +}) interaction potential as well as on a helium-oxygen (X{sup 3}Σ{sub g}{sup −}) interaction potential from the literature. The calculated integrated line cross sections and broadening coefficients are in good agreement with experimental results from the literature. Additionally, cavity ring-down experiments were performed in the wings of the spectral lines for a quantitative study of line-mixing, i.e., the redistribution of rotational line intensities by helium-oxygen collisions. It is shown that inclusion of line-mixing in the theory is required to reproduce the experimentally determined absolute absorption strengths as a function of the density of the helium gas.

  5. On-line tests of organic additives for the inhibition of the precipitation of silica from hypersaline geothermal brine IV. Final tests of candidate additives

    SciTech Connect

    Harrar, J.E.; Locke, F.E.; Otto, C.H. Jr.; Lorensen, L.E.; Frey, W.P.; Snell, E.O.

    1980-02-01

    The Lawrence Livermore Laboratory Brine Treatment Test System at Niland, Imperial Valley, California, has been used to evaluate a number of cationic polymers and surfactants as scale control agents. An initial group of compounds was narrowed to four on the basis of their activity as silica precipitation inhibitors. Three of these and certain combinations of compounds were then given a 40-h test to determine their effectiveness in retarding scales formed at 220, 125, and 90/sup 0/C. The best single compound was Corcat P-18 (Cordova Chemical Co. polyethylene imine, M.W. approx. = 1800). It had no effect on the scale at 220/sup 0/C, but it reduced the scales at 125 and 90/sup 0/C by factors of 4 and 18, respectively, and it also has activity as a corrosion inhibitor. Other promising compounds are PAE HCl (Dynapol poly(aminoethylene, HCl salt)), which also somewhat reduces the 220/sup 0/C scale; Ethoquad 18/25 (Armak methyl polyoxyethylene(15) octadecylammonium chloride); and Mirapol A-15 (a Miranol Chemical polydiquaternary compound). The best additive formulation for the brines of the Salton Sea Geothermal Field appears to be a mixture of one of these silica precipitation inhibitors with a small amount of hydrochloric acid and a phosphonate crystalline deposit inhibitor. Speculations are presented as to the mechanism of inhibition of silica precipitation and recommendations for further testing of these additives.

  6. CCD observations of additional interstellar lines in stars associated with the Vela Remnant and Eta Carinae nebulosity

    NASA Technical Reports Server (NTRS)

    Wallerstein, George; Gilroy, Kalpana K.

    1992-01-01

    Nine stars from the Vela Remnant and seven stars in the Eta Carinae complex are examined with CCD spectrograms with high signal-to-noise ratios for data regarding the optical interstellar lines. These data are supplemented by observations of objects with known high-velocity components and substantial interstellar Ti II lines. The CCD spectrograms have signal-to-noise ratios of 100-300, a 2-pixel resolving power of 20,000, and cover features of Na I, Ti II, Ca I, CH(+), and CH in the 3200-4400-A range. The Ca I line confirms the high H density in Vela, and the Ti II lines show evidence of shock-induced grain evaporation. Weak shocks are thought to contribute to the CH(+) component, and a high H I density in some clouds is inferred from the CH line. The high H I density is supported by IUE data on Ca I and on the fine-structure carbon lines. The data point to a significant difference in spectroscopic morphology between the two groups of stars, and the need for theoretical support is underscored.

  7. A SYSTEMATIC SURVEY FOR BROADENED CO EMISSION TOWARD GALACTIC SUPERNOVA REMNANTS

    SciTech Connect

    Kilpatrick, Charles D.; Bieging, John H.; Rieke, George H.

    2016-01-01

    We present molecular spectroscopy toward 50 Galactic supernova remnants (SNRs) taken at millimeter wavelengths in {sup 12}CO J = 2 − 1. These observations are part of a systematic survey for broad molecular line (BML) regions indicative of interactions with molecular clouds (MCs). We detected BML regions toward 19 SNRs, including 9 newly identified BML regions associated with SNRs (G08.3–0.0, G09.9–0.8, G11.2–0.3, G12.2+0.3, G18.6–0.2, G23.6+0.3, 4C–04.71, G29.6+0.1, and G32.4+0.1). The remaining 10 SNRs with BML regions confirm previous evidence for MC interaction in most cases (G16.7+0.1, Kes 75, 3C 391, Kes 79, 3C 396, 3C 397, W49B, Cas A, and IC 443), although we confirm that the BML region toward HB 3 is associated with the W3(OH) H ii region, not the SNR. Based on the systemic velocity of each MC, molecular line diagnostics, and cloud morphology, we test whether these detections represent SNR–MC interactions. One of the targets (G54.1+0.3) had previous indications of a BML region, but we did not detect broadened emission toward it. Although broadened {sup 12}CO J = 2 − 1 line emission should be detectable toward virtually all SNR–MC interactions, we find relatively few examples; therefore, the number of interactions is low. This result favors mechanisms other than supernova feedback as the basic trigger for star formation. In addition, we find no significant association between TeV gamma-ray sources and MC interactions, contrary to predictions that SNR–MC interfaces are the primary venues for cosmic ray acceleration.

  8. Potent Vinblastine C20′ Ureas Displaying Additionally Improved Activity Against a Vinblastine-Resistant Cancer Cell Line

    PubMed Central

    2013-01-01

    A series of disubstituted C20′-urea derivatives of vinblastine were prepared from 20′-aminovinblastine that was made accessible through a unique Fe(III)/NaBH4-mediated alkene functionalization reaction of anhydrovinblastine. Three analogues were examined across a panel of 15 human tumor cell lines, displaying remarkably potent cell growth inhibition activity (avg. IC50 = 200–300 pM), being 10–200-fold more potent than vinblastine (avg. IC50 = 6.1 nM). Significantly, the analogues also display further improved activity against the vinblastine-resistant HCT116/VM46 cell line that bears the clinically relevant overexpression of Pgp, exhibiting IC50 values on par with that of vinblastine against the sensitive HCT116 cell line, 100–200-fold greater than the activity of vinblastine against the resistant HCT116/VM46 cell line, and display a reduced 10–20-fold activity differential between the matched sensitive and resistant cell lines (vs 100-fold for vinblastine). PMID:24223237

  9. Fundamental edge broadening effects during focused electron beam induced nanosynthesis

    SciTech Connect

    Schmied, Roland; Fowlkes, Jason Davidson; Winkler, Robert; Rack, Phillip D.; Plank, Harald

    2015-01-01

    In this study, we explore lateral broadening effects of 3D structures fabricated through focused electron beam induced deposition using MeCpPt(IV)Me3 precursor. In particular, the scaling behavior of proximity effects as a function of the primary electron energy and the deposit height is investigated through experiments and validated through simulations. Correlated Kelvin force microscopy and conductive atomic force microscopy measurements identified conductive and non-conductive proximity regions. It was determined that the highest primary electron energies enable the highest edge sharpness while lower energies contain a complex convolution of broadening effects. In addition, it is demonstrated that intermediate energies lead to even more complex proximity effects that significantly reduce lateral edge sharpness and thus should be avoided if desiring high lateral resolution.

  10. Fundamental edge broadening effects during focused electron beam induced nanosynthesis

    DOE PAGES

    Schmied, Roland; Fowlkes, Jason Davidson; Winkler, Robert; ...

    2015-01-01

    In this study, we explore lateral broadening effects of 3D structures fabricated through focused electron beam induced deposition using MeCpPt(IV)Me3 precursor. In particular, the scaling behavior of proximity effects as a function of the primary electron energy and the deposit height is investigated through experiments and validated through simulations. Correlated Kelvin force microscopy and conductive atomic force microscopy measurements identified conductive and non-conductive proximity regions. It was determined that the highest primary electron energies enable the highest edge sharpness while lower energies contain a complex convolution of broadening effects. In addition, it is demonstrated that intermediate energies lead to evenmore » more complex proximity effects that significantly reduce lateral edge sharpness and thus should be avoided if desiring high lateral resolution.« less

  11. Stark broadening corrections to laser-induced fluorescence temperature measurements in a hydrogen arcjet plume.

    PubMed

    Storm, P V; Cappelli, M A

    1996-08-20

    Laser-induced fluorescence of the H(α) transition of atomic hydrogen has previously been performed in the plume of a hydrogen arcjet thruster. Measurements of plasma velocity and temperature, based on the Doppler shift and broadening of the H(α) line shape, were previously published [Appl. Opt. 32, 6117 (1993)]. In that paper the Stark broadening of the H(α) transition was estimated from static-ion calculations performed in the early 1970's and found to be negligible in comparison with the Doppler broadening. However, more recent dynamic-ion calculations have shown the Stark broadening to be considerably larger than was previously assumed, resulting in inaccurate temperature measurements. We present a reanalysis of the fluorescence data, taking into account the improved Stark broadening calculations. The correct atomic hydrogen translation temperature and electron number density are obtained from the Doppler and Stark broadening components of the measured line shape. The results indicate a substantial drop in temperature from those previously reported.

  12. Spectral Broadening of Excitation induced by Ultralong-range Interaction in a Cold Gas of Rydberg Atoms

    SciTech Connect

    Loboda, A. V.; Mischenko, E. V.; Gurnitskaya, E. P.; Glushkov, A. V.; Khetselius, O. Yu.

    2008-10-22

    Preliminary results of calculating the broadening of spectral lines of excited atoms induced by ultralong- range (100 Bohr radii) interactions in a cold gas of Rb atoms within the 'own pressure' approximation and perturbation theory formalism are presented.

  13. Broadening the definition of autoinflammation.

    PubMed

    Masters, Seth L

    2015-07-01

    Initially, the concept of autoinflammation posited that there be no involvement of autoreactive B or T cells, and no evidence of infection. These criteria served well to help establish the concept, and distinguish autoinflammatory diseases from autoimmune or infectious conditions. However, the characterisation of additional monogenic autoinflammatory diseases has established that a primary trigger of the innate immune system may also be accompanied by infection or manifestations of autoimmunity, which may even contribute to pathogenesis. This issue of Seminars in Immunopathology draws out these themes and also shows how autoinflammation can help to maintain homeostasis, which is its primary evolutionary function. Elucidating the fundamental innate immune pathways underlying autoinflammatory disease leads back to these same homeostatic parameters, to inform about how infection is sensed, and providing for new targets against chronic inflammatory disease.

  14. Does interest broaden or narrow attentional scope?

    PubMed

    Sung, Billy; Yih, Jennifer

    2015-08-10

    Theory proposes that interest is a positive emotion that may either broaden attention to facilitate processing of new information, or narrow attention to preserve engagement with new information. To our knowledge, no research has directly examined the effect of interest on attentional scope. Across four experiments, we show that traits associated with the propensity to experience interest-specifically, trait curiosity and internal boredom proneness-are associated with a narrower scope of attention. We also find that, instead of broadening, interest actually narrows attentional scope in comparison to a neutral state and awe. Challenging the conventional notion that all positive emotions broaden cognition and attention, our findings suggest that specific emotions influence attention in ways that extend beyond a general emotional valence effect.

  15. Sound pulse broadening in stressed granular media

    NASA Astrophysics Data System (ADS)

    Langlois, Vincent; Jia, Xiaoping

    2015-02-01

    The pulse broadening and decay of coherent sound waves propagating in disordered granular media are investigated. We find that the pulse width of these compressional waves is broadened when the disorder is increased by mixing the beads made of different materials. To identify the responsible mechanism for the pulse broadening, we also perform the acoustic attenuation measurement by spectral analysis and the numerical simulation of pulsed sound wave propagation along one-dimensional disordered elastic chains. The qualitative agreement between experiment and simulation reveals a dominant mechanism by scattering attenuation at the high-frequency range, which is consistent with theoretical models of sound wave scattering in strongly random media via a correlation length.

  16. Stark broadening experiments on a vacuum arc discharge in tin vapor.

    PubMed

    Kieft, E R; van der Mullen, J J A M; Kroesen, G M W; Banine, V; Koshelev, K N

    2004-12-01

    Pinched discharge plasmas in tin vapor are candidates for application in future semiconductor lithography tools. This paper presents time-resolved measurements of Stark broadened linewidths in a pulsed tin discharge. Stark broadening parameters have been determined for four lines of the Sn III spectrum in the range from 522 to 538 nm, based on a cross-calibration to a Sn II line with a previously known Stark width. The influence of the electron temperature on the Stark widths is discussed. Results for the electron densities in the discharge are presented and compared to Thomson scattering results.

  17. Measurement of self-broadening of the ozone nu(3) transitions

    NASA Technical Reports Server (NTRS)

    Flannery, C.; Klaassen, J. J.; Gojer, M.; Steinfeld, J. I.; Spencer, M.; Chackerian, C., Jr.

    1991-01-01

    Self-broadening coefficients have been measured for a number of rovibrational lines in the nu(3) band of ozone, in the frequency range 1015-1058/cm, with J values between 0 and 27, and over a range of K(a) values. A multiparameter nonlinear least-squares fitting procedure is used to reduce the data, and the sensitivity of the procedure to instrument line width, weak satellite features, and absolute intensity has been examined. The retrieved coefficients are compared with millimeter-wave broadening coefficients, direclty measured rotational relaxation times, and recently suggested empirical representations.

  18. Brillouin resonance broadening due to structural variations in nanoscale waveguides

    NASA Astrophysics Data System (ADS)

    Wolff, C.; Van Laer, R.; Steel, M. J.; Eggleton, B. J.; Poulton, C. G.

    2016-02-01

    We study the impact of structural variations (that is slowly varying geometry aberrations and internal strain fields) on the width and shape of the stimulated Brillouin scattering (SBS) resonance in nanoscale waveguides. We find that they lead to an inhomogeneous resonance broadening through two distinct mechanisms: firstly, the acoustic frequency is directly influenced via mechanical nonlinearities; secondly, the optical wave numbers are influenced via the opto-mechanical nonlinearity leading to an additional acoustic frequency shift via the phase-matching condition. We find that this second mechanism is proportional to the opto-mechanical coupling and, hence, related to the SBS-gain itself. It is absent in intra-mode forward SBS, while it plays a significant role in backward scattering. In backward SBS increasing the opto-acoustic overlap beyond a threshold defined by the fabrication tolerances will therefore no longer yield the expected quadratic increase in overall Stokes amplification. Finally, we illustrate in a numerical example that in backward SBS and inter-mode forward SBS the existence of two broadening mechanisms with opposite sign also opens the possibility to compensate the effect of geometry-induced broadening. Our results can be transferred to other micro- and nano-structured waveguide geometries such as photonic crystal fibres.

  19. Establishment of a series of alien monosomic addition lines of Japanese bunching onion (Allium fistulosum L.) with extra chromosomes from shallot (A. cepa L. aggregatum group).

    PubMed

    Shigyo, M; Tashiro, Y; Isshiki, S; Miyazaki, S

    1996-12-01

    Forty one plants of alien monosomic addition lines of Allium fistulosum L. with extra chromosomes from A. cepa L. Aggregatum group (FF + nA) were produced through the second backcross of amphidiploids between these two species to A. fistulosum. Identification of the extra chromosomes in the 16 plants by elaborate karyotype analyses indicate that a complete series (eight different types) of the alien monosomic addition lines was established in Allium for the first time in this study. Chromosomal locations of malate dehydrogenase (MDH) gene, triosephosphate isomerase (TPI) gene and 5S rDNA of A. cepa Aggregatum group were determined using the series; The gene locus Mdh-1 was located on 4A, Tpi-1 on 3A and a 5S rDNA locus on 7A. Our previous and present studies using the alien monosomic addition lines revealed 11 genetic markers (isozyme and 5S rDNA) assigned to all eight chromosomes of A. cepa Aggregatum group, and these markers reconfirmed the completion of the series. Extra chromosomes of 25 other plants were examined by means of simple analyses of the chromosome markers and karyotypes. Of the total 41 plants, frequencies of the alien monosomic addition lines with extra chromosomes 1A to 8A were as follows: 1A, 5 plants; 2A, 3; 3A, 5; 4A, 9; 5A, 4; 6A, 2; 7A, 11; and 8A, 2.

  20. Correlation of secondary-side IGA/SCC degradation of recirculating steam generator tubing with the on-line addition of boric acid

    SciTech Connect

    Partridge, M.J.; Zemitis, W.S.; Gorman, J.A. )

    1992-08-01

    A survey of field data indicates that the on-line addition of boric acid can reduce the rate of intergranular attack and stress corrosion cracking (IGA/SCC) within the hot leg tube support crevices for some PWR steam generators. However, the beneficial effect was not seen at all surveyed plants. 68 refs., 12 tabs., 12 refs.

  1. Broadening Our View of Linguistic Diversity

    ERIC Educational Resources Information Center

    O'Neal, Debra; Ringler, Marjorie

    2010-01-01

    The definition of English language learners needs to be broadened to include the marginalized dialects of English. Not all native speakers speak Standard English, and even those who do need to learn Academic English to succeed in school. By using strategies developed for ELLs, teachers can help all students become fluent in the language of school.

  2. Unified classical path theories of pressure broadening.

    NASA Technical Reports Server (NTRS)

    Bottcher, C.

    1971-01-01

    Derivation of a unified classical path theory of pressure broadening, using only elementary concepts. It is shown that the theory of Smith, Cooper and Vidal (1969) is only correct at all frequencies to first order in the number density of perturbers.

  3. Pressure broadening of H(2)O absorption lines in the 1.3 microm region measured by continuous wave-cavity ring-down spectroscopy: application in the trace detection of water vapor in N(2), SiH(4), CF(4), and PH(3).

    PubMed

    Fiadzomor, Phyllis A Y; Baker, Derek M; Keen, Anthony M; Grant, Robert B; Orr-Ewing, Andrew J

    2008-12-01

    A continuous wave cavity ring-down (cw-CRD) spectrometer has been developed for the measurement of trace levels of water vapor by absorption spectroscopy at wavelengths in the vicinity of 1358 nm and 1392 nm. The speed of data acquisition and selectivity make cavity ringdown spectroscopy potentially more useful than current techniques for measurement of trace water in process gases and vacuum environments used for semiconductor manufacture where water vapor contamination has a detrimental effect on the final product. The pressure broadening coefficients (gamma) for bath gases N(2), air, and Ar and semiconductor process gases SiH(4), PH(3), and CF(4) were determined for a range of absorption lines in the 2nu(1) and nu(1) + nu(3) bands of H(2)O. For the transitions investigated, the concentration of water vapor in the sample gas varied from 1.7 x 10(12) to 2.9 x 10(15) molecule cm(-3) in N(2) at a total pressure of <10 mbar and was mixed with the bath gas of increasing pressure up to approximately 200 mbar. The values of gamma quantify the reduction in peak absorption cross-sections with bath gas pressure and, thus, their effects on the detection limit of water vapor. For a CRD spectrometer with a ring-down time of tau = 12.0 mus measured with a precision of 0.6%, detection limits for the measurement of water vapor in 1 atm N(2) and of CF(4) were estimated to be 18 and 14 ppbv, respectively. Competing absorption by SiH(4) and PH(3) in the 1.3 mum wavelength region results in respective detection limits for water vapor of 98 and 319 ppbv (relative to 1 atm) in 0.2 atm SiH(4) and 0.37 atm PH(3).

  4. Effects of the addition of casein phosphopeptide-amorphous calcium phosphate (CPP-ACP) on mechanical properties of luting and lining glass ionomer cement

    NASA Astrophysics Data System (ADS)

    Heravi, Farzin; Bagheri, Hossein; Rangrazi, Abdolrasoul; Mojtaba Zebarjad, Seyed

    2016-07-01

    Recently, the addition of casein phosphopeptide-amorphous calcium phosphate (CPP-ACP) into glass ionomer cements (GICs) has attracted interest due to its remineralization of teeth and its antibacterial effects. However, it should be investigated to ensure that the incorporation of CPP-ACP does not have significant adverse effects on its mechanical properties. The purpose of this study was to evaluate the effects of the addition of CPP-ACP on the mechanical properties of luting and lining GIC. The first step was to synthesize the CPP-ACP. Then the CPP-ACP at concentrations of 1%, 1.56% and 2% of CPP-ACP was added into a luting and lining GIC. GIC without CPP-ACP was used as a control group. The results revealed that the incorporation of CPP-ACP up to 1.56%(w/w) increased the flexural strength (29%), diametral tensile strength (36%) and microhardness (18%), followed by a reduction in these mechanical properties at 2%(w/w) CPP-ACP. The wear rate was significantly decreased (23%) in 1.56%(w/w) concentration of CPP-ACP and it was increased in 2%(w/w). Accordingly, the addition of 1.56%(w/w) CPP-ACP into luting and lining GIC had no adverse effect on the mechanical properties of luting and lining GIC and could be used in clinical practice.

  5. The effectiveness of the McKenzie method in addition to first-line care for acute low back pain: a randomized controlled trial

    PubMed Central

    2010-01-01

    Background Low back pain is a highly prevalent and disabling condition worldwide. Clinical guidelines for the management of patients with acute low back pain recommend first-line treatment consisting of advice, reassurance and simple analgesics. Exercise is also commonly prescribed to these patients. The primary aim of this study was to evaluate the short-term effect of adding the McKenzie method to the first-line care of patients with acute low back pain. Methods A multi-centre randomized controlled trial with a 3-month follow-up was conducted between September 2005 and June 2008. Patients seeking care for acute non-specific low back pain from primary care medical practices were screened. Eligible participants were assigned to receive a treatment programme based on the McKenzie method and first-line care (advice, reassurance and time-contingent acetaminophen) or first-line care alone, for 3 weeks. Primary outcome measures included pain (0-10 Numeric Rating Scale) over the first seven days, pain at 1 week, pain at 3 weeks and global perceived effect (-5 to 5 scale) at 3 weeks. Treatment effects were estimated using linear mixed models. Results One hundred and forty-eight participants were randomized into study groups, of whom 138 (93%) completed the last follow-up. The addition of the McKenzie method to first-line care produced statistically significant but small reductions in pain when compared to first-line care alone: mean of -0.4 points (95% confidence interval, -0.8 to -0.1) at 1 week, -0.7 points (95% confidence interval, -1.2 to -0.1) at 3 weeks, and -0.3 points (95% confidence interval, -0.5 to -0.0) over the first 7 days. Patients receiving the McKenzie method did not show additional effects on global perceived effect, disability, function or on the risk of persistent symptoms. These patients sought less additional health care than those receiving only first-line care (P = 0.002). Conclusions When added to the currently recommended first-line care of acute

  6. Nitrogen-broadened lineshapes in the oxygen A-band: Experimental results and theoretical calculations

    NASA Astrophysics Data System (ADS)

    Predoi-Cross, Adriana; Holladay, Christopher; Heung, Henry; Bouanich, Jean-Pierre; Mellau, Georg Ch.; Keller, Reimund; Hurtmans, Daniel R.

    2008-09-01

    We report measurements for N 2-broadening, pressure-shift and line mixing coefficients for 55 oxygen transitions in the A-band retrieved using a multispectrum fitting technique. Nineteen laboratory absorption spectra were recorded at 0.02 cm -1 resolution using a multi-pass absorption cell with path length of 1636.9 cm and the IFS 120 Fourier transform spectrometer located at Justus-Liebig-University in Giessen, Germany. The total sample pressures ranged from 8.8 to 3004.5 Torr with oxygen volume mixing ratios in nitrogen ranging between 0.057 and 0.62. An Exponential Power Gap (EPG) scaling law was used to calculate the N 2-broadening and N 2-line mixing coefficients. The line broadening and shift coefficients for the A-band of oxygen self-perturbed and perturbed by N 2 are modeled using semiclassical calculations based on the Robert-Bonamy formalism and two intermolecular potentials. These potentials involve electrostatic contributions including the hexadecapole moment of the molecules and (a) a simple dispersion contribution with one adjustable parameter to fit the broadening coefficients or (b) the atom-atom Lennard-Jones model without such adjustable parameters. The first potential leads to very weak broadening coefficients for high J transitions whereas the second potential gives much more improved results at medium and large J values, in reasonable agreement with the experimental data. For the line shifts which mainly arise in our calculation from the electronic state dependence of the isotropic potential, their general trends with increasing J values can be well predicted, especially from the first potential. From the theoretical results, we have derived air-broadening and air-induced shift coefficients with an agreement comparable to that obtained for O 2-O 2 and O 2-N 2.

  7. Spectral broadening and compression of high-intensity laser pulses in quasi-periodic systems with Kerr nonlinearity

    SciTech Connect

    Vlasov, Sergei N; Koposova, E V; Yashin, V E

    2012-11-30

    We report the results of theoretical studies and numerical simulations of optical high-power pulse compression systems based on the spectral broadening in a Kerr nonlinear medium with subsequent pulse compression in a dispersive delay line. It is shown that the effective spectral broadening requires suppressing a smallscale instability arising due to self-focusing, which is possible in quasi-periodic systems consisting of a nonlinear medium and optical relay telescopes transmitting images of the laser beam through the system. The numerical calculations have shown the possibility of broadening the spectrum, followed by 15-fold pulse compression until the instability is excited. (control of laser radiation parameters)

  8. Origin of asymmetric broadening of Raman peak profiles in Si nanocrystals

    PubMed Central

    Gao, Yukun; Yin, Penggang

    2017-01-01

    The asymmetric peak broadening towards the low-frequency side of the Raman-active mode of Si nanocrystals with the decreasing size has been extensively reported in the literatures. In this study, an atomic coordination model is developed to study the origin of the ubiquitous asymmetric peak on the optical phonon fundamental in the Raman spectra of Si nanocrystals. Our calculation results accurately replicate the line shape of the experimentally measured optical Raman curves. More importantly, it is revealed that the observed asymmetric broadening is mainly caused by the surface bond contraction and the quantum confinement. PMID:28240325

  9. Identification of a sugar beet BvM14-MADS box gene through differential gene expression analysis of monosomic addition line M14.

    PubMed

    Ma, Chunquan; Wang, Yuguang; Wang, Yuting; Wang, Lifa; Chen, Sixue; Li, Haiying

    2011-11-01

    Monosomic addition line M14 carrying an additional chromosome 9 from Beta corolliflora Zosimovic ex Buttler was obtained through hybridization between the wild species B. corolliflora and a cultivated species Beta vulgaris L. var Saccharifera Alef. The M14 line showed diplosporic reproduction and stress tolerance. To identify differentially expressed genes in M14, a subtractive cDNA library was prepared by suppression subtractive hybridization (SSH) between M14 (2n=18+1) and B. vulgaris (2n=18). A total of 190 unique sequences were identified in the library and their putative functions were analyzed using Gene Ontology (GO). One of the genes, designated as BvM14-MADS box, encodes a MADS box transcription factor. It was cloned from M14 and over-expressed in transgenic tobacco plants. Interestingly, this gene was located on chromosome 2 of B. vulgaris, not on the additional chromosome 9. Overexpression of BvM14-MADS box led to significant phenotypic changes in tobacco. The differential expression of BvM14-MADS box gene in M14 may be caused by the interaction between the additional chromosome 9 from B. corolliflora and the B. vulgaris chromosomes in M14.

  10. Diode laser spectra of CCl2F2 near 10.8 muon M: Air-broadening effects

    NASA Technical Reports Server (NTRS)

    Jennings, D. E.

    1977-01-01

    Laboratory spectra of CCL2F2 in the 10.8 micron region was recorded, using a tuneable diode laser spectrometer. Effects of air-broadening at pressures up to 48 Torr show that spectral structure should be exhibited under high resolution at altitudes as low as 19 Km. The single line, pressure-broadening coefficient for CCL2F2 was estimated to be 8 MHz/Torr FWHM.

  11. Additive effects of two quantitative trait loci that confer Rhopalosiphum maidis (corn leaf aphid) resistance in maize inbred line Mo17

    PubMed Central

    Betsiashvili, Mariam; Ahern, Kevin R.; Jander, Georg

    2015-01-01

    Plants show considerable within-species variation in their resistance to insect herbivores. In the case of Zea mays (cultivated maize), Rhopalosiphum maidis (corn leaf aphids) produce approximately twenty times more progeny on inbred line B73 than on inbred line Mo17. Genetic mapping of this difference in maize aphid resistance identified quantitative trait loci (QTL) on chromosomes 4 and 6, with the Mo17 allele reducing aphid reproduction in each case. The chromosome 4 QTL mapping interval includes several genes involved in the biosynthesis of DIMBOA (2,4-dihydroxy-7-methoxy-1,4-benzoxazin-3-one), a maize defensive metabolite that also is required for callose accumulation in response to aphid feeding. Consistent with the known association of callose with plant defence against aphids, R. maidis reproduction on B73×Mo17 recombinant inbred lines was negatively correlated with both DIMBOA content and callose formation. Further genetic mapping, as well as experiments with near-isogenic lines, confirmed that the Mo17 allele causes increased DIMBOA accumulation relative to the B73 allele. The chromosome 6 aphid resistance QTL functions independently of DIMBOA accumulation and has an effect that is additive to that of the chromosome 4 QTL. Thus, at least two separate defence mechanisms account for the higher level of R. maidis resistance in Mo17 compared with B73. PMID:25249072

  12. Proton disorder in ice Ih and inhomogeneous broadening in two-dimensional infrared spectroscopy.

    PubMed

    Shi, L; Skinner, J L

    2013-12-12

    It is well-known that in ice Ih the oxygen atoms form a regular hexagonal lattice while the positions of the hydrogen atoms are disordered, called proton disorder in the literature. Various OH (OD) stretch vibrational spectroscopies (e.g., IR, Raman, two-dimensional IR (2DIR), and hole burning) have been used to probe this proton disorder in the past several decades. However, the presence and the magnitude of the inhomogeneous broadening due to this proton disorder in the vibrational spectroscopy is still controversial. In this work, we calculate 2DIR spectroscopy for HOD in D2O ice Ih at 80 K with a mixed quantum/classical approach, and make comparison to a recent 2DIR experiment on the same system. Fair agreement is achieved between theory and experiment, although the calculated 2DIR line shape shows inhomogeneous broadening that was not observed in the experiment. However, the theory reproduces the linear IR for the same system fairly well, and the inhomogeneous broadening from the calculation is consistent with the extrapolation of the experimental IR line-widths in the literature. The effect of this proton disorder on the 2DIR line shape is explored in detail. We also calculate the vibrational three-pulse photon echo peak shift signal, which shows signatures of both low-frequency dynamics and inhomogeneous broadening.

  13. Simultaneous determination of some food additives in soft drinks and other liquid foods by flow injection on-line dialysis coupled to high performance liquid chromatography.

    PubMed

    Kritsunankul, Orawan; Jakmunee, Jaroon

    2011-06-15

    Flow injection on-line dialysis was developed for sample pretreatment prior to the simultaneous determination of some food additives by high performance liquid chromatography (FID-HPLC). A liquid sample or mixed standard solution (900 μL) was injected into a donor stream (5%, w/v, sucrose) of FID system and was pushed further through a dialysis cell, while an acceptor solution (0.025 mol L(-1) phosphate buffer, pH 3.75) was held in the opposite side of the dialysis membrane. The dialysate was then flowed to an injection loop of the HPLC valve, where it was further injected into the HPLC system and analyzed under isocratic reverse-phase HPLC conditions and UV detection (230 nm). The order of elution of five food additives was acesulfame-K, saccharin, caffeine, benzoic acid and sorbic acid, respectively, with the analysis time of 14 min. On-line dialysis and HPLC analysis could be performed in parallel, providing sample throughput of 4.3h(-1). Dialysis efficiencies of five food additives were in ranges of 5-11%. Linear calibration graphs were in ranges of 10-100 mg L(-1) for acesulfame-K and saccharin, 10-250 mg L(-1) for benzoic acid and 10-500 mg L(-1) for caffeine and sorbic acid. Good precisions (RSD<5%) for all the additives were obtained. The proposed system was applied to soft drink and other liquid food samples. Acceptable percentage recoveries could be obtained by appropriate dilution of the sample before injecting into the system. The developed system has advantages of high degrees of automation for sample pretreatment, i.e., on-line sample separation and dilution and low consumption of chemicals and materials.

  14. Influence of resonant collisions on the self-broadening of acetylene

    NASA Astrophysics Data System (ADS)

    Lehmann, Kevin K.

    2017-03-01

    Iwakuni et al. [Phys. Rev. Lett. 117, 143902 (2016)] have reported an ortho-para alternation of ˜10% in the self pressure broadening coefficients for ro-vibrational lines of the C2H2 transitions in the ν1+ν3 C-H (local mode) overtone band near 197 THz (1.52 μm). These authors attributed this effect to the contribution of resonant collisions, where the rotational energy change of one molecule is exactly compensated by the rotational energy change of its collision partner. Resonant collisions are known to be important in the case of self pressure broadening of highly polar molecules, such as HCN, but have not previously been invoked in the case of nonpolar molecules, such as acetylene, where the long range potential is dominated by the quadrupole-quadrupole electrostatic interaction. In the present work, the simple semiclassical Anderson-theory approach is used to estimate the rates of C2H2-C2H2 rotationally inelastic collisions and these used to predict pressure broadening rates, ignoring other contributions to the broadening, which should not have resonant enhancements. It is found that exactly resonant collisions do not make a major contribution to the broadening and these calculations predict an ortho-para alternation of the pressure broadening coefficients far below what was inferred by Iwakuni et al. The present results are consistent with a large body of published work that reported self-broadening coefficients of C2H2 ro-vibrational transitions that found negligible dependence on the vibrational transition and no even-odd alternation, even for Q and S branch transitions where any such effect is predicted to be much larger than for the P and R branch transitions studied by Iwakuni et al.

  15. Spectral broadening in lithium niobate in a self-diffraction geometry using ultrashort pulses

    NASA Astrophysics Data System (ADS)

    Dharmadhikari, Jayashree A.; Dota, Krithika; Mathur, Deepak; Dharmadhikari, Aditya K.

    2016-05-01

    We report on broadband light generation in the impulsive regime in an un-doped lithium niobate (LiNbO3) crystal by two femtosecond laser pulses (36 fs) from a Ti-sapphire laser amplifier. We systematically investigate the role of incident intensity on spectral broadening. At relatively low incident intensity (0.7 TW cm-2), spectral broadening in the transmitted beam occurs due to the combined effect of self-phase modulation and cross-phase modulation. At higher incident intensity (10.2 TW cm-2), we observe generation of as many as 21 anti-Stokes orders due to coherent anti-Stokes Raman scattering in self-diffraction geometry. Moreover, we observe order-dependent spectral broadening of anti-Stokes lines that may be attributed to the competition with other nonlinear optical effects like cross-phase modulation.

  16. Oxidative and inert pyrolysis on-line coupled to gas chromatography with mass spectrometric detection: On the pyrolysis products of tobacco additives.

    PubMed

    Paschke, Meike; Hutzler, Christoph; Henkler, Frank; Luch, Andreas

    2016-11-01

    According to European legislation, tobacco additives may not increase the toxicity or the addictive potency of the product, but there is an ongoing debate on how to reliably characterize and measure such properties. Further, too little is known on pyrolysis patterns of tobacco additives to assume that no additional toxicological risks need to be suspected. An on-line pyrolysis technique was used and coupled to gas chromatography-mass spectrometry (GC/MS) to identify the pattern of chemical species formed upon thermal decomposition of 19 different tobacco additives like raw cane sugar, licorice or cocoa. To simulate the combustion of a cigarette it was necessary to perform pyrolysis at inert conditions as well as under oxygen supply. All individual additives were pyrolyzed under inert or oxidative conditions at 350, 700 and 1000°C, respectively, and the formation of different toxicants was monitored. We observed the generation of vinyl acrylate, fumaronitrile, methacrylic anhydride, isobutyric anhydride and 3-buten-2-ol exclusively during pyrolysis of tobacco additives. According to the literature, these toxicants so far remained undetectable in tobacco or tobacco smoke. Further, the formation of 20 selected polycyclic aromatic hydrocarbons (PAHs) with molecular weights of up to 278Da was monitored during pyrolysis of cocoa in a semi-quantitative approach. It was shown that the adding of cocoa to tobacco had no influence on the relative amounts of the PAHs formed.

  17. Action potential broadening in a presynaptic channelopathy

    PubMed Central

    Begum, Rahima; Bakiri, Yamina; Volynski, Kirill E.; Kullmann, Dimitri M.

    2016-01-01

    Brain development and interictal function are unaffected in many paroxysmal neurological channelopathies, possibly explained by homoeostatic plasticity of synaptic transmission. Episodic ataxia type 1 is caused by missense mutations of the potassium channel Kv1.1, which is abundantly expressed in the terminals of cerebellar basket cells. Presynaptic action potentials of small inhibitory terminals have not been characterized, and it is not known whether developmental plasticity compensates for the effects of Kv1.1 dysfunction. Here we use visually targeted patch-clamp recordings from basket cell terminals of mice harbouring an ataxia-associated mutation and their wild-type littermates. Presynaptic spikes are followed by a pronounced afterdepolarization, and are broadened by pharmacological blockade of Kv1.1 or by a dominant ataxia-associated mutation. Somatic recordings fail to detect such changes. Spike broadening leads to increased Ca2+ influx and GABA release, and decreased spontaneous Purkinje cell firing. We find no evidence for developmental compensation for inherited Kv1.1 dysfunction. PMID:27381274

  18. Action potential broadening in a presynaptic channelopathy

    NASA Astrophysics Data System (ADS)

    Begum, Rahima; Bakiri, Yamina; Volynski, Kirill E.; Kullmann, Dimitri M.

    2016-07-01

    Brain development and interictal function are unaffected in many paroxysmal neurological channelopathies, possibly explained by homoeostatic plasticity of synaptic transmission. Episodic ataxia type 1 is caused by missense mutations of the potassium channel Kv1.1, which is abundantly expressed in the terminals of cerebellar basket cells. Presynaptic action potentials of small inhibitory terminals have not been characterized, and it is not known whether developmental plasticity compensates for the effects of Kv1.1 dysfunction. Here we use visually targeted patch-clamp recordings from basket cell terminals of mice harbouring an ataxia-associated mutation and their wild-type littermates. Presynaptic spikes are followed by a pronounced afterdepolarization, and are broadened by pharmacological blockade of Kv1.1 or by a dominant ataxia-associated mutation. Somatic recordings fail to detect such changes. Spike broadening leads to increased Ca2+ influx and GABA release, and decreased spontaneous Purkinje cell firing. We find no evidence for developmental compensation for inherited Kv1.1 dysfunction.

  19. Commitment to Broadening Participation at NOAO

    NASA Astrophysics Data System (ADS)

    Garmany, Catharine D.; Norman, D.

    2011-01-01

    AURA and NOAO take seriously the importance of Broadening Participation in Astronomy. At the request of the AURA President, each of the AURA centers (NOAO, NSO, STSCI, Gemini) appointed a Diversity Advocates (DA). At NOAO this job is shared by Dara Norman and Katy Garmany, who were appointed by Dave Silva in Jan 2009. The DA's are members of the AURA Committee on Workforce and Diversity (WDC), a designated subcommittee of the AURA Board of Directors. The role of this committee includes reviewing activities and plans on an AURA wide basis aimed at broadening the participation within AURA, and reviewing AURA wide policies on the workforce. At NOAO, the role of the DAs spans a number of departments and activities. They serve on observatory search committees, and offer suggestions on how NOAO job searches can reach the most diverse audience. The DA's job is to insure that NOAO actively pursues every opportunity to increase diversity: to this end they are involved in outreach and educational activities that focus on workplace development and encourage inclusion of woman, minorities and persons with disabilities.

  20. Action potential broadening in a presynaptic channelopathy.

    PubMed

    Begum, Rahima; Bakiri, Yamina; Volynski, Kirill E; Kullmann, Dimitri M

    2016-07-06

    Brain development and interictal function are unaffected in many paroxysmal neurological channelopathies, possibly explained by homoeostatic plasticity of synaptic transmission. Episodic ataxia type 1 is caused by missense mutations of the potassium channel Kv1.1, which is abundantly expressed in the terminals of cerebellar basket cells. Presynaptic action potentials of small inhibitory terminals have not been characterized, and it is not known whether developmental plasticity compensates for the effects of Kv1.1 dysfunction. Here we use visually targeted patch-clamp recordings from basket cell terminals of mice harbouring an ataxia-associated mutation and their wild-type littermates. Presynaptic spikes are followed by a pronounced afterdepolarization, and are broadened by pharmacological blockade of Kv1.1 or by a dominant ataxia-associated mutation. Somatic recordings fail to detect such changes. Spike broadening leads to increased Ca(2+) influx and GABA release, and decreased spontaneous Purkinje cell firing. We find no evidence for developmental compensation for inherited Kv1.1 dysfunction.

  1. VAMDC FP7 project and STARK-B database: C II Stark broadening parameters for white dwarf atmospheres research

    NASA Astrophysics Data System (ADS)

    Larbi-Terzi, Neila; Sahal-Bréchot, Sylvie; Ben Nessib, Nebil; Dimitrijević, Milan S.

    2010-11-01

    Stark broadening parameters of C II lines were determined within 3s-np spectral series within the semiclassical perturbation method. The atomic energy levels needed for calculations were taken from TOPBASE as well as the oscillator strengths, calculated additionally using the Coulomb approximation (the method of Bates and Damgaard). The both results were compared and the disagreement is found only in one case where the configuration mixing allows a forbidden transition to a close perturbing energy level. Calculations were performed for plasma conditions relevant for atmospheres of DQ white dwarfs and for a new type of white dwarfs, with surface composed mostly of carbon, discovered in 2007 by Dufour et al.. The aim of this work is to provide accurate C II Stark broadening data, which are crucial for this type of white dwarf atmosphere modellisation. Obtained results will be included in STARK-B database (http://stark-b.obspm.fr/), entering in the FP7 project of European Virtual Atomic and Molecular Data Center VAMDC aiming at building an interoperable e-Infrastructure for the exchange of atomic and molecular data (http://www.vamdc.org/).

  2. VAMDC FP7 project and STARK-B database: C II Stark broadening parameters for white dwarf atmospheres research

    SciTech Connect

    Larbi-Terzi, Neila; Ben Nessib, Nebil; Sahal-Brechot, Sylvie; Dimitrijevic, Milan S.

    2010-11-23

    Stark broadening parameters of C II lines were determined within 3s-np spectral series within the semiclassical perturbation method. The atomic energy levels needed for calculations were taken from TOPBASE as well as the oscillator strengths, calculated additionally using the Coulomb approximation (the method of Bates and Damgaard). The both results were compared and the disagreement is found only in one case where the configuration mixing allows a forbidden transition to a close perturbing energy level. Calculations were performed for plasma conditions relevant for atmospheres of DQ white dwarfs and for a new type of white dwarfs, with surface composed mostly of carbon, discovered in 2007 by Dufour et al.. The aim of this work is to provide accurate C II Stark broadening data, which are crucial for this type of white dwarf atmosphere modellisation. Obtained results will be included in STARK-B database (http://stark-b.obspm.fr/), entering in the FP7 project of European Virtual Atomic and Molecular Data Center VAMDC aiming at building an interoperable e-Infrastructure for the exchange of atomic and molecular data (http://www.vamdc.org/).

  3. Asymmetry in the triplet 3p-4s Mg lines in cool DZ white dwarfs

    NASA Astrophysics Data System (ADS)

    Allard, N. F.; Leininger, T.; Gadéa, F. X.; Brousseau-Couture, V.; Dufour, P.

    2016-04-01

    The purpose of the present work is to make an exhaustive study of the line shape of the triplet 3p-4s Mg line (Mgb triplet), which is perturbed by He in the extreme physical conditions found in the cool atmosphere of DZ white dwarfs. This study is undertaken by inferring both a unified theory of spectral line broadening and ab initio potential energies. Cool white dwarfs require a specific treatment for line broadening owing to the high helium densities that are involved. Beyond the conventional symmetrical Lorentzian core at low density, we show that the line profiles are asymmetrical and have significant additional contributions on the short wavelength side. This blue asymmetry is a consequence of low maxima in the corresponding Mg-He potential energy difference curves at short and intermediate internuclear distances. The new profiles are shown to provide a good fit to an SDSS (Sloan Digital Sky Survey) observation.

  4. Cis-transcriptional variation in maize inbred lines B73 and Mo17 leads to additive expression patterns in the F1 hybrid.

    PubMed

    Stupar, Robert M; Springer, Nathan M

    2006-08-01

    Microarray analysis of gene expression patterns in immature ear, seedling, and embryo tissues from the maize inbred lines B73 and Mo17 identified numerous genes with variable expression. Some genes had detectable expression in only one of the two inbreds; most of these genes were detected in the genomic DNA of both inbreds, indicating that the expression differences are likely caused by differential regulation rather than by differences in gene content. Gene expression was also monitored in the reciprocal F1 hybrids B73xMo17 and Mo17xB73. The reciprocal F1 hybrid lines did not display parental effects on gene expression levels. Approximately 80% of the differentially expressed genes displayed additive expression patterns in the hybrids relative to the inbred parents. The approximately 20% of genes that display nonadditive expression patterns tend to be expressed at levels within the parental range, with minimal evidence for novel expression levels greater than the high parent or less than the low parent. Analysis of allele-specific expression patterns in the hybrid suggested that intraspecific variation in gene expression levels is largely attributable to cis-regulatory variation in maize. Collectively, our data suggest that allelic cis-regulatory variation between B73 and Mo17 dictates maintenance of inbred allelic expression levels in the F1 hybrid, resulting in additive expression patterns.

  5. High Temporal and Spatial Resolution Electron Density Diagnostic for the Edge Plasma based on Stark Broadening

    NASA Astrophysics Data System (ADS)

    Zafar, Abdullah; Martin, Elijah; Shannon, Steve; Isler, Ralph; Caughman, John

    2016-10-01

    Passive spectroscopic measurements of Stark broadening have been reliably used to determine electron density for decades. However, a low-density limit ( 1014 cm-3) exists due to Doppler and instrument broadening of the spectral line profile. A synthetic electron density diagnostic capable of high temporal (ms) and spatial (mm) resolution is currently under development at Oak Ridge National Laboratory. The diagnostic is based on measuring the Stark broadened, Doppler-free, spectral line profile of a Balmar series transition by using an active laser based technique. The diagnostic approach outlined here greatly reduces both of these broadening contributions using Doppler-free saturation spectroscopy (DFSS), allowing access to lower density regimes. The measured profile is then fit to a fully quantum mechanical model including the appropriate electric and magnetic field operators. The modeling and experimental results for this active spectroscopic technique are presented for a magnetized (<=5 T), low-density (1011-1013 cm-3) plasma. Details of applying DFSS to the plasma edge are also discussed.

  6. Calculation of quasi-static helium triplet diffuse line profiles

    NASA Technical Reports Server (NTRS)

    Scott, C. D.

    1972-01-01

    Calculated spectral line profiles (intensity distributions) of the helium triplet diffuse series were obtained using the quasi-static approximation for ions and electrons. In these calculations, Doppler broadening, although negligible in most of the cases, was included as a device to avoid singularities. Plots and tabulations of the calculated profiles are presented, in addition to a discussion of the computational procedure and the validity of the calculations.

  7. Case studies on recent Stark broadening calculations and STARK-B database development in the framework of the European project VAMDC (Virtual Atomic and Molecular Data Center)

    NASA Astrophysics Data System (ADS)

    Sahal-Bréchot, S.

    2010-11-01

    Stark broadening theories and calculations have been extensively developed for about 50 years. The theory can now be considered as mature for many applications, especially for accurate spectroscopic diagnostics and modelling. In astrophysics, with the increasing sensitivity of observations and spectral resolution, in all domains of wavelengths from far UV to infrared, it has become possible to develop realistic models of interiors and atmospheres of stars and interpret their evolution and the creation of elements through nuclear reactions. For hot stars, especially white dwarfs, Stark broadening is the dominant collisional line broadening process. This requires the knowledge of numerous profiles, especially for trace elements, which are used as useful probes for modern spectroscopic diagnostics. Hence, calculations based on a simple but enough accurate and fast method, are necessary for obtaining numerous results. Ab initio calculations are a growing domain of development. Nowadays, the access to such data via an on line database becomes crucial. This is the object of STARK-B, which is a collaborative project between the Paris Observatory and the Astronomical Observatory of Belgrade. It is a database of calculated widths and shifts of isolated lines of atoms and ions due to electron and ion collisions. It is devoted to modelling and spectroscopic diagnostics of stellar atmospheres and envelopes. In addition, it is relevant to laboratory plasmas, laser equipments and technological plasmas. It is a part of VAMDC (Virtual Atomic and Molecular Data Centre), which is an European Union funded collaboration between groups involved in the generation and use of atomic and molecular data.

  8. Photoinduced broadening of cholesteric liquid crystal reflectors

    NASA Astrophysics Data System (ADS)

    White, Timothy J.; Freer, Alexander S.; Tabiryan, Nelson V.; Bunning, Timothy J.

    2010-04-01

    The selective reflection of cholesteric liquid crystals (CLCs) is well-known and has been utilized in a number of dynamic optical applications. This work presents a novel approach to passively (e.g., all-optically) cue reflection notch broadening in photoresponsive CLC formulations based on high helical twisting power (HTP) bis(azo) chiral dopants. The original reflection bandwidth of approximately 100 nm is increased to as much as 1700 nm, by exposing 36 μm thick cells to UV light. The maximum attainable bandwidth is shown to be a function of cell thickness, light intensity, and strongly related to the HTP of the photoresponsive chiral dopants. An all-optical technique of simultaneous UV and green light exposure is demonstrated to trap the reflection notch at a predetermined position and bandwidth.

  9. Broadening Participation in the Coastal Environmental Sciences

    NASA Astrophysics Data System (ADS)

    Christian, A.; Hannigan, R.

    2011-12-01

    Embracing diversity of discipline and perspective is central to broadening participation in the ocean sciences. Research focused on coastal environmental issues seen through the lenses of indigenous knowledge, industry, and public-private partnership perspectives engages younger non-ocean science students from minority serving institutions in unique ways. Demonstrating multiple entry points to students interested in a career in the sciences and engaging them in research across spatial and temporal scales is vitally important to the creation of a learning cohort that will sustain these students past their often short summer research experience. By combining recruitment partnerships with select minority serving institutions, engaging younger students in research, and creating a diverse set of cohort building activities ensures that as we embrace the diversity of coastal environmental disciplines we also embrace the diversity of perspectives that these students bring to our research.

  10. Alien genes introgression and development of alien monosomic addition lines from a threatened species, Allium roylei Stearn, to Allium cepa L.

    PubMed

    Vu, Hoa Q; Yoshimatsu, Yasuyuki; Khrustaleva, Ludmila I; Yamauchi, Naoki; Shigyo, Masayoshi

    2012-05-01

    To produce alien monosomic addition lines (AMALs) of Allium cepa (genomes CC, 2n = 2x = 16) carrying extrachromosomes from Allium roylei (RR, 2n = 2x = 16), reciprocal backcrossing of allotriploids (2n = 24, CCR) with diploids (2n = 16, CC) and selfing of a single allotriploid were carried out. The chromosome numbers in the BC(2)F(1) and BC(1)F(2) progenies ranged from 16 to 32. Forty-eight plants were recorded to possess 2n = 17 among a total of 169 plants in observation. Through the analyses of isozymes, expressed sequence tag (EST) markers, and karyotypes, all eight possible types of A. cepa-A. roylei monosomic addition lines (CC+1R-CC+8R) could be identified. Seven types of representative AMALs (without CC+2R) were used for the GISH analysis of somatic chromosomes. Except for CC+6R, all AMALs showed an entire (unrecombined) extrachromosome from A. roylei in the integral diploid background of A. cepa. A single recombination between A. cepa and A. roylei was observed on the extrachromosome in the remaining type. All alloplasmic AMALs possessing A. roylei cytoplasm showed high or complete pollen sterility. Only the autoplasmic CC+4R with A. cepa cytoplasm possessed relatively high pollen fertility. The bulbs of CC+4R displayed the distinct ovoid shape that discriminates them from spherical or oval ones in other AMALs. Downy mildew screening in the field showed higher resistance in A. roylei, a hypo-allotriploid (CCR-nR, 2n = 23), and an allotriploid (CCR, 2n = 24). Meanwhile, no complete resistance was found in some AMALs examined. This was the first trial toward the establishment of a complete set of A. cepa-A. roylei monosomic additions.

  11. Analysis of pressure-broadened ozone spectra in the 3 micron region

    NASA Technical Reports Server (NTRS)

    Prochaska, Eleanor S.

    1991-01-01

    This work involves the analysis of a series of McMath Fourier Transform Infrared (FTIR) spectra of ozone broadened by mixing with air (four different pressures), nitrogen (three pressures), or oxygen (three pressures). Each spectrum covers the region from 2396 to 4057 cm(-1). This study focused on the 3 sub nu sub 3 band in t 3000 to 3060 cm(-1). The band is analyzed by first dividing its region into small intervals containing a few well isolated absorption lines of reasonable intensity. Each of these small intervals is fit by multiple iterations of the nonlinear least squares program until residuals (the difference between calculated and observed spectrum, as a percent of the strongest intensity in the interval) are minimized to a reasonable value which corresponds to the noise level of the measured spectrum. Position, intensity, and half-width are recorded for later analysis. From the measured half-widths, a pressure broadening coefficient was determined for each absorption line. Pressure shifts were determined by comparing observed line positions in the spectra of the diluted ozone samples to tabulated line positions determined from spectra of pure gas samples. Comparisons to other work on ozone indicate that the broadening and shift coefficients determined in this study are consistent with those determined in other spectral regions.

  12. Portable Hyperspectral Imaging Broadens Sensing Horizons

    NASA Technical Reports Server (NTRS)

    2007-01-01

    Broadband multispectral imaging can be very helpful in showing differences in energy being radiated and is often employed by NASA satellites to monitor temperature and climate changes. In addition, hyperspectral imaging is ideal for advanced laboratory uses, biomedical imaging, forensics, counter-terrorism, skin health, food safety, and Earth imaging. Lextel Intelligence Systems, LLC, of Jackson, Mississippi purchased Photon Industries Inc., a spinoff company of NASA's Stennis Space Center and the Institute for Technology Development dedicated to developing new hyperspectral imaging technologies. Lextel has added new features to and expanded the applicability of the hyperspectral imaging systems. It has made advances in the size, usability, and cost of the instruments. The company now offers a suite of turnkey hyperspectral imaging systems based on the original NASA groundwork. It currently has four lines of hyperspectral imaging products: the EagleEye VNIR 100E, the EagleEye SWIR 100E, the EagleEye SWIR 200E, and the EagleEye UV 100E. These Lextel instruments are used worldwide for a wide variety of applications including medical, military, forensics, and food safety.

  13. Revisiting the Stark Broadening by fluctuating electric fields using the Continuous Time Random Walk Theory

    NASA Astrophysics Data System (ADS)

    Capes, H.; Christova, M.; Boland, D.; Catoire, F.; Godbert-Mouret, L.; Koubiti, M.; Mekkaoui, A.; Rosato, J.; Marandet, Y.; Stamm, R.

    2010-10-01

    Stark broadening of atomic lines in plasmas is calculated by modelling the plasma stochastic electric field using the CTRW approach [1,2]. This allows retaining non Markovian terms in the Schrödinger equation averaged over the electric field fluctuations. As an application we consider a special case of a non separable CTRW process, the so called Kangaroo process [3]. An analytic expression for the line profile is presented for arbitrary waiting time distribution functions. A preliminary application to the hydrogen Lyman α line is discussed.

  14. Influence of Impact Broadening on the CP Stars Spectra %t Uticaj sudarnog sirenja na spektre CP zvezda

    NASA Astrophysics Data System (ADS)

    Milovanovic, N.

    2004-09-01

    Stark broadening of spectral lines is dominant pressure broadening mechanism in hot, early-type, stars and white dwarf atmospheres. This type of broadening might also be important even in interstellar molecular and ionized hydrogen clouds, as e.g. for radio spectral lines in W51 emission nebulae, and in cooler stars as solar type ones for transitions involving higher principal quantum numbers. Present abundance analyses for early-type stars show that 10% - 20% of A and B stars have abundance anomalies, including anomalies in isotopic composition. The abundance anomalies in these stars, called CP stars, could be caused by diffusion occurring in the presence of selective radiative acceleration. The chemical species that absorb more of the outgoing photons are dragged by the photons to the stellar surface. Advanced calculation of the Stark broadening parameters using strong-coupling quantum-mechanical method are so complicated that only limited number of data for spectral lines originating from low laying transitions can be calculated in an adequate way. On the other hand, semiclassical method needs a set of large number of atomic data, energy levels and oscillator strengths. This method is not applicable in adequate way to the Stark broadening calculation of Zr II, Zr III and Cd III because there is no sufficient number of reliable atomic data. Here we use the modified semiempirical approach (MSE) which include explicitly only levels with δ n = 0 and l'if=lif +/- 1, where n is the principal quantum number, l is the orbital quantum number and i and f denote initial and final level, respectively. Levels with δ n ≠ 0 are lumped together and approximately estimated, so that for Stark broadening parameter calculation we need less atomic data then in the semiclassical method. The accuracy of the MSE calculations for spectral line widths is around +/- 50%. We present the computed electron-impact broadening parameters, Stark widths and shifts, for 30 multiplets of Zr III

  15. Mechanism of frequency-dependent broadening of molluscan neurone soma spikes.

    PubMed

    Aldrich, R W; Getting, P A; Thompson, S H

    1979-06-01

    1. Action potentials recorded from isolated dorid neurone somata increase in duration, i.e. broaden, during low frequency repetitive firing. Spike broadening is substantially reduced by external Co ions and implicates an inward Ca current. 2. During repetitive voltage clamp steps at frequencies slower than 1 Hz, in 100 mM-tetraethyl ammonium ions (TEA) inward Ca currents do not increase in amplitude. 3. Repetitive action potentials result in inactivation of delayed outward current. Likewise, repetitive voltage clamp steps which cause inactivation of delayed outward current also result in longer duration action potentials. 4. The frequency dependence of spike broadening and inactivation of the voltage dependent component (IK) of delayed outward current are similar. 5. Inactivation of IK is observed in all cells, however, only cells with relative large inward Ca currents show significant spike broadening. Spike broadening apparently results from the frequency dependent inactivation of IK which increases the expression of inward Ca current as a prominent shoulder on the repolarizing phase of the action potential. In addition, the presence of a prolonged Ca current increases the duration of the first action potential thereby allowing sufficient time for inactivation of IK.

  16. Parton Energy Loss and Momentum Broadening at NLO in High Temperature QCD Plasmas

    NASA Astrophysics Data System (ADS)

    Ghiglieri, Jacopo; Teaney, Derek

    We present an overview of a perturbative-kinetic approach to jet propagation, energy loss, and momentum broadening in a high temperature quark-gluon plasma. The leading-order kinetic equations describe the interactions between energetic jet-particles and a non-abelian plasma, consisting of on-shell thermal excitations and soft gluonic fields. These interactions include 2 ↔ 2 scatterings, collinear bremsstrahlung, and drag and momentum diffusion. We show how the contribution from the soft gluonic fields can be factorized into a set of Wilson line correlators on the light-cone. We review recent field-theoretical developments, rooted in the causal properties of these correlators, which simplify the calculation of the appropriate Wilson lines in thermal field theory. With these simplifications lattice measurements of transverse momentum broadening have become possible, and the kinetic equations describing parton transport have been extended to next-to-leading order in the coupling g.

  17. Parton energy loss and momentum broadening at NLO in high temperature QCD plasmas

    NASA Astrophysics Data System (ADS)

    Ghiglieri, Jacopo; Teaney, Derek

    2015-10-01

    We present an overview of a perturbative-kinetic approach to jet propagation, energy loss, and momentum broadening in a high temperature quark-gluon plasma. The leading-order kinetic equations describe the interactions between energetic jet-particles and a non-abelian plasma, consisting of on-shell thermal excitations and soft gluonic fields. These interactions include ↔ scatterings, collinear bremsstrahlung, and drag and momentum diffusion. We show how the contribution from the soft gluonic fields can be factorized into a set of Wilson line correlators on the light-cone. We review recent field-theoretical developments, rooted in the causal properties of these correlators, which simplify the calculation of the appropriate Wilson lines in thermal field theory. With these simplifications lattice measurements of transverse momentum broadening have become possible, and the kinetic equations describing parton transport have been extended to next-to-leading order in the coupling g.

  18. Low Temperature Measurements of HCN Broadened by N2 in the 14-micron Spectral Region

    SciTech Connect

    Smith, M.A.H.; Rinsland, Curtis P.; Blake, Thomas A.; Sams, Robert L.; Benner, D. C.; Devi, V. M.

    2008-04-01

    N2-broadening and N2-pressure-induced shift coefficients; and the temperature dependence exponent of the N2-broadening and the temperature dependent coefficients of N2-pressure-induced shifts have been measured for transitions in the v2 band of HCN from analysis of high-resolution absorption spectra recorded with two different Fourier transform spectrometers. A total of 34 laboratory spectra recorded at 0.002-0.005 cm-1 resolution and at temperatures ranging from 211 to 300 K were used in the determination of various spectral line parameters. A multispectrum nonlinear least squares curve fitting technique employing a modified Voigt line profile including speed dependence was used in the P- and R-branch measurements. In analyzing the Q branch transitions, the off-diagonal relaxation matrix element coefficients were included in analysis to fit the data. Present results are compared to previous measurements reported in the literature.

  19. Deconvolution of Stark broadened spectra for multi-point density measurements in a flow Z-pinch

    DOE PAGES

    Vogman, G. V.; Shumlak, U.

    2011-10-13

    Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian functionmore » associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. As a result, these measurements are used to gain a better understanding of Z-pinch equilibria.« less

  20. Deconvolution of Stark broadened spectra for multi-point density measurements in a flow Z-pinch

    SciTech Connect

    Vogman, G. V.; Shumlak, U.

    2011-10-15

    Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian function associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. These measurements are used to gain a better understanding of Z-pinch equilibria.

  1. Deconvolution of Stark broadened spectra for multi-point density measurements in a flow Z-pinch

    SciTech Connect

    Vogman, G. V.; Shumlak, U.

    2011-10-13

    Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian function associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. As a result, these measurements are used to gain a better understanding of Z-pinch equilibria.

  2. Doppler Broadening Thermometry Based on Cavity Ring-Down Spectroscopy

    NASA Astrophysics Data System (ADS)

    Wang, Jin; Sun, Yu Robert; Cheng, Cunfeng; Tao, Lei-Gang; Tan, Yan; Kang, Peng; Liu, An-Wen; Hu, Shui-Ming

    2016-06-01

    A Doppler broadening thermometry (DBT) instrument is implemented based on a laser-locked cavity ring-down spectrometer. [1,2] It can be used to determine the Boltzmann constant by measuring the Doppler width of a molecular ro-vibrational transition in the near infrared. Compared with conventional direct absorption methods, the high-sensitivity of CRDS allows to reach satisfied precision at lower sample pressures, which reduces the influence due to collisions. By measuring the ro-vibrational transition of C_2H_2 at 787 nm, we demonstrate a statistical uncertainty of 6 ppm (part per million) in the determined linewidth by several hours' measurement at a sample pressure of 1.5 Pa. [3] However, the complicity in the spectrum of a polyatomic molecule induces potential systematic influence on the line profile due to nearby ``hidden'' lines from weak bands or minor isotopologues. Recently, the instrument has been upgraded in both sensitivity and frequency accuracy. A narrow-band fiber laser frequency-locked to a frequency comb is applied, and overtone transitions at 1.56 μm of the 12C16O molecule are used in the CRDS-DBT measurements. The simplicity of the spectrum of the diatomic CO molecule eliminates the potential influence from ``hidden'' lines. Our preliminary measurements and analysis show that it is feasible to pursue a DBT measurement toward the 1 ppm precision. H. Pan, et al., Rev. Sci. Instrum. 82, 103110 (2011) Y. R. Sun, et al., Opt. Expr., 19, 19993 (2011) C.-F. Cheng, et al., Metrologia, 52, S385 (2015)

  3. Ghost features in Doppler-broadened spectra of rovibrational transitions in trapped HD+ ions

    NASA Astrophysics Data System (ADS)

    Patra, Sayan; Koelemeij, J. C. J.

    2017-02-01

    Doppler broadening plays an important role in laser rovibrational spectroscopy of trapped deuterated molecular hydrogen ions (HD+), even at the millikelvin temperatures achieved through sympathetic cooling by laser-cooled beryllium ions. Recently, Biesheuvel et al. (2016) presented a theoretical lineshape model for such transitions which not only considers linestrengths and Doppler broadening, but also the finite sample size and population redistribution by blackbody radiation, which are important in view of the long storage and probe times achievable in ion traps. Here, we employ the rate equation model developed by Biesheuvel et al. to theoretically study the Doppler-broadened hyperfine structure of the (v, L) : (0, 3) → (4, 2) rovibrational transition in HD+ at 1442 nm. We observe prominent yet hitherto unrecognized ghost features in the simulated spectrum, whose positions depend on the Doppler width, transition rates, and saturation levels of the hyperfine components addressed by the laser. We explain the origin and behavior of such features, and we provide a simple quantitative guideline to assess whether ghost features may appear. As such ghost features may be common to saturated Doppler-broadened spectra of rotational and vibrational transitions in trapped ions composed of partly overlapping lines, our work illustrates the necessity to use lineshape models that take into account all the relevant physics.

  4. Laser-induced plasma electron number density: Stark broadening method versus the Saha-Boltzmann equation

    NASA Astrophysics Data System (ADS)

    Arnab, Sarkar; Manjeet, Singh

    2017-02-01

    We report spectroscopic studies on plasma electron number density of laser-induced plasma produced by ns-Nd:YAG laser light pulses on an aluminum sample in air at atmospheric pressure. The effect of different laser energy and the effect of different laser wavelengths were compared. The experimentally observed line profiles of neutral aluminum have been used to extract the excitation temperature using the Boltzmann plot method, whereas the electron number density has been determined from the Stark broadened as well as using the Saha-Boltzmann equation (SBE). Each approach was also carried out by using the Al emission line and Mg emission lines. It was observed that the SBE method generated a little higher electron number density value than the Stark broadening method, but within the experimental uncertainty range. Comparisons of N e determined by the two methods show the presence of a linear relation which is independent of laser energy or laser wavelength. These results show the applicability of the SBE method for N e determination, especially when the system does not have any pure emission lines whose electron impact factor is known. Also use of Mg lines gives superior results than Al lines.

  5. Droplet spectral broadening in marine stratus

    SciTech Connect

    Hudson, J.G.; Yum, Seong Soo

    1997-11-15

    Broadening of the cloud droplet (diameter < 50 {mu}m) spectrum with increased droplet size was found to depend on the vertical profiles of cloud water. Clouds with liquid water profiles resembling adiabatic conditions displayed constant spectral widths. Other clouds displayed broader droplet spectra and increasing broadness with mean droplet sizes. Less than adiabatic cloud liquid water profiles may be accounted for by conversion to drops (diameter > 50 {mu}m, i.e., drizzle). Broad droplet spectra were most closely associated with drizzle drops. Both the concentration, C and slope, k, of the cloud condensation nuclei (CCN) spectra were theoretically found to affect droplet spectral width. For individual cloud parcels a higher C and lower k each contributed to broader droplet spectra. When mixing among cloud parcels with different updrafts was considered, the predictions deviated especially at larger mean droplet diameters. Variations in updraft velocity result in differences in droplet concentrations and mean droplet sizes. The predictions for this internal mixing process showed greater droplet spectral widths for CCN spectra with higher k, especially at the larger mean droplet diameters. Instead of the individual parcel predictions of narrower droplet spectra at larger mean droplet sizes, internal mixing predicted increasing droplet spectral width with increasing mean droplet size. These predictions are consistent with the observations. First, when only cloud parcels with small mean droplet diameters (< 1 {mu}m) were considered, the polluted clouds that formed on CCN with higher C and lower k displayed broader droplet spectra than clean clouds. Cloud parcels with large mean droplet diameters (>12 {mu}m) and large {sigma} were observed only in clean conditions where k was high. Increasing droplet spectral width with mean droplet diameter (especially > 12 {mu}m) is typical of many observations here and elsewhere.

  6. Deconvolution of 2D coincident Doppler broadening spectroscopy using the Richardson Lucy algorithm

    NASA Astrophysics Data System (ADS)

    Zhang, J. D.; Zhou, T. J.; Cheung, C. K.; Beling, C. D.; Fung, S.; Ng, M. K.

    2006-05-01

    Coincident Doppler Broadening Spectroscopy (CDBS) measurements are popular in positron solid-state studies of materials. By utilizing the instrumental resolution function obtained from a gamma line close in energy to the 511 keV annihilation line, it is possible to significantly enhance the quality of the CDBS spectra using deconvolution algorithms. In this paper, we compare two algorithms, namely the Non-Negativity Least Squares (NNLS) regularized method and the Richardson-Lucy (RL) algorithm. The latter, which is based on the method of maximum likelihood, is found to give superior results to the regularized least-squares algorithm and with significantly less computer processing time.

  7. Isobolographic analysis demonstrates additive effect of cisplatin and HDIs combined treatment augmenting their anti-cancer activity in lung cancer cell lines

    PubMed Central

    Gumbarewicz, Ewelina; Luszczki, Jarogniew J; Wawruszak, Anna; Dmoszynska-Graniczka, Magdalena; Grabarska, Aneta J; Jarząb, Agata M; Polberg, Krzysztof; Stepulak, Andrzej

    2016-01-01

    Histone deacetylase inhibitors (HDIs) are a new class of drugs which affect the activity of HDACs resulting in changed of acetylation in many proteins. HDIs can induce differentiation, cell growth arrest, apoptosis, inhibit proliferation and angiogenesis in cancer, whereas normal cells are comparatively resistant to the action of HDIs. The aim of this study was to investigate the combined effect of a well-known cytostatic agent-cisplatin (CDDP) and a histone deacetylase inhibitors-either suberoylanilide hydroxamic acid (SAHA, vorinostat) or valproic acid (VPA), on the proliferation of lung cancer cells, as well as induction of apoptosis and inhibition of the cell cycle progression. The anti-proliferative activity of VPA or SAHA used alone, or in combination with CDDP were determined by means of MTT test. The type of pharmacologic interactions between HDAC inhibitors and CDDP was assessed using isobolographic analysis. We observed additive interactions for the CCDP with SAHA, as well as for the CDDP with VPA combinations with respect to their anti-proliferative effects on three different lung cancer cell lines (A549, NCI-H1563 and NCI-H2170). Such additive effects were observed regardless of the histologic type (adenocarcinoma or squamous cell carcinoma) and sensitivity for the drugs applied. Combination treatment also augmented the induction of apoptosis and cell cycle perturbation mediated by CDDP alone, thereby enhancing anti-cancer effect of tested drugs. In conclusion, the combined therapy of HDIs and CDDP may be a promising therapeutic tool in the treatment of lung cancer. PMID:28042503

  8. Doppler Broadening Thermometry Based on Cavity Ring-Down Spectroscopy

    NASA Astrophysics Data System (ADS)

    Hu, Shui-Ming; Cheng, Cunfeng; Wang, Jin; Tan, Yan; Sun, Yu Robert; Liu, An-Wen; Zhang, Jin-Tao

    2014-06-01

    A Doppler broadening thermometry is implemented using a laser-locked cavity ring-down spectrometer [1,2] combined with a temperature-stabilized sample cell. The temperature fluctuation of the gas sample cell is kept below 1 mK for hours. The probing laser is frequency locked at a longitudinal mode of a Fabry-Pérot interferometer made of ultra-low-expansion glass, and the spectral scan is implemented by scanning the sideband produced by an electro-optic modulator. As a result, a kHz precision has been maintained during the measurement of the spectrum of 10 GHz wide. A ro-vibrational line of C_2H_2 is measured at sample pressures of a few Pa. Using a pair of mirrors with a reflectivity of 0.99997 at 787 nm, we are able to detect absorption line profiles with a signal-to-noise ratio of 10^5. Fitting of the recorded spectra allows us to determine the Doppler width with a statistical uncertainty of 10 ppm. Further improvements on the experimental reproducibility and investigations on the collision effects will probably lead to an optical determination of the Boltzmann constant with an uncertainty of a few ppm. H. Pan, C.-F. Cheng, Y. R. Sun, B. Gao, A.-W. Liu, S.-M. Hu, ``Laser-locked, continuously tunable high resolution cavity ring-down spectrometer," Rev. Sci. Instrum. 82, 103110 (2011) Y. R. Sun, H. Pan, C.-F. Cheng, A.-W. Liu, J.-T. Zhang, S.-M. Hu, ``Application of cavity ring-down spectroscopy to the Boltzmann constant determination," Opt. Express, 19, 19993 (2011)

  9. Electronic Broadening operator for relativistic plasmas

    SciTech Connect

    Meftah, M. T.; Naam, A.

    2008-10-22

    In this work we review some aspects of the semiclassical dipole impact approximation for isolated ion lines in relativistic plasma. Mainly we focuss our work on the collision operator for relativistic electrons. In this case, the electron trajectory around a positive charge in the plasma differs drastically from those known earlier as hyperbolic. The effect of this difference on the collision operator is discussed with respect the various plasma conditions. Some theoretical and practical aspects of lines -shape calculations are discussed. Detailed calculations are performed for the collision operator in the semiclassical (dipole) impact approximation.

  10. Implementation of On-the-Fly Doppler Broadening in MCNP5 for Multiphysics Simulation of Nuclear Reactors

    SciTech Connect

    William Martin

    2012-11-16

    A new method to obtain Doppler broadened cross sections has been implemented into MCNP, removing the need to generate cross sections for isotopes at problem temperatures. Previous work had established the scientific feasibility of obtaining Doppler-broadened cross sections "on-the-fly" (OTF) during the random walk of the neutron. Thus, when a neutron of energy E enters a material region that is at some temperature T, the cross sections for that material at the exact temperature T are immediately obtained by interpolation using a high order functional expansion for the temperature dependence of the Doppler-broadened cross section for that isotope at the neutron energy E. A standalone Fortran code has been developed that generates the OTF library for any isotope that can be processed by NJOY. The OTF cross sections agree with the NJOY-based cross sections for all neutron energies and all temperatures in the range specified by the user, e.g., 250K - 3200K. The OTF methodology has been successfully implemented into the MCNP Monte Carlo code and has been tested on several test problems by comparing MCNP with conventional ACE cross sections versus MCNP with OTF cross sections. The test problems include the Doppler defect reactivity benchmark suite and two full-core VHTR configurations, including one with multiphysics coupling using RELAP5-3D/ATHENA for the thermal-hydraulic analysis. The comparison has been excellent, verifying that the OTF libraries can be used in place of the conventional ACE libraries generated at problem temperatures. In addition, it has been found that using OTF cross sections greatly reduces the complexity of the input for MCNP, especially for full-core temperature feedback calculations with many temperature regions. This results in an order of magnitude decrease in the number of input lines for full-core configurations, thus simplifying input preparation and reducing the potential for input errors. Finally, for full-core problems with multiphysics

  11. Laboratory spectroscopy of nitrogen-broadened methane at 79 K to 297 K

    NASA Astrophysics Data System (ADS)

    Smith, M. A. H.; Mantz, A. W.; Sung, K.; Brown, L. R.; Crawford, T. J.; Malathy Devi, V.; Benner, D. Chris

    2010-04-01

    To support the remote sensing of Titan's atmosphere, we studied the temperature dependence of the nitrogen-broadened spectrum of the three most abundant methane isotopomers (12CH4, 13CH4, and CH3D) in the 7.5-micron region. For this purpose a temperature stabilized cryogenic cell, cooled by a closed-cycle helium refrigerator, was designed to be fit into the sample compartment of a Bruker high-resolution Fourier transform spectrometer. Two generations of this cell, built at Connecticut College, have been used to record N2-broadened methane spectra with the Bruker IFS-125HR spectrometer at the Jet Propulsion Laboratory (JPL). Nitrogen-broadened spectra of all three methane isotopomers were recorded at temperatures between 79.3 K and 297.1 K. The spectra are analyzed using a multispectrum fitting technique to determine the temperature-dependences of line widths, pressure-induced shifts, and line mixing parameters. Preliminary results will be shown and compared with the few available literature values. The research described in this paper was performed at NASA Langley, the Jet Propulsion Laboratory, California Institute of Technology, Connecticut College, and the College of William and Mary under contracts and grants with the National Aeronautics and Space Administration.

  12. The 0 --> 3 Overtone Band of CO: Precise Linestrengths and Broadening Parameters.

    PubMed

    Henningsen; Simonsen; Møgelberg; Trudsø

    1999-02-01

    Linestrengths and self-broadening parameters are determined with a standard uncertainty of 1% for 21 lines in the R branch of the 0 --> 3 overtone band of CO around 1.57 µm. The values are lower than those given in the Hitran database by 6-8% for the linestrengths and 1-5% for the collision broadening parameters, and they agree within 0-2% with more recent results obtained with FTIR. Also, results are given for foreign gas broadening by N2 and H2O. The line profiles show clear evidence for collisional narrowing with deviations corresponding to those expected for a Galatry profile. When analyzed in terms of a Voigt profile, this effect causes a reduction in effective Doppler width of about 5%. The linestrengths determined for gas mixtures are used for producing independent values for the CO concentrations. These results are derived without reference to any certified gas standard, and it is suggested that optical spectroscopy satisfies the criteria of a primary method set up by the Consultative Committee for Quantity of Matter (CCQM). Copyright 1999 Academic Press.

  13. Photoacoustic measurements of Lorentz broadening in CO2 between 25° C and 450° C

    NASA Astrophysics Data System (ADS)

    Hammerich, M.; Vildrik-Sørensen, L.; de Vries, H.; Henningsen, J.

    1991-09-01

    A variable temperature photoacoustic cell has been constructed and tested by studying the interplay of CO2, H2O, and NH3 in synthetic smoke. Saturation effects for CO2 and NH3 have been modeled and compared with experiments, and results are obtained for the vibrational relaxation rate associated with NH3-H2O collisions. The cell has been used for studying the temperature dependence of self-broadening and N2 broadening of CO2 lines. The temperature dependence of the scattering rate is well described by a T - n law with n=0.77 in both cases. This result agrees with previous results obtained by tunable diode laser spectroscopy, but disagrees with results obtained by indirect methods.

  14. Medium induced transverse momentum broadening in hard processes

    NASA Astrophysics Data System (ADS)

    Mueller, A. H.; Wu, Bin; Xiao, Bo-Wen; Yuan, Feng

    2017-02-01

    Using deep inelastic scattering on a large nucleus as an example, we consider the transverse momentum broadening of partons in hard processes in the presence of medium. We find that one can factorize the vacuum radiation contribution and medium related PT broadening effects into the Sudakov factor and medium dependent distributions, respectively. Our derivations can be generalized to other hard processes, such as dijet productions, which can be used as a probe to measure the medium PT broadening effects in heavy ion collisions when Sudakov effects are not overwhelming.

  15. Band-broadening in capillary zone electrophoresis with axial temperature gradients.

    PubMed

    Xuan, Xiangchun; Li, Dongqing

    2005-01-01

    It is widely accepted that Joule heating effects yield radial temperature gradients in capillary zone electrophoresis (CZE). The resultant parabolic profile of electrophoretic velocity of analyte molecules is believed to increase the band-broadening via Taylor-Aris dispersion. This typically insignificant contribution, however, cannot explain the decrease in separation efficiency at high electric fields. We show that the additional band-broadening due to axial temperature gradients may provide the answer. These axial temperature variations result from the change of heat transfer condition along the capillary, which is often present in CZE with thermostating. In this case, the electric field becomes nonuniform due to the temperature dependence of fluid conductivity, and hence the induced pressure gradient is brought about to meet the mass continuity. This modification of the electroosmotic flow pattern can cause significant band-broadening. An analytical model is developed to predict the band-broadening in CZE with axial temperature gradients in terms of the theoretical plate height. We find that the resultant thermal plate height can be very high and even comparable to that due to molecular diffusion. This thermal plate height is much higher than that due to radial temperature gradients alone. The analytical model explains successfully the phenomena observed in previous experiments.

  16. Laboratory Pressure Broadening Coefficients To Support SOIR/VEx And SOIR-NOMAD

    NASA Astrophysics Data System (ADS)

    Drummond, Rachel; Földes, T.; Vander Auwera, J.; Mahieux, A.; Robert, S.; Vandaele, A.; Wilquet, V.

    2010-10-01

    Precise spectroscopic data to describe CO2 pressure-broadened lineshapes of trace gases in the Venus and Mars atmospheres are rather scarce. In an attempt to compensate for such a situation, we recorded in the laboratory CO2 broadened absorption spectra of the 1-0 band of HCl near 2886 cm-1 and the ν3 band of CH4 near 3019 cm-1 at several pressures between 150 and 700 Torr, using a high-resolution Fourier transform spectrometer. CO2 pressure broadening half-width coefficients are extracted by least-squares fitting of suitable molecular line profiles, including instrumental effects. Sensitivity studies have been performed using the characteristics of the SOIR instrument. This instrument is currently on board the Venus Express mission (ESA) and has been proposed as payload for the future ExoMars 2016 TGO mission (ESA/NASA). The SOIR instrument is designed to measure atmospheric transmission in the near-IR (2.2 - 4.3 µm) at high resolution (0.12 cm-1) through solar occultation observations. It therefore allows the derivation of unique remote sensing information about the vertical structure and composition of the Venus mesosphere, with very good spatial resolution. At Venus, SOIR is able to provide HCl vertical profiles ranging typically from 80 to 105 km, at both morning and evening terminators, where the dynamics of the planetary atmosphere are relatively unknown. At Mars, the high resolution of the instrument will make it possible to observe CH4, if any. We show here how these two approaches, laboratory and space missions, are complimentary, as broadening coefficients measured in the laboratory allow us to simulate perfectly HCl and CH4 lines as seen by SOIR.

  17. Transcriptome analysis of genes related to resistance against powdery mildew in wheat-Thinopyrum alien addition disomic line germplasm SN6306.

    PubMed

    Li, Quanquan; Niu, Zubiao; Bao, Yinguang; Tian, Qiuju; Wang, Honggang; Kong, Lingrang; Feng, Deshun

    2016-09-15

    Wheat powdery mildew, which is mainly caused by Blumeria graminis f. sp. tritici (Bgt), seriously damages wheat production. The wheat-Thinopyrum intermedium alien addition disomic line germplasm SN6306, being one of the important sources of genes for wheat resistance, is highly resistant to Bgt E09 and to many other powdery mildew physiological races. However, knowledge on the resistance mechanism of SN6306 remains limited. Our study employed high-throughput RNA sequencing based on next-generation sequencing technology (Illumina) to obtain an overview of the transcriptome characteristics of SN6306 and its parent wheat Yannong 15 (YN15) during Bgt infection. The sequencing generated 104,773 unigenes, 9909 of which showed varied expression levels. Among the 9909 unigenes, 1678 unigenes showed 0 reads in YN15. The expression levels in Bgt-inoculated SN6306 and YN15 of exactly 39 unigenes that showed 0 or considerably low reads in YN15 were validated to identify the genes involved in Bgt resistance. Among the 39 unigenes, 12 unigenes were upregulated in SN6306 by 3-45 times. These unigenes mainly encoded kinase, synthase, proteases, and signal transduction proteins, which may play an important role in the resistance against Bgt. To confirm whether the unigenes that showed 0 reads in YN15 are really unique to SN6306, 8 unigenes were cloned and sequenced. Results showed that the selected unigenes are more similar to SN6306 and Th. intermedium than to the wheat cultivar YN15. The sequencing results further confirmed that the unigenes showing 0 reads in YN15 are unique to SN6306 and are most likely derived from Th. intermedium (Host) Nevski. Thus, the genes from Th. intermedium most probably conferred the resistance of SN6306 to Bgt.

  18. Microparticles generated by decompression stress cause central nervous system injury manifested as neurohypophysial terminal action potential broadening.

    PubMed

    Yang, Ming; Kosterin, Paul; Salzberg, Brian M; Milovanova, Tatyana N; Bhopale, Veena M; Thom, Stephen R

    2013-11-01

    The study goal was to use membrane voltage changes during neurohypophysial action potential (AP) propagation as an index of nerve function to evaluate the role that circulating microparticles (MPs) play in causing central nervous system injury in response to decompression stress in a murine model. Mice studied 1 h following decompression from 790 kPa air pressure for 2 h exhibit a 45% broadening of the neurohypophysial AP. Broadening did not occur if mice were injected with the MP lytic agent polyethylene glycol telomere B immediately after decompression, were rendered thrombocytopenic, or were treated with an inhibitor of nitric oxide synthase-2 (iNOS) prior to decompression, or in knockout (KO) mice lacking myeloperoxidase or iNOS. If MPs were harvested from control (no decompression) mice and injected into naive mice, no AP broadening occurred, but AP broadening was observed with injections of equal numbers of MPs from either wild-type or iNOS KO mice subjected to decompression stress. Although not required for AP broadening, MPs from decompressed mice, but not control mice, exhibit NADPH oxidase activation. We conclude that inherent differences in MPs from decompressed mice, rather than elevated MPs numbers, mediate neurological injury and that a component of the perivascular response to MPs involves iNOS. Additional study is needed to determine the mechanism of AP broadening and also mechanisms for MP generation associated with exposure to elevated gas pressure.

  19. Frequency band broadening of magnetospheric VLF emissions near the equator

    NASA Technical Reports Server (NTRS)

    Maeda, K.; Lin, C. S.

    1981-01-01

    The broadening of the whistler mode VLF emission band has frequently been observed by the equatorially orbiting S3-A (Explorer 45) satellite outside the midnight sector of the plasmasphere, during periods of geomagnetic disturbance. Prior to the broadening, the band of this emission is narrow with a sharp gap at the half electron gyrofrequency. The gradual broadening of the emission band on the low-frequency side is associated with the simultaneously observed spreading of the anisotropy of the ring current electrons to higher and wider energy ranges. Using the modeled distribution function, the linear growth rates of the cyclotron instability are calculated numerically. The results suggest that broadening of the VLF emission band near the plasmasphere can be caused by spreading of the ring current electron anisotropy toward higher energies.

  20. SOLAR WIND STRAHL BROADENING BY SELF-GENERATED PLASMA WAVES

    SciTech Connect

    Pavan, J.; Gaelzer, R.; Vinas, A. F.; Yoon, P. H.; Ziebell, L. F. E-mail: rudi@ufpel.edu.br E-mail: yoonp@umd.edu

    2013-06-01

    This Letter reports on the results of numerical simulations which may provide a possible explanation for the strahl broadening during quiet solar conditions. The relevant processes involved in the broadening are due to kinetic quasi-linear wave-particle interaction. Making use of static analytical electron distribution in an inhomogeneous field, it is found that self-generated electrostatic waves at the plasma frequency, i.e., Langmuir waves, are capable of scattering the strahl component, resulting in energy and pitch-angle diffusion that broadens its velocity distribution significantly. The present theoretical results provide an alternative or complementary explanation to the usual whistler diffusion scenario, suggesting that self-induced electrostatic waves at the plasma frequency might play a key role in broadening the solar wind strahl during quiet solar conditions.

  1. Level broadening and quantum interference effects in insulators

    NASA Astrophysics Data System (ADS)

    Medina, Ernesto; Pastawski, Horacio

    2000-03-01

    We study quantum interference effects in the context of the Nguyen-Spivak-Shklovskii (NSS) model including level broadening due to inelastic events. Improving on a recent mean-field approach, we incorporate path correlations and study both the log-conductance and its fluctuations. In contrast with mean field, we find that all changes in the conductance, due to broadening, imply corrections to the localization length. Furthermore, the change in the magnetoconductance sign, predicted by mean field, is not borne out by direct solution of the NSS model within reasonable broadening parameters. We compute a phase diagram for the magnetoconductance in the broadening parameter space and propose a replica theory for weak inelastic events.

  2. Probing transverse momentum broadening in heavy ion collisions

    NASA Astrophysics Data System (ADS)

    Mueller, A. H.; Wu, Bin; Xiao, Bo-Wen; Yuan, Feng

    2016-12-01

    We study the dijet azimuthal de-correlation in relativistic heavy ion collisions as an important probe of the transverse momentum broadening effects of a high energy jet traversing the quark-gluon plasma. We take into account both the soft gluon radiation in vacuum associated with the Sudakov logarithms and the jet PT-broadening effects in the QCD medium. We find that the Sudakov effects are dominant at the LHC, while the medium effects can play an important role at RHIC energies. This explains why the LHC experiments have not yet observed sizable PT-broadening effects in the measurement of dijet azimuthal correlations in heavy ion collisions. Future investigations at RHIC will provide a unique opportunity to study the PT-broadening effects and help to pin down the underlying mechanism for jet energy loss in a hot and dense medium.

  3. Solar Wind Strahl Broadening by Self-Generated Plasma Waves

    NASA Technical Reports Server (NTRS)

    Pavan, J.; Vinas, A. F.; Yoon, P. H.; Ziebell, L. F.; Gaelzer, R.

    2013-01-01

    This Letter reports on the results of numerical simulations which may provide a possible explanation for the strahl broadening during quiet solar conditions. The relevant processes involved in the broadening are due to kinetic quasi-linear wave-particle interaction. Making use of static analytical electron distribution in an inhomogeneous field, it is found that self-generated electrostatic waves at the plasma frequency, i.e., Langmuir waves, are capable of scattering the strahl component, resulting in energy and pitch-angle diffusion that broadens its velocity distribution significantly. The present theoretical results provide an alternative or complementary explanation to the usual whistler diffusion scenario, suggesting that self-induced electrostatic waves at the plasma frequency might play a key role in broadening the solar wind strahl during quiet solar conditions.

  4. Coherent and incoherent spectral broadening in a photonic crystal fiber.

    PubMed

    Gross, C; Best, Th; van Oosten, D; Bloch, I

    2007-07-01

    The coherence of the spectral broadening process is the key requisite for the application of supercontinua in frequency combs. We investigate the coherence of two subsequent supercontinuum pulses created in a photonic crystal fiber pumped by a femtosecond laser. We measure Young interference fringes from a Michelson-type interferometer at different wavelengths of the output spectrum and analyze their dependence on pump intensity and polarization. The visibility of these fringes is a direct measure of the coherence of the spectral broadening processes.

  5. Self-phase-modulation induced spectral broadening in silicon waveguides.

    PubMed

    Boyraz, Ozdal; Indukuri, Tejaswi; Jalali, Bahram

    2004-03-08

    The prospect for generating supercontinuum pulses on a silicon chip is studied. Using ~4ps optical pulses with 2.2GW/cm(2) peak power, a 2 fold spectral broadening is obtained. Theoretical calculations, that include the effect of two-photon-absorption, indicate up to 5 times spectral broadening is achievable at 10x higher peak powers. Representing a nonlinear loss mechanism at high intensities, TPA limits the maximum optical bandwidth that can be generated.

  6. CO2-broadening coefficients in the ν4 fundamental band of methane at room temperature and application to CO2-rich planetary atmospheres

    NASA Astrophysics Data System (ADS)

    Fissiaux, Laurent; Delière, Quentin; Blanquet, Ghislain; Robert, Séverine; Vandaele, Ann Carine; Lepère, Muriel

    2014-03-01

    Using a tunable diode-laser spectrometer, we have measured the CO2-broadening coefficients of 28 absorption lines in the ν4 band of CH4. Each line was recorded at room temperature (296 K) and at 4 different pressures, ranging from 8 to 50 mbar. The experimental determination of the CO2-broadening coefficients was performed by fitting a theoretical profile to the experimental profile of each line recorded at each pressure. Voigt, Rautian-Sobel'man and Galatry models were therefore used. The impact of these determinations on atmospheric investigations on CO2-rich planetary atmospheres are addressed.

  7. Diode laser spectra of CC12F2 near 10.8 microns; air-broadening effects

    NASA Technical Reports Server (NTRS)

    Jennings, D. E.

    1978-01-01

    A tunable diode laser absorption spectrometer with resolution of about 0.0001/cm was used to record air-broadened spectra of CC12F2 in two regions near 922.8/cm and 921.7/cm. In the 922.8/cm region the structure shows good intensity contrast at pressures corresponding to upper atmospheric pressures. The absorption features have a spacing of 0.014/cm, which is sufficiently wide to retain spectral structure at pressures as high as 48 torr or altitudes as low as 19 km. The apparent broadening is 2 MHz/torr. The single-line broadening coefficient for CC12F2 can be estimated to be 8 + or - 2 MHz/torr FWHM. In the 921.7/cm region the high-resolution structure is discernible up to 24 torr, but the intensity contrast is not sufficiently strong to be of use in analysis of stratospheric spectra.

  8. Research on Fast-Doppler-Broadening of neutron cross sections

    SciTech Connect

    Li, S.; Wang, K.; Yu, G.

    2012-07-01

    A Fast-Doppler-Broadening method is developed in this work to broaden Continuous Energy neutron cross-sections for Monte Carlo calculations. Gauss integration algorithm and parallel computing are implemented in this method, which is unprecedented in the history of cross section processing. Compared to the traditional code (NJOY, SIGMA1, etc.), the new Fast-Doppler-Broadening method shows a remarkable speedup with keeping accuracy. The purpose of using Gauss integration is to avoid complex derivation of traditional broadening formula and heavy load of computing complementary error function that slows down the Doppler broadening process. The OpenMP environment is utilized in parallel computing which can take full advantage of modern multi-processor computers. Combination of the two can reduce processing time of main actinides (such as {sup 238}U, {sup 235}U) to an order of magnitude of 1{approx}2 seconds. This new method is fast enough to be applied to Online Doppler broadening. It can be combined or coupled with Monte Carlo transport code to solve temperature dependent problems and neutronics-thermal hydraulics coupled scheme which is a big challenge for the conventional NJOY-MCNP system. Examples are shown to determine the efficiency and relative errors compared with the NJOY results. A Godiva Benchmark is also used in order to test the ACE libraries produced by the new method. (authors)

  9. The broaden-and-build theory of positive emotions.

    PubMed Central

    Fredrickson, Barbara L

    2004-01-01

    The broaden-and-build theory describes the form and function of a subset of positive emotions, including joy, interest, contentment and love. A key proposition is that these positive emotions broaden an individual's momentary thought-action repertoire: joy sparks the urge to play, interest sparks the urge to explore, contentment sparks the urge to savour and integrate, and love sparks a recurring cycle of each of these urges within safe, close relationships. The broadened mindsets arising from these positive emotions are contrasted to the narrowed mindsets sparked by many negative emotions (i.e. specific action tendencies, such as attack or flee). A second key proposition concerns the consequences of these broadened mindsets: by broadening an individual's momentary thought-action repertoire--whether through play, exploration or similar activities--positive emotions promote discovery of novel and creative actions, ideas and social bonds, which in turn build that individual's personal resources; ranging from physical and intellectual resources, to social and psychological resources. Importantly, these resources function as reserves that can be drawn on later to improve the odds of successful coping and survival. This chapter reviews the latest empirical evidence supporting the broaden-and-build theory and draws out implications the theory holds for optimizing health and well-being. PMID:15347528

  10. Low Arousing Positive Affect Broadens Visual Attention and Alters the Thought-Action Repertoire While Broadened Visual Attention Does Not

    PubMed Central

    Jäger, Daniel T.; Rüsseler, Jascha

    2016-01-01

    The Broaden-and-Build Theory states that positive emotions broaden cognition and therefore build personal resources. However, missing theoretical precision regarding the interaction of the cognitive processes involved offers a variety of possible explanations for the mechanisms of broadening and building. In Experiment 1 we tested the causality assumption which states that positive emotions first broaden visual attention which in turn leads to broadened cognition. We examined the effects of a broadened, narrowed or neutral attentional scope of 72 subjects (30 men) on their momentary thought-action repertoire. Results showed that there were no significant differences between groups regarding the breadth or the content of the thought-action repertoire. In Experiment 2 we studied the non-causality hypothesis which assumes a non-causal relationship between cognitive processes. We did so by investigating the effects of negative, neutral, and positive affect on the visual attentional scope of 85 subjects (41 men) in Experiment 2a, as well as on the thought-action repertoire of 85 participants (42 men) in Experiment 2b. Results revealed an attentional broadening effect in Experiment 2a but no differences between groups concerning the breadth of the thought-action repertoire in Experiment 2b. However, a theory driven content analysis showed that positive affect promoted social actions. Thus, our results favor the non-causality assumption. Moreover, results indicate that positive emotions do not target personal resources in general but rather resources associated with social behavior. In conclusion, we argue that the Broaden-and-Build Theory should be refined. PMID:27826276

  11. Case Studies On Recent Stark Broadening Calculations And Stark-B Database Development In The Framework Of The European Project Vamdc (Virtual Atomic And Molecular Data Center)

    NASA Astrophysics Data System (ADS)

    Sahal-Bréchot, S.

    2010-07-01

    Stark broadening theories and calculations have been extensively developed for about 50 years. The theory can now be considered as mature for many applications, especially for accurate spectroscopic diagnostics and modelisation. In astrophysics, with the increasing sensitivity of observations and spectral resolution, in all domains of wavelengths from far UV to infrared, it has become possible to develop realistic models of interiors and atmospheres of stars and interpret their evolution. For hot stars, especially white dwarfs, Stark broadening is the dominant collisional line broadening process. This requires the knowledge of numerous collisional line profiles, especially for very weakly abundant atoms and ions that are used as useful probes for modern spectroscopic diagnostics. Hence, calculations based on a simple but enough accurate and fast method is indispensable for obtaining numerous results. Ab initio quantum calculations are also a useful domain of development, especially for ion emitters. Nowadays, the access to such data via an on line database becomes indispensable. The Virtual Atomic and Molecular Data Centre (VAMDC, http://www.vamdc.eu) is a European Union funded collaboration between groups involved in the generation and use of atomic and molecular data. VAMDC aims to build a secure, documented, flexible and interoperable e-science environment-based interface to existing atomic and molecular data. In this framework, the Stark-B (http://starkb.obspm.fr) database, which is a part of VAMDC, is a collaborative project between the Astronomical Observatory of Belgrade and the Laboratoire d'Etude du Rayonnement et de la Matière en Astrophysique (LERMA). It is a database of calculated widths and shifts of isolated lines of atoms and ions due to electron and ion collisions (i.e. impacts are separated in time). This database is devoted to modelisation and spectroscopic diagnostics of stellar atmospheres and envelopes. In addition, it is relevant to

  12. Charge Carrier Hopping Dynamics in Homogeneously Broadened PbS Quantum Dot Solids.

    PubMed

    Gilmore, Rachel H; Lee, Elizabeth M Y; Weidman, Mark C; Willard, Adam P; Tisdale, William A

    2017-02-08

    Energetic disorder in quantum dot solids adversely impacts charge carrier transport in quantum dot solar cells and electronic devices. Here, we use ultrafast transient absorption spectroscopy to show that homogeneously broadened PbS quantum dot arrays (σhom(2):σinh(2) > 19:1, σinh/kBT < 0.4) can be realized if quantum dot batches are sufficiently monodisperse (δ ≲ 3.3%). The homogeneous line width is found to be an inverse function of quantum dot size, monotonically increasing from ∼25 meV for the largest quantum dots (5.8 nm diameter/0.92 eV energy) to ∼55 meV for the smallest (4.1 nm/1.3 eV energy). Furthermore, we show that intrinsic charge carrier hopping rates are faster for smaller quantum dots. This finding is the opposite of the mobility trend commonly observed in device measurements but is consistent with theoretical predictions. Fitting our data to a kinetic Monte Carlo model, we extract charge carrier hopping times ranging from 80 ps for the smallest quantum dots to over 1 ns for the largest, with the same ethanethiol ligand treatment. Additionally, we make the surprising observation that, in slightly polydisperse (δ ≲ 4%) quantum dot solids, structural disorder has a greater impact than energetic disorder in inhibiting charge carrier transport. These findings emphasize how small improvements in batch size dispersity can have a dramatic impact on intrinsic charge carrier hopping behavior and will stimulate further improvements in quantum dot device performance.

  13. Accurate modeling of size and strain broadening in the Rietveld refinement: The {open_quotes}double-Voigt{close_quotes} approach

    SciTech Connect

    Balzar, D.; Ledbetter, H.

    1995-12-31

    In the {open_quotes}double-Voigt{close_quotes} approach, an exact Voigt function describes both size- and strain-broadened profiles. The lattice strain is defined in terms of physically credible mean-square strain averaged over a distance in the diffracting domains. Analysis of Fourier coefficients in a harmonic approximation for strain coefficients leads to the Warren-Averbach method for the separation of size and strain contributions to diffraction line broadening. The model is introduced in the Rietveld refinement program in the following way: Line widths are modeled with only four parameters in the isotropic case. Varied parameters are both surface- and volume-weighted domain sizes and root-mean-square strains averaged over two distances. Refined parameters determine the physically broadened Voigt line profile. Instrumental Voigt line profile parameters are added to obtain the observed (Voigt) line profile. To speed computation, the corresponding pseudo-Voigt function is calculated and used as a fitting function in refinement. This approach allows for both fast computer code and accurate modeling in terms of physically identifiable parameters.

  14. Nitrogen-Broadened 13CH_4 at 80 TO 296 K

    NASA Astrophysics Data System (ADS)

    Smith, M. A. H.; Sung, K.; Brown, L. R.; Crawford, T. J.; Mantz, A. W.; Devi, V. Malathy; Benner, D. Chris

    2011-06-01

    High-resolution spectra of the ν_4 fundamental band of 13CH_4 broadened by N_2 at temperatures relevant to the atmosphere of Titan were recorded using temperature-controlled absorption cells installed in the sample compartment of a Bruker IFS-125HR Fourier Transform spectrometer (FTS) at the Jet Propulsion Laboratory (JPL). Analysis of these spectra using multispectrum fitting has determined half widths, pressure-induced shifts, line mixing parameters and their temperature dependences for transitions belonging to a number of P- and R-branch J-manifolds. The analysis examined in detail the temperature-dependence of N_2-broadened half width and pressure-induced shift coefficients over the entire temperature range from 80 K to 296 K. The results are compared with other published measurements of N_2- and air-broadened methane parameters. Research described in this paper was performed at Connecticut College, the College of William and Mary, NASA Langley Research Center and the Jet Propulsion Laboratory, California Institute of Technology, under contracts and cooperative agreements with the National Aeronautics and Space Administration. K. Sung, A. W. Mantz, M. A. H. Smith, L. R. Brown, T. J. Crawford, V. Malathy Devi and D. C. Benner, JMS 262 (2010) 122-134. D. C. Benner, C. P. Rinsland, V. Malathy Devi, M. A. H. Smith and D. A. Atkins, JQSRT 53 (1995) 705-721.

  15. Labeling strategy and signal broadening mechanism of Protein NMR spectroscopy in Xenopus laevis oocytes.

    PubMed

    Ye, Yansheng; Liu, Xiaoli; Chen, Yanhua; Xu, Guohua; Wu, Qiong; Zhang, Zeting; Yao, Chendie; Liu, Maili; Li, Conggang

    2015-06-08

    We used Xenopus laevis oocytes, a paradigm for a variety of biological studies, as a eukaryotic model system for in-cell protein NMR spectroscopy. The small globular protein GB1 was one of the first studied in Xenopus oocytes, but there have been few reports since then of high-resolution spectra in oocytes. The scarcity of data is at least partly due to the lack of good labeling strategies and the paucity of information on resonance broadening mechanisms. Here, we systematically evaluate isotope enrichment and labeling methods in oocytes injected with five different proteins with molecular masses of 6 to 54 kDa. (19) F labeling is more promising than (15) N, (13) C, and (2) H enrichment. We also used (19) F NMR spectroscopy to quantify the contribution of viscosity, weak interactions, and sample inhomogeneity to resonance broadening in cells. We found that the viscosity in oocytes is only about 1.2 times that of water, and that inhomogeneous broadening is a major factor in determining line width in these cells.

  16. Investigation on the influence of spectral linewidth broadening on beam quality in spectral beam combination

    NASA Astrophysics Data System (ADS)

    Tian, Fei; Yan, Hong; Chen, Li; Ye, Yidong; Li, Jianmin; Luo, Jia; Lu, Fei

    2015-02-01

    Spectral beam combination (SBC) is a promising method to combine multiple fiber outputs for further power scaling with the capability of maintaining high beam quality, but the beam quality will be degraded with spectral linewidth broadening, because it could result in additional angular spread in the output beam. In this paper, we described theoretical calculation as well as experimental investigation on the influence of spectral linewidth broadening on beam quality. The results show that in single SBC system the spectral linewidth should be limited to less than a few GHz in order to avoid beam quality degradation, but the linewidth requirement could be decreased to more than hundreds of GHz using a pair of parallel gratings, which reveals a feasible way to increase the stimulated Brillouin scattering (SBS)-free power output of single fiber laser for overall output scaling and high beam quality.

  17. The Occurrence of Additional Giant Planets Inside the Water-Ice Line in Systems with Hot Jupiters: Evidence Against High-Eccentricity Migration

    NASA Astrophysics Data System (ADS)

    Schlaufman, Kevin C.; Winn, Joshua N.

    2016-07-01

    The origin of Jupiter-mass planets with orbital periods of only a few days is still uncertain. It is widely believed that these planets formed near the water-ice line of the protoplanetary disk, and subsequently migrated into much smaller orbits. Most of the proposed migration mechanisms can be classified either as disk-driven migration, or as excitation of a very high eccentricity followed by tidal circularization. In the latter scenario, the giant planet that is destined to become a hot Jupiter spends billions of years on a highly eccentric orbit, with apastron near the water-ice line. Eventually, tidal dissipation at periastron shrinks and circularizes the orbit. If this is correct, then it should be especially rare for hot Jupiters to be accompanied by another giant planet interior to the water-ice line. Using the current sample of giant planets discovered with the Doppler technique, we find that hot Jupiters with P orb < 10 days are no more or less likely to have exterior Jupiter-mass companions than longer-period giant planets with P orb ≥ 10 days. This result holds for exterior companions both inside and outside of the approximate location of the water-ice line. These results are difficult to reconcile with the high-eccentricity migration scenario for hot Jupiter formation.

  18. Pressure broadening and collisional narrowing in OH(v=1 <-- 0) rovibrational transitions with Ar, He, O2, and N2

    NASA Astrophysics Data System (ADS)

    Schiffman, A.; Nesbitt, David J.

    1994-02-01

    Line shapes are measured for OH(v=1←0) transitions in the presence of Ar, He, O2, and N2 as a function of N rotational, spin-orbit, and λ doublet states. Pressure broadening coefficients for all transitions and buffer gases are determined from fits of the observed line shapes to the Voigt profile. The dependencies of the observed broadening coefficients on the OH quantum levels are discussed and compared with previous pressure broadening studies in HF and NO. The observed OH line shapes are interpreted in terms of their impact on the determination of mesospheric and stratospheric OH populations, temperatures, and quantum state distributions from OH nightglow and dayglow emission. In the case of OH+Ar, evidence for Dicke narrowing is presented and narrowing coefficients are reported from fits to a ``hard collision'' model.

  19. Broadening Industry Governance to Include Nonproliferation

    SciTech Connect

    Hund, Gretchen; Seward, Amy M.

    2008-11-11

    As industry is the first line of defense in detecting and thwarting illicit trade networks, the engagement of the private sector is critical to any government effort to strengthen existing mechanisms to protect goods and services throughout the supply chain. This study builds on previous PNNL work to continue to evaluate means for greater industry engagement to complement and strengthen existing governmental efforts to detect and stem the trade of illicit goods and to protect and secure goods that could be used in making a weapon of mass destruction. Specifically, the study evaluates the concept of Industry Self Regulation, defined as a systematic voluntary program undertaken by an industry or by individual companies to anticipate, implement, supplement, or substitute for regulatory requirements in a given field, generally through the adoption of best practices. Through a series of interviews with companies with a past history of non-compliance, trade associations and NGOs, the authors identify gaps in the existing regulatory infrastructure, drivers for a self regulation approach and the form such an approach might take, as well as obstacles to be overcome. The authors conclude that it is at the intersection of industry, government, and security that—through collaborative means—the effectiveness of the international nonproliferation system—can be most effectively strengthened to the mutual benefit of both government and the private sector. Industry has a critical stake in the success of this regime, and has the potential to act as an integrating force that brings together the existing mechanisms of the global nonproliferation regime: export controls, physical protection, and safeguards. The authors conclude that industry compliance is not enough; rather, nonproliferation must become a central tenant of a company’s corporate culture and be viewed as an integral component of corporate social responsibility (CSR).

  20. Decoupling in the line mixing of acetylene infrared Q branches

    NASA Technical Reports Server (NTRS)

    Pine, A. S.; Looney, J. P.

    1990-01-01

    A difference-frequency laser spectrometer was used to record the Q-branch profiles of the nu1 + nu5, nu3 + nu4, and nu2 + 2nu4 + nu5 Pi(u)-Sigma(g) combination bands in the 2.5 micron C-H stretch-bend region of acetylene. The experiment was carried out at pressures in the range of 1 to 500 Torr. It is shown that line mixing causes substantial deviation of collisionally overlapped Q-branch profiles from the independently additive superposition of Lorentzian line shapes. It is also found that the degree of line mixing is greatly reduced from that assuming all the broadening arises from rotationally inelastic collisions coupling Q-branch lines only to one another.

  1. Self- and N2-collisional broadening coefficients of ethylene in the 1800-2350 cm-1 spectral region

    NASA Astrophysics Data System (ADS)

    Hassen, A. Ben; Galalou, S.; Tchana, F. Kwabia; Dhib, M.; Aroui, H.

    2016-08-01

    Self- and N2-broadening coefficients have been retrieved for 566 lines of C2H4 at room temperature in the 5 μm region including the ν7 + ν8, ν4 + ν8, ν6 + ν10, ν6 + ν7, ν4 + ν6 and ν3 + ν10 vibrational bands. Measurements have been performed using Fourier transform infrared spectroscopy. The lines were fitted with a single-spectrum non-linear least squares fitting procedure of Voigt profiles which appeared to properly model the observed molecular line shapes within the noise level. The experimental results are compared with theoretical values calculated using the Robert and Bonamy formalism which reproduces the measured broadening coefficients. For the self- and N2-broadening coefficients, the average discrepancy <(γmea - γcal/γmea) × 100> for 566 lines, is (-1.6 ± 7.8)% and (-2.8 ± 9.9)%, respectively. One standard deviation is given after ±. These coefficients show dependence with both rotational quantum numbers J and Ka. Comparisons with previous measurements taken in the ν7 band of C2H4 show difference range between 7% and 15%. These differences not insignificant can come from inconsistency between experimental measurements.

  2. A Simple Analytical Approximation to an Inhomogeneously-Broadened Dispersion Spectrum. Application to Absorption-Dispersion Admixtures.

    PubMed

    Bales, Barney L

    2016-09-19

    A simple analytical approximation to an inhomogeneously-broadened dispersion signal is proposed and tested with resonance lines broadened by unresolved hyperfine structure. Spectral parameters may be rapidly and accurately extracted using a nonlinear least-squares fitting algorithm. Combining the new approximation to a dispersion signal with a well-known approximation to the absorption signal allows dispersion-absorption admixtures, a problem of growing importance, to be analyzed quickly and accurately. For pure dispersion signals, the maximum difference between the fit and the signal for unresolved lines is 1.1 % of the maximum intensity. For pure absorption, the difference is 0.33 % of the peak-to-peak intensity, and for admixtures up to 40 % dispersion (maximum intensity/peak-to-peak intensity), the difference is 0.7 %. The accuracy of the recovered spectral parameters depends on the degree of inhomogeneously-broadened and the percentage admixture, but they are generally about 1 % at most. A significant finding of the work is that the parameters pertinent to the dispersion or the absorption are insignificantly different when fitting isolated lines vs. fitting admixtures. Admixtures with added noise or an unsuspected extraneous line are investigated.

  3. Longitudinal broadening of quenched jets in turbulent color fields.

    PubMed

    Majumder, A; Müller, B; Bass, S A

    2007-07-27

    The nearside distribution of particles at intermediate transverse momentum, associated with a high momentum trigger hadron produced in a high energy heavy-ion collision, is broadened in rapidity compared with the jet cone. This broadened distribution is thought to contain the energy lost by the progenitor parton of the trigger hadron. We show that the broadening can be explained as the final-state deflection of the gluons radiated from the hard parton inside the medium by soft, transversely oriented, turbulent color fields that arise in the presence of plasma instabilities. The magnitude of the effect is found to grow with medium size and density and diminish with increasing energy of the associated hadron.

  4. Combustion technology overview. [the use of broadened property aircraft fuels

    NASA Technical Reports Server (NTRS)

    Niedzwiecki, R. W.

    1980-01-01

    An overview of combustor technology developments required for use of broadened property fuels in jet aircraft is presented. The intent of current investigations is to determine the extent to which fuel properties can be varied, to obtain a data base of combustion - fuel quality effects, and to determine the trade-offs associated with broadened property fuels. Subcomponents of in-service combustors such as fuel injectors and liners, as well as air distributions and stoichiometry, are being altered to determine the extent to which fuel flexibility can be extended. Finally, very advanced technology consisting of new combustor concepts is being evolved to optimize the fuel flexibility of gas turbine combustors.

  5. Trace Isotope Detection Enhanced by Coherent Elimination of Power Broadening

    SciTech Connect

    Conde, Alvaro Peralta; Brandt, Lukas; Halfmann, Thomas

    2006-12-15

    The selectivity and spectral resolution of traditional laser-based trace isotope analysis, i.e., resonance ionization mass spectrometry (RIMS), is limited by power broadening of the radiative transition. We use the fact that power broadening does not occur in coherently driven quantum systems when the probing and excitation processes are temporally separated to demonstrate significant improvement of trace element detection, even under conditions of strong signals. Specifically, we apply a coherent variant of RIMS to the detection of traces of molecular nitric oxide (NO) isobars. For large laser intensities, the detected isotope signal can be increased by almost 1 order of magnitude without any loss in spectral resolution.

  6. Multigroup Free-atom Doppler-broadening Approximation. Theory

    SciTech Connect

    Gray, Mark Girard

    2015-11-06

    Multigroup cross sections at a one target temperature can be Doppler-broadened to multigroup cross sections at a higher target temperature by matrix multiplication if the group structure suf- ficiently resolves the original temperature continuous energy cross section. Matrix elements are the higher temperature group weighted averages of the integral over the lower temperature group boundaries of the free-atom Doppler-broadening kernel. The results match theory for constant and 1/v multigroup cross sections at 618 lanl group structure resolution.

  7. Trace isotope detection enhanced by coherent elimination of power broadening.

    PubMed

    Conde, Alvaro Peralta; Brandt, Lukas; Halfmann, Thomas

    2006-12-15

    The selectivity and spectral resolution of traditional laser-based trace isotope analysis, i.e., resonance ionization mass spectrometry (RIMS), is limited by power broadening of the radiative transition. We use the fact that power broadening does not occur in coherently driven quantum systems when the probing and excitation processes are temporally separated to demonstrate significant improvement of trace element detection, even under conditions of strong signals. Specifically, we apply a coherent variant of RIMS to the detection of traces of molecular nitric oxide (NO) isobars. For large laser intensities, the detected isotope signal can be increased by almost 1 order of magnitude without any loss in spectral resolution.

  8. Beam broadening in transmission and conventional EBSD.

    PubMed

    Rice, Katherine P; Chen, Yimeng; Keller, Robert R; Stoykovich, Mark P

    2017-04-01

    Transmission electron backscatter diffraction (t-EBSD) has become a routine technique for crystal orientation mapping when ultrahigh resolution is needed and has demonstrated advantages in the characterization of nanoscale and micron-sized samples (Babinsky et al., 2015). In this work, we use experimental measurements and simulations to compare the resolution of the transmission and conventional reflection EBSD techniques across a range of sample volumes and characterization conditions. Monte Carlo simulations of electron trajectories provide the opportunity to estimate beam size and effective resolution, as well as electron flux, as a function of sample thickness or incident beam energy in t-EBSD. Increasing incident beam energy is shown to negatively impact beam diameter in some cases, and the effect of thinning a sample for conventional EBSD is shown to improve characterization resolution but dramatically decrease the number of high-loss electrons backscattered to the detector. In addition to considering spatial resolution when implementing EBSD techniques, it is found that maintaining a high yield of diffracted electrons to the detector is also of critical importance, which is supported by experimental results. Consequently, this work provides key insights into the nature of electron scattering and probe volume for the practical implementation of both transmission and reflection EBSD techniques.

  9. Measurements of Methane at 7.5 μm Broadened by Nitrogen at Low Temperatures

    NASA Astrophysics Data System (ADS)

    Smith, Mary-Ann H.; Mantz, A. W.; Sung, K.; Brown, L. R.; Crawford, T. J.; Malathy Devi, V.; Benner, D. Chris

    2010-10-01

    Since the ν4 band system of methane (CH4) at 7.5 µm appears prominently in infrared spectra of Titan's atmosphere, we are conducting laboratory studies to examine the temperature-dependence of infrared transitions of CH4 broadened by N2 in this spectral region. Spectra of methane-nitrogen mixtures at temperatures from 79 to 297 K were obtained at 0.006 cm-1 resolution (resolving power = 2x105) using the Bruker IFS 125HR Fourier transform spectrometer at the Jet Propulsion Laboratory with new temperature-controlled gas cells designed specifically to fit in the spectrometer's sample compartment. Details of the cells and spectrometer performance [1] are described in an adjacent poster by Sung et al. A multispectrum nonlinear least squares technique [2] is used to fit selected intervals of 9 or more spectra simultaneously to obtain the temperature dependences of line broadening, pressure-induced shift and line mixing parameters. Results for 13CH4 at 80 to 297 K are discussed relative to our previous high-resolution studies of air- and self-broadened 12CH4 and 13CH4 [3-5] at terrestrial atmospheric temperatures (210 to 314 K). This research is supported by NASA's Planetary Atmospheres Program. 1. K. Sung et al., J. Mol. Spectrosc. (2010) doi:10.1016/j.jms.2010.05.004. 2. D. Chris Benner et al., J. Quant. Spectrosc. Radiat. Transfer 53 (1995) 705-721. 3. M. A. H. Smith et al., J. Quant. Spectrosc. Radiat. Transfer 110 (2009) 639-653. 4. M. A. H. Smith et al., J. Quant. Spectrosc. Radiat. Transfer 111 (2010) 1152-1166. 5. M. A. H. Smith et al., J. Quant. Spectrosc. Radiat. Transfer (2010) submitted.

  10. Ten deep blue to cyan emission lines from an intracavity frequency converted Raman laser

    NASA Astrophysics Data System (ADS)

    Geskus, Dimitri; Jakutis-Neto, Jonas; Pask, Helen M.; Wetter, Niklaus U.

    2015-02-01

    Here we report on the generation of ten deep blue to cyan laser emission lines using an intracavity frequency converted Raman laser. The fundamental laser field of the intracavity Raman laser is based on the 3 level transition of a Nd:YLF laser crystal, providing a short wavelength at 903 or 908 nm. When combined with generation of a Stokes shifted field via intracavity stimulated Raman scattering (SRS) by a KGW Raman crystal, enables generation of laser emission in the deep blue to cyan wavelength regime via additional nonlinear frequency conversion. Output at several blue-green wavelengths was achieved, with quasi continuous wave (qcw) output powers of up to 1W. A detailed study of the spectral behavior of the underlying Raman laser processes revealed strong spectral broadening of the fundamental laser line at 908 nm to a width of up to 4 nm. The effect of the spectral broadening on the overall laser efficiency is analyzed.

  11. Communicating Science with Batiks: Broadening the Audience

    NASA Astrophysics Data System (ADS)

    Pilkey, O. H.; Fraser, M. E.

    2012-12-01

    Batik artist Fraser and coastal geologist Pilkey began their collaboration in 1994 at the Smithsonian Air and Space Museum. Since that time they have made over 25 joint presentations and produced 25 educational art exhibitions, some with as many as 60 batiks on silk, each large-scale artwork accompanied by a brief wall description of its geologic significance. Among other venues, the exhibitions have been housed at The National Academy of Sciences, The National Science Foundation, Duke University's Museum of Art, and the North Carolina Museum of Natural Sciences. They were also featured in a National Geographic TV special and have been widely picked up in cyberspace. In addition, the duo has published 2 books. One, A Celebration of the World's Barrier Islands (2003), combines color images with batiks, and the second, Global Climate Change: A Primer (2011), is illustrated exclusively with batiks. The creation of each batik is preceded by a scientist-artist conference wherein they discuss the salient features of the natural system to be depicted. The objective is to show the majesty of selected natural features or processes and at the same time to communicate the science behind them. From the artist's standpoint, this collaboration has given focus and purpose to her art and fulfills her desire to support environmental causes. The science-art alliance has been highly successful in attracting a new audience to the problems facing barrier islands and also to the broader subject of global climate change. A feared backlash from hardnosed science colleagues over "dilution" or "softening" of science has not materialized. A future collaboration with the "American Rivers" society will highlight the problems facing rivers.A batik of an iceberg showing the typical proportion of underwater versus above-water ice volumes.

  12. Thermally insensitive determination of the linewidth broadening factor in nanostructured semiconductor lasers using optical injection locking

    PubMed Central

    Wang, Cheng; Schires, Kevin; Osiński, Marek; Poole, Philip J.; Grillot, Frédéric

    2016-01-01

    In semiconductor lasers, current injection not only provides the optical gain, but also induces variation of the refractive index, as governed by the Kramers-Krönig relation. The linear coupling between the changes of the effective refractive index and the modal gain is described by the linewidth broadening factor, which is responsible for many static and dynamic features of semiconductor lasers. Intensive efforts have been made to characterize this factor in the past three decades. In this paper, we propose a simple, flexible technique for measuring the linewidth broadening factor of semiconductor lasers. It relies on the stable optical injection locking of semiconductor lasers, and the linewidth broadening factor is extracted from the residual side-modes, which are supported by the amplified spontaneous emission. This new technique has great advantages of insensitivity to thermal effects, the bias current, and the choice of injection-locked mode. In addition, it does not require the explicit knowledge of optical injection conditions, including the injection strength and the frequency detuning. The standard deviation of the measurements is less than 15%. PMID:27302301

  13. Thermally insensitive determination of the linewidth broadening factor in nanostructured semiconductor lasers using optical injection locking.

    PubMed

    Wang, Cheng; Schires, Kevin; Osiński, Marek; Poole, Philip J; Grillot, Frédéric

    2016-06-15

    In semiconductor lasers, current injection not only provides the optical gain, but also induces variation of the refractive index, as governed by the Kramers-Krönig relation. The linear coupling between the changes of the effective refractive index and the modal gain is described by the linewidth broadening factor, which is responsible for many static and dynamic features of semiconductor lasers. Intensive efforts have been made to characterize this factor in the past three decades. In this paper, we propose a simple, flexible technique for measuring the linewidth broadening factor of semiconductor lasers. It relies on the stable optical injection locking of semiconductor lasers, and the linewidth broadening factor is extracted from the residual side-modes, which are supported by the amplified spontaneous emission. This new technique has great advantages of insensitivity to thermal effects, the bias current, and the choice of injection-locked mode. In addition, it does not require the explicit knowledge of optical injection conditions, including the injection strength and the frequency detuning. The standard deviation of the measurements is less than 15%.

  14. A Bichromator for High Time Resolution Measurements of Stark Broadened Pellet Ablation Light

    NASA Astrophysics Data System (ADS)

    Schmidt, G. L.; Baylor, L. R.; Fehling, D. T.; Jernigan, T. C.; Brooks, N. H.; Parks, P. B.

    2004-11-01

    Details of the pellet/plasma interaction are important for modeling of local pellet source rates and cross field transport of pellet mass. Understanding these processes is critical for projection of current fueling experiments to future devices such as ITER. Measurement of the Stark broadened deuterium emission lines provides the electron density and temperature of the pellet cloud for comparison with modeling details. Stark broadening measurements on JET for low field launch pellets at moderate time resolution indicate a slow variation in the cloud parameters. Observations of ablation light suggest changes in cloud parameters may occur on faster time scales. We report on the possible application of a multiple interference filter technique[1]to allow monitoring of cloud parameters at time resolution sufficient to study both the slow and rapid variations in cloud parameters. Application of the bichromator to line widths and temporal evolution typical of DIII-D pellet injection cases will be discussed.[1]McNeill,D.H.,RSI 73 (2002) 3193.

  15. Broadening the Horizons: Organizational Communication in the Real World.

    ERIC Educational Resources Information Center

    Swanson, Georgia

    Working in the microcosm of an individual class, organizational communication instructors can broaden the student's horizon by starting with what are local types of diversity and then expanding the classroom understanding to include the larger world where that student is going to live and work. Speech communication teachers/scholars have seen…

  16. Quality's Higher Education Dividends: Broadened Custodianship and Global Public Scholarship

    ERIC Educational Resources Information Center

    Jacobs, Gerrie J.

    2010-01-01

    This paper speculates on the possible contribution of the quality movement to higher education and the perceived dividends received from this, in general, over the past two decades but also, more specifically, with reference to the author's institution in South Africa. The first major quality contribution is a gradual broadening of higher…

  17. Phase dynamics in a Doppler broadened optically-pumped laser

    NASA Astrophysics Data System (ADS)

    Roldán, E.; de Valcárcel, G. J.; Vilaseca, R.; Silva, F.; Pujol, J.; Corbalán, R.; Laguarta, F.

    1989-11-01

    The dynamic behavior of the phase of the generated field in a Doppler-broadened optically-pumped far-infrared laser is theoretically investigated for the first time. The phase undergoes sudden jumps of approximately π radians, which allow to establish the actual symmetry of the main attractor in the phase space, explaining the heteroclynic character of the chaotic behavior observed in experiments.

  18. The STARS Alliance: Viable Strategies for Broadening Participation in Computing

    ERIC Educational Resources Information Center

    Dahlberg, Teresa; Barnes, Tiffany; Buch, Kim; Rorrer, Audrey

    2011-01-01

    The Students and Technology in Academia, Research, and Service (STARS) Alliance is a nationally-connected system of regional partnerships among higher education, K-12 schools, industry and the community with a mission to broaden the participation of women, under-represented minorities and persons with disabilities in computing (BPC). Each regional…

  19. On-The-Fly Neutron Doppler Broadening in MCNP

    NASA Astrophysics Data System (ADS)

    Martin, William R.; Brown, Forrest B.; Wilderman, Scott; Yesilyurt, Gokhan

    2014-06-01

    Multi-physics calculations may involve coupling continuous-energy Monte Carlo neutronics codes to CFD codes that provide many thousands or even millions of region temperatures. The traditional Monte Carlo approach - using precalculated Doppler broadened nuclear cross-sections - is not feasible for these large multiphysics problems. Instead, an On-the-Fly (OTF) Doppler broadening methodology is required, whereby neutron cross-sections are broadened during the Monte Carlo transport. To this end, we have developed a methodology for MCNP to provide OTF broadening based on cell temperatures during neutron tracking. The method enables the use of many thousands or more temperatures in MCNP Monte Carlo calculations for multiphysics applications, significantly advancing the state-of-the-art by permitting the solution of problems that were not previously possible with continuous-energy Monte Carlo codes. A production library with an extended set of isotopes has been developed for use with MCNP6. Calculations of test problems with MCNP6 and the new library demonstrate the accuracy and effectiveness of the OTF approach.

  20. Coincidence doppler broadening study in electron-irradiated polyurethane

    NASA Astrophysics Data System (ADS)

    Yang, D. J.; Zhang, J. D.; Leung, J. K. C.; Beling, C. D.; Liu, L. B.

    2007-06-01

    Coincidence doppler broadening measurements on electron-irradiated polyurethanes were performed in the presence of air. It is shown that, after a certain electron irradiation, the momentum density distributions of annihilation electrons have obvious changes for the high crosslinking polyurethane, but no significant changes have been observed for the low crosslinking polyurethane. The results were performed to analyse by irradiation crosslinking and degradation principles.

  1. Community Colleges Broadening Horizons through Service Learning, 2006-2009

    ERIC Educational Resources Information Center

    Robinson, Gail

    2007-01-01

    This brief introduces "Community Colleges Broadening Horizons through Service Learning," the American Association of Community Colleges' (AACC's) fifth national Learn and Serve America grant project and describes its grantee college programs. The goals of this grant project are to build on established foundations to integrate service…

  2. Relational Themes in Counseling Supervision: Broadening and Narrowing Processes

    ERIC Educational Resources Information Center

    Gazzola, Nicola; Theriault, Anne

    2007-01-01

    This study investigated the experiences of broadening (i.e., thinking and acting creatively and being open to exploring new ways of being) and narrowing (i.e., the experience of perceiving one's choices as limited) in the supervisory process with the aim of identifying key relational themes from the perspective of supervisees. We interviewed 10…

  3. Phenomenological plasmon broadening and relation to the dispersion

    NASA Astrophysics Data System (ADS)

    Hobbiger, Raphael; Drachta, Jürgen T.; Kreil, Dominik; Böhm, Helga M.

    2017-02-01

    Pragmatic ways of including lifetime broadening of collective modes in the electron liquid are critically compared. Special focus lies on the impact of the damping parameter onto the dispersion. It is quantitatively exemplified for the two-dimensional case, for both, the charge ('sheet'-)plasmon and the spin-density plasmon. The predicted deviations fall within the resolution limits of advanced techniques.

  4. Rayleigh-backscattering doppler broadening correction for differential absorption lidar

    NASA Astrophysics Data System (ADS)

    Fan, Lanlan; Zhang, Yinchao; Chen, Siying; Guo, Pan; Chen, He

    2015-11-01

    The spectral broadening by Rayleigh backscattering can cause large changes in water vapor echo signals, causing errors when the water vapor concentration is inversed by differential absorption lidar (DIAL). A correction algorithm is proposed to revise the errors due to the effect of laser spectral broadening. The relative errors of water vapor are calculated in cases of different aerosol distribution and temperature changes before and after correction. The results show that measurement errors due to the Doppler broadening are more than 5% before correction and a 2% measurement error after corrected for the case of a smooth, background aerosol distribution. However, due to the high aerosol gradients and strong temperature inversion, errors can be up to 40% and 10% with no corrections for this effect, respectively. The relative errors can reduce to less than 2% after correction. Hence, the correction algorithm for Rayleigh Doppler broadening can improve detection accuracy in H2O DIAL measurements especially when it is applied to high aerosol concentration or strong temperature inversion.

  5. Broadening horizons: engaging advanced practice nursing students in faculty research.

    PubMed

    Weiss, Josie A

    2009-01-01

    Inviting advanced practice nursing students to participate in faculty research can be an innovative way to interest students in using current evidence as the basis for their practice. The author discusses strategies for effectively engaging graduate nursing students into research projects in ways that broaden the students' perspectives and strengthen their healthcare decision-making skills.

  6. ECRH microwave beam broadening in the edge turbulent plasma

    SciTech Connect

    Sysoeva, E. V.; Gusakov, E. Z.; Popov, A. Yu.; Silva, F. da; Heuraux, S.

    2014-02-12

    The influence of turbulent plasma density fluctuations on angular and spatial beam width is treated analytically in the framework of WKB based eikonal method. Reasonable agreement of analytical and numerical treatment results is demonstrated within the domain of quasi-optical approximation validity. Significant broadening of microwave beams is predicted for future ECRH experiments at ITER.

  7. Introgressing Subgenome Components from Brassica rapa and B. carinata to B. juncea for Broadening Its Genetic Base and Exploring Intersubgenomic Heterosis

    PubMed Central

    Wei, Zili; Wang, Meng; Chang, Shihao; Wu, Chao; Liu, Peifa; Meng, Jinling; Zou, Jun

    2016-01-01

    Brassica juncea (AjAjBjBj), is an allotetraploid that arose from two diploid species, B. rapa (ArAr) and B. nigra (BnBn). It is an old oilseed crop with unique favorable traits, but the genetic improvement on this species is limited. We developed an approach to broaden its genetic base within several generations by intensive selection. The Ar subgenome from the Asian oil crop B. rapa (ArAr) and the Bc subgenome from the African oil crop B. carinata (BcBcCcCc) were combined in a synthesized allohexaploid (ArArBcBcCcCc), which was crossed with traditional B. juncea to generate pentaploid F1 hybrids (ArAjBcBjCc), with subsequent self-pollination to obtain newly synthesized B. juncea (Ar/jAr/jBc/jBc/j). After intensive cytological screening and phenotypic selection of fertility and agronomic traits, a population of new-type B. juncea was obtained and was found to be genetically stable at the F6 generation. The new-type B. juncea possesses good fertility and rich genetic diversity and is distinctly divergent but not isolated from traditional B. juncea, as revealed by population genetic analysis with molecular markers. More than half of its genome was modified, showing exotic introgression and novel variation. In addition to the improvement in some traits of the new-type B. juncea lines, a considerable potential for heterosis was observed in inter-subgenomic hybrids between new-type B. juncea lines and traditional B. juncea accessions. The new-type B. juncea exhibited a stable chromosome number and a novel genome composition through multiple generations, providing insight into how to significantly broaden the genetic base of crops with subgenome introgression from their related species and the potential of exploring inter-subgenomic heterosis for hybrid breeding. PMID:27909440

  8. Evaluation of the Doppler-Broadening of Gamma-Ray Spectra from Neutron Inelastic Scattering on Light Nuclei

    SciTech Connect

    Womble, Phillip C.; Barzilov, Alexander; Novikov, Ivan; Howard, Joseph; Musser, Jason

    2009-03-10

    Neutron-induced gamma-ray reactions are extensively used in the nondestructive analysis of materials and other areas where the information about the chemical composition of a substance is crucial. The common technique to find the intensity of the gamma ray is to fit gamma-ray line shape with an analytical function, for example, a Gaussian. However, the Gaussian fitting may fail if the gamma-ray peak is Doppler-broadened since this leads to the miscalculation of the area of the peak and, therefore, to misidentification of the material. Due to momentum considerations, Doppler-broadening occurs primarily with gamma rays from neutron-induced inelastic scattering reactions with light nuclei. The recoiling nucleus of interest must have excited states whose lifetimes are much smaller than the time of flight in the material. We have examined various light nuclei bombarded by 14 MeV neutrons to predict when the peak shape of a neutron-induced gamma ray emitted from these nuclei will be Doppler-broadened. We have found that nearly all the gamma rays from neutron-induced gamma-ray reactions on light elements (A<20) are Doppler-broadened with only a few exceptions. This means that utilization of resolution curves derived from isotopic sources or thermal neutron capture reactions have little value in the analysis.

  9. Measurements and calculations of Ar-broadening and -shifting parameters of water vapor transitions of ν1+ν2+ν3 band

    NASA Astrophysics Data System (ADS)

    Petrova, T. M.; Solodov, A. M.; Solodov, A. A.; Starikov, V. I.

    2014-11-01

    The water vapor line broadening and shifting for 94 lines in the ν1+ν2+ν3 band induced by argon pressure are measured with Bruker IFS 125 HR FTIR spectrometer. The measurements were performed at room temperature, at the spectral resolution of 0.01 cm-1 and in a wide pressure range of Ar. The calculations of the broadening coefficients γ and δ were performed in the framework of the semi-classical method. The intermolecular potential was taken as the sum of pair potentials which, in turn, were modeled by the Lennard-Jones potentials. Optimal sets of potential parameters given the best discrepancy of measured broadening coefficients are found. The influence of the rotational dependence of an intermolecular potential and its repulsive part on the calculated coefficients γ and δ is discussed.

  10. Effect of photoions on the line shape of the Foerster resonance lines and microwave transitions in cold rubidium Rydberg atoms

    SciTech Connect

    Tretyakov, D. B.; Beterov, I. I.; Entin, V. M.; Yakshina, E. A.; Ryabtsev, I. I.; Dyubko, S. F.; Alekseev, E. A.; Pogrebnyak, N. L.; Bezuglov, N. N.; Arimondo, E.

    2012-01-15

    Experiments are carried out on the spectroscopy of the Foerster resonance lines Rb(37P) + Rb(37P) {yields} Rb(37S) + Rb(38S) and microwave transitions nP {yields} n Prime S, n Prime D between Rydberg states of cold rubidium atoms in a magneto-optical trap (MOT). Under ordinary conditions, all spectra exhibit a linewidth of 2-3 MHz irrespective of the interaction time between atoms or between atoms and microwave radiation, although the limit resonance width should be determined by the inverse interaction time. The analysis of experimental conditions has shown that the main source of line broadening is the inhomogeneous electric field of cold photoions that are generated under the excitation of initial nP Rydberg states by broadband pulsed laser radiation. The application of an additional electric-field pulse that rapidly extracts photoions produced by a laser pulse leads to a considerable narrowing of lines of microwave resonances and the Foerster resonance. Various sources of line broadening in cold Rydberg atoms are analyzed.

  11. First-line therapy in HER2 positive metastatic breast cancer: is the mosaic fully completed or are we missing additional pieces?

    PubMed

    Fabi, Alessandra; Malaguti, Paola; Vari, Sabrina; Cognetti, Francesco

    2016-06-30

    The discovery of human epidermal growth factor receptor 2 (HER2) and its role in the biology of breast cancer and the subsequent development of HER2-targeted therapies, have dramatically improved clinical outcomes for women with early-stage and advanced HER2-positive breast cancer (BC).HER-2 targeted therapies represent a major step forward in achieving the goal of delivering individualized targeted therapy for BC, and trastuzumab was the first anti-HER-2 strategy to be approved for treatment of HER-2 positive BC. This review discusses the treatment of metastatic HER2-positive BC and describes efficacy and safety of novel anti-HER2 target therapies in first-line metastatic settings and the future challenges include refining such treatments, reducing toxicity and simultaneously developing innovative therapies. Furthermore, combinations of trastuzumab and drugs targeting the downstream pathway are described.In the next future will be possible to use an ample armamentarium of combination therapies directed against HER2 and key signaling components integrated in the HER network. This approach will allow clinicians to tailor the management of the individual patient on the basis of tumor- specific biomarker profiles.There is an urgent need for prospective biomarker-driven trials to identify patients for whom targeting is cost-effective.

  12. Impact of H2O broadening effect on atmospheric CO and N2O detection near 4.57 μm

    NASA Astrophysics Data System (ADS)

    Deng, Hao; Sun, Juan; Liu, Ningwu; Wang, Hongliang; Yu, Benli; Li, Jingsong

    2017-01-01

    A tunable quantum cascade laser spectrometer (QCLS) was used to study H2O broadening coefficients for CO and N2O transitions at 4.57 μm region, which contains well-characterized and relatively isolated transitions of appropriate line strengths for sensitive gas detection. The influence of H2O broadening effect on CO R(11) and N2O P(38e) transitions at 2186.639 cm-1 and 2187.099 cm-1, respectively, was detailed investigated. Our measurements indicate that H2O broadening coefficients are 1.8 and 1.9 times higher than the corresponding air-broadening parameters, respectively. Based on the experimental data, our simulation confirmed that the WMS-2f shapes of CO and N2O lines will be significantly affected by variations of the water vapor mixing ratio, while no significant dependence on target concentration, and prove that the difference between air- and H2O-broadenings thus cannot be neglected if one wants to measure gas concentrations in a high humid environment with a sub-percent precision.

  13. Positive emotions and the social broadening effects of Barack Obama.

    PubMed

    Ong, Anthony D; Burrow, Anthony L; Fuller-Rowell, Thomas E

    2012-10-01

    Past experiments have demonstrated that the cognitive broadening produced by positive emotions may extend to social contexts. Building on this evidence, we hypothesized that positive emotions triggered by thinking about Barack Obama may broaden and expand people's sense of self to include others. Results from an expressive-writing study demonstrated that African American college students prompted to write about Obama immediately prior to and after the 2008 presidential election used more plural self-references, fewer other-references, and more social references. Mediation analyses revealed that writing about Obama increased positive emotions, which in turn increased the likelihood that people thought in terms of more-inclusive superordinate categories (we and us rather than they and them). Implications of these findings for the role of positive emotions in perspective-taking and intergroup relations are considered.

  14. Fundamental edge broadening effects during focused electron beam induced nanosynthesis.

    PubMed

    Schmied, Roland; Fowlkes, Jason D; Winkler, Robert; Rack, Phillip D; Plank, Harald

    2015-01-01

    The present study explores lateral broadening effects of 3D structures fabricated through focused electron beam induced deposition using MeCpPt(IV)Me3 precursor. In particular, the scaling behavior of proximity effects as a function of the primary electron energy and the deposit height is investigated through experiments and validated through simulations. Correlated Kelvin force microscopy and conductive atomic force microscopy measurements identified conductive and non-conductive proximity regions. It was determined that the highest primary electron energies enable the highest edge sharpness while lower energies contain a complex convolution of broadening effects. Moreover, it is demonstrated that intermediate energies lead to even more complex proximity effects that significantly reduce lateral edge sharpness and thus should be avoided if desiring high lateral resolution.

  15. Modeling Solvent Broadening on the Vibronic Spectra of a Series of Coumarin Dyes. From Implicit to Explicit Solvent Models.

    PubMed

    Cerezo, Javier; Avila Ferrer, Francisco J; Prampolini, Giacomo; Santoro, Fabrizio

    2015-12-08

    We present a protocol to estimate the solvent-induced broadening of electronic spectra based on a model that explicitly takes into account the environment embedding the solute. Starting from a classical approximation of the solvent contribution to the spectrum, the broadening arises from the spread of the excitation energies due to the fluctuation of the solvent coordinates, and it is represented as a Gaussian line shape that convolutes the vibronic spectrum of the solute. The latter is computed in harmonic approximation at room temperature with a time-dependent approach. The proposed protocol for the computation of spectral broadening exploits molecular dynamics (MD) simulations performed on the solute-solvent system, keeping the solute degrees of freedom frozen, followed by the computation of the excitation properties with a quantum mechanics/molecular mechanics (QM/MM) approach. The factors that might influence each step of the protocol are analyzed in detail, including the selection of the empirical force field (FF) adopted in the MD simulations and the QM/MM partition of the system to compute the excitation energies. The procedure is applied to a family of coumarin dyes, and the results are compared with experiments and with the predictions of a very recent work (Cerezo et al., Phys. Chem. Chem. Phys. 2015, 17, 11401-11411), where an implicit model was adopted for the solvent. The final spectra of the considered coumarins were obtained without including ad hoc phenomenological parameters and indicate that the broadenings computed with explicit and implicit models both follow the experimental trend, increasing as the polarity change from the initial to the final state increases. More in detail, the implicit model provides larger estimations of the broadening that are closer to the experimental evidence, while explicit models appear to better capture relative differences arising from different solvents or different solutes. Possible inaccuracies of the adopted

  16. Observation of Doppler broadening in β -delayed proton- γ decay

    SciTech Connect

    Schwartz, S. B.; Wrede, C.; Bennett, M. B.; Liddick, S. N.; Pérez-Loureiro, D.; Bowe, A.; Chen, A. A.; Chipps, K. A.; Cooper, N.; Irvine, D.; McNeice, E.; Montes, F.; Naqvi, F.; Ortez, R.; Pain, S. D.; Pereira, J.; Prokop, C.; Quaglia, J.; Quinn, S. J.; Sakstrup, J.; Santia, M.; Shanab, S.; Simon, A.; Spyrou, A.; Thiagalingam, E.

    2015-09-14

    Background: The Doppler broadening of gamma-ray peaks is due to nuclear recoil from beta-delayed nucleon emission can be used to measure the energies of the nucleons. This method has never been tested using beta-delayed proton emission or applied to a recoil heavier than A = 10. Purpose: To test and apply this Doppler broadening method using gamma-ray peaks from the P-26(beta p gamma)Al-25 decay sequence. Methods: A fast beam of P-26 was implanted into a planar Ge detector, which was used as a P-26 beta-decay trigger. The SeGA array of high-purity Ge detectors was used to detect gamma rays from the P-26(beta p gamma)Al-25 decay sequence. Results: Radiative Doppler broadening in beta-delayed proton-gamma decay was observed for the first time. Moreover, the Doppler broadening analysis method was verified using the 1613-keV gamma-ray line for which the proton energies were previously known. The 1776-keV gamma ray de-exciting the 2720 keV Al-25 level was observed in P-26(beta p gamma)Al-25 decay for the first time and used to determine that the center-of-mass energy of the proton emission feeding the 2720-keV level is 5.1 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV, corresponding to a Si-26 excitation energy of 13.3 +/- 1.0 (stat.) +/- 0.6 (syst.) MeV for the proton-emitting level. Conclusions: Finally, the Doppler broadening method has been demonstrated to provide practical measurements of the energies for beta-delayed nucleon emissions populating excited states of nuclear recoils at least as heavy as A = 25.

  17. Natural broadening in the quantum emission spectra of higher-dimensional Schwarzschild black holes

    NASA Astrophysics Data System (ADS)

    Hod, Shahar

    2017-01-01

    Following an intriguing heuristic argument of Bekenstein, many researches have suggested during the last four decades that quantized black holes may be characterized by discrete radiation spectra. Bekenstein and Mukhanov (BM) have further argued that the emission spectra of quantized (3 +1 )-dimensional Schwarzschild black holes are expected to be sharp in the sense that the characteristic natural broadening δ ω of the black-hole radiation lines, as deduced from the quantum time-energy uncertainty principle, is expected to be much smaller than the characteristic frequency spacing Δ ω =O (TBH/ℏ) between adjacent black-hole quantum emission lines. It is of considerable physical interest to test the general validity of the interesting conclusion reached by BM regarding the sharpness of the Schwarzschild black-hole quantum radiation spectra. To this end, in the present paper we explore the physical properties of the expected radiation spectra of quantized (D +1 )-dimensional Schwarzschild black holes. In particular, we analyze the functional dependence of the characteristic dimensionless ratio ζ (D )≡δ ω /Δ ω on the number D +1 of spacetime dimensions. Interestingly, it is proved that the dimensionless physical parameter ζ (D ), which characterizes the sharpness of the black-hole quantum emission spectra, is an increasing function of D . In particular, we prove that the quantum emission lines of (D +1 )-dimensional Schwarzschild black holes in the regime D ≳10 are characterized by the dimensionless ratio ζ (D )≳1 and are therefore effectively blended together. The results presented in this paper thus suggest that, even if the underlying energy spectra of quantized (D +1 )-dimensional Schwarzschild black holes are fundamentally discrete, as argued by many authors, the quantum phenomenon of natural broadening is expected to smear the characteristic emission spectra of these higher-dimensional black holes into a continuum.

  18. Spectral broadening of interacting pigments: polarized absorption by photosynthetic proteins.

    PubMed

    Somsen, O J; van Grondelle, R; van Amerongen, H

    1996-10-01

    Excitonic interaction between pigment molecules is largely responsible for the static and dynamic spectroscopic properties of photosynthetic pigment-proteins. This paper provides a new description of its effect on polarized absorption spectroscopy, in particular on circular dichroism (CD). We investigate excitonic spectra of finite width and use "spectral moments" to compare 1) inhomogeneously broadened excitonic spectra, 2) spectra that are (homogeneously broadened by vibrations or electron-phonon interaction, and 3) spectra that are simulated by applying convolution after the interaction has been evaluated. Two cases are distinguished. If the excitonic splitting is smaller than the width of the interacting absorption bands, the broadening of the excitonic spectrum can be approximated by a convolution approach, although a correction is necessary for CD spectra. If the excitonic splitting exceeds the bandwidth, the well-known exchange narrowing occurs. We demonstrate that this is accompanied by redistribution of dipole strength and spectral shifts. The magnitude of a CD spectrum is conveniently expressed by its first spectral moment. As will be shown, this is independent of spectral broadening as well as dispersive shifts induced by pigment-protein interactions. Consequently, it provides a simple tool to relate the experimental CD spectrum of a pigment complex to the excitonic interactions from which it originates. To illustrate the potential of the presented framework, the spectroscopy of the LH2 pigment-protein complex from purple bacteria is analyzed and compared for dimer-like and ring-like structures. Furthermore, it is demonstrated that the variability of the CD of chlorosomes from green bacteria can be explained by small changes in the structure of their cylindrical bacteriochlorophyll c subunits.

  19. Inhomogeneous broadening effects in multimode CW chemical lasers

    NASA Astrophysics Data System (ADS)

    Mirels, H.

    1981-01-01

    The performance of a multiple longitudinal mode CW chemical laser is investigated with reference to the effects of inhomogeneous broadening for the case where the longitudinal mode spacing is small compared with the characteristic Doppler and homogeneous widths of the lasing medium. Both a Fabry-Perot resonator and a saturated amplifier are considered, using a two-vibrational-level model. Closed form solutions are obtained which are shown to be in good agreement with the numerical results of Bullock and Lipkis (1979).

  20. Time sequence spectroscopy of AW UMa. The 518 nm Mg I triplet region analyzed with broadening functions

    SciTech Connect

    Rucinski, Slavek M.

    2015-02-01

    High-resolution spectroscopic observations of AW UMa, obtained on three consecutive nights with a median time resolution of 2.1 minutes, have been analyzed using the broadening function method in the spectral window of 22.75 nm around the 518 nm Mg i triplet region. Doppler images of the system reveal the presence of vigorous mass motions within the binary system; their presence puts into question the solid-body rotation assumption of the contact binary model. AW UMa appears to be a very tight, semi-detached binary; the mass transfer takes place from the more massive to the less massive component. The primary, a fast-rotating star with Vsini=181.4±2.5 km s{sup −1}, is covered with inhomogeneities: very slowly drifting spots and a dense network of ripples more closely participating in its rotation. The spectral lines of the primary show an additional broadening component (called the “pedestal”) that originates either in the equatorial regions, which rotate faster than the rest of the star by about 50 km s{sup −1}, or in an external disk-like structure. The secondary component appears to be smaller than predicted by the contact model. The radial velocity field around the secondary is dominated by accretion of matter transferred from (and possibly partly returned to) the primary component. The parameters of the binary are Asini=2.73±0.11 R{sub ⊙} and M{sub 1}sin{sup 3}i=1.29±0.15 M{sub ⊙}, M{sub 2}sin{sup 3}i=0.128±0.016 M{sub ⊙}. The mass ratio, q{sub sp}=M{sub 2}/M{sub 1}=0.099±0.003, while still the most uncertain among the spectroscopic elements, is substantially different from the previous numerous and mutually consistent photometric investigations which were based on the contact model. It should be studied why photometry and spectroscopy give such discrepant results and whether AW UMa is an unusual object or if only very high-quality spectroscopy can reveal the true nature of W UMa-type binaries.

  1. Measurements of air-broadened and nitrogen-broadened Lorentz width coefficients and pressure shift coefficients in the nu4 and nu2 bands of C-12H4

    NASA Technical Reports Server (NTRS)

    Rinsland, Curtis P.; Smith, Mary Ann H.; Devi, V. Malathy; Benner, D. Chris

    1988-01-01

    Air-broadened and N2-broadened halfwidth and pressure shift coefficients of 294 transitions in the nu4 and nu2 bands of C-12H4 have been measured from laboratory absorption spectra recorded at room temperature with the Fourier transform spectrometer in the McMath solar telescope facility of the National Solar Observatory. Total pressures of up to 551 Torr were employed with absorption paths of 5-150 cm, CH4 volume mixing ratios of 2.6 percent or less, and resolutions of 0.005 and 0.01/cm. A nonlinear least-squares spectral fitting technique has been utilized in the analysis of the twenty-five measured spectra. Lines up to J double-prime = 18 in the nu4 band and J double-prime = 15 in the nu2 band have been analyzed.

  2. Search for Magnetically Broadened Cascade Emission from Blazars with VERITAS

    NASA Astrophysics Data System (ADS)

    Archambault, S.; Archer, A.; Benbow, W.; Buchovecky, M.; Bugaev, V.; Cerruti, M.; Connolly, M. P.; Cui, W.; Falcone, A.; Fernández Alonso, M.; Finley, J. P.; Fleischhack, H.; Fortson, L.; Furniss, A.; Griffin, S.; Hütten, M.; Hervet, O.; Holder, J.; Humensky, T. B.; Johnson, C. A.; Kaaret, P.; Kar, P.; Kieda, D.; Krause, M.; Krennrich, F.; Lang, M. J.; Lin, T. T. Y.; Maier, G.; McArthur, S.; Moriarty, P.; Nieto, D.; O’Brien, S.; Ong, R. A.; Otte, A. N.; Pohl, M.; Popkow, A.; Pueschel, E.; Quinn, J.; Ragan, K.; Reynolds, P. T.; Richards, G. T.; Roache, E.; Rovero, A. C.; Sadeh, I.; Shahinyan, K.; Staszak, D.; Telezhinsky, I.; Tyler, J.; Wakely, S. P.; Weinstein, A.; Weisgarber, T.; Wilcox, P.; Wilhelm, A.; Williams, D. A.; Zitzer, B.

    2017-02-01

    We present a search for magnetically broadened gamma-ray emission around active galactic nuclei (AGNs), using VERITAS observations of seven hard-spectrum blazars. A cascade process occurs when multi-TeV gamma-rays from an AGN interact with extragalactic background light (EBL) photons to produce electron–positron pairs, which then interact with cosmic microwave background photons via inverse-Compton scattering to produce gamma-rays. Due to the deflection of the electron–positron pairs, a non-zero intergalactic magnetic field (IGMF) would potentially produce detectable effects on the angular distribution of the cascade emission. In particular, an angular broadening compared to the unscattered emission could occur. Through non-detection of angularly broadened emission from 1ES 1218+304, the source with the largest predicted cascade fraction, we exclude a range of IGMF strengths around 10‑14 G at the 95% confidence level. The extent of the exclusion range varies with the assumptions made about the intrinsic spectrum of 1ES 1218+304 and the EBL model used in the simulation of the cascade process. All of the sources are used to set limits on the flux due to extended emission.

  3. Microstructure Evaluation of Fe-BASED Amorphous Alloys Investigated by Doppler Broadening Positron Annihilation Technique

    NASA Astrophysics Data System (ADS)

    Lu, Wei; Huang, Ping; Wang, Yuxin; Yan, Biao

    2013-07-01

    Microstructure of Fe-based amorphous and nanocrystalline soft magnetic alloy has been investigated by X-ray diffraction (XRD), transmission electronic microscopy (TEM) and Doppler broadening positron annihilation technique (PAT). Doppler broadening measurement reveals that amorphous alloys (Finemet, Type I) which can form a nanocrystalline phase have more defects (free volume) than alloys (Metglas, Type II) which cannot form this microstructure. XRD and TEM characterization indicates that the nanocrystallization of amorphous Finemet alloy occurs at 460°C, where nanocrystallites of α-Fe with an average grain size of a few nanometers are formed in an amorphous matrix. With increasing annealing temperature up to 500°C, the average grain size increases up to around 12 nm. During the annealing of Finemet alloy, it has been demonstrated that positron annihilates in quenched-in defect, crystalline nanophase and amorphous-nanocrystalline interfaces. The change of line shape parameter S with annealing temperature in Finemet alloy is mainly due to the structural relaxation, the pre-nucleation of Cu nucleus and the nanocrystallization of α-Fe(Si) phase during annealing. This study throws new insights into positron behavior in the nanocrystallization of metallic glasses, especially in the presence of single or multiple nanophases embedded in the amorphous matrix.

  4. Direct comparison between genomic constitution and flavonoid contents in Allium multiple alien addition lines reveals chromosomal locations of genes related to biosynthesis from dihydrokaempferol to quercetin glucosides in scaly leaf of shallot (Allium cepa L.).

    PubMed

    Masuzaki, S; Shigyo, M; Yamauchi, N

    2006-02-01

    The extrachromosome 5A of shallot (Allium cepa L., genomes AA) has an important role in flavonoid biosynthesis in the scaly leaf of Allium fistulosum-shallot monosomic addition lines (FF+nA). This study deals with the production and biochemical characterisation of A. fistulosum-shallot multiple alien addition lines carrying at least 5A to determine the chromosomal locations of genes for quercetin formation. The multiple alien additions were selected from the crossing between allotriploid FFA (female symbol) and A. fistulosum (male symbol). The 113 plants obtained from this cross were analysed by a chromosome 5A-specific PGI isozyme marker of shallot. Thirty plants were preliminarily selected for an alien addition carrying 5A. The chromosome numbers of the 30 plants varied from 18 to 23. The other extrachromosomes in 19 plants were completely identified by using seven other chromosome markers of shallot. High-performance liquid chromatography analyses of the 19 multiple additions were conducted to identify the flavonoid compounds produced in the scaly leaves. Direct comparisons between the chromosomal constitution and the flavonoid contents of the multiple alien additions revealed that a flavonoid 3'-hydroxylase (F3'H) gene for the synthesis of quercetin from kaempferol was located on 7A and that an anonymous gene involved in the glucosidation of quercetin was on 3A or 4A. As a result of supplemental SCAR analyses by using genomic DNAs from two complete sets of A. fistulosum-shallot monosomic additions, we have assigned F3'H to 7A and flavonol synthase to 4A.

  5. Stark broadening measurement of the electron density in an atmospheric pressure argon plasma jet with double-power electrodes

    SciTech Connect

    Qian Muyang; Ren Chunsheng; Wang Dezhen; Zhang Jialiang; Wei Guodong

    2010-03-15

    Characteristics of a double-power electrode dielectric barrier discharge of an argon plasma jet generated at the atmospheric pressure are investigated in this paper. Time-averaged optical emission spectroscopy is used to measure the plasma parameters, of which the excitation electron temperature is determined by the Boltzmann's plot method whereas the gas temperature is estimated using a fiber thermometer. Furthermore, the Stark broadening of the hydrogen Balmer H{sub {beta}} line is applied to measure the electron density, and the simultaneous presence of comparable Doppler, van der Waals, and instrumental broadenings is discussed. Besides, properties of the jet discharge are also studied by electrical diagnosis. It has been found that the electron densities in this argon plasma jet are on the order of 10{sup 14} cm{sup -3}, and the excitation temperature, gas temperature, and electron density increase with the applied voltage. On the other hand, these parameters are inversely proportional to the argon gas flow rate.

  6. Addition of long-acting beta2-agonists to inhaled steroids as first line therapy for persistent asthma in steroid-naive adults and children

    PubMed Central

    Ni Chroinin, Muireann; Greenstone, Ilana; Lasserson, Toby J; Ducharme, Francine M

    2014-01-01

    Background Consensus statements recommend the addition of long-acting inhaled ß2-agonists (LABA) only in asthmatic patients who are inadequately controlled on inhaled corticosteroids (ICS). It is not uncommon for some patients to be commenced on ICS and LABA together as initial therapy. Objectives To compare the efficacy of combining inhaled corticosteroids with long-acting ß2-agonists (ICS+LABA) with inhaled corticosteroids alone (ICS alone) in steroid-naive children and adults with persistent asthma. We assessed two protocols: (1) LABA + ICS versus a similar dose of ICS (comparison 1) and (2) LABA + ICS versus a higher dose of ICS (comparison 2). Search methods We identified randomised controlled trials through electronic database searches (May 2008). Selection criteria Randomised trials comparing ICS + LABA with ICS alone in children and adults with asthma who had no inhaled corticosteroids in the preceding 28 days prior to enrolment. Data collection and analysis Each author assessed studies independently for risk of bias and extracted data. We obtained confirmation from the trialists when possible. The primary endpoint was rate of patients with one or more asthma exacerbations requiring rescue systemic corticosteroids. Results are expressed as relative risks (RR) for dichotomous data and as mean differences (MD) or standardised mean differences (SMD) for continuous data. Main results Twenty-eight study comparisons drawn from 27 trials (22 adult; five paediatric) met the review entry criteria (8050 participants). Baseline data from the studies indicated that trial populations had moderate or mild airway obstruction (FEV1 65% predicted), and that they were symptomatic prior to randomisation. In comparison 1, the combination of ICS and LABA was not associated with a significantly lower risk of patients with exacerbations requiring oral corticosteroids (RR 1.04; 95% confidence interval (CI) 0.73 to 1.47) or requiring hospital admissions (RR 0.38; 95% CI 0.09 to 1

  7. Measurements of the CO_2 15 μm Band System Broadened by Air, N_2 and CO_2 at Terrestrial Atmospheric Temperatures

    NASA Astrophysics Data System (ADS)

    Smith, M. A. H.; Devi, V. Malathy; Benner, D. Chris; Blake, T. A.; Sams, R. L.

    2009-06-01

    In earth remote sensing, retrievals of atmospheric temperature profiles are often based on observed radiances in infrared spectral regions where emission from atmospheric CO_2 predominates. To achieve improved retrieval accuracy, systematic errors in the forward model must be reduced, especially those associated with errors in the spectroscopic line calculation. We have recorded more than 110 new high-resolution infrared spectra of the 15-μm band system of CO_2 to accurately determine line intensities, self-, air- and N_2-broadened widths and pressure-induced line shifts, along with their temperature dependences. The spectra were recorded with the Bruker IFS 120 HR Fourier transform spectrometer at Pacific Northwest National Laboratory (PNNL) and temperature-controlled sample cells. Sample temperatures were between 206K and 298K. Maximum total pressures were 15 Torr for self-broadening and 613 Torr for air- and N_2-broadening. Analysis is done using a multispectrum fitting technique to retrieve the spectroscopic parameters. Line mixing and other non-Lorentz, non-Voigt line shapes are also assessed. The resulting line parameters are compared with the HITRAN database and with other measurements. D. Chris Benner, C.P. Rinsland, V. Malathy Devi, M.A.H. Smith, and D. Atkins, J. Quant. Spectrosc. Radiat. Transfer 53, 705-721 (1995) L.S. Rothman et al., J. Quant. Spectrosc. Radiat. Transfer 96, 139-204 (2005) L.S. Rothman et al., J. Quant. Spectrosc. Radiat. Transfer, in press (2009)

  8. Collision broadening effect upon tropospheric temperature calibration functions for pure rotational Raman lidars

    NASA Astrophysics Data System (ADS)

    Gerasimov, V. V.; Zuev, V. V.; Pravdin, V. L.; Nakhtigalova, D. P.; Pavlinskiy, A. V.

    2015-11-01

    We present the general calibration function for temperature retrievals in the cloud-free troposphere using pure rotational Raman (PRR) lidars under the condition of the laser-beam receiver-field-of-view complete overlap. The function is derived within the framework of the semiclassical theory and takes account of the broadened by collision effects elastic backscattered signal leakage into the nearest (to the laser line) lidar PRR channel. The two simplest nonlinear special cases of the general calibration function are considered to be applied in the temperature retrieval algorithm. The vertical temperature profiles retrieved from nighttime lidar measurements in Tomsk (56.48°N, 85.05°E), on October 2, 2014, are given as an example. The measurements were performed using a PRR lidar designed in Institute of Monitoring of Climatic and Ecological Systems of the Siberian Branch of the Russian Academy of Sciences (IMCES SB RAS) for lower-atmosphere temperature-profile retrievals.

  9. Self-, Nitrogen-, and Oxygen-Broadening Coefficient Measurements in the ν 1 Band of H 2O Using a Difference Frequency Generation Spectrometer at 3 μm

    NASA Astrophysics Data System (ADS)

    Bruno, A.; Pesce, G.; Rusciano, G.; Sasso, A.

    2002-10-01

    In this paper we investigate the mid-infrared spectrum of the H 216O molecule between 3367 and 3447 cm -1 to study the gas-collision-broadened linewidths. The coherent radiation used in this experiment is produced through difference frequency generation in a periodically poled lithium niobate crystal. The spectroscopic analysis has concerned nine H 2O lines in the ν 1 fundamental vibrational band. For these lines the self-, N 2-, and O 2-broadening coefficients are measured at room temperature. From these data, the widths due to air broadening are also determined. The experimental collisional broadening coefficients are compared with other experimental data and with theoretical calculations based on the Anderson-Tsao-Cornutte and Robert-Bonamy theories. Lineshape analysis is performed using both the standard Voigt profile and the Nelkin-Ghatak profile for the hard collision regime. For all the investigated lines the agreement between the Voigt profile and the measured profiles is found to be good.

  10. Effects of velocity averaging on the shapes of absorption lines

    NASA Technical Reports Server (NTRS)

    Pickett, H. M.

    1980-01-01

    The velocity averaging of collision cross sections produces non-Lorentz line shapes, even at densities where Doppler broadening is not apparent. The magnitude of the effects will be described using a model in which the collision broadening depends on a simple velocity power law. The effect of the modified profile on experimental measures of linewidth, shift and amplitude will be examined and an improved approximate line shape will be derived.

  11. Semi-classical calculations of self-broadening coefficients of OCS and HCN at temperatures between 200 K and 298 K.

    PubMed

    Jellali, C; Galalou, S; Cuisset, A; Dhib, M; Aroui, H

    2016-11-01

    For some temperatures of atmospheric interest from 200 to 298 K, the self-broadening coefficients of OCS-OCS and HCN-HCN collisional systems, at different strengths of electrostatic interactions, were calculated respectively for ν1 and ν2 bands for a wide range of rotational quantum numbers J. In particular, we have considered some lines that were not studied previously. We have employed the approximation of bi-resonance functions (Starikov, 2012) in the frame of the semiclassical model of Robert and Bonamy with exact trajectory (RBE). The calculated results are found to be fully consistent with the available experimental values of self-broadening coefficients of OCS and HCN. A comparative study shows that the RBE calculations reproduce the dependence of broadening coefficients on quantum number J much better than the simpler Robert and Bonamy model with parabolic trajectory (RB) for all considered temperatures.

  12. Semi-classical calculations of self-broadening coefficients of OCS and HCN at temperatures between 200 K and 298 K

    NASA Astrophysics Data System (ADS)

    Jellali, C.; Galalou, S.; Cuisset, A.; Dhib, M.; Aroui, H.

    2016-11-01

    For some temperatures of atmospheric interest from 200 to 298 K, the self-broadening coefficients of OCS-OCS and HCN-HCN collisional systems, at different strengths of electrostatic interactions, were calculated respectively for ν1 and ν2 bands for a wide range of rotational quantum numbers J. In particular, we have considered some lines that were not studied previously. We have employed the approximation of bi-resonance functions (Starikov, 2012) in the frame of the semiclassical model of Robert and Bonamy with exact trajectory (RBE). The calculated results are found to be fully consistent with the available experimental values of self-broadening coefficients of OCS and HCN. A comparative study shows that the RBE calculations reproduce the dependence of broadening coefficients on quantum number J much better than the simpler Robert and Bonamy model with parabolic trajectory (RB) for all considered temperatures.

  13. Numerical computation of doppler-broadening in the resonance domain

    SciTech Connect

    Sanchez, R.

    2013-07-01

    We have implemented an accurate and fast calculation of the Doppler-broadened kernel PT(E {yields} E') for neutron elastic scattering based on a gas model. An exponential cutoff which accounts for the asymptotic behavior of the error function helps limit the range of integration while eliminating difference effects. This allows for calculating a kernel library for {sup 238}U over a very fine energy grid covering the resonance range in only a few hours in a laptop. We give an example showing the impact of {sup 238}U elastic up-scattering on the values of self shielded cross sections. (authors)

  14. Fatigue damage in superalloys determined using Doppler broadening positron annihilation

    NASA Technical Reports Server (NTRS)

    Hoeckelman, Donald; Leighly, H. P., Jr.

    1990-01-01

    Axial fatigue specimens of three superalloys, Inconel 718, Incoloy 903 and Haynes 188, were machined from solution-heat-treated material and artificially aged. They were subjected to cyclic loading for a selected number of cycles after which the S parameter was determined using Doppler broadening positron annihilation. Initially, the S parameter decreased, followed by a large increase and a subsequent decline leading to fracture. This has been interpreted as the removal of residual vacancies, the introduction of new defects by cyclic loading, and, finally, a clustering of the defects as microcracks which grow to cause failure.

  15. Strategies for broadening public involvement in space developments

    NASA Technical Reports Server (NTRS)

    Harris, Philip R.

    1992-01-01

    There is widespread public interest in and goodwill toward the space program. For NASA's plans for the next 25 years to be achieved, this public reservoir of support needs to be tapped and channeled. NASA endeavors have to reach out beyond the scientific, technological, and aerospace communities to foster wider participation in space exploration and exploitation. To broaden NASA support and spread out the financing of space activities, recommendations for consideration are offered in the area of economics, political, institutional, international, and managerial areas.

  16. Commercial observation satellites: broadening the sources of geospatial data

    NASA Astrophysics Data System (ADS)

    Baker, John C.; O'Connell, Kevin M.; Venzor, Jose A.

    2002-09-01

    Commercial observation satellites promise to broaden substantially the sources of imagery data available to potential users of geospatial data and related information products. We examine the new trend toward private firms acquiring and operating high-resolution imagery satellites. These commercial observation satellites build on the substantial experience in Earth observation operations provided by government-owned imaging satellites for civilian and military purposes. However, commercial satellites will require governments and companies to reconcile public and private interests in allowing broad public access to high-resolution satellite imagery data without creating national security risks or placing the private firms at a disadvantage compared with other providers of geospatial data.

  17. Anomalous excitation facilitation in inhomogeneously broadened Rydberg gases

    NASA Astrophysics Data System (ADS)

    Letscher, F.; Thomas, O.; Niederprüm, T.; Ott, H.; Fleischhauer, M.

    2017-02-01

    When atomic gases are laser driven to Rydberg states in an off-resonant way, a single Rydberg atom may enhance the excitation rate of surrounding atoms. This leads to a facilitated excitation referred to as Rydberg antiblockade. In the usual facilitation scenario, the detuning of the laser from resonance compensates the interaction shift. Here, we discuss a different excitation mechanism, which we call anomalous facilitation. This occurs on the "wrong side" of the resonance and originates from inhomogeneous broadening. The anomalous facilitation may be seen in experiments of attractively interacting atoms on the blue detuned side, where facilitation is not expected to appear.

  18. Broadening the potential bandwidth of piezoelectric transducers by partial depolarization

    SciTech Connect

    Hariti, Sid Ahmed; Hole, Stephane; Lewiner, Jacques

    2001-06-18

    Elastic waves are used more and more in a nondestructive way to probe the physical properties of materials. The resolution of the images or the accuracy of the measurements is directly associated with the ultrasonic signal bandwidth and amplitude a system can generate or detect. The authors propose a technique to broaden the potential bandwidth of piezoelectric generators and sensors, which is based on utilizing a nonuniformly-polarized piezoelectric material. Both simulated and experimental responses are shown. They are in good agreement and exhibit a useful bandwidth over several natural harmonics of the piezoelectric transducer. {copyright} 2001 American Institute of Physics.

  19. Effects of inhomogeneous broadening on the resonance Raman excitation profile of lycopene

    NASA Astrophysics Data System (ADS)

    Cotting, J. E.; Hoskins, L. C.; Levan, M. E.

    1982-08-01

    The resonance Raman excitation profiles for the ν1, ν2, and ν3 vibrations of lycopene in ethyl alcohol, toluene, and carbon disulfide solvents have been measured. The results are interpreted in terms of a three-mode vibrational theory which includes both homogeneous and inhomogeneous broadening effects. Excellent agreement between calculated and observed excitation profiles and visible spectra was found, thus emphasizing the need to interpret resonance Raman data using a multimode vibrational model. The results indicate that the major broadening mechanism is homogeneous broadening, with about a 25% contribution from inhomogeneous broadening. The excitation profiles in carbon disulfide gave the largest inhomogeneous broadening.

  20. Linking the thermodynamic temperature to an optical frequency: recent advances in Doppler broadening thermometry.

    PubMed

    Gianfrani, Livio

    2016-03-28

    Laser spectroscopy in the linear regime of radiation-matter interaction is a powerful tool for measuring thermodynamic quantities in a gas at thermodynamic equilibrium. In particular, the Doppler effect can be considered a gift of nature, linking the thermal energy to an optical frequency, namely the line centre frequency of an atomic or molecular spectral line. This is the basis of a relatively new method of primary gas thermometry, known as Doppler broadening thermometry (DBT). This paper reports on the efforts that have been carried out, in the last decade, worldwide, to the end of making DBT competitive with more consolidated and accurate methodologies, such as acoustic gas thermometry and dielectric constant gas thermometry. The main requirements for low-uncertainty DBT, of both theoretical and technical nature, will be discussed, with a special focus on those related to the line shape model and to the frequency scale. A deep comparison among the different molecules that have been selected in successful DBT implementations is also reported. Finally, for the first time, to the best of my knowledge, the influence of refractive index effects is discussed.

  1. Linking the thermodynamic temperature to an optical frequency: recent advances in Doppler broadening thermometry

    PubMed Central

    2016-01-01

    Laser spectroscopy in the linear regime of radiation–matter interaction is a powerful tool for measuring thermodynamic quantities in a gas at thermodynamic equilibrium. In particular, the Doppler effect can be considered a gift of nature, linking the thermal energy to an optical frequency, namely the line centre frequency of an atomic or molecular spectral line. This is the basis of a relatively new method of primary gas thermometry, known as Doppler broadening thermometry (DBT). This paper reports on the efforts that have been carried out, in the last decade, worldwide, to the end of making DBT competitive with more consolidated and accurate methodologies, such as acoustic gas thermometry and dielectric constant gas thermometry. The main requirements for low-uncertainty DBT, of both theoretical and technical nature, will be discussed, with a special focus on those related to the line shape model and to the frequency scale. A deep comparison among the different molecules that have been selected in successful DBT implementations is also reported. Finally, for the first time, to the best of my knowledge, the influence of refractive index effects is discussed. PMID:26903093

  2. Cross Functional Career Navigation: The Way to Broaden Your Career Options

    NASA Astrophysics Data System (ADS)

    Greenhalgh, Todd

    2000-03-01

    In today's rapid paced global environment, broadening career options for career development depends on successful cross-functional career navigation. For scientists and engineers, this means developing a diversity of skills in addition to a strong technical foundation. Fortunately, companies use cross-functional teams as one of the key tools for rapidly developing and commercializing products and services. Participation on these teams carries with it the additional benefit of allowing an individual to develop new skills, and to gain valuable expertise in areas that are critical to the growth of their company, their industry and, most importantly, their career. This talk will outline some of the important cross functional skills that can propel your career ahead and ways in which you can take charge of your career mapping and enhance your value and employability.

  3. Measurements of Lorentz air-broadening coefficients and relative intensities in the H2O-16 pure rotational and nu2 bands from long horizontal path atmospheric spectra

    NASA Technical Reports Server (NTRS)

    Rinsland, Curtis P.; Smith, Mary Ann H.; Goldman, Aaron; Malathy Devi, V.

    1991-01-01

    Lorentz air-broadening coefficients and relative intensities have been measured for forty-three lines in the pure rotational band and twenty lines in the nu2 band of H2O-16 between 800 and 1150/cm. The results were derived from analysis of nine 0.017/cm-resolution atmospheric absorption spectra recorded over horizontal paths of 0.5-1.5 km with the McMath Fourier transform spectrometer and main solar telescope operated on Kitt Peak by the National Solar Observatory. A nonlinear least-squares spectral fitting technique was used in the spectral analysis. The results are compared with previous measurements and calculations. In most cases, the measured pressure-broadening coefficients and intensities are significantly different from the values in the 1986 HITRAN line parameters compilation.

  4. Influence of disordered cover on cascade mechanism of medium response spectrum broadening at THz-TDS of substance

    NASA Astrophysics Data System (ADS)

    Trofimov, Vyacheslav A.; Zagursky, Dmitry Yu.; Zakharova, Irina G.

    2016-09-01

    Remote sensing using the pulsed THz-TDS is of great interest because of its possible practical applications. Many ordinary materials (paper, for example) are transparent to THz radiation while the hazardous substances, which have to detect, possess fingerprints in this frequency range. However, covers of ordinary material can distort its spectrum in such a way that the spectrum of reflected THz pulse or transmitted THz pulse will contain absorption frequencies, which are inherent to dangerous substance (explosives, illistic drugs....), despite their absence in the material under consideration. On the other hand, it is well-known that the spectrum of medium response under the action of THz pulse is broader than the incident THz pulse spectrum. This is a result of a possibility of high energy level excitation due to cascade mechanism of their excitation. For practical point of view, it is very important to know about features of a covering substance influence on the medium response spectrum broadening. This problem is investigated in our report using the computer simulation. We carry out computer simulation of a few-cycle electromagnetic pulse interaction with a substance exhibiting nonlinear non-instantaneous response. An influence of the pulse duration and polarization relaxation rate on the pulse interaction with an uncovered medium and with a medium, which is covered by a linear disordered structure, is investigated. We demonstrate that the spectra of reflected or transmitted pulses may comprise multiple additional spectral lines, caused by various transitions between energy levels of molecules. The spectral intensity of these energy level transitions is affected by the pulse duration and the effective time of interaction which depends on polarization relaxation rate as well as the medium layer thickness.

  5. Improving Program Design and Assessment with Broadening Participation Resources

    NASA Astrophysics Data System (ADS)

    Siegfried, D.; Johnson, A.; Thomas, S. H.; Fauver, A.; Detrick, L.

    2012-12-01

    Many theoretical and research-based approaches suggest how to best use mentoring to enhance an undergraduate research program. The Institute for Broadening Participation's Pathways to Engineering and Pathways to Ocean Sciences projects synthesized a set of mentoring studies, theoretical sources, and other texts pertinent to undergraduate research program design into a suite of practical tools that includes an online mentoring manual, an online reference library of mentoring and diversity literature, and practical guides such as Using Social Media to Build Diversity in Your REU. The overall goal is to provide easy-to-access resources that can assist faculty and program directors in implementing or honing the mentoring elements in their research programs for undergraduates. IBP's Online Mentoring Manual addresses common themes, such as modeling, student self-efficacy, career development, retention and evaluation. The Online Diversity Reference Library provides a comprehensive, annotated selection of key policy documents, research studies, intervention studies, and other texts on broadening participation in science, technology, engineering and mathematics. IBP's suite of tools provides the theoretical underpinnings and research findings that can help leaders in education integrate site-appropriate mentoring elements into their educational programs. Program directors and faculty from a variety of program types and disciplines have benefitted from using the Manual and other resources. IBP continues the work of translating and synthesizing theory to practice and welcomes your participation and partnership in that effort.

  6. Rotational relaxation contributions to infrared pressure broadening in ozone

    NASA Technical Reports Server (NTRS)

    Flannery, C.; Mizugai, Y.; Steinfeld, J. I.; Spencer, M. N.

    1990-01-01

    The time-resolved IR double-resonance spectroscopy apparatus and procedures described by Millot et al. (1988) are used to measure the relaxation times of rotational levels in the v3 =1 state of O3. Findings reported include (1) total rotational cross sections about 20-70 percent larger than the Lennard-Jones collision cross section, consistent with an interaction dominated by dipole-dipole forces; (2) equal relaxation cross sections in the upper and lower vibrational states; (3) an estimated pressure-broadening cross section of 185 sq A, with less than 10 percent due to dephasing; (4) no strong Ka dependence of rotational relaxation rates at Ka = 4-8 in J of about 16; (5) a rate for J = 8 and Ka = 7 about 40 percent larger than the other values measured, in agreement with the pressure-broadening model of Gamache and Rothman (1985); and (6) a V-V energy-transfer rate between v3 = 1 and v1 = 1 of (2.5 + or - 0.5) x 10 to the 6th/torr sec.

  7. Momentum broadening in unstable quark-gluon plasma

    NASA Astrophysics Data System (ADS)

    Carrington, M. E.; Mrówczyński, St.; Schenke, B.

    2017-02-01

    Quark-gluon plasma produced at the early stage of ultrarelativistic heavy-ion collisions is unstable, if weakly coupled, due to the anisotropy of its momentum distribution. Chromomagnetic fields are spontaneously generated and can reach magnitudes much exceeding typical values of the fields in equilibrated plasma. We consider a high-energy test parton traversing an unstable plasma that is populated with strong fields. We study the momentum broadening parameter q ̂ which determines the radiative energy loss of the test parton. We develop a formalism which gives q ̂ as the solution of an initial value problem, and we focus on extremely oblate plasmas which are physically relevant for relativistic heavy-ion collisions. The parameter q ̂ is found to be strongly dependent on time. For short times it is of the order of the equilibrium value, but at later times q ̂ grows exponentially due to the interaction of the test parton with unstable modes and becomes much bigger than the value in equilibrium. The momentum broadening is also strongly directionally dependent and is largest when the test parton velocity is transverse to the beam axis. Consequences of our findings for the phenomenology of jet quenching in relativistic heavy-ion collisions are briefly discussed.

  8. The assembly of ant-farmed gardens: mutualism specialization following host broadening.

    PubMed

    Chomicki, Guillaume; Janda, Milan; Renner, Susanne S

    2017-03-15

    Ant-gardens (AGs) are ant/plant mutualisms in which ants farm epiphytes in return for nest space and food rewards. They occur in the Neotropics and Australasia, but not in Africa, and their evolutionary assembly remains unclear. We here use phylogenetic frameworks for important AG lineages in Australasia, namely the ant genus Philidris and domatium-bearing ferns (Lecanopteris) and flowering plants in the Apocynaceae (Hoya and Dischidia) and Rubiaceae (Myrmecodia, Hydnophytum, Anthorrhiza, Myrmephytum and Squamellaria). Our analyses revealed that in these clades, diaspore dispersal by ants evolved at least 13 times, five times in the Late Miocene and Pliocene in Australasia and seven times during the Pliocene in Southeast Asia, after Philidris ants had arrived there, with subsequent dispersal between these two areas. A uniquely specialized AG system evolved in Fiji at the onset of the Quaternary. The farming in the same AG of epiphytes that do not offer nest spaces suggests that a broadening of the ants' plant host spectrum drove the evolution of additional domatium-bearing AG-epiphytes by selecting on pre-adapted morphological traits. Consistent with this, we found a statistical correlation between the evolution of diaspore dispersal by ants and domatia in all three lineages. Our study highlights how host broadening by a symbiont has led to new farming mutualisms.

  9. Broadening Participation of Women and Underrepresented Minorities in STEM through a Hybrid Online Transfer Program

    PubMed Central

    Drew, Jennifer C.; Galindo-Gonzalez, Sebastian; Ardissone, Alexandria N.; Triplett, Eric W.

    2016-01-01

    The Microbiology and Cell Science (MCS) Department at the University of Florida (UF) developed a new model of a 2 + 2 program that uses a hybrid online approach to bring its science, technology, engineering, and mathematics (STEM) curriculum to students. In this paradigm, 2-year graduates transfer as online students into the Distance Education in MCS (DE MCS) bachelor of science program. The program has broadened access to STEM with a steadily increasing enrollment that does not draw students away from existing on-campus programs. Notably, half of the DE MCS students are from underrepresented minority (URM) backgrounds and two-thirds are women, which represents a greater level of diversity than the corresponding on-campus cohort and the entire university. Additionally, the DE MCS cohort has comparable retention and academic performance compared with the on-campus transfer cohort. Of those who have earned a BS through the DE MCS program, 71% are women and 61% are URM. Overall, these data demonstrate that the hybrid online approach is successful in increasing diversity and provides another viable route in the myriad of STEM pathways. As the first of its kind in a STEM field, the DE MCS program serves as a model for programs seeking to broaden their reach. PMID:27587859

  10. Broadening Participation of Women and Underrepresented Minorities in STEM through a Hybrid Online Transfer Program.

    PubMed

    Drew, Jennifer C; Galindo-Gonzalez, Sebastian; Ardissone, Alexandria N; Triplett, Eric W

    2016-01-01

    The Microbiology and Cell Science (MCS) Department at the University of Florida (UF) developed a new model of a 2 + 2 program that uses a hybrid online approach to bring its science, technology, engineering, and mathematics (STEM) curriculum to students. In this paradigm, 2-year graduates transfer as online students into the Distance Education in MCS (DE MCS) bachelor of science program. The program has broadened access to STEM with a steadily increasing enrollment that does not draw students away from existing on-campus programs. Notably, half of the DE MCS students are from underrepresented minority (URM) backgrounds and two-thirds are women, which represents a greater level of diversity than the corresponding on-campus cohort and the entire university. Additionally, the DE MCS cohort has comparable retention and academic performance compared with the on-campus transfer cohort. Of those who have earned a BS through the DE MCS program, 71% are women and 61% are URM. Overall, these data demonstrate that the hybrid online approach is successful in increasing diversity and provides another viable route in the myriad of STEM pathways. As the first of its kind in a STEM field, the DE MCS program serves as a model for programs seeking to broaden their reach.

  11. Spectral broadening measurement of the lower hybrid waves during long pulse operation in Tore Supra

    NASA Astrophysics Data System (ADS)

    Berger-By, G.; Decampy, J.; Antar, G. Y.; Goniche, M.; Ekedahl, A.; Delpech, L.; Leroux, F.; Tore Supra Team

    2014-02-01

    On many tokamaks (C-Mod, EAST, FTU, JET, HT-7, TS), a decrease in current drive efficiency of the Lower Hybrid (LH) waves is observed in high electron density plasmas. The cause of this behaviour is believed to be: Parametric Instabilities (PI) and Scattering from Density Fluctuations (SDF). For the ITER LH system, our knowledge must be improved to avoid such effects and to maintain the LH current drive efficiency at high density. The ITPA IOS group coordinates this effort [1] and all experimental data are essential to validate the numerical codes in progress. Usually the broadening of the LH wave frequency spectrum is measured by a probe located in the plasma edge. For this study, the frequency spectrum of a reflected power signal from the LH antenna was used. In addition, the spectrum measurements are compared with the density fluctuations observed on RF probes located at the antenna mouth. Several plasma currents (0.6 to 1.4 MA) and densities up to 5.2 × 1019 m-3 have been realised on Tore Supra (TS) long pulses and with high injected RF power, up to 5.4 MW-30s. This allowed using a spectrum analyser to make several measurements during the plasma pulse. The side lobe amplitude, shifted by 20-30MHz with respect to the main peak, grows with increasing density. Furthermore, for an increase of plasma current at the same density, the spectra broaden and become asymmetric. Some parametric dependencies are shown in this paper.

  12. Interference of radiating states and ion dynamics in spectral line broadening

    NASA Astrophysics Data System (ADS)

    Kosarev, I. N.; Stehlé, C.; Feautrier, N.; Demura, A. V.; Lisitsa, V. S.

    1997-01-01

    The influence of the plasma coupling between the populations and the coherences on the lineshape is investigated. Ion dynamics is taken into account. The present research is performed within the atomic density matrix formalism. Ion microfield dynamics is simulated by the kangaroo - Poisson stochastic process (model microfield method). Numerical calculations of both lifetimes of radiating states and lineshapes are performed for the spectral doublet (1s - 2s)0953-4075/30/2/016/img6 - (1s - 4p)0953-4075/30/2/016/img7, (1s - 2)0953-4075/30/2/016/img6 - (1s - 4d)0953-4075/30/2/016/img9 of helium-like multicharged ions in hot dense plasmas. It is found that the ion microfield essentially influences the difference of populations of radiating 0953-4075/30/2/016/img10 states. Calculation of the lineshape of the doublet (1s - 2p)0953-4075/30/2/016/img11 - (1s - 4d)0953-4075/30/2/016/img12, (1s - 2p)0953-4075/30/2/016/img11 - (1s - 4f)0953-4075/30/2/016/img14 of neutral helium at astrophysical plasma conditions is also performed. The contribution of nonlinear interference effects (NIEF) in both allowed and forbidden components is calculated at various plasma conditions and a comparison with binary adiabatic theory is made. The results demonstrate that it is essential to take account of NIEF in the calculation of lineshapes of multicharged ions, but not essential in the case of neutral helium.

  13. Resonance line broadening of alkali metals in pyrotechnic flames. Doctoral thesis

    SciTech Connect

    Dillehay, D.R.

    1983-04-15

    A mathematical model of a pyrotechnic flame has been developed and validated. The model utilizes a computer program to calculate the relative radiant power of flares containing any of the alkali metals. The computation takes into consideration known system variables such as formulation, candle size, displacement along the plume axis, and atmospheric pressure. These effects were evaluated over a wide range of conditions and the computed spectra follow the established experimental spectra trends. The computer solution is a general solution requiring no ad hoc modifications to the model for any of the metals or conditions tested. The basis for the model of the flame permits calculation of the effects of mixing of the flare plume with the ambient atmosphere and takes heat loss along the plume axis into consideration.

  14. Slip Activity in Single Grains Extracted from Polycrystalline Specimen by X-Ray Line Broadening (Preprint)

    DTIC Science & Technology

    2010-01-01

    4 6 8 0.005 0.010 -101-3 -110-2 1-10-2F W H M [ 1 /n m ] K [ 1/nm ] Gr #44 Gr #50 Gr #72 -101-1 1-101 (a...0 2 4 6 0.000 0.005 0.010 (b) K2Ccalc [ 1/nm ] FW H M [ 1 /n m ] Gr #44 Gr #50 Gr #72 17 Figure 5. The FWHM (in 1/nm scales) in...Preprint 01 January 2010 – 01 January 2010 4 . TITLE AND SUBTITLE SLIP ACTIVITY IN SINGLE GRAINS EXTRACTED FROM POLYCRYSTALLINE SPECIMEN BY X-RAY

  15. Functional Flexibility of Intestinal IgA – Broadening the Fine Line

    PubMed Central

    Slack, Emma; Balmer, Maria Luisa; Fritz, Jörg H.; Hapfelmeier, Siegfried

    2012-01-01

    Intestinal bacteria outnumber our own human cells in conditions of both health and disease. It has long been recognized that secretory antibody, particularly IgA, is produced in response to these microbes and hypothesized that this must play an important role in defining the relationship between a host and its intestinal microbes. However, the exact role of IgA and the mechanisms by which IgA can act are only beginning to be understood. In this review we attempt to unravel the complex interaction between so-called “natural,” “primitive” (T-cell-independent), and “classical” IgA responses, the nature of the intestinal microbiota/intestinal pathogens and the highly flexible dynamic homeostasis of the mucosal immune system. Such an analysis reveals that low-affinity IgA is sufficient to protect the host from excess mucosal immune activation induced by harmless commensal microbes. However, affinity-maturation of “classical” IgA is essential to provide protection from more invasive commensal species such as segmented filamentous bacteria and from true pathogens such as Salmonella typhimurium. Thus a correlation is revealed between “sophistication” of the IgA response and aggressiveness of the challenge. A second emerging theme is that more-invasive species take advantage of host inflammatory mechanisms to more successfully compete with the resident microbiota. In many cases, the function of IgA may be to limit such inflammatory responses, either directly by coagulating or inhibiting virulence of bacteria before they can interact with the host or by modulating immune signaling induced by host recognition. Therefore IgA appears to provide an added layer of robustness in the intestinal ecosystem, promoting “commensal-like” behavior of its residents. PMID:22563329

  16. On Use of Pseudo-Voigt Profiles in Diffraction Line Broadening Analysis

    NASA Astrophysics Data System (ADS)

    Dasgupta, Prabal

    Sample-related X-ray diffraction profiles are often fitted with a pseudo-Voigt function, which is a linear combination of a Cauchy and a Gaussian function, particularly for the cases of size-strain analysis. This work reveals that Cauchy content, h, must be greater than 0.328 in case of pseudo-Voigt profile, otherwise one can not expect any meaningful accuracy in terms of data on crystallite size extracted from such profiles. h values published by several authors, who have made use of pseudo-Voigt function as profile fitting function, were thoroughly studied and it was found that their reported h values agree with the present theory.

  17. Influence of xenon on the self-reversal maxima of the Na-D emission lines in high-pressure sodium lamps

    NASA Astrophysics Data System (ADS)

    Jongerius, M. J.

    1987-10-01

    We report on the influence of xenon buffer gas on the shape of the self-reversed Na-D lines emitted by high-pressure sodium (HPS) arcs. In a previous paper we have reported experimental results on the collisional broadening of the Na-D line wings by xenon at high temperatures [M. J. Jongerius, J. Phys. B 20, 3345 (1987)]. These results are used to calculate the relative wavelength positions Δλr and Δλb of the red and blue Na-D self-reversal maximum, respectively, as functions of the Na/Hg amalgam temperature. The additional broadening by xenon leads to a strong asymmetry in the shape of the Na-D emission lines and a distinct maximum in Δλr/Δλb because of the Na-Xe satellite at 590.9 nm. The presence of this maximum in Δλr/Δλb is confirmed by experiments in which the shape of the Na-D emission lines is measured as a function of the arc power. The maximum value of Δλr/Δλb can be used as a measure of the xenon pressure in the arc. Furthermore, Δλr and Δλb can be used to obtain values for the sodium and mercury pressures in the burning arc. In the conventional method (J. J. de Groot and J. A. J. M. van Vliet, in Proceedings of the 2nd International Symposium on Incoherent Light Sources, Enschede, 1979, summary p. 30), the Na-D line broadening by the xenon buffer gas is not taken into account. We propose a modification of the conventional method to account for the influence of the collisional Na-D line broadening by xenon.

  18. A simple formula for estimating Stark widths of neutral lines. [of stellar atmospheres

    NASA Technical Reports Server (NTRS)

    Freudenstein, S. A.; Cooper, J.

    1978-01-01

    A simple formula for the prediction of Stark widths of neutral lines similar to the semiempirical method of Griem (1968) for ion lines is presented. This formula is a simplification of the quantum-mechanical classical path impact theory and can be used for complicated atoms for which detailed calculations are not readily available, provided that the effective position of the closest interacting level is known. The expression does not require the use of a computer. The formula has been applied to a limited number of neutral lines of interest, and the width obtained is compared with the much more complete calculations of Bennett and Griem (1971). The agreement generally is well within 50% of the published value for the lines investigated. Comparisons with other formulas are also made. In addition, a simple estimate for the ion-broadening parameter is given.

  19. Spectral line shapes. Volume 4 - Proceedings of the Eighth International Conference, College of William and Mary, Williamsburg, VA, June 9-13, 1986

    NASA Technical Reports Server (NTRS)

    Exton, Reginald J. (Editor)

    1987-01-01

    The present conference discusses topics in line broadening and shift phenomena in low-to-moderately dense plasmas, resonances in the continuum, hot and dense laser-produced plasmas, collisional broadening and intermolecular potentials, molecular broadening and collision-induced spectroscopy, collisional redistribution and laser-assisted collision processes, coherent and nonlinear spectroscopy, astrophysical line-shapes, and short-wavelength lasers. Attention is given to the widths and shifts of Be ion lines, the Stark broadening of Xe II and Fe I lines, perturbed and unperturbed series in the line-shapes of autoionizing Rydberg series, the line-broadening of hydrogenic ions in dense plasmas, Doppler-free line-shapes, the Franck-Condon principle, the dynamics of laser-assisted reactive collisions, the gas-kinetic effects of light, collision-induced processes in nonlinear optics, and line-shaping phenomena in cool stars.

  20. Spectral line shapes. Volume 4 - Proceedings of the Eighth International Conference, College of William and Mary, Williamsburg, VA, June 9-13, 1986

    NASA Astrophysics Data System (ADS)

    Exton, Reginald J.

    The present conference discusses topics in line broadening and shift phenomena in low-to-moderately dense plasmas, resonances in the continuum, hot and dense laser-produced plasmas, collisional broadening and intermolecular potentials, molecular broadening and collision-induced spectroscopy, collisional redistribution and laser-assisted collision processes, coherent and nonlinear spectroscopy, astrophysical line-shapes, and short-wavelength lasers. Attention is given to the widths and shifts of Be ion lines, the Stark broadening of Xe II and Fe I lines, perturbed and unperturbed series in the line-shapes of autoionizing Rydberg series, the line-broadening of hydrogenic ions in dense plasmas, Doppler-free line-shapes, the Franck-Condon principle, the dynamics of laser-assisted reactive collisions, the gas-kinetic effects of light, collision-induced processes in nonlinear optics, and line-shaping phenomena in cool stars.

  1. Food additives

    PubMed Central

    Spencer, Michael

    1974-01-01

    Food additives are discussed from the food technology point of view. The reasons for their use are summarized: (1) to protect food from chemical and microbiological attack; (2) to even out seasonal supplies; (3) to improve their eating quality; (4) to improve their nutritional value. The various types of food additives are considered, e.g. colours, flavours, emulsifiers, bread and flour additives, preservatives, and nutritional additives. The paper concludes with consideration of those circumstances in which the use of additives is (a) justified and (b) unjustified. PMID:4467857

  2. Effect of Doppler broadening on quantitative concentration measurements with degenerate four-wave mixing spectroscopy

    NASA Astrophysics Data System (ADS)

    Reichardt, Thomas A.; Lucht, Robert P.

    1996-06-01

    The effect of Doppler broadening on degenerate four-wave mixing (DFWM) signal intensities in the regime of high pump and probe laser intensities is investigated theoretically. DFWM reflectivities are calculated by solving the time-dependent density-matrix equations for a two-level system interacting with three laser fields. The density-matrix equations are integrated directly in the time domain on a grid of spatial locations along the phase-matching axis; the DFWM signal level is then calculated by summation of the polarization contribution (with the appropriate phase factor) from each of the spatial grid points. For the case in which the Doppler and the collisional linewidths are comparable, the DFWM reflectivity is found to be inversely proportional to the factor 1+(b Delta omega D/ Delta omega C ) 2 , where Delta omega D is the Doppler width, Delta omega C is the collisional width, and b is weakly dependent on the pump and the probe laser powers. We developed an analytical expression for the reflectivity of a line that is both collision and Doppler broadened by dividing the widely used Abrams and Lind expression for homogeneous reflectivity Rhom by the factor 1+(b Delta omega D/ Delta omega C )2 . This modified reflectivity expression is found to give accurate results for the DFWM reflectivity over a wide range of values for the ratio of Doppler to collisional width. With this modified Abrams-Lind expression, strategies for quantitative DFWM concentration measurements in flames and plasmas are proposed and analyzed. We conclude that, by selection of the appropriate rotational transition, a DFWM reflectivity that is directly proportional to the square of the total species number density can be obtained over a wide range of temperature for constant-laser-intensity spatial profile mapping in flames.

  3. Photosynthetic innovation broadens the niche within a single species.

    PubMed

    Lundgren, Marjorie R; Besnard, Guillaume; Ripley, Brad S; Lehmann, Caroline E R; Chatelet, David S; Kynast, Ralf G; Namaganda, Mary; Vorontsova, Maria S; Hall, Russell C; Elia, John; Osborne, Colin P; Christin, Pascal-Antoine

    2015-10-01

    Adaptation to changing environments often requires novel traits, but how such traits directly affect the ecological niche remains poorly understood. Multiple plant lineages have evolved C4 photosynthesis, a combination of anatomical and biochemical novelties predicted to increase productivity in warm and arid conditions. Here, we infer the dispersal history across geographical and environmental space in the only known species with both C4 and non-C4 genotypes, the grass Alloteropsis semialata. While non-C4 individuals remained confined to a limited geographic area and restricted ecological conditions, C4 individuals dispersed across three continents and into an expanded range of environments, encompassing the ancestral one. This first intraspecific investigation of C4 evolutionary ecology shows that, in otherwise similar plants, C4 photosynthesis does not shift the ecological niche, but broadens it, allowing dispersal into diverse conditions and over long distances. Over macroevolutionary timescales, this immediate effect can be blurred by subsequent specialisation towards more extreme niches.

  4. E-cigarettes: a need to broaden the debate.

    PubMed

    Latif, E; Nair, M

    2016-11-01

    The unregulated market for e-cigarettes continues to grow, with debates on their efficacy and impact on global public health. E-cigarettes, or electronic nicotine delivery systems (ENDs), are marketed as a 'safe' alternative to tobacco products and a tool for 'harm reduction'. Some public health experts are calling it a 'game changer' and favour the 'harm reduction' strategy, while others dispute this claim. In our opinion, the debate needs to be broadened to encompass other related concerns and effects on non-users and affected stakeholders. As with tobacco control, a holistic approach is needed to build a raft of policies that effectively address the issue from all angles and look beyond the direct health implications of e-cigarette use to explore the social, economic, political and environmental aspects of this debate, putting 'harm reduction' in context.

  5. Broadening the interface bandwidth in simulation based training

    NASA Technical Reports Server (NTRS)

    Somers, Larry E.

    1989-01-01

    Currently most computer based simulations rely exclusively on computer generated graphics to create the simulation. When training is involved, the method almost exclusively used to display information to the learner is text displayed on the cathode ray tube. MICROEXPERT Systems is concentrating on broadening the communications bandwidth between the computer and user by employing a novel approach to video image storage combined with sound and voice output. An expert system is used to combine and control the presentation of analog video, sound, and voice output with computer based graphics and text. Researchers are currently involved in the development of several graphics based user interfaces for NASA, the U.S. Army, and the U.S. Navy. Here, the focus is on the human factors considerations, software modules, and hardware components being used to develop these interfaces.

  6. America's economic future: environmentalists broaden the industrial policy debate

    SciTech Connect

    Not Available

    1984-01-01

    America's future economic health depends on the condition of our natural resources, our human resources, and our agricultural, energy, service, and high-technology industries, as well as on the traditional manufacturing industries. Industrial structure and output will do much to determine future levels of pollutants and resource use, and the shape of our economy will influence the character of American society and the quality of American life. The debate over proposals for government intervention in the growth and decline of specific industries changes the focus to microeconomic issues and broadens the discussion of economic goals. Environmentalists offer five goals for (1) a sustainable global economy, (2) a higher quality of life, (3) a sustainable environment and resource base, (4) total employment, and (5) widespread participation in decisions. They offer specific courses of action to meet these goals.

  7. Workshops Without Walls: broadening access to science around the world.

    PubMed

    Arslan, Betül K; Boyd, Eric S; Dolci, Wendy W; Dodson, K Estelle; Boldt, Marco S; Pilcher, Carl B

    2011-08-01

    The National Aeronautics and Space Administration (NASA) Astrobiology Institute (NAI) conducted two "Workshops Without Walls" during 2010 that enabled global scientific exchange--with no travel required. The second of these was on the topic "Molecular Paleontology and Resurrection: Rewinding the Tape of Life." Scientists from diverse disciplines and locations around the world were joined through an integrated suite of collaborative technologies to exchange information on the latest developments in this area of origin of life research. Through social media outlets and popular science blogs, participation in the workshop was broadened to include educators, science writers, and members of the general public. In total, over 560 people from 31 US states and 30 other nations were registered. Among the scientific disciplines represented were geochemistry, biochemistry, molecular biology and evolution, and microbial ecology. We present this workshop as a case study in how interdisciplinary collaborative research may be fostered, with substantial public engagement, without sustaining the deleterious environmental and economic impacts of travel.

  8. Effects of Doppler broadening on Autler-Townes splitting in six-wave mixing

    SciTech Connect

    Niu Jinyan; Pei Liya; Lu Xiaogang; Wang Ruquan; Wu Lingan; Fu Panming

    2011-09-15

    The effects of Doppler broadening on Autler-Townes (AT) splitting in six-wave mixing (SWM) are investigated by the dressed-state model. We analyze the velocities at which the atoms are in resonance with the dressed states through Doppler frequency shifting and find that, depending on the wave-number ratio, there may be two resonant velocities which can originate from resonance with one of the dressed states or from resonance with two different dressed states. Based on this model, we discuss a novel type of AT doublet in the SWM spectrum, where macroscopic effects play an important role. Specifically, the existence of resonant peaks requires polarization interference between atoms of different velocities in addition to a change in the number of resonant atoms involved. Our model can also be employed to analyze electromagnetically induced transparency resonance and other types of Doppler-free high-resolution AT spectroscopy.

  9. Creation of problem-dependent Doppler-broadened cross sections in the KENO Monte Carlo code

    SciTech Connect

    Hart, Shane W. D.; Celik, Cihangir; Maldonado, G. Ivan; Leal, Luiz C.

    2015-11-06

    In this paper, we introduce a quick method for improving the accuracy of Monte Carlo simulations by generating one- and two-dimensional cross sections at a user-defined temperature before performing transport calculations. A finite difference method is used to Doppler-broaden cross sections to the desired temperature, and unit-base interpolation is done to generate the probability distributions for double differential two-dimensional thermal moderator cross sections at any arbitrarily user-defined temperature. The accuracy of these methods is tested using a variety of contrived problems. In addition, various benchmarks at elevated temperatures are modeled, and results are compared with benchmark results. Lastly, the problem-dependent cross sections are observed to produce eigenvalue estimates that are closer to the benchmark results than those without the problem-dependent cross sections.

  10. THEORY AND SIMULATIONS OF REFRACTIVE SUBSTRUCTURE IN RESOLVED SCATTER-BROADENED IMAGES

    SciTech Connect

    Johnson, Michael D.; Gwinn, Carl R.

    2015-06-01

    At radio wavelengths, scattering in the interstellar medium distorts the appearance of astronomical sources. Averaged over a scattering ensemble, the result is a blurred image of the source. However, Narayan and Goodman and Goodman and Narayan showed that for an incomplete average, scattering introduces refractive substructure in the image of a point source that is both persistent and wideband. We show that this substructure is quenched but not smoothed by an extended source. As a result, when the scatter-broadening is comparable to or exceeds the unscattered source size, the scattering can introduce spurious compact features into images. In addition, we derive efficient strategies to numerically compute realistic scattered images, and we present characteristic examples from simulations. Our results show that refractive substructure is an important consideration for ongoing missions at the highest angular resolutions, and we discuss specific implications for RadioAstron and the Event Horizon Telescope.

  11. Creation of problem-dependent Doppler-broadened cross sections in the KENO Monte Carlo code

    DOE PAGES

    Hart, Shane W. D.; Celik, Cihangir; Maldonado, G. Ivan; ...

    2015-11-06

    In this paper, we introduce a quick method for improving the accuracy of Monte Carlo simulations by generating one- and two-dimensional cross sections at a user-defined temperature before performing transport calculations. A finite difference method is used to Doppler-broaden cross sections to the desired temperature, and unit-base interpolation is done to generate the probability distributions for double differential two-dimensional thermal moderator cross sections at any arbitrarily user-defined temperature. The accuracy of these methods is tested using a variety of contrived problems. In addition, various benchmarks at elevated temperatures are modeled, and results are compared with benchmark results. Lastly, the problem-dependentmore » cross sections are observed to produce eigenvalue estimates that are closer to the benchmark results than those without the problem-dependent cross sections.« less

  12. Inelastic collision processes in ozone and their relation to atmospheric pressure broadening

    NASA Technical Reports Server (NTRS)

    Steinfeld, J. I.; Flannery, C.; Klaassen, J.; Mizugai, Y.; Spencer, M.

    1990-01-01

    The research task employs infrared double-resonance to determine rotational energy transfer rates and pathways, in both the ground and vibrationally excited states of ozone. The resulting data base will then be employed to test inelastic scattering theories and to assess intermolecular potential models, both of which are necessary for the systematization and prediction of infrared pressure-broadening coefficients, which are in turn required by atmospheric ozone monitoring techniques based on infrared remote sensing. In addition, observation of excited-state absorption transitions will permit us to improve the determination of the 2 nu(sub 3), nu(sub 1) + nu(sub 2), and 2 nu(sub 1) rotational constants and to derive band strengths for hot-band transitions involving these levels.

  13. Theory and Simulations of Refractive Substructure in Resolved Scatter-broadened Images

    NASA Astrophysics Data System (ADS)

    Johnson, Michael D.; Gwinn, Carl R.

    2015-06-01

    At radio wavelengths, scattering in the interstellar medium distorts the appearance of astronomical sources. Averaged over a scattering ensemble, the result is a blurred image of the source. However, Narayan & Goodman and Goodman & Narayan showed that for an incomplete average, scattering introduces refractive substructure in the image of a point source that is both persistent and wideband. We show that this substructure is quenched but not smoothed by an extended source. As a result, when the scatter-broadening is comparable to or exceeds the unscattered source size, the scattering can introduce spurious compact features into images. In addition, we derive efficient strategies to numerically compute realistic scattered images, and we present characteristic examples from simulations. Our results show that refractive substructure is an important consideration for ongoing missions at the highest angular resolutions, and we discuss specific implications for RadioAstron and the Event Horizon Telescope.

  14. Investigating the ultimate accuracy of Doppler-broadening thermometry by means of a global fitting procedure

    NASA Astrophysics Data System (ADS)

    Amodio, Pasquale; De Vizia, Maria Domenica; Moretti, Luigi; Gianfrani, Livio

    2015-09-01

    Doppler-limited, high-precision, molecular spectroscopy in the linear regime of interaction may refine our knowledge of the Boltzmann constant. To this end, the global uncertainty in the retrieval of the Doppler width should be reduced down to 1 part over 106, which is a rather challenging target. So far, Doppler-broadening thermometry has been mostly limited by the uncertainty associated to the line shape model that is adopted for the nonlinear least-squares fits of experimental spectra. In this paper, we deeply investigate this issue by using a very realistic and sophisticated model, known as partially correlated speed-dependent Keilson-Storer profile, to reproduce near-infrared water spectra. A global approach has been developed to fit a large number of numerically simulated spectra, testing a variety of simplified line-shape models. It turns out that the most appropriate model is the speed-dependent hard-collision profile. We demonstrate that the Doppler width can be determined with relative precision and accuracy, respectively, of 0.42 and 0.75 part per million.

  15. Temperature Dependences of Air-Broadening and Shift Parameters in the ν_3 Band of Ozone

    NASA Astrophysics Data System (ADS)

    Smith, Mary Ann H.; Devi, V. Malathy; Benner, D. Chris

    2015-06-01

    Line parameter errors can contribute significantly to the total errors in retrievals of terrestrial atmospheric ozone concentration profiles using the strong 9.6-μm band, particularly for nadir-viewing experiments Detailed knowledge of the interfering ozone signal is also needed for retrievals of other atmospheric species in this spectral region. We have determined Lorentz air-broadening and pressure-induced shift coefficients along with their temperature dependences for a number of transitions in the ν_3 fundamental band of 16O_3. These results were obtained by applying the multispectrum nonlinear least-squares fitting technique to a set of 31 high-resolution infrared absorption spectra of O_3 recorded at temperatures between 160 and 300 K with several different room-temperature and coolable sample cells at the McMath-Pierce Fourier transform spectrometer at the National Solar Observatory on Kitt Peak. We compare our results with other available measurements and with the ozone line parameters in the HITRAN database. J.~Worden et al., J.~Geophys.~Res. 109 (2004) 9308-9319. R.~Beer et al., Geophys.~Res.~Lett. 35 (2008) L09801. D.~Chris Benner et al., JQSRT 53 (1995) 705-721. Rothman et al., J. Quant. Spectrosc. Radiat. Transfer 130 (2013) 4. JQSRT 130 (2013) 4-50.

  16. Air-Broadening and Shift Parameters in the ν_3 Band of Ozone

    NASA Astrophysics Data System (ADS)

    Smith, M. A. H.; Devi, V. Malathy; Benner, D. Chris

    2013-06-01

    Line parameter errors can contribute significantly to the total errors in retrievals of terrestrial atmospheric ozone concentration profiles using the strong 9.6-μm band, particularly for nadir-viewing experiments Detailed knowledge of the interfering ozone signal is also needed for retrievals of other atmospheric species in this spectral region. We have determined Lorentz air-broadening and pressure-induced shift coefficients along with their temperature dependences for a number of transitions in the ν_3 fundamental band of ^{16}O_3. These results were obtained by applying the multispectrum nonlinear least-squares fitting technique to a set of 31 high-resolution infrared absorption spectra of O_3 previously recorded at temperatures between 160 and 300 K with several different room-temperature and coolable sample cells at the McMath-Pierce Fourier transform spectrometer at the National Solar Observatory on Kitt Peak. We compare our results with other available measurements and with the ozone line parameters in the 2008 HITRAN database. J. Worden {et al., J. Geophys. Res. {109} (2004) 9308-9319.}. R. Beer {et al., Geophys. Res. Lett. {35} (2008) L09801. D. Chris Benner {et al., JQSRT {53} (1995) 705-721. L. S. Rothman {et al., JQSRT {110} (2009) 533-572.

  17. Measurement Of Magnetic Fields In Magnetized Plasmas Using Zeeman Broadening Diagnostics

    NASA Astrophysics Data System (ADS)

    Haque, Showera; Wallace, Matthew S.; Neill, Paul; Presura, Radu

    2015-11-01

    The Zeeman effect has been used to measure the magnetic field in high energy density plasmas. The measurements are difficult in this regime because the line broadening due to the high plasma density and temperature surpasses the Zeeman splitting. Using an idea proposed by Tessarin et al. (2011), we have measured the field in magnetized laser plasmas and the magnetized precursor of wire array z-pinches. Time-gated spectra with one-dimensional space-resolution were obtained at the Nevada Terawatt Facility for laser plasmas created by 20 J, 1 ns Leopard laser pulses, and expanding in the azimuthal magnetic field produced by the 0.6 MA Zebra pulsed power generator, and for wire array plasmas driven by the 1 MA configuration of the Zebra generator. We explore the response of the Al III 4s 2S1/2- 4p 2P1 / 2 , 3 / 2 doublet components and the C IV 3s 2S1/2- 3p 2P1 / 2 , 3 / 2 doublet components to the external magnetic field spatially along the plasma. In these measurements the Zeeman splitting was not resolved, but the magnetic field strength was measured from the difference between the widths of the line profiles. This work was supported by the DOE/OFES grant DE-SC0008829 and DOE/NNSA contract DE-FC52-06NA27616.

  18. Magnetic Field Measurement in Magnetized Laser Plasmas Using Zeeman Broadening Diagnostics

    NASA Astrophysics Data System (ADS)

    Haque, S.; Wallace, M. S.; Arias, A.; Morita, T.; Plechaty, C.; Huntington, C.; Martinez, D.; Ross, S. J.; Park, H.-S.; Presura, R.

    2013-10-01

    The Zeeman effect has been used to measure the magnetic field in high energy density plasmas. The measurements are difficult when the field orientation is fluctuating in the plasma volume or when the line broadening due to the high plasma density and temperature surpasses the Zeeman splitting. Based on an idea proposed by Tessarin et al. (2011), we implemented a solution to this problem to the field measurement in magnetized laser plasmas. High resolution spectra were obtained at the Nevada Terawatt Facility for plasmas created by 20 J, 400 fs Leopard laser pulses in the azimuthal magnetic field produced by the 0.6 MA Zebra pulsed power generator. The components of the Al III 3s 2S1/2 - 3p 2P1 / 2 , 3 / 2 were recorded with space resolution along the direction normal to the target, which coincided with the magnetic field radius. In several shots, the spectra were time gated for 10 ns at different values of the magnetic field. In these measurements the Zeeman splitting was not resolved, but the magnetic field strength can be measured from the difference between the widths of the line profiles. This work was supported by the DOE/OFES grant DE-SC0008829 and DOE/NNSA contract DE-FC52-06NA27616.

  19. Polarization-Sensitive Measurements Of Magnetic Fields In Magnetized Plasmas Using Zeeman Broadening Diagnostics

    NASA Astrophysics Data System (ADS)

    Haque, Showera; Wallace, Matthew S.; Neill, Paul; Presura, Radu

    2016-10-01

    The Zeeman effect has been used to measure the magnetic field in high energy density plasmas. The measurements are difficult in this regime because the line broadening due to the high plasma density and temperature surpasses the Zeeman splitting. Using an idea proposed by Tessarin et al. (2011), we have measured the field in magnetized laser plasmas and in the current-driven exploding wire plasmas. Time-gated spectra with one-dimensional space-resolution were obtained at the Nevada Terawatt Facility for laser plasmas created by 20 J, 1 ns Leopard laser pulses, and expanding in the azimuthal magnetic field produced by the 0.6 MA Zebra pulsed power generator, and for wire array plasmas driven by the 1 MA configuration of the Zebra generator. We explore the response of the Al III 4s 2S1/2- 4p 2P1 / 2 , 3 / 2 doublet components to the external magnetic field spatially along the plasma in two orthogonal polarizations. In these measurements the Zeeman splitting was not resolved, but the magnetic field strength was measured from the difference between the widths of the line profiles. This work was supported by the DOE/OFES Grant DE-SC0008829 and DOE/NNSA contract DE-FC52-06NA27616.

  20. Adaptive broadening to improve spectral resolution in the numerical renormalization group

    NASA Astrophysics Data System (ADS)

    Lee, Seung-Sup B.; Weichselbaum, Andreas

    2016-12-01

    We propose an adaptive scheme of broadening the discrete spectral data from numerical renormalization group (NRG) calculations to improve the resolution of dynamical properties at finite energies. While the conventional scheme overbroadens narrow features at large frequency by broadening discrete weights with constant width in log-frequency, our scheme broadens each discrete contribution individually based on its sensitivity to a z -shift in the logarithmic discretization intervals. We demonstrate that the adaptive broadening better resolves various features in noninteracting and interacting models at comparable computational cost. The resolution enhancement is more significant for coarser discretization as typically required in multiband calculations. At low frequency below the energy scale of temperature, the discrete NRG data necessarily needs to be broadened on a linear scale. Here we provide a method that minimizes transition artifacts in between these broadening kernels.

  1. Opacity Broadening of 13CO Linewidths and its Effect on the Variance-Sonic Mach Number Relation

    NASA Astrophysics Data System (ADS)

    Correia, C.; Burkhart, B.; Lazarian, A.; Ossenkopf, V.; Stutzki, J.; Kainulainen, J.; Kowal, G.; de Medeiros, J. R.

    2014-04-01

    We study how the estimation of the sonic Mach number (Ms ) from 13CO linewidths relates to the actual three-dimensional sonic Mach number. For this purpose we analyze MHD simulations that include post-processing to take radiative transfer effects into account. As expected, we find very good agreement between the linewidth estimated sonic Mach number and the actual sonic Mach number of the simulations for optically thin tracers. However, we find that opacity broadening causes Ms to be overestimated by a factor of ≈1.16-1.3 when calculated from optically thick 13CO lines. We also find that there is a dependence on the magnetic field: super-Alfvénic turbulence shows increased line broadening compared with sub-Alfvénic turbulence for all values of optical depth for supersonic turbulence. Our results have implications for the observationally derived sonic Mach number-density standard deviation (σρ/langρrang) relationship, \\sigma ^2_{\\rho /\\langle \\rho \\rangle }=b^2M_s^2, and the related column density standard deviation (σ N/langNrang) sonic Mach number relationship. In particular, we find that the parameter b, as an indicator of solenoidal versus compressive driving, will be underestimated as a result of opacity broadening. We compare the σ N/langNrang-Ms relation derived from synthetic dust extinction maps and 13CO linewidths with recent observational studies and find that solenoidally driven MHD turbulence simulations have values of σ N/langNrangwhich are lower than real molecular clouds. This may be due to the influence of self-gravity which should be included in simulations of molecular cloud dynamics.

  2. CH3D photomixing spectroscopy up to 2.5 THz: New set of rotational and dipole parameters, first THz self-broadening measurements

    NASA Astrophysics Data System (ADS)

    Bray, Cédric; Cuisset, Arnaud; Hindle, Francis; Bocquet, Robin; Mouret, Gaël; Drouin, Brian J.

    2017-03-01

    Several previously unmeasured transitions of 12CH3D have been recorded by a terahertz photomixing continuous-wave spectrometer up to QR(10) branch at 2.5 THz. An improved set of rotational constants has been obtained utilizing a THz frequency metrology based on a frequency comb that achieved an averaged frequency position better than 150 kHz on more than fifty ground-state transitions. A detailed analysis of the measured line intensities was undertaken using the multispectrum fitting program and has resulted in a determination of new dipole moment parameters. Measurements at different pressures of the QR(7) transitions provide the first determination of self-broadening coefficients from pure rotational CH3D lines. The THz rotational measurements are consistent with IR rovibrational data but no significant vibrational dependence of self-broadening coefficient may be observed by comparison.

  3. Food additives

    MedlinePlus

    ... or natural. Natural food additives include: Herbs or spices to add flavor to foods Vinegar for pickling ... Certain colors improve the appearance of foods. Many spices, as well as natural and man-made flavors, ...

  4. Doppler shift measurement of Balmer-alpha line spectrum emission from a plasma in a negative hydrogen ion source

    SciTech Connect

    Wada, M. Doi, K.; Kisaki, M.; Nakano, H.; Tsumori, K.; Nishiura, M.

    2015-04-08

    Balmer-α light emission from the extraction region of the LHD one-third ion source has shown a characteristic Doppler broadening in the wavelength spectrum detected by a high resolution spectrometer. The spectrum resembles Gaussian distribution near the wavelength of the intensity peak, while it has an additional component of a broader foot. The measured broadening near the wavelength of the intensity peak corresponds to 0.6 eV hydrogen atom temperature. The spectrum exhibits a larger expansion in the blue wing which becomes smaller when the line of sight is tilted toward the driver region from the original observation axis parallel to the plasma grid. A surface collision simulation model predicts the possibility of hydrogen reflection at the plasma grid surface to form a broad Balmer-α light emission spectrum.

  5. Meaningful Engagement to Enhance Diversity: Broadened Impact Actualized

    NASA Astrophysics Data System (ADS)

    Whitney, V. W.; Pyrtle, A. J.

    2008-12-01

    The MS PHD'S Professional Development Program was established by and for UR/US populations to facilitate increased and sustained participation within the Earth system science community. MS PHD'S is jointly funded by NSF and NASA. Fourteen (14) minority Earth system scientists served as Program mentors and one- hundred fifteen (115) minority and non-minority scientists served as Meeting Mentors to student participants. Representatives from fifty-six (56) agencies and institutions provided support and exposure to MS PHD'S student participants. Two hundred fifty-eight (258) highly qualified UR/US students completed on-line applications to participate in the MS PHD'S Professional Development Program. Because of funding limitations, slightly fewer than 50% of the applicants were selected to participate. One-hundred twenty-six (126) undergraduate and graduate students from 26 states and Puerto Rico participated in the MS PHD'S program. Sixty-eight (68) MS PHD'S student participants self-identified as African American; thirty-four (34) as Puerto Rican; nine (9) as Hispanic/Mexican American, ten (10) as Native American and one (1) each as African, Asian, Pacific Islander, Hispanic and Multi-Ethnic. During the five year span of MS PHD'S programming, sixteen (16) student participants completed BS degrees, twelve (12) completed MS degrees and ten (10) completed the Doctoral degrees. How did MS PHD'S establish meaningful engagement to enhance diversity within the Earth system science community? This case study reveals replicable processes and constructs to enhance the quality of meaningful collaboration and engagement. In addition, the study addresses frequently asked questions (FAQ's) on outreach, recruitment, engagement, retention and success of students from underrepresented populations within diversity-focused programs.

  6. Broadening the Participation of Native Americans in Earth Science

    NASA Astrophysics Data System (ADS)

    Bueno Watts, Nievita

    Climate change is not a thing of the future. Indigenous people are being affected by climate changes now. Native American Earth scientists could help Native communities deal with both climate change and environmental pollution issues, but are noticeably lacking in Earth Science degree programs. The Earth Sciences produce the lowest percentage of minority scientists when compared with other science and engineering fields. Twenty semi-structured interviews were gathered from American Indian/ Alaska Native Earth Scientists and program directors who work directly with Native students to broaden participation in the field. Data was analyzed using qualitative methods and constant comparison analysis. Barriers Native students faced in this field are discussed, as well as supports which go the furthest in assisting achievement of higher education goals. Program directors give insight into building pathways and programs to encourage Native student participation and success in Earth Science degree programs. Factors which impede obtaining a college degree include financial barriers, pressures from familial obligations, and health issues. Factors which impede the decision to study Earth Science include unfamiliarity with geoscience as a field of study and career choice, the uninviting nature of Earth Science as a profession, and curriculum that is irrelevant to the practical needs of Native communities or courses which are inaccessible geographically. Factors which impede progress that are embedded in Earth Science programs include educational preparation, academic information and counseling and the prevalence of a Western scientific perspective to the exclusion of all other perspectives. Intradepartmental relationships also pose barriers to the success of some students, particularly those who are non-traditional students (53%) or women (80%). Factors which support degree completion include financial assistance, mentors and mentoring, and research experiences. Earth scientists

  7. UVES and X-Shooter spectroscopy of the emission line AM CVn systems GP Com and V396 Hya

    NASA Astrophysics Data System (ADS)

    Kupfer, T.; Steeghs, D.; Groot, P. J.; Marsh, T. R.; Nelemans, G.; Roelofs, G. H. A.

    2016-04-01

    We present time-resolved spectroscopy of the AM CVn-type binaries GP Com and V396 Hya obtained with VLT/X-Shooter and VLT/UV-Visual Echelle Spectrograph (UVES). We fully resolve the narrow central components of the dominant helium lines and determine radial velocity semi-amplitudes of Kspike = 11.7 ± 0.3 km s-1 for GP Com and Kspike = 5.8 ± 0.3 km s-1 for V396 Hya. The mean velocities of the narrow central components show variations from line to line. Compared to calculated line profiles that include Stark broadening we are able to explain the displacements, and the appearance of forbidden helium lines, by additional Stark broadening of emission in a helium plasma with an electron density ne ≃ 5 × 1015 cm-3. More than 30 nitrogen and more than 10 neon lines emission lines were detected in both systems. Additionally, 20 nitrogen absorption lines are only seen in GP Com. The radial velocity variations of these lines show the same phase and velocity amplitude as the central helium emission components. The small semi-amplitude of the central helium emission component, the consistency of phase and amplitude with the absorption components in GP Com as well as the measured Stark effect shows that the central helium emission component, the so-called central-spike, is consistent with an origin on the accreting white dwarf. We use the dynamics of the bright spot and the central-spike to constrain the binary parameters for both systems and find a donor mass of 9.6-42.8 MJupiter for GP Com and 6.1-30.5 MJupiter for V396 Hya. We find an upper limit for the rotational velocity of the accretor of vrot < 46 km s-1 for GP Com and vrot < 59 km s-1 for V396 Hya which excludes a fast rotating accretor in both systems.

  8. A temporally and spatially resolved electron density diagnostic method for the edge plasma based on Stark broadening

    NASA Astrophysics Data System (ADS)

    Zafar, A.; Martin, E. H.; Shannon, S. C.; Isler, R. C.; Caughman, J. B. O.

    2016-11-01

    An electron density diagnostic (≥1010 cm-3) capable of high temporal (ms) and spatial (mm) resolution is currently under development at Oak Ridge National Laboratory. The diagnostic is based on measuring the Stark broadened, Doppler-free spectral line profile of the n = 6-2 hydrogen Balmer series transition. The profile is then fit to a fully quantum mechanical model including the appropriate electric and magnetic field operators. The quasi-static approach used to calculate the Doppler-free spectral line profile is outlined here and the results from the model are presented for H-δ spectra for electron densities of 1010-1013 cm-3. The profile shows complex behavior due to the interaction between the magnetic substates of the atom.

  9. Tunable diode laser measurements of line widths in the nu1-fundamental band of (N-14)2(O-16) at atmospheric temperatures

    NASA Technical Reports Server (NTRS)

    Varanasi, P.; Chudamani, S.

    1989-01-01

    A tunable diode-laser spectrometer and a low-temperature absorption cell have been employed to measure the N2-broadened and O2-broadened half-widths of rotational lines in the nu1 fundamental band of (N-14)2(O-16) at 185, 235, 263, and 295 K. The temperature dependence of the line widths has been observed to be practically identical, thereby leading to the suggestion that air-broadening would exhibit the same dependence.

  10. Broadening of analyte streams due to a transverse pressure gradient in free-flow isoelectric focusing.

    PubMed

    Dutta, Debashis

    2017-02-10

    Pressure-driven cross-flows can arise in free-flow isoelectric focusing systems (FFIEF) due to a non-uniform electroosmotic flow velocity along the channel width induced by the pH gradient in this direction. In addition, variations in the channel cross-section as well as unwanted differences in hydrostatic heads at the buffer/sample inlet ports can also lead to such pressure-gradients which besides altering the equilibrium position of the sample zones have a tendency to substantially broaden their widths deteriorating the separations. In this situation, a thorough assessment of stream broadening due to transverse pressure-gradients in FFIEF devices is necessary in order to establish accurate design rules for the assay. The present article describes a mathematical framework to estimate the noted zone dispersion in FFIEF separations based on the method-of-moments approach under laminar flow conditions. A closed-form expression has been derived for the spatial variance of the analyte streams at their equilibrium positions as a function of the various operating parameters governing the assay performance. This expression predicts the normalized stream variance under the chosen conditions to be determined by two dimensionless Péclet numbers evaluated based on the transverse pressure-driven and electrophoretic solute velocities in the separation chamber, respectively. Moreover, the analysis shows that while the stream width can be expected to increase with an increase in the value of the first Péclet number, the opposite trend will be followed with respect to the latter. The noted results have been validated using Monte Carlo simulations that also establish a time/length scale over which the predicted equilibrium stream width is attained in the system.

  11. Spectral broadening measurement of the lower hybrid waves during long pulse operation in Tore Supra

    SciTech Connect

    Berger-By, G.; Decampy, J.; Goniche, M.; Ekedahl, A.; Delpech, L.; Leroux, F.; Antar, G. Y.; Collaboration: Tore Supra Team

    2014-02-12

    On many tokamaks (C-Mod, EAST, FTU, JET, HT-7, TS), a decrease in current drive efficiency of the Lower Hybrid (LH) waves is observed in high electron density plasmas. The cause of this behaviour is believed to be: Parametric Instabilities (PI) and Scattering from Density Fluctuations (SDF). For the ITER LH system, our knowledge must be improved to avoid such effects and to maintain the LH current drive efficiency at high density. The ITPA IOS group coordinates this effort [1] and all experimental data are essential to validate the numerical codes in progress. Usually the broadening of the LH wave frequency spectrum is measured by a probe located in the plasma edge. For this study, the frequency spectrum of a reflected power signal from the LH antenna was used. In addition, the spectrum measurements are compared with the density fluctuations observed on RF probes located at the antenna mouth. Several plasma currents (0.6 to 1.4 MA) and densities up to 5.2 × 10{sup 19} m−3 have been realised on Tore Supra (TS) long pulses and with high injected RF power, up to 5.4 MW-30s. This allowed using a spectrum analyser to make several measurements during the plasma pulse. The side lobe amplitude, shifted by 20-30MHz with respect to the main peak, grows with increasing density. Furthermore, for an increase of plasma current at the same density, the spectra broaden and become asymmetric. Some parametric dependencies are shown in this paper.

  12. Broadening Participation: Mentoring Community College Students in a Geoscience REU

    NASA Astrophysics Data System (ADS)

    Smith, M.; Osborn, J.

    2015-12-01

    Increasingly, REUs are recruiting from community colleges as a means of broadening participation of underrepresented minorities, women, and low-income students in STEM. As inclusion of community college students becomes normalized, defining the role of science faculty and preparing them to serve as mentors to community college students is a key component of well-designed programs. This session will present empirical research regarding faculty mentoring in the first two years of an NSF-REU grant to support community college students in a university's earth and environmental science labs. Given the documented benefits of undergraduate research on students' integration into the scientific community and their career trajectory in STEM, the focus of the investigation has been on the processes and impact of mentoring community college STEM researchers at a university serving a more traditionally privileged population; the degree to which the mentoring relationships have addressed community college students needs including their emotional, cultural and resource needs; and gaps in mentor training and the mentoring relationship identified by mentors and students.

  13. More Than Additional Space...

    ERIC Educational Resources Information Center

    CEFP Journal, 1973

    1973-01-01

    A much needed addition to the Jamestown Elementary School turned out to be more than an expansion of walls for more space. A new educational program, a limited budget, and a short time line were tackled on a team approach basis and were successfully resolved. (Author)

  14. Optoelectronic Workshops. Dynamical Instabilities in Homogeneously Broadened Lasers (9th) (23 August 1988)

    DTIC Science & Technology

    1988-08-23

    Broadened Lasers: Dye Lasers Karl Koch Modulation Techniques: Alexandrite Lasers Stephen Chakmakjian Summary Carlos R. Stroud B. CECOM Center for Night... alexandrite , another phonon assisted homogeneously broadened laser. He described in some detail modulation spectroscopic techniques developed in Rochester that...measurement determines the population cycling rate slow decay from level 1 may cause instabilities Single Laser AM Experiments ruby alexandrite modulator

  15. Potlining Additives

    SciTech Connect

    Rudolf Keller

    2004-08-10

    In this project, a concept to improve the performance of aluminum production cells by introducing potlining additives was examined and tested. Boron oxide was added to cathode blocks, and titanium was dissolved in the metal pool; this resulted in the formation of titanium diboride and caused the molten aluminum to wet the carbonaceous cathode surface. Such wetting reportedly leads to operational improvements and extended cell life. In addition, boron oxide suppresses cyanide formation. This final report presents and discusses the results of this project. Substantial economic benefits for the practical implementation of the technology are projected, especially for modern cells with graphitized blocks. For example, with an energy savings of about 5% and an increase in pot life from 1500 to 2500 days, a cost savings of $ 0.023 per pound of aluminum produced is projected for a 200 kA pot.

  16. Phosphazene additives

    DOEpatents

    Harrup, Mason K; Rollins, Harry W

    2013-11-26

    An additive comprising a phosphazene compound that has at least two reactive functional groups and at least one capping functional group bonded to phosphorus atoms of the phosphazene compound. One of the at least two reactive functional groups is configured to react with cellulose and the other of the at least two reactive functional groups is configured to react with a resin, such as an amine resin of a polycarboxylic acid resin. The at least one capping functional group is selected from the group consisting of a short chain ether group, an alkoxy group, or an aryloxy group. Also disclosed are an additive-resin admixture, a method of treating a wood product, and a wood product.

  17. The apparent spectral broadening of VLF transmitter signals during transionospheric propagation

    NASA Technical Reports Server (NTRS)

    Bell, T. F.; Inan, U. S.; Katsufrakis, J. P.; James, H. G.

    1983-01-01

    ISIS 1 and 2 and ISEE 1 VLF/ELF electric field wave data indicate the existence of a novel phenomenon, in which initially narrow band upgoing signals from ground-based VLF transmitters undergo a significant spectral broadening as they propagate through the ionosphere and protonosphere, up to altitudes in the 600-3800 km range. For transmitter signals in the 10-20 kHz range, the spectral broadening can be as high as 10 percent of the input signal's nominal frequency. In many cases, the bandwidth of the spectrally broadened signals is a strong function of the electric dipole antenna orientation with respect to the local direction of the earth's magnetic field. The unusual dispersion in the components of the spectrally broadened pulses suggests that the spectral broadening may be due to a Doppler shift effect in which the initial signals scatter from irregularities in the F region and couple into quasi-electrostatic modes of short wave length.

  18. OH-radical specific addition to the antioxidant glutathione S-atom at the air-water interface - Relevance to the redox balance of the lung epithelial lining fluid and the causality of adverse health effects induced by air pollution

    NASA Astrophysics Data System (ADS)

    Colussi, A. J.; Enami, S.; Hoffmann, M. R.

    2015-12-01

    Inhalation of oxidant pollutants upsets the redox balance (RB) of the lung epithelial lining fluid (ELF) by triggering the formation of reactive OH-radicals therein. RB is deemed to be controlled by the equilibrium between the most abundant ELF protective antioxidant glutathione (GSH) and its putative disulfide GSSG oxidation product. The actual species produced from the oxidation of GSH initiated by ·OH in ELF interfacial layers exposed to air, i.e., under realistic ELF conditions, however, were never identified. Here we report the online electrospray mass spectrometric detection of sulfenate (GSO-), sulfinate (GSO2-) and sulfonate (GSO3-) on the surface of aqueous GSH solutions collided with ·OH(g). We show that these products arise from ·OH specific additions to S-atoms, rather than via H-abstraction from GS-H. The remarkable specificity of ·OH in interfacial water vis-a-vis its lack of selectivity in bulk water implicates an unprecedented steering process during ·OH-GSH encounters at water interfaces. A non-specific systemic immune response to inhaled oxidants should be expected if they were initially converted into a common ·OH intermediate on the ELF (e.g., via fast Fenton chemistry) and oxidative stress signaled by the [GSH]/[GSOH] ratio.

  19. Building 1D resonance broadened quasilinear (RBQ) code for fast ions Alfvénic relaxations

    NASA Astrophysics Data System (ADS)

    Gorelenkov, Nikolai; Duarte, Vinicius; Berk, Herbert

    2016-10-01

    The performance of the burning plasma is limited by the confinement of superalfvenic fusion products, e.g. alpha particles, which are capable of resonating with the Alfvénic eigenmodes (AEs). The effect of AEs on fast ions is evaluated using a resonance line broadened diffusion coefficient. The interaction of fast ions and AEs is captured for cases where there are either isolated or overlapping modes. A new code RBQ1D is being built which constructs diffusion coefficients based on realistic eigenfunctions that are determined by the ideal MHD code NOVA. The wave particle interaction can be reduced to one-dimensional dynamics where for the Alfvénic modes typically the particle kinetic energy is nearly constant. Hence to a good approximation the Quasi-Linear (QL) diffusion equation only contains derivatives in the angular momentum. The diffusion equation is then one dimensional that is efficiently solved simultaneously for all particles with the equation for the evolution of the wave angular momentum. The evolution of fast ion constants of motion is governed by the QL diffusion equations which are adapted to find the ion distribution function.

  20. Stark Broadening Analysis Using Optical Spectroscopy of the Dense Plasma Focus

    NASA Astrophysics Data System (ADS)

    Ross, Patrick; Bennett, Nikki; Dutra, Eric; Hagen, E. Chris; Hsu, Scott; Hunt, Gene; Koch, Jeff; Waltman, Tom; NSTec DPF Team

    2015-11-01

    To aid in validating numerical modeling of MA-class dense plasma focus (DPF) devices, spectroscopic measurements of the Gemini Dense Plasma Focus (DPF) were performed using deuterium and deuterium/dopant (argon/krypton) gas. The spectroscopic measurements were made using a fiber-coupled spectrometer and streak camera. Stark line-broadening analysis was applied to the deuterium beta emission (486 nm) in the region near the breakdown of the plasma and during the run-down and run-in phases of the plasma evolution. Densities in the range of 1e17 to low 1e18 cm-3 were obtained. These values are in agreement with models of the DPF performed using the LSP code. The spectra also show a rise and fall with time, indicative of the plasma sheath passing by the view port. Impurity features were also identified in the spectra which grew in intensity as the gas inside the DPF was discharged repeatedly without cycling. Implications of this impurity increase for D-T discharges (without fresh gas fills between every discharge) will be discussed. This work was done by National Security Technologies, LLC, under Contract No. DE-AC52-06NA25946, and by Los Alamos National Laboratory, under Contract no. DE-AC52-06NA25396 with the U.S. Department of Energy. DOE/NV/25946-2515.