Science.gov

Sample records for additional supporting materials

  1. Reduction of sludge generation by the addition of support material in a cyclic activated sludge system for municipal wastewater treatment.

    PubMed

    Araujo, Moacir Messias de; Lermontov, André; Araujo, Philippe Lopes da Silva; Zaiat, Marcelo

    2013-09-01

    An innovative biomass carrier (Biobob®) was tested for municipal wastewater treatment in an activated sludge system to evaluate the pollutant removal performance and the sludge generation for different carrier volumes. The experiment was carried out in a pilot-scale cyclic activated sludge system (CASS®) built with three cylindrical tanks in a series: an anoxic selector (2.1 m(3)), an aerobic selector (2.5 m(3)) and the main aerobic reactor (25.1 m(3)). The results showed that by adding the Biobob® carrier decreased the MLVSS concentration, which consequently reduced the waste sludge production of the system. Having 7% and 18% (v/v) support material in the aerobic reactor, the observed biomass yield decreased 18% and 36%, respectively, relative to the reactor operated with suspended biomass. The addition of media did not affect the system's performance for COD and TSS removal. However, TKN and TN removal were improved by 24% and 14%, respectively, using 18% (v/v) carrier. PMID:23831747

  2. 46 CFR 355.5 - Additional material.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 8 2011-10-01 2011-10-01 false Additional material. 355.5 Section 355.5 Shipping... STATES CITIZENSHIP § 355.5 Additional material. If additional material is determined to be essential to clarify or support the evidence of U.S. citizenship, such material shall be furnished by...

  3. 46 CFR 355.5 - Additional material.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 8 2014-10-01 2014-10-01 false Additional material. 355.5 Section 355.5 Shipping... STATES CITIZENSHIP § 355.5 Additional material. If additional material is determined to be essential to clarify or support the evidence of U.S. citizenship, such material shall be furnished by...

  4. 46 CFR 355.5 - Additional material.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 8 2013-10-01 2013-10-01 false Additional material. 355.5 Section 355.5 Shipping... STATES CITIZENSHIP § 355.5 Additional material. If additional material is determined to be essential to clarify or support the evidence of U.S. citizenship, such material shall be furnished by...

  5. 46 CFR 355.5 - Additional material.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 8 2012-10-01 2012-10-01 false Additional material. 355.5 Section 355.5 Shipping... STATES CITIZENSHIP § 355.5 Additional material. If additional material is determined to be essential to clarify or support the evidence of U.S. citizenship, such material shall be furnished by...

  6. ATS materials support

    SciTech Connect

    Karnitz, M.A.; Wright, I.G.; Ferber, M.K.; Holcomb, R.S.; Rawlins, M.H.

    1996-12-31

    The technology based portion of the Advanced Turbine System Program (ATS) contains several subelements which address generic technology issues for land-base gas turbine systems. One subelement is the Materials/Manufacturing Technology Program which is coordinated by DOE-Oak Ridge Operations and Oak Ridge National laboratory (ORNL) for the Department of Energy. The work in this subelement is being performed predominantly by industry with assistance from national laboratories and universities. Projects in this subelement are aimed toward hastening the incorporation of new materials and components in gas turbines. The materials manufacturing subelement was developed with input from gas turbine manufacturers, material suppliers, government laboratories and universities. Work is currently ongoing on thermal barrier coatings (TBCs), the scale-up of single-crystal airfoil manufacturing technologies, materials characterization and technology information exchange. Westinghouse Power Generation and Pratt and Whitney each have material programs to develop dependable TBCs that enable increased turbine inlet temperatures while maintaining airfoil substrate temperatures at levels to meet the ATS life goals. Howmet and PCC Airfoils each have projects to extend the capability of single-crystal complex-cored airfoil technology to larger sizes so that higher turbine inlet temperatures can be attained in land-based turbines in a cost-effective manner. Materials characterization tasks are ongoing on TBCs in support of the industrial projects. In addition, a project on long-term testing of ceramics and ceramic-matrix composites for gas turbines is being conducted in support of programs at Solar Turbines, Allison Engines, and Westinghouse Power Generation.

  7. Materials support for HITAF

    SciTech Connect

    Breder, K.; Tennery, V.J.

    1994-09-01

    The primary objective of this work is to compare the mechanical performance of structural ceramic materials which are being proposed for use in the air heater of a coal fired high temperature advanced furnace (HITAF) for power generation. The effort is focused on providing preliminary evaluations of key mechanical properties required of ceramic materials for this application. The critical properties studied include fast fracture strength distribution at room temperature and two elevated temperatures, any trends in slow crack growth (SCG) susceptibility at elevated temperatures, and preliminary creep behavior. In addition residual fast fracture strength of a limited number of specimens corroded in a coal ash environment will be evaluated at a later stage in the project.

  8. Materials support for HITAF

    SciTech Connect

    Breder, K.; Parten, R.J.; Lin, H.T.

    1996-06-01

    The purpose of this project is to compare structural ceramic materials proposed for use in the air heater of a coal fired high temperature furnace (HITAF) for power generation. This new generation of coal fired power plants with increased efficiency, fewer emissions and lower costs are currently being developed under the Combustion 2000 program funded by Pittsburgh Energy Technology Center (PETC). Large improvements in efficiencies will require a change to combined cycles that employ gas turbines and steam turbines (Brayton Cycle) instead of exclusive reliance on steam turbines. Extremely high temperature working fluid is required to boost the efficiency, and the result is that the power plant sub-systems will be exposed to much more corrosive environments than in the present systems. The uses of ceramic heat exchangers are being investigated for those new power plants because of the potential for producing a clean, hot working fluid for the gas turbine.

  9. Additive manufacturing of materials: Opportunities and challenges

    DOE PAGESBeta

    Babu, Sudarsanam Suresh; Love, Lonnie J.; Dehoff, Ryan R.; Peter, William H.; Watkins, Thomas R.; Pannala, Sreekanth

    2015-11-01

    Additive manufacturing (also known as 3D printing) is considered a disruptive technology for producing components with topologically optimized complex geometries as well as functionalities that are not achievable by traditional methods. The realization of the full potential of 3D printing is stifled by a lack of computational design tools, generic material feedstocks, techniques for monitoring thermomechanical processes under in situ conditions, and especially methods for minimizing anisotropic static and dynamic properties brought about by microstructural heterogeneity. In this paper, we discuss the role of interdisciplinary research involving robotics and automation, process control, multiscale characterization of microstructure and properties, and high-performancemore » computational tools to address each of these challenges. In addition, emerging pathways to scale up additive manufacturing of structural materials to large sizes (>1 m) and higher productivities (5–20 kg/h) while maintaining mechanical performance and geometrical flexibility are also discussed.« less

  10. Additive manufacturing of materials: Opportunities and challenges

    SciTech Connect

    Babu, Sudarsanam Suresh; Love, Lonnie J.; Dehoff, Ryan R.; Peter, William H.; Watkins, Thomas R.; Pannala, Sreekanth

    2015-11-01

    Additive manufacturing (also known as 3D printing) is considered a disruptive technology for producing components with topologically optimized complex geometries as well as functionalities that are not achievable by traditional methods. The realization of the full potential of 3D printing is stifled by a lack of computational design tools, generic material feedstocks, techniques for monitoring thermomechanical processes under in situ conditions, and especially methods for minimizing anisotropic static and dynamic properties brought about by microstructural heterogeneity. In this paper, we discuss the role of interdisciplinary research involving robotics and automation, process control, multiscale characterization of microstructure and properties, and high-performance computational tools to address each of these challenges. In addition, emerging pathways to scale up additive manufacturing of structural materials to large sizes (>1 m) and higher productivities (5–20 kg/h) while maintaining mechanical performance and geometrical flexibility are also discussed.

  11. Additive manufacturing of biologically-inspired materials.

    PubMed

    Studart, André R

    2016-01-21

    Additive manufacturing (AM) technologies offer an attractive pathway towards the fabrication of functional materials featuring complex heterogeneous architectures inspired by biological systems. In this paper, recent research on the use of AM approaches to program the local chemical composition, structure and properties of biologically-inspired materials is reviewed. A variety of structural motifs found in biological composites have been successfully emulated in synthetic systems using inkjet-based, direct-writing, stereolithography and slip casting technologies. The replication in synthetic systems of design principles underlying such structural motifs has enabled the fabrication of lightweight cellular materials, strong and tough composites, soft robots and autonomously shaping structures with unprecedented properties and functionalities. Pushing the current limits of AM technologies in future research should bring us closer to the manufacturing capabilities of living organisms, opening the way for the digital fabrication of advanced materials with superior performance, lower environmental impact and new functionalities. PMID:26750617

  12. Microstructural Control of Additively Manufactured Metallic Materials

    NASA Astrophysics Data System (ADS)

    Collins, P. C.; Brice, D. A.; Samimi, P.; Ghamarian, I.; Fraser, H. L.

    2016-07-01

    In additively manufactured (AM) metallic materials, the fundamental interrelationships that exist between composition, processing, and microstructure govern these materials’ properties and potential improvements or reductions in performance. For example, by using AM, it is possible to achieve highly desirable microstructural features (e.g., highly refined precipitates) that could not otherwise be achieved by using conventional approaches. Simultaneously, opportunities exist to manage macro-level microstructural characteristics such as residual stress, porosity, and texture, the last of which might be desirable. To predictably realize optimal microstructures, it is necessary to establish a framework that integrates processing variables, alloy composition, and the resulting microstructure. Although such a framework is largely lacking for AM metallic materials, the basic scientific components of the framework exist in literature. This review considers these key components and presents them in a manner that highlights key interdependencies that would form an integrated framework to engineer microstructures using AM.

  13. Additional Support Needs Policy in Scotland: Challenging or Reinforcing Social Inequality?

    ERIC Educational Resources Information Center

    Riddell, Sheila; Weedon, Elisabet

    2016-01-01

    This paper focuses on Scottish policy on additional support needs and its material outcomes. The central question addressed is the extent to which the Scottish additional support needs system undermines or reinforces existing social and economic inequalities. Administrative data highlight the inflation of the additional support needs category,…

  14. Infrared Database for Process Support Materials

    NASA Technical Reports Server (NTRS)

    Bennett, K. E.; Boothe, R. E.; Burns, H. D.

    2003-01-01

    Process support materials' compatibility with cleaning processes is critical to ensure final hardware cleanliness and that performance requirements are met. Previous discovery of potential contaminants in process materials shows the need for incoming materials testing and establishment of a process materials database. The Contamination Control Team of the Materials, Processes, and Manufacturing (MP&M) Department at Marshall Space Flight Center (MSFC) has initiated the development of such an infrared (IR) database, called the MSFC Process Materials IR database, of the common process support materials used at MSFC. These process support materials include solvents, wiper cloths, gloves, bagging materials, etc. Testing includes evaluation of the potential of gloves, wiper cloths, and other items to transfer contamination to handled articles in the absence of solvent exposure, and the potential for solvent exposure to induce material degradation. This Technical Memorandum (TM) summarizes the initial testing completed through December 2002. It is anticipated that additional testing will be conducted with updates provided in future TMs.Materials were analyzed using two different IR techniques: (1) Dry transference and (2) liquid extraction testing. The first of these techniques utilized the Nicolet Magna 750 IR spectrometer outfitted with a horizontal attenuated total reflectance (HATR) crystal accessory. The region from 650 to 4,000 wave numbers was analyzed, and 50 scans were performed per IR spectrum. A dry transference test was conducted by applying each sample with hand pressure to the HATR crystal to first obtain a spectrum of the parent material. The material was then removed from the HATR crystal and analyzed to determine the presence of any residues. If volatile, liquid samples were examined both prior to and following evaporation.The second technique was to perform an extraction test with each sample in five different solvents.Once the scans were complete for

  15. Electrostatic Levitation for Studies of Additive Manufactured Materials

    NASA Technical Reports Server (NTRS)

    SanSoucie, Michael P.; Rogers, Jan R.; Tramel, Terri

    2014-01-01

    The electrostatic levitation (ESL) laboratory at NASA's Marshall Space Flight Center is a unique facility for investigators studying high temperature materials. The laboratory boasts two levitators in which samples can be levitated, heated, melted, undercooled, and resolidified. Electrostatic levitation minimizes gravitational effects and allows materials to be studied without contact with a container or instrumentation. The lab also has a high temperature emissivity measurement system, which provides normal spectral and normal total emissivity measurements at use temperature. The ESL lab has been instrumental in many pioneering materials investigations of thermophysical properties, e.g., creep measurements, solidification, triggered nucleation, and emissivity at high temperatures. Research in the ESL lab has already led to the development of advanced high temperature materials for aerospace applications, coatings for rocket nozzles, improved medical and industrial optics, metallic glasses, ablatives for reentry vehicles, and materials with memory. Modeling of additive manufacturing materials processing is necessary for the study of their resulting materials properties. In addition, the modeling of the selective laser melting processes and its materials property predictions are also underway. Unfortunately, there is very little data for the properties of these materials, especially of the materials in the liquid state. Some method to measure thermophysical properties of additive manufacturing materials is necessary. The ESL lab is ideal for these studies. The lab can provide surface tension and viscosity of molten materials, density measurements, emissivity measurements, and even creep strength measurements. The ESL lab can also determine melting temperature, surface temperatures, and phase transition temperatures of additive manufactured materials. This presentation will provide background on the ESL lab and its capabilities, provide an approach to using the ESL

  16. 9. DETAIL OF FIXED SUPPORT (A RECENT ADDITION THE ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    9. DETAIL OF FIXED SUPPORT (A RECENT ADDITION -- THE BRIDGE IS NO LONGER MOVEABLE) AND LOWER CHORD OF THROUGH TRUSS, LOOKING SOUTH - Romeo Road, Sanitary & Ship Canal Bridge, Spanning Sanitary & Ship Canal, Romeoville, Will County, IL

  17. 15 CFR 930.127 - Briefs and supporting materials.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... material as the appellant deems necessary for consideration by the Secretary. The State agency (or... additional documentation and material as the State agency (or appellant on reply) deems necessary for... in the appendix as much of the supporting documentation and material as any party deems necessary...

  18. Computer Maintenance Operations Center (CMOC), additional computer support equipment ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    Computer Maintenance Operations Center (CMOC), additional computer support equipment - Beale Air Force Base, Perimeter Acquisition Vehicle Entry Phased-Array Warning System, Techinical Equipment Building, End of Spencer Paul Road, north of Warren Shingle Road (14th Street), Marysville, Yuba County, CA

  19. Additional Support Needs Reforms and Social Justice in Scotland

    ERIC Educational Resources Information Center

    Riddell, Sheila; Stead, Joan; Weedon, Elisabet; Wright, Kevin

    2010-01-01

    New additional support-needs legislation in Scotland sought to recognise the way in which poverty, as well as individual impairment, contribute to the creation of children's difficulties in learning. As well as identifying a wider range of needs, the legislation sought to provide parents, irrespective of social background, with more powerful means…

  20. Interactions between sealing materials and lubricating oil additives

    SciTech Connect

    Winkenbach, R.; Von Arndt, E.M.; Mindermann, H.

    1987-01-01

    Due to the increasingly higher application demands, engine and transmission manufactures are today using lubrication oils with more and more additives. The result is that seal materials are being damaged when exposed to such conditions and such additives. This paper shows the effects of basic oils with, and without, additives on elastomeric materials such as NBR, ACM, MVQ and FPM.

  1. Supporting student nurses in practice with additional online communication tools.

    PubMed

    Morley, Dawn A

    2014-01-01

    Student nurses' potential isolation and difficulties of learning on placement have been well documented and, despite attempts to make placement learning more effective, evidence indicates the continuing schism between formal learning at university and situated learning on placement. First year student nurses, entering placement for the first time, are particularly vulnerable to the vagaries of practice. During 2012 two first year student nurse seminar groups (52 students) were voluntarily recruited for a mixed method study to determine the usage of additional online communication support mechanisms (Facebook, wiki, an email group and traditional methods of support using individual email or phone) while undertaking their first five week clinical placement. The study explores the possibility of strengthening clinical learning and support by promoting the use of Web 2.0 support groups for student nurses. Results indicate a high level of interactivity in both peer and academic support in the use of Facebook and a high level of interactivity in one wiki group. Students' qualitative comments voice an appreciation of being able to access university and peer support whilst working individually on placement. Recommendations from the study challenge universities to use online communication tools already familiar to students to complement the support mechanisms that exist for practice learning. This is tempered by recognition of the responsibility of academics to ensure their students are aware of safe and effective online communication. PMID:23871299

  2. Material Selection for Cryogenic Support Structures

    NASA Astrophysics Data System (ADS)

    Kramer, Erik; Kellaris, Nicholas; Daal, Miguel; Sadoulet, Bernard; Golwala, Sunil; Hollister, Matthew

    2014-09-01

    Design specifications for the support structures of low temperature instrumentation often call for low thermal conductivity between temperature stages, high stiffness, and specific load bearing capabilities. While overall geometric design plays an important role in both overall stiffness and heat conduction between stages, material selection can affect a structure's properties significantly. In this contribution, we suggest and compare several alternative materials to the current standard materials for building cryogenic support structures.

  3. Longevity of emplacement drift ground support materials

    SciTech Connect

    Tang, David

    2000-04-01

    The purpose of this analysis is to evaluate the factors affecting the longevity of emplacement drift ground support materials and to develop a basis for the selection of materials for ground support that will function throughout the preclosure period of a potential repository at Yucca Mountain. The Development Plan (DP) for this analysis is given in Longevity of Emplacement Drift Ground Support Materials (CRWMS M and O 1999a). The objective of this analysis is to update the previous analysis (CRWMS M and O 2000a) to account for related changes in the Ground Control System Description Document (CRWMS M and O 2000b), the Monitored Geologic Repository Project Description Document (CRWMS M and O 1999b), and in environmental conditions, and to provide updated information on candidate ground support materials.

  4. Materials processing in space program support

    NASA Technical Reports Server (NTRS)

    Glicksman, Martin; Vanalstine, James M.

    1987-01-01

    Activities in support of NASA's Materials Processing in Space (MPS) program are reported. The overall task of the MPS project support contract was to provide the organization and administration of colloquiums, science reviews, workshops, technical meetings, bibliographic services, and visiting scientist programs. The research objectives and accomplishments of the University Space Research Association visiting scientist team are also summarized.

  5. Longevity of Emplacement Drift Ground Support Materials

    SciTech Connect

    D. Tang

    2000-01-07

    The purpose of this analysis is to evaluate the factors affecting the longevity of emplacement drift ground support materials and to develop a basis for selection of materials for ground support that will function throughout the preclosure period. The Development Plan (DP) for this analysis is given in CRWMS M&O (Civilian Radioactive Waste Management System Management and Operating Contractor) (1999a). The candidate materials for ground support are steel (carbon steel, ductile cast iron, galvanized steel, and stainless steel, etc.) and cement. Steel will mainly be used for steel sets, lagging, channels, rock bolts, and wire mesh. Cement usage is only considered in the case of grouted rock bolts. The candidate materials for the invert structure are steel and crushed rock ballast. The materials shall be evaluated for the repository emplacement drift environment under a specific thermal loading condition based on the proposed License Application Design Selection (LADS) design. The analysis consists of the following tasks: (1) Identify factors affecting the longevity of ground control materials for use in emplacement drifts. (2) Review existing documents concerning behavior of candidate ground control materials during the preclosure period. The major criteria to be considered for steel are mechanical and thermal properties, and durability, of which corrosion is the most important concern. (3) Evaluate the available results and develop recommendations for material(s) to be used.

  6. Longevity of Emplacement Drift Ground Support Materials

    SciTech Connect

    Tang, David H.

    2001-05-30

    The purpose of this analysis is to evaluate the factors affecting the longevity of emplacement drift ground support materials and to develop a basis for the selection of materials for ground support that will function throughout the preclosure period of a potential repository at Yucca Mountain. REV 01 ICN 01 of this analysis is developed in accordance with AP-3.10Q, Analyses and Models, Revision 2, ICN 4, and prepared in accordance with the Technical Work Plan for Subsurface Design Section FY 01 Work Activities (CRWMS M&O 2001a). The objective of this analysis is to update the previous analysis (CRWMS M&O 2000a) to account for related changes in the Ground Control System Description Document (CRWMS M&O 2000b), the Monitored Geologic Repository Project Description Document, which is included in the Requirements and Criteria for Implementing a Repository Design that can be Operated Over a Range of Thermal Modes (BSC 2001), input information, and in environmental conditions, and to provide updated information on candidate ground support materials. Candidate materials for ground support are carbon steel and cement grout. Steel is mainly used for steel sets, lagging, channel, rock bolts, and wire mesh. Cement grout is only considered in the case of grouted rock bolts. Candidate materials for the emplacement drift invert are carbon steel and granular natural material. Materials are evaluated for the repository emplacement drift environment based on the updated thermal loading condition and waste package design. The analysis consists of the following tasks: (1) Identify factors affecting the longevity of ground support materials for use in emplacement drifts. (2) Review existing documents concerning the behavior of candidate ground support materials during the preclosure period. (3) Evaluate impacts of temperature and radiation effects on mechanical and thermal properties of steel. Assess corrosion potential of steel at emplacement drift environment. (4) Evaluate factors

  7. Thermodynamically consistent microstructure prediction of additively manufactured materials

    NASA Astrophysics Data System (ADS)

    Smith, Jacob; Xiong, Wei; Cao, Jian; Liu, Wing Kam

    2016-03-01

    Additive manufacturing has risen to the top of research interest in advanced manufacturing in recent years due to process flexibility, achievability of geometric complexity, and the ability to locally modify and optimize materials. The present work is focused on providing an approach for incorporating thermodynamically consistent properties and microstructure evolution for non-equilibrium supercooling, as observed in additive manufacturing processes, into finite element analysis. There are two primary benefits of this work: (1) the resulting prediction is based on the material composition and (2) the nonlinear behavior caused by the thermodynamic properties of the material during the non-equilibrium solution is accounted for with extremely high resolution. The predicted temperature response and microstructure evolution for additively manufactured stainless steel 316L using standard handbook-obtained thermodynamic properties are compared with the thermodynamic properties calculated using the CALculation of PHAse Diagrams (CALPHAD) approach. Data transfer from the CALPHAD approach to finite element analysis is discussed.

  8. Material Characterization of Additively Manufactured Components for Rocket Propulsion

    NASA Technical Reports Server (NTRS)

    Carter, Robert; Draper, Susan; Locci, Ivan; Lerch, Bradley; Ellis, David; Senick, Paul; Meyer, Michael; Free, James; Cooper, Ken; Jones, Zachary

    2015-01-01

    To advance Additive Manufacturing (AM) technologies for production of rocket propulsion components the NASA Glenn Research Center (GRC) is applying state of the art characterization techniques to interrogate microstructure and mechanical properties of AM materials and components at various steps in their processing. The materials being investigated for upper stage rocket engines include titanium, copper, and nickel alloys. Additive manufacturing processes include laser powder bed, electron beam powder bed, and electron beam wire fed processes. Various post build thermal treatments, including Hot Isostatic Pressure (HIP), have been studied to understand their influence on microstructure, mechanical properties, and build density. Micro-computed tomography, electron microscopy, and mechanical testing in relevant temperature environments has been performed to develop relationships between build quality, microstructure, and mechanical performance at temperature. A summary of GRCs Additive Manufacturing roles and experimental findings will be presented.

  9. Materials Characterization of Additively Manufactured Components for Rocket Propulsion

    NASA Technical Reports Server (NTRS)

    Carter, Robert; Draper, Susan; Locci, Ivan; Lerch, Bradley; Ellis, David; Senick, Paul; Meyer, Michael; Free, James; Cooper, Ken; Jones, Zachary

    2015-01-01

    To advance Additive Manufacturing (AM) technologies for production of rocket propulsion components the NASA Glenn Research Center (GRC) is applying state of the art characterization techniques to interrogate microstructure and mechanical properties of AM materials and components at various steps in their processing. The materials being investigated for upper stage rocket engines include titanium, copper, and nickel alloys. Additive manufacturing processes include laser powder bed, electron beam powder bed, and electron beam wire fed processes. Various post build thermal treatments, including Hot Isostatic Pressure (HIP), have been studied to understand their influence on microstructure, mechanical properties, and build density. Micro-computed tomography, electron microscopy, and mechanical testing in relevant temperature environments has been performed to develop relationships between build quality, microstructure, and mechanical performance at temperature. A summary of GRC's Additive Manufacturing roles and experimental findings will be presented.

  10. Overview of Materials Qualification Needs for Metal Additive Manufacturing

    NASA Astrophysics Data System (ADS)

    Seifi, Mohsen; Salem, Ayman; Beuth, Jack; Harrysson, Ola; Lewandowski, John J.

    2016-03-01

    This overview highlights some of the key aspects regarding materials qualification needs across the additive manufacturing (AM) spectrum. AM technology has experienced considerable publicity and growth in the past few years with many successful insertions for non-mission-critical applications. However, to meet the full potential that AM has to offer, especially for flight-critical components (e.g., rotating parts, fracture-critical parts, etc.), qualification and certification efforts are necessary. While development of qualification standards will address some of these needs, this overview outlines some of the other key areas that will need to be considered in the qualification path, including various process-, microstructure-, and fracture-modeling activities in addition to integrating these with lifing activities targeting specific components. Ongoing work in the Advanced Manufacturing and Mechanical Reliability Center at Case Western Reserve University is focusing on fracture and fatigue testing to rapidly assess critical mechanical properties of some titanium alloys before and after post-processing, in addition to conducting nondestructive testing/evaluation using micro-computerized tomography at General Electric. Process mapping studies are being conducted at Carnegie Mellon University while large area microstructure characterization and informatics (EBSD and BSE) analyses are being conducted at Materials Resources LLC to enable future integration of these efforts via an Integrated Computational Materials Engineering approach to AM. Possible future pathways for materials qualification are provided.

  11. A Public Opinion Survey on Correctional Education: Does Additional Information on Efficacy Lead to Additional Support?

    ERIC Educational Resources Information Center

    Waterland, Keri Lynn

    2009-01-01

    Though much research has been done on the efficacy of correctional education on reducing recidivism rates for prison inmates, there is little research on the effect that information about the efficacy of correctional education has on public opinion. This study examined whether providing additional information regarding the efficacy of correctional…

  12. Additional support for the TDK/MABL computer program

    NASA Technical Reports Server (NTRS)

    Nickerson, G. R.; Dunn, Stuart S.

    1993-01-01

    An advanced version of the Two-Dimensional Kinetics (TDK) computer program was developed under contract and released to the propulsion community in early 1989. Exposure of the code to this community indicated a need for improvements in certain areas. In particular, the TDK code needed to be adapted to the special requirements imposed by the Space Transportation Main Engine (STME) development program. This engine utilizes injection of the gas generator exhaust into the primary nozzle by means of a set of slots. The subsequent mixing of this secondary stream with the primary stream with finite rate chemical reaction can have a major impact on the engine performance and the thermal protection of the nozzle wall. In attempting to calculate this reacting boundary layer problem, the Mass Addition Boundary Layer (MABL) module of TDK was found to be deficient in several respects. For example, when finite rate chemistry was used to determine gas properties, (MABL-K option) the program run times became excessive because extremely small step sizes were required to maintain numerical stability. A robust solution algorithm was required so that the MABL-K option could be viable as a rocket propulsion industry design tool. Solving this problem was a primary goal of the phase 1 work effort.

  13. Exploration Life Support: ELS Functions and Materials Interfaces

    NASA Technical Reports Server (NTRS)

    Duffield, Bruce

    2007-01-01

    This viewgraph presentation reviews some of the processes used to develop life support systems, and how that supports the materials that are selected. Of particular concern in the selection of materials is flammability.

  14. ANALYSIS OF MPC ACCESS REQUIREMENTS FOR ADDITION OF FILLER MATERIALS

    SciTech Connect

    W. Wallin

    1996-09-03

    This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development Department (WPDD) in response to a request received via a QAP-3-12 Design Input Data Request (Ref. 5.1) from WAST Design (formerly MRSMPC Design). The request is to provide: Specific MPC access requirements for the addition of filler materials at the MGDS (i.e., location and size of access required). The objective of this analysis is to provide a response to the foregoing request. The purpose of this analysis is to provide a documented record of the basis for the response. The response is stated in Section 8 herein. The response is based upon requirements from an MGDS perspective.

  15. Multiscale and Multiphysics Modeling of Additive Manufacturing of Advanced Materials

    NASA Technical Reports Server (NTRS)

    Liou, Frank; Newkirk, Joseph; Fan, Zhiqiang; Sparks, Todd; Chen, Xueyang; Fletcher, Kenneth; Zhang, Jingwei; Zhang, Yunlu; Kumar, Kannan Suresh; Karnati, Sreekar

    2015-01-01

    The objective of this proposed project is to research and develop a prediction tool for advanced additive manufacturing (AAM) processes for advanced materials and develop experimental methods to provide fundamental properties and establish validation data. Aircraft structures and engines demand materials that are stronger, useable at much higher temperatures, provide less acoustic transmission, and enable more aeroelastic tailoring than those currently used. Significant improvements in properties can only be achieved by processing the materials under nonequilibrium conditions, such as AAM processes. AAM processes encompass a class of processes that use a focused heat source to create a melt pool on a substrate. Examples include Electron Beam Freeform Fabrication and Direct Metal Deposition. These types of additive processes enable fabrication of parts directly from CAD drawings. To achieve the desired material properties and geometries of the final structure, assessing the impact of process parameters and predicting optimized conditions with numerical modeling as an effective prediction tool is necessary. The targets for the processing are multiple and at different spatial scales, and the physical phenomena associated occur in multiphysics and multiscale. In this project, the research work has been developed to model AAM processes in a multiscale and multiphysics approach. A macroscale model was developed to investigate the residual stresses and distortion in AAM processes. A sequentially coupled, thermomechanical, finite element model was developed and validated experimentally. The results showed the temperature distribution, residual stress, and deformation within the formed deposits and substrates. A mesoscale model was developed to include heat transfer, phase change with mushy zone, incompressible free surface flow, solute redistribution, and surface tension. Because of excessive computing time needed, a parallel computing approach was also tested. In addition

  16. Staff Data and Materials on Child Support.

    ERIC Educational Resources Information Center

    Congress of the U.S., Washington, DC. Senate Committee on Finance.

    The purpose of Part D of Title IV of the Social Security Act is to enforce the support obligations owed by absent parents to their children, locate absent parents, establish paternity and obtain child support from parents. This Senate report provides an overview of the child support enforcement program and 23 tables of statistical data. Many of…

  17. Timing of Getter Material Addition in Cementitious Wasteforms

    NASA Astrophysics Data System (ADS)

    Lawter, A.; Qafoku, N. P.; Asmussen, M.; Neeway, J.; Smith, G. L.

    2015-12-01

    A cementitious waste form, Cast Stone, is being evaluated as a possible supplemental immobilization technology for the Hanford sites's low activity waste (LAW), which contains radioactive 99Tc and 129I, as part of the tank waste cleanup mission. Cast Stone is made of a dry blend 47% blast furnace slag, 45% fly ash, and 8% ordinary Portland cement, mixed with a low-activity waste (LAW). To improve the retention of Tc and/or I in Cast Stone, materials with a high affinity for Tc and/or I, termed "getters," can be added to provide a stable domain for the radionuclides of concern. Previous testing conducted with a variety of getters has identified Tin(II)-Apatite and Silver Exchanged Zeolite as promising candidates for Tc and I, respectively. Investigation into the sequence in which getters are added to Cast Stone was performed following two methods: 1) adding getters to the Cast Stone dry blend, and then mixing with liquid waste, and 2) adding getters to the liquid waste first, followed by addition of the Cast Stone dry blend. Cast Stone monolith samples were prepared with each method and leach tests, following EPA method 1315, were conducted in either distilled water or simulated vadose zone porewater for a period of up to 63 days. The leachate was analyzed for Tc, I, Na, NO3-, NO2- and Cr with ICP-MS, ICP-OES and ion chromatography and the results indicated that the Cast Stone with getter addition in the dry blend mix (method 1) has lower rates of Tc and I leaching. The mechanisms of radionuclide release from the Cast Stone were also investigated with a variety of solid phase characterization techniques of the monoliths before and after leaching, such as XRD, SEM/EDS, TEM/SAED and other spectroscopic techniques.

  18. Additive manufacturing of stretchable tactile sensors: Processes, materials, and applications

    NASA Astrophysics Data System (ADS)

    Vatani, Morteza

    3D printing technology is becoming more ubiquitous every day especially in the area of smart structures. However, fabrication of multi-material, functional, and smart structures is problematic because of the process and material limitations. This thesis sought to develop a Direct Print Photopolymerization (DPP) fabrication technique that appreciably extends the manufacturing space for the 3D smart structures. This method employs a robotically controlled micro-extrusion of a filament equipped with a photopolymerization process. The ability to use polymers and ultimately their nanocomposites in this process is the advantage of the proposed process over the current fabrication methods in the fabrication of 3D structures featuring mechanical, physical, and electrical functionalities. In addition, this study focused to develop a printable, conductive, and stretchable nanocomposite based on a photocurable and stretchable liquid resin filled with multi-walled carbon nanotubes (MWNTs). This nanocomposite exhibited piezoresistivity, means its resistivity changes as it deforms. This property is a favorable factor in developing resistance based tactile sensors. They were also able to resist high tensile strains while they showed conductivity. Furthermore, this study offered a possible and low-cost method to have a unique and highly stretchable pressure sensitive polymer. This disruptive pressure sensitive polymer composed of an Ionic Liquid (IL) and a stretchable photopolymer embedded between two layers of Carbon Nanotube (CNTs) based stretchable electrodes. The developed IL-polymer showed both field effect property and piezoresistivity that can detect large tensile strains up 30%. In summary, this research study focused to present feasible methods and materials for printing a 3D smart structure especially in the context of flexible tactile sensors. This study provides a foundation for the future efforts in fabrication of skin like tactile sensors in three-dimensional motifs

  19. Cyclic material properties tests supporting elastic-plastic analysis development

    SciTech Connect

    Hodge, S.C.; Minicucci, J.M.

    1996-11-01

    Correlation studies have shown that hardening models currently available in the ABAQUS finite element code (isotropic, kinematic) do not accurately capture the inelastic strain reversals that occur due to structural rebounding from a rapidly applied transient dynamic load. The purpose of the Cyclic Material properties Test program was to obtain response data for the first several cycles of inelastic strain reversal from a cyclic properties test. This data is needed to develop elastic-plastic analysis methods that can accurately predict strains and permanent sets in structures due to rapidly applied transient dynamic loading. Test specimens were cycled at inelastic strain levels typical of rapidly applied transient dynamic analyses (0.5% to 4.0%). In addition to the inelastic response data, cyclic material properties for high yield strength (80 ksi) steel were determined including a cyclic stress-strain curve for a stabilized specimen. Two test methods, the Incremental Step method and the Companion specimen Method, were sued to determine cyclic properties. The incrementally decreasing strain amplitudes in the first loading block of the Incremental Step method test is representative of the response of structures subjected to rapidly applied transient dynamic loads. The inelastic strain history data generated by this test program will be used to support development of a material model that can accurately predict inelastic material behavior including inelastic strain reversals. Additionally, this data can be used to verify material model enhancements to elastic-plastic finite element analysis codes.

  20. Effective Mechanical Properties of Lattice Material Fabricated by Material Extrusion Additive Manufacturing

    SciTech Connect

    Park, Sang-In; Choi, Seung-kyum; Rosen, David W; Duty, Chad E

    2014-01-01

    In this paper, a two-step homogenization method is proposed and implemented for evaluating effective mechanical properties of lattice structured material fabricated by the material extrusion additive manufacturing process. In order to consider the characteristics of the additive manufacturing process in estimation procedures, the levels of scale for homogenization are divided into three stages the levels of layer deposition, structural element, and lattice structure. The method consists of two transformations among stages. In the first step, the transformation between layer deposition and structural element levels is proposed to find the geometrical and material effective properties of structural elements in the lattice structure. In the second step, the method to estimate effective mechanical properties of lattice material is presented, which uses a unit cell and is based on the discretized homogenization method for periodic structure. The method is implemented for cubic lattice structure and compared to experimental results for validation purposes.

  1. The effectiveness of Additional Literacy Support (ALS) in Years 3 and 4.

    PubMed

    Bunn, Tim

    2008-08-01

    This study compared the progress in reading and spelling of 256 children in 11 classes in 9 English primary schools in Years 3 and 4, and a partially overlapping sample of 126 children who received additional help with literacy during 1 year. Teachers and teaching assistants used either Additional Literacy Support (ALS), a highly structured set of small group teaching materials devised by the English National Literacy Strategy, or a wide variety of other materials including other published intervention programmes, reading scheme-based, computer-based and individually designed interventions, or a combination of ALS and other interventions. The influence of a broad range of contextual factors were investigated, especially whether children's qualities, school factors such as socio-economic status and class size, and delivery differences made significant differences to the outcomes of the different interventions. The study used a naturalistic quasi-experimental design, in which teachers were asked to record details of their children and interventions without altering their professional decisions, which has not been used before in investigating literacy difficulties in context. ALS was marginally more effective than other interventions in the majority of classes, but was clearly superior in value for money terms. Children's qualities did not appear to affect outcomes. Although children receiving additional help made better than average progress, overall catch-up was limited, especially in spelling. PMID:18697191

  2. 24 CFR 574.330 - Additional standards for short-term supported housing.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... Uses of Grant Funds § 574.330 Additional standards for short-term supported housing. Short-term... 24 Housing and Urban Development 3 2013-04-01 2013-04-01 false Additional standards for short-term supported housing. 574.330 Section 574.330 Housing and Urban Development Regulations Relating to Housing...

  3. 24 CFR 574.330 - Additional standards for short-term supported housing.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Uses of Grant Funds § 574.330 Additional standards for short-term supported housing. Short-term... 24 Housing and Urban Development 3 2010-04-01 2010-04-01 false Additional standards for short-term supported housing. 574.330 Section 574.330 Housing and Urban Development Regulations Relating to Housing...

  4. 24 CFR 574.330 - Additional standards for short-term supported housing.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... Uses of Grant Funds § 574.330 Additional standards for short-term supported housing. Short-term... 24 Housing and Urban Development 3 2011-04-01 2010-04-01 true Additional standards for short-term supported housing. 574.330 Section 574.330 Housing and Urban Development Regulations Relating to Housing...

  5. 24 CFR 574.330 - Additional standards for short-term supported housing.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... Uses of Grant Funds § 574.330 Additional standards for short-term supported housing. Short-term... 24 Housing and Urban Development 3 2014-04-01 2013-04-01 true Additional standards for short-term supported housing. 574.330 Section 574.330 Housing and Urban Development Regulations Relating to Housing...

  6. Additives

    NASA Technical Reports Server (NTRS)

    Smalheer, C. V.

    1973-01-01

    The chemistry of lubricant additives is discussed to show what the additives are chemically and what functions they perform in the lubrication of various kinds of equipment. Current theories regarding the mode of action of lubricant additives are presented. The additive groups discussed include the following: (1) detergents and dispersants, (2) corrosion inhibitors, (3) antioxidants, (4) viscosity index improvers, (5) pour point depressants, and (6) antifouling agents.

  7. Support materials for PEMFC and DMFC electrocatalysts-A review

    NASA Astrophysics Data System (ADS)

    Sharma, Surbhi; Pollet, Bruno G.

    2012-06-01

    Polymer electrolyte membrane fuel cells (PEMFC) and direct methanol fuel cells (DMFC) have found a wide variety of commercial applications. Their performance is essentially governed by the electrocatalyst support materials as they strongly influence the electrocatalyst performance, durability and efficiency. It is well known that carbonaceous support materials suffer from carbon corrosion (oxidation) especially at high potentials over time and thus alternative low-cost, high-performing and non-corrosive electrocatalyst support materials are urgently required. This review highlights the performance and issues associated with a variety of carbon based materials such as carbon nanotubes (CNT), carbon nanofibers (CNF), mesoporous carbon and graphene as well as non-carbonaceous based materials, e.g. titania, indium oxides, alumina, silica and tungsten oxide and carbide, ceria, zirconia nanostructures and conducting polymers catalyst support materials. Comparisons and advantages and disadvantages of the various supports are clearly described in this review.

  8. Growth of CZT using additionally zone-refined raw materials

    NASA Astrophysics Data System (ADS)

    Knuteson, David J.; Berghmans, Andre; Kahler, David; Wagner, Brian; King, Matthew; Mclaughlin, Sean; Bolotnikov, Aleksey; James, Ralph; Singh, Narsingh B.

    2012-10-01

    Results will be presented for the growth of CdZnTe by the low pressure Bridgman growth technique. To decrease deeplevel trapping and improve detector performance, high purity commercial raw materials will be further zone refined to reduce impurities. The purified materials will then be compounded into a charge for crystal growth. The crystals will be grown in the programmable multi-zone furnace (PMZF), which was designed and built at Northrop Grumman's Bethpage facility to grow CZT on Space Shuttle missions. Results of the purification and crystal growth will be presented as well as characterization of crystal quality and detector performance.

  9. Fabrication of Turbine Disk Materials by Additive Manufacturing

    NASA Technical Reports Server (NTRS)

    Sudbrack, Chantal; Bean, Quincy A.; Cooper, Ken; Carter, Robert; Semiatin, S. Lee; Gabb, Tim

    2014-01-01

    Precipitation-strengthened, nickel-based superalloys are widely used in the aerospace and energy industries due to their excellent environmental resistance and outstanding mechanical properties under extreme conditions. Powder-bed additive manufacturing (AM) technologies offer the potential to revolutionize the processing of superalloy turbine components by eliminating the need for extensive inventory or expensive legacy tooling. Like selective laser melting (SLM), electron beam melting (EBM) constructs three-dimensional dense components layer-by-layer by melting and solidification of atomized, pre-alloyed powder feedstock within 50-200 micron layers. While SLM has been more widely used for AM of nickel alloys like 718, EBM offers several distinct advantages, such as less retained residual stress, lower risk of contamination, and faster build rates with multiple-electron-beam configurations. These advantages are particularly attractive for turbine disks, for which excessive residual stress and contamination can shorten disk life during high-temperature operation. In this presentation, we will discuss the feasibility of fabricating disk superalloy components using EBM AM. Originally developed using powder metallurgy forging processing, disk superalloys contain a higher refractory content and precipitate volume fraction than alloy 718, thus making them more prone to thermal cracking during AM. This and other challenges to produce homogeneous builds with desired properties will be presented. In particular, the quality of lab-scale samples fabricated via a design of experiments, in which the beam current, build temperature, and beam velocity were varied, will be summarized. The relationship between processing parameters, microstructure, grain orientation, and mechanical response will be discussed.

  10. Influence of modifying additives on the electronic state of supported palladium

    NASA Astrophysics Data System (ADS)

    Pestryakov, A. N.; Lunin, V. V.; Fuentes, S.; Bogdanchikova, N.; Barrera, A.

    2003-01-01

    The influence of modifying additives of Ce, Zr, La and Cs oxides on the electronic state of palladium supported on γ-Al 2O 3 has been studied by IR-spectroscopy of adsorbed CO, diffuse reflectance UV-visible spectroscopy, X-ray diffraction (XRD) and H 2 chemisorption. The modified supports have been prepared using impregnation, coprecipitation and sol-gel methods. It is established that Ce and Zr oxide additives increase the effective charge of palladium ions whereas La and Cs oxides lower it. The effect of metal-support interaction is stronger in samples prepared by sol-gel than by coprecipitation

  11. The Effectiveness of Additional Literacy Support (ALS) in Years 3 and 4

    ERIC Educational Resources Information Center

    Bunn, Tim

    2008-01-01

    This study compared the progress in reading and spelling of 256 children in 11 classes in 9 English primary schools in Years 3 and 4, and a partially overlapping sample of 126 children who received additional help with literacy during 1 year. Teachers and teaching assistants used either Additional Literacy Support (ALS), a highly structured set of…

  12. Characterization of Effect of Support Structures in Laser Additive Manufacturing of Stainless Steel

    NASA Astrophysics Data System (ADS)

    Järvinen, Jukka-Pekka; Matilainen, Ville; Li, Xiaoyun; Piili, Heidi; Salminen, Antti; Mäkelä, Ismo; Nyrhilä, Olli

    Laser additive manufacturing (LAM) of stainless steel is a layer wisetechnology for fabricating 3D parts from metal powder via selectively melting powder with laser beam. Support structures play a significant role in LAM process as they help to remove heat away from the process and on the other hand hold the work piece in its place. A successful design of support structures can help to achievea building process fast and inexpensive with high quality. Aimof this study was to characterize the usability of two types of support structures: web and tube supports. Purpose of this studywas also to analyze how suitable they are in two industrial application cases: case for dental application and case for jewelry application. It was concluded that the removability of web supports was much better than tube supports. It was noticed that support structures are an important part of LAM process and they strongly affect the manufacturability and the end quality of the part.

  13. Anisotropic microporous supports impregnated with polymeric ion-exchange materials

    DOEpatents

    Friesen, Dwayne; Babcock, Walter C.; Tuttle, Mark

    1985-05-07

    Novel ion-exchange media are disclosed, the media comprising polymeric anisotropic microporous supports containing polymeric ion-exchange or ion-complexing materials. The supports are anisotropic, having small exterior pores and larger interior pores, and are preferably in the form of beads, fibers and sheets.

  14. Anisotropic microporous supports impregnated with polymeric ion-exchange materials

    DOEpatents

    Friesen, D.; Babcock, W.C.; Tuttle, M.

    1985-05-07

    Novel ion-exchange media are disclosed, the media comprising polymeric anisotropic microporous supports containing polymeric ion-exchange or ion-complexing materials. The supports are anisotropic, having small exterior pores and larger interior pores, and are preferably in the form of beads, fibers and sheets. 5 figs.

  15. 15 CFR 930.127 - Briefs and supporting materials.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... material as the appellant deems necessary for consideration by the Secretary. The State agency (or... additional documentation and material as the State agency (or appellant on reply) deems necessary for... appendix). The parties are encouraged to discuss the contents of appellant's appendix in order to...

  16. 15 CFR 930.127 - Briefs and supporting materials.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... material as the appellant deems necessary for consideration by the Secretary. The State agency (or... additional documentation and material as the State agency (or appellant on reply) deems necessary for... appendix). The parties are encouraged to discuss the contents of appellant's appendix in order to...

  17. 15 CFR 930.127 - Briefs and supporting materials.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... material as the appellant deems necessary for consideration by the Secretary. The State agency (or... additional documentation and material as the State agency (or appellant on reply) deems necessary for... appendix). The parties are encouraged to discuss the contents of appellant's appendix in order to...

  18. Carbon nanotube synthesis with different support materials and catalysts

    NASA Astrophysics Data System (ADS)

    Gümüş, Fatih; Yuca, Neslihan; Karatepe, Nilgün

    2013-09-01

    Having remarkable characteristics, carbon nanotubes (CNTs) have attracted a lot of interest. Their mechanical, electrical, thermal and chemical properties make CNTs suitable for several applications such as electronic devices, hydrogen storage, textile, drug delivery etc. CNTs have been synthesized by various methods, such as arc discharge, laser ablation and catalytic chemical vapor deposition (CCVD). In comparison with the other techniques, CCVD is widely used as it offers a promising route for mass production. High capability of decomposing hydrocarbon formation is desired for the selected catalysts. Therefore, transition metals which are in the nanometer scale are the most effective catalysts. The common transition metals that are being used are Fe, Co, Ni and their binary alloys. The impregnation of the catalysts over the support material has a crucial importance for the CNT production. In this study, the influence of the support materials on the catalytic activity of metals was investigated. CNTs have been synthesized over alumina (Al2O3), silica (SiO2) and magnesium oxide (MgO) supported Fe, Co, Fe-Co catalysts. Catalyst - support material combinations have been investigated and optimum values for each were compared. Single walled carbon nanotubes (SWCNTs) were produced at 800°C. The duration of synthesis was 30 minutes for all support materials. The synthesized materials were characterized by thermal gravimetric analysis (TGA), Raman spectroscopy and transmission electron microscopy.

  19. 49 CFR 173.422 - Additional requirements for excepted packages containing Class 7 (radioactive) materials.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... containing Class 7 (radioactive) materials. 173.422 Section 173.422 Transportation Other Regulations Relating... (Radioactive) Materials § 173.422 Additional requirements for excepted packages containing Class 7 (radioactive) materials. An excepted package of Class 7 (radioactive) material that is prepared for shipment under...

  20. 49 CFR 173.422 - Additional requirements for excepted packages containing Class 7 (radioactive) materials.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... containing Class 7 (radioactive) materials. 173.422 Section 173.422 Transportation Other Regulations Relating... (Radioactive) Materials § 173.422 Additional requirements for excepted packages containing Class 7 (radioactive) materials. An excepted package of Class 7 (radioactive) material that is prepared for shipment under...

  1. 49 CFR 173.422 - Additional requirements for excepted packages containing Class 7 (radioactive) materials.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... containing Class 7 (radioactive) materials. 173.422 Section 173.422 Transportation Other Regulations Relating... (Radioactive) Materials § 173.422 Additional requirements for excepted packages containing Class 7 (radioactive) materials. An excepted package of Class 7 (radioactive) material that is prepared for shipment under...

  2. 49 CFR 173.422 - Additional requirements for excepted packages containing Class 7 (radioactive) materials.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... containing Class 7 (radioactive) materials. 173.422 Section 173.422 Transportation Other Regulations Relating... (Radioactive) Materials § 173.422 Additional requirements for excepted packages containing Class 7 (radioactive) materials. An excepted package of Class 7 (radioactive) material that is prepared for shipment under...

  3. 49 CFR 173.422 - Additional requirements for excepted packages containing Class 7 (radioactive) materials.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... containing Class 7 (radioactive) materials. 173.422 Section 173.422 Transportation Other Regulations Relating... (Radioactive) Materials § 173.422 Additional requirements for excepted packages containing Class 7 (radioactive) materials. An excepted package of Class 7 (radioactive) material that is prepared for shipment under...

  4. 36 CFR 1206.86 - What additional materials must I submit with the final narrative report?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... RECORDS COMMISSION Grant Administration § 1206.86 What additional materials must I submit with the final narrative report? You must submit the materials required in the NHPRC grant announcements and in the...

  5. 36 CFR 1206.86 - What additional materials must I submit with the final narrative report?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... RECORDS COMMISSION Grant Administration § 1206.86 What additional materials must I submit with the final narrative report? You must submit the materials required in the NHPRC grant announcements and in the...

  6. 36 CFR 1206.86 - What additional materials must I submit with the final narrative report?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... RECORDS COMMISSION Grant Administration § 1206.86 What additional materials must I submit with the final narrative report? You must submit the materials required in the NHPRC grant announcements and in the...

  7. 36 CFR 1206.86 - What additional materials must I submit with the final narrative report?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... RECORDS COMMISSION Grant Administration § 1206.86 What additional materials must I submit with the final narrative report? You must submit the materials required in the NHPRC grant announcements and in the...

  8. Teachers' Perceptions of Students' Additional Support Needs: In the Eye of the Beholder?

    ERIC Educational Resources Information Center

    Bruggink, Marjon; Goei, Sui L.; Koot, Hans M.

    2016-01-01

    Nowadays, teachers are regarded as key players in the process of identifying and catering to students' additional support needs within mainstream primary classrooms. However, teachers' professional judgements regarding students with special needs have been found to be contextually influenced (e.g. by school context, student population, level of…

  9. 24 CFR 574.330 - Additional standards for short-term supported housing.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 3 2012-04-01 2012-04-01 false Additional standards for short-term supported housing. 574.330 Section 574.330 Housing and Urban Development Regulations Relating to Housing and Urban Development (Continued) OFFICE OF ASSISTANT SECRETARY FOR COMMUNITY PLANNING AND DEVELOPMENT, DEPARTMENT OF HOUSING AND...

  10. Solving Additive Problems at Pre-Elementary School Level with the Support of Graphical Representation

    ERIC Educational Resources Information Center

    Selva, Ana Coelho Vieira; Falcao, Jorge Tarcisio da Rocha; Nunes, Terezinha

    2005-01-01

    This research offers empirical evidence of the importance of supplying diverse symbolic representations in order to support concept development in mathematics. Graphical representation can be a helpful symbolic tool for concept development in the conceptual field of additive structures. Nevertheless, this symbolic tool has specific difficulties…

  11. Catalytic functionalities of supported sulfides. I. Effect of support and additives on the CoMo catalyst

    SciTech Connect

    Muralidhar, G.; Massoth, F.E.; Shabtai, J.

    1984-01-01

    C-S hydrogenolysis (HDS) of thiophene, hydrogenation (HYD) of 1-hexene, and hydrocracking (HCG) of 2,4,4-trimethyl-1-pentene, were used as separate model test reactions to differentiate and assess the catalytic functionalities of sulfided CoMo catalysts, and their dependence on the nature of the support and incorporation of additives. Rate constants and relative catalyst activities for these three reaction types were determined. HDS and HYD activities of CoMo supported on different types of Al/sub 2/O/sub 3/ were higher, while the HCG activity was lower compared with CoMo supported on SiO/sub 2/-Al/sub 2/O/sub 3/, SiO/sub 2/-MgO, or TiO/sub 2/. For SiO/sub 2/-Al/sub 2/O/sub 3/ supports both HDS and HYD activities decreased with increase in SiO/sub 2/ content from 10 to 75%, while HCG activity showed the opposite trend. Additives to a finished CoMo catalyst at 0.5% level caused variations in HDS and HCG activities, while HYD was essentially unaffected. HDS was promoted by NH/sub 4/HF/sub 2/ and NH/sub 4/Cl, but depressed by NaNO/sub 3/, Ca(NO/sub 3/)/sub 2/, and H/sub 3/BO/sub 3/. HCG was promoted by NH/sub 4/HF/sub 2/, NH/sub 4/Cl, and H/sub 3/BO/sub 3/. Additives at 5% level, prior to or after CoMo impregnation, showed a strong depressing effect on HDS and a lesser effect on HYD, while HCG was strongly promoted by NH/sub 4/HF/sub 2/, Ti isopropoxide, and H/sub 3/BO/sub 3/. The changes in catalytic functionalities are rationalized in terms of different interactions between CoMo phase, support, and additives. 3 tables, 1 figure.

  12. Supporting English as an Additional Language Students in Science: Integrating Content and Language

    ERIC Educational Resources Information Center

    McCallum, Miranda; Miller, Jenny

    2013-01-01

    In this article, we report on a teacher-researcher collaboration that emerged from a large study on literacy strategies for diverse classrooms. Using the example of one Year 9 class of ten English as an Additional Language (EAL) students, we trialled language-focussed materials on the topic of Ecosystems as an alternative or adjunct to the…

  13. Support Assembly for Composite Laminate Materials During Roll Press Processing

    NASA Technical Reports Server (NTRS)

    Catella, Luke A.

    2011-01-01

    A composite laminate material is supported during the roll press processing thereof by an assembly having: first and second perforated films disposed adjacent to first and second opposing surfaces of a mixture of uncured resin and fibers defining the composite laminate material, a gas permeable encasement surrounding the mixture and the first and second films, a gas impervious envelope sealed about the gas permeable encasement, and first and second rigid plates clamped about the gas impervious envelope.

  14. 15 CFR 930.127 - Briefs and supporting materials.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 15 Commerce and Foreign Trade 3 2011-01-01 2011-01-01 false Briefs and supporting materials. 930... for Review Related to the Objectives of the Act and National Security Interests § 930.127 Briefs and... appellant shall submit to the Secretary its principal brief accompanied by the appendix described...

  15. 31 CFR 542.304 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 542.304 Section 542.304 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY SYRIAN SANCTIONS REGULATIONS General Definitions § 542.304...

  16. 31 CFR 549.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 549.313 Section 549.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY LEBANON SANCTIONS REGULATIONS General Definitions § 549.313...

  17. 31 CFR 548.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 548.313 Section 548.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS General Definitions § 548.313...

  18. 31 CFR 546.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 546.313 Section 546.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DARFUR SANCTIONS REGULATIONS General Definitions § 546.313...

  19. 31 CFR 537.327 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 537.327 Section 537.327 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BURMESE SANCTIONS REGULATIONS General Definitions § 537.327...

  20. 31 CFR 543.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 543.313 Section 543.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY CÃTE D'IVOIRE SANCTIONS REGULATIONS General Definitions §...

  1. 31 CFR 548.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 548.313 Section 548.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS General Definitions § 548.313...

  2. 31 CFR 549.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 549.313 Section 549.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY LEBANON SANCTIONS REGULATIONS General Definitions § 549.313...

  3. 31 CFR 594.317 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 594.317 Section 594.317 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS REGULATIONS General Definitions §...

  4. 31 CFR 547.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 547.313 Section 547.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO SANCTIONS REGULATIONS General...

  5. 31 CFR 546.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 546.313 Section 546.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DARFUR SANCTIONS REGULATIONS General Definitions § 546.313...

  6. 31 CFR 595.317 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 595.317 Section 595.317 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY TERRORISM SANCTIONS REGULATIONS General Definitions § 595.317...

  7. 31 CFR 595.317 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 595.317 Section 595.317 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY TERRORISM SANCTIONS REGULATIONS General Definitions § 595.317...

  8. 31 CFR 588.312 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 588.312 Section 588.312 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WESTERN BALKANS STABILIZATION REGULATIONS General Definitions §...

  9. 31 CFR 594.317 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 594.317 Section 594.317 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS REGULATIONS General Definitions §...

  10. 31 CFR 547.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 547.313 Section 547.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO SANCTIONS REGULATIONS General...

  11. 31 CFR 588.312 - Financial, material, or technological support.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Financial, material, or technological support. 588.312 Section 588.312 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WESTERN BALKANS STABILIZATION REGULATIONS General Definitions §...

  12. 31 CFR 543.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Financial, material, or technological support. 543.313 Section 543.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY CÃTE D'IVOIRE SANCTIONS REGULATIONS General Definitions §...

  13. 31 CFR 548.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Financial, material, or technological support. 548.313 Section 548.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS...

  14. 31 CFR 547.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Financial, material, or technological support. 547.313 Section 547.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DEMOCRATIC REPUBLIC OF THE CONGO SANCTIONS REGULATIONS General...

  15. 31 CFR 548.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Financial, material, or technological support. 548.313 Section 548.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS General Definitions § 548.313...

  16. 31 CFR 588.312 - Financial, material, or technological support.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Financial, material, or technological support. 588.312 Section 588.312 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WESTERN BALKANS STABILIZATION REGULATIONS General Definitions §...

  17. 31 CFR 549.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Financial, material, or technological support. 549.313 Section 549.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY LEBANON SANCTIONS REGULATIONS General Definitions § 549.313...

  18. 31 CFR 594.317 - Financial, material, or technological support.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Financial, material, or technological support. 594.317 Section 594.317 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS REGULATIONS General Definitions §...

  19. 31 CFR 588.312 - Financial, material, or technological support.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Financial, material, or technological support. 588.312 Section 588.312 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY WESTERN BALKANS STABILIZATION REGULATIONS General Definitions §...

  20. 31 CFR 548.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Financial, material, or technological support. 548.313 Section 548.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY BELARUS SANCTIONS REGULATIONS General Definitions § 548.313...

  1. 31 CFR 546.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Financial, material, or technological support. 546.313 Section 546.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY DARFUR SANCTIONS REGULATIONS General Definitions § 546.313...

  2. 31 CFR 594.317 - Financial, material, or technological support.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Financial, material, or technological support. 594.317 Section 594.317 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS REGULATIONS General Definitions §...

  3. 31 CFR 543.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Financial, material, or technological support. 543.313 Section 543.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY CôTE D'IVOIRE SANCTIONS REGULATIONS General Definitions §...

  4. 31 CFR 549.313 - Financial, material, or technological support.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Financial, material, or technological support. 549.313 Section 549.313 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY LEBANON SANCTIONS REGULATIONS General Definitions § 549.313...

  5. 31 CFR 594.317 - Financial, material, or technological support.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Financial, material, or technological support. 594.317 Section 594.317 Money and Finance: Treasury Regulations Relating to Money and Finance (Continued) OFFICE OF FOREIGN ASSETS CONTROL, DEPARTMENT OF THE TREASURY GLOBAL TERRORISM SANCTIONS REGULATIONS General Definitions §...

  6. Supported metal nanoparticles on porous materials. Methods and applications.

    PubMed

    White, Robin J; Luque, Rafael; Budarin, Vitaliy L; Clark, James H; Macquarrie, Duncan J

    2009-02-01

    Nanoparticles are regarded as a major step forward to achieving the miniaturisation and nanoscaling effects and properties that have been utilised by nature for millions of years. The chemist is no longer observing and describing the behaviour of matter but is now able to manipulate and produce new types of materials with specific desired physicochemical characteristics. Such materials are receiving extensive attention across a broad range of research disciplines. The fusion between nanoparticle and nanoporous materials technology represents one of the most interesting of these rapidly expanding areas. The harnessing of nanoscale activity and selectivity, potentially provides extremely efficient catalytic materials for the production of commodity chemicals, and energy needed for a future sustainable society. In this tutorial review, we present an introduction to the field of supported metal nanoparticles (SMNPs) on porous materials, focusing on their preparation and applications in different areas. PMID:19169462

  7. Nonporous magnetic materials as enzyme supports: studies with immobilized chymotrypsin.

    PubMed

    Munro, P A; Dunnill, P; Lilly, M D

    1977-01-01

    Chymotrypsin has been immobilized to several nonporous magnetic materials. Nickel particles were considered to be most suitable as immobilized enzyme supports. Chymotrypsin immobilized to nonporous magnetic supports was not fouled significantly by either whole milk or clarified yeast homogenate. AE-cellulose-chymotrypsin was rapidly fouled by both these materials and chymotrypsin immobilized to acrylic-based ion exchangers was slowly fouled. Immobilized enzyme activity was found to be inversely proportional to particle diameter for nonporous rock magnetic particles. Immobilization by adsorption and then glutaraldehyde crosslinking was used to produce controlled amounts of chymotrypsin on the particles. Esterolytic activity increased with enzyme loading but caseinolytic activity did not increase. Chymotrypsin is inhibited by metal ions from the magnetic supports. It is partially protected by use of a preliminary protein coating and may be reactivated by incubation with EDTA or BSA. PMID:14743

  8. 16 CFR 803.20 - Requests for additional information or documentary material.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... documentary material. 803.20 Section 803.20 Commercial Practices FEDERAL TRADE COMMISSION RULES, REGULATIONS... RULES § 803.20 Requests for additional information or documentary material. (a)(1) Persons and... documentary material relevant to the acquisition may be required from one or more persons required to...

  9. 16 CFR 803.20 - Requests for additional information or documentary material.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... documentary material. 803.20 Section 803.20 Commercial Practices FEDERAL TRADE COMMISSION RULES, REGULATIONS... RULES § 803.20 Requests for additional information or documentary material. (a)(1) Persons and... documentary material relevant to the acquisition may be required from one or more persons required to...

  10. 16 CFR 803.20 - Requests for additional information or documentary material.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... documentary material. 803.20 Section 803.20 Commercial Practices FEDERAL TRADE COMMISSION RULES, REGULATIONS... RULES § 803.20 Requests for additional information or documentary material. (a)(1) Persons and... documentary material relevant to the acquisition may be required from one or more persons required to...

  11. 16 CFR 803.20 - Requests for additional information or documentary material.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... documentary material. 803.20 Section 803.20 Commercial Practices FEDERAL TRADE COMMISSION RULES, REGULATIONS... RULES § 803.20 Requests for additional information or documentary material. (a)(1) Persons and... documentary material relevant to the acquisition may be required from one or more persons required to...

  12. Report on the Implementation of the Education (Additional Support for Learning) (Scotland) Act 2004

    ERIC Educational Resources Information Center

    Her Majesty's Inspectorate of Education, 2007

    2007-01-01

    The Additional Support for Learning Act is a key piece of legislation in Scotland's efforts to achieve a more inclusive society and to give all young people the access to the learning opportunities they need in order to meet their potential. The Act also has a key role to play in the day-to-day preventative action that schools can take to be…

  13. The biobehavioral family model: testing social support as an additional exogenous variable.

    PubMed

    Woods, Sarah B; Priest, Jacob B; Roush, Tara

    2014-12-01

    This study tests the inclusion of social support as a distinct exogenous variable in the Biobehavioral Family Model (BBFM). The BBFM is a biopsychosocial approach to health that proposes that biobehavioral reactivity (anxiety and depression) mediates the relationship between family emotional climate and disease activity. Data for this study included married, English-speaking adult participants (n = 1,321; 55% female; M age = 45.2 years) from the National Comorbidity Survey Replication, a nationally representative epidemiological study of the frequency of mental disorders in the United States. Participants reported their demographics, marital functioning, social support from friends and relatives, anxiety and depression (biobehavioral reactivity), number of chronic health conditions, and number of prescription medications. Confirmatory factor analyses supported the items used in the measures of negative marital interactions, social support, and biobehavioral reactivity, as well as the use of negative marital interactions, friends' social support, and relatives' social support as distinct factors in the model. Structural equation modeling indicated a good fit of the data to the hypothesized model (χ(2)  = 846.04, p = .000, SRMR = .039, CFI = .924, TLI = .914, RMSEA = .043). Negative marital interactions predicted biobehavioral reactivity (β = .38, p < .001), as did relatives' social support, inversely (β = -.16, p < .001). Biobehavioral reactivity predicted disease activity (β = .40, p < .001) and was demonstrated to be a significant mediator through tests of indirect effects. Findings are consistent with previous tests of the BBFM with adult samples, and suggest the important addition of family social support as a predicting factor in the model. PMID:24981970

  14. Intelligence is as intelligence does: can additional support needs replace disability?

    PubMed

    Arnold, Samuel R C; Riches, Vivienne C; Stancliffe, Roger J

    2011-12-01

    Abstract In many developed cultures there is an assumption that IQ is intelligence. However, emerging theories of multiple intelligences, of emotional intelligence, as well as the application of IQ testing to other cultural groups, and to people with disability, raises many questions as to what IQ actually measures. Despite recent research that shows IQ testing produces a floor effect when applied to people with lower IQ, as well as research that shows the Flynn effect also applies to people with lower IQ, in practice IQ scores below a certain cut-off are still being used to determine and classify a person's intellectual disability. However, a new paradigm is emerging, almost returning to the original intent of Binet, where measurement is made of the supports the person needs. In this paper, we argue that if one extends the notions of this supports paradigm that diagnosis of intellectual or physical disability could potentially be replaced by diagnosis of additional intellectual support needs, or additional physical support needs. PMID:21992715

  15. Material characterization via least squares support vector machines

    NASA Astrophysics Data System (ADS)

    Swaddiwudhipong, S.; Tho, K. K.; Liu, Z. S.; Hua, J.; Ooi, N. S. B.

    2005-09-01

    Analytical methods to interpret the load indentation curves are difficult to formulate and execute directly due to material and geometric nonlinearities as well as complex contact interactions. In the present study, a new approach based on the least squares support vector machines (LS-SVMs) is adopted in the characterization of materials obeying power law strain-hardening. The input data for training and verification of the LS-SVM model are obtained from 1000 large strain-large deformation finite element analyses which were carried out earlier to simulate indentation tests. The proposed LS-SVM model relates the characteristics of the indentation load-displacement curve directly to the elasto-plastic material properties without resorting to any iterative schemes. The tuned LS-SVM model is able to accurately predict the material properties when presented with new sets of load-indentation curves which were not used in the training and verification of the model.

  16. Development of Novel Supported Gold Catalysts: A Materials Perspective

    SciTech Connect

    Dai, Sheng; Ma, Zhen

    2011-01-01

    Since Haruta et al. discovered that small gold nanoparticles finely dispersed on certain metal oxide supports can exhibit surprisingly high activity in CO oxidation below room temperature, heterogeneous catalysis by supported gold nanoparticles has attracted tremendous attention. The majority of publications deal with the preparation and characterization of conventional gold catalysts (e.g., Au/TiO{sub 2}), the use of gold catalysts in various catalytic reactions, as well as elucidation of the nature of the active sites and reaction mechanisms. In this overview, we highlight the development of novel supported gold catalysts from a materials perspective. Examples, mostly from those reported by our group, are given concerning the development of simple gold catalysts with single metal-support interfaces and heterostructured gold catalysts with complicated interfacial structures. Catalysts in the first category include active Au/SiO{sub 2} and Au/metal phosphate catalysts, and those in the second category include catalysts prepared by pre-modification of supports before loading gold, by post-modification of supported gold catalysts, or by simultaneous dispersion of gold and an inorganic component onto a support. CO oxidation has generally been employed as a probe reaction to screen the activities of these catalysts. These novel gold catalysts not only provide possibilities for applied catalysis, but also furnish grounds for fundamental research.

  17. Children's Recall and Motivation for an Environmental Education Video with Supporting Pedagogical Materials

    ERIC Educational Resources Information Center

    Viteri, Fátima; Clarebout, Geraldine; Crauwels, Marion

    2014-01-01

    This study examined recall (Rcl) differences of high, average and low achieving fifth-grade elementary students (72) for an environmental education video with supporting pedagogical materials. In addition, it assessed the motivational level of all students. Recall assessment was carried out one-week and twenty-weeks after intervention. Main…

  18. Carbon recycling in materially closed ecological life support systems

    NASA Technical Reports Server (NTRS)

    Obenhuber, D. C.; Folsome, C. E.

    1988-01-01

    Results of studies are presented of materially closed energetically open microbial ecosystems or 'closed ecosystems'. These are natural marine ecosystems that have been sealed in glass containers to prevent material exchange with the environment but allow energy to pass freely through them. They represent model life support systems for the future human habitation of space. The results are discussed analytically and indicate that these ecosystems, when subjected to a constant energy flux, seem to be reliable and self-sufficient systems for recycling of biologically produced carbon compounds.

  19. Material transfer system in support of the plutonium immobilization program

    SciTech Connect

    Pak, D

    2000-12-20

    The Plutonium Immobilization Program requires development of the process and plant prototypic equipment to immobilize surplus plutonium in ceramic for long-term storage. Because of the hazardous nature of plutonium, it was necessary to develop a remotely operable materials transfer system which can function within the confines of a glovebox. In support of this work at LLNL, such a material transfer system (MTS) was developed. This paper presents both the mechanical and controls parts making up this system, and includes photographs of the key components and diagrams of their assemblies, as well as a description of the control sequence used to validate the MTS capabilities.

  20. Nuclear Industry Support Services by the Buffalo Materials Research Center

    SciTech Connect

    Henry, L.G. )

    1993-01-01

    The Buffalo Materials Research Center (BMRC) is located on the campus of the State University of New York at Buffalo, Principal facilities within BMRC include a 2-MW PULSTAR, low-enrichment reactor, an electron accelerator, and irradiated materials remote testing facilities. The reactor and the materials testing facilities have been utilized extensively in support of the power reactor community since 1961. This paper briefly highlights the nature and scope of this service. The BMRC is operated for the university by Buffalo Materials Research, Inc., a private for-profit company, which is a subsidiary of Materials Engineering Associates, Inc. (MEA), a Maryland-based materials testing company. A primary mission of MEA has been research on the effects of neutron irradiation on reactor structural materials, including those used for pressure vessel and piping systems. The combined resources of MEA and BMRC have played a pivotal role in the assessment of reactor pressure vessel safety both in the United States and abroad and in the development of new radiation-resistant steels.

  1. Electrostatic Levitation: A Tool to Support Materials Research in Microgravity

    NASA Technical Reports Server (NTRS)

    Rogers, Jan; SanSoucie, Mike

    2012-01-01

    Containerless processing represents an important topic for materials research in microgravity. Levitated specimens are free from contact with a container, which permits studies of deeply undercooled melts, and high-temperature, highly reactive materials. Containerless processing provides data for studies of thermophysical properties, phase equilibria, metastable state formation, microstructure formation, undercooling, and nucleation. The European Space Agency (ESA) and the German Aerospace Center (DLR) jointly developed an electromagnetic levitator facility (MSL-EML) for containerless materials processing in space. The electrostatic levitator (ESL) facility at the Marshall Space Flight Center provides support for the development of containerless processing studies for the ISS. Apparatus and techniques have been developed to use the ESL to provide data for phase diagram determination, creep resistance, emissivity, specific heat, density/thermal expansion, viscosity, surface tension and triggered nucleation of melts. The capabilities and results from selected ESL-based characterization studies performed at NASA's Marshall Space Flight Center will be presented.

  2. Compositions, Functions, and Testing of Friction Brake Materials and Their Additives

    SciTech Connect

    Blau, PJ

    2001-10-22

    The purpose of this report is to present a survey of commercial brake materials and additives, and to indicate their typical properties and functions, especially as regards their use in heavy trucks. Most truck pad and shoe materials described here were designed to wear against cast iron. Brake material test methods are also briefly described. This report does not address issues associated with the fabrication and manufacturing of brake materials. Since there are literally thousands of brake material additives, and their combinations are nearly limitless, it is impractical to list them all here. Rather, an attempt has been made to capture the primary constituents and their functions. An Appendix contains thermo-physical properties of some current and potential brake materials.

  3. 16 CFR 2.20 - Petitions for review of requests for additional information or documentary material.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... or documentary material issued under 16 CFR 803.20. (b) Second request procedures—(1) Notice. Every request for additional information or documentary material issued under 16 CFR 803.20 shall inform the..., glossaries, proposed form of relief and any appendices containing only sections of statutes or...

  4. 16 CFR 2.20 - Petitions for review of requests for additional information or documentary material.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... or documentary material issued under 16 CFR 803.20. (b) Second request procedures—(1) Notice. Every request for additional information or documentary material issued under 16 CFR 803.20 shall inform the..., glossaries, proposed form of relief and any appendices containing only sections of statutes or...

  5. 16 CFR 2.20 - Petitions for review of requests for additional information or documentary material.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... or documentary material issued under 16 CFR 803.20. (b) Second request procedures—(1) Notice. Every request for additional information or documentary material issued under 16 CFR 803.20 shall inform the..., glossaries, proposed form of relief and any appendices containing only sections of statutes or...

  6. 16 CFR 2.20 - Petitions for review of requests for additional information or documentary material.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... or documentary material issued under 16 CFR 803.20. (b) Second request procedures—(1) Notice. Every request for additional information or documentary material issued under 16 CFR 803.20 shall inform the..., glossaries, proposed form of relief and any appendices containing only sections of statutes or...

  7. 16 CFR 2.20 - Petitions for review of requests for additional information or documentary material.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... or documentary material issued under 16 CFR 803.20. (b) Second request procedures—(1) Notice. Every request for additional information or documentary material issued under 16 CFR 803.20 shall inform the..., glossaries, proposed form of relief and any appendices containing only sections of statutes or...

  8. 12 CFR 367.15 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... facts. 367.15 Section 367.15 Banks and Banking FEDERAL DEPOSIT INSURANCE CORPORATION REGULATIONS AND... Additional proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil... facts material to the proposed suspension and/or exclusion, the contractor shall be afforded...

  9. 12 CFR 367.15 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... facts. 367.15 Section 367.15 Banks and Banking FEDERAL DEPOSIT INSURANCE CORPORATION REGULATIONS AND... Additional proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil... facts material to the proposed suspension and/or exclusion, the contractor shall be afforded...

  10. 12 CFR 367.15 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... facts. 367.15 Section 367.15 Banks and Banking FEDERAL DEPOSIT INSURANCE CORPORATION REGULATIONS AND... Additional proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil... facts material to the proposed suspension and/or exclusion, the contractor shall be afforded...

  11. 12 CFR 367.15 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... facts. 367.15 Section 367.15 Banks and Banking FEDERAL DEPOSIT INSURANCE CORPORATION REGULATIONS AND... Additional proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil... facts material to the proposed suspension and/or exclusion, the contractor shall be afforded...

  12. 12 CFR 367.15 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... facts. 367.15 Section 367.15 Banks and Banking FEDERAL DEPOSIT INSURANCE CORPORATION REGULATIONS AND... Additional proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil... facts material to the proposed suspension and/or exclusion, the contractor shall be afforded...

  13. 36 CFR 1206.86 - What additional materials must I submit with the final narrative report?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... RECORDS COMMISSION Grant Administration § 1206.86 What additional materials must I submit with the final narrative report? You must submit the materials determined by the Commission as found in the NHPRC grant announcements or specified in the grant award....

  14. Survival of Listeria monocytogenes on a conveyor belt material with or without antimicrobial additives.

    PubMed

    Chaitiemwong, N; Hazeleger, W C; Beumer, R R

    2010-08-15

    Survival of Listeria monocytogenes on a conveyor belt material with or without antimicrobial additives, in the absence or presence of food debris from meat, fish and vegetables and at temperatures of 10, 25 and 37 degrees C was investigated. The pathogen survived best at 10 degrees C, and better at 25 degrees C than at 37 degrees C on both conveyor belt materials. The reduction in the numbers of the pathogen on belt material with antimicrobial additives in the first 6h at 10 degrees C was 0.6 log unit, which was significantly higher (P<0.05) than the reduction of 0.2 log unit on belt material without additives. Reductions were significantly less (P<0.05) in the presence of food residue. At 37 degrees C and 20% relative humidity, large decreases in the numbers of the pathogen on both conveyor belt materials during the first 6h were observed. Under these conditions, there was no obvious effect of the antimicrobial substances. However, at 25 degrees C and 10 degrees C and high humidity (60-75% rh), a rapid decrease in bacterial numbers on the belt material with antimicrobial substances was observed. Apparently the reduction in numbers of L. monocytogenes on belt material with antimicrobial additives was greater than on belt material without additives only when the surfaces were wet. Moreover, the presence of food debris neutralized the effect of the antimicrobials. The results suggest that the antimicrobial additives in conveyor belt material could help to reduce numbers of microorganisms on belts at low temperatures when food residues are absent and belts are not rapidly dried. PMID:20655607

  15. Recycling of fly ash for preparing porous mullite membrane supports with titania addition.

    PubMed

    Dong, Yingchao; Hampshire, Stuart; Zhou, Jian-er; Lin, Bin; Ji, Zhanlin; Zhang, Xiaozhen; Meng, Guangyao

    2010-08-15

    In order to effectively utilize industrial waste fly ash, porous mullite ceramic membrane supports were prepared from fly ash and calcined bauxite with chemically pure titania as sintering additive. The effects of TiO(2) on the sintering behaviors and main properties of porous mullite were studied in detail. Due to the addition of titania, the sintering of the flyash-based mullite was inhibited at low temperatures, but effectively improved at high temperatures, the latter is suitable for preparing porous mullite membrane supports by incomplete sintering. Titania entered into liquid glassy phase with low high-temperature viscosity during sintering, resulting in the improvement of sintering activity, as well as the lowering of secondary mullitization temperature (where 2.0% titania). Between 1300 and 1500 degrees C, with increasing titania content, the samples exhibit increased trends in both linear shrinkage percent and bulk density, but a slightly decreased trend in open porosity, at all sintering temperatures. At 1300-1500 degrees C, the samples sintered at 1450 degrees C for 2h exhibit the lowest shrinkage and bulk density, as well as the highest open porosities in the investigated titania content range of 0-6.0 wt.%. Also, with increasing titania content, the pore size decreases slightly but the three-point flexural strength increases gradually at 1450 degrees C. PMID:20452727

  16. Flammability, Odor, Offgassing, and Compatibility Requirements and Test Procedures for Materials in Environments that Support Combustion

    NASA Technical Reports Server (NTRS)

    1998-01-01

    This handbook establishes NASA program requirements for evaluation, testing, and selection of materials to preclude unsafe conditions related to flammability, odor, offgassing, and fluid compatibility. Materials intended for use in space vehicles, specified test facilities, and specified ground support equipment (GSE) must meet the requirements of this document. Additional materials performance requirements may be specified in other program or NASA center specific documentation. Responsible NASA centers materials organizations must include applicable requirements of this document in their materials control programs. Materials used in habitable areas of spacecraft, including the materials of the spacecraft, stowed equipment, and experiments, must be evaluated for flammability, odor, and offgassing characteristics. All materials used in other areas must be evaluated for flammability characteristics. In addition, materials that are exposed to liquid oxygen (LOX), gaseous oxygen (GOX), and other reactive fluids' must be evaluated for compatibility with the fluid in their use application. Materials exposed to pressurized breathing gases also must be evaluated for odor and offgassing characteristics. The worst-case anticipated use environment (most hazardous pressure, temperature, material thickness, and fluid exposure conditions) must be used in the evaluation process. Materials that have been shown to meet the criteria of the required tests are acceptable for further consideration in design. Whenever possible, materials should be selected that have already been shown to meet the test criteria in the use environment. Existing test data are compiled in the NASA Marshall Space Flight Center (MSFC) Materials and Processes Technical Information System (MAPTIS) and published periodically as the latest revision of a joint document with Johnson Space Center (JSC), MSFC-HDBK-527/JSC 09604. MAPTIS can be accessed by computer datalink. Systems containing materials that have not

  17. Support Operators Method for the Diffusion Equation in Multiple Materials

    SciTech Connect

    Winters, Andrew R.; Shashkov, Mikhail J.

    2012-08-14

    A second-order finite difference scheme for the solution of the diffusion equation on non-uniform meshes is implemented. The method allows the heat conductivity to be discontinuous. The algorithm is formulated on a one dimensional mesh and is derived using the support operators method. A key component of the derivation is that the discrete analog of the flux operator is constructed to be the negative adjoint of the discrete divergence, in an inner product that is a discrete analog of the continuum inner product. The resultant discrete operators in the fully discretized diffusion equation are symmetric and positive definite. The algorithm is generalized to operate on meshes with cells which have mixed material properties. A mechanism to recover intermediate temperature values in mixed cells using a limited linear reconstruction is introduced. The implementation of the algorithm is verified and the linear reconstruction mechanism is compared to previous results for obtaining new material temperatures.

  18. Addition of gonadotropin releasing hormone agonist for luteal phase support in in-vitro fertilization: an analysis of 2739 cycles

    PubMed Central

    Şimşek, Erhan; Kılıçdağ, Esra Bulgan; Aytaç, Pınar Çağlar; Çoban, Gonca; Şimşek, Seda Yüksel; Çok, Tayfun; Haydardedeoğlu, Bülent

    2015-01-01

    Objective Luteal phase is defective in in vitro fertilization (IVF) cycles, and many regimens were tried for the very best luteal phase support (LPS). Gonadotropin releasing hormone (GnRH) agonist use, which was administered as an adjunct to the luteal phase support in IVF cycles, was suggested to improve pregnancy outcome measures in certain randomized studies. We analyzed the effects of addition of GnRH agonist to standard progesterone luteal support on pregnancy outcome measures, particularly the live birth rates. Material and Methods This is a retrospective cohort study, including 2739 IVF cycles. Long GnRH agonist and antagonist stimulation IVF cycles with cleavage-stage embryo transfer were included. Cycles were divided into two groups: Group A included cycles with single-dose GnRH agonist plus progesterone LPS and Group B included progesterone only LPS. Live birth rates were the primary outcome measures of the analysis. Miscarriage rates and multiple pregnancy rates were the secondary outcome measures. Results Live birth rates were not statistically different in GnRH agonist plus progesterone (Group A) and progesterone only (Group B) groups in both the long agonist and antagonist stimulation arms (40.8%/41.2% and 32.8%/34.4%, p<0.05 respectively). Moreover, pregnancy rates, implantation rates, and miscarriage rates were found to be similar between groups. Multiple pregnancy rates in antagonist cycles were significantly higher in Group A than those in Group B (12.0% and 6.9%, respectively). Conclusion A beneficial effect of a single dose of GnRH agonist administration as a luteal phase supporting agent is yet to be determined because of the wide heterogeneity of data present in literature. Well-designed randomized clinical studies are required to clarify any effect of luteal GnRH agonist addition on pregnancy outcome measures with different doses, timing, and administration routes of GnRH agonists. PMID:26097392

  19. Deformation and failure of a superplastic AA5083 aluminum material with a cu addition

    NASA Astrophysics Data System (ADS)

    Green, W. Paul; Kulas, Mary-Anne; Niazi, Amanda; Taleff, Eric M.; Oishi, Keiichiro; Krajewski, Paul E.; McNelley, Terry R.

    2006-09-01

    A modified AA5083 aluminum sheet material containing a Cu addition of 0.61 wt pct has been investigated under conditions relevant to commercial hot-forming technologies. This material was produced by continuous casting followed by industrial hot and cold rolling into sheet. Deformation and failure mechanisms at elevated temperatures were investigated through mechanical testing, thermal analysis, and microscopy. The effects of Cu addition are evaluated by comparisons with data from AA5083 sheet materials without Cu addition, produced both by continuous and direct-chill (DC) casting techniques. At low temperatures and fast strain rates, for which solute-drag (SD) creep governs deformation, the Cu addition slightly increases tensile ductility at 450 °C but does not otherwise alter deformation behaviors. At high temperatures and slow strain rates, for which grainboundary-sliding (GBS) creep governs deformation, the Cu addition decreases flow stress and, at 450 °C, improves tensile ductility. A strong temperature dependence for tensile ductility results from the Cu addition; tensile ductility at 500 °C is notably reduced from that at 450 °C. The Cu addition creates platelike particles at grain boundaries, which produce incipient melting and the observed mechanical behavior.

  20. Effect of additions of aluminosilicate and silicate materials on the softening temperature of chromite ore

    NASA Astrophysics Data System (ADS)

    Zhdanov, A. V.; Nurmaganbetova, B. N.; Pavlov, V. A.

    2015-07-01

    The temperatures of the beginning and end of softening and the temperature range of softening of the fines of the rich chromite ore of the Donskoy Ore Mining & Processing Plant in Kazakhstan are experimentally determined. The following natural and technical silica-containing materials, which are considered as fluxing additions to decrease the melting temperature of the chromite ore, are investigated: aluminosilicate clays, microsilica, and quartzite of various fractions. The effect of additions of the natural and technical silica-containing materials on the temperatures of the beginning and end of softening and the temperature range of softening of the chromite ore of DODPE is analyzed. The influences of various materials and their fraction compositions on the temperature of softening of the chromite ores are compared.

  1. On the design of novel multifunctional materials by using particulate additives

    NASA Astrophysics Data System (ADS)

    Dunnigan, Ross Daniel

    This thesis has been organized into five chapters. The main focus of this thesis is to design novel multifunctional materials by using particulate additives. Chapter 1 is devoted to reviewing recent studies in additive manufacturing (AM) and other background information. In Chapter 2, the synthesis and characterization of novel Ti3SiC2-reinforced Zn-matrix composites is reported. During this study, all the Zn composites were hot pressed at 500°C for 5 min at a uniaxial pressure of ~150 MPa. Microstructure analysis by SEM (Scanning Electron Microscopy) and phase analysis by XRD (X-ray Diffraction) confirmed that there was minimal interfacial reaction between Ti3SiC 2 particles and the Zn matrix. The addition of Ti3SiC 2 improved the tribological performance of these composites against alumina substrates but did not have any beneficial effect on the mechanical performance. The addition of Ti3SiC2 particulates to metal and polymer matrices show interesting properties. Chapter 3 will focus on additive manufacturing of Ti3SiC2 particulates in a polymer matrix. Waste materials are a big problem in the world. Chapters 4 and 5 focus on recycling materials. The mechanical and tribological properties of the Resin-Nylon and ResinPolyester composites are reported, respectively.

  2. Effects of addition of different carbon materials on the electrochemical performance of nickel hydroxide electrode

    NASA Astrophysics Data System (ADS)

    Sierczynska, Agnieszka; Lota, Katarzyna; Lota, Grzegorz

    Nickel hydroxide is used as an active material in positive electrodes of rechargeable alkaline batteries. The capacity of nickel-metal hydride (Ni-MH) batteries depends on the specific capacity of the positive electrode and utilization of the active material because of the Ni(OH) 2/NiOOH electrode capacity limitation. The practical capacity of the positive nickel electrode depends on the efficiency of the conductive network connecting the Ni(OH) 2 particle with the current collector. As β-Ni(OH) 2 is a kind of semiconductor, the additives are necessary to improve the conductivity between the active material and the current collector. In this study the effect of adding different carbon materials (flake graphite, multi-walled carbon nanotubes (MWNT)) on the electrochemical performance of pasted nickel-foam electrode was established. A method of production of MWNT special type of catalysts had an influence on the performance of the nickel electrodes. The electrochemical tests showed that the electrode with added MWNT (110-170 nm diameter) exhibited better electrochemical properties in the chargeability, specific discharge capacity, active material utilization, discharge voltage and cycling stability. The nickel electrodes with MWNT addition (110-170 nm diameter) have exhibited a specific capacity close to 280 mAh g -1 of Ni(OH) 2, and the degree of active material utilization was ∼96%.

  3. Effect of vermicomposting on concentration and speciation of heavy metals in sewage sludge with additive materials.

    PubMed

    He, Xin; Zhang, Yaxin; Shen, Maocai; Zeng, Guangming; Zhou, Mucen; Li, Meirong

    2016-10-01

    The aim of this work was to evaluate the total content and speciation of heavy metals (As, Cr, Cd, Cu, Fe, Mn, Ni, Pb and Zn) during vermicomposting of sewage sludge by Eisenia fetida earthworm with different additive materials (soil, straw, fly ash and sawdust). Results showed that the pH, total organic carbon were reduced, while the electric conductivity and germination index increased after a combined composting - vermicomposting process. The addition of bulking agents accelerated the stabilization of sludge and eliminated its toxicity. The total heavy metals after vermicomposting in 10 scenarios were lowered as compared with the initial values and the control without amendment. BCR sequential extraction indicated that vermicomposting significantly decreased the mobility of all heavy metals by increasing the residual fractions. The activity of earthworms and appropriate addition of amendment materials played a positive role in sequestering heavy metals during the treatment of sewage sludge. PMID:27434304

  4. Material need support interventions for diabetes prevention and control: a systematic review.

    PubMed

    Barnard, Lily S; Wexler, Deborah J; DeWalt, Darren; Berkowitz, Seth A

    2015-02-01

    Unmet material needs, such as food insecurity and housing instability, are associated with increased risk of diabetes and worse outcomes among diabetes patients. Healthcare delivery organizations are increasingly held accountable for health outcomes that may be related to these "social determinants," which are outside the scope of traditional medical intervention. This review summarizes the current literature regarding interventions that provide material support for income, food, housing, and other basic needs. In addition, we propose a conceptual model of the relationship between unmet needs and diabetes outcomes and provide recommendations for future interventional research. PMID:25620406

  5. Novel Overhang Support Designs for Powder-Based Electron Beam Additive Manufacturing (EBAM)

    NASA Technical Reports Server (NTRS)

    Nabors, Sammy A.

    2014-01-01

    NASA Marshall Space Flight Center, in collaboration with the University of Alabama, has developed a contact-free support structure used to fabricate overhang-type geometries via EBAM. The support structure is used for 3-D metal-printed components for the aerospace, automotive, biomedical and other industries. Current techniques use support structures to address deformation challenges inherent in 3-D metal printing. However, these structures (overhangs) are bonded to the component and need to be removed in post-processing using a mechanical tool. This new technology improves the overhang support structure design for components by eliminating associated geometric defects and post-processing requirements.

  6. Pyramidal Fin Arrays Performance Using Streamwise Anisotropic Materials by Cold Spray Additive Manufacturing

    NASA Astrophysics Data System (ADS)

    Cormier, Yannick; Dupuis, Philippe; Jodoin, Bertrand; Corbeil, Antoine

    2016-01-01

    This work evaluates the thermal and hydrodynamic performance of pyramidal fin arrays produced using cold spray as an additive manufacturing process. Near-net-shaped pyramidal fin arrays of pure aluminum, pure nickel, and stainless steel 304 were manufactured. Fin array characterization such as fin porosity level and surface roughness evaluation was performed. The thermal conductivities of the three different coating materials were measured by laser flash analysis. The results obtained show a lower thermal efficiency for stainless steel 304, whereas the performances of the aluminum and nickel fin arrays are similar. This result is explained by looking closely at the fin and substrate roughness induced by the cold gas dynamic additive manufacturing process. The multi-material fin array sample has a better thermal efficiency than stainless steel 304. The work demonstrates the potential of the process to produce streamwise anisotropic fin arrays as well as the benefits of such arrays.

  7. Material Development for Tooling Applications Using Big Area Additive Manufacturing (BAAM)

    SciTech Connect

    Duty, Chad E.; Drye, Tom; Franc, Alan

    2015-03-01

    Techmer Engineered Solutions (TES) is working with Oak Ridge National Laboratory (ORNL) to develop materials and evaluate their use for ORNL s recently developed Big Area Additive Manufacturing (BAAM) system for tooling applications. The first phase of the project established the performance of some commercially available polymer compositions deposited with the BAAM system. Carbon fiber reinforced ABS demonstrated a tensile strength of nearly 10 ksi, which is sufficient for a number of low temperature tooling applications.

  8. Computed Tomography Support for Microgravity Materials Science Experiments

    NASA Technical Reports Server (NTRS)

    Gillies, Donald C.; Engel, H. Peter; Whitaker, Ann F. (Technical Monitor)

    2001-01-01

    The accurate measurement of density in both liquid and solid samples is of considerable interest to Principal Investigators with materials science experiments slated for the ISS. The work to be described is an innovative application of a conventional industrial nondestructive evaluation instrument. Traditional applications of industrial computed tomography (CT) rely on reconstructing cross sections of large structures to provide two-dimensional planar views which can identify defects such as porosity, or other material anomalies. This has been done on microgravity materials science experiments to check the integrity of ampoule-cartridge assemblies for safety purposes. With a substantially monoenergetic flux, as can be obtained with a radioactive cobalt source, there will be a direct correlation between absorption and density. Under such conditions it then becomes possible to make accurate measurements of density throughout a sample, and even when the sample itself is enclosed within a furnace and a safety required cartridge. Such a system has been installed at Kennedy Space Center (KSC) and is available to PIs to examine samples before and after flight. The CT system is being used to provide density information for two purposes. Firstly, the determination of density changes from liquid to solid is vital information to the PI for purposes of modeling the solidification behavior of his sample, and to engineers who have to design containment ampoules and must allow for shrinkage and other volume changes that may occur during processing. While such information can be obtained by pycnometric measurements, the possibility of using a furnace installed on the CT system enables one to examine potentially dangerous materials having high vapor pressures, while not needing visible access to the material. In addition, uniform temperature can readily be obtained, and the system can be controlled to ramp up, hold, and ramp down while collecting data over a wide range of

  9. A comparison of dimensional accuracy between three different addition cured silicone impression materials.

    PubMed

    Forrester-Baker, L; Seymour, K G; Samarawickrama, D; Zou, L; Cherukara, G; Patel, M

    2005-06-01

    Ten impressions of a metal implant abutment were made with each of three addition-cured silicone impression materials. Using the technique of co-ordinate metrology, the shoulder region of the abutment and corresponding regions of both impressions and dies made from these impressions were scanned and measured. Comparison of these measurements indicated that the mean dimension measured from the shoulder region for each group of impression materials was significantly different from those taken from the original metal implant abutment. However, when these impressions were cast in a gypsum based die material, none of the measured dimensions taken from the casts were significantly different from those taken from the original metal implant abutment. Thus, any change in measured dimensions occurring during impression making, was compensated for in some way by the casting process. PMID:16011234

  10. Additional material of the enigmatic Early Miocene mammal Kelba and its relationship to the order Ptolemaiida

    PubMed Central

    Cote, Susanne; Werdelin, Lars; Seiffert, Erik R.; Barry, John C.

    2007-01-01

    Kelba quadeemae, a fossil mammal from the Early Miocene of East Africa, was originally named on the basis of three isolated upper molars. Kelba has previously been interpreted as a creodont, a pantolestid, an insectivoran, and a hemigaline viverrid. The true affinities of this taxon have remained unclear because of the limited material and its unique morphology relative to other Miocene African mammals. New material of Kelba from several East African Miocene localities, most notably a skull from the Early Miocene locality of Songhor in Western Kenya, permits analysis of the affinities of Kelba and documents the lower dentition of this taxon. Morphological comparison of this new material clearly demonstrates that Kelba is a member of the order Ptolemaiida, a poorly understood group whose fossil record was previously restricted to the Oligocene Fayum deposits of northern Egypt. Phylogenetic analysis supports the monophyly of the Ptolemaiida, including Kelba, and recovers two monophyletic clades within the order. We provide new family names for these groups and an emended diagnosis for the order. The discovery of ptolemaiidans from the Miocene of East Africa is significant because it extends the known temporal range of the order by >10 million years and the geographic range by >3,200 km. Although the higher-level affinities of the Ptolemaiida remain obscure, their unique morphology and distribution through a larger area of Africa (and exclusively Africa) lend support to the idea that Ptolemaiida may have an ancient African origin. PMID:17372202

  11. Development and evaluation of measurement devices used to support testing of radioactive material transportation packages

    SciTech Connect

    Uncapher, W. L.; Ammerman, D. J.; Stenberg, D R; Bronowski, D. R.; Arviso, M.

    1992-01-01

    Radioactive material package designers use structural testing to verify and demonstrate package performance. A major part of evaluating structural response is the collection of instrumentation measurement data. Sandia National Laboratories (SNL) has an ongoing program to develop and evaluate measurement devices to support testing of radioactive material packages. Measurement devices developed in support of this activity include evaluation channels, ruggedly constructed linear variable differential transformers, and piezoresistive accelerometers with enhanced measurement capabilities. In addition to developing measurement devices, a method has been derived to evaluate accelerometers and strain gages for measurement repeatability, ruggedness, and manufacturers' calibration data under both laboratory and field conditions. The developed measurement devices and evaluation technique will be discussed and the results of the evaluation will be presented.

  12. The work of the European Union Reference Laboratory for Food Additives (EURL) and its support for the authorisation process of feed additives in the European Union: a review

    PubMed Central

    von Holst, Christoph; Robouch, Piotr; Bellorini, Stefano; de la Huebra, María José González; Ezerskis, Zigmas

    2016-01-01

    ABSTRACT This paper describes the operation of the European Union Reference Laboratory for Feed Additives (EURL) and its role in the authorisation procedure of feed additives in the European Union. Feed additives are authorised according to Regulation (EC) No. 1831/2003, which introduced a completely revised authorisation procedure and also established the EURL. The regulations authorising feed additives contain conditions of use such as legal limits of the feed additives, which require the availability of a suitable method of analysis for official control purposes under real world conditions. It is the task of the EURL to evaluate the suitability of analytical methods as proposed by the industry for this purpose. Moreover, the paper shows that one of the major challenges is the huge variety of the methodology applied in feed additive analysis, thus requiring expertise in quite different analytical areas. In order to cope with this challenge, the EURL is supported by a network of national reference laboratories (NRLs) and only the merged knowledge of all NRLs allows for a scientifically sound assessment of the analytical methods. PMID:26540604

  13. Laser-shocked energetic materials with metal additives: evaluation of detonation performance

    NASA Astrophysics Data System (ADS)

    Gottfried, Jennifer; Bukowski, Eric

    A focused, nanosecond-pulsed laser with sufficient energy to exceed the breakdown threshold of a material generates a laser-induced plasma with high peak temperatures, pressures, and shock velocities. Depending on the laser parameters and material properties, nanograms to micrograms of material is ablated, atomized, ionized and excited in the laser-induced plasma. The subsequent shock wave expansion into the air above the sample has been monitored using high-speed schlieren imaging in a recently developed technique, laser-induced air shock from energetic materials (LASEM). The estimated detonation velocities using LASEM agree well with published experimental values. A comparison of the measured shock velocities for various energetic materials including RDX, DNTF, and LLM-172 doped with Al or B to the detonation velocities predicted by CHEETAH for inert or active metal participation demonstrates that LASEM has potential for predicting the early time participation of metal additives in detonation events. The LASEM results show that reducing the amount of hydrogen present in B formulations increases the resulting detonation velocities

  14. Porous hollow carbon spheres for electrode material of supercapacitors and support material of dendritic Pt electrocatalyst

    NASA Astrophysics Data System (ADS)

    Fan, Yang; Liu, Pei-Fang; Huang, Zhong-Yuan; Jiang, Tong-Wu; Yao, Kai-Li; Han, Ran

    2015-04-01

    Porous hollow carbon spheres (PHCSs) are prepared through hydrothermal carbonization of alginic acid and subsequent chemical activation by KOH. The porosity of the alginic acid derived PHCSs can be finely modulated by varying activation temperature in the range of 600-900 °C. The PHCSs activated at 900 °C possess the largest specific surface area (2421 m2 g-1), well-balanced micro- and mesoporosity, as well as high content of oxygen-containing functional groups. As the electrode material for supercapacitors, the PHCSs exhibit superior capacitive performance with specific capacitance of 314 F g-1 at current density of 1 A g-1. Pt nanodendrites supported on the PHCSs are synthesized by polyol reduction method which exhibit high electrocatalytic activity towards methanol oxidation reaction (MOR). Moreover, CO-poisoning tolerance of the Pt nanodendrites is greatly enhanced owing to the surface chemical property of the PHCSs support.

  15. Application of polymer graded-index materials for aberration correction of progressive addition lenses

    NASA Astrophysics Data System (ADS)

    Shitanoki, Yuki; Tagaya, Akihiro; Koike, Yasuhiro

    2009-02-01

    Graded-index (GRIN) progressive addition lens (PAL) was successfully fabricated, and GRIN's potential for aberration correction of PAL was confirmed. GRIN material was prepared by partial diffusion of methyl methacrylate (MMA (nd at polymer = 1.492)) monomer into cross-linked benzyl methacrylate (BzMA (nd at polymer=1.568)) flat gel, and GRINPAL was prepared by polymerization of the GRIN material attached to a mold of commercially available PAL. GRIN polymer materials have been used for various applications such as rod lenses and optical fibers. GRIN represents gradual change of refractive index in a material, which adds or reduces light focusing power of the material. PAL is a multifocal spectacle lens for presbyopia. However, some localized aberrations (especially astigmatism) in PAL have not yet been reduced satisfactorily for decades by optimizing surface geometry of a lens. In this research, we propose to employ GRIN materials for astigmatism reduction of PALs. BzMA flat gel was prepared by UV polymerization of BzMA, crosslinking agent ethylene glycol dimethacrylate (EDMA) and photopolymerization initiator DAROCURE 1173. MMA monomer was diffused into BzMA flat gel from a portion of periphery for several hours. The obtained GRIN material was attached to a mold of commercially available PAL and polymerized by UV. As a result, reduction of astigmatism was confirmed locally in the fabricated PAL and GRIN-PAL using lens meter. In conclusion, GRIN-PAL was successfully fabricated. The validity of GRIN employment for the astigmatism reduction in PAL was demonstrated experimentally.

  16. Flexible Foam Protection Materials for Constellation Space Suit Element Portable Life Support Subsystem Packaging Study

    NASA Technical Reports Server (NTRS)

    Tang, Henry H.; Orndoff, Evelyne S.; Thomas, Gretchen A.

    2009-01-01

    This paper discusses the effort in evaluating and selecting a light weight impact protection material for the Constellation Space Suit Element (CSSE) Portable Life Support Subsystem (PLSS) conceptual packaging study. A light weight material capable of holding and protecting the components inside the PLSS is required to demonstrate the viability of the flexible PLSS packaging concept. The material needs to distribute, dissipate, and absorb the impact energy of the PLSS falling on the lunar surface. It must also be very robust and function in the extreme lunar thermal vacuum environment for up to one hundred Extravehicular Activity (EVA) missions. This paper documents the performance requirements for selecting a foam protection material, and the methodologies for evaluating commercial off-the-shelf (COTS) foam protection materials. It also presents the materials properties test results and impact drop test results of the various foam materials evaluated in the study. The findings from this study suggest that a foam based flexible protection system is a viable solution for PLSS packaging. However, additional works are needed to optimize COTS foam properties or to develop a composite foam system that will meet all the performance requirements for the CSSE PLSS flexible packaging.

  17. Hydrogen Economy: The Role of Nano-scaled Support Material for Electrocatalysts Aimed for Water Electrolysis

    NASA Astrophysics Data System (ADS)

    Paunović, Perica; Popovski, Orce; Dimitrov, Aleksandar T.

    The role and importance of support materials for electrocatalysts aimed for water electrolysis is given. Besides their superior support characteristics such as electroconductivity, a high developed surface area and chemical stability, support materials should be an active participant in the catalytic activity through strong metal-support interactions (SMSI) with the metallic catalytic phase. Subject of this paper are several support materials: (i) Vulcan XC-72, (ii) Vulcan XC-72 with TiO2, (iii) multiwalled carbon nanotubes (MWCNTs) and (iv) Magneli phases, i.e. nonstoichiometric titanium oxides. A comparison of catalytic activity of Co-based electrocatalysts deposited on all support materials mentioned is given.

  18. Development of Additive Construction Technologies for Application to Development of Lunar/Martian Surface Structures Using In-Situ Materials

    NASA Technical Reports Server (NTRS)

    Werkheiser, Niki J.; Fiske, Michael R.; Edmunson, Jennifer E.; Khoshnevis, Berokh

    2015-01-01

    For long-duration missions on other planetary bodies, the use of in situ materials will become increasingly critical. As human presence on these bodies expands, so must the breadth of the structures required to accommodate them including habitats, laboratories, berms, radiation shielding for natural radiation and surface reactors, garages, solar storm shelters, greenhouses, etc. Planetary surface structure manufacturing and assembly technologies that incorporate in situ resources provide options for autonomous, affordable, pre-positioned environments with radiation shielding features and protection from micrometeorites, exhaust plume debris, and other hazards. The ability to use in-situ materials to construct these structures will provide a benefit in the reduction of up-mass that would otherwise make long-term Moon or Mars structures cost prohibitive. The ability to fabricate structures in situ brings with it the ability to repair these structures, which allows for the self-sufficiency and sustainability necessary for long-duration habitation. Previously, under the auspices of the MSFC In-Situ Fabrication and Repair (ISFR) project and more recently, under the jointly-managed MSFC/KSC Additive Construction with Mobile Emplacement (ACME) project, the MSFC Surface Structures Group has been developing materials and construction technologies to support future planetary habitats with in-situ resources. One such additive construction technology is known as Contour Crafting. This paper presents the results to date of these efforts, including development of novel nozzle concepts for advanced layer deposition using this process. Conceived initially for rapid development of cementitious structures on Earth, it also lends itself exceptionally well to the automated fabrication of planetary surface structures using minimally processed regolith as aggregate, and binders developed from in situ materials as well. This process has been used successfully in the fabrication of

  19. Active metal-matrix composites with embedded smart materials by ultrasonic additive manufacturing

    NASA Astrophysics Data System (ADS)

    Hahnlen, Ryan; Dapino, Marcelo J.

    2010-04-01

    This paper presents the development of active aluminum-matrix composites manufactured by Ultrasonic Additive Manufacturing (UAM), an emerging rapid prototyping process based on ultrasonic metal welding. Composites created through this process experience temperatures as low as 25 °C during fabrication, in contrast to current metal-matrix fabrication processes which require temperatures of 500 °C and above. UAM thus provides unprecedented opportunities to develop adaptive structures with seamlessly embedded smart materials and electronic components without degrading the properties that make these materials and components attractive. This research focuses on developing UAM composites with aluminum matrices and embedded shape memory NiTi, magnetostrictive Galfenol, and electroactive PVDF phases. The research on these composites will focus on: (i) electrical insulation between NiTi and Al phases for strain sensors, investigation and modeling of NiTi-Al composites as tunable stiffness materials and thermally invariant structures based on the shape memory effect; (ii) process development and composite testing for Galfenol-Al composites; and (iii) development of PVDF-Al composites for embedded sensing applications. We demonstrate a method to electrically insulate embedded materials from the UAM matrix, the ability create composites containing up to 22.3% NiTi, and their resulting dimensional stability and thermal actuation characteristics. Also demonstrated is Galfenol-Al composite magnetic actuation of up to 54 μ(see manuscript), and creation of a PVDF-Al composite sensor.

  20. Evaluation of critical materials in five additional advance design photovoltaic cells

    SciTech Connect

    Smith, S.A.; Watts, R.L.; Martin, P.; Gurwell, W.E.

    1981-02-01

    The objective of this study is to identify potential material supply constraints due to the large-scale deployment of five advanced photovoltaic (PV) cell designs, and to suggest strategies to reduce the impacts of these production capacity limitations and potential future material shortages. The Critical Materials Assessment Program (CMAP) screens the designs and their supply chains and identifies potential shortages which might preclude large-scale use of the technologies. The results of the screening of five advanced PV cell designs are presented: (1) indium phosphide/cadmium sulfide, (2) zinc phosphide, (3) cadmium telluride/cadmium sulfide, (4) copper indium selenium, and (5) cadmium selenide photoelectrochemical. Each of these five cells is screened individually assuming that they first come online in 1991, and that 25 Gwe of peak capacity is online by the year 2000. A second computer screening assumes that each cell first comes online in 1991 and that each cell has a 5 GWe of peak capacity by the year 2000, so that the total online capacity for the five cells is 25 GWe. Based on a review of the preliminary baseline screening results, suggestions were made for varying such parameters as the layer thickness, cell production processes, etc. The resulting PV cell characterizations were then screened again by the CMAP computer code. The CMAP methodology used to identify critical materials is described; and detailed characterizations of the advanced photovoltaic cell designs under investigation, descriptions of additional cell production processes, and the results are presented. (WHK)

  1. Comparative study of dimensional accuracy of different impression techniques using addition silicone impression material.

    PubMed

    Penaflor, C F; Semacio, R C; De Las Alas, L T; Uy, H G

    1998-01-01

    This study compared dimensional accuracy of the single, double with spacer, double with cut-out and double mix impression technique using addition silicone impression material. A typhodont containing Ivorine teeth model with six (6) full-crown tooth preparations were used as the positive control. Two stone replication models for each impression technique were made as test materials. Accuracy of the techniques were assessed by measuring four dimensions on the stone dies poured from the impression of the Ivorine teeth model. Results indicated that most of the measurements for the height, width and diameter slightly decreased and a few increased compared with the Ivorine teeth model. The double with cut-out and double mix technique presents the least difference from the master model as compared to the two latter impression techniques. PMID:10202524

  2. Processing of New Materials by Additive Manufacturing: Iron-Based Alloys Containing Silver for Biomedical Applications

    NASA Astrophysics Data System (ADS)

    Niendorf, Thomas; Brenne, Florian; Hoyer, Peter; Schwarze, Dieter; Schaper, Mirko; Grothe, Richard; Wiesener, Markus; Grundmeier, Guido; Maier, Hans Jürgen

    2015-07-01

    In the biomedical sector, production of bioresorbable implants remains challenging due to improper dissolution rates or deficient strength of many candidate alloys. Promising materials for overcoming the prevalent drawbacks are iron-based alloys containing silver. However, due to immiscibility of iron and silver these alloys cannot be manufactured based on conventional processing routes. In this study, iron-manganese-silver alloys were for the first time synthesized by means of additive manufacturing. Based on combined mechanical, microscopic, and electrochemical studies, it is shown that silver particles well distributed in the matrix can be obtained, leading to cathodic sites in the composite material. Eventually, this results in an increased dissolution rate of the alloy. Stress-strain curves showed that the incorporation of silver barely affects the mechanical properties.

  3. Multi-material additive manufacturing of robot components with integrated sensor arrays

    NASA Astrophysics Data System (ADS)

    Saari, Matt; Cox, Bryan; Galla, Matt; Krueger, Paul S.; Richer, Edmond; Cohen, Adam L.

    2015-06-01

    Fabricating a robotic component comprising 100s of distributed, connected sensors can be very difficult with current approaches. To address these challenges, we are developing a novel additive manufacturing technology to enable the integrated fabrication of robotic structural elements with distributed, interconnected sensors and actuators. The focus is on resistive and capacitive sensors and electromagnetic actuators, though others are anticipated. Anticipated applications beyond robotics include advanced prosthetics, wearable electronics, and defense electronics. This paper presents preliminary results for printing polymers and conductive material simultaneously to form small sensor arrays. Approaches to optimizing sensor performance are discussed.

  4. Material transfer system in support of the plutonium immobilization program

    SciTech Connect

    Pak, D

    2000-02-23

    The Plutonium Immobilization Project is currently undertaking formulation and process development to demonstrate the immobilization of surplus plutonium in a titanate-based ceramic. These ceramic forms will be encapsulated within canisters containing high level waste glass for geologic disposal. Process development work is being conducted with sub-scale, process prototypic equipment. Final validation of the process will be done using actual plutonium material and functionally prototypic equipment within a glovebox. Due to the radioactive nature of the material, remote material handling is necessary to reduce the radiation exposure to the operators. A remote operated Material Transfer System to interface with process equipment has been developed.

  5. Flexible Foam Protection Materials for Portable Life Support System Packaging Study

    NASA Technical Reports Server (NTRS)

    Tang,Henry H.; Dillon, Paul A.; Thomas, Gretchen A.

    2009-01-01

    This paper discusses the phase I effort in evaluating and selecting a light weight impact protection material for the Constellation Space Suit Element (CSSE) Portable Life Support System (PLSS) conceptual packaging study. A light weight material capable of holding and protecting the components inside the PLSS is required to demonstrate the viability of the flexible PLSS packaging concept. The material needs to distribute, dissipate, and absorb the impact energy of the PLSS falling on the lunar surface. It must also be robust to consistently perform over several Extravehicular Activity (EVA) missions in the extreme lunar thermal vacuum environment. This paper documents the performance requirements for selecting a foam protection material, and the methodologies for evaluating some commercial off-the-shelf (COTS) foam material candidates. It also presents the mechanical properties and impact drop tests results of the foam material candidates. The results of this study suggest that a foam based flexible protection system is a viable solution for PLSS packaging. However, additional works are needed to optimize COTS foam or to develop a composite foam system that will meet all the performance requirements for the CSSE PLSS flexible packaging.

  6. Additive-free thick graphene film as an anode material for flexible lithium-ion batteries.

    PubMed

    Rana, Kuldeep; Kim, Seong Dae; Ahn, Jong-Hyun

    2015-04-28

    This work demonstrates a simple route to develop mechanically flexible electrodes for Li-ion batteries (LIBs) that are usable as lightweight effective conducting networks for both cathodes and anodes. Removing electrochemically dead elements, such as binders, conducting agents and metallic current collectors, from the battery components will allow remarkable progress in this area. To investigate the feasibility of using thick, additive-free graphene films as anodes for flexible LIBs, we have synthesized and tested thick, additive-free, freestanding graphene films as anodes, first in a coin cell and further in a flexible full cell. As an anode material in a half cell, it showed a discharge capacity of about 350 mA h g(-1) and maintained nearly this capacity over 50 cycles at various current rates. This film was also tested as an anode material in a full cell with a LiCoO2 cathode and showed good electrochemical performance. Because the graphene-based flexible film showed good performance in half- and full coin cells, we used this film as a flexible anode for flexible LIBs. No conducting agent or binder was used in the anode side, which helped in realizing the flexible LIBs. Using this, we demonstrate a thin, lightweight and flexible lithium ion battery with good electrochemical performance in both its flat and bent states. PMID:25587843

  7. Support the Common Core with the Right Instructional Materials

    ERIC Educational Resources Information Center

    Leifer, Rachel; Udall, Denis

    2014-01-01

    Strong instructional materials are crucial to realizing the promise of the Common Core State Standards. Research suggests that the choice of instructional materials can have an impact as large as or larger than the impact of teacher quality. Unfortunately, many popular textbooks are not aligned to the new standards, leaving educators scrambling.…

  8. 30 CFR 75.214 - Supplemental support materials, equipment and tools.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... tools. 75.214 Section 75.214 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF....214 Supplemental support materials, equipment and tools. (a) A supply of supplementary roof support materials and the tools and equipment necessary to install the materials shall be available at a...

  9. 30 CFR 75.214 - Supplemental support materials, equipment and tools.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... tools. 75.214 Section 75.214 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF....214 Supplemental support materials, equipment and tools. (a) A supply of supplementary roof support materials and the tools and equipment necessary to install the materials shall be available at a...

  10. 30 CFR 75.214 - Supplemental support materials, equipment and tools.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... tools. 75.214 Section 75.214 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF....214 Supplemental support materials, equipment and tools. (a) A supply of supplementary roof support materials and the tools and equipment necessary to install the materials shall be available at a...

  11. 30 CFR 75.214 - Supplemental support materials, equipment and tools.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... tools. 75.214 Section 75.214 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF....214 Supplemental support materials, equipment and tools. (a) A supply of supplementary roof support materials and the tools and equipment necessary to install the materials shall be available at a...

  12. 30 CFR 75.214 - Supplemental support materials, equipment and tools.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... tools. 75.214 Section 75.214 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF....214 Supplemental support materials, equipment and tools. (a) A supply of supplementary roof support materials and the tools and equipment necessary to install the materials shall be available at a...

  13. Neutron measurement support for radiation material science in research reactors

    SciTech Connect

    Bregadze, Yu.I.; Grigor'ev, E.I.; Ivanov, V.B.; Klinov, A.V.; Kuprienko, V.A.; Starostov, B.I.; Yaryna, V.P.

    1987-07-01

    The authors discuss the need for development of a support system for unity in neutron measurement. Basic problems are outlined with regard to the support of neutron measurement unity for specialized service, such as research of working neutron fields, monitoring neutron fields during irradiation, and classification, analysis and storage of information about the controlled neutron field. Methods of realizing the metrological functions of the Metrological Center of Neutron Measurements are discussed as is the technical equipment used by the Center.

  14. In-situ materials processing systems and bioregenerative life support systems interrelationships

    NASA Technical Reports Server (NTRS)

    Mignon, George V.; Frye, Robert J.

    1992-01-01

    The synergy and linkages between bioregenerative life support systems and the materials produced by in-situ materials processing systems was investigated. Such systems produce a broad spectrum of byproducts such as oxygen, hydrogen, processed soil material, ceramics, refractory, and other materials. Some of these materials may be utilized by bioregenerative systems either directly or with minor modifications. The main focus of this project was to investigate how these materials can be utilized to assist a bioregenerative life support system. Clearly the need to provide a sustainable bioregenerative life support system for long term human habitation of space is significant.

  15. Process feasibility study in support of silicon material task 1

    NASA Technical Reports Server (NTRS)

    Yaws, C. L.; Li, K. Y.; Hopper, J. R.; Fang, C. S.; Hansen, K. C.

    1981-01-01

    Results for process system properties, chemical engineering and economic analyses of the new technologies and processes being developed for the production of lower cost silicon for solar cells are presented. Analyses of process system properties are important for chemical materials involved in the several processes under consideration for semiconductor and solar cell grade silicon production. Major physical, thermodynamic and transport property data are reported for silicon source and processing chemical materials.

  16. Materials Technology Support for Radioisotope Power Systems Final Report

    SciTech Connect

    Daniel P. Kramer; Chadwick D. Barklay

    2008-10-07

    Over the period of this sponsored research, UDRI performed a number of materials related tasks that helped to facilitate increased understanding of the properties and applications of a number of candidate program related materials including; effects of neutron irradiation on tantalum alloys using a 500kW reactor, thermodynamic based modeling of the chemical species in weld pools, and the application of candidate coatings for increased oxidation resistance of FWPF (Fine Weave Pierced Fabric) modules.

  17. Sign-Supported English: Is It Effective at Teaching Vocabulary to Young Children with English as an Additional Language?

    ERIC Educational Resources Information Center

    Marshall, Chloë R.; Hobsbaum, Angela

    2015-01-01

    Background: Children who are learning English as an Additional Language (EAL) may start school with smaller vocabularies than their monolingual peers. Given the links between vocabulary and academic achievement, it is important to evaluate interventions that are designed to support vocabulary learning in this group of children. Aims: To evaluate…

  18. Additive-free thick graphene film as an anode material for flexible lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Rana, Kuldeep; Kim, Seong Dae; Ahn, Jong-Hyun

    2015-04-01

    This work demonstrates a simple route to develop mechanically flexible electrodes for Li-ion batteries (LIBs) that are usable as lightweight effective conducting networks for both cathodes and anodes. Removing electrochemically dead elements, such as binders, conducting agents and metallic current collectors, from the battery components will allow remarkable progress in this area. To investigate the feasibility of using thick, additive-free graphene films as anodes for flexible LIBs, we have synthesized and tested thick, additive-free, freestanding graphene films as anodes, first in a coin cell and further in a flexible full cell. As an anode material in a half cell, it showed a discharge capacity of about 350 mA h g-1 and maintained nearly this capacity over 50 cycles at various current rates. This film was also tested as an anode material in a full cell with a LiCoO2 cathode and showed good electrochemical performance. Because the graphene-based flexible film showed good performance in half- and full coin cells, we used this film as a flexible anode for flexible LIBs. No conducting agent or binder was used in the anode side, which helped in realizing the flexible LIBs. Using this, we demonstrate a thin, lightweight and flexible lithium ion battery with good electrochemical performance in both its flat and bent states.This work demonstrates a simple route to develop mechanically flexible electrodes for Li-ion batteries (LIBs) that are usable as lightweight effective conducting networks for both cathodes and anodes. Removing electrochemically dead elements, such as binders, conducting agents and metallic current collectors, from the battery components will allow remarkable progress in this area. To investigate the feasibility of using thick, additive-free graphene films as anodes for flexible LIBs, we have synthesized and tested thick, additive-free, freestanding graphene films as anodes, first in a coin cell and further in a flexible full cell. As an anode

  19. Laser powder bed fusion additive manufacturing of metals; physics, computational, and materials challenges

    SciTech Connect

    King, W. E.; Anderson, A. T.; Ferencz, R. M.; Hodge, N. E.; Kamath, C.; Khairallah, S. A.; Rubencik, A. M.

    2015-12-29

    The production of metal parts via laser powder bed fusion additive manufacturing is growing exponentially. However, the transition of this technology from production of prototypes to production of critical parts is hindered by a lack of confidence in the quality of the part. Confidence can be established via a fundamental understanding of the physics of the process. It is generally accepted that this understanding will be increasingly achieved through modeling and simulation. However, there are significant physics, computational, and materials challenges stemming from the broad range of length and time scales and temperature ranges associated with the process. In this study, we review the current state of the art and describe the challenges that need to be met to achieve the desired fundamental understanding of the physics of the process.

  20. Laser powder bed fusion additive manufacturing of metals; physics, computational, and materials challenges

    SciTech Connect

    King, W. E.; Anderson, A. T.; Ferencz, R. M.; Hodge, N. E.; Khairallah, S. A.; Kamath, C.; Rubenchik, A. M.

    2015-12-15

    The production of metal parts via laser powder bed fusion additive manufacturing is growing exponentially. However, the transition of this technology from production of prototypes to production of critical parts is hindered by a lack of confidence in the quality of the part. Confidence can be established via a fundamental understanding of the physics of the process. It is generally accepted that this understanding will be increasingly achieved through modeling and simulation. However, there are significant physics, computational, and materials challenges stemming from the broad range of length and time scales and temperature ranges associated with the process. In this paper, we review the current state of the art and describe the challenges that need to be met to achieve the desired fundamental understanding of the physics of the process.

  1. Laser powder bed fusion additive manufacturing of metals; physics, computational, and materials challenges

    NASA Astrophysics Data System (ADS)

    King, W. E.; Anderson, A. T.; Ferencz, R. M.; Hodge, N. E.; Kamath, C.; Khairallah, S. A.; Rubenchik, A. M.

    2015-12-01

    The production of metal parts via laser powder bed fusion additive manufacturing is growing exponentially. However, the transition of this technology from production of prototypes to production of critical parts is hindered by a lack of confidence in the quality of the part. Confidence can be established via a fundamental understanding of the physics of the process. It is generally accepted that this understanding will be increasingly achieved through modeling and simulation. However, there are significant physics, computational, and materials challenges stemming from the broad range of length and time scales and temperature ranges associated with the process. In this paper, we review the current state of the art and describe the challenges that need to be met to achieve the desired fundamental understanding of the physics of the process.

  2. Laser powder bed fusion additive manufacturing of metals; physics, computational, and materials challenges

    DOE PAGESBeta

    King, W. E.; Anderson, A. T.; Ferencz, R. M.; Hodge, N. E.; Kamath, C.; Khairallah, S. A.; Rubencik, A. M.

    2015-12-29

    The production of metal parts via laser powder bed fusion additive manufacturing is growing exponentially. However, the transition of this technology from production of prototypes to production of critical parts is hindered by a lack of confidence in the quality of the part. Confidence can be established via a fundamental understanding of the physics of the process. It is generally accepted that this understanding will be increasingly achieved through modeling and simulation. However, there are significant physics, computational, and materials challenges stemming from the broad range of length and time scales and temperature ranges associated with the process. In thismore » study, we review the current state of the art and describe the challenges that need to be met to achieve the desired fundamental understanding of the physics of the process.« less

  3. Mission and spacecraft support functions of the Materials Engineering Branch: A space oriented technology resource

    NASA Technical Reports Server (NTRS)

    Fisher, A.; Staugaitis, C. L.

    1974-01-01

    The capabilities of the Materials Engineering Branch (MEB) of the Goddard Space Flight Center, Greenbelt, Maryland, are surveyed. The specific functions of spacecraft materials review, materials processing and information dissemination, and laboratory support, are outlined in the Activity Report. Further detail is provided by case histories of laboratory satellite support and equipment. Project support statistics are shown, and complete listings of MEB publications, patents, and tech briefs are included. MEB staff, and their respective discipline areas and spacecraft liaison associations, are listed.

  4. 21 CFR 570.14 - Indirect food additives resulting from packaging materials for animal feed and pet food.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... materials for animal feed and pet food. 570.14 Section 570.14 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES General Provisions § 570.14 Indirect food additives resulting from packaging materials for animal feed...

  5. 21 CFR 570.14 - Indirect food additives resulting from packaging materials for animal feed and pet food.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... materials for animal feed and pet food. 570.14 Section 570.14 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES General Provisions § 570.14 Indirect food additives resulting from packaging materials for animal feed...

  6. 21 CFR 570.14 - Indirect food additives resulting from packaging materials for animal feed and pet food.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... materials for animal feed and pet food. 570.14 Section 570.14 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES General Provisions § 570.14 Indirect food additives resulting from packaging materials for animal feed...

  7. 21 CFR 570.14 - Indirect food additives resulting from packaging materials for animal feed and pet food.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... materials for animal feed and pet food. 570.14 Section 570.14 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES General Provisions § 570.14 Indirect food additives resulting from packaging materials for animal feed...

  8. 21 CFR 570.14 - Indirect food additives resulting from packaging materials for animal feed and pet food.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... materials for animal feed and pet food. 570.14 Section 570.14 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS FOOD ADDITIVES General Provisions § 570.14 Indirect food additives resulting from packaging materials for animal feed...

  9. Internet and paper self-help materials for problem drinking: is there an additive effect?

    PubMed

    Cunningham, John A; Humphreys, Keith; Koski-Jännes, Anja; Cordingley, Joanne

    2005-09-01

    The objective of this study was to conduct a preliminary evaluation of an Internet-based intervention for problem drinkers, comparing changes in drinking between respondents who only received the intervention to those who also received a self-help book. After receiving a personalized feedback summary on the Internet, 83 respondents provided complete baseline information and volunteered to participate in a 3-month follow-up survey. Half of the respondents were randomized to receive an additional self-help book. The follow-up was returned by 48 respondents (69% female). Repeated measures ANOVAs were conducted to compare drinking levels at baseline and 3-month follow-up among respondents who only received the Internet-based intervention. There was minimal support for an impact of the Internet intervention alone. In addition, hierarchical regression analyses were conducted to compare respondents in the two intervention conditions on their drinking at follow-up, controlling for baseline consumption. Respondents who received the additional self-help book reported drinking less and experiencing fewer consequences at follow-up as compared to respondents who received only the Internet-based intervention. While the results are promising, they cannot be taken as evidence of the efficacy of Internet-based personalized feedback as a stand-alone intervention because of the absence of a control group that did not receive the intervention. Further research on this topic should be a priority because of the potential for Internet-based interventions to reach problem drinkers underserved by traditional treatment. PMID:15893433

  10. Process Feasibility Study in Support of Silicon Material, Task 1

    NASA Technical Reports Server (NTRS)

    Li, K. Y.; Hansen, K. C.; Yaws, C. L.

    1979-01-01

    During this reporting period, major activies were devoted to process system properties, chemical engineering and economic analyses. Analyses of process system properties was continued for materials involved in the alternate processes under consideration for solar cell grade silicon. The following property data are reported for silicon tetrafluoride: critical constants, vapor pressure, heat of varporization, heat capacity, density, surface tension, viscosity, thermal conductivity, heat of formation and Gibb's free energy of formation. Chemical engineering analysis of the BCL process was continued with primary efforts being devoted to the preliminary process design. Status and progress are reported for base case conditions; process flow diagram; reaction chemistry; material and energy balances; and major process equipment design.

  11. Characteristics of phase-change materials containing oxide nano-additives for thermal storage

    PubMed Central

    2012-01-01

    In this study, the authors report the production of nanocomposite-enhanced phase-change materials (NEPCMs) using the direct-synthesis method by mixing paraffin with alumina (Al2O3), titania (TiO2), silica (SiO2), and zinc oxide (ZnO) as the experimental samples. Al2O3, TiO2, SiO2, and ZnO were dispersed into three concentrations of 1.0, 2.0, and 3.0 wt.%. Through heat conduction and differential scanning calorimeter experiments to evaluate the effects of varying concentrations of the nano-additives on the heat conduction performance and thermal storage characteristics of NEPCMs, their feasibility for use in thermal storage was determined. The experimental results demonstrate that TiO2 is more effective than the other additives in enhancing both the heat conduction and thermal storage performance of paraffin for most of the experimental parameters. Furthermore, TiO2 reduces the melting onset temperature and increases the solidification onset temperature of paraffin. This allows the phase-change heat to be applicable to a wider temperature range, and the highest decreased ratio of phase-change heat is only 0.46%, compared to that of paraffin. Therefore, this study demonstrates that TiO2, added to paraffin to form NEPCMs, has significant potential for enhancing the thermal storage characteristics of paraffin. PMID:23127224

  12. Passive vibration control in rotor dynamics: Optimization of composed support using viscoelastic materials

    NASA Astrophysics Data System (ADS)

    Ribeiro, Eduardo Afonso; Pereira, Jucélio Tomás; Alberto Bavastri, Carlos

    2015-09-01

    One of the major reasons for inserting damping into bearings is that rotating machines are often requested in critical functioning conditions having sometimes to function under dynamic instability or close to critical speeds. Hydrodynamic and magnetic bearings have usually been used for this purpose, but they present limitations regarding costs and operation, rendering the use of viscoelastic supports a feasible solution for vibration control in rotating machines. Most papers in the area use simple analytic or single degree of freedom models for the rotor as well as classic mechanical models of linear viscoelasticity for the support - like Maxwell, Kelvin-Voigt, Zenner, four-element, GHM models and even frequency independent models - but they lack the accuracy of fractional models in a large range of frequency and temperature regarding the same number of coefficients. Even in those works, the need to consider the addition of degrees of freedom to the support is evident. However, so far no paper has been published focusing on a methodology to determine the optimal constructive form for any viscoelastic support in which the rotor is discretized by finite elements associated to an accurate model for characterizing the viscoelastic material. In general, the support is meant to be a simple isolation system, and the fact the stiffness matrix is complex and frequency-temperature dependent - due to its viscoelastic properties - forces the traditional methods to require an extremely long computing time, thus rendering them too time consuming in an optimization environment. The present work presents a robust methodology based mainly on generalized equivalent parameters (GEP) - for an optimal design of viscoelastic supports for rotating machinery - aiming at minimizing the unbalance frequency response of the system using a hybrid optimization technique (genetic algorithms and Nelder-Mead method). The rotor is modeled based on the finite element method using Timoshenko's thick

  13. Research Opportunities Supporting the Vision for Space Exploration from the Transformation of the Former Microgravity Materials Science Program

    NASA Technical Reports Server (NTRS)

    Clinton, R. G., Jr.; Szofran, Frank; Bassler, Julie A.; Schlagheck, Ronald A.; Cook, Mary Beth

    2005-01-01

    The Microgravity Materials Science Program established a strong research capability through partnerships between NASA and the scientific research community. With the announcement of the vision for space exploration, additional emphasis in strategic materials science areas was necessary. The President's Commission recognized that achieving its exploration objectives would require significant technical innovation, research, and development in focal areas defined as "enabling technologies." Among the 17 enabling technologies identified for initial focus were: advanced structures, advanced power and propulsion; closed-loop life support and habitability; extravehicular activity systems; autonomous systems and robotics; scientific data collection and analysis, biomedical risk mitigation; and planetary in situ resource utilization. Mission success may depend upon use of local resources to fabricate a replacement part to repair a critical system. Future propulsion systems will require materials with a wide range of mechanical, thermophysical, and thermochemical properties, many of them well beyond capabilities of today's materials systems. Materials challenges have also been identified by experts working to develop advanced life support systems. In responding to the vision for space exploration, the Microgravity Materials Science Program aggressively transformed its research portfolio and focused materials science areas of emphasis to include space radiation shielding; in situ fabrication and repair for life support systems; in situ resource utilization for life support consumables; and advanced materials for exploration, including materials science for space propulsion systems and for life support systems. The purpose of this paper is to inform the scientific community of these new research directions and opportunities to utilize their materials science expertise and capabilities to support the vision for space exploration.

  14. Action Research to Support Teachers' Classroom Materials Development

    ERIC Educational Resources Information Center

    Edwards, Emily; Burns, Anne

    2016-01-01

    Language teachers constantly create, adapt and evaluate classroom materials to develop new curricula and meet their learners' needs. It has long been argued (e.g. by Stenhouse, L. [1975]. "An Introduction to Curriculum Research and Development." London: Heinemann) that teachers themselves, as opposed to managers or course book writers,…

  15. Develop Improved Materials to Support the Hydrogen Economy

    SciTech Connect

    Dr. Michael C. Martin

    2012-07-18

    The Edison Materials Technology Center (EMTEC) solicited and funded hydrogen infrastructure related projects that have a near term potential for commercialization. The subject technology of each project is related to the US Department of Energy hydrogen economy goals as outlined in the multi-year plan titled, 'Hydrogen, Fuel Cells and Infrastructure Technologies Program Multi-Year Research, Development and Demonstration Plan.' Preference was given to cross cutting materials development projects that might lead to the establishment of manufacturing capability and job creation. The Edison Materials Technology Center (EMTEC) used the US Department of Energy hydrogen economy goals to find and fund projects with near term commercialization potential. An RFP process aligned with this plan required performance based objectives with go/no-go technology based milestones. Protocols established for this program consisted of a RFP solicitation process, white papers and proposals with peer technology and commercialization review (including DoE), EMTEC project negotiation and definition and DoE cost share approval. Our RFP approach specified proposals/projects for hydrogen production, hydrogen storage or hydrogen infrastructure processing which may include sensor, separator, compression, maintenance, or delivery technologies. EMTEC was especially alert for projects in the appropriate subject area that have cross cutting materials technology with near term manufacturing and commercialization opportunities.

  16. Physics of Granular Materials: Investigations in Support of Astrobiology

    NASA Technical Reports Server (NTRS)

    Marshall, John R.

    2002-01-01

    This publication list is submitted as a summary of the work conducted under Cooperative Agreement 1120. The goal of the 1120 research was to study granular materials within a planetary, astrophysical, and astrobiological context. This involved research on the physical, mechanical and electrostatic properties of granular systems, as well as the examination of these materials with atomic force microscopy and x-ray analysis. Instruments for analyzing said materials in planetary environments were developed, including the MECA (Mars Environment Compatibility Assessment) experiment for the MSP '01 lander, the ECHOS/MATADOR experiment for the MSP '03 lander, an ISRU experiment for the '03 lander, and MiniLEAP technology. Flight experiments for microgravity (Space Station and Shuttle) have also been developed for the study of granular materials. As expressed in the publications, work on 1120 encompassed laboratory research, theoretical modeling, field experiments, and flight experiments: a series of successful new models were developed for understanding the behavior of triboelectrostatically charged granular masses, and 4 separate instruments were selected for space flight. No inventions or patents were generated by the research under this Agreement.

  17. Instruments and Supporting Materials for Practical Skills Testing in Science.

    ERIC Educational Resources Information Center

    Kay, Chris; And Others

    1992-01-01

    Student test booklets, equipment and materials lists, directions for set-up, and directions for administration are given in English for the six countries participating in the science practical skills testing portions of the Second International Association for the Evaluation of Educational Improvement Science Study. (SLD)

  18. Information Support for Using Open Learning Materials within Engineering Education.

    ERIC Educational Resources Information Center

    Cox, Stephen M.; Davies, D. T.

    1987-01-01

    Reviewed are some current trends in engineering education in the UK, particularly those toward open and distance learning. A case study is provided that shows a recent move to develop relevant and up-to-date course materials in the area of Advanced Manufacturing Technology for undergraduates through collaboration between academic and library…

  19. Materials support for HITAF. Final report for Phase 1

    SciTech Connect

    Breder, K.; Tennery, V.J.

    1995-03-01

    Improvements in coal-fired systems will require a change from steam turbines to gas turbines using air as working fluid; pressurized ceramic heat exchangers operating up to 1600 C will be needed. Leading candidate materials are SiC-based ceramics. Mechanical properties of 3 materials are compared in this work: NT230 Si/SiC from Saint Gobain Norton, {beta}-SiC from Coors Ceramics Co., and Lanxide DIMOX SiCp/Al{sub 2}O{sub 3} from Du Pont Lanxide Composites Inc. The first material is siliconized Si carbide, the second is sintered. They all were tested in 4-point flexure at RT and 1100 and 1400 C. Fast-fracture tests were carried out. Slow crack growth was investigated. Failure modes were studied using optical microscopy and SEM. Four materials were exposed to two coal ashes at two different temperatures. In the comparison, Coors {beta}-SiC stands out from a strength and reliability standpoint when exposed to air at high temperatures. Lanxide DIMOX withstood coal ash exposure well.

  20. Microanalytical Efforts in Support of NASA's Materials Science Programs

    NASA Technical Reports Server (NTRS)

    Gillies, Donald C.

    2004-01-01

    Following a brief overview of NASA s Microgravity Materials Science programs, specific examples will be given showing electron beam and optical microscopic applications to two-phase glass structures, dendrite tip radii, solid solution semiconductors, undercooled two-phase stainless steels and meteorites.

  1. Basic Science Research to Support the Nuclear Materials Focus Area

    SciTech Connect

    Chipman, N. A.; Castle, P. M.; Boak, J. M.; Eller, P. G.

    2002-02-26

    The Department of Energy's (DOE's) Office of Environmental Management (EM) is responsible for managing more than 760,000 metric tons of nuclear material that is excess to the current DOE weapons program, as a result of shutdown of elements of the weapons program, mainly during the 1990s. EMowned excess nuclear material comprises a variety of material types, including uranium, plutonium, other actinides and other radioactive elements in numerous forms, all of which must be stabilized for storage and ultimate disposition. Much of this quantity has been in storage for many years. Shutdown of DOE sites and facilities requires removal of nuclear material and consolidation at other sites, and may be delayed by the lack of available technology. Within EM, the Office of Science and Technology (OST) is dedicated to providing timely, relevant technology to accelerate completion and reduce cleanup cost of the DOE environmental legacy. OST is organized around five focus areas, addressing crucial areas of end-user-defined technology need. The Focus Areas regularly identify potential technical solutions for which basic scientific research is needed to determine if the technical solution can be developed and deployed. To achieve a portfolio of projects that is balanced between near-term priorities driven by programmatic risks (such as site closure milestones) and long-term, high-consequence needs that depend on extensive research and development, OST has established the Environmental Management Science Program (EMSP) to develop the scientific basis for solutions to long-term site needs. The EMSP directs calls for proposals to address scientific needs of the focus areas. Needs are identified and validated annually by individual sites in workshops conducted across the complex. The process captures scope and schedule requirements of the sites, so that focus areas can identify technology that can be delivered to sites in time to complete site cleanup. The Nuclear Material Focus Area

  2. Basic science research to support the nuclear material focus area

    SciTech Connect

    Boak, J. M.; Eller, P. Gary; Chipman, N. A.; Castle, P. M.

    2002-01-01

    The Department of Energy's (DOE'S) Office of Environmental Management (EM) is responsible for managing more than 760,000 metric tons of nuclear material that is excess to the current DOE weapons program, as a result of shutdown of elements of the weapons program, mainly during the 1990s. EMowned excess nuclear material comprises a variety of material types, including uranium, plutonium, other actinides and other radioactive elements in numerous forms, all of which must be stabilized for storage and ultimate disposition. Much of this quantity has been in storage for many years. Shutdown of DOE sites and facilities requires removal of nuclear material and consolidation at other sites, and may be delayed by the lack of available technology. Within EM, the Office of Science and Technology (OST) is dedicated to providing timely, relevant technology to accelerate completion and reduce cleanup cost of the DOE environmental legacy. OST is organized around five focus areas, addressing crucial areas of end-user-defined technology need. The Focus Areas regularly identify potential technical solutions for which basic scientific research is needed to determine if the technical solution can be developed and deployed. To achieve a portfolio of projects that is balanced between near-term priorities driven by programmatic risks (such as site closure milestones) and long-term, high-consequence needs that depend on extensive research and development, OST has established the Environmental Management Science Program (EMSP) to develop the scientific basis for solutions to long-term site needs. The EMSP directs calls for proposals to address scientific needs of the focus areas. Needs are identified and validated annually by individual sites in workshops conducted across the complex. The process captures scope and schedule requirements of the sites, so that focus areas can identify technology that can be delivered to sites in time to complete site cleanup. The Nuclear Material Focus Area

  3. Paleomagnetism of Silver Island, Keweenaw Peninsula, Michigan: Additional Support (?) for the Primary Curvature of the MCR

    NASA Astrophysics Data System (ADS)

    Diehl, J. F.; Durant, A. J.; Schepke, C.

    2009-05-01

    Silver Island lies between Eagle Harbor and Copper Harbor on the NW coastline of the Keweenaw Peninsula, Michigan. The island consists of a series of basaltic lava flows which dip to the north-northwest (356°) at an angle of approximately 38°. These flows constitute part of the Lake Shore Traps (LST), a series of interbedded lava flows within the Copper Harbor Conglomerate (CHC). The LST represent the youngest eruptive material associated with the 1.1 Ga Mid-Continent Rift (MCR). The most recent paleomagnetic study (now 15 years old) on the Lakeshore Traps (LST) defined three distinct directional clusters. Each cluster of directions corresponded to a different stratigraphic package of the LST within the CHC and all have extremely low between-site dispersion (s ˜ 4°) suggesting rather rapid emplacement of the LST packages. Consequently, each cluster has its own unique direction of magnetization. Since the lower two LST packages crop out along the coast line of the Peninsula with different structural trends, an opportunity was presented to test the conclusions of Hnat et al. (2006) that the curvature of the MCR was primary. To that end nine lava flows were sampled on Silver Island and their mean direction compared to the equivalent mean from lava flows sampled by Diehl and Haig (1994) from the tip of the Keweenaw Peninsula (upper lava flows of the Middle LST) which have an entirely different structural trend. Characteristic directions of magnetization of the Silver Island lava flows were isolated either using alternating field, thermal or a combination of both. The mean direction of magnetization for the nine sites is: D = 277.7°, I = 46.9°, α95 = 3.0°, k = 292.5. The mean direction recalculated from the Diehl and Haig study is: D = 277.8°, I = 40.6°, α95 = 2.9°, k = 315.7. Although the declinations of the two means are identical, interestingly the two means are statistically distinct at the 95% confidence level. Fold tests were inconclusive. Nevertheless

  4. Process feasibility study in support of silicon material task 1

    NASA Technical Reports Server (NTRS)

    Li, K. Y.; Hansen, K. C.; Yaws, C. L.

    1978-01-01

    Process system properties are analyzed for materials involved in the alternate processes under consideration for solar cell grade silicon. The following property data are reported for trichlorosilane: critical constants, vapor pressure, heat of vaporization, gas heat capacity, liquid heat capacity, density, surface tension, viscosity, thermal conductivity, heat of formation, and Gibb's free energy of formation. Work continued on the measurement of gas viscosity values of silicon source materials. Gas phase viscosity values for silicon tetrafluoride between 40 C and 200 C were experimentally determined. Major efforts were expended on completion of the preliminary economic analysis of the silane process. Cost, sensitivity and profitability analysis results are presented based on a preliminary process design of a plant to produce 1,000 metric tons/year of silicon by the revised process.

  5. Process feasibility study in support of silicon material task 1

    NASA Technical Reports Server (NTRS)

    Fang, C. S.; Hansen, K. C.; Miller, J. W., Jr.; Yaws, C. L.

    1978-01-01

    Initial results for gas thermal conductivity of silicon tetrafluoride and trichlorosilane are reported in respective temperature ranges of 25 to 400 C and 50 to 400 C. For chemical engineering analyses, the preliminary process design for the original silane process of Union Carbide was completed for Cases A and B, Regular and Minimum Process Storage. Included are raw material usage, utility requirements, major process equipment lists, and production labor requirements. Because of the large differences in surge tankage between major unit operations the fixed capital investment varied from $19,094,000 to $11,138,000 for Cases A and B, respectively. For the silane process the original flowsheet was revised for a more optimum arrangement of major equipment, raw materials and operating conditions. The initial issue of the revised flowsheet (Case C) for the silane process indicated favorable cost benefits over the original scheme.

  6. Light-harvesting materials: Soft support for energy conversion

    SciTech Connect

    Stolley, Ryan M.; Helm, Monte L.

    2014-11-10

    To convert solar energy into viable fuel sources, coupling light-harvesting materials to catalysts is a critical challenge. Now, coupling between an organic supramolecular hydrogel and a non precious metal catalyst has been demonstrated to be effective for photocatalytic H2 production. Ryan M. Stolley and Monte L. Helm are at Pacific Northwest National Laboratory (PNNL), Richland, WA, USA 99352. PNNL is operated by Battelle for the US Department of Energy. e-mail: Monte.Helm@pnnl.gov

  7. 36 CFR 1290.4 - Types of materials included in scope of assassination record and additional records and information.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... scope of assassination record and additional records and information. 1290.4 Section 1290.4 Parks... COLLECTION ACT OF 1992 (JFK ACT) § 1290.4 Types of materials included in scope of assassination record and additional records and information. The term record in assassination record and additional records...

  8. 36 CFR 1290.4 - Types of materials included in scope of assassination record and additional records and information.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... in scope of assassination record and additional records and information. 1290.4 Section 1290.4 Parks... COLLECTION ACT OF 1992 (JFK ACT) § 1290.4 Types of materials included in scope of assassination record and additional records and information. The term record in assassination record and additional records...

  9. 36 CFR 1290.4 - Types of materials included in scope of assassination record and additional records and information.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... in scope of assassination record and additional records and information. 1290.4 Section 1290.4 Parks... COLLECTION ACT OF 1992 (JFK ACT) § 1290.4 Types of materials included in scope of assassination record and additional records and information. The term record in assassination record and additional records...

  10. Polymeric Materials With Additives for Durability and Radiation Shielding in Space

    NASA Technical Reports Server (NTRS)

    Kiefer, Richard

    2011-01-01

    Polymeric materials are attractive for use in space structures because of their light weight and high strength In addition, polymers are made of elements with low atomic numbers (Z), primarily carbon (C), hydrogen (H), oxygen (0), and nitrogen (N) which provide the best shielding from galactic cosmic rays (GCR) (ref. 1). Galactic cosmic rays are composed primarily of nuclei (i.e., fully ionized atoms) plus a contribution of about 2% from electrons and positrons. There is a small but significant component of GCR particles with high charge (Z > 10) and high energy (E >100 GeV) (ref. 2). These so-called HZE particles comprise only 1 to 2% of the cosmic ray fluence but they interact with very high specific ionization and contribute 50% of the long- term dose to humans. The best shield for this radiation would be liquid hydrogen, which is not feasible. For this reason, hydrogen-containing polymers make the most effective practical shields. Moreover, neutrons are formed in the interactions of GCR particles with materials. Neutrons can only lose energy by collisions or reactions with a nucleus since they are uncharged. This is a process that is much less probable than the Coulombic interactions of charged particles. Thus, neutrons migrate far from the site of the reaction in which they were formed. This increases the probability of neutrons reaching humans or electronic equipment. Fast neutrons (> 1 MeV) can interact with silicon chips in electronic equipment resulting in the production of recoil ions which can cause single event upsets (SEU) in sensitive components (ref. 3). Neutrons lose energy most effectively by elastic collisions with light atoms, particularly hydrogen atoms. Therefore, hydrogen-containing polymers are not only effective in interacting with GCR particles; they are also effective in reducing the energy of the neutrons formed in the interactions.

  11. A NIST standard reference material (SRM) to support the detection of trace explosives.

    PubMed

    MacCrehan, William A

    2009-09-01

    SRM 2905 Trace Particulate Explosives was developed to simulate the residues produced by handling plastic and military explosives. A series of nine candidate materials were prepared by coating chromatographic supports with either Composition C-4 (containing RDX (hexahydro-1,3,5-trinitro-1,3,5-Triazine) and HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-Tetrazocine)) or TNT (2,4,6-trinitrotoluene). Criteria for selection of the best material for the SRM included: coating efficiency, extractability with organic solvents, thermal storage stability, consistency of the particle size with fingerprint residues, and suitability for calibration of trace explosives detectors. The final base material selected for the SRM was octadecylsilane-modified silica (C(18)) with a nominal 20-30 microm particle size. Four materials comprise the SRM, with two nominal concentrations of explosive, 0.01% and 0.1% (mass fraction) for both C-4 and TNT, respectively. The final certified concentrations were determined by liquid chromatography (LC) with ultraviolet absorbance detection (LC/UV) and a liquid chromatography with mass spectrometric (LC/MS) method using negative ion atmospheric pressure ionization (APCI(-)) with an acetate ionization additive that improves quantitation. The SRM was tested on a table-top field explosives detector based ion mobility spectrometry (IMS). PMID:19637901

  12. Linking process, structure, property, and performance for metal-based additive manufacturing: computational approaches with experimental support

    NASA Astrophysics Data System (ADS)

    Smith, Jacob; Xiong, Wei; Yan, Wentao; Lin, Stephen; Cheng, Puikei; Kafka, Orion L.; Wagner, Gregory J.; Cao, Jian; Liu, Wing Kam

    2016-04-01

    Additive manufacturing (AM) methods for rapid prototyping of 3D materials (3D printing) have become increasingly popular with a particular recent emphasis on those methods used for metallic materials. These processes typically involve an accumulation of cyclic phase changes. The widespread interest in these methods is largely stimulated by their unique ability to create components of considerable complexity. However, modeling such processes is exceedingly difficult due to the highly localized and drastic material evolution that often occurs over the course of the manufacture time of each component. Final product characterization and validation are currently driven primarily by experimental means as a result of the lack of robust modeling procedures. In the present work, the authors discuss primary detrimental hurdles that have plagued effective modeling of AM methods for metallic materials while also providing logical speculation into preferable research directions for overcoming these hurdles. The primary focus of this work encompasses the specific areas of high-performance computing, multiscale modeling, materials characterization, process modeling, experimentation, and validation for final product performance of additively manufactured metallic components.

  13. From waste biomass to solid support: lignosulfonate as a cost-effective and renewable supporting material for catalysis.

    PubMed

    Sun, Shaohuan; Bai, Rongxian; Gu, Yanlong

    2014-01-01

    Lignosulfonate (LS) is an organic waste generated as a byproduct of the cooking process in sulfite pulping in the manufacture of paper. In this paper, LS was used as an anionic supporting material for immobilizing cationic species, which can then be used as heterogeneous catalysts in some organic transformations. With this strategy, three lignin-supported catalysts were prepared including 1) lignin-SO3 Sc(OTf)2 , 2) lignin-SO3 Cu(OTf), and 3) lignin-IL@NH2 (IL=ionic liquid). These solid materials were then examined in many organic transformations. It was finally found that, compared with its homogeneous counterpart as well as some other solid catalysts that are prepared by using different supports with the same metal or catalytically active species, the lignin-supported catalysts showed better performance in these reactions not only in terms of activity but also with regard to recyclability. PMID:24307475

  14. Longevity of Emplacement Drift Ground Support Materials for LA

    SciTech Connect

    D. Tang

    2003-09-16

    The purpose of this analysis report is to evaluate and document the inclusion or exclusion of the disruptive events features, events, and processes (FEPs) with respect to modeling used to support the total system performance assessment for license application (TSPA-LA). A screening decision, either ''Included'' or ''Excluded,'' is given for each FEP, along with the technical basis for screening decisions. This information is required by the U.S. Nuclear Regulatory Commission (NRC) at 10 CFR 63.114 (d), (e), and (f) [DIRS 156605]. The FEPs addressed in this report deal with both seismic and igneous disruptive events, such as fault displacements through the repository and an igneous intrusion into the repository. For included FEPs, this analysis summarizes the implementation of the FEP in TSPA-LA (i.e., how the FEP is included). For excluded FEPs, this analysis provides the technical basis for exclusion from TSPA-LA (i.e., why the FEP is excluded). Previous versions of this report were developed to support the total system performance assessments (TSPA) for various prior repository designs. This revision addresses the repository design for the license application (LA).

  15. Supporting the Global Threat Reduction Initiative through Nuclear Material Recovery: Collaboration between NNSA and AREVA

    SciTech Connect

    Bieniawski, Andrew; Sheely, Ken; Hunter, Ian; Louvet, Thibault

    2007-07-01

    The Global Threat Reduction Initiative (GTRI) was established by the U.S. Department of Energy National Nuclear Security Administration (NNSA) in response to the growing need to comprehensively and internationally address the potential threat posed by vulnerable high-risk nuclear material. GTRI's mission is to foster international support for national programs to identify, secure, remove and/or facilitate the disposition, as quickly and expeditiously as possible, of vulnerable, high-risk nuclear and other radioactive materials around the world that pose a potential threat to the international community. Specifically, GTRI establishes international partnerships to address this global issue. To achieve these objectives, GTRI works with international, regional, and domestic partners to: (1) minimize and, to the extent possible, eliminate the use of highly enriched uranium (HEU) in civil nuclear applications worldwide by converting research reactors to LEU fuels; (2) accelerate the removal or final disposition of vulnerable nuclear material throughout the world; (3) accelerate securing and/or removing vulnerable high-risk radiological materials throughout the world; and (4) address the 'gaps' of other programs by identifying throughout the world, recovering and facilitating permanent disposition of vulnerable high-risk nuclear material not previously addressed by other threat reduction programs. DOE desires to work with more partners, both government and industry, to develop options for the disposal of nuclear material in the most expeditious manner. This paper will present the recent success of the first Plutonium Gap Material recycling contract signed by AREVA thanks to the collaboration developed between NNSA and AREVA. Another item which will be presented and illustrates how GTRI supports government-to-industry partnership, is the willingness to consider the treatment option for Gap Materials used-fuel. This new step represents another broadening of the

  16. Improved thermal storage material for portable life support systems

    NASA Technical Reports Server (NTRS)

    Kellner, J. D.

    1975-01-01

    The availability of thermal storage materials that have heat absorption capabilities substantially greater than water-ice in the same temperature range would permit significant improvements in performance of projected portable thermal storage cooling systems. A method for providing increased heat absorption by the combined use of the heat of solution of certain salts and the heat of fusion of water-ice was investigated. This work has indicated that a 30 percent solution of potassium bifluoride (KHF2) in water can absorb approximately 52 percent more heat than an equal weight of water-ice, and approximately 79 percent more heat than an equal volume of water-ice. The thermal storage material can be regenerated easily by freezing, however, a lower temperature must be used, 261 K as compared to 273 K for water-ice. This work was conducted by the United Aircraft Research Laboratories as part of a program at Hamilton Standard Division of United Aircraft Corporation under contract to NASA Ames Research Center.

  17. Process Feasibility Study in Support of Silicon Material Task 1

    NASA Technical Reports Server (NTRS)

    Li, K. Y.; Hansen, K. C.; Yaws, C. L.

    1979-01-01

    Analysis of process system properties was continued for silicon source materials under consideration for producing silicon. The following property data are reported for dichlorosilane which is involved in processing operations for silicon: critical constants, vapor pressure, heat of vaporization, heat capacity, density, surface tension, thermal conductivity, heat of formation and Gibb's free energy of formation. The properties are reported as a function of temperature to permit rapid engineering usage. The preliminary economic analysis of the process is described. Cost analysis results for the process (case A-two deposition reactors and six electrolysis cells) are presented based on a preliminary process design of a plant to produce 1,000 metric tons/year of silicon. Fixed capital investment estimate for the plant is $12.47 million (1975 dollars) ($17.47 million, 1980 dollars). Product cost without profit is 8.63 $/kg of silicon (1975 dollars)(12.1 $/kg, 1980 dollars).

  18. Metallic and Non-Metallic Materials for the Primary Support Structure

    SciTech Connect

    RA Wolf; RP Corson

    2006-02-21

    The primary support structure (PSS) is required for mechanical support of reactor module (RM) components and mounting of the RM to the spacecraft. The PSS would provide support and accept all loads associated with dynamic (e. g., launch and maneuvering) or thermally induced loading. Prior to termination of NRPCT involvement in Project Prometheus, the NRPCT Mechanical Systems team developed preliminary finite element models to gain a basic understanding of the behavior of the structure, but optimization of the models, specification of the final design, and materials selection were not completed. The Space Plant Materials team had evaluated several materials for potential use in the primary support structure, namely titanium alloys, beryllium, aluminum alloys and carbon-carbon composites. The feasibility of application of each material system was compared based on mass, stiffness, thermal expansion, and ease of fabrication. Due to insufficient data on environmental factors, such as temperatures and radiation, and limited modeling support, a final materials selection was not made.

  19. Data Collection Handbook to Support Modeling Impacts of Radioactive Material in Soil and Building Structures

    SciTech Connect

    Yu, Charley; Kamboj, Sunita; Wang, Cheng; Cheng, Jing-Jy

    2015-09-01

    This handbook is an update of the 1993 version of the Data Collection Handbook and the Radionuclide Transfer Factors Report to support modeling the impact of radioactive material in soil. Many new parameters have been added to the RESRAD Family of Codes, and new measurement methodologies are available. A detailed review of available parameter databases was conducted in preparation of this new handbook. This handbook is a companion document to the user manuals when using the RESRAD (onsite) and RESRAD-OFFSITE code. It can also be used for RESRAD-BUILD code because some of the building-related parameters are included in this handbook. The RESRAD (onsite) has been developed for implementing U.S. Department of Energy Residual Radioactive Material Guidelines. Hydrogeological, meteorological, geochemical, geometrical (size, area, depth), crops and livestock, human intake, source characteristic, and building characteristic parameters are used in the RESRAD (onsite) code. The RESRAD-OFFSITE code is an extension of the RESRAD (onsite) code and can also model the transport of radionuclides to locations outside the footprint of the primary contamination. This handbook discusses parameter definitions, typical ranges, variations, and measurement methodologies. It also provides references for sources of additional information. Although this handbook was developed primarily to support the application of RESRAD Family of Codes, the discussions and values are valid for use of other pathway analysis models and codes.

  20. The Impact of Emotional and Material Social Support on Women's Drug Treatment Completion

    ERIC Educational Resources Information Center

    Lewandowski, Cathleen A.; Hill, Twyla J.

    2009-01-01

    This study assessed how women's perceptions of emotional and material social support affect their completion of residential drug treatment. Although previous research has examined how social support affects recovery, few studies, if any, have examined both the types and the sources of social support. The study hypothesized that women's perceptions…

  1. Materials study supporting thermochemical hydrogen cycle sulfuric acid decomposer design

    NASA Astrophysics Data System (ADS)

    Peck, Michael S.

    Increasing global climate change has been driven by greenhouse gases emissions originating from the combustion of fossil fuels. Clean burning hydrogen has the potential to replace much of the fossil fuels used today reducing the amount of greenhouse gases released into the atmosphere. The sulfur iodine and hybrid sulfur thermochemical cycles coupled with high temperature heat from advanced nuclear reactors have shown promise for economical large-scale hydrogen fuel stock production. Both of these cycles employ a step to decompose sulfuric acid to sulfur dioxide. This decomposition step occurs at high temperatures in the range of 825°C to 926°C dependent on the catalysis used. Successful commercial implementation of these technologies is dependent upon the development of suitable materials for use in the highly corrosive environments created by the decomposition products. Boron treated diamond film was a potential candidate for use in decomposer process equipment based on earlier studies concluding good oxidation resistance at elevated temperatures. However, little information was available relating the interactions of diamond and diamond films with sulfuric acid at temperatures greater than 350°C. A laboratory scale sulfuric acid decomposer simulator was constructed at the Nuclear Science and Engineering Institute at the University of Missouri-Columbia. The simulator was capable of producing the temperatures and corrosive environments that process equipment would be exposed to for industrialization of the sulfur iodide or hybrid sulfur thermochemical cycles. A series of boron treated synthetic diamonds were tested in the simulator to determine corrosion resistances and suitability for use in thermochemical process equipment. These studies were performed at twenty four hour durations at temperatures between 600°C to 926°C. Other materials, including natural diamond, synthetic diamond treated with titanium, silicon carbide, quartz, aluminum nitride, and Inconel

  2. Resource Materials To Support Your Environmental Education Efforts. EE-TIPS (Environmental Education Technical Information Packages).

    ERIC Educational Resources Information Center

    North American Association for Environmental Education, Troy, OH.

    This collection gathers together over 50 high-quality materials to support environmental education (EE) curricula. Because each community has unique environmental and educational needs, the guide includes a broad set of educational materials that can be adapted to a variety of settings. The materials can be used to supplement educational…

  3. Guidelines for Supporting Re-Use of Existing Digital Learning Materials and Methods in Higher Education

    ERIC Educational Resources Information Center

    Schoonenboom, Judith; Sligte, Henk; Kliphuis, Eja

    2009-01-01

    The literature on the re-use of learning materials has largely focused on the development of materials. This paper explores how re-use can be stimulated after learning materials have been developed and made available. We searched for and developed guidelines that support staff and/or management most frequently adopt in cases of (un)successful…

  4. Preparations and properties of anti-corrosion additives of water-soluble metal working fluids for aluminum alloy materials.

    PubMed

    Watanabe, Shoji

    2008-01-01

    This short review describes various types of anti-corrosion additives of water-soluble metal working fluids for aluminum alloy materials. It is concerned with synthetic additives classified according to their functional groups; silicone compounds, carboxylic acids and dibasic acids, esters, Diels-Alder adducts, various polymers, nitrogen compounds, phosphoric esters, phosphonic acids, and others. Testing methods for water-soluble metal working fluids for aluminum alloy materials are described for a practical application in a laboratory. PMID:18075217

  5. Advanced Materials in Support of EERE Needs to Advance Clean Energy Technologies Program Implementation

    SciTech Connect

    Liby, Alan L; Rogers, Hiram

    2013-10-01

    The goal of this activity was to carry out program implementation and technical projects in support of the ARRA-funded Advanced Materials in Support of EERE Needs to Advance Clean Energy Technologies Program of the DOE Advanced Manufacturing Office (AMO) (formerly the Industrial Technologies Program (ITP)). The work was organized into eight projects in four materials areas: strategic materials, structural materials, energy storage and production materials, and advanced/field/transient processing. Strategic materials included work on titanium, magnesium and carbon fiber. Structural materials included work on alumina forming austentic (AFA) and CF8C-Plus steels. The advanced batteries and production materials projects included work on advanced batteries and photovoltaic devices. Advanced/field/transient processing included work on magnetic field processing. Details of the work in the eight projects are available in the project final reports which have been previously submitted.

  6. Visible Light Enabled Photocatalytic Splitting of Water over Spatially Isolated Semiconductors Supported Mesoporous Materials

    NASA Astrophysics Data System (ADS)

    Peng, Rui

    Hydrogen generation from photocatalytic splitting of water is an ideal scenario that possesses promise for the sustainable development of human society and the establishment of the ultimate "green," infinitely renewable energy system. This work contains a series of novel photocatalytic systems in which the photoactive chromophores and/or the co-catalysts were incorporated into highly periodically cubic-phased MCM-48 mesoporous materials to achieve significantly higher photocatalytic efficiencies compared with conventional semiconductor photocatalysts. Cubic-phased MCM-48 mesoporous materials were chosen as supports to accommodate the photoactive species throughout the entire work. Several unique and iconic properties of these materials, such as large surface area, highly uniform mesoscale pores arrayed in a long-range periodicity, and an interconnected network of three-dimensional sets of pores that were recognized as positive parameters facilitated the photogenerated charge transfer and promoted the photocatalytic performance of the encapsulated photoactive species. It was validated that in the CdS/TiO2-incorporated MCM-48 photocatalytic system, the solar hydrogen conversion efficiency was prevalently governed by the photogenerated electron injection efficiency from the CdS conduction band to that of TiO2. The use of MCM-48 mesoporous host materials enabled the high and even dispersion of both CdS and TiO 2 so that the intimate and sufficient contact between CdS and TiO 2 was realized. In addition, with the presence of both TiO2 and MCM-48 mesoporous support, the photostability of CdS species was dramatically enhanced compared with that of bare CdS or CdS-incorporated MCM-48 photocatalysts. In advance, by loading the RuO2 co-catalyst into the CdS/TiO 2-incorporated MCM-48 photocatalytic system, the photocatalytic splitting of pure water to generate both hydrogen and oxygen under visible light illumination was achieved. In the various Pd-assisted, TiO2-incorporated

  7. Material Not Categorized As Waste (MNCAW) data report. Radioactive Waste Technical Support Program

    SciTech Connect

    Casey, C.; Heath, B.A.

    1992-11-01

    The Department of Energy (DOE), Headquarters, requested all DOE sites storing valuable materials to complete a questionnaire about each material that, if discarded, could be liable to regulation. The Radioactive Waste Technical Support Program entered completed questionnaires into a database and analyzed them for quantities and type of materials stored. This report discusses the data that TSP gathered. The report also discusses problems revealed by the questionnaires and future uses of the data. Appendices contain selected data about material reported.

  8. 45 CFR 1641.10 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... facts. 1641.10 Section 1641.10 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  9. 45 CFR 1641.21 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... facts. 1641.21 Section 1641.21 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  10. 45 CFR 1641.21 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... facts. 1641.21 Section 1641.21 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  11. 45 CFR 1641.21 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... facts. 1641.21 Section 1641.21 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  12. 45 CFR 1641.21 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... facts. 1641.21 Section 1641.21 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  13. 45 CFR 1641.10 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... facts. 1641.10 Section 1641.10 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  14. 45 CFR 1641.21 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... facts. 1641.21 Section 1641.21 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  15. 45 CFR 1641.10 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... facts. 1641.10 Section 1641.10 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  16. 45 CFR 1641.10 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... facts. 1641.10 Section 1641.10 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  17. 45 CFR 1641.10 - Additional proceedings as to disputed material facts.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... facts. 1641.10 Section 1641.10 Public Welfare Regulations Relating to Public Welfare (Continued) LEGAL... proceedings as to disputed material facts. (a) In actions not based upon a conviction or civil judgment under... of material fact, the IPA shall be afforded an opportunity to appear (with counsel, if...

  18. Effects of Silica Nanoparticle Supported Ionic Liquid as Additive on Thermal Reversibility of Human Carbonic Anhydrase II

    PubMed Central

    Fallahbagheri, Azadeh; Saboury, Ali Akbar; Ma'mani, Leila; Taghizadeh, Mohammad; Khodarahmi, Reza; Ranjbar, Samira; Bohlooli, Mousa; Shafiee, Abbas; Foroumadi, Alireza; Sheibani, Nader; Moosavi-Movahedi, Ali Akbar

    2013-01-01

    Silica nanoparticle supported imidazolium ionic liquid [SNImIL] was synthesized and utilized as a biocompatible additive for studying the thermal reversibility of human carbonic anhydrase II (HCA II). For this purpose, we prepared additive by modification of nanoparticles through the grafting of ionic liquids on the surface of nanoparticles (SNImIL). The SNImIL were fully characterized by Fourier Transform Infrared spectroscopy, scanning electron microscopy and thermo gravimetric analysis. The characterization of HCA II was investigated by various techniques including UV–Vis and ANS fluorescence spectrophotometry, differential scanning calorimetry, and docking study. SNImIL induced disaggregation, enhanced protein stability and increased thermal reversibility of HCA II by up to 42% at pH 7.75. PMID:22829053

  19. Evaluation of fuel additives for reduction of material imcompatibilities in methanol-gasoline blends

    NASA Technical Reports Server (NTRS)

    Rodriguez, C. F.; Barbee, J. G.; Knutson, W. K.; Cuellar, J. P., Jr.

    1983-01-01

    Screening tests determined the efficacy of six commercially available additives as modifiers of methanol's corrosivity toward metals and its weakening of tensile properties of nonmetals in automotive fuel systems. From the screening phase, three additives which seemed to protect some of the metals were tested in higher concentrations and binary combinations in search of optimal application conditions. Results indicate that two of the additives have protective properties and combining them increases the protection of the metals corroded by methanol-gasoline blends. Half of the metals in the tests were not corroded. Testing at recommended concentrations and then at higher concentrations and in combinations shows that the additives would have no protective or harmful effects on the nonmetals. Two additives emerged as candidates for application to the protection of metals in automotive methanol-gasoline fuel systems. The additives tested were assigned letter codes to protect their proprietary nature.

  20. High temperature support apparatus and method of use for casting materials

    DOEpatents

    Clark, Roger F; Cliber, James A; Stoddard, Nathan G; Gerber, Jesse I; Roberts, Raymond J; Wilmerton, Mark A

    2015-02-10

    This invention relates to a system and a method of use for large ceramic member support and manipulation at elevated temperatures in non-oxidizing atmospheres, such as using carbon-carbon composite materials for producing high purity silicon in the manufacture of solar modules. The high temperature apparatus of this invention includes one or more support ribs, one or more cross braces in combination with the one or more support ribs, and a shaped support liner positionable upon the one or more support ribs and the one or more cross braces.

  1. Materials used in new generation vehicles: supplies, shifts, and supporting infrastructure

    SciTech Connect

    Das, S.; Curlee, T.R.; Schexnayder, S.M.

    1997-08-01

    The Partnership for a New Generation of Vehicles (PNGV) program intends to develop new designs for automobiles that will reduce fuel consumption by two thirds but otherwise have price, comfort, safety, and other measures of performance similar to the typical automobile now on the market. PNGV vehicle designs are expected to substitute lightweight materials, such as aluminum, magnesium, carbon-reinforced polymer composites, glass-reinforced polymer composites, and ultra- light steel, for heavier materials such as steel and iron in automobile components. The target mass of a PNGV vehicle is 1,960 pounds, as compared to the average current vehicle that weights 3,240 pounds. Other changes could include the use of different ferrous alloys, engineering changes, or incorporation of advanced ceramic components. Widespread adoption of these vehicle designs would affect materials markets and require concurrent development and adoption of supporting technologies to supply the materials and to use and maintain them in automobiles. This report identifies what would be required to bring about these changes and developments in materials substitution; identifies reasons that might make these substitutions difficult to accomplish within the overall objectives and timetable of the PNGV program; and identifies any issues arising from the substitution that could prompt consideration of policies to deal with them. The analysis in this paper uses scenarios that assume the production of new generation vehicles will begin in 2007 and that their market share will increase gradually over the following 25 years. The scenarios on which the analysis is based assume a maximum substitution of each potential replacement material considered. This maximum substitution of individual materials (i.e., the amount of replacement material by weight that would be added to the baseline vehicle`s composition) is as follows: ULSAB (high strength steel), 298 lbs.; glass-reinforced composites, 653 lbs.; carbon

  2. The effects of material property assumptions on predicted meltpool shape for laser powder bed fusion based additive manufacturing

    NASA Astrophysics Data System (ADS)

    Teng, Chong; Ashby, Kathryn; Phan, Nam; Pal, Deepankar; Stucker, Brent

    2016-08-01

    The objective of this study was to provide guidance on material specifications for powders used in laser powder bed fusion based additive manufacturing (AM) processes. The methodology was to investigate how different material property assumptions in a simulation affect meltpool prediction and by corrolary how different material properties affect meltpool formation in AM processes. The sensitvity of meltpool variations to each material property can be used as a guide to help drive future research and to help prioritize material specifications in requirements documents. By identifying which material properties have the greatest affect on outcomes, metrology can be tailored to focus on those properties which matter most; thus reducing costs by eliminating unnecessary testing and property charaterizations. Futhermore, this sensitivity study provides insight into which properties require more accurate measurements, thus motivating development of new metrology methods to measure those properties accurately.

  3. Simplified Language Materials--Their Usage and Value to Teachers and Support Staff in Mainstream Settings

    ERIC Educational Resources Information Center

    Rix, Jonathan

    2006-01-01

    This paper examines the current use of simplified language materials (SLMs) by teachers and support staff across England. Drawing on a survey of Primary and Secondary schools it identifies the degree to which teachers and support staff use and produce SLMs. It explores both the contradictions and similarities between practitioners' perceptions of…

  4. The Contribution of Social Support to the Material Well-Being of Low-Income Families

    ERIC Educational Resources Information Center

    Henly, Julia R.; Danziger, Sandra K.; Offer, Shira

    2005-01-01

    We hypothesize that the social support available from low-income networks serves primarily a coping function, rather than a leverage function. Social support and its relationship to material well-being is assessed in a sample of 632 former and current welfare recipients. Respondents report higher levels of perceived emotional, instrumental, and…

  5. Controlling cell-material interactions with polymer nanocomposites by use of surface modifying additives

    NASA Astrophysics Data System (ADS)

    Poole-Warren, L. A.; Farrugia, B.; Fong, N.; Hume, E.; Simmons, A.

    2008-11-01

    Polymer nanocomposites (NC) are fabricated by incorporating well dispersed nanoscale particles within a polymer matrix. This study focuses on elastomeric polyurethane (PU) based nanocomposites, containing organically modified silicates (OMS), as bioactive materials. Nanocomposites incorporating chlorhexidine diacetate as an organic modifier (OM) were demonstrated to be antibacterial with a dose dependence related to both the silicate loading and the loading of OM. When the non-antibacterial OM dodecylamine was used, both cell and platelet adhesion were decreased on the nanocomposite surface. These results suggest that OM is released from the polymer and can impact on cell behaviour at the interface. Nanocomposites have potential use as bioactive materials in a range of biomedical applications.

  6. Selectability of Print Materials in Support of the Grades 10 and 11 Social Studies Curriculum.

    ERIC Educational Resources Information Center

    Yearwood, D. B.; Yearwood, E. I.

    This project report critiques library print materials used to support grades 10 and 11 social studies curriculum in British Columbia. The data collected are intended to provide a ready reference for school librarians when considering the particular print materials listed. Four criteria were used: readability, format and style, organization, and…

  7. Farm Management and Leadership. Numeracy. Level 1. Level 2. Level 3. Support Materials for Agricultural Training.

    ERIC Educational Resources Information Center

    Batman, Kangan; Gadd, Nick; Lucas, Michele

    This publication contains the three numeracy units of the three levels of Support Materials for Agricultural Training (SMAT) in farm management and leadership: Level 1 (starting), 2 (continuing), and 3 (completing). The units are designed to help the learner improve his or her numeracy skills needed to deal with farm management. SMAT materials can…

  8. Using Educative Curriculum Materials to Support the Development of Prospective Teachers' Knowledge

    ERIC Educational Resources Information Center

    Drake, Corey; Land, Tonia J.; Tyminski, Andrew M.

    2014-01-01

    Building on the work of Ball and Cohen and that of Davis and Krajcik, as well as more recent research related to teacher learning from and about curriculum materials, we seek to answer the question, How can prospective teachers (PTs) learn to read and use educative curriculum materials in ways that support them in acquiring the knowledge needed…

  9. As Teachers Tell It: Implementing All Aspects of the Industry. Supporting Materials. [Volume Two.

    ERIC Educational Resources Information Center

    Andrew, Erika Nielsen, Ed.

    This document contains supporting materials from five case studies illustrating the All Aspects of the Industry (AAI) approach. AAI provides a framework for redesigning programs around broadly conceived, interdisciplinary, industry-focused programs and integrating academic and vocational education. Materials from the Boston (Massachusetts) Public…

  10. 16 CFR 803.20 - Requests for additional information or documentary material.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... documentary material relevant to the acquisition may be required from one or more persons required to file... corporation “X”, and files notification. Under § 801.30, the waiting period begins upon filing by “A,” and “X” must file within 15 days thereafter (10 days if it were a cash tender offer). Assume that before...

  11. Metallic sulfide additives for positive electrode material within a secondary electrochemical cell

    DOEpatents

    Walsh, William J.; McPheeters, Charles C.; Yao, Neng-ping; Koura, Kobuyuki

    1976-01-01

    An improved active material for use within the positive electrode of a secondary electrochemical cell includes a mixture of iron disulfide and a sulfide of a polyvalent metal. Various metal sulfides, particularly sulfides of cobalt, nickel, copper, cerium and manganese, are added in minor weight proportion in respect to iron disulfide for improving the electrode performance and reducing current collector requirements.

  12. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides

    DOEpatents

    Zidan, Ragaiy; Ritter, James A.; Ebner, Armin D.; Wang, Jun; Holland, Charles E.

    2008-06-10

    A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

  13. TiO2 anode materials for lithium-ion batteries with different morphology and additives

    NASA Astrophysics Data System (ADS)

    Liu, Xiang; Ng, Yip Hang; Leung, Yu Hang; Liu, Fangzhou; Djurišic, Aleksandra B.; Xie, Mao Hai; Chan, Wai Kin

    2014-03-01

    Electrochemical performances of different TiO2 nanostructures, TiO2/CNT composite and TiO2 with titanium isopropoxide (TTIP) treatment anode were investigated. For different TiO2 nanostructures, we investigated vertically aligned TiO2 nanotubes on Ti foil and TiO2 nanotube-powders fabricated by rapid breakdown anodization technique. The morphology of the prepared samples was characterized by scanning probe microscopy (SEM). The electrochemical lithium storage abilities were studied by galvanostatic method. In addition, carbon nanotubes (CNT) additives and solution treatment process of TiO2 anode were investigated, and the results show that the additives and treatment could enhance the cycling performance of the TiO2 anode on lithium ion batteries.

  14. Study of the effects of potassium addition to supported iron catalysts in the Fischer-Tropsch reaction

    SciTech Connect

    Miller, D.G.; Moskovits, M.

    1988-10-20

    The Fischer-Tropsch activity of supported iron catalysts prepared via electrochemical techniques has been evaluated as a function of potassium addition. Catalyst pretreatment in 0.09, 0.18, and 0.27 M K/sub 2/CO/sub 3/ solutions generated potassium levels of 1.7, 2.8, and 3.9 wt %, respectively. Pretreatment in 0.18 M KOH provided a catalyst with 2.3 wt% potassium and facilitated comparison of the effects of the basicity of the pretreatment solution upon catalyst activity. A maximum in catalyst activity and CO conversion was noted upon increasing K content, followed by a sharp decline in activity at potassium levels in excess of the maximum. The hydrogenation ability of the catalyst decreased, and a shift to higher molecular weight products was observed, with increasing potassium content. The type of pretreatment solution had little effect on the catalyst activity or the product selectivity.

  15. Thermodynamic method of calculating the effect of alloying additives on interphase interaction in composite materials

    NASA Technical Reports Server (NTRS)

    Tuchinsky, L. I.

    1986-01-01

    The effect of alloying additives to the matrix of a composite on the high temperature solubility rate of a single component fiber was analyzed thermodynamically. With an example of binary Ni alloys, with Group IV-VI transition metals reinforced with W fibers, agreement between the calculated and experimental data was demonstrated.

  16. Materials management FY 1995 site support program plan WBS 6.10.7

    SciTech Connect

    Dahlin, E.C.

    1994-09-01

    The Work Breakdown Structure is tabulated for the six main activities within the materials management site support program. Materials Management involves the receipt, storage, issuance, management and disposition of the government`s physical assets. Property Management involves maintaining acceptable levels of property accountability and proper utilization of government owned property. Warehousing involves the shipping, receiving, storage, issuance, and distribution of materials, parts, components and equipment required to support the ongoing operation of the Hanford Site. Inventory Management maintains appropriate levels of general supplies, spare parts, and essential materials to ensure availability of items required to support site operations is timely and provided at the lowest possible cost. Investment Recovery involves the identification and disposition of assets excess to the needs of the site through redeployment, recycling initiatives, and public sale of surplus property. Property Systems operate, maintain and enhance the development of cost effective data systems to control and administer multi-contractor personal property assets.

  17. Does the Use of Diamond-Like Carbon Coating and Organophosphate Lubricant Additive Together Cause Excessive Tribochemical Material Removal?

    DOE PAGESBeta

    Zhou, Yan; Leonard, Donovan N.; Meyer, Harry M.; Luo, Huimin; Qu, Jun

    2015-08-22

    We observe unexpected wear increase on a steel surface that rubbed against diamond-like carbon (DLC) coatings only when lubricated by phosphate-based antiwear additives. Contrary to the literature hypothesis of a competition between zinc dialkyldithiophosphate produced tribofilms and DLC-induced carbon transfer, here a new wear mechanism based on carbon-catalyzed tribochemical interactions supported by surface characterization is proposed

  18. Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams

    NASA Astrophysics Data System (ADS)

    Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokić, Miroslav; Maksimović, Vesna

    2014-08-01

    A method of synthesizing Ni-based catalysts supported on α-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.

  19. Interoperability of Materials Database Systems in Support of Nuclear Energy Development and Potential Applications for Fuel Cell Material Selection

    SciTech Connect

    Lin, Lianshan; Austin, Timothy; Ren, Weiju

    2015-01-01

    Materials database interoperability has been of great interest in recent years for information exchange in support of research and development (R&D). In response to data and knowledge sharing needs of the GenIV International Forum (GIF) for global collaboration in nuclear energy R&D, the European Commission JRC Institute for Energy and Transport (JRC-IET) and the Oak Ridge National Laboratory (ORNL) have established a materials database interoperability project that develops techniques for automated materials data exchange between systems hosted at the two institutes MatDB Online at JRC IET and the Gen IV Materials Handbook at ORNL, respectively. The work to enable automated exchange of data between the two systems leverages the XML data import and export functionalities of both systems in combination with recently developed standards for engineering materials data. The preliminary results of data communication between the two systems have demonstrated the feasibility and efficiency of materials database interoperability, which constructs an interoperation framework that can be seamlessly integrated into the high-throughput First Principles material databases and thus advance the discovery of novel materials in fuel cell applications.

  20. Interoperability of Materials Database Systems in Support of Nuclear Energy Development and Potential Applications for Fuel Cell Material Selection

    DOE PAGESBeta

    Lin, Lianshan; Austin, Timothy; Ren, Weiju

    2015-01-01

    Materials database interoperability has been of great interest in recent years for information exchange in support of research and development (R&D). In response to data and knowledge sharing needs of the GenIV International Forum (GIF) for global collaboration in nuclear energy R&D, the European Commission JRC Institute for Energy and Transport (JRC-IET) and the Oak Ridge National Laboratory (ORNL) have established a materials database interoperability project that develops techniques for automated materials data exchange between systems hosted at the two institutes MatDB Online at JRC IET and the Gen IV Materials Handbook at ORNL, respectively. The work to enable automatedmore » exchange of data between the two systems leverages the XML data import and export functionalities of both systems in combination with recently developed standards for engineering materials data. The preliminary results of data communication between the two systems have demonstrated the feasibility and efficiency of materials database interoperability, which constructs an interoperation framework that can be seamlessly integrated into the high-throughput First Principles material databases and thus advance the discovery of novel materials in fuel cell applications.« less

  1. Does the addition of proteases affect the biogas yield from organic material in anaerobic digestion?

    PubMed

    Müller, Liane; Kretzschmar, Jörg; Pröter, Jürgen; Liebetrau, Jan; Nelles, Michael; Scholwin, Frank

    2016-03-01

    The aim of this study was to investigate the biochemical disintegration effect of hydrolytic enzymes in lab scale experiments. Influences of enzyme addition on the biogas yield as well as effects on the process stability were examined. The addition of proteases occurred with low and high dosages in batch and semi-continuous biogas tests. The feed mixture consisted of maize silage, chicken dung and cow manure. Only very high concentrated enzymes caused an increase in biogas production in batch experiments. In semi-continuous biogas tests no positive long-term effects (100 days) were observed. Higher enzyme-dosage led to a reduced biogas-yield (13% and 36% lower than the reference). Phenylacetate and -propionate increased (up to 372 mgl(-1)) before the other volatile fatty acids did. Volatile organic acids rose up to 6.8 gl(-1). The anaerobic digestion process was inhibited. PMID:26741852

  2. Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition

    DOE PAGESBeta

    Yue, Lanping; Jin, Yunlong; Zhang, Wenyong; Sellmyer, David J.

    2015-01-01

    Tmore » he addition of Molybdenum was used to modify the nanostructure and enhance coercivity of rare-earth-free Zr2Co11-based nanocrystalline permanent magnets. he effect of Mo addition on magnetic domain structures of melt spun nanocrystalline Zr16Co84-xMox(x=0, 0.5, 1, 1.5, and 2.0) ribbons has been investigated. It was found that magnetic properties and local domain structures are strongly influenced by Mo doping. he coercivity of the samples increases with the increase in Mo content (x≤1.5). he maximum energy product(BH)maxincreases with increasingxfrom 0.5 MGOe forx=0to a maximum value of 4.2 MGOe forx=1.5. he smallest domain size with a relatively short magnetic correlation length of 128 nm and largest root-mean-square phase shiftΦrmsvalue of 0.66° are observed for thex=1.5. he optimal Mo addition promotes magnetic domain structure refinement and thus leads to a significant increase in coercivity and energy product in this sample.« less

  3. Magnetic Properties of FeNi-Based Thin Film Materials with Different Additives.

    PubMed

    Liang, Cai; Gooneratne, Chinthaka P; Wang, Qing Xiao; Liu, Yang; Gianchandani, Yogesh; Kosel, Jurgen

    2014-09-01

    This paper presents a study of FeNi-based thin film materials deposited with Mo, Al and B using a co-sputtering process. The existence of soft magnetic properties in combination with strong magneto-mechanical coupling makes these materials attractive for sensor applications. Our findings show that FeNi deposited with Mo or Al yields magnetically soft materials and that depositing with B further increases the softness. The out-of-plane magnetic anisotropy of FeNi thin films is reduced by depositing with Al and completely removed by depositing with B. The effect of depositing with Mo is dependent on the Mo concentration. The coercivity of FeNiMo and FeNiAl is reduced to less than a half of that of FeNi, and a value as low as 40 A/m is obtained for FeNiB. The surfaces of the obtained FeNiMo, FeNiAl and FeNiB thin films reveal very different morphologies. The surface of FeNiMo shows nano-cracks, while the FeNiAl films show large clusters and fewer nano-cracks. When FeNi is deposited with B, a very smooth morphology is obtained. The crystal structure of FeNiMo strongly depends on the depositant concentration and changes into an amorphous structure at a higher Mo level. FeNiAl thin films remain polycrystalline, even at a very high concentration of Al, and FeNiB films are amorphous, even at a very low concentration of B. PMID:25587418

  4. Controlling the Electrostatic Discharge Ignition Sensitivity of Composite Energetic Materials Using Carbon Nanotube Additives

    SciTech Connect

    Kade H. Poper; Eric S. Collins; Michelle L. Pantoya; Michael Daniels

    2014-10-01

    Powder energetic materials are highly sensitive to electrostatic discharge (ESD) ignition. This study shows that small concentrations of carbon nanotubes (CNT) added to the highly reactive mixture of aluminum and copper oxide (Al + CuO) significantly reduces ESD ignition sensitivity. CNT act as a conduit for electric energy, bypassing energy buildup and desensitizing the mixture to ESD ignition. The lowest CNT concentration needed to desensitize ignition is 3.8 vol.% corresponding to percolation corresponding to an electrical conductivity of 0.04 S/cm. Conversely, added CNT increased Al + CuO thermal ignition sensitivity to a hot wire igniter.

  5. Supporting Infrastructure and Acceptability Issues for Materials Used in New Generation Vehicles

    SciTech Connect

    Das, S.; Curlee, T.R.; Jones, D.W.; Leiby, P.E.; Rubin, J.D.; Schexnayder, S.M.; Vogt, D.P.; Wolfe, A.K.

    1999-03-01

    To achieve its goal of producing vehicles that use two thirds less fuel than current vehicles, the Partnership of a New Generation of Vehicles (PNGV) is designing vehicles that will use lightweight materials in place of heavier materials used in current vehicles. using new materials in automobiles will require the development of a supporting infrastructure to produce both the substitute materials and the components of the substitute materials, as well as the automotive parts constructed from the new materials. This report documents a set of analyses that attempt to identify potential barriers--economic, infrastructure, and public acceptance barriers--to the materials substitution in New Generation Vehicles. The analyses rely on hypothetical vehicle market penetration scenarios and material composition. The approach is comprehensive, examining issues ranging from materials availability to their eventual disposition and its effect on the automobile recycling industry, and from supporting industries' capacity to the public acceptability of these vehicles. The analyses focus on two likely substitute materials, aluminum and glass-reinforced polymer composites.

  6. Novel techniques for the synthesis of three-way catalytic converter support materials

    NASA Astrophysics Data System (ADS)

    Anyaba, Prince Nwabueze

    Current automobiles use catalytic converters, consisting of noble metals on an oxide support, to convert noxious engine exhaust pollutants into less harmful species. The development of mesoporous oxide supports with optimal pore geometries could enable these devises to decrease in size and weight and significantly reduce the metal loadings required to achieve optimal performance. Thus, in this work, I investigated a wide range of techniques for the synthesis of mesoporous oxides to determine if they could be adapted to ceria-zirconia-yttria mixed oxide (CZY) systems, which are the industry standard for the optimal oxide support for catalytic converter applications. Additionally, I compared and critically evaluated the catalytic performance of the CZY mixed oxides, which were synthesized from the various templating techniques. The catalytic performance test was broken up into two: catalyst activity test which was determined based on the light-off temperatures at which 50% conversion of the reacting species have been converted; and resistance to surface area loss under accelerated aging at heating rate of 20°C/min form 700 to 1000°C, with the final temperature being held fixed for 4 h. To date, the most cost effective methods for preparing mesoporous materials are via techniques that employ templates or structure directing agents. These templates can be divided into two groups: endo-templates (i.e., soft templates, such as surfactants, dendrimers, and block copolymers) and exo-templates (i.e., hard templates, such as porous carbons and resins). The soft templating techniques generally involve both sol-gel and templating methods, while the hard templates required no sol-gel chemistry to achieve the desired templating effect. The precursors for ceria, zirconia, and yttria used were cerium (III) nitrate hexahydrate, zirconyl nitrate, and yttrium nitrate hexahydrate, respectively. The mesoporous CZY materials that were synthesized had surface area values that were

  7. Reduction of CO2 diffuse emissions from the traditional ceramic industry by the addition of Si-Al raw material.

    PubMed

    González, I; Barba-Brioso, C; Campos, P; Romero, A; Galán, E

    2016-09-15

    The fabrication of ceramics can produce the emission of several gases, denominated exhaust gases, and also vapours resulting from firing processes, which usually contain metals and toxic substances affecting the environment and the health of workers. Especially harmful are the diffuse emissions of CO2, fluorine, chlorine and sulphur from the ceramics industry, which, in highly industrialized areas, can suppose an important emission focus of dangerous effects. Concerning CO2, factories that use carbonate-rich raw materials (>30% carbonates) can emit high concentrations of CO2 to the atmosphere. Thus, carbonate reduction or substitution with other raw materials would reduce the emissions. In this contribution, we propose the addition of Al-shales to the carbonated ceramic materials (marls) for CO2 emission reduction, also improving the quality of the products. The employed shales are inexpensive materials of large reserves in SW-Spain. The ceramic bodies prepared with the addition of selected Al-shale to marls in variable proportions resulted in a 40%-65% CO2 emission reduction. In addition, this research underlines at the same time that the use of a low-price raw material can also contribute to obtaining products with higher added value. PMID:27233044

  8. Sensitivity alteration of fiber Bragg grating sensors with additive micro-scale bi-material coatings

    NASA Astrophysics Data System (ADS)

    Zhang, Xixi; Alemohammad, Hamidreza; Toyserkani, Ehsan

    2013-02-01

    This paper describes a combined fabrication method for creating a bi-material micro-scale coating on fiber Bragg grating (FBG) optical sensors using laser-assisted maskless microdeposition (LAMM) and electroless nickel plating. This bi-material coating alters the sensitivity of the sensor where it also acts as a protective layer. LAMM is used to coat bare FBGs with a 1-2 µm thick conductive silver layer followed by the electroless nickel plating process to increase layer thickness to a desired level ranging from 1 to 80 µm. To identify an optimum coating thickness and predict its effect on the sensor's sensitivity to force and temperature, an optomechanical model is developed in this study. According to the model if the thickness of the Ni layer is 30-50 µm, maximum temperature sensitivity is achieved. Our analytical and experimental results suggest that the temperature sensitivity of the coated FBG with 1 µm Ag and 33 µm Ni is almost doubled compared to a bare FBG with sensitivity of 0.011 ± 0.001 nm °C-1. In contrast, the force sensitivity is decreased; however, this sensitivity reduction is less than the values reported in the literature.

  9. A Metallurgical Evaluation of the Powder-Bed Laser Additive Manufactured 4140 Steel Material

    NASA Astrophysics Data System (ADS)

    Wang, Wesley; Kelly, Shawn

    2016-03-01

    Using laser powder bed fusion (PBF-L) additive manufacturing (AM) process for steel or iron powder has been attempted for decades. This work used a medium carbon steel (AISI 4140) powder to explore the feasibility of AM. The high carbon equivalent of 4140 steel (CEIIW ≈ 0.83) has a strong tendency toward cold cracking. As such, the process parameters must be carefully controlled to ensure the AM build quality. Through an orthogonally designed experimental matrix, a laser-welding procedure was successfully developed to produce 4140 steel AM builds with no welding defects. In addition, the microstructure and micro-cleanliness of the as-welded PBF-L AM builds were also examined. The results showed an ultra-fine martensite lath structure and an ultra-clean internal quality with minimal oxide inclusion distribution. After optimizing the PBF-L AM process parameters, including the laser power and scan speed, the as-welded AM builds yielded an average tensile strength higher than 1482 MPa and an average 33 J Charpy V-notch impact toughness at -18°C. The surface quality, tensile strength, and Charpy V-notch impact toughness of AM builds were comparable to the wrought 4140 steel. The excellent mechanical properties of 4140 steel builds created by the PBF-L AM AM process make industrial production more feasible, which shows great potential for application in the aerospace, automobile, and machinery industries.

  10. Components of yeast (Sacchromyces cervisiae) extract as defined media additives that support the growth and productivity of CHO cells.

    PubMed

    Spearman, Maureen; Chan, Sarah; Jung, Vince; Kowbel, Vanessa; Mendoza, Meg; Miranda, Vivian; Butler, Michael

    2016-09-10

    Yeast and plant hydrolysates are used as media supplements to support the growth and productivity of CHO cultures for biopharmaceutical production. Through fractionation of a yeast lysate and metabolic analysis of a fraction that had bioactivity equivalent to commercial yeast extract (YE), bioactive components were identified that promoted growth and productivity of two recombinant CHO cell lines (CHO-Luc and CHO-hFcEG2) equivalent to or greater than YE-supplemented media. Autolysis of the yeast lysate was not necessary for full activity, suggesting that the active components are present in untreated yeast cells. A bioactive fraction (3KF) of the yeast lysate was isolated from the permeate using a 3kDa molecular weight cut-off (MWCO) filter. Supplementation of this 3KF fraction into the base media supported growth of CHO-Luc cells over eight passages equivalent to YE-supplemented media. The 3KF fraction was fractionated further by a cation exchange spin column using a stepwise pH elution. Metabolomic analysis of a bioactive fraction isolated at high pH identified several arginine and lysine-containing peptides as well as two polyamines, spermine and spermidine, with 3.5× and 4.5× higher levels compared to a fraction showing no bioactivity. The addition of a mixture of polyamines and their precursors (putrescine, spermine, spermidine, ornithine and citrulline) as well as increasing the concentration of some of the components of the original base medium resulted in a chemically-defined (CD) formulation that produced an equivalent viable cell density (VCD) and productivity of the CHO-Luc cells as the YE-supplemented medium. The VCD of the CHO-hFcEG2 culture in the CD medium was 1.9× greater and with equivalent productivity to the YE-supplemented media. PMID:27165505

  11. Silica nanoparticle addition to control the calcium-leaching in cement-based materials

    NASA Astrophysics Data System (ADS)

    Gaitero, J. J.; Sáez de Ibarra, Y.; Erkizia, E.; Campillo, I.

    2006-05-01

    The calcium leaching of the cement hydrated matrix is of vital importance for constructions like water containers, dams, bridges, etc which have to be in contact with water during their lifetime. The aim of this work is the study of the reduction of such a negative phenomenon by the addition of silica nanoparticles. Several characterisation techniques such as 29Si MAS NMR, X-ray diffraction, mercury intrusion porosimetry and EDX-microanalysis have been used to evaluate the effect of the nanoparticles in the cement matrix nanostructure and in their impact on the evolution of the Ca leaching throughout time. Subsequent analysis of the results indicates that silica nanoparticles can reduce the Ca-leaching both decreasing the amount of portlandite in the matrix and controlling the degradation rate of the C-S-H gel.

  12. Heat transfer and material flow during laser assisted multi-layer additive manufacturing

    SciTech Connect

    Manvatkar, V.; De, A.; DebRoy, T.

    2014-09-28

    A three-dimensional, transient, heat transfer, and fluid flow model is developed for the laser assisted multilayer additive manufacturing process with coaxially fed austenitic stainless steel powder. Heat transfer between the laser beam and the powder particles is considered both during their flight between the nozzle and the growth surface and after they deposit on the surface. The geometry of the build layer obtained from independent experiments is compared with that obtained from the model. The spatial variation of melt geometry, cooling rate, and peak temperatures is examined in various layers. The computed cooling rates and solidification parameters are used to estimate the cell spacings and hardness in various layers of the structure. Good agreement is achieved between the computed geometry, cell spacings, and hardness with the corresponding independent experimental results.

  13. Heat transfer and material flow during laser assisted multi-layer additive manufacturing

    NASA Astrophysics Data System (ADS)

    Manvatkar, V.; De, A.; DebRoy, T.

    2014-09-01

    A three-dimensional, transient, heat transfer, and fluid flow model is developed for the laser assisted multilayer additive manufacturing process with coaxially fed austenitic stainless steel powder. Heat transfer between the laser beam and the powder particles is considered both during their flight between the nozzle and the growth surface and after they deposit on the surface. The geometry of the build layer obtained from independent experiments is compared with that obtained from the model. The spatial variation of melt geometry, cooling rate, and peak temperatures is examined in various layers. The computed cooling rates and solidification parameters are used to estimate the cell spacings and hardness in various layers of the structure. Good agreement is achieved between the computed geometry, cell spacings, and hardness with the corresponding independent experimental results.

  14. Study on Friction and Wear Properties of Silver Matrix Brush Material with Different Additives

    NASA Astrophysics Data System (ADS)

    Chen, Xiaoli; Wang, Wenfang; Hong, Yu; Wu, Yucheng

    2013-07-01

    Friction and wear processes of AgCuX (G, CF and AlN) composites-CuAgV alloy friction pair and effects of different additive content in silver based composite on friction and wear behavior are studied in this paper. The microstructure of the brush wear surface is observed by SEM. The results show that when graphite content is up to 9 wt.%, Ag-Cu-CF-G composite exhibits the best wear properties; when the content of aluminum nitride is up to 0.5 wt.%, Ag-Cu-AlN-G composites has the most comprehensive performance. The wear loss of both composites arises with the increase of both pressure and speed, but when speed reaches a critical value, the increased amplitude of wear loss tends to be steady.

  15. Feasibility Study on 3-D Printing of Metallic Structural Materials with Robotized Laser-Based Metal Additive Manufacturing

    NASA Astrophysics Data System (ADS)

    Ding, Yaoyu; Kovacevic, Radovan

    2016-05-01

    Metallic structural materials continue to open new avenues in achieving exotic mechanical properties that are naturally unavailable. They hold great potential in developing novel products in diverse industries such as the automotive, aerospace, biomedical, oil and gas, and defense. Currently, the use of metallic structural materials in industry is still limited because of difficulties in their manufacturing. This article studied the feasibility of printing metallic structural materials with robotized laser-based metal additive manufacturing (RLMAM). In this study, two metallic structural materials characterized by an enlarged positive Poisson's ratio and a negative Poisson's ratio were designed and simulated, respectively. An RLMAM system developed at the Research Center for Advanced Manufacturing of Southern Methodist University was used to print them. The results of the tensile tests indicated that the printed samples successfully achieved the corresponding mechanical properties.

  16. Feasibility Study on 3-D Printing of Metallic Structural Materials with Robotized Laser-Based Metal Additive Manufacturing

    NASA Astrophysics Data System (ADS)

    Ding, Yaoyu; Kovacevic, Radovan

    2016-07-01

    Metallic structural materials continue to open new avenues in achieving exotic mechanical properties that are naturally unavailable. They hold great potential in developing novel products in diverse industries such as the automotive, aerospace, biomedical, oil and gas, and defense. Currently, the use of metallic structural materials in industry is still limited because of difficulties in their manufacturing. This article studied the feasibility of printing metallic structural materials with robotized laser-based metal additive manufacturing (RLMAM). In this study, two metallic structural materials characterized by an enlarged positive Poisson's ratio and a negative Poisson's ratio were designed and simulated, respectively. An RLMAM system developed at the Research Center for Advanced Manufacturing of Southern Methodist University was used to print them. The results of the tensile tests indicated that the printed samples successfully achieved the corresponding mechanical properties.

  17. Carbon nanocages: a new support material for Pt catalyst with remarkably high durability.

    PubMed

    Wang, Xiao Xia; Tan, Zhe Hua; Zeng, Min; Wang, Jian Nong

    2014-01-01

    Low durability is the major challenge hindering the large-scale implementation of proton exchange membrane fuel cell (PEMFC) technology, and corrosion of carbon support materials of current catalysts is the main cause. Here, we describe the finding of remarkably high durability with the use of a novel support material. This material is based on hollow carbon nanocages developed with a high degree of graphitization and concurrent nitrogen doping for oxidation resistance enhancement, uniform deposition of fine Pt particles, and strong Pt-support interaction. Accelerated degradation testing shows that such designed catalyst possesses a superior electrochemical activity and long-term stability for both hydrogen oxidation and oxygen reduction relative to industry benchmarks of current catalysts. Further testing under conditions of practical fuel cell operation reveals almost no degradation over long-term cycling. Such a catalyst of high activity, particularly, high durability, opens the door for the next-generation PEMFC for "real world" application. PMID:24658614

  18. Carbon nanocages: A new support material for Pt catalyst with remarkably high durability

    PubMed Central

    Wang, Xiao Xia; Tan, Zhe Hua; Zeng, Min; Wang, Jian Nong

    2014-01-01

    Low durability is the major challenge hindering the large-scale implementation of proton exchange membrane fuel cell (PEMFC) technology, and corrosion of carbon support materials of current catalysts is the main cause. Here, we describe the finding of remarkably high durability with the use of a novel support material. This material is based on hollow carbon nanocages developed with a high degree of graphitization and concurrent nitrogen doping for oxidation resistance enhancement, uniform deposition of fine Pt particles, and strong Pt-support interaction. Accelerated degradation testing shows that such designed catalyst possesses a superior electrochemical activity and long-term stability for both hydrogen oxidation and oxygen reduction relative to industry benchmarks of current catalysts. Further testing under conditions of practical fuel cell operation reveals almost no degradation over long-term cycling. Such a catalyst of high activity, particularly, high durability, opens the door for the next-generation PEMFC for “real world” application. PMID:24658614

  19. Support vector machine to predict diesel engine performance and emission parameters fueled with nano-particles additive to diesel fuel

    NASA Astrophysics Data System (ADS)

    Ghanbari, M.; Najafi, G.; Ghobadian, B.; Mamat, R.; Noor, M. M.; Moosavian, A.

    2015-12-01

    This paper studies the use of adaptive Support Vector Machine (SVM) to predict the performance parameters and exhaust emissions of a diesel engine operating on nanodiesel blended fuels. In order to predict the engine parameters, the whole experimental data were randomly divided into training and testing data. For SVM modelling, different values for radial basis function (RBF) kernel width and penalty parameters (C) were considered and the optimum values were then found. The results demonstrate that SVM is capable of predicting the diesel engine performance and emissions. In the experimental step, Carbon nano tubes (CNT) (40, 80 and 120 ppm) and nano silver particles (40, 80 and 120 ppm) with nanostructure were prepared and added as additive to the diesel fuel. Six cylinders, four-stroke diesel engine was fuelled with these new blended fuels and operated at different engine speeds. Experimental test results indicated the fact that adding nano particles to diesel fuel, increased diesel engine power and torque output. For nano-diesel it was found that the brake specific fuel consumption (bsfc) was decreased compared to the net diesel fuel. The results proved that with increase of nano particles concentrations (from 40 ppm to 120 ppm) in diesel fuel, CO2 emission increased. CO emission in diesel fuel with nano-particles was lower significantly compared to pure diesel fuel. UHC emission with silver nano-diesel blended fuel decreased while with fuels that contains CNT nano particles increased. The trend of NOx emission was inverse compared to the UHC emission. With adding nano particles to the blended fuels, NOx increased compared to the net diesel fuel. The tests revealed that silver & CNT nano particles can be used as additive in diesel fuel to improve complete combustion of the fuel and reduce the exhaust emissions significantly.

  20. Exploring the role of curriculum materials to support teachers in science education reform

    NASA Astrophysics Data System (ADS)

    Schneider, Rebecca M.

    2001-07-01

    For curriculum materials to succeed in promoting large-scale science education reform, teacher learning must be supported. Materials were designed to reflect desired reforms and to be educative by including detailed lesson descriptions that addressed necessary content, pedagogy, and pedagogical content knowledge for teachers. The goal of this research was to describe how such materials contributed to classroom practices. As part of an urban systemic reform effort, four middle school teachers' initial enactment of an inquiry-based science unit on force and motion were videotaped. Enactments focused on five lesson sequences containing experiences with phenomena, investigation, technology use, or artifact development. Each sequence spanned three to five days across the 10-week unit. For each lesson sequence, intended and actual enactment were compared using ratings of (1) accuracy and completeness of science ideas presented, (2) amount student learning opportunities, similarity of learning opportunities with those intended, and quality of adaptations , and (3) amount of instructional supports offered, appropriateness of instructional supports and source of ideas for instructional supports. Ratings indicated two teachers' enactments were consistent with intentions and two teachers' enactments were not. The first two were in school contexts supportive of the reform. They purposefully used the materials to guide enactment, which tended to be consistent with standards-based reform. They provided students opportunities to use technology tools, design investigations, and discuss ideas. However, enactment ratings were less reflective of curriculum intent when challenges were greatest, such as when teachers attempted to present challenging science ideas, respond to students' ideas, structure investigations, guide small-group discussions, or make adaptations. Moreover, enactment ratings were less consistent in parts of lessons where materials did not include lesson specific

  1. Data collection handbook to support modeling the impacts of radioactive material in soil

    SciTech Connect

    Yu, C.; Cheng, J.J.; Jones, L.G.; Wang, Y.Y.; Faillace, E.; Loureiro, C.; Chia, Y.P.

    1993-04-01

    A pathway analysis computer code called RESRAD has been developed for implementing US Department of Energy Residual Radioactive Material Guidelines. Hydrogeological, meteorological, geochemical, geometrical (size, area, depth), and material-related (soil, concrete) parameters are used in the RESRAD code. This handbook discusses parameter definitions, typical ranges, variations, measurement methodologies, and input screen locations. Although this handbook was developed primarily to support the application of RESRAD, the discussions and values are valid for other model applications.

  2. The capability of satellite borne remote sensors to measure stratospheric trace constituents. Volume 3: Supporting material

    NASA Technical Reports Server (NTRS)

    Keitz, E. L.

    1978-01-01

    Contained in this volume is material of a supportive nature not considered to be of sufficient importance to be included in the other two previous volumes. This material is of two types:(1) information and numerical evaluations used in the development of mission evaluations for stratospheric trace constituent measurement;and (2) various spatial and temporal distributions for those stratospheric trace species having sufficient measurements available to warrant their presentation.

  3. Sail film materials and supporting structure for a solar sail, a preliminary design, volume 4

    NASA Technical Reports Server (NTRS)

    Rowe, W. M. (Editor)

    1978-01-01

    Solar sailing technology was examined in relation to a mission to rendezvous with Halley's Comet. Development of an ultra-light, highly reflecting material system capable of operating at high solar intensity for long periods of time was emphasized. Data resulting from the sail materials study are reported. Topics covered include: basic film; coatings and thermal control; joining and handling; system performance; and supporting structures assessment for the heliogyro.

  4. Evaluation of additional head of biceps brachii: a study with autopsy material.

    PubMed

    Ballesteros, L E; Forero, P L; Buitrago, E R

    2014-05-01

    Additional head of the biceps brachii (AHBB) has been reported in different population groups with a frequency of 1-25%. The purpose of this study was to determine the incidence and morphologic expression of the AHBB as determined in a sample of the Colombian population. An exploration was conducted with 106 arms corresponding to unclaimed corpses autopsied at Institute of Legal and Forensic Medicine of Bucaramanga, Colombia. Using medial incision involvingskin, subcutaneous tissue, and brachial fascia, the heads of the biceps and their innervating branches were visualised. One AHBB was observed in 21 (19.8%) of the arms evaluated, with non-significant difference (p = 0.568) per side of presentation: 11 (52.4%) cases on the right side and 10 (47.6%) on the left side. All AHBBs were originated in the infero-medial segment of the humerus, with a mean thickness of 17.8 ± 6.8 mm. In 4 (19%) cases the fascicle was thin, less than 10 mm; in 7 (33.3%) cases it was of medium thickness, between 11 and 20 mm, whereas in 47.6% it was longer than 20 mm. The length of the AHBB was 118.3 ± 26.8 mm; its motor point supplied by the musculocutaneous nerve was located at 101.3 ± 20.9 mm of the bi-epicondylar line. The incidence of AHBB in this study is located at the upper segment of what has been reportedin the literature and could be a morphologic trait of the Colombian population; in agreement with prior studies, the origin was the infero-medial surface of the humerus. PMID:24902098

  5. Experimental rivers: from braided to meandering by addition of cohesive floodplain material

    NASA Astrophysics Data System (ADS)

    Van Dijk, W. M.; van de Lageweg, W. I.; Kleinhans, M. G.

    2011-12-01

    much more sediment was reworked. Apparently, the lack of bank cohesion allowed more sediment to be available within the channels, which in turn enhanced the braiding tendency. We conclude that the increase of fine cohesive material leads to a decrease in chute cutoffs and the tendency to braid. The upstream moving inflow boundary was a necessary condition for dynamic meandering and braiding.

  6. Dispositions Supporting Elementary Interns in the Teaching of Reform-Based Science Materials

    NASA Astrophysics Data System (ADS)

    Eick, Charles J.; Stewart, Bethany

    2010-11-01

    Dispositions supporting the teaching of science as structured inquiry by four elementary candidates are presented. Candidates were studied during student teaching based on their positive attitudes toward teaching science with reform-based materials in their methods course. Personal learning histories informed their attitudes, values, and beliefs about the teaching and learning of science through structured inquiry. Supportive dispositions included curiosity and questioning, investigating first-hand, learning together, and active learning. These dispositions supported early science teaching despite candidates limited science content knowledge, and may contribute to candidates’ further learning of science.

  7. Application of copper nanoparticles as additions to a grinding fluid to increase the quality of grinding of magnetic ceramic materials

    NASA Astrophysics Data System (ADS)

    Krevchik, V. D.; Skryabin, V. A.; Sokolov, A. V.; Men'shova, S. B.; Artemov, I. I.; Prokof'ev, M. V.; Karasev, N. Ya.

    2015-12-01

    The influence of copper nanoparticles in a grinding fluid (GF) used for grinding on the characteristics of the surface layer of ferrite parts and their service properties is studied. Profilograms of the ground surfaces and their roughness are measured. The electromagnetic losses of 10000NN ferrite parts ground in an GF medium with copper nanoparticles are estimated. The use of metal nanoparticles as additions to a grinding fluid is shown to be useful for processing of brittle nonmetallic materials.

  8. A pathway-based analysis provides additional support for an immune-related genetic susceptibility to Parkinson's disease

    PubMed Central

    Holmans, Peter; Moskvina, Valentina; Jones, Lesley; Sharma, Manu; Vedernikov, Alexey; Buchel, Finja; Sadd, Mohamad; Bras, Jose M.; Bettella, Francesco; Nicolaou, Nayia; Simón-Sánchez, Javier; Mittag, Florian; Gibbs, J. Raphael; Schulte, Claudia; Durr, Alexandra; Guerreiro, Rita; Hernandez, Dena; Brice, Alexis; Stefánsson, Hreinn; Majamaa, Kari; Gasser, Thomas; Heutink, Peter; Wood, Nicholas W.; Martinez, Maria; Singleton, Andrew B.; Nalls, Michael A.; Hardy, John; Morris, Huw R.; Williams, Nigel M.; Arepalli, Sampath; Barker, Roger; Barrett, Jeffrey; Ben-Shlomo, Yoav; Berendse, Henk W.; Berg, Daniela; Bhatia, Kailash; de Bie, Rob M.A.; Biffi, Alessandro; Bloem, Bas; Brice, Alexis; Bochdanovits, Zoltan; Bonin, Michael; Bras, Jose M.; Brockmann, Kathrin; Brooks, Janet; Burn, David J.; Charlesworth, Gavin; Chen, Honglei; Chinnery, Patrick F.; Chong, Sean; Clarke, Carl E.; Cookson, Mark R.; Cooper, Jonathan M.; Corvol, Jen-Christophe; Counsell, Carl; Damier, Philippe; Dartigues, Jean Francois; Deloukas, Panagiotis; Deuschl, Günther; Dexter, David T.; van Dijk, Karin D.; Dillman, Allissa; Durif, Frank; Durr, Alexandra; Edkins, Sarah; Evans, Jonathan R.; Foltynie, Thomas; Gao, Jianjun; Gardner, Michelle; Gasser, Thomas; Gibbs, J. Raphael; Goate, Alison; Gray, Emma; Guerreiro, Rita; Gústafsson, Ómar; Hardy, John; Harris, Clare; Hernandez, Dena G.; Heutink, Peter; van Hilten, Jacobus J.; Hofman, Albert; Hollenbeck, Albert; Holmans, Peter; Holton, Janice; Hu, Michele; Huber, Heiko; Hudson, Gavin; Hunt, Sarah E.; Huttenlocher, Johanna; Illig, Thomas; Langford, Cordelia; Lees, Andrew; Lesage, Suzanne; Lichtner, Peter; Limousin, Patricia; Lopez, Grisel; Lorenz, Delia; Martinez, Maria; McNeill, Alisdair; Moorby, Catriona; Moore, Matthew; Morris, Huw; Morrison, Karen E.; Moskvina, Valentina; Mudanohwo, Ese; Nalls, Michael A.; Pearson, Justin; Perlmutter, Joel S.; Pétursson, Hjörvar; Plagnol, Vincent; Pollak, Pierre; Post, Bart; Potter, Simon; Ravina, Bernard; Revesz, Tamas; Riess, Olaf; Rivadeneira, Fernando; Rizzu, Patrizia; Ryten, Mina; Saad, Mohamad; Sawcer, Stephen; Schapira, Anthony; Scheffer, Hans; Sharma, Manu; Shaw, Karen; Sheerin, Una-Marie; Shoulson, Ira; Schulte, Claudia; Sidransky, Ellen; Simón-Sánchez, Javier; Singleton, Andrew B.; Smith, Colin; Stefánsson, Hreinn; Stefánsson, Kári; Steinberg, Stacy; Stockton, Joanna D.; Sveinbjornsdottir, Sigurlaug; Talbot, Kevin; Tanner, Carlie M.; Tashakkori-Ghanbaria, Avazeh; Tison, François; Trabzuni, Daniah; Traynor, Bryan J.; Uitterlinden, André G.; Velseboer, Daan; Vidailhet, Marie; Walker, Robert; van de Warrenburg, Bart; Wickremaratchi, Mirdhu; Williams, Nigel; Williams-Gray, Caroline H.; Winder-Rhodes, Sophie; Wood, Nicholas

    2013-01-01

    Parkinson's disease (PD) is the second most common neurodegenerative disease affecting 1–2% in people >60 and 3–4% in people >80. Genome-wide association (GWA) studies have now implicated significant evidence for association in at least 18 genomic regions. We have studied a large PD-meta analysis and identified a significant excess of SNPs (P < 1 × 10−16) that are associated with PD but fall short of the genome-wide significance threshold. This result was independent of variants at the 18 previously implicated regions and implies the presence of additional polygenic risk alleles. To understand how these loci increase risk of PD, we applied a pathway-based analysis, testing for biological functions that were significantly enriched for genes containing variants associated with PD. Analysing two independent GWA studies, we identified that both had a significant excess in the number of functional categories enriched for PD-associated genes (minimum P = 0.014 and P = 0.006, respectively). Moreover, 58 categories were significantly enriched for associated genes in both GWA studies (P < 0.001), implicating genes involved in the ‘regulation of leucocyte/lymphocyte activity’ and also ‘cytokine-mediated signalling’ as conferring an increased susceptibility to PD. These results were unaltered by the exclusion of all 178 genes that were present at the 18 genomic regions previously reported to be strongly associated with PD (including the HLA locus). Our findings, therefore, provide independent support to the strong association signal at the HLA locus and imply that the immune-related genetic susceptibility to PD is likely to be more widespread in the genome than previously appreciated. PMID:23223016

  9. Selection of support materials for immobilization of Burkholderia cepacia PCL3 in treatment of carbofuran-contaminated water.

    PubMed

    Laocharoen, S; Plangklang, P; Reungsang, A

    2013-01-01

    This study investigated the utilization of agricultural matrices as the support materials for cell immobilization to improve the technique of bioremediation. Coir, bulrush, banana stem and water hyacinth stem in both delignified and undelignified forms were used to immobilize Burkholderia cepacia PCL3 in bioremediation of carbofuran at 5 mg l(-1) in synthetic wastewater. Undelignified coir was found to be the most suitable support material for cell immobilization, giving the short half-life of carbofuran of 3.40 d (2.8 times shorter than the treatments with free cells). In addition, it could be reused three times without a loss in ability to degrade carbofuran. The growth and degradation ability of free cells were completely inhibited at the initial carbofuran concentrations of 250 mg l(-1), while there was no inhibitory effect of carbofuran on the immobilized cells. The results indicated a great potential for using the agricultural matrices as support material for cell immobilization to improve the overall efficiency of carbofuran bioremediation in contaminated water by B. cepacia PCL3. PMID:24527620

  10. 18 CFR 346.2 - Material in support of initial rates or change in rates.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... PIPELINE COST-OF-SERVICE FILING REQUIREMENTS § 346.2 Material in support of initial rates or change in... service, the test period will be based on a 12-month projection of costs and revenues. (b) Cost-of-service summary schedule. This schedule must contain the following information: (1) Total carrier cost of...

  11. Occupational Health and Safety. Numeracy. Level 1. Level 2. Level 3. Support Materials for Agricultural Training.

    ERIC Educational Resources Information Center

    Batman, Kangan; Tully, Chris

    This publication contains the three numeracy units of the three levels of Support Materials for Agricultural Training (SMAT) in the area of occupational health and safety: Level 1 (starting), 2 (continuing), and 3 (completing). The units are designed to help the learner improve his or her numeracy skills needed to deal with occupational safety and…

  12. Farmers as Employers. Level 1. Level 2. Level 3. Support Materials for Agricultural Training.

    ERIC Educational Resources Information Center

    Batman, Kangan; Gadd, Nick; Lucas, Michele

    This publication contains the three communication skills units of the three levels of Support Materials for Agricultural Training (SMAT) in the area of farmers as employers: Level 1 (starting), 2 (continuing), and 3 (completing). The units are designed to help the learner improve his or her written and spoken communication and numeracy skills…

  13. Dispositions Supporting Elementary Interns in the Teaching of Reform-Based Science Materials

    ERIC Educational Resources Information Center

    Eick, Charles J.; Stewart, Bethany

    2010-01-01

    Dispositions supporting the teaching of science as structured inquiry by four elementary candidates are presented. Candidates were studied during student teaching based on their positive attitudes toward teaching science with reform-based materials in their methods course. Personal learning histories informed their attitudes, values, and beliefs…

  14. Occupational Health and Safety. Level 1. Level 2. Level 3. Support Materials for Agricultural Training.

    ERIC Educational Resources Information Center

    Batman, Kangan; Gadd, Nick; Lucas, Michele

    This publication contains the three communication skills units of the three levels of Support Materials for Agricultural Training (SMAT) in the area of occupational health and safety: Level 1 (starting), 2 (continuing), and 3 (completing). The units are designed to help the learner improve his or her written and spoken communication skills needed…

  15. 18 CFR 346.2 - Material in support of initial rates or change in rates.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 18 Conservation of Power and Water Resources 1 2011-04-01 2011-04-01 false Material in support of initial rates or change in rates. 346.2 Section 346.2 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE INTERSTATE COMMERCE ACT...

  16. 18 CFR 346.2 - Material in support of initial rates or change in rates.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 18 Conservation of Power and Water Resources 1 2014-04-01 2014-04-01 false Material in support of initial rates or change in rates. 346.2 Section 346.2 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE INTERSTATE COMMERCE ACT...

  17. 18 CFR 346.2 - Material in support of initial rates or change in rates.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Material in support of initial rates or change in rates. 346.2 Section 346.2 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE INTERSTATE COMMERCE ACT...

  18. 18 CFR 346.2 - Material in support of initial rates or change in rates.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Material in support of initial rates or change in rates. 346.2 Section 346.2 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE INTERSTATE COMMERCE ACT...

  19. Agricultural Production. Level 1. Level 2. Level 3. Support Materials for Agricultural Training.

    ERIC Educational Resources Information Center

    Batman, Kangan; Gadd, Nick; Lucas, Michele

    This publication contains the three communication skills units of the three levels of Support Materials for Agricultural Training (SMAT) in agricultural production: Level 1 (starting), 2 (continuing), and 3 (completing). The units are designed to help the learner improve his or her written and spoken communication skills needed to deal with…

  20. Farm Management and Leadership. Level 1. Level 2. Level 3. Support Materials for Agricultural Training.

    ERIC Educational Resources Information Center

    Batman, Kangan; Gadd, Nick; Lucas, Michele

    This publication contains the three communication skills units of the three levels of Support Materials for Agricultural Training (SMAT) in farm management and leadership: Level 1 (starting), 2 (continuing), and 3 (completing). The units are designed to help the learner with the reading, writing, and spoken communication skills needed to deal with…

  1. Farmers as Employers. Numeracy. Level 1. Level 2. Level 3. Support Materials for Agricultural Training.

    ERIC Educational Resources Information Center

    Batman, Kangan; Tully, Chris

    This publication contains the three numeracy units of the three levels of Support Materials for Agricultural Training (SMAT) in the area of farmers as employers: Level 1 (starting), 2 (continuing), and 3 (completing). The units are designed to help the learner improve his or her numeracy skills needed to deal with employment of agriculture…

  2. Templated synthesis for highly ordered metal/support nanocomposite materials with catalytic applications

    NASA Astrophysics Data System (ADS)

    Sarkar, Jayashri

    Template synthesis is a powerful method of synthesizing materials with tunable properties. Tailorability of the templates makes it a viable method for high performance material synthesis. Surfactant, polymers and semiconductors have been used as templating tools for a long time. In the present work, we demonstrate the ability to synthesize hexagonally organized porous titania, zirconia and zirconia/titania mixed oxide supports and their respective nanocomposites of Pt from their alkoxide precursors using a highly viscous mixed surfactant template, separating nanoscopic bicontinuous channels of water and isooctane. Oil soluble precursor that eventually forms the support, precipitates at the oil-water interface mimicking the microstructure of the template. Subsequent reduction of Pt precursor in the aqueous nanochannels decorates the surface of the macropore walls with well-separated platinum (Pt) nanoparticles. This technique enables us to synthesize two components in a single template system by utilizing both oil and water phases. The composite formed possess a bimodal pore size distribution with one mean pore size ˜3.5nm (nanopores) and the other in the larger mean pore diameter regions ˜100nm-2mum (macropores), depending on the oxide support. Because of the decreased mass transfer resistance provided by the ordered and interconnected macropores in the support, the Pt/TiO2 nanocomposite exhibits a significantly higher carbon monoxide oxidation efficiency than that obtained with a commercial support that has a 4-fold larger specific surface area (at equivalent Pt loadings). We further demonstrate that simple changes in the post-synthesis processing can improve the properties of the material. Altering the drying technique and calcination temperature result in a substantial improvement in the specific surface area of the support material making them better than or comparable to the commercial support materials. We are able to synthesize materials with very low Pt

  3. Intelligent decision support for polymer composite material design in an integrated design environment

    SciTech Connect

    Lenz, T.; McDowell, J.K.; Moy, D.; Sticklen, J.; Hawley, M.C.

    1994-12-31

    Previously used routine design systems which generate multiple designs for composite materials have had a strong focus on thermosets. A natural evolution of the material designer involved an expansion of the domain knowledge for possible composite material designs, as well as a re-engineering of the problem-solving structure. This was guided by an in-depth analysis of the existing material designer. The results of these analyses enabled decisions to be made regarding the adequacy of the existing problem-solving structure and identified avenues to pursue for the re-engineering of the knowledge structuring and decision processes. This reengineering and expansion to a third generation of the material designer has been completed. The third generation material designer, COMADE (Composite Material Designer), now includes an expanded thermoset and fiber material coverage; in addition, thermoplastics and discontinuous fibers have been introduced into the knowledge base. As a result, both the variables input to the system and the outputted material designs have been modified. The inclusion of this information has substantially increased the domain coverage of possible composite material designs.

  4. Carbon fiber as an excellent support material for wastewater treatment biofilms.

    PubMed

    Matsumoto, Shinya; Ohtaki, Akihito; Hori, Katsutoshi

    2012-09-18

    Fibrous materials made of carbon fiber (CF), aromatic polyamide (AP), preoxidized polyacrylonitrile (PAN), and polyethylene (PE), which are widely used in the textile industry, were evaluated as biofilm supports for wastewater treatment. We found that CF has a high capacity for adsorbing nitrifying bacterial sludge. The adhesion rate of four pure strains-Cytophaga hutchinsonii, Alcaligenes faecalis, Bacillus subtilis, and Escherichia coli-was highest to CF. The ζ-potentials of the fibrous supports, and the cell surface potentials of these bacteria on the basis of the soft particle theory, were experimentally determined. Bacterial cell adhesion to the fibrous supports could be explained by Derjaguin-Landau-Verwey-Overbeek theory. Interaction energy profiles based on this theory indicated the disappearance of the energy barrier in bacterial cell adhesion to the CF support, whereas an insurmountable energy barrier was observed in the adhesion to the other fibrous supports. This result was attributed to the less negative ζ-potential of CF and the relatively large Hamaker constant for the CF/bacterium interaction in water; through simulations, the latter factor was found to make a greater contribution to lowering the energy barrier. In practice and theory, CF is an excellent material as a microbial and biofilm support for wastewater treatment. PMID:22906194

  5. Physicochemical analysis of initial adhesion and biofilm formation of Methanosarcina barkeri on polymer support material.

    PubMed

    Nguyen, Vi; Karunakaran, Esther; Collins, Gavin; Biggs, Catherine A

    2016-07-01

    The retention of selective biofilms of Methanosarcina species within anaerobic digesters could reduce start-up times and enhance the efficiency of the process in treating high-strength domestic sewage. The objective of the study was to examine the effect of the surface characteristics of six common polymer support materials on the initial adhesion of the model methanogen, Methanosarcina barkeri, and to assess the potential of these support materials as selective biofilm carriers. Results from both the initial adhesion tests and extended DLVO (xDLVO) model correlated with each other, with PVC (12% surface coverage/mm(2)), PTFE (6% surface coverage/mm(2)), and PP (6% surface coverage/mm(2)), shown to be the better performing support materials for initial adhesion, as well as subsequent biofilm formation by M. barkeri after 72h. Experimental results of these three support materials showed that the type of material strongly influenced the extent of adhesion from M. barkeri (p<0.0001), and the xDLVO model was able to explain the results in these environmental conditions. Therefore, DLVO physicochemical forces were found to be influential on the initial adhesion of M. barkeri. Scanning electron microscopy suggested that production of extracellular polymeric substances (EPS) from M. barkeri could facilitate further biofilm development. This study highlights the potential of using the xDLVO model to rapidly identify suitable materials for the selective adhesion of M. barkeri, which could be beneficial in both the start-up and long-term phases of anaerobic digestion. PMID:27038917

  6. Modeling the mechanical and aging properties of silicone rubber and foam - stockpile-historical & additively manufactured materials

    SciTech Connect

    Maiti, A.; Weisgraber, T. H.; Gee, R. H.

    2014-09-30

    M97* and M9763 belong to the M97xx series of cellular silicone materials that have been deployed as stress cushions in some of the LLNL systems. Their purpose of these support foams is to distribute the stress between adjacent components, maintain relative positioning of various components, and mitigate the effects of component size variation due to manufacturing and temperature changes. In service these materials are subjected to a continuous compressive strain over long periods of time. In order to ensure their effectiveness, it is important to understand how their mechanical properties change over time. The properties we are primarily concerned about are: compression set, load retention, and stress-strain response (modulus).

  7. Supporting Teachers' Use of a Project-Based Learning Environment in Ocean Science: Web-Based Educative Curriculum Materials

    ERIC Educational Resources Information Center

    Duncan, Ravit Golan; El-Moslimany, Hebbah; McDonnell, Janice; Lichtenwalner, Sage

    2011-01-01

    The development of inquiry and project-based materials is challenging in many ways, not the least of which is the design of supports for teachers implementing such materials. We report on the design of educative and just-in-time teacher supports for an online project-based unit in ocean science. The teacher supports were visible as tabs on the…

  8. Beyond Mentoring: A Review of Literature Detailing the Need for Additional and Alternative Forms of Support for Novice Music Teachers

    ERIC Educational Resources Information Center

    Bell-Robertson, Catherine G.

    2015-01-01

    Support for music teachers new to the profession is important and necessary. Some school districts use traditional mentor-mentee pairings as their primary support for novice music teachers; however, many factors in the professional lives of music teachers, such as traveling among multiple schools or a lack of subject-specific colleagues often…

  9. Surface characterization of an energetic material, pentaerythritoltetranitrate (PETN), having a thin coating achieved through a starved addition microencapsulation technique

    SciTech Connect

    Worley, C.M.

    1986-05-07

    The objective of this research was to: (1) determine the nature of a thin coating on an explosive material which was applied using a starved addition microencapsulation technique, (2) understand the coating/crystal bond, and (3) investigate the wettability/adhesion of plastic/solvent combinations using the coating process. The coating used in this work was a Firestone Plastic Company copolymer (FPC-461) of vinylchloride/trifluorochloroethylene in a 1.5/1.0 weight ratio. The energetic explosive examined was pentaerythritoltetranitrate (PETN). The coating process used was starved addition followed by a solvent evaporation technique. Surface analytical studies, completed for characterization of the coating process, show (1) evidence that the polymer coating is present, but not continuous, over the surface of PETN; (2) the average thickness of the polymer coating is between 16-32 A and greater than 44 A, respectively, for 0.5 and 20 wt % coated PETN; (3) no changes in surface chemistry of the polymer or the explosive material following microencapsulation; and (4) the presence of explosive material on the surface of 0.5 wt % FPC-461 coated explosives. 5 refs., 15 figs., 6 tabs.

  10. Readability of Educational Materials to Support Parent Sexual Communication With Their Children and Adolescents.

    PubMed

    Ballonoff Suleiman, Ahna; Lin, Jessica S; Constantine, Norman A

    2016-05-01

    Sexual communication is a principal means of transmitting sexual values, expectations, and knowledge from parents to their children and adolescents. Many parents seek information and guidance to support talking with their children about sex and sexuality. Parent education materials can deliver this guidance but must use appropriate readability levels to facilitate comprehension and motivation. This study appraised the readability of educational materials to support parent sexual communication with their children. Fifty brochures, pamphlets, and booklets were analyzed using the Flesch-Kincaid, Gunning Fog, and Simple Measure of Gobbledygook (SMOG) index methods. Mean readability grade-level scores were 8.3 (range = 4.5-12.8), 9.7 (range = 5.5-14.9), and 10.1 (range = 6.7-13.9), respectively. Informed by National Institutes of Health-recommended 6th to 7th grade levels and American Medical Association-recommended 5th to 6th grade levels, percentages falling at or below the 7.0 grade level were calculated as 38%, 12%, and 2% and those falling at or below the 6.0 grade level were calculated as 12%, 2%, and 0% based on the Flesch-Kincaid, Gunning Fog, and SMOG methods, respectively. These analyses indicate that the majority of educational materials available online to support parents' communication with their children about sex and sexuality do not meet the needs of many or most parents. Efforts to improve the accessibility of these materials are warranted. PMID:27116292

  11. Use of silicate crystallite mesoporous material as catalyst support for Fischer Tropsch reaction

    NASA Astrophysics Data System (ADS)

    Iwasaki, T.; Reinikainen, M.; Onodera, Y.; Hayashi, H.; Ebina, T.; Nagase, T.; Torii, K.; Kataja, K.; Chatterjee, A.

    1998-06-01

    Novel uniform mesoporous materials (silicate crystallite mesoporous material, SCMM) were synthesized by hydrothermal treatment of Si, Mg and/or Al containing hydroxide precipitates, along with quaternary ammonium salt, and were applied as catalyst support for Fischer-Tropsch reaction. SCMM is composed of aggregates of homogeneous layer silicate crystallites, as identified by X-ray diffraction (XRD) patterns and transmission electron microscopy (TEM) photographs which are structurally analogous to smectite clay. The mesopore of SCMM corresponds to interparticle space of disk-shaped crystallites (6-25 nm in diameter) aggregated by edge-to-face bonding. Two kinds of SCMM with variable negative charge locations were used as support materials of Co-catalysts for hydrogenation of CO. Conversion of CO was high on SCMM compared with that of silica gel. Furthermore, the main products obtained were hydrocarbons. In case of SCMM type with negative charge near the surface, olefins and branched hydrocarbons were efficiently produced in CO conversion reaction; where as another SCMM type having negative charge at the middle of crystallite platelets produced mainly normal hydrocarbons for the same reaction. This may be due to the role of the negative charge of SCMM which affects the chemical state of Co-catalyst supported on SCMM. The function of SCMM as compared to other mesoporous materials is better in terms of homogeneous and site-specific distribution of negative charge, which is further helpful in controlling the surface phenomenon as confirmed by the existence of linear CO species adsorbed on Co.

  12. Influence of the supporting die structures on the fracture strength of all-ceramic materials.

    PubMed

    Yucel, Munir Tolga; Yondem, Isa; Aykent, Filiz; Eraslan, Oğuz

    2012-08-01

    This study investigated the influence of the elastic modulus of supporting dies on the fracture strengths of all-ceramic materials used in dental crowns. Four different types of supporting die materials (dentin, epoxy resin, brass, and stainless steel) (24 per group) were prepared using a milling machine to simulate a mandibular molar all-ceramic core preparation. A total number of 96 zirconia cores were fabricated using a CAD/CAM system. The specimens were divided into two groups. In the first group, cores were cemented to substructures using a dual-cure resin cement. In the second group, cores were not cemented to the supporting dies. The specimens were loaded using a universal testing machine at a crosshead speed of 0.5 mm/min until fracture occurred. Data were statistically analyzed using two-way analysis of variance and Tukey HSD tests (α = 0.05). The geometric models of cores and supporting die materials were developed using finite element method to obtain the stress distribution of the forces. Cemented groups showed statistically higher fracture strength values than non-cemented groups. While ceramic cores on stainless steel dies showed the highest fracture strength values, ceramic cores on dentin dies showed the lowest fracture strength values among the groups. The elastic modulus of the supporting die structure is a significant factor in determining the fracture resistance of all-ceramic crowns. Using supporting die structures that have a low elastic modulus may be suitable for fracture strength tests, in order to accurately reflect clinical conditions. PMID:21845404

  13. ESF GROUND SUPPORT - MATERIAL DEDICATION ANALYSIS FOR STRUCTURAL STEEL AND ACCESSORIES FROM A COMMERCIAL GRADE SOURCE

    SciTech Connect

    M.D. Stine

    1996-01-23

    The purpose of this analysis is to select the critical characteristics to be verified for steel sets and accessories and the verification methods to be implemented through a material dedication process for the procurement and use of commercial grade structural steel sets and accessories (which have a nuclear safety function) to be used in ground support (with the exception of alcove ground support and alcove opening framing, which are not addressed in this analysis) for the Exploratory Studies Facility (ESF) Topopah Spring (TS) Loop. The ESF TS Loop includes the North Ramp, Main Drift, and South Ramp underground openings.

  14. Mechanical degradation under hydrogen of yttrium doped barium zirconate electrolyte material prepared with NiO additive

    NASA Astrophysics Data System (ADS)

    Ciria, D.; Ben Hassine, M.; Jiménez-Melendo, M.; Iakovleva, A.; Haghi-Ashtiani, P.; Aubin, V.; Dezanneau, G.

    2016-07-01

    Recently, a novel process was presented to fabricate dense yttrium-doped barium zirconate electrolytes with high proton conductivity. This process was based on the use of a NiO additive during reactive sintering. We show here that materials made from this process present a fast degradation of mechanical properties when put in hydrogen-rich conditions, while material made from conventional sintering without NiO aid remains intact in the same conditions. The fast degradation of samples made from reactive sintering, leading to sample failure under highly compressive conditions, is due to the reduction of NiO nanoparticles at grain boundaries as shown from structural and chemical analyses using Transmission Electron Microscopy. By the present study, we alert about the potential risk of cell failure due to this mechanical degradation.

  15. Methodological framework for developing decision support systems (DSS) for hazardous materials emergency response operations.

    PubMed

    Zografos, K G; Vasilakis, G M; Giannouli, I M

    2000-01-01

    The production, storage, and transportation of hazardous materials are processes of vital economic importance for any advanced and technologically complex society. Although the production and distribution of hazardous materials is associated with economic development, there is a significant potential danger to the natural and social environment in the event of their accidental release, a fact that prompts for the development and implementation of methods and techniques that aim to improve hazardous materials risk management decisions. The objective of this paper is to present a unified framework for developing a Decision Support System (DSS) for supporting a vital function of risk management, namely the management of emergency response operations. The proposed framework recognizes the peculiarities of the hazardous materials decision-making environment which is characterized by: (i) multiple stakeholders, i.e., persons and organizations involved in and affected by hazardous materials risk management decisions; (ii) lack of a formal management structure for monitoring and controlling in a unified manner all Emergency Response Resources; (iii) lack of clear distinction and fragmentation of responsibilities of the actors involved in risk management operations; and (iv) dynamic/real-time decisions, i.e., risk determinants change over time. The proposed framework was used in order to develop a DSS for managing emergency response operations for large scale industrial accidents in Western Attica, Greece. PMID:10677678

  16. A color-tunable luminescent material with functionalized graphitic carbon nitride as multifunctional supports

    NASA Astrophysics Data System (ADS)

    Lu, Jiutian; Cao, Yudong; Fan, Hai; Hou, Juying; Ai, Shiyun

    2015-12-01

    A color-tunable luminescent material was prepared based on the composition of functionalized graphitic carbon nitride (g-C3N4) and europium (III). The functionalized g-C3N4 layers not only behave as multifunctional supports including ligand coordinated with europium (III) and a support structure for the formation of the luminescent material, but exhibit excitation wavelength-dependent luminescence, thus the energy transfer between the functionalized g-C3N4 and europium (III) can match very well by controlling the emission wavelength of functionalized g-C3N4. The as-prepared materials was comprehensively characterized via X-ray photoelectron spectroscopy, Fourier Transform Infrared spectroscopy, X-ray scattering techniques, Ultraviolet and Visible spectrophotometer, fluorescence spectrophotometer, thermogravimetric analysis, etc. The luminescent material exhibits multi-color emissions which are consistent with the characteristic emissions of europium (III) and functionalized g-C3N4, and the photoluminescence quality and density of the europium (III) can be greatly enhanced. The brilliant optical properties of the materials make them suiting for multipurpose applications in practical fields.

  17. Facilities to Support Beamed Energy Launch Testing at the Laser Hardened Materials Evaluation Laboratory (LHMEL)

    NASA Astrophysics Data System (ADS)

    Lander, Michael L.

    2003-05-01

    The Laser Hardened Materials Evaluation Laboratory (LHMEL) has been characterizing material responses to laser energy in support of national defense programs and the aerospace industry for the past 26 years. This paper reviews the overall resources available at LHMEL to support fundamental materials testing relating to impulse coupling measurement and to explore beamed energy launch concepts. Located at Wright-Patterson Air Force Base, Ohio, LHMEL is managed by the Air Force Research Laboratory Materials Directorate AFRL/MLPJ and operated by Anteon Corporation. The facility's advanced hardware is centered around carbon dioxide lasers producing output power up to 135kW and neodymium glass lasers producing up to 10 kilojoules of repetitively pulsed output. The specific capabilities of each laser device and related optical systems are discussed. Materials testing capabilities coupled with the laser systems are also described including laser output and test specimen response diagnostics. Environmental simulation capabilities including wind tunnels and large-volume vacuum chambers relevant to beamed energy propulsion are also discussed. This paper concludes with a summary of the procedures and methods by which the facility can be accessed.

  18. Novel Dental Restorative Materials having Low Polymerization Shrinkage Stress via Stress Relaxation by Addition-Fragmentation Chain Transfer

    PubMed Central

    Park, Hee Young; Kloxin, Christopher J.; Abuelyaman, Ahmed S.; Oxman, Joe D.; Bowman, Christopher N.

    2012-01-01

    Objectives To produce a reduced stress dental restorative material while simultaneously maintaining excellent mechanical properties, we have incorporated an allyl sulfide functional group into norbornene-methacrylate comonomer resins. We hypothesize that the addition-fragmentation chain transfer (AFCT) enabled by the presence of the allyl sulfide relieves stress in these methacrylate-based systems while retaining excellent mechanical properties owing to the high glass transition temperature of norbornene-containing resins. Methods An allyl sulfide-containing dinorbornene was stoichiometrically formulated with a ring-containing allyl sulfide-possessing methacrylate. To evaluate the stress relaxation effect as a function of the allyl sulfide concentration, a propyl sulfide-based dinorbornene, not capable of addition-fragmentation, was also formulated with the methacrylate monomer. Shrinkage stress, the glass transition temperature and the elastic modulus were all measured. The composite flexural strength and modulus were also measured. ANOVA (CI 95%) was conducted to determine differences between the means. Results Increasing the allyl sulfide content in the resin dramatically reduces the final stress in the norbornene-methacrylate systems. Both norbornene-methacrylate resins demonstrated almost zero stress (more than 96% stress reduction) compared with the conventional BisGMA/TEGDMA 70/30 wt% control. Mechanical properties of the allyl sulfide-based dental composites were improved to the point of being statistically indistinguishable from the control BisGMA-TEGDMA by changing the molar ratio between the methacrylate and norbornene functionalities. Significance The allyl sulfide-containing norbornene-methacrylate networks possessed super-ambient Tg, and demonstrated significantly lower shrinkage stress when compared with the control (BisGMA/TEGDMA 70 to 30 wt%). Although additional development remains, these low stress materials exhibit excellent mechanical

  19. Materials technology programs in support of a mercury Rankine space power system

    NASA Technical Reports Server (NTRS)

    Stone, P. L.

    1973-01-01

    A large portion of the materials technology is summarized that was generated in support of the development of a mercury-rankine space power system (SNAP-8). The primary areas of investigation are: (1) the compatibility of various construction materials with the liquid metals mercury and NaK, (2) the mechanical properties of unalloyed tantalum, and (3) the development of refractory metal/austenitic stainless steel tubing and transition joints. The primary results, conclusions, and state of technology at the completion of this effort for each of these areas are summarized. Results of possible significance to other applications are highlighted.

  20. Fabrication of Fe-FeAl Functionally Graded Material Using the Wire-Arc Additive Manufacturing Process

    NASA Astrophysics Data System (ADS)

    Shen, Chen; Pan, Zengxi; Cuiuri, Dominic; Roberts, Jon; Li, Huijun

    2016-02-01

    A functionally gradient iron-aluminum wall structure with aluminum composition gradient from 0 at. pct to over 50 at. pct is fabricated using a wire-arc additive manufacturing (WAAM) system. The as-fabricated alloy is investigated using optical microstructure analysis, hardness testing, tensile testing, X-ray diffraction phase characterization, and electron-dispersive spectrometry. The comprehensive analysis of the experimental samples has shown that the WAAM system can be used for manufacturing iron aluminide functionally graded material with full density, desired composition, and reasonable mechanical properties.

  1. Aryl bromides as inexpensive starting materials in the catalytic enantioselective arylation of aryl aldehydes: the additive TMEDA enhances the enantioselectivity.

    PubMed

    Yang, Yong-Xin; Liu, Yue; Zhang, Lei; Jia, Yan-E; Wang, Pei; Zhuo, Fang-Fang; An, Xian-Tao; Da, Chao-Shan

    2014-11-01

    We used aryl bromides as inexpensive starting materials to enantioselectively arylate aldehydes in one pot. Aryl bromides readily transfer aryls to aryllithiums with n-butyllithium, successively to triarylaluminums with aluminum chloride, and then to aryltitaniums with titanium isopropoxide. Finally aryltitaniums arylate aldehydes catalyzed by (S)-H8-BINOL-Ti(Oi-Pr)2 in excellent yields and enantioselectivities. The additive TMEDA evidently suppresses the racemic background reaction promoted by LiCl generated from salt metathesis. This procedure represents a cost-effective and operationally convenient method for enantioenriched diarylmethanols. PMID:25279967

  2. Active-material additives for high-rate lead/acid batteries: have there been any positive advances?

    NASA Astrophysics Data System (ADS)

    McGregor, K.

    Low positive mass utilization poses a major problem for lead/acid batteries, particularly at high discharge rates, and is one of the major factors that limits the specific energy of the battery. The reasons for the incomplete discharge at high rates are generally ascribed to a combination of various polarization phenomena including: (i) poor acid transport from the bulk of the solution in the interior of the plate, and (ii) a continuous decrease in the conductivity of the plates due to formation of non-conductive PbSO 4. One approach to alleviating these problems is to improve the positive-plate porosity and/or conductivity by the incorporation of additives into the positive active-material. The purpose of this paper is to reew recent work with such additives, and to appraise their effectiveness towards raising battery performance.

  3. 49 CFR 40.303 - What happens if the SAP believes the employee needs additional treatment, aftercare, or support...

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 49 Transportation 1 2012-10-01 2012-10-01 false What happens if the SAP believes the employee... the Return-to-Duty Process § 40.303 What happens if the SAP believes the employee needs additional...? (a) As a SAP, if you believe that ongoing services (in addition to follow-up tests) are needed...

  4. 49 CFR 40.303 - What happens if the SAP believes the employee needs additional treatment, aftercare, or support...

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 49 Transportation 1 2013-10-01 2013-10-01 false What happens if the SAP believes the employee... the Return-to-Duty Process § 40.303 What happens if the SAP believes the employee needs additional...? (a) As a SAP, if you believe that ongoing services (in addition to follow-up tests) are needed...

  5. 49 CFR 40.303 - What happens if the SAP believes the employee needs additional treatment, aftercare, or support...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 49 Transportation 1 2010-10-01 2010-10-01 false What happens if the SAP believes the employee... the Return-to-Duty Process § 40.303 What happens if the SAP believes the employee needs additional...? (a) As a SAP, if you believe that ongoing services (in addition to follow-up tests) are needed...

  6. 49 CFR 40.303 - What happens if the SAP believes the employee needs additional treatment, aftercare, or support...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 49 Transportation 1 2011-10-01 2011-10-01 false What happens if the SAP believes the employee... the Return-to-Duty Process § 40.303 What happens if the SAP believes the employee needs additional...? (a) As a SAP, if you believe that ongoing services (in addition to follow-up tests) are needed...

  7. 49 CFR 40.303 - What happens if the SAP believes the employee needs additional treatment, aftercare, or support...

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 49 Transportation 1 2014-10-01 2014-10-01 false What happens if the SAP believes the employee... the Return-to-Duty Process § 40.303 What happens if the SAP believes the employee needs additional...? (a) As a SAP, if you believe that ongoing services (in addition to follow-up tests) are needed...

  8. Energetic materials research and development activities at Sandia National Laboratories supported under DP-10 programs

    SciTech Connect

    Ratzel, A.C. III

    1998-09-01

    This report provides summary descriptions of Energetic Materials (EM) Research and Development activities performed at Sandia National Laboratories and funded through the Department of Energy DP-10 Program Office in FY97 and FY98. The work falls under three major focus areas: EM Chemistry, EM Characterization, and EM Phenomenological Model Development. The research supports the Sandia component mission and also Sandia's overall role as safety steward for the DOE Nuclear Weapons Complex.

  9. Immobilization of heavy metals in polluted soils by the addition of zeolitic material synthesized from coal fly ash.

    PubMed

    Querol, Xavier; Alastuey, Andrés; Moreno, Natàlia; Alvarez-Ayuso, Esther; García-Sánchez, Antonio; Cama, Jordi; Ayora, Carles; Simón, Mariano

    2006-01-01

    The use of zeolitic material synthesized from coal fly ash for the immobilization of pollutants in contaminated soils was investigated in experimental plots in the Guadiamar Valley (SW Spain). This area was affected by a pyrite slurry spill in April 1998. Although reclamation activities were completed in a few months, residual pyrite slurry mixed with soil accounted for relatively high leachable levels of trace elements such as Zn, Pb, As, Cu, Sb, Co, Tl and Cd. Phytoremediation strategies were adopted for the final recovery of the polluted soils. The immobilization of metals had previously been undertaken to avoid leaching processes and the consequent groundwater pollution. To this end, 1100 kg of high NaP1 (Na6[(AlO2)6(SiO2)10] .15H2O) zeolitic material was synthesized using fly ash from the Teruel power plant (NE Spain), in a 10 m3 reactor. This zeolitic material was manually applied using different doses (10000-25000 kg per hectare), into the 25 cm topsoil. Another plot (control) was maintained without zeolite. Sampling was carried out 1 and 2 years after the zeolite addition. The results show that the zeolitic material considerably decreases the leaching of Cd, Co, Cu, Ni, and Zn. The sorption of metals in soil clay minerals (illite) proved to be the main cause contributing to the immobilization of these pollutants. This sorption could be a consequence of the rise in pH from 3.3 to 7.6 owing to the alkalinity of the zeolitic material added (caused by traces of free lime in the fly ash, or residual NaOH from synthesis). PMID:16039695

  10. Apparatus for supporting contactors used in extracting nuclear materials from liquids

    DOEpatents

    Leonard, Ralph A.; Frank, Robert C.

    1991-01-01

    Apparatus is provided for supporting one or more contactor stages used to remove radioactive materials from aqueous solutions. The contactor stages include a housing having an internal rotor, a motor secured to the top of the housing for rotating the rotor, and a drain in the bottom of the housing. The support apparatus includes two or more vertical members each secured to a ground support that is horizontal and perpendicular to the frame member, and a horizontally disposed frame member. The frame member may be any suitable shape, but is preferably a rectangular tube having substantially flat, spaced top and bottom surfaces separated by substantially vertical side surfaces. The top and bottom surfaces each have an opening through which the contactor housing is secured so that the motor is above the frame and the drain is below the frame during use.

  11. Estimating the Additional Greenhouse Gas Emissions in Korea: Focused on Demolition of Asbestos Containing Materials in Building.

    PubMed

    Kim, Young-Chan; Hong, Won-Hwa; Zhang, Yuan-Long; Son, Byeung-Hun; Seo, Youn-Kyu; Choi, Jun-Ho

    2016-01-01

    When asbestos containing materials (ACM) must be removed from the building before demolition, additional greenhouse gas (GHG) emissions are generated. However, precedent studies have not considered the removal of ACM from the building. The present study aimed to develop a model for estimating GHG emissions created by the ACM removal processes, specifically the removal of asbestos cement slates (ACS). The second objective was to use the new model to predict the total GHG emission produced by ACM removal in the entire country of Korea. First, an input-equipment inventory was established for each step of the ACS removal process. Second, an energy consumption database for each equipment type was established. Third, the total GHG emission contributed by each step of the process was calculated. The GHG emissions generated from the 1,142,688 ACS-containing buildings in Korea was estimated to total 23,778 tonCO₂eq to 132,141 tonCO₂eq. This study was meaningful in that the emissions generated by ACS removal have not been studied before. Furthermore, the study deals with additional problems that can be triggered by the presence of asbestos in building materials. The method provided in this study is expected to contribute greatly to the calculation of GHG emissions caused by ACM worldwide. PMID:27626433

  12. Role of the support material on laser desorption/ionization mass spectra.

    PubMed

    Gruszecka, A; Szymanska-Chargot, M; Smolira, A; Cytawa, J; Michalak, L

    2008-04-01

    We report the results of experimental studies on the effects of sample supports in laser desorption/ionization mass spectrometry (LDI-MS). LDI time-of-flight (TOF) mass spectra obtained for C(60) and insulin samples deposited onto standard stainless steel substrate and/or onto some non-metallic materials (glass, scotch tape, floppy disc foil, Teflon foil, photocopy film), all recorded under identical, typical experimental conditions, have been compared with regard to their intensity and quality. The LDI investigations show that compared with stainless steel, glass and floppy disc foil sample supports boost (2-3.5 times) ion yields for C(60)(+) and C(60)(-) ions, respectively. The stainless steel and scotch tape sample supports are the best for the mass resolution of positive ions and the formation of (C(60))(n)(-) (n support materials tested. A mechanism of ion formation in the desorption plume is suggested. PMID:18302166

  13. Effect of PEG additive on anode microstructure and cell performance of anode-supported MT-SOFCs fabricated by phase inversion method

    NASA Astrophysics Data System (ADS)

    Ren, Cong; Liu, Tong; Maturavongsadit, Panita; Luckanagul, Jittima Amie; Chen, Fanglin

    2015-04-01

    Anode-supported micro-tubular solid oxide fuel cells (MT-SOFCs) have been fabricated by phase inversion method. For the anode support preparation, N-methyl-2-pyrrolidone (NMP), polyethersulfone (PESf) and poly ethylene glycol (PEG) were applied as solvent, polymer binder and additive, respectively. The effect of molecular weight and amount of PEG additive on the thermodynamics of the casting solutions was characterized by measuring the coagulation value. Viscosity of the casting slurries was also measured and the influence of PEG additive on viscosity was studied and discussed. The presence of PEG in the casting slurry can significantly influence the final anode support microstructure. Based on the microstructure result and the measured gas permeation value, two anode supports were selected for cell fabrication. For cell with the anode support fabricated using slurry with PEG additive, a maximum cell power density of 704 mW cm-2 is obtained at 750 °C with humidified hydrogen as fuel and ambient air as oxidant; cell fabricated without any PEG additive shows the peak cell power density of 331 mW cm-2. The relationship between anode microstructure and cell performance was discussed.

  14. Effect of veneering material on the deformation suffered by implant-supported fixed prosthesis framework

    PubMed Central

    GRANDO, Antônio Francisco; REZENDE, Carlos Eduardo Edwards; SOUSA, Edson Antônio Capello; RUBO, José Henrique

    2014-01-01

    Knowing how stresses are dissipated on the fixed implant-supported complex allows adequate treatment planning and better choice of the materials used for prosthesis fabrication. Objectives The aim of this study was to evaluate the deformation suffered by cantilevered implant-supported fixed prostheses frameworks cast in silver-palladium alloy and coated with two occlusal veneering materials: acrylic resin or porcelain. Material and Methods Two strain gauges were bonded to the inferior surface of the silver-palladium framework and two other were bonded to the occlusal surface of the prosthesis framework covered with ceramic and acrylic resin on each of its two halves. The framework was fixed to a metallic master model and a 35.2 N compression force was applied to the cantilever at 10, 15 and 20 mm from the most distal implant. The measurements of deformation by compression and tension were obtained. The statistical 2-way ANOVA test was used for individual analysis of the experiment variables and the Tukey test was used for the interrelation between all the variables (material and distance of force application). Results The results showed that both variables had influence on the studied factors (deformation by compression and tension). Conclusion The ceramic coating provided greater rigidity to the assembly and therefore less distortion compared with the uncoated framework and with the resin-coated framework. The cantilever arm length also influenced the prosthesis rigidity, causing higher deformation the farther the load was applied from the last implant. PMID:25025562

  15. CO oxidation over gold supported on Cs, Li and Ti-doped cryptomelane materials.

    PubMed

    Carabineiro, Sónia A C; Santos, Vera P; Pereira, M Fernando R; Órfão, José J M; Figueiredo, José L

    2016-10-15

    Cryptomelane-type manganese oxides were synthesized by redox reaction under acid and reflux conditions. Different metals (cesium, lithium and titanium) were incorporated into the tunnel structure by the ion-exchange technique. Gold was loaded onto these materials (1wt%) by a double impregnation method. The obtained catalysts were characterized by high-resolution transmission electron microscopy, energy-dispersive X-ray spectrometry, scanning electron microscopy, X-ray diffraction and temperature-programmed reduction. The catalytic activity of these materials was evaluated in the oxidation of carbon monoxide. The incorporation of Cs, Li or Ti into cryptomelane was detrimental in terms of catalytic activity. Further addition of gold to cryptomelane doped materials significantly improved the catalytic performance, especially for Cs-K-OMS-2 and Li-K-OMS-2 (to a smaller extent). Addition of gold to the Ti containing material did not show a significant improvement. The observed trends are related to the effect of gold on samples reducibility and to the gold particle size. The lattice oxygen can also be considered accountable for the activity of the materials, since the most active cryptomelane catalysts are those with higher lattice oxygen donating ability for the oxidation of the CO molecule. PMID:27399615

  16. Geochemistry and materials studies in support of the Magma Energy Extraction Program

    SciTech Connect

    Westrich, H.R.; Weirick, L.J.

    1986-01-01

    Geochemistry and materials studies are being performed in support of the Magma Energy Extraction Program. The scope of the studies is dictated by the sites under consideration and the designs of the drilling and energy extraction systems. The work has been largely restricted to characterizing magmatic environments at sites of interest and testing engineering materials in laboratory simulated rhyolite magmatic environments. The behavior of 17 commercially available materials has been examined at magmatic conditions. Analysis of reaction products reveal that oxidation, and not sulfidation, is the main corrosion problem for most alloys in rhyolite, and that reaction with other magmatic components is limited. Considerations of corrosion resistance, high-temperature strength, and cost indicate nickel-base superalloys offer the most promise as candidates for use in rhyolitic magma.

  17. The use of nanometer tetrabasic lead sulfate as positive active material additive for valve regulated lead-acid battery

    NASA Astrophysics Data System (ADS)

    Lang, Xiaoshi; Wang, Dianlong; Hu, Chiyu; Tang, Shenzhi; Zhu, Junsheng; Guo, Chenfeng

    2014-12-01

    Conventional tetrabasic lead sulfate used as positive active material additive shows the results of the low effective lead dioxide conversion rate due to the large grain size and crossed the crystal structure. In this paper, we study on a type of nanometer tetrabasic lead sulfate. Through the XRD and SEM test and Material Studio software calculation, the purity of tetrabasic lead sulfate is very high, the grain size of the nanometer 4BS is almost unanimous, and can be controlled below 200 nm. When charged and discharged in 1.75 V-2.42 V with the current density of 40 mA g-1, 80 mA g-1 and 160 mA g-1, the effective lead dioxide conversion rate of nanometer 4BS after formation can achieve to 83.48%, 71.42%, and 66.96%. Subsequently, the nanometer 4BS as additive is added to positive paste of lead-acid battery. When the batteries are tested galvanostatically between 1.75 V and 2.42 V at 0.25 C charge and 0.5 C discharge rates at room temperature. The ratio of adding nanometer 4BS is 0%, 1% and 4% and the initial discharge specific capacities are 60 mAh g-1, 65 mAh g-1 and 68 mAh g-1. After 80 cycles, the initial discharge capacity of positive active material with 1% nanometer 4BS decreased less than 10%, while adding 4% nanometer 4BS, the initial discharge capacity doesn't decrease obviously.

  18. Rational molecular dynamics scheme for predicting optimum concentration loading of nano-additive in phase change materials

    NASA Astrophysics Data System (ADS)

    Rastogi, Monisha; Vaish, Rahul; Madhar, Niyaz Ahamad; Shaikh, Hamid; Al-Zahrani, S. M.

    2015-10-01

    The present study deals with the diffusion and phase transition behaviour of paraffin reinforced with carbon nano-additives namely graphene oxide (GO) and surface functionalized single walled carbon nanotubes (SWCNT). Bulk disordered systems of paraffin hydrocarbons impregnated with carbon nano-additives have been generated in realistic equilibrium conformations for potential application as latent heat storage systems. Ab initio molecular dynamics(MD) in conjugation with COMPASS forcefield has been implemented using periodic boundary conditions. The proposed scheme allows determination of optimum nano-additive loading for improving thermo-physical properties through analysis of mass, thermal and transport properties; and assists in determination of composite behaviour and related performance from microscopic point of view. It was observed that nanocomposites containing 7.8 % surface functionalised SWCNT and 55% GO loading corresponds to best latent heat storage system. The propounded methodology could serve as a by-pass route for economically taxing and iterative experimental procedures required to attain the optimum composition for best performance. The results also hint at the large unexplored potential of ab-initio classical MD techniques for predicting performance of new nanocomposites for potential phase change material applications.

  19. LEVERAGING AGING MATERIALS DATA TO SUPPORT EXTENSION OF TRANSPORTATION SHIPPING PACKAGES SERVICE LIFE

    SciTech Connect

    Dunn, K.; Bellamy, S.; Daugherty, W.; Sindelar, R.; Skidmore, E.

    2013-08-18

    Nuclear material inventories are increasingly being transferred to interim storage locations where they may reside for extended periods of time. Use of a shipping package to store nuclear materials after the transfer has become more common for a variety of reasons. Shipping packages are robust and have a qualified pedigree for performance in normal operation and accident conditions but are only certified over an approved transportation window. The continued use of shipping packages to contain nuclear material during interim storage will result in reduced overall costs and reduced exposure to workers. However, the shipping package materials of construction must maintain integrity as specified by the safety basis of the storage facility throughout the storage period, which is typically well beyond the certified transportation window. In many ways, the certification processes required for interim storage of nuclear materials in shipping packages is similar to life extension programs required for dry cask storage systems for commercial nuclear fuels. The storage of spent nuclear fuel in dry cask storage systems is federally-regulated, and over 1500 individual dry casks have been in successful service up to 20 years in the US. The uncertainty in final disposition will likely require extended storage of this fuel well beyond initial license periods and perhaps multiple re-licenses may be needed. Thus, both the shipping packages and the dry cask storage systems require materials integrity assessments and assurance of continued satisfactory materials performance over times not considered in the original evaluation processes. Test programs for the shipping packages have been established to obtain aging data on materials of construction to demonstrate continued system integrity. The collective data may be coupled with similar data for the dry cask storage systems and used to support extending the service life of shipping packages in both transportation and storage.

  20. Medial prefrontal cortex supports source memory for self-referenced materials in young and older adults

    PubMed Central

    Leshikar, Eric D.; Duarte, Audrey

    2013-01-01

    Behavioral evidence suggests that young and older adults show a benefit in source memory accuracy when processing materials in reference to the self. In the young, activity within the medial prefrontal cortex supports this source memory benefit at study. This investigation examined whether the same neural regions support this memory benefit in both age groups. Using fMRI, participants were scanned while studying and retrieving pictures of objects paired with one of three scenes (source) under self-reference and other-reference conditions. At the time of study, half of the items were presented once and half twice, allowing us to match behavioral performance between groups. Both groups showed equivalent source accuracy benefit for objects encoded self-referentially. Activity in the left dorsal medial prefrontal cortex supported subsequent source memory in both age groups for the self-referenced relative to the other-referenced items. At the time of test, source accuracy for both self- and other-referenced items was supported by a network of regions including the precuneus in both age groups. At both study and test, little in the way of age-differences emerged, suggesting that when matched on behavioral performance young and older adults engage similar regions in support of source memory when processing materials in reference to the self; however, when performance was not matched, age differences in functional recruitment were prevalent. These results suggest that by capitalizing on preserved processes (self-referential encoding), older adults can show improvement in memory for source details which typically are not well remembered relative to the young. PMID:23904335

  1. Effect of kaolin addition on the performance of controlled low-strength material using industrial waste incineration bottom ash.

    PubMed

    Naganathan, Sivakumar; Razak, Hashim Abdul; Hamid, Siti Nadzriah Abdul

    2010-09-01

    Incineration of industrial waste produces large quantities of bottom ash which are normally sent to secured landfill, but is not a sustainable solution. Use of bottom ash in engineering applications will contribute to sustainability and generate revenue. One way of using the industrial waste incineration bottom ash is in controlled low-strength material (CLSM). Use of bottom ash in CLSM has problems related to bleeding and excessive strength development and so an additive has to be used to control bleeding and strength development. The main objective of this research is to study the effect of kaolin addition on the performance of CLSM made using industrial waste incineration bottom ash. CLSM mixes were made with bottom ash, cement, and refined kaolin. Various tests were performed on the CLSM in fresh and hardened states including compressive strength, water absorption, California bearing ratio (CBR) and the tests for concentration of leachable substances on the bleed and leachate. The compressive strength of CLSM tested ranged from 0.11 to 9.86 MPa. CBR values ranged from 6 to 46, and water absorption values from 12 to 36%. It was shown that the addition of kaolin delayed the initial setting time of CLSM mixtures, reduced bleeding, lowered the compressive strength, and increased the values of water absorption, sorption, and initial surface absorption. The CLSM tested did not have corrosivity. It was shown that the hardened CLSM was non hazardous, and the addition of kaolin increased the concentration of heavy metals and salts in the bleed and leachate. PMID:20852000

  2. Nanostructured TiOx as a catalyst support material for proton exchange membrane fuel cells

    NASA Astrophysics Data System (ADS)

    Phillips, Richard S.

    Recent interest in the development of new catalyst support materials for proton exchange membrane fuel cells (PEMFCs) has stimulated research into the viability of TiO2-based support structures. Specifically, substoichiometric TiO2 (TiOx) has been reported to exhibit a combination of high conductivity, stability, and corrosion resistance. These properties make TiOx-based support materials a promising prospect when considering the inferior corrosion resistance of traditional carbon-based supports. This document presents an investigation into the formation of conductive and stable TiOx thin films employing atomic layer deposition (ALD) and a post deposition oxygen reducing anneal (PDORA). Techniques for manufacturing TiOx-based catalyst support nanostructures by means of ALD in conjunction with carbon black (CB), anodic aluminum oxide (AAO) and silicon nanowires (SiNWs) will also be presented. The composition and thickness of resulting TiOx thin films was determined with the aid of Auger electron spectroscopy (AES), Rutherford backscattering spectrometry (RBS), X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray spectroscopy (EDS), and scanning electron microscopy (SEM). Film crystal structure was determined with X-ray diffraction (XRD) analysis. Film conductivity was calculated using four-point probe (4-PP) and film thickness measurement data. Resulting thin films show a significant decrease of oxygen in ALD TiOx films corresponding with a great increase in conductivity following the PDORA. The effectiveness of the PDORA was also found to be highly dependent on ALD process parameters. TiOx-based nanostructures were coated with platinum using one of three Pt deposition techniques. First, liquid phase deposition (LPD), which was performed at room temperature, provided equal access to catalyst support material surfaces which were suspended in solution. Second, plasma enhanced atomic layer deposition (PEALD), which was performed at 450°C, provided good Pt

  3. Investigating Teacher Learning Supports in High School Biology Curricular Programs to Inform the Design of Educative Curriculum Materials

    ERIC Educational Resources Information Center

    Beyer, Carrie J.; Delgado, Cesar; Davis, Elizabeth A.; Krajcik, Joseph

    2009-01-01

    Reform efforts have emphasized the need to support teachers' learning about reform-oriented practices. Educative curriculum materials are one potential vehicle for promoting teacher learning about these practices. Educative curriculum materials include supports that are intended to promote both student "and" teacher learning. However, little is…

  4. Designing and Evaluating the Effectiveness of Physlet-Based Learning Materials in Supporting Conceptual Learning in Secondary School Physics

    ERIC Educational Resources Information Center

    Ülen, Simon; Cagran, Branka; Slavinec, Mitja; Gerlic, Ivan

    2014-01-01

    Many educational researchers have investigated how best to support conceptual learning in science education. In this study, the aim was to design learning materials using Physlets, small computer simulations, and to evaluate the effectiveness of these materials in supporting conceptual learning in secondary school physics. Students were taught in…

  5. GAG-augmented polysaccharide hydrogel: a novel biocompatible and biodegradable material to support chondrogenesis.

    PubMed

    Sechriest, V F; Miao, Y J; Niyibizi, C; Westerhausen-Larson, A; Matthew, H W; Evans, C H; Fu, F H; Suh, J K

    2000-03-15

    The quality of articular cartilage engineered using a cell-polymer construct depends, in part, on the chemical composition of the biomaterial and whether that biomaterial can support the chondrocytic phenotype. Acknowledging the supportive influence of tissue-specific matrix molecules on the chondrocytic phenotype, we have combined chondroitin sulfate-A (CSA) and chitosan, a glycosaminoglycan (GAG) analog, to develop a novel biomaterial to support chondrogenesis. Chitosan is a polycationic repeating monosaccharide of beta-1,4-linked glucosamine monomers with randomly located N-acetyl glucosamine units. Chitosan may be combined with the polyanionic CSA such that ionic crosslinking results in hydrogel formation. Bovine primary articular chondrocytes, when seeded onto a thin layer of CSA-chitosan, form discrete, focal adhesions to the material and maintain many characteristics of the differentiated chondrocytic phenotype, including round morphology, limited mitosis, collagen type II, and proteoglycan production. Our findings suggest CSA-chitosan may be well suited as a carrier material for the transplant of autologous chondrocytes or as a scaffold for the tissue engineering of cartilage-like tissue. PMID:10602087

  6. Ultrafast laser processing of transparent materials supported by in-situ diagnostics

    NASA Astrophysics Data System (ADS)

    Kumkar, M.; Kaiser, M.; Kleiner, J.; Grossmann, D.; Flamm, D.; Bergner, K.; Nolte, S.

    2016-03-01

    For the development of industrial NIR ultrafast laser processing of transparent materials, the absorption inside the bulk material has to be controlled. Applications we aim for are front and rear side ablation, drilling and inscription of modifications for cleaving and selective laser etching of glass and sapphire in sheet geometry. We applied pump probe technology and in situ stress birefringence microscopy for fundamental studies on the influence of energy and duration (100 fs - 20 ps), temporal and spatial spacing, focusing and beam shaping of the laser pulses. Applying pump probe technique we are able to visualize differences of spatio-temporal build up of absorption, self focusing, shock wave generation for standard, multispot and beam shaped focusing. Incubation effects and disturbance of beam propagation due to modifications or ablation can be observed. In-situ imaging of stress birefringence gained insight in transient build up of stress with and without translation. The results achieved so far, demonstrate that transient stress has to be taken into account in scaling the laser machining throughput of brittle materials. Furthermore it points out that transient stress birefringence is a good indicator for accumulation effects, supporting tailored processing strategies. Cutting results achieved for selective laser etching by single pass laser modification exemplifies the benefits of process development supported by in situ diagnostics.

  7. Evaluation of the thermal performance of fire fighter protective clothing with the addition of phase change material

    NASA Astrophysics Data System (ADS)

    McCarthy, Lee K.

    Fire fighters rely on fire fighter protective clothing (FFPC) to provide adequate protection in the various hazardous environments they may encounter during operations. FFPC has seen significant advancement in technology over the past few decades. The addition of phase change material (PCM) to FFPC is a new technology with potential to enhance the thermal protection provided by the FFPC. To explore this technology, data from bench-scale experiments involving FFPC with PCMs are compared with a theoretical finite difference heat transfer model. The results demonstrate an effective method to mathematically model the heat transfer and provide insight into the effectiveness of improving the thermal protection of FFPC. The experiments confirm that the latent heat absorbed during the phase change reduces temperatures that might be experienced at the fire fighter's skin surface, advancing the high temperature performance of FFPC.

  8. On The Development of Additive Construction Technologies for Application to Development of Lunar/Martian Surface Structures Using In-Situ Materials

    NASA Technical Reports Server (NTRS)

    Werkheiser, Niki; Fiske, Michael; Edmunson, Jennifer; Khoshnevis, Behrokh

    2015-01-01

    For long-duration missions on other planetary bodies, the use of in-situ materials will become increasingly critical. As man's presence on these bodies expands, so must the breadth of the structures required to accommodate them including habitats, laboratories, berms, radiation shielding for natural radiation and surface reactors, garages, solar storm shelters, greenhouses, etc. Planetary surface structure manufacturing and assembly technologies that incorporate in-situ resources provide options for autonomous, affordable, pre-positioned environments with radiation shielding features and protection from micrometeorites, exhaust plume debris, and other hazards. This is important because gamma and particle radiation constitute a serious but reducible threat to long-term survival of human beings, electronics, and other materials in space environments. Also, it is anticipated that surface structures will constitute the primary mass element of lunar or Martian launch requirements. The ability to use in-situ materials to construct these structures will provide a benefit in the reduction of up-mass that would otherwise make long-term Moon or Mars structures cost prohibitive. The ability to fabricate structures in situ brings with it the ability to repair these structures, which allows for self-sufficiency necessary for long-duration habitation. Previously, under the auspices of the MSFC In Situ Fabrication and Repair (ISFR) project and more recently, under the joint MSFC/KSC Additive Construction with Mobile Emplacement (ACME) project, the MSFC Surface Structures Group has been developing materials and construction technologies to support future planetary habitats with in situ resources. One such technology, known as Contour Crafting (additive construction), is shown in Figure 1, along with a typical structure fabricated using this technology. This paper will present the results to date of these efforts, including development of novel nozzle concepts for advanced layer

  9. Nb doped TiO2 as a Cathode Catalyst Support Material for Polymer Electrolyte Membrane Fuel Cells

    NASA Astrophysics Data System (ADS)

    O'Toole, Alexander W.

    In order to reduce the emissions of greenhouse gases and reduce dependence on the use of fossil fuels, it is necessary to pursue alternative sources of energy. Transportation is a major contributor to the emission of greenhouse gases due to the use of fossil fuels in the internal combustion engine. To reduce emission of these pollutants into the atmosphere, research is needed to produce alternative solutions for vehicle transportation. Low temperature polymer electrolyte membrane fuel cells are energy conversion devices that provide an alternative to the internal combustion engine, however, they still have obstacles to overcome to achieve large scale implementation. T he following work presents original research with regards to the development of Nb doped TiO2 as a cathode catalyst support material for low temperature polymer electrolyte membrane fuel cells. The development of a new process to synthesize nanoparticles of Nb doped TiO2 with controlled compositions is presented as well as methods to scale up the process and optimize the synthesis for the aforementioned application. In addition to this, comparison of both electrochemical activity and durability with current state of the art Pt on high surface area carbon black (Vulcan XC-72) is investigated. Effects of the strong metal-support interaction on the electrochemical behavior of these materials is also observed and discussed.

  10. Bacterial biodegradation of melamine-contaminated aged soil: influence of different pre-culture media or addition of activation material.

    PubMed

    Hatakeyama, Takashi; Takagi, Kazuhiro

    2016-08-01

    This study aimed to investigate the biodegrading potential of Arthrobacter sp. MCO, Arthrobacter sp. CSP, and Nocardioides sp. ATD6 in melamine-contaminated upland soil (melamine: approx. 10.5 mg/kg dry weight) after 30 days of incubation. The soil sample used in this study had undergone annual treatment of lime nitrogen, which included melamine; it was aged for more than 10 years in field. When R2A broth was used as the pre-culture medium, Arthrobacter sp. MCO could degrade 55 % of melamine after 30 days of incubation, but the other strains could hardly degrade melamine (approximately 25 %). The addition of trimethylglycine (betaine) in soil as an activation material enhanced the degradation rate of melamine by each strain; more than 50 % of melamine was degraded by all strains after 30 days of incubation. In particular, strain MCO could degrade 72 % of melamine. When the strains were pre-cultured in R2A broth containing melamine, the degradation rate of melamine in soil increased remarkably. The highest (72 %) melamine degradation rate was noted when strain MCO was used with betaine addition. PMID:27080407

  11. Chemistry and materials science progress report. Weapons-supporting research and laboratory directed research and development: FY 1995

    SciTech Connect

    1996-04-01

    This report covers different materials and chemistry research projects carried out a Lawrence Livermore National Laboratory during 1995 in support of nuclear weapons programs and other programs. There are 16 papers supporting weapons research and 12 papers supporting laboratory directed research.

  12. Enzyme conversion of lignocellulosic plant materials for resource recovery in a controlled ecological life support system

    NASA Astrophysics Data System (ADS)

    Kohlmann, K. L.; Westgate, P.; Velayudhan, A.; Weil, J.; Sarikaya, A.; Brewer, M. A.; Hendrickson, R. L.; Ladisch, M. R.

    1996-01-01

    A large amount of inedible plant material composed primarily of the carbohydrate materials cellulose, hemicellulose, and lignin is generated as a result of plant growth in a Controlled Ecological Life-Support System (CELSS). Cellulose is a linear homopolymer of glucose, which when properly processed will yield glucose, a valuable sugar because it can be added directly to human diets. Hemicellulose is a heteropolymer of hexoses and pentoses that can be treated to give a sugar mixture that is potentially a valuable fermentable carbon source. Such fermentations yield desirable supplements to the edible products from hydroponically-grown plants such as rapeseed, soybean, cowpea, or rice. Lignin is a three-dimensionally branched aromatic polymer, composed of phenyl propane units, which is susceptible to bioconversion through the growth of the white rot fungus, Pluerotus ostreatus. Processing conditions, that include both a hot water pretreatment and fungal growth and that lead to the facile conversion of plant polysaccharides to glucose, are presented.

  13. Enzyme conversion of lignocellulosic plant materials for resource recovery in a Controlled Ecological Life Support System

    NASA Technical Reports Server (NTRS)

    Kohlmann, K. L.; Westgate, P.; Velayudhan, A.; Weil, J.; Sarikaya, A.; Brewer, M. A.; Hendrickson, R. L.; Ladisch, M. R.; Mitchell, C. A. (Principal Investigator)

    1996-01-01

    A large amount of inedible plant material composed primarily of the carbohydrate materials cellulose, hemicellulose, and lignin is generated as a result of plant growth in a Controlled Ecological Life-Support System (CELSS). Cellulose is a linear homopolymer of glucose, which when properly processed will yield glucose, a valuable sugar because it can be added directly to human diets. Hemicellulose is a heteropolymer of hexoses and pentoses that can be treated to give a sugar mixture that is potentially a valuable fermentable carbon source. Such fermentations yield desirable supplements to the edible products from hydroponically-grown plants such as rapeseed, soybean, cowpea, or rice. Lignin is a three-dimensionally branched aromatic polymer, composed of phenyl propane units, which is susceptible to bioconversion through the growth of the white rot fungus, Pluerotus ostreatus. Processing conditions, that include both a hot water pretreatment and fungal growth and that lead to the facile conversion of plant polysaccharides to glucose, are presented.

  14. High accuracy determination of the thermal properties of supported 2D materials

    PubMed Central

    Judek, Jarosław; Gertych, Arkadiusz P.; Świniarski, Michał; Łapińska, Anna; Dużyńska, Anna; Zdrojek, Mariusz

    2015-01-01

    We present a novel approach for the simultaneous determination of the thermal conductivity κ and the total interface conductance g of supported 2D materials by the enhanced opto-thermal method. We harness the property of the Gaussian laser beam that acts as a heat source, whose size can easily and precisely be controlled. The experimental data for multi-layer graphene and MoS2 flakes are supplemented using numerical simulations of the heat distribution in the Si/SiO2/2D material system. The procedure of κ and g extraction is tested in a statistical approach, demonstrating the high accuracy and repeatability of our method. PMID:26179785

  15. Hurler-Scheie phenotype with parental consanguinity. Report of an additional case supporting the concept of genetic heterogeneity.

    PubMed

    Kaibara, N; Katsuki, I; Hotokebuchi, T; Takagishi, K; Kure, T

    1983-05-01

    The Hurler-Scheie phenotype in a 27-year-old woman of first-cousin parentage is possibly the first reported in the orthopedic literature. The patient exhibited short stature, coarse facies, corneal clouding, multiple stiff joints, normal intelligence, and a long history of bilateral carpal tunnel syndrome, which has not been relieved after operation. The irreversible nerve damage was apparently produced by the marked thickening of the transverse carpal ligament. Surgical findings in this case and data from published reports emphasize the need for early surgical treatment of the associated carpal tunnel syndrome in patients with the Hurler-Scheie phenotype. Parental consanguinity present in this patient is further evidence supporting the concept of a third mutant allele different from both the Hurler gene and the Scheie gene. PMID:6404579

  16. Piloting the Post-Entry Language Assessment: Outcomes from a New System for Supporting Research Candidates with English as an Additional Language

    ERIC Educational Resources Information Center

    Tynan, Liz; Johns, Kellie

    2015-01-01

    The Post-Entry Language Assessment (PELA) was introduced by the James Cook University Graduate Research School in February 2013 as a pilot programme to test a new mechanism for initiating post-enrolment support for research degree candidates who have English as an additional language. Language ability does not necessarily, on its own, predict…

  17. Gene expression suggests conserved aspects of Hox gene regulation in arthropods and provides additional support for monophyletic Myriapoda.

    PubMed

    Janssen, Ralf; Budd, Graham E

    2010-01-01

    Antisense transcripts of Ultrabithorax (aUbx) in the millipede Glomeris and the centipede Lithobius are expressed in patterns complementary to that of the Ubx sense transcripts. A similar complementary expression pattern has been described for non-coding RNAs (ncRNAs) of the bithoraxoid (bxd) locus in Drosophila, in which the transcription of bxd ncRNAs represses Ubx via transcriptional interference. We discuss our findings in the context of possibly conserved mechanisms of Ubx regulation in myriapods and the fly.Bicistronic transcription of Ubx and Antennapedia (Antp) has been reported previously for a myriapod and a number of crustaceans. In this paper, we show that Ubx/Antp bicistronic transcripts also occur in Glomeris and an onychophoran, suggesting further conserved mechanisms of Hox gene regulation in arthropods.Myriapod monophyly is supported by the expression of aUbx in all investigated myriapods, whereas in other arthropod classes, including the Onychophora, aUbx is not expressed. Of the two splice variants of Ubx/Antp only one could be isolated from myriapods, representing a possible further synapomorphy of the Myriapoda. PMID:20849647

  18. Beta zeolite supported sol-gel TiO2 materials for gas phase photocatalytic applications.

    PubMed

    Lafjah, Mama; Djafri, Fatiha; Bengueddach, Abdelkader; Keller, Nicolas; Keller, Valérie

    2011-02-28

    Beta zeolite supported sol-gel TiO(2) photocatalytic materials were prepared according to a sol-gel route in which high specific surface area Beta zeolite powder was incorporated into the titanium isopropoxide sol during the course of the sol-gel process. This led to an intimate contact between the zeolite surface and the TiO(2) precursors, and resulted in the anchorage of large amounts of dispersed TiO(2) nanoparticles and in the stabilization of TiO(2) in its anatase form, even for high TiO(2) wt. contents and high calcination temperatures. Taking the UV-A photocatalytic oxidation of methanol as gas phase target reaction, high methanol conversions were obtained on the Beta zeolite supported TiO(2) photocatalysts when compared to bulk sol-gel TiO(2), despite lower amounts of TiO(2) within the photoactive materials. The methanol conversion was optimum for about 40 wt.% TiO(2) loading and calcination temperatures of 500-600°C. PMID:21177024

  19. Testing of organic waste surrogate materials in support of the Hanford organic tank program. Final report

    SciTech Connect

    Turner, D.A.; Miron, Y.

    1994-01-01

    To address safety issues regarding effective waste management efforts of underground organic waste storage tanks at the Hanford Site, the Bureau of Mines conducted a series of tests, at the request of the Westinghouse Hanford company. In this battery of tests, the thermal and explosive characteristics of surrogate materials, chosen by Hanford, were determined. The surrogate materials were mixtures of inorganic and organic sodium salts, representing fuels and oxidants. The oxidants were sodium nitrate and sodium nitrite. The fuels were sodium salts of oxalate, citrate and ethylenediamine tetraacetic acid (EDTA). Polyethylene powder was also used as a fuel with the oxidant(s). Sodium aluminate was used as a diluent. In addition, a sample of FeCN, supplied by Hanford was also investigated.

  20. Material report in support to RCC-MRX code 2010 stainless steel parts and products

    SciTech Connect

    Ancelet, Olivier; Lebarbe, Thierry; Dubiez-Le Goff, Sophie; Bonne, Dominique; Gelineau, Odile

    2012-07-01

    This paper presents the Material Report dedicated to stainless steels parts and products issued by AFCEN (Association Francaise pour les regles de Conception et de Construction des Materiels des Chaudieres Electro-Nucleaires) in support to RCC-MRx 2010 Code. The RCC-MRx Code is the result of the merger of the RCC-MX 2008, developed in the context of the research reactor Jules Horowitz Reactor project, in the RCC-MR 2007, which set up rules applicable to the design of components operating at high temperature and to the Vacuum Vessel of ITER (a presentation of RCC-MRx 2010 Code is the subject of another paper proposed in this Congress; it explains in particular the status of this Code). This Material Report is part of a set of Criteria of RCC-MRx (this set of Criteria is under construction). The Criteria aim at explaining the design and construction rules of the Code. They cover analyses rules as well as part procurement, welding, methods of tests and examination and fabrication rules. The Material Report particularly provides justifications and explanations on requirements and features dealing with parts and products proposed in the Code. The Material Report contains the following information: Introduction of the grade(s): codes and standards and Reference Procurement Specifications covering parts and products, applications and experience gained, - Physical properties, - Mechanical properties used for design calculations (base metal and welds): basic mechanical properties, creep mechanical properties, irradiated mechanical properties, - Fabrication: experience gained, metallurgy, - Welding: weldability, experience gained during welding and repair procedure qualifications, - Non-destructive examination, - In-service behaviour. In the article, examples of data supplied in the Material Report dedicated to stainless steels will be exposed. (authors)

  1. Fish composition and species richness in eastern South American coastal lagoons: additional support for the freshwater ecoregions of the world.

    PubMed

    Petry, A C; Guimarães, T F R; Vasconcellos, F M; Hartz, S M; Becker, F G; Rosa, R S; Goyenola, G; Caramaschi, E P; Díaz de Astarloa, J M; Sarmento-Soares, L M; Vieira, J P; Garcia, A M; Teixeira de Mello, F; de Melo, F A G; Meerhoff, M; Attayde, J L; Menezes, R F; Mazzeo, N; Di Dario, F

    2016-07-01

    The relationships between fish composition, connectivity and morphometry of 103 lagoons in nine freshwater ecoregions (FEOW) between 2·83° S and 37·64° S were evaluated in order to detect possible congruence between the gradient of species richness and similarities of assemblage composition. Most lagoons included in the study were <2 km(2) , with a maximum of 3975 km(2) in surface area. Combined surface area of all lagoons included in the study was 5411 km(2) . Number of species varied locally from one to 76. A multiple regression revealed that latitude, attributes of morphometry and connectivity, and sampling effort explained a large amount of variability in species richness. Lagoon area was a good predictor of species richness except in low latitude ecoregions, where lagoons are typically small-sized and not affected by marine immigrants, and where non-native fish species accounted for a significant portion of species richness. Relationships between species and area in small-sized lagoons (<2 km(2) ) is highly similar to the expected number in each ecoregion, with systems located between 18·27° S and 30·15° S attaining higher levels of species richness. Similarities in species composition within the primary, secondary and peripheral or marine divisions revealed strong continental biogeographic patterns only for species less tolerant or intolerant to salinity. Further support for the FEOW scheme in the eastern border of South America is therefore provided, and now includes ecotonal systems inhabited simultaneously by freshwater and marine species of fishes. PMID:27401481

  2. Systematic Dissection of Coding Exons at Single Nucleotide Resolution Supports an Additional Role in Cell-Specific Transcriptional Regulation

    PubMed Central

    Kim, Mee J.; Findlay, Gregory M.; Martin, Beth; Zhao, Jingjing; Bell, Robert J. A.; Smith, Robin P.; Ku, Angel A.; Shendure, Jay; Ahituv, Nadav

    2014-01-01

    In addition to their protein coding function, exons can also serve as transcriptional enhancers. Mutations in these exonic-enhancers (eExons) could alter both protein function and transcription. However, the functional consequence of eExon mutations is not well known. Here, using massively parallel reporter assays, we dissect the enhancer activity of three liver eExons (SORL1 exon 17, TRAF3IP2 exon 2, PPARG exon 6) at single nucleotide resolution in the mouse liver. We find that both synonymous and non-synonymous mutations have similar effects on enhancer activity and many of the deleterious mutation clusters overlap known liver-associated transcription factor binding sites. Carrying a similar massively parallel reporter assay in HeLa cells with these three eExons found differences in their mutation profiles compared to the liver, suggesting that enhancers could have distinct operating profiles in different tissues. Our results demonstrate that eExon mutations could lead to multiple phenotypes by disrupting both the protein sequence and enhancer activity and that enhancers can have distinct mutation profiles in different cell types. PMID:25340400

  3. PREPARATION AND CHARACTERIZATION OF NANOSTRUCTURED GRANULAR SUPPORT PARTICLES AND CATALYTIC MATERIALS

    SciTech Connect

    Zhenchen Zhong

    2002-01-15

    We have set up successfully two experimental systems during the past time of the project. The first system is sol-gel chemical method for preparing {gamma}-Al{sub 2}O{sub 3}, SiO{sub 2}, Cr{sub 2}O{sub 3} granular support particles. The second system is the laser-induced solution deposition (LISD) technique for nanoparticle catalysts containing Fe/Cu, and Co/Cu on the granular support. We have successfully deposited {gamma}-Al{sub 2}O{sub 3}, SiO{sub 2}, Cr{sub 2}O{sub 3} granular support particles by sol-gel method and Co and CoO nanoparticles by LISD novel fabrication technique. The characterization methods we have used include scanning electron microscope (SEM), high-resolution transmission electron microscope (HRTEM) and X-Ray diffraction (XRD). The research toward to the proposed direction is in good progress. We have given three presentations in national and local materials meetings and have submitted another two papers in another two key national meetings in nanotechnology and American Physical Annual March Meeting 2002. A couple of papers are in preparation.

  4. Assessment of rock wool as support material for on-site sanitation: hydrodynamic and mechanical characterization.

    PubMed

    Wanko, Adrien; Laurent, Julien; Bois, Paul; Mosé, Robert; Wagner-Kocher, Christiane; Bahlouli, Nadia; Tiffay, Serge; Braun, Bouke; Provo kluit, Pieter-Willem

    2016-01-01

    This study proposes mechanical and hydrodynamic characterization of rock wool used as support material in compact filter. A double-pronged approach, based on experimental simulation of various physical states of this material was done. First of all a scanning electron microscopy observation allows to highlight the fibrous network structure, the fibres sizing distribution and the atomic absorption spectrum. The material was essentially lacunar with 97 ± 2% of void space. Static compression tests on variably saturated rock wool samples provide the fact that the strain/stress behaviours depend on both the sample conditioning and the saturation level. Results showed that water exerts plastifying effect on mechanical behaviour of rock wool. The load-displacement curves and drainage evolution under different water saturation levels allowed exhibiting hydraulic retention capacities under stress. Finally, several tracer experiments on rock wool column considering continuous and batch feeding flow regime allowed: (i) to determine the flow model for each test case and the implications for water dynamic in rock wool medium, (ii) to assess the rock wool double porosity and discuss its advantages for wastewater treatment, (iii) to analyse the benefits effect for water treatment when the high level of rock wool hydric retention was associated with the plug-flow effect, and (iv) to discuss the practical contributions for compact filter conception and management. PMID:26165374

  5. Materials derived from synthetic organo-clay complexes as novel hydrodesulfurization catalyst supports.

    SciTech Connect

    Carrado, K. A.; Marshall, C. L.; Brenner, J. R.; Song, K.; Chemistry

    1998-01-01

    A series of mesoporous synthetic organo-clay complexes has been prepared by hydrothermal crystallization of gels containing silica, magnesium hydroxide, lithium fluoride, and an organic of choice, followed by calcination to remove the organics. The organic serves to impart structural order to the inorganic network that does not disappear upon its removal. The choice of organic modifier can be used to control the pore structure of the resulting mesoporous materials. Pore size distributions appear in some cases to be related to the type of polymer packing upon clay formation in situ. These materials are being explored as Co Mo hydrodesulfurization (HDS) catalyst supports. Preliminary HDS results show performance commensurate with commercial catalysis for the mesoporous materials when a model heavy oil feed is used (1 wt% S as dibenzothiophene in hexadecane). Temperature programmed reduction experiments of used catalysts suggest a relationship between HDS activity and ease of reduction of the CoMo/clay catalysts. Reactivity of the CoMo clay also correlates with the percentage of mesopore volume remaining after reaction. Losses in mesopore volume are largely recouped by recalcination, suggesting that reversible coke is formed inside the pore structure of clays faster than inside conventional alumina.

  6. Notable improvement of capacitive performance of highly nanoporous carbon materials simply by a redox additive electrolyte of p-nitroaniline

    NASA Astrophysics Data System (ADS)

    Zhu, Yan Qi; Zhang, Lei; Chen, Xiang Ying; Xiao, Zheng Hui; Zhang, Zhong Jie

    2015-12-01

    Highly nanoporous carbon materials have been produced by a synchronous carbonization/graphitization process, using magnesium citrate serves as the carbon source and nickel nitrate as graphitization catalyst. The carbonization temperature plays a crucial role in determining the porosity and graphitization. The lower temperature favors for the formation of larger porosity, whilst higher temperature for better crystallinity. Resultantly, a high BET surface area of 2587.13 m2 g-1 and large total pore volume of 4.64 cm3 g-1 appear, the case of C-800 sample, thereby resulting in a large specific capacitance of 305.3 F g-1 at 1 A g-1 from the contribution of electric double layer capacitances. More importantly, we demonstrate a novel redox active additive of p-nitroaniline (PNA) into the 6 mol L-1 KOH electrolyte to largely improve the capacitance by the quick self-discharge redox reaction of H+/e-. The C-800-2 sample with the PNA concentration of 2 mmol delivers largely improved capacitance of 502.1 F g-1 at 1 A g-1, which is almost 1.65 fold increase. Apparently, the present PNA is commercially available, and highly effective for elevating the specific capacitance and might be implemented for the wide supercapacitor application.

  7. Design and analysis of a piezoelectric material based touch screen with additional pressure and its acceleration measurement functions

    NASA Astrophysics Data System (ADS)

    Chu, Xiang-Cheng; Liu, Jia-Yi; Gao, Ren-Long; Chang, Jie; Li, Long-Tu

    2013-12-01

    Touch screens are becoming more and more prevalent in everyday environments due to their convenience and humanized operation. In this paper, a piezoelectric material based touch screen is developed and investigated. Piezoelectric ceramics arrayed under the touch panel at the edges or corners are used as tactile sensors to measure the touch positioning point similarly to conventional touch screens. However, additional touch pressure and its acceleration performance can also be obtained to obtain a higher-level human-machine interface. The piezoelectric ceramics can also be added to a traditional touch screen structure, or they can be used independently to construct a novel touch screen with a high light transmittance approach to a transparent glass. The piezoelectric ceramics were processed from PZT piezoelectric ceramic powder into a round or rectangular shape. According to the varied touch position and physical press strength of a finger, or even a gloved hand or fingernail, the piezoelectric tactile sensors will have different output voltage responses. By calculating the ratio of different piezoelectric tactile sensors’ responses and summing up all piezoelectric tactile sensors’ output voltages, the touch point position, touch pressure and touch force acceleration can be detected. A prototype of such a touch screen is manufactured and its position accuracy, touch pressure and response speed are measured in detail. The experimental results show that the prototype has many advantages such as high light transmittance, low energy cost and high durability.

  8. Analytical modeling in support of the development of fiber reinforced ceramic composite materials for re-heater burners

    SciTech Connect

    Kibler, J.J.; DiPietro, S.G.

    1995-10-01

    Development of Continuous Fiber reinforced Ceramic Composite (CFCC) materials is a process of identifying components which will benefit from CFCC properties, and defining appropriate composite constructions which will provide materials which will meet the structural and thermal requirements of the application. Materials Sciences Corporation (MSC) has been providing analytical support to Textron Specialty Materials in the development of re-heated tubes for metal reheating furnaces. As part of this support, a study has been made of the sensitivity of composite properties to fiber orientation as well as a number of matrix properties which control the stress-strain behavior of the composite.

  9. A new supporting material for fascia grafting during myringoplasty: polyglycolic acid sheets.

    PubMed

    Yamanaka, Toshiaki; Sawai, Yachiyo; Hosoi, Hiroshi

    2013-08-01

    We used polyglycolic acid (PGA) sheets, a reinforcing material, as supporting devices for securing the fascia instead of fibrin glue or Gelfoam in patients with tympanic membrane (TM) perforations. PGA sheets were placed lateral to the fascia graft attached using the underlay grafting technique in 6 patients. In each case, the PGA sheet had been macerated and had merged into the fascia within 1 week of the procedure. At 2 to 3 postoperative weeks, parts of the sheet had become dehydrated and detached from the fascia, revealing a new epithelialized TM underneath. Eventually, the sheet had disappeared, and complete epithelialization had been achieved at 4 to 5 postoperative weeks, resulting in the successful closure of the perforation. The repair of TM remained stable throughout the follow-up period of at least 6 months in all patients. These results suggest that PGA sheets have the potential to secure fascia grafts and to guide the epithelialization of new tissue. PMID:23744836

  10. Alumina supported carbon composite material with exceptionally high defluoridation property from eggshell waste.

    PubMed

    Lunge, Sneha; Thakre, Dilip; Kamble, Sanjay; Labhsetwar, Nitin; Rayalu, Sadhana

    2012-10-30

    A new alumina supported carbon composite material called "Eggshell Composite" (EC) was synthesized from eggshell waste as calcium source for selective fluoride adsorption from water. The effect of various synthesis parameters like eggshell (ES): Eggshell membrane (ESM) ratio, aluminium loading, mixing time and calcinations temperature to optimize the synthesis conditions for selective fluoride removal has been studied. It was observed that the synthesis parameters have significant influence on development of EC and in turn on fluoride removal capacity. EC synthesized was characterized for elemental composition, morphology, functionality and textural properties. Results showed that EC obtained from eggshell modified with alumina precursor is more selective and efficient for fluoride removal. Langmuir and Freundlich isotherm were used to obtain ultimate fluoride removal capacity. The calcium and alumina species in EC shows synergistic effect in fluoride adsorption process. Fluoride sorption studies were carried out in synthetic, groundwater and wastewater. EC proved to be a potential, indigenous and economic adsorbent for fluoride removal. PMID:22944591

  11. Material balance and diets in biological life support systems: a relationship with a coefficient of closure

    NASA Astrophysics Data System (ADS)

    Manukovsky, N. S.; Kovalev, V. S.; Somova, L. A.

    Biological life support systems (BLSS) of various coefficients of closure were considered The basic coefficient of closure was accepted equal to 66%. With increase in coefficient of closure food requirements for the greater degree should be satisfied due to the manufacture of food inside the BLSS. In this connection food values were estimated both in the basic variant, and in those with increased coefficients of closure. Metabolic massflow rates were estimated at the input and output of the BLSS as well as inside it. Human massflow rates were submitted on the basis of characteristics of the 'reference man'. Stoichiometric synthesis - degradation equations of organic substances in the BLSS were obtained. A problem of nitrogen imbalance was shown to occur under an incomplete BLSS closure. To compensate losses of nitrogen with urine and feces, food and nitrogen-containing additives should be introduced into the BLSS.

  12. Supported Lipid Bilayers for the Generation of Dynamic Cell-Material Interfaces.

    PubMed

    van Weerd, Jasper; Karperien, Marcel; Jonkheijm, Pascal

    2015-12-30

    Supported lipid bilayers (SLB) offer unique possibilities for studying cellular membranes and have been used as a synthetic architecture to interact with cells. Here, the state-of-the-art in SLB-based technology is presented. The fabrication, analysis, characteristics and modification of SLBs are described in great detail. Numerous strategies to form SLBs on different substrates, and the means to patteren them, are described. The use of SLBs as model membranes for the study of membrane organization and membrane processes in vitro is highlighted. In addition, the use of SLBs as a substratum for cell analysis is presented, with discrimination between cell-cell and cell-extracellular matrix (ECM) mimicry. The study is concluded with a discussion of the potential for in vivo applications of SLBs. PMID:26573989

  13. The Astronomy Workshop: Computer Assisted Learning Tools with Instructor Support Materials and Student Activities

    NASA Astrophysics Data System (ADS)

    Deming, Grace; Hamilton, D.; Hayes-Gehrke, M.

    2006-12-01

    The Astronomy Workshop (http://janus.astro.umd.edu) is a collection of interactive World Wide Web tools that were developed under the direction of Doug Hamilton for use in undergraduate classes, as supplementary materials appropriate for grades 9-12, and by the general public. The philosophy of the website is to foster student and public interest in astronomy by capitalizing on their fascination with computers and the internet. Many of the tools were developed by graduate and undergraduate students at UMD. This website contains over 20 tools on topics including scientific notation, giant impacts, extrasolar planets, astronomical distances, planets, moons, comets, and asteroids. Educators around the country at universities, colleges, and secondary schools have used the Astronomy Workshop’s tools and activities as homework assignments, in-class demos, or extra credit. Since 2005, Grace Deming has assessed several of the Astronomy Workshop’s tools for clarity and effectiveness by interviewing students as they used tools on the website. Based on these interviews, Deming wrote student activities and instructor support materials and posted them to the website. Over the next three years, we will continue to interview students, develop web materials, and field-test activities. We are targeting classes in introductory undergraduate astronomy courses and grades 11-12 for our Spring 2007 field tests. We are interested in hearing your ideas on how we can make the Astronomy Workshop more appealing to educators, museum directors, specialty programs, and professors. This research is funded by NASA EPO grants NNG04GM18G and NNG06GGF99G.

  14. 18 CFR 347.1 - Material to support request for newly established or changed property account depreciation studies.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 18 Conservation of Power and Water Resources 1 2013-04-01 2013-04-01 false Material to support request for newly established or changed property account depreciation studies. 347.1 Section 347.1... REGULATIONS UNDER THE INTERSTATE COMMERCE ACT OIL PIPELINE DEPRECIATION STUDIES § 347.1 Material to...

  15. Method to develop data supporting consequence analyses of transporting nuclear materials in the United States

    SciTech Connect

    Reese, R.T.; Sandoval, R.P.

    1980-01-01

    The Transportation System Safety Evaluation (TSSE) program at Sandia National Laboratories' Transportation Technology Center was initiated to provide the necessary information on source terms for nuclear materials subjected to extreme environments. The techniques for derivation of source terms for the fuel alone has been described as well as the outline for package response. An additional facet of this problem is the development of analytical methods to describe the transport of the released radionuclides from the fuel rods to possible release points. This work is also covered in the TSSE program. Not all the work required will be performed or funded by Sandia; rather existing work will be sought out and ongoing work will be utilized in an attempt to unify the presentation of data and thus increase its usefulness.

  16. The Astronomy Workshop: Instructor Support Materials and Student Activities for the Scientific Notation Tool

    NASA Astrophysics Data System (ADS)

    Deming, Grace; Hayes-Gehrke, M.; Hamilton, D.

    2008-05-01

    The Astronomy Workshop (http://janus.astro.umd.edu) is a collection of interactive World Wide Web tools that were developed under the direction of Doug Hamilton for use in undergraduate classes and by the general public. The philosophy of the site is to foster student interest in astronomy by exploiting their fascination with computers and the internet. We have upgraded the "Scientific Notation" tool in response to faculty feedback and input from student interviews. In addition to providing students practice in changing decimal numbers into scientific notation, they may now practice multiplication and division with numbers in scientific notation. We have added instructor materials and student quizzes to enhance the instructional use of the scientific notation web tools. This research was sponsored by NASA EPO grant NNG06GGF99G.

  17. IWRM decision support with material flow analysis: consideration of urban system input.

    PubMed

    Terekhanova, T A; Helm, B; Traenckner, J; Krebs, P

    2012-01-01

    A review of material flow analysis (MFA) tools, comparison of case studies and analysis of approximately 20 MFA tools (static, semi-empirical models) are performed. The evaluation of the quantification procedures revealed several deficits in the approaches. The following principal complications for a reliable quantification of inputs from the urban water system are identified: (1) frequently insufficient data for urban system model validation (e.g. combined sewer overflow (CSO) discharges); (2) the necessity for additionally quantifying diffuse sources in order to verify modelling results at basin scale, where both input pathways occur, and (3) the contradictions arising when describing the highly dynamic urban system with the help of static MFA models. However, a wise selection of appropriate calculation procedures with regard to the concrete systems characteristics and available data can minimize the model deviations significantly. Criteria and suggestions for designing adapted quantification procedures are given. PMID:23032775

  18. Recycling cycle of materials applied to acrylonitrile-butadiene-styrene/policarbonate blends with styrene-butadiene-styrene copolymer addition

    NASA Astrophysics Data System (ADS)

    Cândido, L. H. A.; Ferreira, D. B.; Júnior, W. Kindlein; Demori, R.; Mauler, R. S.

    2014-05-01

    The scope of this research is the recycling of polymers from mobile phones hulls discarded and the performance evaluation when they are submitted to the Recycling Cycle of Materials (RCM). The studied material was the ABS/PC blend in a 70/30 proportion. Different compositions were evaluated adding virgin material, recycled material and using the copolymer SBS as impact modifier. In order to evaluate the properties of material's composition, the samples were characterized by TGA, FTIR, SEM, IZOD impact strength and tensile strength tests. At the first stage, the presented results suggest the composition containing 25% of recycled material and 5% of SBS combines good mechanical performance to the higher content of recycled material and lower content of impact modifier providing major benefits to recycling plans. Five cycles (RCM) were applied in the second stage; they evidenced a decrease trend considering the impact strength. At first and second cycle the impact strength was higher than reference material (ABS/PC blend) and from the fourth cycle it was lower. The superiority impact strength in the first and second cycles can be attributed to impact modifier effect. The thermal tests and the spectrometry didn't show the presence of degradation process in the material and the TGA curves demonstrated the process stability. The impact surface of each sample was observed at SEM. The microstructures are not homogeneous presenting voids and lamellar appearance, although the outer surface presents no defects, demonstrating good moldability. The present work aims to assess the life cycle of the material from the successive recycling processes.

  19. Effect of an organic additive on the rheology of an aluminous cement paste and consequences on the densification of the hardened material

    NASA Astrophysics Data System (ADS)

    El Hafiane, Y.; Smith, A.; Bonnet, J. P.; Tanouti, B.

    2005-03-01

    The material used in the present work is Secar 71 (Lafarge) mixed with water containing an organic additive (acetic acid noted HOAc). The rheological behavior of these pastes is studied. The best dispersion is obtained when the mass content of the additive with respect to the cement is equal to 0.5%. The microstructural characterizations of samples aged 4 days at 20° C and 95 % relative humidity reveal a significant increase in the density and a reduction in porosity for very small percentages of additive. The remarkable effect of the acetic acid on the microstructure of hardened material is correlated with its good dispersing action.

  20. Improving the damping ability by the addition of Nano SiO2 to the concrete materials

    NASA Astrophysics Data System (ADS)

    Zou, Dujian; Liu, Tiejun; Teng, Jun

    2009-07-01

    Damping in structures is commonly provided by viscoelastic nonstructural materials. Due to the large volume of structural materials in a structure, the contribution of a structural material to damping can be substantial. In this paper, the experimental investigation on damping ability of concrete materials and its members with Nana SiO2 was carried out by the method of 3-point bending beam damping measurement and cantilever beam free vibration respectively. The microstructure of concrete mix with Nano SiO2 was observed by XRD and SEM, then damping mechanism was discussed. The experimental results show that the damping reinforced effect achieved best with the 4% mixture ratio of Nana SiO2, but the optimal adulteration quantity of Nano SiO2 was 3% of cement weight by the comprehensive consideration of cost, workability, strength and dynamic properties. Nano materials as a mixture increase interfaces, and the non-uniform stress distribution under external force improves frictional damping energy consumption ability of concrete. The experimental results on the damping ratio and the loss tangent of the concrete materials with Nano materials are consistent.

  1. Materialism.

    PubMed

    Melnyk, Andrew

    2012-05-01

    Materialism is nearly universally assumed by cognitive scientists. Intuitively, materialism says that a person's mental states are nothing over and above his or her material states, while dualism denies this. Philosophers have introduced concepts (e.g., realization and supervenience) to assist in formulating the theses of materialism and dualism with more precision, and distinguished among importantly different versions of each view (e.g., eliminative materialism, substance dualism, and emergentism). They have also clarified the logic of arguments that use empirical findings to support materialism. Finally, they have devised various objections to materialism, objections that therefore serve also as arguments for dualism. These objections typically center around two features of mental states that materialism has had trouble in accommodating. The first feature is intentionality, the property of representing, or being about, objects, properties, and states of affairs external to the mental states. The second feature is phenomenal consciousness, the property possessed by many mental states of there being something it is like for the subject of the mental state to be in that mental state. WIREs Cogn Sci 2012, 3:281-292. doi: 10.1002/wcs.1174 For further resources related to this article, please visit the WIREs website. PMID:26301463

  2. [Application of support vector machine approach in studying nephron toxicity of Chinese medicinal materials].

    PubMed

    Zhang, Jing-fang; Jiang, Lu-di; Zhang, Yan-ling

    2015-03-01

    On the basis of web databases, 111 compounds with nephrotoxicity and 90 compounds without nephrotoxicity were collected as data set of nephrotoxicity discrimination model, 39 compounds with tubular necrosis and 39 compounds without tubular necrosis were collected as data set of tubular necrosis discrimination model. The 6 122 molecular descriptors, including physicochemical, charge distribution and geometrical descriptors were calculated to characterize the molecular structure of the above-mentioned compounds. CfsSubsetEval valuation method and BestFirst-D1-N5 searching method were used to select molecular descriptors. Two models with high accuracy were built based on the support vector machine (SVM) approach, respectively. Accuracy, sensitivity, specificity and matthew's correlation coefficient of the two models were all above 70%. By using 22 nephrotoxicity compounds of Chinese medicine, the nephrotoxicity discrimination model was further verified with an accuracy of 72.73%. Using the tubular necrosis discrimination model, 10 potential compounds which can cause tubular necrosis were screened from the positive results of nephrotoxicity discrimination model, 6 of them have been verified by literatures. The results demonstrated that the discrimination models can be applied to screen nephrotoxic compounds from Chinese medicinal materials, and they also offer a new research idea for the further studies on the mechanism of nephrotoxicity. PMID:26226759

  3. Online Condition Monitoring of Bearings to Support Total Productive Maintenance in the Packaging Materials Industry.

    PubMed

    Gligorijevic, Jovan; Gajic, Dragoljub; Brkovic, Aleksandar; Savic-Gajic, Ivana; Georgieva, Olga; Di Gennaro, Stefano

    2016-01-01

    The packaging materials industry has already recognized the importance of Total Productive Maintenance as a system of proactive techniques for improving equipment reliability. Bearing faults, which often occur gradually, represent one of the foremost causes of failures in the industry. Therefore, detection of their faults in an early stage is quite important to assure reliable and efficient operation. We present a new automated technique for early fault detection and diagnosis in rolling-element bearings based on vibration signal analysis. Following the wavelet decomposition of vibration signals into a few sub-bands of interest, the standard deviation of obtained wavelet coefficients is extracted as a representative feature. Then, the feature space dimension is optimally reduced to two using scatter matrices. In the reduced two-dimensional feature space the fault detection and diagnosis is carried out by quadratic classifiers. Accuracy of the technique has been tested on four classes of the recorded vibrations signals, i.e., normal, with the fault of inner race, outer race, and ball operation. The overall accuracy of 98.9% has been achieved. The new technique can be used to support maintenance decision-making processes and, thus, to increase reliability and efficiency in the industry by preventing unexpected faulty operation of bearings. PMID:26938541

  4. Role of core support material in veneer failure of brittle layer structures.

    PubMed

    Hermann, Ilja; Bhowmick, Sanjit; Lawn, Brian R

    2007-07-01

    A study is made of veneer failure by cracking in all-ceramic crown-like layer structures. Model trilayers consisting of a 1 mm thick external glass layer (veneer) joined to a 0.5 mm thick inner stiff and hard ceramic support layer (core) by epoxy bonding or by fusion are fabricated for testing. The resulting bilayers are then glued to a thick compliant polycarbonate slab to simulate a dentin base. The specimens are subjected to cyclic contact (occlusal) loading with spherical indenters in an aqueous environment. Video cameras are used to record the fracture evolution in the transparent glass layer in situ during testing. The dominant failure mode is cone cracking in the glass veneer by traditional outer (Hertzian) cone cracks at higher contact loads and by inner (hydraulically pumped) cone cracks at lower loads. Failure is deemed to occur when one of these cracks reaches the veneer/core interface. The advantages and disadvantages of the alumina and zirconia core materials are discussed in terms of mechanical properties-strength and toughness, as well as stiffness. Consideration is also given to the roles of interface strength and residual thermal expansion mismatch stresses in relation to the different joining methods. PMID:17078086

  5. Online Condition Monitoring of Bearings to Support Total Productive Maintenance in the Packaging Materials Industry

    PubMed Central

    Gligorijevic, Jovan; Gajic, Dragoljub; Brkovic, Aleksandar; Savic-Gajic, Ivana; Georgieva, Olga; Di Gennaro, Stefano

    2016-01-01

    The packaging materials industry has already recognized the importance of Total Productive Maintenance as a system of proactive techniques for improving equipment reliability. Bearing faults, which often occur gradually, represent one of the foremost causes of failures in the industry. Therefore, detection of their faults in an early stage is quite important to assure reliable and efficient operation. We present a new automated technique for early fault detection and diagnosis in rolling-element bearings based on vibration signal analysis. Following the wavelet decomposition of vibration signals into a few sub-bands of interest, the standard deviation of obtained wavelet coefficients is extracted as a representative feature. Then, the feature space dimension is optimally reduced to two using scatter matrices. In the reduced two-dimensional feature space the fault detection and diagnosis is carried out by quadratic classifiers. Accuracy of the technique has been tested on four classes of the recorded vibrations signals, i.e., normal, with the fault of inner race, outer race, and ball operation. The overall accuracy of 98.9% has been achieved. The new technique can be used to support maintenance decision-making processes and, thus, to increase reliability and efficiency in the industry by preventing unexpected faulty operation of bearings. PMID:26938541

  6. A Strategy to Support Design Processes for Fibre Reinforced Thermoset Composite Materials

    NASA Astrophysics Data System (ADS)

    Gascons, Marc; Blanco, Norbert; Mayugo, Joan Andreu; Matthys, Koen

    2012-06-01

    The concept stage in the design for a new composite part is a time when several fundamental decisions must be taken and a considerable amount of the budget is spent. Specialized commercial software packages can be used to support the decision making process in particular aspects of the project (e.g. material selection, numerical analysis, cost prediction,...). However, a complete and integrated virtual environment that covers all the steps in the process is not yet available for the composite design and manufacturing industry. This paper does not target the creation of such an overarching virtual tool, but instead presents a strategy that handles the information generated in each step of the design process, independently of the commercial packages used. Having identified a suitable design parameter shared in common with all design steps, the proposed strategy is able to evaluate the effects of design variations throughout all the design steps in parallel. A case study illustrating the strategy on an industrial part is presented.

  7. Using supported Au nanoparticles as starting material for preparing uniform Au/Pd bimetallic catalysts

    SciTech Connect

    Villa, Alberto; Prati, Laura; Su, Dangshen; Wang, Di; Veith, Gabriel M

    2010-01-01

    One of the best methods for producing bulk homogeneous (composition) supported bimetallic AuPd clusters involves the immobilization of a protected Au seed followed by the addition of Pd. This paper investigates the importance of this gold seed in controlling the resulting bimetallic AuPd clusters structures, sizes and catalytic activities by investigating three different gold seeds. Uniform Au-Pd alloy were obtained when a steric/electrostatic protecting group, poly(vinyl alcohol) (PVA), was used to form the gold clusters on activated carbon (AC). In contrast Au/AC precursors prepared using Au nanoparticles with only electrostatic stabilization (tetrakis(hydroxypropyl)phosphonium chloride (THPC)), or no stabilization (magnetron sputtering) produced inhomogeneous alloys and segregation of the gold and palladium. The uniform alloyed catalyst (Pd{at}Au{sub PVA}/AC) is the most active and selective catalyst, while the inhomogenous catalysts are less active and selective. Further study of the PVA protected Au clusters revealed that the amount of PVA used is also critical for the preparation of uniform alloyed catalyst, their stability, and their catalytic activity.

  8. Supporting Technology for Chain of Custody of Nuclear Weapons and Materials throughout the Dismantlement and Disposition Processes

    SciTech Connect

    Bunch, Kyle J.; Jones, Anthony M.; Ramuhalli, Pradeep; Benz, Jacob M.; Denlinger, Laura Schmidt

    2014-05-04

    The ratification and ongoing implementation of the New START Treaty have been widely regarded as noteworthy global security achievements for both the Obama Administration and the Putin (formerly Medvedev) regime. But deeper cuts that move beyond the United States and Russia to engage the P-5 and other nuclear weapons possessor states are envisioned under future arms control regimes, and are indeed required for the P-5 in accordance with their Article VI disarmament obligations in the Nuclear Non-Proliferation Treaty. Future verification needs will include monitoring the cessation of production of new fissile material for weapons, monitoring storage of warhead components and fissile materials and verifying dismantlement of warheads, pits, secondary stages, and other materials. A fundamental challenge to implementing a nuclear disarmament regime is the ability to thwart unauthorized material diversion throughout the dismantlement and disposition process through strong chain of custody implementation. Verifying the declared presence, or absence, of nuclear materials and weapons components throughout the dismantlement and disposition lifecycle is a critical aspect of the disarmament process. From both the diplomatic and technical perspectives, verification under these future arms control regimes will require new solutions. Since any acceptable verification technology must protect sensitive design information and attributes to prevent the release of classified or other proliferation-sensitive information, non-nuclear non-sensitive modalities may provide significant new verification tools which do not require the use of additional information barriers. Alternative verification technologies based upon electromagnetic and acoustics could potentially play an important role in fulfilling the challenging requirements of future verification regimes. For example, researchers at the Pacific Northwest National Laboratory (PNNL) have demonstrated that low frequency electromagnetic

  9. Materials for sustained and controlled release of nutrients and molecules to support plant growth.

    PubMed

    Davidson, Drew; Gu, Frank X

    2012-02-01

    Controlled release fertilizers (CRFs) are a branch of materials that are designed to improve the soil release kinetics of chemical fertilizers to address problems stemming losses from runoff or other factors. Current CRFs are used but only in a limited market due to relatively high costs and doubts about their abilities to result in higher yields and increased profitability for agricultural businesses. New technologies are emerging that promise to improve the efficacy of CRFs to add additional functionality and reduce cost to make CRFs a more viable alternative to traditional chemical fertilizer treatment. CRFs that offer ways of reducing air and water pollution from fertilizer treatments, improving the ability of plants to access required nutrients, improving water retention to increase drought resistance, and reducing the amount of fertilizer needed to provide maximum crop yields are under development. A wide variety of different strategies are being considered to tackle this problem, and each approach offers different advantages and drawbacks. Agricultural industries will soon be forced to move toward more efficient and sustainable practices to respond to increasing fertilizer cost and desire for sustainable growing practices. CRFs have the potential to solve many problems in agriculture and help enable this shift while maintaining profitability. PMID:22224363

  10. Preparation and adsorption behavior of berberine hydrochloride imprinted polymers by using silica gel as sacrificed support material

    NASA Astrophysics Data System (ADS)

    Li, Hui; Li, Yuzhuo; Li, Zhiping; Peng, Xiyang; Li, Yanan; Li, Gui; Tan, Xianzhou; Chen, Gongxi

    2012-03-01

    Preparation of berberine hydrochloride (B-Cl) imprinted polymers (MIPs) based on surface imprinting technique with silica gel as sacrificial support material was performed successfully by using B-Cl as template, methacrylic acid (MAA) and ethylene glycol dimethacrylate (EGDMA) as functional monomer and cross-linker, respectively. The prepared polymers were characterized by Fourier transmission infrared spectrometry (FTIR) and scanning electron microscopy (SEM). Adsorption behavior of the MIPs for the template and its structural analogues was investigated. Sites distribution on the surface of MIPs was explored by using different isotherm adsorption models and thermodynamic parameters for the adsorption of B-Cl on the MIPs determined. Sample application and reusability for the MIPs was also evaluated. Results indicated the strong adsorption and high selectivity of the MIPs for B-Cl. Saturated adsorption capacity reached 27.2 μmol g-1 and the selectivity coefficient of the MIPs for B-Cl relative to jatrorrhizine hydrochloride (J-Cl) and palmatine palmatus hydrochloride (P-Cl) are 3.70 and 6.03, respectively. In addition, the MIPs were shown with good reusability and selectively retention ability in sample application.

  11. 21 CFR 570.13 - Indirect food additives resulting from packaging materials prior sanctioned for animal feed and...

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... materials prior sanctioned for animal feed and pet food. 570.13 Section 570.13 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS... prior sanctioned for animal feed and pet food. Regulations providing for the use of food...

  12. 21 CFR 570.13 - Indirect food additives resulting from packaging materials prior sanctioned for animal feed and...

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... materials prior sanctioned for animal feed and pet food. 570.13 Section 570.13 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS... prior sanctioned for animal feed and pet food. Regulations providing for the use of food...

  13. 21 CFR 570.13 - Indirect food additives resulting from packaging materials prior sanctioned for animal feed and...

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... materials prior sanctioned for animal feed and pet food. 570.13 Section 570.13 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS... prior sanctioned for animal feed and pet food. Regulations providing for the use of food...

  14. 21 CFR 570.13 - Indirect food additives resulting from packaging materials prior sanctioned for animal feed and...

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... materials prior sanctioned for animal feed and pet food. 570.13 Section 570.13 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS... prior sanctioned for animal feed and pet food. Regulations providing for the use of food...

  15. 21 CFR 570.13 - Indirect food additives resulting from packaging materials prior sanctioned for animal feed and...

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... materials prior sanctioned for animal feed and pet food. 570.13 Section 570.13 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS... prior sanctioned for animal feed and pet food. Regulations providing for the use of food...

  16. 36 CFR 1290.4 - Types of materials included in scope of assassination record and additional records and information.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ..., Forests, and Public Property NATIONAL ARCHIVES AND RECORDS ADMINISTRATION JFK ASSASSINATION RECORDS... COLLECTION ACT OF 1992 (JFK ACT) § 1290.4 Types of materials included in scope of assassination record and... information includes, for purposes of interpreting and implementing the JFK Act: (a) Papers, maps, and...

  17. Supporting Students' Construction of Scientific Explanations by Fading Scaffolds in Instructional Materials

    ERIC Educational Resources Information Center

    McNeill, Katherine L.; Lizotte, David J.; Krajcik, Joseph; Marx, Ronald W.

    2006-01-01

    The purpose of this study was to determine whether providing students with continuous written instructional support or fading written instructional support (scaffolds) better prepares students to construct scientific explanations when they are no longer provided with support. This article investigated the influence of scaffolding on 331…

  18. The Nuclear Fuel Services, Inc. program to support disposition of enriched uranium-bearing materials

    SciTech Connect

    Schutt, Stephen M.; Jacob, Norman P.

    2007-07-01

    The disposition of surplus nuclear materials has become one of the most pressing issues of our time. Numerous agencies have invoked programs with the purpose of removing such materials from various international venues and disposing these materials in a manner that achieves non-proliferability. This paper describes the Nuclear Fuel Services, Inc (NFS) Nuclear Material Disposition Program, which to date has focused on a variety of Special Nuclear Material (SNM), in particular uranium of various enrichments. The major components of this program are discussed, with emphasis on recycle and return of material to the nuclear fuel cycle. (authors)

  19. Modulation of the Reactivity of a WO3/Al Energetic Material with Graphitized Carbon Black as Additive

    NASA Astrophysics Data System (ADS)

    Bach, Arnaud; Gibot, Pierre; Vidal, Loïc; Gadiou, Roger; Spitzer, Denis

    2015-10-01

    Although pyrotechnic performance is fundamental, the strong mechanical and electrostatic intrinsic sensitivities of nanothermite energetic composites represent an obstacle to their development. The addition of a ternary component to the classical binary energetic composite appears to be a promising idea to overcome the problem. A carbon black additive (V3G) was used on a WO3/Al nanothermite. The effect of the pristine and modified carbon particles on the mechanical and electrical sensitivities of the composites was measured together with the pyrotechnic properties. The results show a complete desensitization to friction with a ball-milled carbon when the combustion velocity is slightly reduced.

  20. Full Mouth Oral Rehabilitation by Maxillary Implant Supported Hybrid Denture Employing a Fiber Reinforced Material Instead of Conventional PMMA

    PubMed Central

    Qamheya, Ala Hassan A.; Yeniyol, Sinem; Arısan, Volkan

    2015-01-01

    Many people have life-long problems with their dentures, such as difficulties with speaking and eating, loose denture, and sore mouth syndrome. The evolution of dental implant supported prosthesis gives these patients normal healthy life for their functional and esthetic advantages. This case report presents the fabrication of maxillary implant supported hybrid prosthesis by using Nanofilled Composite (NFC) material in teeth construction to rehabilitate a complete denture wearer patient. PMID:26557392

  1. Hexagonal nanorods of tungsten trioxide: Synthesis, structure, electrochemical properties and activity as supporting material in electrocatalysis

    NASA Astrophysics Data System (ADS)

    Salmaoui, Samiha; Sediri, Faouzi; Gharbi, Néji; Perruchot, Christian; Aeiyach, Salah; Rutkowska, Iwona A.; Kulesza, Pawel J.; Jouini, Mohamed

    2011-07-01

    Tungsten trioxide, unhydrated with hexagonal structure (h-WO 3), has been prepared by hydrothermal method at a temperature of 180 °C in acidified sodium tungstate solution. Thus prepared h-WO 3 has been characterized by X-ray diffraction (XRD) method and using electrochemical techniques. The morphology has been examined by scanning and transmission electron microscopies (SEM and TEM) and it is consistent with existence of nanorods of 50-70 nm diameter and up to 5 μm length. Cyclic voltammetric characterization of thin films of h-WO 3 nanorods has revealed reversible redox behaviour with charge-discharge cycling corresponding to the reversible lithium intercalation/deintercalation into the crystal lattice of the h-WO 3 nanorods. In propylene carbonate containing LiClO 4, two successive redox processes of hexagonal WO 3 nanorods are observed at the scan rate of 50 mV/s. Such behaviour shall be attributed to the presence of at least two W atoms of different surroundings in the lattice structure of h-WO 3 nanorods. On the other hand, in aqueous LiClO 4 solution, only one redox process is observed at the scan rate of 10 mV/s. The above observations can be explained in terms of differences in the diffusion of ions inside two types of channel cavities existing in the structure of the h-WO 3 nanorods. Moreover, the material can be applied as active support for the catalytic bi-metallic Pt-Ru nanoparticles during electrooxidation of ethanol in acid medium (0.5 mol dm -3 H 2SO 4).

  2. The influence of collagen support and ionic species on the morphology of collagen/hydroxyapatite composite materials

    SciTech Connect

    Ficai, Anton; Andronescu, Ecaterina; Voicu, Georgeta; Ghitulica, Cristina; Ficai, Denisa

    2010-04-15

    The purpose of this investigation is to study the influence of collagenous supports and ionic species on the precipitation of hydroxyapatite (HA) from aqueous solutions. To this end, we obtained hydroxyapatite by co-precipitation from a solution of calcium hydroxide and sodium dihydrogenophosphate. The formation of HA was studied by energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The results of this study indicate that the morphology of hydroxyapatite is highly influenced by the support material and the ionic species present. The obtained materials were studied by scanning electron microscopy (SEM).

  3. The development of a digital signal processing and plotting package to support testing of hazardous and radioactive material packages

    SciTech Connect

    Ludwigsen, J.S.; Uncapher, W.L.; Arviso, M.; Lattier, C.N.; Hankinson, M.; Cannone, D.J.

    1995-12-31

    Federal regulations allow package designers to use analysis, testing, or a combination of analysis and testing to support certification of packages used to transport hazardous or radioactive materials. In recent years, many certified packages were subjected to a combination of analysis and testing. A major part of evaluating structural or thermal package response is the collection, reduction and presentation of instrumentation measurement data. Sandia National Laboratories, under the sponsorship of the US Department of Energy, has developed a comprehensive analysis and plotting package (known as KAPP) that performs digital signal processing of both transient structural and thermal data integrated with a comprehensive plotting package designed to support radioactive material package testing.

  4. Sulfate reduction in sulfuric material after re-flooding: Effectiveness of organic carbon addition and pH increase depends on soil properties.

    PubMed

    Yuan, Chaolei; Fitzpatrick, Rob; Mosley, Luke M; Marschner, Petra

    2015-11-15

    Sulfuric material is formed upon oxidation of sulfidic material; it is extremely acidic, and therefore, an environmental hazard. One option for increasing pH of sulfuric material may be stimulation of bacterial sulfate reduction. We investigated the effects of organic carbon addition and pH increase on sulfate reduction after re-flooding in ten sulfuric materials with four treatments: control, pH increase to 5.5 (+pH), organic carbon addition with 2% w/w finely ground wheat straw (+C), and organic carbon addition and pH increase (+C+pH). After 36 weeks, in five of the ten soils, only treatment +C+pH significantly increased the concentration of reduced inorganic sulfur (RIS) compared to the control and increased the soil pore water pH compared to treatment+pH. In four other soils, pH increase or/and organic carbon addition had no significant effect on RIS concentration compared to the control. The RIS concentration in treatment +C+pH as percentage of the control was negatively correlated with soil clay content and initial nitrate concentration. The results suggest that organic carbon addition and pH increase can stimulate sulfate reduction after re-flooding, but the effectiveness of this treatment depends on soil properties. PMID:26024614

  5. FePO 4 nanoparticles supported on mesoporous SBA-15: Interesting cathode materials for Li-ion cells

    NASA Astrophysics Data System (ADS)

    Gerbaldi, C.; Meligrana, G.; Bodoardo, S.; Tuel, A.; Penazzi, N.

    Exploiting the properties of stability, low cost and low toxicity of iron phosphates, we have tried to enhance the performance of FePO 4 as cathode material for Li-ion cells. We adopted the strategy of obtaining FePO 4, via a typical preparation, onto the channels of an ordered mesoporous SBA-15 silica, a low cost mesoporous material commonly used in industry, which possesses larger pores, thicker walls and higher thermal stability as compared with other mesoporous silicas like MCM-41. Characterizations with ICP-AES, XRPD, BET and HRTEM suggest that the supported iron phosphate species, with loading amounts as high as 30 wt%, are located and dispersed in the mesopores of SBA-15. Iron phosphate can be reduced/oxidized more readily than the unsupported iron phosphate at room temperature, and in fact, cycling at C/10, the supported phosphate shows a utilization of 70% with respect to a value of 30% for the unsupported solid. The result is interesting from the scientific viewpoint but not suitable for application at the moment. Indeed, the amount of active material does not exceed 30% of the electrode mass and the total electrode capacity, though the active material is very efficient, is largely insufficient. Researches are being developed trying to increase the performances of the materials and also to eliminate the support after the dispersion of the active material.

  6. Laser and electron-beam powder-bed additive manufacturing of metallic implants: A review on processes, materials and designs.

    PubMed

    Sing, Swee Leong; An, Jia; Yeong, Wai Yee; Wiria, Florencia Edith

    2016-03-01

    Additive manufacturing (AM), also commonly known as 3D printing, allows the direct fabrication of functional parts with complex shapes from digital models. In this review, the current progress of two AM processes suitable for metallic orthopaedic implant applications, namely selective laser melting (SLM) and electron beam melting (EBM) are presented. Several critical design factors such as the need for data acquisition for patient-specific design, design dependent porosity for osteo-inductive implants, surface topology of the implants and design for reduction of stress-shielding in implants are discussed. Additive manufactured biomaterials such as 316L stainless steel, titanium-6aluminium-4vanadium (Ti6Al4V) and cobalt-chromium (CoCr) are highlighted. Limitations and future potential of such technologies are also explored. PMID:26488900

  7. Effect of additives on mechanical and electrical properties of semi organic non linear material-γ-glycine

    NASA Astrophysics Data System (ADS)

    Ravishankar, M. N.; Chandramani, R.; Prakash, A. P. Gnana

    2012-06-01

    The semi-organic non-linear optical (NLO) crystals of γ-Glycine (G), with additives like Ammonium Oxalate (AO), Barium Nitrate (BN) and Potassium Nitrate (PN) were grown by aqueous solution method. The mechanical properties, dielectric constant, dielectric loss, AC conductivity of the grown crystals were studied. Studies confirm that the grown NLO crystals retain the merits of organic (SHG response and flexibility) and inorganic (good hardness) properties.

  8. Mechanical and Structural Behavior of Granular Material Packed Beds for Space Life Support System Applications

    NASA Technical Reports Server (NTRS)

    Malla, Ramesh B.; Anandakumar, Ganesh

    2005-01-01

    Long-term human mission to space, such as living in International Space Station (ISS), Lunar, and Martian bases, and travel to Mars, must m ake use of Advanced Life Support Systems (ALSS) to generate and recycle critical life supporting elements like oxygen and water. Oxygen Gen eration Assembly (OGA) and Water Processor Assembly (WPA), critical c omponents of ALSS, make use of series of granular material packed beds for generation and recycling of oxygen and water. Several granular m aterials can be used for generation, recycling, processing and recovery of oxygen and water. For example, they may include soft bed media, e.g. ion exchange resins for oxygen generation assembly and hard bed media such as, activated alumina, magchem (Magnesium oxide) and activa ted carbon to remove organic species like ethanol, methanol, and urea from wastewater in Water recovery/processing assembly. These beds are generally packed using a plate-spring mechanism to provide sufficien t compaction to the bed media throughout the course of operation. This paper presents results from an experimental study of a full-scale, 3 8.1 cm (15 inches) long and 3.7 cm (1.44 inches) diameter. activated alumina bed enclosed in a cylinder determining its force-displacement behavior, friction mobilizing force, and axial normal stress distribu tion under various axially applied loads and at different levels of packing. It is observed that force-displacement behavior is non-linear for low compaction level and becomes linear with increase in compaction of the bed media. Axial normal stress distribution along the length of the bed media decreased non-linearly with increase in depth from the loading end of the granular media. This paper also presents experimental results on the amount of particulates generated corresponding to various compaction levels. Particulates generated from each of the tests were measured using standard US sieves. It was found that the p articulates and the overall displacement of

  9. Thermal conductivity of thermally-isolating polymeric and composite structural support materials between 0.3 and 4 K

    NASA Astrophysics Data System (ADS)

    Runyan, M. C.; Jones, W. C.

    2008-09-01

    We present measurements of the low-temperature thermal conductivity of a number of polymeric and composite materials from 0.3 to 4 K. The materials measured are Vespel SP-1, Vespel SP-22, unfilled PEEK, 30% carbon fiber-filled PEEK, 30% glass-filled PEEK, carbon fiber Graphlite composite rod, Torlon 4301, G-10/FR-4 fiberglass, pultruded fiberglass composite, Macor ceramic, and graphite rod. These materials have moderate to high elastic moduli making them useful for thermally-isolating structural supports.

  10. Heat treatment and the use of additives to improve the stability of paralytic shellfish poisoning toxins in shellfish tissue reference materials for internal quality control and proficiency testing.

    PubMed

    Burrell, Stephen; Clion, Valentin; Auroy, Virginie; Foley, Barry; Turner, Andrew D

    2015-06-01

    The need for homogenous reference materials stable for paralytic shellfish toxins is vital for the monitoring and quality assurance of these potent neurotoxins in shellfish. Two stabilisation techniques were investigated, heat treatment through autoclaving and the addition of preserving additives into the tissue matrix. Short and long-term stability experiments as well as homogeneity determination were conducted on materials prepared by both techniques in comparison with an untreated control using two LC-FLD methods. Both techniques improved the stability of the matrix and the PSP toxins present compared to the controls. A material was prepared using the combined techniques of heat treatment followed by spiking with additives and data is presented from this optimised reference material as used over a two year period in the Irish national monitoring program and in a development exercise as part of a proficiency testing scheme operated by QUASIMEME (Quality Assurance of Information for Marine Environmental Monitoring in Europe) since 2011. The results were indicative of the long-term stability of the material as evidenced through consistent assigned values in the case of the proficiency testing scheme and a low relative standard deviation of 10.5% for total toxicity data generated over 24 months. PMID:25816999

  11. The effect of diet supplementation and addition of zinc in vitro on the growth-supporting property of amniotic fluid in African women.

    PubMed

    Appelbaum, P C; Ross, S M; Dhupelia, I; Naeye, R L

    1979-09-01

    The effect of diet supplementation throughout pregnancy on third-trimester amniotic fluid growth-supporting activity (GSP) was studied in 100 African women; 32 were given zinc supplementation, 22 each animal and vegetable supplements, respectively, and 24 served as control subjects. No difference in GSP was noted in any of the four groups, the majority of fluids (65%) being noninhibitory. Zinc levels in fluids from African women were much lower than those described for other population groups at corresponding periods of gestation. Although zinc levels in liquor rose following dietary zinc supplementation, these remained lower than values described in white patients. In vitro addition of zinc (up to 153 mu moles per liter final concentration) to 17 noninhibitory African liquors resulted in these fluids becoming inhibitory. PMID:474664

  12. 18 CFR 347.1 - Material to support request for newly established or changed property account depreciation studies.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 18 Conservation of Power and Water Resources 1 2012-04-01 2012-04-01 false Material to support request for newly established or changed property account depreciation studies. 347.1 Section 347.1 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION, DEPARTMENT OF ENERGY REGULATIONS UNDER THE INTERSTATE COMMERCE ACT...

  13. Optimization of the β-Elimination/Michael Addition Chemistry on Reversed-Phase Supports for Mass Spectrometry Analysis of O-Linked Protein Modifications

    PubMed Central

    Nika, Heinz; Nieves, Edward; Hawke, David H.; Angeletti, Ruth Hogue

    2013-01-01

    We previously adapted the β-elimination/Michael addition chemistry to solid-phase derivatization on reversed-phase supports, and demonstrated the utility of this reaction format to prepare phosphoseryl peptides in unfractionated protein digests for mass spectrometric identification and facile phosphorylation-site determination. Here, we have expanded the use of this technique to β-N-acetylglucosamine peptides, modified at serine/threonine, phosphothreonyl peptides, and phosphoseryl/phosphothreonyl peptides, followed in sequence by proline. The consecutive β-elimination with Michael addition was adapted to optimize the solid-phase reaction conditions for throughput and completeness of derivatization. The analyte remained intact during derivatization and was recovered efficiently from the silica-based, reversed-phase support with minimal sample loss. The general use of the solid-phase approach for enzymatic dephosphorylation was demonstrated with phosphoseryl and phosphothreonyl peptides and was used as an orthogonal method to confirm the identity of phosphopeptides in proteolytic mixtures. The solid-phase approach proved highly suitable to prepare substrates from low-level amounts of protein digests for phosphorylation-site determination by chemical-targeted proteolysis. The solid-phase protocol provides for a simple, robust, and efficient tool to prepare samples for phosphopeptide identification in MALDI mass maps of unfractionated protein digests, using standard equipment available in most biological laboratories. The use of a solid-phase analytical platform is expected to be readily expanded to prepare digest from O-glycosylated- and O-sulfonated proteins for mass spectrometry-based structural characterization. PMID:23997661

  14. Game theory and decision support system for use in security reviews of nuclear material tracking and accountancy systems

    SciTech Connect

    Goutal, P.; Werkoff, F.; Le Manchec, K.; Preston, N.; Roche, F.

    1995-12-31

    Tracking and accountancy arrangements help guarantee the security of nuclear materials. Verifications consisting of comparisons between physical identifications or measurements on one hand and material accountancy on the other hand are carried out, in order to detect any unexpected absence of nuclear material. This paper studies two different aspects of the problem of the efficiency of these verifications. First, a decision support system for use in security reviews of nuclear material accountancy systems is presented. Its purpose is firstly to represent a facility and the associated verifications, tracking and accountancy operations and secondly, to calculate the detection delay in the case of an absence of nuclear material. Next, in order to minimize the detection delay for a limited, fixed number of physical identifications, a two-person, zero-sum game with incomplete information is described. The first results obtained from this analysis indicate shorter detection times than those given by games with complete information.

  15. Graphene nanoribbons hybridized carbon nanofibers: remarkably enhanced graphitization and conductivity, and excellent performance as support material for fuel cell catalysts

    NASA Astrophysics Data System (ADS)

    Wang, Chaonan; Gao, Hongrong; Li, Hong; Zhang, Yiren; Huang, Bowen; Zhao, Junhong; Zhu, Yan; Yuan, Wang Zhang; Zhang, Yongming

    2014-01-01

    High electronic conductivity of the support material and uniform distribution of the catalyst nanoparticles (NPs) are extremely desirable for electrocatalysts. In this paper, we present our recent progress on electrocatalysts for fuel cells with simultaneously improved conductivity of the supporting carbon nanofibers (CNFs) and distribution of platinum (Pt) NPs through facile incorporation of graphene nanoribbons (GNRs). Briefly, GNRs were obtained by the cutting and unzipping of multiwalled carbon nanotubes (MWCNTs) and subsequent thermal reduction and were first used as novel nanofillers in CNFs towards high performance support material for electrocatalysis. Through electrospinning and carbonization processes, GNR embedded carbon nanofibers (G-CNFs) with greatly enhanced graphitization and electronic conductivity were synthesized. Chemical deposition of Pt NPs onto G-CNFs generated a new Pt-G-CNF hybrid catalyst, with homogeneously distributed Pt NPs of ~3 nm. Compared to Pt-CNF (Pt on pristine CNFs) and Pt-M-CNF (Pt on MWCNT embedded CNFs), Pt-G-CNF hybrids exhibit significantly improved electrochemically active surface area (ECSA), better CO tolerance for electro-oxidation of methanol and higher electrochemical stability, testifying G-CNFs are promising support materials for high performance electrocatalysts for fuel cells.High electronic conductivity of the support material and uniform distribution of the catalyst nanoparticles (NPs) are extremely desirable for electrocatalysts. In this paper, we present our recent progress on electrocatalysts for fuel cells with simultaneously improved conductivity of the supporting carbon nanofibers (CNFs) and distribution of platinum (Pt) NPs through facile incorporation of graphene nanoribbons (GNRs). Briefly, GNRs were obtained by the cutting and unzipping of multiwalled carbon nanotubes (MWCNTs) and subsequent thermal reduction and were first used as novel nanofillers in CNFs towards high performance support material for

  16. Evaluation of western shale-oil residue as an additive to petroleum asphalt for use as a pavement crack and joint sealant material

    SciTech Connect

    Harnsberger, P.M.; Wolf, J.M.; Robertson, R.E.

    1992-11-01

    The objective of this study was to perform a preliminary evaluation of using a distillation residue from Green River Formation (western) shale oil as an additive to a petroleum asphalt for use as a crack and joint filler material in portland cement concrete and asphaltic pavements. A commercially available rubberized asphalt crack and joint filler material was also tested for comparison. ASTM specification tests for sealant materials used in concrete and asphalt pavements were performed on the sealant materials. Portland cement concrete briquets prepared with an asphalt material sandwiched between two concrete wafers were tested in a stress-relaxation experiment to evaluate the relaxation and recovery properties of the sealant materials. The results show that the shale-oil modified petroleum asphalts and the neat petroleum asphalt do not pass the extension portion of the ASTM test; however, there is indication of improvement in the adhesive properties of the shale-oil modified asphalts. There is also evidence that the addition of shale-oil residue to the petroleum asphalt, especially at the 20% level, improves the relaxation and recovery properties compared with the petroleum asphalt.

  17. Investigation of Cross-Linked and Additive Containing Polymer Materials for Membranes with Improved Performance in Pervaporation and Gas Separation

    PubMed Central

    Hunger, Katharina; Schmeling, Nadine; Jeazet, Harold B. Tanh; Janiak, Christoph; Staudt, Claudia; Kleinermanns, Karl

    2012-01-01

    Pervaporation and gas separation performances of polymer membranes can be improved by crosslinking or addition of metal-organic frameworks (MOFs). Crosslinked copolyimide membranes show higher plasticization resistance and no significant loss in selectivity compared to non-crosslinked membranes when exposed to mixtures of CO2/CH4 or toluene/cyclohexane. Covalently crosslinked membranes reveal better separation performances than ionically crosslinked systems. Covalent interlacing with 3-hydroxypropyldimethylmaleimide as photocrosslinker can be investigated in situ in solution as well as in films, using transient UV/Vis and FTIR spectroscopy. The photocrosslinking yield can be determined from the FTIR-spectra. It is restricted by the stiffness of the copolyimide backbone, which inhibits the photoreaction due to spatial separation of the crosslinker side chains. Mixed-matrix membranes (MMMs) with MOFs as additives (fillers) have increased permeabilities and often also selectivities compared to the pure polymer. Incorporation of MOFs into polysulfone and Matrimid® polymers for MMMs gives defect-free membranes with performances similar to the best polymer membranes for gas mixtures, such as O2/N2 H2/CH4, CO2/CH4, H2/CO2, CH4/N2 and CO2/N2 (preferentially permeating gas is named first). The MOF porosity, its particle size and content in the MMM are factors to influence the permeability and the separation performance of the membranes. PMID:24958427

  18. Utilization of liquid human wastes and introduction into the material cycling in biological life-support systems

    NASA Astrophysics Data System (ADS)

    Kovaleva, N. P.>; Ushakova, S. A.; Gribovskaya, I. V.; Kudenko, U. A.

    The possibilities of step-by-step utilization of liquid human wastes in biological life-support systems on long-functioning space stations have been considered in this work. Utilization involves "wet" urine incineration with hydrogen peroxide at normal pressure and 90 - 95°C temperature, urease-enzymic decomposition of urine and biological desalination in the higher plant link. The soybean flour was used as a source of urease. Growing soya plants as a component of the higher plant link would give a steady source of urease to the system. To decompose urea (9-15g) contained in 1l of incinerated urine we used 0.5 - 1 g of soy flour. The duration of hydrolysis of daily urea excreted by a human is 70 - 95 hours. It is supposed that ammonia excreted in the reaction of urea decomposition will be processed by nitrifying bacteria. The concentration of total nitrogen in urine after urea hydrolysis and removal of ammonia formed during the reaction constituted 0.6 - 1.2 g/l. Further biological desalination was carried out in the higher plant link, for that the edible salt-accumulating halophytes Salicornia europaea were used. To grow this plant under the aqueous culture conditions, the urine was additionally mineralized at 180 °C after incineration and decomposition of urea. The process of additional mineralization was related to the necessity of removal of organic materials and nitrogen residues, which higher concentration under the aqueous culture conditions has negative effect on plants. The volume of the nutrient solution for growing 6 plants of Salicornia europaea was 1.5 l (daily norm of urine excreted by human), the planting area was 0.032 m2. By the end of vegetation the productivity and mineral composition of Salicornia europaea plants were analyzed. The productivity of plants grown on liquid human wastes (the experiment) practically was not different from the productivity of plants grown on the mineral solution with sodium chloride (checkout). In experimental

  19. Wear behavior of 2-1/4 Cr-1 Mo tubing against alloy 718 tube-support material in sodium-cooled steam generators

    SciTech Connect

    Wilson, W L

    1983-05-01

    A series of prototypic steam generator 2-{1/4} Cr-1 Mo tube/alloy 718 tube support plate wear tests were conducted in direct support of the Westinghouse Nuclear Components Division -- Breeder Reactor Components Project Large Scale steam Generator design. The initial objective was to verify the acceptable wear behavior of softer, over-aged'' alloy 718 support plate material. For all interfaces under all test conditions, resultant wear damage was adhesive in nature with varying amounts of 2-{1/4} Cr-1 Mo tube material being adhesively transferred to the alloy 718 tube supports. Maximum tube wear depths exceeded the initially established design allowable limit of 127 {mu}m (.005 in.) at 17 of the 18 interfaces tested. A decrease in contact stresses produced acceptable tube wear depths below a readjusted maximum design allowable value of 381 {mu}m (.015 in.). Additional conservatisms associated with the simulation of a 40-year lifetime of rubbing in a one-week laboratory test provided further confidence that the 381 {mu}m maximum tube wear allowance would not be exceeded in service. Softer, over-aged'' alloy 718 material was found to produce slightly less wear damage on 2-{1/4} Cr-1 Mo tubing than fully age hardened material. Also, air formed oxide films on the alloy 718 reduced initial tube wear and delayed the onset of adhesive surface damage. However, at high surface stress levels, these films were not sufficiently stable to provide adequate long term protection from adhesive wear. The results of the present work and those of previous test programs suggest that the successful in-sodium tribological performance of 2-{1/4} Cr-1 Mo/alloy 718 rubbing couples is dependent upon the presence of lubricative surface films, such as oxides and/or surface reaction or deposition products. 11 refs., 13 figs., 4 tabs.

  20. Adsorption of peptides at the sample drying step: influence of solvent evaporation technique, vial material and solution additive.

    PubMed

    Pezeshki, Adel; Vergote, Valentijn; Van Dorpe, Sylvia; Baert, Bram; Burvenich, Christian; Popkov, Alexander; De Spiegeleer, Bart

    2009-04-01

    Although the efficient and careful removal of solvent from samples by centrifugal evaporation or freeze-drying methods is an important step in peptidomics, the recovery of peptides has not yet been fully investigated with these sample drying methods. Moreover, the surface adsorption of the peptides by the container and efforts to reduce this adsorption by organic additives is only scarcely elaborated until now. In this experiment, the recovery of five model peptides, i.e. bovine insulin, mouse obestatin, goserelin, buserelin and leucine-enkephalin was investigated applying dimethylsulfoxide (DMSO), dimethylformamide (DMF), polyethylene glycol 400 (PEG 400), mannitol and n-nonyl-beta-d-glucopyranoside (C(9)-Glu) in function of the two applied solvent evaporation processes (freeze-drying vs. centrifugal evaporation) and vial types, i.e. polypropylene (PP) and glass. Under our experimental conditions, drying resulted in a decreased recovery of the model peptides by 10% on average. Insulin showed the lowest recovery value relative to the other model peptides. For both drying methods, recovery of the model peptides was increased when C(9)-Glu was present. Overall, the use of PP vials is proposed for freeze-drying, while glass vials are found to be more suitable for centrifugal evaporation. The presence of PEG 400 in PP vials caused significantly reduced recoveries for all model peptides using centrifugal evaporation, although this was not observed in glass vials. As a general conclusion, applying C(9)-Glu as an additive along with choosing appropriate vial type (i.e. PP for lyophilization and glass for centrifugal evaporation) can avoid or diminish peptide loss during the evaporation procedure. PMID:19150589

  1. Development of a Support Environment for First Year Students Taking Materials Science/Engineering

    ERIC Educational Resources Information Center

    Laoui, Tahar; O'Donoghue, John

    2008-01-01

    This paper is based on the experience acquired in teaching materials science/engineering to first year university students. It has been observed that students struggle with some of the fundamental materials concepts addressed in the module/course. This applies to delivered lectures but extends to the incorporation of tutorial sessions provided…

  2. Student-Instructor Communication: An Innovative Teaching Material in Support of Student Learning

    ERIC Educational Resources Information Center

    Cheng, Kai- Wen; Chen, Yu-Fen

    2008-01-01

    The purpose of this study was to understand how the innovative teaching material "Interactive Learning Disk (ILD)" could enhance the learning effect of students taking the course of Tourist Database Management (TDM). "ILD" is a kind of teaching material that incorporate interactive concept into course and help students to learn after class. This…

  3. Reusable biocompatible interface for immobilization of materials on a solid support

    DOEpatents

    Salamon, Z.; Schmidt, R.A.; Tollin, G.; Macleod, H.A.

    1996-05-28

    A method is presented for the formation of a biocompatible film composed of a self-assembled bilayer membrane deposited on a planar surface. This bilayer membrane is capable of immobilizing materials to be analyzed in an environment very similar to their native state. Materials so immobilized may be subject to any of a number of analytical techniques. 3 figs.

  4. Distinguished-Level Learning Online: Support Materials from LangNet and RussNet

    ERIC Educational Resources Information Center

    Leaver, Betty Lou; Ehrman, Madeline; Lekic, Maria

    2004-01-01

    This article introduces the reader to two online sources of materials for working on improving listening and reading skills. The materials are intended for learners already at Interagency Language Roundtable (ILR) Level 3 (Superior) proficiency in Arabic, Chinese, Hindi, Korean, Russian, and Spanish, who desire to reach Level 4 (Distinguished, or…

  5. Reusable biocompatible interface for immobilization of materials on a solid support

    DOEpatents

    Salamon, Zdzislaw; Schmidt, Richard A.; Tollin, Gordon; Macleod, H. Angus

    1996-01-01

    A method for the formation of a biocompatible film composed of a self-assembled bilayer membrane deposited on a planar surface. This bilayer membrane is capable of immobilizing materials to be analyzed in an environment very similar to their native state. Materials so immobilized may be subject to any of a number of analytical techniques.

  6. Self-help quit smoking interventions: effects of self-help materials, social support instructions, and telephone counseling.

    PubMed

    Orleans, C T; Schoenbach, V J; Wagner, E H; Quade, D; Salmon, M A; Pearson, D C; Fiedler, J; Porter, C Q; Kaplan, B H

    1991-06-01

    Smokers requesting self-help materials for smoking cessation (N = 2,021) were randomized to receive (a) an experimental self-quitting guide emphasizing nicotine fading and other nonaversive behavioral strategies, (b) the same self-quitting guide with a support guide for the quitter's family and friends, (c) self-quitting and support guides along with four brief counselor calls, or (d) a control guide providing motivational and quit tips and referral to locally available guides and programs. Subjects were predominantly moderate to heavy smokers with a history of multiple previous quit attempts and treatments. Control subjects achieved quit rates similar to those of smokers using the experimental quitting guide, with fewer behavioral prequitting strategies and more outside treatments. Social support guides had no effect on perceived support for quitting or on 8- and 16-month quit rates. Telephone counseling increased adherence to the quitting protocol and quit rates. PMID:2071729

  7. Superconductive material and magnetic field for damping and levitation support and damping of cryogenic instruments

    NASA Technical Reports Server (NTRS)

    Dolgin, Benjamin P. (Inventor)

    1994-01-01

    A superconductive load bearing support without a mechanical contact and vibration damping for cryogenic instruments in space is presented. The levitation support and vibration damping is accomplished by the use of superconducting magnets and the 'Meissner' effect. The assembly allows for transfer of vibration energy away from the cryogenic instrument which then can be damped by the use of either an electronic circuit or conventional vibration damping mean.

  8. Conversion of biomass-derived sorbitol to glycols over carbon-materials supported Ru-based catalysts

    NASA Astrophysics Data System (ADS)

    Guo, Xingcui; Guan, Jing; Li, Bin; Wang, Xicheng; Mu, Xindong; Liu, Huizhou

    2015-11-01

    Ruthenium (Ru) supported on activated carbon (AC) and carbon nanotubes (CNTs) was carried out in the hydrogenolysis of sorbitol to ethylene glycol (EG) and 1,2-propanediol (1,2-PD) under the promotion of tungsten (WOx) species and different bases. Their catalytic activities and glycols selectivities strongly depended on the support properties and location of Ru on CNTs, owning to the altered metal-support interactions and electronic state of ruthenium. Ru located outside of the tubes showed excellent catalytic performance than those encapsulated inside the nanotubes. Additionally, the introduction of WOx into Ru/CNTs significantly improved the hydrogenolysis activities, and a complete conversion of sorbitol with up to 60.2% 1,2-PD and EG yields was obtained on RuWOx/CNTs catalyst upon addition of Ca(OH)2. Stability study showed that this catalyst was highly stable against leaching and poisoning and could be recycled several times.

  9. Conversion of biomass-derived sorbitol to glycols over carbon-materials supported Ru-based catalysts.

    PubMed

    Guo, Xingcui; Guan, Jing; Li, Bin; Wang, Xicheng; Mu, Xindong; Liu, Huizhou

    2015-01-01

    Ruthenium (Ru) supported on activated carbon (AC) and carbon nanotubes (CNTs) was carried out in the hydrogenolysis of sorbitol to ethylene glycol (EG) and 1,2-propanediol (1,2-PD) under the promotion of tungsten (WOx) species and different bases. Their catalytic activities and glycols selectivities strongly depended on the support properties and location of Ru on CNTs, owning to the altered metal-support interactions and electronic state of ruthenium. Ru located outside of the tubes showed excellent catalytic performance than those encapsulated inside the nanotubes. Additionally, the introduction of WOx into Ru/CNTs significantly improved the hydrogenolysis activities, and a complete conversion of sorbitol with up to 60.2% 1,2-PD and EG yields was obtained on RuWOx/CNTs catalyst upon addition of Ca(OH)2. Stability study showed that this catalyst was highly stable against leaching and poisoning and could be recycled several times. PMID:26578426

  10. Conversion of biomass-derived sorbitol to glycols over carbon-materials supported Ru-based catalysts

    PubMed Central

    Guo, Xingcui; Guan, Jing; Li, Bin; Wang, Xicheng; Mu, Xindong; Liu, Huizhou

    2015-01-01

    Ruthenium (Ru) supported on activated carbon (AC) and carbon nanotubes (CNTs) was carried out in the hydrogenolysis of sorbitol to ethylene glycol (EG) and 1,2-propanediol (1,2-PD) under the promotion of tungsten (WOx) species and different bases. Their catalytic activities and glycols selectivities strongly depended on the support properties and location of Ru on CNTs, owning to the altered metal-support interactions and electronic state of ruthenium. Ru located outside of the tubes showed excellent catalytic performance than those encapsulated inside the nanotubes. Additionally, the introduction of WOx into Ru/CNTs significantly improved the hydrogenolysis activities, and a complete conversion of sorbitol with up to 60.2% 1,2-PD and EG yields was obtained on RuWOx/CNTs catalyst upon addition of Ca(OH)2. Stability study showed that this catalyst was highly stable against leaching and poisoning and could be recycled several times. PMID:26578426

  11. Mesophilic hydrogen production in acidogenic packed-bed reactors (APBR) using raw sugarcane vinasse as substrate: Influence of support materials.

    PubMed

    Nunes Ferraz Júnior, Antônio Djalma; Etchebehere, Claudia; Zaiat, Marcelo

    2015-08-01

    Bio-hydrogen production from sugarcane vinasse in anaerobic up-flow packed-bed reactors (APBR) was evaluated. Four types of support materials, expanded clay (EC), charcoal (Ch), porous ceramic (PC), and low-density polyethylene (LDP) were tested as support for biomass attachment. APBR (working volume - 2.3 L) were operated in parallel at a hydraulic retention time of 24 h, an organic loading rate of 36.2 kg-COD m(-3) d(-1), at 25 °C. Maximum volumetric hydrogen production values of 509.5, 404, 81.4 and 10.3 mL-H2 d(-1) L(-1)reactor and maximum yields of 3.2, 2.6, 0.4 and 0.05 mol-H2 mol(-1) carbohydrates total, were observed during the monitoring of the reactors filled with LDP, EC, Ch and PC, respectively. Thus, indicating the strong influence of the support material on H2 production. LDP was the most appropriate material for hydrogen production among the materials evaluated. 16S rRNA gene by Terminal Restriction Fragment Length Polymorphism (T-RFLP) analysis and scanning electron microscopy confirmed the selection of different microbial populations. 454-pyrosequencing performed on samples from APBR filled with LDP revealed the presence of hydrogen-producing organisms (Clostridium and Pectinatus), lactic acid bacteria and non-fermentative organisms. PMID:25891935

  12. FY 1984 and FY 1985 geochemistry and materials studies in support of the Magma Energy Extraction Program

    SciTech Connect

    Westrich, H.R.; Weirick, L.J.; Cygan, R.T.; Reece, M.; Hlava, P.F.; Stockman, H.W.; Gerlach, T.M.

    1986-04-01

    Geochemistry and materials studies are being performed in support of the Magma Energy Extraction Program. The work is largely restricted to: (1) characterizing magmatic environments at sites of interest, (2) testing engineering materials in laboratory simulated magmatic environments, (3) investigating chemical mass transport effects inherent in designs for direct contact heat exchangers, and (4) evaluating degassing hazards associated with drilling into and extracting energy from shallow magma. Magma characterization studies have been completed for shallow magma at Long Valley, Coso volcanic field, and Kilauea volcano. The behavior of 17 commercially available materials has been examined in rhyolite magma at 850/sup 0/C and 200 MPa for periods up to seven days. Analysis of reaction products from materials tests to date indicate that oxidation is the main corrosion problem for most alloys in rhyolitic magma. Considerations of corrosion resistance, high-temperature strength, and cost indicate nickel-base superalloys offer the most promise as candidates for use in rhyolitic magma.

  13. Survey of Technetium Analytical Production Methods Supporting Hanford Nuclear Materials Processing

    SciTech Connect

    TROYER, G.L.

    1999-11-03

    This document provides a historical survey of analytical methods used for measuring {sup 99}Tc in nuclear fuel reprocessing materials and wastes at Hanford. Method challenges including special sludge matrices tested are discussed. Special problems and recommendations are presented.

  14. Investigating the role of educative curriculum materials in supporting teacher enactment of a field-based urban ecology investigation

    NASA Astrophysics Data System (ADS)

    Houle, Meredith

    2008-10-01

    This multiple case study examined how three urban science teachers used curriculum materials designed educatively. Educative curriculum materials have been suggested as one way to support science teacher learning, particularly around new innovations and new pedagogies and to support teachers in evaluating and modifying materials to meet the needs of their students (Davis & Krajcik, 2005). While not a substitute for professional development, educative curriculum materials may provide an opportunity to support teachers' enactment and learning in the classroom context (Davis & Krajcik, 2005; Remillard, 2005; Schneider & Krajcik, 2002). However, little work has examined how science teachers interact with written curriculum materials to design classroom instruction. Grounded in sociocultural analysis, this study takes the theoretical stance that teachers and curriculum materials are engaged in a dynamic and participatory relationship from which the planned and enacted curriculum emerges (Remillard, 2005). Teaching is therefore a design activity where teachers rely on their personal resources and the curricular resources to construct and shape their students' learning experiences (Brown, 2002). Specifically this study examines how teacher beliefs influence their reading and use of curriculum and how educative features in the written curriculum inform teachers' pedagogical decisions. Data sources included classroom observation and video, teacher interviews, and classroom artifacts. To make sense how teachers' make curricular decisions, video were analyzed using Brown's (2002) Pedagogical Design for Enactment Framework. These coded units were examined in light of the teacher interviews, classroom notes and artifacts to examine how teachers' beliefs influenced these decisions. Data sources were then reexamined for evidence of teachers' use of specific educative features. My analyses revealed that teachers' beliefs about curriculum influenced the degree to which teachers

  15. In vivo comparison of force development with various materials of implant-supported prostheses.

    PubMed

    Kim, H K; Heo, S J; Koak, J Y; Kim, S K

    2009-08-01

    The purpose of this study was to measure axial loading, generating bending moments on fibre reinforced composite (FRC) implant prostheses using strain-gauged customized abutment in vivo. Bending moments of conventional implant prosthetic material were also measured and the data were compared with those for FRC. Three unit fixed dental prostheses were made for two dental implant fixtures, which had been functioning properly for more than one year using Tescera ATL, porcelain fused to metal and gold as occlusal material. Three patients participated in this study; two patients had two implants on one side of the mandible and one had two implants on both sides of the mandible. Five sets of fixed dental prostheses were fabricated for each material and these were cemented with Temp-bond on strain-gauged customized abutments, which were screwed into the underlying implant fixtures. Axial loadings and bending moments were measured when a patient bit the experimental fixed dental prosthesis. ANOVA and the Tukey HSD test (alpha = 0.05) were used for statistical analysis. There were no significant differences in normalized bending moments among the three different implant prosthetic materials. Within the limitations of this study, Tescera ATL generated bending moments similar to conventional implant prosthetic materials such as gold and porcelain. PMID:19548956

  16. Biaxial experiments supporting the development of constitutive theories for advanced high-temperature materials

    NASA Technical Reports Server (NTRS)

    Ellis, J. R.

    1988-01-01

    Complex states of stress and strain are introduced into components during service in engineering applications. It follows that analysis of such components requires material descriptions, or constitutive theories, which reflect the tensorial nature of stress and strain. For applications involving stress levels above yield, the situation is more complex in that material response is both nonlinear and history dependent. This has led to the development of viscoplastic constitutive theories which introduce time by expressing the flow and evolutionary equation in the form of time derivatives. Models were developed here which can be used to analyze high temperature components manufactured from advanced composite materials. In parallel with these studies, effort was directed at developing multiaxial testing techniques to verify the various theories. Recent progress in the development of constitutive theories from both the theoretical and experimental viewpoints are outlined. One important aspect is that material descriptions for advanced composite materials which can be implemented in general purpose finite element codes and used for practical design are verified.

  17. Ozonation of bezafibrate over ceria and ceria supported on carbon materials.

    PubMed

    Gonçalves, Alexandra G; Órfão, José J M; Pereira, Manuel Fernando R

    2015-01-01

    Two catalysts containing ceria dispersed on the surface of multi-walled carbon nanotubes and activated carbon were investigated as ozonation catalysts for the mineralization of bezafibrate (BZF). The results were compared with those obtained in the absence of the catalyst and in the presence of the parent carbon materials, as well as in the presence of ceria (CeO2). Carbon materials containing ceria showed an interesting catalytic effect. Both materials enhanced the mineralization of BZF relatively to single ozonation and ozonation catalysed by the corresponding carbon materials. In the catalytic ozonation with these materials, both surface and bulk reactions are supposed to occur. The BZF ozonation catalysed by CeO2 leaded to the highest mineralization degrees, indicating that the reaction mechanism followed in the presence of CeO2 (free radical oxidation in solution) leads to the formation of intermediates more easily degradable, mainly after 120 min of reaction. Some primary products and refractory final oxidation compounds in single and catalytic ozonation of BZF were followed. The original chlorine present on the BZF molecule is completely converted to chloride anion and part of the nitrogen is mainly converted to NO3- along with smaller amounts of NO2- and NH4+. Microtox tests revealed that simultaneous use of ozone and CeO2 originated lower acute toxicity. PMID:25189707

  18. Lateral Diffusion of Proteins on Supported Lipid Bilayers: Additive Friction of Synaptotagmin 7 C2A–C2B Tandem Domains

    PubMed Central

    2015-01-01

    The synaptotagmin (Syt) family of proteins contains tandem C2 domains, C2A and C2B, which bind membranes in the presence of Ca2+ to trigger vesicle fusion during exocytosis. Despite recent progress, the role and extent of interdomain interactions between C2A and C2B in membrane binding remain unclear. To test whether the two domains interact on a planar lipid bilayer (i.e., experience thermodynamic interdomain contacts), diffusion of fluorescent-tagged C2A, C2B, and C2AB domains from human Syt7 was measured using total internal reflection fluorescence microscopy with single-particle tracking. The C2AB tandem exhibits a lateral diffusion constant approximately half the value of the isolated single domains and does not change when additional residues are engineered into the C2A–C2B linker. This is the expected result if C2A and C2B are separated when membrane-bound; theory predicts that C2AB diffusion would be faster if the two domains were close enough together to have interdomain contact. Stopped-flow measurements of membrane dissociation kinetics further support an absence of interdomain interactions, as dissociation kinetics of the C2AB tandem remain unchanged when rigid or flexible linker extensions are included. Together, the results suggest that the two C2 domains of Syt7 bind independently to planar membranes, in contrast to reported interdomain cooperativity in Syt1. PMID:25437758

  19. REMOTE MATERIAL HANDLING IN THE YUCCA MOUNTAIN WASTE PACKAGE CLOSURE CELL AND SUPPORT AREA GLOVEBOX

    SciTech Connect

    K.M. Croft; S.M. Allen; M.W. Borland

    2005-08-02

    The Yucca Mountain Waste Package Closure System (WPCS) cells provide for shielding of highly radioactive materials contained in unsealed waste packages. The purpose of the cells is to provide safe environments for package handling and sealing operations. Once sealed, the packages are placed in the Yucca Mountain Repository. Closure of a typical waste package involves a number of remote operations. Those involved typically include the placement of matched lids onto the waste package. The lids are then individually sealed to the waste package by welding. Currently, the waste package includes three lids. One lid is placed before movement of the waste package to the closure cell; the final two are placed inside the closure cell, where they are welded to the waste package. These and other important operations require considerable remote material handling within the cell environment. This paper discusses the remote material handling equipment, designs, functions, operations, and maintenance, relative to waste package closure.

  20. Advanced material testing in support of accurate sheet metal forming simulations

    NASA Astrophysics Data System (ADS)

    Kuwabara, Toshihiko

    2013-05-01

    This presentation is a review of experimental methods for accurately measuring and modeling the anisotropic plastic deformation behavior of metal sheets under a variety of loading paths: biaxial compression test, hydraulic bulge test, biaxial tension test using a cruciform specimen, multiaxial tube expansion test using a closed-loop electrohydraulic testing machine for the measurement of forming limit strains and stresses, combined tension-shear test, and in-plane stress reversal test. Observed material responses are compared with predictions using phenomenological plasticity models to highlight the importance of accurate material testing. Special attention is paid to the plastic deformation behavior of sheet metals commonly used in industry, and to verifying the validity of constitutive models based on anisotropic yield functions at a large plastic strain range. The effects of using appropriate material models on the improvement of predictive accuracy for forming defects, such as springback and fracture, are also presented.

  1. Large-strain quasi-static compression materials tests in support of penetration modeling research

    SciTech Connect

    Brandon, S.L.; Totten, J.J.

    1990-09-01

    Target penetration by projectiles typically generates large strains, at least locally. Hence, accurate analytic modeling of penetration demands that constitutive models be calibrated using large strain material test data. Tensile test data is limited by specimen necking (the Considere criterion), restricting attainable strains. Linear extrapolation of tensile data to target strains can seriously overestimate the material flow stress, resulting in erroneously stiff analytical predictions. That is, other tests which can attain larger strains often reveal a continually decreasing tangent modulus at large strains. We report quasistatic room temperature compression tests approaching true strains of {var epsilon} = {minus}1. A few tensile tests are included to illustrate the previous point. Materials tested are 7075-T651, 5083-H131, and 6061-T651 aluminum alloys, 4340 steel and X21-C tungsten alloy. 7 refs., 6 figs.

  2. Use of activated carbon and natural zeolite as support materials, in an anaerobic fluidised bed reactor, for vinasse treatment.

    PubMed

    Fernández, N; Fdz-Polanco, F; Montalvo, S J; Toledano, D

    2001-01-01

    In Cuba, the alcohol distillation process from cane sugar molasses, produces a final waste (vinasse), with an enormous polluting potential and a high sulfate content. Applying the anaerobic technology, most of the biodegradable organic matter can turn into biogas, rich in methane but with concentrations of sulfide above 1%. The present work develops two experiences with anaerobic fluidized bed reactors (AFBR) using both Cuban raw material, activated carbon and natural zeolite, as support media, with the purpose of obtaining high organic matter removal rates and keeping sulfide and ammonium concentrations in the permissible ranges. The reactors were operated during 120 days, achieving an organic loading rate of 10 kg COD/m3 day, with COD removal above 70%, and a methane production of 2 L/d. The activated carbon and natural zeolite used support materials in anaerobic fluidized bed reactors, and showed good results of distillery waste removal. PMID:11575071

  3. Comparing composite materials with structural steels in the design of the optical support structure of very large telescopes

    NASA Astrophysics Data System (ADS)

    Cheng, Andrew Y.; Li, Robert K.

    1992-03-01

    The method of finite element analysis is used to study some candidate composite materials: carbon filter reinforced epoxy and glass fiber reinforced epoxy. These composites may have real applications in the design of the optical support structures of very large telescopes where stringent thermomechanical stability are needed. The lightweight property of these materials allows one to build very stiff members for the optical support to withstand the structural deflections due to wind, vibration, and gravity. We have run finite element models of these composites using ABAQUS on a VAX VMS computer. Simple beams with rectangular cross- sections were computed for the composites with structural steel as a comparison. The static properties of these beams were studied.

  4. A Statistics-Based Material Property Analysis to Support TPS Characterization

    NASA Technical Reports Server (NTRS)

    Copeland, Sean R.; Cozmuta, Ioana; Alonso, Juan J.

    2012-01-01

    Accurate characterization of entry capsule heat shield material properties is a critical component in modeling and simulating Thermal Protection System (TPS) response in a prescribed aerothermal environment. The thermal decomposition of the TPS material during the pyrolysis and charring processes is poorly characterized and typically results in large uncertainties in material properties as inputs for ablation models. These material property uncertainties contribute to large design margins on flight systems and cloud re- construction efforts for data collected during flight and ground testing, making revision to existing models for entry systems more challenging. The analysis presented in this work quantifies how material property uncertainties propagate through an ablation model and guides an experimental test regimen aimed at reducing these uncertainties and characterizing the dependencies between properties in the virgin and charred states for a Phenolic Impregnated Carbon Ablator (PICA) based TPS. A sensitivity analysis identifies how the high-fidelity model behaves in the expected flight environment, while a Monte Carlo based uncertainty propagation strategy is used to quantify the expected spread in the in-depth temperature response of the TPS. An examination of how perturbations to the input probability density functions affect output temperature statistics is accomplished using a Kriging response surface of the high-fidelity model. Simulations are based on capsule configuration and aerothermal environments expected during the Mars Science Laboratory (MSL) entry sequence. We identify and rank primary sources of uncertainty from material properties in a flight-relevant environment, show the dependence on spatial orientation and in-depth location on those uncertainty contributors, and quantify how sensitive the expected results are.

  5. APPLICATION OF THE US DECISION SUPPORT TOOL FOR MATERIALS AND WASTE MANAGEMENT

    EPA Science Inventory

    EPA¿s National Risk Management Research Laboratory has led the development of a municipal solid waste decision support tool (MSW-DST). The computer software can be used to calculate life-cycle environmental tradeoffs and full costs of different waste management plans or recycling...

  6. Environmental Support Specialist, Block V, 17-6. Military Curriculum Materials for Vocational and Technical Education.

    ERIC Educational Resources Information Center

    Ohio State Univ., Columbus. National Center for Research in Vocational Education.

    This military-developed text contains the third section of a four-part course to train environmental support specialists. Covered in the individual sections are field sanitation, classes and sources of waste, composition and characteristics of sewage, principles of sewage treatment, primary waste treatment, secondary waste treatment, tertiary…

  7. Structural analysis in support of the waterborne transport of radioactive materials

    SciTech Connect

    Ammerman, D.J.

    1996-08-01

    The safety of the transportation of radioactive materials by road and rail has been well studied and documented. However, the safety of waterborne transportation has received much less attention. Recent highly visible waterborne transportation campaigns have led to DOE and IAEA to focus attention on the safety of this transportation mode. In response, Sandia National Laboratories is conducting a program to establish a method to determine the safety of these shipments. As part of that program the mechanics involved in ship-to-ship collisions are being evaluated to determine the loadings imparted to radioactive material transportation packages during these collisions. This paper will report on the results of these evaluations.

  8. The Efficacy of Educative Curriculum Materials to Support Geospatial Science Pedagogical Content Knowledge

    ERIC Educational Resources Information Center

    Bodzin, Alec; Peffer, Tamara; Kulo, Violet

    2012-01-01

    Teaching and learning about geospatial aspects of energy resource issues requires that science teachers apply effective science pedagogical approaches to implement geospatial technologies into classroom instruction. To address this need, we designed educative curriculum materials as an integral part of a comprehensive middle school energy…

  9. Covalent attachment of lysozyme to cotton/cellulose materials: protein verses solid support activation

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Covalent attachment of enzymes to cellulosic materials like cotton is of interest where either release or loss of enzyme activity over time needs to be avoided. The covalent attachment of an enzyme to a cellulosic substrate requires either activation of a protein side chain or an organic functional ...

  10. Language Practice with Multimedia Supported Web-Based Grammar Revision Material

    ERIC Educational Resources Information Center

    Baturay, Meltem Huri; Daloglu, Aysegul; Yildirim, Soner

    2010-01-01

    The aim of this study was to investigate the perceptions of elementary-level English language learners towards web-based, multimedia-annotated grammar learning. WEBGRAM, a system designed to provide supplementary web-based grammar revision material, uses audio-visual aids to enrich the contextual presentation of grammar and allows learners to…

  11. Using Japanese Curriculum Materials to Support Lesson Study outside Japan: Toward Coherent Curriculum

    ERIC Educational Resources Information Center

    Lewis, Catherine C.; Perry, Rebecca R.; Friedkin, Shelley

    2011-01-01

    Lesson study (jugyou kenkyuu) has spread outside Japan in the last decade, providing opportunities to see how lesson study fares in countries where the instructional practices and curriculum materials differ from those in Japan. This study reports an elementary mathematics lesson study cycle from the United States. To investigate the nature of the…

  12. A National Study of State Disseminated Materials' Incorporation of Research Supported Art Education Improvement Concepts.

    ERIC Educational Resources Information Center

    Chipley, Sheila M.; Chipley, Donald R.

    The study examined the extent to which recent art education concepts are reflected in materials circulated by state departments of education. Project staff members identified ten major concepts: aesthetic and humanistic education, environmental design, interrelated arts, visual literacy, community resource utilization, art education for…

  13. Satellite Material Type and Phase Function Determination in Support of Orbital Debris Size Estimation

    NASA Technical Reports Server (NTRS)

    Hejduk, M. D.; Cowardin, H. M.; Stansbery, Eugene G.

    2012-01-01

    In performing debris surveys of deep-space orbital regions, the considerable volume of the area to be surveyed and the increased orbital altitude suggest optical telescopes as the most efficient survey instruments; but to proceed this way, methodologies for debris object size estimation using only optical tracking and photometric information are needed. Basic photometry theory indicates that size estimation should be possible if satellite albedo and shape are known. One method for estimating albedo is to try to determine the object's material type photometrically, as one can determine the albedos of common satellite materials in the laboratory. Examination of laboratory filter photometry (using Johnson BVRI filters) on a set of satellite material samples indicates that most material types can be separated at the 1-sigma level via B-R versus R-I color differences with a relatively small amount of required resampling, and objects that remain ambiguous can be resolved by B-R versus B-V color differences and solar radiation pressure differences. To estimate shape, a technique advanced by Hall et al. [1], based on phase-brightness density curves and not requiring any a priori knowledge of attitude, has been modified slightly to try to make it more resistant to the specular characteristics of different materials and to reduce the number of samples necessary to make robust shape determinations. Working from a gallery of idealized debris shapes, the modified technique identifies most shapes within this gallery correctly, also with a relatively small amount of resampling. These results are, of course, based on relatively small laboratory investigations and simulated data, and expanded laboratory experimentation and further investigation with in situ survey measurements will be required in order to assess their actual efficacy under survey conditions; but these techniques show sufficient promise to justify this next level of analysis.

  14. Influence of Prosthetic Screw Material on Joint Stability in Passive and Non-Passive Implant-Supported Dentures

    PubMed Central

    Spazzin, Aloísio Oro; Henriques, Guilherme Elias Pessanha; de Arruda Nóbilo, Mauro Antônio; Consani, Rafael Leonardo Xediek; Correr-Sobrinho, Lourenço; Mesquita, Marcelo Ferraz

    2009-01-01

    Objectives: This study evaluated the influence of prosthetic screw material on joint stability in implantsupported dentures at two levels of fit. Methods: Ten mandibular implant-supported dentures were fabricated. Twenty cast models were fabricated using these dentures. Four groups (n=10) were tested, according to the vertical fit of the dentures [passive and non-passive] and prosthetic screw materials [titanium (Ti) or gold (Au) alloy]. The one-screw test was performed to quantify the vertical misfits using an optic microscope. The loosening torque for the prosthetic screws was measured 24 hours after the tightening torque (10 Ncm) using a digital torque meter. Data were analyzed by two-way ANOVA and Tukey’s test (α=0.05). Results: Overall, dentures with passive fit and Ti screws resulted in significantly higher loosening torque of the prosthetic screws (p<0.05). No significant interaction was found between fit level and screw material (p=0.199). The prosthetic screw material and fit of implant-supported dentures have an influence on screw joint stability. Ti screws presented higher joint stability than Au screws and minimum of misfit should be found clinically to improve the mechanical behavior of the screw joint. PMID:20148135

  15. Degradation of simazine from aqueous solutions by diatomite-supported nanosized zero-valent iron composite materials.

    PubMed

    Sun, Zhiming; Zheng, Shuilin; Ayoko, Godwin A; Frost, Ray L; Xi, Yunfei

    2013-12-15

    A novel composite material based on deposition of nanosized zero-valent iron (nZVI) particles on acid-leached diatomite was synthesised for the removal of a chlorinated contaminant in water. The nZVI/diatomite composites were characterised by X-ray diffraction, scanning electron microscopy, elemental analysis, transmission electron microscopy and X-ray photoelectron spectroscopy. Compared with the pure nZVI particles, better dispersion of nZVI particles on the surface or inside the pores of diatom shells was observed. The herbicide simazine was selected as the model chlorinated contaminant and the removal efficiency by nZVI/diatomite composite was compared with that of the pristine nZVI and commercial iron powder. It was found that the diatomite supported nZVI composite material prepared by centrifugation exhibits relatively better efficient activity in decomposition of simazine than commercial Fe, lab synthesised nZVI and composite material prepared via rotary evaporation, and the optimum experimental conditions were obtained based on a series of batch experiments. This study on immobilising nZVI particles onto diatomite opens a new avenue for the practical application of nZVI and the diatomite-supported nanosized zero-valent iron composite materials have potential applications in environmental remediation. PMID:24231330

  16. Highly Efficient Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over Gold Supported on Zinc Oxide Materials

    DOE PAGESBeta

    Chen, Hangning; Cullen, David A.; Larese, J. Z.

    2015-11-30

    We used Au/ZnO catalysts for liquid-phase selective hydrogenation of cinnamaldehyde to cinnamyl alcohol and compared with Au/Fe2O3 catalysts. To investigate the influence of the support on the hydrogenation activity and selectivity, three different Au/ZnO catalysts were synthesized, including Au/rod-tetrapod ZnO, Au/porous ZnO, and Au/ZnO-CP prepared using a coprecipitation method. Moreover, the influence of calcination temperature was also systematically investigated in this study. The characterization of Au/ZnO catalysts was performed using ICP, N2 adsorption/desorption isotherms, X-ray diffraction, scanning transmission electron microscopy, and X-ray photoelectron spectroscopy. Among all the supported Au catalysts prepared in this study, Au/ZnO-CP exhibits both the highest hydrogenationmore » activity and selectivity. Using a 1.5% Au/ZnO-CP catalyst, 100% selectivity could be achieved with 94.9% conversion. Finally, we find that the Au particle (size and shape), the ZnO support (size and surface texture) and the interaction between Au and ZnO are three important parameters for achieving a highly efficient Au/ZnO catalyst.« less

  17. Highly Efficient Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over Gold Supported on Zinc Oxide Materials

    SciTech Connect

    Chen, Hangning; Cullen, David A.; Larese, J. Z.

    2015-11-30

    We used Au/ZnO catalysts for liquid-phase selective hydrogenation of cinnamaldehyde to cinnamyl alcohol and compared with Au/Fe2O3 catalysts. To investigate the influence of the support on the hydrogenation activity and selectivity, three different Au/ZnO catalysts were synthesized, including Au/rod-tetrapod ZnO, Au/porous ZnO, and Au/ZnO-CP prepared using a coprecipitation method. Moreover, the influence of calcination temperature was also systematically investigated in this study. The characterization of Au/ZnO catalysts was performed using ICP, N2 adsorption/desorption isotherms, X-ray diffraction, scanning transmission electron microscopy, and X-ray photoelectron spectroscopy. Among all the supported Au catalysts prepared in this study, Au/ZnO-CP exhibits both the highest hydrogenation activity and selectivity. Using a 1.5% Au/ZnO-CP catalyst, 100% selectivity could be achieved with 94.9% conversion. Finally, we find that the Au particle (size and shape), the ZnO support (size and surface texture) and the interaction between Au and ZnO are three important parameters for achieving a highly efficient Au/ZnO catalyst.

  18. Demonstration of Super Cooled Ice as a Phase Change Material Heat Sink for Portable Life Support Systems

    NASA Technical Reports Server (NTRS)

    Leimkuehler, Thomas O.; Bue, Grant C.

    2009-01-01

    A phase change material (PCM) heat sink using super cooled ice as a nontoxic, nonflammable PCM is being developed. The latent heat of fusion for water is approximately 70% larger than most paraffin waxes, which can provide significant mass savings. Further mass reduction is accomplished by super cooling the ice significantly below its freezing temperature for additional sensible heat storage. Expansion and contraction of the water as it freezes and melts is accommodated with the use of flexible bag and foam materials. A demonstrator unit has been designed, built, and tested to demonstrate proof of concept. Both testing and modeling results are presented along with recommendations for further development of this technology.

  19. Graphene oxide supported copper oxide nanoneedles: An efficient hybrid material for removal of toxic azo dyes.

    PubMed

    Rajesh, Rajendiran; Iyer, Sahithya S; Ezhilan, Jayabal; Kumar, S Senthil; Venkatesan, Rengarajan

    2016-09-01

    Herein, we report a simple, one step synthesis of hybrid copper oxide nanoneedles on graphene oxide sheets (GO-CuONNs) through sonochemical method. The present method affords a facile mean for controlling effective concentration of the active CuO nanoneedles on the graphene oxide sheets, and also offers the necessary stability to the resulting GO-CuONNs structure for adsorption transformations.Furthermore, this hybrid GO-CuONNs is successfully employed in the removal of a series of hazardous ionic organic dyes namely coomassie brilliant blue, methylene blue, congo red and amidoblack 10B. Through careful investigation of the material, we found that the synergetic effect between CuONNs and GO play a significant role in the adsorption of all the dyes studied. The prepared hybrid material contains both hydrophobic and hydrophilic environment which is expected to enhance the electrostatic interaction between the adsorbent and the dye molecules, consequently favouring the adsorption process. PMID:27208759

  20. Graphene oxide supported copper oxide nanoneedles: An efficient hybrid material for removal of toxic azo dyes

    NASA Astrophysics Data System (ADS)

    Rajesh, Rajendiran; Iyer, Sahithya S.; Ezhilan, Jayabal; Kumar, S. Senthil; Venkatesan, Rengarajan

    2016-09-01

    Herein, we report a simple, one step synthesis of hybrid copper oxide nanoneedles on graphene oxide sheets (GO-CuONNs) through sonochemical method. The present method affords a facile mean for controlling effective concentration of the active CuO nanoneedles on the graphene oxide sheets, and also offers the necessary stability to the resulting GO-CuONNs structure for adsorption transformations.Furthermore, this hybrid GO-CuONNs is successfully employed in the removal of a series of hazardous ionic organic dyes namely coomassie brilliant blue, methylene blue, congo red and amidoblack 10B. Through careful investigation of the material, we found that the synergetic effect between CuONNs and GO play a significant role in the adsorption of all the dyes studied. The prepared hybrid material contains both hydrophobic and hydrophilic environment which is expected to enhance the electrostatic interaction between the adsorbent and the dye molecules, consequently favouring the adsorption process.

  1. Very High Temperature Reactor (VHTR) Survey of Materials Research and Development Needs to Support Early Deployment

    SciTech Connect

    Eric Shaber; G. Baccaglini; S. Ball; T. Burchell; B. Corwin; T. Fewell; M. Labar; P. MacDonald; P. Rittenhouse; Russ Vollam; F. Southworth

    2003-01-01

    The VHTR reference concept is a helium-cooled, graphite moderated, thermal neutron spectrum reactor with an outlet temperature of 1000 C or higher. It is expected that the VHTR will be purchased in the future as either an electricity producing plant with a direct cycle gas turbine or a hydrogen producing (or other process heat application) plant. The process heat version of the VHTR will require that an intermediate heat exchanger (IHX) and primary gas circulator be located in an adjoining power conversion vessel. A third VHTR mission - actinide burning - can be accomplished with either the hydrogen-production or gas turbine designs. The first ''demonstration'' VHTR will produce both electricity and hydrogen using the IHX to transfer the heat to either a hydrogen production plant or the gas turbine. The plant size, reactor thermal power, and core configuration will be designed to assure passive decay heat removal without fuel damage during accidents. The fuel cycle will be a once-through very high burnup low-enriched uranium fuel cycle. The purpose of this report is to identify the materials research and development needs for the VHTR. To do this, we focused on the plant design described in Section 2, which is similar to the GT-MHR plant design (850 C core outlet temperature). For system or component designs that present significant material challenges (or far greater expense) there may be some viable design alternatives or options that can reduce development needs or allow use of available (cheaper) materials. Nevertheless, we were not able to assess those alternatives in the time allotted for this report and, to move forward with this material research and development assessment, the authors of this report felt that it was necessary to use a GT-MHR type design as the baseline design.

  2. SUPPORTING SAFE STORAGE OF PLUTONIUM-BEARING MATERIALS THROUGH SCIENCE, ENGINEERING AND SURVEILLANCE

    SciTech Connect

    Dunn, K.; Chandler, G.; Gardner, C.; Louthan, M.; Mcclard, J.

    2009-11-10

    Reductions in the size of the U. S. nuclear weapons arsenal resulted in the need to store large quantities of plutonium-bearing metals and oxides for prolonged periods of time. To assure that the excess plutonium from the U. S. Department of Energy (DOE) sites was stored in a safe and environmentally friendly manner the plutonium-bearing materials are stabilized and packaged according to well developed criteria published as a DOE Standard. The packaged materials are stored in secure facilities and regular surveillance activities are conducted to assure continuing package integrity. The stabilization, packaging, storage and surveillance requirements were developed through extensive science and engineering activities including those related to: plutonium-environment interactions and container pressurization, corrosion and stress corrosion cracking, plutonium-container material interactions, loss of sealing capability and changes in heat transfer characteristics. This paper summarizes some of those activities and outlines ongoing science and engineering programs that assure continued safe and secure storage of the plutonium-bearing metals and oxides.

  3. Interplay between synchronization of multivesicular release and recruitment of additional release sites support short-term facilitation at hippocampal mossy fiber to CA3 pyramidal cells synapses.

    PubMed

    Chamberland, Simon; Evstratova, Alesya; Tóth, Katalin

    2014-08-13

    Synaptic short-term plasticity is a key regulator of neuronal communication and is controlled via various mechanisms. A well established property of mossy fiber to CA3 pyramidal cell synapses is the extensive short-term facilitation during high-frequency bursts. We investigated the mechanisms governing facilitation using a combination of whole-cell electrophysiological recordings, electrical minimal stimulation, and random-access two-photon microscopy in acute mouse hippocampal slices. Two distinct presynaptic mechanisms were involved in short-term facilitation, with their relative contribution dependent on extracellular calcium concentration. The synchronization of multivesicular release was observed during trains of facilitating EPSCs recorded in 1.2 mM external Ca(2+) ([Ca(2+)]e). Indeed, covariance analysis revealed a gradual augmentation in quantal size during trains of EPSCs, and application of the low-affinity glutamate receptor antagonist γ-D-glutamylglycine showed an increase in cleft glutamate concentration during paired-pulse stimulation. Whereas synchronization of multivesicular release contributed to the facilitation in 1.2 mM [Ca(2+)]e, variance-mean analysis showed that recruitment of more release sites (N) was likely to account for the larger facilitation observed in 2.5 mM [Ca(2+)]e. Furthermore, this increase in N could be promoted by calcium microdomains of heterogeneous amplitudes observed in single mossy fiber boutons. Our findings suggest that the combination of multivesicular release and the recruitment of additional release sites act together to increase glutamate release during burst activity. This is supported by the compartmentalized spatial profile of calcium elevations in boutons and helps to expand the dynamic range of mossy fibers information transfer. PMID:25122902

  4. Material grain size characterization method based on energy attenuation coefficient spectrum and support vector regression.

    PubMed

    Li, Min; Zhou, Tong; Song, Yanan

    2016-07-01

    A grain size characterization method based on energy attenuation coefficient spectrum and support vector regression (SVR) is proposed. First, the spectra of the first and second back-wall echoes are cut into several frequency bands to calculate the energy attenuation coefficient spectrum. Second, the frequency band that is sensitive to grain size variation is determined. Finally, a statistical model between the energy attenuation coefficient in the sensitive frequency band and average grain size is established through SVR. Experimental verification is conducted on austenitic stainless steel. The average relative error of the predicted grain size is 5.65%, which is better than that of conventional methods. PMID:26995732

  5. Strength Analysis and Process Simulation of Subway Contact Rail Support Bracket of Composite Materials

    NASA Astrophysics Data System (ADS)

    Fedulov, Boris N.; Safonov, Alexander A.; Sergeichev, Ivan V.; Ushakov, Andrey E.; Klenin, Yuri G.; Makarenko, Irina V.

    2016-05-01

    An application of composites for construction of subway brackets is a very effective approach to extend their lifetime. However, this approach involves the necessity to prevent process-induced distortions of the bracket due to thermal deformation and chemical shrinkage. At present study, a process simulation has been carried out to support the design of the production tooling. The simulation was based on the application of viscoelastic model for the resin. Simulation results were verified by comparison with results of manufacturing experiments. To optimize the bracket structure the strength analysis was carried out as well.

  6. Remediation of metal-contaminated soils with the addition of materials--part I: characterization and viability studies for the selection of non-hazardous waste materials and silicates.

    PubMed

    González-Núñez, R; Alba, M D; Orta, M M; Vidal, M; Rigol, A

    2011-11-01

    Contamination episodes in soils require interventions to attenuate their impact. These actions are often based on the addition of materials to increase contaminant retention in the soil and to dilute the contaminant concentration. Here, non-hazardous wastes (such as sugar foam, fly ash and a material produced by the zeolitization of fly ash) and silicates (including bentonites) were tested and fully characterized in the laboratory to select suitable materials for remediating metal-contaminated soils. Data from X-ray fluorescence (XRF), N(2) adsorption/desorption isotherms, X-ray diffraction (XRD) and scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM-EDX) analyses revealed the chemical composition, specific surface area and the phases appearing in the materials. A pH titration test allowed the calculation of their acid neutralization capacity (ANC). The metal sorption and desorption capacities of the waste materials and silicates were also estimated. Sugar foam, fly ash and the zeolitic material were the best candidate materials. Sugar foam was selected because of its high ANC (17000 meq kg(-1)), and the others were selected because of their larger distribution coefficients and lower sorption reversibilities than those predicted in the contaminated soils. PMID:22018740

  7. Synthesis and catalytic application of palladium nanoparticles supported on kaolinite-based nanohybrid materials.

    PubMed

    Ngnie, Gaelle; Dedzo, Gustave K; Detellier, Christian

    2016-05-31

    Palladium nanoparticles (PdNPs) were deposited on the surface of the modified clay mineral, kaolinite. To improve compatibility, abundance and control of the size of the nanoparticles, kaolinite was modified by the grafting of an amino alcohol (triethanolamine (TEA)) and an ionic liquid (1-(2-hydroxyethyl)-3-methylimidazolium (ImIL)). Characterization techniques (XRD, TGA, solid state (13)C NMR and FTIR spectroscopy) confirmed the effective grafting of these compounds on the internal surface of kaolinite. After the synthesis of PdNPs onto clay particles, TEM allowed the visualization of abundant PdNPs with sizes ranging from 4 to 6 nm, uniformly distributed onto the platelets of modified kaolinite. Unmodified clay showed low abundance and random distribution of the nanoparticles. The catalysts obtained were effective for the catalytic reduction of 4-nitrophenol (4-NP), the material with TEA being the most effective. These materials have exhibited excellent performance during the Heck and particularly the Suzuki-Miyaura coupling reactions, with reaction yields up to 100%. These catalysts showed a very slight loss in activity for three consecutive catalytic cycles (less than 10% decrease of the activity compared to the first cycle). This was an evidence that the prior grafting modification of kaolinite helps in significantly improving the quality of the synthesized NPs and also promotes their strong attachment onto the clay mineral surface. PMID:27160392

  8. Material Testing in Support of the ISS Electrochemical Disinfection Feasibility Study

    NASA Technical Reports Server (NTRS)

    Clements, Anna; Shindo, David; Modica, Cathy

    2011-01-01

    The International Space Station Program recognizes the risk of microbial contamination in their potable and non-potable water sources. With the end of the Space Shuttle Program, the ability to send up shock-kits of biocides in the event of an outbreak becomes even more difficult. Currently, the US Segment water system relies primarily on iodine to mitigate contamination concerns. To date, several small cases of contamination have occurred which have been remediated. NASA, however, realizes that having a secondary method of combating a microbial outbreak is a prudent investment. NASA is looking into developing hardware that can generate biocides electrochemically, and potentially deploying that hardware. The specific biocides that the technology could generate include: hydrogen peroxide, oxone, hypochlorite and peracetic acid. In order to use these biocides on deployed water systems, the project must determine that all the materials in the potential application are compatible with the biocides at their anticipated administered concentrations. This paper will detail the materials test portion of the feasibility assessment including the plan for both metals and non-metals along with results to date.

  9. Effect of the addition of by-product ash of date palms on the mechanical characteristics of gypsum-calcareous materials used in road construction

    NASA Astrophysics Data System (ADS)

    Khellou, A.; Kriker, A.; Hafssi, A.; Belbarka, K.; Baali, K.

    2016-07-01

    The gypsum-calcareous materials, also known as the crusting tuff, are used in the pavement layers of low -traffic road and considered as the materials of first choice in the Saharan region of Algeria. The objective of this paper is to study the mechanical characteristics of tuff of Ouargla town that is situated in the Southeast of Algeria, by adding different percentage of ash resulted from the combustion of by-products of date palms, such as 4%, 8% and l2%, to the tuff. The results obtained have shown a remarkable improvement both in compressive strength at different ages and in the bearing index in the two cases immediate and after immersion in water. These characteristics of the mixture (tuff+ash) reach their maximum values at the 8% of ash addition.

  10. Characterization and catalytic performance of heteropoly acid H4SiW12O40 supported on nanoporous materials.

    PubMed

    Chen, Fengxi; Ma, Jiping; Dong, Zhibing; Liu, Rong

    2014-09-01

    Heteropoly acid H4SiW12O40 (SiW) has been supported on different nanoporous materials and characterized by powder X-ray diffraction (XRD), FTIR, HRTEM, N2 physisorption, and thermal analysis. No SiW diffraction peaks are observed after loading 33-50 wt% of SiW on various mesoporous materials (pore size: -30 Å) except for siliceous MCM-48. In contrast, the SiW diffraction peaks appear at 14 wt% loading on zeolite EMT with micropore size of ca. 7.4 x 6.5 Å. Supported SiW retains the Keggin structure on mesopore surface. The cubic mesostructure of MCM-48 is stable while MCM-41 loses its regular hexagonal mesostructure upon loading SiW. Several factors account for different behaviours of various supports, including pore size, curvature of mesopore interface and interaction between SiW and aluminium sites in the framework. The resulting 33-50 wt% SiW/MCM-48 solid acid catalysts have large surface area (- 550 m2/g), regular pore arrangement with uniform pore size (- 25 Å), finely dispersed SiW and good thermal stability. They exhibit significantly improved activity in acid-catalyzed cracking of long-chain hydrocarbons in comparison with bulk SiW and SiW/MCM-41. PMID:25924405

  11. Graphene supported Li2SnO3 as anode material for lithium-ion batteries

    NASA Astrophysics Data System (ADS)

    Zhao, Yang; Huang, Ying; Wang, Qiufen; Wang, XiaoYa; Zong, Meng; Wu, Haiwei; Zhang, Wei

    2013-09-01

    The graphene supported Li2SnO3 composites were prepared via a deoxidation technique. The structure, morphology and electrochemical properties of the composites were detected by means of XRD, SEM, TEM, Raman, TGA and electrochemical measurements. The Li2SnO3 powders could be distributed on the graphene sheets (GNS). The Li2SnO3/GNS composites exhibit good electrochemical performance with high capacity and good cycling stability (582.2 mAh/g after 50 cycles at 60 mA/g). The performance is ascribed to the presence of graphene keeping the structure stable. The composites Li2SnO3/GNS exhibited a better electrochemical property than Li2SnO3 and graphene.

  12. Supporting online materials for mineralogy and petrology of Comet81P/Wild 2 nucleus samples

    SciTech Connect

    Zolensky, Michael E.; Zega, Thomas J.; Yano, Hajime; Wirick, Sue; Westphal, Andrew J.; Weisberg, Mike K.; Weber, Iris; Warren, Jack L.; Velbel, Michael A.; Tsuchiyama, Akira; Tsou, Peter; Toppani, Alice; Tomioka, Naotaka; Tomeoka, Kazushige; Teslich, Nick; Taheri, Mitra; Susini, Jean; Stroud, Rhonda; Stephan, Thomas; Stadermann, Frank J.; Snead, Christopher J.; Simon, Steven B.; Simionovici, Alexandre; See,Thomas H.; Robert Francois; Rietmeijer, Frans J.M.; Rao, William; Perronnet, Murielle C.; Papanastassiou, Dimitri A.; Okudaira, Kyoko; Ohsumi, Kazumasa; Ohnishi, Ichiro; Nakamura-Messenger, Keilo; Nakamura,Tomoki; Mostefaoui, Smail; Mikouchi, Takashi; Meibom, Anders; Matrajt,Graciela; Marcus, Matthew A.; Leroux, Hugues; Lemelle, Laurence; Antonio,Loan Le; Lanzirotti, Antonio; Langenhorst, Falko; Krot, Alexander N.; Keller, Lindsay P.; Kearsley, Anton T.; Joswiak, Davis; Jacob, Damien; Ishii, Hope; Harvey, Ralph; Hagiya, Kenji; Grossman, Lawrence; Grossman,Jeffrey N.; Graham, Giles A.; Gounelle, Matthieu; Gillet, Philippe; Genge, Matthew J.; Flynn, George; Ferroir, Tristan; Fallow, Stewart; Ebel, Denton S.; Dai, Zu Rong; Cordier, Patrick; Clark, Benton; Chi,Miaofang; Butterworth, Anna L.; Brownlee, Donald E.; Bridges, John C.; Brennan, Sean; Brearley, Adrian; Bradley, John P.; Bleuet, Pierre; Bland,Phil A.; Bastien, Ron

    2006-01-01

    The bulk of the comet 81P/Wild 2 (hereafter Wild 2) samples returned to Earth by the Stardust spacecraft appear to be weakly constructed mixtures of nanometer-scale grains, with occasional much larger (over 1 micrometer) ferromagnesian silicates, Fe-Ni sulfides, Fe-Ni metal, and accessory phases. The very wide range of olivine and low-Ca pyroxene compositions in comet Wild 2 requires a wide range of formation conditions, probably reflecting very different formation locations in the protoplanetary disk. The restricted compositional ranges of Fe-Ni sulfides, the wide range for silicates, and the absence of hydrous phases indicate that comet Wild 2 experienced little or no aqueous alteration. Less abundant Wild 2 materials include a refractory particle, whose presence appears to require radial transport in the early protoplanetary disk.

  13. Synthesis of Pt/PEI-MWCNT composite materials on polyethyleneimine-functionalized MWNTs as supports

    SciTech Connect

    Yi, Sung-Chul; Jung, Chi Young; Kim, Wha Jung

    2011-12-15

    Graphical abstract: Schematic diagram for (a) the preparation of Pt/MWCNT functionalized with PEI and (b) TEM of Pt/PEI-MWCNT. Highlights: Black-Right-Pointing-Pointer We prepared Pt/PEI/MWCNT where MWCNT was first functionalized by PEI (polyethyleneimine) followed by Pt deposit onto it. Black-Right-Pointing-Pointer PEI functionalization provided high density homogeneous functional groups on MWCNT's sidewall. Black-Right-Pointing-Pointer Cationic PEI leads to homogeneous dispersion in solutions such as water and organic solvents. Black-Right-Pointing-Pointer Pt/PEI/MWCNT catalyst exhibits excellent electrocatalytic activity compared to that of Pt/MWCNT catalyst obtained with polyvinylpyrrolidine (PVP). -- Abstract: Composite materials with highly dispersed platinum (Pt) nanoparticles on multiwalled carbon nanotubes (MWCNTs), functionalized with polyethyleneimine (PEI) by a noncovalent method were prepared. The PEI-functionalization provided high density homogeneous functional groups on the MWCNTs' sidewalls for binding Pt nanoparticles. Cationic PEI leads to homogeneous dispersion in solutions such as water and organic solvents. The effects of a reducing agent on the Pt nanoparticles that form on the surfaces of the MWCNT were studied by varying the molar ratio of NaOH to H{sub 2}PtCl{sub 6}. These composite materials were characterized with transmission electron micrograph (TEM), X-ray diffractometer (XRD) and X-ray photoelectron spectroscopy (XPS). The Pt/PEI-MWCNT catalyst exhibits excellent electrocatalytic activity and compared with Pt/PVP-MWCNT catalysts obtained with polyvinylpyrrolidone (PVP). Finally, the cyclic voltammogram of methanol electrooxidation for Pt/PEI-MWCNT shows better tolerance to CO and methanol oxidation to CO{sub 2} than of Pt/PVP-MWCNT.

  14. Telechelic Poly(2-oxazoline)s with a biocidal and a polymerizable terminal as collagenase inhibiting additive for long-term active antimicrobial dental materials

    PubMed Central

    Fik, Christoph P.; Konieczny, Stefan; Pashley, David H.; Waschinski, Christian J.; Ladisch, Reinhild S.; Salz, Ulrich; Bock, Thorsten; Tiller, Joerg C.

    2015-01-01

    Although modern dental repair materials show excellent mechanical and adhesion properties, they still face two major problems: First, any microbes that remain alive below the composite fillings actively decompose dentin and thus, subsequently cause secondary caries. Second, even if those microbes are killed, the extracellular proteases such as MMP, remain active and can still degrade collagenousdental tissue. In order to address both problems, a poly(2-methyloxazoline) with a biocidal quaternary ammonium and a polymerizable methacrylate terminal was explored as additive for a commercial dental adhesive. It could be demonstrated that the adhesive rendered the adhesive contact-active antimicrobial against S. mutans at a concentration of only 2.5 wt% and even constant washing with water for 101 days did not diminish this effect. Increasing the amount of the additive to 5 wt% allowed killing S. mutans cells in the tubuli of bovinedentin upon application of the adhesive. Further, the additive fully inhibited bacterial collagenase at a concentration of 0.5 wt% and reduced human recombinant collagenase MMP-9 to 13% of its original activity at that concentration. Human MMPs naturally bound to dentin were inhibited by more than 96% in a medium containing 5 wt% of the additive. Moreover, no adverse effect on the enamel/dentine shear bond strength was detected in combination with a dental composite. PMID:25130877

  15. Optical Property Characterization of Far IR Materials Critical for CLARREO Mission Support

    NASA Astrophysics Data System (ADS)

    Hanssen, L. M.; Wilthan, B.; Mekhontsev, S.; Monte, C.; Hollandt, J.; McKenna, P.; Szczesniak, M.

    2010-12-01

    The Climate Absolute Radiance and Refractivity Observatory (CLARREO) and other climate science and remote sensing applications require accurate thermal and far infrared (IR) spectral radiance measurements, which are dependent on reference blackbody sources that have high and well-characterized spectral emissivity. The design and performance of blackbody sources are strongly affected by the spectral emittance of available coatings. Hence the emittance or reflectance of such coatings need to be accurately characterized. The measurement metrology for the reflectance of near-ambient targets in the thermal IR spectral range (2.5 to 15 microns) is well established and validated. The equivalent metrology for the far IR spectral range (15 to 50 microns and longer) is currently being established at National Measurement Institutes (NMIs), such as the National Institute of Standards and Technology (NIST) and at the Physikalisch-Technische Bundesanstalt (PTB), but will take several years to become operational and validated. Other existing facilities, such as at Surface Optics Corporation (SOC), do not have well characterized uncertainty budgets and are not traceable to the SI, but may be useful to provide support of the R&D for CLARREO. The direct measurement of the spectral emittance can also be used to obtain or validate reflectance data, but until cryo-vacuum facilities become fully functional at an NMI, such measurements are possible only for targets at elevated temperatures (typically above 200 °C). This limitation prevents the characterization of several critically important coatings. This paper describes ongoing efforts to establish the uncertainty of reflectance measurements at the SOC calibration facility over the far IR spectral range. For this purpose, NIST and PTB emittance facilities are used to measure the spectral emittance of transfer standard targets at 200 °C at wavelengths from 10 to 100 microns. Subsequently, these samples are measured at the SOC facility

  16. A hybrid plasma technology life support system for the generation of oxygen on Mars: Considerations on materials and geometry

    NASA Astrophysics Data System (ADS)

    Gruenwald, J.

    2016-06-01

    As there is a growing interest in conducting human missions to Mars, the need for suitable life support systems becomes more and more important. The reliability of such systems has to increase with the duration of manned missions. Furthermore the maintenance requirements have to be low in order to ensure their efficient use over a long period of time. A proposal for a hybrid life support system that is based on plasma technology for the creation of oxygen from the dissociation of carbon dioxide is given in this paper. The main focus lies on geometrical considerations regarding the optimal shape of the main reactor chamber as well as on suitable materials, which are most promising for the construction of such a system.

  17. Cyclophosphazene based conductive polymer-carbon nanotube composite as novel supporting material for methanol fuel cell applications.

    PubMed

    Prasanna, Dakshinamoorthy; Selvaraj, Vaithilingam

    2016-06-15

    This present study reports the development of novel catalyst support of amine terminated cyclophosphazene/cyclophosphazene/hexafluoroisopropylidenedianiline-carbon nanotube (ATCP/CP/HFPA-CNT) composite. The ATCP/CP/HFPA-CNT composite has been used as a catalyst support for platinum (Pt) and platinum-gold (Pt-Au) nanoparticles towards electrooxidation of methanol in alkaline medium. The obtained anode materials were characterized by X-ray diffraction, transmission electron microscope and energy dispersive X-ray analysis. Electrocatalytic performances of Pt/ATCP/CP/HFPA-CNT and Pt-Au/ATCP/CP/HFPA-CNT catalysts were investigated by cyclic voltammetry, CO stripping and chronoamperometric techniques. The electrooxidation of methanol and CO stripping results conclude that the metal nanocatalyst embedded with ATCP/CP/HFPA-CNT composite shows significantly higher anodic oxidation current, more CO tolerance and lower onset potential when compared to that of the Pt/CNT and Pt/C (Vulcan carbon) catalysts. PMID:27016917

  18. Leukopak PBMC Sample Processing for Preparing Quality Control Material to Support Proficiency Testing Programs

    PubMed Central

    Garcia, Ambrosia; Keinonen, Sarah; Sanchez, Ana M.; Ferrari, Guido; Denny, Thomas N.; Moody, M. Anthony

    2014-01-01

    External proficiency testing programs designed to evaluate the performance of end-point laboratories involved in vaccine and therapeutic clinical trials form an important part of clinical trial quality assurance. Good Clinical Laboratory Practice (GCLP) guidelines recommend both assay validation and proficiency testing for assays being used in clinical trials, and such testing is facilitated by the availability of large numbers of well-characterized test samples. These samples can be distributed to laboratories participating in these programs and allow monitoring of laboratory performance over time and among participating sites when results are obtained with samples derived from a large master set. The leukapheresis procedure provides an ideal way to collect samples from participants that can meet the required number of cells to support these activities. The collection and processing of leukapheresis samples requires tight coordination between the clinical and laboratory teams to collect, process, and cryopreserve large number of samples within the established ideal time of ≤8 hours. Here, we describe our experience with a leukapheresis cryopreseration program that has been able to preserve the functionality of cellular subsets and that provides the sample numbers necessary to run an external proficiency testing program. PMID:24928650

  19. Material selection and evaluation of new encapsulation compounds for electric cables for launch support system

    NASA Technical Reports Server (NTRS)

    Ray, Asit K.

    1992-01-01

    Eight urethane compounds were evaluated as possible replacement for the existing encapsulating compoounds for electrical cables for the Launch Support System at Kennedy Space Center (KSC). The existing encapsulating compound, PR-1535, contains the curative MOCA 4-4'-Methylene-BIS (2-chloroaniline), which is a suspect carcinogen and hence may be the subject of further restrictions of its use by the Occupational Safety and Health Administration (OSHA). The samples made in the configuration of cable joints and in the form of disks were evaluated for flammability and hypergolic compatibility. These also underwent accelerated weatherability tests that measured the residual hardness of the exposed samples. Three candidates and the existing compound passed the hardness test. Of these, only one candidate and the existing compound passed the flammability test. The thermal and hydrolytic stability (weatherability) of these samples was studied using thermogravimetric analysis (DSC) techniques. The TMA and DSC data correlated with the residual hardness data; whereas, the TGA data showed no correlation. A hypergolic compatibility test will be conducted on the compound V-356-HE80, which passed both the flammability and accelerated weatherability tests.

  20. An analytical calculation of the fluid load support fraction in a biphasic material: An alternative technique

    PubMed Central

    Stops, A.J.F.; Wilcox, R.K.; Jin, Z.

    2012-01-01

    Background The fluid load support fraction (WF/WT) can be used to define the mechanical contribution of the interstitial fluid (WF) to the total force (WT) in the deformation of cartilage. Traditionally, WF/WT is calculated using complex experimental setups or time-consuming micromechanical poroelastic Finite Element (FE) simulations. Aim To define and validate a fast and efficient technique to predict WF/WT using an analytical approach that can be applied without micromechanical detail or experimental measurement. Methodology Poroelastic FE simulations defined accurate values of WF/WT for a range of loading configurations and were used to validate subsequent predictions. The analytical prediction of WF/WT used elastic contact mechanics to calculate WF, and viscoelastic FE representation to calculate WT. Subsequently, these independent calculations of WF and WT provided values of WF/WT that were compared with the poroelastic FE calculations. Results and discussion The analytical prediction of WF/WT proved effective and suitably accurate (mean difference S<0.05). This technique demonstrated how WF and WT can be determined independently, without a biphasic constitutive model. Here we used viscoelasticity to calculate WT as an example, however, WT could be measured experimentally or predicted computationally. PMID:23026695

  1. The Infrastructure Necessary to Support a Sustainable Material Protection, Control and Accounting (MPC&A) Program in Russia

    SciTech Connect

    Bachner, Katherine M.; Mladineo, Stephen V.

    2011-07-20

    The NNSA Material Protection, Control, and Accounting (MPC&A) program has been engaged for fifteen years in upgrading the security of nuclear materials in Russia. Part of the effort has been to establish the conditions necessary to ensure the long-term sustainability of nuclear security. A sustainable program of nuclear security requires the creation of an indigenous infrastructure, starting with sustained high level government commitment. This includes organizational development, training, maintenance, regulations, inspections, and a strong nuclear security culture. The provision of modern physical protection, control, and accounting equipment to the Russian Federation alone is not sufficient. Comprehensive infrastructure projects support the Russian Federation's ability to maintain the risk reduction achieved through upgrades to the equipment. To illustrate the contributions to security, and challenges of implementation, this paper discusses the history and next steps for an indigenous Tamper Indication Device (TID) program, and a Radiation Portal Monitoring (RPM) program.

  2. Novel functionalized polymeric fabric and fiber material as solid support for solid-phase synthesis and biomedical applications

    NASA Astrophysics Data System (ADS)

    Xiang, Bei

    The aim of the research is to develop novel polymer solid support by modifying or fabricating polymeric fibrous materials for peptide synthesis and biomedical applications. Originally chemical inert isotactic polypropylene (iPP) fabric was utilized and modified to serve as a functional flexible planar solid support for solid phase peptide synthesis. The modification was achieved through thermal initiated radical grafting polymerization using acrylic acid, poly (ethylene glycol) diacrylate as monomers, and benzoyl peroxide as radical initiator. The iPP fabric was successfully functionalized and possessing as high as 0.7mmol/g carboxylic acid groups. Peptide ligand LHPQF was successfully synthesized on the new functional planar support. Specific enzyme immobilization was fulfilled on the functional iPP fabric support. A commercially available ethylene-acrylic acid copolymer was made into ultrafine copolymer fiber bundles which are composed of nanofibers with diameters ranging from 200nm to 800nm. Various mixing ratios of copolymer/matrix materials were utilized to explore the effect on the final nanofiber physical properties including morphology and stability in solvents. The surface carboxylic acid groups were further converted to amino groups before the functional nanofibers can be applied in solid phase peptide synthesis. Two peptide ligands, LHPQF and HWRGWV, were also successfully synthesized on the nanofiber bundles. Streptavidin and human immunoglobulin G specific binding with the corresponding ligand which was anchored on the nanofibers was conducted successfully to illustrate the potential applications of the nanofiber materials in biomedical field. Further study on the dispersion of the ethylene-acrylic acid nanofiber bundles was pursued to take advantage of the super high active surface area of functional nanofibers. To manipulate the polymer nanofibers during synthesis and bio-assays, a technique was developed to controllably assemble and disperse the

  3. Development of additives in negative active-material to suppress sulfation during high-rate partial-state-of-charge operation of lead-acid batteries

    NASA Astrophysics Data System (ADS)

    Sawai, Ken; Funato, Takayuki; Watanabe, Masashi; Wada, Hidetoshi; Nakamura, Kenji; Shiomi, Masaaki; Osumi, Shigeharu

    Additives in the negative active-material of lead-acid batteries were examined to determine whether they could prevent progressive accumulation of lead sulfate (PbSO 4) in negative plates during high-rate partial-state-of-charge (HRPSoC) operation. This phenomenon is caused by progressive growth of PbSO 4 particles and a lack of conductive paths near these PbSO 4 particles. Barium sulfate (BaSO 4) particles in various sizes and synthetic lignin were added to the negative active-material to control PbSO 4 particle size during HRPSoC cycle-life. Some types of carbon fibres were also added to form conductive paths around the PbSO 4 particles. Synthetic lignin was found to be the most effective additive for improving battery life in HRPSoC cycle-life tests, whereas the other factors such as BaSO 4 size or carbon fibre extended less influence. The growth rate of PbSO 4 particles per cycle was much lower in a cell with synthetic lignin than in a cell with natural lignin.

  4. Materials

    NASA Technical Reports Server (NTRS)

    Glaessgen, Edward H.; Schoeppner, Gregory A.

    2006-01-01

    NASA Langley Research Center has successfully developed an electron beam freeform fabrication (EBF3) process, a rapid metal deposition process that works efficiently with a variety of weldable alloys. The EBF3 process can be used to build a complex, unitized part in a layer-additive fashion, although the more immediate payoff is for use as a manufacturing process for adding details to components fabricated from simplified castings and forgings or plate products. The EBF3 process produces structural metallic parts with strengths comparable to that of wrought product forms and has been demonstrated on aluminum, titanium, and nickel-based alloys to date. The EBF3 process introduces metal wire feedstock into a molten pool that is created and sustained using a focused electron beam in a vacuum environment. Operation in a vacuum ensures a clean process environment and eliminates the need for a consumable shield gas. Advanced metal manufacturing methods such as EBF3 are being explored for fabrication and repair of aerospace structures, offering potential for improvements in cost, weight, and performance to enhance mission success for aircraft, launch vehicles, and spacecraft. Near-term applications of the EBF3 process are most likely to be implemented for cost reduction and lead time reduction through addition of details onto simplified preforms (casting or forging). This is particularly attractive for components with protruding details that would require a significantly large volume of material to be machined away from an oversized forging, offering significant reductions to the buy-to-fly ratio. Future far-term applications promise improved structural efficiency through reduced weight and improved performance by exploiting the layer-additive nature of the EBF3 process to fabricate tailored unitized structures with functionally graded microstructures and compositions.

  5. Novel supported bimetallic carbide catalysts for coprocessing of coal with waste materials

    SciTech Connect

    S.T. Oyama; D.F. Cox; C. Song; F. Allen

    1999-12-15

    In this reporting period the authors have continued their investigation of bimetallic nitride and carbide compounds for use in coprocessing of coal and waste plastics or rubber. Following up on their finding of a class of bimetallic nitrides, reported in the last period, they now report on a new family of bimetallic oxycarbides M{sup I}-M{sup II}-O-C (M{sup I} = Mo, W; M{sup II} = V, Nb, Cr, Fe, Co, Ni). They have carried out a preliminary test of the compounds with a model coal liquid feed and find that, in general, these carbides are even more active than the nitrides. They have identified Nb-Mo-O-C as the most promising catalyst, and this catalyst together with Mo{sub 2}C, the most active single-metal carbide are being investigated for the coprocessing reaction. Comparison is made to standard sulfide catalysts. The latter reaction is carried out in batch autoclave systems, so that preliminary tests are first carried out with a simpler five-component feedstock. The feedstock is a multi-component model mixture that simulates the combined feed of coal and waste materials. The idea is to use different compounds that are specific for each reaction type but have no overlapping products. The proposed design involves a 5-component mixture containing: 4-(1-naphthylmethyl)bibenzyl, abbreviated as NMBB, pyrene, tetradecane, dibenzothiophene and quinoline. NMBB simulates the aromatic-aliphatic as well as aliphatic-aliphatic C-C bonds in coal and in some aromatic plastics such as polystyrene. This compound has been used as a probe molecule in previous studies. Pyrene represents polyaromatic structures in coal, while tetradecane is representative of polyethylene-type plastics in chemical reactivity. Dibenzothiophene and quinoline provide sulfur and nitrogen content.

  6. Nitrogen and oxygen functionalized hollow carbon materials: The capacitive enhancement by simply incorporating novel redox additives into H2SO4 electrolyte

    NASA Astrophysics Data System (ADS)

    Nie, Yong Fu; Wang, Qian; Chen, Xiang Ying; Zhang, Zhong Jie

    2016-07-01

    In present work, we have developed a simple but effective template carbonization method for producing hollow carbon materials with high content of nitrogen and oxygen from thiocarbanilide. Among all samples, the NPC-1 exhibits high specific surface area (736 m2 g-1) and large pore volume (5.93 cm3 g-1) with high content of heteroatoms (∼11.25 at% nitrogen and ∼5.74 at% oxygen), which is conducive to the improvement of electrochemical performance. Specifically, the high specific capacitance and excellent cycling stability over 5000 cycles of the NPC-1-based electrode are achieved in 1 mol L-1 H2SO4 electrolyte. Additionally, pyrocatechol and rutin as novel redox additives that can easily cause redox-reactions have been incorporated into H2SO4 electrolyte to improve the capacitances. As a result, the NPC-1-R-0.15 and NPC-1-P-0.15 samples deliver high specific capacitances of 120.5 and 368.7 F g-1 at 2 A g-1, respectively, which are much higher than that of the NPC-1 sample (66.2 F g-1) without redox-additives at same current density. Furthermore, the large energy density of 18.9 and 11.9 Wh kg-1 of the NPC-1-based symmetric supercapacitors have been obtained in H2SO4+pyrocatechol and H2SO4+rutin electrolyte, respectively, and both samples also demonstrate excellent cyclic performance for 5000 cycles.

  7. Preparation and characterization of new dental porcelains, using K-feldspar and quartz raw materials. Effect of B2O3 additions on sintering and mechanical properties.

    PubMed

    Harabi, Abdelhamid; Guerfa, Fatiha; Harabi, Esma; Benhassine, Mohamed-Tayeb; Foughali, Lazhar; Zaiou, Soumia

    2016-08-01

    The aim of this work was to determine the effect of temperature and boric oxide (B2O3) addition on sintering and mechanical properties of a newly developed dental porcelain (DP) prepared from local Algerian raw materials. Based on a preliminary work, the new selected composition was 75wt.% feldspar, 20wt.% quartz and 5wt.% kaolin. It was prepared by sintering the mixture at different temperatures (1100-1250°C). The optimum sintering conditions gave a relatively higher density (2.47g/cm(3)) and excellent mechanical properties. The three point flexural strength (3PFS) and Martens micro-hardness of dental porcelains were 149MPa and 2600MPa, respectively. This obtained 3PFS value is more than four times greater than that of hydroxyapatite (HA) value (about 37MPa) sintered under the same conditions. However, the sintering temperature was lowered by about 25 and 50°C for 3 and 5wt.% B2O3 additions, respectively. But, it did not improve furthermore the samples density and their mechanical properties. It has also been found that B2O3 additions provoke a glass matrix composition variation which delays the leucite formation during sintering. PMID:27157725

  8. Least Square Support Vector Machine Modelling of Breakdown Voltage of Solid Insulating Materials in the Presence of Voids

    NASA Astrophysics Data System (ADS)

    Behera, S.; Tripathy, R. K.; Mohanty, S.

    2013-03-01

    The least square formulation of support vector machine (SVM) was recently proposed and derived from the statistical learning theory. It is also marked as a new development by learning from examples based on neural networks, radial basis function and splines or other functions. Here least square support vector machine (LS-SVM) is used as a machine learning technique for the prediction of the breakdown voltage of solid insulator. The breakdown voltage is due to partial discharge of five solid insulating materials under ac condition. That has been predicted as a function of four input parameters such as thickness of insulating samples ` t', diameter of void ` d', the thickness of the void ` t 1' and relative permittivity of materials `ɛ r ' by using the LS-SVM model. From experimental studies performed on cylindrical-plane electrode system, the requisite training data is obtained. The voids with different dimension are artificially created. Detailed studies have been carried out to determine the LS-SVM parameters which give the best result. At the completion of training it is found that the LS-SVM model is capable of predicting the breakdown voltage V b = ( t, t 1, d, ɛ r ) very efficiently and with a small value of the mean absolute error.

  9. High performance addition-type thermoplastics (ATTs) - Evidence for the formation of a Diels-Alder adduct in the reaction of an acetylene-terminated material and a bismaleimide

    NASA Technical Reports Server (NTRS)

    Pater, R. H.; Soucek, M. D.; Chang, A. C.; Partos, R. D.

    1991-01-01

    Recently, the concept and demonstration of a new versatile synthetic reaction for making a large number of high-performance addition-type thermoplastics (ATTs) were reported. The synthesis shows promise for providing polymers having an attractive combination of easy processability, good toughness, respectable high temperature mechanical performance, and excellent thermo-oxidative stability. The new chemistry involves the reaction of an acetylene-terminated material with a bismaleimide or benzoquinone. In order to clarify the reaction mechanism, model compound studies were undertaken in solutions as well as in the solid state. The reaction products were purified by flash chromatography and characterized by conventional analytical techniques including NMR, FT-IR, UV-visible, mass spectroscopy, and high pressure liquid chromatography. The results are presented of the model compound studies which strongly support the formation of a Diels-Alder adduct in the reaction of an acetylene-terminated compound and a bismaleimide or benzoquinone.

  10. The Importance of a Theory-Informed Understanding of Additive Bilingual Education: Supporting Bilingualism and Biliteracy in a Melbourne Primary School

    ERIC Educational Resources Information Center

    Molyneux, Paul

    2006-01-01

    While Government commitments to supporting instruction in languages other than English have largely been honoured, bilingual education as a form of learning has not been widespread. Acknowledging the benefits of learning a language other than English, the most recent Australian national languages policy statement nonetheless makes no mention of…

  11. Effect of quarry dust addition on the performance of controlled low-strength material made from industrial waste incineration bottom ash

    NASA Astrophysics Data System (ADS)

    Sivakumar, Naganathan; Hashim, Abdul Razak; Nadzriah, Abdul Hamid Siti

    2012-06-01

    The performance of industrial waste incineration bottom ash in controlled low-strength material (CLSM) was investigated in this paper, as the quarry dust was added. CLSM mixtures were made from the industrial waste incineration bottom ash, quarry dust, and cement. Tests for fresh density, bleeding, compressive strength, shear strength, hydraulic conductivity, and excavatability were carried out. The compressive strength ranges from 60 kPa to 6790 kPa, the friction angle varies from 5° to 19°, and the cohesion is from 4 to 604 kPa. Most of the mixtures are found to be non-excavatable. It is indicated that the quarry dust addition increases the compressive strength and shear parameters, decreases bleeding, and increases the removability modulus.

  12. Establishment of a reference collection of additives and an analytical handbook of reference data to support enforcement of EU regulations on food contact plastics.

    PubMed

    van Lierop, B; Castle, L; Feigenbaum, A; Ehlert, K; Boenke, A

    1998-10-01

    A collection has been made of additives that are required as analytical standards for enforcement of European Union legislation on food contact plastics. The 100 additives have been characterized by mass spectrometry, infra-red spectroscopy and proton nuclear magnetic resonance spectroscopy to provide reference spectra. Gas chromatographic retention times have been recorded to facilitate identification by retention index. This information has been further supplemented by physico-chemical data. Finally, chromatographic methods have been used to indicate the presence of any impurities in the commercial chemicals. Samples of the reference substances are available on request and the collection of spectra and other information will be made available in printed format and on-line through the Internet. This paper gives an overview of the work done to establish the reference collection and the spectral atlas, which together will assist enforcement laboratories in the characterization of plastics and the selection of analytical methods for additives that may migrate. PMID:10211194

  13. Review of information on the radiation chemistry of materials around waste canisters in salt and assessment of the need for additional experimental information

    SciTech Connect

    Jenks, G.H.; Baes, C.F. Jr.

    1980-03-01

    The brines, vapors, and salts precipitated from the brines will be exposed to gamma rays and to elevated temperatures in the regions close to a waste package in the salt. Accordingly, they will be subject to changes in composition brought about by reactions induced by the radiations and heat. This report reviews the status of information on the radiation chemistry of brines, gases, and solids which might be present around a waste package in salt and to assess the need for additional laboratory investigations on the radiation chemistry of these materials. The basic aspects of the radiation chemistry of water and aqueous solutions, including concentrated salt solutions, were reviewed briefly and found to be substantially unchanged from those presented in Jenks's 1972 review of radiolysis and hydrolysis in salt-mine brines. Some additional information pertaining to the radiolytic yields and reactions in brine solutions has become available since the previous review, and this information will be useful in the eventual, complete elucidation of the radiation chemistry of the salt-mine brines. 53 references.

  14. Detection and Identification of Leachables in Vaccine from Plastic Packaging Materials Using UPLC-QTOF MS with Self-Built Polymer Additives Library.

    PubMed

    Zhang, Yun; Sun, Shuqi; Xing, Xuebin; Du, Zhenxia; Guo, Qiaozhen; Yu, Wenlian

    2016-07-01

    The direct contact of plastic parts with the medical products raises the possibility that plastic-related contaminants (leachables) may be present in the finished medical product. The leachable components from plastic materials may impact the safety and efficacy of the final medical product, so identification and determination of the leachables are essential for the safety assessment of medical products. A method to identify main leachables-polymer additives in medical products was developed by ultraperformance liquid chromatography-quadrupole time-of-flight-mass spectrometry (UPLC-QTOF MS) and a self-built library. The library contains 174 additives and the information on their names, formulas, structures, retention times, fragments, classifications, origin, and corresponding MS(E) and MSMS spectra. The reliability of the construction process of the library was guaranteed by the system stability and suitability test. Identification parameters of library application, such as mass error, retention times, fragments, and isotope pattern, were evaluated. Leachables in real vaccine and the intermediates were identified using automatic library searching. In vaccine, the peak m/z 239.0887 that could not be assigned by the library was identified as dimethyl 2-hydroxy-1,3-cyclohexanedicarboxylate using a series of elucidation tools. As a result, the concentrations of leachables in vaccine and the intermediates ranged from 0.85 to 21.91 μg/L. PMID:27258161

  15. Process feasibility study in support of silicon material task 1. Quarterly technical progress report (XX), June 1-August 31, 1980

    SciTech Connect

    Yaws, C.L.; Li, K.Y.

    1980-09-01

    Analyses of process system properties were continued for chemical materials important in the production of silicon including compilation and collection activities of the property data for use in the final report. Major efforts in chemical engineering analysis centered on the DCS process - Case A which involves production of dichlorosilane (DCS) as a silicon source material for polysilicon production in the Hemlock Semiconductor Corporation program. The preliminary process design of a plant to produce DCS was completed including process flowsheet (100%), base case conditions (100%), reaction chemistry (100%), raw materials (100%), utilities (100%), major process equipment (100%) and production labor (100%). The process design package was forwarded for economic analysis. Economic analysis of the DCS process - Case A was completed during this reporting period. The results for dichlorosilane (DCS) indicated a total product cost without profit of 1.29 $/kg (1980 dollars). This product cost without profit includes direct manufacturing cost, indirect manufacturing cost, plant overhead and general expenses. The sales price of DCS at 15% DCF rate of return on investment is 1.47$/kg (1980 dollars). Additional results are reported for sales price of dichlorosilane at various profitability levels as measured by ROI (return on original investment) and DCF (discounted cash flow rate of return).

  16. Role of different additives and metallic micro minerals on the enhanced citric acid production by Aspergillus niger MNNG-115 using different carbohydrate materials.

    PubMed

    Ali, Sikander; Haq, Ikram-ul

    2005-01-01

    The present investigation deals with the promotry effect of different additives and metallic micro minerals on citric acid production by Aspergillus niger MNNG-115 using different carbohydrate materials. For this, sugar cane bagasse was fortified with sucrose salt medium. Ethanol and coconut oil at 3.0% (v/w) level increased citric acid productivity. Fluoroacetate at a concentration of 1.0 mg/ml bagasse enhanced the yield of citric acid significantly. However, the addition of ethanol and fluoroacetate after 6 h of growth gave the maximum conversion of available sugar to citric acid. In another study, influence of some metallic micro-minerals viz. copper sulphate, molybdenum sulphate, zinc sulphate and cobalt sulphate on microbial synthesis of citric acid using molasses medium was also carried out. It was found that copper sulphate and molybdenum sulphate remarkably enhanced the production of citric acid while zinc sulphate was not so effective. However, cobalt sulphate was the least effective for microbial biosynthesis of citric acid under the same experimental conditions. In case of CuSO(4), the strain of Aspergillus niger MNNG-115 showed enhanced citric productivity with experimental (9.80%) over the control (7.54%). In addition, the specific productivity of the culture at 30 ppm CuSO(4) (Q(p) = 0.012a g/g cells/h) was several folds higher than other all other concentrations. All kinetic parameters including yield coefficients and volumetric rates revealed the hyper productivity of citric acid by CuSO(4) using blackstrap molasses as the basal carbon source. PMID:15678560

  17. Biofilm development during the start-up period of anaerobic biofilm reactors: the biofilm Archaea community is highly dependent on the support material

    PubMed Central

    Habouzit, Frédéric; Hamelin, Jérôme; Santa-Catalina, Gaëlle; Steyer, Jean-P; Bernet, Nicolas

    2014-01-01

    To evaluate the impact of the nature of the support material on its colonization by a methanogenic consortium, four substrata made of different materials: polyvinyl chloride, 2 polyethylene and polypropylene were tested during the start-up of lab-scale fixed-film reactors. The reactor performances were evaluated and compared together with the analysis of the biofilms. Biofilm growth was quantified and the structure of bacterial and archaeal communities were characterized by molecular fingerprinting profiles (capillary electrophoresis-single strand conformation polymorphism). The composition of the inoculum was shown to have a major impact on the bacterial composition of the biofilm, whatever the nature of the support material or the organic loading rate applied to the reactors during the start-up period. In contrast, the biofilm archaeal populations were independent of the inoculum used but highly dependent on the support material. Supports favouring Archaea colonization, the limiting factor in the overall process, should be preferred. PMID:24612643

  18. Interactive PDF files with embedded 3D designs as support material to study the 32 crystallographic point groups

    NASA Astrophysics Data System (ADS)

    Arribas, Victor; Casas, Lluís; Estop, Eugènia; Labrador, Manuel

    2014-01-01

    Crystallography and X-ray diffraction techniques are essential topics in geosciences and other solid-state sciences. Their fundamentals, which include point symmetry groups, are taught in the corresponding university courses. In-depth meaningful learning of symmetry concepts is difficult and requires capacity for abstraction and spatial vision. Traditionally, wooden crystallographic models are used as support material. In this paper, we describe a new interactive tool, freely available, inspired in such models. Thirty-two PDF files containing embedded 3D models have been created. Each file illustrates a point symmetry group and can be used to teach/learn essential symmetry concepts and the International Hermann-Mauguin notation of point symmetry groups. Most interactive computer-aided tools devoted to symmetry deal with molecular symmetry and disregard crystal symmetry so we have developed a tool that fills the existing gap.

  19. Graphene nanosheets-polypyrrole hybrid material as a highly active catalyst support for formic acid electro-oxidation.

    PubMed

    Yang, Sudong; Shen, Chengmin; Liang, Yanyu; Tong, Hao; He, Wei; Shi, Xuezhao; Zhang, Xiaogang; Gao, Hong-jun

    2011-08-01

    A novel electrode material based on graphene oxide (GO)-polypyrrole (PPy) composites was synthesized by in situ chemical oxidation polymerization. Palladium nanoparticles (NPs) with a diameter of 4.0 nm were loaded on the reduced graphene oxide(RGO)-PPy composites by a microwave-assisted polyol process. Microstructure analysis showed that a layer of coated PPy film with monodisperse Pd NPs is present on the RGO surface. The Pd/RGO-PPy catalysts exhibit excellent catalytic activity and stability for formic acid electro-oxidation when the weight feed ratio of GO to pyrrole monomer is 2:1. The superior performance of Pd/RGO-PPy catalysts may arise from utilization of heterogeneous nucleation sites for NPs and the greatly increased electronic conductivity of the supports. PMID:21713273

  20. Biological regeneration of ferric (Fe3+) solution during desulphurisation of gaseous streams: effect of nutrients and support material.

    PubMed

    Mulopo, Jean; Schaefer, L

    2015-01-01

    This paper evaluates the biological regeneration of ferric Fe3+ solution during desulphurisation of gaseous streams. Hydrogen sulphide (H2S) is absorbed into aqueous ferric sulphate solution and oxidised to elemental sulphur, while ferric ions Fe3+ are reduced to ferrous ions Fe2+. During the industrial regeneration of Fe3+, nutrients and trace minerals usually provided in a laboratory setup are not present and this depletion of nutrients may have a negative impact on the bacteria responsible for ferrous iron oxidation and may probably affect the oxidation rate. In this study, the effect of nutrients and trace minerals on ferrous iron oxidation have been investigated and the results showed that the presence of nutrients and trace minerals affects the efficiency of bacterial Fe2+oxidation. The scanning electron microscopy analysis of the geotextile support material was also conducted and the results showed that the iron precipitate deposits appear to play a direct role on the bacterial biofilm formation. PMID:26038932