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Sample records for adiabatic saturation temperature

  1. Does temperature increase or decrease in adiabatic decompression of magma?

    NASA Astrophysics Data System (ADS)

    Kilinc, A. I.; Ghiorso, M. S.; Khan, T.

    2011-12-01

    We have modeled adiabatic decompression of an andesitic and a basaltic magma as an isentropic process using the Melts algorithm. Our modeling shows that during adiabatic decompression temperature of andesitic magma increases but temperature of basaltic magma decreases. In an isentropic process entropy is constant so change of temperature with pressure can be written as dT/dP=T (dV/dT)/Cp where T (dV/dT)/Cp is generally positive. If delta P is negative so is delta T. In general, in the absence of phase change, we expect the temperature to decrease with adiabatic decompression. The effect of crystallization is to turn a more entropic phase (liquid) into a less entropic phase (solid), which must be compensated by raising the temperature. If during adiabatic decompression there is small amount or no crystallization, T (dV/dT)/Cp effect which lowers the temperature overwhelms the small amount of crystallization, which raises the temperature, and overall system temperature decreases.

  2. Spin-label CW microwave power saturation and rapid passage with triangular non-adiabatic rapid sweep (NARS) and adiabatic rapid passage (ARP) EPR spectroscopy.

    PubMed

    Kittell, Aaron W; Hyde, James S

    2015-06-01

    Non-adiabatic rapid passage (NARS) electron paramagnetic resonance (EPR) spectroscopy was introduced by Kittell et al. (2011) as a general purpose technique to collect the pure absorption response. The technique has been used to improve sensitivity relative to sinusoidal magnetic field modulation, increase the range of inter-spin distances that can be measured under near physiological conditions (Kittell et al., 2012), and enhance spectral resolution in copper (II) spectra (Hyde et al., 2013). In the present work, the method is extended to CW microwave power saturation of spin-labeled T4 Lysozyme (T4L). As in the cited papers, rapid triangular sweep of the polarizing magnetic field was superimposed on slow sweep across the spectrum. Adiabatic rapid passage (ARP) effects were encountered in samples undergoing very slow rotational diffusion as the triangular magnetic field sweep rate was increased. The paper reports results of variation of experimental parameters at the interface of adiabatic and non-adiabatic rapid sweep conditions. Comparison of the forward (up) and reverse (down) triangular sweeps is shown to be a good indicator of the presence of rapid passage effects. Spectral turning points can be distinguished from spectral regions between turning points in two ways: differential microwave power saturation and differential passage effects. Oxygen accessibility data are shown under NARS conditions that appear similar to conventional field modulation data. However, the sensitivity is much higher, permitting, in principle, experiments at substantially lower protein concentrations. Spectral displays were obtained that appear sensitive to rotational diffusion in the range of rotational correlation times of 10(-3) to 10(-7) s in a manner that is analogous to saturation transfer spectroscopy.

  3. Spin-label CW microwave power saturation and rapid passage with triangular non-adiabatic rapid sweep (NARS) and adiabatic rapid passage (ARP) EPR spectroscopy

    NASA Astrophysics Data System (ADS)

    Kittell, Aaron W.; Hyde, James S.

    2015-06-01

    Non-adiabatic rapid passage (NARS) electron paramagnetic resonance (EPR) spectroscopy was introduced by Kittell et al. (2011) as a general purpose technique to collect the pure absorption response. The technique has been used to improve sensitivity relative to sinusoidal magnetic field modulation, increase the range of inter-spin distances that can be measured under near physiological conditions (Kittell et al., 2012), and enhance spectral resolution in copper (II) spectra (Hyde et al., 2013). In the present work, the method is extended to CW microwave power saturation of spin-labeled T4 Lysozyme (T4L). As in the cited papers, rapid triangular sweep of the polarizing magnetic field was superimposed on slow sweep across the spectrum. Adiabatic rapid passage (ARP) effects were encountered in samples undergoing very slow rotational diffusion as the triangular magnetic field sweep rate was increased. The paper reports results of variation of experimental parameters at the interface of adiabatic and non-adiabatic rapid sweep conditions. Comparison of the forward (up) and reverse (down) triangular sweeps is shown to be a good indicator of the presence of rapid passage effects. Spectral turning points can be distinguished from spectral regions between turning points in two ways: differential microwave power saturation and differential passage effects. Oxygen accessibility data are shown under NARS conditions that appear similar to conventional field modulation data. However, the sensitivity is much higher, permitting, in principle, experiments at substantially lower protein concentrations. Spectral displays were obtained that appear sensitive to rotational diffusion in the range of rotational correlation times of 10-3 to 10-7 s in a manner that is analogous to saturation transfer spectroscopy.

  4. Spin-label CW microwave power saturation and rapid passage with triangular non-adiabatic rapid sweep (NARS) and adiabatic rapid passage (ARP) EPR spectroscopy.

    PubMed

    Kittell, Aaron W; Hyde, James S

    2015-06-01

    Non-adiabatic rapid passage (NARS) electron paramagnetic resonance (EPR) spectroscopy was introduced by Kittell et al. (2011) as a general purpose technique to collect the pure absorption response. The technique has been used to improve sensitivity relative to sinusoidal magnetic field modulation, increase the range of inter-spin distances that can be measured under near physiological conditions (Kittell et al., 2012), and enhance spectral resolution in copper (II) spectra (Hyde et al., 2013). In the present work, the method is extended to CW microwave power saturation of spin-labeled T4 Lysozyme (T4L). As in the cited papers, rapid triangular sweep of the polarizing magnetic field was superimposed on slow sweep across the spectrum. Adiabatic rapid passage (ARP) effects were encountered in samples undergoing very slow rotational diffusion as the triangular magnetic field sweep rate was increased. The paper reports results of variation of experimental parameters at the interface of adiabatic and non-adiabatic rapid sweep conditions. Comparison of the forward (up) and reverse (down) triangular sweeps is shown to be a good indicator of the presence of rapid passage effects. Spectral turning points can be distinguished from spectral regions between turning points in two ways: differential microwave power saturation and differential passage effects. Oxygen accessibility data are shown under NARS conditions that appear similar to conventional field modulation data. However, the sensitivity is much higher, permitting, in principle, experiments at substantially lower protein concentrations. Spectral displays were obtained that appear sensitive to rotational diffusion in the range of rotational correlation times of 10(-3) to 10(-7) s in a manner that is analogous to saturation transfer spectroscopy. PMID:25917132

  5. Temperature dependence of electronic eigenenergies in the adiabatic harmonic approximation

    NASA Astrophysics Data System (ADS)

    Poncé, S.; Antonius, G.; Gillet, Y.; Boulanger, P.; Laflamme Janssen, J.; Marini, A.; Côté, M.; Gonze, X.

    2014-12-01

    The renormalization of electronic eigenenergies due to electron-phonon interactions (temperature dependence and zero-point motion effect) is important in many materials. We address it in the adiabatic harmonic approximation, based on first principles (e.g., density-functional theory), from different points of view: directly from atomic position fluctuations or, alternatively, from Janak's theorem generalized to the case where the Helmholtz free energy, including the vibrational entropy, is used. We prove their equivalence, based on the usual form of Janak's theorem and on the dynamical equation. We then also place the Allen-Heine-Cardona (AHC) theory of the renormalization in a first-principles context. The AHC theory relies on the rigid-ion approximation, and naturally leads to a self-energy (Fan) contribution and a Debye-Waller contribution. Such a splitting can also be done for the complete harmonic adiabatic expression, in which the rigid-ion approximation is not required. A numerical study within the density-functional perturbation theory framework allows us to compare the AHC theory with frozen-phonon calculations, with or without the rigid-ion approximation. For the two different numerical approaches without non-rigid-ion terms, the agreement is better than 7 μ eV in the case of diamond, which represent an agreement to five significant digits. The magnitude of the non-rigid-ion terms in this case is also presented, distinguishing specific phonon modes contributions to different electronic eigenenergies.

  6. Flammability zone prediction using calculated adiabatic flame temperatures

    SciTech Connect

    Mashuga, C.V.; Crowl, D.A.

    1999-11-01

    This paper describes work to predict the flammability zone for any mixture of fuel, oxygen and nitrogen. The method utilizes a commercially available equilibrium program to determine the calculated adiabatic flame temperature (CAFT). The model is compared with extensive experimental data obtained in a 20 L sphere at an initial pressure of 1 atm and 298 K. The data and model compare well over the entire flammability zone for two pure species, methane and ethylene, and not as well for a 50/50 mixture of methane/ethylene. Results show that a good prediction of the flammability zone is obtained using a CAFT criterion of 1200 K. Furthermore, the intermediate species and solid carbon must be included in the equilibrium calculation to fit the fuel rich part of the zone. The intermediate species were selected by the equilibrium program using a built-in species selection criteria. For a gas mixture of methane and ethylene, the authors were unable to identify mixing rules for estimating K{sub G} and P{sub max} from pure component data. This method provides a direct approach to full flammability zone prediction.

  7. Adiabatic temperature changes of magma-gas mixtures during ascent and eruption

    USGS Publications Warehouse

    Mastin, L.G.; Ghiorso, M.S.

    2001-01-01

    Most quantitative studies of flow dynamics in eruptive conduits during volcanic eruptions use a simplified energy equation that ignores either temperature changes, or the thermal effects of gas exsolution. In this paper we assess the effects of those simplifications by analyzing the influence of equilibrium gas exsolution and expansion on final temperatures, velocities, and liquid viscosities of magma-gas mixtures during adiabatic decompression. For a given initial pressure (p1), temperature (T1) and melt composition, the final temperature (Tf) and velocity (Umax) will vary depending on the degree to which friction and other irreversible processes reduce mechanical energy within the conduit. The final conditions range between two thermodynamic end members: (1) Constant enthalpy (dh=0), in which Tf is maximal and no energy goes into lifting or acceleration; and (2) constant entropy (ds=0), in which Tf is minimal and maximum energy goes into lifting and acceleration. For ds=0, T1=900 ??C and p1=200 MPa, a water-saturated albitic melt cools by ???200 ??C during decompression, but only about 250 ??C of this temperature decrease can be attributed to the energy of gas exsolution per se: The remainder results from expansion of gas that has already exsolved. For the same T1 and p1, and dh=0, Tf is 10-15 ??C hotter than T1 but is about 10-25 ??C cooler than Tf in similar calculations that ignore the energy of gas exsolution. For ds=0, p1=200 MPa and T1= 9,000 ??C, assuming that all the enthalpy change of decompression goes into kinetic energy, a water-saturated albitic mixture can theoretically accelerate to ???800 m/s. Similar calculations that ignore gas exsolution (but take into account gas expansion) give velocities about 10-15% higher. For the same T1, p1 = 200 MPa, and ds = 0, the cooling associated with gas expansion and exsolution increases final melt viscosity more than 2.5 orders of magnitude. For dh = 0, isenthalpic heating decreases final melt viscosity by about

  8. HyspIRI High-Temperature Saturation Study

    NASA Technical Reports Server (NTRS)

    Realmuto, V.; Hook, S.; Foote, M.; Csiszar, I.; Dennison, P.; Giglio, L.; Ramsey, M.; Vaughan, R.G.; Wooster, M.; Wright, R.

    2011-01-01

    As part of the precursor activities for the HyspIRI mission, a small team was assembled to determine the optimum saturation level for the mid-infrared (4-?m) channel, which is dedicated to the measurement of hot targets. Examples of hot targets include wildland fires and active lava flows. This determination took into account both the temperature expected for the natural phenomena and the expected performance of the mid-infrared channel as well as its overlap with the other channels in the thermal infrared (7.5-12 ?m) designed to measure the temperature of lower temperature targets. Based on this work, the hot target saturation group recommends a saturation temperature of 1200 K for the mid-infrared channel. The saturation temperature of 1200 K represents a good compromise between the prevention of saturation and sensitivity to ambient temperature.

  9. Analytical equation for calculating the adiabatic temperature of the wet-bulb thermometer

    NASA Astrophysics Data System (ADS)

    Baskakov, A. P.; Rakov, O. A.

    2013-03-01

    A formula for calculating the adiabatic temperature of the wet-bulb thermometer has been obtained analytically without using the analogy between the heat and mass transfer processes. A comparison of the results of calculations with the use of this formula and formulas of other authors used in the technical literature has been made.

  10. Space Charge Saturated Sheath Regime and Electron Temperature Saturation in Hall Thrusters

    SciTech Connect

    Y. Raitses; D. Staack; A. Smirnov; N.J. Fisch

    2005-03-16

    Secondary electron emission in Hall thrusters is predicted to lead to space charge saturated wall sheaths resulting in enhanced power losses in the thruster channel. Analysis of experimentally obtained electron-wall collision frequency suggests that the electron temperature saturation, which occurs at high discharge voltages, appears to be caused by a decrease of the Joule heating rather than by the enhancement of the electron energy loss at the walls due to a strong secondary electron emission.

  11. Model-based estimation of adiabatic flame temperature during coal gasification

    NASA Astrophysics Data System (ADS)

    Sarigul, Ihsan Mert

    Coal gasification temperature distribution in the gasifier is one of the important issues. High temperature may increase the risk of corrosion of the gasifier wall or it may cause an increase in the amount of volatile compounds. At the same time, gasification temperature is a dominant factor for high conversion of products and completing the reactions during coal gasification in a short time. In the light of this information it can be said that temperature is one of key parameters of coal gasification to enhance the production of high heating value syngas and maximize refractory longevity. This study aims to predict the adiabatic flame temperatures of Australian bituminous coal and Indonesian roto coal in an entrained flow gasifier using different operating conditions with the ChemCAD simulation and design program. To achieve these objectives, two types of gasification parameters were carried out using simulation of a vertical entrained flow reactor: oxygen-to-coal feed ratio by kg/kg and pressure and steam-to-coal feed ratio by kg/kg and pressure. In the first part of study the adiabatic flame temperatures, coal gasification products and other coal characteristics of two types of coals were determined using ChemCAD software. During all simulations, coal feed rate, coal particle size, initial temperature of coal, water and oxygen were kept constant. The relationships between flame temperature, coal gasification products and operating parameters were fundamentally investigated. The second part of this study addresses the modeling of the flame temperature relation to methane production and other input parameters used previous chapter. The scope of this work was to establish a reasonable model in order to estimate flame temperature without any theoretical calculation. Finally, sensitivity analysis was performed after getting some basic correlations between temperature and input variables. According to the results, oxygen-to-coal feed ratio has the most influential

  12. Application of a digital computer to data acquisition and shield temperature control of a high-temperature, adiabatic calorimeter

    SciTech Connect

    Cash, W.M.; Stansbury, E.E.; Moore, C.F.; Brooks, C.R.

    1981-06-01

    The use of a digital computer, operating under real-time, time-sharing mode, for the operation of a high-temperature (300--1300 K), adiabatic calorimeter is described. The specimen temperature and power to the specimen heater are logged continuously, from which the heat capacity is calculated for specified temperature intervals (e.g., 20 K). The determinate error in the calculated heat capacity is about +- 0.6%. The temperature control of the adiabatic shields is quite comparable with that obtained previously with analog controllers. The temperature difference between the specimen and a shield can be maintained to about +- 0.1 K. The heat capacity of a pure titanium specimen has been measured from 320 to 1020 K using the computer and also using the analog control. No discernible difference in results can be seen. The heat capacity data scatter about +- 1% from a smooth curve fitted through the 325 data points.

  13. Large-Strain Time-Temperature Equivalence and Adiabatic Heating of Polyethylene

    SciTech Connect

    Furmanski, Jevan; Brown, Eric; Cady, Carl M.

    2012-06-06

    Time-temperature equivalence is a well-known phenomenon in time-dependent material response, where rapid events at a moderate temperature are indistinguishable from some occurring at modest rates but elevated temperatures. However, there is as-yet little elucidation of how well this equivalence holds for substantial plastic strains. In this work, we demonstrate time-temperature equivalence over a large range in a previously studied high-density polyethylene formulation (HDPE). At strain-rates exceeding 0.1/s, adiabatic heating confounds the comparison of nominally isothermal material response, apparently violating time-temperature equivalence. Strain-rate jumps can be employed to access the instantaneous true strain rate without heating. Adiabatic heating effects were isolated by comparing a locus of isothermal instantaneous flow stress measurements from strain-rate jumps up to 1/s with the predicted equivalent states at 0.01/s and 0.001/s in compression. Excellent agreement between the isothermal jump condition locus and the quasi-static tests was observed up to 50% strain, yielding one effective isothermal plastic response for each material for a given time-temperature equivalent state. These results imply that time-temperature equivalence can be effectively used to predict the deformation response of polymers during extreme mechanical events (large strain and high strain-rate) from measurements taken at reduced temperatures and nominal strain-rates in the laboratory.

  14. Temperature gradients due to adiabatic plasma expansion in a magnetic nozzle

    NASA Astrophysics Data System (ADS)

    Sheehan, J. P.; Longmier, B. W.; Bering, E. A.; Olsen, C. S.; Squire, J. P.; Ballenger, M. G.; Carter, M. D.; Cassady, L. D.; Díaz, F. R. Chang; Glover, T. W.; Ilin, A. V.

    2014-08-01

    A mechanism for ambipolar ion acceleration in a magnetic nozzle is proposed. The plasma is adiabatic (i.e., does not exchange energy with its surroundings) in the diverging section of a magnetic nozzle so any energy lost by the electrons must be transferred to the ions via the electric field. Fluid theory indicates that the change in plasma potential is proportional to the change in average electron energy. These predictions were compared to measurements in the VX-200 experiment which has conditions conducive to ambipolar ion acceleration. A planar Langmuir probe was used to measure the plasma potential, electron density, and electron temperature for a range of mass flow rates and power levels. Axial profiles of those parameters were also measured, showing consistency with the adiabatic ambipolar fluid theory.

  15. Temperature calibration of cryoscopic solutions used in the milk industry by adiabatic calorimetry

    NASA Astrophysics Data System (ADS)

    Méndez-Lango, E.; Lira-Cortes, L.; Quiñones-Ibarra, R.

    2013-09-01

    One method to detect extraneous water in milk is through cryoscopy. This method is used to measure the freezing point of milk. For calibration of a cryoscope there are is a set of standardized solution with known freezing points values. These values are related with the solute concentration, based in almost a century old data; it was no found recent results. It was found that reference solution are not certified in temperature: they do not have traceability to the temperature unit or standards. We prepared four solutions and measured them on a cryoscope and on an adiabatic calorimeter. It was found that results obtained with one technique dose not coincide with the other one.

  16. Large adiabatic temperature change in magnetoelastic transition in Ni50Mn35Cr2Sn13 Heusler alloy of granular nanostructure

    NASA Astrophysics Data System (ADS)

    Prakash, H. R.; Sharma, S. K.; Ram, S.; Chatterjee, S.

    2016-05-01

    The Ni-Mn-Sn alloys are a pioneering series of magnetocaloric materials of a huge heat-energy exchanger in the martensite transition. A small additive of nearly 2 at% Cr effectively tunes the valence electron density of 8.090 electrons per atom and a large change in the entropy ΔSM←A = 4.428 J/kg-K (ΔSM→A = 3.695 J/kg-K in the recycle) at the martensite ← austenite phase transition as it is useful for the magnetic refrigeration and other cooling devices. The Cr additive tempers the tetragonality with the aspect ratio c/a = 0.903 of the martensite phase and exhibits an adiabatic temperature change of 10 K. At room temperature, a hysteresis loop exhibits 48.91 emu/g saturation magnetization and 82.1Oe coercivity.

  17. Effect of solution saturation state and temperature on diopside dissolution

    SciTech Connect

    Dixit, S; Carroll, S A

    2007-03-23

    Steady-state dissolution rates of diopside are measured as a function of solution saturation state using a titanium flow-through reactor at pH 7.5 and temperature ranging from 125 to 175 C. Diopside dissolved stoichiometrically under all experimental conditions and rates were not dependent on sample history. At each temperature, rates continuously decreased by two orders of magnitude as equilibrium was approached and did not exhibit a dissolution plateau of constant rates at high degrees of undersaturation. The variation of diopside dissolution rates with solution saturation can be described equally well with a ion exchange model based on transition state theory or pit nucleation model based on crystal growth/dissolution theory from 125 to 175 C. At 175 C, both models over predict dissolution rates by two orders of magnitude indicating that a secondary phase precipitated in the experiments. The ion exchange model assumes the formation of a Si-rich, Mg-deficient precursor complex. Lack of dependence of rates on steady-state aqueous calcium concentration supports the formation of such a complex, which is formed by exchange of protons for magnesium ions at the surface.

  18. A Compact, Continuous Adiabatic Demagnetization Refrigerator with High Heat Sink Temperature

    NASA Technical Reports Server (NTRS)

    Shirron, P. J.; Canavan, E. R.; DiPirro, M. J.; Jackson, M.; Tuttle, J. G.

    2003-01-01

    In the continuous adiabatic demagnetization refrigerator (ADR), the existence of a constant temperature stage attached to the load breaks the link between the requirements of the load (usually a detector array) and the operation of the ADR. This allows the ADR to be cycled much faster, which yields more than an order of magnitude improvement in cooling power density over single-shot ADRs. Recent effort has focused on developing compact, efficient higher temperature stages. An important part of this work has been the development of passive gas-gap heat switches that transition (from conductive to insulating) at temperatures around 1 K and 4 K without the use of an actively heated getter. We have found that by carefully adjusting available surface area and the number of He-3 monolayers, gas-gap switches can be made to operate passively. Passive operation greatly reduces switching time and eliminates an important parasitic heat load. The current four stage ADR provides 6 micro W of cooling at 50 mK (21 micro W at 100 mK) and weighs less than 8 kg. It operates from a 4.2 K heat sink, which can be provided by an unpumped He bath or many commercially available mechanical cryocoolers. Reduction in critical current with temperature in our fourth stage NbTi magnet presently limits the maximum temperature of our system to approx. 5 K. We are developing compact, low-current Nb3Sn magnets that will raise the maximum heat sink temperature to over 10 K.

  19. Isothermal and Adiabatic Measurements.

    ERIC Educational Resources Information Center

    McNairy, William W.

    1996-01-01

    Describes the working of the Adiabatic Gas Law Apparatus, a useful tool for measuring the pressure, temperature, and volume of a variety of gases undergoing compressions and expansions. Describes the adaptation of this apparatus to perform isothermal measurements and discusses the theory behind the adiabatic and isothermal processes. (JRH)

  20. Microstructural characteristics of adiabatic shear localization in a metastable beta titanium alloy deformed at high strain rate and elevated temperatures

    SciTech Connect

    Zhan, Hongyi; Zeng, Weidong; Wang, Gui; Kent, Damon; Dargusch, Matthew

    2015-04-15

    The microstructural evolution and grain refinement within adiabatic shear bands in the Ti6554 alloy deformed at high strain rates and elevated temperatures have been characterized using transmission electron microscopy. No stress drops were observed in the corresponding stress–strain curve, indicating that the initiation of adiabatic shear bands does not lead to the loss of load capacity for the Ti6554 alloy. The outer region of the shear bands mainly consists of cell structures bounded by dislocation clusters. Equiaxed subgrains in the core area of the shear band can be evolved from the subdivision of cell structures or reconstruction and transverse segmentation of dislocation clusters. It is proposed that dislocation activity dominates the grain refinement process. The rotational recrystallization mechanism may operate as the kinetic requirements for it are fulfilled. The coexistence of different substructures across the shear bands implies that the microstructural evolution inside the shear bands is not homogeneous and different grain refinement mechanisms may operate simultaneously to refine the structure. - Graphical abstract: Display Omitted - Highlights: • The microstructure within the adiabatic shear band was characterized by TEM. • No stress drops were observed in the corresponding stress–strain curve. • Dislocation activity dominated the grain refinement process. • The kinetic requirements for rotational recrystallization mechanism were fulfilled. • Different grain refinement mechanisms operated simultaneously to refine the structure.

  1. High-temperature adiabatic calorimeter for constant-volume heat capacity measurements of compressed gases and liquids

    SciTech Connect

    Magee, J.W.; Deal, R.J.; Blanco, J.C.

    1998-01-01

    A high-temperature adiabatic calorimeter has been developed to measure the constant-volume specific heat capacities (c{sub v}) of both gases and liquids, especially fluids of interest to emerging energy technologies. The chief design feature is its nearly identical twin bomb arrangement, which allows accurate measurement of energy differences without large corrections for energy losses due to thermal radiation fluxes. Operating conditions for the calorimeter cover a range of temperatures from 250 K to 700 K and at pressures up to 20 MPa. Performance tests were made with a sample of twice-distilled water. Heat capacities for water were measured from 300 K to 420 K at pressures to 20 MPa. The measured heat capacities differed from those calculated with an independently developed standard reference formulation with a root-mean-square fractional deviation of 0.48%.

  2. A method of computing the transient temperature of thick walls from arbitrary variation of adiabatic-wall temperature and heat-transfer coefficient

    NASA Technical Reports Server (NTRS)

    Hill, P R

    1958-01-01

    A method of calculating the temperature of thick walls has been developed in which the time series and the response to a unit triangle variation of surface temperature concepts are used, together with essentially standard formulas for transient temperature and heat flow into thick walls. The method can be used without knowledge of the mathematical tools of its development. The method is particularly suitable for determining the wall temperature in one-dimensional thermal problems in aeronautics where there is a continuous variation of the heat-transfer coefficient and adiabatic-wall temperature. The method also offers a convenient means for solving the inverse problem of determining the heat-flow history when temperature history is known.

  3. Formation of bubbly horizon in liquid-saturated porous medium by surface temperature oscillation.

    PubMed

    Goldobin, Denis S; Krauzin, Pavel V

    2015-12-01

    We study nonisothermal diffusion transport of a weakly soluble substance in a liquid-saturated porous medium in contact with a reservoir of this substance. The surface temperature of the porous medium half-space oscillates in time, which results in a decaying solubility wave propagating deep into the porous medium. In this system, zones of saturated solution and nondissolved phase coexist with ones of undersaturated solution. The effect is first considered for the case of annual oscillation of the surface temperature of water-saturated ground in contact with the atmosphere. We reveal the phenomenon of formation of a near-surface bubbly horizon due to temperature oscillation. An analytical theory of the phenomenon is developed. Further, the treatment is extended to the case of higher frequency oscillations and the case of weakly soluble solids and liquids. PMID:26764828

  4. Calculation of reaction energies and adiabatic temperatures for waste tank reactions

    SciTech Connect

    Burger, L.L.

    1993-03-01

    Continual concern has been expressed over potentially hazardous exothermic reactions that might occur in underground Hanford waste tanks. These tanks contain many different oxidizable compounds covering a wide range of concentrations. Several may be in concentrations and quantities great enough to be considered a hazard in that they could undergo rapid and energetic chemical reactions with nitrate and nitrite salts that are present. The tanks also contain many inorganic compounds inert to oxidation. In this report the computed energy that may be released when various organic and inorganic compounds react is computed as a function of the reaction mix composition and the temperature. The enthalpy, or integrated heat capacity, of these compounds and various reaction products is presented as a function of temperature, and the enthalpy of a given mixture can then be equated to the energy release from various reactions to predict the maximum temperature that may be reached. This is estimated for several different compositions. Alternatively, the amounts of various diluents required to prevent the temperature from reaching a critical value can be estimated.

  5. Calculation of reaction energies and adiabatic temperatures for waste tank reactions

    SciTech Connect

    Burger, L.L.

    1995-10-01

    Continual concern has been expressed over potentially hazardous exothermic reactions that might occur in Hanford Site underground waste storage tanks. These tanks contain many different oxidizable compounds covering a wide range of concentrations. The chemical hazards are a function of several interrelated factors, including the amount of energy (heat) produced, how fast it is produced, and the thermal absorption and heat transfer properties of the system. The reaction path(s) will determine the amount of energy produced and kinetics will determine the rate that it is produced. The tanks also contain many inorganic compounds inert to oxidation. These compounds act as diluents and can inhibit exothermic reactions because of their heat capacity and thus, in contrast to the oxidizable compounds, provide mitigation of hazardous reactions. In this report the energy that may be released when various organic and inorganic compounds react is computed as a function of the reaction-mix composition and the temperature. The enthalpy, or integrated heat capacity, of these compounds and various reaction products is presented as a function of temperature; the enthalpy of a given mixture can then be equated to the energy release from various reactions to predict the maximum temperature which may be reached. This is estimated for several different compositions. Alternatively, the amounts of various diluents required to prevent the temperature from reaching a critical value can be estimated. Reactions taking different paths, forming different products such as N{sub 2}O in place of N{sub 2} are also considered, as are reactions where an excess of caustic is present. Oxidants other than nitrate and nitrite are considered briefly.

  6. Thermodynamic properties of saturated liquid parahydrogen charted for important temperature range

    NASA Technical Reports Server (NTRS)

    Mc Carty, R. D.; Roder, H. M.

    1967-01-01

    Six entropy diagrams for parahydrogen in or near the saturated liquid state cover the temperature range from 29.16 degrees to 42.48 degrees R with pressures to 100 psia and mixtures of the liquid and vapor phases to 0.003 quality. The diagrams are printed in color, are 19 by 30 inches in size, and are suitable for wall mounting.

  7. Weather Types, temperature and relief relationship in the Iberian Peninsula: A regional adiabatic processes under directional weather types

    NASA Astrophysics Data System (ADS)

    Peña Angulo, Dhais; Trigo, Ricardo; Cortesi, Nicola; Gonzalez-Hidalgo, Jose Carlos

    2016-04-01

    We have analyzed at monthly scale the spatial distribution of Pearson correlation between monthly mean of maximum (Tmax) and minimum (Tmin) temperatures with weather types (WTs) in the Iberian Peninsula (IP), represent them in a high spatial resolution grid (10km x 10km) from MOTEDAS dataset (Gonzalez-Hidalgo et al., 2015a). The WT classification was that developed by Jenkinson and Collison, adapted to the Iberian Peninsula by Trigo and DaCamara, using Sea Level Pressure data from NCAR/NCEP Reanalysis dataset (period 1951-2010). The spatial distribution of Pearson correlations shows a clear zonal gradient in Tmax under the zonal advection produced in westerly (W) and easterly (E) flows, with negative correlation in the coastland where the air mass come from but positive correlation to the inland areas. The same is true under North-West (NW), North-East (NE), South-West (SW) and South-East (SE) WTs. These spatial gradients are coherent with the spatial distribution of the main mountain chain and offer an example of regional adiabatic phenomena that affect the entire IP (Peña-Angulo et al., 2015b). These spatial gradients have not been observed in Tmin. We suggest that Tmin values are less sensitive to changes in Sea Level Pressure and more related to local factors. These directional WT present a monthly frequency over 10 days and could be a valuable tool for downscaling processes. González-Hidalgo J.C., Peña-Angulo D., Brunetti M., Cortesi, C. (2015a): MOTEDAS: a new monthly temperature database for mainland Spain and the trend in temperature (1951-2010). International Journal of Climatology 31, 715-731. DOI: 10.1002/joc.4298 Peña-Angulo, D., Trigo, R., Cortesi, C., González-Hidalgo, J.C. (2015b): The influence of weather types on the monthly average maximum and minimum temperatures in the Iberian Peninsula. Submitted to Hydrology and Earth System Sciences.

  8. Low-Temperature Polymorphic Phase Transition in a Crystalline Tripeptide l-Ala-l-Pro-Gly·H2O Revealed by Adiabatic Calorimetry

    PubMed Central

    Markin, Alexey V.; Markhasin, Evgeny; Sologubov, Semen S.; Ni, Qing Zhe; Smirnova, Natalia N.; Griffin, Robert G.

    2015-01-01

    We demonstrate application of precise adiabatic vacuun calorimetry to observation of phase transition in the tripeptide l-alanyl-l-prolyl-glycine monohydrate (APG) from 6 to 320 K and report the standard thermodynamic properties of the tripeptide in the entire range. Thus, the heat capacity of APG was measured by adiabatic vacuun calorimetry in the above temperature range. The tripeptide exhibits a reversible first-order solid-to-solid phase transition characterized by strong thermal hysteresis. We report the standard thermodynamic characteristics of this transition and show that differential scanning calorimetry can reliably characterize the observed phase transition with <5 mg of the sample. Additionally, the standard entropy of formation from the elemental substances and the standard entropy of hypothetical reaction of synthesis from the amino acids at 298.15 K were calculated for the studied tripeptide. PMID:25588051

  9. IMPACT OF CURING TEMPERATURE ON THE SATURATED LIQUID PERMEABILITY OF SALTSTONE

    SciTech Connect

    Williams, F.; Harbour, J.

    2011-02-14

    This report focuses on the impact of curing temperature on the performance properties of simulated Saltstone mixes. The key performance property of interest is saturated liquid permeability (measured as hydraulic conductivity), an input to the Performance Assessment (PA) modeling for the Saltstone Disposal Facility (SDF). Therefore, the current study was performed to measure the dependence of saturated hydraulic conductivity on curing temperature of Saltstone mixes, to correlate these results with measurements of Young's moduli on the same samples and to compare the Scanning Electron Microscopy (SEM) images of the microstructure at each curing temperature in an effort to associate this significant changes in permeability with changes in microstructure. This work demonstrated that the saturated liquid permeability of Saltstone mixes depends significantly on the curing temperature. As the curing temperature increases, the hydraulic conductivity can increase over three orders of magnitude from roughly 10{sup -9} cm/sec to 10{sup -6} cm/sec over the temperature range of 20 C to 80 C. Although an increased aluminate concentration (at 0.22 M) in the ARP/MCU waste stream improves (decreases) saturated permeability for samples cured at lower temperatures, the permeabilities for samples cured at 60 C to 80 C are the same as the permeabilities measured for an equivalent mix but with lower aluminate concentration. Furthermore, it was demonstrated that the unsaturated flow apparatus (UFA) system can be used to measure hydraulic conductivity of Saltstone samples. The permeability results obtained using the UFA centrifuge system were equivalent within experimental error to the conventional permeameter results (the falling head method) obtained at MACTEC. In particular the UFA technique is best suited for the range of hydraulic conductivities between 10{sup -10} cm/sec to 10{sup -6} cm/sec. Measurements of dynamic Young's moduli (E) for these mixes revealed a correlation between

  10. Wave-particle interaction and the nonlinear saturation of the electron temperature gradient mode

    NASA Astrophysics Data System (ADS)

    Vadlamani, Srinath; Parker, Scott E.; Chen, Yang; Howard, James E.

    2004-11-01

    It has been proposed that the electron temperature gradient (ETG) driven turbulence is responsible for experimentally relevant electron thermal transport in tokamak plasmas. Significant transport levels are possible by the creation of radially elongated vortices or ``streamers" [1,2], which are sustained by the nonlinear saturation of the instability and are not susceptible to shear flow destruction, as is the case with the ion temperature gradient (ITG) mode. We present a dynamical system to explore the dependence of saturation level due to E × B and E_\\| motion, as well as the effect of radial elongation. With this model, we can predict the nonlinear saturation level of the ETG streamers. We compare our theoretical predictions with a 2D shear-less slab gyrokinetic electron code that includes the E_\\| nonlinearity. [1]F. Jenko, W. Dorland, M Kotschenreuther, and B.N. Rogers, Phys. Plasmas 7, 1904 (2000). [2]C. Holland, and P.H. Diamond, Phys. Plasmas 9, 3857 (2002). [3]W. M. Manheimer, Phys. Fluids 14, 579 (1971). [4]R. A. Smith, John A. Krommes, and W. W. Lee, Phys. Fluids 28, 1069 (1985).

  11. Sulfide saturation of basalt and andesite melts at high pressures and temperatures

    NASA Technical Reports Server (NTRS)

    Wendlandt, R. F.

    1982-01-01

    When the sulfur content of an Fe-bearing magma exceeds the saturation limit for the bulk composition, an immiscible iron sulfide melt fraction separates. For an understanding of the geochemistry of sulfur-bearing magmatic systems, more information is needed regarding the solubility of metal sulfide in silicate melt at its source and the solubility changes as a function of changing intensive and extensive variables. In the present investigation, the sulfur saturation surface is determined for the pressure range from 12.5 to 30 kbar and the temperature range from 1300 to 1460 C for three silicate melt compositions representing a range of SiO2 and FeO compositions.

  12. High temperature measurement using very high shutter speed to avoid image saturation

    SciTech Connect

    Ma, Zhen; Zhang, Yang

    2014-04-11

    This paper explores the adaptation of the two-colour principle to develop a high-speed colour temperature correlation system, which is able to cover a range of temperature that is challenging to achieve before. A colour digital camera has built in RGB filters. It is possible to measure the temperature from the ratio of intensity of the green and red pixels using the two-colour principle based on the expansion of the Plank’s radiation law. In this study, experiments were carried out using a temperature calibrated tungsten ribbon lamp which can be tuned to vary from 1300 to 2200°C. Using very high shutter speed and small aperture, the high-speed camera successfully captured the tungsten ribbon without image saturation at the full temperature scale. Tests have been carried out at different temperature and camera settings. The sensitivity and errors have been analysed, and experiment results demonstrate the potential of using very high shutter speed is available for measuring the temperature even beyond 2200°C.

  13. Design, Test and Demonstration of Saturable Reactor High-Temperature Superconductor Fault Current Limiters

    SciTech Connect

    Darmann, Frank; Lombaerde, Robert; Moriconi, Franco; Nelson, Albert

    2012-03-01

    Zenergy Power has successfully designed, built, tested, and installed in the US electrical grid a saturable reactor Fault Current Limiter. Beginning in 2007, first as SC Power Systems and from 2008 as Zenergy Power, Inc., ZP used DOE matching grant and ARRA funds to help refine the design of the saturated reactor fault current limiter. ZP ultimately perfected the design of the saturated reactor FCL to the point that ZP could reliably design a suitable FCL for most utility applications. Beginning with a very basic FCL design using 1G HTS for a coil housed in a LN2 cryostat for the DC bias magnet, the technology progressed to a commercial system that was offered for sale internationally. Substantial progress was made in two areas. First, the cryogenics cooling system progressed from a sub-cooled liquid nitrogen container housing the HTS coils to cryostats utilizing dry conduction cooling and reaching temperatures down to less than 20 degrees K. Large, round cryostats with warm bore diameters of 1.7 meters enabled the design of large tanks to hold the AC components. Second, the design of the AC part of the FCL was refined from a six legged spider design to a more compact and lighter design with better fault current limiting capability. Further refinement of the flux path and core shape led to an efficient saturated reactor design requiring less Ampere-turns to saturate the core. In conclusion, the development of the saturable reactor FCL led to a more efficient design not requiring HTS magnets and their associated peripheral equipment, which yielded a more economical product in line with the electric utility industry expectations. The original goal for the DOE funding of the ZP project Design, Test and Demonstration of Saturable Reactor High-Temperature Superconductor Fault Current Limiters was to stimulate the HTS wire industry with, first 1G, then 2G, HTS wire applications. Over the approximately 5 years of ZP's product development program, the amount of HTS wire

  14. Temperature gradient effects on vapor diffusion in partially-saturated porous media

    SciTech Connect

    Webb, S.W.

    1999-07-01

    Vapor diffusion in porous media in the presence of its own liquid may be enhanced due to pore-scale processes, such as condensation and evaporation across isolated liquid islands. Webb and Ho (1997) developed one-and two-dimensional mechanistic pore-scale models of these processes in an ideal porous medium. For isothermal and isobaric boundary conditions with a concentration gradient, the vapor diffusion rate was significantly enhanced by these liquid island processes compared to a dry porous media. The influence of a temperature gradient on the enhanced vapor diffusion rate is considered in this paper. The two-dimensional pore network model which is used in the present study is shown. For partially-saturated conditions, a liquid island is introduced into the top center pore. Boundary conditions on the left and right sides of the model are specified to give the desired concentration and temperature gradients. Vapor condenses on one side of the liquid island and evaporates off the other side due to local vapor pressure lowering caused by the interface curvature, even without a temperature gradient. Rather than acting as an impediment to vapor diffusion, the liquid island actually enhances the vapor diffusion rate. The enhancement of the vapor diffusion rate can be significant depending on the liquid saturation. Vapor diffusion is enhanced by up to 40% for this single liquid island compared to a dry porous medium; enhancement factors of up to an order of magnitude have been calculated for other conditions by Webb and Ho (1997). The dominant effect on the enhancement factor is the concentration gradient; the influence of the temperature gradient is smaller. The significance of these results, which need to be confirmed by experiments, is that the dominant model of enhanced vapor diffusion (EVD) by Philip and deVries (1957) predicts that temperature gradients must exist for EVD to occur. If there is no temperature gradient, there is no enhancement. The present results

  15. Variations of temperature, concentration, and supersaturation in a laboratory-scale saturated solar pond

    SciTech Connect

    Vitner, A.; Sarig, S. )

    1990-01-01

    A laboratory simulation system of saturated solar pond using alum potash was operated in a series of experiments of 30 to 120 days duration. The system consisted of an insulated column 100 cm deep, heated at the bottom by heat exchangers with varying energy output. The supersaturation, temperature and concentration in the upper layer as a function of time are presented. Both insufficient and excessive heat flow cause failure of the layered configuration. Suitably, adjusted heat flow allows preservation of the layered structure. The concentration of the upper layer and the supersaturation display cyclic character: after attaining high supersaturation massive crystallization occurs with crystals sinking to the bottom where they are dissolved. The upward diffusion from the highly concentrated bottom solution completes the solute cycle and maintains the stability of the pond.

  16. Heating and cooling in adiabatic mixing process

    SciTech Connect

    Zhou Jing; Zou Xubo; Guo Guangcan; Cai Zi

    2010-12-15

    We study the effect of interaction on the temperature change in the process of adiabatic mixing of two components of Fermi gases using the real-space Bogoliubov-de Gennes method. We find that in the process of adiabatic mixing, the competition between the adiabatic expansion and the attractive interaction makes it possible to cool or heat the system depending on the strength of the interaction and the initial temperature of the system. The changes of the temperature in a bulk system and in a trapped system are investigated.

  17. Effects of episodic low aragonite saturation and elevated temperature on the physiology of Stylophora pistillata

    NASA Astrophysics Data System (ADS)

    Lürig, M.; Kunzmann, A.

    2015-05-01

    As global climate change is predicted to gradually alter the oceans' carbonate system and water temperature, knowledge about the effects an altered marine environment has on the physiology of reef building (hermatypic) coral species is more widely established. However, although it is recognized that seawater temperature and the carbonate system of a coral reef can change rapidly and with great amplitude, little is known about how the interaction of these natural fluctuations with long term effects of climate change may affect the metabolism and productivity of hermatypic corals. To investigate this, we acclimated the hermatypic coral Stylophora pistillata to a "worst case" scenario for carbon dioxide emissions (aragonite saturation state [ΩARAG] = 1.6), and tested how exposure to short term (24 h) elevated temperature (+ 3 °C) and further lowered ΩARAG (-1 unit) affected its photosynthesis and respiration. While episodic exposure to very low ΩARAG had only little effect on S. pistillata's physiology, short term heat stress caused a shift from net oxygen production to consumption and partial coral bleaching. Higher gross coral respiration, and lowered photosynthetic activity under episodically elevated temperature may have been the result of photoinhibition and partial coral bleaching. These findings suggest that fluctuating environmental conditions in combination with a low ΩARAG background signal may impair basic metabolic processes in calcifying corals. In a future high-CO2 world short term stress could be relevant for reef ecosystem processes, and may affect the resilience of coral reefs to other external influences and effects of climate change.

  18. Long-Range Distance Measurements in Proteins at Physiological Temperatures Using Saturation Recovery EPR Spectroscopy

    PubMed Central

    2015-01-01

    Site-directed spin labeling in combination with EPR is a powerful method for providing distances on the nm scale in biological systems. The most popular strategy, double electron–electron resonance (DEER), is carried out at cryogenic temperatures (50–80 K) to increase the short spin–spin relaxation time (T2) upon which the technique relies. A challenge is to measure long-range distances (20–60 Å) in proteins near physiological temperatures. Toward this goal we are investigating an alternative approach based on the distance-dependent enhancement of spin–lattice relaxation rate (T1–1) of a nitroxide spin label by a paramagnetic metal. With a commonly used nitroxide side chain (R1) and Cu2+, it has been found that interspin distances ≤25 Å can be determined in this way (Jun et al. Biochemistry2006, 45, 11666). Here, the upper limit of the accessible distance is extended to ≈40 Å using spin labels with long T1, a high-affinity 5-residue Cu2+ binding loop inserted into the protein sequence, and pulsed saturation recovery to measure relaxation enhancement. Time-domain Cu2+ electron paramagnetic resonance, quantum mechanical calculations, and molecular dynamics simulations provide information on the structure and geometry of the Cu2+ loop and indicate that the metal ion is well-localized in the protein. An important aspect of these studies is that both Cu2+/nitroxide DEER at cryogenic temperatures and T1 relaxation measurements at room temperature can be carried out on the same sample, allowing both validation of the relaxation method and assessment of the effect of freezing on protein structure. PMID:25290172

  19. Constraints of propylene glycol degradation at low temperatures and saturated flow conditions.

    PubMed

    Lissner, Heidi; Wehrer, Markus; Reinicke, Martin; Horváth, Nikoletta; Totsche, Kai Uwe

    2015-02-01

    During snowmelt, the infiltration of large amounts of propylene glycol (PG), the major compound of many aircraft deicing fluids, affects redox processes and poses a contamination risk for the groundwater. To gain a better understanding about the degradation of PG and the associated biogeochemical processes under these conditions, we conducted saturated soil column experiments at 4 °C. During two successive PG pulses, we monitored the effect of the runway deicer formate (FO) and changing redox conditions on PG degradation. Furthermore, we applied first-order and simplified Monod kinetics to describe PG and FO transport. The transport of 50 mg l(-1) PG showed three stages of microbial degradation, which were defined as lag phase, aerobic phase, and anaerobic phase. During the second pulse, lag effects diminished due to the already accomplished microbial adaption, and the initial degradation rate of PG increased. Degradation of PG was most efficient during aerobic conditions (aerobic phase), while the subsequent drop of the redox potential down to -300 mV decreased the degradation rate (anaerobic phase). Formate addition decreased the overall degradation of PG by 50 and 15 % during the first and second pulse, illustrating the inhibitory effect of FO on PG degradation. The concurrent increase of Fe(III), organic carbon, and the turbidity in the column effluent after PG and FO application suggest the combined export of Fe adsorbed to fragments of detached biofilm. Neither the first-order nor the simplified Monod model was able to reconstruct the dynamic breakthrough of 50 mg l(-1) PG. The breakthrough of 1,000 mg l(-1), however, was described reasonably well with first-order kinetics. At low temperature and high water saturation, the application of first-order degradation kinetics seems therefore appropriate to describe the transport of high concentrations of PG.

  20. Hydrogenation at low temperatures does not always lead to saturation: the case of HNCO

    NASA Astrophysics Data System (ADS)

    Noble, J. A.; Theule, P.; Congiu, E.; Dulieu, F.; Bonnin, M.; Bassas, A.; Duvernay, F.; Danger, G.; Chiavassa, T.

    2015-04-01

    Context. It is generally agreed that hydrogenation reactions dominate chemistry on grain surfaces in cold, dense molecular cores, saturating the molecules present in ice mantles. Aims: We present a study of the low temperature reactivity of solid phase isocyanic acid (HNCO) with hydrogen atoms, with the aim of elucidating its reaction network. Methods: Fourier transform infrared spectroscopy and mass spectrometry were employed to follow the evolution of pure HNCO ice during bombardment with H atoms. Both multilayer and monolayer regimes were investigated. Results: The hydrogenation of HNCO does not produce detectable amounts of formamide (NH2CHO) as the major product. Experiments using deuterium reveal that deuteration of solid HNCO occurs rapidly, probably via cyclic reaction paths regenerating HNCO. Chemical desorption during these reaction cycles leads to loss of HNCO from the surface. Conclusions: It is unlikely that significant quantities of NH2CHO form from HNCO. In dense regions, however, deuteration of HNCO will occur. HNCO and DNCO will be introduced into the gas phase, even at low temperatures, as a result of chemical desorption.

  1. Adiabatic Demagnetization Cooler For Far Infrared Detector

    NASA Astrophysics Data System (ADS)

    Sato, Akio; Yazawa, Takashi; Yamamoto, Junya

    1988-11-01

    An small adiabatic demagnetization cooler for an astronomical far infrared detector has been built. Single crystals of manganese ammonium sulphate and chromium potassium alum, were prepared as magnetic substances. The superconducting magnet was indirectly cooled and operated by small current up to 13.3 A, the maximum field being 3.5 T. As a preliminary step, adiabatic demagnetization to zero field was implemented. The lowest temperature obtained was 0.5 K, for 5.0 K initial temperature.

  2. Field study and simulation of diurnal temperature effects on infiltration and variably saturated flow beneath an ephemeral stream

    USGS Publications Warehouse

    Ronan, A.D.; Prudic, D.E.; Thodal, C.E.; Constantz, J.

    1998-01-01

    Two experiments were performed to investigate flow beneath an ephemeral stream and to estimate streambed infiltration rates. Discharge and stream-area measurements were used to determine infiltration rates. Stream and subsurface temperatures were used to interpret subsurface flow through variably saturated sediments beneath the stream. Spatial variations in subsurface temperatures suggest that flow beneath the streambed is dependent on the orientation of the stream in the canyon and the layering of the sediments. Streamflow and infiltration rates vary diurnally: Stream flow is lowest in late afternoon when stream temperature is greatest and highest in early morning when stream temperature is least. The lower afternoon streamflow is attributed to increased infiltration rates; evapotranspiration is insufficient to account for the decreased streamflow. The increased infiltration rates are attributed to viscosity effects on hydraulic conductivity from increased stream temperatures. The first set of field data was used to calibrate a two-dimensional variably saturated flow model that includes heat transport. The model was calibrated to (1) temperature fluctuations in the subsurface and (2) infiltration rates determined from measured stream flow losses. The second set of field data was to evaluate the ability to predict infiltration rates on the basis of temperature measurements alone. Results indicate that the variably saturated subsurface flow depends on downcanyon layering of the sediments. They also support the field observations in indicating that diurnal changes in infiltration can be explained by temperature dependence of hydraulic conductivity. Over the range of temperatures and flows monitored, diurnal stream temperature changes can be used to estimate streambed infiltration rates. It is often impractical to maintain equipment for determining infiltration rates by traditional means; however, once a model is calibrated using both infiltration and temperature data

  3. High-Temperature Saturation Can Produce the [CII] Deficit in LIRGs and ULIRGs

    NASA Astrophysics Data System (ADS)

    Muñoz, Joseph A.; Oh, S. Peng

    2016-08-01

    Current predictions for the line ratios from photo-dissociative regions (PDRs) in galaxies adopt theoretical models that consider only individual parcels of PDR gas each characterized by the local density and far-UV radiation field. However, these quantities are not measured directly from unresolved galaxies, making the connection between theory and observation ambiguous. We develop a model that uses galaxy-averaged, observable inputs to explain and predict measurements of the [CII] fine structure line in luminous and ultra-luminous infrared galaxies. While there are a number of potential explanations for the [CII] deficit observed in the highest IR surface-brightness systems, such as 'dust-bounded' HII regions and grain charging, we propose a simpler solution where the [CII] deficit arises from saturating the upper fine-structure transition state at gas temperatures above 91 K. To reproduce the measured amplitude of the [CII]/FIR ratio in deficit galaxies, we require that [CII] trace approximately 10-17% of all gas in these systems, roughly independent of IR surface brightness and consistent with observed [CII] to CO(1-0) line ratios. Calculating the value of this fraction is a challenge for theoretical models. The difficulty may reside in properly treating the topology of molecular and dissociated gas, different descriptions for which may be observationally distinguished by the [OI]63 μm line in yet-to-be-probed regions of parameter space, allowing PDR emission lines from to probe not only the effects of star formation but also the state and configuration of interstellar gas.

  4. Temperature effect on the transport of bromide and E. coli NAR in saturated soils

    NASA Astrophysics Data System (ADS)

    Gharabaghi, B.; Safadoust, A.; Mahboubi, A. A.; Mosaddeghi, M. R.; Unc, A.; Ahrens, B.; Sayyad, Gh.

    2015-03-01

    In this study we investigated the transport of nalidixic acid-resistant Escherichia coli (E. coli NAR) and bromide (Br-) through two soils, a sandy loam (SL) and clay loam (CL). Soils were repacked in columns (45 cm length × 22 cm diameter) and subjected to physical (freeze/thaw, and wet/dry cycles) and biological (by earthworms, Eisenia fetida) weathering for 12 months. Saturated flow conditions were maintained using a tension infiltrometer. Tests were carried out at either 5 or 20 °C. After steady-state flow conditions were established, a suspension containing E. coli NAR and Br- was sprayed onto the surface of soil columns. Leachate was sampled at three depths, 15, 30 and 45 cm. Time to maximum concentration (Cmax) of E. coli NAR was greater for SL at all depths. Both tracers had rapid breakthrough curves (BTCs) shortly after the suspension injection followed by prolonged tailing indicating the presence of preferential pathways and thus soil heterogeneity regenerated after the induced physical and biological weathering. About 40% of the E. coli NAR and 79% of the Br- leached through the entire 45 cm soil columns during the experiments. Leaching with cold water (5 °C) led to lower hydraulic conductivity and flow rate and consequently enhanced bacterial filtration for both soils. Very low values for the detachment coefficient for E. coli NAR at 5 °C suggest an irreversible process of bacterial attachment in heterogeneous soils. BTCs were well described by the mobile-immobile model (MIM) in HYDRUS-1D. Soil texture/structure and temperature had a significant effect on the model's fitted parameters.

  5. High-Temperature Studies of Glass Dissolution Rates Close to Saturation

    SciTech Connect

    Zavarin, M; Roberts, S; Zhao, P; Williams, R; Rose, T; Rainer, A; Pawloski, G

    2004-06-14

    Most long-lived radionuclides associated with an underground nuclear test are incorporated into a melt glass and are released by glass dissolution to become part of the hydrologic source term (HST) (Pawloski et al., 2001). Although the rates of rhyolite glass dissolution are well known under conditions where the fluid is far from saturation with respect to glass, the rates are not well known under conditions where the fluid approaches saturation. These rates are commonly much lower than the far-fromsaturation rates, often by a factor greater than 100. In recent HST simulations (Pawloski et al., 2001; Pawloski et al., 2000; Tompson et al., 1999), we conservatively estimated steady-state release rates based on a far-from-saturation fluid conditions. In recent CHESHIRE near-field simulations (Pawloski et al., 2001), it was predicted that {approx}30% of the nuclear melt glass dissolved over 1000 years. Although the ''far-from-saturation rate'' approach provides a conservative estimate of glass dissolution, it may greatly overestimate the rates of melt glass dissolution. At CHESHIRE, less conservative estimates suggest that only {approx}1% of the nuclear melt glass will dissolve in 1000 years. Lower glass dissolution rates result in lower radionuclide release rates from nuclear melt glass. The following report documents glass dissolution experiments performed to measure glass dissolution rates close to saturation.

  6. Adiabatic Quantum Search in Open Systems

    NASA Astrophysics Data System (ADS)

    Wild, Dominik S.; Gopalakrishnan, Sarang; Knap, Michael; Yao, Norman Y.; Lukin, Mikhail D.

    2016-10-01

    Adiabatic quantum algorithms represent a promising approach to universal quantum computation. In isolated systems, a key limitation to such algorithms is the presence of avoided level crossings, where gaps become extremely small. In open quantum systems, the fundamental robustness of adiabatic algorithms remains unresolved. Here, we study the dynamics near an avoided level crossing associated with the adiabatic quantum search algorithm, when the system is coupled to a generic environment. At zero temperature, we find that the algorithm remains scalable provided the noise spectral density of the environment decays sufficiently fast at low frequencies. By contrast, higher order scattering processes render the algorithm inefficient at any finite temperature regardless of the spectral density, implying that no quantum speedup can be achieved. Extensions and implications for other adiabatic quantum algorithms will be discussed.

  7. Temperature dependences of saturated vapor pressure and the enthalpy of vaporization of n-pentyl esters of dicarboxylic acids

    NASA Astrophysics Data System (ADS)

    Portnova, S. V.; Krasnykh, E. L.; Levanova, S. V.

    2016-05-01

    The saturated vapor pressures and enthalpies of vaporization of n-pentyl esters of linear C2-C6 dicarboxylic acids are determined by the transpiration method in the temperature range of 309.2-361.2 K. The dependences of enthalpies of vaporization on the number of carbon atoms in the molecule and on the retention indices have been determined. The predictive capabilities of the existing calculation schemes for estimation of enthalpy of vaporization of the studied compounds have been analyzed.

  8. Atomic long-range order effects on Curie temperature and adiabatic spin-wave dynamics in strained Fe-Co alloy films

    NASA Astrophysics Data System (ADS)

    Schönecker, Stephan; Li, Xiaoqing; Johansson, Börje; Vitos, Levente

    2016-08-01

    The strained Fe-Co alloy in body-centered tetragonal (bct) structure has raised considerable interest due to its giant uniaxial magnetocrystalline anisotropy energy. On the basis of the classical Heisenberg Hamiltonian with ab initio interatomic exchange interactions, we perform a theoretical study of fundamental finite temperature magnetic properties of Fe1 -xCox alloy films as a function of three variables: chemical composition 0.3 ≤x ≤0.8 , bct geometry [a ,c (a )] arising from in-plane strain and associated out-of-plane relaxation, and atomic long-range order (ALRO). The Curie temperatures TC(x ,a ) obtained from Monte Carlo simulations display a competition between a pronounced dependence on tetragonality, strong ferromagnetism in the Co-rich alloy, and the beginning instability of ferromagnetic order in the Fe-rich alloy when c /a →√{2 } . Atomic ordering enhances TC and arises mainly due to different distributions of atoms in neighboring coordination shells rather than altering exchange interactions significantly. We investigate the ordering effect on the shape of the adiabatic spin-wave spectrum for selected pairs (x ,a ) . Our results indicate that long-wavelength acoustic spin-wave excitations show dependencies on x , a , and ALRO similar to those of TC. The directional anisotropy of the spin-wave stiffness d (x ,a ) peaks in narrow ranges of composition and tetragonality. ALRO exhibits a strong effect on d for near equiconcentration Fe-Co. We also discuss our findings in the context of employing Fe-Co as perpendicular magnetic recording medium.

  9. Wireless adiabatic power transfer

    SciTech Connect

    Rangelov, A.A.; Suchowski, H.; Silberberg, Y.; Vitanov, N.V.

    2011-03-15

    Research Highlights: > Efficient and robust mid-range wireless energy transfer between two coils. > The adiabatic energy transfer is analogous to adiabatic passage in quantum optics. > Wireless energy transfer is insensitive to any resonant constraints. > Wireless energy transfer is insensitive to noise in the neighborhood of the coils. - Abstract: We propose a technique for efficient mid-range wireless power transfer between two coils, by adapting the process of adiabatic passage for a coherently driven two-state quantum system to the realm of wireless energy transfer. The proposed technique is shown to be robust to noise, resonant constraints, and other interferences that exist in the neighborhood of the coils.

  10. Adiabatic Compression in a Fire Syringe.

    ERIC Educational Resources Information Center

    Hayn, Carl H.; Baird, Scott C.

    1985-01-01

    Suggests using better materials in fire syringes to obtain more effective results during demonstrations which show the elevation in temperature upon a very rapid (adiabatic) compression of air. Also describes an experiment (using ignition temperatures) which introduces students to the use of thermocouples for high temperature measurements. (DH)

  11. Effect of the drilling mud filtrate temperature on the resistivity of the stratum saturated by oil and gas

    NASA Astrophysics Data System (ADS)

    Pen'kovskii, V. I.; Korsakova, N. K.; Nesterova, G. V.

    2014-09-01

    A mathematical model of the axisymmetric distribution of the phases in the zone of invasion of the water-based drilling mud into the productive stratum whose porous space can simultaneously contain three immiscible fluids (oil, gas, and natural water) is constructed; the model takes into account the high rate of heat transfer between the fluids and the rock matrix. It is shown that the resistivity of the invaded zone depends not only on saturation of the latter by the fluids and the concentration of salts in the water phase, but also on the drilling mud filtrate temperature. It is also shown that there is a jump in the function of stratum saturation by oil on the thermal front.

  12. Implications from zircon-saturation temperatures and lithological assemblages for Early Permian thermal anomaly in northwest China

    NASA Astrophysics Data System (ADS)

    Liu, Hai-Quan; Xu, Yi-Gang; He, Bin

    2013-12-01

    Despite considerable efforts, the Paleozoic tectonic setting (subduction vs. post-collision vs. mantle plume) in the Central Asian Orogenic Belt (CAOB) remains controversial. With aims of solving this issue, we examined zircon saturation temperatures of granitoids emplaced in different settings, and demonstrated that zircon saturation thermometry of felsic igneous rocks, especially when integrated with their lithology and geochemistry, can be a simple and powerful tool for tectonic discrimination. This method is then applied in northern Xinjiang where the Early Permian granitoids have higher saturation temperatures (> 800 °C) than the Silurian-Carboniferous granitoids (mainly < 800 °C). Moreover, the latter are mainly of I-type and are characterized by relatively narrow range of uniformly higher εNd. Consistent with high εHf in zircons from contemporaneous ultramafic-mafic complexes, they were most likely derived from subduction-related processes. In contrast, the high-temperature Early Permian granitoids and associated ultramafic-mafic rocks show a wide range in εNd and εHf in zircons, consistent with the involvement of a great variety of crustal and mantle materials in magma genesis. The thermal anomaly and diversity of Permian magmatic rocks in the CAOB can be ascribed to a mantle plume activity, in agreement with widespread contemporaneous flood basalts, and associated mafic dykes and ultramafic complex in Tarim. Therefore, the temporal variation in temperature and geochemistry of Paleozoic granitoids in northern Xinjiang mirrors a significant change in tectonic setting from a subduction-collision setting during Silurian-Carboniferous to an intra-plate setting since Early Permian.

  13. Parallelizable adiabatic gate teleportation

    NASA Astrophysics Data System (ADS)

    Nakago, Kosuke; Hajdušek, Michal; Nakayama, Shojun; Murao, Mio

    2015-12-01

    To investigate how a temporally ordered gate sequence can be parallelized in adiabatic implementations of quantum computation, we modify adiabatic gate teleportation, a model of quantum computation proposed by Bacon and Flammia [Phys. Rev. Lett. 103, 120504 (2009), 10.1103/PhysRevLett.103.120504], to a form deterministically simulating parallelized gate teleportation, which is achievable only by postselection. We introduce a twisted Heisenberg-type interaction Hamiltonian, a Heisenberg-type spin interaction where the coordinates of the second qubit are twisted according to a unitary gate. We develop parallelizable adiabatic gate teleportation (PAGT) where a sequence of unitary gates is performed in a single step of the adiabatic process. In PAGT, numeric calculations suggest the necessary time for the adiabatic evolution implementing a sequence of L unitary gates increases at most as O (L5) . However, we show that it has the interesting property that it can map the temporal order of gates to the spatial order of interactions specified by the final Hamiltonian. Using this property, we present a controlled-PAGT scheme to manipulate the order of gates by a control qubit. In the controlled-PAGT scheme, two differently ordered sequential unitary gates F G and G F are coherently performed depending on the state of a control qubit by simultaneously applying the twisted Heisenberg-type interaction Hamiltonians implementing unitary gates F and G . We investigate why the twisted Heisenberg-type interaction Hamiltonian allows PAGT. We show that the twisted Heisenberg-type interaction Hamiltonian has an ability to perform a transposed unitary gate by just modifying the space ordering of the final Hamiltonian implementing a unitary gate in adiabatic gate teleportation. The dynamics generated by the time-reversed Hamiltonian represented by the transposed unitary gate enables deterministic simulation of a postselected event of parallelized gate teleportation in adiabatic

  14. Energy efficiency of adiabatic superconductor logic

    NASA Astrophysics Data System (ADS)

    Takeuchi, Naoki; Yamanashi, Yuki; Yoshikawa, Nobuyuki

    2015-01-01

    Adiabatic superconductor logic (ASL), including adiabatic quantum-flux-parametron (AQFP) logic, exhibits high energy efficiency because its bit energy can be decreased below the thermal energy through adiabatic switching operations. In the present paper, we present the general scaling laws of ASL and compare the energy efficiency of ASL with those of other energy-efficient logics. Also, we discuss the minimum energy-delay product (EDP) of ASL at finite temperature. Our study shows that there is a maximum temperature at which the EDP can reach the quantum limit given by ħ/2, which is dependent on the superconductor material and the Josephson junction quality, and that it is reasonable to operate ASL at cryogenic temperatures in order to achieve an EDP that approaches ħ/2.

  15. Adiabaticity and viscosity in deep mantle convection

    NASA Technical Reports Server (NTRS)

    Quareni, F.; Yuen, D. A.; Saari, M. R.

    1986-01-01

    A study has been conducted of steady convection with adiabatic and viscous heating for variable viscosity in the Boussinesq limit using the mean-field theory. A strong nonlinear coupling is found between the thermodynamic constants governing adiabatic heating and the rheological parameters. The range of rheological values for which adiabaticity would occur throughout the mantle has been established. Too large an activation volume, greater than 6 cu cm/mol for the cases examined, would produce unreasonably high temperature at the bottom of the mantle (greater than 6000 K) and superadiabatic gradients, especially in the lower mantle. Radiogenic heating plays a profound role in controlling dynamically mantle temperatures. Present values for the averaged mantle heat production would yield objectionably high temperatures in the lower mantle.

  16. Effect of temperature on hydration kinetics and polymerization of tricalcium silicate in stirred suspensions of CaO-saturated solutions

    SciTech Connect

    Grant, Steven A. . E-mail: steven.a.grant@usace.army.mil; Boitnott, Ginger E.; Korhonen, Charles J.; Sletten, Ronald S.

    2006-04-15

    Tricalcium silicate was hydrated at 274, 278, 283, 298, and 313 K in stirred suspensions of saturated CaO solutions under a nitrogen-gas atmosphere until the end of deceleratory period. The suspension conductivities and energy flows were measured continuously. The individual reaction rates for tricalcium silicate dissolution, calcium silicate hydrate precipitation, and calcium hydroxide precipitation were calculated from these measurements. The results suggest that the proportion of tricalcium silicate dissolved was determined by the rate of tricalcium silicate dissolution and the time to very rapid calcium hydroxide precipitation. The time to very rapid calcium hydroxide precipitation was more sensitive to changes in temperature than was the rate of tricalcium silicate dissolution, so that the proportion of tricalcium silicate hydration dissolved by the deceleratory period increased with decreasing temperature. The average chain length of the calcium silicate hydrate ascertained by magic-angle spinning nuclear magnetic resonance spectroscopy increased with increasing temperature.

  17. Characterization of saturated MHD instabilities through 2D electron temperature profile reconstruction from 1D ECE measurements

    NASA Astrophysics Data System (ADS)

    Sertoli, M.; Horváth, L.; Pokol, G. I.; Igochine, V.; Barrera, L.

    2013-05-01

    A new method for the reconstruction of two-dimensional (2D) electron temperature profiles in the presence of saturated magneto-hydro-dynamic (MHD) modes from the one-dimensional (1D) electron cyclotron emission (ECE) diagnostic is presented. The analysis relies on harmonic decomposition of the electron temperature oscillations through short time Fourier transforms and requires rigid poloidal mode rotation as the only assumption. The method is applicable to any magnetic perturbation as long as the poloidal and toroidal mode numbers m and n are known. Its application to the case of a (m, n) = (1, 1) internal kink mode on ASDEX Upgrade is presented and a new way to estimate the mode displacement is explained. For such modes, it is shown that the higher order harmonics usually visible in the ECE spectrogram arise also for the pure m = n = 1 mode and that they cannot be directly associated with m = n > 1 magnetic perturbations. This method opens up new possibilities for electron heat transport studies in the presence of saturated MHD modes and a way to disentangle the impurity density contributions from electron temperature effects in the analysis of the soft x-ray data.

  18. Reactions of C{sub 2}(a {sup 3} product {sub u}) with selected saturated alkanes: A temperature dependence study

    SciTech Connect

    Hu Renzhi; Zhang Qun; Chen Yang

    2010-04-28

    We present a temperature dependence study on the gas phase reactions of the C{sub 2}(a {sup 3} product {sub u}) radical with a selected series of saturated alkanes (C{sub 2}H{sub 6}, C{sub 3}H{sub 8}, n-C{sub 4}H{sub 10}, i-C{sub 4}H{sub 10}, and n-C{sub 6}H{sub 14}) by means of pulsed laser photolysis/laser-induced fluorescence technique. The bimolecular rate constants for these reactions were obtained between 298 and 673 K. A pronounced negative temperature effect was observed for n-C{sub 4}H{sub 10}, i-C{sub 4}H{sub 10}, and n-C{sub 6}H{sub 14} and interpreted in terms of steric hindrance of the more reactive secondary or tertiary C-H bonds by less reactive CH{sub 3} groups. Detailed analysis of our experimental results reveals quantitatively the temperature dependence of reactivities for the primary, secondary, and tertiary C-H bonds in these saturated alkanes and further lends support to a mechanism of hydrogen abstraction.

  19. Predictive Relationships for pH and Carbonate Saturation in the Southern California Current System Using Oxygen and Temperature Data

    NASA Astrophysics Data System (ADS)

    Alin, S. R.; Feely, R. A.; Dickson, A. G.; Hernandez-Ayon, J. M.; Juranek, L. W.; Ohman, M. D.; Goericke, R.

    2010-12-01

    The California Current System is expected to experience the ecological impacts of ocean acidification earlier than most other ocean regions because marine waters in the North Pacific are among the oldest in the global oceans and natural upwelling processes in this eastern boundary current system bring CO2-rich water masses to the surface in coastal oceans during late spring-early fall months. We used a multiple linear regression (MLR) approach to generate predictive models using oxygen and temperature as proxy variables to reconstruct pH and carbonate saturation states in the Southern California Bight. The calibration data set included high-quality measurements of dissolved inorganic carbon, alkalinity, oxygen, temperature, salinity, and nutrients and was collected during a cruise from British Columbia to Baja California in May-June 2007. The resulting relationships predicting pH and aragonite and calcite saturation states (Ω) from oxygen and temperature data were robust, with r2 values >0.98 and root mean square errors of 0.020 (pH), 0.048 (Ωarag), and 0.075 (Ωcalc). Predicted vs. measured ocean acidification conditions (i.e. pH, Ωarag, and Ωcalc) matched very well for seven verification data sets collected between 2008 and 2010 during quarterly CalCOFI cruises in the Southern California Bight and during several sampling dates on an Ensenada transect occupied several times between 2006 and 2010. Over sub-decadal time scales, these predictive models provide a valuable tool for reconstructing historical time-series of ocean acidification conditions in the California Current Ecosystem where historical inorganic carbon measurements are scarce. Reconstructed pH and saturation state values based on CalCOFI oxygen and temperature data for all cruises between 2005 and 2010 reveal a seasonal cycle in the upper water column, with higher pH and Ω values present during the winter cruises, and stronger gradients including much lower pH and Ω values during spring through

  20. Adiabatic processes in monatomic gases

    NASA Astrophysics Data System (ADS)

    Carrera-Patiño, Martin E.

    1988-08-01

    A kinetic model is used to predict the temperature evolution of a monatomic ideal gas undergoing an adiabatic expansion or compression at a constant finite rate, and it is then generalized to treat real gases. The effects of interatomic forces are considered, using as examples the gas with the square-well potential and the van der Waals gas. The model is integrated into a Carnot cycle operating at a finite rate to compare the efficiency's rate-dependent behavior with the reversible result. Limitations of the model, rate penalties, and their importance are discussed.

  1. Adiabatic capture and debunching

    SciTech Connect

    Ng, K.Y.; /Fermilab

    2012-03-01

    In the study of beam preparation for the g-2 experiment, adiabatic debunching and adiabatic capture are revisited. The voltage programs for these adiabbatic processes are derived and their properties discussed. Comparison is made with some other form of adiabatic capture program. The muon g-2 experiment at Fermilab calls for intense proton bunches for the creation of muons. A booster batch of 84 bunches is injected into the Recycler Ring, where it is debunched and captured into 4 intense bunches with the 2.5-MHz rf. The experiment requires short bunches with total width less than 100 ns. The transport line from the Recycler to the muon-production target has a low momentum aperture of {approx} {+-}22 MeV. Thus each of the 4 intense proton bunches required to have an emittance less than {approx} 3.46 eVs. The incoming booster bunches have total emittance {approx} 8.4 eVs, or each one with an emittance {approx} 0.1 eVs. However, there is always emittance increase when the 84 booster bunches are debunched. There will be even larger emittance increase during adiabatic capture into the buckets of the 2.5-MHz rf. In addition, the incoming booster bunches may have emittances larger than 0.1 eVs. In this article, we will concentrate on the analysis of the adiabatic capture process with the intention of preserving the beam emittance as much as possible. At this moment, beam preparation experiment is being performed at the Main Injector. Since the Main Injector and the Recycler Ring have roughly the same lattice properties, we are referring to adiabatic capture in the Main Injector instead in our discussions.

  2. Adiabatic gate teleportation.

    PubMed

    Bacon, Dave; Flammia, Steven T

    2009-09-18

    The difficulty in producing precisely timed and controlled quantum gates is a significant source of error in many physical implementations of quantum computers. Here we introduce a simple universal primitive, adiabatic gate teleportation, which is robust to timing errors and many control errors and maintains a constant energy gap throughout the computation above a degenerate ground state space. This construction allows for geometric robustness based upon the control of two independent qubit interactions. Further, our piecewise adiabatic evolution easily relates to the quantum circuit model, enabling the use of standard methods from fault-tolerance theory for establishing thresholds.

  3. The adiabatic phase mixing and heating of electrons in Buneman turbulence

    SciTech Connect

    Che, H.; Goldstein, M. L.; Drake, J. F.; Swisdak, M.

    2013-06-15

    The nonlinear development of the strong Buneman instability and the associated fast electron heating in thin current layers with Ω{sub e}/ω{sub pe}<1 is explored. Phase mixing of the electrons in wave potential troughs and a rapid increase in temperature are observed during the saturation of the instability. We show that the motion of trapped electrons can be described using a Hamiltonian formalism in the adiabatic approximation. The process of separatrix crossing as electrons are trapped and de-trapped is irreversible and guarantees that the resulting electron energy gain is a true heating process.

  4. Adiabatically implementing quantum gates

    SciTech Connect

    Sun, Jie; Lu, Songfeng Liu, Fang

    2014-06-14

    We show that, through the approach of quantum adiabatic evolution, all of the usual quantum gates can be implemented efficiently, yielding running time of order O(1). This may be considered as a useful alternative to the standard quantum computing approach, which involves quantum gates transforming quantum states during the computing process.

  5. Entanglement and adiabatic quantum computation

    NASA Astrophysics Data System (ADS)

    Ahrensmeier, D.

    2006-06-01

    Adiabatic quantum computation provides an alternative approach to quantum computation using a time-dependent Hamiltonian. The time evolution of entanglement during the adiabatic quantum search algorithm is studied, and its relevance as a resource is discussed.

  6. Assessment of total efficiency in adiabatic engines

    NASA Astrophysics Data System (ADS)

    Mitianiec, W.

    2016-09-01

    The paper presents influence of ceramic coating in all surfaces of the combustion chamber of SI four-stroke engine on working parameters mainly on heat balance and total efficiency. Three cases of engine were considered: standard without ceramic coating, fully adiabatic combustion chamber and engine with different thickness of ceramic coating. Consideration of adiabatic or semi-adiabatic engine was connected with mathematical modelling of heat transfer from the cylinder gas to the cooling medium. This model takes into account changeable convection coefficient based on the experimental formulas of Woschni, heat conductivity of multi-layer walls and also small effect of radiation in SI engines. The simulation model was elaborated with full heat transfer to the cooling medium and unsteady gas flow in the engine intake and exhaust systems. The computer program taking into account 0D model of engine processes in the cylinder and 1D model of gas flow was elaborated for determination of many basic engine thermodynamic parameters for Suzuki DR-Z400S 400 cc SI engine. The paper presents calculation results of influence of the ceramic coating thickness on indicated pressure, specific fuel consumption, cooling and exhaust heat losses. Next it were presented comparisons of effective power, heat losses in the cooling and exhaust systems, total efficiency in function of engine rotational speed and also comparison of temperature inside the cylinder for standard, semi-adiabatic and full adiabatic engine. On the basis of the achieved results it was found higher total efficiency of adiabatic engines at 2500 rpm from 27% for standard engine to 37% for full adiabatic engine.

  7. Temperature and saturation dependence in the vapor sensing of butterfly wing scales.

    PubMed

    Kertész, K; Piszter, G; Jakab, E; Bálint, Zs; Vértesy, Z; Biró, L P

    2014-06-01

    The sensing of gasses/vapors in the ambient air is the focus of attention due to the need to monitor our everyday environment. Photonic crystals are sensing materials of the future because of their strong light-manipulating properties. Natural photonic structures are well-suited materials for testing detection principles because they are significantly cheaper than artificial photonic structures and are available in larger sizes. Additionally, natural photonic structures may provide new ideas for developing novel artificial photonic nanoarchitectures with improved properties. In the present paper, we discuss the effects arising from the sensor temperature and the vapor concentration in air during measurements with a photonic crystal-type optical gas sensor. Our results shed light on the sources of discrepancy between simulated and experimental sensing behaviors of photonic crystal-type structures. Through capillary condensation, the vapors will condensate to a liquid state inside the nanocavities. Due to the temperature and radius of curvature dependence of capillary condensation, the measured signals are affected by the sensor temperature as well as by the presence of a nanocavity size distribution. The sensing materials used are natural photonic nanoarchitectures present in the wing scales of blue butterflies. PMID:24863219

  8. Temperature and saturation dependence in the vapor sensing of butterfly wing scales.

    PubMed

    Kertész, K; Piszter, G; Jakab, E; Bálint, Zs; Vértesy, Z; Biró, L P

    2014-06-01

    The sensing of gasses/vapors in the ambient air is the focus of attention due to the need to monitor our everyday environment. Photonic crystals are sensing materials of the future because of their strong light-manipulating properties. Natural photonic structures are well-suited materials for testing detection principles because they are significantly cheaper than artificial photonic structures and are available in larger sizes. Additionally, natural photonic structures may provide new ideas for developing novel artificial photonic nanoarchitectures with improved properties. In the present paper, we discuss the effects arising from the sensor temperature and the vapor concentration in air during measurements with a photonic crystal-type optical gas sensor. Our results shed light on the sources of discrepancy between simulated and experimental sensing behaviors of photonic crystal-type structures. Through capillary condensation, the vapors will condensate to a liquid state inside the nanocavities. Due to the temperature and radius of curvature dependence of capillary condensation, the measured signals are affected by the sensor temperature as well as by the presence of a nanocavity size distribution. The sensing materials used are natural photonic nanoarchitectures present in the wing scales of blue butterflies.

  9. Constraints on Subduction Zone Temperatures and Chemical Fluxes from Accessory Phase Saturation in Subducted Sediments (Invited)

    NASA Astrophysics Data System (ADS)

    Blundy, J.; Skora, S.

    2009-12-01

    A global correlation between the incompatible trace element chemistry of subducted sediments and that of magmas erupted through the overlying plate testifies to the important role that sediments play in controlling magmagenesis. We report new experimental data on the high pressure (3 GPa) and temperature (700-1300 °C) phase relations of hydrous red clay to evaluate the role of residual accessory phases in controlling the incompatible trace element chemistry of sediment-derived fluids. A particular focus is monazite, which preferentially incorporates LREE and Th, exerting a powerful control on the fluid Th/LREE ratio. Given that arc magmas appear to inherit the Th/LREE ratio of the associated subducting sediment, understanding monazite solubility and stability has the potential to provide new constraints on temperature at the slab surface, a parameter that is notoriously hard to pin down by other means. Experiments on red clay with H2O structurally bound in hydrous minerals (<2 wt%) produced negligible melt fractions for any reasonable temperatures. Experiments with 7-15 wt% added H2O produced copious melting at temperatures only 50-100°C above the solidus (c. 720 °C), e.g. with 15 wt% added H2O, the red clay is >50% molten at 800 °C. Irrespective of the amount of added H2O the residual assemblage comprised garnet and kyanite up to the liquidus (1250 °C with 7 wt% H2O). Phengite is present ≤800 °C; ilmenite and rutile persist to c. 1000 °C; quartz/coesite-out temperature decreases from 1000 °C with 7 wt% H2O to 800 °C with 15%. Monazite was stable to 950 °C in the Th- and LREE-doped starting materials that we used. The trace element contents of the residual melts in equilibrium with monazite-thorite solid solutions were used, in conjunction with published data, to develop a thermodynamic model of LREE and Th solubility in sediment-derived fluids. These models were used to calculate the stability of monazite in a red clay with natural LREE and Th levels

  10. Adiabatic reversible compression: a molecular view

    NASA Astrophysics Data System (ADS)

    Miranda, E. N.

    2002-07-01

    The adiabatic compression (or expansion) of an ideal gas has been analysed. Using the kinetic theory of gases the usual relation between temperature and volume is obtained, while textbooks follow a thermodynamic approach. In this way we show, once again, the agreement between a macroscopic view (thermodynamics) and a microscopic one (kinetic theory).

  11. Low temperature bainitic ferrite: Evidence of carbon super-saturation and tetragonality

    DOE PAGES

    Garcia-Mateo, C.; Jimenez, J. A.; Yen, Hung-Wei; Miller, Michael K.; Morales-Rivas, L; Kuntz, M; Ringer, S. P.; Yang, Jer-Ren; Caballero, Francesca G.

    2015-03-31

    Experimental evidence indicates that bainitic ferrite formed by transformation at low temperatures (200-350 °C) includes quantities of carbon in solid solution far beyond those expected from para-equilibrium. A change in the conventional symmetry of the bainitic ferrite lattice from cubic to tetragonal explains the abnormal solid solubility detected. This carbon supersaturation was measured by atom probe tomography, and the tetragonality of the bainitic ferrite, was characterized by means of X-ray diffraction analysis and high resolution transmission electron microscopy.

  12. Melting Temperature and Partial Melt Chemistry of H2O-Saturated Mantle Peridotite to 11 Gigapascals

    PubMed

    Kawamoto; Holloway

    1997-04-11

    The H2O-saturated solidus of a model mantle composition (Kilborne Hole peridotite nodule, KLB-1) was determined to be just above 1000°C from 5 to 11 gigapascals. Given reasonable H2O abundances in Earth's mantle, an H2O-rich fluid could exist only in a region defined by the wet solidus and thermal stability limits of hydrous minerals, at depths between 90 and 330 kilometers. The experimental partial melts monotonously became more mafic with increasing pressure from andesitic composition at 1 gigapascal to more mafic than the starting peridotite at 10 gigapascals. Because the chemistry of the experimental partial melts is similar to that of kimberlites, it is suggested that kimberlites may be derived by low-temperature melting of an H2O-rich mantle at depths of 150 to 300 kilometers. PMID:9092469

  13. Chemical characteristics and enzymatic saccharification of lignocellulosic biomass treated using high-temperature saturated steam: comparison of softwood and hardwood.

    PubMed

    Asada, Chikako; Sasaki, Chizuru; Hirano, Takeshi; Nakamura, Yoshitoshi

    2015-04-01

    This study investigated the effect of high-temperature saturated steam treatments on the chemical characteristics and enzymatic saccharification of softwood and hardwood. The weight loss and chemical modification of cedar and beech wood pieces treated at 25, 35, and 45 atm for 5 min were determined. Fourier transform infrared and X-ray diffraction analyses indicated that solubilization and removal of hemicellulose and lignin occurred by the steam treatment. The milling treatment of steam-treated wood enhanced its enzymatic saccharification. Maximum enzymatic saccharification (i.e., 94% saccharification rate of cellulose) was obtained using steam-treated beech at 35 atm for 5 min followed by milling treatment for 1 min. However, the necessity of the milling treatment for efficient enzymatic saccharification is dependent on the wood species.

  14. Melting Temperature and Partial Melt Chemistry of H2O-Saturated Mantle Peridotite to 11 Gigapascals

    PubMed

    Kawamoto; Holloway

    1997-04-11

    The H2O-saturated solidus of a model mantle composition (Kilborne Hole peridotite nodule, KLB-1) was determined to be just above 1000°C from 5 to 11 gigapascals. Given reasonable H2O abundances in Earth's mantle, an H2O-rich fluid could exist only in a region defined by the wet solidus and thermal stability limits of hydrous minerals, at depths between 90 and 330 kilometers. The experimental partial melts monotonously became more mafic with increasing pressure from andesitic composition at 1 gigapascal to more mafic than the starting peridotite at 10 gigapascals. Because the chemistry of the experimental partial melts is similar to that of kimberlites, it is suggested that kimberlites may be derived by low-temperature melting of an H2O-rich mantle at depths of 150 to 300 kilometers.

  15. Controlled experimental aquarium system for multi-stressor investigation: carbonate chemistry, oxygen saturation, and temperature

    NASA Astrophysics Data System (ADS)

    Bockmon, E. E.; Frieder, C. A.; Navarro, M. O.; White-Kershek, L. A.; Dickson, A. G.

    2013-02-01

    As the field of ocean acidification has grown, researchers have increasingly turned to laboratory experiments to understand the impacts of increased CO2 on marine organisms. However, other changes such as ocean warming and deoxygenation are occurring concurrently with the increasing CO2 concentrations, complicating the anthropogenic impact on organisms. This experimental aquarium design allows for independent regulation of CO2 concentration, O2 levels, and temperature in a controlled environment to study the impacts of multiple stressors. The system has the flexibility for a wide range of treatment chemistry, seawater volumes, and study organisms. Control of the seawater chemistry is achieved by equilibration of a chosen gas mixture with seawater using a Liqui-Cel® membrane contactor. Included as examples, two experiments performed using the system have shown control of CO2 between approximately 500-1400 μatm and O2 from 80-240 μmol kg-1. Temperature has been maintained to 0.5 °C or better in the range of 10-17 °C. On a weeklong timescale, control results in variability in pH of less than 0.007 pH units and in oxygen concentration less than 3.5 μmol kg-1. Longer experiments, over a month, have been completed with reasonable but lessened control, still better than 0.08 pH units and 13 μmol kg-1 O2. The ability to study the impacts of multiple stressors in the laboratory simultaneously, as well as independently, will be an important part of understanding the response of marine organisms to a high-CO2 world.

  16. Adiabatic topological quantum computing

    NASA Astrophysics Data System (ADS)

    Cesare, Chris; Landahl, Andrew J.; Bacon, Dave; Flammia, Steven T.; Neels, Alice

    2015-07-01

    Topological quantum computing promises error-resistant quantum computation without active error correction. However, there is a worry that during the process of executing quantum gates by braiding anyons around each other, extra anyonic excitations will be created that will disorder the encoded quantum information. Here, we explore this question in detail by studying adiabatic code deformations on Hamiltonians based on topological codes, notably Kitaev's surface codes and the more recently discovered color codes. We develop protocols that enable universal quantum computing by adiabatic evolution in a way that keeps the energy gap of the system constant with respect to the computation size and introduces only simple local Hamiltonian interactions. This allows one to perform holonomic quantum computing with these topological quantum computing systems. The tools we develop allow one to go beyond numerical simulations and understand these processes analytically.

  17. Triacylglyceride composition and fatty acyl saturation profile of a psychrophilic and psychrotolerant fungal species grown at different temperatures.

    PubMed

    Pannkuk, Evan L; Blair, Hannah B; Fischer, Amy E; Gerdes, Cheyenne L; Gilmore, David F; Savary, Brett J; Risch, Thomas S

    2014-01-01

    Pseudogymnoascus destructans is a psychrophilic fungus that infects cutaneous tissues in cave dwelling bats, and it is the causal agent for white nose syndrome (WNS) in North American (NA) bat populations. Geomyces pannorum is a related psychrotolerant keratinolytic species that is rarely a pathogen of mammals. In this study, we grew P. destructans and G. pannorum in static liquid cultures at favourable and suboptimal temperatures to: 1) determine if triacylglyceride profiles are species-specific, and 2) determine if there are differences in fatty acyl (FA) saturation levels with respect to temperature. Total lipids isolated from both fungal spp. were separated by thin-layer chromatography and determined to be primarily sterols (∼15 %), free fatty acids (FFAs) (∼45 %), and triacylglycerides (TAGs) (∼50 %), with minor amounts of mono-/diacylglycerides and sterol esters. TAG compositions were profiled by matrix-assisted laser desorption-ionization time-of-flight mass spectrometry (MALDI-TOF). Total fatty acid methyl esters (FAMEs) and acyl lipid unsaturation levels were determined by gas chromatography-mass spectrometry (GC-MS). Pseudogymnoascus destructans produced higher proportions of unsaturated 18C fatty acids and TAGs than G. pannorum. Pseudogymnoascus destructans and G. pannorum produced up to a two-fold increase in 18:3 fatty acids at 5 °C than at higher temperatures. TAG proportion for P. destructans at upper and lower temperature growth limits was greater than 50 % of total dried mycelia mass. These results indicate fungal spp. alter acyl lipid unsaturation as a strategy to adapt to cold temperatures. Differences between their glycerolipid profiles also provide evidence for a different metabolic strategy to support psychrophilic growth, which may influence P. destructans' pathogenicity to bats. PMID:25209638

  18. Thermal conductivity of water-saturated rocks from the KTB pilot hole at temperatures of 25 to 300°C

    USGS Publications Warehouse

    Pribnow, D.; Williams, C.F.; Sass, J.H.; Keating, R.

    1996-01-01

    The conductivitites of selected gneiss (two) and amphibolite (one) core samples have been measured under conditions of elevated temperature and pressure with a needle-probe. Water-saturated thermal conductivity measurements spanning temperatures from 25 to 300??C and hydrostatic pressures of 0.1 and 34 MPa confirm the general decrease in conductivity with increasing temperature but deviate significantly from results reported from measurements on dry samples over the same temperature range. The thermal conductivity of water-saturated amphibolite decreases with temperature at a rate approximately 40% less than the rate for dry amphibolite, and the conductivity of water-saturated gneiss decreases at a rate approximately 20% less than the rate for dry gneiss. The available evidence points to thermal cracking as the primary cause of the more rapid decrease in dry thermal conductivity with temperature. The effects of thermal cracking were also observed in the water-saturated samples but resulted in a net decrease in room-temperature conductivity of less than 3%. These results highlight the importance of duplicating in-situ conditions when determining thermal conductivity for the deep crust.

  19. Stoichiometry and temperature sensitivity of methanogenesis and CO 2 production from saturated polygonal tundra in Barrow, Alaska

    SciTech Connect

    Roy Chowdhury, Taniya; Herndon, Elizabeth M.; Phelps, Tommy J.; Elias, Dwayne A.; Gu, Baohua; Liang, Liyuan; Wullschleger, Stan D.; Graham, David E.

    2014-11-26

    Arctic permafrost ecosystems store ~50% of global belowground carbon (C) that is vulnerable to increased microbial degradation with warmer active layer temperatures and thawing of the near surface permafrost. We used anoxic laboratory incubations to estimate anaerobic CO2 production and methanogenesis in active layer (organic and mineral soil horizons) and permafrost samples from center, ridge and trough positions of water-saturated low-centered polygon in Barrow Environmental Observatory, Barrow AK, USA. Methane (CH4) and CO2 production rates and concentrations were determined at 2, +4, or +8 C for 60 day incubation period. Temporal dynamics of CO2 production and methanogenesis at 2 C showed evidence of fundamentally different mechanisms of substrate limitation and inhibited microbial growth at soil water freezing points compared to warmer temperatures. Nonlinear regression better modeled the initial rates and estimates of Q10 values for CO2 that showed higher sensitivity in the organic-rich soils of polygon center and trough than the relatively drier ridge soils. Methanogenesis generally exhibited a lag phase in the mineral soils that was significantly longer at 2 C in all horizons. Such discontinuity in CH4 production between 2 C and the elevated temperatures (+4 and +8 C) indicated the insufficient representation of methanogenesis on the basis of Q10 values estimated from both linear and nonlinear models. Production rates for both CH4 and CO2 were substantially higher in organic horizons (20% to 40% wt. C) at all temperatures relative to mineral horizons (<20% wt. C). Permafrost horizon (~12% wt. C) produced ~5-fold less CO2 than the active layer and negligible CH4. High concentrations of initial exchangeable Fe(II) and increasing accumulation rates signified the role of iron as terminal electron acceptors for anaerobic C degradation in the mineral horizons.

  20. Stoichiometry and temperature sensitivity of methanogenesis and CO 2 production from saturated polygonal tundra in Barrow, Alaska

    DOE PAGES

    Roy Chowdhury, Taniya; Herndon, Elizabeth M.; Phelps, Tommy J.; Elias, Dwayne A.; Gu, Baohua; Liang, Liyuan; Wullschleger, Stan D.; Graham, David E.

    2014-11-26

    Arctic permafrost ecosystems store ~50% of global belowground carbon (C) that is vulnerable to increased microbial degradation with warmer active layer temperatures and thawing of the near surface permafrost. We used anoxic laboratory incubations to estimate anaerobic CO2 production and methanogenesis in active layer (organic and mineral soil horizons) and permafrost samples from center, ridge and trough positions of water-saturated low-centered polygon in Barrow Environmental Observatory, Barrow AK, USA. Methane (CH4) and CO2 production rates and concentrations were determined at 2, +4, or +8 C for 60 day incubation period. Temporal dynamics of CO2 production and methanogenesis at 2 Cmore » showed evidence of fundamentally different mechanisms of substrate limitation and inhibited microbial growth at soil water freezing points compared to warmer temperatures. Nonlinear regression better modeled the initial rates and estimates of Q10 values for CO2 that showed higher sensitivity in the organic-rich soils of polygon center and trough than the relatively drier ridge soils. Methanogenesis generally exhibited a lag phase in the mineral soils that was significantly longer at 2 C in all horizons. Such discontinuity in CH4 production between 2 C and the elevated temperatures (+4 and +8 C) indicated the insufficient representation of methanogenesis on the basis of Q10 values estimated from both linear and nonlinear models. Production rates for both CH4 and CO2 were substantially higher in organic horizons (20% to 40% wt. C) at all temperatures relative to mineral horizons (<20% wt. C). Permafrost horizon (~12% wt. C) produced ~5-fold less CO2 than the active layer and negligible CH4. High concentrations of initial exchangeable Fe(II) and increasing accumulation rates signified the role of iron as terminal electron acceptors for anaerobic C degradation in the mineral horizons.« less

  1. Stoichiometry and temperature sensitivity of methanogenesis and CO2 production from saturated polygonal tundra in Barrow, Alaska.

    PubMed

    Roy Chowdhury, Taniya; Herndon, Elizabeth M; Phelps, Tommy J; Elias, Dwayne A; Gu, Baohua; Liang, Liyuan; Wullschleger, Stan D; Graham, David E

    2015-02-01

    Arctic permafrost ecosystems store ~50% of global belowground carbon (C) that is vulnerable to increased microbial degradation with warmer active layer temperatures and thawing of the near surface permafrost. We used anoxic laboratory incubations to estimate anaerobic CO2 production and methanogenesis in active layer (organic and mineral soil horizons) and permafrost samples from center, ridge and trough positions of water-saturated low-centered polygon in Barrow Environmental Observatory, Barrow AK, USA. Methane (CH4 ) and CO2 production rates and concentrations were determined at -2, +4, or +8 °C for 60 day incubation period. Temporal dynamics of CO2 production and methanogenesis at -2 °C showed evidence of fundamentally different mechanisms of substrate limitation and inhibited microbial growth at soil water freezing points compared to warmer temperatures. Nonlinear regression better modeled the initial rates and estimates of Q10 values for CO2 that showed higher sensitivity in the organic-rich soils of polygon center and trough than the relatively drier ridge soils. Methanogenesis generally exhibited a lag phase in the mineral soils that was significantly longer at -2 °C in all horizons. Such discontinuity in CH4 production between -2 °C and the elevated temperatures (+4 and +8 °C) indicated the insufficient representation of methanogenesis on the basis of Q10 values estimated from both linear and nonlinear models. Production rates for both CH4 and CO2 were substantially higher in organic horizons (20% to 40% wt. C) at all temperatures relative to mineral horizons (<20% wt. C). Permafrost horizon (~12% wt. C) produced ~5-fold less CO2 than the active layer and negligible CH4 . High concentrations of initial exchangeable Fe(II) and increasing accumulation rates signified the role of iron as terminal electron acceptors for anaerobic C degradation in the mineral horizons.

  2. Application of the methane saturated dispersion resonance near 2.36 μm over the temperature range of 77-300 K for optical frequency standards

    NASA Astrophysics Data System (ADS)

    Tarabrin, Mikhail K.; Lazarev, Vladimir A.; Karasik, Valeriy E.; Kireev, Alexey N.; Korostelin, Yuri V.; Shelkovnikov, Alexander S.; Tuyrikov, Dmitry A.; Kozlovsky, Vladimir I.; Podmar'kov, Yuri P.; Frolov, Mikhail P.; Gubin, Mikhail A.

    2016-07-01

    New spectroscopic knowledge of the ν1 +ν4 R(2) E line of methane over the temperature range 77-300 K is reported. Theoretical calculations of the absorption coefficient and the amplitudes of saturated dispersion resonances at 4234 cm-1 were derived. The theoretical dependence on the temperature of the amplitudes of the saturated dispersion resonances was obtained. A novel setup based on a Cr2+ : ZnSe laser was used for Doppler-free spectroscopy of methane. The amplitudes of the saturated dispersion resonances of the ν1 +ν4 R(2) E line of methane were measured experimentally at different temperatures. A comparison with theoretical dependence supports the reliability of the experiment. The obtained results are of immediate interest in applications demanding laser frequency stabilization.

  3. Reaction of Water-Saturated Supercritical CO2 with Forsterite: Evidence for Magnesite Formation at Low Temperatures

    SciTech Connect

    Felmy, Andrew R.; Qafoku, Odeta; Arey, Bruce W.; Hu, Jian Z.; Hu, Mary Y.; Schaef, Herbert T.; Ilton, Eugene S.; Hess, Nancy J.; Pearce, Carolyn I.; Feng, Ju; Rosso, Kevin M.

    2012-08-01

    The nature of the reaction products that form on the surfaces of nanometer-sized forsterite particles during reaction with H2O saturated supercritical CO2 (scCO2) at 35 C and 50 C were examined under in situ conditions and ex situ following reaction. The in situ analysis was conducted by X-ray diffraction (XRD). Ex situ analysis consisted of scanning electron microscopy (SEM) examination of the surface phases and chemical characterization of precipitates using a combination of confocal Raman spectroscopy, 13C and 29Si NMR spectroscopy, and energy-dispersive X-ray Spectroscopy (EDS). The results show that the forsterite surface is highly reactive with the primary reaction products being a mixture of nesquehonite (MgCO3.3H2O) and magnesite (MgCO3) at short reaction times ({approx}3-4 days) and then magnesite (MgCO3) and a highly porous amorphous silica phase at longer reaction times (14 days). After 14 days of reaction most of the original forsterite transformed to reaction products. Importantly, the formation of magnesite was observed at temperatures much lower (35 C) than previously thought needed to overcome its well known sluggish precipitation kinetics. The conversion of nesquehonite to magnesite liberates H2O which can potentially facilitate further metal carbonation, as postulated by previous investigators, based upon studies at higher temperature (80 C). The observation that magnesite can form at lower temperatures implies that water recycling may also be important in determining the rate and extent of mineral carbonation in a wide range of potential CO2 storage reservoirs.

  4. Adiabatic Halo Formation

    SciTech Connect

    Bazzani, A.; Turchetti, G.; Benedetti, C.; Rambaldi, S.; Servizi, G.

    2005-06-08

    In a high intensity circular accelerator the synchrotron dynamics introduces a slow modulation in the betatronic tune due to the space-charge tune depression. When the transverse motion is non-linear due to the presence of multipolar effects, resonance islands move in the phase space and change their amplitude. This effect introduces the trapping and detrapping phenomenon and a slow diffusion in the phase space. We apply the neo-adiabatic theory to describe this diffusion mechanism that can contribute to halo formation.

  5. Monitoring cerebral oxygen saturation during cardiopulmonary bypass using near-infrared spectroscopy: the relationships with body temperature and perfusion rate

    NASA Astrophysics Data System (ADS)

    Teng, Yichao; Ding, HaiShu; Gong, Qingcheng; Jia, Zaishen; Huang, Lan

    2006-03-01

    During cardiopulmonary bypass (CPB) because of weak arterial pulsation, near-IR spectroscopy (NIRS) is almost the only available method to monitor cerebral oxygenation noninvasively. Our group develops a NIRS oximeter to monitor regional cerebral oxygenation especially its oxygen saturation (rScO2). To achieve optimal coupling between the sensor and human brain, the distances between the light source and the detectors on it are properly chosen. The oximeter is calibrated by blood gas analysis, and the results indicate that its algorithm is little influenced by either background absorption or overlying tissue. We used it to measure the rScO2 of 15 patients during CPB. It is shown that rScO2 is negatively correlated with body temperature and positively with perfusion rate. There are two critical stages during CPB when rScO2 might be relatively low: one is the low-perfusion-rate stage, the other is the early rewarming stage. During cooling, the changes of total hemoglobin concentration (CtHb) compared with its original value is also monitored. It is shown that CtHb decreases to a small extent, which may mainly reflect cerebral vasoconstriction induced by cooling. All these results indicate that NIRS can be used to monitor cerebral oxygenation to protect cerebral tissue during CPB.

  6. Dependence of expansion of a salt-saturated concrete on temperature and mixing and handling procedures. Final report

    SciTech Connect

    Wakeley, L.D.

    1987-07-01

    In experiments with an expansive salt-saturated concrete (ESC), time of setting was controlled by amount of sodium citrate used. The rheological and physical properties required of ESC were determined by its intended use, in an underground repository for radioactive wastes in bedded rock salt. These properties, including a long working time and low air content, could not be achieved using conventional high-range water-reducing admixtures, such as melamine or naphthalene formaldehyde condensates. Within a fixed range of citrate percentages, expansivity of the concrete was proportional to the amount of citrate used. The desired level of expansion resulted from delaying formation of ettringite until after formation of a rigid structure in the paste. Expansive potential was diminished by warmer temperatures of mixing curing, and by repeated episodes of mixing or disturbance during the extended period of workability (up to 4 hr). These variables should be considered in plans for field placement of this or any expansive concrete. The potential for durability of this concrete in the environment for which it was formulated cannot be gauged by those properties commonly used as indicators of durability for conventional concrete in surface environments. Low permeability and minimal reaction to brine are interrelated factors which may better indicate durability than do traditionally cited properties such as compressive strength or resistance to cyclic phenomena.

  7. Dietary lipid saturation influences environmental temperature preference but not resting metabolic rate in the Djungarian Hamster (Phodopus sungorus).

    PubMed

    Pannorfi, Ryan; Zee, Barry M; Vatnick, Itzick; Berner, Nancy; Hiebert, Sara M

    2012-01-01

    Heterothermic rodents increase self-selection of diets rich in polyunsaturated fatty acids (PUFAs) when exposed to cold, short days, or short-day melatonin profiles, and Djungarian hamsters (Phodopus sungorus) do so in long days in response to cold exposure alone. To determine whether Djungarian hamsters are also capable of selecting a thermal environment in response to dietary lipid composition, continuously normothermic hamsters were fed either a PUFA-rich diet or a diet rich in saturated fatty acids (SFAs) for 6-10 wk and given a choice of thermal environments. As predicted, SFA-fed hamsters were more likely than PUFA-fed hamsters to occupy the single heated corner of their cage ([Formula: see text]) and were most likely to show this diet-related difference in behavior when T(a) fell within the thermal neutral zone. Respirometry revealed no effect of diet on whole-animal or mass-specific resting metabolic rate or on lower critical temperature. The results are more consistent with the homeoviscous adaptation hypothesis, which predicts that organisms should make physiological and/or behavioral adjustments that preserve membrane fluidity within a relatively small range, than with the membrane pacemaker hypothesis, which predicts that high PUFA content in membrane phospholipids should increase basal metabolic rate.

  8. Geometry of the Adiabatic Theorem

    ERIC Educational Resources Information Center

    Lobo, Augusto Cesar; Ribeiro, Rafael Antunes; Ribeiro, Clyffe de Assis; Dieguez, Pedro Ruas

    2012-01-01

    We present a simple and pedagogical derivation of the quantum adiabatic theorem for two-level systems (a single qubit) based on geometrical structures of quantum mechanics developed by Anandan and Aharonov, among others. We have chosen to use only the minimum geometric structure needed for the understanding of the adiabatic theorem for this case.…

  9. Adiabatic charging of nickel-hydrogen batteries

    NASA Astrophysics Data System (ADS)

    Lurie, Chuck; Foroozan, S.; Brewer, Jeff; Jackson, Lorna

    1995-02-01

    Battery management during prelaunch activities has always required special attention and careful planning. The transition from nickel-cadium to nickel-hydrogen batteries, with their high self discharge rate and lower charge efficiency, as well as longer prelaunch scenarios, has made this aspect of spacecraft battery management even more challenging. The AXAF-I Program requires high battery state of charge at launch. The use of active cooling, to ensure efficient charging, was considered and proved to be difficult and expensive. Alternative approaches were evaluated. Optimized charging, in the absence of cooling, appeared promising and was investigated. Initial testing was conducted to demonstrate the feasibility of the 'Adiabatic Charging' approach. Feasibility was demonstrated and additional testing performed to provide a quantitative, parametric data base. The assumption that the battery is in an adiabatic environment during prelaunch charging is a conservative approximation because the battery will transfer some heat to its surroundings by convective air cooling. The amount is small compared to the heat dissipated during battery overcharge. Because the battery has a large thermal mass, substantial overcharge can occur before the cells get too hot to charge efficiently. The testing presented here simulates a true adiabatic environment. Accordingly the data base may be slightly conservative. The adiabatic charge methodology used in this investigation begins with stabilizing the cell at a given starting temperature. The cell is then fully insulated on all sides. Battery temperature is carefully monitored and the charge terminated when the cell temperature reaches 85 F. Charging has been evaluated with starting temperatures from 55 to 75 F.

  10. Advanced Adiabatic Demagnetization Refrigerators for Continuous Cooling

    NASA Technical Reports Server (NTRS)

    Chu, Paul C. W.

    2004-01-01

    The research at Houston was focused on optimizing the design of superconducting magnets for advanced adiabatic demagnetization refrigerators (ADRs), assessing the feasibility of using high temperature superconducting (HTS) magnets in ADRs in the future, and developing techniques to deposit HTS thin and thick films on high strength, low thermal conductivity substrates for HTS magnet leads. Several approaches have been tested for the suggested superconducting magnets.

  11. Colloid-associated plutonium aged at room temperature: evaluating its transport velocity in saturated coarse-grained granites.

    PubMed

    Xie, Jinchuan; Lin, Jianfeng; Wang, Yu; Li, Mei; Zhang, Jihong; Zhou, Xiaohua; He, Yifeng

    2015-01-01

    The fate and transport of colloidal contaminants in natural media are complicated by physicochemical properties of the contaminants and heterogeneous characteristics of the media. Size and charge exclusion are two key microscopic mechanisms dominating macroscopic transport velocities. Faster velocities of colloid-associated actinides than that of (3)H2O were consistently indicated in many studies. However, dissociation/dissolution of these sorbed actinides (e.g., Pu and Np), caused by their redox reactions on mineral surfaces, possibly occurred under certain chemical conditions. How this dissolution is related to transport velocities remains unanswered. In this study, aging of the colloid-associated Pu (pseudo-colloid) at room temperature and transport through the saturated coarse-grained granites were performed to study whether Pu could exhibit slower velocity than that of (3)H2O (UPu/UT <1). The results show that oxidative dissolution of Pu(IV) associated with the surfaces of colloidal granite particles took place during the aging period. The relative velocity of UPu/UT declined from 1.06 (unaged) to 0.745 (135 d) over time. Size exclusion limited to the uncharged nano-sized particles could not explain such observed UPu/UT <1. Therefore, the decline in UPu/UT was ascribed to the presence of electrostatic attraction between the negatively charged wall of granite pore channels and the Pu(V)O2(+), as evidenced by increasing Pu(V)O2(+) concentrations in the suspensions aged in sealed vessels. As a result of this attraction, Pu(V)O2(+) was excluded from the domain closer to the centerline of pore channels. This reveals that charge exclusion played a more important role in dominating UPu than the size exclusion under the specific conditions, where oxidative dissolution of colloid-associated Pu(IV) was observed in the aged suspensions. PMID:25462640

  12. Colloid-associated plutonium aged at room temperature: evaluating its transport velocity in saturated coarse-grained granites.

    PubMed

    Xie, Jinchuan; Lin, Jianfeng; Wang, Yu; Li, Mei; Zhang, Jihong; Zhou, Xiaohua; He, Yifeng

    2015-01-01

    The fate and transport of colloidal contaminants in natural media are complicated by physicochemical properties of the contaminants and heterogeneous characteristics of the media. Size and charge exclusion are two key microscopic mechanisms dominating macroscopic transport velocities. Faster velocities of colloid-associated actinides than that of (3)H2O were consistently indicated in many studies. However, dissociation/dissolution of these sorbed actinides (e.g., Pu and Np), caused by their redox reactions on mineral surfaces, possibly occurred under certain chemical conditions. How this dissolution is related to transport velocities remains unanswered. In this study, aging of the colloid-associated Pu (pseudo-colloid) at room temperature and transport through the saturated coarse-grained granites were performed to study whether Pu could exhibit slower velocity than that of (3)H2O (UPu/UT <1). The results show that oxidative dissolution of Pu(IV) associated with the surfaces of colloidal granite particles took place during the aging period. The relative velocity of UPu/UT declined from 1.06 (unaged) to 0.745 (135 d) over time. Size exclusion limited to the uncharged nano-sized particles could not explain such observed UPu/UT <1. Therefore, the decline in UPu/UT was ascribed to the presence of electrostatic attraction between the negatively charged wall of granite pore channels and the Pu(V)O2(+), as evidenced by increasing Pu(V)O2(+) concentrations in the suspensions aged in sealed vessels. As a result of this attraction, Pu(V)O2(+) was excluded from the domain closer to the centerline of pore channels. This reveals that charge exclusion played a more important role in dominating UPu than the size exclusion under the specific conditions, where oxidative dissolution of colloid-associated Pu(IV) was observed in the aged suspensions.

  13. Changes during leaf expansion of ΦPSII temperature optima in Gossypium hirsutum are associated with the degree of fatty acid lipid saturation.

    PubMed

    Hall, Trent D; Chastain, Daryl R; Horn, Patrick J; Chapman, Kent D; Choinski, John S

    2014-03-15

    In this project, we hypothesize that cotton (Gossypium hirsutum) leaf temperature and the responses of leaf photosynthesis to temperature will change as the leaves expand and that differences between young and mature leaves will be associated with the proportion of saturated fatty acids in thylakoid and other membrane lipids. To that end, we studied main stem leaves obtained from plants growing in a temperature controlled greenhouse and at different times in the field season. We found that young leaves (∼5d old) had higher mid day temperatures, lower stomatal conductance and higher thermal optima as measured by ΦPSII temperature curves than did more mature leaves (∼13d old). Young leaves also had significant differences in fatty acid saturation with the warmer, young leaves having a higher proportion of palmitic acid (16:0) and lower linoleic acid (18:3) in total lipid extracts and higher 16:0 and lower palmitoleic acid (16:1) in the chloroplast membrane phosphoglycerides, digalactosyldiacylglycerol (in the greenhouse) and phosphatidylglycerol when compared with cooler, more mature leaves. Later in the growing season, leaf temperature, stomatal conductance and ΦPSII temperature curves for young and more mature leaves were similar and the proportion of 16:0 fatty acids decreased and 16:1 increased in phosphatidylglycerol. We conclude that changes in temperature as cotton leaves expand leads to alterations in the fatty acid composition of thylakoid and other membranes and, consequently, influence photosynthesis/temperature responses.

  14. Changes during leaf expansion of ΦPSII temperature optima in Gossypium hirsutum are associated with the degree of fatty acid lipid saturation.

    PubMed

    Hall, Trent D; Chastain, Daryl R; Horn, Patrick J; Chapman, Kent D; Choinski, John S

    2014-03-15

    In this project, we hypothesize that cotton (Gossypium hirsutum) leaf temperature and the responses of leaf photosynthesis to temperature will change as the leaves expand and that differences between young and mature leaves will be associated with the proportion of saturated fatty acids in thylakoid and other membrane lipids. To that end, we studied main stem leaves obtained from plants growing in a temperature controlled greenhouse and at different times in the field season. We found that young leaves (∼5d old) had higher mid day temperatures, lower stomatal conductance and higher thermal optima as measured by ΦPSII temperature curves than did more mature leaves (∼13d old). Young leaves also had significant differences in fatty acid saturation with the warmer, young leaves having a higher proportion of palmitic acid (16:0) and lower linoleic acid (18:3) in total lipid extracts and higher 16:0 and lower palmitoleic acid (16:1) in the chloroplast membrane phosphoglycerides, digalactosyldiacylglycerol (in the greenhouse) and phosphatidylglycerol when compared with cooler, more mature leaves. Later in the growing season, leaf temperature, stomatal conductance and ΦPSII temperature curves for young and more mature leaves were similar and the proportion of 16:0 fatty acids decreased and 16:1 increased in phosphatidylglycerol. We conclude that changes in temperature as cotton leaves expand leads to alterations in the fatty acid composition of thylakoid and other membranes and, consequently, influence photosynthesis/temperature responses. PMID:24594393

  15. The signal in total-body plethysmography: errors due to adiabatic-isothermic difference.

    PubMed

    Chaui-Berlinck, J G; Bicudo, J E

    1998-09-01

    Total-body plethysmography is a technique often employed in comparative physiology studies because it avoids excessive handling of the animals. The pressure signal obtained is generated by an increase in internal energy of the gas phase of the system. Currently, this increase in internal energy is ascribed to heating (and water vapour saturation) of the inspired gas. The standard equation for computing tidal-volume implies that only temperature and saturation differences can be responsible for generating the ventilation signal. In this study, we were able to demonstrate that the difference between the external process of the thoracic expansion, which is adiabatic, and the internal process of it, which is isothermic, is an important factor of internal energy change in the total-body plethysmography method. In other words, organic tissues transfer heat to the entering gas but also to the present gas, in a way that keeps internal expansion an isothermic process. This extra amount of energy was never taken into account before. Therefore, experiments using such a technique to measure tidal-volume should be done using isothermic chambers. Moreover, due to uncertainties of the complementary measurements (ambient and lung temperatures, ambient water vapour saturation) needed to compute tidal-volume using total-body plethysmography, a minimal temperature difference about 15 degrees C between body and ambient should exist to keep uncertainties in tidal-volume values below 5%. However, this limit is not absolute, because it varies as a function of humidity and degree of uncertainty of the complementary measurements.

  16. Development of a quasi-adiabatic calorimeter for the determination of the water vapor pressure curve

    NASA Astrophysics Data System (ADS)

    Mokdad, S.; Georgin, E.; Hermier, Y.; Sparasci, F.; Himbert, M.

    2012-07-01

    Progress in the knowledge of the water saturation curve is required to improve the accuracy of the calibrations in humidity. In order to achieve this objective, the LNE-CETIAT and the LNE-CNAM have jointly built a facility dedicated to the measurement of the saturation vapor pressure and temperature of pure water. The principle is based on a static measurement of the pressure and the temperature of pure water in a closed, temperature-controlled thermostat, conceived like a quasi-adiabatic calorimeter. A copper cell containing pure water is placed inside a temperature-controlled copper shield, which is mounted in a vacuum-tight stainless steel vessel immersed in a thermostated bath. The temperature of the cell is measured with capsule-type standard platinum resistance thermometers, calibrated with uncertainties below the millikelvin. The vapor pressure is measured by calibrated pressure sensors connected to the cell through a pressure tube whose temperature is monitored at several points. The pressure gauges are installed in a thermostatic apparatus ensuring high stability of the pressure measurement and avoiding any condensation in the tubes. Thanks to the employment of several technical solutions, the thermal contribution to the overall uncertainty budget is reduced, and the remaining major part is mainly due to pressure measurements. This paper presents a full description of this facility and the preliminary results obtained for its characterization.

  17. Development of a quasi-adiabatic calorimeter for the determination of the water vapor pressure curve.

    PubMed

    Mokdad, S; Georgin, E; Hermier, Y; Sparasci, F; Himbert, M

    2012-07-01

    Progress in the knowledge of the water saturation curve is required to improve the accuracy of the calibrations in humidity. In order to achieve this objective, the LNE-CETIAT and the LNE-CNAM have jointly built a facility dedicated to the measurement of the saturation vapor pressure and temperature of pure water. The principle is based on a static measurement of the pressure and the temperature of pure water in a closed, temperature-controlled thermostat, conceived like a quasi-adiabatic calorimeter. A copper cell containing pure water is placed inside a temperature-controlled copper shield, which is mounted in a vacuum-tight stainless steel vessel immersed in a thermostated bath. The temperature of the cell is measured with capsule-type standard platinum resistance thermometers, calibrated with uncertainties below the millikelvin. The vapor pressure is measured by calibrated pressure sensors connected to the cell through a pressure tube whose temperature is monitored at several points. The pressure gauges are installed in a thermostatic apparatus ensuring high stability of the pressure measurement and avoiding any condensation in the tubes. Thanks to the employment of several technical solutions, the thermal contribution to the overall uncertainty budget is reduced, and the remaining major part is mainly due to pressure measurements. This paper presents a full description of this facility and the preliminary results obtained for its characterization.

  18. Saturation meter

    DOEpatents

    Gregurech, S.

    1984-08-01

    A saturation meter for use in a pressurized water reactor plant comprising a differential pressure transducer having a first and second pressure sensing means and an alarm. The alarm is connected to the transducer and is preset to activate at a level of saturation prior to the formation of a steam void in the reactor vessel.

  19. Effects of cooling rate, saturation temperature, and agitation on the metastable zone width of DL-malic acid-water system

    NASA Astrophysics Data System (ADS)

    Yuan, Ye; Leng, Yixin; Huang, Chunxiang; Yue, Mingxuan; Tan, Qian

    2015-09-01

    A study of metastable zone width (MSZW) and nucleation parameters for a cooling crystallization of DL-malic acid-water system is described in this paper. Experimental determination of the MSZW was performed using a laser method in order to carry out the estimation of nucleation parameters. Measured MSZWs can be affected by a variety of parameters, such as cooling rate, saturation temperature, agitation rate, and so on. In this work, the MSZWs were found to decrease with an increase of saturation temperature, and levels of agitation, while it increased with an increase of cooling rate. Two classical theoretical approaches, Nyvlt's approach and self-consistent Nyvlt-like approach were used to analyze the experimental data on MSZWs.

  20. An adiabatic demagnetization refrigerator for infrared bolometers

    NASA Technical Reports Server (NTRS)

    Britt, R. D.; Richards, P. L.

    1981-01-01

    Adiabatic demagnetization refrigerators have been built and installed in small portable liquid helium cryostats to test the feasibility of this method of cooling infrared bolometric detectors to temperatures below 0.3 K. Performance has been achieved which suggests that bolometer temperatures of 0.2 K can be maintained for periods of approximately 60 hours. Applications to sensitive infrared detection from ground-based telescopes and space satellites are discussed. Design data are given which permit the evaluation of refrigerator performance for a variety of design parameters.

  1. Effects of water-saturation on strength and ductility of three igneous rocks at effective pressures to 50 MPA and temperatures to partial melting

    SciTech Connect

    Bauer, S.J.; Friedman, M.; Handin, J.

    1981-01-01

    The short-term failure strengths and strains at failure of room-dry and water-saturated, cylindrical specimens (2 by 4 cm) of Charcoal Granodiorite (CG), Mt. Hood Andesite (MHA), and Cuerbio Basalt (CB) at a strain rate of 10/sup -4/s/sup -1/, at effective confining pressures of 0, 50, and 100 MPa and at temperatures to partial melting were investigated. Data from water-saturated specimens of the granodiorite and andesite, compared to room-dry counterparts, indicate (1) the pore pressures are essentially communicated throughout each test specimen so that they are fully effective; (2) at P/sub e/ = 0 and 50 MPa the granodiorite does not water-weaken; (3) at these same effective pressures the more porous and finer-grained andesite begins to exhibit water-weakening at about 600/sup 0/C; (4) at P/sub e/ = 0 and 870 to 900/sup 0/C the andesite's strength averages 20 MPa while the strength of dry specimens at the same P and T exhibit a strength of 100 MPa; (5) at P/sub e/ = 50 MPa compared to 160 MPa dry; (6) the basalt at P/sub e/ = 0, appears to be water-weakened at 800/sup 0/C; (7) water saturated specimens deformed at temperatures less than that of melting exhibit ultimate strengths at less than 2% shortening and then work-soften along faults; (8) again as do the dry counterparts, the wet specimens deform primarily by microscopic fracturing that coalesces into one or more macroscopic faults; and (9) the temperature for incipient melting of the andesite is decreased >150/sup 0/C in the water-saturated tests.

  2. Solitary shock waves and adiabatic phase transition in lipid interfaces and nerves

    NASA Astrophysics Data System (ADS)

    Shrivastava, Shamit; Kang, Kevin Heeyong; Schneider, Matthias F.

    2015-01-01

    This study shows that the stability of solitary waves excited in a lipid monolayer near a phase transition requires positive curvature of the adiabats, a known necessary condition in shock compression science. It is further shown that the condition results in a threshold for excitation, saturation of the wave's amplitude, and the splitting of the wave at the phase boundaries. Splitting in particular confirms that a hydrated lipid interface can undergo condensation on adiabatic heating, thus showing retrograde behavior. Finally, using the theoretical insights and state dependence of conduction velocity in nerves, the curvature of the adiabatic state diagram is shown to be closely tied to the thermodynamic blockage of nerve pulse propagation.

  3. Solitary shock waves and adiabatic phase transition in lipid interfaces and nerves.

    PubMed

    Shrivastava, Shamit; Kang, Kevin Heeyong; Schneider, Matthias F

    2015-01-01

    This study shows that the stability of solitary waves excited in a lipid monolayer near a phase transition requires positive curvature of the adiabats, a known necessary condition in shock compression science. It is further shown that the condition results in a threshold for excitation, saturation of the wave's amplitude, and the splitting of the wave at the phase boundaries. Splitting in particular confirms that a hydrated lipid interface can undergo condensation on adiabatic heating, thus showing retrograde behavior. Finally, using the theoretical insights and state dependence of conduction velocity in nerves, the curvature of the adiabatic state diagram is shown to be closely tied to the thermodynamic blockage of nerve pulse propagation.

  4. Adiabatic demagnetization of a pyrochlore antiferromagnet Gd 2Ti 2O 7

    NASA Astrophysics Data System (ADS)

    Sosin, S. S.; Prozorova, L. A.; Smirnov, A. I.; Golov, A. I.; Berkutov, I. B.; Petrenko, O. A.; Balakrishnan, G.; Zhitomirsky, M. E.

    2005-04-01

    An adiabatic demagnetization process is studied in the pyrochlore antiferromagnet Gd2Ti2O7. A strong cooling of the sample is observed by decreasing magnetic field in the range 120-60 kOe corresponding to a crossover between saturated and spin-liquid phases. This phenomenon indicates that a considerable part of the magnetic entropy associated with a macroscopic number of local soft modes survives in the strongly correlated paramagnetic state. Monte Carlo simulations demonstrate good agreement with the experiment. The cooling power of the process is experimentally estimated with a view to possible technical applications. The results on Gd2Ti2O7 are compared to those for Gd3Ga5O12, a related material for low-temperature magnetic cooling.

  5. Large magnetic entropy change and adiabatic temperature rise of a Gd{sub 55}Al{sub 20}Co{sub 20}Ni{sub 5} bulk metallic glass

    SciTech Connect

    Xia, L.; Tang, M. B.; Chan, K. C.; Dong, Y. D.

    2014-06-14

    Gd{sub 55}Al{sub 20}Co{sub 20}Ni{sub 5} bulk metallic glass (BMG) was synthesized by minor Ni substitution for Co in the Gd{sub 55}Al{sub 20}Co{sub 25} BMG in which excellent glass forming ability (GFA) and magneto-caloric effect were reported previously. The Gd{sub 55}Al{sub 20}Ni{sub 20}Co{sub 5} amorphous rod has a similar GFA to the Gd{sub 55}Al{sub 20}Co{sub 25} BMG but exhibits better magnetic properties. The peak value of magnetic entropy change (−ΔS{sub m}{sup peak}) of the Gd{sub 55}Al{sub 20}Co{sub 20}Ni{sub 5} BMG is 9.8 Jkg{sup −1} K{sup −1}. The field dependence of −ΔS{sub m}{sup peak} follows a −ΔS{sub m}{sup peak}∝H{sup 0.85} relationship. The adiabatic temperature rise of the rod is 4.74 K under 5 T and is larger than of other BMGs previously reported. The improved magnetic properties were supposed to be induced by the enhanced interaction between 4f electron in the rare-earth and 3d electron in the transition metal elements by means of a minor Ni substitution for Co.

  6. Adiabatic cooling of solar wind electrons

    NASA Technical Reports Server (NTRS)

    Sandbaek, Ornulf; Leer, Egil

    1992-01-01

    In thermally driven winds emanating from regions in the solar corona with base electron densities of n0 not less than 10 exp 8/cu cm, a substantial fraction of the heat conductive flux from the base is transfered into flow energy by the pressure gradient force. The adiabatic cooling of the electrons causes the electron temperature profile to fall off more rapidly than in heat conduction dominated flows. Alfven waves of solar origin, accelerating the basically thermally driven solar wind, lead to an increased mass flux and enhanced adiabatic cooling. The reduction in electron temperature may be significant also in the subsonic region of the flow and lead to a moderate increase of solar wind mass flux with increasing Alfven wave amplitude. In the solar wind model presented here the Alfven wave energy flux per unit mass is larger than that in models where the temperature in the subsonic flow is not reduced by the wave, and consequently the asymptotic flow speed is higher.

  7. Adiabatic computation: A toy model

    NASA Astrophysics Data System (ADS)

    Ribeiro, Pedro; Mosseri, Rémy

    2006-10-01

    We discuss a toy model for adiabatic quantum computation which displays some phenomenological properties expected in more realistic implementations. This model has two free parameters: the adiabatic evolution parameter s and the α parameter, which emulates many-variable constraints in the classical computational problem. The proposed model presents, in the s-α plane, a line of first-order quantum phase transition that ends at a second-order point. The relation between computation complexity and the occurrence of quantum phase transitions is discussed. We analyze the behavior of the ground and first excited states near the quantum phase transition, the gap, and the entanglement content of the ground state.

  8. Adiabatic computation: A toy model

    SciTech Connect

    Ribeiro, Pedro; Mosseri, Remy

    2006-10-15

    We discuss a toy model for adiabatic quantum computation which displays some phenomenological properties expected in more realistic implementations. This model has two free parameters: the adiabatic evolution parameter s and the {alpha} parameter, which emulates many-variable constraints in the classical computational problem. The proposed model presents, in the s-{alpha} plane, a line of first-order quantum phase transition that ends at a second-order point. The relation between computation complexity and the occurrence of quantum phase transitions is discussed. We analyze the behavior of the ground and first excited states near the quantum phase transition, the gap, and the entanglement content of the ground state.

  9. Adiabatic evolution of plasma equilibrium

    PubMed Central

    Grad, H.; Hu, P. N.; Stevens, D. C.

    1975-01-01

    A new theory of plasma equilibrium is introduced in which adiabatic constraints are specified. This leads to a mathematically nonstandard structure, as compared to the usual equilibrium theory, in which prescription of pressure and current profiles leads to an elliptic partial differential equation. Topologically complex configurations require further generalization of the concept of adiabaticity to allow irreversible mixing of plasma and magnetic flux among islands. Matching conditions across a boundary layer at the separatrix are obtained from appropriate conservation laws. Applications are made to configurations with planned islands (as in Doublet) and accidental islands (as in Tokamaks). Two-dimensional, axially symmetric, helically symmetric, and closed line equilibria are included. PMID:16578729

  10. State of an adiabatic expanding and condensing vapor or slow, medium, and fast explosions into a vacuum

    NASA Astrophysics Data System (ADS)

    Strobel, George L.

    1990-04-01

    A hot dense vapor expanding adiabatically into a vacuum is studied. A condensed phase develops after saturation and supercooling conditions have been achieved. The final state of the system consists of liquid drops in a expanding, cooling vapor. The final condensed mole fraction depends on the drop growth rate compared to the fractional volume rate of expansion at the time saturation is achieved. Drops are produced by a nonequilibrium collision process during supercooling of the vapor. The dependence of the number of drops on various factors is established. The First Law of Thermodynamics is used to solve for the evolution of the system, assuming the volume expansion rate is known. The initial vapor can include an inert gas that does not condense in the temperature range of interest. The vapors are treated as ideal gases until saturation occurs. Slow expansions result in the highest condensed mole fractions. Slow expansions are the result of one-dimensional versus three-dimensional expansions and from saturation occurring at high temperatures and densities. The size per drop depends mostly on how many drops are formed in the nonequilibrium supercooling process.

  11. Control of the saturation temperature in magnetic heating by using polyethylene-glycol-coated rod-shaped nickel-ferrite (NiFe2O4) nanoparticles

    NASA Astrophysics Data System (ADS)

    Iqbal, Yousaf; Bae, Hongsub; Rhee, Ilsu; Hong, Sungwook

    2016-02-01

    Polyethylene-glycol (PEG)-coated nickel-ferrite nanoparticles were prepared for magnetic hyperthermia applications by using the co-precipitation method. The PEG coating occurred during the synthesis of the nanoparticles. The coated nanoparticles were rod-shaped with an average length of 16 nm and an average diameter of 4.5 nm, as observed using transmission electron microscopy. The PEG coating on the surfaces of the nanoparticles was confirmed from the Fourier-transform infrared spectra. The nanoparticles exhibited superparamagnetic characteristics with negligible coercive force. Further, magnetic heating effects were observed in aqueous solutions of the coated nanoparticles. The saturation temperature could be controlled at 42 ℃ by changing the concentration of the nanoparticles in the aqueous solution. Alternately, the saturation temperature could be controlled for a given concentration of nanoparticles by changing the intensity of the magnetic field. The Curie temperature of the nanoparticles was estimated to be 495 ℃. These results for the PEG-coated nickel-ferrite nanoparticles showed the possibility of utilizing them for controlled magnetic hyperthermia at 42 ℃.

  12. Effects of water-saturation on strength and ductility of three igneous rocks at effective pressures to 50 MPa and temperatures to partial melting

    SciTech Connect

    Bauer, S.J.; Friedman, M.; Handin, J.

    1981-01-01

    Instantaneous-failure strengths and ductilities of water-saturated cylindrical specimens of Charcoal Granodiorite, Mount Hood Andesite, and Cuerbio Basalt are determined at a strain rate of 10{sup -4}s{sup -1} and at effective confining pressures (Pe) of 0 and 50 MPa and at temperatures to partial melting. The data indicate: (1) at Pe = 0 and 50 MPa (Pc and Pp of 50 MPa and of 100 and 50 MPa, respectively) the granodiorite does not water-weaken; (2) at these same Pe the more porous and finer-grained andesite begins to exhibit water-weakening at about 600/sup 0/C; (3) at Pe = 0 and 870-900{sup 0}C the andesite's wet strength averages 20 MPa compared to 100 MPa, dry; (4) at Pe = 50 MPa and 920{sup 0}C its wet strength is 45 MPa compared to 160 MPa dry; (5) at Pe = 0, the basalt appears to be water-weakened above 800{sup 0}C; (6) water-saturated specimens deformed at temperatures less than T{sub m} exhibit ultimate strengths at less than 2 percent shortening and then work-soften along faults; and (7) both dry and wet specimens deform primarily by brittle fracture. Extrapolations indicate: (1) crystalline rocks should be drillable because they remain brittle until partial melting occurs, and penetration rates should increase with temperature because there is a corresponding decrease in brittle fracture strength; (2) boreholes in ''water-filled'' holes will be stable to >10 km at temperatures temperatures are kept to less than or equal to 700{sup 0}C, even open boreholes in granodiorite are apt to be stable to >10 km; and (4) open boreholes in the andesite are apt to be much less stable, and at similar temperatures would fail at 2 to 5-km depth.

  13. Elementary examples of adiabatic invariance

    NASA Astrophysics Data System (ADS)

    Crawford, Frank S.

    1990-04-01

    Simple classical one-dimensional systems subject to adiabatic (gradual) perturbations are examined. The first examples are well known: the adiabatic invariance of the product Eτ of energy E and period τ for the simple pendulum and for the simple harmonic oscillator. Next, the adiabatic invariants of the vertical bouncer are found—a ball bouncing elastically from the floor of a rising elevator having slowly varying velocity and acceleration. These examples lead to consideration of adiabatic invariance for one-dimensional systems with potentials of the form V=axn, with a=a(t) slowly varying in time. Then, the horizontal bouncer is considered—a mass sliding on a smooth floor, bouncing back and forth between two impenetrable walls, one of which is slowly moving. This example is generalized to a particle in a bound state of a general potential with one slowly moving ``turning point.'' Finally, circular motion of a charged particle in a magnetic field slowly varying in time under three different configurations is considered: (a) a free particle in a uniform field; (b) a free particle in a nonuniform ``betatron'' field; and (c) a particle constrained to a circular orbit in a uniform field.

  14. Pressure Oscillations in Adiabatic Compression

    ERIC Educational Resources Information Center

    Stout, Roland

    2011-01-01

    After finding Moloney and McGarvey's modified adiabatic compression apparatus, I decided to insert this experiment into my physical chemistry laboratory at the last minute, replacing a problematic experiment. With insufficient time to build the apparatus, we placed a bottle between two thick textbooks and compressed it with a third textbook forced…

  15. Transitionless driving on adiabatic search algorithm

    SciTech Connect

    Oh, Sangchul; Kais, Sabre

    2014-12-14

    We study quantum dynamics of the adiabatic search algorithm with the equivalent two-level system. Its adiabatic and non-adiabatic evolution is studied and visualized as trajectories of Bloch vectors on a Bloch sphere. We find the change in the non-adiabatic transition probability from exponential decay for the short running time to inverse-square decay in asymptotic running time. The scaling of the critical running time is expressed in terms of the Lambert W function. We derive the transitionless driving Hamiltonian for the adiabatic search algorithm, which makes a quantum state follow the adiabatic path. We demonstrate that a uniform transitionless driving Hamiltonian, approximate to the exact time-dependent driving Hamiltonian, can alter the non-adiabatic transition probability from the inverse square decay to the inverse fourth power decay with the running time. This may open up a new but simple way of speeding up adiabatic quantum dynamics.

  16. Studies in Chaotic adiabatic dynamics

    SciTech Connect

    Jarzynski, C.

    1994-01-01

    Chaotic adiabatic dynamics refers to the study of systems exhibiting chaotic evolution under slowly time-dependent equations of motion. In this dissertation the author restricts his attention to Hamiltonian chaotic adiabatic systems. The results presented are organized around a central theme, namely, that the energies of such systems evolve diffusively. He begins with a general analysis, in which he motivates and derives a Fokker-Planck equation governing this process of energy diffusion. He applies this equation to study the {open_quotes}goodness{close_quotes} of an adiabatic invariant associated with chaotic motion. This formalism is then applied to two specific examples. The first is that of a gas of noninteracting point particles inside a hard container that deforms slowly with time. Both the two- and three-dimensional cases are considered. The results are discussed in the context of the Wall Formula for one-body dissipation in nuclear physics, and it is shown that such a gas approaches, asymptotically with time, an exponential velocity distribution. The second example involves the Fermi mechanism for the acceleration of cosmic rays. Explicit evolution equations are obtained for the distribution of cosmic ray energies within this model, and the steady-state energy distribution that arises when this equation is modified to account for the injection and removal of cosmic rays is discussed. Finally, the author re-examines the multiple-time-scale approach as applied to the study of phase space evolution under a chaotic adiabatic Hamiltonian. This leads to a more rigorous derivation of the above-mentioned Fokker-Planck equation, and also to a new term which has relevance to the problem of chaotic adiabatic reaction forces (the forces acting on slow, heavy degrees of freedom due to their coupling to light, fast chaotic degrees).

  17. A Semi-Analytical Method for Rapid Estimation of Near-Well Saturation, Temperature, Pressure and Stress in Non-Isothermal CO2 Injection

    NASA Astrophysics Data System (ADS)

    LaForce, T.; Ennis-King, J.; Paterson, L.

    2015-12-01

    Reservoir cooling near the wellbore is expected when fluids are injected into a reservoir or aquifer in CO2 storage, enhanced oil or gas recovery, enhanced geothermal systems, and water injection for disposal. Ignoring thermal effects near the well can lead to under-prediction of changes in reservoir pressure and stress due to competition between increased pressure and contraction of the rock in the cooled near-well region. In this work a previously developed semi-analytical model for immiscible, nonisothermal fluid injection is generalised to include partitioning of components between two phases. Advection-dominated radial flow is assumed so that the coupled two-phase flow and thermal conservation laws can be solved analytically. The temperature and saturation profiles are used to find the increase in reservoir pressure, tangential, and radial stress near the wellbore in a semi-analytical, forward-coupled model. Saturation, temperature, pressure, and stress profiles are found for parameters representative of several CO2 storage demonstration projects around the world. General results on maximum injection rates vs depth for common reservoir parameters are also presented. Prior to drilling an injection well there is often little information about the properties that will determine the injection rate that can be achieved without exceeding fracture pressure, yet injection rate and pressure are key parameters in well design and placement decisions. Analytical solutions to simplified models such as these can quickly provide order of magnitude estimates for flow and stress near the well based on a range of likely parameters.

  18. Strength and ductility of room-dry and water-saturated igneous rocks at low pressures and temperatures to partial melting. Final report

    SciTech Connect

    Friedman, M.; Handin, J.; Higgs, N.G.; Lantz, J.R.; Bauer, S.J.

    1980-11-01

    Rock types that are likely candidates for drilling were tested. Reported herein are the short-time ultimate strengths and ductilities determined at temperatures of 25/sup 0/ to 1050/sup 0/C and a strain rate of 10/sup -4/s/sup -1/ of (a) room-dry Mt. Hood Andesite, Cuerbio Basalt, and Charcoal (St. Cloud Gray) Granodiorite at confining pressures of 0, 50, and 100 MPa, (b) water-saturated specimens of the same three rocks at zero effective pressure (both pore and confining pressures of 50 MPa), and (c) room-dry Newberry Rhyolite Obsidian at 0 and 50 MPa. These strengths are then compared with the stresses developed at the wall of a borehole in an elastic medium at the appropriate temperatures and mean pressures to assess the problem of borehole stability. (MHR)

  19. Fast Quasi-Adiabatic Gas Cooling: An Experiment Revisited

    ERIC Educational Resources Information Center

    Oss, S.; Gratton, L. M.; Calza, G.; Lopez-Arias, T.

    2012-01-01

    The well-known experiment of the rapid expansion and cooling of the air contained in a bottle is performed with a rapidly responsive, yet very cheap thermometer. The adiabatic, low temperature limit is approached quite closely and measured with our apparatus. A straightforward theoretical model for this process is also presented and discussed.…

  20. A Kinetic Study of the Adiabatic Polymerization of Acrylamide.

    ERIC Educational Resources Information Center

    Thomson, R. A. M.

    1986-01-01

    Discusses theory, procedures, and results for an experiment which demonstrates the application of basic physics to chemical problems. The experiment involves the adiabatic process, in which polymerization carried out in a vacuum flask is compared to the theoretical prediction of the model with the temperature-time curve obtained in practice. (JN)

  1. Adiabatic fluctuations from cosmic strings in a contracting universe

    SciTech Connect

    Brandenberger, Robert H.; Takahashi, Tomo; Yamaguchi, Masahide E-mail: tomot@cc.saga-u.ac.jp

    2009-07-01

    We show that adiabatic, super-Hubble, and almost scale invariant density fluctuations are produced by cosmic strings in a contracting universe. An essential point is that isocurvature perturbations produced by topological defects such as cosmic strings on super-Hubble scales lead to a source term which seeds the growth of curvature fluctuations on these scales. Once the symmetry has been restored at high temperatures, the isocurvature seeds disappear, and the fluctuations evolve as adiabatic ones in the expanding phase. Thus, cosmic strings may be resurrected as a mechanism for generating the primordial density fluctuations observed today.

  2. LETTERS AND COMMENTS: Adiabatic process reversibility: microscopic and macroscopic views

    NASA Astrophysics Data System (ADS)

    Anacleto, Joaquim; Pereira, Mário G.

    2009-05-01

    The reversibility of adiabatic processes was recently addressed by two publications. In the first (Miranda 2008 Eur. J. Phys. 29 937-43), an equation was derived relating the initial and final volumes and temperatures for adiabatic expansions of an ideal gas, using a microscopic approach. In that relation the parameter r accounts for the process reversibility, ranging between 0 and 1, which corresponds to the free and reversible expansion, respectively. In the second (Anacleto and Pereira 2009 Eur. J. Phys. 30 177-83), the authors have shown that thermodynamics can effectively and efficiently be used to obtain the general law for adiabatic processes carried out by an ideal gas, including compressions, for which r \\ge 1. The present work integrates and extends the aforementioned studies, providing thus further insights into the analysis of the adiabatic process. It is shown that Miranda's work is wholly valid for compressions. In addition, it is demonstrated that the adiabatic reversibility coefficient given in terms of the piston velocity and the root mean square velocity of the gas particles is equivalent to the macroscopic description, given just by the quotient between surroundings and system pressure values.

  3. Influence of impurities and deformation temperature on the saturation microstructure and ductility of HPT-deformed nickel.

    PubMed

    Rathmayr, Georg B; Pippan, Reinhard

    2011-11-01

    Ni with different purities between 99.69 and 99.99 wt.% was deformed by high-pressure torsion (HPT) to high strains, where no further refinement of the microstructure is observed. The HPT deformation temperature varied between -196 and 400 °C. Both impurities and temperature significantly affect the lower limit of the grain size obtained by HPT. In the investigated samples, carbon was the most important impurity element in controlling the limit of grain refinement. The decrease in grain size due to an increase in the carbon content from 0.008 to 0.06 wt.% for HPT-deformed Ni samples at room temperature enhanced the ultimate tensile strength from 1000 to 1700 MPa. Surprisingly, the carbon content did not deteriorate the ductility, defined as the reduction in area, which is mainly limited by the total amount of impurities besides carbon. Furthermore, the deformation temperature dependency on ductility was not very pronounced and only visible for deformation temperatures above 200 °C. PMID:22163380

  4. Trace element mass balance in hydrous adiabatic mantle melting: The Hydrous Adiabatic Mantle Melting Simulator version 1 (HAMMS1)

    NASA Astrophysics Data System (ADS)

    Kimura, Jun-Ichi; Kawabata, Hiroshi

    2014-06-01

    numerical mass balance calculation model for the adiabatic melting of a dry to hydrous peridotite has been programmed in order to simulate the trace element compositions of basalts from mid-ocean ridges, back-arc basins, ocean islands, and large igneous provinces. The Excel spreadsheet-based calculator, Hydrous Adiabatic Mantle Melting Simulator version 1 (HAMMS1) uses (1) a thermodynamic model of fractional adiabatic melting of mantle peridotite, with (2) the parameterized experimental melting relationships of primitive to depleted mantle sources in terms of pressure, temperature, water content, and degree of partial melting. The trace element composition of the model basalt is calculated from the accumulated incremental melts within the adiabatic melting regime, with consideration for source depletion. The mineralogic mode in the primitive to depleted source mantle in adiabat is calculated using parameterized experimental results. Partition coefficients of the trace elements of mantle minerals are parameterized to melt temperature mostly from a lattice strain model and are tested using the latest compilations of experimental results. The parameters that control the composition of trace elements in the model are as follows: (1) mantle potential temperature, (2) water content in the source mantle, (3) depth of termination of adiabatic melting, and (4) source mantle depletion. HAMMS1 enables us to obtain the above controlling parameters using Monte Carlo fitting calculations and by comparing the calculated basalt compositions to primary basalt compositions. Additionally, HAMMS1 compares melting parameters with a major element model, which uses petrogenetic grids formulated from experimental results, thus providing better constraints on the source conditions.

  5. The HAWC and SAFIRE Adiabatic Demagnetization Refrigerators

    NASA Technical Reports Server (NTRS)

    Tuttle, Jim; Shirron, Peter; DiPirro, Michael; Jackson, Michael; Behr, Jason; Kunes, Evan; Hait, Tom; Krebs, Carolyn (Technical Monitor)

    2001-01-01

    The High-Resolution Airborne Wide-band Camera (HAWC) and Submillimeter and Far Infrared Experiment (SAFIRE) are far-infrared experiments which will fly on the Stratospheric Observatory for Infrared Astronomy (SOFIA) aircraft. HAWC's detectors will operate at 0.2 Kelvin, while those of SAFIRE will be at 0.1 Kelvin. Each instrument will include an adiabatic demagnetization refrigerator (ADR) to cool its detector stage from the liquid helium bath temperature (HAWC's at 4.2 Kelvin and SAFIRE's pumped to about 1.3 Kelvin) to its operating temperature. Except for the magnets used to achieve the cooling and a slight difference in the heat switch design, the two ADRs are nearly identical. We describe the ADR design and present the results of performance testing.

  6. Sliding seal materials for adiabatic engines

    NASA Technical Reports Server (NTRS)

    Lankford, J.

    1985-01-01

    The sliding friction coefficients and wear rates of promising carbide, oxide, and nitride materials were measured under temperature, environmental, velocity, loading conditions that are representative of the adiabatic engine environment. In order to provide guidance needed to improve materials for this application, the program stressed fundamental understanding of the mechanisms involved in friction and wear. Microhardness tests were performed on the candidate materials at elevated temperatures, and in atmospheres relevant to the piston seal application, and optical and electron microscopy were used to elucidate the micromechanisms of wear following wear testing. X-ray spectroscopy was used to evaluate interface/environment interactions which seemed to be important in the friction and wear process. Electrical effects in the friction and wear processes were explored in order to evaluate the potential usefulness of such effects in modifying the friction and wear rates in service. However, this factor was found to be of negligible significance in controlling friction and wear.

  7. Influence of feedstock and pyrolysis temperature of biochar amendments on transport of Escherichia coli in saturated and unsaturated soil

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Recent research has shown that biochar amendment could enhance bacterial retention in soils. We evaluated the effects of biochar feedstock, pyrolysis temperature and application rate on soil retention of Escherichia coli. We compared how biochar produced from poultry litter and pine chip pyrolyzed ...

  8. Effect of the Heat Pipe Adiabatic Region.

    PubMed

    Brahim, Taoufik; Jemni, Abdelmajid

    2014-04-01

    The main motivation of conducting this work is to present a rigorous analysis and investigation of the potential effect of the heat pipe adiabatic region on the flow and heat transfer performance of a heat pipe under varying evaporator and condenser conditions. A two-dimensional steady-state model for a cylindrical heat pipe coupling, for both regions, is presented, where the flow of the fluid in the porous structure is described by Darcy-Brinkman-Forchheimer model which accounts for the boundary and inertial effects. The model is solved numerically by using the finite volumes method, and a fortran code was developed to solve the system of equations obtained. The results show that a phase change can occur in the adiabatic region due to temperature gradient created in the porous structure as the heat input increases and the heat pipe boundary conditions change. A recirculation zone may be created at the condenser end section. The effect of the heat transfer rate on the vapor radial velocities and the performance of the heat pipe are discussed. PMID:24895467

  9. Distributed Saturation

    NASA Technical Reports Server (NTRS)

    Chung, Ming-Ying; Ciardo, Gianfranco; Siminiceanu, Radu I.

    2007-01-01

    The Saturation algorithm for symbolic state-space generation, has been a recent break-through in the exhaustive veri cation of complex systems, in particular globally-asyn- chronous/locally-synchronous systems. The algorithm uses a very compact Multiway Decision Diagram (MDD) encoding for states and the fastest symbolic exploration algo- rithm to date. The distributed version of Saturation uses the overall memory available on a network of workstations (NOW) to efficiently spread the memory load during the highly irregular exploration. A crucial factor in limiting the memory consumption during the symbolic state-space generation is the ability to perform garbage collection to free up the memory occupied by dead nodes. However, garbage collection over a NOW requires a nontrivial communication overhead. In addition, operation cache policies become critical while analyzing large-scale systems using the symbolic approach. In this technical report, we develop a garbage collection scheme and several operation cache policies to help on solving extremely complex systems. Experiments show that our schemes improve the performance of the original distributed implementation, SmArTNow, in terms of time and memory efficiency.

  10. The effects of temperature and motility on the advective transport of a deep subsurface bacteria through saturated sediment

    SciTech Connect

    McCaulou, D.R.

    1993-10-01

    Replicate column experiments were done to quantify the effects of temperature and bacterial motility on advective transport through repacked, but otherwise unaltered, natural aquifer sediment. The bacteria used in this study, A0500, was a flagellated, spore-forming rod isolated from the deep subsurface at DOE`s Savannah River Laboratory. Motility was controlled by turning on flagellar metabolism at 18{degrees}C but off at 40{degrees}C. Microspheres were used to independently quantify the effects of temperature on the sticking efficiency ({alpha}), estimated using a steady-state filtration model. The observed greater microsphere removal at the higher temperature agreed with the physical-chemical model, but bacteria removal at 18{degrees}C was only half that at 4{degrees}C. The sticking efficiency for non-motile A0500 (4{degrees}C) was over three times that of the motile A0500 (18{degrees}C), 0.073 versus 0.022 respectively. Analysis of complete breakthrough curves using a non-steady, kinetically limited, transport model to estimate the time scales of attachment and detachment suggested that motile A 0500 bacteria traveled twice as far as non-motile A 0500 bacteria before becoming attached. Once attached, non-motile colloids detached on the time scale of 9 to 17 days. The time scale for detachment of motile A0500 bacteria was shorter, 4 to 5 days. Results indicate that bacterial attachment was reversible and detachment was enhanced by bacterial motifity. The kinetic energy of bacterial motility changed the attachment-detachment kinetics in favor of the detached state. The chemical factors responsible for the enhanced transport are not known. However, motility may have caused weakly held bacteria to detach from the secondary minimum, and possibly from the primary minimum, as described by DLVO theory.

  11. Invalidity of the quantitative adiabatic condition and general conditions for adiabatic approximations

    NASA Astrophysics Data System (ADS)

    Li, Dafa

    2016-05-01

    The adiabatic theorem was proposed about 90 years ago and has played an important role in quantum physics. The quantitative adiabatic condition constructed from eigenstates and eigenvalues of a Hamiltonian is a traditional tool to estimate adiabaticity and has proven to be the necessary and sufficient condition for adiabaticity. However, recently the condition has become a controversial subject. In this paper, we list some expressions to estimate the validity of the adiabatic approximation. We show that the quantitative adiabatic condition is invalid for the adiabatic approximation via the Euclidean distance between the adiabatic state and the evolution state. Furthermore, we deduce general necessary and sufficient conditions for the validity of the adiabatic approximation by different definitions.

  12. Design of the PIXIE Adiabatic Demagnetization Refrigerators

    NASA Technical Reports Server (NTRS)

    Shirron, Peter J.; Kimball, Mark Oliver; Fixsen, Dale J.; Kogut, Alan J.; Li, Xiaoyi; DiPirro, Michael

    2012-01-01

    The Primordial Inflation Explorer (PIXIE) is a proposed mission to densely map the polarization of the cosmic microwave background. It will operate in a scanning mode from a sun-synchronous orbit, using low temperature detectors (at 0.1 K) and located inside a teslescope that is cooled to approximately 2.73 K - to match the background temperature. A mechanical cryocooler operating at 4.5 K establishes a low base temperature from which two adiabatic demagnetization refrigerator (ADR) assemblies will cool the telescope and detectors. To achieve continuous scanning capability, the ADRs must operate continuously. Complicating the design are two factors: 1) the need to systematically vary the temperature of various telescope components in order to separate the small polarization signal variations from those that may arise from temperature drifts and changing gradients within the telescope, and 2) the orbital and monthly variations in lunar irradiance into the telescope barrels. These factors require the telescope ADR to reject quasi-continuous heat loads of 2-3 millwatts, while maintaining a peak heat reject rate of less than 12 milliwatts. The detector heat load at 0.1 K is comparatively small at 1-2 microwatts. This paper will describe the 3-stage and 2-stage continuous ADRs that will be used to meet the cooling power and temperature stability requirements of the PIXIE detectors and telescope.

  13. High-temperature stability and saturation magnetization of superparamagnetic nickel nanoparticles in microporous polysilazane-derived ceramics and their gas permeation properties.

    PubMed

    Seifollahi Bazarjani, Mahdi; Müller, Mathis M; Kleebe, Hans-Joachim; Jüttke, Yvonne; Voigt, Ingolf; Baghaie Yazdi, Mehrdad; Alff, Lambert; Riedel, Ralf; Gurlo, Aleksander

    2014-08-13

    Superparamagnetic Ni nanoparticles with diameters of about 3 nm are formed in situ at room temperature in a polysilazane matrix, forming Ni/polysilazane nanocomposite, in the reaction between a polysilazane and trans-bis(aceto-kO)bis(2-aminoethanol-k(2)N,O)nickel(II). The thermolysis of the Ni/polysilazane nanocomposite at 700 °C in an argon atmosphere results in a microporous superparamagnetic Ni/silicon oxycarbonitride (Ni/SiCNO) ceramic nanocomposite. The growth of Ni nanoparticles in Ni/SiCNO ceramic nanocomposite is totally suppressed even after thermolysis at 700 °C, as confirmed by HRTEM and SQUID characterizations. The analysis of saturation magnetization of Ni nanoparticles in Ni/polysilazane and Ni/SiCNO nanocomposites indicates that the saturation magnetization of Ni nanoparticles is higher than expected values and infers that the surfaces of Ni nanoparticles are not oxidized. The microporous superparamagnetic Ni/SiCNO nanocomposite is shaped as a free-standing monolith and foam. In addition, Ni/SiCNO membranes are fabricated by the dip-coating of a tubular alumina substrate in a dispersion of Ni/polysilazane in THF followed by a thermolysis at 700 °C under an argon atmosphere. The gas separation performance of Ni/SiCNO membranes at 25 and 300 °C is assessed by the single gas permeance (pressure rise technique) using He, H2, CO2, N2, CH4, n-propene, n-propane, n-butene, n-butane, and SF6 as probe molecules. After hydrothermal treatment, the higher increase in the hydrogen permeance compared to the permeance of other gases as a function of temperature indicates that the hydrogen affinity of Ni nanoparticles influences the transport of hydrogen in the Ni/SiCNO membrane and Ni nanoparticles stabilize the structure against hydrothermal corrosion. PMID:25014337

  14. Technical Note: Controlled experimental aquarium system for multi-stressor investigation of carbonate chemistry, oxygen saturation, and temperature

    NASA Astrophysics Data System (ADS)

    Bockmon, E. E.; Frieder, C. A.; Navarro, M. O.; White-Kershek, L. A.; Dickson, A. G.

    2013-09-01

    As the field of ocean acidification has grown, researchers have increasingly turned to laboratory experiments to understand the impacts of increased CO2 on marine organisms. However, other changes such as ocean warming and deoxygenation are occurring concurrently with the increasing CO2 concentrations, complicating the understanding of the impacts of anthropogenic changes on organisms. This experimental aquarium design allows for independent regulation of CO2 concentration, O2 levels, and temperature in a controlled environment to study the impacts of multiple stressors. The system has the flexibility for a wide range of treatment chemistry, seawater volumes, and study organisms. Control of the seawater chemistry is achieved by equilibration of a chosen gas mixture with seawater using a Liqui-Cel® membrane contactor. Included as examples, two experiments performed using the system have shown control of CO2 at values between approximately 500 and 1400 μatm and O2 at values from 80 to 240 μmol kg-1. Temperature has been maintained to 0.5 °C or better in the range of 10-17 °C. On a weeklong timescale, the system has achieved variability in pH of less than 0.007 pH units and in oxygen concentration of less than 3.5 μmol kg-1. Longer experiments, over a month in duration, have been completed with control to better than 0.08 pH units and 13 μmol kg-1 O2. The ability to study the impacts of multiple stressors in the laboratory simultaneously, as well as independently, will be an important part of understanding the response of marine organisms to a high-CO2 world.

  15. On adiabatic stabilization and geometry of Bunsen flames

    SciTech Connect

    Sun, C.J.; Sung, C.J.; Law, C.K.

    1994-12-31

    Two aspects of stretched flame dynamics are investigated via the model problem of the stabilization and geometry of Bunsen flames. Specifically, the possibility of stabilizing a Bunsen flame without heat loss to the burner rim is experimentally investigated by examining the temperature of the rim, the temperature gradient between the rim and the flame base, and the standoff distance of the flame base in relation to the flame thickness. Results show that, while heat loss is still the dominant stabilization mechanism for flames in uniform flows and for strong flames in parabolic flow, adiabatic stabilization and, subsequently, blowoff are indeed possible for weak flames in parabolic flows. The adiabatically stabilized flame is then modeled by using the scalar field formulation and by allowing for the effects of curvature and aerodynamic straining on the local flame speed. The calculated flame configuration agrees well with the experiment for the adiabatically stabilized flame but not for the nonadiabatic flame. Results further show that active modification of the flame curvature is the dominant cause for the flame to maintain adiabatic stabilization. Implications of the present results on turbulent flame modeling are discussed.

  16. An adiabatic demagnetization refrigerator for SIRTF

    NASA Technical Reports Server (NTRS)

    Timbie, P. T.; Bernstein, G. M.; Richards, P. L.

    1989-01-01

    An adiabatic demagnetization refrigerator (ADR) has been proposed to cool bolometric infrared detectors on the multiband imaging photometer of the Space Infrared Telescope Facility (SIRTF). One such refrigerator has been built which uses a ferric ammonium alum salt pill suspended by nylon threads in a 3-T solenoid. The resonant modes of this suspension are above 100 Hz. The heat leak to the salt pill is less than 0.5 microW. The system has a hold time at 0.1K of more than 12 h. The cold stage temperature is regulated with a feedback loop that controls the magnetic field. A second, similar refrigerator is being built at a SIRTF prototype to fly on a ballon-borne telescope. It will use a ferromagnetic shield. The possibility of using a high-Tc solenoid-actuated heat switch is also discussed.

  17. An adiabatic demagnetization refrigerator for SIRTF

    SciTech Connect

    Timbie, P.T.; Bernstein, G.M.; Richards, P.L.

    1989-02-01

    An adiabatic demagnetization refrigerator (ADR) has been proposed to cool bolometric infrared detectors on the Multiband Imaging Photometer of the Space Infrared Telescope Facility (SIRTF). The authors have built one such refrigerator which employs a ferric ammonium alum salt pill suspended by nylon threads in a 3 Tesla solenoid. The resonant modes of this suspension are above 100 Hz. The heat leak to the salt pill is <0.5 ..mu..W. The system has a hold time at 0.1 /sup 0/K of >12 hours. The cold stage temperature is regulated with a feedback loop that controls the magnetic field. A second, similar refrigerator is being built as a SIRTF prototype to fly on a balloon-borne telescope. It will employ a ferromagnetic shield. The possibility of using high T/sub c/ leads to the superconducting magnet and a solenoid-actuated heat switch are also discussed.

  18. Stirling engine with one adiabatic cylinder

    NASA Astrophysics Data System (ADS)

    West, C. D.

    1982-03-01

    It is shown that integration around the P-V loop of a Stirling-like cycle with an adiabatic expansion or compression space is possible through careful application of the ideal gas laws. The result is a set of closed-form solutions or the work output, work input, and efficiency for ideal gases. Previous analyses yielded closed-form solutions only for machines in which all spaces behave isothermally, or that have other limitations that simplify the arithmetic but omit important aspects of real machines. The results of this analysis, although still far removed from the exact behavior of real, practical engines, yield important insights into the effects observed in computer models and experimental machines. These results are especially illuminating for machines intended to operate with fairly small temperature differences. Heat pumps and low-technology solar-powered engines might be included in this category.

  19. Viscous Heating of Ions through Saturated Fine-Scale MHD Instabilities in a Z-Pinch at 200-300 KeV Temperature

    NASA Astrophysics Data System (ADS)

    Haines, Malcolm; Coverdale, Christine; Deeney, Chris; Lepell, P. David; Jones, Brent; Apruzese, J. P.

    2006-10-01

    Pulsed power driven Z-pinches yield large X-ray powers at stagnation, the energy of which can exceed by up to factors of 3 or 4, the estimated kinetic energy of the implosion. Furthermore, when electron temperatures are measured at stagnation similar in temperatures would not lead to pressure balance. These problems can be resolved by a theoretical model in which short wavelength (ka >> 1, and viscous Lundquist number ˜ 1), fast growing, m=O MHD instabilities reach a saturated amplitude, and the associated viscous dissipation of the vortices leads to ion heating. Equating this heating rate to the equipartition of energy to electrons leads to an estimate of the ion temperature and pinch radius at pressure balance. Extremely high ion temperatures in the range of 200-300 KeV are predicted from this model for stainless steel wire array experiments on Z at Sandia. These have been confirmed from time-resolved Doppler broadening spectroscopic measurements of the optically thin Fe He-δ line. This conversion of magnetic energy into ion thermal energy occurs on the nanosecond timescale, and can prevent radiative collapse. Any accompanying loss of magnetic flux in this highly conducting plasma can be explained by the occurrence of a large number of hot spots along the axis, with electron density and temperature variating not exactly in phase. This leads to a significant value of the integral of E.dl. Dl along the axis due to the grad Pe term in Ohm's law, analogous to the magnetic field generating term found in laser-plasma interactions. Ref 1. M.G. Haines, et al; Phys. Rev. Lett. 96, 075003 (2006) Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy under Contract DE-ACO4-94AL85000.

  20. Adiabatic Wankel type rotary engine

    NASA Technical Reports Server (NTRS)

    Kamo, R.; Badgley, P.; Doup, D.

    1988-01-01

    This SBIR Phase program accomplished the objective of advancing the technology of the Wankel type rotary engine for aircraft applications through the use of adiabatic engine technology. Based on the results of this program, technology is in place to provide a rotor and side and intermediate housings with thermal barrier coatings. A detailed cycle analysis of the NASA 1007R Direct Injection Stratified Charge (DISC) rotary engine was performed which concluded that applying thermal barrier coatings to the rotor should be successful and that it was unlikely that the rotor housing could be successfully run with thermal barrier coatings as the thermal stresses were extensive.

  1. Adiabatic preparation of Floquet condensates

    NASA Astrophysics Data System (ADS)

    Heinisch, Christoph; Holthaus, Martin

    2016-10-01

    We argue that a Bose-Einstein condensate can be transformed into a Floquet condensate, that is, into a periodically time-dependent many-particle state possessing the coherence properties of a mesoscopically occupied single-particle Floquet state. Our reasoning is based on the observation that the denseness of the many-body system's quasienergy spectrum does not necessarily obstruct effectively adiabatic transport. Employing the idealized model of a driven bosonic Josephson junction, we demonstrate that only a small amount of Floquet entropy is generated when a driving force with judiciously chosen frequency and maximum amplitude is turned on smoothly.

  2. Saturated fat (image)

    MedlinePlus

    ... saturated fats. Vegetable sources of saturated fat include coconut and palm oils. When looking at a food label, pay close ... saturated fats. Vegetable sources of saturated fat include coconut and palm oils. When looking at a food label, pay close ...

  3. On the question of adiabatic invariants

    NASA Astrophysics Data System (ADS)

    Mitropol'Skii, Iu. A.

    Some aspects of the construction of adiabadic invariants for dynamic systems with a single degree of freedom are discussed. Adiabatic invariants are derived using classical principles and the method proposed by Djukic (1981). The discussion covers an adiabatic invariant for a dynamic system with slowly varying parameters; derivation of an expression for an adiabatic invariant by the Djukic method for a second-order equation with a variable mass; and derivation of an expression for the adiabatic invariant for a nearly integrable differential equation.

  4. Vapor Saturation as The Cause of Volcanic Eruptions at the Lassen Volcanic Center, California, as Inferred from Crystallization Pressures and Temperatures

    NASA Astrophysics Data System (ADS)

    De Los Reyes, A. M. A.; Putirka, K. D.; Clynne, M. A.; Scruggs, M. A.

    2015-12-01

    The last three silicic eruptions at the Lassen Volcanic Center occurred at Lassen Peak (27 ka and 1915-17) and Chaos Crags (1103 yrs BP). Klemetti and Clynne (2014) showed that felsic eruptions at Lassen reflect remobilization of resident rhyodacitic crystal mush by intrusion of mafic magma. To better understand the rejuvenation and eruption triggering process, we calculate crystallization temperatures and pressures from clinopyroxene-liquid equilibria on mafic enclaves that provide our closest approach to the composition of mafic magmas delivered to the shallow system. Our goal is to examine whether and to what extent cooling and crystallization occur after recharge, which bears on whether recharge, mixing, or partial crystallization (and consequent vapor saturation) provide the trigger for eruption. We use results from the cpx-liq barometer (1.7 kbar) as input to calculate T for other phases (plagioclase, olivine and amphibole) found in mafic enclave samples. Cpx crystallizes at 1100-1150 oC and olivine precipitates at similar to slightly higher temperatures. Cpx and ol are followed by plagioclase (1000-1050 oC), amphibole (875-1000 oC), and Fe-Ti oxides (1030-1050 oC). These temperatures indicate that recharge magmas are incompletely crystallized as they enter the shallow reservoir of cooler (~725-750 oC, Quinn et al., 2013) felsic crystal mush, and that significant cooling of the mafic magma occurs during mixing and prior to eruption. Such cooling intervals indicate that recharge is not the proximal cause of eruption, but rather that vapor saturation, following a period of mixing and cooling, leads to increased magma overpressure that causes eruption. Interestingly, the Lassen Peak 27 ka volcanics (at 2.09 km3), have a greater volume than either of Chaos Crags (1.2 km3) and the 1915 (0.03 km3) eruption, but our results indicate that their thermal histories are similar. This suggests that while volumes of mafic recharge may control the degree of interaction with

  5. Protecting and accelerating adiabatic passage with time-delayed pulse sequences.

    PubMed

    Sampedro, Pablo; Chang, Bo Y; Sola, Ignacio R

    2016-05-21

    Using numerical simulations of two-photon electronic absorption with femtosecond pulses in Na2 we show that: (i) it is possible to avoid the characteristic saturation or dumped Rabi oscillations in the yield of absorption by time-delaying the laser pulses; (ii) it is possible to accelerate the onset of adiabatic passage by using the vibrational coherence starting in a wave packet; and (iii) it is possible to prepare the initial wave packet in order to achieve full state-selective transitions with broadband pulses. The findings can be used, for instance, to achieve ultrafast adiabatic passage by light-induced potentials and understand its intrinsic robustness. PMID:27125342

  6. Protecting and accelerating adiabatic passage with time-delayed pulse sequences.

    PubMed

    Sampedro, Pablo; Chang, Bo Y; Sola, Ignacio R

    2016-05-21

    Using numerical simulations of two-photon electronic absorption with femtosecond pulses in Na2 we show that: (i) it is possible to avoid the characteristic saturation or dumped Rabi oscillations in the yield of absorption by time-delaying the laser pulses; (ii) it is possible to accelerate the onset of adiabatic passage by using the vibrational coherence starting in a wave packet; and (iii) it is possible to prepare the initial wave packet in order to achieve full state-selective transitions with broadband pulses. The findings can be used, for instance, to achieve ultrafast adiabatic passage by light-induced potentials and understand its intrinsic robustness.

  7. Quasi-adiabatic compression heating of selected foods

    NASA Astrophysics Data System (ADS)

    Landfeld, Ales; Strohalm, Jan; Halama, Radek; Houska, Milan

    2011-03-01

    The quasi-adiabatic temperature increase due to compression heating, during high-pressure (HP) processing (HPP), was studied using specially designed equipment. The temperature increase was evaluated as the difference in temperature, during compression, between atmospheric pressure and nominal pressure. The temperature was measured using a thermocouple in the center of a polyoxymethylene cup, which contained the sample. Fresh meat balls, pork meat pate, and tomato purée temperature increases were measured at three initial temperature levels between 40 and 80 °C. Nominal pressure was either 400 or 500 MPa. Results showed that the fat content had a positive effect on temperature increases. Empirical equations were developed to calculate the temperature increase during HPP at different initial temperatures for pressures of 400 and 500 MPa. This thermal effect data can be used for numerical modeling of temperature histories of foods during HP-assisted pasteurization or sterilization processes.

  8. On the Effect of Strain Gradient on Adiabatic Shear Banding

    NASA Astrophysics Data System (ADS)

    Tsagrakis, Ioannis; Aifantis, Elias C.

    2015-10-01

    Most of the work on adiabatic shear banding is based on the effect of temperature gradients on shear band nucleation and evolution. In contrast, the present work considers the coupling between temperature and strain gradients. The competition of thermal and strain gradient terms on the onset of instability and its dependence on specimen size is illustrated. It is shown that heat conduction promotes the instability initiation in the hardening part of the homogeneous stress-strain, while the strain gradient term favors the occurrence of this initiation in the softening regime. This behavior is size dependent, i.e., small specimens can support stable homogeneous deformations even in the softening regime. The spacing of adiabatic shear bands is also evaluated by considering the dominant instability mode during the primary stages of the localization process and it is found that it is an increasing function of the strain gradient coefficient.

  9. Degenerate adiabatic perturbation theory: Foundations and applications

    NASA Astrophysics Data System (ADS)

    Rigolin, Gustavo; Ortiz, Gerardo

    2014-08-01

    We present details and expand on the framework leading to the recently introduced degenerate adiabatic perturbation theory [Phys. Rev. Lett. 104, 170406 (2010), 10.1103/PhysRevLett.104.170406], and on the formulation of the degenerate adiabatic theorem, along with its necessary and sufficient conditions [given in Phys. Rev. A 85, 062111 (2012), 10.1103/PhysRevA.85.062111]. We start with the adiabatic approximation for degenerate Hamiltonians that paves the way to a clear and rigorous statement of the associated degenerate adiabatic theorem, where the non-Abelian geometric phase (Wilczek-Zee phase) plays a central role to its quantitative formulation. We then describe the degenerate adiabatic perturbation theory, whose zeroth-order term is the degenerate adiabatic approximation, in its full generality. The parameter in the perturbative power-series expansion of the time-dependent wave function is directly associated to the inverse of the time it takes to drive the system from its initial to its final state. With the aid of the degenerate adiabatic perturbation theory we obtain rigorous necessary and sufficient conditions for the validity of the adiabatic theorem of quantum mechanics. Finally, to illustrate the power and wide scope of the methodology, we apply the framework to a degenerate Hamiltonian, whose closed-form time-dependent wave function is derived exactly, and also to other nonexactly solvable Hamiltonians whose solutions are numerically computed.

  10. Fast quasi-adiabatic gas cooling: an experiment revisited

    NASA Astrophysics Data System (ADS)

    Oss, S.; Gratton, L. M.; Calzà, G.; López-Arias, T.

    2012-09-01

    The well-known experiment of the rapid expansion and cooling of the air contained in a bottle is performed with a rapidly responsive, yet very cheap thermometer. The adiabatic, low temperature limit is approached quite closely and measured with our apparatus. A straightforward theoretical model for this process is also presented and discussed. Both the experimental setup and the associated theoretical interpretation of the cooling phenomenon are suited for a standard general physics course at undergraduate level.

  11. On a Nonlinear Model in Adiabatic Evolutions

    NASA Astrophysics Data System (ADS)

    Sun, Jie; Lu, Song-Feng

    2016-08-01

    In this paper, we study a kind of nonlinear model of adiabatic evolution in quantum search problem. As will be seen here, for this problem, there always exists a possibility that this nonlinear model can successfully solve the problem, while the linear model can not. Also in the same setting, when the overlap between the initial state and the final stare is sufficiently large, a simple linear adiabatic evolution can achieve O(1) time efficiency, but infinite time complexity for the nonlinear model of adiabatic evolution is needed. This tells us, it is not always a wise choice to use nonlinear interpolations in adiabatic algorithms. Sometimes, simple linear adiabatic evolutions may be sufficient for using. Supported by the National Natural Science Foundation of China under Grant Nos. 61402188 and 61173050. The first author also gratefully acknowledges the support from the China Postdoctoral Science Foundation under Grant No. 2014M552041

  12. Quantum and classical dynamics in adiabatic computation

    NASA Astrophysics Data System (ADS)

    Crowley, P. J. D.; Äńurić, T.; Vinci, W.; Warburton, P. A.; Green, A. G.

    2014-10-01

    Adiabatic transport provides a powerful way to manipulate quantum states. By preparing a system in a readily initialized state and then slowly changing its Hamiltonian, one may achieve quantum states that would otherwise be inaccessible. Moreover, a judicious choice of final Hamiltonian whose ground state encodes the solution to a problem allows adiabatic transport to be used for universal quantum computation. However, the dephasing effects of the environment limit the quantum correlations that an open system can support and degrade the power of such adiabatic computation. We quantify this effect by allowing the system to evolve over a restricted set of quantum states, providing a link between physically inspired classical optimization algorithms and quantum adiabatic optimization. This perspective allows us to develop benchmarks to bound the quantum correlations harnessed by an adiabatic computation. We apply these to the D-Wave Vesuvius machine with revealing—though inconclusive—results.

  13. Adiabatic shear mechanisms for the hard cutting process

    NASA Astrophysics Data System (ADS)

    Yue, Caixu; Wang, Bo; Liu, Xianli; Feng, Huize; Cai, Chunbin

    2015-05-01

    The most important consequence of adiabatic shear phenomenon is formation of sawtooth chip. Lots of scholars focused on the formation mechanism of sawtooth, and the research often depended on experimental approach. For the present, the mechanism of sawtooth chip formation still remains some ambiguous aspects. This study develops a combined numerical and experimental approach to get deeper understanding of sawtooth chip formation mechanism for Polycrystalline Cubic Boron Nitride (PCBN) tools orthogonal cutting hard steel GCr15. By adopting the Johnson-Cook material constitutive equations, the FEM simulation model established in this research effectively overcomes serious element distortions and cell singularity in high strain domain caused by large material deformation, and the adiabatic shear phenomenon is simulated successfully. Both the formation mechanism and process of sawtooth are simulated. Also, the change features regarding the cutting force as well as its effects on temperature are studied. More specifically, the contact of sawtooth formation frequency with cutting force fluctuation frequency is established. The cutting force and effect of cutting temperature on mechanism of adiabatic shear are investigated. Furthermore, the effects of the cutting condition on sawtooth chip formation are researched. The researching results show that cutting feed has the most important effect on sawtooth chip formation compared with cutting depth and speed. This research contributes a better understanding of mechanism, feature of chip formation in hard turning process, and supplies theoretical basis for the optimization of hard cutting process parameters.

  14. A geometric criterion for adiabatic chaos

    SciTech Connect

    Kaper, T.J. ); Kovacic, G. )

    1994-03-01

    Chaos in adiabatic Hamiltonian systems is a recent discovery and a pervasive phenomenon in physics. In this work, a geometric criterion is discussed based on the theory of action from classical mechanics to detect the existence of Smale horseshoe chaos in adiabatic systems. It is used to show that generic adiabatic planar Hamiltonian systems exhibit stochastic dynamics in large regions of phase space. To illustrate the method, results are obtained for three problems concerning relativistic particle dynamics, fluid mechanics, and passage through resonance, results which either could not be obtained with existing methods, or which were difficult and analytically impractical to obtain with them.

  15. The 0.1K bolometers cooled by adiabatic demagnetization

    NASA Technical Reports Server (NTRS)

    Roellig, T.; Lesyna, L.; Kittel, P.; Werner, M.

    1983-01-01

    The most straightforward way of reducing the noise equivalent power of bolometers is to lower their operating temperature. We have been exploring the possibility of using conventionally constructed bolometers at ultra-low temperatures to achieve NEP's suitable to the background environment of cooled space telescopes. We have chosen the technique of adiabatic demagnetization of a paramagnetic salt as a gravity independent, compact, and low power way to achieve temperatures below pumped He-3 (0.3 K). The demagnetization cryostat we used was capable of reaching temperatures below 0.08 K using Chromium Potassium Alum as a salt from a starting temperature of 1.5 K and a starting magnetic field of 30,000 gauss. Computer control of the magnetic field decay allowed a temperature of 0.2 K to be maintained to within 0.5 mK over a time period exceeding 14 hours. The refrigerator duty cycle was over 90 percent at this temperature. The success of these tests has motivated us to construct a more compact portable adiabatic demagnetization cryostat capable of bolometer optical tests and use at the 5m Hale telescope at 1mm wavelengths.

  16. Simulation of periodically focused, adiabatic thermal beams

    SciTech Connect

    Chen, C.; Akylas, T. R.; Barton, T. J.; Field, D. M.; Lang, K. M.; Mok, R. V.

    2012-12-21

    Self-consistent particle-in-cell simulations are performed to verify earlier theoretical predictions of adiabatic thermal beams in a periodic solenoidal magnetic focusing field [K.R. Samokhvalova, J. Zhou and C. Chen, Phys. Plasma 14, 103102 (2007); J. Zhou, K.R. Samokhvalova and C. Chen, Phys. Plasma 15, 023102 (2008)]. In particular, results are obtained for adiabatic thermal beams that do not rotate in the Larmor frame. For such beams, the theoretical predictions of the rms beam envelope, the conservations of the rms thermal emittances, the adiabatic equation of state, and the Debye length are verified in the simulations. Furthermore, the adiabatic thermal beam is found be stable in the parameter regime where the simulations are performed.

  17. Adiabatic Motion of Fault Tolerant Qubits

    NASA Astrophysics Data System (ADS)

    Drummond, David Edward

    This work proposes and analyzes the adiabatic motion of fault tolerant qubits in two systems as candidates for the building blocks of a quantum computer. The first proposal examines a pair of electron spins in double quantum dots, finding that the leading source of decoherence, hyperfine dephasing, can be suppressed by adiabatic rotation of the dots in real space. The additional spin-orbit effects introduced by this motion are analyzed, simulated, and found to result in an infidelity below the error-correction threshold. The second proposal examines topological qubits formed by Majorana zero modes theorized to exist at the ends of semiconductor nanowires coupled to conventional superconductors. A model is developed to design adiabatic movements of the Majorana bound states to produce entangled qubits. Analysis and simulations indicate that these adiabatic operations can also be used to demonstrate entanglement experimentally by testing Bell's theorem.

  18. General conditions for quantum adiabatic evolution

    SciTech Connect

    Comparat, Daniel

    2009-07-15

    Adiabaticity occurs when, during its evolution, a physical system remains in the instantaneous eigenstate of the Hamiltonian. Unfortunately, existing results, such as the quantum adiabatic theorem based on a slow down evolution [H({epsilon}t),{epsilon}{yields}0], are insufficient to describe an evolution driven by the Hamiltonian H(t) itself. Here we derive general criteria and exact bounds, for the state and its phase, ensuring an adiabatic evolution for any Hamiltonian H(t). As a corollary, we demonstrate that the commonly used condition of a slow Hamiltonian variation rate, compared to the spectral gap, is indeed sufficient to ensure adiabaticity but only when the Hamiltonian is real and nonoscillating (for instance, containing exponential or polynomial but no sinusoidal functions)

  19. Experimental demonstration of composite adiabatic passage

    NASA Astrophysics Data System (ADS)

    Schraft, Daniel; Halfmann, Thomas; Genov, Genko T.; Vitanov, Nikolay V.

    2013-12-01

    We report an experimental demonstration of composite adiabatic passage (CAP) for robust and efficient manipulation of two-level systems. The technique represents a altered version of rapid adiabatic passage (RAP), driven by composite sequences of radiation pulses with appropriately chosen phases. We implement CAP with radio-frequency pulses to invert (i.e., to rephase) optically prepared spin coherences in a Pr3+:Y2SiO5 crystal. We perform systematic investigations of the efficiency of CAP and compare the results with conventional π pulses and RAP. The data clearly demonstrate the superior features of CAP with regard to robustness and efficiency, even under conditions of weakly fulfilled adiabaticity. The experimental demonstration of composite sequences to support adiabatic passage is of significant relevance whenever a high efficiency or robustness of coherent excitation processes need to be maintained, e.g., as required in quantum information technology.

  20. Adiabatic limits on Riemannian Heisenberg manifolds

    SciTech Connect

    Yakovlev, A A

    2008-02-28

    An asymptotic formula is obtained for the distribution function of the spectrum of the Laplace operator, in the adiabatic limit for the foliation defined by the orbits of an invariant flow on a compact Riemannian Heisenberg manifold. Bibliography: 21 titles.

  1. Adiabatic invariance of oscillons/I -balls

    NASA Astrophysics Data System (ADS)

    Kawasaki, Masahiro; Takahashi, Fuminobu; Takeda, Naoyuki

    2015-11-01

    Real scalar fields are known to fragment into spatially localized and long-lived solitons called oscillons or I -balls. We prove the adiabatic invariance of the oscillons/I -balls for a potential that allows periodic motion even in the presence of non-negligible spatial gradient energy. We show that such a potential is uniquely determined to be the quadratic one with a logarithmic correction, for which the oscillons/I -balls are absolutely stable. For slightly different forms of the scalar potential dominated by the quadratic one, the oscillons/I -balls are only quasistable, because the adiabatic charge is only approximately conserved. We check the conservation of the adiabatic charge of the I -balls in numerical simulation by slowly varying the coefficient of logarithmic corrections. This unambiguously shows that the longevity of oscillons/I -balls is due to the adiabatic invariance.

  2. Salt materials testing for a spacecraft adiabatic demagnetization refrigerator

    NASA Astrophysics Data System (ADS)

    Savage, M. L.; Kittel, P.; Roellig, T.

    As part of a technology development effort to qualify adiabatic demagnetization refrigerators for use in a NASA spacecraft, such as the Space Infrared Telescope Facility, a study of low temperature characteristics, heat capacity and resistance to dehydration was conducted for different salt materials. This report includes results of testing with cerrous metaphosphate, several synthetic rubies, and chromic potassium alum (CPA). Preliminary results show that CPA may be suitable for long-term spacecraft use, provided that the salt is property encapsulated. Methods of salt pill construction and testing for all materials are discussed, as well as reliability tests. Also, the temperature regulation scheme and the test cryostat design are briefly discussed.

  3. Salt materials testing for a spacecraft adiabatic demagnetization refrigerator

    NASA Technical Reports Server (NTRS)

    Savage, M. L.; Kittel, P.; Roellig, T.

    1990-01-01

    As part of a technology development effort to qualify adiabatic demagnetization refrigerators for use in a NASA spacecraft, such as the Space Infrared Telescope Facility, a study of low temperature characteristics, heat capacity and resistance to dehydration was conducted for different salt materials. This report includes results of testing with cerrous metaphosphate, several synthetic rubies, and chromic potassium alum (CPA). Preliminary results show that CPA may be suitable for long-term spacecraft use, provided that the salt is property encapsulated. Methods of salt pill construction and testing for all materials are discussed, as well as reliability tests. Also, the temperature regulation scheme and the test cryostat design are briefly discussed.

  4. Symmetry of the Adiabatic Condition in the Piston Problem

    ERIC Educational Resources Information Center

    Anacleto, Joaquim; Ferreira, J. M.

    2011-01-01

    This study addresses a controversial issue in the adiabatic piston problem, namely that of the piston being adiabatic when it is fixed but no longer so when it can move freely. It is shown that this apparent contradiction arises from the usual definition of adiabatic condition. The issue is addressed here by requiring the adiabatic condition to be…

  5. Hierarchical theory of quantum adiabatic evolution

    NASA Astrophysics Data System (ADS)

    Zhang, Qi; Gong, Jiangbin; Wu, Biao

    2014-12-01

    Quantum adiabatic evolution is a dynamical evolution of a quantum system under slow external driving. According to the quantum adiabatic theorem, no transitions occur between nondegenerate instantaneous energy eigenstates in such a dynamical evolution. However, this is true only when the driving rate is infinitesimally small. For a small nonzero driving rate, there are generally small transition probabilities between the energy eigenstates. We develop a classical mechanics framework to address the small deviations from the quantum adiabatic theorem order by order. A hierarchy of Hamiltonians is constructed iteratively with the zeroth-order Hamiltonian being determined by the original system Hamiltonian. The kth-order deviations are governed by a kth-order Hamiltonian, which depends on the time derivatives of the adiabatic parameters up to the kth-order. Two simple examples, the Landau-Zener model and a spin-1/2 particle in a rotating magnetic field, are used to illustrate our hierarchical theory. Our analysis also exposes a deep, previously unknown connection between classical adiabatic theory and quantum adiabatic theory.

  6. Laboratory Measurements of Adiabatic and Isothermal Processes

    NASA Astrophysics Data System (ADS)

    McNairy, W. W.

    1997-04-01

    Adiabatic and isothermal measurements on various of gases are made possible by using the Adiabatic Gas Law apparatus made by PASCO Scientific(Much of this work was published by the author in "The Physics Teacher", vol. 34, March 1996, p. 178-80.). By using a computer interface, undergraduates are able to data for monatomic, diatomic and polyatomic gases for both compression and expansion processes. Designed principally to obtain adiabatic data, the apparatus may be easily modified for use in isothermal processes. The various sets of data are imported into a spreadsheet program where fits may be made to the ideal gas law and the adiabatic gas law. Excellent results are obtained for the natural logarithm of pressure versus the natural logarithm of volume for both the isothermal data (expected slope equal to -1 in all cases) and the adiabatic data (slope equal to -1 times the ratio of specific heats for the particular gas). An overview of the lab procedure used at VMI will be presented along with data obtained for several adiabatic and isothermal processes.

  7. Novel developments and applications of the classical adiabatic dynamics technique

    NASA Astrophysics Data System (ADS)

    Rosso, Lula

    The present work aims to apply and develop modern molecular dynamics techniques based on a novel analysis of the classical adiabatic dynamics approach. In the first part of this thesis, Car-Parrinello ab-initio molecular dynamics, a successful technique based on adiabatic dynamics, is used to study the charge transport mechanism in solid ammonium perchlorate (AP) crystal exposed to an ammonia-rich environment. AP is a solid-state proton conductor composed of NH+4 and ClO-4 units that can undergo a decomposition process at high temperature, leading to its use such as rocket fuel. After computing IR spectra and carefully analysing the dynamics at different temperatures, we found that the charge transport mechanism in the pure crystal is dominated by diffusion of the ammonium ions and that the translational diffusion is strongly coupled to rotational diffusion of the two types of ions present. When the pure ammonium-perchlorate crystal is doped with neutral ammonia, another mechanism comes into play, namely, the Grotthuss proton hopping mechanism via short-lived N2H+7 complexes. In the second part of this thesis, adiabatic dynamics will be used to develop an alternative approach to the calculation of free energy profiles along reaction paths. The new method (AFED) is based on the creation of an adiabatic separation between the reaction coordinate subspace and the remaining degrees of freedom within a molecular dynamics run. This is achieved by associating with the reaction coordinate(s) a high temperature and large mass. These conditions allow the activated process to occur while permitting the remaining degrees of freedom to respond adiabatically. In this limit, by applying a formal multiple time scale Liouville operator factorization, it can be rigorously shown that the free energy profile is obtained directly from the probability distribution of the reaction coordinate subspace and, therefore, no postprocessing of the output data is required. The new method is

  8. Deep proton tunneling in the electronically adiabatic and non-adiabatic limits: comparison of the quantum and classical treatment of donor-acceptor motion in a protein environment.

    PubMed

    Benabbas, Abdelkrim; Salna, Bridget; Sage, J Timothy; Champion, Paul M

    2015-03-21

    Analytical models describing the temperature dependence of the deep tunneling rate, useful for proton, hydrogen, or hydride transfer in proteins, are developed and compared. Electronically adiabatic and non-adiabatic expressions are presented where the donor-acceptor (D-A) motion is treated either as a quantized vibration or as a classical "gating" distribution. We stress the importance of fitting experimental data on an absolute scale in the electronically adiabatic limit, which normally applies to these reactions, and find that vibrationally enhanced deep tunneling takes place on sub-ns timescales at room temperature for typical H-bonding distances. As noted previously, a small room temperature kinetic isotope effect (KIE) does not eliminate deep tunneling as a major transport channel. The quantum approach focuses on the vibrational sub-space composed of the D-A and hydrogen atom motions, where hydrogen bonding and protein restoring forces quantize the D-A vibration. A Duschinsky rotation is mandated between the normal modes of the reactant and product states and the rotation angle depends on the tunneling particle mass. This tunnel-mass dependent rotation contributes substantially to the KIE and its temperature dependence. The effect of the Duschinsky rotation is solved exactly to find the rate in the electronically non-adiabatic limit and compared to the Born-Oppenheimer (B-O) approximation approach. The B-O approximation is employed to find the rate in the electronically adiabatic limit, where we explore both harmonic and quartic double-well potentials for the hydrogen atom bound states. Both the electronically adiabatic and non-adiabatic rates are found to diverge at high temperature unless the proton coupling includes the often neglected quadratic term in the D-A displacement from equilibrium. A new expression is presented for the electronically adiabatic tunnel rate in the classical limit for D-A motion that should be useful to experimentalists working near

  9. Deep proton tunneling in the electronically adiabatic and non-adiabatic limits: Comparison of the quantum and classical treatment of donor-acceptor motion in a protein environment

    SciTech Connect

    Benabbas, Abdelkrim; Salna, Bridget; Sage, J. Timothy; Champion, Paul M.

    2015-03-21

    Analytical models describing the temperature dependence of the deep tunneling rate, useful for proton, hydrogen, or hydride transfer in proteins, are developed and compared. Electronically adiabatic and non-adiabatic expressions are presented where the donor-acceptor (D-A) motion is treated either as a quantized vibration or as a classical “gating” distribution. We stress the importance of fitting experimental data on an absolute scale in the electronically adiabatic limit, which normally applies to these reactions, and find that vibrationally enhanced deep tunneling takes place on sub-ns timescales at room temperature for typical H-bonding distances. As noted previously, a small room temperature kinetic isotope effect (KIE) does not eliminate deep tunneling as a major transport channel. The quantum approach focuses on the vibrational sub-space composed of the D-A and hydrogen atom motions, where hydrogen bonding and protein restoring forces quantize the D-A vibration. A Duschinsky rotation is mandated between the normal modes of the reactant and product states and the rotation angle depends on the tunneling particle mass. This tunnel-mass dependent rotation contributes substantially to the KIE and its temperature dependence. The effect of the Duschinsky rotation is solved exactly to find the rate in the electronically non-adiabatic limit and compared to the Born-Oppenheimer (B-O) approximation approach. The B-O approximation is employed to find the rate in the electronically adiabatic limit, where we explore both harmonic and quartic double-well potentials for the hydrogen atom bound states. Both the electronically adiabatic and non-adiabatic rates are found to diverge at high temperature unless the proton coupling includes the often neglected quadratic term in the D-A displacement from equilibrium. A new expression is presented for the electronically adiabatic tunnel rate in the classical limit for D-A motion that should be useful to experimentalists working

  10. Deep proton tunneling in the electronically adiabatic and non-adiabatic limits: comparison of the quantum and classical treatment of donor-acceptor motion in a protein environment.

    PubMed

    Benabbas, Abdelkrim; Salna, Bridget; Sage, J Timothy; Champion, Paul M

    2015-03-21

    Analytical models describing the temperature dependence of the deep tunneling rate, useful for proton, hydrogen, or hydride transfer in proteins, are developed and compared. Electronically adiabatic and non-adiabatic expressions are presented where the donor-acceptor (D-A) motion is treated either as a quantized vibration or as a classical "gating" distribution. We stress the importance of fitting experimental data on an absolute scale in the electronically adiabatic limit, which normally applies to these reactions, and find that vibrationally enhanced deep tunneling takes place on sub-ns timescales at room temperature for typical H-bonding distances. As noted previously, a small room temperature kinetic isotope effect (KIE) does not eliminate deep tunneling as a major transport channel. The quantum approach focuses on the vibrational sub-space composed of the D-A and hydrogen atom motions, where hydrogen bonding and protein restoring forces quantize the D-A vibration. A Duschinsky rotation is mandated between the normal modes of the reactant and product states and the rotation angle depends on the tunneling particle mass. This tunnel-mass dependent rotation contributes substantially to the KIE and its temperature dependence. The effect of the Duschinsky rotation is solved exactly to find the rate in the electronically non-adiabatic limit and compared to the Born-Oppenheimer (B-O) approximation approach. The B-O approximation is employed to find the rate in the electronically adiabatic limit, where we explore both harmonic and quartic double-well potentials for the hydrogen atom bound states. Both the electronically adiabatic and non-adiabatic rates are found to diverge at high temperature unless the proton coupling includes the often neglected quadratic term in the D-A displacement from equilibrium. A new expression is presented for the electronically adiabatic tunnel rate in the classical limit for D-A motion that should be useful to experimentalists working near

  11. Adiabatic Floquet model for the optical response in femtosecond filaments

    NASA Astrophysics Data System (ADS)

    Hofmann, Michael; Brée, Carsten

    2016-10-01

    The standard model of femtosecond filamentation is based on phenomenological assumptions which suggest that the ionization-induced carriers can be treated as a homogeneous, uncorrelated plasma according to the Drude model, while the nonlinear response of the bound carriers is responsible for the all-optical Kerr effect. Here, we demonstrate that the additional plasma generated at a multiphoton resonance dominates the saturation of the nonlinear refractive index. Since resonances are not captured by the standard model, we propose a modification of the latter in which ionization enhancements can be accounted for by an ionization rate obtained from non-Hermitian Floquet theory. In the adiabatic regime of long pulse envelopes, this augmented standard model is in excellent agreement with direct quantum mechanical simulations. Since our proposal maintains the structure of the standard model, it can be easily incorporated into existing codes for the numerical simulation of femtosecond filaments.

  12. Conditions for super-adiabatic droplet growth after entrainment mixing

    NASA Astrophysics Data System (ADS)

    Yang, Fan; Shaw, Raymond; Xue, Huiwen

    2016-07-01

    Cloud droplet response to entrainment and mixing between a cloud and its environment is considered, accounting for subsequent droplet growth during adiabatic ascent following a mixing event. The vertical profile for liquid water mixing ratio after a mixing event is derived analytically, allowing the reduction to be predicted from the mixing fraction and from the temperature and humidity for both the cloud and environment. It is derived for the limit of homogeneous mixing. The expression leads to a critical height above the mixing level: at the critical height the cloud droplet radius is the same for both mixed and unmixed parcels, and the critical height is independent of the updraft velocity and mixing fraction. Cloud droplets in a mixed parcel are larger than in an unmixed parcel above the critical height, which we refer to as the "super-adiabatic" growth region. Analytical results are confirmed with a bin microphysics cloud model. Using the model, we explore the effects of updraft velocity, aerosol source in the environmental air, and polydisperse cloud droplets. Results show that the mixed parcel is more likely to reach the super-adiabatic growth region when the environmental air is humid and clean. It is also confirmed that the analytical predictions are matched by the volume-mean cloud droplet radius for polydisperse size distributions. The findings have implications for the origin of large cloud droplets that may contribute to onset of collision-coalescence in warm clouds.

  13. Non-adiabatic pulsations in %delta; Scuti stars

    NASA Astrophysics Data System (ADS)

    Moya, A.; Garrido, R.; Dupret, M. A.

    2004-01-01

    For δ Scuti stars, phase differences and amplitude ratios between the relative effective temperature variation and the relative radial displacement can be derived from multicolor photometric observations. The same quantities can be also calculated from theoretical non-adiabatic pulsation models. We present here these theoretical results, which indicate that non-adiabatic quantities depend on the mixing length parameter α used to treat the convection in the standard Mixing Length Theory (MLT). This dependence can be used to test and to constrain, through multicolor observations, the way MLT describes convection in the outermost layers of the star. We will use the equilibrium models provided by the CESAM evolutionary code. The pulsational observables are calculated by using a non-adiabatic pulsation code developed by R. Garridon and A. Moya. In the evolutionary and pulsation codes, a complete reconstruction of the non-grey atmosphere (Kurucz models) is included. The interaction between pulsation and atmosphere, as described by Dupret et al. (2002), is also included in the code.

  14. Graph isomorphism and adiabatic quantum computing

    NASA Astrophysics Data System (ADS)

    Gaitan, Frank; Clark, Lane

    2014-02-01

    In the graph isomorphism (GI) problem two N-vertex graphs G and G' are given and the task is to determine whether there exists a permutation of the vertices of G that preserves adjacency and transforms G →G'. If yes, then G and G' are said to be isomorphic; otherwise they are nonisomorphic. The GI problem is an important problem in computer science and is thought to be of comparable difficulty to integer factorization. In this paper we present a quantum algorithm that solves arbitrary instances of GI and which also provides an approach to determining all automorphisms of a given graph. We show how the GI problem can be converted to a combinatorial optimization problem that can be solved using adiabatic quantum evolution. We numerically simulate the algorithm's quantum dynamics and show that it correctly (i) distinguishes nonisomorphic graphs; (ii) recognizes isomorphic graphs and determines the permutation(s) that connect them; and (iii) finds the automorphism group of a given graph G. We then discuss the GI quantum algorithm's experimental implementation, and close by showing how it can be leveraged to give a quantum algorithm that solves arbitrary instances of the NP-complete subgraph isomorphism problem. The computational complexity of an adiabatic quantum algorithm is largely determined by the minimum energy gap Δ (N) separating the ground and first-excited states in the limit of large problem size N ≫1. Calculating Δ (N) in this limit is a fundamental open problem in adiabatic quantum computing, and so it is not possible to determine the computational complexity of adiabatic quantum algorithms in general, nor consequently, of the specific adiabatic quantum algorithms presented here. Adiabatic quantum computing has been shown to be equivalent to the circuit model of quantum computing, and so development of adiabatic quantum algorithms continues to be of great interest.

  15. Non-adiabatic effect in quantum pumping for a spin-boson system

    NASA Astrophysics Data System (ADS)

    Watanabe, Kota L.; Hayakawa, Hisao

    2014-11-01

    We clarify the role of non-adiabatic effects in quantum pumping for a spin-boson system. When we sinusoidally control the temperatures of two reservoirs with π /2 phase difference, we find that the pumping current strongly depends on the initial condition, and thus, the current deviates from that predicted by the adiabatic treatment. We also analytically obtain the contribution of non-adiabatic effects in the pumping current proportional to Ω ^3, where Ω is the angular frequency of the temperature control. The validity of the analytic expression is verified by our numerical calculation. Moreover, we extend the steady heat fluctuation theorem to the case for slowly modulated temperatures and large transferred energies.

  16. Adiabatic cooling of the artificial Porcupine plasma jet

    NASA Astrophysics Data System (ADS)

    Ruizhin, Iu. Ia.; Treumann, R. A.; Bauer, O. H.; Moskalenko, A. M.

    1987-01-01

    Measurements of the plasma density obtained during the interaction of the artificial plasma jet, fired into the ionosphere with the body of the Porcupine main payload, have been analyzed for times when there was a well-developed wake effect. Using wake theory, the maximum temperature of the quasi-neutral xenon ion beam has been determined for an intermediate distance from the ion beam source when the beam has left the diamagnetic region but is still much denser than the ionospheric background plasma. The beam temperature is found to be about 4 times less than the temperature at injection. This observation is very well explained by adiabatic cooling of the beam during its initial diamagnetic and current-buildup phases at distances r smaller than 10 m. Outside this region, the beam conserves the temperature achieved. The observation proves that the artificial plasma jet passes through an initial gas-like diamagnetic phase restricted to the vicinity of the beam source, where it expands adiabatically. Partial cooling also takes place outside the diamagnetic region where the beam current still builds up. The observations also support a recently developed current-closure model of the quasi-neutral ion beam.

  17. Accurate adiabatic correction in the hydrogen molecule

    NASA Astrophysics Data System (ADS)

    Pachucki, Krzysztof; Komasa, Jacek

    2014-12-01

    A new formalism for the accurate treatment of adiabatic effects in the hydrogen molecule is presented, in which the electronic wave function is expanded in the James-Coolidge basis functions. Systematic increase in the size of the basis set permits estimation of the accuracy. Numerical results for the adiabatic correction to the Born-Oppenheimer interaction energy reveal a relative precision of 10-12 at an arbitrary internuclear distance. Such calculations have been performed for 88 internuclear distances in the range of 0 < R ⩽ 12 bohrs to construct the adiabatic correction potential and to solve the nuclear Schrödinger equation. Finally, the adiabatic correction to the dissociation energies of all rovibrational levels in H2, HD, HT, D2, DT, and T2 has been determined. For the ground state of H2 the estimated precision is 3 × 10-7 cm-1, which is almost three orders of magnitude higher than that of the best previous result. The achieved accuracy removes the adiabatic contribution from the overall error budget of the present day theoretical predictions for the rovibrational levels.

  18. Accurate adiabatic correction in the hydrogen molecule

    SciTech Connect

    Pachucki, Krzysztof; Komasa, Jacek

    2014-12-14

    A new formalism for the accurate treatment of adiabatic effects in the hydrogen molecule is presented, in which the electronic wave function is expanded in the James-Coolidge basis functions. Systematic increase in the size of the basis set permits estimation of the accuracy. Numerical results for the adiabatic correction to the Born-Oppenheimer interaction energy reveal a relative precision of 10{sup −12} at an arbitrary internuclear distance. Such calculations have been performed for 88 internuclear distances in the range of 0 < R ⩽ 12 bohrs to construct the adiabatic correction potential and to solve the nuclear Schrödinger equation. Finally, the adiabatic correction to the dissociation energies of all rovibrational levels in H{sub 2}, HD, HT, D{sub 2}, DT, and T{sub 2} has been determined. For the ground state of H{sub 2} the estimated precision is 3 × 10{sup −7} cm{sup −1}, which is almost three orders of magnitude higher than that of the best previous result. The achieved accuracy removes the adiabatic contribution from the overall error budget of the present day theoretical predictions for the rovibrational levels.

  19. Accurate adiabatic correction in the hydrogen molecule.

    PubMed

    Pachucki, Krzysztof; Komasa, Jacek

    2014-12-14

    A new formalism for the accurate treatment of adiabatic effects in the hydrogen molecule is presented, in which the electronic wave function is expanded in the James-Coolidge basis functions. Systematic increase in the size of the basis set permits estimation of the accuracy. Numerical results for the adiabatic correction to the Born-Oppenheimer interaction energy reveal a relative precision of 10(-12) at an arbitrary internuclear distance. Such calculations have been performed for 88 internuclear distances in the range of 0 < R ⩽ 12 bohrs to construct the adiabatic correction potential and to solve the nuclear Schrödinger equation. Finally, the adiabatic correction to the dissociation energies of all rovibrational levels in H2, HD, HT, D2, DT, and T2 has been determined. For the ground state of H2 the estimated precision is 3 × 10(-7) cm(-1), which is almost three orders of magnitude higher than that of the best previous result. The achieved accuracy removes the adiabatic contribution from the overall error budget of the present day theoretical predictions for the rovibrational levels. PMID:25494728

  20. Properties of a two stage adiabatic demagnetization refrigerator

    NASA Astrophysics Data System (ADS)

    Fukuda, H.; Ueda, S.; Arai, R.; Li, J.; Saito, A. T.; Nakagome, H.; Numazawa, T.

    2015-12-01

    Currently, many space missions using cryogenic temperatures are being planned. In particular, high resolution sensors such as Transition Edge Sensors need very low temperatures, below 100 mK. It is well known that the adiabatic demagnetization refrigerator (ADR) is one of most useful tools for producing ultra-low temperatures in space because it is gravity independent. We studied a continuous ADR system consisting of 4 stages and demonstrated it could provide continuous temperatures around 100 mK. However, there was some heat leakage from the power leads which resulted in reduced cooling power. Our efforts to upgrade our ADR system are presented. We show the effect of using the HTS power leads and discuss a cascaded Carnot cycle consisting of 2 ADR units.

  1. Adiabatic approximation for the density matrix

    NASA Astrophysics Data System (ADS)

    Band, Yehuda B.

    1992-05-01

    An adiabatic approximation for the Liouville density-matrix equation which includes decay terms is developed. The adiabatic approximation employs the eigenvectors of the non-normal Liouville operator. The approximation is valid when there exists a complete set of eigenvectors of the non-normal Liouville operator (i.e., the eigenvectors span the density-matrix space), the time rate of change of the Liouville operator is small, and an auxiliary matrix is nonsingular. Numerical examples are presented involving efficient population transfer in a molecule by stimulated Raman scattering, with the intermediate level of the molecule decaying on a time scale that is fast compared with the pulse durations of the pump and Stokes fields. The adiabatic density-matrix approximation can be simply used to determine the density matrix for atomic or molecular systems interacting with cw electromagnetic fields when spontaneous emission or other decay mechanisms prevail.

  2. Nonadiabatic exchange dynamics during adiabatic frequency sweeps

    NASA Astrophysics Data System (ADS)

    Barbara, Thomas M.

    2016-04-01

    A Bloch equation analysis that includes relaxation and exchange effects during an adiabatic frequency swept pulse is presented. For a large class of sweeps, relaxation can be incorporated using simple first order perturbation theory. For anisochronous exchange, new expressions are derived for exchange augmented rotating frame relaxation. For isochronous exchange between sites with distinct relaxation rate constants outside the extreme narrowing limit, simple criteria for adiabatic exchange are derived and demonstrate that frequency sweeps commonly in use may not be adiabatic with regard to exchange unless the exchange rates are much larger than the relaxation rates. Otherwise, accurate assessment of the sensitivity to exchange dynamics will require numerical integration of the rate equations. Examples of this situation are given for experimentally relevant parameters believed to hold for in-vivo tissue. These results are of significance in the study of exchange induced contrast in magnetic resonance imaging.

  3. Sliding Seal Materials for Adiabatic Engines, Phase 2

    NASA Technical Reports Server (NTRS)

    Lankford, J.; Wei, W.

    1986-01-01

    An essential task in the development of the heavy-duty adiabatic diesel engine is identification and improvements of reliable, low-friction piston seal materials. In the present study, the sliding friction coefficients and wear rates of promising carbide, oxide, and nitride materials were measured under temperature, environmental, velocity, and loading conditions that are representative of the adiabatic engine environment. In addition, silicon nitride and partially stabilized zirconia disks were ion implanted with TiNi, Ni, Co, and Cr, and subsequently run against carbide pins, with the objective of producing reduced friction via solid lubrication at elevated temperature. In order to provide guidance needed to improve materials for this application, the program stressed fundamental understanding of the mechanisms involved in friction and wear. Electron microscopy was used to elucidate the micromechanisms of wear following wear testing, and Auger electron spectroscopy was used to evaluate interface/environment interactions which seemed to be important in the friction and wear process. Unmodified ceramic sliding couples were characterized at all temperatures by friction coefficients of 0.24 and above. The coefficient at 800 C in an oxidizing environment was reduced to below 0.1, for certain material combinations, by the ion implanation of TiNi or Co. This beneficial effect was found to derive from lubricious Ti, Ni, and Co oxides.

  4. On adiabatic invariant in generalized Galileon theories

    SciTech Connect

    Ema, Yohei; Jinno, Ryusuke; Nakayama, Kazunori; Mukaida, Kyohei E-mail: jinno@hep-th.phys.s.u-tokyo.ac.jp E-mail: kazunori@hep-th.phys.s.u-tokyo.ac.jp

    2015-10-01

    We consider background dynamics of generalized Galileon theories in the context of inflation, where gravity and inflaton are non-minimally coupled to each other. In the inflaton oscillation regime, the Hubble parameter and energy density oscillate violently in many cases, in contrast to the Einstein gravity with minimally coupled inflaton. However, we find that there is an adiabatic invariant in the inflaton oscillation regime in any generalized Galileon theory. This adiabatic invariant is useful in estimating the expansion law of the universe and also the particle production rate due to the oscillation of the Hubble parameter.

  5. Spontaneous emission in stimulated Raman adiabatic passage

    SciTech Connect

    Ivanov, P. A.; Vitanov, N. V.; Bergmann, K.

    2005-11-15

    This work explores the effect of spontaneous emission on the population transfer efficiency in stimulated Raman adiabatic passage (STIRAP). The approach uses adiabatic elimination of weakly coupled density matrix elements in the Liouville equation, from which a very accurate analytic approximation is derived. The loss of population transfer efficiency is found to decrease exponentially with the factor {omega}{sub 0}{sup 2}/{gamma}, where {gamma} is the spontaneous emission rate and {omega}{sub 0} is the peak Rabi frequency. The transfer efficiency increases with the pulse delay and reaches a steady value. For large pulse delay and large spontaneous emission rate STIRAP degenerates into optical pumping.

  6. Adiabatic Hyperspherical Analysis of Realistic Nuclear Potentials

    NASA Astrophysics Data System (ADS)

    Daily, K. M.; Kievsky, Alejandro; Greene, Chris H.

    2015-12-01

    Using the hyperspherical adiabatic method with the realistic nuclear potentials Argonne V14, Argonne V18, and Argonne V18 with the Urbana IX three-body potential, we calculate the adiabatic potentials and the triton bound state energies. We find that a discrete variable representation with the slow variable discretization method along the hyperradial degree of freedom results in energies consistent with the literature. However, using a Laguerre basis results in missing energy, even when extrapolated to an infinite number of basis functions and channels. We do not include the isospin T = 3/2 contribution in our analysis.

  7. Complexity of the Quantum Adiabatic Algorithm

    NASA Technical Reports Server (NTRS)

    Hen, Itay

    2013-01-01

    The Quantum Adiabatic Algorithm (QAA) has been proposed as a mechanism for efficiently solving optimization problems on a quantum computer. Since adiabatic computation is analog in nature and does not require the design and use of quantum gates, it can be thought of as a simpler and perhaps more profound method for performing quantum computations that might also be easier to implement experimentally. While these features have generated substantial research in QAA, to date there is still a lack of solid evidence that the algorithm can outperform classical optimization algorithms.

  8. Influence of viscosity and the adiabatic index on planetary migration

    NASA Astrophysics Data System (ADS)

    Bitsch, B.; Boley, A.; Kley, W.

    2013-02-01

    Context. The strength and direction of migration of low mass embedded planets depends on the disk's thermodynamic state. It has been shown that in active disks, where the internal dissipation is balanced by radiative transport, migration can be directed outwards, a process which extends the lifetime of growing embryos. Very important parameters determining the structure of disks, and hence the direction of migration, are the viscosity and the adiabatic index. Aims: In this paper we investigate the influence of different viscosity prescriptions (α-type and constant) and adiabatic indices on disk structures. We then determine how this affects the migration rate of planets embedded in such disks. Methods: We perform three-dimensional numerical simulations of accretion disks with embedded planets. We use the explicit/implicit hydrodynamical code NIRVANA that includes full tensor viscosity and radiation transport in the flux-limited diffusion approximation, as well as a proper equation of state for molecular hydrogen. The migration of embedded 20 MEarth planets is studied. Results: Low-viscosity disks have cooler temperatures and the migration rates of embedded planets tend toward the isothermal limit. Hence, in these disks, planets migrate inwards even in the fully radiative case. The effect of outward migration can only be sustained if the viscosity in the disk is large. Overall, the differences between the treatments for the equation of state seem to play a more important role in disks with higher viscosity. A change in the adiabatic index and in the viscosity changes the zero-torque radius that separates inward from outward migration. Conclusions: For larger viscosities, temperatures in the disk become higher and the zero-torque radius moves to larger radii, allowing outward migration of a 20-MEarth planet to persist over an extended radial range. In combination with large disk masses, this may allow for an extended period of the outward migration of growing

  9. Towards fault tolerant adiabatic quantum computation.

    PubMed

    Lidar, Daniel A

    2008-04-25

    I show how to protect adiabatic quantum computation (AQC) against decoherence and certain control errors, using a hybrid methodology involving dynamical decoupling, subsystem and stabilizer codes, and energy gaps. Corresponding error bounds are derived. As an example, I show how to perform decoherence-protected AQC against local noise using at most two-body interactions.

  10. Dynamical aspects of an adiabatic piston.

    PubMed

    Munakata, T; Ogawa, H

    2001-09-01

    Dynamical aspects of an adiabatic piston are investigated, based on the mass ratio expansion of the master equation for the piston velocity distribution function. Simple theory for piston motion and relaxation of an ideal gas in a cylinder turns out to reproduce our numerical experiments quantitatively.

  11. Dynamical aspects of an adiabatic piston

    NASA Astrophysics Data System (ADS)

    Munakata, Toyonori; Ogawa, Hideki

    2001-09-01

    Dynamical aspects of an adiabatic piston are investigated, based on the mass ratio expansion of the master equation for the piston velocity distribution function. Simple theory for piston motion and relaxation of an ideal gas in a cylinder turns out to reproduce our numerical experiments quantitatively.

  12. Time dependence of adiabatic particle number

    NASA Astrophysics Data System (ADS)

    Dabrowski, Robert; Dunne, Gerald V.

    2016-09-01

    We consider quantum field theoretic systems subject to a time-dependent perturbation, and discuss the question of defining a time-dependent particle number not just at asymptotic early and late times, but also during the perturbation. Naïvely, this is not a well-defined notion for such a nonequilibrium process, as the particle number at intermediate times depends on a basis choice of reference states with respect to which particles and antiparticles are defined, even though the final late-time particle number is independent of this basis choice. The basis choice is associated with a particular truncation of the adiabatic expansion. The adiabatic expansion is divergent, and we show that if this divergent expansion is truncated at its optimal order, a universal time dependence is obtained, confirming a general result of Dingle and Berry. This optimally truncated particle number provides a clear picture of quantum interference effects for perturbations with nontrivial temporal substructure. We illustrate these results using several equivalent definitions of adiabatic particle number: the Bogoliubov, Riccati, spectral function and Schrödinger picture approaches. In each approach, the particle number may be expressed in terms of the tiny deviations between the exact and adiabatic solutions of the Ermakov-Milne equation for the associated time-dependent oscillators.

  13. Apparatus to Measure Adiabatic and Isothermal Processes.

    ERIC Educational Resources Information Center

    Lamb, D. W.; White, G. M.

    1996-01-01

    Describes a simple manual apparatus designed to serve as an effective demonstration of the differences between isothermal and adiabatic processes for the general or elementary physics student. Enables students to verify Boyle's law for slow processes and identify the departure from this law for rapid processes and can also be used to give a clear…

  14. Adiabatic Mass Parameters for Spontaneous Fission

    SciTech Connect

    Baran, A.; Sheikh, J. A.; Nazarewicz, Witold

    2009-01-01

    The collective mass tensor derived from the adiabatic time-dependent Hartree-Fock-Bogoliubov theory, perturbative cranking approximation, and the Gaussian overlap approximation to the generator-coordinate method is discussed. Illustrative calculations are carried out for ^{252}Fm using the nuclear density functional theory with Skyrme interaction SkM* and seniority pairing.

  15. Communication: Adiabatic and non-adiabatic electron-nuclear motion: Quantum and classical dynamics

    NASA Astrophysics Data System (ADS)

    Albert, Julian; Kaiser, Dustin; Engel, Volker

    2016-05-01

    Using a model for coupled electronic-nuclear motion we investigate the range from negligible to strong non-adiabatic coupling. In the adiabatic case, the quantum dynamics proceeds in a single electronic state, whereas for strong coupling a complete transition between two adiabatic electronic states takes place. It is shown that in all coupling regimes the short-time wave-packet dynamics can be described using ensembles of classical trajectories in the phase space spanned by electronic and nuclear degrees of freedom. We thus provide an example which documents that the quantum concept of non-adiabatic transitions is not necessarily needed if electronic and nuclear motion is treated on the same footing.

  16. Communication: Adiabatic and non-adiabatic electron-nuclear motion: Quantum and classical dynamics.

    PubMed

    Albert, Julian; Kaiser, Dustin; Engel, Volker

    2016-05-01

    Using a model for coupled electronic-nuclear motion we investigate the range from negligible to strong non-adiabatic coupling. In the adiabatic case, the quantum dynamics proceeds in a single electronic state, whereas for strong coupling a complete transition between two adiabatic electronic states takes place. It is shown that in all coupling regimes the short-time wave-packet dynamics can be described using ensembles of classical trajectories in the phase space spanned by electronic and nuclear degrees of freedom. We thus provide an example which documents that the quantum concept of non-adiabatic transitions is not necessarily needed if electronic and nuclear motion is treated on the same footing.

  17. The dynamic instability of adiabatic blast waves

    NASA Technical Reports Server (NTRS)

    Ryu, Dongsu; Vishniac, Ethan T.

    1991-01-01

    Adiabatic blastwaves, which have a total energy injected from the center E varies as t(sup q) and propagate through a preshock medium with a density rho(sub E) varies as r(sup -omega) are described by a family of similarity solutions. Previous work has shown that adiabatic blastwaves with increasing or constant postshock entropy behind the shock front are susceptible to an oscillatory instability, caused by the difference between the nature of the forces on the two sides of the dense shell behind the shock front. This instability sets in if the dense postshock layer is sufficiently thin. The stability of adiabatic blastwaves with a decreasing postshock entropy is considered. Such blastwaves, if they are decelerating, always have a region behind the shock front which is subject to convection. Some accelerating blastwaves also have such region, depending on the values of q, omega, and gamma where gamma is the adiabatic index. However, since the shock interface stabilizes dynamically induced perturbations, blastwaves become convectively unstable only if the convective zone is localized around the origin or a contact discontinuity far from the shock front. On the other hand, the contact discontinuity of accelerating blastwaves is subject to a strong Rayleigh-Taylor instability. The frequency spectra of the nonradial, normal modes of adiabatic blastwaves have been calculated. The results have been applied to the shocks propagating through supernovae envelopes. It is shown that the metal/He and He/H interfaces are strongly unstable against the Rayleigh-Taylor instability. This instability will induce mixing in supernovae envelopes. In addition the implications of this work for the evolution of planetary nebulae is discussed.

  18. Adiabatic burst evaporation from bicontinuous nanoporous membranes

    PubMed Central

    Ichilmann, Sachar; Rücker, Kerstin; Haase, Markus; Enke, Dirk

    2015-01-01

    Evaporation of volatile liquids from nanoporous media with bicontinuous morphology and pore diameters of a few 10 nm is an ubiquitous process. For example, such drying processes occur during syntheses of nanoporous materials by sol–gel chemistry or by spinodal decomposition in the presence of solvents as well as during solution impregnation of nanoporous hosts with functional guests. It is commonly assumed that drying is endothermic and driven by non-equilibrium partial pressures of the evaporating species in the gas phase. We show that nearly half of the liquid evaporates in an adiabatic mode involving burst-like liquid-to-gas conversions. During single adiabatic burst evaporation events liquid volumes of up to 107 μm3 are converted to gas. The adiabatic liquid-to-gas conversions occur if air invasion fronts get unstable because of the built-up of high capillary pressures. Adiabatic evaporation bursts propagate avalanche-like through the nanopore systems until the air invasion fronts have reached new stable configurations. Adiabatic cavitation bursts thus compete with Haines jumps involving air invasion front relaxation by local liquid flow without enhanced mass transport out of the nanoporous medium and prevail if the mean pore diameter is in the range of a few 10 nm. The results reported here may help optimize membrane preparation via solvent-based approaches, solution-loading of nanopore systems with guest materials as well as routine use of nanoporous membranes with bicontinuous morphology and may contribute to better understanding of adsorption/desorption processes in nanoporous media. PMID:25926406

  19. Bimolecular recombination reactions: K-adiabatic and K-active forms of the bimolecular master equations and analytic solutions

    NASA Astrophysics Data System (ADS)

    Ghaderi, Nima

    2016-03-01

    Expressions for a K-adiabatic master equation for a bimolecular recombination rate constant krec are derived for a bimolecular reaction forming a complex with a single well or complexes with multiple well, where K is the component of the total angular momentum along the axis of least moment of inertia of the recombination product. The K-active master equation is also considered. The exact analytic solutions, i.e., the K-adiabatic and K-active steady-state population distribution function of reactive complexes, g(EJK) and g(EJ), respectively, are derived for the K-adiabatic and K-active master equation cases using properties of inhomogeneous integral equations (Fredholm type). The solutions accommodate arbitrary intermolecular energy transfer models, e.g., the single exponential, double exponential, Gaussian, step-ladder, and near-singularity models. At the high pressure limit, the krec for both the K-adiabatic and K-active master equations reduce, respectively, to the K-adiabatic and K-active bimolecular Rice-Ramsperger-Kassel-Marcus theory (high pressure limit expressions). Ozone and its formation from O + O2 are known to exhibit an adiabatic K. The ratio of the K-adiabatic to the K-active recombination rate constants for ozone formation at the high pressure limit is calculated to be ˜0.9 at 300 K. Results on the temperature and pressure dependence of the recombination rate constants and populations of O3 will be presented elsewhere.

  20. Bimolecular recombination reactions: K-adiabatic and K-active forms of the bimolecular master equations and analytic solutions.

    PubMed

    Ghaderi, Nima

    2016-03-28

    Expressions for a K-adiabatic master equation for a bimolecular recombination rate constant krec are derived for a bimolecular reaction forming a complex with a single well or complexes with multiple well, where K is the component of the total angular momentum along the axis of least moment of inertia of the recombination product. The K-active master equation is also considered. The exact analytic solutions, i.e., the K-adiabatic and K-active steady-state population distribution function of reactive complexes, g(EJK) and g(EJ), respectively, are derived for the K-adiabatic and K-active master equation cases using properties of inhomogeneous integral equations (Fredholm type). The solutions accommodate arbitrary intermolecular energy transfer models, e.g., the single exponential, double exponential, Gaussian, step-ladder, and near-singularity models. At the high pressure limit, the krec for both the K-adiabatic and K-active master equations reduce, respectively, to the K-adiabatic and K-active bimolecular Rice-Ramsperger-Kassel-Marcus theory (high pressure limit expressions). Ozone and its formation from O + O2 are known to exhibit an adiabatic K. The ratio of the K-adiabatic to the K-active recombination rate constants for ozone formation at the high pressure limit is calculated to be ∼0.9 at 300 K. Results on the temperature and pressure dependence of the recombination rate constants and populations of O3 will be presented elsewhere. PMID:27036434

  1. The Adiabatic Expansion of Gases and the Determination of Heat Capacity Ratios: A Physical Chemistry Experiment.

    ERIC Educational Resources Information Center

    Moore, William M.

    1984-01-01

    Describes the procedures and equipment for an experiment on the adiabatic expansion of gases suitable for demonstration and discussion in the physical chemical laboratory. The expansion produced shows how the process can change temperature and still return to a different location on an isotherm. (JN)

  2. Kinetic Models for Adiabatic Reversible Expansion of a Monatomic Ideal Gas.

    ERIC Educational Resources Information Center

    Chang, On-Kok

    1983-01-01

    A fixed amount of an ideal gas is confined in an adiabatic cylinder and piston device. The relation between temperature and volume in initial/final phases can be derived from the first law of thermodynamics. However, the relation can also be derived based on kinetic models. Several of these models are discussed. (JN)

  3. Properties of an equilibrium hadron gas subjected to the adiabatic longitudinal expansion

    NASA Astrophysics Data System (ADS)

    Prorok, Dariusz; Turko, Ludwik

    1995-06-01

    We consider an ideal gas of massive hadrons in thermal and chemical equilibrium. The gas expands longitudinally in an adiabatic way. This evolution for a baryonless gas reduces to a hydrodynamic expansion. Cooling process is parametrized by the sound velocity. The sound velocity is temperature dependent and is strongly influenced by hadron mass spectrum.

  4. Non-equilibrium scale invariance and shortcuts to adiabaticity in a one-dimensional Bose gas

    PubMed Central

    Rohringer, W.; Fischer, D.; Steiner, F.; Mazets, I. E.; Schmiedmayer, J.; Trupke, M.

    2015-01-01

    We present experimental evidence for scale invariant behaviour of the excitation spectrum in phase-fluctuating quasi-1d Bose gases after a rapid change of the external trapping potential. Probing density correlations in free expansion, we find that the temperature of an initial thermal state scales with the spatial extension of the cloud as predicted by a model based on adiabatic rescaling of initial eigenmodes with conserved quasiparticle occupation numbers. Based on this result, we demonstrate that shortcuts to adiabaticity for the rapid expansion or compression of the gas do not induce additional heating. PMID:25867640

  5. Non-equilibrium scale invariance and shortcuts to adiabaticity in a one-dimensional Bose gas

    NASA Astrophysics Data System (ADS)

    Rohringer, W.; Fischer, D.; Steiner, F.; Mazets, I. E.; Schmiedmayer, J.; Trupke, M.

    2015-04-01

    We present experimental evidence for scale invariant behaviour of the excitation spectrum in phase-fluctuating quasi-1d Bose gases after a rapid change of the external trapping potential. Probing density correlations in free expansion, we find that the temperature of an initial thermal state scales with the spatial extension of the cloud as predicted by a model based on adiabatic rescaling of initial eigenmodes with conserved quasiparticle occupation numbers. Based on this result, we demonstrate that shortcuts to adiabaticity for the rapid expansion or compression of the gas do not induce additional heating.

  6. Non-equilibrium scale invariance and shortcuts to adiabaticity in a one-dimensional Bose gas.

    PubMed

    Rohringer, W; Fischer, D; Steiner, F; Mazets, I E; Schmiedmayer, J; Trupke, M

    2015-04-13

    We present experimental evidence for scale invariant behaviour of the excitation spectrum in phase-fluctuating quasi-1d Bose gases after a rapid change of the external trapping potential. Probing density correlations in free expansion, we find that the temperature of an initial thermal state scales with the spatial extension of the cloud as predicted by a model based on adiabatic rescaling of initial eigenmodes with conserved quasiparticle occupation numbers. Based on this result, we demonstrate that shortcuts to adiabaticity for the rapid expansion or compression of the gas do not induce additional heating.

  7. CORE SATURATION BLOCKING OSCILLATOR

    DOEpatents

    Spinrad, R.J.

    1961-10-17

    A blocking oscillator which relies on core saturation regulation to control the output pulse width is described. In this arrangement an external magnetic loop is provided in which a saturable portion forms the core of a feedback transformer used with the thermionic or semi-conductor active element. A first stationary magnetic loop establishes a level of flux through the saturation portion of the loop. A second adjustable magnet moves the flux level to select a saturation point giving the desired output pulse width. (AEC)

  8. Coherent tunnelling adiabatic passage in optical fibres using superimposed long-period fiber gratings

    NASA Astrophysics Data System (ADS)

    Thyagarajan, K.; Gupta, Ruchi

    2016-08-01

    In this paper, we present the optical analogue of stimulated Raman adiabatic passage (STIRAP) technique for three level atomic system in optical fibre geometry. Considering linearly polarized modes of an optical fibre, it is shown that using a pair of superimposed long-period gratings with peak refractive index perturbation varying spatially along the propagation axis, light can be transferred adiabatically from one core mode to another core mode via an intermediate cladding mode which itself does not get appreciably excited; thus acting like a dark mode. We compare the transmission spectrum of superimposed long-period gratings involved in adiabatic transfer with the transmission spectrum of conventional long-period grating. The analogue output is further analysed for its tolerance to the changes in the ambient refractive index, temperature and other fabrication parameters.

  9. Passive gas-gap heat switch for adiabatic demagnetization refrigerator

    NASA Technical Reports Server (NTRS)

    Shirron, Peter J. (Inventor); Di Pirro, Michael J. (Inventor)

    2005-01-01

    A passive gas-gap heat switch for use with a multi-stage continuous adiabatic demagnetization refrigerator (ADR). The passive gas-gap heat switch turns on automatically when the temperature of either side of the switch rises above a threshold value and turns off when the temperature on either side of the switch falls below this threshold value. One of the heat switches in this multistage process must be conductive in the 0.25? K to 0.3? K range. All of the heat switches must be capable of switching off in a short period of time (1-2 minutes), and when off to have a very low thermal conductance. This arrangement allows cyclic cooling cycles to be used without the need for separate heat switch controls.

  10. Adiabatic passage with spin locking in Tm3+:YAG

    NASA Astrophysics Data System (ADS)

    Pascual-Winter, M. F.; Tongning, R. C.; Lauro, R.; Louchet-Chauvet, A.; Chanelière, T.; Le Gouët, J.-L.

    2012-08-01

    In low-concentration Tm3+:YAG, we observe efficient adiabatic rapid passage (ARP) of thulium nuclear spin over flipping times much longer than T2. Efficient ARP with long flipping time has been observed in monoatomic solids for decades and has been analyzed in terms of spin temperature and of the thermodynamic equilibrium of a coupled spin ensemble. In low-concentration impurity-doped crystals the spin temperature concept may be questioned. A single spin model should be preferred since the impurity ions are weakly coupled together but interact with the numerous off-resonant matrix ions that originate the spin-spin relaxation. The experiment takes place in the context of quantum information investigation, involving impurity-doped crystals, spin hyperpolarization by optical pumping, and optical detection of the spin evolution.

  11. Non-adiabatic perturbations in multi-component perfect fluids

    SciTech Connect

    Koshelev, N.A.

    2011-04-01

    The evolution of non-adiabatic perturbations in models with multiple coupled perfect fluids with non-adiabatic sound speed is considered. Instead of splitting the entropy perturbation into relative and intrinsic parts, we introduce a set of symmetric quantities, which also govern the non-adiabatic pressure perturbation in models with energy transfer. We write the gauge invariant equations for the variables that determine on a large scale the non-adiabatic pressure perturbation and the rate of changes of the comoving curvature perturbation. The analysis of evolution of the non-adiabatic pressure perturbation has been made for several particular models.

  12. Saturation curve of SiO{sub 2} component in rutile-type GeO{sub 2}: A recoverable high-temperature pressure standard from 3 GPa to 10 GPa

    SciTech Connect

    Leinenweber, Kurt; Gullikson, Amber L.; Stoyanov, Emil; Malik, Abds-Sami

    2015-09-15

    The accuracy and precision of pressure measurements and the pursuit of reliable and readily available pressure scales at simultaneous high temperatures and pressures are still topics in development in high pressure research despite many years of work. In situ pressure scales based on x-ray diffraction are widely used but require x-ray access, which is lacking outside of x-ray beam lines. Other methods such as fixed points require several experiments to bracket a pressure calibration point. In this study, a recoverable high-temperature pressure gauge for pressures ranging from 3 GPa to 10 GPa is presented. The gauge is based on the pressure-dependent solubility of an SiO{sub 2} component in the rutile-structured phase of GeO{sub 2} (argutite), and is valid when the argutite solid solution coexists with coesite. The solid solution varies strongly in composition, mainly in pressure but also somewhat in temperature, and the compositional variations are easily detected by x-ray diffraction of the recovered products because of significant changes in the lattice parameters. The solid solution is measured here on two isotherms, one at 1200 °C and the other at 1500 °C, and is developed as a pressure gauge by calibrating it against three fixed points for each temperature and against the lattice parameter of MgO measured in situ at a total of three additional points. A somewhat detailed thermodynamic analysis is then presented that allows the pressure gauge to be used at other temperatures. This provides a way to accurately and reproducibly evaluate the pressure in high pressure experiments and applications in this pressure-temperature range, and could potentially be used as a benchmark to compare various other pressure scales under high temperature conditions. - Graphical abstract: The saturation curve of SiO{sub 2} in TiO{sub 2} shows a strong pressure dependence and a strong dependence of unit cell volume on composition. This provides an opportunity to use this

  13. Utilizing Temperature and Resistivity Data as a Way to Characterize Water and Solute Movement and Groundwater-Surface Water Interaction in Variably Saturated Porous Media

    NASA Astrophysics Data System (ADS)

    Scotch, C.; Murgulet, D.; Hay, R.

    2012-12-01

    This study utilizes a multidisciplinary approach to better analyze the extent to which groundwater and surface water interact in the Oso Creek water shed of South Texas using temperature data, electrical resistivity and numerical modeling methods. The three primary objectives of this study are to: (1) identify primary areas of streambed groundwater-surface water interaction using temperature time series and resistivity soundings; (2) improve understanding of solute flow and groundwater, surface water, and sediment interaction in a semiarid, urban coastal area; (3) improve our understanding of groundwater contribution to contaminant transport and discharge to the bays and estuaries and ultimately the Gulf of Mexico. Temperature data was acquired over a one year period, using temperature loggers, from June 11, 2009 to May 18, 2010 at 15-minute intervals from 17 monitoring sites along Oso Creek and its tributaries. Each monitoring site consisted of 4 temperature loggers equally vertically spaced from the stream surface down to a depth of one meter. Furthermore, groundwater temperatures and water levels were collected from wells adjacent to the temperature monitoring sites. In order to fulfill the objectives of this study, existing hydrogeologic, stratigraphic, and other ancillary data are being integrated into a finite difference model developed using the USGS VS2DT software for the Oso Creek Watershed. The model will be calibrated using existing temperature and water level data and a resistivity component will also be added to assure accuracy of the model and temperature data by helping to identify varying lithologies and water conductivities. Compiling a time-series of temperature data and incorporating available hydrostratigraphic, geomorphologic and water level data will enable the development of a comprehensive database. This database is necessary to develop the detailed flow model that will enable an understanding of the extent of groundwater surface water

  14. Sulfur Saturation Limits in Silicate Melts and their Implications for Core Formation Scenarios for Terrestrial Planets

    NASA Technical Reports Server (NTRS)

    Holzheid, Astrid; Grove, Timothy L.

    2002-01-01

    This study explores the controls of temperature, pressure, and silicate melt composition on S solubility in silicate liquids. The solubility of S in FeO-containing silicate melts in equilibrium with metal sulfide increases significantly with increasing temperature but decreases with increasing pressure. The silicate melt structure also exercises a control on S solubility. Increasing the degree of polymerization of the silicate melt structure lowers the S solubility in the silicate liquid. The new set of experimental data is used to expand the model of Mavrogenes and O'Neill(1999) for S solubility in silicate liquids by incorporating the influence of the silicate melt structure. The expected S solubility in the ascending magma is calculated using the expanded model. Because the negative pressure dependence of S solubility is more influential than the positive temperature dependence, decompression and adiabatic ascent of a formerly S-saturated silicate magma will lead to S undersaturation. A primitive magma that is S-saturated in its source region will, therefore, become S-undersaturated as it ascends to shallower depth. In order to precipitate magmatic sulfides, the magma must first cool and undergo fractional crystallization to reach S saturation. The S content in a metallic liquid that is in equilibrium with a magma ocean that contains approx. 200 ppm S (i.e., Earth's bulk mantle S content) ranges from 5.5 to 12 wt% S. This range of S values encompasses the amount of S (9 to 12 wt%) that would be present in the outer core if S is the light element. Thus, the Earth's proto-mantle could be in equilibrium (in terms of the preserved S abundance) with a core-forming metallic phase.

  15. Decoherence and adiabatic transport in semiconductor quantum dots

    NASA Astrophysics Data System (ADS)

    Switkes, Michael

    2000-10-01

    I present research on ballistic electron transport in lateral GaAs/AlGaAs quantum dots connected to the environment with leads supporting one or more fully transmitting quantum modes. The first part of this dissertation examines electron the phenomena which mediate the transition from quantum mechanical to classical behavior in these quantum dots. Measurements of electron phase coherence time based on the magnitude of weak localization correction are presented as a function both of temperature and of applied bias. The coherence time is found to depend on temperature approximately as a sum of two power laws, tauφ ≈ AT-1 + BT-2, in agreement with the prediction for diffusive two dimensional systems but not with predictions for closed quantum dots or ballistic 2D systems. The effects of a large applied bias can be described with an elevated effective electron temperature calculated from the balance of Joule heating and cooling by Wiedemann-Franz out diffusion of hot electrons. The limits this imposes for quantum dot based technologies are examined through the detailed analysis of a quantum dot magnetometer. The second part of the work presented here focuses on a novel form of electron transport, adiabatic quantum electron pumping, in which a current is driven by cyclic changes in the wave function of a mesoscopic system rather than by an externally imposed bias. After a brief review of other mechanisms which produce a dc current from an ac excitation, measurements of adiabatic pumping are presented. The pumped current (or voltage) is sinusoidal in the phase difference between the two ac voltages deforming the dot potential and fluctuates in both magnitude and direction with small changes in external parameters such as magnetic field. Dependencies of pumping on the strength of the deformations, temperature, and breaking of time-reversal symmetry are also investigated.

  16. Adiabatic fast passage application in solid state NMR study of cross relaxation and molecular dynamics in heteronuclear systems.

    PubMed

    Baranowski, M; Woźniak-Braszak, A; Jurga, K

    2016-01-01

    The paper presents the benefits of using fast adiabatic passage for the study of molecular dynamics in the solid state heteronuclear systems in the laboratory frame. A homemade pulse spectrometer operating at the frequency of 30.2MHz and 28.411MHz for protons and fluorines, respectively, has been enhanced with microcontroller direct digital synthesizer DDS controller [1-4]. This work briefly describes how to construct a low-cost and easy-to-assemble adiabatic extension set for homemade and commercial spectrometers based on recently very popular Arduino shields. The described set was designed for fast adiabatic generation. Timing and synchronization problems are discussed. The cross-relaxation experiments with different initial states of the two spin systems have been performed. Contrary to our previous work [5] where the steady-state NOE experiments were conducted now proton spins (1)H are polarized in the magnetic field B0 while fluorine spins (19)F are perturbed by selective saturation for a short time and then the system is allowed to evolve for a period in the absence of a saturating field. The adiabatic passage application leads to a reversal of magnetization of fluorine spins and increases the amplitude of the signal. PMID:26705906

  17. Adiabatic fast passage application in solid state NMR study of cross relaxation and molecular dynamics in heteronuclear systems

    NASA Astrophysics Data System (ADS)

    Baranowski, M.; Woźniak-Braszak, A.; Jurga, K.

    2016-01-01

    The paper presents the benefits of using fast adiabatic passage for the study of molecular dynamics in the solid state heteronuclear systems in the laboratory frame. A homemade pulse spectrometer operating at the frequency of 30.2 MHz and 28.411 MHz for protons and fluorines, respectively, has been enhanced with microcontroller direct digital synthesizer DDS controller [1-4]. This work briefly describes how to construct a low-cost and easy-to-assemble adiabatic extension set for homemade and commercial spectrometers based on recently very popular Arduino shields. The described set was designed for fast adiabatic generation. Timing and synchronization problems are discussed. The cross-relaxation experiments with different initial states of the two spin systems have been performed. Contrary to our previous work [5] where the steady-state NOE experiments were conducted now proton spins 1H are polarized in the magnetic field B0 while fluorine spins 19F are perturbed by selective saturation for a short time and then the system is allowed to evolve for a period in the absence of a saturating field. The adiabatic passage application leads to a reversal of magnetization of fluorine spins and increases the amplitude of the signal.

  18. Adiabatic fast passage application in solid state NMR study of cross relaxation and molecular dynamics in heteronuclear systems.

    PubMed

    Baranowski, M; Woźniak-Braszak, A; Jurga, K

    2016-01-01

    The paper presents the benefits of using fast adiabatic passage for the study of molecular dynamics in the solid state heteronuclear systems in the laboratory frame. A homemade pulse spectrometer operating at the frequency of 30.2MHz and 28.411MHz for protons and fluorines, respectively, has been enhanced with microcontroller direct digital synthesizer DDS controller [1-4]. This work briefly describes how to construct a low-cost and easy-to-assemble adiabatic extension set for homemade and commercial spectrometers based on recently very popular Arduino shields. The described set was designed for fast adiabatic generation. Timing and synchronization problems are discussed. The cross-relaxation experiments with different initial states of the two spin systems have been performed. Contrary to our previous work [5] where the steady-state NOE experiments were conducted now proton spins (1)H are polarized in the magnetic field B0 while fluorine spins (19)F are perturbed by selective saturation for a short time and then the system is allowed to evolve for a period in the absence of a saturating field. The adiabatic passage application leads to a reversal of magnetization of fluorine spins and increases the amplitude of the signal.

  19. Adiabatic quantum simulation of quantum chemistry.

    PubMed

    Babbush, Ryan; Love, Peter J; Aspuru-Guzik, Alán

    2014-10-13

    We show how to apply the quantum adiabatic algorithm directly to the quantum computation of molecular properties. We describe a procedure to map electronic structure Hamiltonians to 2-body qubit Hamiltonians with a small set of physically realizable couplings. By combining the Bravyi-Kitaev construction to map fermions to qubits with perturbative gadgets to reduce the Hamiltonian to 2-body, we obtain precision requirements on the coupling strengths and a number of ancilla qubits that scale polynomially in the problem size. Hence our mapping is efficient. The required set of controllable interactions includes only two types of interaction beyond the Ising interactions required to apply the quantum adiabatic algorithm to combinatorial optimization problems. Our mapping may also be of interest to chemists directly as it defines a dictionary from electronic structure to spin Hamiltonians with physical interactions.

  20. Quantum adiabatic evolution with energy degeneracy levels

    NASA Astrophysics Data System (ADS)

    Zhang, Qi

    2016-01-01

    A classical-kind phase-space formalism is developed to address the tiny intrinsic dynamical deviation from what is predicted by Wilczek-Zee theorem during quantum adiabatic evolution on degeneracy levels. In this formalism, the Hilbert space and the aggregate of degenerate eigenstates become the classical-kind phase space and a high-dimensional subspace in the phase space, respectively. Compared with the previous analogous study by a different method, the current result is qualitatively different in that the first-order deviation derived here is always perpendicular to the degeneracy subspace. A tripod-scheme Hamiltonian with two degenerate dark states is employed to illustrate the adiabatic deviation with degeneracy levels.

  1. Adiabatic quantum optimization for associative memory recall

    SciTech Connect

    Seddiqi, Hadayat; Humble, Travis S.

    2014-12-22

    Hopfield networks are a variant of associative memory that recall patterns stored in the couplings of an Ising model. Stored memories are conventionally accessed as fixed points in the network dynamics that correspond to energetic minima of the spin state. We show that memories stored in a Hopfield network may also be recalled by energy minimization using adiabatic quantum optimization (AQO). Numerical simulations of the underlying quantum dynamics allow us to quantify AQO recall accuracy with respect to the number of stored memories and noise in the input key. We investigate AQO performance with respect to how memories are stored in the Ising model according to different learning rules. Our results demonstrate that AQO recall accuracy varies strongly with learning rule, a behavior that is attributed to differences in energy landscapes. Consequently, learning rules offer a family of methods for programming adiabatic quantum optimization that we expect to be useful for characterizing AQO performance.

  2. Adiabatic quantum optimization for associative memory recall

    DOE PAGES

    Seddiqi, Hadayat; Humble, Travis S.

    2014-12-22

    Hopfield networks are a variant of associative memory that recall patterns stored in the couplings of an Ising model. Stored memories are conventionally accessed as fixed points in the network dynamics that correspond to energetic minima of the spin state. We show that memories stored in a Hopfield network may also be recalled by energy minimization using adiabatic quantum optimization (AQO). Numerical simulations of the underlying quantum dynamics allow us to quantify AQO recall accuracy with respect to the number of stored memories and noise in the input key. We investigate AQO performance with respect to how memories are storedmore » in the Ising model according to different learning rules. Our results demonstrate that AQO recall accuracy varies strongly with learning rule, a behavior that is attributed to differences in energy landscapes. Consequently, learning rules offer a family of methods for programming adiabatic quantum optimization that we expect to be useful for characterizing AQO performance.« less

  3. Trapped Ion Quantum Computation by Adiabatic Passage

    SciTech Connect

    Feng Xuni; Wu Chunfeng; Lai, C. H.; Oh, C. H.

    2008-11-07

    We propose a new universal quantum computation scheme for trapped ions in thermal motion via the technique of adiabatic passage, which incorporates the advantages of both the adiabatic passage and the model of trapped ions in thermal motion. Our scheme is immune from the decoherence due to spontaneous emission from excited states as the system in our scheme evolves along a dark state. In our scheme the vibrational degrees of freedom are not required to be cooled to their ground states because they are only virtually excited. It is shown that the fidelity of the resultant gate operation is still high even when the magnitude of the effective Rabi frequency moderately deviates from the desired value.

  4. Ramsey numbers and adiabatic quantum computing.

    PubMed

    Gaitan, Frank; Clark, Lane

    2012-01-01

    The graph-theoretic Ramsey numbers are notoriously difficult to calculate. In fact, for the two-color Ramsey numbers R(m,n) with m, n≥3, only nine are currently known. We present a quantum algorithm for the computation of the Ramsey numbers R(m,n). We show how the computation of R(m,n) can be mapped to a combinatorial optimization problem whose solution can be found using adiabatic quantum evolution. We numerically simulate this adiabatic quantum algorithm and show that it correctly determines the Ramsey numbers R(3,3) and R(2,s) for 5≤s≤7. We then discuss the algorithm's experimental implementation, and close by showing that Ramsey number computation belongs to the quantum complexity class quantum Merlin Arthur.

  5. Adiabatic Heating of Contracting Turbulent Fluids

    NASA Astrophysics Data System (ADS)

    Robertson, Brant; Goldreich, Peter

    2012-05-01

    Turbulence influences the behavior of many astrophysical systems, frequently by providing non-thermal pressure support through random bulk motions. Although turbulence is commonly studied in systems with constant volume and mean density, turbulent astrophysical gases often expand or contract under the influence of pressure or gravity. Here, we examine the behavior of turbulence in contracting volumes using idealized models of compressed gases. Employing numerical simulations and an analytical model, we identify a simple mechanism by which the turbulent motions of contracting gases "adiabatically heat," experiencing an increase in their random bulk velocities until the largest eddies in the gas circulate over a Hubble time of the contraction. Adiabatic heating provides a mechanism for sustaining turbulence in gases where no large-scale driving exists. We describe this mechanism in detail and discuss some potential applications to turbulence in astrophysical settings.

  6. ADIABATIC HEATING OF CONTRACTING TURBULENT FLUIDS

    SciTech Connect

    Robertson, Brant; Goldreich, Peter

    2012-05-10

    Turbulence influences the behavior of many astrophysical systems, frequently by providing non-thermal pressure support through random bulk motions. Although turbulence is commonly studied in systems with constant volume and mean density, turbulent astrophysical gases often expand or contract under the influence of pressure or gravity. Here, we examine the behavior of turbulence in contracting volumes using idealized models of compressed gases. Employing numerical simulations and an analytical model, we identify a simple mechanism by which the turbulent motions of contracting gases 'adiabatically heat', experiencing an increase in their random bulk velocities until the largest eddies in the gas circulate over a Hubble time of the contraction. Adiabatic heating provides a mechanism for sustaining turbulence in gases where no large-scale driving exists. We describe this mechanism in detail and discuss some potential applications to turbulence in astrophysical settings.

  7. Adiabatic Quantum Simulation of Quantum Chemistry

    NASA Astrophysics Data System (ADS)

    Babbush, Ryan; Love, Peter J.; Aspuru-Guzik, Alán

    2014-10-01

    We show how to apply the quantum adiabatic algorithm directly to the quantum computation of molecular properties. We describe a procedure to map electronic structure Hamiltonians to 2-body qubit Hamiltonians with a small set of physically realizable couplings. By combining the Bravyi-Kitaev construction to map fermions to qubits with perturbative gadgets to reduce the Hamiltonian to 2-body, we obtain precision requirements on the coupling strengths and a number of ancilla qubits that scale polynomially in the problem size. Hence our mapping is efficient. The required set of controllable interactions includes only two types of interaction beyond the Ising interactions required to apply the quantum adiabatic algorithm to combinatorial optimization problems. Our mapping may also be of interest to chemists directly as it defines a dictionary from electronic structure to spin Hamiltonians with physical interactions.

  8. Shortcuts to adiabaticity from linear response theory

    SciTech Connect

    Acconcia, Thiago V.; Bonança, Marcus V. S.; Deffner, Sebastian

    2015-10-23

    A shortcut to adiabaticity is a finite-time process that produces the same final state as would result from infinitely slow driving. We show that such shortcuts can be found for weak perturbations from linear response theory. Moreover, with the help of phenomenological response functions, a simple expression for the excess work is found—quantifying the nonequilibrium excitations. For two specific examples, i.e., the quantum parametric oscillator and the spin 1/2 in a time-dependent magnetic field, we show that finite-time zeros of the excess work indicate the existence of shortcuts. We finally propose a degenerate family of protocols, which facilitates shortcuts to adiabaticity for specific and very short driving times.

  9. Shortcuts to adiabaticity from linear response theory

    DOE PAGES

    Acconcia, Thiago V.; Bonança, Marcus V. S.; Deffner, Sebastian

    2015-10-23

    A shortcut to adiabaticity is a finite-time process that produces the same final state as would result from infinitely slow driving. We show that such shortcuts can be found for weak perturbations from linear response theory. Moreover, with the help of phenomenological response functions, a simple expression for the excess work is found—quantifying the nonequilibrium excitations. For two specific examples, i.e., the quantum parametric oscillator and the spin 1/2 in a time-dependent magnetic field, we show that finite-time zeros of the excess work indicate the existence of shortcuts. We finally propose a degenerate family of protocols, which facilitates shortcuts tomore » adiabaticity for specific and very short driving times.« less

  10. Adiabatic Processes Realized with a Trapped Brownian Particle

    NASA Astrophysics Data System (ADS)

    Martínez, Ignacio A.; Roldán, Édgar; Dinis, Luis; Petrov, Dmitri; Rica, Raúl A.

    2015-03-01

    The ability to implement adiabatic processes in the mesoscale is of key importance in the study of artificial or biological micro- and nanoengines. Microadiabatic processes have been elusive to experimental implementation due to the difficulty in isolating Brownian particles from their fluctuating environment. Here we report on the experimental realization of a microscopic quasistatic adiabatic process employing a trapped Brownian particle. We circumvent the complete isolation of the Brownian particle by designing a protocol where both characteristic volume and temperature of the system are changed in such a way that the entropy of the system is conserved along the process. We compare the protocols that follow from either the overdamped or underdamped descriptions, demonstrating that the latter is mandatory in order to obtain a vanishing average heat flux to the particle. We provide analytical expressions for the distributions of the fluctuating heat and entropy and verify them experimentally. Our protocols could serve to implement the first microscopic engine that is able to attain the fundamental limit for the efficiency set by Carnot.

  11. Conditions for super-adiabatic droplet growth after entrainment mixing

    DOE PAGES

    Yang, Fan; Shaw, Raymond; Xue, Huiwen

    2016-07-29

    Cloud droplet response to entrainment and mixing between a cloud and its environment is considered, accounting for subsequent droplet growth during adiabatic ascent following a mixing event. The vertical profile for liquid water mixing ratio after a mixing event is derived analytically, allowing the reduction to be predicted from the mixing fraction and from the temperature and humidity for both the cloud and environment. It is derived for the limit of homogeneous mixing. The expression leads to a critical height above the mixing level: at the critical height the cloud droplet radius is the same for both mixed and unmixedmore » parcels, and the critical height is independent of the updraft velocity and mixing fraction. Cloud droplets in a mixed parcel are larger than in an unmixed parcel above the critical height, which we refer to as the “super-adiabatic” growth region. Analytical results are confirmed with a bin microphysics cloud model. Using the model, we explore the effects of updraft velocity, aerosol source in the environmental air, and polydisperse cloud droplets. Results show that the mixed parcel is more likely to reach the super-adiabatic growth region when the environmental air is humid and clean. It is also confirmed that the analytical predictions are matched by the volume-mean cloud droplet radius for polydisperse size distributions. The findings have implications for the origin of large cloud droplets that may contribute to onset of collision–coalescence in warm clouds.« less

  12. Siphon flows in isolated magnetic flux tubes. II - Adiabatic flows

    NASA Technical Reports Server (NTRS)

    Montesinos, Benjamin; Thomas, John H.

    1989-01-01

    This paper extends the study of steady siphon flows in isolated magnetic flux tubes surrounded by field-free gas to the case of adiabatic flows. The basic equations governing steady adiabatic siphon flows in a thin, isolated magnetic flux tube are summarized, and qualitative features of adiabatic flows in elevated, arched flux tubes are discussed. The equations are then cast in nondimensional form and the results of numerical computations of adiabatic siphon flows in arched flux tubes are presented along with comparisons between isothermal and adiabatic flows. The effects of making the interior of the flux tube hotter or colder than the surrounding atmosphere at the upstream footpoint of the arch is considered. In this case, is it found that the adiabatic flows are qualitatively similar to the isothermal flows, with adiabatic cooling producing quantitative differences. Critical flows can produce a bulge point in the rising part of the arch and a concentration of magnetic flux above the bulge point.

  13. Siphon flows in isolated magnetic flux tubes. II. Adiabatic flows

    SciTech Connect

    Montesinos, B.; Thomas, J.H.

    1989-02-01

    This paper extends the study of steady siphon flows in isolated magnetic flux tubes surrounded by field-free gas to the case of adiabatic flows. The basic equations governing steady adiabatic siphon flows in a thin, isolated magnetic flux tube are summarized, and qualitative features of adiabatic flows in elevated, arched flux tubes are discussed. The equations are then cast in nondimensional form and the results of numerical computations of adiabatic siphon flows in arched flux tubes are presented along with comparisons between isothermal and adiabatic flows. The effects of making the interior of the flux tube hotter or colder than the surrounding atmosphere at the upstream footpoint of the arch is considered. In this case, is it found that the adiabatic flows are qualitatively similar to the isothermal flows, with adiabatic cooling producing quantitative differences. Critical flows can produce a bulge point in the rising part of the arch and a concentration of magnetic flux above the bulge point. 15 references.

  14. Growth kinetics of step edges on celestite (0 0 1) surfaces as a function of temperature, saturation state, ionic strength, and aqueous strontium:sulfate ratio: An in-situ atomic force microscopy study

    NASA Astrophysics Data System (ADS)

    Bracco, Jacquelyn N.; Gooijer, Yiscka; Higgins, Steven R.

    2016-02-01

    Step velocities on the celestite (0 0 1) surface have been measured as a function of temperature (23-45 °C), saturation state (S = 1.1-2.2), ionic strength (I = 0.01, 0.06, and 0.1 M), and aqueous strontium:sulfate ratio (r = 0.01-100) using atomic force microscopy (AFM). Celestite growth hillocks were flanked by [0 1 0]-aligned step edges, which are polar, and step edges vicinal to <1 2 0>, which are non-polar. [0 1 0] step velocities increased with temperature and saturation state, however step velocities did not vary significantly with ionic strength. Step velocities were non-linear with saturation state, suggesting a change in mechanism at high S as compared with low S. At constant S, the step velocities were maximized at r = 1 and decreased significantly at extreme r, demonstrating the governing role of solute stoichiometry. We successfully fit the step velocity data as a function of r using the Stack and Grantham (2010) nucleation and propagation model. Based on the results as a function of ionic strength and r, the mechanism at low S is likely ion-by-ion attachment to the step with an activation energy of 75 (±10) kJ mol-1. At high S the mechanism is a combination of the one at low S and possibly attachment of a neutral species such as an ion pair with an activation energy of 43 (±9) kJ mol-1.

  15. Growth kinetics of step edges on celestite (0 0 1) surfaces as a function of temperature, saturation state, ionic strength, and aqueous strontium:sulface ratio: An in-situ atomic force microscopy study

    SciTech Connect

    Bracco, Jacquelyn N.; Gooijer, Yiscka; Higgins, Steven R.

    2015-12-12

    Step velocities on the celestite (0 0 1) surface have been measured as a function of temperature (23–45 °C), saturation state (S = 1.1–2.2), ionic strength (I = 0.01, 0.06, and 0.1 M), and aqueous strontium:sulfate ratio (r = 0.01–100) using atomic force microscopy (AFM). Celestite growth hillocks were flanked by [0 1 0]-aligned step edges, which are polar, and step edges vicinal to <1 2 0>, which are non-polar. [0 1 0] step velocities increased with temperature and saturation state, however step velocities did not vary significantly with ionic strength. Step velocities were non-linear with saturation state, suggesting a change in mechanism at high S as compared with low S. At constant S, the step velocities were maximized at r = 1 and decreased significantly at extreme r, demonstrating the governing role of solute stoichiometry. We successfully fit the step velocity data as a function of r using the Stack and Grantham (2010) nucleation and propagation model. Based on the results as a function of ionic strength and r, the mechanism at low S is likely ion-by-ion attachment to the step with an activation energy of 75 (±10) kJ mol–1. In conclusion, at high S the mechanism is a combination of the one at low S and possibly attachment of a neutral species such as an ion pair with an activation energy of 43 (±9) kJ mol–1.

  16. Growth kinetics of step edges on celestite (0 0 1) surfaces as a function of temperature, saturation state, ionic strength, and aqueous strontium:sulface ratio: An in-situ atomic force microscopy study

    DOE PAGES

    Bracco, Jacquelyn N.; Gooijer, Yiscka; Higgins, Steven R.

    2015-12-12

    Step velocities on the celestite (0 0 1) surface have been measured as a function of temperature (23–45 °C), saturation state (S = 1.1–2.2), ionic strength (I = 0.01, 0.06, and 0.1 M), and aqueous strontium:sulfate ratio (r = 0.01–100) using atomic force microscopy (AFM). Celestite growth hillocks were flanked by [0 1 0]-aligned step edges, which are polar, and step edges vicinal to <1 2 0>, which are non-polar. [0 1 0] step velocities increased with temperature and saturation state, however step velocities did not vary significantly with ionic strength. Step velocities were non-linear with saturation state, suggesting amore » change in mechanism at high S as compared with low S. At constant S, the step velocities were maximized at r = 1 and decreased significantly at extreme r, demonstrating the governing role of solute stoichiometry. We successfully fit the step velocity data as a function of r using the Stack and Grantham (2010) nucleation and propagation model. Based on the results as a function of ionic strength and r, the mechanism at low S is likely ion-by-ion attachment to the step with an activation energy of 75 (±10) kJ mol–1. In conclusion, at high S the mechanism is a combination of the one at low S and possibly attachment of a neutral species such as an ion pair with an activation energy of 43 (±9) kJ mol–1.« less

  17. Computer Code For Turbocompounded Adiabatic Diesel Engine

    NASA Technical Reports Server (NTRS)

    Assanis, D. N.; Heywood, J. B.

    1988-01-01

    Computer simulation developed to study advantages of increased exhaust enthalpy in adiabatic turbocompounded diesel engine. Subsytems of conceptual engine include compressor, reciprocator, turbocharger turbine, compounded turbine, ducting, and heat exchangers. Focus of simulation of total system is to define transfers of mass and energy, including release and transfer of heat and transfer of work in each subsystem, and relationship among subsystems. Written in FORTRAN IV.

  18. Effect of Strain on Microstructure Evolution of 1Cr18Ni9Ti Stainless Steel During Adiabatic Shearing

    NASA Astrophysics Data System (ADS)

    Yang, Y.; Jiang, L. H.; Luo, S. H.; Hu, H. B.; Tang, T. G.; Zhang, Q. M.

    2016-01-01

    Dynamic shear test was conducted on the hat-shaped specimen of the thermo-mechanical-processed 1Cr18Ni9Ti stainless steel by using the split Hopkinson pressure bar at ambient temperature. The effect of the shear strain on the microstructure evolution was investigated during adiabatic shearing. The results revealed that the development of adiabatic shear localization went through three stages, including the incubation period, the development stage, and the maturity period. TEM observations showed that the grains in the shear region were elongated, and the elongated grains were gradually evolved into equiaxed nano-grains of 100 nm as shear strain increased. The rotational dynamic recrystallization kinetics calculation showed that subgrains had sufficient time to generate an equiaxed microcrystalline structure by rotation within the deformation time. Based on the observation of the evolution of dislocations and sub-grains in the adiabatic shear region, a model of the microstructure evolution was established during the adiabatic shearing.

  19. Random matrix model of adiabatic quantum computing

    SciTech Connect

    Mitchell, David R.; Adami, Christoph; Lue, Waynn; Williams, Colin P.

    2005-05-15

    We present an analysis of the quantum adiabatic algorithm for solving hard instances of 3-SAT (an NP-complete problem) in terms of random matrix theory (RMT). We determine the global regularity of the spectral fluctuations of the instantaneous Hamiltonians encountered during the interpolation between the starting Hamiltonians and the ones whose ground states encode the solutions to the computational problems of interest. At each interpolation point, we quantify the degree of regularity of the average spectral distribution via its Brody parameter, a measure that distinguishes regular (i.e., Poissonian) from chaotic (i.e., Wigner-type) distributions of normalized nearest-neighbor spacings. We find that for hard problem instances - i.e., those having a critical ratio of clauses to variables - the spectral fluctuations typically become irregular across a contiguous region of the interpolation parameter, while the spectrum is regular for easy instances. Within the hard region, RMT may be applied to obtain a mathematical model of the probability of avoided level crossings and concomitant failure rate of the adiabatic algorithm due to nonadiabatic Landau-Zener-type transitions. Our model predicts that if the interpolation is performed at a uniform rate, the average failure rate of the quantum adiabatic algorithm, when averaged over hard problem instances, scales exponentially with increasing problem size.

  20. Non-adiabatic dark fluid cosmology

    SciTech Connect

    Hipólito-Ricaldi, W.S.; Velten, H.E.S.; Zimdahl, W. E-mail: velten@cce.ufes.br

    2009-06-01

    We model the dark sector of the cosmic substratum by a viscous fluid with an equation of state p = −ζΘ, where Θ is the fluid-expansion scalar and ζ is the coefficient of bulk viscosity for which we assume a dependence ζ∝ρ{sup ν} on the energy density ρ. The homogeneous and isotropic background dynamics coincides with that of a generalized Chaplygin gas with equation of state p = −A/ρ{sup α}. The perturbation dynamics of the viscous model, however, is intrinsically non-adiabatic and qualitatively different from the Chaplygin-gas case. In particular, it avoids short-scale instabilities and/or oscillations which apparently have ruled out unified models of the Chaplygin-gas type. We calculate the matter power spectrum and demonstrate that the non-adiabatic model is compatible with the data from the 2dFGRS and the SDSS surveys. A χ{sup 2}-analysis shows, that for certain parameter combinations the viscous-dark-fluid (VDF) model is well competitive with the ΛCDM model. These results indicate that non-adiabatic unified models can be seen as potential contenders for a General-Relativity-based description of the cosmic substratum.

  1. Gluon saturation in a saturated environment

    SciTech Connect

    Kopeliovich, B. Z.; Potashnikova, I. K.; Schmidt, Ivan

    2011-07-15

    A bootstrap equation for self-quenched gluon shadowing leads to a reduced magnitude of broadening for partons propagating through a nucleus. Saturation of small-x gluons in a nucleus, which has the form of transverse momentum broadening of projectile gluons in pA collisions in the nuclear rest frame, leads to a modification of the parton distribution functions in the beam compared with pp collisions. In nucleus-nucleus collisions all participating nucleons acquire enhanced gluon density at small x, which boosts further the saturation scale. Solution of the reciprocity equations for central collisions of two heavy nuclei demonstrate a significant, up to several times, enhancement of Q{sub sA}{sup 2}, in AA compared with pA collisions.

  2. Investigations of the internal wave characteristics and saturation degree in the Earth's atmosphere by using radiosonde measurements of wind and temperature and their applications to the RO wave studies

    NASA Astrophysics Data System (ADS)

    Kirillovich, Ivan; Gubenko, Vladimir; Pavelyev, Alexander

    Internal gravity waves (IGWs) affect the structure and circulation of the Earth’s atmosphere by transporting energy and momentum upward from lower atmosphere. Observations of the temperature and wind velocity fluctuations in the middle atmosphere have shown that wave amplitudes grow with increasing altitude, however, no quickly enough in order to correspond to amplitude growth due to exponential decrease of density in the absence of energy dissipation. The theory of saturated IGWs explains such rate of the wave amplitude growth in the following way: any wave amplitude in excess of the threshold value will lead to instability and the production of turbulence that acts to prevent further growth of the wave amplitude. The mechanisms that contribute most to the dissipation and saturation of the dominant IGW motions in the atmosphere are thought to be the dynamical (shear) and convective instability. For high-frequency waves, the threshold amplitude required to achieve shear instability is virtually identical to that required for convective instability. But for low-frequency IGWs, the shear instability threshold falls well below that necessary for convective instability. The knowledge of actual and threshold wave amplitudes is important when the effect of IGWs on the background atmosphere is to be assessed. The internal wave saturation assumption plays the key role for radio occultation (RO) investigations of IGWs in planetary atmospheres [Gubenko et al., 2008, 2011, 2012], therefore a radiosonde study of wave saturation processes in the Earth’s atmosphere is actual task. The results of determination of the actual and threshold amplitudes, saturation degree and other characteristics for identified IGWs in the Earth’s atmosphere found from high-resolution radiosonde measurements SPARC (http://www.sparc.sunysb.edu/) of horizontal wind and temperature are presented. The usefulness of these observations in conjunction with RO studies of IGWs is discussed. The work was

  3. Phase relations and adiabats in boiling seafloor geothermal systems

    USGS Publications Warehouse

    Bischoff, J.L.; Pitzer, Kenneth S.

    1985-01-01

    Observations of large salinity variations and vent temperatures in the range of 380-400??C suggest that boiling or two-phase separation may be occurring in some seafloor geothermal systems. Consideration of flow rates and the relatively small differences in density between vapors and liquids at the supercritical pressures at depth in these systems suggests that boiling is occurring under closed-system conditions. Salinity and temperature of boiling vents can be used to estimate the pressure-temperature point in the subsurface at which liquid seawater first reached the two-phase boundary. Data are reviewed to construct phase diagrams of coexisting brines and vapors in the two-phase region at pressures corresponding to those of the seafloor geothermal systems. A method is developed for calculating the enthalpy and entropy of the coexisting mixtures, and results are used to construct adiabats from the seafloor to the P-T two-phase boundary. Results for seafloor vents discharging at 2300 m below sea level indicate that a 385??C vent is composed of a brine (7% NaCl equivalent) in equilibrium with a vapor (0.1% NaCl). Brine constitutes 45% by weight of the mixture, and the fluid first boiled at approximately 1 km below the seafloor at 415??C, 330 bar. A 400??C vent is primarily vapor (88 wt.%, 0.044% NaCl) with a small amount of brine (26% NaCl) and first boiled at 2.9 km below the seafloor at 500??C, 520 bar. These results show that adiabatic decompression in the two-phase region results in dramatic cooling of the fluid mixture when there is a large fraction of vapor. ?? 1985.

  4. Meteorology (Temperature)

    Atmospheric Science Data Center

    2014-09-25

    ... daily earth temperature minimum and maximum.   Frost Days (days) The number of days for which the temperature falls below 0 degrees Celsius.   Dew/Frost Point Temperature (° C) Temperature at which air is saturated ...

  5. Influence of Commercial Saturated Monoglyceride, Mono-/Diglycerides Mixtures, Vegetable Oil, Stirring Speed, and Temperature on the Physical Properties of Organogels

    PubMed Central

    Rocha-Amador, Omar Gerardo; Huang, Qingrong; Rocha-Guzman, Nuria Elizabeth; Moreno-Jimenez, Martha Rocio; Gonzalez-Laredo, Ruben F.

    2014-01-01

    The objective of this study was to evaluate the influence of gelator, vegetable oil, stirring speed, and temperature on the physical properties of obtained organogels. They were prepared under varying independent conditions and applying a fractional experimental design. From there a rheological characterization was developed. The physical characterization also included polarized light microscopy and calorimetric analysis. Once these data were obtained, X-Ray diffraction was applied to selected samples and a microstructure lattice was confirmed. Commonly, the only conditions that affect crystallization have been analyzed (temperature, solvent, gelator, and cooling rate). We found that stirring speed is the most important parameter in the organogel preparation. PMID:26904637

  6. Non-adiabatic effects in near-adiabatic mixed-field orientation and alignment

    NASA Astrophysics Data System (ADS)

    Maan, Anjali; Ahlawat, Dharamvir Singh; Prasad, Vinod

    2016-11-01

    We present a theoretical study of the impact of a pair of moderate electric fields tilted an angle with respect to one another on a molecule. As a prototype, we consider a molecule with large rotational constant (with corresponding small rotational period) and moderate dipole moment. Within rigid-rotor approximation, the time-dependent Schrodinger equation is solved using fourth-order Runge-Kutta method. We have analysed that lower rotational states are significantly influenced by variation in pulse durations, the tilt angle between the fields and also on the electric field strengths. We also suggest a control scheme of how the rotational dynamics, orientation and alignment of a molecule can be enhanced by a combination of near-adiabatic pulses in comparision to non-adiabatic or adiabatic pulses.

  7. High temperature refrigerator

    DOEpatents

    Steyert, Jr., William A.

    1978-01-01

    A high temperature magnetic refrigerator which uses a Stirling-like cycle in which rotating magnetic working material is heated in zero field and adiabatically magnetized, cooled in high field, then adiabatically demagnetized. During this cycle said working material is in heat exchange with a pumped fluid which absorbs heat from a low temperature heat source and deposits heat in a high temperature reservoir. The magnetic refrigeration cycle operates at an efficiency 70% of Carnot.

  8. Model of TPTC Stirling engine with adiabatic working spaces

    NASA Astrophysics Data System (ADS)

    Renfroe, D. A.; Counts, M.

    1988-10-01

    A Stirling engine incorporating a phase-changing component of the working fluid has been modeled with the assumption that the compression and expansion space are adiabatic, and that the heat exchanger consists of a cooler, regenerator, and heater of finite size where the fluid follows an idealized temperature profile. Differential equations for the rate of change of mass in any cell and pressure over the entire engine were derived from the energy, continuity, state equations, and Dalton's law. From the simultaneous solution of these equations, all of the information necessary for calculation of power output and efficiency were obtained. Comparison of the results from this model with previous studies shows that the advantage of adding a phase-changing component to the working fluid may have been overstated.

  9. Model of TPTC stirling engine with adiabatic working spaces

    SciTech Connect

    Renfroe, D.A.; Counts, M.

    1988-10-01

    A Stirling engine incorporating a phase-changing component of the working fluid has been modeled with the assumption that the compression and expansion space are adiabatic, and that the heat exchanger consists of a cooler, regenerator, and heater of finite size where the fluid follows an idealized temperature profile. Differential equations for the rate of change of mass in any cell and pressure over the entire engine were derived from the energy, continuity, state equations, and Dalton's law. From the simultaneous solution of these equations, all of the information necessary for calculation of power output and efficiency were obtained. Comparison of the results from this model with previous studies shows that the advantage of adding a phase-changing component to the working fluid may have been overstated.

  10. Adiabatic calorimetric decomposition studies of 50 wt.% hydroxylamine/water.

    PubMed

    Cisneros, L O; Rogers, W J; Mannan, M S

    2001-03-19

    Calorimetric data can provide a basis for determining potential hazards in reactions, storage, and transportation of process chemicals. This work provides calorimetric data for the thermal decomposition behavior in air of 50wt.% hydroxylamine/water (HA), both with and without added stabilizers, which was measured in closed cells with an automatic pressure tracking adiabatic calorimeter (APTAC). Among the data provided are onset temperatures, reaction order, activation energies, pressures of noncondensable products, thermal stability at 100 degrees C, and the effect of HA storage time. Discussed also are the catalytic effects of carbon steel, stainless steel, stainless steel with silica coating, inconel, titanium, and titanium with silica coating on the reaction self-heat rates and onset temperatures. In borosilicate glass cells, HA was relatively stable at temperatures up to 133 degrees C, where the HA decomposition self-heat rate reached 0.05 degrees C/min. The added stabilizers appeared to reduce HA decomposition rates in glass cells and at ambient temperatures. The tested metals and metal surfaces coated with silica acted as catalysts to lower the onset temperatures and increase the self-heat rates. PMID:11165058

  11. Adiabatic calorimetric decomposition studies of 50 wt.% hydroxylamine/water.

    PubMed

    Cisneros, L O; Rogers, W J; Mannan, M S

    2001-03-19

    Calorimetric data can provide a basis for determining potential hazards in reactions, storage, and transportation of process chemicals. This work provides calorimetric data for the thermal decomposition behavior in air of 50wt.% hydroxylamine/water (HA), both with and without added stabilizers, which was measured in closed cells with an automatic pressure tracking adiabatic calorimeter (APTAC). Among the data provided are onset temperatures, reaction order, activation energies, pressures of noncondensable products, thermal stability at 100 degrees C, and the effect of HA storage time. Discussed also are the catalytic effects of carbon steel, stainless steel, stainless steel with silica coating, inconel, titanium, and titanium with silica coating on the reaction self-heat rates and onset temperatures. In borosilicate glass cells, HA was relatively stable at temperatures up to 133 degrees C, where the HA decomposition self-heat rate reached 0.05 degrees C/min. The added stabilizers appeared to reduce HA decomposition rates in glass cells and at ambient temperatures. The tested metals and metal surfaces coated with silica acted as catalysts to lower the onset temperatures and increase the self-heat rates.

  12. [A simple apparatus for the determination of the resistance of bioindicators to saturated steam at temperatures less than 100 degrees C., tested with Enterococcus faecium as test microbe].

    PubMed

    Spicher, G; Borchers, U; Peters, J

    1991-09-01

    An apparatus is described by means of which the resistance of microbiological indicators to water vapor at temperatures below 100 degrees C can be determined. The apparatus can be assembled from parts generally available in laboratories. The principle of the apparatus consists in the production of water vapor of the desired temperature under conditions of reduced pressure and its recondensation to water after having passed a special chamber. Accordingly, the device consists of a heated round-bottom flask serving as steam generator, an exposure chamber (B), and a condenser (D) attached to a receiver (E). The bioindicators are exposed to the water vapor in the exposure chamber. A bypass located between the steam generator and the condenser allows for continuous operation even when the exposure chamber is opened. The reduced pressure was achieved by means of a waterjet pump and adjusted by two tandem-joined pressure-regulating valves as needed. The apparatus was tested using water vapor of 73, 75 and 77 degrees C, respectively, and bioindicators containing Enterococcus faecium as test organism. In the range of exposure periods in which bioindicators change from the status "all indicators having surviving test organisms" to the status "all indicators free from surviving test organisms" the bioindicators showed D values of 5.7, 4.4 and 2.9 min, respectively. For the temperature dependence of resistance a z value of 12.5 Kelvin resulted. PMID:1953932

  13. Wigner phase space distribution via classical adiabatic switching

    SciTech Connect

    Bose, Amartya; Makri, Nancy

    2015-09-21

    Evaluation of the Wigner phase space density for systems of many degrees of freedom presents an extremely demanding task because of the oscillatory nature of the Fourier-type integral. We propose a simple and efficient, approximate procedure for generating the Wigner distribution that avoids the computational difficulties associated with the Wigner transform. Starting from a suitable zeroth-order Hamiltonian, for which the Wigner density is available (either analytically or numerically), the phase space distribution is propagated in time via classical trajectories, while the perturbation is gradually switched on. According to the classical adiabatic theorem, each trajectory maintains a constant action if the perturbation is switched on infinitely slowly. We show that the adiabatic switching procedure produces the exact Wigner density for harmonic oscillator eigenstates and also for eigenstates of anharmonic Hamiltonians within the Wentzel-Kramers-Brillouin (WKB) approximation. We generalize the approach to finite temperature by introducing a density rescaling factor that depends on the energy of each trajectory. Time-dependent properties are obtained simply by continuing the integration of each trajectory under the full target Hamiltonian. Further, by construction, the generated approximate Wigner distribution is invariant under classical propagation, and thus, thermodynamic properties are strictly preserved. Numerical tests on one-dimensional and dissipative systems indicate that the method produces results in very good agreement with those obtained by full quantum mechanical methods over a wide temperature range. The method is simple and efficient, as it requires no input besides the force fields required for classical trajectory integration, and is ideal for use in quasiclassical trajectory calculations.

  14. Many-body effects on adiabatic passage through Feshbach resonances

    NASA Astrophysics Data System (ADS)

    Tikhonenkov, I.; Pazy, E.; Band, Y. B.; Fleischhauer, M.; Vardi, A.

    2006-04-01

    We theoretically study the dynamics of an adiabatic sweep through a Feshbach resonance, thereby converting a degenerate quantum gas of fermionic atoms into a degenerate quantum gas of bosonic dimers. Our analysis relies on a zero temperature mean-field theory which accurately accounts for initial molecular quantum fluctuations, triggering the association process. The structure of the resulting semiclassical phase space is investigated, highlighting the dynamical instability of the system towards association, for sufficiently small detuning from resonance. It is shown that this instability significantly modifies the finite-rate efficiency of the sweep, transforming the single-pair exponential Landau-Zener behavior of the remnant fraction of atoms Γ on sweep rate α , into a power-law dependence as the number of atoms increases. The obtained nonadiabaticity is determined from the interplay of characteristic time scales for the motion of adiabatic eigenstates and for fast periodic motion around them. Critical slowing-down of these precessions near the instability leads to the power-law dependence. A linear power law Γ∝α is obtained when the initial molecular fraction is smaller than the 1/N quantum fluctuations, and a cubic-root power law Γ∝α1/3 is attained when it is larger. Our mean-field analysis is confirmed by exact calculations, using Fock-space expansions. Finally, we fit experimental low temperature Feshbach sweep data with a power-law dependence. While the agreement with the experimental data is well within experimental error bars, similar accuracy can be obtained with an exponential fit, making additional data highly desirable.

  15. Many-body effects on adiabatic passage through Feshbach resonances

    SciTech Connect

    Tikhonenkov, I.; Pazy, E.; Band, Y. B.; Vardi, A.; Fleischhauer, M.

    2006-04-15

    We theoretically study the dynamics of an adiabatic sweep through a Feshbach resonance, thereby converting a degenerate quantum gas of fermionic atoms into a degenerate quantum gas of bosonic dimers. Our analysis relies on a zero temperature mean-field theory which accurately accounts for initial molecular quantum fluctuations, triggering the association process. The structure of the resulting semiclassical phase space is investigated, highlighting the dynamical instability of the system towards association, for sufficiently small detuning from resonance. It is shown that this instability significantly modifies the finite-rate efficiency of the sweep, transforming the single-pair exponential Landau-Zener behavior of the remnant fraction of atoms {gamma} on sweep rate {alpha}, into a power-law dependence as the number of atoms increases. The obtained nonadiabaticity is determined from the interplay of characteristic time scales for the motion of adiabatic eigenstates and for fast periodic motion around them. Critical slowing-down of these precessions near the instability leads to the power-law dependence. A linear power law {gamma}{proportional_to}{alpha} is obtained when the initial molecular fraction is smaller than the 1/N quantum fluctuations, and a cubic-root power law {gamma}{proportional_to}{alpha}{sup 1/3} is attained when it is larger. Our mean-field analysis is confirmed by exact calculations, using Fock-space expansions. Finally, we fit experimental low temperature Feshbach sweep data with a power-law dependence. While the agreement with the experimental data is well within experimental error bars, similar accuracy can be obtained with an exponential fit, making additional data highly desirable.

  16. Bond selective chemistry beyond the adiabatic approximation

    SciTech Connect

    Butler, L.J.

    1993-12-01

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  17. Shortcut to adiabaticity in spinor condensates

    NASA Astrophysics Data System (ADS)

    Sala, Arnau; Núñez, David López; Martorell, Joan; De Sarlo, Luigi; Zibold, Tilman; Gerbier, Fabrice; Polls, Artur; Juliá-Díaz, Bruno

    2016-10-01

    We devise a method to shortcut the adiabatic evolution of a spin-1 Bose gas with an external magnetic field as the control parameter. An initial many-body state with almost all bosons populating the Zeeman sublevel m =0 is evolved to a final state very close to a macroscopic spin-singlet condensate, a fragmented state with three macroscopically occupied Zeeman states. The shortcut protocol, obtained by an approximate mapping to a harmonic oscillator Hamiltonian, is compared to linear and exponential variations of the control parameter. We find a dramatic speedup of the dynamics when using the shortcut protocol.

  18. On adiabatic perturbations in the ekpyrotic scenario

    SciTech Connect

    Linde, A.; Mukhanov, V.; Vikman, A. E-mail: Viatcheslav.Mukhanov@physik.uni-muenchen.de

    2010-02-01

    In a recent paper, Khoury and Steinhardt proposed a way to generate adiabatic cosmological perturbations with a nearly flat spectrum in a contracting Universe. To produce these perturbations they used a regime in which the equation of state exponentially rapidly changed during a short time interval. Leaving aside the singularity problem and the difficult question about the possibility to transmit these perturbations from a contracting Universe to the expanding phase, we will show that the methods used in Khoury are inapplicable for the description of the cosmological evolution and of the process of generation of perturbations in this scenario.

  19. Generalized Ramsey numbers through adiabatic quantum optimization

    NASA Astrophysics Data System (ADS)

    Ranjbar, Mani; Macready, William G.; Clark, Lane; Gaitan, Frank

    2016-09-01

    Ramsey theory is an active research area in combinatorics whose central theme is the emergence of order in large disordered structures, with Ramsey numbers marking the threshold at which this order first appears. For generalized Ramsey numbers r( G, H), the emergent order is characterized by graphs G and H. In this paper we: (i) present a quantum algorithm for computing generalized Ramsey numbers by reformulating the computation as a combinatorial optimization problem which is solved using adiabatic quantum optimization; and (ii) determine the Ramsey numbers r({{T}}m,{{T}}n) for trees of order m,n = 6,7,8, most of which were previously unknown.

  20. Cavity-state preparation using adiabatic transfer

    NASA Astrophysics Data System (ADS)

    Larson, Jonas; Andersson, Erika

    2005-05-01

    We show how to prepare a variety of cavity field states for multiple cavities. The state preparation technique used is related to the method of stimulated adiabatic Raman passage. The cavity modes are coupled by atoms, making it possible to transfer an arbitrary cavity field state from one cavity to another and also to prepare nontrivial cavity field states. In particular, we show how to prepare entangled states of two or more cavities, such as an Einstein-Podolsky-Rosen state and a W state, as well as various entangled superpositions of coherent states in different cavities, including Schrödinger cat states. The theoretical considerations are supported by numerical simulations.

  1. Phase avalanches in near-adiabatic evolutions

    SciTech Connect

    Vertesi, T.; Englman, R.

    2006-02-15

    In the course of slow, nearly adiabatic motion of a system, relative changes in the slowness can cause abrupt and high magnitude phase changes, ''phase avalanches,'' superimposed on the ordinary geometric phases. The generality of this effect is examined for arbitrary Hamiltonians and multicomponent (>2) wave packets and is found to be connected (through the Blaschke term in the theory of analytic signals) to amplitude zeros in the lower half of the complex time plane. Motion on a nonmaximal circle on the Poincare-sphere suppresses the effect. A spectroscopic transition experiment can independently verify the phase-avalanche magnitudes.

  2. Local entanglement generation in the adiabatic regime

    SciTech Connect

    Cliche, M.; Veitia, Andrzej

    2010-09-15

    We study entanglement generation in a pair of qubits interacting with an initially correlated system. Using time-independent perturbation theory and the adiabatic theorem, we show conditions under which the qubits become entangled as the joint system evolves into the ground state of the interacting theory. We then apply these results to the case of qubits interacting with a scalar quantum field. We study three different variations of this setup; a quantum field subject to Dirichlet boundary conditions, a quantum field interacting with a classical potential, and a quantum field that starts in a thermal state.

  3. Adiabatic demagnetization refrigerator for use in zero gravity

    NASA Technical Reports Server (NTRS)

    Dingus, Michael L.

    1988-01-01

    In this effort, a new design concept for an adiabatic demagnetization refrigerator (ADR) that is capable of operation in zero gravity has been developed. The design uses a vortex precooler to lower the initial temperature of magnetic salt from the initial space superfluid helium dewar of 1.8 K to 1.1 K. This reduces the required maximum magnetic field from 4 Tesla to 2 Tesla. The laboratory prototype vortex precooler reached a minimum temperature of 0.78 K, and had a cooling power of 1 mW at 1.1 K. A study was conducted to determine the dependence of vortex cooler performance on system element configuration. A superfluid filled capillary heat switch was used in the design. The laboratory prototype ADR reached a minimum temperature of 0.107 K, and maintained temperatures below 0.125 K for 90 minutes. Demagnetization was carried out from a maximum field of 2 T. A soft iron shield was developed that reduced the radial central field to 1 gauss at 0.25 meters.

  4. Salt pill design and fabrication for adiabatic demagnetization refrigerators

    NASA Astrophysics Data System (ADS)

    Shirron, Peter J.; McCammon, Dan

    2014-07-01

    The performance of an adiabatic demagnetization refrigerator (ADR) is critically dependent on the design and construction of the salt pills that produce cooling. In most cases, the primary goal is to obtain the largest cooling capacity at the low temperature end of the operating range. The realizable cooling capacity depends on a number of factors, including refrigerant mass, and how efficiently it absorbs heat from the various instrument loads. The design and optimization of “salt pills” for ADR systems depend not only on the mechanical, chemical and thermal properties of the refrigerant, but also on the range of heat fluxes that the salt pill must accommodate. Despite the fairly wide variety of refrigerants available, those used at very low temperature tend to be hydrated salts that require a dedicated thermal bus and must be hermetically sealed, while those used at higher temperature - greater than about 0.5 K - tend to be single- or poly-crystals that have much simpler requirements for thermal and mechanical packaging. This paper presents a summary of strategies and techniques for designing, optimizing and fabricating salt pills for both low- and mid-temperature applications.

  5. Salt Pill Design and Fabrication for Adiabatic Demagnetization Refrigerators

    NASA Technical Reports Server (NTRS)

    Shirron, Peter J.; Mccammon, Dan

    2014-01-01

    The performance of an adiabatic demagnetization refrigerator (ADR) is critically dependent on the design and construction of the salt pills that produce cooling. In most cases, the primary goal is to obtain the largest cooling capacity at the low temperature end of the operating range. The realizable cooling capacity depends on a number of factors, including refrigerant mass, and how efficiently it absorbs heat from the various instrument loads. The design and optimization of "salt pills" for ADR systems depend not only on the mechanical, chemical and thermal properties of the refrigerant, but also on the range of heat fluxes that the salt pill must accommodate. Despite the fairly wide variety of refrigerants available, those used at very low temperature tend to be hydrated salts that require a dedicated thermal bus and must be hermetically sealed, while those used at higher temperature - greater than about 0.5 K - tend to be single-­- or poly-­-crystals that have much simpler requirements for thermal and mechanical packaging. This paper presents a summary of strategies and techniques for designing, optimizing and fabricating salt pills for both low-­- and mid-­-temperature applications.

  6. Quantum Adiabatic Algorithms and Large Spin Tunnelling

    NASA Technical Reports Server (NTRS)

    Boulatov, A.; Smelyanskiy, V. N.

    2003-01-01

    We provide a theoretical study of the quantum adiabatic evolution algorithm with different evolution paths proposed in this paper. The algorithm is applied to a random binary optimization problem (a version of the 3-Satisfiability problem) where the n-bit cost function is symmetric with respect to the permutation of individual bits. The evolution paths are produced, using the generic control Hamiltonians H (r) that preserve the bit symmetry of the underlying optimization problem. In the case where the ground state of H(0) coincides with the totally-symmetric state of an n-qubit system the algorithm dynamics is completely described in terms of the motion of a spin-n/2. We show that different control Hamiltonians can be parameterized by a set of independent parameters that are expansion coefficients of H (r) in a certain universal set of operators. Only one of these operators can be responsible for avoiding the tunnelling in the spin-n/2 system during the quantum adiabatic algorithm. We show that it is possible to select a coefficient for this operator that guarantees a polynomial complexity of the algorithm for all problem instances. We show that a successful evolution path of the algorithm always corresponds to the trajectory of a classical spin-n/2 and provide a complete characterization of such paths.

  7. A study on the high temperature-dependence of the electrical properties in a solution-deposited zinc-tin-oxide thin-film transistor operated in the saturation region

    NASA Astrophysics Data System (ADS)

    Yu, Kyeong Min; Bae, Byung Seong; Jung, Myunghee; Yun, Eui-Jung

    2016-06-01

    We investigate the effects of high temperatures in the range of 292 - 393 K on the electrical properties of solution-processed amorphous zinc-tin-oxide (a-ZTO) thin-film transistors (TFTs) operated in the saturation region. The fabricated a-ZTO TFTs have a non-patterned bottom gate and top contact structure, and they use a heavily-doped Si wafer and SiO2 as a gate electrode and a gate insulator layer, respectively. In a-ZTO TFTs, the trap release energy ( E TR ) was deduced by using Maxwell-Boltzmann statistics. The decreasing E TR toward zero with increasing gate voltage (the density of trap states ( n s )) in the a-ZTO active layer can be attributed to a shift of the Fermi level toward the mobility edge with increasing gate voltage. The TFTs with low gate voltage (low n s ) exhibit multiple trap and release characteristics and show thermally-activated behavior. In TFTs with a high gate voltage (high n s ), however, we observe decreasing mobility and conductivity with increasing temperature at temperatures ranging from 303 to 363 K. This confirms that the E TR can drop to zero, indicating a shift of the Fermi level beyond the mobility edge. Hence, the mobility edge is detected at the cusp between thermally-activated transport and band transport.

  8. Sensitivity of inertial confinement fusion hot spot properties to the deuterium-tritium fuel adiabat

    NASA Astrophysics Data System (ADS)

    Melvin, J.; Lim, H.; Rana, V.; Cheng, B.; Glimm, J.; Sharp, D. H.; Wilson, D. C.

    2015-02-01

    We determine the dependence of key Inertial Confinement Fusion (ICF) hot spot simulation properties on the deuterium-tritium fuel adiabat, here modified by addition of energy to the cold shell. Variation of this parameter reduces the simulation to experiment discrepancy in some, but not all, experimentally inferred quantities. Using simulations with radiation drives tuned to match experimental shots N120321 and N120405 from the National Ignition Campaign (NIC), we carry out sets of simulations with varying amounts of added entropy and examine the sensitivities of important experimental quantities. Neutron yields, burn widths, hot spot densities, and pressures follow a trend approaching their experimentally inferred quantities. Ion temperatures and areal densities are sensitive to the adiabat changes, but do not necessarily converge to their experimental quantities with the added entropy. This suggests that a modification to the simulation adiabat is one of, but not the only explanation of the observed simulation to experiment discrepancies. In addition, we use a theoretical model to predict 3D mix and observe a slight trend toward less mixing as the entropy is enhanced. Instantaneous quantities are assessed at the time of maximum neutron production, determined dynamically within each simulation. These trends contribute to ICF science, as an effort to understand the NIC simulation to experiment discrepancy, and in their relation to the high foot experiments, which features a higher adiabat in the experimental design and an improved neutron yield in the experimental results.

  9. Sensitivity of inertial confinement fusion hot spot properties to the deuterium-tritium fuel adiabat

    SciTech Connect

    Melvin, J.; Lim, H.; Rana, V.; Glimm, J.; Cheng, B.; Sharp, D. H.; Wilson, D. C.

    2015-02-15

    We determine the dependence of key Inertial Confinement Fusion (ICF) hot spot simulation properties on the deuterium-tritium fuel adiabat, here modified by addition of energy to the cold shell. Variation of this parameter reduces the simulation to experiment discrepancy in some, but not all, experimentally inferred quantities. Using simulations with radiation drives tuned to match experimental shots N120321 and N120405 from the National Ignition Campaign (NIC), we carry out sets of simulations with varying amounts of added entropy and examine the sensitivities of important experimental quantities. Neutron yields, burn widths, hot spot densities, and pressures follow a trend approaching their experimentally inferred quantities. Ion temperatures and areal densities are sensitive to the adiabat changes, but do not necessarily converge to their experimental quantities with the added entropy. This suggests that a modification to the simulation adiabat is one of, but not the only explanation of the observed simulation to experiment discrepancies. In addition, we use a theoretical model to predict 3D mix and observe a slight trend toward less mixing as the entropy is enhanced. Instantaneous quantities are assessed at the time of maximum neutron production, determined dynamically within each simulation. These trends contribute to ICF science, as an effort to understand the NIC simulation to experiment discrepancy, and in their relation to the high foot experiments, which features a higher adiabat in the experimental design and an improved neutron yield in the experimental results.

  10. Saturation in coupled oscillators

    NASA Astrophysics Data System (ADS)

    Roman, Ahmed; Hanna, James

    2015-03-01

    We consider a weakly nonlinear system consisting of a resonantly forced oscillator coupled to an unforced oscillator. It has long been known that, for quadratic nonlinearities and a 2:1 resonance between the oscillators, a perturbative solution of the dynamics exhibits a phenomenon known as saturation. At low forcing, the forced oscillator responds, while the unforced oscillator is quiescent. Above a critical value of the forcing, the forced oscillator's steady-state amplitude reaches a plateau, while that of the unforced oscillator increases without bound. We show that, contrary to established folklore, saturation is not unique to quadratically nonlinear systems. We present conditions on the form of the nonlinear couplings and resonance that lead to saturation. Our results elucidate a mechanism for localization or diversion of energy in systems of coupled oscillators, and suggest new approaches for the control or suppression of vibrations in engineered systems.

  11. Adiabat Shaping of ICF Capsules Using Ramped Pressure Profiles

    NASA Astrophysics Data System (ADS)

    Anderson, K.; Betti, R.; Collins, T. J. B.; Marinak, M. M.; Haan, S. W.

    2002-11-01

    Target design of direct-drive ICF capsules has historically involved a compromise between high 1-D (clean) yield and capsule stability. Low-adiabat fuel is desirable to achieve high compression and, hence, high yield. A higher adiabat at the ablation front reduces the growth rate of the Raleigh--Taylor instability due to higher ablation velocity. An optimal target design will take advantage of both by shaping the adiabat of the capsule to allow for high adiabat in the material that is to be ablated and low adiabat in the remaining fuel. We present here a method of adiabat shaping using a low-intensity prepulse followed by laser shutoff before beginning the main drive pulse. This creates a decaying shock with a ramped pressure profile behind it. Since the prepulse is low intensity, the adiabat is not strongly affected by the prepulse. The main shock is then launched up this ramped pressure profile to set the adiabat. Because the main shock sees an increasing pressure profile, the effective strength of the shock decreases as it propagates through the shell, thus creating a smooth adiabat profile from high outer-shell adiabat to low inner-shell adiabat. Results of simulations using 1-D LILAC and 2-D DRACO (LLE), as well as 1-D and 2-D HYDRA (LLNL), are presented. This work was supported by the U.S. DOE Office of Inertial Confinement Fusion under Cooperative Agreement No. DE-FC03-92SF19460 and by the University of California LLNL under contract No. W-7405-Eng-48.

  12. Impacts of seawater saturation state (ΩA = 0.4-4.6) and temperature (10, 25 °C) on the dissolution kinetics of whole-shell biogenic carbonates

    NASA Astrophysics Data System (ADS)

    Ries, Justin B.; Ghazaleh, Maite N.; Connolly, Brian; Westfield, Isaac; Castillo, Karl D.

    2016-11-01

    Anthropogenic increase of atmospheric pCO2 since the Industrial Revolution has caused seawater pH to decrease and seawater temperatures to increase-trends that are expected to continue into the foreseeable future. Myriad experimental studies have investigated the impacts of ocean acidification and warming on marine calcifiers' ability to build protective shells and skeletons. No studies, however, have investigated the combined impacts of ocean acidification and warming on the whole-shell dissolution kinetics of biogenic carbonates. Here, we present the results of experiments designed to investigate the effects of seawater saturation state (ΩA = 0.4-4.6) and temperature (10, 25 °C) on gross rates of whole-shell dissolution for ten species of benthic marine calcifiers: the oyster Crassostrea virginica, the ivory barnacle Balanus eburneus, the blue mussel Mytilus edulis, the conch Strombus alatus, the tropical coral Siderastrea siderea, the temperate coral Oculina arbuscula, the hard clam Mercenaria mercenaria, the soft clam Mya arenaria, the branching bryozoan Schizoporella errata, and the coralline red alga Neogoniolithon sp. These experiments confirm that dissolution rates of whole-shell biogenic carbonates decrease with calcium carbonate (CaCO3) saturation state, increase with temperature, and vary predictably with respect to the relative solubility of the calcifiers' polymorph mineralogy [high-Mg calcite (mol% Mg > 4) ≥ aragonite > low-Mg calcite (mol% Mg < 4)], consistent with prior studies on sedimentary and inorganic carbonates. Furthermore, the severity of the temperature effects on gross dissolution rates also varied with respect to carbonate polymorph solubility, with warming (10-25 °C) exerting the greatest effect on biogenic high-Mg calcite, an intermediate effect on biogenic aragonite, and the least effect on biogenic low-Mg calcite. These results indicate that both ocean acidification and warming will lead to increased dissolution of biogenic

  13. Development of a semi-adiabatic isoperibol solution calorimeter.

    PubMed

    Venkata Krishnan, R; Jogeswararao, G; Parthasarathy, R; Premalatha, S; Prabhakar Rao, J; Gunasekaran, G; Ananthasivan, K

    2014-12-01

    A semi-adiabatic isoperibol solution calorimeter has been indigenously developed. The measurement system comprises modules for sensitive temperature measurement probe, signal processing, data collection, and joule calibration. The sensitivity of the temperature measurement module was enhanced by using a sensitive thermistor coupled with a lock-in amplifier based signal processor. A microcontroller coordinates the operation and control of these modules. The latter in turn is controlled through personal computer (PC) based custom made software developed with LabView. An innovative summing amplifier concept was used to cancel out the base resistance of the thermistor. The latter was placed in the dewar. The temperature calibration was carried out with a standard platinum resistance (PT100) sensor coupled with an 8½ digit multimeter. The water equivalent of this calorimeter was determined by using electrical calibration with the joule calibrator. The experimentally measured values of the quantum of heat were validated by measuring heats of dissolution of pure KCl (for endotherm) and tris (hydroxyl methyl) amino-methane (for exotherm). The uncertainity in the measurements was found to be within ±3%. PMID:25554316

  14. Spontaneous freezing of supercooled water under isochoric and adiabatic conditions.

    PubMed

    Prestipino, Santi; Giaquinta, Paolo V

    2013-07-11

    The return of a supercooled liquid to equilibrium usually begins with a fast heating up of the sample which ends when the system reaches the equilibrium freezing temperature. At this stage, the system is still a microsegregated mixture of solid and liquid. Only later is solidification completed through the exchange of energy with the surroundings. Using the IAPWS-95 formulation, we investigate the adiabatic freezing of supercooled water in a closed and rigid vessel, i.e., under thermally and mechanically isolated conditions, which captures the initial stage of the decay of metastable water to equilibrium. To improve realism further, we also account for a fixed amount of foreign gas in the vessel. Under the simplifying assumption that the system is at equilibrium immediately after the nominal freezing temperature has been attained, we determine-as a function of undercooling and gas mole number-the final temperature and pressure of the system, the fraction of ice at equilibrium, and the entropy increase. Assuming a nonzero energy cost for the ice-water interface, we also show that, unless sufficiently undercooled, perfectly isolated pure-water droplets cannot start freezing in the bulk.

  15. Development of a semi-adiabatic isoperibol solution calorimeter

    SciTech Connect

    Venkata Krishnan, R.; Jogeswararao, G.; Parthasarathy, R.; Premalatha, S.; Prabhakar Rao, J.; Gunasekaran, G.; Ananthasivan, K.

    2014-12-15

    A semi-adiabatic isoperibol solution calorimeter has been indigenously developed. The measurement system comprises modules for sensitive temperature measurement probe, signal processing, data collection, and joule calibration. The sensitivity of the temperature measurement module was enhanced by using a sensitive thermistor coupled with a lock-in amplifier based signal processor. A microcontroller coordinates the operation and control of these modules. The latter in turn is controlled through personal computer (PC) based custom made software developed with LabView. An innovative summing amplifier concept was used to cancel out the base resistance of the thermistor. The latter was placed in the dewar. The temperature calibration was carried out with a standard platinum resistance (PT100) sensor coupled with an 8½ digit multimeter. The water equivalent of this calorimeter was determined by using electrical calibration with the joule calibrator. The experimentally measured values of the quantum of heat were validated by measuring heats of dissolution of pure KCl (for endotherm) and tris (hydroxyl methyl) amino-methane (for exotherm). The uncertainity in the measurements was found to be within ±3%.

  16. Development of a semi-adiabatic isoperibol solution calorimeter

    NASA Astrophysics Data System (ADS)

    Venkata Krishnan, R.; Jogeswararao, G.; Parthasarathy, R.; Premalatha, S.; Prabhakar Rao, J.; Gunasekaran, G.; Ananthasivan, K.

    2014-12-01

    A semi-adiabatic isoperibol solution calorimeter has been indigenously developed. The measurement system comprises modules for sensitive temperature measurement probe, signal processing, data collection, and joule calibration. The sensitivity of the temperature measurement module was enhanced by using a sensitive thermistor coupled with a lock-in amplifier based signal processor. A microcontroller coordinates the operation and control of these modules. The latter in turn is controlled through personal computer (PC) based custom made software developed with LabView. An innovative summing amplifier concept was used to cancel out the base resistance of the thermistor. The latter was placed in the dewar. The temperature calibration was carried out with a standard platinum resistance (PT100) sensor coupled with an 8½ digit multimeter. The water equivalent of this calorimeter was determined by using electrical calibration with the joule calibrator. The experimentally measured values of the quantum of heat were validated by measuring heats of dissolution of pure KCl (for endotherm) and tris (hydroxyl methyl) amino-methane (for exotherm). The uncertainity in the measurements was found to be within ±3%.

  17. Pump for Saturated Liquids

    NASA Technical Reports Server (NTRS)

    Elliott, D. G.

    1986-01-01

    Boiling liquids pumped by device based on proven components. Expanding saturated liquid in nozzle and diverting its phases along separate paths in liquid/vapor separator raises pressure of liquid. Liquid cooled in process. Pump makes it unnecessary to pressurize cryogenic liquids in order to pump them. Problems of introducing noncondensable pressurizing gas avoided.

  18. The Adiabatic Invariance of the Action Variable in Classical Dynamics

    ERIC Educational Resources Information Center

    Wells, Clive G.; Siklos, Stephen T. C.

    2007-01-01

    We consider one-dimensional classical time-dependent Hamiltonian systems with quasi-periodic orbits. It is well known that such systems possess an adiabatic invariant which coincides with the action variable of the Hamiltonian formalism. We present a new proof of the adiabatic invariance of this quantity and illustrate our arguments by means of…

  19. Generation of atomic NOON states via shortcuts to adiabatic passage

    NASA Astrophysics Data System (ADS)

    Song, Chong; Su, Shi-Lei; Bai, Cheng-Hua; Ji, Xin; Zhang, Shou

    2016-10-01

    Based on Lewis-Riesenfeld invariants and quantum Zeno dynamics, we propose an effective scheme for generating atomic NOON states via shortcuts to adiabatic passage. The photon losses are efficiently suppressed by engineering shortcuts to adiabatic passage in the scheme. The numerical simulation shows that the atomic NOON states can be generated with high fidelity.

  20. Kinetic Theory Derivation of the Adiabatic Law for Ideal Gases.

    ERIC Educational Resources Information Center

    Sobel, Michael I.

    1980-01-01

    Discusses how the adiabatic law for ideal gases can be derived from the assumption of a Maxwell-Boltzmann (or any other) distribution of velocities--in contrast to the usual derivations from thermodynamics alone, and the higher-order effect that leads to one-body viscosity. An elementary derivation of the adiabatic law is given. (Author/DS)

  1. Adiabat-shaping in indirect drive inertial confinement fusion

    SciTech Connect

    Baker, K. L.; Robey, H. F.; Milovich, J. L.; Jones, O. S.; Smalyuk, V. A.; Casey, D. T.; MacPhee, A. G.; Pak, A.; Celliers, P. M.; Clark, D. S.; Landen, O. L.; Peterson, J. L.; Berzak-Hopkins, L. F.; Weber, C. R.; Haan, S. W.; Döppner, T. D.; Dixit, S.; Hamza, A. V.; Jancaitis, K. S.; Kroll, J. J.; and others

    2015-05-15

    Adiabat-shaping techniques were investigated in indirect drive inertial confinement fusion experiments on the National Ignition Facility as a means to improve implosion stability, while still maintaining a low adiabat in the fuel. Adiabat-shaping was accomplished in these indirect drive experiments by altering the ratio of the picket and trough energies in the laser pulse shape, thus driving a decaying first shock in the ablator. This decaying first shock is designed to place the ablation front on a high adiabat while keeping the fuel on a low adiabat. These experiments were conducted using the keyhole experimental platform for both three and four shock laser pulses. This platform enabled direct measurement of the shock velocities driven in the glow-discharge polymer capsule and in the liquid deuterium, the surrogate fuel for a DT ignition target. The measured shock velocities and radiation drive histories are compared to previous three and four shock laser pulses. This comparison indicates that in the case of adiabat shaping the ablation front initially drives a high shock velocity, and therefore, a high shock pressure and adiabat. The shock then decays as it travels through the ablator to pressures similar to the original low-adiabat pulses when it reaches the fuel. This approach takes advantage of initial high ablation velocity, which favors stability, and high-compression, which favors high stagnation pressures.

  2. A progress report on bolometers operating at 0.1 K using adiabatic demagnetization refrigeration

    NASA Technical Reports Server (NTRS)

    Roellig, T.; Lesyna, L.; Werner, M.; Kittel, P.

    1986-01-01

    Bolometers are still the detectors of choice for low background infrared observations at wavelengths longer than 200 microns. In the low background limit, bolometers become more sensitive as their operating temperature decreases, due to fundamental thermodynamic laws. The adiabatic demagnetization technique was evaluated by building a bolometer detection system operating at a wavelength of 1 millimeter for use at a ground based telescope. The system was fit checked at the telescope and is expected to take its first data in November, 1985.

  3. Number Partitioning via Quantum Adiabatic Computation

    NASA Technical Reports Server (NTRS)

    Smelyanskiy, Vadim N.; Toussaint, Udo; Clancy, Daniel (Technical Monitor)

    2002-01-01

    We study both analytically and numerically the complexity of the adiabatic quantum evolution algorithm applied to random instances of combinatorial optimization problems. We use as an example the NP-complete set partition problem and obtain an asymptotic expression for the minimal gap separating the ground and exited states of a system during the execution of the algorithm. We show that for computationally hard problem instances the size of the minimal gap scales exponentially with the problem size. This result is in qualitative agreement with the direct numerical simulation of the algorithm for small instances of the set partition problem. We describe the statistical properties of the optimization problem that are responsible for the exponential behavior of the algorithm.

  4. Differential topology of adiabatically controlled quantum processes

    NASA Astrophysics Data System (ADS)

    Jonckheere, Edmond A.; Rezakhani, Ali T.; Ahmad, Farooq

    2013-03-01

    It is shown that in a controlled adiabatic homotopy between two Hamiltonians, H 0 and H 1, the gap or "anti-crossing" phenomenon can be viewed as the development of cusps and swallow tails in the region of the complex plane where two critical value curves of the quadratic map associated with the numerical range of H 0 + i H 1 come close. The "near crossing" in the energy level plots happens to be a generic situation, in the sense that a crossing is a manifestation of the quadratic numerical range map being unstable in the sense of differential topology. The stable singularities that can develop are identified and it is shown that they could occur near the gap, making those singularities of paramount importance. Various applications, including the quantum random walk, are provided to illustrate this theory.

  5. Quantum Adiabatic Optimization and Combinatorial Landscapes

    NASA Technical Reports Server (NTRS)

    Smelyanskiy, V. N.; Knysh, S.; Morris, R. D.

    2003-01-01

    In this paper we analyze the performance of the Quantum Adiabatic Evolution (QAE) algorithm on a variant of Satisfiability problem for an ensemble of random graphs parametrized by the ratio of clauses to variables, gamma = M / N. We introduce a set of macroscopic parameters (landscapes) and put forward an ansatz of universality for random bit flips. We then formulate the problem of finding the smallest eigenvalue and the excitation gap as a statistical mechanics problem. We use the so-called annealing approximation with a refinement that a finite set of macroscopic variables (verses only energy) is used, and are able to show the existence of a dynamic threshold gamma = gammad, beyond which QAE should take an exponentially long time to find a solution. We compare the results for extended and simplified sets of landscapes and provide numerical evidence in support of our universality ansatz.

  6. Geometric Adiabatic Transport in Quantum Hall States.

    PubMed

    Klevtsov, S; Wiegmann, P

    2015-08-21

    We argue that in addition to the Hall conductance and the nondissipative component of the viscous tensor, there exists a third independent transport coefficient, which is precisely quantized. It takes constant values along quantum Hall plateaus. We show that the new coefficient is the Chern number of a vector bundle over moduli space of surfaces of genus 2 or higher and therefore cannot change continuously along the plateau. As such, it does not transpire on a sphere or a torus. In the linear response theory, this coefficient determines intensive forces exerted on electronic fluid by adiabatic deformations of geometry and represents the effect of the gravitational anomaly. We also present the method of computing the transport coefficients for quantum Hall states. PMID:26340197

  7. Geometric Adiabatic Transport in Quantum Hall States.

    PubMed

    Klevtsov, S; Wiegmann, P

    2015-08-21

    We argue that in addition to the Hall conductance and the nondissipative component of the viscous tensor, there exists a third independent transport coefficient, which is precisely quantized. It takes constant values along quantum Hall plateaus. We show that the new coefficient is the Chern number of a vector bundle over moduli space of surfaces of genus 2 or higher and therefore cannot change continuously along the plateau. As such, it does not transpire on a sphere or a torus. In the linear response theory, this coefficient determines intensive forces exerted on electronic fluid by adiabatic deformations of geometry and represents the effect of the gravitational anomaly. We also present the method of computing the transport coefficients for quantum Hall states.

  8. Adiabatic frequency conversion of ultrafast pulses

    NASA Astrophysics Data System (ADS)

    Suchowski, H.; Bruner, B. D.; Ganany-Padowicz, A.; Juwiler, I.; Arie, A.; Silberberg, Y.

    2011-12-01

    A new method for efficient, broadband sum and difference frequency generation of ultrafast pulses is demonstrated. The principles of the method follow from an analogy between frequency conversion and coherent optical excitation of a two-level system. For conversion of ultrafast pulses, the concepts of adiabatic conversion are developed further in order to account for dispersion and group velocity mismatch. The scheme was implemented using aperiodically poled nonlinear crystals and a single step nonlinear mixing process, leading to conversion of near-IR (˜790 nm) ultrafast pulses into the blue (˜450 nm) and mid-IR (˜3.15 μm) spectral regions. Conversion bandwidths up to 15 THz FWHM and efficiencies up to 50% are reported.

  9. Adiabatic connection at negative coupling strengths

    SciTech Connect

    Seidl, Michael; Gori-Giorgi, Paola

    2010-01-15

    The adiabatic connection of density functional theory (DFT) for electronic systems is generalized here to negative values of the coupling strength alpha (with attractive electrons). In the extreme limit alpha->-infinity a simple physical solution is presented and its implications for DFT (as well as its limitations) are discussed. For two-electron systems (a case in which the present solution can be calculated exactly), we find that an interpolation between the limit alpha->-infinity and the opposite limit of infinitely strong repulsion (alpha->+infinity) yields a rather accurate estimate of the second-order correlation energy E{sub c}{sup GL2}[rho] for several different densities rho, without using virtual orbitals. The same procedure is also applied to the Be isoelectronic series, analyzing the effects of near degeneracy.

  10. Adiabatic theory for anisotropic cold molecule collisions

    SciTech Connect

    Pawlak, Mariusz; Shagam, Yuval; Narevicius, Edvardas; Moiseyev, Nimrod

    2015-08-21

    We developed an adiabatic theory for cold anisotropic collisions between slow atoms and cold molecules. It enables us to investigate the importance of the couplings between the projection states of the rotational motion of the atom about the molecular axis of the diatom. We tested our theory using the recent results from the Penning ionization reaction experiment {sup 4}He(1s2s {sup 3}S) + HD(1s{sup 2}) → {sup 4}He(1s{sup 2}) + HD{sup +}(1s) + e{sup −} [Lavert-Ofir et al., Nat. Chem. 6, 332 (2014)] and demonstrated that the couplings have strong effect on positions of shape resonances. The theory we derived provides cross sections which are in a very good agreement with the experimental findings.

  11. Lattice Boltzmann method for adiabatic acoustics.

    PubMed

    Li, Yanbing; Shan, Xiaowen

    2011-06-13

    The lattice Boltzmann method (LBM) has been proved to be a useful tool in many areas of computational fluid dynamics, including computational aero-acoustics (CAA). However, for historical reasons, its applications in CAA have been largely restricted to simulations of isothermal (Newtonian) sound waves. As the recent kinetic theory-based reformulation establishes a theoretical framework in which LBM can be extended to recover the full Navier-Stokes-Fourier (NS) equations and beyond, in this paper, we show that, at least at the low-frequency limit (sound frequency much less than molecular collision frequency), adiabatic sound waves can be accurately simulated by the LBM provided that the lattice and the distribution function ensure adequate recovery of the full NS equations.

  12. An integrated programming and development environment for adiabatic quantum optimization

    NASA Astrophysics Data System (ADS)

    Humble, T. S.; McCaskey, A. J.; Bennink, R. S.; Billings, J. J.; DʼAzevedo, E. F.; Sullivan, B. D.; Klymko, C. F.; Seddiqi, H.

    2014-01-01

    Adiabatic quantum computing is a promising route to the computational power afforded by quantum information processing. The recent availability of adiabatic hardware has raised challenging questions about how to evaluate adiabatic quantum optimization (AQO) programs. Processor behavior depends on multiple steps to synthesize an adiabatic quantum program, which are each highly tunable. We present an integrated programming and development environment for AQO called Jade Adiabatic Development Environment (JADE) that provides control over all the steps taken during program synthesis. JADE captures the workflow needed to rigorously specify the AQO algorithm while allowing a variety of problem types, programming techniques, and processor configurations. We have also integrated JADE with a quantum simulation engine that enables program profiling using numerical calculation. The computational engine supports plug-ins for simulation methodologies tailored to various metrics and computing resources. We present the design, integration, and deployment of JADE and discuss its potential use for benchmarking AQO programs by the quantum computer science community.

  13. An Integrated Development Environment for Adiabatic Quantum Programming

    SciTech Connect

    Humble, Travis S; McCaskey, Alex; Bennink, Ryan S; Billings, Jay Jay; D'Azevedo, Eduardo; Sullivan, Blair D; Klymko, Christine F; Seddiqi, Hadayat

    2014-01-01

    Adiabatic quantum computing is a promising route to the computational power afforded by quantum information processing. The recent availability of adiabatic hardware raises the question of how well quantum programs perform. Benchmarking behavior is challenging since the multiple steps to synthesize an adiabatic quantum program are highly tunable. We present an adiabatic quantum programming environment called JADE that provides control over all the steps taken during program development. JADE captures the workflow needed to rigorously benchmark performance while also allowing a variety of problem types, programming techniques, and processor configurations. We have also integrated JADE with a quantum simulation engine that enables program profiling using numerical calculation. The computational engine supports plug-ins for simulation methodologies tailored to various metrics and computing resources. We present the design, integration, and deployment of JADE and discuss its use for benchmarking adiabatic quantum programs.

  14. Non-adiabatic molecular dynamics with complex quantum trajectories. II. The adiabatic representation

    SciTech Connect

    Zamstein, Noa; Tannor, David J.

    2012-12-14

    We present a complex quantum trajectory method for treating non-adiabatic dynamics. Each trajectory evolves classically on a single electronic surface but with complex position and momentum. The equations of motion are derived directly from the time-dependent Schroedinger equation, and the population exchange arises naturally from amplitude-transfer terms. In this paper the equations of motion are derived in the adiabatic representation to complement our work in the diabatic representation [N. Zamstein and D. J. Tannor, J. Chem. Phys. 137, 22A517 (2012)]. We apply our method to two benchmark models introduced by John Tully [J. Chem. Phys. 93, 1061 (1990)], and get very good agreement with converged quantum-mechanical calculations. Specifically, we show that decoherence (spatial separation of wavepackets on different surfaces) is already contained in the equations of motion and does not require ad hoc augmentation.

  15. Experimental investigation of saturated polarization spectroscopy for quantitative concentration measurements.

    PubMed

    Reichardt, T A; Giancola, W C; Lucht, R P

    2000-04-20

    Polarization-spectroscopy (PS) line shapes and signal intensities are measured in well-characterized hydrogen-air flames operated over a wide range of equivalence ratios. We use both low (perturbative) and high (saturating) pump beam intensities in the counterpropagating pump-probe geometry. The effects of saturation on the line-center signal intensity and the resonance linewidth are investigated. The PS signal intensities are used to measure relative OH number densities in a series of near-adiabatic flames at equivalence ratios (phi) ranging from 0.5 to 1.5. The use of saturating pump intensities minimizes the effect of pump beam absorption, providing more accurate number density measurements. When calibrated to the calculated OH concentration in the phi = 0.6 flame, the saturated PS number density measurements probing the P(1)(2) transition are in excellent agreement with OH absorption measurements, equilibrium calculations of OH number density, and previous saturated degenerate four-wave mixing OH number density measurements. PMID:18345100

  16. Experimental investigation of saturated polarization spectroscopy for quantatative concentration measurements

    SciTech Connect

    Reichardt, Thomas A.; Giancola, William C.; Lucht, Robert P.

    2000-04-20

    Polarization-spectroscopy (PS) line shapes and signal intensities are measured in well-characterized hydrogen-air flames operated over a wide range of equivalence ratios. We use both low (perturbative) and high (saturating) pump beam intensities in the counterpropagating pump-probe geometry. The effects of saturation on the line-center signal intensity and the resonance linewidth are investigated. The PS signal intensities are used to measure relative OH number densities in a series of near-adiabatic flames at equivalence ratios ({phi}) ranging from 0.5 to 1.5. The use of saturating pump intensities minimizes the effect of pump beam absorption, providing more accurate number density measurements. When calibrated to the calculated OH concentration in the {phi}=0.6 flame, the saturated PS number density measurements probing the P{sub 1}(2) transition are in excellent agreement with OH absorption measurements, equilibrium calculations of OH number density, and previous saturated degenerate four-wave mixing OH number density measurements. (c) 2000 Optical Society of America.

  17. Boundary Layer Dynamics and Sub-Adiabaticity in Convecting Planetary Mantles

    NASA Astrophysics Data System (ADS)

    Moore, W. B.

    2007-05-01

    A broad range of phenomena are influenced by the behavior of thermal boundary layers in planetary mantles including plume temperatures, lithospheric stresses, resistance to plate motions, and the temperature structure of the mantle as a whole. The textbook picture of the temperature profile in a convecting layer consists of two boundary layers separated by a well-mixed, adiabatic interior. The sum of the temperature drops across the upper and lower boundary layers is equal to super-adiabatic temperature drop across the entire layer. This picture does not accurately describe, however, the horizontally averaged temperature structure derived from numerical solutions of the equations of infinite Prandtl number, Boussinesq convection. The sum of the average temperature drops across the boundary layers in such models is always greater than the super-adiabatic drop across the whole layer, with the result that some portions of the interior are sub-adiabatic. The excess average temperature drop across each boundary layer is due to the arrival of material from the other boundary layer which has not equilibrated with the well-mixed interior. It is this material which transfers heat conductively across the boundary and thus controls the heat transport of the layer. Internal heating breaks the symmetry of the boundary layers (as does temperature dependence of viscosity), and it is the interaction between the two boundary layers that sets the equilibrium temperature drops. The scaling of the temperature drop across each boundary layer is controlled by two competing factors which depend on the Rayleigh number in different ways: the scale of boundary layer instabilities and the velocity of plumes (hot and cold). Furthermore, these scalings change as the system becomes time-dependent at moderate Rayleigh number. At very high Rayleigh number, beyond that of most planetary mantles, the plumes do equilibrate with the interior and the textbook picture applies. A scaling theory for the

  18. Adiabatic Heat of Hydration Calorimetric Measurements for Reference Saltstone Waste

    SciTech Connect

    Bollinger, James

    2006-01-12

    The production of nuclear materials for weapons, medical, and space applications from the mid-1950's through the late-1980's at the Savannah River Site (SRS) generated approximately 35 million gallons of liquid high-level radioactive waste, which is currently being processed into vitrified glass for long-term storage. Upstream of the vitrification process, the waste is separated into three components: high activity insoluble sludge, high activity insoluble salt, and very low activity soluble salts. The soluble salt represents 90% of the 35 million gallons of overall waste and is processed at the SRS Saltstone Facility, where it mixed with cement, blast furnace slag, and flyash, creating a grout-like mixture. The resulting grout is pumped into aboveground storage vaults, where it hydrates into concrete monoliths, called saltstone, thus immobilizing the low-level radioactive salt waste. As the saltstone hydrates, it generates heat that slowly diffuses out of the poured material. To ensure acceptable grout properties for disposal and immobilization of the salt waste, the grout temperature must not exceed 95 C during hydration. Adiabatic calorimetric measurements of the heat generated for a representative sample of saltstone were made to determine the time-dependent heat source term. These measurements subsequently were utilized as input to a numerical conjugate heat transfer model to determine the expected peak temperatures for the saltstone vaults.

  19. Progress in the Development of a Continuous Adiabatic Demagnetization Refrigerator

    NASA Technical Reports Server (NTRS)

    Shirron, Peter; Canavan, Edgar; DiPirro, Michael; Jackson, Michael; King, Todd; Tuttle, James; Krebs, Carolyn A. (Technical Monitor)

    2002-01-01

    We report on recent progress in the development of a continuous adiabatic demagnetization refrigerator (CADR). Continuous operation avoids the constraints of long hold times and short recycle times that lead to the generally large mass of single-shot ADRs, allowing us to achieve an order of magnitude larger cooling power per unit mass. Our current design goal is 10 micro W of cooling at 50 mK using a 6-10 K heat sink. The estimated mass is less than 10 kg, including magnetic shielding of each stage. The relatively high heat rejection capability allows it to operate with a mechanical cryocooler as part of a cryogen-free, low temperature cooling system. This has the advantages of long mission life and reduced complexity and cost. We have assembled a three-stage CADR and have demonstrated continuous cooling using a superfluid helium bath as the heat sink. The temperature stability is 8 micro K rms or better over the entire cycle, and the cooling power is 2.5 micro W at 60 mK rising to 10 micro W at 100 mK.

  20. Capillary saturation and desaturation.

    PubMed

    Hilfer, R; Armstrong, R T; Berg, S; Georgiadis, A; Ott, H

    2015-12-01

    Capillary desaturation experiments produce disconnected (trapped) ganglia of mesoscopic sizes intermediate between pore size and system size. Experimental evidence for interactions between these mesoscale clusters during desaturation is analyzed and discussed within the established microscopic and macroscopic laws of Newton, Young-Laplace, and Darcy. A theoretical expression for capillary number correlations is introduced that seems to have remained unnoticed. It expresses capillary desaturation curves in terms of stationary capillary pressures and relative permeabilities. The theoretical expression shows that the plateau saturation in capillary desaturation curves may in general differ from the residual nonwetting saturation defined through the saturation limit of the main hysteresis loop. Hysteresis effects as well as the difference between wetting and nonwetting fluids are introduced into the analysis of capillary desaturation experiments. The article examines experiments with different desaturation protocols and discusses the existence of a mesoscopic length scale intermediate between pore scale and sample scale. The theoretical expression is derived entirely within the existing traditional theory of two-phase flow in porous media and compared to a recent experiment. PMID:26764820

  1. Effects of EOS adiabat on hot spot dynamics

    NASA Astrophysics Data System (ADS)

    Cheng, Baolian; Kwan, Thomas; Wang, Yi-Ming; Batha, Steven

    2013-10-01

    Equation of state (EOS) and adiabat of the pusher play significant roles in the dynamics and formation of the hot spot of an ignition capsule. For given imploding energy, they uniquely determine the partition of internal energy, mass, and volume between the pusher and the hot spot. In this work, we apply the new scaling laws recently derived by Cheng et al. to the National Ignition Campaign (NIC) ignition capsules and study the impacts of EOS and adiabat of the pusher on the hot spot dynamics by using the EOS adiabat index as an adjustable model parameter. We compare our analysis with the NIC data, specifically, for shots N120321 and N120205, and with the numerical simulations of these shots. The predictions from our theoretical model are in good agreements with the NIC data when a hot adiabat was used for the pusher, and with code simulations when a cold adiabat was used for the pusher. Our analysis indicates that the actual adiabat of the pusher in NIC experiments may well be higher than the adiabat assumed in the simulations. This analysis provides a physical and systematic explanation to the ongoing disagreements between the NIC experimental results and the multi-dimensional numerical simulations. This work was performed under the auspices of the U.S. Department of Energy by the Los Alamos National Laboratory under contract number W-7405-ENG-36.

  2. Large magnetocaloric effect and adiabatic demagnetization refrigeration with YbPt2Sn

    NASA Astrophysics Data System (ADS)

    Jang, Dongjin; Gruner, Thomas; Steppke, Alexander; Mitsumoto, Keisuke; Geibel, Christoph; Brando, Manuel

    2015-10-01

    Adiabatic demagnetization is currently gaining strong interest in searching for alternatives to 3He-based refrigeration techniques for achieving temperatures below 2 K. The main reasons for that are the recent shortage and high price of the rare helium isotope 3He. Here we report the discovery of a large magnetocaloric effect in the intermetallic compound YbPt2Sn, which allows adiabatic demagnetization cooling from 2 K down to 0.2 K. We demonstrate this with a home-made refrigerator. Other materials, for example, paramagnetic salts, are commonly used for the same purpose but none of them is metallic, a severe limitation for low-temperature applications. YbPt2Sn is a good metal with an extremely rare weak magnetic coupling between the Yb atoms, which prevents them from ordering above 0.25 K, leaving enough entropy free for use in adiabatic demagnetization cooling. The large volumetric entropy capacity of YbPt2Sn guarantees also a good cooling power.

  3. Large magnetocaloric effect and adiabatic demagnetization refrigeration with YbPt2Sn

    PubMed Central

    Jang, Dongjin; Gruner, Thomas; Steppke, Alexander; Mitsumoto, Keisuke; Geibel, Christoph; Brando, Manuel

    2015-01-01

    Adiabatic demagnetization is currently gaining strong interest in searching for alternatives to 3He-based refrigeration techniques for achieving temperatures below 2 K. The main reasons for that are the recent shortage and high price of the rare helium isotope 3He. Here we report the discovery of a large magnetocaloric effect in the intermetallic compound YbPt2Sn, which allows adiabatic demagnetization cooling from 2 K down to 0.2 K. We demonstrate this with a home-made refrigerator. Other materials, for example, paramagnetic salts, are commonly used for the same purpose but none of them is metallic, a severe limitation for low-temperature applications. YbPt2Sn is a good metal with an extremely rare weak magnetic coupling between the Yb atoms, which prevents them from ordering above 0.25 K, leaving enough entropy free for use in adiabatic demagnetization cooling. The large volumetric entropy capacity of YbPt2Sn guarantees also a good cooling power. PMID:26493166

  4. Optimality of partial adiabatic search and its circuit model

    NASA Astrophysics Data System (ADS)

    Mei, Ying; Sun, Jie; Lu, Songfeng; Gao, Chao

    2014-08-01

    In this paper, we first uncover a fact that a partial adiabatic quantum search with time complexity is in fact optimal, in which is the total number of elements in an unstructured database, and () of them are the marked ones(one) . We then discuss how to implement a partial adiabatic search algorithm on the quantum circuit model. From the implementing procedure on the circuit model, we can find out that the approximating steps needed are always in the same order of the time complexity of the adiabatic algorithm.

  5. Adiabatic control of atomic dressed states for transport and sensing

    NASA Astrophysics Data System (ADS)

    Cooper, N. R.; Rey, A. M.

    2015-08-01

    We describe forms of adiabatic transport that arise for dressed-state atoms in optical lattices. Focusing on the limit of weak tunnel-coupling between nearest-neighbor lattice sites, we explain how adiabatic variation of optical dressing allows control of atomic motion between lattice sites: allowing adiabatic particle transport in a direction that depends on the internal state, and force measurements via spectroscopic preparation and readout. For uniformly filled bands these systems display topologically quantized particle transport. An implementation of the dressing scheme using optical transitions in alkaline-earth atoms is discussed as well as its favorable features for precise force sensing.

  6. Adiabatic Deceleration Effects on the Formation of Heavy Ion Charge Spectra in Interplanetary Space

    NASA Astrophysics Data System (ADS)

    Kartavykh, J. J.; Dröge, W.; Kovaltsov, G. A.; Ostryakov, V. M.

    2005-03-01

    We investigate the effects of interplanetary propagation on the energy dependence of the mean ionic charge of ~0.1 1 MeV/n iron observed during impulsive solar particle events at 1 AU. A Monte-Carlo approach is applied to solve the transport equation which takes into account spatial diffusion as well as convection and adiabatic deceleration. We find that interplanetary propagation results in a shift of charge spectra observed at 1 AU towards lower energies due to adiabatic deceleration. Taking the above effect into account, we compare predictions of our model of charge-consistent stochastic acceleration with recent ACE observations. A detailed analysis of two particle events shows that our model can give a consistent explanation of the observed iron charge and energy spectra, and allows one to put constraints on the temperature, density, and the acceleration and escape time scales in the acceleration region.

  7. Topological States and Adiabatic Pumping in Quasicrystals

    NASA Astrophysics Data System (ADS)

    Kraus, Yaakov; Lahini, Yoav; Ringel, Zohar; Verbin, Mor; Zilberberg, Oded

    2012-02-01

    We find a connection between quasicrystals and topological matter, namely that quasicrystals exhibit non-trivial topological phases attributed to dimensions higher than their own [1]. Quasicrystals are materials which are neither ordered nor disordered, i.e. they exhibit only long-range order [2]. This long-range order is usually expressed as a projection from a higher dimensional ordered system. Recently, the unrelated discovery of Topological Insulators [3] defined a new type of materials classified by their topology. We show theoretically and experimentally using photonic lattices, that one-dimensional quasicrystals exhibit topologically-protected boundary states equivalent to the edge states of the two-dimensional Integer Quantum Hall Effect. We harness this property to adiabatically pump light across the quasicrystal, and generalize our results to higher dimensional systems. Hence, quasicrystals offer a new platform for the study of topological phases while their topology may better explain their surface properties.[4pt] [1] Y. E. Kraus, Y. Lahini, Z. Ringel, M. Verbin, and O. Zilberberg, arXiv:1109.5983 (2011).[0pt] [2] C. Janot, Quasicrystals (Clarendon, Oxford, 1994), 2nd ed.[0pt] [3] M. Z. Hasan and C. L. Kane, Rev. Mod. Phys. 82, 3045 (2010).

  8. On the persistence of adiabatic shear bands

    NASA Astrophysics Data System (ADS)

    Boakye-Yiadom, S.; Bassim, M. N.; Al-Ameeri, S.

    2012-08-01

    It is generally agreed that the initiation and development of adiabatic shear bands (ASBs) are manifestations of damage in metallic materials subjected to high strain rates and large strains as those due to impact in a Hopkinson Bar system. Models for evolution of these bands have been described in the literature. One question that has not received attention is how persistent these bands are and whether their presence and effect can be reversed or eliminated by using a process of thermal (heat treatment) or thermo-mechanical treatment that would relieve the material from the high strain associated with ASBs and their role as precursors to crack initiation and subsequent failure. Since ASBs are more prevalent and more defined in BCC metals including steels, a study was conducted to investigate the best conditions of generating ASBs in a heat treatable steel, followed by determining the best conditions for heat treatment of specimens already damaged by the presence of ASBs in order to relieve the strains due to ASBs and restore the material to an apparent microstructure without the "scars" due to the previous presence of ASBs. It was found that heat treatment achieves the curing from ASBs. This presentation documents the process undertaken to achieve this objective.

  9. Adiabatic quantum algorithm for search engine ranking.

    PubMed

    Garnerone, Silvano; Zanardi, Paolo; Lidar, Daniel A

    2012-06-01

    We propose an adiabatic quantum algorithm for generating a quantum pure state encoding of the PageRank vector, the most widely used tool in ranking the relative importance of internet pages. We present extensive numerical simulations which provide evidence that this algorithm can prepare the quantum PageRank state in a time which, on average, scales polylogarithmically in the number of web pages. We argue that the main topological feature of the underlying web graph allowing for such a scaling is the out-degree distribution. The top-ranked log(n) entries of the quantum PageRank state can then be estimated with a polynomial quantum speed-up. Moreover, the quantum PageRank state can be used in "q-sampling" protocols for testing properties of distributions, which require exponentially fewer measurements than all classical schemes designed for the same task. This can be used to decide whether to run a classical update of the PageRank. PMID:23003933

  10. Graph isomorphism and adiabatic quantum computing

    NASA Astrophysics Data System (ADS)

    Gaitan, Frank; Clark, Lane

    2014-03-01

    In the Graph Isomorphism (GI) problem two N-vertex graphs G and G' are given and the task is to determine whether there exists a permutation of the vertices of G that preserves adjacency and maps G --> G'. If yes (no), then G and G' are said to be isomorphic (non-isomorphic). The GI problem is an important problem in computer science and is thought to be of comparable difficulty to integer factorization. We present a quantum algorithm that solves arbitrary instances of GI, and which provides a novel approach to determining all automorphisms of a graph. The algorithm converts a GI instance to a combinatorial optimization problem that can be solved using adiabatic quantum evolution. Numerical simulation of the algorithm's quantum dynamics shows that it correctly distinguishes non-isomorphic graphs; recognizes isomorphic graphs; and finds the automorphism group of a graph. We also discuss the algorithm's experimental implementation and show how it can be leveraged to solve arbitrary instances of the NP-Complete Sub-Graph Isomorphism problem.

  11. Saturation current in solar cells - An analysis

    NASA Astrophysics Data System (ADS)

    Ravindra, N. M.

    1980-10-01

    An analysis of the saturation current in solar cells indicates that the factor A in the Shockley equation is material independent and has a constant value of 2.95 x 10 to the 5th A per sq cm of the cell. The saturation current, I(0), and a fundamental solid state parameter, the 0 K Debye temperature, are explicitly correlated on the basis of the work of Ravindra and Srivastava (1979). It is shown that dLnI(0)/dT increases with the energy gap at 0 K.

  12. Adiabaticity and spectral splits in collective neutrino transformations

    SciTech Connect

    Raffelt, Georg G.; Smirnov, Alexei Yu.

    2007-12-15

    Neutrinos streaming off a supernova core transform collectively by neutrino-neutrino interactions, leading to 'spectral splits' where an energy E{sub split} divides the transformed spectrum sharply into parts of almost pure but different flavors. We present a detailed description of the spectral-split phenomenon which is conceptually and quantitatively understood in an adiabatic treatment of neutrino-neutrino effects. Central to this theory is a self-consistency condition in the form of two sum rules (integrals over the neutrino spectra that must equal certain conserved quantities). We provide explicit analytic and numerical solutions for various neutrino spectra. We introduce the concept of the adiabatic reference frame and elaborate on the relative adiabatic evolution. Violating adiabaticity leads to the spectral split being 'washed out'. The sharpness of the split appears to be represented by a surprisingly universal function.

  13. Adiabatic rotation, quantum search, and preparation of superposition states

    NASA Astrophysics Data System (ADS)

    Siu, M. Stewart

    2007-06-01

    We introduce the idea of using adiabatic rotation to generate superpositions of a large class of quantum states. For quantum computing this is an interesting alternative to the well-studied “straight line” adiabatic evolution. In ways that complement recent results, we show how to efficiently prepare three types of states: Kitaev’s toric code state, the cluster state of the measurement-based computation model, and the history state used in the adiabatic simulation of a quantum circuit. We also show that the method, when adapted for quantum search, provides quadratic speedup as other optimal methods do with the advantages that the problem Hamiltonian is time independent and that the energy gap above the ground state is strictly nondecreasing with time. Likewise the method can be used for optimization as an alternative to the standard adiabatic algorithm.

  14. Coherent transfer by adiabatic passage in two-dimensional lattices

    SciTech Connect

    Longhi, Stefano

    2014-09-15

    Coherent tunneling by adiabatic passage (CTAP) is a well-established technique for robust spatial transport of quantum particles in linear chains. Here we introduce two exactly-solvable models where the CTAP protocol can be extended to two-dimensional lattice geometries. Such bi-dimensional lattice models are synthesized from time-dependent second-quantization Hamiltonians, in which the bosonic field operators evolve adiabatically like in an ordinary three-level CTAP scheme thus ensuring adiabatic passage in Fock space. - Highlights: • New ways of coherent transport by adiabatic passage (CTAP) in 2D lattices. • Synthesis of exactly-solvable 2D lattices from a simple three-well model. • CTAP in 2D lattices can be exploited for quantum state transfer.

  15. Adiabatic and isocurvature perturbation projections in multi-field inflation

    SciTech Connect

    Gordon, Chris; Saffin, Paul M. E-mail: Paul.Saffin@nottingham.ac.uk

    2013-08-01

    Current data are in good agreement with the predictions of single field inflation. However, the hemispherical asymmetry, seen in the cosmic microwave background data, may hint at a potential problem. Generalizing to multi-field models may provide one possible explanation. A useful way of modeling perturbations in multi-field inflation is to investigate the projection of the perturbation along and perpendicular to the background fields' trajectory. These correspond to the adiabatic and isocurvature perturbations. However, it is important to note that in general there are no corresponding adiabatic and isocurvature fields. The purpose of this article is to highlight the distinction between a field redefinition and a perturbation projection. We provide a detailed derivation of the evolution of the isocurvature perturbation to show that no assumption of an adiabatic or isocurvature field is needed. We also show how this evolution equation is consistent with the field covariant evolution equations for the adiabatic perturbation in the flat field space limit.

  16. Ultrafast stimulated Raman parallel adiabatic passage by shaped pulses

    SciTech Connect

    Dridi, G.; Guerin, S.; Hakobyan, V.; Jauslin, H. R.; Eleuch, H.

    2009-10-15

    We present a general and versatile technique of population transfer based on parallel adiabatic passage by femtosecond shaped pulses. Their amplitude and phase are specifically designed to optimize the adiabatic passage corresponding to parallel eigenvalues at all times. We show that this technique allows the robust adiabatic population transfer in a Raman system with the total pulse area as low as 3{pi}, corresponding to a fluence of one order of magnitude below the conventional stimulated Raman adiabatic passage process. This process of short duration, typically picosecond and subpicosecond, is easily implementable with the modern pulse shaper technology and opens the possibility of ultrafast robust population transfer with interesting applications in quantum information processing.

  17. Adiabatic Compression Sensitivity of Liquid Fuels and Monopropellants

    NASA Technical Reports Server (NTRS)

    Ismail, Ismail M. K.; Hawkins, Tom W.

    2000-01-01

    Liquid rocket propellants can be sensitive to rapid compression. Such liquids may undergo decomposition and their handling may be accompanied with risk. Decomposition produces small gas bubbles in the liquid, which upon rapid compression may cause catastrophic explosions. The rapid compression can result from mechanical shocks applied on the tank containing the liquid or from rapid closure of the valves installed on the lines. It is desirable to determine the conditions that may promote explosive reactions. At Air Force Research Laboratory (AFRL), we constructed an apparatus and established a safe procedure for estimating the sensitivity of propellant materials towards mechanical shocks (Adiabatic Compression Tester). A sample is placed on a stainless steel U-tube, held isothermally at a temperature between 20 and 150 C then exposed to an abrupt mechanical shock of nitrogen gas at a pressure between 6.9 and 20.7 MPa (1000 to 3000 psi). The apparatus is computer interfaced and is driven with LABTECH NOTEBOOK-pro (registered) Software. In this presentation, the design of the apparatus is shown, the operating procedure is outlined, and the safety issues are addressed. The results obtained on different energetic materials are presented.

  18. H2O-fluid-saturated melting of subducted continental crust facilitates exhumation of ultrahigh-pressure rocks in continental subduction zones

    NASA Astrophysics Data System (ADS)

    Labrousse, L.; Duretz, T.; Gerya, T.

    2015-10-01

    We present two-dimensional numerical models of plate subduction and collision inspired by the Scandinavian Caledonian orogeny to investigate the possible impact of continental crust partial melting on the exhumation of ultra-high pressure metamorphic rocks. Three possible reactions were tested: low temperature solidus representing H2O-fluid-saturated partial melting, and two end-member reaction curves for dehydration melting. Thermo-mechanical effects of partial melting were implemented as (1) a viscosity decrease as a determined rheologically critical melt percentage was reached (here 0.1), (2) a change in effective heat capacity and adiabatic heating/cooling accounting for a latent heat term in the heat equation. Among the 3 tested reactions, only H2O-fluid-saturated partial melting drastically modifies the collision dynamics from the non-melting reference model holding all other parameters constant. A substantially low general viscosity truncation (here 1017 Pa s) is needed to properly resolve the effect of partial melting on deep collision processes. Low temperature melting indeed induces the development of a low viscosity buoyant plume prior to slab detachment, where migmatites exhume from UHP conditions at rates and with pressure-temperature paths similar to the natural values acknowledged for the Norwegian Caledonides. High temperature melting has no drastic influence on early collision dynamics. While positive buoyancy remains the first order driver for the exhumation of buried continental rocks, exhumation initiates in these cases with eduction subsequent to slab detachment. Melting and formation of a migmatite plume can later occur along decompression path while continental crust undergoes thermal reequilibration at temperatures above 900 °C. Some of the partially molten material can also relaminate in the overriding plate rather than exhume within the collision zone. Even if minor in terms of amount of magma produced, H2O-fluid-saturated partial melting

  19. Adiabatic invariant value variation under shortwave band subcritical conditions

    NASA Astrophysics Data System (ADS)

    Svistunov, K. V.; Tinin, M. V.

    1985-04-01

    The possibility of significant variations of the adiabatic invariant is examined for the propagation of radio waves in an irregular Earth-ionosphere waveguide with a parabolic dependence of permittivity on height. Numerical and analytical results indicate that nonexponential deviations of the adiabatic invariant can occur not only when the characteristic size of horizontal irregularity decreases (e.g., during resonant beam excitation) but also in quasi-critical conditions and for smoothly irregular waveguides.

  20. Shortcuts to adiabaticity for non-Hermitian systems

    SciTech Connect

    Ibanez, S.; Martinez-Garaot, S.; Torrontegui, E.; Muga, J. G.; Chen Xi

    2011-08-15

    Adiabatic processes driven by non-Hermitian, time-dependent Hamiltonians may be sped up by generalizing inverse engineering techniques based on counter-diabatic (transitionless driving) algorithms or on dynamical invariants. We work out the basic theory and examples described by two-level Hamiltonians: the acceleration of rapid adiabatic passage with a decaying excited level and of the dynamics of a classical particle on an expanding harmonic oscillator.

  1. Experimental aspects of the adiabatic approach in estimating the effect of electron screening on alpha decay

    SciTech Connect

    Karpeshin, F. F.; Trzhaskovskaya, M. B.

    2015-12-15

    Special features of the effect of the electron shell on alpha decay that have important experimental implications are studied within the adiabatic approach. The magnitude of the effect is about several tenths of a percent or smaller, depending on the transition energy and on the atomic number. A dominant role of inner shells is shown: more than 80% of the effect is saturated by 1s electrons. This circumstance plays a crucial role for experiments, making it possible to measure this small effect by a difference method in the same storage rings via a comparison of, for example, decay probabilities in bare nuclei and heliumlike ions. The reasons behind the relative success and the applicability limits of the frozen-shell model, which has been used to calculate the effect in question for more than half a century, are analyzed. An interesting experiment aimed at studying charged alpha-particle states is proposed. This experiment will furnish unique information for testing our ideas of the interplay of nonadiabatic and adiabatic processes.

  2. Saturated Zone Colloid Transport

    SciTech Connect

    H. S. Viswanathan

    2004-10-07

    This scientific analysis provides retardation factors for colloids transporting in the saturated zone (SZ) and the unsaturated zone (UZ). These retardation factors represent the reversible chemical and physical filtration of colloids in the SZ. The value of the colloid retardation factor, R{sub col} is dependent on several factors, such as colloid size, colloid type, and geochemical conditions (e.g., pH, Eh, and ionic strength). These factors are folded into the distributions of R{sub col} that have been developed from field and experimental data collected under varying geochemical conditions with different colloid types and sizes. Attachment rate constants, k{sub att}, and detachment rate constants, k{sub det}, of colloids to the fracture surface have been measured for the fractured volcanics, and separate R{sub col} uncertainty distributions have been developed for attachment and detachment to clastic material and mineral grains in the alluvium. Radionuclides such as plutonium and americium sorb mostly (90 to 99 percent) irreversibly to colloids (BSC 2004 [DIRS 170025], Section 6.3.3.2). The colloid retardation factors developed in this analysis are needed to simulate the transport of radionuclides that are irreversibly sorbed onto colloids; this transport is discussed in the model report ''Site-Scale Saturated Zone Transport'' (BSC 2004 [DIRS 170036]). Although it is not exclusive to any particular radionuclide release scenario, this scientific analysis especially addresses those scenarios pertaining to evidence from waste-degradation experiments, which indicate that plutonium and americium may be irreversibly attached to colloids for the time scales of interest. A section of this report will also discuss the validity of using microspheres as analogs to colloids in some of the lab and field experiments used to obtain the colloid retardation factors. In addition, a small fraction of colloids travels with the groundwater without any significant retardation

  3. Coupled thermal, electrical, and fluid flow analyses of AMTEC multitube cell with adiabatic side wall

    NASA Astrophysics Data System (ADS)

    Schock, A.; Or, C.; Noravian, H.

    1997-01-01

    The paper describes a novel OSC-generated methodology for analyzing the performance of multitube AMTEC (Alkali Metal Thermal-to-Electrical Conversion) cells, which are under development by AMPS (Advanced Modular Power Systems, Inc.) for the Air Force Phillips Laboratory (AFPL) and NASA's Jet Propulsion Laboratory (JPL), for possible application to the Pluto Express and other space missions. The OSC study was supported by the Department of Energy (DOE), and was strongly encouraged by JPL, AFPL, and AMPS. It resulted in an iterative procedure for the coupled solution of the interdependent thermal, electrical, and fluid flow differential and integral equations governing the performance of AMTEC cells and generators. The paper clarifies the OSC procedure by presenting detailed results of its application to an illustrative example of a converter cell with an adiabatic side wall, including the non-linear axial variation of temperature, pressure, open-circuit voltage, interelectrode voltage, current density, axial current, sodium mass flow, and power density. The next paper in these proceedings describes parametric results obtained by applying the same procedure to variations of the baseline adiabatic converter design, culminating in an OSC-recommended revised cell design. A subsequent paper in these proceedings extends the procedure to analyze a variety of OSC-designed radioisotope-heated generators employing non-adiabatic multitube AMTEC cells.

  4. Adiabatic Effectiveness and Heat Transfer Coefficient on a Film-Cooled Rotating Blade

    NASA Technical Reports Server (NTRS)

    Garg, Vijay K.

    1997-01-01

    three-dimensional Navier-Stokes code has been used to compute the adiabatic effectiveness and heat transfer coefficient on a rotating film-cooled turbine blade. The blade chosen is the United Technologies Research Center(UTRC) rotor with five film-cooling rows containing 83 holes, including three rows on the shower head with 49 holes, covering about 86% of the blade span. The mainstream is akin to that under real engine conditions with stagnation temperature 1900 K and stagnation pressure 3 MPa. The blade speed is taken to be 5200 rpm. The adiabatic effectiveness is higher for a rotating blade as compared to that for a stationary blade. Also, the direction of coolant injection from the shower-head holes considerably affects the effectiveness and heat transfer coefficient values on both the pressure and suction surfaces. In all cases the heat transfer coefficient and adiabatic effectiveness are highly three-dimensional in the vicinity of holes but tend to become two-dimensional far downstream.

  5. Zero-point energy, tunnelling, and vibrational adiabaticity in the Mu + H2 reaction

    NASA Astrophysics Data System (ADS)

    Mielke, Steven L.; Garrett, Bruce C.; Fleming, Donald G.; Truhlar, Donald G.

    2015-01-01

    Isotopic substitution of muonium for hydrogen provides an unparalleled opportunity to deepen our understanding of quantum mass effects on chemical reactions. A recent topical review in this journal of the thermal and vibrationally state-selected reaction of Mu with H2 raises a number of issues that are addressed here. We show that some earlier quantum mechanical calculations of the Mu + H2 reaction, which are highlighted in this review, and which have been used to benchmark approximate methods, are in error by as much as 19% in the low-temperature limit. We demonstrate that an approximate treatment of the Born-Oppenheimer diagonal correction that was used in some recent studies is not valid for treating the vibrationally state-selected reaction. We also discuss why vibrationally adiabatic potentials that neglect bend zero-point energy are not a useful analytical tool for understanding reaction rates, and why vibrationally non-adiabatic transitions cannot be understood by considering tunnelling through vibrationally adiabatic potentials. Finally, we present calculations on a hierarchical family of potential energy surfaces to assess the sensitivity of rate constants to the quality of the potential surface.

  6. Facts about saturated fats

    MedlinePlus

    ... with trans fat . These fats are most often solid at room temperature. Foods like butter, palm and ... products (butter, ice cream, pudding, cheese, whole milk) Solid fats such as coconut oil, palm, and palm ...

  7. Super-heavy electron material as metallic refrigerant for adiabatic demagnetization cooling

    PubMed Central

    Tokiwa, Yoshifumi; Piening, Boy; Jeevan, Hirale S.; Bud’ko, Sergey L.; Canfield, Paul C.; Gegenwart, Philipp

    2016-01-01

    Low-temperature refrigeration is of crucial importance in fundamental research of condensed matter physics, because the investigations of fascinating quantum phenomena, such as superconductivity, superfluidity, and quantum criticality, often require refrigeration down to very low temperatures. Currently, cryogenic refrigerators with 3He gas are widely used for cooling below 1 K. However, usage of the gas has been increasingly difficult because of the current worldwide shortage. Therefore, it is important to consider alternative methods of refrigeration. We show that a new type of refrigerant, the super-heavy electron metal YbCo2Zn20, can be used for adiabatic demagnetization refrigeration, which does not require 3He gas. This method has a number of advantages, including much better metallic thermal conductivity compared to the conventional insulating refrigerants. We also demonstrate that the cooling performance is optimized in Yb1−xScxCo2Zn20 by partial Sc substitution, with x ~ 0.19. The substitution induces chemical pressure that drives the materials to a zero-field quantum critical point. This leads to an additional enhancement of the magnetocaloric effect in low fields and low temperatures, enabling final temperatures well below 100 mK. This performance has, up to now, been restricted to insulators. For nearly a century, the same principle of using local magnetic moments has been applied for adiabatic demagnetization cooling. This study opens new possibilities of using itinerant magnetic moments for cryogen-free refrigeration.

  8. Super-heavy electron material as metallic refrigerant for adiabatic demagnetization cooling

    PubMed Central

    Tokiwa, Yoshifumi; Piening, Boy; Jeevan, Hirale S.; Bud’ko, Sergey L.; Canfield, Paul C.; Gegenwart, Philipp

    2016-01-01

    Low-temperature refrigeration is of crucial importance in fundamental research of condensed matter physics, because the investigations of fascinating quantum phenomena, such as superconductivity, superfluidity, and quantum criticality, often require refrigeration down to very low temperatures. Currently, cryogenic refrigerators with 3He gas are widely used for cooling below 1 K. However, usage of the gas has been increasingly difficult because of the current worldwide shortage. Therefore, it is important to consider alternative methods of refrigeration. We show that a new type of refrigerant, the super-heavy electron metal YbCo2Zn20, can be used for adiabatic demagnetization refrigeration, which does not require 3He gas. This method has a number of advantages, including much better metallic thermal conductivity compared to the conventional insulating refrigerants. We also demonstrate that the cooling performance is optimized in Yb1−xScxCo2Zn20 by partial Sc substitution, with x ~ 0.19. The substitution induces chemical pressure that drives the materials to a zero-field quantum critical point. This leads to an additional enhancement of the magnetocaloric effect in low fields and low temperatures, enabling final temperatures well below 100 mK. This performance has, up to now, been restricted to insulators. For nearly a century, the same principle of using local magnetic moments has been applied for adiabatic demagnetization cooling. This study opens new possibilities of using itinerant magnetic moments for cryogen-free refrigeration. PMID:27626073

  9. Super-heavy electron material as metallic refrigerant for adiabatic demagnetization cooling.

    PubMed

    Tokiwa, Yoshifumi; Piening, Boy; Jeevan, Hirale S; Bud'ko, Sergey L; Canfield, Paul C; Gegenwart, Philipp

    2016-09-01

    Low-temperature refrigeration is of crucial importance in fundamental research of condensed matter physics, because the investigations of fascinating quantum phenomena, such as superconductivity, superfluidity, and quantum criticality, often require refrigeration down to very low temperatures. Currently, cryogenic refrigerators with (3)He gas are widely used for cooling below 1 K. However, usage of the gas has been increasingly difficult because of the current worldwide shortage. Therefore, it is important to consider alternative methods of refrigeration. We show that a new type of refrigerant, the super-heavy electron metal YbCo2Zn20, can be used for adiabatic demagnetization refrigeration, which does not require (3)He gas. This method has a number of advantages, including much better metallic thermal conductivity compared to the conventional insulating refrigerants. We also demonstrate that the cooling performance is optimized in Yb1-x Sc x Co2Zn20 by partial Sc substitution, with x ~ 0.19. The substitution induces chemical pressure that drives the materials to a zero-field quantum critical point. This leads to an additional enhancement of the magnetocaloric effect in low fields and low temperatures, enabling final temperatures well below 100 mK. This performance has, up to now, been restricted to insulators. For nearly a century, the same principle of using local magnetic moments has been applied for adiabatic demagnetization cooling. This study opens new possibilities of using itinerant magnetic moments for cryogen-free refrigeration. PMID:27626073

  10. Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + Ca(NO3)2 + H2O, NaNO3 + KNO3 + H2O, and NaCl + KNO3 + H2O, and Dry Out Temperatures for NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O

    SciTech Connect

    Rard, J A

    2005-11-29

    Boiling temperature measurements have been made for saturated ternary solutions of NaCl + KNO{sub 3} + H{sub 2}O and NaNO{sub 3} + KNO{sub 3} + H{sub 2}O at three selected salt ratios and for NaCl + Ca(NO{sub 3}){sub 2} + H{sub 2}O over the full composition range. The maximum boiling temperature found for the NaCl + Ca(NO{sub 3}){sub 2} + H{sub 2}O system is 164.7 {+-} 0.6 C, and the composition is estimated to occur at x(Ca(NO{sub 3}){sub 2}) {approx} 0.25. Experiments were also performed for the five component NaCl + NaNO{sub 3} + KNO{sub 3} + Ca(NO{sub 3}){sub 2} + H{sub 2}O mixtures with the molar ratio of NaCl:NaNO{sub 3}:KNO{sub 3} held essentially constant at 1:0.9780:1.1468 as the solute mole fraction of Ca(NO{sub 3}){sub 2}, x(Ca(NO{sub 3}){sub 2}), was varied between 0 and 0.25. The NaCl + NaNO{sub 3} + KNO{sub 3} + Ca(NO{sub 3}){sub 2} + H{sub 2}O system forms low melting mixtures and thus boiling temperatures for saturated were not determined. Instead, the temperatures corresponding to the cessation of boiling (i.e., dry out temperatures) of these liquid mixtures were determined. These dry out temperatures range from {approx} 300 C when x(Ca(NO{sub 3}){sub 2}) = 0 to {ge} 400 C when x(Ca(NO{sub 3}){sub 2}) = 0.20 and 0.25. The investigated mixture compositions correspond to some of the major mineral assemblages that are predicted to control the deliquescence relative humidity of salts formed by leaching dust samples from the proposed nuclear repository at Yucca Mountain, Nevada.

  11. Adiabatic continuity, wave-function overlap, and topological phase transitions

    NASA Astrophysics Data System (ADS)

    Gu, Jiahua; Sun, Kai

    2016-09-01

    In this paper, we study the relation between wave-function overlap and adiabatic continuity in gapped quantum systems. We show that for two band insulators, a scalar function can be defined in the momentum space, which characterizes the wave-function overlap between Bloch states in the two insulators. If this overlap is nonzero for all momentum points in the Brillouin zone, these two insulators are adiabatically connected, i.e., we can deform one insulator into the other smoothly without closing the band gap. In addition, we further prove that this adiabatic path preserves all the symmetries of the insulators. The existence of such an adiabatic path implies that two insulators with nonzero wave-function overlap belong to the same topological phase. This relation, between adiabatic continuity and wave-function overlap, can be further generalized to correlated systems. The generalized relation cannot be applied to study generic many-body systems in the thermodynamic limit, because of the orthogonality catastrophe. However, for certain interacting systems (e.g., quantum Hall systems), the quantum wave-function overlap can be utilized to distinguish different quantum states. Experimental implications are also discussed.

  12. Adiabatic condition and the quantum hitting time of Markov chains

    SciTech Connect

    Krovi, Hari; Ozols, Maris; Roland, Jeremie

    2010-08-15

    We present an adiabatic quantum algorithm for the abstract problem of searching marked vertices in a graph, or spatial search. Given a random walk (or Markov chain) P on a graph with a set of unknown marked vertices, one can define a related absorbing walk P{sup '} where outgoing transitions from marked vertices are replaced by self-loops. We build a Hamiltonian H(s) from the interpolated Markov chain P(s)=(1-s)P+sP{sup '} and use it in an adiabatic quantum algorithm to drive an initial superposition over all vertices to a superposition over marked vertices. The adiabatic condition implies that, for any reversible Markov chain and any set of marked vertices, the running time of the adiabatic algorithm is given by the square root of the classical hitting time. This algorithm therefore demonstrates a novel connection between the adiabatic condition and the classical notion of hitting time of a random walk. It also significantly extends the scope of previous quantum algorithms for this problem, which could only obtain a full quadratic speedup for state-transitive reversible Markov chains with a unique marked vertex.

  13. Controls on Highly Siderophile Element Concentrations in Martian Basalt: Sulfide Saturation and Under-Saturation

    NASA Technical Reports Server (NTRS)

    Righter, Kevin

    2009-01-01

    Highly siderophile elements (HSE; Re, Au and the platinum group elements) in shergottites exhibit a wide range from very high, similar to the terrestrial mantle, to very low, similar to sulfide saturated mid ocean ridge basalt (e.g., [1]). This large range has been difficult to explain without good constraints on sulfide saturation or under-saturation [2]. A new model for prediction of sulfide saturation places new constraints on this problem [3]. Shergottite data: For primitive shergottites, pressure and temperature estimates are between 1.2-1.5 GPa, and 1350-1470 C [4]. The range of oxygen fugacities is from FMQ-2 to IW, where the amount of Fe2O3 is low and thus does not have a significant effect on the S saturation values. Finally, the bulk compositions of shergottites have been reported in many recent studies (e.g., [5]). All of this information will be used to test whether shergottites are sulfide saturated [3]. Modeling values and results: The database for HSE partition coefficients has been growing with many new data for silicates and oxides [6-8] to complement a large sulfide database [9- 11]. Combining these data with simple batch melting models allows HSE contents of mantle melts to be estimated for sulfide-bearing vs. sulfide-free mantle. Combining such models with fractional crystallization modeling (e.g., [12]) allows HSE contents of more evolved liquids to be modeled. Most primitive shergottites have high HSE contents (and low S contents) that can be explained by sulfide under-saturated melting of the mantle. An exception is Dhofar 019 which has high S contents and very low HSE contents suggesting sulfide saturation. Most evolved basaltic shergottites have lower S contents than saturation, and intermediate HSE contents that can be explained by olivine, pyroxene, and chromite fractionation. An exception is EET A79001 lithology B, which has very low HSE contents and S contents higher than sulfide saturation values . evidence for sulfide saturation

  14. Heat and mass transfer at adiabatic evaporation of binary zeotropic solutions

    NASA Astrophysics Data System (ADS)

    Makarov, M. S.; Makarova, S. N.

    2016-01-01

    Results of numerical simulation of heat and mass transfer in a laminar flow of three-component gas at adiabatic evaporation of binary solutions from a flat plate are presented. The studies were carried out for the perfect solution of ethanol/methanol and zeotrope solutions of water/acetone, benzene/acetone, and ethanol/acetone. The liquid-vapor equilibrium is described by the Raoult law for the ideal solution and Carlson-Colburn model for real solutions. The effect of gas temperature and liquid composition on the heat and diffusion flows, and temperature of vapor-gas mixture at the interface is analyzed. The formula for calculating the temperature of the evaporation surface for the binary liquid mixtures using the similarity of heat and mass transfer was proposed. Data of numerical simulations are in a good agreement with the results of calculations based on the proposed dependence for all examined liquid mixtures in the considered range of temperatures and pressures.

  15. Shortcuts to adiabaticity in a time-dependent box

    PubMed Central

    Campo, A. del; Boshier, M. G.

    2012-01-01

    A method is proposed to drive an ultrafast non-adiabatic dynamics of an ultracold gas trapped in a time-dependent box potential. The resulting state is free from spurious excitations associated with the breakdown of adiabaticity, and preserves the quantum correlations of the initial state up to a scaling factor. The process relies on the existence of an adiabatic invariant and the inversion of the dynamical self-similar scaling law dictated by it. Its physical implementation generally requires the use of an auxiliary expulsive potential. The method is extended to a broad family of interacting many-body systems. As illustrative examples we consider the ultrafast expansion of a Tonks-Girardeau gas and of Bose-Einstein condensates in different dimensions, where the method exhibits an excellent robustness against different regimes of interactions and the features of an experimentally realizable box potential. PMID:22970340

  16. Shortcuts to adiabaticity in a time-dependent box.

    PubMed

    del Campo, A; Boshier, M G

    2012-01-01

    A method is proposed to drive an ultrafast non-adiabatic dynamics of an ultracold gas trapped in a time-dependent box potential. The resulting state is free from spurious excitations associated with the breakdown of adiabaticity, and preserves the quantum correlations of the initial state up to a scaling factor. The process relies on the existence of an adiabatic invariant and the inversion of the dynamical self-similar scaling law dictated by it. Its physical implementation generally requires the use of an auxiliary expulsive potential. The method is extended to a broad family of interacting many-body systems. As illustrative examples we consider the ultrafast expansion of a Tonks-Girardeau gas and of Bose-Einstein condensates in different dimensions, where the method exhibits an excellent robustness against different regimes of interactions and the features of an experimentally realizable box potential.

  17. Shortcuts to adiabaticity in a time-dependent box

    NASA Astrophysics Data System (ADS)

    Del Campo, A.; Boshier, M. G.

    2012-09-01

    A method is proposed to drive an ultrafast non-adiabatic dynamics of an ultracold gas trapped in a time-dependent box potential. The resulting state is free from spurious excitations associated with the breakdown of adiabaticity, and preserves the quantum correlations of the initial state up to a scaling factor. The process relies on the existence of an adiabatic invariant and the inversion of the dynamical self-similar scaling law dictated by it. Its physical implementation generally requires the use of an auxiliary expulsive potential. The method is extended to a broad family of interacting many-body systems. As illustrative examples we consider the ultrafast expansion of a Tonks-Girardeau gas and of Bose-Einstein condensates in different dimensions, where the method exhibits an excellent robustness against different regimes of interactions and the features of an experimentally realizable box potential.

  18. Effect of dephasing on stimulated Raman adiabatic passage

    SciTech Connect

    Ivanov, P.A.; Vitanov, N.V.; Bergmann, K.

    2004-12-01

    This work explores the effect of phase relaxation on the population transfer efficiency in stimulated Raman adiabatic passage (STIRAP). The study is based on the Liouville equation, which is solved analytically in the adiabatic limit. The transfer efficiency of STIRAP is found to decrease exponentially with the dephasing rate; this effect is stronger for shorter pulse delays and weaker for larger delays, since the transition time is found to be inversely proportional to the pulse delay. Moreover, it is found that the transfer efficiency of STIRAP in the presence of dephasing does not depend on the peak Rabi frequencies at all, as long as they are sufficiently large to enforce adiabatic evolution; hence increasing the field intensity cannot reduce the dephasing losses. It is shown also that for any dephasing rate, the final populations of the initial state and the intermediate state are equal. For strong dephasing all three populations tend to (1/3)

  19. Design of a photonic lattice using shortcuts to adiabaticity

    NASA Astrophysics Data System (ADS)

    Stefanatos, Dionisis

    2014-08-01

    In this article we use the method of shortcuts to adiabaticity to design a photonic lattice (array of waveguides) which can drive the input light to a controlled location at the output. The output position in the array is determined by functions of the propagation distance along the waveguides, which modulate the lattice characteristics (index of refraction, and first- and second-neighbor couplings). The proposed coupler is expected to possess the robustness properties of the design method, coming from its adiabatic nature, and also to have a smaller footprint than purely adiabatic couplers. The present work provides a very interesting example where methods from quantum control can be exploited to design lattices with desired input-output properties.

  20. Adiabatic Quantum Programming: Minor Embedding With Hard Faults

    SciTech Connect

    Klymko, Christine F; Sullivan, Blair D; Humble, Travis S

    2013-01-01

    Adiabatic quantum programming defines the time-dependent mapping of a quantum algorithm into the hardware or logical fabric. An essential programming step is the embedding of problem-specific information into the logical fabric to define the quantum computational transformation. We present algorithms for embedding arbitrary instances of the adiabatic quantum optimization algorithm into a square lattice of specialized unit cells. Our methods are shown to be extensible in fabric growth, linear in time, and quadratic in logical footprint. In addition, we provide methods for accommodating hard faults in the logical fabric without invoking approximations to the original problem. These hard fault-tolerant embedding algorithms are expected to prove useful for benchmarking the adiabatic quantum optimization algorithm on existing quantum logical hardware. We illustrate this versatility through numerical studies of embeddabilty versus hard fault rates in square lattices of complete bipartite unit cells.

  1. Adiabatic Quantum Computation and the Theory of Quantum Phase Transitions

    NASA Astrophysics Data System (ADS)

    Kaminsky, William; Lloyd, Seth

    2007-03-01

    We present a general approach to determining the asymptotic scaling of adiabatic quantum computational resources (space, time, energy, and precision) on random instances of NP-complete graph theory problems. By utilizing the isomorphisms between certain NP-complete graph theory problems and certain frustrated spin models, we demonstrate that the asymptotic scaling of the minimum spectral gap that determines the asymptotic running time of adiabatic algorithms is itself determined by the presence and character of quantum phase transitions in these frustrated models. Most notably, we draw the conclusion that adiabatic quantum computers based on quantum Ising models are much less likely to be efficient than those based on quantum rotor or Heisenberg models. We then exhibit practical rotor and Heisenberg model based architectures using Josephson junction and quantum dot circuits.

  2. Statistical mechanics of Roskilde liquids: Configurational adiabats, specific heat contours, and density dependence of the scaling exponent

    SciTech Connect

    Bailey, Nicholas P.; Bøhling, Lasse; Veldhorst, Arno A.; Schrøder, Thomas B.; Dyre, Jeppe C.

    2013-11-14

    We derive exact results for the rate of change of thermodynamic quantities, in particular, the configurational specific heat at constant volume, C{sub V}, along configurational adiabats (curves of constant excess entropy S{sub ex}). Such curves are designated isomorphs for so-called Roskilde liquids, in view of the invariance of various structural and dynamical quantities along them. The slope of the isomorphs in a double logarithmic representation of the density-temperature phase diagram, γ, can be interpreted as one third of an effective inverse power-law potential exponent. We show that in liquids where γ increases (decreases) with density, the contours of C{sub V} have smaller (larger) slope than configurational adiabats. We clarify also the connection between γ and the pair potential. A fluctuation formula for the slope of the C{sub V}-contours is derived. The theoretical results are supported with data from computer simulations of two systems, the Lennard-Jones fluid, and the Girifalco fluid. The sign of dγ/dρ is thus a third key parameter in characterizing Roskilde liquids, after γ and the virial-potential energy correlation coefficient R. To go beyond isomorph theory we compare invariance of a dynamical quantity, the self-diffusion coefficient, along adiabats and C{sub V}-contours, finding it more invariant along adiabats.

  3. Statistical mechanics of Roskilde liquids: configurational adiabats, specific heat contours, and density dependence of the scaling exponent.

    PubMed

    Bailey, Nicholas P; Bøhling, Lasse; Veldhorst, Arno A; Schrøder, Thomas B; Dyre, Jeppe C

    2013-11-14

    We derive exact results for the rate of change of thermodynamic quantities, in particular, the configurational specific heat at constant volume, CV, along configurational adiabats (curves of constant excess entropy Sex). Such curves are designated isomorphs for so-called Roskilde liquids, in view of the invariance of various structural and dynamical quantities along them. The slope of the isomorphs in a double logarithmic representation of the density-temperature phase diagram, γ, can be interpreted as one third of an effective inverse power-law potential exponent. We show that in liquids where γ increases (decreases) with density, the contours of CV have smaller (larger) slope than configurational adiabats. We clarify also the connection between γ and the pair potential. A fluctuation formula for the slope of the CV-contours is derived. The theoretical results are supported with data from computer simulations of two systems, the Lennard-Jones fluid, and the Girifalco fluid. The sign of dγ∕dρ is thus a third key parameter in characterizing Roskilde liquids, after γ and the virial-potential energy correlation coefficient R. To go beyond isomorph theory we compare invariance of a dynamical quantity, the self-diffusion coefficient, along adiabats and CV-contours, finding it more invariant along adiabats.

  4. Theory of stimulated Raman adiabatic passage in a degenerated reaction system: Application to control of molecular handedness

    NASA Astrophysics Data System (ADS)

    Ohta, Y.; Hoki, K.; Fujimura, Y.

    2002-05-01

    We have developed a new type of stimulated Raman adiabatic passage (STIRAP) that is applicable to a degenerated reaction system. The direction of the photon polarization vector is the adiabatic parameter in the STIRAP. The molecular handedness of H2POSH, a preoriented phosphinotioic acid that has two stable configurations, L and R enantiomers, is used as a model system. The control of molecular handedness in both pure and mixed state cases are considered. In the case of a pure state, a STIRAP with a linearly polarized single laser allows an almost complete transfer from an L (R) enantiomer to the other by adiabatically changing its polarization direction. The adiabatic criterion for changing the polarization direction is clarified. In the case of a mixed state, a STIRAP with two linearly polarized laser pulses allows a selective preparation of pure enantiomers from its racemic mixture. In the low temperature limit, a five-level model reduces a three-level model by setting the direction of the polarization of the pump and Stokes pulses in such a way that only the forward transfer is allowed, while the reverse is forbidden. Furthermore, in the case of mixed state, relaxation effects originating from vibrational mode couplings are taken into account, and the influence of the population decay from intermediate states on the STIRAP is compared with that by a π-pulse approach.

  5. Global adiabaticity and non-Gaussianity consistency condition

    NASA Astrophysics Data System (ADS)

    Romano, Antonio Enea; Mooij, Sander; Sasaki, Misao

    2016-10-01

    In the context of single-field inflation, the conservation of the curvature perturbation on comoving slices, Rc, on super-horizon scales is one of the assumptions necessary to derive the consistency condition between the squeezed limit of the bispectrum and the spectrum of the primordial curvature perturbation. However, the conservation of Rc holds only after the perturbation has reached the adiabatic limit where the constant mode of Rc dominates over the other (usually decaying) mode. In this case, the non-adiabatic pressure perturbation defined in the thermodynamic sense, δPnad ≡ δP - cw2 δρ where cw2 = P ˙ / ρ ˙ , usually becomes also negligible on superhorizon scales. Therefore one might think that the adiabatic limit is the same as thermodynamic adiabaticity. This is in fact not true. In other words, thermodynamic adiabaticity is not a sufficient condition for the conservation of Rc on super-horizon scales. In this paper, we consider models that satisfy δPnad = 0 on all scales, which we call global adiabaticity (GA), which is guaranteed if cw2 = cs2, where cs is the phase velocity of the propagation of the perturbation. A known example is the case of ultra-slow-roll (USR) inflation in which cw2 = cs2 = 1. In order to generalize USR we develop a method to find the Lagrangian of GA K-inflation models from the behavior of background quantities as functions of the scale factor. Applying this method we show that there indeed exists a wide class of GA models with cw2 = cs2, which allows Rc to grow on superhorizon scales, and hence violates the non-Gaussianity consistency condition.

  6. Gravitational Chern-Simons and the adiabatic limit

    NASA Astrophysics Data System (ADS)

    McLellan, Brendan

    2010-12-01

    We compute the gravitational Chern-Simons term explicitly for an adiabatic family of metrics using standard methods in general relativity. We use the fact that our base three-manifold is a quasiregular K-contact manifold heavily in this computation. Our key observation is that this geometric assumption corresponds exactly to a Kaluza-Klein Ansatz for the metric tensor on our three-manifold, which allows us to translate our problem into the language of general relativity. Similar computations have been performed by Guralnik et al. [Ann. Phys. 308, 222 (2008)], although not in the adiabatic context.

  7. Speeding up Adiabatic Quantum State Transfer by Using Dressed States

    NASA Astrophysics Data System (ADS)

    Baksic, Alexandre; Ribeiro, Hugo; Clerk, Aashish A.

    2016-06-01

    We develop new pulse schemes to significantly speed up adiabatic state transfer protocols. Our general strategy involves adding corrections to an initial control Hamiltonian that harness nonadiabatic transitions. These corrections define a set of dressed states that the system follows exactly during the state transfer. We apply this approach to stimulated Raman adiabatic passage protocols and show that a suitable choice of dressed states allows one to design fast protocols that do not require additional couplings, while simultaneously minimizing the occupancy of the "intermediate" level.

  8. Quantum Adiabatic Pumping by Modulating Tunnel Phase in Quantum Dots

    NASA Astrophysics Data System (ADS)

    Taguchi, Masahiko; Nakajima, Satoshi; Kubo, Toshihiro; Tokura, Yasuhiro

    2016-08-01

    In a mesoscopic system, under zero bias voltage, a finite charge is transferred by quantum adiabatic pumping by adiabatically and periodically changing two or more control parameters. We obtained expressions for the pumped charge for a ring of three quantum dots (QDs) by choosing the magnetic flux penetrating the ring as one of the control parameters. We found that the pumped charge shows a steplike behavior with respect to the variance of the flux. The value of the step heights is not universal but depends on the trajectory of the control parameters. We discuss the physical origin of this behavior on the basis of the Fano resonant condition of the ring.

  9. Classical nuclear motion coupled to electronic non-adiabatic transitions

    SciTech Connect

    Agostini, Federica; Abedi, Ali; Gross, E. K. U.

    2014-12-07

    Based on the exact factorization of the electron-nuclear wave function, we have recently proposed a mixed quantum-classical scheme [A. Abedi, F. Agostini, and E. K. U. Gross, Europhys. Lett. 106, 33001 (2014)] to deal with non-adiabatic processes. Here we present a comprehensive description of the formalism, including the full derivation of the equations of motion. Numerical results are presented for a model system for non-adiabatic charge transfer in order to test the performance of the method and to validate the underlying approximations.

  10. Gravitational Chern-Simons and the adiabatic limit

    SciTech Connect

    McLellan, Brendan

    2010-12-15

    We compute the gravitational Chern-Simons term explicitly for an adiabatic family of metrics using standard methods in general relativity. We use the fact that our base three-manifold is a quasiregular K-contact manifold heavily in this computation. Our key observation is that this geometric assumption corresponds exactly to a Kaluza-Klein Ansatz for the metric tensor on our three-manifold, which allows us to translate our problem into the language of general relativity. Similar computations have been performed by Guralnik et al.[Ann. Phys. 308, 222 (2008)], although not in the adiabatic context.

  11. Spatial adiabatic passage: a review of recent progress

    NASA Astrophysics Data System (ADS)

    Menchon-Enrich, R.; Benseny, A.; Ahufinger, V.; Greentree, A. D.; Busch, Th; Mompart, J.

    2016-07-01

    Adiabatic techniques are known to allow for engineering quantum states with high fidelity. This requirement is currently of large interest, as applications in quantum information require the preparation and manipulation of quantum states with minimal errors. Here we review recent progress on developing techniques for the preparation of spatial states through adiabatic passage, particularly focusing on three state systems. These techniques can be applied to matter waves in external potentials, such as cold atoms or electrons, and to classical waves in waveguides, such as light or sound.

  12. Adiabatic effects in the dynamics of Langmuir solitons

    SciTech Connect

    Astrelin, V.T.; Breizman, B.N.; Sedlacek, Z.; Jungwirth, K.

    1988-06-01

    The adiabatic slowness with which the plasma density profile is reconstructed from localized in large-amplitude Langmuir solitons is characteristic of such solitons. Several examples making use of this feature in the description of the soliton dynamics are given. Specifically, long-lived states in the form of composite solitons ar found. Additional limitations are found on the interaction of solitons with each other and with sound waves. The effect of the adiabatic nature on the formation of solitons from free plasmons is discussed.

  13. Power-driven and adiabatic expansions into vacuum

    NASA Astrophysics Data System (ADS)

    Farnsworth, A. V., Jr.

    1980-08-01

    Analytical solutions are obtained for the planar, cylindrical, and spherical expansions into vacuum of matter initially concentrated at a plane, a line, or a point. Both power-driven and adiabatic expansions are considered, where in the power-driven case, the specific power is deposited uniformly in space, but may vary in time according to a power law. These problems are found to be self-similar. The non-self-similar motion of matter during the adiabatic expansion that follows a power pulse of finite duration has also been addressed and a solution has been obtained.

  14. Adiabatic regularisation of power spectra in k-inflation

    SciTech Connect

    Alinea, Allan L.; Kubota, Takahiro; Nakanishi, Yukari; Naylor, Wade E-mail: kubota@celas.osaka-u.ac.jp E-mail: naylor@phys.sci.osaka-u.ac.jp

    2015-06-01

    We look at the question posed by Parker et al. about the effect of UV regularisation on the power spectrum for inflation. Focusing on the slow-roll k-inflation, we show that up to second order in the Hubble and sound flow parameters, the adiabatic regularisation of such model leads to no difference in the power spectrum apart from certain cases that violate near scale-invariant power spectra. Furthermore, extending to non-minimal k-inflation, we establish the equivalence of the subtraction terms in the adiabatic regularisation of the power spectrum in Jordan and Einstein frames.

  15. Local control of non-adiabatic dissociation dynamics

    NASA Astrophysics Data System (ADS)

    Bomble, L.; Chenel, A.; Meier, C.; Desouter-Lecomte, M.

    2011-05-01

    We present a theoretical approach which consists of applying the strategy of local control to projectors based on asymptotic scattering states. This allows to optimize final state distributions upon laser excitation in cases where strong non-adiabatic effects are present. The approach, despite being based on a time-local formulation, can take non-adiabatic transitions that appear at later times fully into account and adopt a corresponding control strategy. As an example, we show various dissociation channels of HeH+, a system where the ultrafast dissociation dynamics is determined by strong non-Born-Oppenheimer effects.

  16. Spatial adiabatic passage: a review of recent progress.

    PubMed

    Menchon-Enrich, R; Benseny, A; Ahufinger, V; Greentree, A D; Busch, Th; Mompart, J

    2016-07-01

    Adiabatic techniques are known to allow for engineering quantum states with high fidelity. This requirement is currently of large interest, as applications in quantum information require the preparation and manipulation of quantum states with minimal errors. Here we review recent progress on developing techniques for the preparation of spatial states through adiabatic passage, particularly focusing on three state systems. These techniques can be applied to matter waves in external potentials, such as cold atoms or electrons, and to classical waves in waveguides, such as light or sound. PMID:27245462

  17. Saturation current spikes eliminated in saturable core transformers

    NASA Technical Reports Server (NTRS)

    Schwarz, F. C.

    1971-01-01

    Unsaturating composite magnetic core transformer, consisting of two separate parallel cores designed so impending core saturation causes signal generation, terminates high current spike in converter primary circuit. Simplified waveform, demonstrates transformer effectiveness in eliminating current spikes.

  18. Neuropsychologic effects of saturation diving.

    PubMed

    Vaernes, R J; Kløve, H; Ellertsen, B

    1989-05-01

    Neuropsychologic status of saturation divers was assessed before and after 300-500 msw dives (deep saturation diving--DSD group) and before and after 3.5 yr of ordinary saturation diving (saturation diving--SD group). Average baseline results showed the divers to be slightly superior to nondiving controls. Mild-to-moderate neuropsychologic changes (greater than 10% impairment) were found in measures of tremor, spatial memory, vigilance, and automatic reactivity in 20% of the divers after deep dives (DSD group). One year postdive no recovery was observed except for a vigilance test. In the SD group, 20% of the divers showed greater than 10% impairment after 3.5 yr of ordinary saturation diving. Significant reduction in autonomic reactivity was also found and there was a relationship between low autonomic reactivity before saturation diving and number of greater than 10% impairments. For the whole group (DSD + SD divers), negative correlations were found between saturation experience and results on memory and complex visuomotor tests. Years of diving from first to last examination was positively correlated with number of greater than 10% impairments and with reduction in autonomic reactivity. No similar correlations were found to dive variables after about 3 yr of air diving. The mild-to-moderate changes seen in some divers, therefore, seem to be the effects of saturation diving. Since one deep dive may cause an effect similar to the effect of 3.5 yr of ordinary saturation diving, there is reason to believe that repeated deep diving may lead to more pronounced neuropsychologic impairment.

  19. Ion thermal effects on slow mode solitary waves in plasmas with two adiabatic ion species

    SciTech Connect

    Nsengiyumva, F. Hellberg, M. A. Mace, R. L.

    2015-09-15

    Using both the Sagdeev and Korteweg-de Vries (KdV) methods, ion thermal effects on slow mode ion acoustic solitons and double layers are investigated in a plasma with two adiabatic positive ion species. It is found that reducing the gap between the two ion thermal speeds by increasing the relative temperature of the cool ions increases the typical soliton/double layer speeds for all values of the ion-ion density ratio and reduces the range in the density ratio that supports double layers. The effect of increasing the relative cool ion temperature on the soliton/double layer amplitudes depends on the relative densities. For lower values of the ion density ratio, an increase in cool ion temperature leads to a significant decrease in soliton/double layer amplitude, so one may find that solitons of all permissible speeds lie within the range of KdV theory.

  20. Digitized adiabatic quantum computing with a superconducting circuit

    NASA Astrophysics Data System (ADS)

    Barends, R.; Shabani, A.; Lamata, L.; Kelly, J.; Mezzacapo, A.; Heras, U. Las; Babbush, R.; Fowler, A. G.; Campbell, B.; Chen, Yu; Chen, Z.; Chiaro, B.; Dunsworth, A.; Jeffrey, E.; Lucero, E.; Megrant, A.; Mutus, J. Y.; Neeley, M.; Neill, C.; O'Malley, P. J. J.; Quintana, C.; Roushan, P.; Sank, D.; Vainsencher, A.; Wenner, J.; White, T. C.; Solano, E.; Neven, H.; Martinis, John M.

    2016-06-01

    Quantum mechanics can help to solve complex problems in physics and chemistry, provided they can be programmed in a physical device. In adiabatic quantum computing, a system is slowly evolved from the ground state of a simple initial Hamiltonian to a final Hamiltonian that encodes a computational problem. The appeal of this approach lies in the combination of simplicity and generality; in principle, any problem can be encoded. In practice, applications are restricted by limited connectivity, available interactions and noise. A complementary approach is digital quantum computing, which enables the construction of arbitrary interactions and is compatible with error correction, but uses quantum circuit algorithms that are problem-specific. Here we combine the advantages of both approaches by implementing digitized adiabatic quantum computing in a superconducting system. We tomographically probe the system during the digitized evolution and explore the scaling of errors with system size. We then let the full system find the solution to random instances of the one-dimensional Ising problem as well as problem Hamiltonians that involve more complex interactions. This digital quantum simulation of the adiabatic algorithm consists of up to nine qubits and up to 1,000 quantum logic gates. The demonstration of digitized adiabatic quantum computing in the solid state opens a path to synthesizing long-range correlations and solving complex computational problems. When combined with fault-tolerance, our approach becomes a general-purpose algorithm that is scalable.

  1. Digitized adiabatic quantum computing with a superconducting circuit.

    PubMed

    Barends, R; Shabani, A; Lamata, L; Kelly, J; Mezzacapo, A; Las Heras, U; Babbush, R; Fowler, A G; Campbell, B; Chen, Yu; Chen, Z; Chiaro, B; Dunsworth, A; Jeffrey, E; Lucero, E; Megrant, A; Mutus, J Y; Neeley, M; Neill, C; O'Malley, P J J; Quintana, C; Roushan, P; Sank, D; Vainsencher, A; Wenner, J; White, T C; Solano, E; Neven, H; Martinis, John M

    2016-06-01

    Quantum mechanics can help to solve complex problems in physics and chemistry, provided they can be programmed in a physical device. In adiabatic quantum computing, a system is slowly evolved from the ground state of a simple initial Hamiltonian to a final Hamiltonian that encodes a computational problem. The appeal of this approach lies in the combination of simplicity and generality; in principle, any problem can be encoded. In practice, applications are restricted by limited connectivity, available interactions and noise. A complementary approach is digital quantum computing, which enables the construction of arbitrary interactions and is compatible with error correction, but uses quantum circuit algorithms that are problem-specific. Here we combine the advantages of both approaches by implementing digitized adiabatic quantum computing in a superconducting system. We tomographically probe the system during the digitized evolution and explore the scaling of errors with system size. We then let the full system find the solution to random instances of the one-dimensional Ising problem as well as problem Hamiltonians that involve more complex interactions. This digital quantum simulation of the adiabatic algorithm consists of up to nine qubits and up to 1,000 quantum logic gates. The demonstration of digitized adiabatic quantum computing in the solid state opens a path to synthesizing long-range correlations and solving complex computational problems. When combined with fault-tolerance, our approach becomes a general-purpose algorithm that is scalable. PMID:27279216

  2. Digitized adiabatic quantum computing with a superconducting circuit.

    PubMed

    Barends, R; Shabani, A; Lamata, L; Kelly, J; Mezzacapo, A; Las Heras, U; Babbush, R; Fowler, A G; Campbell, B; Chen, Yu; Chen, Z; Chiaro, B; Dunsworth, A; Jeffrey, E; Lucero, E; Megrant, A; Mutus, J Y; Neeley, M; Neill, C; O'Malley, P J J; Quintana, C; Roushan, P; Sank, D; Vainsencher, A; Wenner, J; White, T C; Solano, E; Neven, H; Martinis, John M

    2016-06-08

    Quantum mechanics can help to solve complex problems in physics and chemistry, provided they can be programmed in a physical device. In adiabatic quantum computing, a system is slowly evolved from the ground state of a simple initial Hamiltonian to a final Hamiltonian that encodes a computational problem. The appeal of this approach lies in the combination of simplicity and generality; in principle, any problem can be encoded. In practice, applications are restricted by limited connectivity, available interactions and noise. A complementary approach is digital quantum computing, which enables the construction of arbitrary interactions and is compatible with error correction, but uses quantum circuit algorithms that are problem-specific. Here we combine the advantages of both approaches by implementing digitized adiabatic quantum computing in a superconducting system. We tomographically probe the system during the digitized evolution and explore the scaling of errors with system size. We then let the full system find the solution to random instances of the one-dimensional Ising problem as well as problem Hamiltonians that involve more complex interactions. This digital quantum simulation of the adiabatic algorithm consists of up to nine qubits and up to 1,000 quantum logic gates. The demonstration of digitized adiabatic quantum computing in the solid state opens a path to synthesizing long-range correlations and solving complex computational problems. When combined with fault-tolerance, our approach becomes a general-purpose algorithm that is scalable.

  3. Failure of geometric electromagnetism in the adiabatic vector Kepler problem

    SciTech Connect

    Anglin, J.R.; Schmiedmayer, J.

    2004-02-01

    The magnetic moment of a particle orbiting a straight current-carrying wire may precess rapidly enough in the wire's magnetic field to justify an adiabatic approximation, eliminating the rapid time dependence of the magnetic moment and leaving only the particle position as a slow degree of freedom. To zeroth order in the adiabatic expansion, the orbits of the particle in the plane perpendicular to the wire are Keplerian ellipses. Higher-order postadiabatic corrections make the orbits precess, but recent analysis of this 'vector Kepler problem' has shown that the effective Hamiltonian incorporating a postadiabatic scalar potential ('geometric electromagnetism') fails to predict the precession correctly, while a heuristic alternative succeeds. In this paper we resolve the apparent failure of the postadiabatic approximation, by pointing out that the correct second-order analysis produces a third Hamiltonian, in which geometric electromagnetism is supplemented by a tensor potential. The heuristic Hamiltonian of Schmiedmayer and Scrinzi is then shown to be a canonical transformation of the correct adiabatic Hamiltonian, to second order. The transformation has the important advantage of removing a 1/r{sup 3} singularity which is an artifact of the adiabatic approximation.

  4. Quantum back-reaction from non-adiabatic changes

    NASA Astrophysics Data System (ADS)

    Asplund, Curtis; Berenstein, David

    2011-04-01

    Motivated by the problem of thermalization in QFTs and the dual non-equilibrium BH dynamics, we examine a generic and non-trivial aspect of these phenomena, non-adiabatic changes, in a highly simplified setting. We consider a harmonic oscillator whose frequency depends on a second quantum variable x. Beginning with a classical analysis, we show how the system can be described by an improved adiabatic expansion with a velocity dependent force for x. We find an instability at a critical velocity beyond which the adiabatic (Born-Oppenheimer) approximation breaks down. We extend this calculation to the fully quantum system and to field theory and describe how to study fermions with similar techniques. Finally, we set up a model with an abrupt change in the oscillator whose quantum mechanics can be solved exactly so that one can study the effects of back-reaction of a fully non-adiabatic change in a controlled setting. We comment on applications of these general results to the physics of D-branes, inflation, and BHs in AdS/CFT.

  5. Adiabatic quantum computing with phase modulated laser pulses

    PubMed Central

    Goswami, Debabrata

    2005-01-01

    Implementation of quantum logical gates for multilevel systems is demonstrated through decoherence control under the quantum adiabatic method using simple phase modulated laser pulses. We make use of selective population inversion and Hamiltonian evolution with time to achieve such goals robustly instead of the standard unitary transformation language. PMID:17195865

  6. Adiabatic frequency conversion with a sign flip in the coupling

    NASA Astrophysics Data System (ADS)

    Hristova, H. S.; Rangelov, A. A.; Montemezzani, G.; Vitanov, N. V.

    2016-09-01

    Adiabatic frequency conversion is a method recently developed in nonlinear optics [H. Suchowski, D. Oron, A. Arie, and Y. Silberberg, Phys. Rev. A 78, 063821 (2008), 10.1103/PhysRevA.78.063821], using ideas from the technique of rapid adiabatic passage (RAP) via a level crossing in quantum physics. In this method, the coupling coefficients are constant and the phase mismatch is chirped adiabatically. In this work, we propose another method for adiabatic frequency conversion, in which the phase mismatch is constant and the coupling is a pulse-shaped function with a sign flip (i.e., a phase step of π ) at its maximum. Compared to the RAP method, our technique has comparable efficiency but it is simpler to implement for it only needs two bulk crystals with opposite χ(2 ) nonlinearity. Moreover, because our technique requires constant nonzero frequency mismatch and has zero conversion efficiency on exact frequency matching, it can be used as a frequency filter.

  7. The flat Grothendieck-Riemann-Roch theorem without adiabatic techniques

    NASA Astrophysics Data System (ADS)

    Ho, Man-Ho

    2016-09-01

    In this paper we give a simplified proof of the flat Grothendieck-Riemann-Roch theorem. The proof makes use of the local family index theorem and basic computations of the Chern-Simons form. In particular, it does not involve any adiabatic limit computation of the reduced eta-invariant.

  8. When an Adiabatic Irreversible Expansion or Compression Becomes Reversible

    ERIC Educational Resources Information Center

    Anacleto, Joaquim; Ferreira, J. M.; Soares, A. A.

    2009-01-01

    This paper aims to contribute to a better understanding of the concepts of a "reversible process" and "entropy". For this purpose, an adiabatic irreversible expansion or compression is analysed, by considering that an ideal gas is expanded (compressed), from an initial pressure P[subscript i] to a final pressure P[subscript f], by being placed in…

  9. Nonequilibrium Statistical Mechanics for Adiabatic Piston Problem

    NASA Astrophysics Data System (ADS)

    Itami, Masato; Sasa, Shin-ichi

    2015-01-01

    We consider the dynamics of a freely movable wall of mass with one degree of freedom that separates a long tube into two regions, each of which is filled with rarefied gas particles of mass . The gases are initially prepared at equal pressure but different temperatures, and we assume that the pressure and temperature of gas particles before colliding with the wall are kept constant over time in each region. We elucidate the energetics of the setup on the basis of the local detailed balance condition, and then derive the expression for the heat transferred from each gas to the wall. Furthermore, by using the condition, we obtain the linear response formula for the steady velocity of the wall and steady energy flux through the wall. By using perturbation expansion in a small parameter , we calculate the steady velocity up to order.

  10. Linewidth measurement of external grating cavity quantum cascade laser using saturation spectroscopy

    NASA Astrophysics Data System (ADS)

    Mukherjee, Nandini; Go, Rowel; Patel, C. Kumar N.

    2008-03-01

    A room temperature external grating cavity (EGC) quantum cascade laser (QCL) is characterized using saturation spectroscopy of NO2. The presence of two strong EGC QCL waveguide modes is evident from the saturation spectra. A linewidth of 21MHz for each EGC-QCL mode is measured from the width of the saturation peak at 10mTorr pressure of NO2.

  11. Volume crossover in deeply supercooled water adiabatically freezing under isobaric conditions.

    PubMed

    Aliotta, Francesco; Giaquinta, Paolo V; Pochylski, Mikolaj; Ponterio, Rosina C; Prestipino, Santi; Saija, Franz; Vasi, Cirino

    2013-05-14

    The irreversible return of a supercooled liquid to stable thermodynamic equilibrium often begins as a fast process which adiabatically drives the system to solid-liquid coexistence. Only at a later stage will solidification proceed with the expected exchange of thermal energy with the external bath. In this paper we discuss some aspects of the adiabatic freezing of metastable water at constant pressure. In particular, we investigated the thermal behavior of the isobaric gap between the molar volume of supercooled water and that of the warmer ice-water mixture which eventually forms at equilibrium. The available experimental data at ambient pressure, extrapolated into the metastable region within the scheme provided by the reference IAPWS-95 formulation, show that water ordinarily expands upon (partially) freezing under isenthalpic conditions. However, the same scheme also suggests that, for increasing undercoolings, the volume gap is gradually reduced and eventually vanishes at a temperature close to the currently estimated homogeneous ice nucleation temperature. This behavior is contrasted with that of substances which do not display a volumetric anomaly. The effect of increasing pressures on the alleged volume crossover from an expanded to a contracted ice-water mixture is also discussed.

  12. Landsliding in partially saturated materials

    NASA Astrophysics Data System (ADS)

    Godt, Jonathan W.; Baum, Rex L.; Lu, Ning

    2009-01-01

    Rainfall-induced landslides are pervasive in hillslope environments around the world and among the most costly and deadly natural hazards. However, capturing their occurrence with scientific instrumentation in a natural setting is extremely rare. The prevailing thinking on landslide initiation, particularly for those landslides that occur under intense precipitation, is that the failure surface is saturated and has positive pore-water pressures acting on it. Most analytic methods used for landslide hazard assessment are based on the above perception and assume that the failure surface is located beneath a water table. By monitoring the pore water and soil suction response to rainfall, we observed shallow landslide occurrence under partially saturated conditions for the first time in a natural setting. We show that the partially saturated shallow landslide at this site is predictable using measured soil suction and water content and a novel unified effective stress concept for partially saturated earth materials.

  13. Landsliding in partially saturated materials

    USGS Publications Warehouse

    Godt, J.W.; Baum, R.L.; Lu, N.

    2009-01-01

    [1] Rainfall-induced landslides are pervasive in hillslope environments around the world and among the most costly and deadly natural hazards. However, capturing their occurrence with scientific instrumentation in a natural setting is extremely rare. The prevailing thinking on landslide initiation, particularly for those landslides that occur under intense precipitation, is that the failure surface is saturated and has positive pore-water pressures acting on it. Most analytic methods used for landslide hazard assessment are based on the above perception and assume that the failure surface is located beneath a water table. By monitoring the pore water and soil suction response to rainfall, we observed shallow landslide occurrence under partially saturated conditions for the first time in a natural setting. We show that the partially saturated shallow landslide at this site is predictable using measured soil suction and water content and a novel unified effective stress concept for partially saturated earth materials. Copyright 2009 by the American Geophysical Union.

  14. Adiabatic Swimming in an Ideal Quantum Gas

    NASA Astrophysics Data System (ADS)

    Avron, J. E.; Gutkin, B.; Oaknin, D. H.

    2006-04-01

    Interference effects are important for swimming of mesoscopic systems that are small relative to the coherence length of the surrounding quantum medium. Swimming is geometric for slow swimmers and the distance covered in each stroke is determined, explicitly, in terms of the on-shell scattering matrix. Remarkably, for a one-dimensional Fermi gas at zero temperature we find that slow swimming is topological: the swimming distance covered in one stroke is quantized in half integer multiples of the Fermi wavelength. In addition, a careful choice of the swimming stroke can eliminate dissipation.

  15. Pulsed spheromak reactor with adiabatic compression

    SciTech Connect

    Fowler, T K

    1999-03-29

    Extrapolating from the Pulsed Spheromak reactor and the LINUS concept, we consider ignition achieved by injecting a conducting liquid into the flux conserver to compress a low temperature spheromak created by gun injection and ohmic heating. The required energy to achieve ignition and high gain by compression is comparable to that required for ohmic ignition and the timescale is similar so that the mechanical power to ignite by compression is comparable to the electrical power to ignite ohmically. Potential advantages and problems are discussed. Like the High Beta scenario achieved by rapid fueling of an ohmically ignited plasma, compression must occur on timescales faster than Taylor relaxation.

  16. Design, fabrication and delivery of a prototype saturator for ACPL

    NASA Technical Reports Server (NTRS)

    Keyser, G.; Rogers, C. F.; Squires, P.

    1979-01-01

    The design configuration and performance characteristics of a saturator developed to provide ground-based simulation for some of the experiments for ACPL-1 first flights of Spacelab are described, some difficulties encountered with the apparatus are discussed, and recommendations concerning testing of this type of instrument are presented. The saturators provide a means of accurately fixing the water vapor mixing ratio of an aerosol sample. Dew point temperatures from almost freezing to ambient room temperatures can be attained with high precision. The instruments can accommodate aerosol flow rates approaching 1000 cc/s. Provisions were made to inject aerosols upstream of these saturators, although downstream injection can be accomplished as well. A device of this type will be used in the ACPL-1 to condition various aerosols delivered concurrently to a CFD, expansion chamber, and static diffusion chamber used in zero gravity cloud-forming experiments. The saturator was designed to meet the requirements projected for the flight instrument.

  17. In-Flight Measurements of Capsule Shell Adiabats in Laser-Driven Implosions

    SciTech Connect

    Kritcher, A. L.; Doeppner, T.; Ma, T.; Landen, O. L.; Wallace, R.; Glenzer, S. H.; Fortmann, C.

    2011-07-01

    We present the first x-ray Thomson scattering measurements of temperature and density from spherically imploding matter. The shape of the Compton downscattered spectrum provides a first-principles measurement of the electron velocity distribution function, dependent on T{sub e} and the Fermi temperature T{sub F}{approx}n{sub e}{sup 2/3}. In-flight compressions of Be and CH targets reach 6-13 times solid density, with T{sub e}/T{sub F}{approx}0.4-0.7 and {Gamma}{sub ii}{approx}5, resulting in minimum adiabats of {approx}1.6-2. These measurements are consistent with low-entropy implosions and predictions by radiation-hydrodynamic modeling.

  18. Adiabatic pressure dependence of the 2.7 and 1.9 micron water vapor bands

    NASA Technical Reports Server (NTRS)

    Mathai, C. V.; Walls, W. L.; Broersma, S.

    1977-01-01

    An acoustic excitation technique is used to determine the adiabatic pressure derivative of the spectral absorptance of the 2.7 and 1.9 micron water vapor bands, and the 3.5 micron HCl band. The dependence of this derivative on thermodynamic parameters such as temperature, concentration, and pressure is evaluated. A cross-flow water vapor system is used to measure spectral absorptance. Taking F as the ratio of nonrigid to rotor line strengths, it is found that an F factor correction is needed for the 2.7 micron band. The F factor for the 1.9 micron band is also determined. In the wings of each band a wavelength can be found where the concentration dependence is predominant. Farther out in the wings a local maximum occurs for the temperature derivative. It is suggested that the pressure derivative is significant in the core of the band.

  19. Thermal characterization of starch-water system by photopyroelectric technique and adiabatic scanning calorimetry

    NASA Astrophysics Data System (ADS)

    Cruz-Orea, A.; Bentefour, E. H.; Jamée, P.; Chirtoc, M.; Glorieux, C.; Pitsi, G.; Thoen, J.

    2003-01-01

    Starch is one of the most important carbohydrate sources in human nutrition. For the thermal analysis of starch, techniques such as differential scanning calorimetry have been extensively used. As an alternative, we have applied a photopyroelectric (PPE) configuration and adiabatic scanning calorimetry (ASC) to study the thermal properties of starch-water systems. For this study we used nixtamalized corn flour and potato starch with different quantities of distilled water, in order to obtain samples with different moisture content. By using PPE and ASC methods we have measured, for each technique separately, the heat capacity by unit volume (ρcp) at room temperature for a corn flour sample at 90% moisture. The obtained values agree within experimental uncertainty. By using these techniques we also studied the thermal behavior of potato starch, at 80% moisture, in the temperature range where phase transitions occur. In this case the PPE signal phase could be used as a sensitive and versatile monitor for phase transitions.

  20. In-Flight Measurements of Capsule Adiabats in Laser Driven Spherical Implosions

    SciTech Connect

    Kritcher, A L; Doppner, T; Fortman, C; Ma, T; Landen, O L; Wallace, R; Glenzer, S H

    2011-03-07

    We present the first x-ray Thomson scattering measurements of temperature and density from spherically imploding matter. The shape of the Compton downscattered spectrum provides a first-principles measurement of the electron velocity distribution function, dependent on T{sub e} and the Fermi temperature T{sub F} {approx} n{sub e}{sup 2/3}. In flight compressions of Be and CH targets reach 6-13 times solid density, with T{sub e}/T{sub F} {approx} 0.4-0.7, resulting in minimum adiabats of {approx}1.6-2. These measurements are consistent with low-entropy implosions and predictions by simulations using radiation-hydrodynamic modeling.

  1. Theory of laser-induced adiabat shaping in inertial fusion implosions: The relaxation method

    SciTech Connect

    Betti, R.; Anderson, K.; Knauer, J.; Collins, T.J.B.; McCrory, R.L.; McKenty, P.W.; Skupsky, S.

    2005-04-15

    The theory of the adiabat shaping induced by a strong shock propagating through a relaxed density profile is carried out for inertial confinement fusion (ICF) capsules. The relaxed profile is produced through a laser prepulse, while the adiabat-shaping shock is driven by the foot of the main laser pulse. The theoretical adiabat profiles accurately reproduce the simulation results. ICF capsules with a shaped adiabat are expected to benefit from improved hydrodynamic stability while maintaining the same one-dimensional performances as flat-adiabat shells.

  2. Slow light and saturable absorption

    NASA Astrophysics Data System (ADS)

    Selden, A. C.

    2009-06-01

    Quantitative analysis of slow light experiments utilising coherent population oscillation (CPO) in a range of saturably absorbing media, including ruby and alexandrite, Er3+:Y2SiO5, bacteriorhodopsin, semiconductor quantum devices and erbium-doped optical fibres, shows that the observations may be more simply interpreted as saturable absorption phenomena. A basic two-level model of a saturable absorber displays all the effects normally associated with slow light, namely phase shift and modulation gain of the transmitted signal, hole burning in the modulation frequency spectrum and power broadening of the spectral hole, each arising from the finite response time of the non-linear absorption. Only where hole-burning in the optical spectrum is observed (using independent pump and probe beams), or pulse delays exceeding the limits set by saturable absorption are obtained, can reasonable confidence be placed in the observation of slow light in such experiments. Superluminal (“fast light”) phenomena in media with reverse saturable absorption (RSA) may be similarly explained.

  3. Direct heating rates associated with gravity wave saturation

    NASA Astrophysics Data System (ADS)

    Becker, Erich

    2004-04-01

    Analysis of filtering out subscale motions is applied for internal gravity waves. This leads to a new perspective of the planetary-scale sensible heat budget of the upper mesosphere/lower thermosphere. In line with previous results of Becker and Schmitz, the present paper recapitulates that the dissipation of gravity wave kinetic energy and the local adiabatic conversion of mean enthalpy into gravity wave kinetic energy cannot be neglected, and that the net effect of both cools the upper mesosphere/lower thermosphere. In addition, the importance of the wave entropy flux-an effect which is ignored in customary gravity wave parameterizations for global circulation models-is stressed. We show that, when evaluated on the basis of Lindzen's saturation assumption, the wave entropy flux convergence behaves like a vertical diffusion of the mean stratification, where the wave-induced diffusion coefficient is involved with a Prandtl number of 2. This result imposes an upper bound of 2 for the effective Prandtl number which scales the combined entropy flux owing to turbulence and gravity waves. The direct heating rates generated by gravity wave saturation are assessed quantitatively, using an idealized general circulation model completed by a Lindzen-type gravity wave parameterization.

  4. Robust quantum logic in neutral atoms via adiabatic Rydberg dressing

    NASA Astrophysics Data System (ADS)

    Keating, Tyler; Cook, Robert L.; Hankin, Aaron M.; Jau, Yuan-Yu; Biedermann, Grant W.; Deutsch, Ivan H.

    2015-01-01

    We study a scheme for implementing a controlled-Z (cz) gate between two neutral-atom qubits based on the Rydberg blockade mechanism in a manner that is robust to errors caused by atomic motion. By employing adiabatic dressing of the ground electronic state, we can protect the gate from decoherence due to random phase errors that typically arise because of atomic thermal motion. In addition, the adiabatic protocol allows for a Doppler-free configuration that involves counterpropagating lasers in a σ+/σ- orthogonal polarization geometry that further reduces motional errors due to Doppler shifts. The residual motional error is dominated by dipole-dipole forces acting on doubly excited Rydberg atoms when the blockade is imperfect. For reasonable parameters, with qubits encoded into the clock states of 133Cs, we predict that our protocol could produce a cz gate in <10 μ s with error probability on the order of 10-3.

  5. Adiabatic molecular-dynamics-simulation-method studies of kinetic friction

    NASA Astrophysics Data System (ADS)

    Zhang, J.; Sokoloff, J. B.

    2005-06-01

    An adiabatic molecular-dynamics method is developed and used to study the Muser-Robbins model for dry friction (i.e., nonzero kinetic friction in the slow sliding speed limit). In this model, dry friction between two crystalline surfaces rotated with respect to each other is due to mobile molecules (i.e., dirt particles) adsorbed at the interface. Our adiabatic method allows us to quickly locate interface potential-well minima, which become unstable during sliding of the surfaces. Since dissipation due to friction in the slow sliding speed limit results from mobile molecules dropping out of such unstable wells, our method provides a way to calculate dry friction, which agrees extremely well with results found by conventional molecular dynamics for the same system, but our method is more than a factor of 10 faster.

  6. Adiabatic far-field sub-diffraction imaging

    PubMed Central

    Cang, Hu; Salandrino, Alessandro; Wang, Yuan; Zhang, Xiang

    2015-01-01

    The limited resolution of a conventional optical imaging system stems from the fact that the fine feature information of an object is carried by evanescent waves, which exponentially decays in space and thus cannot reach the imaging plane. We introduce here an adiabatic lens, which utilizes a geometrically conformal surface to mediate the interference of slowly decompressed electromagnetic waves at far field to form images. The decompression is satisfying an adiabatic condition, and by bridging the gap between far field and near field, it allows far-field optical systems to project an image of the near-field features directly. Using these designs, we demonstrated the magnification can be up to 20 times and it is possible to achieve sub-50 nm imaging resolution in visible. Our approach provides a means to extend the domain of geometrical optics to a deep sub-wavelength scale. PMID:26258769

  7. Adiabatic creation of atomic squeezing in dark states versus decoherences

    SciTech Connect

    Gong, Z. R.; Sun, C. P.; Wang Xiaoguang

    2010-07-15

    We study the multipartite correlations of the multiatom dark states, which are characterized by the atomic squeezing beyond the pairwise entanglement. It is shown that, in the photon storage process with atomic ensemble via the electromagnetically induced transparency (EIT) mechanism, the atomic squeezing and the pairwise entanglement can be created by adiabatically manipulating the Rabi frequency of the classical light field on the atomic ensemble. We also consider the sudden death for the atomic squeezing and the pairwise entanglement under various decoherence channels. An optimal time for generating the greatest atomic squeezing and pairwise entanglement is obtained by studying in detail the competition between the adiabatic creation of quantum correlation in the atomic ensemble and the decoherence that we describe with three typical decoherence channels.

  8. Adiabatic theory of solitons fed by dispersive waves

    NASA Astrophysics Data System (ADS)

    Pickartz, Sabrina; Bandelow, Uwe; Amiranashvili, Shalva

    2016-09-01

    We consider scattering of low-amplitude dispersive waves at an intense optical soliton which constitutes a nonlinear perturbation of the refractive index. Specifically, we consider a single-mode optical fiber and a group velocity matched pair: an optical soliton and a nearly perfectly reflected dispersive wave, a fiber-optical analog of the event horizon. By combining (i) an adiabatic approach that is used in soliton perturbation theory and (ii) scattering theory from quantum mechanics, we give a quantitative account of the evolution of all soliton parameters. In particular, we quantify the increase in the soliton peak power that may result in the spontaneous appearance of an extremely large, so-called champion soliton. The presented adiabatic theory agrees well with the numerical solutions of the pulse propagation equation. Moreover, we predict the full frequency band of the scattered dispersive waves and explain an emerging caustic structure in the space-time domain.

  9. Steam bottoming cycle for an adiabatic diesel engine

    NASA Technical Reports Server (NTRS)

    Poulin, E.; Demier, R.; Krepchin, I.; Walker, D.

    1984-01-01

    Steam bottoming cycles using adiabatic diesel engine exhaust heat which projected substantial performance and economic benefits for long haul trucks were studied. Steam cycle and system component variables, system cost, size and performance were analyzed. An 811 K/6.90 MPa state of the art reciprocating expander steam system with a monotube boiler and radiator core condenser was selected for preliminary design. The costs of the diesel with bottoming system (TC/B) and a NASA specified turbocompound adiabatic diesel with aftercooling with the same total output were compared, the annual fuel savings less the added maintenance cost was determined to cover the increase initial cost of the TC/B system in a payback period of 2.3 years. Steam bottoming system freeze protection strategies were developed, technological advances required for improved system reliability are considered and the cost and performance of advanced systes are evaluated.

  10. Fluctuations of work in nearly adiabatically driven open quantum systems.

    PubMed

    Suomela, S; Salmilehto, J; Savenko, I G; Ala-Nissila, T; Möttönen, M

    2015-02-01

    We extend the quantum jump method to nearly adiabatically driven open quantum systems in a way that allows for an accurate account of the external driving in the system-environment interaction. Using this framework, we construct the corresponding trajectory-dependent work performed on the system and derive the integral fluctuation theorem and the Jarzynski equality for nearly adiabatic driving. We show that such identities hold as long as the stochastic dynamics and work variable are consistently defined. We numerically study the emerging work statistics for a two-level quantum system and find that the conventional diabatic approximation is unable to capture some prominent features arising from driving, such as the continuity of the probability density of work. Our results reveal the necessity of using accurate expressions for the drive-dressed heat exchange in future experiments probing jump time distributions. PMID:25768477

  11. Coherent adiabatic transport of atoms in radio-frequency traps

    SciTech Connect

    Morgan, T.; O'Sullivan, B.; Busch, Th.

    2011-05-15

    Coherent transport by adiabatic passage has recently been suggested as a high-fidelity technique to engineer the center-of-mass state of single atoms in inhomogeneous environments. While the basic theory behind this process is well understood, several conceptual challenges for its experimental observation have still to be addressed. One of these is the difficulty that currently available optical or magnetic micro-trap systems have in adjusting the tunneling rate time dependently while keeping resonance between the asymptotic trapping states at all times. Here we suggest that both requirements can be fulfilled to a very high degree in an experimentally realistic setup based on radio-frequency traps on atom chips. We show that operations with close to 100% fidelity can be achieved and that these systems also allow significant improvements for performing adiabatic passage with interacting atomic clouds.

  12. Characterization of adiabatic shear bands in AM60B magnesium alloy under ballistic impact

    SciTech Connect

    Zou, D.L.; Zhen, L. Xu, C.Y.; Shao, W.Z.

    2011-05-15

    Adiabatic shear bands in Mg alloy under ballistic impact at a velocity of 0.5 km.s{sup -1} were characterized by means of optical microscope, scanning electron microscope, transmission electron microscope and indenter technique. The results show that adiabatic shear bands were formed around the impacted crater, and the deformed and transformed bands were distinguished by etching colors in metallographic observation. TEM observation shows that the deformed bands were composed of the elongated grains and high density dislocations, while the transformed bands composed of the ultrafine and equiaxed grains were confirmed. In initial stage, the severe localized plastic deformation led to the formation of elongated grains in the deformed bands. With localized strain increasing, the severe localized deformation assisted with the plastic temperature rising led to the severe deformation grains evolved into the ultrafine and equiaxed grains, while the deformed bands were developed into transformed bands. The formation of the ultrafine and equiaxed grains in the transformed bands should be attributed to the twinning-induced rotational dynamic recrystallization mechanism. High microhardness in the bands was obtained because of the strain hardening, grain refining and content concentration. - Research Highlights: {yields} Deformed and transformed bands are found in Mg alloy under ballistic impact. {yields} The microstructures in the deformed and transformed bands are characterized. {yields} The evolution process of the microstructure in the bands is discussed.

  13. Reduction of thioredoxin significantly decreases its partial specific volume and adiabatic compressibility.

    PubMed Central

    Kaminsky, S. M.; Richards, F. M.

    1992-01-01

    The partial specific volume and adiabatic compressibility were determined at several temperatures for oxidized and reduced Escherichia coli thioredoxin. Oxidized thioredoxin had a partial specific volume of 0.785-0.809 mL/g at the observed upper limit for all proteins whereas the partial specific volume of reduced thioredoxin was 0.745-0.755 mL/g, a value in the range found for a majority of proteins. The adiabatic compressibility of oxidized thioredoxin was also much larger (9.8-18 x 10(-12) cm2 dyne-1) than that of the reduced protein (3.8-7.3 x 10(-12)). Apart from the region immediately around the small disulfide loop, the structures of the oxidized (X-ray, crystal) and reduced protein (nuclear magnetic resonance, solution) are reported to be very similar. It would appear that alterations in the solvent layer in contact with the protein surface must play a major role in producing these large changes in the apparent specific volumes and compressibilities in this system. Some activities of thioredoxin require the reduced structure but are not electron transfer reactions. The large changes in physical parameters reported here suggest the possibility of a reversible metabolic control function for the SS bond. PMID:1304879

  14. Zero-point energy, tunneling, and vibrational adiabaticity in the Mu + H2 reaction

    SciTech Connect

    Mielke, Steven L.; Garrett, Bruce C.; Fleming, Donald G.; Truhlar, Donald G.

    2015-01-09

    Abstract: Isotopic substitution of muonium for hydrogen provides an unparalleled opportunity to deepen our understanding of quantum mass effects on chemical reactions. A recent topical review [Aldegunde et al., Mol. Phys. 111, 3169 (2013)] of the thermal and vibrationally-stateselected reaction of Mu with H2 raises a number of issues that are addressed here. We show that some earlier quantum mechanical calculations of the Mu + H2 reaction, which are highlighted in this review and which have been used to benchmark approximate methods, are in error by as much as 19% in the low-temperature limit. We demonstrate that an approximate treatment of the Born–Oppenheimer diagonal correction that was used in some recent studies is not valid for treating the vibrationally-state-selected reaction. We also discuss why vibrationally adiabatic potentials that neglect bend zero-point energy are not a useful analytical tool for understanding reaction rates and why vibrationally nonadiabatic transitions cannot be understood by considering tunneling through vibrationally adiabatic potentials. Finally, we present calculations on a hierarchical family of potential energy surfaces to assess the sensitivity of rate constants to the quality of the potential surface.

  15. Two-mode multiplexer and demultiplexer based on adiabatic couplers.

    PubMed

    Xing, Jiejiang; Li, Zhiyong; Xiao, Xi; Yu, Jinzhong; Yu, Yude

    2013-09-01

    A two-mode (de)multiplexer based on adiabatic couplers is proposed and experimentally demonstrated. The experimental results are in good agreement with the simulations. An ultralow mode cross talk below -36 dB and a low insertion loss of about 0.3 dB over a broad bandwidth from 1500 to 1600 nm are measured. The design is also fabrication-tolerant, and the insertion loss can be further improved in the future. PMID:23988986

  16. Excitation energies along a range-separated adiabatic connection

    SciTech Connect

    Rebolini, Elisa Toulouse, Julien Savin, Andreas; Teale, Andrew M.; Helgaker, Trygve

    2014-07-28

    We present a study of the variation of total energies and excitation energies along a range-separated adiabatic connection. This connection links the non-interacting Kohn–Sham electronic system to the physical interacting system by progressively switching on the electron–electron interactions whilst simultaneously adjusting a one-electron effective potential so as to keep the ground-state density constant. The interactions are introduced in a range-dependent manner, first introducing predominantly long-range, and then all-range, interactions as the physical system is approached, as opposed to the conventional adiabatic connection where the interactions are introduced by globally scaling the standard Coulomb interaction. Reference data are reported for the He and Be atoms and the H{sub 2} molecule, obtained by calculating the short-range effective potential at the full configuration-interaction level using Lieb's Legendre-transform approach. As the strength of the electron–electron interactions increases, the excitation energies, calculated for the partially interacting systems along the adiabatic connection, offer increasingly accurate approximations to the exact excitation energies. Importantly, the excitation energies calculated at an intermediate point of the adiabatic connection are much better approximations to the exact excitation energies than are the corresponding Kohn–Sham excitation energies. This is particularly evident in situations involving strong static correlation effects and states with multiple excitation character, such as the dissociating H{sub 2} molecule. These results highlight the utility of long-range interacting reference systems as a starting point for the calculation of excitation energies and are of interest for developing and analyzing practical approximate range-separated density-functional methodologies.

  17. Adiabaticity and gravity theory independent conservation laws for cosmological perturbations

    NASA Astrophysics Data System (ADS)

    Romano, Antonio Enea; Mooij, Sander; Sasaki, Misao

    2016-04-01

    We carefully study the implications of adiabaticity for the behavior of cosmological perturbations. There are essentially three similar but different definitions of non-adiabaticity: one is appropriate for a thermodynamic fluid δPnad, another is for a general matter field δPc,nad, and the last one is valid only on superhorizon scales. The first two definitions coincide if cs2 = cw2 where cs is the propagation speed of the perturbation, while cw2 = P ˙ / ρ ˙ . Assuming the adiabaticity in the general sense, δPc,nad = 0, we derive a relation between the lapse function in the comoving slicing Ac and δPnad valid for arbitrary matter field in any theory of gravity, by using only momentum conservation. The relation implies that as long as cs ≠cw, the uniform density, comoving and the proper-time slicings coincide approximately for any gravity theory and for any matter field if δPnad = 0 approximately. In the case of general relativity this gives the equivalence between the comoving curvature perturbation Rc and the uniform density curvature perturbation ζ on superhorizon scales, and their conservation. This is realized on superhorizon scales in standard slow-roll inflation. We then consider an example in which cw =cs, where δPnad = δPc,nad = 0 exactly, but the equivalence between Rc and ζ no longer holds. Namely we consider the so-called ultra slow-roll inflation. In this case both Rc and ζ are not conserved. In particular, as for ζ, we find that it is crucial to take into account the next-to-leading order term in ζ's spatial gradient expansion to show its non-conservation, even on superhorizon scales. This is an example of the fact that adiabaticity (in the thermodynamic sense) is not always enough to ensure the conservation of Rc or ζ.

  18. Adiabatic pipelining: a key to ternary computing with quantum dots.

    PubMed

    Pečar, P; Ramšak, A; Zimic, N; Mraz, M; Lebar Bajec, I

    2008-12-10

    The quantum-dot cellular automaton (QCA), a processing platform based on interacting quantum dots, was introduced by Lent in the mid-1990s. What followed was an exhilarating period with the development of the line, the functionally complete set of logic functions, as well as more complex processing structures, however all in the realm of binary logic. Regardless of these achievements, it has to be acknowledged that the use of binary logic is in computing systems mainly the end result of the technological limitations, which the designers had to cope with in the early days of their design. The first advancement of QCAs to multi-valued (ternary) processing was performed by Lebar Bajec et al, with the argument that processing platforms of the future should not disregard the clear advantages of multi-valued logic. Some of the elementary ternary QCAs, necessary for the construction of more complex processing entities, however, lead to a remarkable increase in size when compared to their binary counterparts. This somewhat negates the advantages gained by entering the ternary computing domain. As it turned out, even the binary QCA had its initial hiccups, which have been solved by the introduction of adiabatic switching and the application of adiabatic pipeline approaches. We present here a study that introduces adiabatic switching into the ternary QCA and employs the adiabatic pipeline approach to successfully solve the issues of elementary ternary QCAs. What is more, the ternary QCAs presented here are sizewise comparable to binary QCAs. This in our view might serve towards their faster adoption.

  19. Adiabatic expansion of a strongly correlated pure electron plasma

    SciTech Connect

    Dubin, D.H.E.; O'Neil, T.M.

    1986-02-17

    Adiabatic expansion is proposed as a method of increasing the degree of correlation of a magnetically confined pure electron plasma. Quantum mechanical effects and correlation effects make the physics of the expansion quite different from that for a classical ideal gas. The proposed expansion may be useful in a current experimental effort to cool a pure electron plasma to the liquid and solid (crystalline) states.

  20. Adiabatic expansion of a strongly correlated pure electron plasma

    NASA Astrophysics Data System (ADS)

    Dubin, D. H. E.; Oneil, T. M.

    1986-02-01

    Adiabatic expansion is proposed as a method of increasing the degree of correlation of a magnetically confined pure electron plasma. Quantum mechanical effects and correlation effects make the physics of the expansion quite different from that for a classical ideal gas. The proposed expansion may be useful in a current experimental effort to cool a pure electron plasma to the liquid and solid (crystalline) states.

  1. Geometric Phase for Adiabatic Evolutions of General Quantum States

    SciTech Connect

    Wu, Biao; Liu, Jie; Niu, Qian; Singh, David J

    2005-01-01

    The concept of a geometric phase (Berry's phase) is generalized to the case of noneigenstates, which is applicable to both linear and nonlinear quantum systems. This is particularly important to nonlinear quantum systems, where, due to the lack of the superposition principle, the adiabatic evolution of a general state cannot be described in terms of eigenstates. For linear quantum systems, our new geometric phase reduces to a statistical average of Berry's phases. Our results are demonstrated with a nonlinear two-level model.

  2. Complete Cycle Experiments Using the Adiabatic Gas Law Apparatus

    NASA Astrophysics Data System (ADS)

    Kutzner, Mickey D.; Plantak, Mateja

    2014-10-01

    The ability of our society to make informed energy-usage decisions in the future depends partly on current science and engineering students retaining a deep understanding of the thermodynamics of heat engines. Teacher imaginations and equipment budgets can both be taxed in the effort to engage students in hands-on heat engine activities. The experiments described in this paper, carried out using the Adiabatic Gas Law Apparatus1 (AGLA), quantitatively explore popular complete cycle heat engine processes.

  3. Adiabatic corrections to density functional theory energies and wave functions.

    PubMed

    Mohallem, José R; Coura, Thiago de O; Diniz, Leonardo G; de Castro, Gustavo; Assafrão, Denise; Heine, Thomas

    2008-09-25

    The adiabatic finite-nuclear-mass-correction (FNMC) to the electronic energies and wave functions of atoms and molecules is formulated for density-functional theory and implemented in the deMon code. The approach is tested for a series of local and gradient corrected density functionals, using MP2 results and diagonal-Born-Oppenheimer corrections from the literature for comparison. In the evaluation of absolute energy corrections of nonorganic molecules the LDA PZ81 functional works surprisingly better than the others. For organic molecules the GGA BLYP functional has the best performance. FNMC with GGA functionals, mainly BLYP, show a good performance in the evaluation of relative corrections, except for nonorganic molecules containing H atoms. The PW86 functional stands out with the best evaluation of the barrier of linearity of H2O and the isotopic dipole moment of HDO. In general, DFT functionals display an accuracy superior than the common belief and because the corrections are based on a change of the electronic kinetic energy they are here ranked in a new appropriate way. The approach is applied to obtain the adiabatic correction for full atomization of alcanes C(n)H(2n+2), n = 4-10. The barrier of 1 mHartree is approached for adiabatic corrections, justifying its insertion into DFT. PMID:18537228

  4. Non-adiabatic molecular dynamics by accelerated semiclassical Monte Carlo

    SciTech Connect

    White, Alexander J.; Gorshkov, Vyacheslav N.; Tretiak, Sergei; Mozyrsky, Dmitry

    2015-07-07

    Non-adiabatic dynamics, where systems non-radiatively transition between electronic states, plays a crucial role in many photo-physical processes, such as fluorescence, phosphorescence, and photoisomerization. Methods for the simulation of non-adiabatic dynamics are typically either numerically impractical, highly complex, or based on approximations which can result in failure for even simple systems. Recently, the Semiclassical Monte Carlo (SCMC) approach was developed in an attempt to combine the accuracy of rigorous semiclassical methods with the efficiency and simplicity of widely used surface hopping methods. However, while SCMC was found to be more efficient than other semiclassical methods, it is not yet as efficient as is needed to be used for large molecular systems. Here, we have developed two new methods: the accelerated-SCMC and the accelerated-SCMC with re-Gaussianization, which reduce the cost of the SCMC algorithm up to two orders of magnitude for certain systems. In most cases shown here, the new procedures are nearly as efficient as the commonly used surface hopping schemes, with little to no loss of accuracy. This implies that these modified SCMC algorithms will be of practical numerical solutions for simulating non-adiabatic dynamics in realistic molecular systems.

  5. Numerical study of polaron problem in the adiabatic limit

    NASA Astrophysics Data System (ADS)

    Marsiglio, Frank; Li, Zhou; Blois, Cindy; Baillie, Devin

    2010-03-01

    We study the polaron problem in a one dimensional chain and on a two dimensional square lattice. The models we have used are the Holstein model and the Su-Schrieffer-Heeger (SSH) model. By a variational procedure based on the Lanczos method, we are able to examine the polaron problem in the limit when the mass of the ion is very large, i.e. close to the adiabatic limit. It is known that for the Holstein model there is no phase transition [1] for any nonzero phonon energy. It is also known that for the one dimensional Holstein or SSH model there will be long range order [2] (e.g. dimerization) in the adiabatic limit at half-filling. It is then interesting to study the long range order on a two dimensional square lattice in and away from the adiabatic limit. Moreover, recent progress for the single polaron near an impurity (disorder) [3] make it an interesting problem for studying bond length disorder which can change the hopping energy in a specific direction in the Holstein model. Reference: [1] H. Lowen, Phys.Rev.B 37, 8661 (1988) [2] J.E.Hirsch and E. Frandkin, Phys. Rev. Lett. 49, 402 (1982) [3]A.S.Mishchenko et.al Phys.Rev.B 79(2009) 180301(R)

  6. Non-adiabatic molecular dynamics by accelerated semiclassical Monte Carlo.

    PubMed

    White, Alexander J; Gorshkov, Vyacheslav N; Tretiak, Sergei; Mozyrsky, Dmitry

    2015-07-01

    Non-adiabatic dynamics, where systems non-radiatively transition between electronic states, plays a crucial role in many photo-physical processes, such as fluorescence, phosphorescence, and photoisomerization. Methods for the simulation of non-adiabatic dynamics are typically either numerically impractical, highly complex, or based on approximations which can result in failure for even simple systems. Recently, the Semiclassical Monte Carlo (SCMC) approach was developed in an attempt to combine the accuracy of rigorous semiclassical methods with the efficiency and simplicity of widely used surface hopping methods. However, while SCMC was found to be more efficient than other semiclassical methods, it is not yet as efficient as is needed to be used for large molecular systems. Here, we have developed two new methods: the accelerated-SCMC and the accelerated-SCMC with re-Gaussianization, which reduce the cost of the SCMC algorithm up to two orders of magnitude for certain systems. In most cases shown here, the new procedures are nearly as efficient as the commonly used surface hopping schemes, with little to no loss of accuracy. This implies that these modified SCMC algorithms will be of practical numerical solutions for simulating non-adiabatic dynamics in realistic molecular systems. PMID:26156473

  7. Dynamics of Quantum Adiabatic Evolution Algorithm for Number Partitioning

    NASA Technical Reports Server (NTRS)

    Smelyanskiy, Vadius; vonToussaint, Udo V.; Timucin, Dogan A.; Clancy, Daniel (Technical Monitor)

    2002-01-01

    We have developed a general technique to study the dynamics of the quantum adiabatic evolution algorithm applied to random combinatorial optimization problems in the asymptotic limit of large problem size n. We use as an example the NP-complete Number Partitioning problem and map the algorithm dynamics to that of an auxiliary quantum spin glass system with the slowly varying Hamiltonian. We use a Green function method to obtain the adiabatic eigenstates and the minimum exitation gap, gmin = O(n2(sup -n/2)), corresponding to the exponential complexity of the algorithm for Number Partitioning. The key element of the analysis is the conditional energy distribution computed for the set of all spin configurations generated from a given (ancestor) configuration by simultaneous flipping of a fixed number of spins. For the problem in question this distribution is shown to depend on the ancestor spin configuration only via a certain parameter related to the energy of the configuration. As the result, the algorithm dynamics can be described in terms of one-dimensional quantum diffusion in the energy space. This effect provides a general limitation of a quantum adiabatic computation in random optimization problems. Analytical results are in agreement with the numerical simulation of the algorithm.

  8. Dynamics of Quantum Adiabatic Evolution Algorithm for Number Partitioning

    NASA Technical Reports Server (NTRS)

    Smelyanskiy, V. N.; Toussaint, U. V.; Timucin, D. A.

    2002-01-01

    We have developed a general technique to study the dynamics of the quantum adiabatic evolution algorithm applied to random combinatorial optimization problems in the asymptotic limit of large problem size n. We use as an example the NP-complete Number Partitioning problem and map the algorithm dynamics to that of an auxiliary quantum spin glass system with the slowly varying Hamiltonian. We use a Green function method to obtain the adiabatic eigenstates and the minimum excitation gap. g min, = O(n 2(exp -n/2), corresponding to the exponential complexity of the algorithm for Number Partitioning. The key element of the analysis is the conditional energy distribution computed for the set of all spin configurations generated from a given (ancestor) configuration by simultaneous flipping of a fixed number of spins. For the problem in question this distribution is shown to depend on the ancestor spin configuration only via a certain parameter related to 'the energy of the configuration. As the result, the algorithm dynamics can be described in terms of one-dimensional quantum diffusion in the energy space. This effect provides a general limitation of a quantum adiabatic computation in random optimization problems. Analytical results are in agreement with the numerical simulation of the algorithm.

  9. Steam bottoming cycle for an adiabatic diesel engine

    SciTech Connect

    Poulin, E.; Demler, R.; Krepchin, I.; Walker, D.

    1984-03-01

    A study of steam bottoming cycles using adiabatic diesel engine exhaust heat projected substantial performance and economic benefits for long haul trucks. A parametric analysis of steam cycle and system component variables, system cost, size and performance was conducted. An 811 K/6.90 MPa state-of-the-art reciprocating expander steam system with a monotube boiler and radiator core condenser was selected for preliminary design. When applied to a NASA specified turbo-charged adiabatic diesel the bottoming system increased the diesel output by almost 18%. In a comparison of the costs of the diesel with bottoming system (TC/B) and a NASA specified turbocompound adiabatic diesel with after-cooling with the same total output, the annual fuel savings less the added maintenance cost was determined to cover the increased initial cost of the TC/B system in a payback period of 2.3 years. Also during this program steam bottoming system freeze protection strategies were developed, technological advances required for improved system reliability were considered and the cost and performance of advanced systems were evaluated.

  10. NMR implementation of adiabatic SAT algorithm using strongly modulated pulses.

    PubMed

    Mitra, Avik; Mahesh, T S; Kumar, Anil

    2008-03-28

    NMR implementation of adiabatic algorithms face severe problems in homonuclear spin systems since the qubit selective pulses are long and during this period, evolution under the Hamiltonian and decoherence cause errors. The decoherence destroys the answer as it causes the final state to evolve to mixed state and in homonuclear systems, evolution under the internal Hamiltonian causes phase errors preventing the initial state to converge to the solution state. The resolution of these issues is necessary before one can proceed to implement an adiabatic algorithm in a large system where homonuclear coupled spins will become a necessity. In the present work, we demonstrate that by using "strongly modulated pulses" (SMPs) for the creation of interpolating Hamiltonian, one can circumvent both the problems and successfully implement the adiabatic SAT algorithm in a homonuclear three qubit system. This work also demonstrates that the SMPs tremendously reduce the time taken for the implementation of the algorithm, can overcome problems associated with decoherence, and will be the modality in future implementation of quantum information processing by NMR. PMID:18376911

  11. NMR implementation of adiabatic SAT algorithm using strongly modulated pulses

    NASA Astrophysics Data System (ADS)

    Mitra, Avik; Mahesh, T. S.; Kumar, Anil

    2008-03-01

    NMR implementation of adiabatic algorithms face severe problems in homonuclear spin systems since the qubit selective pulses are long and during this period, evolution under the Hamiltonian and decoherence cause errors. The decoherence destroys the answer as it causes the final state to evolve to mixed state and in homonuclear systems, evolution under the internal Hamiltonian causes phase errors preventing the initial state to converge to the solution state. The resolution of these issues is necessary before one can proceed to implement an adiabatic algorithm in a large system where homonuclear coupled spins will become a necessity. In the present work, we demonstrate that by using "strongly modulated pulses" (SMPs) for the creation of interpolating Hamiltonian, one can circumvent both the problems and successfully implement the adiabatic SAT algorithm in a homonuclear three qubit system. This work also demonstrates that the SMPs tremendously reduce the time taken for the implementation of the algorithm, can overcome problems associated with decoherence, and will be the modality in future implementation of quantum information processing by NMR.

  12. Non-adiabatic molecular dynamics by accelerated semiclassical Monte Carlo

    DOE PAGES

    White, Alexander J.; Gorshkov, Vyacheslav N.; Tretiak, Sergei; Mozyrsky, Dmitry

    2015-07-07

    Non-adiabatic dynamics, where systems non-radiatively transition between electronic states, plays a crucial role in many photo-physical processes, such as fluorescence, phosphorescence, and photoisomerization. Methods for the simulation of non-adiabatic dynamics are typically either numerically impractical, highly complex, or based on approximations which can result in failure for even simple systems. Recently, the Semiclassical Monte Carlo (SCMC) approach was developed in an attempt to combine the accuracy of rigorous semiclassical methods with the efficiency and simplicity of widely used surface hopping methods. However, while SCMC was found to be more efficient than other semiclassical methods, it is not yet as efficientmore » as is needed to be used for large molecular systems. Here, we have developed two new methods: the accelerated-SCMC and the accelerated-SCMC with re-Gaussianization, which reduce the cost of the SCMC algorithm up to two orders of magnitude for certain systems. In many cases shown here, the new procedures are nearly as efficient as the commonly used surface hopping schemes, with little to no loss of accuracy. This implies that these modified SCMC algorithms will be of practical numerical solutions for simulating non-adiabatic dynamics in realistic molecular systems.« less

  13. Non-adiabatic molecular dynamics by accelerated semiclassical Monte Carlo

    SciTech Connect

    White, Alexander J.; Gorshkov, Vyacheslav N.; Tretiak, Sergei; Mozyrsky, Dmitry

    2015-07-07

    Non-adiabatic dynamics, where systems non-radiatively transition between electronic states, plays a crucial role in many photo-physical processes, such as fluorescence, phosphorescence, and photoisomerization. Methods for the simulation of non-adiabatic dynamics are typically either numerically impractical, highly complex, or based on approximations which can result in failure for even simple systems. Recently, the Semiclassical Monte Carlo (SCMC) approach was developed in an attempt to combine the accuracy of rigorous semiclassical methods with the efficiency and simplicity of widely used surface hopping methods. However, while SCMC was found to be more efficient than other semiclassical methods, it is not yet as efficient as is needed to be used for large molecular systems. Here, we have developed two new methods: the accelerated-SCMC and the accelerated-SCMC with re-Gaussianization, which reduce the cost of the SCMC algorithm up to two orders of magnitude for certain systems. In many cases shown here, the new procedures are nearly as efficient as the commonly used surface hopping schemes, with little to no loss of accuracy. This implies that these modified SCMC algorithms will be of practical numerical solutions for simulating non-adiabatic dynamics in realistic molecular systems.

  14. Irreconcilable difference between quantum walks and adiabatic quantum computing

    NASA Astrophysics Data System (ADS)

    Wong, Thomas G.; Meyer, David A.

    2016-06-01

    Continuous-time quantum walks and adiabatic quantum evolution are two general techniques for quantum computing, both of which are described by Hamiltonians that govern their evolutions by Schrödinger's equation. In the former, the Hamiltonian is fixed, while in the latter, the Hamiltonian varies with time. As a result, their formulations of Grover's algorithm evolve differently through Hilbert space. We show that this difference is fundamental; they cannot be made to evolve along each other's path without introducing structure more powerful than the standard oracle for unstructured search. For an adiabatic quantum evolution to evolve like the quantum walk search algorithm, it must interpolate between three fixed Hamiltonians, one of which is complex and introduces structure that is stronger than the oracle for unstructured search. Conversely, for a quantum walk to evolve along the path of the adiabatic search algorithm, it must be a chiral quantum walk on a weighted, directed star graph with structure that is also stronger than the oracle for unstructured search. Thus, the two techniques, although similar in being described by Hamiltonians that govern their evolution, compute by fundamentally irreconcilable means.

  15. Saturation and pulsed FEL dynamics

    SciTech Connect

    Giannessi, L.; Mezi, L.

    1995-12-31

    The behavior of a FEL operating in the saturated pulsed regime, may be reproduced by the linear FEL integral equation, suitably modified to include saturation effects through a gain depression coefficient depending on the laser intensity. This simple method allows to evaluate several FEL parameters like gain, efficiency, band-width and optical pulse duration as functions of the optical cavity length, only with a numerical integration. The predictions have been compared with available experimental and numerical data, and the method has been applied to estimate the operating characteristics of some planned FEL experiments.

  16. Solid-state lamps with optimized color saturation ability.

    PubMed

    Zukauskas, Artūras; Vaicekauskas, Rimantas; Shur, Michael

    2010-02-01

    Spectral power distribution of trichromatic clusters of light-emitting diodes (LEDs) was optimized for rendering the highest number of colors with a perceptually noticeable gain in chroma (color saturation) out of 1269 Munsell samples. The basic tradeoffs of the number of colors rendered with increased saturation with the number of colors rendered with high fidelity and with luminous efficacy of radiation were established. High-saturation RGB clusters composed of commercially available AlGaInP and InGaN LEDs were modeled for a standard set of correlated color temperatures and the stability of the color saturation ability of the clusters against the drift of peak wavelengths was investigated. PMID:20174057

  17. Experimental investigation of saturated degenerate four-wave mixing for quantitative concentration measurements.

    PubMed

    Reichardt, T A; Giancola, W C; Shappert, C M; Lucht, R P

    1999-11-20

    Degenerate four-wave mixing (DFWM) line shapes and signal intensities are measured experimentally in well-characterized hydrogen-air flames operated over a wide range of equivalence ratios. We use both low (perturbative) and high (saturating) beam intensities in the phase-conjugate geometry. Resonances in the A 2Sigma+ -X 2II (0,0) band of OH are probed with multiaxial-mode laser radiation. The effects of saturation on the line-center signal intensity and the resonance linewidth are investigated. The DFWM signal intensities are used to measure OH number densities in a series of near-adiabatic flames at equivalence ratios ranging from 0.5 to 1.5. Use of saturating pump intensities minimizes the effects of beam absorption, providing more-accurate number density measurements. The saturated DFWM results are in excellent agreement with OH absorption measurements and equilibrium calculations of OH number density. The polarization dependence of the P(1)(2) and R(2)(1) resonances is investigated in both laser intensity regimes. There is a significant change in relative reflectivities for different polarization configurations when saturated. PMID:18324238

  18. Geometric effects in nonequilibrium electron transfer statistics in adiabatically driven quantum junctions

    NASA Astrophysics Data System (ADS)

    Goswami, Himangshu Prabal; Agarwalla, Bijay Kumar; Harbola, Upendra

    2016-05-01

    Cyclic Pancharatnam-Berry (PB) and adiabatic noncyclic geometric (ANG) effects are investigated in a single electron orbital system connected to two metal contacts with externally driven chemical potential and/or temperatures. The PB contribution doesn't affect the density matrix evolution, but has a quantitative effect on the statistics (fluctuations) of electron transfer. The ANG contribution, on the other hand, affects the net flux across the junction. Unlike the PB, the ANG contribution is nonzero when two parameters are identically driven. Closed analytical expressions are derived for the ANG contribution to the flux, and the PB contribution to the first two leading order fluctuations. Fluctuations can be modified by manipulating the relative phases of the drivings. Interestingly, we find that the fluctuations of the pumped charge do not satisfy the steady state fluctuation theorem in presence of nonzero geometric contribution, but can be recovered for a vanishing geometric contribution even in presence of the external driving.

  19. Adiabatically twisting a magnetic molecule to generate pure spin currents in graphene

    NASA Astrophysics Data System (ADS)

    Islam, Firoz; Benjamin, Colin

    2016-01-01

    The spin-orbit effect in graphene is too muted to have any observable significance with respect to its application in spintronics. However, graphene technology is too valuable to be rendered impotent to spin transport. In this communication we look at the effect of adiabatically twisting a single-molecule magnet embedded in a graphene monolayer. Surprisingly, we see that pure spin currents (zero charge current) can be generated from the system via quantum pumping. In addition we also see that spin-selective current can be pumped from the system. The pure spin current seen is quite resilient to temperature while disorder has a limited effect. Furthermore, the direction of these spin-pumped currents can be easily and exclusively controlled by the magnetization of the single-molecule magnet, with disorder having no effect on the magnetization control of the pumped spin currents.

  20. Quantum state specific reactant preparation in a molecular beam by rapid adiabatic passage.

    PubMed

    Chadwick, Helen; Hundt, P Morten; van Reijzen, Maarten E; Yoder, Bruce L; Beck, Rainer D

    2014-01-21

    Highly efficient preparation of molecules in a specific rovibrationally excited state for gas/surface reactivity measurements is achieved in a molecular beam using tunable infrared (IR) radiation from a single mode continuous wave optical parametric oscillator (cw-OPO). We demonstrate that with appropriate focusing of the IR radiation, molecules in the molecular beam crossing the fixed frequency IR field experience a Doppler tuning that can be adjusted to achieve complete population inversion of a two-level system by rapid adiabatic passage (RAP). A room temperature pyroelectric detector is used to monitor the excited fraction in the molecular beam and the population inversion is detected and quantified using IR bleaching by a second IR-OPO. The second OPO is also used for complete population transfer to an overtone or combination vibration via double resonance excitation using two spatially separated RAP processes.

  1. Specific absorption rate determination of magnetic nanoparticles through hyperthermia measurements in non-adiabatic conditions

    NASA Astrophysics Data System (ADS)

    Coïsson, M.; Barrera, G.; Celegato, F.; Martino, L.; Vinai, F.; Martino, P.; Ferraro, G.; Tiberto, P.

    2016-10-01

    An experimental setup for magnetic hyperthermia operating in non-adiabatic conditions is described. A thermodynamic model that takes into account the heat exchanged by the sample with the surrounding environment is developed. A suitable calibration procedure is proposed that allows the experimental validation of the model. Specific absorption rate can then be accurately determined just from the measurement of the sample temperature at the equilibrium steady state. The setup and the measurement procedure represent a simplification with respect to other systems requiring calorimeters or crucial corrections for heat flow. Two families of magnetic nanoparticles, one superparamagnetic and one characterised by larger sizes and static hysteresis, have been characterised as a function of field intensity, and specific absorption rate and intrinsic loss power have been obtained.

  2. Quantum state specific reactant preparation in a molecular beam by rapid adiabatic passage.

    PubMed

    Chadwick, Helen; Hundt, P Morten; van Reijzen, Maarten E; Yoder, Bruce L; Beck, Rainer D

    2014-01-21

    Highly efficient preparation of molecules in a specific rovibrationally excited state for gas/surface reactivity measurements is achieved in a molecular beam using tunable infrared (IR) radiation from a single mode continuous wave optical parametric oscillator (cw-OPO). We demonstrate that with appropriate focusing of the IR radiation, molecules in the molecular beam crossing the fixed frequency IR field experience a Doppler tuning that can be adjusted to achieve complete population inversion of a two-level system by rapid adiabatic passage (RAP). A room temperature pyroelectric detector is used to monitor the excited fraction in the molecular beam and the population inversion is detected and quantified using IR bleaching by a second IR-OPO. The second OPO is also used for complete population transfer to an overtone or combination vibration via double resonance excitation using two spatially separated RAP processes. PMID:25669393

  3. Extended adiabatic blast waves and a model of the soft X-ray background. [interstellar matter

    NASA Technical Reports Server (NTRS)

    Cox, D. P.; Anderson, P. R.

    1981-01-01

    An analytical approximation is generated which follows the development of an adiabatic spherical blast wave in a homogeneous ambient medium of finite pressure. An analytical approximation is also presented for the electron temperature distribution resulting from coulomb collisional heating. The dynamical, thermal, ionization, and spectral structures are calculated for blast waves of energy E sub 0 = 5 x 10 to the 50th power ergs in a hot low-density interstellar environment. A formula is presented for estimating the luminosity evolution of such explosions. The B and C bands of the soft X-ray background, it is shown, are reproduced by such a model explosion if the ambient density is about .000004 cm, the blast radius is roughly 100 pc, and the solar system is located inside the shocked region. Evolution in a pre-existing cavity with a strong density gradient may, it is suggested, remove both the M band and OVI discrepancies.

  4. Quantum state specific reactant preparation in a molecular beam by rapid adiabatic passage

    SciTech Connect

    Chadwick, Helen Hundt, P. Morten; Reijzen, Maarten E. van; Yoder, Bruce L.; Beck, Rainer D.

    2014-01-21

    Highly efficient preparation of molecules in a specific rovibrationally excited state for gas/surface reactivity measurements is achieved in a molecular beam using tunable infrared (IR) radiation from a single mode continuous wave optical parametric oscillator (cw-OPO). We demonstrate that with appropriate focusing of the IR radiation, molecules in the molecular beam crossing the fixed frequency IR field experience a Doppler tuning that can be adjusted to achieve complete population inversion of a two-level system by rapid adiabatic passage (RAP). A room temperature pyroelectric detector is used to monitor the excited fraction in the molecular beam and the population inversion is detected and quantified using IR bleaching by a second IR-OPO. The second OPO is also used for complete population transfer to an overtone or combination vibration via double resonance excitation using two spatially separated RAP processes.

  5. Statistical theory of rarified gases in the coulomb model of substance: Adiabatic approximation and initial atoms

    NASA Astrophysics Data System (ADS)

    Bobrov, V. B.

    2014-03-01

    In the framework of the adiabatic approximation for a subsystem of nuclei with the average distance between them significantly exceeding the dimensions of the initial atom, we consider a nonrelativistic Coulomb system consisting of electrons and nuclei of one type for the temperature range where we can restrict ourself to using the ground state to describe the electron subsystem. We show that the equilibrium properties of such a system are equivalent to the thermodynamic properties of the one-component system of initial atoms interacting between themselves via a short-range potential that is the effective potential of the nucleus-nucleus interaction. In the framework of the applicability of Boltzmann statistics, we present quantum group expansions for the thermodynamic properties of a chemically reacting rarified gas that correspond to the method of initial atoms.

  6. Quantum state specific reactant preparation in a molecular beam by rapid adiabatic passage

    NASA Astrophysics Data System (ADS)

    Chadwick, Helen; Hundt, P. Morten; van Reijzen, Maarten E.; Yoder, Bruce L.; Beck, Rainer D.

    2014-01-01

    Highly efficient preparation of molecules in a specific rovibrationally excited state for gas/surface reactivity measurements is achieved in a molecular beam using tunable infrared (IR) radiation from a single mode continuous wave optical parametric oscillator (cw-OPO). We demonstrate that with appropriate focusing of the IR radiation, molecules in the molecular beam crossing the fixed frequency IR field experience a Doppler tuning that can be adjusted to achieve complete population inversion of a two-level system by rapid adiabatic passage (RAP). A room temperature pyroelectric detector is used to monitor the excited fraction in the molecular beam and the population inversion is detected and quantified using IR bleaching by a second IR-OPO. The second OPO is also used for complete population transfer to an overtone or combination vibration via double resonance excitation using two spatially separated RAP processes.

  7. Helium Saturation of Liquid Propellants

    NASA Technical Reports Server (NTRS)

    Yavrouian, A. H.; Moran, Clifford M.

    1990-01-01

    The research is in three areas which are: (1) techniques were devised for achieving the required levels of helium (He) saturation in liquid propellants (limited to monomethylhydrazine (MMH) and nitrogen tetroxide (NTO)); (2) the values were evaluated for equilibrium solubilities of He in liquid propellants as currently used in the industry; and (3) the He dissolved in liquid propellants were accurately measured. Conclusions drawn from these studies include: (1) Techniques for dissolving He in liquid propellants depending upon the capabilities of the testing facility (Verification of the quantity of gas dissolved is essential); (2) Until greater accuracy is obtained, the equilibrium solubility values of He in MMH and NTO as cited in the Air Force Propellant Handbooks should be accepted as standard (There are still enough uncertainties in the He saturation values to warrant further basic experimental studies); and (3) The manometric measurement of gas volume from a frozen sample of propellant should be the accepted method for gas analysis.

  8. Criteria for saturated magnetization loop

    NASA Astrophysics Data System (ADS)

    Harres, A.; Mikhov, M.; Skumryev, V.; Andrade, A. M. H. de; Schmidt, J. E.; Geshev, J.

    2016-03-01

    Proper estimation of magnetization curve parameters is vital in studying magnetic systems. In the present article, criteria for discrimination non-saturated (minor) from saturated (major) hysteresis loops are proposed. These employ the analysis of (i) derivatives of both ascending and descending branches of the loop, (ii) remanent magnetization curves, and (iii) thermomagnetic curves. Computational simulations are used in order to demonstrate their validity. Examples illustrating the applicability of these criteria to well-known real systems, namely Fe3O4 and Ni fine particles, are provided. We demonstrate that the anisotropy-field value estimated from a visual examination of an only apparently major hysteresis loop could be more than two times lower than the real one.

  9. Adiabatic quantum computing with spin qubits hosted by molecules.

    PubMed

    Yamamoto, Satoru; Nakazawa, Shigeaki; Sugisaki, Kenji; Sato, Kazunobu; Toyota, Kazuo; Shiomi, Daisuke; Takui, Takeji

    2015-01-28

    A molecular spin quantum computer (MSQC) requires electron spin qubits, which pulse-based electron spin/magnetic resonance (ESR/MR) techniques can afford to manipulate for implementing quantum gate operations in open shell molecular entities. Importantly, nuclear spins, which are topologically connected, particularly in organic molecular spin systems, are client qubits, while electron spins play a role of bus qubits. Here, we introduce the implementation for an adiabatic quantum algorithm, suggesting the possible utilization of molecular spins with optimized spin structures for MSQCs. We exemplify the utilization of an adiabatic factorization problem of 21, compared with the corresponding nuclear magnetic resonance (NMR) case. Two molecular spins are selected: one is a molecular spin composed of three exchange-coupled electrons as electron-only qubits and the other an electron-bus qubit with two client nuclear spin qubits. Their electronic spin structures are well characterized in terms of the quantum mechanical behaviour in the spin Hamiltonian. The implementation of adiabatic quantum computing/computation (AQC) has, for the first time, been achieved by establishing ESR/MR pulse sequences for effective spin Hamiltonians in a fully controlled manner of spin manipulation. The conquered pulse sequences have been compared with the NMR experiments and shown much faster CPU times corresponding to the interaction strength between the spins. Significant differences are shown in rotational operations and pulse intervals for ESR/MR operations. As a result, we suggest the advantages and possible utilization of the time-evolution based AQC approach for molecular spin quantum computers and molecular spin quantum simulators underlain by sophisticated ESR/MR pulsed spin technology.

  10. Shortcuts to adiabaticity by counterdiabatic driving for trapped-ion displacement in phase space

    NASA Astrophysics Data System (ADS)

    An, Shuoming; Lv, Dingshun; Del Campo, Adolfo; Kim, Kihwan

    2016-09-01

    The application of adiabatic protocols in quantum technologies is severely limited by environmental sources of noise and decoherence. Shortcuts to adiabaticity by counterdiabatic driving constitute a powerful alternative that speed up time-evolution while mimicking adiabatic dynamics. Here we report the experimental implementation of counterdiabatic driving in a continuous variable system, a shortcut to the adiabatic transport of a trapped ion in phase space. The resulting dynamics is equivalent to a `fast-motion video' of the adiabatic trajectory. The robustness of this protocol is shown to surpass that of competing schemes based on classical local controls and Fourier optimization methods. Our results demonstrate that shortcuts to adiabaticity provide a robust speedup of quantum protocols of wide applicability in quantum technologies.

  11. Kibble-Zurek mechanism beyond adiabaticity: Finite-time scaling with critical initial slip

    NASA Astrophysics Data System (ADS)

    Huang, Yingyi; Yin, Shuai; Hu, Qijun; Zhong, Fan

    2016-01-01

    The Kibble-Zurek mechanism demands an initial adiabatic stage before an impulse stage to have a frozen correlation length that generates topological defects in a cooling phase transition. Here we study such a driven critical dynamics but with an initial condition that is near the critical point and that is far away from equilibrium. In this case, there is no initial adiabatic stage at all and thus adiabaticity is broken. However, we show that there again exists a finite length scale arising from the driving that divides the evolution into three stages. A relaxation-finite-time-scaling-adiabatic scenario is then proposed in place of the adiabatic-impulse-adiabatic scenario of the original Kibble-Zurek mechanism. A unified scaling theory, which combines finite-time scaling with critical initial slip, is developed to describe the universal behavior and is confirmed with numerical simulations of a two-dimensional classical Ising model.

  12. Effect of Grain Boundary Character Distribution on the Adiabatic Shear Susceptibility

    NASA Astrophysics Data System (ADS)

    Yang, Yang; Jiang, Lihong; Luo, Shuhong; Hu, Haibo; Tang, Tiegang; Zhang, Qingming

    2016-11-01

    The adiabatic shear susceptibility of AISI321 stainless steels with different grain boundary character distributions (GBCDs) was investigated by means of split-Hopkinson pressure bar. The results indicate that the width of the adiabatic shear band of the specimen after thermomechanical processing (TMP) treatment is narrower. The comparison of the stress collapse time, the critical stress, and the adiabatic shear forming energy suggests that the TMP specimens have lower adiabatic shear susceptibility than that of the solution-treated samples under the same loading condition. GBCD and grain size affected the adiabatic shear susceptibility. The high-angle boundary network of the TMP specimens was interrupted or replaced by the special grain boundary, and smaller grain size hindered the adiabatic shearing.

  13. Shortcuts to adiabaticity by counterdiabatic driving for trapped-ion displacement in phase space

    PubMed Central

    An, Shuoming; Lv, Dingshun; del Campo, Adolfo; Kim, Kihwan

    2016-01-01

    The application of adiabatic protocols in quantum technologies is severely limited by environmental sources of noise and decoherence. Shortcuts to adiabaticity by counterdiabatic driving constitute a powerful alternative that speed up time-evolution while mimicking adiabatic dynamics. Here we report the experimental implementation of counterdiabatic driving in a continuous variable system, a shortcut to the adiabatic transport of a trapped ion in phase space. The resulting dynamics is equivalent to a ‘fast-motion video' of the adiabatic trajectory. The robustness of this protocol is shown to surpass that of competing schemes based on classical local controls and Fourier optimization methods. Our results demonstrate that shortcuts to adiabaticity provide a robust speedup of quantum protocols of wide applicability in quantum technologies. PMID:27669897

  14. Saturation of the turbulent dynamo.

    PubMed

    Schober, J; Schleicher, D R G; Federrath, C; Bovino, S; Klessen, R S

    2015-08-01

    The origin of strong magnetic fields in the Universe can be explained by amplifying weak seed fields via turbulent motions on small spatial scales and subsequently transporting the magnetic energy to larger scales. This process is known as the turbulent dynamo and depends on the properties of turbulence, i.e., on the hydrodynamical Reynolds number and the compressibility of the gas, and on the magnetic diffusivity. While we know the growth rate of the magnetic energy in the linear regime, the saturation level, i.e., the ratio of magnetic energy to turbulent kinetic energy that can be reached, is not known from analytical calculations. In this paper we present a scale-dependent saturation model based on an effective turbulent resistivity which is determined by the turnover time scale of turbulent eddies and the magnetic energy density. The magnetic resistivity increases compared to the Spitzer value and the effective scale on which the magnetic energy spectrum is at its maximum moves to larger spatial scales. This process ends when the peak reaches a characteristic wave number k☆ which is determined by the critical magnetic Reynolds number. The saturation level of the dynamo also depends on the type of turbulence and differs for the limits of large and small magnetic Prandtl numbers Pm. With our model we find saturation levels between 43.8% and 1.3% for Pm≫1 and between 2.43% and 0.135% for Pm≪1, where the higher values refer to incompressible turbulence and the lower ones to highly compressible turbulence. PMID:26382506

  15. Saturation of the turbulent dynamo.

    PubMed

    Schober, J; Schleicher, D R G; Federrath, C; Bovino, S; Klessen, R S

    2015-08-01

    The origin of strong magnetic fields in the Universe can be explained by amplifying weak seed fields via turbulent motions on small spatial scales and subsequently transporting the magnetic energy to larger scales. This process is known as the turbulent dynamo and depends on the properties of turbulence, i.e., on the hydrodynamical Reynolds number and the compressibility of the gas, and on the magnetic diffusivity. While we know the growth rate of the magnetic energy in the linear regime, the saturation level, i.e., the ratio of magnetic energy to turbulent kinetic energy that can be reached, is not known from analytical calculations. In this paper we present a scale-dependent saturation model based on an effective turbulent resistivity which is determined by the turnover time scale of turbulent eddies and the magnetic energy density. The magnetic resistivity increases compared to the Spitzer value and the effective scale on which the magnetic energy spectrum is at its maximum moves to larger spatial scales. This process ends when the peak reaches a characteristic wave number k☆ which is determined by the critical magnetic Reynolds number. The saturation level of the dynamo also depends on the type of turbulence and differs for the limits of large and small magnetic Prandtl numbers Pm. With our model we find saturation levels between 43.8% and 1.3% for Pm≫1 and between 2.43% and 0.135% for Pm≪1, where the higher values refer to incompressible turbulence and the lower ones to highly compressible turbulence.

  16. From Classical Nonlinear Integrable Systems to Quantum Shortcuts to Adiabaticity.

    PubMed

    Okuyama, Manaka; Takahashi, Kazutaka

    2016-08-12

    Using shortcuts to adiabaticity, we solve the time-dependent Schrödinger equation that is reduced to a classical nonlinear integrable equation. For a given time-dependent Hamiltonian, the counterdiabatic term is introduced to prevent nonadiabatic transitions. Using the fact that the equation for the dynamical invariant is equivalent to the Lax equation in nonlinear integrable systems, we obtain the counterdiabatic term exactly. The counterdiabatic term is available when the corresponding Lax pair exists and the solvable systems are classified in a unified and systematic way. Multisoliton potentials obtained from the Korteweg-de Vries equation and isotropic XY spin chains from the Toda equations are studied in detail.

  17. From Classical Nonlinear Integrable Systems to Quantum Shortcuts to Adiabaticity

    NASA Astrophysics Data System (ADS)

    Okuyama, Manaka; Takahashi, Kazutaka

    2016-08-01

    Using shortcuts to adiabaticity, we solve the time-dependent Schrödinger equation that is reduced to a classical nonlinear integrable equation. For a given time-dependent Hamiltonian, the counterdiabatic term is introduced to prevent nonadiabatic transitions. Using the fact that the equation for the dynamical invariant is equivalent to the Lax equation in nonlinear integrable systems, we obtain the counterdiabatic term exactly. The counterdiabatic term is available when the corresponding Lax pair exists and the solvable systems are classified in a unified and systematic way. Multisoliton potentials obtained from the Korteweg-de Vries equation and isotropic X Y spin chains from the Toda equations are studied in detail.

  18. Magnetic shielding for a spaceborne adiabatic demagnetization refrigerator (ADR)

    NASA Technical Reports Server (NTRS)

    Warner, Brent A.; Shirron, Peter J.; Castles, Stephen H.; Serlemitsos, Aristides T.

    1991-01-01

    The Goddard Space Flight Center has studied magnetic shielding for an adiabatic demagnetization refrigerator. Four types of shielding were studied: active coils, passive ferromagnetic shells, passive superconducting coils, and passive superconducting shells. The passive superconducting shells failed by allowing flux penetration. The other three methods were successful, singly or together. Experimental studies of passive ferromagnetic shielding are compared with calculations made using the Poisson Group of programs, distributed by the Los Alamos Accelerator Code Group of the Los Alamos National Laboratory. Agreement between calculation and experiment is good. The ferromagnetic material is a silicon iron alloy.

  19. More bang for your buck: Super-adiabatic quantum engines

    PubMed Central

    Campo, A. del; Goold, J.; Paternostro, M.

    2014-01-01

    The practical untenability of the quasi-static assumption makes any realistic engine intrinsically irreversible and its operating time finite, thus implying friction effects at short cycle times. An important technological goal is thus the design of maximally efficient engines working at the maximum possible power. We show that, by utilising shortcuts to adiabaticity in a quantum engine cycle, one can engineer a thermodynamic cycle working at finite power and zero friction. Our findings are illustrated using a harmonic oscillator undergoing a quantum Otto cycle. PMID:25163421

  20. Non-Adiabatic Holonomic Quantum Gates in an atomic system

    NASA Astrophysics Data System (ADS)

    Azimi Mousolou, Vahid; Canali, Carlo M.; Sjoqvist, Erik

    2012-02-01

    Quantum computation is essentially the implementation of a universal set of quantum gate operations on a set of qubits, which is reliable in the presence of noise. We propose a scheme to perform robust gates in an atomic four-level system using the idea of non-adiabatic holonomic quantum computation proposed in [1]. The gates are realized by applying sequences of short laser pulses that drive transitions between the four energy levels in such a way that the dynamical phases vanish. [4pt] [1] E. Sjoqvist, D.M. Tong, B. Hessmo, M. Johansson, K. Singh, arXiv:1107.5127v2 [quant-ph

  1. Gravitational radiation reaction and inspiral waveforms in the adiabatic limit.

    PubMed

    Hughes, Scott A; Drasco, Steve; Flanagan, Eanna E; Franklin, Joel

    2005-06-10

    We describe progress evolving an important limit of binaries in general relativity: stellar mass compact objects spiraling into much larger black holes. Such systems are of great observational interest. We have developed tools to compute for the first time the radiation from generic orbits. Using global conservation laws, we find the orbital evolution and waveforms for special cases. For generic orbits, inspirals and waveforms can be found by augmenting our approach with an adiabatic self-force rule due to Mino. Such waveforms should be accurate enough for gravitational-wave searches. PMID:16090377

  2. Relativistic blast waves in two dimensions. I - The adiabatic case

    NASA Technical Reports Server (NTRS)

    Shapiro, P. R.

    1979-01-01

    Approximate solutions are presented for the dynamical evolution of strong adiabatic relativistic blast waves which result from a point explosion in an ambient gas in which the density varies both with distance from the explosion center and with polar angle in axisymmetry. Solutions are analytical or quasi-analytical for the extreme relativistic case and numerical for the arbitrarily relativistic case. Some general properties of nonplanar relativistic shocks are also discussed, including the incoherence of spherical ultrarelativistic blast-wave fronts on angular scales greater than the reciprocal of the shock Lorentz factor, as well as the conditions for producing blast-wave acceleration.

  3. Optimized sympathetic cooling of atomic mixtures via fast adiabatic strategies

    SciTech Connect

    Choi, Stephen; Sundaram, Bala; Onofrio, Roberto

    2011-11-15

    We discuss fast frictionless cooling techniques in the framework of sympathetic cooling of cold atomic mixtures. It is argued that optimal cooling of an atomic species--in which the deepest quantum degeneracy regime is achieved--may be obtained by means of sympathetic cooling with another species whose trapping frequency is dynamically changed to maintain constancy of the Lewis-Riesenfeld adiabatic invariant. Advantages and limitations of this cooling strategy are discussed, with particular regard to the possibility of cooling Fermi gases to a deeper degenerate regime.

  4. Mysterious dipole synchrotron oscillations during and after adiabatic capture

    SciTech Connect

    Ng, K.Y.; /Fermilab

    2012-03-01

    Strong synchrotron oscillations were observed during and after the 2.5-MHz rf adiabatic capture of a debunched booster batch in the Main Injector. Analysis shows two possible sources for the synchrotron oscillations. One is the frequency drift of the 2.5-MHz rf after the turning off of the 53-MHz rf voltage, thus resulting in an energy mismatch with the debunched beam. The second source is the energy mismatch of the injected booster beam with the frequency of the 53-MHz rf. We have been able to rule out the first possibility.

  5. Adiabatic regularization of power spectra in nonminimally coupled chaotic inflation

    NASA Astrophysics Data System (ADS)

    Alinea, Allan L.

    2016-10-01

    We investigate the effect of adiabatic regularization on both the tensor- and scalar-perturbation power spectra in nonminimally coupled chaotic inflation. Similar to that of the minimally coupled general single-field inflation, we find that the subtraction term is suppressed by an exponentially decaying factor involving the number of e -folds. By following the subtraction term long enough beyond horizon crossing, the regularized power spectrum tends to the ``bare'' power spectrum. This study justifies the use of the unregularized (``bare'') power spectrum in standard calculations.

  6. Adiabatic invariants in stellar dynamics. 2: Gravitational shocking

    NASA Technical Reports Server (NTRS)

    Weinberg, Martin D.

    1994-01-01

    A new theory of gravitational shocking based on time-dependent perturbation theory shows that the changes in energy and angular momentum due to a slowly varying disturbance are not exponentially small for stellar dynamical systems in general. It predicts significant shock heating by slowly varying perturbations previously thought to be negligible according to the adiabatic criterion. The theory extends the scenarios traditionally computed only with the impulse approximation and is applicable to a wide class of disturbances. The approach is applied specifically to the problem of disk shocking of star clusters.

  7. Fast CNOT gate via shortcuts to adiabatic passage

    NASA Astrophysics Data System (ADS)

    Wang, Zhe; Xia, Yan; Chen, Ye-Hong; Song, Jie

    2016-10-01

    Based on the shortcuts to adiabatic passage, we propose a scheme for directly implementing a controlled-not (CNOT) gate in a cavity quantum electrodynamics system. Moreover, we generalize the scheme to realize a CNOT gate in two separate cavities connected by an optical fiber. The strictly numerical simulation shows that the schemes are fast and insensitive to the decoherence caused by atomic spontaneous emission and photon leakage. In addition, the schemes can provide a theoretical basis for the manipulation of the multiqubit quantum gates in distant nodes of a quantum network.

  8. Major Steps in the Discovery of Adiabatic Shear Bands

    NASA Astrophysics Data System (ADS)

    Dodd, Bradley; Walley, Stephen M.; Yang, Rong; Nesterenko, Vitali F.

    2015-10-01

    The standard story of the discovery of adiabatic shear bands is that it began with the American researchers Zener and Hollomon's famous 1944 paper where the phenomenon was first reported and named. However, a recent discovery by one of us (SMW) in the Cambridge University Library has shown that the phenomenon was discovered and described by a Russian researcher, V.P. Kravz-Tarnavskii, in 1928. A follow-up paper was published by two of his colleagues in 1935. Translations of the 1928 and 1935 papers may be found at http://arxiv.org/abs/1410.1353.

  9. Non-adiabatic pumping in an oscillating-piston model

    NASA Astrophysics Data System (ADS)

    Chuchem, Maya; Dittrich, Thomas; Cohen, Doron

    2012-05-01

    We consider the prototypical "piston pump" operating on a ring, where a circulating current is induced by means of an AC driving. This can be regarded as a generalized Fermi-Ulam model, incorporating a finite-height moving wall (piston) and non-trivial topology (ring). The amount of particles transported per cycle is determined by a layered structure of phase space. Each layer is characterized by a different drift velocity. We discuss the differences compared with the adiabatic and Boltzmann pictures, and highlight the significance of the "diabatic" contribution that might lead to a counter-stirring effect.

  10. Stimulated Raman adiabatic passage in Tm{sup 3+}:YAG

    SciTech Connect

    Alexander, A. L.; Lauro, R.; Louchet, A.; Chaneliere, T.; Le Goueet, J. L.

    2008-10-01

    We report on the experimental demonstration of stimulated Raman adiabatic passage in a Tm{sup 3+}:YAG crystal. Tm{sup 3+}:YAG is a promising material for use in quantum information processing applications, but as yet there are few experimental investigations of coherent Raman processes in this material. We investigate the effect of inhomogeneous broadening and Rabi frequency on the transfer efficiency and the width of the two-photon spectrum. Simulations of the complete Tm{sup 3+}:YAG system are presented along with the corresponding experimental results.

  11. Saturating the holographic entropy bound

    SciTech Connect

    Bousso, Raphael; Freivogel, Ben; Leichenauer, Stefan

    2010-10-15

    The covariant entropy bound states that the entropy, S, of matter on a light sheet cannot exceed a quarter of its initial area, A, in Planck units. The gravitational entropy of black holes saturates this inequality. The entropy of matter systems, however, falls short of saturating the bound in known examples. This puzzling gap has led to speculation that a much stronger bound, S < or approx. A{sup 3/4}, may hold true. In this note, we exhibit light sheets whose entropy exceeds A{sup 3/4} by arbitrarily large factors. In open Friedmann-Robertson-Walker universes, such light sheets contain the entropy visible in the sky; in the limit of early curvature domination, the covariant bound can be saturated but not violated. As a corollary, we find that the maximum observable matter and radiation entropy in universes with positive (negative) cosmological constant is of order {Lambda}{sup -1} ({Lambda}{sup -2}), and not |{Lambda}|{sup -3/4} as had hitherto been believed. Our results strengthen the evidence for the covariant entropy bound, while showing that the stronger bound S < or approx. A{sup 3/4} is not universally valid. We conjecture that the stronger bound does hold for static, weakly gravitating systems.

  12. Shortcut to Adiabatic Passage in Two- and Three-Level Atoms

    SciTech Connect

    Chen Xi; Lizuain, I.; Muga, J. G.; Ruschhaupt, A.; Guery-Odelin, D.

    2010-09-17

    We propose a method to speed up adiabatic passage techniques in two-level and three-level atoms extending to the short-time domain their robustness with respect to parameter variations. It supplements or substitutes the standard laser beam setups with auxiliary pulses that steer the system along the adiabatic path. Compared to other strategies, such as composite pulses or the original adiabatic techniques, it provides a fast and robust approach to population control.

  13. Tunneling conductance through the half-metal/conical magnet/superconductor junctions in the adiabatic and non-adiabatic regimes: Self-consistent calculations

    NASA Astrophysics Data System (ADS)

    Wójcik, P.; Zegrodnik, M.; Rzeszotarski, B.; Adamowski, J.

    2016-09-01

    The tunneling conductance through the half-metal/conical magnet/superconductor (HM/CM/SC) junctions is investigated with the use of the Bogoliubov-de Gennes equations in the framework of Blonder-Tinkham-Klapwijk formalism. Due to the spin band separation in the HM, the conductance in the subgap region is mainly determined by the anomalous Andreev reflection, the probability of which strongly depends on the spin transmission in the CM layer. We show that the spins of electrons injected from the HM can be transmitted through the CM to the SC either adiabatically or non-adiabatically depending on the period of the spatial modulation of the exchange field. We find that the conductance in the subgap region oscillates as a function of the CM layer thickness wherein the oscillations transform from the irregular pattern in the non-adiabatic regime to the regular one in the adiabatic regime. For both adiabatic and non-adiabatic transport regimes the conductance is studied over a broad range of parameters determining the spiral magnetization in the CM. We find that in the non-adiabatic regime, the decrease of the exchange field amplitude in the CM leads to the emergence of the conductance peak for the particular CM thickness in agreement with recent experiments.

  14. Saturation diving; physiology and pathophysiology.

    PubMed

    Brubakk, Alf O; Ross, John A S; Thom, Stephen R

    2014-07-01

    In saturation diving, divers stay under pressure until most of their tissues are saturated with breathing gas. Divers spend a long time in isolation exposed to increased partial pressure of oxygen, potentially toxic gases, bacteria, and bubble formation during decompression combined with shift work and long periods of relative inactivity. Hyperoxia may lead to the production of reactive oxygen species (ROS) that interact with cell structures, causing damage to proteins, lipids, and nucleic acid. Vascular gas-bubble formation and hyperoxia may lead to dysfunction of the endothelium. The antioxidant status of the diver is an important mechanism in the protection against injury and is influenced both by diet and genetic factors. The factors mentioned above may lead to production of heat shock proteins (HSP) that also may have a negative effect on endothelial function. On the other hand, there is a great deal of evidence that HSPs may also have a "conditioning" effect, thus protecting against injury. As people age, their ability to produce antioxidants decreases. We do not currently know the capacity for antioxidant defense, but it is reasonable to assume that it has a limit. Many studies have linked ROS to disease states such as cancer, insulin resistance, diabetes mellitus, cardiovascular diseases, and atherosclerosis as well as to old age. However, ROS are also involved in a number of protective mechanisms, for instance immune defense, antibacterial action, vascular tone, and signal transduction. Low-grade oxidative stress can increase antioxidant production. While under pressure, divers change depth frequently. After such changes and at the end of the dive, divers must follow procedures to decompress safely. Decompression sickness (DCS) used to be one of the major causes of injury in saturation diving. Improved decompression procedures have significantly reduced the number of reported incidents; however, data indicate considerable underreporting of injuries

  15. Saturation diving; physiology and pathophysiology.

    PubMed

    Brubakk, Alf O; Ross, John A S; Thom, Stephen R

    2014-07-01

    In saturation diving, divers stay under pressure until most of their tissues are saturated with breathing gas. Divers spend a long time in isolation exposed to increased partial pressure of oxygen, potentially toxic gases, bacteria, and bubble formation during decompression combined with shift work and long periods of relative inactivity. Hyperoxia may lead to the production of reactive oxygen species (ROS) that interact with cell structures, causing damage to proteins, lipids, and nucleic acid. Vascular gas-bubble formation and hyperoxia may lead to dysfunction of the endothelium. The antioxidant status of the diver is an important mechanism in the protection against injury and is influenced both by diet and genetic factors. The factors mentioned above may lead to production of heat shock proteins (HSP) that also may have a negative effect on endothelial function. On the other hand, there is a great deal of evidence that HSPs may also have a "conditioning" effect, thus protecting against injury. As people age, their ability to produce antioxidants decreases. We do not currently know the capacity for antioxidant defense, but it is reasonable to assume that it has a limit. Many studies have linked ROS to disease states such as cancer, insulin resistance, diabetes mellitus, cardiovascular diseases, and atherosclerosis as well as to old age. However, ROS are also involved in a number of protective mechanisms, for instance immune defense, antibacterial action, vascular tone, and signal transduction. Low-grade oxidative stress can increase antioxidant production. While under pressure, divers change depth frequently. After such changes and at the end of the dive, divers must follow procedures to decompress safely. Decompression sickness (DCS) used to be one of the major causes of injury in saturation diving. Improved decompression procedures have significantly reduced the number of reported incidents; however, data indicate considerable underreporting of injuries

  16. Development of an adiabatic calorimeter in the range 54K-273K in frame of a scientific collaboration LNE-NIS

    NASA Astrophysics Data System (ADS)

    Ahmed, M. G.; Hermier, Y.

    2013-09-01

    The National Institute for Standards (NIS), in cooperation with the French National Metrology Institute (LNE-CNAM), has recently developed a new adiabatic calorimeter, to realize the International Temperature Scale of 1990 (ITS-90) in the temperature range between 54 K and 273 K using Capsule Standard Platinum Resistance Thermometers (CSPRTs). The work has been realized through an international scientific-cooperation project "IMHOTEP" between the two sides. The new calorimeter comprises a cylindrical double-wall vacuum-tight stainless steel Dewar that withstands evacuation on the liquid nitrogen to reach a temperature close to the oxygen triple point. The thermal shield accommodates a multi-compartment cell containing the oxygen and argon triple-points cells. The temperature control for best adiabatic conditions is achieved through PID software, running under LABVIEW environment. Two calorimeters have been constructed. The first one was installed at LNE-CNAM and tested for optimum adiabatic conditions. The system was then transferred to NIS. The second calorimeter was tested and stayed at LNE-CNAM. Experiments, at NIS, showed the possibility of reaching a temperature close to the oxygen triple point. Uncertainties for CSPRTs calibrations were 0.27 and 0.25 mK for triple points of oxygen and argon respectively.

  17. Experimental study of the validity of quantitative conditions in the quantum adiabatic theorem.

    PubMed

    Du, Jiangfeng; Hu, Lingzhi; Wang, Ya; Wu, Jianda; Zhao, Meisheng; Suter, Dieter

    2008-08-01

    The quantum adiabatic theorem plays an important role in quantum mechanics. However, counter-examples were produced recently, indicating that their transition probabilities do not converge as predicted by the adiabatic theorem [K. P. Marzlin et al., Phys. Rev. Lett. 93, 160408 (2004); D. M. Tong et al., Phys. Rev. Lett. 95, 110407 (2005)]. For a special class of Hamiltonians, we examine the standard criterion for adiabatic evolution experimentally and theoretically, as well as three newly suggested adiabatic conditions. We show that the standard criterion is neither sufficient nor necessary.

  18. Singularity of the time-energy uncertainty in adiabatic perturbation and cycloids on a Bloch sphere

    PubMed Central

    Oh, Sangchul; Hu, Xuedong; Nori, Franco; Kais, Sabre

    2016-01-01

    Adiabatic perturbation is shown to be singular from the exact solution of a spin-1/2 particle in a uniformly rotating magnetic field. Due to a non-adiabatic effect, its quantum trajectory on a Bloch sphere is a cycloid traced by a circle rolling along an adiabatic path. As the magnetic field rotates more and more slowly, the time-energy uncertainty, proportional to the length of the quantum trajectory, calculated by the exact solution is entirely different from the one obtained by the adiabatic path traced by the instantaneous eigenstate. However, the non-adiabatic Aharonov- Anandan geometric phase, measured by the area enclosed by the exact path, approaches smoothly the adiabatic Berry phase, proportional to the area enclosed by the adiabatic path. The singular limit of the time-energy uncertainty and the regular limit of the geometric phase are associated with the arc length and arc area of the cycloid on a Bloch sphere, respectively. Prolate and curtate cycloids are also traced by different initial states outside and inside of the rolling circle, respectively. The axis trajectory of the rolling circle, parallel to the adiabatic path, is shown to be an example of transitionless driving. The non-adiabatic resonance is visualized by the number of cycloid arcs. PMID:26916031

  19. Singularity of the time-energy uncertainty in adiabatic perturbation and cycloids on a Bloch sphere.

    PubMed

    Oh, Sangchul; Hu, Xuedong; Nori, Franco; Kais, Sabre

    2016-01-01

    Adiabatic perturbation is shown to be singular from the exact solution of a spin-1/2 particle in a uniformly rotating magnetic field. Due to a non-adiabatic effect, its quantum trajectory on a Bloch sphere is a cycloid traced by a circle rolling along an adiabatic path. As the magnetic field rotates more and more slowly, the time-energy uncertainty, proportional to the length of the quantum trajectory, calculated by the exact solution is entirely different from the one obtained by the adiabatic path traced by the instantaneous eigenstate. However, the non-adiabatic Aharonov-Anandan geometric phase, measured by the area enclosed by the exact path, approaches smoothly the adiabatic Berry phase, proportional to the area enclosed by the adiabatic path. The singular limit of the time-energy uncertainty and the regular limit of the geometric phase are associated with the arc length and arc area of the cycloid on a Bloch sphere, respectively. Prolate and curtate cycloids are also traced by different initial states outside and inside of the rolling circle, respectively. The axis trajectory of the rolling circle, parallel to the adiabatic path, is shown to be an example of transitionless driving. The non-adiabatic resonance is visualized by the number of cycloid arcs. PMID:26916031

  20. An Adiabatic Calorimeter for the Realization of the ITS-90 in the Cryogenic Range at the LNE-CNAM

    NASA Astrophysics Data System (ADS)

    Sparasci, F.; Pitre, L.; Rouillé, G.; Thermeau, J.-P.; Truong, D.; Galet, F.; Hermier, Y.

    2011-01-01

    The LNE-CNAM, in cooperation with the IPN, has recently developed a new cryogen-free adiabatic calorimeter, to realize the International Temperature Scale of 1990 (ITS-90) in the temperature range between 6 K and 84 K. The new calorimeter, cooled by a closed-cycle Gifford-McMahon refrigerator, is equipped with three thermal shields and two separate vacuum chambers, to minimize the effect of parasitic heat fluxes. The inner adiabatic chamber can accommodate either a multi-compartment cell—containing the triple points of hydrogen, neon, oxygen, and argon, to realize the ITS-90 between 14 K and 84 K—or a comparison block for thermometers, the calibration of rhodium-iron (RhFe) thermometers between 6 K and 24 K. The use of a cryogen-free system and a fully computer-controlled measurement chain allow long lasting experiments and good thermal control, resulting in a substantial reduction of the measurement uncertainties. The new adiabatic calorimeter has been successfully tested at the LNE-CNAM. The overall standard uncertainties in the realization of the ITS-90 have been reduced from 2.08 mK to 0.37 mK at the hydrogen triple point, from 1.40 mK to 0.30 mK at the triple point of neon, and are maintained below 0.26 mK at the triple points of oxygen and argon. In the temperature range between 6 K and 24 K, calibrations of rhodium-iron resistance thermometers have been carried out with a standard uncertainty of the order of 0.80 mK.

  1. Calculation of the thermodynamic properties at elevated temperatures and pressures of saturated and aromatic high molecular weight solid and liquid hydrocarbons in kerogen, bitumen, petroleum, and other organic matter of biogeochemical interest

    NASA Astrophysics Data System (ADS)

    Richard, Laurent; Helgeson, Harold C.

    1998-12-01

    To supplement the relatively sparse set of calorimetric data available for the multitude of high molecular weight organic compounds of biogeochemical interest, group additivity algorithms have been developed to estimate heat capacity power function coefficients and the standard molal thermodynamic properties at 25°C and 1 bar of high molecular weight compounds in hydrocarbon source rocks and reservoirs, including crystalline and liquid isoprenoids, steroids, tricyclic diterpenoids, hopanoids, and polynuclear aromatic hydrocarbons. A total of ninety-six group contributions for each coefficient and property were generated from the thermodynamic properties of lower molecular weight reference species for which calorimetric data are available in the literature. These group contributions were then used to compute corresponding coefficients and properties for ˜360 representative solid and liquid high molecular weight compounds in kerogen, bitumen, and petroleum for which few or no experimental data are available. The coefficients and properties of these high molecular weight compounds are summarized in tables, together with those of the groups and reference species from which they were generated. The tabulated heat capacity power function coefficients and standard molal thermodynamic properties at 25°C and 1 bar include selected crystalline and liquid regular, irregular and highly branched isoprenoids, tricyclic diterpanes, 17α(H)- and 17β(H)-hopanes, 5α(H),14α(H)-, 5β(H),14α(H)-, 5α(H),14β(H)-, and 5β(H),14β(H)-steranes, double ether- and ester-bonded n-alkanes, and various polynuclear aromatic hydrocarbons, including methylated biphenyls, naphthalenes, phenanthrenes, anthracenes, pyrenes, and chrysenes. However, corresponding coefficients and properties for many more saturated and unsaturated high molecular weight hydrocarbons can be estimated from the equations of state group additivity algorithms. Calculations of this kind permit comprehensive

  2. Calculation of the thermodynamic properties at elevated temperatures and pressures of saturated and aromatic high molecular weight solid and liquid hydrocarbons in kerogen, bitumen, petroleum, and other organic matter of biogeochemical interest

    SciTech Connect

    Richard, L.; Helgeson, H.C.

    1998-12-01

    To supplement the relatively sparse set of calorimetric data available for the multitude of high molecular weight organic compounds of biogeochemical interest, group additivity algorithms have been developed to estimate heat capacity power function coefficients and the standard molal thermodynamic properties at 25 C and 1 bar of high molecular weight compounds in hydrocarbon source rocks and reservoirs, including crystalline and liquid isoprenoids, steroids, tricyclic diterpenoids, hopanoids, and polynuclear aromatic hydrocarbons. A total of ninety-six group contributions for each coefficient and property were generated from the thermodynamic properties of lower molecular weight reference species for which calorimetric data are available in the literature. These group contributions were then used to compute corresponding coefficients and properties for {approximately}360 representative solid and liquid high molecular weight compounds in kerogen, bitumen, and petroleum for which few or no experimental data are available. The coefficients and properties of these high molecular weight compounds are summarized in tables, together with those of the groups and reference species from which they were generated. The tabulated heat capacity power function coefficients and standard molal thermodynamic properties at 25 C and 1 bar include selected crystalline and liquid regular, irregular and highly branched isoprenoids, tricyclic diterpanes, 17{alpha}(H)- and 17{beta}(H)-hopanes, 5{alpha}(H),14{alpha}(H)-, 5{beta}(H),14{alpha}(H)-, 5{alpha}(H),14{beta}(H)-, and 5{beta}(H),14{beta}(H)-steranes, double ether- and ester-bonded n-alkanes, and various polynuclear aromatic hydrocarbons, including methylated biphenyls, naphthalenes, phenanthrenes, anthracenes, pyrenes, and chrysenes. However, corresponding coefficients and properties for many more saturated and unsaturated high molecular weight hydrocarbons can be estimated from the equations of state group additivity algorithms

  3. Adiabatic Quasi-Spherical Compressions Driven by Magnetic Pressure for Inertial Confinement Fusion

    SciTech Connect

    NASH,THOMAS J.

    2000-11-01

    The magnetic implosion of a high-Z quasi-spherical shell filled with DT fuel by the 20-MA Z accelerator can heat the fuel to near-ignition temperature. The attainable implosion velocity on Z, 13-cm/{micro}s, is fast enough that thermal losses from the fuel to the shell are small. The high-Z shell traps radiation losses from the fuel, and the fuel reaches a high enough density to reabsorb the trapped radiation. The implosion is then nearly adiabatic. In this case the temperature of the fuel increases as the square of the convergence. The initial temperature of the fuel is set by the heating of an ion acoustic wave to be about 200-eV after a convergence of 4. To reach the ignition temperature of 5-keV an additional convergence of 5 is required. The implosion dynamics of the quasi-spherical implosion is modeled with the 2-D radiation hydrodynamic code LASNEX. LASNEX shows an 8-mm diameter quasi-spherical tungsten shell on Z driving 6-atmospheres of DT fuel nearly to ignition at 3.5-keV with a convergence of 20. The convergence is limited by mass flow along the surface of the quasi-spherical shell. With a convergence of 20 the final spot size is 400-{micro}m in diameter.

  4. Enhanced diffusion weighting generated by selective adiabatic pulse trains

    NASA Astrophysics Data System (ADS)

    Sun, Ziqi; Bartha, Robert

    2007-09-01

    A theoretical description and experimental validation of the enhanced diffusion weighting generated by selective adiabatic full passage (AFP) pulse trains is provided. Six phantoms (Ph-1-Ph-6) were studied on a 4 T Varian/Siemens whole body MRI system. Phantoms consisted of 2.8 cm diameter plastic tubes containing a mixture of 10 μm ORGASOL polymer beads and 2 mM Gd-DTPA dissolved in 5% agar (Ph-1) or nickel(II) ammonium sulphate hexahydrate doped (56.3-0.8 mM) water solutions (Ph-2-Ph-6). A customized localization by adiabatic selective refocusing (LASER) sequence containing slice selective AFP pulse trains and pulsed diffusion gradients applied in the phase encoding direction was used to measure 1H 2O diffusion. The b-value associated with the LASER sequence was derived using the Bloch-Torrey equation. The apparent diffusion coefficients measured by LASER were comparable to those measured by a conventional pulsed gradient spin-echo (PGSE) sequence for all phantoms. Image signal intensity increased in Ph-1 and decreased in Ph-2-Ph-6 as AFP pulse train length increased while maintaining a constant echo-time. These experimental results suggest that such AFP pulse trains can enhance contrast between regions containing microscopic magnetic susceptibility variations and homogeneous regions in which dynamic dephasing relaxation mechanisms are dominant.

  5. Robust quantum logic in neutral atoms via adiabatic Rydberg dressing

    DOE PAGES

    Keating, Tyler; Cook, Robert L.; Hankin, Aaron M.; Jau, Yuan -Yu; Biedermann, Grant W.; Deutsch, Ivan H.

    2015-01-28

    We study a scheme for implementing a controlled-Z (CZ) gate between two neutral-atom qubits based on the Rydberg blockade mechanism in a manner that is robust to errors caused by atomic motion. By employing adiabatic dressing of the ground electronic state, we can protect the gate from decoherence due to random phase errors that typically arise because of atomic thermal motion. In addition, the adiabatic protocol allows for a Doppler-free configuration that involves counterpropagating lasers in a σ+/σ- orthogonal polarization geometry that further reduces motional errors due to Doppler shifts. The residual motional error is dominated by dipole-dipole forces actingmore » on doubly-excited Rydberg atoms when the blockade is imperfect. As a result, for reasonable parameters, with qubits encoded into the clock states of 133Cs, we predict that our protocol could produce a CZ gate in < 10 μs with error probability on the order of 10-3.« less

  6. AB INITIO SIMULATIONS FOR MATERIAL PROPERTIES ALONG THE JUPITER ADIABAT

    SciTech Connect

    French, Martin; Becker, Andreas; Lorenzen, Winfried; Nettelmann, Nadine; Bethkenhagen, Mandy; Redmer, Ronald; Wicht, Johannes

    2012-09-15

    We determine basic thermodynamic and transport properties of hydrogen-helium-water mixtures for the extreme conditions along Jupiter's adiabat via ab initio simulations, which are compiled in an accurate and consistent data set. In particular, we calculate the electrical and thermal conductivity, the shear and longitudinal viscosity, and diffusion coefficients of the nuclei. We present results for associated quantities like the magnetic and thermal diffusivity and the kinematic shear viscosity along an adiabat that is taken from a state-of-the-art interior structure model. Furthermore, the heat capacities, the thermal expansion coefficient, the isothermal compressibility, the Grueneisen parameter, and the speed of sound are calculated. We find that the onset of dissociation and ionization of hydrogen at about 0.9 Jupiter radii marks a region where the material properties change drastically. In the deep interior, where the electrons are degenerate, many of the material properties remain relatively constant. Our ab initio data will serve as a robust foundation for applications that require accurate knowledge of the material properties in Jupiter's interior, e.g., models for the dynamo generation.

  7. Turbulent Density Variations in Non-Adiabatic Interstellar Fluids

    NASA Astrophysics Data System (ADS)

    Higdon, J. C.; Conley, Alex

    1998-05-01

    Analyses of radio scintillation measurements have demonstrated (e.g., Rickett, ARAA, 28, 561, 1990) the existence of ubiquitous turbulent density fluctuations in the interstellar medium. Higdon (ApJ, 309, 342, 1986) and Goldreich and Sridhar (ApJ, 438, 763 1995) have modeled successfully these density variations as entropy structures distorted by convection in anisotropic magnetohydrodynamic turbulent flows. However, the interstellar medium is a heterogeneous non-adiabatic fluid whose thermal properties result ( Field, ApJ, 142, 531 1965) from a balance of heating and cooling rates. The effect of the non-adiabatic nature of interstellar fluids on the properties of turbulent cascades to small scales has not been considered previously. We find that in thermally stable fluids that the required balance of heating and cooling decreases the amplitudes of entropy structures independently of their spatial scale. Consequently, we show that if the time scale for turbulent flows to cascade to small scales is significantly greater than the cooling time of an interstellar fluid, the generation of turbulent denisty density variations at large wave numbers is greatly suppressed. Such results constrain possible values for the turbulent outer scale in models of interstellar turbulent flows.

  8. Robust quantum logic in neutral atoms via adiabatic Rydberg dressing

    SciTech Connect

    Keating, Tyler; Cook, Robert L.; Hankin, Aaron M.; Jau, Yuan -Yu; Biedermann, Grant W.; Deutsch, Ivan H.

    2015-01-28

    We study a scheme for implementing a controlled-Z (CZ) gate between two neutral-atom qubits based on the Rydberg blockade mechanism in a manner that is robust to errors caused by atomic motion. By employing adiabatic dressing of the ground electronic state, we can protect the gate from decoherence due to random phase errors that typically arise because of atomic thermal motion. In addition, the adiabatic protocol allows for a Doppler-free configuration that involves counterpropagating lasers in a σ+- orthogonal polarization geometry that further reduces motional errors due to Doppler shifts. The residual motional error is dominated by dipole-dipole forces acting on doubly-excited Rydberg atoms when the blockade is imperfect. As a result, for reasonable parameters, with qubits encoded into the clock states of 133Cs, we predict that our protocol could produce a CZ gate in < 10 μs with error probability on the order of 10-3.

  9. FRW-type cosmologies with adiabatic matter creation

    NASA Astrophysics Data System (ADS)

    Lima, J. A. S.; Germano, A. S. M.; Abramo, L. R. W.

    1996-04-01

    Some properties of cosmological models with matter creation are investigated in the framework of the Friedmann-Robertson-Walker line element. For adiabatic matter creation, as developed by Prigogine and co-workers, we derive a simple expression relating the particle number density n and energy density ρ which holds regardless of the matter creation rate. The conditions to generate inflation are discussed and by considering the natural phenomenological matter creation rate ψ=3βnH, where β is a pure number of the order of unity and H is the Hubble parameter, a minimally modified hot big-bang model is proposed. The dynamic properties of such models can be deduced from the standard ones simply by replacing the adiabatic index γ of the equation of state by an effective parameter γ*=γ(1-β). The thermodynamic behavior is determined and it is also shown that ages large enough to agree with observations are obtained even given the high values of H suggested by recent measurements.

  10. High Energy Signatures of POST Adiabatic Supernova Remnants

    NASA Astrophysics Data System (ADS)

    Telezhinsky, Igor; Hnatyk, Bohdan

    Between the well-known adiabatic and radiative stages of the Supernova remnant (SNR) evolution there is, in fact, a transition stage with a duration comparable to the duration of adiabatic one. Physical existence of the transition stage is motivated by cooling of some part of the downstream hot gas with formation of a thin cold shell that is joined to a shell of swept up interstellar medium (ISM). We give an approximate analytical method for full hydrodynamical description of the transition stage. On its base we investigate the evolution of X-ray and γ-ray radiation during this stage. It is shown that formation of a dense shell during the transition stage is accompanied by the decrease of X-ray luminosity because of hot gas cooling and increase of gamma-ray flux according to the increase of target proton density and CR energy in the newly born shell. The role of nonuniformity of ISM and its influence on the high energy fluxes from the SNRs is also discussed.

  11. Breakdown of adiabatic electron behavior in expanding magnetic fields

    NASA Astrophysics Data System (ADS)

    Lichko, Emily; Egedal, Jan; Daughton, William

    2015-11-01

    During magnetic reconnection the incoming magnetic flux tubes expand in the inflow region. If this expansion is sufficiently slow the results are well described by a previously developed adiabatic model. Using kinetic simulations in a simple geometry and applying rapid magnetic perturbations, this study investigates the point at which the adiabatic assumption fails. To this end a 2D VPIC simulation was constructed, where the magnetic field in a uniform plasma is perturbed by externally driven currents. By varying the onset speed of the magnetic perturbation and the electron thermal speed, we found a sharp threshold at which this model breaks down. We believe that this point is determined by the time of the magnetic pumping compared to the electron transit time through the region, i.e. ω ~ Ḃ / B ~vthe / L . This threshold was also characterized by the launching of Whistler waves and with time domain structures, such as electron holes and double layers, which agree with those seen during magnetic reconnection and may relate to similar structures in the Van Allen Belts. NSF GEM award 1405166 and NASA grant NNX14AC68G.

  12. Schedule path optimization for adiabatic quantum computing and optimization

    NASA Astrophysics Data System (ADS)

    Zeng, Lishan; Zhang, Jun; Sarovar, Mohan

    2016-04-01

    Adiabatic quantum computing and optimization have garnered much attention recently as possible models for achieving a quantum advantage over classical approaches to optimization and other special purpose computations. Both techniques are probabilistic in nature and the minimum gap between the ground state and first excited state of the system during evolution is a major factor in determining the success probability. In this work we investigate a strategy for increasing the minimum gap and success probability by introducing intermediate Hamiltonians that modify the evolution path between initial and final Hamiltonians. We focus on an optimization problem relevant to recent hardware implementations and present numerical evidence for the existence of a purely local intermediate Hamiltonian that achieve the optimum performance in terms of pushing the minimum gap to one of the end points of the evolution. As a part of this study we develop a convex optimization formulation of the search for optimal adiabatic schedules that makes this computation more tractable, and which may be of independent interest. We further study the effectiveness of random intermediate Hamiltonians on the minimum gap and success probability, and empirically find that random Hamiltonians have a significant probability of increasing the success probability, but only by a modest amount.

  13. Numerical Investigation of the effect of adiabatic section location on thermal performance of a heat pipe network with the application in thermal energy storage systems

    NASA Astrophysics Data System (ADS)

    Mahdavi, Mahboobe; Tiari, Saeed; Qiu, Songgang

    2015-11-01

    Latent heat thermal energy storage systems benefits from high energy density and isothermal storing process. However, the low thermal conductivity of the phase change material leads to prolong the melting or solidification time. Using a passive device such as heat pipes is required to enhance the heat transfer and to improve the efficiency of the system. In the present work, the performance of a heat pipe network specifically designed for a thermal energy storage system is studied numerically. The network includes a primary heat pipe, which transfers heat received from solar receiver to the heat engine. The excess heat is simultaneously delivered to charge the phase change material via secondary heat pipes. The primary heat pipe composed of a disk shape evaporator, an adiabatic section and a disk shape condenser. The adiabatic section can be either located at the center or positioned outward to the surrounding of the container. Here, the effect of adiabatic section position on thermal performance of the system is investigated. It was concluded that displacing the adiabatic section outwards dramatically increases the average temperatures of the condensers and reduces the thermal resistance of heat pipes.

  14. Core saturation in a moving medium

    NASA Technical Reports Server (NTRS)

    Kalkofen, W.; Ulmschneider, P.

    1984-01-01

    A numerical technique for solving the line transfer equation of a two-level atom in static equilibrium is presented. Complete redistribution of emitted photons is assumed, as is saturation at the line core. Emission intensity is calculated either by a generalized Eddington-Barber relation, a first-order differential equation for the specific intensity, or by a formal transfer integral. Sample calculations are performed of the line transfer equation in a semi-infinite atmosphere with a constant Planck function of the collision parameter and for the Mg II resonance line in a model solar atmosphere experiencing shocks. Attention is focused on the line wings in the latter problem. The first order differential equation approach yields the best intensity values and temperature structure.

  15. Saturation of repeated quantum measurements

    NASA Astrophysics Data System (ADS)

    Haapasalo, Erkka; Heinosaari, Teiko; Kuramochi, Yui

    2016-08-01

    We study sequential measurement scenarios where the system is repeatedly subjected to the same measurement process. We first provide examples of such repeated measurements where further repetitions of the measurement do not increase our knowledge on the system after some finite number of measurement steps. We also prove, however, that repeating the Lüders measurement of an unsharp two-outcome observable never saturates in this sense, and we characterize the observable measured in the limit of infinitely many repetitions. Our result implies that a repeated measurement can be used to correct the inherent noise of an unsharp observable.

  16. Gain saturation in semiconductor lasers - Theory and experiment

    NASA Technical Reports Server (NTRS)

    Kasemset, D.; Fonstad, C. G., Jr.

    1982-01-01

    The semiconductor stimulated gain saturation model of Zee has been extended using reasonable approximations to obtain an analytical solution for the gain saturation process in PbSnTe and to determine the limit to single mode power directly from the gain expression, the intraband relaxation time, and device and material parameters. The theoretical results are compared with experimental observations for single transverse mode cavity narrow stripe buried heterostructure PbSnTe lasers. Those results are interpreted in terms of an intraband relaxation time on the order of 2 x 10 to the -12th s in the temperature range 20-80 K.

  17. Normal jugular bulb oxygen saturation

    PubMed Central

    Chieregato, A; Calzolari, F; Trasforini, G; Targa, L; Latronico, N

    2003-01-01

    Background: Normal values of the jugular bulb oxygen saturation were obtained in 1942 and in 1963. Correct catheter positioning was not confirmed radiologically. Objectives: To replicate the measurements during angiographic catheterisation of the jugular bulb. Methods: Oxygen saturation in the jugular bulb (SjO2), inferior petrosal sinus (SipsO2), and internal jugular vein was bilaterally measured in 12 patients with Cushing's syndrome undergoing selective bilateral catheterisation of the inferior petrosal sinus. In addition, data from the two old series were reanalysed for comparison. Results: SjO2 values (44.7%) were significantly lower than in the two old series, particularly concerning the normal lower limit (54.6% and 55.0% respectively). Comparative analysis suggests that contamination with the extracerebral blood of the facial veins and inferior petrosal sinuses was responsible for falsely high SjO2 values in the two old series. Conclusions: The normal lower SjO2 limit is lower than previously recognised. This may have practical implications for treating severe head trauma patients. PMID:12754351

  18. Adiabatic calorimetry test of the reaction kinetics and self-heating model for 18650 Li-ion cells in various states of charge

    NASA Astrophysics Data System (ADS)

    Chen, Wei-Chun; Wang, Yih-Wen; Shu, Chi-Min

    2016-06-01

    Use of adiabatic calorimetry to characterise thermal runaway of Li-ion cells is a crucial technique in battery safety testing. Various states of charge (SoC) of Li-ion cells were investigated to ascertain their thermal runaway features using a Vent Sizing Package 2 (VSP2) adiabatic calorimeter. To evaluate the thermal runaway characteristics, the temperature-pressure-time trajectories of commercial cylindrical cells were tested, and it was found that cells at a SoC of greater than 50% were subject to thermal explosion at elevated temperatures. Calorimetry data from various 18650 Li-ion cells with different SoC were used to calculate the thermal explosion energies and chemical kinetics; furthermore, a novel self-heating model based on a pseudo-zero-order reaction that follows the Arrhenius equation was found to be applicable for studying the exothermic reaction of a charged cell.

  19. THE FIRST MEASUREMENT OF THE ADIABATIC INDEX IN THE SOLAR CORONA USING TIME-DEPENDENT SPECTROSCOPY OF HINODE/EIS OBSERVATIONS

    SciTech Connect

    Van Doorsselaere, Tom; Wardle, Nick; Jansari, Kishan; Verwichte, Erwin; Nakariakov, Valery M.; Del Zanna, Giulio

    2011-02-01

    We use observations of a slow magnetohydrodynamic wave in the corona to determine for the first time the value of the effective adiabatic index, using data from the Extreme-ultraviolet Imaging Spectrometer on board Hinode. We detect oscillations in the electron density, using the CHIANTI atomic database to perform spectroscopy. From the time-dependent wave signals from multiple spectral lines the relationship between relative density and temperature perturbations is determined, which allows in turn to measure the effective adiabatic index to be {gamma}{sub eff} = 1.10 {+-} 0.02. This confirms that the thermal conduction along the magnetic field is very efficient in the solar corona. The thermal conduction coefficient is measured from the phase lag between the temperature and density, and is shown to be compatible with Spitzer conductivity.

  20. Diffusion of a massive particle in a periodic potential: Application to adiabatic ratchets

    NASA Astrophysics Data System (ADS)

    Rozenbaum, Viktor M.; Makhnovskii, Yurii A.; Shapochkina, Irina V.; Sheu, Sheh-Yi; Yang, Dah-Yen; Lin, Sheng Hsien

    2015-12-01

    We generalize a theory of diffusion of a massive particle by the way in which transport characteristics are described by analytical expressions that formally coincide with those for the overdamped massless case but contain a factor comprising the particle mass which can be calculated in terms of Risken's matrix continued fraction method (MCFM). Using this generalization, we aim to elucidate how large gradients of a periodic potential affect the current in a tilted periodic potential and the average current of adiabatically driven on-off flashing ratchets. For this reason, we perform calculations for a sawtooth potential of the period L with an arbitrary sawtooth length (l temperature dependences of the quantities under study reveals the dominant role of inertia in the high-temperature region. In particular, we show, by the analytical strong-inertia approach developed for this region, that the temperature-dependent contribution to the mobility at zero force and to the related effective diffusion coefficient are proportional to T-3 /2 and T-1 /2, respectively, and have a logarithmic singularity at l →0 .

  1. Diffusion of a massive particle in a periodic potential: Application to adiabatic ratchets.

    PubMed

    Rozenbaum, Viktor M; Makhnovskii, Yurii A; Shapochkina, Irina V; Sheu, Sheh-Yi; Yang, Dah-Yen; Lin, Sheng Hsien

    2015-12-01

    We generalize a theory of diffusion of a massive particle by the way in which transport characteristics are described by analytical expressions that formally coincide with those for the overdamped massless case but contain a factor comprising the particle mass which can be calculated in terms of Risken's matrix continued fraction method (MCFM). Using this generalization, we aim to elucidate how large gradients of a periodic potential affect the current in a tilted periodic potential and the average current of adiabatically driven on-off flashing ratchets. For this reason, we perform calculations for a sawtooth potential of the period L with an arbitrary sawtooth length (ltemperature dependences of the quantities under study reveals the dominant role of inertia in the high-temperature region. In particular, we show, by the analytical strong-inertia approach developed for this region, that the temperature-dependent contribution to the mobility at zero force and to the related effective diffusion coefficient are proportional to T(-3/2) and T(-1/2), respectively, and have a logarithmic singularity at l→0. PMID:26764657

  2. Adiabatic and nonadiabatic perturbation theory for coherence vector description of neutrino oscillations

    NASA Astrophysics Data System (ADS)

    Hollenberg, Sebastian; Päs, Heinrich

    2012-01-01

    The standard wave function approach for the treatment of neutrino oscillations fails in situations where quantum ensembles at a finite temperature with or without an interacting background plasma are encountered. As a first step to treat such phenomena in a novel way, we propose a unified approach to both adiabatic and nonadiabatic two-flavor oscillations in neutrino ensembles with finite temperature and generic (e.g., matter) potentials. Neglecting effects of ensemble decoherence for now, we study the evolution of a neutrino ensemble governed by the associated quantum kinetic equations, which apply to systems with finite temperature. The quantum kinetic equations are solved formally using the Magnus expansion and it is shown that a convenient choice of the quantum mechanical picture (e.g., the interaction picture) reveals suitable parameters to characterize the physics of the underlying system (e.g., an effective oscillation length). It is understood that this method also provides a promising starting point for the treatment of the more general case in which decoherence is taken into account.

  3. Second law analysis of water flow through smooth microtubes under adiabatic conditions

    SciTech Connect

    Parlak, Nezaket; Guer, Mesut; Ari, Vedat; Kuecuek, Hasan; Engin, Tahsin

    2011-01-15

    In the study, a second law analysis for a steady-laminar flow of water in adiabatic microtubes has been conducted. Smooth microtubes with the diameters between 50 and 150 {mu}m made of fused silica were used in the experiments. Considerable temperature rises due to viscous dissipation and relatively high pressure losses of flow were observed in experiments. To identify irreversibility of flow, rate of entropy generation from the experiments have been determined in the laminar flow range of Re = 20-2200. The second law of thermodynamics was applied to predict the entropy generation. The results of model taken from the literature, proposed to predict the temperature rise caused by viscous heating, correspond well with the experimental data. The second law analysis results showed that the flow characteristics in the smooth microtubes distinguish substantially from the conventional theory for flow in the larger tubes with respect to viscous heating/dissipation (temperature rise of flow) total entropy generation rate and lost work. (author)

  4. On the adiabatic stability of solitons and the matching of conservation laws

    NASA Astrophysics Data System (ADS)

    Lochak, Pierre

    1984-08-01

    We derive a series of identities which generalize and simplify the results obtained for adiabatically modulated solitons in the case of perturbed specific integrable equations. It stresses the importance of the variational properties of the solitons, which make an adiabatic theorem plausible. A precise conjecture is made and its validity discussed from different points of view.

  5. Molybdenite saturation in silicic magmas: Occurrence and petrological implications

    USGS Publications Warehouse

    Audetat, A.; Dolejs, D.; Lowenstern, J. B.

    2011-01-01

    We identified molybdenite (MoS2) as an accessory magmatic phase in 13 out of 27 felsic magma systems examined worldwide. The molybdenite occurs as small (<20 ??m) triangular or hexagonal platelets included in quartz phenocrysts. Laser-ablation inductively coupled plasma mass spectrometry analyses of melt inclusions in molybdenite-saturated samples reveal 1-13 ppm Mo in the melt and geochemical signatures that imply a strong link to continental rift basalt-rhyolite associations. In contrast, arc-associated rhyolites are rarely molybdenite-saturated, despite similar Mo concentrations. This systematic dependence on tectonic setting seems to reflect the higher oxidation state of arc magmas compared with within-plate magmas. A thermodynamic model devised to investigate the effects of T, f O2 and f S2 on molybdenite solubility reliably predicts measured Mo concentrations in molybdenite-saturated samples if the magmas are assumed to have been saturated also in pyrrhotite. Whereas pyrrhotite microphenocrysts have been observed in some of these samples, they have not been observed from other molybdenite-bearing magmas. Based on the strong influence of f S2 on molybdenite solubility we calculate that also these latter magmas must have been at (or very close to) pyrrhotite saturation. In this case the Mo concentration of molybdenite-saturated melts can be used to constrain both magmatic f O2 and f S2 if temperature is known independently (e.g. by zircon saturation thermometry). Our model thus permits evaluation of magmatic f S2, which is an important variable but is difficult to estimate otherwise, particularly in slowly cooled rocks. ?? The Author 2011. Published by Oxford University Press. All rights reserved.

  6. Differential geometric treewidth estimation in adiabatic quantum computation

    NASA Astrophysics Data System (ADS)

    Wang, Chi; Jonckheere, Edmond; Brun, Todd

    2016-07-01

    The D-Wave adiabatic quantum computing platform is designed to solve a particular class of problems—the Quadratic Unconstrained Binary Optimization (QUBO) problems. Due to the particular "Chimera" physical architecture of the D-Wave chip, the logical problem graph at hand needs an extra process called minor embedding in order to be solvable on the D-Wave architecture. The latter problem is itself NP-hard. In this paper, we propose a novel polynomial-time approximation to the closely related treewidth based on the differential geometric concept of Ollivier-Ricci curvature. The latter runs in polynomial time and thus could significantly reduce the overall complexity of determining whether a QUBO problem is minor embeddable, and thus solvable on the D-Wave architecture.

  7. Optical waveguide device with an adiabatically-varying width

    DOEpatents

    Watts; Michael R. , Nielson; Gregory N.

    2011-05-10

    Optical waveguide devices are disclosed which utilize an optical waveguide having a waveguide bend therein with a width that varies adiabatically between a minimum value and a maximum value of the width. One or more connecting members can be attached to the waveguide bend near the maximum value of the width thereof to support the waveguide bend or to supply electrical power to an impurity-doped region located within the waveguide bend near the maximum value of the width. The impurity-doped region can form an electrical heater or a semiconductor junction which can be activated with a voltage to provide a variable optical path length in the optical waveguide. The optical waveguide devices can be used to form a tunable interferometer (e.g. a Mach-Zehnder interferometer) which can be used for optical modulation or switching. The optical waveguide devices can also be used to form an optical delay line.

  8. Planar prism spectrometer based on adiabatically connected waveguiding slabs

    NASA Astrophysics Data System (ADS)

    Civitci, F.; Hammer, M.; Hoekstra, H. J. W. M.

    2016-04-01

    The device principle of a prism-based on-chip spectrometer for TE polarization is introduced. The spectrometer exploits the modal dispersion in planar waveguides in a layout with slab regions having two different thicknesses of the guiding layer. The set-up uses parabolic mirrors, for the collimation of light of the input waveguide and focusing of the light to the receiver waveguides, which relies on total internal reflection at the interface between two such regions. These regions are connected adiabatically to prevent unwanted mode conversion and loss at the edges of the prism. The structure can be fabricated with two wet etching steps. The paper presents basic theory and a general approach for device optimization. The latter is illustrated with a numerical example assuming SiON technology.

  9. Adiabatic invariants in stellar dynamics. 1: Basic concepts

    NASA Technical Reports Server (NTRS)

    Weinberg, Martin D.

    1994-01-01

    The adiabatic criterion, widely used in astronomical dynamics, is based on the harmonic oscillator. It asserts that the change in action under a slowly varying perturbation is exponentially small. Recent mathematical results that precisely define the conditions for invariance show that this model does not apply in general. In particular, a slowly varying perturbation may cause significant evolution stellar dynamical systems even if its time scale is longer than any internal orbital time scale. This additional 'heating' may have serious implications for the evolution of star clusters and dwarf galaxies which are subject to long-term environmental forces. The mathematical developments leading to these results are reviewed, and the conditions for applicability to and further implications for stellar systems are discussed. Companion papers present a computational method for a general time-dependent disturbance and detailed example.

  10. Shortcut to Adiabaticity for an Anisotropic Gas Containing Quantum Defects.

    PubMed

    Papoular, D J; Stringari, S

    2015-07-10

    We present a shortcut to adiabaticity (STA) protocol applicable to 3D unitary Fermi gases and 2D weakly interacting Bose gases containing defects such as vortices or solitons. Our protocol relies on a new class of exact scaling solutions in the presence of anisotropic time-dependent harmonic traps. It connects stationary states in initial and final traps having the same frequency ratios. The resulting scaling laws exhibit a universal form and also apply to the classical Boltzmann gas. The duration of the STA can be made very short so as to realize a quantum quench from one stationary state to another. When applied to an anisotropically trapped superfluid gas, the STA conserves the shape of the quantum defects hosted by the cloud, thereby acting like a perfect microscope, which sharply contrasts with their strong distortion occurring during the free expansion of the cloud.

  11. Multiphoton Raman Atom Optics with Frequency-Swept Adiabatic Passage

    NASA Astrophysics Data System (ADS)

    Kotru, Krish; Butts, David; Kinast, Joseph; Stoner, Richard

    2016-05-01

    Light-pulse atom interferometry is a promising candidate for future inertial navigators, gravitational wave detectors, and measurements of fundamental physical constants. The sensitivity of this technique, however, is often limited by the small momentum separations created between interfering atom wave packets (typically ~ 2 ℏk) . We address this issue using light-pulse atom optics derived from stimulated Raman transitions and frequency-swept adiabatic rapid passage (ARP). In experiments, these Raman ARP atom optics have generated up to 30 ℏk photon recoil momenta in an acceleration-sensitive atom interferometer, thereby enhancing the phase shift per unit acceleration by a factor of 15. Since this approach forgoes evaporative cooling and velocity selection, it could enable large-area atom interferometry at higher data rates, while also lowering the atom shot-noise-limited measurement uncertainty.

  12. Some properties of adiabatic blast waves in preexisting cavities

    NASA Technical Reports Server (NTRS)

    Cox, D. P.; Franco, J.

    1981-01-01

    Cox and Anderson (1982) have conducted an investigation regarding an adiabatic blast wave in a region of uniform density and finite external pressure. In connection with an application of the results of the investigation to a study of interstellar blast waves in the very hot, low-density matrix, it was found that it would be desirable to examine situations with a positive radial density gradient in the ambient medium. Information concerning such situations is needed to learn about the behavior of blast waves occurring within preexisting, presumably supernova-induced cavities in the interstellar mass distribution. The present investigation is concerned with the first steps of a study conducted to obtain the required information. A review is conducted of Sedov's (1959) similarity solutions for the dynamical structure of any explosion in a medium with negligible pressure and power law density dependence on radius.

  13. Hydroxylamine nitrate self-catalytic kinetics study with adiabatic calorimetry.

    PubMed

    Liu, Lijun; Wei, Chunyang; Guo, Yuyan; Rogers, William J; Sam Mannan, M

    2009-03-15

    Hydroxylamine nitrate (HAN) is an important member of the hydroxylamine compound family with applications that include equipment decontamination in the nuclear industry and aqueous or solid propellants. Due to its instability and autocatalytic behavior, HAN has been involved in several incidents at the Hanford and Savannah River Site (SRS) [Technical Report on Hydroxylamine Nitrate, US Department of Energy, 1998]. Much research has been conducted on HAN in different areas, such as combustion mechanism, decomposition mechanism, and runaway behavior. However, the autocatalytic decomposition behavior of HAN at runaway stage has not been fully addressed due to its highly exothermic and rapid decomposition behavior. This work is focused on extracting HAN autocatalytic kinetics and analyzing HAN critical behavior from adiabatic calorimetry measurements. A lumped autocatalytic kinetic model for HAN and associated model parameters are determined. Also the storage and handling critical conditions of diluted HAN solution without metal presence are quantified.

  14. Controlled Rapid Adiabatic Passage in a V-Type System

    NASA Astrophysics Data System (ADS)

    Song, Yunheung; Lee, Han-Gyeol; Jo, Hanlae; Ahn, Jaewook

    2016-05-01

    In chirped rapid adiabatic passage (RAP), chirp sign determines the final state to which the complete population transfer (CPT) occurs in a three-level V-type system. In this study, we show that laser intensity can be alternatively used as a control means in RAP, when the laser pulse is chirped and of a spectral hole resonant to one of the excited states. We verified such excitation selectivity in the experiment performed as-shaped femtosecond laser pulses interacting with the lowest three levels (5S, 5 P1/2, and 5 P3/2) of atomic rubidium. The successful demonstration implies that this intensity-dependent RAP in conjunction with laser beam profile programming may allow excitation selectivity for atoms or ions arranged in space.

  15. Nucleon-deuteron scattering using the adiabatic projection method

    NASA Astrophysics Data System (ADS)

    Elhatisari, Serdar; Lee, Dean; Meißner, Ulf-G.; Rupak, Gautam

    2016-06-01

    In this paper we discuss the adiabatic projection method, a general framework for scattering and reaction calculations on the lattice. We also introduce several new techniques developed to study nucleus-nucleus scattering and reactions on the lattice. We present technical details of the method for large-scale problems. To estimate the systematic errors of the calculations we consider simple two-particle scattering on the lattice. Then we benchmark the accuracy and efficiency of the numerical methods by applying these to calculate fermion-dimer scattering in lattice effective field theory with and without a long-range Coulomb potential. The fermion-dimer calculations correspond to neutron-deuteron and proton-deuteron scattering in the spin-quartet channel at leading order in the pionless effective field theory.

  16. Vertical and adiabatic electronic excitations in biphenylene: A theoretical study

    NASA Astrophysics Data System (ADS)

    Beck, M. E.; Rebentisch, R.; Hohlneicher, G.; Fülscher, M. P.; Serrano-Andrés, L.; Roos, B. O.

    1997-12-01

    The low-lying singlet states of biphenylene have been studied using ab initio methods. Vertical excitation energies were calculated by multiconfigurational perturbation theory (CASPT2), starting from a complete active space self-consistent field (CASSCF) reference. The geometries of the most important low-lying excited states were individually optimized at the CASSCF level to study the difference between vertical and adiabatic excitations. Extended atomic natural orbital (ANO)-type basis sets were used to calculate state energies. Geometry optimizations were done with smaller ANO-type basis sets. Excitations from the ground state to the 1 1B3g and 1 1B2u excited singlet states lead to pronounced geometry changes which alter the bond alternation pattern. The theoretical results provide a solid basis for the assignment and interpretation of experimental spectra.

  17. Perspective: Stimulated Raman adiabatic passage: The status after 25 years

    NASA Astrophysics Data System (ADS)

    Bergmann, Klaas; Vitanov, Nikolay V.; Shore, Bruce W.

    2015-05-01

    The first presentation of the STIRAP (stimulated Raman adiabatic passage) technique with proper theoretical foundation and convincing experimental data appeared 25 years ago, in the May 1st, 1990 issue of The Journal of Chemical Physics. By now, the STIRAP concept has been successfully applied in many different fields of physics, chemistry, and beyond. In this article, we comment briefly on the initial motivation of the work, namely, the study of reaction dynamics of vibrationally excited small molecules, and how this initial idea led to the documented success. We proceed by providing a brief discussion of the physics of STIRAP and how the method was developed over the years, before discussing a few examples from the amazingly wide range of applications which STIRAP now enjoys, with the aim to stimulate further use of the concept. Finally, we mention some promising future directions.

  18. Adiabatic model and design of a translating field reversed configuration

    SciTech Connect

    Intrator, T. P.; Siemon, R. E.; Sieck, P. E.

    2008-04-15

    We apply an adiabatic evolution model to predict the behavior of a field reversed configuration (FRC) during decompression and translation, as well as during boundary compression. Semi-empirical scaling laws, which were developed and benchmarked primarily for collisionless FRCs, are expected to remain valid even for the collisional regime of FRX-L experiment. We use this approach to outline the design implications for FRX-L, the high density translated FRC experiment at Los Alamos National Laboratory. A conical theta coil is used to accelerate the FRC to the largest practical velocity so it can enter a mirror bounded compression region, where it must be a suitable target for a magnetized target fusion (MTF) implosion. FRX-L provides the physics basis for the integrated MTF plasma compression experiment at the Shiva-Star pulsed power facility at Kirtland Air Force Research Laboratory, where the FRC will be compressed inside a flux conserving cylindrical shell.

  19. Differential geometric treewidth estimation in adiabatic quantum computation

    NASA Astrophysics Data System (ADS)

    Wang, Chi; Jonckheere, Edmond; Brun, Todd

    2016-10-01

    The D-Wave adiabatic quantum computing platform is designed to solve a particular class of problems—the Quadratic Unconstrained Binary Optimization (QUBO) problems. Due to the particular "Chimera" physical architecture of the D-Wave chip, the logical problem graph at hand needs an extra process called minor embedding in order to be solvable on the D-Wave architecture. The latter problem is itself NP-hard. In this paper, we propose a novel polynomial-time approximation to the closely related treewidth based on the differential geometric concept of Ollivier-Ricci curvature. The latter runs in polynomial time and thus could significantly reduce the overall complexity of determining whether a QUBO problem is minor embeddable, and thus solvable on the D-Wave architecture.

  20. Shortcut to Adiabaticity for an Anisotropic Gas Containing Quantum Defects

    NASA Astrophysics Data System (ADS)

    Papoular, D. J.; Stringari, S.

    2015-07-01

    We present a shortcut to adiabaticity (STA) protocol applicable to 3D unitary Fermi gases and 2D weakly interacting Bose gases containing defects such as vortices or solitons. Our protocol relies on a new class of exact scaling solutions in the presence of anisotropic time-dependent harmonic traps. It connects stationary states in initial and final traps having the same frequency ratios. The resulting scaling laws exhibit a universal form and also apply to the classical Boltzmann gas. The duration of the STA can be made very short so as to realize a quantum quench from one stationary state to another. When applied to an anisotropically trapped superfluid gas, the STA conserves the shape of the quantum defects hosted by the cloud, thereby acting like a perfect microscope, which sharply contrasts with their strong distortion occurring during the free expansion of the cloud.