Estimating costs of improving Adirondack timber stands by killing culls with frills and sodium arsenite

Treesearch

Robert O. Curtis

1956-01-01

Although it has been known for many years that sodium arsenite solution applied in ax frills is an effective means of killing cull trees (1), no published information could be found on the cost of stand-improvement work with this method under Adirondack conditions.

'They of the Great Rocks'-2

NASA Technical Reports Server (NTRS)

2004-01-01

This approximate true color image taken by the panoramic camera onboard the Mars Exploration Rover Spirit shows 'Adirondack,' the rover's first target rock. Spirit traversed the sandy martian terrain at Gusev Crater to arrive in front of the football-sized rock on Sunday, Jan. 18, 2004, just three days after it successfully rolled off the lander. The rock was selected as Spirit's first target because its dust-free, flat surface is ideally suited for grinding. Clean surfaces also are better for examining a rock's top coating. Scientists named the angular rock after the Adirondack mountain range in New York. The word Adirondack is Native American and is interpreted by some to mean 'They of the great rocks.'

Exploring satisfaction among paddlers in two Adirondack canoeing areas

Treesearch

Becky J. Pfaffenbach; Harry C. Zinn; Chad P. Dawson

2003-01-01

An exploratory study examining the relationships between visitor satisfaction, perceived crowding, and expected crowding was conducted using both quantitative and qualitative methods. The study sample consisted of non-motorized watercraft users in two adjacent popular canoe areas in New York State's Adirondack Forest Preserve: the Saint Regis Canoe Area (SRCA) and...

Attributes affecting campsite selection at two types of campgrounds in the Adirondack Park

Treesearch

Kye-Young Choi; Chad P. Dawson

2003-01-01

This study compared the important attributes affecting campers' decisions in selecting their preferred campsites at two different types of New York State Department of Environmental Conservation (NYSDEC) campgrounds in the Adirondack Park. Mail surveys were sent to campers using six NYSDEC campgrounds (three less-developed campgrounds and three more-developed...

Deep crustal deformation by sheath folding in the Adirondack Mountains, USA

NASA Technical Reports Server (NTRS)

Mclelland, J. M.

1988-01-01

As described by McLelland and Isachsen, the southern half of the Adirondacks are underlain by major isoclinal (F sub 1) and open-upright (F sub 2) folds whose axes are parallel, trend approximately E-W, and plunge gently about the horizontal. These large structures are themselves folded by open upright folds trending NNE (F sub 3). It is pointed out that elongation lineations in these rocks are parallel to X of the finite strain ellipsoid developed during progressive rotational strain. The parallelism between F sub 1 and F sub 2 fold axes and elongation lineations led to the hypothesis that progressive rotational strain, with a west-directed tectonic transport, rotated earlier F sub 1-folds into parallelism with the evolving elongation lineation. Rotation is accomplished by ductile, passive flow of F sub 1-axes into extremely arcuate, E-W hinges. In order to test these hypotheses a number of large folds were mapped in the eastern Adirondacks. Other evidence supporting the existence of sheath folds in the Adirondacks is the presence, on a map scale, of synforms whose limbs pass through the vertical and into antiforms. This type of outcrop pattern is best explained by intersecting a horizontal plane with the double curvature of sheath folds. It is proposed that sheath folding is a common response of hot, ductile rocks to rotational strain at deep crustal levels. The recognition of sheath folds in the Adirondacks reconciles the E-W orientation of fold axes with an E-W elongation lineation.

Response of fish assemblages to declining acidic deposition in Adirondack Mountain lakes, 1984–2012

USGS Publications Warehouse

Baldigo, Barry P.; Roy, Karen; Driscoll, Charles T.

2016-01-01

Adverse effects of acidic deposition on the chemistry and fish communities were evident in Adirondack Mountain lakes during the 1980s and 1990s. Fish assemblages and water chemistry in 43 Adirondack Long-Term Monitoring (ALTM) lakes were sampled by the Adirondack Lakes Survey Corporation and the New York State Department of Environmental Conservation during three periods (1984–87, 1994–2005, and 2008–12) to document regional impacts and potential biological recovery associated with the 1990 amendments to the 1963 Clean Air Act (CAA). We assessed standardized data from 43 lakes sampled during the three periods to quantify the response of fish-community richness, total fish abundance, and brook trout (Salvelinus fontinalis) abundance to declining acidity that resulted from changes in U.S. air-quality management between 1984 and 2012. During the 28-year period, mean acid neutralizing capacity (ANC) increased significantly from 3 to 30 μeq/L and mean inorganic monomeric Al concentrations decreased significantly from 2.22 to 0.66 μmol/L, yet mean species richness, all species or total catch per net night (CPNN), and brook trout CPNN did not change significantly in the 43 lakes. Regression analyses indicate that fishery metrics were not directly related to the degree of chemical recovery and that brook trout CPNN may actually have declined with increasing ANC. While the richness of fish communities increased with increasing ANC as anticipated in several Adirondack lakes, observed improvements in water quality associated with the CAA have generally failed to produce detectable shifts in fish assemblages within a large number of ALTM lakes. Additional time may simply be needed for biological recovery to progress, or else more proactive efforts may be necessary to restore natural fish assemblages in Adirondack lakes in which water chemistry is steadily recovering from acidification.

Mercury in the Soil of Two Contrasting Watersheds in the Eastern United States

PubMed Central

Burns, Douglas A.; Woodruff, Laurel G.; Bradley, Paul M.; Cannon, William F.

2014-01-01

Soil represents the largest store of mercury (Hg) in terrestrial ecosystems, and further study of the factors associated with soil Hg storage is needed to address concerns about the magnitude and persistence of global environmental Hg bioaccumulation. To address this need, we compared total Hg and methyl Hg concentrations and stores in the soil of different landscapes in two watersheds in different geographic settings with similar and relatively high methyl Hg concentrations in surface waters and biota, Fishing Brook, Adirondack Mountains, New York, and McTier Creek, Coastal Plain, South Carolina. Median total Hg concentrations and stores in organic and mineral soil samples were three-fold greater at Fishing Brook than at McTier Creek. Similarly, median methyl Hg concentrations were about two-fold greater in Fishing Brook soil than in McTier Creek soil, but this difference was significant only for mineral soil samples, and methyl Hg stores were not significantly different among these watersheds. In contrast, the methyl Hg/total Hg ratio was significantly greater at McTier Creek suggesting greater climate-driven methylation efficiency in the Coastal Plain soil than that of the Adirondack Mountains. The Adirondack soil had eight-fold greater soil organic matter than that of the Coastal Plain, consistent with greater total Hg stores in the northern soil, but soil organic matter – total Hg relations differed among the sites. A strong linear relation was evident at McTier Creek (r2 = 0.68; p<0.001), but a linear relation at Fishing Brook was weak (r2 = 0.13; p<0.001) and highly variable across the soil organic matter content range, suggesting excess Hg binding capacity in the Adirondack soil. These results suggest greater total Hg turnover time in Adirondack soil than that of the Coastal Plain, and that future declines in stream water Hg concentrations driven by declines in atmospheric Hg deposition will be more gradual and prolonged in the Adirondacks. PMID:24551042

Mercury in the soil of two contrasting watersheds in the eastern United States

USGS Publications Warehouse

Burns, Douglas A.; Woodruff, Laurel G.; Bradley, Paul M.; Cannon, William F.

2014-01-01

Soil represents the largest store of mercury (Hg) in terrestrial ecosystems, and further study of the factors associated with soil Hg storage is needed to address concerns about the magnitude and persistence of global environmental Hg bioaccumulation. To address this need, we compared total Hg and methyl Hg concentrations and stores in the soil of different landscapes in two watersheds in different geographic settings with similar and relatively high methyl Hg concentrations in surface waters and biota, Fishing Brook, Adirondack Mountains, New York, and McTier Creek, Coastal Plain, South Carolina. Median total Hg concentrations and stores in organic and mineral soil samples were three-fold greater at Fishing Brook than at McTier Creek. Similarly, median methyl Hg concentrations were about two-fold greater in Fishing Brook soil than in McTier Creek soil, but this difference was significant only for mineral soil samples, and methyl Hg stores were not significantly different among these watersheds. In contrast, the methyl Hg/total Hg ratio was significantly greater at McTier Creek suggesting greater climate-driven methylation efficiency in the Coastal Plain soil than that of the Adirondack Mountains. The Adirondack soil had eight-fold greater soil organic matter than that of the Coastal Plain, consistent with greater total Hg stores in the northern soil, but soil organic matter – total Hg relations differed among the sites. A strong linear relation was evident at McTier Creek (r2 = 0.68; p2 = 0.13; p<0.001) and highly variable across the soil organic matter content range, suggesting excess Hg binding capacity in the Adirondack soil. These results suggest greater total Hg turnover time in Adirondack soil than that of the Coastal Plain, and that future declines in stream water Hg concentrations driven by declines in atmospheric Hg deposition will be more gradual and prolonged in the Adirondacks.

Using Critical Loads to Look at Improvements in Acidic Surface Water Conditions since the 1990 Amendments to the Clear Air Act: Case Study Adirondack, NY

NASA Astrophysics Data System (ADS)

Lynch, J. A.; Kolian, M. J.; Haeuber, R.

2008-12-01

Acid deposition has affected hundreds of lakes and thousands of miles of headwater streams in the Adirondack region of New York State. The diversity of life in these acidic waters has been greatly reduced. The poor buffering capacity of the thin, acidic soils in the Adirondack Mountains makes the lakes and ponds particularly susceptible to acidification. Since the mid-1990's, lakes in the Adirondack region are finally showing signs of recovery. The good news is that emissions of sulfur dioxide and nitrogen oxides have been reduced and as a result acidic deposition of sulfate and nitrate has decreased in surface waters approximately 26 and 13%, respectively. This has led to improvement in the acid neutralizing capacity (ANC) of these water bodies. Although improvement in water quality is a good sign, it does not tell us if a particular lake or a group of lakes have recovered from decades of acidic deposition. However, the critical loads approach does allow for evaluation of whether a water body has reached recovery for acidic deposition. Critical loads and exceedances for lake surface water and acidity were calculated for 187 lakes in the Adirondack region. The Steady-State Water Chemistry (SSWC) model was used to calculate the critical load, relying on water chemistry data from the TIME/LTM network. An ANC threshold of 50 μeq/L was selected for this case study. Exceedances were calculated from deposition for the period before implementation of the Acid Rain program (ARP) (1989-1991) and for the period of 2004-2006 to judge improvements as a result of the ARP. On average, the critical load for lakes in the Adirondack region is 164 meq/m2/yr, while it is 48 meq/m2/yr for the most sensitive lakes (i.e. ANC less than 100 μeq/L). For the period from 2004 to 2006, 65% of the lakes within the TIME/LTM network continued to receive levels of acid deposition that exceeded the lake's critical load down from 72% of lakes before implementation of the Acid Rain Program. Despite improvement in water quality that has occurred over the past decades in the Adirondack region additional reduction in acidic deposition is needed in order for greater recovery of these sensitive aquatic systems.

USE OF A LUMPED MODEL (MAGIC) TO BOUND THE ESTIMATION OF POTENTIAL FUTURE EFFECTS OF SULFUR AND NITROGEN DEPOSITION ON LAKE CHEMISTRY IN THE ADIRONDACK MOUNTAINS

EPA Science Inventory

Leaching of atmospherically deposited nitrogen from forested watersheds can acidify lakes and streams. Using a modified version of the Model of Acidification of Groundwater in Catchments, we made computer simulations of such effects for 36 lake catchments in the Adirondack Mount...

Rehabilitation of alpine vegetation in the Adirondack Mountains of New York State

Treesearch

E.H. Ketchledge; R.E. Leonard; N.A. Richards; P.F. Craul; A.R. Eschner; A.R. Eschner

1985-01-01

This paper describes field experiments in using sod-forming grasses from lower elevations as soil stabilizers, and discusses the effects of fertilizing and transplanting native vegetation as part of an integrated management plan for rehabilitating alpine plant communities in the Adirondacks. Results show that it is possible to stabilize severely degraded alpine...

Lake acidification in the Adirondack Mountains of New York causes and consequences

Treesearch

Carl L. Schofield

1976-01-01

Current and historic geographic distributions of acidity in Adirondack lakes were examined in relation to regional edaphic, climatic, and physiographic features. Acid conditions are currently predominant in high elevation drainage lakes having small watershed/surface area ratios. Comparable levels of acidity were found only in small seepage lakes and bog ponds during...

Aluminum toxicity risk reduction as a result of reduced acid deposition in Adirondack lakes and ponds.

PubMed

Michelena, Toby M; Farrell, Jeremy L; Winkler, David A; Goodrich, Christine A; Boylen, Charles W; Sutherland, James W; Nierzwicki-Bauer, Sandra A

2016-11-01

In 1990, the US Congress amended the Clean Air Act (CAA) to reduce regional-scale ecosystem degradation from SO x and NO x emissions which have been responsible for acid deposition in regions such as the Adirondack Mountains of New York State. An ecosystem assessment project was conducted from 1994 to 2012 by the Darrin Fresh Water Institute to determine the effect of these emission reduction policies on aquatic systems. The project investigated water chemistry and biota in 30 Adirondack lakes and ponded waters. Although regulatory changes made in response to the 1990 CAA amendments resulted in a reduction of acid deposition within the Adirondacks, the ecosystem response to these reductions is complicated. A statistical analysis of SO 4 , pH, Al, and DOC data collected during this project demonstrates positive change in response to decreased deposition. The changes in water chemistry also have lowered the risk of Al toxicity to brook trout (Salvelinus fontinalis [Mitchill]), which allowed the re-introduction of this species to Brooktrout Lake from which it had been extirpated. However, pH and labile aluminum (Al im ) fluctuate and are not strongly correlated to changes in acid deposition. As such, toxicity to S. fontinalis also is cyclic and provides rationale for the difficulties inherent in re-establishing resident populations in impacted aquatic environments. Overall, aquatic ecosystems of the Adirondacks show a positive response to reduced deposition driven by changes in environmental policy, but the response is more complex and indicates an ecosystem-wide interaction between aquatic and watershed components of the ecosystem.

Sensitivity of stream methyl Hg concentrations to environmental change in the Adirondack mountains of New York, USA

Treesearch

Doug Burns; Karen Riva Murray; Elizabeth A. Nystrom; David M. Wolock; Geofrey Millard; Charles T. Driscoll

2016-01-01

The Adirondacks of New York have high levels of mercury (Hg) bioaccumulation as demonstrated by a region-wide fish consumption advisory for children and women who may become pregnant. The source of this Hg is atmospheric deposition that originates from regional, continental, and global emissions.

Toward a better understanding of recreational boating in the Adirondack lakes region

Treesearch

Herbert E. Echelberger; George H. Moeller

1973-01-01

Results of a study to determine the relationship between physical characteristics of Adirondack lakes and variations in peak boat-use intensity indicated that 69 percent of the variation in peak use can be accounted for by the number of public and commercial boat-launching facilities per mile of lake shoreline. Other lake characteristics related to peak boat use were:...

Impact of backcountry recreationists on the water quality of an Adirondack lake

Treesearch

Robert G. Werner; Raymond E. Leonard; James O. Crevelling; James O. Crevelling

1985-01-01

This study reports the effects of recreational use on the water quality of an Adirondack lake. Phosphates, nitrates, conductivity, fecal coliform, transparency, and temperature were regularly measured over a period of 2 years and related to the recreational use that the lake received during that time. An adjacent lake, which was not visited by recreationists, served as...

Climbers' attitudes toward recreation resource impacts in the Adirondack Park

Treesearch

Christopher A. Monz; Katherine E. Smith; Leah Knickerbocker

2006-01-01

Climbers arriving at trailheads to popular climbing areas in Adirondack Park, NY were surveyed as to the types of resource impacts they found to be offensive. Climbers were also asked about their degree of concern regarding crowding, noise and management of climbing areas. Some resource impacts, such as damage to trees as a result of poor climbing practices, are...

Effects of acidic deposition and soil acidification on sugar maple trees in the Adirondack Mountains, New York

USGS Publications Warehouse

Sullivan, Timothy J.; Lawrence, Gregory B.; Bailey, Scott W.; McDonnell, Todd C.; McPherson, G.T.

2013-01-01

This study documents the effects of acidic deposition and soil acid-base chemistry on the growth, regeneration, and canopy condition of sugar maple (SM) trees in the Adirondack Mountains of New York. Sugar maple is the dominant canopy species throughout much of the northern hardwood forest in the State. A field study was conducted in 2009 in which 50 study plots within 20 small Adirondack watersheds were sampled and evaluated for soil acid-base chemistry and SM growth, canopy condition, and regeneration. Atmospheric sulfur (S) and nitrogen (N) deposition were estimated for each plot. Trees growing on soils with poor acid-base chemistry (low exchangeable calcium and % base saturation) that receive relatively high levels of atmospheric S and N deposition exhibited little to no SM seedling regeneration, decreased canopy condition, and short-to long-term growth declines compared with study plots having better soil condition and lower levels of atmospheric deposition. These results suggest that the ecosystem services provided by SM in the western and central Adirondack Mountain region, including aesthetic, cultural, and monetary values, are at risk from ongoing soil acidification caused in large part by acidic deposition.

Fluid-absent metamorphism in the Adirondacks

NASA Technical Reports Server (NTRS)

Valley, J. W.

1986-01-01

Results on late Proterozoic metamorphism of granulite in the Adirondacks are presented. There more than 20,000 sq km of rock are at granulite facies. Low water fugacites are implied by orthopyroxene bearing assemblages and by stability of k'spar-plag-quartz assemblages. After mentioning the popular concept of infiltration of carbon dioxide into Precambrian rocks and attendent generation of granulite facies assemblages, several features of Adirondack rocks pertinent to carbon dioxide and water during their metamorphism are summarized: wollastonite occurs in the western lowlands; contact metamorphism by anorthosite preceeding granulite metamorphism is indicated by oxygen isotopes. Oxygen fugacity lies below that of the QFM buffer; total P sub water + P sub carbon dioxide determined from monticellite bearing assemblages are much less than P sub total (7 to 7.6 kb). These and other features indicate close spatial association of high- and low-P sub carbon dioxide assemblages and that a vapor phase was not present during metamorphism. Thus Adirondack rocks were not infiltrated by carbon dioxide vapor. Their metamorphism, at 625 to 775 C, occurred either when the protoliths were relatively dry or after dessication occurred by removal of a partial melt phase.

Regional planning acceptance by residents of Northern New York, USA

NASA Astrophysics Data System (ADS)

Bobrow, Patricia; Gaige, Barbara; Harris, Glenn; Kennedy, Joyce; King, Leslie; Raymond, William; Werbitsky, Darrin

1984-01-01

This study compares the effectiveness of two regional planning agencies in terms of public support for various planning activities. The Adirondack Park Agency and the Temporary State Commission on Tug Hill have fundamentally different approaches to planning. The Adirondack Park Agency has implemented a restrictive regulatory program with little citizen participation by Adirondack residents. The Tug Hill Commission has implemented an advisory and coordinating program with an emphasis on public input. Residents of two towns in each region were surveyed to determine environmental concern and support for regional planning activities. Respondents from both regions favored a planning agency that incorporates citizen input; controls air, water, and toxic waste pollution; and develops recreation areas. They strongly opposed an agency that regulates private land-use. Basic demographic characteristics and levels of environmental concern were similar in all four towns, but receptivity to various planning activities was consistently greater among residents of the Tug Hill Region. Paired comparisons of the four towns demonstrated no differences between towns of the same region and significant differences between towns of different regions. Public support for regional planning is greater in the Tug Hill Region than in the Adirondack Park.

Recreation-related values, attitudes, and beliefs of business owners in the Saranac Lakes region of New York State's Adirondack Park

Treesearch

Diane Kuehn; Rudy Schuster

2008-01-01

Public forest management agencies often work with recreation-related business owners as they implement management policies. The main objective of this study is to quantify the values, beliefs, and attitudes of business owners in the Saranac Lakes Region of New York's Adirondack Park regarding motorboating, nonmotorized boating, and personal watercraft use. The...

Some effects of stand density and deer browsing on reproduction in an Adirondack hardwood stand

Treesearch

Robert O. Curtis; F.M. Rushmore

1958-01-01

The northern hardwood stands of the Adirondack region of New York constitute a major natural resource, the basis of one of the few year-round industries of the area. However, knowledge of their silviculture and potential productivity is limited. The results of an exploratory study begun in 1938 provide some information about the problems involved in the management of...

Effects of Acidic Deposition and Soil Acidification on Sugar Maple Trees in the Adirondack Mountains, New York

Treesearch

T. J. Sullivan; G. B. Lawrence; S. W. Bailey; T. C. McDonnell; C. M. Beier; K. C. Weathers; G. T. McPherson; D. A. Bishop

2013-01-01

We documented the effects of acidic atmospheric deposition and soil acidification on the canopy health, basal area increment, and regeneration of sugar maple (SM) trees across the Adirondack region of New York State, in the northeastern United States, where SM are plentiful but not well studied and where widespread depletion of soil calcium (Ca) has been...

Conservation easements in the Adirondack Park of New York state

Treesearch

Chad P. Dawson; Steven Bick; Peter D' Luhosch; Matthew Nowak; Diane Kuehn

2015-01-01

The use of conservation easements to keep private lands undeveloped and protect open space and large scale landscapes has grown rapidly. The New York State Adirondack Park includes 2.5 million acres (1 million ha) of state owned land and 3 million acres (1.2 million ha) of private lands; over 781,000 acres (316,194 ha) of these private lands were under publicly held...

Fish population losses from Adirondack Lakes: The role of surface water acidity and acidification

NASA Astrophysics Data System (ADS)

Baker, Joan P.; Warren-Hicks, William J.; Gallagher, James; Christensen, Sigurd W.

1993-04-01

Changes over time in the species composition of fish communities in Adirondack lakes were assessed to determine (1) the approximate numbers offish populations that have been lost and (2) the degree to which fish population losses may have resulted from surface water acidification and acidic deposition. Information on the present-day status offish communities was obtained by the Adirondack Lakes Survey Corporation, which surveyed 1469 Adirondack lakes in 1984-1987 (53% of the total ponded waters in the Adirondack ecological zone). Two hundred and ninety-five of these lakes had been surveyed in 1929-1934 during the first statewide biological survey; 720 had been surveyed in one or more years prior to 1970. Sixteen to 19% of the lakes with adequate historical data appeared to have lost one or more fish populations as a result of acidification. Brook trout and acid-sensitive minnow species had experienced the most widespread effects. Populations of brook trout and acid-sensitive minnows had been lost apparently as a result of acidification from 11% and 19%, respectively, of the lakes with confirmed historical occurrence of these taxa. By contrast, fish species that tend to occur primarily in lower elevation and larger lakes, such as largemouth and smallmouth bass and brown trout, have experienced little to no documented adverse effects. Lakes that were judged to have lost fish populations as a result of acidification had significantly lower; pH and, in most cases, also had higher estimated concentrations of inorganic aluminum and occurred at higher elevations than did lakes with the fish species still present. No other lake characteristics were consistently associated with fish population losses attributed to acidification. The exact numbers and proportions of fish populations affected could not be determined because of limitations on the quantity and quality of historical data. Lakes for which we had adequate historical data to assess long-term trends in fish communities were significantly larger and deeper and have higher pH than do Adirondack lakes in general; thus, fish communities adversely affected by acidification and acidic deposition may be underrepresented in this study.

U-Pb age of the Diana Complex and Adirondack granulite petrogenesis

USGS Publications Warehouse

Basu, A.R.; Premo, W.R.

2001-01-01

U-Pb isotopic analyses of eight single and multi-grain zircon fractions separated from a syenite of the Diana Complex of the Adirondack Mountains do not define a single linear array, but a scatter along a chord that intersects the Concordia curve at 1145 ?? 29 and 285 ?? 204 Ma. For the most concordant analyses, the 207Pb/206Pb ages range between 1115 and 1150 Ma. Detailed petrographic studies revealed that most grains contained at least two phases of zircon growth, either primary magmatic cores enclosed by variable thickness of metamorphic overgrowths or magmatic portions enclosing presumably older xenocrystic zircon cores. The magmatic portions are characterized by typical dipyramidal prismatic zoning and numerous black inclusions that make them quite distinct from adjacent overgrowths or cores when observed in polarizing light microscopy and in back-scattered electron micrographs. Careful handpicking and analysis of the "best" magmatic grains, devoid of visible overgrowth of core material, produced two nearly concordant points that along with two of the multi-grain analyses yielded an upper-intercept age of 1118 ?? 2.8 Ma and a lower-intercept age of 251 ?? 13 Ma. The older age is interpreted as the crystallization age of the syenite and the younger one is consistent with late stage uplift of the Appalachian region. The 1118 Ma age for the Diana Complex, some 35 Ma younger than previously believed, is now approximately synchronous with the main Adirondack anorthosite intrusion, implying a cogenetic relationship among the various meta-igneous rocks of the Adirondacks. The retention of a high-temperature contact metamorphic aureole around Diana convincingly places the timing of Adirondack regional metamorphism as early as 1118 Ma. This result also implies that the sources of anomalous high-temperature during granulite metamorphism are the syn-metamorphic intrusions, such as the Diana Complex.

Preliminary investigation of two areas in New York State in terms of possible potential for hot dry rock geothermal energy. [Adirondack Mountains and Catskill Mountains

DOE Office of Scientific and Technical Information (OSTI.GOV)

Isachsen, Y.W.

1978-09-27

Two areas in New York State were studied in terms of possible long range potential for geothermal energy: the Adirondack Mountains which are undergoing contemporary doming, and an anomalous circular feature centered on Panther Mountain in the Catskill Mountains. The Adirondack Mountains constitute an anomalously large, domical uplift on the Appalachian foreland. The domical configuration of the area undergoing uplift, combined with subsidence at the northeastern perimeter of the dome, argues for a geothermal rather than glacioisostatic origin. A contemporary hot spot near the crust-mantle boundary is proposed as the mechanism of doming, based on analogy with uplifts of similarmore » dimensions elsewhere in the world, some of which have associated Tertiary volcanics. The lack of thermal springs in the area, or high heat flow in drill holes up to 370 m deep, indicates that the front of the inferred thermal pulse must be at some depth greater than 1 km. From isopach maps by Rickard (1969, 1973), it is clear that the present Adirondack dome did not come into existence until sometime after Late Devonian time. Strata younger than this are not present to provide further time stratigraphic refinement of this lower limit. However, the consequent radial drainage pattern in the Adirondacks suggests that the dome is a relatively young tectonic feature. Using arguments based on fixed hot spots in central Africa, and the movement of North American plate, Kevin Burke (Appendix I) suggests that the uplift may be less than 4 m.y. old.The other area of interest, the Panther Mountain circular feature in the Catskill Mountains, was studied using photogeology, gravity and magnetic profiling, gravity modeling, conventional field methods, and local shallow seismic refraction profiling.« less

'They of the Great Rocks'-3

NASA Technical Reports Server (NTRS)

2004-01-01

This 3-D perspective image taken by the panoramic camera onboard the Mars Exploration Rover Spirit shows 'Adirondack,' the rover's first target rock. Spirit traversed the sandy martian terrain at Gusev Crater to arrive in front of the football-sized rock on Sunday, Jan. 18, 2004, just three days after it successfully rolled off the lander. The rock was selected as Spirit's first target because it has a flat surface and is relatively free of dust - ideal conditions for grinding into the rock to expose fresh rock underneath. Clean surfaces also are better for examining a rock's top coating.Scientists named the angular rock after the Adirondack mountain range in New York. The word Adirondack is Native American and means 'They of the great rocks.' Data from the panoramic camera's red, green and blue filters were combined to create this approximate true color image.

A monitor for continuous measurement of temperature, pH, and conductance of wet precipitation: Preliminary results from the Adirondack Mountains, New York

USGS Publications Warehouse

Johnsson, P.A.; Reddy, M.M.

1990-01-01

This report describes a continuous wet-only precipitation monitor designed by the U.S. Geological Survey to record variations in rainfall temperature, pH, and specific conductance at 1-min intervals over the course of storms. Initial sampling in the Adirondack Mountains showed that rainfall acidity varied over the course of summer storms, with low initial pH values increasing as storm intensity increased.This report describes a continuous wet-only precipitation monitor designed by the U.S. Geological Survey to record variations in rainfall temperature, pH, and specific conductance at 1-min intervals over the course of storms. Initial sampling in the Adirondack Mountains showed that rainfall acidity varied over the course of summer storms, with low initial pH values increasing as storm intensity increased.

Roadside camping on forest preserve lands in the Adirondack Park: A qualitative exploration of place attachment and resource substitutability

Treesearch

David A. Graefe; Chad Dawson; Rudolph M. Schuster

2012-01-01

Roadside camping is a popular and widespread public outdoor recreation activity on New York State Forest Preserve (FP) lands within the Adirondack Park (AP). While several roadside camping areas exist on FP lands throughout the Park, little is known about these camping areas or the visitors who use them. Recently, debate has developed over how to define and manage...

Effects of acidic deposition and soil acidification on sugar maple trees in the Adirondack Mountains, New York.

PubMed

Sullivan, T J; Lawrence, G B; Bailey, S W; McDonnell, T C; Beier, C M; Weathers, K C; McPherson, G T; Bishop, D A

2013-11-19

We documented the effects of acidic atmospheric deposition and soil acidification on the canopy health, basal area increment, and regeneration of sugar maple (SM) trees across the Adirondack region of New York State, in the northeastern United States, where SM are plentiful but not well studied and where widespread depletion of soil calcium (Ca) has been documented. Sugar maple is a dominant canopy species in the Adirondack Mountain ecoregion, and it has a high demand for Ca. Trees in this region growing on soils with poor acid-base chemistry (low exchangeable Ca and % base saturation [BS]) that receive relatively high levels of atmospheric sulfur and nitrogen deposition exhibited a near absence of SM seedling regeneration and lower crown vigor compared with study plots with relatively high exchangeable Ca and BS and lower levels of acidic deposition. Basal area increment averaged over the 20th century was correlated (p < 0.1) with acid-base chemistry of the Oa, A, and upper B soil horizons. A lack of Adirondack SM regeneration, reduced canopy condition, and possibly decreased basal area growth over recent decades are associated with low concentrations of nutrient base cations in this region that has undergone soil Ca depletion from acidic deposition.

Effects of acidic deposition and soil acidification on sugar maple trees in the Adirondack Mountains, New York

USGS Publications Warehouse

Sullivan, Timothy J.; Lawrence, Gregory B.; Bailey, Scott W.; McDonnell, Todd C.; Beier, Colin M.; Weathers, K.C.; McPherson, G.T.; Bishop, Daniel A.

2013-01-01

We documented the effects of acidic atmospheric deposition and soil acidification on the canopy health, basal area increment, and regeneration of sugar maple (SM) trees across the Adirondack region of New York State, in the northeastern United States, where SM are plentiful but not well studied and where widespread depletion of soil calcium (Ca) has been documented. Sugar maple is a dominant canopy species in the Adirondack Mountain ecoregion, and it has a high demand for Ca. Trees in this region growing on soils with poor acid–base chemistry (low exchangeable Ca and % base saturation [BS]) that receive relatively high levels of atmospheric sulfur and nitrogen deposition exhibited a near absence of SM seedling regeneration and lower crown vigor compared with study plots with relatively high exchangeable Ca and BS and lower levels of acidic deposition. Basal area increment averaged over the 20th century was correlated (p < 0.1) with acid–base chemistry of the Oa, A, and upper B soil horizons. A lack of Adirondack SM regeneration, reduced canopy condition, and possibly decreased basal area growth over recent decades are associated with low concentrations of nutrient base cations in this region that has undergone soil Ca depletion from acidic deposition.

Post-metamorphic fluid infiltration into granulites from the Adirondack Mountains, USA

NASA Technical Reports Server (NTRS)

Morrison, J.; Valley, John W.

1988-01-01

Post-metamorphic effects in the anorthosites of the Adirondacks, New York were described. Calcite-chlorite-sericite assemblages occur as veins, in disseminated form and as clots, and document retrograde fluid infiltration. These features are associated with late-state CO2-rich fluid inclusions. Stable isotope analyses of calcites indicates that the retrograde fluids interacted with meta-igneous and supracrustal lithologies, but the precise timing of the retrogression is as yet unknown.

The importance of visitors' knowledge of the cultural and natural history of the Adirondacks in influencing sense of place in the high peaks region

Treesearch

Laura Fredrickson

2002-01-01

This study examined various dimensions of the sense of place experience felt by visitors to the High Peaks of the Adirondack Park. More specifically, a 6-page questionnaire (mail-back postage-paid) was distributed to 803 people over a three-month period (June, July & August, 1999). The two primary objectives of this study were to: 1) explore the various...

Contemporary doming of the Adirondack mountains: Further evidence from releveling

USGS Publications Warehouse

Isachsen, Y.W.

1981-01-01

The Adirondack Mountains constitute an anomalously large, domical uplift on the Appalachian foreland. The dome has a NNE-SSW axis about 190 km long, and an east-west dimension of about 140 km. It has a structural relief of at least 1600 m, and a local topographic relief of up to 1200 m. First-order leveling in 1955, and again in 1973 along a north-south line at the eastern margin of the Adirondack shows an uplift rate of 2.2 mm/yr at the latitude of the center of the dome and a subsidence rate of 2.8 mm/yr at the northern end of the line near the Canadian border. The net amount of arching along this releveled line is 9 cm ?? 2 cm (Isachsen, 1975). To test the idea that this arching represented an "edge effect" of contemporary doming of the Adirondacks as a whole, the National Geodetic Survey was encouraged to relevel a 1931 north-south line between Utica and Fort Covington (near the Canadian border) which crosses the center of the dome. The releveling showed that the mountain mass is undergoing contemporary domical uplift at a rate which reaches 3.7 mm/yr near the center of the dome (compare with 1 mm/yr for the Swiss Alps). Three other releveled lines in the area support this conclusion. ?? 1981.

Browning of Adirondack, NY Lakes: Rates and Effects

NASA Astrophysics Data System (ADS)

Driscoll, C. T.; Mota, Y.; Fakhraei, H.; Todorova, S.; Leach, T.; Rose, K. C.; O'Donnell, S.

2017-12-01

Browning, or increases in the concentrations of dissolved organic matter (DOM), is an intriguing recent phenomenon occurring in northern freshwaters. It is hypothesized that browning is a watershed response to decreases in acid deposition, although changing in climate may also contribute. The Adirondack region of NY is experiencing marked increases in lake concentrations of dissolved organic carbon (DOC), with 29 out of 48 lakes in the Adirondack Long-Term Monitoring (ALTM) program showing significant increases and two exhibiting decreases since 1992. Increases in DOC is altering the acid base status of Adirondack lakes largely due increases in DOM with strongly acidic functional groups. DOM mobilization limits increases in acid neutralizing capacity that can be achieved in recovery of surface waters from acid deposition. A subset of ALTM lakes also appear to be experiencing changes in their physical characteristics during the summer stratification period, consistent with increases in DOM and browning. Of 28 lakes monitored for water column profiles since 1994: 8 are showing declines in thermocline depth (5 significant, p<0.05); all are exhibiting increases in epilimnetic temperature (9 significant); 26 are experiencing increases in the difference between epilimnetic and hypolimnetic temperatures (6 significant); and 17 are experiencing decreases in hypolimnetic dissolved oxygen concentrations (6 significant decreases, 1 increase). These changes may be a manifestation of increases in the attenuation of light associated with increases in DOM, increasing the intensity and duration of thermal stratification.

Long-term temporal trends and spatial patterns in the acid-base chemistry of lakes in the Adirondack region of New York in response to decreases in acidic deposition

NASA Astrophysics Data System (ADS)

Driscoll, Charles T.; Driscoll, Kimberley M.; Fakhraei, Habibollah; Civerolo, Kevin

2016-12-01

We examined the response of lake water chemistry in the Adirondack Mountains of New York State, USA to decreases in acid deposition. Striking declines in the concentrations and fluxes of sulfate and hydrogen ion in wet deposition have been observed since the late 1970s, while significant decreases in nitrate have been evident since the early 2000s. Decreases in estimated dry sulfur and nitrate deposition have also occurred in the Adirondacks, but with no change in dry to wet deposition ratios. These patterns follow long-term decreases in anthropogenic emissions of sulfur dioxide and nitrogen oxides in the U.S. over the same interval. All of the 48 lakes monitored through the Adirondack Long-Term Monitoring program since 1992 have exhibited significant declines in sulfate concentrations, consistent with reductions in atmospheric deposition of sulfur. Nitrate concentrations have also significantly diminished at variable rates in many (33 of 48) lakes. Decreases in concentrations of sulfate plus nitrate (48 of 48) in lakes have driven widespread increases in acid neutralizing capacity (ANC; 42 of 48) and lab pH (33 of 48), and decreases in the toxic fraction, inorganic monomeric Al (45 of 48). Coincident with decreases in acid deposition, concentrations of dissolved organic carbon (DOC) have also increased in some (29 of 48) lakes. While recovery from elevated acid deposition is evident across Adirondack lakes, highly sensitive and impacted mounded seepages lakes and thin till drainage lakes are recovering most rapidly. Future research might focus on how much additional recovery could be achieved given the current deposition relative to future deposition anticipated under the Clean Power Plan, ecosystem effects of increased mobilization of dissolved organic matter, and the influence of changing climate on recovery from acidification.

Adirondack Under the Microscope

NASA Technical Reports Server (NTRS)

2004-01-01

This image was taken by the Mars Exploration Rover Spirit front hazard-identification camera after the rover's first post-egress drive on Mars Sunday, Jan. 15, 2004. Engineers drove the rover approximately 3 meters (10 feet) from the Columbia Memorial Station toward the first rock target, seen in the foreground. The football-sized rock was dubbed Adirondack because of its mountain-shaped appearance. Scientists have begun using the microscopic imager instrument at the end of the rover's robotic arm to examine the rock and understand how it formed.

Diatom diversity in chronically versus episodically acidified adirondack streams

USGS Publications Warehouse

Passy, S.I.; Ciugulea, I.; Lawrence, G.B.

2006-01-01

The relationship between algal species richness and diversity, and pH is controversial. Furthermore, it is still unknown how episodic stream acidification following atmospheric deposition affects species richness and diversity. Here we analyzed water chemistry and diatom epiphyton dynamics and showed their contrasting behavior in chronically vs. episodically acidic streams in the Adirondack region. Species richness and diversity were significantly higher in the chronically acidic brown water stream, where organic acidity was significantly higher and the ratio of inorganic to organic monomeric aluminum significantly lower. Conversely, in the episodically acidic clear water stream, the inorganic acidity and pH were significantly higher and the diatom communities were very species-poor. This suggests that episodic acidification in the Adirondacks may be more stressful for stream biota than chronic acidity. Strong negative linear relationships between species diversity, Eunotia exigua, and dissolved organic carbon against pH were revealed after the influence of non-linear temporal trends was partialled out using a novel way of temporal modeling. ?? 2006 WILEY-VCH Verlag GmbH & Co. KGaA.

Evaluation of ERTS imagery for spectral geological mapping in diverse terranes of New York State

NASA Technical Reports Server (NTRS)

Isachsen, Y. W. (Principal Investigator); Rickard, L. V.

1972-01-01

The author has identified the following significant results. Preliminary visual examination of film positives of thirty ERTS-1 scenes obtained over New York State and adjacent areas indicates the following: (1) sixty percent of the imagery has a cloud cover of 70-100 percent, twenty-five percent has a cloud cover of 0-30 percent, and the remainder has a cover of 40-65 percent; (2) on the useable imagery, the spectral lines which may turn out to be geologically-linked totals as follows: spectral linears, 5200 km; broadly curved lines (spectral curvilinears), 700 km; major forest boundaries, 3100 km; areas with spectral geological fabric, 3100 sgkm. In the central and northwest Adirondacks, known lineaments and faults were subtracted from the spectral linears leaving a residue which totals 160 km in the central Adirondacks and 230 km in the northwest Adirondacks. It must be emphasized that these are spectral linears which have not yet been checked out against any ground truth except geological.

Fluid heterogeneity during granulite facies metamorphism in the Adirondacks: stable isotope evidence

USGS Publications Warehouse

Valley, J.W.; O'Neil, J.R.

1984-01-01

The preservation of premetamorphic, whole-rock oxygen isotope ratios in Adirondack metasediments shows that neither these rocks nor adjacent anorthosites and gneisses have been penetrated by large amounts of externally derived, hot CO2-H2O fluids during granulite facies metamorphism. This conclusion is supported by calculations of the effect of fluid volatilization and exchange and is also independently supported by petrologic and phase equilibria considerations. The data suggest that these rocks were not an open system during metamorphism; that fluid/rock ratios were in many instances between 0.0 and 0.1; that externally derived fluids, as well as fluids derived by metamorphic volatilization, rose along localized channels and were not pervasive; and thus that no single generalization can be applied to metamorphic fluid conditions in the Adirondacks. Analyses of 3 to 4 coexisting minerals from Adirondack marbles show that isotopic equilibrium was attained at the peak of granulite and upper amphibolite facies metamorphism. Thus the isotopic compositions of metamorphic fluids can be inferred from analyses of carbonates and fluid budgets can be constructed. Carbonates from the granulite facies are on average, isotopically similar to those from lower grade or unmetamorphosed limestones of the same age showing that no large isotopic shifts accompanied high grade metamorphism. Equilibrium calculations indicate that small decreases in ??18O, averaging 1 permil, result from volatilization reactions for Adirondack rock compositions. Additional small differences between amphibolite and granulite facies marbles are due to systematic lithologie differences. The range of Adirondack carbonate ??18O values (12.3 to 27.2) can be explained by the highly variable isotopic compositions of unmetamorphosed limestones in conjunction with minor 18O and 13C depletions caused by metamorphic volatilization suggesting that many (and possibly most) marbles have closely preserved their premetamorphic isotopic compositions. Such preservation is particularly evident in instances of high ??18O calcites (25.0 to 27.2), low ??18O wollastonites (-1.3 to 3.5), and sharp gradients in ??18O (18 permil/15m between marble and anorthosite, 8 permil/25 m in metasediments, and 6 permil/1 m in skarn). Isotopic exchange is seen across marble-anorthosite and marble-granite contacts only at the scale of a few meters. Small (<5 m) marble xenoliths are in approximate exchange equilibrium with their hosts, but for larger xenoliths and layers of marble there is no evidence of exchange at distances greater than 10 m from meta-igneous contacts. ?? 1984 Springer-Verlag.

Drainage basin control of acid loadings to two Adirondack lakes

NASA Astrophysics Data System (ADS)

Booty, W. G.; Depinto, J. V.; Scheffe, R. D.

1988-07-01

Two adjacent Adirondack Park (New York) calibrated watersheds (Woods Lake and Cranberry Pond), which receive identical atmospheric inputs, generate significantly different unit area of watershed loading rates of acidity to their respective lakes. A watershed acidification model is used to evaluate the watershed parameters which are responsible for the observed differences in acid loadings to the lakes. The greater overall mean depth of overburden on Woods Lake watershed, which supplies a greater buffer capacity as well as a longer retention time of groundwater, appears to be the major factor responsible for the differences.

Kyanite-bearing migmatites in the central Adirondack Mountains: Implications for late to post-orogenic metamorphism and melting in a collisional orogen

NASA Astrophysics Data System (ADS)

Reeder, J.; Metzger, E. P.; Bickford, M. E.; Leech, M. L.

2016-12-01

Sillimanite-rich felsic migmatites exposed at Ledge Mountain in the Central Adirondack Highlands (AH) represent the only location in the AH where kyanite is found. The texturally young kyanite is overprinted on sillimanite in largely undeformed pegmatitic leucosomes, suggesting a late episode of melting taking place deeper than previously thought, and requiring a counter-clockwise P-T path. A final phase of anatexis ca. 1050 Ma in the Eastern AH is consistent with an influx of fluid or decompression from extension in sillimanite-bearing migmatites. Temperatures both from this study and previous work are consistent with granulite-facies metamorphism; however, the presence of kyanite requires higher pressure conditions corresponding to deeper burial of rocks exposed in the central Adirondacks. The Adirondacks are associated with the Grenville Province of eastern North America, that formed during four orogenic events. The most recent (Grenville) orogeny consisted of two stages: crustal thickening and granulite facies metamorphism during the Ottawan phase (ca 1090-1020) then metamorphism and melting in the kyanite field during the much shorter Rigolet pulse (ca 1005-980 Ma). Preliminary U-Pb SHRIMP zircon ages from Ledge Mountain kyanite-bearing migmatites suggest that melting in the Central AH persisted into the Rigolet phase. On the basis of mineral composition and chemistry and the presence of distinctive quartz-sillimanite nodules, the Ledge Mountain migmatites closely resemble the K-rich phase of the Ottawan-age Lyon Mountain granite (LMG) and may represent LMG that was metamorphosed to sillimanite grade and then overprinted by a higher pressure, lower temperature assemblage. Kyanite-bearing felsic anatectites of Rigolet age have previously been observed only in the western portion of the Grenville Province. Documentation of a counterclockwise P-T path and post-Ottawan melting in the Ledge Mountain migmatites requires re-evaluation of current tectonic models for the Grenville Province and its Adirondacks outlier. Further analysis of age, geochemical, and petrographic data will help develop a better-defined P-T-t path and may lead to the development of a new tectonic model to be compared with other collisional orogens such as Himalaya or the Bohemian Massif of the Variscan orogenic belt.

PIXE Analysis of Atmospheric Aerosol Samples Collected in the Adirondack Mountains

NASA Astrophysics Data System (ADS)

Yoskowitz, Josh; Ali, Salina; Nadareski, Benjamin; Safiq, Alexandrea; Smith, Jeremy; Labrake, Scott; Vineyard, Michael

2013-10-01

We have performed an elemental analysis of atmospheric aerosol samples collected at Piseco Lake in Upstate New York using proton induced x-ray emission spectroscopy (PIXE). This work is part of a systematic study of airborne pollution in the Adirondack Mountains. Of particular interest is the sulfur content that can contribute to acid rain, a well-documented problem in the Adirondacks. We used a nine-stage cascade impactor to collect the samples and distribute the particulate matter onto Kapton foils by particle size. The PIXE experiments were performed with 2.2-MeV proton beams from the 1.1-MV pelletron accelerator in the Union College Ion-Beam Analysis Laboratory. X-Ray energy spectra were measured with a silicon drift detector and analyzed with GUPIX software to determine the elemental concentrations of the aerosols. A broad range of elements from silicon to zinc were detected with significant sulfur concentrations measured for particulate matter between 0.25 and 0.5 μm in size. The PIXE analysis will be described and preliminary results will be presented.

Assessing Brook Trout populations in headwater streams of the Adirondack Mountains using environmental DNA -- Summary report

USGS Publications Warehouse

Baldigo, Barry P.; George, Scott D.; Sporn, Lee Ann; Ball, Jacob

2016-01-01

This project evaluated standard fish-survey and environmental DNA (eDNA) sampling methods to determine the ability of eDNA to accurately predict the presence and abundance of resident Brook Trout populations in 40 headwater streams mainly in the western Adirondack Mountains during 2014–2015 (Figure 2). Standard 3-pass electrofishing surveys found that Brook Trout were absent from about 25 percent of study sites, and at low densities in 25 percent of sites, moderate densities in 25 percent of sites, and high densities in 25 percent of sites. Environmental DNA results correctly predicted the presence/absence of Brook Trout in 85.0 to 92.5 percent of study sites and explained 44.0 percent of the variability in density and 24 percent of the variability in biomass of their populations. The findings indicate that eDNA surveys will enable researchers to effectively characterize the presence as well as the abundance of Brook Trout and other species populations in headwater streams across the Adirondack Mountains and elsewhere.

Changes in the chemistry of acidified Adirondack streams from the early 1980s to 2008

USGS Publications Warehouse

Lawrence, G.B.; Simonin, H.A.; Baldigo, Barry P.; Roy, K.M.; Capone, S.B.

2011-01-01

Lakes in the Adirondack region of New York have partially recovered in response to declining deposition, but information on stream recovery is limited. Here we report results of Adirondack stream monitoring from the early 1980s to 2008. Despite a 50% reduction in atmospheric deposition of sulfur, overall increases in pH of only 0.28 and ANC of 13 μeq L-1 were observed in 12 streams over 23 years, although greater changes did occur in streams with lower initial ANC, as expected. In the North Tributary of Buck Creek with high dissolved organic carbon (DOC) concentrations, SO(4)(2-) concentrations decreased from 1999 to 2008 at a rate of 2.0 μmol L-1 y-1, whereas in the neighboring South Tributary with low DOC concentrations, the decrease was only 0.73 μmol L-1 y-1. Ca2+ leaching decreased in the North Tributary due to the SO(4)(2-) decrease, but this was partially offset by an increase in Ca2+ leaching from increased DOC concentrations.

Mercury contribution to an Adirondack lake

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scrudato, R.J.; Long, D.; Weinbloom, R.

1987-01-01

Elevated copper, lead, and zinc concentrations in the upper 10 to 20 cm of sediment sampled from Cranberry Lake, a large Adirondack lake, are attributed to atmospheric contributions. Pb-210 and pollen core data, however, suggest Cranberry Lake also received mercury discharges during the turn of the century when the area was the center of extensive lumbering and related activities. Elevated mercury concentrations in Cranberry Lake smallmouth bass derived from remobilization from mercury-contaminated bottom sediments which increased the bioavailability to Cranberry Lake organisms. Mercury remobilization and accumulation by fish are promoted by fluctuating pH values resulting from acid precipitation.

Mercury contribution to an adirondack lake

NASA Astrophysics Data System (ADS)

Scrudato, R. J.; Long, D.; Weinbloom, Robert

1987-10-01

Elevated copper, lead, and zinc concentrations in the upper 10 to 20 cm of sediment sampled from Cranberry Lake, a large Adirondack lake, are attributed to atmospheric contributions. Pb-210 and pollen core data, however, suggest Cranberry Lake also received mercury discharges during the turn of the century when the area was the center of extensive lumbering and related activities. Elevated mercury concentrations in Cranberry Lake smallmouth bass derived from remobilization from mercury-contaminated bottom sediments which increased the bioavailability to Cranberry Lake organisms. Mercury remobilization and accumulation by fish are promoted by fluctuating pH values resulting from acid precipilation.

Alteration Mineralogy of Adirondack-class Rocks in Gusev Crater, Mars

NASA Astrophysics Data System (ADS)

Hamilton, V. E.; Ruff, S. W.

2009-12-01

The rock Adirondack is the type example of a class of basaltic rocks analyzed by the Mars Exploration Rover Spirit in Gusev crater. Thermal infrared spectra of Adirondack-class rocks acquired by the Mini-TES instrument are distinguishable from spectra of other rock classes by the presence of an emissivity peak at 430 cm-1 and a minimum near 510 cm-1, which are characteristic of olivine. This is the primary spectral class on the plains of Gusev, but spectra of rocks exhibiting similar low wavenumber spectral character have been acquired along the rover traverse in the Columbia Hills, and we have confirmed that these also are Adirondack-class. Linear mixture modeling of their infrared spectra (enabled by applying a correction for dust on the Mini-TES optics) suggests that they are mafic with sulfate minerals present as alteration phases (up to 25%) in the majority of these rocks, broadly consistent with APXS-measured chemistry. The RAT-brushed surface of an unusual plains rock referred to as Mazatzal exhibits a spectral shape and modeled mineralogy consistent with the absence of olivine and the presence of amorphous phases low in silica, and is a coating unlike any other observed on Mars. We have also used a previously-demonstrated factor analysis and target transformation (FATT) technique with Adirondack-class rock spectra to retrieve the spectral shapes of independently-varying components within the data set. Using this approach, we have identified four shapes attributable to two distinct surface components, fine particulate surface dust, and a second dust component similar to downwelling sky radiance and/or dust on the Mini-TES optics. The two surface shapes do not resemble those of the two canonical surface types measured from orbit. One of the surface shapes is very similar to that of the lherzolitic Shergottite ALH A77005. Preliminary linear mixture analysis of this shape shows that it is dominated by olivine (~57%, ~Fo45) and pyroxene (~28%), with minor amounts of oxides and basaltic glass (~15%). This ultramafic composition is similar to that derived from linear mixture modeling of the measured Mini-TES spectra, but differs in detail from the APXS-derived normative mineralogy and Mössbauer ol:px. These differences may be artifacts of the penetration depths and spot sizes of the measurements, or assumptions inherent in the conversions from chemistry and spectra to norms and abundances; work in progress is aimed at explaining these differences. The other shape is modeled with high-silica phases (29%), sulfates (~24%), olivine (~19%), pyroxene (~15%), and oxides (~12%), suggesting it represents a highly altered mineralogy. We linearly modeled the highest-quality measured spectra of Adirondack-class rocks using only the FATT-derived spectral shapes. Surface components are modeled by varying proportions of the two surface shapes, with all containing ≥40% of the ultramafic shape. These preliminary results suggest that Adirondack-class rocks are a single lithology exhibiting sulfate-bearing surface alteration that is variable from rock to rock. We are in the process of converting the mineralogies derived from measured and FATT-derived spectra into bulk oxides and will present quantitative comparisons with APXS data and qualitative comparisons with Mössbauer data.

Chronic and episodic acidification of Adirondack streams from acid rain in 2003-2005

USGS Publications Warehouse

Lawrence, G.B.; Roy, K.M.; Baldigo, Barry P.; Simonin, H.A.; Capone, S.B.; Sutherland, J.W.; Nierzwicki-Bauer, S. A.; Boylen, C.W.

2008-01-01

Limited information is available on streams in the Adirondack region of New York, although streams are more prone to acidification than the more studied Adirondack lakes. A stream assessment was therefore undertaken in the Oswegatchie and Black River drainages; an area of 4585 km2 in the western part of the Adirondack region. Acidification was evaluated with the newly developed base-cation surplus (BCS) and the conventional acid-neutralizing capacity by Gran titration (ANCG). During the survey when stream water was most acidic (March 2004), 105 of 188 streams (56%) were acidified based on the criterion of BCS < 0 ??eq L-1, whereas 29% were acidified based on an ANCG value < 0 ??eq L-1. During the survey when stream water was least acidic (August 2003), 15 of 129 streams (12%) were acidified based on the criterion of BCS < 0 ??eq L-1, whereas 5% were acidified based on ANCG value < 0 ??eq L -1. The contribution of acidic deposition to stream acidification was greater than that of strongly acidic organic acids in each of the surveys by factors ranging from approximately 2 to 5, but was greatest during spring snowmelt and least during elevated base flow in August. During snowmelt, the percentage attributable to acidic deposition was 81%, whereas during the October 2003 survey, when dissolved organic carbon (DOC) concentrations were highest, this percentage was 66%. The total length of stream reaches estimated to be prone to acidification was 718 km out of a total of 1237 km of stream reaches that were assessed. Copyright ?? 2008 by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America. All rights reserved.

Age and petrogenesis of the Diana Complex, Adirondack Mountains, New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grant, N.; Yang, Yingping; Cliff, R.

1992-01-01

U-Pb zircon data show that the Diana Complex was emplaced 1152[plus minus]12 Ma ago along the Carthage-Colton Mylonite Zone (CCMZ), that marks the boundary between the Adirondack Highlands and the Lowlands. The tectonic setting of the Complex is uncertain because granitoid plutons of the same age were emplaced under syntectonic conditions in the Lowlands, while in the Highlands the same plutons have been viewed as anorogenic. Deformation focused on the CCMZ is reflected in whole-rock Rb-Sr isochron age of 1038[plus minus]97 Ma for the Complex. This resetting is typical of granitoid plutons within a 10 km-wide zone across the CCMZ,more » but is absent outside this zone elsewhere in the Lowlands. Although the chemical continuity of the Complex with Adirondack mafic rocks of the same presumed age demonstrates that crystal fractionation from a basic parent was a likely origin for the Complex, it is probable the magmas were modified by crustal assimilation. For example, the initial [sup 87]Sr/[sup 86]Sr[sub 1152] values for the Complex (0.7042[plus minus]3) are higher than the same ratios for Adirondack mafic rocks (0.7033[plus minus]6), and one zircon fraction lies to the right of the discordia defined by the other four analyzed fractions. The nature and age of the assimilant may be constrained by a metasedimentary xenolith with a whole-rock Rb-Sr isochron age of 1318[plus minus]15 Ma. Changes in TiO[sub 2] and P[sub 2]O[sub 5] abundances and La/Yb values indicate that the crystallization of both accessory (e.g., Fe-Ti oxides, apatite and zircon) and silicate phases were important in the fractionation of the Diana Complex syenites.« less

Calcium Sulfate in Atacama Desert Basalt: A Possible Analog for Bright Material in Adirondack Basalt, Gusev Crater

NASA Technical Reports Server (NTRS)

Sutter, B.; Golden, D. C.; Amundson, R.; Chong-Diaz, G.; Ming, D. W.

2007-01-01

The Atacama Desert in northern Chile is one of the driest deserts on Earth (< 2mm/y). The hyper-arid conditions allow extraordinary accumulations of sulfates, chlorides, and nitrates in Atacama soils. Examining salt accumulations in the Atacama may assist understanding salt accumulations on Mars. Recent work examining sulfate soils on basalt parent material observed white material in the interior vesicles of surface basalt. This is strikingly similar to the bright-white material present in veins and vesicles of the Adirondack basalt rocks at Gusev Crater which are presumed to consist of S, Cl, and/or Br. The abundance of soil gypsum/anhydrite in the area of the Atacama basalt suggested that the white material consisted of calcium sulfate (Ca-SO4) which was later confirmed by SEM/EDS analysis. This work examines the Ca-SO4 of Atacama basalt in an effort to provide insight into the possible nature of the bright material in the Adirondack basalt of Gusev Crater. The objectives of this work are to (i) discuss variations in Ca-SO4 crystal morphology in the vesicles and (ii) examine the Ca-SO4 interaction(s) with the basalt interior.

To evaluate ERTS-1 data for usefulness as a geological sensor in the diverse geological terranes of New York State

NASA Technical Reports Server (NTRS)

Isachsen, Y. W. (Principal Investigator)

1972-01-01

The author has identified the following significant results. In the present imagery, obtained during the full foliage of summer and fall, the greatest amount of spectral geology is displayed in the Adirondack region where bedrock geology is strongly linked to topography. Of the four spectral bands imaged, band 5 and 7 provide the most geological information. The boundary between the basement rocks of the Adirondack Dome and the surrounding Lower Paleozoic rocks is well delineated except in the Northwest Lowlands and along parts of the eastern Adirondacks. Within the basement complex, the most prominently displayed features are numerous north-northeast trending faults and topographic lineaments, and arcuate east-west valleys developed in some of the weaker metasedimentary rocks. The majority of the faults and lineaments shown on the geologic map of New York appear in the ERTS-1 imagery. In addition, many new linears were detected, as well as a number of anomalous curvilinear elements, some circular in plan and measuring up to 25 km in diameter, which do not bear any clear relationship to mapped geological contacts. The possibility that it is an astrobleme will be investigated after snow melts in the spring.

Long-term trends in breeding birds in an old-growth Adirondack forest and the surrounding region

USGS Publications Warehouse

McNulty, S.A.; Droege, S.; Masters, R.D.

2008-01-01

Breeding bird populations were sampled between 1954 and 1963, and 1990 and 2000 in an old-growth forest, the Natural Area of Huntington Wildlife Forest (HWF), in the Adirondack Mountains of New York. Trends were compared with data from regional North American Breeding Bird Surveys (BBS) and from a forest plot at Hubbard Brook Experimental Forest, New Hampshire. Trends for 22 species in the HWF Natural Area were negative, eight were positive, and one was zero; 20 were significant. Fifteen of 17 long-distance migrants declined, whereas 7 of 14 short-distance migrants and permanent residents declined. Most (74%) HWF Natural Area species, despite differences in sampling periods and local habitat features, matched in sign of trend when compared to Adirondack BBS routes, 61% matched northeastern BBS routes, and 71% matched eastern United States BBS routes, while 66% matched Hubbard Brook species. The agreement in population trends suggests that forest interior birds, especially long-distance migrants, are affected more by regional than local factors. The analysis indicated that bird trends generated from BBS routes may not be as biased toward roads as previously suggested.

PIXE Analysis of Aerosol and Soil Samples Collected in the Adirondack Mountains

NASA Astrophysics Data System (ADS)

Yoskowitz, Joshua; Ali, Salina; Nadareski, Benjamin; Labrake, Scott; Vineyard, Michael

2014-09-01

We have performed an elemental analysis of aerosol and soil samples collected at Piseco Lake in Upstate New York using proton induced X-ray emission spectroscopy (PIXE). This work is part of a systematic study of airborne pollution in the Adirondack Mountains. Of particular interest is the sulfur content that can contribute to acid rain, a well-documented problem in the Adirondacks. We used a nine-stage cascade impactor to collect the aerosol samples near Piseco Lake and distribute the particulate matter onto Kapton foils by particle size. The soil samples were also collected at Piseco Lake and pressed into cylindrical pellets for experimentation. PIXE analysis of the aerosol and soil samples were performed with 2.2-MeV proton beams from the 1.1-MV Pelletron accelerator in the Union College Ion-Beam Analysis Laboratory. There are higher concentrations of sulfur at smaller particle sizes (0.25-1 μm), suggesting that it could be suspended in the air for days and originate from sources very far away. Other elements with significant concentrations peak at larger particle sizes (1-4 μm) and are found in the soil samples, suggesting that these elements could originate in the soil. The PIXE analysis will be described and the resulting data will be presented.

Responses of 20 lake-watersheds in the Adirondack region of New York to historical and potential future acidic deposition.

PubMed

Zhou, Qingtao; Driscoll, Charles T; Sullivan, Timothy J

2015-04-01

Critical loads (CLs) and dynamic critical loads (DCLs) are important tools to guide the protection of ecosystems from air pollution. In order to quantify decreases in acidic deposition necessary to protect sensitive aquatic species, we calculated CLs and DCLs of sulfate (SO4(2-))+nitrate (NO3-) for 20 lake-watersheds from the Adirondack region of New York using the dynamic model, PnET-BGC. We evaluated lake water chemistry and fish and total zooplankton species richness in response to historical acidic deposition and under future deposition scenarios. The model performed well in simulating measured chemistry of Adirondack lakes. Current deposition of SO4(2-)+NO3-, calcium (Ca2+) weathering rate and lake acid neutralizing capacity (ANC) in 1850 were related to the extent of historical acidification (1850-2008). Changes in lake Al3+ concentrations since the onset of acidic deposition were also related to Ca2+ weathering rate and ANC in 1850. Lake ANC and fish and total zooplankton species richness were projected to increase under hypothetical decreases in future deposition. However, model projections suggest that lake ecosystems will not achieve complete chemical and biological recovery in the future. Copyright © 2014. Published by Elsevier B.V.

The origin of garnet in the anorthosite-charnockite suite of the Adirondacks

USGS Publications Warehouse

McLelland, J.M.; Whitney, P.R.

1977-01-01

Detailed analysis of textural and chemical criteria in rocks of the anorthosite-charnockite suite of the Adirondack Highlands suggests that development of garnet in silica-saturated rocks of the suite occurs according to the reaction: {Mathematical expression}, where ?? is a function of the distribution of Fe and Mg between the several coexisting ferromagnesian phases. Depending upon the relative amounts of Fe and Mg present, quartz may be either a reactant or a product. Using an aluminum-fixed reference frame, this reaction can be restated in terms of a set of balanced partial reactions describing the processes occurring in spatially separated domains within the rock. The fact that garnet invariably replaces plagioclase as opposed to the other reactant phases indicates that the aluminum-fixed model is valid as a first approximation. This reaction is univariant and produces unzoned garnet. It differs from a similar equation proposed by de Waard (1965) for the origin of garnet in Adirondack metabasic rocks, i.e. 6 Orthopyroxene+2 Anorthite = Clinopyroxene+Garnet+2 Quartz, the principle difference being that iron oxides (ilmenite and/or magnetite) are essential reactant phases in the present reactions. The product assemblage (garnet+clinopyroxene+plagioclase ?? orthopyroxene ?? quartz) is characteristic of the clinopyroxene-almandine subfacies of the granulite facies. ?? 1977 Springer-Verlag.

A preliminary synthesis of structural, stratigraphic, and magnetic data from part of the northwest Adirondacks, New York

USGS Publications Warehouse

Foose, M.P.; Brown, C. Ervin

1976-01-01

Synthesis of recent work in the NW Adirondacks, New York allows the development of a coherent geologic picture. Mapping of the Precambrian rock units enables the recognition of four major units which are, from bottom to top, 1) Granitic Gneiss (alaskite), 2) Lower Marble, 3) Major Gneiss, and 4) Upper Marble. Additionally, lenses of amphibolite and granite occur as intrusives within this succession. These rock units have been complexly deformed by three major folding episodes, and by two distinctly different styles of faulting. The result has been to produce large northeast-southwest trending dome and basin structures. Patterns of magnetic intensity closely parallel distribution of rock units and provide additional information for a structural and stratigraphic synthesis-.

Interpretation of gravity anomalies in the northwest Adirondack lowlands, northern New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Revetta, F.A.; O'Brian, B.

1993-03-01

Twelve hundred gravity measurements were made in the Adirondack Highlands and northwest Adirondack Lowlands, New York between 44[degree]15 minutes and 44[degree]30 minutes N. Latitude and 75[degree]00 minutes W. Longitude. A Bouguer gravity map constructed from the gravity measurements includes the Carthage-Colton Mylonite Zone, a major structural boundary between the highlands and lowlands. The gravity map indicates the gravity contours trend parallel to the CCMZ along most of its length however in some areas the contours cross the boundary. No clear-cut relationships exists between the CCMZ and gravity contours. The Bouguer gravity map shows several prominent gravity anomalies which correlate withmore » the geology seismicity and mineral deposits in the area. Gravity lows of 20 to 30 g.u. are centered over the Gouverneur, Hyde and Payne Lake Alaskite gneiss bodies. A gravity high of 20 g.u. occurs over the Pleasant Lake gabbro pluton. Gravity highs of 35 and 100 g.u. occur over the Sylvia Lake Zinc District and marble just north of the district. A gravity high at Russell, N.Y. coincides with a cluster of nine earthquake epicenters. Finally a steep gravity gradient separates high density rocks from lower density rocks along the Black Lake fault. Two-dimensional computer modeling of the geologic features is underway and quantitative models of the structures will be presented.« less

American Fisheries Society 136th Annual Meeting Lake Placid, NY 10-14 September, 2006

USGS Publications Warehouse

Einhouse, D.; Walsh, M.G.; Keeler, S.; Long, J.M.

2005-01-01

The New York Chapter of the American Fisheries Society and the New York State Department of Environmental Conservation invite you to experience the beauty of New York's famous Adirondack Park as the American Fisheries Society (AFS) convenes its 136th Annual Meeting in the legendary Olympic Village of Lake Placid, NY, 10-14 September 2006. Our meeting theme "Fish in the Balance" will explore the interrelation between fish, aquatic habitats, and man, highlighting the challenges facing aquatic resource professionals and the methods that have been employed to resolve conflicts between those that use or have an interest in our aquatic resources. As fragile as it is beautiful, the Adirondack Region is the perfect location to explore this theme. Bordered by Mirror Lake and its namesake, Lake Placid, the Village of Lake Placid has small town charm, but all of the conveniences that a big city would provide. Whether its reliving the magic of the 1980 hockey team's "Miracle on Ice" at the Lake Placid Olympic Center, getting a panoramic view of the Adirondack high peaks from the top of the 90 meter ski jumps, fishing or kayaking in adjacent Mirror Lake, hiking a mountain trail, or enjoying a quiet dinner or shopping excursion in the various shops and restaurants that line Main Street, Lake Placid has something for everyone.

Sustainability and economics: The Adirondack Park experience, a forest economic-ecological model, and solar energy policy

NASA Astrophysics Data System (ADS)

Erickson, Jon David

The long-term sustainability of human communities will depend on our relationship with regional environments, our maintenance of renewable resources, and our successful disengagement from nonrenewable energy dependence. This dissertation investigates sustainability at these three levels, following a critical analysis of sustainability and economics. At the regional environment level, the Adirondack Park of New York State is analyzed as a potential model of sustainable development. A set of initial and ongoing conditions are presented that both emerge from and support a model of sustainability in the Adirondacks. From these conditions, a clearer picture emerges of the definition of regional sustainability, consequences of its adoption, and lessons from its application. Next, an economic-ecological model of the northern hardwood forest ecosystem is developed. The model integrates economic theory and intertemporal ecological concepts, linking current harvest decisions with future forest growth, financial value, and ecosystem stability. The results indicate very different economic and ecological outcomes by varying opportunity cost and ecosystem recovery assumptions, and suggest a positive benefit to ecological recovery in the forest rotation decision of the profit maximizing manager. The last section investigates the motives, economics, and international development implications of renewable energy (specifically photovoltaic technology) in rural electrification and technology transfer, drawing on research in the Dominican Republic. The implications of subsidizing a photovoltaic market versus investing in basic research are explored.

Simulation of growth of Adirondack conifers in relation to global climate change

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, Y.; Raynal, D.J.

1993-06-01

Several conifer species grown in plantations in the southeastern Adirondack mountains of New York were chosen to model tree growth. In the models, annual xylem growth was decomposed into several components that reflect various intrinsic or extrinsic factors. Growth signals indicative of climatic effects were used to construct response functions using both multivariate analysis and Kalman filter methods. Two models were used to simulate tree growth response to future CO[sub 2]-induced climate change projected by GCMs. The comparable results of both models indicate that different conifer species have individualistic growth responses to future climatic change. The response behaviors of treesmore » are affected greatly by local stand conditions. The results suggest possible changes in future growth and distributions of naturally occurring conifers in this region.« less

Origin of coronas in metagabbros of the Adirondack mts., N. Y

USGS Publications Warehouse

Whitney, P.R.; McLelland, J.M.

1973-01-01

Metagabbros from two widely separated areas in the Adirondacks show development of coronas. In the Southern Adirondacks, these are cored by olivine which is enclosed in a shell of orthopyroxene that is partially, or completely, rimmed by symplectites consisting of clinopyroxene and spinel. Compositions of the corona phases have been determined by electron probe and are consistent with a mechanism involving three partial reactions, thus: (a) Olivine=Orthopyroxene+(Mg, Fe)++. (b) Plagioclase+(Mg, Fe)+++Ca++=Clinopyroxene+Spinel+Na+. (c) Plagioclase+(Mg, Fe)+++Na+=Spinel+more sodic plagioclase+Ca++. Reaction (a) occurs in the inner shell of the corona adjacent to olivine; reaction (b) in the outer shell; and (c) in the surrounding plagioclase, giving rise to the spinel clouding which is characteristic of the plagioclase in these rocks. Alumina and silica remain relatively immobile. These reactions, when balanced, can be generalized to account for the aluminous nature of the pyroxenes and for changing plagioclase composition. Summed together, the partial reactions are equivalent to: (d) Olivine + Anorthite = Aluminous orthopyroxene + Aluminous Clinopyroxene + Spinel (Kushiro and Yoder, 1966). In the Adirondack Highlands, coronas between olivine and plagioclase commonly have an outer shell of garnet replacing the clinopyroxene/spinel shell. The origin of the garnet can also be explained in terms of three partial reactions: (e) Orthopyroxene+Ca++=Clinopyroxene+(Mg, Fe)++. (f) Clinopyroxene+Spinel+Plagioclase+(Mg, Fe)++=Garnet+Ca+++Na+. (g) Plagioclase+(Mg, Fe)+++Na+=Spinel + more sodic plagioclase+Ca++. These occur in the inner and outer corona shell and the surrounding plagioclase, respectively, and involve the products of reactions (a)-(d). Alumina and silica are again relatively immobile. Balanced, and generalized to account for aluminous pyroxenes and variable An content of plagioclase, they are equivalent to: (h) Orthopyroxene+Anorthite+Spinel=Garnet (Green and Ringwood, 1967). Amphibole coronas about opaque oxides in rocks of both areas are the result of oxide/plagioclase reactions with addition of magnesium from coexisting olivine. Based on published experimental data, pressure and temperature at the time of corona formation were on the order of 8 kb and 800?? C for the garnet bearing coronas, with somewhat lower pressures indicated for the clinopyroxene/spinel coronas. ?? 1973 Springer-Verlag.

Kyanite-Bearing Migmatites at Ledge Mountain, Adirondack Highlands

NASA Astrophysics Data System (ADS)

Swanson, B.; Leech, M.; Metzger, E. P.

2017-12-01

Sillimanite-rich felsic migmatites exposed at Ledge Mountain represent the only location in the Adirondack Highlands where kyanite has been found. The texturally young kyanite is overprinted on sillimanite in largely undeformed pegmatitic leucosomes, suggesting a late episode of melting taking place deeper than previously thought, and requiring a counter-clockwise P-T path. A final phase of anatexis ca. 1050 Ma in the Eastern Adirondack Highlands is consistent with an influx of fluid or decompression from extension in sillimanite-bearing migmatites. Temperatures both from this study and previous work are consistent with granulite-facies metamorphism, however the presence of kyanite requires higher pressure conditions corresponding to deeper burial of these central Adirondack rocks. We used Perple_X to model phase equilibria using XRF+ICP-MS whole-rock chemistries for the kyanite-bearing migmatites. Pseudosection models suggest that the peak P-T mineral assemblage kyanite + mesoperthite + garnet + rutile formed at approximately 15-20kb and 1000°C which is higher than previously proposed for granulites in the region. These P-T conditions for peak metamorphism are similar to those reported for the distinctive and relatively rare assemblage that we observe kyanite + hypersolvus feldspar (now mesoperthite) + garnet + rutile. We have evidence of isothermal decompression to <11kb and 880°-1000°C based on Grt + Pl equilibrium in the assemblage Grt + Pl ± Kfs + Qz + Ilm + melt. The leucocratic melt phase comprises 16 vol. % of the rock at these P-T conditions which is sufficient for ductile flow in the deep crust. This melt phase is present syn-exhumation and helped to buoyantly exhume Ledge Moutain rocks beneath bounding normal faults as a granitic gneiss dome. Preliminary U-Pb SHRIMP zircon ages from Ledge Mountain kyanite-bearing migmatites show anatexis continuing well after high-grade metamorphism is believed to have ceased in the range. A counter-clockwise P-T path is consistent with the mechanisms in the current model, and this study indicates anatectic melting persisted into the Rigolet phase. The Ledge Mountain migmatite may represent the Hawkeye granite and/or Lyon Mountain Gneiss that were metamorphosed to sillimanite grade and then overprinted by a higher pressure, lower temperature assemblage.

3. INTERIOR VIEW SHOWING SLEEPING BUNKS AT ONE END AND ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

3. INTERIOR VIEW SHOWING SLEEPING BUNKS AT ONE END AND STORAGE LOCKER AT RIGHT - Camp Cleawox, Adirondack Sleeping Shelter, Oregon Dunes National Recreation Area, Siuslaw National Forest, Florence, Lane County, OR

Northeastern Exterior, Northwestern Exterior, & Southwestern Exterior Elevations, Northeastern Interior, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

Northeastern Exterior, Northwestern Exterior, & Southwestern Exterior Elevations, Northeastern Interior, Southeastern Interior, & Southwestern Interior Elevations, Floor Plan, and Eastern Corner Detail - Manatoc Reservation, Vale Edge Adirondack, 1075 Truxell Road, Peninsula, Summit County, OH

Identifying Common Patterns in Diverse Systems: Effects of Exurban Development on Birds of the Adirondack Park and the Greater Yellowstone Ecosystem, USA

NASA Astrophysics Data System (ADS)

Glennon, Michale J.; Kretser, Heidi E.; Hilty, Jodi A.

2015-02-01

We examined the impacts of exurban development on bird communities in Essex County, New York and Madison County, Montana by comparing differences in abundance of songbirds between subdivisions and control sites in both regions. We hypothesized that impacts to bird communities would be greater in the relatively homogeneous, closed canopy Adirondack forest of northern New York State than they would be in the more naturally heterogeneous grasslands interspersed with trees and shrubs of the Greater Yellowstone Ecosystem. We examined birds in five functional groups expected to be responsive to exurban development, and determined relative abundance within subdivisions and control sites across these two distinct regions. We found little support for our hypothesis. For birds in the area-sensitive, low nesting, and Neotropical migrant functional groups, relative abundance was lower in subdivisions in the Adirondacks and in Madison County, while relative abundance of edge specialists was greater in subdivisions in both regions. The direction and magnitude of change in the avian communities between subdivisions and controls was similar in both regions for all guilds except microhabitat specialists. These similarities across diverse ecosystems suggest that the ecological context of the encompassing region may be less important than other elements in shaping avian communities in exurban systems. This finding suggests that humans and their specific behaviors and activities in exurban areas may be underappreciated but potentially important drivers of change in these regions.

Use of stream chemistry for monitoring acidic deposition effects in the Adirondack region of New York

USGS Publications Warehouse

Lawrence, G.B.; Momen, B.; Roy, K.M.

2004-01-01

Acid-neutralizing capacity (ANC) and pH were measured weekly from October 1991 through September 2001 in three streams in the western Adirondack Mountain region of New York to identify trends in stream chemistry that might be related to changes in acidic deposition. A decreasing trend in atmospheric deposition of SO42- was observed within the region over the 10-yr period, although most of the decrease occurred between 1991 and 1995. Both ANC and pH were inversely related to flow in all streams; therefore, a trend analysis was conducted on (i) the measured values of ANC and pH and (ii) the residuals of the concentration-discharge relations. In Buck Creek, ANC increased significantly (p 0.10). In Bald Mountain Brook, ANC and residuals of ANC increased significantly (p < 0.01), although the trend was diatonic-a distinct decrease from 1991 to 1996 was followed by a distinct increase from 1996 to 2001. In Fly Pond outlet, ANC and residuals of ANC increased over the study period (p < 0.01), although the trend of the residuals resulted largely from an abrupt increase in 1997. In general, the trends observed in the three streams are similar to results presented for Adirondack lakes in a previous study, and are consistent with the declining trend in atmospheric deposition for this region, although the observed trends in ANC and pH in streams could not be directly attributed to the trends in acidic deposition.

Efficacy of environmental DNA to detect and quantify Brook Trout populations in headwater streams of the Adirondack Mountains, New York

USGS Publications Warehouse

Baldigo, Barry P.; Sporn, Lee Ann; George, Scott D.; Ball, Jacob

2016-01-01

Environmental DNA (eDNA) analysis is rapidly evolving as a tool for monitoring the distributions of aquatic species. Detection of species’ populations in streams may be challenging because the persistence time for intact DNA fragments is unknown and because eDNA is diluted and dispersed by dynamic hydrological processes. During 2015, the DNA of Brook Trout Salvelinus fontinalis was analyzed from water samples collected at 40 streams across the Adirondack region of upstate New York, where Brook Trout populations were recently quantified. Study objectives were to evaluate different sampling methods and the ability of eDNA to accurately predict the presence and abundance of resident Brook Trout populations. Results from three-pass electrofishing surveys indicated that Brook Trout were absent from 10 sites and were present in low (<100 fish/0.1 ha), moderate (100–300 fish/0.1 ha), and high (>300 fish/0.1 ha) densities at 9, 11, and 10 sites, respectively. The eDNA results correctly predicted the presence and confirmed the absence of Brook Trout at 85.0–92.5% of the study sites; eDNA also explained 44% of the variability in Brook Trout population density and 24% of the variability in biomass. These findings indicate that eDNA surveys will enable researchers to effectively characterize the presence and abundance of Brook Trout and other species’ populations in headwater streams across the Adirondack region and elsewhere.

Using Satellite Imagery to Assess Large-Scale Habitat Characteristics of Adirondack Park, New York, USA

NASA Astrophysics Data System (ADS)

McClain, Bobbi J.; Porter, William F.

2000-11-01

Satellite imagery is a useful tool for large-scale habitat analysis; however, its limitations need to be tested. We tested these limitations by varying the methods of a habitat evaluation for white-tailed deer ( Odocoileus virginianus) in the Adirondack Park, New York, USA, utilizing harvest data to create and validate the assessment models. We used two classified images, one with a large minimum mapping unit but high accuracy and one with no minimum mapping unit but slightly lower accuracy, to test the sensitivity of the evaluation to these differences. We tested the utility of two methods of assessment, habitat suitability index modeling, and pattern recognition modeling. We varied the scale at which the models were applied by using five separate sizes of analysis windows. Results showed that the presence of a large minimum mapping unit eliminates important details of the habitat. Window size is relatively unimportant if the data are averaged to a large resolution (i.e., township), but if the data are used at the smaller resolution, then the window size is an important consideration. In the Adirondacks, the proportion of hardwood and softwood in an area is most important to the spatial dynamics of deer populations. The low occurrence of open area in all parts of the park either limits the effect of this cover type on the population or limits our ability to detect the effect. The arrangement and interspersion of cover types were not significant to deer populations.

Woodland Detection.

ERIC Educational Resources Information Center

Fischer, Richard B.

1989-01-01

Presents tips on nature observation during a woodland hike in the Adirondacks. Discusses engraver beetles and Dutch elm disease, birds' nests, hornets' nests, caterpillar webs, deer and bear signs, woodpecker holes, red squirrels, porcupine and beaver signs, and galls. (SV)

Oxygen isotope geospeedometry by SIMS

NASA Astrophysics Data System (ADS)

Bonamici, C. E.; Valley, J. W.

2013-12-01

Geospeedometry, a discipline closely related and complimentary to thermochronology, exploits the phenomenon of diffusion in order to extract rate and duration information for segments of a rock's thermal history. Geospeedometry data, when anchored in absolute time by geochronologic data, allow for the construction of detailed temperature-time paths for specific terranes and geologic processes. We highlight the developing field of SIMS-based oxygen isotope geospeedometry with an application from granulites of the Adirondack Mountains (New York) and discuss potential future applications based on a recently updated and expanded modeling tool, the Fast Grain Boundary diffusion program (FGB; Eiler et al. 1994). Equilibrium oxygen isotope ratios in minerals are a function of temperature and bulk rock composition. In dynamic systems, intragrain oxygen isotope zoning can develop in response to geologic events that affect the thermal state of a rock and/or induce recrystallization, especially tectonic deformation and fluid infiltration. As an example, titanite grains from late-Grenville shear zones in the northwestern Adirondack Mountains exhibit a range of δ18O zoning patterns that record post-peak metamorphic cooling, episodic fluid infiltration, and deformation-facilitated recrystallization. Many titanite grains preserve smooth, core-to-rim decreasing, diffusional δ18O profiles, which are amenable to diffusion modeling. FGB models that best fit the measured δ18O profiles indicate cooling from ~700-500°C in just 2-5 m.y., a rapid thermal change signaling the final gravitational collapse of the late-Grenville orogen. Titanite can also be utilized as a U-Pb chronometer, and comparison of δ18O and U-Pb age zoning patterns within the Adirondack titanites pins the episode of rapid cooling inferred from the δ18O record to some time between 1054 and 1047 Ma. The expanded capabilities of FGB also allow for evaluation of a range of heating-cooling histories for the Adirondack granulites. Diffusional δ18O zoning profiles in titanite are best fit by complete re-equilibration at temperatures above 675 °C followed by rapid, monotonic cooling; FGB models that include only partial re-equilibration and/or episodes of reheating along the retrograde path do not fit the observed δ18O profiles. Beyond the Adirondack titanite example, FGB can be used as a predictive tool to target either specific minerals within a rock or specific rock types within a terrane for oxygen isotope geospeedometry and zoning studies. FGB generates predictions of δ18O zoning for all minerals in a rock of a given mineralogy and heating-cooling history. Different minerals within the same rock will record different segments of the thermal and fluid history based on their individual diffusivities, phase stabilities, and propensities for deformation-induced/facilitated recrystallization. It should therefore be possible to extract long thermal histories from a single sample by measuring oxygen isotope zoning profiles across several minerals with different partial retention zones for oxygen.

4. INTERIOR VIEW OF SLEEPING SHELTER SHOWING STORAGE LOCKERS IN ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

4. INTERIOR VIEW OF SLEEPING SHELTER SHOWING STORAGE LOCKERS IN CENTER PORTION WITH SLEEPING BUNKS AT EACH END - Camp Cleawox, Adirondack Sleeping Shelter, Oregon Dunes National Recreation Area, Siuslaw National Forest, Florence, Lane County, OR

Further observations of snow and frost in the Adirondacks

Treesearch

Howard W. Lull; Francis M. Rushmore

1961-01-01

Snow-depth and water-content measurements were made in March and April 1960 in the vicinity of Paul Smiths, New York, to check on procedures developed the previous year for predicting snow accumulation and melt.

Development of a total maximum daily load (TMDL) for acid-impaired lakes in the Adirondack region of New York

NASA Astrophysics Data System (ADS)

Fakhraei, Habibollah; Driscoll, Charles T.; Selvendiran, Pranesh; DePinto, Joseph V.; Bloomfield, Jay; Quinn, Scott; Rowell, H. Chandler

2014-10-01

Acidic deposition has impaired acid-sensitive surface waters in the Adirondack region of New York by decreasing pH and acid neutralizing capacity (ANC). In spite of air quality programs over past decades, 128 lakes in the Adirondacks were classified as “impaired” under Section 303(d) of the Clean Water Act in 2010 due to elevated acidity. The biogeochemical model, PnET-BGC, was used to relate decreases in atmospheric sulfur (S) and nitrogen (N) deposition to changes in lake water chemistry. The model was calibrated and confirmed using observed soil and lake water chemistry data and then was applied to calculate the maximum atmospheric deposition that the impaired lakes can receive while still achieving ANC targets. Two targets of ANC were used to characterize the recovery of acid-impaired lakes: 11 and 20 μeq L-1. Of the 128 acid-impaired lakes, 97 currently have ANC values below the target value of 20 μeq L-1 and 83 are below 11 μeq L-1. This study indicates that a moderate control scenario (i.e., 60% decrease from the current atmospheric S load) is projected to recover the ANC of lakes at a mean rate of 0.18 and 0.05 μeq L-1 yr-1 during the periods 2022-2050 and 2050-2200, respectively. The total maximum daily load (TMDL) of acidity corresponding to this moderate control scenario was estimated to be 7.9 meq S m-2 yr-1 which includes a 10% margin of safety.

Sensitivity of Stream Methyl Hg Concentrations to Environmental Change in the Adirondack Mountains of New York, USA

NASA Astrophysics Data System (ADS)

Burns, D. A.; Riva-Murray, K.; Nystrom, E.; Millard, G.; Driscoll, C. T.

2014-12-01

The Adirondacks of New York have high levels of mercury (Hg) bioaccumulation as demonstrated by a region-wide fish consumption advisory for children and women who may become pregnant. The source of this Hg is atmospheric deposition that originates from regional, continental, and global emissions. Soils in the region have large Hg stores equivalent to several decades of atmospheric deposition suggesting that the processes controlling Hg transport from soils to surface waters may greatly affect Hg concentrations and loads in surface waters. Furthermore, Hg can be converted to its neuro-toxic methyl form (MeHg), particularly in riparian and wetland soils where biogeochemical conditions favor net methylation. We measured MeHg concentrations during 33 months at Fishing Brook, a 65 km2 catchment in the upper Hudson River basin in the Adirondacks. Seasonal variation in stream MeHg concentrations was more than tenfold, consistent with temperature-driven variation in net methylation rates in soils and sediment. These data also indicate greater than twofold annual variation in stream MeHg concentrations among the three monitored growing seasons. The driest growing season had the lowest MeHg concentrations, and these values were greater during the two wetter growing seasons. We hypothesize that contact of the riparian water table with abundant organic matter and MeHg stored in the shallowest soil horizons is a dominant control on MeHg transport to the stream. An empirical model was developed that accounted for 81% of the variation in stream MeHg concentrations. Water temperature and the length of time the simulated riparian water table remained in the shallow soil were key predictive variables, highlighting the sensitivity of MeHg to climatic variation. Future changes in other factors such as Hg emissions and deposition and acid deposition will likely also influence stream MeHg concentrations and loads. For example, lime application to an Adirondack stream to increase pH and enhance ecosystem recovery from acidification has increased MeHg concentrations, which may be associated with parallel increases in dissolved organic carbon concentrations. Future changes in the Hg cycle of this region will likely be complex, reflecting changes in climatic drivers and emissions of Hg and other air pollutants.

Combining Long-Term Watershed Monitoring at Buck Creek with Spatially Extensive Ecosystem Data to Understand the Processes of Acid Rain Effects and Recovery

NASA Astrophysics Data System (ADS)

Lawrence, G. B.; Ross, D. S.; Sullivan, T. J.; McDonnell, T. C.; Bailey, S. W.; Dukett, J. E.

2014-12-01

The Buck Creek Monitoring Watershed, in the western Adirondack Region of New York, has provided long-term data back to 1982 for tracking acid rain effects and recovery, and for supporting fundamental research on environmental change. At Buck Creek, monitoring acidic deposition effects as they worsened, then diminished, has advanced our understanding of key biogeochemical processes such as Al mobilization. Although Al mobilization has been one of the primary adverse effects of acidic deposition, in the recovery phase it is now affecting terrestrial and aquatic ecosystems in new ways that could be both positive and negative, as soils and surface waters respond to further declines in acidic deposition. Using stream Al measurements from Buck Creek over varying seasons and flows, a new index, the base cation surplus (BCS), was developed to account for dissolved organic carbon (DOC) effects on the relationship between ANC and inorganic Al. Mobilization of inorganic Al, the form toxic to biota, occurs below a BCS of zero, regardless of DOC concentrations. Soil and stream data from Adirondack surveys showed that a BCS value of zero corresponds to a soil base saturation value in the B horizon of approximately 12%. Additional Adirondack survey work indicated that, where sugar maple stands grew in soils with base saturation values below 12%, seedling regeneration was nearly zero, suggesting a link between Al mobilization and impairment of tree regeneration. In recovering Adirondack lakes, the BCS was also used to show that increasing trends in DOC were accelerating decreases of inorganic Al beyond what would be expected from the increasing trends of ANC. Similar decreases of inorganic Al in Buck Creek, were coupled with increases in organic Al concentrations, which resulted in no trend in total Al concentrations despite a strong increase in pH. Sampling of Buck Creek soils in 1997, and again in 2009-2010, indicated a substantial decrease in forest floor exchangeable Al, of which approximately 85% was accounted for by stream export through leaching of exchangeable Al from soil to stream. Changes in the chemistry of the upper B horizon also suggest the possibility that recovery from acidification is accelerating podzolization in these soils.

Trends in summer chemistry linked to productivity in lakes recovering from acid deposition in the Adirondack region of New York

USGS Publications Warehouse

Momen, B.; Lawrence, G.B.; Nierzwicki-Bauer, S. A.; Sutherland, J.W.; Eichler, L.W.; Harrison, J.P.; Boylen, C.W.

2006-01-01

The US Environmental Protection Agency established the Adirondack Effects Assessment Program (AEAP) to evaluate and monitor the status of biological communities in lakes in the Adirondack region of New York that have been adversely affected by acid deposition. This program includes chemical analysis of 30 lakes, sampled two to three times each summer. Results of trends analysis for lake chemistry and chlorophyll a (chlor a) are presented for 1994 to 2003, and a general comparison is made with recent results of the Adirondack Long-Term Monitoring (ALTM) Program, which included chemical analysis of all but two of these lakes (plus an additional 24 lakes) monthly, year-round for 1992-2004. Increases in pH were found in 25 of the 30 AEAP lakes (P < 0.05) and increases in acid-neutralizing capacity (ANC) were found in 12 of the 30 lakes (P < 0.05). Concentrations of both SO 42- and Mg 2+ decreased in 11 lakes (P < 0.05), whereas concentrations of NO 3- decreased in 20 lakes (P < 0.05). Concentrations of NH 4+ decreased in 10 lakes at a significance level of P < 0.05 and in three other lakes based on P < 0.1. Concentrations of inorganic and organic monomeric aluminum generally were below the reporting limit of 1.5 ??mol L-1, but decreases were detected in four and five lakes, respectively (P < 0.1). Concentrations of chlor a increased in seven lakes at a significance level of P < 0.05 and two lakes at a significance level of P < 0.1. A significant inverse correlation was also found between chlor a and NO 3- concentrations in nine lakes at a significance level of P < 0.05 and two lakes at a significance level of P < 0.1. Results of AEAP analysis of lake chemistry were similar to those of the ALTM Program, although decreases in SO 42- concentrations were more evident in the year-round ALTM record. Overall, the results suggest (a) a degree of chemical recovery from acidification during the summer, (b) an increase in phytoplankton productivity, and (c) a decreasing trend in NO 3- concentrations resulting from the increased productivity. ?? 2007 Springer Science+Business Media, Inc.

Research and Publications in New York State History, 1980.

ERIC Educational Resources Information Center

Bliven, Briane C., Comp.

Books, monographs, and journal articles dealing with New York State history are listed and described. The briefly annotated bibliography is organized into alphabetically arranged, topical categories, including the following: Adirondacks; agriculture and farm life; American Revolution; archaeology; architecture and historic preservation; Black…

76 FR 31678 - San Luis & Rio Grande Railroad-Continuance in Control Exemption-Saratoga and North Creek Railway...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-01

... Hudson Railway Company, Inc, d/b/a Canadian Pacific (CP) a permanent and exclusive freight rail easement... interchange with CP between Adirondack Branch milepost 39.44 and CP's yard at Saratoga Springs located at...

Loss of ecosystem services due to chronic pollution of forests and surface waters in the Adirondack region (USA)

USGS Publications Warehouse

Beier, Colin M.; Caputo, Jesse; Lawrence, Gregory B.; Sullivan, Timothy J.

2017-01-01

Sustaining recent progress in mitigating acid pollution could require lower emissions caps that will give rise to real or perceived tradeoffs between healthy ecosystems and inexpensive energy. Because most impacts of acid rain affect ecosystem functions that are poorly understood by policy-makers and the public, an ecosystem services (ES) framework can help to measure how pollution affects human well-being. Focused on the Adirondack region (USA), a global ‘hot-spot’ of acid pollution, we measured how the chronic acidification of the region's forests, lakes, and streams has affected the potential economic and cultural benefits they provide to society. We estimated that acid-impaired hardwood forests provide roughly half of the potential benefits of forests on moderate to well-buffered soils – an estimated loss of ∼ $10,000 ha−1 in net present value of wood products, maple syrup, carbon sequestration, and visual quality. Acidic deposition has had only nominal impact – relative to the effects of surficial geology and till depth – on the capacity of Adirondack lakes and streams to provide water suitable for drinking. However, as pH declines in lakes, the estimated value of recreational fishing decreases significantly due to loss of desirable fish such as trout. Hatchery stocking programs have partially offset the pollution-mediated losses of fishery value, most effectively in the pH range 4.8–5.5, but are costly and limited in scope. Although any estimates of the monetary ‘damages’ of acid rain have significant uncertainties, our findings highlight some of the more tangible economic and cultural benefits of pollution mitigation efforts, which continue to face litigation and political opposition.

Loss of ecosystem services due to chronic pollution of forests and surface waters in the Adirondack region (USA).

PubMed

Beier, Colin M; Caputo, Jesse; Lawrence, Gregory B; Sullivan, Timothy J

2017-04-15

Sustaining recent progress in mitigating acid pollution could require lower emissions caps that will give rise to real or perceived tradeoffs between healthy ecosystems and inexpensive energy. Because most impacts of acid rain affect ecosystem functions that are poorly understood by policy-makers and the public, an ecosystem services (ES) framework can help to measure how pollution affects human well-being. Focused on the Adirondack region (USA), a global 'hot-spot' of acid pollution, we measured how the chronic acidification of the region's forests, lakes, and streams has affected the potential economic and cultural benefits they provide to society. We estimated that acid-impaired hardwood forests provide roughly half of the potential benefits of forests on moderate to well-buffered soils - an estimated loss of ∼ $10,000 ha -1 in net present value of wood products, maple syrup, carbon sequestration, and visual quality. Acidic deposition has had only nominal impact - relative to the effects of surficial geology and till depth - on the capacity of Adirondack lakes and streams to provide water suitable for drinking. However, as pH declines in lakes, the estimated value of recreational fishing decreases significantly due to loss of desirable fish such as trout. Hatchery stocking programs have partially offset the pollution-mediated losses of fishery value, most effectively in the pH range 4.8-5.5, but are costly and limited in scope. Although any estimates of the monetary 'damages' of acid rain have significant uncertainties, our findings highlight some of the more tangible economic and cultural benefits of pollution mitigation efforts, which continue to face litigation and political opposition. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

The application of an integrated biogeochemical model (PnET-BGC) to five forested watersheds in the Adirondack and Catskill regions of New York

USGS Publications Warehouse

LiJun, Chen; Driscoll, C.T.; Gbondo-Tugbawa, S.; Mitchell, M.J.; Murdoch, Peter S.

2004-01-01

PnET-BGC is an integrated biogeochemical model formulated to simulate the response of soil and surface waters in northern forest ecosystems to changes in atmospheric deposition and land disturbances. In this study, the model was applied to five intensive study sites in the Adirondack and Catskill regions of New York. Four were in the Adirondacks: Constable Pond, an acid-sensitive watershed; Arbutus Pond, a relatively insensitive watershed; West Pond, an acid-sensitive watershed with extensive wetland coverage; and Willy's Pond, an acid-sensitive watershed with a mature forest. The fifth was Catskills: Biscuit Brook, an acid-sensitive watershed. Results indicated model-simulated surface water chemistry generally agreed with the measured data at all five sites. Model-simulated internal fluxes of major elements at the Arbutus watershed compared well with previously published measured values. In addition, based on the simulated fluxes, element and acid neutralizing capacity (ANC) budgets were developed for each site. Sulphur budgets at each site indicated little retention of inputs of sulphur. The sites also showed considerable variability in retention of NO3-. Land-disturbance history and in-lake processes were found to be important in regulating the output of NO3- via surface waters. Deposition inputs of base cations were generally similar at these sites. Various rates of base cation outputs reflected differences in rates of base cation supply at these sites. Atmospheric deposition was found to be the largest source of acidity, and cation exchange, mineral weathering and in-lake processes served as sources of ANC. ?? 2004 John Wiley and Sons, Ltd.

Specific ultra-violet absorbance as an indicator measurement of merucry sources in an Adirondack River basin

USGS Publications Warehouse

Burns, Douglas A.; Aiken, George R.; Bradley, Paul M.; Journey, Celeste A.; Schelker, Jakob

2013-01-01

The Adirondack region of New York has been identified as a hot spot where high methylmercury concentrations are found in surface waters and biota, yet mercury (Hg) concentrations vary widely in this region. We collected stream and groundwater samples for Hg and organic carbon analyses across the upper Hudson River, a 493 km2 basin in the central Adirondacks to evaluate and model the sources of variation in filtered total Hg (FTHg) concentrations. Variability in FTHg concentrations during the growing seasons (May-Oct) of 2007-2009 in Fishing Brook, a 66-km2 sub-basin, was better explained by specific ultra-violet absorbance at 254 nm (SUVA254), a measure of organic carbon aromaticity, than by dissolved organic carbon (DOC) concentrations, a commonly used Hg indicator. SUVA254 was a stronger predictor of FTHg concentrations during the growing season than during the dormant season. Multiple linear regression models that included SUVA254 values and DOC concentrations could explain 75 % of the variation in FTHg concentrations on an annual basis and 84 % during the growing season. A multiple linear regression landscape modeling approach applied to 27 synoptic sites across the upper Hudson basin found that higher SUVA254 values are associated with gentler slopes, and greater riparian area, and lower SUVA254 values are associated with an increasing influence of open water. We hypothesize that the strong Hg?SUVA254 relation in this basin reflects distinct patterns of FTHg and SUVA254 that are characteristic of source areas that control the mobilization of Hg to surface waters, and that the seasonal influence of these source areas varies in this heterogeneous basin landscape.

Basalt-Trachybasalt Fractionation in Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Bridges, J. C.; Edwards, P. H.; Filiberto, J.; Schwenzer, S. P.; Gasda, P.; Wiens, R.

2016-08-01

A set of igneous float rocks in Gale Crater have been analysed by ChemCam. They are basalt-trachybasalts, 47 to 53 ± 5 wt% SiO2 and formed by ol-dominated crystal fractionation from an Adirondack type basalt, in magmatism with tholeiitic affinities.

Origin of biotite-hornblende-garnet coronas between oxides and plagioclase in olivine metagabbros, Adirondack region, New York

USGS Publications Warehouse

Whitney, P.R.; McLelland, J.M.

1982-01-01

Complex multivariant reactions involving Fe-Ti oxide minerals, plagioclase and olivine have produced coronas of biotite, hornblende and garnet between ilmenite and plagioclase in Adirondack olivine metagabbros. Both the biotite (6-10% TiO2) and the hornblende (3-6% TiO2) are exceptionally Titanium-rich. The garnet is nearly identical in composition to the garnet in coronas around olivine in the same rocks. The coronas form in two stages: (a) Plagioclase+Fe-Ti Oxides+Olivine+water =Hornblende+Spinel+Orthopyroxene??Biotite +more-sodic Plagioclase (b) Hornblende+Orthopyroxene??Spinel+Plagioclase =Garnet+Clinopyroxene+more-sodic Plagioclase The Orthopyroxene and part of the clinopyroxene form adjacent to olivine. Both reactions are linked by exchange of Mg2+ and Fe2+ with the reactions forming pyroxene and garnet coronas around olivine in the same rocks. The reactions occur under granulite fades metamorphic conditions, either during isobaric cooling or with increasing pressure at high temperature. ?? 1983 Springer-Verlag.

U-Pb zircon geochronology and evolution of some Adirondack meta-igneous rocks

NASA Technical Reports Server (NTRS)

Mclelland, J. M.

1988-01-01

An update was presented of the recent U-Pb isotope geochronology and models for evolution of some of the meta-igneous rocks of the Adirondacks, New York. Uranium-lead zircon data from charnockites and mangerites and on baddeleyite from anorthosite suggest that the emplacement of these rocks into a stable crust took place in the range 1160 to 1130 Ma. Granulite facies metamorphism was approximately 1050 Ma as indicated by metamorphic zircon and sphene ages of the anorthosite and by development of magmatitic alaskitic gneiss. The concentric isotherms that are observed in this area are due to later doming. However, an older contact metamorphic aureole associated with anorthosite intrusion is observed where wollastonite develops in metacarbonates. Zenoliths found in the anorthosite indicate a metamorphic event prior to anorthosite emplacement. The most probable mechanism for anorthosite genesis is thought to be ponding of gabbroic magmas at the Moho. The emplacement of the anorogenic anorthosite-mangerite-charnockite suite was apparently bracketed by compressional orogenies.

Roughing It Smoothly.

ERIC Educational Resources Information Center

Turner, Donna

1988-01-01

A mother of a 17-year-old son with spina bifida recounts the family's experiences camping in the Adirondack Mountains. Her son has enjoyed swimming, modified waterskiing, riding to the top of a mountain during the summer on a ski chair lift, and blueberry picking from a toboggan rather than his wheelchair. (VW)

New York's TUNDRA.

ERIC Educational Resources Information Center

Kalinowski, Thomas

1983-01-01

Found at the summit of some of the highest peaks of New York State's Adirondack Mountains are low-growing plants similar, and in many cases, identical to plants growing in the Arctic. Describes these plants and the environment in which they are found. Includes a color plate of alpine tundra plants. (Author/JN)

Facility rehabilitation

Treesearch

Edwin H. Ketchledge

1971-01-01

Restoration of vegetation on damaged sites is the most perplexing challenge in facility rehabilitation. In the Adirondack Mountains, the ecological impact of recreationists on the natural environment has become critical in two high-quality interior areas: on the steep higher slopes where trails soon become eroding stream channels, washing away the thin mountain soils;...

Implications for Ecosystem Services of Watershed Processes that affect the Transport and Transformations of Mercury in an Adirondack Stream Basin

NASA Astrophysics Data System (ADS)

Burns, D. A.; Riva-Murray, K.; Bradley, P. M.

2012-12-01

Mercury (Hg) is a potent neurotoxin that can affect the health of humans and wildlife through the ingestion of methyl Hg. Mercury contamination of ecosystems originates from human activities such as mining, coal burning and other industrial emissions, and the use of Hg-containing products. Natural sources such as volcanic and geothermal emissions and the weathering of Hg-bearing minerals also contribute to Hg contamination, but are believed to be minor sources in most ecosystems. Various ecosystem disturbances including fires, forest harvesting, and the submergence of land by impoundment may also contribute to Hg ecosystem contamination by mobilizing stores that have previously originated from the sources described above. Mercury from a mix of regional and global emissions sources is transported in the atmosphere to remote landscapes that are distant from local emissions sources. The Adirondacks of New York State is a forested, mountainous region characterized by abundant lakes and streams, and is distant from local emissions sources. Recreational fishing, wildlife viewing, hiking, and hunting are valued ecosystem services in this region. Here, we report on the relevance to ecosystem services of findings based on five years of Hg data collection of stream water, groundwater, invertebrates, and fish in the upper Hudson River basin in the central part of the Adirondack region. The New York State Dept. of Health has issued fish consumption advisories for the entire Adirondacks based on elevated levels previously measured in lakes and rivers of this region. Our work seeks improved understanding and models of the landscape sources and watershed processes that control the transformation of Hg to its methyl form (MeHg), the transport of MeHg to streams, and bioaccumulation of MeHg in aquatic food webs. Mean annual atmospheric Hg deposition was 6.3 μg/m2/yr during 2007-09, compared to mean annual filtered total Hg stream yields of 1.66 μg/m2/yr and filtered MeHg stream yields of 0.095 μg/m2/yr in a sub-basin of the upper Hudson during this same period. Our work shows that Hg in stream biota, which is largely in the methyl form, is strongly related to MeHg measured in the water column; food web factors that affect Hg bioaccumulation also play a role. In brook trout, the top aquatic predator in the food web of the upper Hudson, Hg concentrations average about 0.1 μg/g, a level believed to affect fish behavior, and a few values were greater than 0.3 μg/g, a level at which human fish consumption advisories are issued. Landscape-based regression models that account for about 80% of the variation in stream MeHg concentrations at 25 sites across the upper Hudson basin include metrics of riparian area and open water indicating the importance of these landscape types in affecting methylation rates, losses of MeHg (through demethylation and other processes), and the transport of MeHg to surface waters. These and other study results indicate that factors such as watershed geomorphology, seasonal variations in discharge and air temperature, and the location and connection of riparian wetlands to streams are the strongest factors that affect stream MeHg concentrations and therefore, the potential ecosystem services provided by fish and other wildlife in the Adirondack region.

Look to the hardwoods!

Treesearch

W. E. McQuilken

1957-01-01

The northeast is hardwood country. To be sure, central and northern Maine and the higher elevations of the Green Mountains, White Mountains, and Adirondacks have their spruce-fir; cool, moist sites throughout the region typically support some hemlock; and white pine - the original foundation of the lumber industry in North America - is widely represented by scattered...

Kayak Design Challenge

ERIC Educational Resources Information Center

Wood, Anson

2011-01-01

Living in the Adirondack Park and being an avid outdoorsman has often resulted in the author's love of the outdoors working its way into class projects. In 2010, the author gave a group of 25 students in grades 9-12 a challenge that required them to design and construct a prototype inexpensive, lightweight kayak for backpackers and fisherman. In…

Bringing the northern forest to your classroom

Treesearch

Mark J. Twery; Sandra J. Hildreth; Celia A. Evans

2008-01-01

In recent years the Forest Service has reemphasized the need for increased environmental literacy among the Nation's citizens and has recognized the benefits of addressing that need among school-age children. This publication is a product of an Adirondack Curriculum Project workshop sponsored by the USDA Forest Service, Northeastern Research Station, and Paul...

An interactive information kiosk for the Adirondack Park Visitor Interpretive Center, Newcomb, NY

Treesearch

Lien Alpert; Lee P. Herrington

1998-01-01

Kiosks have traditionally been non-electronic, but today kiosks are being developed as interactive, electronic information centers to transmit information about government services, commercial products and recreational experiences. This project's objective was to develop and evaluate the usefulness of a user-friendly information interface for kiosks in the...

LOCAL CLIMATE INFLUENCES ON PRECIPITATION, CLOUD WATER, AND DRY DEPOSITION TO AN ADIRONDACK SUBALPINE FOREST: INSIGHTS FROM OBSERVATIONS 1986-1996. (R826591)

EPA Science Inventory

The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

The wildland-urban interface fire problem

Treesearch

Jack Cohen

2010-01-01

The fire destruction of hundreds of homes associated with wildfires has occurred in the United States for more than a century. From 1870 to 1920, massive wildfires occurred principally in the Lake States but also elsewhere. Wildfires such as Peshtigo (Wisconsin, 1871), Michigan (1881), Hinckley (Minnesota, 1894), Adirondack (New York, 1903), the Big Blowup (Idaho-...

Campers' perspectives about boating in the Saranac Lakes Wild Forest, New York

Treesearch

Diane Kuehn; Rudy Schuster

2009-01-01

This study examines the beliefs and attitudes of campers in the Saranac Lakes Wild Forest in New York's Adirondack Park with respect to participation in nonmotorized boating, motorized boating, and personal watercraft use. Initially, qualitative interviews with land managers provided insight into campers' beliefs and attitudes about boating; these insights...

Sailing to White Boat

NASA Technical Reports Server (NTRS)

2004-01-01

This is a composite red-green-blue image of the rock called White Boat. It is the first rock target that Spirit drove to after finishing a series of investigations on the rock Adirondack. White Boat stood out to scientists due to its light color and more tabular shape compared to the dark, rounded rocks that surround it.

Development of LANDSAT Derived Forest Cover Information for Integration into Adirondack Park GIS

NASA Technical Reports Server (NTRS)

Curran, R. P.; Banta, J. S.

1982-01-01

Based upon observed changes in timber harvest practices partially attributable to forest biomass removable for energy supply purposes, the Adirondack Park Agency began in 1979 a multi-year project to implement a digital geographic information system (GIS). An initial developmental task was an inventory of forest cover information and analysis of forest resource change and availability. While developing the GIS, a pilot project was undertaken to evaluate the usefulness of LANDSAT derived land cover information for this purpose, and to explore the integration of LANDSAT data into the GIS. The prototype LANDSAT analysis project involved: (1) the use of both recent and historic data to derive land cover information for two dates; and (2) comparison of land cover over time to determine quantitative and geographic changes. The "recent data," 1978 full foliage data over portions of four LANDSAT scenes, was classified, using ground truth derived training samples in various forested and non-forested categories. Forested categories include the following: northern hardwoods, pine, spruce-fir, and pine plantation, while nonforested categories include wet-conifer, pasture, grassland, urban, exposed soil, agriculture, and water.

Compositional controls on spinel clouding and garnet formation in plagioclase of olivine metagabbros, Adirondack Mountains, New York

USGS Publications Warehouse

McLelland, J.M.; Whitney, P.R.

1980-01-01

Olivine metagabbros from the Adirondacks usually contain both clear and spinel-clouded plagioclase, as well as garnet. The latter occurs primarily as the outer rim of coronas surrounding olivine and pyroxene, and less commonly as lamellae or isolated grains within plagioclase. The formation of garnet and metamorphic spinel is dependent upon the anorthite content of the plagioclase. Plagioclase more sodic than An38??2 does not exhibit spinel clouding, and garnet rarely occurs in contact with plagioclase more albitic than An36??4. As a result of these compositional controls, the distribution of spinel and garnet mimics and visually enhances original igneous zoning in plagioclase. Most features of the arrangement of clear (unclouded) plagioclase, including the shells or moats of clear plagioclase which frequently occur inside the garnet rims of coronas, can be explained on the basis of igneous zoning. The form and distribution of the clear zones may also be affected by the metamorphic reactions which have produced the coronas, and by redistribution of plagioclase in response to local volume changes during metamorphism. ?? 1980 Springer-Verlag.

To evaluate ERTS-1 data for the usefulness as a geological sensor in the diverse geological terranes of New York State

NASA Technical Reports Server (NTRS)

Isachsen, Y. W. (Principal Investigator)

1973-01-01

The author has identified the following significant results. The straight NNE-trending escarpment that marks the easternmost extent of the Catskill Mountains appears, from ERTS-1 imagery (1079-15124) to be related to a set of parallel topographic lineaments which occur over a distance of 40 km to the west. The October 11 imagery of the Adirondacks (1080-15174) displays the pre-Paleozoic erosion surface along the western and northern margin of the Adirondack Mountains dome. The northern portion of this paleoplain is terminated to the southeast by an escarpment following an ENE topographic linear to produce a pseudo-cuesta. The snow covered terrain in the Mohawk Valley between Albany and Rome (1170-15182 and 1169-15123) displays with sculptural clarity a drumlin field having a cloud-free area of about 2600 sq km; glacial flow directions can be plotted readily because the stoss and lee sides of the drumlins can be distinguished. In the imagery of summer and fall, agricultural patterns obscured the detail which is visible in the winter imagery.

Response of surface water chemistry to reduced levels of acid precipitation: Comparison of trends in two regions of New York, USA

USGS Publications Warehouse

Burns, Douglas A.; McHale, M.R.; Driscoll, C.T.; Roy, K.M.

2006-01-01

In light of recent reductions in sulphur (S) and nitrogen (N) emissions mandated by Title IV of the Clean Air Act Amendments of 1990, temporal trends and trend coherence in precipitation (1984-2001 and 1992-2001) and surface water chemistry (1992-2001) were determined in two of the most acid-sensitive regions of North America, i.e. the Catskill and Adirondack Mountains of New York. Precipitation chemistry data from six sites located near these regions showed decreasing sulphate (SO42-), nitrate (NO3-), and base cation (CB) concentrations and increasing pH during 1984-2001, but few significant trends during 1992-2001. Data from five Catskill streams and 12 Adirondack lakes showed decreasing trends in SO42- concentrations at all sites, and decreasing trends in NO3-, CB, and H+ concentrations and increasing trends in dissolved organic carbon at most sites. In contrast, acid-neutralizing capacity (ANC increased significantly at only about half the Adirondack lakes and in one of the Catskill streams. Flow correction prior to trend analysis did not change any trend directions and had little effect on SO42- trends, but it caused several significant non-flow-corrected trends in NO3- and ANC to become non-significant, suggesting that trend results for flow-sensitive constituents are affected by flow-related climate variation. SO42- concentrations showed high temporal coherence in precipitation, surface waters, and in precipitation-surface water comparisons, reflecting a strong link between S emissions, precipitation SO42- concentrations, and the processes that affect S cycling within these regions. NO3- and H+ concentrations and ANC generally showed weak coherence, especially in surface waters and in precipitation-surface water comparisons, indicating that variation in local-scale processes driven by factors such as climate are affecting trends in acid-base chemistry in these two regions. Copyright ?? 2005 John Wiley & Sons, Ltd.

Impacts of acidification on macroinvertebrate communities in streams of the western Adirondack Mountains, New York, USA

USGS Publications Warehouse

Baldigo, Barry P.; Lawrence, G.B.; Bode, R.W.; Simonin, H.A.; Roy, K.M.; Smith, A.J.

2009-01-01

Limited stream chemistry and macroinvertebrate data indicate that acidic deposition has adversely affected benthic macroinvertebrate assemblages in numerous headwater streams of the western Adirondack Mountains of New York. No studies, however, have quantified the effects that acidic deposition and acidification may have had on resident fish and macroinvertebrate communities in streams of the region. As part of the Western Adirondack Stream Survey, water chemistry from 200 streams was sampled five times and macroinvertebrate communities were surveyed once from a subset of 36 streams in the Oswegatchie and Black River Basins during 2003-2005 and evaluated to: (a) document the effects that chronic and episodic acidification have on macroinvertebrate communities across the region, (b) define the relations between acidification and the health of affected species assemblages, and (c) assess indicators and thresholds of biological effects. Concentrations of inorganic Al in 66% of the 200 streams periodically reached concentrations toxic to acid-tolerant biota. A new acid biological assessment profile (acidBAP) index for macroinvertebrates, derived from percent mayfly richness and percent acid-tolerant taxa, was strongly correlated (R2 values range from 0.58 to 0.76) with concentrations of inorganic Al, pH, ANC, and base cation surplus (BCS). The BCS and acidBAP index helped remove confounding influences of natural organic acidity and to redefine acidification-effect thresholds and biological-impact categories. AcidBAP scores indicated that macroinvertebrate communities were moderately or severely impacted by acidification in 44-56% of 36 study streams, however, additional data from randomly selected streams is needed to accurately estimate the true percentage of streams in which macroinvertebrate communities are adversely affected in this, or other, regions. As biologically relevant measures of impacts caused by acidification, both BCS and acidBAP may be useful indicators of ecosystem effects and potential recovery at the local and regional scale.

Convening Young Leaders for Climate Resilience in New York State

NASA Astrophysics Data System (ADS)

Kretser, J.

2017-12-01

This project, led by The Wild Center, will partner with Cornell Cooperative Extension of Delaware County, the Kurt Hahn Expeditionary Learning School in Brooklyn, and the Alliance for Climate Education to do the following over three years: 1) increase climate literacy and preparedness planning in high school students through place-based Youth Climate Summits in the Adirondacks, Catskills, and New York City; 2) enhance young people's capacity to lead on climate issues through a Youth Climate Leadership Practicum 3) increase teacher comprehension and understanding of climate change through a Teacher Climate Institute and 4) communicate climate change impacts and resilience through student-driven Community Climate Outreach activities. The project will align with New York State's climate resiliency planning by collaborating with the NYS Department of Environmental Conservation Office of Climate (OCC), NYS Energy Research Development Authority (NYSERDA), and NOAA's Climate Program Office to provide accurate scientific information, resources, and tools. This collaboration will result in an increase in understanding of the impacts of climate change in rural (Adirondacks, Catskills) and urban (New York City) regions of New York State; a wider awareness of the threats and vulnerabilities that are associated with a community's location; and a stronger connection between current community resilience initiatives, educators, and youth. All three of the project sites are critically underserved in both climate literacy and action, making addressing the need of these sites to be resilient and proactive in the face of climate change critical. Our model will provide pilot lessons for how youth in both rural and urban areas can draw on local assets to address resiliency in ways appropriate for their own areas, and these lessons may be able to be applied across the United States.The proposed project is informed by best practices and specifically strengthens and replicates The Wild Center's past success with the Adirondack Youth Climate Summit, student leadership, and student-led community outreach for climate awareness - all work that has been tested or piloted over the last seven years.

A generalized garnet-forming reaction for metaigneous rocks in the Adirondacks

USGS Publications Warehouse

McLelland, J.M.; Whitney, P.R.

1980-01-01

A generalized reaction is presented to account for garnet formation in a variety of Adirondack metaigneous rocks. This reaction, which is the sum of five partial reactions written in aluminum-fixed frames of reference, is given by: 4(y+1+w)Anorthite+4 k(y+1+2 w)Olivine +4(1-k)(y+1+2 w)Fe-oxide+(8(y+1) -4 k(y+1+2 w))Orthopyroxene = 2(y+1)Garnet +2(y+1+2 w)Clinopyroxene+4 wSpinel where y is a function of plagioclase composition, k refers to the relative amounts of olivine and Fe-oxide participating in the reaction, and w is a measure of silicon mobility. When mass balanced for Mg and Fe, this reaction is found to be consistent with analyzed mineral compositions in a wide range of Adirondack metaigneous rocks. The reaction applies equally well whether the garnets were formed directly from the rectants given above or went through an intermadiate stage involving the formation of spinel, orthopyroxene, and clinopyroxene. The actual reactions which have produced garnet in both undersaturated and quartz-bearing rocks are special cases of the above general reaction. The most important special cases appear to be those in which the reactants include either olivine alone (k=1) or Fe-oxide alone (k=0). Silicon is relatively immobile (w =2) in olivine bearing, magnesium-rich rocks (k???1), and this correlates with the increased intensity in spinel clouding of plagioclase in these rocks. Silicon mobility apparently increases in the more iron-rich rocks, which also tend to contain clear or lightly clouded plagioclase. In all the rocks studied the most common composition of metamorphic plagioclase is close to An33 (i.e., y=1). Plagioclase of lower anorthite content may be too sodic to participate in garnet formation at the P-T conditions involved. ?? 1980 Springer-Verlag.

Recreation-related perceptions of natural resource managers in the Saranac Lakes wild forest area

Treesearch

Diane Kuehn; Mark Mink; Rudy Schuster

2007-01-01

Public forest managers often work with diverse stakeholder groups as they implement forest management policies. Within the Saranac Lakes Wild Forest area of New York State's Adirondack Park, stakeholder groups such as visitors, business owners, and landowners often have conflicting perceptions about issues related to water-based recreation in the region's...

North Country Successes: Case Studies of Successful Entrepreneurs in the ANCA Region.

ERIC Educational Resources Information Center

Chugh, Ram L.; Gandhi, Prem P.

This study identifies the characteristics of both successful small businesses and their entrepreneurial owners in a 14-county area of the Adirondack North Country Association (ANCA). Of the 100 survey respondents representing successful small businesses, 50% had been in business for less than 14 years; 38% were in manufacturing; 48% employed more…

Choice modeling: public preferences for enhancing benefits from private forests in the Adirondacks

Treesearch

Donald F. Dennis; Mark J. Twery

2007-01-01

Recognizing the importance of private land in meeting society's needs for forest-related benefits, public agencies fund programs that provide aid to private landowners to enhance public benefits derived from these lands. This may include technical help, education, tax incentives, and cost-share programs for various management activities. It is important that...

76 FR 31679 - Saratoga and North Creek Railway, LLC-Operation Exemption-Warren County, NY

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-01

... Company, Inc. d/b/a Canadian Pacific (CP). Saratoga also states that the subject trackage continues north... Canadian Pacific, in which Saratoga seeks an exemption under 49 CFR 1150.31 to acquire from CP a permanent... operating rights for the purpose of interchange with CP between Adirondack Branch milepost 39.44 and CP's...

Elemental cycling response of an Adirondack subalpine spruce-fir forest to atmospheric and environmental change

Treesearch

Andrew J. Friedland; Eric K. Miller

1996-01-01

Patterns and trends in forest elemental cycling can become more apparent in the presence of atmospheric perturbations. High-elevation forests of the northeastern United States have received large amounts of atmospheric deposition of pollutants, which have altered natural elemental cycling and retention rates in a variety of ways. This study examined atmospheric...

Measures of wilderness trip satisfaction and user perceptions of crowding

Treesearch

Chad P. Dawson; Alan E. Watson

2000-01-01

The inverse relationship between user perceptions of crowding and satisfaction with the wilderness experience was studied in three national wilderness areas in Oregon (1991) and in four state wilderness areas in the Adirondack Park of New York State (1997). User perceptions of crowding were correlated (low negative coefficients) with user satisfaction on the wilderness...

Contrasting stream water NO3- and Ca2+ in two nearly adjacent catchments: the role of soil Ca and forest vegetation

Treesearch

Sheila F. Christopher; Blair D. Page; John L. Campbell; Myron J. Mitchell

2006-01-01

Two nearly adjacent subcatchments, located in the Adirondack Mountains of New York State, US, with similar atmospheric inputs of N (0.6 kmol ha-1 yr-1), but markedly different stream water solute concentrations, provided a unique opportunity to evaluate the mechanisms causing this variation.

Scat-detection dogs survey low density moose in New York

Treesearch

Heidi Kretser; Michale Glennon; Alice Whitelaw; Aimee Hurt; Kristine Pilgrim; Michael Schwartz

2016-01-01

The difficulty of collecting occurrence and population dynamics data in mammalian populations of low density poses challenges for making informed management decisions. We assessed the use of scat-detection dogs to search for fecal pellets in a low density moose (Alces alces) population in the Adirondack Park in New York State, and the success rate of DNA...

Linking Foreign Language to Occupational Education in a Rural High School: Foreign Language with Criminal Justice and Travel & Tourism.

ERIC Educational Resources Information Center

Connors, William R.

Ticonderoga High School (New York) has succeeded in increasing enrollments in foreign language courses beyond the college bound, Regents-level students who usually choose such courses. The school is located in the Adirondack Mountains, a region that, in the past decade, has seen increases both in prison construction and in tourism by…

The gypsy moth in the central hardwoods: research and management needs

Treesearch

Robert Lawrence; Susan Burks; Dennis Haugen; Marc Linit

1997-01-01

The gypsy moth, Lymantria dispar (L.), is the most serious insect defoliator of trees in the Eastern United States. It is currently established in the area northeast of a line from Michigan to Virginia, and occupies most of the Adirondack and Laurentian Mixed Forest Provinces dominated by northern hardwood, spruce and fir forests. The range of the...

76 FR 31678 - Saratoga and North Creek Railway, LLC-Acquisition and Operation Exemption-Delaware and Hudson...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-06-01

... Canadian Pacific (CP) a permanent and exclusive freight rail easement over, and to operate, approximately... purpose of interchange with CP between Adirondack Branch milepost 39.44 and CP's yard at Saratoga Springs... owned by Iowa Pacific Holdings, LLC. \\2\\ CP sold the underlying track and right-of-way to the Town of...

The wildland-urban interface fire problem: A consequence of the fire exclusion paradigm

Treesearch

Jack Cohen

2008-01-01

The fire destruction of hundreds of homes associated with wildfires has occurred in the United States for more than a century. From 1870 to 1920, massive wildfires occurred principally in the Lake States but also elsewhere. Wildfires such as Peshtigo (Wisconsin, 1871), Michigan (1881), Hinckley (Minnesota, 1894), Adirondack (New York, 1903), the Big Blowup (Idaho-...

Cognitive dimensions of recreational user experiences in wilderness: an exploratory study in Adirondack wilderness areas.

Treesearch

Chad P. Dawson; Peter Newman; Alan Watson

1998-01-01

This exploratory study involved identifying the dimensions of a wilderness experience sought by users based on the available literature and on input from wilderness users. Input was collected using focus group interviews with members of four groups that were primarily involved in wilderness use and preservation in recent years. Positive and negative dimensions are...

Data-collection methods and quality-assurance/quality-control procedures used in the study of episodic stream acidification and its effect on fish and aquatic invertebrates in four Catskill Mountain streams, New York, 1988-90

USGS Publications Warehouse

Ranalli, Anthony J.; Baldigo, Barry P.; Horan-Ross, Debra; Allen, Ronald V.

1997-01-01

The U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency, conducted a 20-month study during 1988-90 to evaluate the effects of episodic acidification on fish and aquatic invertebrates in pristine headwater streams in the Catskill Mountains of New York. The study was part of the Episodic Response Project, a regional survey of episodic acidification by the U.S. Environmental Protection Agency, and was carried out simultaneously with other studies in the Adirondack Mountains of New York by the Adirondack Lake Survey Corporation and in central Pennsylvania by Pennsylvania State University. This report summarizes the methods used, describes the sampling sites, and presents the data collected from October 1, 1988 through May 30, 1990 at four headwater watersheds (Biscuit Brook, East Branch Neversink River, Black Brook, and High Falls Brook). The study entailed (1) monitoring the quantity and chemical quality of atmospheric deposition and the quality of discharge of streams, and (2) experiments to determine the effect of stream-water-quality changes on fish and invertebrate populations.

Increases in dissolved organic carbon accelerate loss of toxic Al in Adirondack lakes recovering from acidification

USGS Publications Warehouse

Lawrence, Gregory B.; Dukett, James E; Houck, Nathan; Snyder, Phillip; Capone, Susan B.

2013-01-01

Increasing pH and decreasing Al in surface waters recovering from acidification have been accompanied by increasing concentrations of dissolved organic carbon (DOC) and associated organic acids that partially offset pH increases and complicate assessments of recovery from acidification. To better understand the processes of recovery, monthly chemistry from 42 lakes in the Adirondack region, NY, collected from 1994 to 2011, were used to (1) evaluate long-term changes in DOC and associated strongly acidic organic acids and (2) use the base-cation surplus (BCS) as a chemical index to assess the effects of increasing DOC concentrations on the Al chemistry of these lakes. Over the study period, the BCS increased (p < 0.01) and concentrations of toxic inorganic monomeric Al (IMAl) decreased (p < 0.01). The decreases in IMAl were greater than expected from the increases in the BCS. Higher DOC concentrations that increased organic complexation of Al resulted in a decrease in the IMAl fraction of total monomeric Al from 57% in 1994 to 23% in 2011. Increasing DOC concentrations have accelerated recovery in terms of decreasing toxic Al beyond that directly accomplished by reducing atmospheric deposition of strong mineral acids.

Landowner perceptions of three types of boating in the Saranac Lakes area of New York State׳s Adirondack Park

USGS Publications Warehouse

Kuehn, Diane; Schuster, Rudy; Nordman, Erik

2015-01-01

In order for natural resource managers to better understand conflicting landowner perspectives related to non-motorized, motorized, and personal watercraft use, this study examines the demographic and experiential characteristics, values, attitudes, and beliefs of landowners in the Saranac Lakes area of the Adirondack Park in New York State. A mixed-methods approach, composed of 20 in-depth interviews with land managers and a mail survey of 1000 landowners, was used. Three path analyses were completed, one for each type of boat use. Results indicate that resource-related values influence beliefs and attitudes related to boat use, supporting the cognitive hierarchy model of human behavior (Fulton, D. C., Manfredo, M. J., & Lipscomb, J. (1996). Wildlife value orientations: a conceptual and measurement approach. Human Dimensions of Wildlife, 1, 24–47). In addition, length of residence in the area, past participation in non-motorized and motorized boating, age, and education were found to influence attitudes towards certain types of boating. The results of this study can be used by natural resource managers to identify management strategies that better address the values and recreational interests of landowners.

Regional growth decline of sugar maple (Acer saccharum) and its potential causes

USGS Publications Warehouse

Bishop, Daniel A.; Beier, Colin M.; Pederson, Neil; Lawrence, Gregory B.; Stella, John C; Sullivan, Timothy J.

2015-01-01

Sugar maple (Acer saccharum Marsh) has experienced poor vigor, regeneration failure, and elevated mortality across much of its range, but there has been relatively little attention to its growth rates. Based on a well-replicated dendrochronological network of range-centered populations in the Adirondack Mountains (USA), which encompassed a wide gradient of soil fertility, we observed that the majority of sugar maple trees exhibited negative growth trends in the last several decades, regardless of age, diameter, or soil fertility. Such growth patterns were unexpected, given recent warming and increased moisture availability, as well as reduced acidic deposition, which should have favored growth. Mean basal area increment was greater on base-rich soils, but these stands also experienced sharp reductions in growth. Growth sensitivity of sugar maple to temperature and precipitation was non-stationary during the last century, with overall weaker relationships than expected. Given the favorable competitive status and age structure of the Adirondack sugar maple populations sampled, evidence of widespread growth reductions raises concern over this ecologically and economically important tree. Further study will be needed to establish whether growth declines of sugar maple are occurring more widely across its range.

Smectite Formation from Basaltic Glass Under Acidic Conditions on Mars

NASA Technical Reports Server (NTRS)

Peretyazhko, T. S.; Sutter, B.; Morris, R. V.; Agresti, D. G.; Le, L.; Ming, D. W.

2015-01-01

Massive deposits of phyllosilicates of the smectite group, including Mg/Fe-smectite, have been identified in Mars's ancient Noachian terrain. The observed smectite is hypothesized to form through aqueous alteration of basaltic crust under neutral to alkaline pH conditions. These pH conditions and the presence of a CO2-rich atmosphere suggested for ancient Mars were favorable for the formation of large carbonate deposits. However, the detection of large-scale carbonate deposits is limited on Mars. We hypothesized that smectite deposits may have formed under acidic conditions that prevented carbonate precipitation. In this work we investigated formation of saponite at a pH of approximately 4 from Mars-analogue synthetic Adirondack basaltic glass of composition similar to Adirondack class rocks located at Gusev crater. Hydrothermal (200º Centigrade) 14 day experiments were performed with and without 10 millimoles Fe(II) or Mg under anoxic condition [hereafter denoted as anoxic_Fe, anoxic_Mg and anoxic (no addition of Fe(II) or Mg)] and under oxic condition [hereafter denoted as oxic (no addition of Fe(II) or Mg)]. Characterization and formation conditions of the synthesized saponite provided insight into the possible geochemical conditions required for saponite formation on Mars.

Increases in dissolved organic carbon accelerate loss of toxic Al in Adirondack lakes recovering from acidification.

PubMed

Lawrence, Gregory B; Dukett, James E; Houck, Nathan; Snyder, Phil; Capone, Sue

2013-07-02

Increasing pH and decreasing Al in surface waters recovering from acidification have been accompanied by increasing concentrations of dissolved organic carbon (DOC) and associated organic acids that partially offset pH increases and complicate assessments of recovery from acidification. To better understand the processes of recovery, monthly chemistry from 42 lakes in the Adirondack region, NY, collected from 1994 to 2011, were used to (1) evaluate long-term changes in DOC and associated strongly acidic organic acids and (2) use the base-cation surplus (BCS) as a chemical index to assess the effects of increasing DOC concentrations on the Al chemistry of these lakes. Over the study period, the BCS increased (p < 0.01) and concentrations of toxic inorganic monomeric Al (IMAl) decreased (p < 0.01). The decreases in IMAl were greater than expected from the increases in the BCS. Higher DOC concentrations that increased organic complexation of Al resulted in a decrease in the IMAl fraction of total monomeric Al from 57% in 1994 to 23% in 2011. Increasing DOC concentrations have accelerated recovery in terms of decreasing toxic Al beyond that directly accomplished by reducing atmospheric deposition of strong mineral acids.

Variation in fish mercury concentrations in streams of the Adirondack region, New York: A simplified screening approach using chemical metrics

USGS Publications Warehouse

Burns, Douglas A.; Riva-Murray, Karen

2018-01-01

Simple screening approaches for the neurotoxicant methylmercury (MeHg) in aquatic ecosystems may be helpful in risk assessments of natural resources. We explored the development of such an approach in the Adirondack Mountains of New York, USA, a region with high levels of MeHg bioaccumulation. Thirty-six perennial streams broadly representative of 1st and 2nd order streams in the region were sampled during summer low flow and analyzed for several solutes and for Hg concentrations in fish. Several landscape and chemical metrics that are typically strongly related to MeHg concentrations in aquatic biota were explored for strength of association with fish Hg concentrations. Data analyses were based on site mean length-normalized and standardized Hg concentrations (assumed to be dominantly MeHg) in whole juvenile and adult Brook Trout Salvelinus fontinalis, Creek Chub Semotilus atromaculatus, Blacknose Dace Rhinichthys atratulus, and Central Mudminnow Umbra limi, as well as on multi-species z-scores. Surprisingly, none of the landscape metrics was related significantly to regional variation in fish Hg concentrations or to z-scores across the study streams. In contrast, several chemical metrics including dissolved organic carbon (DOC) concentrations, sulfate concentrations (SO42−), pH, ultra-violet absorbance (UV254), and specific ultra-violet absorbance were significantly related to regional variation in fish Hg concentrations. A cluster analysis based on DOC, SO42−, and pH identified three distinct groups of streams: (1) high DOC, acidic streams, (2) moderate DOC, slightly acidic streams, and (3) low DOC circum-neutral streams with relatively high SO42−. Preliminary analysis indicated no significant difference in fish Hg z-scores between the moderate and high DOC groups, so these were combined for further analysis. The resulting two groups showed strong differences (p < 0.001) in DOC and SO42−concentrations as well as in pH and UV254 values. Median fish z-scores were significantly higher (p = 0.002) in the group of streams with higher DOC and UV254 and lower pH and SO42−. Screening values of DOC >6.9 mg/L, SO42− <2.8 mg/L, pH <6.6, and UV254>0.31 cm−1 were tested as thresholds to identify Adirondack stream sites likely to have higher fish Hg concentrations. By applying a combined threshold of exceedance for either pH or UV254, sites with fish Hg concentrations that exceeded a wildlife guideline of 100 ng/g were correctly identified about 75% of the time among the 36 study streams. An estimate of Hg risk applied to a data set of 391 streams based on DOC concentrations showed that about 28% were likely to pose high risk to wildlife; most of these streams were located in the western Adirondacks.

Alteration of Basaltic Glass to Mg/Fe-Smectite under Acidic Conditions: A Potential Smectite Formation Mechanism on Mars

NASA Technical Reports Server (NTRS)

Peretyazhko, Tanya; Sutter, Brad; Ming, Douglas W.

2014-01-01

Phyllosilicates of the smectite group including Mg- and Fe-saponite and Fe(III)-rich nontronite have been identified on Mars. Smectites are believed to be formed under neutral to alkaline conditions that prevailed on early Mars. This hypothesis is supported by the observation of smectite and carbonate deposits in Noachian terrain on Mars. However, smectite may have formed under mildly acidic conditions. Abundant smectite formations have been detected as layered deposits hundreds of meters thick in intracrater depositional fans and plains sediments, while no large deposits of carbonates are found. Development of mildly acidic conditions at early Mars might allow formation of smectite but inhibit widespread carbonate precipitation. Little is known regarding the mechanisms of smectite formation from basaltic glass under acidic conditions. The objective of this study was to test a hypothesis that Mars-analogue basaltic glass alters to smectite minerals under acidic conditions (pH 4). The effects of Mg and Fe concentrations and temperature on smectite formation from basaltic glass were evaluated. Phyllosilicate synthesis was performed in batch reactors (Parr acid digestion vessel) under reducing hydrothermal conditions at 200 C and 100 C. Synthetic basaltic glass with a composition similar to that of the Gusev crater rock Adirondack (Ground surface APXS measurement) was used in these experiments. Basaltic glass was prepared by melting and quenching procedures. X-ray diffraction (XRD) analysis indicated that the synthesized glass was composed of olivine, magnetite and X-ray amorphous phase. Samples were prepared by mixing 250 mg Adirondack with 0.1 M acetic acid (final pH 4). In order to study influence of Mg concentration on smectite formation, experiments were performed with addition of 0, 1 and 10 mM MgCl2. After 1, 7 and 14 day incubations the solution composition was analyzed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and the altered glass and formed phyllosilicates were examined by XRD analysis. Mineralogical changes were significant in Adirondack incubated with 10 mM MgCl2 at pH 4 and heated at 200 C. X-ray diffraction analysis revealed formation of phyllosilicate during 14 day incubation (Figure 1). Smectite was confirmed as the phyllosilicate after treatments with glycerol and KCl and heating to 550 C. The position of 02l (4.60 A) and 060 (1.54 A) diffraction bands were indicative of trioctahedral smectite such as saponite. Analysis of solution composition demonstrated that aqueous concentration of Mg decreased from 10 mM to approx.4 mM after 7 day incubation likely due to saponite formation. Smectite also formed in Adirondack incubated with 0 mM MgCl2 at pH 4 and heated at 200 C. However, diffraction peak positions of 02l (4.52 A) and 060 (1.51 A) suggested formation of dioctahedral nontronite. The 100degC Mg and Fe(II) treated basaltic glass experiments are ongoing and results will be presented.

Fine Root Growth Phenology, Production, and Turnover in a Northern Hardwood Forest Ecosystem

Treesearch

Dudley J. Raynal

1994-01-01

A large part of the nutrient flux in deciduous forests is through fine root turnover, yet this process is seldom measured. As part of a nutrient cycling study, fine root dynamics were studied for two years at Huntington Forest in the Adirondack Mountain region of New York, USA. Root growth phenology was characterized using field rhizotrons, three methods were used to...

How long do people look and listen to forest-oriented exhibits?

Treesearch

James William Shiner; Elwood L., Jr. Shafer

1975-01-01

To gain a better understanding of public reaction to I & E displays, average visitor-viewing time was measured for a variety of exhibits at the Adirondack Museum, Blue Mountain Lake, N.Y. Visitors viewed displays 15 to 64 percent of the time required to read or listen to the total message presented. The longer the message per exhibit, the less time was spent...

Spirit Switches on Its X-ray Vision

NASA Technical Reports Server (NTRS)

2004-01-01

This image shows the Mars Exploration Rover Spirit probing its first target rock, Adirondack. At the time this picture was snapped, the rover had begun analyzing the rock with the alpha particle X-ray spectrometer located on its robotic arm. This instrument uses alpha particles and X-rays to determine the elemental composition of martian rocks and soil. The image was taken by the rover's hazard-identification camera.

Vascular Plant Species of the Forest Ecology Research and Demonstration Area, Paul Smith's, New York

Treesearch

Gary L. Wade; Jonathan A. Myers; Cecilia R. Martin; Kathie Detmar; William, III Mator; Mark J. Twery; Mike Rechlin

2003-01-01

Five forest harvest methods (single-tree selection, group selection, two-age cut, shelterwood cut, and clearcut) are being demonstrated on 5-acre tracts near the Adirondack Park Agency?s Visitor Interpretation Center (VIC) at Paul Smith?s, New York. The tracts are part of the agency?s Forest Ecology Research and Demonstration Area. A primary goal is to show visitors...

An exploratory analysis of coping schemes used by paddlers who camped in the St. Regis Canoe Area, New York

Treesearch

Blake M. Probst; Rudy M. Schuster; Chad P. Dawson

2009-01-01

This study addresses requirements in the Adirondack Park State Land Master Plan for developing unit management plans. Recreational paddlers in New York State's St. Regis Canoe Area were surveyed about their perceptions of stress from daily hassles common to outdoor recreation activities, their coping responses to hassles, daily visit satisfaction, and overall trip...

Experiences of campers and campsite impacts in the St. Regis Canoe Area Wilderness

Treesearch

Chad P. Dawson; Rudy M. Schuster; Blake M. Propst; Corenne Black

2010-01-01

Visitors who camped during the summer of 2007 in the St. Regis Canoe Area (SRCA) in the Adirondack Park, New York, were surveyed via an on-site interview and diary about 14 detracting situations or problems they may have experienced, how they coped with these situations, and how they rated satisfaction with various attributes of the trip. Campsite condition assessments...

Laurentide ice sheet meltwater routing along the Iro-Mohawk River, eastern New York, USA

NASA Astrophysics Data System (ADS)

Porreca, Charles; Briner, Jason P.; Kozlowski, Andrew

2018-02-01

The rerouting of meltwater as the configuration of ice sheets evolved during the last deglaciation is thought to have led to some of the most significant perturbations to the climate system in the late Quaternary. However, the complex pattern of ice sheet meltwater drainage off the continents, and the timing of rerouting events, remains to be fully resolved. As the Laurentide Ice Sheet (LIS) retreated north of the Adirondack Uplands of northeastern New York State during the last deglaciation, a large proglacial lake, Lake Iroquois, found a lower outlet that resulted in a significant flood event. This meltwater rerouting event, from outflow via the Iro-Mohawk River valley (southern Adirondack Mountains) to the spillway at Covey Hill (northeastern Adirondack Mountains), is hypothesized to have taken place 13.2 ka and disturbed meridional circulation in the North Atlantic Ocean. However, the timing of the rerouting event is not certain because the event has not been directly dated. With improving the history of Lake Iroquois drainage in mind, we obtained cosmogenic 10Be exposure ages on a strath terrace on Moss Island, along the Iro-Mohawk River spillway. We hypothesize that Moss Island's strath terrace became abandoned during the rerouting event. Six 10Be ages from the strath surface average 14.8 ± 1.3 ka, which predates the previously published bracketing radiocarbon ages of 13.2 ka. Several possibilities for the discrepancy exist: (1) the 10Be age accurately represents the timing of a decrease in discharge through the Iro-Mohawk River spillway; (2) the age is influenced by inheritance. The 10Be ages from glacially sculpted surfaces on Moss Island above the strath terrace predate the deglaciation of the site by 5 to 35 ky; and (3) the abandonment of the Moss Island strath terrace relates to knickpoint migration and not the final abandonment of the Iro-Mohawk River as the Lake Iroquois spillway. Further study and application of cosmogenic 10Be exposure dating in the region may lead to tighter chronologic constraints of meltwater history of the LIS.

The alkaline volcanic rocks of Craters of the Moon National Monument, Idaho and the Columbia Hills of Gusev Crater, Mars

NASA Astrophysics Data System (ADS)

Neakrase, L. D.; Lim, D. S. S.; Haberle, C. W.; Hughes, S. S.; Kobs-Nawotniak, S. E.; Christensen, P. R.

2016-12-01

Idaho's Eastern Snake River Plain (ESRP) is host to extensive expressions of basaltic volcanism dominated by non evolved olivine tholeiites (NEOT) with localized occurrences of evolved lavas. Craters of the Moon National Monument (COTM) is a polygenetic lava field comprised of more than 60 lava flows emplaced during 8 eruptive periods spanning the last 15 kyrs. The most recent eruptive period (period A; 2500-2000 yr B.P.) produced flows with total alkali vs. silica classifications spanning basalt to trachyte. Coeval with the emplacement of the COTM period A volcanic pile was the emplacement of the Wapi and King's Bowl NEOT 70 km SSE of COTM along the Great Rift. Previous investigations have determined a genetic link between these two compositionally distinct volcanic centers where COTM compositions can be generated from NEOT melts through complex ascent paths and variable degrees of fractionation and assimilation of lower-middle crustal materials. The Mars Exploration Rover, Spirit, conducted a robotic investigation of Gusev crater from 2004-2010. Spirit was equipped with the Athena science payload enabling the determination of mineralogy (mini-Thermal Emission Spectrometer, Pancam multispectral camera, and Mössbauer spectrometer), bulk chemistry (Alpha Particle X-ray Spectrometer) and context (Pancam and Microscopic Imager). During sol 32 Spirit investigated an olivine basalt named Adirondack, the type specimen for a class of rock that composes much of the plains material within Gusev Crater and embays the Columbia Hills. Following the characterization of the plains material, Spirit departed the plains targeting the Columbia Hills and ascending at Husband Hill. During Spirit's ascent of Husband Hill three additional classes of volcanic rock were identified as distinct by their mini-TES spectra; Wishstone, Backstay and Irvine. These rocks are classified as tephrite, trachy-basalt and basalt, respectively, and are the first alkaline rocks observed on Mars. These alkaline rocks can be genetically linked to Adirondack class basalts through fractionation of parental Adirondack melts at various depths. The alkaline rocks of COTM share similarities to the alkaline rocks of Gusev crater. Their mineralogical, chemical and spectral similarities and differences is the focus of this investigation.

Aluminum mobilization and calcium depletion in the forest floor of red spruce forests in the northeastern United States

Treesearch

Gregory B. Lawrence; Mark B. David; Walter C. Shortle

1996-01-01

Mechanisms of Ca depletion were investigated as part of a regional study of relations among acidic deposition, soil chemistry and red spruce decline. Comparison with results from studies in the Adirondack Mountains of New York and the White Mountains of New Hampshire indicates that current acid-extractable Ca concentrations in the Oa horizon are less than one-half the...

Increasing soil temperature in a northern hardwood forest: effects on elemental dynamics and primary productivity

Treesearch

Patrick J. McHale; Myron J. Mitchell; Dudley J. Raynal; Francis P. Bowles

1996-01-01

To investigate the effects of elevated soil temperatures on a forest ecosystem, heating cables were buried at a depth of 5 cm within the forest floor of a northern hardwood forest at the Huntington Wildlife Forest (Adirondack Mountains, New York). Temperature was elevated 2.5, 5.0 and 7.5?C above ambient, during May - September in both 1993 and 1994. Various aspects of...

The Grog. A Journal of Navy Medical History and Culture. Issue 44

DTIC Science & Technology

2016-01-01

medical observation before being sent to sea. All Sailors would now have to undergo physical examination before being transferred or before they could...Wieber. carefully balanced rations, ventilation aboard ships, systematic physical ex- ercise, and general personal hygiene of all men in the Navy...cases helio (light) and occupational therapies . Below are some of the more notable sanitariums that still exist in the United States. Adirondack

Changes in abundance of vascular plants under varying silvicultural systems at the Forest Ecosystem Research and Demonstration Area, Paul Smiths, New York

Treesearch

Mark J. Twery; Elizabeth Olson; Gary L. Wade; Michael. Rechlin

2013-01-01

The Forest Ecosystem Research and Demonstration Area (FERDA) was established in 1998 adjacent to the Visitor Interpretive Center (VIC) for the Adirondack Park in Paul Smiths, NY, to provide visitors with first-hand exposure to forest management activities and to provide research opportunities for scientists and students at Paul Smith's College. This research note...

Alkaline volcanic rocks from the Columbia Hills, Gusev crater, Mars

USGS Publications Warehouse

McSween, H.Y.; Ruff, S.W.; Morris, R.V.; Bell, J.F.; Herkenhoff, K.; Gellert, Ralf; Stockstill, K.R.; Tornabene, L.L.; Squyres, S. W.; Crisp, J.A.; Christensen, P.R.; McCoy, T.J.; Mittlefehldt, D. W.; Schmidt, M.

2006-01-01

Irvine, Backstay, and Wishstone are the type specimens for three classes of fine-grained or fragmental, relatively unaltered rocks with distinctive thermal emission spectra, found as float on the flanks of the Columbia Hills. Chemical analyses indicate that these rocks are mildly alkaline basalt, trachybasalt, and tephrite, respectively. Their mineralogy consists of Na- and K-rich feldspar(s), low- and high-Ca pyroxenes, ferroan olivine, Fe-Ti (and possibly Cr) oxides, phosphate, and possibly glass. The texture of Wishstone is consistent with a pyroclastic origin, whereas Irvine and Backstay are lavas or possibly dike rocks. Chemical compositions of these rocks plot on or near liquid lines of descent for most elements calculated for Adirondack class rocks (olivine-rich basalts from the Gusev plains) at various pressures from 0.1 to 1.0 GPa. We infer that Wishstone-, Backstay-, and Irvine-class magmas may have formed by fractionation of primitive, oxidized basaltic magma similar to Adirondack-class rocks. The compositions of all these rocks reveal that the Gusev magmatic province is alkaline, distinct from the subalkaline volcanic rocks thought to dominate most of the planet's surface. The fact that differentiated volcanic rocks were not encountered on the plains prior to ascending Husband Hill may suggest a local magma source for volcanism beneath Gusev crater. Copyright 2006 by the American Geophysical Union.

Fishes of the Adirondack Park

DOE Office of Scientific and Technical Information (OSTI.GOV)

George, C.J.

1980-01-01

This review of the ichthyology of the area of the Adirondack Park contained within the blue line centers on biological surveys of the six major watersheds of the study area done in 1930-1935. The total area of 9261 square miles contains 2000-3000 water bodies. The ichthyofauna consists of 96 forms, including four kinds of hybrids commonly produced and used in stock programs; of the remaining 92 forms, 23 may be classified as Boreal or peri-glacial. The Atlantian group consists of 20 species and the Mississippian and adjacent Pleistocene refugia have provided about 45 members of the fauna. Two of themore » fauna are the rainbow and steelhead trout and the Kokanee salmon, introduced from the west coast; three species are from the old world. Spraying for insect control, introduction of exotic plant species, and acid precipitation have all measurably impacted fish populations in recent years, often in complex and synergistic ways. For example, a decline of fish populations in Big Moose Lake is probably the complex result of present and past lumbering, fishing, stocking, forest fires and hurricane damage, as well as acid precipitation. As the system diversifies, many populations of Boreal forms are being lost, and new forms of Atlantian and Mississippian heritage are being established. 253 references, 7 tables.« less

Atmospheric mercury (Hg) in the Adirondacks: Concentrations and sources

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hyun-Deok Choi; Thomas M. Holsen; Philip K. Hopke

2008-08-15

Hourly averaged gaseous elemental Hg (GEM) concentrations and hourly integrated reactive gaseous Hg (RGM), and particulate Hg (HgP) concentrations in the ambient air were measured at Huntington Forest in the Adirondacks, New York from June 2006 to May 2007. The average concentrations of GEM, RGM, and HgP were 1.4 {+-} 0.4 ng m{sup -3}, 1.8 {+-} 2.2 pg m{sup -3}, and 3.2 {+-} 3.7 pg m{sup -3}, respectively. RGM represents <3.5% of total atmospheric Hg or total gaseous Hg (TGM: GEM + RGM) and HgP represents <3.0% of the total atmospheric Hg. The highest mean concentrations of GEM, RGM, andmore » HgP were measured during winter and summer whereas the lowest mean concentrations were measured during spring and fall. Significant diurnal patterns were apparent in warm seasons for all species whereas diurnal patterns were weak in cold seasons. RGM was better correlated with ozone concentration and temperature in both warm than the other species. Potential source contribution function (PSCF) analysis was applied to identify possible Hg sources. This method identified areas in Pennsylvania, West Virginia, Ohio, Kentucky, Texas, Indiana, and Missouri, which coincided well with sources reported in a 2002 U.S. mercury emissions inventory. 51 refs., 7 figs., 1 tab.« less

Critical loads of atmospheric deposition to Adirondack lake watersheds: A guide for policymakers

USGS Publications Warehouse

Burns, Douglas A.; Sullivan, Timothy J.

2015-01-01

Acid deposition is sometimes referred to as “acid rain,” although part of the acid load reaches the surface by means other than rainfall. In the eastern U.S., acid deposition consists of several forms of sulfur and nitrogen that largely originate as emissions to the atmosphere from sources such as electricity-generating facilities (coal, oil, and natural gas), diesel- and gasoline-burning vehicles, some agricultural activities, and smokestack industries. Acid deposition is known to cause deleterious effects to sensitive ecosystems of which the Adirondack region of New York State provides several well-known and well-studied examples. This largely forested region includes abundant lakes, streams, and wetlands and possesses several landscape features that result in high ecosystem sensitivity to acid deposition. These features include bedrock that weathers slowly, steep slopes, and thin, naturally acidic soils. An ecosystem is described as sensitive to, or affected by, acid deposition if prolonged exposure to acid deposition has resulted in detrimental ecosystem effects. Soils, streams, and lakes that are less sensitive are better able to buffer acid deposition. A principal reason that acidification is a concern for resource managers is because of the changes induced in native biota and their habitat on land and in water. As the chemistry of soils and surface waters in sensitive landscapes changes in response to prolonged exposure to acid deposition, organisms that cannot tolerate high acidity, such as sugar maple trees and many species of fish and aquatic insects, may be gradually eliminated from the ecosystem. Other biota such as red spruce may experience increased stress and reduced growth rates as a result of acidification, exposing these species to increased susceptibility to disease and other natural stressors and perhaps increased mortality. The ecological effects of acid deposition have been documented by extensive research that began in the U.S. in the 1970s and continues today. This report does not provide a detailed discussion of these ecological effects, but interested readers can refer to four publications that provide good summaries of current scientific knowledge of these effects, including extensive reference to previous research in the Adirondacks (Driscoll et al. 2001, Jenkins et al. 2007, Burns et al. 2011, Sullivan 2015).

Formation of Fe/mg Smectite Under Acidic Conditions from Synthetic Adirondack Basaltic Glass: an Analog to Fe/mg Smectite Formation on Mars

NASA Technical Reports Server (NTRS)

Sutter, B.; Peretyazhko, T.; Morris, R. V.; Ming, D. W.

2014-01-01

Smectite has been detected as layered material hundreds of meters thick, in intracrater depositional fans, in plains sediments, and deposits at depth on Mars. If early Mars hosted a dense CO2 atmosphere, then extensive carbonate should have formed in the neutral/alkaline conditions expected for smectite formation. However, large carbonate deposits on Mars have not been discovered. Instead of neutral to moderately alkaline conditions, early Mars may have experienced mildly acidic conditions that allowed for Fe/Mg smectite formation but prevented widespread carbonate formation. The objective of this work is to demonstrate that Fe(II)/Mg saponite and nontronite can form in mildly acidic solutions (e.g., pH 4). Synthetic basaltic glass (< 53 microns) of Adirondack rock class composition was exposed to pH 4 (acetic acid buffer) and N2 purged (anoxic) solutions amended with 0 and 10 mM Mg or Fe(II). Basaltic glass in these solutions was heated to 200 C in batch reactors for 1, 7, and 14 days. X-ray diffraction analysis of reacted materials detected the presence of phyllosilicates as indicated by a approx. 15.03-15.23Angstroms (001) peak. Smectite was confirmed as the phyllosilicate after treatments with glycerol and KCl and heating to 550 C. Trioctahedral saponite was confirmed by the presence of a 4.58 to 4.63 Angstroms (02l) and 1.54Angstroms (060) peaks. Saponite concentration was highest, as indicated by XRD peak intensity, in the 10 mM Mg treatment followed by the 0 mM and then 10 mM Fe(II) treatments. This order of sapontite concentration suggests that Fe(II) additions may have a role in slowing the kinetics of saponite formation relative to the other treatments. Nontronite synthesis was attempted by exposing Adirondack basaltic glass to pH 4 oxic solutions (without N2 purge) at 200 C for 14 days. X-ray diffraction analysis indicated that mixtures of trioctahedral (saponite) and dioctahedral (nontronite) may have formed in these experiments based on the 02l and 060 peaks. Moessbauer analysis coupled with future experiments are planned to verify if nontronite can be formed under mildly acidic and oxic conditions. Results of this work demonstrate that acidic conditions could have occurred on an early Mars, which allowed for smectite formation but inhibited carbonate formation.

Evidence for multiple metamorphic events in the Adirondack Mountains, N. Y

DOE Office of Scientific and Technical Information (OSTI.GOV)

McLelland, J.; Lochhead, A.; Vyhnal, C.

1988-05-01

Field evidence consisting of: (1) rotated, foliated xenoliths, (2) country rock foliation truncated by isoclinally folded igneous intrusions bearing granulite facies assemblages document one, or more, early dynamothermal event(s) of regional scale and high grade. Early metamorphism resulted in pronounced linear and planar fabric throughout the Adirondacks and preceded the emplacement of the anorthosite-mangerite-charnockite-granite-alaskite (AMCA) suite which contains xenoliths of the metamorphosed rocks. Olivine metagabbros, believed to be approximately contemporaneous with the AMCA-suite, also crosscut and contain xenoliths of, strongly foliated metasediments. These intrusive rocks caused contact metamorphism in the metasediments which locally exhibit both anatectite and restite assemblages. Subsequently,more » this already complex framework underwent three phases of folding, including an early recumbent isoclinical event, and was metamorphosed to granulite facies P,T conditions. The age of the early metamorphism cannot yet be narrowly constrained, but isotopic results suggest that it may be as young as approx. 1200 Ma or older than approx. 1420 Ma. U-Pb zircon ages indicate emplacement of the AMCA-(metagabbro)-suite in the interval 1160-1130 Ma and place the peak of granulite facies metamorphism between 1070-1025 Ma. The anorogenic character of the AMCA-suite, and the occurrence of metadiabase dike swarms within it, are further evidence of the separate nature of the metamorphic events that precede and postdate AMCA emplacement.« less

Hydrologic analysis of two headwater lake basins of differing lake pH in the west-central Adirondack Mountains of New York

USGS Publications Warehouse

Murdoch, Peter S.; Peters, N.E.; Newton, R.M.

1987-01-01

Hydrologic analysis of two headwater lake basins in the Adirondack Mountains, New York, during 1980-81 indicates that the degree of neutralization of acid precipitation is controlled by the groundwater contribution to the lake. According to flow-duration analyses, daily mean outflow/unit area from the neutral lake (Panther Lake, pH 5-7) was more sustained and contained a higher percentage of groundwater than that of the acidic lake (Woods Lake, pH 4-5). Outflow recession rates and maximum base-flow rates, derived from individual recession curves, were 3.9 times and 1.5 times greater, respectively, in the neutral-lake basin than in the acidic-lake basin. Groundwater contribution to lake outflow was also calculated from a lake-water budget; the groundwater contribution to the neutral lake was about 10 times greater than that to the acidic lake. Thick sandy till forms the groundwater reservoir and the major recharge area in both basins but covers 8.5 times more area in the neutral-lake basin than in the acidic-lake basin. More groundwater storage within the neutral basin provides longer contact time with neutralizing minerals and more groundwater discharge. As a result, the neutral lake has relatively high pH and alkalinity, and more net cation transport. (USGS)

Hydraulic and biochemical gradients limit wetland mercury supply to an Adirondack stream

USGS Publications Warehouse

Bradley, Paul M.; Burns, Douglas A.; Harvey, Judson; Journey, Celeste A.; Brigham, Mark E.; Murray, Karen

2016-01-01

Net fluxes (change between upstream and downstream margins) for water, methylmercury (MeHg), total mercury (THg), dissolved organic carbon (DOC), and chloride (Cl) were assessed twice in an Adirondack stream reach (Sixmile Brook, USA), to test the hypothesized importance of wetland-stream hydraulic and chemical gradients as fundamental controls on fluvial mercury (Hg) supply. The 500 m study reach represented less than 4% of total upstream basin area. During a snowmelt high-flow event in May 2009 surface water, DOC, and chloride fluxes increased by 7.1±1.3%, 8.0±1.3%, and 9.0±1.3%, respectively, within the reach, demonstrating that the adjacent wetlands are important sources of water and solutes to the stream. However, shallow groundwater Hg concentrations lower than in the surface water limited groundwater-surface water Hg exchange and no significant changes in Hg (filtered MeHg and THg) fluxes were observed within the reach despite the favorable hydraulic gradient. In August 2009, the lack of significant wetland-stream hydraulic gradient resulted in no net flux of water or solutes (MeHg, THg, DOC, or Cl) within the reach. The results are consistent with the wetland-Hg-source hypothesis and indicate that hydraulic and chemical gradient (direction and magnitude) interactions are fundamental controls on the supply of wetland Hg to the stream.

Evaluating the efficiency of environmental monitoring programs

USGS Publications Warehouse

Levine, Carrie R.; Yanai, Ruth D.; Lampman, Gregory G.; Burns, Douglas A.; Driscoll, Charles T.; Lawrence, Gregory B.; Lynch, Jason; Schoch, Nina

2014-01-01

Statistical uncertainty analyses can be used to improve the efficiency of environmental monitoring, allowing sampling designs to maximize information gained relative to resources required for data collection and analysis. In this paper, we illustrate four methods of data analysis appropriate to four types of environmental monitoring designs. To analyze a long-term record from a single site, we applied a general linear model to weekly stream chemistry data at Biscuit Brook, NY, to simulate the effects of reducing sampling effort and to evaluate statistical confidence in the detection of change over time. To illustrate a detectable difference analysis, we analyzed a one-time survey of mercury concentrations in loon tissues in lakes in the Adirondack Park, NY, demonstrating the effects of sampling intensity on statistical power and the selection of a resampling interval. To illustrate a bootstrapping method, we analyzed the plot-level sampling intensity of forest inventory at the Hubbard Brook Experimental Forest, NH, to quantify the sampling regime needed to achieve a desired confidence interval. Finally, to analyze time-series data from multiple sites, we assessed the number of lakes and the number of samples per year needed to monitor change over time in Adirondack lake chemistry using a repeated-measures mixed-effects model. Evaluations of time series and synoptic long-term monitoring data can help determine whether sampling should be re-allocated in space or time to optimize the use of financial and human resources.

Paleolimnological assessment of the effects of lake acidification on Chironomidae (Diptera) assemblages in the Adirondack region of New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Uutala, A.J.

1987-01-01

The stratigraphies of larval chironomid and Chaoborus (Diptera: Chironomidae and Chaoboridae) remains were determined for cores from five Adirondack lakes. Big Moose Lake, Deep Lake, Brook trout Lake and Upper Wallface Pond are currently acidic, while Windfall Pond is near neutral. Altered chironomid assemblages were evident in the four acidic lakes, and acid deposition was the most likely cause for the inferred changes. Declining pH was indicated beginning after 1950 in Big Moose L., after 1930 in Deep L. and Upper Wallface P., and after 1920 in Brook trout L. No recent pH change was inferred for Windfall P. Shiftsmore » in the chironomid assemblages were concordant with indications of declining pH inferred from analyses of cladocera, chrysophyte and diatom remains. The best indicators among the chironomid taxa were Heterotrissocladius changi, Micropsectra and Zavreliina, which tended to decline, and Salutschia cf. briani, Psectrocladius (Psectrocladius) and Tanytarsus, which tended to increase in abundance in response to increased acidity. Long-term presence of Chaoborus americanus in Deep L. and Upper Wallface P. indicated that fishes were probably never abundant in these lakes. Increases in the accumulation rates of C. americanus remains in Deep L. and Upper Wallface P. reflected the poor success and eventual halt of fish stocking in these lakes.« less

Approaching Rock Target No. 1

NASA Technical Reports Server (NTRS)

2004-01-01

This 3-D stereo anaglyph image was taken by the Mars Exploration Rover Spirit front hazard-identification camera after the rover's first post-egress drive on Mars Sunday. Engineers drove the rover approximately 3 meters (10 feet) from the Columbia Memorial Station toward the first rock target, seen in the foreground. The football-sized rock was dubbed Adirondack because of its mountain-shaped appearance. Scientists plan to use instruments at the end of the rover's robotic arm to examine the rock and understand how it formed.

Mercury methylation in Sphagnum moss mats and its association with sulfate-reducing bacteria in an acidic Adirondack forest lake wetland.

PubMed

Yu, Ri-Qing; Adatto, Isaac; Montesdeoca, Mario R; Driscoll, Charles T; Hines, Mark E; Barkay, Tamar

2010-12-01

Processes leading to the bioaccumulation of methylmercury (MeHg) in northern wetlands are largely unknown. We have studied various ecological niches within a remote, acidic forested lake ecosystem in the southwestern Adirondacks, NY, to discover that mats comprised of Sphagnum moss were a hot spot for mercury (Hg) and MeHg accumulation (190.5 and 18.6 ng g⁻¹ dw, respectively). Furthermore, significantly higher potential methylation rates were measured in Sphagnum mats as compared with other sites within Sunday Lake's ecosystem. Although MPN estimates showed a low biomass of sulfate-reducing bacteria (SRB), 2.8 × 10⁴ cells mL⁻¹ in mat samples, evidence consisting of (1) a twofold stimulation of potential methylation by the addition of sulfate, (2) a significant decrease in Hg methylation in the presence of the sulfate reduction inhibitor molybdate, and (3) presence of dsrAB-like genes in mat DNA extracts, suggested that SRB were involved in Hg methylation. Sequencing of dsrB genes indicated that novel SRB, incomplete oxidizers including Desulfobulbus spp. and Desulfovibrio spp., and syntrophs dominated the sulfate-reducing guild in the Sphagnum moss mat. Sphagnum, a bryophyte dominating boreal peatlands, and its associated microbial communities appear to play an important role in the production and accumulation of MeHg in high-latitude ecosystems. © 2010 Federation of European Microbiological Societies. Published by Blackwell Publishing Ltd. All rights reserved.

Increased Calcium Availability Leads to Greater Forest Floor Accumulation in an Adirondack Forest

NASA Astrophysics Data System (ADS)

Melvin, A.; Goodale, C. L.

2010-12-01

Nutrient availability in Northeastern US forests has been dramatically altered by anthropogenic activities. Acid deposition has not only increased nitrogen (N) availability, but has also been linked to soil acidification and a loss of base cations, largely calcium (Ca). We are studying the long-term effects of a Ca addition on carbon (C) and N cycling in a forested catchment in the Adirondack Park, New York. In 1989, calcium carbonate (lime) was added to two subcatchments within the Woods Lake Watershed to ameliorate the effects of soil Ca depletion. Two additional subcatchments were left as controls. Eighteen years after the Ca application, both soil pH and exchangeable Ca concentrations remain elevated in the organic horizons and upper mineral soils of the treated subcatchments. The forest floor mass in this watershed is very large and measurements show that the organic layer in the limed subcatchments is significantly larger than in the controls (212 t/ha vs. 116 t/ha), resulting in greater C and N stocks in the Ca-amended soils. This finding suggests that Ca may stabilize soil organic matter (SOM), resulting in greater C storage under high soil Ca conditions. We are investigating potential drivers of this SOM accumulation in the limed subcatchments, including rates of leaf litter production and the decomposition rate of forest floor material. This work will provide important insights into how long-term changes in soil Ca availability influence SOM stabilization, retention and nutrient cycling.

Chemistry and transport of soluble humic substances in forested watersheds of the Adirondack Park, New York

USGS Publications Warehouse

Cronan, C.S.; Aiken, G.R.

1985-01-01

Studies were conducted in conjunction with the Integrated Lake-Watershed Acidification Study (ILWAS) to examine the chemistry and leaching patterns of soluble humic substances in forested watersheds of the Adirondack region. During the summer growing season, mean dissolved organic carbon (DOC) concentrations in the ILWAS watersheds ranged from 21-32 mg C l-1 in O/A horizon leachates, from 5-7 mg C l-1 in B horizon leachates, from 2-4 mg C l-1 in groundwater solutions, from 6-8 mg C l-1 in first order streams, from 3-8 mg C l-1 in lake inlets, and from 2-7 mg C l-1 in lake outlets. During the winter, mean DOC concentrations dropped significantly in the upper soil profile. Soil solutions from mixed and coniferous stands contained as much as twice the DOC concentration of lysimeter samples from hardwood stands. Results of DOC fractionation analysis showed that hydrophobia and hydrophilic acids dominate the organic solute composition of natural waters in these watersheds. Charge balance and titration results indicated that the general acid-base characteristics of the dissolved humic mixture in these natural waters can be accounted for by a model organic acid having an averagepKa of 3.85, an average charge density of 4-5 ??eq mg-1 C at ambient pH, and a total of 6-7 meq COOH per gram carbon. ?? 1985.

Manganese biogeochemistry in a small Adirondack forested lake watershed

USGS Publications Warehouse

Shanley, James B.

1986-01-01

In September and October 1981, manganese (Mn) concentrations and pH were intensively monitored in a small forested lake watershed in the west-central Adirondack Mountains, New York, during two large acidic storms (each ∼5 cm rainfall, pH 4.61 and 4.15). The data were evaluated to identify biogeochemical pathways of Mn and to assess how these pathways are altered by acidic atmospheric inputs. Concentrations of Mn averaged 1.1 μg/L in precipitation and increased to 107 μg/L in canopy throughfall, the enrichment reflecting active biological cycling of Mn. Rain pH and throughfall Mn were negatively correlated, suggesting that foliar leaching of Mn was enhanced by rainfall acidity. The pulselike input of Mn to the forest floor in the high initial concentrations in throughfall (∼1000 μg/L) did not affect Mn concentrations in soil water (< 20 μg/L) or groundwater (usually < 40 μg/L), which varied little with time. In the inlet stream, Mn concentrations remained constant at 48 μg/L as discharge varied from 1.1 to 96 L/s. Manganese was retained in the vegetative cycle and regulated in the stream by adsorption in the soil organic horizon. The higher Mn levels in the stream may be linked to its high acidity (pH 4.2–4.3). Mixing of Mn-rich stream water with neutral lake water (pH 7.0) caused precipitation of Mn and deposition in lake sediment.

Growth response of conifers in Adirondack plantations to changing environment: Model approaches based on stem-analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pan, Y.

1993-01-01

Based on model approaches, three conifer species, red pine, Norway spruce and Scots pine grown in plantations at Pack Demonstration Forest, in the southeastern Adirondack mountains of New York, were chosen to study growth response to different environmental changes, including silvicultural treatments and changes in climate and chemical environment. Detailed stem analysis data provided a basis for constructing tree growth models. These models were organized into three groups: morphological, dynamic and predictive. The morphological model was designed to evaluate relationship between tree attributes and interactive influences of intrinsic and extrinsic factors on the annual increments. Three types of morphological patternsmore » have been characterized: space-time patterns of whole-stem rings, intrinsic wood deposition pattern along the tree-stem, and bolewood allocation ratio patterns along the tree-stem. The dynamic model reflects the growth process as a system which responds to extrinsic signal inputs, including fertilization pulses, spacing effects and climatic disturbance, as well as intrinsic feedback. Growth signals indicative of climatic effects were used to construct growth-climate models using both multivariate analysis and Kalman filter methods. The predictive model utilized GCMs and growth-climate relationships to forecast tree growth responses in relation to future scenarios of CO[sub 2]-induced climate change. Prediction results indicate that different conifer species have individualistic growth response to future climatic change and suggest possible changes in future growth and distribution of naturally occurring conifers in this region.« less

Formation of Fe/Mg Smectite under acidic conditions from synthetic Adirondack Basaltic Glass: An Analog to Fe/Mg Smectite Formation on Mars.

NASA Astrophysics Data System (ADS)

Sutter, B.; Peretyazhko, T.; Morris, R. V.; Ming, D. W.

2014-12-01

Smectite has been detected as layered material hundreds of meters thick, in intracrater depositional fans, in plains sediments, and deposits at depth on Mars. If early Mars hosted a dense CO2 atmosphere, then extensive carbonate should have formed in the neutral/alkaline conditions expected for smectite formation. However, large carbonate deposits on Mars have not been discovered. Instead of neutral to moderately alkaline conditions, early Mars may have experienced mildly acidic conditions that allowed for Fe/Mg smectite formation but prevented widespread carbonate formation. The objective of this work is to demonstrate that Fe(II)/Mg-saponite and nontronite can form in mildly acidic solutions (e.g., pH 4). Synthetic basaltic glass (< 53 μm) of Adirondack rock class composition was exposed to pH 4 (acetic acid buffer) and N2 purged (anoxic) solutions amended with 0 and 10 mM Mg or Fe(II). Basaltic glass in these solutions was heated to 200ºC in batch reactors for 1, 7, and 14 days. X-ray diffraction analysis of reacted materials detected the presence of phyllosilicates as indicated by a ~15.03-15.23Ǻ (001) peak. Smectite was confirmed as the phyllosilicate after treatments with glycerol and KCl and heating to 550°C. Trioctahedral saponite was confirmed by the presence of a 4.58 to 4.63 Ǻ (02l) and 1.54Ǻ (060) peaks. Saponite concentration was highest, as indicated by XRD peak intensity, in the 10 mM Mg treatment followed by the 0 mM and then 10 mM Fe(II) treatments. This order of sapontite concentration suggests that Fe(II) additions may have a role in slowing the kinetics of saponite formation relative to the other treatments. Nontronite synthesis was attempted by exposing Adirondack basaltic glass to pH 4 oxic solutions (without N2 purge) at 200ºC for 14 days. X-ray diffraction analysis indicated that mixtures of trioctahedral (saponite) and dioctahedral (nontronite) may have formed in these experiments based on the 02l and 060 peaks. Mössbauer analysis coupled with future experiments are planned to verify if nontronite can be formed under mildly acidic and oxic conditions. Results of this work demonstrate that acidic conditions could have occurred on an early Mars, which allowed for smectite formation but inhibited carbonate formation.

Hungry for Rocks

NASA Technical Reports Server (NTRS)

2004-01-01

This image from the Mars Exploration Rover Spirit hazard identification camera shows the rover's perspective just before its first post-egress drive on Mars. On Sunday, the 15th martian day, or sol, of Spirit's journey, engineers drove Spirit approximately 3 meters (10 feet) toward its first rock target, a football-sized, mountain-shaped rock called Adirondack (not pictured). In the foreground of this image are 'Sashimi' and 'Sushi' - two rocks that scientists considered investigating first. Ultimately, these rocks were not chosen because their rough and dusty surfaces are ill-suited for grinding.

Ready to Rock and Roll

NASA Technical Reports Server (NTRS)

2004-01-01

This image from the Mars Exploration Rover Spirit hazard-identification camera shows the rover's perspective just before its first post-egress drive on Mars. On Sunday, the 15th martian day, or sol, of Spirit's journey, engineers drove Spirit approximately 3 meters (10 feet)toward its first rock target, a football-sized, mountain-shaped rock called Adirondack (not pictured). In the foreground of this image are 'Sashimi' and 'Sushi' - two rocks that scientists considered investigating first. Ultimately, these rocks were not chosen because their rough and dusty surfaces are ill-suited for grinding.

Rover Takes a Sunday Drive

NASA Technical Reports Server (NTRS)

2004-01-01

This animation, made with images from the Mars Exploration Rover Spirit hazard-identification camera, shows the rover's perspective of its first post-egress drive on Mars Sunday. Engineers drove Spirit approximately 3 meters (10 feet) toward its first rock target, a football-sized, mountain-shaped rock called Adirondack. The drive took approximately 30 minutes to complete, including time stopped to take images. Spirit first made a series of arcing turns totaling approximately 1 meter (3 feet). It then turned in place and made a series of short, straightforward movements totaling approximately 2 meters (6.5 feet).

Acid-base characteristics of the Grass Pond watershed in the Adirondack Mountains of New York State, USA: interactions among soil, vegetation and surface waters

NASA Astrophysics Data System (ADS)

McEathron, K. M.; Mitchell, M. J.; Zhang, L.

2013-07-01

Grass Pond watershed is located within the southwestern Adirondack Mountain region of New York State, USA. This region receives some of the highest rates of acidic deposition in North America and is particularly sensitive to acidic inputs due to many of its soils having shallow depths and being generally base poor. Differences in soil chemistry and tree species between seven subwatersheds were examined in relation to acid-base characteristics of the seven major streams that drain into Grass Pond. Mineral soil pH, stream water BCS (base-cation surplus) and pH exhibited a positive correlation with sugar maple basal area (p = 0.055; 0.48 and 0.39, respectively). Black cherry basal area was inversely correlated with stream water BCS, ANC (acid neutralizing capacity)c and NO3- (p = 0.23; 0.24 and 0.20, respectively). Sugar maple basal areas were positively associated with watershed characteristics associated with the neutralization of atmospheric acidic inputs while in contrast, black cherry basal areas showed opposite relationships to these same watershed characteristics. Canonical correspondence analysis indicated that black cherry had a distinctive relationship with forest floor chemistry apart from the other tree species, specifically a strong positive association with forest floor NH4, while sugar maple had a distinctive relationship with stream chemistry variables, specifically a strong positive association with stream water ANCc, BCS and pH. Our results provide evidence that sugar maple is acid-intolerant or calciphilic tree species and also demonstrate that black cherry is likely an acid-tolerant tree species.

Landscape controls on total and methyl Hg in the Upper Hudson River basin, New York, USA

USGS Publications Warehouse

Burns, Douglas A.; Riva-Murray, K.; Bradley, P.M.; Aiken, G.R.; Brigham, M.E.

2012-01-01

Approaches are needed to better predict spatial variation in riverine Hg concentrations across heterogeneous landscapes that include mountains, wetlands, and open waters. We applied multivariate linear regression to determine the landscape factors and chemical variables that best account for the spatial variation of total Hg (THg) and methyl Hg (MeHg) concentrations in 27 sub-basins across the 493 km2 upper Hudson River basin in the Adirondack Mountains of New York. THg concentrations varied by sixfold, and those of MeHg by 40-fold in synoptic samples collected at low-to-moderate flow, during spring and summer of 2006 and 2008. Bivariate linear regression relations of THg and MeHg concentrations with either percent wetland area or DOC concentrations were significant but could account for only about 1/3 of the variation in these Hg forms in summer. In contrast, multivariate linear regression relations that included metrics of (1) hydrogeomorphology, (2) riparian/wetland area, and (3) open water, explained about 66% to >90% of spatial variation in each Hg form in spring and summer samples. These metrics reflect the influence of basin morphometry and riparian soils on Hg source and transport, and the role of open water as a Hg sink. Multivariate models based solely on these landscape metrics generally accounted for as much or more of the variation in Hg concentrations than models based on chemical and physical metrics, and show great promise for identifying waters with expected high Hg concentrations in the Adirondack region and similar glaciated riverine ecosystems.

An empirical approach to modeling methylmercury concentrations in an Adirondack stream watershed

USGS Publications Warehouse

Burns, Douglas A.; Nystrom, Elizabeth A.; Wolock, David M.; Bradley, Paul M.; Riva-Murray, Karen

2014-01-01

Inverse empirical models can inform and improve more complex process-based models by quantifying the principal factors that control water quality variation. Here we developed a multiple regression model that explains 81% of the variation in filtered methylmercury (FMeHg) concentrations in Fishing Brook, a fourth-order stream in the Adirondack Mountains, New York, a known “hot spot” of Hg bioaccumulation. This model builds on previous observations that wetland-dominated riparian areas are the principal source of MeHg to this stream and were based on 43 samples collected during a 33 month period in 2007–2009. Explanatory variables include those that represent the effects of water temperature, streamflow, and modeled riparian water table depth on seasonal and annual patterns of FMeHg concentrations. An additional variable represents the effects of an upstream pond on decreasing FMeHg concentrations. Model results suggest that temperature-driven effects on net Hg methylation rates are the principal control on annual FMeHg concentration patterns. Additionally, streamflow dilutes FMeHg concentrations during the cold dormant season. The model further indicates that depth and persistence of the riparian water table as simulated by TOPMODEL are dominant controls on FMeHg concentration patterns during the warm growing season, especially evident when concentrations during the dry summer of 2007 were less than half of those in the wetter summers of 2008 and 2009. This modeling approach may help identify the principal factors that control variation in surface water FMeHg concentrations in other settings, which can guide the appropriate application of process-based models.

Spectral Variability among Rocks in Visible and Near Infrared Multispectral Pancam Data Collected at Gusev Crater: Examinations using Spectral Mixture Analysis and Related Techniques

NASA Technical Reports Server (NTRS)

Farrand, W. H.; Bell, J. F., III; Johnson, J. R.; Squyres, S. W.; Soderblom, J.; Ming, D. W.

2006-01-01

Visible and Near Infrared (VNIR) multispectral observations of rocks made by the Mars Exploration Rover Spirit s Panoramic camera (Pancam) have been analysed using a spectral mixture analysis (SMA) methodology. Scenes have been examined from the Gusev crater plains into the Columbia Hills. Most scenes on the plains and in the Columbia Hills could be modeled as three endmember mixtures of a bright material, rock, and shade. Scenes of rocks disturbed by the rover s Rock Abrasion Tool (RAT) required additional endmembers. In the Columbia Hills there were a number of scenes in which additional rock endmembers were required. The SMA methodology identified relatively dust-free areas on undisturbed rock surfaces, as well as spectrally unique areas on RAT abraded rocks. Spectral parameters from these areas were examined and six spectral classes were identified. These classes are named after a type rock or area and are: Adirondack, Lower West Spur, Clovis, Wishstone, Peace, and Watchtower. These classes are discriminable based, primarily, on near-infrared (NIR) spectral parameters. Clovis and Watchtower class rocks appear more oxidized than Wishstone class rocks and Adirondack basalts based on their having higher 535 nm band depths. Comparison of the spectral parameters of these Gusev crater rocks to parameters of glass-dominated basaltic tuffs indicates correspondence between measurements of Clovis and Watchtower classes, but divergence for the Wishstone class rocks which appear to have a higher fraction of crystalline ferrous iron bearing phases. Despite a high sulfur content, the rock Peace has NIR properties resembling plains basalts.

Effects of silicate weathering on water chemistry in forested, upland, felsic terrane of the USA

NASA Astrophysics Data System (ADS)

Stauffer, Robert E.; Wittchen, Bruce D.

1991-11-01

We use data from the US EPA National Surface Water Survey (NSWS), the USGS Bench-Mark Station monitoring program, and the National Acid Deposition Program (NADP) to evaluate the role of weathering in supplying base cations to surface waters in forested, upland, felsic terrane of the northeastern, northcentral, and northwestern (Idaho batholith) United States. Multivariate regression reveals differential effects of discharge on individual base cations and silica, but no secular trend in the Ca/Na denudation rate over 24 yr (1965-1988) for the Wild River catchment in the White Mountains. Because the turn-over time for Na in the soil-exchange complex is only ca. 1.5 yr, the long-term behavior of the ratios Ca/Na and Si/Na in waters leaving this catchment indicates that weathering is compensating for base cation export. In every subregion, Ca and Mg concentrations in lakes are statistically linked to nonmarine Na, but the median Ca/Na ratio is greater than the ratio in local plagioclase. We attribute this inequality to nonstoichiometric weathering of calcium in juvenile (formerly glaciated) terrane, not to leaching of exchangeable cations by SO 4, because intraregional and cross-regional statistical analysis reveals no effect of atmospherically derived sulfate ion. The median base cation denudation rates (meq m -2 yr -1) for these American lake regions are: Maine granites (108); western Adirondack felsic gneiss (85); Vermilion batholith (42); Idaho batholith (52). The regional rates are high enough to compensate for present wet deposition of acidifying anions except in some vulnerable lake watersheds in the western Adirondacks.

Initial Results from the MER Athena Science Investigation at Gusev Crater and Meridiani Planum

NASA Astrophysics Data System (ADS)

Squyres, S.

2004-05-01

The Mars Exploration Rover Spirit landed in Gusev Crater on January 4 (UTC), 2004. It was followed 21 days later by the rover Opportunity, which landed on Meridiani Planum. The landing site at Gusev crater lies on a flat, rock-strewn plain. The rock at Gusev that has been studied best to date has been named Adirondack. In its surface texture, Adirondack appears to be dense, fine-grained and sand-blasted. Three sets of measurements have been made on Adirondack with the full set of payload instruments: one of the natural rock surface, one of the same location after being brushed by the RAT, and one of the same location after removal of 2-3 mm of rock by the RAT. The concentration of presumably dust-borne elements like sulfur and chlorine diminished significantly with brushing, and diminished dramatically with grinding. All of the observations of Adirondack are consistent with it being an essentially unweathered olivine and magnetite-bearing, low-silica basalt. The only soil at Gusev that has been investigated in detail so far is one dominated by fairly coarse (100-300 micron) grains that have the appearance and behavior of well-cemented agglomerates. APXS spectra of this soil are similar to those of soils found at the Viking and Pathfinder sites. Mössbauer spectra show two ferrous doublets and a ferric doublet, with the stronger ferrous doublet assigned to olivine. Mini-TES spectra have been acquired for soils surrounding the the Spirit landing site, and show spectra nearly identical to globally averaged soil viewed by the TES instrument on Mars Global Surveyor. This includes identification of a small amount (a few percent) of carbonate. The landing site at Meridiani Planum lies inside an impact crater that is roughly 20 meters in diameter. The lander came to rest on soil that fills most of the crater. An outcrop of layered bedrock is exposed on the crater wall. The landing site was selected partly because coarse gray hematite was expected to be present on the basis of orbital data. Mini-TES data have confirmed the presence of this hematite in the soil. The soil within the crater has several components. Microscopic images of undisturbed surface soil show that one component is fine (~100 micron) sand. Mössbauer spectra of the sand show two ferrous doublets (one of them due to olivine), a ferric doublet, and a weak magnetic sextet. APXS and Mini-TES data on this sand are consistent with a composition dominated by basalt. Another component of the soil consists of coarse (several mm) granules. These range in shape from subangular to rounded to remarkably spherical. In some locations, granules have been pressed down into the soil by the impact of the landers airbags. At those locations the concentration of hematite as determined by Mini-TES is sharply reduced, suggesting that at least some of the granules are hematite-bearing. The bedrock outcrop is finely laminated, with typical layer thicknesses of only a few mm. The texture of the outcrop as viewed in miroscopic images suggests that it is fine-grained, with well-expressed structure that is revealed by varying degrees of mechanical abrasion of layers of varying induration. Initial APXS results on this fine-grained matrix indicate sulfur concentrations significantly higher than any observed elsewhere on Mars. Embedded within the outcrop and weathering out of it are highly spherical granules with diameters of several mm. The visible to near-IR spectral properties of these embedded spherical granules, as determined by Pancam, are distinctly different from those of the matrix in which they are embedded.

Response of mercury in an Adirondack (NY, USA) forest stream to watershed lime application

USGS Publications Warehouse

Millard, Geoffrey D.; Driscoll, Charles T.; Burns, Douglas; Montesdeoca, Mario R.; Murray, Karen

2018-01-01

significantly in streamwater within two weeks of treatment, to previously unobserved oncentrations. After six months, post-treatment before–after impact-control (BACI) tests indicate that mean dissolved organic carbon concentrations and total mercury to dissolved organic carbon ratios remained significantly higher and limed site fluxes of methylmercury were lower than those at the reference stream. This pattern suggests total mercury is leaching at elevated levels from the limed watershed, but limitations in production and transport to the stream channel likely resulted in increases in methylmercury concentration that were of limited duration.

Comanagement of wildlife corridors: the case for citizen participation in the Algonquin to Adirondack proposal.

PubMed

Brown, Rebecca; Harris, Glenn

2005-01-01

The debate between top-down and bottom-up planning has recently re-emerged in environmental management. Many commentators agree on the merits of comanagement, in which affected citizens and professional managers share responsibility for planning. Nevertheless, the manifold advantages of comanagement have not always been fully appreciated in environmental planning. For example, a group representing NGOs and academic institutions recently proposed an ecological corridor linking Algonquin Provincial Park in southern Ontario to the Adirondack Park in northern New York. This corridor, known as A2A, was designed to encourage the migration of wolves and other wildlife between the parks. Much of the land in A2A is private property. A survey of households, randomly scattered throughout the United States portion of the corridor, revealed that affected landowners had little knowledge of the proposal and no contact with its advocates. Many respondents were farmers who utilized land for livelihood. Other landowners enjoyed property for a variety of recreational purposes. Regardless of use, survey participants placed high value on the importance of conserving biological diversity. They also expressed great distrust toward restrictions that might be placed on their activities. In general, respondents felt very unsure about A2A, and they were uncertain about personal involvement in the planning process. Certain landowners indicated a willingness to have their land be included in an ecological corridor, despite not knowing about it before the survey was administered. These results suggest that A2A proponents have little to lose and much to gain by disseminating information locally and by embracing comanagement for further formulation of this plan.

Response of fish assemblages to decreasing acid deposition in Adirondack Mountain lakes

USGS Publications Warehouse

Baldigo, Barry P.; Roy, Karen; Driscoll, Charles T.

2016-01-01

The CAA and other federal regulations have clearly reduced emissions of NOx and SOx, acidic deposition, and the acidity and toxicity of waters in the ALTM lakes, but these changes have not triggered widespread recovery of brook trout populations or fish communities. The lack of detectable biological recovery appears to result from relatively recent chemical recovery and an insufficient period for species populations to take advantage of improved water quality. Recovery of extirpated species’ populations may simply require more time for individuals to migrate to and repopulate formerly occupied lakes. Supplemental stocking of selected species may be required in some lakes with no remnant (or nearby) populations or with physical barriers between the recovered lake and source populations. The lack of detectable biological recovery could also be related to our inability to calculate measures of uncertainty or error and, thus, examine temporal changes or differences in populations and community metrics in more depth (e.g., within individual lakes) using existing datasets. Indeed, recovery of brook trout populations and partial recovery of fish communities are documented in several lakes of the region, both with and without human intervention. Multiple fish surveys (annually or within the same year) or the use of mark and recapture methods within individual lakes would help alleviate the issue (provide measures of error for key fishery metrics) within the context of a more focused sampling strategy. Efforts to evaluate and detect recovery in fish assemblages from streams may be more effective than in lakes because various life stages, species’ populations, and entire assemblages are easier to quantify, with known levels of error, in streams than in lakes. Such long-term monitoring efforts could increase our ability to detect and quantify biological recovery in recovering (neutralizing) surface waters throughout the Adirondack Region.

Spectral variability among rocks in visible and near-infrared mustispectral Pancam data collected at Gusev crater: Examinations using spectral mixture analysis and related techniques

USGS Publications Warehouse

Farrand, W. H.; Bell, J.F.; Johnson, J. R.; Squyres, S. W.; Soderblom, J.; Ming, D. W.

2006-01-01

Visible and near-infrared (VNIR) multispectral observations of rocks made by the Mars Exploration Rover Spirit's Panoramic camera (Pancam) have been analyzed using a spectral mixture analysis (SMA) methodology. Scenes have been examined from the Gusev crater plains into the Columbia Hills. Most scenes on the plains and in the Columbia Hills could be modeled as three end-member mixtures of a bright material, rock, and shade. Scenes of rocks disturbed by the rover's Rock Abrasion Tool (RAT) required additional end-members. In the Columbia Hills, there were a number of scenes in which additional rock end-members were required. The SMA methodology identified relatively dust-free areas on undisturbed rock surfaces as well as spectrally unique areas on RAT abraded rocks. Spectral parameters from these areas were examined, and six spectral classes were identified. These classes are named after a type rock or area and are Adirondack, Lower West Spur, Clovis, Wishstone, Peace, and Watchtower. These classes are discriminable based, primarily, on near-infrared (NIR) spectral parameters. Clovis and Watchtower class rocks appear more oxidized than Wishstone class rocks and Adirondack basalts based on their having higher 535 nm band depths. Comparison of the spectral parameters of these Gusev crater rocks to parameters of glass-dominated basaltic tuffs indicates correspondence between measurements of Clovis and Watchtower classes but divergence for the Wishstone class rocks, which appear to have a higher fraction of crystalline ferrous iron-bearing phases. Despite a high sulfur content, the rock Peace has NIR properties resembling plains basalts. Copyright 2006 by the American Geophysical Union.

Application of lime (CaCO3) to promote forest recovery from severe acidification increases potential for earthworm invasion

USGS Publications Warehouse

Homan, Caitlin; Beirer, Colin M; McCay, Timothy S; Lawrence, Gregory B.

2016-01-01

The application of lime (calcium carbonate) may be a cost-effective strategy to promote forest ecosystem recovery from acid impairment, under contemporary low levels of acidic deposition. However, liming acidified soils may create more suitable habitat for invasive earthworms that cause significant damage to forest floor communities and may disrupt ecosystem processes. We investigated the potential effects of liming in acidified soils where earthworms are rare in conjunction with a whole-ecosystem liming experiment in the chronically acidified forests of the western Adirondacks (USA). Using a microcosm experiment that replicated the whole-ecosystem treatment, we evaluated effects of soil liming on Lumbricus terrestris survivorship and biomass growth. We found that a moderate lime application (raising pH from 3.1 to 3.7) dramatically increased survival and biomass of L. terrestris, likely via increases in soil pH and associated reductions in inorganic aluminum, a known toxin. Very few L. terrestris individuals survived in unlimed soils, whereas earthworms in limed soils survived, grew, and rapidly consumed leaf litter. We supplemented this experiment with field surveys of extant earthworm communities along a gradient of soil pH in Adirondack hardwood forests, ranging from severely acidified (pH < 3) to well-buffered (pH > 5). In the field, no earthworms were observed where soil pH < 3.6. Abundance and species richness of earthworms was greatest in areas where soil pH > 4.4 and human dispersal vectors, including proximity to roads and public fishing access, were most prevalent. Overall our results suggest that moderate lime additions can be sufficient to increase earthworm invasion risk where dispersal vectors are present.

Hydrogeologic controls of surface-water chemistry in the Adirondack region of New York State

USGS Publications Warehouse

Peters, N.E.; Driscoll, C.T.

1987-01-01

Relationships between surface-water discharge, water chemistry, and watershed geology were investigated to evaluate factors affecting the sensitivity of drainage waters in the Adirondack region of New York to acidification by atmospheric deposition. Instantaneous discharge per unit area was derived from relationships between flow and staff-gage readings at 10 drainage basins throughout the region. The average chemical composition of the waters was assessed from monthly samples collected from July 1982 through July 1984. The ratio of flow at the 50-percent exceedence level to the flow at the 95-percent exceedence level of flow duration was negatively correlated with mean values of alkalinity or acid-neutralizing capacity (ANC), sum of basic cations (SBC), and dissolved silica, for basins containing predominantly aluminosilicate minerals and little or no carbonate-bearing minerals. Low ratios are indicative of systems in which flow is predominately derived from surface- and ground-water storage, whereas high ratios are characteristic of watersheds with variable flow that is largely derived from surface runoff. In an evaluation of two representative surface-water sites, concentrations of ANC, SBC, and dissolved silica, derived primarily from soil mineral weathering reactions. decreased with increasing flow. Furthermore, the ANC was highest at low flow when the percentage of streamflow derived from ground water was maximum. As flow increased, the ANC decreased because the contribution of dilute surface runoff and lateral flow through the shallow acidic soil horizons to total flow increased. Basins having relatively high ground-water contributions to total flow, in general, have large deposits of thick till or stratified drift. A major factor controlling the sensitivity of these streams and lakes to acidification is the relative contribution of ground water to total discharge. ?? 1987 Martinus Nijhoff/Dr W. Junk Publishers.

13C 12C exchange between calcite and graphite: A possible thermometer in Grenville marbles

USGS Publications Warehouse

Valley, J.W.; O'Neil, J.R.

1981-01-01

The fractionation of 13C between calcite and graphite, ??(Cc-Gr). is consistently small (2.6-4.8 permil) in 34 assemblages from upper amphibolite- and granulite-facies marbles of the Grenville Province. In 25 samples from the Adirondack Mountains, New York, it decreases regularly with increasing metamorphic temperature. The fractionations are independent of absolute ??13C values of calcite (-2.9 to +5.0). For T = 600-800??C, the Adirondack data are described by ??(Cc-Gr) = -0.00748T (??C) + 8.68. This good correlation between ?? and T suggests that carbon isotope equilibrium was attained in these high-grade marbles and that the theoretical calculations of this fractionation by Bottinga are approximately 2 permil too large in this temperature range. Because of the relatively high temperature sensitivity suggested by these results and by Bottinga's calculations, and the pressure independence of isotope fractionation, ??(Cc-Gr) may provide a very good thermometer for high-grade marbles. Comparison of this field calibration for ??(Cc-Gr) vs temperature with results from other terranes supports the utility of ??(Cc-Gr) for geothermometry and suggests that graphite is much more sluggish to exchange than calcite, that exchange between calcite and graphite occurs at temperatures as low as 300??C, and that equilibrium may normally be attained only when peak metamorphic temperatures are greater than 500-600??C. Because 13C exchange is an unavoidable metamorphic process at temperatures above 300??C, high values of ??13C(Gr) in moderate- to high-grade carbonate-bearing rocks do not provide a sufficient criterion to infer an abiogenic origin for the graphite. ?? 1981.

Engineering Condition Survey and Evaluation of Troy Lock and Dam, Hudson River, New York Report 2. Evaluation and Rehabilitation.

DTIC Science & Technology

1981-01-01

boats in both the spring and fall make seasonal trips from the sunny south to the more mountainous , wooded north, as well as completing many short...back- ground of Troy Lock and Dam 8. The Hudson River originates in the Adirondack Mountains in northern New York State among the highest peaks of the...0.00 0.00 0.00 ___ ___ __ ___ ___ __ __is_ B C BC 25.24 34.14 0.00 0.00 C 25.24 36.00 0. 00 0.06 &M~E ALEA D 3.45 36.00 0.00 6.10 E 3.45 17.00 0.00

Application of a continuous distribution model for proton binding by humic acids extracted from acidic lake sediments

NASA Astrophysics Data System (ADS)

Rhea, James R.; Young, Thomas C.

1987-10-01

The proton binding characteristics of humic acids extracted from the sediments of Cranberry Pond, an acidic water body located in the Adirondack Mountain region of New York State, were explored by the application of a multiligand distribution model. The model characterizes a class of proton binding sites by mean log K values and the standard deviations of log K values about the mean. Mean log K values and their relative abundances were determined directly from experimental titration data. The model accurately predicts the binding of protons by the humic acids for pH values in the range 3.5 to 10.0.

Application of a continuous distribution model for proton binding by humic acids extracted from acidic lake sediments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rhea, J.R.; Young, T.C.

1987-01-01

The proton binding characteristics of humic acids extracted from the sediments of Cranberry Pond, an acidic water body located in the Adirondack Mountain region of New York State, were explored by the application of a nultiligand distribution model. The model characterizes a class of proton binding sites by mean log K values and the standard deviations of log K values and the mean. Mean log K values and their relative abundances were determined directly from experimental titration data. The model accurately predicts the binding of protons by the humic acids for pH values in the range 3.5 to 10.0.

Spirit's First Grinding of a Rock on Mars

NASA Technical Reports Server (NTRS)

2004-01-01

The round, shallow depression in this image resulted from history's first grinding of a rock on Mars. The rock abrasion tool on NASA's Spirit rover ground off the surface of a patch 45.5 millimeters (1.8 inches) in diameter on a rock called Adirondack. The hole is 2.65 millimeters (0.1 inch) deep, exposing fresh interior material of the rock for close inspection with the rover's microscopic imager and two spectrometers on the robotic arm. This image was taken by Spirit's panoramic camera, providing a quick visual check of the success of the grinding. The rock abrasion tools on both Mars Exploration Rovers were supplied by Honeybee Robotics, New York, N.Y.

Basaltic Soil of Gale Crater: Crystalline Component Compared to Martian Basalts and Meteorites

NASA Technical Reports Server (NTRS)

Treiman, A. H.; Bish, D. L.; Ming, D. W.; Morris, R. V.; Schmidt, M.; Downs, R. T.; Stolper, E. M.; Blake, D. F.; Vaniman, D. T.; Achilles, C. N.;

Modeled effects of soil acidification on long-term ecological and economic outcomes for managed forests in the Adirondack region (USA).

PubMed

Caputo, Jesse; Beier, Colin M; Sullivan, Timothy J; Lawrence, Gregory B

2016-09-15

Sugar maple (Acer saccharum) is among the most ecologically and economically important tree species in North America, and its growth and regeneration is often the focus of silvicultural practices in northern hardwood forests. A key stressor for sugar maple (SM) is acid rain, which depletes base cations from poorly-buffered forest soils and has been associated with much lower SM vigor, growth, and recruitment. However, the potential interactions between forest management and soil acidification - and their implications for the sustainability of SM and its economic and cultural benefits - have not been investigated. In this study, we simulated the development of 50 extant SM stands in the western Adirondack region of NY (USA) for 100years under different soil chemical conditions and silvicultural prescriptions. We found that interactions between management prescription and soil base saturation will strongly shape the ability to maintain SM in managed forests. Below 12% base saturation, SM did not regenerate sufficiently after harvest and was replaced mainly by red maple (Acer rubrum) and American beech (Fagus grandifolia). Loss of SM on acid-impaired sites was predicted regardless of whether the shelterwood or diameter-limit prescriptions were used. On soils with sufficient base saturation, models predicted that SM will regenerate after harvest and be sustained for future rotations. We then estimated how these different post-harvest outcomes, mediated by acid impairment of forest soils, would affect the potential monetary value of ecosystem services provided by SM forests. Model simulations indicated that a management strategy focused on syrup production - although not feasible across the vast areas where acid impairment has occurred - may generate the greatest economic return. Although pollution from acid rain is declining, its long-term legacy in forest soils will shape future options for sustainable forestry and ecosystem stewardship in the northern hardwood forests of North America. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

Charnockites and granites of the western Adirondacks, New York, USA: a differentiated A-type suite

USGS Publications Warehouse

Whitney, P.R.

1992-01-01

Granitic rocks in the west-central Adirondack Highlands of New York State include both relatively homogeneous charnockitic and hornblende granitic gneisses (CG), that occur in thick stratiform bodies and elliptical domes, and heterogeneous leucogneisses (LG), that commonly are interlayered with metasedimentary rocks. Major- and trace-element geochemical analyses were obtained for 115 samples, including both types of granitoids. Data for CG fail to show the presence of more than one distinct group based on composition. Most of the variance within the CG sample population is consistent with magmatic differentiation combined with incomplete separation of early crystals of alkali feldspar, plagioclase, and pyroxenes or amphibole from the residual liquid. Ti, Fe, Mg, Ca, P, Sr, Ba, and Zr decrease with increasing silica, while Rb and K increase. Within CG, the distinction between charnockitic (orthopyroxene-bearing) and granitic gneisses is correlated with bulk chemistry. The charnockites are consistently more mafic than the hornblende granitic gneisses, although forming a continuum with them. The leucogneisses, while generally more felsic than the charnockites and granitic gneisses, are otherwise geochemically similar to them. The data are consistent with the LG suite being an evolved extrusive equivalent of the intrusive CG suite. Both CG and LG suites are metaluminous to mildly peraluminous and display an A-type geochemical signature, enriched in Fe, K, Ce, Y, Nb, Zr, and Ga and depleted in Ca, Mg, and Sr relative to I- and S-type granites. Rare earth element patterns show moderate LREE enrichment and a negative Eu anomaly throughout the suite. The geochemical data suggest an origin by partial melting of biotite- and plagioclase-rich crustal rocks. Emplacement occurred in an anorogenic or post-collisional tectonic setting, probably at relatively shallow depths. Deformation and granulite-facies metamorphism with some partial melting followed during the Ottawan phase of the Grenville Orogeny, yielding the present migmatitic granitic and charnockitic gneisses. ?? 1992.

Modeled effects of soil acidification on long-term ecological and economic outcomes for managed forests in the Adirondack region (USA)

USGS Publications Warehouse

Caputo, Jesse PhD.; Beier, Colin M.; Sullivan, Timothy J.; Lawrence, Gregory B.

2016-01-01

Sugar maple (Acer saccharum) is among the most ecologically and economically important tree species in North America, and its growth and regeneration is often the focus of silvicultural practices in northern hardwood forests. A key stressor for sugar maple (SM) is acid rain, which depletes base cations from poorly-buffered forest soils and has been associated with much lower SM vigor, growth, and recruitment. However, the potential interactions between forest management and soil acidification – and their implications for the sustainability of SM and its economic and cultural benefits – have not been investigated. In this study, we simulated the development of 50 extant SM stands in the western Adirondack region of NY (USA) for 100 years under different soil chemical conditions and silvicultural prescriptions. We found that interactions between management prescription and soil base saturation will strongly shape the ability to maintain SM in managed forests. Below 12% base saturation, SM did not regenerate sufficiently after harvest and was replaced mainly by red maple (Acer rubrum) and American beech (Fagus grandifolia). Loss of SM on acid-impaired sites was predicted regardless of whether the shelterwood or diameter-limit prescriptions were used. On soils with sufficient base saturation, models predicted that SM will regenerate after harvest and be sustained for future rotations. We then estimated how these different post-harvest outcomes, mediated by acid impairment of forest soils, would affect the potential monetary value of ecosystem services provided by SM forests. Model simulations indicated that a management strategy focused on syrup production – although not feasible across the vast areas where acid impairment has occurred – may generate the greatest economic return. Although pollution from acid rain is declining, its long-term legacy in forest soils will shape future options for sustainable forestry and ecosystem stewardship in the northern hardwood forests of North America.

Nitrogen solutes in an Adirondack forested watershed: Importance of dissolved organic nitrogen

USGS Publications Warehouse

McHale, M.R.; Mitchell, M.J.; McDonnell, Jeffery J.; Cirmo, C.P.

2000-01-01

Nitrogen (N) dynamics were evaluated from 1 June 1995 through 31 May 1996 within the Arbutus Lake watershed in the Adirondack Mountains of New York State, U.S.A. At the Arbutus Lake outlet dissolved organic nitrogen (DON), NO3/- and NH4/+ contributed 61%, 33%, and 6% respectively, to the total dissolved nitrogen (TDN) flux (259 mol ha-1 yr-1). At the lake inlet DON, NO3/-, and NH4/+ constituted 36%, 61%, and 3% respectively, of TDN flux (349 mol ha-1 yr-1). Differences between the factors that control DON, NO3/-, and NH4+ stream water concentrations were evaluated using two methods for estimating annual N flux at the lake inlet. Using biweekly sampling NO3/- and NH4/+ flux was 10 and 4 mol ha-1 yr-1 respectively, less than flux estimates using biweekly plus storm and snowmelt sampling. DON flux was 18 mol ha-1 yr-1 greater using only biweekly sampling. These differences are probably not of ecological significance relative to the total flux of N from the watershed (349 mol ha-1 yr-1). Dissolved organic N concentrations were positively related to discharge during both the dormant (R2 = 0.31; P<0.01) and growing season (R2= 0.09; P<0.01). There was no significant relationship between NO3/- concentration and discharge during the dormant season, but a significant negative relationship was found during the growing season (R2 = 0.29; P<0.01). Biotic controls in the growing season appeared to have had a larger impact on stream water NO3- concentrations than on DON concentrations. Arbutus Lake had a major impact on stream water N concentrations of the four landscape positions sampled, suggesting the need to quantify within lake processes to interpret N solute losses and patterns in watershed-lake systems.

Wetlands serve as natural sources for improvement of stream ecosystem health in regions affected by acid deposition

USGS Publications Warehouse

Pound, Katrina L; Lawrence, Gregory B.; Passy, Sophia I.

2013-01-01

For over 40 years, acid deposition has been recognized as a serious international environmental problem, but efforts to restore acidified streams and biota have had limited success. The need to better understand the effects of different sources of acidity on streams has become more pressing with the recent increases in surface water organic acids, or 'brownification' associated with climate change and decreased inorganic acid deposition. Here, we carried out a large scale multi-seasonal investigation in the Adirondacks, one of the most acid-impacted regions in the United States, to assess how acid stream producers respond to local and watershed influences and whether these influences can be used in acidification remediation. We explored the pathways of wetland control on aluminum chemistry and diatom taxonomic and functional composition. We demonstrate that streams with larger watershed wetlands have higher organic content, lower concentrations of acidic anions, and lower ratios of inorganic to organic monomeric aluminum, all beneficial for diatom biodiversity and guilds producing high biomass. Although brownification has been viewed as a form of pollution, our results indicate that it may be a stimulating force for biofilm producers with potentially positive consequences for higher trophic levels. Our research also reveals that the mechanism of watershed control of local stream diatom biodiversity through wetland export of organic matter is universal in running waters, operating not only in hard streams, as previously reported, but also in acid streams. Our findings that the negative impacts of acid deposition on Adirondack stream chemistry and biota can be mitigated by wetlands have important implications for biodiversity conservation and stream ecosystem management. Future acidification research should focus on the potential for wetlands to improve stream ecosystem health in acid-impacted regions and their direct use in stream restoration, for example, through stream rechanneling or wetland construction in appropriate hydrologic settings.

Atmospheric Science Research at the Whiteface Mountain Adirondack High Peaks Observatory

NASA Astrophysics Data System (ADS)

Schwab, J. J.; Brandt, R. E.; Casson, P.; Demerjian, K. L.; Crandall, B. A.

2014-12-01

The Atmospheric Sciences Research Center established an atmospheric observatory at Whiteface Mountain in the Adirondacks in 1961. The current mountain top observatory building was built by the University at Albany in 1969-70 and the New York State Department of Environmental Conservation (DEC) began ozone measurements at this summit location in 1973. Those measurements continue to this day and constitute a valuable long term data record for tropospheric ozone in the northeastern U.S. The elevation of the summit is 1483 m above sea level, and is roughly 90 m above the tree line in this location. With a mean cloud base height of less than 1100 m at the summit, it is a prime location for cloud research. The research station headquarters, laboratories, offices, and a second measurement site are located at the Marble Mountain Lodge, perched on a shoulder northeast of the massif at an elevation of 604 m above sea level. Parameters measured at the site include meteorological variables, trace gases, precipitation chemistry, aerosol mass and components, and more. Precipitation and cloud chemistry has a long history at the lodge and summit locations, respectively, and continues to this day. Some data from the 40-year record will be shown in the presentation. In the late 1980's the summit site was outfitted with instrumentation to measure oxides of nitrogen and other ozone precursors. Measurements of many of these same parameters were added at the lodge site and continue to this day. In this poster we will give an overview of the Whiteface Mountain Observatory and its two measurement locations. We will highlight the parameters currently being measured at our sites, and indicate those measured by ASRC, as well as those measured by other organizations. We will also recap some of the historical activities and measurement programs that have taken place at the site, as alluded to above. Also included will be examples of the rich archive of trends data for gas phase species, precipitation chemistry, and particulate matter.

First Grinding of a Rock on Mars

NASA Technical Reports Server (NTRS)

2004-01-01

The round, shallow depression in this image resulted from history's first grinding of a rock on Mars. The rock abrasion tool on NASA's Spirit rover ground off the surface of a patch 45.5 millimeters (1.8 inches) in diameter on a rock called Adirondack during Spirit's 34th sol on Mars, Feb. 6, 2004. The hole is 2.65 millimeters (0.1 inch) deep, exposing fresh interior material of the rock for close inspection with the rover's microscopic imager and two spectrometers on the robotic arm. This image was taken by Spirit's panoramic camera, providing a quick visual check of the success of the grinding. The rock abrasion tools on both Mars Exploration Rovers were supplied by Honeybee Robotics, New York, N.Y.

Earthquake prediction; new studies yield promising results

USGS Publications Warehouse

Robinson, R.

1974-01-01

On Agust 3, 1973, a small earthquake (magnitude 2.5) occurred near Blue Mountain Lake in the Adirondack region of northern New York State. This seemingly unimportant event was of great significance, however, because it was predicted. Seismologsits at the Lamont-Doherty geologcal Observatory of Columbia University accurately foretold the time, place, and magnitude of the event. Their prediction was based on certain pre-earthquake processes that are best explained by a hypothesis known as "dilatancy," a concept that has injected new life and direction into the science of earthquake prediction. Although much mroe reserach must be accomplished before we can expect to predict potentially damaging earthquakes with any degree of consistency, results such as this indicate that we are on a promising road. 

New York State Police remote communications site small wind energy conversion system. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1985-03-01

This report concludes a year-long demonstration and study of the use of a North Wind Model HR2 wind energy conversion system to supply the power for a remote New York State Police microwave repeater site at Mt. Morris in the Adirondack Mountains. Data were collected on a multi-channel digital strip chart recorder which provided a printout of the real-time relation between windspeed, power output, battery capacity and voltage, and contribution from backup power. These data proved that the site could be run on wind power alone and predictions can now be made on the performance of an HR2 or similarmore » wind system at other sites. 5 figs., 1 tab.« less

The Road to 'Bonneville'

NASA Technical Reports Server (NTRS)

2004-01-01

This false-color panoramic camera composite traverse map depicts the Mars Exploration Rover Spirit's journey since landing at Gusev Crater, Mars. It was generated from three of the camera's different wavelength filters (750 nanometers, 530 nanometers and 480 nanometers). This map was created on the 65th martian day, or sol, of Spirit's mission, after Spirit had traveled 328 meters (1076 feet) from its lander to the rim of the crater dubbed 'Bonneville.' From this high point, Spirit was able to capture with its panoramic camera the entire rover traverse. The map points out major stops that Spirit made along the way, including features nicknamed 'Adirondack;' 'Stone Council;' 'Laguna Hollow;' and 'Humphrey.' Also highlighted is the landscape feature informally named 'Grissom Hill' and Spirit's landing site, the Columbia Memorial Station.

Acid rain stone test sites

NASA Astrophysics Data System (ADS)

Sherwood, Susan I.; Doe, Bruce R.

1984-04-01

As a part of the United States National Acid Precipitation Assessment Program, Task Group G: Effects on Materials and Cultural Resources, which is chaired by Ray Herrmann, the National Park Service has established four test sites for 10-year testing of two kinds of dimension stone used in buildings and monuments. The four sites are (from south to north) Research Triangle Park near Raleigh, N.C. (activated May 25, 1984); the roof of the West End Branch of the Washington, D.C. Library (activated August 11, 1984); the Department of Energy Compound at the Environmental Measurements Laboratory of Bell Telephone Laboratories near Chester, N.J. (activated June 5, 1984); and Huntington Wildlife Forest in the Adirondack Mountains, Newcomb, N.Y. (activated June 19, 1984).

Hydrologic Analyses of Acidic and Alkaline Lakes

NASA Astrophysics Data System (ADS)

Chen, C. W.; Gherini, S. A.; Peters, N. E.; Murdoch, P. S.; Newton, R. M.; Goldstein, R. A.

1984-12-01

Woods and Panther lakes in the Adirondack Mountains of New York respond differently to the same acidic deposition. A mathematical model study has shown that lake water becomes acidic when hydrologic conditions force precipitation to flow to the lakes as surface flow or as lateral flow through the shallow organic soil horizon. Hydrographic data, capacity of flow through inorganic soil horizons, runoff recession curves, and groundwater level fluctuations of Woods and Panther lake basins provide independent evidence to support the thesis that the acidic state of a lake depends on the paths the tributary water takes as it passes thorough the terrestrial system. It is concluded thot Panther Lake is more alkaline than Woods Lake, because a larger proportion of the precipitation falling on the basin passes through deeper mineral soil horizons.

Ti-in-Zircon Thermometer: Preliminary Results

NASA Astrophysics Data System (ADS)

Fu, B.; Cavosie, A. J.; Clechenko, C. C.; Fournelle, J.; Kita, N. T.; Lackey, J.; Page, F.; Wilde, S. A.; Valley, J. W.

2005-12-01

The titanium in zircon thermometer has been applied to 167 zircons from diverse rock types. These rocks include metamorphosed anorthosite and gabbro (1.15 Ga, intrusion age), and unmetamorphosed granitic pegmatite (0.9 Ga) from the Adirondack Highlands; metaluminous and peraluminous granites (114-90 Ma) of the Sierra Nevada Batholith; megacrysts from kimberlite pipes in southern Africa, Brazil, and Siberia; and detrital zircons (4.4-3.9 Ga) of metaconglomerate from Jack Hills, Western Australia. Titanium concentration in zircon was analysed using a CAMECA IMS-1280 ion microprobe (see Page et al., this volume). Spot analyses were correlated to U-Pb SHRIMP pits especially for Adirondack and Jack Hills zircons. The majority of zircons have Ti-content less than 10 ppm. Variability, in excess of analytical precision, within individual zircons is observed in about one-third of crystals. In general, there is no systematic change in Ti from core to rim (identified by cathodoluminescence) of zircons, or with regard to age, U content, Th/U ratio, or U-Pb age concordance for these non-metamict grains. The average temperatures for zircon crystallization in different rock suites using the experimental/empirical calibration of Watson and Harrison (W&H, 2005, Science 308:841), assuming the presence of rutile and quartz, are estimated to be: anorthosite 735±41°C (1SD, n=24; Ti = 10±5 ppm); metagabbro 714±31°C (n=19; Ti = 8±4 ppm); Adirondack pegmatite 500±16°C (n=5; Ti = 0.3±0.1 ppm); metaluminous and peraluminous granites from Sierra Nevada 681±67°C (n=53; Ti = 6±5 ppm) and 613±75°C (n=68; Ti = 3±3 ppm); kimberlite megacrysts 740±64°C (n=169; Ti = 14±13 ppm) (Page et al., this volume); and detrital zircons from Jack Hills metaconglomerate 718±63°C (n=64; Ti = 10±9 ppm). Most of the host rocks contain ilmenite or titanite suggesting that α(TiO2)>0.5, but rutile activity is unknown for megacrysts and detrital zircons. Pegmatite contains no Ti-rich minerals, permissive of low rutile activity. Peraluminous granites have lower whole-rock TiO2 content (0.02-0.21 wt.%) than metaluminous granites (0.54-0.91 wt.%), and both have similar zircon saturation temperatures (710-780°C). The low Ti content and apparent temperature in zircons from anorthosite and metagabbro (magmatic T = ca. 1000-1100°C) and the homogeneity of igneous zircon cores vs. metamorphic rims in metagabbro suggest that Ti content was reset during granulite-facies metamorphism (750°C, 1.0 Ga), in contrast to the current estimate of extremely low diffusivity of Ti in zircon. The Ti contents of >3.9 Ga Jack Hills detrital zircons are consistent with previously published data that were used to constrain magmatic temperature and thus the composition of unknown host rocks (W&H, 2005, Science 308:841). However, these values overlap those from both felsic and mafic rocks, and the Ti data are not sufficient to independently identify parent melt chemistry unless post-crystallization changes can be ruled out. The best evidence of pre-4 Ga evolved crust is provided by previously reported oxygen isotope ratios and felsic mineral inclusions in zircon (see Cavosie et al., 2005, EPSL 235:663).

Tracking hydrothermal alteration and mineralization in rock-forming and accessory minerals from the Lyon Mountain Granite and related iron oxide apatite (IOA) ores from the Adirondack Mountains, New York State

NASA Astrophysics Data System (ADS)

Buchanan, A.; Hanchar, J. M.; Steele-MacInnis, M. J.; Crowley, J. L.; Valley, P. M.; Fisher, C. M.; Fedo, C.; Piccoli, P. M.; Fournelle, J.

2012-12-01

The Lyon Mountain granite (LMG) is located in the northeastern Adirondack Mountains in New York State and hosts several low-titanium iron oxide apatite (IOA) ore deposits. The ores are predominately hosted by perthite bearing granite, which has been extensively altered to albite and microcline granite by Na and K metasomatism. This alteration results in several distinct groups of rocks that are dominated by either K or Na addition and a group composed of mixed Na and K addition. The different groups of altered perthite also lie on a trend suggestive of addition of Fe to each, consistent with a secondary mineralization origin. Previous work showed that the host rocks of the IOA ores have zircon with ~1150 Ma cores and 1060-1050 Ma rims and whole grains. This study aims to further constrain the timing of LMG emplacement, subsequent hydrothermal alteration, and Fe mineralization through geochemical analysis of the major, minor, and accessory phases and geochronology of accessory phases. SIMS analyses of zircon from several of the IOA ores reveal at least two periods of growth after LMG magmatism, at 1039 +/- 4.4 Ma and 1016 +/- 7 Ma to 1000 +/- 9 Ma. In situ EMPA and LA-ICPMS trace element analyses of the zircon rims and cores reveal that in two samples the zircon rims are enriched in rare earth elements (REE) compared to their cores, potentially pointing to a hydrothermal origin. Apatite has unusually high REE and Y concentrations (some total REE2O3 > 20 wt. % oxide and up to 8 wt. % oxide Y2O3), as does titanite, which allowed for the in situ analysis of Sm-Nd in apatite and titanite by LA-MC-ICP-MS. Initial Nd isotopic composition of both ore and host rock apatite and host rock titanite are consistent with published Adirondack initial Nd whole rock data, suggesting a local source for REE in these ores. EMPA and LA-ICPMS trace-element analyses of the major rock-forming minerals indicate that the feldspar have undergone Na-metasomatism and are depleted in REEs, perhaps signifying the "local source" and the mechanism of the REE enrichment in the LMG apatite in the IOA ores and host rocks. In contrast, the minor- and trace-element compositions of the other major rock-forming minerals (e.g., clinopyroxene and fayalite) as well as the zircon, and fluorite in the LMG have average igneous granitic trace- and minor-element compositions. To better understand the timing and origin of these post ~1050 Ma events, U-Pb ID-TIMS dating of apatite and titanite, and in situ LA-MC-ICPMS Sm-Nd analysis were done on the ore and host rock samples. Apatite dates range from 1050 to 850 Ma and titanite dates range from ~1015 to 970 Ma. There is significant age variation within samples and within grains. Titanite does not have sufficient spread for accurate Sm-Nd isochron dating and two ore-apatite samples have homogenous initial Nd isotopic and Sm-Nd elemental ratios, precluding calculation of Sm-Nd dates. A third ore sample shows a large spread in Sm-Nd and yields a Sm-Nd isochron date of ~850 Ma, in close agreement with U-Pb apatite dates. The Sm-Nd isochron and U-Pb apatite dates may reflect cooling recorded in these minerals or a younger hydrothermal mineralization event.

Mature and old-growth riparian forests: structure, dynamics, and effects on Adirondack stream habitats.

PubMed

Keeton, William S; Kraft, Clifford E; Warren, Dana R

2007-04-01

Riparian forests regulate linkages between terrestrial and aquatic ecosystems, yet relationships among riparian forest development, stand structure, and stream habitats are poorly understood in many temperate deciduous forest systems. Our research has (1) described structural attributes associated with old-growth riparian forests and (2) assessed linkages between these characteristics and in-stream habitat structure. The 19 study sites were located along predominantly first- and second-order streams in northern hardwood-conifer forests in the Adirondack Mountains of New York (U.S.A.). Sites were classified as mature forest (6 sites), mature with remnant old-growth trees (3 sites), and old-growth (10 sites). Forest-structure attributes were measured over stream channels and at varying distances from each bank. In-stream habitat features such as large woody debris (LWD), pools, and boulders were measured in each stream reach. Forest structure was examined in relation to stand age using multivariate techniques, ANOVA, and linear regression. We investigated linkages between forest structure and stream characteristics using similar methods, preceded by information-theoretic modeling (AIC). Old-growth riparian forest structure is more complex than that found in mature forests and exhibits significantly greater accumulations of aboveground tree biomass, both living and dead. In-stream LWD volumes were significantly (alpha = 0.05) greater at old-growth sites (200 m3/ha) compared to mature sites (34 m3/ha) and were strongly related to the basal area of adjacent forests. In-stream large-log densities correlated strongly with debris-dam densities. AIC models that included large-log density, debris-dam density, boulder density, and bankfull width had the most support for predicting pool density. There were higher proportions of LWD-formed pools relative to boulder-formed pools at old-growth sites as compared to mature sites. Old-growth riparian forests provide in-stream habitat features that have not been widely recognized in eastern North America, representing a potential benefit from late-successional riparian forest management and conservation. Riparian management practices (including buffer delineation and restorative silvicultural approaches) that emphasize development and maintenance of late-successional characteristics are recommended where the associated in-stream effects are desired.

Effects of acid deposition on dissolution of carbonate stone during summer storms in the Adirondack Mountains, New York, 1987-89

USGS Publications Warehouse

Schuster, Paul F.; Reddy, Michael M.; Sherwood, S.I.

1994-01-01

This study is part of a long-term research program designed to identify and quantify acid rain damage to carbonate stone. Acidic deposition accelerates the dissolution of carbonate-stone monuments and building materials. Sequential sampling of runoff from carbonate-stone (marble) and glass (reference) microcatchments in the Adirondack Mountains in New York State provided a detailed record of the episodic fluctuations in rain rate and runoff chemistry during individual summer storms. Rain rate and chemical concentrations from carbonate-stone and glass runoff fluctuated three to tenfold during storms. Net calcium-ion concentrations from the carbonatestone runoff, a measure of stone dissolution, typically fluctuated twofold during these storms. High net sulfate and net calcium concentrations in the first effective runoff at the start of a storm indicated that atmospheric pollutants deposited on the stone surface during dry periods formed calcium sulfate minerals, an important process in carbonate stone dissolution. Dissolution of the carbonate stone generally increased up to twofold during coincident episodes of low rain rate (less than 5 millimeters per hour) and decreased rainfall (glass runoff) pH (less than 4.0); episodes of high rain rate (cloudbursts) were coincident with a rapid increase in rainfall pH and also a rapid decrease in the dissolution of carbonate-stone. During a storm, it seems the most important factors causing increased dissolution of carbonate stone are coincident periods of low rain rate and decreased rainfall pH. Dissolution of the carbonate stone decreased slightly as the rain rate exceeded about 5 millimeters per hour, probably in response to rapidly increasing rainfall pH during episodes of high rain rate and shorter contact time between the runoff and the stone surface. High runoff rates resulting from cloudbursts remove calcium sulfate minerals formed during dry periods prior to storms and also remove dissolution products formed in large measure by chemical weathering as a result of episodes of low rain rate and decreased rainfall pH during a storm.

Of Paleo-Genes and Perch: What if an “Alien” Is Actually a Native?

PubMed Central

Stager, J. Curt; Sporn, Lee Ann; Johnson, Melanie; Regalado, Sean

2015-01-01

Documenting whether a biotic taxon is native or alien to an ecosystem has theoretical value for ecological and evolutionary studies, and has practical value because it can potentially identify a taxon as a desirable component of an ecosystem or target it for removal. In some cases, however, such background information is inadequate or unavailable. Here we use paleo-DNA to re-evaluate the historical status of yellow perch in the 6 million acre Adirondack State Park of northern New York. Yellow perch DNA in a 2200-year sediment record reveals a long-term native status for these supposedly alien fish and challenges assumptions that they necessarily exclude native trout from upland lakes. Similar approaches could be applied to other species with uncertain historical distributions and could help to identify unrecognized pockets of biodiversity. PMID:25751263

Estimating forest productivity with Thematic Mapper and biogeographical data

NASA Technical Reports Server (NTRS)

Cook, Elizabeth A.; Iverson, Louis R.; Graham, Robin L.

1989-01-01

Spectral data from the Landsat Thematic Mapper (TM) on three forest exosystems (the southern Illinois, the Great Smoky Mountains regions in Tennessee and North Carolina, and the central Adirondack Mountains in New York) were used in conjunction with ground-collected measures of forest productivity and such information as the area's slope, aspect, elevation, and soil and vegetation types, to develop models of regional forest productivity. It is shown that the models developed may be used to estimate the productivity of a region with a high degree of confidence, but that the reliability of single-pixel estimates is poor. The characteristics of a given ecosystem determine which spectral values are most closely related to forest productivity. Thus, mid-IR, NIR, and visible bands are most significant in Illinois and New York, while the thermal band is relatively more important in the Smokies.

Proterozoic low-Ti iron-oxide deposits in New York and New Jersey: relation to Fe-oxide (Cu-U-Au-rare earth element) deposits and tectonic implications

USGS Publications Warehouse

Foose, M.P.; McLelland, J.M.

1995-01-01

Low-Ti iron-oxide deposits in exposed Grenville-age rocks of New York and New Jersey belong to a distinct class of iron-oxide (Cu-U-Au-rare earth element [REE]) deposits that includes similar iron deposits in southeastern Missouri and the Kiruna district of Sweden, the giant Olympic Dam U-Cu-Au-Ag deposit (Australia), and the Bayan Obo REE-Nb deposit (China). Most of the New York-New Jersey deposits exhibit features consistent with a hydrothermal origin and define a regionally significant metallogenic event that provides important clues to the evolution of this part of the Grenville orogen. In the Adirondacks, the tectonic setting of these deposits is consistent with postorogenic uplift and extensive crustal melting at 1070-1050 Ma that was accompanied by late tectonic to posttectonic deposition of iron. -Authors

Epiphytic lichen diversity on dead and dying conifers under different levels of atmospheric pollution.

PubMed

Hauck, Markus

2005-05-01

Based on literature data, epiphytic lichen abundance was comparably studied in montane woodlands on healthy versus dead or dying conifers of Europe and North America in areas with different levels of atmospheric pollution. Study sites comprised Picea abies forests in the Harz Mountains and in the northern Alps, Germany, Picea rubens-Abies balsamea forests on Whiteface Mountain, Adirondacks, New York, U.S.A. and Picea engelmannii-Abies lasiocarpa forests in the Salish Mountains, Montana, U.S.A. Detrended correspondence analysis showed that epiphytic lichen vegetation differed more between healthy and dead or dying trees at high- versus low-polluted sites. This is attributed to greater differences in chemical habitat conditions between trees of different vitality in highly polluted areas. Based on these results, a hypothetical model of relative importance of site factors for small-scale variation of epiphytic lichen abundance versus atmospheric pollutant load is discussed.

Long-term dataset on aquatic responses to concurrent climate change and recovery from acidification

NASA Astrophysics Data System (ADS)

Leach, Taylor H.; Winslow, Luke A.; Acker, Frank W.; Bloomfield, Jay A.; Boylen, Charles W.; Bukaveckas, Paul A.; Charles, Donald F.; Daniels, Robert A.; Driscoll, Charles T.; Eichler, Lawrence W.; Farrell, Jeremy L.; Funk, Clara S.; Goodrich, Christine A.; Michelena, Toby M.; Nierzwicki-Bauer, Sandra A.; Roy, Karen M.; Shaw, William H.; Sutherland, James W.; Swinton, Mark W.; Winkler, David A.; Rose, Kevin C.

2018-04-01

Concurrent regional and global environmental changes are affecting freshwater ecosystems. Decadal-scale data on lake ecosystems that can describe processes affected by these changes are important as multiple stressors often interact to alter the trajectory of key ecological phenomena in complex ways. Due to the practical challenges associated with long-term data collections, the majority of existing long-term data sets focus on only a small number of lakes or few response variables. Here we present physical, chemical, and biological data from 28 lakes in the Adirondack Mountains of northern New York State. These data span the period from 1994-2012 and harmonize multiple open and as-yet unpublished data sources. The dataset creation is reproducible and transparent; R code and all original files used to create the dataset are provided in an appendix. This dataset will be useful for examining ecological change in lakes undergoing multiple stressors.

Outer Appearances Can Be Deceiving

NASA Technical Reports Server (NTRS)

2004-01-01

This graph shows the chemical composition of the rock at Gusev Crater dubbed 'Mazatzal' after it was brushed and ground by the Mars Exploration Rover Spirit's rock abrasion tool. The data, taken by the rover's alpha particle X-ray spectrometer over the last few sols, show that the amount of chlorine and sulfur tri-oxide in Mazatzal first increased after brushing, then diminished after grinding. The interior of the rock appears to have the same chemical make-up as other volcanic or basalt rocks studied in the Gusev Crater area ('Adirondack' and 'Humphrey'). Its outer coating or rind, on the other hand, appears to be of a different constitution. Scientists are still puzzling out the implications of these data.

The larger symbols on the graph represent inferred rock compositions, while the smaller symbols are actual data points. Observations were made at the target dubbed 'New York' on Mazatzal.

Mercury bioaccumulation studies in the National Water-Quality Assessment Program--biological data from New York and South Carolina, 2005-2009

USGS Publications Warehouse

Beaulieu, Karen M.; Button, Daniel T.; Eikenberry, Barbara C. Scudder; Riva-Murray, Karen; Chasar, Lia C.; Bradley, Paul M.; Burns, Douglas A.

2012-01-01

The U.S. Geological Survey National Water-Quality Assessment Program conducted a multidisciplinary study from 2005–09 to investigate the bioaccumulation of mercury in streams from two contrasting environmental settings. Study areas were located in the central Adirondack Mountains region of New York and the Inner Coastal Plain of South Carolina. Fish, macroinvertebrates, periphyton (attached algae and associated material), detritus, and terrestrial leaf litter were collected. Fish were analyzed for total mercury; macroinvertebrates, periphyton, and terrestrial leaf litter were analyzed for total mercury and methylmercury; and select samples of fish, macroinvertebrates, periphyton, detritus, and terrestrial leaf litter were analyzed for stable isotopes of carbon (δ13C) and nitrogen (δ15N). This report presents methodology and data on total mercury, methylmercury, stable isotopes, and other ecologically relevant measurements in biological tissues.

Distinct Igneous APXS Rock Compositions on Mars from Pathfinder, MER and MSL

NASA Technical Reports Server (NTRS)

Gellert, Ralf; Arvidson, Raymond; Clark, Benton, III; Ming, Douglas W.; Morris, Richard V.; Squyres, Steven W.; Yen, Albert S.

2015-01-01

The alpha particle x-ray spectrometer (APXS) on all four Mars Rovers returned geochemical data from about 1000 rocks and soils along the combined traverses of over 50 kilometers. Here we discuss rocks likely of igneous origin, which might represent source materials for the soils and sediments identified along the traverses. Adirondack-type basalts, abundant in the plains of Gusev Crater, are primitive, olivine bearing basalts. They resemble in composition the basaltic soils encountered at all landing sites, except the ubiquitous elevated S, Cl and Zn in soils. They have been postulated to represent closely the average Martian crust composition. The recently identified new Martian meteorite Black Beauty has similar overall geochemical composition, very distinct from the earlier established SNC meteorites. The rim of the Noachian crater Endeavour, predating the sulfate-bearing Burns formation at Meridiani Planum, also resembles closely the composition of Adirondack basalts. At Gale Crater, the MSL Curiosity rover identified a felsic rock type exemplified by the mugearitic float rock JakeM, which is widespread along the traverse at Gale. While a surprise at that time, possibly related more evolved, alkaline rocks had been previously identified on Mars. Spirit encountered the Wishstone rocks in the Columbia Hills with approx. 6% Na2O+K2O, 15 % Al2O3 and low 12% FeO. Pathfinder rocks with elevated K and Na and >50% SiO2 were postulated to be andesitic. Recently Opportunity encountered the rock JeanBaptisteCharbonneau with >15% Al2O3, >50% SiO2 and approx. 10% FeO. A common characteristic all these rocks is the very low abundance of Cr, Ni and Zn, and an Fe/Mn ratio of about 50, indicating an unaltered Fe mineralogy. Beside these likely igneous rock types, which occurred always in several rocks, a few unique rocks were encountered, e.g. Bounce Rock, a pyroxene-bearing ejecta rock fragment resembling the Shergottite EETA 79001B meteorite. The APXS data can be used to relate the findings of all 4 landing sites, constrain the water to rock ratio of sediments or imply source rock provenance. Beyond that the capability to quantify important volatile elements like P, S, Cl, and Br have provided new insights into the chemistry and the environment present during the formation of the sediments.

Long-Term Patterns in C-Q Relations in an Adirondack Stream Reveal Decreasing Severity of Episodic Acidification

NASA Astrophysics Data System (ADS)

Burns, D. A.; Lawrence, G. B.; Driscoll, C. T.; Sullivan, T. J.; Shao, S.; McDonnell, T. C.

2017-12-01

Episodic acidification occurs when surface water pH and ANC decrease temporarily during rain events and snowmelt. The principal drivers of episodic acidification are increases in sulfuric acid, nitric acid, organic acids, and dilution of base cations. In regions where surface waters are sensitive to acid deposition, ANC values may approach or decline below 0 µeq/L during high flows, which may result in deleterious effects to sensitive aquatic biota. The Adirondack Mountains of New York have abundant streams and lakes, many of which are highly sensitive to the effects of acid deposition. Long-term monitoring data indicate that pH and ANC in regional surface waters are increasing in response to decreases in the acidity of atmospheric deposition that result from decreasing SO2 and NOx emissions as the Clean Air Act and its ancillary rules and amendments have been implemented. Most surface-water monitoring focuses on low-flow and broad seasonal patterns, and less is known about how episodic acidification has responded to emissions decreases. Here, we report on spatial and temporal patterns in episodic acidification through analysis of C-Q relations from surveys that target varying flow conditions as well as data from a few long-term intensively sampled stream monitoring sites. Each stream sample was assigned a Q percentile value based on a resident or nearby gage, and a statistical relation between ANC values and Q percentile was developed. The magnitude of episodic decreases in ANC increases as low-flow ANC increases, a pattern that likely results from an increasing influence of dilution, especially evident when low-flow ANC values exceed 100 µeq/L. Chronically acidic streams with low-flow ANC near 0 µeq/L show little episodic acidification, whereas streams with low-flow ANC values of about 50 µeq/L generally show ANC decreases to less than 0 µeq/L at high flow. Preliminary analysis of a 24-yr data set (1991-2014) at Buck Creek indicates that increases in high-flow ANC are more than twice those of low-flow ANC. These ANC values generally no longer decline below 0 µeq/L at the highest flows, which typically occur during spring snowmelt. Further analyses will explore how the drivers of episodic acidification vary across the region with low-flow ANC and whether clear trends in these drivers are evident across the region.

Influence of dietary carbon on mercury bioaccumulation in streams of the Adirondack Mountains of New York and the Coastal Plain of South Carolina, USA

USGS Publications Warehouse

Riva-Murray, Karen; Bradley, Paul M.; Chasar, Lia C.; Button, Daniel T.; Brigham, Mark E.; Eikenberry, Barbara C. Scudder; Journey, Celeste A.; Lutz, Michelle A.

2013-01-01

We studied lower food webs in streams of two mercury-sensitive regions to determine whether variations in consumer foraging strategy and resultant dietary carbon signatures accounted for observed within-site and among-site variations in consumer mercury concentration. We collected macroinvertebrates (primary consumers and predators) and selected forage fishes from three sites in the Adirondack Mountains of New York, and three sites in the Coastal Plain of South Carolina, for analysis of mercury (Hg) and stable isotopes of carbon (δ13C) and nitrogen (δ15N). Among primary consumers, scrapers and filterers had higher MeHg and more depleted δ13C than shredders from the same site. Variation in δ13C accounted for up to 34 % of within-site variation in MeHg among primary consumers, beyond that explained by δ15N, an indicator of trophic position. Consumer δ13C accounted for 10 % of the variation in Hg among predatory macroinvertebrates and forage fishes across these six sites, after accounting for environmental aqueous methylmercury (MeHg, 5 % of variation) and base-N adjusted consumer trophic position (Δδ15N, 22 % of variation). The δ13C spatial pattern within consumer taxa groups corresponded to differences in benthic habitat shading among sites. Consumers from relatively more-shaded sites had more enriched δ13C that was more similar to typical detrital δ13C, while those from the relatively more-open sites had more depleted δ13C. Although we could not clearly attribute these differences strictly to differences in assimilation of carbon from terrestrial or in-channel sources, greater potential for benthic primary production at more open sites might play a role. We found significant variation among consumers within and among sites in carbon source; this may be related to within-site differences in diet and foraging habitat, and to among-site differences in environmental conditions that influence primary production. These observations suggest that different foraging strategies and habitats influence MeHg bioaccumulation in streams, even at relatively small spatial scales. Such influence must be considered when selecting lower trophic level consumers as sentinels of MeHg bioaccumulation for comparison within and among sites.

Determination of chemical composition of soils and rocks at the MER landing sites Gusev crater and Meridiani Planum using the APXS

NASA Astrophysics Data System (ADS)

Brueckner, J.

2004-05-01

The new Alpha Particle X-Ray Spectrometer (APXS) is a small, light-weight instrument to obtain x-ray spectra from Martian surface samples. The sensor head contains a high-resolution x-ray detector that is surrounded by a circle of radioactive Cm-244 sources. Alpha and x-ray radiation emitted by the sources is used to induce x-ray excitation in the sample. Elements from sodium to zinc (increasing by atomic weight) are detected and their concentrations determined. The APXS is mounted on each Instrument Deployment Device (IDD) of the two Mars Exploration Rovers (MER) Spirit and Opportunity. Rover Spirit landed in the large Gusev crater that seems to have been altered by water activities in the past based on evidence of orbital images. Rover Opportunity landed in a very small crater of the Meridiani Planum, where the mineral hematite that points to water-related processes is expected to be found. Inside the little crater, a light-colored outcrop is exposed that shows widespread fine layering. The first APXS high-resolution x-ray spectrum of a Gusev soil indicated many similarities to the composition of the Mars Pathfinder (MPF) and Viking soils. However, differences are also noticeable: Low-Z elements are somewhat higher compared to MPF soils, while high-Z elements are depleted, notably Ti. Potassium in the soils reflects the K concentration of the local rocks at the different landing sites pointing toward a local contribution to the soil's composition. The Rock Abrasion Tool was used to grind the first rock on Mars at Gusev: Adirondack's undisturbed and ground surface was measured by the APXS. The composition of its fresh surface is different from the MPF soilfree rock, noticeably in Mg and Al, and clearly exhibits a basaltic nature related to the composition of basaltic shergottites. The first rock at the Meridiani crater outcrop (dubbed Robert-E) exhibited a very high sulfur concentration, more than a factor of 15 compared to rock Adirondack, indicating it is doubtful that this outcrop is from igneous activity. Camera based observations of the layering of rock Robert-E and its chemical composition are pointing to a sedimentary process where sulfate played a significant role in the cementation of the outcrop.

Nature and origin of fluids in granulite facies metamorphism

NASA Technical Reports Server (NTRS)

Newton, R. C.

1988-01-01

The various models for the nature and origin of fluids in granulite facies metamorphism were summarized. Field and petrologic evidence exists for both fluid-absent and fluid-present deep crustal metamorphism. The South Indian granulite province is often cited as a fluid-rich example. The fluids must have been low in H2O and thus high in CO2. Deep crustal and subcrustal sources of CO2 are as yet unproven possibilities. There is much recent discussion of the possible ways in which deep crustal melts and fluids could have interacted in granulite metamorphism. Possible explanations for the characteristically low activity of H2O associated with granulite terranes were discussed. Granulites of the Adirondacks, New York, show evidence for vapor-absent conditions, and thus appear different from those of South India, for which CO2 streaming was proposed. Several features, such as the presence of high-density CO2 fluid inclusions, that may be misleading as evidence for CO2-saturated conditions during metamorphism, were discussed.

Organic acid modeling and model validation: Workshop summary. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sullivan, T.J.; Eilers, J.M.

1992-08-14

A workshop was held in Corvallis, Oregon on April 9--10, 1992 at the offices of E&S Environmental Chemistry, Inc. The purpose of this workshop was to initiate research efforts on the entitled ``Incorporation of an organic acid representation into MAGIC (Model of Acidification of Groundwater in Catchments) and testing of the revised model using Independent data sources.`` The workshop was attended by a team of internationally-recognized experts in the fields of surface water acid-bass chemistry, organic acids, and watershed modeling. The rationale for the proposed research is based on the recent comparison between MAGIC model hindcasts and paleolimnological inferences ofmore » historical acidification for a set of 33 statistically-selected Adirondack lakes. Agreement between diatom-inferred and MAGIC-hindcast lakewater chemistry in the earlier research had been less than satisfactory. Based on preliminary analyses, it was concluded that incorporation of a reasonable organic acid representation into the version of MAGIC used for hindcasting was the logical next step toward improving model agreement.« less

Organic acid modeling and model validation: Workshop summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sullivan, T.J.; Eilers, J.M.

1992-08-14

A workshop was held in Corvallis, Oregon on April 9--10, 1992 at the offices of E S Environmental Chemistry, Inc. The purpose of this workshop was to initiate research efforts on the entitled Incorporation of an organic acid representation into MAGIC (Model of Acidification of Groundwater in Catchments) and testing of the revised model using Independent data sources.'' The workshop was attended by a team of internationally-recognized experts in the fields of surface water acid-bass chemistry, organic acids, and watershed modeling. The rationale for the proposed research is based on the recent comparison between MAGIC model hindcasts and paleolimnological inferencesmore » of historical acidification for a set of 33 statistically-selected Adirondack lakes. Agreement between diatom-inferred and MAGIC-hindcast lakewater chemistry in the earlier research had been less than satisfactory. Based on preliminary analyses, it was concluded that incorporation of a reasonable organic acid representation into the version of MAGIC used for hindcasting was the logical next step toward improving model agreement.« less

Effects of Parameter Uncertainty on Long-Term Simulations of Lake Alkalinity

NASA Astrophysics Data System (ADS)

Lee, Sijin; Georgakakos, Konstantine P.; Schnoor, Jerald L.

1990-03-01

A first-order second-moment uncertainty analysis has been applied to two lakes in the Adirondack Park, New York, to assess the long-term response of lakes to acid deposition. Uncertainty due to parameter error and initial condition error was considered. Because the enhanced trickle-down (ETD) model is calibrated with only 3 years of field data and is used to simulate a 50-year period, the uncertainty in the lake alkalinity prediction is relatively large. When a best estimate of parameter uncertainty is used, the annual average alkalinity is predicted to be -11 ±28 μeq/L for Lake Woods and 142 ± 139 μeq/L for Lake Panther after 50 years. Hydrologic parameters and chemical weathering rate constants contributed most to the uncertainty of the simulations. Results indicate that the uncertainty in long-range predictions of lake alkalinity increased significantly over a 5- to 10-year period and then reached a steady state.

Episodic acidification of small streams in the northeastern united states: Effects on fish populations

USGS Publications Warehouse

Baker, J.P.; Van Sickle, J.; Gagen, C.J.; DeWalle, David R.; Sharpe, W.E.; Carline, R.F.; Baldigo, Barry P.; Murdoch, Peter S.; Bath, D.W.; Kretser, W.A.; Simonin, H.A.; Wigington, P.J.

1996-01-01

As part of the Episodic Response Project (ERP), we studied the effects of episodic acidification on fish in 13 small streams in the northeastern United States: four streams in the Adirondack region of New York, four streams in the Catskills, New York, and five streams in the northern Appalachian Plateau, Pennsylvania. In situ bioassays with brook trout (Salvelinus fontinalis) and a forage fish species (blacknose dace (Rhinichthys atratulus], mottled sculpin (Cottus bairdi), or slimy sculpin (Cottus cognatus), depending on the region) measured direct toxicity. Movements of individual brook trout, in relation to stream chemistry, were monitored using radiotelemetry. Electrofishing surveys assessed fish community status and the density and biomass of brook trout in each stream. During low flow, all streams except one had chemical conditions considered suitable for the survival and reproduction of most fish species (median pH 6.0-7.2 during low flow; inorganic Al 100-200 ??g/L. We conclude that episodic acidification can have long-term effects on fish communities in small streams.

Global Patch Matching

NASA Astrophysics Data System (ADS)

Huang, X.; Hu, K.; Ling, X.; Zhang, Y.; Lu, Z.; Zhou, G.

2017-09-01

This paper introduces a novel global patch matching method that focuses on how to remove fronto-parallel bias and obtain continuous smooth surfaces with assuming that the scenes covered by stereos are piecewise continuous. Firstly, simple linear iterative cluster method (SLIC) is used to segment the base image into a series of patches. Then, a global energy function, which consists of a data term and a smoothness term, is built on the patches. The data term is the second-order Taylor expansion of correlation coefficients, and the smoothness term is built by combing connectivity constraints and the coplanarity constraints are combined to construct the smoothness term. Finally, the global energy function can be built by combining the data term and the smoothness term. We rewrite the global energy function in a quadratic matrix function, and use least square methods to obtain the optimal solution. Experiments on Adirondack stereo and Motorcycle stereo of Middlebury benchmark show that the proposed method can remove fronto-parallel bias effectively, and produce continuous smooth surfaces.

Combined oxygen-isotope and U-Pb zoning studies of titanite: New criteria for age preservation

DOE PAGES

Bonamici, Chloe E.; Fanning, C. Mark; Kozdon, Reinhard; ...

2015-02-11

Here, titanite is an important U-Pb chronometer for dating geologic events, but its high-temperature applicability depends upon its retention of radiogenic lead (Pb). Experimental data predict similar rates of diffusion for lead (Pb) and oxygen (O) in titanite at granulite-facies metamorphic conditions (T = 650-800°C). This study therefore investigates the utility of O-isotope zoning as an indicator for U-Pb zoning in natural titanite samples from the Carthage-Colton Mylonite Zone of the Adirondack Mountains, New York. Based on previous field, textural, and microanalytical work, there are four generations (types) of titanite in the study area, at least two of which preservemore » diffusion-related δ 18O zoning. U-Th-Pb was analyzed by SIMS along traverses across three grains of type-2 titanite, which show well-developed diffusional δ 18O zoning, and one representative grain from each of the other titanite generations.« less

The role of multispectral scanners as data sources for EPA hydrologic models

NASA Technical Reports Server (NTRS)

Slack, R.; Hill, D.

1982-01-01

An estimated cost savings of 30% to 50% was realized from using LANDSAT-derived data as input into a program which simulates hydrologic and water quality processes in natural and man-made water systems. Data from the satellite were used in conjunction with EPA's 11-channel multispectral scanner to obtain maps for characterizing the distribution of turbidity plumes in Flathead Lake and to predict the effect of increasing urbanization in Montana's Flathead River Basin on the lake's trophic state. Multispectral data are also being studied as a possible source of the parameters needed to model the buffering capability of lakes in an effort to evaluate the effect of acid rain in the Adirondacks. Water quality in Lake Champlain, Vermont is being classified using data from the LANDSAT and the EPA MSS. Both contact-sensed and MSS data are being used with multivariate statistical analysis to classify the trophic status of 145 lakes in Illinois and to identify water sampling sites in Appalachicola Bay where contaminants threaten Florida's shellfish.

The effects of liming an Adirondack lake watershed on downstream water chemistry: Effects of liming on stream chemistry

USGS Publications Warehouse

Burns, Douglas A.

1996-01-01

Calcite treatment of chronically acidic lakes has improved fish habitat, but the effects on downstream water quality have not previously been examined. In this study, the spatial and temporal effects of watershed CaCO3 treatment on the chemistry of a lake outlet stream in the Adirondack Mountains of New York were examined. Before CaCO3 treatment, the stream was chronically acidic. During spring snowmelt before treatment, pH and acid-neutralizing capacity (ANC) in the outlet stream declined, and NO3- and inorganic monomeric aluminum (AlIM) concentrations increased sharply. During that summer, SO42- and NO3- concentrations decreased downstream, and dissolved organic carbon (DOC) concentrations and ANC increased, in association with the seasonal increase in decomposition of organic matter and the attendant SO42--reduction process. A charge-balance ANC calculation closely matched measured downstream changes in ANC in the summer and indicated that SO42- reduction was the major process contributing to summer increases in ANC. Increases in Ca2+ concentration and ANC began immediately after CaCO3 application, and within 3 months, exceeded their pretreatment values by more than 130 ??eq/L. Within 2 months after treatment, downstream decreases in Ca2+ concentration, ANC, and pH, were noted. Stream mass balances between the lake and the sampling site 1.5 km downstream revealed that the transport of all chemical constituents was dominated by conservative mixing with tributaries and ground water; however, non-conservative processes resulted in significant Ca2+ losses during the 13-month period after CaCO3 treatment. Comparison of substrate samples from the buffered outlet stream with those from its untreated tributaries showed that the percentage of cation-exchange sites occupied by Ca2+, as well as non-exchangeable Ca, were higher in the outlet-stream substrate than in tributary-stream substrate. Mass-balance data for Ca2+, H+, AlIM, and DOC revealed net downstream losses of these constituents and indicated that a reasonable set of hypothesized reactions involving AlIM, HCO3-, Ca2+, SO42-, NO3-7, and DOC could have caused the measured changes in stream acid/base chemistry. In the summer, the sharp decrease in ANC continued despite significant downstream decreases in SO42- concentrations. After CaCO3 treatment, reduction of SO42- was only a minor contributor to ANC changes relative to those caused by Ca2+ dilution from acidic tributaries and acidic ground water, and Ca2+ interactions with stream substrate. ?? 1996 Kluwer Academic Publishers.

Effects of watershed and in-stream liming on macroinvertebrate communities in acidified tributaries to an Adirondack lake

USGS Publications Warehouse

George, Scott D.; Baldigo, Barry P.; Lawrence, Gregory B.; Fuller, Randall L.

2018-01-01

Liming techniques are being explored as a means to accelerate the recovery of aquatic biota from decades of acid deposition in many regions. The preservation or restoration of native sportfish populations has typically been the impetus for liming programs, and as such, less attention has been given to its effects on other biological assemblages such as macroinvertebrates. Furthermore, the differing effects of various lime application strategies such as in-stream and watershed applications are not well understood. In 2012, a program was initiated using in-stream and aerial (whole-watershed) liming to improve water quality and Brook Trout (Salvelinus fontinalis) recruitment in three acidified tributaries of a high-elevation Adirondack lake in New York State. Concurrently, macroinvertebrates were sampled annually between 2013 and 2016 at 3 treated sites and 3 untreated reference sites to assess the effects of each liming technique on this community. Despite improvements in water chemistry in all three limed streams, our results generally suggest that neither liming technique succeeded in improving the condition of macroinvertebrate communities. The watershed application caused an immediate and unsustained decrease in the density of macroinvertebrates and increase in the proportion of sensitive taxa. These changes were driven primarily by a one-year 71 percent reduction of the acid-tolerant Leuctra stoneflies and likely represent an initial chemistry shock from the lime application rather than a recovery response. The in-stream applications appeared to reduce the density of macroinvertebrates, particularly in one stream where undissolved lime covered the natural substrate. The close proximity of our study sites to the in-stream application points (50 and 1230 m) may partly explain these negative effects. Our results are consistent with prior studies of in-stream liming which indicate that this technique often fails to restore macroinvertebrate communities to a pre-acidification condition, especially at distances <1.5 km downstream of the lime application point. The inability of either liming technique to improve the condition of macroinvertebrate communities may be partly explained by the persistence of acidic episodes in all three streams. This suggests that in order to be effective, liming programs should attempt to eliminate even temporary episodes of unsuitable water chemistry rather than just meeting minimal criteria the majority of the time. Because watershed liming produced a more stable water chemistry regime than in-stream liming, this technique may have greater future potential to eliminate toxic episodes and accelerate the recovery of acid-impacted macroinvertebrate communities.

Seismotectonics of northeastern United States and adjacent Canada

NASA Astrophysics Data System (ADS)

Yang, Jih-Ping; Aggarwal, Yash Pal

1981-06-01

Data for local earthquakes recorded by a network of stations in northeastern United States and adjacent Canada were analyzed to study the seismicity, the relationship between earthquakes and known faults, the state of stress, and crustal and upper mantle velocity structure. In addition, portable seismographs were deployed in the field to study aftershocks. As a result, accurate locations for about 364 local earthquakes (2 ≤ mb ≤ 5) and 22 focal mechanism solutions were determined. A comparison of the spatial distribution of these events (1970-1979) with historical earthquakes (1534-1959) reveals that seismic activity in the northeast is relatively stationary in space: those areas that have had little or no seismicity historically are relatively aseismic today, whereas the historically active areas are also active today. The instrumental locations, historical seismicity, and focal mechanism solutions show an internal consistency that help us distinguish two distinct seismogenic provinces. (1) The Adirondack-western Quebec province is a northwesterly trending zone of seismic activity, about 200 km wide and at least 500 km long, extending from the SE Adirondacks into western Quebec, Canada. Thrust faulting on planes striking NNW to NW appears to predominate, and the inferred axis of maximum horizontal compression is largely uniform and trends WSW, nearly parallel to the calculated absolute plate motion of North America. Little or no seismicity is found where anorthosite outcrops at the surface. Correlations between gravity anomalies and earthquake locations suggest that seismic activity in this zone is localized to regions of steep NE or SW gradient in Bouguer anomalies. This zone does not appear to extend southeastward to Boston, as proposed by some workers. (2) The Appalachian province is a northeasterly trending zone of seismic activity extending from northern Virginia to New Brunswick, Canada. Highangle reverse or thrust faulting on N to NE trending planes appears to predominate. The western margin of this province, however, appears to be relatively aseismic. We attribute this relative lack of activity to one or more of the following: the presence of igneous activity postdating rifting of Africa from North America, the occurrence of intense metamorphism during the Acadian orogeny which may have annealed preexisting faults, and the predominance of ductile as opposed to brittle deformation in the geologic past. The inferred axis of maximum horizontal compression along the eastern margin of the Appalachians is rather uniform and trends W-WNW, almost perpendicular to the magnetic lineations offshore. We suggest that this W-WNW compression reflects the gravitational force arising from horizontal density variations in the oceanic lithosphere as it cools and moves away from spreading centers.

Initial results from the MER Athena science investigation

NASA Astrophysics Data System (ADS)

Squyres, S.; Athena Science Team

The Mars Exploration Rover Spirit landed in Gusev Crater on January 4 (UTC), 2004. It was followed 21 days later by the rover Opportunity, which landed on Meridiani Planum. The landing site at Gusev crater lies on a flat, rock-strewn plain. The rocks at the site are mostly angular, and some clearly appear to contain vesicles. The rock at Gusev that has been studied best to date has been named "Adirondack". Three sets of measurements have been made on Adirondack with the full set of payload instruments: one of the natural rock surface, one of the same location after being brushed by the RAT, and one of the same location after removal of 2-3 mm of rock by the RAT. The concentration of presumably dust-borne elements like sulfur and chlorine diminished significantly with brushing, and diminished dramatically with grinding. All of the observations of Adirondack are consistent with it being an essentially unweathered olivine and magnetite-bearing, low-silica basalt. The only soil at Gusev that has been investigated in detail so far is one dominated by fairly coarse (100-300 micron) grains that have the appearance and behavior of well-cemented agglomerates. APXS spectra of this soil are similar to those of soils found at the Viking and Pathfinder sites. Mössbauer spectra show two ferrous doublets and a ferric doublet, with the stronger ferrous doublet assigned to olivine. Mini-TES spectra have been acquired for soils surrounding the the Spirit landing site, and show spectra nearly identical to globally averaged soil viewed by the TES instrument on Mars Global Surveyor. This includes identification of a small amount (a few percent) of carbonate. The dominant rocks in the vicinity of the Spirit landing site at Gusev are clearly volcanic. Upcoming rover activities include a traverse to a nearby crater that is about 200 m in diameter and whose ejecta may include other non-volcanic geologic materials. The landing site at Meridiani Planum lies inside an impact crater that is roughly 20 meters in diameter. The lander came to rest on soil that fills most of the crater. An outcrop of layered bedrock is exposed on the crater wall. The landing site was selected partly because coarse gray hematite was expected to be present on the basis of orbital data. Mini-TES data have confirmed the presence of this hematite in the soil. The soil within the crater has several components. Microscopic images of undisturbed surface soil show that one component is fine (~100 micron) sand. Mössbauer spectra of the sand show two ferrous doublets (one of them due to olivine), a ferric doublet, and a weak magnetic sextet. APXS and Mini-TES data on this sand are consistent with a composition dominated by basalt. Another component of the soil consists of coarse (several mm) granules. These range in shape from subangular to rounded to remarkably spherical. In some locations, granules have been pressed down into the soil by the impact of the lander's airbags. At those locations the concentration of hematite as determined by Mini-TES is sharply reduced, suggesting that at least some of the granules are hematite-bearing. The bedrock outcrop is finely laminated, with typical layer thicknesses of only a few mm. The texture of the outcrop as viewed in miroscopic images suggests that it is fine-grained, with well-expressed structure that is revealed by varying degrees of mechanical abrasion of layers of varying induration. Initial APXS results on this fine-grained matrix suggest an unusual composition, including sulfur concentrations significantly higher than any observed elsewhere on Mars. Embedded within the outcrop and weathering out of it are highly spherical granules with diameters of several mm. The visible to near-IR spectral properties of these embedded spherical granules, as determined by Pancam, are distinctly different from those of the matrix in which they are embedded. The highest Mini-TES-derived concentrations of hematite are found in soil and possible rock units above the bedrock outcrop that have not been visited by the rover as of this writing. Future activities include climbing out of the crater and investigating this hematite-rich material.

Assessing the Factors of Regional Growth Decline of Sugar Maple

NASA Astrophysics Data System (ADS)

Bishop, D. A.; Beier, C. M.; Pederson, N.; Lawrence, G. B.; Stella, J. C.; Sullivan, T. J.

2014-12-01

Sugar maple (Acer saccharum Marsh) is among the most ecologically, economically and culturally important trees in North America, but has experienced a decline disease across much of its range. We investigated the climatic and edaphic factors associated with A. saccharum growth in the Adirondack Mountains (USA) using a well-replicated tree-ring network incorporating a range of soil fertility (base cation availability). We found that nearly 3 in 4 A. saccharum trees exhibited declining growth rates during the last several decades, regardless of tree age or size. Although diameter growth was consistently higher on base-rich soils, the negative trends in growth were largely consistent across the soil chemistry gradient. Sensitivity of sugar maple growth to climatic variability was overall weaker than expected, but were also non-stationary during the 20th century. We observed increasingly positive responses to late-winter precipitation, increasingly negative responses to growing season temperatures, and strong positive responses to moisture availability during the 1960s drought that became much weaker during the recent pluvial. Further study is needed of these factors and their interactions as potential mechanisms for sugar maple growth decline.

Analysis of ERTS-1 linear features in New York State

NASA Technical Reports Server (NTRS)

Isachsen, Y. W. (Principal Investigator); Fakundiny, R. H.; Forster, S. W.

1974-01-01

The author has identified the following significant results. All ERTS-1 linears confirmed to date have topographic expression although they may appear as featureless tonal linears on the imagery. A bias is unavoidably introduced against any linears which may parallel raster lines, lithological trends, or the azimuth of solar illumination. Ground study of ERTS-1 topographic lineaments in the Adirondacks indicates: outcrops along linears are even more rare than expected, fault breccias are found along some NNE lineaments, chloritization and slickensiding without brecciation characterize one EW lineament whereas closely-spaced jointing plus a zone of plastic shear define another. Field work in the Catskills suggests that the prominent new NNE lineaments may be surface manifestations of normal faulting in the basement, and that it may become possible to map major joint sets over extensive plateau regions directly on the imagery. Fall and winter images each display some unique linears, and long linears on the fall image commonly appear as aligned segments on the winter scene. A computer-processed color composite image permitted the extraction or additional information on the shaded side of mountains.

Episodic acidification of small streams in the northeastern united states: episodic response project

USGS Publications Warehouse

Wigington, P.J.; Baker, J.P.; DeWalle, David R.; Kretser, W.A.; Murdoch, Peter S.; Simonin, H.A.; Van Sickle, J.; Mcdowell, M.K.; Peck, D.V.; Barchet, W.R.

1996-01-01

The Episodic Response Project (ERP) was an interdisciplinary study designed to address uncertainties about the occurrence, nature, and biological effects of episodic acidification of streams in the northeastern United States. The ERP research consisted of intensive studies of the chemistry and biological effects of episodes in 13 streams draining forested watersheds in the three study regions: the Northern Appalachian region of Pennsylvania and the Catskill and Adirondack Mountains of New York. Wet deposition was measured in each of the three study regions. Using automated instruments and samplers, discharge and chemistry of each stream was monitored intensively from fall 1988 through spring 1990. Biological studies focused on brook trout and native forage fish. Experimental approaches included in situ bioassays, radio transmitter studies of fish movement, and fish population studies. This paper provides an overview of the ERP, describes the methodology used in hydrologic and water chemistry components of the study, and summarizes the characteristics of the study sites, including the climatic and deposition conditions during the ERP and the general chemical characteristics of the study streams.

Undergraduate Research and Training in Ion-Beam Analysis of Environmental Materials

NASA Astrophysics Data System (ADS)

Vineyard, Michael F.; Chalise, Sajju; Clark, Morgan L.; LaBrake, Scott M.; McCalmont, Andrew M.; McGuire, Brendan C.; Mendez, Iseinie I.; Watson, Heather C.; Yoskowitz, Joshua T.

We have an active undergraduate research program at the Union College Ion-Beam Analysis Laboratory (UCIBAL) focused on the study of environmental materials. Accelerator-based ion-beam analysis (IBA) is a powerful tool for the study of environmental pollution because it can provide information on a broad range of elements with high sensitivity and low detection limits, is non-destructive, and requires little or no sample preparation. It also provides excellent training for the next generation of environmental scientists. Beams of protons and alpha particles with energies of a few MeV from the 1.1-MV tandem Pelletron accelerator (NEC Model 3SDH) in the UCIBAL are used to characterize environmental samples using IBA techniques such as proton-induced X-ray emission, Rutherford back-scattering, and proton-induced gamma-ray emission. Recent projects include the characterization of atmospheric aerosols in the Adirondack Mountains of upstate New York, the study of heavy metal pollutants in river sediment, measurements of Pb diffusion in sulfide minerals to help constrain the determination of the age of iron meteorites, and the search for heavy metals and toxins in artificial turf.

Episodic yo-yo movements (epeirogeny) on continental platform intracratonic basins: Need for reinterpretation of paleogeography, faunal extinctions, and source rock maturity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Friedman, G.M.

1989-08-01

In the Appalachian basin and Mississippi Valley, dates for epeirogeny cluster between 250 and 300 Ma, with the completion of the uplifts at about the Permian-Triassic boundary. In the Fennoscandian shield and elsewhere, uplifts appear to be of comparable age. This was the time when the continents had collided to become supercontinent Pangea which, as a result of uplift, stood high above sea level; environments became stressful, weather patterns changed, and faunal extinctions occurred. Large-scale epeirogeny began again at about 100 Ma, with some dates at about 60 Ma marking Cretaceous-Tertiary boundary extinctions. Precambrian basements, such as the Adirondacks, themore » Canadian shield, and the Arabo-Nubian shield suffered domal uplift during the Oligocene-Miocene, especially in the Miocene to Holocene interval. Oceanic sedimentation rates were elevated in the Miocene to accommodate this increased continental erosion. Active Holocene uplift in the Arabo-Nubian shield involving several meters or even tens of meters occurred as recently as between 3,405 {plus minus} 90 years and 2,465 {plus minus} 155 years ago.« less

Effect of whole catchment liming on the episodic acidification of two adirondack streams

USGS Publications Warehouse

Newton, R.M.; Burns, Douglas A.; Blette, V.L.; Driscoll, C.T.

1996-01-01

During the fall of 1989 7.7Mg/ha of calcium carbonate was applied on two tributary catchments (40 ha and 60 ha) to Woods Lake, a small (25 ha) acidic headwater lake in the western Adirondack region of New York. Stream-water chemistry in both catchment tributaries responded immediately. Acid-neutralizing capacity (ANC) increased by more than 200 ??eq/L in one of the streams and more than 1000 ??eq/L in the other, from pre-liming values which ranged from -25 to +40 ??eq/L. The increase in ANC was primarily due to increases in dissolved Ca2+ concentrations. Most of the initial response of the streams was due to the dissolution of calcite that fell directly into the stream channels and adjacent wetlands. A small beaver impoundment and associated wetlands were probably responsible for the greater response observed in one of the streams. After the liming of subcatchmentIV (60 ha), Ca2+ concentrations increased with increasing stream discharge in the stream during fall rain events, suggesting a contribution from calcite dissolved within the soil and transported to the stream by surface runoff or shallow interflow. Concentrations of other ions not associated with the calcite (e.g. Na+) decreased during fall rain events, presumably due to mixing of solute-rich base flow with more dilute shallow interflow. The strong relation between changes in Ca2+ and changes in NO3- concentrations during spring snowmelt, (r2 = 0.93, slope = 0.96, on an equivalent basis) suggests that both solutes had a common source in the organic horizon of the soil. Increases in NO3- concentrations during snowmelt were balanced by increases in Ca2+ that was released either directly from the calcite or from exchange sites, mitigating episodic acidification of the stream. However, high ambient NO3- concentrations and relatively low ambient Ca2+ concentrations in the stream during the spring caused the stream to become acidic despite the CaCO3 treatment. In stream WO2 (40ha), Ca2+ concentrations were much higher than in stream WO4 because of the dissolution of calcite which fell directly into the upstream beaver pond and its associated wetlands. Calcium concentrations decreased as both NO3- concentrations and stream discharge increased, due to the dilution of Ca-enriched beaver pond water by shallow interflow. Despite this dilution, Ca2+ concentrations were high enough to more than balance strong acid anion (SO42-, NO3-, Cl-) concentrations, resulting in a positive ANC in this stream throughout the year. These data indicate that liming of wetlands and beaver ponds is more effective than whole catchment liming in neutralizing acidic surface waters. ?? 1996 Kluwer Academic Publishers.

Structure, stratigraphy, and origin of Husband Hill, Columbia Hills, Gusev Crater, Mars

USGS Publications Warehouse

McCoy, T.J.; Sims, M.; Schmidt, M.E.; Edwards, L.; Tornabene, L.L.; Crumpler, L.S.; Cohen, B. A.; Soderblom, L.A.; Blaney, D.L.; Squyres, S. W.; Arvidson, R. E.; Rica, J.W.; Treguier, E.; d'Uston, C.; Grant, J. A.; McSween, H.Y.; Golombek, M.P.; Haldemann, A.F.C.; de Souza, P.A.

2008-01-01

The strike and dip of lithologic units imaged in stereo by the Spirit rover in the Columbia Hills using three-dimensional imaging software shows that measured dips (15-32??) for bedding on the main edifice of the Columbia Hill are steeper than local topography (???8-10??). Outcrops measured on West Spur are conformable in strike with shallower dips (7-15??) than observed on Husband Hill. Dips are consistent with observed strata draping the Columbia Hills. Initial uplift was likely related either to the formation of the Gusev Crater central peak or ring or through mutual interference of overlapping crater rims. Uplift was followed by subsequent draping by a series of impact and volcaniclastic materials that experienced temporally and spatially variable aqueous infiltration, cementation, and alteration episodically during or after deposition. West Spur likely represents a spatially isolated depositional event. Erosion by a variety of processes, including mass wasting, removed tens of meters of materials and formed the Tennessee Valley primarily after deposition. This was followed by eruption of the Adirondack-class plains basalt lava flows which embayed the Columbia Hills. Minor erosion, impact, and aeolian processes have subsequently modified the Columbia Hills. Copyright 2008 by the American Geophysical Union.

Reacidification modeling and dose calculation procedures for calcium-carbonate-treated lakes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Scheffe, R.D.

1987-01-01

Two dose calculation models and a reacidification model were developed and applied to two Adirondack acid lakes (Woods Lake and Cranberry Pond) that were treated with calcite during May 30-31, 1985 as part of the EPRI-funded Lake Acidification Mitigation Project. The first dose model extended Sverdrup's (1983) Lake Liming model by incorporating chemical equilibrium routines to eliminate empirical components. The model simulates laboratory column water chemistry profiles (spatially and temporally) and dissolution efficiencies fairly well; however, the model predicted conservative dissolution efficiencies for the study lakes. Time-series water chemistry profiles of the lakes suggest that atmospheric carbon dioxide intrusion ratemore » was far greater than expected and enhanced dissolution efficiency. Accordingly, a second dose model was developed that incorporated ongoing CO/sub 2/ intrusion and added flexibility in the handling of solid and dissolved species transport. This revised model simulated whole-lake water chemistry throughout the three week dissolution period. The Acid Lake Reacidification Model (ALaRM) is a general mass-balance model developed for the temporal prediction of the principal chemical species in both the water column and sediment pore water of small lakes and ponds.« less

The Effect of Climate Change on Snow Pack at Sleepers River, Vermont, USA

NASA Astrophysics Data System (ADS)

Shanley, J. B.; Chalmers, A.; Denner, J.; Clark, S.

2017-12-01

Sleepers River Research Watershed, a U.S. Geological Survey Water, Energy, and Biogeochemical Budgets (WEBB) site in northeastern Vermont, has a 58-year record (since 1959) of snow depth and snow water equivalence (SWE), one of the longest continuous records in eastern North America. Snow measurements occur weekly during the winter at the watershed using an Adirondack type snow tube sampler. Sleepers River averages about 1100 mm of precipitation annually of which 20 to 30 percent falls as snow. Snow cover typically persists from December to April. Length of snow cover and snow depth vary with elevation, aspect, and cover type. Sites include open field, and hardwood and conifer stand clearings from 225 to 630 meters elevation. We evaluated changes in snow depth, snow cover duration, and SWE relative to elevation, soil frost depth, air temperature, total precipitation, and the El Niño - Southern Oscillation (ENSO) cycle. Overall, warmer winter temperatures have resulted in more midwinter thaws, more rain during the winter, and more variable soil frost depth. Trends in snowpack amount and duration were compared to winter-spring streamflow center-of-mass to evaluate if shifts in the snow pack regime were leading to earlier snowmelt.

Impact of Canadian wildfire smoke on air quality at two rural sites in NY State

NASA Astrophysics Data System (ADS)

Dutkiewicz, Vincent A.; Husain, Liaquat; Roychowdhury, Utpal K.; Demerjian, Kenneth L.

2011-04-01

We report high concentrations of black carbon aerosols (BC), present at two rural sites in New York during the last week in May 2010, that are linked to wildfire activity. At Mayville BC from wood smoke was recorded for a total of 20 h from three separate episodes, mean concentration was 1400 ng m -3. These three short events contributed 13% of the BC burden during the month of May. At Whiteface Mountain high concentrations of BC, carbon monoxide gas (CO), and fine particulate matter mass (PM 2.5) are reported from a heavy smoke event that impacted the Adirondack region of the State on May 31, 2010. PM 2.5 mass recorded at the Lodge site (600 m above mean sea level) was 150 μg m -3 at 8:30 am EST and the 24-h mean was almost twice the USEPA limits while CO concentration exceeded 1000 ppb and BC concentration reached 9600 ng m -3. The event was delayed several hours at the Summit site (1500 m above mean sea level) but at 5:45 pm BC concentration reached 1600 ng m -3 and CO was 317 ppbv. Detailed temporal profiles and correlations are presented.

Perspective View, New York State, Lake Ontario to Long Island

NASA Technical Reports Server (NTRS)

2000-01-01

From Lake Ontario and the St. Lawrence River (at the bottom of the image) and extending to Long Island (at the top), this perspective view shows the varied topography of eastern New York State and parts of Massachusetts, Connecticut, Pennsylvania, New Jersey and Rhode Island. The high 'bumpy' area in the left foreground is the southern and western Adirondack Mountains, a deeply eroded landscape that includes the oldest rocks in the eastern United States. On the right side are the Catskill Mountains, a part of the Appalachian Mountain chain, where river erosion has produced an intricate pattern of valleys. Between the Adirondacks and Catskills, A wide valley contains the Mohawk River and the Erie Canal. To the northwest (lower right) of the Catskills are the Finger Lakes of central New York . They were carved by the vast glacier that covered this entire area as recently as 18,000 years ago. The Hudson River runs along a straight valley from left center (near Glens Falls), widening out as it approaches New York City at the upper right on the image. The Connecticut River valley has a similar north-south trend further to the east (across the upper left corner of the image). The Berkshire Hills are between the Hudson and Connecticut valleys.

This image was generated using a single swath of data acquired in 68 seconds by SRTM and an enhanced false-color mosaic of images from the Landsat 5 satellite. Lush vegetation appears green, water appears dark blue, and cities are generally light blue. White clouds occur in the upper left and lower left. Topographic shading in the image was enhanced with false shading derived from the elevation model. Topographic expression is exaggerated 5X.

Elevation data used in this image was acquired by the Shuttle Radar Topography Mission (SRTM) aboard the Space Shuttle Endeavour, launched on February 11, 2000. SRTM used the same radar instrument that comprised the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) that flew twice on the Space Shuttle Endeavour in 1994. SRTM was designed to collect three-dimensional measurements of the Earth's surface. To collect the 3-D data, engineers added a 60-meter-long (200-foot) mast, installed additional C-band and X-band antennas, and improved tracking and navigation devices. The mission is a cooperative project between the National Aeronautics and Space Administration (NASA), the National Imagery and Mapping Agency (NIMA) of the U.S. Department of Defense (DoD), and the German and Italian space agencies. It is managed by NASA's Jet Propulsion Laboratory, Pasadena, CA, for NASA's Earth Science Enterprise, Washington, DC.

Size: 220 by 510 kilometers (135 by 315 miles) Location: 43 deg. North lat., 75 deg. West lon. Orientation: View southeast Colors: Landsat bands 2,4,7 in blue, green, and red Date Acquired: February 13, 2000 (SRTM); Various Dates (Landsat Mosaic) Image: NASA/JPL/NIMA

Perspective View, New York State, Long Island to Lake Ontario

NASA Technical Reports Server (NTRS)

2000-01-01

From Lake Ontario and the St. Lawrence River (at the top of the image) and extending to Long Island (at the bottom), this perspective view shows the varied topography of eastern New York State and parts of Massachusetts, Connecticut, Pennsylvania, New Jersey and Rhode Island. The high'bumpy' area in the upper right is the southern and western Adirondack Mountains, a deeply eroded landscape that includes the oldest rocks in the eastern United States. On the left side are the Catskill Mountains, a part of the Appalachian Mountain chain, where river erosion has produced an intricate pattern of valleys. Between the Adirondacks and Catskills, a wide valley contains the Mohawk River and the Erie Canal. To the northwest (upper left) of the Catskills are several long, narrow lakes, some of the Finger Lakes of central New York that were carved by the vast glacier that covered this entire area as recently as 18,000 years ago. The Hudson River runs along a straight valley from right center (near Glens Falls), widening out as it approaches New York City at the lower left on the image. The Connecticut River valley has a similar north-south trend further to the east (across the lower right corner of the image). The Berkshire Hills are between the Hudson and Connecticut valleys.

This image was generated using a single swath of data acquired in 68 seconds by SRTM and an enhanced false-color mosaic of images from the Landsat 5 satellite. Lush vegetation appears green, water appears dark blue, and cities are generally light blue. White clouds occur in the upper right and lower right. Topographic shading in the image was enhanced with false shading derived from the elevation model. Topographic expression is exaggerated 5X.

Elevation data used in this image was acquired by the Shuttle Radar Topography Mission (SRTM) aboard the Space Shuttle Endeavour, launched on February 11,2000. SRTM used the same radar instrument that comprised the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) that flew twice on the Space Shuttle Endeavour in 1994. SRTM was designed to collect three-dimensional measurements of the Earth's surface. To collect the 3-D data, engineers added a 60-meter-long (200-foot) mast, installed additional C-band and X-band antennas, and improved tracking and navigation devices. The mission is a cooperative project between the National Aeronautics and Space Administration (NASA), the National Imagery and Mapping Agency (NIMA) of the U.S. Department of Defense (DoD), and the German and Italian space agencies. It is managed by NASA's Jet Propulsion Laboratory, Pasadena, CA, for NASA's Earth Science Enterprise,Washington, DC.

Size: 220 by 510 kilometers (135 by 315 miles) Location: 43 deg. North lat., 75 deg. West lon. Orientation: View northwest Colors: Landsat bands 2, 4, 7 in blue, green, and red Date Acquired: February 13, 2000 (SRTM); Various Dates (Landsat Mosaic)

Mid to late proterozoic magmatism within Northeastern North America and its iplications for the growth of the continental crust

NASA Technical Reports Server (NTRS)

Mclelland, J. M.

1988-01-01

Recent studies of the mangerite-charnockite-alaskite suite exposed in the Adirondack Highlands strongly suggest that these rocks were emplaced under anorogenic, or mildly extensional, conditions. The characteristic signatures of the rocks are high (FeO/FeO+MgO) and (FeO/Fe2O3); mildly alkaline to subalkaline and metaluminous trends; high Ga/Al2O3; and within plate concentrations of Nb vs Y, Ta vs Yb, Rb vs (Y+Nb), and Rb vs (Yb+Ta). Evolved members of the series are low in CaO and MgO and high in alkalies and halogens. All of these properties are consistent with anorogenic magmatism comprising acidic crustal melts and mantle derived mafic additions to the crust. Major and minor element trends, as well as field evidence, strongly suggest that the anorogenic acidic suite is coeval, but not comagmatic, with closely associated anorthositic massifs. Present outcrop configurations are consistent with the evolution of the acidic and anorthositic rocks in zoned, bimodal magma chambers cored by the mafic constituents and overlain by explosive, caldera-type volcanism. Age determinations indicate that the emplacement of the anorthosite-charnockite suite extended over approximately 500 Ma in the Grenville and adjacent Nain, Provinces.

Mid to late proterozoic magmatism within Northeastern North America and its iplications for the growth of the continental crust

NASA Astrophysics Data System (ADS)

McLelland, J. M.

Recent studies of the mangerite-charnockite-alaskite suite exposed in the Adirondack Highlands strongly suggest that these rocks were emplaced under anorogenic, or mildly extensional, conditions. The characteristic signatures of the rocks are high (FeO/FeO+MgO) and (FeO/Fe2O3); mildly alkaline to subalkaline and metaluminous trends; high Ga/Al2O3; and within plate concentrations of Nb vs Y, Ta vs Yb, Rb vs (Y+Nb), and Rb vs (Yb+Ta). Evolved members of the series are low in CaO and MgO and high in alkalies and halogens. All of these properties are consistent with anorogenic magmatism comprising acidic crustal melts and mantle derived mafic additions to the crust. Major and minor element trends, as well as field evidence, strongly suggest that the anorogenic acidic suite is coeval, but not comagmatic, with closely associated anorthositic massifs. Present outcrop configurations are consistent with the evolution of the acidic and anorthositic rocks in zoned, bimodal magma chambers cored by the mafic constituents and overlain by explosive, caldera-type volcanism. Age determinations indicate that the emplacement of the anorthosite-charnockite suite extended over approximately 500 Ma in the Grenville and adjacent Nain, Provinces.

Detection and Quantification of Inorganic and Organic Anions in Natural, Potable, and Wastewaters in Northern New York Using Capillary Zone Electrophoresis and Indirect UV Detection

PubMed Central

Varden, Lara; Smith, Britannia; Bou-Abdallah, Fadi

2017-01-01

Capillary zone electrophoresis (CZE) is a sensitive and rapid technique used for determining traces of inorganic and organic anions in potable, natural, and wastewaters. Here, CZE with indirect UV-diode array detection (CZE-DAD) was employed with a background electrolyte system comprising of an Agilent Technologies proprietary basic anion buffer at pH 12.0 and a forensic anion detection method. The limits of detection (LOD) for this method ranged between 3 and 5 ppm and involved hydrodynamic injection of 50 mbar for 6 s with a negative polarity separation voltage of −30 kV at 30°C, a detection wavelength of 350 nm and indirect reference of 275 nm. Fourteen different anions were checked for in the water samples that were examined and included bromide, chloride, thiosulfate, nitrate, nitrite, sulfate, azide, carbonate, fluoride, arsenate, phosphate, acetate, lactate, and silicate. The water samples were collected from Northern New York towns and the Raquette River water system, the third longest river in New York State and the largest watershed of the central and western Adirondacks. The concentrations detected for these anions ranged from <5.0 ppm to 260 ppm. PMID:29057145

Hierarchical models for estimating density from DNA mark-recapture studies

USGS Publications Warehouse

Gardner, B.; Royle, J. Andrew; Wegan, M.T.

2009-01-01

Genetic sampling is increasingly used as a tool by wildlife biologists and managers to estimate abundance and density of species. Typically, DNA is used to identify individuals captured in an array of traps ( e. g., baited hair snares) from which individual encounter histories are derived. Standard methods for estimating the size of a closed population can be applied to such data. However, due to the movement of individuals on and off the trapping array during sampling, the area over which individuals are exposed to trapping is unknown, and so obtaining unbiased estimates of density has proved difficult. We propose a hierarchical spatial capture-recapture model which contains explicit models for the spatial point process governing the distribution of individuals and their exposure to (via movement) and detection by traps. Detection probability is modeled as a function of each individual's distance to the trap. We applied this model to a black bear (Ursus americanus) study conducted in 2006 using a hair-snare trap array in the Adirondack region of New York, USA. We estimated the density of bears to be 0.159 bears/km2, which is lower than the estimated density (0.410 bears/km2) based on standard closed population techniques. A Bayesian analysis of the model is fully implemented in the software program WinBUGS.

Use of Combined Biogeochemical Model Approaches and Empirical Data to Assess Critical Loads of Nitrogen

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fenn, Mark E.; Driscoll, Charles; Zhou, Qingtao

2015-01-01

Empirical and dynamic biogeochemical modelling are complementary approaches for determining the critical load (CL) of atmospheric nitrogen (N) or other constituent deposition that an ecosystem can tolerate without causing ecological harm. The greatest benefits are obtained when these approaches are used in combination. Confounding environmental factors can complicate the determination of empirical CLs across depositional gradients, while the experimental application of N amendments for estimating the CL does not realistically mimic the effects of chronic atmospheric N deposition. Biogeochemical and vegetation simulation models can provide CL estimates and valuable ecosystem response information, allowing for past and future scenario testing withmore » various combinations of environmental factors, pollutants, pollutant control options, land management, and ecosystem response parameters. Even so, models are fundamentally gross simplifications of the real ecosystems they attempt to simulate. Empirical approaches are vital as a check on simulations and CL estimates, to parameterize models, and to elucidate mechanisms and responses under real world conditions. In this chapter, we provide examples of empirical and modelled N CL approaches in ecosystems from three regions of the United States: mixed conifer forest, desert scrub and pinyon- juniper woodland in California; alpine catchments in the Rocky Mountains; and lakes in the Adirondack region of New York state.« less

Changes in faunal and vegetation communities along a soil calcium gradient in northern hardwood forests

USGS Publications Warehouse

Beier, Colin M.; Woods, Anne M.; Hotopp, Kenneth P.; Gibbs, James P.; Mitchell, Myron J.; Dovciak, Martin; Leopold, Donald J.; Lawrence, Gregory B.; Page, Blair D.

2012-01-01

Depletion of Ca from forest soils due to acidic deposition has had potentially pervasive effects on forest communities, but these impacts remain largely unknown. Because snails, salamanders, and plants play essential roles in the Ca cycle of northern hardwood forests, we hypothesized that their community diversity, abundance, and structure would vary with differences in biotic Ca availability. To test this hypothesis, we sampled 12 upland hardwood forests representing a soil Ca gradient in the Adirondack Mountains, New York (USA), where chronic deposition has resulted in acidified soils but where areas of well-buffered soils remain Ca rich due to parent materials. Along the gradient of increasing soil [Ca2+], we observed increasing trends in snail community richness and abundance, live biomass of redback salamanders (Plethodon cinereus (Green, 1818)), and canopy tree basal area. Salamander communities were dominated by mountain dusky salamanders (Desmognathus ochrophaeus Cope, 1859) at Ca-poor sites and changed continuously along the Ca gradient to become dominated by redback salamanders at the Ca-rich sites. Several known calciphilic species of snails and plants were found only at the highest-Ca sites. Our results indicated that Ca availability, which is shaped by geology and acidic deposition inputs, influences northern hardwood forest ecosystems at multiple trophic levels, although the underlying mechanisms require further study.

Temporal and geographic trends in mercury concentrations in muscle tissue in five species of Hudson River, USA, fish.

PubMed

Levinton, Jeffrey S; Pochron, Sharon T

2008-08-01

We analyzed a New York (USA) state database of mercury concentrations in muscle tissue for five species of fish (striped bass, yellow perch, largemouth bass, smallmouth bass, and carp) over a range of locations in the Hudson River (USA) between 1970 and 2004. We used regression models to discern temporal and geographic change in the fish while controlling for a positive correlation between mercury concentration and body mass. Mercury concentrations significantly increased in fish from New York Harbor waters to the mid-Hudson River. Striped bass and yellow perch showed a shallower increase in mercury concentration with river mile than did carp, largemouth bass, and smallmouth bass. Mercury concentrations declined over the 34-year period. These results imply that a geographically restricted source of mercury may be spread throughout the watershed by toxin-laden dispersing species. The increase of mercury toward the north may relate to a point source in the mid-Hudson River, or it may indicate mercury released from the Adirondack watershed. The decline of mercury over three decades corresponds to a reduction of various inputs in the region. The temporal and geographic pattern of mercury in sediments corresponds to the geographic trend of mercury in fish.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Horn, M.E.

A field study and associated risk assessment was conducted to evaluate the potential ecological and human health impacts related to the standard application of five supplemental wood preservatives to 20 electric utility transmission poles. Post-application monitoring for chemical residuals and microbiological effects was conducted over a 17 month post-application period (June 6, 1990--November 7, 1991). The utility wood poles in the study were located in wetland sites of the New York State Adirondack Park. All poles were western red cedar and all had been treated with pentachlorophenol (PCP) prior to installation. At the time supplemental preservatives were applied, the polesmore » had been in service for approximately 40 years. Groundwater, surface water, and soil around each treated pole were monitored for release of active ingredients, organic carriers and subsequent degradation products of the commercial wood preservatives. The analytes were as follows: chlorpyrifos, 1,1,1-trichloroethane, creosote, 2,4-dinitrophenol, fluoride, chromium, arsenic, copper, naphthenate, sodium methyl dithiocarbamate and methyl isothiocyanate. Ecological response to chemical exposure was estimated by means of measuring soil gases (carbon dioxide and methane), soil macroinvertebrate populations and soil microbial biomass. Results from near-pole post-treatment sampling were compared to pre-treatment samples and reference plots used to establish preapplication biological conditions and background levels of wood preservative constituents.« less

Physical Controls on Carbon Flux from a Temperate Lake During Autumn Cooling

NASA Astrophysics Data System (ADS)

Czikowsky, M. J.; Miller, S. D.; Tedford, E. W.; MacIntyre, S.

2011-12-01

Seasonally-stratified temperate lakes are a source of carbon dioxide to the atmosphere during autumn overturning as CO2 trapped below the thermocline becomes available to the surface for release to the atmosphere. We made continuous measurements of the vertical profile of pCO2 in a ~600 ha temperate lake (Lake Pleasant, maximum depth ~24 m) in southwestern Adirondack Park, New York from mid-September to mid-October 2010 from a moored pontoon boat. Continuous eddy covariance flux measurements of momentum, sensible and latent heat, and CO2 were made in situ, and the water column thermal structure was measured using thermistor chains. The spatial variability (horizontal and vertical) of pCO2 throughout the lake was characterized periodically using a roving profiling system. At the beginning of the study interval, pCO2 at the pontoon boat varied from 500 ppm at the surface to > 3000 ppm below the thermocline. The vertical profile of pCO2 changed markedly during the campaign due to the effects of wind forcing and evaporation (buoyancy), with nearly uniform, high pCO2 throughout the water column at the end of the campaign (Figure 1). The elevated surface water pCO2 increased CO2 emission to the atmosphere.

Interpretation of Local Gravity Anomalies in Northern New York

NASA Astrophysics Data System (ADS)

Revetta, F. A.

2004-05-01

About 10,000 new gravity measurements at a station spacing of 1 to 2 Km were made in the Adirondack Mountains, Lake Champlain Valley, St. Lawrence River Valley and Tug Hill Plateau. These closely spaced gravity measurements were compiled to construct computer contoured gravity maps of the survey areas. The gravity measurements reveal local anomalies related to seismicity, faults, mineral resources and gas fields that are not seen in the regional gravity mapping. In northern New York gravity and seismicity maps indicate epicenters are concentrated in areas of the most pronounced gravity anomalies along steep gravity gradients. Zones of weakness along the contacts of these lithologies of different density could possibly account for the earthquakes in this high stress area. Also, a computer contoured gravity map of the 5.3 magnitude Au Sable Forks earthquake of April 20, 2002 indicates the epicenter lies along a north-south trending gravity gradient produced by a high angle fault structure separating a gravity low in the west from high gravity in the east. In the St. Lawrence Valley, the Carthage-Colton Mylonite Zone, a major northeast trending structural boundary between the Adirondack Highlands and Northwest Lowlands, is represented as a steep gravity gradient extending into the eastern shore of Lake Ontario. At Russell, New York near the CCMZ, a small circular shaped gravity high coincides with a cluster of earthquakes. The coincidence of the epicenters over the high may indicate stress amplification at the boundary of a gabbro pluton. The Morristown fault located in the Morristown Quadrangle in St. Lawrence County produces both gravity and magnetic anomalies due to Precambrian Basement faulting. This faulting indicates control of the Morristown fault in the overlying Paleozoics by the Precambrian faults. Gravity and magnetic anomalies also occur over proposed extensions of the Gloucester and Winchester Springs faults into northern New York. Gravity and magnetic surveys were conducted at the closed Benson Mines magnetite mine and the Zinc Mines at Balmat, New York. The gravity and magnetic anomalies at Benson Mines indicate that significant amounts of magnetite remain in the subsurface and the steep gradients indicate a shallow depth. A gravity high of 35 gravity units in the Sylvia Lake Zinc District at Balmat, New York occurs over the upper marble and a 100 gu anomaly occurs just northeast of the zinc district. Abandoned natural gas fields exist along the southern and southwestern boundary of the Tug Hill Plateau. Gravity surveys were conducted in the vicinity of three of these gas fields in the Tug Hill Plateau (Camden, Sandy Creek and Pulaski). The Tug Hill Plateau is thought to be an uplifted-fault-bounded block which, if correct, might account for the existence of those gas fields. The trends of the gravity contours on the gravity maps lends credence to the fault interpretation. Also gravity and magnetic traverses were conducted across faults in the Trenton-Black River. These traverses show gravity anomalies across the faults which indicate control by faulting in the Precambrian.

Deposition of mercury in forests across a montane elevation gradient: Elevational and seasonal patterns in methylmercury inputs and production

USGS Publications Warehouse

Gerson, Jacqueline R.; Driscoll, Charles T.; Demers, Jason D.; Sauer, Amy K.; Blackwell, Bradley D.; Montesdeoca, Mario R.; Shanley, James B.; Ross, Donald S.

2017-01-01

Global mercury contamination largely results from direct primary atmospheric and secondary legacy emissions, which can be deposited to ecosystems, converted to methylmercury, and bioaccumulated along food chains. We examined organic horizon soil samples collected across an elevational gradient on Whiteface Mountain in the Adirondack region of New York State, USA to determine spatial patterns in methylmercury concentrations across a forested montane landscape. We found that soil methylmercury concentrations were highest in the midelevation coniferous zone (0.39 ± 0.07 ng/g) compared to the higher elevation alpine zone (0.28 ± 0.04 ng/g) and particularly the lower elevation deciduous zone (0.17 ± 0.02 ng/g), while the percent of total mercury as methylmercury in soils decreased with elevation. We also found a seasonal pattern in soil methylmercury concentrations, with peak methylmercury values occurring in July. Given elevational patterns in temperature and bioavailable total mercury (derived from mineralization of soil organic matter), soil methylmercury concentrations appear to be driven by soil processing of ionic Hg, as opposed to atmospheric deposition of methylmercury. These methylmercury results are consistent with spatial patterns of mercury concentrations in songbird species observed from other studies, suggesting that future declines in mercury emissions could be important for reducing exposure of mercury to montane avian species.

Trace fossils and bioturbation in peritidal facies of the Potsdam-Theresa Formations (Cambrian-Ordovician), Northwest Adirondacks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bjerstedt, T.W.; Erickson, J.M.

The Cambrian-Ordovician Potsdam Sandstone, Theresa Formation, and Canadian correlatives in the St. Lawrence Lowlands preserve tide-dominated facies during the basal Cambrian transgression. Low intertidal sand flats in the upper Potsdam contain a Skolithos Ichnofacies dominated by Diplocraterion parallelum in clean, herringbone cross-bedded sandstones indicative of high tidal current energy. Wind-wave-driven longshore and tidal currents along a macrotidal coastline were funneled northeast-southwest by Precambrian topographic relief of up to 65 m. This relief is now expressed as the Thousand Islands of New York and Canada. The conformably overlying Theresa Formation preserves a shoaling-upward sequence of mixed clastic-carbonate facies. Shallow subtidal andmore » peritidal facies contain a mixed Skolithos-Cruziana Ichnofacies in sharply alternating lithofacies consisting of gray, intensely bioturbated, poorly sorted calcareous sandstone, and meter-thick, white cross-bedded sandstone. The parallelism between ichnofacies and lithofacies indicates that environmental energy level and persistence rather than water depth controlled trace fossil distribution. Bioturbated sandstones contain a Cruziana ichnofacies of abundant deposit feeders including: Fustiglyphus , Gyrochorte , Neonereites uniserialis , Phycodes flabellum, Planolites beverlyensis, Rosselia socialis, and Teichichnus. Suspension feeders are represented by D. habichi, D. parallelum, Skolithos, Monocraterion, and possibly Palaeophycus tubularis. Scavenging or deposit-feeding arthropods are represented by rare Cruziana furrows. Cross-bedded sandstones contain a Skolithos Ichnofacies of shallow Skolithos and Monocraterion burrows, and an undescribed large epistratal eurypterid( ) trail.« less

Hydrologic data from the integrated lake-watershed acidification study in the west-central Adirondack Mountains, New York : October 1977 through January 1982

USGS Publications Warehouse

Peters, N.E.; Murdoch, Peter S.; Dalton, F.N.

1987-01-01

Hydrologic data were collected from three forested headwater lake watersheds in Herkimer and Hamilton Counties from October 1977 through early January 1982 as part of the Integrated Lake-Watersheds Acidification Study (ILWAS). ILWAS was established in 1977 to determine why these lakes differ in pH when all receive equal amounts of acidic atmospheric deposition. Woods Lake is acidic (pH ranges from 4 to 5), Panther Lake is neutral (pH ranges from 5 to 7.5), and Sagamore Lake is intermediate (pH ranges from 5 to 6). The data tabulated herein include discharge at the three lake outlets and in a tributary to each lake; lake-water stage at each lake; chemical quality of lake water, including total concentrations of zinc, iron, manganese, and lead, at each lake outlet and at Lost Brook (a tributary to Sagamore Lake); groundwater stage from 29 wells; major ion concentrations of groundwater from 22 of these wells; temperature of soil from three depths at one site in each watershed; soil-moisture tension at three depths at eight sites - four in the neutral-lake basin, three in the acidic-lake basin , and one in the intermediate-lake basin; and average snowpack depths and water equivalents at approximately 20 snow-course sites in each basin for three sampling periods during the 1979-80 winter. (USGS)

Calcite-graphite thermometry of the Franklin Marble, New Jersey Highlands

USGS Publications Warehouse

Peck, W.H.; Volkert, R.A.; Meredith, M.T.; Rader, E.L.

2006-01-01

We present new stable-isotope data for the Mesoproterozoic Franklin Marble from outcrops along an 80-km traverse parallel to and across strike of the structural grain of the western New Jersey Highlands. Calcite and dolomite from marble have an average ??13C of 0.35??? ?? 0.73??? PDB (n = 46) and a more limited range than other Mesoproterozoic marbles from the Adirondacks and the Canadian Grenville Province. The small range of ??13C values from the New Jersey samples is consistent with the preservation of a primary marine isotopic signature and limited postdepositional isotopic modification, except proximal to Zn or Fe ore deposits and fault zones. Fractionations between calcite and well-formed graphite (??13C[Cal-Gr]) for analyzed Franklin Marble samples average 3.31???. ?? 0.25??? (n = 34), and dolomite-graphite fractionations average 3.07??? ?? 0.30??? (n = 6). Taken together, these indicate an average temperature of 769?? ?? 43??C during metamorphism associated with the Ottawan Orogeny in the New Jersey Highlands. Thus, carbon isotope fractionations demonstrate that the Franklin Marble was metamorphosed at granulite facies conditions. Metamorphic temperatures are relatively constant for the area sampled and overprint the metamorphosed carbonatehosted Zn-Fe-Mn ore deposits. The results of this study support recent work proposing that pressure and temperature conditions during Ottawan orogenesis did not vary greatly across faults that partition the Highlands into structural blocks. ?? 2006 by The University of Chicago. All rights reserved.

Deposition of mercury in forests across a montane elevation gradient: Elevational and seasonal patterns in methylmercury inputs and production

NASA Astrophysics Data System (ADS)

Gerson, Jacqueline R.; Driscoll, Charles T.; Demers, Jason D.; Sauer, Amy K.; Blackwell, Bradley D.; Montesdeoca, Mario R.; Shanley, James B.; Ross, Donald S.

2017-08-01

Global mercury contamination largely results from direct primary atmospheric and secondary legacy emissions, which can be deposited to ecosystems, converted to methylmercury, and bioaccumulated along food chains. We examined organic horizon soil samples collected across an elevational gradient on Whiteface Mountain in the Adirondack region of New York State, USA to determine spatial patterns in methylmercury concentrations across a forested montane landscape. We found that soil methylmercury concentrations were highest in the midelevation coniferous zone (0.39 ± 0.07 ng/g) compared to the higher elevation alpine zone (0.28 ± 0.04 ng/g) and particularly the lower elevation deciduous zone (0.17 ± 0.02 ng/g), while the percent of total mercury as methylmercury in soils decreased with elevation. We also found a seasonal pattern in soil methylmercury concentrations, with peak methylmercury values occurring in July. Given elevational patterns in temperature and bioavailable total mercury (derived from mineralization of soil organic matter), soil methylmercury concentrations appear to be driven by soil processing of ionic Hg, as opposed to atmospheric deposition of methylmercury. These methylmercury results are consistent with spatial patterns of mercury concentrations in songbird species observed from other studies, suggesting that future declines in mercury emissions could be important for reducing exposure of mercury to montane avian species.

The surface integral approach to Radarclinometry

USGS Publications Warehouse

Wildey, R.L.

1988-01-01

Because radarclinometry is fundamentally describable in terms of a nonlinear, first-order, partial differential equation, one expects that it can, in principle, be carried out by direct deterministic integration beginning at a given threshold profile along the azimuthal coordinate. Such a boundary condition could be provided by the altimetry profile obtained on a preceding or succeeding orbital revolution of the radar-bearing spacecraft. Notwithstanding the mismatched resolutions of the radar altimeter and the radar imaging system as planned for the Megallan mission to Venus, there are fundamental considerations, not involving system noise, that influence the possibility of success of this approach. From the topographic map of the Lake Champlain West quadrangle in the Adirondack Mountains of the U.S., a radar image is synthesized. Radarclinometry, in surface integral form, recaptures the topographic map when the applicable radar reflectance function is weakly variable over the range of application, but it diverges beyond a certain point for nominally variable reflectance functions. The effect can be understood by using results from the "shape-from-shading" literature. (This literature is produced by a group within the artificial intelligence community who have been independently attacking, for all practical purposes, photoclinometry, except that they have not given primacy to images of terrain.) The ubiquity of the instability suggests that the value of the surface integral approach is much in doubt. ?? 1988 Kluwer Academic Publishers.

Transient Liquid Water as a Mechanism for Induration of Soil Crusts on Mars

NASA Technical Reports Server (NTRS)

Landis, G. A.; Blaney, D.; Cabrol, N.; Clark, B. C.; Farmer, J.; Grotzinger, J.; Greeley, R.; McLennan, S. M.; Richter, L.; Yen, A.

2004-01-01

The Viking and the Mars Exploration Rover missions observed that the surface of Mars is encrusted by a thinly cemented layer tagged as "duricrust". A hypothesis to explain the formation of duricrust on Mars should address not only the potential mechanisms by which these materials become cemented, but also the textural and compositional components of cemented Martian soils. Elemental analyzes at five sites on Mars show that these soils have sulfur content of up to 4%, and chlorine content of up to 1%. This is consistent with the presence of sulfates and halides as mineral cements. . For comparison, the rock "Adirondack" at the MER site, after the exterior layer was removed, had nearly five times lower sulfur and chlorine content , and the Martian meteorites have ten times lower sulfur and chlorine content, showing that the soil is highly enriched in the saltforming elements compared with rock.Here we propose two alternative models to account for the origin of these crusts, each requiring the action of transient liquid water films to mediate adhesion and cementation of grains. Two alternative versions of the transient water hypothesis are offered, a top down hypothesis that emphasizes the surface deposition of frost, melting and downward migration of liquid water and a bottom up alternative that proposes the presence of interstitial ice/brine, with the upward capillary migration of liquid water.

Utility theoretic approach to estimating the demand for and benefits from recreational fishing: the impact of acid rain

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shaw, W.D. Jr.

1985-01-01

The Adirondack State Park has been hit especially hard by acid precipitation. Acid precipitation impacts particular species of fish at various high altitudes sites in the park. The author estimates consumer surplus measures for changes in a variable to proxy the stock size of these species at specific sites. To do this he first estimates the individual's demand for a recreation site as a function of site prices and the site's characteristics. The demand function for the individual is derived from a utility function. A travel cost approach is used to estimate an individual's share of total fishing time spentmore » at a five fishing site. The shares are estimated by maximum likelihood and the results indicate that price and the three characteristics do explain the allocation of the individual's time spent at the various sites selected for the analysis. Finally, consumer surplus measures for a reduction in the catch rates of the species most likely to be affected by Acid Precipitation are calculated. The meaning of these measures in the context of a model that assumes weak separability is examined. These reductions in catch rates can be linked to changes in the level of Acid Precipitation in the Park, and this provides us with a method for quantifying the impact of acid precipitation on recreation fishing.« less

Windows of opportunity: white-tailed deer and the dynamics of northern hardwood forests of the northeastern US

USGS Publications Warehouse

Sage, R.W.; Porter, W.F.; Underwood, H.B.

2003-01-01

Herbivory, lighting regimes, and site conditions are among the most important determinants of forest regeneration success, but these are affected by a host of other factors such as weather, predation, human exploitation, pathogens, wind and fire. We draw together > 50 years of research on the Huntington Wildlife Forest in the central Adirondack Mountains of New York to explore regeneration of northern hardwoods. A series of studies each of which focused on a single factor failed to identify the cause of regeneration failure. However, integration of these studies led to broader understanding of the process of forest stand development and identified at least three interacting factors: lighting regime, competing vegetation and selective browsing by white-tailed deer (Odocoileus virginianus). The diverse 100-200 year-old hardwood stands present today probably reflect regeneration during periods of low deer density (< 2.0 deer/km super(2)) and significant forest disturbance. If this hypothesis is correct, forest managers can mimic these 'natural windows of opportunity' through manipulation of a few sensitive variables in the system. Further, these manipulations can be conducted on a relatively small geographic scale. Control of deer densities on a scale of 500 ha and understory American beech (Fagus grandifolia) on a scale of < 100 ha in conjunction with an even-aged regeneration system consistently resulted in successful establishment of desirable hardwood regeneration.

Acid rain effects on aluminum mobilization clarified by inclusion of strong organic acids

USGS Publications Warehouse

Lawrence, G.B.; Sutherland, J.W.; Boylen, C.W.; Nierzwicki-Bauer, S. W.; Momen, B.; Baldigo, Barry P.; Simonin, H.A.

2007-01-01

Assessments of acidic deposition effects on aquatic ecosystems have often been hindered by complications from naturally occurring organic acidity. Measurements of pH and ANCG, the most commonly used indicators of chemical effects, can be substantially influenced by the presence of organic acids. Relationships between pH and inorganic Al, which is toxic to many forms of aquatic biota, are also altered by organic acids. However, when inorganic Al concentrations are plotted against ANC (the sum of Ca2+, Mg 2+, Na+, and K+, minus SO42-, NO3-, and Cl-), a distinct threshold for Al mobilization becomes apparent. If the concentration of strong organic anions is included as a negative component of ANC, the threshold occurs at an ANC value of approximately zero, the value expected from theoretical charge balance constraints. This adjusted ANC is termed the base-cation surplus. The threshold relationship between the base-cation surplus and Al was shown with data from approximately 200 streams in the Adirondack region of New York, during periods with low and high dissolved organic carbon concentrations, and for an additional stream from the Catskill region of New York. These results indicate that (1) strong organic anions can contribute to the mobilization of inorganic Al in combination with SO42- and NO 3-, and (2) the presence of inorganic Al in surface waters is an unambiguous indication of acidic deposition effects. ?? 2007 American Chemical Society.

Local Government Capacity to Respond to Environmental Change: Insights from Towns in New York State.

PubMed

Larson, Lincoln R; Lauber, T Bruce; Kay, David L; Cutts, Bethany B

2017-07-01

Local governments attempting to respond to environmental change face an array of challenges. To better understand policy responses and factors influencing local government capacity to respond to environmental change, we studied three environmental issues affecting rural or peri-urban towns in different regions of New York State: climate change in the Adirondacks (n = 63 towns), loss of open space due to residential/commercial development in the Hudson Valley (n = 50), and natural gas development in the Southern Tier (n = 62). Our analysis focused on towns' progression through three key stages of the environmental policy process (issue awareness and salience, common goals and agenda setting, policy development and implementation) and the factors that affect this progression and overall capacity for environmental governance. We found that-when compared to towns addressing open space development and natural gas development-towns confronted with climate change were at a much earlier stage in the policy process and were generally less likely to display the essential resources, social support, and political legitimacy needed for an effective policy response. Social capital cultivated through collaboration and networking was strongly associated with towns' policy response across all regions and could help municipalities overcome omnipresent resource constraints. By comparing and contrasting municipal responses to each issue, this study highlights the processes and factors influencing local government capacity to address a range of environmental changes across diverse management contexts.

Acid rain effects on aluminum mobilization clarified by inclusion of strong organic acids.

PubMed

Lawrence, G B; Sutherland, J W; Boylen, C W; Nierzwicki-Bauer, S W; Momen, B; Baldigo, B P; Simonin, H A

2007-01-01

Assessments of acidic deposition effects on aquatic ecosystems have often been hindered by complications from naturally occurring organic acidity. Measurements of pH and ANCG, the most commonly used indicators of chemical effects, can be substantially influenced by the presence of organic acids. Relationships between pH and inorganic Al, which is toxic to many forms of aquatic biota, are also altered by organic acids. However, when inorganic Al concentrations are plotted against ANC (the sum of Ca2+, Mg2+, Na+, and K+, minus S042-, N03-, and Cl-), a distinct threshold for Al mobilization becomes apparent. If the concentration of strong organic anions is included as a negative component of ANC, the threshold occurs at an ANC value of approximately zero, the value expected from theoretical charge balance constraints. This adjusted ANC is termed the base-cation surplus. The threshold relationship between the base-cation surplus and Al was shown with data from approximately 200 streams in the Adirondack region of New York, during periods with low and high dissolved organic carbon concentrations, and for an additional stream from the Catskill region of New York. These results indicate that (1) strong organic anions can contribute to the mobilization of inorganic Al in combination with SO42- and N03-, and (2) the presence of inorganic Al in surface waters is an unambiguous indication of acidic deposition effects.

A novel transferable individual tree crown delineation model based on Fishing Net Dragging and boundary classification

NASA Astrophysics Data System (ADS)

Liu, Tao; Im, Jungho; Quackenbush, Lindi J.

2015-12-01

This study provides a novel approach to individual tree crown delineation (ITCD) using airborne Light Detection and Ranging (LiDAR) data in dense natural forests using two main steps: crown boundary refinement based on a proposed Fishing Net Dragging (FiND) method, and segment merging based on boundary classification. FiND starts with approximate tree crown boundaries derived using a traditional watershed method with Gaussian filtering and refines these boundaries using an algorithm that mimics how a fisherman drags a fishing net. Random forest machine learning is then used to classify boundary segments into two classes: boundaries between trees and boundaries between branches that belong to a single tree. Three groups of LiDAR-derived features-two from the pseudo waveform generated along with crown boundaries and one from a canopy height model (CHM)-were used in the classification. The proposed ITCD approach was tested using LiDAR data collected over a mountainous region in the Adirondack Park, NY, USA. Overall accuracy of boundary classification was 82.4%. Features derived from the CHM were generally more important in the classification than the features extracted from the pseudo waveform. A comprehensive accuracy assessment scheme for ITCD was also introduced by considering both area of crown overlap and crown centroids. Accuracy assessment using this new scheme shows the proposed ITCD achieved 74% and 78% as overall accuracy, respectively, for deciduous and mixed forest.

Anaglyph of Shaded Relief New York State, Lake Ontario to Long Island

NASA Technical Reports Server (NTRS)

2000-01-01

From Lake Ontario and the St. Lawrence River (at the top of the image) and extending to Long Island (at the bottom) this image shows the varied topography of eastern New York State and parts of Massachusetts, Connecticut, Pennsylvania and New Jersey. The high 'bumpy' area in the middle to top right is the southern and western Adirondack Mountains, a deeply eroded landscape that includes the oldest exposed rocks in the eastern U.S.

On the left side is the Catskill Mountains, a part of the Appalachian Mountain chain, where river erosion has produced an intricate pattern of valleys. Between the Adirondacks and Catskills is a wide valley that contains the Mohawk River and the Erie Canal. On the northwest (top) of the Catskills are several long, narrow lakes, some of the Finger Lakes of central New York that were carved by the vast glacier that covered this entire region as recently as 18,000 years ago.

The Hudson River runs along a straight valley from right center (near Glens Falls), widening out as it approaches New York City at the lower left on the image. The Connecticut River valley has a similar north-south trend further to the east (across the lower right corner of the image). The Berkshires are between the Hudson and Connecticut valleys. Closer to the coast are the more deeply eroded rocks of the area around New York City, where several resistant rock units form topographic ridges.

This image product is derived from a preliminary SRTM elevation model, processed with preliminary navigation information from the Space Shuttle. Broad scale and fine detail distortions in the model seen here will be corrected in the final elevation model.

This anaglyph was generated by first creating a shaded relief image from the elevation data, masking the large water bodies, and draping the result back over the elevation model. Two differing perspectives were then calculated, one for each eye. When viewed through special glasses, the result is a vertically exaggerated view of the Earth's surface in its full three dimensions. Anaglyph glasses cover the left eye with a red filter and cover the right eye with a blue filter.

This image was acquired by the Shuttle Radar Topography Mission (SRTM) aboard the Space Shuttle Endeavour, launched on February 11, 2000. SRTM used the same radar instrument that comprised the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) that flew twice on the Space Shuttle Endeavour in 1994. SRTM was designed to collect three-dimensional measurements of the Earth's surface. To collect the 3-D data, engineers added a 60-meter-long (200-foot) mast, installed additional C-band and X-band antennas, and improved tracking and navigation devices. The mission is a cooperative project between the National Aeronautics and Space Administration (NASA), the National Imagery and Mapping Agency (NIMA) of the U.S. Department of Defense (DoD), and the German and Italian space agencies. It is managed by NASA's Jet Propulsion Laboratory, Pasadena, CA, for NASA's Earth Science Enterprise, Washington DC.

Size: 220 by 510 kilometers (135 by 315 miles) Location: 43 deg. North lat., 75 deg. West lon. Orientation: North toward the upper right Date Acquired: February 13, 2000

Stereo Pair of Height as Color & Shaded Relief, New York State, Lake Ontario to Long Island

NASA Technical Reports Server (NTRS)

2000-01-01

From Lake Ontario and the St. Lawrence River (at the top of the image) and extending to Long Island (at the bottom) this image shows the varied topography of eastern New York State and parts of Massachusetts, Connecticut, Pennsylvania and New Jersey. The high 'bumpy' area in the middle to top right is the southern and western Adirondack Mountains, a deeply eroded landscape that includes the oldest exposed rocks in the eastern U.S.

On the left side is the Catskill Mountains, a part of the Appalachian Mountain chain, where river erosion has produced an intricate pattern of valleys. Between the Adirondacks and Catskills is a wide valley that contains the Mohawk River and the Erie Canal. On the northwest (top) of the Catskills are several long, narrow lakes, some of the Finger Lakes of central New York that were carved by the vast glacier that covered this entire image as recently as 18,000 years ago.

The Hudson River runs along a straight valley from right center (near Glens Falls), widening out as it approaches New York City at the lower left on the image. The Connecticut River valley has a similar north-south trend further to the east (across the lower right corner of the image). The Berkshires are between the Hudson and Connecticut valleys. Closer to the coast are the more deeply eroded rocks of the area around New York City, where several resistant rock units form topographic ridges.

This image product is derived from a preliminary SRTM elevation model, processed with preliminary navigation information from the Space Shuttle. Broad scale and fine detail distortions in the model seen here will be corrected in the final elevation model.

This stereoscopic image was generated by first creating and combining a shaded relief image and a height as color image, both of which were derived from the elevation model. Large water bodies were then masked, and the result was then draped back over the elevation model. Two differing perspectives were then calculated, one for each eye. This color image can be viewed in 3-D by viewing the left image with the right eye and the right image with the left eye (cross-eyed viewing), or by downloading and printing the image pair, and viewing them with a stereoscope. When stereoscopically merged, the result is a vertically exaggerated view of the Earth's surface in its full three dimensions.

This image was acquired by the Shuttle Radar Topography Mission (SRTM) aboard the Space Shuttle Endeavour, launched on February 11, 2000. SRTM used the same radar instrument that comprised the Spaceborne Imaging Radar-C/X-Band Synthetic Aperture Radar (SIR-C/X-SAR) that flew twice on the Space Shuttle Endeavour in 1994. SRTM was designed to collect three-dimensional measurements of the Earth's surface. To collect the 3-D data, engineers added a 60-meter-long (200-foot) mast, installed additional C-band and X-band antennas, and improved tracking and navigation devices. The mission is a cooperative project between the National Aeronautics and Space Administration (NASA), the National Imagery and Mapping Agency (NIMA) of the U.S. Department of Defense (DoD), and the German and Italian space agencies. It is managed by NASA's Jet Propulsion Laboratory, Pasadena, CA, for NASA's Earth Science Enterprise, Washington DC.

Size: 220 by 510 kilometers (135 by 315 miles) Location: 43 deg. North lat., 75 deg. West lon. Orientation: North toward the upper right Date Acquired: February 13, 2000

A Newly Identified Role of the Deciduous Forest Floor in the Timing of Green-Up

NASA Astrophysics Data System (ADS)

Lapenis, Andrei G.; Lawrence, Gregory B.; Buyantuev, Alexander; Jiang, Shiguo; Sullivan, Timothy J.; McDonnell, Todd C.; Bailey, Scott

2017-11-01

Plant phenology studies rarely consider controlling factors other than air temperature. We evaluate here the potential significance of physical and chemical properties of soil (edaphic factors) as additional important controls on phenology. More specifically, we investigate causal connections between satellite-observed green-up dates of small forest watersheds and soil properties in the Adirondack Mountains of New York, USA. Contrary to the findings of previous studies, where edaphic controls of spring phenology were found to be marginal, our analyses show that at least three factors manifest themselves as significant controls of seasonal patterns of variation in vegetated land surfaces observed from remote sensing: (1) thickness of the forest floor, (2) concentration of exchangeable soil potassium, and (3) soil acidity. For example, a thick forest floor appears to delay the onset of green-up. Watersheds with elevated concentrations of potassium are associated with early surface greening. We also found that trees growing in strongly acidified watersheds demonstrate delayed green-up dates. Overall, our work demonstrates that, at the scale of small forest watersheds, edaphic factors can explain a significant percentage of the observed spatial variation in land surface phenology that is comparable to the percentage that can be explained by climatic and landscape factors. We conclude that physical and chemical properties of forest soil play important roles in forest ecosystems as modulators of climatic drivers controlling the rate of spring soil warming and the transition of trees out of winter dormancy.

Basalt-trachybasalt samples in Gale Crater, Mars

NASA Astrophysics Data System (ADS)

Edwards, Peter H.; Bridges, John C.; Wiens, Roger; Anderson, Ryan; Dyar, Darby; Fisk, Martin; Thompson, Lucy; Gasda, Patrick; Filiberto, Justin; Schwenzer, Susanne P.; Blaney, Diana; Hutchinson, Ian

2017-11-01

The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single-laser-shot spectra of igneous targets observed by ChemCam shows a strong peak at 55 wt% SiO2 and 6 wt% total alkalis, with a minor secondary maximum at 47-51 wt% SiO2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg# = 54. We suggest that all of these igneous rocks resulted from low-pressure, olivine-dominated fractionation of Adirondack (MER) class-type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe-rich, relatively low-Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine-grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. The Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.

Detection and Separation of Inorganic Cations in Natural, Potable, and Wastewater Samples Using Capillary Zone Electrophoresis with Indirect UV Detection

PubMed Central

Varden, Lara; Bou-Abdallah, Fadi

2017-01-01

Capillary zone electrophoresis (CZE) is a sensitive and rapid technique for determining traces of inorganic cations in water samples. CZE with indirect UV-diode array detection (CZE-DAD) was utilized to identify several inorganic cations in natural, potable, and wastewater samples. A pH 4.35 background electrolyte system was employed and consisted of 15 mM imidazole, 8 mM malonic acid, 2 mM 18-crown-6 ether as complexing agents, 10% v/v methanol as an organic modifier with indirect absorbance reference at 214 nm. The CZE method involved electromigration injection at 5 kV for 5 s, a separation voltage of 20 kV at 25°C, and a detection wavelength of 280 nm. Six main cations (ammonium NH4+, potassium K+, calcium Ca2+, sodium Na+, magnesium Mg2+, and lead Pb2+) were tested, and all but lead, were detected in the water samples at concentrations between 0.03 and 755 ppm with a detection limit ranging between 0.023 and 0.084 ppm. The successful evaluation of the proposed methodology allowed us to reliably detect and separate six metal ions in different water samples without any pretreatment. All water samples were collected from Northern New York towns and the Raquette River water system, the third longest river in New York State and the largest watershed of the central and western Adirondacks. PMID:29057144

Evidence for migratory spawning behavior by morphologically distinct Cisco (Coregonus artedi) from a small inland lake

USGS Publications Warehouse

Ross, Alexander J.; Weidel, Brian C.; Leneker, Mellisa; Solomon, Christopher T.

2017-01-01

Conservation and management of rare fishes relies on managers having the most informed understanding of the underlying ecology of the species under investigation. Cisco (Coregonus artedi), a species of conservation concern, is a cold-water pelagic fish that is notoriously variable in morphometry and life history. Published reports indicate, at spawning time, Cisco in great lakes may migrate into or through large rivers, whereas those in small lakes move inshore. Nonetheless, during a sampling trip to Follensby Pond, a 393 ha lake in the Adirondack Mountains, New York, we observed gravid Cisco swimming over an outlet sill from a narrow shallow stream and into the lake. We opportunistically dip-netted a small subsample of 11 individuals entering the lake from the stream (three female, eight male) and compared them to fish captured between 2013 and 2015 with gillnets in the lake. Stream-captured Cisco were considerably larger than lake-captured individuals at a given age, had significantly larger asymptotic length, and were present only as mature individuals between age of 3 and age 5. These results could suggest either Cisco are migrating from a nearby lake to spawn in Follensby Pond, or that a distinct morphotype of Cisco from Follensby Pond migrates out to the stream and then back in at spawning time. Our results appear to complement a handful of other cases in which Cisco spawning migrations have been documented and to provide the first evidence for such behavior in a small inland lake.

Regional trends in aquatic recovery from acidification in North America and Europe

USGS Publications Warehouse

Stoddard, J.L.; Jeffries, D.S.; Lukewille, A.; Clair, T.A.; Dillon, P.J.; Driscoll, C.T.; Forsius, M.; Johannessen, M.; Kahl, J.S.; Kellogg, J.H.; Kemp, A.; Mannlo, J.; Monteith, D.T.; Murdoch, Peter S.; Patrick, S.; Rebsdorl, A.; Skjelkvale, B.L.; Stainton, M.P.; Traaen, T.; Van Dam, H.; Webster, K.E.; Wleting, J.; Wllander, A.

1999-01-01

Rates of acidic deposition from the atmosphere ('acid rain') have decreased throughout the 1980s and 1990s across large portions of North America and Europe. Many recent studies have attributed observed reversals in surface-water acidification at national and regional scales to the declining deposition. To test whether emissions regulations have led to widespread recovery in surface-water chemistry, we analysed regional trends between 1980 and 1995 in indicators of acidification (sulphate, nitrate and base-cation concentrations, and measured (Gran) alkalinity) for 205 lakes and streams in eight regions of North America and Europe. Dramatic differences in trend direction and strength for the two decades are apparent. In concordance with general temporal trends in acidic deposition, lake and stream sulphate concentrations decreased in all regions with the exception of Great Britain all but one of these regions exhibited stronger downward trends in the 1990s than in the 1980s. In contrast, regional declines in lake and stream nitrate concentrations were rare and, when detected, were very small. Recovery in alkalinity, expected wherever strong regional declines in sulphate concentrations have occurred, was observed in all regions of Europe, especially in the 1990s, but in only one region (of five) in North America. We attribute the lack of recovery in three regions (south/central Ontario, the Adirondack/Catskill mountains and midwestern North America) to strong regional declines in base-cation concentrations that exceed the decreases in sulphate concentrations.

Migration patterns and wintering range of common loons breeding in the Northeastern United States

USGS Publications Warehouse

Kenow, K.P.; Adams, D.; Schoch, N.; Evers, D.C.; Hanson, W.; Yates, D.; Savoy, L.; Fox, T.J.; Major, A.; Kratt, R.; Ozard, J.

2009-01-01

A study, using satellite telemetry, was conducted to determine the precise migration patterns and wintering locations of Common Loons (Gavia immer) breeding in the northeastern United States. Transmitters were implanted in 17 loons (16 adults and one juvenile) that were captured on breeding lakes in New York, New Hampshire, and Maine during the summers of 2003, 2004, and 2005. Transmitters from ten of the birds provided adequate location data to document movement to wintering areas. Most adult loons appeared to travel non-stop from breeding lakes, or neighboring lakes (within 15 km), to the Atlantic coast. Adult loons marked in New Hampshire and Maine wintered 152 to 239 km from breeding lakes, along the Maine coast. Adult loons marked in the Adirondack Park of New York wintered along the coasts of Massachusetts (414 km from breeding lake), Rhode Island (362 km), and southern New Jersey (527 km). Most of the loons remained relatively stationary throughout the winter, but the size of individual wintering areas of adult loons ranged from 43 to 1,159 km 2, based on a 95% fixed kernel utilization distribution probability. A juvenile bird from New York made a number of stops at lakes and reservoirs en route to Long Island Sound (325 km from breeding lake). Maximum functional life of transmitters was about 12 months, providing an opportunity to document spring migration movements as well. This work provides essential information for development and implementation of regional Common Loon conservation strategies in the Northeastern U.S.

Hot Spots and Hot Times: Wildlife Road Mortality in a Regional Conservation Corridor.

PubMed

Garrah, Evelyn; Danby, Ryan K; Eberhardt, Ewen; Cunnington, Glenn M; Mitchell, Scott

2015-10-01

Strategies to reduce wildlife road mortality have become a significant component of many conservation efforts. However, their success depends on knowledge of the temporal and spatial patterns of mortality. We studied these patterns along the 1000 Islands Parkway in Ontario, Canada, a 37 km road that runs adjacent to the St. Lawrence River and bisects the Algonquin-to-Adirondacks international conservation corridor. Characteristics of all vertebrate road kill were recorded during 209 bicycle surveys conducted from 2008 to 2011. We estimate that over 16,700 vertebrates are killed on the road from April to October each year; most are amphibians, but high numbers of birds, mammals, and reptiles were also found, including six reptiles considered at-risk in Canada. Regression tree analysis was used to assess the importance of seasonality, weather, and traffic on road kill magnitude. All taxa except mammals exhibited distinct temporal peaks corresponding to phases in annual life cycles. Variations in weather and traffic were only important outside these peak times. Getis-Ord analysis was used to identify spatial clusters of mortality. Hot spots were found in all years for all taxa, but locations varied annually. A significant spatial association was found between multiyear hot spots and wetlands. The results underscore the notion that multi-species conservation efforts must account for differences in the seasonality of road mortality among species and that multiple years of data are necessary to identify locations where the greatest conservation good can be achieved. This information can be used to inform mitigation strategies with implications for conservation at regional scales.

Potential environmental contaminant risks to avian species at important bird areas in the northeastern United States

USGS Publications Warehouse

Rattner, B.A.; Ackerson, B.K.

2008-01-01

Environmental contaminants can have profound effects on birds, acting from the molecular through population levels of biological organization. An analysis of potential contaminant threats was undertaken at 52 Important Bird Areas (IBAs) within the northeastern Atlantic coast drainage. Using geographic information system methodology, data layers describing or integrating contamination (impaired waters, fish or wildlife consumption advisories, toxic release inventory sites, and estimates of pesticide use) were overlaid on buffered IBA boundaries, and the relative threat at each site was ranked. The most threatened sites include Jefferson National Forest (NF), Stewart B. McKinney National Wildlife Refuge (NWR), Great Dismal Swamp NWR, Blue Ridge Parkway, Shenandoah National Park (NP), Adirondack Park, Edwin B. Forsythe NWR, George Washington NF, Green Mountain NF, Long Island Piping Plover Beaches, and Merrymeeting Bay. These sites exhibited moderate to high percentages of impaired waters and had fish consumption advisories related to mercury and polychlorinated biphenyls, and were located in counties with substantial pesticide use. Endangered, threatened and Watch List bird species are present at these sites. The Contaminant Exposure and Effects--Terrestrial Vertebrates database was searched within buffered IBA boundaries, and for a moderate number of sites there was concordance between the perceived risk and contaminant exposure. Several of the IBAs with apparently substantial contaminant threats had no avian ecotoxicological data (e.g., George Washington NF, Shenandoah NP). Based upon this screening level risk assessment, contaminant biomonitoring is warranted at such sites, and data generated from these efforts should foster natural resource management activities.

Basalt-trachybasalt samples in Gale Crater, Mars

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, Peter H.; Bridges, John C.; Wiens, Roger Craig

The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single-laser-shot spectra of igneous targets observed by ChemCam shows a strong peak at ~55 wt% SiO 2 and 6 wt% total alkalis, with a minor secondary maximum at 47–51 wt% SiO 2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg#more » = 54. We suggest that all of these igneous rocks resulted from low-pressure, olivine-dominated fractionation of Adirondack (MER) class-type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe-rich, relatively low-Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine-grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. Finally, the Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.« less

Comparing protein and energy status of winter-fed white-tailed deer

USGS Publications Warehouse

Page, B.D.; Underwood, H.B.

2006-01-01

Although nutritional status in response to controlled feeding trials has been extensively studied in captive white-tailed deer (Odocoileus virginianus), there remains a considerable gap in understanding the influence of variable supplemental feeding protocols on free-ranging deer. Consequently, across the northern portion of the white-tailed deer range, numerous property managers are investing substantial resources into winter supplemental-feeding programs without adequate tools to assess the nutritional status of their populations. We studied the influence of a supplemental winter feeding gradient on the protein and energy status of free-ranging white-tailed deer in the Adirondack Mountains of New York. We collected blood and fecal samples from 31 captured fawns across 3 sites that varied considerably in the frequency, quantity, and method of supplemental feed distribution. To facilitate population-wide comparisons, we collected fresh fecal samples off the snow at each of the 3 sites with supplemental feeding and 1 reference site where no feeding occurred. Results indicated that the method of feed distribution, in addition to quantity and frequency, can affect the nutritional status of deer. The least intensively fed population showed considerable overlap in diet quality with the unfed population in a principal components ordination, despite the substantial time and financial resources invested in the feeding program. Data from fecal samples generally denoted a gradient in diet quality and digestibility that corresponded with the availability of supplements. Our results further demonstrated that fecal nitrogen and fecal fiber, indices of dietary protein and digestibility, can be estimated using regressions of fecal pellet mass, enabling a rapid qualitative assessment of diet quality.

Flooding of December 29, 1984 through January 2, 1985, in northern New York State, with flood profiles of the Black and Salmon rivers

USGS Publications Warehouse

Lumia, Richard; Burke, P.M.; Johnston, W.H.

1987-01-01

Precipitation, snowmelt, and resultant flooding throughout northern New York from December 28 through January 2, 1985, were investigated through a detailed analysis of 56 precipitation stations, 101 stage and/or discharge gaging stations, and 9 miscellaneous measurement sites. Flood damage to property and roads and bridges exceeded $5 million. Lewis and Oswego Counties were declared Federal disaster areas, primarily a result of flooding of the Black River and Salmon River. Storm-precipitation and runoff maps show the storms ' greatest intensity to have been over the Tug Hill and southwest Adirondack areas. Total rainfall from December 28 through January 2 was 6.90 inches at Stillwater Reservoir but only 0.69 inches at Lake Placid. New peak discharges of record occurred at 17 gaging stations throughout northern New York, and the maximum discharge at 17 sites had recurrence intervals equal to or greater than 100 years. Computed inflows to 11 major lakes and reservoirs in northern New York indicate that significant volumes of water (as much as 5 inches of storm runoff at Stillwater Reservoir) were stored during the storm-runoff period. Maximum 1-day flood volumes at two gaging stations on the Black River had recurrence intervals greater than 100 years. To help evaluate the extent of flooding, 67 floodmarks were obtained along a 94-mile reach of the Black River from Dexter to Forestport, and several floodmarks were surveyed within major communities along the Salmon River. The floodmarks were obtained primarily near major bridges and dams along these rivers. (Author 's abstract)

Similarities and Differences in Barriers and Opportunities Affecting Climate Change Adaptation Action in Four North American Landscapes

NASA Astrophysics Data System (ADS)

Lonsdale, Whitney R.; Kretser, Heidi E.; Chetkiewicz, Cheryl-Lesley B.; Cross, Molly S.

2017-12-01

Climate change presents a complex set of challenges for natural resource managers across North America. Despite recognition that climate change poses serious threats to species, ecosystems, and human communities, implementation of adaptation measures is not yet happening on a broad scale. Among different regions, a range of climate change trajectories, varying political contexts, and diverse social and ecological systems generate a myriad of factors that can affect progress on climate change adaptation implementation. In order to understand the general versus site-specific nature of barriers and opportunities influencing implementation, we surveyed and interviewed practitioners, decision-makers, and scientists involved in natural resource management in four different North American regions, northern Ontario (Canada), the Adirondack State Park (US), Arctic Alaska (US), and the Transboundary Rocky Mountains (US and Canada). Common barriers among regions related to a lack of political support and financial resources, as well as challenges related to translating complex and interacting effects of climate change into management actions. Opportunities shared among regions related to collaboration, funding, and the presence of strong leadership. These commonalities indicate the importance of cross-site learning about ways to leverage opportunities and address adaptation barriers; however, regional variations also suggest that adaptation efforts will need to be tailored to fit specific ecological, political, social and economic contexts. Comparative findings on the similarities and differences in barriers and opportunities, as well as rankings of barriers and opportunities by region, offers important contextual insights into how to further refine efforts to advance adaptation actions in those regions.

Overview of seismic potential in the central and eastern United States

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schweig, E.S.

1995-12-31

The seismic potential of any region can be framed in terms the locations of source zones, the frequency of earthquake occurrence for each source, and the maximum size earthquake that can be expect from each source. As delineated by modern and historical seismicity, the most important seismic source zones affecting the eastern United States include the New Madrid and Wabash Valley seismic zones of the central U.S., the southern Appalachians and Charleston, South Carolina, areas in the southeast, and the northern Appalachians and Adirondacks in the northeast. The most prominant of these in terms of current seismicity and historical seismicmore » moment release in the New Madrid seismic zone, which produced three earthquakes of moment magnitude {ge} 8 in 1811 and 1812. The frequency of earthquake recurrence can be examined using the instrumental record, the historical record, and the geological record. Each record covers a unique time period and has a different scale of temporal resolution and completeness of the data set. The Wabash Valley is an example where the long-term geological record indicates a greater potential than the instrumental and historical records. This points to the need to examine all of the evidence in any region in order to obtain a credible estimates of earthquake hazards. Although earthquake hazards may be dominated by mid-magnitude 6 earthquakes within the mapped seismic source zones, the 1994 Northridge, California, earthquake is just the most recent example of the danger of assuming future events will occur on faults known to have had past events and how destructive such an earthquake can be.« less

Basalt-trachybasalt samples in Gale Crater, Mars

DOE PAGES

Edwards, Peter H.; Bridges, John C.; Wiens, Roger Craig; ...

2017-09-14

The ChemCam instrument on the Mars Science Laboratory (MSL) rover, Curiosity, observed numerous igneous float rocks and conglomerate clasts, reported previously. A new statistical analysis of single-laser-shot spectra of igneous targets observed by ChemCam shows a strong peak at ~55 wt% SiO 2 and 6 wt% total alkalis, with a minor secondary maximum at 47–51 wt% SiO 2 and lower alkali content. The centers of these distributions, together with the rock textures, indicate that many of the ChemCam igneous targets are trachybasalts, Mg# = 27 but with a secondary concentration of basaltic material, with a focus of compositions around Mg#more » = 54. We suggest that all of these igneous rocks resulted from low-pressure, olivine-dominated fractionation of Adirondack (MER) class-type basalt compositions. This magmatism has subalkaline, tholeiitic affinities. The similarity of the basalt endmember to much of the Gale sediment compositions in the first 1000 sols of the MSL mission suggests that this type of Fe-rich, relatively low-Mg#, olivine tholeiite is the dominant constituent of the Gale catchment that is the source material for the fine-grained sediments in Gale. The similarity to many Gusev igneous compositions suggests that it is a major constituent of ancient Martian magmas, and distinct from the shergottite parental melts thought to be associated with Tharsis and the Northern Lowlands. Finally, the Gale Crater catchment sampled a mixture of this tholeiitic basalt along with alkaline igneous material, together giving some analogies to terrestrial intraplate magmatic provinces.« less

Similarities and Differences in Barriers and Opportunities Affecting Climate Change Adaptation Action in Four North American Landscapes.

PubMed

Lonsdale, Whitney R; Kretser, Heidi E; Chetkiewicz, Cheryl-Lesley B; Cross, Molly S

2017-12-01

Climate change presents a complex set of challenges for natural resource managers across North America. Despite recognition that climate change poses serious threats to species, ecosystems, and human communities, implementation of adaptation measures is not yet happening on a broad scale. Among different regions, a range of climate change trajectories, varying political contexts, and diverse social and ecological systems generate a myriad of factors that can affect progress on climate change adaptation implementation. In order to understand the general versus site-specific nature of barriers and opportunities influencing implementation, we surveyed and interviewed practitioners, decision-makers, and scientists involved in natural resource management in four different North American regions, northern Ontario (Canada), the Adirondack State Park (US), Arctic Alaska (US), and the Transboundary Rocky Mountains (US and Canada). Common barriers among regions related to a lack of political support and financial resources, as well as challenges related to translating complex and interacting effects of climate change into management actions. Opportunities shared among regions related to collaboration, funding, and the presence of strong leadership. These commonalities indicate the importance of cross-site learning about ways to leverage opportunities and address adaptation barriers; however, regional variations also suggest that adaptation efforts will need to be tailored to fit specific ecological, political, social and economic contexts. Comparative findings on the similarities and differences in barriers and opportunities, as well as rankings of barriers and opportunities by region, offers important contextual insights into how to further refine efforts to advance adaptation actions in those regions.

Hot Spots and Hot Times: Wildlife Road Mortality in a Regional Conservation Corridor

NASA Astrophysics Data System (ADS)

Garrah, Evelyn; Danby, Ryan K.; Eberhardt, Ewen; Cunnington, Glenn M.; Mitchell, Scott

2015-10-01

Strategies to reduce wildlife road mortality have become a significant component of many conservation efforts. However, their success depends on knowledge of the temporal and spatial patterns of mortality. We studied these patterns along the 1000 Islands Parkway in Ontario, Canada, a 37 km road that runs adjacent to the St. Lawrence River and bisects the Algonquin-to-Adirondacks international conservation corridor. Characteristics of all vertebrate road kill were recorded during 209 bicycle surveys conducted from 2008 to 2011. We estimate that over 16,700 vertebrates are killed on the road from April to October each year; most are amphibians, but high numbers of birds, mammals, and reptiles were also found, including six reptiles considered at-risk in Canada. Regression tree analysis was used to assess the importance of seasonality, weather, and traffic on road kill magnitude. All taxa except mammals exhibited distinct temporal peaks corresponding to phases in annual life cycles. Variations in weather and traffic were only important outside these peak times. Getis-Ord analysis was used to identify spatial clusters of mortality. Hot spots were found in all years for all taxa, but locations varied annually. A significant spatial association was found between multiyear hot spots and wetlands. The results underscore the notion that multi-species conservation efforts must account for differences in the seasonality of road mortality among species and that multiple years of data are necessary to identify locations where the greatest conservation good can be achieved. This information can be used to inform mitigation strategies with implications for conservation at regional scales.

Acidic deposition in the northeastern United States: Sources and inputs, ecosystem effects, and management strategies

USGS Publications Warehouse

Driscoll, C.T.; Lawrence, G.B.; Bulger, A.J.; Butler, T.J.; Cronan, C.S.; Eagar, C.; Lambert, K.F.; Likens, G.E.; Stoddard, J.L.; Weathers, K.C.

2001-01-01

North America and Europe are in the midst of a large-scale experiment. Sulfuric and nitric acids have acidified soils, lakes, and streams, thereby stressing or killing terrestrial and aquatic biota. It is therefore critical to measure and to understand the recovery of complex ecosystems in response to decreases in acidic deposition. Fortunately, the NADP, CASTNet, and AIRMoN-dry networks are in place to measure anticipated improvements in air quality and in atmospheric deposition. Unfortunately, networks to measure changes in water quality are sparse, and networks to monitor soil, vegetation, and fish responses are even more limited. There is an acute need to assess the response of these resources to decreases in acid loading. It would be particularly valuable to assess the recovery of aquatic biota - which respond directly to acid stress - to changes in surface water chemistry (Gunn and Mills 1998). We used long-term research from the HBEF and other sites across the northeastern United States to synthesize data on the effects of acidic deposition and to assess ecosystem responses to reductions in emissions. On the basis of existing data, it is clear that in the northeastern United States ??? reductions of SO2 emissions since 1970 have resulted in statistically significant decreases in SO42- in wet and bulk deposition and in surface waters ??? emissions of NOX and concentrations of NO3- in wet and bulk deposition and in surface waters have shown no increase or decrease since the 1980s ??? estimates of NH3 emissions are uncertain, although atmospheric deposition of NH4+ remains important for forest management and stream NO3- loss ??? acidic deposition has accelerated the leaching of base cations from soils, thus delaying the recovery of ANC in lakes and streams from decreased emissions of SO2 (at the HBEF the available soil Ca pool appears to have declined 50% over the past 50 years) ???sulfur and N from atmospheric deposition have accumulated in forest soils across the region, and the slow release of these stored elements from soil has delayed the recovery of lakes and streams after emissions have been reduced ??? acidic deposition has increased the concentration of toxic forms of Al in soil waters, lakes, and streams ??? acidic deposition has leached cellular Ca from red spruce foliage, which has made trees susceptible to freezing injury and led to more than 50% mortality of canopy trees in some areas of the Northeast ??? deficiencies of Ca2+ and Mg2+ have caused extensive mortality of sugar maple in Pennsylvania, and acidic deposition contributed to the depletion of these cations from soil ??? forty-one percent of lakes in the Adirondack Mountains and 15% of lakes in New England have exhibited chronic or episodic acidification or both; 83% of the affected lakes are acidic because of atmospheric deposition ??? the ANC of surface waters in New England has increased only modestly, and the Adirondack and Catskill regions have experienced no significant improvement, after decreases in atmospheric S deposition in recent decades ??? acidification of surface waters has resulted in a decrease in the survival, size, and density of fish and in the loss of fish and other aquatic biota from lakes and streams ??? emissions of air pollutants have important linkages to other large-scale environmental problems, including coastal eutrophication, mercury contamination, visibility impairment, climate change, and tropospheric ozone Moreover, we anticipate that recovery from acidic deposition will be a complex, two-phase process in which chemical recovery precedes biological recovery. The time for biological recovery is better defined for aquatic than for terrestrial ecosystems. For acid-affected aquatic ecosystems, we expect that stream populations of macroinvertebrates and lake populations of zooplankton will recover 3-10 years after favorable chemical conditions are reestablished; recovery of fish populations would follow. For terrestrial ecos

Soil base saturation combines with Beech Bark Disease to influence composition and structure of Sugar Maple-Beech forests in an acid rain-impacted region

USGS Publications Warehouse

Lawrence, Gregory B.; McDonnell, Todd C.; Sullivan, Timothy J.; Dovciak, Martin; Bailey, Scott W.; Antidormi, Michael; Zarfos, Michael R.

2018-01-01

Sugar maple, an abundant and highly valued tree species in eastern North America, has experienced decline from soil calcium (Ca) depletion by acidic deposition, while beech, which often coexists with sugar maple, has been afflicted with beech bark disease (BBD) over the same period. To investigate how variations in soil base saturation combine with effects of BBD in influencing stand composition and structure, measurements of soils, canopy, subcanopy, and seedlings were taken in 21 watersheds in the Adirondack region of NY (USA), where sugar maple and beech were the predominant canopy species and base saturation of the upper B horizon ranged from 4.4 to 67%. The base saturation value corresponding to the threshold for Al mobilization (16.8%) helped to define the species composition of canopy trees and seedlings. Canopy vigor and diameter at breast height (DBH) were positively correlated (P < 0.05) with base saturation for sugar maple, but unrelated for beech. However, beech occupied lower canopy positions than sugar maple, and as base saturation increased, the average canopy position of beech decreased relative to sugar maple (P < 0.10). In low-base saturation soils, soil-Ca depletion and BBD may have created opportunities for gap-exploiting species such as red maple and black cherry, whereas in high-base saturation soils, sugar maple dominated the canopy. Where soils were beginning to recover from acidic deposition effects, sugar maple DBH and basal area increased progressively from 2000 to 2015, whereas for beech, average DBH did not change and basal area did not increase after 2010.

Reconciling deep seismic refraction and reflection data from the grenvillian-appalachian boundary in western New England

USGS Publications Warehouse

Hughes, S.; Luetgert, J.H.; Christensen, N.I.

1993-01-01

The Grenvillian-Appalachian boundary is characterized by pervasive mylonitic deformation and retrograde alteration of a suite of imbricated allochthonous and parautochthonous gneisses that were thrust upon the Grenvillian continental margin during the lower Paleozoic. Seismic reflection profiling across this structural boundary zone reveals prominent dipping reflectors interpreted as overthrust basement slices (parautochthons) of the Green Mountain Anticlinorium. In contrast, a seismic refraction study of the Grenvillian-Appalachian boundary reveals a sub-horizontally layered seismic velocity model that is difficult to reconcile with the pronounced sub-vertical structures observed in the Green mountains. A suite of rock samples was collected from the Green Mountain Anticlinorium and measured at high pressures in the laboratory to determine the seismic properties of these allochthonous and parautochthonous gneisses. The laboratory-measured seismic velocities agree favorably with the modelled velocity structure across the Grenvillian-Appalachian boundary suggesting that the rock samples are reliable indicators of the rock mass as whole. Samples of the parautochthonous Grenvillian basement exposed in the Green Mountains have lower velocities, by about 0.5 km/s, than lithologically equivalent units exposed in the eastern Adirondack Highlands. Velocity reduction in the Green Mountain parautochthons can be accounted for by retrograde metamorphic alteration (hydration) of the paragneisses. Seismic anisotropies, ranging from 2 to 12%, in the mylonitized Green Mountain paragneisses may also contribute to the observation of lower seismic velocities, where the direction of ray propagation is normal to the foliation. The velocity properties of the Green Mountain paragneisses are thus insufficiently different from the mantling Appalachian allochthons to permit their resolution by the Ontario-New York-New England seismic refraction profile. ?? 1993.

Spatial patterns of mercury in macroinvertebrates and fishes from streams of contrasting forested landscapes in the eastern United States

USGS Publications Warehouse

Riva-Murray, Karen; Chasar, Lia C.; Bradley, Paul M.; Burns, Douglas A.; Brigham, Mark E.; Smith, Martyn J.; Abrahamsen, Thomas A.

2011-01-01

Controls on mercury bioaccumulation in lotic ecosystems are not well understood. During 2007–2009, we studied mercury and stable isotope spatial patterns of macroinvertebrates and fishes from two medium-sized (2) forested basins in contrasting settings. Samples were collected seasonally from multiple sites across the Fishing Brook basin (FBNY), in New York's Adirondack Mountains, and the McTier Creek basin (MCSC), in South Carolina's Coastal Plain. Mean methylmercury (MeHg) concentrations within macroinvertebrate feeding groups, and mean total mercury (THg) concentrations within most fish feeding groups were similar between the two regions. However, mean THg concentrations in game fish and forage fish, overall, were much lower in FBNY (1300 and 590 ng/g dw, respectively) than in MCSC (2300 and 780 ng/g dw, respectively), due to lower trophic positions of these groups from FBNY (means 3.3 and 2.7, respectively) than MCSC (means 3.7 and 3.3, respectively). Much larger spatial variation in topography and water chemistry across FBNY contributed to greater spatial variation in biotic Hg and positive correlations with dissolved MeHg and organic carbon in streamwater. Hydrologic transport distance (HTD) was negatively correlated with biotic Hg across FBNY, and was a better predictor than wetland density. The small range of landscape conditions across MCSC resulted in no consistent spatial patterns, and no discernable correspondence with local-scale environmental factors. This study demonstrates the importance of local-scale environmental factors to mercury bioaccumulation in topographically heterogeneous landscapes, and provides evidence that food-chain length can be an important predictor of broad-scale differences in Hg bioaccumulation among streams.

Earth Observation taken during the Expedition 36 mission

NASA Image and Video Library

2013-08-24

ISS036-E-035635 (24 Aug. 2013) --- Plankton bloom and Lake Ontario are featured in this image photographed by an Expedition 36 crew member on the International Space Station. This photograph highlights a late summer plankton bloom visible throughout much of Lake Ontario (one of the Great Lakes, together with Michigan, Superior, Erie, and Huron). Cyanobacteria, or blue-green algae, can reach such large concentrations that they color the water to such an extent that the change is visible from orbit. Harmful algal blooms, or HABs, have been observed in all of the Great Lakes – particularly Lake Erie - and are associated with a variety of causative factors including changes in precipitation; drought; invasive species (quagga, zebra mussels, Asian carp); nutrient loading from runoff and sewage (nitrogen and phosphorus); and warmer average temperatures. In addition to reduced water quality and human health concerns, algal blooms can also lead to hypoxia (reduction of oxygen in the bottom waters) that kills large numbers of fish and other aquatic life. Lake Ontario, like the other Great Lakes Erie, Huron, and Superior is roughly divided between the USA and Canada. The USA side of Lake Ontario has its shoreline along the state of New York, while its Canadian shoreline lies within the province of Ontario. The city of Kingston, Ontario, is visible near the Saint Lawrence River outflow from the lake. Several other landscape features of New York State are visible in the image, including the Finger Lakes region to the west of Syracuse, NY (upper left). To the northeast of Syracuse, the dark wooded slopes of the Adirondack Mountains are visible at lower right. Patchy white cloud cover obscures much of the land surface to the west of Lake Ontario.

Drivers of inverse DOC-nitrate loss patterns in forest soils and streams

NASA Astrophysics Data System (ADS)

Goodale, C. L.

2013-12-01

Nitrate loss from forested catchments varies greatly across sites and over time, with few reliable correlates. One of the few recurring patterns, however, is the negative nonlinear relationship that occurs regularly between surface water nitrate and dissolved organic carbon (DOC) concentrations: that is, nitrate declines sharply as DOC concentrations increase, and high nitrate levels occur only at low DOC concentrations. Several hypotheses have been proposed to explain this pattern, but its cause has remained speculative. It is likely to be driven by C- or N-limitation of biological processes such as assimilation or denitrification, but the identity of which biological process or the main landscape position of their activity are not known. We examined whether DOC and nitrate are both driven by soil C content, at scales of both soil blocks and across catchments, by measuring soil, soil extract, and surface water chemistry across nine catchments selected from long-term monitoring networks in the Catskill and Adirondack Mountains. We measured soil C and N status and solution nitrate, DOC, bioavailable DOC (bDOC), and isotopic composition (13C-DOC, 15N- and 18O-NO3) to examine whether variation in stocks of soil C partly controls DOC and nitrate loss from forested catchments in New York State. These measurements showed that surface soil C and C:N ratio together determine soil production of DOC and nitrate, reflecting assimilative demand for N by heterotrophic microbes. Yet, they also show that these processes do not produce the inverse DOC-NO3 curve observed at the catchment scale. Rather, catchment-scale DOC-nitrate patterns are more likely to be governed by the balance between excess nitrate production and its bDOC-mediated loss to denitrification.

Hydrological mobilization of mercury and dissolved organic carbon in a snow-dominated, forested watershed: Conceptualization and modeling

USGS Publications Warehouse

Schelker, J.; Burns, Douglas A.; Weiler, M.; Laudon, H.

2011-01-01

The mobilization of mercury and dissolved organic carbon (DOC) during snowmelt often accounts for a major fraction of the annual loads. We studied the role of hydrological connectivity of riparian wetlands and upland/wetland transition zones to surface waters on the mobilization of Hg and DOC in Fishing Brook, a headwater of the Adirondack Mountains, New York. Stream water total mercury (THg) concentrations varied strongly (mean = 2.25 ?? 0.5 ng L -1), and the two snowmelt seasons contributed 40% (2007) and 48% (2008) of the annual load. Methyl mercury (MeHg) concentrations ranged up to 0.26 ng L-1, and showed an inverse log relationship with discharge. TOPMODEL-simulated saturated area corresponded well with wetland areas, and the application of a flow algorithm based elevation-above-creek approach suggests that most wetlands become well connected during high flow. The dynamics of simulated saturated area and soil storage deficit were able to explain a large part of the variation of THg concentrations (r2 = 0.53 to 0.72). In contrast, the simulations were not able to explain DOC variations and DOC and THg concentrations were not correlated. These results indicate that all three constituents, THg, MeHg, and DOC, follow different patterns at the outlet: (1) the mobilization of THg is primarily controlled by the saturation state of the catchment, (2) the dilution of MeHg suggests flushing from a supply limited pool, and (3) DOC dynamics follow a pattern different from THg dynamics, which likely results from differing gain and/or loss processes for THg and/or DOC within the Fishing Brook catchment. Copyright 2011 by the American Geophysical Union.

Melting of the primitive martian mantle at 0.5-2.2 GPa and the origin of basalts and alkaline rocks on Mars

NASA Astrophysics Data System (ADS)

Collinet, Max; Médard, Etienne; Charlier, Bernard; Vander Auwera, Jacqueline; Grove, Timothy L.

2015-10-01

We have performed piston-cylinder experiments on a primitive martian mantle composition between 0.5 and 2.2 GPa and 1160 to 1550 °C. The composition of melts and residual minerals constrain the possible melting processes on Mars at 50 to 200 km depth under nominally anhydrous conditions. Silicate melts produced by low degrees of melting (<10 wt.%) were analyzed in layers of vitreous carbon spheres or in micro-cracks inside the graphite capsule. The total range of melt fractions investigated extends from 5 to 50 wt.%, and the liquids produced display variable SiO2 (43.7-59.0 wt.%), MgO (5.3-18.6 wt.%) and Na2O + K2O (1.0-6.5 wt.%) contents. We provide a new equation to estimate the solidus temperature of the martian mantle: T (°C) = 1033 + 168.1 P (GPa) - 14.22P2 (GPa), which places the solidus 50 °C below that of fertile terrestrial peridotites. Low- and high-degree melts are compared to martian alkaline rocks and basalts, respectively. We suggest that the parental melt of Adirondack-class basalts was produced by ∼25 wt.% melting of the primitive martian mantle at 1.5 GPa (∼135 km) and ∼1400 °C. Despite its brecciated nature, NWA 7034/7533 might be composed of material that initially crystallized from a primary melt produced by ∼10-30 wt.% melting at the same pressure. Other igneous rocks from Mars require mantle reservoirs with different CaO/Al2O3 and FeO/MgO ratios or the action of fractional crystallization. Alkaline rocks can be derived from mantle sources with alkali contents (∼0.5 wt.%) similar to the primitive mantle.

Developing recreational harvest regulations for an unexploited lake trout population

USGS Publications Warehouse

Lenker, Melissa A; Weidel, Brian C.; Jensen, Olaf P.; Solomon, Christopher T.

2016-01-01

Developing fishing regulations for previously unexploited populations presents numerous challenges, many of which stem from a scarcity of baseline information about abundance, population productivity, and expected angling pressure. We used simulation models to test the effect of six management strategies (catch and release; trophy, minimum, and maximum length limits; and protected and exploited slot length limits) on an unexploited population of Lake Trout Salvelinus namaycush in Follensby Pond, a 393-ha lake located in New York State’s Adirondack Park. We combined field and literature data and mark–recapture abundance estimates to parameterize an age-structured population model and used the model to assess the effects of each management strategy on abundance, catch per unit effort (CPUE), and harvest over a range of angler effort (0–2,000 angler-days/year). Lake Trout density (3.5 fish/ha for fish ≥ age 13, the estimated age at maturity) was similar to densities observed in other unexploited systems, but growth rate was relatively slow. Maximum harvest occurred at levels of effort ≤ 1,000 angler-days/year in all the scenarios considered. Regulations that permitted harvest of large postmaturation fish, such as New York’s standard Lake Trout minimum size limit or a trophy size limit, resulted in low harvest and high angler CPUE. Regulations that permitted harvest of small and sometimes immature fish, such as a protected slot or maximum size limit, allowed high harvest but resulted in low angler CPUE and produced rapid declines in harvest with increases in effort beyond the effort consistent with maximum yield. Management agencies can use these results to match regulations to management goals and to assess the risks of different management options for unexploited Lake Trout populations and other fish species with similar life history traits.

Energy Efficiency and Air Quality Repairs at Lyonsdale Biomass

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brower, Michael R; Morrison, James A; Spomer, Eric

2012-07-31

This project enabled Lyonsdale Biomass, LLC to effect analyses, repairs and upgrades for its biomass cogeneration facility located in Lewis County, New York and close by the Adirondack Park to reduce air emissions by improving combustion technique and through the overall reduction of biomass throughput by increasing the system's thermodynamic efficiency for its steam-electrical generating cycle. Project outcomes result in significant local, New York State, Northeast U.S. and national benefits including improved renewable energy operational surety, enhanced renewable energy efficiency and more freedom from foreign fossil fuel source dependence. Specifically, the reliability of the Lyonsdale Biomass 20MWe woody biomass combined-heatmore » and power (CHP) was and is now directly enhanced. The New York State and Lewis County benefits are equally substantial since the facility sustains 26 full-time equivalency (FTE) jobs at the facility and as many as 125 FTE jobs in the biomass logistics supply chain. Additionally, the project sustains essential local and state payment in lieu of taxes revenues. This project helps meet several USDOE milestones and contributes directly to the following sustainability goals:  Climate: Reduces greenhouse gas emissions associated with bio-power production, conversion and use, in comparison to fossil fuels. Efficiency and Productivity: Enhances efficient use of renewable resources and maximizes conversion efficiency and productivity. Profitability: Lowers production costs. Rural Development: Enhances economic welfare and rural development through job creation and income generation. Standards: Develop standards and corresponding metrics for ensuring sustainable biopower production. Energy Diversification and Security: Reduces dependence on foreign oil and increases energy supply diversity. Net Energy Balance: Ensures positive net energy balance for all alternatives to fossil fuels.« less

Commonalities in Mercury Behavior in Contrasting Northeastern USA Landscapes

NASA Astrophysics Data System (ADS)

Shanley, J. B.; Scherbatskoy, T.; Schuster, P. F.; Reddy, M. M.; Chalmers, A.

2001-05-01

Generally less than 20% of atmospherically deposited mercury is exported from watersheds in streamflow, but the mercury export that does occur is highly episodic. Our research from diverse landscapes in northern New England, including small forested, agricultural, and urban watersheds as well as some larger rivers discharging to Lake Champlain and the Atlantic Ocean, indicates a consistent positive correlation between Hg concentrations and stream discharge. This relation appears to be driven by increased DOC, POC, and suspended sediment concentrations at increased streamflow. Streamwater Hg analyses pooled from 10 watersheds of diverse size and land use during the 2000 snowmelt within the Sleepers River Research Watershed in northeastern Vermont displayed a high correlation between (1) dissolved Hg and DOC, and (2) particulate Hg and POC. The same correlations held at Nettle Brook, a forested Vermont watershed 100 km west of Sleepers River. At Nettle Brook, DOC and dissolved mercury concentrations were both greater than at Sleepers River but the relation at the two sites was co-linear. In an agricultural watershed in northwestern Vermont, particulate Hg concentrations in streamflow were comparable to those at Nettle Brook despite markedly higher suspended sediment (and presumably POC) concentrations, suggesting the soil Hg pool is depleted by more frequent erosional events. The coupling of organic carbon with mercury may originate in the shallow soil zone; high concentrations of DOC and dissolved Hg were observed in O-horizon soil solution both at Nettle Brook and at some sites in the Adirondack Mountains of New York. Our findings underscore the importance of sampling during high-flow to determine accurate fluxes of Hg in streamflow. It is not clear, however, whether organic carbon actually controls Hg mobility, or whether organic carbon and Hg move in tandem simply as a result of their common source in soil organic matter.

Permeability generation and resetting of tracers during metamorphic fluid flow: implications for advection-dispersion models

NASA Astrophysics Data System (ADS)

Cartwright, Ian

Advection-dispersion fluid flow models implicitly assume that the infiltrating fluid flows through an already fluid-saturated medium. However, whether rocks contain a fluid depends on their reaction history, and whether any initial fluid escapes. The behaviour of different rocks may be illustrated using hypothetical marble compositions. Marbles with diverse chemistries (e.g. calcite + dolomite + quartz) are relatively reactive, and will generally produce a fluid during heating. By contrast, marbles with more restricted chemistries (e.g. calcite + quartz or calcite-only) may not. If the rock is not fluid bearing when fluid infiltration commences, mineralogical reactions may produce a reaction-enhanced permeability in calcite + dolomite + quartz or calcite + quartz, but not in calcite-only marbles. The permeability production controls the pattern of mineralogical, isotopic, and geochemical resetting during fluid flow. Tracers retarded behind the mineralogical fronts will probably be reset as predicted by the advection-dispersion models; however, tracers that are expected to be reset ahead of the mineralogical fronts cannot progress beyond the permeability generating reaction. In the case of very unreactive lithologies (e.g. pure calcite marbles, cherts, and quartzites), the first reaction to affect the rocks may be a metasomatic one ahead of which there is little pervasive resetting of any tracer. Centimetre-scale layering may lead to the formation of self-perpetuating fluid channels in rocks that are not fluid saturated due to the juxtaposition of reactants. Such layered rocks may show patterns of mineralogical resetting that are not predicted by advection-dispersion models. Patterns of mineralogical and isotopic resetting in marbles from a number of terrains, for example: Chillagoe, Marulan South, Reynolds Range (Australia); Adirondack Mountains, Old Woman Mountains, Notch Peak (USA); and Stephen Cross Quarry (Canada) vary as predicted by these models.

Radar analysis of fall bird migration stopover sites in the northeastern U.S.

USGS Publications Warehouse

Buler, Jeffrey J.; Dawson, Deanna K.

2014-01-01

The national network of weather surveillance radars (WSR-88D) detects flying birds and is a useful remote-sensing tool for ornithological study. We used data collected during fall 2008 and 2009 by 16 WSR-88D radars in the northeastern U.S. to quantify the spatial distribution of landbirds during migratory stopover. We geo-referenced estimates based on radar reflectivity, of the density of migrants aloft at their abrupt evening exodus from daytime stopover sites, to the approximate locations from which they emerged. We classified bird stopover use by the magnitude and variation of radar reflectivity across nights; areas were considered “important” stopover sites for conservation if bird density was consistently high. We developed statistical models that predict potentially important stopover sites across the region, based on land cover, ground elevation, and geographic location. Large areas of regionally important stopover sites were located along the coastlines of Long Island Sound, throughout the Delmarva Peninsula, in areas surrounding Baltimore and Washington, along the western edge of the Adirondack Mountains, and within the Appalachian Mountains of southwestern Virginia and West Virginia. Locally important stopover sites generally were associated with deciduous forests embedded within landscapes dominated by developed or agricultural lands, or near the shores of major water bodies. Preserving or enhancing patches of natural habitat, particularly deciduous forests, in developed or agricultural landscapes and along major coastlines could be a priority for conservation plans addressing the stopover requirements of migratory landbirds in the northeastern U.S. Our maps of important stopover sites can be used to focus conservation efforts and can serve as a sampling frame for fieldwork to validate radar observations or for ecological studies of landbirds on migratory stopover.

Antibiotic-Resistant Genes and Pathogens Shed by Wild Deer Correlate with Land Application of Residuals.

PubMed

Rogers, Shane W; Shaffer, Carrie E; Langen, Tom A; Jahne, Michael; Welsh, Rick

2018-03-09

The purpose of this study was to investigate genetic biomarkers of zoonotic enteric pathogens and antibiotic-resistant genes (ARGs) in the feces of white-tailed deer (Odocoileus virginianus) as related to proximity of deer to land that receives livestock manure or human waste biosolid fertilizers. Deer feces were collected in the St. Lawrence River Valley and Adirondack State Park of New York. Campylobacter spp. 16S rDNA was detected in 12 of 232 fecal samples (8 of 33 sites). Salmonellae were cultivated from 2 of 182 fecal samples (2 of 29 sites). Genetic virulence markers for Shiga-like toxin I (stx 1 ) and enterohemolysin (hylA) were each detected in one isolate of Escherichia coli; E. coli O157 was not detected in any of 295 fecal samples. ARGs detected in deer feces included ermB (erythromycin-resistant gene; 9 of 295 fecal samples, 5 of 38 sites), vanA (vancomycin-resistant gene; 93 of 284 samples, 33 of 38 sites), tetQ (tetracycline-resistant gene; 93 of 295 samples, 25 of 38 sites), and sul(I) (sulfonamide-resistant gene; 113 of 292 samples, 28 of 38 sites). Genetic markers of pathogens and ARGs in deer feces were spatially associated with collection near concentrated animal feeding operations (CAFOs; Campylobacter spp., tetQ, and ermB) and land-applied biosolids (tetQ). These results indicate that contact with human waste biosolids or animal manure may be an important method of pathogen and ARG transmission and that deer in proximity to land-applied manure and human waste biosolids pose increased risk to nearby produce and water quality.

Shorter contributions to stratigraphy and structural geology, 1979

USGS Publications Warehouse

,

1980-01-01

PART A: A system of anticlines lies along the trend of the sinuous course of the Colorado River for a distance of 97 km in the central Grand Canyon. Similar anticlines occur in some perennially wet side canyons. The anticlines are most abundant and well developed along northeast-trending reaches of the main canyon where it is floored by the Cambrian Muav Limestone. Dips of the folded strata are as great as 60?, and the folding locally extends more than 250 m from the river. Low-angle thrust faults in the limbs of the anticlines parallel the river and have formed in response to folding of the comparatively brittle carbonate strata. High-angle reverse kink bands, along which rocks are displaced up toward the river, also parallel the anticlines and have develop2d in response to the upward bulging of the canyon floor. The river anticlines are an unloading phenomenon. They result from lateral squeezing toward the river of saturated shaly parts of the Muav Limestone and underlying Bright Angel Shale. The driving mechanism for the deformation is a stress gradient that results from a difference in lithostatic load between the heavily loaded rocks under the 650-m-high canyon walls and the unloaded canyon floor. Saturation appears to weaken the shaly rocks sufficiently to allow deformation to take place. River anticlines are not present in the eastern Grand Canyon, where the Cambrian rocks also occur at river level. Their absence is explained by a lack of shaly rocks that could flow when saturated. PART B: The current interest in contemporary tectonic processes in the Eastern United States is turning up abundant evidence of crustal movements in late geologic time. Topographic analysis of the highland areas from the southern Blue Ridge to the Adirondack Mountains indicates that most of the landforms owe their origin to erosion of rocks of different resistance rather than to tectonic processes. Most areas of high relief and high altitude have been formed on resistant rocks. The Cambrian and Ordovician belt, containing mostly shale and carbonate rock, on the other hand, forms an extensive lowland from Alabama to the Canadian border and girdles the Adirondack Mountains. Differences in altitude can be explained by the presence of resistant rocks outside the belt; these resistant rocks form local base levels on the streams that drain the belt. A few areas may have undergone local uplift at a higher rate than areas nearby--for example, the Piedmont region northwest of Chesapeake Bay. Most estimates of erosion rates, based on the load transported by streams and of uplift rates, based on removal during a known period of time, are of the same order of magnitude, averaging almost 4x 10^-2 millimeters per year. Rates of uplift, based on study of tilted Pleistocene beaches and repeated geodetic traverses, are at least an order of magnitude higher for comparable areas. Tectonic uplift of the highlands has been slow and involves mostly warping or tilting on a large scale. Erosion rates keep up with or exceed the rate of uplift and have been sufficient to mask evidence of faulting or other differential movements. The high rates of uplift that are inferred on tilted water planes in the glaciated regions or that are measured by differences in repeated geodetic traverses cannot have been sustained for long periods of time. PART C: The Hanson Creek Formation southwest of Eureka, Nev., in the Bellevue Peak Quadrangle is composed of three lithostratigraphic members: (1) a basal dark-gray dolomite, (2) a middle silty thin- to thick-bedded, locally nodular, dark-gray, light-yellow-mottled limestone topped by light-gray dolomite, and (3) an upper dark-gray dolomite, which is herein named the Combs Canyon Dolomite Member. Detailed geologic mapping and accompanying fossil collecting prove that the same lithostratigraphic and biostratigraphic sequence is present in the Mountain Boy Range and 11 km to the south near Wood Cone Peak. Minor differences in

Data Base for a National Mineral-Resource Assessment of Undiscovered Deposits of Gold, Silver, Copper, Lead, and Zinc in the Conterminous United States

USGS Publications Warehouse

Ludington, S.D.; Cox, D.P.; McCammon, R.B.

1996-01-01

For this assessment, the conterminous United States was divided into 12 regions Adirondack Mountains, Central and Southern Rocky Mountains, Colorado Plateau, East Central, Great Basin, Great Plains, Lake Superior, Northern Appalachians, Northern Rocky Mountains, Pacific Coast, Southern Appalachians, and Southern Basin and Range. The assessment, which was conducted by regional assessment teams of scientists from the USGS, was based on the concepts of permissive tracts and deposit models. Permissive tracts are discrete areas of the United States for which estimates of numbers of undiscovered deposits of a particular deposit type were made. A permissive tract is defined by its geographic boundaries such that the probability of deposits of the type delineated occurring outside the boundary is neglible. Deposit models, which are based on a compilation of worldwide literature and on observation, are sets of data in a convenient form that describe a group of deposits which have similar characteristics and that contain information on the common geologic attributes of the deposits and the environments in which they are found. Within each region, the assessment teams delineated permissive tracts for those deposit models that were judged to be appropriate and, when the amount of information warranted, estimated the number of undiscovered deposits. A total of 46 deposit models were used to assess 236 separate permissive tracts. Estimates of undiscovered deposits were limited to a depth of 1 km beneath the surface of the Earth. The estimates of the number of undiscovered deposits of gold, silver, copper, lead, and zinc were expressed in the form of a probability distribution. Commonly, the number of undiscovered deposits was estimated at the 90th, 50th, and 10th percentiles. A Monte Carlo simulation computer program was used to combine the probability distribution of the number of undiscovered deposits with the grade and tonnage data sets associated with each deposit model to obtain the probability distribution for undiscovered metal.

Potential environmental contaminant risks to avian species at important bird areas in the northeastern United States

USGS Publications Warehouse

Rattner, B.A.; Ackerson, B.K.

2007-01-01

Environmental contaminants, acting at molecular through population levels of biological organization, can have profound effects upon birds. A screening level risk assessment was conducted that examined potential contaminant threats at 52 Important Bird Areas (IBAs) in the northeastern Atlantic coast drainage. Using geographic information system methodology, data layers describing or integrating pollutant hazards (impaired waters, fish or wildlife consumption advisories, toxic release inventory data, estimated pesticide use and hazard) were overlaid on buffered IBA boundaries, and the relative contaminant threat for each site was ranked. The 10 sites identified as having the greatest contaminant threats included Jefferson National Forest, Stewart B. McKinney National Wildlife Refuge, Great Dismal Swamp National Wildlife Refuge, Blue Ridge Parkway, Shenandoah National Park, Adirondack Park, Edwin B. Forsythe National Wildlife Refuge, George Washington National Forest, Green Mountain National Forest, and Long Island Piping Plover Beaches. These sites accounted for over 50% of the entire study area, and in general had moderate to high percentages of impaired waters, fish consumption advisories related to mercury and PCBs, and were located in counties with substantial application rates of pesticides known to be toxic to birds. Avian species at these IBAs include Federally endangered Roseate terns (Sterna dougallii), threatened piping plovers (Charadrius melodus), neotropical migrants, Bicknell?s thrush (Catharus bicknelli), Swainson?s warbler (Limnothlypis swainsonii) and wintering brant geese (Branta bernicla). Extant data for free-ranging birds from the Contaminant Exposure and Effects--Terrestrial Vertebrates database were examined within the buffered boundaries of each IBA, and for a moderate number of sites there was qualitative concordance between the perceived risk and actual contaminant exposure data. However, several of the IBAs with substantial contaminant hazards (e.g., Blue Ridge Parkway, George Washington National Forest, Shenandoah National Park) had no recent avian ecotoxicological data. Contaminant biomonitoring is warranted at such sites, and data generated from such efforts should foster natural resource management activities.

Regional analysis of the effect of paved roads on sodium and chloride in lakes.

PubMed

Kelting, Daniel L; Laxson, Corey L; Yerger, Elizabeth C

2012-05-15

Salinization of surface water from sodium chloride (road salt) applied to paved roads is a widely recognized environmental concern in the northern hemisphere, yet practical information to improve winter road management to reduce the environmental impacts of this deicer is lacking. The purpose of our study was to provide such information by developing baseline concentrations for sodium and chloride for lakes in watersheds without paved roads, and then determining the relationship between these ions and density, type, and proximity of paved roads to shoreline. We used average summer (June-September) sodium and chloride data for 138 lakes combined in a watershed based analysis of paved road networks in the Adirondack Park of New York, U.S.A. The watersheds used in our study represented a broad range in paved road density and type, 56 of which had no paved roads. Median lake sodium and chloride concentrations in these 56 watersheds averaged 0.55 and 0.24 mg/L, respectively. In contrast, the median sodium and chloride concentrations for the 82 lakes in watersheds with paved roads were 3.60 and 7.22 mg/L, respectively. Paved road density (lane-km/km(2)) was positively correlated with sodium and chloride concentrations, but only state roads were significantly correlated with sodium and chloride while local roads were not. State road density alone explained 84 percent of the variation in both ions. We also successfully modeled the relationship between road proximity to shoreline and sodium and chloride concentrations in lakes, which allowed us to identify sections of road that contributed more to explaining the variation in sodium and chloride in lakes. This model and our approach could be used as part of larger efforts to identify environmentally sensitive areas where alternative winter road management treatments should be applied. Copyright © 2012 Elsevier Ltd. All rights reserved.

Geochemical Properties of Rocks and Soils in Gusev Crater, Mars: APXS Results from Cumberland Ridge to Home Plate

NASA Technical Reports Server (NTRS)

Ming, D. W.; Gellert, R.; Morris, R. V.; Yen, A. S.; Arvidson, E.; Brueckner, J.; Clark, B. C.; Cohen, B. A.; Fleischer, I.; Klingelhoefer, G.;

Sources of nitrate in snowmelt discharge: Evidence from water chemistry and stable isotopes of nitrate

USGS Publications Warehouse

Piatek, K.B.; Mitchell, M.J.; Silva, S.R.; Kendall, C.

2005-01-01

To determine whether NO3- concentration pulses in surface water in early spring snowmelt discharge are due to atmospheric NO 3-, we analyzed stream ??15N-NO 3- and ??18O-NO3- values between February and June of 2001 and 2002 and compared them to those of throughfall, bulk precipitation, snow, and groundwater. Stream total Al, DOC and Si concentrations were used to indicate preferential water flow through the forest floor, mineral soil, and ground water. The study was conducted in a 135-ha subcatchment of the Arbutus Watershed in the Huntington Wildlife Forest in the Adirondack Region of New York State, U.S.A. Stream discharge in 2001 increased from 0.6 before to 32.4 mm day-1 during snowmelt, and element concentrations increased from 33 to 71 ??mol L-1 for NO3-, 3 to 9 ??mol L-1 for total Al, and 330 to 570 ??mol L-1 for DOC. Discharge in 2002 was variable, with a maximum of 30 mm day-1 during snowmelt. The highest NO3-, Al, and DOC concentrations were 52, 10, and 630 ??mol L -1, respectively, and dissolved Si decreased from 148 ??mol L -1 before to 96 ??mol L-1 during snowmelt. Values of ??15N and ??18O of NO3- in stream water were similar in both years. Stream water, atmospherically- derived solutions, and groundwaters had overlapping ??15N- NO3- values. In stream and ground water, ??18O-NO3- values ranged from +5.9 to +12.9??? and were significantly lower than the +58.3 to +78.7??? values in atmospheric solutions. Values of ??18O-NO3- indicating nitrification, increase in Al and DOC, and decrease in dissolved Si concentrations indicating water flow through the soil suggested a dilution of groundwater NO3- by increasing contributions of forest floor and mineral soil NO3- during snowmelt. ?? Springer 2005.

A model for Iapetan rifting of Laurentia based on Neoproterozoic dikes and related rocks

USGS Publications Warehouse

Burton, William C.; Southworth, Scott

2010-01-01

Geologic evidence of the Neoproterozoic rifting of Laurentia during breakup of Rodinia is recorded in basement massifs of the cratonic margin by dike swarms, volcanic and plutonic rocks, and rift-related clastic sedimentary sequences. The spatial and temporal distribution of these geologic features varies both within and between the massifs but preserves evidence concerning the timing and nature of rifting. The most salient features include: (1) a rift-related magmatic event recorded in the French Broad massif and the southern and central Shenandoah massif that is distinctly older than that recorded in the northern Shenandoah massif and northward; (2) felsic volcanic centers at the north ends of both French Broad and Shenandoah massifs accompanied by dike swarms; (3) differences in volume between massifs of cover-sequence volcanic rocks and rift-related clastic rocks; and (4) WNW orientation of the Grenville dike swarm in contrast to the predominately NE orientation of other Neoproterozoic dikes. Previously proposed rifting mechanisms to explain these features include rift-transform and plume–triple-junction systems. The rift-transform system best explains features 1, 2, and 3, listed here, and we propose that it represents the dominant rifting mechanism for most of the Laurentian margin. To explain feature 4, as well as magmatic ages and geochemical trends in the Northern Appalachians, we propose that a plume–triple-junction system evolved into the rift-transform system. A ca. 600 Ma mantle plume centered east of the Sutton Mountains generated the radial dike swarm of the Adirondack massif and the Grenville dike swarm, and a collocated triple junction generated the northern part of the rift-transform system. An eastern branch of this system produced the Long Range dike swarm in Newfoundland, and a subsequent western branch produced the ca. 554 Ma Tibbit Hill volcanics and the ca. 550 Ma rift-related magmatism of Newfoundland.

Subsurface Investigation of the Internal Architecture of Massawepie Esker-Mire Complex, Gale, New York

NASA Astrophysics Data System (ADS)

Rupp, J. R.; Davis, J. L.; Robinson, S. D.

2005-05-01

The retreat of the Laurentide Ice Sheet from the Adirondack Highlands of northern New York approximately 12,500 yr. B.P. led to the development of a landscape marked by glaciofluvial landforms such as kames, outwash, kettles and eskers. The Gale, New York study site (44o 15'N, 74o38'W) contains a prominent esker approximately 30 m high that trends northeast/southwest for 12 km. A 364 ha ombrotrophic peatland underlain by outwash lies adjacent to the esker along a portion of its length. Ground Penetrating Radar (GPR) surveys were conducted on the esker and peatland areas, as well as at the contact between these landforms in an attempt to establish possible linkages between their environmental, developmental and topographic settings. Using 50 and 100 MHz antennas, the esker profiles yielded a signal penetration of approximately 20 m through primarily sand. Interpreted facies showed reflector beds of variable continuity indicative of both turbulent and laminar flow, chute and pool structures, erosional unconformities, random boulder distribution and diagenetic failure planes. On the peatland, the surveys were successful in mapping internal structure and development of the peat, and delineation of a relatively flat basal outwash unit dated at 5,600 yr. B.P. at approximately 3 m depth. The basal unit consists of medium to coarse grained sand, with discrete portions of the bed raised 2 m above the high amplitude basal reflectors suggesting possible channelization. The preliminary interpretation of a channelized base suggests that there is a link between the esker and peatland. The sinuous form of the infilled subglacial network suggests that the rise in the peatland base may be a remnant of an esker branch. This smaller remnant branch bounded by shallow stagnant ice depressions could create a landscape that would encourage peatland development. The peatland currently has three different floral zones showing different levels of wetland maturation possibly reflective of the basal topography.

The geography of So{sub 2} emissions trading

DOE Office of Scientific and Technical Information (OSTI.GOV)

Solomon, B.

1995-12-01

Interstate trading of SO{sub 2} emission allowances under the Clean Air Act Amendments of 1990 represents the largest-scale application of market principles to environmental protection. some opponents have hypothesized that high emitting electric power plants in the Midwestern states will buy additional allowances and thereby sustain SO{sub 2} emissions at unacceptable high levels. Much of these emissions would then continue to return downwind as sulfates in the Northeast, damaging critical ecosystems such as lakes and forests in the Adirondacks. A competing hypothesis is that in an increasingly competitive utility industry, a power plant will choose the least-cost compliance option formore » its SO{sub 2} emission requirements, which for many large and dirty Midwestern plants will be to retrofit with scrubbers. This paper will provide the first comprehensive empirical analysis of the geographic pattern of SO{sub 2} allowance trading for the first three years (early 1992 to early 1995) to determine the validity of the first hypothesis. It will be shown that with the exception of one electric utility in Illinois, the Midwestern states have not used allowance trading to sustain high emission levels. A Congressionally-mandated subsidy for scrubber retrofits at Phase I affected-units, however, has allowed two of these states (Ohio and Indiana) plus three additional Appalachian states (Tennessee, West Virginia and Pennsylvania) to acquire large quantities of bonus allowances. Most of these additional allowances may be banked for future use at other affected units by the acquiring utilities, since the newly scrubbed plants will have much lower SO{sub 2} emissions because of the scrubber retrofits. The good news is that the trading program is projected to save a lot of money, over $2 billion out of a possible $3 billion in annual compliance costs by the time of Phase II.« less

Spatial patterns of soil nitrification and nitrate export from forested headwaters in the northeastern United States

USGS Publications Warehouse

Ross, D.S.; Shanley, J.B.; Campbell, J.L.; Lawrence, G.B.; Bailey, S.W.; Likens, G.E.; Wemple, B.C.; Fredriksen, G.; Jamison, A.E.

2012-01-01

Nitrogen export from small forested watersheds is known to be affected by N deposition but with high regional variability. We studied 10 headwater catchments in the northeastern United States across a gradient of N deposition (5.4 - 9.4 kg ha -1 yr -1) to determine if soil nitrification rates could explain differences in stream water NO 3 - export. Average annual export of two years (October 2002 through September 2004) varied from 0.1 kg NO 3 --N ha -1 yr -1 at Cone Pond watershed in New Hampshire to 5.1 kg ha -1 yr -1 at Buck Creek South in the western Adirondack Mountains of New York. Potential net nitrification rates and relative nitrification (fraction of inorganic N as NO 3 -) were measured in Oa or A soil horizons at 21-130 sampling points throughout each watershed. Stream NO 3 - export was positively related to nitrification rates (r 2 = 0.34, p = 0.04) and the relative nitrification (r 2 = 0.37, p = 0.04). These relationships were much improved by restricting consideration to the 6 watersheds with a higher number of rate measurements (59-130) taken in transects parallel to the streams (r 2 of 0.84 and 0.70 for the nitrification rate and relative nitrification, respectively). Potential nitrification rates were also a better predictor of NO 3 - export when data were limited to either the 6 sampling points closest to the watershed outlet (r 2 = 0.75) or sampling points <250 m from the watershed outlet (r 2 = 0.68). The basal area of conifer species at the sampling plots was negatively related to NO 3 - export. These spatial relationships found here suggest a strong influence of near-stream and near-watershed-outlet soils on measured stream NO 3 - export. Copyright 2012 by the American Geophysical Union.

Moessbauer Mineralogy of Rock, Soil, and Dust at Gusev Crater, Mars: Spirit's Journey through Weakly Altered Olivine Basalt on the Plains and Pervasively Altered Basalt in the Columbia Hills

NASA Technical Reports Server (NTRS)

Morris, R. V.; Klingelhoefer, G.; Schroeder, C.; Rodionov, D. S.; Yen, A.; Ming, D. W.; deSouza, P. A., Jr.; Fleischer, I.; Wdowiak, T.; Gellert, R.;

Modelling the Properties of Rock Coatings Observed by the Mars Exploration Rovers' Alpha Particle X-ray Spectrometer and Hypthesized Environments of Formation

NASA Astrophysics Data System (ADS)

Perrett, G.; Clark, B. C.; Squyres, S. W.; Campbell, J. L.

2016-12-01

Rock coatings on Mars have been of interest to the scientific community since in situ exploration of the martian surface began in the late 1970s [1-3]. The presence of rock coatings on Mars was speculative until the positive identification of a dark coating on the Adirondack-class rock Mazatzal by the MER Rover Spirit [4]. There has since been evidence for additional rock coatings at both MER and MSL rover sites [5]. These coatings are primarily Cl-rich, which suggests aqueous activity, and their formation may be common in the martian equatorial region [6]. An important objective to better understanding these coatings and their influence on geochemical data sets is to determine their thickness and various other properties [3]. For this work additional coated rocks have been identified in the MER alpha particle X-ray spectrometer (APXS) data set [7]. Using the APXS bulk chemistry for both brushed (dust-free) and abraded (coating-free) measurements on the identified targets the thicknesses, area coverage, and coating compositions have been modelled. The modelling results for the well-studied Mazatzal coating will be compared to previous studies that report thickness [8] and compositional enrichments [4] and environments of formation will be hypothesized. The formation age of the Mazatzal coating is poorly constrained but it could have conceivably formed over a period spanning much of martian history. References: [1] Binder, A.B. et al. (1977), Journal of Geophysical Research, 82:28, 4439-4451;[2] Strickland, E.L. et al. (1979), 10th LPSC, 3, 3055-3077;[3] Guinness, E.A. et al. (1996), 27th LPSC, 27, 471-472;[4] Haskin, L. A. et al. (2005), Nature, 436, 66-69;[5] Lanza, N. et al (2016), Geophysical Research Letters, 43;[6] Clark, B.C. and R. Gellert (2016), 79th Annual Meeting of the Meteoritical Society, #6079;[7] http://pds-geosciences.wustl.edu/missions/mer/mer_apxs_oxide.htm;[8] Fleischer, I. et al (2008), Hyperfine Interact, 186, 193-198.

The rocks of Gusev Crater as viewed by the Mini-TES instrument

USGS Publications Warehouse

Ruff, S.W.; Christensen, P.R.; Blaney, D.L.; Farrand, W. H.; Johnson, J. R.; Michalski, J.R.; Moersch, J.E.; Wright, S.P.; Squyres, S. W.

2006-01-01

The Miniature Thermal Emission Spectrometer (Mini-TES) on board the Mars Exploration Rover Spirit is part of a payload designed to investigate whether a lake once existed in Gusev Crater. Mini-TES has observed hundreds of rocks along the rover's traverse into the Columbia Hills, yielding information on their distribution, bulk mineralogy, and the potential role of water at the site. Although dust in various forms produces contributions to the spectra, we have established techniques for dealing with it. All of the rocks encountered on the plains traverse from the lander to the base of the Columbia Hills share common spectral features consistent with an olivine-rich basaltic rock known as Adirondack Class. Beginning at the base of the West Spur of the Columbia Hills and across its length, the rocks are spectrally distinct from the plains but can be grouped into a common type called Clovis Class. These rocks, some of which appear as in-place outcrop, are dominated by a component whose spectral character is consistent with unaltered basaltic glass despite evidence from other rover instruments for significant alteration. The northwest flank of Husband Hill is covered in float rocks known as Wishstone Class with spectral features that can be attributed uniquely to plagioclase feldspar, a phase that represents more than half of the bulk mineralogy. Rare exceptions are three classes of basaltic "exotics" found scattered across Husband Hill that may represent impact ejecta and/or float derived from local intrusions within the hills. The rare outcrops observed on Husband Hill display distinctive spectral characteristics. The outcrop called Peace shows a feature attributable to molecular bound water, and the outcrop that hosts the rock called Watchtower displays a dominant basaltic glass component. Despite evidence from the rover's payload for significant alteration of some of the rocks, no unambiguous detection of crystalline phyllosilicates or other secondary silicates has been observed by Mini-TES. The mineralogical results supplied by Mini-TES provide no clear evidence that a lake once existed in Gusev Crater. Copyright 2006 by the American Geophysical Union.

Can the eastern red-backed salamander (Plethodon cinereus) persist in an acidified landscape?

USGS Publications Warehouse

Bondi, Cheryl A; Beier, Colin M.; Ducey, Peter K; Lawrence, Gregory B.; Bailey, Scott W.

2016-01-01

Hardwood forests of eastern North America have experienced decades of acidic deposition, leading to soil acidification where base cation supply was insufficient to neutralize acid inputs. Negative impacts of soil acidity on amphibians include disrupted embryonic development, lower growth rates, and habitat loss. However, some amphibians exhibit intraspecific variation in acid tolerance, suggesting the potential for local adaptation in areas where soils are naturally acidic. The eastern red-backed salamander (Plethodon cinereus) is a highly abundant top predator of the northern hardwood forest floor. Early research found that P. cinereus was sensitive to acidic soils, avoiding substrates with pH < 3.8 and experiencing decreased growth rates in acidic habitats. However, recent studies have documented P. cinereus populations in lower pH conditions than previously observed, suggesting some populations may persist in acidic conditions. Here, we evaluated relationships between organic horizon soil pH and P. cinereus abundance, adult health (body size and condition), and microhabitat selection, based on surveys of 34 hardwood forests in northeastern United States that encompass a regional soil pH gradient. We found no associations between soil pH and P. cinereus abundance or health, and observed that this salamander used substrates with pH similar to that available, suggesting that pH does not mediate their fine-scale distributions. The strongest negative predictor of P. cinereus abundance was the presence of dusky salamanders (Desmognathus spp.), which were most abundant in the western Adirondacks. Our results indicate that P. cinereus occupies a wider range of soil pH than has been previously thought, which has implications for their functional role in forest food webs and nutrient cycles in acid-impaired ecosystems. Tolerance of P. cinereus for more acidic habitats, including anthropogenically acidified forests, may be due to local adaptation in reproductively isolated populations and/or generalist life history traits that allow them to exploit a wider resource niche.

Variability of Plant Wax Concentrations and Carbon Isotope Values in Surface Lake Sediments Provide Clues into Their Transport and Deposition

NASA Astrophysics Data System (ADS)

Bates, B.; Lowell, T. V.; Diefendorf, A. F.; Freimuth, E. J.; Stewart, A. K.

2017-12-01

Plant wax compounds preserved in lake sediments are used as proxies for paleohydrologic reconstructions. Despite their presence in lake sediments, little is known about their transport from plants to their deposition in lake sediments. By drawing on the leaf and pollen taphonomy literature combined with sediment focusing models, it is possible to develop several working hypotheses for the transport and deposition of plant waxes in lake sediments. An improved understanding of plant wax transport and deposition into lake sediments is necessary to increase the accuracy of paleohydrologic reconstructions. To better understand the controls on plant wax transport and deposition in lake sediment, we analyzed the sedimentary plant waxes from 3 lakes in the Adirondack Mountains of New York. These lakes were chosen to capture a range of basin-specific properties to evaluate their influences on the transport and deposition of plant wax compounds in surface sediments. We spatially characterized sediment properties with surface sediment samples and high-resolution underwater imaging, acoustically profiled the sub-bottom, and measured temperature profiles. From each site, we measured n-alkanes, bulk organic content (loss-on-ignition), bulk carbon and nitrogen concentrations, C:N ratios, and bulk carbon isotopes. Preliminary n-alkane concentrations and chain length distributions, as well as bulk carbon isotopes, are variable within each lake basin suggesting a mix of aquatic and terrestrial sources. The bulk carbon isotope values for two of the three lakes show a similar range of -2‰ compared to a range of -6.3‰ at the third lake. Likewise, the range of total n-alkane concentrations is much higher in the third lake suggesting that the controls on the distribution of n-alkanes and organic carbon are different between lakes. For terrestrial plant waxes, we find low n-alkane concentrations in sandy nearshore sediments relative to higher n-alkane concentrations in deeper fine-grained sediments. Combined, this information suggests that littoral processes focus organic compounds and fine sediments towards the main depo-center of the lake. These and other observations highlight important relationships between basin-specific properties and processes controlling the transport and deposition of plant wax compounds.

Increasing Soil Calcium Availability Alters Forest Soil Carbon Stocks

NASA Astrophysics Data System (ADS)

Melvin, A.; Goodale, C. L.

2011-12-01

Acid deposition in the Northeastern U.S. has been linked to a loss of soil base cations, especially calcium (Ca). While much research has addressed the effects of Ca depletion on soil and stream acidification, few studies have investigated its effects on ecosystem carbon (C) balance. We studied the long-term effects of increased Ca availability on C cycling in a northern hardwood forest in the Adirondack Park, NY. In 1989, calcium carbonate (lime) was added to ~ 100 ha of the Woods Lake Watershed to ameliorate the effects of soil Ca depletion. An additional 100 ha were maintained as controls. We hypothesized that the lime addition would improve forest health and that this improvement would be evident in increased tree biomass, leaf litter, and fine root production. Within the forest floor, we anticipated that the increased pH associated with liming would stimulate microbial activity resulting in increased decomposition and basal soil respiration, and reduced C stocks. Additionally, we hypothesized that increased Ca availability could enhance Ca-OM complexation in the upper mineral soils, leading to increased C stocks in these horizons. Eighteen years after liming, soil pH and exchangeable Ca pools remained elevated in the forest floor and upper mineral soil of the limed plots. Forest floor C stocks were significantly larger in limed plots (68 vs. 31 t C ha-1), and were driven primarily by greater C accumulation in the forest floor Oa horizon. Mineral soil C stocks did not differ between limed and control soils. Liming did not affect tree growth, however a net decline in biomass was observed across the entire watershed. There was a trend for larger fine root and foliar litter inputs in limed plots relative to controls, but the observed forest floor accumulation appears to be driven primarily by a suppression of decomposition. Liming reduced basal soil respiration rates by 17 and 43 % in the Oe and Oa horizons, respectively. This research suggests that Ca may stabilize soil organic matter and that long-term Ca depletion caused by acid deposition could have large, unexpected effects on ecosystem C dynamics.

Inverse coupling of DOC and nitrate export from soils and streams

NASA Astrophysics Data System (ADS)

Goodale, Christine

2013-04-01

Over the last two decades, nitrate concentrations in surface waters have decreased across the Northeastern United States and parts of northern Europe. Many hypotheses have been proposed to explain this decrease, but the cause remains unclear. One control may be associated with increasing abundance of dissolved organic carbon (DOC), which in turn may be a result of soil recovery from acidification. Compared across catchments, surface water NO3- decreases sharply with increasing DOC concentration. Here, we used measurements of soil and solution nitrate, DOC, and their isotopic composition (13C-DOC, 15N- and 18O-NO3) to test several related hypotheses that changing acidification affects the release of DOC and bio-available DOC (bDOC) from soil, and that variation in stocks of soil C and release of bDOC partly control NO3- export from forested catchments in New York State, USA. We examined whether DOC and NO3- are both driven by soil C processes that produce inverse coupling at the scale of soil cores as well as across catchments, through comparison of soil and surface water chemistry across nine catchments selected from long-term monitoring networks in the Catskill and Adirondack Mountains. In addition, we conducted a series of soil core leaching experiments to examine the role of acidification and recovery in driving the net production of DOC and NO3- from soils. Over 8 months, soil cores were leached biweekly with simulated rainfall solutions of varying pH (3.6 to 7.0) from additions of H2SO4, CaCO3 and NaOH. These experiments did not yield a pH-induced change in DOC quantity, but did show a change in DOC quality, in that acidified cores released more bio-available DOC with less depleted 13C-DOC than cores with experimentally increased pH. All cores leached substantial amounts of nitrate. Together, these lab- and field comparisons are being used to identify the role of soil production and consumption processes in driving cross-watershed differences in DOC and NO3- loss, or whether other factors (e.g., riparian, in-stream or hydrologic processes) likely explain this relationship.

Source Process of the Mw 5.0 Au Sable Forks, New York, Earthquake Sequence from Local Aftershock Monitoring Network Data

NASA Astrophysics Data System (ADS)

Kim, W.; Seeber, L.; Armbruster, J. G.

2002-12-01

On April 20, 2002, a Mw 5 earthquake occurred near the town of Au Sable Forks, northeastern Adirondacks, New York. The quake caused moderate damage (MMI VII) around the epicentral area and it is well recorded by over 50 broadband stations in the distance ranges of 70 to 2000 km in the Eastern North America. Regional broadband waveform data are used to determine source mechanism and focal depth using moment tensor inversion technique. Source mechanism indicates predominantly thrust faulting along 45° dipping fault plane striking due South. The mainshock is followed by at least three strong aftershocks with local magnitude (ML) greater than 3 and about 70 aftershocks are detected and located in the first three months by a 12-station portable seismographic network. The aftershock distribution clearly delineate the mainshock rupture to the westerly dipping fault plane at a depth of 11 to 12 km. Preliminary analysis of the aftershock waveform data indicates that orientation of the P-axis rotated 90° from that of the mainshock, suggesting a complex source process of the earthquake sequence. We achieved an important milestone in monitoring earthquakes and evaluating their hazards through rapid cross-border (Canada-US) and cross-regional (Central US-Northeastern US) collaborative efforts. Hence, staff at Instrument Software Technology, Inc. near the epicentral area joined Lamont-Doherty staff and deployed the first portable station in the epicentral area; CERI dispatched two of their technical staff to the epicentral area with four accelerometers and a broadband seismograph; the IRIS/PASSCAL facility shipped three digital seismographs and ancillary equipment within one day of the request; the POLARIS Consortium, Canada sent a field crew of three with a near real-time, satellite telemetry based earthquake monitoring system. The Polaris station, KSVO, powered by a solar panel and batteries, was already transmitting data to the central Hub in London, Ontario, Canada within a day after the field crew arrived in the Au Sable Forks area. This collaboration allowed us to maximize the scarce resources available for monitoring this damaging earthquake and its aftershocks in the Northeastern U.S.

Sutures, Sinkers, Shear zones and Sills: Cryptic Targets and Explicit Strategies for EARTHSCOPE FlexArray in the East

NASA Astrophysics Data System (ADS)

Brown, L. D.

2006-05-01

Given the 3D framework represented by EarthScope's USArray as it scans eastward, the strategic challenge falls to defining cost-effective deployments of FlexArray to address specific lithospheric targets. Previous deep geophysical surveys (e.g. COCORP, USGS, GLIMPCE, et al.) provide guidance not only in framing the geological issues involved, but in designing field experiments that overcome the limitations of previous work. Opportunities highlighted by these precursor studies include: a) Collisional sutures (e.g. Brunswick Anomaly/Suwannee terrane) which lie buried beneath overthrust terranes/ younger sedimentary covers. Signal penetration in previous controlled source surveys has been insufficient. High resolution passive surveys designed to map intralithospheric detachments, Moho, and mantle subduction scars is needed to validate the extrapolations of the existing upper crustal information; b) Intracratonic basins and domes (e.g. Michigan Basin, Adirondack Dome) are perhaps the greatest geological mystery hosted in the east. Previous geophysical studies have lacked the resolution or penetration needed to identify the buoyancy drivers presumed to be responsible for such structures. It is likely that these drivers lie in the upper mantle and will require detailed velocity imaging to recognized. c) Distributed shear fabrics are a defining characteristic of the deep crust in many deformation zones (e.g. Grenville Front). Detailed mapping of crustal anisotropy associated with such shear zones should help delineate ductile flow directions associated with the orogenies that accreted the eastern U.S. 3 component, 3D active+passive surveys are needed to obtain definitive remote measures of such vector characteristics in the deep crust. d) Extensive reflectors in the central U.S. may mark important buried Precambrian basins and/or sill complexes. If the latter, the magmatic roots of those systems remain unrecognized, as does their volumetric contribution to crustal growth. 3C expanding spreads to resolve lithology in the upper crust, coupled with passive imaging of potential mantle sources, are needed to evaluate the role of these sequences in mid Proterozoic continental evolution. Effective experiments must build upon existing data, be strategic in the selection of the various FlexArray tools available, and link operationally with the Bigfoot deployments in an appropriately staged fashion.

Episodic acidification of small streams in the northeastern united states: Fish mortality in field bioassays

USGS Publications Warehouse

Van Sickle, J.; Baker, J.P.; Simonin, H.A.; Baldigo, Barry P.; Kretser, W.A.; Sharpe, W.E.

1996-01-01

In situ bioassays were performed as part of the Episodic Response Project, to evaluate the effects of episodic stream acidification on mortality of brook trout (Salvelinus fontinalis) and forage fish species. We report the results of 122 bioassays in 13 streams of the three study regions: the Adirondack mountains of New York, the Catskill mountains of New York, and the Northern Appalachian Plateau of Pennsylvania. Bioassays during acidic episodes had significantly higher mortality than did bioassays conducted under nonacidic conditions, but there was little difference in mortality rates in bioassays experiencing acidic episodes and those experiencing acidic conditions throughout the test period. Multiple logistic regression models were used to relate bioassay mortality rates to summary statistics of time-varying stream chemistry (inorganic monomeric aluminum, calcium, pH, and dissolved organic carbon) estimated for the 20-d bioassay periods. The large suite of candidate regressors also included biological, regional, and seasonal factors, as well as several statistics summarizing various features of aluminum exposure duration and magnitude. Regressor variable selection and model assessment were complicated by multicol-linearity and overdispersion. For the target fish species, brook trout, bioassay mortality was most closely related to time-weighted median inorganic aluminum. Median Ca and minimum pH offered additional explanatory power, as did stream-specific aluminum responses. Due to high multicollinearity, the relative importance of different aluminum exposure duration and magnitude variables was difficult to assess, but these variables taken together added no significant explanatory power to models already containing median aluminum. Between 59 and 79% of the variation in brook trout mortality was explained by models employing between one and five regressors. Simpler models were developed for smaller sets of bioassays that tested slimy and mottled sculpin (Cottus cognatus and C. bairdi) as well as blacknose dace (Rhinichthys atratulus). For these forage species a single inorganic aluminum exposure variable successfully accounted for 86-98% of the observed mortality. Even though field bioassays showed evidence of multiple toxicity factors, model results suggest that adequate mortality predictions can be obtained from a single index of inorganic Al concentrations during exposure periods.

Smectite formation in the presence of sulfuric acid: Implications for acidic smectite formation on early Mars

NASA Astrophysics Data System (ADS)

Peretyazhko, T. S.; Niles, P. B.; Sutter, B.; Morris, R. V.; Agresti, D. G.; Le, L.; Ming, D. W.

2018-01-01

The excess of orbital detection of smectite deposits compared to carbonate deposits on the martian surface presents an enigma because smectite and carbonate formations are both favored alteration products of basalt under neutral to alkaline conditions. We propose that Mars experienced acidic events caused by sulfuric acid (H2SO4) that permitted phyllosilicate, but inhibited carbonate, formation. To experimentally verify this hypothesis, we report the first synthesis of smectite from Mars-analogue glass-rich basalt simulant (66 wt% glass, 32 wt% olivine, 2 wt% chromite) in the presence of H2SO4 under hydrothermal conditions (∼200 °C). Smectites were analyzed by X-ray diffraction, Mössbauer spectroscopy, visible and near-infrared reflectance spectroscopy and electron microprobe to characterize mineralogy and chemical composition. Solution chemistry was determined by Inductively Coupled Plasma Mass Spectrometry. Basalt simulant suspensions in 11-42 mM H2SO4 were acidic with pH ≤ 2 at the beginning of incubation and varied from acidic (pH 1.8) to mildly alkaline (pH 8.4) at the end of incubation. Alteration of glass phase during reaction of the basalt simulant with H2SO4 led to formation of the dioctahedral smectite at final pH ∼3 and trioctahedral smectite saponite at final pH ∼4 and higher. Anhydrite and hematite formed in the final pH range from 1.8 to 8.4 while natroalunite was detected at pH 1.8. Hematite was precipitated as a result of oxidative dissolution of olivine present in Adirondack basalt simulant. Formation of secondary phases, including smectite, resulted in release of variable amounts of Si, Mg, Na and Ca while solubilization of Al and Fe was low. Comparison of mineralogical and solution chemistry data indicated that the type of smectite (i.e., dioctahedral vs trioctahedral) was likely controlled by Mg leaching from altering basalt and substantial Mg loss created favorable conditions for formation of dioctahedral smectite. We present a model for global-scale smectite formation on Mars via acid-sulfate conditions created by the volcanic outgassing of SO2 in the Noachian and early Hesperian.

Chemical evaluation of soil-solution in acid forest soils

USGS Publications Warehouse

Lawrence, G.B.; David, M.B.

1996-01-01

Soil-solution chemistry is commonly studied in forests through the use of soil lysimeters.This approach is impractical for regional survey studies, however, because lysimeter installation and operation is expensive and time consuming. To address these problems, a new technique was developed to compare soil-solution chemistry among red spruce stands in New York, Vermont, New Hampshire, Maine. Soil solutions were expelled by positive air pressure from soil that had been placed in a sealed cylinder. Before the air pressure was applied, a solution chemically similar to throughfall was added to the soil to bring it to approximate field capacity. After the solution sample was expelled, the soil was removed from the cylinder and chemically analyzed. The method was tested with homogenized Oa and Bs horizon soils collected from a red spruce stand in the Adirondack Mountains of New York, a red spruce stand in east-central Vermont, and a mixed hardwood stand in the Catskill Mountains of New York. Reproducibility, effects of varying the reaction time between adding throughfall and expelling soil solution (5-65 minutes) and effects of varying the chemical composition of added throughfall, were evaluated. In general, results showed that (i) the method was reproducible (coefficients of variation were generally < 15%), (ii) variations in the length of reaction-time did not affect expelled solution concentrations, and (iii) adding and expelling solution did not cause detectable changes in soil exchange chemistry. Concentrations of expelled solutions varied with the concentrations of added throughfall; the lower the CEC, the more sensitive expelled solution concentrations were to the chemical concentrations of added throughfall. Addition of a tracer (NaBr) showed that the expelled solution was a mixture of added solution and solution that preexisted in the soil. Comparisons of expelled solution concentrations with concentrations of soil solutions collected by zero-tension and tension lysimetry indicated that expelled solution concentrations were higher than those obtained with either type of lysimeter, although there was less difference with tension lysimeters than zero-tension lysimeters. The method used for collection of soil solution should be taken into consideration whenever soil solution data are being interpreted.

Earthquake source parameter and focal mechanism estimates for the Western Quebec Seismic Zone in eastern Canada

NASA Astrophysics Data System (ADS)

Rodriguez Padilla, A. M.; Onwuemeka, J.; Liu, Y.; Harrington, R. M.

2017-12-01

The Western Quebec Seismic Zone (WQSZ) is a 160-km-wide band of intraplate seismicity extending 500 km from the Adirondack Highlands (United States) to the Laurentian uplands (Canada). Historically, the WQSZ has experienced over fifteen earthquakes above magnitude 5, with the noteworthy MN5.2 Ladysmith event on May 17, 2013. Previous studies have associated seismicity in the area to the reactivation of Early Paleozoic normal faults within a failed Iapetan rift arm, or strength contrasts between mafic intrusions and felsic rocks due to the Mesozoic track of the Great Meteor hotspot. A good understanding of seismicity and its relation to pre-existing structures requires information about event source properties, such as static stress drop and fault plane orientation, which can be constrained via spectral analysis and focal mechanism solutions. Using data recorded by the CNSN and USArray Transportable Array, we first characterize b-value for 709 events between 2012 and 2016 in WQSZ, obtaining a value of 0.75. We then determine corner frequency and seismic moment values by fitting S-wave spectra on transverse components at all stations for 35 events MN 2.7+. We select event pairs with highly similar waveforms, proximal hypocenters, and magnitudes differing by 1-2 units. Our preliminary results using single-station spectra show corner frequencies of 15 to 40 Hz and stress drop values between 7 and 130 MPa, typical of intraplate seismicity. Last, we solve focal mechanism solutions of 35 events with impulsive P-wave arrivals at a minimum of 8 stations using the hybridMT moment tensor inversion algorithm. Our preliminary results suggest predominantly thrust faulting mechanisms, and at times oblique thrust faulting. The P-axis trend of the focal mechanism solutions suggests a principal stress orientation of NE-SW, which is consistent with that derived from focal mechanisms of earthquakes prior to 2013. We plan to fit the event pair spectral ratios to correct for attenuation effects and more accurately constrain the corner frequency values which can lead to more accurate static stress drop estimates, particularly of the larger events within an event pair.

Strategic graphite, a survey

USGS Publications Warehouse

Cameron, Eugene N.; Weis, Paul L.

1960-01-01

Strategic graphite consists of certain grades of lump and flake graphite for which the United States is largely or entirely dependent on sources abroad. Lump graphite of high purity, necessary in the manufacture of carbon brushes, is imported from Ceylon, where it occurs in vein deposits. Flake graphite, obtained from deposits consisting of graphite disseminated in schists and other metamorphic rocks, is an essential ingredient of crucibles used in the nonferrous metal industries and in the manufacture of lubricants and packings. High-quality flake graphite for these uses has been obtained mostly from Madagascar since World War I. Some flake graphite of strategic grade has been produced, however, from deposits in Texas, Alabama, and Pennsylvania. The development of the carbon-bonded crucible, which does not require coarse flake, should lessen the competitive advantage of the Madagascar producers of crucible flake. Graphite of various grades has been produced intermittently in the United States since 1644. The principal domestic deposits of flake graphite are in Texas, Alabama, Pennsylvania, and New York. Reserves of flake graphite in these four States are very large, but production has been sporadic and on the whole unprofitable since World War I, owing principally to competition from producers in Madagascar. Deposits in Madagascar are large and relatively high in content of flake graphite. Production costs are low and the flake produced is of high quality. Coarseness of flake and uniformity of the graphite products marketed are cited as major advantages of Madagascar flake. In addition, the usability of Madagascar flake for various purposes has been thoroughly demonstrated, whereas the usability of domestic flake for strategic purposes is still in question. Domestic graphite deposits are of five kinds: deposits consisting of graphite disseminated in metamorphosed siliceous sediments, deposits consisting of graphite disseminated in marble, deposits formed by thermal or dynamothermal metamorphism of coal beds or other highly carbonaceous sediments, vein deposits, and contact metasomatic deposits in marble. Only the first kind comprises deposits sufficiently large and rich in flake graphite to be significant potential sources of strategic grades of graphite. Vein deposits in several localities are known, but none is known to contain substantial reserves of graphite of strategic quality.Large resources of flake graphite exist in central Texas, in northeastern Alabama, in eastern Pennsylvania, and in the eastern Adirondack Mountains of New York. Tonnages available, compared with the tonnages of flake graphite consumed annually in the United States, are very large. There have been indications that flake graphite from Texas, Alabama, and Pennsylvania can be used in clay-graphite crucibles as a substitute for Madagascar flake, and one producer has made progress in establishing markets for his flake products as ingredients of lubricants. The tonnages of various commercial grades of graphite recoverable from various domestic deposits, however, have not been established; hence, the adequacy of domestic resources of graphite in a time of emergency is not known.The only vein deposits from which significant quantities of lump graphite have been produced are those of the Crystal Graphite mine, Beaverhead County, Mont. The deposits are fracture fillings in Precambrian gneiss and pegmatite. Known reserves in the deposits are small. In Texas, numerous flake-graphite deposits occur in the Precambrian Packsaddle schist in Llano and Burnet Counties. Graphite disseminated in certain parts of this formation ranges from extremely fine to medium grained. The principal producer has been the mine of the Southwestern Graphite Co., west of the town of Burnet. Substantial reserves of medium-grained graphite are present in the deposit mined by the company. In northeastern Alabama, flake-graphite deposits occur in the Ashland mica schist in two belts that trend northeastward across Clay, Goosa, and Chilton Counties. The northeastern belt has been the most productive. About 40 mines have been operated at one time or another, but only a few have been active during or since World War I. The deposits consist of flake graphite disseminated in certain zones or "leads" consisting of quartz-mica-feldspar schists and mica quartzite. Most of past production has come from the weathered upper parts of the deposits, but unweathered rock has been mined at several localities. Reserves of weathered rock containing 3 to 5 percent graphite are very large, and reserves of unweathered rock are even greater. Flake graphite deposits in Chester County, Pa., have been worked intermittently since about 1890. The deposits consist of medium- to coarse-grained graphite disseminated in certain belts of the Pickering gneiss. The most promising deposit is one worked in the Benjamin Franklin and the Eynon Just mines. Reserves of weathered rock containing 1.5 percent graphite are of moderate size; reserves of unweathered rock are large. In the eastern Adirondack Mountains in New York there are two principal kinds of flake-graphite deposits: contact-metasomatic deposits and those consisting of flake graphite disseminated in quartz schist. The contact-metasomatic deposits are small, irregular, and very erratic in graphite content. The deposits in quartz schist are very large, persistent, and uniform in grade. There are large reserves of schist containing 3 to 5 percent graphite, but the graphite is relatively fine grained.

REE Mineralization in Kiruna-type Magnetite-Apatite Ore Deposits: Magmatism and Metasomatism

NASA Astrophysics Data System (ADS)

Harlov, D. E.

2015-12-01

Magnetite-apatite ore bodies of the Kiruna type occur worldwide and are generally associated with volcanic rocks or volcanism. They also show strong evidence of extensive metasomatism over a wide P-T range. Notable examples include the Kiirunavaara ore body, northern Sweden (Harlov et al., 2002, Chem. Geol., 191, 47-72); the Grängesberg ore body, central Sweden (Jonsson et al., 2010, NGF abstracts, vol 1, 88-89); the Mineville ore body, Adirondacks, New York, USA (McKeown and Klemc, 1956, U.S. Geol Sur Bull (1956), pp. 9-23); the Pea Ridge ore body, SE Missouri, USA (Kerr, 1998, MS Thesis, Univ. Windsor, Windsor, Ontario, Canada 113 pp); the Jurassic Marcona ore body in south-central Peru (Chen et al., 2010, Econ Geol, 105, 1441-1456); and a collection of ore bodies from the Bafq Region, central Iran (Daliran et al., 2010, Geol. Assoc. Canada, Short Course Notes, v. 20, p.147-159). In these ore bodies, low Th and U monazite, xenotime, allanite, REE carbonates, and/or REE fluorides are commonly associated with the apatite as inclusions, rim grains, or as independent grains in the surrounding mineral matrix. High contrast BSE imaging, coupled with EMPA and LA-ICPMS, indicates that the apatite has experienced fluid-induced alteration in the form of (Y+REE) + Na + Si + Cl depletion implying that it served as the source for the (Y+REE) (e.g. Kiirunavaara, northern Sweden; Harlov et al., 2002). Formation of monazite and xenotime associated with fluorapatite, as inclusions or rim grains, has experimentally been demonstrated to originate from the fluorapatite as the result of fluid-aided, coupled dissolution-reprecipitation processes (Harlov et al., 2005, Contrib. Mineral. Petrol. 150, 268-286). This is explains the low Th and U content of the monazite and xenotime. Fluid sources could range from 700-900 °C, residual, acidic (HCl, H2HSO4) grain boundary fluids, remaining after the last stages of ore body crystallization, to later stage, cooler (< 600 °C) (H2O-CO2-(Na,K)Cl) fluids originating in the surrounding country rock or as fluids associated with metamorphic events such as regional albitization or actinolization. The abundance of (Y+REE)-bearing minerals in these deposits suggests that in addition to being mined for their Fe ore, they could also be economically mined for (Y+REE) as well.

Chapter L: U.S. Industrial Garnet

USGS Publications Warehouse

Evans, James G.; Moyle, Phillip R.

2006-01-01

The United States presently consumes about 16 percent of global production of industrial garnet for use in abrasive airblasting, abrasive coatings, filtration media, waterjet cutting, and grinding. As of 2005, domestic garnet production has decreased from a high of 74,000 t in 1998, and imports have increased to the extent that as much as 60 percent of the garnet used in the United States in 2003 was imported, mainly from India, China, and Australia; Canada joined the list of suppliers in 2005. The principal type of garnet used is almandite (almandine), because of its specific gravity and hardness; andradite is also extensively used, although it is not as hard or dense as almandite. Most industrial-grade garnet is obtained from gneiss, amphibolite, schist, skarn, and igneous rocks and from alluvium derived from weathering and erosion of these rocks. Garnet mines and occurrences are located in 21 States, but the only presently active (2006) mines are in northern Idaho (garnet placers; one mine), southeastern Montana (garnet placers; one mine), and eastern New York (unweathered bedrock; two mines). In Idaho, garnet is mined from Tertiary and (or) Quaternary sedimentary deposits adjacent to garnetiferous metapelites that are correlated with the Wallace Formation of the Proterozoic Belt Supergroup. In New York, garnet is mined from crystalline rocks of the Adirondack Mountains that are part of the Proterozoic Grenville province, and from the southern Taconic Range that is part of the northern Appalachian Mountains. In Montana, sources of garnet in placers include amphibolite, mica schist, and gneiss of Archean age and younger granite. Two mines that were active in the recent past in southwestern Montana produced garnet from gold dredge tailings and saprolite. In this report, we review the history of garnet mining and production and describe some garnet occurrences in most of the Eastern States along the Appalachian Mountains and in some of the Western States where industrial-grade garnet or its possible occurrence has been reported. Other natural and manmade materials compete with garnet in nearly all of the applications for which garnet can be used; garnet, however, has the advantages that it is reusable, nontoxic, and nonreactive. In addition, garnet produces much less dust than other abrasive materials, and spills are relatively benign and easy to clean up.

ROCK AND SOIL PHYSICAL PROPERTIES AT THE MER GUSEV CRATER AND MERIDIANI PLANUM LANDING SITES

NASA Technical Reports Server (NTRS)

Ming, Douglas W.; Richter, L.; Arvidson, R.; Bell, J.; Cabrol, N.; Gorevan, S.; Greeley, R.; Herkenhoff, K.

2006-01-01

Following the successful landings of both Mars Exploration Rover (MER) vehicles at Gusev Crater and Meridiani Planum, respectively, their Athena suite of instruments is being used to study the geologic history of these two very different landing sites on Mars that had been selected on the basis of showing different types of evidence for aqueous processes in the planet s past. Utilizing the on-board instruments as well as the rovers mobility system, a wide range of physical properties investigations is carried out as well - the subject of this abstract - that provide additional information on the geology and processes at the sites. Results of the mission in general as well as of the physical properties studies thus far greatly exceed expectations in that observations and measurements by both vehicles show a rich variety in materials and processes: the Gusev site in the vicinity of the lander is remarkably flat and generally devoid of large rocks along traverses up to the time of this writing (approx.Sol 50) and suggestive of a deflated surface with generally only thin veneers of bright dust while exhibiting evidence of a widespread occurrence of a crust from cemented fines that has been observed to fail in the form of blocky clods when disturbed by vehicle rolling action; numerous small and shallow depressions - presumably created by impacts - are observed at the site which are infilled with bright, fine-grained material that likewise appears indurated and which was studied by a trenching experiment; small ripple bedforms are scattered across the site and were characterized in terms of particle size distributions. At the Meridiani site, studies so far - up to approx.Sol 33 - have focussed on soils and the rock outcrop encountered within the approx.20 m diameter crater that the spacecraft came to rest in: from a physical properties point of view, a mantle of dark, well-sorted, apparently basaltic sand with small to moderate cohesion has been of interest - and has been studied by a trenching experiment - as well as a fine-grained unit underlying the mantle at least locally within the crater. Rock grindings were accomplished successfully at both sites at the time of this writing, suggesting different strengths of the two targets (the basaltic rock nicknamed Adirondack at Gusev and the Meridiani rock outcrop) in addition to enabling compositional measurements below the original rock surfaces.

Meteorological effects on Hg wet deposition in a forested site in the Adirondack region of New York during 2000-2015

NASA Astrophysics Data System (ADS)

Mao, Huiting; Ye, Zhuyun; Driscoll, Charles

2017-11-01

An analysis of weekly measurement data of mercury (Hg) wet deposition was conducted for Huntington Wildlife Forest (HWF), a forest ecosystem in Upstate New York and a biological Hg hotspot, during 2000-2015. Annual accumulated Hg wet deposition flux was found to decrease at a rate of -0.13 μg m-2 yr-1 (2% yr-1) (p = 0.09), and volume weighted mean (VWM) Hg precipitation concentrations at -0.14 ng L-1 yr-1 (2.5% yr-1) (p = 0.00). In examining data by season, no trends were identified for the two variables. It was found that the North Atlantic Oscillation (NAO) affected Hg wet deposition predominantly in spring, as did the position of the U.S. East Coast trough in summer, which suggests different dominant mechanisms driving Hg wet deposition in different seasons. The impacts of such large scale circulation processes were facilitated via variations in precipitation amounts. This was manifested in spring 2011 with the strongest positive phase of NAO, resulting in the wettest spring with the largest Hg wet deposition flux, and in summer 2007 with the U.S. East Coast trough positioned the farthest out over the Atlantic Ocean, causing the driest summer with the lowest Hg wet deposition flux of the study period. Extreme precipitation amounts in spring could singularly drive the overall long-term trend in Hg wet deposition whereas in summer other factors could just be as important. Similar mechanisms were thought to control the long term variations of Hg wet deposition and precipitation concentrations in all seasons but summer as indicated in their significant correlation in all but summer. Atmospheric concentrations of gaseous oxidized mercury (GOM) and particulate borne mercury (PBM) at HWF over 2009-2015 hardly exhibited correlations with Hg wet deposition or precipitation concentrations. Chemical transport model simulations strongly supported efficient scavenging of oxidized Hg by precipitation resulting in the lowest concentration of GOM in the warm season despite the supposedly largest GOM production. Our findings suggest that over the long run climate change could play an important role in atmospheric deposition of Hg into ecosystems facilitated by precipitation amounts, which is closely linked to variations in large scale circulation.

Radarclinometry: Bootstrapping the radar reflectance function from the image pixel-signal frequency distribution and an altimetry profile

USGS Publications Warehouse

Wildey, R.L.

1988-01-01

A method is derived for determining the dependence of radar backscatter on incidence angle that is applicable to the region corresponding to a particular radar image. The method is based on enforcing mathematical consistency between the frequency distribution of the image's pixel signals (histogram of DN values with suitable normalizations) and a one-dimensional frequency distribution of slope component, as might be obtained from a radar or laser altimetry profile in or near the area imaged. In order to achieve a unique solution, the auxiliary assumption is made that the two-dimensional frequency distribution of slope is isotropic. The backscatter is not derived in absolute units. The method is developed in such a way as to separate the reflectance function from the pixel-signal transfer characteristic. However, these two sources of variation are distinguishable only on the basis of a weak dependence on the azimuthal component of slope; therefore such an approach can be expected to be ill-conditioned unless the revision of the transfer characteristic is limited to the determination of an additive instrumental background level. The altimetry profile does not have to be registered in the image, and the statistical nature of the approach minimizes pixel noise effects and the effects of a disparity between the resolutions of the image and the altimetry profile, except in the wings of the distribution where low-number statistics preclude accuracy anyway. The problem of dealing with unknown slope components perpendicular to the profiling traverse, which besets the one-to-one comparison between individual slope components and pixel-signal values, disappears in the present approach. In order to test the resulting algorithm, an artificial radar image was generated from the digitized topographic map of the Lake Champlain West quadrangle in the Adirondack Mountains, U.S.A., using an arbitrarily selected reflectance function. From the same map, a one-dimensional frequency distribution of slope component was extracted. The algorithm recaptured the original reflectance function to the degree that, for the central 90% of the data, the discrepancy translates to a RMS slope error of 0.1 ???. For the central 99% of the data, the maximum error translates to 1 ???; at the absolute extremes of the data the error grows to 6 ???. ?? 1988 Kluwer Academic Publishers.

X-ray photoelectron spectroscopic evidence for bacteria-enhanced dissolution of hornblende

NASA Astrophysics Data System (ADS)

Kalinowski, B. E.; Liermann, L. J.; Brantley, S. L.; Barnes, A.; Pantano, C. G.

2000-04-01

An Arthrobacter species capable of extracting Fe from hornblende was isolated from a soil from the Adirondacks, NY (USA). This bacteria isolate, used in batch experiments with hornblende, accelerated the release of Fe from hornblende without measurably affecting Al release. The isolate produces both low molecular weight organic acids (LMWOA) and a catecholate siderophore. Polished hornblende (glass and crystal) discs were analyzed with X-ray photoelectron spectroscopy (XPS) before and after incubation with growing Arthrobacter sp. to investigate whether the bacteria caused a distinguishable chemical signature on the upper 100 Å of mineral surface. After removal of the arthrobacter grown on hornblende crystal or glass substrates using lysozyme, XPS revealed surface depletion of Fe for samples grown for several days in buffered (crystal) and unbuffered (crystal and glass) media. Fe/Si ratios of hornblende surfaces dissolved under biotic conditions are significantly lower than Fe/Si ratios on surfaces dissolved under abiotic conditions for similar amounts of time. Enhanced Fe release and the formation of Fe-depleted surfaces is inferred to be caused by catechol complexation at the mineral surface. Because natural siderophore was not isolated in sufficient quantities to run bacteria-free leaching experiments, parallel investigations were run with a commercially available siderophore (desferrioxamine B). Desferrioxamine B was observed to enhance release of Fe, Si, and Al from hornblende both with and without added bacteria. Formation of desferrioxamine-Fe surface complexes were probed by studying the multiple splitting and shift in intensities of the N 1s line analyzed by XPS on siderophore ± Fe on gold surfaces and siderophore + hornblende crystal surfaces. Based upon the observed formation of an hydroxamate (desferrioxamine) surface complex on hornblende, we infer that catecholate siderophores, such as those produced by the arthrobacter, also complex on the hornblende surface. Surface complexation is favored because of the extremely high association constants for siderophore + Fe(III). X-ray photoelectron spectroscopic data is therefore consistent with a model wherein enhanced Fe release by these bacteria or desferrioxamine B is caused by Fe-siderophore complexation at the silicate surface. Such complexation presumably weakens bonds between the Fe and the oxide lattice, causing enhanced Fe leaching and an Fe-depleted surface. Some leaching may also be due to LMWOA, although this is interpreted to be of secondary importance.

Depth to the Moho in Southern New England and Eastern New York State from Seismic Receiver Functions

NASA Astrophysics Data System (ADS)

Cipar, J. J.; Ebel, J.

2016-12-01

The thickness of the Earth's crust is a fundamental parameter of geophysics and geology. The eastern New York/southern New England area encompasses the suture between the Paleozoic Appalachian orogen and the Proterozoic Laurentian craton. The recent installation of the IRIS Traveling Array (TA) in 2013-2014 coupled with stations operated by Boston College, Lamont-Doherty, and the US National Seismic Network provide an unprecedented source of data for seismic studies of crustal structure. We use the receiver functions complied by the EarthScope Automated Receiver Survey (EARS) to measure crustal thickness. Our procedure is to stack receiver functions (RFs) at each station using the correct moveout for the P-to-S conversion at the Moho (Ps phase). The time difference between the Ps and direct P arrivals (Ps-P time) is dependent on crustal thickness (H) and crustal S-wave velocity (Vs). To get an estimate of H, we assume that the mean P-wave velocity (Vp) in the crust is 6.5 km/s, and determine the range of Vs for a range of Poisson's ratio (0.23-0.27). We then solve for H using the P-Ps times measured from the RF stacks (at Δ=60°) and our estimates for Vp and Vs. The uncertainty in S-wave velocity translates to approximately ±2 km uncertainty in crustal thickness. Our crustal thickness map shows the well-known general progression from shallow crust near the Atlantic coast line ( 30 km) to deeper crust (45+ km) in the Laurentian craton. However, some detailed features become evident on our map. Most notably, thin crust ( 30 km) extends inland from the coast to the Connecticut River valley in eastern-central Massachusetts and southeastern New Hampshire. The Berkshire Hills of western Massachusetts have thick crust (43 km), reaching as deep as 46 km in extreme northwestern Massachusetts. Thus, there is a 13-15 km increase in crustal thickness over a distance of about 60 km. Currently, no stations are located in that zone. We find that the eastern Adirondacks have very thick crust, generally in excess of 45 km. Overall, our crustal thickness measurements are in excellent agreement with those from the 1988 Ontario-New York-New England refraction experiment (USGS) and from a local receiver function study conducted using closely-spaced stations (John Schuh, Boston College).

Structurally bound sulfide and sulfate in apatite from the Philips Mine iron oxide - apatite deposit, New York, USA: A tracer of redox changes

NASA Astrophysics Data System (ADS)

Sadove, G.; Konecke, B.; Fiege, A.; Simon, A. C.

2017-12-01

Multiple competing hypotheses attempt to explain the genesis of iron oxide-apatite (IOA) ore deposits. Many studies have investigated the chemistry of apatite because the abundances of F and Cl can distinguish magmatic vs. hydrothermal processes. Recent experiments demonstrate that apatite incorporates S6+, S4+, and S2-, and that total sulfur (∑S) as well as the S6+/∑S ratio in apatite vary systematically as a function of oxygen fugacity [1], providing information about sulfur budget and redox. Here, we present results from X-ray absorption near-edge structure (XANES) spectroscopy at the S K-edge, electron microprobe analyses, cathodoluminescence (CL) imaging, and element mapping of apatite from the Philip's Mine IOA deposit, southern Adirondack Mountains, USA. The Philip's Mine apatite contains inclusions of pyrite and pyrrhotite, where the latter includes iron oxide and Ni-rich domains. The apatite also contains inclusions of monazite, and exhibits complex CL zonation coincident with variations in the abundances of REE and S. The presence of monazite fingerprints fluid-mediated dissolution-reprecipitation of originally REE-enriched apatite [2]. The S XANES spectra reveal varying proportions of structurally bound S6+ and S2-, as the S6+/∑S ratio ranges from sulfide-only to sulfate-only. Notably, sulfide-dominated domains contain higher S contents than sulfate-dominated regions. These observations are consistent with co-crystallization of apatite and monosulfide solid solution (MSS) at reducing conditions, followed by decomposition of MSS to pyrrhotite, pyrite and intermediate solid solution (ISS, which is not preserved; [3]). Metasomatism of that assemblage by an oxidized fluid resulted in formation of monazite in apatite and iron oxide domains in pyrrhotite. We conclude that the deposit formed by a H2S-Fe-rich volatile phase, possibly evolved from a rather primitive magmatic source, which is consistent with the low Ti content of magnetite. The deposit was subsequently altered by a rather oxidized SO2-poor volatile phase more typical of evolved felsic source regions. [1] Konecke et al. (2017) American Mineralogist 102-3, 548-557; [2] Harlov (2015) Elements 11-3, 171-176; [3] Edmonds & Mather (2017) Elements 13-2, 105-110.

Hydrogeologic comparison of an acidic-lake basin with a neutral-lake basin in the West-Central Adirondack Mountains, New York

USGS Publications Warehouse

Peters, N.E.; Murdoch, Peter S.

1985-01-01

Two small headwater lake basins that receive similar amounts of acidic atmospheric deposition have significantly different lake outflow pH values; pH at Panther Lake (neutral) ranges from about 4.7 to 7; that at Woods Lake (acidic) ranges from about 4.3 to 5. A hydrologic analysis, which included monthly water budgets, hydrograph analysis, examination of flow duration and runoff recession curves, calculation of ground-water storage, and an analysis of lateral flow capacity of the soil, indicates that differences in lakewater pH can be attributed to differences in the ground-water contribution to the lakes. A larger percentage of the water discharged from the neutral lake is derived from ground water than that from the acidic lake. Ground water has a higher pH resulting from a sufficiently long residence time for neutralizing chemical reactions to occur with the till. The difference in ground-water contribution is attributed to a more extensive distribution of thick till (<3m) in the neutral-lake basin than in the acidic-lake basin; average thickness of till in the neutral-lake basin is 24m whereas that in the other is 2.3m. During the snowmelt period, as much as three months of accumulated precipitation may be released within two weeks causing the lateral flow capacity of the deeper mineral soil to be exceeded in the neutral-lake basin. This excess water moves over and through the shallow acidic soil horizons and causes the lakewater pH to decrease during snowmelt.Two small headwater lake basins that receive similar amounts of acidic atmospheric deposition have significantly different lake outflow pH values; pH at Panther Lake (neutral) ranges from about 4. 7 to 7; that at Woods Lake (acidic) ranges from about 4. 3 to 5. A hydrologic analysis, which included monthly water budgets, hydrograph analysis, examination of flow duration and runoff recession curves, calculation of ground-water storage, and an analysis of lateral flow capacity of the soil, indicates that differences in lakewater pH can be attributed to differences in the ground-water contribution to the lakes. A larger percentage of the water discharged from the neutral lake is derived from ground water than that from the acidic lake. Ground water has a higher pH resulting from a sufficiently long residence time for neutralizing chemical reactions to occur with the till.

A River Summer on the Hudson

NASA Astrophysics Data System (ADS)

Kenna, T. C.; Pfirman, S.; Selleck, B.; Son, L.; Land, M.; Cronin, J.

2006-12-01

River Summer is a month-long faculty development program extending from the continental shelf off New York City to the headwaters of the Hudson in the Adirondack Mountains. During the program, faculty from the Environmental Consortium of Hudson Valley Colleges and Universities teach each other about the Hudson environment, using innovative methods of teaching and learning, with a focus on incorporation of hands-on approaches from the perspective of multiple disciplines. Over four weeks, faculty from research universities, community colleges, liberal arts institutions, and middle and high schools work and live together, on board a research vessel or in a remote tent campsite, for several days at a time. Using the geology, hydrology, and landscape of the River as a foundation, River Summer focuses on understanding development of the Hudson within the context of its natural resources and cultural history. Participants conduct field sampling and analyses and consider issues through approaches that are common to many disciplines: scaling for problem solving; sampling and assessing bias and representation; observing and documenting; representing and depicting; interpretation and assessing relationships and causality; and evaluation. They also get a chance to experience, first-hand, the complexity and often open-ended nature of doing science. By allowing individuals, many of whom come from non-science disciplines, to experience these methods and processes in a safe learning environment, science is made more meaningful and accessible. The program's pedagogy is based on the principles of cognitive psychology and immersive field-, place- and inquiry-based learning. Field programs have been found to provide memorable, transformative experiences for undergraduate students, and our experience with River Summer 2005 and 2006 suggests they are equally effective with faculty. Evaluation shows that River Summer has a significant impact on its participants. Participants develop new inter-institutional collaborations, and interdisciplinary pedagogical and research approaches that would otherwise never have happened. River Summer content and pedagogy are being used by participants to transform their teaching at their home institutions in disciplines as diverse as anthropology, art history, biology, economics, engineering, geochemistry, political science, and writing. Using local resources and landscapes develops an understanding of the environment in which one works and lives, providing greater accessibility and deeper meaning. Proximity to the areas being studied also allows them to be developed into class field trips. The enthusiasm and energy that the project evokes suggests that the model developed for this program could be successfully implemented in other settings to promote interdisciplinary learning about the earth and its environment.

Mush!

NASA Astrophysics Data System (ADS)

Ashwal, L. D.

2012-12-01

Evidence for emplacement as crystal-laden mushes is abundant in mafic magma systems (i.e. products of broadly basaltic magmatism), including anorthosite complexes, layered mafic intrusions and a variety of sills and dikes. Some of the best examples involve the way feldspar becomes concentrated into anorthositic rocks. Proterozoic anorthosite massifs (e.g. Nain, Rogaland, Adirondacks), whose bulk compositions are characteristically hyperfeldspathic, are best interpreted as resulting from emplacement of plagioclase-rich mushes that ascended to shallow crustal emplacement sites from deep (~Moho) staging chambers in which ~An50 crystals floated due to density relations at high pressure. Supporting evidence includes large (up to ~1 m) grain size, compositional homogeneity of plagioclase with variable Mg# (caused by trapped liquid effects), and protoclastic textures. Isotopic disequilibrium between cumulus plagioclase and post-cumulus pyroxene result from progressive contamination with continental components. This is dramatically demonstrated at Nain (Labrador), where the anorthositic crystal mushes (~1.3 Ga) were emplaced into early Archean (~3.8 Ga) country rocks. High-Al, high-pressure orthopyroxene megacrysts are commonly dragged upward in feldspathic mushes to shallow emplacement sites, where they exsolved plagioclase lamellae (Bybee & Ashwal, this meeting). Archean calcic anorthosites (e.g. Fiskenaesset, W Greenland) and related sills, dikes and flows that contain homogeneous megacrysts up to 10s of cm across of ~An80 also must have formed by mush emplacement, although probably from shallower staging chambers in oceanic rather than continental crust. Many layered mafic intrusions (e.g. Bushveld, Stillwater, Dufek, Duluth) contain thick horizons of anorthosite in which plagioclase compositions are uniform, in some cases throughout >1000 m of stratigraphy. This is best interpreted as representing repeated emplacement of plagioclase-rich mushes from one or more deeper crystallizing magma chambers. In the Bushveld Complex, where deep drill cores have allowed near-continuous measurements of mineral compositions and geophysical properties, the results reveal a subtle cyclicity, invisible in outcrops, over scales of 50 - 100 m, commonly associated with broad reversals in mineral compositional trends. Each of these can be interpreted as a blending zone involving a new addition of crystal-laden magma. Much of Bushveld stratigraphy, and that of other layered intrusions contains plagioclase:pyroxene demonstrably higher than cotectic proportions, supporting overall construction by plagioclase-rich magmas. Isotopic disequilibrium effects, similar to those described above, have been detected in Bushveld cumulates, lending further support to mush emplacement models. Large layered intrusions were probably constructed by repeated emplacement of dozens of individual magmatic entities with variable crystal:melt ratios (Marsh, 2006, Elements). Even the properties of very small (~30 km2) layered intrusions like that at Doros, Namibia (Owen-Smith & Ashwal, this meeting) show abundant evidence for multiple mush emplacement. In plutonic magma bodies arising from mafic magmatism, therefore, the involvement of crystal mushes appears to be the rule rather than the exception.

U-Pb geochronology of zircon and monazite from Mesoproterozoic granitic gneisses of the northern Blue Ridge, Virginia and Maryland, USA

USGS Publications Warehouse

Aleinikoff, J.N.; Burton, W.C.; Lyttle, P.T.; Nelson, A.E.; Southworth, C.S.

2000-01-01

Mesoproterozoic granitic gneisses comprise most of the basement of the northern Blue Ridge geologic province in Virginia and Maryland. Lithology, structure, and U-Pb geochronology have been used to subdivide the gneisses into three groups. The oldest rocks, Group 1, are layered granitic gneiss (1153 ?? 6 Ma), hornblende monzonite gneiss (1149 ?? 19 Ma), porphyroblastic granite gneiss (1144 ?? 2 Ma), coarse-grained metagranite (about 1140 Ma), and charnockite (>1145 Ma?). These gneisses contain three Proterozoic deformational fabrics. Because of complex U-Pb systematics due to extensive overgrowths on magmatic cores, zircons from hornblende monzonite gneiss were dated using the sensitive high-resolution ion microprobe (SHRIMP), whereas all other ages are based on conventional U-Pb geochronology. Group 2 rocks are leucocratic and biotic varieties of Marshall Metagranite, dated at 1112??3 Ma and 1111 ?? 2 Ma respectively. Group 3 rocks are subdivided into two age groups: (1) garnetiferous metagranite (1077 ?? 4 Ma) and quartz-plagioclase gneiss (1077 ?? 4 Ma); (2) white leucocratic metagranite (1060 ?? 2 Ma), pink leucocratic metagranite (1059 ?? 2), biotite granite gneiss (1055 ?? 4 Ma), and megacrystic metagranite (1055 ?? 2 Ma). Groups 2 and 3 gneisses contain only the two younger Proterozoic deformational fabrics. Ages of monazite, seprated from seven samples, indicate growth during both igneous and metamorphic (thermal) events. However, ages obtained from individual grains may be mixtures of different age components, as suggested by backscatter electron (BSE) imaging of complexly zoned grains. Analyses of unzoned monazite (imaged by BSE and thought to contain only one age component) from porphyroblastic granite gneiss yield ages of 1070, 1060, and 1050 Ma. The range of ages of monazite (not reset to a uniform date) indicates that the Grenville granulite event at about 1035 Ma did not exceed about 750??C. Lack of evidence for 1110 Ma growth of monazite in porphyroblastic granite gneiss suggests that the Short Hill fault might be a Grenvillian structure that was reactivated in the Paleozoic. The timing of Proterozoic deformations is constrained by crystallization ages of the gneissic rocks. D1 occurred between about 1145 and 1075 Ma (or possibly between about 1145 and 1128 Ma). D2 and D3 must be younger than about 1050 Ma. Ages of Mesoproterozoic granitic rocks of the northern Blue Ridge are similar to rocks in other Grenville terranes of the eastern USA, including the Adirondacks and Hudson Highlands. However, comparisons with conventional U-Pb ages of granulite-grade rocks from the central and southern Appalachians may be specious because these ages may actually be mixtures of ages of cores and overgrowths.

Watershed-scale changes in terrestrial nitrogen cycling during a period of decreased atmospheric nitrate and sulfur deposition

USGS Publications Warehouse

Sabo, Robert D.; Scanga, Sara E.; Lawrence, Gregory B.; Nelson, David M.; Eshleman, Keith N.; Zabala, Gabriel A.; Alinea, Alexandria A.; Schirmer, Charles D.

2016-01-01

Recent reports suggest that decreases in atmospheric nitrogen (N) deposition throughout Europe and North America may have resulted in declining nitrate export in surface waters in recent decades, yet it is unknown if and how terrestrial N cycling was affected. During a period of decreased atmospheric N deposition, we assessed changes in forest N cycling by evaluating trends in tree-ring δ15N values (between 1980 and 2010; n = 20 trees per watershed), stream nitrate yields (between 2000 and 2011), and retention of atmospherically-deposited N (between 2000 and 2011) in the North and South Tributaries (North and South, respectively) of Buck Creek in the Adirondack Mountains, USA. We hypothesized that tree-ring δ15N values would decline following decreases in atmospheric N deposition (after approximately 1995), and that trends in stream nitrate export and retention of atmospherically deposited N would mirror changes in tree-ring δ15N values. Three of the six sampled tree species and the majority of individual trees showed declining linear trends in δ15N for the period 1980–2010; only two individual trees showed increasing trends in δ15N values. From 1980 to 2010, trees in the watersheds of both tributaries displayed long-term declines in tree-ring δ15N values at the watershed scale (R = −0.35 and p = 0.001 in the North and R = −0.37 and p <0.001 in the South). The decreasing δ15N trend in the North was associated with declining stream nitrate concentrations (−0.009 mg N L−1 yr−1, p = 0.02), but no change in the retention of atmospherically deposited N was observed. In contrast, nitrate yields in the South did not exhibit a trend, and the watershed became less retentive of atmospherically deposited N (−7.3% yr−1, p < 0.001). Our δ15N results indicate a change in terrestrial N availability in both watersheds prior to decreases in atmospheric N deposition, suggesting that decreased atmospheric N deposition was not the sole driver of tree-ring δ15N values at these sites. Other factors, such as decreased sulfur deposition, disturbance, long-term successional trends, and/or increasing atmospheric CO2concentrations, may also influence trends in tree-ring δ15N values. Furthermore, declines in terrestrial N availability inferred from tree-ring δ15N values do not always correspond with decreased stream nitrate export or increased retention of atmospherically deposited N.

Solute sources in stream water during consecutive fall storms in a northern hardwood forest watershed: A combined hydrological, chemical and isotopic approach

USGS Publications Warehouse

Mitchell, M.J.; Piatek, K.B.; Christopher, S.; Mayer, B.; Kendall, C.; McHale, P.

2006-01-01

Understanding the effects of climate change including precipitation patterns has important implications for evaluating the biogeochemical responses of watersheds. We focused on four storms in late summer and early fall that occurred after an exceptionally dry period in 2002. We analyzed not only the influence of these storms on episodic chemistry and the role of different water sources in affecting surface water chemistry, but also the relative contributions of these storms to annual biogeochemical mass balances. The study site was a well studied 135-ha watershed in the Adirondack Park of New York State (USA). Our analyses integrated measurements on hydrology, solute chemistry and the isotopic composition of NO 3- (??15N and ??18O) and SO 42- (??34S and ??18O) to evaluate how these storms affected surface water chemistry. Precipitation amounts varied among the storms (Storm 1: Sept. 14-18, 18.5 mm; Storm 2: Sept. 21-24, 33 mm; Storm 3: Sept. 27-29, 42.9 mm; Storm 4: Oct. 16-21, 67.6 mm). Among the four storms, there was an increase in water yields from 2 to 14%. These water yields were much less than in studies of storms in previous years at this same watershed when antecedent moisture conditions were higher. In the current study, early storms resulted in relatively small changes in water chemistry. With progressive storms the changes in water chemistry became more marked with particularly major changes in Cb (sum of base cations), Si, NO 3- , and SO 42- , DOC and pH. Analyses of the relationships between Si, DOC, discharge and water table height clearly indicated that there was a decrease in ground water contributions (i.e., lower Si concentrations and higher DOC concentrations) as the watershed wetness increased with storm succession. The marked changes in chemistry were also reflected in changes in the isotopic composition of SO 42- and NO 3- . There was a strong inverse relationship between SO 42- concentrations and ??34S values suggesting the importance of S biogeochemical redox processes in contributing to SO 42- export. The isotopic composition of NO 3- in stream water indicated that this N had been microbially processed. Linkages between SO 42- and DOC concentrations suggest that wetlands were major sources of these solutes to drainage waters while the chemical and isotopic response of NO 3- suggested that upland sources were more important. Although these late summer and fall storms did not play a major role in the overall annual mass balances of solutes for this watershed, these events had distinctive chemistry including depressed pH and therefore have important consequences to watershed processes such as episodic acidification, and the linkage of these processes to climate change. ?? Springer 2006.

Reconnaissance for radioactive materials in northeastern United States during 1952

USGS Publications Warehouse

McKeown, Francis A.; Klemic, Harry

1953-01-01

Reconnaissance for radioactive materials was made in parts of Maine, New York, New Jersey, and Pennsylvania. The primary objective was to examine the iron ore deposits and associated rocks in the Adirondack Mountains of New York and the Highlands of New Jersey. In addition, several deposits known or reported to contain radioactive minerals were examined to delimit their extent. Most of the deposits examined are not significant as possible sources of radioactive elements and the data pertaining to them are summarized in table form. Deposits that do warrant more description than can be given in table form are: Benson Mines, St. Lawrence County, N. Y.; Rutgers mine, Clinton County, N. Y.; Mineville Mines, Essex County, N. Y.l Canfield phosphate mine, Morris County, N. J.; Mullgan quarry, Hunterdon County, N. J.; and the Chestnut Hill-Marble Mountain area, Pennsylvania and New Jersey. The Old Bed in the Mineville district is the only deposit that may be economically significant. Apatite from Old Bed ore contains as much as 4.9 percent total rare earth. 0.04 percent thorium, and 0.018 percent uranium. Magnetite ore at the Rutgers mine contains radioactive zircon and apatite. Radioactivity measurements of outcrops and dump material show that the ore contains from 0.005 to 0.010 percent equivalent uranium. One sample of lean magnetite ore contains 0.006 percent equivalent uranium. Garnet-rich zones in the Benson Mines magnetite deposit contain as much as 0.017 equivalent uranium. Most of the rock and ore, however, contains about 0.005 percent equivalent uranium. Available data indicate that the garnet-rich zones are enriched in radioactive allanite. A shear zone in the Kittatinny limestone of Cambrian age at the Mulligan quarry contains uraniferous material. Radioactivity anomalies elsewhere in the quarry and in adjacent fields indicate that there may be other uraniferous shear zones. Assays of samples and measurements of outcrop radioactivity indicate that the uranium content of these zones is low; samples contain from 0.008 to 0.068 percent equivalent uranium. The anomalies, however, may indicate greater concentrations of uranium below surficial leached zones. The Chestnut Hill-Marble Mountain area contains radioactivity anomalies for about 2 miles along the strike of the contact of pre-Cambrian Pickering gneiss and Franklin limestone formations. In places this contact is injected with pegmatite, which probably was the source of the radioelements. The most favorable area for further study is at Marble Mountain, where a nearly continuous anomaly extends for about 1500 feet. Samples from part of this area contain as much as 0.044 percent equivalent uranium and 0.005 percent uranium. Radioactive hematite and florencite, in which thorium may have substituted for cerium, are the only radioactive minerals observed in the Marble Mountain area.

Atmospheric nitrogen in the Mississippi River Basin - Amissions, deposition and transport

USGS Publications Warehouse

Lawrence, G.B.; Goolsby, D.A.; Battaglin, W.A.; Stensland, G.J.

2000-01-01

Atmospheric deposition of nitrogen has been cited as a major factor in the nitrogen saturation of forests in the north-eastern United States and as a contributor to the eutrophication of coastal waters, including the Gulf of Mexico near the mouth of the Mississippi River. Sources of nitrogen emissions and the resulting spatial patterns of nitrogen deposition within the Mississippi River Basin, however, have not been fully documented. An assessment of atmospheric nitrogen in the Mississippi River Basin was therefore conducted in 1998-1999 to: (1) evaluate the forms in which nitrogen is deposited from the atmosphere; (2) quantify the spatial distribution of atmospheric nitrogen deposition throughout the basin; and (3) relate locations of emission sources to spatial deposition patterns to evaluate atmospheric transport. Deposition data collected through the NADP/NTN (National Atmospheric Deposition Program/National Trends Network) and CASTNet (Clean Air Status and Trends Network) were used for this analysis. NO(x) Tier 1 emission data by county was obtained for 1992 from the US Environmental Protection Agency (Emissions Trends Viewer CD, 1985-1995, version 1.0, September 1996) and NH3 emissions data was derived from the 1992 Census of Agriculture (US Department of Commerce. Census of Agriculture, US Summary and County Level Data, US Department of Commerce, Bureau of the Census. Geographic Area series, 1995:1b) or the National Agricultural Statistics Service (US Department of Agriculture. National Agricultural Statistics Service Historical Data. Accessed 7/98 at URL, 1998. http://www.usda.gov/nass/pubs/hisdata.htm). The highest rates of wet deposition of NO3- were in the north-eastern part of the basin, downwind of electric utility plants and urban areas, whereas the highest rates of wet deposition of NH4+ were in Iowa, near the center of intensive agricultural activities in the Midwest. The lowest rates of atmospheric nitrogen deposition were on the western (windward) side of the basin, which suggests that most of the nitrogen deposited within the basin is derived from internal sources. Atmospheric transport eastward across the basin boundary is greater for NO3- than NH4+, but a significant amount of NH4+ is likely to be transported out of the basin through the formation of (NH4)2SO4 and NH4NO3 particles - a process that greatly increases the atmospheric residence time of NH4+. This process is also a likely factor in the atmospheric transport of nitrogen from the Midwest to upland forest regions in the North-East, such as the western Adirondack region of New York, where NH4+ constitutes 38% of the total wet deposition of N. Copyright (C) 2000 Elsevier Science B.V.

Interactive effects of climate change with nutrients, mercury, and freshwater acidification on key taxa in the North Atlantic Landscape Conservation Cooperative region.

PubMed

Pinkney, Alfred E; Driscoll, Charles T; Evers, David C; Hooper, Michael J; Horan, Jeffrey; Jones, Jess W; Lazarus, Rebecca S; Marshall, Harold G; Milliken, Andrew; Rattner, Barnett A; Schmerfeld, John; Sparling, Donald W

2015-07-01

The North Atlantic Landscape Conservation Cooperative LCC (NA LCC) is a public-private partnership that provides information to support conservation decisions that may be affected by global climate change (GCC) and other threats. The NA LCC region extends from southeast Virginia to the Canadian Maritime Provinces. Within this region, the US National Climate Assessment documented increases in air temperature, total precipitation, frequency of heavy precipitation events, and rising sea level, and predicted more drastic changes. Here, we synthesize literature on the effects of GCC interacting with selected contaminant, nutrient, and environmental processes to adversely affect natural resources within this region. Using a case study approach, we focused on 3 stressors with sufficient NA LCC region-specific information for an informed discussion. We describe GCC interactions with a contaminant (Hg) and 2 complex environmental phenomena-freshwater acidification and eutrophication. We also prepared taxa case studies on GCC- and GCC-contaminant/nutrient/process effects on amphibians and freshwater mussels. Several avian species of high conservation concern have blood Hg concentrations that have been associated with reduced nesting success. Freshwater acidification has adversely affected terrestrial and aquatic ecosystems in the Adirondacks and other areas of the region that are slowly recovering due to decreased emissions of N and sulfur oxides. Eutrophication in many estuaries within the region is projected to increase from greater storm runoff and less denitrification in riparian wetlands. Estuarine hypoxia may be exacerbated by increased stratification. Elevated water temperature favors algal species that produce harmful algal blooms (HABs). In several of the region's estuaries, HABs have been associated with bird die-offs. In the NA LCC region, amphibian populations appear to be declining. Some species may be adversely affected by GCC through higher temperatures and more frequent droughts. GCC may affect freshwater mussel populations via altered stream temperatures and increased sediment loading during heavy storms. Freshwater mussels are sensitive to un-ionized ammonia that more toxic at higher temperatures. We recommend studying the interactive effects of GCC on generation and bioavailability of methylmercury and how GCC-driven shifts in bird species distributions will affect avian exposure to methylmercury. Research is needed on how decreases in acid deposition concurrent with GCC will alter the structure and function of sensitive watersheds and surface waters. Studies are needed to determine how GCC will affect HABs and avian disease, and how more severe and extensive hypoxia will affect fish and shellfish populations. Regarding amphibians, we suggest research on 1) thermal tolerance and moisture requirements of species of concern, 2) effects of multiple stressors (temperature, desiccation, contaminants, nutrients), and 3) approaches to mitigate impacts of increased temperature and seasonal drought. We recommend studies to assess which mussel species and populations are vulnerable and which are resilient to rising stream temperatures, hydrological shifts, and ionic pollutants, all of which are influenced by GCC. © 2015 SETAC.

Igneous and Sedimentary Compositions from Four Landing Sites on Mars from the Alpha Particle X-Ray Spectrometer (APXS)

NASA Technical Reports Server (NTRS)

Gellert, R.; Arvidson, R. E.; Clark, B. C.; Ming, D. W.; Mittlefehldt, D. W.; Morris, R. W.; Squyres, S. W.; VanBommel, S.; Yen, A. S.

2016-01-01

The APXS - supported and promoted strongly by Heinrich Waenke - on all four Mars Rovers has returned compositional data from about 1000 rocks and soil targets along the combined traverses of over 60 kilometers. Providing precise and accurate bulk chemistry with typically 16 quantified elements, the APXS is a powerful and versatile tool that when combined with the ability to traverse to key rocks and soils has provided critical information needed to understand the geologic evolution of Mars. APXS data allow comparisons among landing sites, provide ground truth for orbiters and connections back to SNC meteorites. The soils and dust are basaltic in character and represent the average Mars composition similar to Adirondack basalts from Gusev crater but with unambiguous elevated and correlated S, Cl and Zn contents. At all four landing sites the APXS found several rocks with a felsic composition. The similarity is best assessed in a logarithmic ratio plot of rock normalized to the average soil composition (Fig.1). High alkaline, Al, and low Mg, Fe, low S, Cl and Ni, Zn as well as an Fe/Mn ratio of approximately 50 indicate a likely unaltered and igneous origin. Sediments, e.g. the Burns formation, with approximately 25 wt% SO3 at Meridiani Planum have been documented over 10s of kilometers (Fig. 2). This formation is compositionally homogeneous, but showing the removal of MgSO4 and a threefold increase in Cl downhill in 2 craters. The degraded rim of the Noachian crater Endeavour resembles average Mars crust, with local Ca, Mg and Fe sulfate alteration and elevated Mn, some felsic rocks, and high Al, Si and low Fe rocks, possibly indicating clays. Unusual soils at Gusev crater in the area surrounding Home Plate include some very rich in ferric sulfate salts (up to 35 wt% SO3) and some with 90% wt% SiO2, possibly indicating fumerolic activities. Rocks in the Columbia Hills show significant signs of alteration including elevated S, Cl and Br in the abraded interior. At Gale Crater, mudstones with approximately 20% clay, less than 1% SO3 and overall average Mars composition indicate a former habitable environment with low acidity. A remarkable diversity of compositions was found during Curiosity's traverses, which likely stems from material influx from the northern Gale rim. At Pahrump, the base of Mount Sharp, a homogeneous mudstone with lower Mg and Ca was encountered. The composition of this Murray unit can be traced over several kilometers with smooth trends of higher Fe/Mn and lower soluble trace elements Ni and Zn at higher elevation. The likely aeolian Stimson formation with average Mars crustal composition intersects in several places in sharp contact with the Murray formation. Both units show local alteration halos with highly elevated SiO2 of up to 75%, usually correlated with increase in Ti and often P.

Interactive effects of climate change with nutrients, mercury, and freshwater acidification on key taxa in the North Atlantic Landscape Conservation Cooperative region

USGS Publications Warehouse

Pinkney, Alfred E.; Driscoll, Charles T.; Evers, David C.; Hooper, Michael J.; Horan, Jeffrey; Jones, Jess W.; Lazarus, Rebecca S.; Marshall, Harold G.; Milliken, Andrew; Rattner, Barnett A.; Schmerfeld, John J.; Sparling, Donald W.

2015-01-01

The North Atlantic Landscape Conservation Cooperative LCC (NA LCC) is a public–private partnership that provides information to support conservation decisions that may be affected by global climate change (GCC) and other threats. The NA LCC region extends from southeast Virginia to the Canadian Maritime Provinces. Within this region, the US National Climate Assessment documented increases in air temperature, total precipitation, frequency of heavy precipitation events, and rising sea level, and predicted more drastic changes. Here, we synthesize literature on the effects of GCC interacting with selected contaminant, nutrient, and environmental processes to adversely affect natural resources within this region. Using a case study approach, we focused on 3 stressors with sufficient NA LCC region-specific information for an informed discussion. We describe GCC interactions with a contaminant (Hg) and 2 complex environmental phenomena—freshwater acidification and eutrophication. We also prepared taxa case studies on GCC- and GCC-contaminant/nutrient/process effects on amphibians and freshwater mussels. Several avian species of high conservation concern have blood Hg concentrations that have been associated with reduced nesting success. Freshwater acidification has adversely affected terrestrial and aquatic ecosystems in the Adirondacks and other areas of the region that are slowly recovering due to decreased emissions of N and sulfur oxides. Eutrophication in many estuaries within the region is projected to increase from greater storm runoff and less denitrification in riparian wetlands. Estuarine hypoxia may be exacerbated by increased stratification. Elevated water temperature favors algal species that produce harmful algal blooms (HABs). In several of the region's estuaries, HABs have been associated with bird die-offs. In the NA LCC region, amphibian populations appear to be declining. Some species may be adversely affected by GCC through higher temperatures and more frequent droughts. GCC may affect freshwater mussel populations via altered stream temperatures and increased sediment loading during heavy storms. Freshwater mussels are sensitive to un-ionized ammonia that more toxic at higher temperatures. We recommend studying the interactive effects of GCC on generation and bioavailability of methylmercury and how GCC-driven shifts in bird species distributions will affect avian exposure to methylmercury. Research is needed on how decreases in acid deposition concurrent with GCC will alter the structure and function of sensitive watersheds and surface waters. Studies are needed to determine how GCC will affect HABs and avian disease, and how more severe and extensive hypoxia will affect fish and shellfish populations. Regarding amphibians, we suggest research on 1) thermal tolerance and moisture requirements of species of concern, 2) effects of multiple stressors (temperature, desiccation, contaminants, nutrients), and 3) approaches to mitigate impacts of increased temperature and seasonal drought. We recommend studies to assess which mussel species and populations are vulnerable and which are resilient to rising stream temperatures, hydrological shifts, and ionic pollutants, all of which are influenced by GCC.

Geochemistry of the furnace magnetite bed, Franklin, New Jersey, and the relationship between stratiform iron oxide ores and stratiform zinc oxide-silicate ores in the New Jersey highlands

USGS Publications Warehouse

Johnson, C.A.; Skinner, B.J.

2003-01-01

The New Jersey Highlands terrace, which is an exposure of the Middle Proterozoic Grenville orogenic belt located in northeastern United States, contains stratiform zinc oxide-silicate deposits at Franklin and Sterling Hill and numerous massive magnetite deposits. The origins of the zinc and magnetite deposits have rarely been considered together, but a genetic link is suggested by the occurrence of the Furnace magnetite bed and small magnetite lenses immediately beneath the Franklin zinc deposit. The Furnace bed was metamorphosed and deformed along with its enclosing rocks during the Grenvillian orogeny, obscuring the original mineralogy and obliterating the original rock fabrics. The present mineralogy is manganiferous magnetite plus calcite. Trace hydrous silicates, some coexisting with fluorite, have fluorine contents that are among the highest ever observed in natural assemblages. Furnace bed calcite has ??13C values of -5 ?? 1 per mil relative to Peedee belemnite (PDB) and ??18O values of 11 to 20 per mil relative to Vienna-standard mean ocean water (VSMOW). The isotopic compositions do not vary as expected for an original siderite layer that decarbonated during metamorphism, but they are consistent with nearly isochemical metamorphism of an iron oxide + calcite protolith that is chemically and minerlogically similar to iron-rich sediments found near the Red Sea brine pools and isotopically similar to Superior-type banded iron formations. Other magniferous magnite + calcite bodies occur at approximately the same stratigraphic position as far 50 km from the zinc deposits. A model is presented in which the iron and zinc deposits formed along the western edge of a Middle Proterozoic marine basin. Zinc was transported by sulfate-stable brines and was precipitated under sulfate-stable conditions as zincian carbonates and Fe-Mn-Zn oxides and silicates. Whether the zincian assemblages settled from the water column or formed by replacement reactions in shallowly buried sediments is uncertain. The iron deposits formed at interfaces between anoxic and oxygenated waters. The Furnace magnetite bed resulted from seawater oxidation of hydrothermally transported iron near a brine conduit. Iron deposits also formed regionally on the basin floor at the interface betveen anoxic deep waters and oxygenated shallower waters. These deposits include not only manganiferous magnetite + calcite bodies similar to the Furnace magnetite bed but also silicate-facies deposits that formed by iron oxide accumulation where detrital sediment was abundant. A basin margin model can be extended to Grenvillian stratiform deposits in the northwest Adirondacks of New York and the Mont Laurier basin of Quebec. In these areas iron deposits (pyrite or magnetite) are found basinward of marble-hosted sphalerite deposits, such as those in the Balmat-Edwards district. Whether the iron and zinc precipitated as sulfide assemblages or carbonate-oxide-silicate assemblages depended on whether sufficient organic matter or other reductants were available in local sediments or bottom waters to stabilize H2S.

Magnesium isotope fractionation in co-existing clino-pyroxene and garnet: implications for geothermometry and mantle source characterization

NASA Astrophysics Data System (ADS)

Chakrabarti, R.; Jacobsen, S. B.; Basu, A. R.

2011-12-01

It is now well established that the Mg isotopic composition of the bulk silicate Earth, as represented by olivines, peridotites and basalts is identical to bulk meteorites and the Moon. However, small differences have been documented between co-existing olivines and clino-pyroxenes in mantle xenoliths as well as co-existing hornblendes and biotites in granitoids; spinels show some of the heaviest δ26Mg (deviation of the 26Mg/24Mg ratio from the Dead Sea Metal standard). A recent study has documented a large Mg isotopic fractionation between co-existing omphacite and garnet (Δ26MgOMP-GT = δ26MgOMP - δ26MgGT ~1.14) from eclogites in the Dabie orogen of China. This large equilibrium Mg isotope fractionation is explained by the difference in coordination number of Mg in omphacite (six) and garnet (eight). We report stable Mg isotopic compositions of co-existing garnet and clino-pyroxenes from different mantle-derived rocks. Garnet-omphacite pairs analyzed are from an eclogite xenolith from the Roberts Victor kimberlite pipe, the ultra-high pressure Tso Morari eclogite from the Ladakh Himalayas and the Healdsburg eclogite from the Franciscan Subduction Complex, which have a wide range in estimated temperatures of equilibration. Although, the latter two eclogites were exhumed in orogenic belts, our selective picking of the mineral cores for analysis avoided retrograded compositions. We have also analyzed Cr-diopside and pyrope-rich garnet pairs from several southern African kimberlite pipes. These include granular garnet peridotite xenoliths (P = 30-40 kbar, T =950-10500C) as well as the deeper sheared xenoliths (P = 50-60 kbar, T = 13500C). Rapid quenching of the kimberlite-hosted xenoliths ensures minimal low temperature pervasive alteration of these samples. Also analyzed are samples from the Gore Mt. amphibolite and a wollastonite-diopside-garnet skarn from the Adirondacks with equilibration temperatures of 700-7260C. Minerals were separated by hand-picking under a binocular microscope. Mg was quantitatively separated from other matrix elements using cation exchange chromatography. All three Mg isotopes were simultaneously measured using the IsoProbe-P MC-ICPMS at Harvard University by sample-standard bracketing. Our results from 11 garnet-clinopyroxene mineral pairs with widely varying temperatures of equilibration indicate that δ26Mg in garnet (-0.6 to -2.3) is much lower than that in co-existing clino-pyroxenes (-0.1 to -0.6 and -1.3 in the wollastonite skarn). This result is consistent with theoretical predictions as well as recent results from the Dabie orogen. Δ26Mg between clino-pyroxene and garnet ranges from 0.7 to 2.3. Our results suggest a temperature dependence of Δ26Mg between clino-pyroxene and garnet in mantle-derived rocks which can potentially be used as a geothermometer. Large Mg isotopic fractionation between co-existing garnet and clino-pyroxenes has implications for source characterization (garnet peridotite versus eclogite) of mantle-derived melts.

SemantGeo: Powering Ecological and Environment Data Discovery and Search with Standards-Based Geospatial Reasoning

NASA Astrophysics Data System (ADS)

Seyed, P.; Ashby, B.; Khan, I.; Patton, E. W.; McGuinness, D. L.

2013-12-01

Recent efforts to create and leverage standards for geospatial data specification and inference include the GeoSPARQL standard, Geospatial OWL ontologies (e.g., GAZ, Geonames), and RDF triple stores that support GeoSPARQL (e.g., AllegroGraph, Parliament) that use RDF instance data for geospatial features of interest. However, there remains a gap on how best to fuse software engineering best practices and GeoSPARQL within semantic web applications to enable flexible search driven by geospatial reasoning. In this abstract we introduce the SemantGeo module for the SemantEco framework that helps fill this gap, enabling scientists find data using geospatial semantics and reasoning. SemantGeo provides multiple types of geospatial reasoning for SemantEco modules. The server side implementation uses the Parliament SPARQL Endpoint accessed via a Tomcat servlet. SemantGeo uses the Google Maps API for user-specified polygon construction and JsTree for providing containment and categorical hierarchies for search. SemantGeo uses GeoSPARQL for spatial reasoning alone and in concert with RDFS/OWL reasoning capabilities to determine, e.g., what geofeatures are within, partially overlap with, or within a certain distance from, a given polygon. We also leverage qualitative relationships defined by the Gazetteer ontology that are composites of spatial relationships as well as administrative designations or geophysical phenomena. We provide multiple mechanisms for exploring data, such as polygon (map-based) and named-feature (hierarchy-based) selection, that enable flexible search constraints using boolean combination of selections. JsTree-based hierarchical search facets present named features and include a 'part of' hierarchy (e.g., measurement-site-01, Lake George, Adirondack Region, NY State) and type hierarchies (e.g., nodes in the hierarchy for WaterBody, Park, MeasurementSite), depending on the ';axis of choice' option selected. Using GeoSPARQL and aforementioned ontology, these hierarchies are constrained based on polygon selection, where the corresponding polygons of the contained features are visually rendered to assist exploration. Once measurement sites are plotted based on initial search, subsequent searches using JsTree selections can extend the previous based on nearby waterbodies in some semantic relationship of interest. For example, ';tributary of' captures water bodies that flow into the current one, and extending the original search to include tributaries of the observed water body is useful to environmental scientists for isolating the source of characteristic levels, including pollutants. Ultimately any SemantEco module can leverage SemantGeo's underlying APIs, leveraged in a deployment of SemantEco that combines EPA and USGS water quality data, and one customized for searching data available from the Darrin Freshwater Institute. Future work will address generating RDF geometry data from shape files, aligning RDF data sources to better leverage qualitative and spatial relationships, and validating newly generated RDF data adhering to the GeoSPARQL standard.

Effects of a beaver pond on runoff processes: comparison of two headwater catchments

USGS Publications Warehouse

Burns, Douglas A.; McDonnell, Jeffery J.

1998-01-01

Natural variations in concentrations of 18O, D, and H4SiO4 in two tributary catchments of Woods Lake in the west-central Adirondack Mountains of New York were measured during 1989–1991 to examine runoff processes and their implications for the neutralization of acidic precipitation by calcium carbonate treatment. The two catchments are similar except that one contained a 1.3 ha beaver pond. Evaporation from the beaver pond caused a seasonal decrease in the slope of the meteoric water line in stream water from the catchment with a beaver pond (WO2). No corresponding change in slope of the meteoric water line was evident in stream water from the other catchment (WO4), nor in ground water nor soil water from either catchment, indicating that evaporative fractionation was not significant. Application of a best-fit sine curve to δ18O data indicated that base flow in both catchments had a residence time of about 100 days. Ground water from a well finished in thick till had the longest residence time (160 days); soil water from the O-horizon and B-horizon had residence times of 63 and 80 days, respectively. Water previously stored within each catchment (pre-event water) was the predominant component of streamflow during spring snowmelt and during spring and autumn rainfall events, but the proportion of streamflow that consisted of pre-event water differed significantly in the two catchments. The proportion of event water (rain and snowmelt) in WO2 was smaller than at WO4 early in the spring snowmelt of March 13–17, 1990, but the proportions of source water components for the two catchments were almost indistinguishable by the peak flow on the third day of the melt. The event water was further separated into surface-water and subsurface-water components by utilizing measured changes in H4SiO4 concentrations in stream water during the snowmelt. Results indicated that subsurface flow was the dominant pathway by which event water reached the stream except during the peak flow of a rain-on-snow event on the last day of the melt. Streamflow from a spring rain storm with dry antecendent conditions two months later (May 16–18, 1990), was less than 5% event water at peak flow in WO2 and 26% in WO4. This change from the runoff pattern in March is attributed to retention of event water in the beaver pond favored by relatively low pre-event storage and isothermal (nonstratified) conditions in the pond that allowed mixing. Streamflow during several autumn storms was about 15–25% event water at peak flow in WO4; the highest values for event water were associated with wet antecedent moisture conditions. These results indicate that a beaver pond can significantly affect the downstream delivery of event water through evaporation and mixing, but provides minimal retention during large runoff events such as snowmelt. Beaver ponds are expected to provide greater opportunity for neutralization of acidic waters during most of the year in catchments treated with calcium carbonate, but little neutralization effect during snowmelt.

Chloride cycling in two forested lake watersheds in the west-central Adirondack Mountains, New York, U.S.A.

USGS Publications Warehouse

Peters, N.E.

1991-01-01

The chemistry of precipitation, throughfall, soil water, ground water, and surface water was evaluated in two forested lake-watersheds over a 4-yr period to assess factors controlling C1- cycling. Results indicate that C1- cycling in these watersheds is more complex than the generally held view of the rapid transport of atmospherically derived C1- through the ecosystem. The annual throughfall Cl- flux for individual species in the northern hardwood forest was 2 to 5 times that of precipitation (56 eq ha-1), whereas the Na+ throughfall flux, in general, was similar to the precipitation flux. Concentrations of soil-water Cl- sampled from ceramic tension lysimeters at 20 cm below land surface generally exceeded the Na+ concentrations and averaged 31 ??eq L-1, the highest of any waters sampled in the watersheds, except throughfall under red spruce which averaged 34 ??eq L-1. Chloride was concentrated prior to storms and mobilized rapidly during storms as suggested by increases in streamwater Cl- concentrations with increasing flow. Major sources of Cl- in both watersheds are the forest floor and hornblende weathering in the soils and till. In the Panther Lake watershed, which contains mainly thick deposits of till( > 3 m), hornblende weathering results in a net Cl- flux 3 times greater than that in the Woods Lake watershed, which contains mainly thin deposits of till. The estimated accumulation rate of Cl- in the biomass of the two watersheds was comparable to the precipitation Cl- flux.The chemistry of precipitation, throughfall, soil water, ground water, and surface water was evaluated in two forested lake-watersheds over a 4-yr period to assess factors controlling Cl- cycling. Results indicate that Cl- cycling in these watersheds is more complex than the generally held view of the rapid transport of atmospherically derived Cl- through the excosystem. The annual throughfall Cl- flux for individual species in the northern hardwood forest was 2 to 5 times that of precipitation (56 eq ha-1), whereas the Na+ throughfall flux, in general, was similar to the precipitation flux. Concentrations of soil-water Cl- sampled from ceramic tension lysimeters at 20 cm below land surface generally exceeded the Na+ concentrations and averaged 31 ??eq L-1, the highest of any waters sampled in the watersheds, except throughfall under red spruce which averaged 34 ??eq L-1. Chloride was concentrated prior to storms and mobilized rapidly during storms as suggested by increases in streamwater Cl- concentrations with increasing flow. Major sources of Cl- in both watersheds are the forest floor and hornblende weathering in the soils and till. In the Panther Lake watershed, which contains mainly thick deposits of till (> 3 m), hornblende weathering results in a net Cl- flux 3 times greater than that in the Woods Lake watershed, which contains mainly thin deposits of till. The estimated accumulation rate of Cl- in the biomass of the two watersheds was comparable to the precipitation Cl- flux.

Spatial Connectivity and Temporal Response of Variable Source Areas (VSAs): Implications for Catchment Scale Water and Solute Mixing

NASA Astrophysics Data System (ADS)

Inamdar, S.; Mitchell, M.; McDonnell, J.; McGlynn, B.; Shanley, J.

2001-05-01

The significance of variable source areas (VSAs) in storm runoff generation and as loci for mixing of event and pre-event waters has long been recognized. Recent research suggests that VSAs may also play an important role in regulating the export of C and N solutes from catchments. We hypothesize that the spatial distribution of VSAs in the catchment and their connectedness with the stream network is a first order control on the temporal dynamics and expression of water and solutes from the catchment. We examined two contrasting scenarios of VSA distribution: (1) VSAs located lower in the catchment and well connected to the stream network, versus, (2) discrete VSAs located in the upper portions of the catchment and disconnected from the stream network. We evaluated the potential impact of these scenarios on: (a) the timing and peak of event water contributions, and (b) the timing and peak of solute signatures. We hypothesized that if VSAs are well connected to the stream network (Scenario 1), then event water contributions would be distinct and would predominate early on during the rising limb of the hydrograph of stream discharge. In contrast, if VSAs are isolated and disconnected (Scenario 2), then event water contributions would be damped and delayed and possibly continue to be observed through hydrograph recession. We believe solutes such as dissolved organic carbon (DOC), which are primarily flushed from near surface soil horizons, will follow an event water trajectory. We tested these hypotheses for a 135 ha forested headwater catchment in the Adirondack Mountains of New York. Detailed storm runoff and solute data for the catchment are available since 1994. A two-component separation model using base cations (Na, Mg, Ca, and K) was used to partition stormflow discharge into pre-event and event components. Event water contributions were small on the rising limb of the hydrograph, reached their maximum just after the discharge peak, and continued through the recession limb, hours after cessation of rainfall. DOC concentrations followed a temporal pattern very similar to the event water contributions, with a peak at or just after peak discharge. In contrast, the timing of the nitrate peak appeared to vary seasonally, indicating availability of nitrate in the soil profile as a controlling mechanism. Nitrate peaks appeared to match DOC and event water peaks for spring events, but occurred much earlier on the rising limb of the discharge hydrograph during fall events. Results from this study appear to confirm our hypothesis for scenario 2, where the disconnected nature of VSAs is displayed by the delayed expression of event water and DOC. These results also confirm our hypothesis that the spatial distribution of VSAs will have a greater impact on the temporal expression of solutes that are available in near surface soil horizons, as opposed to solutes whose availability in the near surface soil varies with seasons. These hypotheses are also being evaluated for a forested subcatchment of the Sleepers River watershed in Vermont.

Ti-in-zircon thermometry: applications and limitations

NASA Astrophysics Data System (ADS)

Fu, Bin; Page, F. Zeb; Cavosie, Aaron J.; Fournelle, John; Kita, Noriko T.; Lackey, Jade Star; Wilde, Simon A.; Valley, John W.

2008-08-01

The titanium concentrations of 484 zircons with U-Pb ages of ˜1 Ma to 4.4 Ga were measured by ion microprobe. Samples come from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons (32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413-433) without making corrections for reduced oxide activities (e.g., TiO2 or SiO2), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (˜15% melt residue for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually, the effects of reduced a_{TiO2} or a_{SiO2}, variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous melts with significantly lower crystallization temperature for the last 10-15% melt residue than that of the main rock. While some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once. However, there is no systematic change in Ti content from core to rim, or correlation with zoning, age, U content, Th/U ratio, or concordance in U-Pb age. Thus, it is likely that other variables, in addition to temperature and a_{TiO2}, are important in controlling the Ti content of zircon. The Ti contents of igneous zircons from different rock types worldwide overlap significantly. However, on a more restricted regional scale, apparent Ti-in-zircon temperatures correlate with whole-rock SiO2 and HfO2 for plutonic rocks of the Sierra Nevada batholith, averaging 750°C at 50 wt.% SiO2 and 600°C at 75 wt.%. Among felsic plutons in the Sierra, peraluminous granites average 610 ± 88°C, while metaluminous rocks average 694 ± 94°C. Detrital zircons from the Jack Hills, Western Australia with ages from 4.4 to 4.0 Ga have apparent temperatures of 717 ± 108°C, which are intermediate between values for felsic rocks and those for mafic rocks. Although some mafic zircons have higher Ti content, values for Early Archean detrital zircons from a proposed granitic provenance are similar to zircons from many mafic rocks, including anorthosites from the Adirondack Mts (709 ± 76°C). Furthermore, the Jack Hills zircon apparent Ti-temperatures are significantly higher than measured values for peraluminous granites (610 ± 88°C). Thus the Ti concentration in detrital zircons and apparent Ti-in-zircon temperatures are not sufficient to independently identify parent melt composition.

A new garnet-orthopyroxene thermometer developed: method, results and applications

NASA Astrophysics Data System (ADS)

Olivotos, Spyros-Christos; Kostopoulos, Dimitrios

2014-05-01

The Fe-Mg exchange reaction between garnet and orthopyroxene is a robust geothermometer that has extensively been used to retrieve metamorphic temperatures from granulitic and peridotitic/pyroxenitic lithologies with important implications on the thermal state of the continental lithosphere. More than 800 experimental mineral pairs from both simple and complex systems were gleaned from the literature covering the P-T range 0.5-15 GPa / 800-1800°C. Grt was treated as a senary (Py, Alm, Grs, Sps, Kno and Uv), whereas Opx as a septenary (En, Fs, Di, Hd, FeTs, MgTs and MgCrTs) solid solution. For Opx, Al in the M1 site was calculated following Carswell (1991) and Fe/Mg equipartitioning between sites was assumed. A mixing on sites model was employed to calculate mole fractions of components for both minerals. With regard to the excess free energy of solution and activity coefficients the formalism of Mukhopadhyay et al. (1993) was adopted treating both minerals as symmetric regular solutions. Calibration was achieved in multiple steps; in each step ΔS was allowed to vary until the standard deviation of the differences between experimental and calculated temperature for all experiments was minimised. The experiment with the largest absolute relative deviation in temperature was then eliminated and the process was repeated. The new thermometer reproduces the experimental data to within 50°C and is independent of P-T-X variations within the bounds of the calibrant data set. Application of our new calibration to metamorphosed crustal and mantle rocks that occur both as massifs and xenoliths in volcanics suggested the following results. Granulite terranes have recorded differences in temperature between peak and re-equilibration conditions in the range 100-340°C, primarily depending on the mechanism and rate of exhumation. Several provinces retain memory of discrete cooling pulses (e.g. Palni Hills, South Harris, Adirondacks, E. Antarctic Belt, Aldan Shield) whereas others are dominated by a single thermal event (Lisof Massif, SW Greenland, Eifel). UHT granulites appear to be more common than previously thought. There are a considerable number of localities in Europe that have recorded temperatures in excess of 950°C (South Harris, Schwarzwald, Pannonian Basin, Sudetes, Rogaland, Massif Central, Iberian Hercynian Belt), with the first four listed peaking over 1000°C. In settings such as South Harris, the model of Schmalholz & Podladchikov (2013) for heat generation within a crustal-scale shear zone is most appealing. Mafic/ultramafic xenoliths from Deccan conform to geotherms with surface heat flow between 60 and 90 mW.m-2 signifying a reduction in lithospheric thickness of the order of 43 km. Similar xenoliths from the Tariat Depression testify to a 20 km thinning beneath Mongolia. Mantle xenoliths from Canadian and Russian kimberlites demonstrate the great diamond potential of the Lac des Gras, Jericho, Udachnaya and Mir pipes but the limited potential of the Somerset Isl. and Obnazhennaya pipes. UHP mantle peridotites from the Dabie-SuLu orogen are characterised by the coldest geotherm identified so far (33mW.m-2) implying a minimum removal of 110 km from the lithospheric keel underneath E. China. References: Carswell, D. A., 1991. Min. Mag. 55, 19-31; Mukhopadhyay, B., et al., 1993. GCA 57, 277-283; Schmalholz, S. M., & Podladchikov, Y. Y., 2013. GRL 40, 1984-1988.

Spirit Discovers New Class of Igneous Rocks

NASA Technical Reports Server (NTRS)

2006-01-01

During the past two-and-a-half years of traversing the central part of Gusev Crater, NASA's Mars Exploration Rover Spirit has analyzed the brushed and ground-into surfaces of multiple rocks using the alpha particle X-ray spectrometer, which measures the abundance of major chemical elements. In the process, Spirit has documented the first example of a particular kind of volcanic region on Mars known as an alkaline igneous province. The word alkaline refers to the abundance of sodium and potassium, two major rock-forming elements from the alkali metals on the left-hand side of the periodic table.

All of the relatively unaltered rocks -- those least changed by wind, water, freezing, or other weathering agents -- examined by Spirit have been igneous, meaning that they crystallized from molten magmas. One way geologists classify igneous rocks is by looking at the amount of potassium and sodium relative to the amount of silica, the most abundant rock-forming mineral on Earth. In the case of volcanic rocks, the amount of silica present gives scientists clues to the kind of volcanism that occurred, while the amounts of potassium and sodium provide clues about the history of the rock. Rocks with more silica tend to erupt explosively. Higher contents of potassium and sodium, as seen in alkaline rocks like those at Gusev, may indicate partial melting of magma at higher pressure, that is, deeper in the Martian mantle. The abundance of potassium and sodium determines the kinds of minerals that make up igneous rocks. If igneous rocks have enough silica, potassium and sodium always bond with the silica to form certain minerals.

The Gusev rocks define a new chemical category not previously seen on Mars, as shown in this diagram plotting alkalis versus silica, compiled by University of Tennessee geologist Harry McSween. The abbreviations 'Na2O' and 'K2O' refer to oxides of sodium and potassium. The abbreviation 'SiO2' refers to silica. The abbreviation 'wt. %' indicates that the numbers tell what percentage of the total weight of each rock is silica (on the horizontal scale) and what percentage is oxides of sodium and potassium (on the vertical scale). The thin lines separate volcanic rock types identified on Earth by different scientific names such as foidite and picrobasalt. Various classes of Gusev rocks (see box in upper right) all plot either on or to the left of the green lines, which define 'alkaline' and 'subalkaline' categories (subalkaline rocks have more silica than alkaline rocks).

Members of the rover team have named different classes of rocks after specimens examined by Spirit that represent their overall character. During the rover's travels, Spirit discovered that Adirondack-class rocks littered the Gusev plains; that Backstay, Irvine, and Wishstone-class rocks occurred as loose blocks on the northwest slope of 'Husband Hill'; and that outcrops of Algonquin-class rocks protruded in several places on the southeast face.

These rocks have less silica than all previously analyzed Mars samples, which are subalkaline. The previously analyzed Mars samples include Martian meteorites found on Earth and rocks analyzed by the Mars Pathfinder rover in 1997. Gusev is the first documented example of an alkaline igneous province on Mars.

Geomorphology of New England

USGS Publications Warehouse

Denny, C.S.

1982-01-01

Widely scattered terrestrial deposits of Cretaceous or Tertiary age and extensive nearshore and fluvial Coastal Plain deposits now largely beneath the sea indicate that the New England region has been above sea level during and since the Late Cretaceous. Estimates of rates of erosion based on sediment load in rivers and on volume of sediments in the Coastal Plain suggest that if the New England highlands had not been uplifted in the Miocene, the area would now be largely a lowland. If the estimated rates of erosion and uplift are of the right order of magnitude, then it is extremely unlikely that any part of the present landscape dates back before Miocene time. The only exception would be lowlands eroded in the early Mesozoic, later buried beneath Mesozoic and Cenozoic deposits, and exhumed by stream and glacial erosion during the later Cenozoic. Many of the rocks in the New England highlands are similar to those that underlie the Piedmont province in the central and southern Appalachians, where the relief over large areas is much less than in the highlands of New England. These comparisons suggest that the New England highlands have been upwarped in late Cenozoic time. The uplift took place in the Miocene and may have continued into the Quaternary. The New England landscape is primarily controlled by the underlying bedrock. Erosion and deposition during the Quaternary, related in large part to glaciation, have produced only minor changes in drainage and in topography. Shale and graywacke of Ordovician, Cambrian, and Proterozoic age forming the Taconic highlands, and akalic plutonic rocks of Mesozoic age are all highland makers. Sandstone and shale of Jurassic and Triassic age, similar rocks of Carboniferous age, and dolomite, limestone, and shale of Ordovician and Cambrian age commonly underlie lowlands. High-grade metapelites are more resistant than similar schists of low metamorphic grade and form the highest mountains in New England. Feldspathic rocks tend to form lowlands. Alkalic plutonic rocks of Mesozoic age underlie a large area in the White Mountains of New Hampshire and doubtless are a factor in their location and relief. Where the major streams flow across the regional structure of the bedrock, the location of the crossings probably is related to some other characteristic of the bedrock, such as joints or cross faults. The course of the Connecticut River is the result of the adjustment of the drainage to the bedrock geology during a long period of time. There is no ready explanation why many of the large rivers do not cross areas of calcalkalic plutonic rock, but rather take a longer course around such areas, which tend to include segments of the divide between the streams. The presence of coarse clastic materials in Miocene rocks of the emerged Coastal Plain of the Middle Atlantic States suggests uplift of the adjacent Piedmont and of the Adirondack Mountains at that time. The Miocene rocks of the submerged Coastal Plain in the Gulf of Maine and south of New England are fine grained and contain only small amounts of fluvial gravel. Perhaps the coarse clastic materials shed by the New England highlands in late Cenozoic time are buried by or incorporated in the Pleistocene glacial deposits.

Petrology and geochronology of Mesoproterozoic basement of the Mount Rogers area of southwestern Virginia and northwestern North Carolina: Implications for the Precambrian tectonic evolution of the southern Blue Ridge province

USGS Publications Warehouse

Tollo, Richard P.; Aleinikoff, John N.; Dickin, Alan P.; Radwany, Molly S.; Southworth, C. Scott; Fanning, C. Mark

2017-01-01

Results from new geologic mapping, SHRIMP U-Pb geochronology, and petrologic studies indicate that Mesoproterozoic basement in the northern French Broad massif near Mount Rogers consists of multiple, mostly granitic plutons, map- and outcrop-scale xenoliths of pre-existing crustal rocks, and remnants of formerly overlying meta-sedimentary lithologies. Zircon and titanite ages demonstrate that these rocks collectively record nearly 350 m.y. of tectonic evolution including periods of igneous intrusion at ca. 1190 to 1130 Ma (Early Magmatic Suite) and ca. 1075 to 1030 Ma (Late Magmatic Suite) and three episodes of regional metamorphism at ca. 1170 to 1140, 1070 to 1020, and 1000 to 970 Ma. The existence of ca. 1.3 Ga age crust is indicated by (1) orthogranofels of ca. 1.32 Ga age in a map-scale xenolith, (2) inherited zircons of ca. 1.33 to 1.29 Ga age in Early Magmatic Suite plutons, and (3) ca. 1.36 to 1.30 Ga age detrital zircons in meta-sedimentary lithologies. Mineral assemblages developed in amphibolites and granofelses indicate that metamorphism during both Mesoproterozoic episodes occurred at upper amphibolite- to lower granulite-facies conditions. Syn-orogenic Early Magmatic Suite plutons emplaced at ca. 1190 to 1145 Ma are characterized by high-K, variably magnesian, dominantly calc-alkalic compositions, and have trace-element characteristics indicative of continental-arc magmatic origin involving melting of thick continental crust. In contrast, ca. 1140 Ma age quartz syenite displays A-type features indicating derivation from depleted crustal sources with increased mantle input during waning stages of regional contraction. Plutons of the compositionally bimodal Late Magmatic Suite include (1) ca. 1060 Ma meta-granite with geochemical characteristics transitional between silicic rocks of arc systems and post-collisional granites of A-type lineage, and (2) ca. 1055 Ma monzodioritic rocks with A-type compositional characteristics that likely reflect derivation from fertile, mafic sources in the lower crust. Collectively, these data suggest that Mesoproterozoic rocks of the study area preserve evidence of multiple orogenic episodes that likely involved continental-arc development and deformation at ca. 1150 Ma followed by crustal thickening at ca. 1060 Ma. Field relations and geochronologic data indicate that regional uplift and sedimentation occurred at ca. 1100 Ma between the two episodes of overlapping magmatism and orogenesis. The nature and timing of Mesoproterozoic events recorded in basement rocks of the study area illustrate significant differences in the lithologic assemblages and geologic history preserved by Mesoproterozoic basement of the adjacent Shenandoah and French Broad massifs, suggesting that the Blue Ridge massifs occupied different locations within the regional Grenville-age orogen until about 1070 Ma when the effects of Ottawan-age tectonics began to affect both areas. The near ubiquity of Ottawan-age orogenic activity recorded in Mesoproterozoic rocks of the Blue Ridge, other Appalachian inliers such as the New Jersey Highlands, and the Grenville province of Canada, including the Adirondacks, suggests that these formerly disparate terranes were amalgamated to form a common, regional orogen by this time.

Radarclinometry of the Earth and Venus from space-shuttle and Venera-15 imagery

USGS Publications Warehouse

Wildey, R.L.

1990-01-01

The project to develop a line-integral approach to 2-dimensional radarclinometry and to bring it to the status of producing topographic maps from real radar images has been concluded. The final developments of the theory itself have involved a trial-and-error resolution of the curvature decision process at each integration step over range as follows: (1) Locally Indeterminate Azimuth-Azimuth Curvature is invoked if the range-directed path of integration is within 1 ??? in angle of the tangent to a local characteristic curve of the partial differential equation of radarclinometry (equivalent to a lapse in the necessity for an auxiliary curvature assumption); (2) Local Cylindricity is invoked if the local image isophote has a radius-of-curvature greater than 50 pixels; (3) Least-Squared Local Sphericity is invoked if the characteristic curve trends at greater than 70 ??? to the range direction (the auxiliary curvature assumption is becoming a sufficiently strong influence as to warrant the overconstraint), and (4) the default hypothesis, which is invoked most often, is the localization through the Euler/Lagrange equation from the calculus of variations of the global principle of minimization of the surface area of the terrain. The development of the set of line integrals into a 2-dimensional topographic surface is not practically achieved by branching the line integral at the range threshold, because the radarclinometry equations are too frequently coupled but weakly to the slope component in the direction of radar-azimuth, and under circumstances for which the powerfully influential auxiliary curvature assumption is too unrealistic. In other words, a line integration in radar-azimuth is far more frequently directed orthogonally to the local characteristic curve than is one carried out over range. Such orthogonality results in stepping the strike under the exclusive control of the curvature assumption. Instead, a quasi-surface-integration step is taken by modeling the dependence on initial strike of the gravitational potential energy of the vertical slab of terrain under the range-profile. The adopted starting strike for the range integral is the one which minimizes the gravitational potential energy. This radarclinometric method, in combination with my recently published method for determining an effective radar back-scattering function from one-dimensional slope statistics and image pixel-signal statistics, was applied to three images. First, to separate theoretical difficulties from experimental impediments, an artificial radar image was generated from a topographic map of the Lake Champlain West quadrangle in the Adirondack Mountains. Except for the regional trend in elevation, to which radarclinometry is insensitive by design, the agreement between the original and derived topography appears good. The morphologies agree and the range of relief is the same to within 4%. As an example of data of the highest quality available from space-borne radar at the present time, a SIR-B image of very rugged terrain in the coastal mountains of Oregon was similarly processed. The result, after filtering to redistribute photoclinometric errors about the two-dimensional spatial spectrum, agrees with ground truth almost as well. As an example of the worst possible data, in terms of signal-to-noise ratio and radar incidence angle (no detraction from the praise due the first high resolution space-borne radar-imaging of Venus intended), a Venera-15 image segment in Sedna Planitia just north-east of Sapho was processed, using Venera altimetry and Pioneer roughness data for slope statistics, in spite of the resolution mis-match. Considerably more trial-and-error filtering was required. The result appears plausible, but an error check is, of course, impossible. ?? 1990 Kluwer Academic Publishers.

Geology and hydrology of the West Milton area, Saratoga County, New York

USGS Publications Warehouse

Mack, Frederick K.; Pauszek, F.H.; Crippen, John R.

1964-01-01

This report describes the geology, ground-water conditions, streamflow characteristics, and quality of water in the West Milton area, Saratoga County, N.Y. The West Milton area is in the east-central part of New York in the hilly region that forms a transition zone between the Adirondack Mountains and the Hudson-Mohawk valley lowland. Bedrock underlying the area consists of crystalline rocks of Precambrian age and sandstone, dolomite, limestone, and shale formations of Cambrian and Ordovician age. The formations have been moderately folded and have been displaced as much as several hundred feet' along at least three northeast-trending normal faults. The bedrock is overlain in nearly all parts of the area by a layer of unconsolidated deposits which ranges in thickness from a few feet to more than 200 feet. The unconsolidated deposits are of Pleistocene age and consist of unstratified materials (till) laid down by glacial ice at stratified sediments deposited by glacial meltwaters. The topography of the bedrock surface differs greatly from the topography of the land surface. Although not evident in the present topography, at least two channels, cut in bedrock by preglacial streams, pass through the area. Ground-water supplies adequate to satisfy domestic requirements can be obtained from wells in any part of the area. Large ground-water supplies may be taken from coarse-grained stratified deposits comprising two aquifers in the valley of Kayaderosseras Creek. The Atomic Energy Commission has pumped as much as 1 mgd from a horizontal well drawing from the uppermost aquifer which is composed of flood-plain deposits. Part of the water yielded by this well during extended periods of pumping is induced flow from the creek. Three nearby vertical wells drilled by the Commission comprise a separate well field capable of yielding at least 2 mgd and possibly as much as 3 mgd from the deeper stratified deposits underlying the valley. A pumping test showed that at near the center of this well field the coefficient of transmissibility is about 125,000 gpd per ft and the coefficient of storage is about 0.0003. The water obtained from the sand and gravel has a hardness of about 125 ppm and contains about 150 ppm of dissolved solids. Most of the Government reservation is drained by Glowegee Creek, one of the larger tributaries of Kayaderosseras Creek. The average streamflow of Kayaderosseras Creek at West Milton is 141 cfs or about 1.5 cfs per sq. mi. The monthly mean discharge has ranged from a low of 21.7 cfs in September 1958 to a high of 866 cfs in March 1936, and the annual mean discharge has ranged from 94.5 cfs in 1941 to 198 cfs in 1952. The mean annual flood is 1,740 cfs and the 50-year flood is 5,300 cfs. Streamflow data have been collected on Glowegee Creek since 1948 at a station 0.5 mile south of West Milton. The average streamflow of Glowegee Creek at this station is 41 cfs or about 1.5 cfs per sq mi. The mean annual flood is 740 cfs and the 50-year flood is 2,250 cfs. The quality of the water in both Kayaderosseras Creek and Glowegee Creek is satisfactory for public supply and most industrial purposes. The mineral content of both streams is low--the dissolved-solids content averaging about 93 ppm in Kayaderosseras Creek and about 131 ppm in Glowegee Creek. The average hardness of water in Kayaderosseras Creek and Glowegee Creek is 68 ppm and 102 ppm, respectively. During periods of low flow, suspended sediment discharge in both streams is less than 10 tons per day, but during periods of high flow, the sediment discharge has been as great as 163 tons per day in Glowegee Creek and 437 tons per day in Kayaderosseras Creek.

Effects of recreational flow releases on natural resources of the Indian and Hudson Rivers in the Central Adirondack Mountains, New York, 2004-06

USGS Publications Warehouse

Baldigo, Barry P.; Mulvihill, C.I.; Ernst, A.G.; Boisvert, B.A.

2011-01-01

The U.S. Geological Survey (USGS), the New York State Department of Environmental Conservation (NYSDEC), and Cornell University carried out a cooperative 2-year study from the fall of 2004 through the fall of 2006 to characterize the potential effects of recreational-flow releases from Lake Abanakee on natural resources in the Indian and Hudson Rivers. Researchers gathered baseline information on hydrology, temperature, habitat, nearshore wetlands, and macroinvertebrate and fish communities and assessed the behavior and thermoregulation of stocked brown trout in study reaches from both rivers and from a control river. The effects of recreational-flow releases (releases) were assessed by comparing data from affected reaches with data from the same reaches during nonrelease days, control reaches in a nearby run-of-the-river system (the Cedar River), and one reach in the Hudson River upstream from the confluence with the Indian River. A streamgage downstream from Lake Abanakee transmitted data by satellite from November 2004 to November 2006; these data were used as the basis for developing a rating curve that was used to estimate discharges for the study period. River habitat at most study reaches was delineated by using Global Positioning System and ArcMap software on a handheld computer, and wetlands were mapped by ground-based measurements of length, width, and areal density. River temperature in the Indian and Hudson Rivers was monitored continuously at eight sites during June through September of 2005 and 2006; temperature was mapped in 2005 by remote imaging made possible through collaboration with the Rochester Institute of Technology. Fish communities at all study reaches were surveyed and characterized through quantitative, nearshore electrofishing surveys. Macroinvertebrate communities in all study reaches were sampled using the traveling-kick method and characterized using standard indices. Radio telemetry was used to track the movement and persistence of stocked brown trout (implanted with temperature-sensitive transmitters) in the Indian and Hudson Rivers during the summer of 2005 and in all three rivers during the summer of 2006. The releases had little effect on river temperatures, but increased discharges by about one order of magnitude. Regardless of the releases, river temperatures at all study sites commonly exceeded the threshold known to be stressful to brown trout. At most sites, mean and median water temperatures on release days were not significantly different, or slightly lower, than water temperatures on nonrelease days. Most differences were very small and, thus, were probably not biologically meaningful. The releases generally increased the total surface area of fast-water habitat (rapids, runs, and riffles) and decreased the total surface area of slow-water habitat (pools, glides, backwater areas, and side channels). The total surface areas of wetlands bordering the Indian River were substantially smaller than the surface areas bordering the Cedar River; however, no channel geomorphology or watershed soil and topographic data were assessed to determine whether the releases or other factors were mainly responsible for observed differences. Results from surveys of resident biota indicate that the releases generally had a limited effect on fish and macroinvertebrate communities in the Indian River and had no effect on communities in the Hudson River. Compared to fish data from Cedar River control sites, the impoundment appeared to reduce total density, biomass, and richness in the Indian River at the first site downstream from Lake Abanakee, moderately reduce the indexes at the other two sites on the Indian River, and slightly reduce the indexes at the first Hudson River site downstream from the confluence with the Indian River. The densities of individual fish populations at all Indian River sites were also reduced, but related effects on fish populations in the Hudson River were less evident. Altho

Ground-Water Quality in the St. Lawrence River Basin, New York, 2005-06

USGS Publications Warehouse

Nystrom, Elizabeth A.

2007-01-01

The Federal Clean Water Act requires that States monitor and report on the quality of ground water and surface water. To satisfy part of these requirements, the U.S. Geological Survey and New York State Department of Environmental Conservation have developed a program in which ground-water quality is assessed in 2 to 3 of New York State's 14 major river basins each year. To characterize the quality of ground water in the St. Lawrence River Basin in northern New York, water samples were collected from 14 domestic and 11 production wells between August 2005 and January 2006. Eight of the wells were finished in sand and gravel and 17 wells were finished in bedrock. Ground-water samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 229 constituents and physical properties, including inorganic constituents, nutrients, trace elements, radon-222, pesticides and pesticide degradates, volatile organic compounds, and bacteria. Sixty-six constituents were detected above laboratory reporting levels. Concentrations of most compounds at most sites were within drinking water standards established by the U.S. Environmental Protection Agency and New York State Department of Health, but a few compounds exceeded drinking water standards at some sites. Water in the basin is generally hard to very hard (hardness equal to 121 mg/L as CaCO3 or greater); hardness and alkalinity were generally higher in the St. Lawrence Valley than in the Adirondack Mountains. The cation with the highest median concentration was calcium; the anion with the highest median concentration was bicarbonate. The concentration of chloride in one sample exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard; the concentration of sulfate in one sample also exceeded the 250 milligrams per liter U.S. Environmental Protection Agency Secondary Drinking Water Standard. Nitrate was the predominant nutrient detected but no sample exceeded the 10 mg/L U.S. Environmental Protection Agency Maximum Contaminant Level. The trace elements detected with the highest median concentrations were strontium, barium, and iron. Concentration of trace elements in several samples exceeded U.S. Environmental Protection Agency Secondary Drinking Water Standards, including aluminum (50 micrograms per liter, 4 samples), iron (300 micrograms per liter, 5 samples), and manganese (50 micrograms per liter, 4 samples). The concentration of uranium in one sample from a domestic well finished in crystalline bedrock was three times the U.S. Environmental Protection Agency Maximum Contaminant Level of 30 micrograms per liter. The median concentration of radon-222 was 600 picoCuries per liter, but concentrations as high as 18,800 picoCuries per liter were detected; two wells with high radon concentrations also had high uranium concentrations. Radon-222 is not currently regulated, but the U.S. Environmental Protection Agency has proposed a Maximum Contaminant Level of 300 picoCuries per liter along with an Alternative Maximum Contaminant Level of 4,000 picoCuries per liter, to be in effect in states that have programs to address radon in indoor air. Concentrations of radon-222 exceeded the proposed Maximum Contaminant Level in 60 percent of samples and exceeded the proposed Alternative Maximum Contaminant Level in 8 percent of samples. Six pesticides and pesticide degradates were detected; all were amide or triazine herbicides or degradates. Five volatile organic compounds were detected, including disinfection byproducts such as trichloromethane and gasoline components or additives such as methyl tert-butyl ether. No pesticides, pesticide degradates, or volatile organic compounds were detected above established limits. Coliform bacteria, including Escherichia coli, were detected in three wells finished in carbonate bedrock.

Geologic summary of the Appalachian Basin, with reference to the subsurface disposal of radioactive waste solutions

USGS Publications Warehouse

Colton, G.W.

1962-01-01

The Appalachian basin is an elongate depression in the crystalline basement complex< which contains a great volume of predominantly sedimentary stratified rocks. As defined in this paper it extends from the Adirondack Mountains in New York to central Alabama. From east to west it extends from the west flank of the Blue Ridge Mountains to the crest of the Findlay and Cincinnati arches and the Nashville dome. It encompasses an area of about 207,000 square miles, including all of West Virginia and parts of New York, New Jersey, Pennsylvania, Ohio, Maryland, Virginia, Kentucky, Tennessee, North Carolina, Georgia, and Alabama. The stratified rocks that occupy the basin constitute a wedge-shaped mass whose axis of greatest thickness lies close to and parallel to the east edge of the basin. The maximum thickness of stratified rocks preserved in any one part of the basin today is between 35,000 and 40,000 feet. The volume of the sedimentary rocks is approximately 510,000 cubic miles and of volcanic rocks is a few thousand cubic miles. The sedimentary rocks are predominantly Paleozoic in age, whereas the volcanic rocks are predominantly Late Precambrian. On the basis of gross lithology the stratified rocks overlying the crystalline basement complex can be divided into nine vertically sequential units, which are designated 'sequences' in this report. The boundaries between contiguous sequences do not necessarily coincide with the commonly recognized boundaries between systems or series. All sequences are grossly wedge shaped, being thickest along the eastern margin of the basin and thinnest along the western margin. The lowermost unit--the Late Precambrian stratified sequence--is present only along part of the eastern margin of the basin, where it lies unconformably on the basement complex. It consists largely of volcanic tuffs and flows but contains some interbedded sedimentary rocks. The Late Precambrian sequence is overlain by the Early Cambrian clastic sequence. Where the older sequence is absent, the Early Cambrian sequence rests on the basement complex. Interbedded fine- to coarse-grained noncarbonate detrital rocks comprise the bulk of the sequence, but some volcanic and carbonate rocks are included. Next above is the Cambrian-Ordovician carbonate sequence which consists largely of limestone and dolomite. Some quartzose sandstone is present in the lower part in the western half of the basin, and much shale is present in the upper part in the southeast part of the basin. The next higher sequence is the Late Ordovician clastic sequence, which consists largely of shale, siltstone, and sandstone. Coarse-grained light-gray to red rocks are common in the sequence along the eastern side of the basin, whereas fine-grained dark-gray to black calcareous rocks are common along the west side. The Late Ordovician clastic sequence is overlain--unconformably in many places--by the Early Silurian clastic sequence. The latter comprises a relatively thin wedge of coarse-grained clastic rocks. Some of the most prolific oil- and gas-producing sandstones in the Appalachian basin are included. Among these are the 'Clinton' sands of Ohio, the Medina Sandstones of New York and Pennsylvania, and the Keefer or 'Big Six' Sandstone of West Virginia and Kentucky. Conformably overlying the Early Silurian clastic sequence is the Silurian-Devonian carbonate sequence, which consists predominantly of limestone and dolomite. It also contains a salt-bearing unit in the north-central part of the basin and a thick wedge of coarse-grained red beds in the northeastern part. The sequence is absent in much of the southern part of the basin. Large volumes of gas and much oil are obtained from some of its rocks, especially from the Oriskany Sandstone and the Huntersville Chert. The Silurian-Devonian carbonate sequence is abruptly overlain by the Devonian clastic sequence--a thick succession of interbedded shale, mudrock, siltstone, and sandstone. Colors range f

Iron-ore resources of the United States including Alaska and Puerto Rico, 1955

USGS Publications Warehouse

Carr, Martha S.; Dutton, Carl E.

1959-01-01

The importance of iron ore, the basic raw material of steel, as a fundamental mineral, resource is shown by the fact that about 100 million long tons of steel is used annually in the economy of the United States, as compared with a combined total of about 5 million long tons of copper, lead, zinc, and aluminum. Satisfying this annual demand for steel requires about 110 million tons of iron ore and 70 million tons of scrap iron and steel. The average annual consumption of iron ore in the United States from 1951 to 1955, inclusive, was about 110 million long tons, which is about twice the annual average from 1900 to 1930. Production of iron ore in the United States in this 5-year period averaged approximately 100 million long tons annually, divided by regions as follows (in percent): Lake Superior, 84.1; southeastern, 6.7; western, 6.7; northeastern, 1.4; and central and gulf, 1.1. Mining of iron ore began in the American Colonies about 1619, and for 225 years it was limited to eastern United States where fuel and markets were readily available. Production of iron ore from the Lake Superior region began in 1846; the region became the leading domestic source by 1890, and the Mesabi range in Minnesota has been the world's most productive area since 1896. Proximity of raw materials, water transportation, and markets has resulted in centralization of the country's iron and steel industry in the lower Great Lakes area. Increased imports of iron ore being delivered to eastern United States as well as demands for steel in nearby markets have given impetus to expansion in the steel-making capacity in this area. The four chief iron-ore minerals - hematite, liminite, magnetite, and siderite - are widely distributed but only locally form deposits of sufficient tonnage and grade to be commercially valuable at the present time. The iron content of these minerals, of which hematite is the most important, ranges from 48 percent in siderite to 72 percent in magnetite, but as these minerals are associated with other rock-forming minerals, the iron content of marketable ore has a lower range from 30 to 67 percent.Chemical constituents other than iron also are important in determining the marketability of iron ore. Although some iron ores can be used in the blast furnace as mined, others must first be improved either chemically by reduction of undesirable constituents, or physically by aggregation. Phosphorus and sulfur particularly are common deleterious elements; excessive silica is also undesirable but within certain limits can be controlled by additional flux. Lime and magnesia are beneficial in specified amounts because of their fluxing qualities, and a small amount of alumina improves the fluidity of slag. Manganese is especially desirable as a deoxidizing and desulfurizing agent. Titanium, chromium, and nickel must also be considered in the use of ore containing these elements.The principal iron-ore deposits in the United States have been formed by three processes. Hematite-bearing bedded deposits such as those at Birmingham, Ala., are marine sedimentary rocks which, except for weathering along the outcrop, have remained practically unaltered since deposition. Deposits of the Lake Superior region, also in sedimentary strata, originally had a slightly lower iron content than those at-Birmingham, but ore bodies of hematite and limonite were formed by removal of other constituents in solution after deposition of the beds, with a relative increase of iron content in the material remaining. Limestone adjacent to igneous intrusions has been replaced by magnetite deposits at Cornwall, Pa., and by hematite-magnetite deposits near Cedar City, Utah. Magnetite deposits in New Jersey and in the Adirondack Mountains of New York are generally believed to have been formed by replacement of grains of other minerals in metamorphic rocks. Iron-ore resources are made up of reserves of iron ore, material usable under existing economic and technologic conditions; and potential ore, material likely to become usable under more favorable conditions. The tonnage and grade of material of combined reserves and potential ore in each of the deposits known or believed to contain at least 200,000 long tons of iron-ore resources are tabulated in this report, and numerous sources of additional information are given in a selected bibliography. The total domestic iron-ore resources are estimated at approximately 75,000 million long tons of crude ore. About 10,000 million tons of the resources is reserves of crude ore that will probably yield 5,500 million tons of concentrates and direct-shipping ore. About 65,000 million tons is potential ore and may yield 25,000 million tons of concentrates and some direct-shipping ore.